Combined in-situ and ex-situ bioremediation of petroleum hydrocarbon contaminated soils by closed-loop soil vapor extraction and air injection

International Nuclear Information System (INIS)

Hu, S.S.; Buckler, M.J.

1993-01-01

Treatment and restoration of petroleum hydrocarbon contaminated soils at a bulk petroleum above-ground storage tank (AST) site in Michigan is being conducted through in-situ and ex-situ closed-loop soil vapor extraction (SVE), soil vapor treatment, and treated air injection (AI) processes. The soil vapor extraction process applies a vacuum through the petroleum hydrocarbon affected soils in the ex-situ bio-remediation pile (bio-pile) and along the perimeter of excavated area (in-situ area) to remove the volatile or light petroleum hydrocarbons. This process also draws ambient air into the ex-situ bio-pile and in-situ vadose zone soil along the perimeter of excavated area to enhance biodegradation of light and heavy petroleum hydrocarbons in the soil. The extracted soil vapor is treated using a custom-designed air bio-remediation filter (bio-filter) to degrade the petroleum hydrocarbon compounds in the soil vapor extraction air streams. The treated air is then injected into a flush grade soil bed in the backfill area to perform final polishing of the air stream, and to form a closed-loop air flow with the soil vapor extraction perforated pipes along the perimeter of the excavated area

Soil remediation via bioventing, vapor extraction and transition regime between vapor extraction and bioventing

Directory of Open Access Journals (Sweden)

Mohammad Mehdi Amin

2014-01-01

Conclusion: Comparison of the BV, SVE and AIBV technologies indicated that all of those technologies are efficient for remediation of unsaturated zone, but after specific remediation time frames, only AIBV able to support guide line values and protect ground waters.

Stakeholder acceptance analysis: Passive soil vapor extraction using borehole flux

International Nuclear Information System (INIS)

Peterson, T.S.

1995-12-01

This report presents evaluations, recommendations, and requirements concerning passive soil vapor extraction (PSVE) derived from a three-year program of stakeholder involvement. PSVE takes advantage of the naturally occurring tendency of soil vapor to leave the subsurface during periods of low barometric pressure. PSVE seeks to expedite the release of volatile contaminants through the use of boreholes and technological enhancements. This report is for technology developers and those responsible for making decisions about the use of technology to remediate contamination by volatile organic compounds. Stakeholders' perspectives help those responsible for technology deployment to make good decisions concerning the acceptability and applicability of PSVE to the remediation problems they face. The report provides: stakeholders' final evaluation of the acceptability of PSVE in light of the technology's field test; stakeholders' principal comments concerning PSVE; requirements that stakeholders have of any remediation technology. Technology decision makers should take these conclusions into account in evaluating the effectiveness and acceptability of any remedial method proposed for their site. In addition, the report presents data requirements for the technology's field demonstration defined by stakeholders associated with the Hanford site in Washington State, as well as detailed comments on PSVE from stakeholders from Sandia National Laboratory, Rocky Flats, Idaho National Engineering Laboratory, and Los Alamos National Laboratory

Effects of seasonal and well construction variables on soil vapor extraction pilot tests

International Nuclear Information System (INIS)

Campbell, R.; Hudon, N.; Bass, D.

1995-01-01

The selection and design of an effective soil vapor extraction system is dependent upon data generated from pilot testing. Therefore, it is critical to understand factors that may affect the testing prior to selecting or designing a system. In Sebago Lake Village, Maine, two adjacent gasoline stations experienced a release. Gasoline migrated through fine sand into the groundwater and discharged to a small stream. Soil vapor extraction was investigated as a remedial alternative to reduce volatile organic compounds in the unsaturated soil. Three soil vapor extraction pilot tests were performed at one of the sites and one test at the other site. The results of the testing varied. Data collected during a summer test indicated soil vapor extraction was less likely to work. The wells tested were installed using an excavator. An adequate surface seal was not present in any of the tested wells. An additional test was performed in the winter using wells installed by a drill rig. Winter test results indicated that soil vapor extraction could be effective. Another test was performed after a horizontal soil vapor extraction system with a surface seal was installed. The results of this testing indicated that soil vapor extraction was more effective than predicted by the earlier tests. Tests performed on the other property indicated that the horizontal wells were more effective than the vertical wells. Testing results were affected by the well installation method, well construction, proximity to manmade structures, and the season in which testing was performed. Understanding factors that affect the testing is critical in selecting and designing the system

Bioremediation of petroleum hydrocarbon contaminated soils using soil vapor extraction: Case study

International Nuclear Information System (INIS)

Roth, R.J.; Peterson, R.M.

1994-01-01

Soils contaminated with petroleum hydrocarbons are being remediated in situ at a site in Lakewood, New Jersey by bioremediation in conjunction with soil vapor extractions (SVE) and nutrient addition. The contaminants were from hydraulic oils which leaked from subsurface hydraulic lifts, waste oil from leaking underground storage tanks (USTs), an aboveground storage tank, and motor oil from a leaking UST. The oils contaminated subsurface soils at the site to a depth of 25 feet. Approximately 900 cubic yards of soil were contaminated. Soil sample analyses showed total petroleum hydrocarbon (TPH) concentrations up to 31,500 ppm. The design of the remedial system utilized the results of a treatability study which showed that TPH degrading microorganisms, when supplied with oxygen and nutrients, affected a 14% reduction in TPH in 30 days. A SVE system was installed which used three wells, each installed to a depth of 25 feet below grade. The SVE system was operated to achieve an extracted air flow of approximately 20 to 30 scfm from each well. Bioremediation of the TPH was monitored by measuring CO 2 and O 2 concentrations at the wellheads and vapor monitoring probes. After four months of remediation, CO 2 concentrations were at a minimum, at which point the subsurface soils were sampled and analyzed for TPH. The soil analyses showed a removal of TPH by biodegradation of up to 99.8% after four months of remediation

Test plan for the FY 1997 rebound study at the carbon tetrachloride soil vapor extraction site

International Nuclear Information System (INIS)

Rohay, V.J.; Tranbarger, R.K.

1996-11-01

This test plan describes the strategy and field measurements designed to evaluate the potential rebound of carbon tetrachloride vapor concentrations following cessation of soil vapor extraction (SVE) operations at the 200-ZP-2 Operable Unit in the 200 West Area of the Hanford Site. Soil vapor extraction was initiated in February 1992 as the preferred remedial alternative of the Carbon Tetrachloride Expedited Response Action for removal of carbon tetrachloride from the unsaturated zone beneath the primary carbon tetrachloride disposal sites. The magnitude, extent, and rate of rebound in carbon tetrachloride vapor concentrations will help determine the availability of additional carbon tetrachloride for removal using SVE. At the conclusion of the field measurements, a report will be completed to evaluate the results of the rebound study

Multilevel soil-vapor extraction test for heterogeneous soil

International Nuclear Information System (INIS)

Widdowson, M.A.; Haney, O.R.; Reeves, H.W.

1997-01-01

The design, performance, and analysis of a field method for quantifying contaminant mass-extraction rates and air-phase permeability at discrete vertical locations of the vadose zones are presented. The test configuration consists of a multiscreen extraction well and multilevel observation probes located in soil layers adjacent to the extraction well. For each level tested an inflatable packer system is used to pneumatically isolate a single screen in the extraction well, and a vacuum is applied to induce air flow through the screen. Test data include contaminant concentration and flow characteristics at the extraction well, and transient or steady-state pressure drawdown data at observation probes located at variable radii from the extraction well. The test method is applicable to the design of soil-vapor extraction (SVE) and bioventing remediation systems in a variety of geologic settings, particularly stratified soils. Application of the test method at a gasoline-polluted site located in the Piedmont physiographic region is described. Contaminant mass-extraction rates, expressed in terms of volatile hydrocarbons, varied from 0.16 to 14 kg/d

Dual vapor extraction on acidic sludge tar at a former refinery

International Nuclear Information System (INIS)

Lear, P.R.; Beall, P.; Townsend, S.

1996-01-01

OHM Remediation Services Corp conducted a pilot-scale demonstration for a novel application of dual vapor extraction technology for the pretreatment of the acid tar sludge material. The acid tar sludge comprised of approximately 60% asphaltene hydrocarbon material, 20% clay, and up to 20% sulfuric acid (H 2 SO 4 ). The liquid layer in the bottom of the pits has a low pH ( 2 ) gas which is released with the sludge material is excavated or handled. The objective of the dual vapor extraction was to remove the SO 2 vapors and liquid layer containing sulfuric acid prior to any further treatment. The dual vapor extraction would reduce the amount of alkaline reagent required for neutralization while eliminating the health and safety concerns. Overall, the DVE pilot demonstration successfully showed that both liquids and vapors could be removed from the acid tar sludge material. The liquid present in the lower portions of the pits will have pH values of 1.0 or less and acidities on the order of 5% H 2 SO 4 . The liquid removed from the acid tar sludge material by a DVE system will have slightly higher pH (∼1.5) and lower alkalinities (∼3% H 2 SO 4 ). The SO 2 concentration in the vapors removed by the DVE system will be variable with initial levels approaching 1,200 ppmv SO 2 . The SO 2 concentration in the vapor phase should decrease with time. A caustic scrubber solution will remove any SO 2 from the vapor phase. After DVE treatment, the acid tar sludge material would have a slightly increased pH and a decreased SO 2 concentration

Case studies illustrating in-situ remediation methods for soil and groundwater contaminated with petrochemicals

Energy Technology Data Exchange (ETDEWEB)

Dixon, Robert A; Lance, P E; Downs, A; Kier, Brian P [EMCON Northwest Inc., Portland, OR (United States)

1994-12-31

Four case studies of successful in-situ remediation are summarized illustrating cost-effective methods to remediate soil and groundwater contaminated with volatile and non-volatile petrochemicals. Each site is in a different geologic environment with varying soil types and with and without groundwater impact. The methods described include vadose zone vapor extraction, high-vacuum vapor extraction combined with groundwater tab.le depression, air sparging with groundwater recovery and vapor extraction, and bio remediation of saturated zone soils using inorganic nutrient and oxygen addition

Case studies illustrating in-situ remediation methods for soil and groundwater contaminated with petrochemicals

Energy Technology Data Exchange (ETDEWEB)

Dixon, Robert A.; Lance, P.E.; Downs, A.; Kier, Brian P. [EMCON Northwest Inc., Portland, OR (United States)

1993-12-31

Four case studies of successful in-situ remediation are summarized illustrating cost-effective methods to remediate soil and groundwater contaminated with volatile and non-volatile petrochemicals. Each site is in a different geologic environment with varying soil types and with and without groundwater impact. The methods described include vadose zone vapor extraction, high-vacuum vapor extraction combined with groundwater tab.le depression, air sparging with groundwater recovery and vapor extraction, and bio remediation of saturated zone soils using inorganic nutrient and oxygen addition

Resistive heating enhanced soil vapor extraction of chlorinated solvents from trichloroethylene contaminated silty, low permeable soil

NARCIS (Netherlands)

Zutphen, M. van; Heron, G.; Enfield, C.G.; Christensen, T.H.

1998-01-01

A 2D-laboratory box experiment (12 x 56 x 116 cm) was conducted to simulate the enhancement of soil vapor extraction by the application of low frequency electrical heating Uoule heating) for the remediation of a low permeable, silty soil contaminated with trichloroethylene. Joule heating enlarged

Three-dimensional computer simulations of bioremediation and vapor extraction

International Nuclear Information System (INIS)

Travis, B.; Trent, B.

1991-01-01

Numerical simulations of two remediation strategies are presented. These calculations are significant in that they will play a major role in the actual field implementation of two very different techniques. The first set of calculations simulates the actual spill event of nearly 60,000 gallons of No. 2 diesel fuel oil and its subsequent flow toward the water table for 13 years. Hydrogen peroxide saturated water flooding is then performed and bioremediation of the organic material is then calculated. The second set of calculations describes the vacuum extraction of organic vapors subject to various assumed formation properties and boundary conditions

Soil Vapor Extraction System Optimization, Transition, and Closure Guidance

Energy Technology Data Exchange (ETDEWEB)

Truex, Michael J.; Becker, Dave; Simon, Michelle A.; Oostrom, Martinus; Rice, Amy K.; Johnson, Christian D.

2013-02-08

Soil vapor extraction (SVE) is a prevalent remediation approach for volatile contaminants in the vadose zone. A diminishing rate of contaminant extraction over time is typically observed due to 1) diminishing contaminant mass, and/or 2) slow rates of removal for contamination in low-permeability zones. After a SVE system begins to show indications of diminishing contaminant removal rate, SVE performance needs to be evaluated to determine whether the system should be optimized, terminated, or transitioned to another technology to replace or augment SVE. This guidance specifically addresses the elements of this type of performance assessment. While not specifically presented, the approach and analyses in this guidance could also be applied at the onset of remediation selection for a site as a way to evaluate current or future impacts to groundwater from vadose zone contamination. The guidance presented here builds from existing guidance for SVE design, operation, optimization, and closure from the U.S. Environmental Protection Agency, U.S. Army Corps of Engineers, and the Air Force Center for Engineering and the Environment. The purpose of the material herein is to clarify and focus on the specific actions and decisions related to SVE optimization, transition, and/or closure.

Vapor vacuum extraction treatability study at the Idaho National Engineering Laboratory

International Nuclear Information System (INIS)

Herd, M.D.; Matthern, G.; Michael, D.L.; Spang, N.; Downs, W.; Weidner, J.; Cleary, P.

1993-01-01

During the 1960s and early 1970s, barreled mixed waste containing volatile organic compounds (VOCS) and radioactive waste was buried at the Subsurface Disposal Area (SDA) at the Idaho National Engineering Laboratory (INEL) Radioactive Waste Management Complex (RWMC). Over time, some of the barrels have deteriorated allowing, VOC vapors to be released into the vadose zone. The primary VOC contaminates of concern are CCl 4 and trichloroethylene; however, chloroform, tetrachloroethylene, and 1,1,1-trichloroethane have also been detected. Vapor Vacuum Extraction (VVE) is one alternative being considered for remediation of the RWMC SDA vadose zone. A proposed pilot-scale treatability study (TS) will provide operation and maintenance costs for the design of the potential scale-up of the system

In situ remediation of Jet A in soil and ground water by high vacuum, dual phase extraction

International Nuclear Information System (INIS)

Kirshner, M.; Pressly, N.C.; Roth, R.J.

1996-01-01

This report summarizes the initial results of subsurface remediation at Terminal 1, Kennedy International Airport, to remediate soil and ground water contaminated with Jet A fuel. The project was driven and constrained by the construction schedule of a major new terminal at the facility. The remediation system used a combination of ground water pumping, air injection, and soil vapor extraction. In the first five months of operation, the combined processes of dewatering, volatilization, and biodegradation removed a total of 36,689 pounds of total volatile and semivolatile organic jet fuel hydrocarbons from subsurface soil and ground water. The results of this case study have shown that 62% of the removal resulted from biodegradation, 27% occurred as a result of liquid removal, and 11% resulted from the extraction of volatile organic compounds (VOCs)

Predicting Soil-Air and Soil-Water Transport Properties During Soil Vapor Extraction

DEFF Research Database (Denmark)

Poulsen, Tjalfe

Increased application of in-situ technology for control and removal of volatile organic compounds (VOC) in the subsurface has made the understanding of soil physical properties and their impact upon contaminant transport even more important. Knowledge of contaminant transport is important when...... properties of undisturbed soil from more easily measurable soil properties are developed. The importance of soil properties with respect to contaminant migration during remediation by soil vapor extraction (SVE) in the unsaturated zone was investigated using numerical simulations....

Model analysis of mechanisms controlling pneumatic soil vapor extraction

DEFF Research Database (Denmark)

Høier, Camilla Kruse; Sonnenborg, Torben Obel; Jensen, Karsten Høgh

2009-01-01

of heterogeneous soils by enforcing large fluctuating pressure fronts through the contaminated area. Laboratory experiments have suggested that pneumatic SVE considerably improves the recovery rate from low-permeable units. We have analyzed the experimental results using a numerical code and quantified......The efficiency of traditional soil venting or soil vapor extraction (SVE) highly depends on the architecture of the subsurface because imposed advective air flow tends to bypass low-permeable contaminated areas. Pneumatic SVE is a technique developed to enhance remediation efficiency...... level the pneumatic venting technology is superior to the traditional technique, and that the method is particularly efficient in cases where large permeability contrasts exist between soil units in the subsurface....

General well function for soil vapor extraction

Science.gov (United States)

Perina, Tomas

2014-04-01

This paper develops a well function applicable to extraction of groundwater or soil vapor from a well under the most common field test conditions. The general well function (Perina and Lee, 2006) [12] is adapted to soil vapor extraction and constant head boundary at the top. For groundwater flow, the general well function now applies to an extraction well of finite diameter with uniform drawdown along the screen, finite-thickness skin, and partially penetrating an unconfined, confined, and leaky aquifer, or an aquifer underneath a reservoir. With a change of arguments, the model applies to soil vapor extraction from a vadose zone with no cover or with leaky cover at the ground surface. The extraction well can operate in specified drawdown (pressure for soil vapor) or specified flowrate mode. Frictional well loss is computed as flow-only dependent component of the drawdown inside the extraction well. In general case, the calculated flow distribution is not proportional to screen length for a multiscreen well.

Hanford soil partitioning and vapor extraction study

International Nuclear Information System (INIS)

Yonge, D.; Hossain, A.; Cameron, R.; Ford, H.; Storey, C.

1996-07-01

This report describes the testing and results of laboratory experiments conducted to assist the carbon tetrachloride soil vapor extraction project operating in the 200 West Area of the Hanford Site in Richland, Washington. Vapor-phase adsorption and desorption testing was performed using carbon tetrachloride and Hanford Site soils to estimate vapor-soil partitioning and reasonably achievable carbon tetrachloride soil concentrations during active vapor extractions efforts at the 200 West Area. (CCl 4 is used in Pu recovery from aqueous streams.)

Application of tracer gas studies in the optimal design of soil vapor extraction systems

International Nuclear Information System (INIS)

Marley, M.C.; Cody, R.J.; Polonsky, J.D.; Woodward, D.D.; Buterbaugh, G.J.

1992-01-01

In the design of an optimal, cost effective vapor extraction system (VE) for the remediation of volatile organic compounds (VOCs), it is necessary to account for heterogeneities in the vadose zone. In some cases, such as those found in relatively homogeneous sands, heterogeneities can be neglected as induced air flow through the subsurface can be considered uniform. The subsurface conditions encountered at many sites (soil/bedrock interfaces, fractured bedrock) will result in preferential subsurface-air flow pathways during the operation of the VES. The use of analytical and numerical compressible fluid flow models calibrated and verified from parameter evaluation tests can be utilized to determine vadose zone permeability tensors in heterogeneous stratifications and can be used to project optimal, full scale VES performance. Model-derived estimations of the effect of uniform and/or preferential air flow pathways on subsurface induced air flow velocities can be enhanced, confirmed utilizing tracer gas studies. A vadose zone tracer gas study entails the injection of an easily detected, preferably inert gas into differing locations within the vadose zone at distances away from the VES extraction well. The VES extraction well is monitored for the detection of the gas. This is an effective field methodology to qualify and quantify the subsurface air flow pathways. It is imperative to gain an understanding of the dynamics of the air flow in the soils and lithologies of each individual site, and design quick and effective methodologies for the characterization of the subsurface to streamline remediation costs and system operations. This paper focuses on the use of compressible fluid flow models and tracer gas studies in the enhancement of the design of vapor extraction systems

Multimedia risk-based soil cleanup at a gasoline-contaminated site using vapor extraction

International Nuclear Information System (INIS)

Mills, W.B.; Johnson, K.M.; Liu, S.; Loh, J.Y.; Lew, C.S.

1996-01-01

At a utility service center, gasoline from an underground storage tank had leaked into subsurface vadose zone soils for several years. To remediate the site, a soil vapor extraction (SVE) system was installed and operated. At the completion of the SVE operation, gasoline-containing residues in several confirmation soil borings exceeded agency-mandated cleanup levels. Rather than continue with SVE, a risk-based approach was developed to evaluate what levels of gasoline-containing residues could be left in the soil and still protect human health. The risk-based approach consisted of simulating the fate of chemical residues through the vadose zone and then into both the ground water and atmosphere. Receptor point concentrations were predicted, and health risks were assessed. The risk assessment concluded that ingestion of contaminated ground water and inhalation of air while showering were the largest potential contributors to risk, and that risks associated with inhalation of vapor-containing ambient air are small. However, all predicted risks are below the acceptable risk levels of 10 -6 individual cancer risk probability and 1.0 hazard index. Therefore, the lead agency accepted the recommendation that the site requires no further remediation. The service center continues normal operations today

Performance Evaluation Report for Soil Vapor Extraction Operations at the Carbon Tetrachloride Site, February 1992 - September 1998

International Nuclear Information System (INIS)

Rohay, V. J.

1999-01-01

Soil vapor extraction (SVE) is being used to remove carbon tetrachloride from the vadose zone at the 200-ZP-2 Operable Unit. The purpose of this report is to evaluate both the SVE system operating data and the effectiveness of SVE in remediating the carbon tetrachloride contamination. This report has been revised to cover the operating period from February 25, 1992 through September 30, 1998. The scope of the report includes the history of SVE operations at 200-ZP-2, the efficiency of those operations over time, the volume of vapor processed per extraction system, the change in carbon tetrachloride concentrations with time, the mass of carbon tetrachloride removed per site, and recommendations for future operations and evaluations. This revision includes an update to the carbon tetrachloride conceptual model

FEASIBILITY OF HYDRAULIC FRACTURING OF SOILS TO IMPROVE REMEDIAL ACTIONS

Science.gov (United States)

Hydraulic fracturing, a method of increasing fluid flow within the subsurface, should improve the effectiveness of several remedial techniques, including pump and treat, vapor extraction, bio-remediation, and soil-flushing. he technique is widely used to increase the yields of oi...

SOIL VAPOR EXTRACTION TECHNOLOGY: REFERENCE HANDBOOK

Science.gov (United States)

Soil vapor extraction (SVE) systems are being used in Increasing numbers because of the many advantages these systems hold over other soil treatment technologies. SVE systems appear to be simple in design and operation, yet the fundamentals governing subsurface vapor transport ar...

The use of in-situ dual vacuum extraction for remediation of soil and groundwater

International Nuclear Information System (INIS)

Trowbridge, B.E.; Ott, D.E.

1992-01-01

Dual Extraction provides a rapid and cost-effective method of remediating soil and groundwater impacted by volatile organic compounds (VOC's). Dual Extraction is the removal of both water and vapors through the same borehole using entrainment. This technology provides for the remediation of the vadose zone, capillary fringe, smear zone, and existing water table. The effectiveness of this technology is shown in a case study. A release from an Underground Storage Tank (UST) was responsible for a hydrocarbon plume spreading over approximately 50,000 square feet. The release produced vadose zone contamination in the silty and sandy clays from 10 - 30 feet below ground surface with TPH concentrations up to 1,400 mg/kg. A layer of free floating liquid hydrocarbon was present on a shallow aquifer located at 30 feet bgs in thicknesses ranging from 0.5 feet to 3.0 feet. An in-situ dual-extraction system was installed to remediate the soils and groundwater to levels as required by the Los Angeles Regional Water Quality Control Board (RWQCB). The system operated 24 hours/day for 196 days with an operating efficiency of over 99%. After 196 days, over 17,000 pounds of hydrocarbons had been extracted from the soils. Seven confirmatory soil borings were advanced in the area of highest initial hydrocarbon concentrations and indicated that TPH and BTEX concentrations had decreased over 99% from initial soil concentrations. Three confirmatory groundwater samples were obtained from monitoring wells initially exhibiting up to 3 feet of floating product. Confirmatory samples exhibited non-detectable (ND) concentrations of TPH and BTEX. Based upon the positive confirmatory results, site closure was obtained from the RWQCB in May of 1991. In only 28 weeks of operation, the groundwater contamination was reduced from free floating product to non-detectable concentrations of TPH using Dual Vacuum Extraction

MICHIGAN SOIL VAPOR EXTRACTION REMEDIATION (MISER) MODEL: A COMPUTER PROGRAM TO MODEL SOIL VAPORT EXTRACTION AND BIOVENTING OF ORGANIC MATERIALS IN UNSATURATED GEOLOGICAL MATERIAL

Science.gov (United States)

This report describes the formulation, numerical development, and use of a multiphase, multicomponent, biodegradation model designed to simulate physical, chemical, and biological interactions occurring primarily in field scale soil vapor extraction (SVE) and bioventing (B...

Integrated enhanced bioremediation and vacuum extraction for remediation of a hydrocarbon release in response to oscillating hydrologic conditions 'Traverse Co-Bio-Vac'

International Nuclear Information System (INIS)

Korreck, W.M.; Armstrong, J.M.; Douglass, R.H.

1992-01-01

The use of enhanced in-situ biological treatment and vacuum extraction has been demonstrated to be successful in the remediation of ground water and soil contaminated with hydrocarbons. Seasonal fluctuations in the ground water causes the zone of contamination to be in the either saturated or unsaturated zone of the aquifer. In order to address these conditions, an integrated engineering design approach is being taken for the full scale remediation of an aviation of an aviation gasoline spill at the US Coast Guard Air Station at Traverse City, Township, Michigan. Enhanced aerobic biodegradation will be utilized during the periods of high water table whereby most of the contaminated interval is saturated. Carbon treated water will be utilized from the existing ground water plume. Oxygen will be injected via an oxygen generator to saturate the process stream prior to discharge to the aquifer. During low water table conditions, the same infrastructure will be utilized as a modified vacuum extraction system. The same injection wells used during the high water table would then be used during the low table condition as vapor extraction wells. The vapors will be routed to an above-ground catalytic incinerator for compound destruction. This integrated approach, entitled 'Traverse Co-Bio-Vac,' should reduce the capital costs of installing a full scale remedial system as well allowing the system to operate efficiently depending on water table conditions. The system is expected to be constructed in 1992

Use of in-situ Dual Vacuum Extraction trademark for remediation of soil and ground water

International Nuclear Information System (INIS)

Dodson, M.E.; Trowbridge, B.E.; Ott, D.

1994-01-01

Dual Vacuum Extraction trademark provides a rapid and cost-effective method of remediating soil and ground water contaminated with volatile organic compounds. The system involves the removal of both water and vapors through the same borehole by use of entrainment. This technology provides for the remediation of the vadose zone, capillary fringe, smear zone, and existing water table. The effectiveness of this technology is shown in a case study. A release from an underground storage tank was responsible for a hydrocarbon plume spreading over approximately 50,000 ft 2 . The release produced vadose-zone contamination in the silty and sandy clays from 10 to 30 ft below ground surface (bgs) with total petroleum hydrocarbon (TPH) concentrations up to 1,400 mg/kg. In addition, a layer of free-floating liquid hydrocarbon was present on a shallow aquifer located at 25 ft bgs in thicknesses ranging from 0.5 to 3.0 ft. An in-situ dual-extraction system was installed to remediate the soils and ground water to levels as required by the Los Angeles Regional Water Quality Control Board (RWQCB). The system operated 24 hr a day, with an operating efficiency of over 99%. After 196 days (28 weeks), over 17,000 lb of hydrocarbons had been extracted from the soils. Seven confirmatory soil borings in the area of highest initial hydrocarbon concentrations indicated that TPH and benzene, toluene, ethylbenzene, xylene (BTEX) concentrations had decreased over 99% from initial soil concentrations

Remediation challenges posed by the fate and transport properties of MTBE

International Nuclear Information System (INIS)

Day, M.J.

2002-01-01

Releases of fuel from underground tank systems have been a major source of groundwater contamination for several decades. The fate and transport characteristics of fuel components significantly influence the potential risk to groundwater supplies and the methodologies to manage and remediate contamination at fuel release sites. The recognition that MTBE can be more mobile in groundwater systems than other components of oxygenated fuels has put an increased emphasis on early detection and response to fuel leaks and spills. Remediation of oxygenated fuel releases usually follows a sequence of tasks: receptor protection, source control, residual and dissolved phase remediation, and monitored natural attenuation. Good characterization of hydrogeological and geochemical conditions is required because understanding the fate and transport of fuel components is critical to developing an appropriate management plan and an efficient remediation program. Understanding the specific site conditions allows appropriate selection and sequencing of remedial technologies. The physical and chemical characteristics of MTBE can result in a higher mobility in the subsurface, compared with the BTEX components of a gasoline release. These same characteristics make MTBE more readily extractable from the subsurface compared with BTEX. There is an impression that remediating gasoline releases containing MTBE requires costly, specialized technologies compared with those employed to deal with non-oxygenated fuel releases. However, the characteristics of MTBE are well suited to traditional, physical remedial approaches that have proven to be effective with the other components of gasoline. Technologies such as groundwater extraction, soil vapor extraction (SVE), and thermal desorption work exceptionally well with MTBE due to its low adsorptive and high vapor pressure characteristics. Similarly, recent studies have demonstrated that MTBE is biodegradable under a wide variety of conditions

The application of in situ air sparging as an innovative soils and ground water remediation technology

International Nuclear Information System (INIS)

Marley, M.C.; Hazebrouck, D.J.; Walsh, M.T.

1992-01-01

Vapor extraction (soil venting) has been demonstrated to be a successful and cost-effective remediation technology for removing VOCs from the vadose (unsaturated) zone. However, in many cases, seasonal water table fluctuations, drawdown associated with pump-and-treat remediation techniques, and spills involving dense, non-aqueous phase liquids (DNAPLS) create contaminated soil below the water table. Vapor extraction alone is not considered to be an optimal remediation technology to address this type of contamination. An innovative approach to saturated zone remediation is the use of sparging (injection) wells to inject a hydrocarbon-free gaseous medium (typically air) into the saturated zone below the areas of contamination. The contaminants dissolved in the ground water and sorbed onto soil particles partition into the advective air phase, effectively simulating an in situ air-stripping system. The stripped contaminants are transported in the gas phase to the vadose zone, within the radius of influence of a vapor extraction and vapor treatment system. In situ air sparging is a complex multifluid phase process, which has been applied successfully in Europe since the mid-1980s. To date, site-specific pilot tests have been used to design air-sparging systems. Research is currently underway to develop better engineering design methodologies for the process. Major design parameters to be considered include contaminant type, gas injection pressures and flow rates, site geology, bubble size, injection interval (areal and vertical) and the equipment specifications. Correct design and operation of this technology has been demonstrated to achieve ground water cleanup of VOC contamination to low part-per-billion levels

Measurement of air and VOC vapor fluxes during gas-driven soil remediation: bench-scale experiments.

Science.gov (United States)

Kim, Heonki; Kim, Taeyun; Shin, Seungyeop; Annable, Michael D

2012-09-04

In this laboratory study, an experimental method was developed for the quantitative analyses of gas fluxes in soil during advective air flow. One-dimensional column and two- and three-dimensional flow chamber models were used in this study. For the air flux measurement, n-octane vapor was used as a tracer, and it was introduced in the air flow entering the physical models. The tracer (n-octane) in the gas effluent from the models was captured for a finite period of time using a pack of activated carbon, which then was analyzed for the mass of n-octane. The air flux was calculated based on the mass of n-octane captured by the activated carbon and the inflow concentration. The measured air fluxes are in good agreement with the actual values for one- and two-dimensional model experiments. Using both the two- and three-dimensional models, the distribution of the air flux at the soil surface was measured. The distribution of the air flux was found to be affected by the depth of the saturated zone. The flux and flux distribution of a volatile contaminant (perchloroethene) was also measured by using the two-dimensional model. Quantitative information of both air and contaminant flux may be very beneficial for analyzing the performance of gas-driven subsurface remediation processes including soil vapor extraction and air sparging.

Autonomous gas chromatograph system for Thermal Enhanced Vapor Extraction System (TEVES) proof of concept demonstration

International Nuclear Information System (INIS)

Peter, F.J.; Laguna, G.R.

1996-09-01

An autonomous gas chromatograph system was designed and built to support the Thermal Enhanced Vapor Extraction System (TEVES) demonstration. TEVES is a remediation demonstration that seeks to enhance an existing technology (vacuum extraction) by adding a new technology (soil heating). A pilot scale unit was set up at one of the organic waste disposal pits at the Sandia National Laboratories Chemical Waste Landfill (CWL) in Tech Area 3. The responsibility for engineering a major part of the process instrumentation for TEVES belonged to the Manufacturing Control Subsystems Department. The primary mission of the one-of-a-kind hardware/software system is to perform on-site gas sampling and analysis to quantify a variety of volatile organic compounds (VOCs) from various sources during TEVES operations. The secondary mission is to monitor a variety of TEVES process physical parameters such as extraction manifold temperature, pressure, humidity, and flow rate, and various subsurface pressures. The system began operation in September 1994 and was still in use on follow-on projects when this report was published

Analysis of vapor extraction data from applications in Europe

International Nuclear Information System (INIS)

Hiller, D.; Gudemann, H.

