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Sample records for varistores zno-cuo ferrita

  1. convencional proveniente de ferrita cúprica

    Directory of Open Access Journals (Sweden)

    NÉSTOR R. ROJAS R.

    2007-01-01

    Full Text Available Se presentan los resultados de la cianuración, de un residuo proveniente de una lixiviación de una calcina oxidada de metal blanco con alto contenido de cobre (10,6 % en la forma de ferrita cúprica, con tenores de oro y plata de 38,5 y 1085 g/Ton, respectivamente. Las extracciones de cobre en la cianuraciones son siempre más bajas que las reportadas en la literatura, pues bajo condiciones de extracción completa de oro, el cobre se disuelve tan sólo un 0,36 %, mientras que en las condiciones requeridas para una extracción del 60 % de la plata, se obtuvo una disolución cercana al 5 % de cobre. Es posible que la alta refractariedad del cobre en forma de ferrita cúprica sea la causa de la baja disolución de este metal en cianuro.

  2. Process for fabricating ZnO-based varistors

    Science.gov (United States)

    Lauf, R.J.

    The invention is a process for producing ZnO-based varistors incorporating a metal oxide dopant. In one form, the invention comprises providing a varistor powder mix of colloidal particles of ZnO and metal-oxide dopants including Bi/sub 2/O/sub 3/. The mix is hot-pressed to form a compact at temperatures below 850/sup 0/C and under conditions effecting reduction of the ZnO to sub-stoichiometric oxide. This promotes densification while restricting liquid formation and grain growth. The compact then is heated under conditions restoring the zinc oxide to stoichiometric composition, thus improving the varistor properties of the compact. The process produces fine-grain varistors characterized by a high actual breakdown voltage and a high average breakdown voltage per individual grain boundary.

  3. A comprehensible need of zinc oxide varistors in electronics technology

    International Nuclear Information System (INIS)

    Mehmood, F.S.

    2007-01-01

    A range of varistors, in terms of break down voltage, is required to protect integrated circuits, automotive systems and other modern electronics against transient over-voltages. There is a progressing need for the development and advancement of rugged and reliable varistor capable and proficient of working in harsh and callous environment like automotive Industry where greater than before use of electronics technology has led to improvements in equipment performance and presentation. There is a comprehensible need to combine triumphant and successable models developed at different length scales into an integrated framework that can be used to drive new research and guide experimental efforts and device development. The review of ZnO varistor in particular and metal-oxide varistors (MOVs) in general is presented In this article. (author)

  4. Processing and properties of ZnO-based varistors

    Energy Technology Data Exchange (ETDEWEB)

    de Bracho, E.O.

    1981-10-01

    The objective of this work is to study the influence of sintering temperature and additive content on the electrical characteristics and microstructure of ZnO based varistors with Bi/sub 2/O/sub 3/ (always present), Sb/sub 2/O/sub 3/, Co/sub 3/O/sub 4/, MnO/sub 2/ and Cr/sub 2/O/sub 3/ as additive oxides. The influence of sintering temperature and additive content on the electrical characteristics of ZnO based varistors without Bi/sub 2/O/sub 3/, but with additives from the rare-earth oxide series such as Eu/sub 2/O/sub 3/, La/sub 2/O/sub 3/, Pr/sub 6/O/sub 11/ and Ho/sub 2/O/sub 3/, is also studied. Procedures and results are presented in detail.

  5. Fabrication of an Electrically-Resistive, Varistor-Polymer Composite

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    Sanaz A. Mohammadi

    2012-11-01

    Full Text Available This study focuses on the fabrication and electrical characterization of a polymer composite based on nano-sized varistor powder. The polymer composite was fabricated by the melt-blending method. The developed nano-composite was characterized by X-ray diffraction (XRD, transmission electron microscopy (TEM, field emission scanning electron microscopy (FeSEM, and energy-dispersive X-ray spectroscopy (EDAX. The XRD pattern revealed the crystallinity of the composite. The XRD study also showed the presence of secondary phases due to the substitution of zinc by other cations, such as bismuth and manganese. The TEM picture of the sample revealed the distribution of the spherical, nano-sized, filler particles throughout the matrix, which were in the 10–50 nm range with an average of approximately 11 nm. The presence of a bismuth-rich phase and a ZnO matrix phase in the ZnO-based varistor powder was confirmed by FeSEM images and EDX spectra. From the current-voltage curves, the non-linear coefficient of the varistor polymer composite with 70 wt% of nano filler was 3.57, and its electrical resistivity after the onset point was 861 KΩ. The non-linear coefficient was 1.11 in the sample with 100 wt% polymer content. Thus, it was concluded that the composites established a better electrical non-linearity at higher filler amounts due to the nano-metric structure and closer particle linkages.

  6. Sintering and microstructure of ZnO varistor

    International Nuclear Information System (INIS)

    Leite, E.R.; Longo, E.; Varela, J.A.

    1987-01-01

    The sintering and microstructure of ZnO-Bi 2 O 3 (ZB) and ZuO-Sb 2 O 3 -CoO-Bi 2 O 3 (ZSCB) varistors in several temperatures, for one hour in dry air temperature were studied. The compounds were analyzed by scanning electron microscopy, X-ray diffraction, differential thermal analysis and the density and porosity were determined by mercury picnometry. The experimental results showed that the ZB and ZSCB system sinters by liquid means and that liquid will control the density and grain growth mechanisms. (E.G.) [pt

  7. Effects on the properties and microstructure of ZNO varistors

    International Nuclear Information System (INIS)

    Nemati, Z. A.; Navaei-Alvar, H.; Hooshiar-Fard, M. A.; Faghihi-Sani, M. A.

    2007-01-01

    In this research, after preparation of zinc oxide nano powder via a high energy ball mill (SPEX) and evaluation of its particle size distribution, as well as morphology, by a zeta potential particle size analyzer and transmission electron microscopy, the samples were made and sintered at different temperatures. The physical and electrical properties were measured and the microstructure was studied by scanning electron microscopy. For determining the grain size distribution, X-ray diffraction analyses were also used. Finally, the I-V characteristics of the varistors were obtained with an 1-V meter (Keithley 237). It was shown that by using nano powders produced by high energy ball milling, the electrical properties of Zn O based varistors, such as breakdown voltage and the non-linear coefficient (α), were enhanced, in comparison with micro powders. The non-linear coefficient (α) was about 60 and breakdown voltage was about 5500 V/cm. The enhancement of the properties was related to the fine and homogeneous microstructures of the samples

  8. Microstructural and electrical characteristics of rare earth oxides doped ZnO varistor films

    Science.gov (United States)

    Jiao, Lei; Mei, Yunzhu; Xu, Dong; Zhong, Sujuan; Ma, Jia; Zhang, Lei; Bao, Li

    2018-02-01

    ZnO-Bi2O3 varistor films doped with two kinds of rare earth element oxides (Lu2O3 and Yb2O3) were prepared by the sol-gel method. The effects of Lu2O3/Yb2O3 doping on the microstructure and electrical characteristics of ZnO-Bi2O3 varistor films were investigated. All samples show a homogenized morphology and an improved nonlinear relationship between the electric field (E) and current density (I). Both Yb2O3 and Lu2O3 doping can decrease the grain size of ZnO-Bi2O3 varistor films and improve the electrical properties, which have a positive effect on the development of ZnO varistor ceramics. Yb2O3 doping significantly increases the dielectric constant at low frequency. 0.2 mol. % Yb2O3 doped ZnO-Bi2O3 varistor films exhibit the highest nonlinear coefficient (2.5) and the lowest leakage current (328 μA) among Lu2O3/Yb2O3 doped ZnO-Bi2O3 varistor films. Similarly, 0.1 mol. % Lu2O3 doping increases the nonlinear coefficient to 1.9 and decrease the leakage current to 462 μA.

  9. Breakdown in ZnO Varistors by High Power Electrical Pulses; TOPICAL

    International Nuclear Information System (INIS)

    PIKE, GORDON E.

    2001-01-01

    This report documents an investigation of irreversible electrical breakdown in ZnO varistors due to short pulses of high electric field and current density. For those varistors that suffer breakdown, there is a monotonic, pulse-by-pulse degradation in the switching electric field. The electrical and structural characteristics of varistors during and after breakdown are described qualitatively and quantitatively. Once breakdown is nucleated, the degradation typically follows a well-defined relationship between the number of post-initiation pulses and the degraded switching voltage. In some cases the degraded varistor has a remnant 20(micro)m diameter hollow track showing strong evidence of once-molten ZnO. A model is developed for both electrical and thermal effects during high energy pulsing. The breakdown is assumed to start at one electrode and advance towards the other electrode as a thin filament of conductive material that grows incrementally with each successive pulse. The model is partially validated by experiments in which the varistor rod is cut at several different lengths from the electrode. Invariably one section of the cut varistor has a switching field that is not degraded while the other section(s) are heavily degraded. Based on the experiments and models of behavior during breakdown, some speculations about the nature of the nucleating mechanism are offered in the last section

  10. Microstructural evaluation of a varistor block utilized in high voltage surge arresters; Avaliacao microestrutural de um bloco varistor utilizado em para-raios de alta tensao

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, J.M. de; Dias, R.; Furtado, J.G. de M., E-mail: jma_ime@yahoo.com.b [Centro de Pesquisas de Energia Eletrica (CEPEL), Rio de Janeiro, RJ (Brazil); Assuncao, F.C.R. [Pontificia Univ. Catolica do Rio de Janeiro (PUC-Rio), RJ (Brazil)

    2010-07-01

    Varistor is a semiconductor ceramic device characterized to have a high non-linear electrical resistance, it is used as active element of surge arresters with purpose of protecting of electro-electronics systems. Its properties are directly dependents of chemical composition and microstructural characteristics, such as grain size, porosity, twins and phases distribution. This work has the objective to characterize microstructurally a commercial varistor block of ZnO used in high voltage surge arrest and from this characterization to infer aspects about of its electrical macroscopic performance. DRX and SEM-EDS were used for microstructural analysis. The microstructural evaluation allows pointing the critical points of microstructure and, suggest relevant aspects to the improvement of commercial varistor microstructure, optimizing the electrothermal behavior of the device. (author)

  11. Desarrollo y caracterización de varistores de óxido de cinc

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    Attolini, P.

    2001-06-01

    Full Text Available In this paper the electric behaviour and other structural, physicochemical and micro structural characteristics of four commercial varistors of different makers were studied and compared with other three developed prototypes. The comparative results permitted to know the causes of the prototypes low performance, concluding that with a better control of the raw materials processing, the pre-forming and the thermal treatment, in conjunction with an increase of the Sb2O3 quantities in the prototype M2, a varistor with a good performance may be produced.

    En el presente trabajo se comparan el comportamiento eléctrico y las características estructurales (DRX, fisicoquímicas y microestructurales (Microscopía óptica, electrónica y microsonda de cuatro varistores comerciales de distinta procedencia con otros tres desarrollados como prototipos. El análisis comparativo de los resultados obtenidos para todos los varistores estudiados permitió conocer las causas del bajo rendimiento de los prototipos desarrollados. Un mayor control en las etapas de procesamiento de las materias primas, del prensado y del tratamiento térmico, conjuntamente con un aumento en la composición de Sb2O3 en la formulación del prototipo denominado M2 podría conducir a un varistor con buenas prestaciones de servicio.

  12. Microstructural evaluation of a varistor block utilized in high voltage surge arresters

    International Nuclear Information System (INIS)

    Andrade, J.M. de; Dias, R.; Furtado, J.G. de M.; Assuncao, F.C.R.

    2010-01-01

    Varistor is a semiconductor ceramic device characterized to have a high non-linear electrical resistance, it is used as active element of surge arresters with purpose of protecting of electro-electronics systems. Its properties are directly dependents of chemical composition and microstructural characteristics, such as grain size, porosity, twins and phases distribution. This work has the objective to characterize microstructurally a commercial varistor block of ZnO used in high voltage surge arrest and from this characterization to infer aspects about of its electrical macroscopic performance. DRX and SEM-EDS were used for microstructural analysis. The microstructural evaluation allows pointing the critical points of microstructure and, suggest relevant aspects to the improvement of commercial varistor microstructure, optimizing the electrothermal behavior of the device. (author)

  13. Mild degradation processes in ZnO-based varistors: the role of Zn vacancies

    Science.gov (United States)

    Ponce, M. A.; Macchi, C.; Schipani, F.; Aldao, C. M.; Somoza, A.

    2015-03-01

    The effects of a degradation process on the structural and electrical properties of ZnO-based varistors induced by the application of dc bias voltage were analysed. Capacitance and resistance measurements were carried out to electrically characterize the polycrystalline semiconductor before and after different degrees of mild degradation. Vacancies' changes in the varistors were studied with positron annihilation lifetime spectroscopy. Variations on the potential barrier height and effective doping concentration were determined by fitting the experimental data from impedance spectroscopy measurements. These results indicate two different stages in the degradation process consistent with vacancy-like concentration changes.

  14. Síntese em reator de hidrometalurgia de nanopartícula de ferrita de cobalto

    OpenAIRE

    Araújo, Elton John Nunes de

    2017-01-01

    Investigamos a síntese de nanopartículas de ferrita de cobalto por precipitação hidrotérmica, em reator de hidrometalurgia em temperaturas entre 100 e 250°C. Foram variados os parâmetros: temperatura de síntese, composição do meio reacional, concentração da base e presença de agente complexante. As nanopartículas obtidas foram caracterizadas do ponto de vista estrutural por difração de raios-X, sua composição foi verifica por medidas de espectroscopia por energia dispersiva de raios-x (EDX) e...

  15. Study of positron lifetime spectrum for Zn O varistor ceramics fabricated by Sol-gel route

    International Nuclear Information System (INIS)

    Li Xigui; Wei Shutao; Zhang Ruiying; Cheng Guosheng; Dai Xianqi; Zhang Jincang; Xing Huaimin

    2000-01-01

    An investigation of positron lifetime spectrum for ZnO varistor ceramics fabricated by Sol-gel route was carried out. The relationship between lifetime parameters and the densification and nonlinear coefficient α was given. The dependence of electrical properties on sintering temperature and duration was discussed

  16. Degradación y recuperación de varistores de ZnO

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    Ramírez, M. A.

    2006-10-01

    Full Text Available In the present work it was studied the main aspect that influences on degradation and physical-chemical properties at grainboundary region of metal oxide varistors and its consequences on microstructure and nonohmic electric properties. Based on the comprehension of the degradation aspects it was proposed some methodologies to recover the varistors nonohmic properties after being failed with long (2000 μs and short current pulses (8/20 μs. Our analysis shown that one of the cause of degradation process is related to the lowering of oxygen species amount at grain-boundary region. Therefore, it is possible to re-promote oxygen enrichment of such regions by specific thermal treatments in rich oxygen atmospheres (the best condition found in the present work was temperatures around 900°C for 2 h at an oxygen flux of 15 l/h. The proposed nonohmic properties recovering procedure appear to be valid for all kind metal oxide varistors studied and is very important from technological point of view.

    En este trabajo se estudia el fenómeno de la degradación eléctrica en varistores basados en ZnO y los factores físico-químicos que influyen en ella, así como su efecto sobre la microestructura y propiedades eléctricas. Con la comprensión de los fenómenos de degradación se proponen metolodogías para recuperar varistores después de fallados con pulsos de corriente de larga (2000 μs y corta duración (8/20 μs. Los análisis mostraron que una de las causas de degradación es la pérdida de especies de oxígeno en el borde de grano, permitiendo implementar un tratamiento térmico posterior en atmósfera enriquecida de oxígeno para recuperar las propiedades del varistor (temperatura de 900°C por dos horas y 15 l/h de flujo de oxígeno, fue la mejor condición. El procedimiento de recuperación propuesto es válido para todos los sistemas varistores con base en óxido metálico, sean comerciales o no y es de gran interés tecnológico, pues

  17. SÍNTESIS Y CARACTERIZACIÓN DE FERRITAS DE Cd, Pb y Mn VÍA HIDROQUÍMICA

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    Eliazar Aquino

    2010-01-01

    Full Text Available El objetivo del presente trabajo ha sido obtener por vía hidroquímica y bajo condiciones optimizadas, ferritas de cadmio, plomo y manganeso y realizar comparaciones de sus características químicas, fìsicoquímicas y estequiométricas. Se ha podido corroborar que el proceso de formación de ferritas in situ bajo condiciones óptimas, permite eliminar metales pesados como los evaluados de los medios acuosos, con eficiencias superiores al 98%. De igual manera se logran obtener estequiometrías definidas que permiten proponer los mecanismos de reacción que tienen lugar, toda vez que pueden ser justificados a partir de las estequiometrías logradas y por las diferentes técnicas empleadas en su caracterización. Se han podido dilucidar los mecanismos de sustitución de los iones Fe2+ por los metales divalentes como los estudiados en las estructuras de espinela inversa de estas ferritas y su correlación con las propiedades magnéticas de las mismas.

  18. Synthesis of ZnO based nanopowders via a non-hydrolytic sol gel technique and their densification behaviour and varistor properties

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    Shereef Anas

    2010-03-01

    Full Text Available Hexagonal nanocrystalline varistor grade ZnO particles with size 50 nm and the specific surface area of 28 m2/g have been prepared by non-aqueous gelation technique involving diethylene glycol and triethanolamine. The as-prepared varistor nanopowders were analyzed with the support of XRD, TG/DTA, FTIR, TMA, SEM and TEM. Varistor discs were fabricated by pressing and their densification was studied at 850, 950, 1050 and 1150°C. The evolution of varistor microstructures, extent of grain growth and the influence of microstructure on the I-V properties were explored and presented.

  19. Tratamiento mecanoquímico de la ferrita MgFe2O4

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    Torralba, J. M.

    2000-06-01

    Full Text Available Powder of MgFe2O4, previously prepared by solid state reaction, was mechanochemically treated in a centrifugal ball mill in air atmosphere. Different milling conditions has been employed varying ball/powder mass ratio. After low milling time a strong reduction on crystallite size has been detected while the strain lattice increase slowly. The presence of α-Fe2O3 was also observed at different milling time, depending on milling conditions, by means of X-Ray diffraction experiments. Magnetic transition temperatures were evaluated using a thermogravimetric analyser, equipped with a small permanent magnet. An attempt of dependence of magnetic properties with crystallite size has been established.La ferrita MgFe2O4, en forma de polvo y previamente preparada por reacción en estado sólido, se ha sometido a un proceso de molienda mecánica en atmósfera de aire usando un molino centrífugo. Se emplearon diferentes condiciones de molienda variando la relación de peso bolas/ferrita. La variación del tamaño de dominio cristalino o de cristalita y lamicrodeformaciones de red a escala de celda unidad se evaluaron mediante difracción de rayos-X de polvo. Para bajos tiempos de molienda se observó una acusada disminución del tamaño de dominio cristalino, mientras que las microdeformaciones de la red experimentaron un ligero aumento. Así mismo, a partir de determinados tiempos de molienda, se detectó la presencia de α-Fe2O3. Las temperaturas de transición magnética fueron evaluadas a partir de un analizador termogravimétrico equipado con un pequeño imán permanente y se estableció un correlación entre la temperatura de Curie y el tamaño de dominio cristalino.

  20. The study on ZnO ceramic varistors by positron annihilation

    International Nuclear Information System (INIS)

    Huang, M.; Gu, H.; He, Y.; Wang, Y.; Yang, J.; Chen, X.

    1992-01-01

    The relations among nonlinear exponents (α), instantaneous voltage (Va) and various additive agents in ZnO varistors were studied by positron lifetime and Doppler broadening S parameters, and discussed: (1) The influence of sample homogeneity and various plating foils on S parameters; (2) The relations of τ and S with electric character; (3) The relations of τ, S, and α with elements in additive agents

  1. Effect of thermal treatment on electrical properties and varistors degradation of ZnO

    International Nuclear Information System (INIS)

    Leite, E.R.; Cerri, J.A.; Longo, E.; Catao, P.S.P.; Varela, J.A.

    1990-01-01

    ZnO varistors obstained by conventional processing was heat treated and their electrical properties and degradation was analyzed. Infra-red spectroscopy, X-Ray diffraction and current-voltage curves were used to analize the properties with type of thermal cycle. The results showed that heat treatment promote stabilization against degradation and that exist a linear dependence of leakage current with square root of time. (author) [pt

  2. Electrical degradation of double-Schottky barrier in ZnO varistors

    Energy Technology Data Exchange (ETDEWEB)

    He, Jinliang, E-mail: hejl@tsinghua.edu.cn; Cheng, Chenlu; Hu, Jun [The State Key Lab of Power System, Department of Electrical Engineering, Tsinghua University, Beijing 100084 (China)

    2016-03-15

    Researches on electrical degradation of double-Schottky barrier in ZnO varistors are reviewed, aimed at the constitution of a full picture of universal degradation mechanism within the perspective of defect. Recent advances in study of ZnO materials by atomic-scale first-principles calculations are partly included and discussed, which brings to our attention distinct cognition on the native point defects and their profound impact on degradation.

  3. Processing parameters for ZnO-based thick film varistors obtained by screen printing

    Directory of Open Access Journals (Sweden)

    de la Rubia, M. A.

    2006-06-01

    Full Text Available Thick film varistors based on the ZnO-Bi2O3-Sb2O3 system have been prepared by screen printing on dense alumina substrates. Different processing parameters like the paste viscosity, burn out and sintering cycles, green and sintered thickness, have been studied to improve the processing of ZnO-based thick film varistors. Starting powders were pre-treated in two different ways in order to control both the Bi-rich liquid phase formation and the excessive volatilization of Bi2O3 during sintering due to the high area/volume ratio of the thick films. Significant changes have been observed in the electrical properties related to the different firing schedule and selection of the starting powders.

    Se han preparado varistores basados en el sistema ZnO-Bi2O3-Sb2O3 en forma de lámina gruesa sobre sustratos de alúmina densa. Diferentes parámetros del procesamiento como la viscosidad de la pasta, los ciclos de calcinación y sinterización y el espesor en verde y sinterizado han sido estudiados para mejorar el procesamiento de los varistores basados en ZnO preparados en forma de lámina gruesa. Los polvos de partida fueron pretratados de dos formas diferentes con el objetivo de controlar la formación de la fase líquida rica en bismuto y la excesiva volatilización de Bi2O3 durante la sinterización debida a la alta relación área-volumen de las láminas gruesas. Se han observado cambios significativos en las propiedades eléctricas relacionadas con los diferentes ciclos de calcinado y con la selección de los polvos de partida.

  4. Analysis of electrical and microstructural characteristics of a ZnO-based varistor doped with rare earth oxide

    International Nuclear Information System (INIS)

    Andrade, J.M. de; Dias, R.; Furtado, J.G. de M.; Assuncao, F.C.R.

    2010-01-01

    Varistor is a semiconductor device, used in the protection of electrical systems, characterized to have a high no-linear electric resistance. Its properties are directly dependents of its chemical composition and microstructural characteristics. In this work were analyzed microstructural and electrical characteristics of a ZnO-based varistor doped with rare earth oxide, with chemical composition (mol%) 98,5.ZnO - 0,3.Pr 6 O 11 - 0,2.Dy 2 O 3 - 0,9.Co 2 O 3 - 0,1.Cr 2 O 3 . X-ray diffraction for phase characterization, scanning electron microscopy and energy dispersive X-ray spectroscopy were used for microstructural analysis. Measurement of average grain size and electrical and dielectric characteristics complete the characterization. The results show the formation of biphasic microstructure and with high densification, presenting relevant varistors characteristics but that would need improvements.(author)

  5. Development and fabrication process for ZnO based varistors for medium voltage arresters 13000 V to 34000 V; Desarrollo y produccion de varistores de ZnO dopados para media tension 13000 V a 34000 V

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez Rolon, B.; Ireta Moreno, F. [Facultad de Ingenieria Mecanica, Electrica y Electronica, Universidad de Guanajuato, Salamanca, Guanajuato (Mexico)]. E-mail: barbara@salamanca.ugto.mx; fireta@salamanca.ugto.mx

    2011-04-15

    The fabrication process for ZnO doped varistor blocks with Sb2O3/ Bi2O3 to medium tension of 13000 V to 34000 V, and was optimised in terms of a starting composition and firing temperatures with amounts for Sb2O3/ Bi2O3 ratios of 1.7 by dry pressing, and fired in the temperature 1150 degrees Celsius {+-}2 degrees Celsius. The microstructure characteristics were analysed across the surface of the varistor blocks in order to evaluate their microstructure homogeneity. Their current-voltage I-V and energy handling capabilities were also determined. Characteristics and electrical properties of the varistor blocks are discussed. [Spanish] El proceso de fabricacion para varistores de media tension de 13000 V a 34000 V de ZnO consistio en dopar con Sb2O3, Bi2O3 y optimizarlos en terminos de la composicion de inicio, con una relacion de Sb2O3/Bi2O3 de 1.7, y el uso de aditivos para ceramicas, la temperatura de sinterizado fue de 1150 grados centigrados {+-}2 grados centigrados. Se investigo la homogeneidad de la microestructura. Se determinaron las propiedades electricas mediante la determinacion de la grafica I-V. Las caracteristicas electricas son discutidas.

  6. Effect of SrO on the electrical barrier formation and microstructure of TiO{sub 2} varistors

    Energy Technology Data Exchange (ETDEWEB)

    Delbrücke, Tiago, E-mail: tiagodt@gmail.com [Laboratory of Biomaterials & Advanced Ceramics, Engineering Materials Department, Federal University of Rio Grande do Sul, 91501-970, Porto Alegre, RS (Brazil); Pianaro, Sidnei A. [Interdisciplinary Laboratory of Ceramic Materials/LIMAC, Department of Materials Engineering, State University of Ponta Grossa, 84031-510, Ponta Grossa, PR (Brazil); Schmidt, Igor [Laboratory of Biomaterials & Advanced Ceramics, Engineering Materials Department, Federal University of Rio Grande do Sul, 91501-970, Porto Alegre, RS (Brazil); Cava, Sergio [Advanced Crystal Growth and Photonics, Technology Development Center, Federal University of Pelotas, 96010-900, Pelotas, RS (Brazil); Jurado, Jose R.; Sousa, Vânia C. [Laboratory of Biomaterials & Advanced Ceramics, Engineering Materials Department, Federal University of Rio Grande do Sul, 91501-970, Porto Alegre, RS (Brazil)

    2016-12-01

    TiO{sub 2}-based varistor materials with SrO dopants were prepared by the mechanical mixed oxides synthesis technique using conventional sintering at 1400 °C. I−V and microstructural characterization were performed. The composition range of 0.50–2.00 mol % SrO was studied and compared to pure TiO{sub 2}. Experimental evidence shows that small amounts of SrO improve the nonlinear properties of the samples significantly. Optimal varistor characteristics α = 5.50 and E{sub b} = 345 V/cm, were obtained with 1.00 mol % SrO-doped TiO{sub 2}. SrO in larger amounts causes the formation of precipitates of the SrTiO{sub 3} layer on the microstructure, being deleterious to the electrical properties. Therefore, dopants such as SrO or TiO{sub 2} play a special role in the morphology of the grain boundary and nonlinear response of these materials. An atomic defect model based on the double barrier Schottky type can be adopted to explain the formation of electrical barriers in TiO{sub 2} grain boundaries. - Highlights: • Training an effective potential barrier in the grain boundary, measured by electrical measurements on AC and DC. • Microstructure versus electrical properties. • Good properties getting varistor using a single dopant, forming a varistor binary system based on TiO{sub 2}.

  7. Characterization of ZnO-degraded varistors used in high-tension devices

    International Nuclear Information System (INIS)

    Ramirez, M.A.; Simoes, A.Z.; Marquez, M.A.; Maniette, Y.; Cavalheiro, A.A; Varela, J.A.

    2007-01-01

    The effects of the degradation process on the structural, microstructural and electrical properties of ZnO-based varistors were analyzed. Rietveld refinement showed that the BiO 2-x phase is affected by the degradation process. Besides the changes in the spinel phase, the degradation process also affects the lattice microstrain in the ZnO phase. Scanning electron microscopy analysis showed electrode-melting failure, while wavelength dispersive X-ray spectroscopy qualitative analysis showed deficiency of oxygen species at the grain boundaries in the degraded samples. Atomic force microscopy using electrostatic mode force illustrated a decrease in the charge density at the grain boundaries of the degraded sample. Transmission electron microscopy showed submicrometric spinel grains embedded in a ZnO matrix, but their average grain size is smaller in the degraded sample than in the standard one. Long pulses appeared to be more harmful for the varistors' properties than short ones, causing higher leakage current values. The electrical characteristics of the degraded sample are partially restored after heat treatment in an oxygen-rich atmosphere

  8. Gum Tragacanth-Mediated Synthesis of Nanocrystalline ZnO Powder for Use in Varistors

    Science.gov (United States)

    Liu, Ting-Ting; Wang, Mao-Hua; Su, Hang; Chen, Xi; Chen, Chao; Zhang, Ruo-Chen

    2015-10-01

    Zinc oxide nanopowders were synthesized by a sol-gel method with gum tragacanth and zinc nitrate as raw materials. Gum tragacanth was used as stabilizer to control the mobility of zinc cations and the growth of the nanopowders. Thermo-gravimetric analysis, x-ray diffraction, Fourier-transform infrared spectroscopy, transmission electron microscopy, energy dispersive x-ray spectroscopy, and scanning electron microscopy were used to characterize the as-prepared samples. Zinc oxide (ZnO) nanoparticles calcined at different temperatures had a hexagonal wurtzite structure with average particle size ranging from 32.29 nm to 42.83 nm. The crystallinity of ZnO nanoparticles was improved by increasing the calcination temperature. The density of ZnO varistor ceramics sintered at 1150°C for 2 h in air was 5.46 g/cm3, which was 97.5% of the theoretical density, their breakdown voltage was 4572 V/cm, and their nonlinear coefficient was ~16.8. This method can be used as an excellent alternative method for synthesis of ZnO nanoparticles with a plant extract as a raw material. Our experimental results show our method had the advantage of improving the electrical performance of ZnO varistors.

  9. Polyamide 6/nickel ferrite composites: morphological and structural evaluation; Compositos poliamida 6 /ferrita de niquel: avaliacao morfologica e estrutural

    Energy Technology Data Exchange (ETDEWEB)

    Menezes, P.C.F.; Santos, P.T.A.; Wanderley, A.S.D.; Costa, A.C.F.M.; Araujo, E.M., E-mail: patricia.fernandes24@hotmail.com [Universidade Federal de Campina Grande (UFCG), Campina Grande, PB (Brazil). Unidade Academica de Engenharia de Materiais

    2011-07-01

    This study aims to evaluate the influence of particle size of the load on the structure and morphology of polyamide composite 6/ferrita nickel. To obtain the composite, the polyamide 6 was previously vacuum dried at 80 ° C/48h to eliminate moisture, and then the load was incorporated as powders and as synthesized after calcination at 900°C in the mass concentration of 50%. Subsequently, the mixture was compressed using three tons to obtain the composites, which were characterized by XRD and SEM. XRD results showed the characteristic peaks of polyamide 6 and ferrite. An increase in crystallinity was observed for the composite loaded calcined at 900° C. SEM results showed a good dispersion of nickel ferrite loading in the matrix, the presence of larger clusters and evenly distributed load for the composite calcined at 900 ° C. (author)

  10. Note: Self-biased voltage to suppress secondary electrons by a ZnO varistor in a compact pulsed neutron generator

    Science.gov (United States)

    Yang, Z.; Li, X.; Li, J.; Long, J. D.; Lan, C. H.; Wang, T.; Dong, P.; He, J. L.

    2017-03-01

    A large amount of back streaming electrons will bring about a part of current drain on power supply, cause sparking or high-voltage breakdowns, and affect the neutron yield and waveform for a compact sealed-tube pulsed neutron generator. A novel idea which uses a ZnO varistor to provide a constant self-biased voltage to suppress the secondary electrons is introduced. The I-V curve for the ZnO varistor was measured in the experiment. The effects of suppressing the secondary electrons were investigated using a ZnO varistor, linear resistors, and an independent power supply, respectively. The results show that the secondary electrons are suppressed effectively by the compact ZnO varistor, while not increasing the size and the component of the device. It is a promising design for compact sealed-tube neutron generators.

  11. SÍNTESIS DE FERRITAS DE Pb, Cd y Mn VÍA HIDROQUÍMICA: INCIDENCIA DEL ANIÓN Y EL FLUJO DE AIRE

    Directory of Open Access Journals (Sweden)

    Eliazar Aquino Torres

    2013-01-01

    cloruro, se observó una disminución mayor de Fe2+ que en las obtenidas a partir de nitratos; probablemente debido a la presencia de Cl que en medio básico pasa a ClO- y éstos dan lugar a la oxidación de Fe2+ a Fe3+ catalizada por los propios iones Fe2+, Fe. Para la ferrita de cadmio se determinaron contenidos de Fe mayores a los encontrados en las ferritas de manganeso; posiblemente no se oxidó todo el Fe2+2+ por menor concentración de cloruros (0.018M que en la de manganeso (0.036M.

  12. Microstructure-property relationships of rare-earth--zinc-oxide varistors

    International Nuclear Information System (INIS)

    Williams, P.; Krivanek, O.L.; Thomas, G.; Yodogawa, M.

    1980-01-01

    The microstructure and properties of ZnO varistors containing Ba, Co, and rare-earth--metal oxides, which give values of α [α=d(log I)/d(log V)] as high as 29, are examined. Mean ZnO grain size is 11 μm, and the grains are uniformly doped with Co. The barium and rare earth metals concentrate into 1.5-μm-wide particles embedded in a matrix of ZnO grains. Within the grains and at grain boundaries, the barium and rare-earth--metal concentration is below the detection limit of the energy-dispersive spectrometer technique (about 0.5%). No intergranular films, amorphous or crystalline, are detected, to within 10 A resolution. These results are shown to be consistent with the grain boundary charge depletion model for the voltage barrier formation and breakdown

  13. Analysis of electrical and microstructural characteristics of a ZnO-based varistor doped with rare earth oxide; Analise das caracteristicas microestruturais e eletricas de um varistor a base de ZnO dopado com oxidos de terras raras

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, J.M. de; Dias, R.; Furtado, J.G. de M. [Centro de Pesquisas de Energia Eletrica (CEPEL), Rio de Janeiro, RJ (Brazil); Assuncao, F.C.R. [Pontificia Univ. Catolica do Rio de Janeiro (PUC/Rio), RJ (Brazil)

    2010-07-01

    Varistor is a semiconductor device, used in the protection of electrical systems, characterized to have a high no-linear electric resistance. Its properties are directly dependents of its chemical composition and microstructural characteristics. In this work were analyzed microstructural and electrical characteristics of a ZnO-based varistor doped with rare earth oxide, with chemical composition (mol%) 98,5.ZnO - 0,3.Pr{sub 6}O{sub 11} - 0,2.Dy{sub 2}O{sub 3} - 0,9.Co{sub 2}O{sub 3} - 0,1.Cr{sub 2}O{sub 3}. X-ray diffraction for phase characterization, scanning electron microscopy and energy dispersive X-ray spectroscopy were used for microstructural analysis. Measurement of average grain size and electrical and dielectric characteristics complete the characterization. The results show the formation of biphasic microstructure and with high densification, presenting relevant varistors characteristics but that would need improvements.(author)

  14. Long-term research in Japan: amorphous metals, metal oxide varistors, high-power semiconductors and superconducting generators

    Energy Technology Data Exchange (ETDEWEB)

    Hane, G.J.; Yorozu, M.; Sogabe, T.; Suzuki, S.

    1985-04-01

    The review revealed that significant activity is under way in the research of amorphous metals, but that little fundamental work is being pursued on metal oxide varistors and high-power semiconductors. Also, the investigation of long-term research program plans for superconducting generators reveals that activity is at a low level, pending the recommendations of a study currently being conducted through Japan's Central Electric Power Council.

  15. Características microestructurales de varistores del sistema ZnO-BaO-P2O5

    Directory of Open Access Journals (Sweden)

    Fernández, J. F.

    1999-10-01

    Full Text Available Ceramic materials based on the system ZnO-BaO show a great potential for varistor applications. However, the BaO rich phase located at the grain boundaries shows high solubility in water which causes severe damage of the materials. In order to overcome this problem, doping with P2O5 to form BaZn2(PO42 and Zn3(PO42 has been studied. The resistance of these materials to degradation by moisture has been evaluated by lixiviation experiments. Sintering has been followed by means of dilatometric technique and microstructure was analysed by Scanning Electron Microscopy, SEM. The electrical properties of these materials evidence a varistor behaviour similar to that observed for materials in the system ZnO-BaO.Los materiales basados en el sistema ZnO-BaO presentan unas propiedades de gran interés para su aplicación como varistores. Sin embargo, la fase rica en BaO localizada en el borde de grano exhibe una solubilidad elevada en agua que origina una rápida degradación del material. Para soslayar este problema se ha estudiado la incorporación adicional de P2O5 con el objeto de formar las fases BaZn2(PO42 y Zn3(PO42. La estabilidad de estos nuevos materiales frente a la humedad se ha evaluado mediante ensayos de lixiviación. La sinterización se ha seguido mediante dilatometría y la microestructura de los materiales sinterizados se ha analizado por Microscopía Electrónica de Barrido, MEB. La respuesta eléctrica de los materiales muestra un comportamiento varistor comparable al que se observa en los del sistema binario ZnO-BaO.

