WorldWideScience

Sample records for velocity air fuel

  1. Analysis of Fuel Vaporization, Fuel-Air Mixing, and Combustion in Integrated Mixer-Flame Holders

    Science.gov (United States)

    Deur, J. M.; Cline, M. C.

    2004-01-01

    Requirements to limit pollutant emissions from the gas turbine engines for the future High-Speed Civil Transport (HSCT) have led to consideration of various low-emission combustor concepts. One such concept is the Integrated Mixer-Flame Holder (IMFH). This report describes a series of IMFH analyses performed with KIVA-II, a multi-dimensional CFD code for problems involving sprays, turbulence, and combustion. To meet the needs of this study, KIVA-II's boundary condition and chemistry treatments are modified. The study itself examines the relationships between fuel vaporization, fuel-air mixing, and combustion. Parameters being considered include: mixer tube diameter, mixer tube length, mixer tube geometry (converging-diverging versus straight walls), air inlet velocity, air inlet swirl angle, secondary air injection (dilution holes), fuel injection velocity, fuel injection angle, number of fuel injection ports, fuel spray cone angle, and fuel droplet size. Cases are run with and without combustion to examine the variations in fuel-air mixing and potential for flashback due to the above parameters. The degree of fuel-air mixing is judged by comparing average, minimum, and maximum fuel/air ratios at the exit of the mixer tube, while flame stability is monitored by following the location of the flame front as the solution progresses from ignition to steady state. Results indicate that fuel-air mixing can be enhanced by a variety of means, the best being a combination of air inlet swirl and a converging-diverging mixer tube geometry. With the IMFH configuration utilized in the present study, flashback becomes more common as the mixer tube diameter is increased and is instigated by disturbances associated with the dilution hole flow.

  2. Zinc-air battery/fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Wang, H.; Li, H.; Qu, W. [National Research Council Canada, Vancouver, BC (United States). Inst. for Fuel Cell Innovation

    2010-07-01

    The zinc-air battery/fuel cell is an old technology invented one hundred years ago. However, there is renewed interest in this technology in response to the growing need for clean energy technology. The zinc-air battery/fuel cell is more attractive than similar technologies because its characteristics include high power density, safe operation and storage, and low cost. Zinc-air battery/fuel cells can be made in milliwatts to mega watts to accommodate different applications. The zinc-air battery/fuel cell has four major designs, namely primary, mechanically rechargeable, continuous feed and electrically rechargeable zinc-air battery/fuel cells. Among the different designs, the most common is the air cathode. There are 3 generations of catalysts used in the air cathodes. This paper discussed the different designs of the zinc-air battery/fuel cell, and more specifically, the air cathode structure and performance.

  3. Microstructure and Wear Behavior of FeCoCrNiMo0.2 High Entropy Coatings Prepared by Air Plasma Spray and the High Velocity Oxy-Fuel Spray Processes

    Directory of Open Access Journals (Sweden)

    Tianchen Li

    2017-09-01

    Full Text Available In the present research, the spherical FeCoCrNiMo0.2 high entropy alloy (HEA powders with a single FCC solid solution structure were prepared by gas atomization. Subsequently, the FeCoCrNiMo0.2 coatings with a different content of oxide inclusions were prepared by air plasma spraying (APS and high-velocity oxy-fuel spraying (HVOF, respectively. The microstructure, phase composition, mechanical properties, and tribological behaviors of these HEA coatings were investigated. The results showed that both HEA coatings showed a typical lamellar structure with low porosity. Besides the primary FCC phase, a mixture of Fe2O3, Fe3O4, and AB2O4 (A = Fe, Co, Ni, and B = Fe, Cr was identified as the oxide inclusions. The oxide content of the APS coating and HVOF coating was calculated to be 47.0% and 12.7%, respectively. The wear resistance of the APS coating was approximately one order of magnitude higher than that of the HVOF coating. It was mainly attributed to the self-lubricated effect caused by the oxide films. The mass loss of the APS coating was mainly ascribed to the breakaway of the oxide film, while the main wear mechanism of the HVOF coating was the abrasive wear.

  4. Fuel Cell Electrodes for Hydrogen-Air Fuel Cell Assemblies.

    Science.gov (United States)

    The report describes the design and evaluation of a hydrogen-air fuel cell module for use in a portable hydrid fuel cell -battery system. The fuel ... cell module consists of a stack of 20 single assemblies. Each assembly contains 2 electrically independent cells with a common electrolyte compartment

  5. The effect of air velocity on heat stress at increased air temperature

    DEFF Research Database (Denmark)

    Bjerg, Bjarne Schmidt; Wang, Xiaoshuai; Zhang, Guoqiang

    to the temperature difference between the surfaces of animals and the surrounding air, and this temperature difference declines when the air temperature approaches the animal body temperature. Consequently it can it by expected that the effect of air velocity decreases at increased air temperature. The literature...... on different categories of farm animals to determine how the effect of air velocity depends on the air temperature. A new expression to calculate the chilling effect of increased air velocity was suggested. In addition to the parameters air velocity and air temperature this new expression included three......Increased air velocity is a frequently used method to reduce heat stress of farm animals housed in warm conditions. The main reason why the method works is that higher air velocity increases the convective heat release from the animals. Convective heat release from the animals is strongly related...

  6. Air-cooled, hydrogen-air fuel cell

    Science.gov (United States)

    Shelekhin, Alexander B. (Inventor); Bushnell, Calvin L. (Inventor); Pien, Michael S. (Inventor)

    1999-01-01

    An air-cooled, hydrogen-air solid polymer electrolyte (SPE) fuel cell with a membrane electrode assembly operatively associated with a fluid flow plate having at least one plate cooling channel extending through the plate and at least one air distribution hole extending from a surface of the cathode flow field into the plate cooling channel.

  7. Fuel flexible fuel injector

    Science.gov (United States)

    Tuthill, Richard S; Davis, Dustin W; Dai, Zhongtao

    2015-02-03

    A disclosed fuel injector provides mixing of fuel with airflow by surrounding a swirled fuel flow with first and second swirled airflows that ensures mixing prior to or upon entering the combustion chamber. Fuel tubes produce a central fuel flow along with a central airflow through a plurality of openings to generate the high velocity fuel/air mixture along the axis of the fuel injector in addition to the swirled fuel/air mixture.

  8. Investigation on Effect of Air Velocity in Turbulent Non-Premixed Flames

    Directory of Open Access Journals (Sweden)

    Namazian Zafar

    2016-09-01

    Full Text Available In this study, the turbulent non-premixed methane-air flame is simulated to determine the effect of air velocity on the length of flame, temperature distribution and mole fraction of species. The computational fluid dynamics (CFD technique is used to perform this simulation. To solve the turbulence flow, k-ε model is used. In contrast to the previous works, in this study, in each one of simulations the properties of materials are taken variable and then the results are compared. The results show that at a certain flow rate of fuel, by increasing the air velocity, similar to when the properties are constant, the width of the flame becomes thinner and the maximum temperature is higher; the penetration of oxygen into the fuel as well as fuel consumption is also increased. It is noteworthy that most of the pollutants produced are NOx, which are strongly temperature dependent. The amount of these pollutants rises when the temperature is increased. As a solution, decreasing the air velocity can decrease the amount of these pollutants. Finally, comparing the result of this study and the other work, which considers constant properties, shows that the variable properties assumption leads to obtaining more exact solution but the trends of both results are similar.

  9. The Effect Of Initial Temperature On Burning Velocity Of Methane, Propane, Lpg And Iso Butane - Air Mixtures

    OpenAIRE

    Hamid, M. N.; Said, Arkan F.

    2001-01-01

    In present work, the burning velocity of a fuel - air mixtures varies with equivalence ratio, temperature and number of carbon atoms. Laminar flame speed have been measured experimentally inside a tube using the optical technique. The experimental work was carried out in a pre-pressure period in order to use density ratio method for calculation of laminar burning velocity. Mixture strength, unbumed mixture temperature and number of carbon atoms dependence of burning velocity is represented by...

  10. US Air Force fuel cell application analysis

    Science.gov (United States)

    Pouchot, W. D.; Summers, W. A.; Hofbauer, J. A.

    1982-01-01

    Fuel Cell Power Unit conceptual designs and cost/benefit analyses were accomplished for six U.S. Air Force applications. The applications included two attended remote sites, two unattended remote sites and two tactical/mobile requirements. The electrical power ratings of these designs ranged from 23 kW to 100 kW. Fuels considered included diesel, Jet Fuel (JP-4) and methanol. Life cycle cost and benefit analyses showed that significant savings and operational improvements could be realized with the introduction of fuel cells into the USAF power generation inventory.

  11. Air breathing direct methanol fuel cell

    Science.gov (United States)

    Ren, Xiaoming; Gottesfeld, Shimshon

    2002-01-01

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source. Water loss from the cell is minimized by making the conductive cathode assembly hydrophobic and the conductive anode assembly hydrophilic.

  12. The acceptable air velocity range for local air movement in the Tropics

    DEFF Research Database (Denmark)

    Gong, Nan; Tham, K.W.; Melikov, Arsen Krikor

    2006-01-01

    for 15 minutes, during which the subjects responded to computer-administered questionnaires on their thermal and draft sensations using visual-analogue scales. The results showed that the subjects preferred air movement within a certain range, i.e., a higher percentage was dissatisfied at both low...... and high velocity values. Most dissatisfaction with air movement is caused by thermal sensation, with air movement perception accounting for a smaller proportion. The subjects preferred air movement to be between "just right" and "slightly breezy" and preferred their thermal sensation to be between...... "neutral" and "slightly cool. The study also identified an acceptable air velocity range from 0.3 up to 0.9 m/s under the experimental conditions. This velocity range is relevant for the design of personalized ventilation in practice. This preferred velocity range is higher than the maximum velocity...

  13. Significance of air humidity and air velocity for fungal spore release into the air

    Science.gov (United States)

    Pasanen, A.-L.; Pasanen, P.; Jantunen, M. J.; Kalliokoski, P.

    Our previous field studies have shown that the presence of molds in buildings does not necessarily mean elevated airborne spore counts. Therefore, we investigated the release of fungal spores from cultures of Aspergillus fumigatus, Penicillium sp. and Cladosporium sp. at different air velocities and air humidities. Spores of A. fumigatus and Penicillium sp. were released from conidiophores already at air velocity of 0.5 ms -1, whereas Cladosporium spores required at least a velocity of 1.0 ms -1. Airborne spore counts of A. fumigatus and Penicillium sp. were usually higher in dry than moist air, being minimal at relative humidities (r.h.) above 70%, while the effect of r.h. on the release of Cladosporium sp. was ambivalent. The geometric mean diameter of released spores increased when the r.h. exceeded a certain level which depends on fungal genus. Thus, spores of all three fungi were hygroscopic but the hygroscopicity of various spores appeared at different r.h.-ranges. This study indicates that spore release is controlled by external factors and depends on fungal genus which can be one reason for considerable variation of airborne spore counts in buildings with mold problems.

  14. Influences of the Air in Metal Powder High Velocity Compaction

    Directory of Open Access Journals (Sweden)

    Liu Jun

    2017-01-01

    Full Text Available During the process of metal powder high velocity impact compaction, the air is compressed sharply and portion remains in the compacts. In order to study the Influences, a discrete density volleyball accumulation model for aluminium powder was established with the use of ABAQUS. Study found that the powder porosity air obstruct the pressing process because remaining air reduced strength and density of the compacts in the current high-speed pressing (V≤100m/s. When speed further increased (V≥100m/s, the temperature of the air increased sharply, and was even much higher than the melting point of the material. When aluminium powder was compressed at a speed of 200m/s, temperatures of air could reach 2033 K, far higher than the melting point of 877 K. Increased density of powders was a result of local softening and even melt adhesive while air between particles with high temperature and pressure flowed past.

  15. Influence of local air velocity from air conditioner evaluated by salivary and skin biomarkers

    Energy Technology Data Exchange (ETDEWEB)

    Yamaguchi, Masaki; Takahashi, Takayuki; Yoshino, Yuichiro; Sasaki, Makoto [Graduate School of Engineering, Iwate University, 4-3-5 Ueda, Morioka 020-8551 (Japan); Nishimiya, Hajime [Asahi Kasei Homes Corporation, R and D Laboratories, 2-1 Samejima, Fuji, Shizuoka 416-8501 (Japan)

    2010-11-15

    The purpose of this paper is to reveal both the psychosomatic and the physical effects of local air velocity from an air conditioner using biomarkers which can be collected noninvasively. Salivary {alpha}-amylase activity (SAA) and salivary cortisol were used as the indexes of psychosomatic effects. The total protein (TP) collected from stratum corneum was used as an index of the physical condition of dry skin. A continuous experiment over a 5 days period in summer was conducted using 8 healthy young male adults for 2-types of airflow conditioners, a whole ceiling-type air conditioner (without local air velocity) and a normal-type air conditioner (with local air velocity). The subjects felt cool, windy, dry and uncomfortable when under the normal-type air conditioner as determined in a subjective evaluation. The SAA under the normal-type air conditioner fluctuated more widely than with the whole ceiling-type air conditioner. The level of salivary cortisol decreased more in a day under the normal-type air conditioner than with the whole ceiling-type air conditioner. These results showed that reducing local air velocity may provide more healthy psychosomatic conditions over the long-term. Moreover, the TP of a drying-exposed skin area showed a significant change during this experiment whereas the TP of drying-protected area was relatively unchanged. It was indicated that one week's exposure to local air velocity conditions possibly influences the drying of facial skin. Thus, air movement at low velocity can be provides more comfortable conditions not only psychosomatically but also physically. (author)

  16. Coaxial fuel and air premixer for a gas turbine combustor

    Science.gov (United States)

    York, William D; Ziminsky, Willy S; Lacy, Benjamin P

    2013-05-21

    An air/fuel premixer comprising a peripheral wall defining a mixing chamber, a nozzle disposed at least partially within the peripheral wall comprising an outer annular wall spaced from the peripheral wall so as to define an outer air passage between the peripheral wall and the outer annular wall, an inner annular wall disposed at least partially within and spaced from the outer annular wall, so as to define an inner air passage, and at least one fuel gas annulus between the outer annular wall and the inner annular wall, the at least one fuel gas annulus defining at least one fuel gas passage, at least one air inlet for introducing air through the inner air passage and the outer air passage to the mixing chamber, and at least one fuel inlet for injecting fuel through the fuel gas passage to the mixing chamber to form an air/fuel mixture.

  17. Parameterizing air-sea gas transfer velocity with dissipation

    Science.gov (United States)

    Esters, L.; Landwehr, S.; Sutherland, G.; Bell, T. G.; Christensen, K. H.; Saltzman, E. S.; Miller, S. D.; Ward, B.

    2017-04-01

    The air-sea gas transfer velocity k is frequently estimated as an empirical function of wind speed. However, it is widely recognized that k depends on processes other than wind speed alone. The small-eddy model, which describes periodic events of small eddies disturbing the sea surface with water from below, suggests a direct relation between k and the dissipation rate of turbulent kinetic energy ɛ at the air-sea interface. This relation has been proven both in laboratories and in the field in various freshwater and coastal environments, but to date has not been verified in open ocean conditions. Here, concurrent North Atlantic field observations of ɛ and eddy covariance measurements of DMS and CO2 air-sea gas flux are presented. Using ɛ measurements, we compare the small-eddy model at various depths to previously published observations. Extrapolating the measured ɛ profiles to the thickness of the viscous sublayer allows us to formulate a function of k that depends solely on the water side friction velocity u∗w, which can be inferred from direct eddy covariance measurements of the air-side friction velocity u∗a. These field observations are generally consistent with the theoretical small-eddy model. Utilizing a variable Schmidt number exponent in the model, rather than a constant value of 1/2 yields improved agreement between model and observations.

  18. Measurements and correlations of turbulent burning velocities over wide ranges of fuels and elevated pressures

    KAUST Repository

    Bradley, Derek

    2013-01-01

    The implosion technique has been used to extend measurements of turbulent burning velocities over greater ranges of fuels and pressures. Measurements have been made up to 3.5 MPa and at strain rate Markstein numbers as low as 23. The implosion technique, with spark ignition at two opposite wall positions within a fan-stirred spherical bomb is capable of measuring turbulent burning velocities, at higher pressures than is possible with central ignition. Pressure records and schlieren high speed photography define the rate of burning and the smoothed area of the flame front. The first aim of the study was to extend the previous measurements with ethanol and propane-air, with further measurements over wider ranges of fuels and equivalence ratios with mixtures of hydrogen, methane, 10% hydrogen-90% methane, toluene, and i-octane, with air. The second aim was to study further the low turbulence regime in which turbulent burning co-exists with laminar flame instabilities. Correlations are presented of turbulent burning velocity normalised by the effective rms turbulent velocity acting on the flame front, ut=u0k , with the Karlovitz stretch factor, K, for different strain rate Markstein numbers, a decrease in which increases ut=u0k . Experimental correlations are presented for the present measurements, combined with previous ones. Different burning regimes are also identified, extending from that of mixed turbulence/laminar instability at low values of K to that at high values of K, in which ut=u0k is gradually reduced due to increasing localised flame extinctions. © 2012 The Combustion Institute.

  19. INTERACTION OF AIR TRANSPORTATION AND FUEL-SUPPLY COMPANIES

    Directory of Open Access Journals (Sweden)

    I. P. Zheleznaya

    2014-01-01

    Full Text Available The article describes the role of aviation fuel in the life of air transport. Fueling industry worldwide solves two main tasks - ensuring the safety and economy of air traffic. In Russia, there is one more task of airlines fuel supply. The article deals with fuel pricing taking into consideration today's realities.

  20. Microcomputer measurement of the velocity of sound in air

    Science.gov (United States)

    Bates, P. A.

    1983-05-01

    The velocity of sound in air can be measured in a general physics laboratory using many well known methods such as Hebb's method, Kundt's tube, etc. The experiment described allows the velocity of sound in air to be determined relatively easily but it has really been developed to enable a student to use a microcomputer in a physical experiment. The intention has been for the student to become familiar with an Apple II microcomputer that is being used for data collection and to realise that data collected in this manner may be processed manually as well as with the aid of a computer. It is hoped that by using such techniques students may be instructed in the best use of computers in both the collection and handling of experimental results.

  1. Hydrogen/Air Fuel Nozzle Emissions Experiments

    Science.gov (United States)

    Smith, Timothy D.

    2001-01-01

    The use of hydrogen combustion for aircraft gas turbine engines provides significant opportunities to reduce harmful exhaust emissions. Hydrogen has many advantages (no CO2 production, high reaction rates, high heating value, and future availability), along with some disadvantages (high current cost of production and storage, high volume per BTU, and an unknown safety profile when in wide use). One of the primary reasons for switching to hydrogen is the elimination of CO2 emissions. Also, with hydrogen, design challenges such as fuel coking in the fuel nozzle and particulate emissions are no longer an issue. However, because it takes place at high temperatures, hydrogen-air combustion can still produce significant levels of NOx emissions. Much of the current research into conventional hydrocarbon-fueled aircraft gas turbine combustors is focused on NOx reduction methods. The Zero CO2 Emission Technology (ZCET) hydrogen combustion project will focus on meeting the Office of Aerospace Technology goal 2 within pillar one for Global Civil Aviation reducing the emissions of future aircraft by a factor of 3 within 10 years and by a factor of 5 within 25 years. Recent advances in hydrocarbon-based gas turbine combustion components have expanded the horizons for fuel nozzle development. Both new fluid designs and manufacturing technologies have led to the development of fuel nozzles that significantly reduce aircraft emissions. The goal of the ZCET program is to mesh the current technology of Lean Direct Injection and rocket injectors to provide quick mixing, low emissions, and high-performance fuel nozzle designs. An experimental program is planned to investigate the fuel nozzle concepts in a flametube test rig. Currently, a hydrogen system is being installed in cell 23 at NASA Glenn Research Center's Research Combustion Laboratory. Testing will be conducted on a variety of fuel nozzle concepts up to combustion pressures of 350 psia and inlet air temperatures of 1200 F

  2. Degradation characteristics of air cathode in zinc air fuel cells

    Science.gov (United States)

    Ma, Ze; Pei, Pucheng; Wang, Keliang; Wang, Xizhong; Xu, Huachi; Liu, Yongfeng; peng, Guanlin

    2015-01-01

    The zinc air fuel cell (ZAFC) is a promising candidate for electrical energy storage and electric vehicle propulsion. However, its limited durability has become a major obstacle for its successful commercialization. In this study, 2-cell stacks, 25 cm² cells and three-electrode half-cells are constructed to experimentally investigate the degradation characteristics of the air cathode. The results of electrochemical tests reveal that the peak power density for the 25 cm2 cell with a new air cathode is 454 mW cm-2, which is twice as the value of the used air cathode. The electrochemical impedance analysis shows that both the charge transfer resistance and the mass transfer resistance of the used air cathodes have increased, suggesting that the catalyst surface area and gas diffusion coefficient have decreased significantly. Additionally, the microstructure and morphology of the catalytic layer (CL) and gas diffusion layer (GDL) are characterized by scanning electron microscopes (SEM). SEM results confirm that the micropores in CL and GDL of the used air cathode are seriously clogged, and many catalyst particles are lost. Therefore, the performance degradation is mainly due to the clogging of micropores and loss of catalyst particles. Furthermore, hypotheses of degradation mechanism and mitigation strategies for GDL and CL are discussed briefly.

  3. Air Breathing Direct Methanol Fuel Cell

    Science.gov (United States)

    Ren; Xiaoming

    2003-07-22

    A method for activating a membrane electrode assembly for a direct methanol fuel cell is disclosed. The method comprises operating the fuel cell with humidified hydrogen as the fuel followed by running the fuel cell with methanol as the fuel.

  4. Thermal regulator for fuel and air to a carburetor

    Energy Technology Data Exchange (ETDEWEB)

    Pallares-martinez, J.L.; Pallares-osorio, J.

    1982-11-02

    An apparatus for providing fuel of a predetermined temperature and at a predetermined fuel rate based on demand to a carburetor of an internal combustion engine comprising a temperature regulated air flow mixer valve, a cool air inlet to the valve, a warm air inlet to the valve, a thermal balancing chamber connected to the outlet of the valve including a fuel pressure control valve mounted thereon, an expansion chamber mounted on the thermal balancing chamber and a fuel metering valve mounted at the outlet of the thermal expansion chamber. The fuel metering valve is responsive to engine vacuum. The thermally-regulated air flow mixer valve is responsive to the mixture in the intake manifold, and mixes the cool air and warm air to produce a desired temperature in the thermal balancing chamber. The warm air inlet includes a heat exchanger mounted in the exhaust manifold of the engine for warming intake air.

  5. Air/fuel ratio control system having an evaporated fuel purging control arrangement

    Energy Technology Data Exchange (ETDEWEB)

    Hasegawa, S.; Narasaka, S.; Otsuka, K.

    1983-03-22

    An air/fuel ratio control system for performing feedback control of the air/fuel ratio of an air/fuel mixture being supplied to an internal combustion engine. The air/fuel ratio control system is provided with an evaporated fuel purging control arrangement which is adapted to use an engine cooling water temperature sensor as an engine temperature sensor for control of purging of evaporated fuel from a canister to a venturi of the engine. At the same time, the above sensor is used for detection of various engine operating conditions for control of the air/fuel ratio of the mixture and adapted to produce an output continuously variable with a change in the temperature of engine coolant. The preclusion of the use of a special temperature sensor simplifies the structure of the evaporated fuel purging arrangement.

  6. Air Force Achieves Fuel Efficiency through Industry Best Practices

    Energy Technology Data Exchange (ETDEWEB)

    None

    2012-12-01

    The U.S. Air Force’s Air Mobility Command (AMC) is changing the way it does business. It is saving energy and money through an aircraft fleet fuel-efficiency program inspired by private industry best practices and ideas resulting from the empowered fuel savings culture.

  7. Planar near-nozzle velocity measurements during a single high-pressure fuel injection

    Science.gov (United States)

    Schlüßler, Raimund; Gürtler, Johannes; Czarske, Jürgen; Fischer, Andreas

    2015-09-01

    In order to reduce the fuel consumption and exhaust emissions of modern Diesel engines, the high-pressure fuel injections have to be optimized. This requires continuous, time-resolved measurements of the fuel velocity distribution during multiple complete injection cycles, which can provide a deeper understanding of the injection process. However, fuel velocity measurements at high-pressure injection nozzles are a challenging task due to the high velocities of up to 300 m/s, the short injection durations in the range and the high fuel droplet density especially near the nozzle exit. In order to solve these challenges, a fast imaging Doppler global velocimeter with laser frequency modulation (2D-FM-DGV) incorporating a high-speed camera is presented. As a result, continuous planar velocity field measurements are performed with a measurement rate of 200 kHz in the near-nozzle region of a high-pressure Diesel injection. The injection system is operated under atmospheric surrounding conditions with injection pressures up to 1400 bar thereby reaching fuel velocities up to 380 m/s. The measurements over multiple entire injection cycles resolved the spatio-temporal fluctuations of the fuel velocity, which occur especially for low injection pressures. Furthermore, a sudden setback of the velocity at the beginning of the injection is identified for various injection pressures. In conclusion, the fast measurement system enables the investigation of the complete temporal behavior of single injection cycles or a series of it. Since this eliminates the necessity of phase-locked measurements, the proposed measurement approach provides new insights for the analysis of high-pressure injections regarding unsteady phenomena.

  8. Study on the Effect of Air Throttling on Flame Stabilization of an Ethylene Fueled Scramjet Combustor

    Directory of Open Access Journals (Sweden)

    Ye Tian

    2015-01-01

    Full Text Available The effect of air throttling on flame stabilization of an ethylene fueled scramjet combustor was investigated by numerical simulation and experiments in this paper. The results were obtained under the inflow condition with Mach number of 2.0, total temperature of 900 K, total pressure of 0.8 MPa, and total equivalence ratio of 0.5. The shock train generated by air throttling had a big effect on the flow structure of the scramjet combustor. Compared with the combustor without air throttling, the flow field with air throttling had a lower velocity and higher pressure, temperature, and vortices intensity. Air throttling was an effective way to achieve flame stabilization; the combustion in the combustor without air throttling was nearly blowout. In the experiment, the combustion was nearly blowout with air throttling location of 745 mm, and the fuel/air mixture in the combustor with air throttling location of 875 mm was burned intensively. It was important to choose the location and time sequence of air throttling for fuel ignition and flame stabilization. The numerical simulation results agreed well with experimental measurements.

  9. Annular feed air breathing fuel cell stack

    Science.gov (United States)

    Wilson, Mahlon S.

    1996-01-01

    A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

  10. Effect of Intake Air Filter Condition on Vehicle Fuel Economy

    Energy Technology Data Exchange (ETDEWEB)

    Norman, Kevin M [ORNL; Huff, Shean P [ORNL; West, Brian H [ORNL

    2009-02-01

    The U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy and the U.S. Environmental Protection Agency (EPA) jointly maintain a fuel economy website (www.fueleconomy.gov), which helps fulfill their responsibility under the Energy Policy Act of 1992 to provide accurate fuel economy information [in miles per gallon (mpg)] to consumers. The site provides information on EPA fuel economy ratings for passenger cars and light trucks from 1985 to the present and other relevant information related to energy use such as alternative fuels and driving and vehicle maintenance tips. In recent years, fluctuations in the price of crude oil and corresponding fluctuations in the price of gasoline and diesel fuels have renewed interest in vehicle fuel economy in the United States. (User sessions on the fuel economy website exceeded 20 million in 2008 compared to less than 5 million in 2004 and less than 1 million in 2001.) As a result of this renewed interest and the age of some of the references cited in the tips section of the website, DOE authorized the Oak Ridge National Laboratory (ORNL) Fuels, Engines, and Emissions Research Center (FEERC) to initiate studies to validate and improve these tips. This report documents a study aimed specifically at the effect of engine air filter condition on fuel economy. The goal of this study was to explore the effects of a clogged air filter on the fuel economy of vehicles operating over prescribed test cycles. Three newer vehicles (a 2007 Buick Lucerne, a 2006 Dodge Charger, and a 2003 Toyota Camry) and an older carbureted vehicle were tested. Results show that clogging the air filter has no significant effect on the fuel economy of the newer vehicles (all fuel injected with closed-loop control and one equipped with MDS). The engine control systems were able to maintain the desired AFR regardless of intake restrictions, and therefore fuel consumption was not increased. The carbureted engine did show a decrease in

  11. Annular feed air breathing fuel cell stack

    Science.gov (United States)

    Wilson, Mahlon S.; Neutzler, Jay K.

    1997-01-01

    A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. The fuel distribution manifold is formed from a hydrophilic-like material to redistribute water produced by fuel and oxygen reacting at the cathode. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

  12. Investigation of the impact of imposed air inlet velocity oscillations on the formation and oxidation of soot using simultaneous 2-Colour-TIRE-LII

    Science.gov (United States)

    Aleksandrov, A.; Suntz, R.; Bockhorn, H.

    2015-05-01

    The response of non-premixed swirling flames to acoustic perturbations at various frequencies (0-350 Hz) and the impact of imposed air inlet velocity oscillations on the formation and oxidation of soot are investigated. The results obtained from these flames are of special interest for "rich-quenched-lean" (RQL) combustion concepts applied in modern gas turbines. In RQL combustion, the fuel is initially oxidized by air under fuel-rich conditions in a first stage followed by a fuel-lean combustion step in a second stage. To mimic soot formation and oxidation in RQL combustion, soot particle measurements in highly turbulent, non-premixed swirling natural gas/ethylene-confined flames at imposed air inlet velocity oscillations are performed using simultaneous 2-Colour-Time-Resolved-Laser-Induced Incandescence (simultaneous 2-Colour-TIRE-LII). The latter technique is combined with line-of-sight averaged OH*-chemiluminescence imaging, measurements of the velocity field by high-speed particle imaging velocimetry under reactive combustion conditions and measurements of the mean temperature field obtained by a thermocouple. A natural gas/ethylene mixture (Φ = 1.56, 42 % C2H4, 58 % natural gas, P th = 17.6 kW at atmospheric pressure) is used as a fuel, which is oxidized by air under fuel-rich conditions in the first combustion chamber.

  13. Planar solid oxide fuel cell with staged indirect-internal air and fuel preheating and reformation

    Science.gov (United States)

    Geisbrecht, Rodney A; Williams, Mark C

    2003-10-21

    A solid oxide fuel cell arrangement and method of use that provides internal preheating of both fuel and air in order to maintain the optimum operating temperature for the production of energy. The internal preheat passes are created by the addition of two plates, one on either side of the bipolar plate, such that these plates create additional passes through the fuel cell. This internal preheat fuel cell configuration and method reduce the requirements for external heat exchanger units and air compressors. Air or fuel may be added to the fuel cell as required to maintain the optimum operating temperature through a cathode control valve or an anode control valve, respectively. A control loop comprises a temperature sensing means within the preheat air and fuel passes, a means to compare the measured temperature to a set point temperature and a determination based on the comparison as to whether the control valves should allow additional air or fuel into the preheat or bypass manifolds of the fuel cell.

  14. Air/fuel supply system for use in a gas turbine engine

    Science.gov (United States)

    Fox, Timothy A; Schilp, Reinhard; Gambacorta, Domenico

    2014-06-17

    A fuel injector for use in a gas turbine engine combustor assembly. The fuel injector includes a main body and a fuel supply structure. The main body has an inlet end and an outlet end and defines a longitudinal axis extending between the outlet and inlet ends. The main body comprises a plurality of air/fuel passages extending therethrough, each air/fuel passage including an inlet that receives air from a source of air and an outlet. The fuel supply structure communicates with and supplies fuel to the air/fuel passages for providing an air/fuel mixture within each air/fuel passage. The air/fuel mixtures exit the main body through respective air/fuel passage outlets.

  15. DIRECT AMMONIA-AIR FUEL CELL.

    Science.gov (United States)

    A new type of direct oxidation ammonia fuel cell was investigated. This cell is based on the use of a non-aqueous fused hydroxide electrolyte matrix...EMF’s of 0.5 to 0.6 volts. At practical levels of current density the direct ammonia fuel cell has an overall efficiency of about 60% compared to 30-35% for the indirect-type fuel cell . (Author)

  16. Fuel Reduction for the Mobility Air Forces

    Science.gov (United States)

    2015-01-01

    with energy use within DoD. RAND Project AIR FORCE RAND Project AIR FORCE ( PAF ), a division of the RAND Corporation, is the U.S. Air Force’s federally...funded research and development center for studies and analyses. PAF provides the Air Force with independent analyses of policy alternatives...reported here was prepared under contract FA7014-06-C-0001. Additional information about PAF is available on our website: http://www.rand.org/ paf / v

  17. The Effect of Air Velocity on the Prevention of Heat Stress in Iranian Veiled Females

    Directory of Open Access Journals (Sweden)

    Habibi

    2016-09-01

    Full Text Available Background Some environmental factors such as the ambient temperature, radiant temperature, humidity and air velocity as well as clothing and activity level are effective to induce heat strain on the workers. Objectives The current study aimed to evaluate the effect of air velocity on Iranian veiled females at various exercise intensities and climatic conditions. Methods The current experimental study was conducted on 51 healthy veiled females with Islamic clothing (n = 30 in two hot-dry climatic chambers (wet-bulb globe temperature (WBGT = 32 ± 0.1°C and WBGT = 30 ± 0.1°C, 40% relative humidity (RH without air velocity and (n = 21 with air velocity 0.31 m/s in sitting and light workload conditions, respectively, for 60 minutes. The WBGT, oral temperature and heart rate were measured simultaneously every five minutes during the heat exposure and resting state. Data were analyzed using correlation and line regression by SPSS ver. 16. Results In both groups, oral temperature and heart rate increased during heat exposure. The increase of oral temperature and heart rate were larger in the group with air velocity (sitting position, 37.05 ± 0.20°C, 98.30 ± 7.79 bpm, light workload, 37.34 ± 0.24°C, 124.08 ± 6.09 bpm compared those of the group without air velocity (sitting position, 36.70 ± 0.36°C, 69.74 ± 0.98 bpm, light workload, 36.71 ± 0.27°C, 110.78 ± 17.9 bpm. The difference in physiological strain index (PSI between resting and low workload were higher in with air velocity group than those of the group without air velocity. Conclusions The results showed that the heat stress increased by increasing air velocity and humidity in both groups. The air velocity with high humidity can be considered as a positive factor in the occurrence of heat strain. Therefore, the incidence of heat stress decreases with the increase of humidity and reduction of air velocity or with increase of air velocity and reduction of humidity in Iranian veiled

  18. CFD Simulation of Air Velocity Distribution in Occupied Livestock Buildings

    DEFF Research Database (Denmark)

    Svidt, Kjeld; Zhang, G.; Bjerg, B.

    In modem livestock buildings the design of the ventilation systems is important in order to obtain good air distribution. The use of Computational Fluid Dynamics for predicting the air flow and air quality makes it possible to include the effect of room geometry, equipment and occupants in the de....... In this study laboratory measurements in a ventilated test room with "pig simulators" are compared with CFD-simulations....

  19. Air/fuel ratio control system and method for fuel vapor purging

    Energy Technology Data Exchange (ETDEWEB)

    Davenport, M.F.; Orzel, D.V.; Hamburg, D.R.

    1991-09-17

    This patent describes a control system for a vehicle having a fuel vapor recovery system coupled between a fuel supply system and an intake manifold of an internal combustion engine. It comprises an exhaust gas oxygen sensor coupled to the engine exhaust providing a rich output indication when engine exhaust gases are richer than a predetermined value and providing a lean output indication when the engine exhaust gases are leaner than the predetermined value; purging means coupled to the fuel supply system and the fuel vapor recovery system for purging a vapor mixture of fuel vapor and purged air into the engine air/fuel intake; and purge control means for increasing flow rate of the purged vapor mixture by a predetermined amount when the exhaust gas oxygen sensor changes from the rich output indication to the lean output indication.

  20. Progress of air-breathing cathode in microbial fuel cells

    Science.gov (United States)

    Wang, Zejie; Mahadevan, Gurumurthy Dummi; Wu, Yicheng; Zhao, Feng

    2017-07-01

    Microbial fuel cell (MFC) is an emerging technology to produce green energy and vanquish the effects of environmental contaminants. Cathodic reactions are vital for high electrical power density generated from MFCs. Recently tremendous attentions were paid towards developing high performance air-breathing cathodes. A typical air-breathing cathode comprises of electrode substrate, catalyst layer, and air-diffusion layer. Prior researches demonstrated that each component influenced the performance of air-breathing cathode MFCs. This review summarized the progress in development of the individual component and elaborated main factors to the performance of air-breathing cathode.

  1. The Effects of Air Preheating and Fuel/Air Inlet Diameter on the Characteristics of Vortex Flame

    Directory of Open Access Journals (Sweden)

    Mostafa Khaleghi

    2015-01-01

    Full Text Available The effects of fuel/air inlet diameter as well as air preheating on the flame stability, temperature distribution, pollutant formation, and combustion characteristics of a lab-scaled asymmetric vortex flame have been investigated. A three-dimensional steady-state finite volume solver has been used to solve the governing and energy equations. The solver uses a first-order upwind scheme to discretize the governing equations in the space. The semi-implicit method for pressure linked equations has been applied to couple the pressure to the velocity terms. Several turbulence models were applied to predict the flame temperature and it was found that k-ε RNG has given the best results in accordance with the experimental results. The results reveal that the inlet air diameter can enhance the thermal properties and reduce the NOx emission while the inlet fuel diameter has less significant impact. Increasing diameters are accompanied with a pressure drop. It was found that preheating the air and fuel would significantly affect the flame temperature and NOx emission with constant mass flow rate.

  2. Modelling of the combustion velocity in UIT-85 on sustainable alternative gas fuel

    Science.gov (United States)

    Smolenskaya, N. M.; Korneev, N. V.

    2017-05-01

    The flame propagation velocity is one of the determining parameters characterizing the intensity of combustion process in the cylinder of an engine with spark ignition. Strengthening of requirements for toxicity and efficiency of the ICE contributes to gradual transition to sustainable alternative fuels, which include the mixture of natural gas with hydrogen. Currently, studies of conditions and regularities of combustion of this fuel to improve efficiency of its application are carried out in many countries. Therefore, the work is devoted to modeling the average propagation velocities of natural gas flame front laced with hydrogen to 15% by weight of the fuel, and determining the possibility of assessing the heat release characteristics on the average velocities of the flame front propagation in the primary and secondary phases of combustion. Experimental studies, conducted the on single cylinder universal installation UIT-85, showed the presence of relationship of the heat release characteristics with the parameters of the flame front propagation. Based on the analysis of experimental data, the empirical dependences for determination of average velocities of flame front propagation in the first and main phases of combustion, taking into account the change in various parameters of engine operation with spark ignition, were obtained. The obtained results allow to determine the characteristics of heat dissipation and to assess the impact of addition of hydrogen to the natural gas combustion process, that is needed to identify ways of improvement of the combustion process efficiency, including when you change the throttling parameters.

  3. Computational Analysis of Mixing and Transport of Air and Fuel in Co-Fired Combustor

    Directory of Open Access Journals (Sweden)

    Javaid Iqbal

    2015-01-01

    Full Text Available Computational analysis for air fuel mixing and transport in a combustor used for co fired burner has been done by RANS (Reynolds-Averaged Navier?Stokes model comparing with 3D (Three Dimensional LES (Large Eddy Simulation. To investigate the better turbulence level and mixing within co fired combustor using the solid fuel biomass with coal is main purpose of this research work. The results show the difference in flow predicted by the two models, LES give better results than the RANS. For compressible flow the LES results show more swirling effect, The velocity decays along axial and radial distance for both swirling and non-swirling jet. Because of no slip condition near boundary the near the wall velocity is about zero

  4. Air/fuel ratio visualization in a diesel spray

    Science.gov (United States)

    Carabell, Kevin David

    1993-01-01

    To investigate some features of high pressure diesel spray ignition, we have applied a newly developed planar imaging system to a spray in an engine-fed combustion bomb. The bomb is designed to give flow characteristics similar to those in a direct injection diesel engine yet provide nearly unlimited optical access. A high pressure electronic unit injector system with on-line manually adjustable main and pilot injection features was used. The primary scalar of interest was the local air/fuel ratio, particularly near the spray plumes. To make this measurement quantitative, we have developed a calibration LIF technique. The development of this technique is the key contribution of this dissertation. The air/fuel ratio measurement was made using biacetyl as a seed in the air inlet to the engine. When probed by a tripled Nd:YAG laser the biacetyl fluoresces, with a signal proportional to the local biacetyl concentration. This feature of biacetyl enables the fluorescent signal to be used as as indicator of local fuel vapor concentration. The biacetyl partial pressure was carefully controlled, enabling estimates of the local concentration of air and the approximate local stoichiometry in the fuel spray. The results indicate that the image quality generated with this method is sufficient for generating air/fuel ratio contours. The processes during the ignition delay have a marked effect on ignition and the subsequent burn. These processes, vaporization and pre-flame kinetics, very much depend on the mixing of the air and fuel. This study has shown that poor mixing and over-mixing of the air and fuel will directly affect the type of ignition. An optimal mixing arrangement exists and depends on the swirl ratio in the engine, the number of holes in the fuel injector and the distribution of fuel into a pilot and main injection. If a short delay and a diffusion burn is desired, the best mixing parameters among those surveyed would be a high swirl ratio, a 4-hole nozzle and a

  5. Computational fluid dynamics analysis of a wire-feed, high-velocity oxygen fuel (HVOF) thermal spray torch

    Science.gov (United States)

    Lopez, A. R.; Hassan, B.; Oberkampf, W. L.; Neiser, R. A.; Roemer, T. J.

    1998-09-01

    The fluid and particle dynamics of a high-velocity oxygen fuel (HVOF) thermal spray torch are analyzed using computational and experimental techniques. Three-dimensional computational fluid dynamics (CFD) results are presented for a curved aircap used for coating interior surfaces such as engine cylinder bores. The device analyzed is similar to the Metco diamond jet rotating wire (DJRW) torch. The feed gases are injected through an axisymmetric nozzle into the curved aircap. Premixed propylene and oxygen are introduced from an annulus in the nozzle, while cooling air is injected between the nozzle and the interior wall of the aircap. The combustion process is modeled using a single-step, finite-rate chemistry model with a total of nine gas species which includes dissociation of combustion products. A continually fed steel wire passes through the center of the nozzle, and melting occurs at a conical tip near the exit of the aircap. Wire melting is simulated computationally by injecting liquid steel particles into the flow field near the tip of the wire. Experimental particle velocity measurements during wire feed were also taken using a laser two-focus (L2F) velocimeter system. Flow fields inside and outside the aircap are presented, and particle velocity predictions are compared with experimental measurements outside of the aircap.

  6. Air quality effects of alternative fuels. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Guthrie, P.; Ligocki, M.; Looker, R.; Cohen, J.

    1997-11-01

    To support the Alternative Fuels Utilization Program, a comparison of potential air quality effects of alternative transportation fuels is being performed. This report presents the results of Phase 1 of this program, focusing on reformulated gasoline (RFG), methanol blended with 15 percent gasoline (M85), and compressed natural gas (CNG). The fuels are compared in terms of effects on simulated future concentrations of ozone and mobile source air toxics in a photochemical grid model. The fuel comparisons were carried out for the future year 2020 and assumed complete replacement of gasoline in the projected light-duty gasoline fleet by each of the candidate fuels. The model simulations were carried out for the areas surrounding Los Angeles and Baltimore/DC, and other (non-mobile) sources of atmospheric emissions were projected according to published estimates of economic and population growth, and planned emission control measures specific to each modeling domain. The future-year results are compared to a future-year run with all gasoline vehicle emissions removed. The results of the comparison indicate that the use of M85 is likely to produce similar ozone and air toxics levels as those projected from the use of RFG. Substitution of CNG is projected to produce significantly lower levels of ozone and the mobile source air toxics than those projected for RFG or M85. The relative benefits of CNG substitution are consistent in both modeling domains. The projection methodologies used for the comparison are subject to a large uncertainty, and modeled concentration distributions depend on meteorological conditions. The quantitative comparison of fuel effects is thus likely to be sensitive to alternative assumptions. The consistency of the results for two very different modeling domains, using very different base assumptions, lends credibility to the qualitative differentiation among these fuels. 32 refs., 42 figs., 47 tabs.

  7. The Influence of Furniture on Air Velocity in a Room

    DEFF Research Database (Denmark)

    Nielsen, J. R.; Nielsen, Peter V.; Svidt, Kjeld

    Using isothermal full-scale experiments and 3-dimensional CFD simulations it is investigated how normal office furniture influences the air movements in a mixing ventilated room. Two different types of inlets are used in the experiments and a set-up with normal office furniture is made. The set......-up is simulated with one of the inlets where a volume resistance represents the furniture....

  8. Combustion Velocity of Benzine-Benzol-Air Mixtures in High-Speed Internal-Combustion Engines

    Science.gov (United States)

    Schnauffer, Kurt

    1932-01-01

    The present paper describes a device whereby rapid flame movement within an internal-combustion engine cylinder may be recorded and determined. By the aid of a simple cylindrical contact and an oscillograph the rate of combustion within the cylinder of an airplane engine during its normal operation may be measured for gas intake velocities of from 30 to 35 m/s and for velocities within the cylinder of from 20 to 25 m/s. With it the influence of mixture ratios, of turbulence, of compression ratio and kind of fuel on combustion velocity may be determined. Besides the determination of the influence of the above factors on combustion velocity, the degree of turbulence may also be determined. As a unit of reference in estimating the degree of turbulence, the intake velocity of the charge is chosen.

  9. Modeling and Analysis of Aluminum/Air Fuel Cell

    Science.gov (United States)

    Leon, Armando J.

    The technical and scientific challenges to provide reliable sources energy for US and global economy are enormous tasks, and especially so when combined with strategic and recent economic concerns of the last five years. It is clear that as part of the mix of energy sources necessary to deal with these challenges, fuel cells technology will play critical or even a central role. The US Department of Energy, as well as a number of the national laboratories and academic institutions have been aware of the importance such technology for some time. Recently, car manufacturers, transportation experts, and even utilities are paying attention to this vital source of energy for the future. In this thesis, a review of the main fuel cell technologies is presented with the focus on the modeling, and control of one particular and promising fuel cell technology, aluminum air fuel cells. The basic principles of this fuel cell technology are presented. A major part of the study consists of a description of the electrochemistry of the process, modeling, and simulations of aluminum air FC using Matlab Simulink(TM). The controller design of the proposed model is also presented. In sequel, a power management unit is designed and analyzed as an alternative source of power. Thus, the system commutes between the fuel cell output and the alternative power source in order to fulfill a changing power load demand. Finally, a cost analysis and assessment of this technology for portable devices, conclusions and future recommendations are presented.

  10. Polymer electrolyte fuel cells: flow field for efficient air operation

    Energy Technology Data Exchange (ETDEWEB)

    Buechi, F.N.; Tsukada, A.; Haas, O.; Scherer, G.G. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    A new flow field was designed for a polymer electrolyte fuel cell stack with an active area of 200 cm{sup 2} for operation at low air stoichiometry and low air over pressure. Optimum of gas flow and channel dimensions were calculated based on the required pressure drop in the fluid. Single cells and a bi-cell stack with the new flow field show an improved current/voltage characteristic when operated at low air stoichiometries as compared to that of the previous non optimized design. (author) 4 figs., 3 refs.

  11. Computational modeling of alkaline air-breathing microfluidic fuel cells with an array of cylinder anodes

    Science.gov (United States)

    Ye, Ding-Ding; Zhang, Biao; Zhu, Xun; Sui, Pang-Chieh; Djilali, Ned; Liao, Qiang

    2015-08-01

    A three-dimensional computational model is developed for an alkaline air-breathing microfluidic fuel cell (AMFC) with an array of cylinder anodes. The model is validated against experimental data from an in-house prototype AMFC. The distributions of fluid velocity, fuel concentration and current density of the fuel cell are analyzed in detail. The effect of reactant flow rate on the cell performance and electrode potentials is also studied. The model results suggest that fuel crossover is minimized by the fast electrolyte flow in the vicinity of the cathode. The current production of each anode is uneven and is well correlated with internal ohmic resistance. Fuel transfer limitation occurs at low flow rates (<100 μL min-1) but diminishes at high flow rates. The model results also indicate that cathode potential reversal takes place at combined low flow rate and high current density conditions, mainly due to the improved overpotential downstream where fuel starvation occurs. The anode reaction current distribution is found to be relatively uniform, which is a result of a compensating mechanism that improves the current production of the bottom anodes downstream.

  12. The Effect of Temperature and Air Velocity on Drying Kinetics of Pistachio Nuts during Roasting by using Hot Air Flow

    Directory of Open Access Journals (Sweden)

    A Dini

    2017-10-01

    Full Text Available Introduction Pistachio nut is one of the most delicious and nutritious nuts in the world and it is being used as a saltedand roasted product or as an ingredient in snacks, ice cream, desserts, etc. The purpose of roasting is to promote flavour and texture changes in nuts that ultimately increase the overall palatability of the product.Roasting involves a number of physico-chemical changes, including heat exchange, chemical reactions and drying. Knowledge of desorption kinetics is essential to predict the behavior of the material during roasting process and to design roaster equipment.The main aim of this research was to evaluate suitable models for predicting moisture ratio, the effect of air temperature and velocity on the drying kinetics of pistachio nuts and obtain the effective diffusivity coefficient and activation energy in the drying process during the roasting of pistachio nuts. Materials and Methods Dried Ahmadaghaei pistachio nuts were supplied from Kashefan Kavir company (Doraj co. in Rafsanjan. Pistachio nuts were soaked in 17% salt solution for 8 minute and roasting was investigated at air temperatures of 120,130, 145, 160 and 170 °C and air velocities of 0.6, 0.88, 1.3, 1.72 and 2 ms-1. Five semi-theoretical and two empirical kinetic models were fitted to drying experimental data using nonlinear regression analysis techniques in the Curve Expert 2.2 computer program. Results and Discussion Tow-way ANOVA indicated that temperature and hot air velocity significantly affected the drying process during roasting of shelled pistachio nuts. The higher roasting temperatures and air velocities resulted in the higher drying rates. During first 10 min of roasting at constant air velocity of 1.3 ms-1, 64.5%, 70.3%, 77.1%, 83.5%, 89.7% of the moisture were removed at roasting air temperatures of 120 °C, 130 °C, 145 °C, 160 °C, 170 °C, respectively. The high regression coefficients (R2>0.996 and low reduced chi-square (χ2, mean relative

  13. Air Shipment of Spent Nuclear Fuel from Romania to Russia

    Energy Technology Data Exchange (ETDEWEB)

    Igor Bolshinsky; Ken Allen; Lucian Biro; Alexander Buchelnikov

    2010-10-01

    Romania successfully completed the world’s first air shipment of spent nuclear fuel transported in Type B(U) casks under existing international laws and without shipment license special exceptions when the last Romanian highly enriched uranium (HEU) spent nuclear fuel was transported to the Russian Federation in June 2009. This air shipment required the design, fabrication, and licensing of special 20 foot freight containers and cask tiedown supports to transport the eighteen TUK 19 shipping casks on a Russian commercial cargo aircraft. The new equipment was certified for transport by road, rail, water, and air to provide multi modal transport capabilities for shipping research reactor spent fuel. The equipment design, safety analyses, and fabrication were performed in the Russian Federation and transport licenses were issued by both the Russian and Romanian regulatory authorities. The spent fuel was transported by truck from the VVR S research reactor to the Bucharest airport, flown by commercial cargo aircraft to the airport at Yekaterinburg, Russia, and then transported by truck to the final destination in a secure nuclear facility at Chelyabinsk, Russia. This shipment of 23.7 kg of HEU was coordinated by the Russian Research Reactor Fuel Return Program (RRRFR), as part of the U.S. Department of Energy Global Threat Reduction Initiative (GTRI), in close cooperation with the Rosatom State Atomic Energy Corporation and the International Atomic Energy Agency, and was managed in Romania by the National Commission for Nuclear Activities Control (CNCAN). This paper describes the planning, shipment preparations, equipment design, and license approvals that resulted in the safe and secure air shipment of this spent nuclear fuel.

  14. Ground measurements of fuel and fuel consumption from experimental and operational prescribed fires at Eglin Air Force Base, Florida

    Science.gov (United States)

    Roger D. Ottmar; Robert E. Vihnanek; Clinton S. Wright; Andrew T. Hudak

    2014-01-01

    Ground-level measurements of fuel loading, fuel consumption, and fuel moisture content were collected on nine research burns conducted at Eglin Air Force Base, Florida in November, 2012. A grass or grass-shrub fuelbed dominated eight of the research blocks; the ninth was a managed longleaf pine (Pinus palustrus) forest. Fuel loading ranged from 1.7 Mg ha-1 on a...

  15. Unsteady Extinction of Opposed Jet Ethylene/Methane HIFiRE Surrogate Fuel Mixtures vs Air

    Science.gov (United States)

    Vaden, Sarah N.; Debes, Rachel L.; Lash, E. Lara; Burk, Rachel S.; Boyd, C. Merritt; Wilson, Lloyd G.; Pellett, Gerald L.

    2009-01-01

    A unique idealized study of the subject fuel vs. air systems was conducted using an Oscillatory-input Opposed Jet Burner (OOJB) system and a newly refined analysis. Extensive dynamic-extinction measurements were obtained on unanchored (free-floating) laminar Counter Flow Diffusion Flames (CFDFs) at 1-atm, stabilized by steady input velocities (e.g., U(sub air)) and perturbed by superimposed in-phase sinusoidal velocity inputs at fuel and air nozzle exits. Ethylene (C2H4) and methane (CH4), and intermediate 64/36 and 15/85 molar percent mixtures were studied. The latter gaseous surrogates were chosen earlier to mimic ignition and respective steady Flame Strengths (FS = U(sub air)) of vaporized and cracked, and un-cracked, JP-7 "like" kerosene for a Hypersonic International Flight Research Experimentation (HIFiRE) scramjet. For steady idealized flameholding, the 100% C2H4 flame is respectively approx. 1.3 and approx.2.7 times stronger than a 64/36 mix and CH4; but is still 12.0 times weaker than a 100% H2-air flame. Limited Hot-Wire (HW) measurements of velocity oscillations at convergent-nozzle exits, and more extensive Probe Microphone (PM) measurements of acoustic pressures, were used to normalize Dynamic FSs, which decayed linearly with pk/pk U(sub air) (velocity magnitude, HW), and also pk/pk P (pressure magnitude, PM). Thus Dynamic Flame Weakening (DFW) is defined as % decrease in FS per Pascal of pk/pk P oscillation, namely, DFW = -100 d(U(sub air)/U(sub air),0Hz)/d(pkpk P). Key findings are: (1) Ethylene flames are uniquely strong and resilient to extinction by oscillating inflows below 150 Hz; (2) Methane flames are uniquely weak; (3) Ethylene / methane surrogate flames are disproportionately strong with respect to ethylene content; and (4) Flame weakening is consistent with limited published results on forced unsteady CFDFs. Thus from 0 to approx. 10 Hz and slightly higher, lagging diffusive responses of key species led to progressive phase lags (relative

  16. Methanol/air fuel cells: catalytic aspects and experimental diagnostics

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, M.F.; Sieben, J.M.; Pilla, A.S.; Duarte, M.M.E.; Mayer, C.E. [Instituto de Ingenieria Electroquimica y Corrosion, Depto. de Ingenieria Quimica, Universidad Nacional del Sur, Av. Alem 1253, 8000 Bahia Blanca (Argentina)

    2008-07-15

    Methanol/air fuel cell with direct feed of methanol has received growing attention due to the possibility of using a liquid fuel of simple storing. This work comments studies on the preparation of PtRu catalysts for methanol oxidation and on the influence of different operative parameter on the performance of a lab scale fuel cell. The best conditions for PtRu catalysts preparation using metal electrodeposition techniques were found. Different carbon materials were used, such as glassy carbon, carbon paper and graphite fiber cloths and felts. The more active materials were found to be graphite felts after being preoxidized electrochemically to obtain a higher surface oxide concentration. Acceptable performance of the fuel cell was obtained working at 90 C and low methanol concentration, because in these conditions the potential, the transport process rates and the electrode reaction kinetics increase. (author)

  17. Performance Investigation of Air Velocity Effects on PV Modules under Controlled Conditions

    Directory of Open Access Journals (Sweden)

    Muzaffar Ali

    2017-01-01

    Full Text Available Junction temperature of PV modules is one of the key parameters on which the performance of PV modules depends. In the present work, an experimental investigation was carried out to analyze the effects of air velocity on the performance of two PV modules, that is, monocrystalline silicon and polycrystalline silicon under the controlled conditions of a wind tunnel in the presence of an artificial solar simulator. The parameters investigated include the surface temperature variation, power output, and efficiency of PV modules under varying air velocity from near zero (indoor lab. conditions to 15 m/s. Additionally, the results were also determined at two different module angular positions: at 0° angle, that is, parallel to air direction and at 10° angle with the direction of coming air to consider the effects of tilt angles. Afterwards, the thermal analysis of the modules was performed using Ansys-Fluent in which junction temperature and heat flux of modules were determined by applying appropriate boundary conditions, such as air velocity, heat flux, and solar radiation. Finally, the numerical results are compared with the experiment in terms of junction temperatures of modules and good agreement was found. Additionally, the results showed that the maximum module temperature drops by 17.2°C and the module efficiency and power output increased from 10 to 12% with increasing air velocity.

  18. Velocity Distribution in a Room Ventilated by Displacement Ventilation and Wall-Mounted Air Terminal Devices

    DEFF Research Database (Denmark)

    Nielsen, Peter Vilhelm

    2000-01-01

    The article describes experiments with wall-mounted air terminal devices. The airflow from an air terminal device influences the occupants' thermal comfort and, therefore, it is important to develop an expression for this flow in the occupied zone. The velocity at the floor is influenced...... by the flow rate to the room, the temperature difference and the type of diffuser. The flow is stratified at Archimedes numbers larger than four. The article gives expressions for the velocity distribution close to the floor. It is shown that openings between obstacles placed directly on the floor generate...

  19. Normal-Mode and Free-Air Gravity Constraints on Lateral Variations in Velocity and Density of Earth's Mantle

    National Research Council Canada - National Science Library

    Miaki Ishii; Jeroen Tromp

    1999-01-01

    With the use of a large collection of free-oscillation data and additional constraints imposed by the free-air gravity anomaly, lateral variations in shear velocity, compressional velocity, and density within the mantle...

  20. Production of Babbitt Coatings by High Velocity Oxygen Fuel (HVOF) Spraying

    Science.gov (United States)

    Nascimento, A. R. C.; Ettouil, F. B.; Moreau, C.; Savoie, S.; Schulz, R.

    2017-10-01

    This work presents HVOF as an alternative means to produce dense Babbitt coatings by thermal spray. A radial injection setup and low fuel flow rates were used to minimize heat transfer to the low melting point alloy. In-flight particle diagnostic systems were used to correlate spray parameters with the changes in particle velocity and thermal radiation intensity. The use of particles with larger diameters resulted in higher deposition efficiencies. It was shown that HVOF Babbitt coatings combine a dense structure and a fine distribution of intermetallic phases when compared to more traditional babbitting techniques.

  1. Elementary reaction models and correlations for burning velocities of multicomponent organic fuel mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Cho, S.; Niksa, S. [Stanford Univ., CA (United States). High Temperature Gasdynamics Lab.

    1995-06-01

    This computational study uses elementary reaction mechanisms to interpret the trends in a database of burning velocities for multicomponent organic fuel mixtures derived from coal. These mixtures contain CO, H{sub 2}, CH{sub 4}, C{sub 2}H{sub 2}, oils, and, in some cases, appreciable amounts of C{sub 2}H{sub 4}, C{sub 2}H{sub 6}, C{sub 3}H{sub 6} and C{sub 3}H{sub 8}. The database represents fuel equivalent ratios from 0.5 to 1.5, two unburned gas temperatures, and two diluent: O{sub 2} ratios. Predicted burning velocities are based on a one-dimensional laminar flame code with the Miller-Bowman mechanism without nitrogen conversion chemistry or oxidative pyrolysis of any higher hydrocarbons. The initial amounts of oils and higher hydrocarbons are expressed as additional amounts of C{sub 2}H{sub 4} and C{sub 2}H{sub 6} and reduced levels of H{sub 2}. Burning velocities of multicomponent fuel mixtures at high temperatures can be interpreted with only oxyhydrogen and C{sub 1}/C{sub 2} chemistry without any fuel decomposition steps for the higher hydrocarbons. This approach rationalizes the trends due to higher extents of secondary volatiles pyrolysis, which means increasing CO and H{sub 2} levels and diminishing hydrocarbon levels in the fuel mixtures. It also rationalizes the variations with coals of higher rank, which means diminishing CO levels and H{sub 2} and hydrocarbon levels that pass through maxima. Predictions from the elementary reaction mechanism are quantitatively accurate for nearly all lean mixtures, but discrepancies are substantial for rich mixtures, especially those with abundant CO and H{sub 2}. Systematic overpredictions for rich mixtures are probably due to defects in steps for the attack of C{sub 1} or C{sub 2} species by O{sub 2} or H atoms.

  2. Experience of air transport of nuclear fuel material in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Yamashita, T.; Toguri, D. [Transnuclear, LTD. (AREVA group), Tokyo (Japan); Kawasaki, M. [Japan Nuclear Cycle Development Inst., Muramatsu, Ibaraki (Japan)

    2004-07-01

    Certified Reference Materials (hereafter called as to CRMs), which are indispensable for Quality Assurance and Material Accountability in nuclear fuel plants, are being provided by overseas suppliers to Japanese nuclear entities as Type A package (non-fissile) through air transport. However, after the criticality accident at JCO in Japan, special law defining nuclear disaster countermeasures (hereafter called as to the LAW) has been newly enforced in June 2000. Thereafter, nuclear fuel materials must meet not only to the existing transport regulations but also to the LAW for its transport.

  3. Higher fuel prices are associated with lower air pollution levels.

    Science.gov (United States)

    Barnett, Adrian G; Knibbs, Luke D

    2014-05-01

    Air pollution is a persistent problem in urban areas, and traffic emissions are a major cause of poor air quality. Policies to curb pollution levels often involve raising the price of using private vehicles, for example, congestion charges. We were interested in whether higher fuel prices were associated with decreased air pollution levels. We examined an association between diesel and petrol prices and four traffic-related pollutants in Brisbane from 2010 to 2013. We used a regression model and examined pollution levels up to 16 days after the price change. Higher diesel prices were associated with statistically significant short-term reductions in carbon monoxide and nitrogen oxides. Changes in petrol prices had no impact on air pollution. Raising diesel taxes in Australia could be justified as a public health measure. As raising taxes is politically unpopular, an alternative political approach would be to remove schemes that put a downward pressure on fuel prices, such as industry subsidies and shopping vouchers that give fuel discounts. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Apparatus and method for burning a lean, premixed fuel/air mixture with low NOx emission

    Science.gov (United States)

    Kostiuk, Larry W.; Cheng, Robert K.

    1996-01-01

    An apparatus for enabling a burner to stably burn a lean fuel/air mixture. The burner directs the lean fuel/air mixture in a stream. The apparatus comprises an annular flame stabilizer; and a device for mounting the flame stabilizer in the fuel/air mixture stream. The burner may include a body having an internal bore, in which case, the annular flame stabilizer is shaped to conform to the cross-sectional shape of the bore, is spaced from the bore by a distance greater than about 0.5 mm, and the mounting device mounts the flame stabilizer in the bore. An apparatus for burning a gaseous fuel with low NOx emissions comprises a device for premixing air with the fuel to provide a lean fuel/air mixture; a nozzle having an internal bore through which the lean fuel/air mixture passes in a stream; and a flame stabilizer mounted in the stream of the lean fuel/air mixture. The flame stabilizer may be mounted in the internal bore, in which case, it is shaped and is spaced from the bore as just described. In a method of burning a lean fuel/air mixture, a lean fuel/air mixture is provided, and is directed in a stream; an annular eddy is created in the stream of the lean fuel/air mixture; and the lean fuel/air mixture is ignited at the eddy.

  5. Storage of LWR spent fuel in air. Volume 3, Results from exposure of spent fuel to fluorine-contaminated air

    Energy Technology Data Exchange (ETDEWEB)

    Cunningham, M.E.; Thomas, L.E.

    1995-06-01

    The Behavior of Spent Fuel in Storage (BSFS) Project has conducted research to develop data on spent nuclear fuel (irradiated U0{sub 2}) that could be used to support design, licensing, and operation of dry storage installations. Test Series B conducted by the BSFS Project was designed as a long-term study of the oxidation of spent fuel exposed to air. It was discovered after the exposures were completed in September 1990 that the test specimens had been exposed to an atmosphere of bottled air contaminated with an unknown quantity of fluorine. This exposure resulted in the test specimens reacting with both the oxygen and the fluorine in the oven atmospheres. The apparent source of the fluorine was gamma radiation-induced chemical decomposition of the fluoro-elastomer gaskets used to seal the oven doors. This chemical decomposition apparently released hydrofluoric acid (HF) vapor into the oven atmospheres. Because the Test Series B specimens were exposed to a fluorine-contaminated oven atmosphere and reacted with the fluorine, it is recommended that the Test Series B data not be used to develop time-temperature limits for exposure of spent nuclear fuel to air. This report has been prepared to document Test Series B and present the collected data and observations.

  6. Numerical Simulation of Air Temperature and Velocity in a Naturally Ventilated Office

    Directory of Open Access Journals (Sweden)

    S. Shodiya

    2017-04-01

    Full Text Available This paper presents a numerical simulation of air velocity and air temperature distribution in an office room of Computer Engineering Department of University of Maiduguri which is naturally ventilated. The office room under investigation with the dimension 5 m × 5 m × 4 m has a door in the East direction, and two windows, one in the East direction and the other in the South direction. For cost effectiveness, numerical solutions of steady-state airflow and heat transfer were done using a complete two-dimensional model. The results showed that the windows and the door could not undertake indoor heat load that can make the occupants to be thermally comfortable. In activity area where people sit and stand, the air velocity is moderate, this is about 0.98 m/s on the average. In addition, the temperature in this area is relatively high of about 302 K (29 °C on the average. Based on the American Society of Heating, Refrigeration and Air-Conditioning Engineers (ASHRAE standard for comfort environment in summer (air temperature: 293 – 299 K (20 – 26 °C; air velocity: 0.5 – 0.8 m/s, the natural ventilation for the office room cannot give a thermal comfort for the inhabitant of the room. However, a window, if installed opposite the door could improve the ventilation of the office.

  7. The influence of air-fuel ratio on mixture parameters in port fuel injection engines

    Directory of Open Access Journals (Sweden)

    Adrian Irimescu

    2008-10-01

    Full Text Available Nowadays, research in the internal combustion engine field is focusing on detailed understanding of the processes that take place in certain parts of the aggregate, and can have a great influence on the engine’s performance and pollution levels. Such research is developed in this paper, in which using a numerical method based on the i-x air-fuel diagram, one can simulate a series of values for pressure, temperature and intake air humidity before and after mixture formation takes place in a spark ignition engine inlet port. The aim is to evaluate the final temperature of the air-fuel mixture near the inlet valve and evaluating the main factors of influence on the homogeneity of the mixture.

  8. 42 CFR 84.1139 - Air velocity and noise levels; hoods and helmets; minimum requirements.

    Science.gov (United States)

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Air velocity and noise levels; hoods and helmets; minimum requirements. 84.1139 Section 84.1139 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF...

  9. Radial variation of refractive index, plasma frequency and phase velocity in laser induced air plasma

    CSIR Research Space (South Africa)

    Mathuthu, M

    2006-12-01

    Full Text Available induced air plasma to study the spatial variation of plasma parameters in the axial direction of the laser beam. In this paper, the authors report investigation on the radial variation of the refractive index, plasma frequency, and phase velocity of a...

  10. Measurement and Numerical Simulation of Air Velocity in a Tunnel-Ventilated Broiler House

    Directory of Open Access Journals (Sweden)

    Eliseo Bustamante

    2015-02-01

    Full Text Available A building needs to be designed for the whole period of its useful life according to its requirements. However, future climate predictions involve some uncertainty. Thus, several sustainable strategies of adaptation need to be incorporated after the initial design. In this sense, tunnel ventilation in broiler houses provides high air velocity values (2–3 m·s−1 at animal level to diminish their thermal stress and associated mortality. This ventilation system was experimentally incorporated into a Mediterranean climate. The aim was to resolve these thermal problems in hot seasons, as (traditional cross-mechanical ventilation does not provide enough air velocity values. Surprisingly, very little information on tunnel ventilation systems is available, especially in terms of air velocity. Using Computational Fluid Dynamics (CFD and a multi-sensor system, the average results are similar (at animal level: 1.59 ± 0.68 m·s−1 for CFD and 1.55 ± 0.66 m·s−1 for measurements. The ANOVA for validation concluded that the use of CFD or measurements is not significant (p-value = 0.1155. Nevertheless, some problems with air velocity distribution were found and need to be solved. To this end, CFD techniques can help by means of virtual designs and scenarios providing information for the whole indoor space.