1989-01-01

This paper discusses vapor extraction, an in-situ process to remove volatile organic compounds (VOC) from soils of the vadose zone, applied in Europe since the early 1980s. In a vapor extraction well a negative differential pressure is created by a blower or similar device. The differential pressure generates a steady flow of soil gas towards the extraction well and thus provides a flushing of the soil with air undersaturated in respect to the contaminant concentration. Contaminants will evaporate into the gaseous phase both form the liquid phase and form the soil. Differential pressures applied range from 15 inches - 350 inches of water. The contaminated discharge air can be treated by activated carbon or other suitable methods. The effective radius of vapor extraction systems (VES) ranges typically form 20 feet to 150 feet underneath non-sealed - and up to 300 feet underneath sealed surfaces. Contamination from volatile organic compounds (VOC) have turned out to be widespread due to their almost ubiquitous presence in industrial processes. Specifically, VOC include halogenated hydrocarbons like TCE, PCE or TCA, aromatic hydrocarbons like benzene, toluene, xylene and volatile fuels like gasoline

In-well vapor stripping drilling and characterization work plan

International Nuclear Information System (INIS)

Koegler, K.J.

1994-01-01

This work plan provides the information necessary for drilling, sampling, and hydrologic testing of wells to be completed in support of a demonstration of the in-well vapor stripping system. The in-well vapor stripping system is a remediation technology designed to preferentially extract volatile organic compounds (VOCs) from contaminated groundwater by converting them to a vapor phase. Air-lift pumping is used to lift and aerate groundwater within the well. The volatiles escaping the aerated water are drawn off by a slight vacuum and treated at the surface while the water is allowed to infiltrate the vadose zone back to the watertable

Laboratory testing of the in-well vapor-stripping system

International Nuclear Information System (INIS)

Gilmore, T.J.; Francois, O.

1996-03-01

The Volatile organic Compounds-Arid Integrated Demonstration (VOC-Arid ID) was implemented by the US Department of Energy's (DOE's) Office of Technology Development to develop and test new technologies for the remediation of organic chemicals in the subsurface. One of the technologies being tested under the VOC-Arid ID is the in-well vapor-stripping system. The in-well vapor-stripping concept was initially proposed by researchers at Stanford University and is currently under development through a collaboration between workers at Stanford University and DOE's Pacific Northwest National Laboratory. The project to demonstrate the in-well vapor-stripping technology is divided into three phases: (1) conceptual model and computer simulation, (2) laboratory testing, and (3) field demonstration. This report provides the methods and results of the laboratory testing in which a full-scale replica was constructed and tested above ground in a test facility located at DOE's Hanford Site, Washington. The system is a remediation technology designed to preferentially extract volatile organic compounds (VOCs) from contaminated groundwater by converting them to a vapor phase

A case study on the application of air sparging with vapor extraction at a gasoline spill site

International Nuclear Information System (INIS)

Marley, M.C.; Walsh, M.T.; Nangeroni, T.E.

1991-01-01

This paper reports that in 1985, remedial activities were implemented at a gasoline spill site in Pawtucket, Rhode Island. The engineering company that contracted to perform the remedial activities designed, installed, and operated a free gasoline product recovery system and a groundwater pump and treat system. An air striping tower was utilized to remove volatile organic hydrocarbons (VOCs) dissolved in the groundwater. Gasoline hydrocarbon vapor migration into nearby basements was controlled through the operation of a soil gas venting system (SGVS), also installed in 1985. The groundwater treatment and free product recovery systems were shut off in may 1987; however, the soil venting system remained in operation and additional vacuum wells were installed to remediate gasoline contaminated vadose zone soils and to recover hydrocarbon vapors in the vicinity of the spill location

Sustainable in-well vapor stripping: A design, analytical model, and pilot study for groundwater remediation

Science.gov (United States)

Sutton, Patrick T.; Ginn, Timothy R.

2014-12-01

A sustainable in-well vapor stripping system is designed as a cost-effective alternative for remediation of shallow chlorinated solvent groundwater plumes. A solar-powered air compressor is used to inject air bubbles into a monitoring well to strip volatile organic compounds from a liquid to vapor phase while simultaneously inducing groundwater circulation around the well screen. An analytical model of the remediation process is developed to estimate contaminant mass flow and removal rates. The model was calibrated based on a one-day pilot study conducted in an existing monitoring well at a former dry cleaning site. According to the model, induced groundwater circulation at the study site increased the contaminant mass flow rate into the well by approximately two orders of magnitude relative to ambient conditions. Modeled estimates for 5 h of pulsed air injection per day at the pilot study site indicated that the average effluent concentrations of dissolved tetrachloroethylene and trichloroethylene can be reduced by over 90% relative to the ambient concentrations. The results indicate that the system could be used cost-effectively as either a single- or multi-well point technology to substantially reduce the mass of dissolved chlorinated solvents in groundwater.

Application of a 2D air flow model to soil vapor extraction and bioventing case studies

International Nuclear Information System (INIS)

Mohr, D.H.; Merz, P.H.

1995-01-01

Soil vapor extraction (SVE) is frequently the technology of choice to clean up hydrocarbon contamination in unsaturated soil. A two-dimensional air flow model provides a practical tool to evaluate pilot test data and estimate remediation rates for soil vapor extraction systems. The model predictions of soil vacuum versus distance are statistically compared to pilot test data for 65 SVE wells at 44 sites. For 17 of 21 sites where there was asphalt paving, the best agreement was obtained for boundary conditions with no barrier to air flow at the surface. The model predictions of air flow rates and stream lines around the well allow an estimate of the gasoline removal rates by both evaporation and bioremediation. The model can be used to quickly estimate the effective radius of influence, defined here as the maximum distance from the well where there is enough air flow to remove the contaminant present within the allowable time. The effective radius of influence is smaller than a radius of influence defined by soil vacuum only. For a case study, in situ bioremediation rates were estimated using the air flow model and compared to independent estimates based on changes in soil temperature. These estimate bioremediation rates for heavy fuel oil ranged from 2.5 to 11 mg oil degraded per kg soil per day, in agreement with values in the literature

Remediation of flare pit soils using supercritical fluid extraction

Energy Technology Data Exchange (ETDEWEB)

Nagpal, V.; Guigard, S.E. [Alberta Univ., Edmonton, AB (Canada). Dept. of Civil Engineering

2005-09-01

A laboratory study was conducted to examine the ability of supercritical fluid extraction (SFE) to remove petroleum hydrocarbons (PHCs) from two flare pit soils in Alberta. SFE is a technology for remediation of contaminated soils. In order to determine the optimal extraction conditions and to understand the effects of pressure, temperature, supercritical carbon dioxide flow rate, soil type, and extraction time on the extraction efficiency of SFE, extractions were performed on two flare pit soils at various pressures and temperatures. Chemicals in the study included diesel oil, SAE 10-30W motor oil, n-decane, hexadecane, tetratriacontane and pentacontane. The best extraction conditions were defined as conditions that result in a treated soil with a PHC concentration that meets the regulatory guidelines of the Canadian Council of Ministers of the Environment in the Canada-wide standard for PHC is soil. The study results indicate that the efficiency of the SFE process is solvent-density dependent for the conditions studied. The highest extraction efficiency for both soils was obtained at conditions of 24.1 MPa and 40 degrees C. An increase in pressure at a fixed temperature led to an increase in the extraction efficiency while an increase in temperature at a fixed pressure led to a decrease in the extraction efficiency. The treated soils were observed to be lighter in colour, drier, and grainier than the soil prior to extraction. It was concluded that SFE is an effective method for remediating flare pit soils. 63 refs., 4 tabs., 5 figs.

Barometric pumping with a twist: VOC containment and remediation without boreholes. Phase I

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-08-01

The majority of the planned remediation sites within the DOE complex are contaminated with volatile organic compounds (VOCs). In many instances the contamination has not reached the water table, does not pose an immediate threat, and is not considered a high priority problem. These sites will ultimately require remediation of some type, either by active vapor extraction, bioremediation, or excavation and ex-situ soil treatment. The cost of remediating these sites can range from $50 K to more than $150 K, depending on site characteristics, contaminants, and remediation method. Additionally, for many remediated sites, residual contamination exists which could not practically be removed by the applied remediation technology. These circumstances result in modest sites with contamination of limited risk, but by regulation they must still be controlled. A remediation solution being developed by Science and Engineering Associates, Inc. (SEA) for the Department of Energy serves as an in-situ containment and extraction methodology for sites where most or all of the contamination resides in the vadose zone soil. The approach capitalizes on the advective soil gas movement resulting from barometric pressure oscillations.

Distribution of multi-component solvents in solvent vapor extraction chamber

Energy Technology Data Exchange (ETDEWEB)

Das, S. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Marathon Oil Corp., Houston, TX (United States)

2008-10-15

Vapex process performance is sensitive to operating pressures, temperatures and the types of solvent used. The hydrocarbon solvents used in Vapex processes typically have between 5 and 10 per cent hydrocarbon impurities, and the accumulation of dense phases inside the vapor chamber reduces gravity drainage potential. This study investigated the partitioning of solvent compounds inside the vapor chamber during in situ Vapex processes.The aim of the study was to examine how the different components of the mixed solvent partitioned inside the extracted chamber during the oil and vapor phase. A 2-D homogenous reservoir model was used to simulate the Vapex process with a solvent mixture comprised of propane and methane at various percentages. The effect of injecting a hot solvent vapor was also investigated. The study showed that injected methane accumulated at both the top and the extraction interface. Accumulations near the top had a positive impact on solvent confinement in thin reservoirs. Diffusion of the solvent component was controlled by gas phase molecular diffusion, and was much faster than the diffusion of solvent molecules in the liquid phase. The use of hot solvent mixtures slowed the extraction process due to lower solvent solubility in the oil phase. It was concluded that the negative impact on viscosity reduction by dilution was not compensated by rises in temperature. 6 refs., 11 figs.

Case study of shallow soil mixing and soil vacuum extraction remediation project

International Nuclear Information System (INIS)

Carey, M.J.; Day, S.R.; Pinewski, R.; Schroder, D.

1995-01-01

Shallow Soil Mixing (SSM) and Soil Vacuum Extraction (SVE) are techniques which have been increasingly relied on for the insitu remediation of contaminated soils. The primary applications of SSM have been to mix cement, bentonite, or other reagents to modify properties and thereby remediate contaminated soils or sludges. Soil vacuum extraction has been used at numerous applications for insitu removal of contaminants from soils. At a recent project in southern Ohio, the two technologies were integrated and enhanced to extract volatile organic compounds (VOCs) from soils at a Department of Energy facility. Advantages of the integrated SSM/SVE technology over alternative technologies include a relatively rapid remediation compared to other in-situ techniques at a lower cost, less exposure of waste to the surface environment and elimination of off-site disposal. These advantages led to the selection of the use of both technologies on the project in Southern Ohio. The information presented in this paper is intended to provide Engineers and owners with the level of understanding necessary to apply soil mixing and vacuum extraction technology to a specific site. The most important steps in implementing the technology are site investigation, feasibility estimate, selection of performance criteria, selection of appropriate materials, bench scale testing and construction

Remediation in clay using two-phase vacuum extraction

International Nuclear Information System (INIS)

Lindhult, E.C.; Tarsavage, J.M.; Foukaris, K.A.

1995-01-01

Soil and groundwater contamination in a tight clay usually requires costly and/or time consuming remediation, due to the inherently low hydraulic conductivity of the soil. However, Dames and Moore is successfully using an innovative, cost-effective two-phase vacuum extraction (VE) technology at a former gasoline service station. Dramatic decreases in BTEX concentrations in onsite and downgradient monitoring wells are apparent

Advances in vacuum extraction technology for effective subsurface remediation

International Nuclear Information System (INIS)

Dodson, M.E.; Pezzullo, J.A.; Piniewski, R.J.

1994-01-01

Vacuum extraction technology has become one of the most widely acclaimed methods for remediating soils contaminated by petroleum hydrocarbons and volatile organic compounds. Removal of the source of contamination in the soil is often the first step in effective control of groundwater contamination. Though originally thought effective only for removal of light-end hydrocarbons from permeable vadose-zone soils, vacuum extraction can now be adapted to address situations of low-permeable soils, heavier-end hydrocarbons and groundwater contamination. This paper reviews four innovative modifications to the vacuum extraction process and how they solve a wide variety of subsurface contamination problems. The modifications, or processes, reviewed include: vacuum-extraction-enhanced bioremediation, groundwater sparging, pneumatic soil fracturing, and soil heating

Cost and performance of innovative remediation technologies

International Nuclear Information System (INIS)

Cummings, J.B.; Kingscott, J.W.; Fiedler, L.D.

1995-01-01

The selection and use of more cost-effective remedies requires better access to data on the performance and cost of technologies used in the field. To make data more widely available, the US Environmental Protection Agency is working jointly with member agencies of the Federal Remediation Technologies Round table to publish case studies of full-scale remediation and demonstration projects. EPA, DoD, and DOE have published case studies of cleanup projects primarily consisting of bioremediation, soil vapor extraction, and thermal desorption. Within the limits of this initial data set, the paper evaluates technology performance and cost. In the analysis of cost factors, the paper shows the use of a standardized Work Breakdown Structure (WBS). Use of the WBS will be important in future reporting of completed projects to facilitate cost comparison. The paper notes the limits to normalization and thus cross-site comparison which can be achieved using the WBS. The paper identifies conclusions from initial efforts to compile cost and performance data, highlights the importance of such efforts to the overall remediation effort, and discusses future cost and performance documentation efforts

Bioventing feasibility study of low permeability soils for remediation of petroleum contamination

International Nuclear Information System (INIS)

Brackney, K.M.

1994-01-01

A site characterization of leaking underground gasoline and diesel storage tanks at the University of Idaho, West Farm Operations Center, identified approximately 800 cubic yards of petroleum-contaminated soil exceedingly regulatory action limits of 100 ppm TPH. Bioventing, a combination of in situ soil vapor extraction and microbial degradation, was selected as a remedial alternative on the basis of the presumably unsaturated paleo-soil with a 45-foot depth to groundwater, and a microbial study which concluded that indigenous petroleum-degrading microorganisms existed throughout the contamination. Soil vapor extraction tests were conducted by applying a 60-inch water column vacuum to a soil vapor extraction well and monitoring pneumatic pressure drawdown in 12 adjacent pneumatic piezometers and vertically distributed piezometer clusters. Pressure drawdown vs time data plots indicated that air permeability is inadequate everywhere at the site except at 20 feet below ground surface. Low soil permeability creates conditions for a perched water table that was documented during the investigation, resulting in unsatisfactory conditions for in situ bioventing. 8 refs., 14 figs

Investigations of Cu, Pb and Zn partitioning by sequential extraction in harbour sediments after electrodialytic remediation

DEFF Research Database (Denmark)

Kirkelund, Gunvor Marie; Ottosen, Lisbeth M.; Villumsen, Arne

2010-01-01

remediation time. A three step sequential extraction scheme (BCR), with an extra residual step, was used to evaluate the heavy metal distribution in the sediments before and after electrodialytic remediation. Cu was mainly associated with the oxidisable phase of the sediment, both before and after remediation...

A statistical approach to evaluate hydrocarbon remediation in the unsaturated zone

International Nuclear Information System (INIS)

Hajali, P.; Marshall, T.; Overman, S.

1991-01-01

This paper presents an evaluation of performance and cleanup effectiveness of a vapor extraction system (VES) in extracting chlorinated hydrocarbons and petroleum-based hydrocarbons (mineral spirits) from the unsaturated zone. The statistical analysis of soil concentration data to evaluate the VES remediation success is described. The site is a former electronics refurbishing facility in southern California; soil contamination from organic solvents was found mainly in five areas (Area A through E) beneath two buildings. The evaluation begins with a brief description of the site background, discusses the statistical approach, and presents conclusions

Performance assessment of the In-Well Vapor-Stripping System

Energy Technology Data Exchange (ETDEWEB)

Gilmore, T.J.; White, M.D.; Spane, F.A. Jr. [and others

1996-10-01

In-well vapor stripping is a remediation technology designed to preferentially extract volatile organic compounds dissolved in groundwater by converting them to a vapor phase and then treating the vapor. This vapor-stripping system is distinctly different from the more traditional in situ air-sparging concept. In situ sparging takes place in the aquifer formation; in-well vapor stripping takes place within the well casing. The system was field demonstrated at Edwards Air Force Base, California; the first-time demonstration of this technology in the United States. Installation and testing of the system were completed in late 1995, and the demonstration was operated nearly continuously for 6 months (191 days) between January 16 and July 25, 1996. Postdemonstration hydrochemical sampling continued until September 1996. The demonstration was conducted by collaborating researchers from Pacific Northwest National Laboratory (a) and Stanford University as part of an interim cleanup action at the base. Edwards Air Force Base and its environmental subcontractor, Earth Technology Corporation, as well as EG&G Environmental, holders of the commercial rights to the technology, were also significant contributors to the demonstration.

Control technologies for soil vapor extraction at petroleum hydrocarbon impacted sites -- Regulatory challenges to system operations

International Nuclear Information System (INIS)

Cacossa, K.F.; Campbell, G.E.; Devine, K.

1995-01-01

Soil vapor extraction (SVE) is frequently used to remediate soils impacted by petroleum hydrocarbons. Four technologies have proven to be viable methods to control the off-gas emissions from SVE systems, namely, internal combustion, thermal oxidation, catalytic oxidation, and granular activated carbon adsorption. The optimal range of influent vapor concentrations for system operation differs for each of the technologies. Over the past several years the authors have worked proactively with the state regulatory community to develop general, all inclusive air pollution control permits which allow for the potential use of all four technologies over the life of the permit. Private industry has similarly worked with the state regulators to develop a less labor intensive sampling/monitoring procedure. Actual system performances, which were monitored using summa canisters and field equipment, provided the basis for the new procedure. System performance data indicated that field sampling with portable hydrocarbon analyzers, such as flame ionization detectors (FID), was preferable over the use of summa canister sampling. In addition, to reduce the costs associated with the analysis of samples, the new SVE monitoring protocol also reduced the number of system monitoring visits. These reductions equated into a cost effective, yet environmentally sound SVE system monitoring programs. Finally, the authors have worked with the regulatory community to establish permit limitations which allow operational flexibility

The Rush to Remediate: Long Term Performance Favors Passive Systems at SRS

International Nuclear Information System (INIS)

Hoffman, D.; Cauthen, K.; Beul, R. R.

2003-01-01

The purpose of this paper is to describe the long-term performance of groundwater remediation systems at SRS and compare active versus passive systems. The presentation will focus on the limited effectiveness of active pump and treat systems and share the experience with more passive and natural systems such as soil vapor extraction, barometric pumping, bioremediation, and phytoremediation. Three remediation projects are presented. In each case the waste source is capped with clay or synthetic barriers; however, extensive groundwater contamination remains. The first project features the cleanup of the largest plume in the United States. The second project entails solvent and vinyl chloride remediation of groundwater beneath a hazardous waste landfill. The third project discusses tritium containment from a 160-acre radioactive waste disposal area. Special emphasis is placed on performance data from alternate technology cleanup. The goals are to share remediation data, successes and lessons learned, while making a case for passive systems use in groundwater remediation

Cost studies of thermally enhanced in situ soil remediation technologies

International Nuclear Information System (INIS)

Bremser, J.; Booth, S.R.

1996-05-01

This report describes five thermally enhanced technologies that may be used to remediate contaminated soil and water resources. The standard methods of treating these contaminated areas are Soil Vapor Extraction (SVE), Excavate ampersand Treat (E ampersand T), and Pump ampersand Treat (P ampersand T). Depending on the conditions at a given site, one or more of these conventional alternatives may be employed; however, several new thermally enhanced technologies for soil decontamination are emerging. These technologies are still in demonstration programs which generally are showing great success at achieving the expected remediation results. The cost savings reported in this work assume that the technologies will ultimately perform as anticipated by their developers in a normal environmental restoration work environment. The five technologies analyzed in this report are Low Frequency Heating (LF or Ohmic, both 3 and 6 phase AC), Dynamic Underground Stripping (DUS), Radio Frequency Heating (RF), Radio Frequency Heating using Dipole Antennae (RFD), and Thermally Enhanced Vapor Extraction System (TEVES). In all of these technologies the introduction of heat to the formation raises vapor pressures accelerating contaminant evaporation rates and increases soil permeability raising diffusion rates of contaminants. The physical process enhancements resulting from temperature elevations permit a greater percentage of volatile organic compound (VOC) or semi- volatile organic compound (SVOC) contaminants to be driven out of the soils for treatment or capture in a much shorter time period. This report presents the results of cost-comparative studies between these new thermally enhanced technologies and the conventional technologies, as applied to five specific scenarios

DNAPL Surface Chemistry: Its Impact on DNAPL Distribution in the Vadose Zone and its Manipulation to Enhance Remediation

Energy Technology Data Exchange (ETDEWEB)

Suan Power; Stefan Grimberg; Miles Denham

2003-06-16

The remediation of DNAPLs in subsurface environments is often limited by the heterogeneous distribution of the organic fluid. The fraction of DNAPL that is in the high conductivity regions of the subsurface can often be recovered relatively easily, although DNAPL in lower conductivity regions is much more difficult to extract, either through direct pumping or remediation measures based on interface mass transfer. The distribution of DNAPL within the vadose zone is affected by a complex interplay of heterogeneities in the porous matrix and the interfacial properties defining the interactions among all fluid and solid phases. Decreasing the interfacial tension between a DNAPL and water in the vadose zone could change the spreading of the DNAPL, thereby increase the surface area for mass transfer and the effectiveness of soil vapor extraction remediation.

Remediation of soils, sediments and sludges by extraction with organic solvents

NARCIS (Netherlands)

Noordkamp, E.R.

1999-01-01

Remediation of contaminated soils, sediments and sludges by extraction with organic solvents is still in the initial stages of development. So far hardly any scientific research has been carried out into this approach. Therefore, the main objective of the present investigation was to study

In-situ treatment of hydrocarbons contamination through enhanced bio-remediation and two phase extraction system

International Nuclear Information System (INIS)

Aglietto, I.; Brunero Bronzin, M.

2005-01-01

It happens frequently to find industrial site affected by contamination of subsoil and groundwater with consequent presence of free phase product floating on the water table. The remediation technologies in this case shall be properly selected and coordinated in a way that the interactions between each activities will help to decontaminate the site. The case study deals with an industrial site located near Turin, in Italy, of about 50 hectares of extension where has been found an area of about 4000 square meters with contamination of subsoil and groundwater. The compounds with higher concentrations are petroleum hydrocarbons found both in soil and in groundwater. Another big problem is represented by the presence of a layer of free product floating on the water table with a maximum measured thickness of 70 cm; this situation can be considered in fact one of the major difficulty in management of selected remediation technologies because the complete recover of the free phase is a priority for any kind of remediation system to apply subsequently. The present work is based upon the selection and implementation of a multiple treatment for definitive remediation of subsoil and groundwater. Free product recovery has been faced with a two-phase extraction technology, then for the remediation of subsoil we implemented a bio-venting system to improve biodegradation processes and finally for groundwater treatment we apply an enhanced in situ bio-remediation injecting oxygen release compounds directly into the aquifer. To reach these choices we have to pass through a complex activity of investigation of the site made up of more than 40 sampling point, 8 monitoring wells, about 140 analysis on subsoil samples and 10 on groundwater samples and one well used for an aquifer test. The preliminary design of the remediation system was therefore based on an extensive site characterization that included geological and geochemical, microbiological and hydrological data, together with

Natural Remediation at Savannah River Site

International Nuclear Information System (INIS)

Lewis, C. M.; Van Pelt, R.

2002-01-01

Natural remediation is a general term that includes any technology or strategy that takes advantage of natural processes to remediate a contaminated media to a condition that is protective of human health and the environment. Natural remediation techniques are often passive and minimally disruptive to the environment. They are generally implemented in conjunction with traditional remedial solutions for source control (i.e., capping, stabilization, removal, soil vapor extraction, etc.). Natural remediation techniques being employed at Savannah River Site (SRS) include enhanced bio-remediation, monitored natural attenuation, and phytoremediation. Enhanced bio-remediation involves making nutrients available and conditions favorable for microbial growth. With proper precautions and feeding, the naturally existing microbes flourish and consume the contaminants. Case studies of enhanced bio-remediation include surface soils contaminated with PCBs and pesticides, and Volatile Organic Compound (VOC) contamination in both the vadose zone and groundwater. Monitored natural attenuation (MNA) has been selected as the preferred alternative for groundwater clean up at several SRS waste units. Successful implementation of MNA has been based on demonstration that sources have been controlled, groundwater modeling that indicates that plumes will not expand or reach surface water discharge points at levels that exceed regulatory limits, and continued monitoring. Phytoremediation is being successfully utilized at several SRS waste units. Phytoremediation involves using plants and vegetation to uptake, break down, or manage contaminants in groundwater or soils. Case studies at SRS include managing groundwater plumes of tritium and VOCs with pine trees that are native to the area. Significant decreases in tritium discharge to a site stream have been realized in one phytoremediation project. Studies of other vegetation types, methods of application, and other target contaminants are

Remediation of sandy soils contaminated with hydrocarbons and halogenated hydrocarbons by soil vapour extraction.

Science.gov (United States)

Albergaria, José Tomás; Alvim-Ferraz, Maria da Conceição M; Delerue-Matos, Cristina

2012-08-15

This paper presents the study of the remediation of sandy soils containing six of the most common contaminants (benzene, toluene, ethylbenzene, xylene, trichloroethylene and perchloroethylene) using soil vapour extraction (SVE). The influence of soil water content on the process efficiency was evaluated considering the soil type and the contaminant. For artificially contaminated soils with negligible clay contents and natural organic matter it was concluded that: (i) all the remediation processes presented efficiencies above 92%; (ii) an increase of the soil water content led to a more time-consuming remediation; (iii) longer remediation periods were observed for contaminants with lower vapour pressures and lower water solubilities due to mass transfer limitations. Based on these results an easy and relatively fast procedure was developed for the prediction of the remediation times of real soils; 83% of the remediation times were predicted with relative deviations below 14%. Copyright © 2012 Elsevier Ltd. All rights reserved.

Feasibility Study of the Use of Thiosulfate as Extractant Agent in the Electrokinetic Remediation of a Soil Contaminated by Mercury from Almadén

DEFF Research Database (Denmark)

Subires-Muñoz, José Diego; García-Rubio, Ana; Vereda-Alonso, Carlos

2010-01-01

Natural soils are rather complex, making the predictability of the behavior of some remediation techniques very complicated. In this paper, the remediation of a Hg contaminated soil close to Almadén using a thiosulfate solution as extractant agent is studied. In addition, the use of the BCR...... extraction procedure before and after the remediation was performed. Once again, a clear relationship between the remediation and the extraction results are observed, giving further support to the idea that BCR can be used as a reasonable tool for feasibility studies of EKR among other remediation techniques....

Investigation of Pore Scale Processes That Affect Soil Vapor Extraction. Final Technical Report EMSP 70045

International Nuclear Information System (INIS)

Valocchi, Albert J.; Werth, Charles W.; Webb, Andrew W.

2004-01-01

Dense nonaqueous phase liquid (DNAPL) contamination in the vadose zone is a significant problem at Department of Energy sites. Soil vapor extraction (SVE) is commonly used to remediate DNAPLs from the vadose zone. In most cases, a period of high recovery has been followed by a sustained period of low recovery. This behavior has been attributed to multiple processes including slow interphase mass transfer, retarded vapor phase transport, and diffusion from unswept zones of low permeability. This research project used a combination of laboratory experimentation and mathematical modeling to determine how these various processes interact to limit the removal of DNAPL components in heterogeneous porous media during SVE. Our results were applied to scenarios typical of the carbon tetrachloride spill zone at the Hanford Site. Our results indicate that: (a) the initial distribution of the spilled DNAPL (i.e., the spill-zone architecture) has a major influence upon the performance of any subsequent SVE operations; (b) while the pattern of higher and lower conductivity soil zones has an important impact upon spill zone architecture, soil moisture distribution plays an even larger role when there are large quantities of co-disposed waste-water (as in the Hanford scenario); (c) depending upon soil moisture dynamics, liquid DNAPL that is trapped by surrounding water is extremely difficult to remove by SVE; (d) natural barometric pumping can remove a large amount of the initial DNAPL mass for spills occurring close to the land surface, and hence the initial spilled inventory will be over-estimated if this process is neglected

Integrated vacuum extraction/pneumatic soil fracturing system for remediation of low permeability soil

International Nuclear Information System (INIS)

Plaines, A.L.; Piniewski, R.J.; Yarbrough, G.D.

1994-01-01

There is wide use of vacuum extraction to remove volatile and semi-volatile organic compounds (VOCs) from unsaturated soil. At sites with soil of low permeability, VOC extraction rates may not be sufficient to meet soil clean-up objectives within the desired time frame. During vacuum extraction in low permeability soil, the diffusion rates of VOCs through the soil matrix may limit VOC removal rates. An increase in the number of subsurface paths for advective flow through the contaminated zone results in a larger mass of contaminant being removed in a shorter time frame, accelerating site remediation. One technique for increasing the number of subsurface flow paths is Terra Vac's process of pneumatic soil fracturing (PSF). In this process, pressurized air is injected into the subsurface, creating micro-fractures for the vacuum extraction system to withdraw contaminants. Similar to hydraulic fracturing techniques long used in the petroleum industry for increasing yield from oil and gas production wells, this technique has applications for soil remediation in low permeability conditions. Two case studies, one in Louisiana at a gasoline service station and one at a manufacturing plant in New York, are presented

[Removal of volatile organic compounds in soils by soil vapor extraction (SVE)].

Science.gov (United States)

Yin, Fu-xiang; Zhang, Sheng-tian; Zhao, Xin; Feng, Ke; Lin, Yu-suo

2011-05-01

An experiment study has been carried out to investigate effects of the diameter of soil columns, the size of soil particulate and different contaminants on efficiency of simulated soil vapor extraction (SVE). Experiments with benzene, toluene, ethylbenzene and n-propylbenzene contaminated soils showed that larger bottom area/soil height (S/H) of the columns led to higher efficiency on removal of contaminants. Experiments with contaminated soils of different particulate size showed that the efficiency of SVE decreased with increases in soil particulate size, from 10 mesh to between 20 mesh and 40 mesh and removal of contaminants in soils became more difficult. Experiments with contaminated soils under different ventilation rates suggested that soil vapor extraction at a ventilation rate of 0.10 L x min(-1) can roughly remove most contaminants from the soils. Decreasing of contaminants in soils entered tailing stages after 12 h, 18 h and 48 h for benzene, toluene and ethylbenzene, respectively. Removal rate of TVOCs (Total VOCs) reached a level as high as 99.52%. The results of the experiment have indicated that molecule structure and properties of the VOCs are also important factors which have effects on removal rates of the contaminants. Increases in carbon number on the benzene ring, decreases in vapor pressure and volatile capability resulted in higher difficulties in soil decontamination. n-propylbenzene has a lower vapor pressure than toluene and ethylbenzene which led to a significant retard effect on desorption and volatilization of benzene and ethylbenzene.

The use of high vacuum soil vapor extraction to improve contaminant recovery from ground water zones of low transmissivity

International Nuclear Information System (INIS)

Brown, A.; Farrow, J.R.C.; Burgess, W.