  16. Investigations into Recycling Zinc from Used Metal Oxide Varistors via pH Selective Leaching: Characterization, Leaching, and Residue Analysis

    Science.gov (United States)

    Gutknecht, Toni; Gustafsson, Anna; Forsgren, Christer; Steenari, Britt-Marie

    2015-01-01

    Metal oxide varistors (MOVs) are a type of resistor with significantly nonlinear current-voltage characteristics commonly used in power lines to protect against overvoltages. If a proper recycling plan is developed MOVs can be an excellent source of secondary zinc because they contain over 90 weight percent zinc oxide. The oxides of antimony, bismuth, and to a lesser degree cobalt, manganese, and nickel are also present in varistors. Characterization of the MOV showed that cobalt, nickel, and manganese were not present in the varistor material at concentrations greater than one weight percent. This investigation determined whether a pH selective dissolution (leaching) process can be utilized as a starting point for hydrometallurgical recycling of the zinc in MOVs. This investigation showed it was possible to selectively leach zinc from the MOV without coleaching of bismuth and antimony by selecting a suitable pH, mainly higher than 3 for acids investigated. It was not possible to leach zinc without coleaching of manganese, cobalt, and nickel. It can be concluded from results obtained with the acids used, acetic, hydrochloric, nitric, and sulfuric, that sulfate leaching produced the most desirable results with respect to zinc leaching and it is also used extensively in industrial zinc production. PMID:26421313

  17. Investigations into Recycling Zinc from Used Metal Oxide Varistors via pH Selective Leaching: Characterization, Leaching, and Residue Analysis

    Directory of Open Access Journals (Sweden)

    Toni Gutknecht

    2015-01-01

    Full Text Available Metal oxide varistors (MOVs are a type of resistor with significantly nonlinear current-voltage characteristics commonly used in power lines to protect against overvoltages. If a proper recycling plan is developed MOVs can be an excellent source of secondary zinc because they contain over 90 weight percent zinc oxide. The oxides of antimony, bismuth, and to a lesser degree cobalt, manganese, and nickel are also present in varistors. Characterization of the MOV showed that cobalt, nickel, and manganese were not present in the varistor material at concentrations greater than one weight percent. This investigation determined whether a pH selective dissolution (leaching process can be utilized as a starting point for hydrometallurgical recycling of the zinc in MOVs. This investigation showed it was possible to selectively leach zinc from the MOV without coleaching of bismuth and antimony by selecting a suitable pH, mainly higher than 3 for acids investigated. It was not possible to leach zinc without coleaching of manganese, cobalt, and nickel. It can be concluded from results obtained with the acids used, acetic, hydrochloric, nitric, and sulfuric, that sulfate leaching produced the most desirable results with respect to zinc leaching and it is also used extensively in industrial zinc production.

  18. Desarrollo del proceso de moldeo por extrusión de polvos para la obtención de varillas de un material compuesto ferrita-polímeros

    OpenAIRE

    Gil Cirilo, MIguel

    2011-01-01

    El objetivo principal de este proyecto es la fabricación mediante extrusión termoplástica de polvos de varillas de un composite altamente cargado de ferrita y polímero para su utilización en antenas para móviles. La solución óptima desde el punto de vista de las propiedades magnéticas sería un material 100% ferrita, pero el fabricante requiere unas propiedades mecánicas que son imposibles de alcanzar con un material de este tipo. Para ello se decidió fabricar un material compue...

  19. Sinterização por micro-ondas de ferrita de níquel sintetizada pelo método Pechini

    Directory of Open Access Journals (Sweden)

    J. R. Muñoz Hoyos

    2013-09-01

    Full Text Available A sinterização por micro-ondas é uma técnica que oferece enorme potencial para a fabricação de diversos materiais cerâmicos com microestruturas cerâmicas diferenciadas. Este trabalho teve por objetivo sinterizar cerâmicas de ferrita de níquel (NiFe2O4 em forno de micro-ondas, visando controle de crescimento de grão e alta densificação. Para realizar esta investigação, foi utilizado o processo de síntese por Pechini para a preparação do pó das ferritas de níquel. Amostras desse material foram sinterizadas em forno convencional e de micro-ondas. A caracterização foi feita por difração de raios X, microscopia eletrônica de varredura, determinação de densidade aparente e obtenção das curvas de histerese magnética. A sinterização da ferrita de níquel por micro-ondas levou apenas 10% do tempo gasto da sinterização convencional. As amostras apresentaram menor tamanho de grão, e densidade e magnetização de saturação semelhantes às obtidas pela sinterização convencional, mostrando o alto potencial de aplicação da técnica de micro-ondas para o processamento desses materiais.

  20. Experiments of a 100 kV-level pulse generator based on metal-oxide varistor

    Science.gov (United States)

    Cui, Yan-cheng; Wu, Qi-lin; Yang, Han-wu; Gao, Jing-ming; Li, Song; Shi, Cheng-yu

    2018-03-01

    This paper introduces the development and experiments of a 100 kV-level pulse generator based on a metal-oxide varistor (MOV). MOV has a high energy handling capacity and nonlinear voltage-current (V-I) characteristics, which makes it useful for high voltage pulse shaping. Circuit simulations based on the measured voltage-current characteristics of MOV verified the shaping concept and showed that a circuit containing a two-section pulse forming network (PFN) will result in better defined square pulse than a simple L-C discharging circuit. A reduced-scale experiment was carried out and the result agreed well with simulation prediction. Then a 100 kV-level pulse generator with multiple MOVs in a stack and a two-section pulse forming network (PFN) was experimented. A pulse with a voltage amplitude of 90 kV, rise time of about 50 ns, pulse width of 500 ns, and flat top of about 400 ns was obtained with a water dummy load of 50 Ω. The results reveal that the combination of PFN and MOV is a practical way to generate high voltage pulses with better flat top waveforms, and the load voltage is stable even if the load's impedance varies. Such pulse generator can be applied in many fields such as surface treatment, corona plasma generation, industrial dedusting, and medical disinfection.

  1. Electrical and microstructural properties of microwave sintered SnO{sub 2}-based varistors

    Energy Technology Data Exchange (ETDEWEB)

    Furtado, P.S.; Oliveira, M.M.; Vasconcelos, J.S.; Rangel, J.H.G., E-mail: periclesft@ifma.edu.br, E-mail: marcelo@ifma.edu.br, E-mail: jomar@ifma.edu.br, E-mail: hiltonrangel@ifma.edu.br [IFMA-DAQ- PPGEM, S. Luis, MA (Brazil); Longo, E., E-mail: elson@iq.unesp.br [CMDMC, LIEC, Instituto de Quimica, UNESP, Araraquara, SP (Brazil); Sousa, V.C. de, E-mail: vania.sousa@ufrgs.br [DEMAT, Universidade Federal do Rio Grande do Sul - UFRGS, Porto Alegre, RS (Brazil)

    2012-04-15

    An investigation was made of the microstructural and electrical properties of SnO{sub 2} -based varistors microwave sintered at 1200 deg C, applying a heating rate of 120 deg C/min and treatment times of 10, 20, 30, 40, 50 and 60 min. The system used in this study was (98.95-X)%SnO{sub 2}.1.0%CoO.0.05%Cr{sub 2}O{sub 3}.X%Ta{sub 2}O{sub 5}, where X corresponds to 0.05 and 0.065 mol%. Sintering was carried out in a domestic microwave oven (2.45 GHz) fitted for lab use. Silicon carbide was placed in a refractory vessel to form a heating chamber surrounding the sample holder. The pellets were examined by scanning electron microscopy, X-ray diffractometry, direct current measurements and impedance spectroscopy. The parameters of density, medium grain size, coefficient of nonlinearity, breakdown electrical field, leakage current, and height and width of the potential barrier were analyzed. (author)

  2. Restart of the chemical preparation process for the fabrication of ZnO varistors for ferroelectric neutron generator power supplies

    International Nuclear Information System (INIS)

    Lockwood, Steven John

    2005-01-01

    To date, all varistors used in ferroelectric neutron generators have been supplied from a single, proprietary source, General Electric Corporate Research and Development (GE CR and D). To protect against the vulnerability of a single source, Sandia initiated a program in the early 1980's to develop a second source for this material. A chemical preparation process for making homogeneous, high purity ZnO-based varistor powder was generated, scaled to production quantities, and transferred to external suppliers. In 1992, the chem-prep varistor program was suspended when it appeared there was sufficient inventory of GE CR and D material to supply ferroelectric neutron generator production for many years. In 1999, neutron generator production schedules increased substantially, resulting in a predicted exhaustion of the existing supply of varistor material within five years. The chem-prep program was restarted in January, 2000. The goals of the program were to (1) duplicate the chem-prep powder synthesis process that had been qualified for WR production, (2) demonstrate sintered billets from the chem-prep powder met requirements, (3) develop a process for rod fabrication and demonstrate that all component specifications could be met, and (4) optimize the process from powder synthesis through component fabrication for full-scale production. The first three of these goals have been met and are discussed in this report. A facility for the fabrication of production quantities of chem-prep powder has been established. All batches since the restart have met compositional requirements, but differences in sintering behavior between the original process and the restarted process were noted. Investigation into the equipment, precipitant stoichiometry, and powder processing procedures were not able to resolve the discrepancies. It was determined that the restarted process, which incorporated Na doping for electrical stability (a process that was not introduced until the end of the

  3. Electrothermal and microstructural characterization of varistors ceramics used in high-voltage surge arresters; Caracterizacao eletrotermica e microestrutural de ceramicas varistoras utilizadas em para-raios de altas tensoes

    Energy Technology Data Exchange (ETDEWEB)

    Barbosa, Flavio Bittencourt; Furtado, Jose G. de Melo [Centro de Pesquisas de Energia Eletrica (CEPEL), Rio de Janeiro, RJ (Brazil); Nobrega, Maria C. de S. [Universidade Federal do Rio de Janeiro (COPPE/UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia

    2008-07-01

    In this work is studied the electrothermal behavior of varistor ceramic blocks used in high voltage surge arresters of transmission and distribution lines, relating this behavior to microstructural characteristics of the studied varistor ceramics. We studied blocks of zinc oxide varistors with nominal voltage of 4.0 kV, by and voltage-capacitance characterization curves, reference voltage test, impulse residual voltage, polarization tests and induced degradation tests. On the other hand, the microstructural characterization was made by scanning electron microscopy and energy-dispersive spectroscopy. The obtained results allow to correlate the behavior of the resistive component of the leakage current with the microstructural characteristics of the studied varistors, specially in pre-breakdown region. (author)

  4. Fe2 O3 addition influence on the Sn O2.Co O.Nb2 O5 varistors system

    International Nuclear Information System (INIS)

    Antunes, A.C.; Antunes, S.R.M.; Castilhos, J.G.R.; Pianaro, S.R.; Zara, J.A.; Longo, E.; Varela, J.A.

    1997-01-01

    The effect 0.05 to 0.30 mol% Fe 2 0 3 addition on the electrical and microstructural properties of ternary varistor system composed by tin oxide, niobium oxide and cobaltum oxide was studied in this work. The samples were sintered at 1300 deg C for two hours. The characterizations were performed by Vxi measurements, scanning electron microscopy and X - ray diffraction. The Fe 2 O 3 additions up to 0,10% increased the α values breakdown electric fields (E r ) and it was observed that the barrier voltage (v b ) depends on the chemical composition. The second phase had high concentration of iron that precipitated in the grain boundaries and inhibited the grain growth during sintering. Fe 2 O 3 concentrations upper 0,10 mol% were deleterious for electrical properties of the ceramics. (author)

  5. The influence of CeO2 on the microstructure and electrical behaviour of ZnO-Bi2O3 based varistors

    International Nuclear Information System (INIS)

    Lei Ming; Li Shengtao; Jiao Xiaodong; Li Jianying; Alim, Mohammad A

    2004-01-01

    The processing-microstructure-property relations have been studied in order to understand the role of the addition of CeO 2 (up to 0.9 mole%) in the ZnO-Bi 2 O 3 based varistor recipe. The microstructural investigation suggests that CeO 2 is segregated at the corners of the ZnO grains in addition to the existence of the Zn 7 Sb 2 O 12 spinel phase. However, the α -spinel phase was observed instead of the β -spinel phase that is usually found in most commercial and laboratory ZnO-Bi 2 O 3 based varistors. The α -spinel phase is more stable than the β -spinel phase and does not transform to the pyrochlore phase during the cooling process. The most significant effect of the CeO 2 particles is the ZnO grain refinement owing to the pinning effect of the grain growth. The average grain size decreases from 7.8 to 5.7 μm when compared to the 0.9 mole% CeO 2 -added sample against the CeO 2 -free sample. This grain refinement results in a significantly enhanced breakdown field when compared to the CeO 2 -free sample. The coefficient of nonlinearity of the current-voltage (I-V) characteristics is found to be nearly identical for the CeO 2 added varistor materials. However, when a slower cooling cycle (1 deg. C min -1 instead of 4 deg. C min -1 ) is used in the sintering process, these varistor materials exhibited a high nonlinear coefficient (α = 29 ± 5) as extracted from the I-V behaviour

  6. Effect of Ca, Sr and Ba on the structure, morphology and electrical properties of (Co,Sb)-doped SnO{sub 2} varistors

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar-Martínez, J.A., E-mail: josue.aguilarm@uanl.mx [Universidad Autónoma de Nuevo León, Facultad de Ingeniería Mecánica y Eléctrica, Centro de Investigación e Innovación en Ingeniería Aeronáutica (CIIIA), Carretera a Salinas Victoria km. 2.3, C.P. 66600 Apodaca, N.L. (Mexico); Rodríguez, Edén [Universidad Autónoma de Nuevo León, Facultad de Ingeniería Mecánica y Eléctrica, Av. Universidad S/N, Cd. Universitaria, C.P. 66451 San Nicolás de los Garza, N.L. (Mexico); García-Villarreal, S.; Falcon-Franco, L. [Universidad Autónoma de Coahuila, Facultad de Metalurgia, Carr. 57, Km 4.5, C.P. 25710 Monclova, Coah. (Mexico); Hernández, M.B. [Universidad Autónoma de Nuevo León, Facultad de Ingeniería Mecánica y Eléctrica, Av. Universidad S/N, Cd. Universitaria, C.P. 66451 San Nicolás de los Garza, N.L. (Mexico)

    2015-03-01

    In this work, the effect of calcium (Ca), barium (Ba) and strontium (Sr) additions on the microstructure and electrical properties of SnO{sub 2}-Co{sub 3}O{sub 4}-Sb{sub 2}O{sub 5} ceramic varistors was investigated. It was found that the calcium addition promotes densification and grain growth. Ceramics with calcium addition exhibit the lowest electric field at a fixed current density (10{sup −3} A cm{sup −2}). The addition of strontium shows a similar effect on microstructure and current-voltage characteristics. However, barium addition causes porosity increase, grain size reduction, changes in the grain morphology (from approximately equiaxed to elongated grains) and the electric field at a fixed current density showed almost no change. Consequently, Ba-containing SnO{sub 2}-based ceramics cannot be considered as attractive candidates for low-voltage varistors. - Highlights: • The calcium and Strontium addition promotes densification and grain growth. • Barium addition causes porosity increase, grain size reduction and changes in the grain morphology. • Ceramics with calcium addition exhibit the lowest electric field. • Ceramics with calcium addition can be considered as promising materials for low-voltage varistors.

  7. Estudio comparativo de las propiedades magnéticas de ferritas hexagonales de Bario obtenidas por los métodos de coprecipitación y microemulsión

    Directory of Open Access Journals (Sweden)

    García-Casillas, P. E.

    1999-12-01

    Full Text Available Using the chemical coprecipitation method a precursor formed by iron and barium hidroxides and carbonates was obtained. For calcination temperatures higher than 730ºC this precursor transforms into barium ferrite. Calcining the precursor during 2 hours a maximum magnetization of 59.1 emu/g for 925ºC was obtained. Using the microemulsion method a fine precursor formed by iron and barium hidroxides and carbonates was obtained. For calcination temperatures higher than 760ºC this precursor transforms into barium ferrite. Calcining the precursor during 12 hours a maximum magnetization of 60.5 emu/g for 925ºC was obtained. For the barium ferrite obtained by microemulsion the intrinsic coercitivity was 20% lower than the intrinsic coercitivity of the barium ferrite obtained by chemical coprecipitation. This lower intrinsic coercivity should favor the microemulsion method for producing barium ferrite particles used as perpendicular magnetic recording medium.

    Por el método de coprecipitación química se obtuvo un precursor formado por hidróxidos y carbonatos de hierro y bario que al calcinarlo a temperaturas superiores a 730ºC se transforma en ferrita de bario. Al calcinar el precursor durante 2 horas se obtuvo la magnetización máxima de 59.1 emu/g para la temperatura de 925ºC. Por el método de microemulsión se obtuvo un precursor fino de hidróxidos y carbonatos de hierro y bario que al calcinarlo a temperaturas superiores a 760ºC se transforma en ferrita de bario. Al calcinar el precursor durante 12 horas se obtuvo la magnetización máxima de 60.5 emu/g para la temperatura de 925ºC. La coercitividad intrínseca del polvo de ferrita de bario obtenido por microemulsión resultó ser un 20% menor que la coercitividad intrínseca del polvo de ferrita de bario obtenido por coprecipitación. Esta menor coercitividad debe favorecer al método de microemulsión para la producción de partículas de ferrita de bario que sirvan como medio

  8. In vitro cytotoxicity tests of ZnO‐Bi{sub 2}O{sub 3}‐Mn{sub 2}O{sub 3}-based varistor fabricated from ZnO micro and nanoparticle powders on L929 mouse cells

    Energy Technology Data Exchange (ETDEWEB)

    Sendi, Rabab Khalid, E-mail: last-name3@hotmail.com, E-mail: shahromx@hotmail.com, E-mail: ameerah7@hotmail.com; Mahmud, Shahrom, E-mail: last-name3@hotmail.com, E-mail: shahromx@hotmail.com, E-mail: ameerah7@hotmail.com; Munshi, Ayman, E-mail: last-name3@hotmail.com, E-mail: shahromx@hotmail.com, E-mail: ameerah7@hotmail.com [Nano-optoelectronics Research and Technology Laboratory (N.O.R.), School of Physics, Universiti Sains Malaysia, 11800, Penang (Malaysia); Seeni, Azman, E-mail: azanseeni@gmail.com [Advanced Medical and Dental Institute (AMDI), Universiti Sains Malaysia, 13200, Bertam, Pulau Pinang (Malaysia)

    2014-10-24

    The present study investigated the cytotoxicity of ZnO‐Bi{sub 2}O{sub 3}‐Mn{sub 2}O{sub 3}-varistors. To this effect, ZnO‐Bi{sub 2}O{sub 3}‐Mn{sub 2}O{sub 3} varistors fabricated from ZnO micro-and nanoparticle powders are prepared via conventional ceramic processing method. The effects of ZnO particle size on the properties of ZnO varistors are also investigated. The strong solid-state reaction during sintering may be attributed to the high surface area of the 20 nm ZnO nanoparticles that promote strong surface reaction. The intensity of XRD peaks reflected the high degree of crystallinity of the ZnO nanoparticles. However, the width of the peaks in case of ZnO nanoparticles has increased due to the quantum size effect. The cytotoxicity evaluation of ZnO varistor was conducted on mouse connective tissue fibroblast cells (L929) using Trypan Blue Exclusion Assay analysis. The results show that the four types of varistor samples lead to cellular mitochondrial dysfunction, morphological modifications and apoptosis at the various concentration range and the toxic effects are obviously displayed in high concentration samples. 20nm-VDR is the most toxic materials followed by 40nm-VDR, P8-VDR, and W4-VDR in a descending order.

  9. Ciclo térmico para la obtención de una ferrita de Ni-Zn: (II Influencia de la etapa de enfriamiento

    Directory of Open Access Journals (Sweden)

    Barba, A.

    2008-04-01

    Full Text Available Ceramic bodies formed from (Cu0.12Ni0.23Zn0.65Fe2O4 ferrite powders stand out as electromagnetic radiation absorbers among Cu-doped Ni-Zn ferrites, preventing interference between electronic devices. In a preliminary study, a methodology was established for designing the sintering stage of a thermal cycle, which allows the foregoing ceramic bodies to be obtained with the appropriate microstructure (high relative density and little grain growth to provide them with good electromagnetic properties. The present study examines the cooling stage (i.e. the stage following the sintering stage of that thermal cycle and the influence of the cooling rate on fired relative density, average grain size, and grain size distribution, varying the sintering time of the thermal cycle used.

    Las piezas cerámicas obtenidas a partir de polvos de ferritas de composición (Cu0.12Ni0.23Zn0.65Fe2O4 destacan como absorbentes de radiación electromagnética entre las ferritas de Ni-Zn dopadas con Cu, impidiendo interferencias entre dispositivos electrónicos. En un trabajo previo se estableció la metodología para diseñar la etapa de sinterización de un ciclo térmico que permite obtener las piezas cerámicas mencionadas con una microestructura adecuada (elevada densidad relativa y escaso crecimiento de grano para que presenten unas buenas propiedades electromagnéticas. En este trabajo se ha estudiado la etapa de enfriamiento del mismo ciclo térmico (etapa siguiente a la de sinterización, determinando la influencia que ejerce la velocidad de enfriamiento sobre la densidad relativa en cocido, el tamaño medio de grano y la distribución de tamaños de grano, variando el tiempo de sinterización del ciclo térmico empleado.

  10. Modelización de la formación isotérmica de ferrita idiomórfica en aceros de medio carbono microaleados con vanadio-titanio

    Directory of Open Access Journals (Sweden)

    Capdevila, C.

    2002-06-01

    Full Text Available A theoretical model is presented in this work to calculate the evolution of isothermal austenite-to-idiomorphic ferrite transformation in a medium carbon vanadium-titanium microalloyed steel. This model has been developed on the basis of the study of the nucleation and growth kinetics of idiomorphic ferrite, considering the influence of the nature, size and distribution of the inclusions, which are responsible of the intragranular nucleation of idiomorphic ferrite. Moreover, the influence of the austenite grain size on the isothermal decomposition of austenite in idiomorphic ferrite has been thoroughly analysed. An excellent agreement (85 % in R has been obtained between experimental and predicted values of volume fraction of idiomorphic ferrite.

    En este trabajo se presenta un modelo teórico para calcular la evolución con el tiempo de la transformación isotérmica de la austenita en ferrita idiomórfica en un acero de medio carbono microaleado con vanadio-titanio. En dicho modelo, desarrollado en base al estudio de la cinética de nucleación y crecimiento de ferrita idiomórfica, se ha valorado la influencia de la naturaleza, tamaño y distribución de las inclusiones responsables de la nucleación intragranular de ferrita. Así mismo, se ha analizado, con detenimiento, la influencia que tiene el tamaño de grano austenítico. El modelo ha sido validado experimentalmente, mostrándose un excelente acuerdo (85 % en R entre los resultados experimentales y los predichos por el modelo de transformación propuesto en este trabajo.

  11. Incorporación de la fase Zn7Sb2O12 previamente sintetizada en varistores cerámicos basados en ZnO

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    Caballero, A. C.

    2002-02-01

    Full Text Available During the sintering process of ZnO-Bi2O3-Sb2O3 based varistors, different reactions take place. The formation of the Zn7Sb2O12 spinel phase occurs between 900 and 1100ºC depending on the composition of the material. The spinel phase acts as ZnO grain growth inhibitor and its distribution on the whole material as a secondary phase in the matrix of ZnO grains determines the kinetics of grain growth. However, it is difficult to control the nucleation and growth of this phase, and this concerns on the final grain size and consequently on the characteristics of the varistor device. The present study has focused on the incorporation of the previously synthesized spinel phase. Scanning Electronic Microscopy analysis of sintered samples reveals a better control of microstructure in those materials with the synthesized spinel phase. The electrical behaviour of these materials agrees with the microstructural features and a greater reproducibility is observed.Una de las reacciones que tiene lugar durante la sinterización de varistores cerámicos basados en el sistema ZnO-Bi2O3-Sb2O3 es la formación de la fase Zn7Sb2O12, de estructura tipo espinela, que ocurre en el intervalo de temperaturas comprendido entre 900 y 1100ºC, dependiendo de la composición específica del material. Esta fase es la responsable del control del crecimiento de grano y su distribución en el seno del material como una segunda fase dispersa en la matriz mayoritaria de granos de ZnO determinará la cinética del crecimiento de los granos. Sin embargo, el proceso de nucleación y crecimiento de esta fase resulta difícil de controlar cuantitativamente, aspecto que se refleja en las características finales del dispositivo varistor obtenido. En el presente trabajo se analiza el efecto de la incorporación de la fase espinela previamente sintetizada a partir de los óxidos de zinc y antimonio. El análisis mediante Microscopía Electrónica de Barrido (MEB de la microestructura de

  12. Síntese in situ pelo método hidrotérmico de heteroestruturas de titanato-ferritas e sua atividade fotocatalítica

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    B. F. Troque

    Full Text Available Resumo A aplicação de fotocatalisadores na forma de heteroestruturas tem se destacado através da propriedade de degradação de diversos compostos orgânicos no tratamento de efluentes. Neste contexto, o objetivo deste trabalho foi sintetizar compostos heteroestruturados à base de titanato-ferritas pelo método hidrotérmico in situ para aplicação em processo foto-Fenton. Os materiais sintetizados in situ foram caracterizados por difratometria de raios X, espectroscopia de infravermelho, espectroscopia de reflectância difusa, área específica superficial por BET e microscopia eletrônica de transmissão. A síntese in situ de SrTiO3-CoFe2O4 e SrTiO3-NiFe2O4 foi desenvolvida de forma inédita neste trabalho, resultando com sucesso em sistemas heteroestruturados sem presença de fases secundárias, distribuição altamente homogênea das fases constituintes com tamanho médio de partículas nanométrico e garantia de reprodutibilidade do método. A atividade fotocatalítica dos compostos sintetizados foi investigada por meio da degradação do corante Rodamina B, utilizando luz visível, onde o sistema SrTiO3-CoFe2O4 apresentou a melhor atividade fotocatalítica degradando 82% do corante.

  13. Effect of Pr6O11 doping in electrical and microstructural properties of SnO2-based varistors

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    Hervê Stangler Irion

    2014-04-01

    Full Text Available The influence of the dopant Pr6O11 was investigated with regard to the electrical and microstructural properties of the system (98.95-x%SnO2.1.0%CoO.0.05%Ta2O5.x%Pr6O11, where x = 0.05%, 0.10%, 0.30% and 0.50% in mol. Pr6O11 doping modifies the electrical behavior of the ceramics. The electrical parameters were: α = 8.0, EB = 319 V cm-1 and Vb = 0.66 V barrier-1 for the system without Pr6O11 and α = 17.0, EB = 853 V cm-1 and Vb = 1.15 V barrier-1 with the addition of 0.10% in mol Pr6O11. The system with 0.05% in mol Pr6O11 had the same non-linearity coefficient α as the system with 0.10% in mol. However, breakdown electrical field and voltage per barrier rates were lower (EB = 708 V cm-1 and Vb = 0.98 V barrier-1. The low rates in the breakdown electrical field enabled the varistor systems under study to be used in protection systems for low-voltage energy grids. In the case of Pr6O11 concentrations above 0.10% in mol, the presence of the dopant became deleterious to the varistor’s electrical characteristics. This effect was due to an increase in praseodymium stannate (Pr2Sn2O7 secondary phase. The crystalline phase coupled to the cassiterite (SnO2 phase was found with XRD and SEM/EDS and quantified by Rietveld’s refining method.

  14. Control de la descomposición anisotérmica de la austenita en ferrita acicular buscando la combinación óptima de propiedades mecánicas en un acero microaleado de forja

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    García de Andrés, C.

    2001-04-01

    Full Text Available The aim of this work is to study the anisothermal decomposition of austenite at two different austenisation conditions in a medium carbon microalloyed steel. In this sense, continuous cooling transformation diagrams (CCT have been obtained for both austenisation conditions to determine the continuous cooling that allows the formation of a microstructure mainly formed of acicular ferrite with the best mechanical properties.The knowledge of the anisothermal decomposition oí austenite in this steel has allowed to propose continuous cooling cycles for industrial aplication. That produce high volume fraction of acicular ferrite.

    El propósito del presente trabajo es estudiar la descomposición anisotérmica de la austenita de un acero microaleado de contenido medio en carbono para dos diferentes condiciones de austenización. Con este objeto se han construido los diagramas CCT del acero para ambos estados de austenización y se han establecido las condiciones de enfriamiento que permiten la formación de microestructuras constituidas mayoritariamente por ferrita acicular con propiedades mecánicas óptimas. El conocimiento de la evolución de las transformaciones anisotérmicas de este acero, ha permitido encontrar ciclos de enfriamiento continuo, aplicables en procesos industriales, para obtener directamente microestructuras con un alto porcentaje de ferrita acicular.

  15. Espectroscopia de admitancias de banda ancha aplicada al control microestructural de propiedades eléctricas en varistores cerámicos

    Directory of Open Access Journals (Sweden)

    Fernández Hevia, D.

    2004-06-01

    Full Text Available In the present work, the theory of charge transport through active interfaces is used to study the electronic properties of ZnO-based varistors. It has been observed that for a certain range of sintering temperatures the microscopic electrical response of the material is constant, so that the macroscopic response is microstructure controlled. This allows controlling the functional response of the material with a high precision.

    En el presente estudio se utiliza la teoría de transporte de carga a través de interfases eléctricamente activas para estudiar las propiedades electrónicas de varistores basados en ZnO. Se obtiene un rango de temperaturas de sinterización en el que la respuesta eléctrica microscópica del material se mantiene esencialmente constante, de manera que su respuesta macroscópica está controlada por su microestructura. Esto permite una gran precisión en el control de las propiedades eléctricas funcionales del material.

  16. Simulação da difusão do zinco e do oxigênio, e análise da durabilidade de varistor de ZnO utilizando o planejamento fatorial

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    Pariona M. M.

    2000-01-01

    Full Text Available A durabilidade do varistor de ZnO está relacionada com suas características elétricas, microestruturais, térmicas e com o fenômeno de transporte de massa nos contornos de grão durante o processo de operação do varistor. O estado de polarização nos contornos de grão está relacionado com a difusão do zinco, do oxigênio e dos dopantes durante a aplicação do potencial elétrico e/ou da temperatura. Quando o potencial elétrico é retirado e o estado de polarização não recupera seu estado natural, significa que o dispositivo adquire os piores parâmetros e o varistor sofre degradação, comprometendo sua durabilidade. Neste trabalho, foi simulada a difusão do zinco intersticial e das vacâncias de oxigênio em ZnO. Foi também simulada a durabilidade do varistor, através do planejamento fatorial dos parâmetros elétricos, térmicos e geométricos que caracterizam o dispositivo. Através destes resultados, verificou-se que a difusão do zinco intersticial controla principalmente as propriedades elétricas. Observou-se, também, que quando aumenta a temperatura e a queda de tensão registrada em 0,5 mA/cm², a durabilidade do varistor fica comprometida.

  17. Control microestructural en varistores cerámicos basados en el sistema ZnO-Bi2O3-Sb2O3 dopados con TiO2

    Directory of Open Access Journals (Sweden)

    Fernández-Hevia, D.

    2012-02-01

    Full Text Available Typically Titanium oxide is added to the formulation of Bi2O3-doped ZnO based varistors to enhance the growth of ZnO grains, thus allowing their application in low voltage devices. However its incorporation to formulation based on the ZnOBi2O3-Sb2O3 (ZBS system, characteristic of high voltage applications has not been analyzed jet. In this contribution it has been verified that far from promoting the ZnO grain growth, the incorporation of TiO2 to varistor formulations based on this ZBS ternary system leads to a better control of the varistor microstructure, which in turns causes an appreciable improvement of its electrical response.Típicamente el Óxido de Titanio se incorpora a la formulación de varistores basados en ZnO dopado con Bi2O3 para favorecer un crecimiento de los granos de ZnO, lo que determina su aplicación en dispositivos de bajo voltaje. Sin embargo su incorporación en formulaciones basadas en el ternario ZnO-Bi2O3-Sb2O3 (sistema ZBS, características de aplicaciones de alto voltaje, es algo que apenas se ha analizado. En este trabajo se ha comprobado que lejos de favorecer el crecimiento de los granos de ZnO, la incorporación de TiO2 a sistemas basados en dicho ternario ZBS lleva a un mayor control de la microestructura de estos electrocerámicos, y esto además se traduce en una apreciable mejoría de su respuesta eléctrica.

  18. Estudo do efeito da diluição nas propriedades microestruturais e magnéticas de ferritas Mn0,65Zn0,35Fe2O4 por reação de combustão

    Directory of Open Access Journals (Sweden)

    R. L. P. Santos

    Full Text Available Resumo As ferritas Mn-Zn vêm sendo utilizadas em diversas áreas tecnológicas por apresentarem propriedades atrativas no âmbito técnico-científico. Este trabalho teve como objetivo sintetizar ferritas Mn0,65Zn0,35Fe2O4 por reação de combustão e avaliar o efeito da diluição dos reagentes em água destilada sobre as características microestruturais e magnéticas. As amostras foram caracterizadas por difração de raios X, microscopia eletrônica de varredura e transmissão, temperatura de Curie e por medidas magnéticas. Foi observado que o aumento da diluição em água durante a síntese por reação de combustão foi favorável para obtenção da ferrita Mn0,65Zn0,35Fe2O4 monofásica. Também favoreceu a diminuição do tamanho de aglomerado e aumento da temperatura de Curie com valor máximo de magnetização de saturação de 62 emu/g para a amostra diluída na proporção 1:10.

  19. Effect of MnO2 doping and temperature treatment on optical energy band gap properties in Zn-Bi-Ti-O varistor ceramics

    International Nuclear Information System (INIS)

    Ghazali, M. S. M.; Abdullah, W. R. W.; Zakaria, A.; Kamari, H. M.; Rizwan, Z.

    2016-01-01

    In this study, the optical band-gap energy ( Eg ) was investigated with respect to MnO 2 and sintering temperatures on ZnO based varistor ceramics. Eg of the ceramic (99-x) mol% ZnO + 0.5 mol% Bi 2 O 3 + 0.5 mol% TiO 2 + × MnO 2 where × = 0, 0.2, 0.4, 0.6 and 0.8 mol%, were determined using UV-Vis spectrophotometer. The samples was prepared through solid-state route and sintered at the sintering temperature from 1110, 1140 and 1170 °C for 45 and 90 min in open air. At no doping of MnO 2 , the values of Eg are 2.991 ± 0.001, 2.989 ± 0.001 eV for 45 and 90 min sintering time; respectively. Eg was decreased to 2.192 ± 0.001 eV at 1140 °C at 45 min sintering time. Similar result of Eg was observed at longer heat treatment. Further addition of dopant causing the Eg decreases rapidly to 2.099 and 2.106 ± 0.001 eV at 45 and 90 min sintering time; respectively. XRD analysis indicates that there is hexagonal ZnO and secondary phases, Zn 2 MnO 4 , Bi 4 Ti 3 O 12 and Zn 2 Ti 3 O 8 . The relative density of the sintered ceramics decreased or remain constant with the increase of MnO 2 concentration for 45 min sintering time, however, further prolong sintering time; the relative density decreases form 90.25 to 88.35%. This indicates the pores are increasing with the increase of heat treatment. The variation of sintering temperatures to the optical band gap energy of based ZnO varistor doped with MnO 2 due to the formation of interface states. (paper)

  20. Fe{sub 2} O{sub 3} addition influence on the Sn O{sub 2}.Co O.Nb{sub 2} O{sub 5} varistors system; Influencia da adicao de Fe{sub 2} O{sub 3} no sistema varistor Sn O{sub 2}.Co O.Nb{sub 2} O{sub 5}

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, A.C.; Antunes, S.R.M. [Universidade Estadual de Ponta Grossa, PR (Brazil). Dept. de Quimica; Castilhos, J.G.R.; Pianaro, S.R.; Zara, J.A. [Universidade Estadual de Ponta Grossa, PR (Brazil). Dept. de Engenharia dos Materiais; Longo, E. [Sao Carlos Univ., SP (Brazil). Dept. de Quimica; Varela, J.A. [UNESP, Araraquara, SP (Brazil). Inst. de Quimica

    1997-12-31

    The effect 0.05 to 0.30 mol% Fe{sub 2} 0{sub 3} addition on the electrical and microstructural properties of ternary varistor system composed by tin oxide, niobium oxide and cobaltum oxide was studied in this work. The samples were sintered at 1300 deg C for two hours. The characterizations were performed by Vxi measurements, scanning electron microscopy and X - ray diffraction. The Fe{sub 2} O{sub 3} additions up to 0,10% increased the {alpha} values breakdown electric fields (E{sub r}) and it was observed that the barrier voltage (v{sub b}) depends on the chemical composition. The second phase had high concentration of iron that precipitated in the grain boundaries and inhibited the grain growth during sintering. Fe{sub 2} O{sub 3} concentrations upper 0,10 mol% were deleterious for electrical properties of the ceramics. (author) 7 refs., 3 figs., 4 tabs.

  1. Influência do uso de PTFE como aglomerante em eletrodos revestidos básicos sobre a formação de ferrita acicular no metal de solda

    Directory of Open Access Journals (Sweden)

    Cláudio Turani Vaz

    2014-06-01

    Full Text Available Metais de solda produzidos por eletrodos revestidos básicos aglomerados com politetrafluoretileno (PTFE têm apresentado baixíssimos teores de hidrogênio difusível e elevadas frações volumétricas de ferrita acicular. Esse estudo investigou o papel desempenhado pelo polímero na formação de tal constituinte. A microestrutura produzida por consumíveis contendo esse componente apresentou quantidades de ferrita acicular consideravelmente superiores à prevista na literatura para um metal de solda com os mesmos teores de carbono, silício e manganês. Tal diferença não pode ser atribuída a variações nos parâmetros de soldagem empregados. A análise dos elementos químicos residuais apontou o nitrogênio como sendo o principal responsável pelas discrepâncias observadas na microestrutura. O estudo das características operacionais de eletrodos classe E7018 tradicionais e aglomerados com polímero mostrou que a menor absorção de nitrogênio pelo metal de solda se deve a dois fatores principais. Medidas do teor de nitrogênio dissolvido das gotas coletadas durante a soldagem do eletrodo aglomerado com polímero demonstrou uma atmosfera protetora mais efetiva. O teor de carbono presente no metal de solda obtido pela soldagem do eletrodo com polímero apontou para uma atmosfera rica nesse elemento. Tal característica é coerente com a hipótese de uma melhor proteção gasosa. O tamanho médio das gotas coletadas, teor de nitrogênio dissolvido em função do tamanho e os oscilogramas de tensão indicaram alterações no modo de transferência metálica.