  11. Fuel-air mixing apparatus for reducing gas turbine combustor exhaust emissions

    Science.gov (United States)

    Zupanc, Frank J. (Inventor); Yankowich, Paul R. (Inventor)

    2006-01-01

    A fuel-air mixer for use in a combustion chamber of a gas turbine engine is provided. The fuel air mixing apparatus comprises an annular fuel injector having a plurality of discrete plain jet orifices, a first swirler wherein the first swirler is located upstream from the fuel injector and a second swirler wherein the second swirler is located downstream from the fuel injector. The plurality of discrete plain jet orifices are situated between the highly swirling airstreams generated by the two radial swirlers. The distributed injection of the fuel between two highly swirling airstreams results in rapid and effective mixing to the desired fuel-air ratio and prevents the formation of local hot spots in the combustor primary zone. A combustor and a gas turbine engine comprising the fuel-air mixer of the present invention are also provided as well as a method using the fuel-air mixer of the present invention.

  12. Numerical Simulation of Air Staged Mechanism Effect in a High Velocity Burner

    Directory of Open Access Journals (Sweden)

    Bernardo A. Herrera-Múnera

    2013-11-01

    Full Text Available In this work, staged air combustion in a high speed burner was analyzed by mean of numerical simulation in order to determine its effects on temperature distribution and pollutant chemical species formation such as CO and NOx. The simulations were achieved using the commercial software ANSYS FLUENT as a design tool to predict the behavior of the thermal system and to establish operation conditions with or without staged air. Eddy Dissipation model was used for combustion simulation, while k - ε Realizable and Discrete Ordinates models were utilized for turbulence and radiation simulation, respectively. Results show that staged air mechanism allows better flame stabilization, combustion reactions initiation and fuel-air mixing. The CO formation was different in reaction zone and NOx emissions were not significantly influenced by the staged air.

  13. Simultaneous velocity and pressure quantification using pressure-sensitive flow tracers in air

    Science.gov (United States)

    Zhang, Peng; Peterson, Sean; Porfiri, Maurizio

    2017-11-01

    Particle-based measurement techniques for assessing the velocity field of a fluid have advanced rapidly over the past two decades. Full-field pressure measurement techniques have remained elusive, however. In this work, we aim to demonstrate the possibility of direct simultaneous planar velocity and pressure measurement of a high speed aerodynamic flow by employing novel pressure-sensitive tracer particles for particle image velocimetry (PIV). Specifically, the velocity and pressure variations of an airflow through a converging-diverging channel are studied. Polystyrene microparticles embedded with a pressure-sensitive phosphorescent dye-platinum octaethylporphyrin (PtOEP)-are used as seeding particles. Due to the oxygen quenching effect, the emission lifetime of PtOEP is highly sensitive to the oxygen concentration, that is, the partial pressure of oxygen, in the air. Since the partial pressure of oxygen is linearly proportional to the air pressure, we can determine the air pressure through the phosphorescence emission lifetime of the dye. The velocity field is instead obtained using traditional PIV methods. The particles have a pressure resolution on the order of 1 kPa, which may be improved by optimizing the particle size and dye concentration to suit specific flow scenarios. This work was supported by the National Science Foundation under Grant Number CBET-1332204.

  14. Preferred Air Velocity and Local Cooling Effect of desk fans in warm environments

    DEFF Research Database (Denmark)

    Simone, Angela; Olesen, Bjarne W.

    2013-01-01

    , and the possibility to keep comfortable conditions for the occupants in warm environments were evaluated in studies with human subjects. In an office-like climatic chamber, the effect of higher air velocity was investigated at room temperatures between 26°C to 34°C and at constant absolute humidity of 12.2 g......Common experiences, standards, and laboratory studies show that increased air velocity helps to offset warm sensation due to high environmental temperatures. In warm climate regions the opening of windows and the use of desk or ceiling fans are the most common systems to generate increased airflows....../kg. By a thermal manikin the effect of direct air movement generated by a personal desk fan at 26 °C, 28 °C, or 30 °C room temperatures and the achievable thermal comfort was also analyzed. Results show that it is possible to offset warm sensation within a range of indoor conditions using increased air velocity...

  15. Microstructure Characterization of WCCo-Mo Based Coatings Produced Using High Velocity Oxygen Fuel

    Directory of Open Access Journals (Sweden)

    Serkan Islak

    2015-12-01

    Full Text Available The present study has been carried out in order to investigate the microstructural properties of WCCo-Mo composite coatings deposited onto a SAE 4140 steel substrate by high velocity oxygen fuel (HVOF thermal spray. For this purpose, the Mo quantity added to the WCCo was changed as 10, 20, 30 and 40 wt. % percents. The coatings are compared in terms of their phase composition, microstructure and hardness. Phase compound and microstructure of coating layers were examined using X-ray diffractometer (XRD and scanning electron microscope (SEM. XRD results showed that WCCo-Mo composite coatings were mainly composed of WC, W2C, Co3W3C, Mo2C, MoO2, Mo and Co phases. The average hardness of the coatings increased with increasing Mo content.

  16. Measurements of the laminar burning velocity of hydrogen-air premixed flames

    Energy Technology Data Exchange (ETDEWEB)

    Pareja, Jhon; Burbano, Hugo J. [Science and Technology of Gases and Rational Use of Energy Group, Faculty of Engineering, University of Antioquia, Calle 67 N 53, 108 Bloque 20, 447 Medellin (Colombia); Ogami, Yasuhiro [Institute of Fluid Science, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577 (Japan)

    2010-02-15

    Experimental and numerical studies on laminar burning velocities of hydrogen-air mixtures were performed at standard pressure and room temperature varying the equivalence ratio from 0.8 to 3.0. The flames were generated using a contoured slot-type nozzle burner (4 mm x 10 mm). Measurements of laminar burning velocity were conducted using particle tracking velocimetry (PTV) combined with Schlieren photography. This technique provides the information of instantaneous local burning velocities in the whole region of the flame front, and laminar burning velocities were determined using the mean value of local burning velocities in the region of non-stretch. Additionally, average laminar burning velocities were determined using the angle method and compared with the data obtained with the PTV method. Numerical calculations were also conducted using detailed reaction mechanisms and transport properties. The experimental results from the PTV method are in good agreement with the numerical results at every equivalence ratio of the range of study. Differences between the results obtained with the angle method and those with the PTV method are reasonably small when the effects of flame stretch and curvature are reduced by using a contoured slot-type nozzle. (author)

  17. Surface velocity divergence model of air/water interfacial gas transfer in open-channel flows

    Science.gov (United States)

    Sanjou, M.; Nezu, I.; Okamoto, T.

    2017-04-01

    Air/water interfacial gas transfer through a free surface plays a significant role in preserving and restoring water quality in creeks and rivers. However, direct measurements of the gas transfer velocity and reaeration coefficient are still difficult, and therefore a reliable prediction model needs to be developed. Varying systematically the bulk-mean velocity and water depth, laboratory flume experiments were conducted and we measured surface velocities and dissolved oxygen (DO) concentrations in open-channel flows to reveal the relationship between DO transfer velocity and surface divergence (SD). Horizontal particle image velocimetry measurements provide the time-variations of surface velocity divergence. Positive and negative regions of surface velocity divergence are transferred downstream in time, as occurs in boil phenomenon on natural river free-surfaces. The result implies that interfacial gas transfer is related to bottom-situated turbulence motion and vertical mass transfer. The original SD model focuses mainly on small-scale viscous motion, and this model strongly depends on the water depth. Therefore, we modify the SD model theoretically to accommodate the effects of the water depth on gas transfer, introducing a non-dimensional parameter that includes contributions of depth-scale large-vortex motion, such as secondary currents, to surface renewal events related to DO transport. The modified SD model proved effective and reasonable without any dependence on the bulk mean velocity and water depth, and has a larger coefficient of determination than the original SD model. Furthermore, modeling of friction velocity with the Reynolds number improves the practicality of a new formula that is expected to be used in studies of natural rivers.

  18. DENSITY AND VELOCITY MEASUREMENTS IN TURBULENT HE-AIR BOUNDARY LAYERS

    Directory of Open Access Journals (Sweden)

    A SOUDANI

    2003-06-01

    Full Text Available A turbulent  boundary layer with large density variations has been generated by tangential injection of air or helium Into a boundary layer of air-helium mixture. Instrumentation based on thermo- anemometry has been successfully developed for the investigation of this flow  Analysis or the mean and fluctuating density fields shows that the flow is mainly governed by the ratio of the injection to the external velocity and that the density ratio plays a secondary role in the mixing processes. However, a sight enhancement of turbulent activity is observed when helium is injected.

  19. Storage of LWR spent fuel in air: Volume 1: Design and operation of a spent fuel oxidation test facility

    Energy Technology Data Exchange (ETDEWEB)

    Thornhill, C.K.; Campbell, T.K.; Thornhill, R.E.

    1988-12-01

    This report describes the design and operation and technical accomplishments of a spent-fuel oxidation test facility at the Pacific Northwest Laboratory. The objective of the experiments conducted in this facility was to develop a data base for determining spent-fuel dry storage temperature limits by characterizing the oxidation behavior of light-water reactor (LWR) spent fuels in air. These data are needed to support licensing of dry storage in air as an alternative to spent-fuel storage in water pools. They are to be used to develop and validate predictive models of spent-fuel behavior during dry air storage in an Independent Spent Fuel Storage Installation (ISFSI). The present licensed alternative to pool storage of spent fuel is dry storage in an inert gas environment, which is called inerted dry storage (IDS). Licensed air storage, however, would not require monitoring for maintenance of an inert-gas environment (which IDS requires) but does require the development of allowable temperature limits below which UO/sub 2/ oxidation in breached fuel rods would not become a problem. Scoping tests at PNL with nonirradiated UO/sub 2/ pellets and spent-fuel fragment specimens identified the need for a statistically designed test matrix with test temperatures bounding anticipated maximum acceptable air-storage temperatures. This facility was designed and operated to satisfy that need. 7 refs.

  20. Determination of the integral characteristics of an asymmetrical thermal plume from air speed/velocity and temperature measurements

    DEFF Research Database (Denmark)

    Zukowska, Daria; Popiolek, Zbigniew; Melikov, Arsen Krikor

    2010-01-01

    A method, named the Approximate Distributions Integration Method (ADI-method), is proposed for calculation of parameters of the asymmetrical thermal plume above a heat source, such as maximum air temperature excess and velocity, their position in the plume cross-section, the widths of the tempera......A method, named the Approximate Distributions Integration Method (ADI-method), is proposed for calculation of parameters of the asymmetrical thermal plume above a heat source, such as maximum air temperature excess and velocity, their position in the plume cross-section, the widths...... of the temperature and velocity profiles, asymmetry parameters of the plume cross-section, and the integral characteristics. The method is based on an approximation of the measured profiles of air velocity and air temperature excess in the plume cross-section. A procedure for conversion of the air speed measured...... by omnidirectional sensors into air velocity is incorporated with the ADI-method. Experiments were performed in a climate chamber with air temperature of 23 _C, radiant temperature equal to the air temperature and upward airflow with velocity of less than 0.05 m/s. Air speed and temperature in a thermal plume...

  1. Flame holding tolerant fuel and air premixer for a gas turbine combustor

    Science.gov (United States)

    York, William David; Johnson, Thomas Edward; Ziminsky, Willy Steve

    2012-11-20

    A fuel nozzle with active cooling is provided. It includes an outer peripheral wall, a nozzle center body concentrically disposed within the outer wall in a fuel and air pre-mixture. The fuel and air pre-mixture includes an air inlet, a fuel inlet and a premixing passage defined between the outer wall in the center body. A gas fuel flow passage is provided. A first cooling passage is included within the center body in a second cooling passage is defined between the center body and the outer wall.

  2. Quantifying energy and mass transfer in crop canopies: sensors for measurement of temperature and air velocity

    Science.gov (United States)

    Bugbee, B.; Monje, O.; Tanner, B.

    1996-01-01

    Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.

  3. Development of air fuel ratio sensor; A/F sensor no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Sakawa, T.; Hori, M. [Denso Corp., Aichi (Japan); Nakamura, Y. [Toyota Motor Corp., Aichi (Japan)

    1997-10-01

    The Air Fuel Ratio Sensor (A/F sensor), which is applied to a 1997 model year Low Emission Vehicle (LEV) was developed. This sensor enables the detection of the exhaust gas air fuel ratio, both lean and rich of stoichiometric. It has an effective air fuel ratio range from 12 to 18 as required for LEV regulation. It has the fast light off, - within 20 seconds - to minimize exhaust hydrocarbon content. Further, it has fast response time, less than 200 msec, to improve the air fuel ratio controllability. 3 refs., 7 figs.

  4. Effect of aviation fuel type and fuel injection conditions on the spray characteristics of pressure swirl and hybrid air blast fuel injectors

    Science.gov (United States)

    Feddema, Rick

    Feddema, Rick T. M.S.M.E., Purdue University, December 2013. Effect of Aviation Fuel Type and Fuel Injection Conditions on the Spray Characteristics of Pressure Swirl and Hybrid Air Blast Fuel Injectors. Major Professor: Dr. Paul E. Sojka, School of Mechanical Engineering Spray performance of pressure swirl and hybrid air blast fuel injectors are central to combustion stability, combustor heat management, and pollutant formation in aviation gas turbine engines. Next generation aviation gas turbine engines will optimize spray atomization characteristics of the fuel injector in order to achieve engine efficiency and emissions requirements. Fuel injector spray atomization performance is affected by the type of fuel injector, fuel liquid properties, fuel injection pressure, fuel injection temperature, and ambient pressure. Performance of pressure swirl atomizer and hybrid air blast nozzle type fuel injectors are compared in this study. Aviation jet fuels, JP-8, Jet A, JP-5, and JP-10 and their effect on fuel injector performance is investigated. Fuel injector set conditions involving fuel injector pressure, fuel temperature and ambient pressure are varied in order to compare each fuel type. One objective of this thesis is to contribute spray patternation measurements to the body of existing drop size data in the literature. Fuel droplet size tends to increase with decreasing fuel injection pressure, decreasing fuel injection temperature and increasing ambient injection pressure. The differences between fuel types at particular set conditions occur due to differences in liquid properties between fuels. Liquid viscosity and surface tension are identified to be fuel-specific properties that affect the drop size of the fuel. An open aspect of current research that this paper addresses is how much the type of aviation jet fuel affects spray atomization characteristics. Conventional aviation fuel specifications are becoming more important with new interest in alternative

  5. Effects of light intensity light quality and air velocity on temperature in plant reproductive organs

    Science.gov (United States)

    Kitaya, Y.; Hirai, H.

    Excess temperature increase in plant reproductive organs such as anthers and stigmata could cause fertility impediments and thus produce sterile seeds under artificial lighting conditions in closed plant growth facilities There is a possibility that the aberration was caused by an excess increase in temperatures of reproductive organs in Bioregenerative Life Support Systems under microgravity conditions in space The fundamental study was conducted to know the thermal situation of the plant reproductive organs as affected by light intensity light quality and air velocity on the earth and to estimate the excess temperature increase in the reproductive organs in closed plant growth facilities in space Thermal images of reproductive organs of rice and strawberry were captured using infrared thermography at an air temperature of 10 r C The temperatures in flowers at 300 mu mol m -2 s -1 PPFD under the lights from red LEDs white LEDs blue LEDs fluorescent lamps and incandescent lamps increased by 1 4 1 7 1 9 6 0 and 25 3 r C respectively for rice and by 2 8 3 4 4 1 7 8 and 43 4 r C respectively for strawberry The flower temperatures increased with increasing PPFD levels The temperatures in petals anthers and stigmas of strawberry at 300 mu mol m -2 s -1 PPFD under incandescent lamps increased by 32 7 29 0 and 26 6 r C respectively at 0 1 m s -1 air velocity and by 20 6 18 5 and 15 9 r C respectively at 0 8 m s -1 air velocity The temperatures of reproductive organs decreased with increasing

  6. A review on air cathodes for zinc-air fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Neburchilov, Vladimir; Wang, Haijiang; Martin, Jonathan J.; Qu, Wei [Institute for Fuel Cell Innovation, National Research Council (Canada)

    2010-03-01

    This paper reviews the compositions, design and methods of fabrication of air cathodes for alkali zinc-air fuel cells (ZAFCs), one of the few successfully commercialized fuel cells. The more promising compositions for air cathodes are based on individual oxides, or mixtures of such, with a spinel, perovskite, or pyrochlore structure: MnO{sub 2}, Ag, Co{sub 3}O{sub 4}, La{sub 2}O{sub 3}, LaNiO{sub 3}, NiCo{sub 2}O{sub 4}, LaMnO{sub 3}, LaNiO{sub 3}, etc. These compositions provide the optimal balance of ORR activity and chemical stability in an alkali electrolyte. The sol-gel and reverse micelle methods supply the most uniform distribution of the catalyst on carbon and the highest catalyst BET surface area. It is shown that the design of the air cathode, including types of carbon black, binding agents, current collectors, Teflon membranes, thermal treatment of the GDL, and catalyst layers, has a strong effect on performance. (author)

  7. Impact of Biodiesel Fuels on Air Quality and Human Health: Task 4 Report; Impacts of Biodiesel Fuel Use on PM

    Energy Technology Data Exchange (ETDEWEB)

    Morris, R. E.; Jia, Y.

    2003-05-01

    This document is the Task 4 report for the NREL"Impacts of Biodiesel Fuels on Air Quality and Human Health" study. The objective of Task 4 is to estimate the effects of the use of biodiesel fuels on particulate matter levels and the resulting exposure to elevated levels of particulate matter.

  8. Direct numerical simulations of the ignition of lean primary reference fuel/air mixtures with temperature inhomogeneities

    KAUST Repository

    Luong, Minhbau

    2013-10-01

    The effects of fuel composition, thermal stratification, and turbulence on the ignition of lean homogeneous primary reference fuel (PRF)/air mixtures under the conditions of constant volume and elevated pressure are investigated by direct numerical simulations (DNSs) with a new 116-species reduced kinetic mechanism. Two-dimensional DNSs were performed in a fixed volume with a two-dimensional isotropic velocity spectrum and temperature fluctuations superimposed on the initial scalar fields with different fuel compositions to elucidate the influence of variations in the initial temperature fluctuation and turbulence intensity on the ignition of three different lean PRF/air mixtures. In general, it was found that the mean heat release rate increases slowly and the overall combustion occurs fast with increasing thermal stratification regardless of the fuel composition under elevated pressure and temperature conditions. In addition, the effect of the fuel composition on the ignition characteristics of PRF/air mixtures was found to vanish with increasing thermal stratification. Chemical explosive mode (CEM), displacement speed, and Damköhler number analyses revealed that the high degree of thermal stratification induces deflagration rather than spontaneous ignition at the reaction fronts, rendering the mean heat release rate more distributed over time subsequent to thermal runaway occurring at the highest temperature regions in the domain. These analyses also revealed that the vanishing of the fuel effect under the high degree of thermal stratification is caused by the nearly identical propagation characteristics of deflagrations of different PRF/air mixtures. It was also found that high intensity and short-timescale turbulence can effectively homogenize mixtures such that the overall ignition is apt to occur by spontaneous ignition. These results suggest that large thermal stratification leads to smooth operation of homogeneous charge compression-ignition (HCCI

  9. Influence of relative air/water flow velocity on oxygen mass transfer in gravity sewers.

    Science.gov (United States)

    Carrera, Lucie; Springer, Fanny; Lipeme-Kouyi, Gislain; Buffiere, Pierre

    2017-04-01

    Problems related to hydrogen sulfide may be serious for both network stakeholders and the public in terms of health, sustainability of the sewer structure and urban comfort. H2S emission models are generally theoretical and simplified in terms of environmental conditions. Although air transport characteristics in sewers must play a role in the fate of hydrogen sulfide, only a limited number of studies have investigated this issue. The aim of this study was to better understand H2S liquid to gas transfer by highlighting the link between the mass transfer coefficient and the turbulence in the air flow and the water flow. For experimental safety reasons, O2 was taken as a model compound. The oxygen mass transfer coefficients were obtained using a mass balance in plug flow. The mass transfer coefficient was not impacted by the range of the interface air-flow velocity values tested (0.55-2.28 m·s-1) or the water velocity values (0.06-0.55 m·s-1). Using the ratio between kL,O2 to kL,H2S, the H2S mass transfer behavior in a gravity pipe in the same hydraulic conditions can be predicted.

  10. Velocity and temperature field characteristics of water and air during natural convection heating in cans.

    Science.gov (United States)

    Erdogdu, Ferruh; Tutar, Mustafa

    2011-01-01

    Presence of headspace during canning is required since an adequate amount allows forming vacuum during the process. Sealing technology may not totally eliminate all entrapped gases, and headspace might affect heat transfer. Not much attention has been given to solve this problem in computational studies, and cans, for example, were mostly assumed to be fully filled with product. Therefore, the objective of this study was to determine velocity and temperature evolution of water and air in cans during heating to evaluate the relevance of headspace in the transport mechanism. For this purpose, canned water samples with a certain headspace were used, and required governing continuity, energy, and momentum equations were solved using a finite volume approach coupled with a volume of fluid element model. Simulation results correlated well with experimental results validating faster heating effects of headspace rather than insulation effects as reported in the literature. The organized velocity motions along the air-water interface were also shown. Practical Application: Canning is a universal and economic method for processing of food products, and presence of adequate headspace is required to form vacuum during sealing of the cans. Since sealing technology may not totally eliminate the entrapped gases, mainly air, headspace might affect heating rates in cans. This study demonstrated the increased heating rates in the presence of headspace in contrast with some studies in the literature. By applying the effect of headspace, required processing time for thermally processed foods can be reduced leading to more rapid processes and lower energy consumptions.

  11. Thermal stability effects on the structure of the velocity field above an air-water interface

    Science.gov (United States)

    Papadimitrakis, Y. A.; Hsu, Y.-H. L.; Wu, J.

    1987-01-01

    Mean velocity and turbulence measurements are described for turbulent flows above laboratory water waves, under various wind and thermal stratification conditions. Experimental results, when presented in the framework of Monin-Obukhov (1954) similarity theory, support local scaling based on evaluation of stratification effects at the same nondimensional distance from the mean water surface. Such scaling allows an extension of application of the above theory to the outer region of the boundary layer. Throughout the fully turbulent region, ratios of mean velocity gradients, eddy viscosities, and turbulence intensities under nonneutral and neutral conditions correlate well with the parameter z/Lambda (Lambda being a local Obukhov length and z the vertical coordinate of the mean air flow) and show good agreement with established field correlations. The influence of stratification on the wind-stress coefficient can be estimated from an empirical relationship in terms of its value under neutral conditions and a bulk Richardson number.

  12. Catalytic oxidative desulfurization of liquid hydrocarbon fuels using air

    Science.gov (United States)

    Sundararaman, Ramanathan

    Conventional approaches to oxidative desulfurization of liquid hydrocarbons involve use of high-purity, expensive water soluble peroxide for oxidation of sulfur compounds followed by post-treatment for removal of oxidized sulfones by extraction. Both are associated with higher cost due to handling, storage of oxidants and yield loss with extraction and water separation, making the whole process more expensive. This thesis explores an oxidative desulfurization process using air as an oxidant followed by catalytic decomposition of sulfones thereby eliminating the aforementioned issues. Oxidation of sulfur compounds was realized by a two step process in which peroxides were first generated in-situ by catalytic air oxidation, followed by catalytic oxidation of S compounds using the peroxides generated in-situ completing the two step approach. By this technique it was feasible to oxidize over 90% of sulfur compounds present in real jet (520 ppmw S) and diesel (41 ppmw S) fuels. Screening of bulk and supported CuO based catalysts for peroxide generation using model aromatic compound representing diesel fuel showed that bulk CuO catalyst was more effective in producing peroxides with high yield and selectivity. Testing of three real diesel fuels obtained from different sources for air oxidation over bulk CuO catalyst showed different level of effectiveness for generating peroxides in-situ which was consistent with air oxidation of representative model aromatic compounds. Peroxides generated in-situ was then used as an oxidant to oxidize sulfur compounds present in the fuel over MoO3/SiO2 catalyst. 81% selectivity of peroxides for oxidation of sulfur compounds was observed on MoO3/SiO2 catalyst at 40 °C and under similar conditions MoO3/Al2O3 gave only 41% selectivity. This difference in selectivity might be related to the difference in the nature of active sites of MoO3 on SiO2 and Al2O 3 supports as suggested by H2-TPR and XRD analyses. Testing of supported and bulk Mg

  13. Design Optimization of Liquid Fueled High Velocity Oxy- Fuel Thermal Spraying Technique for Durable Coating for Fossil Power Systems

    Energy Technology Data Exchange (ETDEWEB)

    Choudhuri, Ahsan [Univ. of Texas, El Paso, TX (United States); Love, Norman [Univ. of Texas, El Paso, TX (United States)

    2016-11-04

    High-velocity oxy–fuel (HVOF) thermal spraying was developed in 1930 and has been commercially available for twenty-five years. HVOF thermal spraying has several benefits over the more conventional plasma spray technique including a faster deposition rate which leads to quicker turn-around, with more durable coatings and higher bond strength, hardness and wear resistance due to a homogeneous distribution of the sprayed particles. HVOF thermal spraying is frequently used in engineering to deposit cermets, metallic alloys, composites and polymers, to enhance product life and performance. HVOF thermal spraying system is a highly promising technique for applying durable coatings on structural materials for corrosive and high temperature environments in advanced ultra-supercritical coal- fired (AUSC) boilers, steam turbines and gas turbines. HVOF thermal spraying is the preferred method for producing coatings with low porosity and high adhesion. HVOF thermal spray process has been shown to be one of the most efficient techniques to deposit high performance coatings at moderate cost. Variables affecting the deposit formation and coating properties include hardware characteristics such as nozzle geometry and spraying distance and process parameters such as equivalence ratio, gas flow density, and powder feedstock. In the spray process, the powder particles experience very high speeds combined with fast heating to the powder material melting point or above. This high temperature causes evaporation of the powder, dissolution, and phase transformations. Due to the complex nature of the HVOF technique, the control and optimization of the process is difficult. In general, good coating quality with suitable properties and required performance for specific applications is the goal in producing thermal spray coatings. In order to reach this goal, a deeper understanding of the spray process as a whole is needed. Although many researchers studied commercial HVOF thermal spray

  14. Alternative Observers for SI Engine Air/Fuel Ratio Control

    DEFF Research Database (Denmark)

    Hendricks, Elbert; Poulsen, Jannik; Olsen, Mads Bruun

    1996-01-01

    In earlier work it has been shown that a nonlinear observer based on the use of the manifold pressure state equation and a nonlinear fuel film compensator can maintain accurate A/F ratio control during both steady state and transient operation. This observer may be called a manifold absolute pres...... engine control system designer with a variety of robust control systems which can easily be made redundant in order to satisfy newer engine emissions and diagnosis requirements and legislation......In earlier work it has been shown that a nonlinear observer based on the use of the manifold pressure state equation and a nonlinear fuel film compensator can maintain accurate A/F ratio control during both steady state and transient operation. This observer may be called a manifold absolute...... sensors other than a MAP sensor. In this paper it is shown that it is possible to construct a family of alternative nonlinear observers which “naturally” allow the use of any given air mass flow related sensor or a combination of them for A/F ratio control. This new family of observers provides the SI...

  15. Laser induced fluorescence measurements of the mixing of fuel oil with air

    Energy Technology Data Exchange (ETDEWEB)

    Arnold, A.; Bombach, R.; Hubschmid, W.; Kaeppeli, B. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    We report on measurements of the mixing of fuel oil with air at atmospheric pressure in an industrial premixed gas turbine burner. The concentration of the vaporized fuel oil was measured with laser induced fluorescence. We reason that the fuel oil concentration can be considered with good accuracy as proportional to the fluorescence intensity. (author) 6 fig., 3 refs.

  16. Ignition of an organic water-coal fuel droplet floating in a heated-air flow

    Science.gov (United States)

    Valiullin, T. R.; Strizhak, P. A.; Shevyrev, S. A.; Bogomolov, A. R.

    2017-01-01

    Ignition of an organic water-coal fuel (CWSP) droplet floating in a heated-air flow has been studied experimentally. Rank B2 brown-coal particles with a size of 100 μm, used crankcase Total oil, water, and a plasticizer were used as the main CWSP components. A dedicated quartz-glass chamber has been designed with inlet and outlet elements made as truncated cones connected via a cylindrical ring. The cones were used to shape an oxidizer flow with a temperature of 500-830 K and a flow velocity of 0.5-5.0 m/s. A technique that uses a coordinate-positioning gear, a nichrome thread, and a cutter element has been developed for discharging CWSP droplets into the working zone of the chamber. Droplets with an initial size of 0.4 to 2.0 mm were used. Conditions have been determined for a droplet to float in the oxidizer flow long enough for the sustainable droplet burning to be initiated. Typical stages and integral ignition characteristics have been established. The integral parameters (ignition-delay times) of the examined processes have been compared to the results of experiments with CWSP droplets suspended on the junction of a quick-response thermocouple. It has been shown that floating fuel droplets ignite much quicker than the ones that sit still on the thermocouple due to rotation of an CWSP droplet in the oxidizer flow, more uniform heating of the droplet, and lack of heat drainage towards the droplet center. High-speed video recording of the peculiarities of floatation of a burning fuel droplet makes it possible to complement the existing models of water-coal fuel burning. The results can be used for a more substantiated modeling of furnace CWSP burning with the ANSYS, Fluent, and Sigma-Flow software packages.

  17. An Investigation of Fuel Mixing and Reaction in a CH4/Syngas/Air Premixed Impinging Flame with Varied H2/CO Proportion

    Directory of Open Access Journals (Sweden)

    Chih-Pin Chiu

    2017-07-01

    Full Text Available For industrial applications, we propose a concept of clean and efficient combustion through burning syngas on an impinging burner. We performed experimental measurements of particle image velocimetry, OH radical (OH* chemiluminescence, flame temperature, and CO emission to examine the fuel mixing and reaction of premixed impinging flames of CH4/syngas/air with H2/CO in varied proportions. The velocity distribution of the combustion flow field showed that a deceleration area in the main flow formed through the mutual impingement of two jet flows, which enhanced the mixing of fuel and air because of an increased momentum transfer. The deceleration area expanded with an increased CO proportion, which indicated that the mixing of fuel and air also increased with the increased CO proportion. Our examination of the OH* chemiluminescence demonstrated that its intensity increased with increased CO proportion, which showed that the reaction between fuel and air accordingly increased. CO provided in the syngas hence participated readily in the reaction of the CH4/syngas/air premixed impinging flames when the syngas contained CO in a large proportion. Although the volume flow rate of the provided CO quadrupled, the CO emission increased by only 12% to 15%. The results of this work are useful to improve the feasibility of fuel-injection systems using syngas as an alternative fuel.

  18. Air-Induced Drag Reduction at High Reynolds Numbers: Velocity and Void Fraction Profiles

    Science.gov (United States)

    Elbing, Brian; Mäkiharju, Simo; Wiggins, Andrew; Dowling, David; Perlin, Marc; Ceccio, Steven

    2010-11-01

    The injection of air into a turbulent boundary layer forming over a flat plate can reduce the skin friction. With sufficient volumetric fluxes an air layer can separate the solid surface from the flowing liquid, which can produce drag reduction in excess of 80%. Several large scale experiments have been conducted at the US Navy's Large Cavitation Channel on a 12.9 m long flat plate model investigating bubble drag reduction (BDR), air layer drag reduction (ALDR) and the transition between BDR and ALDR. The most recent experiment acquired phase velocities and void fraction profiles at three downstream locations (3.6, 5.9 and 10.6 m downstream from the model leading edge) for a single flow speed (˜6.4 m/s). The profiles were acquired with a combination of electrode point probes, time-of-flight sensors, Pitot tubes and an LDV system. Additional diagnostics included skin-friction sensors and flow-field image visualization. During this experiment the inlet flow was perturbed with vortex generators immediately upstream of the injection location to assess the robustness of the air layer. From these, and prior measurements, computational models can be refined to help assess the viability of ALDR for full-scale ship applications.

  19. Drying southern pine at 240°F. -- effects of air velocity and humidity, board thickness and density

    Science.gov (United States)

    Peter Koch

    1972-01-01

    Kiln time to each 10 percent moisture content was shortened by circulating air at high velocity, but was little affected by board specific gravity. A wet-bulb depression of 80oF. provided faster drying than depressions of 40 or 115oF. At 80 depression and with air circulated at 930 f.p.m., kiln time was directly...

  20. Three-wheel air turbocompressor for PEM fuel cell systems

    Science.gov (United States)

    Rehg, Tim; Gee, Mark; Emerson, Terence P.; Ferrall, Joe; Sokolov, Pavel

    2003-08-19

    A fuel cell system comprises a compressor and a fuel processor downstream of the compressor. A fuel cell stack is in communication with the fuel processor and compressor. A combustor is downstream of the fuel cell stack. First and second turbines are downstream of the fuel processor and in parallel flow communication with one another. A distribution valve is in communication with the first and second turbines. The first and second turbines are mechanically engaged to the compressor. A bypass valve is intermediate the compressor and the second turbine, with the bypass valve enabling a compressed gas from the compressor to bypass the fuel processor.

  1. AN INVESTIGATION OF THE EFFECTS OF AIR VELOCITY AND MOVEMENT ON THE THERMAL COMFORT INSIDE AN AUTOMOBILE

    Directory of Open Access Journals (Sweden)

    Ömer KAYNAKLI

    2003-03-01

    Full Text Available In this study, heat loss from various parts of human body, generated sweat mass and skin wetness depends on this are determined and their effect on thermal comfort are investigated. In the model human body is examined as divided into 16 parts and heat and mass transfer from each parts is simulated, as air flow velocity over the surface and thermal and evaporation resistance of clothing are accounted for the model. After checking the validity of the model (in comparison with results as an experimental study heat transfer coefficients, sensible and latent heat loss, skin wetness and variations of predicted percentage of dissatisfied (PPD are investigated for various air velocities, air temperatures and clothing groups. It is included that, average skin wetness decreases with increasing air velocity and sensible and latent heat losses increase due to the increase in heat transfer coefficient with increasing air velocity. However increase in sensible heat loss is more than latent heat loss. The most sensitive parameter to the air velocity is PPD.

  2. The effects of different air velocities on heat storage and body temperature in humans cycling in a hot, humid environment.

    Science.gov (United States)

    Saunders, A G; Dugas, J P; Tucker, R; Lambert, M I; Noakes, T D

    2005-03-01

    The purposes of this study were to determine (i) the effects of different facing air velocities on body temperature and heat storage during exercise in hot environmental conditions and (ii) the effects of ingesting fluids at two different rates on thermoregulation during exercise in hot conditions with higher air velocities. On five occasions nine subjects cycled for 2 h at 33.0 +/- 0.4 degrees C with a relative humidity of 59 +/- 3%. Air velocity was maintained at 0.2 km h(-1) (0 WS), 9.9 +/- 0.3 km h(-1) (10 WS), 33.3 +/-2.2 km h(-1) (100 WS) and 50.1 +/- 3.2 km h(-1) (150 WS) while subjects replaced 58.8 +/- 6.8% of sweat losses. In the fifth condition, air velocity was maintained at 33.7 +/- 2.2 km h(-1) and subjects replaced 80.0 +/- 6.8% of sweat losses (100.80 WS). Heat storage, body temperature and rating of perceived exertion were higher in 0 and 10 WS compared with all other conditions. There were no differences in any measured variable between 100 and 150 WS, or between 100 and 100.80 WS. Thus, the evaporative capacity of the environment is increased with higher air velocities, reducing heat storage and body temperature. At higher air velocities, a higher rate of fluid ingestion did not influence heat storage, body temperature or sweat rate. The finding of previous laboratory studies showing a beneficial effect of high rates of fluid ingestion on thermoregulation during exercise in hot, humid, windstill conditions cannot be extrapolated to out-of-doors exercise in which facing air velocities are seldom lower than the athlete's rate of forward progression.

  3. Multiple mechanisms generate a universal scaling with dissipation for the air-water gas transfer velocity

    Science.gov (United States)

    Katul, Gabriel; Liu, Heping

    2017-02-01

    A large corpus of field and laboratory experiments support the finding that the water side transfer velocity kL of sparingly soluble gases near air-water interfaces scales as kL˜(νɛ)1/4, where ν is the kinematic water viscosity and ɛ is the mean turbulent kinetic energy dissipation rate. Originally predicted from surface renewal theory, this scaling appears to hold for marine and coastal systems and across many environmental conditions. It is shown that multiple approaches to representing the effects of turbulence on kL lead to this expression when the Kolmogorov microscale is assumed to be the most efficient transporting eddy near the interface. The approaches considered range from simplified surface renewal schemes with distinct models for renewal durations, scaling and dimensional considerations, and a new structure function approach derived using analogies between scalar and momentum transfer. The work offers a new perspective as to why the aforementioned 1/4 scaling is robust.

  4. Potential of hydrogen fuel for future air transportation systems.

    Science.gov (United States)

    Small, W. J.; Fetterman, D. E.; Bonner, T. F., Jr.

    1973-01-01

    Recent studies have shown that hydrogen fuel can yield spectacular improvements in aircraft performance in addition to its more widely discussed environmental advantages. The characteristics of subsonic, supersonic, and hypersonic transport aircraft using hydrogen fuel are discussed, and their performance and environmental impact are compared to that of similar aircraft using conventional fuel. The possibilities of developing hydrogen-fueled supersonic and hypersonic vehicles with sonic boom levels acceptable for overland flight are also explored.

  5. Liquid Hydrogen Fuel System for Small Unmanned Air Vehicles

    Science.gov (United States)

    2013-01-07

    the Office of Naval Research for support of this research. VII. References 1 R. Stroman, J.C. Kellogg, K. Swider-Lyons, “Testing of a PEM Fuel Cell ...energy storage system. The Naval Research Laboratory has been extending the duration of electric UAVs through the use of hydrogen fuel cells , which...take advantage of both the high energy of H2 fuel in combination with the high efficiency (~50%) of polymer fuel cells . In this paper, we describe

  6. Influence of high velocity oxy-fuel parameters on properties of ...

    Indian Academy of Sciences (India)

    ... fuel-to-oxygen ratio with nanostructure coating by grain size smaller than feedstock powder. Photocatalytic activity evaluation results indicated that all the TiO2 coatings are effective to degradation MB under UV radiation and their activities differ in different spray conditions. It is found that fuel flow rate strongly influenced ...

  7. Refined weighted sum of gray gases model for air-fuel combustion and its impacts

    DEFF Research Database (Denmark)

    Yin, Chungen

    2013-01-01

    evaluated by Smith et al. for several partial pressures of CO2 and H2O vapor are often used for gas temperatures up to 2400 K, which is supplemented by the coefficient values presented by Coppalle and Vervisch for higher temperatures until 3000 K. This paper refines the air-fuel WSGGM in terms of accuracy......, completeness, and implementation and demonstrates the use and impacts of the refined model in CFD simulation of a conventional air-fuel utility boiler. The refined model is found to make a remarkable difference from the existing models in CFD results, when the particle−radiation interaction is negligible...... and not taken into account (e.g., in gaseous fuel combustion). Comparatively, the impacts of the refined model are greatly compromised under a solid-fuel combustion scenario because of the important role of the particle−radiation interaction. As the conclusion, the refined air-fuel WSGGM is highly recommended...

  8. Performance of PEM Liquid-Feed Direct Methanol-Air Fuel Cells

    Science.gov (United States)

    Narayanan, S. R.

    1995-01-01

    A direct methanol-air fuel cell operating at near atmospheric pressure, low-flow rate air, and at temperatures close to 60oC would tremendously enlarge the scope of potential applications. While earlier studies have reported performance with oxygen, the present study focuses on characterizing the performance of a PEM liquid feed direct methanol-air cell consisting of components developed in house. These cells employ Pt-Ru catalyst in the anode, Pt at the cathode and Nafion 117 as the PEM. The effect of pressure, flow rate of air and temperature on cell performance has been studied. With air, the performance level is as high as 0.437 V at 300 mA/cm2 (90oC, 20 psig, and excess air flow) has been attained. Even more significant is the performance level at 60oC, 1 atm and low flow rates of air (3-5 times stoichiometric), which is 0.4 V at 150 mA/cm2. Individual electrode potentials for the methanol and air electrode have been separated and analyzed. Fuel crossover rates and the impact of fuel crossover on the performance of the air electrode have also been measured. The study identifies issues specific to the methanol-air fuel cell and provides a basis for improvement strategies.

  9. Experimental study of convective heat transfer during cooling with low air velocity in a stack of objects

    Energy Technology Data Exchange (ETDEWEB)

    Ben Amara, Sami; Laguerre, Onrawee [Cemagref - Refrigeration Processes Engineering Research Unit, parc de Tourvoie, BP 44, 92163 cedex, Antony (France); Flick, Denis [National Agronomic Institute - INAPG, 16 rue Claude Bernard, 75231 cedex 05, Paris (France)

    2004-12-01

    During cooling with low air velocity (u{<=}0.2 m.s{sup -1}) of a stack of foodstuffs (a few centimeters dimension), the radiation and conduction between products can be of the same order of magnitude as convection. A method was developed to quantify these various transfer modes. The experiment was carried out using an in-line spherical arrangement; however, the same methodology can be applied to other product shapes. The results confirm that the heat transfers by radiation and conduction cannot be neglected. In addition, the convective heat transfer coefficient varies not only with air velocity but also with the product position in the stack. (authors)

  10. The indicative effects of inefficient urban traffic flow on fuel cost and exhaust air pollutant emissions

    CSIR Research Space (South Africa)

    Moselakgomo, M

    2015-07-01

    Full Text Available The indicative effects of inefficient urban traffic flow on fuel cost and exhaust air pollutant emissions Madumetja Moselakgomo, Mogesh Naidoo, Mosimanegape O. Letebele ABSTRACT: Poor urban traffic management such as poor intersection controls...

  11. Experimental investigation of the effect of air velocity on a unit cooler under frosting condition: a case study

    Science.gov (United States)

    Bayrak, Ergin; Çağlayan, Akın; Konukman, Alp Er S.

    2017-10-01

    Finned tube evaporators are used in a wide range of applications such as commercial and industrial cold/freezed storage rooms with high traffic loading under frosting conditions. In this case study, an evaporator with an integrated fan was manufactured and tested under frosting conditions by only changing the air flow rate in an ambient balanced type test laboratory compared to testing in a wind tunnel with a more uniform flow distribution in order to detect the effect of air flow rate on frosting. During the test, operation was performed separately based on three different air flow rates. The parameters concerning test operation such as the changes of air temperature, air relative humidity, surface temperature, air-side pressure drop and refrigerant side capacity etc. were followed in detail for each air flow rate. At the same time, digital images were captured in front of the evaporator; thus, frost thicknesses and blockage ratios at the course of fan stall were determined by using an image-processing technique. Consequently, the test and visual results showed that the trendline of air-side pressure drop increased slowly at the first stage of test operations, then increased linearly up to a top point and then the linearity was disrupted instantly. This point speculated the beginning of defrost operation for each case. In addition, despite detecting a velocity that needs to be avoided, a test applied at minimum air velocity is superior to providing minimum capacity in terms of loss of capacity during test operations.

  12. Studies on SI engine simulation and air/fuel ratio control systems design

    OpenAIRE

    Bai, Yang

    2013-01-01

    This thesis was submitted for the degree of Doctor of Philosophy and awarded by Brunel University. More stringent Euro 6 and LEV III emission standards will immediately begin execution on 2014 and 2015 respectively. Accurate air/fuel ratio control can effectively reduce vehicle emission. The simulation of engine dynamic system is a very powerful method for developing and analysing engine and engine controller. Currently, most engine air/fuel ratio control used look-up table combined with p...

  13. Interim results from UO/sub 2/ fuel oxidation tests in air

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, T.K.; Gilbert, E.R.; Thornhill, C.K.; White, G.D.; Piepel, G.F.; Griffin, C.W.j

    1987-08-01

    An experimental program is being conducted at Pacific Northwest Laboratory (PNL) to extend the characterization of spent fuel oxidation in air. To characterize oxidation behavior of irradiated UO/sub 2/, fuel oxidation tests were performed on declad light-water reactor spent fuel and nonirradited UO/sub 2/ pellets in the temperature range of 135 to 250/sup 0/C. These tests were designed to determine the important independent variables that might affect spent fuel oxidation behavior. The data from this program, when combined with the test results from other programs, will be used to develop recommended spent fuel dry-storage temperature limits in air. This report describes interim test results. The initial PNL investigations of nonirradiated and spent fuels identified the important testing variables as temperature, fuel burnup, radiolysis of the air, fuel microstructure, and moisture in the air. Based on these initial results, a more extensive statistically designed test matrix was developed to study the effects of temperature, burnup, and moisture on the oxidation behavior of spent fuel. Oxidation tests were initiated using both boiling-water reactor and pressurized-water reactor fuels from several different reactors with burnups from 8 to 34 GWd/MTU. A 10/sup 5/ R/h gamma field was applied to the test ovens to simulate dry storage cask conditions. Nonirradiated fuel was included as a control. This report describes experimental results from the initial tests on both the spent and nonirradiated fuels and results to date on the tests in a 10/sup 5/ R/h gamma field. 33 refs., 51 figs., 6 tabs.

  14. Fuel Cell Propulsion Systems for an All-electric Personal Air Vehicle

    Science.gov (United States)

    Kohout, Lisa L.; Schmitz, Paul C.

    2003-01-01

    There is a growing interest in the use of fuel cells as a power source for all-electric aircraft propulsion as a means to substantially reduce or eliminate environmentally harmful emissions. Among the technologies under consideration for these concepts are advanced proton exchange membrane and solid oxide fuel cells, alternative fuels and fuel processing, and fuel storage. This paper summarizes the results of a first-order feasibility study for an all-electric personal air vehicle utilizing a fuel cell-powered propulsion system. A representative aircraft with an internal combustion engine was chosen as a baseline to provide key parameters to the study, including engine power and subsystem mass, fuel storage volume and mass, and aircraft range. The engine, fuel tank, and associated ancillaries were then replaced with a fuel cell subsystem. Various configurations were considered including: a proton exchange membrane (PEM) fuel cell with liquid hydrogen storage; a direct methanol PEM fuel cell; and a direct internal reforming solid oxide fuel cell (SOFC)/turbine hybrid system using liquid methane fuel. Each configuration was compared to the baseline case on a mass and range basis.

  15. Conclusions and recommendations. [for problems in energy situation, air transportation, and hydrogen fuel

    Science.gov (United States)

    1973-01-01

    Conclusions and recommendations are presented for an analysis of the total energy situation; the effect of the energy problem on air transportation; and hydrogen fuel for aircraft. Properties and production costs of fuels, future prediction for energy and transportation, and economic aspects of hydrogen production are appended.

  16. Multi-dimensional modelling of spray, in-cylinder air motion and fuel ...

    Indian Academy of Sciences (India)

    of the compression stroke so as to create a stratified mixture to save fuel and ensure that the engine continues to run with ... in the suction stroke to allow the fuel droplets to mix with the in-cylinder air and create a homogeneous mixture at the ... 30 mm. Figure 2. Mesh generated for the three-dimensional engine simulation.

  17. Indoor air pollution in rural China: Cooking fuels, stoves, and health status

    Energy Technology Data Exchange (ETDEWEB)

    Peabody, J.W.; Riddell, T.J.; Smith, K.R.; Liu, Y.P.; Zhao, Y.Y.; Gong, J.H.; Milet, M.; Sinton, J.E. [Amgen Inc., Thousand Oaks, CA (United States)

    2005-03-15

    Solid fuels are a major source of indoor air pollution, but in less developed countries the short-term health effects of indoor air pollution are poorly understood. The authors conducted a large cross-sectional study of rural Chinese households to determine associations between individual health status and domestic cooking as a source of indoor air pollution. The study included measures of health status as well as measures of indoor air-pollution sources, such as solid cooking fuels and cooking stoves. Compared with other fuel types, coal was associated with a lower health status, including negative impacts on exhaled carbon monoxide level, forced vital capacity, lifetime prevalence of chronic obstructive pulmonary disease and asthma, and health care utilization. Decreasing household coal use, increasing use of improved stove technology, and increasing kitchen ventilation may decrease the short-term health effects of indoor air pollution.

  18. Air/fuel ratio for an internal combustion engine controlled by gas sensor in intake manifold

    Energy Technology Data Exchange (ETDEWEB)

    Barnard, D.D.

    1978-08-22

    In a closed loop fuel management system for an internal combustion engine, a gas sensor is positioned in the intake manifold and is responsive to a characteristic of the fuel mixture for generating an electrical control signal for controlling the metering of the fuel to the mixture. In the preferred embodiment, the air and fuel are mixed together and the resultant mixture passes by an oxygen gas sensor prior to being distributed to the cylinders through the intake manifold system. The output signal of the sensor is used for controlling the metering of the fuel. Fuel delivery correction delays due to transport lag in conventional closed loop fuel management systems using oxygen gas sensors are eliminated.

  19. Effects of air temperature and velocity on the drying kinetics and product particle size of starch from arrowroot (Maranta arundinacae)

    Science.gov (United States)

    Caparanga, Alvin R.; Reyes, Rachael Anne L.; Rivas, Reiner L.; De Vera, Flordeliza C.; Retnasamy, Vithyacharan; Aris, Hasnizah

    2017-11-01

    This study utilized the 3k factorial design with k as the two varying factors namely, temperature and air velocity. The effects of temperature and air velocity on the drying rate curves and on the average particle diameter of the arrowroot starch were investigated. Extracted arrowroot starch samples were dried based on the designed parameters until constant weight was obtained. The resulting initial moisture content of the arrowroot starch was 49.4%. Higher temperatures correspond to higher drying rates and faster drying time while air velocity effects were approximately negligible or had little effect. Drying rate is a function of temperature and time. The constant rate period was not observed for the drying rate of arrowroot starch. The drying curves were fitted against five mathematical models: Lewis, Page, Henderson and Pabis, Logarithmic and Midili. The Midili Model was the best fit for the experimental data since it yielded the highest R2 and the lowest RSME values for all runs. Scanning electron microscopy (SEM) was used for qualitative analysis and for determination of average particle diameter of the starch granules. The starch granules average particle diameter had a range of 12.06 - 24.60 μm. The use of ANOVA proved that particle diameters for each run varied significantly with each other. And, the Taguchi Design proved that high temperatures yield lower average particle diameter, while high air velocities yield higher average particle diameter.

  20. CO2 dynamics along Danish lowland streams: water-air gradients, piston velocities and evasion rates

    DEFF Research Database (Denmark)

    Sand-Jensen, Kaj; Stæhr, Peter A.

    2012-01-01

    We measured CO2 concentration and determined evasion rate and piston velocity across the water–air interface in flow-through chambers at eight stations along two 20 km long streams in agricultural landscapes in Zealand, Denmark. Both streams were 9–18-fold supersaturated in CO2 with daily means...

  1. Calculation and measurement of a neutral air flow velocity impacting a high voltage capacitor with asymmetrical electrodes

    Directory of Open Access Journals (Sweden)

    M. Malík

    2014-01-01

    Full Text Available This paper deals with the effects surrounding phenomenon of a mechanical force generated on a high voltage asymmetrical capacitor (the so called Biefeld-Brown effect. A method to measure this force is described and a formula to calculate its value is also given. Based on this the authors derive a formula characterising the neutral air flow velocity impacting an asymmetrical capacitor connected to high voltage. This air flow under normal circumstances lessens the generated force. In the following part this velocity is measured using Particle Image Velocimetry measuring technique and the results of the theoretically calculated velocity and the experimentally measured value are compared. The authors found a good agreement between the results of both approaches.

  2. A Novel Hybrid-Fuel Storage System of Compressed Air Energy for China

    Directory of Open Access Journals (Sweden)

    Wenyi Liu

    2014-08-01

    Full Text Available Compressed air energy storage (CAES is a large-scale technology that provides long-duration energy storage. It is promising for balancing the large-scale penetration of intermittent and dispersed sources of power, such as wind and solar power, into electric grids. The existing CAES plants utilize natural gas (NG as fuel. However, China is rich in coal but is deficient in NG; therefore, a hybrid-fuel CAES is proposed and analyzed in this study. Based on the existing CAES plants, the hybrid-fuel CAES incorporates an external combustion heater into the power generation subsystem to heat the air from the recuperator and the air from the high-pressure air turbine. Coal is the fuel for the external combustion heater. The overall efficiency and exergy efficiency of the hybrid-fuel CAES are 61.18% and 59.84%, respectively. Given the same parameters, the cost of electricity (COE of the hybrid-fuel CAES, which requires less NG, is $5.48/MW∙h less than that of the gas-fuel CAES. Although the proposed CAES requires a relatively high investment in the current electricity system in North China, the proposed CAES will be likely to become competitive in the market, provided that the energy supplies are improved and the large scale grid-connection of wind power is realized.

  3. Air-fuel-ratio control of engine system with unknown input observer

    OpenAIRE

    Na, Jing; Herrmann, Guido; Rames, Clement; Burke, Richard; Brace, Chris

    2016-01-01

    This paper presents an alternative control to maintain the air-fuel-ratio (AFR) of port-injected spark ignition (SI) engines at certain value, i.e. stoichiometric value, to improve the fuel economy. We first reformulate the AFR regulation problem as a tracking control for the injected fuel mass flow rate, which can simplify the control synthesis when the fuel film dynamics are taken into account. The unknown engine parameters and dynamics can be lumped as an unknown signal, and then compensat...

  4. Turbulent and Stable/Unstable Laminar Burning Velocity Measurements from Outwardly Propagating Spherical Hydrogen-Air Flames at Elevated Pressures

    Science.gov (United States)

    Smallbone, Andrew; Tsuneyoshi, Kousaku; Kitagawa, Toshiaki

    The laminar burning velocity of pre-mixed hydrogen-air mixtures was measured in a fan stirred combustion bomb. Unstretched laminar burning velocities and Markstein lengths were obtained at 0.10MPa for equivalence ratios of 0.4, 0.6, 0.8 and 1.0 using high speed flame imaging. The difficulties which arose whilst obtaining similar measurements at 0.25MPa and 0.50MPa are outlined. The turbulent burning velocity was measured at equivalence ratios of 0.4 and 0.8 from explosions carried out at 0.10MPa with turbulence intensities of 0.8 and 1.6m/s. Higher turbulent burning velocity ratios were observed for mixtures which yielded lower Markstein lengths in the laminar combustion experiments.

  5. High-speed non-intrusive measurements of fuel velocity fields at high-pressure injectors

    Science.gov (United States)

    Gürtler, Johannes; Schlüßler, Raimund; Fischer, Andreas; Czarske, Jürgen

    2017-03-01

    Using a single high-speed camera and a frequency modulated laser, a novel approach is presented for fast velocity field measurements in unsteady spray flows. The velocity range is from zero up to several 100 m/s, which requires a high measurement rate and a large dynamic. Typically, flow measurements require to seed tracer particles to the fluid. A paradigm shift to seeding-free measurements is presented. The light scattered at the phase boundaries of the fluid droplets is evaluated. In order to validate the high-speed measurement system, a detailed uncertainty analysis is performed by means of measurements as well as simulations. Thereby, variations of the scattered light intensity, which are based on the high temporal velocity gradients, are found to be the main contribution to the uncertainty. The eventually measurement results, obtained at a measurement rate of 500 kHz, exhibit spray velocities ranging from 0 m/s up to 400 m/s in less than 1 ms, and the detection of unsteady and irregular flow phenomena with a characteristic time of several μs is achieved. This demonstrates the high measurement rate, the high temporal resolution and the large measurement range of the proposed high-speed measurement system.

  6. Fuel-in-air FY07 summary report

    Energy Technology Data Exchange (ETDEWEB)

    Hanson, Brady D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Daniel, Richard C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Casella, Andy M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wittman, Richard S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wu, Wesley [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); MacFarlan, Paul J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Shimskey, Rick W. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2008-01-22

    Results of the testing program to determine fractional release rates and particle size distributions from failed commercial spent fuel related to the operations in the surface facility at Yucca Mountain are presented.

  7. Step-Wise Velocity of an Air Bubble Rising in a Vertical Tube Filled with a Liquid Dispersion of Nanoparticles.

    Science.gov (United States)

    Cho, Heon Ki; Nikolov, Alex D; Wasan, Darsh T

    2017-03-21

    The motion of air bubbles in tubes filled with aqueous suspensions of nanoparticles (nanofluids) is of practical interest for bubble jets, lab-on-a-chip, and transporting media. Therefore, the focus of this study is the dynamics of air bubbles rising in a tube in a nanofluid. Many authors experimentally and analytically proposed that the velocity of rising air bubbles is constant for long air bubbles suspended in a vertical tube in common liquids (e.g. an aqueous glycerol solution) when the capillary number is larger than 10-4. For the first time, we report here a systematic study of an air bubble rising in a vertical tube in a nanofluid (e.g. an aqueous silica dioxide nanoparticle suspension, nominal particle size, 19 nm). We varied the bubble length scaled by the diameter of the tubes (L/D), the concentration of the nanofluid (10 and 12.5 v %), and the tube diameter (0.45, 0.47, and 0.50 cm). The presence of the nanoparticles creates a significant change in the bubble velocity compared with the bubble rising in the common liquid with the same bulk viscosity. We observed a novel phenomenon of a step-wise increase in the air bubble rising velocity versus bubble length for small capillary numbers less than 10-7. This step-wise velocity increase versus the bubble length was not observed in a common fluid. The step-wise velocity increase is attributed to the nanoparticle self-layering phenomenon in the film adjacent to the tube wall. To elucidate the role of the nanoparticle film self-layering on the bubble rising velocity, the effect of the capillary number, the tube diameter (e.g. the capillary pressure), and nanofilm viscosity are investigated. We propose a model that takes into consideration the nanoparticle layering in the film confinement to explain the step-wise velocity phenomenon versus the length of the bubble. The oscillatory film interaction energy isotherm is calculated and the Frenkel approach is used to estimate the film viscosity.

  8. Impact of Biodiesel Fuels on Air Quality and Human Health: Task 2 Report; The Impact of Biodiesel Fuels on Ozone Concentrations

    Energy Technology Data Exchange (ETDEWEB)

    Morris, R. E.; Mansell, G. E.; Jia, Y.; Wilson, G.

    2003-05-01

    This report documents Task 2 of the NREL study"Impact of Biodiesel Fuels on Air Quality and Hyman Health". Under Task 1, engine test data using biodiesel and standard diesel fuels were analyzed to estimate the effects biodiesel fuel has on heavy duty diesel vehicle tailpipe emissions.

  9. Performance Analysis of Air Breathing Proton Exchange Membrane Fuel Cell Stack (PEMFCS) At Different Operating Condition

    Science.gov (United States)

    Sunil, V.; Venkata siva, G.; Yoganjaneyulu, G.; Ravikumar, V. V.

    2017-08-01

    The answer for an emission free power source in future is in the form of fuel cells which combine hydrogen and oxygen producing electricity and a harmless by product-water. A proton exchange membrane (PEM) fuel cell is ideal for automotive applications. A single cell cannot supply the essential power for any application. Hence PEM fuel cell stacks are used. The effect of different operating parameters namely: type of convection, type of draught, hydrogen flow rate, hydrogen inlet pressure, ambient temperature and humidity, hydrogen humidity, cell orientation on the performance of air breathing PEM fuel cell stack was analyzed using a computerized fuel cell test station. Then, the fuel cell stack was subjected to different load conditions. It was found that the stack performs very poorly at full capacity (runs only for 30 min. but runs for 3 hours at 50% capacity). Hence, a detailed study was undertaken to maximize the duration of the stack’s performance at peak load.

  10. Study on Strength and Ultrasonic Velocity of Air-Entrained Concrete and Plain Concrete in Cold Environment

    Directory of Open Access Journals (Sweden)

    Huai-shuai Shang

    2014-01-01

    Full Text Available Nondestructive testing technology is essential in the quality inspection of repair, alteration, and renovation of the existing engineering, especially for concrete structure in severe environment. The objective of this work is to deal with the behavior of ultrasonic velocity and mechanical properties of plain concrete and air-entrained concrete subjected to freeze-thaw cycles (F-T-C. The ultrasonic velocity and mechanical properties (tensile strength, compressive strength, cubic compressive strength, and splitting strength of C30 air-entrained concrete and plain concrete with different water-cement ratio (water-cement ratio was 0.55, 0.45, and 0.50, resp. after F-T cycles were measured. The influences of F-T cycles on ultrasonic velocity and mechanical properties of C30 air-entrained concrete and plain concrete were analyzed. And the relationship between mechanical properties and ultrasonic velocity was established. The experimental results can be useful for the design of new concrete structure, maintenance and life prediction of existing concrete structure such as offshore platform and concrete dock wall.

  11. The influence of air-fuel ratio on engine performance and pollutant emission of an SI engine using ethanol-gasoline-blended fuels

    Science.gov (United States)

    Wu, Chan-Wei; Chen, Rong-Horng; Pu, Jen-Yung; Lin, Ta-Hui

    Ethanol-gasoline-blended fuel was tested in a conventional engine under various air-fuel equivalence ratios ( λ) for its performance and emissions. The amount of fuel injection was adjusted manually by an open-loop control system using a CONSULT controller. It was found that without changing throttle opening and injection strategy, λ could be extended to a leaner condition as ethanol content increased. The results of engine performance tests showed that torque output would increase slightly at small throttle valve opening when ethanol-gasoline-blended fuel was used. It was also shown that CO and HC emissions were reduced with the increase of ethanol content in the blended fuel, which resulted from oxygen enrichment. At an air-fuel equivalence ratio slightly larger than one, the smallest amounts of CO and HC and the largest amounts of CO 2 resulted. It was noted that under the lean combustion condition, CO 2 emission was controlled by air-fuel equivalence ratio; while under the rich combustion condition, CO 2 emission is offset by CO emission. It was also found that CO 2 emission per unit horse power output for blended fuel was similar or less than that for gasoline fuel. From the experimental data, the optimal ethanol content in the gasoline and air-fuel equivalence ratio in terms of engine performance and air pollution was found.

  12. Characterization of Copper Coatings Deposited by High-Velocity Oxy-Fuel Spray for Thermal and Electrical Conductivity Applications

    Science.gov (United States)

    Salimijazi, H. R.; Aghaee, M.; Salehi, M.; Garcia, E.

    2017-11-01

    Copper coatings were deposited on steel substrates by high-velocity oxy-fuel spraying. The microstructure of the feedstock copper powders and free-standing coatings were evaluated by optical and scanning electron microscopy. The x-ray diffraction pattern was utilized to determine phase compositions of powders and coatings. Oxygen content was determined by a LECO-T300 oxygen determiner. The thermal conductivity of the coatings was measured in two directions, through-thickness and in-plane by laser flash apparatus. The electrical resistivity of the coatings was measured by the four-point probe method. Oxygen content of the coatings was two times higher than that of the initial powders (0.35-0.37%). The thermal and electrical conductivities of the coatings were different depending on the direction of the measurement. The thermal and electrical conductivity of the coatings improved after annealing for 6 h at a temperature of 600°C.

  13. Biofuels: An Alternative to U.S. Air Force Petroleum Fuel Dependency

    Science.gov (United States)

    2007-12-01

    of biodiesel. Virgin oil feedstock such as rapeseed, and soybean oils are most commonly used, though other crops such as mustard, palm oil or hemp ...fleet may make the biofuel alternative cost prohibitive . Additionally, the U.S. Air Force mission is global, and in order to operate around the...railroads, tanker trucks, barges and pipelines. An alternative fuel would be cost prohibitive if it forced the establishment of a new fuel

  14. Modeling skin temperature to assess the effect of air velocity to mitigate heat stress among growing pigs

    DEFF Research Database (Denmark)

    Bjerg, Bjarne Schmidt; Pedersen, Poul; Morsing, Svend

    to the skin and from the skin to the surroundings. The latter is modelled as the united resistance for convection, radiation and evaporation. The model considers that the thermal heat load affects the tissue resistance, the body temperature and the evaporation from the skin, which is managed by modeling...... temperature model to generated data for determining the potential effect of air velocity to mitigate heat stress among growing pigs housed in warm environment. The model calculates the skin temperature as function of body temperature, air temperature and the resistances for heat transfer from the body...

  15. Study of the ventilation at ATLAS cavern UX15 air velocity and temperature around the muon chambers

    CERN Document Server

    Vigo-Castellví, E

    2000-01-01

    The Muon Chambers of ATLAS detector cannot work under temperature differences between two opposed faces above 3 K. In addition, a low velocity of the air around the Muon Chambers is essential to avoid vibration problems. The CV group at the ST division is involved in an airflow simulation inside UX15 cavern to check air temperature and velocity profiles around the ATLAS Muon Chambers. In this paper, the status and the content of the performed theoretical studies will be explained. Three simulation models, which helped to understand the Muon Spectrometer thermal environment and the efficiency of the ventilation system at ATLAS cavern, will be presented. Besides, it will be shown how these studies support the proposal of a deeper individual Muon Chamber study.

  16. Influence of gas flow velocity on the transport of chemical species in an atmospheric pressure air plasma discharge

    Science.gov (United States)

    Hasan, M. I.; Walsh, J. L.

    2017-03-01

    This paper reports on a numerical study of the transport of reactive chemical species generated in an atmospheric-pressure air plasma discharge under the influence of a high velocity flowing gas. Using a 1D air plasma model, it is shown that the reactive species transported downstream of the discharge region can be categorized into three distinct groups based on their spatial distribution: (i) decaying downstream species, (ii) increasing downstream species and (iii) variable density species, where the density is a function of both spatial position and gas flow velocity. It is demonstrated that the gas flow velocity influences the dominant chemical reactions downstream of the discharge region, noticeably altering the composition of several key reactive chemical species transported to a given downstream location. As many emerging applications of atmospheric pressure plasma are driven by the flux of reactive chemical species, this study highlights the importance of gas flow velocity, not only as a means to enhance mass transport but also as a means to manipulate the very nature of the reactive plasma chemistry arriving at a given location.

  17. Fuel Jettisoning by U.S. Air Force Aircraft. Volume II. Fuel Dump Listings.

    Science.gov (United States)

    1980-03-01

    fuel jettisoning during the period I January 1975 through 30 June 1978, but the work involved, including establish - ment of the fuel dump reporting...Day/Year Time: Zulu (Greenwich Mean Time); 24-hour clock ACFT: Aircraft Designation Fuel: Type fuel jettisoned ALT: Altitude, in thousands of feet; to...C 󈧇 3 0 3’ .’. 9 A, MOOC -3 0 ftC’C’C’* ’ V CC’V N0 04*4C C -C’U~ 0 UN QO ’UC ’ ’UC ’C Coo I 0 0 0 0C𔃺 00C 0000 0 00 MI 00 OI ’Q 000 00 ’r 00 0 4 0

  18. Air Quality Benefits of Ship Fuel Regulations in the San Francisco Bay Area

    Science.gov (United States)

    Tao, L.; Harley, R. A.; Fairley, D.; Martien, P. T.

    2012-12-01

    Ocean-going vessels burning high-sulfur heavy fuel oil are an important emission source of air pollutants such as sulfur dioxide and particulate matter. Beginning July 1, 2009, an emission control area was put into effect at ports and along the California coastline, requiring use of low-sulfur marine fuels in place of heavy fuel oil in main engines of ships. To assess impacts of the fuel changes on air quality at the Port of Oakland and in the surrounding San Francisco Bay area, we analyzed speciated fine particle composition data from 4 urban sites and 2 more remote sites (Point Reyes and Pinnacles) from the IMPROVE network. Measured changes in concentrations of vanadium, a useful and specific tracer for heavy fuel oil combustion, are related to overall changes in primary aerosol emissions from ships. The results indicate a substantial reduction in vanadium concentrations after the fuel change, and a 13 to 38% decrease in SO2 concentration, with the SO2 decrease varying depending on proximity to shipping lanes. We inferred from emission factors documented in the literature that marine vessel contributions to primary fine particulate matter mass in the Bay Area, prior to the fuel change, were on the order of 1 to 5%.