1996-01-01

This study examines the potential for enhancing hydrocarbon contaminant mass recovery from ground water using high vacuum soil vapor extraction (SVE). The effectiveness of this form of remediation is compared with the effectiveness of conventional pump-and-treat. This study focuses on the performance of a high vacuum SVE system at two ground water monitoring wells (MW-17 and MW-65b) at a site in Santa Barbara, California, US. The site is a highly characterized site with vadose zone and ground water petroleum hydrocarbon contamination (gasoline). The ground water wells are located beyond a defined area of vadose zone soil contamination. Ground water hydrocarbon contamination [light non-aqueous phase liquid (LNAPL) and dissolved phase] is present at each of the wells. the ground water wells have been part of a low-flow, pump-and-treat, ground water treatment system (GWTS) since August, 1986. The low transmissivity of the aquifer sediments prevent flow rates above approximately 0.02 gpm (0.01 l/min) per well

Subsurface Interim Measures/Interim Remedial Action Plan and Decision Document for the 903 Pad, Mound, and East Trenches Areas (Operable Unit No. 2)

International Nuclear Information System (INIS)

1992-01-01

The Department of Energy (DOE) is pursuing an Interim Measure/Interim Remedial Action (IM/IRA) at the 903 Pad, Mound, and East Trenches Areas (Operable Unit No. 2) at the Rocky Flats Plant (RFP). This MIRA is to be conducted to provide information that will aid in the selection and design of final remedial actions at OU2 that will address removal of suspected free-phase volatile organic compound (VOC) contamination. The Plan involves investigating the removal of residual free-phase VOCs by in situ vacuum-enhanced vapor extraction technology at 3 suspected VOC source areas within OU2. VOC-contaminated vapors extracted from the subsurface would be treated by granular activated carbon (GAC) adsorption and discharged. The Plan also includes water table depression, when applicable at the test sites, to investigate the performance of vapor extraction technology in the saturated zone. The Plan provides for treatment of any contaminated ground water recovered during the IM/IRA at existing RFP treatment facilities. The proposed MVIRA Plan is presented in the document entitled ''Proposed Subsurface Interim Measures/Interim Remedial Action Plan/Environmental Assessment and Decision Document, 903 Pad, Mound, and East Trenches Areas, Operable Unit No. 2, '' dated 20 March 1992. Information concerning the proposed Subsurface IM/IRA was presented during a DOE Quarterly Review meeting held on 07 April 1992 and a public meeting held on 07 May 1992, at the Marriott Hotel in Golden, Colorado. The Responsiveness Summary presents DOE's response to all comments received at the public meeting, as well as those mailed to date to DOE during the public comment period

Remediation of soils contaminated with particulate depleted uranium by multi stage chemical extraction

Energy Technology Data Exchange (ETDEWEB)

Crean, Daniel E. [Immobilisation Science Laboratory, Department of Materials Science and Engineering, The University of Sheffield (United Kingdom); Centre for Radiochemistry Research, School of Chemistry, The University of Manchester (United Kingdom); Livens, Francis R.; Sajih, Mustafa [Centre for Radiochemistry Research, School of Chemistry, The University of Manchester (United Kingdom); Stennett, Martin C. [Immobilisation Science Laboratory, Department of Materials Science and Engineering, The University of Sheffield (United Kingdom); Grolimund, Daniel; Borca, Camelia N. [Swiss Light Source, Paul Scherrer Institute, Villigen (Switzerland); Hyatt, Neil C., E-mail: n.c.hyatt@sheffield.ac.uk [Immobilisation Science Laboratory, Department of Materials Science and Engineering, The University of Sheffield (United Kingdom)

2013-12-15

Highlights: • Batch leaching was examined to remediate soils contaminated with munitions depleted uranium. • Site specific maximum extraction was 42–50% total U in single batch with NH{sub 4}HCO{sub 3}. • Analysis of residues revealed partial leaching and secondary carbonate phases. • Sequential batch leaching alternating between NH{sub 4}HCO{sub 3} and citric acid was designed. • Site specific extraction was increased to 68–87% total U in three batch steps. -- Abstract: Contamination of soils with depleted uranium (DU) from munitions firing occurs in conflict zones and at test firing sites. This study reports the development of a chemical extraction methodology for remediation of soils contaminated with particulate DU. Uranium phases in soils from two sites at a UK firing range, MOD Eskmeals, were characterised by electron microscopy and sequential extraction. Uranium rich particles with characteristic spherical morphologies were observed in soils, consistent with other instances of DU munitions contamination. Batch extraction efficiencies for aqueous ammonium bicarbonate (42–50% total DU extracted), citric acid (30–42% total DU) and sulphuric acid (13–19% total DU) were evaluated. Characterisation of residues from bicarbonate-treated soils by synchrotron microfocus X-ray diffraction and X-ray absorption spectroscopy revealed partially leached U(IV)-oxide particles and some secondary uranyl-carbonate phases. Based on these data, a multi-stage extraction scheme was developed utilising leaching in ammonium bicarbonate followed by citric acid to dissolve secondary carbonate species. Site specific U extraction was improved to 68–87% total U by the application of this methodology, potentially providing a route to efficient DU decontamination using low cost, environmentally compatible reagents.

Toluene removal from sandy soils via in situ technologies with an emphasis on factors influencing soil vapor extraction.

Science.gov (United States)

Amin, Mohammad Mehdi; Hatamipour, Mohammad Sadegh; Momenbeik, Fariborz; Nourmoradi, Heshmatollah; Farhadkhani, Marzieh; Mohammadi-Moghadam, Fazel

2014-01-01

The integration of bioventing (BV) and soil vapor extraction (SVE) appears to be an effective combination method for soil decontamination. This paper serves two main purposes: it evaluates the effects of soil water content (SWC) and air flow rate on SVE and it investigates the transition regime between BV and SVE for toluene removal from sandy soils. 96 hours after air injection, more than 97% removal efficiency was achieved in all five experiments (carried out for SVE) including 5, 10, and 15% for SWC and 250 and 500 mL/min for air flow rate on SVE. The highest removal efficiency (>99.5%) of toluene was obtained by the combination of BV and SVE (AIBV: Air Injection Bioventing) after 96 h of air injection at a constant flow rate of 250 mL/min. It was found that AIBV has the highest efficiency for toluene removal from sandy soils and can remediate the vadose zone effectively to meet the soil guideline values for protection of groundwater.

Toluene Removal from Sandy Soils via In Situ Technologies with an Emphasis on Factors Influencing Soil Vapor Extraction

Directory of Open Access Journals (Sweden)

Mohammad Mehdi Amin

2014-01-01

Full Text Available The integration of bioventing (BV and soil vapor extraction (SVE appears to be an effective combination method for soil decontamination. This paper serves two main purposes: it evaluates the effects of soil water content (SWC and air flow rate on SVE and it investigates the transition regime between BV and SVE for toluene removal from sandy soils. 96 hours after air injection, more than 97% removal efficiency was achieved in all five experiments (carried out for SVE including 5, 10, and 15% for SWC and 250 and 500 mL/min for air flow rate on SVE. The highest removal efficiency (>99.5% of toluene was obtained by the combination of BV and SVE (AIBV: Air Injection Bioventing after 96 h of air injection at a constant flow rate of 250 mL/min. It was found that AIBV has the highest efficiency for toluene removal from sandy soils and can remediate the vadose zone effectively to meet the soil guideline values for protection of groundwater.

EXTRACTION, RECOVERY, AND BIOSTABILITY OF EDTA FOR REMEDIATION OF HEAVY METAL-CONTAMINATED SOIL. (R825549C052)

Science.gov (United States)

Chelation removal of heavy metals from contaminated soil is seen as a viable remediation technique. A useful chelating agent should be strong, reusable, and biostable during metal extraction and recovery operations. This work tested the extraction, recovery, and biostability o...

Remediation of the Wells G & H Superfund Site, Woburn, Massachusetts.

Science.gov (United States)

Bair, E Scott; Metheny, Maura A

2002-01-01

Remediation of ground water and soil contamination at the Wells G & H Superfund Site, Woburn, Massachusetts, uses technologies that reflect differences in hydrogeologic settings, concentrations of volatile organic compounds (VOCs), and costs of treatment. The poorly permeable glacial materials that overlie fractured bedrock at the W.R. Grace property necessitate use of closely spaced recovery wells. Contaminated ground water is treated with hydrogen peroxide and ultraviolet (UV) oxidation. At UniFirst, a deep well completed in fractured bedrock removes contaminated ground water, which is treated by hydrogen peroxide, UV oxidation, and granular activated carbon (GAC). The remediation system at Wildwood integrates air sparging, soil-vapor extraction, and ground water pumping. Air stripping and GAC are used to treat contaminated water; GAC is used to treat contaminated air. New England Plastics (NEP) uses air sparging and soil-vapor extraction to remove VOCs from the unsaturated zone and shallow ground water. Contaminated air and water are treated using separate GAC systems. After nine years of operation at W.R. Grace and UniFirst, 30 and 786 kg, respectively, of VOCs have been removed. In three years of operation, 866 kg of VOCs have been removed at Wildwood. In 15 months of operation, 36 kg of VOCs were removed at NEP. Characterization work continues at the Olympia Nominee Trust, Whitney Barrel, Murphy Waste Oil, and Aberjona Auto Parts properties. Risk assessments are being finalized that address heavy metals in the floodplain sediments along the Aberjona River that are mobilized from the Industri-Plex Superfund Site located a few miles upstream.

In situ radio-frequency heating for soil remediation at a former service station: case study and general aspects

Energy Technology Data Exchange (ETDEWEB)

Huon, G.; Simpson, T.; Maini, G. [Ecologia Environmental Solutions Ltd., Sittingbourne, Kent (United Kingdom); Holzer, F.; Kopinke, F.D.; Roland, U. [Helmholtz Centre for Environmental Research - UFZ, Department of Environmental Engineering, Leipzig (Germany); Will, F. [Total UK, Watford (United Kingdom)

2012-08-15

In situ radio-frequency heating (ISRFH) was successfully applied during remediation of a former petrol station. Using a three-electrode array in combination with extraction wells for soil vapor extraction (SVE), pollution consisting mainly of benzene, toluene, ethylbenzene, xylenes, and mineral oil hydrocarbons (in total about 1100 kg) was eliminated from a chalk soil in the unsaturated zone. Specially designed rod electrodes allowed selective heating of a volume of approximately 480 m{sup 3}, at a defined depth, to a mean temperature of about 50 C. The heating drastically increased the extraction rates. After switching off ISRFH, SVE remained highly efficient for some weeks due to the heat-retaining properties of the soil. Comparison of an optimized regime of ISRFH/SVE with conventional ''cold'' SVE showed a reduction of remediation time by about 80 % while keeping the total energy consumption almost constant. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Soil remediation process and system

International Nuclear Information System (INIS)

Monlux, K.J.

1992-01-01

This patent describes a process for remediation of soil containing up to about 30,000 ppm hydrocarbon contaminants. It comprises: providing hydrocarbon-contaminated soil in a divided condition of minus 1 1/2 double-prime to a first confined zone where it is exposed to an open flame; heating while agitating the contaminated soil in an oxidizing atmosphere in the first zone to a temperature below soil ignition within a range of from about 375 degrees F. to about 750 degrees F. for a time sufficient to drive off as vapors a substantial percentage of the hydrocarbon contaminates from the soil; passing hot gases containing the hydrocarbon contaminates from the soil; passing hot gases containing the hydrocarbon vapors from the first zone to a second zone; recovering heat from the hot gases in the second zone to condense a substantial percentage of the hydrocarbon vapors as liquid hydrocarbons; recovering the liquid hydrocarbons; and removing the soil from the first zone as remediated soil having below about 1000 ppm hydrocarbon contaminants

Improving the two-step remediation process for CCA-treated wood. Part I, Evaluating oxalic acid extraction

Science.gov (United States)

Carol Clausen

2004-01-01

In this study, three possible improvements to a remediation process for chromated-copper-arsenate (CCA) treated wood were evaluated. The process involves two steps: oxalic acid extraction of wood fiber followed by bacterial culture with Bacillus licheniformis CC01. The three potential improvements to the oxalic acid extraction step were (1) reusing oxalic acid for...

Intrinsic remediation of JP-4 fuel in soil and ground water

International Nuclear Information System (INIS)

Schmithorst, W.L. Jr.; Vardy, J.A.

1995-01-01

Intrinsic remediation methods were employed to remediate soil and ground water contaminated by JP-4 fuel at the United States Coast Guard (USCG) Support Center facility in Elizabeth City, North Carolina. By the time the release was discovered, non-aqueous phase JP-4 fuel was detected in ground water over an area of approximately 8,000 square feet. In addition, concentrations of dissolved BTEX in ground water exceeded 5,000 microg/L. Tight clays present in the upper two meters of the aquifer, underlain by highly transmissive sands, prevented remediation of the JP-4 by conventional treatment methods. Therefore, a system of air injection and air extraction wells were installed that simultaneously depressed the water table and extracted hydrocarbon vapors. The conceptual idea, developed by the EPA RS Kerr Environmental Laboratory (RSKERL) in Ada, Oklahoma, is to stimulate rapid intrinsic biodegradation of the JP-4 fuel compounds. Subsequent biorespiration measurements indicated that the fuel compounds were being rapidly biodegraded. Upon removal of the non aqueous JP-4 compounds, an investigation was conducted to determine if the aquifer had an adequate assimilative capacity to support natural aerobic and anaerobic biodegradation of the contaminants. Analysis of ground water samples collected using a cone penetrometer and a direct-push sampling device indicate a sufficient concentration of electron acceptors to support natural biodegradation of the JP-4 compounds

Passive remediation of chlorinated volatile organic compounds using barometric pumping

International Nuclear Information System (INIS)

Rossabi, J.; Looney, B.B.; Dilek, C.A.E.; Riha, B.; Rohay, V.J.

1993-01-01

The purpose of the Savannah River Integrated Demonstration Program, sponsored by the Department of Energy, is to demonstrate new subsurface characterization, monitoring, and remediation technologies. The interbedded clay and sand layers at the Integrated Demonstration Site (IDS) are contaminated with chlorinated volatile organic compounds (CVOCs). Characterization studies show that the bulk of the contamination is located in the approximately 40 m thick vadose zone. The most successful strategy for removing contaminants of this type from this environment is vapor extraction alone or in combination with other methods such as air sparging or enhanced bioremediation. Preliminary work at the IDS has indicated that natural pressure differences between surface and subsurface air caused by surface barometric fluctuations can produce enough gas flow to make barometric pumping a viable method for subsurface remediation. Air flow and pressure were measured in wells that are across three stratigraphic intervals in the vadose zone' The subsurface pressures were correlated to surface pressure fluctuations but were damped and lagging in phase corresponding to depth and stratum permeability. Piezometer wells screened at lower elevations exhibited a greater phase lag and damping than wells screened at higher elevations where the pressure wave from barometric fluctuations passes through a smaller number of low permeable layers. The phase lag between surface and subsurface pressures results in significant fluxes through these wells. The resultant air flows through the subsurface impacts CVOC fate and transport. With the appropriate controls (e.g. solenoid valves) a naturally driven vapor extraction system can be implemented requiring negligible operating costs yet capable of a large CVOC removal rate (as much as 1--2 kg/day in each well at the IDS)

Design, demonstration and evaluation of a thermal enhanced vapor extraction system

International Nuclear Information System (INIS)

Phelan, J.; Reavis, B.; Swanson, J.

1997-08-01

The Thermal Enhanced Vapor Extraction System (TEVES), which combines powerline frequency heating (PLF) and radio frequency (RF) heating with vacuum soil vapor extraction, was used to effectively remove volatile organic compounds (VOCs) and semi-volatile organic compounds (SVOCs) from a pit in the chemical waste landfill (CWL) at Sandia National Laboratories (SNL) within a two month heating period. Volume average temperatures of 83 degrees C and 112 degrees C were reached for the PLF and RF heating periods, respectively, within the 15 ft x 45 ft x 18.5 ft deep treated volume. This resulted in the removal of 243 lb of measured toxic organic compounds (VOCs and SVOCs), 55 gallons of oil, and 11,000 gallons of water from the site. Reductions of up to 99% in total chromatographic organics (TCO) was achieved in the heated zone. Energy balance calculations for the PLF heating period showed that 36.4% of the heat added went to heating the soil, 38.5% went to evaporating water and organics, 4.2% went to sensible heat in the water, 7.1% went to heating the extracted air, and 6.6% was lost. For the RF heating period went to heating the soil, 23.5% went to evaporating water and organics, 2.4% went to sensible heat in the water, 7.5% went to heating extracted air, and 9.7% went to losses. Energy balance closure was 92.8% for the PLF heating and 98% for the RF heating. The energy input requirement per unit soil volume heated per unit temperature increase was 1.63 kWH/yd 3 -degrees C for PLF heating and 0.73 kWH/yd 3 degrees C for RF heating

Air sparging/high vacuum extraction to remove chlorinated solvents in groundwater and soil

International Nuclear Information System (INIS)

Phelan, J.M.; Gilliat, M.D.

1998-01-01

An air sparging and high vacuum extraction was installed as an alternative to a containment pump and treat system to reduce the long-term remediation schedule. The site is located at the DOE Mound facility in Miamisburg, Ohio, just south of Dayton. The air sparging system consists of 23 wells interspersed between 17 soil vapor extraction wells. The SVE system has extracted about 1,500 lbs of VOCs in five months. The air sparging system operated for about 6 weeks before shutdown due to suspected biochemical fouling. Technical data are presented on the operating characteristics of the system

Supercritical fluid extraction-capillary gas chromatography: on-line coupling with a programmed temperature vaporizer

NARCIS (Netherlands)

Houben, R.J.; Janssen, J.G.M.; Leclercq, P.A.; Rijks, J.A.; Cramers, C.A.M.G.

1990-01-01

A simple and versatile system is described for the on-line coupling of SFE to capillary GC. The interfacing consists of a programmed temperature vaporizer (PTV) injector. With this injector it is possible to combine solute trapping, elimination of a high flow of extraction fluid, and quantitative

Soil Vapor Extraction and Bioventing Test Work Plan for the MOGAS Site, Myrtle Beach Air Force Base, South Carolina

National Research Council Canada - National Science Library

1995-01-01

This work plan presents an evaluation of soil vapor extraction (SVE) and bioventing, and describes the SVE pilot scale and bioventing activities to be conducted to extract and treat soil gas at Installation Restoration Program (IRP...

Vapor Extraction/Bioventing Sequential Treatment of Soil Contaminated with Volatile and SemiVolatile Hydrocarbon Mixtures

NARCIS (Netherlands)

Malina, G.; Grotenhuis, J.T.C.; Rulkens, W.H.

2002-01-01

A cost-effective removal strategy was studied in bench-scale columns that involved vapor extraction and bioventing sequential treatment of toluene- and decane-contaminated soil. The effect of operating mode on treatment performance was examined at a continuous air flow and consecutively at two

The Effect of Mercury Vapor and the Role of Green Tea Extract on Brain Cells

Directory of Open Access Journals (Sweden)

Dhona Afriza

2013-09-01

Full Text Available Mercury is a wellknown toxic metal that is capable to induce free radical-induced oxidative stress. It can cause human disease including brain disorders. Objective: To identify the effect of mercury vapor inhalation on brain cells and the role of green tea extract (Camellia sinensis as antioxidant on the brain cells exposed to mercury. Methods: Fourty-eight male Mus musculus were divided into 8 groups, which were given treatment for 3 and 6 weeks. Group A did not receive any treatment and served as a negative control. Group B was a positive control exposed to Mercury. Group C was exposed to Mercury and treated with 26μg/g green tea extract. Group D was exposed to mercury and treated with 52μg/g green tea extract. All animals in the Group B, C, D were exposed to mercury through inhalation for 4 hours daily. The effect of mercury on the brain cells were examined histopathologically. Results: The numbers of necrotic cells counted in the green tea-treated mice group were significantly lower than those untreated group (p<0,05. Conclusion: Mercury vapor inhalation may cause necrosis on brain cells. Administration of green tea extract as an antioxidant reduced the amount of mercury-induced necrotic brain cells in mice.DOI: 10.14693/jdi.v20i2.151

Remediation of lead-contaminated soil with non-toxic biodegradable natural ligands extracted from soybean.

Science.gov (United States)

Lee, Yong-Woo; Kim, Chulsung

2012-01-01

Bench-scale soil washing studies were performed to evaluate the potential application of non-toxic, biodegradable extracted soybean-complexing ligands for the remediation of lead-contaminated soils. Results showed that, with extracted soybean-complexing ligands, lead solubility extensively increased when pH of the solution was higher than 6, and approximately 10% (500 mg/kg) of lead was removed from a rifle range soil. Two potential primary factors controlling the effectiveness of lead extraction from lead-contaminated soils with natural ligands are adsorption of extracted aqueous lead ions onto the ground soybean and the pH of the extraction solution. More complexing ligands were extracted from the ground soybean as the reaction pH increased. As a result, significantly higher lead extraction efficiency was observed under basic environments. In addition, less adsorption onto soybean was observed when the pH of the solution was higher than 7. Among two available Lewis base functional groups in the extracted soybean-complexing ligands such as carboxylate and the alpha-amino functional groups, the non-protonated alpha-amino functional groups may play an important role for the dissolution of lead from lead-contaminated soil through the formation of soluble lead--ligand complexes.

Melissa officinalis L. extract – an effective remedy

Directory of Open Access Journals (Sweden)

Karol Terlecki

2014-04-01

Full Text Available Lemon balm is the popular name of Melissa officinalis L. Melissa comes from the Greek word Mélissa meaning honeybee. Within the species were distinguished three subspecies: M. officinalis ssp. altissima Arcangeli, M. officinalis ssp. officinalis, and M. officinalis ssp. indora Boran. These are the plants from Lamiaceae group, native to the Mediterranean, but also widespread distributed in moderate and subtropical climate regions. M. officinalis is commonly used for nervous complaints, lower abdominal disorders and more recently in the treatment of Herpes simplex lesions. Leaves are pharmacopeia material. In the fresh herb a content of balm oil is 0.01-0.10% and in the dried leaves from 0.1% up to 0.3%. The main components of M. officinalis usually are: citronellal (approximately 40% of content of balm oil, citral, neral, linalool, flavonoids, chlorogenic, ferulic, rosmarinic (4% of content of balm oil and caffeic acid. The aim of the study was to analyze the literature date about the application of balm extract and oil in the contemporary medicine. The latest studies showed the evidence that the alcoholic lemon balm leaves extract has antihyperlipidemic and antihyperglycemic effects. Thus could be used for the treatment of diabetes mellitus type 2 or dyslipidemia by the activation of receptors PPAR playing the major role in glucose and lipids metabolism. Another importance of the lemon balm leaves extract is its antiviral activity, owes to rosmarinic acid. Melissa extract demonstrates high virucidal activity even at very low concentrations; it demonstrates low toxicity and inhibits HSV-1 attachment to host cells in vitro. The volatile oils included in lemon balm inhibit the replication of HSV-2. Moreover, the rosmarinic acid found out to be cytotoxic against Human Colon Cancer Cell Line. The substance contained in an alcoholic extract from M. officinalis turned out to be anti-proliferative and decrease in cell number neoplasmatic cell

Optimized remedial groundwater extraction using linear programming

International Nuclear Information System (INIS)

Quinn, J.J.

1995-01-01

Groundwater extraction systems are typically installed to remediate contaminant plumes or prevent further spread of contamination. These systems are expensive to install and maintain. A traditional approach to designing such a wellfield uses a series of trial-and-error simulations to test the effects of various well locations and pump rates. However, the optimal locations and pump rates of extraction wells are difficult to determine when objectives related to the site hydrogeology and potential pumping scheme are considered. This paper describes a case study of an application of linear programming theory to determine optimal well placement and pump rates. The objectives of the pumping scheme were to contain contaminant migration and reduce contaminant concentrations while minimizing the total amount of water pumped and treated. Past site activities at the area under study included disposal of contaminants in pits. Several groundwater plumes have been identified, and others may be present. The area of concern is bordered on three sides by a wetland, which receives a portion of its input budget as groundwater discharge from the pits. Optimization of the containment pumping scheme was intended to meet three goals: (1) prevent discharge of contaminated groundwater to the wetland, (2) minimize the total water pumped and treated (cost benefit), and (3) avoid dewatering of the wetland (cost and ecological benefits). Possible well locations were placed at known source areas. To constrain the problem, the optimization program was instructed to prevent any flow toward the wetland along a user-specified border. In this manner, the optimization routine selects well locations and pump rates so that a groundwater divide is produced along this boundary

Remediation of soils contaminated with particulate depleted uranium by multi stage chemical extraction.

Science.gov (United States)

Crean, Daniel E; Livens, Francis R; Sajih, Mustafa; Stennett, Martin C; Grolimund, Daniel; Borca, Camelia N; Hyatt, Neil C

2013-12-15

Contamination of soils with depleted uranium (DU) from munitions firing occurs in conflict zones and at test firing sites. This study reports the development of a chemical extraction methodology for remediation of soils contaminated with particulate DU. Uranium phases in soils from two sites at a UK firing range, MOD Eskmeals, were characterised by electron microscopy and sequential extraction. Uranium rich particles with characteristic spherical morphologies were observed in soils, consistent with other instances of DU munitions contamination. Batch extraction efficiencies for aqueous ammonium bicarbonate (42-50% total DU extracted), citric acid (30-42% total DU) and sulphuric acid (13-19% total DU) were evaluated. Characterisation of residues from bicarbonate-treated soils by synchrotron microfocus X-ray diffraction and X-ray absorption spectroscopy revealed partially leached U(IV)-oxide particles and some secondary uranyl-carbonate phases. Based on these data, a multi-stage extraction scheme was developed utilising leaching in ammonium bicarbonate followed by citric acid to dissolve secondary carbonate species. Site specific U extraction was improved to 68-87% total U by the application of this methodology, potentially providing a route to efficient DU decontamination using low cost, environmentally compatible reagents. Copyright © 2013 The Authors. Published by Elsevier B.V. All rights reserved.

Solvent extraction for remediation of manufactured gas plant sites

International Nuclear Information System (INIS)

Luthy, R.G.; Dzombak, D.A.; Peters, C.; Ali, M.A.; Roy, S.B.

1992-12-01

This report presents the results of an initial assessment of the feasibility of solvent extraction for removing coal tar from the subsurface or for treating contaminated soil excavated at manufactured gas plant (MGP) sites. In situ solvent extraction would involve injection, recovery, and reclamation for reinjection of an environmentally-benign, water-miscible solvent. Accelerated dissolution and removal of coaltar from the subsurface might be desirable as a remedial approach if excavation is not practical (e.g., the site underlies facilities in current use), direct pumping of coal tar is ineffective, and bioremediation is not feasible because of the presence of high concentrations of coal tar. Both laboratory experiments and engineering evaluations were performed to provide a basis for the initial feasibility assessment. Laboratory work included identification and evaluation of promising solvents, measurement of fundamental properties of coal tar-solvent-water systems, and measurement of rates of dissolution of coal tar in porous media into flowing solvent-water solutions. Engineering evaluations involved identification of common hydrogeologic features and contaminant distributions at MGP sites, and identification and evaluation of possible injection-recovery well deployment schemes. A coupled flow-chemistry model was developed for simulation of the in situ process and evaluation of the well deployment schemes. Results indicate that in situsolvent extraction may be able to recover a significant amount of coal tar from the subsurface within a reasonable time frame (on the order of one year or so) provided that subsurface conditions are conducive to process implementation. Some important implementation issues remain to be addressed

Simultaneous application of chemical oxidation and extraction processes is effective at remediating soil Co-contaminated with petroleum and heavy metals.

Science.gov (United States)

Yoo, Jong-Chan; Lee, Chadol; Lee, Jeung-Sun; Baek, Kitae

2017-01-15

Chemical extraction and oxidation processes to clean up heavy metals and hydrocarbon from soil have a higher remediation efficiency and take less time than other remediation processes. In batch extraction/oxidation process, 3% hydrogen peroxide (H 2 O 2 ) and 0.1 M ethylenediaminetetraacetic acid (EDTA) could remove approximately 70% of the petroleum and 60% of the Cu and Pb in the soil, respectively. In particular, petroleum was effectively oxidized by H 2 O 2 without addition of any catalysts through dissolution of Fe oxides in natural soils. Furthermore, heavy metals bound to Fe-Mn oxyhydroxides could be extracted by metal-EDTA as well as Fe-EDTA complexation due to the high affinity of EDTA for metals. However, the strong binding of Fe-EDTA inhibited the oxidation of petroleum in the extraction-oxidation sequential process because Fe was removed during the extraction process with EDTA. The oxidation-extraction sequential process did not significantly enhance the extraction of heavy metals from soil, because a small portion of heavy metals remained bound to organic matter. Overall, simultaneous application of oxidation and extraction processes resulted in highly efficient removal of both contaminants; this approach can be used to remove co-contaminants from soil in a short amount of time at a reasonable cost. Copyright © 2016 Elsevier Ltd. All rights reserved.

Preliminary analysis of NAPL behavior in soil-heated vapor extraction for in-situ environmental restoration

International Nuclear Information System (INIS)

Webb, S.W.; Phelan, J.M.

1995-01-01

Simulations of soil-heated vapor extraction have been performed to evaluate the NAPL removal performance as a function of borehole vacuum. The possibility of loss of NAPL containment, or NAPL migration into the unheated soil, is also evaluated in the simulations. A practical warning sign indicating migration of NAPL into the unheated zone is discussed

Remediation of PAH-contaminated soil using Achromobacter sp

International Nuclear Information System (INIS)

Cutright, T.J.; Lee, S.

1994-01-01

Several technologies have the potential to effectively remediate soil contaminated with polycyclic aromatic hydrocarbons (PAHs): solvent extraction, coal-oil agloflotation, supercritical extraction, and bioremediation. Due to the cost effectiveness and in-situ treatment capabilities of bioremediation, studies were conducted to determine the efficiency of Achromobacter sp. to remediate an industrial contaminated soil sample. Specifically, the use of three different mineral salt solutions in conjunction with the Achromobacter sp. was investigated. The molecular identification of the contaminants and their respective levels after remediation were determined using a Hewlett-Packard 1050 HPLC. Preliminary results show a 92% remediation for the use of two of the mineral salt solutions after 20 days' treatment. After 8 weeks, the remediation efficiency reached 99%. Bioremediation was also critically compared to the other potential remediation technologies

Design criteria for the 200-ZP-1 interim remedial measure

International Nuclear Information System (INIS)

Mudge, J.F.; Olson, J.W.

1995-08-01

The Interim Remedial Measure Proposed Plan for the 200-ZP-1 Operable Unit recommended a pump and treat action to contain contaminated groundwater and limit further degradation of groundwater due to elevated concentrations of carbon tetrachloride, chloroform, and trichloroethylene in the 200-ZP-1 Operable Unit. This design criteria document defines the Project. The Project encompasses: site preparation; development of groundwater wells for monitoring, extraction, and injection; extraction and injection equipment; construction of a treatment system with support buildings/utilities; management; engineering design, analysis, and reporting; and operation and maintenance. A groundwater pump and treat system, hereafter the System, will be composed of extraction wells, a piping network, treatment equipment, water storage, and injection wells. Based upon engineering judgment, the selected technology in the proposed plan (DOE-RL 1994a) is air stripping of the organic contaminants followed by vapor-phase adsorption onto granulated activated carbon (GAC); liquid-phase GAC may be required as a polishing step. The Treatment Equipment refers to air stripping towers, adsorption vessels, water pumps, air blowers, instrumentation, and control devices which will be procured as a turn-key system

Thermal enhanced vapor extraction systems: Design, application and performance prediction including contaminant behavior

International Nuclear Information System (INIS)

Phelan, J.M.; Webb, S.W.

1994-01-01

Soil heating technologies have been proposed as a method to accelerate contaminant removal from subsurface soils. These methods include the use of hot air, steam, conductive heaters, in-situ resistive heating and in-situ radiofrequency heating (Buettner et.al., EPA, Dev et.al., Heath et.al.). Criteria for selection of a particular soil heating technology is a complex function of contaminant and soil properties, and efficiency in energy delivery and contaminant removal technologies. The work presented here seeks to expand the understanding of the interactions of subsurface water, contaminant, heat and vacuum extraction through model predictions and field data collection. Field demonstration will involve the combination of two soil heating technologies (resistive and dielectric) with a vacuum vapor extraction system and will occur during the summer of 1994

Remediation techniques for heavy metal-contaminated soils: Principles and applicability.

Science.gov (United States)

Liu, Lianwen; Li, Wei; Song, Weiping; Guo, Mingxin

2018-08-15

Globally there are over 20millionha of land contaminated by the heavy metal(loid)s As, Cd, Cr, Hg, Pb, Co, Cu, Ni, Zn, and Se, with the present soil concentrations higher than the geo-baseline or regulatory levels. In-situ and ex-situ remediation techniques have been developed to rectify the heavy metal-contaminated sites, including surface capping, encapsulation, landfilling, soil flushing, soil washing, electrokinetic extraction, stabilization, solidification, vitrification, phytoremediation, and bioremediation. These remediation techniques employ containment, extraction/removal, and immobilization mechanisms to reduce the contamination effects through physical, chemical, biological, electrical, and thermal remedy processes. These techniques demonstrate specific advantages, disadvantages, and applicability. In general, in-situ soil remediation is more cost-effective than ex-situ treatment, and contaminant removal/extraction is more favorable than immobilization and containment. Among the available soil remediation techniques, electrokinetic extraction, chemical stabilization, and phytoremediation are at the development stage, while the others have been practiced at full, field scales. Comprehensive assessment indicates that chemical stabilization serves as a temporary soil remediation technique, phytoremediation needs improvement in efficiency, surface capping and landfilling are applicable to small, serious-contamination sites, while solidification and vitrification are the last remediation option. The cost and duration of soil remediation are technique-dependent and site-specific, up to $500ton -1 soil (or $1500m -3 soil or $100m -2 land) and 15years. Treatability studies are crucial to selecting feasible techniques for a soil remediation project, with considerations of the type and degree of contamination, remediation goals, site characteristics, cost effectiveness, implementation time, and public acceptability. Copyright © 2018 Elsevier B.V. All rights

Design, operations, and maintenance of the soil vapor extraction systems for the 200 West Area Carbon Tetrachloride Expedited Response Action

International Nuclear Information System (INIS)

Tranbarger, R.K.