  2. Effect of Cr2O3 on the microstructure and non-ohmic properties of (Co, Sb)-doped SnO2 varistors

    International Nuclear Information System (INIS)

    Aguilar M, J. A.; Pech C, M. I.; Hernandez, M. B.; Rodriguez, E.; Garcia O, L.; Glot, A. B.

    2013-01-01

    The effect of Cr 2 O 3 addition on the physical characteristics, microstructure, and current-voltage properties of (Co-Sb)-doped SnO 2 varistors was investigated. SnO 2 -Co 3 O 4 -Sb 2 O 5 ceramics with additions of 0.0, 0.03, 0.05 and 0.07 mol % Cr 2 O 3 were sintered at 1350 C under ambient atmosphere and characterized micro structurally and electrically. The characterization by X-ray diffraction and scanning electron microscopy show that the microstructure remains as a single phase material with multimodal size distribution of SnO 2 grains. The greatest effect of Cr 2 O 3 additions is manifested in the electric breakdown field. Additions of high levels (0.07 and 0.05 %) of this oxide promote and increase of approximately 55% in this parameter compared to the Cr 2 O 3 -free sample. Another physical property is affected: the measured density values decreases as the Cr 2 O 3 content increases. A change in the nonlinearity coefficient value is produced only at the highest Cr 2 O 3 content while at intermediate levels there is not change at all. Consequently, when seeking high nonlinearity coefficients, intermediate levels of Cr 2 O 3 are not recommended. (Author)

  3. Estudo da adsorção de dispersante à base de poliacrilato em um sistema varistor comercial: caracterização físico-química Study of polyacrylate adsorption in a commercial varistor system: characterization of the physical-chemistry properties

    Directory of Open Access Journals (Sweden)

    S. L. M. Brito

    2005-03-01

    Full Text Available Um dos grandes desafios no processamento cerâmico é a obtenção de dispersões de partículas estáveis e homogêneas contendo materiais com diferentes características físicas e químicas, como densidade, área de superfície específica, distribuição de tamanho de partículas e ponto isoelétrico. O comportamento de suspensões obtidas a partir da composição de um sistema varistor à base de ZnO (aditivos: Bi2O3, Sb2O3, Co3O4, Mn2O3, NiO, Cr2O3 em meio aquoso, utilizando o poliacrilato de amônio como dispersante foi avaliada para determinar a influência dos diferentes óxidos no processamento. Os óxidos foram caracterizados a partir das técnicas mobilidade eletroforética dinâmica, espectroscopia no infravermelho, distribuição granulométrica e área de superfície específica. Os óxidos aditivos apresentam características de superfície, como ponto isoelétricos (pie, distintos com relação ao óxido base (ZnO - pie 9.4. Os dois mais importantes, devido às fortes diferenças de pie foram o Sb2O3 e o Cr2O3, pie = 3,4 e 4,4, respectivamente. Esta diferença de pie entre o ZnO e os aditivos promovem uma mudança no pH quando em dispersão aquosa, que passa a ser de aproximadamente 8,0 e que pode comprometer a estabilidade da dispersão em algumas etapas do processo de dispersão.One of the greatest challenges of ceramic processing is to obtain a stable and homogeneous dispersion of particles when the components present different physical and chemical characteristics, such as density, specific surface area, size distribution and isoelectric point (iep. The ZnO varistor composition contains 7 different oxides (additives: Bi2O3, Sb2O3, Co3O4, Mn2O3, NiO, and Cr2O3 and the stability of the aqueous dispersion strongly depends on the specific surface area, the iep and the dispersant choice. In this work we evaluated the ammonium polyacrylate (PAA-NH4 as a dispersant to determine the influence of the different oxides on the

  4. Desenvolvimento da ferrita delta na solda e ZTA resultante de soldagem plasma pulsada em um aço inoxidável supermartensítico Delta-ferrite development in weld and HAZ produced by pulsed plasma arc welding in a supermartensitic stainless steel

    Directory of Open Access Journals (Sweden)

    Sérgio L. Henke

    2013-03-01

    Full Text Available A ferrita delta é considerada uma fase indesejável na microestrutura dos aços inoxidáveis martensíticos haja vista a mesma poder influenciar no desempenho da resistência à fadiga, tenacidade e corrosão sob-tensão. Sendo assim, o objetivo deste trabalho foi investigar o efeito da soldagem plasma pulsada sobre a distribuição e quantidade de ferrita delta em um aço inoxidável supermartensítico. Para tal foram obtidos cordões por meio de fusão superficial sobre uma amostra de aço inoxidável supermartensítico de alta liga utilizando corrente pulsada e convencional. Em seguida foi efetuada a caracterização microestrutural, em especial da ferrita delta, via análises metalográficas por meio de microscopia óptica e eletrônica de varredura . Os experimentos revelaram que, para o mesmo aporte térmico, a pulsação de corrente promoveu a formação de ferrita delta na forma de bandas ao longo do cordão de solda e redução significativa desta fase na ZTA quando comparada à soldagem convencional.The objective of this study was to investigate the effect of pulsed plasma welding on the distribution and amount of delta ferrite which is considered an undesirable phase in a supermartensitic stainless steel. For such weld beads have been obtained by melting the surface of a sample of a high-alloy supermartensitic stainless steel using pulsed and conventional current. Microstructural characterization, especially of delta ferrite, was performed by metallographic analysis by means of optical microscopy and scanning electron microscopy. The experiments showed that for the same heat input, pulsed current promoted the formation of delta ferrite in the form of bands along the weld bead and caused a significant reduction of this phase in HAZ as compared to conventional welding.

  5. Ciclo térmico para la obtención de una ferrita de Ni-Zn: (I Diseño de la etapa de sinterización

    Directory of Open Access Journals (Sweden)

    Barba, A.

    2008-02-01

    Full Text Available Ceramic bodies formed from (Cu0.12Ni0.23Zn0.65Fe2O4 ferrite powders stand out as electromagnetic radiation absorbers among Cu-doped Ni-Zn ferrites, preventing interference between electronic devices. This study establishes a methodology for designing the sintering stage of a thermal cycle, which allows the foregoing ceramic bodies to be obtained with the appropriate microstructure (high relative density and little grain growth to provide them with good electromagnetic properties. The methodology consists, first, of determining the differential equations that relate the densification and grain-growth rates to average grain size, relative density, and sintering temperature, proposing the corresponding rate-controlling mass-transfer mechanism in each case. Secondly, the simultaneous integration of the two rate equations allows the evolution of relative density and average grain size with sintering time at a prefixed sintering temperature to be obtained. Thirdly, it is determined how this temperature needs to decrease with sintering time in order constantly to maintain a relatively high densification rate, while concurrently keeping the grain-growth rate from causing irregular and/or exaggerated grain growth.

    Las piezas cerámicas obtenidas a partir de polvos de ferritas de composición (Cu0.12Ni0.23Zn0.65Fe2O4 destacan como absorbentes de radiación electromagnética entre las ferritas de Ni-Zn dopadas con Cu, impidiendo interferencias entre dispositivos electrónicos. En este trabajo se ha establecido una metodología para diseñar la etapa de sinterización de un ciclo térmico, que permite obtener las piezas cerámicas mencionadas con una microestructura adecuada (elevada densidad relativa y escaso crecimiento de grano para que presenten unas buenas propiedades electromagnéticas. La metodología establecida consiste, en primer lugar, en determinar las ecuaciones diferenciales que relacionan las velocidades de densificación y de

  6. Effect of Cr{sub 2}O{sub 3} on the microstructure and non-ohmic properties of (Co, Sb)-doped SnO{sub 2} varistors

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar M, J. A. [Centro de Investigac ion en Materiales Avanzados, S. C., Alianza Norte No. 202, Parque de Investigacion e Innovacion Tecnologica, Nueva Carretera Aeropuerto Km. 10 Apodaca 66600, Nuevo Leon (Mexico); Pech C, M. I. [IPN, Centro de Investigacion y de Estudios Avanzados, Unidad Saltillo, Carretera Saltillo-Monterrey Km. 13, Saltillo 25900, Coahuila (Mexico); Hernandez, M. B.; Rodriguez, E.; Garcia O, L. [Universidad Autonoma de Nuevo Leon, Facultad de Ingenieria Mecanica y Electrica, San Nicolas de los Garza, Nuevo Leon (Mexico); Glot, A. B., E-mail: josue.aguilar@cimav.edu.mx [Universidad Tecnologica de la Mixteca, Division de Estudios de Posgrado, Carretera Acatlima Km. 2.5, Huajuapan de Leon 69000, Oaxaca (Mexico)

    2013-10-01

    The effect of Cr{sub 2}O{sub 3} addition on the physical characteristics, microstructure, and current-voltage properties of (Co-Sb)-doped SnO{sub 2} varistors was investigated. SnO{sub 2}-Co{sub 3}O{sub 4}-Sb{sub 2}O{sub 5} ceramics with additions of 0.0, 0.03, 0.05 and 0.07 mol % Cr{sub 2}O{sub 3} were sintered at 1350 C under ambient atmosphere and characterized micro structurally and electrically. The characterization by X-ray diffraction and scanning electron microscopy show that the microstructure remains as a single phase material with multimodal size distribution of SnO{sub 2} grains. The greatest effect of Cr{sub 2}O{sub 3} additions is manifested in the electric breakdown field. Additions of high levels (0.07 and 0.05 %) of this oxide promote and increase of approximately 55% in this parameter compared to the Cr{sub 2}O{sub 3}-free sample. Another physical property is affected: the measured density values decreases as the Cr{sub 2}O{sub 3} content increases. A change in the nonlinearity coefficient value is produced only at the highest Cr{sub 2}O{sub 3} content while at intermediate levels there is not change at all. Consequently, when seeking high nonlinearity coefficients, intermediate levels of Cr{sub 2}O{sub 3} are not recommended. (Author)

  7. Intrinsic defects in ZnO varistors

    International Nuclear Information System (INIS)

    Mahan, G.D.

    1983-01-01

    Theoretical calculations are presented for equilibrium concentrations of zinc and oxygen vacancies in ZnO. Results are presented at the sintering temperature, and also at room temperature. Theoretical calculations of reaction constants show that the intrinsic donor is the oxygen vacancy, rather than the zinc interstitial. The depletion of vacancies in the surface region, as the ZnO is cooled from the sintering temperature, is also calculated. Homojunction effects which are caused by such depletion are shown to be small

  8. Low voltage varistor ceramics based on SnO2

    Indian Academy of Sciences (India)

    WINTEC

    School of Environmental and Chemical Engineering, Chonbuk National University, Jeonju 561-756, South Korea. † ... et al (2001) compared the grain boundary barrier proper- ... parameter, EB (breakdown voltage), was taken as the field.

  9. Piezotronically modified double Schottky barriers in ZnO varistors.

    Science.gov (United States)

    Raidl, Nadine; Supancic, Peter; Danzer, Robert; Hofstätter, Michael

    2015-03-25

    Double Schottky barriers in ZnO are modified piezotronically by the application of mechanical stresses. New effects such as the enhancement of the potential barrier height and the increase or decrease of the natural barrier asymmetry are presented. Also, an extended model for the piezotronic modification of double Schottky barriers is given. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Multi-channel recording of a pulse spectrum on the screen of a Williams tube used with a ferrite memory analyser; Enregistrement du spectre d'impulsion sur l'ecran d'un tube de Williams au moyen d'un analyseur multicanal a memoire en ferrite; Zapis' spektra impul'sov na ehkrane ehlektronno-luchevoj trubki mnogokanal'nogo analizatora s ferritovoj pamyat'yu; Registro multicanal del espectro de los impulsos en la pantalla del tubo electronico, en un analizador con memoria de ferrita

    Energy Technology Data Exchange (ETDEWEB)

    Rumler, Shtirad [Institut Yadernogo Issledovannya Chekhoslovatskoj Akldemii Nauk, Rzhezh Chekhoslovatskaya Sotsialisticheskaya Respublika (Czech Republic)

    1962-04-15

    mentionne. Cet enregistrement n'est pas assez precis, notamment lorsqu'on analyse des intermittentes caracterisees par une basse frequence de repetition et une faible moyenne du nombre des impulsions. La raison en est que le dechiffrage de l'information fournie s'effectue dans le canal a partir des circuits additionneurs et des circuits , l'enregistrement se passant directement sur l'ecran. L'insuffisance de l'enregistrement direct s'explique par la moyenne faible du nombre des impulsions et par leur distribution statistique. La methode proposee se revele dans le cas considere comme plus satisfaisante; en effet, la qualite de l'enregistrement ne depend ni de la forme du spectre ni de la vitesse de comptage des impulsions. Elle est utilisee dans le selecteur a 256 canaux dont la memoire en ferrite presente un temps mort de 15 microsecondes. Le cycle de la representation oscillographique alterne periodiquement avec celui de l'analyse du spectre a mesurer, la frequence de base etant de 50 Hz. Le temps necessaire a l'enregistrement oscillographique est d'environ 4 millisecondes soit 20% de la duree totale du cycle d'utilisation du selecteur dans les selecteurs ayant un nombre de canaux plus petit et une memoire en ferrite a temps mort plus court; la duree de l'enregistrement oscillographique ne represente qu'un faible pourcentage de la duree du cycle d'utilisation. (author) [Spanish] Se describe un diagrama de conjunto aplicable al establecimiento de programas operativos que permiten el registro multicanal de un espectro creciente de impulsos analizados en la pantalla del tubo electronico, en combinacion con una memoria estatica de ferrita. Los dipositivos comunes de registro directo en el tubo electronico, en algunos casos, resultan imperfectos en un analizador del tipo indicado. Se comprueba que el registro no es suficientemente claro, especialmente cuando se trata de analizar de impulsos momentaneos con baja frecuencia de repeticion y cuyo

  11. Partículas nanométricas de ferritas de ítrio

    Directory of Open Access Journals (Sweden)

    Godoi Ricardo H. M.

    1999-01-01

    Full Text Available Nanoparticles of yttrium iron garnet (YIG were obtained by coprecipitation. The particles were prepared by hydrolysis in acid medium with addition of ammonia or urea, for homogeneous nucleation, at 90ºC. Different compositions and spherical morphologies were achieved by changing reactants concentrations and precipitation agent. X-ray diffractometry, transmission electron microscopy, differential thermal analysis and electrophoretic mobility were carried out on these particles to investigate the obtained phase, phase transition temperature, morphology, particle size and zeta potential, respectively.

  12. Crystal phase analysis of SnO2-based varistor ceramic using the Rietveld method

    International Nuclear Information System (INIS)

    Moreira, M.L.; Pianaro, S.A.; Andrade, A.V.C.; Zara, A.J.

    2006-01-01

    A second addition of l mol% of CoO to a pre calcined SnO 2 -based ceramic doped with 1.0 mol% of CoO, 0.05 mol% of Nb 2 O 5 and 0.05 mol% of Cr 2 O 3 promotes the appearance of a secondary phase, Co 2 SnO 4 , besides the SnO 2 cassiterite phase, when the ceramic was sintered at 1350 deg. C/2 h. This was observed using X-ray powder diffraction, scanning electron microscopy and energy dispersive X-ray techniques. Rietveld refinement was carried out to quantify the phases present in the ceramic system. The results of the quantitative analysis were 97 wt.% SnO 2 and 3 wt.% Co 2 SnO 4 . The microstructural analysis showed that a certain amount of cobalt ion remains into cassiterite grains

  13. Influence of electric gas discharge to x-ray spectra on composite varistor based on ZnO-polymer

    International Nuclear Information System (INIS)

    Ahadzade, Sh.M.

    2016-01-01

    In work the X-ray spectrum of the composite resistors before and after being subjected to an electric discharge is carried out. It is found that the effect of electrical discharge on the samples greatly influences on the intensity of the diffraction reflexes. It was revealed that, the intensity of the reflections increases in dependence on the percentage of filler content in the case of samples exposed to electric discharge.

  14. Structural and morphological characteristics of composite: polyamide 6/ferrite nickel; Caracteristicas morfologicas e estruturais do composito: poliamida 6/ferrita de niquel

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, P.C.; Santos, P.T.A.; Silva, T.R.G.; Araujo, E.M.; Costa, A.C.F.M., E-mail: patricia.fernandes24@hotmail.co [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais

    2010-07-01

    This study aims to evaluate the structural and morphological characteristics of a composite polyamide 6 with 50% loading of nickel ferrite. The ferrite was obtained by combustion synthesis and calcined in muffle furnace at 700 deg C. The polymer matrix was previously dried in vacuum oven at 80 deg C / 48 h to eliminate moisture. The composites were characterized by XRD and SEM. XRD results show the incorporation of cargo in the matrix, and that increasing temperature led to a considerable increase in crystallinity. The particle size of the load in the matrix was changed by increasing temperature. (author)

  15. Reducción catalítica selectiva de NOx usando nanopartículas de ferritas Cu1-XCoXFe2O4 como catalizador

    Directory of Open Access Journals (Sweden)

    Sarah Briceño1*

    2009-12-01

    Full Text Available Nanostructured catalysts AB2O4 spinel type oxides (A = Co and B = Cu were prepared by the sol-gel self-combustion method using citric acid as precursor. They were characterized by X-ray diffraction (XRD, Scanning Electron Microscopy (SEM, Transmission Electron Microscopy (TEM and Catalytic activity tests, which have proven to be effective for selective catalytic reduction of NOx using hydrocarbon as a reducing agent (SCR-HC in a temperature range 250 - 450 ° C, reaching up to 40% conversion of NO and 100% selectivity towards the formation of N2

  16. Structural and magnetic Ni-Zn ferrite synthesized by combustion reaction and sintered in a conventional oven; Caracterizacao estrutural e magnetica de ferrita Ni-Zn sintetizadas por reacao de combustao e sinterizadas em forno convencional

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, D.A.; Diniz, V.C.S.; Costa, A.C.F.M., E-mail: deboralbq@hotmail.com [Universidade Federal de Campina Grande (UFCG), Campina Grande, PB (Brazil). Departamento de Engenharia de Materiais; Kiminami, R.H.G.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Departamento de Engenharia de Materiais; Cornejo, D.R. [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Instituto de Fisica. Departamento de Fisica dos Materiais e Mecanica

    2011-07-01

    The Ni-Zn ferrite due to their electrical and magnetic properties allows use in various technological applications. These properties can be controlled through appropriate choice of chemical composition, structural characteristics and morphology of the powders used and the techniques used for sintering. Thus, this study aims to evaluate the sintering in a conventional oven at a temperature of 1200 deg C/2h samples of Ni-Zn ferrite synthesized by microwave energy. The samples were characterized by density measurement, XRD, SEM and magnetic measurements. The results indicate the phase formation of Ni-Zn ferrite crystalline phase with crystallite size of 80 nm. The sample was heterogeneous microstructure with grain size of about 1 μm high intergranular porosity. The sample showed the saturation magnetization of 7.57 emu/g, coercive field and remanent magnetization close to zero, thus indicating a behavior characteristic of superparamagnetic materials. (author)

  17. Morphological and structural analysis of ferrite NiFe{sub 2}O{sub 4} doped with chromium; Analise estrutural e morfologica de ferrita NiFe{sub 2}O{sub 4} dopada com cromo

    Energy Technology Data Exchange (ETDEWEB)

    Costa, A.C.F., E-mail: anacristina@dema.ufcg.edu.br [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais; Viana, K.M.S. [Universidade Federal do Rio Grande do Norte (UFRN), Natal (Brazil). Escola de Ciencias e Tecnologia; Miola, E.J.; Antonio, S.G.; Kiminami, R.H.G.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil); Paiva-Santos, C.O. [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Araraquara, SP (Brazil). Departamento de Fisico-Quimica

    2011-07-01

    This paper reports on the effect of the substitution of Fe{sup 3+} for Cr{sup 3+} ions in the spinel lattice of the powders was investigated. Nickel ferrite powders with a NiFe{sub 2-x}Cr{sub x}O{sub 4} nominal composition (x = 0.0; 0.5; 1.0 and 1.5 mol of the chromium) were synthesized by combustion reaction using urea as fuel. The powders resulting were characterized by XRD, nitrogen adsorption by BET, SEM and Mössbauer spectroscopy ({sup 57}Fe Mössbauer spectra). The results show that the substitution of the Fe{sup 3+} for Cr{sup 3+} ions increased the crystalline degree of the phase, reduced the superficial area and consequently increased the particle size. The Mössbauer spectra of the samples also confirm the distribution of the particles size by the magnetic properties. Analyze of the spectra Mössbauer gives an estimate of the superparamagnetic and ferromagnetic particles behavior in each sample for several chromium concentrations. (author)

  18. Estudio magnético de compuestos de nanopartículas de [gamma]-ferrita dispersas en sílice mediante el efecto faraday y su aplicación a sensores de campo magnético

    OpenAIRE

    Rosa Palacios, Gregorio

    2004-01-01

    Se ha realizado un estudio de compuestos de g-Fe2O3/SiO2 a partir de desarrollos teóricos, simulaciones computacionales y pruebas experimentales. Estos experimentos se han basado en el efecto Faraday para determinar diferentes propiedades magnéticas del conjunto de nanopartículas. En este trabajo se describen los montajes experimentales desarrollados y los resultados obtenidos, así como su adecuación tanto a la teoría como a las simulaciones computacionales. Se ha conseguido determinar tamaño...

  19. Synthesis and sintering Ni-Zn ferrite obtained for combustion reaction in large scale; Sintese e sinterizacao de ferrita Ni-Zn obtida por reacao de combustao em larga escala

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, D.A., E-mail: debora.vieira@cear.ufpb.br [Universidade Federal da Paraiba (UFPB), Joao Pessoa, PB (Brazil). Centro de Energias Alternativas e Renovaveis; Diniz, V.C.S.; Costa, A.C.F.M. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Departamento de Ciencias e Engenharia de Materiais; Cornejo, D.R. [Universidade de Sao Paulo (USP), SP (Brazil). Instituto de Fisica; Kiminami, R.H.G.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Departamento de Ciencias e Engenharia de Materiais

    2014-07-01

    This research proposes to evaluate the magnetic properties of ferrite Ni-Zn synthesized by combustion reaction on a large scale and sintered at 1250 deg C in resistive furnace. The sample was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and magnetic measurements. The results show that the synthesized product in large scale resulted in soft magnetic material with saturation magnetization of 40 emu·g{sup -1} and coercivity of 0.080 kOe, after sintering it was observed an increase to 68 emu·g{sup -1} in the magnetization and a reduction to 0.016 kOe in coercivity, indicating that the obtained material has promising characteristics for applications in electro-electronic devices. (author)

  20. Magnetic and microstructural properties of Ni-Zn ferrites synthesized and sintered by microwave energy; Propriedades magneticas e microestruturais de ferritas Ni-Zn sintetizadas e sinterizadas oir energia de microondas

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, D.A.; Diniz, V.C.S.; Sousa, J-P.LM.L.; Costa, A.C.F.M. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Dept. de Engenharia de Materiais; Kiminami, R.H.G.A. [Universidade Federal de Sao Carlos (UFScar), SP (Brazil). Dept. de Engenharia de Materiais; Cornejo, D.R. [Universidade de Sao Paulo (IF/USP), SP (Brazil). Inst. de Fisica

    2009-07-01

    The soft ferrites (or soft) and the Ni-Zn type are composed of spinel with cubic structure, which exhibit a permanent magnetization, called ferrimagnetism. Thus, this work will be assessed the structure and magnetic properties of ferrites Ni{sub 0},{sub 5}Zn{sub 0},{sub 5}Fe{sub 2}O{sub 4} prepared by combustion reaction using microwave energy as a source of heat and urea as fuel and after sintering by microwave energy. The synthesized powders were compacted by uniaxial pressing. The synthesized powders and the samples after sintering were characterized by XRD, SEM and magnetic measures. The diffractogram X-ray powder and the sintered samples showed the presence of the desired phase Ni{sub 0},{sub 5}Zn{sub 0},{sub 5}Fe{sub 2}O{sub 4} in both cases. The powders and sintered samples resulted in the Ms value of 8.09 emu/g and 67.73 emu/g, respectively. (author)

  1. Perekond Pärna film tõi Eestile esimese koduvõidu / Tiit Tuumalu

    Index Scriptorium Estoniae

    Tuumalu, Tiit, 1971-

    2008-01-01

    Animafilmide festivali "Animated Dreams" võitis Priit ja Olga Pärna joonisfilm "Elu ilma Gabriella Ferrita". Samuti esitati see Põhjamaade ja Balti riikide animafestivalide ühise auhinna ANOBA nominendiks. Ka teistest auhinnatutest

  2. Animeeritud unistused said juba kümnendat korda tõeks / Kristiina Davidjants

    Index Scriptorium Estoniae

    Davidjants, Kristiina, 1974-

    2008-01-01

    Animafilmide festivali "Animated Dreams" võitis Priit ja Olga Pärna joonisfilm "Elu ilma Gabriella Ferrita". Samuti esitati see Põhjamaade ja Balti riikide animafestivalide ühise auhinna ANOBA nominendiks

  3. Estonskije filmõ stali laureatami festivalei

    Index Scriptorium Estoniae

    2008-01-01

    Sõltumatu kino 35. festivalil Brüsselis sai peaauhinna Veiko Õunpuu "Sügisball" ja animafilmifestivalil Utrechtis Hollandis võitis peapreemia Priit ja Olga Pärna joonisfilm "Elu ilma Gabriella Ferrita"

  4. Microstructural and magnetic study of ferrites Ni{sub 0,5}Zn{sub 0,5}Fe{sub 2}O{sub 4} sintered by microwave energy; Estudo microestrutral e magnetico de ferritas Ni{sub 0,5}Zn{sub 0,5}Fe{sub 2}O{sub 4} sinterizadas por energia de micro-ondas

    Energy Technology Data Exchange (ETDEWEB)

    Diniz, V.C.S.; Costa, A.C.F.M., E-mail: veronicacristhina@hotmail.com [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Programa de Pos-Graduacao em Ciencias e Engenharia de Materiais; Kiminami, R.H.G.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Departamento de Engenharia de Materiais; Cornejo, D.R. [Universidade de Sao Paulo (USP), SP (Brazil). Instituto de Fisica

    2014-07-01

    The study of the processing of Ni-Zn ferrite is of extreme importance to improve its magnetic properties, as they are directly influenced by the final microstructure of the material. This study evaluated the influence of exposure time in the sintering of Ni-Zn ferrite phase by microwave energy, and its subsequent microstructural characterization, and magnetic. The samples of Ni-Zn ferrite were sintered using microwave energy at a temperature of 1200 °C and an exposure time of 10, 20 and 30 minutes, respectively. Then were characterized by X-ray diffraction spectroscopy, scanning electron microscopy and magnetic measurements. With the results, it was observed that all samples obtained from the formation Ni{sub 0,5}Zn{sub 0,5}Fe{sub 2}O{sub 4} phase with all high intensity peaks. It was possible to obtain a nanostructure with maximum saturation magnetization of 71 emu / g for the sample sintered in longer exposure time. (author)

  5. Ferrite re-crystallization kinetics on a C-Mn steel and on two micro alloyed steels after dual-phase strain; Cinetica de recristalizacao da ferrita em um aco C-Mn e dois acos microligados apos deformacao na regiao bifasica

    Energy Technology Data Exchange (ETDEWEB)

    Simieli, Eider A. [Instituto de Pesquisas Tecnologicas (IPT), Sao Paulo, SP (Brazil)

    1991-12-31

    Ferrite recrystallization was investigated in two micro alloyed steels deformed in the inter critical range. A reference steel was also used, which had a composition of 0,06% C and 1,31% Mn. (author). 15 refs., 7 figs., 3 tabs.

  6. Ferrites Ni{sub 0,5}Zn{sub 0,5}Fe{sub 2}O{sub 4} doped with samarium: structural analysis, morphological and electromagnetic; Ferritas Ni{sub 0,5}Zn{sub 0,5}Fe{sub 2}O{sub 4} dopada com samario: analise estrutural, morfologica e eletromagnetica

    Energy Technology Data Exchange (ETDEWEB)

    Costa, A.C.F.M.; Diniz, A.P., E-mail: anacristina@dema.ufcg.edu.br [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academinca de Engenharia de Materiais; Viana, K.M.S. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, PE (Brazil). Escola de Ciencias e Tecnologia; Cornejo, D.R. [Universidade de Sao Paulo (USP), SP (Brazil). Instituto de Fisica; Kiminami, R.H.G.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Departamento de Engenharia de Materiais

    2010-07-01

    This paper proposes to investigate the sintering at 1200 deg C/2h of Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2-x}Sm{sub x}O{sub 4} ferrite doped with 0.05; 0.075 e 0.1 mol of Sm synthesized by combustion reaction to evaluate the performance materials as absorbers of electromagnetic radiation. The influence of the concentration of samarium on the structure, morphology and electromagnetic properties of ferrites was studied. The resulting samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), magnetic measurements and reflectivity measurements in the frequency range between 8-12 GHz. The results showed that increasing the concentration of samarium caused a decrease in particle size of the samples, encouraging, therefore, to obtain materials with better values of magnetization and reflectivity, allowing for use as absorbers in narrow-band frequency between 9-10 GHz. (author)

  7. Synthesis and characterization of magnetic cobalt ferrite nanoparticles covered with 3-aminopropyltriethoxysilane for use as hybrid material in nano technology; Sintese e caracterizacao de nanoparticulas magneticas de ferrita de cobalto recobertas por 3-aminopropiltrietoxissilano para uso como material hibrido em nanotecnologia

    Energy Technology Data Exchange (ETDEWEB)

    Camilo, Ruth Luqueze

    2006-07-01

    Nowadays with the appear of nano science and nano technology, magnetic nanoparticles have been finding a variety of applications in the fields of biomedicine, diagnosis, molecular biology, biochemistry, catalysis, etc. The magnetic functionalized nanoparticles are constituted of a magnetic nucleus, involved by a polymeric layer with active sites, which ones could anchor metals or selective organic compounds. These nanoparticles are considered organic inorganic hybrid materials and have great interest as materials for commercial applications due to the specific properties. Among the important applications it can be mentioned: magneto hyperthermia treatment, drugs delivery in specific local of the body, molecular recognition, biosensors, enhancement of nuclear magnetic resonance images quality, etc. This work was developed in two parts: 1) the synthesis of the nucleus composed by superparamagnetic nanoparticles of cobalt ferrite and, 2) the recovering of nucleus by a polymeric bifunctional 3-aminopropyltriethoxysilane. The parameters studied in the first part of the research were: pH, hydroxide molar concentration, hydroxide type, reagent order of addition, reagent way of addition, speed of shake, metals initial concentrations, molar fraction of cobalt and thermal treatment. In the second part it was studied: pH, temperature, catalyst type, catalyst concentration, time of reaction, relation ratios of H{sub 2}O/silane, type of medium and the efficiency of the recovering regarding to pH. The products obtained were characterized using the following techniques X-ray powder diffraction (DRX), transmission electronic microscopy (TEM), scanning electronic microscopy (SEM), spectroscopy of scatterbrained energy spectroscopy (DES), atomic emission spectroscopy (ICP-AES), thermogravimetric analysis (TGA/DTGA), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and magnetization curves (VSM). (author)

  8. Nanopartículas magnéticas de zinc y calcio para aplicaciones en hipertermia magnética

    Directory of Open Access Journals (Sweden)

    Rosario Argentina Jasso-Terán

    2016-05-01

    Full Text Available El cáncer es la segunda causa de muerte en el mundo. El tratamiento alternativo de hipertermia magnética consiste en elevar la temperatura de las células cancerígenas por medio de nanopartículas magnéticas. En este trabajo se presenta la síntesis y la caracterización de dos ferritas de zinc-calcio (Zn0.50Ca0.50Fe2O4 y Zn0.25Ca0.75Fe2O4. La síntesis de estas ferritas se llevó a cabo por el método de sol-gel, con posterior calcinación a 400 °C. La ferrita Zn0.50Ca0.50Fe2O4 (ZCF050 presentó una magnetización de 31.31 emu/g, y la ferrita Zn0.25Ca0.75Fe2O4 (ZCF075, de 38.30 emu/g. El tamaño de partícula promedio fue de 14 nm para la ZCF050 y de 12 nm para la ZCF075. Adicionalmente, se realizaron pruebas de bioactividad in vitro mediante la inmersión de muestras en un fluido fisiológico simulado por 21 días bajo condiciones fisiológicas de pH y temperatura. Se encontró que solo la ZCF075 fue bioactiva. La habilidad de calentamiento de las ferritas se evaluó utilizando un equipo de inducción magnética en estado sólido. Las condiciones de trabajo fueron las siguientes: un campo magnético de 10.2 kA/m y una frecuencia de 362 kHz. La ferrita ZCF050 alcanzó una temperatura de 41.2 °C, utilizando una concentración de ferrita/agua de 20 mg/2ml. La ferrita ZCF075 no logró alcanzar los 40 °C. Los resultados obtenidos del análisis de la ferrita ZCF050 indicaron que es un material potencial para su uso en tratamientos de cáncer por hipertermia magnética.

  9. Estudio comparativo de dos métodos de síntesis para la obtención de polvos cerámicos de ZnO - Pr2O3 - CoO

    OpenAIRE

    Rodríguez-Páez, J. E.; Caballero, A. C.; Villegas, M.; Cruz, A. M.; Ávila, H.

    2004-01-01

    Zinc oxide containing rare earth metal and Cobalt oxide are utilized as raw material to make varistors. Some of systems were found to exhibit non-ohmic current-voltaje characteristics and they are applicable not only for low voltaje devices but also for hight voltaje electric power stations. The microstructure of ZnO varistor can be considered as a vehicle thorugh which all of these properties ara manifested. Therefore, a discussion of the microstructure cannot be separated from a discussion ...

  10. Modification of the ferrite load Ni{sub 0,5}Zn{sub 0,5}Fe{sub 2}O{sub 3} by silane agent for improving the interface in the absorbing composite; Modificacao da carga de ferrita Ni{sub 0,5}Zn{sub 0,5}Fe{sub 2}O{sub 3} por agente silano para melhoria da interface no composito absorvedor

    Energy Technology Data Exchange (ETDEWEB)

    Menezes, P.C.F.; Santos, P.T.A.; Silva, T.R.G.; Costa, A.C.F.M.; Araujo, E.M., E-mail: patricia.fernandes24@hotmail.com.br [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Departamento de Engenharia de Materiais

    2014-07-01

    The main challenge of composite materials processing technology is the obtaining of an adequate interface between the components of a composite. Thus, this work aims to promote the modification of the ferrite load surface Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 3} (inorganic), by the silane agent (3-aminopropyltriethoxysilane) for introduction into the matrix of silicone (organic) rubber, and thus obtaining a efficient composite for use in electromagnetic radiation absorbing materials.