  19. Multiple Threats to Child Health from Fossil Fuel Combustion: Impacts of Air Pollution and Climate Change.

    Science.gov (United States)

    Perera, Frederica P

    2017-02-01

    Approaches to estimating and addressing the risk to children from fossil fuel combustion have been fragmented, tending to focus either on the toxic air emissions or on climate change. Yet developing children, and especially poor children, now bear a disproportionate burden of disease from both environmental pollution and climate change due to fossil fuel combustion. This commentary summarizes the robust scientific evidence regarding the multiple current and projected health impacts of fossil fuel combustion on the young to make the case for a holistic, child-centered energy and climate policy that addresses the full array of physical and psychosocial stressors resulting from fossil fuel pollution. The data summarized here show that by sharply reducing our dependence on fossil fuels we would achieve highly significant health and economic benefits for our children and their future. These benefits would occur immediately and also play out over the life course and potentially across generations. Going beyond the powerful scientific and economic arguments for urgent action to reduce the burning of fossil fuels is the strong moral imperative to protect our most vulnerable populations. Citation: Perera FP. 2017. Multiple threats to child health from fossil fuel combustion: impacts of air pollution and climate change. Environ Health Perspect 125:141-148; http://dx.doi.org/10.1289/EHP299.

  20. Computer program for obtaining thermodynamic and transport properties of air and products of combustion of ASTM-A-1 fuel and air

    Science.gov (United States)

    Hippensteele, S. A.; Colladay, R. S.

    1978-01-01

    A computer program for determining desired thermodynamic and transport property values by means of a three-dimensional (pressure, fuel-air ratio, and either enthalpy or temperature) interpolation routine was developed. The program calculates temperature (or enthalpy), molecular weight, viscosity, specific heat at constant pressure, thermal conductivity, isentropic exponent (equal to the specific heat ratio at conditions where gases do not react), Prandtl number, and entropy for air and a combustion gas mixture of ASTM-A-1 fuel and air over fuel-air ratios from zero to stoichiometric, pressures from 1 to 40 atm, and temperatures from 250 to 2800 K.

  1. Emerging Fuel Cell Technology Being Developed: Offers Many Benefits to Air Vehicles

    Science.gov (United States)

    Walker, James F.; Civinskas, Kestutis C.

    2004-01-01

    Fuel cells, which have recently received considerable attention for terrestrial applications ranging from automobiles to stationary power generation, may enable new aerospace missions as well as offer fuel savings, quiet operations, and reduced emissions for current and future aircraft. NASA has extensive experience with fuel cells, having used them on manned space flight systems over four decades. Consequently, the NASA Glenn Research Center has initiated an effort to investigate and develop fuel cell technologies for multiple aerospace applications. Two promising fuel cell types are the proton exchange membrane (PEM) and solid oxide fuel cell (SOFC). PEM technology, first used on the Gemini spacecraft in the sixties, remained unutilized thereafter until the automotive industry recently recognized the potential. PEM fuel cells are low-temperature devices offering quick startup time but requiring relatively pure hydrogen fuel. In contrast, SOFCs operate at high temperatures and tolerate higher levels of impurities. This flexibility allows SOFCs to use hydrocarbon fuels, which is an important factor considering our current liquid petroleum infrastructure. However, depending on the specific application, either PEM or SOFC can be attractive. As only NASA can, the Agency is pursuing fuel cell technology for civil uninhabited aerial vehicles (UAVs) because it offers enhanced scientific capabilities, including enabling highaltitude, long-endurance missions. The NASA Helios aircraft demonstrated altitudes approaching 100,000 ft using solar power in 2001, and future plans include the development of a regenerative PEM fuel cell to provide nighttime power. Unique to NASA's mission, the high-altitude aircraft application requires the PEM fuel cell to operate on pure oxygen, instead of the air typical of terrestrial applications.

  2. United States Air Force Shale Oil to Fuels. Phase II.

    Science.gov (United States)

    1981-11-01

    There is no attempt to recover propane , and the light end hydrocarbons are taken to the fuel gas system for feed to the hydrogen plant. Part of the...shale oil charged from the high pressure hydro- treater separator. The hydrotreated shale oil charge stock is combined with the recycle hydrogen rich gas...sulfide and ammonia are steam stripped from the water. The clean water is returned to the refinery and the gas is sent to the amine treater for

  3. Numerical investigation of interfacial mass transport resistance and two-phase flow in PEM fuel cell air channels

    Science.gov (United States)

    Koz, Mustafa

    Proton exchange membrane fuel cells (PEMFCs) are efficient and environmentally friendly electrochemical engines. The performance of a PEMFC is adversely affected by oxygen (O2) concentration loss from the air flow channel to the cathode catalyst layer (CL). Oxygen transport resistance at the gas diffusion layer (GDL) and air channel interface is a non-negligible component of the O2 concentration loss. Simplified PEMFC performance models in the available literature incorporate the O2 resistance at the GDL-channel interface as an input parameter. However, this parameter has been taken as a constant so far in the available literature and does not reflect variable PEMFC operating conditions and the effect of two-phase flow in the channels. This study numerically calculates the O2 transport resistance at the GDL-air channel interface and expresses this resistance through the non-dimensional Sherwood number (Sh). Local Sh is investigated in an air channel with multiple droplets and films inside. These water features are represented as solid obstructions and only air flow is simulated. Local variations of Sh in the flow direction are obtained as a function of superficial air velocity, water feature size, and uniform spacing between water features. These variations are expressed with mathematical expressions for the PEMFC performance models to utilize and save computational resources. The resulting mathematical correlations for Sh can be utilized in PEMFC performance models. These models can predict cell performance more accurately with the help of the results of this work. Moreover, PEMFC performance models do not need to use a look-up table since the results were expressed through correlations. Performance models can be kept simplified although their predictions will become more realistic. Since two-phase flow in channels is experienced mostly at lower temperatures, performance optimization at low temperatures can be done easier.

  4. Quantification of emission reduction potentials of primary air pollutants from residential solid fuel combustion by adopting cleaner fuels in China.

    Science.gov (United States)

    Shen, Guofeng

    2015-11-01

    Residential low efficient fuel burning is a major source of many air pollutants produced during incomplete combustions, and household air pollution has been identified as one of the top environmental risk factors. Here we compiled literature-reported emission factors of pollutants including carbon monoxide (CO), total suspended particles (TSPs), PM2.5, organic carbon (OC), elemental carbon (EC) and polycyclic aromatic hydrocarbons (PAHs) for different household energy sources, and quantified the potential for emission reduction by clean fuel adoption. The burning of crop straws, firewood and coal chunks in residential stoves had high emissions per unit fuel mass but lower thermal efficiencies, resulting in high levels of pollution emissions per unit of useful energy, whereas pelletized biofuels and coal briquettes had lower pollutant emissions and higher thermal efficiencies. Briquetting coal may lead to 82%-88% CO, 74%-99% TSP, 73%-76% PM2.5, 64%-98% OC, 92%-99% EC and 80%-83% PAH reductions compared to raw chunk coal. Biomass pelletizing technology would achieve 88%-97% CO, 73%-87% TSP, 79%-88% PM2.5, 94%-96% OC, 91%-99% EC and 63%-96% PAH reduction compared to biomass burning. The adoption of gas fuels (i.e., liquid petroleum gas, natural gas) would achieve significant pollutant reduction, nearly 96% for targeted pollutants. The reduction is related not only to fuel change, but also to the usage of high efficiency stoves. Copyright © 2015. Published by Elsevier B.V.

  5. An Experimental Measurement on Laminar Burning Velocities and Markstein Length of Iso-Butane-Air Mixtures at Ambient Conditions

    Directory of Open Access Journals (Sweden)

    Yousif Alaeldeen Altag

    2016-01-01

    Full Text Available In the present work, experimental investigation on laminar combustion of iso-butane-air mixtures was conducted in constant volume explosion vessel. The experiments were conducted at wide range of equivalence ratios ranging between Ф = 0.6 and 1.4 and atmospheric pressure of 0.1 MPa and ambient temperature of 303K. Using spherically expanding flame method, flame parameters including stretched, unstretched flame propagation speeds, laminar burning velocities and Markstein length were calculated. For laminar burning velocities the method of error bars of 95% confidence level was applied. In addition, values of Markstein lengths were measured in wide range of equivalence ratios to study the influence of stretch rate on flame instability and burning velocity. It was found that the stretched flame speed and laminar burning velocities increased with equivalence ratios and the peak value was obtained at equivalence ratio of Ф = 1.1. The Markstein length decreased with the increases in equivalence ratios, which indicates that the diffusion thermal flame instability increased at high equivalence ratios in richer mixture side. However, the total deviations in the laminar burning velocities have discrepancies of 1.2-2.9% for all investigated mixtures.

  6. Experimental Study on Bluff-Body Stabilized Premixed Flame with a Central Air/Fuel Jet

    Directory of Open Access Journals (Sweden)

    Yiheng Tong

    2017-12-01

    Full Text Available Bluff-body flame holders are commonly employed in many industrial applications. A bluff-body is usually adopted to enhance the downstream mixing of the combustion products and the fresh fuel-air mixtures, thus to improve the flame stability and to control the combustion process. In the present paper, flames stabilized by a conical-shape bluff-body flame holder with a central air/fuel jet were studied. Effects of both a central air jet and a central fuel jet on the structures and lean blowout limits of the premixed annular flames, and on the temperature on the upper surface of the bluff-body were investigated and presented. It was revealed that a central jet led to a considerable reduction of the temperature on the upper surface of the bluff-body. It was proposed to be caused by the alternation of flow structures (in the case with a central air jet altogether with the flame lifting from the burner (in the case with a central fuel jet. Thus, it might be used to solve the problem of the bluff-body with high heat loads in practical applications. The flame stability characteristics, for example the unstable flame dynamics and the lean blowout limits, varied with the injection of an air or fuel jet through the central pipe. Different blowout behaviors, being with or without the occurrence of flame split and flashing, caused by a central air jet were presented in the paper. In addition, when a small amount of central fuel jet (i.e., Uf/Ua = 0.045 was injected into the flow fields, an unsteady circular motion of the flame tip along the outer edge of the bluff-body was observed as well. Whereas, with an increase in the amount of the central fuel jet, the flame detached from the outer edge of the bluff-body and then became much more unstable. With a central air or fuel jet injecting into the flow field, premixed flames stabilized by the bluff-body became more unstable and easier to blowout.

  7. Effect of Inlet Air Temperature on Auto-Ignition of Fuels with Different Cetane Number and Volatility

    Science.gov (United States)

    2011-10-01

    diesel engine. The inlet air temperature is varied over a range of 30?C to 110?C. The fuels used are ultra-low-sulfur-diesel (ULSD), JP-8 (two blends...plots are developed to calculate the global activation energy for the auto-ignition reactions of these fuels. Correlations are developed for the ID and the mean air temperature and pressure.

  8. HAZARDOUS AIR POLLUTANTS FROM THE COMBUSTION OF AN EMULSIFIED HEAVY FUEL OIL IN A FIRETUBE BOILER

    Science.gov (United States)

    The report gives results of measuring emissions of hazardous air pollutants (HAPs) from the combustion flue gases of a No. 6 fuel oil, both with and without an emulsifying agent, in a 2.5 million Btu/hr (732 kW) firetube boiler with the purpose of determining the impacts of the e...

  9. Combustion gas properties. Part 3: Hydrogen gas fuel and dry air

    Science.gov (United States)

    Wear, J. D.; Jones, R. E.; Mcbride, B. J.; Beyerle, R. A.

    1985-01-01

    A series of computations has been made to produce the equilibrium temperature and gas composition for hydrogen gas fuel and dry air. The computed tables and figures provide combustion gas property data for pressures from 0.5 to 50 atmospheres and equivalence ratios from 0 to 2.0. Only sample tables and figures are provided in this report.

  10. Fast predictive control for air-fuel ratio of SI engines using a ...

    African Journals Online (AJOL)

    In this paper MPC based on an adaptive neural network model is attempted for air fuel ratio (AFR), in which the model is adapted on-line to cope with nonlinear dynamics and parameter uncertainties. A radial basis function (RBF) network is employed and the recursive least squares (RLS) algorithm is used for weight ...

  11. 30 CFR 7.87 - Test to determine the maximum fuel-air ratio.

    Science.gov (United States)

    2010-07-01

    ..., EVALUATION, AND APPROVAL OF MINING PRODUCTS TESTING BY APPLICANT OR THIRD PARTY Diesel Engines Intended for Use in Underground Coal Mines § 7.87 Test to determine the maximum fuel-air ratio. (a) Test procedure. (1) Couple the diesel engine to the dynamometer and connect the sampling and measurement devices...

  12. Fuel data standardization study for JP-4, JP-5, JP-7, and RJ-5 combusted in air. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Ross, J.L.

    1974-03-01

    This report summarizes a study conducted to standardize the fuel performance data used in the Ramjet and Laser Aerodynamics Division of the Air Force Aero Propulsion Laboratory. The NASA one-dimensional equilibrium (ODE) thermochemical computer program was used to generate the fuel combustion product properties contained in the tables and graphs in this report. Thermochemical equilibrium data (molecular weight, specific heat ratio, and ideal temperature rise) is presented for JP-4, JP-5, JP-7, and RJ-5 combusted in air at constant pressures of 1, 5, and 10 atmospheres, at fuel-to-air ratios from 0.025 to 0.10, and at total air temperatures from 400 to 2500R. The combustion process was assumed adiabatic and a constant fuel temperature of 298.15K was maintained. The fuel and air properties used in the calculations are presented.

  13. Analytical modeling of operating characteristics of premixing-prevaporizing fuel-air mixing passages. Volume 1: Analysis and results

    Science.gov (United States)

    Anderson, O. L.; Chiappetta, L. M.; Edwards, D. E.; Mcvey, J. B.

    1982-01-01

    A model for predicting the distribution of liquid fuel droplets and fuel vapor in premixing-prevaporizing fuel-air mixing passages of the direct injection type is reported. This model consists of three computer programs; a calculation of the two dimensional or axisymmetric air flow field neglecting the effects of fuel; a calculation of the three dimensional fuel droplet trajectories and evaporation rates in a known, moving air flow; a calculation of fuel vapor diffusing into a moving three dimensional air flow with source terms dependent on the droplet evaporation rates. The fuel droplets are treated as individual particle classes each satisfying Newton's law, a heat transfer, and a mass transfer equation. This fuel droplet model treats multicomponent fuels and incorporates the physics required for the treatment of elastic droplet collisions, droplet shattering, droplet coalescence and droplet wall interactions. The vapor diffusion calculation treats three dimensional, gas phase, turbulent diffusion processes. The analysis includes a model for the autoignition of the fuel air mixture based upon the rate of formation of an important intermediate chemical species during the preignition period.

  14. Fuel consumption in an air blower for agricultural use under different operating conditions

    Directory of Open Access Journals (Sweden)

    Robson L. da Silva

    Full Text Available ABSTRACT Evaluation of fuel consumption in internal combustion engines (ICE of agricultural machinery and equipment is important in determining the performance under various operating conditions, especially when using biofuels. This study consisted of experimental evaluation of the gasoline (petrol/ethanol consumption in a two-stroke 1-cylinder ICE, Otto cycle, functioning as an air blower for agriculture and related applications. A methodology for tests of non-automotive ICE, based on ABNT/NBR technical standards, was considered. The presented results refer to operation with commercial and non-commercial fuel blends. Characteristic curves for the tested equipment are presented, identifying consumption conditions and trend in the whole operating range of angular speeds (RPM, for five fuel blends (gasoline/ethanol. For the operating conditions of minimum and maximum angular speeds, 20 and 30% ethanol blends had the highest and lowest fuel consumptions, respectively.

  15. COD removal characteristics in air-cathode microbial fuel cells

    KAUST Repository

    Zhang, Xiaoyuan

    2015-01-01

    © 2014 Elsevier Ltd. Exoelectrogenic microorganisms in microbial fuel cells (MFCs) compete with other microorganisms for substrate. In order to understand how this affects removal rates, current generation, and coulombic efficiencies (CEs), substrate removal rates were compared in MFCs fed a single, readily biodegradable compound (acetate) or domestic wastewater (WW). Removal rates based on initial test conditions fit first-order kinetics, but rate constants varied with circuit resistance. With filtered WW (100Ω), the rate constant was 0.18h- 1, which was higher than acetate or filtered WW with an open circuit (0.10h- 1), but CEs were much lower (15-24%) than acetate. With raw WW (100Ω), COD removal proceeded in two stages: a fast removal stage with high current production, followed by a slower removal with little current. While using MFCs increased COD removal rate due to current generation, secondary processes will be needed to reduce COD to levels suitable for discharge.

  16. Calculation of the Arc Velocity Along the Polluted Surface of Short Glass Plates Considering the Air Effect

    Directory of Open Access Journals (Sweden)

    Tao Yuan

    2012-03-01

    Full Text Available To investigate the microphysics mechanism and the factors that influence arc development along a polluted surface, the arc was considered as a plasma fluid. Based on the image method and the collision ionization theory, the electric field of the arc needed to maintain movement with different degrees of pollution was calculated. According to the force of the charged particle in an arc plasma stressed under an electric field, a calculation model of arc velocity, which is dependent on the electric field of the arc head that incorporated the effects of airflow around the electrode and air resistance is presented. An experiment was carried out to measure the arc velocity, which was then compared with the calculated value. The results of the experiment indicated that the lighter the pollution is, the larger the electric field of the arc head and arc velocity is; when the pollution is heavy, the effect of thermal buoyancy that hinders arc movement increases, which greatly reduces the arc velocity.

  17. CALGRID Photochemical Modeling of Air Quality Impacts of Alternative Transportation Fuel Use in Los Angeles

    Energy Technology Data Exchange (ETDEWEB)

    Moore, G. E.; Londergan, R. J.; Fernau, M. E.

    1998-11-19

    The National Renewable Energy Laboratory has been conducting a comprehensive program to quantify and assess the air quality impacts of the emissions of ozone precursors, air toxins, and greenhouse gases from alternative fuel vehicles. This program includes both an emissions estimation component and a photochemical modeling component to study three fuels: reformulated gasoline, compressed natural gas, and 85% methanol (M85). This report describes the use of the CALGRID model in the Los Angeles modeling domain using the State-Wide Air Pollution Research Center (SAPRC90) chemical mechanism and an early version of the SAPRC93 mechanism. A variety of conclusions can be drawn from the results of this study, including results from chemical mechanism testing; development of meteorological inputs; model evaluation and comparison; and the analyses of the impacts of the emissions scenarios. The report summarizes the study's major findings in these areas.

  18. Impact of the electric compressor for automotive air conditioning system on fuel consumption and performance analysis

    Science.gov (United States)

    Zulkifli, A. A.; Dahlan, A. A.; Zulkifli, A. H.; Nasution, H.; Aziz, A. A.; Perang, M. R. M.; Jamil, H. M.; Misseri, M. N.

    2015-12-01

    Air conditioning system is the biggest auxiliary load in a vehicle where the compressor consumed the largest. Problem with conventional compressor is the cooling capacity cannot be control directly to fulfill the demand of thermal load inside vehicle cabin. This study is conducted experimentally to analyze the difference of fuel usage and air conditioning performance between conventional compressor and electric compressor of the air conditioning system in automobile. The electric compressor is powered by the car battery in non-electric vehicle which the alternator will recharge the battery. The car is setup on a roller dynamometer and the vehicle speed is varied at 0, 30, 60, 90 and 110 km/h at cabin temperature of 25°C and internal heat load of 100 and 400 Watt. The results shows electric compressor has better fuel consumption and coefficient of performance compared to the conventional compressor.

  19. The effect of air temperature, velocity and visual lean (VL) composition on the tempering times of frozen boneless beef blocks.

    Science.gov (United States)

    Brown, Tim; James, Stephen J

    2006-08-01

    Beef blocks of two compositions, 100% and 50% visual lean (VL), in standard commercial packaging with nominal dimensions of 510×390×150mm were tempered from -18°C to -3°C using air at temperatures from 3°C to -3°C and velocities of 0.5 and 5ms(-1). These conditions were then modelled using a finite difference mathematical model and the accuracy of the model assessed by comparison with the experimental results. An extended range of conditions (including an intermediate air velocity of 2ms(-1) and an intermediate composition of 75% VL) was then modelled to produce data that can be used to design tempering processes. The results show that single stage air tempering of even single blocks within their cartons needs to be a long process. In air at 3°C and 5ms(-1), blocks of 50% VL rose to deep temperatures of -10°C and -3°C after 4.0 and 22.5h, respectively, while with 100% VL 4.6 and 27.3h were required. Under these conditions, the surface layers of the meat would have spent many hours in a thawed condition that would be detrimental to both drip and optimal processing. Using lower temperatures avoids thawing and at the same time produces an optimum temperature difference for subsequent processing. However, tempering times are substantially extended. For example, times to the above temperatures using air at -1°C and 5ms(-1) were 4.8 and 37.5h for 50% VL and 5.1 and 44.5h for 100% VL.

  20. Air humidity and water pressure effects on the performance of air-cathode microbial fuel cell cathodes

    KAUST Repository

    Ahn, Yongtae

    2014-02-01

    To better understand how air cathode performance is affected by air humidification, microbial fuel cells were operated under different humidity conditions or water pressure conditions. Maximum power density decreased from 1130 ± 30 mW m-2 with dry air to 980 ± 80 mW m -2 with water-saturated air. When the cathode was exposed to higher water pressures by placing the cathode in a horizontal position, with the cathode oriented so it was on the reactor bottom, power was reduced for both with dry (1030 ± 130 mW m-2) and water-saturated (390 ± 190 mW m-2) air. Decreased performance was partly due to water flooding of the catalyst, which would hinder oxygen diffusion to the catalyst. However, drying used cathodes did not improve performance in electrochemical tests. Soaking the cathode in a weak acid solution, but not deionized water, mostly restored performance (960 ± 60 mW m-2), suggesting that there was salt precipitation in the cathode that was enhanced by higher relative humidity or water pressure. These results showed that cathode performance could be adversely affected by both flooding and the subsequent salt precipitation, and therefore control of air humidity and water pressure may need to be considered for long-term MFC operation. © 2013 Elsevier B.V. All rights reserved.

  1. Total uncertainty of low velocity thermal anemometers for measurement of indoor air movements

    DEFF Research Database (Denmark)

    Jørgensen, F.; Popiolek, Z.; Melikov, Arsen Krikor

    2004-01-01

    developed mathematical model of the anemometer in combination with a large database of representative room flows measured with a 3-D Laser Doppler anemometer (LDA). A direct comparison between measurements with a thermal anemometer and a 3-D LDA in flows of varying velocity and turbulence intensity shows...

  2. The Role of Hydrogen Bonding on Laminar Burning Velocity of Hydrous and Anhydrous Ethanol Fuel with Small Addition of n-Heptane

    Directory of Open Access Journals (Sweden)

    I Made Suarta

    2016-01-01

    Full Text Available The molecular structure of mixed hydrous and anhydrous ethanol with up to 10% v n-heptane had been studied. The burning velocity was examined in a cylindrical explosion combustion chamber. The result showed that the burning velocity of hydrous ethanol is higher than anhydrous ethanol and n-heptane at stoichiometric, rich, and very rich mixtures. The burning velocity of hydrous ethanol with n-heptane drops drastically compared to the burning velocity of anhydrous ethanol with n-heptane. It is caused by two reasons. Firstly, there was a composition change of azeotropic hydrous ethanol molecules within the mixture of fuel. Secondly, at the same volume the number of ethanol molecules in hydrous ethanol was less than in anhydrous ethanol at the same composition of the n-heptane in the mixture. At the mixture of anhydrous ethanol with n-heptane, the burning velocity decreases proportionally to the addition of the n-heptane composition. The burning velocity is between the velocities of anhydrous ethanol and n-heptane. It shows that the burning velocity of anhydrous ethanol mixed with n-heptane is only influenced by the mixture composition.

  3. An experimental study on air gasification of biomass micron fuel (BMF) in a cyclone gasifier

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Xianjun [School of Environmental Science and Engineering, Huazhong University of Science and Technology, 1037 Luoyu Rd., Wuhan 430074 (China)]|[School of Environment and Materials Engineering, Yantai University, 32 Qingquan Rd., Yantai 264005 (China); Xiao, Bo; Liu, Shiming; Hu, Zhiquan; Luo, Siyi; He, Maoyun [School of Environmental Science and Engineering, Huazhong University of Science and Technology, 1037 Luoyu Rd., Wuhan 430074 (China)

    2009-02-15

    Biomass micron fuel (BMF) produced from feedstock (energy crops, agricultural wastes, forestry residues and so on) through an efficient crushing process is a kind of powdery biomass fuel with particle size of less than 250 {mu}m. Based on the properties of BMF, a cyclone gasifier concept has been considered in our laboratory for biomass gasification. The concept combines and integrates partial oxidation, fast pyrolysis, gasification, and tar cracking, as well as a shift reaction, with the purpose of producing a high quality of gas. In this paper, characteristics of BMF air gasification were studied in the gasifier. Without outer heat energy input, the whole process is supplied with energy produced by partial combustion of BMF in the gasifier using a hypostoichiometric amount of air. The effects of equivalence ratio (ER) and biomass particle size on gasification temperature, gas composition, gas yield, low-heating value (LHV), carbon conversion and gasification efficiency were studied. The results showed that higher ER led to higher gasification temperature and contributed to high H{sub 2}-content, but too high ER lowered fuel gas content and degraded fuel gas quality. A smaller particle was more favorable for higher gas yield, LHV, carbon conversion and gasification efficiency. And the BMF air gasification in the cyclone gasifier with the energy self-sufficiency is reliable. (author)

  4. Feature of high velocity oxygen-fuel flame spraying; Kosoku flame yoshaho no tokucho to sono oyo

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, Y.; Sakaki, K. [Shinshu University, Nagano (Japan). Faculty of Engineering

    1996-05-01

    A description is given about the high velocity flame spraying method. In this method, fuel and oxygen under high pressure are supplied to a spraying gun, a supersonic stream of flame is jetted out of a fine nozzle, and spray particles are injected into the flame to impinge on the substrate surface at a very high speed for the formation of a coating. This method is advantageous in that the spray particles are higher in flying speed than in other spraying methods, that the produced coating is dense and close and excellent in adhesion, that the flame temperature is relatively low, and that the spray material is suppressed in terms of phase transformation, oxidation, and decomposition. This spraying technique is disadvantageous in that the spray materials that it can use are limited in variety because this method meets difficulties in spraying upon high melting-point metal or ceramics. This paper also outlines the spraying devices (chamber combustion type and throat combustion type) and the characteristics of produced coatings, and spray materials and their application (centering about carbide thermit spraying) are mentioned. 23 refs., 6 figs., 2 tabs.

  5. Application of High-Velocity Oxygen-Fuel (HVOF Spraying to the Fabrication of Yb-Silicate Environmental Barrier Coatings

    Directory of Open Access Journals (Sweden)

    Emine Bakan

    2017-04-01

    Full Text Available From the literature, it is known that due to their glass formation tendency, it is not possible to deposit fully-crystalline silicate coatings when the conventional atmospheric plasma spraying (APS process is employed. In APS, rapid quenching of the sprayed material on the substrate facilitates the amorphous deposit formation, which shrinks when exposed to heat and forms pores and/or cracks. This paper explores the feasibility of using a high-velocity oxygen-fuel (HVOF process for the cost-effective fabrication of dense, stoichiometric, and crystalline Yb2Si2O7 environmental barrier coatings. We report our findings on the HVOF process optimization and its resultant influence on the microstructure development and crystallinity of the Yb2Si2O7 coatings. The results reveal that partially crystalline, dense, and vertical crack-free EBCs can be produced by the HVOF technique. However, the furnace thermal cycling results revealed that the bonding of the Yb2Si2O7 layer to the Silicon bond coat needs to be improved.

  6. Air Quality and Acute Respiratory Illness in Biomass Fuel using homes in Bagamoyo, Tanzania

    Directory of Open Access Journals (Sweden)

    Satoshi Nakai

    2007-03-01

    Full Text Available Respiratory Diseases are public health concern worldwide. The diseases have been associated with air pollution especially indoor air pollution from biomass fuel burning in developing countries. However, researches on pollution levels and on association of respiratory diseases with biomass fuel pollution are limited. A study was therefore undertaken to characterize the levels of pollutants in biomass fuel using homes and examine the association between biomass fuel smoke exposure and Acute Respiratory Infection (ARI disease in Nianjema village in Bagamoyo, Tanzania. Pollution was assessed by measuring PM10, NO2, and CO concentrations in kitchen, living room and outdoors. ARI prevalence was assessed by use of questionnaire which gathered health information for all family members under the study. Results showed that PM10, NO2, and CO concentrations were highest in the kitchen and lowest outdoors. Kitchen concentrations were highest in the kitchen located in the living room for all pollutants except CO. Family size didn’t have effect on the levels measured in kitchens. Overall ARI prevalence for cooks and children under age 5 making up the exposed group was 54.67% with odds ratio (OR of 5.5; 95% CI 3.6 to 8.5 when compared with unexposed men and non-regular women cooks. Results of this study suggest an association between respiratory diseases and exposure to domestic biomass fuel smoke, but further studies with improved design are needed to confirm the association.

  7. Pressurized air cathodes for enhanced stability and power generation by microbial fuel cells

    KAUST Repository

    He, Weihua

    2016-09-30

    Large differences between the water and air pressure in microbial fuel cells (MFCs) can deform and damage cathodes. To avoid deformation, the cathode air pressure was controlled to balance pressure differences between the air and water. Raising the air pressures from 0 to 10 kPa at a set cathode potential of −0.3 V (versus Ag/AgCl) enhanced cathode performance by 17%, but pressures ≥25 kPa decreased current and resulted in air leakage into the solution. Matching the air pressure with the water pressure avoided cathode deformation and improved performance. The maximum power density increased by 15%, from 1070 ± 20 to 1230 ± 70 mW m, with balanced air and water pressures of 10–25 kPa. Oxygen partial pressures ≥12.5 kPa in the cathode compartment maintained the oxygen reduction rate to be within 92 ± 1% of that in ambient air. The use of pressurized air flow through the cathode compartments can enable closer spacing of the cathodes compared to passive gas transfer systems, which could make the reactor design more compact. The energy cost of pressurizing the cathodes was estimated to be smaller than the increase in power that resulted from the use of pressurized cathodes.

  8. Power plant fuel switching and air quality in a tropical, forested environment

    Science.gov (United States)

    Medeiros, Adan S. S.; Calderaro, Gisele; Guimarães, Patricia C.; Magalhaes, Mateus R.; Morais, Marcos V. B.; Rafee, Sameh A. A.; Ribeiro, Igor O.; Andreoli, Rita V.; Martins, Jorge A.; Martins, Leila D.; Martin, Scot T.; Souza, Rodrigo A. F.

    2017-07-01

    How a changing energy matrix for electricity production affects air quality is considered for an urban region in a tropical, forested environment. Manaus, the largest city in the central Amazon Basin of Brazil, is in the process of changing its energy matrix for electricity production from fuel oil and diesel to natural gas over an approximately 10-year period, with a minor contribution by hydropower. Three scenarios of urban air quality, specifically afternoon ozone concentrations, were simulated using the Weather Research and Forecasting (WRF-Chem) model. The first scenario used fuel oil and diesel for electricity production, which was the reality in 2008. The second scenario was based on the fuel mix from 2014, the most current year for which data were available. The third scenario considered nearly complete use of natural gas for electricity production, which is the anticipated future, possibly for 2018. For each case, inventories of anthropogenic emissions were based on electricity generation, refinery operations, and transportation. Transportation and refinery operations were held constant across the three scenarios to focus on effects of power plant fuel switching in a tropical context. The simulated NOx and CO emissions for the urban region decrease by 89 and 55 %, respectively, after the complete change in the energy matrix. The results of the simulations indicate that a change to natural gas significantly decreases maximum afternoon ozone concentrations over the population center, reducing ozone by > 70 % for the most polluted days. The sensitivity of ozone concentrations to the fuel switchover is consistent with a NOx-limited regime, as expected for a tropical forest having high emissions of biogenic volatile organic compounds, high water vapor concentrations, and abundant solar radiation. There are key differences in a shifting energy matrix in a tropical, forested environment compared to other world environments. Policies favoring the burning of

  9. Free air breathing proton exchange membrane fuel cell: Thermal behavior characterization near freezing temperature

    Science.gov (United States)

    Higuita Cano, Mauricio; Kelouwani, Sousso; Agbossou, Kodjo; Dubé, Yves

    2014-01-01

    A free air breathing fuel cell thermal model is developed. This proton exchange membrane fuel cell (PEMFC) has been selected as the basis for the study due to its use in automotive applications. The blowers integrated to the stack provide the required air flow for hydrogen oxidation as well as the fluid for the stack thermal regulation. Hence, their controls are a key point for keeping the system to maximum efficiency. Using well-known fuel cell electrochemistry, a dynamic thermal model near freezing temperature, which includes the stack physical parameters, is developed and validated. In addition to these parameters, only the inlet and outlet air temperatures are used to derive the model. Experimental validation with a real 1 kW free air breathing PEMFC has demonstrated that the model can reasonably track the stack internal temperature with a maximum deviation between the observed and the estimated temperatures of 5%. Therefore, the proposed method will allow the development of efficient blower management systems for PEMFC efficiency improvement.

  10. Predicting the effects of nanoscale cerium additives in diesel fuel on regional-scale air quality.

    Science.gov (United States)

    Erdakos, Garnet B; Bhave, Prakash V; Pouliot, George A; Simon, Heather; Mathur, Rohit

    2014-11-04

    Diesel vehicles are a major source of air pollutant emissions. Fuel additives containing nanoparticulate cerium (nCe) are currently being used in some diesel vehicles to improve fuel efficiency. These fuel additives also reduce fine particulate matter (PM2.5) emissions and alter the emissions of carbon monoxide (CO), nitrogen oxides (NOx), and hydrocarbon (HC) species, including several hazardous air pollutants (HAPs). To predict their net effect on regional air quality, we review the emissions literature and develop a multipollutant inventory for a hypothetical scenario in which nCe additives are used in all on-road and nonroad diesel vehicles. We apply the Community Multiscale Air Quality (CMAQ) model to a domain covering the eastern U.S. for a summer and a winter period. Model calculations suggest modest decreases of average PM2.5 concentrations and relatively larger decreases in particulate elemental carbon. The nCe additives also have an effect on 8 h maximum ozone in summer. Variable effects on HAPs are predicted. The total U.S. emissions of fine-particulate cerium are estimated to increase 25-fold and result in elevated levels of airborne cerium (up to 22 ng/m3), which might adversely impact human health and the environment.

  11. 78 FR 20881 - Control of Air Pollution From Motor Vehicles: Tier 3 Motor Vehicle Emission and Fuel Standards...

    Science.gov (United States)

    2013-04-08

    ... AGENCY 40 CFR Part 80 RIN 2060-AQ86 Control of Air Pollution From Motor Vehicles: Tier 3 Motor Vehicle... hearings to be held for the proposed rule ``Control of Air Pollution from Motor Vehicles: Tier 3 Motor... 2017, as part of a systems approach to addressing the impacts of motor vehicles and fuels on air...

  12. Determining air quality and greenhouse gas impacts of hydrogen infrastructure and fuel cell vehicles.

    Science.gov (United States)

    Stephens-Romero, Shane; Carreras-Sospedra, Marc; Brouwer, Jacob; Dabdub, Donald; Samuelsen, Scott

    2009-12-01

    Adoption of hydrogen infrastructure and hydrogen fuel cell vehicles (HFCVs) to replace gasoline internal combustion engine (ICE) vehicles has been proposed as a strategy to reduce criteria pollutant and greenhouse gas (GHG) emissions from the transportation sector and transition to fuel independence. However, it is uncertain (1) to what degree the reduction in criteria pollutants will impact urban air quality, and (2) how the reductions in pollutant emissions and concomitant urban air quality impacts compare to ultralow emission gasoline-powered vehicles projected for a future year (e.g., 2060). To address these questions, the present study introduces a "spatially and temporally resolved energy and environment tool" (STREET) to characterize the pollutant and GHG emissions associated with a comprehensive hydrogen supply infrastructure and HFCVs at a high level of geographic and temporal resolution. To demonstrate the utility of STREET, two spatially and temporally resolved scenarios for hydrogen infrastructure are evaluated in a prototypical urban airshed (the South Coast Air Basin of California) using geographic information systems (GIS) data. The well-to-wheels (WTW) GHG emissions are quantified and the air quality is established using a detailed atmospheric chemistry and transport model followed by a comparison to a future gasoline scenario comprised of advanced ICE vehicles. One hydrogen scenario includes more renewable primary energy sources for hydrogen generation and the other includes more fossil fuel sources. The two scenarios encompass a variety of hydrogen generation, distribution, and fueling strategies. GHG emissions reductions range from 61 to 68% for both hydrogen scenarios in parallel with substantial improvements in urban air quality (e.g., reductions of 10 ppb in peak 8-h-averaged ozone and 6 mug/m(3) in 24-h-averaged particulate matter concentrations, particularly in regions of the airshed where concentrations are highest for the gasoline scenario).

  13. On the effects of vertical air velocity on winter precipitation types

    Directory of Open Access Journals (Sweden)

    J. M. Thériault

    2007-01-01

    Full Text Available The various precipitation types formed within winter storms (such as snow, wet snow and freezing rain often lead to very hazardous weather conditions. These types of precipitation often occur during the passage of a warm front as a warm air mass ascends over a cold air mass. To address this issue further, we used a one-dimensional kinematic cloud model to simulate this gentle ascent (≤10 cm/s of warm air. The initial temperature profile has an above 0°C inversion, a lower subfreezing layer, and precipitation falls from above the temperature inversion. The cloud model is coupled to a double-moment microphysics scheme that simulates the production of various types of winter precipitation. The results are compared with those from a previous study carried out in still air. Based on the temporal evolution of surface precipitation, snow reaches the surface significantly faster than in still air whereas other precipitation types including freezing rain and ice pellets have a shorter duration. Overall, even weak background vertical ascent has an important impact on the precipitation reaching the surface, the time of the elimination of the melting layer, and also the evolution of the lower subfreezing layer.

  14. Recent decreases in fossil-fuel emissions of ethane and methane derived from firn air.

    Science.gov (United States)

    Aydin, Murat; Verhulst, Kristal R; Saltzman, Eric S; Battle, Mark O; Montzka, Stephen A; Blake, Donald R; Tang, Qi; Prather, Michael J

    2011-08-10

    Methane and ethane are the most abundant hydrocarbons in the atmosphere and they affect both atmospheric chemistry and climate. Both gases are emitted from fossil fuels and biomass burning, whereas methane (CH(4)) alone has large sources from wetlands, agriculture, landfills and waste water. Here we use measurements in firn (perennial snowpack) air from Greenland and Antarctica to reconstruct the atmospheric variability of ethane (C(2)H(6)) during the twentieth century. Ethane levels rose from early in the century until the 1980s, when the trend reversed, with a period of decline over the next 20 years. We find that this variability was primarily driven by changes in ethane emissions from fossil fuels; these emissions peaked in the 1960s and 1970s at 14-16 teragrams per year (1 Tg = 10(12) g) and dropped to 8-10 Tg  yr(-1) by the turn of the century. The reduction in fossil-fuel sources is probably related to changes in light hydrocarbon emissions associated with petroleum production and use. The ethane-based fossil-fuel emission history is strikingly different from bottom-up estimates of methane emissions from fossil-fuel use, and implies that the fossil-fuel source of methane started to decline in the 1980s and probably caused the late twentieth century slow-down in the growth rate of atmospheric methane.

  15. Gaseous fuels production from dried sewage sludge via air gasification.

    Science.gov (United States)

    Werle, Sebastian; Dudziak, Mariusz

    2014-07-01

    Gasification is a perspective alternative method of dried sewage sludge thermal treatment. For the purpose of experimental investigations, a laboratory fixed-bed gasifier installation was designed and built. Two sewage sludge (SS) feedstocks, taken from two typical Polish wastewater treatment systems, were analysed: SS1, from a mechanical-biological wastewater treatment system with anaerobic stabilization (fermentation) and high temperature drying; and (SS2) from a mechanical-biological-chemical wastewater treatment system with fermentation and low temperature drying. The gasification results show that greater oxygen content in sewage sludge has a strong influence on the properties of the produced gas. Increasing the air flow caused a decrease in the heating value of the produced gas. Higher hydrogen content in the sewage sludge (from SS1) affected the produced gas composition, which was characterized by high concentrations of combustible components. In the case of the SS1 gasification, ash, charcoal, and tar were produced as byproducts. In the case of SS2 gasification, only ash and tar were produced. SS1 and solid byproducts from its gasification (ash and charcoal) were characterized by lower toxicity in comparison to SS2. However, in all analysed cases, tar samples were toxic. © The Author(s) 2014.

  16. A COMPUTATIONAL FLUID DYNAMICS ANALYSIS OF AIR FLOW THROUGH A TELECOM BACK-UP UNIT POWERED BY AN AIR-COOLED PROTON EXCHANGE MEMBRANE FUEL CELL

    OpenAIRE

    Gao, Xin; Berning, Torsten; Kær, Søren Knudsen

    2016-01-01

    Proton exchange membrane fuel cells (PEMFC’s) are currently being commercialized for various applications ranging from automotive to stationary such as powering telecom back-up units. In PEMFC’s, oxygen from air is internally combined with hydrogen to form water and produce electricity and heat. This product heat has to be effectively removed from the fuel cell, and while automotive fuel cells are usually liquid-cooled using a secondary coolant loop similar to the internal combustion engines,...

  17. Enthalpy analysis and Heat Exchanger Sizing of an Air-cooled Proton Exchange Membrane Fuel Cell System

    DEFF Research Database (Denmark)

    Gao, Xin; Berning, Torsten; Kær, Søren Knudsen

    the warmer exhaust air is used to pre-heat and also humidify the incoming colder and dryer air stream using an enthalpy wheel. It is important to thermodynamically understand such a fuel cell system, and in this work the enthalpy streams and the humidity stream are followed throughout the fuel cell system...... simulations have been carried out to better understand the distribution of the reactant air over the fuel cell stack and the resulting temperature distribution across the stack. These results suggest that the humidifying function of the current enthalpy wheel is negligible and a smaller enthalpy wheel...

  18. Dry deposition models for radionuclides dispersed in air: a new approach for deposition velocity evaluation schema

    Science.gov (United States)

    Giardina, M.; Buffa, P.; Cervone, A.; De Rosa, F.; Lombardo, C.; Casamirra, M.

    2017-11-01

    In the framework of a National Research Program funded by the Italian Minister of Economic Development, the Department of Energy, Information Engineering and Mathematical Models (DEIM) of Palermo University and ENEA Research Centre of Bologna, Italy are performing several research activities to study physical models and mathematical approaches aimed at investigating dry deposition mechanisms of radioactive pollutants. On the basis of such studies, a new approach to evaluate the dry deposition velocity for particles is proposed. Comparisons with some literature experimental data show that the proposed dry deposition scheme can capture the main phenomena involved in the dry deposition process successfully.

  19. Experimental investigation on a turbine compressor for air supply system of a fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Matsuda, Masayasu [Sumitomo Heavy Industries, Ltd., Yokosuka (Japan); Tsuchiyama, Syozo [Shipbuilding Research Association, Minato-ku, Tokyo (Japan)

    1996-12-31

    This report covers part of a joint study on a PEFC propulsion system for surface ships, summarized in a presentation to this Seminar, entitled {open_quotes}Study on a Polymer Electrolyte Fuel Cell (PEFC) Propulsion System for Surface Ships{close_quotes}, and which envisages application to a 1,500 DWT cargo vessel. The aspect treated here concerns a study on the air supply system for the PEFC, with particular reference to system components.

  20. Control device for controlling the fuel-air ratio of an internal combustion engine

    Energy Technology Data Exchange (ETDEWEB)

    Rado, W.G.

    1982-04-08

    The invention deals with a control device for controlling the fuel-air ratio of a combustion engine. The oxygen content in the exhaust gas is measured in certain time intervals thereby determining whether a pre-determined number of measurements shows the result ''lean'' or ''rich'', the control device adjusts the mixture according to the measured results if necessary.

  1. JV Task 75 - Lignite Fuel Enhancement via Air-Jigging Technology

    Energy Technology Data Exchange (ETDEWEB)

    Jason Lamb; Steven Benson; Joshua Stanislowski

    2007-03-01

    Several North Dakota lignite coals from the Falkirk Mine were processed in a 5-ton-per-hour dry coal-cleaning plant. The plant uses air-jigging technology to separate undesirable ash constituents as well as sulfur and mercury. The results of this study indicate average ash, sulfur, and mercury reductions on a weight basis of 15%, 22%, and 28%, respectively. The average heating value was increased by 2% on a Btu/lb basis. Two computer models were used to understand the impact of a cleaned fuel on boiler performance: PCQUEST{reg_sign} and Vista. The PCQUEST model indicated improvements in slagging and fouling potential when cleaned coals are used over feed coals. The Vista model was set up to simulate coal performance and economics at Great River Energy's Coal Creek Station. In all cases, the cleaned fuel performed better than the original feed coal, with economic benefits being realized for all fuels tested. The model also indicated that one fuel considered to be unusable before cleaning was transformed into a potentially salable product. While these data indicate full-scale implementation of air-jigging technology may be beneficial to the mine and the plant, complete economic analysis, including payback period, is needed to make the final decision to implement.

  2. Biomass fuel use and indoor air pollution in homes in Malawi

    Science.gov (United States)

    Fullerton, D G; Semple, S; Kalambo, F; Suseno, A; Malamba, R; Henderson, G; Ayres, J G; Gordon, S B

    2009-01-01

    Background: Air pollution from biomass fuels in Africa is a significant cause of mortality and morbidity both in adults and children. The work describes the nature and quantity of smoke exposure from biomass fuel in Malawian homes. Methods: Markers of indoor air quality were measured in 62 homes (31 rural and 31 urban) over a typical 24 h period. Four different devices were used (one gravimetric device, two photometric devices and a carbon monoxide (HOBO) monitor. Gravimetric samples were analysed for transition metal content. Data on cooking and lighting fuel type together with information on indicators of socioeconomic status were collected by questionnaire. Results: Respirable dust levels in both the urban and rural environment were high with the mean (SD) 24 h average levels being 226 μg/m3 (206 μg/m3). Data from real-time instruments indicated respirable dust concentrations were >250 μg/m3 for >1 h per day in 52% of rural homes and 17% of urban homes. Average carbon monoxide levels were significantly higher in urban compared with rural homes (6.14 ppm vs 1.87 ppm; pIndoor air pollution levels in Malawian homes are high. Further investigation is justified because the levels that we have demonstrated are hazardous and are likely to be damaging to health. Interventions should be sought to reduce exposure to concentrations less harmful to health. PMID:19671533

  3. Seeking effective dyes for a mediated glucose-air alkaline battery/fuel cell

    Science.gov (United States)

    Eustis, Ross; Tsang, Tsz Ming; Yang, Brigham; Scott, Daniel; Liaw, Bor Yann

    2014-02-01

    A significant level of power generation from an abiotic, air breathing, mediated reducing sugar-air alkaline battery/fuel cell has been achieved in our laboratories at room temperature without complicated catalysis or membrane separation in the reaction chamber. Our prior studies suggested that mass transport limitation by the mediator is a limiting factor in power generation. New and effective mediators were sought here to improve charge transfer and power density. Forty-five redox dyes were studied to identify if any can facilitate mass transport in alkaline electrolyte solution; namely, by increasing the solubility and mobility of the dye, and the valence charge carried per molecule. Indigo dyes were studied more closely to understand the complexity involved in mass transport. The viability of water-miscible co-solvents was also explored to understand their effect on solubility and mass transport of the dyes. Using a 2.0 mL solution, 20% methanol by volume, with 100 mM indigo carmine, 1.0 M glucose and 2.5 M sodium hydroxide, the glucose-air alkaline battery/fuel cell attained 8 mA cm-2 at short-circuit and 800 μW cm-2 at the maximum power point. This work shall aid future optimization of mediated charge transfer mechanism in batteries or fuel cells.

  4. Evaluation of lower flammability limits of fuel-air-diluent mixtures using calculated adiabatic flame temperatures.

    Science.gov (United States)

    Vidal, M; Wong, W; Rogers, W J; Mannan, M S

    2006-03-17

    The lower flammability limit (LFL) of a fuel is the minimum composition in air over which a flame can propagate. Calculated adiabatic flame temperatures (CAFT) are a powerful tool to estimate the LFL of gas mixtures. Different CAFT values are used for the estimation of LFL. SuperChems is used by industry to perform flammability calculations under different initial conditions which depends on the selection of a threshold temperature. In this work, the CAFT at the LFL is suggested for mixtures of fuel-air and fuel-air-diluents. These CAFT can be used as the threshold values in SuperChems to calculate the LFL. This paper discusses an approach to evaluate the LFL in the presence of diluents such as N2 and CO2 by an algebraic method and by the application of SuperChems using CAFT as the basis of the calculations. The CAFT for different paraffinic and unsaturated hydrocarbons are presented as well as an average value per family of chemicals.

  5. CLIMATE CHANGE FUEL CELL PROGRAM UNITED STATES COAST GUARD AIR STATION CAPE COD BOURNE, MASSACHUSETTS

    Energy Technology Data Exchange (ETDEWEB)

    John K. Steckel Jr

    2004-06-30

    This report covers the first year of operation of a fuel cell power plant, installed by PPL Spectrum, Inc. (PPL) under contract with the United States Coast Guard (USCG), Research and Development Center (RDC). The fuel cell was installed at Air Station Cape Cod in Bourne, MA. The project had the support of the Massachusetts Technology Collaborative (MTC), the Department of Energy (DOE), and Keyspan Energy. PPL selected FuelCell Energy, Inc. (FCE) and its fuel cell model DFC{reg_sign}300 for the contract. Grant contributions were finalized and a contract between PPL and the USCG for the manufacture, installation, and first year's maintenance of the fuel cell was executed on September 24, 2001. As the prime contractor, PPL was responsible for all facets of the project. All the work was completed by PPL through various subcontracts, including the primary subcontract with FCE for the manufacture, delivery, and installation of the fuel cell. The manufacturing and design phases proceeded in a relatively timely manner for the first half of the project. However, during latter stages of manufacture and fuel cell testing, a variety of issues were encountered that ultimately resulted in several delivery delays, and a number of contract modifications. Final installation and field testing was completed in April and May 2003. Final acceptance of the fuel cell was completed on May 16, 2003. The fuel cell has operated successfully for more than one year. The unit achieved an availability rate of 96%, which exceeded expectations. The capacity factor was limited because the unit was set at 155 kW (versus a nameplate of 250 kW) due to the interconnection with the electric utility. There were 18 shutdowns during the first year and most were brief. The ability of this plant to operate in the island mode improved availability by 3 to 4%. Events that would normally be shutdowns were simply island mode events. The mean time between failure was calculated at 239 hours, or slightly

  6. High velocity air microabrasion for conservative tooth preparation: the principle and the clinical procedure.

    Science.gov (United States)

    Feinman, R A

    1995-10-01

    Various technologies within the dental armamentarium are applied to achieve the precise tooth preparations required for the different types of restorations. This article reintroduces the air microabrasion technique, which was first presented in 1945. The popular use of this technique had been postponed, pending the decrease in cost and development of compatible restorative materials to repair the tooth structure. With increased patient demand for less invasive preparation techniques and the decrease of the equipment cost, the use of air microbrasion for tooth preparation has been recognized. The history of the technology, its function, indications, advantages, and limitations are discussed, and a step-by-step clinical procedure is presented. The learning objective of this article is to familiarize the readers with this preparation procedure, enhancing the knowledge of preparation options.

  7. Air-breathing direct formic acid microfluidic fuel cell with an array of cylinder anodes

    Science.gov (United States)

    Zhu, Xun; Zhang, Biao; Ye, Ding-Ding; Li, Jun; Liao, Qiang

    2014-02-01

    An air-breathing direct formic acid membraneless microfluidic fuel cell using graphite cylinder arrays as the anode is proposed. The three dimensional anode volumetrically extends the reactive surface area and improves fuel utilization. The effects of spacer configuration, fuel and electrolyte concentration as well as reactant flow rate on the species transport and cell performance are investigated. The dynamic behavior of generated CO2 bubbles is visualized and its effect on current generation is discussed. The results show that the absence of two spacers adjacent to the cathode surface improves the cell performance by reducing the proton transfer resistance. The CO2 gas bubbles are constrained within the anode array and expelled by the fluid flow periodically. Proper reactant concentration and flow rate are crucial for cell operation. At optimum conditions, a maximum current density of 118.3 mA cm-3 and a peak power density of 21.5 mW cm-3 are obtained. In addition, benefit from the volumetrically stacked anodes and enhanced fuel transfer, the maximum single pass fuel utilization rate reaches up to 87.6% at the flow rate of 1 mL h-1.

  8. Air emission from the co-combustion of alternative derived fuels within cement plants: Gaseous pollutants.

    Science.gov (United States)

    Richards, Glen; Agranovski, Igor E

    2015-02-01

    Cement manufacturing is a resource- and energy-intensive industry, utilizing 9% of global industrial energy use while releasing more than 5% of global carbon dioxide (CO₂) emissions. With an increasing demand of production set to double by 2050, so too will be its carbon footprint. However, Australian cement plants have great potential for energy savings and emission reductions through the substitution of combustion fuels with a proportion of alternative derived fuels (ADFs), namely, fuels derived from wastes. This paper presents the environmental emissions monitoring of 10 cement batching plants while under baseline and ADF operating conditions, and an assessment of parameters influencing combustion. The experiential runs included the varied substitution rates of seven waste streams and the monitoring of seven target pollutants. The co-combustion tests of waste oil, wood chips, wood chips and plastic, waste solvents, and shredded tires were shown to have the minimal influence when compared to baseline runs, or had significantly reduced the unit mass emission factor of pollutants. With an increasing ADF% substitution, monitoring identified there to be no subsequent emission effects and that key process parameters contributing to contaminant suppression include (1) precalciner and kiln fuel firing rate and residence time; (2) preheater and precalciner gas and material temperature; (3) rotary kiln flame temperature; (4) fuel-air ratio and percentage of excess oxygen; and (5) the rate of meal feed and rate of clinker produced.

  9. Laminar Burning Velocities of Fuels for Advanced Combustion Engines (FACE) Gasoline and Gasoline Surrogates with and without Ethanol Blending Associated with Octane Rating

    KAUST Repository

    Mannaa, Ossama

    2016-05-04

    Laminar burning velocities of fuels for advanced combustion engines (FACE) C gasoline and of several blends of surrogate toluene reference fuels (TRFs) (n-heptane, iso-octane, and toluene mixtures) of the same research octane number are presented. Effects of ethanol addition on laminar flame speed of FACE-C and its surrogate are addressed. Measurements were conducted using a constant volume spherical combustion vessel in the constant pressure, stable flame regime at an initial temperature of 358 K and initial pressures up to 0.6 MPa with the equivalence ratios ranging from 0.8 to 1.6. Comparable values in the laminar burning velocities were measured for the FACE-C gasoline and the proposed surrogate fuel (17.60% n-heptane + 77.40% iso-octane + 5% toluene) over the range of experimental conditions. Sensitivity of flame propagation to total stretch rate effects and thermo-diffusive instability was quantified by determining Markstein length. Two percentages of an oxygenated fuel of ethanol as an additive, namely, 60 vol% and 85 vol% were investigated. The addition of ethanol to FACE-C and its surrogate TRF-1 (17.60% n-heptane + 77.40% iso-octane + 5% toluene) resulted in a relatively similar increase in the laminar burning velocities. The high-pressure measured values of Markstein length for the studied fuels blended with ethanol showed minimal influence of ethanol addition on the flame’s response to stretch rate and thermo-diffusive instability. © 2016 Taylor & Francis.

  10. A COMPUTATIONAL FLUID DYNAMICS ANALYSIS OF AIR FLOW THROUGH A TELECOM BACK-UP UNIT POWERED BY AN AIR-COOLED PROTON EXCHANGE MEMBRANE FUEL CELL

    DEFF Research Database (Denmark)

    Gao, Xin; Berning, Torsten; Kær, Søren Knudsen

    2016-01-01

    commercial telecom back-up system produced by Dantherm Power A/S, Denmark. The analysis is carried out with the commercial CFD solver Fluent (ANSYS Inc.). The fuel cell stack is modeled as a porous medium to accurately match the pressure drop, and it includes a heat source to account for the product heat......Proton exchange membrane fuel cells (PEMFC’s) are currently being commercialized for various applications ranging from automotive to stationary such as powering telecom back-up units. In PEMFC’s, oxygen from air is internally combined with hydrogen to form water and produce electricity and heat....... This product heat has to be effectively removed from the fuel cell, and while automotive fuel cells are usually liquid-cooled using a secondary coolant loop similar to the internal combustion engines, stationary fuel cell systems as they are used for telecom back-up applications often rely on excessive air fed...

  11. Morphology control of zinc regeneration for zinc-air fuel cell and battery

    Science.gov (United States)

    Wang, Keliang; Pei, Pucheng; Ma, Ze; Xu, Huachi; Li, Pengcheng; Wang, Xizhong

    2014-12-01

    Morphology control is crucial both for zinc-air batteries and for zinc-air fuel cells during zinc regeneration. Zinc dendrite should be avoided in zinc-air batteries and zinc pellets are yearned to be formed for zinc-air fuel cells. This paper is mainly to analyze the mechanism of shape change and to control the zinc morphology during charge. A numerical three-dimensional model for zinc regeneration is established with COMSOL software on the basis of ionic transport theory and electrode reaction electrochemistry, and some experiments of zinc regeneration are carried out. The deposition process is qualitatively analyzed by the kinetics Monte Carlo method to study the morphological change from the electrocrystallization point of view. Morphological evolution of deposited zinc under different conditions of direct currents and pulse currents is also investigated by simulation. The simulation shows that parametric variables of the flowing electrolyte, the surface roughness and the structure of the electrode, the charging current and mode affect morphological evolution. The uniform morphology of deposited zinc is attained at low current, pulsating current or hydrodynamic electrolyte, and granular morphology is obtained by means of an electrode of discrete columnar structure in combination with high current and flowing electrolyte.

  12. Mean droplet size and local velocity in horizontal isothermal free jets of air and water, respectively, viscous liquid in quiescent ambient air

    Energy Technology Data Exchange (ETDEWEB)

    Al Rabadi, S.; Friedel, L. [Fluid Mechanics Institute, Technical University of Hamburg-Harburg (Germany); Al Salaymeh, A. [Mechanical Engineering Department, University of Jordan (Jordan)

    2007-01-15

    Measurements using two-dimensional Phase Doppler Anemometry as well as high speed cinematography in free jets at several nozzle exit pressures and mass flow rates, show that the Sauter mean droplet diameter decreases with increasing air and liquid-phase mass flow ratio due to the increase of the air stream impact on the liquid phase. This leads to substantial liquid fragmentation, respectively primary droplet breakup, and hence, satellite droplet formation with small sizes. This trend is also significant in the case of a liquid viscosity higher than that of water. The increased liquid viscosity stabilizes the droplet formation and breakup by reducing the rate of surface perturbations and consequently droplet distortions, ultimately also leading, in total, to the formation of smaller droplets. The droplet velocity decreases with the nozzle downstream distance, basically due to the continual air entrainment and due to the collisions between the droplets. The droplet collisions may induce further liquid fragmentation and, hence, formation of a number of relatively smaller droplets respectively secondary breakup, or may induce agglomeration to comparatively larger liquid fragments that may rain out of the free jet. (Abstract Copyright [2007], Wiley Periodicals, Inc.)

  13. AIR SHIPMENT OF SPENT NUCLEAR FUEL FROM THE BUDAPEST RESEARCH REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    Dewes, J.

    2014-02-24

    The shipment of spent nuclear fuel is usually done by a combination of rail, road or sea, as the high activity of the SNF needs heavy shielding. Air shipment has advantages, e.g. it is much faster than any other shipment and therefore minimizes the transit time as well as attention of the public. Up to now only very few and very special SNF shipments were done by air, as the available container (TUK6) had a very limited capacity. Recently Sosny developed a Type C overpack, the TUK-145/C, compliant with IAEA Standard TS-R-1 for the VPVR/M type Skoda container. The TUK-145/C was first used in Vietnam in July 2013 for a single cask. In October and November 2013 a total of six casks were successfully shipped from Hungary in three air shipments using the TUK-145/C. The present paper describes the details of these shipments and formulates the lessons learned.

  14. New developments in the Electric Fuel Ltd. zinc/air system

    Science.gov (United States)

    Goldstein, Jonathan; Brown, Ian; Koretz, Binyamin

    Electric Fuel Ltd. is engaged in the design, development and commercialization of its proprietary zinc/air battery technology for electric vehicles, consumer electronic products and defence applications. To meet the challenging requirements for propelling an all-electric bus, the Vehicle Division sought a unique solution: an all electric battery-battery hybrid propulsion system. The high energy zinc/air battery is coupled with a high-power auxiliary battery. The combined system offers zero emission, high power and long range in an economically viable package. The consumer battery group has developed a high power primary zinc/air cell aimed at cellular phone users, offering extended use, convenience and low cost.

  15. Indoor air pollution from solid biomass fuels combustion in rural agricultural area of Tibet, China.

    Science.gov (United States)

    Gao, X; Yu, Q; Gu, Q; Chen, Y; Ding, K; Zhu, J; Chen, L

    2009-06-01

    In this study, we are trying to investigate the indoor air pollution and to estimate the residents' pollution exposure reduction of energy altering in rural Tibet. Daily PM(2.5) monitoring was conducted in indoor microenvironments like kitchen, living-room, bedroom, and yard in rural Tibet from December 2006 to March 2007. For kitchen air pollution, impact of two fuel types, methane and solid biomass fuels (SBFs), were compared. Questionnaire survey on the domestic energy pattern and residents' daily activity pattern was performed in Zha-nang County. Daily average PM(2.5) concentrations in kitchen, living-room, bedroom, and yard were 134.91 microg/m(3) (mean, n = 45, 95%CI 84.02, 185.80), 103.61 microg/m(3) (mean, n = 21, 95%CI 85.77, 121.45), 76.13 microg/m(3) (mean, n = 18, 95%CI 57.22, 95.04), and 78.33 microg/m(3) (mean, n = 34, 95%CI 60.00, 96.65) respectively. Using SBFs in kitchen resulted in higher indoor pollution than using methane. PM(2.5) concentrations in kitchen with dung cake, fuel wood and methane use were 117.41 microg/m(3) (mean, n = 18, 95%CI 71.03, 163.79), 271.11 microg/m(3) (mean, n = 12, 95%CI 104.74, 437.48), and 46.96 microg/m(3) (mean, n = 15, 95%CI 28.10, 65.82) respectively. Family income has significant influence on cooking energy choice, while the lack of commercial energy supply affects the energy choice for heating more. The effects of two countermeasures to improve indoor air quality were estimated in this research. One is to replace SBFs by clean energy like methane, the other is to separate the cooking place from other rooms and by applying these countermeasures, residents' exposure to particulate matters would reduce by 25-50% (methane) or 20-30% (separation) compared to the present situation. Indoor air pollution caused by solid biomass fuels is one of the most important burdens of disease in the developing countries, which attracts the attention of environment and public health researchers, as well as policy makers. This paper

  16. Power plant fuel switching and air quality in a tropical, forested environment

    Directory of Open Access Journals (Sweden)

    A. S. S. Medeiros

    2017-07-01

    Full Text Available How a changing energy matrix for electricity production affects air quality is considered for an urban region in a tropical, forested environment. Manaus, the largest city in the central Amazon Basin of Brazil, is in the process of changing its energy matrix for electricity production from fuel oil and diesel to natural gas over an approximately 10-year period, with a minor contribution by hydropower. Three scenarios of urban air quality, specifically afternoon ozone concentrations, were simulated using the Weather Research and Forecasting (WRF-Chem model. The first scenario used fuel oil and diesel for electricity production, which was the reality in 2008. The second scenario was based on the fuel mix from 2014, the most current year for which data were available. The third scenario considered nearly complete use of natural gas for electricity production, which is the anticipated future, possibly for 2018. For each case, inventories of anthropogenic emissions were based on electricity generation, refinery operations, and transportation. Transportation and refinery operations were held constant across the three scenarios to focus on effects of power plant fuel switching in a tropical context. The simulated NOx and CO emissions for the urban region decrease by 89 and 55 %, respectively, after the complete change in the energy matrix. The results of the simulations indicate that a change to natural gas significantly decreases maximum afternoon ozone concentrations over the population center, reducing ozone by > 70 % for the most polluted days. The sensitivity of ozone concentrations to the fuel switchover is consistent with a NOx-limited regime, as expected for a tropical forest having high emissions of biogenic volatile organic compounds, high water vapor concentrations, and abundant solar radiation. There are key differences in a shifting energy matrix in a tropical, forested environment compared to other world environments. Policies

  17. 78 FR 32223 - Control of Air Pollution From Motor Vehicles: Tier 3 Motor Vehicle Emission and Fuel Standards

    Science.gov (United States)

    2013-05-29

    ... AGENCY 40 CFR Parts 80, 85, 86, 600, 1036, 1037, 1065, and 1066 RIN 2060-A0 Control of Air Pollution From Motor Vehicles: Tier 3 Motor Vehicle Emission and Fuel Standards AGENCY: Environmental Protection Agency... (``EPA'') is announcing an extension of the public comment period for the proposed rule ``Control of Air...

  18. Experimental study on air-stream gasification of biomass micron fuel (BMF) in a cyclone gasifier.

    Science.gov (United States)

    Guo, X J; Xiao, B; Zhang, X L; Luo, S Y; He, M Y

    2009-01-01

    Based on biomass micron fuel (BMF) with particle size of less than 250 microm, a cyclone gasifier concept has been considered in our laboratory for biomass gasification. The concept combines and integrates partial oxidation, fast pyrolysis, gasification, and tar cracking, as well as a shift reaction, with the purpose of producing a high quality of gas. In this paper, experiments of BMF air-stream gasification were carried out by the gasifier, with energy for BMF gasification produced by partial combustion of BMF within the gasifier using a hypostoichiometric amount of air. The effects of ER (0.22-0.37) and S/B (0.15-0.59) and biomass particle size on the performances of BMF gasification and the gasification temperature were studied. Under the experimental conditions, the temperature, gas yields, LHV of the gas fuel, carbon conversion efficiency, stream decomposition and gasification efficiency varied in the range of 586-845 degrees C, 1.42-2.21 N m(3)/kg biomass, 3806-4921 kJ/m(3), 54.44%-85.45%, 37.98%-70.72%, and 36.35%-56.55%, respectively. The experimental results showed that the gasification performance was best with ER being 3.7 and S/B being 0.31 and smaller particle, as well as H(2)-content. And the BMF gasification by air and low temperature stream in the cyclone gasifier with the energy self-sufficiency is reliable.

  19. Tolerance of non-platinum group metals cathodes proton exchange membrane fuel cells to air contaminants

    Science.gov (United States)

    Reshetenko, Tatyana; Serov, Alexey; Artyushkova, Kateryna; Matanovic, Ivana; Sarah Stariha; Atanassov, Plamen

    2016-08-01

    The effects of major airborne contaminants (SO2, NO2 and CO) on the spatial performance of Fe/N/C cathode membrane electrode assemblies were studied using a segmented cell system. The injection of 2-10 ppm SO2 in air stream did not cause any performance decrease and redistribution of local currents due to the lack of stably adsorbed SO2 molecules on Fe-Nx sites, as confirmed by density functional theory (DFT) calculations. The introduction of 5-20 ppm of CO into the air stream also did not affect fuel cell performance. The exposure of Fe/N/C cathodes to 2 and 10 ppm NO2 resulted in performance losses of 30 and 70-75 mV, respectively. DFT results showed that the adsorption energies of NO2 and NO were greater than that of O2, which accounted for the observed voltage decrease and slight current redistribution. The cell performance partially recovered when the NO2 injection was stopped. The long-term operation of the fuel cells resulted in cell performance degradation. XPS analyses of Fe/N/C electrodes revealed that the performance decrease was due to catalyst degradation and ionomer oxidation. The latter was accelerated in the presence of air contaminants. The details of the spatial performance and electrochemical impedance spectroscopy results are presented and discussed.

  20. Design, fabrication and testing of an air-breathing micro direct methanol fuel cell with compound anode flow field

    Science.gov (United States)

    Wang, Luwen; Zhang, Yufeng; Zhao, Youran; An, Zijiang; Zhou, Zhiping; Liu, Xiaowei

    2011-10-01

    An air-breathing micro direct methanol fuel cell (μDMFC) with a compound anode flow field structure (composed of the parallel flow field and the perforated flow field) is designed, fabricated and tested. To better analyze the effect of the compound anode flow field on the mass transfer of methanol, the compound flow field with different open ratios (ratio of exposure area to total area) and thicknesses of current collectors is modeled and simulated. Micro process technologies are employed to fabricate the end plates and current collectors. The performances of the μDMFC with a compound anode flow field are measured under various operating parameters. Both the modeled and the experimental results show that, comparing the conventional parallel flow field, the compound one can enhance the mass transfer resistance of methanol from the flow field to the anode diffusion layer. The results also indicate that the μDMFC with an anode open ratio of 40% and a thickness of 300 µm has the optimal performance under the 7 M methanol which is three to four times higher than conventional flow fields. Finally, a 2 h stability test of the μDMFC is performed with a methanol concentration of 7 M and a flow velocity of 0.1 ml min-1. The results indicate that the μDMFC can work steadily with high methanol concentration.