1996-05-01

This report provides the design, operating, and maintenance guidelines for the soil vapor extraction (SVE) systems implemented as part of the 200 West Area Carbon Tetrachloride ERA. Additionally, this document provides general information regarding the ERA, the SVE system design, and the general approach towards soil vapor extraction. The remaining content of this document includes the following: regulatory compliance; summary of vadose zone physical and containment characteristics; past and present SVE system designs and potential design upgrades; general design and monitoring considerations for the SVE systems; descriptions of the SVE system components and their respective functions; safety requirements; operation of the SVE systems including startup, surveillances, shutdown, GAC canister changeouts, and wellfield characterization; monitoring requirements; SVE optimization; and instrument calibrations, preventive maintenance, and spare parts and site inventory requirements

Sustainable Remediation for Enhanced NAPL Recovery from Groundwater

Science.gov (United States)

Javaher, M.

2012-12-01

Sustainable remediation relates to the achievement of balance between environmental, social, and economic elements throughout the remedial lifecycle. A significant contributor to this balance is the use of green and sustainable technologies which minimize environmental impacts, while maximizing social and economic benefits of remedial implementation. To this end, a patented mobile vapor energy generation (VEG) technology has been developed targeting variable applications, including onsite soil remediation for unrestricted reuse and enhanced non-aqueous phase liquid (NAPL) recover at the water table. At the core of the mobile VEG technology is a compact, high efficiency vapor generator, which utilizes recycled water and propane within an entirely enclosed system to generate steam as high as 1100°F. Operating within a fully enclosed system and capturing all heat that is generated within this portable system, the VEG technology eliminates all emissions to the atmosphere and yields an undetected carbon footprint with resulting carbon dioxide concentrations that are below ambient levels. Introduction of the steam to the subsurface via existing wells results in a desired change in the NAPL viscosity and the interfacial tension at the soil, water, NAPL interface; in turn, this results in mobilization and capture of the otherwise trapped, weathered NAPL. Approved by the California Air Resources Control Board (and underlying Air Quality Management Districts) and applied in California's San Joaquin Valley, in-well heating of NAPLs trapped at the water table using the VEG technology has proven as effective as electrical resistivity heating (ERH) in changing the viscosity of and mobilizing NAPLs in groundwater in support of recovery, but has achieved these results while minimizing the remedial carbon footprint by 90%, reducing energy use by 99%, and reducing remedial costs by more than 95%. NAPL recovery using VEG has also allowed for completion of source removal historically

Arsenic Speciation and Extraction and the Significance of Biodegradable Acid on Arsenic Removal—An Approach for Remediation of Arsenic-Contaminated Soil

Science.gov (United States)

Nguyen Van, Thinh; Osanai, Yasuhito; Do Nguyen, Hai; Kurosawa, Kiyoshi

2017-01-01

A series of arsenic remediation tests were conducted using a washing method with biodegradable organic acids, including oxalic, citric and ascorbic acids. Approximately 80% of the arsenic in one sample was removed under the effect of the ascorbic and oxalic acid combination, which was roughly twice higher than the effectiveness of the ascorbic and citric acid combination under the same conditions. The soils treated using biodegradable acids had low remaining concentrations of arsenic that are primarily contained in the crystalline iron oxides and organic matter fractions. The close correlation between extracted arsenic and extracted iron/aluminum suggested that arsenic was removed via the dissolution of Fe/Al oxides in soils. The fractionation of arsenic in four contaminated soils was investigated using a modified sequential extraction method. Regarding fractionation, we found that most of the soil contained high proportions of arsenic (As) in exchangeable fractions with phosphorus, amorphous oxides, and crystalline iron oxides, while a small amount of the arsenic fraction was organic matter-bound. This study indicated that biodegradable organic acids can be considered as a means for arsenic-contaminated soil remediation.

Papers of the remediation technologies symposium 2005. CD-ROM ed.

International Nuclear Information System (INIS)

2005-01-01

This conference was attended by over 500 delegates and provided an opportunity for industry, practitioners, researchers and regulators to discuss technical issues in environmental remediation research and recent innovations in soil and groundwater remediation. Sessions included presentations on in-situ, groundwater and surface water remediation. Issues concerning phytoremediation, natural attenuation, extraction and commercial redevelopment were examined. The aim of the conference was also to provide a forum for innovators in remediation to present new work. Topics included hydrocarbon and salt contamination; engineered soil cover for management of salt impacted sites; remediation and revegetation of tar sands composite tailings containing naphthenic acids; sorption of oil sands naphthenic acid mixtures; denitrification as a natural attenuation mechanism; sampling methodologies; variability assessments; stabilization treatment technologies; remediation of coal wastes; bioreactor landfills; well blowouts in Alberta; soil remediation in coarse gravelly soils; diesel-contaminated aquifers; gasoline spill remediation; soil vapour extraction systems; technological solutions for erosion control and water clarification; and cost-effective in-situ remediation strategies. Fifty-two technical presentations were given, of which 27 have been catalogued separately for inclusion in this database

Papers of the remediation technologies symposium 2005. CD-ROM ed.

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-07-01

This conference was attended by over 500 delegates and provided an opportunity for industry, practitioners, researchers and regulators to discuss technical issues in environmental remediation research and recent innovations in soil and groundwater remediation. Sessions included presentations on in-situ, groundwater and surface water remediation. Issues concerning phytoremediation, natural attenuation, extraction and commercial redevelopment were examined. The aim of the conference was also to provide a forum for innovators in remediation to present new work. Topics included hydrocarbon and salt contamination; engineered soil cover for management of salt impacted sites; remediation and revegetation of tar sands composite tailings containing naphthenic acids; sorption of oil sands naphthenic acid mixtures; denitrification as a natural attenuation mechanism; sampling methodologies; variability assessments; stabilization treatment technologies; remediation of coal wastes; bioreactor landfills; well blowouts in Alberta; soil remediation in coarse gravelly soils; diesel-contaminated aquifers; gasoline spill remediation; soil vapour extraction systems; technological solutions for erosion control and water clarification; and cost-effective in-situ remediation strategies. Fifty-two technical presentations were given, of which 27 have been catalogued separately for inclusion in this database. tabs., figs.

Lab-scale tests on ISV vapor transport phenomena

International Nuclear Information System (INIS)

Farnsworth, R.K.; Gardner, B.M.

1996-01-01

In situ vitrification (ISV) is a promising technology for remediating buried waste sites and contaminated soil sites. However, concerns exist that low soil permeabilities may limit vapor transport away from the advancing melt front and cause a melt expulsion that breaches ISV containment. As a result, two ISV lab tests were conducted at the Idaho National Engineering Laboratory (INEL) using INEL soil (permeability: 10 -6 cm/s) and a low permeability (10 -10 cm/s) clay material. The clay test also had a ceramic tube inserted vertically through the center of the area being melted to provide one-dimensional data on vapor transport. Results confirm that low soil permeabilities can limit vapor transport away from the advancing ISV melt front. In addition, peak pressures inside the ceramic tube were significantly greater than those outside the tube, indicating the importance of horizontal vapor transport around the advancing ISV melt front

Automatic flow-through dynamic extraction: A fast tool to evaluate char-based remediation of multi-element contaminated mine soils.

Science.gov (United States)

Rosende, María; Beesley, Luke; Moreno-Jimenez, Eduardo; Miró, Manuel

2016-02-01

An automatic in-vitro bioaccessibility test based upon dynamic microcolumn extraction in a programmable flow setup is herein proposed as a screening tool to evaluate bio-char based remediation of mine soils contaminated with trace elements as a compelling alternative to conventional phyto-availability tests. The feasibility of the proposed system was evaluated by extracting the readily bioaccessible pools of As, Pb and Zn in two contaminated mine soils before and after the addition of two biochars (9% (w:w)) of diverse source origin (pine and olive). Bioaccessible fractions under worst-case scenarios were measured using 0.001 mol L(-1) CaCl2 as extractant for mimicking plant uptake, and analysis of the extracts by inductively coupled optical emission spectrometry. The t-test of comparison of means revealed an efficient metal (mostly Pb and Zn) immobilization by the action of olive pruning-based biochar against the bare (control) soil at the 0.05 significance level. In-vitro flow-through bioaccessibility tests are compared for the first time with in-vivo phyto-toxicity assays in a microcosm soil study. By assessing seed germination and shoot elongation of Lolium perenne in contaminated soils with and without biochar amendments the dynamic flow-based bioaccessibility data proved to be in good agreement with the phyto-availability tests. Experimental results indicate that the dynamic extraction method is a viable and economical in-vitro tool in risk assessment explorations to evaluate the feasibility of a given biochar amendment for revegetation and remediation of metal contaminated soils in a mere 10 min against 4 days in case of phyto-toxicity assays. Copyright © 2015 Elsevier B.V. All rights reserved.

Six-phase soil heating accelerates VOC extraction from clay soil

International Nuclear Information System (INIS)

Gauglitz, P.A.; Roberts, J.S.; Bergsman, T.M.; Caley, S.M.; Heath, W.O.; Miller, M.C.; Moss, R.W.; Schalla, R.; Jarosch, T.R.; Eddy-Dilek, C.A.

1994-08-01

Six-Phase Soil Heating (SPSH) was demonstrated as a viable technology for heating low permeability soils containing volatile organic contaminants. Testing was performed as part of the Volatile Organic Compounds in Non-Arid Soils Integrated Demonstration (VOC Non-Arid ID) at the Savannah River Site. The soil at the integrated demonstration site is contaminated with perchloroethylene (PCE) and trichloroethylene (TCE); the highest soil contamination occurs in clay-rich zones that are ineffectively treated by conventional soil vapor extraction due to the very low permeability of the clay. The SPSH demonstration sought to heat the clay zone and enhance the performance of conventional soil vapor extraction. Thermocouples at thirty locations quantified the areal and vertical heating within the treated zone. Soil samples were collected before and after heating to quantify the efficacy of heat-enhanced vapor extraction of PCE and TCE from the clay soil. Samples were taken (essentially every foot) from six wells prior to heating and adjacent to these wells after heating. Results show that contaminant removal from the clay zone was 99.7% (median) within the electrode array. Outside the array where the soil was heated, but to only 50 degrees C, the removal efficiency was 93%, showing that heating accelerated the removal of VOCs from the clay soil. The accelerated remediation resulted from effective heating of the contaminated clay zone by SPSH. The temperature of the clay zone increased to 100 degrees C after 8 days of heating and was maintained near 100 degrees C for 17 days. Electrical heating removed 19,000 gal of water from the soil as steam, with peak removal rate of 1,500 gpd of condensed steam

Proceedings of the remediation technologies symposium, RemTech 2010

International Nuclear Information System (INIS)

2010-01-01

In response to concerns regarding environmental impacts resulting from the extraction and production of fossil fuels, many oil and gas operators are seeking ways to reduce their environmental footprint and ensure the sustainable development of the industry. This symposium provided a forum to discuss innovations in soil and groundwater remediation. It highlighted recent work conducted in the field of contamination and remediation of industrial pollutant treatments. The conference technical sessions were entitled: British Columbia perspective; DND sites; hydrocarbons; oilfield remediation; Saskatchewan perspective; brownfields; miscellaneous; Quebec perspective; laboratory analysis and testing; landfill management and remediation; and, in-situ treatment methods. Some presentations also reviewed biological and non-biological treatment methods; thermal desorption; encapsulation; natural attenuation; multi-phase extraction; solar detoxification; electrochemical remediation; pre-treatment considerations; phytoremediation; and environmental management. The pre-conference workshop discussed methods of working with the federal government on future contaminated sites. The symposium featured 67 presentations, of which 26 have been catalogued separately for inclusion in this database

Proceedings of the remediation technologies symposium, RemTech 2010

Energy Technology Data Exchange (ETDEWEB)

NONE

2010-07-01

In response to concerns regarding environmental impacts resulting from the extraction and production of fossil fuels, many oil and gas operators are seeking ways to reduce their environmental footprint and ensure the sustainable development of the industry. This symposium provided a forum to discuss innovations in soil and groundwater remediation. It highlighted recent work conducted in the field of contamination and remediation of industrial pollutant treatments. The conference technical sessions were entitled: British Columbia perspective; DND sites; hydrocarbons; oilfield remediation; Saskatchewan perspective; brownfields; miscellaneous; Quebec perspective; laboratory analysis and testing; landfill management and remediation; and, in-situ treatment methods. Some presentations also reviewed biological and non-biological treatment methods; thermal desorption; encapsulation; natural attenuation; multi-phase extraction; solar detoxification; electrochemical remediation; pre-treatment considerations; phytoremediation; and environmental management. The pre-conference workshop discussed methods of working with the federal government on future contaminated sites. The symposium featured 67 presentations, of which 26 have been catalogued separately for inclusion in this database. tabs., figs.

The solvent absorption-extractive distillation (SAED) process for ethanol recovery from gas/vapor streams

Energy Technology Data Exchange (ETDEWEB)

Dale, M.C.

1993-12-31

A low energy system for ethanol recovery and dehydration has been developed. This system utilizes a solvent for (1) absorption of ethanol vapors, and then the same solvent for (2) extractive distillation. The ideal solvent for this process would have a high affinity for ethanol, and no affinity for water. Heavy alcohols such as dodecanol, and tridecanol, some phosphorals, and some fatty acids have been determined to meet the desired specifications. These solvents have the effect of making water more volatile than ethanol. Thus, a water stream is taken off initially in the dehydration column, and a near anhydrous ethanol stream is recovered from the ethanol/solvent stripper column. Thus the solvent serves dual uses (1) absorption media, and (2) dehydration media. The SAED process as conceptualized would use a solvent similar to solvents used for direct extractive separation of ethanol from aqueous ethanol solutions.

Remediation of copper in vineyards – A mini review

International Nuclear Information System (INIS)

Mackie, K.A.; Müller, T.; Kandeler, E.

2012-01-01

Viticulturists use copper fungicide to combat Downy Mildew. Copper, a non-degradable heavy metal, can accumulate in soil or leach into water sources. Its accumulation in topsoil has impacted micro and macro organisms, spurring scientists to research in situ copper removal methods. Recent publications suggest that microorganism assisted phytoextraction, using plants and bacteria to actively extract copper, is most promising. As vineyards represent moderately polluted sites this technique has great potential. Active plant extraction and chelate assisted remediation extract too little copper or risk leaching, respectively. However, despite interesting pot experiment results using microorganism assisted phytoextraction, it remains a challenge to find plants that primarily accumulate copper in their shoots, a necessity in vineyards where whole plant removal would be time consuming and financially cumbersome. Vineyard remediation requires a holistic approach including sustainable soil management, proper plant selection, increasing biodiversity and microorganisms. - Highlights: ► We describe copper distribution and availability in vineyards. ► We explain the environmental impact of copper on organisms, plants and processes. ► We detail possible remediation methods within vineyards. ► Microbially assisted phytoremediation is the most promising remediation method. ► A solution requires an interdisciplinary approach between plants, soil and vines. - This review is significant because it highlights prospective remediation methods usable in copper contaminated vineyards.

Soil Contamination and Remediation Strategies. Current research and future challenge

Science.gov (United States)

Petruzzelli, G.

2012-04-01

Soil contamination: the heritage of industrial development Contamination is only a part of a whole set of soil degradation processes, but it is one of paramount importance since soil pollution greatly influences the quality of water, food and human health. Soil contamination has been identified as an important issue for action in the European strategy for soil protection, it has been estimated that 3.5 million of sites are potentially contaminated in Europe. Contaminated soils have been essentially discovered in industrial sites landfills and energy production plants, but accumulation of heavy metals and organic compounds can be found also in agricultural land . Remediation strategies. from incineration to bioremediation The assessment of soil contamination is followed by remedial action. The remediation of contaminated soils started using consolidates technologies (incineration inertization etc.) previously employed in waste treatment,. This has contributed to consider a contaminated soil as an hazardous waste. This rough approximation was unfortunately transferred in many legislations and on this basis soil knowledge have been used only marginally in the clean up procedures. For many years soil quality has been identified by a value of concentration of a contaminant and excavation and landfill disposal of soil has been largely used. In the last years the knowledge of remediation technology has rapidly grown, at present many treatment processes appear to be really feasible at field scale, and soil remediation is now based on risk assessment procedures. Innovative technologies, largely dependent on soil properties, such as in situ chemical oxidation, electroremediation, bioventing, soil vapor extraction etc. have been successfully applied. Hazardous organic compounds are commonly treated by biological technologies, biorememdiation and phytoremediation, being the last partially applied also for metals. Technologies selection is no longer exclusively based on

Six phase soil heating. Innovative technology summary report

International Nuclear Information System (INIS)

1995-04-01

Six Phase Soil Heating (SPSH) was developed to remediate soils contaminated with volatile and semi-volatile organic compounds. SPSH is designed to enhance the removal of contaminates from the subsurface during soil vapor extraction. The innovation combines an emerging technology, six-phase electric heating, with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation systems for difficult soil and/or contaminate applications. This document describes the technology and reports on field demonstrations conducted at Savannah River and the Hanford Reservation

Proceedings of the remediation technologies symposium 2007

Energy Technology Data Exchange (ETDEWEB)

NONE

2007-07-01

This conference provided a forum to discuss the remediation of contaminated sites. It was attended by all industry sectors that have an interest in learning about technical issues in environmental remediation research and the latest innovations in soil and groundwater remediation and industrial pollutant treatments. Cost effective in-situ and ex-situ soil reclamation strategies were presented along with groundwater and surface water remediation strategies. The diversified sessions at this conference were entitled: regulatory update; Montreal Centre of Excellence in Brownfields Rehabilitation; soil and groundwater remediation through the Program of Energy Research and Development at Environment Canada; technology from the Netherlands; bioremediation; hydrocarbons; in-situ remediation; phytoremediation; salt management; unique locations; and, miscellaneous issues. Some areas and case studies covered in the presentations included: biological and non-biological treatments; thermal desorption; encapsulation; natural attenuation; multi-phase extraction; electrochemical remediation; and membrane technology. The conference featured 63 presentations, of which 23 have been catalogued separately for inclusion in this database. tabs., figs.

Proceedings of the remediation technologies symposium 2007

International Nuclear Information System (INIS)

2007-01-01

This conference provided a forum to discuss the remediation of contaminated sites. It was attended by all industry sectors that have an interest in learning about technical issues in environmental remediation research and the latest innovations in soil and groundwater remediation and industrial pollutant treatments. Cost effective in-situ and ex-situ soil reclamation strategies were presented along with groundwater and surface water remediation strategies. The diversified sessions at this conference were entitled: regulatory update; Montreal Centre of Excellence in Brownfields Rehabilitation; soil and groundwater remediation through the Program of Energy Research and Development at Environment Canada; technology from the Netherlands; bioremediation; hydrocarbons; in-situ remediation; phytoremediation; salt management; unique locations; and, miscellaneous issues. Some areas and case studies covered in the presentations included: biological and non-biological treatments; thermal desorption; encapsulation; natural attenuation; multi-phase extraction; electrochemical remediation; and membrane technology. The conference featured 63 presentations, of which 23 have been catalogued separately for inclusion in this database. tabs., figs

Work Plan for the Evaluation of Soil Vapor Extraction Using Internal Combustion Engine Technology at Site SS-42 Luke Air Force Base, Arizona

National Research Council Canada - National Science Library

1996-01-01

...). Luke AFB is one of several Air Force installations identified as prospective test sites to demonstrate the ICE system with advanced emission controls as part of a low-cost soil vapor extraction (SVE...

Soil treatment technologies combined

International Nuclear Information System (INIS)

Davis, K.J.; Russell, D.J.

1993-01-01

The Superfund Amendments and Reauthorization Act (SARA) presents a legislative mandate to select effective and long-term remediation options. SARA has spurred the development of innovative technologies and other remedial alternatives that can be applied to the diverse contaminated media at hazardous waste sites. Even though many treatment technologies have been investigated for use at hazardous waste sites, only a few have been used successfully. Soil vapor extraction and soil composting have achieved cleanup goals at sites with soils contaminated with solvents, aromatic hydrocarbons and petroleum derivatives. With the increased use of innovative on-site technologies, the integration of multiple technologies to remediate sites with complex contaminants becomes a viable and cost-effective remedial alternative. Soil vapor extraction and composting have been applied successfully as individual technologies at hazardous waste sites. An integration of these two technologies also has been used to remediate a complex contaminated site

Radioactive tank waste remediation focus area

International Nuclear Information System (INIS)

1996-08-01

EM's Office of Science and Technology has established the Tank Focus Area (TFA) to manage and carry out an integrated national program of technology development for tank waste remediation. The TFA is responsible for the development, testing, evaluation, and deployment of remediation technologies within a system architecture to characterize, retrieve, treat, concentrate, and dispose of radioactive waste stored in the underground stabilize and close the tanks. The goal is to provide safe and cost-effective solutions that are acceptable to both the public and regulators. Within the DOE complex, 335 underground storage tanks have been used to process and store radioactive and chemical mixed waste generated from weapon materials production and manufacturing. Collectively, thes tanks hold over 90 million gallons of high-level and low-level radioactive liquid waste in sludge, saltcake, and as supernate and vapor. Very little has been treated and/or disposed or in final form

Radioactive tank waste remediation focus area

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-08-01

EM`s Office of Science and Technology has established the Tank Focus Area (TFA) to manage and carry out an integrated national program of technology development for tank waste remediation. The TFA is responsible for the development, testing, evaluation, and deployment of remediation technologies within a system architecture to characterize, retrieve, treat, concentrate, and dispose of radioactive waste stored in the underground stabilize and close the tanks. The goal is to provide safe and cost-effective solutions that are acceptable to both the public and regulators. Within the DOE complex, 335 underground storage tanks have been used to process and store radioactive and chemical mixed waste generated from weapon materials production and manufacturing. Collectively, thes tanks hold over 90 million gallons of high-level and low-level radioactive liquid waste in sludge, saltcake, and as supernate and vapor. Very little has been treated and/or disposed or in final form.

ELECTROKINETIC REMEDIATION: BASICS AND TECHNOLOGY STATUS

Science.gov (United States)

Electrokinetic remediation, variably named as electrochemical soil processing, electromigration, electrokinetic decontamination or electroreclamation uses electric currents to extract radionuclides, heavy metals, certain organic compounds, or mixed inorganic species and some orga...

Electrochemical remediation of copper contaminated clay soils

Energy Technology Data Exchange (ETDEWEB)

Korolev, V.A.; Babakina, O.A.; Mitojan, R.A. [Moscow State Univ. (Russian Federation)

2001-07-01

The study objective focused on electrochemical remediation copper polluted soils in the presence of adjuvant substances and conditions that are more effective for the treatment. Some of these substances were studied in different researches. Moreover, authors obtained a result of extraction copper rate higher than 90%. In this connection the following problems were set: - Influence organic and inorganic substances on copper mobility in soil under the DC current. - Moisture effect on copper migration in clay. - Electrochemical remediation soils different mineralogical composition. - A washing conditions contribution to electrochemical remediation of soil from copper. - Accuracy rating experimental dates. (orig.)

Remediation of Soil at Nuclear Sites

International Nuclear Information System (INIS)

Holmes, R.; Boardman, C.; Robbins, R; Fox, Robert Vincent; Mincher, Bruce Jay

2000-01-01

As the major nuclear waste and decontamination and decommissioning projects progress, one of the remaining problems that faces the nuclear industry is that of site remediation. The range of contamination levels and contaminants is wide and varied and there is likely to be a significant volume of soil contaminated with transuranics and hazardous organic materials that could qualify as mixed TRU waste. There are many technologies that offer the potential for remediating this waste but few that tackle all or most of the contaminants and even fewer that have been deployed with confidence. This paper outlines the progress made in proving the ability of Supercritical Fluid Extraction as a method of remediating soil, classified as mixed (TRU) transuranic waste

Remediation of arsenic-contaminated soils and groundwaters

Science.gov (United States)

Peters, Robert W.; Frank, James R.; Feng, Xiandong

1998-01-01

An in situ method for extraction of arsenic contaminants from a soil medium and remediation of the medium including contacting the medium with an extractant solution, directing the solution within and through the medium, and collecting the solution and contaminants. The method can also be used for arsenate and/or arsenite removal.

Causal knowledge extraction by natural language processing in material science: a case study in chemical vapor deposition

Directory of Open Access Journals (Sweden)

Yuya Kajikawa

2006-11-01

Full Text Available Scientific publications written in natural language still play a central role as our knowledge source. However, due to the flood of publications, the literature survey process has become a highly time-consuming and tangled process, especially for novices of the discipline. Therefore, tools supporting the literature-survey process may help the individual scientist to explore new useful domains. Natural language processing (NLP is expected as one of the promising techniques to retrieve, abstract, and extract knowledge. In this contribution, NLP is firstly applied to the literature of chemical vapor deposition (CVD, which is a sub-discipline of materials science and is a complex and interdisciplinary field of research involving chemists, physicists, engineers, and materials scientists. Causal knowledge extraction from the literature is demonstrated using NLP.

PROBABILISTIC RISK ANALYSIS OF REMEDIATION EFFORTS IN NAPL SITES

Science.gov (United States)

Fernandez-Garcia, D.; de Vries, L.; Pool, M.; Sapriza, G.; Sanchez-Vila, X.; Bolster, D.; Tartakovsky, D. M.

2009-12-01

The release of non-aqueous phase liquids (NAPLs) such as petroleum hydrocarbons and chlorinated solvents in the subsurface is a severe source of groundwater and vapor contamination. Because these liquids are essentially immiscible due to low solubility, these contaminants get slowly dissolved in groundwater and/or volatilized in the vadoze zone threatening the environment and public health over a long period. Many remediation technologies and strategies have been developed in the last decades for restoring the water quality properties of these contaminated sites. The failure of an on-site treatment technology application is often due to the unnoticed presence of dissolved NAPL entrapped in low permeability areas (heterogeneity) and/or the remaining of substantial amounts of pure phase after remediation efforts. Full understanding of the impact of remediation efforts is complicated due to the role of many interlink physical and biochemical processes taking place through several potential pathways of exposure to multiple receptors in a highly unknown heterogeneous environment. Due to these difficulties, the design of remediation strategies and definition of remediation endpoints have been traditionally determined without quantifying the risk associated with the failure of such efforts. We conduct a probabilistic risk assessment of the likelihood of success of an on-site NAPL treatment technology that easily integrates all aspects of the problem (causes, pathways, and receptors). Thus, the methodology allows combining the probability of failure of a remediation effort due to multiple causes, each one associated to several pathways and receptors.

Selection of innovative technologies for the remediation of soils contaminated with radioactive and mixed wastes

International Nuclear Information System (INIS)

Steude, J.; Tucker, B.

1991-01-01

The remediation of sites containing radioactive and mixed wastes is in a period of rapid growth. The state of the art of remediation is progressing to handle the shortcomings of conventional pump and treat or disposal technologies. The objective of this paper is to review the status of selected innovative technologies which treat soils contaminated with radioactive and mixed waste. Technologies are generally classified as innovative if they are fully developed, but lack sufficient cost or performance data for comparison with conventional technologies. The Environmental Protection Agency recommends inclusion of innovative technologies in the RI/FS screening process if there is reason to believe that they would offer advantages in performance, implementability, cost, etc. This paper serves as a compilation of the pertinent information necessary to gain an overview of the selected innovative technologies to aid in the RI/F'S screening process. The innovative technologies selected for evaluation are listed below. Bioremediation, although innovative, was not included due to the combination of the vast amount of literature on this subject and the limited scope of this project. 1. Soil washing and flushing; 2. Low temperature thermal treatment; 3. Electrokinetics; 4. Infrared incineration; 5. Ultrasound; 6. In situ vitrification; 7. Soil vapor extraction; 8. Plasma torch slagging; 9. In situ hot air/steam extraction; 10. Cyclone reactor treatment; 11. In situ radio frequency; 12. Vegetative radionuclide uptake; and 13. In situ soil heating. The information provided on each technology includes a technical description, status, summary of results including types of contaminants and soils treated, technical effectiveness, feasibility and estimated cost

Effects of remediation train sequence on decontamination of heavy metal-contaminated soil containing mercury.

Science.gov (United States)

Hseu, Zeng-Yei; Huang, Yu-Tuan; Hsi, Hsing-Cheng

2014-09-01

When a contaminated site contains pollutants including both nonvolatile metals and Hg, one single remediation technology may not satisfactorily remove all contaminants. Therefore, in this study, chemical extraction and thermal treatment were combined as a remediation train to remove heavy metals, including Hg, from contaminated soil. A 0.2 M solution of ethylenediamine tetraacetic acid (EDTA) was shown to be the most effective reagent for extraction of considerable amounts of Cu, Pb, and Zn (> 50%). Hg removal was ineffective using 0.2 M EDTA, but thermogravimetric analysis suggested that heating to 550 degrees C with a heating rate of 5 degrees C/min for a duration of 1 hr appeared to be an effective approach for Hg removal. With the employment of thermal treatment, up to 99% of Hg could be removed. However executing thermal treatment prior to chemical extraction reduced the effectiveness of the subsequent EDTA extraction because nonvolatile heavy metals were immobilized in soil aggregates after the 550 degrees C treatment. The remediation train of chemical extraction followed by thermal treatment appears to remediate soils that have been contaminated by many nonvolatile heavy metals and Hg. Implications: A remediation train conjoining two or more techniques has been initialized to remove multiple metals. Better understandings of the impacts of treatment sequences, namely, which technique should be employed first on the soil properties and the decontamination efficiency, are in high demand. This study provides a strategy to remove multiple heavy metals including Hg from a contaminated soil. The interactions between thermal treatment and chemical extraction on repartitioning of heavy metals was revealed. The obtained results could offer an integrating strategy to remediate the soil contaminated with both heavy metals and volatile contaminants.

Determination of solvent concentration-dependent dispersion in the vapor extraction (VAPEX) process

Energy Technology Data Exchange (ETDEWEB)

Abukhalifeh, H.; Lohi, A.; Upreti, S. [Ryerson Polytechnic Univ., Toronto, ON (Canada)

2008-07-01

This paper presented the results of a computational algorithm that revealed the optimal conditions required for vapor extraction (VAPEX) for a solvent gas-heavy oil system. VAPEX is a promising recovery process because it requires low energy use and emits fewer greenhouse gases to the atmosphere compared to other enhanced oil recovery methods. The process is governed by the dispersion of solvent gases into heavy oil and bitumen. As such, it is essential to accurately determine solvent dispersion in VAPEX in order to effectively predict the amount and time scale of oil recovery, and to optimize field operations. VAPEX experiments were conducted in this study to determined the dispersion coefficient of a solvent as a function of its concentration in heavy oil and bitumen. The principles of variational calculus were used together with a mass transfer model of the experimental process. It was concluded that the oil production determined by the model should agree with its experimental counterpart, given the optimal gas dispersion versus concentration function.

A Lithium Vapor Box Divertor Similarity Experiment

Science.gov (United States)

Cohen, Robert A.; Emdee, Eric D.; Goldston, Robert J.; Jaworski, Michael A.; Schwartz, Jacob A.

2017-10-01

A lithium vapor box divertor offers an alternate means of managing the extreme power density of divertor plasmas by leveraging gaseous lithium to volumetrically extract power. The vapor box divertor is a baffled slot with liquid lithium coated walls held at temperatures which increase toward the divertor floor. The resulting vapor pressure differential drives gaseous lithium from hotter chambers into cooler ones, where the lithium condenses and returns. A similarity experiment was devised to investigate the advantages offered by a vapor box divertor design. We discuss the design, construction, and early findings of the vapor box divertor experiment including vapor can construction, power transfer calculations, joint integrity tests, and thermocouple data logging. Heat redistribution of an incident plasma-based heat flux from a typical linear plasma device is also presented. This work supported by DOE Contract No. DE-AC02-09CH11466 and The Princeton Environmental Institute.

Stakeholder acceptance analysis: In-well vapor stripping, in-situ bioremediation, gas membrane separation system (membrane separation)

International Nuclear Information System (INIS)

Peterson, T.

1995-12-01

This document provides stakeholder evaluations on innovative technologies to be used in the remediation of volatile organic compounds from soils and ground water. The technologies evaluated are; in-well vapor stripping, in-situ bioremediation, and gas membrane separation

Reconditioning perovskite films in vapor environments through repeated cation doping

Science.gov (United States)

Boonthum, Chirapa; Pinsuwan, Kusuma; Ponchai, Jitprabhat; Srikhirin, Toemsak; Kanjanaboos, Pongsakorn

2018-06-01

Perovskites have attracted considerable attention for application as high-efficiency photovoltaic devices owing to their low-cost and low-temperature fabrication. A good surface and high crystallinity are necessary for high-performance devices. We examine the negative effects of chemical ambiences on the perovskite crystal formation and morphology. The repeated cation doping (RCD) technique was developed to remedy these issues by gradually dropping methylammonium ions on top of about-to-form perovskite surfaces to cause recrystallization. RCD promotes pinhole-free, compact, and polygonal-like surfaces under various vapor conditions. Furthermore, it enhances the electronic properties and crystallization. The benefits of RCD extend beyond perovskites under vapor ambiences, as it can improve regular and wasted perovskites.