  11. Synthesis and characterization of nanoparticles ferrites of the type ZN{sub x}Cu{sub 1-x}FE{sub 2}O{sub 4} and your application catalyst in acetylation vegetable oils; Sintese e caracterizacao de nanoparticulas de ferritas do tipo Zn{sub x}Cu{sub 1-x}Fe{sub 2}O{sub 4} e a sua aplicacao como catalisador em acetilacao em oleos vegetais

    Energy Technology Data Exchange (ETDEWEB)

    Casagrande, D.S; Costa, W.V; Hechenleitner, A.A.W.; Oliveira, D.M.F. de; Pineda, E.A.G., E-mail: diogo_casagrande@msn.com [Universidade Estadual de Maringa (UEM), PR (Brazil)

    2016-07-01

    In this work were synthesized copper and zinc ferrites (0 - 10% mol with respect to copper), by the combustion method, using citrate as stabilizer. The obtained products were analyzed by Infrared spectrometry (FTIR), Raman spectroscopy (RAMAN) and x-ray diffractometry (DRX). Synthesized ferrites present hematite phase, maghemite phase and copper ferrite phases. The analysis indicated that increasing the zinc content leads to decreased of hematite phase. Increasing of zinc content lead to an increase of particle size. The best results of oil acylation were obtained with ferrites containing 2 and 4% of zinc, wherein the increase the increase of yield of acetylated product reached at 19% when compared with the yield obtained whit copper ferrite without zinc. (author)

  12. Study of the effect of dilution on the microstructural and magnetic properties of Mn{sub 0.65}Zn{sub 0.35}Fe{sub 2}O{sub 4} ferrites by combustion reaction; Estudo do efeito da diluicao nas propriedades microestruturais e magneticas de ferritas Mn{sub 0.65}Zn{sub 0.35}Fe{sub 2}O{sub 4} por reacao de combustao

    Energy Technology Data Exchange (ETDEWEB)

    Santos, R.L.P.; Costa, A.C.F.M., E-mail: raffitasantos8@hotmail.com [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Dept. de Engenharia de Materiais; Diniz, V.C.S., E-mail: veronicacristhina@hotmail.com, E-mail: c_r_i_s_2005@yahoo.com.br [Universidade Federal de Campina Grande (UFCG), Campina Grande, PB (Brazil). Dept. de Engenharia de Materiais; Kiminami, R.H.G.A., E-mail: ruth@ufscar.br [Universidade de Sao Carlos (UFSCar), Sao Carlos, SP (Brazil). Dept. de Engenharia de Materiais; Cornejo, D.R., E-mail: cornejo@if.usp.br [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Instituto de Fisica

    2016-10-15

    The Mn-Zn ferrites have been used in various technological areas, due to their attractive properties in technical and scientific senses. This paper aimed to synthesize Mn{sub 0.65}Zn{sub 0.35}Fe{sub 2}O{sub 4} ferrites by combustion reaction and evaluate the effect of dilution of the reactants in distilled water on the microstructural and magnetic characteristics. The samples were characterized by X-ray diffraction, scanning and transmission electron microscopy, Curie temperature and magnetic measurements. It was observed that increasing dilution with water during synthesis by combustion reaction was favorable for obtaining monophasic Mn{sub 0.65}Zn{sub 0.35}Fe{sub 2}O{sub 4} ferrite. It also favored a decrease in the agglomerate size and an increase in Curie temperature with maximum value of saturation magnetization of 62 emu/g for the sample diluted in 1:10 ratio. (author)

  13. Influence of Zn{sup 2+} content on morphological and magnetic properties of Mn{sub 1-x}Zn{sub x}Fe{sub 2}O{sub 4} ferrites synthesized on a large scale by combustion reaction; Influencia do teor de Zn{sup 2+} nas caracteristicas morfologicas e magneticas de ferritas Mn{sub 1-x}Zn{sub x}Fe{sub 2}O{sub 4} sintetizados em grande escala por reacao de combustao

    Energy Technology Data Exchange (ETDEWEB)

    Diniz, V.C.S.; Silveira Junior, J.E.R.; Costa, A.C.F.M., E-mail: veronicacristhina@hotmail.com, E-mail: juniorramos_1@hotmail.com, E-mail: c_r_i_s_2005@yahoo.com.br [Universidade Federal de Campina Grande (UFCG), Campina Grande, PB (Brazil). Departamento de Engenharia de Materiais; Cornejo, D.R., E-mail: cornejo@if.usp.br [Universidade de Sao Paulo (USP), SP (Brazil). Instituto de Fisica; Kiminami, R.H.G.A., E-mail: ruth@ufscar.br [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Departamento de Engenharia de Materiais

    2017-04-15

    This study aimed to evaluate the influence of Zn{sup 2+} in the morphological and magnetic characteristics of ferrites Mn{sub 1-x}Zn{sub x} Fe{sub 2} O{sub 4} (where x= 0.0, 0.35, 0.5 and 0.65 mol of Zn) synthesized by combustion reaction in a pilot scale with batches of 200 g/reaction. The samples were characterized by X-ray diffraction, scanning/transmission electron microscopy, and magnetic measurements. The results indicated that all compositions were single phase of ferrite; morphologically the addition of Zn to MnFe{sub 2} O{sub 4} system caused a slight reduction in size of the agglomerates, and reduced the particle size, but this behavior was not linear with the Zn{sup 2+} content. The samples had characteristic magnetic behavior of soft magnetic materials, maximum saturation magnetization of 62 emu/g for the sample with lower zinc content in its composition. (author)

  14. Ni{sub 0,5}Zn{sub 0,5}Fe{sub 2}O{sub 3} ferrite synthesized by combustion and Pechini method for use in nanomedicine: methods evaluation; Ferrita Ni{sub 0,5}Zn{sub 0,5}Fe{sub 2}O{sub 3} sintetizada por reacao de combustao e metodo Pechini para uso na nanomedicina: avaliacao dos metodos

    Energy Technology Data Exchange (ETDEWEB)

    Albuquerque, I.L.T. de; Nascimento, A.L.C.; Costa, A.C.F.M., E-mail: allana.layla@gmail.com [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais

    2016-07-01

    The objective of this work was to synthesize the Ni0.5Zn0.5Fe2O3 ferrite by combustion reaction and Pechini method, and to evaluate structural characteristics and magnetic behavior for its use in nanomedicine. The synthesized ferrite was characterized by DRX, BET, TG and magnetic properties. According to the results of XRD, the Ni{sub 0,5}Zn{sub 0,5}Fe{sub 2}O{sub 3} ferrite synthesized by both methods presented nano crystallite sizes, high crystallinity, surface area, stable at high temperatures and with high saturation magnetization, being higher in the ferrite synthesized by combustion reaction. Both methods produced materials that could be used in nanomedicine.

  15. Pärn(ad) fookuses, sedapuhku Londonis / Stuart Sweeney

    Index Scriptorium Estoniae

    Sweeney, Stuart

    2009-01-01

    Londoni animafilmide festival pühendas ühe programmi Priit ja Olga Pärna uuemale loomingule. Ka 2009.a. parima Balti- ja Põhjamaade animafilmi auhinna - ANOBA auhinna, sai Olga ja Priit Pärna joonisfilm "Elu ilma Gabriella Ferrita". Viimane oli valitud ka suvise Austraalia festivali kavva

  16. Nonlinear current-voltage characteristics of WO3-x nano-/micro-rods

    Science.gov (United States)

    Shen, Zhenguang; Peng, Zhijian; Zhao, Zengying; Fu, Xiuli

    2018-04-01

    A series of crystalline tungsten oxide nano-/micro-rods with different compositions of WO3, WO2.90, W19O55 (WO2.89) and W18O49 (WO2.72) but identical morphology feature were first prepared. Then, various nanoscaled electrical devices were fabricated from them by micro-fabrication through a focused ion beam technique. Interestingly, the devices from the oxygen-deficient WO3-x display significantly nonlinear current-voltage characteristics. The calculated nonlinear coefficients of the WO2.90, WO2.83, and WO2.72 varistors are 2.52, 3.32 and 4.91, respectively. The breakdown voltage of the WO2.90, WO2.83, and WO2.72 varistors are 1.93, 1.28 and 0.93 V, respectively. Such WO3-x nano-varistors might be promising for low-voltage electrical/electronic devices.

  17. Young Investigator Program: Quasi-Liquid Grain Boundary Films in Refractory Metals

    Science.gov (United States)

    2010-01-15

    Bi2O3 based varistors [29, 44, 85] ( Ba , Sr )TiO3-based sensors and actuators [86-91] Thermal conductivity in AlN [92, 93] High-Tc...varistors [29, 85], functions of ( Sr , Ba )TiO3 based sensors and actuators [86-91], thermal conductivity of AlN substrates [92, 93], and critical currents...independent ion beam to sputter the specimen surface while collecting the Auger electron spectrum. The Auger experiments were conducted at Oak Ridge National

  18. Estudio comparativo de dos métodos de síntesis para la obtención de polvos cerámicos de ZnO-Pr2O3-CoO

    OpenAIRE

    Villegas, Marina; Caballero Cuesta, Amador; Ávila, H.; Cruz, Ana Milena; Rodríguez Páez, Jorge E.

    2004-01-01

    [ES] Los polvos cerámicos de ZnO - Pr2O3 - CoO son utilizados como materia prima para la fabricación de varistores. Estos dispositivos presentan una característica corriente - voltaje altamente no lineal que permiten su uso como conmutadores de estado sólido con capacidad de manejar altas energías. La discusión de las propiedades de los varistores no se puede realizar de manera separada de una discusión sobre su microestructura ya que ésta se puede considerar como un medio a través d...

  19. Sintesis de ceramicos de ZnO dopados con praseodimio y cobalto

    Directory of Open Access Journals (Sweden)

    Ana Milena Cruz

    2003-06-01

    Full Text Available Zinc oxide, ZnO, is a very interesting compound in science and electronic ceramics technology. ZnO ceramics containing some additives were reported to show varistor action with excellent nonlinearity in current - voltage characteristics. However, investigations were restricted to the ZnO - Bi2O3 ceramic system. Other type of varistor, which contains praseodymium oxide, also present nonlinear behaviour. In this work, results obtained in the synthesis Zn-Pr-Co powder are shown. In order to determine and control the several stages of the chemical method, potentiometric titration was used. The solid phase obtained was pressed and sintered.

  20. Nonlinear I–V characteristics study of doped SnO2

    Indian Academy of Sciences (India)

    Unknown

    type semiconductor with many interesting electronic pro- perties. Tin oxide ... The current–voltage curves were plotted on log–log scale from which the ... 4. Conclusion. A new varistor system based on doped SnO2 system is prepared and it ...

  1. 75 FR 27422 - Airworthiness Directives; Hawker Beechcraft Corporation (Type Certificate No. A00010WI Previously...

    Science.gov (United States)

    2010-05-17

    ... lightning strike protection for proper installation of metal oxide varistor (MOV) and spark gap wiring. This... issuing this AD to detect and correct improper installation of the MOV and spark gap wiring, which could.... September 2009. wiring installation for the MOV and spark gap. Alternative Methods of Compliance (AMOCs) (g...

  2. Research Article Special Issue

    African Journals Online (AJOL)

    2017-08-08

    Aug 8, 2017 ... fects of doping material on microstructure ZnO and nonlinear characte ristor ceramics ..... [2] Gupta T K. Application of zinc oxide varistors. ... [5] Wang M H, Zhao Z Y, Liu T T. Synthesis of Pr-doped ZnO nanoparticles by sol–gel.

  3. Improved zinc oxide film for gas sensor applications

    Indian Academy of Sciences (India)

    Zinc oxide (ZnO) is a versatile material for different commercial applications such as transparent electrodes, piezoelectric devices, varistors, SAW devices etc because of its high piezoelectric coupling, greater stability of its hexagonal phase and its pyroelectric property. In fact, ZnO is a potential material for gas sensor ...

  4. A METHOD OF DETERMINING THE ABILITY OF THE ARRESTER TO ABSORB ENERGY WITHOUT BREAKING THE HEAT BALANCE

    Directory of Open Access Journals (Sweden)

    S.Yu. Shevchenko

    2015-08-01

    Full Text Available Purpose.The aim of this study is to obtain a method for determining the capacity surge arrester nonlinear absorb energy without breaking the heat balance in modes of long-term application of operating voltage, which allows for analysis of their work in terms of violations as electricity. Methodology. For values of the energy passing through the arrester must be able to determine the current value for the voltage value in the area of leakage current-voltage characteristics. We have carried out calculations of the energy passing everywhere arrester for certain periods of time based on the current-voltage characteristics obtained experimentally. Analysis of the experimental current-voltage characteristics of resistors and literature led to the important conclusion that the dielectric properties of the ceramic varistor affect the value of active power losses in the arrester only when the active component of the leakage current is very small. This is confirmed by the characteristics of different classes of varistor voltage. This property of varistors and surge arresters shows the need to consider how the dielectric and conductive properties of the varistor ceramics in the analysis of work in the area of the arrester leakage current-voltage characteristic. These results demonstrate the need to clarify the mathematical model and the method for determining the energy dissipates in the area of the arrester leakage current CVC with their account. Results. The study, an improved mathematical model for calculating energy affects surge arrester during its working life. The study obtained the method, of evaluation capacity surge arrester, maintains heat balance throughout working life. Based on experimentally obtained current-voltage characteristic of the varistors is defined voltage at which surge arrester starts conducting active current. This allowed to receive specified mathematical model for calculating energy affects surge arrester and develop a method

  5. PÖFFi võitis poliitiline näljastreik / Tiit Tuumalu

    Index Scriptorium Estoniae

    Tuumalu, Tiit, 1971-

    2008-01-01

    12. PÖFFi auhinnasaajad : Euraasia võistlusprogrammi võit langes Steve McQueeni mängufilmile "Nälg" ("Hunger"). Balti filmidest oli parim Laila Pakalnina ja Maris Maskalansi dokumentaalfilm "Kolm meest ja kalatiik". Eesti filmidest oli parim Priit ja Olga Pärna "Elu ilma Gabriella Ferrita". Žüriid juhtis Hollandi režissöör Jos Stelling. Lisatud võitjate nimekiri

  6. Efectos gammágenos del cobre en los aceros inoxidables 18Cr8Ni

    Directory of Open Access Journals (Sweden)

    Botella, J.

    1997-10-01

    Full Text Available From a series of 22 typical 18Cr8Ni stainless steel 40 kg ingots, with copper variable concentrations from 0.6 to 3.0 weight %, δ-ferrite is measured with a ferrite-meter device, calculating a nickel equivalent of 0.27 for copper. Some differences between the 8-ferrite and that on calculated by DeLong -excluding the copper γ-gene action- have been found because of different solidification and cooling regimes in ingot and weld cases.

    A partir de una serie de 22 lingotes de 40 kg de aceros inoxidables típicos 18Cr8Ni, con concentraciones variables de cobre entre 0,6 y 3,0 % en masa, se mide la ferrita δ mediante un medidor de ferrita y se deduce para el cobre un equivalente en níquel de 0,27, a la vez que se establecen ciertas diferencias entre los contenidos de ferrita δ medida y la deducida según DeLong -excluida la acción gammágena del cobre- por el hecho de solidificar en lingotes en vez de la típica solidificación de soldaduras.

  7. The influence of the cations Cu{sup +2}/Co{sup +2}/Nd{sup +3} at the ferrite Mi{sub 0,2}Y{sub 0,3}Zn{sub 0,5}Fe{sub 2}O{sub 4} at different temperatures; Estudo da influencia dos cations Cu{sup +2}/Co{sup +2}/Nd{sup +3} na ferrita Mi{sub 0,2}Y{sub 0,3}Zn{sub 0,5}Fe{sub 2}O{sub 4} em diferentes temperaturas

    Energy Technology Data Exchange (ETDEWEB)

    Lima, U.R., E-mail: ulisandra.lima@ifrn.edu.br [Instituto Federal de Educacao, Ciencia e Tecnologia do Rio Grande do Norte (IFRN), Sao Paulo do Potengi, RN (Brazil); Nasar, R.S.; Nasar, M.C.; Silva, J.E.M. da [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Programa de Pos-Grduacao em Quimica

    2016-07-01

    The work consisted of Ni{sub 0,2}Y{sub 0,3}Zn{sub 0,5}Fe{sub 2}O{sub 4} composition ferrites synthesis ranging copper ions (Cu{sup +2}), cobalt (Co{sup +2}) and neodymium (Nd{sup +3}) whose objective is to evaluate the particle size by the method citrate precursor. After synthesis, the samples were calcined at 350° C and subsequently sintered at 1000° for 3 hours, with controlled heating and cooling rate. The calcined materials were characterized by XRD and SEM showed that the method of the precursor citrate is an effective method. The X-ray diffraction spectra and refinement show good agreement between the experimental peaks and the theoretical spectrum. In Scanning Electron Microscopy (SEM), the samples to 350° C/3h, have dimensions in the micrometer order in all compositions. The average size of the crystals are consistent with the higher definition and intensity of peaks of X-rays, that is, there is high correlation with those obtained by refining method. (author)

  8. Computation of the current density in nonlinear materials subjected to large current pulses

    International Nuclear Information System (INIS)

    Hodgdon, M.L.; Hixson, R.S.; Parsons, W.M.

    1991-01-01

    This paper reports that the finite element method and the finite difference method are used to calculate the current distribution in two nonlinear conductors. The first conductor is a small ferromagnetic wire subjected to a current pulse that rises to 10,000 Amperes in 10 microseconds. Results from the transient thermal and transient magnetic solvers of the finite element code FLUX2D are used to compute the current density in the wire. The second conductor is a metal oxide varistor. Maxwell's equations, Ohm's law and the varistor relation for the resistivity and the current density of p = αj -β are used to derive a nonlinear differential equation. The solutions of the differential equation are obtained by a finite difference approximation and a shooting method. The behavior predicted by these calculations is in agreement with experiments

  9. On the I-V characteristic in the non-linear tenary mixture model for polycrystalline semiconductors

    International Nuclear Information System (INIS)

    Nguyen Van Lien; Nguyen Hoai Nam

    2000-08-01

    A simple expression for the voltage dependence of grain-boundary potential barrier heights is proposed and the Effective Medium Approximation is extended for calculating the I-V characteristic in tenary mixtures of highly non-linear circuit elements. Numerical calculations are performed for the case of polycrystalline semiconductors, such as ZnO-based varistors, where the thermoionic emission is believed to be the dominant mechanism for the electric conduction across double Schottky barriers at room temperature. (author)

  10. Microstructure and electrical properties in SnO2 ceramics with sequential addition of Co, Sb and Ca

    International Nuclear Information System (INIS)

    Aguilar-Martinez, J A; Hernandez, M B; Glot, A B; Pech-Canul, M I

    2007-01-01

    The effect of sequential additions of Co 3 O 4 , Sb 2 O 5 and CaCO 3 on the microstructure and electrical behaviour of SnO 2 -based ceramics was investigated. Although without conferring varistor properties, Co 3 O 4 additions promote densification in the material. Successive addition of Sb 2 O 5 provides the sample varistor properties but with low nonlinearity coefficient (α = 5.7) and high electric field (E 1 = 2022 V cm -1 ) at current density 10 -3 A cm -3 . Moreover, antimony oxide addition degrades the microstructure condition by inducing porosity. Subsequent addition of CaCO 3 promotes densification and grain growth. However, it does not lead to the increase in the nonlinearity coefficient. It only lowers the electric field, thus making the material suitable for lower voltage applications. Observed significant increase in the relative dielectric permittivity up to a factor of about 60 and 200 in the cases of antimony or antimony and calcium addition to SnO 2 -Co 3 O 4 (accompanied by the appearance of varistor effect) is due to the formation of barrier depletion layers at grain boundaries

  11. Comparison of ANSI, IEC and CSA standards durability requirements on station-type metal oxide surge arresters for EHV power systems

    International Nuclear Information System (INIS)

    Hamel, A.; St-Jean, G.

    1992-01-01

    This paper presents an analysis of stresses applied to two actual types of station class surge arresters of the same voltage rating when tested for durability as prescribed by American (ANSI) International (IEC) and Canadian (CSA) standards for 315 kV and 734 kV power systems. The analysis which is made with an experimentally validated arrester model, reveals that the IEC duty cycle test is the most severe of all. In fact it can bring the varistors of an actual station-type arrester to a peak temperature of 129 degrees C, which leaves a margin of only 46 degrees C to its thermal stability limit at maximum continuous operating voltage (MCOV). Another actual arrester using lesser V-I-T varistor characteristics but larger varistor volume and better heat transfer from inside to outside the arrester, produces 103 degrees C which corresponds to a slightly better temperature margin of 49 degrees C. It is observed that even when using the lower performance V-I-T characteristics of the latter arrester, a thin-wall arrester housing design can improve heat transfer to a point where the margin improves to 101 degrees C on a hypothetical arrester

  12. Microstructure and electrical properties in SnO{sub 2} ceramics with sequential addition of Co, Sb and Ca

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar-Martinez, J A [Instituto de MinerIa, Universidad Tecnologica de la Mixteca, Carretera a Acatlima Km. 2.5, Huajuapan de Leon, Oaxaca 69000 (Mexico); Hernandez, M B [Instituto de Diseno, Universidad Tecnologica de la Mixteca, Carretera a Acatlima Km. 2.5, Huajuapan de Leon, Oaxaca 69000 (Mexico); Glot, A B [Division de Posgrado, Universidad Tecnologica de la Mixteca, Carretera a Acatlima Km. 2.5, Huajuapan de Leon, Oaxaca 69000 (Mexico); Pech-Canul, M I [Cinvestav Saltillo, Carr. Saltillo-Mty Km 13 Apdo., Saltillo Coahuila 25000 (Mexico)

    2007-11-21

    The effect of sequential additions of Co{sub 3}O{sub 4}, Sb{sub 2}O{sub 5} and CaCO{sub 3} on the microstructure and electrical behaviour of SnO{sub 2}-based ceramics was investigated. Although without conferring varistor properties, Co{sub 3}O{sub 4} additions promote densification in the material. Successive addition of Sb{sub 2}O{sub 5} provides the sample varistor properties but with low nonlinearity coefficient ({alpha} = 5.7) and high electric field (E{sub 1} = 2022 V cm{sup -1}) at current density 10{sup -3} A cm{sup -3}. Moreover, antimony oxide addition degrades the microstructure condition by inducing porosity. Subsequent addition of CaCO{sub 3} promotes densification and grain growth. However, it does not lead to the increase in the nonlinearity coefficient. It only lowers the electric field, thus making the material suitable for lower voltage applications. Observed significant increase in the relative dielectric permittivity up to a factor of about 60 and 200 in the cases of antimony or antimony and calcium addition to SnO{sub 2}-Co{sub 3}O{sub 4} (accompanied by the appearance of varistor effect) is due to the formation of barrier depletion layers at grain boundaries.

  13. Cinéticas de transformación de fases a 850 ºC de aceros inoxidables dúplex clásicos (2205 y 2507 y de uno nuevo de bajo contenido en níquel y alto en manganeso (DBNi

    Directory of Open Access Journals (Sweden)

    Rodríguez, M. P.

    2004-04-01

    Full Text Available Austenitic-ferritic stainless steels are formed by ferrite and austenite in a variable proportion between 30 % and 70 %. Their chemical composition conditions the ageing processes that can happen during heat treatments, where phases that hardens and brittles the material can be generated. Evolution of a new duplex stainless steel with lower nickel and higher nitrogen and manganese content maintained at 1123 K (critical precipitation temperature up to 8 hours compared to classical ones (2205 and 2507 is presented. The study, done by magnetic measurements, XRD, optical and scanning electron microscopy and microanalysis, revealed a roughly similar behaviour for the three steels. The new one presents a higher initial stability, probably due to the high nitrogen and manganese contents; however, it also produces the higher final transformation due to the higher initial ferrite. A fine comparative analysis was done to correctly identify any phase; an accurate microanalysis in every generated phase was performed. All the steels tested are initially made on ferrite and austenite. After the ageing treatment, 8 hours at 1123 K, in the 2205 duplex steel a strong precipitation of sigma phase is observed, austenite and some of the original ferrite are also present; ferrite completely transforms in the 2507 duplex and austenite, sigma, secondary austenite and chromium nitride can be found; regarding the new duplex steel DBNi, austenite, ferrite, sigma, chi and chromium nitrides are detected.

    Los aceros dúplex austeno-ferríticos están constituidos por ferrita y austenita en proporciones variables del 30 % al 70 %. Su composición química condiciona los procesos de envejecimiento que sufren durante los tratamientos térmicos, cuando se generan fases que endurecen y fragilizan el material. Este trabajo estudia la evolución de un nuevo inoxidable dúplex con bajo contenido en níquel y alto en nitrógeno y manganeso a 1123 K (temperatura crítica de

  14. Influencia de la cantidad de O2 adicionado al CO2 en el gas de protección sobre la microestructura del metal depositado en uniones soldadas de bordes rectos en aceros de bajo contenido de carbono con el proceso GMAW Influence of O2 content, added to CO2 in the shielding gas, on the microstructure of deposited metal in butt welded joint with straight edges, in low carbon steels using GMAW process

    Directory of Open Access Journals (Sweden)

    Eduardo Díaz-Cedré

    2010-12-01

    Full Text Available La presencia de ferrita acicular (FA en la microestructura del cordón de soldadura, dentro de determinado rango de valores, eleva considerablemente la tenacidad de las uniones soldadas. Es por ello, que el presente trabajo trata sobre un estudio que relaciona la cantidad de ferrita acicular en el cordón en función del contenido de oxígeno presente en la mezcla activa CO2+O2, durante la realización de uniones soldadas de bordes rectos en aceros de bajo carbono con el proceso con electrodo fusible y protección gaseosa (GMAW en condiciones invariables de parámetros de proceso (corriente de soldadura, voltaje de arco, velocidad de soldadura, longitud libre y flujo de gas protector. Como resultado del trabajo se estableció la relación gráfica existente entre la ferrita acicular y el contenido de oxígeno en la mezcla.The presence of acicular ferrite (AF in the microstructure of weld bead, in a specified range of values, increase considerably the toughness of welded joints. The present paper, for that reason, study the relationship between the acicular ferrite quantity in the deposited metal and the oxygen present in the active gas mixture of CO2+O2, during the execution of butt welded joints with straight edges, in low carbon steels with consumable electrode and gas protection (GMAW in invariable conditions of process parameters (welding current, arc voltage, welding speed, electrode extension, and gas flow. The graphic relation between the acicular ferrite and the oxygen content was established, as result of the research work.

  15. Preparação e caracterização de nanocompósitos multifuncionais obtidos com nanopartículas ferroelétricas e paramagnéticas em filmes de borracha natural

    OpenAIRE

    Bellucci, Felipe Silva

    2013-01-01

    La presente investigación tuvo como objetivo desarrollar una metodología para la preparación de nanocompuestos funcionales y multifuncionales a partir de caucho natural vulcanizado combinado con distintas concentraciones de nanopartículas de cerámicas ferroeléctricas de niobato de potasio y estroncio KSr2Nb5O15 (KSN) y de una cerámica paramagnética con base níquel-zinc denominada ferrita Ni0,5Zn0,5Fe2O4 (NZF). Por otra parte se puso a punto, con satisfactorios resultados, el desarrollo de las...

  16. Medidas de selectividad y sensibilidad en un receptor de AM simplificado

    OpenAIRE

    Przylecki Siwek, Maciej

    2011-01-01

    Se describen las medidas de selectividad y sensibilidad de un receptor de AM simplificado que sólo dispone de una etapa detectora formada por antena de ferrita y un transistor BJT npn polarizado en zona no líneal actuando como un amplificador de clase B. La señal detectada se preamplifica y finalmente se lleva a un amplificador de audio de circuito integrado y al altavoz. Debido a la sencillez la selectividad es variable con la frecuencia de sintonía proporcionando a 392 KHz un...

  17. Soldadura de recargue con aceros inoxidables dúplex

    OpenAIRE

    Zappa, Sebastián; Martínez, Juan; Svoboda, Hernán Gabriel; Surian, Estela

    2016-01-01

    Los aceros inoxidables dúplex se caracterizan por poseer una estructura dual constituida por ferrita y austenita en iguales proporciones. Poseen una combinación de buenas propiedades mecánicas y resistencia a la corrosión, que dependen de la composición química y de la relación entre las fases mencionadas. Son ampliamente utilizados en las industrias de procesos químicos y, fundamentalmente, del petróleo y gas. La soldadura de recargue, es utilizada en las industrias de fabricación y reparaci...

  18. Soldadura TIG de los aceros inoxidables dúplex del tipo 22-05 (Uranus 45N y Avesta. Estudio de la microestructura y de las propiedades mecánicas

    Directory of Open Access Journals (Sweden)

    Gómez de Salazar, J. M.

    1998-05-01

    Full Text Available TIG welding of two different duplex stainless steels is carried out. Arc-discharge on base-material plates by means of the TIG technique without filler metal and varying the energetic conditions (E.N.A. has been performed, A comparative study concerning the microstructural evolution as well as mechanical properties is carried out, The relation between hardness profiles, the microstructural variations and the ferrita δ concentration is established. Further, the above mentioned properties are related to the E.N.A. for each welded joint.

    Se estudia la soldadura TIG de dos aceros inoxidables dúplex. Para ello, se ha descargado un arco sobre las chapas de material base mediante la técnica TIG, sin aportación de material y variando las E.N.A. Se realiza un estudio comparativo de la evolución microestructural, así como de las propiedades mecánicas. Se establece la relación entre los perfiles de dureza obtenidos y la variación microestructural y de la concentración de ferrita δ, así como estas propiedades con el E.N.A, de cada cordón.

  19. Preparação e caracterização da hexaferrita de bário dopada com niquel e cobalto

    Directory of Open Access Journals (Sweden)

    R. R. Corrêa

    2013-12-01

    Full Text Available O objetivo deste trabalho foi a obtenção de ferritas de bário tipo W com estequiometria BaCo2-xNi xFe16O27 por meio do método cerâmico tradicional, que é muito difundindo nas indústrias de processamento cerâmico por ser econômico e de relativa facilidade na obtenção de pós-cerâmicos. Materiais aditivados podem afetar as propriedades elétricas, magnéticas e a microestrutura das ferritas por diferentes mecanismos. Assim, temos como objetivo investigar o efeito da substituição dos elementos cobalto e níquel na microestrutura da hexaferrita tipo W com fórmula estequiométrica BaCo2-xNi xFe16O27, x = 0,0, 0,6, 1,0 e 2.

  20. Small Business Innovation Research (SBIR) Program. Program Solicitation 90.2 FY-1990

    Science.gov (United States)

    1990-07-02

    A90-255 Biogeneration of Obscurants A90-256 Urease -Linked Immunoassay Reagent Stability Studies A90-257 Advanced Technology Microphone for NBC...Multispectral Smoke Model A90.311 Atmospheric Boundary Layer Stability Estimators For Urban Areas ELECTRONICS ThCHOLOGY AND DEVICES LABORATORY A90-312...Wideband Army Radars A90-329 GPS Frequency Translator Integrated Circuits A90-330 Surface-Mounted Multi- Layer Chip Varistors A90-331 Over-the-Ground

  1. The destruction influence of pulse and surge currents on overvoltage protection

    International Nuclear Information System (INIS)

    Glasa, M.; Huettner, L.

    2012-01-01

    This article deals about the influences caused during the active operation process of the surge arrester against the pulse and surge currents. It also refers about a lightning, the characteristic of lightning and about the lightning (surge) currents caused its influence. One parts of the article is focused on a total elimination of surge current energy, and on an ineffective operation, which leads to partially or totally destruction of a protection element. There is a comparison with two basic types of surge arresters (spark gap and varistor based arresters), and theirs re-effectiveness on prescribed level. (Authors)

  2. XPS Analysis of Ni and Oxygen in Single-Sintered SrTiO3 Multifunction Ceramic

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    XPS analyses have been performed to investigate the chemical conditions of Ni and oxygen on grain surfaces in single-sintered SrTiO3 capacitor-varistor ceramic doped with Nb2O5 and NiO. It is ascertained that Ni is in form of Ni2+ ions, which substitute for Ti4+ ions on grain surfaces during the oxidizing annealing. Moreover, it is confirmed that three kinds of chemically adsorbed oxygen such as O2-, O- and O~ are formed on grain surfaces. It is proposed that these behaviors contribute greatly to the generation of multiple types of grain boundary acceptor states in the ceramic.

  3. THE EFFECT OF ISOVALENT SUBSTITUTIONS AND DOPANTS OF 3D-METALS ON THE PROPERTIES OF FERROELECTRICS- SEMICONDUCTORS

    Directory of Open Access Journals (Sweden)

    O.I.V'yunov

    2003-01-01

    Full Text Available Electrophysical properties and microstructure of PTCR ceramics of the system (Ba,Ca,Sr,YTiO3+y%Mn have been investigated. It has been shown that manganese ions increase the potential barrier at grain boundaries and form a high-resistance outer layer in (Ba,Ca,Sr,YTiO3 ceramics. The resistance of grains, outer layers and grain boundaries, the values of temperature coefficient of resistance as well as the varistor effect as a function of manganese content of PTCR materials have been investigated.

  4. Estudio de la región rica en Bi2O3 en el sistema binario ZnO-Bi2O3

    Directory of Open Access Journals (Sweden)

    Caballero, A. C.

    2004-08-01

    Full Text Available Ceramic materials based in the ZnO- Bi2O3 system have their principal application as varistors. The binary system ZnO-Bi2O3 is specially relevant to the formation of the microstructure responsable of the varistor behaviour. The study of the different equilibrium phases at high temperatures at the Bi2O3-rich region of the ZnO-Bi2O3 will allow a correct understanding of the microstructural development. Equilibrium phases have been analyzed by XRD, SEM and DTA. Different temperature treatments of samples formulated in the Bi2O3 rich region of the ZnO-Bi2O3 binary system have allowed to determine the phase 19Bi2O3•ZnO as the equilibrium one instead of the 24Bi2O3•ZnO phase.Los materiales cerámicos basados en el sistema binario ZnO-Bi2O3 tienen su principal aplicación en el campo de los varistores. El sistema binario ZnO-Bi2O3 resulta especialmente relevante para la formación de la microestructura funcional de varistores. La determinación de las diferentes fases en equilibrio a alta temperatura en la región rica en Bi2O3 en el sistema binario ZnO-Bi2O3 permitirá interpretar correctamente el desarrollo microestructural. El estudio de las fases en equilibrio se ha llevado a cabo mediante difracción de rayos X, microscopía electrónica de barrido (MEB y análisis térmico diferencial (ATD. Tratamientos a diferentes temperaturas, en la zona rica en Bi2O3 del sistema, han permitido determinar la presencia del compuesto 19Bi2O3•ZnO como fase estable en equilibrio, en lugar del compuesto 24Bi2O3•ZnO.

  5. Efeito do Tratamento Térmico de Solubilização e Estabilização Convencional e Alternativo na Microestrutura de uma Junta Soldada com Aço Inox 347

    Directory of Open Access Journals (Sweden)

    Renata Barbosa Gonçalves

    2015-03-01

    Full Text Available Este trabalho estuda a microestrutura formada na zona termicamente afetada (ZTA e na zona fundida (ZF de uma junta soldada pelo processo TIG automático no passe de raiz, processo plasma nos passes de enchimento e soldagem SAW para os passes de acabamento em junta de topo com chanfro “V” simples, usando o aço inoxidável austenítico AISI 347. Foram estudadas as condições: como soldada; após tratamento térmico convencional de solubilização a 1060 °C e estabilização a 900 °C; e após tratamento térmico alternativo, onde a peça foi solubilizada a 1060 °C e mantida no forno que foi resfriado até 900 °C para a estabilização. Os resultados mostram que, na condição como soldado houve crescimento de grão na ZTA e a ZF apresentou 13% de ferrita com diferentes morfologias, tendo sido observada a precipitação de carbetos de Cr e de Nb. Após o tratamento térmico convencional de solubilização e estabilização, foi observada uma diminuição significativa do teor de ferrita na ZTA e na ZF, tendo sido observados carbetos de Nb e Cr, distribuídos de forma mais dispersa e com tamanhos menores, que contribuem para minimizar a possibilidade de ocorrer o fenômeno da sensitização. Após tratamento térmico alternativo de solubilização e estabilização, a microestrutura da ZTA e ZF foi similar à obtida no tratamento convencional, sendo que o teor de ferrita δ na ZF foi ainda mais reduzido, de 4,5%. Foi concluído que o tratamento térmico alternativo de solubilização e estabilização foi tão eficaz quanto o tratamento térmico convencional para a adequação da microestrutura da junta soldada, com uma significativa vantagem do tratamento térmico proposto em reduzir o tempo e o custo desta operação.

  6. Overvoltage protection for magnetic system during disruption in tokamak

    International Nuclear Information System (INIS)

    Zhang, Ming; Li, Xiaolong; He, Yang; Zhang, Jun; Chen, Zhongyong; Yu, Kexun

    2015-01-01

    Highlights: • We investigate the way to limit the plasma disruption overvoltage by using the MOVs. • An overvoltage model of plasma disruption is introduced. • The overvoltage protection scheme has been verified by disruption experiments. • The overvoltage during plasma disruption can be limited to 330 V. - Abstract: During a plasma disruption the magnetic flux in the tokamak changes rapidly, which in most cases will cause high-voltage surges among the magnetic systems and may bring severe damage to the components if there is no overvoltage protection. This paper investigates the way to limit the plasma disruption overvoltage and absorb the energy with the use of metal oxide varistors (MOVs). An overvoltage model of plasma disruption is introduced which can be used for the simulation of plasma disruption and the analysis of the overvoltage. The effectiveness of the overvoltage protection system is validated with disruption experiments. It shows that by optimizing the varistors voltage, the overvoltage during plasma disruption can be limited to an ideal low value. Now the overvoltage protection system has been deployed in J-TEXT tokamak and serves well for daily experiments.

  7. Structural disorder and transport in ternary oxides with the pyrochlore structure. Final report; FINAL

    International Nuclear Information System (INIS)

    Tuller, Harry L.

    2001-01-01

    This research program has focused on the structure-electrical property relations in families of pyrochlore compounds which exhibit, on the one hand, controlled levels of structural disorder and on the other, controlled levels of ionic and electronic conductivities. Models have been developed to evaluate the often complex defect chemistry of these systems. Much progress has been made in extracting key thermodynamic and kinetic data. From a technological standpoint, novel solid electrolytes and compatible mixed conducting electrodes have been identified and the concept of the single phase monolithic fuel cell design has been demonstrated and patented. Related work on lanthanum gallate-based perovskites has shown even more promising results for use of such materials in the monolithic fuel cell structures. Recent work on the Bi(sub 3)Zn(sub 2)Sb(sub 3)O(sub 14) Pyrochlore, a phase found at grain boundaries in varistors, was also completed. This material was found to be a mixed ionic-electronic conductor with interesting implications for grain boundary equilibration kinetics in SnO-base varistor materials. Three of the most recent projects are summarized in this paper. The results of work on the perovskites are reported in recent publications

  8. Estudio comparativo de dos métodos de síntesis para la obtención de polvos cerámicos de ZnO - Pr2O3 - CoO

    Directory of Open Access Journals (Sweden)

    Rodríguez-Páez, J. E.