  1. Utilization of ventilation air methane as a supplementary fuel at a circulating fluidized bed combustion boiler.

    Science.gov (United States)

    You, Changfu; Xu, Xuchang

    2008-04-01

    Ventilation air methane (VAM) accounts for 60-80% of the total emissions from coal mining activities in China, which is of serious greenhouse gas concerns as well as a waste of valuable fuel sources. This contribution evaluates the use of the VAM utilization methods as a supplementary fuel at a circulating fluidized bed combustion boiler. The paper describes the system design and discusses some potential technical challenges such as methane oxidation rate, corrosion, and efficiency. Laboratory experimentation has shown that the VAM can be burnt completely in circulated fluidized bed furnaces, and the VAM oxidation does not obviously affect the boiler operation when the methane concentration is less than 0.6%. The VAM decreased the incomplete combustion loss for the circulating fluidized bed combustion furnace. The economic benefit from the coal saving insures that the proposed system is more economically feasible.

  2. An approximate estimation of velocity profiles and turbulence factor models for air-flows along the exterior of TEFC induction motors

    Directory of Open Access Journals (Sweden)

    Klimenta Dardan O.

    2017-01-01

    Full Text Available Compared to a number of other existing correlations for heat transfer, the empirical correlations for forced convection from a short horizontal cylinder in axial air-flows usually do not involve the effects of changes in air-flow velocity and/or air-flow turbulence. Therefore, a common analysis of the heat transfer by using only one energy balance equation for entire outer surface of a solid is considered insufficient for induction motor applications because it fails to include aforementioned effects. This paper presents a novel, empirically-based methodology to estimate approximately the values of air-flow velocities and turbulence factors, that is, velocity profiles and turbulence factor models for stationary horizontal cylinders with and without fins (frame and two end-shields in axial air-flows. These velocity profiles and turbulence factor models can then be used in analytical modelling of steady-state heat transfer from the exterior of totally enclosed fan-cooled induction motors.

  3. Computational modeling of air-breathing microfluidic fuel cells with flow-over and flow-through anodes

    Science.gov (United States)

    Zhang, Biao; Ye, Ding-ding; Sui, Pang-Chieh; Djilali, Ned; Zhu, Xun

    2014-08-01

    A three-dimensional computational model for air-breathing microfluidic fuel cells (AMFCs) with flow-over and flow-through anodes is developed. The coupled multiphysics phenomena of fluid flow, species transport and electrochemical reactions are resolved numerically. The model has been validated against experimental data using an in-house AMFC prototype with a flow-through anode. Characteristics of fuel transfer and fuel crossover for both types of anodes are investigated. The model results reveal that the fuel transport to the flow-over anode is intrinsically limited by the fuel concentration boundary layer. Conversely, fuel transport for the flow-through anode is convectively enhanced by the permeate flow, and no concentration boundary layer is observed. An unexpected additional advantage of the flow-through anode configuration is lower parasitic (crossover) current density than the flow-over case at practical low flow rates. Cell performance of the flow-through case is found to be limited by reaction kinetics. The present model provides insights into the fuel transport and fuel crossover in air-breathing microfluidic fuel cells and provides guidance for further design and operation optimization.

  4. A Rechargeable Li-Air Fuel Cell Battery Based on Garnet Solid Electrolytes

    Science.gov (United States)

    Sun, Jiyang; Zhao, Ning; Li, Yiqiu; Guo, Xiangxin; Feng, Xuefei; Liu, Xiaosong; Liu, Zhi; Cui, Guanglei; Zheng, Hao; Gu, Lin; Li, Hong

    2017-01-01

    Non-aqueous Li-air batteries have been intensively studied in the past few years for their theoretically super-high energy density. However, they cannot operate properly in real air because they contain highly unstable and volatile electrolytes. Here, we report the fabrication of solid-state Li-air batteries using garnet (i.e., Li6.4La3Zr1.4Ta0.6O12, LLZTO) ceramic disks with high density and ionic conductivity as the electrolytes and composite cathodes consisting of garnet powder, Li salts (LiTFSI) and active carbon. These batteries run in real air based on the formation and decomposition at least partially of Li2CO3. Batteries with LiTFSI mixed with polyimide (PI:LiTFSI) as a binder show rechargeability at 200 °C with a specific capacity of 2184 mAh g-1carbon at 20 μA cm-2. Replacement of PI:LiTFSI with LiTFSI dissolved in polypropylene carbonate (PPC:LiTFSI) reduces interfacial resistance, and the resulting batteries show a greatly increased discharge capacity of approximately 20300 mAh g-1carbon and cycle 50 times while maintaining a cutoff capacity of 1000 mAh g-1carbon at 20 μA cm-2 and 80 °C. These results demonstrate that the use of LLZTO ceramic electrolytes enables operation of the Li-air battery in real air at medium temperatures, leading to a novel type of Li-air fuel cell battery for energy storage.

  5. A new air-fuel WSGGM for better utility boiler simulation, design and optimization

    DEFF Research Database (Denmark)

    Yin, Chungen

    Radiation is the principal mode of heat transfer in utility boiler furnaces. Models for radiative properties play a vital role in reliable simulations of utility boilers and simulation-based design and optimization. The weighted sum of gray gases model (WSGGM) is one of the most widely used models...... and Vervisch (1983) for higher temperatures until 3000K. This paper refines the WSGGM in terms of accuracy, completeness and implementation, and demonstrates the use and impacts of the refined model in CFD simulation of a conventional air-fuel utility boiler....

  6. Numerical Simulations of Dynamic Deformation of Air Transport Fresh Fuel Package in Accidental Impacts

    Energy Technology Data Exchange (ETDEWEB)

    Ryabov, A. A.; Romanov, V. I.; Sotskov, G. I.

    2003-02-24

    Results of numerical investigations of dynamic deformations of packages for air transportation of fresh nuclear fuel from Nuclear Power Plants are presented for the cases of axis and on-side impacts with hard surface at a speed of 90 meters/second (m/s). Modeling results on deformed structure shapes and kinematical parameters (displacements, decelerations, cramping) for axis impact are compared with experimental data. Use of this numerical-experimental technology gives new capabilities to analyze correctly the safety of such a package in accidents through modeling, which does not require implantation of expensive testing, thereby saving money.

  7. Particle swarm optimization applied to the co-design of a fuel cell air circuit

    Energy Technology Data Exchange (ETDEWEB)

    Sari, Ali; Espanet, Christophe; Hissel, Daniel [University of Franche-Comte, FEMTO-ST Laboratory, ENISYS Department, FCLAB, Rue Thierry Mieg, 90010 Belfort Cedex (France)

    2008-04-15

    This paper presents an optimization approach applied to a whole fuel cell (FC) air supply system including its geometry and its control. The aim is to optimize its power consumption along with its mass. Particle swarm optimization (PSO) algorithm is used to define the design parameters of both permanent magnet synchronous motor (PMSM) and a fuzzy logic controller (FLC). The results are compared with those obtained by a sequential optimization process and advantages of co-design optimization approach are clearly shown. Indeed, a significant reduction of the objective function (made up on both motor mass and energy consumption) on a considered operating cycle can be obtained. (author)

  8. Estimation of Individual Cylinder Air-Fuel Ratio in Gasoline Engine with Output Delay

    OpenAIRE

    Wang, Changhui; Liu, Zhiyuan

    2016-01-01

    The estimation of the individual cylinder air-fuel ratio (AFR) with a single universal exhaust gas oxygen (UEGO) sensor installed in the exhaust pipe is an important issue for the cylinder-to-cylinder AFR balancing control, which can provide high-quality torque generation and reduce emissions in multicylinder engine. In this paper, the system dynamic for the gas in exhaust pipe including the gas mixing, gas transport, and sensor dynamics is described as an output delay system, and a new metho...

  9. A New Control and Design of PEM Fuel Cell System Powered Diffused Air Aeration System

    Directory of Open Access Journals (Sweden)

    Hassen T. Dorrah

    2012-06-01

    Full Text Available The goal of aquaculture ponds is to maximize production and profits while holding labor and management efforts to the minimum. Poor water quality in most ponds causes risk of fish kills, disease outbreaks which lead to minimization of pond production. Dissolved Oxygen (DO is considered to be among the most important water quality parameters in fish culture. Fish ponds in aquaculture farms are usually located in remote areas where grid lines are at far distance. Aeration of ponds is required to prevent mortality and to intensify production, especially when feeding is practical, and in warm regions. To increase pond production it is necessary to control dissolved oxygen. Aeration offers the most immediate and practical solution to water quality problems encountered at higher stocking and feeding rates. Many units of aeration system are electrical units so using a continuous, high reliability, affordable, and environmentally friendly power sources is necessary. Fuel cells have become one of the major areas of research in the academia and the industry. Aeration of water by using PEM fuel cell power is not only a new application of the renewable energy, but also, it provides an affordable method to promote biodiversity in stagnant ponds and lakes. This paper presents a new design and control of PEM fuel cell powered a diffused air aeration system for a shrimp farm in Mersa Matruh in Egypt. Also Artificial intelligence (AI control techniques are used to control the fuel cell output power by controlling its input gases flow rate. Moreover the mathematical modeling and simulation of PEM fuel cell is introduced. A comparative study is applied between the performance of fuzzy logic controller (FLC and neural network controller (NNC. The results show the effectiveness of NNC over FLC.

  10. Improved combustion performance of waste-fired FB-boilers -The influence of the dynamics of the bed on the air-/fuel interaction; Foerbaettrad foerbraenningsprestanda vid avfallsfoerbraenning i FB-pannor -Baeddynamikens inverkan paa luft-/braensleomblandningen

    Energy Technology Data Exchange (ETDEWEB)

    Olsson, Johanna (Hoegskolan i Boraas (Sweden)); Pallares, David; Thunman, Henrik; Johnsson, Filip (Chalmers (Sweden)); Andersson, Bengt-Aake (E.on/Hoegskolan i Boraas (Sweden)); Victoren, Anders (Metso Power AB (Sweden)); Johansson, Andreas (SP, Boraas (Sweden))

    2010-07-01

    One of the key benefits of fluidized bed combustion is that the bed - through mixing of fuel and air and accumulated heat - facilitates combustion at low stoichiometry and with low emissions. Even so, it is not unusual that waste-fired FB-boilers are operated at 6-8% oxygen that corresponds to 30-40% higher flows of gas than theoretically needed. In addition to that and in comparison to grate furnaces, FB-boiler can cause high pressure drop losses because of the fluidization of the bottom bed, which in turn are associated with high costs for power (fans). This work aims therefore at increasing the knowledge for how the dynamics of the bed affects the air and fuel mixture. Methods to explain and characterize the phenomenon have been derived within this work showing: - Distribution of air in a bed for various cases and the influence of pressure drop, bed height and fluidization velocity - A semi-empiric method to calculate an even bubble distribution - The relation between fluidization and fuel distribution for various fluidization flows and fuels - Dispersion rates for various fuels - Volatilization rates for waste in relation to biomass The result can be useful when optimizing units, for instance through finding as low pressure drops as possible with an even bubble distribution, low risk for sintering and unwanted emissions. The work has thereby reached its ultimate goal of increasing the generic knowledge about waste combustion in FB-boiler

  11. Ambient Fine Particulate (PM2.5) Air Pollution Attributable to Household Cooking Fuel in Asia

    Science.gov (United States)

    Chafe, Z.; Mehta, S.; Smith, K. R.

    2011-12-01

    Using the Greenhouse Gas and Air Pollution Interactions and Synergies (GAINS) model, hosted by the International Institute for Applied Systems Analysis (IIASA), we estimate the proportion of fine particulate ambient air pollution (PM2.5) attributable to household fuel use for cooking in Asia. This analysis considers primary anthropogenic PM2.5 emissions in two years: 1990 and 2005. Only emissions from household cooking fuels-not heating or lighting-are considered. Due to data availability, this analysis focuses solely on Asian countries, notably India and China which are home to about half of the households using solid fuel use worldwide. Forest and grassland fires, dust, and other "natural" particle sources were omitted from this analysis. The impact of emission sources on secondary particles from aerosol precursors was not determined. In China, the proportion of total primary anthropogenic PM2.5 attributable to household cooking decreased from 44% to 31% between 1990 and 2005. In India, the percent of primary anthropogenic PM2.5 emissions attributable to household cooking decreased from 55% to 49% between 1990 and 2005. Total mass change in primary anthropogenic PM2.5 emissions was much more variable by state in India, between 1990 and 2005, than by province in China (where there was a general downward trend in the total mass emitted). Similarly, growth in industrial emissions was much more variable at the sub-national level, between 1990 and 2005, in India than in China. Energy production played a more prominent role in the growth of primary anthropogenic PM2.5 emissions in India than it did in China. Forward-looking GAINS scenarios show that the contribution of household cooking to total primary anthropogenic PM2.5 emissions is much greater than that from on-road transport in India and China between 1990 and 2030. On-road cars, trucks, and other transport vehicles are, however, the cause of important pollutants other than PM2.5 (as are as cooking stoves that do

  12. Durability and regeneration of activated carbon air-cathodes in long-term operated microbial fuel cells

    Science.gov (United States)

    Zhang, Enren; Wang, Feng; Yu, Qingling; Scott, Keith; Wang, Xu; Diao, Guowang

    2017-08-01

    The performance of activated carbon catalyst in air-cathodes in microbial fuel cells was investigated over one year. A maximum power of 1722 mW m-2 was produced within the initial one-month microbial fuel cell operation. The air-cathodes produced a maximum power >1200 mW m-2 within six months, but gradually became a limiting factor for the power output in prolonged microbial fuel cell operation. The maximum power decreased by 55% when microbial fuel cells were operated over one year due to deterioration in activated carbon air-cathodes. While salt/biofilm removal from cathodes experiencing one-year operation increased a limiting performance enhancement in cathodes, a washing-drying-pressing procedure could restore the cathode performance to its original levels, although the performance restoration was temporary. Durable cathodes could be regenerated by re-pressing activated carbon catalyst, recovered from one year deteriorated air-cathodes, with new gas diffusion layer, resulting in ∼1800 mW m-2 of maximum power production. The present study indicated that activated carbon was an effective catalyst in microbial fuel cell cathodes, and could be recovered for reuse in long-term operated microbial fuel cells by simple methods.

  13. Various Perspectives of Mitigating Fossil Fuel Use and Air Pollutant Emissions in China's Megacity

    Science.gov (United States)

    Wang, H.

    2014-12-01

    It is critical to reduce energy use and air pollutions in metropolitan areas because these areas usually serve as economic engines and have large, dense populations. Fossil fuel use and air-polluting emissions were analyzed in Beijing between 1997 and 2010 from both a bottom-up and a top-down perspective. From a bottom-up perspective, the key energy-intensive industrial sectors directly caused changes in Beijing's air pollution by means of a series of energy and economic policies. From a top-down perspective, variation in industrial production caused increases in most emissions between 2000 and 2010, however, there were decreases in PM10 and PM2.5 emissions during 2005-2010. Population growth was found to be the largest driver of energy consumption and emissions between1997 and 2010. Energy use and air pollutant emissions were also found to outsource from Beijing to other regions in China. Policies for reducing urban energy consumption and emissions should consider not only the key industrial sectors but also socioeconomic drivers.

  14. Using cathode spacers to minimize reactor size in air cathode microbial fuel cells

    KAUST Repository

    Yang, Qiao

    2012-04-01

    Scaling up microbial fuel cells (MFCs) will require more compact reactor designs. Spacers can be used to minimize the reactor size without adversely affecting performance. A single 1.5mm expanded plastic spacer (S1.5) produced a maximum power density (973±26mWm -2) that was similar to that of an MFC with the cathode exposed directly to air (no spacer). However, a very thin spacer (1.3mm) reduced power by 33%. Completely covering the air cathode with a solid plate did not eliminate power generation, indicating oxygen leakage into the reactor. The S1.5 spacer slightly increased columbic efficiencies (from 20% to 24%) as a result of reduced oxygen transfer into the system. Based on operating conditions (1000ς, CE=20%), it was estimated that 0.9Lh -1 of air would be needed for 1m 2 of cathode area suggesting active air flow may be needed for larger scale MFCs. © 2012 Elsevier Ltd.

  15. Durability study of KOH doped polybenzimidazole membrane for air-breathing alkaline direct ethanol fuel cell

    Science.gov (United States)

    Hou, Hongying; Wang, Suli; Jiang, Qian; Jin, Wei; Jiang, Luhua; Sun, Gongquan

    2011-03-01

    Recently, KOH doped polybenzimidazole (PBI/KOH) membrane has been reported as polymer electrolyte membrane for alkaline direct alcohol fuel cell (ADAFC), but little is known about its durability for ADAFC application. In this paper, the durability of PBI/KOH membrane for air-breathing alkaline direct ethanol fuel cell (ADEFC) is evaluated by means of ex situ and in situ tests. In the case of ex situ durability test, the ionic conductivity of PBI/KOH degrades from initial 0.023 S cm-1 to 0.01 S cm-1 after 100 h, and the degrading rate was 1.3 × 10-4 S cm-1 h-1. As for in situ test, Pt-free air-breathing ADEFC with PBI/KOH membrane can output a peak power density of 16 mW cm-2 at 60 °C. Moreover, it can stably operate for 336 h above 0.3 V. In addition, the interaction between KOH and PBI matrix is also explored by density functional theory study.

  16. Thermal Cyclability of Reactive Air Braze Seals in Anode Supported Solid Oxide Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Hardy, John S.; Darsell, Jens T.; Coyle, Christopher A.; Birnbaum, Jerome C.; Weil, K. Scott

    2004-12-31

    The popularity of anode-supported solid oxide fuel cells (SOFC) has increased in tandem with the ability to fabricate thinner gas-tight yttrium-stabilized zirconia (YSZ) electrolyte layers, which can now be routinely produced on the order of 7 to 10 μm thick. While this has significantly improved power output and decreased the required fuel cell operating temperatures, the ability to reliably seal fuel cells remains a concern. The seals must be hermetic and be robust enough to retain their hermeticity even under the extreme operating conditions of SOFCs. Perhaps the largest contributor to stresses experienced by the seal is the fact that the SOFC is an assembly of many different materials with different thermal expansion properties. Although every effort is made to minimize thermal expansion mismatches across the seals, the stresses developed during thermal cycling still jeopardize seal integrity. Reactive air brazing (RAB), a method of joining that employs a metallic, and therefore non-brittle, seal material has been used to seal electrolyte/anode bilayers, such as those in anode-supported SOFCs, to Crofer-22 alloy. The results of rupture strength testing will be reported for as-brazed and thermally cycled samples and the effect of thermal cycling on the RAB seal microstructure will be shown

  17. NanoCapillary Network Proton Conducting Membranes for High Temperature Hydrogen/Air Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Pintauro, Peter [Vanderbilt Univ., Nashville, TN (United States)

    2012-07-09

    The objective of this proposal is to fabricate and characterize a new class of NanoCapillary Network (NCN) proton conducting membranes for hydrogen/air fuel cells that operate under high temperature, low humidity conditions. The membranes will be intelligently designed, where a high density interconnecting 3-D network of nm-diameter electrospun proton conducting polymer fibers is embedded in an inert (uncharged) water/gas impermeable polymer matrix. The high density of fibers in the resulting mat and the high ion-exchange capacity of the fiber polymer will ensure high proton conductivity. To further enhance water retention, molecular silica will be added to the sulfonated polymer fibers. The uncharged matrix material will control water swelling of the high ion-exchange capacity proton conducting polymer fibers and will impart toughness to the final nanocapillary composite membrane. Thus, unlike other fuel cell membranes, the role of the polymer support matrix will be decoupled from that of the proton-conducting channels. The expected final outcome of this 5-year project is the fabrication of fuel cell membranes with properties that exceed the DOE’s technical targets, in particular a proton conductivity of 0.1 S/cm at a temperature less than or equal to120°C and 25-50% relative humidity.

  18. Effects of pressure on fuel-rich combustion of methane-air under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, Tsuyoshi; Kobayashi, Noriyuki; Arai, Norio [Nagoya Univ., Research Center for Advanced Energy Conversion, Nagoya (Japan); Tanaka, Tadashi [Chubu Electric Power Co. Inc., Electric Power Research and Development Center, Nagoya (Japan)

    1997-12-31

    We have proposed a new and innovative gas turbine system, named chemical gas turbine system. It would improve the thermal efficiency more than 10% compared to conventional ones. This gas turbine system is based on promising developments in fuel-rich combustors with a carbon fiber reinforced carbon composite (C/C composite) being used as the turbine blades. As one of fundamental researches to develop this system, we designed a 4 MPa-scale combustor with methane-air. Flammability limit, components of combustion gases and combustion temperature were measured between 1.1 and 4.1 MPa in pressure. Results from these measurements were as follows: (1) stable combustion could attain between the equivalence ratio theta= 0.7 and 1.3 at 4 MPa in pressure; (2) there was little effect of the pressure on the components of combustion gases; and (3) flammability limit extended with increasing the pressure on the fuel-rich region while it was almost constant in the fuel-lean one. (Author)

  19. Catalytic combustion of residual fuels

    Science.gov (United States)

    Bulzan, D. L.; Tacina, R. R.

    1981-01-01

    A noble metal catalytic reactor was tested using two grades of petroleum derived residual fuels at specified inlet air temperatures, pressures, and reference velocities. Combustion efficiencies greater than 99.5 percent were obtained. Steady state operation of the catalytic reactor required inlet air temperatures of at least 800 K. At lower inlet air temperatures, upstream burning in the premixing zone occurred which was probably caused by fuel deposition and accumulation on the premixing zone walls. Increasing the inlet air temperature prevented this occurrence. Both residual fuels contained about 0.5 percent nitrogen by weight. NO sub x emissions ranged from 50 to 110 ppm by volume at 15 percent excess O2. Conversion of fuel-bound nitrogen to NO sub x ranged from 25 to 50 percent.

  20. Building America Case Study: Standard- Versus High-Velocity Air Distribution in High-Performance Townhomes, Denver, Colorado

    Energy Technology Data Exchange (ETDEWEB)

    2017-06-09

    IBACOS investigated the performance of a small-diameter high velocity heat pump system compared to a conventional system in a new construction triplex townhouse. A ductless heat pump system also was installed for comparison, but the homebuyer backed out because of aesthetic concerns about that system. In total, two buildings, having identical solar orientation and comprised of six townhomes, were monitored for comfort and energy performance. Results show that the small-diameter system provides more uniform temperatures from floor to floor in the three-story townhome. No clear energy consumption benefit was observed from either system. The builder is continuing to explore the small-diameter system as its new standard system to provide better comfort and indoor air quality. The homebuilder also explored the possibility of shifting its townhome product to meet the U.S. Department of Energy Challenge Home National Program Requirements. Ultimately, the builder decided that adoption of these practices would be too disruptive midstream in the construction cycle. However, the townhomes met the ENERGY STAR Version 3.0 program requirements.

  1. Measurement of the Tracer Gradient and Sampling System Bias of the Hot Fuel Examination Facility Stack Air Monitoring System

    Energy Technology Data Exchange (ETDEWEB)

    Glissmeyer, John A.; Flaherty, Julia E.

    2011-07-20

    This report describes tracer gas uniformity and bias measurements made in the exhaust air discharge of the Hot Fuel Examination Facility at Idaho National Laboratory. The measurements were a follow-up on earlier measurements which indicated a lack of mixing of the two ventilation streams being discharged via a common stack. The lack of mixing is detrimental to the accuracy of air emission measurements. The lack of mixing was confirmed in these new measurements. The air sampling probe was found to be out of alignment and that was corrected. The suspected sampling bias in the air sample stream was disproved.

  2. Coherent Anti-Stokes Raman Scattering (CARS) as a Probe for Supersonic Hydrogen-Fuel/Air Mixing

    Science.gov (United States)

    Danehy, P. M.; O'Byrne, S.; Cutler, A. D.; Rodriguez, C. G.

    2003-01-01

    The dual-pump coherent anti-Stokes Raman spectroscopy (CARS) method was used to measure temperature and the absolute mole fractions of N2, O2 and H2 in a supersonic non-reacting fuel-air mixing experiment. Experiments were conducted in NASA Langley Research Center s Direct Connect Supersonic Combustion Test Facility. Under normal operation of this facility, hydrogen and air burn to increase the enthalpy of the test gas and O2 is added to simulate air. This gas is expanded through a Mach 2 nozzle and into a combustor model where fuel is then injected, mixes and burns. In the present experiment the O2 of the test gas is replaced by N2. The lack of oxidizer inhibited combustion of the injected H2 fuel jet allowing the fuel/air mixing process to be studied. CARS measurements were performed 427 mm downstream of the nozzle exit and 260 mm downstream of the fuel injector. Maps were obtained of the mean temperature, as well as the N2, O2 and H2 mean mole fraction fields. A map of mean H2O vapor mole fraction was also inferred from these measurements. Correlations between different measured parameters and their fluctuations are presented. The CARS measurements are compared with a preliminary computational prediction of the flow.

  3. Perspective use of direct human blood as an energy source in air-breathing hybrid microfluidic fuel cells

    Science.gov (United States)

    Dector, A.; Escalona-Villalpando, R. A.; Dector, D.; Vallejo-Becerra, V.; Chávez-Ramírez, A. U.; Arriaga, L. G.; Ledesma-García, J.

    2015-08-01

    This work presents a flexible and light air-breathing hybrid microfluidic fuel cell (HμFC) operated under biological conditions. A mixture of glucose oxidase, glutaraldehyde, multi-walled carbon nanotubes and vulcan carbon (GOx/VC-MWCNT-GA) was used as the bioanode. Meanwhile, integrating an air-exposed electrode (Pt/C) as the cathode enabled direct oxygen delivery from air. The microfluidic fuel cell performance was evaluated using glucose obtained from three different sources as the fuel: 5 mM glucose in phosphate buffer, human serum and human blood. For the last fuel, an open circuit voltage and maximum power density of 0.52 V and 0.20 mW cm-2 (at 0.38 V) were obtained respectively; meanwhile the maximum current density was 1.1 mA cm-2. Furthermore, the stability of the device was measured in terms of recovery after several polarization curves, showing excellent results. Although this air-breathing HμFC requires technological improvements before being tested in a biomedical device, it represents the best performance to date for a microfluidic fuel cell using human blood as glucose source.

  4. Evaluation of mechanical properties and low velocity impact characteristics of balsa wood and urethane foam applied to impact limiter of nuclear spent fuel shipping cask

    Energy Technology Data Exchange (ETDEWEB)

    Goo, Junsung; Shin, Kwangbok [Hanbat Nat' l Univ., Daejeon (Korea, Republic of); Choi, Woosuk [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2012-11-15

    The paper aims to evaluate the low velocity impact responses and mechanical properties of balsa wood and urethane foam core materials and their sandwich panels, which are applied as the impact limiter of a nuclear spent fuel shipping cask. For the urethane foam core, which is isotropic, tensile, compressive, and shear mechanical tests were conducted. For the balsa wood core, which is orthotropic and shows different material properties in different orthogonal directions, nine mechanical properties were determined. The impact test specimens for the core material and their sandwich panel were subjected to low velocity impact loads using an instrumented testing machine at impact energy levels of 1, 3, and 5J. The experimental results showed that both the urethane foam and the balsa wood core except in the growth direction (z-direction) had a similar impact response for the energy absorbing capacity, contact force, and indentation. Furthermore, it was found that the urethane foam core was suitable as an impact limiter material owing to its resistance to fire and low cost, and the balsa wood core could also be strongly considered as an impact limiter material for a lightweight nuclear spent fuel shipping cask.

  5. Fuel-rich hydrogen-air combustion for a gas-turbine system without CO{sub 2} emission

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, Noriyuki; Namo, Takamitsu; Arai, Norio [Nagoya Univ. (Japan). Research Center for Advanced Energy Conversion

    1997-02-01

    We propose a new and innovative gas-turbine system using fuel-rich hydrogen combustion, which we call a chemical gas-turbine system. It involves a fuel-rich hydrogen-air combustor as a major component. We have focused on a coaxial diffusion flame under normal pressure. The effects of equivalence ratio and swirl number have been investigated by measuring temperature profiles, gas composition, and flame structures using direct observations of OH radical emissions. The flames were shortened and NO{sub x} emission decreased with swirling under fuel-rich conditions. (author)

  6. High-Performance Carbon Aerogel Air Cathodes for Microbial Fuel Cells

    KAUST Repository

    Zhang, Xiaoyuan

    2016-08-11

    Microbial fuel cells (MFCs) can generate electricity from the oxidation of organic substrates using anodic exoelectrogenic bacteria and have great potential for harvesting electric energy from wastewater. Improving oxygen reduction reaction (ORR) performance at a neutral pH is needed for efficient energy production. Here we show a nitrogen doped (≈4 wt%) ionothermal carbon aerogel (NDC) with a high surface area, large pore volume, and hierarchical porosity, with good electrocatalytic properties for ORR in MFCs. The MFCs using NDC air cathodes achieved a high maximum power density of 2300 mW m−2, which was 1.7 times higher than the most commonly used Pt/C air cathodes and also higher than most state-of-the-art ORR catalyst air cathodes. Rotating disk electrode measurements verified the superior electrocatalytic activity of NDC with an efficient four-electron transfer pathway (n=3.9). These findings highlight NDC as a better-performing and cost-efficient catalyst compared with Pt/C, making it highly viable for MFC applications.

  7. Power generation by packed-bed air-cathode microbial fuel cells

    KAUST Repository

    Zhang, Xiaoyuan

    2013-08-01

    Catalysts and catalyst binders are significant portions of the cost of microbial fuel cell (MFC) cathodes. Many materials have been tested as aqueous cathodes, but air-cathodes are needed to avoid energy demands for water aeration. Packed-bed air-cathodes were constructed without expensive binders or diffusion layers using four inexpensive carbon-based materials. Cathodes made from activated carbon produced the largest maximum power density of 676±93mW/m2, followed by semi-coke (376±47mW/m2), graphite (122±14mW/m2) and carbon felt (60±43mW/m2). Increasing the mass of activated carbon and semi-coke from 5 to ≥15g significantly reduced power generation because of a reduction in oxygen transfer due to a thicker water layer in the cathode (~3 or ~6cm). These results indicate that a thin packed layer of activated carbon or semi-coke can be used to make inexpensive air-cathodes for MFCs. © 2013 Elsevier Ltd.

  8. Experimental study and empirical prediction of fuel flow parameters under air evolution conditions

    Science.gov (United States)

    Kitanina, E. E.; Kitanin, E. L.; Bondarenko, D. A.; Kravtsov, P. A.; Peganova, M. M.; Stepanov, S. G.; Zherebzov, V. L.

    2017-11-01

    Air evolution in kerosene under the effect of gravity flow with various hydraulic resistances in the pipeline was studied experimentally. The study was conducted at pressure ranging from 0.2 to 1.0 bar and temperature varying between -20°C and +20°C. Through these experiments, the oversaturation limit beyond which dissolved air starts evolving intensively from the fuel was established and the correlations for the calculation of pressure losses and air evolution on local loss elements were obtained. A method of calculating two-phase flow behaviour in a titled pipeline segment with very low mass flow quality and fairly high volume flow quality was developed. The complete set of empirical correlations obtained by experimental analysis was implemented in the engineering code. The software simulation results were repeatedly verified against our experimental findings and Airbus test data to show that the two-phase flow simulation agrees quite well with the experimental results obtained in the complex branched pipelines.

  9. Thermodynamic Analysis of Three Compressed Air Energy Storage Systems: Conventional, Adiabatic, and Hydrogen-Fueled

    Directory of Open Access Journals (Sweden)

    Hossein Safaei

    2017-07-01

    Full Text Available We present analyses of three families of compressed air energy storage (CAES systems: conventional CAES, in which the heat released during air compression is not stored and natural gas is combusted to provide heat during discharge; adiabatic CAES, in which the compression heat is stored; and CAES in which the compression heat is used to assist water electrolysis for hydrogen storage. The latter two methods involve no fossil fuel combustion. We modeled both a low-temperature and a high-temperature electrolysis process for hydrogen production. Adiabatic CAES (A-CAES with physical storage of heat is the most efficient option with an exergy efficiency of 69.5% for energy storage. The exergy efficiency of the conventional CAES system is estimated to be 54.3%. Both high-temperature and low-temperature electrolysis CAES systems result in similar exergy efficiencies (35.6% and 34.2%, partly due to low efficiency of the electrolyzer cell. CAES with high-temperature electrolysis has the highest energy storage density (7.9 kWh per m3 of air storage volume, followed by A-CAES (5.2 kWh/m3. Conventional CAES and CAES with low-temperature electrolysis have similar energy densities of 3.1 kWh/m3.

  10. Performance of air-cathode stacked microbial fuel cells systems for wastewater treatment and electricity production.

    Science.gov (United States)

    Estrada-Arriaga, Edson Baltazar; Guillen-Alonso, Yvonne; Morales-Morales, Cornelio; García-Sánchez, Liliana; Bahena-Bahena, Erick Obed; Guadarrama-Pérez, Oscar; Loyola-Morales, Félix

    2017-07-01

    Two different air-cathode stacked microbial fuel cell (MFC) configurations were evaluated under continuous flow during the treatment of municipal wastewater and electricity production at a hydraulic retention time (HRT) of 3, 1, and 0.5 d. Stacked MFC 1 was formed by 20 individual air-cathode MFC units. The second stacked MFC (stacked MFC 2) consisted of 40 air-cathode MFC units placed in a shared reactor. The maximum voltages produced at closed circuit (1,000 Ω) were 170 mV for stacked MFC 1 and 94 mV for stacked MFC 2. Different power densities in each MFC unit were obtained due to a potential drop phenomenon and to a change in chemical oxygen demand (COD) concentrations inside reactors. The maximum power densities from individual MFC units were up to 1,107 mW/m 2 for stacked MFC 1 and up to 472 mW/m 2 for stacked MFC 2. The maximum power densities in stacked MFC 1 and MFC 2 connected in series were 79 mW/m 2 and 4 mW/m 2 , respectively. Electricity generation and COD removal efficiencies were reduced when the HRT was decreased. High removal efficiencies of 84% of COD, 47% of total nitrogen, and 30% of total phosphorus were obtained during municipal wastewater treatment.

  11. Effects of switching to lower sulfur marine fuel oil on air quality in the San Francisco Bay area.

    Science.gov (United States)

    Tao, Ling; Fairley, David; Kleeman, Michael J; Harley, Robert A

    2013-09-17

    Ocean-going vessels burning high-sulfur heavy fuel oil are an important source of air pollutants, such as sulfur dioxide and particulate matter. Beginning in July 2009, an emission control area was put into effect at ports and along the California coastline, requiring use of lower sulfur fuels in place of heavy fuel oil in main engines of ships. To assess impacts of the fuel changes on air quality at the Port of Oakland and in the surrounding San Francisco Bay area, we analyzed speciated fine particle concentration data from four urban sites and two more remote sites. Measured changes in concentrations of vanadium, a specific marker for heavy fuel oil combustion, are related to overall changes in aerosol emissions from ships. We found a substantial reduction in vanadium concentrations after the fuel change and a 28-72% decrease in SO2 concentrations, with the SO2 decrease varying depending on proximity to shipping lanes. We estimate that the changes in ship fuel reduced ambient PM2.5 mass concentrations at urban sites in the Bay area by about 3.1 ± 0.6% or 0.28 ± 0.05 μg/m(3). The largest contributing factor to lower PM mass concentrations was reductions in particulate sulfate. Absolute sulfate reductions were fairly consistent across sites, whereas trace metal reductions were largest at a monitoring site in West Oakland near the port.

  12. Electronic modification of Pt via Ti and Se as tolerant cathodes in air-breathing methanol microfluidic fuel cells.

    Science.gov (United States)

    Ma, Jiwei; Habrioux, Aurélien; Morais, Cláudia; Alonso-Vante, Nicolas

    2014-07-21

    We reported herein on the use of tolerant cathode catalysts such as carbon supported Pt(x)Ti(y) and/or Pt(x)Se(y) nanomaterials in an air-breathing methanol microfluidic fuel cell. In order to show the improvement of mixed-reactant fuel cell (MRFC) performances obtained with the developed tolerant catalysts, a classical Pt/C nanomaterial was used for comparison. Using 5 M methanol concentration in a situation where the fuel crossover is 100% (MRFC-mixed reactant fuel cell application), the maximum power density of the fuel cell with a Pt/C cathodic catalyst decreased by 80% in comparison with what is observed in the laminar flow fuel cell (LFFC) configuration. With Pt(x)Ti(y)/C and Pt(x)Se(y)/C cathode nanomaterials, the performance loss was only 55% and 20%, respectively. The evaluation of the tolerant cathode catalysts in an air-breathing microfluidic fuel cell suggests the development of a novel nanometric system that will not be size restricted. These interesting results are the consequence of the high methanol tolerance of these advanced electrocatalysts via surface electronic modification of Pt. Herein we used X-ray photoelectron and in situ FTIR spectroscopies to investigate the origin of the high methanol tolerance on modified Pt catalysts.

  13. Indoor air pollution from solid biomass fuels combustion in rural agricultural area of Tibet, China

    Energy Technology Data Exchange (ETDEWEB)

    Gao, X.; Yu, Q.; Gu, Q.; Chen, Y.; Ding, K.; Zhu, J.; Chen, L.

    2009-01-15

    In this study, we are trying to investigate the indoor air pollution and to estimate the residents pollution exposure reduction of energy altering in rural Tibet. Daily PM{sub 2.5} monitoring was conducted in indoor microenvironments like kitchen, living-room, bedroom, and yard in rural Tibet from December 2006 to March 2007. For kitchen air pollution, impact of two fuel types, methane and solid biomass fuels (SBFs), were compared. Questionnaire survey on the domestic energy pattern and residents daily activity pattern was performed in Zha-nang County. Daily average PM{sub 2.5} concentrations in kitchen, living-room, bedroom, and yard were 134.91 mug/m3 (mean, n = 45, 95%CI 84.02, 185.80), 103.61 mug/m3 (mean, n = 21, 95%CI 85.77, 121.45), 76.13 mug/m3 (mean, n = 18, 95%CI 57.22, 95.04), and 78.33 mug/m3 (mean, n = 34, 95%CI 60.00, 96.65) respectively. Using SBFs in kitchen resulted in higher indoor pollution than using methane. PM{sub 2.5} concentrations in kitchen with dung cake, fuel wood and methane use were 117.41 mug/m3 (mean, n = 18, 95%CI 71.03, 163.79), 271.11 mug/m3 (mean, n = 12, 95%CI 104.74, 437.48), and 46.96 mug/m3 (mean, n = 15, 95%CI 28.10, 65.82) respectively. Family income has significant influence on cooking energy choice, while the lack of commercial energy supply affects the energy choice for heating more. The effects of two countermeasures to improve indoor air quality were estimated in this research. One is to replace SBFs by clean energy like methane, the other is to separate the cooking place from other rooms and by applying these countermeasures, residents exposure to particulate matters would reduce by 25-50% (methane) or 20-30% (separation) compared to the present situation. (au)

  14. The effect of wind velocity, air temperature and humidity on NH 3 and SO 2 transfer into bean leaves ( phaseolus vulgaris L.)

    Science.gov (United States)

    van Hove, L. W. A.; Vredenberg, W. J.; Adema, E. H.

    The influence of wind velocity, air temperature and vapour pressure deficit of the air (VPD) on NH 3 and SO 2 transfer into bean leaves ( Phaseolus vulgaris L.) was examined using a leaf chamber. The measurements suggested a transition in the properties of the leaf boundary layer at a wind velocity of 0.3-0.4 ms -1 which corresponds to a Recrit value of about 2000. At higher wind velocities the leaf boundary layer resistance ( rb) was 1.5-2 times lower than can be calculated from the theory. Nevertheless, the assessed relationships between rb and wind velocity appeared to be similar to the theoretical derived relationship for rb. The NH 3 flux and in particular the SO 2 flux into the leaf strongly increased at a VPD decline. The increase of the NH 3 flux could be attributed to an increase of the stomatal conductance ( gs). However, the increase of the SO 2 flux could only partly be explained by an increase of gs. An apparent additional uptake was also observed for the NH 3 uptake at a low temperature and VPD. The SO 2 flux was also influenced by air temperature which could be explained by a temperature effect on gs. The results suggest that calculation of the NH 3 and SO 2 flux using data of gs gives a serious understimation of the real flux of these gases into leaves at a low temperature and VPD.

  15. Assessment of JP-8 as a replacement fuel for the Air Force standard jet fuel JP-4. Part I. Assessment of JP-8/JP-4 fuel in noncombat environment. Final report, Jun 1972--Apr 1975

    Energy Technology Data Exchange (ETDEWEB)

    Beery, G.T.; Clodfelter, R.G.; Gandee, G.W.; Spear, D.M.; Wight, D.C.

    1975-06-01

    This report is an assessment of JP-8 as a replacement fuel for the Air Force standard jet fuel JP-4. All facets of the problem are examined including fire safety under combat and noncombat conditions, crash fire safety, storage, handling and maintenance safety, laboratory testing, gunfire testing, flight testing, cost and availability, and impact on current Air Force weapons systems. The report concludes that a significant improvement in overall fire safety could be achieved by conversion to JP-8 however, additional investigation into problems related to low temperature ground start and altitude relight should be accomplished prior to conversion. (GRA)

  16. A Comprehensive Review on Fluid Dynamics and Transport of Suspension/Liquid Droplets and Particles in High-Velocity Oxygen-Fuel (HVOF Thermal Spray

    Directory of Open Access Journals (Sweden)

    Mehdi Jadidi

    2015-10-01

    Full Text Available In thermal spraying processes, molten, semi-molten, or solid particles, which are sufficiently fast in a stream of gas, are deposited on a substrate. These particles can plastically deform while impacting on the substrate, which results in the formation of well-adhered and dense coatings. Clearly, particles in flight conditions, such as velocity, trajectory, temperature, and melting state, have enormous influence on the coating properties and should be well understood to control and improve the coating quality. The focus of this study is on the high velocity oxygen fuel (HVOF spraying and high velocity suspension flame spraying (HVSFS techniques, which are widely used in academia and industry to generate different types of coatings. Extensive numerical and experimental studies were carried out and are still in progress to estimate the particle in-flight behavior in thermal spray processes. In this review paper, the fundamental phenomena involved in the mentioned thermal spray techniques, such as shock diamonds, combustion, primary atomization, secondary atomization, etc., are discussed comprehensively. In addition, the basic aspects and emerging trends in simulation of thermal spray processes are reviewed. The numerical approaches such as Eulerian-Lagrangian and volume of fluid along with their advantages and disadvantages are explained in detail. Furthermore, this article provides a detailed review on simulation studies published to date.

  17. NUMERICAL INVESTIGATION OF THE EFFECTS OF AIR/FUEL RATIO ON COMBUSTION IN A SPARK IGNITION ENGINE

    OpenAIRE

    DINLER, Nureddin; YUCEL, Nuri

    2016-01-01

    Combustion is one of the main research areas of internal combustion engines. To reduce the air pollution from internal combustion engines, it is required to increase combustion efficiency. In this study, effects of air/fuel ratio were investigated numerically. An axisymmetrical internal combustion engine was modeled in order to simulate in-cylinder engine flow and combustion. Two dimensional transient continuity, momentum, turbulence, energy and combustion equations were solved. k-e turbulenc...

  18. COMBUSTION SIMULATION IN A SPARK IGNITION ENGINE CYLINDER: EFFECTS OF AIR-FUEL RATIO ON THE COMBUSTION DURATION

    OpenAIRE

    Nureddin Dinler; Nuri Yucel

    2010-01-01

    Combustion is an important subject of internal combustion engine studies. To reduce the air pollution from internal combustion engines and to increase the engine performance, it is required to increase combustion efficiency. In this study, effects of air/fuel ratio were investigated numerically. An axisymmetrical internal combustion engine was modeled in order to simulate in-cylinder engine flow and combustion. Two dimensional transient continuity, momentum, turbulence, energy, and combustion...

  19. Influence of inlet velocity of air and solid particle feed rate on holdup mass and heat transfer characteristics in cyclone heat exchanger

    Energy Technology Data Exchange (ETDEWEB)

    Mothilal, T. [T. J. S. Engineering College, Gummidipoond (India); Pitchandi, K. [Sri Venkateswara College of Engineering, Sriperumbudur (India)

    2015-10-15

    Present work elaborates the effect of inlet velocity of air and solid particle feed rate on holdup mass and heat transfer characteristics in a cyclone heat exchanger. The RNG k-ε turbulence model was adopted for modeling high turbulence flow and Discrete phase model (DPM) to track solid particles in a cyclone heat exchanger by ANSYS FLUENT software. The effect of inlet air velocity (5 to 25 m/s) and inlet solid particle feed rate of (0.2 to 2.5 g/s) at different particle diameter (300 to 500 μm) on holdup mass and heat transfer rate in cyclone heat exchanger was studied at air inlet temperature of 473 K. Results show that holdup mass and heat transfer rate increase with increase in inlet air velocity and inlet solid particle feed rate. Influence of solid particle feed rate on holdup mass has more significance. Experimental setup was built for high efficiency cyclone. Good agreement was found between experimental and simulation pressure drop. Empirical correlation was derived for dimensionless holdup mass and Nusselt number based on CFD data by regression technique. Correlation predicts dimensional holdup mass with +5% to -8% errors of experimental data and Nusselt number with +9% to -3%.

  20. The Melting of Spherical Ice Particles Falling at Terminal Velocity in Air: AN Experimental and Theoretical Study.

    Science.gov (United States)

    Rasmussen, Roy Martin

    This study utilized the UCLA cloud physics wind tunnel and the IBM 3033 computer. The wind tunnel experiments were conducted using two separate procedures, depending on the size of the spherical particle. Particles less than 1 mm diameter, were melted in free fall while experiencing a time varying environmental temperature, similar to the variation of temperature it would encounter while freely falling in the atmosphere. Particles larger than 1 mm diameter have a tendency to wander towards the tunnel walls, requiring restraint by a thin nylon fiber frozen halfway through the particle. Using this fiber, the particle was suspended from above. Although attached to a thread, the particle's terminal velocity was constantly maintained during melting by keeping the fiber slack. Particles less than 1 mm diameter usually undergo "sailing" motions upon melting due to the melting of surface protuberances. Once the protuberances are melted, the particle falls with no horizontal drift. The melting ice core was observed to remain tangent with the downstream end of the particle, resulting in an eccentric melting location. The meltwater itself was also observed to circulate due to the external shear of the air on the meltwater surface. For these small particles, no meltwater was shed. Particles larger than 9 mm diameter were found to shed meltwater, with the fraction shed increasing with particle size. Particles between 9 mm and 5 mm diameter did not shed their meltwater, and did not develop an internal circulation. Particles between 1 mm and 5 mm, however, did develop a significant internal circulation, resulting in a conically shaped ice core. For each of the above size ranges, melting theories are developed which are able to quantitatively describe the melting rates of these particles.

  1. Copper current collectors reduce long-term fouling of air cathodes in microbial fuel cells

    KAUST Repository

    Myung, Jaewook

    2018-02-05

    Long-term operation of wastewater-fed, microbial fuel cells (MFCs) with cathodes made of activated carbon and stainless steel (SS) current collectors can result in decreased performance due to cathode fouling. Copper has good antimicrobial properties, and it is more electrically conductive than SS. To demonstrate that a copper current collector could produce a more fouling resistant cathode, MFCs with air cathodes using either SS or copper current collectors were operated using domestic wastewater for 27 weeks. The reduction in biofouling over time was shown by less biofilm formation on the copper cathode surface compared to SS cathodes, due to the antimicrobial properties of copper. Maximum power densities from 17–27 weeks were 440 ± 38 mW/m2 using copper and 370 ± 21 mW/m2 using SS cathodes. The main difference in the microbial community was a nitrifying community on the SS cathodes, which was not present on the copper cathodes.

  2. Water management in a planar air-breathing fuel cell array using operando neutron imaging

    Science.gov (United States)

    Coz, E.; Théry, J.; Boillat, P.; Faucheux, V.; Alincant, D.; Capron, P.; Gébel, G.

    2016-11-01

    Operando Neutron imaging is used for the investigation of a planar air-breathing array comprising multiple cells in series. The fuel cell demonstrates a stable power density level of 150 mW/cm2. Water distribution and quantification is carried out at different operating points. Drying at high current density is observed and correlated to self-heating and natural convection. Working in dead-end mode, water accumulation at lower current density is largely observed on the anode side. However, flooding mechanisms are found to begin with water condensation on the cathode side, leading to back-diffusion and anodic flooding. Specific in-plane and through-plane water distribution is observed and linked to the planar array design.

  3. Power generation using adjustable Nafion/PTFE mixed binders in air-cathode microbial fuel cells.

    Science.gov (United States)

    Wang, Xin; Feng, Yujie; Liu, Jia; Shi, Xinxin; Lee, He; Li, Nan; Ren, Nanqi

    2010-10-15

    Nafion, poly(tetrafluoroethylene) (PTFE) and polymers made of Nafion-PTFE mixture (Nafion and PTFE ratios of 1:2 and 2:1) were examined as catalyst binders in air-cathode microbial fuel cells (MFCs). MFC tests showed that the maximum power density (from 549 to 1060 mW/m2) increased with the increase of Nafion percentage in binders (from 0% to 100%). Multi-cycle tests (25 cycles) showed that the maximum voltages decreased by 4-6% with simultaneous increase in Coulombic efficiency in all MFCs using various binders (from 20% to 29% with Nafion binder; from 17% to 26% with other binders), indicating that adjustable Nafion/PTFE mixed polymers were applicable in MFCs as catalyst binders when considering both cost and performance of cathodes. Copyright © 2010 Elsevier B.V. All rights reserved.

  4. Cleaning the air and improving health with hydrogen fuel-cell vehicles.

    Science.gov (United States)

    Jacobson, M Z; Colella, W G; Golden, D M

    2005-06-24

    Converting all U.S. onroad vehicles to hydrogen fuel-cell vehicles (HFCVs) may improve air quality, health, and climate significantly, whether the hydrogen is produced by steam reforming of natural gas, wind electrolysis, or coal gasification. Most benefits would result from eliminating current vehicle exhaust. Wind and natural gas HFCVs offer the greatest potential health benefits and could save 3700 to 6400 U.S. lives annually. Wind HFCVs should benefit climate most. An all-HFCV fleet would hardly affect tropospheric water vapor concentrations. Conversion to coal HFCVs may improve health but would damage climate more than fossil/electric hybrids. The real cost of hydrogen from wind electrolysis may be below that of U.S. gasoline.

  5. Air-fuel ratio and speed control for low emission vehicles based on sliding mode techniques

    Energy Technology Data Exchange (ETDEWEB)

    Puleston, P.F. [UNLP, La Plata (Argentina). Departamento de Electrotecnia, CONICET and LEICI; Monsees, G. [Delft University of Technology (Netherlands). Faculty of Information, Technology and Systems, Control Laboratory; Spurgeon, S.K. [University of Leicester (United Kingdom). Department of Engineering, Control and Instrumentation Group

    2002-05-01

    This paper deals with the combined air-fuel ratio (AFR) and speed control of automotive engines. The robust controller is developed using dynamic sliding mode (SM) control design methods. The proposed controller set-up is tested under realistic operating conditions by means of computer simulation using a comprehensive non-linear model of a four-stroke engine, specifically provided by the automotive industry for these purposes. This accurate industrial model comprises extensive dynamics description and numerous look-up tables representing parameter characteristics obtained from experimental data. The SM controller set-up proves to be robust to model uncertainties and unknown disturbances, regulating effectively the engine speed for a wide range of set-points while maintaining the AFR at the stoichiometric value. (author)

  6. Epidemiological evidence that indoor air pollution from cooking with solid fuels accelerates skin aging in Chinese women.

    Science.gov (United States)

    Li, Miaozhu; Vierkötter, Andrea; Schikowski, Tamara; Hüls, Anke; Ding, Anan; Matsui, Mary S; Deng, Binwei; Ma, Chuan; Ren, Aiguo; Zhang, Juan; Tan, Jingze; Yang, Yajun; Jin, Li; Krutmann, Jean; Li, Zhiwen; Wang, Sijia

    2015-08-01

    Recently, we showed that outdoor air pollution exposure from traffic and industry is associated with an increased risk of skin aging in Caucasian women. In China, indoor air pollution exposure caused by the use of solid fuels like coal is a major health problem and might also increase the risk of skin aging in Chinese women. As cooking with solid fuels is a major source of indoor air pollution exposure in China, we aimed to test if cooking with solid fuels is associated with more pronounced skin aging in Chinese women. We conducted two cross-sectional studies in China to assess the association between cooking with solid fuels and signs of skin aging. In Pingding (in northern China) we assessed N=405 and in Taizhou (in southern China) N=857 women between 30 and 90 years of age. Skin aging was evaluated by the SCINEXA score. Indoor air pollution exposure, sun exposure, smoking and other confounders were assessed by questionnaires. Associations were then tested by linear and logistic regression analyses adjusted for further confounders. The analysis showed that cooking with solid fuels was significantly associated with a 5-8% more severe wrinkle appearance on face and an 74% increased risk of having fine wrinkles on back of hands in both studies combined, independent of age and other influences on skin aging. The present studies thus corroborate our previous finding that air pollution is associated with skin aging and extend it by showing that indoor air pollution might be another risk factor for skin aging. Copyright © 2015. Published by Elsevier Ireland Ltd.

  7. Clean Air Program : Design Guidelines for Bus Transit Systems Using Alcohol Fuel (Methanol and Ethanol) as an Alternative Fuel

    Science.gov (United States)

    1996-08-01

    Although there are over one thousand transit buses in revenue service in the U.S. that are powered by alternative fuels, there are no comprehensive guidelines for the safe design and operation of alternative fuel facilities and vehicles for transit s...

  8. Activated carbon derived from chitosan as air cathode catalyst for high performance in microbial fuel cells

    Science.gov (United States)

    Liu, Yi; Zhao, Yong; Li, Kexun; Wang, Zhong; Tian, Pei; Liu, Di; Yang, Tingting; Wang, Junjie

    2018-02-01

    Chitosan with rich of nitrogen is used as carbon precursor to synthesis activated carbon through directly heating method in this study. The obtained carbon is activated by different amount of KOH at different temperatures, and then prepared as air cathodes for microbial fuel cells. Carbon sample treated with double amount of KOH at 850 °C exhibits maximum power density (1435 ± 46 mW m-2), 1.01 times improved, which ascribes to the highest total surface area, moderate micropore and mesoporous structure and the introduction of nitrogen. The electrochemical impedance spectroscopy and powder resistivity state that carbon treated with double amount of KOH at 850 °C possesses lower resistance. The other electrochemical measurements demonstrate that the best kinetic activity make the above treated sample to show the best oxygen reduction reaction activity. Besides, the degree of graphitization of samples increases with the activated temperature increasing, which is tested by Raman. According to elemental analysis and X-ray photoelectron spectroscopy, all chitosan samples are nitrogen-doped carbon, and high content nitrogen (pyridinic-N) improves the electrochemical activity of carbon treated with KOH at 850 °C. Thus, carbon materials derived from chitosan would be an optimized catalyst for oxygen reduction reaction in microbial fuel cell.

  9. A MultiAir®/MultiFuel Approach to Enhancing Engine System Efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Reese, Ronald [Chrysler Group LLC., Auburn Hills, MI (United States)

    2015-05-20

    FCA US LLC (formally known as Chrysler Group LLC, and hereinafter “Chrysler”) was awarded an American Recovery and Reinvestment Act (ARRA) funded project by the Department of Energy (DOE) titled “A MultiAir®/MultiFuel Approach to Enhancing Engine System Efficiency” (hereinafter “project”). This award was issued after Chrysler submitted a proposal for Funding Opportunity Announcement DE-FOA- 0000079, “Systems Level Technology Development, Integration, and Demonstration for Efficient Class 8 Trucks (SuperTruck) and Advanced Technology Powertrains for Light-Duty Vehicles (ATP-LD).” Chrysler started work on this project on June 01, 2010 and completed testing activities on August 30, 2014. Overall objectives of this project were; Demonstrate a 25% improvement in combined Federal Test Procedure (FTP) City and Highway fuel economy over a 2009 Chrysler minivan; Accelerate the development of highly efficient engine and powertrain systems for light-duty vehicles, while meeting future emissions standards; and Create and retain jobs in accordance with the American Recovery and Reinvestment Act of 2009

  10. Temperature dependence of an abiotic glucose/air alkaline fuel cell

    Science.gov (United States)

    Orton, Dane; Scott, Daniel

    2015-11-01

    The temperature dependence of a previously developed glucose fuel cell is explored. This cell uses a small molecule dye mediator to transport oxidizable electrons from glucose to a carbon felt anode. This reaction is driven by an air breathing MnO2 cathode. This research investigates how the temperature of the system affects the power production of the fuel cell. Cell performance is observed using either methyl viologen, indigo carmine, trypan blue, or hydroquinone as a mediator at temperatures of 15, 19, 27, 32, 37, 42, and 49 °C. Cyclic voltammetry of the cell anode at the given temperatures with the individual dyes is also presented. The highest power production amongst all of the cells occurs at 32 °C. This occurs with the mediator indigo carmine or with the mediator methyl viologen. These sustained powers are 2.31 mW cm-2 and 2.39 mW cm-2, respectively. This is approximately a 350% increase for these cells compared to their power produced at room temperature. This dramatic increase is likely due to increased solubility of the mediator dye at higher temperatures.

  11. Research and Development of Zinc Air Fuel Cell To Achieve Commercialization Final Report CRADA No. TC-1544-98

    Energy Technology Data Exchange (ETDEWEB)

    Cooper, J. F. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Haley, H. D. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2017-09-28

    The specific goal of this project was to advance the development of the zinc air fuel cell (ZAFC) towards commercial readiness in different mobile applications, including motor bikes, passenger cars, vans, buses and off-road vehicles (golf carts, factory equipment), and different stationary applications including generator sets, uninterruptible power systems and electric utility loading leveling and distributive power.

  12. Diode laser absorption measurement and analysis of HCN in atmospheric-pressure, fuel-rich premixed methane/air flames

    NARCIS (Netherlands)

    Gersen, Sander; Mokhov, A. V.; Levinsky, H. B.

    2008-01-01

    Measurements of HCN in flat, fuel-rich premixed methane/air flames at atmospheric pressure are reported. Quartz-microprobe sampling followed by wavelength modulation absorption spectroscopy with second harmonic detection was used to obtain an overall measurement uncertainty of better than 20% for

  13. Impacts of using reformulated and oxygenated fuel blends on the regional air quality of the upper Rhine valley

    Directory of Open Access Journals (Sweden)

    J.-F. Vinuesa

    2006-01-01

    Full Text Available The effects of using three alternative gasoline fuel blends on regional air quality of the upper Rhine valley have been investigated. The first of the tested fuels is oxygenated by addition of ethyl-tertio-butyl ether (ETBE, the second is based on a reformulation of its composition and the third on is both oxygenated and reformulated. The upper Rhine valley is a very sensitive region for pollution episodes and several meteorological and air quality studies have already been performed. High temporal and spatial emission inventories are available allowing relevant and realistic modifications of the emission inventories. The calculation period, i.e., 11 May 1998, corresponds to a regional photochemical ozone pollution episode during which ozone concentrations exceeded several times the information threshold of the ozone directive of the European Union (180 μg m-3 as 1 hourly average. New emission inventories are set up using specific emission factors related to the alternative fuels by varying the fraction of gasoline passenger cars (from 50% to 100% using the three fuel blends. Then air quality modeling simulations are performed using these emission inventories over the upper Rhine valley. The impact of alternative fuels on regional air quality is evaluated by comparing these simulations with the one using a reference emission inventory, e.g., where no modifications of the fuel composition are included. The results are analyzed by focusing on peak levels and daily averaged concentrations. The use of the alternative fuels leads to general reductions of ozone and volatile organic compounds (VOC and increases of NOx levels. We found different behaviors related to the type of the area of concern i.e. rural or urban. The impacts on ozone are enhanced in urban areas where 15% reduction of the ozone peak and daily averaged concentrations can be reached. This behavior is similar for the NOx for which, in addition, an increase of the levels can be noted

  14. A Single-Chamber Microbial Fuel Cell without an Air Cathode

    Science.gov (United States)

    Nimje, Vanita Roshan; Chen, Chien-Cheng; Chen, Hau-Ren; Chen, Chien-Yen; Tseng, Min-Jen; Cheng, Kai-Chien; Shih, Ruey-Chyuan; Chang, Young-Fo

    2012-01-01

    Microbial fuel cells (MFCs) represent a novel technology for wastewater treatment with electricity production. Electricity generation with simultaneous nitrate reduction in a single-chamber MFC without air cathode was studied, using glucose (1 mM) as the carbon source and nitrate (1 mM) as the final electron acceptor employed by Bacillus subtilis under anaerobic conditions. Increasing current as a function of decreased nitrate concentration and an increase in biomass were observed with a maximum current of 0.4 mA obtained at an external resistance (Rext) of 1 KΩ without a platinum catalyst of air cathode. A decreased current with complete nitrate reduction, with further recovery of the current immediately after nitrate addition, indicated the dependence of B. subtilis on nitrate as an electron acceptor to efficiently produce electricity. A power density of 0.0019 mW/cm2 was achieved at an Rext of 220 Ω. Cyclic voltammograms (CV) showed direct electron transfer with the involvement of mediators in the MFC. The low coulombic efficiency (CE) of 11% was mainly attributed to glucose fermentation. These results demonstrated that electricity generation is possible from wastewater containing nitrate, and this represents an alternative technology for the cost-effective and environmentally benign treatment of wastewater. PMID:22489190

  15. A Single-Chamber Microbial Fuel Cell without an Air Cathode

    Directory of Open Access Journals (Sweden)

    Ruey-Chyuan Shih

    2012-03-01

    Full Text Available Microbial fuel cells (MFCs represent a novel technology for wastewater treatment with electricity production. Electricity generation with simultaneous nitrate reduction in a single-chamber MFC without air cathode was studied, using glucose (1 mM as the carbon source and nitrate (1 mM as the final electron acceptor employed by Bacillus subtilis under anaerobic conditions. Increasing current as a function of decreased nitrate concentration and an increase in biomass were observed with a maximum current of 0.4 mA obtained at an external resistance (Rext of 1 KΩ without a platinum catalyst of air cathode. A decreased current with complete nitrate reduction, with further recovery of the current immediately after nitrate addition, indicated the dependence of B. subtilis on nitrate as an electron acceptor to efficiently produce electricity. A power density of 0.0019 mW/cm2 was achieved at an Rext of 220 Ω. Cyclic voltammograms (CV showed direct electron transfer with the involvement of mediators in the MFC. The low coulombic efficiency (CE of 11% was mainly attributed to glucose fermentation. These results demonstrated that electricity generation is possible from wastewater containing nitrate, and this represents an alternative technology for the cost-effective and environmentally benign treatment of wastewater.

  16. Experimental investigation on the effect of intake air temperature and air-fuel ratio on cycle-to-cycle variations of HCCI combustion and performance parameters

    Energy Technology Data Exchange (ETDEWEB)

    Maurya, Rakesh Kumar; Agarwal, Avinash Kumar [Engine Research Laboratory, Department of Mechanical Engineering, Indian Institute of Technology Kanpur, Kanpur 208016 (India)

    2011-04-15

    Combustion in HCCI engines is a controlled auto ignition of well-mixed fuel, air and residual gas. Since onset of HCCI combustion depends on the auto ignition of fuel/air mixture, there is no direct control on the start of combustion process. Therefore, HCCI combustion becomes unstable rather easily, especially at lower and higher engine loads. In this study, cycle-to-cycle variations of a HCCI combustion engine fuelled with ethanol were investigated on a modified two-cylinder engine. Port injection technique is used for preparing homogeneous charge for HCCI combustion. The experiments were conducted at varying intake air temperatures and air-fuel ratios at constant engine speed of 1500 rpm and P-{theta} diagram of 100 consecutive combustion cycles for each test conditions at steady state operation were recorded. Consequently, cycle-to-cycle variations of the main combustion parameters and performance parameters were analyzed. To evaluate the cycle-to-cycle variations of HCCI combustion parameters, coefficient of variation (COV) of every parameter were calculated for every engine operating condition. The critical optimum parameters that can be used to define HCCI operating ranges are 'maximum rate of pressure rise' and 'COV of indicated mean effective pressure (IMEP)'. (author)

  17. Experimental analysis of the local heat transfer coefficient of falling film evaporation with and without co-current air flow velocity

    Science.gov (United States)

    Louahlia-Gualous, H.; Omari, L. El.; Panday, P. K.; Artioukhine, E.

    2005-10-01

    This paper presents the experimental results of the local heat transfer for falling film evaporation of water sheet by solving the inverse heat conduction problem. It is shown that the local heat transfer coefficients increase by increasing the air flow velocity, the film liquid flow rate or decreasing the inlet bulk film temperature. Correlations for the mean heat transfer coefficients in the absence of superimposed flow for the stagnation region, the thermally developed region and the bottom of the heated cylinder are proposed.

  18. The dynamic velocity of long positive streamers observed using a multi-frame ICCD camera in a 57 cm air gap

    Science.gov (United States)

    Zeng, Rong; Chen, She

    2013-12-01

    The streamer propagation plays an important role in long air gap discharge. In this paper, a multi-frame intensified charge-coupled display (ICCD) camera was used to observe the long positive streamers in a 57 cm air gap. The propagation process of the 20-30 cm long streamers was captured, and the velocity variation in a single streamer was analysed. When applying a +210-290 kV lightning impulse voltage on a rod-plane gap with three different tips, the velocity of a streamer decreases from 8.3 ± 2.7 mm ns-1 at the ignition stage to 0.4 ± 0.1 mm ns-1 at the later stage. The influence of the applied voltage and the electrode size was obtained and analysed. Higher voltage amplitude and larger electrode size lead to a greater velocity. In addition, the relationship between the velocity and the background electric field is discussed here, and the experimental results are compared with an analytical model of different parameters.

  19. Manipulating ship fuel sulfur content and modeling the effects on air quality and climate

    Science.gov (United States)

    Partanen, Antti-Ilari; Laakso, Anton; Schmidt, Anja; Kokkola, Harri; Kuokkanen, Tuomas; Kerminen, Veli-Matti; Lehtinen, Kari E. J.; Laakso, Lauri; Korhonen, Hannele

    2013-04-01

    Aerosol emissions from international shipping are known to cause detrimental health effects on people mainly via increased lung cancer and cardiopulmonary diseases. On the other hand, the aerosol particles from the ship emissions modify the properties of clouds and are believed to have a significant cooling effect on the global climate. In recent years, aerosol emissions from shipping have been more strictly regulated in order to improve air quality and thus decrease the mortality due to ship emissions. Decreasing the aerosol emissions from shipping is projected to decrease their cooling effect, which would intensify the global warming even further. In this study, we use a global aerosol-climate model ECHAM5.5-HAM2 to test if continental air quality can be improved while still retaining the cooling effect from shipping. The model explicitly resolves emissions of aerosols and their pre-cursor gases. The model also calculates the interaction between aerosol particles and clouds, and can thus predict the changes in cloud properties due to aerosol emissions. We design and simulate a scenario where ship fuel sulfur content is strictly limited to 0.1% near all coastal regions, but doubled in the open oceans from the current global mean value of 2.7% (geo-ships). This scenario is compared to three other simulations: 1) No shipping emissions at all (no-ships), 2) present-day shipping emissions (std-ships) and 3) a future scenario where sulfur content is limited to 0.1% in the coastal zones and to 0.5% in the open ocean (future-ships). Global mean radiative flux perturbation (RFP) in std-ships compared to no-ships is calculated to be -0.4 W m-2, which is in the range of previous estimates for present-day shipping emissions. In the geo-ships simulation the corresponding global mean RFP is roughly equal, but RFP is spatially distributed more on the open oceans, as expected. In future-ships the decreased aerosol emissions provide weaker cooling effect of only -0.1 W m-2. In

  20. Mixed cellulose ester filter as a separator for air-diffusion cathode microbial fuel cells.

    Science.gov (United States)

    Wang, Zejie; Lim, Bongsu

    2017-04-01

    Separator is important to prevent bio-contamination of the catalyst layer of air-diffusion cathode microbial fuel cells (MFCs). Mixed cellulose ester filter (MCEF) was examined as a separator for an air-cathode MFC in the present study. The MCEF-MFC produced a maximum power density of 780.7 ± 18.7 mW/m2, which was comparable to 770.9 ± 35.9 mW/m2 of MFC with Nafion membrane (NFM) as a separator. Long-term examination demonstrated a more stable performance of the MCEF-MFC than NFM-MFC. After 25 cycles, the maximum voltage of the MCEF-MFC decreased by only 1.3% from 425.1 ± 4.3 mV (initial 5 cycles) to 419.5 ± 2.3 mV (last 5 cycles). However, it was decreased by 9.1% from 424.8 ± 5.7 to 386 ± 2.5 mV for the NFM-MFC. The coulombic efficiency (CE) of the MCEF-MFC did not change (from 3.11 ± 0.09% to 3.13 ± 0.02%), while it decreased by 9.12% from 3.18 ± 0.04% to 2.89 ± 0.02% for the NFM-MFC. The MCEF separator was with less biofouling than the NFM separator over 60 days' operation, which might be the reason for the more table long-term performance of the MCEF-MFC. The results demonstrated that MCEF was feasible as a separator to set up good-performing and cost-effective air-diffusion cathode MFC.