Regeneration strategies of polymers employed in ex-situ remediation of contaminated soil: Bioregeneration versus solvent extraction.

Science.gov (United States)

Mosca Angelucci, Domenica; Tomei, M Concetta

2015-08-15

In this study we evaluated the feasibility of two regeneration strategies of contaminated polymers employed for ex-situ soil remediation in a two-step process. Soil decontamination is achieved by sorption of the pollutants on the polymer beads, which are regenerated in a subsequent step. Tested soil was contaminated with a mixture of 4-chlorophenol and pentachlorophenol, and a commercial polymer, Hytrel, has been employed for extraction. Removal efficiencies of the polymer-soil extraction are in the range of 51-97% for a contact time ≤ 24 h. Two polymer regeneration strategies, solvent extraction and biological regeneration (realized in a two-phase partitioning bioreactor), were tested and compared. Performance was assessed in terms of removal rates and efficiencies and an economic analysis based on the operating costs has been performed. Results demonstrated the feasibility of both regeneration strategies, but the bioregeneration was advantageous in that provided the biodegradation of the contaminants desorbed from the polymer. Practically complete removal for 4-chlorophenol and up to 85% biodegradation efficiency for pentachlorophenol were achieved. Instead, in the solvent extraction, a relevant production (184-831 L kg(pol)(-1)) of a highly polluted stream to be treated or disposed of is observed. The cost analysis of the two strategies showed that the bioregeneration is much more convenient with operating costs of ∼12 €/kg(pol) i.e. more than one order of magnitude lower in comparison to ∼233 €/kg(pol) of the solvent extraction. Copyright © 2015 Elsevier Ltd. All rights reserved.

Biocomplementation of SVE to achieve clean up goals in soils contaminated with toluene and xylene

DEFF Research Database (Denmark)

Soares, Antonio; Pinho, Maria Teresa; Albergaria, José Tomás

2013-01-01

Soil vapor extraction (SVE) and bioremediation (BR) are two of the most common soil remediation technologies. Their application is widespread; however, both present limitations, namely related to the efficiencies of SVE on organic soils and to the remediation times of some BR processes. This work...

Vapor-Driven Propulsion of Catalytic Micromotors

Science.gov (United States)

Dong, Renfeng; Li, Jinxing; Rozen, Isaac; Ezhilan, Barath; Xu, Tailin; Christianson, Caleb; Gao, Wei; Saintillan, David; Ren, Biye; Wang, Joseph

2015-08-01

Chemically-powered micromotors offer exciting opportunities in diverse fields, including therapeutic delivery, environmental remediation, and nanoscale manufacturing. However, these nanovehicles require direct addition of high concentration of chemical fuel to the motor solution for their propulsion. We report the efficient vapor-powered propulsion of catalytic micromotors without direct addition of fuel to the micromotor solution. Diffusion of hydrazine vapor from the surrounding atmosphere into the sample solution is instead used to trigger rapid movement of iridium-gold Janus microsphere motors. Such operation creates a new type of remotely-triggered and powered catalytic micro/nanomotors that are responsive to their surrounding environment. This new propulsion mechanism is accompanied by unique phenomena, such as the distinct off-on response to the presence of fuel in the surrounding atmosphere, and spatio-temporal dependence of the motor speed borne out of the concentration gradient evolution within the motor solution. The relationship between the motor speed and the variables affecting the fuel concentration distribution is examined using a theoretical model for hydrazine transport, which is in turn used to explain the observed phenomena. The vapor-powered catalytic micro/nanomotors offer new opportunities in gas sensing, threat detection, and environmental monitoring, and open the door for a new class of environmentally-triggered micromotors.

Operable Unit 7-13/14 in situ thermal desorption treatability study work plan

International Nuclear Information System (INIS)

Shaw, P.; Nickelson, D.; Hyde, R.

1999-01-01

This Work Plan provides technical details for conducting a treatability study that will evaluate the application of in situ thermal desorption (ISTD) to landfill waste at the Subsurface Disposal Area (SDA) at the Idaho National Engineering and Environmental Laboratory (INEEL). ISTD is a form of thermally enhanced vapor vacuum extraction that heats contaminated soil and waste underground to raise its temperature and thereby vaporize and destroy most organics. An aboveground vapor vacuum collection and treatment system then destroys or absorbs the remaining organics and vents carbon dioxide and water to the atmosphere. The technology is a byproduct of an advanced oil-well thermal extraction program. The purpose of the ISTD treatability study is to fill performance-based data gaps relative to off-gas system performance, administrative feasibility, effects of the treatment on radioactive contaminants, worker safety during mobilization and demobilization, and effects of landfill type waste on the process (time to remediate, subsidence potential, underground fires, etc.). By performing this treatability study, uncertainties associated with ISTD as a selected remedy will be reduced, providing a better foundation of remedial recommendations and ultimate selection of remedial actions for the SDA

Lead immobilization in thermally remediated soils and igneous rocks

International Nuclear Information System (INIS)

Hickmott, D.D.; Carey, J.W.; Stimac, J.; Larocque, A.; Abell, R.; Gauerke, E.; Eppler, A.

1997-01-01

This is the final report for a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The principal goal of this project was to investigate the speciation of lead in the environment at LANL and to determine the feasibility of using thermal remediation methods to immobilize lead in the environment. Lead occurs as pyromorphite [Pb(PO 4 ) 3 (Cl, OH)], cerussite (PbCO 3 ) and galena (PbS) in vapor-phase-altered Bandelier Tuff samples. LANL soils primarily contain cerussite and PbO. Thermal remediation experiments at high temperatures (up to 400 C) suggest that thermal immobilization of highly-reactive Pb compounds in the environment may be feasible, but that this technique is not optimal for more refractory lead phases such as cerussite and PbO

Summary of a Gas Transport Tracer Test in the Deep Cerros Del Rio Basalts, Mesita del Buey, Los Alamos NM.

Energy Technology Data Exchange (ETDEWEB)

Stauffer, Philip H. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Rahn, Thomas A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Ortiz, John Philip [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Salazar, Larry Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Boukhalfa, Hakim [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Snyder, Emily Elisabeth [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2018-01-16

Here we describe results from a tracer test in the Cerros del Rio basalt beneath Mesita del Buey, Technical Area 54 (TA-54) at Los Alamos National Laboratory (LANL or the Laboratory). This report follows from plans outlined in our previous Tracer Test Work Plan (LANL 2016). These activities were conducted by LANL to further characterize subsurface properties of the Cerros del Rio basalts at Material Disposal Area (MDA) L (Figure 1.1-1). The work presented follows from the “Interim Measures Work Plan for Soil-Vapor Extraction of Volatile Organic Compounds from Material Disposal Area L, Technical Area 54, Revision 1,” submitted to the New Mexico Environment Department (NMED) in September 2014 (LANL 2014). Remediation of the MDA L vapor plume by soil-vapor extraction (SVE) is recommended as part of the final remedy in the “Corrective Measures Evaluation Report for Material Disposal Area L, Solid Waste Management Unit 54-006, at Technical Area 54, Revision 2” to meet a remedial action objective of preventing groundwater from being impacted above a regulatory standard by the transport of volatile organic compounds (VOCs) to groundwater through soil vapor (LANL 2011).

Remediation of Site of Decommissioning Research Reactor

Energy Technology Data Exchange (ETDEWEB)

Danilovich, A.S.; Ivanov, O.P.; Lemus, A.V.; Pavlenko, V.I.; Potapov, V.N.; Semenov, S.G.; Shisha, A.D.; Chesnokov, A.V. [National Research Center ' Kurchatov Institute' , 123182, Moscow (Russian Federation)

2014-07-01

In the world the most widespread method of soil decontamination consists of removing the contaminated upper layer and sending it for long-term controlled storage. However, implementation of this soil cleanup method for remediation of large contaminated areas would involve high material and financial expenditures, because it produces large amounts of radioactive waste demanding removal to special storage sites. Contaminated soil extraction and cleanup performed right on the spot of remediation activities represents a more advanced and economically acceptable method. Radiological separation of the radioactive soil allows reducing of amount of radwaste. Studies performed during the liquidation of the Chernobyl accident consequences revealed that a considerable fraction of radioactivity is accumulated in minute soil grains. So, the separation of contaminated soil by size fractions makes it possible to extract and concentrate the major share of radioactivity in the fine fraction. Based on these researches water gravity separation technology was proposed by Bochvar Institute. The method extracts the fine fraction from contaminated soil. Studies carried out by Bochvar Institute experts showed that, together with the fine fraction (amounting to 10-20% of the initial soil), this technology can remove up to 85-90% of contaminating radionuclides. The resulting 'dirty' soil fraction could be packaged into containers and removed as radwaste, and decontaminated fractions returned back to their extraction site. Use of radiological and water gravity separations consequently increases the productivity of decontamination facility. Efficiency of this technology applied for contaminated soil cleanup was confirmed in the course of remediation of the contaminated territories near decommissioning research reactor in the Kurchatov Institute. For soil cleaning purposes, a special facility implementing the technology of water gravity separation and radiometric monitoring of soil

Chemopreventive and remediation effect of Adansonia digitata L. Baobab (Bombacaceae) stem bark extracts in mouse model malaria.

Science.gov (United States)

Adeoye, A O; Bewaji, C O

2018-01-10

Adansonia digitata L. Baobab (Bombacaceae) solvent extracts have been reported to possess medicinal properties and are currently been used traditionally for the treatment of malaria and several other diseases and infection; however few reports exist in literature that provides supportive scientific evidence in favour of its medicinal use. This study investigated the efficacy of Adansonia digitata stem bark extract in offering protection against experimental malaria and also examined its remediation effect when administered after established infection. Weanling albino mice were used in the study. The mice were transfected intraperitonially with an inoculums size of 1× 10 7 of chloroquine susceptible strain of plasmodium berghei infected erythrocytes. Mechanisms of action of the extract were investigated by measuring the degree of tissue peroxidation and tissue antioxidant status. Severity of malaria was determined by measuring the serum C-reactive protein (CRP), tumor necrosis factor-alpha (TNF-α), and serum and tissue Alkaline phosphatase (ALP) activity. There was a significant increase in serum CRP, TNF-α concentrations and serum and tissue ALP activity in the control mice following Plasmodium berghei infection. All the treatment had effect on the growth of Plasmodium berghei parasites in mice. The extracts showed a significant dose dependent increase packed cell volume (PCV), percentage chemosupression/clearance and a significant decrease in percentage parasitemia at the two doses when administered after established infection. Methanolic extract (MEAD) at 400mg/kg exhibited the highest chemosupressive activity. The extract significantly reduced the degree of tissue peroxidation, increased the level of reduced glutathione (GSH), catalase and superoxide dismutase activity. Administration of the extract after established infection reduced serum CRP and TNF-α concentrations and serum and tissue ALP activity. Our study suggests that Adansonia digitata protects

Effect of soil organic matter on antimony bioavailability after the remediation process

International Nuclear Information System (INIS)

Nakamaru, Yasuo Mitsui; Martín Peinado, Francisco José

2017-01-01

We evaluated the long-term (18 year) and short-term (4 weeks) changes of Sb in contaminated soil with SOM increase under remediation process. In the Aznalcóllar mine accident (1998) contaminated area, the remediation measurement implemented the Guadiamar Green Corridor, where residual pollution is still detected. Soils of the re-vegetated area (O2) with high pH and high SOM content, moderately re-vegetated area (O1) and unvegetated area (C) were sampled. Soil pH, CEC, SOM amount and soil Sb forms were evaluated. Soil Sb was measured as total, soluble, exchangeable, EDTA extractable, acid oxalate extractable, and pyro-phosphate extractable fractions. Further, the short-term effect of artificial organic matter addition was also evaluated with incubation study by adding compost to the sampled soil from C, O1 and O2 areas. After 4 weeks of incubation, soil chemical properties and Sb forms were evaluated. In re-vegetated area (O2), soil total Sb was two times lower than in unvegetated area (C); however, soluble, exchangeable, and EDTA extractable Sb were 2–8 times higher. The mobile/bioavailable Sb increase was also observed after 4 weeks of incubation with the addition of compost. Soluble, exchangeable, and EDTA extractable Sb was increased 2–4 times by compost addition. By the linear regression analysis, the significantly related factors for soluble, exchangeable, and EDTA extractable Sb values were pH, CEC, and SOM, respectively. Soluble Sb increase was mainly related to pH rise. Exchangeable Sb should be bound by SOM-metal complex and increased with CEC. EDTA extractable fraction should be increased with increase of SOM as SOM-Fe associated Sb complex. From these results, it was shown that increase of SOM under natural conditions or application of organic amendment under remediation process should increase availability of Sb to plants. - Highlights: • The effect of SOM on Sb availability was evaluated after the remediation process. • Increase in SOM raised

Part 2: A field study of enhanced remediation of Toluene in the vadose zone using a nutrient solution

Science.gov (United States)

Tindall, J.A.; Weeks, E.P.; Friedel, M.

2005-01-01

The objective of this study was to test the effectiveness of a nitrate-rich nutrient solution and hydrogen peroxide (H2O2) to enhance in-situ microbial remediation of toluene in the unsaturated zone. Three sand-filled plots were tested in three phases (each phase lasting approximately 2 weeks). During the control phase, toluene was applied uniformly via sprinkler irrigation. Passive remediation was allowed to occur during this phase. A modified Hoagland nutrient solution, concentrated in 150 L of water, was tested during the second phase. The final phase involved addition of 230 moles of H2O2 in 150 L of water to increase the available oxygen needed for aerobic biodegradation. During the first phase, measured toluene concentrations in soil gas were reduced from 120 ppm to 25 ppm in 14 days. After the addition of nutrients during the second phase, concentrations were reduced from 90 ppm to about 8 ppm within 14 days, and for the third phase (H 2O2), toluene concentrations were about 1 ppm after only 5 days. Initial results suggest that this method could be an effective means of remediating a contaminated site, directly after a BTEX spill, without the intrusiveness and high cost of other abatement technologies such as bioventing or soil-vapor extraction. However, further tests need to be completed to determine the effect of each of the BTEX components. ?? Springer 2005.

DSMC simulations of vapor transport toward development of the lithium vapor box divertor concept

Science.gov (United States)

Jagoe, Christopher; Schwartz, Jacob; Goldston, Robert

2016-10-01

The lithium vapor divertor box concept attempts to achieve volumetric dissipation of the high heat efflux from a fusion power system. The vapor extracts the heat of the incoming plasma by ionization and radiation, while remaining localized in the vapor box due to differential pumping based on rapid condensation. Preliminary calculations with lithium vapor at densities appropriate for an NSTX-U-scale machine give Knudsen numbers between 0.01 and 1, outside both the range of continuum fluid dynamics and of collisionless Monte Carlo. The direct-simulation Monte Carlo (DSMC) method, however, can simulate rarefied gas flows in this regime. Using the solver contained in the OpenFOAM package, pressure-driven flows of water vapor will be analyzed. The use of water vapor in the relevant range of Knudsen number allows for a flexible similarity experiment to verify the reliability of the code before moving to tests with lithium. The simulation geometry consists of chains of boxes on a temperature gradient, connected by slots with widths that are a representative fraction of the dimensions of the box. We expect choked flow, sonic shocks, and order-of-magnitude pressure and density drops from box to box, but this expectation will be tested in the simulation and then experiment. This work is supported by the Princeton Environmental Institute.

76 FR 5370 - Potential Addition of Vapor Intrusion Component to the Hazard Ranking System

Science.gov (United States)

2011-01-31

... Estimated Costs to Remediate Existing Sites Exceed Current Funding Levels, and More Sites are Expected to Be.... Methods for incorporating vapor intrusion into the HRS while, to the extent possible, maintaining the... will also be able to sign up for a mailing list that will be used to distribute logistical information...

Uranium mill tailings remedial action technology

International Nuclear Information System (INIS)

Hartley, J.N.; Gee, G.W.

1984-01-01

The uranium milling process involves the hydrometallurgical extraction of uranium from ores and the resultant generation of large quantities of waste referred to as tailings. Uranium mill tailings have been identified as requiring remediation because they contain residual radioactive material that is not removed in the milling process. Potential radiation exposure can result from direct contact with the tailings, from radon gas emitted by the tailings, and from radioactive contamination of groundwater. As a result, the technology developed under the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action Project (UMTRAP) and the US Nuclear Regulatory Commission (NRC) Uranium Recovery Program have focused on radon control, groundwater contamination and the long-term protection of the containment system. This paper briefly summarizes the UMTRAP and NRC remedial action technology development. 33 references, 9 figures, 5 tables

Radon remediation of dwellings with suspended timber floors -case studies from the Building Research Establishment (UK)

International Nuclear Information System (INIS)

Welsh, P.; Stephen, R.

1994-01-01

Dwellings with suspended floors and high radon levels are proving difficult to remediate. This paper reports on the experience of the Building Research Establishment in dealing with such dwellings. Brief details of the remediation of 14 houses are given, and comparisons are made between the effectiveness of the different techniques adopted. Natural ventilation, mechanical supply ventilation and mechanical extract ventilation are three techniques that have been used successfully as radon remedial measures. Preliminary results suggest that supply ventilation is more effective than extract ventilation. (author)

Horizontal wells in subsurface remediation

International Nuclear Information System (INIS)

Losonsky, G.; Beljin, M.S.

1992-01-01

This paper reports on horizontal wells which offer an effective alternative to vertical wells in various environmental remediation technologies. Hydrogeological advantages of horizontal wells over vertical wells include a larger zone of influence, greater screen length, higher specific capacity and lower groundwater screen entrance velocity. Because of these advantages, horizontal wells can reduce treatment time and costs of groundwater recovery (pump-and-treat), in situ groundwater aeration (sparging) and soil gas extraction (vacuum extraction). Horizontal wells are also more effective than vertical wells in landfill leachate collection (under-drains), bioremediation, and horizontal grout injection

Uranium extraction in northern Bohemia by leaching and provisions for remediation of its adverse impacts on the environment

International Nuclear Information System (INIS)

Tomas, J.

1992-01-01

The problems of uranium extraction at the Straz pod Ralskem and Hamr sites in northern Bohemia are highlighted. The geological situation at the two deposits is described. At Hamr, uranium is mined conventionally, whereas at Straz, hydrochemical extraction is practised. The two deposits are located close to each other, they affect one another and affect adversely the rock environment. A remedial programme has been worked out, based on (i) abandoning deep mining at the Hamr 1 mine and shutting down the ore treatment plant, (ii) preparation of a membrane project to decontaminate the Turonian groundwater body and ore processing lagoons, (iii) sustaining a protective hydraulic barrier between the Hamr 1 mine and the chemical extraction site, (iv) design preparation and construction of a desalination station, (v) monitoring the Turonian drinking water quality, and (vi) preparation of technologies for a final separation and use of alum and inert leachates. The technology of thermal concentration by evaporation followed by concentrate treatment was chosen for the decontamination of the polluted waters. The entire decontamination of the deposits is expected to take 50 to 70 years. (J.B.). 1 tab., 3 figs

Natural bioventing remediation from tidal wave action at a field site

International Nuclear Information System (INIS)

Kampbell, D.H.; Kittel, J.A.

1996-01-01

A remediation research study has been implemented at a jet fuel spill site on an island airport. A buried pipeline fracture several years ago resulted in a fuel spill exceeding 160,000 gallons. The site hydrogeology is a fragmented coral matrix with fresh water overlying more dense salt water. Water table fluctuations of about two feet occur once every twelve hours from tidal action. The research approach being pursued is to recover free-phase floating petroleum liquid using vacuum-mediated subsurface skimming wells. The vacuum will create an active vadose zone aeration to enhance aerobic biodegradation processes and vaporization of fuel. Once the floating fuel is removed, a natural bioventing action caused by tidal oscillations will complete remediation of the spill site

The possible use of soluble humic substances for remediation of heavy metal polluted soils

DEFF Research Database (Denmark)

Borggaard, Ole K.; Jensen, Julie Katrine; Holm, Peter Engelund

2008-01-01

Polluted soil is a common and serious environmental problem. While reliable methods exist for cleaning soil contaminated by organic compounds through degradation, remediation of heavy metal polluted soils awaits an appropriate solution. This is because heavy metals are nondegradable and generally....... Therefore, the potential of soluble natural humic substances (HS) to extract heavy metals from contaminated soils is tested as an environmental friendly substitute for EDTA. A strongly polluted urban soil and a moderately polluted agricultural soil were extracted at neutral pH in batch mode by three HS...... extraction. Heavy metal extraction with dissolved HS is compared with EDTA at the same concentration and sequential extraction has been performed to identify extracted pools. The results indicate a clear potential of using HS solutions for remediation of heavy metal polluted soils, which is fortunate...

Demonstration of risk-based decision analysis in remedial alternative selection and design

International Nuclear Information System (INIS)

Evans, E.K.; Duffield, G.M.; Massmann, J.W.; Freeze, R.A.; Stephenson, D.E.

1993-01-01

This study demonstrates the use of risk-based decision analysis (Massmann and Freeze 1987a, 1987b) in the selection and design of an engineering alternative for groundwater remediation at a waste site at the Savannah River Site, a US Department of Energy facility in South Carolina. The investigation focuses on the remediation and closure of the H-Area Seepage Basins, an inactive disposal site that formerly received effluent water from a nearby production facility. A previous study by Duffield et al. (1992), which used risk-based decision analysis to screen a number of ground-water remediation alternatives under consideration for this site, indicated that the most attractive remedial option is ground-water extraction by wells coupled with surface water discharge of treated effluent. The aim of the present study is to demonstrate the iterative use of risk-based decision analysis throughout the design of a particular remedial alternative. In this study, we consider the interaction between two episodes of aquifer testing over a 6-year period and the refinement of a remedial extraction well system design. Using a three-dimensional ground-water flow model, this study employs (1) geostatistics and Monte Carlo techniques to simulate hydraulic conductivity as a stochastic process and (2) Bayesian updating and conditional simulation to investigate multiple phases of aquifer testing. In our evaluation of a remedial alternative, we compute probabilistic costs associated with the failure of an alternative to completely capture a simulated contaminant plume. The results of this study demonstrate the utility of risk-based decision analysis as a tool for improving the design of a remedial alternative through the course of phased data collection at a remedial site

Microorganisms in heavy metal bioremediation: strategies for applying microbial-community engineering to remediate soils

OpenAIRE

Jennifer L. Wood; Caixian Tang; Ashley E. Franks; Wuxing Liu

2016-01-01

The remediation of heavy-metal-contaminated soils is essential as heavy metals persist and do not degrade in the environment. Remediating heavy-metal-contaminated soils requires metals to be mobilized for extraction whilst, at the same time, employing strategies to avoid mobilized metals leaching into ground-water or aquatic systems. Phytoextraction is a bioremediation strategy that extracts heavy metals from soils by sequestration in plant tissues and is currently the predominant bioremediat...

The lithium vapor box divertor

International Nuclear Information System (INIS)

Goldston, R J; Schwartz, J; Myers, R

2016-01-01

It has long been recognized that volumetric dissipation of the plasma heat flux from a fusion power system is preferable to its localized impingement on a material surface. Volumetric dissipation mitigates both the anticipated very high heat flux and intense particle-induced damage due to sputtering. Recent projections to a tokamak demonstration power plant suggest an immense upstream parallel heat flux, of order 20 GW m −2 , implying that fully detached operation may be a requirement for the success of fusion power. Building on pioneering work on the use of lithium by Nagayama et al and by Ono et al as well as earlier work on the gas box divertor by Watkins and Rebut, we present here a concept for a lithium vapor box divertor, in which lithium vapor extracts momentum and energy from a fusion-power-plant divertor plasma, using fully volumetric processes. At the high powers and pressures that are projected this requires a high density of lithium vapor, which must be isolated from the main plasma in order to avoid lithium build-up on the chamber walls or in the plasma. Isolation is achieved through a powerful multi-box differential pumping scheme available only for condensable vapors. The preliminary box-wise calculations are encouraging, but much more work is required to demonstrate the practical viability of this scheme, taking into account at least 2D plasma and vapor flows within and between the vapor boxes and out of the vapor boxes to the main plasma. (paper)

Eisenia fetida avoidance behavior as a tool for assessing the efficiency of remediation of Pb, Zn and Cd polluted soil

International Nuclear Information System (INIS)

Udovic, Metka; Lestan, Domen

2010-01-01

Remediation by means of soil leaching with ethylenediaminetetraacetic acid (EDTA) is capable of extracting the most labile soil fractions, leaving the residual metals in biologically non-available forms. We evaluated the feasibility of the standardized earthworm (Eisenia fetida) avoidance test for assessing the efficiency of soil remediation of Pb, Zn and Cd polluted soil. Chemical extraction tests (six-step sequential extraction, toxicity characteristic leaching procedure, physiologically based extraction test, diethylenediaminepentaacetic acid extraction) indicated that the mobility, oral bioaccessibility and phytoavailability of Pb, Zn and Cd were consistently reduced. However, the avoidance test showed no significant avoidance of polluted soil in favor of that which had been remediated. Pb, Zn and Cd accumulation in E. fetida mirrored the decreasing pattern of metal potential bioavailability gained by leaching the soil with increasing EDTA concentrations. The calculated bioaccumulation factors indicated the possibility of underestimating the metal bioavailability in soil using chemical extraction tests. - Tests with indicator organisms should be used for a more meaningful and holistic assessment of metal biological availability in polluted and remediated soil.

Eisenia fetida avoidance behavior as a tool for assessing the efficiency of remediation of Pb, Zn and Cd polluted soil

Energy Technology Data Exchange (ETDEWEB)

Udovic, Metka [Centre for Soil and Environmental Science, Department of Agronomy, Biotechnical Faculty, University of Ljubljana, Jamnikarjeva 101, Sl-1000 Ljubljana (Slovenia); Lestan, Domen, E-mail: domen.lestan@bf.uni-lj.s [Centre for Soil and Environmental Science, Department of Agronomy, Biotechnical Faculty, University of Ljubljana, Jamnikarjeva 101, Sl-1000 Ljubljana (Slovenia)

2010-08-15

Remediation by means of soil leaching with ethylenediaminetetraacetic acid (EDTA) is capable of extracting the most labile soil fractions, leaving the residual metals in biologically non-available forms. We evaluated the feasibility of the standardized earthworm (Eisenia fetida) avoidance test for assessing the efficiency of soil remediation of Pb, Zn and Cd polluted soil. Chemical extraction tests (six-step sequential extraction, toxicity characteristic leaching procedure, physiologically based extraction test, diethylenediaminepentaacetic acid extraction) indicated that the mobility, oral bioaccessibility and phytoavailability of Pb, Zn and Cd were consistently reduced. However, the avoidance test showed no significant avoidance of polluted soil in favor of that which had been remediated. Pb, Zn and Cd accumulation in E. fetida mirrored the decreasing pattern of metal potential bioavailability gained by leaching the soil with increasing EDTA concentrations. The calculated bioaccumulation factors indicated the possibility of underestimating the metal bioavailability in soil using chemical extraction tests. - Tests with indicator organisms should be used for a more meaningful and holistic assessment of metal biological availability in polluted and remediated soil.

A review of centrifugal testing of gasoline contamination and remediation.

Science.gov (United States)

Meegoda, Jay N; Hu, Liming

2011-08-01

Leaking underground storage tanks (USTs) containing gasoline represent a significant public health hazard. Virtually undetectable to the UST owner, gasoline leaks can contaminate groundwater supplies. In order to develop remediation plans one must know the extent of gasoline contamination. Centrifugal simulations showed that in silty and sandy soils gasoline moved due to the physical process of advection and was retained as a pool of free products above the water table. However, in clayey soils there was a limited leak with lateral spreading and without pooling of free products above the water table. Amount leaked depends on both the type of soil underneath the USTs and the amount of corrosion. The soil vapor extraction (SVE) technology seems to be an effective method to remove contaminants from above the water table in contaminated sites. In-situ air sparging (IAS) is a groundwater remediation technology for contamination below the water table, which involves the injection of air under pressure into a well installed into the saturated zone. However, current state of the art is not adequate to develop a design guide for site implementation. New information is being currently generated by both centrifugal tests as well as theoretical models to develop a design guide for IAS. The petroleum contaminated soils excavated from leaking UST sites can be used for construction of highway pavements, specifically as sub-base material or blended and used as hot or cold mix asphalt concrete. Cost analysis shows that 5% petroleum contaminated soils is included in hot or cold mix asphalt concrete can save US$5.00 production cost per ton of asphalt produced.

A Review of Centrifugal Testing of Gasoline Contamination and Remediation

Directory of Open Access Journals (Sweden)

Jay N. Meegoda

2011-08-01

Full Text Available Leaking underground storage tanks (USTs containing gasoline represent a significant public health hazard. Virtually undetectable to the UST owner, gasoline leaks can contaminate groundwater supplies. In order to develop remediation plans one must know the extent of gasoline contamination. Centrifugal simulations showed that in silty and sandy soils gasoline moved due to the physical process of advection and was retained as a pool of free products above the water table. However, in clayey soils there was a limited leak with lateral spreading and without pooling of free products above the water table. Amount leaked depends on both the type of soil underneath the USTs and the amount of corrosion. The soil vapor extraction (SVE technology seems to be an effective method to remove contaminants from above the water table in contaminated sites. In-situ air sparging (IAS is a groundwater remediation technology for contamination below the water table, which involves the injection of air under pressure into a well installed into the saturated zone. However, current state of the art is not adequate to develop a design guide for site implementation. New information is being currently generated by both centrifugal tests as well as theoretical models to develop a design guide for IAS. The petroleum contaminated soils excavated from leaking UST sites can be used for construction of highway pavements, specifically as sub-base material or blended and used as hot or cold mix asphalt concrete. Cost analysis shows that 5% petroleum contaminated soils is included in hot or cold mix asphalt concrete can save US$5.00 production cost per ton of asphalt produced.

Vapor-fed bio-hybrid fuel cell.

Science.gov (United States)

Benyamin, Marcus S; Jahnke, Justin P; Mackie, David M

2017-01-01

Concentration and purification of ethanol and other biofuels from fermentations are energy-intensive processes, with amplified costs at smaller scales. To circumvent the need for these processes, and to potentially reduce transportation costs as well, we have previously investigated bio-hybrid fuel cells (FCs), in which a fermentation and FC are closely coupled. However, long-term operation requires strictly preventing the fermentation and FC from harming each other. We introduce here the concept of the vapor-fed bio-hybrid FC as a means of continuously extracting power from ongoing fermentations at ambient conditions. By bubbling a carrier gas (N 2 ) through a yeast fermentation and then through a direct ethanol FC, we protect the FC anode from the catalyst poisons in the fermentation (which are non-volatile), and also protect the yeast from harmful FC products (notably acetic acid) and from build-up of ethanol. Since vapor-fed direct ethanol FCs at ambient conditions have never been systematically characterized (in contrast to vapor-fed direct methanol FCs), we first assess the effects on output power and conversion efficiency of ethanol concentration, vapor flow rate, and FC voltage. The results fit a continuous stirred-tank reactor model. Over a wide range of ethanol partial pressures (2-8 mmHg), power densities are comparable to those for liquid-fed direct ethanol FCs at the same temperature, with power densities >2 mW/cm 2 obtained. We then demonstrate the continuous operation of a vapor-fed bio-hybrid FC with fermentation for 5 months, with no indication of performance degradation due to poisoning (of either the FC or the fermentation). It is further shown that the system is stable, recovering quickly from disturbances or from interruptions in maintenance. The vapor-fed bio-hybrid FC enables extraction of power from dilute bio-ethanol streams without costly concentration and purification steps. The concept should be scalable to both large and small

Adaptive remediation using portable treatment units

International Nuclear Information System (INIS)

Bahowick, S.; Folsom, E.; Pico, T.

1996-01-01

Lawrence Livermore National Laboratory (LLNL) is using adaptive remediation to optimize their environmental restoration strategy. Adaptive remediation uses hydrostratigraphic analysis to gain a better understanding of the subsurface characteristics, hydraulic tests to optimize contaminant transport models, and Portable Treatment Units (PTUs) as an alternative to fixed facilities. Hydrostratigraphic analysis is an optimization tool that improves the ability to identify and target contaminant migration pathways, identify the relationship between plumes and source areas, and better define hydraulic capture areas. Hydraulic tests, performed with PTUs, provide valuable data about subsurface characteristics. As clean up progresses, PTUs can be moved to the appropriate extraction wells to optimize contaminant mass removal. PTUs can also be placed to support innovative treatment technologies such as steam injection and microbial filters. Construction of PTUs will reduce by one-half the capital costs of building the rest of the fixed treatment system planned in the Record of Decision. Regulatory agencies are receptive to the use of the PTUs because the same treatment technology is being used and the PTUs will be able to clean up the plume cheaper and faster. Using adaptive remediation, LLNL is more effectively implementing remediation plans, improving cleanup time, and reducing project costs

Biochar based remediation of water and soil contaminated by phenanthrene and pentachlorophenol.