    2004-08-01

    Full Text Available Zinc oxide containing rare earth metal and Cobalt oxide are utilized as raw material to make varistors. Some of systems were found to exhibit non-ohmic current-voltaje characteristics and they are applicable not only for low voltaje devices but also for hight voltaje electric power stations. The microstructure of ZnO varistor can be considered as a vehicle thorugh which all of these properties ara manifested. Therefore, a discussion of the microstructure cannot be separated from a discussion of the properties. Fine particle dimensions and a narrow size distribution are often important aims when fabricating a ceramic material of a desired microstructure. Chemical methods give the ability to produce powders with an exceptionally small size in the nanometer range. In this paper we report the production of nanosized ZnO, doped with cobalt and Praseodymium oxides, using co-precipitation reaction and metallorganic polymeric method. Adequate description of synthesis methods and the characterization of ceramic powders obtained are show.Los polvos cerámicos de ZnO - Pr2O3 - CoO son utilizados como materia prima para la fabricación de varistores. Estos dispositivos presentan una característica corriente - voltaje altamente no lineal que permiten su uso como conmutadores de estado sólido con capacidad de manejar altas energías. La discusión de las propiedades de los varistores no se puede realizar de manera separada de una discusión sobre su microestructura ya que ésta se puede considerar como un medio a través de la cual aquellas se manifiestan. Con el fin de optimizar las propiedades de los varistores de ZnO es necesario establecer un adecuado control sobre la composición del sistema, la naturaleza de los dopantes, métodos de síntesis y condiciones de sinterización. Concretamente, en métodos de síntesis, se han realizado muchos esfuerzos para desarrollar procesos que permitan obtener partículas con tamaño y morfología determinada y que

  9. EFECTO DEL PRECALENTAMIENTO Y LA SEVERIDAD DE TEMPLE SOBRE LA RESISTENCIA AL DESGASTE ADHESIVO DEL ACERO AUSTENÍTICO AL MANGANESO

    Directory of Open Access Journals (Sweden)

    OSCAR FABIÁN HIGUERA COBOS

    2010-01-01

    Full Text Available En este trabajo de investigación se estudió el efecto del precalentamiento y la severidad de temple sobre la resistencia al desgaste adhesivo del acero austenítico al manganeso ASTM A 128 grado C. El material se sometió a ciclos térmicos de temple y revenido con y sin precalentamiento con el fin de evaluar su influencia sobre la resistencia al desgaste. Posteriormente el material fue sometido a prueba según norma ASTM G83 y se determinó que el acero Austenítico al manganeso, es un material que presenta una microestructura metaestable en condiciones estables y no debe ser sometido a tratamiento térmico de revenido a altas temperaturas debido que favorece la descomposición de esta a ferrita (fase blanda de los acero y por ende disminuye su resistencia al desgaste.

  10. Caracterización de las propiedades mecánicas y microestructurales de soldaduras empleadas en la recuperación de ejes

    Directory of Open Access Journals (Sweden)

    César Cerón Bolaños

    2006-01-01

    Full Text Available Se analizaron las propiedades mecánicas y las características microestructurales de los materiales de aporte y la zona afectada térmicamente (ZAT de tres procedimientos de soldadura de arco eléctrico, usados para la recuperación de ejes desgastados de molinos de caña de azúcar. En dos procedimientos se identificó que en la ZAT había ferrita en bordes de grano, mayor crecimiento de grano y la estructura Widmanstaetten, lo cual reduce la tenacidad del acero. Las soldaduras se compararon partiendo de sus propiedades mecánicas por medio de ensayos de tensión y de impacto Charpy.

  11. Estudio del efecto del tamaño en la estructura cristalina de nanopartículas de CoFe2O4

    OpenAIRE

    Menchaca Nal, Sandra; Londoño Calderon, Cesar Leandro; Pardo Saavedra, D. C.; Pampillo, L. G.; Socolovsky, Leandro Martin; Martinez Garcia, Ricardo

    2016-01-01

    Se estudió como afecta el tamaño de nanopartículas de ferrita de cobalto en el desorden cristalino por efecto de superficie. Las nanopartículas se obtuvieron por el método de coprecipitación de sales. Para controlar el tamaño realizaron diferentes tratamientos térmicos posteriores a la síntesis. La estructura cristalina y la morfología se evaluaron por medio de Difracción de rayos-X y Microscopía Electrónica de Transmisión de Alta Resolución. Los resultados obtenidos demuestran en forma cuant...

  12. TIG AISI-316 welds using an inert gas welding chamber and different filler metals: Changes in mechanical properties and microstructure

    Directory of Open Access Journals (Sweden)

    Sánchez, A.

    2010-12-01

    Full Text Available This report analyses the influence of the use of an inert gas welding chamber with a totally inert atmosphere on the microstructure and mechanical properties of austenitic AISI 316L stainless steel TIG welds, using AISI ER316L, AISI 308L and Inconel 625 as filler metals. When compared with the typical TIG process, the use of the inert gas chamber induced changes in the microstructure, mainly an increase in the presence of vermicular ferrite and ferrite stringers, what resulted in higher yield strengths and lower values of hardness. Its effect on other characteristics of the joins, such as tensile strength, depended on the filler metal. The best combination of mechanical characteristics was obtained when welding in the inert gas chamber using Inconel 625 as filler metal.

    En este estudio se analiza la influencia que el uso de una cámara de soldadura de gas inerte tiene sobre la microestructura y las propiedades mecánicas de las soldaduras TIG en el acero inoxidable austenítico AISI-316L cuando se emplean AISI ER316L, AISI 308L e Inconel 625 como materiales de aporte. Cuando se compara con el típico proceso de TIG, el uso de una cámara de gas inerte induce cambios en la microestructura, incrementando la presencia de ferrita vermicular y de laminillas de ferrita, resultando en un aumento del límite elástico y una pérdida de dureza. Su influencia sobre otras características de las soldaduras como la carga de rotura depende de la composición del material de aporte. La mejor combinación de propiedades mecánicas se obtuvo usando el Inconel 625 como material de aporte y soldando en la cámara de gas inerte.

  13. Influencia de la transferencia por arco sobre la microestructura de uniones soldadas usando arco pulsado//Influence of the transfer by arc on the microstructure of welded joint produced by pulsed arc

    Directory of Open Access Journals (Sweden)

    Sandra Patricia Romero-Nieto

    2012-12-01

    Full Text Available Este artículo estudia la influencia de la transferencia de arco pulsado en el proceso de soldadura por arco eléctrico con gas de protección (GMAW, Gas Metal Arc Welding, sobre la microestructura, utilizando dos composiciones de gas de protección y los modos de transferencia de arco pulsado y corto circuito. Se caracterizó la microestructura y las propiedades mecánicas y los resultados indican que se logra una mayor resistencia a la tensión y un perfil de dureza más homogéneo utilizando el modo de transferencia de arco pulsado, debido a que con esta existe una distribución más uniforme del tamaño de grano en lastres zonas de soldadura. La presencia de ferrita acicular fue una constante en todos los tratamientos evaluados, mientras la ferrita widmastatten se presentó con preferencia en la transferencia de arco pulsado.Palabras claves: transferencia en arco pulsado, proceso GMAW, mezclas de gases de protección._______________________________________________________________________________AbstractThis article studies the influence of pulsed arc transfer in the GMAW process on the microstructure, usingtwo shielding gas composition and the pulsed arc and short circuit transfer. The microstructure andmechanical properties was characterized and the results show that is achieved a greater tensile strengthand more homogeneous in the hardness profile using the pulsed arc transfer, because it creates a moreuniform size grain in the three areas of welding. The presence of a circular ferrite was constant in alltreatments tested, while widmastatten ferrite was presented preferably in the pulsed arc transfer.Key words: transfer in pulsed current, GMAW process, shielding gas mixtures

  14. Investigation of ceramic devices by analytical electron microscopy techniques

    International Nuclear Information System (INIS)

    Shiojiri, M.; Saijo, H.; Isshiki, T.; Kawasaki, M.; Yoshioka, T.; Sato, S.; Nomura, T.

    1999-01-01

    Ceramics are widely used as capacitors and varistors. Their electrical properties depend on the structure, which is deeply influenced not only by the composition of raw materials and additives but also by heating treatments in the production process. This paper reviews our investigations of SrTiO 3 ceramic devices, which have been performed using various microscopy techniques such as high-resolution transmission electron microscopy (HRTEM), cathodoluminescence scanning electron microscopy (CLSEM), field emission SEM (FE-SEM), energy dispersive X-ray spectroscopy (EDS), electron energy-loss spectroscopy (EELS) and high angle annular dark field (HAADF) imaging method in a FE-(scanning) transmission electron microscope(FE-(S)TEM). (author)

  15. Research on IGBT solid state switch

    International Nuclear Information System (INIS)

    Gan Kongyin; Tang Baoyin; Wang Xiaofeng; Wang Langping; Wang Songyan; Wu Hongchen

    2002-01-01

    The experiments on the IGBT solid state switch for induction accelerator was carried out with two series 1.2 kV, 75 A IGBT (GA75TS120U). The static and dynamic balancing modules were carried out with metal oxide varistors, capacities and diodes in order to suppress the over-voltage during IGBT on and off. Experimental results show that IGBT solid state switch works very stable under the different conditions. It can output peak voltage 1.8 kV, rise time 300 ns, fall time 1.64 μs waveforms on the loads. The simulation data using OrCAD are in accord with experimental results except the rise time

  16. Research on IGBT solid state switch

    CERN Document Server

    Gan Kong Yin; Wang Xiao Feng; Wang Lang Ping; Wang Song Yan; Chu, P K; Wu Hong Chen

    2002-01-01

    The experiments on the IGBT solid state switch for induction accelerator was carried out with two series 1.2 kV, 75 A IGBT (GA75TS120U). The static and dynamic balancing modules were carried out with metal oxide varistors, capacities and diodes in order to suppress the over-voltage during IGBT on and off. Experimental results show that IGBT solid state switch works very stable under the different conditions. It can output peak voltage 1.8 kV, rise time 300 ns, fall time 1.64 mu s waveforms on the loads. The simulation data using OrCAD are in accord with experimental results except the rise time

  17. Morphological and structural characterization of the Zn{sub 0,9}Mn{sub 0,1}O powder synthesized by combustion reaction and Pechini; Caracterizacao estrutural e morfologica de pos de Zn{sub 0,9}Mn{sub 0,1}O sintetizados por reacao de combustao e metodo Pechini

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, M A; Torquato, R; Simoes, A N; Costa, A C.F.M.; Gama, L [Universidade Federal de Campina Grande (DEMA/UFCG), PB (Brazil). Dept. de Engenharia dos Materiais; Kiminami, R H.G.A. [Universidade Federal de Sao Carlos (DEMA/UFSCar), SP (Brazil). Dept. de Engenharia de Materiais

    2009-07-01

    Zinc oxide, due to the piezoelectric and electro-optical characteristics, is used in application such as, chemical sensor, varistor, transparent conductive thin film and DMS. The aim of this work is to evaluate and compare structural and morphological characteristics of nanometric powders of Zn{sub 0,9}Mn{sub 0,1}O prepared by chemical synthesis of combustion reaction and Pechini method. The powders were characterized by XRD, SEM and BET. The XRD data shown to both studied method the presence of ZnO phase with hexagonal structure and without second phase. The powder prepared by combustion reaction presented 9% of reduction in crystallinity and 42% of increase in surface area in comparison with the powder prepared by Pechini method. The morphological analysis of the powder showed that both method produce powders with soft agglomerates constituted by nano size particles. (author)

  18. Morphological and structural characterization of the Zn0,9Mn0,1O powder synthesized by combustion reaction and Pechini

    International Nuclear Information System (INIS)

    Ribeiro, M.A.; Torquato, R.; Simoes, A.N.; Costa, A.C.F.M.; Gama, L.; Kiminami, R.H.G.A.

    2009-01-01

    Zinc oxide, due to the piezoelectric and electro-optical characteristics, is used in application such as, chemical sensor, varistor, transparent conductive thin film and DMS. The aim of this work is to evaluate and compare structural and morphological characteristics of nanometric powders of Zn 0,9 Mn 0,1 O prepared by chemical synthesis of combustion reaction and Pechini method. The powders were characterized by XRD, SEM and BET. The XRD data shown to both studied method the presence of ZnO phase with hexagonal structure and without second phase. The powder prepared by combustion reaction presented 9% of reduction in crystallinity and 42% of increase in surface area in comparison with the powder prepared by Pechini method. The morphological analysis of the powder showed that both method produce powders with soft agglomerates constituted by nano size particles. (author)

  19. Fault Location Based on Synchronized Measurements: A Comprehensive Survey

    Science.gov (United States)

    Al-Mohammed, A. H.; Abido, M. A.

    2014-01-01

    This paper presents a comprehensive survey on transmission and distribution fault location algorithms that utilize synchronized measurements. Algorithms based on two-end synchronized measurements and fault location algorithms on three-terminal and multiterminal lines are reviewed. Series capacitors equipped with metal oxide varistors (MOVs), when set on a transmission line, create certain problems for line fault locators and, therefore, fault location on series-compensated lines is discussed. The paper reports the work carried out on adaptive fault location algorithms aiming at achieving better fault location accuracy. Work associated with fault location on power system networks, although limited, is also summarized. Additionally, the nonstandard high-frequency-related fault location techniques based on wavelet transform are discussed. Finally, the paper highlights the area for future research. PMID:24701191

  20. Effect of Bi2O3 and Nb2O5 addition on the electrical properties of grain boundaries of SnO2 ceramics

    International Nuclear Information System (INIS)

    Gouvea, D.; Kobori, M.H.; Las, W.C.; Santilli, C.V.; Varela, J.A.

    1990-01-01

    Grain boundary phenomena in SnO 2 ceramics are widely explored in gas sensor fabrication. On the other hand, the high electronic mobility in the conduction band and the energy gap width of 3,5 eV are characteristics which can lead to the formation of an intergranular potential barrier similar to those encountered in ceramic varistors. In this work, the Nb 2 O 5 and Bi 2 O 3 influence on the electrical transport mechanisms through grain boundaries in SnO 2 ceramics was investigated. The samples were characterized by measuring the electrical conductivity as a function of electric field for temperatures from 25 0 C to 200 0 C. The results were analyzed by models which are based on phenomena that occur at interfaces between semiconducting materials. (author) [pt

  1. Modelling of fluid flow in tape casting of thin ceramics: Analytical approaches and numerical investigations

    DEFF Research Database (Denmark)

    Jabbaribehnam, Mirmasoud; Hattel, Jesper Henri

    2016-01-01

    Tape casting has been used to produce thin layers of ceramics that can be used as single layers or can be stacked and laminated into multilayered structures. Many startup products such as multilayered inductors, multilayered varistors, piezoelectrics, ceramic fuel cells and lithium ion battery...... components are dependent upon tape casting technology. One of the growing sciences in the processing of ceramics by tape casting is the use of fluid flow analysis to control and enhance the final tapes. The fluid dynamics analysis of the ceramic slurries during tape casting is an efficient mean to elucidate...... the physical parameters crucial to the process. A review of the development of the tape casting process with particular focus on modelling the material flow is presented and in this context the current status is examined and future potential discussed....

  2. Synthesising highly reactive tin oxide using Tin(II2- ethylhexanoate polynucleation as precursor

    Directory of Open Access Journals (Sweden)

    Alejandra Montenegro Hernández

    2009-01-01

    Full Text Available Tin oxide is a widely used compound in technological applications, particularity as a catalyst, gas sensor and in making varistors, transparent conductors, electrocatalytic electrodes and photovoltaic cells. An ethylhexanoate tin salt, a carboxylic acid and poly-esterification were used for synthesising highly reactive tin oxide in the present study. Synthesis was controlled by Fourier transform infrared (FTIR spectroscopy and recording changes in viscosity. The tin oxide characteristics so obtained were determined using FTIR spectroscopy, X-ray diffraction (XRD and scanning electron microscopy (SEM. The SnO2 dust synthesised and heat-treated at 550°C yielded high density aggregates, having greater than 50 μm particle size. This result demonstrates the high reactivity of the ceramic powders synthesised here.

  3. Current status and future aspects of R&D activities on electro- ceramic components in Japanese industry

    Science.gov (United States)

    Takagi, Hiroshi

    2011-05-01

    The oldest pottery in Japan was made 16,500 years ago in Jomon period. On the background of a long history of Japanese ceramics, Murata and other Japanese manufacturers have been developing electro-ceramic materials and manufacturing many kinds of electronic components using them. In 1937, TDK manufactured ferrite cores first in the world. Then, Japanese electro-ceramic industry has led the world on electro-ceramic materials and components until now, especially in the fields of BaTiO3, PZT, PTC thermistor, ZnO varistor and insulating ceramics. From the analysis of the papers reported lately, R&D activities of Japanese manufacturers are understood to cover not only improving properties of electro-ceramics, but also appropriate technologies and basic technologies.

  4. Solid state compatibility in the ZnO-rich region of ZnO-Bi2O3-Sb2O3 and ZnO-Bi2O3-Sb2O5 systems

    Directory of Open Access Journals (Sweden)

    Jardiel, T.

    2010-04-01

    Full Text Available The obtaining of ZnO-Bi2O3-Sb2O3 (ZBS based varistor thick films with high non-linear properties is constrained by the bismuth loss by vaporization that takes place during the sintering step of these ceramics, a process which is yet more critical in the thick film geometry due to its inherent high are/volume ratio. This volatilization can be controlled to a certain extent by modifying the proportions of the Bi and/or Sb precursors. Obviously this requires a clear knowledge of the different solid state compatibilities in the mentioned ZBS system. In this sense a detailed study of the thermal evolution of the ZnO-Bi2O3-Sb2O3 and ZnO-Bi2O3-Sb2O5 systems in the ZnO-rich region of interest for varistors, is presented in this contribution. A different behaviour is observed when using Sb2O3 or Sb2O5 as starting precursor, which should be attributed to the oxidation process experimented by Sb2O3 compound during the heating. On the other hand the use of high amounts of Bi in the starting formulation leads to the formation of a liquid phase at lower temperatures, which would allow the use of lower sintering temperatures.La obtención de varistors en lámina gruesa basados en ZnO-Bi2O3-Sb2O3 (ZBS y con propiedades altamente no-lineales está limitada por la perdida de bismuto por volatilización durante la sinterización de estos cerámicos, un proceso que es todavía más crítico en la geometría de lámina gruesa debido a su elevada relación área/volumen inherente. Dicha volatilización puede ser no obstante controlada hasta cierta extensión modificando las proporciones de los precursores de Bi y/o Sb. Obviamente ello conlleva un amplio conocimiento de las diferentes compatibilidades en estado sólido en el mencionado sistema ZBS. En este sentido, en la presente contribución se presenta un estudio detallado de la evolución térmica de los sistemas ZnO-Bi2O3-Sb2O3 y ZnO-Bi2O3-Sb2O5 en la región rica en ZnO de interés para varistores. Como

  5. A model of electric breakdown in polycrystalline semiconductors with highly nonlinear I - V characteristics

    International Nuclear Information System (INIS)

    Yildirim, E.H.; Tanatar, B.; Canessa, E.

    1993-07-01

    A deterministic algorithm to study the nonlinear current-voltage characteristics of polycrystalline semiconductors, such as ZnO-based metal oxide varistors, under dc bias and at room temperature is developed based on the electrical properties of individual grain boundaries. Assuming a thermionic emission type mechanism between individual grains and a nonuniform distribution of barrier heights at grain boundaries, the set of nonlinear Kirchhoff equations that determines the macroscopic current across the specimen and the nonlinearity coefficient α is solved numerically. The applied voltage dependence of the barrier height is found to be crucial to obtain α values reaching ∼50, indicating high nonlinearity as required by potential commercial applications. (author). 20 refs, 3 figs

  6. Design and measurement of a piezoresistive triaxial accelerometer based on MEMS technology

    International Nuclear Information System (INIS)

    Du Chunhui; He Changde; Yu Jiaqi; Ge Xiaoyang; Zhang Wendong; Zhang Yongping

    2012-01-01

    With the springing up of the MEMS industry, research on accelerometers is focused on miniaturization, integration, high reliability, and high resolution, and shares extensive application prospects in military and civil fields. Comparing with the traditional single cantilever beam structure or 'cantilever-mass' structure, the proposed structure of '8-beams/mass' with its varistor completely symmetric distribution in micro-silicon piezoresistive triaxial accelerometer in this paper has a higher axial sensitivity and smaller cross-axis sensitivity. Adopting ANSYS, the process of structural analysis and the manufacturing flow of sensing unit are showed. In dynamic testing conditions, it can be concluded that the axial sensitivity of x, y, and z are S x = 48 μV/g, S y = 54 μV/g and S z = 217 μV/g respectively, and the nonlinearities are 0.4%, 0.6% and 0.4%.

  7. Fault Location Based on Synchronized Measurements: A Comprehensive Survey

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    A. H. Al-Mohammed

    2014-01-01

    Full Text Available This paper presents a comprehensive survey on transmission and distribution fault location algorithms that utilize synchronized measurements. Algorithms based on two-end synchronized measurements and fault location algorithms on three-terminal and multiterminal lines are reviewed. Series capacitors equipped with metal oxide varistors (MOVs, when set on a transmission line, create certain problems for line fault locators and, therefore, fault location on series-compensated lines is discussed. The paper reports the work carried out on adaptive fault location algorithms aiming at achieving better fault location accuracy. Work associated with fault location on power system networks, although limited, is also summarized. Additionally, the nonstandard high-frequency-related fault location techniques based on wavelet transform are discussed. Finally, the paper highlights the area for future research.

  8. Thermodynamic study of the rich-Bi2O3 region of the Bi2O3-ZnO system

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    de la Rubia, M. A.

    2006-06-01

    Full Text Available Precise knowledge of the Bi2O3-ZnO system is fundamental to control the functional microstructure of ZnO-based varistors. Also the potential applications of materials based on ZnO and Bi2O3 as dielectric materials in the high frequency range have renewed the interest in this binary system. The aim of the present work is to carry out a thermodynamic analysis of the Bi2O3-ZnO phase diagram, taking into account the existing experimental information. Thermodynamic calculation has been performed according CALPHAD methodology (CALculation of PHAse Diagrams, using the software Thermo-Calc.El conocimiento preciso del sistema Bi2O3-ZnO es una herramienta básica para conseguir el control de la microestructura de los varistores basados en ZnO. Recientemente otros materiales basados en óxidos de cinc y bismuto han mostrado un gran potencial para su uso en aplicaciones como dieléctricos a frecuencias altas, renovando el interés por dicho sistema binario. El objetivo del presente trabajo es realizar una evaluación termodinámica del diagrama de fases consistente para el sistema Bi2O3-ZnO teniendo en cuenta la información experimental existente del mismo. La evaluación termodinámica del sistema se ha llevado a cabo mediante la metodología CALPHAD (CALculation of PHAse Diagrams, empleando el software Thermo- Calc.

  9. Development of an electro-thermal model for ZnO surge arrester under contamination; Desarrollo de un modelo electro-termico para apartarrayos de ZnO bajo contaminacion

    Energy Technology Data Exchange (ETDEWEB)

    Guardado Zavala, J.L.; Moreno Barraza, M.; Zazueta Pena, H.; Venegas Rebollar, V.; Melgoza Vazquez, E. [Instituto Tecnologico de Morelia, Morelia, Michoacan (Mexico)]. E-mail: lguarda@prodigy.net.mx; hzazuetapea@yahoo.com; vvenegas@yahoo.com; emelgoza@iimorelia.edu.mx

    2010-01-15

    An electro-thermal model for a Zinc Oxide (ZnO) surge arrester under contamination test is presented. The model is based in three sub-models: electrical, thermal and contamination, which interact in order to obtain the surge arrester performance under contamination tests. The electrical model is obtained from measurements and is based on a capacitance and a non-linear resistor. The thermal model takes into account the heat generated and dissipated by the column of varistors and its surroundings. The contamination is represented by dynamic impedance obtained from measurements in the arrester column during contamination tests. The full model is validated by calculating the temperature increase during contamination tests carried out in a two units ZnO surge arrester, class 190 kV. Finally, the results of the effect of several design and construction parameters in the voltage and temperature distribution in the arrester column during contamination tests are presented. [Spanish] Se presenta el modelo electro-termico para un apartarrayos de Oxido de Zinc (ZnO) durante pruebas de contaminacion. El modelo esta compuesto de tres sub-modelos: electrico, termico y de contaminacion, los cuales interactuan armonicamente para obtener el comportamiento del apartarrayos durante pruebas de contaminacion. El modelo electrico se obtiene de mediciones y esta compuesto de una capacitancia y una resistencia no-lineal. El modelo termico considera el calor generado y disipado en la columna de varistores y su entorno. La contaminacion se representa como una impedancia dinamica, cuyos valores se obtienen de mediciones en la columna del apartarrayos durante pruebas de contaminacion. El modelo se valida determinando el incremento de temperatura durante pruebas de contaminacion en un apartarrayos de ZnO de dos unidades clase 1990 kV. Finalmente, se presentan los resultados del impacto de diversos parametros de diseno y construccion en la distribucion de voltaje y temperatura en el apartarrayos

  10. Soldagem unilateral com suporte cerâmico de cordierita One-sided welding with cordierite ceramic backing

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    Luciana Lezira Pereira de Almeida

    2010-06-01

    Full Text Available Este trabalho apresenta a avaliação de juntas soldadas com suporte cerâmico de cordierita produzido em laboratorio. Foi utilizada a técnica de soldagem unilateral em chapas de aço A-36 com espessuras de 6,4 e 15,8 mm pelo processo MIG-MAG. Com a chapa de 6,4 mm foi avalliado apenas o passe de raiz sobre o suporte cerâmico. Com a chapa de 15,8 mm foi produzida uma junta soldada em passes múltiplos. Após soldagem as juntas soldadas foram submetidas a ensaios de inspeção visual, liquido penetrante, macrografia, microdureza Vickers, microscopia ótica, ensaios de dobramento e de tração e análise química por EDS. Os resultados mostram que o passe de raiz, realizado sobre o suporte cerâmico, apresentou bom acabamento, isento de descontinuidades, com penetração adequada nas laterais do chanfro e reforço de solda apropriado. Em relação à junta soldada, a microestrutura da zona fundida (ZF obteve predominância de ferrita primária, em suas formas de ferrita de contorno de grão e poligonal, e ferrita com segunda fase alinhada. A microdureza Vickers obteve valores médios abaixo de 180 HV tanto na zona termicamente afetada (ZTA como na ZF. Os ensaios de dobramento não apresentaram descontinuidades maiores que 3 mm e nos ensaios de tração a ruptura ocorreu no metal base, indicando que o procedimento de soldagem foi adequado. A composição das inclusões tanto do passe de raiz como do ultimo passe de solda possuem os mesmos constituintes, apesar de proporções diferentes, indicando que não houve contaminação do material do suporte cerâmico no cordão de solda.This work presents the evaluation of welded joints using ceramic backing made in the laboratory. The one-sided welding technique was used to weld A-36 steel plate with 6,4 and 15,8 mm thick by the GMAW process. With the 6,4 mm steel plate, only the root bead welded over the ceramic backing was evaluated. With the 15,8 mm steel plate, a multipass welded joint was made

  11. Soldagem unilateral com suporte cerâmico de cordierita One-sided welding with cordierite ceramic backing

    Directory of Open Access Journals (Sweden)

    Luciana Lezira Pereira de Almeida

    2010-03-01

    Full Text Available Este trabalho apresenta a avaliação de juntas soldadas com suporte cerâmico de cordierita produzido em laboratorio. Foi utilizada a técnica de soldagem unilateral em chapas de aço A-36 com espessuras de 6,4 e 15,8 mm pelo processo MIG-MAG. Com a chapa de 6,4 mm foi avalliado apenas o passe de raiz sobre o suporte cerâmico. Com a chapa de 15,8 mm foi produzida uma junta soldada em passes múltiplos. Após soldagem as juntas soldadas foram submetidas a ensaios de inspeção visual, liquido penetrante, macrografia, microdureza Vickers, microscopia ótica, ensaios de dobramento e de tração e análise química por EDS. Os resultados mostram que o passe de raiz, realizado sobre o suporte cerâmico, apresentou bom acabamento, isento de descontinuidades, com penetração adequada nas laterais do chanfro e reforço de solda apropriado. Em relação à junta soldada, a microestrutura da zona fundida (ZF obteve predominância de ferrita primária, em suas formas de ferrita de contorno de grão e poligonal, e ferrita com segunda fase alinhada. A microdureza Vickers obteve valores médios abaixo de 180 HV tanto na zona termicamente afetada (ZTA como na ZF. Os ensaios de dobramento não apresentaram descontinuidades maiores que 3 mm e nos ensaios de tração a ruptura ocorreu no metal base, indicando que o procedimento de soldagem foi adequado. A composição das inclusões tanto do passe de raiz como do ultimo passe de solda possuem os mesmos constituintes, apesar de proporções diferentes, indicando que não houve contaminação do material do suporte cerâmico no cordão de solda.This work presents the evaluation of welded joints using ceramic backing made in the laboratory. The one-sided welding technique was used to weld A-36 steel plate with 6,4 and 15,8 mm thick by the GMAW process. With the 6,4 mm steel plate, only the root bead welded over the ceramic backing was evaluated. With the 15,8 mm steel plate, a multipass welded joint was made

  12. Efeito da temperatura interpasse na microestrutura, tenacidade ao impacto e propagação de trinca por fadiga de uniões soldadas por GTAW do aço ASTM A743-CA6NM Interpass temperature influence on the microstructure, impact toughness and fatigue crack propagation in ASTM A743-CA6NM GTAW welded joints

    Directory of Open Access Journals (Sweden)

    Ruimar Rubens de Gouveia

    2013-06-01

    Full Text Available Atualmente os aços inoxidáveis martensíticos tem sido utilizados para a fabricação de turbinas hidráulicas, devido principalmente a sua elevada tenacidade. Entretanto, estes aços apresentam algumas restrições com relação à regiões recuperadas por soldagem, principalmente em razão da formação de martensita não revenida, a qual gera redução na tenacidade. Considerando as aplicações de reparo de turbinas hidráulicas, há grande interesse em desenvolver procedimentos de soldagem que elevem a tenacidade ao impacto e evitem os tratamentos térmicos pós-soldagem (TTPS. O presente trabalho busca analisar a influência da temperatura de interpasse na microestrutura, tenacidade ao impacto e propagação de trincas por fadiga nas uniões soldadas multipasse do aço inoxidável martensitico CA6NM usando AWS410NiMo como metal de adição, e processo TIG (tungsten inert gas. Observou-se a influência da temperatura de interpasse na formação de ferrita d, com formação intergranular no campo bifásico δ+γ, na amostra com temperatura interpasse de 80ºC, enquanto que na amostra soldada a 150ºC a formação de ferrita d ocorreu principalmente no campo monofásico. A alteração na formação da ferrita d, com a menor temperatura, promoveu um aumento na tenacidade ao impacto e uma diminuição na velocidade de propagação de trinca, quando comparada com a amostra soldada com maior temperatura de soldagem. Os resultados obtidos indicam que o processo TIG apresenta-se como uma excelente alternativa para o reparo do aço CA6NM, observando-se também uma influência significativa da temperatura de interpasse.Martensitic stainless steels have been used for hydraulic turbines manufacturing, because its high toughness. However, these steels have some restrictions regarding regions recovered by welding, mainly by non-tempered martensite formation, promoting toughness reduction. Concerning hydraulic turbine repairs, there is a great interest

  13. Estructura y textura de un meteorito metálico de tipo octaedrita (Gibeon

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    Gil Sevillano, J.

    2000-06-01

    Full Text Available A sample from the meteoritic iron Gibeon (fine octahedrite has been studied combining optical and scanning electron microscopy, crystallographic microtexture by EBSP (Electron Back Scattered Patterns and macrotexture by X-ray diffraction. The sample (approx. 24x23x3 mm, 14.3 g shows the classical Widmastätten structure of intersecting ferrite (kamacite plates grown along {111}γ octahedric previous austenite (taenite planes. Residual layers of austenite are also seen between the ferrite plates as well as larger domains of more complex structures of bainitic type (plessite produced by the last fraction of austenite transformed during extra-terrestrial cooling. The sample structure shows few signs of impact modifications (Neumann bands, etc.. Kamacite plates are divided in weakly misoriented (< 2º subgranular domains. The measurement of individual orientations by EBSP or the macroscopic texture measurement show a single austenite orientation (although with a non-negligible dispersion around the average orientation and a limited number of ferrite orientations compatible with the variants of the Kurdjumov-Sachs orientation relationship.

    Se ha estudiado un fragmento del hierro meteorítico Gibeon (Namibia, 1847, con estructura de octaedrita fina, combinando técnicas de microscopía óptica, microscopía electrónica de barrido, análisis EDX, medida de orientaciones cristalográficas mediante EBSP (Electron Back Scattered Patterns y difracción de rayos X. La muestra (aprox. 24x23x3 mm, 14.3 g presenta la clásica estructura de Widmanstätten, producto de la intersección de placas lenticulares de ferrita (kamacita, orientadas según planos octaédricos, con la sección metalográfica de la muestra. Se observan también una fracción residual de austenita (taenita retenida entre las placas ferríticas y estructuras más complejas (plesita, producto de la descomposición extraterrestre de la última fracción de austenita. La muestra

  14. Influência da energia de soldagem na microestrutura e na microdureza de revestimentos de aço inoxidável duplex Influence of the heat input on the microstructure and microhardness of weld overlay of duplex stainless steel

    Directory of Open Access Journals (Sweden)

    Everton Barbosa Nunes

    2012-06-01

    Full Text Available Aços inoxidáveis duplex (AID são caracterizados por apresentar interessante boas propriedades mecânicas e resistência à corrosão, possuindo um vasto campo de aplicação na indústria química e petroquímica. Geralmente, os reparos dos equipamentos ou estruturas são realizados por soldagem, sendo importante a seleção de parâmetros. É de suma importância a obtenção do teor adequado de ferrita no metal de solda, sendo que a variação da energia de soldagem pode influenciar de forma direta no percentual de ferrita. Logo, o objetivo deste trabalho é avaliar a influência da variação da energia de soldagem na microestrutura e na microdureza do metal de solda do AID. Foram realizadas soldagens de revestimento com sobreposição de duas camadas sobre o aço estrutural ASTM A516 Gr.60, utilizando eletrodo revestido AWS E2209-17. Três níveis de energia (15, 20 e 24 kJ/cm foram empregados, variando-se a corrente e a velocidade de soldagem. Foi verificado que para os níveis de energia empregados não houve diferença significativa no percentual de ferrita, porém o primeiro cordão depositado apresentou maior teor de austenita em relação aos demais cordões. De forma geral, foi verificado que o primeiro cordão depositado obteve níveis maiores de microdureza. Todas as condições apresentaram microdurezas abaixo do valor crítico.Duplex stainless steels (DSS are characterized by the presentation of an interesting combination of good mechanical properties and corrosion resistance, having a wide application in chemical and petrochemical industry. Generally, the manufacture and repair of any industrial equipment involve welding operations, even though it is very important to evaluate the influence of welding parameters. It is very important to obtain appropriate ferrite content in the weld metal, so that the variation of heat input can influence on the ferrite content directly. Therefore, the aim this work is to evaluate the

  15. Effect of microstructure on the impact toughness of high strength steels

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    Gutiérrez, Isabel

    2014-12-01

    Full Text Available One of the major challenges in the development of new steel grades is to get increasingly high strength combined with a low ductile brittle transition temperature and a high upper shelf energy. This requires the appropriate microstructural design. Toughness in steels is controlled by different microstructural constituents. Some of them, like inclusions, are intrinsic while others happening at different microstructural scales relate to processing conditions. A series of empirical equations express the transition temperature as a sum of contributions from substitutional solutes, free nitrogen, carbides, pearlite, grain size and eventually precipitation strengthening. Aimed at developing a methodology that could be applied to high strength steels, microstructures with a selected degree of complexity were produced at laboratory in a Nb-microalloyed steel. As a result a model has been developed that consistently predicts the Charpy curves for ferrite-pearlite, bainitic and quenched and tempered microstructures using as input data microstructural parameters. This model becomes a good tool for microstructural design.El desarrollo de nuevos grados de acero se tropieza con frecuencia con la necesidad de incrementar la resistencia mecánica al mismo tiempo que se reduce la temperatura de transición dúctil-frágil y se eleva la energía del palier dúctil. Hacer frente a este reto requiere un diseño microestructural. La tenacidad en aceros está controlada por diferentes constituyentes microestructurales. Algunos de ellos, como las inclusiones son intrínsecos, pero otros que se manifiestan a diferentes escalas microestructurales dependen de las condiciones de proceso. Existen algunas ecuaciones empíricas que permiten calcular para ferrita-perlita en aceros de bajo carbono la temperatura de transición como suma de contribuciones de elementos en solución sólida, nitrógeno libre, carburos, fracción de perlita, tamaño de grano y, eventualmente

  16. Efecto de la serpentina en la formación de fases mineralógicas y su relación con la resistencia mecánica en sinterizados de mineral de hierro

    Directory of Open Access Journals (Sweden)

    Bedolla, E.

    1995-12-01

    Full Text Available The influence of microstructures formed by serpentine addition on mechanical strength is investigated. It was found that the microstructure formed depends mainly on firing temperature, basicity and serpentine percent. The mineralogical phases present were quantified by the point-count method. The addition of serpentine on acid briquettes (CaO/Si O2 = 0.3, mainly on those fired at 1,275, 1,300 and 1,325 °C, leads to the formation of magnesio-ferrite that diminishes the mechanical strength of fired briquettes, and at the temperature of 1,250 °C the mechanical strength decreases because of the presence of glassy slags. On the other hand, the addition of serpentine on basic briquettes (CaO/Si O2 = 1.2 leads to the formation of olivines and ferrites that improve the mechanical strength of fired briquettes.