  1. Influence of air contaminants on planar, self-breathing hydrogen PEM fuel cells in an outdoor environment

    Science.gov (United States)

    Biesdorf, Johannes; Zamel, Nada; Kurz, Timo

    2014-02-01

    In this study, the effects of air contaminants on the operation of air-breathing fuel cells in an outdoor environment are investigated. For this purpose, a unique testing platform, which allows continuous operation of 30 cells at different locations, was developed. Three of these testing platforms were placed at different sites in Freiburg im Breisgau, Germany, with high variances of weather and pollution patterns. These locations range from a highly polluted place next to a busy highway to a location with virtually pure air at an altitude of 1205 m. The fuel cells were tested at all sites for over 4500 h in continuous operation. The degradation of the cells due to air pollutants was measured as a voltage decrease for three different operation loads and membranes from two different manufactures. As the temperature of the fuel cells has not been regulated, the irreversible degradation of the cell voltages could not be isolated from the dominant influence of the temperature in the raw data. With the use of the measured data, the impact of real mixtures of air contaminants was observed to be mainly reversible.

  2. Selected properties of high velocity oxy liquid fuel (HVOLF - sprayed nanocrystalline WC-CO INFRALLOYTM S7412 coatings modified by high energy electric pulse

    Directory of Open Access Journals (Sweden)

    S. Spadło

    2017-01-01

    Full Text Available The paper presents a brief study of selected properties of HVOLF-sprayed nanocrystalline WC-Co InfralloyTM S7412 coatings modified by the application of a high energy electric pulse. The anti-wear coatings were applied on carbon steel with the use of High Velocity Oxy Liquid Fuel (HVOLF spraying system TAFA – JP-5000. The process was modified by the application of the SST France & Vision Lasertechnik device WS 7000 S. The resultant type of coatings may be applied to increase the abrasive wear resistance of tools and machine parts. The properties of the powders and coatings were studied using metallographic methods and EDS analyses. The microhardness and nanohardness of the resultant layers were measured and Young’s modulus of elasticity was determined.

  3. The effect of post-treatment of a high-velocity oxy-fuel Ni-Cr-Mo-Si-B coating Part I: Microstructure/corrosion behavior relationships

    Science.gov (United States)

    Shrestha, S.; Hodgkiess, T.; Neville, A.

    2001-09-01

    The microstructure and aqueous corrosion characteristics of a Ni-Cr-Mo-Si-B high-velocity oxy-fuel (HVOF) coating have been assessed. It has been shown that postprocessing by vacuum fusion has a significant effect on the coating microstructure by increasing the type and concentration of hard phase particles. The principal hard phases in the as-sprayed condition and vacuum-sealed condition are chromium carbides, whereas molybdenum-containing boride phases are also present after vacuum fusion. Vacuumfusion post-treatment eliminates splat boundaries, which can act as sites, where preferential corrosion can occur and, hence, the dominant corrosion mechanisms change. In as-sprayed and vacuum-sealed coatings, localized attack at splat particle boundaries and crevice corrosion dominate, whereas in vacuum-fused coating, the principal mechanism of corrosion is “micropitting” as a result of the hard phase loss.

  4. A Method for Retrieving Vertical Air Velocities in Convective Clouds over the Tibetan Plateau from TIPEX-III Cloud Radar Doppler Spectra

    Directory of Open Access Journals (Sweden)

    Jiafeng Zheng

    2017-09-01

    Full Text Available In the summertime, convective cells occur frequently over the Tibetan Plateau (TP because of the large dynamic and thermal effects of the landmass. Measurements of vertical air velocity in convective cloud are useful for advancing our understanding of the dynamic and microphysical mechanisms of clouds and can be used to improve the parameterization of current numerical models. This paper presents a technique for retrieving high-resolution vertical air velocities in convective clouds over the TP through the use of Doppler spectra from vertically pointing Ka-band cloud radar. The method was based on the development of a “small-particle-traced” idea and its associated data processing, and it used three modes of radar. Spectral broadening corrections, uncertainty estimations, and results merging were used to ensure accurate results. Qualitative analysis of two typical convective cases showed that the retrievals were reliable and agreed with the expected results inferred from other radar measurements. A quantitative retrieval of vertical air motion from a ground-based optical disdrometer was used to compare with the radar-derived result. This comparison illustrated that, while the data trends from the two methods of retrieval were in agreement while identifying the updrafts and downdrafts, the cloud radar had a much higher resolution and was able to reveal the small-scale variations in vertical air motion.

  5. [Electricity generation using the short-arm air-cathode microbial fuel cell].

    Science.gov (United States)

    Guo, Kun; Li, Ding-jie; Li, Hao-ran; Du, Zhu-wei

    2009-10-15

    The short-arm air-cathode microbial fuel cell (ACMFC) was constructed using a cramp to fix the proton exchange membrane (PEM) and carbon paper with 0.5 mg/cm2 onto the short-arm side of the anode chamber. Exoelectrogens on the surface of graphite rod were enriched by a sludge microbial fuel cell from the anaerobic digestion sludge. And the cyclic voltammetry result showed these microbes had electrochemical activities. Using the graphite rod covered by exoelectrogens as the anode and sodium acetate as the substrate, the short-arm ACMFC showed a maximal power density (Pm) of 738 mW/m2, internal resistance (Ri) of 280 omega and open circuit voltage (OCV) of 741 mV. Continuous sparging the anode chamber with nitrogen or removal of the proton exchange membrane enhance the Pm of the cell to 745 mW/m2 and 759 mW/m2 respectively. When both of the two measures were used together, the Pm reached up to 922 mW/m2. Under these three conditions the Ri of the cell was kept around 280 omega. When the substrate concentration was 12.62-100.96 mg/L and external resistance was 510 omega, the maximal voltage of the cell and the substrate concentration showed an obvious linear relation (R2 = 0.99). But when the concentration was above 100.96 mg/L, the maximal voltage stably kept around 302mV(the external resistance was 510 omega). However, the Coulombic efficiency of the short-arm ACMFC gradually increased with the increase of the substrate concentration, from 31.83% to 45.03%.

  6. Water velocity at water-air interface is not zero: Comment on "Three-dimensional quantification of soil hydraulic properties using X-ray computed tomography and image-based modeling" by Saoirse R. Tracy et al.

    Science.gov (United States)

    Zhang, X. X.; Fan, X. Y.; Li, Z. Y.

    2016-07-01

    Tracy et al. (2015, doi: 10.1002/2014WR016020) assumed in their recent paper that water velocity at the water-air interface is zero in their pore-scale simulations of water flow in 3-D soil images acquired using X-ray computed tomography. We comment that such a treatment is physically wrong, and explain that it is the water-velocity gradient in the direction normal to the water-air interface, rather than the water velocity, that should be assumed to be zero at the water-air interface if one needs to decouple the water flow and the air flow. We analyze the potential errors caused by incorrectly taking water velocity at the water-air interface zero based on two simple examples, and conclude that it is not physically sound to make such a presumption because its associated errors are unpredictable.

  7. Hot-wire air flow meter for gasoline fuel-injection system. Calculation of air mass in cylinder during transient condition; Gasoline funsha system yo no netsusenshiki kuki ryuryokei. Kato untenji no cylinder juten kukiryo no keisan

    Energy Technology Data Exchange (ETDEWEB)

    Oyama, Y. [Hitachi Car Engineering, Ltd., Tokyo (Japan); Nishimura, Y.; Osuga, M.; Yamauchi, T. [Hitachi, Ltd., Tokyo (Japan)

    1997-10-01

    Air flow characteristics of hot-wire air flow meters for gasoline fuel-injection systems with supercharging and exhaust gas recycle during transient conditions were investigated to analyze a simple method for calculating air mass in cylinder. It was clarified that the air mass in cylinder could be calculated by compensating for the change of air mass in intake system by using aerodynamic models of intake system. 3 refs., 6 figs., 1 tab.

  8. CFD Analysis on the Passive Heat Removal by Helium and Air in the Canister of Spent Fuel Dry Storage System

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Do Young; Jeong, Ui Ju; Kim, Sung Joong [Hanyang University, Seoul (Korea, Republic of)

    2016-05-15

    In the current commercial design, the canister of the dry storage system is mainly backfilled with helium gas. Helium gas shows very conductive behavior due to high thermal conductivity and small density change with temperature. However, other gases such as air, argon, or nitrogen are expected to show effective convective behavior. Thus these are also considered as candidates for the backfill gas to provide effective coolability. In this study, to compare the dominant cooling mechanism and effectiveness of cooling between helium gas and air, a computational fluid dynamics (CFD) analysis for the canister of spent fuel dry storage system with backfill gas of helium and air is carried out. In this study, CFD simulations for the helium and air backfilled gas for dry storage system canister were carried out using ANSYS FLUENT code. For the comparison work, two backfilled fluids were modeled with same initial and boundary conditions. The observed major difference can be summarized as follows. - The simulation results showed the difference in dominant heat removal mechanism. Conduction for helium, and convection for air considering Reynolds number distribution. - The temperature gradient inside the fuel assembly showed that in case of air, more effective heat mixing occurred compared to helium.

  9. Combinatorial electrochemical cell array for high throughput screening of micro-fuel-cells and metal/air batteries.

    Science.gov (United States)

    Jiang, Rongzhong

    2007-07-01

    An electrochemical cell array was designed that contains a common air electrode and 16 microanodes for high throughput screening of both fuel cells (based on polymer electrolyte membrane) and metal/air batteries (based on liquid electrolyte). Electrode materials can easily be coated on the anodes of the electrochemical cell array and screened by switching a graphite probe from one cell to the others. The electrochemical cell array was used to study direct methanol fuel cells (DMFCs), including high throughput screening of electrode catalysts and determination of optimum operating conditions. For screening of DMFCs, there is about 6% relative standard deviation (percentage of standard deviation versus mean value) for discharge current from 10 to 20 mAcm(2). The electrochemical cell array was also used to study tin/air batteries. The effect of Cu content in the anode electrode on the discharge performance of the tin/air battery was investigated. The relative standard deviations for screening of metal/air battery (based on zinc/air) are 2.4%, 3.6%, and 5.1% for discharge current at 50, 100, and 150 mAcm(2), respectively.

  10. Seasonal and long-term variation of 210Pb concentration in air, atmospheric deposition rate and total deposition velocity in south Germany.

    Science.gov (United States)

    Winkler, R; Rosner, G

    2000-12-18

    The activity concentration in air and atmospheric deposition rate of the long-lived radon progeny 210Pb has been investigated at Munich-Neuherberg, south Germany, from 1972 (activity concentration) and from 1981 (atmospheric flux) to 1999. For these periods, the continuous measurements yielded an average 210Pb activity concentration at ground level of 0.57 mBq m(-3) and an average total 210Pb deposition rate to ground of 180 Bq m(-2) year(-1). The average total deposition velocity, which relates the total 210Pb deposition rate to the 210Pb activity concentration was calculated to be 1.0 cm s(-1). The variation of the data with time was studied by time-series analysis and distinct seasonal patterns were identified. Maximum 210Pb activity concentrations in air are observed in the autumn and winter months (October through February) of each year. By contrast, the maximum 210Pb deposition rate is observed during summer (June-August), i.e. in the months with the highest amount of rainfall at this site. Like the 210Pb deposition rate, the total deposition velocity exhibits a seasonal pattern with maximum values in summer. Due to the long observation period of 18 years, it was possible to observe for the first time a strong positive relationship between 210Pb deposition and precipitation, especially for the months May and June and to a smaller extent for several other months. In the long-term, variations of approximately a factor of 2 were observed in the annual average 210Pb activity concentrations, the annual deposition sums and the annual average deposition velocities. Since around 1981 210Pb concentrations in air steadily decreased while 210Pb depositions increased. As a consequence of these significant trends, the time series of the total deposition velocity exhibits a trend of the data from approximately 0.7 cm s(-1) in 1981 to 1.7 cm s(-1) in 1999.

  11. Indoor air pollution from secondhand tobacco smoke, solid fuels, and kerosene in homes with active tuberculosis disease in South Africa.

    Science.gov (United States)

    Elf, Jessica L; Eke, Onyinyechi; Rakgokong, Modiehi; Variava, Ebrahim; Baliram, Yudesh; Motlhaoleng, Katlego; Lebina, Limakatso; Shapiro, Adrienne E; Breysse, Patrick N; Golub, Jonathan E; Martinson, Neil

    2017-11-13

    Secondhand tobacco smoke (SHS), use of solid fuels, and kerosene may play an important role in perpetuating the tuberculosis (TB) epidemic. The purpose of this study was to explore the prevalence of household air pollution (HAP) from these sources in homes of someone with TB in a high HIV-prevalence setting. A convenience sample of homes and household members participating in an ongoing active case-finding study in Matlosana district townships surrounding Klerksdorp, South Africa were included. We found a high prevalence of air pollution from SHS, solid fuels, and kerosene among individuals in homes with a case of prevalent active TB disease in Klerksdorp, South Africa. Adults in 40% of homes reported a daily smoker in the home, and 70% of homes had detectable air nicotine. In homes with a history of previous TB (prior to but not including the index case) as compared to those without previous TB, both SHS (83% vs. 65%, respectively) and solid/kerosene fuel use for more than 1 h/day (27% vs. 21%, respectively) were more prevalent. Larger studies are needed to estimate the risk of TB from these types of air pollution in HIV infected individuals and settings with high HIV prevalence.

  12. Effect of indoor air pollution from biomass and solid fuel combustion on symptoms of preeclampsia/eclampsia in Indian women.

    Science.gov (United States)

    Agrawal, S; Yamamoto, S

    2015-06-01

    Available evidence concerning the association between indoor air pollution (IAP) from biomass and solid fuel combustion and preeclampsia/eclampsia is not available in developing countries. We investigated the association between exposure to IAP from biomass and solid fuel combustion and symptoms of preeclampsia/eclampsia in Indian women by analyzing cross-sectional data from India's third National Family Health Survey (NFHS-3, 2005-2006). Self-reported symptoms of preeclampsia/eclampsia during pregnancy such as convulsions (not from fever), swelling of legs, body or face, excessive fatigue or vision difficulty during daylight, were obtained from 39,657 women aged 15-49 years who had a live birth in the previous 5 years. Effects of exposure to cooking smoke, ascertained by type of fuel used for cooking on preeclampsia/eclampsia risk, were estimated using logistic regression after adjusting for various confounders. Results indicate that women living in households using biomass and solid fuels have two times higher likelihood of reporting preeclampsia/eclampsia symptoms than do those living in households using cleaner fuels (OR = 2.21; 95%: 1.26-3.87; P = 0.006), even after controlling for the effects of a number of potentially confounding factors. This study is the first to empirically estimate the associations of IAP from biomass and solid fuel combustion and reported symptoms suggestive of preeclampsia/eclampsia in a large nationally representative sample of Indian women and we observed increased risk. These findings have important program and policy implications for countries such as India, where large proportions of the population rely on polluting biomass fuels for cooking and space heating. More epidemiological research with detailed exposure assessments and clinical measures of preeclampsia/eclampsia is needed in a developing country setting to validate these findings. © 2014 The Authors. Indoor Air published by John Wiley & Sons Ltd.

  13. Advanced air staging techniques to improve fuel flexibility, reliability and emissions in fluidized bed co-combustion

    Energy Technology Data Exchange (ETDEWEB)

    Aamand, Lars-Erik; Leckner, Bo [Chalmers Technical Univ., Goeteborg (Sweden); Luecke, Karsten; Werther, Joachim [Technical Univ. of Hamburg-Harburg (Germany)

    2001-12-01

    A joint research project between the Technical University of Hamburg-Harburg and Chalmers Technical University. For operation under co-combustion the following results should be considered: The high ash content of the sewage sludge results in significantly increased ash flows. Although high alkali metal concentrations are found in the sewage sludge ash, no critical concentrations were reached and tendencies to fouling were not observed. The trace metal input rises with increased sludge fraction. However, emissions of metal compounds were well below legal limits. The trace metals tend to accumulate on the fly ash. In general, very low fuel nitrogen conversions to NO and N{sub 2}O of 2 - 4 % are achievable. With coal as a base fuel alternative air staging with secondary air supply after solids separation attains even lower NO emissions than normal staging without strongly affecting CO and SO{sub 2} emissions. Alternative staging also reduces N{sub 2}O emissions. An optimum for the excess air ratio in the riser of 1.05 was found for a total excess air ratio of 1.2. The higher the volatile content of the fuel is, the less effective the NO reduction due to air staging becomes. The measurements suggest that the optimum gas residence time regarding the emissions in CFB combustors is around 6 to 7 s. These times are achieved in commercial scale plants due to their large cyclones that perhaps partly can replace a large afterburner chamber. The circulating fluidized bed boiler can be operated in a very flexible way with various fuel mixtures up to an energy fraction of sludge of 25% without exceeding legal emission limits.

  14. Diffusion layer characteristics for increasing the performance of activated carbon air cathodes in microbial fuel cells

    KAUST Repository

    Zhang, Xiaoyuan

    2016-01-01

    The characteristics of several different types of diffusion layers were systematically examined to improve the performance of activated carbon air cathodes used in microbial fuel cells (MFCs). A diffusion layer of carbon black and polytetrafluoroethylene (CB + PTFE) that was pressed onto a stainless steel mesh current collector achieved the highest cathode performance. This cathode also had a high oxygen mass transfer coefficient and high water pressure tolerance (>2 m), and it had the highest current densities in abiotic chronoamperometry tests compared to cathodes with other diffusion layers. In MFC tests, this cathode also produced maximum power densities (1610 ± 90 mW m−2) that were greater than those of cathodes with other diffusion layers, by 19% compared to Gore-Tex (1350 ± 20 mW m−2), 22% for a cloth wipe with PDMS (1320 ± 70 mW m−2), 45% with plain PTFE (1110 ± 20 mW m−2), and 19% higher than those of cathodes made with a Pt catalyst and a PTFE diffusion layer (1350 ± 50 mW m−2). The highly porous diffusion layer structure of the CB + PTFE had a relatively high oxygen mass transfer coefficient (1.07 × 10−3 cm s−1) which enhanced oxygen transport to the catalyst. The addition of CB enhanced cathode performance by increasing the conductivity of the diffusion layer. Oxygen mass transfer coefficient, water pressure tolerance, and the addition of conductive particles were therefore critical features for achieving higher performance AC air cathodes.

  15. Air-cathode structure optimization in separator-coupled microbial fuel cells

    KAUST Repository

    Zhang, Xiaoyuan

    2011-12-01

    Microbial fuel cells (MFC) with 30% wet-proofed air cathodes have previously been optimized to have 4 diffusion layers (DLs) in order to limit oxygen transfer into the anode chamber and optimize performance. Newer MFC designs that allow close electrode spacing have a separator that can also reduce oxygen transfer into the anode chamber, and there are many types of carbon wet-proofed materials available. Additional analysis of conditions that optimize performance is therefore needed for separator-coupled MFCs in terms of the number of DLs and the percent of wet proofing used for the cathode. The number of DLs on a 50% wet-proofed carbon cloth cathode significantly affected MFC performance, with the maximum power density decreasing from 1427 to 855mW/m 2 for 1-4 DLs. A commonly used cathode (30% wet-proofed, 4 DLs) produced a maximum power density (988mW/m 2) that was 31% less than that produced by the 50% wet-proofed cathode (1 DL). It was shown that the cathode performance with different materials and numbers of DLs was directly related to conditions that increased oxygen transfer. The coulombic efficiency (CE) was more affected by the current density than the oxygen transfer coefficient for the cathode. MFCs with the 50% wet-proofed cathode (2 DLs) had a CE of >84% (6.8A/m 2), which was substantially larger than that previously obtained using carbon cloth air-cathodes lacking separators. These results demonstrate that MFCs constructed with separators should have the minimum number of DLs that prevent water leakage and maximize oxygen transfer to the cathode. © 2011 Elsevier B.V.

  16. MWCNT-supported phthalocyanine cobalt as air-breathing cathodic catalyst in glucose/O2 fuel cells

    Science.gov (United States)

    Elouarzaki, Kamal; Haddad, Raoudha; Holzinger, Michael; Le Goff, Alan; Thery, Jessica; Cosnier, Serge

    2014-06-01

    Simple and highly efficient glucose fuel cells using abiotic catalysts and different ion exchange membranes were designed. The glucose fuel cells are based on a multi-walled carbon nanotube (MWCNT)-supported cobalt phthalocyanine (CoPc) cathode and a carbon black/platinum (C/Pt) anode. The electrocatalytic activity of the MWCNT/CoPc electrode for oxygen reduction was investigated by cyclic and linear sweep voltammetry. The electrochemical experiments show that CoPc exhibits promising catalytic properties for oxygen reduction due to its high overpotential and efficiency at reduced metal load. The MWCNT/CoPc electrodes were applied to the oxygen reduction reaction as air-breathing cathode in a single-chambered glucose fuel cell. This cathode was associated with a C/Pt anode in fuel cell configurations using either an anion (Nafion®) or a cation (Tokuyama) exchange membrane. The best fuel cell configuration delivered a maximum power density of 2.3 mW cm-2 and a cell voltage of 0.8 V in 0.5 M KOH solution containing 0.5 M glucose using the Tokuyama membrane at ambient conditions. Beside the highest power density per cathodic catalyst mass (383 W g-1), these glucose fuel cells exhibit a high operational stability, delivering 0.3 mW cm-2 after 50 days.

  17. Regulatory fire test requirements for plutonium air transport packages : JP-4 or JP-5 vs. JP-8 aviation fuel.

    Energy Technology Data Exchange (ETDEWEB)

    Figueroa, Victor G.; Lopez, Carlos; Nicolette, Vernon F.

    2010-10-01

    For certification, packages used for the transportation of plutonium by air must survive the hypothetical thermal environment specified in 10CFR71.74(a)(5). This regulation specifies that 'the package must be exposed to luminous flames from a pool fire of JP-4 or JP-5 aviation fuel for a period of at least 60 minutes.' This regulation was developed when jet propellant (JP) 4 and 5 were the standard jet fuels. However, JP-4 and JP-5 currently are of limited availability in the United States of America. JP-4 is very hard to obtain as it is not used much anymore. JP-5 may be easier to get than JP-4, but only through a military supplier. The purpose of this paper is to illustrate that readily-available JP-8 fuel is a possible substitute for the aforementioned certification test. Comparisons between the properties of the three fuels are given. Results from computer simulations that compared large JP-4 to JP-8 pool fires using Sandia's VULCAN fire model are shown and discussed. Additionally, the Container Analysis Fire (CAFE) code was used to compare the thermal response of a large calorimeter exposed to engulfing fires fueled by these three jet propellants. The paper then recommends JP-8 as an alternate fuel that complies with the thermal environment implied in 10CFR71.74.

  18. Modeling and control of a proton exchange membrane fuel cell with the air compressor according to requested electrical current

    Directory of Open Access Journals (Sweden)

    Malekbala Mohammad Rahim

    2015-01-01

    Full Text Available The aim of this paper is to design and investigate the dynamic behavior of a PEM fuel cell system. Dynamic analysis of a PEM fuel cell system has been done in Matlab\\Simulink software according to electrical current that has been applied from hybrid system. In addition, dynamical fuel cell system has been explained according to oriented control that is started from air injection compressor model. Also hydrogen valve actuator has been controlled according to the compressor model. The results of the fuel cell dynamic model as well as the applied compressor model are fully validated based on the available results in the open literature. Finally, the effects of several operating parameters of the fuel cell system such as anode and cathode pressures, cell voltage, compressor voltage, compressor mass flow rate variation with respect to inlet pressure ratio, net and stack powers on the dynamic behavior of the hybrid system are investigated. The results show that the model can predict the dynamic behavior of the fuel cell system accurately and it can be used directly for any control purposes.

  19. Logistic Fuel Processor Development

    National Research Council Canada - National Science Library

    Salavani, Reza

    2004-01-01

    The Air Base Technologies Division of the Air Force Research Laboratory has developed a logistic fuel processor that removes the sulfur content of the fuel and in the process converts logistic fuel...

  20. Use of novel permeable membrane and air cathodes in acetate microbial fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Pant, Deepak, E-mail: deepak.pant@vito.b [Separation and Conversion Technology, VITO - Flemish Institute for Technological Research, Boeretang 200, Mol 2400 (Belgium); Van Bogaert, Gilbert; De Smet, Mark; Diels, Ludo; Vanbroekhoven, Karolien [Separation and Conversion Technology, VITO - Flemish Institute for Technological Research, Boeretang 200, Mol 2400 (Belgium)

    2010-11-01

    In the existing microbial fuel cells (MFCs), the use of platinized electrodes and Nafion as proton exchange membrane (PEM) leads to high costs leading to a burden for wastewater treatment. In the present study, two different novel electrode materials are reported which can replace conventional platinized electrodes and can be used as very efficient oxygen reducing cathodes. Further, a novel membrane which can be used as an ion permeable membrane (Zirfon) can replace Nafion as the membrane of choice in MFCs. The above mentioned gas porous electrodes were first tested in an electrochemical half cell configuration for their ability to reduce oxygen and later in a full MFC set up. It was observed that these non-platinized air electrodes perform very well in the presence of acetate under MFC conditions (pH 7, room temperature) for oxygen reduction. Current densities of -0.43 mA cm{sup -2} for a non-platinized graphite electrode and -0.6 mA cm{sup -2} for a non-platinized activated charcoal electrode at -200 mV vs. Ag/AgCl of applied potential were obtained. The proposed ion permeable membrane, Zirfonwas tested for its oxygen mass transfer coefficient, K{sub 0} which was compared with Nafion. The K{sub 0} for Zirfon was calculated as 1.9 x 10{sup -3} cm s{sup -1}.

  1. Influences of the Cloud Shape of Fuel-Air Mixtures on the Overpressure Field

    Directory of Open Access Journals (Sweden)

    Chunhua Bai

    2016-01-01

    Full Text Available This paper presents an experiment system in the open field, which comprises a charge structure (approximately 166.2 kg, a high-speed camera subsystem, and a pressure measurement subsystem. Through a series of experiments under the cylindrical clouds with different diameters, heights, and diameter-to-height ratios (D : H, the influences of various cloud shapes on the overpressure field were analyzed and discussed. Based on the experimental results, the overpressure field was divided into two zones: detonation wave zone and shock wave zone. It is found that the overpressure of shock waves at the same distance from the explosion center increased with the diameters, but the variations of heights had little impact on the overpressure. Therefore, the pancake-shaped cloud of fuel-air mixtures is the optimal shape for obtaining the wider overpressure field. Moreover, it is found that the overpressure field gets the maximum under the diameter-to-height ratios of 5.7 in the same distance within the studied range.

  2. Electricity generation from fermented primary sludge using single-chamber air-cathode microbial fuel cells

    KAUST Repository

    Yang, Fei

    2013-01-01

    Single-chamber air-cathode microbial fuel cells (MFCs) were used to generate electricity from fermented primary sludge. Fermentation (30°C, 9days) decreased total suspended solids (26.1-16.5g/L), volatile suspended solids (24.1-15.3g/L) and pH (5.7-4.5), and increased conductivity (2.4-4.7mS/cm), soluble COD (2.66-15.5g/L), and volatile fatty acids (1.9-10.1g/L). To lower the COD and increase pH, fermentation supernatant was diluted with primary effluent before being used in the MFCs. The maximum power density was 0.32±0.01W/m2, compared to 0.24±0.03W/m2 with only primary effluent. Power densities were higher with phosphate buffer added to the supernatant (1.03±0.06W/m2) or the solution (0.87±0.05W/m2). Coulombic efficiencies ranged from 18% to 57%, and sCOD removals from 84% to 94%. These results demonstrated that sludge can effectively be used for power generation when fermented and then diluted with only primary effluent. © 2012 Elsevier Ltd.

  3. Gas Diffusion Electrodes Manufactured by Casting Evaluation as Air Cathodes for Microbial Fuel Cells (MFC).

    Science.gov (United States)

    Srikanth, Sandipam; Pant, Deepak; Dominguez-Benetton, Xochitl; Genné, Inge; Vanbroekhoven, Karolien; Vermeiren, Philippe; Alvarez-Gallego, Yolanda

    2016-07-21

    One of the most intriguing renewable energy production methods being explored currently is electrical power generation by microbial fuel cells (MFCs). However, to make MFC technology economically feasible, cost efficient electrode manufacturing processes need to be proposed and demonstrated. In this context, VITO has developed an innovative electrode manufacturing process based on film casting and phase inversion. The screening and selection process of electrode compositions was done based on physicochemical properties of the active layer, which in turn maintained a close relation with their composition A dual hydrophilic-hydrophobic character in the active layer was achieved with values of ε hydrophilic up to 10% while ε TOTAL remained in the range 65 wt % to 75 wt %. Eventually, selected electrodes were tested as air cathodes for MFC in half cell and full cell modes. Reduction currents, up to -0.14 mA·cm 2- at -100 mV (vs. Ag/AgCl) were reached in long term experiments in the cathode half-cell. In full MFC, a maximum power density of 380 mW·m -2 was observed at 100 Ω external load.

  4. Gas Diffusion Electrodes Manufactured by Casting Evaluation as Air Cathodes for Microbial Fuel Cells (MFC

    Directory of Open Access Journals (Sweden)

    Sandipam Srikanth

    2016-07-01

    Full Text Available One of the most intriguing renewable energy production methods being explored currently is electrical power generation by microbial fuel cells (MFCs. However, to make MFC technology economically feasible, cost efficient electrode manufacturing processes need to be proposed and demonstrated. In this context, VITO has developed an innovative electrode manufacturing process based on film casting and phase inversion. The screening and selection process of electrode compositions was done based on physicochemical properties of the active layer, which in turn maintained a close relation with their composition A dual hydrophilic-hydrophobic character in the active layer was achieved with values of εhydrophilic up to 10% while εTOTAL remained in the range 65 wt % to 75 wt %. Eventually, selected electrodes were tested as air cathodes for MFC in half cell and full cell modes. Reduction currents, up to −0.14 mA·cm2− at −100 mV (vs. Ag/AgCl were reached in long term experiments in the cathode half-cell. In full MFC, a maximum power density of 380 mW·m−2 was observed at 100 Ω external load.

  5. Adaptive critic learning techniques for engine torque and air-fuel ratio control.

    Science.gov (United States)

    Liu, Derong; Javaherian, Hossein; Kovalenko, Olesia; Huang, Ting

    2008-08-01

    A new approach for engine calibration and control is proposed. In this paper, we present our research results on the implementation of adaptive critic designs for self-learning control of automotive engines. A class of adaptive critic designs that can be classified as (model-free) action-dependent heuristic dynamic programming is used in this research project. The goals of the present learning control design for automotive engines include improved performance, reduced emissions, and maintained optimum performance under various operating conditions. Using the data from a test vehicle with a V8 engine, we developed a neural network model of the engine and neural network controllers based on the idea of approximate dynamic programming to achieve optimal control. We have developed and simulated self-learning neural network controllers for both engine torque (TRQ) and exhaust air-fuel ratio (AFR) control. The goal of TRQ control and AFR control is to track the commanded values. For both control problems, excellent neural network controller transient performance has been achieved.

  6. Estimation of Individual Cylinder Air-Fuel Ratio in Gasoline Engine with Output Delay

    Directory of Open Access Journals (Sweden)

    Changhui Wang

    2016-01-01

    Full Text Available The estimation of the individual cylinder air-fuel ratio (AFR with a single universal exhaust gas oxygen (UEGO sensor installed in the exhaust pipe is an important issue for the cylinder-to-cylinder AFR balancing control, which can provide high-quality torque generation and reduce emissions in multicylinder engine. In this paper, the system dynamic for the gas in exhaust pipe including the gas mixing, gas transport, and sensor dynamics is described as an output delay system, and a new method using the output delay system observer is developed to estimate the individual cylinder AFR. With the AFR at confluence point augmented as a system state, an observer for the augmented discrete system with output delay is designed to estimate the AFR at confluence point. Using the gas mixing model, a method with the designed observer to estimate the individual cylinder AFR is presented. The validity of the proposed method is verified by the simulation results from a spark ignition gasoline engine from engine software enDYNA by Tesis.

  7. 40 CFR 1065.655 - Chemical balances of fuel, intake air, and exhaust.

    Science.gov (United States)

    2010-07-01

    ... orm fuel. (1) Crankcase flow rate. If engines are not subject to crankcase controls under the standard-setting part, you may calculate raw exhaust flow based on n int orm fuel using one of the following: (i...

  8. Environmental Assessment: Construction of Consolidated Fuel Overhaul and Repair Facility at Tinker Air Force Base, Oklahoma

    Science.gov (United States)

    2007-10-01

    qtr B3001 Add A 165gal/qtr B3001 hotsy soap 300gal/qtr B3108 acetone 12 cans/yr B3108 talc powder 12 pounds/yr B3108 isopropyl alcohol 48 gallons...handled in bulk at the base include JP-5, JP-8 (aviation fuel), JP-10 (missile fuel), Mogas (automotive gasoline), PF-1, diesel fuel, biodiesel fuel

  9. Association between the use of biomass fuels on respiratory health ...

    African Journals Online (AJOL)

    abp

    2013-05-06

    May 6, 2013 ... factors. Confounding variables such as smoking, age and fuel used at home were treated as independent factors in separate analyses. Although broader environmental factors such as temperature, humidity, air velocity, ambient air quality and others might have contributed to the observed respiratory health ...

  10. Anti-air pollution & energy conservation system for automobiles using leaded or unleaded gasoline, diesel or alternate fuel

    Science.gov (United States)

    Bose, Ranendra K.

    2002-06-04

    Exhaust gases from an internal combustion engine operating with leaded or unleaded gasoline or diesel or natural gas, are used for energizing a high-speed gas turbine. The convoluting gas discharge causes a first separation stage by stratifying of heavier and lighter exhaust gas components that exit from the turbine in opposite directions, the heavier components having a second stratifying separation in a vortex tube to separate combustible pollutants from non-combustible components. The non-combustible components exit a vortex tube open end to atmosphere. The lighter combustible, pollutants effected in the first separation are bubbled through a sodium hydroxide solution for dissolving the nitric oxide, formaldehyde impurities in this gas stream before being piped to the engine air intake for re-combustion, thereby reducing the engine's exhaust pollution and improving its fuel economy. The combustible, heavier pollutants from the second separation stage are piped to air filter assemblies. This gas stream convoluting at a high-speed through the top stator-vanes of the air filters, centrifugally separates the coalescent water, aldehydes, nitrogen dioxides, sulfates, sulfur, lead particles which collect at the bottom of the bowl, wherein it is periodically released to the roadway. Whereas, the heavier hydrocarbon, carbon particles are piped through the air filter's porous element to the engine air intake for re-combustion, further reducing the engine's exhaust pollution and improving its fuel economy.

  11. An air-breathing micro direct methanol fuel cell stack employing a single shared anode using silicon microfabrication technologies

    Science.gov (United States)

    Wang, Xiaohong; Zhou, Yan'an; Zhang, Qian; Zhu, Yiming; Liu, Litian

    2009-09-01

    This paper presents a silicon-based air-breathing micro direct methanol fuel cell (μDMFC) stack with a shared anode plate and two air-breathing cathode plates. Three kinds of anode plates featured by different methanol transport methods are designed and simulated. Microfabrication technologies, including double-side lithography and bulk-micromachining, are used to fabricate both anode and cathode silicon plates on the same wafer simultaneously. Three μDMFC stacks with different kinds of anodes are assembled, and characterized with a single cell together. Simulation and experimental results show that the μDMFC stack with fuel transport in a shared model has the best performance, and this stack achieves a power of 2.52 mW which is almost double that of a single cell of 1.28 mW.

  12. New fuel air control strategy for reducing NOx emissions from corner-fired utility boilers at medium-low loads

    DEFF Research Database (Denmark)

    Zhao, Sinan; Fang, Qingyan; Yin, Chungen

    2017-01-01

    . The combustion characteristics and NOx emissions from a 1000 MWe corner-fired tower boiler under different loads are investigated experimentally and numerically. A new control strategy for the annular fuel air is proposed and implemented in the boiler, in which the secondary air admitted to the furnace through...... of the selective catalytic reduction (SCR) system by about 20% at medium–low loads, compared to those based on the original control. The new control strategy has also been successfully applied to two other corner-fired boilers to achieve a significant NOx emission reduction at partial loads. In all three......Due to the rapidly growing renewable power, the fossil fuel power plants have to be increasingly operated under large and rapid load change conditions, which can induce various challenges. This work aims to reduce NOx emissions of large-scale corner-fired boilers operated at medium–low loads...

  13. Simultaneous processes of electricity generation and ceftriaxone sodium degradation in an air-cathode single chamber microbial fuel cell

    Science.gov (United States)

    Wen, Qing; Kong, Fanying; Zheng, Hongtao; Yin, Jinling; Cao, Dianxue; Ren, Yueming; Wang, Guiling

    2011-03-01

    A single chamber microbial fuel cell (MFC) with an air-cathode is successfully demonstrated using glucose-ceftriaxone sodium mixtures or ceftriaxone sodium as fuel. Results show that the ceftriaxone sodium can be biodegraded and produce electricity simultaneously. Interestingly, these ceftriaxone sodium-glucose mixtures play an active role in production of electricity. The maximum power density is increased in comparison to 1000 mg L-1 glucose (19 W m-3) by 495% for 50 mg L-1 ceftriaxone sodium + 1000 mg L-1 glucose (113 W m-3), while the maximum power density is 11 W m-3 using 50 mg L-1 ceftriaxone sodium as the sole fuel. Moreover, ceftriaxone sodium biodegradation rate reaches 91% within 24 h using the MFC in comparison with 51% using the traditional anaerobic reactor. These results indicate that some toxic and bio-refractory organics such as antibiotic wastewater might be suitable resources for electricity generation using the MFC technology.

  14. Modeling and Implementation of a 1 kW, Air Cooled HTPEM Fuel Cell in a Hybrid Electrical Vehicle

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Ashworth, Leanne; Remón, Ian Natanael

    2008-01-01

    , was implemented in a small electrical vehicle. A dynamic model was developed using Matlab-Simulink to describe the system characteristics, select operating conditions and to size system components. Preheating of the fuel cell stack with electrical resistors was investigated and found to be an unrealistic approach......This work is a preliminary study of using the PBI-based, HTPEM fuel cell technology in automotive applications. This issue was investigated through computational modeling and an experimental investigation. A hybrid fuel cell system, consisting of a 1 kW stack and lead acid batteries...... for automotive applications. A simple and reliable approach to temperature management in the stack was using the unpressurized, cathode air stream as coolant....

  15. The electrolyte challenge for a direct methanol-air polymer electrolyte fuel cell operating at temperatures up to 200 C

    Science.gov (United States)

    Savinell, Robert; Yeager, Ernest; Tryk, Donald; Landau, Uziel; Wainright, Jesse; Gervasio, Dominic; Cahan, Boris; Litt, Morton; Rogers, Charles; Scherson, Daniel

    1993-01-01

    Novel polymer electrolytes are being evaluated for use in a direct methanol-air fuel cell operating at temperatures in excess of 100 C. The evaluation includes tests of thermal stability, ionic conductivity, and vapor transport characteristics. The preliminary results obtained to date indicate that a high temperature polymer electrolyte fuel cell is feasible. For example, Nafion 117 when equilibrated with phosphoric acid has a conductivity of at least 0.4 Omega(exp -1)cm(exp -1) at temperatures up to 200 C in the presence of 400 torr of water vapor and methanol vapor cross over equivalent to 1 mA/cm(exp 2) under a one atmosphere methanol pressure differential at 135 C. Novel polymers are also showing similar encouraging results. The flexibility to modify and optimize the properties by custom synthesis of these novel polymers presents an exciting opportunity to develop an efficient and compact methanol fuel cell.

  16. Boise, Idaho: Improving Air Quality through Alternative Fuels & Reduced Vehicular Travel (City Energy: From Data to Decisions)

    Energy Technology Data Exchange (ETDEWEB)

    Strategic Priorities and Impact Analysis Team, Office of Strategic Programs

    2017-11-01

    This fact sheet "Boise, Idaho: Improving Air Quality through Alternative Fuels & Reduced Vehicular Travel" explains how the City of Boise used data from the U.S. Department of Energy's Cities Leading through Energy Analysis and Planning (Cities-LEAP) and the State and Local Energy Data (SLED) programs to inform its city energy planning. It is one of ten fact sheets in the "City Energy: From Data to Decisions" series.

  17. Final Environmental Assessment for the Disposal of the Former Lynn Haven Fuel Depot, Tyndall Air Force Base, Florida

    Science.gov (United States)

    2015-12-01

    significant adverse effect on aircraft operations, noise, air quality, safety and occupational health, earth resources (i.e., geology , topography and...Gulf of Mexico Lynn HavenFuel Depot Property Panama City Lynn Haven Rail Spur Tyndall AFB 11TH 231 98 23RD 390 77 TYN DA LL EAS T JEN KS 389 OH IO 231...occupational health, earth resources (i.e., geology , topography and soils), hazardous materials and waste (i.e., hazardous materials, hazardous waste

  18. Indoor air pollution from solid fuels and peripheral blood DNA methylation: findings from a population study in Warsaw, Poland.

    Science.gov (United States)

    Tao, Meng-Hua; Zhou, Jiachen; Rialdi, Alexander P; Martinez, Regina; Dabek, Joanna; Scelo, Ghislaine; Lissowska, Jolanta; Chen, Jia; Boffetta, Paolo

    2014-10-01

    DNA methylation is a potential mechanism linking indoor air pollution to adverse health effects. Fetal and early-life environmental exposures have been associated with altered DNA methylation and play a critical role in progress of diseases in adulthood. We investigated whether exposure to indoor air pollution from solid fuels at different lifetime periods was associated with global DNA methylation and methylation at the IFG2/H19 imprinting control region (ICR) in a population-based sample of non-smoking women from Warsaw, Poland. Global methylation and IFG2/H19 ICR methylation were assessed in peripheral blood DNA from 42 non-smoking women with Luminometric Methylation Assay (LUMA) and quantitative pyrosequencing, respectively. Linear regression models were applied to estimate associations between indoor air pollution and DNA methylation in the blood. Compared to women without exposure, the levels of LUMA methylation for women who had ever exposed to both coal and wood were reduced 6.70% (95% CI: -13.36, -0.04). Using both coal and wood before age 20 was associated with 6.95% decreased LUMA methylation (95% CI: -13.79, -0.11). Further, the negative correlations were more significant with exposure to solid fuels for cooking before age 20. There were no clear associations between indoor solid fuels exposure before age 20 and through the lifetime and IFG2/H19 ICR methylation. Our study of non-smoking women supports the hypothesis that exposure to indoor air pollution from solid fuels, even early-life exposure, has the capacity to modify DNA methylation that can be detected in peripheral blood. Copyright © 2014 Elsevier Inc. All rights reserved.

  19. Robust Control of the Air to Fuel Ratio in Spark Ignition Engines with Delayed Measurements from a UEGO Sensor

    OpenAIRE

    Javier Espinoza-Jurado; Emmanuel Dávila; Jorge Rivera; Juan José Raygoza-Panduro; Susana Ortega

    2015-01-01

    A precise control of the normalized air to fuel ratio in spark ignition engines is an essential task. To achieve this goal, in this work we take into consideration the time delay measurement presented by the universal exhaust gas oxygen sensor along with uncertainties in the volumetric efficiency. For that purpose, observers are designed by means of a super-twisting sliding mode estimation scheme. Also two control schemes based on a general nonlinear model and a similar nonlinear affine repre...

  20. A single laser all fibre based optical sensor and switching system and method for measuring velocity in atmospheric air flow

    DEFF Research Database (Denmark)

    2013-01-01

    A system for measuring a velocity of tracer particle motion in a fluid comprising at least one laser emitter configured to emit a continuous wave laser beam and a plur ality of optical devices being configured to alternately receive a laser beam, focusing the laser beam onto a same probe volume c...

  1. [Current status of air pollution in Sao Paulo, Brazil: effects and problems associated with the introduction of ethanol-fueled motor vehicles].

    Science.gov (United States)

    Kabuto, M; Tsugane, S; Hamada, G S

    1990-05-01

    Recently suggestions have been advanced that alternative fuels including ethanol, methanol or methane instead of so called "fossil fuels" may help improve the current conditions of air pollution. According to results of general survey in Sao Paulo, since their introduction in 1978, ethanol-fueled cars have increased their share to almost 50% of all light vehicles in 1983. The current status of air pollution in Sao Paulo metropolitan area (SPMA) is described in relation to the use of such alternative fuel. The average concentrations in air of SO2 and lead have been decreasing drastically during the period of 1982-88, whereas non-methane hydrocarbon, NO2 and O3 levels have been increasing to attain the worst levels in the world as indicated in Fig. 2. The use of ethanol-fuel, which contains less sulphate and lead, is thought to have contributed more or less to the above reductions of SO2 and lead in the air. However, the pollutants that have increased may derive mainly from diesel and gasoline exhausts of heavy vehicles. The general state of air pollutions appears not to have been improved, suggesting the difficulty in resolving air pollution issues. On the other hand, a current problem specific to ethanol-fuel is the aldehydes or other carcinogenic components in exhaust. Peak formaldehyde concentration, for example, have been reported to have reached 159 ppb in SPMA, which may be one of the highest levels shown in ambient air.(ABSTRACT TRUNCATED AT 250 WORDS)

  2. Prediction of air-fuel and oxy-fuel combustion through a generic gas radiation property model

    DEFF Research Database (Denmark)

    Yin, Chungen

    2017-01-01

    of participating species other than H2O and CO2. As a result, WSGGMs with different coefficients have been published for specific applications. In this paper, a reliable generic model for gaseous radiation property calculation, which is a computationally efficient exponential wide band model (E-EWBM) applicable......-EWBM that appropriately takes the impacts of H2O, CO2, CO and CH4 into account is a good replacement of the oxy-fuel WSGGMs for oxy-fuel combustion CFD....... for evaluating gaseous radiative properties. However, the WSGGMs still have some limitations in practical use, e.g., unable to naturally accommodate different combustion environments, difficult to accurately address the variations in species concentrations in a flame, and inconvenient to account for the impacts...

  3. Fe-Al Weld Overlay and High Velocity Oxy-Fuel Thermal Spray Coatings for Corrosion Protection of Waterwalls in Fossil Fired Plants with Low NOx Burners

    Energy Technology Data Exchange (ETDEWEB)

    Regina, J.R.

    2002-02-08

    Iron-aluminum-chromium coatings were investigated to determine the best candidates for coatings of boiler tubes in Low NOx fossil fueled power plants. Ten iron-aluminum-chromium weld claddings with aluminum concentrations up to 10wt% were tested in a variety of environments to evaluate their high temperature corrosion resistance. The weld overlay claddings also contained titanium additions to investigate any beneficial effects from these ternary and quaternary alloying additions. Several High-Velocity Oxy-Fuel (HVOF) thermal spray coatings with higher aluminum concentrations were investigated as well. Gaseous corrosion testing revealed that at least 10wt%Al is required for protection in the range of environments examined. Chromium additions were beneficial in all of the environments, but additions of titanium were beneficial only in sulfur rich atmospheres. Similar results were observed when weld claddings were in contact with corrosive slag while simultaneously, exposed to the corrosive environments. An aluminum concentration of 10wt% was required to prevent large amounts of corrosion to take place. Again chromium additions were beneficial with the greatest corrosion protection occurring for welds containing both 10wt%Al and 5wt%Cr. The exposed thermal spray coatings showed either significant cracking within the coating, considerable thickness loss, or corrosion products at the coating substrate interface. Therefore, the thermal spray coatings provided the substrate very little protection. Overall, it was concluded that of the coatings studied weld overlay coatings provide superior protection in these Low NOx environments; specifically, the ternary weld composition of 10wt%Al and 5wt%Cr provided the best corrosion protection in all of the environments tested.

  4. Carbon-Based Air-Breathing Cathodes for Microbial Fuel Cells

    Directory of Open Access Journals (Sweden)

    Irene Merino-Jimenez

    2016-08-01

    Full Text Available A comparison between different carbon-based gas-diffusion air-breathing cathodes for microbial fuel cells (MFCs is presented in this work. A micro-porous layer (MPL based on carbon black (CB and an activated carbon (AC layer were used as catalysts and applied on different supporting materials, including carbon cloth (CC, carbon felt (CF, and stainless steel (SS forming cathode electrodes for MFCs treating urine. Rotating ring disk electrode (RRDE analyses were done on CB and AC to: (i understand the kinetics of the carbonaceous catalysts; (ii evaluate the hydrogen peroxide production; and (iii estimate the electron transfer. CB and AC were then used to fabricate electrodes. Half-cell electrochemical analysis, as well as MFCs continuous power performance, have been monitored. Generally, the current generated was higher from the MFCs with AC electrodes compared to the MPL electrodes, showing an increase between 34% and 61% in power with the AC layer comparing to the MPL. When the MPL was used, the supporting material showed a slight effect in the power performance, being that the CF is more powerful than the CC and the SS. These differences also agree with the electrochemical analysis performed. However, the different supporting materials showed a bigger effect in the power density when the AC layer was used, being the SS the most efficient, with a power generation of 65.6 mW·m−2, followed by the CC (54 mW·m−2 and the CF (44 mW·m−2.

  5. A study on a swirl type multi-hole fuel injector for a PFI system to improve air-fuel mixture formation

    Science.gov (United States)

    Alimin, A. J.; Kuang He, Y.; Sapit, A.; Selamat, H.

    2017-09-01

    This paper described the development and simulation works thatwere conducted on an injector that has a combined swirl spray and multi-hole injection functions. It was expected that those two functions would provide beneficial effects to the fuel injector, in order to provide better fuel and air mixing, especially for Port Fuel Injection (PFI) application. The combination of both functions was aimed for achieving high quality spray formation, which might be useful in cases when the combustion time is limited. Swirl spray pattern is known for fine droplets production with relatively smaller SMD and bigger coverage area in the combustion chamber. On the other hand, a multi-hole injector has the advantages of simplicity in manufacturing and operation. Preliminary results on the simulation works that were done separately, demonstrated the ability of the injector’s design to produce swirl spray as well as injecting near-symmetrical sprays from the four holes at the injector’s end. Nevertheless, these findings must be improved further in the future, especially on simulating the benefits of having a combined swirl and multi-hole functions inside a single injector. Furthermore, detailed assessment on manufacturability and cost effectiveness of this injector must also be addressed.

  6. Building America Case Study: Standard- Versus High-Velocity Air Distribution in High-Performance Townhomes, Denver, Colorado

    Energy Technology Data Exchange (ETDEWEB)

    A. Poerschke, R. Beach, T. Begg

    2017-06-01

    IBACOS investigated the performance of a small-diameter high-velocity heat pump system compared to a conventional system in a new construction triplex townhouse. A ductless heat pump system also was installed for comparison, but the homebuyer backed out because of aesthetic concerns about that system. In total, two buildings, having identical solar orientation and comprised of six townhomes, were monitored for comfort and energy performance.

  7. System modeling of an air-independent solid oxide fuel cell system for unmanned undersea vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Burke, A. Alan; Carreiro, Louis G. [Naval Undersea Warfare Center, Division Newport, 1176 Howell Street, Bldg. 1302/2, Newport, RI 02841 (United States)

    2006-07-14

    To examine the feasibility of a solid oxide fuel cell (SOFC)-powered unmanned undersea vehicle (UUV), a system level analysis is presented that projects a possible integration of the SOFC stack, fuel steam reformer, fuel/oxidant storage and balance of plant components into a 21-in. diameter UUV platform. Heavy hydrocarbon fuel (dodecane) and liquid oxygen (LOX) are chosen as the preferred reactants. A maximum efficiency of 45% based on the lower heating value of dodecane was calculated for a system that provides 2.5kW for 40h. Heat sources and sinks have been coupled to show viable means of thermal management. The critical design issues involve proper recycling of exhaust steam from the fuel cell back into the reformer and effective use of the SOFC stack radiant heat for steam reformation of the hydrocarbon fuel. (author)

  8. Delayed Fission Product Gamma-Ray Transmission Through Low Enriched UO2 Fuel Pin Lattices in Air

    Energy Technology Data Exchange (ETDEWEB)

    Trumbull, TH [Rensselaer Polytechnic Inst., Troy, NY (United States)

    2004-10-18

    The transmission of delayed fission-product gamma rays through various arrangements of low-enriched UO2 fuel pin lattices in an air medium was studied. Experimental measurements, point-kernel and Monte Carlo photon transport calculations were performed to demonstrate the shielding effect of ordered lattices of fuel pins on the resulting gamma-ray dose to a detector outside the lattice. The variation of the gamma-ray dose on the outside of the lattice as a function of radial position, the so-called “channeling” effect, was analyzed. Techniques for performing experimental measurements and data reduction at Rensselaer Polytechnic Institute’s Reactor Critical Facility (RCF) were derived. An experimental apparatus was constructed to hold the arrangements of fuel pins for the measurements. A gamma-ray spectroscopy system consisting of a sodium-iodide scintillation detector was used to collect data. Measurements were made with and without a collimator installed. A point-kernel transport code was developed to map the radial dependence of the gamma-ray flux. Input files for the Monte Carlo code, MCNP, were also developed to accurately model the experimental measurements. The results of the calculations were compared to the experimental measurements. In order to determine the delayed fission-product gamma-ray source for the calculations, a technique was developed using a previously written code, DELBG and the reactor state-point data obtained during the experimental measurements. Calculations were performed demonstrating the effects of material homogenization on the gamma-ray transmission through the fuel pin lattice.Homogeneous and heterogeneous calculations were performed for all RCF fuel pin lattices as well as for a typical commercial pressurized water reactor fuel bundle. The results of the study demonstrated the effectiveness of the experimental measurements to isolate the channeling effect of delayed fission-product gamma-rays through lattices of RCF fuel pins

  9. Comparison of in vitro behavior of as-sprayed, alkaline-treated and collagen-treated bioceramic coatings obtained by high velocity oxy-fuel spray

    Energy Technology Data Exchange (ETDEWEB)

    Melero, H., E-mail: hortensia.melero.correas@gmail.com [Thermal Spray Centre, Universitat de Barcelona, Martí i Franqués, 1, 08028 Barcelona (Spain); Garcia-Giralt, N. [URFOA, IMIM (Institut Hospital del Mar d’Investigacions Mèdiques), RETICEF, Doctor Aiguader, 80, 08003 Barcelona (Spain); Fernández, J. [Thermal Spray Centre, Universitat de Barcelona, Martí i Franqués, 1, 08028 Barcelona (Spain); Díez-Pérez, A. [URFOA, IMIM (Institut Hospital del Mar d’Investigacions Mèdiques), RETICEF, Doctor Aiguader, 80, 08003 Barcelona (Spain); Servei de Medicina Interna, Hospital del Mar, Barcelona (Spain); Guilemany, J.M. [Thermal Spray Centre, Universitat de Barcelona, Martí i Franqués, 1, 08028 Barcelona (Spain)

    2014-07-01

    Hydroxyapatite (HAp)–TiO{sub 2} samples obtained using high velocity oxy-fuel spray (HVOF), that had previously shown excellent mechanical behaviour, were innovatively surface treated in order to improve their biological performance. The chosen treatments were an alkaline treatment to increase –OH radicals density on the surface (especially on TiO{sub 2} zones), and a collagen treatment to bond collagen fibrils to the –OH radicals present in hydroxyapatite. These coatings were analysed using scanning electron microscopy, energy-dispersive X-ray spectroscopy and infrared spectroscopy, and tested for human osteoblast biocompatibility and functionality. In the case of the alkaline treatment, although the –OH radicals density did not increase compared to the as-sprayed coatings, a nanostructured layer of sodium hydroxycarbonate precipitated on the surface, thus improving biological behaviour due to the nanoroughness effect. For the collagen-treated samples, collagen fibrils appeared well-adhered to the surface, and in vitro cell culture tests showed that these surfaces were much more conducive to cell adhesion and differentiation than the as-sprayed and alkaline-treated samples. These results pointed to collagen treatment as a very promising method to improve bioactivity of HAp–TiO{sub 2} thermal-sprayed coatings.

  10. Improvement in wear and corrosion resistance of AISI 1020 steel by high velocity oxy-fuel spray coating containing Ni-Cr-B-Si-Fe-C

    Science.gov (United States)

    Prince, M.; Thanu, A. Justin; Gopalakrishnan, P.

    2012-04-01

    In this investigation, AISI 1020 low carbon steel has been selected as the base material. The Ni based super alloy powder NiCrBSiFeC was sprayed on the base material using high velocity oxy-fuel spraying (HVOF) technique. The thickness of the coating was approximately 0.5 mm (500 μm). The coating was characterized using optical microscopy, Vickers microhardness testing, X-ray diffraction technique and scanning electron microscopy. Dry sliding wear tests were carried out at 3 m/s sliding speed under the load of 10 N for 1000 m sliding distance at various temperatures i.e., 35° C, 250° C and 350° C. The corrosion test was carried out in 1 M copper chloride in acetic acid solution. The polarization studies were also conducted for both base material and coating. The improvement in microhardness from 1.72 GPa (175 HV0.05) to 10.54 GPa (1075 HV0.05) was observed. The coatings exhibited 3-6 times improved wear resistance as compared with base material. Also, the corrosion rate was reduced by 3.5 times due to the presence of coatings.

  11. Nitric oxide density measurements in air and air/fuel nanosecond pulse discharges by laser induced fluorescence

    Science.gov (United States)

    Uddi, M.; Jiang, N.; Adamovich, I. V.; Lempert, W. R.

    2009-04-01

    Laser induced fluorescence is used to measure absolute nitric oxide concentrations in air, methane-air and ethylene-air non-equilibrium plasmas, as a function of time after initiation of a single pulse, 20 kV peak voltage, 25 ns pulse duration discharge. A mixture of NO and nitrogen with known composition (4.18 ppm NO) is used for calibration. Peak NO density in air at 60 Torr, after a single pulse, is ~8 × 1012 cm-3 (~4.14 ppm) occurring at ~250 µs after the pulse, with decay time of ~16.5 ms. Peak NO atom mole fraction in a methane-air mixture with equivalence ratio of phiv = 0.5 is found to be approximately equal to that in air, with approximately the same rise and decay rate. In an ethylene-air mixture (also with equivalence ratio of phiv = 0.5), the rise and decay times are comparable to air and methane-air, but the peak NO concentration is reduced by a factor of approximately 2.5. Spontaneous emission measurements show that excited electronic states N2(C 3Π) and NO(A 2Σ) in air at P = 60 Torr decay within ~20 ns and ~1 µs, respectively. Kinetic modelling calculations incorporating air plasma kinetics complemented with the GRI Mech 3.0 hydrocarbon oxidation mechanism are compared with the experimental data using three different NO production mechanisms. It is found that NO concentration rise after the discharge pulse is much faster than predicted by Zel'dovich mechanism reactions, by two orders of magnitude, but much slower compared with reactions of electronically excited nitrogen atoms and molecules, also by two orders of magnitude. It is concluded that processes involving long lifetime (~100 µs) metastable states, such as N2(X 1Σ,v) and O2(b 1Σ), formed by quenching of the metastable N2(A 3Σ) state by ground electronic state O2, may play a dominant role in NO formation. NO decay, in all cases, is found to be dominated by the reverse Zel'dovich reaction, NO + O → N + O2, as well as by conversion into NO2 in a reaction of NO with ozone.

  12. Experimental evaluation of the sensitivity to fuel utilization and air management on a 100 kW SOFC system

    Science.gov (United States)

    Santarelli, M.; Leone, P.; Calì, M.; Orsello, G.

    The tubular SOFC generator CHP-100, built by Siemens Power Generation (SPG) Stationary Fuel Cells (SFC), is running at the Gas Turbine Technologies (GTT) in Torino (Italy), in the framework of the EOS Project. The nominal load of the generator ensures a produced electric power of around 105 kW e ac and around 60 kW t of thermal power at 250 °C to be used for the custom tailored HVAC system. Several experimental sessions have been scheduled on the generator; the aim is to characterize the operation through the analysis of some global performance index and the detailed control of the operation of the different bundles of the whole stack. All the scheduled tests have been performed by applying the methodology of design of experiment; the main obtained results show the effect of the change of the analysed operating factors in terms of distribution of voltage and temperature over the stack. Fuel consumption tests give information about the sensitivity of the voltage and temperature distribution along the single bundles. On the other hand, since the generator is an air cooled system, the results of the tests on the air stoichs have been used to analyze the generator thermal management (temperature distribution and profiles) and its effect on the polarization. The sensitivity analysis of the local voltage to the overall fuel consumption modifications can be used as a powerful procedure to deduce the local distribution of fuel utilization (FU) along the single bundles: in fact, through a model obtained by deriving the polarization curve respect to FU, it is possible to link the distribution of voltage sensitivities to FC to the distribution of the local FU. The FU distribution will be shown as non-uniform, and this affects the local voltage and temperatures, causing a high warming effect in some rows of the generator. Therefore, a discussion around the effectiveness of the thermal regulation made by the air stoichs, in order to reduce the non-uniform distribution of

  13. Robust Control of the Air to Fuel Ratio in Spark Ignition Engines with Delayed Measurements from a UEGO Sensor

    Directory of Open Access Journals (Sweden)

    Javier Espinoza-Jurado

    2015-01-01

    Full Text Available A precise control of the normalized air to fuel ratio in spark ignition engines is an essential task. To achieve this goal, in this work we take into consideration the time delay measurement presented by the universal exhaust gas oxygen sensor along with uncertainties in the volumetric efficiency. For that purpose, observers are designed by means of a super-twisting sliding mode estimation scheme. Also two control schemes based on a general nonlinear model and a similar nonlinear affine representation for the dynamics of the normalized air to fuel ratio were designed in this work by using the super-twisting sliding mode methodology. Such dynamics depends on the control input, that is, the injected fuel mass flow, its time derivative, and its reciprocal. The two latter terms are estimated by means of a robust sliding mode differentiator. The observers and controllers are designed based on an isothermal mean value engine model. Numeric and hardware in the loop simulations were carried out with such model, where parameters were taken from a real engine. The obtained results show a good output tracking and rejection of disturbances when the engine is closed loop with proposed control methods.

  14. Household Cooking Fuel Use among Residents of a Sub-Urban Community in Nigeria: Implications for Indoor Air Pollution.

    Science.gov (United States)

    Isara, Alphonsus Rukevwe; Aigbokhaode, Adesuwa Queen

    2014-10-01

    The aim of this study is to assess the types of household cooking fuel used by residents of Isiohor community in Edo State, Nigeria. This descriptive cross-sectional study was conducted among 133 household heads or their representatives in Isiohor Community in Edo State, Nigeria. Data collection was by means of a structured interviewer administered questionnaire. Half (50.3%) of the households studied were made up of 4-6 persons living in them. Sixty-two (46.6%) respondents had tertiary level of education and a third 44 (33.1%) earned between 21,000 and 30,000 naira (150-200 dollars) monthly. Forty six (34.6%) and 27 (20.3%) respondents live in passage houses and flats respectively. Two thirds (68.4%) of the respondents cook their food indoors. The predominant household cooking fuels used by the respondents were cooking gas (51.1%), Kerosene (45.9%), vegetables (25.6%) and firewood (14.3%). Majority 106 (79.7%) had poor knowledge of the health effects of prolonged exposure to smoke arising from indoor cooking. There was a statistically significant association between the occupation of the respondents and the type of household cooking fuel used (p=0.002). The use of unclean indoor cooking fuel was high among the residents of Isiohor community in Edo State, Nigeria. Also, there was poor knowledge of the health effects of prolonged exposure to smoke from unclean cooking fuel among the respondents and this has serious implications for indoor air pollution. There is an urgent need for health/hygiene education on the health effects of use of unclean indoor cooking fuel among these residents. There is also need for use of clean/green cooking stoves and construction of exhaust ventilation pipes in these households.

  15. Continuous control of fuel feed and grade velocity in a small-scale grade combustor; Kontinuerlig styrning av matning och rosthastighet foer en smaaskalig foerbraenningsrost

    Energy Technology Data Exchange (ETDEWEB)

    Padban, Nader; Ramstroem, Erik; Larfeldt, Jenny; Berge, Niklas [TPS Termiska Processer AB, Nykoeping (Sweden)

    2004-01-01

    At present, on/off-controlling is the widely used method in control of the power output from grate boilers with capacities lower than 1 MW. Availability of cheap actuators and control units nowadays, has however created the opportunity to apply more advanced control strategies, which can combine economic advantages with low emissions. Within this work four different strategies were used to adapt the load of a 220 kW grate boiler to the heat demand, in the range 18 to 100% of the boilers full capacity. The following control strategies were investigated: 1) discontinuous load control; 2) discontinuous load control combined with pulsing feed; 3) continuous load control; 4) continuous load control combined with pulsing feed. The results from the experiments show that continuous load control enhances the efficiency of the process by decreasing the oxygen content in the flue gas. In the case of continuous load control it was possible to keep an oxygen level of between 5 and 7 % in the flue gas, without exciding some specific limits for CO and THC emissions (CO below 200 mg/MJ and THC less than 10 ppm). In the case with discontinuous load control the oxygen level in the flue gas was much higher (3 % in average) and neither optimised air/fuel-ratio, nor active oxygen control could reduce the high levels. Discontinuous load control resulted in periodical fluctuations in CO and THC emissions. The pulsation of the feeding screw is one of the most important reasons for CO and THC peaks. The total cost for modification of a process from discontinuous to continuous load control is evaluated to be between 10,000 to 40,000 SEK ({approx} 1,300-6,000 USD), depending on the 'start condition'. The programming cost is not included in this cost statement. The pay-off time is a function of the capacity of the boiler, the cost for the fuel and the degree of improvement in efficiency. As an example for a boiler with 500 kW capacity, 6,000 hours/year operation time 250 SEK

  16. Combustion characteristics and air pollutant formation during oxy-fuel co-combustion of microalgae and lignite.

    Science.gov (United States)

    Gao, Yuan; Tahmasebi, Arash; Dou, Jinxiao; Yu, Jianglong

    2016-05-01

    Oxy-fuel combustion of solid fuels is seen as one of the key technologies for carbon capture to reduce greenhouse gas emissions. The combustion characteristics of lignite coal, Chlorella vulgaris microalgae, and their blends under O2/N2 and O2/CO2 conditions were studied using a Thermogravimetric Analyzer-Mass Spectroscopy (TG-MS). During co-combustion of blends, three distinct peaks were observed and were attributed to C. vulgaris volatiles combustion, combustion of lignite, and combustion of microalgae char. Activation energy during combustion was calculated using iso-conventional method. Increasing the microalgae content in the blend resulted in an increase in activation energy for the blends combustion. The emissions of S- and N-species during blend fuel combustion were also investigated. The addition of microalgae to lignite during air combustion resulted in lower CO2, CO, and NO2 yields but enhanced NO, COS, and SO2 formation. During oxy-fuel co-combustion, the addition of microalgae to lignite enhanced the formation of gaseous species. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. Impact of Biodiesel Fuels on Air Quality and Human Health: Task 1 Report; Incorporate Biodiesel Data into Vehicle Emissions Databases for Modeling

    Energy Technology Data Exchange (ETDEWEB)

    Lindhjem, C.; Pollack, A.

    2003-05-01

    This document is the Task 1 report for the NREL"Impact of Biodiesel Fuels on Air Quality and Human Health" study. This report provides a discussion and analysis of the available biodiesel test data, and makes recommendations for how biodiesel effects on pollutant mass emissions as well as chemical composition should be incorporated into emission inventories for use in air quality modeling.