Science.gov (United States)

Rao, Maria A; Di Rauso Simeone, Giuseppe; Scelza, Rosalia; Conte, Pellegrino

2017-11-01

Phenanthrene (Phe) and pentachlorophenol (PCP) are classified as persistent organic pollutants and represent serious concern for the environment as they are toxic and ubiquitous. Biochar based remediation is an emerging technology used in water and soil contamination. In this study we used poplar (BP) and conifer (BC) biochars to remediate water and soil contaminated by Phe and PCP. BP and BC were able to remove completely either Phe or PCP from contaminated water within one to three days. When biochar was confined in a porous membrane, BC and BP maintained their sorption efficiency for several remediation cycles. However, in these conditions BC allowed faster Phe removal. In soil remediation experiments, addition of two biochar rates, i.e. 2.5 and 5 mg g -1 , strongly reduced Phe extractability (up to 2.7% of the initially added Phe with the larger BC dose). This was similar to the behavior observed when compost was applied in order to verify the role of soil organic matter in the fate of both contaminants. PCP extractability was reduced only up to 75% (in average) in all samples including those with compost amendment. Only larger amount of biochar (20 and 50 mg g -1 ) allowed reduction of the extractable PCP and nullified phytotoxicity of the contaminant. Copyright © 2017 Elsevier Ltd. All rights reserved.

Mobile vapor recovery and vapor scavenging unit

International Nuclear Information System (INIS)

Stokes, C.A.; Steppe, D.E.

1991-01-01

This patent describes a mobile anti- pollution apparatus, for the recovery of hydrocarbon emissions. It comprises a mobile platform upon which is mounted a vapor recovery unit for recovering vapors including light hydrocarbons, the vapor recovery unit having an inlet and an outlet end, the inlet end adapted for coupling to an external source of hydrocarbon vapor emissions to recover a portion of the vapors including light hydrocarbons emitted therefrom, and the outlet end adapted for connection to a means for conveying unrecovered vapors to a vapor scavenging unit, the vapor scavenging unit comprising an internal combustion engine adapted for utilizing light hydrocarbon in the unrecovered vapors exiting from the vapor recovery unit as supplemental fuel

Comparison of the environmental impacts of two remediation technologies used at hydrocarbon contaminated sites

International Nuclear Information System (INIS)

Viikala, R.; Kuusola, J.

2000-01-01

Investigation and remediation of contaminated sites has rapidly increased in Finland during the last decade. Public organisations as well as private companies are investigating and remediating their properties, e.g. redevelopment or business transactions. Also numerous active and closed gasoline stations have been investigated and remediated during the last few years. Usually the contaminated sites are remediated to limit values regardless of the risk caused by contamination. The limit values currently used in Finland for hydrocarbon remediation at residential or ground water areas are 300 mg/kg of total hydrocarbons and 100 mg/kg of volatile hydrocarbons (boiling point < appr. 200 deg C). Additionally, compounds such as aromatic hydrocarbons have specific limit values. Remediation of hydrocarbon contaminated sites is most often carried out by excavating the contaminated soil and taking it to a landfill by lorries. As distances from the sites to landfills are generally rather long, from tens of kilometres to few hundred kilometres, it is evident that this type of remediation has environmental impacts. Another popular technology used at sites contaminated by volatile hydrocarbons is soil vapour extraction (SVE). SVE is a technique of inducing air flow through unsaturated soils by vapour extraction wells or pipes to remove organic contaminants with an off-gas treatment system. The purpose of this study was to evaluate some of the environmental impacts caused by remediation of hydrocarbon contaminated soil. Energy consumption and air emissions related remedial activities of the two methods were examined in this study. Remediation of the sites used in this study were carried out by Golder Associates Oy in different parts of Finland in different seasons. Evaluation was made by using life cycle assessment based approach

Green Remediation Best Management Practices: Implementing In Situ Thermal Technologies

Science.gov (United States)

Over recent years, the use of in situ thermal technologies such as electrical resistance heating, thermal conductive heating, and steam enhanced extraction to remediate contaminated sites has notably increased.

Extraction of negative lithium ions from a lithium-containing hydrogen plasma

International Nuclear Information System (INIS)

Wada, M.; Sasao, M.

1996-01-01

Negative lithium ions (Li - ) were extracted from a 6-cm-diam 7-cm-long negative hydrogen ion (H - ) source to simulate the condition of Li - extraction from a Li vapor introduced ion source for the neutral beam heating. The amount of the Li - current extracted from a hydrogen plasma with Li vapor was comparable to that extracted from a pure Li plasma. However, the amount of the H - current decreased as the H 2 gas pressure in the source decreased due to a getter-pump effect of Li during the introduction of Li vapor. A heat shield installed to keep a high wall temperature was effective in mitigating the pressure decrease. However, the H - current extracted from the ion source equipped with the heat shield became 20% of the original value, as Li vapor was injected into the ion source. copyright 1996 American Institute of Physics

To fail is human: remediating remediation in medical education.

Science.gov (United States)

Kalet, Adina; Chou, Calvin L; Ellaway, Rachel H

2017-12-01

Remediating failing medical learners has traditionally been a craft activity responding to individual learner and remediator circumstances. Although there have been moves towards more systematic approaches to remediation (at least at the institutional level), these changes have tended to focus on due process and defensibility rather than on educational principles. As remediation practice evolves, there is a growing need for common theoretical and systems-based perspectives to guide this work. This paper steps back from the practicalities of remediation practice to take a critical systems perspective on remediation in contemporary medical education. In doing so, the authors acknowledge the complex interactions between institutional, professional, and societal forces that are both facilitators of and barriers to effective remediation practices. The authors propose a model that situates remediation within the contexts of society as a whole, the medical profession, and medical education institutions. They also outline a number of recommendations to constructively align remediation principles and practices, support a continuum of remediation practices, destigmatize remediation, and develop institutional communities of practice in remediation. Medical educators must embrace a responsible and accountable systems-level approach to remediation if they are to meet their obligations to provide a safe and effective physician workforce.

Chemical remediation of wood treated with micronised, nano or soluble copper preservatives

Science.gov (United States)

Saip Nami Kartal; Evren Terzi; Bessie Woodward; Carol A. Clausen; Stan T. Lebow

2013-01-01

The potential for extraction of copper from wood treated with micronised, nano or soluble forms of copper has been evaluated in view of chemical remediation. In focus were EDTA, oxalic acid, bioxalate, and D-gluconic acid for extraction of Cu from treated wood. Bioxalate extractions for 24 h resulted in Cu removal over 95% for all tested...

Microorganisms in heavy metal bioremediation: strategies for applying microbial-community engineering to remediate soils

Directory of Open Access Journals (Sweden)

Jennifer L. Wood

2016-06-01

Full Text Available The remediation of heavy-metal-contaminated soils is essential as heavy metals persist and do not degrade in the environment. Remediating heavy-metal-contaminated soils requires metals to be mobilized for extraction whilst, at the same time, employing strategies to avoid mobilized metals leaching into ground-water or aquatic systems. Phytoextraction is a bioremediation strategy that extracts heavy metals from soils by sequestration in plant tissues and is currently the predominant bioremediation strategy investigated for remediating heavy-metal-contaminated soils. Although the efficiency of phytoextraction remains a limiting feature of the technology, there are numerous reports that soil microorganisms can improve rates of heavy metal extraction.This review highlights the unique challenges faced when remediating heavy-metal-contaminated soils as compared to static aquatic systems and suggests new strategies for using microorganisms to improve phytoextraction. We compare how microorganisms are used in soil bioremediation (i.e. phytoextraction and water bioremediation processes, discussing how the engineering of microbial communities, used in water remediation, could be applied to phytoextraction. We briefly outline possible approaches for the engineering of soil communities to improve phytoextraction either by mobilizing metals in the rhizosphere of the plant or by promoting plant growth to increase the root-surface area available for uptake of heavy metals. We highlight the technological advances that make this research direction possible and how these technologies could be employed in future research.

Technology selection for remediation of lead and hydrocarbon contaminated soil

International Nuclear Information System (INIS)

Richardson, K.E.; Sparks, G.M.

1993-01-01

This paper presents a methodology for selection of a technology for remediation of 70,000 tons of lead and hydrocarbon impacted soil resulting from an excavation at the Mobil Torrance Refinery. This methodology resulted from over two years of extensive research and technology evaluation. Twelve technologies and combination of technologies were evaluated, which often included bench scale testing, to determine the most cost effective and technically feasible remediation option. The results of the studies for each technology are discussed and presented in tabular form. The technologies investigated include: fixation/stabilization, soil washing, solvent washing, heap leach extraction, froth flotation, bioremediation, thermal desorption, electrokinetic extraction, asphalt incorporation, vitrification, off-site treatment, and off-site disposal. The associated costs and technical feasibility of each of the remediation options evaluated are presented. Laboratory analyses of the excavated soil indicate hydrocarbons range from non-detect to 11,000 ppm with an average of 2,600 ppm, soluble lead (CA test-not TCLP) range from 1.4 ppm to 100 ppm with an average of 29 ppm, and low levels of organic lead are present. Average grain size of the soil ranges from number-sign 200 to number-sign 120 mesh, and permeability averages 10--4 cm/sec. Significant odors, likely caused by hydrogen sulfide and thiophenes, were detected when the soil was excavated and control of odors during the remediation phase is a critical concern

Remedial Process Optimization and Green In-Situ Ozone Sparging for Treatment of Groundwater Impacted with Petroleum Hydrocarbons

Science.gov (United States)

Leu, J.

2012-12-01

A former natural gas processing station is impacted with TPH and BTEX in groundwater. Air sparging and soil vapor extraction (AS/AVE) remediation systems had previously been operated at the site. Currently, a groundwater extraction and treatment system is operated to remove the chemicals of concern (COC) and contain the groundwater plume from migrating offsite. A remedial process optimization (RPO) was conducted to evaluate the effectiveness of historic and current remedial activities and recommend an approach to optimize the remedial activities. The RPO concluded that both the AS/SVE system and the groundwater extraction system have reached the practical limits of COC mass removal and COC concentration reduction. The RPO recommended an in-situ chemical oxidation (ISCO) study to evaluate the best ISCO oxidant and approach. An ISCO bench test was conducted to evaluate COC removal efficiency and secondary impacts to recommend an application dosage. Ozone was selected among four oxidants based on implementability, effectiveness, safety, and media impacts. The bench test concluded that ozone demand was 8 to 12 mg ozone/mg TPH and secondary groundwater by-products of ISCO include hexavalent chromium and bromate. The pH also increased moderately during ozone sparging and the TDS increased by approximately 20% after 48 hours of ozone treatment. Prior to the ISCO pilot study, a capture zone analysis (CZA) was conducted to ensure containment of the injected oxidant within the existing groundwater extraction system. The CZA was conducted through a groundwater flow modeling using MODFLOW. The model indicated that 85%, 90%, and 95% of an injected oxidant could be captured when a well pair is injecting and extracting at 2, 5, and 10 gallons per minute, respectively. An ISCO pilot test using ozone was conducted to evaluate operation parameters for ozone delivery. The ozone sparging system consisted of an ozone generator capable of delivering 6 lbs/day ozone through two ozone

Effect of soil organic matter on antimony bioavailability after the remediation process.

Science.gov (United States)

Nakamaru, Yasuo Mitsui; Martín Peinado, Francisco José

2017-09-01

We evaluated the long-term (18 year) and short-term (4 weeks) changes of Sb in contaminated soil with SOM increase under remediation process. In the Aznalcóllar mine accident (1998) contaminated area, the remediation measurement implemented the Guadiamar Green Corridor, where residual pollution is still detected. Soils of the re-vegetated area (O2) with high pH and high SOM content, moderately re-vegetated area (O1) and unvegetated area (C) were sampled. Soil pH, CEC, SOM amount and soil Sb forms were evaluated. Soil Sb was measured as total, soluble, exchangeable, EDTA extractable, acid oxalate extractable, and pyro-phosphate extractable fractions. Further, the short-term effect of artificial organic matter addition was also evaluated with incubation study by adding compost to the sampled soil from C, O1 and O2 areas. After 4 weeks of incubation, soil chemical properties and Sb forms were evaluated. In re-vegetated area (O2), soil total Sb was two times lower than in unvegetated area (C); however, soluble, exchangeable, and EDTA extractable Sb were 2-8 times higher. The mobile/bioavailable Sb increase was also observed after 4 weeks of incubation with the addition of compost. Soluble, exchangeable, and EDTA extractable Sb was increased 2-4 times by compost addition. By the linear regression analysis, the significantly related factors for soluble, exchangeable, and EDTA extractable Sb values were pH, CEC, and SOM, respectively. Soluble Sb increase was mainly related to pH rise. Exchangeable Sb should be bound by SOM-metal complex and increased with CEC. EDTA extractable fraction should be increased with increase of SOM as SOM-Fe associated Sb complex. From these results, it was shown that increase of SOM under natural conditions or application of organic amendment under remediation process should increase availability of Sb to plants. Copyright © 2017 Elsevier Ltd. All rights reserved.

Bioaccumulation in Porcellio scaber (Crustacea, Isopoda) as a measure of the EDTA remediation efficiency of metal-polluted soil

International Nuclear Information System (INIS)

Udovic, Metka; Drobne, Damjana; Lestan, Domen

2009-01-01

Leaching using EDTA applied to a Pb, Zn and Cd polluted soil significantly reduced soil metal concentrations and the pool of metals in labile soil fractions. Metal mobility (Toxicity Characteristic Leaching Procedure), phytoavailability (diethylenetriaminepentaacetic acid extraction) and human oral-bioavailability (Physiologically Based Extraction Test) were reduced by 85-92%, 68-91% and 88-95%, respectively. The metal accumulation capacity of the terrestrial isopod Porcellio scaber (Crustacea) was used as in vivo assay of metal bioavailability, before and after soil remediation. After feeding on metal contaminated soil for two weeks, P. scaber accumulated Pb, Zn and Cd in a concentration dependent manner. The amounts of accumulated metals were, however, higher than expected on the basis of extraction (in vitro) tests. The combined results of chemical extractions and the in vivo test with P. scaber provide a more relevant picture of the availability stripping of metals after soil remediation. - Bioaccumulation tests with Porcellio scaber isopods are proposed as a supplement to chemical extraction in assessing metal bioavailability before and after soil remediation.

Architecture and environmental restoration: Remediating uranium mill tailings from buildings

International Nuclear Information System (INIS)

Teply, J.D.

1991-01-01

The US Department of Energy (DOE) Grand Junction Projects Office (GJPO) manages the Uranium Mill Tailings Remedial Action (UMTRA) Program in Grand Junction, Colorado. This program is a congressionally mandated clean up of by-product waste that resulted from the extraction of yellow cake from uranium ore. The by-product waste, a fine sand commonly called open-quotes mill tailingclose quotes is contaminated with low-level radioactivity. These mill tailings were available to the community for use as construction material from approximately 1952 to 1966; their use as bedding material for concrete slabs, utilities, backfill materials, concrete sand, and mortar created unique remediation problems that required innovative solutions. This paper describes how design personnel approach the remediation of structures, the evaluation of the buildings, and the factors that must be considered in completing the remediation design. This paper will not address the health risks of the tailings in an inhabited space, the remediation of exterior areas, or the process of determining where the tailings exist in the building

Functioning of metal contaminated garden soil after remediation

International Nuclear Information System (INIS)

Jelusic, Masa; Grcman, Helena; Vodnik, Dominik; Suhadolc, Metka; Lestan, Domen

2013-01-01

The effect of remediation using three EDTA doses (10, 30, 60 mmol kg −1 ) on soil functioning was assessed using column experiment and Brassica rapa. Soil washing removed up to 77, 29 and 72% of metals from soil contaminated with 1378, 578 and 8.5 mg kg −1 of Pb, Zn and Cd, respectively. Sequential extraction indicated removal from the carbonate soil fraction. Metal oral-accessibility from the stomach phase was reduced by up to 75 and from the small intestine by up to 79% (Pb). Part of metals (up to 0.8% Cd) was lost due to leaching from columns. Remediation reduced toxic metal soil-root transfer by up to 61% but did not prevent metal accumulation in leaves. The fitness of plants grown on EDTA washed soils (gas exchange, fluorescence) was not compromised. Remediation initially reduced the soil DNA content (up to 29%, 30 mmol kg −1 EDTA) and changed the structure of microbial population. -- Highlights: ► Toxic metals contaminated garden soil was remediated in a pilot-scale. ► EDTA washing reduced soil Pb, Zn and Cd content and bioavailability. ► Remediated soil preserved the function of plant and microbial substrate. ► Remediation didn't prevent the accumulation of toxic metals in the test plant. -- EDTA soil washing effectively removed toxic metals and reduced their transfer from the soil to plant roots but did not prevent their accumulation in leaves

Pre- and post-remediation characterization of acid-generating fluvial tailings material

Science.gov (United States)

Smith, Kathleen S.; Walton-Day, Katherine; Hoal, Karin O.; Driscoll, Rhonda L.; Pietersen, K.

2012-01-01

The upper Arkansas River south of Leadville, Colorado, USA, contains deposits of fluvial tailings from historical mining operations in the Leadville area. These deposits are potential non-point sources of acid and metal contamination to surface- and groundwater systems. We are investigating a site that recently underwent in situ remediation treatment with lime, fertilizer, and compost. Pre- and post-remediation fluvial tailings material was collected from a variety of depths to examine changes in mineralogy, acid generation, and extractable nutrients. Results indicate sufficient nutrient availability in the post-remediation near-surface material, but pyrite and acid generation persist below the depth of lime and fertilizer addition. Mineralogical characterization performed using semi-quantitative X-ray diffraction and quantitative SEM-based micro-mineralogy (Mineral Liberation Analysis, MLA) reveal formation of gypsum, jarosite, and complex coatings surrounding mineral grains in post-remediation samples.

Kinetics as a tool to assess the immobilization of soil trace metals by binding phase amendments for in situ remediation purposes

International Nuclear Information System (INIS)

Varrault, Gilles; Bermond, Alain

2011-01-01

Highlights: → Assessment of the efficiency of soil remediation method by binding phase amendment. → Use of a kinetic fractionation method to assess trace metal mobility in amended soils. → Vernadite amendments are effective for lead and cadmium remediation. → IHA amendments are only effective for copper remediation. → Advantages of kinetic fractionation vs. extraction schemes performed at equilibrium. - Abstract: Many soil remediation techniques consist in decreasing the mobility of trace metals by means of adding trace metal binding phases. For this study, whose aim is to assess the efficiency of soil remediation method by binding phase amendment, a kinetic fractionation method that provides the labile and slowly labile trace metal amounts in soil has been introduced. Manganese oxides (vernadite) and insolubilized humic acids (IHA) have been used as binding phases for the remediation of four heavily polluted soils. Vernadite amendments are effective for lead and cadmium remediation, whereas IHA amendments are only effective for copper remediation. In most cases, the labile metal fractions decrease dramatically in amended soils (up to 50%); on the other hand, the amounts of total extracted metal near the point of thermodynamic equilibrium often show no significant difference between the amended soil and the control soil. These results highlight the utility of kinetic fractionation in assessing the efficiency of soil remediation techniques and, more generally, in evaluating trace metal mobility in soils and its potential advantages compared to extraction schemes performed under equilibrium conditions. In the future, this kinetic method could be considerably simplified so as to consume much less time allowing its routine use.

Sustainability likelihood of remediation options for metal-contaminated soil/sediment.

Science.gov (United States)

Chen, Season S; Taylor, Jessica S; Baek, Kitae; Khan, Eakalak; Tsang, Daniel C W; Ok, Yong Sik

2017-05-01

Multi-criteria analysis and detailed impact analysis were carried out to assess the sustainability of four remedial alternatives for metal-contaminated soil/sediment at former timber treatment sites and harbour sediment with different scales. The sustainability was evaluated in the aspects of human health and safety, environment, stakeholder concern, and land use, under four different scenarios with varying weighting factors. The Monte Carlo simulation was performed to reveal the likelihood of accomplishing sustainable remediation with different treatment options at different sites. The results showed that in-situ remedial technologies were more sustainable than ex-situ ones, where in-situ containment demonstrated both the most sustainable result and the highest probability to achieve sustainability amongst the four remedial alternatives in this study, reflecting the lesser extent of off-site and on-site impacts. Concerns associated with ex-situ options were adverse impacts tied to all four aspects and caused by excavation, extraction, and off-site disposal. The results of this study suggested the importance of considering the uncertainties resulting from the remedial options (i.e., stochastic analysis) in addition to the overall sustainability scores (i.e., deterministic analysis). The developed framework and model simulation could serve as an assessment for the sustainability likelihood of remedial options to ensure sustainable remediation of contaminated sites. Copyright © 2017 Elsevier Ltd. All rights reserved.

300-FF-1 remedial design report/remedial action work plan

Energy Technology Data Exchange (ETDEWEB)

Gustafson, F.W.

1997-02-01

The 300 Area has been divided into three operable units 300-FF-1, 300-FF-2, and 300-FF-5 all of which are in various stages of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) process. The 300-FF-1 Operable Unit, the subject of this report, includes liquid waste disposal sites, landfills, and a burial ground. This Remedial Design Report/Remedial Action Work Plan (RDR/RAWP) provides a summary description of each waste site included in the 300-FF-1 Operable Unit, the basis for remedial actions to be taken, and the remedial action approach and management process for implementing these actions. The remedial action approach and management sections provide a description of the remedial action process description, the project schedule, the project team, required planning documentation, the remedial action change process, the process for verifying attainment of the remedial action goals, and the required CERCLA and RCRA closeout documentation. Appendix A provides additional details on each waste site. In addition to remediation of the waste sites, waste generated during the remedial investigation/feasibility study portions of the project will also be disposed at the Environmental Restoration Disposal Facility (ERDF). Appendix B provides a summary of the modeling performed in the 300-FF-1 Phase 3 FS and a description of the modeling effort to be used to show attainment of the remedial action goals. Appendix C provides the sampling and analysis plan (SAP) for all sampling and field-screening activities performed during remediation and for verification of attainment with the remedial action goals. Appendix D provides the public involvement plan, prepared to ensure information is provided to the public during remedial design and remedial action processes.

300-FF-1 remedial design report/remedial action work plan

International Nuclear Information System (INIS)

Gustafson, F.W.

1997-02-01

The 300 Area has been divided into three operable units 300-FF-1, 300-FF-2, and 300-FF-5 all of which are in various stages of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) process. The 300-FF-1 Operable Unit, the subject of this report, includes liquid waste disposal sites, landfills, and a burial ground. This Remedial Design Report/Remedial Action Work Plan (RDR/RAWP) provides a summary description of each waste site included in the 300-FF-1 Operable Unit, the basis for remedial actions to be taken, and the remedial action approach and management process for implementing these actions. The remedial action approach and management sections provide a description of the remedial action process description, the project schedule, the project team, required planning documentation, the remedial action change process, the process for verifying attainment of the remedial action goals, and the required CERCLA and RCRA closeout documentation. Appendix A provides additional details on each waste site. In addition to remediation of the waste sites, waste generated during the remedial investigation/feasibility study portions of the project will also be disposed at the Environmental Restoration Disposal Facility (ERDF). Appendix B provides a summary of the modeling performed in the 300-FF-1 Phase 3 FS and a description of the modeling effort to be used to show attainment of the remedial action goals. Appendix C provides the sampling and analysis plan (SAP) for all sampling and field-screening activities performed during remediation and for verification of attainment with the remedial action goals. Appendix D provides the public involvement plan, prepared to ensure information is provided to the public during remedial design and remedial action processes

Characterization and monitoring of total organic chloride vapors

International Nuclear Information System (INIS)

Anheier, N.C. Jr.; Evans, J.C. Jr.; Olsen, K.B.

1992-07-01

Chemical sensors are being developed intermediate highly selective and broadly selective methods. PNL is developing an optical-emission based TOCl (total organic chlorinated compounds) sensor (Halosnif) which is capable of measuring TOCl in real time on an extracted gas sample over a wide linear dynamic range. Halosnif employs an atomic emission sensor that is broadly selective for any moderately volatile organic hclorinated vapor but does not distinguish between classes of chlorinated compounds. A rf-induced He plasma is used to excite the chlorine atoms, causing light emission at 837.6 nm. The sensitivity ranges from 1-2 ppM up to at least 10,000 ppM. Field tests were conducted at Tinker AFB in areas of high TCE contamination, in two boreholes at Savannah River, and at Hanford CCl 4 vapor extraction system. This sensor is briefly compared with acoustic wave sensors being developed by SNL (PAWS). 4 figs

Remediation Performance and Mechanism of Heavy Metals by a Bottom Up Activation and Extraction System Using Multiple Biochemical Materials.

Science.gov (United States)

Xiao, Kemeng; Li, Yunzhen; Sun, Yang; Liu, Ruyue; Li, Junjie; Zhao, Yun; Xu, Heng

2017-09-13

Soil contamination with heavy metals has caused serious environmental problems and increased the risks to humans and biota. Herein, we developed an effective bottom up metals removal system based on the synergy between the activation of immobilization metal-resistant bacteria and the extraction of bioaccumulator material (Stropharia rugosoannulata). In this system, the advantages of biochar produced at 400 °C and sodium alginate were integrated to immobilize bacteria. Optimized by response surface methodology, the biochar and bacterial suspension were mixed at a ratio of 1:20 (w:v) for 12 h when 2.5% sodium alginate was added to the mixture. Results demonstrated that the system significantly increased the proportion of acid soluble Cd and Cu and improved the soil microecology (microbial counts, soil respiration, and enzyme activities). The maximum extractions of Cd and Cu were 8.79 and 77.92 mg kg -1 , respectively. Moreover, details of the possible mechanistic insight into the metal removal are discussed, which indicate positive correlation with the acetic acid extractable metals and soil microecology. Meanwhile, the "dilution effect" in S. rugosoannulata probably plays an important role in the metal removal process. Furthermore, the metal-resistant bacteria in this system were successfully colonized, and the soil bacteria community were evaluated to understand the microbial diversity in metal-contaminated soil after remediation.

Full scale solvent extraction remedial results

International Nuclear Information System (INIS)

Cash, A.B.

1992-01-01

Sevenson Extraction Technology, Inc. has completed the development of the Soil Restoration Unit (initially developed by Terra-Kleen Corporation), a mobile, totally enclosed solvent extraction treatment facility for the removal of organic contaminated media is greater by a closed loop, counter current process that recycles all solvents. The solvents used are selected for the individual site dependant upon the contaminants, such as PCB's, oil, etc. and the soil conditions. A mixture of up to fourteen non-toxic solvents can be used for complicated sites. The full scale unit has been used to treat one superfund site, the Traband Site in Tulsa, Oklahoma, and is currently treating another superfund site, the Pinette's Salvage Yard Site in Washburn, Maine. The full scale Soil Restoration Unit has also been used at a non-superfund site, as part of a TSCA Research and Development permit. The results from these sites will be discussed in brief herein, and in more detail in the full paper

Phyto-remediation of contaminated soils

International Nuclear Information System (INIS)

Chagvardieff, P.

2014-01-01

Some plants can be selected for their capacity to extract radionuclides from the soil, on the contrary other plants can be chosen for being able to produce food grade products in a contaminated environment. Modern genetic methods can be used to enhance these abilities and turn some plants into an efficient means in the managing of contaminated areas. The DEMETERRES project that gathers different research organisations like CEA, IRSN and INRA and industrial partners like AREVA and VEOLIA aims at developing innovative bio-technologies like phyto-extraction and environment friendly physico-chemical technologies for the remediation of contaminated soils. This project was launched in 2013 on a 5-year scheme and is expected to lead to industrial applications. (A.C.)

Preliminary remediation goals for ecological endpoints

International Nuclear Information System (INIS)

Efroymson, R.A.; Suter, G.W. II; Sample, B.E.; Jones, D.S.

1996-07-01

Preliminary remediation goals (PRGs) are useful for risk assessment and decision making at Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) sites. PRGs are upper concentration limits for specific chemicals in specific environmental media that are anticipated to protect human health or the environment. They can be used for multiple remedial investigations at multiple facilities. In addition to media and chemicals of potential concern, the development of PRGs generally requires some knowledge or anticipation of future land use. In Preliminary Remediation Goals for Use at the U.S. Department of Energy Oak Ridge Operations Office (Energy Systems 1995), PRGs intended to protect human health were developed with guidance from Risk Assessment Guidance for Superfund: Volume I - Human Health Evaluation Manual, Part B (RAGS) (EPA 1991). However, no guidance was given for PRGs based on ecological risk. The numbers that appear in this volume have, for the most part, been extracted from toxicological benchmarks documents for Oak Ridge National Laboratory (ORNL) and have previously been developed by ORNL. The sources of the quantities, and many of the uncertainties associated with their derivation, are described in this technical memorandum

Preliminary remediation goals for ecological endpoints

International Nuclear Information System (INIS)

Efroymson, R.A.; Suter, G.W. II.

1995-09-01

Preliminary remediation goals (PRGs) are useful for risk assessment and decision making at Comprehensive Environmental Response, compensation, and Liability Act (CERCLA) sites. PRGs are upper concentration limits for specific chemicals in specific environmental media that are anticipated to protect human health or the environment. They can be used for multiple remedial investigations at multiple facilities. In addition to media and chemicals of potential concern, the development of PRGs generally requires some knowledge or anticipation of future land use. In Preliminary Remediation Goals for Use at the US Department of Energy Oak Ridge Operations Office (Energy Systems 1995), PRGs intended to protect human health were developed with guidance from Risk Assessment Guidance for Superfund: Volume I-Human Health Evaluation Manual, Part B (RAGS) (EPA 1991). However, no guidance was given for PRGs based on ecological risk. The numbers that appear in this volume have, for the most part, been extracted from toxicological benchmarks documents for Oak Ridge National Laboratory (ORNL) and have previously been developed by ORNL. The sources of the quantities, and many of the uncertainties associated with their derivation, are described in this technical memorandum

Vapor pressures and enthalpies of vaporization of azides

International Nuclear Information System (INIS)

Verevkin, Sergey P.; Emel'yanenko, Vladimir N.; Algarra, Manuel; Manuel Lopez-Romero, J.; Aguiar, Fabio; Enrique Rodriguez-Borges, J.; Esteves da Silva, Joaquim C.G.

2011-01-01

Highlights: → We prepared and measured vapor pressures and vaporization enthalpies of 7 azides. → We examined consistency of new and available in the literature data. → Data for geminal azides and azido-alkanes selected for thermochemical calculations. - Abstract: Vapor pressures of some azides have been determined by the transpiration method. The molar enthalpies of vaporization Δ l g H m of these compounds were derived from the temperature dependencies of vapor pressures. The measured data sets were successfully checked for internal consistency by comparison with vaporization enthalpies of similarly structured compounds.

Experiments on Plume Spreading by Engineered Injection and Extraction

Science.gov (United States)

Mays, D. C.; Jones, M.; Tigera, R. G.; Neupauer, R.

2014-12-01

The notion that groundwater remediation is transport-limited emphasizes the coupling between physical (i.e., hydrodynamic), geochemical, and microbiological processes in the subsurface. Here we leverage this coupling to promote groundwater remediation using the approach of engineered injection and extraction. In this approach, inspired by the literature on chaotic advection, uncontaminated groundwater is injected and extracted through a manifold of wells surrounding the contaminated plume. The potential of this approach lies in its ability to actively manipulate the velocity field near the contaminated plume, generating plume spreading above and beyond that resulting from aquifer heterogeneity. Plume spreading, in turn, promotes mixing and reaction by chemical and biological processes. Simulations have predicted that engineered injection and extraction generates (1) chaotic advection whose characteristics depend on aquifer heterogeneity, and (2) faster rates and increased extent of groundwater remediation. This presentation focuses on a complimentary effort to experimentally demonstrate these predictions experimentally. In preparation for future work using refractive index matched (RIM) porous media, the experiments reported here use a Hele-Shaw apparatus containing silicone oil. Engineered injection and extraction is used to manipulate the geometry of an initially circular plume of black pigment, and photographs record the plume geometry after each step of injection of extraction. Image analysis, using complimentary Eulerian and Lagrangian approaches, reveals the thickness and variability of the dispersion zone surrounding the deformed plume of black pigment. The size, shape, and evolution of this dispersion zone provides insight into the interplay between engineered injection and extraction, which generates plume structure, and dispersion (here Taylor dispersion), which destroys plume structure. These experiments lay the groundwork for application of engineered

Spectral induced polarization for monitoring electrokinetic remediation processes

Science.gov (United States)

Masi, Matteo; Losito, Gabriella

2015-12-01

Electrokinetic remediation is an emerging technology for extracting heavy metals from contaminated soils and sediments. This method uses a direct or alternating electric field to induce the transport of contaminants toward the electrodes. The electric field also produces pH variations, sorption/desorption and precipitation/dissolution of species in the porous medium during remediation. Since heavy metal mobility is pH-dependent, the accurate control of pH inside the material is required in order to enhance the removal efficiency. The common approach for monitoring the remediation process both in laboratory and in the field is the chemical analysis of samples collected from discrete locations. The purpose of this study is the evaluation of Spectral Induced Polarization as an alternative method for monitoring geochemical changes in the contaminated mass during remediation. The advantage of this technique applied to field-scale is to offer higher resolution mapping of the remediation site and lower cost compared to the conventional sampling procedure. We carried out laboratory-scale electrokinetic remediation experiments on fine-grained marine sediments contaminated by heavy metal and we made Spectral Induced Polarization measurements before and after each treatment. Measurements were done in the frequency range 10- 3-103 Hz. By the deconvolution of the spectra using the Debye Decomposition method we obtained the mean relaxation time and total chargeability. The main finding of this work is that a linear relationship exists between the local total chargeability and pH, with good agreement. The observed behaviour of chargeability is interpreted as a direct consequence of the alteration of the zeta potential of the sediment particles due to pH changes. Such relationship has a significant value for the interpretation of induced polarization data, allowing the use of this technique for monitoring electrokinetic remediation at field-scale.