    Se estudia la influencia de las microestructuras formadas sobre la resistencia mecánica de mineral de hierro aglomerado con serpentina. Se deduce que la microestructura formada depende de la temperatura de sinterización, de la basicidad y del valor porcentual de serpentina, principalmente. Las fases mineralógicas presentes se cuantificaron utilizando la técnica de conteo por puntos. En briquetas acidas (CaO/SiO2 = 0,3 sinterizadas a 1.275, 1.300 y 1.325 °C, se encontró que la serpentina induce la formación de magnesio-ferritas que traen, como consecuencia, una disminución de la resistencia mecánica, mientras que, a la temperatura de sinterización de 1.250 °C, la aparición de escorias vítreas es la causa principal de la disminución de resistencia. En el caso de briquetas básicas (CaO/SiO2 = 1,2, la adición de serpentina produce la formación de olivinas y calcio-ferritas que originan un aumento de la resistencia mecánica de los sinterizados.

  17. Avaliação metalúrgica da soldagem de revestimento inox austenítico sobre aço SAE 4130

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    Márcio de Souza Elias

    2014-12-01

    Full Text Available O objetivo deste trabalho foi realizar uma avaliação metalúrgica da soldagem de revestimento inox austenítico sobre a área de selagem de tubos de Riser fabricados em aço SAE 4130. O estudo foi dividido em duas etapas. A primeira etapa teve como objetivo a determinação da taxa de diluição e taxa de deposição para os níveis máximo e mínimo de energia de soldagem conforme procedimentos de soldagem (EPS com os processos TIG e ER. A seguir, foi feita análise e estudo com o diagrama de Schaeffler para identificar os consumíveis de solda mais adequados, conforme critérios de qualidade estabelecidos. Este estudo identificou o metal de adição 312 para a primeira camada, o 309 e 308 para a segunda. Todos usando o nível máximo de energia de soldagem e o processo de soldagem ER, com benefícios à produtividade. A segunda etapa teve como objetivo a validação dos resultados empíricos encontrados na 1ª etapa, com a execução de soldas de revestimento com duas camadas cada, e a caracterização metalúrgica das juntas soldadas por ensaios mecânicos e análise microestrutural por MO e MEV. Os resultados dos ensaios mecânicos e da microestrutura foram considerados satisfatórios, atendendo os critérios de qualidade adotados. Foi observada uma microestrutura austeno-ferritica com teor de ferrita delta entre 10 a 15 % nas duas camadas do revestimento. O eletrodo 312 assumiu posição de destaque na aplicação da 1ª camada da solda de revestimento sobre o aço SAE 4130, em função do seu maior teor de ferrita delta e cromo, evitando a formação de trincas a quente. Para a segunda camada, tanto o 309 como o 308 podem ser usados. Todas as soldas foram feitas com elevada energia de soldagem, garantindo o aumento da produtividade, sem alteração significativa nas características físicas e mecânicas.

  18. Reciclado de las aguas de decapado

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    López, F. A.

    1998-05-01

    Full Text Available Pickling liquors from steel industry, listed as hazardous wastes in most industrializated countries, have been treated by means of several procedures in order to recover the iron and other metals and to obtain an environmental friendly effluent. Depending on the treatment employed, different valuable ferrous products have been obtained. Ammoniojarosite and zinc ferrite were precipitated from the previously oxidised ferrous solutions.

    En la mayoría de los países industrializados, se incluyen las aguas de decapado, tanto las procedentes de los aceros al carbono como de aceros inoxidables, dentro de las listas de residuos tóxicos y peligrosos. Se presentan en este trabajo los resultados obtenidos en las investigaciones realizadas en los últimos años en los que se ha estudiado el tratamiento y recuperación de aguas de decapado de aceros comunes e inoxidables. Su tratamiento se ha enfocado hacia la consecución de dos objetivos: la recuperación del contenido total de metales y la obtención de un efluente de menor impacto ambiental. Se presentan los procedimientos estudiados para la obtención de compuestos de hierro, amoniojarosita y ferritas de zinc, con cierto valor añadido.

  19. Efecto de la desestabilización de la cementita sobre el desarrollo de altos niveles de resistencia mecánica en aceros perlíticos

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    Mykhaylo Romanyuk

    2016-01-01

    Full Text Available Se estudió la deformación en aceros de alto contenido de carbono trefilados en frío, sobre el comportamiento mecánico y de fractura. La deformación promueve fenómenos de disolución de la cementita en la perlita, alcanzando alta resistencia y ductilidad, lo que permite aplicarlos en usos críticos como cables de grúas. Para estudiar el comportamiento mecánico y a la fractura, se estudian muestras de dos alambres sometidas a torsión hasta rotura. Estos presentan distinto comportamiento: uno sufrió fractura plana (normal y otro fractura delaminada. Se efectúa un estudio estructural mediante microscopía óptica y electrónica de barrido. Los resultados obtenidos muestran la presencia del fenómeno de rizado (curling. Además, se realizan ensayos de análisis térmico diferencial y simulación termodinámica aplicando Fact Sage, para analizar la estabilidad de carburos. Se corroboró la precipitación de carburos épsilon que ocurre por difusión de carbono en la interfaz ferrita-perlita, justificando el incremento de la resistencia mecánica.

  20. Transformaciones Microestructurales en Soldaduras Disímiles de Acero Inoxidable Austenítico con Acero Inoxidable Ferrítico

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    Sara María Aguilar-Sierra

    2015-03-01

    Full Text Available En este trabajo se estudian los fenómenos metalúrgicos que ocurren en la soldadura SMAW de un acero inoxidable ferrítico AISI 430 con un acero inoxidable austenítico AISI 316L. Para el estudio se utilizaron dos tipos de electrodos: austenítico AWS E309L y dúplex AWS E2209-16, ambos con un diámetro de 3,2 mm. Las uniones soldadas se realizaron con un solo pase y se variaron simultáneamente la corriente y la velocidad de soldadura; las condiciones fueron 49 A y 2,4 mm.s–1como valores bajos y 107 A y 4,3 mm.s–1como valores altos. Se evaluó la influencia del tipo de electrodo y de los parámetros de soldadura en la evolución microestructural de las zonas afectadas por el calor y de las zonas de fusión, encontrando diferencias en la morfología y cantidad de ferrita delta para todas las condiciones estudiadas. Se evidenció crecimiento y refinación de grano ferrítico y formación de martensita en la zona afectada por el calor del metal base ferrítico. Se evaluó también la resistencia a la tensión hallando similitudes en todas las soldaduras.

  1. Oxide Ferromagnetic Semiconductors for Spin-Electronic Transprt

    International Nuclear Information System (INIS)

    Pandey, R.K.

    2008-01-01

    The objective of this research was to investigate the viability of oxide magnetic semiconductors as potential materials for spintronics. We identified some members of the solid solution series of ilmenite (FeTiO3) and hematite (Fe2O3), abbreviated as (IH) for simplicity, for our investigations based on their ferromagnetic and semiconducting properties. With this objective in focus we limited our investigations to the following members of the modified Fe-titanates: IH33 (ilmenitehematite with 33 atomic percent hematite), IH45 (ilmenite-hematite with 45 atomic percent hematite), Mn-substituted ilmenite (Mn-FeTiO3), and Mn-substituted pseudobrookite (Mn- Fe2TiO5). All of them are: (1) wide bandgap semiconductors with band gaps ranging in values between 2.5 to 3.5 eV; (2) n-type semiconductors; (3) they exhibit well defined magnetic hysteresis loops and (4) their magnetic Curie points are greater than 400K. Ceramic, film and single crystal samples were studied and based on their properties we produced varistors (also known as voltage dependent resistors) for microelectronic circuit protection from power surges, three-terminal microelectronic devices capable of generating bipolar currents, and an integrated structured device with controlled magnetic switching of spins. Eleven refereed journal papers, three refereed conference papers and three invention disclosures resulted from our investigations. We also presented invited papers in three international conferences and one national conference. Furthermore two students graduated with Ph.D. degrees, three with M.S. degrees and one with B.S. degree. Also two post-doctoral fellows were actively involved in this research. We established the radiation hardness of our devices in collaboration with a colleague in an HBCU institution, at the Cyclotron Center at Texas A and M University, and at DOE National Labs (Los Alamos and Brookhaven). It is to be appreciated that we met most of our goals and expanded vastly the scope of

  2. New Methods and Facilities for the Measurement of Physical Properties of Reactor Components and Irradiated Materials; Nouveaux Procedes et Instruments de Mesure des Proprietes Physiques des Elements de Reacteur et des Matieres Irradiees; Novye metody i sredstva izmereniya fizicheskikh s vojstv komponentov reaktora i obluchennykh materialov; Nuevos Metodos y Equipos para Medir Propiedades Fisicas de Componentes de Reactor y de Materiales Irradiados

    Energy Technology Data Exchange (ETDEWEB)

    Foerster, F.; Mueller, P. [Institut Dr. Foerster, Reutlingen, Federal Republic of Germany (Germany)

    1965-09-15

    radiactivas a temperaturas comprendidas entre 20 y 1 000 Degree-Sign C. Los autores discuten el control de calidad de metales no ferrosos por medida de la conductividad electrica aplicando corrientes de Foucault. Se describe un instrumento para medir la conductividad electrica de metales no ferrosos sin utilizar elementos en contacto. Se explica la correlacion entre la conductividad electrica y las caracteristicas de esfuerzo-deformacion de metales y aleaciones no ferrosos. Se presta especial atencion a la determinacion de estas propiedades en muestras pequenas. Se describe un dispositivo para medicion directa a distancia en la zona radiactiva del reactor. Se examina la relacion existente entre conductividad electrica y la dosis de radiacion. Se describe un instrumento para medir la permeabilidad, la remanencia y la fuerza coercitiva en funcion de la-solicitacion mecanica y la deformacion elastica y plastica, como tambien de la dosis de radiacion. Se expone un metodo para medir la variacion de las propiedades magneticas en funcion de la solicitacion elastica y la deformacion plastica. Se discuten los efectos de la irradiacion sobre la permeabilidad y la fuerza coercitiva. Se describe un instrumento para medicion rapida e indicacion directa de la permeabilidad de componentes de acero inoxidable. Se explica la correlacion entre permeabilidad y contenido de {Delta} - ferrita. Se exponen las mediciones del porcentaje de {Delta} - ferrita en soldaduras practicadas en tubos de acero inoxidable, y de las precipitaciones de {Delta}-ferrita en funcion de la deformacion plastica (forjado de los elementos combustibles). (author) [Russian] Opisan pribor dlja avtomaticheskogo izmerenija i registracii modulja Junga, modulja sdviga i kojefficienta zatuhanija kak funkcii temperatury i vremeni. Izmerenie modulja Junga proizvoditsja s pomoshh'ju vozbuzhdennyh obrazcov razlichnyh razmerov pri ih estestvennoj chastote. Izmerenie kojefficienta zatuhanija proizvoditsja po svobodnomu zatuhaniju

  3. Performance of Surge Arrester Installation to Enhance Protection

    Directory of Open Access Journals (Sweden)

    Mbunwe Muncho Josephine

    2017-01-01

    Full Text Available The effects of abnormal voltages on power system equipment and appliances in the home have raise concern as most of the equipments are very expensive. Each piece of electrical equipment in an electrical system needs to be protected from surges. To prevent damage to electrical equipment, surge protection considerations are paramount to a well designed electrical system. Lightning discharges are able to damage electric and electronic devices that usually have a low protection level and these are influenced by current or voltage pulses with a relatively low energy, which are induced by lightning currents. This calls for proper designed and configuration of surge arresters for protection on the particular appliances. A more efficient non-linear surge arrester, metal oxide varistor (MOV, should be introduced to handle these surges. This paper shows the selection of arresters laying more emphasis on the arresters for residential areas. In addition, application and installation of the arrester will be determined by the selected arrester. This paper selects the lowest rated surge arrester as it provides insulation when the system is under stress. It also selected station class and distribution class of arresters as they act as an open circuit under normal system operation and to bring the system back to its normal operation mode as the transient voltage is suppressed. Thus, reduces the risk of damage, which the protection measures can be characterized, by the reduction value of the economic loss to an acceptable level.

  4. Study of protection devices against the effects of electric discharges inside a very high voltage generator: the Vivitron accelerator

    International Nuclear Information System (INIS)

    Nolot, E.

    1996-01-01

    The Vivitron tandem is a large electrostatic accelerator comprising a Van de Graaff generator designed to reach terminal voltages of around 30 MV. The machine is limited at rather lower nominal voltages (about 20 MV) due to the sensitivity of the insulating column structure to transient overvoltages. These are induced by electrical discharges in compressed SF 6 . This thesis first aims at analysing the fundamental reasons of electrical discharges in order to limit the probability of their occurrence. Then we simulate the transient overvoltages induced and present some improvements which may lead to a stable behaviour of the Vivitron at nominal voltages higher than 20 MV. Initially we deduce discharge onset voltages and actual breakdown field limitations in the different gap geometries from analysis of possible breakdown mechanisms in compressed SF 6 . In a second part, some electrical characteristics of the insulating column structure are measured at high voltage. Fast rising oscillating waves induced by sparking in the Vivitron, along with the associated energies,are determined in the third part. The last part deals with new surge protections of the insulating column structure. Spark gaps with precise onset voltage and optimized shielding electrodes are discussed. ZnO-based varistors designed for operation at very high fields have also been developed in order to reduce transient overvoltage values. (author)

  5. Study of protection devices against the effects of electric discharges inside a very high voltage generator: the Vivitron accelerator; Etude de dispositifs de protection contre les effets des decharges electriques au sein d`un generateur de tres haute tension: l`accelerateur Vivitron

    Energy Technology Data Exchange (ETDEWEB)

    Nolot, E

    1996-10-31

    The Vivitron tandem is a large electrostatic accelerator comprising a Van de Graaff generator designed to reach terminal voltages of around 30 MV. The machine is limited at rather lower nominal voltages (about 20 MV) due to the sensitivity of the insulating column structure to transient overvoltages. These are induced by electrical discharges in compressed SF{sub 6}. This thesis first aims at analysing the fundamental reasons of electrical discharges in order to limit the probability of their occurrence. Then we simulate the transient overvoltages induced and present some improvements which may lead to a stable behaviour of the Vivitron at nominal voltages higher than 20 MV. Initially we deduce discharge onset voltages and actual breakdown field limitations in the different gap geometries from analysis of possible breakdown mechanisms in compressed SF{sub 6}. In a second part, some electrical characteristics of the insulating column structure are measured at high voltage. Fast rising oscillating waves induced by sparking in the Vivitron, along with the associated energies,are determined in the third part. The last part deals with new surge protections of the insulating column structure. Spark gaps with precise onset voltage and optimized shielding electrodes are discussed. ZnO-based varistors designed for operation at very high fields have also been developed in order to reduce transient overvoltage values. (author). 122 refs.

  6. Influence of doping of Mn{sup +2} and Co{sup +2} in ZnO synthesized by combustion reaction for use in DMS; Influencia da dopagem do Mn{sup +2} e Co{sup +2} no ZnO sintetizado por reacao de combustao para uso em SMD

    Energy Technology Data Exchange (ETDEWEB)

    Torquato, R.; Costa, A.C.F.M. [Universidade Federal de Campina Grande (UFCG), Campina Grande, PB (Brazil). Departamento de Engenharia de Materiais; Shirsath, S.E. [Department of Physics, Vivekanand College, Aurangabad, MS (India); Kiminami, R.H.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Departamento de Engenharia de Materiais

    2011-07-01

    ZnO is a semiconducting ceramics used for development of electrical devices such as varistors, chemical sensors, piezoelectric transducers and diluted magnetic semiconductors. So this paper proposes to investigate the influence of doping of 0.1 mol of Mn{sup +2} and Co{sup +2} on the structure, morphology and magnetic measurements of ZnO synthesized by combustion reaction in DMS applications. The resulting samples were characterized by XRD, SEM, BET, VSM. The combustion temperature for samples doped with Mn and Co were 512 deg C and 397 °C, respectively. XRD results for both samples showed the formation of ZnO as the major phase, with crystallite size of 21nm and 23nm and a surface area of 59 and 17 m2/g for samples doped with Mn{sup +2} and Co{sup +2}, respectively. The magnetic measurements showed values of saturation magnetization and coercive force of 12 and 3 emu/g, and 94 and 237Oe, respectively. (author)

  7. Experimental study on microstructure development of binary system Zn-O-Nb2O5 sintered at 1100 deg C-1400 deg C

    International Nuclear Information System (INIS)

    Syarif, Dani Gustaman; Sukirman, Engkir; Handayani, Ari; Hidayat, Saeful

    2000-01-01

    In order to find effective (simple) varistor, in this work effect of Nb 2 O 5 addition on microstructure development and it's mechanism was studied experimentally. The study was conducted by sintering Zn-O added with 0-1% mole Nb 2 O 5 at 1100 o C-1400 o C in air for 1 hour and analyzing the sintered pellets using optical and electromicroscope (SEM) and x-ray diffractometer. The x-ray diffraction analysis showed that in Nb 2 O 5 added -ZnO (Zn-O-Nb 2 O 5 ) pellets sintered at 1100 o C-1400 o C, second phase of Zn 3 Nb 2 O 8 existed. On the other hand, the metallographic analysis showed that at sintering temperature of 1100 o C-1400 o C, grain size of Zn-O-Nb 2 O 5 pellets increased with increasing of Nb 2 O 5 , however, the grain size decreased again after the concentration of Nb 2 O 5 exceeding certain value. From this data it was know also, that there was solid solution area in Zn-O-Nb 2 O 5 phase diagram. At sintering temperature ≥ 1300 o C, there was liquid phase sintering that make grains become rounded

  8. Controlling interface characteristics by adjusting core-shell structure

    International Nuclear Information System (INIS)

    Chang, H.Y.; Cheng, S.Y.; Sheu, C.I.

    2004-01-01

    Most grain boundary layer ceramics comprise semiconductive/conductive grains and insulated grain boundaries. Such a structure can be theoretically regarded as a shell (grain boundary layer) surrounds a core (conductive or semiconductive grain). The core-shell structure of titanium (Ti)-strontium titanate (ST) is composed of three zones - ST, non-stoichiometric strontium-titanium oxide and Ti, in order from shell to core. It was successfully prepared using a hydrothermal method. The Ti-ST core-shell structure was sintered in a reducing atmosphere and then annealed in air to achieve the metal-insulator-metal structure (MIM structure). The resulting MIM structure, annealed in air, changes with the oxygen stoichiometry of the ST shell (insulator layer) at various temperatures, which is thus used to tune its electrical characteristics. The characteristics exhibit nonlinear behavior. Accordingly, the thickness of the insulator layer can be adjusted in various annealing atmospheres and at various temperatures to develop various interfacial devices, such as varistors, capacitors and thermistors, without the use of complex donor/acceptor doping technology

  9. Research using small tokamaks

    International Nuclear Information System (INIS)

    1991-01-01

    The technical reports contained in this collection of papers on research using small tokamaks fall into four main categories, i.e., (i) experimental work (heating, stability, plasma radial profiles, fluctuations and transport, confinement, ultra-low-q tokamaks, wall physics, a.o.), (ii) diagnostics (beam probes, laser scattering, X-ray tomography, laser interferometry, electron-cyclotron absorption and emission systems), (iii) theory (strong turbulence, effects of heating on stability, plasma beta limits, wave absorption, macrostability, low-q tokamak configurations and bootstrap currents, turbulent heating, stability of vortex flows, nonlinear islands growth, plasma-drift-induced anomalous transport, ergodic divertor design, a.o.), and (iv) new technical facilities (varistors applied to establish constant current and loop voltage in HT-6M), lower-hybrid-current-drive systems for HT-6B and HT-6M, radio-frequency systems for HT-6M ICR heating experimentation, and applications of fiber optics for visible and vacuum ultraviolet radiation detection as applied to tokamaks and reversed-field pinches. A total number of 51 papers are included in the collection. Refs, figs and tabs

  10. Study for obtaining a suppressor device of transients using the Al/SRO/Si structure; Estudio para la obtencion de un dispositivo supresor de transitorios utilizando la estructura Al/SRO/Si

    Energy Technology Data Exchange (ETDEWEB)

    Marin Ramos, Heriberto

    1999-06-01

    The circuits and electronic equipment use protective devices against voltage transients. In this work the Aluminium/Oxide structure rich in Silicon/Silicon is presented as another option in the field of transient suppressors devices. Some devices used in the suppression of voltage transients are: zinc oxide varistors, of silicon carbide varistors, selenium cells, and Zener diodes. The Al/SRO/Si structure presents conductive properties due to the presence of excess Silicon in the SRO film. Varying the reacting gases ratio (Ro=N{sub 2}O/SiH{sub 4}) during the growth of the film of Oxide Rich in Silicon (SRO), the conductivity of the material can be varied. The SRO turns out to be of great importance for the suppressor device of transients device that is pretended to be obtained in the present work due to its non-ohmic behavior. The Al/SRO/Si device behaves of several ways depending on the characteristics of the SRO and the silicon substrate. It has been found that one of these behaviors is as a of voltage transients suppressor. Verifying its behavior as transient suppressor, the effects of the film thickness, the area and the excess of silicon of the device were studied, for this purpose the characteristic I-V was obtained, and the obtention of some parameters in DC. In the present work the SRO was obtained by means of LPCVD (Low Pressure Chemical Vapor Deposition), initially a C-V characterization was made to obtain an indicative parameter of excess silicon, such as: permittivity of the SRO film. Also, the refraction index was obtained, which is an indicative parameter of the presence of excess Silicon. Once having the certainty of the presence of excess silicon it was proceed to obtain the I-V characteristic of the Al/SRO/Si structure as a device. The behavior of the Al/SRO/Si structure was analyzed with different parameters, such as: Ro, thickness of the SOR, areas. [Spanish] Los circuitos y equipos electronicos utilizan dispositivos de proteccion contra

  11. A soft computing scheme incorporating ANN and MOV energy in fault detection, classification and distance estimation of EHV transmission line with FSC.

    Science.gov (United States)

    Khadke, Piyush; Patne, Nita; Singh, Arvind; Shinde, Gulab

    2016-01-01

    In this article, a novel and accurate scheme for fault detection, classification and fault distance estimation for a fixed series compensated transmission line is proposed. The proposed scheme is based on artificial neural network (ANN) and metal oxide varistor (MOV) energy, employing Levenberg-Marquardt training algorithm. The novelty of this scheme is the use of MOV energy signals of fixed series capacitors (FSC) as input to train the ANN. Such approach has never been used in any earlier fault analysis algorithms in the last few decades. Proposed scheme uses only single end measurement energy signals of MOV in all the 3 phases over one cycle duration from the occurrence of a fault. Thereafter, these MOV energy signals are fed as input to ANN for fault distance estimation. Feasibility and reliability of the proposed scheme have been evaluated for all ten types of fault in test power system model at different fault inception angles over numerous fault locations. Real transmission system parameters of 3-phase 400 kV Wardha-Aurangabad transmission line (400 km) with 40 % FSC at Power Grid Wardha Substation, India is considered for this research. Extensive simulation experiments show that the proposed scheme provides quite accurate results which demonstrate complete protection scheme with high accuracy, simplicity and robustness.

  12. Current-voltage characteristics of SnO{sub 2}-Co{sub 3}O{sub 4}-Cr{sub 2}O{sub 3}-Sb{sub 2}O{sub 5} ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar-Martinez, J A [Centro de Investigacion en Materiales Avanzados, S.C. (CIMAV), Alianza Norte 202, Parque de Investigacion e Innovacion Tecnologica (PIIT), Nueva Carretera Aeropuerto km. 10, Apodaca, Nuevo Leon, CP 66600 (Mexico); Glot, A B [Posgrado, Universidad Tecnologica de la Mixteca, Carretera Acatlima Km. 2.5, Huajuapan de Leon, Oaxaca, CP 69000 (Mexico); Gaponov, A V [Department of Radioelectronics, Dniepropetrovsk National University, Dniepropetrovsk 49050 (Ukraine); Hernandez, M B [Instituto de Mineria, Universidad Tecnologica de la Mixteca, Carretera Acatlima Km. 2.5, Huajuapan de Leon, Oaxaca, CP 69000 (Mexico); Guerrero-Paz, J, E-mail: josue.aguilar@cimav.edu.m [Particulate Materials Lab, Universidad Autonoma del Estado de Hidalgo, Pachuca, CP 42184 (Mexico)

    2009-10-21

    The effect of mechanical treatment in a planetary mill on the microstructure and electrical properties of tin dioxide based varistor ceramics in the system SnO{sub 2}-Co{sub 3}O{sub 4}-Cr{sub 2}O{sub 3}-Sb{sub 2}O{sub 5} sintered in the range 1150-1450 {sup 0}C was studied. The mechanical treatment leads to an increase in shrinkage, decrease in porosity, decrease in sample diameter, change in colour of the sintered samples from grey to black and enhancement of nonlinearity. For the sample sintered at 1350 {sup 0}C the mechanical treatment enhances the nonlinearity coefficient from 11 to 31 and decreases the electric field E{sub 1} (at 10{sup -3} A cm{sup -2}) from 3500 to 2800 V cm{sup -1}. The observed changes in physical properties are explained in terms of an additional size reduction of oxide particles and a better mixing of oxide powder followed by the formation of potential barriers at the grain boundaries throughout the whole sample. In spite of the low porosity, the low-field electrical conductivity of mechanically treated ceramics is significantly increased with the growth of relative humidity. A higher humidity sensitivity is found for mechanically treated ceramics with higher barrier height and higher nonlinearity coefficient.

  13. Current-voltage characteristics of SnO2-Co3O4-Cr2O3-Sb2O5 ceramics

    International Nuclear Information System (INIS)

    Aguilar-Martinez, J A; Glot, A B; Gaponov, A V; Hernandez, M B; Guerrero-Paz, J

    2009-01-01

    The effect of mechanical treatment in a planetary mill on the microstructure and electrical properties of tin dioxide based varistor ceramics in the system SnO 2 -Co 3 O 4 -Cr 2 O 3 -Sb 2 O 5 sintered in the range 1150-1450 0 C was studied. The mechanical treatment leads to an increase in shrinkage, decrease in porosity, decrease in sample diameter, change in colour of the sintered samples from grey to black and enhancement of nonlinearity. For the sample sintered at 1350 0 C the mechanical treatment enhances the nonlinearity coefficient from 11 to 31 and decreases the electric field E 1 (at 10 -3 A cm -2 ) from 3500 to 2800 V cm -1 . The observed changes in physical properties are explained in terms of an additional size reduction of oxide particles and a better mixing of oxide powder followed by the formation of potential barriers at the grain boundaries throughout the whole sample. In spite of the low porosity, the low-field electrical conductivity of mechanically treated ceramics is significantly increased with the growth of relative humidity. A higher humidity sensitivity is found for mechanically treated ceramics with higher barrier height and higher nonlinearity coefficient.

  14. UNA MIRADA AL ESTUDIO Y LAS APLICACIONES TECNOLÓGICAS Y BIOMÉDICAS DE LA MAGNETITA UM OLHAR AO ESTUDO E AS APLICAÇÕES TECNOLÓGICAS E BIOMÉDICAS DA MAGNETITA A LOOK AT THE STUDY AND THE TECHNOLOGICAL AND BIOMEDICAL APPLICATIONS OF MAGNETITE

    Directory of Open Access Journals (Sweden)

    Johan Mazo-Zuluaga

    2011-12-01

    Full Text Available La investigación orientada al conocimiento de las propiedades magnéticas de los materiales se mantiene como un tema de actualidad y alta importancia en ciencia, tecnología e ingeniería; con mayor razón en las últimas décadas, dado el desarrollo de los materiales nanoestructurados. Con el presente trabajo se pretende ilustrar la importancia de la ferrita de hierro o magnetita (Fe3O4, en los campos de la ingeniería y la nanotecnología. Se examinan algunos de los aspectos más relevantes de las aplicaciones de materiales nanoestructurados a la tecnología moderna, y se revisa con detalle la bibliografía sobre estudios científicos de la magnetita en su aspecto biológico, técnico y teórico-computacional. Se espera ofrecer así un panorama amplio, aunque no acabado, de las formas de utilización de este interesante material en la apasionante área del magnetismo y la nanotecnología.A pesquisa orientada ao conhecimento das propriedades magnéticas dos materiais mantém-se como um tema de atualidade e alta importância em ciência, tecnologia e engenharia; com maior razão nas últimas décadas, dado o desenvolvimento dos materiais nanoestructurados. Com o presente trabalho pretende-se ilustrar a importância da ferrita de ferro ou magnetita (Fe3O4, nos campos da engenharia e a nanotecnologia. Examinamse alguns dos aspectos mais relevantes das aplicações de materiais nanoestructurados à tecnologia moderna, e revisa-se com detalhe a bibliografia sobre estudos científicos da magnetita em seu aspecto biológico, técnico e teórico-computacional. Espera-se oferecer assim um panorama amplo, ainda que não acabado, das formas de utilização deste interessante material na apaixonante área do magnetismo e a nanotecnologia.In the last decades, research oriented towards the development of knowledge regarding magnetic properties of materials remains as a relevant field of study in science, technology and engineering due to its implications on

  15. Avaliação de Revestimentos de Liga de Níquel 625 Depositados pelo Processo Eletroescória

    Directory of Open Access Journals (Sweden)

    Soraia Simões Sandes

    Full Text Available Resumo A aplicação de revestimentos de ligas de níquel é comumente realizada na indústria de petróleo e gás para aumento da vida de equipamentos em ambientes agressivos, dado que este procedimento melhora a resistência à corrosão, sem um aumento significativo do custo de produção quando comparado com equipamentos maciços fabricados com outras ligas. Normalmente, as juntas são soldadas pelos processos de eletrodos revestidos, MIG/MAG ou TIG. Neste aspecto, o processo eletroescória realiza deposições com elevada energia de soldagem e baixa diluição, podendo ser uma opção interessante, uma vez que proporciona uma elevada produtividade, permitindo a soldagem com aplicação de apenas uma camada. O presente trabalho avalia propriedades mecânicas, microestruturais e de corrosão de revestimentos de liga de níquel 625 depositada em aço carbono ASTM A516 Grau 70 pelo processo eletroescória, tanto na condição como soldado quanto tratado termicamente. A deposição foi realizada com uma e duas camadas sobre chapas de dimensão 50x400x400 mm, na posição plana e energia de soldagem média de 11,7 kJ/mm. Após a soldagem realizou-se tratamento térmico a 620°C por 10 horas, sendo esta condição comparada ao estado de como soldado. Os ensaios de dobramento não indicaram evidências de defeitos. A avaliação microestrutural realizada por microscopia ótica (MO, eletrônica de varredura (MEV e eletrônica de transmissão (MET mostrou uma microestrutura austenítica para o depósito com pequena fração volumétrica de fases secundárias e o tratamento térmico de alívio de tensões não promoveu mudanças significativas nas propriedades. Na região de grãos grosseiros da zona termicamente afetada (RGGZTA foi observada a ocorrência de ferrita pró-eutetóide, perlita e bainita para o depósito com 1 camada e basicamente ferrita e perlita refinadas para o deposito com 2 passes devido às baixas taxas de resfriamento

  16. Avaliação da proporção de fases em juntas soldadas de tubulações de aço inoxidável duplex mediante aplicação de ensaios não destrutivos Evaluation of phases proportions in welded joints of duplex stainless steel by non-destructive testing

    Directory of Open Access Journals (Sweden)

    Guttemberg Chagas de Souza

    2013-06-01

    Full Text Available Os aços inoxidáveis Duplex (AID aliam uma excelente resistência à corrosão com elevada resistência mecânica devido à fina microestrutura bifásica composta por quantidades similares de ferrita (δ e austenita (γ. Portanto, estas ligas são utilizados em tubulações e equipamentos industriais onde se requer elevada relação resistência/peso, especialmente em empreendimentos de construção e montagem off-shore. Entretanto, as condições operacionais, na soldagem de campo, podem promover um significativo desbalanço microestrutural destas fases, resultando em decréscimo das propriedades mencionadas. A inspeção com o ferritoscópio é uma avaliação normalmente utilizada nestas atividades. Durante a avaliação com esta técnica pode ocorrer a rejeição da junta soldada quando o metal de solda se encontra com valores de ferrita fora das faixas estabelecidas pelas especificações de projeto. Assim, torna-se importante a análise destas juntas, com outras técnicas complementares, tal como a utilização das réplicas metalográficas. Este fato motivou a avaliação da proporção de fases em spools de AID de espessuras relativamente finas, soldados no campo, comparando-se as técnicas não destrutivas descritas. Os resultados denotam valores semelhantes, contudo o resultado pode ser influenciado pela forma e condições superficiais da junta soldada.Duplex stainless steels are high strength and corrosion resistant alloys, whose properties are devoted to the fine microstructure composed by similar amounts of ferrite and austenite and also to the high concentrations of Cr, Mo and N in solid solution. Not for coincidence, duplex steels are extensively used in chemical and petrochemical industries. However, welding operations conditions can promote the unbalance of the ferrite/austenite proportions mainly in the welding metal, with decrease of the properties mentioned. For this reason, non destructive measurements of ferrite content

  17. Estudo dos efeitos da restrição na microestrutura, microdureza e tenacidade em juntas soldadas em aço inoxidável duplex Study of restriction effects on mMicrostructure, microhardness and toughness in welded joints of duplex stainless steel

    Directory of Open Access Journals (Sweden)

    Everton Barbosa Nunes

    2011-06-01

    Full Text Available Os aços inoxidáveis duplex (AID apresentam em sua microestrutura ferrita e austenita, de modo a aliar boas propriedades mecânicas e resistência à corrosão. Estes materiais possuem grande aplicação na indústria petroquímica, sendo o UNS S31803 um dos mais conhecidos. Existem poucos trabalhos referentes ao estudo da influência da restrição na soldagem da junta na formação de Widmanstätten. Logo, este trabalho tem como objetivo analisar a influência da restrição no balanceamento de fases, na morfologia da austenita, na microdureza e na tenacidade da Zona Afetada pelo Calor (ZAC e da Zona Fundida (ZF. Foram realizadas soldagens em juntas tipo V utilizando eletrodo revestido AWS E2209-17com dois níveis de energia: 15 kJ/cm e 20 kJ/cm, com e sem restrição. De maneira geral, houve maior quantidade de ferrita nos passes de acabamento em relação aos passes de enchimento e de raiz. Foram observadas maiores quantidades de Widmanstätten nas condições soldadas com restrição. A ZAC apresentou uma microestrutura mais grosseira nos passes de acabamento. No entanto, não foram observadas diferenças significativas nas microestruturas quando comparadas as condições com e sem restrição. As condições que apresentaram maior quantidade de Widmanstätten obtiveram menores níveis de microdureza. Não foram observadas diferenças na energia absorvida na ZAC e ZF.Duplex stainless steels present ferrite and austenite in their microstructure in order to join good mechanical properties and corrosion resistance. These materials are very used in petrochemical industry, being the DSS UNS S31803 one of the most commercially known. There were not much published literature to study the influence of the precipitation of Widmanstätten austenite in joins with some restriction. This work has as objective to analyze the influence of the restriction in the phase balance of austenite and ferrite, in the morphology of the austenite, in the

  18. Efecto de la Composición Química del Metal de Aporte y del Calor Aportado Sobre la Microestructura y las Propiedades Mecánicas de Juntas Soldadas de Aceros Inoxidables Dúplex

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    Sebastián Zappa

    Full Text Available Resumen Los aceros inoxidables dúplex poseen una microestructura dual (ferrita y austenita con contenidos aproximadamente iguales y se caracterizan por tener buena soldabilidad, buenas propiedades mecánicas y una alta resistencia a la corrosión generalizada y localizada. Gracias a estas características, estos aceros son los principales materiales a emplear en cañerías con altas exigencias, ampliamente utilizados en varias industrias, principalmente la petroquímica. Dichas propiedades están controladas por la composición química, el equilibrio microestructural y la ausencia de compuestos intermetálicos. El objetivo de este trabajo fue estudiar la influencia de la composición química del metal de aporte y el calor aportado sobre la microestructura y las propiedades mecánicas en juntas soldadas de cañerías de acero inoxidable dúplex. El metal base utilizado fue un acero inoxidable dúplex UNS S31803 de 8” de diámetro y 8,18 mm de espesor y los metales de aporte fueron dos alambres tubulares que depositan aceros inoxidables dúplex y lean dúplex (AWS A5.22: E2209T1-1 y E2209T1-G, mediante el proceso de soldadura semi-automático bajo protección gaseosa, soldados con alto y bajo calor aportado. De cada probeta se extrajeron muestras donde se determinó la composición química, se realizó la caracterización microestructural y se determinaron las propiedades mecánicas (dureza, tracción y Charpy-V.

  19. Estudio dilatométrico de la descomposición anisotérmica de la perlita en un acero bajo en carbono (0,11 C-0,50 Mn

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    García de Andrés, C.

    1998-05-01

    Full Text Available A dilatometric contraction at the onset of the austenitization has been detected by means of high resolution dilatometric analysis. This anomaly was associated with the pearlite dissolution process. A significant effect of pearlite interlamellar spacing on the shape of the dilatometric anomaly has been found. A clear dilatometric anomaly can only be detected when a fine pearlite is present in the starting microstructure of the steel. The identification of the temperature at which pearlite dissolution finishes would make it possible to select the most suitable intercritical temperature to obtain ferrite + martensite dual phase microstructures with an optimum combination of mechanical properties. In the presente work, the influence of starting pearlite morphology on the dilatometric response associated with the pearlite dissolution process during continuous heating has been studied in 0.11C-0.50Mn low carbon steel.