  18. Biofuels that cause land-use change may have much larger non-GHG air quality emissions than fossil fuels.

    Science.gov (United States)

    Tsao, C-C; Campbell, J E; Mena-Carrasco, M; Spak, S N; Carmichael, G R; Chen, Y

    2012-10-02

    Although biofuels present an opportunity for renewable energy production, significant land-use change resulting from biofuels may contribute to negative environmental, economic, and social impacts. Here we examined non-GHG air pollution impacts from both indirect and direct land-use change caused by the anticipated expansion of Brazilian biofuels production. We synthesized information on fuel loading, combustion completeness, and emission factors, and developed a spatially explicit approach with uncertainty and sensitivity analyses to estimate air pollution emissions. The land-use change emissions, ranging from 6.7 to 26.4 Tg PM(2.5), were dominated by deforestation burning practices associated with indirect land-use change. We also found Brazilian sugar cane ethanol and soybean biodiesel including direct and indirect land-use change effects have much larger life-cycle emissions than conventional fossil fuels for six regulated air pollutants. The emissions magnitude and uncertainty decrease with longer life-cycle integration periods. Results are conditional to the single LUC scenario employed here. After LUC uncertainty, the largest source of uncertainty in LUC emissions stems from the combustion completeness during deforestation. While current biofuels cropland burning policies in Brazil seek to reduce life-cycle emissions, these policies do not address the large emissions caused by indirect land-use change.

  19. The Role of Distribution Infrastructure and Equipment in the Life-cycle Air Emissions of Liquid Transportation Fuels

    Science.gov (United States)

    Strogen, Bret Michael

    component. In order to apply the new emission factors to policy-relevant scenarios, a projection is made for the fleet inventory of infrastructure components necessary to distribute 21 billion gallons of ethanol (the 2022 federal mandate for advanced biofuels under the Energy Independence and Security Act of 2007) derived entirely from Miscanthus grass, for comparison to the baseline petroleum system. Due to geographic, physical and chemical properties of biomass and alcohols, the distribution system for Miscanthus-based ethanol is more capital- and energy-intensive than petroleum per unit of fuel energy delivered. The transportation of biofuels away from producer regions poses environmental, health, and economic trade-offs that are herein evaluated using a simplified national distribution network model. In just the last ten years, ethanol transportation within the contiguous United States is estimated to have increased more than ten-fold in total t-km as ethanol has increasingly been transported away from Midwest producers due to air quality regulations pertaining to gasoline, renewable fuel mandates, and the 10% blending limit (i.e., the E10 blend wall). From 2004 to 2009, approximately 10 billion t-km of ethanol transportation are estimated to have taken place annually for reasons other than the E10 blend wall, leading to annual freight costs greater than $240 million and more than 300,000 tonnes of CO2-e emissions and significant emissions of criteria air pollutants from the combustion of more than 90 million liters of diesel. Although emissions from distribution activities are small when normalized to each unit of fuel, they are large in scale. Archetypal fuel distribution routes by rail and by truck are created to evaluate the significance of mode choice and route location on the severity of public health impacts from locomotive and truck emissions, by calculating the average PM2.5 pollution intake fraction along each route. Exposure to pollution resulting from

  20. A Systematic Review of Innate Immunomodulatory Effects of Household Air Pollution Secondary to the Burning of Biomass Fuels.

    Science.gov (United States)

    Lee, Alison; Kinney, Patrick; Chillrud, Steve; Jack, Darby

    2015-01-01

    Household air pollution (HAP)-associated acute lower respiratory infections cause 455,000 deaths and a loss of 39.1 million disability-adjusted life years annually. The immunomodulatory mechanisms of HAP are poorly understood. The aim of this study was to conduct a systematic review of all studies examining the mechanisms underlying the relationship between HAP secondary to solid fuel exposure and acute lower respiratory tract infection to evaluate current available evidence, identify gaps in knowledge, and propose future research priorities. We conducted and report on studies in accordance with the PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) guidelines. In all, 133 articles were fully reviewed and main characteristics were detailed, namely study design and outcome, including in vivo versus in vitro and pollutants analyzed. Thirty-six studies were included in a nonexhaustive review of the innate immune system effects of ambient air pollution, traffic-related air pollution, or wood smoke exposure of developed country origin. Seventeen studies investigated the effects of HAP-associated solid fuel (biomass or coal smoke) exposure on airway inflammation and innate immune system function. Particulate matter may modulate the innate immune system and increase susceptibility to infection through a) alveolar macrophage-driven inflammation, recruitment of neutrophils, and disruption of barrier defenses; b) alterations in alveolar macrophage phagocytosis and intracellular killing; and c) increased susceptibility to infection via upregulation of receptors involved in pathogen invasion. HAP secondary to the burning of biomass fuels alters innate immunity, predisposing children to acute lower respiratory tract infections. Data from biomass exposure in developing countries are scarce. Further study is needed to define the inflammatory response, alterations in phagocytic function, and upregulation of receptors important in bacterial and viral

  1. The Hardware Implementation of Demonstrator Air Independent Electric Supply System Based on Pem Fuel Cell

    Directory of Open Access Journals (Sweden)

    Grzeczka G.

    2016-12-01

    Full Text Available The paper presents results of the research project whose the main goal was to build a technology demonstrator of an electric supply system based on the PEM fuel cell. The electric supply system is dedicated to operation on a board of a submarine during emergency situations. The underwater conditions influence on a specific architecture of supply subsystems of the PEM fuel cell system. In this case the fuel cell stack is supplied by both clean hydrogen and clean oxygen stored in pressurized tanks. The hydrogen has to be delivered in a closed loop, while the oxygen can be delivered in a closed or an open loop. In the technology demonstrator, the supply of the fuel cell stack by the hydrogen in the closed loop and the oxygen in the open loop with a precise control of its flow were used.

  2. Self-assembled nitrogen-doped fullerenes and their catalysis for fuel cell and rechargeable metal-air battery applications.

    Science.gov (United States)

    Noh, Seung Hyo; Kwon, Choah; Hwang, Jeemin; Ohsaka, Takeo; Kim, Beom-Jun; Kim, Tae-Young; Yoon, Young-Gi; Chen, Zhongwei; Seo, Min Ho; Han, Byungchan

    2017-06-08

    In this study, we report self-assembled nitrogen-doped fullerenes (N-fullerene) as non-precious catalysts, which are active for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), and thus applicable for energy conversion and storage devices such as fuel cells and metal-air battery systems. We screen the best N-fullerene catalyst at the nitrogen doping level of 10 at%, not at the previously known doping level of 5 or 20 at% for graphene. We identify that the compressive surface strain induced by doped nitrogen plays a key role in the fine-tuning of catalytic activity.

  3. Data Acquisition User’s Guide-1 for Fuel/Engine Evaluation System Applied to an Experimental Air Stirling Engine

    Science.gov (United States)

    1981-07-01

    expfrimenta! d’avion no 1 de marque Stirling ; ce dernier avait d6ja ftg conqu et construit dans le cadre des Atudes sur lea " moteurs avanc6s" men-es pour...crivons le logiciel que l’on utilise pour faire l’essai du moteur de marque Stirling . Finalement, nous d~crivons certaines limites du systime d’ AD. i...ACQUISITION USER’S GUIDE-1 FOR FUEL/ENGINE EVALUATION SYSTEM APPLIED TO AN EXPERIMENTAL AIR STIRLING ENGINE by IR. Bingham and G.D. Webster Energy

  4. Tankering Fuel on U.S. Air Force Transport Aircraft: An Assessment of Cost Savings

    Science.gov (United States)

    2015-01-01

    therefore increase the traffic of fuel trucks at the apron ( leading to possible safety concerns) with truck drivers going from one aircraft to...Boone continued Col Fowler’s lead , and his help as we concluded our effort was very much appreciated. Also from the FEO, Col Michael Horsey, Maj Darren...relative fuel price differences that exist between the various refueling locations. This situation would lead AMC to conclude that tankering is

  5. Air-Independent Solid Oxide Fuel Cells for NASA's LOX-CH4 Landers

    Science.gov (United States)

    Ryan, Abigail C.; Araghi, Koorosh R.; Farmer, Serene C.

    2013-01-01

    Gemini, Apollo, and Space Shuttle used fuel cells as main power source for vehicle and water source for life support and thermal PEM (Gemini) and Alkaline (Apollo, Shuttle) fuel cells were used Ideal for short (less than 3 weeks) missions when the required O2 and H2 can be launched with the vehicle. New missions that might require long-duration stays in orbit or at a habitat, cannot rely on the availability of pure reactants but should also aim to be sun-independent - a problem for which Solid Oxide Fuel Cells might be the answer. Recently, NASA has investigated & developed LOX/CH4-propelled landers (Altair, MORPHEUS). In order to preserve mission flexibility, fuel cells are being studied as a potential power source. Much of NASA's fuel cell development has been focused on creating a dead-headed, non-flow through PEM fuel cells which would weigh less and be more reliable than the existing Alkaline and PEM technology; however, LOX/CH4 as a propellant introduces SOFCs as a power option due to their ability to accept those reactants without much reforming.

  6. Effects of proton exchange membrane on the performance and microbial community composition of air-cathode microbial fuel cells.

    Science.gov (United States)

    Lee, Yun-Yeong; Kim, Tae Gwan; Cho, Kyung-Suk

    2015-10-10

    This study investigated the effects of proton exchange membranes (PEMs) on performance and microbial community of air-cathode microbial fuel cells (MFCs). Air-cathode MFCs with reactor volume of 1L were constructed in duplicate with or without PEM (designated as ACM-MFC and AC-MFC, respectively) and fed with a mixture of glucose and acetate (1:1, w:w). The maximum power density and coulombic efficiency did not differ between MFCs in the absence or presence of a PEM. However, PEM use adversely affected maximum voltage production and the rate of organic compound removal (p0.9 and pelectricity generation in MFC systems. Taken together, these findings demonstrate that MFC systems without PEM are more efficient with respect to power production and COD removal as well as exoelectrogen growth. Copyright © 2015 Elsevier B.V. All rights reserved.

  7. Breakdown voltage at the electric terminals of GCFR-core flow test loop fuel rod simulators in helium and air

    Energy Technology Data Exchange (ETDEWEB)

    Huntley, W.R.; Conley, T.B.

    1979-12-01

    Tests were performed to determine the ac and dc breakdown voltage at the terminal ends of a fuel rod simulator (FRS) in helium and air atmospheres. The tests were performed at low pressures (1 to 2 atm) and at temperatures from 20 to 350/sup 0/C (68 to 660/sup 0/F). The area of concern was the 0.64-mm (0.025-in.) gap between the coaxial conductor of the FRS and the sheaths of the four internal thermocouples as they exit the FRS. The tests were prformed to ensure a sufficient safety margin during Core Flow Test Loop (CFTL) operations that require potentials up to 350 V ac at the FRS terminals. The primary conclusion from the test results is that the CFTL cannot be operated safely if the terminal ends of the FRSs are surrounded by a helium atmosphere but can be operated safely in air.

  8. Estimation of bubble-mediated air-sea gas exchange from concurrent DMS and CO2 transfer velocities at intermediate-high wind speeds

    Science.gov (United States)

    Bell, Thomas G.; Landwehr, Sebastian; Miller, Scott D.; de Bruyn, Warren J.; Callaghan, Adrian H.; Scanlon, Brian; Ward, Brian; Yang, Mingxi; Saltzman, Eric S.

    2017-07-01

    Simultaneous air-sea fluxes and concentration differences of dimethylsulfide (DMS) and carbon dioxide (CO2) were measured during a summertime North Atlantic cruise in 2011. This data set reveals significant differences between the gas transfer velocities of these two gases (Δkw) over a range of wind speeds up to 21 m s-1. These differences occur at and above the approximate wind speed threshold when waves begin breaking. Whitecap fraction (a proxy for bubbles) was also measured and has a positive relationship with Δkw, consistent with enhanced bubble-mediated transfer of the less soluble CO2 relative to that of the more soluble DMS. However, the correlation of Δkw with whitecap fraction is no stronger than with wind speed. Models used to estimate bubble-mediated transfer from in situ whitecap fraction underpredict the observations, particularly at intermediate wind speeds. Examining the differences between gas transfer velocities of gases with different solubilities is a useful way to detect the impact of bubble-mediated exchange. More simultaneous gas transfer measurements of different solubility gases across a wide range of oceanic conditions are needed to understand the factors controlling the magnitude and scaling of bubble-mediated gas exchange.

  9. Cycle-by-cycle Variations in a Direct Injection Hydrogen Enriched Compressed Natural Gas Engine Employing EGR at Relative Air-Fuel Ratios.

    Directory of Open Access Journals (Sweden)

    Olalekan Wasiu Saheed

    2014-07-01

    Full Text Available Since the pressure development in a combustion chamber is uniquely related to the combustion process, substantial variations in the combustion process on a cycle-by-cycle basis are occurring. To this end, an experimental study of cycle-by-cycle variation in a direct injection spark ignition engine fueled with natural gas-hydrogen blends combined with exhaust gas recirculation at relative air-fuel ratios was conducted. The impacts of relative air-fuel ratios (i.e. λ = 1.0, 1.2, 1.3 and 1.4 which represent stoichiometric, moderately lean, lean and very lean mixtures respectively, hydrogen fractions and EGR rates were studied. The results showed that increasing the relative air-fuel ratio increases the COVIMEP. The behavior is more pronounced at the larger relative air-fuel ratios. More so, for a specified EGR rate; increasing the hydrogen fractions decreases the maximum COVIMEP value just as increasing in EGR rates increases the maximum COVIMEP value. (i.e. When percentage EGR rates is increased from 0% to 17% and 20% respectively. The maximum COVIMEP value increases from 6.25% to 6.56% and 8.30% respectively. Since the introduction of hydrogen gas reduces the cycle-by-cycle combustion variation in engine cylinder; thus it can be concluded that addition of hydrogen into direct injection compressed natural gas engine employing EGR at various relative air-fuel ratios is a viable approach to obtain an improved combustion quality which correspond to lower coefficient of variation in imep, (COVIMEP in a direct injection compressed natural gas engine employing EGR at relative air-fuel ratios.

  10. Fuel consumption and CO2/pollutant emissions of mobile air conditioning at fleet level - new data and model comparison.

    Science.gov (United States)

    Weilenmann, Martin F; Alvarez, Robert; Keller, Mario

    2010-07-01

    Mobile air conditioning (MAC) systems are the second-largest energy consumers in cars after driving itself. While different measurement series are available to illustrate their behavior in hot ambient conditions, little data are available for lower temperatures. There are also no data available on diesel vehicles, despite these being quite common in Europe (up to 70% of the fleet in some countries). In the present study, six representative modern diesel passenger cars were tested. In combination with data from previous measurements on gasoline cars, a new model was developed - EEMAC = Empa Emission model for Mobile Air Conditioning systems - to predict emissions from air conditioning. The measurements obtained show that A/C activity still occurs at temperatures below the desired interior temperature. The EEMAC model was applied to the average meteorological year of a central European region and compared with the US EPA MOBILE6 model. As temperatures in central Europe are often below 20 degrees C (the point below which the two models differ), the overall results differ clearly. The estimated average annual CO(2) output according to EEMAC is six times higher than that of MOBILE6. EEMAC also indicates that around two-thirds of the fuel used for air conditioning could be saved by switching the MAC system off below 18 degrees C.

  11. External CO2 and water supplies for enhancing electrical power generation of air-cathode microbial fuel cells.

    Science.gov (United States)

    Ishizaki, So; Fujiki, Itto; Sano, Daisuke; Okabe, Satoshi

    2014-10-07

    Alkalization on the cathode electrode limits the electrical power generation of air-cathode microbial fuel cells (MFCs), and thus external proton supply to the cathode electrode is essential to enhance the electrical power generation. In this study, the effects of external CO2 and water supplies to the cathode electrode on the electrical power generation were investigated, and then the relative contributions of CO2 and water supplies to the total proton consumption were experimentally evaluated. The CO2 supply decreased the cathode pH and consequently increased the power generation. Carbonate dissolution was the main proton source under ambient air conditions, which provides about 67% of total protons consumed for the cathode reaction. It is also critical to adequately control the water content on the cathode electrode of air-cathode MFCs because the carbonate dissolution was highly dependent on water content. On the basis of these experimental results, the power density was increased by 400% (143.0 ± 3.5 mW/m(2) to 575.0 ± 36.0 mW/m(2)) by supplying a humid gas containing 50% CO2 to the cathode chamber. This study demonstrates that the simultaneous CO2 and water supplies to the cathode electrode were effective to increase the electrical power generation of air-cathode MFCs for the first time.

  12. Research of power fuel low-temperature vortex combustion in industrial boiler based on numerical modelling

    Directory of Open Access Journals (Sweden)

    Orlova K.Y.

    2017-01-01

    Full Text Available The goal of the presented research is to perform numerical modelling of fuel low-temperature vortex combustion in once-through industrial steam boiler. Full size and scaled-down furnace model created with FIRE 3D software and was used for the research. All geometrical features were observed. The baseline information for the low-temperature vortex furnace process are velocity and temperature of low, upper and burner blast, air-fuel ratio, fuel consumption, coal dust size range. The obtained results are: temperature and velocity three dimensional fields, furnace gases and solid fuel ash particles concentration.

  13. Optimization of air injection parameters toward optimum fuel saving effect for ships

    Science.gov (United States)

    Lee, Inwon; Park, Seong Hyeon

    2016-11-01

    Air lubrication method is the most promising commercial strategy for the frictional drag reduction of ocean going vessels. Air bubbles are injected through the array of holes or the slots installed onto the flat bottom surface of vessel and a sufficient supply of air is required to ensure the formation of stable air layer by the by the coalescence of the bubbles. The air layer drag reduction becomes economically meaningful when the power gain through the drag reduction exceeds the pumping power consumption. In this study, a model ship of 50k medium range tanker is employed to investigate air lubrication method. The experiments were conducted in the 100m long towing tank facility at the Pusan National University. To create the effective air lubrication with lower air flow rate, various configurations including the layout of injection holes, employment of side fences and static trim have been tested. In the preliminary series of model tests, the maximum 18.13%(at 15kts) of reduction of model resistance was achieved. This research was supported by the National Research Foundation of Korea (NRF) Grant funded by the Korea government (MEST) through GCRC-SOP (Grant No. 2011-0030013).

  14. COMBUSTION SIMULATION IN A SPARK IGNITION ENGINE CYLINDER: EFFECTS OF AIR-FUEL RATIO ON THE COMBUSTION DURATION

    Directory of Open Access Journals (Sweden)

    Nureddin Dinler

    2010-01-01

    Full Text Available Combustion is an important subject of internal combustion engine studies. To reduce the air pollution from internal combustion engines and to increase the engine performance, it is required to increase combustion efficiency. In this study, effects of air/fuel ratio were investigated numerically. An axisymmetrical internal combustion engine was modeled in order to simulate in-cylinder engine flow and combustion. Two dimensional transient continuity, momentum, turbulence, energy, and combustion equations were solved. The k-e turbulence model was employed. The fuel mass fraction transport equation was used for modeling of the combustion. For this purpose a computational fluid dynamics code was developed by using the finite volume method with FORTRAN programming code. The moving mesh was utilized to simulate the piston motion. The developed code simulates four strokes of engine continuously. In the case of laminar flow combustion, Arrhenius type combustion equations were employed. In the case of turbulent flow combustion, eddy break-up model was employed. Results were given for rich, stoichiometric, and lean mixtures in contour graphs. Contour graphs showed that lean mixture (l = 1.1 has longer combustion duration.

  15. Quantitative Analysis of Spectral Interference of Spontaneous Raman Scattering in High-Pressure Fuel-Rich H2-Air Combustion

    Science.gov (United States)

    Kojima, Jun; Nguyen, Quang-Viet

    2004-01-01

    We present a theoretical study of the spectral interferences in the spontaneous Raman scattering spectra of major combustion products in 30-atm fuel-rich hydrogen-air flames. An effective methodology is introduced to choose an appropriate line-shape model for simulating Raman spectra in high-pressure combustion environments. The Voigt profile with the additive approximation assumption was found to provide a reasonable model of the spectral line shape for the present analysis. The rotational/vibrational Raman spectra of H2, N2, and H2O were calculated using an anharmonic-oscillator model using the latest collisional broadening coefficients. The calculated spectra were validated with data obtained in a 10-atm fuel-rich H2-air flame and showed excellent agreement. Our quantitative spectral analysis for equivalence ratios ranging from 1.5 to 5.0 revealed substantial amounts of spectral cross-talk between the rotational H2 lines and the N2 O-/Q-branch; and between the vibrational H2O(0,3) line and the vibrational H2O spectrum. We also address the temperature dependence of the spectral cross-talk and extend our analysis to include a cross-talk compensation technique that removes the nterference arising from the H2 Raman spectra onto the N2, or H2O spectra.

  16. Development of fuel-rich combustor of methane-air under high pressure for chemical gas turbine system

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, Tsuyoshi; Kobayashi, Noriyuki; Arai, Norio [Nagoya Univ. (Japan)

    1996-12-31

    A new turbine system, called Chemical gas turbine system, is based on promising developments in fuel-rich combustor with a carbon fiber reinforced carbon composite (C/C composite) being used as the turbine blades. It would improve the thermal efficiency of more than 10% compared to conventional ones. As one of fundamental researches to develop this system, we designed a 4MPa-scale combustor with methane-air. Flammability limit and components of combustion gases were measured between 1.1 and 4.1 MPa in pressure. Temperature distributions of combustion gases were also measured by the thermocouple. Furthermore, simultaneous measurements of the intensity of OH fluorescence and the combustion temperature were made to clarify instant planar-distributions of these quantities under high pressure by a Planar Laser Induced Fluorescence (PLIF) system. Results from these measurements were as follows: (1) Stable combustion could attain between the equivalence ratio 0=0.7 and 1.3 at 4MPa in pressure, (2) Flammability limit extended with increasing the pressure in the fuel-rich region while it was almost constant in the fuel-lean one, (3) There was little effect of the pressure on the components of combustion gases, and (4 )Simultaneous measurements of the instant of OH fluorescence and the combustion temperature could be successfully made by a PLIF system. 2 refs., 7 figs.

  17. Characteristic Evaluation on the Cooling Performance of an Electrical Air Conditioning System Using R744 for a Fuel Cell Electric Vehicle

    Directory of Open Access Journals (Sweden)

    Moo-Yeon Lee

    2012-05-01

    Full Text Available The objective of this study was to investigate the cooling performance characteristics of an electrical air conditioning system using R744 as an alternative of R-134a for a fuel cell electric vehicle. In order to analyze the cooling performance characteristics of the air conditioning system using R744 for a fuel cell electric vehicle, an electrical air conditioning system using R744 was developed and tested under various operating conditions according to both inlet air conditions of the gas cooler and evaporator and compressor speed. The cooling capacity and coefficient of performance (COP forcooling of the tested air conditioning system were up to 6.4 kW and 2.5, respectively. In addition, the electrical air conditioning system with R744 using an inverter driven compressor showed better performance than the conventional air conditioning system with R-134a under the same operating conditions. The observed cooling performance of the developed electrical air conditioning system was found to be sufficient for cooling loads under various real driving conditions for a fuel cell electric vehicle.

  18. Indoor Air Pollution and Health in Ghana: Self-Reported Exposure to Unprocessed Solid Fuel Smoke.

    Science.gov (United States)

    Armah, Frederick A; Odoi, Justice O; Luginaah, Isaac

    2015-06-01

    Most countries in Sub-Saharan Africa including Ghana still depend extensively on unprocessed solid cooking fuels with many people exposed on a daily basis to harmful emissions and other health risks. In this study, using complementary log-log multivariate models, we estimated the health effects of exposure to smoke from unprocessed wood in four regions of Ghana while controlling for socio-environmental and socio-demographic factors. The results show that the distribution of self-reported exposure to smoke was highest among participants in the Northern region, rural dwellers, the 25-49 age groups, individuals with no education, and married women. As expected, exposure to smoke was higher in crowded households and in communities without basic social amenities. Region, residential locality, housing quality (type of roofing, floor and exterior materials), self-reported housing condition, and access to toilet facilities were associated with self-reported exposure to solid fuel smoke. Participants living in urban areas were less likely (OR = 0.82, ρ ≤ 0.01) to be exposed to solid fuel smoke compared to their rural counterparts. An inverse relationship between self-reported housing condition and exposure to solid fuel smoke was observed and persisted even after adjustments were made for confounding variables in the demographic model. In Ghana, the cost and intermittent shortages of liquefied petroleum gas and other alternative fuel sources hold implications for the willingness of the poor to shift to their use. Thus, the poorest rural populations with nearly no cash income and electricity, but with access to wood and/or agricultural waste, are unlikely to move to clean fuels or use significantly improved stoves without large subsidies, which are usually not sustainable. However, there appears to be large populations between these extremes that can be targeted by efforts to introduce improved stoves.

  19. Sustainable design of high-performance microsized microbial fuel cell with carbon nanotube anode and air cathode.

    Science.gov (United States)

    Mink, Justine E; Hussain, Muhammad Mustafa

    2013-08-27

    Microbial fuel cells (MFCs) are a promising alternative energy source that both generates electricity and cleans water. Fueled by liquid wastes such as wastewater or industrial wastes, the microbial fuel cell converts waste into energy. Microsized MFCs are essentially miniature energy harvesters that can be used to power on-chip electronics, lab-on-a-chip devices, and/or sensors. As MFCs are a relatively new technology, microsized MFCs are also an important rapid testing platform for the comparison and introduction of new conditions or materials into macroscale MFCs, especially nanoscale materials that have high potential for enhanced power production. Here we report a 75 μL microsized MFC on silicon using CMOS-compatible processes and employ a novel nanomaterial with exceptional electrochemical properties, multiwalled carbon nanotubes (MWCNTs), as the on-chip anode. We used this device to compare the usage of the more commonly used but highly expensive anode material gold, as well as a more inexpensive substitute, nickel. This is the first anode material study done using the most sustainably designed microsized MFC to date, which utilizes ambient oxygen as the electron acceptor with an air cathode instead of the chemical ferricyanide and without a membrane. Ferricyanide is unsustainable, as the chemical must be continuously refilled, while using oxygen, naturally found in air, makes the device mobile and is a key step in commercializing this for portable technology such as lab-on-a-chip for point-of-care diagnostics. At 880 mA/m(2) and 19 mW/m(2) the MWCNT anode outperformed the others in both current and power densities with between 6 and 20 times better performance. All devices were run for over 15 days, indicating a stable and high-endurance energy harvester already capable of producing enough power for ultra-low-power electronics and able to consistently power them over time.

  20. Sustainable design of high-performance microsized microbial fuel cell with carbon nanotube anode and air cathode

    KAUST Repository

    Mink, Justine E.

    2013-08-27

    Microbial fuel cells (MFCs) are a promising alternative energy source that both generates electricity and cleans water. Fueled by liquid wastes such as wastewater or industrial wastes, the microbial fuel cell converts waste into energy. Microsized MFCs are essentially miniature energy harvesters that can be used to power on-chip electronics, lab-on-a-chip devices, and/or sensors. As MFCs are a relatively new technology, microsized MFCs are also an important rapid testing platform for the comparison and introduction of new conditions or materials into macroscale MFCs, especially nanoscale materials that have high potential for enhanced power production. Here we report a 75 μL microsized MFC on silicon using CMOS-compatible processes and employ a novel nanomaterial with exceptional electrochemical properties, multiwalled carbon nanotubes (MWCNTs), as the on-chip anode. We used this device to compare the usage of the more commonly used but highly expensive anode material gold, as well as a more inexpensive substitute, nickel. This is the first anode material study done using the most sustainably designed microsized MFC to date, which utilizes ambient oxygen as the electron acceptor with an air cathode instead of the chemical ferricyanide and without a membrane. Ferricyanide is unsustainable, as the chemical must be continuously refilled, while using oxygen, naturally found in air, makes the device mobile and is a key step in commercializing this for portable technology such as lab-on-a-chip for point-of-care diagnostics. At 880 mA/m2 and 19 mW/m2 the MWCNT anode outperformed the others in both current and power densities with between 6 and 20 times better performance. All devices were run for over 15 days, indicating a stable and high-endurance energy harvester already capable of producing enough power for ultra-low-power electronics and able to consistently power them over time. © 2013 American Chemical Society.

  1. The Role of Hydrogen Bonding on Laminar Burning Velocity of Hydrous and Anhydrous Ethanol Fuel with Small Addition of n-Heptane

    OpenAIRE

    I Made Suarta; Wardana, I. N. G.; Nurkholis Hamidi; Widya Wijayanti

    2016-01-01

    The molecular structure of mixed hydrous and anhydrous ethanol with up to 10% v n-heptane had been studied. The burning velocity was examined in a cylindrical explosion combustion chamber. The result showed that the burning velocity of hydrous ethanol is higher than anhydrous ethanol and n-heptane at stoichiometric, rich, and very rich mixtures. The burning velocity of hydrous ethanol with n-heptane drops drastically compared to the burning velocity of anhydrous ethanol with n-heptane. It is ...

  2. COMPARISON OF AIR POLLUTANT EMISSIONS FROM THE COMBUSTION OF ORIMULSION AND OTHER FUELS

    Science.gov (United States)

    The paper gives results of inhouse emissions testing and a literature review relating to Orimulsion, an emulsion of Venezuelan bitumen, water, and a proprietary surfactant, being used as a fuel for utilities in Canada, China, Denmark, Italy, Japan, and Lithuania, primarily as a r...

  3. Fuel Cell Vehicle Fleet and Hydrogen Infrastructure at Hickam Air Force Base

    Science.gov (United States)

    2009-04-27

    busbar in the manifold region of the fuel cell power module. To address this accelerated corrosion problem, the endplate and busbar were both...there has been no evidence of busbar or endplate corrosion in the manifold region. The crossover leak was the result of a failed humidification device

  4. Method for the integrated operation of a fuel cell and an air separator

    NARCIS (Netherlands)

    Hemmes, K.

    The invention relates to a system and method for integrating renewable energy and a fuel cell for the production of electricity and hydrogen, wherein this comprises the use of renewable energy as fluctuating energy source for the production of electricity and also comprises the use of at least one

  5. Aircraft Fuel, Hydraulic and Pneumatic Systems (Course Outlines), Aviation Mechanics 3 (Air Frame): 9067.01.

    Science.gov (United States)

    Dade County Public Schools, Miami, FL.

    This document presents an outline for a 135-hour course designed to familiarize the student with the operation, inspection, and repair of aircraft fuel, hydraulic, and pneumatic systems. It is designed to help the trainee master the knowledge and skills necessary to become an aviation airframe mechanic. The aviation airframe maintenance technician…

  6. Method for the integrated operation of a fuel cell and an air separator

    NARCIS (Netherlands)

    Hemmes, K.

    2007-01-01

    The invention relates to a system and method for integrating renewable energy and a fuel cell for the production of electricity and hydrogen, wherein this comprises the use of renewable energy as fluctuating energy source for the production of electricity and also comprises the use of at least one

  7. Steam Methane Reformation Testing for Air-Independent Solid Oxide Fuel Cell Systems

    Science.gov (United States)

    Mwara, Kamwana N.

    2015-01-01

    Recently, NASA has been looking into utilizing landers that can be propelled by LOX-CH (sub 4), to be used for long duration missions. Using landers that utilize such propellants, also provides the opportunity to use solid oxide fuel cells as a power option, especially since they are able to process methane into a reactant through fuel reformation. One type of reformation, called steam methane reformation, is a process to reform methane into a hydrogen-rich product by reacting methane and steam (fuel cell exhaust) over a catalyst. A steam methane reformation system could potentially use the fuel cell's own exhaust to create a reactant stream that is hydrogen-rich, and requires less internal reforming of the incoming methane. Also, steam reformation may hold some advantages over other types of reforming, such as partial oxidation (PROX) reformation. Steam reformation does not require oxygen, while up to 25 percent can be lost in PROX reformation due to unusable CO (sub 2) reformation. NASA's Johnson Space Center has conducted various phases of steam methane reformation testing, as a viable solution for in-space reformation. This has included using two different types of catalysts, developing a custom reformer, and optimizing the test system to find the optimal performance parameters and operating conditions.

  8. Conceptual Design Tool for Fuel-Cell Powered Micro Air Vehicles

    Science.gov (United States)

    2010-03-01

    power of 0.6 W/cm 2 /cell. The BOP power consumption of the compressor, water pump, and radiator was found by scaling. The motor was modeled as a...for a hydrogen fuel cell is given by F g E f 2   , where E is the reversible electromotive force ( EMF ) or reversible open circuit voltage, fg

  9. The United States Air Force Aims to be Fueled by Innovation, but is it Developing Leaders Who Can Hit That Target?

    Science.gov (United States)

    2014-06-13

    2001/12/ primal -leadership-the-hidden-driver-of-great-performance/ar/pr (accessed November 7, 2013). Govindarajan, Vijay. 2010. Innovation is not...THE UNITED STATES AIR FORCE AIMS TO BE FUELED BY INNOVATION , BUT IS IT DEVELOPING LEADERS WHO CAN HIT THAT TARGET? A thesis...Force Aims to be Fueled by Innovation , but is it Developing Leaders Who Can Hit That Target? 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM

  10. Effects of fuel and air mixing on WOT output in direct injection gasoline engine; Chokufun gasoline kikan ni okeru nenryo to kuki no kongo to shutsuryoku seino

    Energy Technology Data Exchange (ETDEWEB)

    Noda, T.; Iriya, Y.; Naito, K.; Mitsumoto, H.; Iiyama, A. [Nissan Motor Co. Ltd., Tokyo (Japan)

    1997-10-01

    The effects of in-cylinder charge motion and the characteristics of the fuel spray and piston crown shape on WOT output in a direct injection gasoline engine are investigated. The fuel and air mixing process in a cylinder is analyzed by computer simulation and LIF method visualization. As a result, the technical factors to achieve enough mixing in a DI gasoline engine equipped with bowl in piston optimized for stratified combustion are clarified. 7 refs., 9 figs., 1 tab.

  11. Effect of the air-fuel mixing on the NOx yield in a low-emission gas-turbine plant combustor

    Science.gov (United States)

    Vasil'ev, V. D.; Bulysova, L. A.; Berne, A. L.

    2016-04-01

    The article deals with construction of a simplified model of inhibition of nitric oxides formed in the combustors of the gas-turbine plants (GTPs) operating on natural gas. A combustor in which premixed, lean air-fuel mixtures are burnt is studied theoretically and experimentally. The research was carried out using a full-scale combustor that had parameters characteristic of modern GTPs. The article presents the results computed by the FlowVision software and the results of the experiments carried out on the test bench of the All-Russia Thermal Engineering Institute. The calculations and the tests were conducted under the following conditions: a flow rate of approximately 4.6 kg/s, a pressure to 450 kPa, an air temperature at the combustor inlet of approximately 400°C, the outlet temperature t 3 ≤ 1200°C, and natural gas as the fuel. The comparison of the simulated parameters with the experimental results underlies the constructed correlation dependence of the experimental NO x emission on the calculated parameter of nonuniform fuel concentration at the premixing zone outlet. The postulate about a weak dependence of the emission of NO x formed upon combustion of a perfectly mixed air-fuel mixture—when the methane concentration in air is constant at any point of the air-fuel mixture, i.e., constant in the mixture bulk—on the pressure in the combustor has been experimentally proven. The correctness and the practicability of the stationary mathematical model of the mixing process used to assess the NO x emission by the calculated amount of the air-fuel mixture generated in the premixing zone has been validated. This eliminates some difficulties that arise in the course of calculation of combustion and formation of NO x .

  12. Our Breaths We Take: Outdoor Air Quality, Health, and Climate Change Consequences of Household Heating and Cooking with Solid Fuels

    Science.gov (United States)

    Chafe, Zoe Anna

    Worldwide, nearly 3 billion people--40% of the global population--burn wood, coal, and other solid fuels every day to cook their food; this number is even larger when including those who heat their homes with solid fuels as well. Exposure to pollution from heating and cooking fires causes about 3 million deaths each year, making it one of the biggest environmental health problems the world faces. The harm from this smoke is not restricted to those who breathe it, however: it contains gases and particles that contribute to global climate change as well. Chapter 2 shows that household cooking with solid fuels caused an estimated 12% of population-weighted ambient PM2.5 worldwide in 2010. Exposure to this air pollution caused the loss of 370,000 lives and 9.9 million disability-adjusted life years (DALYs) globally in the same year. In Chapter 3 I demonstrate that household heating with solid fuels caused an estimated 21% of population-weighted ambient PM2.5 in 2010 in Central Europe, 13% in Eastern Europe, 12% in Western Europe, and 8% in North America. Exposure to this air pollution results caused approximately 60,000 premature deaths in Europe, and nearly 10,000 deaths in North America, as well as an estimated 1.0 million disability-adjusted life years (DALYs) in Europe and 160,000 DALYs in North America. Chapter 4 addresses drivers of household wood combustion pollution in the San Francisco Bay Area, where the sector is the largest source of PM 2.5 and regulators recently introduced amendments to wood burning rules for the airshed. Fireplaces are the source of the vast majority (84%) of PM 2.5 from residential wood combustion in the San Francisco Bay Area, despite their use primarily as an aesthetic or recreational combustion activity. By evaluating hypothetical fuel and combustion device changeouts, I find that replacing fireplaces with gas would yield significant health and economic benefits. Specifically, retrofitting frequently used fireplaces (300,000 units

  13. Escape Velocity

    Directory of Open Access Journals (Sweden)

    Nikola Vlacic

    2010-01-01

    Full Text Available In this project, we investigated if it is feasible for a single staged rocket with constant thrust to attain escape velocity. We derived an equation for the velocity and position of a single staged rocket that launches vertically. From this equation, we determined if an ideal model of a rocket is able to reach escape velocity.

  14. Accelerated OH(-) transport in activated carbon air cathode by modification of quaternary ammonium for microbial fuel cells.

    Science.gov (United States)

    Wang, Xin; Feng, Cuijuan; Ding, Ning; Zhang, Qingrui; Li, Nan; Li, Xiaojing; Zhang, Yueyong; Zhou, Qixing

    2014-04-01

    Activated carbon (AC) is a promising catalyst for the air cathode of microbial fuel cells (MFCs) because of its high performance and low cost. To increase the performance of AC air cathodes, the acceleration of OH(-) transport is one of the most important methods, but it has not been widely investigated. Here we added quaternary ammonium to ACs by in situ anchoring of a quaternary ammonium/epoxide-reacting compound (QAE) or ex situ mixing with anion exchange resins in order to modify ACs from not only the external surface but also inside the pores. In 50 mM phosphate buffer solution (PBS), the in situ anchoring of QAE was a more effective way to increase the power. The highest power density of 2781 ± 36 mW/m(2), which is 10% higher than that of the control, was obtained using QAE-anchored AC cathodes. When the medium was switched to an unbuffered NaCl solution, the increase in maximum power density (885 ± 25 mW/m(2)) was in accordance with the anion exchange capacity (0.219 mmol/g). The highest power density of the anion exchange resin-mixed air cathode was 51% higher than that of the control, indicating that anion exchange is urgently needed in real wastewaters. Excess anchoring of QAE blocked both the mesopores and micropores, causing the power output to be inhibited.

  15. Air

    Science.gov (United States)

    ... and your health: Green living Sun Water Air Health effects of air pollution How to protect yourself from air pollution Chemicals Noise Quizzes Links to more information girlshealth glossary girlshealth. ...

  16. SPUTUM CYTOLOGY CULTURE HAEMATOLOGICAL CHANGES AND AIR QUALITY IN CHRONIC EXPOSURE TO SMOKE FROM BIOMASS FUEL IN RURAL AREA OF SOUTH INDIA

    Directory of Open Access Journals (Sweden)

    Razia Sultana

    2016-08-01

    Full Text Available BACKGROUND Air pollution is generally perceived as an urban problem associated with automobiles and industries. However, half of the world’s population in rural areas of the developing countries is exposed to some of the highest levels of air pollution due to burning of traditional biomass fuels. In view of this, the health impact of biomass fuel use in rural India has been evaluated in this study. OBJECTIVES To analyse the mass concentration in biomass fuel user and LPG user household and to investigate the effects of biomass smoke exposure in a group of rural women who cook regularly with biomass fuels and compare the results obtained from control group women who cook relatively cleaner fuel, liquefied petroleum gas (LPG. METHODS Respiratory health was evaluated from Questionnaire survey, Clinical examination, haematology, sputum cytology culture and serum C-reactive protein (CRP levels are investigated in biomass and control users. RESULTS A total of 150 women were approached, of which only 70 non-smoking women without any history of any major chronic illness in the past were selected for this study. CRP levels differ significantly in biomass exposure than control users. CONCLUSION From our study it is clear that with increasing duration of exposure to biomass fuel combustion. Women who used to cook with traditional biomass fuels had low haemoglobin & Red Blood Cells values, increased neutrophil and allergic manifestations. Sputum cytology of majority biomass users revealed bacterial infections & chronic inflammation.

  17. Impacts of internal fuel reforming and varied levels of EGR on ethanol/air HCCI combustion: a second law analysis

    Energy Technology Data Exchange (ETDEWEB)

    Gnanam, G.; Johnson, M.; Sobiesiak, A.; Reader, G. [Windsor Univ., ON (Canada). Dept. of Mechanical, Automotive and Materials Engineering

    2005-07-01

    A study of internal fuel reforming on ethanol/air homogenous charge compression ignition (HCCI) combustion engines was presented. Fuel reforming is carried out to generate hydrogen or hydrogen-rich products from primary fuel. Hydrogen has the advantage of relatively wide flammability limits and good burning quality, and a hydrogen addition allows the operation of the methane or propane fuelled engine at a leaner equivalence ratio, with less cycle-to-cycle variations. Leaner mixtures have the advantage of reducing the peak cycle temperatures with a concurrent reduction in engine-out nitrogen oxide (NO{sub x}) emissions. This analysis was based on the second law of thermodynamics and it calculated the values of thermodynamic function availability and its distribution during the HCCI engine cycle. The engine modelling involved a multi-step simulation of the engine cycle, which consisted of a fuel reformation cycle and a HCCI combustion cycle. The modelling was carried out using a single zone well-stirred reactor model and established reaction mechanisms. The HCCI engine cycle was fuelled with a lean mixture of air and ethanol. Simulation results indicated that internal reforming has the advantage of operating the HCCI engine with lower charge preheating and had fewer efficiency losses than the HCCI engine operated with no internal reforming. In addition, the composition of reformation products as a whole rather than just the hydrogen concentration had a high impact on the efficiency of the HCCI engine. Results indicate that there is an optimal internal reforming duration, for which the hydrogen yield is maximized. However, heat transfer losses had a major impact on the availability analysis calculations, contributing to availability transfer and destruction, and should be included in the model. It was concluded that in order to fully investigate the effects of heat transfer losses and combustion, a dedicated model needs to be developed to separately calculate the

  18. Internal combustion engine cylinder-to-cylinder balancing with balanced air-fuel ratios

    Science.gov (United States)

    Harris, Ralph E.; Bourn, Gary D.; Smalley, Anthony J.

    2006-01-03

    A method of balancing combustion among cylinders of an internal combustion engine. For each cylinder, a normalized peak firing pressure is calculated as the ratio of its peak firing pressure to its combustion pressure. Each cylinder's normalized peak firing pressure is compared to a target value for normalized peak firing pressure. The fuel flow is adjusted to any cylinder whose normalized peak firing pressure is not substantially equal to the target value.

  19. Air pollution from household solid fuel combustion in India: an overview of exposure and health related information to inform health research priorities

    Science.gov (United States)

    Balakrishnan, Kalpana; Ramaswamy, Padmavathi; Sambandam, Sankar; Thangavel, Gurusamy; Ghosh, Santu; Johnson, Priscilla; Mukhopadhyay, Krishnendu; Venugopal, Vidhya; Thanasekaraan, Vijayalakshmi

    2011-01-01

    Environmental and occupational risk factors contribute to nearly 40% of the national burden of disease in India, with air pollution in the indoor and outdoor environment ranking amongst leading risk factors. It is now recognized that the health burden from air pollution exposures that primarily occur in the rural indoors, from pollutants released during the incomplete combustion of solid fuels in households, may rival or even exceed the burden attributable to urban outdoor exposures. Few environmental epidemiological efforts have been devoted to this setting, however. We provide an overview of important available information on exposures and health effects related to household solid fuel use in India, with a view to inform health research priorities for household air pollution and facilitate being able to address air pollution within an integrated rural–urban framework in the future. PMID:21987631

  20. Effect of additives on the electrochemical behaviour of zinc anodes for zinc/air fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Chang Woo; Sathiyanarayanan, K.; Eom, Seung Wook; Kim, Hyun Soo; Yun, Mun Soo [Battery Research Group, Korea Electrotechnology Research Institute (KERI), P.O. Box 20, ChangWon, 641-600 (S. Korea)

    2006-09-29

    Due to its low cost and high power density, the Zn/air energy system is considered to be a promising power energy source. Furthermore, Zn/air technology could be used as either an electrically or a mechanically rechargeable system. Electrical recharging is problematic, however, due to the formation of zinc dendrites. Similarly, hydrogen overpotential plays a major role. The present study attempts to reduce dendrite formation and raise hydrogen overpotential through the addition of cellulose and lead oxide, respectively. It is concluded that cellulose reduces dendrite formation to some extent. It also works well to raise the hydrogen overpotential even in the absence of lead oxide. (author)

  1. New highly active oxygen reduction electrode for PEM fuel cell and Zn/air battery applications (NORA). Final report

    Energy Technology Data Exchange (ETDEWEB)

    Thiele, D.; Zuettel, A.

    2008-04-15

    This illustrated final report for the Swiss Federal Office of Energy (SFOE) presents the results of a project concerning a new, highly active oxygen reduction electrode for PEM fuel cell and zinc/air battery applications. The goal of this project was, according to the authors, to increase the efficiency of the oxygen reduction reaction by lowering the activation polarisation through the right choice of catalyst and by lowering the concentration polarisation. In this work, carbon nanotubes are used as support material. The use of these nanotubes grown on perovskites is discussed. Theoretical considerations regarding activation polarisation are discussed and alternatives to the use of platinum are examined. The results of experiments carried out are presented in graphical and tabular form. The paper is completed with a comprehensive list of references.

  2. A Soft Sensor-Based Fault-Tolerant Control on the Air Fuel Ratio of Spark-Ignition Engines

    Directory of Open Access Journals (Sweden)

    Yu-Jia Zhai

    2017-01-01

    Full Text Available The air/fuel ratio (AFR regulation for spark-ignition (SI engines has been an essential and challenging control problem for engineers in the automotive industry. The feed-forward and feedback scheme has been investigated in both academic research and industrial application. The aging effect can often cause an AFR sensor fault in the feedback loop, and the AFR control performance will degrade consequently. In this research, a new control scheme on AFR with fault-tolerance is proposed by using an artificial neural network model based on fault detection and compensation, which can provide the satisfactory AFR regulation performance at the stoichiometric value for the combustion process, given a certain level of misreading of the AFR sensor.

  3. [Research on parameters of dynamic colorimetric temperature sensor and it's application to fuel air explosion temperature field detection].

    Science.gov (United States)

    Li, Lei; Liu, Qing-ming; Wang, Jian-ping

    2013-09-01

    According to the theory of colorimetric thermometry,the influences of center wavelength, wavelength bandwidth and solid angle on response speed and the precision of the sensor was analyzed systematically, and the operating parameters for transient high temperature measurement system were determined. A calculation method based on photoelectric conversion coefficient, and higher and lower operating wavelength of the colorimetric temperature sensor was given. At the optimal operating temperature, calibration experiment was conducted in a high temperature blackbody furnace. Based on the experimental results, the operating parameters of the sensor were determined and the colorimetric temperature response was calculated. The results show that the errors between the calculated response and the experiment one are less than 1%. By using the colorimetric temperature sensor, the temperature response of fuel air explosion field was detected and the variations of temperature with time and space in detonation field were obtained.

  4. CFD modelling of air-fired and oxy-fuel combustion of lignite in a 100 KW furnace

    Energy Technology Data Exchange (ETDEWEB)

    Audai Hussein Al-Abbas; Jamal Naser; David Dodds [Swinburne University of Technology, Hawthorn, Vic. (Australia). Faculty of Engineering and Industrial Science

    2011-05-15

    A comprehensive computational fluid dynamics (CFD) modelling study was undertaken by integrating the combustion of pulverized dry lignite in several combustion environments. Four different cases were investigated: an air-fired and three different oxy-fuel combustion environments (25 vol.% O{sub 2} concentration (OF25), 27 vol.% O{sub 2} concentration (OF27), and 29 vol.% O{sub 2} concentration (OF29) were considered. The chemical reactions (devolatilization and char burnout), convective and radiative heat transfer, fluid and particle flow fields (homogenous and heterogenous processes), and turbulent models were employed in 3-D hybrid unstructured grid CFD simulations. The available experimental results from a lab-scale 100 KW firing lignite unit (Chalmer's furnace) were selected for the validation of these simulations. The numerical results showed that the flame temperature distributions and O{sub 2} consumptions of the OF25 case were approximately similar to the reference combustion case. In contrast, in the OF27 and OF29 combustion cases, the flame temperatures were higher and more confined in the closest region of the burner exit plane. This was a result of the quick consumption of oxygen that led to improve the ignition conditions in the latter combustion cases. Therefore, it is concluded that the resident time, stoichiometry, and recycled flue gas rates are relevant parameters to optimize the design of oxy-fuel furnaces. The findings showed reasonable agreement with the qualitative and quantitative measurements of temperature distribution profiles and species concentration profiles at the most intense combustion locations inside the furnace. These numerical results can provide useful information towards future modelling of the behaviour of pulverized brown coal in a large-scale oxy-fuel furnace/boiler in order to optimize the burner's and combustor's design. 46 refs., 16 figs., 6 tabs.

  5. Multi-dimensional modelling of spray, in-cylinder air motion and fuel ...

    Indian Academy of Sciences (India)

    Keywords. SI engine; direct injection; in-cylinder fuel–air mixing; CFD; two-phase flow. ... with regards to injector and spark plug locations. Simulations over a range of speed and load indicate the need for a novel ignition strategy involving dual spark plugs and also provide guidelines in deciding spark plug locations.

  6. Fuel-Air Injection Effects on Combustion in Cavity-Based Flameholders in a Supersonic Flow

    Science.gov (United States)

    2005-03-01

    University Air Education and Training Command In Partial Fulfillment of the Requirements for the Degree of Master of Science in Aeronautical Engineering...Combustion Science and Tecnology Vol 97 pp 137- 156. 3 Aviation History On Line Museum, http://www.aviation- history.com/engines/ramjet.html

  7. Inhalation Exposure to Jet Fuel (JP8) Among U.S. Air Force Personnel

    Science.gov (United States)

    2010-10-01

    collect vapor samples on coconut shell chareoal in tWQ.scction (100 mg/50 mg) glass sorbcnt tubes (Anasorb; SKC Inc .. Eighty Four. Pa.) at a now...with flamc ionizatiol1 detcction (GCfFID) (NIOSH 1550).(19) Air samples were cxtractcd using NIOSH method 1550.(19) Brieny lhe charcoal from the

  8. Wastewater treatment, energy recovery and desalination using a forward osmosis membrane in an air-cathode microbial osmotic fuel cell

    KAUST Repository

    Werner, Craig M.

    2013-02-01

    A microbial osmotic fuel cell (MOFC) has a forward osmosis (FO) membrane situated between the electrodes that enable desalinated water recovery along with power generation. Previous designs have required aerating the cathode chamber water, offsetting the benefits of power generation by power consumption for aeration. An air-cathode MOFC design was developed here to improve energy recovery, and the performance of this new design was compared to conventional microbial fuel cells containing a cation (CEM) or anion exchange membrane (AEM). Internal resistance of the MOFC was reduced with the FO membrane compared to the ion exchange membranes, resulting in a higher maximum power production (43W/m3) than that obtained with an AEM (40W/m3) or CEM (23W/m3). Acetate (carbon source) removal reached 90% in the MOFC; however, a small amount of acetate crossed the membrane to the catholyte. The initial water flux declined by 28% from cycle 1 to cycle 3 of operation but stabilized at 4.1L/m2/h over the final three batch cycles. This decline in water flux was due to membrane fouling. Overall desalination of the draw (synthetic seawater) solution was 35%. These results substantially improve the prospects for simultaneous wastewater treatment and seawater desalination in the same reactor. © 2012 Elsevier B.V.

  9. Management Impact Assessment of Refuse-Derived Fuel Implementation at Wright-Patterson Air Force Base.

    Science.gov (United States)

    1982-03-19

    yard Leach Packers, although a recovery facility, number of vehicles by Heil, Garwood, and Truxmore Nearly a decade ago, Baltimore County public also are...fluff. First, pellets will store for a much longer period of time. "if you store fluff for longer than ten days, you wind up with a compost heap ...demonstrate that we can mix one or mare of the fuels with oil in order to save scm of the increasingly costly "liquid gold ." Simultaneously, we are looking

  10. Catalytic autothermal reforming of Jet fuel

    Science.gov (United States)

    Lenz, Bettina; Aicher, Thomas

    Aircraft manufacturers have to reduce the emissions and the specific fuel consumption of their systems. Fuel cell use in a 'more electric aircraft' can be one possibility. To keep the technology simple only one fuel (Jet A, Jet A-1) shall be used on board the aircraft. Therefore, the catalytic reforming of Jet A-1 fuel was examined in this paper, although the use of fossil fuels causes the production of greenhouse effect promoting gases like carbon dioxide CO 2. The autothermal reforming of desulphurised kerosene is examined with a 15 kW (based on the lower heating value of Jet fuel) test rig. The experiments are performed at steam to carbon ratios of S/C = 1.5-2.5 and air to fuel ratios of λ = 0.24-0.32, respectively. The composition of the product gas, the volumetric flow rate of the product gas at standard conditions and the temperatures in the catalyst are determined as a function of the operating variables. The gas hourly space velocity (GHSV) is varied between 50,000 and 300,000 h -1. The influence of sulphur containing feed streams (real Jet fuel) on reforming behaviour is investigated as well as the influence of the hydrogen concentration on the hydrodesulphurisation process. Another simple way of desulphurisation is the adsorption of liquid sulphur containing hydrocarbons, the influence of the variation of the liquid hourly space velocity (LHSV) is measured at a temperature of 150 °C.

  11. Effect of Water-Alcohol Injection and Maximum Economy Spark Advance on Knock-Limited Performance and Fuel Economy of a Large Air-Cooled Cylinder

    Science.gov (United States)

    Heinicke, Orville H.; Vandeman, Jack E.

    1945-01-01

    An investigation was conducted to determine the effect of a coolant solution of 25 percent ethyl alcohol, 25 percent methyl alcohol, and 50 percent water by volume and maximum-economy spark advance on knock-limited performance and fuel economy of a large air-cooled cylinder. The knock-limited performance of the cylinder at engine speeds of 2100 and 2500 rpm was determined for coolant-fuel ratios of 0.0, 0.2, and 0.4. The effect of water-alcohol injection on fuel economy was determined in constant charge-air flow tests. The tests were conducted at a spark advance of 20 deg B.T.C. and maximum-economy spark advance.

  12. Quantitative fuel vapor/air mixing imaging in droplet/gas regions of an evaporating spray flow using filtered Rayleigh scattering.

    Science.gov (United States)

    Allison, Patton M; McManus, Thomas A; Sutton, Jeffrey A

    2016-03-15

    This Letter demonstrates the application of filtered Rayleigh scattering (FRS) for quantitative two-dimensional fuel vapor/air mixing measurements in an evaporating hydrocarbon fuel spray flow. Using the FRS approach, gas-phase measurements are made in the presence of liquid-phase droplets without interference. Effective suppression of the liquid-phase droplet scattering using FRS is enabled by the high spectral purity of the current Nd:YAG laser system. Simultaneous Mie-scattering imaging is used to visualize the droplet field and illustrate the droplet loading under which the FRS imaging is applied in the current spray flows. The initial quantification of the FRS imaging is based on calibration measurements from a flow cell of known fuel vapor/air mixtures, while future work targets the utilization of a Rayleigh-Brillouin spectral model for quantification of the FRS signals.

  13. Spatial distribution of bacterial communities on volumetric and planar anodes in single-chamber air-cathode microbial fuel cells

    KAUST Repository

    Vargas, Ignacio T.

    2013-05-29

    Pyrosequencing was used to characterize bacterial communities in air-cathode microbial fuel cells across a volumetric (graphite fiber brush) and a planar (carbon cloth) anode, where different physical and chemical gradients would be expected associated with the distance between anode location and the air cathode. As expected, the stable operational voltage and the coulombic efficiency (CE) were higher for the volumetric anode than the planar anode (0.57V and CE=22% vs. 0.51V and CE=12%). The genus Geobacter was the only known exoelectrogen among the observed dominant groups, comprising 57±4% of recovered sequences for the brush and 27±5% for the carbon-cloth anode. While the bacterial communities differed between the two anode materials, results showed that Geobacter spp. and other dominant bacterial groups were homogenously distributed across both planar and volumetric anodes. This lends support to previous community analysis interpretations based on a single biofilm sampling location in these systems. © 2013 Wiley Periodicals, Inc.

  14. Electric field induced salt precipitation into activated carbon air-cathode causes power decay in microbial fuel cells.

    Science.gov (United States)

    An, Jingkun; Li, Nan; Wan, Lili; Zhou, Lean; Du, Qing; Li, Tian; Wang, Xin

    2017-10-15

    As a promising design for the real application of microbial fuel cells (MFCs) in wastewater treatment, activated carbon (AC) air-cathode is suffering from a serious power decay after long-term operation. However, the decay mechanism is still not clear because of the complex nature of contaminations. Different from previous reports, we found that local alkalinization and natural evaporation had an ignorable effect on cathode performance (∼2% decay on current densities), while electric field induced salt precipitation (∼53%) and biofouling (∼37%) were dominant according to the charge transfer resistance, which decreased power desities by 36% from 1286 ± 30 to 822 ± 23 mW m -2 in 6 months. Biofouling can be removed by scrapping, however, electric field induced salt precipitation under biofilm still clogged 37% of specific area in catalyst layer, which was even seen to penetrate through the gas diffusion layer. Our findings provided a new insight of AC air-cathode performance decay, providing important information for the improvement of cathodic longevity in the future. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. Performance evaluation of an advanced air-fuel ratio controller on a stationary, rich-burn natural gas engine

    Science.gov (United States)

    Kochuparampil, Roshan Joseph

    The advent of an era of abundant natural gas is making it an increasingly economical fuel source against incumbents such as crude oil and coal, in end-use sectors such as power generation, transportation and industrial chemical production, while also offering significant environmental benefits over these incumbents. Equipment manufacturers, in turn, are responding to widespread demand for power plants optimized for operation with natural gas. In several applications such as distributed power generation, gas transmission, and water pumping, stationary, spark-ignited, natural gas fueled internal combustion engines (ICEs) are the power plant of choice (over turbines) owing to their lower equipment and operational costs, higher thermal efficiencies across a wide load range, and the flexibility afforded to end-users when building fine-resolution horsepower topologies: modular size increments ranging from 100 kW -- 2 MW per ICE power plant compared to 2 -- 5 MW per turbine power plant. Under the U.S. Environment Protection Agency's (EPA) New Source Performance Standards (NSPS) and Reciprocating Internal Combustion Engine National Emission Standards for Hazardous Air Pollutants (RICE NESHAP) air quality regulations, these natural gas power plants are required to comply with stringent emission limits, with several states mandating even stricter emissions norms. In the case of rich-burn or stoichiometric natural gas ICEs, very high levels of sustained emissions reduction can be achieved through exhaust after-treatment that utilizes Non Selective Catalyst Reduction (NSCR) systems. The primary operational constraint with these systems is the tight air-fuel ratio (AFR) window of operation that needs to be maintained if the NSCR system is to achieve simultaneous reduction of carbon monoxide (CO), nitrogen oxides (NOx), total hydrocarbons (THC), volatile organic compounds (VOCs), and formaldehyde (CH 2O). Most commercially available AFR controllers utilizing lambda (oxygen

  16. The Prescribed Velocity Method

    DEFF Research Database (Denmark)

    Nielsen, Peter Vilhelm

    The- velocity level in a room ventilated by jet ventilation is strongly influenced by the supply conditions. The momentum flow in the supply jets controls the air movement in the room and, therefore, it is very important that the inlet conditions and the numerical method can generate a satisfactory...

  17. Coal-water mixture fuel burner

    Science.gov (United States)

    Brown, T.D.; Reehl, D.P.; Walbert, G.F.

    1985-04-29

    The present invention represents an improvement over the prior art by providing a rotating cup burner arrangement for use with a coal-water mixture fuel which applies a thin, uniform sheet of fuel onto the inner surface of the rotating cup, inhibits the collection of unburned fuel on the inner surface of the cup, reduces the slurry to a collection of fine particles upon discharge from the rotating cup, and further atomizes the fuel as it enters the combustion chamber by subjecting it to the high shear force of a high velocity air flow. Accordingly, it is an object of the present invention to provide for improved combustion of a coal-water mixture fuel. It is another object of the present invention to provide an arrangement for introducing a coal-water mixture fuel into a combustion chamber in a manner which provides improved flame control and stability, more efficient combustion of the hydrocarbon fuel, and continuous, reliable burner operation. Yet another object of the present invention is to provide for the continuous, sustained combustion of a coal-water mixture fuel without the need for a secondary combustion source such as natural gas or a liquid hydrocarbon fuel. Still another object of the present invention is to provide a burner arrangement capable of accommodating a coal-water mixture fuel having a wide range of rheological and combustion characteristics in providing for its efficient combustion. 7 figs.

  18. Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air or Liquid Heat Integration

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen; Sahlin, Simon Lennart

    2013-01-01

    The present work describes the ongoing development of high temperature PEM fuel cell systems fuelled by steam reformed methanol. Various fuel cell system solutions exist, they mainly differ depending on the desired fuel used. High temperature PEM (HTPEM) fuel cells offer the possibility of using...

  19. Soil- and groundwater-quality data for petroleum hydrocarbon compounds within Fuels Area C, Ellsworth Air Force Base, South Dakota, 2014

    Science.gov (United States)

    Bender, David A.; Rowe, Barbara L.

    2015-01-01

    Ellsworth Air Force Base is an Air Combat Command located approximately 10 miles northeast of Rapid City, South Dakota. Ellsworth Air Force Base occupies about 6,000 acres within Meade and Pennington Counties, and includes runways, airfield operations, industrial areas, housing, and recreational facilities. Fuels Area C within Ellsworth Air Force Base is a fuels storage area that is used to support the mission of the base. In fall of 2013, the U.S. Geological Survey began a study in cooperation with the U.S. Air Force, Ellsworth Air Force Base, to estimate groundwater-flow direction, select locations for permanent monitoring wells, and install and sample monitoring wells for petroleum hydrocarbon compounds within Fuels Area C. Nine monitoring wells were installed for the study within Fuels Area C during November 4–7, 2014. Soil core samples were collected during installation of eight of the monitoring wells and analyzed for benzene, toluene, ethylbenzene, total xylenes, naphthalene,m- and p-xylene, o-xylene, and gasoline- and diesel-range organic compounds. Groundwater samples were collected from seven of the nine wells (two of the monitoring wells did not contain enough water to sample or were dry) during November 19–21, 2014, and analyzed for select physical properties, benzene, toluene, ethylbenzene, total xylenes, naphthalene, m- and p-xylene, o-xylene, and gasoline- and diesel-range organic compounds. This report describes the nine monitoring well locations and presents the soil- and groundwater-quality data collected in 2014 for this study.

  20. Alternate Fuels Combustion Research

    Science.gov (United States)

    1983-10-01

    nozzle using a vernier e. take photographs of carbon accumulation Carbon deposition checks were done for all fifteen fuels with simplex nozzle and six... micrometer valve and open cooler valve - set fuel circuit to bypass mode - start fuel pump & close cooler valve until abotit 100 psi is indicated on the...cooler gauge - open micrometer valve to desired fuel flow - start main air and switch on the refrigeration unit - allow both the fuel and air systems to

  1. Source apportionment of air pollution exposures of rural Chinese women cooking with biomass fuels

    Science.gov (United States)

    Huang, Wei; Baumgartner, Jill; Zhang, Yuanxun; Wang, Yuqin; Schauer, James J.

    2015-03-01

    Particulate matter (PM) from different sources may differentially affect human health. Few studies have assessed the main sources of personal exposure to PM and their contributions among residents of developing countries, where pollution sources differ from those in higher-income settings. 116 daily (24-h) personal PM2.5 exposure samples were collected among 81 women cooking with biomass fuels in two villages in rural Yunnan, China. The PM samples were analyzed for mass and chemical composition, including water-soluble organic carbon (WSOC), black carbon (BC), and molecular markers. We found black carbon, n-alkanes and levoglucosan dominated the most abundant fractions of the total measured species and average personal PM2.5 exposure was higher in winter than that in summer in both villages. The composition data were then analyzed using a positive matrix factorization (PMF) receptor model to identify the main PM emission sources contributing to women's exposures and to assess their spatial (between villages) and seasonal variation in our study setting. The 6-factor solution provided reasonably stable profiles and was selected for further analysis. Our results show that rural Chinese women cooking with biomass fuels are exposed to a variety of sources. The identified factors include wood combustion (41.1%), a cooking source (35.6%), a mobile source (12.6%), plant waxes (6.7%), pyrolysis combustion (3.0%), and secondary organic aerosols (SOA; 1.0%). The mean source contributions of the mobile source, cooking source, and wood combustion factor to PM2.5 exposure were significantly different between women living in the two study villages, whereas the mean SOA, wood combustion, and plant waxes factors differed seasonally. There was no relationship between source contributions and questionnaire-based measurements of source-specific exposures, implying that the impacts of source contributions on exposure are affected by complex spatial, temporal and behavioral patterns

  2. Indoor air pollution from solid fuels and risk of hypopharyngeal/laryngeal and lung cancers: a multicentric case-control study from India

    Energy Technology Data Exchange (ETDEWEB)

    Sapkota, A.; Gajalakshmi, V.; Jetly, D.H.; Roychowdhury, S.; Dikshit, R.P.; Brennan, P.; Hashibe, M.; Boffetta, P. [International Agency for Research on Cancer, Lyon (France)

    2008-04-15

    A recent monograph by the International Agency for Research on Cancer (IARC) has identified indoor air pollution from coal usage as a known human carcinogen, while that from biomass as a probable human carcinogen. Although as much as 74 of the Indian population relies on solid fuels for cooking, very little information is available on cancer risk associated with these fuels in India. Using data from a multicentric case control study of 799 lung and 1062 hypopharyngeal/laryngeal cancer cases, and 718 controls, we investigated indoor air pollution from various solid fuels as risk factors for these cancers in India. Compared with never users, individuals who always used coal had an increased risk of lung cancer (odds ratio (OR) 3.76, 95 confidence interval (CI) 1.648.63). Long duration of coal usage (50 years) was a risk factor for hypopharyngeal (OR 3.47, CI 0.9512.69) and laryngeal (OR 3.65, CI 1.1111.93) cancers. An increased risk of hypopharyngeal cancer was observed among lifelong users of wood (OR 1.62, CI 1.142.32), however this was less apparent among never-smokers. Increasing level of smokiness inside the home was associated with an increasing risk of hypopharyngeal and lung cancer (P-trend < 0.05). Our findings suggest that reducing indoor air pollution from solid fuels may contribute to prevention of these cancers in India, in addition to tobacco and alcohol control programs.

  3. Performance characteristics of part-load operations of a solid oxide fuel cell/gas turbine hybrid system using air-bypass valves

    Science.gov (United States)

    Yang, Jin Sik; Sohn, Jeong L.; Ro, Sung Tack

    In spite of the high-performance characteristics of a solid oxide fuel cell/gas turbine (SOFC/GT) hybrid system, it is difficult to maintain high-level performance under real application conditions, which generally require part-load operations. The efficiency loss of the SOFC/GT hybrid system under such conditions is closely related to that of the gas turbine. The power generated by the gas turbine in a hybrid system is much less than that generated by the SOFC, but its contribution to the efficiency of the system is important, especially under part-load conditions. Over the entire operating load profile of a hybrid system, the efficiency of the hybrid system can be maximized by increasing the contribution of power coming from the high efficiency component, namely the fuel cell. In this study, part-load control strategies using air-bypass valves are proposed, and their impact on the performance of an SOFC/GT hybrid system is discussed. It is found that air-bypass modes with control of the fuel supply help to overcome the limits of the part-load operation characteristics in air/fuel control modes, such as variable rotational speed control and variable inlet guide vane control.