In-Situ Electrokinetic Remediation for Metal Contaminated Soils

Science.gov (United States)

2001-03-01

phytoremediation , and electrokinetic extraction. The US Army Environmental Center (USAEC) and Engineer Research and Development Center (ERDC...California (CA) List Metals: Antimony, arsenic, barium, beryllium, cadmium, chromium, cobalt, copper, lead, mercury , molybdenum, nickel, selenium...Comparison Technologies with which electrokinetic remediation must compete are "Dig and Haul", Soil Washing, and Phytoremediation . "Dig and haul

Toxicity of vapor phase petroleum contaminants to microbial degrader communities

International Nuclear Information System (INIS)

Long, S.C.; Davey, C.A.

1994-01-01

Petroleum products constitute the largest quantity of synthetic organic chemical products produced in the US. They are comprised of mostly hydrocarbon constituents from many different chemical classes including alkenes, cycloalkanes, aromatic compounds, and polyaromatic hydrocarbons. Many petroleum constituents are classified as volatile organic compounds or VOCs. Petroleum products also constitute a major portion of environmental pollution. One emerging technology, with promise for applications to VOCs in subsurface soil environments, is bioventing coupled with soil vapor extraction. These technologies involve volatilization of contaminants into the soil gas phase by injection and withdrawal of air. This air movement causes enhancement of the aerobic microbial degradation of the mobilized vapors by the indigenous populations. This study investigated the effects of exposure of mixed, subsurface microbial communities to vapor phase petroleum constituents or vapors of petroleum mixtures. Soil slurries were prepared and plated onto mineral salts agar plates and exposed to vapor phase contaminants at equilibrium with pure product. Representative n-alkane, branched alkane, cycloalkane, and aromatic compounds were tested as well as petroleum product mixtures. Vapor exposure altered the numbers and morphologies of the colonies enumerated when compared to controls. However, even at high, equilibrium vapor concentrations, microbial degrader populations were not completely inhibited

[Recent advance in solidification/stabilization technology for the remediation of heavy metals-contaminated soil].

Science.gov (United States)

Hao, Han-zhou; Chen, Tong-bin; Jin, Meng-gui; Lei, Mei; Liu, Cheng-wu; Zu, Wen-pu; Huang, Li-mi

2011-03-01

Remediation of heavy metals-contaminated soil is still a difficulty and a hotspot of international research projects. At present, the technologies commonly adopted for the remediation of contaminated sites mainly include excavation, solidification/stabilization (S/S), soil washing, soil vapor extraction (SVE), thermal treatment, and bioremediation. Based on the S/S technical guidelines of Unite State Environmental Protection Agency (EPA) and United Kingdom Environment Agency (EA) and the domestic and foreign patents, this paper introduced the concepts of S/S and its development status at home and abroad, and discussed its future development directions. Solidification refers to a process that binds contaminated media with a reagent, changing the media's physical properties via increasing its compressive strength, decreasing its permeability, and encapsulating the contaminants to form a solid material. Stabilization refers to the process that involves a chemical reaction which reduces the leachability of a waste, chemically immobilizes the waste and reduces its solubility, making the waste become less harmful or less mobile. S/S technology includes cement solidification, lime pozzolanic solidification, plastic materials stabilization, vitrification, and regent-based stabilization. Stabilization (or immobilization) treatment processes convert contaminants to less mobile forms through chemical or thermal interactions. In stabilization technology, the aim of adding agents is to change the soil physical and chemical properties through pH control technology, redox potential technology, precipitation techniques, adsorption technology, and ion-exchange technology that change the existing forms of heavy metals in soil, and thus, reduce the heavy metals bioavailability and mobility. This review also discussed the S/S evaluation methods, highlighted the need to enhance S/S technology in the molecular bonding, soil polymers, and formulation of China's S/S technical guidelines.

Sandia National Laboratories Chemical Waste Landfill: Innovative strategies towards characterization and remediation

International Nuclear Information System (INIS)

Ardito, Cynthia P.; Parsons, Alva M.; Lindgren, Eric R.; Phelan, James M.; Mattson, Earl D.

1992-01-01

energy, and soil gas measured from monitor wells to aid in characterization of the soil gas plume. Additionally, as the CWL is part of Department of Energy's (DOE) Integrated Demonstration Program, an on-site demonstration of the thermal-enhanced vapor extraction system (TEVES) will be completed and a discussion of this demonstration at the CWL is provided. (author)

DOE-EMSP Final Report: Characterization of Changes in Colloid and DNAPL Affecting Surface Chemistry and Remediation

Energy Technology Data Exchange (ETDEWEB)

Susan E. Powers; Stefan J. Grimberg; Miles Denham

2007-02-07

The waste disposal to the M-area basin and A-14 outfall at the Savannah River Department of Energy facility in Aiken SC (USA) included a wide variety of inorganic aqueous flows and organic solvents in the form of dense non-aqueous phase liquids (DNAPL). The DNAPL has migrated through the subsurface resulting in widespread groundwater contamination. The goal of this research was to identify and quantify processes that could have affected the migration and remediation of the DNAPL in the subsurface. It was hypothesized that the variety of waste disposed at this site could have altered the mineral, microbial and DNAPL properties at this site relative to other DNAPL sites. The DNAPL was determined to have a very low interfacial tension and is suspected to be distributed in fine grained media, thereby reducing the effectiveness of soil vapor extraction remediation efforts. Although the DNAPL is primarily comprised of tetrachloroethene and trichloroethane, it also contains organic acids and several heavy metals. Experimental results suggest that iron from the aqueous and DNAPL phases undergoes precipitation and dechlorination reactions at the DNAPL-water interface, contributing to the low interfacial tension and acidity of the DNAPL. Biological activity in the contaminated region can also contribute to the low interfacial tension. PCE degrading bacteria produce biosurfactants and adhere to the DNAPL-water interface when stressed by high tetrachloroethene or low dissolved oxygen concentrations. The presence of iron can reduce the interfacial tension by nearly an order of magnitude, while the PCE degraders reduced the interfacial tension by nearly 50%. Abiotic changes in the mineral characteristics were not found to be substantially different between contaminated and background samples. The research completed here begins to shed some insight into the complexities of DNAPL fate and migration at sites where co-disposal of many different waste products occurred. Quantifying

Use of plant and earthworm bioassays to evaluate remediation of soil from a site contaminated with polychlorinated biphenyls

Energy Technology Data Exchange (ETDEWEB)

Meier, J.R.; Chang, L.W.; Meckes, M.C.; Smith, M.K. [Environmental Protection Agency, Cincinnati, OH (United States); Jacobs, S. [DynCorp, Cincinnati, OH (United States); Torsella, J. [Oak Ridge Inst. of Science and Education, Cincinnati, OH (United States)

1997-05-01

Soil from a site heavily contaminated with polychlorinated biphenyls (PCBs) was treated with a pilot-scale, solvent extraction technology. Bioassays in earthworms and plants were used to examine the efficacy of the remediation process for reducing the toxicity of the soil. The earthworm toxicity bioassays were the 14-d survival test and 21-d reproduction test, using Lumbricus terrestris and Eisenia fetida andrei. The plant bioassays included phytotoxicity tests for seed germination and root elongation in lettuce and oats, and a genotoxicity test (anaphase aberrations) in Allium cepa (common onion). Although the PCB content of the soil was reduced by 99% (below the remediation goal), toxicity to earthworm reproduction remained essentially unchanged following remediation. Furthermore, phytotoxicity and genotoxicity were higher for the remediated soil compared to the untreated soil. The toxicity remaining after treatment appeared to be due to residual solvent introduced during the remediation process, and/or to heavy metals or other inorganic contaminants not removed by the treatment. Mixture studies involving isopropanol and known toxicants indicated possible synergistic effects of the extraction solvent and soil contaminants. The toxicity in plants was essentially eliminated by a postremediation, water-rinsing step. These results demonstrate a need for including toxicity measurements in the evaluation of technologies used in hazardous waste site remediations, and illustrate the potential value of such measurements for making modifications to remediation processes.

Anti-venom potentials of Friedelin isolated from hexane extract ...

African Journals Online (AJOL)

... taenicidal, cough remedy, dysentery, cancer, diabetes mellitus, tuberculosis and snake bite remedy. In this report, an attempt has been made to evaluate the bioactive molecules in the plant that are anti-venom agents. Consequently, the stem bark was exhaustively extracted with hexane and subsequently with methanol.

GC/MS Evaluation and In Vitro Antioxidant Activity of Essential Oil and Solvent Extracts of an Endemic Plant Used as Folk Remedy in Turkey: Phlomis bourgaei Boiss.

Directory of Open Access Journals (Sweden)

Cengiz Sarikurkcu

2013-01-01

Full Text Available This study was outlined to examine the chemical composition of hydrodistilled essential oil and in vitro antioxidant potentials of the essential oil and different solvent extracts of endemic Phlomis bourgaei Boiss. used as folk remedy in Turkey. The chemical composition of the oil was analyzed by GC and GC-MS, and the predominant components in the oil were found to be β-caryophyllene (37.37%, (Z-β-farnesene (15.88%, and germacrene D (10.97%. Antioxidant potentials of the solvent extracts and the oil were determined by four testing systems including β-carotene/linoleic acid, DPPH, reducing power, and chelating effect. In β-carotene/linoleic acid assay, all extracts showed the inhibition of more than 50% at all concentrations. In DPPH, chelating effect, and reducing power test systems, the water extract with 88.68%, 77.45%, and 1.857 (absorbance at 700 nm, respectively, exhibited more excellent activity potential than other extracts (hexane, ethyl acetate and methanol and the essential oil at 1.0 mg/mL concentration. The amount of the total phenolics and flavonoids was the highest in this extract (139.50 ± 3.98 μg gallic acid equivalents (GAEs/mg extract and 22.71 ± 0.05 μg quercetin equivalents (QEs/mg extract.

GC/MS Evaluation and In Vitro Antioxidant Activity of Essential Oil and Solvent Extracts of an Endemic Plant Used as Folk Remedy in Turkey: Phlomis bourgaei Boiss.

Science.gov (United States)

Sarikurkcu, Cengiz; Sabih Ozer, M.; Cakir, Ahmet; Eskici, Mustafa; Mete, Ebru

2013-01-01

This study was outlined to examine the chemical composition of hydrodistilled essential oil and in vitro antioxidant potentials of the essential oil and different solvent extracts of endemic Phlomis bourgaei Boiss. used as folk remedy in Turkey. The chemical composition of the oil was analyzed by GC and GC-MS, and the predominant components in the oil were found to be β-caryophyllene (37.37%), (Z)-β-farnesene (15.88%), and germacrene D (10.97%). Antioxidant potentials of the solvent extracts and the oil were determined by four testing systems including β-carotene/linoleic acid, DPPH, reducing power, and chelating effect. In β-carotene/linoleic acid assay, all extracts showed the inhibition of more than 50% at all concentrations. In DPPH, chelating effect, and reducing power test systems, the water extract with 88.68%, 77.45%, and 1.857 (absorbance at 700 nm), respectively, exhibited more excellent activity potential than other extracts (hexane, ethyl acetate and methanol) and the essential oil at 1.0 mg/mL concentration. The amount of the total phenolics and flavonoids was the highest in this extract (139.50 ± 3.98 μg gallic acid equivalents (GAEs)/mg extract and 22.71 ± 0.05 μg quercetin equivalents (QEs)/mg extract). PMID:23762120

A microfluidic sub-critical water extraction instrument

Science.gov (United States)

Sherrit, Stewart; Noell, Aaron C.; Fisher, Anita; Lee, Mike C.; Takano, Nobuyuki; Bao, Xiaoqi; Kutzer, Thomas C.; Grunthaner, Frank

2017-11-01

This article discusses a microfluidic subcritical water extraction (SCWE) chip for autonomous extraction of amino acids from astrobiologically interesting samples. The microfluidic instrument is composed of three major components. These include a mixing chamber where the soil sample is mixed and agitated with the solvent (water), a subcritical water extraction chamber where the sample is sealed with a freeze valve at the chip inlet after a vapor bubble is injected into the inlet channels to ensure the pressure in the chip is in equilibrium with the vapor pressure and the slurry is then heated to ≤200 °C in the SCWE chamber, and a filter or settling chamber where the slurry is pumped to after extraction. The extraction yield of the microfluidic SCWE chip process ranged from 50% compared to acid hydrolysis and 80%-100% compared to a benchtop microwave SCWE for low biomass samples.

Remediation of lead-contaminated soils

International Nuclear Information System (INIS)

Peters, R.W.; Shem, L.

1992-01-01

Excavation and transport of soil contaminated with heavy metals has generally been the standard remediation technique for treatment of heavy-metal-contaminated soils. This approach is not a permanent solution; moreover, off-site shipment and disposal of contaminated soil involves high expense, liability, and appropriate regulatory approval. Recently, a number of other techniques have been investigated for treating such contaminated sites, including flotation, solidification/stabilization, vitrification, and chemical extraction. This paper reports the results of a laboratory investigation determining the efficiency of using chelating agents to extract lead from contaminated soils. Lead concentrations in the soils ranged from 500 to 10,000 mg/kg. Ethylenediaminetetraacetic acid (EDTA) and nitrilotriacetic acid (NTA) were examined for their potential extractive capabilities. Concentrations of the chelating agents ranged from 0.01 to 0.10 M. The pH of the suspensions in which the extractions were performed ranged from 4 to 12. Results showed that the removal of lead using NTA and water was ph-dependent, whereas the removal of lead using EDTA was ph-insensitive. Maximum removals of lead were 68.7%,19.1%, and 7.3% using EDTA, NTA, and water, respectively (as compared with initial lead concentrations)

Tank Waste Remediation System fiscal year 1996 multi-year program plan WBS 1.1. Revision 1, Appendix A

International Nuclear Information System (INIS)

1995-09-01

This document is a compilation of data relating to the Tank Waste Remediation System Multi-Year Program. Topics discussed include: management systems; waste volume, transfer and evaporation management; transition of 200 East and West areas; ferricyanide, volatile organic vapor, and flammable gas management; waste characterization; retrieval from SSTs and DSTs; heat management; interim storage; low-level and high-level radioactive waste management; and tank farm closure

Field-scale multi-phase LNAPL remediation: Validating a new computational framework against sequential field pilot trials.

Science.gov (United States)

Sookhak Lari, Kaveh; Johnston, Colin D; Rayner, John L; Davis, Greg B

2018-03-05

Remediation of subsurface systems, including groundwater, soil and soil gas, contaminated with light non-aqueous phase liquids (LNAPLs) is challenging. Field-scale pilot trials of multi-phase remediation were undertaken at a site to determine the effectiveness of recovery options. Sequential LNAPL skimming and vacuum-enhanced skimming, with and without water table drawdown were trialled over 78days; in total extracting over 5m 3 of LNAPL. For the first time, a multi-component simulation framework (including the multi-phase multi-component code TMVOC-MP and processing codes) was developed and applied to simulate the broad range of multi-phase remediation and recovery methods used in the field trials. This framework was validated against the sequential pilot trials by comparing predicted and measured LNAPL mass removal rates and compositional changes. The framework was tested on both a Cray supercomputer and a cluster. Simulations mimicked trends in LNAPL recovery rates (from 0.14 to 3mL/s) across all remediation techniques each operating over periods of 4-14days over the 78day trial. The code also approximated order of magnitude compositional changes of hazardous chemical concentrations in extracted gas during vacuum-enhanced recovery. The verified framework enables longer term prediction of the effectiveness of remediation approaches allowing better determination of remediation endpoints and long-term risks. Copyright © 2017 Commonwealth Scientific and Industrial Research Organisation. Published by Elsevier B.V. All rights reserved.

A comprehensive guide of remediation technologies for oil contaminated soil - Present works and future directions.

Science.gov (United States)

Lim, Mee Wei; Lau, Ee Von; Poh, Phaik Eong

2016-08-15

Oil spills result in negative impacts on the environment, economy and society. Due to tidal and waves actions, the oil spillage affects the shorelines by adhering to the soil, making it difficult for immediate cleaning of the soil. As shoreline clean-up is the most costly component of a response operation, there is a need for effective oil remediation technologies. This paper provides a review on the remediation technologies for soil contaminated with various types of oil, including diesel, crude oil, petroleum, lubricating oil, bitumen and bunker oil. The methods discussed include solvent extraction, bioremediation, phytoremediation, chemical oxidation, electrokinetic remediation, thermal technologies, ultrasonication, flotation and integrated remediation technologies. Each of these technologies was discussed, and associated with their advantages, disadvantages, advancements and future work in detail. Nonetheless, it is important to note that no single remediation technology is considered the best solution for the remediation of oil contaminated soil. This review provides a comprehensive literature on the various remediation technologies studied in the removal of different oil types from soil. Copyright © 2016 Elsevier Ltd. All rights reserved.

Development of dry barriers for containment and remediation at waste sites

International Nuclear Information System (INIS)

Thomson, B.M.; Morris, C.E.; Ankeny, M.D.

1994-01-01

This paper describes a concept in which dry air is injected into an unsaturated formation to reduce the soil moisture content, referred to here as a dry (or sometimes tensiometric) barrier. The objective is to reduce the hydraulic conductivity of the unsaturated media to the point where liquid phase transport becomes negligible, thereby achieving containment. The concept could be applied in subsurface formations to provide containment from a leaking facility, or it could be incorporated into a cover design to provide redundancy for a capillary barrier. The air injection process could in principle be coupled with a vacuum extraction system to recover soil vapors, which would then provide a remediation process that would be appropriate if volatile organic compounds were present. Work to date has consisted of a combined theoretical, laboratory, and field research investigation. The objective of this research was to demonstrate the technical feasibility of the dry barrier concept by identifying the parameters which determine its effectiveness. Based on the results obtained for the experimental and theoretical studies, feasibility analyses were prepared for as a modification for a landfill cover design to prevent infiltration from atmospheric precipitation and for potential application of dry barriers to achieve subsurface containment and removal of volatile constituents. These analyses considered the technical as well as the economic aspects of the dry barrier concept

Fast pyrolysis of biomass in a fluidized bed reactor: in-situ filtering of the vapors

NARCIS (Netherlands)

Hoekstra, E.; Hogendoorn, Kees; Wang, X.; Westerhof, Roel Johannes Maria; Kersten, Sascha R.A.; van Swaaij, Willibrordus Petrus Maria; Groeneveld, M.J.

2009-01-01

A system to remove in situ char/ash from hot pyrolysis vapors has been developed and tested at the University of Twente. The system consists of a continuous fluidized bed reactor (0.7 kg/h) with immersed filters (wire mesh, pore size 5 μm) for extracting pyrolysis vapors. Integration of the filter

Hanford Tank Farm Vapors Abatement Technology and Vendor Proposals Assessment

International Nuclear Information System (INIS)

Burns, H. H.; Farrar, M. E.; Fink, S. D.

2016-01-01

Suspected chemical vapor releases from the Hanford nuclear waste tank system pose concerns for worker exposure. Washington River Protection Solutions (WRPS) contracted the Savannah River National Laboratory (SRNL) to explore abatement technologies and strategies to remediate the vapors emitted through the ventilation system. In response, SRNL conducted an evaluation of technologies to abate, or reduce, vapor emissions to below 10% of the recognized occupational exposure limits (OELs). The evaluation included a review of published literature and a broadly communicated Request for Information to commercial vendors through a Federal Business Opportunities (Fed Biz Opps) web posting. In addition, SRNL conducted a workshop and post-workshop conference calls with interested suppliers (vendors) to assess proposals of relevant technologies. This report reviews applicable technologies and summarizes the approaches proposed by the vendors who participated in the workshop and teleconference interviews. In addition, the report evaluates the estimated performance of the individual technologies for the various classes of chemical compounds present in the Hanford Chemicals of Potential Concern (COPCs) list. Similarly, the report provides a relative evaluation of the vendor proposed approaches against criteria of: technical feasibility (and maturity), design features, operational considerations, secondary waste generation, safety/regulatory, and cost / schedule. These rough order-of-magnitude (ROM) cost estimates are intended to provide a comparison basis between technologies and are not intended to be actual project estimates.

Hanford Tank Farm Vapors Abatement Technology and Vendor Proposals Assessment

Energy Technology Data Exchange (ETDEWEB)

Burns, H. H. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Farrar, M. E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Fink, S. D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-09-20

Suspected chemical vapor releases from the Hanford nuclear waste tank system pose concerns for worker exposure. Washington River Protection Solutions (WRPS) contracted the Savannah River National Laboratory (SRNL) to explore abatement technologies and strategies to remediate the vapors emitted through the ventilation system. In response, SRNL conducted an evaluation of technologies to abate, or reduce, vapor emissions to below 10% of the recognized occupational exposure limits (OELs). The evaluation included a review of published literature and a broadly communicated Request for Information to commercial vendors through a Federal Business Opportunities (Fed Biz Opps) web posting. In addition, SRNL conducted a workshop and post-workshop conference calls with interested suppliers (vendors) to assess proposals of relevant technologies. This report reviews applicable technologies and summarizes the approaches proposed by the vendors who participated in the workshop and teleconference interviews. In addition, the report evaluates the estimated performance of the individual technologies for the various classes of chemical compounds present in the Hanford Chemicals of Potential Concern (COPCs) list. Similarly, the report provides a relative evaluation of the vendor proposed approaches against criteria of: technical feasibility (and maturity), design features, operational considerations, secondary waste generation, safety/regulatory, and cost / schedule. These rough order-of-magnitude (ROM) cost estimates are intended to provide a comparison basis between technologies and are not intended to be actual project estimates.

Hydrodynamic analysis application of contaminated groundwater remediation to oil hydrocarbons

Directory of Open Access Journals (Sweden)

Pajić Predrag R.

2017-01-01

Full Text Available In this paper, the application of the hydrodynamic analysis in the selected ‘pumping and treatment’ remediation method of groundwater hydrocarbon pollution in the case of the Pancevo oil refinery is examined. The applied hydrodynamic analysis represents a regular and necessary approach in modern hydrogeology. Previous chemical analysis of soil and groundwater samples at observation objects revealed their pollution by oil products. New researches included the constraction of 12 piezometric boreholes of varying depths, geoelectric soil sounding, ‘in situ’ measurement of the present contaminant, detected as a hydrophobic phase of LNAPL, chemical analysis of soil and groundwater samples with emphasis on total petroleum hydrocarbons (TPH content, total fats and mineral oils, mercury cations and other characteristic compounds, etc. These researches define the volume of contamination issued by the ‘light’ (LNAPL contamination phase. The selected remediation method for this type of pollution is the ‘Pump and Treat’ method, which implies the pumping of contaminated groundwater from aquifer and their subsequent treatment. A hydrodynamic method was used to select the optimal hydrotechnical solution for LNAPL extraction. On the mathematical model, the prediction calculations for two variant solutions were carried out (‘hydraulic isolation’ and complex for the application of groundwater contamination remediation characterized as front pollution substance (by extraction and injection wells or infiltration pool. By extraction wells performing, it would be possible to remove the LNAPL from the surface of the water with special pumps-skimmers. The importance of the hydrodynamic method application is, in addition to the hydrotechnical solution selection for the LNAPL drainage, the provision of quality basis for the dimensioning of these objects based on the results of the groundwater balance.

The effect of earthworms on the fractionation and bioavailability of heavy metals before and after soil remediation

International Nuclear Information System (INIS)

Udovic, Metka; Lestan, Domen

2007-01-01

The effect of two earthworm species, Lumbricus rubellus and Eisenia fetida, on the fractionation/bioavailability of Pb and Zn before and after soil leaching with EDTA was studied. Four leaching steps with total 12.5 mmol kg -1 EDTA removed 39.8% and 6.1% of Pb and Zn, respectively. EDTA removed Pb from all soil fractions fairly uniformly (assessed using sequential extractions). Zn was mostly present in the chemically inert residual soil fraction, which explains its poor removal. Analysis of earthworm casts and the remainder of the soil indicated that L. rubellus and E. fetida actively regulated soil pH, but did not significantly change Pb and Zn fractionation in non-remediated and remediated soil. However, the bioavailability of Pb (assessed using Ruby's physiologically based extraction test) in E. fetida casts was significantly higher than in the bulk of the soil. In remediated soil the Pb bioavailability in the simulated stomach phase increased by 5.1 times. - Earthworm activity increases heavy metal bioavailability in soil before and after remediation

The effect of earthworms on the fractionation and bioavailability of heavy metals before and after soil remediation

Energy Technology Data Exchange (ETDEWEB)

Udovic, Metka [Agronomy Department, Centre for Soil and Environmental Science, Biotechnical Faculty, University of Ljubljana, Jamnikarjeva 101, 1000 Ljubljana (Slovenia); Lestan, Domen [Agronomy Department, Centre for Soil and Environmental Science, Biotechnical Faculty, University of Ljubljana, Jamnikarjeva 101, 1000 Ljubljana (Slovenia)]. E-mail: domen.lestan@bf.uni-lj.si

2007-07-15

The effect of two earthworm species, Lumbricus rubellus and Eisenia fetida, on the fractionation/bioavailability of Pb and Zn before and after soil leaching with EDTA was studied. Four leaching steps with total 12.5 mmol kg{sup -1} EDTA removed 39.8% and 6.1% of Pb and Zn, respectively. EDTA removed Pb from all soil fractions fairly uniformly (assessed using sequential extractions). Zn was mostly present in the chemically inert residual soil fraction, which explains its poor removal. Analysis of earthworm casts and the remainder of the soil indicated that L. rubellus and E. fetida actively regulated soil pH, but did not significantly change Pb and Zn fractionation in non-remediated and remediated soil. However, the bioavailability of Pb (assessed using Ruby's physiologically based extraction test) in E. fetida casts was significantly higher than in the bulk of the soil. In remediated soil the Pb bioavailability in the simulated stomach phase increased by 5.1 times. - Earthworm activity increases heavy metal bioavailability in soil before and after remediation.

Vapor-phase biofiltration: Laboratory and field experience

International Nuclear Information System (INIS)

Evans, P.J.; Bourbonais, K.A.; Peterson, L.E.; Lee, J.H.; Laakso, G.L.

1995-01-01

Application of vapor-phase bioreactors (VPBs) to petroleum hydrocarbons is complicated by the different mass transfer characteristics of aliphatics and aromatics. Laboratory- and pilot-scale VPB studies were conducted to evaluate treatment of soil vapor extraction (SVE) off-gas. A mixture of compost, perlite, and activated carbon was the selected medium based on pressure drop, microbial colonization, and adsorption properties. Two different pilot-scale reactors were built with a difference of 70:1 in scale. The smaller VPB's maximum effective elimination capacity (EC) was determined to be 7.2 g m -3 h -1 ; the larger unit's EC was 70% to 80% of this value. Low EC values may be attributable to a combination of mass-transfer and kinetic limitations

Experimental and theoretical investigations about the vaporization of laser-produced aerosols and individual particles inside inductively-coupled plasmas — Implications for the extraction efficiency of ions prior to mass spectrometry

International Nuclear Information System (INIS)

Flamigni, Luca; Koch, Joachim; Günther, Detlef

2012-01-01

Current quantification capabilities of laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) are known to be restricted by elemental fractionation as a result of LA-, transport-, and ICP-induced effects which, particularly, may provoke inaccuracies whenever calibration strategies on the basis of non-matrix matched standard materials are applied. The present study is dealing with the role of ICP in this complex scenario. Therefore, the vaporization process of laser-produced aerosols and subsequent diffusion losses occurring inside ICP sources were investigated using 2-D optical emission spectrometry (OES) and ICP-quadrupole (Q)MS of individual particles. For instance, Na- and Ca-specific OES of aerosols produced by LA of silicate glasses or metals revealed axial shifts in the onset and maximum position of atomic emission which were in the range of a few millimeters. The occurrence of these shifts was found to arise from composition-dependent particle/aerosol penetration depths, i.e. the displacement of axial vaporization starting points controlling the ion extraction efficiency through the ICP-MS vacuum interface due to a delayed, diffusion-driven expansion of oxidic vs. metallic aerosols. Furthermore, ICP-QMS of individual particles resulted in 1/e half-value signal durations of approximately 100 μs, which complies with modeled values if OES maxima are assumed to coincide with positions of instantaneous vaporization and starting points for atomic diffusion. To prove phenomena observed for their consistency, in addition, “ab initio” as well as semi-empirical simulations of particle/aerosol penetration depths followed by diffusion-driven expansion was accomplished indicating differences of up to 15% in the relative ion extraction efficiency depending on whether analytes are supplied as metals or oxides. Implications of these findings on the accuracy achievable by state-of-the-art LA-ICP-MS systems are outlined. - Highlights: ► Specification

Soil radiological characterisation and remediation at CIEMAT

International Nuclear Information System (INIS)

Correa, Cristina; Garcia Tapias, Esther; Leganes, Jose

2012-01-01

Located in Madrid, CIEMAT is the Spanish Centre for Energy-Related, Environmental and Technological Research. It used to have more than 60 facilities in operation that allowed a wide range of activities in the nuclear field and in the application of ionising radiations. At present, the centre includes several facilities; some of them are now obsolete, shut down and in dismantling phases. In 2000 CIEMAT started the 'Integrated plan for the improvement of CIEMAT facilities (PIMIC)', which includes activities for the decontamination, dismantling, rehabilitation of obsolete installations and soil remediation activities. A small contaminated area named with the Spanish word 'Lenteja' (Lentil), has had to be remediate and restored. In the 70's, an incidental leakage of radioactive liquid occurred during a transference operation from the Reprocessing Plant to the Liquid Treatment Installation, and contaminated about 1000 m 3 of soil. Remediation activities in this area started with an exhaustive radiological characterisation of the soil, including surface samples and up to 16 meters boreholes, and the development of a comprehensive radiological characterization methodology for pre-classification of materials. Once the framework was defined the following tasks were being carried out: preparation of the area, soil extraction activities and final radiological characterisation for release purposes. Next step will be the refilling of the resulting hole from the removal soil activities. This paper will describe the soil radiological characterization and remediation activities at the Lentil Zone in Ciemat Research Centre. (authors)

Proceedings (of the) first annual groundwater and soil remediation R, D and D (research, development and demonstration) symposium

Energy Technology Data Exchange (ETDEWEB)

1991-01-01

A symposium was held to present results of research on the remediation of contamination of groundwater and soils. Papers were presented on groundwater/soil remediation research and demonstration programs, in-situ bioremediation, remediation of groundwater contaminated by gasoline-derived aromatics, solvent extraction of petroleum hydrocarbons from soil, bioreactors for cleaning hydrocarbon- and salt-contaminated soils, in-situ volatilization technologies, evaluations of spill cleanup technologies, remediating subsurface contamination around sour gas processing plants, and the influence of gasoline oxygenates on the persistence of aromatics in groundwater. Separate abstracts have been prepared for 9 papers from this symposium.

In-situ active/passive bioreclamation of vadose zone soils contaminated with gasoline and waste oil using soil vapor extraction/bioventing: Laboratory pilot study to full scale site operation

International Nuclear Information System (INIS)

Zachary, S.P.; Everett, L.G.

1993-01-01

The use of soil venting to supply oxygen and remove metabolites from the biodegradation of light hydrocarbons is a cost effective in-situ remediation approach. To date, little data exists on the effective in-situ bioreclamation of vadose zone soil contaminated with waste/hydraulic oil without excavation or the addition of water or nutrients to degrade the heavy petroleum contaminants. Gasoline and waste/hydraulic oil contaminated soils below an active commercial building required an in-situ non-disruptive remediation approach. Initial soil vapor samples collected from the vadose zone revealed CO 2 concentrations in excess of 16% and O 2 concentrations of less than 1% by volume. Soil samples were collected from below the building within the contaminated vadose zone for laboratory chemical and physical analysis as well as to conduct a laboratory biotreatability study. The laboratory biotreatability study was conducted for 30 days to simulate vadose zone bioventing conditions using soil taken from the contaminated vadose zone. Results of the biotreatability study revealed that the waste oil concentrations had been reduced from 960 mg/Kg to non-detectable concentrations within 30 days and the volatile hydrocarbon content had decreased exponentially to less than 0.1% of the original concentration. Post treatability study biological enumeration revealed an increase in the microbial population of two orders of magnitude

Biochemical basis of mercury remediation and bioaccumulation by Enterobacter sp. EMB21.