    Por medio del análisis dilatométrico de alta resolución, se ha detectado la aparición de una contracción dilatométrica asociada con el proceso de disolución de la perlita, que únicamente aparece cuando la microestructura inicial presenta perlita con un espaciado interlaminar fino. Esta contracción dilatométrica desaparece cuando la estructura inicial presenta una perlita grosera o de mayor espaciado interlaminar, impidiendo así la selección de las temperaturas del intercrítico más apropiadas para la obtención de microestructuras dual de ferrita + martensita con las mejores propiedades mecánicas. En este trabajo se estudia la influencia de la morfología de la perlita inicial de un acero 0,11C-0,50Mn sobre la respuesta dilatométrica asociada al proceso de disolución de dicha fase en calentamiento continuo.

  20. Efecto del V y el Si Sobre la Microestructura de Depósitos Realizados con Electrodos Tubulares Revestidos de Alto Contenido de Mn (Hadfield

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    Manuel Rodríguez

    2017-10-01

    Full Text Available Resumen: Las aleaciones para el relleno superficial Fe-Mn-C (Hadfield han demostrado una excelente resistencia al desgaste bajo altas cargas dinámicas. En los últimos años se han realizado numerosos estudios para aumentar la resistencia al desgaste y mejorar su desempeño, a través de la introducción de otros elementos de aleación. En el presente trabajo se investiga la microestructura y dureza de los depósitos de relleno con alto contenido de Mn y adiciones de 1.2% de V y 2.4% de Si. Los depósitos estudiados se realizaron utilizando electrodos tubulares revestidos fabricados a escala de laboratorio. Las fases y microconstituyentes en el metal depositado se identificaron mediante microscopía óptica (MO, electrónica de barrido (MEB, difracción de rayos X (DRX, dureza y microdureza. De acuerdo a los resultados obtenidos, la adición de V al sistema aleante originó que la fase predominante fuera la austenita. Además, contribuyó a la formación de carburos de vanadio (VC en la microestructura de la capa de relleno, sin observarse la presencia de carburos complejos. Por otra parte, la presencia de Si favoreció la formación de una red de ferrita interdendrítica. La adición de estos elementos de aleación mejoró las propiedades de estos depósitos, potencializando su uso en aplicaciones que requieren alta resistencia al desgaste bajo altas cargas.

  1. Modelling reaustenitisation in Fe-C steels with concentration-dependent diffusivity of carbon

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    Mancini, R.

    2002-12-01

    Full Text Available A finite difference method used to model reaustenitisation from a ferrite/cementite mixture in Fe-C steels is presented in this paper. Concentration-dependent carbon diffusivity in austenite is taken into account in order to generalize our earlier numerical model. We select some parameters, such as cementite dissolution time, and compare their values as calculated by different approximations available in the literature (in particular at steady state for planar and spherical geometries. When the dependence of diffusivity on concentration or temperature is increased, the steady state approximation fails to predict correctly the above mentioned parameters and the use of numerical techniques becomes indispensable.

    En este trabajo se presenta un método numérico de diferencias finitas para modelar la reaustenización en aceros Fe-C a partir de una distribución inicial de ferrita y cementita. Se tiene en cuenta la dependencia de la difusividad en la austenita con la concentración de carbono, a fin de generalizar el propio modelo numérico previo. Se han seleccionado algunos parámetros, como el tiempo de disolución de la cementita, para comparar los valores obtenidos en este caso con los calculados con diferentes aproximaciones (en particular con la de estado estacionario para los casos de geometrías plana y esférica. Los resultados obtenidos muestran que, cuando la difusividad depende fuertemente de la concentración, la aproximación de estado estacionario no predice correctamente los parámetros calculados y se hace imprescindible la aplicación de métodos numéricos.

  2. Microestrutura de uma Solda Dissimilar entre o Aço Inoxidável Ferrítico AISI 410S e o Aço Inoxidável Austenítico AISI 304L Soldado pelo Processo FSW

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    Tathiane Caminha Andrade

    2015-12-01

    Full Text Available Resumo O presente trabalho visa investigar a microestrutura formada na soldagem dissimilar entre chapas de aços inoxidáveis ferríticos AISI 410S e aços inoxidáveis austeníticos AISI 304L pelo processo friction stir welding. A soldagem foi realizada com o ajuste dos seguintes parâmetros: rotação 450 rpm; velocidade de soldagem de 1,0 mm/s; e força axial 40 kN. O aço AISI 410S foi posicionado no lado de avanço enquanto que o aço AISI 304L foi posicionado no lado de retrocesso. A análise consistiu de preparação metalográfica e caracterização microestrutural por microscopia ótica e microscopia eletrônica de varredura. Para o aço AISI 410S foi observada a formação de martensita associada com ferrita na zona de mistura (ZM, zona termomecanicamente afetada (ZTMA e na zona afetada pelo calor (ZAC. As características do processo de soldagem FSW resultaram num refino de grão para o aço inoxidável ferrítico, posicionado no lado de avanço, tanto na ZM quanto nas ZTMA e ZAC. O mesmo comportamento não foi observado para o lado austenítico.

  3. Sintering of tin oxide and its applications in electronics and processing of high purity optical glasses Sinterização de óxido de estanho e sua aplicação em eletrônica e no processamento de vidros ópticos de alta pureza

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    J. A. Varela

    2001-06-01

    Full Text Available Tin oxide is an n type semiconductor material with a high covalent behavior. Mass transport in this oxide depends on the surface state promoted by atmosphere or by the solid solution of aliovalent oxide doping. The sintering and grain grow of this type of oxide powder is then controlled by atmosphere and by extrinsic oxygen vacancy formation. For pure SnO2 powder the surface state depends only in the interaction of atmosphere molecules with the SnO2 surface. Inert atmosphere like argon promotes oxygen vacancy formation at the surface due to the reduction of SnO 2 to SnO at surface and liberation of oxygen molecules forming an oxygen vacancy. As a consequence, surface diffusion is enhanced leading to grain coarsening, but no densification. Oxygen atmosphere inhibits the SnO2 reduction decreasing the surface oxygen vacancy concentration. Additions of dopants with lower valence at sintering temperature create extrinsic charged oxygen vacancies that promote mass transport at grain boundary leading to densification and grain growth of this polycrystalline oxide. Cobalt and niobium doped SnO2 ceramics exhibit varistor behavior, which can be applied in electronics. Moreover, SnO2 ceramics are chemically inert and can be applied in form of crucibles to melt some optical glasses.Óxido de estanho é um material semicondutor do tipo n com comportamento altamente covalente. O transporte de massa neste óxido depende do estado da superfície promovido pela atmosfera ou pela solução sólida devida a dopagem de óxido aliovalente. A sinterização e o crescimento de grão deste tipo de óxido na forma de pó é então controlado pela atmosfera e pela formação de vacância de oxigênio extrínseca. Para o pó de SnO2 puro o estado da superfície depende somente da interação das moléculas da atmosfera com a superfície do SnO2. Atmosferas inertes como a de argônio promovem a formação de vacâncias de oxigênio na superfície devido a redução de SnO2

  4. Efecto del lavado con etilendiamina sobre las propiedades de las nanopartículas de óxido de estaño

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    Montenegro Hernández, A.

    2007-08-01

    Full Text Available Tin oxide, is a compound used in many technological applications among them as gas sensor and in the production of varistors, electronic devices, electrocatalitic electrodes and fotovoltaic cells, among others. In this work the controlled precipitation method was used to synthesize tin oxide of nanometric size using tin sulfate precursor. The control of different stages of the synthesis process was carried out through the variation of the system pH registrations, potentiometric titration,; This curve contain information on the different processes that take place in the system and it can be used to guarantee the process reproducibility. Additionally we propose a mechanism to explain the nucleation of solid phase in the solution. The hydrolysis and policondensation reactions are very important for this mechanism. Precipitate washing with an ethylendiamine solution permitted eliminated of SO4 2- and it permitted to obtain the tin oxide as the principal crystalline phase at room temperature. The characteristics of the obtained ceramic powder were determined using infrared espectroscopy (FTIR, X-ray diffraction (XRD, and transmission electron microscopy (TEM.

    El óxido de estaño es un compuesto ampliamente utilizado en aplicaciones tecnológicas destacándose como catalizador, sensor de gas, en fabricación de varistores, dispositivos electrónicos, electrodos electrocatalíticos y celdas fotovoltaicas, entre otros. En el presente trabajo se utilizó el método de precipitación controlada (MPC para sintetizar óxido de estaño de tamaño nanométrico, empleando como precursor sulfato de estaño. El control de las diferentes etapas del proceso de síntesis se realizó a través de los registros de variación de pH, valoración potenciométrica, del sistema. Con base a esta información y el estudio de espectroscopía infrarroja realizada en la fase sólida, a diferentes valores de pH, se propone un mecanismo de formación de las part

  5. Uso de métodos químicos para obtener polvos cerámicos del sistema (Sn, TiO2

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    Rodríguez-Páez, J E.

    2005-08-01

    Full Text Available The (Sn,TiO2 system has a great interest due to its technological applications such as gas sensor and varistor. Although the thermodynamic properties and the kinetics of spinoidal decomposition in this system have been extensively studied, the general properties and applications of SnO2 – TiO2 binary compositions have been not investigated yet in depth. On the other hand, little work has been done to optimize the synthesis methods to obtain (Sn,TiO2 ceramic powders, with pre – determinate physical and chemical characteristics. In this work the ceramic powders has been obtained by coprecipitation and polymeric precursor (Pechini methods. The different physical chemistry phenomena that occurred during the synthesis were discussed. The (Sn,TiO2 ceramic powders were characterized with X- ray diffraction (XRD, thermal analysis (DTA/ TG and scanning electron microscopy (SEM. The knowledge about of steps and variables of synthesis process acquired with development of this work, we permited to obtain (Sn, TiO2 nanometers particles to low temperatures: to 450°C for coprecipitation method and to 600°C for Pechini method. The spinodal decomposition that ocurr to 900°C was discussed also.El sistema (Sn,TiO2, puro o dopado, tiene gran interés por las potencialidades tecnológicas que presenta como sensor de gas y varistor. A pesar del amplio estudio realizado de este sistema binario, respecto a las propiedades termodinámicas y cinéticas de la descomposición espinoidal que en él se presenta, sus propiedades y sus posibles aplicaciones no se han abordado con profundidad. Por otro lado, se ha realizado muy poco trabajo para optimizar métodos de síntesis que permitan obtener polvos cerámicos de (Sn,TiO2, puro o dopado, con características físicas y químicas pre-determinadas. En este trabajo se realizó la síntesis de polvos cerámicos de este sistema utilizando los métodos de coprecipitación y precursor polimérico (Pechini y se discutieron

  6. Thermoluminescence of europium-doped zinc oxide exposed to beta particle irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Iriqui R, J. L.; Cruz V, C. [Universidad de Sonora, Departamento de Investigacion en Polimeros y Materiales, Apdo. Postal 130, 83000 Hermosillo, Sonora (Mexico); Bernal, R. [Universidad de Sonora, Departamento de Investigacion en Fisica, Apdo. Postal 5-088, 83000 Hermosillo, Sonora (Mexico); Castano, V. M., E-mail: jorgeiriqui@gimmunison.com [UNAM, Instituto de Fisica, Centro de Fisica Aplicada y Tecnologia Avanzada, Apdo. Postal 1-1010, 76000 Queretaro, Qro. (Mexico)

    2015-10-15

    Full text: Zn O is a promising material for a range of optoelectronics applications, due to its direct wide band gap (E{sub g} ∼3.3 eV at 300 K) and large exciton binding energy (60 MeV). Its applications include UV light emitters, varistors, surface acoustic wave devices, piezoelectric transducers, and chemical and gas sensing. Rare-earth activation of phosphors has long been seen as an effective process since coupling energy into the rare-earth-ion site, either by ionization, charge exchange or a resonance energy process, results in light production. It is reported that Europium modifies the response thermoluminescence (Tl) for pure zinc oxide, when is irradiated with X-ray, created a peak at 365 degrees C. In this work, Zn O:Eu phosphors were synthesized by a chemical method. Some samples were exposed to beta particle irradiation for doses ranging from 1 up to 100 Gy. Tl response as a function of dose is linear throughout the studied dose range. The glow curve exhibits three maxima, centered at 176, 279 and 340 degrees C. The reusability studies obtained after ten repeated cycles of annealing irradiation readout for the Zn O:Eu shows that the variation in the Tl response is ten percent and tends to stabilization. The results indicate that these new Zn O:Eu phosphors are promising detectors and dosimeters for beta radiation. The structural and morphological characterization was carried out by X-ray diffraction and scanning electron microscopy, respectively. (Author)

  7. Pesquisa e desenvolvimento em cerâmicas eletro-eletrônicas no IPEN

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    Muccillo R.

    1999-01-01

    Full Text Available O Grupo de Cerâmicas Eletro-eletrônicas do IPEN desenvolve trabalhos de pesquisa em materiais cerâmicos avançados para utilização em dispositivos sensores de espécies químicas e em células de combustíveis a eletrólitos sólidos. As principais áreas de atuação do grupo são em 1 síntese, processamento e caracterização elétrica de materiais cerâmicos, 2 estudo de correlação microestrutura-propriedades elétricas de materiais cerâmicos, 3 projeto, desenvolvimento, montagem e testes de sensores eletroquímicos de espécies químicas. Os principais materiais estudados são condutores iônicos (à base de ZrO2, ThO2 e outros, protônicos (à base de BaCeO3, varistores à base de SnO2, supercondutores cerâmicos de alta temperatura crítica (das famílias Y-Ba-Cu-O e Bi-Sr-Ca-Cu-O e compósitos de matriz cerâmica (dos tipos isolante em matriz condutora iônica e condutor iônico em matriz supercondutora. A infra-estrutura experimental dispõe de analisador de impedância, difratômetro de raios X, equipamento de análise térmica simultânea, fornos para sinterização e laboratório químico. O trabalho de pesquisa do Grupo é financiado por projetos FAPESP e PRONEX.

  8. The influence of green microstructure and sintering parameters on precipitation process during copper-nickel-zinc ferrites sintering

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    Barba, Antonio

    2014-04-01

    Full Text Available Microstructural changes that occur during heat treatment of copper-nickel-zinc ferrites have been studied. The process of precipitation of the two types of crystals that occur during the sintering process has been analyzed. It is found that this process depends on dry relative density of the press specimens and on the following sintering parameters: sintering temperature, sintering time and cooling rate of the thermal cycle. Crystal precipitates characterization have been done by scanning electron microscopy (SEM, energy-dispersive X-ray (EDX analysis, X-ray diffraction (XRD, and X-ray photoelectron spectroscopy (XPS. These techniques have allowed to determine the nature of these crystals, which in this case correspond to zinc and copper oxides. It has been used two chemical reactions to explain the bulk precipitation and subsequent re-dissolution of these crystal precipitates during sintering.En este trabajo se han estudiado los cambios microestructurales que se producen durante el tratamiento térmico de las ferritas de cobre-níquel-cinc y se ha analizado el proceso de precipitación de los dos tipos de cristales que aparecen durante el proceso de sinterización. Se ha encontrado que este proceso depende de la densidad relativa en seco de las muestras compactadas y de las siguientes variables de la etapa de sinterización: temperatura y tiempo de sinterización y velocidad de enfriamiento. La caracterización de los cristales precipitados se ha realizado por microscopía electrónica de barrido (MEB, microanálisis por dispersión de energía de rayos X (EDX, difracción de rayos X (DRX, y espectroscopía de fotoelectrones de rayos X (XPS. Estas técnicas han permitido determinar la naturaleza de estos cristales, que en este caso corresponden a los óxidos de cinc y de cobre. Se han propuesto dos reacciones químicas que permiten explicar el proceso de precipitación y la posterior re-disolución de estos cristales precipitados durante la

  9. Caracterización y propiedades mecánicas a alta temperatura de un acero inoxidable dúplex

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    Jiménez, J. A.

    1998-05-01

    Full Text Available The microstructure and mechanical behavior at high temperature of a thermomechanical processed duplex stainless steel have been studied. Recrystalization of the material takes place during heating to test temperature, and a microstructure consisting of islands of austenitic grains of about 10-15 μm in size included in a more or less continuous matrix of ferrite is observed. Tensile tests at temperatures above 1,000°C and at low strain rates show a stress exponent of about 2 and elongations to failure up to 290 %. These values suggest that deformation is controlled by a grain boundary sliding mechanism, which causes a decrease in the size of the islands during deformation. Finally, an activation energy for plastic deformation of 167 kJ/mol was observed that was related to the activation energy for grain boundary diffusion of iron.

    Se ha estudiado la microestructura y el comportamiento mecánico a alta temperatura de un acero inoxidable dúplex procesado termomecánicamente. Durante el calentamiento a la temperatura de ensayo, el material recristaliza y se obtiene una microestructura de granos austeníticos de tamaños comprendidos entre 10 y 15 μm agrupados en islas incluidas en una matriz más o menos continua de ferrita. Ensayos de tracción a temperaturas superiores a 1.000°C y bajas velocidades de deformación muestran un exponente de la tensión igual a 2 y alargamientos a rotura de hasta 290 %. Estos valores permiten asociar el mecanismo de deformación al deslizamiento de fronteras de grano, el cual determina la desaparición progresiva de las islas de granos austeníticos durante la deformación. Finalmente, se encontró un valor de 167 kJ/mol para la energía de activación de la deformación plástica, la cual se relacionó con la energía de autodifusión del hierro a lo largo de las fronteras de grano.

  10. Reciclagem de Cavacos de Titânio para a Deposição de Revestimentos Duros por Soldagem

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    José Gedael Fagundes Júnior

    2015-03-01

    Full Text Available O titânio é um metal nobre e possui excelentes propriedades biomecânicas, podendo assim ser plenamente aceito pelo organismo humano. A grande demanda na utilização de implantes dentários, fabricados a partir de ligas de titânio traz consigo um aumento significativo na geração de resíduos (cavacos, resultantes dos processos de usinagem empregados. Com o objetivo de reduzir os impactos ambientais, soluções alternativas para a reutilização de tais resíduos têm sido estudadas. O carboneto de titânio (TiC possui elevada dureza, o que potencialmente permitiria a sua utilização como reforço em revestimentos antidesgaste aplicados em equipamentos das indústrias sucroalcooleira e mineradoras. Neste trabalho cavacos de ligas a base de titânio foram processados e utilizados como matéria prima para a fabricação de consumíveis experimentais de soldagem. Cordões de solda foram produzidos sobre amostras de aço-carbono por soldagem a arco elétrico com proteção gasosa e eletrodo de tungstênio (tradução do termo inglês GTAW. A caracterização microestrutural do metal de solda foi realizada por MEV e difração de raios-X. O comportamento mecânico dos revestimentos foi analisado por meio de um ultramicrodurômetro digital. Verificou-se que a microestrutura do metal de solda era composta por partículas não prismáticas de alta dureza distribuídas em uma matriz ferrítica. Medidas feitas por microanálise EDS mostraram diferenças na concentração de titânio entre a matriz e as partículas duras, onde maiores teores deste elemento foram identificados. A análise cristalográfica confirmou que houve a formação de carbonetos de titânio envoltos por uma matriz de ferrita.

  11. Efeito dos parâmetros de processo na obtenção e na microestrutura de juntas alumínio-aço realizadas mediante soldagem por atrito com pino não consumível (SAPNC

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    Edwar Andrés Torres López

    2013-09-01

    Full Text Available Os resultados bem-sucedidos apresentados na literatura acerca da soldagem por atrito com pino não consumível das juntas alumínio-aço, desconsideram o aspecto e formação de defeitos na junta como pontos de referência para sua avaliação. Igualmente aumenta a controvérsia acerca da presença de compostos intermetálicos do tipo Fe xAl y, somado à falta de informação sobre sua origem. O objetivo deste trabalho é determinar parâmetros adequados para a obtenção de juntas alumínio-aço livres de defeitos e sua relação com a formação de fases deletérias durante a soldagem por atrito com pino. Foram obtidas juntas soldadas consolidadas e foi determinada a microestrutura resultante destas juntas soldadas da liga de alumínio 6063-T5 e aço AISI SAE 1020. Utilizou-se uma ferramenta de carbeto de tungstênio (WC-14Co a velocidades de rotação e de avanço de 300 rpm e 150 mm.min-1, respectivamente. Foram empregados deslocamentos da ferramenta de +0,5; +1,0 e +1,5 mm. Os resultados realçam a importância do aporte energético na obtenção de juntas alumínio-aço com aspecto superficial e penetração adequados. A análise microestrutural revela a formação de sete regiões na junta soldada, destacando a zona termo-mecanicamente afetada no lado do aço, uma banda de grãos ultra finos de ferrita e a ausência de compostos intermetálicos na interface alumínio-aço.

  12. Synthesis, microstructure and properties of BiFeO3-based multiferroic materials: A review

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    Bernardo, M. S.

    2014-02-01

    Full Text Available BiFeO3-based materials are currently one of the most studied multiferroics due to their possible applications at room temperature. However, among the large number of published papers there is much controversy. For example, possibility of synthesizing a pure BiFeO3 phase is still source of discussion in literature. Not even the nature of the binary Bi2O3-Fe2O3 diagram has been clarified yet. The difficulty in controlling the formation of parasite phases reaches the consolidation step. Accordingly, the sintering conditions must be carefully determined both to get dense materials and to avoid bismuth ferrite decomposition. However, the precise conditions to attain dense bismuth ferrite materials are frequently contradictory among different works. As a consequence, the reported properties habitually result opposed and highly irreproducible hampering the preparation of BiFeO3 materials suitable for practical applications. In this context, the purpose of the present review is to summarize the main researches regarding BiFeO3 synthesis, microstructure and properties in order to provide an easier understanding of these materials.Los materiales basados en BiFeO3 son en la actualidad uno de los multiferroicos más estudiados debido a sus posibles aplicaciones a temperatura ambiente. Sin embargo, entre la multitud de trabajos publicados referentes a estos materiales existe mucha controversia. Por ejemplo, la posibilidad de sintetizar una fase BiFeO3 pura es aún objeto de discusión en la bibliografía y la naturaleza de los diagramas de fases del sistema Bi2O3-Fe2O3 aún no está clara. La dificultad para controlar las fases parásitas se extiende al proceso de consolidación por lo que las condiciones de sinterización deben ser cuidadosamente controladas para obtener materiales densos y al mismo tiempo evitar la descomposición de la ferrita. No obstante, las condiciones precisas para obtener materiales densos de BiFeO3 son frecuentemente

  13. Influencia de la microestructura en el comportamiento a fatiga de aceros inoxidables austeníticos con alto contenido en molibdeno

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    Oñoro, J.

    2006-02-01

    íticos 317LN con microestructuras diferentes. El acero con una estructura completamente austenítica ha presentado mejor resistencia a la fatiga y a la corrosión-fatiga y mejor ductilidad que el acero con una microestructura austenítica con presencia de ferrita, especialmente a cargas bajas.

  14. Influencia del revenido en la estructura y las propiedades de dureza, resistencia a la tracción y resiliencia del acero cubano al cromomanganeso- silicio-níquel. // Influence of tempering on structure and hardness, strength and resilience properties of ch

    Directory of Open Access Journals (Sweden)

    G. Tourón-Alonso

    2009-09-01

    Full Text Available La actual demanda de herramientas y accesorios para maquinarias agrícolas se presenta comofuente creciente de nuevas aplicaciones del acero al Cr-Mn-Si-Ni. Este criterio justifica la práctica detratamientos térmicos, para conseguir distintos valores de propiedades mecánicas, que orienten almaterial hacia las exigencias y circunstancias de aplicaciones concretas. El trabajo tiene comoobjetivo conocer la estructura del acero, heredadas de las transformaciones de fase en diferentesregímenes de tratamiento térmico de revenido, y la correlación entre dicha estructura y suspropiedades de dureza, resistencia a la tracción y resiliencia. Las observaciones al microscopioóptico de las muestras revenidas sugieren, en unos casos, una estructura compuesta por martensitarevenida, en otros, indican la presencia de partículas de ferrita y cementita. Los ensayos de dureza ytracción revelaron una disminución de la dureza y de la resistencia a la tracción con el aumento dela temperatura de revenido. El ensayo de impacto reveló un aumento de la resiliencia con elaumento de la temperatura de revenido, aunque aparecen dos intervalos de temperatura en que laresiliencia disminuye.Palabras claves: revenido, estructura, dureza, resistencia, resiliencia____________________________________________________________________________AbstractSpecimens were tempered after being hardened into oil. Tempered specimens for tension tests,were heated from 200 to 500ºC, in an interval of 100ºC; while, specimens for hardness andresilience tests, were heated from 200 to 550ºC, in an interval of 50ºC. Tempering time, for tensionand resilience tests, depends on specimens’ thickness, while, for hardness tests is 30, 60 and 90minutes. Tempered specimens microstructures at 200 and 300ºC indicate the presence of carbideparticles; it suggests a tempering martensite structure. Tempered specimens microstructures at500ºC indicate the presence of ferrite and cementite particles

  15. Sinterização ultrarrápida por micro-ondas de compósitos particulados PZT/FCO preparados por mistura em ultrassom

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    C. P. Fernandez

    Full Text Available Resumo Pós de Pb(Zr0,53Ti0,47O3 (PZT e Fe2CoO4 (FCO, foram sintetizados separadamente pelo método Pechini e misturados em ultrassom, nas proporções molares 80/20 e 50/50 (PZT/FCO. Os compósitos preparados foram prensados e submetidos à sinterização em forno convencional e sinterização ultrarrápida assistida por micro-ondas. A caracterização estrutural e microestrutural das amostras foram realizadas por difração de raios X e microscopia eletrônica de varredura, respectivamente. Medidas de constante dielétrica em função da temperatura, resistividade elétrica e coeficiente de acoplamento magnetoelétrico foram também realizadas. Os resultados evidenciaram que o método de mistura do PZT com a FCO por ultrassom foi rápido e eficiente, gerando, após sinterização, compósitos particulados com conectividade global (0-3 e distribuição uniforme de grãos da fase ferromagnética (FCO na matriz ferroelétrica (PZT. Da análise estrutural, verificou-se que a sinterização por micro-ondas propiciou um arranjo diferenciado no esquema de conectividade local na amostra (1-3 e (2-3, relacionada com a intensificação dos processos de difusão que ocorrem nesse tipo de sinterização principalmente em sistemas nanométricos. Pelos altos valores de resistividade obtidos, comprovou-se que a integridade das fases foi conservada nos dois métodos de sinterização, sendo mais eficiente na sinterização por micro-ondas, característica que garantiu o comportamento magnetoelétrico em todos os compósitos estudados neste trabalho. Os valores do campo Hmax foram dependentes da concentração da fase ferrita e da sinterização; para a composição 80/20 de 1,4 e 1,9 kOe, e para 50/50 de 3,5 e 3,0 kOe nas amostras sinterizadas por micro-ondas e convencionalmente, compatíveis com a literatura e que confirmaram a integridade das fases constituintes PZT e FCO.

  16. MATERIALES COMPUESTOS DE MATRIZ POLIMÉRICA USADOS PARA EL BLINDAJE DE INTERFERENCIA ELECTROMAGNÉTICA

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    Andrés Orlando Garzón Posada

    2017-01-01

    Full Text Available Este trabajo tiene como propósito revisar el estado del arte en la síntesis y caracterización de materiales de matriz polimérica reforzados con compuestos a base de carbón o ferritas para su uso como materiales atenuadores de interferencia electromagnética (EMI. Recientemente, este tipo de materiales han sido objeto de investigación debido a sus potenciales aplicaciones tecnológicas, economía y de ser además ambientalmente amigables, puesto que polímeros o cauchos reciclados se pueden utilizar para su fabricación. Estos compuestos pueden ser empleados en la producción de blindajes electromagnéticos, transductores, entrega focalizada de medicamentos, marcación de órganos, hipertermia magnética, etc. Para la fabricación de este tipo de materiales compuestos se usan refuerzos particulados, fibras o láminas y como matrices polímeros termoplásticos o termoestables, cauchos sintéticos o naturales. El método de producción de los compuestos (mezcla fundida, métodos químicos, etc. influye en las propiedades eléctricas, magnéticas y electromagnéticas del material obtenido, debido a la relación de aspecto de los refuerzos: compuestos con elevada relación de aspecto de sus refuerzos tendrán mejores propiedades magnéticas, eléctricas y desempeño frente a la interferencia electromagnética. El blindaje electromagnético de estos materiales se cuantifica a través de la efectividad del blindaje (SE o en otros casos a través de la pérdida reflectiva (RL. Una efectividad de blindaje de 30 dB corresponde a 99,9% de atenuación de la radiación electromagnética incidente. En todos los trabajos se comprueba que las propiedades del compuesto dependen de la cantidad y del tipo de refuerzo adicionado a la matriz.

  17. Caracterização química e metalográfica dos aços inoxidáveis de implantes removidos de pacientes Chemical and metallographic characterization of stainless steel in implants removed from patients

    Directory of Open Access Journals (Sweden)

    Elison da Fonseca e Silva

    2011-01-01

    Full Text Available OBJETIVO: Este trabalho estudou a composição química e metalográfica (microestrutura, tamanho de grão, teor de inclusões de aços inoxidáveis austeníticos, desenvolvidos para aplicações como biomateriais, utilizados na fabricação de implantes ortopédicos. MÉTODO: Foram analisados doze implantes removidos de pacientes afetados por quadro inflamatório. As análises químicas foram desenvolvidas pelas técnicas Espectrometria de Emissão Ótica e Microanálise por Dispersão de Energia (EDS e o tamanho de grão foi determinado por microscopia ótica e Microscopia Eletrônica de Varredura (MEV conforme norma ASTM E 1382 97. RESULTADOS: Observou-se que, todos os implantes apresentavam tamanho de grão superior ao recomendado pela norma, constatou-se também a presença de ferrita delta em dez dos doze implantes removidos, que de acordo com a norma ASTM F138-92 não deveriam ser percebidas microscopicamente com um aumento de 100 vezes. CONCLUSÕES: Em oito casos existe forte indicação de que as inflamações foram desencadeadas pela corrosão por pite. Nivel de Evidência III, Revisão sistemática de Estudos .OBJECTIVE: This study examines the chemical and metallographic composition (microstructure, grain size, inclusion content of austenitic stainless steel developed as biomaterials for used in the manufacture of orthopedic implants. METHOD: An analysis was carried out of twelve implants removed from patients affected by inflammation. Chemical analyses were carried out using Optical Emission Spectrometry and Energy Dispersive Microanalysis (EDS, and the grain size was determined by optical microscopy and scanning electron microscopy (SEM according to ASTM Standard E 1382 97. RESULTS: It was observed that all the implants had a larger grain size than is recommended by the Standard. The presence of delta ferrite was also observed in ten of the twelve implants removed, which according to ASTM Standard F138-92, should not be perceived

  18. Ferrites nanoparticles MFe2O4 (M = Ni and Zn: hydrothermal synthesis and magnetic properties

    Directory of Open Access Journals (Sweden)

    Pérez Mazariego, J. L.

    2008-06-01

    Full Text Available MFe2O4 (M = Ni and Zn nanoparticles were prepared by the hydrothermal method. The obtained samples were characterized by X-ray and electron diffraction, Scanning and Transmission Electron Microscopy and Mössbauer spectroscopy. The transmission images show homogeneous shape and particle size ranging from 10 to 40 nm, depending on the nature of the M cation. Mössbauer spectroscopy yields to a ratio of occupancy between the A and B sites of 0.7 in the case of NiFe2O4 oxide. DC magnetization (2-300 K measurements reveal a superparamagnetic behaviour for the ZnFe2O4 sample with a blocking temperature of 20 K. By contrast, in the case of the NiFe2O4 ferrite the blocking temperature appears to be above 300 K and at lower temperature, it shows a ferrimagnetic behaviour arising from the superexchange interactions that take place in this inverse spinel. Mössbauer spectroscopy results confirm the bulk magnetic measurements.Se han preparado mediante el método hidrotermal nanopartículas de ferritas MFe2O4 (M = Ni, Zn. Las muestras obtenidas fueron caracterizadas mediante difracción de rayos X y electrones, microscopía electrónica de transmisión y barrido y espectroscopia Mössbauer. Las imágenes de transmisión muestran partículas de forma y tamaño homogéneo de 10 a 40 nm según la naturaleza del catión M. La espectroscopia Mössbauer revela una relación de ocupación entre los sitios A y B por los átomos de hierro de 0.7 en el caso del óxido NiFe2O4. Las medidas de magnetización DC (2 – 300 K muestran un comportamiento superparamagnético para la muestra ZnFe2O4 con una temperatura de bloqueo de 20 K. En el caso de las nanopartículas de NiFe2O4 la temperatura de bloqueo parece estar por encima de los 300 K mostrando por debajo de la misma, comportamiento ferrimagnético provocado por las interacciones de superintercambio que tienen lugar en esta espinela inversa. Los resultados de espectroscopia Mössbauer confirman los datos de las

  19. Influencia de los tratamientos térmicos en el comportamiento frente al desgaste por abrasión de una fundición de grafito esferoidal obtenida mediante adición de boro

    Directory of Open Access Journals (Sweden)

    Varela, A.

    2008-08-01

    Full Text Available By adding boron to the liquid metal, it is possible to obtain spheroidal graphite cast iron without any need for special inoculants. The boron may be in metallic form; alternatively, borax, ferroboron, boron carbonate or borocalcium can be used. These alloys as cast present a pearlite matrix with more or less spheroidal graphite, which is usually edged in ferrite that has markings in the shape of bull’s eye. With normalising, the ferrite edges are eliminated. Thus, a pearlite matrix is achieved. Annealing results in an entirely ferrite matrix; quenching and tempering produce a tempered martensite matrix.This study measures the behaviour under wear of this alloy as cast, normalised, annealed, quenched and tempered . A “pin on disk” test is employed; load and speed conditions, as well as the pin type, are kept constant. Moreover, wear is calculated through weighing, and the variation for the friction coefficient is determined in each case.

    Mediante la adición de boro al metal líquido, bien en forma metálica o en forma de bórax, ferroboro, carburo de boro o boruro cálcico, se pueden obtener fundiciones de grafito esferoidal sin necesidad de inoculantes especiales. Estas fundiciones en estado bruto de colada presentan una matriz perlítica con grafito más o menos esferoidal que suele estar orlado de ferrita formando ojos de buey. Por tratamiento térmico de normalizado, se consigue eliminar la orla ferrítica y tener una matriz enteramente perlítica. Por recocido, se puede obtener una matriz enteramente ferrítica y por temple y revenido una matriz de martensita revenida. En el presente trabajo se mide el comportamiento frente al desgaste abrasivo de la aleación indicada, en estado bruto de colada, normalizado, recocido y bonificado, utilizando el ensayo pin on disk, manteniendo fijas las condiciones de ensayo en cuanto a carga, velocidad y tipo de pin, calculando el desgaste producido por pesada. También, se

  20. Formación de fase sigma en uniones soldadas de acero inoxidable súper dúplex fundido

    Directory of Open Access Journals (Sweden)

    Garin, J. L.

    2011-08-01

    Full Text Available This paper decribes the microstructural characteristics of weldments of cast super duplex stainless steel (J93404, being subjected to annealing processes to induce formation of sigma-phase at high temperatures. The influence of heating time at 1073 K, 1123 K and 1173 K upon precipitation of sigma in the heat affected zone, base metal and fusion zone of the weldments was analyzed. The experimental results revealed the formation of this intermetallic compound throughout decomposition of the ferritic phase into austenite and sigma. At earlier stages of the transformation the phase rapidly nucleates and growth along the ferrite-austenite grain boundaries, and then massively advances towards the bulk of the ferritic zone with greater effectiveness as temperature increases. The formation of sigma-phase in all weldments resembles the Johnson-Mehl-Avrami’s mechanism stated for nucleation and growth.

    El presente trabajo describe las características microestructurales de uniones soldadas de acero súper dúplex fundido (J93404, al ser sometidas a procesos de recocido para inducir la formación de fase sigma a altas temperaturas. Se analizó la influencia del tiempo de calentamiento a 1.073 K, 1.123 K y 1.173 K sobre la precipitación de fase sigma en la zona afectada térmicamente, metal base y zona de fusión de los conjuntos soldados. Los resultados experimentales evidenciaron la formación de este compuesto intermetálico por descomposición de la fase ferrítica en austenita y sigma. Al comienzo de la transformación la fase nuclea y crece rápidamente en los bordes de grano austenita-ferrita, extendiéndose luego masivamente hacia el seno de la zona ferrítica, con mayor efectividad en términos del aumento de la temperatura de proceso. La formación de sigma en todas las uniones soldadas obedece a un mecanismo de nucleación y crecimiento del tipo Jonson-Mehl-Avrami.

  1. Estudio del daño por hidrógeno en uniones soldadas de un acero API 5L X52

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    Réquiz, R.

    2008-04-01

    Full Text Available The main objective of the present investigation was to study the susceptibility to hydrogen damage on a type API 5L X52 steel welded by electrical resistance. Several techniques, such as hydrogen permeation and cathodic charging were used. The metallic material was characterized using SEM and TEM. The base metal microstructure was very similar to that one corresponding to the welded area. This microstructure was mainly comprised by ferrite and perlite, differing only in the grain size. Therefore, the susceptibility to hydrogen damage was similar in both cases. It is worth mentioning that the welded area has very small dimensions. Indeed, the fusion zone is only 5 mm wide while the heat affected zone is 1 mm wide. The hydrogen damage observed was mainly in the form of blisters, which were associated to the presence of aluminum rich inclusions. Also, it was noticed partial inclusion dissolution and some matrix attack adjacent to the inclusions.