  4. Electrochemical analysis of separators used in single-chamber, air-cathode microbial fuel cells

    KAUST Repository

    Wei, Bin

    2013-02-01

    Polarization, solution-separator, charge transfer, and diffusion resistances of clean and used separator electrode assemblies were examined in microbial fuel cells using current-voltage curves and electrochemical impedance spectroscopy (EIS). Current-voltage curves showed the total resistance was reduced at low cathode potentials. EIS results revealed that at a set cathode potential of 0.3 V diffusion resistance was predominant, and it substantially increased when adding separators. However, at a lower cathode potential of 0.1 V all resistances showed only slight differences with and without separators. Used separator electrode assemblies with biofilms had increased charge transfer and diffusion resistances (0.1 V) when one separator was used; however, charge transfer resistance increased, and diffusion resistance did not appreciably change with four separators. Adding a plastic mesh to compress the separators improved maximum power densities. These results show the importance of pressing separators against the cathode, and the adverse impacts of biofilm formation on electrochemical performance. © 2012 Elsevier Ltd. All Rights Reserved.

  5. Electricity generation using white and red wine lees in air cathode microbial fuel cells

    Science.gov (United States)

    Pepe Sciarria, Tommy; Merlino, Giuseppe; Scaglia, Barbara; D'Epifanio, Alessandra; Mecheri, Barbara; Borin, Sara; Licoccia, Silvia; Adani, Fabrizio

    2015-01-01

    Microbial fuel cell (MFC) is a useful biotechnology to produce electrical energy from different organic substrates. This work reports for the first time results of the application of single chamber MFCs to generate electrical energy from diluted white wine (WWL) and red wine (RWL) lees. Power obtained was of 8.2 W m-3 (262 mW m-2; 500 Ω) and of 3.1 W m-3 (111 mW m-2; 500Ω) using white and red wine lees, respectively. Biological processes lead to a reduction of chemical oxygen (TCOD) and biological oxygen demand (BOD5) of 27% and 83% for RWL and of 90% and 95% for WWL, respectively. These results depended on the degradability of organic compounds contained, as suggest by BOD5/TCOD of WWL (0.93) vs BOD5/TCOD of RWL (0.33), and to the high presence of polyphenols in RWL that inhibited the process. Coulombic efficiency (CE) of 15 ± 0%, for WWL, was in line with those reported in the literature for other substrates, i.e. CE of 14.9 ± 11.3%. Different substrates led to different microbial consortia, particularly at the anode. Bacterial species responsible for the generation of electricity, were physically connected to the electrode, where the direct electron transfer took place.

  6. Increasing power generation for scaling up single-chamber air cathode microbial fuel cells

    KAUST Repository

    Cheng, Shaoan

    2011-03-01

    Scaling up microbial fuel cells (MFCs) requires a better understanding the importance of the different factors such as electrode surface area and reactor geometry relative to solution conditions such as conductivity and substrate concentration. It is shown here that the substrate concentration has significant effect on anode but not cathode performance, while the solution conductivity has a significant effect on the cathode but not the anode. The cathode surface area is always important for increasing power. Doubling the cathode size can increase power by 62% with domestic wastewater, but doubling the anode size increases power by 12%. Volumetric power density was shown to be a linear function of cathode specific surface area (ratio of cathode surface area to reactor volume), but the impact of cathode size on power generation depended on the substrate strength (COD) and conductivity. These results demonstrate the cathode specific surface area is the most critical factor for scaling-up MFCs to obtain high power densities. © 2010 Elsevier Ltd.

  7. Hardware/Software Data Acquisition System for Real Time Cell Temperature Monitoring in Air-Cooled Polymer Electrolyte Fuel Cells

    Science.gov (United States)

    Bartolucci, Veronica

    2017-01-01

    This work presents a hardware/software data acquisition system developed for monitoring the temperature in real time of the cells in Air-Cooled Polymer Electrolyte Fuel Cells (AC-PEFC). These fuel cells are of great interest because they can carry out, in a single operation, the processes of oxidation and refrigeration. This allows reduction of weight, volume, cost and complexity of the control system in the AC-PEFC. In this type of PEFC (and in general in any PEFC), the reliable monitoring of temperature along the entire surface of the stack is fundamental, since a suitable temperature and a regular distribution thereof, are key for a better performance of the stack and a longer lifetime under the best operating conditions. The developed data acquisition (DAQ) system can perform non-intrusive temperature measurements of each individual cell of an AC-PEFC stack of any power (from watts to kilowatts). The stack power is related to the temperature gradient; i.e., a higher power corresponds to a higher stack surface, and consequently higher temperature difference between the coldest and the hottest point. The developed DAQ system has been implemented with the low-cost open-source platform Arduino, and it is completed with a modular virtual instrument that has been developed using NI LabVIEW. Temperature vs time evolution of all the cells of an AC-PEFC both together and individually can be registered and supervised. The paper explains comprehensively the developed DAQ system together with experimental results that demonstrate the suitability of the system. PMID:28698497

  8. Hardware/Software Data Acquisition System for Real Time Cell Temperature Monitoring in Air-Cooled Polymer Electrolyte Fuel Cells

    Directory of Open Access Journals (Sweden)

    Francisca Segura

    2017-07-01

    Full Text Available This work presents a hardware/software data acquisition system developed for monitoring the temperature in real time of the cells in Air-Cooled Polymer Electrolyte Fuel Cells (AC-PEFC. These fuel cells are of great interest because they can carry out, in a single operation, the processes of oxidation and refrigeration. This allows reduction of weight, volume, cost and complexity of the control system in the AC-PEFC. In this type of PEFC (and in general in any PEFC, the reliable monitoring of temperature along the entire surface of the stack is fundamental, since a suitable temperature and a regular distribution thereof, are key for a better performance of the stack and a longer lifetime under the best operating conditions. The developed data acquisition (DAQ system can perform non-intrusive temperature measurements of each individual cell of an AC-PEFC stack of any power (from watts to kilowatts. The stack power is related to the temperature gradient; i.e., a higher power corresponds to a higher stack surface, and consequently higher temperature difference between the coldest and the hottest point. The developed DAQ system has been implemented with the low-cost open-source platform Arduino, and it is completed with a modular virtual instrument that has been developed using NI LabVIEW. Temperature vs time evolution of all the cells of an AC-PEFC both together and individually can be registered and supervised. The paper explains comprehensively the developed DAQ system together with experimental results that demonstrate the suitability of the system.

  9. Hardware/Software Data Acquisition System for Real Time Cell Temperature Monitoring in Air-Cooled Polymer Electrolyte Fuel Cells.

    Science.gov (United States)

    Segura, Francisca; Bartolucci, Veronica; Andújar, José Manuel

    2017-07-09

    This work presents a hardware/software data acquisition system developed for monitoring the temperature in real time of the cells in Air-Cooled Polymer Electrolyte Fuel Cells (AC-PEFC). These fuel cells are of great interest because they can carry out, in a single operation, the processes of oxidation and refrigeration. This allows reduction of weight, volume, cost and complexity of the control system in the AC-PEFC. In this type of PEFC (and in general in any PEFC), the reliable monitoring of temperature along the entire surface of the stack is fundamental, since a suitable temperature and a regular distribution thereof, are key for a better performance of the stack and a longer lifetime under the best operating conditions. The developed data acquisition (DAQ) system can perform non-intrusive temperature measurements of each individual cell of an AC-PEFC stack of any power (from watts to kilowatts). The stack power is related to the temperature gradient; i.e., a higher power corresponds to a higher stack surface, and consequently higher temperature difference between the coldest and the hottest point. The developed DAQ system has been implemented with the low-cost open-source platform Arduino, and it is completed with a modular virtual instrument that has been developed using NI LabVIEW. Temperature vs time evolution of all the cells of an AC-PEFC both together and individually can be registered and supervised. The paper explains comprehensively the developed DAQ system together with experimental results that demonstrate the suitability of the system.

  10. Enhanced electrode-reducing rate during the enrichment process in an air-cathode microbial fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Ishii, Shun' ichi [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki (Japan). Bio-Medical Research Inst.; J. Craig Venter Institute, San Diego, CA (United States); Japan Society for the Promotion of Science (JSPS), Tokyo (Japan); Logan, Bruce E. [Penn State Univ., University Park, PA (United States). Dept. of Civil and Environmental Engineering; Sekiguchi, Yuji [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki (Japan). Bio-Medical Research Inst.

    2012-05-15

    The improvement in electricity generation during the enrichment process of a microbial consortium was analyzed using an air-cathode microbial fuel cell (MFC) repeatedly fed with acetate that was originally inoculated with sludge from an anaerobic digester. The anodic maximum current density produced by the anode biofilm increased from 0.12 mA/cm{sup 2} at day 28 to 1.12 mA/cm{sup 2} at day 105. However, the microbial cell density on the carbon cloth anode increased only three times throughout this same time period from 0.21 to 0.69 mg protein/cm{sup 2}, indicating that the biocatalytic activity of the consortium was also enhanced. The microbial activity was calculated to have a per biomass anode-reducing rate of 374 {mu}mol electron g protein{sup -1} min{sup -1} at day 28 and 1,002 {mu}mol electron g protein{sup -1} min{sup -1} at day 105. A bacterial community analysis of the anode biofilm revealed that the dominant phylotype, which was closely related to the known exoelectrogenic bacterium, Geobacter sulfurreducens, showed an increase in abundance from 32% to 70% of the total microbial cells. Fluorescent in situ hybridization observation also showed the increase of Geobacter-like phylotypes from 53% to 72%. These results suggest that the improvement of microbial current generation in microbial fuel cells is a function of both microbial cell growth on the electrode and changes in the bacterial community highly dominated by a known exoelectrogenic bacterium during the enrichment process. (orig.)

  11. Contribution of solid fuel, gas combustion, or tobacco smoke to indoor air pollutant concentrations in Irish and Scottish homes

    Energy Technology Data Exchange (ETDEWEB)

    Semple, S.; Garden, C. (Univ. of Aberdeen. Scottish Centre for Indoor Air, Div. of Applied Health Sciences (United Kingdom)); Galea, K.S.; Cowie, H.; Hurley, J.F.; Sanchez-Jimenez, A. (Scottish Centre for Indoor Air. Institute of Occupational Medicine, Edinburgh (United Kingdom)); Whelan, P.; Coggins, M. (National Univ. of Ireland Galway (Ireland)); Thorne, P.S. (Univ. of Iowa. Environmental Health Sciences Research Center, Iowa City, IA (United States)); Ayres, J.G. (Univ. of Birmingham. Institute of Occupational and Environmental Medicine (United Kingdom))

    2012-06-15

    There are limited data describing pollutant levels inside homes that burn solid fuel within developed country settings with most studies describing test conditions or the effect of interventions. This study recruited homes in Ireland and Scotland where open combustion processes take place. Open combustion was classified as coal, peat, or wood fuel burning, use of a gas cooker or stove, or where there is at least one resident smoker. Twenty-four-hour data on airborne concentrations of particulate matter <2.5 mu in size (PM{sub 2.5}), carbon monoxide (CO), endotoxin in inhalable dust and carbon dioxide (CO{sub 2}), together with 2-3 week averaged concentrations of nitrogen dioxide (NO{sub 2}) were collected in 100 houses during the winter and spring of 2009-2010. The geometric mean of the 24-h time-weighted-average (TWA) PM{sub 2.5} concentration was highest in homes with resident smokers (99 mu/m3- much higher than the WHO 24-h guidance value of 25 mu/m3). Lower geometric mean 24-h TWA levels were found in homes that burned coal (7 mu/m3) or wood (6 mu/m3) and in homes with gas cookers (7 mu/m3). In peat-burning homes, the average 24-h PM{sub 2.5} level recorded was 11 mu/m3. Airborne endotoxin, CO, CO{sub 2}, and NO{sub 2} concentrations were generally within indoor air quality guidance levels. (Author)

  12. Calculation and Experimental Validation of Pressure and Temperature Effects on COG-Air Fuel Mixtures

    Directory of Open Access Journals (Sweden)

    Jan Skrinsky

    2018-01-01

    Full Text Available COG have been widely used together with blast furnace gas and blast furnace oxygen gas in the steel industry in Moravian-Silesian region of Czech Republic. COG is a flammable and explosive substance. Most explosion characteristics published so far are valid for pure compounds and limited experimental conditions, mostly ambient. There have been no explosion characteristic exists for COG-air mixtures which cover industrial conditions up to 423 K. Experimental tests have been carried out in a 20-L closed explosion chamber adopted for the explosion tests. The element potential approach in the thermochemical equilibrium calculations applied in the Chemkin subroutine has been used for explosion pressure calculations. Different explosion characteristics have been reported in a range from 298 K up to 423 K and from 0.5 bar(a up to 1.0 bar(a.

  13. Biogas Laminar Burning Velocity and Flammability Characteristics in Spark Ignited Premix Combustion

    Science.gov (United States)

    Anggono, Willyanto; Wardana, I. N. G.; Lawes, M.; Hughes, K. J.; Wahyudi, Slamet; Hamidi, Nurkholis; Hayakawa, Akihiro

    2013-04-01

    Spherically expanding flames propagating at constant pressure were employed to determine the laminar burning velocity and flammability characteristics of biogas-air mixtures in premixed combustion to uncover the fundamental flame propagation characteristics of a new alternative and renewable fuel. The results are compared with those from a methane-air flame. Biogas is a sustainable and renewable fuel that is produced in digestion facilities. The composition of biogas discussed in this paper consists of 66.4% methane, 30.6% carbon dioxide and 3% nitrogen. Burning velocity was measured at various equivalence ratios (phi) using a photographic technique in a high pressure fan-stirred bomb, the initial condition being at room temperature and atmospheric pressure. The flame for methane-air mixtures propagates from phi=0.6 till phi=1.3. The flame at phi >= 1.4 does not propagate because the combustion reaction is quenched by the larger mass of fuel. At phiflame for biogas-air mixtures propagates in a narrower range, that is from phi=0.6 to phi=1.2. Different from the methane flame, the biogas flame does not propagate at phi>=1.3 because the heat absorbed by inhibitors strengthens the quenching effect by the larger mass of fuel. As in the methane flame, the biogas flame at phi<=0.5 does not propagate. This shows that the effect of inhibitors in extremely lean mixtures is small. Compared to a methane-air mixture, the flammability characteristic (flammable region) of biogas becomes narrower in the presence of inhibitors (carbon dioxide and nitrogen) and the presence of inhibitors causes a reduction in the laminar burning velocity. The inhibitor gases work more effectively at rich mixtures because the rich biogas-air mixtures have a higher fraction of carbon dioxide and nitrogen components compared to the lean biogas-air mixtures.

  14. Measurement of Absolute Hydroxyl Radical Concentration in Lean Fuel-Air Mixtures Excited by Nanosecond Pulsed Discharge.

    Science.gov (United States)

    Yin, Z.; Lempert, W. R.; Adamovich, I. V.

    2013-06-01

    The focus in plasma assisted combustion research has been on the evaluation of conventional plasma/combustion mechanisms in predicting oxidation and ignition processes initiated and/or sustained by non-equilibrium, nanosecond discharges. Accurate quantitative data such as temperature and species concentration are needed for assessing and improving numerical modeling. As an important intermediate species, the concentration of hydroxyl radical (OH) is very sensitive to the combustion environment (e.g., temperature, equivalence ratio), and therefore is of great interest to kinetic study. In this work, Laser-Induced Fluorescence (LIF) was used for time-resolved temperature and OH number density measurements in lean H_2-, CH_4-, C_2H_4-, and C_3H_8- air mixtures in a plasma flow reactor inside a tube furnace. The premixed fuel-air flow in the reactor, initially at T_0=500 K and P=100 torr, was excited by a burst of repetitive nanosecond electric pulses in a dielectric-barrier plane-to-plane geometry (˜28 kV peak voltage and ˜5 nsec pulse width, estimated 1.25 mJ/pulse coupled energy). Laser was timed to probe after the discharge burst was over to avoid strong plasma emission interference. Relative fluorescence signal was put on an absolute scale by calibrating against Rayleigh scattering signal in the same flow reactor. Experimental results were compared to predictions from a 0-D plasma/combustion chemistry model employing several well-established combustion mechanisms. 2-D temperature and OH concentration distributions in the discharge volume were obtained by planar LIF and was used to quantitatively evaluate plasma uniformity in the reactor. These results were used to determine the validity of the 0-D model. thanks

  15. Electricity generation and nutrients removal from high-strength liquid manure by air-cathode microbial fuel cells.

    Science.gov (United States)

    Lin, Hongjian; Wu, Xiao; Nelson, Chad; Miller, Curtis; Zhu, Jun

    2016-01-01

    Air-cathode microbial fuel cells (MFCs) are widely tested to recover electrical energy from waste streams containing organic matter. When high-strength wastewater, such as liquid animal manure, is used as a medium, inhibition on anode and cathode catalysts potentially impairs the effectiveness of MFC performance in power generation and pollutant removal. This study evaluated possible inhibitive effects of liquid swine manure components on MFC power generation, improved liquid manure-fed MFCs performance by pretreatment (dilution and selective adsorption), and modeled the kinetics of organic matter and nutrients removal kinetics. Parameters monitored included pH, conductivity, chemical oxygen demand (COD), volatile fatty acids (VFAs), total ammoniacal nitrogen (TAN), nitrite, nitrate, and phosphate concentrations. The removals of VFA and TAN were efficient, indicated by the short half-life times of 4.99 and 7.84 d, respectively. The mechanism for phosphate decrease was principally the salt precipitation on cathode, but the removal was incomplete after 42-d operation. MFC with an external resistor of 2.2 kΩ and fed with swine wastewater generated relatively small power (28.2 μW), energy efficiency (0.37%) and Coulombic efficiency (1.5%). Dilution of swine wastewater dramatically improved the power generation as the inhibitory effect was decreased. Zeolite and granular activated carbon were effective in the selective adsorption of ammonia or organic matter in swine wastewater, and so substantially improved the power generation, energy efficiency, and Coulombic efficiency. A smaller external resistor in the circuit was also observed to promote the organic matter degradation and thus to shorten the treatment time. Overall, air-cathode MFCs are promising for generating electrical power from livestock wastewater and meanwhile reducing the level of organic matter and nutrients.

  16. Effects of fractal grid on emissions in burner combustion by using fuel-water-air premix injector derived from biodiesel crude palm oil (CPO base

    Directory of Open Access Journals (Sweden)

    Suardi Mirnah

    2017-01-01

    Full Text Available The alternative fuel is attracted good attention from worldwide especially for renewable and prevention energy such as biodiesel. Biodiesel is one of the hydrocarbon fuels and it has potential for external combustion. As one of the different solutions to these problems, rapid mixing of biodiesel-water-air technique is one of the most significant approaches to improve the combustion and reduce the emissions. The gas emission can be reduced by two methods. First is by improving an injector with fractal and the other is by using a biodiesel-water mixture as an alternative fuel. Mixing of water with fuel in the combustion process is a low cost and effective way. This research used biodiesel Crude Palm Oil (CPO as fuels in which blended with diesel. This study investigated the effects of water content and equivalence ratio on emissions with the rapid mixing injector. Fuels used are diesel, CPO5, CPO10 and CPO15 and the exhausts gaseous tested are CO, CO2, HC and NOX. The gas emissions processes are tested by using the gas analyzer. In this research, water premix of percentage up to 15vol% and blending biodiesel ratio was varied from 5vom% - 15vol%. The result shows that increasing of water content will effected decrement of CO, CO2 and HC emissions but increasing the NOX emissions.

  17. Continuous electricity generation in stacked air cathode microbial fuel cell treating domestic wastewater.

    Science.gov (United States)

    Choi, Jeongdong; Ahn, Youngho

    2013-11-30

    This study examined the continuous performance of air cathode MFC stacks for domestic wastewater treatments at two different temperatures (23 ± 3 °C and 30 ± 1 °C) and organic loading rates to determine the effects of the electrode connection and hydraulic flow mode on the stack performance. The power density and process stability were affected significantly by the electrode connection type, flow mode, and operating parameters. The parallel electrode connection system (in series flow mode) had benefits of COD removal, Coulombic efficiency and maximal power density due to the higher stability of the ORP in overall cells. The highest power density of 420 mW/m(2) (12.8 W/m(3)) was achieved in series flow and parallel connection mode at an organic loading rate of 25.6 g COD/L-d (HRT of 0.33 h) under mesophilic conditions, achieving a COD removal of 44%. The results highlight the importance of prefermentation process in the application of a stacked MFC for an actual wastewater treatment. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. SENSOR FOR INDIVIDUAL BURNER CONTROL OF FIRING RATE, FUEL-AIR RATIO, AND COAL FINENESS CORRELATION

    Energy Technology Data Exchange (ETDEWEB)

    Wayne Hill; Roger Demler; Robert G. Mudry

    2004-10-01

    Instrumentation difficulties encountered in the previous reporting period were addressed early in this reporting period, resulting in a new instrumentation configuration that appears to be free of the noise issues found previously. This permitted the collection of flow calibration data to begin. The first issues in question are the effects of the type and location of the transducer mount. Data were collected for 15 different transducer positions (upstream and downstream of an elbow in the pipe), with both a stud mount and a magnetic transducer mount, for each of seven combinations of air and coal flow. Analysis of these data shows that the effects of the transducer mount type and location on the resulting dynamics are complicated, and not easily captured in a single analysis. To maximize the practical value of the calibration data, further detailed calibration data will be collected with both the magnetic and stud mounts, but at a single mounting location just downstream of a pipe elbow. This testing will be performed in the Coal Flow Test Facility in the next reporting period. The program progress in this reporting period was sufficient to put us essentially back on schedule.

  19. Long-term performance of activated carbon air cathodes with different diffusion layer porosities in microbial fuel cells

    KAUST Repository

    Zhang, Fang

    2011-08-01

    Activated carbon (AC) air-cathodes are inexpensive and useful alternatives to Pt-catalyzed electrodes in microbial fuel cells (MFCs), but information is needed on their long-term stability for oxygen reduction. AC cathodes were constructed with diffusion layers (DLs) with two different porosities (30% and 70%) to evaluate the effects of increased oxygen transfer on power. The 70% DL cathode initially produced a maximum power density of 1214±123mW/m 2 (cathode projected surface area; 35±4W/m 3 based on liquid volume), but it decreased by 40% after 1 year to 734±18mW/m 2. The 30% DL cathode initially produced less power than the 70% DL cathode, but it only decreased by 22% after 1 year (from 1014±2mW/m 2 to 789±68mW/m 2). Electrochemical tests were used to examine the reasons for the degraded performance. Diffusion resistance in the cathode was found to be the primary component of the internal resistance, and it increased over time. Replacing the cathode after 1 year completely restored the original power densities. These results suggest that the degradation in cathode performance was due to clogging of the AC micropores. These findings show that AC is a cost-effective material for oxygen reduction that can still produce ~750mW/m 2 after 1 year. © 2011 Elsevier B.V.

  20. Long-Term Performance of Chemically and Physically Modified Activated Carbons in Air Cathodes of Microbial Fuel Cells

    KAUST Repository

    Zhang, Xiaoyuan

    2014-07-31

    © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Activated carbon (AC) is a low-cost and effective catalyst for oxygen reduction in air cathodes of microbial fuel cells (MFCs), but its performance must be maintained over time. AC was modified by three methods: 1)pyrolysis with iron ethylenediaminetetraacetic acid (AC-Fe), 2)heat treatment (AC-heat), and 3)mixing with carbon black (AC-CB). The maximum power densities after one month with these AC cathodes were 35% higher with AC-Fe (1410±50mW m-2) and AC-heat (1400±20mW m-2), and 16% higher with AC-CB (1210±30mW m-2) than for plain AC (1040±20mW m-2), versus 1270±50mW m-2 for a Pt control. After 16months, the Pt cathodes produced only 250±10mW m-2. However, the AC-heat and AC-CB cathodes still produced 960-970mW m-2, whereas plain AC produced 860±60mW m-2. The performance of the AC cathodes was restored to >85% of the initial maximum power densities by cleaning with a weak acid solution. Based on cost considerations among the AC materials, AC-CB appears to be the best choice for long-term performance.

  1. Nonlinear torque and air-to-fuel ratio control of spark ignition engines using neuro-sliding mode techniques.

    Science.gov (United States)

    Huang, Ting; Javaherian, Hossein; Liu, Derong

    2011-06-01

    This paper presents a new approach for the calibration and control of spark ignition engines using a combination of neural networks and sliding mode control technique. Two parallel neural networks are utilized to realize a neuro-sliding mode control (NSLMC) for self-learning control of automotive engines. The equivalent control and the corrective control terms are the outputs of the neural networks. Instead of using error backpropagation algorithm, the network weights of equivalent control are updated using the Levenberg-Marquardt algorithm. Moreover, a new approach is utilized to update the gain of corrective control. Both modifications of the NSLMC are aimed at improving the transient performance and speed of convergence. Using the data from a test vehicle with a V8 engine, we built neural network models for the engine torque (TRQ) and the air-to-fuel ratio (AFR) dynamics and developed NSLMC controllers to achieve tracking control. The goal of TRQ control and AFR control is to track the commanded values under various operating conditions. From simulation studies, the feasibility and efficiency of the approach are illustrated. For both control problems, excellent tracking performance has been achieved.

  2. A small-scale air-cathode microbial fuel cell for on-line monitoring of water quality.

    Science.gov (United States)

    Di Lorenzo, Mirella; Thomson, Alexander R; Schneider, Kenneth; Cameron, Petra J; Ieropoulos, Ioannis

    2014-12-15

    The heavy use of chemicals for agricultural, industrial and domestic purposes has increased the risk of freshwater contamination worldwide. Consequently, the demand for efficient new analytical tools for on-line and on-site water quality monitoring has become particularly urgent. In this study, a small-scale single chamber air-cathode microbial fuel cell (SCMFC), fabricated by rapid prototyping layer-by-layer 3D printing, was tested as a biosensor for continuous water quality monitoring. When acetate was fed as the rate-limiting substrate, the SCMFC acted as a sensor for chemical oxygen demand (COD) in water. The linear detection range was 3-164 ppm, with a sensitivity of 0.05 μA mM(-1) cm(-2) with respect to the anode total surface area. The response time was as fast as 2.8 min. At saturating acetate concentrations (COD>164 ppm), the miniature SCMFC could rapidly detect the presence of cadmium in water with high sensitivity (0.2 μg l(-1) cm(-2)) and a lower detection limit of only 1 μg l(-1). The biosensor dynamic range was 1-25 μg l(-1). Within this range of concentrations, cadmium affected only temporarily the electroactive biofilm at the anode. When the SCMFCs were again fed with fresh wastewater and no pollutant, the initial steady-state current was recovered within 12 min. Copyright © 2014. Published by Elsevier B.V.

  3. Development and characterization of a novel air-breathing micro direct methanol fuel cell stack for portable applications

    Science.gov (United States)

    Liu, Xiaowei; Zhang, Bo; Zhang, Yufeng; He, Hong; Li, Jianmin; Wang, Shibo; Yuan, Zhenyu; Deng, Huichao

    2010-10-01

    An air-breathing 10-cell micro direct methanol fuel cell (µDMFC) stack with four anode feeding patterns is designed, fabricated and tested. For a better understanding of the operational characteristics of both the single cell and the stack, a two-dimensional numerical model is established and calculated. Employing micro-stamping technology, the current collectors of each single cell are microfabricated on the stainless steel plate with a thickness of 300 µm. The single µDMFC is first tested under various operating parameters. On the basis of the simulation and experimental observation of the single cell performance, the µDMFC stack performance is thoroughly analyzed with different anode feeding patterns. The results indicate that the µDMFC stack with pattern B can ensure the uniform performance of each single cell and generate the highest power output. With pattern B, further experiments are carried out to investigate the influence of the anode flow rate on the stack performance. As a result, the µDMFC stack achieves the best performance with the maximum power density of about 24.75 mW cm-2 at 5.0 ml min-1. Finally, the stack is successfully applied to two electronic devices of different rated power.

  4. Theoretical and experimental validation study on automotive air-conditioning based on heat pipe and LNG cold energy for LNG-fueled heavy vehicles

    Science.gov (United States)

    Deng, Dong; Cheng, Jiang-ping; Zhang, Sheng-chang; Ge, Fang-gen

    2017-08-01

    As a clean fuel, LNG has been used in heavy vehicles widely in China. Before reaching the engine for combustion, LNG store in a high vacuum multi-layer thermal insulation tank and need to be evaporated from its cryogenic state to natural gas. During the evaporation, the available cold energy of LNG has been calculated. The concept has been proposed that the separated type heat pipe technology is employed to utilize the available cold energy for automotive air-conditioning. The experiment has been conducted to validate the proposal. It is found that it is feasible to use the separated type heat pipe to convey the cold energy from LNG to automotive air-conditioning. And the cooling capacity of the automotive air-conditioning increase with the LNG consumption and air flow rate increasing.

  5. Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air or Liquid Heat Integration

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Sahlin, Simon Lennart; Justesen, Kristian Kjær

    The present work describes the ongoing development of high temperature PEM fuel cell systems fuelled by steam reformed methanol. Various fuel cell system solutions exist, they mainly differ depending on the desired fuel used. High temperature PEM (HTPEM) fuel cells offer the possibility of using...... liquid fuels such as methanol, due to the increased robustness of operating at higher temperatures (160-180oC). Using liquid fuels such as methanol removes the high volume demands of compressed hydrogen storages, simplifies refueling, and enables the use of existing fuel distribution systems. The liquid...... methanol is converted to a hydrogen rich gas with CO2 trace amounts of CO, the increased operating temperatures allow the fuel cell to tolerate much higher CO concentrations than Nafion-based membranes. The increased tolerance to CO also enables the use of reformer systems with less hydrogen cleaning steps...

  6. 78 FR 29815 - Control of Air Pollution From Motor Vehicles: Tier 3 Motor Vehicle Emission and Fuel Standards

    Science.gov (United States)

    2013-05-21

    ... Butane manufacturers. ] Industry 325193 2869 Ethyl alcohol manufacturing. Industry 211112 1321 Natural... manufacturing. Industry 486910 4613 Natural gas liquids pipelines, refined petroleum products pipelines... economy. Sulfur in the fuel quickly causes the fuel economy benefits of lean- burn technologies to...

  7. Occupational Jet Fuel Exposure and Invasive Cancer Occurrence in the United States Air Force, 1989-2003

    National Research Council Canada - National Science Library

    D'Mello, Tiffany A; Yamane, Grover K

    2007-01-01

    .... Based on job descriptions, et fuel exposure was categorized as high, moderate or low. Conditional logistic regressions were used to calculate odds ratios for fuel exposure with cancer occurrence as the primary outcome of interest...

  8. U.S. Light-duty Vehicle Air Conditioning Fuel Use and the Impact of Four Solar/Thermal Control Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Rugh, John P [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Kekelia, Bidzina [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Kreutzer, Cory J [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Titov, Eugene V [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-28

    The U.S. uses 7.6 billion gallons of fuel per year for vehicle air conditioning (A/C), equivalent to 5.7 percent of the total national light-duty vehicle (LDV) fuel use. This equates to 30 gallons/year per vehicle, or 23.5 grams (g) of carbon dioxide (CO2) per mile, for an average U.S. vehicle. A/C is a significant contribution to national fuel use; therefore, technologies that reduce A/C loads may reduce operational costs, A/C fuel use, and CO2 emissions. Since A/C is not operated during standard EPA fuel economy testing protocols, EPA provides off-cycle credits to encourage OEMs to implement advanced A/C technologies that reduce fuel use in the real world. NREL researchers assessed thermal/solar off-cycle credits available in the U.S. Environmental Protection Agency's (EPA's) Final Rule for Model Year 2017 and Later Light-Duty Vehicle Greenhouse Gas Emissions and Corporate Average Fuel Economy. Credits include glazings, solar reflective paint, and passive and active cabin ventilation. Implementing solar control glass reduced CO2 emissions by 2.0 g/mi, and solar reflective paint resulted in a reduction of 0.8 g/mi. Active and passive ventilation strategies only reduced emissions by 0.1 and 0.2 g/mi, respectively. The national-level analysis process is powerful and general; it can be used to determine the impact of a wide range of new vehicle thermal technologies on fuel use, EV range, and CO2 emissions.

  9. Simulation of an air conditioning absorption refrigeration system in a co-generation process combining a proton exchange membrane fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Pilatowsky, I.; Gamboa, S.A.; Rivera, W. [Centro de Investigacion en Energia - UNAM, Temixco, Morelos (Mexico); Romero, R.J. [Centro de Investigacion en Ingenieria y Ciencias Aplicadas - UAEM, Cuernavaca, Morelos (Mexico); Isaza, C.A. [Universidad Pontificia Bolivariana, Medellin (Colombia). Instituto de Energia y Termodinamica; Sebastian, P.J. [Centro de Investigacion en Energia - UNAM, Temixco, Morelos (Mexico); Cuerpo Academico de Energia y Sustentabilidad-UP Chiapas, Tuxtla Gutierrez, Chiapas (Mexico); Moreira, J. [Cuerpo Academico de Energia y Sustentabilidad-UP Chiapas, Tuxtla Gutierrez, Chiapas (Mexico)

    2007-10-15

    In this work, a computer simulation program was developed to determine the optimum operating conditions of an air conditioning system during the co-generation process. A 1 kW PEMFC was considered in this study with a chemical/electrical theoretical efficiency of 40% and a thermal efficiency of 30% applying an electrical load of 100%. A refrigeration-absorption cycle (RAC) operating with monomethylamine-water solutions (MMA-WS), with low vapor generation temperatures (up to 80 C) is proposed in this work. The computer simulation was based on the refrigeration production capacity at the maximum power capacity of the PEMFC. Heat losses between the fuel cell and the absorption air conditioning system at standard operating conditions were considered to be negligible. The results showed the feasibility of using PEMFC for cooling, increasing the total efficiency of the fuel cell system. (author)

  10. Tracer-based laser-induced fluorescence measurement technique for quantitative fuel/air-ratio measurements in a hydrogen internal combustion engine.

    Science.gov (United States)

    Blotevogel, Thomas; Hartmann, Matthias; Rottengruber, Hermann; Leipertz, Alfred

    2008-12-10

    A measurement technique for the quantitative investigation of mixture formation processes in hydrogen internal combustion engines (ICEs) has been developed using tracer-based laser-induced fluorescence (TLIF). This technique can be employed to fired and motored engine operation. The quantitative TLIF fuel/air-ratio results have been verified by means of linear Raman scattering measurements. Exemplary results of the simultaneous investigation of mixture formation and combustion obtained at an optical accessible hydrogen ICE are shown.

  11. WHO indoor air quality guidelines on household fuel combustion: Strategy implications of new evidence on interventions and exposure-risk functions

    Science.gov (United States)

    Bruce, Nigel; Pope, Dan; Rehfuess, Eva; Balakrishnan, Kalpana; Adair-Rohani, Heather; Dora, Carlos

    2015-04-01

    Background: 2.8 billion people use solid fuels as their primary cooking fuel; the resulting high levels of household air pollution (HAP) were estimated to cause more than 4 million premature deaths in 2012. The people most affected are among the world's poorest, and past experience has shown that securing adoption and sustained use of effective, low-emission stove technologies and fuels in such populations is not easy. Among the questions raised by these challenges are (i) to what levels does HAP exposure need to be reduced in order to ensure that substantial health benefits are achieved, and (ii) what intervention technologies and fuels can achieve the required levels of HAP in practice? New WHO air quality guidelines are being developed to address these issues. Aims: To address the above questions drawing on evidence from new evidence reviews conducted for the WHO guidelines. Methods: Discussion of key findings from reviews covering (i) systematic reviews of health risks from HAP exposure, (ii) newly developed exposure-response functions which combine combustion pollution risk evidence from ambient air pollution, second-hand smoke, HAP and active smoking, and (iii) a systematic review of the impacts of solid fuel and clean fuel interventions on kitchen levels of, and personal exposure to, PM2.5 and carbon monoxide (CO). Findings: Evidence on health risks from HAP suggest that controlling this exposure could reduce the risk of multiple child and adult health outcomes by 20-50%. The new integrated exposure-response functions (IERs) indicate that in order to secure these benefits, HAP levels require to be reduced to the WHO IT-1 annual average level (35 μg/m3 PM2.5), or below. The second review found that, in practice, solid fuel 'improved stoves' led to large percentage and absolute reductions, but post-intervention kitchen levels were still very high, at several hundreds of μg/m3 of PM2.5, although most solid fuel stove types met the WHO 24-hr average guideline

  12. Numerical study of turbulent normal diffusion flame CH4-air stabilized by coaxial burner

    Directory of Open Access Journals (Sweden)

    Riahi Zouhair

    2013-01-01

    Full Text Available The practical combustion systems such as combustion furnaces, gas turbine, engines, etc. employ non-premixed combustion due to its better flame stability, safety, and wide operating range as compared to premixed combustion. The present numerical study characterizes the turbulent flame of methane-air in a coaxial burner in order to determine the effect of airflow on the distribution of temperature, on gas consumption and on the emission of NOx. The results in this study are obtained by simulation on FLUENT code. The results demonstrate the influence of different parameters on the flame structure, temperature distribution and gas emissions, such as turbulence, fuel jet velocity, air jet velocity, equivalence ratio and mixture fraction. The lift-off height for a fixed fuel jet velocity is observed to increase monotonically with air jet velocity. Temperature and NOx emission decrease of important values with the equivalence ratio, it is maximum about the unity.

  13. Commercial aviation alternative fuels initiative

    Science.gov (United States)

    2010-04-22

    This presentation looks at alternative fuels to enhance environmental stability, reduction of greenhouse gas emissions, air quality benefits (e.g., SOx and PM), fuel supply stability, and fuel price stability.

  14. Investigations of a Combustor Using a 9-Point Swirl-Venturi Fuel Injector: Recent Experimental Results

    Science.gov (United States)

    Hicks, Yolanda R.; Heath, Christopher M.; Anderson, Robert C.; Tacina, Kathleen M.

    2012-01-01

    This paper explores recent results obtained during testing in an optically-accessible, JP8-fueled, flame tube combustor using baseline Lean Direct Injection (LDI) research hardware. The baseline LDI geometry has nine fuel/air mixers arranged in a 3 x 3 array. Results from this nine-element array include images of fuel and OH speciation via Planar Laser-Induced Fluorescence (PLIF), which describe fuel spray pattern and reaction zones. Preliminary combustion temperatures derived from Stokes/Anti-Stokes Spontaneous Raman Spectroscopy are also presented. Other results using chemiluminescence from major combustion radicals such as CH* and C2* serve to identify the primary reaction zone, while OH PLIF shows the extent of reaction further downstream. Air and fuel velocities and fuel drop size results are also reported.

  15. Orbital velocity

    OpenAIRE

    Modestino, Giuseppina

    2016-01-01

    The trajectory and the orbital velocity are determined for an object moving in a gravitational system, in terms of fundamental and independent variables. In particular, considering a path on equipotential line, the elliptical orbit is naturally traced, verifying evidently the keplerian laws. The case of the planets of the solar system is presented.

  16. US EPA, US DOT, California’s Air Resources Board Issue Draft Technical Assessment Report of Greenhouse Gas Emissions and Fuel Economy Standards for Model Year 2022-2025 Cars and Light Trucks

    Science.gov (United States)

    EPA News Release: US EPA, US DOT, California’s Air Resources Board Issue Draft Technical Assessment Report of Greenhouse Gas Emissions and Fuel Economy Standards for Model Year 2022-2025 Cars and Light Trucks

  17. Household air pollution from use of cooking fuel and under-five mortality: The role of breastfeeding status and kitchen location in Pakistan.

    Directory of Open Access Journals (Sweden)

    Sabrina Naz

    Full Text Available Household air pollution (HAP mainly from cooking fuel is one of the major causes of respiratory illness and deaths among young children in low and middle-income countries like Pakistan. This study investigates for the first time the association between HAP from cooking fuel and under-five mortality using the 2013 Pakistan Demographic and Health Survey (PDHS data. Multi-level logistic regression models were used to examine the association between HAP and under-five mortality in a total of 11,507 living children across four age-groups (neonatal aged 0-28 days, post-neonatal aged 1-11 months, child aged 12-59 months and under-five aged 0-59 months. Use of cooking fuel was weakly associated with total under-five mortality (OR = 1.22, 95%CI = 0.92-1.64, P = 0.170, with stronger associations evident for sub-group analyses of children aged 12-59 months (OR = 1.98, 95%CI = 0.75-5.25, P = 0.169. Strong associations between use of cooking fuel and mortality were evident (ORs >5 in those aged 12-59 months for households without a separate kitchen using polluting fuels, and in children whose mother never breastfed. The results of this study suggest that HAP from cooking fuel is associated with a modest increase in the risk of death among children under five years of age in Pakistan, but particularly in those aged 12-59 months, and those living in poorer socioeconomic conditions. To reduce exposure to cooking fuel which is a preventable determinant of under-five mortality in Pakistan, the challenge remains to promote behavioural interventions such as breastfeeding in infancy period, keeping young children away from the cooking area, and improvements in housing and kitchen design.

  18. Comparing hydrogen and hydrocarbon booster fuels

    Science.gov (United States)

    Martin, James A.

    1988-01-01

    The present evaluation of the consequences of hydrogen and hydrocarbon fuels as the basis of launch vehicle booster rocket-stage performance notes that hydrocarbon fuels lead to lower vehicle dry mass, for low-velocity requirements, while hydrogen fuel furnishes lower dry mass. Vehicles employing both types of fuel attempt to take advantage of the low intercept and slope of hydrocarbon fuel at low velocity, and subsequently, of the slope of the hydrogen curves at higher velocities.

  19. Effect of Sodium Dodecyl Sulfate (SDS) and Tween 80 on Cell Viability in an Air-Cathode Microbial Fuel Cell

    KAUST Repository

    Fregoso, Luisa

    2011-07-01

    Microbial fuel cells (MFCs) generate current via electrochemical reactions produced by bacteria attached to the anode that oxidize organic matter. Due to their high volume use in household products, some concentration of surfactant will reach wastewater treatment plants. The average surfactant concentration in wastewater ranges from 10 to 20 mg L-1, and up to 300 mg L-1, for domestic and industrial wastewaters, respectively. This study aimed to demonstrate the feasibility of enhancing power production by adding Tween 80 and SDS surfactants to air-cathode MFCs, and their effect in cell viability at the anodic biofilm. In order to analyze the effect of anionic and nonionic surfactants in MFCs performance, eight MFCs were spiked with two types of surfactants, the anionic surfactant sodium dodecyl sulfate (SDS) and the nonionic surfactant Tween® 80 at two different concentrations 10 and 100 mg L-1. Cell viability at the anodic biofilms was examined using the LIVE/DEAD BacLight viability assay and images were visualized with a confocal laser scanning microscope. The electrochemical results demonstrate that, for an air-cathode MFC operating on 1 g L-1 acetate in a fed-batch mode, reactors where SDS was added show a lower overall performance, maximum PD of 544 mW m-2, CE of 12.3%, Rint of 322 Ω (10 mg L-1) and maximum PD of 265 mW m-2, CE of 9.4%, Rint of 758 Ω (100 mg L-1). Reactors where Tween 80 was added show quite stable performance, maximum PD of 623 mW m-2, CE of 15.4%, Rint of 216 Ω (10 mg L-1) and maximum PD of 591 mW m-2, CE of 10.8%, Rint of 279 Ω (100 mg L-1), compared with reactors operating at only acetate as a substrate, maximum PD of 574 mW m-2. Confocal microscopy images confirm this observation and biofilm viability appeared severely compromised in SDS reactors, especially at high concentrations. This study has opened up a whole new research area in determining which types of surfactants are toxic to the anodic biofilm and to further investigate the

  20. Nitrogen removal in a single-chamber microbial fuel cell with nitrifying biofilm enriched at the air cathode

    KAUST Repository

    Yan, Hengjing

    2012-05-01

    Nitrogen removal is needed in microbial fuel cells (MFCs) for the treatment of most waste streams. Current designs couple biological denitrification with side-stream or combined nitrification sustained by upstream or direct aeration, which negates some of the energy-saving benefits of MFC technology. To achieve simultaneous nitrification and denitrification, without extra energy input for aeration, the air cathode of a single-chamber MFC was pre-enriched with a nitrifying biofilm. Diethylamine-functionalized polymer (DEA) was used as the Pt catalyst binder on the cathode to improve the differential nitrifying biofilm establishment. With pre-enriched nitrifying biofilm, MFCs with the DEA binder had an ammonia removal efficiency of up to 96.8% and a maximum power density of 900 ± 25 mW/m 2, compared to 90.7% and 945 ± 42 mW/m 2 with a Nafion binder. A control with Nafion that lacked nitrifier pre-enrichment removed less ammonia and had lower power production (54.5% initially, 750 mW/m 2). The nitrifying biofilm MFCs had lower Coulombic efficiencies (up to 27%) than the control reactor (up to 36%). The maximum total nitrogen removal efficiency reached 93.9% for MFCs with the DEA binder. The DEA binder accelerated nitrifier biofilm enrichment on the cathode, and enhanced system stability. These results demonstrated that with proper cathode pre-enrichment it is possible to simultaneously remove organics and ammonia in a single-chamber MFC without supplemental aeration. © 2012 Elsevier Ltd.

  1. The relationship between air pollution, fossil fuel energy consumption, and water resources in the panel of selected Asia-Pacific countries.

    Science.gov (United States)

    Rafindadi, Abdulkadir Abdulrashid; Yusof, Zarinah; Zaman, Khalid; Kyophilavong, Phouphet; Akhmat, Ghulam

    2014-10-01

    The objective of the study is to examine the relationship between air pollution, fossil fuel energy consumption, water resources, and natural resource rents in the panel of selected Asia-Pacific countries, over a period of 1975-2012. The study includes number of variables in the model for robust analysis. The results of cross-sectional analysis show that there is a significant relationship between air pollution, energy consumption, and water productivity in the individual countries of Asia-Pacific. However, the results of each country vary according to the time invariant shocks. For this purpose, the study employed the panel least square technique which includes the panel least square regression, panel fixed effect regression, and panel two-stage least square regression. In general, all the panel tests indicate that there is a significant and positive relationship between air pollution, energy consumption, and water resources in the region. The fossil fuel energy consumption has a major dominating impact on the changes in the air pollution in the region.

  2. Fuel density effect on near nozzle flow field in small laminar coflow diffusion flames

    KAUST Repository

    Xiong, Yuan

    2015-01-01

    Flow characteristics in small coflow diffusion flames were investigated with a particular focus on the near-nozzle region and on the buoyancy force exerted on fuels with densities lighter and heavier than air (methane, ethylene, propane, and n-butane). The flow-fields were visualized through the trajectories of seed particles. The particle image velocimetry technique was also adopted for quantitative velocity field measurements. The results showed that the buoyancy force exerted on the fuel as well as on burnt gas significantly distorted the near-nozzle flow-fields. In the fuels with densities heavier than air, recirculation zones were formed very close to the nozzle, emphasizing the importance of the relative density of the fuel to that of the air on the flow-field. Nozzle heating influenced the near-nozzle flow-field particularly among lighter fuels (methane and ethylene). Numerical simulations were also conducted, focusing specifically on the effect of specifying inlet boundary conditions for fuel. The results showed that a fuel inlet boundary with a fully developed velocity profile for cases with long tubes should be specified inside the fuel tube to permit satisfactory prediction of the flow-field. The calculated temperature fields also indicated the importance of the selection of the location of the inlet boundary, especially in testing various combustion models that include soot in small coflow diffusion flames. © 2014 The Combustion Institute.

  3. An Investigation of the Performance of a Ribbon and Small Planar Magnetic Transducer, Made for Use in Air, as an Underwater Acoustic Velocity Sensor

    Science.gov (United States)

    2016-09-01

    an education at Naval Postgraduate School. I want to thank my children, Joaquin, Rosario , and Emilia, for enduring long hours without the company of...Hoses and clamps • Two (2) plastic containers 2 m 87 1. The vacuum pump evacuates air from the green topped plastic container. 2. Air is

  4. Apparatus and method for mixing fuel in a gas turbine nozzle

    Science.gov (United States)

    Johnson, Thomas Edward; Ziminsky, Willy Steve; Berry, Jonathan Dwight

    2014-08-12

    A nozzle includes a fuel plenum and an air plenum downstream of the fuel plenum. A primary fuel channel includes an inlet in fluid communication with the fuel plenum and a primary air port in fluid communication with the air plenum. Secondary fuel channels radially outward of the primary fuel channel include a secondary fuel port in fluid communication with the fuel plenum. A shroud circumferentially surrounds the secondary fuel channels. A method for mixing fuel and air in a nozzle prior to combustion includes flowing fuel to a fuel plenum and flowing air to an air plenum downstream of the fuel plenum. The method further includes injecting fuel from the fuel plenum through a primary fuel passage, injecting fuel from the fuel plenum through secondary fuel passages, and injecting air from the air plenum through the primary fuel passage.

  5. Self-sustaining fuel purging fuel injection system

    Energy Technology Data Exchange (ETDEWEB)

    Bradley, J.R.; Koblish, T.R.

    1994-01-11

    A fuel injector system for a combustor of a gas turbine engine includes first and second fuel injectors rendered operative to discharge fuel to the combustor during a high power regime of engine operation and rendered non-operative during a lower power regime of engine operation. The first and second fuel injectors include respective first and second fuel discharge passages in fuel flow communication to one another and to the combustor via associated fuel discharge lips to sustain a flame region. The first and second fuel injectors are operatively associated with respective first and second air discharge means having air discharge lips for discharging air to the combustor for sustaining the flame region therein. When the fuel injectors are rendered non-operative, different pneumatic pressures are established at the fuel discharge lips to purge fuel from the fuel injectors to the combustor. 26 figs.

  6. Predicting vehicle fuel consumption patterns using floating vehicle data.

    Science.gov (United States)

    Du, Yiman; Wu, Jianping; Yang, Senyan; Zhou, Liutong

    2017-09-01

    The status of energy consumption and air pollution in China is serious. It is important to analyze and predict the different fuel consumption of various types of vehicles under different influence factors. In order to fully describe the relationship between fuel consumption and the impact factors, massive amounts of floating vehicle data were used. The fuel consumption pattern and congestion pattern based on large samples of historical floating vehicle data were explored, drivers' information and vehicles' parameters from different group classification were probed, and the average velocity and average fuel consumption in the temporal dimension and spatial dimension were analyzed respectively. The fuel consumption forecasting model was established by using a Back Propagation Neural Network. Part of the sample set was used to train the forecasting model and the remaining part of the sample set was used as input to the forecasting model. Copyright © 2017. Published by Elsevier B.V.

  7. Particle velocity measurements in HVOF and APS systems

    Energy Technology Data Exchange (ETDEWEB)

    Knight, R.; Smith, R.W.; Xiao, Z. [Drexel Univ., Philadelphia, PA (United States); Hoffman, T.T. [Control Vision, Inc., Idaho Falls, ID (United States)

    1994-12-31

    Production of reliable, repeatable coatings requires precise control of the process used to deposit them. Significant advances have recently been made in controlling the inputs to thermal spray processes, however, much work remains to be done to control process outputs and to correlate these with coatings characteristics. Thermal spray processes comprise the heating/melting, acceleration, impact, rapid solidification and incremental build-up of a large number of individual particles. Particle velocity is a key process parameter in determining coating properties such as density/porosity, bond strength and residual stress. Laser Stroboscopy and optical image analysis techniques have been used to image particles traveling in high velocity oxy-fuel (HVOF) and air plasma spray (APS) jets. Results indicate that these techniques can be used to measure particle velocity, trajectory and velocity distribution(s) in thermal spray jets. mean particle velocities of {approximately}400 m/s and {approximately}100 m/s have been measured for HVOF and APS respectively.

  8. Performance of direct ethanol fuel cells as function of using of compressed air; Desempenho de celulas a combustivel com alimentacao direta de etanol em funcao do uso de ar comprimido

    Energy Technology Data Exchange (ETDEWEB)

    Belchor, P.M. [UFRGS - Universidade Federal do Rio Grande do Sul, Porto Alegre, RS (Brazil); Berns, B.A.; Ferreira, R.C.; Goldbach, A.; Carpenter, D. [FURB - Fundacao Universidade Regional de Blumenau, Blumenau, SC (Brazil)

    2010-07-01

    This paper compared the performance of a direct ethanol fuel cell (CCADE) cathode feeding with air replacing the pure oxygen. The results have shown that the small decreasing of the yield of the cell under both practical and experimental situations, by the use of air replacing pure oxygen, it completely acceptable as function of great diminishing of operational costs. (author)

  9. Stall/surge dynamics of a multi-stage air compressor in response to a load transient of a hybrid solid oxide fuel cell-gas turbine system

    Science.gov (United States)

    Azizi, Mohammad Ali; Brouwer, Jacob

    2017-10-01

    A better understanding of turbulent unsteady flows in gas turbine systems is necessary to design and control compressors for hybrid fuel cell-gas turbine systems. Compressor stall/surge analysis for a 4 MW hybrid solid oxide fuel cell-gas turbine system for locomotive applications is performed based upon a 1.7 MW multi-stage air compressor. Control strategies are applied to prevent operation of the hybrid SOFC-GT beyond the stall/surge lines of the compressor. Computational fluid dynamics tools are used to simulate the flow distribution and instabilities near the stall/surge line. The results show that a 1.7 MW system compressor like that of a Kawasaki gas turbine is an appropriate choice among the industrial compressors to be used in a 4 MW locomotive SOFC-GT with topping cycle design. The multi-stage radial design of the compressor enhances the ability of the compressor to maintain air flow rate during transient step-load changes. These transient step-load changes are exhibited in many potential applications for SOFC/GT systems. The compressor provides sustained air flow rate during the mild stall/surge event that occurs due to the transient step-load change that is applied, indicating that this type of compressor is well-suited for this hybrid application.

  10. Radioactive Air Emissions Notice of Construction (NOC) for the Solid Waste Treatment Facility (T Plant) Fuel Removal Project

    Energy Technology Data Exchange (ETDEWEB)

    JOHNSON, R.E.

    2000-11-16

    This NOC describes the activities to remove all spent nuclear fuel (SNF) assemblies from the spent fuel pool in the T Plant Complex 221-T canyon for interim storage in the Canister Storage Building (CSB). The unabated total effective dose equivalent (TEDE) estimated for the public hypothetical maximally exposed individual (MEI) is 5.7 E-6 millirem (mrem) per year for this fuel removal NOC. The abated TEDE conservatively is estimated to account for 2.9 E-9 mrem per year to the MEI.

  11. Treatment of synthetic arsenate wastewater with iron-air fuel cell electrocoagulation to supply drinking water and electricity in remote areas.

    Science.gov (United States)

    Kim, Jung Hwan; Maitlo, Hubdar Ali; Park, Joo Yang

    2017-05-15

    Electrocoagulation with an iron-air fuel cell is an innovative arsenate removal system that can operate without an external electricity supply. Thus, this technology is advantageous for treating wastewater in remote regions where it is difficult to supply electricity. In this study, the possibility of real applications of this system for arsenate treatment with electricity production was verified through electrolyte effect investigations using a small-scale fuel cell and performance testing of a liter-scale fuel cell stack. The electrolyte species studied were NaCl, Na 2 SO 4 , and NaHCO 3 . NaCl was overall the most effective electrolyte for arsenate treatment, although Na 2 SO 4 produced the greatest electrical current and power density. In addition, although the current density and power density were proportional to the concentrations of NaCl and Na 2 SO 4 , the use of concentrations above 20 mM of NaCl and Na 2 SO 4 inhibited arsenate treatment due to competition effects between anions and arsenate in adsorption onto the iron hydroxide. The dominant iron hydroxide produced at the iron anode was found to be lepidocrocite by means of Raman spectroscopy. A liter-scale four-stack iron-air fuel cell with 10 mM NaCl electrolyte was found to be able to treat about 300 L of 1 ppm arsenate solution to below 10 ppb during 1 day, based on its 60-min treatment capacity, as well as produce the maximum power density of 250 mW/m 2 . Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. U.S. Air Force Environmental Assessment, Add To and Alter Type III Hydrant Fueling System, Tinker Air Force Base, Oklahoma

    Science.gov (United States)

    2011-12-01

    expose buried archaeological materials such as chipped stone tools, pottery , bone, historic crockery, glass, metal items or building materials, this...ApprOXImately 11,000 linear feet of e.>usllng underjllOund fiberglass fuel transfer line would be remCYed and replaced with an Interior coated carbon steel...Trai’ISfer Line ApproxJ tely 1 lng underground fiberglass fuel Ira ~ 11 • ma 1,000 linear feet of exist- . . n~.er na would be removed and -•--A tnterior

  13. In-situ air injection, soil vacuum extraction and enhanced biodegradation: A case study in a JP-4 jet fuel contaminated site

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Jong Soo; DiGiulio, D.C.; Wilson, J.T. [National Risk Management Lab., Ada, OK (United States)

    1997-12-31

    The US Environmental Protection Agency (US EPA) and the US Coast Guard (USCG) conducted a joint demonstration of in situ remediation of a JP-4 jet fuel spill at the USCG Support Center in Elizabeth City, North Carolina. The jet fuel was trapped beneath a clay layer that extended from the surface to a depth of 1.5 in. The water table was 2.0 in below land surface, and jet fuel extended from a depth of 1.0 to 3.5 in. Air was injected under pressure to depress the water table and bring the entire spill into the unsaturated zone, where hydrocarbons could be removed by volatilization and biodegradation. The injected air was recovered through soil vacuum extraction (SVE) at the treatment area. To document actual removal of hydrocarbons, core samples were acquired in August 1992 before air injection, and September 1994 at the end of the demonstration. The spill originally contained 3600 kg of JP-4. Between the core sampling events, only 55 % of the total petroleum hydrocarbons were removed, but more than 98% of benzene was removed. The initial goal was to reduce the concentration of total petroleum hydrocarbons (TPH) to concentrations less than 100 mg/kg soil. This was not accomplished within 18 months of operation. During the period of operation, ground water was monitored for the concentration of benzene, toluene, ethylbenzene, and the xylene isomers (BTEX), and methyl tertiary butyl ether (MTBE). The concentration of BTEX and MTBE in the subsurface was reduced to a very low level, but concentrations of benzene and MTBE in ground water did not meet the EPA drinking water standards in the most heavily impacted wells. The effluent gas from SVE was monitored for the concentration of total hydrocarbon vapors. 12 refs., 7 figs., 5 tabs.

  14. The effect of incomplete fuel-air mixing on the lean blowout limit, lean stability limit and NO(x) emissions in lean premixed gas turbine combustors

    Science.gov (United States)

    Shih, W.-P.; Lee, J. G.; Santavicca, D. A.

    1994-01-01

    Gas turbine engines for both land-based and aircraft propulsion applications are facing regulations on NOx emissions which cannot be met with current combustor technology. A number of alternative combustor strategies are being investigated which have the potential capability of achieving ultra-low NOx emissions, including lean premixed combustors, direct injection combustors, rich burn-quick quench-lean burn combustors and catalytic combustors. The research reported in this paper addresses the effect of incomplete fuel-air mixing on the lean limit performance and the NOx emissions characteristics of lean premixed combustors.

  15. Impact assessment of biomass-based district heating systems in densely populated communities. Part II: Would the replacement of fossil fuels improve ambient air quality and human health?

    Science.gov (United States)

    Petrov, Olga; Bi, Xiaotao; Lau, Anthony

    2017-07-01

    To determine if replacing fossil fuel combustion with biomass gasification would impact air quality, we evaluated the impact of a small-scale biomass gasification plant (BRDF) at a university campus over 5 scenarios. The overall incremental contribution of fine particles (PM2.5) is found to be at least one order of magnitude lower than the provincial air quality objectives. The maximum PM2.5 emission from the natural gas fueled power house (PH) could adversely add to the already high background concentration levels. Nitrogen dioxide (NO2) emissions from the BRDF with no engineered pollution controls for NOx in place exceeded the provincial objective in all seasons except during summer. The impact score, IS, was the highest for NO2 (677 Disability Adjusted Life Years, DALY) when biomass entirely replaced fossil fuels, and the highest for PM2.5 (64 DALY) and CO (3 DALY) if all energy was produced by natural gas at PH. Complete replacement of fossil fuels by one biomass plant can result in almost 28% higher health impacts (708 DALY) compared to 513 DALY when both the current BRDF and the PH are operational mostly due to uncontrolled NO2 emissions. Observations from this study inform academic community, city planners, policy makers and technology developers on the impacts of community district heating systems and possible mitigation strategies: a) community energy demand could be met either by splitting emissions into more than one source at different locations and different fuel types or by a single source with the least-impact-based location selection criteria with biomass as a fuel; b) advanced high-efficiency pollution control devices are essential to lower emissions for emission sources located in a densely populated community; c) a spatial and temporal impact assessment should be performed in developing bioenergy-based district heating systems, in which the capital and operational costs should be balanced with not only the benefit to greenhouse gas emission

  16. Environmental Assessment For the Proposed Construction and Operation of a Consolidated Fuels Facility and the Demolition of the Existing Fuel Farm at Buckley Air Force Base, Colorado

    Science.gov (United States)

    2005-12-01

    outlined in its 39 guidance to "apply a simple screening procedure ... " to determine if a potential air-quality 4-7 Environmental Assessment For the... cultura ~ economic, social, or health, whether direct, indirect, or cumulative. Effects may also include those resulting from actions which may have· both

  17. Performance of a single fuel-vaporizing combustor with six injectors adapted for gaseous hydrogen

    Science.gov (United States)

    Wear, Jerrold D; Smith, Arthur L

    1955-01-01

    The combustor was operated over a range of inlet-air pressures from 5.3 to 24.0 inches of mercury absolute and inlet-air reference velocities from 60 to 100 feet per second. The combustion efficiencies obtained with the six configurations varied from about 65 to 95 percent for a combustor temperature-rise range of 200 degrees to 1400 degrees F. At a temperature rise of 1200 degrees F (near-rated engine conditions), the spread in efficiencies of the six configurations was about 5 percent. Efficiencies in the range of 65 to 85 percent were obtained at operating conditions beyond the burning range of conventional jet fuels. A fuel-injector configuration that fed only gaseous hydrogen fuel into the standard liquid-fuel-vaporizing tubes generally gave the highest efficiencies. This configuration minimizes the possibility of combustion in the fuel-vaporizing tubes and could be easily adapted to the full-scale engine combustor.

  18. Idle Operation with Low Intake Valve Lift in a Port Fuel Injected Engine

    Directory of Open Access Journals (Sweden)

    Adrian Clenci

    2013-06-01

    Full Text Available Reducing fuel consumption is a prime objective in the automotive industry in order to meet regulatory and customer demands. Variable valve actuation offers many opportunities for improving the spark ignition engine’s performance in areas such as fuel economy and pollutant emissions. Our studies revealed that the ability to control maximum intake valve lift does indeed offer the ability to control intake air mass, but also has the added benefit that it improves the fuel-air mixing process thanks to an increased turbulence, caused by the increased intake flow velocity. This is particularly important at idle and low part loads when low maximum lifts are to be used for improving the fuel economy or for achieving the required power. The paper focuses on the experimental results obtained when approaching idle operation with different intake valve laws. Results indicating the potential of using low intake valve lift for fuel economy and cyclic dispersion improvement are presented in this paper.

  19. Simulation with GOTHIC of experiments Oxidation of fuel in Air; Simulacion con GOTHIC de Experimentos de Oxidacion de Combustible en Aire

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-Murillo Mendez, J. C.

    2012-07-01

    In the present work has been addressed for the first time la simulation with the GOTHIC code, experiments oxidation and ignition of SFP in phase 1. This work represents a solid starting point for analysis of specific degradation of fuel in the pools of our facilities.

  20. 40 CFR 80.602 - What records must be kept by entities in the NRLM diesel fuel, ECA marine fuel, and diesel fuel...

    Science.gov (United States)

    2010-07-01

    ... in the NRLM diesel fuel, ECA marine fuel, and diesel fuel additive production, importation, and... (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Recordkeeping and Reporting Requirements...

  1. A Unified Model Considering Effects of Droplet Break-Up and Air Entrainment at the Initial Stage of Fuel Spray Penetration

    Directory of Open Access Journals (Sweden)

    S. Jafarmadar

    2014-01-01

    Full Text Available This paper proposes a new unified single model that considers droplet break-up and air entrainment impact on three flow regimes (namely, Stokes, Allen, and Newton in the initial stage of fuel spray penetration. Homotopy perturbation method was used to obtain semianalytical solutions of unified single model on diesel fuel’s spray penetration when the influence of air entrainment is small (up to 0.1-0.2 ms after the start of injection. It is demonstrated that the applied analytical method is very straightforward in comparison with existing techniques. Furthermore, it is decidedly effectual in terms of accuracy and rapid convergence. The formulation of the problem is presented in the text as well as the analytical and numerical procedures.

  2. Investigation of Ignition and Combustion Processes of Diesel Engines Operating with Turbulence and Air-storage Chambers

    Science.gov (United States)

    Petersen, Hans

    1938-01-01

    The flame photographs obtained with combustion-chamber models of engines operating respectively, with turbulence chamber and air-storage chambers or cells, provide an insight into the air and fuel movements that take place before and during combustion in the combustion chamber. The relation between air velocity, start of injection, and time of combustion was determined for the combustion process employing a turbulence chamber.

  3. Charge Stratification and Fuel/Air Ratio Effect on theEfficiency of (ICADE) I. C. Engine Cycle

    OpenAIRE

    Hayder Abed Dhahad

    2011-01-01

    The Isolated Combustion and Diluted Expansion (ICADE) internal combustion engine cycle combines the advantages of constant volume combustion of the Otto cycle with the high compression ratio of the Diesel cycle. This work studies the effect of isolated air mass (charge stratification) on the efficiency of the cycle; the analysis shows that the decrease of isolated air mass will increase the efficiency of the cycle and the large dilution air mass will quench all NOx forming reactions and reduc...

  4. WC-CoCr coatings sprayed by high velocity oxygen-fuel (HVOF flame on AA7050 aluminum alloy: electrochemical behavior in 3.5% NaCl solution

    Directory of Open Access Journals (Sweden)

    Marina Magnani

    2007-12-01

    Full Text Available In the present work, the electrochemical behavior of WC-CoCr coatings with 10 (W10, 15 (W15 and 20 (W20 torch passes sprayed by High Velocity Oxygen-Fuel (HVOF flame on AA7050 aluminum alloy substrate, evaluated in 3.5% NaCl solution, were compared using open-circuit potential (E OC measurements, electrochemical impedance spectroscopy (EIS and polarization curves. The coating surfaces and their cross sections were characterized by X ray diffraction and the Rockwell-C hardness test, and also by optical (OM and scanning electron microscopy (SEM before and after the corrosion tests. The electrochemical data showed that sample W10 presented higher corrosion resistance than the others in chloride solutions. In some tests, aluminum salts on the coating surface were identified by EDS, indicating the corrosion of the substrate. And using aluminon, aluminum ions were detected and analyzing the surface via stereomicroscopy, hydrogen bubbles were observed, both showing that the electrolyte reached the substrate and galvanic corrosion possibly occurred. The physical characterization showed that sample W10 presented a lower number of cracks and pores, justifying its higher corrosion resistance.

  5. A Systematic Study of Separators in Air-Breathing Flat-Plate Microbial Fuel Cells—Part 1: Structure, Properties, and Performance Correlations

    Directory of Open Access Journals (Sweden)

    Sona Kazemi

    2016-01-01

    Full Text Available Passive air-breathing microbial fuel cells (MFCs are a promising technology for energy recovery from wastewater and their performance is highly dependent on characteristics of the separator that isolates the anaerobic anode from the air-breathing cathode. The goal of the present work is to systematically study the separator characteristics and its effect on the performance of passive air-breathing flat-plate MFCs (FPMFCs. This was performed through characterization of structure, properties, and performance correlations of eight separators in Part 1 of this work. Eight commercial separators were characterized, in non-inoculated and inoculated setups, and were examined in passive air-breathing FPMFCs with different electrode spacing. The results showed a decrease in the peak power density as the oxygen and ethanol mass transfer coefficients in the separators increased, due to the increase of mixed potentials especially at smaller electrode spacing. Increasing the electrode spacing was therefore desirable for the application of diaphragms. The highest peak power density was measured using Nafion®117 with minimal electrode spacing, whereas using Nafion®117 or Celgard® with larger electrode spacing resulted in similar peak powers. Part 2 of this work focuses on numerical modelling of the FPMFCs based on mixed potential theory, implementing the experimental data from Part 1.