    En la presente investigación se estudió la susceptibilidad al daño por hidrógeno en un acero API 5L X52 soldado por resistencia eléctrica. Para ello, se emplearon técnicas de permeación y de carga catódica de hidrógeno. El material fue caracterizado mediante microscopía electrónica de barrido y de transmisión. La susceptibilidad al daño por hidrógeno fue similar tanto en el metal base como en el cordón de soldadura. Este comportamiento se vincula a la microestructura homogénea constituida por perlita y ferrita, que presentan ambos, aun cuando existen diferencias en el tamaño de grano. El cordón de soldadura tenía dimensiones muy pequeñas, donde la zona de fusión y la afectada por el calor poseen espesores de 5 mm y 1 mm, respectivamente. El daño inducido por hidrógeno se presentó en forma de ampollas en la superficie del material, asociado, principalmente, a la presencia de inclusiones globulares y semiglobulares ricas en aluminio. Además, se manifestó una disoluci

  2. Evaluación de diferentes tipos de barnices en la protección de electrodos para la soldadura subacuática//Evaluation of different types of varnishs to protect underwater welding electrodes

    Directory of Open Access Journals (Sweden)

    Manuel Rodríguez-Pérez

    2012-05-01

    Full Text Available El artículo tiene como objetivo evaluar  las posibilidades de empleo de diferentes tipos de barnices como impermeabilizantes para los electrodos del tipo AWS E 6013, cuando se realiza la soldadura  en condiciones subacuática mojada. Los barnices evaluados son el Vinílico, Marítimo, base Poliuretano y una nueva variante base Isopor. Los métodos de evaluación incluye el comportamiento de la resistencia mecánica que le confiere al revestimiento a cada uno de los barnices, el agua adsorbida y el tipo de estructura en el cordón, utilizando microscopía óptica convencional. En este aspecto, la estructura en todos los cordones realizados con el electrodo E 6013, independientemente del impermeabilizante utilizado es similar, caracterizada por ferrita primaria o de contorno de grano y del tipo Widmanstätten, sin embargo, se determinó, que el impermeabilizante base Isopor, garantiza una mejor protección del electrodo en cuanto a la cantidad de agua adsorbida y adherencia del revestimiento.Palabras claves: soldadura subacuática, impermeabilizante, electrodos._______________________________________________________________________________The article aims to assess the potential use of different types of paints and waterproofing materials for the electrodes of type AWS E 6013, when performing underwater welding in wet conditions. The coatings evaluated are Vinyl, Maritime, polyurethane base and a new variant Isopor base. Evaluation methods include the behavior of the mechanical strength to the coating gives each of the varnishes, the adsorbed water and the type of structure in the welds, using conventional microscopy. In this sense, the structure in all the welds made with the electrode E 6013, regardless of waterproofed used is similar, characterized by primary or ferrite grain boundary and Widmanstätten type, however, it was determined that the base waterproofing Isopor, guarantees better protection of the electrode in terms of the amount of

  3. Avaliação da microestrutura e propriedades mecânicas de metais de solda obtidos por processos de soldagem manual e automatizado utilizado na soldagem de aço API 5L X80 Evaluation of microstructure and mechanical properties of weld metals obtained by manual and automated welding process used in the welding of API 5L X80 steel

    Directory of Open Access Journals (Sweden)

    Siderley Fernandes Albuquerque

    2011-12-01

    Full Text Available O objetivo do trabalho foi avaliar as características da zona termicamente afetada (ZTA e a microestrutura e propriedades mecânicas de metais de solda de juntas soldadas do aço API 5L X80, obtidos para quatro diferentes procedimentos de soldagem utilizando processos manuais e automatizados. Para isto, chapas do referido aço foram soldadas por processo manual ao Arco Elétrico com Eletrodo Revestido (SMAW, utilizando 473 e 673 K como temperaturas de interpasses e o eletrodo celulósico AWS E8010-G como consumível; por processo ao Arco Elétrico com Arame Tubular (FCAW robotizado, utilizando o arame AWS E71T- 1C como metal de adição e argônio com 25%CO2 como gás de proteção; por processo a Arco Elétrico com Eletrodo de Tungstênio (GTAW mecanizado na raiz da solda, usando o arame ER70S-3 e argônio como gás de proteção. As análises microestruturais foram relacionadas com os resultados de ensaios de impacto Charpy nos metais de solda e com os perfis de microdureza Vickers ao longo da junta soldada. Os resultados indicaram maiores percentuais de Ferrita Acicular e maiores valores de resistência ao impacto nos metais de solda e uma menor extensão e granulometria da ZTA, associado ao procedimento de soldagem utilizando processo automatizado com maior velocidade de soldagem.The objective of this work was to evaluate the heat affected zone characteristics and weld metals microstructure and mechanical properties of API 5L X80 steel welded joints, obtained for four different welding procedures using manual and automated processes. For this, plates of this steel were welded by manual Shielded Metal Arc Welding (SMAW process with interpasses temperatures of 473 e 673 K, and using AWS E8010-G electrode as filler metals; robotized Flux Cored Arc Welding (FCAW process, using AWS E71T-1C wire and Ar25%CO2 as consumable and mechanized Gas Tungsten Arc Welding (GTAW process, for the root pass using AWS ER70S-3 and Ar as consumable .The

  4. Evaluation of cold crack susceptibility on HSLA steel welded joints

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    Silverio-Freire Júnior, R. C.

    2003-04-01

    únicamente en la zona de metal de aporte con una combinación de los valores de dureza superiores a 230 Hv y con porcentajes de ferrita acicular superiores al 93 %, obtenidos sin precalentamiento. Además de ello, en las chapas de mayor espesor, se obtuvo una mayor susceptibilidad a la fisuración en frío, aunque presentasen menor valor de carbono equivalente.

  5. Heterogeneous Materials I and Heterogeneous Materials II

    International Nuclear Information System (INIS)

    Knowles, K M

    2004-01-01

    In these two volumes the author provides a comprehensive survey of the various mathematically-based models used in the research literature to predict the mechanical, thermal and electrical properties of hetereogeneous materials, i.e., materials containing two or more phases such as fibre-reinforced polymers, cast iron and porous ceramic kiln furniture. Volume I covers linear properties such as linear dielectric constant, effective electrical conductivity and elastic moduli, while Volume II covers nonlinear properties, fracture and atomistic and multiscale modelling. Where appropriate, particular attention is paid to the use of fractal geometry and percolation theory in describing the structure and properties of these materials. The books are advanced level texts reflecting the research interests of the author which will be of significant interest to research scientists working at the forefront of the areas covered by the books. Others working more generally in the field of materials science interested in comparing predictions of properties with experimental results may well find the mathematical level quite daunting initially, as it is apparent that the author assumes a level of mathematics consistent with that taught in final year undergraduate and graduate theoretical physics courses. However, for such readers it is well worth persevering because of the in-depth coverage to which the various models are subjected, and also because of the extensive reference lists at the back of both volumes which direct readers to the various source references in the scientific literature. Thus, for the wider materials science scientific community the two volumes will be a valuable library resource. While I would have liked to see more comparison with experimental data on both ideal and 'real' heterogeneous materials than is provided by the author and a discussion of how to model strong nonlinear current--voltage behaviour in systems such as zinc oxide varistors, my overall

  6. Adaptive settings of distance relay for MOV-protected series compensated line with distributed capacitance considering wind power

    Science.gov (United States)

    Sivov, Oleg Viktorovich

    Series compensated lines are protected from overvoltage by metal-oxide-varistors (MOVs) connected in parallel with the capacitor bank. The nonlinear characteristics of MOV devices add complexity to fault analysis and distance protection operation. During faults, the impedance of the line is modified by an equivalent impedance of the parallel MOV/capacitor circuit, which affects the distance protection. The intermittent wind generation introduces additional complexity to the system performance and distance protection. Wind variation affects the fault current level and equivalent MOV/capacitor impedance during a fault, and hence the distance relay operation. This thesis studies the impact of the intermittent wind power generation on the operation of MOV during faults. For the purpose of simulation, an equivalent wind farm model is proposed to generate a wind generation profile using wind farm generation from California independent system operator (ISO) as a guide for wind power variation to perform the study. The IEEE 12-bus test system is modified to include MOV-protected series capacitor and the equivalent wind farm model. The modified test system is simulated in the MATLAB/Simulink environment. The study has been achieved considering three phase and single line to ground (SLG) faults on the series compensated line to show the effect of wind variation on the MOV operation. This thesis proposes an adaptive setting method for the mho relay distance protection of series compensated line considering effects of wind power variation and MOV operation. The distributed parameters of a transmission line are taken into account to avoid overreaching and underreaching of distance relays. The study shows that variable wind power affects system power flow and fault current in the compensated line during a fault which affects the operation of MOVs for different fault conditions. The equivalent per-phase impedance of the MOV/capacitor circuit has an effect on the system operation

  7. Preparation and electrical properties of heterostructures nCdSe-pInAs

    International Nuclear Information System (INIS)

    Gospodinov, M.; Dobreva, S.

    1993-01-01

    Single crystals of InAs n-type produced by the Czochralski method have been used as a base material for substrates; CdSe in powder form with a purity 99.999% - as a source for epitaxy. The optimal layers growth conditions are obtained by a series of experiments. Best results are obtained at: source temperature 650-680 o C, substrate temperature 550-570 o C, difference between the source and substrate temperature 100-110 o C, hydrogen flow rate 1 l/h, growth time 1-8 h, distance between the source and the substrate 2 mm. The voltage-current characteristics of an iso type heterojunction nInAs [111] - nCdSe [0001] are measured at liquid nitrogen temperature. Non-symmetry of the characteristics are observed which distinguishes them from those of varistors. The current/voltage dependence in forward direction is different from the exponential one, whereby in reverse direction of the voltage it is almost exponential. The rectifying properties of the heterojunction in forward voltage mode are explained. It is shown that the heterojunction nInAs-nCdSe appears like a p-n heterojunction. For higher reverse voltages a weak breakdown is observed. The mechanism of this breakdown is explained by the tunneling of electrons from the conduction band of InAs towards the conduction band of CdSe as well as by surface leaking effects. The barrier in CdSe is determined by measurement of the voltage-capacity characteristics. It is shown that the capacity changes only in the reverse direction which means that the barrier is located on the side of CdSe. It is assumed that due to the very small difference in the lattice constants of CdSe and InAs [0.033], the density of the states on the boundary is relatively low (10 -11 - 10 -12 ) cm -2 . So, the boundary states exercise a weak influence on the energetic zone diagram. 3 figs., 9 refs

  8. Cinética de sinterização para sistemas à base de SnO2 por taxa de aquecimento constante Sintering kinetics for SnO2-based systems by constant heating rate

    Directory of Open Access Journals (Sweden)

    S. M. Tebcheran

    2003-04-01

    Full Text Available Cerâmicas densas de óxido de estanho são muito promissoras para aplicações tecnológicas como varistores e cadinhos de fusão de vidros corrosivos. Vários aditivos em pequenas concentrações podem ser usados como promotores de densificação desta cerâmica. No presente trabalho foram estudadas as cinéticas de sinterização do óxido de estanho, considerando o efeito de atmosfera de sinterização e da concentração de MnO2. Sistemas de SnO2-MnO2 foram preparados pelo método dos precursores poliméricos e os pós obtidos foram caracterizados por medidas de área de superfície específica (BET e por difração de raios X. Pós de SnO2 com concentrações variadas de MnO2 foram compactados de forma cilíndrica e sinterizados em dilatômetro com taxa de aquecimento constante e atmosferas controladas. Amostras sinterizadas foram caracterizadas por microscopia eletrônica de varredura. A influência da atmosfera (argônio, ar ou CO2 como também das concentrações de MnO2 na cinética de sinterização foram determinadas. Os dados cinéticos da retração linear foram analisados pelos modelos cinéticos para a fase inicial de sinterização (Woolfrey e Bannister como também para a sinterização global (Su e Johnson permitindo determinar a energia de ativação aparente. De acordo com a determinação da curva mestre de sinterização, a energia de ativação aparente de todo o processo de sinterização foi determinada bem como sua dependência com a atmosfera e concentrações de manganês. Baseado nestes valores e no expoente n, pode-se determinar, pela equação clássica de crescimento de grão, que o mecanismo de sinterização mais provável é de difusão por contorno de grão com redistribuição superficial controlando a cinética de sinterização.Dense tin oxide based ceramics are very promising for technological applications such as varistors and crucibles for melting very corrosive glasses. Several additives have been used

  9. Microestructura y propiedades mecánicas de dos aceros para herramientas con ultra alto contenido de boro

    Directory of Open Access Journals (Sweden)

    Jiménez, J. A.

    1998-05-01

    Full Text Available In the present work, two selected tool steels have been modified by a boron addition of 0.5 and 1 mass %. Both steels were processed by powder metallurgy methods, including argon atomization and hot isostatic pressing. The Consolidated materials presented a microstructure consisting of a fine and homogeneous distribution borocarbides M23(C,B6 in a ferrite-martensite matrix. No changes are observed in the microstructure after deformation by compression-strain-rate-change tests at temperatures ranging from 700 to 1,100 °C. For the Fe-lB-lC steel, a stress exponent of 4.5 was obtained, that suggests that slip creep is the controlling deformation mechanism. On the other hand, a stress exponent between 2 and 3 was obtained for the Fe-0.5B-1.5C steel that suggests that grain boundary sliding is the controlling deformation mechanism. In both cases, the activation energy for creep was related to the activation energy for iron self-diffusion.

    En el presente trabajo se han modificado dos aceros para herramientas convencionales por la presencia de un contenido de boro entre 0,5 y 1 % en masa. Ambos aceros se procesaron por la ruta pulvimetalúrgica, incluyendo atomización por argón y compactación isostática en caliente. El material compactado presentó una microestructura caracterizada por una distribución de partículas de borocarburos M23(C,B6 fina y homogénea en una matriz de ferrita-martensita. Esta microestructura permanece prácticamente inalterada tras los ensayos de cambios en la velocidad de deformación durante el ensayo de compresión a temperaturas entre 750 y 1.000 °C. En el caso del acero Fe-lB-lC se obtuvo un valor para el exponente de la tensión de 4,5, que sugiere que la deformación plástica está controlada por un mecanismo de fluencia por movimiento de dislocaciones. Por otro lado, para el acero Fe-0,5B-1,5C, se obtuvieron valores para el exponente de la tensión comprendidos

  10. Caracterización dinámica de los cambios microestructurales en barras de aceros dúplex SAF 2205 utilizando la dimensión de información

    Directory of Open Access Journals (Sweden)

    Rodríguez, Edda

    2014-03-01

    Full Text Available This study evaluates the ultrasonic signals behavior of a duplex stainless steel SAF 2205 (UNS S31803 after aging treatments at 875 and 950 °C. The first treatment promotes the precipitation of the sigma phase and the second, its dissolution. The microstructural evaluation was carried out by optical microscopy. The results showed an increase of the sigma phase fraction and the secondary austenite with the time of aging treatment at 875 °C. On the other hand, increasing the time of treatment at 950 °C promotes a reduction of the sigma phase and the corresponding increase of the ferrite phase fraction. The study proposed to evaluate in the dynamical system field the influence of microstructural phases in the signals behavior and their dependence on the energy losses occurring in system during heat treatment, by deterministic chaos theory. To accomplish characterization, algorithm employs the representation of dynamic phase space and the information dimension estimate. The results show a higher correlation between the information dimension and the attenuation coefficient in comparison with the phase fractions. However, the efficiency of this type of study will depend on the frequency selected for the evaluation of the material.En el presente estudio se evalúa el comportamiento dinámico de las señales ultrasónicas de muestras de acero dúplex SAF 2205 (UNS31803, sometidos a tratamientos de envejecimiento a 875 y 950 °C. En el primer tratamiento se promueve la precipitación de la fase sigma y en el segundo su disolución. Los resultados obtenidos por microscopía óptica indican que la cantidad relativa de la fase sigma aumenta progresivamente con el tiempo de envejecimiento a 875 °C, observándose la transformación de la fase ferrita en fase sigma y en austenita secundaria. Por otra parte, a medida que se aumenta el tiempo de tratamiento a 950 °C, se observa una reducción del porcentaje de fase sigma y un aumento de la fase ferr

  11. Influência da refusão por plasma na microestrutura de um revestimento Fe-Mn-Cr-Si depositado por aspersão térmica arco elétrico sobre aço inoxidável ASTM A743-CA6NM Influence of plasma remelting on the microstructure of Fe-Mn-Cr-Si arc thermal spray coating deposited on ASTM A743-CA6NM stainless steel

    Directory of Open Access Journals (Sweden)

    Anderson Geraldo Marenda Pukasiewicz

    2012-03-01

    Full Text Available ASTM A743-CA6NM é um aço inoxidável martensítico muito utilizado na fabricação de turbinas hidráulicas devido a sua elevada tenacidade, entretanto apresenta restrições com relação à regiões recuperadas por soldagem. Diferentes técnicas de deposição tem sido aplicadas com o intuito de reduzir ou eliminar a tensão residual. A deposição de revestimentos resistentes a cavitação é outra forma importante de aumentar a vida útil destes componentes. O objetivo deste trabalho é avaliar a influência do tipo e intensidade de corrente de refusão por plasma na microestrutura, composição química e microdureza de um revestimento Fe-Mn-Cr-Si resistente a cavitação depositado por aspersão térmica arco elétrico sobre aço ASTMA743-CA6NM. Observou-se que a adoção de menores valores de corrente média, assim como a utilização de corrente pulsada reduziram a formação de ferrita δ e a espessura final da ZTA, possibilitando a formação do revestimento com menores alterações na microestrutura do metal base. Verificou-se que a microestrutura e microdureza dos revestimentos refundidos não se mostraram muito sensível a variações na diluição do metal base. A utilização de corrente contínua promoveu um alinhamento da estrutura dendrítica no sentido da movimentação da tocha, entretanto este comportamento não foi observado em revestimentos refundidos com corrente pulsada.ASTM A743-CA6NM martensitic stainless steel have been used in hydraulic turbines manufacturing, but show some restrictions in welded recovered areas. Different techniques have been applied in order to reduce or eliminate residual stress, with life increase. The deposition of cavitation resistant coatings is another important way to increase the service life of these components. The objective of this study is evaluate the influence of type and intensity of plasma remelting current on the microstructure, chemical composition and microhardness of the Fe

  12. Physical metallurgy of laser surface melted plastic mould steels: a case study

    Directory of Open Access Journals (Sweden)

    Colaço, R.

    1998-04-01

    martensita. Aunque la fase en equilibrio sería ferrita 8, la formación de austenita primaria está favorecida cinéticamente, por lo que esta fase tiende a ser predominante a las altas velocidades de solidificación que se consiguen en los tratamientos láser. Se ha observado que la fracción de volumen de austenita retenida depende de manera crítica de los parámetros del procesado con láser , así como que la microestructura puede cambiar de martensita a austenita en función de dichos parámetros. En la fusión superficial del acero DIN X42Cr13 se obtiene un pico de endurecimiento secundario después del tratamiento con láser a 600°C, mientras que, para los tratamientos térmicos convencionales éste aparece a 500°C, debido a la presencia de gran cantidad de austenita retenida. El endurecimiento secundario se debe a la transformación de la austenita retenida en martensita y a la precipitación de carburos del tipo M7C3 y M23C6.

  13. Efecto de la adición de Gd2O3 sobre las propiedades magnéticas de hexaferritas de estroncio

    Directory of Open Access Journals (Sweden)

    Sánchez Ll., J. L.

    1999-12-01

    Full Text Available The hexaferrites (AFe12O19, A = Ba, Sr have been used since years ago. Because of their low cost these materials continue in the market and they have not been substituted for other powerful magnets. The partial substitution of metallic elements or the use of additives in small proportions have been widely used for industrial processes in order to improve magnetic properties or the sintering process. Efforts had been made to determinate the effect of an important number of diamagnetic or paramagnetic cations on the microstructure and magnetic properties of the hexagonal ferrites. Previous studies have reported a remarkable increase in the coercitive field of the hexaferrites of barium with the substitution partial of that by La, Lu, Sm, Nd and Gd. In the present research a structural and magnetic study of sintered permanent magnets with the general formula Sr1-XGdX/2NaX/2Fe12O19 (0.00≤ X ≤0.10 was made. The samples were characterized by X-ray diffraction, vibrating sample magnetometry, scanning electron microscopy and elemental analysis (EDAX. The dependency of the densification, the medium grain size, the cells parameters and the magnetic properties with the gadolinium oxide content is discussed.Las hexaferritas (AFe12O19, A = Ba, Sr se vienen utilizando desde hace varios años; debido a su bajo costo dominan el mercado y no han sido sustituidas por imanes permanentes más potentes. La sustitución parcial de los elementos metálicos o la utilización de aditivos en pequeña proporción ha sido ampliamente utilizada en la industria con el objeto de mejorar las propiedades magnéticas o facilitar el proceso de sinterización. Se han dedicado esfuerzos importantes para determinar el efecto de un número importante de iones diamagnéticos y paramagnéticos sobre la microestructura y las propiedades magnéticas de las ferritas hexagonales. Trabajos previos reportaron un aumento notable del campo coercitivo en hexaferritas de bario con substituci

  14. Obtainment of Hg-free Mn/Zn solutions from spent alkaline batteries; Obtencion de soluciones de Mn/Zn libres de Hg provenientes de pilas alcalinas gastadas

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Nicolas, L.; Espinosa-Ramirez, I. [Instituto Politecnico Nacional, UPALM, Mexico, D.F. (Mexico)]. E-mail: lepeni@hotmail.com; Aguilar, M. [Instituto de Fisica, UNAM, Mexico, D.F. (Mexico); Palacios-Beas, E. [Instituto Politecnico Nacional, UPALM, Mexico, D.F. (Mexico)

    2009-09-15

    a la naturaleza, terminando en basureros al aire libre o contenedores donde son incinerados, contaminando el ambiente, los suelos y los mantos acuiferos del planeta. Por lo anterior, en el presente trabajo se estudia la obtencion de soluciones de Mn y Zn (Mn/Zn {>=} 1) libres de Hg a partir de pilas alcalinas gastadas, para su utilizacion en la sintesis de ferritas (Mn,Zn)Fe{sub 2}O{sub 4} por via humeda. Se analiza el efecto del medio disolvente (H{sub 2}SO{sub 4}/H{sub 2}O{sub 2}, HCl y HCl/NO{sub 3}), la temperatura y el tiempo sobre el porcentaje de disolucion de los metales presentes en el material electrodico, utilizando espectroscopia de absorcion atomica (AA) y difraccion de rayos X (DRX) para la caracterizacion. Los resultados de la investigacion indican que las mejores condiciones de disolucion son MD=H{sub 2}SO{sub 4}/H{sub 2}O{sub 2}, T=50 grados centigrados y t =30 min, donde se obtiene 94.1 y 90.7 % (w/w) de Mn y Zn respectivamente, con Mn/Zn = 1.51. Se determino que el contenido de mercurio es 3.91%, superior al declarado en las especificaciones de las pilas, que se recupera mediante disolucion con HCl/HNO{sub 3} en el solido remanente.

  15. Estudo da soldagem de tubos de aço inoxidável duplex e superduplex na posição 5G Study of the welding of duplex and superduplex stainless steel pipes in the 5G position

    Directory of Open Access Journals (Sweden)

    Pedro Ivo Guimarães de Vasconcellos

    2010-09-01

    Full Text Available Os aços inoxidáveis duplex e superduplex possuem uma microestrutura austeno-ferrítica com fração média de cada fase de cerca 50%. A microestrutura duplex é responsável pelas excelentes propriedades mecânicas, especialmente o limite de escoamento e a tenacidade, e pela elevada resistência a corrosão por pites e sob tensão em meios contendo cloretos. A soldagem destes aços é frequentemente uma operação crítica. Neste trabalho, um tubo de superduplex SAF 2207 foi soldado pelo processo TIG (GTAW no passe de raiz e eletrodo revestido (SMAW nos passes de enchimento, e um tubo de duplex SAF 2205 foi todo soldado pelo processo GTAW. A microestrutura do metal base, zona afetada termicamente (ZTA e metal de solda foi caracterizada e quantificada. As propriedades de tenacidade, resistência a corrosão e composição química foram avaliadas e correlacionadas. Os valores de tenacidade ao impacto Charpy-V foram considerados adequados. Não foi observada a precipitação de intermetálicos, carbonetos e nitretos. O melhor resultado no teste de corrosão da junta soldada de aço inox superduplex, comparado ao duplex, foi atribuído ao baixo teor de ferrita delta na solda e ZTA, e composição química da solda enriquecida em Cr, Mo, W e N.The duplex and superduplex stainless steels have an austenitic-ferritic microstructure with an average fraction of each phase of approximately 50%. This duplex microstructure is responsible for the excellent mechanical properties, specially the yield strength and toughness, and for the improved pitting and stress corrosion cracking resistance in chloride environments. Welding of these steels is often a critical operation. In this work, a superduplex stainless steel SAF 2507 pipe was welded by the GTAW process in the root pass and by SMAW process on filler passes, and one pipe of duplex SAF 2205 was entirely welded by the GTAW process. The microstructure of the base metal, heat affected zone (HAZ and weld

  16. Estudo do processo de fabricação de tubos flexíveis de aço inoxidável duplex UNS 32304 utilizados na indústria de petróleo e gás Study of the manufacturing process of UNS 32304 flexible pipes for the oil and gas industry

    Directory of Open Access Journals (Sweden)

    Ida Paula Gusmão de Oliveira

    2013-03-01

    Full Text Available A principal característica dos aços inoxidáveis duplex é o equilíbrio entre as fases austenita e ferrita, que garantem ao material melhores índices de resistências à corrosão e mecânica. No entanto, durante o processo de soldagem, ocorrem modificações estruturais, principalmente no balanço destas fases. Este desbalanceamento, em função dos níveis de solicitações mecânicas, pode levar tais regiões soldadas ao colapso. No intuito de minimizar o desequilíbrio das fases na região soldada, diversas técnicas são utilizadas, tais como inserção de metal de adição com elementos austenitizantes, uso de gás de proteção com nitrogênio ou, em outros casos, controle pós soldagem. Buscou-se identificar o verdadeiro efeito dos parâmetros de soldagem e do tratamento térmico especificado pela literatura em situações de campo. Através de uma avaliação temporal, observando uma linha de produção de tubulação flexível de aço inoxidável duplex UNS 32304 durante três anos, utilizando-se de procedimentos convencionais de soldagem com e sem a utilização de tratamento térmico foram observadas as falhas por fratura na zona termicamente afetada (ZTA. Foi utilizado um indutor localizado para o tratamento térmico, gerando um intenso fluxo de calor que promoveu temperaturas da ordem de 1000 ºC a altíssimas taxas de subida e descida, conforme estabelecem algumas literaturas.The main characteristic of duplex stainless steels is the balance between ferrite and austenite phases, wich ensures to such material the best levels of corrosion and mechanical resistance. However, during the welding process, structural modifications occur, especially with regard to the balance of these phases. This imbalance, depending on the levels of mechanical stress, may lead welded regions to collapse. In order to minimize the imbalance of the phases in the welded steel, several techniques are used, such as the insertion of filler metal with

  17. Brasagem dos aços inoxidáveis duplex 'baixa liga' UNS S32101, UNS S32304 e superduplex UNS S32750 com metal de adição AWS A5.3 tipo BNi-7 (Ni-Cr-P

    Directory of Open Access Journals (Sweden)

    Dany Michell Andrade Centeno

    2013-12-01

    Full Text Available Os aços inoxidáveis duplex, devido à sua resistência à corrosão, têm uma grande aplicação em diversos segmentos industriais, onde a resistência à corrosão é uma propriedade requerida. Por terem resistência mecânica superior aos aços inoxidáveis ferríticos e austeníticos convencionais, podem produzir equipamentos mais leves. Quando ciclados termicamente, estes aços podem ter suas propriedades alteradas, principalmente quando se emprega processos de junção, como a brasagem, e quando ocorre o desbalanceamento da fração volumétrica ferrita/austenita. O objetivo deste trabalho é caracterizar a brasagem de aços inoxidáveis duplex 'baixa liga' e superduplex, verificando o efeito da folga e do tempo de brasagem na formação de intermetálicos contínuos no interior da junta brasada. Neste trabalho foram brasados, em forno continuo com atmosfera de hidrogênio, corpos-de-prova de aço inoxidável duplex UNS S32101, UNS S32304 e UNS S32750 com a adição para brasagem BNi-7 (Ni-Cr-P, na temperatura de 1100ºC, por tempos de 12 min e 32 min, utilizando-se folgas das juntas de 0,0 e 0,3 mm, seguidos de resfriamento em forno. Os corpos de prova foram caracterizados utilizando-se microscópio óptico, microscópio eletrônico de varredura com EDS e difração de raios X. Os resultados mostraram que a melhor condição para a brasagem em forno empregado foi a brasagem com a folga de 0,0 mm. Ambas as folgas apresentaram microestruturas variadas, porém a folga de 0,0 mm mostrou a presença de uma fase contínua CFC (cúbica de face centrada, rica em níquel, que é denominada, frequentemente, de γ-Ni. Para folgas de 0,3 mm, forma-se uma região eutética contínua no centro da junta, que pode prejudicar as propriedades mecânicas da mesma. Esta região é composta de fases intermetálicas ricas em fósforo. Foram observadas precipitações de fase sigma no metal de base no AID UNS S35750, nas condições de brasagem estudadas.

  18. Mechanical Properties of Photovoltaic Silicon in Relation to Wafer Breakage

    Science.gov (United States)

    Kulshreshtha, Prashant Kumar

    the surface/edge micro-cracks (i.e. sources of crack initiation). The low load (real decorated multi-crystalline grain boundary. We found that Fe precipitates harden the undecorated GB structure, whereas Cu precipitates introduce dislocation-induced plasticity to soften it. Aluminum Schottky diodes have been evaporated on the DSB samples to sensitively detect the instantaneous current response from the phase-transformed Si under nanoindenter tip. The impact of metallic impurity and their precipitates on characteristic phase transformations (i.e. pop-in or pop-out) demonstrate that scattered distribution of large Cu-precipitates (upto 50 nm) compresses Si-lattice to facilitate Si-XII/III formations, i.e. high pressure ductile phases. Sweeping voltage measurements at a given load determine that Si lattice has to be stressed beyond 1 mN to complete the Si-I (semiconducting) to Si-II (ohmic) phase changes. Above 1 mN load DSB sample has a varistor-like behavior due to higher grain-boundary resistance from interfacial states. The precipitate defect structure stimulated stresses at the bulk Si lattice or grain boundary modify the rate of elastic energy release at the crack-tip and associated phase change and hardness values in response to external loading. The systematic approach in this thesis elucidates that the interfacial surface area between Si-lattice and precipitate plays pivotal role in defining extent of stresses in the silicon, i.e. smaller precipitates in higher densities are severe than few larger volume precipitates. The finding of high-pressure ductile phase formation during loading of compressed silicon structure has been suggested to PV industry as a prospective candidate for reducing the wafer breakage and allowing larger handling stresses.

  19. A 900-channel coincidence pulse-amplitude analyser; Selecteur d'amplitudes d'impulsions a coincidence a trois dimensions; Devyatisotkanal'nyj amplitudnyj analizator impul'sov sovpadeniya; Analizador de amplitud de impulsos de coincidencia con 900 canales

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, T K; Robinson, L B [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

    1962-04-15

    , les huit de la distribution A definissent huit groupes de 100 canaux pour les distributions B. En effet, on aura dans ce cas un analyseur a 100 canaux pour la distribution A et huit analyseurs distincts a 100 canaux, sur lesquels B peut etre dirige. Le memoire decrit les circuits de base du codeur et la logique de la memoire et de l'element . (author) [Spanish] Se describe un analizador proyectado para estudios de correlacion entre las distribuciones de amplitudes de impulsos procedentes de dos contadores de centelleo. El analizador consiste en dos unidades transistorizadas: un convertidor analogico-digital de doble canal y una unidad almacenadora de nucleos de ferrita, con 900 canales y una capacidad de 2{sup 16} por canal. La unidad de control y lectura del instrumento esta separada del resto y puede ser colocada a cierta distancia del analizador. El funcionamiento del aparato para el analisis de impulsos coincidentes en las entradas A u V del convertidor puede ser regulado de manera que sea de 30 canales por 30 distribuciones, de 100 por 9, o de 300 por 3. En los dos ultimos casos las lineas de base y la anchura de las ''ventanas'' de amplitud de impulsos en la distribucion A pueden ser elegidas por el operador. Con 100 canales para el analisis de amplitud de impulsos, ocho ''ventanas'' en la distribucion A definen ocho grupos de 100 canales para las distribuciones B. En este caso se dispone, en efecto, de un analizador de 100 canales para la distribucion A y de ocho analizadores separados de 100 canales para la distribucion B. Se describen los circuitos basicos del convertidor y se explica la logica de las unidades de almacenamiento y lectura. (author) [Russian] Opisyvaetsya analizator, prednaznachennyj dlya issledovaniya sootnosheniya raspredeleniya amplitud impul'sov dvukh stsintillyatsionnykh schetchikov. Analizator sostoit iz d v u kh otdel'nykh sektsij, rabotayushchikh na tranzistorakh, dvukhkanal'nogo kodirovochnogo

  20. A 256-channel measuring and recording system; Un systeme de mesure et d'enregistrement a 256 canaux; Sistema izmerenij i registratsii na 256 kanalov; Sistema de medicion y registro de 256 canales

    Energy Technology Data Exchange (ETDEWEB)

    Krasheninnikov, I S; Kuronkin, S S; Pasechnikova, I P; Safonovi, O A; Tuchina, A S

    1962-04-15

    sistema, que consiste fundamentalmente en un dispositivo de registro de 256 canales con una capacidad de 2{sup 16} por canal y en un dispositivo de mando, esta constituido por nucleos de ferritas y transistores. El elemento aritmetico del dispositivo de registro permite efectuar operaciones de adicion y sustraccion. La duracion de un ciclo completo basta la ''memoria'' es de 20 {mu}s. En el dispositivo de mando, el registro, el recuento y la inscripcion pueden ajustarse y combinarse en el orden que se desee; esto da al nuevo sistema un campo de aplicacion mucho mas amplio que el del equipo corrientemente utilizado. Un generador de cuarzo de 4 MHz establece la frecuencia para el dispositivo de mando. En el sistema se utilizan los siguientes dispositivos de medicion: un convertidor de amplitud de impulsos en clave de computo numerico con un tiempo de conversion de 0,25 {mu}s por canal, una desviacion de linealidad integral inferior a 0,1 por ciento, una desviacion de linealidad diferencial inferior al 4 por ciento, una deriva del cero inferior a 0,2 V y una inestabilidad a largo plazo de anchura de canal inferior a 0,4 por ciento. Para el circuito de conversion se utilizan valvulas. El selector de tiempo, para el que se emplean transistores, tiene una anchura de canal variable entre 1 y 64 {mu}s; la inestabilidad de esta anchura es inferior a 10{sup -4}. El circuito esta concebido de forma que permite registrar en el canal impulsos incompletos para anchuras de canal superiores a 8 {mu}s. El convertidor utilizado para expresar intervalos breves de tiempo (10{sup -9} a 10{sup -7} s) en una clave de computo numerico simple tiene un tiempo de resolucion del orden de 2 {center_dot} 10{sup -5} s y una estabilidad de anchura de canal superior a 10{sup -2}. La informacion acumulada en la ''memoria'' puede transmitirse en forma analogica a un tubo oscilografico y, en clave de computo numerico, a un aparato impresor y a lamparas indicadoras. (author) [Russian] V doklade obsuzhdaetsya

  1. A transistorized 1024-channel neutron time-of-flight analyser; Selecteur transistorise de temps de vol pour neutrons, a 1024 canaux; Nejtronnyj analizator vremeni proleta s 1024 kanalami i s perevodom skhemy na tranzistory; Aparato transistorizado de 1024 canales para analizar tiempos de vuelo de neutrones

    Energy Technology Data Exchange (ETDEWEB)

    Giannelli, G [European Atomic Energy Community, CCR, Ispra (Italy)

    1962-04-15

    extremement souple qui puisse se preter aux modifications ou extensions que les recherches pourraient souhaiter introduire. (author) [Spanish] Se describe un aparato transistorizado de 1024 canales para analizar tiempos de vuelo de neutrones. El aparato se divide en dos partes completamente independientes: el convertidor analogicodigital (CAD), que mide el tiempo de vuelo, y la memoria de nucleos de ferrita de 1024 canales. De este modo, las senales que salen del CAD pueden ser registradas en cinta magnetica junto con las senales de otros CAD que miden otras magnitudes fisicas relacionadas con el mismo suceso nuclear, con un numero total de canales superior a la capacidad de la memoria. El CAD tiene una memoria temporal que por su accion reguladora del ritmo de los impulsos permite: 1) obtener un tiempo muerto de solo 0,5 microsegundos cuando el CAD esta conectado directamente a la memoria de 1024 canales, y 2) aprovechar mejor la cinta magnetica cuando es el propio CAD quien acciona el registrador magnetico. La memoria temporal tiene una capacidad de cuatro numeros de hasta 16 digitos. La amplitud de los canales del analizador se puede variar desde 0,5 hasta 48 microsegundos. Los 1024 canales se pueden dividir en dos grupos simultaneos de 512 canales, conectado cada uno a dos detectores. La memoria temporal permite registrar senales simultaneamente en ambos grupos. Tambien se pueden subdividir los canales en dos grupos segun el tiempo de vuelo; el primero (de 16 canales) se emplea para registrar el origen de tiempos de vuelo, y el segundo se puede colocar en cualquier posicion a todo lo largo del intervalo de tiempos de vuelo. El numero de canales empleados para registrar tiempos de vuelo se puede reducir para poder registrar simultaneamente otra magnitud en el total de 1024 canales. El autor describe el diseno logico del instrumento, que aprovecha las posibilidades que ofrecen los transistores con una oportuna disposicion mecanica, para lograr un instrumento de gran