  6. Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines

    Energy Technology Data Exchange (ETDEWEB)

    Venkatesan, Krishna

    2011-11-30

    The purpose of this program was to develop low-emissions, efficient fuel-flexible combustion technology which enables operation of a given gas turbine on a wider range of opportunity fuels that lie outside of current natural gas-centered fuel specifications. The program encompasses a selection of important, representative fuels of opportunity for gas turbines with widely varying fundamental properties of combustion. The research program covers conceptual and detailed combustor design, fabrication, and testing of retrofitable and/or novel fuel-flexible gas turbine combustor hardware, specifically advanced fuel nozzle technology, at full-scale gas turbine combustor conditions. This project was performed over the period of October 2008 through September 2011 under Cooperative Agreement DE-FC26-08NT05868 for the U.S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled "Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines". The overall objective of this program was met with great success. GE was able to successfully demonstrate the operability of two fuel-flexible combustion nozzles over a wide range of opportunity fuels at heavy-duty gas turbine conditions while meeting emissions goals. The GE MS6000B ("6B") gas turbine engine was chosen as the target platform for new fuel-flexible premixer development. Comprehensive conceptual design and analysis of new fuel-flexible premixing nozzles were undertaken. Gas turbine cycle models and detailed flow network models of the combustor provide the premixer conditions (temperature, pressure, pressure drops, velocities, and air flow splits) and illustrate the impact of widely varying fuel flow rates on the combustor. Detailed chemical kinetic mechanisms were employed to compare some fundamental combustion characteristics of the target fuels, including flame speeds and lean blow-out behavior. Perfectly premixed combustion experiments were conducted to

  7. Improving a free air breathing proton exchange membrane fuel cell through the Maximum Efficiency Point Tracking method

    Science.gov (United States)

    Higuita Cano, Mauricio; Mousli, Mohamed Islam Aniss; Kelouwani, Sousso; Agbossou, Kodjo; Hammoudi, Mhamed; Dubé, Yves

    2017-03-01

    This work investigates the design and validation of a fuel cell management system (FCMS) which can perform when the fuel cell is at water freezing temperature. This FCMS is based on a new tracking technique with intelligent prediction, which combined the Maximum Efficiency Point Tracking with variable perturbation-current step and the fuzzy logic technique (MEPT-FL). Unlike conventional fuel cell control systems, our proposed FCMS considers the cold-weather conditions, the reduction of fuel cell set-point oscillations. In addition, the FCMS is built to respond quickly and effectively to the variations of electric load. A temperature controller stage is designed in conjunction with the MEPT-FL in order to operate the FC at low-temperature values whilst tracking at the same time the maximum efficiency point. The simulation results have as well experimental validation suggest that propose approach is effective and can achieve an average efficiency improvement up to 8%. The MEPT-FL is validated using a Proton Exchange Membrane Fuel Cell (PEMFC) of 500 W.

  8. Electricity production and phosphorous recovery as struvite from synthetic wastewater using magnesium-air fuel cell electrocoagulation.

    Science.gov (United States)

    Kim, Jung Hwan; An, Byung Min; Lim, Dae Hwan; Park, Joo Yang

    2018-01-05

    This research was based on the investigation of a major principle, regarding the effects of NaCl and KH2PO4 concentrations on struvite recovery, with electricity production using magnesium-air fuel cell electrocoagulation, in accordance with the concentration of phosphorous and chloride. The weight ratio of N:P in the synthetic wastewater was in the range of 1.2-21. The concentration of NH4Cl was fixed at 0.277 M (approximately 3888 ppm as NH3-N and 5000 ppm as NH4), while PO4-P was in the range of 0.006-0.1 M. In addition, the concentrations of NaCl as electrolyte were 0, 0.01, and 0.1 M. Phosphate removal increased linearly with the Mg:P ratio, up to approximately 1.1 mol mol-1, irrespective of the initial concentrations of phosphate and NaCl. The one-to-one reaction as mole ratio between phosphate and the dissolved Mg ions resulted in phosphate removal, with the production of a one-to-one magnesium/phosphate mineral, such as struvite. The average removal rate of phosphorous in experiments without a dose of NaCl was 4.19 mg P cm-2 h-1, which was lower than the relative values of 5.35 and 4.77 mg P cm-2 h-1, in experiments with 0.01 and 0.1 M NaCl. The dissolution rate of Mg with electro-oxidation determined the rate of phosphorous removal with struvite recovery. The average removal rates of phosphorous with dose concentrations of 0.006, 0.01 and 0.02 M KH2PO4 were 4.02, 5.54, 6.9 mg P cm-2 h-1, respectively, which increased with the increase in KH2PO4 dose. However, in experiments with a dose of 0.05 and 0.1 M KH2PO4, the average removal rates of phosphorous decreased to 4.84 and 2.51, respectively. The maximum power densities in the electrolyte mixture of 0.05 M KH2PO4/0.277 M NH4Cl, 0.01 M NaCl/0.05 M KH2PO4/0.277 M NH4Cl, and 0.1 NaCl/0.05 KH2PO4/0.277 M NH4Cl were 25.1, 26.4, and 33.2 W/m2, respectively. The increase in the NaCl dose concentration resulted in an increase in the maximum power density and current

  9. Achieving high-powered Zn/air fuel cell through N and S co-doped hierarchically porous carbons with tunable active-sites as oxygen electrocatalysts

    Science.gov (United States)

    Tang, Qiaowei; Wang, Luming; Wu, Mingjie; Xu, Nengneng; Jiang, Lei; Qiao, Jinli

    2017-10-01

    Electrochemical reduction of oxygen is the heart of the next-generation energy technologies to fuel cells and metal-air batteries, of which the reference catalysts suffer from two critical bottlenecks lying in their insufficient electroactivities and unclear active site structures. Herein, we introduce the effectively hierarchically porous carbons (HPCs) as the active-sites enriched platform for oxygen electroreduction. Three quaternized copolymers (PUB, PAADDA and PICP) with different chemical structures are used to pursue Fe/N/S-tailored ORR electrocatalysts. The most efficient one prepared by PAADDA gives the onset potential of 0.94 V and a half-wave potential of 0.85 V in basic solution, as well as superb electroactivities of low H2O2% and high electron transfer number in both alkaline and acidic medium. Surprisingly, they all display high discharge power density as applied to Zn-air fuel cells, and the HPCs-PAADDA catalyst thrillingly reaches 516.3 mW cm-2 when catalyst loading is optimized to 5.0 mg cm-2. The results elucidate that the polymer with long aliphatic chain is propitious to trap metals to create active sites and enwrap silica template to construct uniform pore structure. Only two kinds of nitrogen configuration (pyridinic-N and graphitic-N) are found with distinct structure in these HPCs, which happens to be active sites.

  10. Effect of pH in a Pd-based ethanol membraneless air breathing nanofluidic fuel cell with flow-through electrodes

    Science.gov (United States)

    López-Rico, C. A.; Galindo-de-la-Rosa, J.; Ledesma-García, J.; Arriaga, L. G.; Guerra-Balcázar, M.; Arjona, N.

    2015-12-01

    In this work, a nanofluidic fuel cell (NFC) in which streams flow through electrodes was used to investigate the role of pH in the cell performance using ethanol as fuel and two Pd nanoparticles as electrocatalysts: one commercially available (Pd/C from ETEK) and other synthesized using ionic liquids (Pd/C IL). The cell performances for both electrocatalysts in acid/acid (anodic/cathodic) streams were of 18.05 and 9.55 mW cm-2 for Pd/C ETEK and Pd/C IL. In alkaline/alkaline streams, decrease to 15.94 mW cm-2 for Pd/C ETEK and increase to 15.37 mW cm-2 for Pd/C IL. In alkaline/acidic streams both electrocatalysts showed similar cell voltages (up to 1 V); meanwhile power densities were of 87.6 and 99.4 mW cm-2 for Pd/C ETEK and Pd/C IL. The raise in cell performance can be related to a decrease in activation losses, the combined used of alkaline and acidic streams and these high values compared with flow-over fuel cells can be related to the enhancement of the cathodic mass transport by using three dimensional porous electrodes and two sources of oxygen: from air and from a saturated solution.

  11. On the effect of injection timing on the ignition of lean PRF/air/EGR mixtures under direct dual fuel stratification conditions

    KAUST Repository

    Luong, Minh Bau

    2017-06-10

    The ignition characteristics of lean primary reference fuel (PRF)/air/exhaust gas recirculation (EGR) mixture under reactivity-controlled compression ignition (RCCI) and direct duel fuel stratification (DDFS) conditions are investigated by 2-D direct numerical simulations (DNSs) with a 116-species reduced chemistry of the PRF oxidation. The 2-D DNSs of the DDFS combustion are performed by varying the injection timing of iso-octane (i-C8H18) with a pseudo-iso-octane (PC8H18) model together with a novel compression heating model to account for the compression heating and expansion cooling effects of the piston motion in an engine cylinder. The PC8H18 model is newly developed to mimic the timing, duration, and cooling effects of the direct injection of i-C8H18 onto a premixed background charge of PRF/air/EGR mixture with composition inhomogeneities. It is found that the RCCI combustion exhibits a very high peak heat release rate (HRR) with a short combustion duration due to the predominance of the spontaneous ignition mode of combustion. However, the DDFS combustion has much lower peak HRR and longer combustion duration regardless of the fuel injection timing compared to those of the RCCI combustion, which is primarily attributed to the sequential injection of i-C8H18. It is also found that the ignition delay of the DDFS combustion features a non-monotonic behavior with increasing fuel-injection timing due to the different effect of fuel evaporation on the low-, intermediate-, and high-temperature chemistry of the PRF oxidation. The budget and Damköhler number analyses verify that although a mixed combustion mode of deflagration and spontaneous ignition exists during the early phase of the DDFS combustion, the spontaneous ignition becomes predominant during the main combustion, and hence, the spread-out of heat release rate in the DDFS combustion is mainly governed by the direct injection process of i-C8H18. Finally, a misfire is observed for the DDFS combustion when

  12. Effective sulfur and energy recovery from hydrogen sulfide through incorporating an air-cathode fuel cell into chelated-iron process.

    Science.gov (United States)

    Sun, Min; Song, Wei; Zhai, Lin-Feng; Cui, Yu-Zhi

    2013-12-15

    The chelated-iron process is among the most promising techniques for the hydrogen sulfide (H2S) removal due to its double advantage of waste minimization and resource recovery. However, this technology has encountered the problem of chelate degradation which made it difficult to ensure reliable and economical operation. This work aims to develop a novel fuel-cell-assisted chelated-iron process which employs an air-cathode fuel cell for the catalyst regeneration. By using such a process, sulfur and electricity were effectively recovered from H2S and the problem of chelate degradation was well controlled. Experiment on a synthetic sulfide solution showed the fuel-cell-assisted chelated-iron process could maintain high sulfur recovery efficiencies generally above 90.0%. The EDTA was preferable to NTA as the chelating agent for electricity generation, given the Coulombic efficiencies (CEs) of 17.8 ± 0.5% to 75.1 ± 0.5% for the EDTA-chelated process versus 9.6 ± 0.8% to 51.1 ± 2.7% for the NTA-chelated process in the pH range of 4.0-10.0. The Fe (III)/S(2-) ratio exhibited notable influence on the electricity generation, with the CEs improved by more than 25% as the Fe (III)/S(2-) molar ratio increased from 2.5:1 to 3.5:1. Application of this novel process in treating a H2S-containing biogas stream achieved 99% of H2S removal efficiency, 78% of sulfur recovery efficiency, and 78.6% of energy recovery efficiency, suggesting the fuel-cell-assisted chelated-iron process was effective to remove the H2S from gas streams with favorable sulfur and energy recovery efficiencies. Copyright © 2013 Elsevier B.V. All rights reserved.

  13. Conceptual and feasibility study on lab-scale series power generation by carbon-air and conventional solid oxide fuel cells

    Science.gov (United States)

    Duan, Nan-Qi; Cao, Yong; Chi, Bo; Pu, Jian; Li, Jian

    2016-10-01

    To take the advantage chemical-looping combustion (CLC) process for CO2 sequestration, carbon-air fuel cell (CAFC) and conventional solid oxide fuel cell (SOFC) are prepared for high-efficiency series power generation. The tubular CAFC (Cell-I) consisting of Sb anode, (Y2O3)0.08(ZrO2)0.92 (YSZ) electrolyte and La0.6Sr0.4Co0.2Fe0.8O3-δ-Gd0.1Ce0.9O3-δ (LSCF-GDC) cathode has achieved peak power densities of 117, 186 and 295 mW cm-2 at 700, 750 and 800 °C, respectively. Fueled by repeatedly added 3 g of coconut-derived activated charcoal, Cell-I has operated stably at 800 °C for 21 h under the condition of 0.4 A cm-2 and 0.502 V, with an electrical efficiency of 30.8%. The tubular conventional SOFC (Cell-II) is designed with Ni-YSZ as anode, YSZ electrolyte as electrolyte and (La0.8Sr0.2)0.95MnO3-δ-YSZ (LSM-YSZ) as cathode. The anode exhaust gas of Cell-I, which is operated at temperatures from 750 to 850 °C, contains CO and CO2. Using this exhaust gas as fuel, Cell-II has demonstrated peak power densities between 87 and 133 mW cm-2 at 750 °C, and performed stably for 6 h at 0.1 A cm-2 and 0.720 V during which 69.6% of CO in the exhaust gas is consumed. Cell-II has achieved an extra electrical efficiency of 11.0%, giving a total electrical efficiency of 41.8% for the series power generation.

  14. Numerical Investigation of Laminar Diffusion Flames Established on a Horizontal Flat Plate in a Parallel Air Stream

    Directory of Open Access Journals (Sweden)

    E. D. Gopalakrishnan

    2011-06-01

    Full Text Available Numerical investigation of laminar diffusion flames established on a flat plate in a parallel air stream is presented. A numerical model with a multi-step chemical kinetics mechanism, variable thermo-physical properties, multi-component species diffusion and a radiation sub-model is employed for this purpose. Both upward and downward injection of fuel has been considered in a normal gravity environment. The thermal and aerodynamic structure of the flame has been explained with the help of temperature and species contours, net reaction rate of fuel and streamlines. Flame characteristics and stability aspects for several air and fuel velocity combinations have been studied. An important characteristic of a laminar boundary layer diffusion flame with upward injection of fuel is the velocity overshoot that occurs near the flame zone. This is not observed when the fuel is injected in the downward direction. The flame standoff distance is slightly higher for the downward injection of fuel due to increase in displacement thickness of boundary layer. Influence of an obstacle, namely the backward facing step, on the flame characteristics and stability aspects is also investigated. Effects of air and fuel velocities, size and location of the step are studied in detail. Based on the air and fuel velocities, different types of flames are predicted. The use of a backward-facing step as a flame holding mechanism for upward injection of fuel, results in increased stability limits due to the formation of a recirculation zone behind the step. The predicted stability limits match with experimentally observed limits. The step location is seen to play a more important role as compared to the step height in influencing the stability aspects of flames.

  15. Fuel processor for fuel cell power system

    Science.gov (United States)

    Vanderborgh, Nicholas E.; Springer, Thomas E.; Huff, James R.

    1987-01-01

    A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

  16. United States Air Force Training Extract AFSC 2A6X4 Aircraft Fuel Systems (ANG/AFRC)

    Science.gov (United States)

    2001-02-01

    manifold ( ETAM ) components 18 17 19 9 8 10 D0176 Inspect EPU components, such as nitrogen control 34...Rebuild ETAMs 9 8 11 4 5 3 F0314 Rebuild fuel level control valves...9 9 6 8 4 D0175 Inspect engine to airframe manifold ( ETAM ) components 18 17 19 9 8 10 D0176

  17. Highlights from Faraday Discussion 182: Solid Oxide Electrolysis: Fuels and Feedstocks from Water and Air, York, UK, July 2015.

    Science.gov (United States)

    Stefan, Elena; Norby, Truls

    2016-01-31

    The rising importance of converting high peak electricity from renewables to fuels has urged field specialists to organize this Faraday Discussion on Solid Oxide Electrolysis. The topic is of essential interest in order to achieve a greater utilization of renewable energy and storage at higher densities.

  18. Environmental Assessment for the Maintenance, Upgrade, and Construction of the Jet Fuel Distribution System, Edwards Air Force Base, California

    Science.gov (United States)

    2009-01-01

    Antiperching devices shall be installed to deter birds from perching on structures. p. If bat roosts are encountered, the bats shall be removed by an...Compliance Branch Gerald Callahan Chief, Environmental Conservation Branch FINAL January 2009 88 Jet Fuel Distribution System EA Robert M

  19. An observational study on the effects of aviation turbine fuel and lubricants on the skin of Indian Air Force ground crew in flying stations.

    Science.gov (United States)

    Radhakrishnan, S; Chopra, Ajay; Mitra, Debdeep; Gnanasekaran, R; Kanagaraj, R

    2017-07-01

    Ground crew of the Air Force routinely handle aviation turbine fuel (ATF) and lubricants and a need was felt to study the adverse effects of these substances on their skin so that remedial measures could be taken to prevent these adverse effects. A multi-centric, cross-sectional, observational study was performed at three Air Force flying stations. 109 ground crew members of the Indian Air Force (IAF) who were in direct contact with ATF and lubricants were screened for dermatological manifestations on exposed areas. History of atopy was elicited, systemic and dermatological examination done and occlusive patch testing carried out where indicated. Fungal infections were excluded by a potassium hydroxide mount. 20 out of the 109 personnel (18.34%) were symptomatic in the form of mild irritant contact dermatitis. There was no case of allergic contact dermatitis. Only two cases showed an irritant reaction on patch testing. 65% of the symptomatic personnel were atopic. There was no predisposing trade or age group for adverse effects to ATF. This study revealed that contact with ATF is associated with only mild irritant contact dermatitis in exposed ground crew members of the IAF and atopy was a predisposing factor for susceptibility to the dermatitis.

  20. A shift in emission time profiles of fossil fuel combustion due to energy transitions impacts source receptor matrices for air quality.

    Science.gov (United States)

    Hendriks, Carlijn; Kuenen, Jeroen; Kranenburg, Richard; Scholz, Yvonne; Schaap, Martijn

    2015-03-01

    Effective air pollution and short-lived climate forcer mitigation strategies can only be designed when the effect of emission reductions on pollutant concentrations and health and ecosystem impacts are quantified. Within integrated assessment modeling source-receptor relationships (SRRs) based on chemistry transport modeling are used to this end. Currently, these SRRs are made using invariant emission time profiles. The LOTOS-EUROS model equipped with a source attribution module was used to test this assumption for renewable energy scenarios. Renewable energy availability and thereby fossil fuel back up are strongly dependent on meteorological conditions. We have used the spatially and temporally explicit energy model REMix to derive time profiles for backup power generation. These time profiles were used in LOTOS-EUROS to investigate the effect of emission timing on air pollutant concentrations and SRRs. It is found that the effectiveness of emission reduction in the power sector is significantly lower when accounting for the shift in the way emissions are divided over the year and the correlation of emissions with synoptic situations. The source receptor relationships also changed significantly. This effect was found for both primary and secondary pollutants. Our results indicate that emission timing deserves explicit attention when assessing the impacts of system changes on air quality and climate forcing from short lived substances.

  1. Estimation of the in-cylinder air/fuel ratio of an internal combustion engine by the use of pressure sensors

    Energy Technology Data Exchange (ETDEWEB)

    Tunestaal, Per

    2000-03-01

    This thesis investigates the use of cylinder pressure measurements for estimation of the in-cylinder air/fuel ratio in a spark ignited internal combustion engine. An estimation model which uses the net heat release profile for estimating the cylinder air/fuel ratio of a spark ignition engine is developed. The net heat release profile is computed from the cylinder pressure trace and quantifies the conversion of chemical energy of the reactants in the charge into thermal energy. The net heat release profile does not take heat- or mass transfer into account. Cycle-averaged air/fuel ratio estimates over a range of engine speeds and loads show an RMS error of 4.1% compared to measurements in the exhaust. A thermochemical model of the combustion process in an internal combustion engine is developed. It uses a simple chemical combustion reaction, polynominal fits of internal energy as function of temperature, and the first law of thermodynamics to derive a relationship between measured cylinder pressure and the progress of the combustion process. Simplifying assumptions are made to arrive at an equation which relates the net heat release to the cylinder pressure. Two methods for estimating the sensor offset of a cylinder pressure transducer are developed. Both methods fit the pressure data during the pre-combustion phase of the compression stroke to a polytropic curve. The first method assumes a known polytropic exponent, and the other estimates the polytropic exponent. The first method results in a linear least-squares problem, and the second method results in a nonlinear least-squares problem. The nonlinear least-squares problem is solved by separating out the nonlinear dependence and solving the single-variable minimization problem. For this, a finite difference Newton method is derived. Using this method, the cost of solving the nonlinear least-squares problem is only slightly higher than solving the linear least-squares problem. Both methods show good statistical

  2. Real-Time Velocity Optimization to Minimize Energy Use in Passenger Vehicles

    Directory of Open Access Journals (Sweden)

    Thomas Levermore

    2016-12-01

    Full Text Available Energy use in internal combustion engine passenger vehicles contributes directly to CO 2 emissions and fuel consumption, as well as producing a number of air pollutants. Optimizing the vehicle velocity by utilising upcoming road information is an opportunity to minimize vehicle energy use without requiring mechanical design changes. Dynamic programming is capable of such an optimization task and is shown in simulation to produce fuel savings, on average 12%, compared to real driving data; however, in this paper it is also applied in real time on a Raspberry Pi, a low cost miniature computer, in situ in a vehicle. A test drive was undertaken with driver feedback being provided by a dynamic programming algorithm, and the results are compared to a simulated intelligent cruise control system that can follow the algorithm results precisely. An 8% reduction in fuel with no loss in time is reported compared to the test driver.

  3. Qualification Test Report for 450 Gallon Crashworthy Fuel Tank for U.S. Air Force H-53 Helicopter. Volume 1

    Science.gov (United States)

    1982-04-02

    liner samples, simulated wall section samples and subscale models of the tank. This testing in- cluded permeability and adhesive testing using...specified • test fluids and known fuel resistant adhesives . Burn test- ing of various simulated tank wall sections, lightning testing of a subscale model of...California. From these tests it was determined that the insulative Polyisocyanurate Foam (I.C.U.) would not be required. This additional insulation Snly

  4. Carbon-Nanotube-Supported Bio-Inspired Nickel Catalyst and Its Integration in Hybrid Hydrogen/Air Fuel Cells.

    Science.gov (United States)

    Gentil, Solène; Lalaoui, Noémie; Dutta, Arnab; Nedellec, Yannig; Cosnier, Serge; Shaw, Wendy J; Artero, Vincent; Le Goff, Alan

    2017-02-06

    A biomimetic nickel bis-diphosphine complex incorporating the amino acid arginine in the outer coordination sphere was immobilized on modified carbon nanotubes (CNTs) through electrostatic interactions. The functionalized redox nanomaterial exhibits reversible electrocatalytic activity for the H2 /2 H(+) interconversion from pH 0 to 9, with catalytic preference for H2 oxidation at all pH values. The high activity of the complex over a wide pH range allows us to integrate this bio-inspired nanomaterial either in an enzymatic fuel cell together with a multicopper oxidase at the cathode, or in a proton exchange membrane fuel cell (PEMFC) using Pt/C at the cathode. The Ni-based PEMFC reaches 14 mW cm(-2) , only six-times-less as compared to full-Pt conventional PEMFC. The Pt-free enzyme-based fuel cell delivers ≈2 mW cm(-2) , a new efficiency record for a hydrogen biofuel cell with base metal catalysts. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Dual Tank Fuel System

    Science.gov (United States)

    Wagner, Richard William; Burkhard, James Frank; Dauer, Kenneth John

    1999-11-16

    A dual tank fuel system has primary and secondary fuel tanks, with the primary tank including a filler pipe to receive fuel and a discharge line to deliver fuel to an engine, and with a balance pipe interconnecting the primary tank and the secondary tank. The balance pipe opens close to the bottom of each tank to direct fuel from the primary tank to the secondary tank as the primary tank is filled, and to direct fuel from the secondary tank to the primary tank as fuel is discharged from the primary tank through the discharge line. A vent line has branches connected to each tank to direct fuel vapor from the tanks as the tanks are filled, and to admit air to the tanks as fuel is delivered to the engine.

  6. Hydrogen from reformer gas a novel fuel and bridging technology: A combustion perspective

    Energy Technology Data Exchange (ETDEWEB)

    Han, P.; Checkel, M.D.; Fleck, B.A. [Department of Mechanical Engineering, University of Alberta, Edmonton (Canada)

    2007-07-15

    Constant-volume combustion experiments measuring laminar burning velocity are presented for combinations of methane, inert diluent and H{sub 2}/CO mixtures that would result from steam reforming of methane. The experiments illustrate the very attractive prospects of on-board steam reforming in natural gas powered vehicles that would employ exhaust gas recirculation (EGR) to improve combustion performance and reduce NO{sub x} emissions. Laminar burning velocity in the partially reformed fuel stream can be maintained at levels similar to that of air/natural gas mixtures by increasing the prereforming of the fuel at increasing concentrations of EGR. Up to 40% dilution was tested, requiring that 53% of the methane fuel be reformed to maintain burning velocity. Calculations indicate NO{sub x} levels are similar to scenarios with unreformed fuel. The knowledge base from this and similar experiments is required to allow for the future adoption of on-board fuel reforming in IC engines. This is a critical intermediate step in introducing hydrogen as a fuel to the currently fossil-hydrocarbon oriented economy and fuel delivery infrastructure. (author)

  7. Assessment of the Effects of Flow Rate and Ionic Strength on the Performance of an Air-Cathode Microbial Fuel Cell Using Electrochemical Impedance Spectroscopy

    Directory of Open Access Journals (Sweden)

    Doug Aaron

    2010-03-01

    Full Text Available Impedance changes of the anode, cathode and solution were examined for an air-cathode microbial fuel cell (MFC under varying conditions. An MFC inoculated with a pre-enriched microbial culture resulted in a startup time of less than ten days. Over this period, the anode impedance decreased below the cathode impedance, suggesting a cathode-limited power output. Increasing the anode flow rate did not impact the anode impedance significantly, but it decreased the cathode impedance by 65%. Increasing the anode-medium ionic strength also decreased the cathode impedance. These impedance results provide insight into electron and proton transport mechanisms and can be used to improve MFC performance.

  8. 77 FR 18297 - Air Traffic Noise, Fuel Burn, and Emissions Modeling Using the Aviation Environmental Design Tool...

    Science.gov (United States)

    2012-03-27

    ... March 21, 2012. FOR FURTHER INFORMATION CONTACT: Rebecca Cointin, Office of Environment and Energy (AEE... emissions. FAA-AEE has approved AEDT 2a as an ``equivalent methodology'' to EDMS for developing aircraft-only emissions inventories when required for air traffic airspace and procedure actions. FAA-AEE has...

  9. Preliminary site characterization summary and engineering evaluation/cost analysis for Site 2, New Fuel Farm, Naval Air Station Fallon, Fallon, Nevada

    Energy Technology Data Exchange (ETDEWEB)

    Cronk, T.A.; Smuin, D.R. (Oak Ridge National Lab., TN (United States)); Schlosser, R.M. (Oak Ridge Associated Universities, Inc., TN (United States))

    1991-09-01

    This report addresses subsurface contamination associated with Site 2, the New Fuel Farm at Naval Air Station Fallon (NAS Fallon), Nevada and is an integral part of Phase 2 of the Installation Restoration Program (IR Program) currently underway at the facility. This report: (1) reviews and assesses environmental information characterizing Site 2; (2) determine if site-characterization information is sufficient to design and evaluate removal actions; and, (3) investigates, develops, and describes any removal actions deemed feasible. Previous environmental investigations at Site 2 indicate the presence of floating product (primarily JP-5, jet fuel) on the water table underlying the facility. While the extent of floating-produce plumes has been characterized, the degree of associated soil and groundwater contamination remains uncertain. A comprehensive characterization of soil and groundwater contamination will be completed as the Remedial Investigation/Feasibility Study progresses. Corrective actions are recommended at this time to remove free-phase floating product. Implementing these removal actions will also provide additional information which will be used to direct further investigations of the extent, mobility, and potential environmental threat from soil and groundwater contaminants at this side.

  10. Coal-fuelled systems for peaking power with 100% CO2 capture through integration of solid oxide fuel cells with compressed air energy storage

    Science.gov (United States)

    Nease, Jake; Adams, Thomas A.

    2014-04-01

    In this study, a coal-fuelled integrated solid oxide fuel cell (SOFC) and compressed air energy storage (CAES) system in a load-following power production scenario is discussed. Sixteen SOFC-based plants with optional carbon capture and sequestration (CCS) and syngas shifting steps are simulated and compared to a state-of-the-art supercritical pulverised coal (SCPC) plant. Simulations are performed using a combination of MATLAB and Aspen Plus v7.3. It was found that adding CAES to a SOFC-based plant can provide load-following capabilities with relatively small effects on efficiencies (1-2% HHV depending on the system configuration) and levelized costs of electricity (∼0.35 ¢ kW-1 h-1). The load-following capabilities, as measured by least-squares metrics, show that this system may utilize coal and achieve excellent load-tracking that is not adversely affected by the inclusion of CCS. Adding CCS to the SOFC/CAES system reduces measurable direct CO2 emission to zero. A seasonal partial plant shutdown schedule is found to reduce fuel consumption by 9.5% while allowing for cleaning and maintenance windows for the SOFC stacks without significantly affecting the performance of the system (∼1% HHV reduction in efficiency). The SOFC-based systems with CCS are found to become economically attractive relative to SCPC above carbon taxes of 22 ton-1.

  11. Electricity generation and microbial community structure of air-cathode microbial fuel cells powered with the organic fraction of municipal solid waste and inoculated with different seeds

    KAUST Repository

    El-Chakhtoura, Joline

    2014-08-01

    The organic fraction of municipal solid waste (OFMSW), normally exceeding 60% of the waste stream in developing countries, could constitute a valuable source of feed for microbial fuel cells (MFCs). This study tested the start-up of two sets of OFMSW-fed air-cathode MFCs inoculated with wastewater sludge or cattle manure. The maximum power density obtained was 123±41mWm-2 in the manure-seeded MFCs and 116±29mWm-2 in the wastewater-seeded MFCs. Coulombic efficiencies ranged between 24±5% (manure-seeded MFCs) and 23±2% (wastewater-seeded MFCs). Chemical oxygen demand removal was >86% in all the MFCs and carbohydrate removal >98%. Microbial community analysis using 16S rRNA gene pyrosequencing demonstrated the dominance of the phylum Firmicutes (67%) on the anode suggesting the possible role of members of this phylum in electricity generation. Principal coordinate analysis showed that the microbial community structure in replicate MFCs converged regardless of the inoculum source. This study demonstrates efficient electricity production coupled with organic treatment in OFMSW-fueled MFCs inoculated with manure or wastewater. © 2014 Elsevier Ltd.

  12. A Study of NO{sub x} Reduction by Fuel Injection Recirculation

    Energy Technology Data Exchange (ETDEWEB)

    Feese, J.J.; Turns, S.R.

    1996-08-01

    Flue-gas recirculation (FGR) is a well-known method used to control oxides of nitrogen (NO{sub X}) in industrial burner applications. Recent small- and large-scale experiments in natural-gas fired boilers have shown that introducing the recirculated flue gases with the fuel results in a much greater reduction in NO{sub X}, per unit mass of gas recirculated, in comparison to introducing the flue gases with the combustion air. That fuel injection recirculation (FIR) is more effective than windbox FGR is quite remarkable. At present, however, there is no definitive understanding of why FIR is more effective than conventional FGR. The objective of the present investigation is to ascertain whether or not chemical and/or molecular transport effects alone can explain the differences in NO{sub X} reduction observed between FIR and FGR by studying laminar diffusion flames. The purpose of studying laminar flames is to isolate chemical effects from the effects of turbulent mixing and heat transfer, which are inherent in practical boilers. Numerical simulations of H{sub 2}-air and CH{sub 4}-air counterflow diffusion flames using full kinetics were performed and NO{sub X} emission indices calculated for various conditions. Studies were conducted in which a N{sub 2} diluent was added either on the fuel- or air-side of the flame for conditions of either fixed initial velocities or fixed fuel mass flux. Results from these simulation studies indicate that a major factor in diluent effectiveness is the differential effect on flame zone residence times associated with fuel-side verses air-side dilution. Simulations in which flow velocities were fixed as diluent was added either to the air or fuel stream showed lower NO{sub X} emissions for air-side dilution; however, if instead, fuel mass fluxes were fixed as diluent was added, which results in an increase in the velocity of the streams, fuel-side dilution was more effective. These results were independent of whether H{sub 2} or Ch

  13. An innovative hybrid 3D analytic-numerical model for air breathing parallel channel counter-flow PEM fuel cells.

    Science.gov (United States)

    Tavčar, Gregor; Katrašnik, Tomaž

    2014-01-01

    The parallel straight channel PEM fuel cell model presented in this paper extends the innovative hybrid 3D analytic-numerical (HAN) approach previously published by the authors with capabilities to address ternary diffusion systems and counter-flow configurations. The model's core principle is modelling species transport by obtaining a 2D analytic solution for species concentration distribution in the plane perpendicular to the cannel gas-flow and coupling consecutive 2D solutions by means of a 1D numerical pipe-flow model. Electrochemical and other nonlinear phenomena are coupled to the species transport by a routine that uses derivative approximation with prediction-iteration. The latter is also the core of the counter-flow computation algorithm. A HAN model of a laboratory test fuel cell is presented and evaluated against a professional 3D CFD simulation tool showing very good agreement between results of the presented model and those of the CFD simulation. Furthermore, high accuracy results are achieved at moderate computational times, which is owed to the semi-analytic nature and to the efficient computational coupling of electrochemical kinetics and species transport.

  14. Planar air-breathing micro-direct methanol fuel cell stacks based on micro-electronic-mechanical-system technology

    Science.gov (United States)

    Cao, Jianyu; Zou, Zhiqing; Huang, Qinghong; Yuan, Ting; Li, Zhilin; Xia, Baojia; Yang, Hui

    To meet the demands for high power micro-electronic devices, two silicon-based micro-direct methanol fuel cell (μDMFC) stacks consisting of six individual cells with two different anode flow fields were designed, fabricated and evaluated. Micro-electronic-mechanical-system (MEMS) technology was used to fabricate both flow field plate and fuel distribution plate on the silicon wafer. Experimental results show that either an individual cell or a stack with double serpentine-type flow fields presents better cell performance than those with pin-type flow fields. A μDMFC stack with double serpentine-type flow fields generates a peak output power of ca. 151 mW at a working voltage of 1.5 V, corresponding to an average power density of ca. 17.5 mW cm -2, which is ca. 20.7% higher than that with pin-type flow fields. The volume and weight of the stacks are only 5.3 cm 3 and 10.7 g, respectively. Such small stacks could be used as power sources for micro-electronic devices.

  15. Carbon-Nanotube-Supported Bio-Inspired Nickel Catalyst and Its Integration in Hybrid Hydrogen/Air Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Gentil, Solène [Univ. Grenoble Alpes, CNRS, DCM UMR 5250, 38000 Grenoble France; Laboratoire de Chimie et Biologie des Métaux, Univ. Grenoble Alpes, CNRS UMR5249, CEA, 38000 Grenoble France; Lalaoui, Noémie [Univ. Grenoble Alpes, CNRS, DCM UMR 5250, 38000 Grenoble France; Dutta, Arnab [Pacific Northwest National Laboratory, Richland WA 99532 USA; Current address: Chemistry Department, IIT Gandhinagar, Gujarat 382355 India; Nedellec, Yannig [Univ. Grenoble Alpes, CNRS, DCM UMR 5250, 38000 Grenoble France; Cosnier, Serge [Univ. Grenoble Alpes, CNRS, DCM UMR 5250, 38000 Grenoble France; Shaw, Wendy J. [Pacific Northwest National Laboratory, Richland WA 99532 USA; Artero, Vincent [Laboratoire de Chimie et Biologie des Métaux, Univ. Grenoble Alpes, CNRS UMR5249, CEA, 38000 Grenoble France; Le Goff, Alan [Univ. Grenoble Alpes, CNRS, DCM UMR 5250, 38000 Grenoble France

    2017-01-12

    A biomimetic nickel bis-diphosphine complex incorporating the amino-acid arginine in the outer coordination sphere, was immobilized on modified single-wall carbon nanotubes (SWCNTs) through electrostatic interactions. The sur-face-confined catalyst is characterized by a reversible 2-electron/2-proton redox process at potentials close to the equibrium potential of the H+/H2 couple. Consequently, the functionalized redox nanomaterial exhibits reversible electrocatalytic activity for the H2/2H+ interconversion over a broad range of pH. This system exhibits catalytic bias, analogous to hydrogenases, resulting in high turnover frequencies at low overpotentials for electrocatalytic H2 oxida-tion between pH 0 and 7. This allowed integrating such bio-inspired nanomaterial together with a multicopper oxi-dase at the cathode side in a hybrid bioinspired/enzymatic hydrogen fuel cell. This device delivers ~2 mW cm–2 with an open-circuit voltage of 1.0 V at room temperature and pH 5, which sets a new efficiency record for a bio-related hydrogen fuel cell with base metal catalysts.

  16. Effects on Air Pollution and Regional Climate of Producing and Using Hydrogen in Fuel Cells in all U.S. OnroadVehicles

    Science.gov (United States)

    Jacobson, M. Z.; Colella, W. G.; Golden, D. M.

    2004-12-01

    The purpose of this study was to examine the potential effects on U.S. air pollution and regional climate of switching the current U.S. fleet of onroad motor vehicles to hydrogen fuel-cell vehicles, where hydrogen was produced by (1) steam-reforming of methane, (2) wind energy, or (3) coal gasification. An additional scenario in which the U.S. fleet was switched to gasoline-electric hybrid vehicles was also examined. The model used was GATOR-GCMOM, a global-through-urban-scale nested and parallelized gas, aerosol, transport, radiation, general-circulation, mesoscale, and ocean model. U.S. emission data for the baseline case were obtained from the U.S. National Emission Inventory, which considers 370,000 stack and fugitive sources, 250,000 area sources, and 1700 categories of onroad and nonroad vehicular sources (including motorcycles, passenger vehicles, trucks, recreational vehicles, construction vehicles, farm vehicles, industrial vehicles, etc.). Emission inventories for each of the three hydrogen scenarios were prepared following a process chain analysis that accounted for energy inputs and pollution outputs during all stages of hydrogen and fossil-fuel production, distribution, storage, and end-use. Emitted pollutants accounted for included CO, CO2, H2, H2O, CH4, speciated ROGs, NOx, NH3, SOx, and speciated particulate matter. Results from the first scenario suggest that switching vehicles in the U.S. to hydrogen produced by steam-reforming of methane may reduce emission of NOx, reactive hydrocarbons, CO, CO2, BC, NO3-, and NH4+, but increase CH4, H2, and SO2 (slightly).The switch may also decrease O3 over most of the U.S. but short-term near-surfaces increases may occur over low-vegetated cities (e.g., in Los Angeles and along the Boston-Washington corridor) due to loss of NOx that otherwise titrates O3. The switch is also estimated to decrease PAN, HCHO, and several other pollutants formed in the atmosphere. Isoprene may increase since fewer oxidants (OH, O3

  17. Injector having multiple fuel pegs

    Science.gov (United States)

    Hadley, Mark Allan; Felling, David Kenton

    2013-04-30

    A fuel injector is provided, including a fuel injector body, a plurality of fuel vanes, and a plurality of fuel pegs. The injector body includes a manifold and an inlet. The manifold is configured for receiving fuel, and the inlet is configured for receiving air. The fuel vanes are located within the injector body and are positioned in a direction that is generally parallel with a longitudinal axis of the injector body to orient the air flowing from the inlet. The plurality of fuel pegs are fluidly connected to the manifold and are arranged within the plurality of fuel vanes. The plurality of fuel pegs are each spaced at a distance that is about equal between each of the plurality of fuel pegs.

  18. Enzymatic fuel cells: integrating flow-through anode and air-breathing cathode into a membrane-less biofuel cell design.

    Science.gov (United States)

    Rincón, Rosalba A; Lau, Carolin; Luckarift, Heather R; Garcia, Kristen E; Adkins, Emily; Johnson, Glenn R; Atanassov, Plamen

    2011-09-15

    One of the key goals of enzymatic biofuel cells research has been the development of a fully enzymatic biofuel cell that operates under a continuous flow-through regime. Here, we present our work on achieving this task. Two NAD(+)-dependent dehydrogenase enzymes; malate dehydrogenase (MDH) and alcohol dehydrogenase (ADH) were independently coupled with poly-methylene green (poly-MG) catalyst for biofuel cell anode fabrication. A fungal laccase that catalyzes oxygen reduction via direct electron transfer (DET) was used as an air-breathing cathode. This completes a fully enzymatic biofuel cell that operates in a flow-through mode of fuel supply polarized against an air-breathing bio-cathode. The combined, enzymatic, MDH-laccase biofuel cell operated with an open circuit voltage (OCV) of 0.584 V, whereas the ADH-laccase biofuel cell sustained an OCV of 0.618 V. Maximum volumetric power densities approaching 20 μW cm(-3) are reported, and characterization criteria that will aid in future optimization are discussed. Copyright © 2011 Elsevier B.V. All rights reserved.

  19. Efficient removal of nitrobenzene and concomitant electricity production by single-chamber microbial fuel cells with activated carbon air-cathode.

    Science.gov (United States)

    Zhang, Enren; Wang, Feng; Zhai, Wenjing; Scott, Keith; Wang, Xu; Diao, Guowang

    2017-04-01

    Single-chamber microbial fuel cells (S-MFCs) with bio-anodes and activated carbon (AC) air-cathodes showed high nitrobenzene (NB) tolerance and NB removal with concomitant electricity production. The maximum power over 25Wm -3 could be obtained when S-MFCs were operated in the NB loading range of 1.2-6.2molm -3 d -1 , and stable electricity production over 13.7Wm -3 could be produced in a NB loading range of 1.2-14.7molm -3 d -1 . The present S-MFCs exhibited high NB removal performance with NB removal efficiency over 97% even when the NB loading rate was increased to 17.2molm -3 d -1 . The potential NB reduced product (i.e. aniline) could also be effectively removed from influents. The findings in this study means that single-chamber MFCs assembled with pre-enriched bio-anodes and AC air-cathodes could be developed as effective bio-electrochemical systems to remove NB from wastewaters and to harvest energy instead of consuming energy. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Bifunctional quaternary ammonium compounds to inhibit biofilm growth and enhance performance for activated carbon air-cathode in microbial fuel cells

    Science.gov (United States)

    Li, Nan; Liu, Yinan; An, Jingkun; Feng, Cuijuan; Wang, Xin

    2014-12-01

    The slow diffusion of hydroxyl out of the catalyst layer as well as the biofouling on the surface of cathode are two problems affecting power for membrane-less air-cathode microbial fuel cells (MFCs). In order to solve both of them simultaneously, here we simply modify activated carbon air-cathode using a bifunctional quaternary ammonium compound (QAC) by forced evaporation. The maximum power density reaches 1041 ± 12 mW m-2 in an unbuffered medium (0.5 g L-1 NaCl), which is 17% higher than the control, probably due to the accelerated anion transport in the catalyst layer. After 2 months, the protein content reduced by a factor of 26 and the power density increases by 33%, indicating that the QAC modification can effectively inhibit the growth of cathodic biofilm and improve the stability of performance. The addition of NaOH and QAC epoxy have a negative effect on power production due to the clogging of pores in catalyst layer.

  1. Increased power from a two-chamber microbial fuel cell with a low-pH air-cathode compartment

    Energy Technology Data Exchange (ETDEWEB)

    Erable, Benjamin; Etcheverry, Luc; Bergel, Alain [Laboratoire de Genie Chimique, CNRS-Universite de Toulouse, 5 rue Paulin Talabot BP1301, 31106 Toulouse (France)

    2009-03-15

    Pt-supported air-cathodes still need improvement if their application in MFC technology is to be sustainable. In this context, the efficiency of an air-cathode was studied with respect to the pH of the solution it was exposed to. Voltammetry showed that oxygen reduction was no longer limited by H{sup +} availability for pH lower than 3.0. A new MFC was designed with a catholyte compartment setup between the anode compartment and the air-cathode. With a catholyte compartment at pH 1.0, the MFC provided up to 5 W/m{sup 2}, i.e., 2.5-fold the power density obtained with the same anode and cathode in a single-chamber MFC working at pH 7.5. Current density exceeded 20 A/m{sup 2}. The benefit of low-pH in the catholyte chamber largely counterbalanced the mass transfer hindrance due the membrane that separated the two compartments. The MFC kept 66% its performance during nine days of continuous operation. (author)

  2. Systematic Study of Separators in Air-Breathing Flat-Plate Microbial Fuel Cells—Part 2: Numerical Modeling

    Directory of Open Access Journals (Sweden)

    Sona Kazemi

    2016-01-01

    Full Text Available The separator plays a key role on the performance of passive air-breathing flat-plate MFCs (FPMFC as it isolates the anaerobic anode from the air-breathing cathode. The goal of the present work was to study the separator characteristics and its effect on the performance of passive air-breathing FPMFCs. This was performed partially through characterization of structure, properties, and performance correlations of eight separators presented in Part 1. Current work (Part 2 presents a numerical model developed based on the mixed potential theory to investigate the sensitivity of the electrode potentials and the power output to the separator characteristics. According to this numerical model, the decreased peak power results from an increase in the mass transfer coefficients of oxygen and ethanol, but mainly increasing mixed potentials at the anode by oxygen crossover. The model also indicates that the peak power is affected by the proton transport number of the separator, which affects the cathode pH. Anode pH, on the other hand, remains constant due to application of phosphate buffer solution as the electrolyte. Also according to this model, the peak power is not sensitive to the resistivity of the separator because of the overshadowing effect of the oxygen crossover.

  3. The Role of Molecule Clustering by Hydrogen Bond in Hydrous Ethanol on Laminar Burning Velocity

    Directory of Open Access Journals (Sweden)

    I Made Suarta

    2016-01-01

    Full Text Available The role of hydrogen bond molecule clustering in laminar burning velocities was observed. The water in hydrous ethanol can change the interaction between water-ethanol molecules. A certain amount of water can become oxygenated which increases the burning velocity. The hydrogen bond interaction pattern of ethanol and water molecules was modeled. Based on the molecular model, azeotropic behavior emerges from ethanol-water hydrogen bond, which is at a 95.1%v composition. The interaction with water molecule causes the ethanol molecule to be clustered with centered oxygenated compound. So, it supplies extra oxygen and provides intermolecular empty spaces that are easily infiltrated by the air. In the azeotropic composition, the molecular bond chain is the shortest, so hypothetically the burning velocity is anticipated to increase. The laminar burning velocity of ethanol fuel was tested in a cylindrical explosion bomb in lean, stoichiometric, and rich mixtures. The experimental result showed that the maximum burning velocity occurred at hydrous ethanol of 95.5%v composition. This discrepancy is the result of the addition of energy from 7.7% free ethanol molecules that are not clustered. At the rich mixture, the burning velocity of this composition is higher than that of anhydrous ethanol.

  4. 40 CFR 92.113 - Fuel specifications.

    Science.gov (United States)

    2010-07-01

    ... mixed fuel) other than diesel fuel, or natural gas fuel (e.g., methanol), and which are expected to use...) CONTROL OF AIR POLLUTION FROM LOCOMOTIVES AND LOCOMOTIVE ENGINES Test Procedures § 92.113 Fuel...) of this section shall be reported in accordance with § 92.133. (b) Natural gas test fuel (compressed...

  5. Combustion Characteristics for Turbulent Prevaporized Premixed Flame Using Commercial Light Diesel and Kerosene Fuels

    Directory of Open Access Journals (Sweden)

    Mohamed S. Shehata

    2014-01-01

    Full Text Available Experimental study has been carried out for investigating fuel type, fuel blends, equivalence ratio, Reynolds number, inlet mixture temperature, and holes diameter of perforated plate affecting combustion process for turbulent prevaporized premixed air flames for different operating conditions. CO2, CO, H2, N2, C3H8, C2H6, C2H4, flame temperature, and gas flow velocity are measured along flame axis for different operating conditions. Gas chromatographic (GC and CO/CO2 infrared gas analyzer are used for measuring different species. Temperature is measured using thermocouple technique. Gas flow velocity is measured using pitot tube technique. The effect of kerosene percentage on concentration, flame temperature, and gas flow velocity is not linearly dependent. Correlations for adiabatic flame temperature for diesel and kerosene-air flames are obtained as function of mixture strength, fuel type, and inlet mixture temperature. Effect of equivalence ratio on combustion process for light diesel-air flame is greater than for kerosene-air flame. Flame temperature increases with increased Reynolds number for different operating conditions. Effect of Reynolds number on combustion process for light diesel flame is greater than for kerosene flame and also for rich flame is greater than for lean flame. The present work contributes to design and development of lean prevaporized premixed (LPP gas turbine combustors.

  6. Bluff Body Fuel Mixer

    Science.gov (United States)

    Cheung, Albert K. (Inventor); Hoke, James B. (Inventor); McKinney, Randal G. (Inventor)

    2017-01-01

    A combustor is provided. The combustor may include an axial fuel injection system, and a radial fuel injection system aft of the axial fuel injection system. The axial fuel injection system includes a mixer having a bluff body at an exit port of the mixer, and a fuel injector disposed within the mixer. A fuel and air mixer is also provided and comprises an outer housing with an exit port and a bluff body. The bluff body extends across the exit port of the outer housing. A fuel injection system is also provided. The systems comprise a mixer having a bluff body at an exit port of the mixer and a fuel injector disposed within the mixer.

  7. Improving the Surface Properties of Inconel 718 BY Applying a CO2 Laser Heat Treatment to a High-Velocity Oxy-Fuel Coating of WC-CrCo Powder

    Science.gov (United States)

    Cho, T. Y.; Yoon, J. H.; Joo, Y. K.; Zhang, S. H.; Cho, J. Y.; Kang, J. H.; Chun, H. G.; Kwon, S. C.; Li, Ming-Xi

    A micron-sized WC-CrCo powder was coated onto an IN718 substrate using high-velocity oxy-fuel (HVOF) thermal spraying. To further improve the surface properties, the HVOF coating was heat-treated by a CO2 laser. The surface properties of both the coating and the laser-heated coating were then compared. The HVOF optimal coating process (OCP) for a coating with the highest surface hardness was determined with the Taguchi program. The friction and wear behaviors of the coating, an electrolytic hard chrome (EHC)-plated coating and IN718, were comparatively investigated via a reciprocating sliding wear test at both 25 and 450°C. The friction coefficient (FC) for all three samples decreased when the sliding surface temperature increased from 25 to 450°C. The FC of the coating decreased with increasing surface temperature: 0.33 ± 0.02 at 25°C to 0.26 ± 0.02 at 450°C the coating had the lowest FC among the three samples. At both temperatures, the coating wear depth (WD) was smaller than those of the EHC sample and IN718. At room temperature, WC-CrCo and the EHC coatings had good wear resistance and had only a shallow WD. IN718, however, had poor wear resistance with 50 μm deep grooves created from fretting corrosion that arose during the 1500 reciprocating slides (2.5 Hz, 10 min sliding wear test). At 450°C, the coating WDs were much shallower than those for the EHC coating and IN718: 0.5-μm deep grooves compared to 60-70-μm deep grooves. These results proved that the coating provided a protective coating for IN718 and other metal components. With the OCP coating fabricated from the powders on the IN718 surface, the surface hardness increased 316% from 399 Hv to 1260 Hv. Furthermore, by laser heating the coating surface for 0.6 s, the hardness increased 44% from 1260 ±30 Hv to 1820 ±100 Hv, porosity decreased more than five times from 2.2 ± 0.3% to 0.4 ± 0.1%, and the coating thickness decreased 17% from 300 to 250 μm. These results showed that both the WC

  8. Development of a fuel flexible, air-regulated, modular, and electrically integrated SOFC-system (FlameSOFC)

    Energy Technology Data Exchange (ETDEWEB)

    Voss, S.; Trimis, D. [TU Bergakademie Freiberg (Germany). Inst. of Thermal Engineering; Valldorf, J. [VDI/VDE Innovation + Technik GmbH (Germany)

    2010-07-01

    The present paper summarizes experimental results from the operation of the SOFC based micro-CHP unit developed within the framework of the project FlameSOFC. The project is co-financed by the European Commission as an Integrated Project within the 6{sup th} framework program. The objective is the development of an innovative SOFC-based micro-CHP system capable of operating with different gaseous and liquid fuels and fulfilling the technological and market requirements at a European level. The partners involved in the FlameSOFC project bring together a sufficient number of important European actors on the scientific, research and industry level including SMEs and industrial partners from the heating sector. The presented work concerns the operation of the 2{sup nd} phase prototype FlameSOFC system, with a 1 kW{sub el.} SOFC stack and natural gas as feedstock. (orig.)

  9. Scalable air cathode microbial fuel cells using glass fiber separators, plastic mesh supporters, and graphite fiber brush anodes

    KAUST Repository

    Zhang, Xiaoyuan

    2011-01-01

    The combined use of brush anodes and glass fiber (GF1) separators, and plastic mesh supporters were used here for the first time to create a scalable microbial fuel cell architecture. Separators prevented short circuiting of closely-spaced electrodes, and cathode supporters were used to avoid water gaps between the separator and cathode that can reduce power production. The maximum power density with a separator and supporter and a single cathode was 75±1W/m3. Removing the separator decreased power by 8%. Adding a second cathode increased power to 154±1W/m3. Current was increased by connecting two MFCs connected in parallel. These results show that brush anodes, combined with a glass fiber separator and a plastic mesh supporter, produce a useful MFC architecture that is inherently scalable due to good insulation between the electrodes and a compact architecture. © 2010 Elsevier Ltd.

  10. Anolyte recycling enhanced bioelectricity generation of the buffer-free single-chamber air-cathode microbial fuel cell.

    Science.gov (United States)

    Ren, Yueping; Chen, Jinli; Shi, Yugang; Li, Xiufen; Yang, Na; Wang, Xinhua

    2017-11-01

    Anolyte acidification is an inevitable restriction for the bioelectricity generation of buffer-free microbial fuel cells (MFCs). In this work, acidification of the buffer-free KCl anolyte has been thoroughly eliminated through anolyte recycling. The accumulated HCO 3 - concentration in the recycled KCl anolyte was above 50mM, which played as natural buffer and elevated the anolyte pH to above 8. The maximum power density (P max ) increased from 322.9mWm -2 to 527.2mWm -2 , which is comparable with the phosphate buffered MFC. Besides Geobacter genus, the gradually increased anolyte pH and conductivity induced the growing of electrochemically active Geoalkalibacter genus, in the anode biofilm. Anolyte recycling is a feasible strategy to strengthen the self-buffering capacity of buffer-free MFCs, thoroughly eliminate the anolyte acidification and prominently enhance the electric power. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Characterization of bacterial and archaeal communities in air-cathode microbial fuel cells, open circuit and sealed-off reactors

    KAUST Repository

    Chehab, Noura A.

    2013-06-18

    A large percentage of organic fuel consumed in a microbial fuel cell (MFC) is lost as a result of oxygen transfer through the cathode. In order to understand how this oxygen transfer affects the microbial community structure, reactors were operated in duplicate using three configurations: closed circuit (CC; with current generation), open circuit (OC; no current generation), and sealed off cathodes (SO; no current, with a solid plate placed across the cathode). Most (98 %) of the chemical oxygen demand (COD) was removed during power production in the CC reactor (maximum of 640 ± 10 mW/m 2), with a low percent of substrate converted to current (coulombic efficiency of 26.5 ± 2.1 %). Sealing the cathode reduced COD removal to 7 %, but with an open cathode, there was nearly as much COD removal by the OC reactor (94.5 %) as the CC reactor. Oxygen transfer into the reactor substantially affected the composition of the microbial communities. Based on analysis of the biofilms using 16S rRNA gene pyrosequencing, microbes most similar to Geobacter were predominant on the anodes in the CC MFC (72 % of sequences), but the most abundant bacteria were Azoarcus (42 to 47 %) in the OC reactor, and Dechloromonas (17 %) in the SO reactor. Hydrogenotrophic methanogens were most predominant, with sequences most similar to Methanobacterium in the CC and SO reactor, and Methanocorpusculum in the OC reactors. These results show that oxygen leakage through the cathode substantially alters the bacterial anode communities, and that hydrogenotrophic methanogens predominate despite high concentrations of acetate. The predominant methanogens in the CC reactor most closely resembled those in the SO reactor, demonstrating that oxygen leakage alters methanogenic as well as general bacterial communities. © 2013 Springer-Verlag Berlin Heidelberg.

  12. Tubular Ridge Surfaces with Intensified Heat Exchange and Technology of Their Manufacturing for Air Coolers of Fuel and Energy Complex

    Directory of Open Access Journals (Sweden)

    V. Кuntysh

    2013-01-01

    Full Text Available The paper presents designs of bimetallic ridge pipes (BRP with spirally-wound aluminium KLM-edges for heat exchange air coolers. Heat exchange BRP differ from the applied ones in heat-transfer coefficient which is higher by 10–15 %, extended temperature of applicability up to 320 °С for a cooled heat carrier at the pipe input, higher thermal reliability at alternating thermal burdens, current consumption for their manufacturing which is less by 1.8–2.5-fold, aluminium consumption which is less up to 1.8-fold, manufacturability in batch production,  availability high-production equipment.

  13. Effect of indoor air pollution from biomass and solid fuel combustion on prevalence of self-reported asthma among adult men and women in India: findings from a nationwide large-scale cross-sectional survey.

    Science.gov (United States)

    Agrawal, Sutapa

    2012-05-01

    Increasing prevalence of asthma in developing countries has been a significant challenge for public health in recent decades. A number of studies have suggested that ambient air pollution can trigger asthma attacks. Biomass and solid fuels are a major source of indoor air pollution, but in developing countries the health effects of indoor air pollution are poorly understood. In this study we examined the effect of cooking smoke produced by biomass and solid fuel combustion on the reported prevalence of asthma among adult men and women in India. The analysis is based on 99,574 women and 56,742 men aged between 20 and 49 years included in India's third National Family Health Survey conducted in 2005-2006. Effects of exposure to cooking smoke, determined by the type of fuel used for cooking such as biomass and solid fuels versus cleaner fuels, on the reported prevalence of asthma were estimated using multivariate logistic regression. Since the effects of cooking smoke are likely to be confounded with effects of tobacco smoking, age, and other such factors, the analysis was carried out after statistically controlling for such factors. The results indicate that adult women living in households using biomass and solid fuels have a significantly higher risk of asthma than those living in households using cleaner fuels (OR: 1.26; 95%CI: 1.06-1.49; p = .010), even after controlling for the effects of a number of potentially confounding factors. Interestingly, this effect was not found among men (OR: 0.98; 95%CI: 0.77-1.24; p = .846). However, tobacco smoking was associated with higher asthma prevalence among both women (OR: 1.72; 95%CI: 1.34-2.21; p polluting biomass fuels for cooking and heating. Decreasing household biomass and solid fuel use and increasing use of improved stove technology may decrease the health effects of indoor air pollution. More epidemiological research with better measures of smoke exposure and clinical measures of asthma is needed to validate the

  14. Effectiveness of interventions to reduce indoor air pollution and/or improve health in homes using solid fuel in lower and middle income countries: protocol for a systematic review.

    Science.gov (United States)

    Quansah, Reginald; Ochieng, Caroline A; Semple, Sean; Juvekar, Sanjar; Emina, Jacques; Armah, Frederick Ato; Luginaah, Isaac

    2015-03-04

    Indoor air pollution (IAP) interventions are widely promoted as a means of reducing indoor air pollution/health from solid fuel use; and research addressing impact of these interventions has increased substantially in the past two decades. It is timely and important to understand more about effectiveness of these interventions. We describe the protocol of a systematic review to (i) evaluate effectiveness of IAP interventions to improve indoor air quality and/or health in homes using solid fuel for cooking and/or heating in lower- and middle-income countries, (ii) identify the most effective intervention to improve indoor air quality and/or health, and (iii) identify future research needs. This review will be conducted according to the National Institute for Health and Care Excellence (NICE) guidelines and will be reported following the PRISMA statement. Ovid MEDLINE, Ovid Embase, SCOPUS, and PubMed searches were conducted in September 2013 and updated in November 2014 (and include any further search updates in February 2015). Additional references will be located through searching the references cited by identified studies and through the World Health Organization Global database of household air pollution measurements. We will also search our own archives. Data extraction and risk of bias assessment of all included papers will be conducted independently by five reviewers. The study will provide insights into what interventions are most effective in reducing indoor air pollution and/or adverse health outcomes in homes using solid fuel for cooking or heating in lower- or middle-income countries. The findings from this review will be used to inform future IAP interventions and policy on poverty reduction and health improvement in poor communities who rely on biomass and solid fuels for cooking and heating. The review has been registered with PROSPERO (registration number CRD42014009768 ).

  15. Further study on the prediction of liquid fuel spray capture by v-gutter downstream of a plain orifice injector under uniform cross air flow

    Science.gov (United States)

    Cao, M.-H.; Chin, J.-S.

    On the basis of the Chin and Cao (1983) flat fan spray and fuel capture models, flame holder liquid fuel spray capture is predicted in route to a consideration of the effect of different factors on fuel spray capture for a wide range of parameters. A comparison is then undertaken between fuel spray capture by vertically and horizontally positioned flame holders, and a correlation for maximum fuel spray capture is determined. The results obtained indicate that the vertically positioned flame holder provides more effective fuel capture, as well as the ability to change fuel capture over a wide range through simple alteration of juxtaposition distance.

  16. FORMALIZATION OF DIESEL ENGINE OPERATION CONSIDERING THE EVALUATION OF VELOCITY DURING THE COMBUSTION PROCESSES

    Directory of Open Access Journals (Sweden)

    V. P. Litvinenko

    2015-10-01

    Full Text Available Purpose. Under modern conditions the applying methods and design models as well as the evaluation of the operational characteristics of diesel engines do not completely take into consideration the specifics of the combustion processes. In part, such situation is characterized by the complexity of considering of varied by its nature processes that haven’t been completely investigated. In this context it is necessary to find the new methods and models which would provide relatively simple solutions through the use of integrated factors based on the analysis of parameters of diesel engines. Methodology. The proposed algorithms for the estimating of the combustion process in the form of volumetric and linear velocities is based on the well-known parameters of power and mean effective pressure and allows to compare the efficiency of their behavior in various versions of diesel engines. Findings. The author specified that the volumetric / linear velocity ratio is characterized by some strength and depends on the geometric dimensions of the cylinder-piston group. Due to the assumptions it has become possible to consider the operation of a diesel engine as a system comprising: 1 the subsystem that provides the possibility of obtaining the thermal energy; 2 the subsystem providing the thermal energy transformation; 3 the subsystem that provides the necessary diesel engine power depending on terms of combustion of air-fuel mixture. Originality. The author of the paper proposed the indices of volumetric and linear combustion velocity of air-fuel mixture in the engine cylinder, that allow to obtain the comparative value in different modifications taking into account the possible choice of optimum ratio. Practical value. The usage of indices of volumetric and linear velocities of the combustion processes in the engine cylinder combined with a mathematical model will simplify the method of diesels calculating. Parametric indices of the mentioned velocities

  17. Surface-oxidized cobalt phosphide used as high efficient electrocatalyst in activated carbon air-cathode microbial fuel cell

    Science.gov (United States)

    Yang, Tingting; Wang, Zhong; Li, Kexun; Liu, Yi; Liu, Di; Wang, Junjie

    2017-09-01

    Herein, we report a simplistic method to fabricate the surface-oxidized cobalt phosphide (CoP) nanocrystals (NCs), which is used as electrocatalyst for oxygen reduction reaction (ORR) in microbial fuel cell (MFC) for the first time. The corallite-like CoP NCs are successfully prepared by a hydrothermal reaction following a phosphating treatment in N2 atmosphere. When used as an ORR catalyst, cobalt phosphide shows comparable onset potential, inferior resistance, as well as a small Tafel slope with long-term stability in neutral media. The maximum power density of MFC embellished with 10% CoP reached 1914.4 ± 59.7 mW m-2, which is 108.5% higher than the control. The four-electron pathway, observed by the RDE, plays a crucial role in electrochemical catalytic activity. In addition, material characterizations indicate that the surface oxide layer (CoOx) around the metallic CoP core is important and beneficial for ORR. Accordingly, it can be expected that the as-synthesized CoP will be a promising candidate of the non-precious metal ORR electrocatalysts for electrochemical energy applications.

  18. Nanotubular MnO2/graphene oxide composites for the application of open air-breathing cathode microbial fuel cells.

    Science.gov (United States)

    Gnana Kumar, G; Awan, Zahoor; Suk Nahm, Kee; Xavier, J Stanley

    2014-03-15

    Nanotubular shaped α-MnO2/graphene oxide nanocomposites were synthesized via a simple, cost and time efficient hydrothermal method. The growth of hollow structured MnO2 nanotubes preferentially occurred along the [001] direction as evidenced from the morphological and structural characterizations. The tunnels of α-MnO2 nanotubes easily accommodated the molecular oxygen and exhibited excellent catalytic activity towards the oxygen reduction reaction over the rod structure and was further enhanced with the effective carbon support graphene oxide. The MnO2 nanotubes/graphene oxide nanocomposite modified electrode exhibited a maximum power density of 3359 mW m(-2) which is 7.8 fold higher than that of unmodified electrode and comparable with the Pt/C modified electrode. The microbial fuel cell equipped with MnO2 nanotubes/graphene oxide nanocomposite modified cathode exhibited quick start up and excellent durability over the studied electrodes and is attributed to the high surface area and number of active sites. These findings not only provide the fundamental studies on carbon supported low-dimensional transition-metal oxides but also open up the new possibilities of their applications in green energy devices. © 2013 Elsevier B.V. All rights reserved.

  19. FePO4 based single chamber air-cathode microbial fuel cell for online monitoring levofloxacin.

    Science.gov (United States)

    Zeng, Libin; Li, Xinyong; Shi, Yueran; Qi, Yefei; Huang, Daqiong; Tadé, Moses; Wang, Shaobin; Liu, Shaomin

    2017-05-15

    A bio-electrochemical strategy was developed for constructing a simple and sensitive levofloxacin (LEV) sensor based on a single chamber microbial fuel cell (SC-MFC) using FePO4 nanoparticles (NPs) as the cathode catalyst instead of traditional Pt/C. In this assembled sensor device, FePO4 NPs dramatically promoted the electrooxidation of oxygen on the cathode, which helps to accelerate the voltage output from SC-MFC and can provide a powerful guarantee for LEV detection. Scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) were used to fully characterize the FePO4 NPs. Under the optimized COD condition (3mM), the LEV with a concentration range of 0.1-1000µg/L could be detected successfully, and exhibited the excellent linear interval in the concentration range of 0.1-100µg/L. During this range of concentrations of LEV, a temporary effect on the anode of exoelectrogenic bacterial in less than 10min could occur, and then came back to the normal. It exhibited a long-term stability, maintaining the stable electricity production for 14 months of continuous running. Besides, the detection mechanism was investigated by quantum chemical calculation using density functional theory (DFT). Copyright © 2016. Published by Elsevier B.V.

  20. The combined effect of reduced fossil fuel consumption and increasing biomass combustion on Athens' air quality, as inferred from long term CO measurements.

    Science.gov (United States)

    Gratsea, Myrto; Liakakou, Eleni; Mihalopoulos, Nikos; Adamopoulos, Anastasios; Tsilibari, Eirini; Gerasopoulos, Evangelos

    2017-08-15

    To evaluate the role of biomass burning emissions, and in particular of residential wood heating, as a result of the economic recession in Greece, carbon monoxide (CO) atmospheric concentrations from five (5) stations of the National Air Pollution Monitoring Network in Athens, spanning the period 2000-2015, in conjunction with black carbon (BC) concentrations from the NOA (National Observatory of Athens) station at Thissio were analysed. The contribution of the different sources to the diurnal cycle of these two pollutants is clear, resulting to a morning peak, mainly due to traffic, and a late evening peak attributed both to fossil fuel (traffic plus central heating) and biomass combustion. Calculated morning and evening integrals of CO peaks, for the investigated period, show consistent seasonal modulations, characterised by low summer and high winter values. The summer and winter morning CO peak integrals demonstrate an almost constant decreasing trend of CO concentrations over time (by almost 50% since 2000), attributed to the renewal of passenger car fleet and to reduced anthropogenic activities during the last years. On the other hand, an increase of 23%-78% (depending on the monitoring site) in the winter evening integrals since 2012, provides evidence of the significant contribution of biomass combustion, which has prevailed over fossil fuel for domestic heating. CO emitted by wood burning was found to contribute almost 50% to the total CO emissions during night time (16:00-5:00), suggesting that emissions from biomass combustion have gained an increasing role in atmospheric pollution levels in Athens. Copyright © 2017 Elsevier B.V. All rights reserved.