Science.gov (United States)

Sinha, Arvind; Kumar, Sumit; Khare, Sunil Kumar

2013-01-01

The aims of this study were to isolate metal bioaccumulating bacterial strains and to study their applications in removal of environmental problematic heavy metals like mercury. Five bacterial strains belonging to genera Enterobacter, Bacillus, and Pseudomonas were isolated from oil-spilled soil. Among these, one of the strains Enterobacter sp. EMB21 showed mercury bioaccumulation inside the cells simultaneous to its bioremediation. The bioaccumulation of remediated mercury was confirmed by transmission electron microscopy and energy dispersive X-ray. The mercury-resistant loci in the Enterobacter sp. EMB21 cells were plasmid-mediated as confirmed by transformation of mercury-sensitive Escherichia coli DH5α by Enterobacter sp. EMB21 plasmid. Effect of different culture parameters viz-a-viz inoculum size, pH, carbon, and nitrogen source revealed that alkaline pH and presence of dextrose and yeast extract favored better remediation. The results indicated the usefulness of Enterobacter sp. EMB21 for the effective remediation of mercury in bioaccumulated form. The Enterobacter sp. EMB21 seems promising for heavy metal remediation wherein the remediated metal can be trapped inside the cells. The process can further be developed for the synthesis of valuable high-end functional alloy, nanoparticles, or metal conjugates from the metal being remediated.

Electrochemical EDTA recycling with sacrificial Al anode for remediation of Pb contaminated soil

International Nuclear Information System (INIS)

Pociecha, Maja; Lestan, Domen

2010-01-01

Recycling chelant is a precondition for cost-effective EDTA-based soil remediation. Extraction with EDTA removed 67.5% of Pb from the contaminated soil and yielded washing solution with 1535 mg L -1 Pb and 33.4 mM EDTA. Electrochemical treatment of the washing solution using Al anode, current density 96 mA cm -2 and pH 10 removed 90% of Pb from the solution (by electrodeposition on the stainless steel cathode) while the concentration of EDTA in the treated solution remained the same. The obtained data indicate that the Pb in the EDTA complex was replaced by electro-corroded Al after electro-reduction of the EDTA and subsequently removed from the solution. Additional soil extraction with the treated washing solution resulted in total removal of 87% of Pb from the contaminated soil. The recycled EDTA retained the Pb extraction potential through several steps of soil extraction and washing solution treatment, although part of the EDTA was lost by soil absorption. - Aluminium anode at alkaline pH in conventional electrolytic cell enables efficient recycling of EDTA as a part of soil washing remediation technology.

Vapor Intrusion Facility Points, South Bay CA, 2014, US EPA Region 9

Data.gov (United States)

U.S. Environmental Protection Agency — POINT locations for the South Bay Vapor Instrusion Sites were derived from the NPL data for Region 9. One site, Philips Semiconductor, was extracted from the...

Clinical Efficacy and Safety of Benjakul Remedy Extract for Treating Primary Osteoarthritis of Knee Compared with Diclofenac: Double Blind, Randomized Controlled Trial

Directory of Open Access Journals (Sweden)

Patamaporn Rachawat

2017-01-01

Full Text Available Background. The purpose of this study was to investigate the clinical efficacy and safety of Benjakul (BJK extract for treating primary osteoarthritis (OA of the knee compared with diclofenac. Methods. A phase 2, double blind, randomized, and controlled study was conducted. The BJK group received 300 mg of BJK extract per day, while another group received 75 mg of diclofenac per day. All patients were followed up at 14 and 28 days. The changing of visual analogue scale (VAS for pain, 100-meter walking times, the modified Thai WOMAC index scores, and the global assessment were evaluated for efficacy. For safety issue, clinical signs and symptoms, complete physical examination, and renal and liver function were evaluated. Results. 39 and 38 patients for BJK extract group and diclofenac group were evaluated. For efficacy, all patients from both groups reported a decrease in the VAS pain score and 100-meter walking times but only the diclofenac group showed significant reduction of both measurements when compared with day 0. The modified Thai WOMAC scores of both groups were significantly reduced from baseline. However, all efficacy outcomes were not significantly different for both groups. For safety outcomes, the patients from both groups had no severe adverse events reported and only BJK had no toxicity in renal and liver functions. Conclusions. The BJK remedy extract showed equal clinical efficacy in relieving symptoms of OA knee when compared with diclofenac.

Vapor pressure and enthalpy of vaporization of aliphatic propanediamines

International Nuclear Information System (INIS)

Verevkin, Sergey P.; Chernyak, Yury

2012-01-01

Highlights: ► We measured vapor pressure of four aliphatic 1,3-diamines. ► Vaporization enthalpies at 298 K were derived. ► We examined consistency of new and available data in the literature. ► A group-contribution method for prediction was developed. - Abstract: Vapor pressures of four aliphatic propanediamines including N-methyl-1,3-propanediamine (MPDA), N,N-dimethyl-1,3-propanediamine (DMPDA), N,N-diethyl-1,3-propanediamine (DEPDA) and N,N,N′,N′-tetramethyl-1,3-propanediamine (4MPDA) were measured using the transpiration method. The vapor pressures developed in this work and reported in the literature were used to derive molar enthalpy of vaporization values at the reference temperature 298.15 K. An internal consistency check of the enthalpy of vaporization was performed for the aliphatic propanediamines studied in this work. A group-contribution method was developed for the validation and prediction vaporization enthalpies of amines and diamines.

Tank vapor sampling and analysis data package for tank 241-C-106 waste retrieval sluicing system process test phase III

Energy Technology Data Exchange (ETDEWEB)

LOCKREM, L.L.

1999-08-13

This data package presents sampling data and analytical results from the March 28, 1999, vapor sampling of Hanford Site single-shell tank 241-C-106 during active sluicing. Samples were obtained from the 296-C-006 ventilation system stack and ambient air at several locations. Characterization Project Operations (CPO) was responsible for the collection of all SUMMATM canister samples. The Special Analytical Support (SAS) vapor team was responsible for the collection of all triple sorbent trap (TST), sorbent tube train (STT), polyurethane foam (PUF), and particulate filter samples collected at the 296-C-006 stack. The SAS vapor team used the non-electrical vapor sampling (NEVS) system to collect samples of the air, gases, and vapors from the 296-C-006 stack. The SAS vapor team collected and analyzed these samples for Lockheed Martin Hanford Corporation (LMHC) and Tank Waste Remediation System (TWRS) in accordance with the sampling and analytical requirements specified in the Waste Retrieval Sluicing System Vapor Sampling and Analysis Plan (SAP) for Evaluation of Organic Emissions, Process Test Phase III, HNF-4212, Rev. 0-A, (LMHC, 1999). All samples were stored in a secured Radioactive Materials Area (RMA) until the samples were radiologically released and received by SAS for analysis. The Waste Sampling and Characterization Facility (WSCF) performed the radiological analyses. The samples were received on April 5, 1999.

A strategy for improving pump and treat ground water remediation

International Nuclear Information System (INIS)

Hoffman, F.

1992-07-01

Established pump and treat ground water remediation has a reputation for being too expensive and time consuming, especially when cleanup standards are set at very low levels, e.g., 50 ft below ground surface) widespread ground water contamination. The perceived shortcomings of pump and treat result from the (1) tendency of most contaminants to sorb to formation materials, thus retarding contaminant removal; (2) geologic complexity, which requires detailed characterization for the design of optimal extraction systems within available resources; and (3) failure to apply dynamic well field management techniques. An alternative strategy for improving pump and treat ground water remediation consists of (1) detailed characterization of the geology, hydrology, and chemistry; (2) use of computer-aided data interpretation, data display, and decision support systems; (3) removal of sources, if possible; (4) initial design for plume containment and source remediation; (5) phased installation of the well field; (6) detailed monitoring of the remediation; (7) active ongoing re-evaluation of the operating well field, including redesign as appropriate (dynamic management); (8) re-injection of treated ground water to speed the flushing of contaminants; and (9) setting of appropriate cleanup levels or goals. Use of some or all of these techniques can dramatically reduce the time required to achieve cleanup goals and thus the cost of ground water remediation

Remediation of trichloroethylene-contaminated soils by star technology using vegetable oil smoldering.

Science.gov (United States)

Salman, Madiha; Gerhard, Jason I; Major, David W; Pironi, Paolo; Hadden, Rory

2015-03-21

Self-sustaining treatment for active remediation (STAR) is an innovative soil remediation approach based on smoldering combustion that has been demonstrated to effectively destroy complex hydrocarbon nonaqueous phase liquids (NAPLs) with minimal energy input. This is the first study to explore the smoldering remediation of sand contaminated by a volatile NAPL (trichloroethylene, TCE) and the first to consider utilizing vegetable oil as supplemental fuel for STAR. Thirty laboratory-scale experiments were conducted to evaluate the relationship between key outcomes (TCE destruction, rate of remediation) to initial conditions (vegetable oil type, oil: TCE mass ratio, neat versus emulsified oils). Several vegetable oils and emulsified vegetable oil formulations were shown to support remediation of TCE via self-sustaining smoldering. A minimum concentration of 14,000 mg/kg canola oil was found to treat sand exhibiting up to 80,000 mg/kg TCE. On average, 75% of the TCE mass was removed due to volatilization. This proof-of-concept study suggests that injection and smoldering of vegetable oil may provide a new alternative for driving volatile contaminants to traditional vapour extraction systems without supplying substantial external energy. Copyright © 2014 Elsevier B.V. All rights reserved.

The remediation of tributyltin-contaminated dredgins and waters

OpenAIRE

Gkenakou, Evgenia-Varvara

2008-01-01

Tributyltin (TBT) is a pollutant, mainly introduced to the environment as a marine anti-fouling agent. The aim of this work was to assess and develop sustainable and cost-effective remediation technologies for TBT-contaminated dredged materials. For this purpose, analytical methods were developed for sediments and sediment leachates.For the sediments, a triple extraction followed by derivatisation and measurement by gas chromatography with pulsed flame photometric detection was employed, avoi...

Vapor pressure and enthalpy of vaporization of linear aliphatic alkanediamines

International Nuclear Information System (INIS)

Pozdeev, Vasiliy A.; Verevkin, Sergey P.

2011-01-01

Highlights: → We measured vapor pressure of diamines H 2 N-(CH 2 ) n -NH 2 with n = 3 to 12. → Vaporization enthalpies at 298 K were derived. → We examined consistency of new and available in the literature data. → Enthalpies of vaporization show linear dependence on numbers n. → Enthalpies of vaporization correlate linearly with Kovat's indices. - Abstract: Vapor pressures and the molar enthalpies of vaporization of the linear aliphatic alkanediamines H 2 N-(CH 2 ) n -NH 2 with n = (3 to 12) have been determined using the transpiration method. A linear correlation of enthalpies of vaporization (at T = 298.15 K) of the alkanediamines with the number n and with the Kovat's indices has been found, proving the internal consistency of the measured data.

Electrodialytic extraction of heavy metals from Greenlandic MSWI fly ash as a function of remediation time and L/S ratio

DEFF Research Database (Denmark)

Kirkelund, Gunvor Marie; Jensen, Pernille Erland; Ottosen, Lisbeth M.

2013-01-01

, where the fly ash was suspended in distilled water in different liquid to solid (L/S) ratios. Remediation times of 7 and 14 days were tested and the current strength was 50 mA in all experiments. The highest removal was seen when an acidic pH in the fly ash suspension was obtained. In an experiment...... lasting 14 days with L/S 10, up to 60 % Cd, 45 % Zn, 20 % Ni and Ba was removed. Regardless of the remediation time and L/S ratio, the fraction of soluble Ba, Cr and Pb decreased due to the electrodialytic remediation. The electrodialytic remediation method showed potential as a treatment method...

Development of site remediation technologies in European countries

International Nuclear Information System (INIS)

Nunno, T.J.; Hyman, J.A.; Pheiffer, T.

1988-01-01

Site remediation is a pressing issue in European countries due to limited availability of land. Therefore, much progress is being made in the development of effective technologies for remediating contaminated sites. The purpose of this program was to investigate the most successful and innovative technologies for potential application into US markets. This EPA-sponsored project was based on a 9-month research effort which identified 95 innovative technologies in use or being researched in foreign countries. The most promising technologies were studied in-depth through personal interviews with the engineers who research and apply these technologies, and tours of laboratory models and full-scale installations. The most successful full-scale technologies investigated were developed in Holland, West Germany and Belgium. These technologies include vacuum extraction of hydrocarbons from soil, in situ washing of cadmium-polluted soil, rotating biocontractors for treating pesticides in ground water, high-temperature slagging incineration of low-level radioactive wastes, in situ steam stripping, and a number of landfarming and soil washing operations. The paper provides description of 13 site remediation techniques that have shown such promise in laboratory studies or in practice to warrant consideration of their use in the US

Analysis of Water Extraction From Lunar Regolith

Science.gov (United States)

Hegde, U.; Balasubramaniam, R.; Gokoglu, S.

2012-01-01

Distribution of water concentration on the Moon is currently an area of active research. Recent studies suggest the presence of ice particles, and perhaps even ice blocks and ice-cemented regolith on the Moon. Thermal extraction of the in-situ water is an attractive means of sa tisfying water requirements for a lunar mission. In this paper, a model is presented to analyze the processes occurring during the heat-up of icy regolith and extraction of the evolved water vapor. The wet regolith is assumed to be present in an initially evacuated and sealed cell which is subsequently heated. The first step of the analysis invol ves calculating the gradual increase of vapor pressure in the closed cell as the temperature is raised. Then, in the second step, the cell is evacuated to low pressure (e.g., vacuum), allowing the water vapor to leave the cell and be captured. The parameters affecting water vap or pressure build-up and evacuation for the purpose of extracting water from lunar regolith are discussed in the paper. Some comparisons wi th available experimental measurements are also made.

Physical vapor deposited thin films of lignins extracted from sugar cane bagasse: morphology, electrical properties, and sensing applications.

Science.gov (United States)

Volpati, Diogo; Machado, Aislan D; Olivati, Clarissa A; Alves, Neri; Curvelo, Antonio A S; Pasquini, Daniel; Constantino, Carlos J L

2011-09-12

The concern related to the environmental degradation and to the exhaustion of natural resources has induced the research on biodegradable materials obtained from renewable sources, which involves fundamental properties and general application. In this context, we have fabricated thin films of lignins, which were extracted from sugar cane bagasse via modified organosolv process using ethanol as organic solvent. The films were made using the vacuum thermal evaporation technique (PVD, physical vapor deposition) grown up to 120 nm. The main objective was to explore basic properties such as electrical and surface morphology and the sensing performance of these lignins as transducers. The PVD film growth was monitored via ultraviolet-visible (UV-vis) absorption spectroscopy and quartz crystal microbalance, revealing a linear relationship between absorbance and film thickness. The 120 nm lignin PVD film morphology presented small aggregates spread all over the film surface on the nanometer scale (atomic force microscopy, AFM) and homogeneous on the micrometer scale (optical microscopy). The PVD films were deposited onto Au interdigitated electrode (IDE) for both electrical characterization and sensing experiments. In the case of electrical characterization, current versus voltage (I vs V) dc measurements were carried out for the Au IDE coated with 120 nm lignin PVD film, leading to a conductivity of 3.6 × 10(-10) S/m. Using impedance spectroscopy, also for the Au IDE coated with the 120 nm lignin PVD film, dielectric constant of 8.0, tan δ of 3.9 × 10(-3), and conductivity of 1.75 × 10(-9) S/m were calculated at 1 kHz. As a proof-of-principle, the application of these lignins as transducers in sensing devices was monitored by both impedance spectroscopy (capacitance vs frequency) and I versus time dc measurements toward aniline vapor (saturated atmosphere). The electrical responses showed that the sensing units are sensible to aniline vapor with the process being

Guidelines for active spreading during in situ chemical oxidation to remediate contaminated groundwater

Science.gov (United States)

The effectiveness of in situ chemical oxidation to remediate contaminated aquifers depends on the extent and duration of contact between the injected treatment chemical and the groundwater contaminant (the reactants). Techniques that inject and extract in the aquifer to ‘ac...

Geostatistical approach for assessing soil volumes requiring remediation: validation using lead-polluted soils underlying a former smelting works.

Science.gov (United States)

Demougeot-Renard, Helene; De Fouquet, Chantal

2004-10-01

Assessing the volume of soil requiring remediation and the accuracy of this assessment constitutes an essential step in polluted site management. If this remediation volume is not properly assessed, misclassification may lead both to environmental risks (polluted soils may not be remediated) and financial risks (unexpected discovery of polluted soils may generate additional remediation costs). To minimize such risks, this paper proposes a geostatistical methodology based on stochastic simulations that allows the remediation volume and the uncertainty to be assessed using investigation data. The methodology thoroughly reproduces the conditions in which the soils are classified and extracted at the remediation stage. The validity of the approach is tested by applying it on the data collected during the investigation phase of a former lead smelting works and by comparing the results with the volume that has actually been remediated. This real remediated volume was composed of all the remediation units that were classified as polluted after systematic sampling and analysis during clean-up stage. The volume estimated from the 75 samples collected during site investigation slightly overestimates (5.3% relative error) the remediated volume deduced from 212 remediation units. Furthermore, the real volume falls within the range of uncertainty predicted using the proposed methodology.

Relationship between solute permeability and osmotic remediability in a galactose-negative strain of Saccharomyces cerevisiae.

Science.gov (United States)

Bassel, J; Douglas, H C

1970-11-01

An osmotic remedial allele, gal 7-1, in the galactose pathway of Saccharomyces cerevisiae responds to either penetrating (ethylene glycol and diethylene glycol) or nonpenetrating (KCl, NaCl, and sorbitol) solutes in the growth medium. Extracts from cells grown under restrictive conditions gave no increase in enzyme activity (gal-1-phosphate, uridylyl transferase) when exposed to the penetrating solutes; thus protein synthesis or possibly polymer assembly is proposed as the critical step remedied by the addition of the solutes.

An overview of the mixed waste landfill integrated demonstration

International Nuclear Information System (INIS)

Williams, C.V.; Burford, T.D.

1994-01-01

Prior to May 1992, field demonstrations of characterization technologies were performed at an uncontaminated site near the Chemical Waste Landfill. In mid-1992 through summer 1993, both non-intrusive and intrusive characterization techniques were demonstrated at the Chemical Waste Landfill. Subsurface and dry barrier demonstrations were started in summer 1993 and will continue into 1995. Future plans include demonstrations of innovative drilling, characterization and long-term monitoring, and remediation techniques. Demonstrations were also scheduled in summer 1993 at the Kirtland Air Force HSWA site and will continue in 1994. The first phase of the Thermal Enhanced Vapor Extraction System (TEVES) project occurred in April 1992 when two holes were drilled and vapor extraction wells were installed at the Chemical Waste Landfill. Obtaining the engineering design and environmental permits necessary to implement this field demonstration will take until early 1994. Field demonstration of the vapor extraction system will occur in 1994

Phosphorus Amendment Efficacy for In Situ Remediation of ...

Science.gov (United States)

A validated method is needed to measure reductions of in vitro bioaccessible (IVBA) Pb in urban soil remediated with amendments. This study evaluated the effect of in vitro extraction solution pH and glycine buffer on bioaccesible Pb in P-treated soils. Two Pb-contaminated soils (790-1300 mg Pb kg-1), one from a garden and one from a city lot in Cleveland, OH, were incubated in a bench scale experiment for 1 yr. Six phosphate amendments, including bone meal, fish bone, poultry litter, monoammonium phosphate, diammonium phosphate, and triple superphosphate, were added to containers at two application rates. Lead IVBA was assessed using USEPA Method 1340 and three modified versions of this method. Modifications included using solutions with pH 1.5 and 2.5 as well as using solutions with and without 0.4 mol L-1 glycine. Soil amendments were effective in reducing IVBA Pb in these soils as measured by pH 1.5 with glycine buffer. The greatest reductions in IVBA Pb, from 5 to 26%, were found using pH 2.5 extractions. Lead mineral results showed several soil amendments promoted Pb phosphate formation, an indicator of remediation success. A significant negative linear relationship between reduction in IVBA Pb and Pb-phosphate formation was found only for pH 2.5 without glycine extraction solution. A modified USEPA Method 1340 without glycine and using pH 2.5 has the potential to predict P soil treatment efficacy and reductions in bioavailable Pb. Developing mana

In situ diesel fuel bioremediation: A case history

International Nuclear Information System (INIS)

Rhodes, D.K.; Burke, G.K.; Smith, N.; Clark, D.

1995-01-01

As a result of a ruptured fuel line, the study site had diesel fuel soil contamination and free product more than 2 ft (0.75 m) thick on the groundwater surface. Diesel fuel, which is composed of a high percentage of nonvolatile compounds, has proven difficult to remediate using conventional extraction remediation techniques. A number of remedial alternatives were reviewed, and the patented in situ biodegradation BioSparge SM technology was selected for the site and performed under license by a specialty contractor. BioSparge SM is a field-proven closed-loop (no vapor emissions) system that supplies a continuous, steady supply of oxygen, moisture, and additional heat to enhance microorganism activity. The system injects an enriched airstream beneath the groundwater surface elevation and/or within the contaminant plume and removes residual vapors from vadose zone soil within and above the contaminant plume. The technology has no air discharge, which is critical in areas where strict air discharge regulations apply. The focus of this paper is the viability of in situ biodegradation as an effective remediation alternative for reducing nonvolatile petroleum products

VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS

Energy Technology Data Exchange (ETDEWEB)

Eric M. Suuberg; Vahur Oja

1997-07-01

This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization which have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.

Chemically enhanced mixed region vapor stripping of TCE-contaminated saturated peat and silty clay soils

International Nuclear Information System (INIS)

West, O.R.; Cameron, P.A.; Lucero, A.J.; Koran, L.J. Jr.

1996-01-01

The objective of this study was to conduct further testing of MRVS, chemically enhanced with calcium oxide conditioning, on field- contaminated soils collected from beneath the NASA Michoud Rinsewater Impoundment. In this study, residual soil VOC levels as a function of vapor stripping time were measured to quantify VOC removal rates. Physical and chemical soil parameters expected to affect MRVS efficiency were measures. The effects of varying the calcium oxide loadings as well as varying the vapor stripping flow rates on VOC removal were also evaluated. The results of this study will be used to determine whether acceptable removals can be achieved within reasonable treatment times, remediation costs being directly proportional to the latter. The purpose of this report is to document the experimental results of this study, as well as to address issues that were raised after completion of the previous Michoud treatability work

Electrodialytic soil remediation

DEFF Research Database (Denmark)

Karlsmose, Bodil; Ottosen, Lisbeth M.; Hansen, Lene

1999-01-01

The paper gives an overview of how heavy metals can be found in the soil and the theory of electrodialytic remediation. Basically electrodialytic remediation works by passing electric current through the soil, and the heavy metals in ionic form will carry some of the current. Ion-exchange membranes...... prevents the protons and the hydroxides ions from the electrode processes to enter the soil. The heavy metals are collected in a concentration compartment, which is separated from the soil by ion-exchange membranes. Examples from remediation experiments are shown, and it is demonstrated that it is possible...... to remediate soil polluted with heavy metals be this method. When adding desorbing agents or complexing agents, chosing the right current density, electrolyte and membranes, the proces can be optimised for a given remediation situation. Also electroosmosis is influencing the system, and if extra water...

Three-dimensional calculation of pollutant migration via compressible two-phase flow, for analysis of the methods of in situ air sparging and soil vapor extraction; Raeumliche Berechnung des Schadstofftransportes mit einer kompressiblen Zweiphasenstroemung zur Untersuchung der Drucklufteinblasung und Bodenluftabsaugung

Energy Technology Data Exchange (ETDEWEB)

Kuepper, S.

1997-12-01

In this study an analysis method is presented which allows numerical simulation of in situ air sparging coupled with soil vapor extraction. The improved FE-program takes the following phenomena into account: - Two-phase flow of compressible air and incompressible water - convective-dispersive contamination migration with air and water - transfer of volatile components from liquid phase to gas and water phase - sorption of contaminants onto soil - transfer of contaminants between air and water phase - biological processes. By means of back calculations of the results of laboratory experiments made by Eisele (1989) it was shown that with the developed program GWLCOND some of the necessary parameters for the numerical simulation of remedial systems can be determined. (orig./SR) [Deutsch] In dieser Arbeit wird ein Verfahren vorgestellt, mit dem eine numerische Simulation der Drucklufteinblasung und Bodenluftabsaugung durchgefuehrt werden kann. Das weiterentwickelte FE-Programmsystem beinhaltet folgende Ablaeufe: - Zweiphasenstroemung der kompressiblen Luft- und der inkompressiblen Wasserphase - Konvektiv-dispersiver Schadstofftransport mit der Gas- und der Wasserphase - Uebergang fluessiger Schadstoffe in die Gas- und in die Wasserphase - Sorption der Schadstoffe an der Feststoffphase - Uebergang der Schadstoffe zwischen der Gas- und der Wasserphase - Biologischer Abbau. Anhand der Nachrechnung eines Laborversuches von Eisele (1989) wird gezeigt, wie mit dem entwickelten Transportprogramm GWLCOND ein Teil der fuer die numerische Simulation des Sanierungsverfahrens benoetigten Kennwerte ermittelt werden kann. (orig./SR)

Enthalpy of Vaporization and Vapor Pressures: An Inexpensive Apparatus

Science.gov (United States)

Battino, Rubin; Dolson, David A.; Hall, Michael A.; Letcher, Trevor M.

2007-01-01

A simple and inexpensive method to determine the enthalpy of vaporization of liquids by measuring vapor pressure as a function of temperature is described. The vapor pressures measured with the stopcock cell were higher than the literature values and those measured with the sidearm rubber septum cell were both higher and lower than literature…

Organic, inorganic and total mercury determination in fish by chemical vapor generation with collection on a gold gauze and electrothermal atomic absorption spectrometry

International Nuclear Information System (INIS)

Duarte, Fabio Andrei; Bizzi, Cezar Augusto; Goldschmidt Antes, Fabiane; Dressler, Valderi Luiz; Flores, Erico Marlon de Moraes

2009-01-01

A method for organic, inorganic and total mercury determination in fish tissue has been developed using chemical vapor generation and collection of mercury vapor on a gold gauze inside a graphite tube and further atomization by electrothermal atomic absorption spectrometry. After drying and cryogenic grinding, potassium bromide and hydrochloric acid solution (1 mol L - 1 KBr in 6 mol L - 1 HCl) was added to the samples. After centrifugation, total mercury was determined in the supernatant. Organomercury compounds were selectively extracted from KBr solution using chloroform and the resultant solution was back extracted with 1% m/v L-cysteine. This solution was used for organic Hg determination. Inorganic Hg remaining in KBr solution was directly determined by chemical vapor generation electrothermal atomic absorption spectrometry. Mercury vapor generation from extracts was performed using 1 mol L - 1 HCl and 2.5% m/v NaBH 4 solutions and a batch chemical vapor generation system. Mercury vapor was collected on the gold gauze heated resistively at 80 deg. C and the atomization temperature was set at 650 deg. C. The selectivity of extraction was evaluated using liquid chromatography coupled to chemical vapor generation and determination by inductively coupled plasma mass spectrometry. The proposed method was applied for mercury analysis in shark, croaker and tuna fish tissues. Certified reference materials were used to check accuracy and the agreement was better than 95%. The characteristic mass was 60 pg and method limits of detection were 5, 1 and 1 ng g - 1 for organic, inorganic and total mercury, respectively. With the proposed method it was possible to analyze up to 2, 2 and 6 samples per hour for organic, inorganic and total Hg determination, respectively.

Enhanced bioremediation as a cost effective approach following thermally enhanced soil vapour extraction for sites requiring remediation of chlorinated solvents - 16296

International Nuclear Information System (INIS)

Kozlowska, Anna-Maria; Kahlon, Manjit S.; Langford, Steve R.; Williams, Haydn G.

2009-01-01

Thermally enhanced bioremediation can be a more cost-effective alternative to full scale in-situ thermal treatment especially for sites contaminated with chlorinated solvents, where reductive dechlorination is or might be a dominant biological step. The effect of Thermally Enhanced Soil Vapour Extraction (TESVE) on indigenous microbial communities and the potential for subsequent biological polishing of chlorinated solvents was investigated in field trials at the Western Storage Area (WSA) - RSRL (formerly United Kingdom Atomic Energy Authority - UKAEA) Oxfordshire, UK. The WSA site had been contaminated with various chemicals including mineral oil, chloroform, trichloroethane (TCA), carbon tetrachloride and tetrachloroethene (PCE). The contamination had affected the unsaturated zone, groundwater in the chalk aquifer and was a continuing source of groundwater contamination below the WSA. During TESVE the target treatment zone was heated to above the boiling point of water increasing the degree of volatilization of contaminants of concern (CoC), which were mobilised and extracted in the vapour phase. A significant reduction of concentrations of chlorinated solvent in the unsaturated zone was achieved by the full-scale application of TESVE - In Situ Thermal Desorption (ISTD) technology. The rock mass temperature within target treatment zone remained in the range of 35 deg. - 44 deg. C, 6 months after cessation of heating. The concentration of chlorinated ethenes and other CoC were found to be significantly lower adjacent to the thermal treatment area and 1 to 2 orders of magnitude lower within the thermal treatment zone. Samples were collected within and outside the thermal treatment zone using BioTraps R (passive, in- situ microbial samplers) from which the numbers of specific bacteria were measured using quantitative polymerase chain reaction (qPCR) methods of analysis. High populations of reductive de-chlorinators such as Dechalococcoides spp. and Dehalobacter spp

Degradation of chlorinated compounds in an anaerobic-aerobic process

Energy Technology Data Exchange (ETDEWEB)

Alfan-Guzman, R.; Guerrero-Barajas, C.; Garcia-Pena, I.

2009-07-01

Remediation technologies that involves gas transport (e.g., soil vapor extraction and air sparging of groundwater) cause the emission of gases contaminated with chlorinated solvents. Under anaerobic conditions, reductive dechlorination of trichloroethylene (TCE) proceeds via the formation of cis and trans dichloroethene (DCEs) and vinyl chloride (VC) as intermediates. (Author)

Bio-prospecting of distillery yeasts as bio-control and bio-remediation agents.

Science.gov (United States)

Ubeda, Juan F; Maldonado, María; Briones, Ana I; Francisco, J Fernández; González, Francisco J

2014-05-01

This work constitutes a preliminary study in which the capacity of non-Saccharomyces yeasts isolated from ancient distilleries as bio-control agents against moulds and in the treatment of waste waters contaminated by heavy metals-i.e. bio-remediation-is shown. In the first control assays, antagonist effect between non-Saccharomyces yeasts, their extracts and supernatants against some moulds, analysing the plausible (not exhaustive) involved factors were qualitatively verified. In addition, two enzymatic degrading properties of cell wall plant polymers, quitinolitic and pectinolitic, were screened. Finally, their use as agents of bio-remediation of three heavy metals (cadmium, chromium and lead) was analysed semi-quantitatively. The results showed that all isolates belonging to Pichia species effectively inhibited all moulds assayed. Moreover, P. kudriavzevii is a good candidate for both bio-control and bio-remediation because it inhibited moulds and accumulated the major proportion of the three tested metals.

Vapor pressures and vaporization enthalpy of codlemone by correlation gas chromatography

International Nuclear Information System (INIS)

Schultz, Shannon M.; Harris, Harold H.; Chickos, James S.

2015-01-01

Highlights: • The vaporization enthalpy of codlemone has been evaluated. • The vapor pressure of codlemone has been evaluated from T = (298.15 to T b ) K. • Vapor pressures for the 1-alkanols standards are available from T = (298.15 to 500) K. - Abstract: The vapor pressure and vaporization enthalpy of codlemone (trans, trans 8,10-dodecadien-1-ol), the female sex hormone of the codling moth is evaluated by correlation gas chromatography using a series of saturated primary alcohols as standards. A vaporization enthalpy of (92.3 ± 2.6) kJ · mol −1 and a vapor pressure, p/Pa = (0.083 ± 0.012) were evaluated at T = 298.15 K. An equation for the evaluation of vapor pressure from ambient temperature to boiling has been derived by correlation for codlemone. The calculated boiling temperature of T B = 389 K at p = 267 Pa is within the temperature range reported in the literature. A normal boiling temperature of T B = (549.1 ± 0.1) K is also estimated by extrapolation

Co-remediation of the lead-polluted garden soil by exogenous natural zeolite and humic acids.

Science.gov (United States)

Shi, Wei-yu; Shao, Hong-bo; Li, Hua; Shao, Ming-an; Du, Sheng

2009-08-15

The current study reported the co-remediation effect on the lead-polluted garden soil by zeolite and humic acids (HA), which was from comparing with the remediation of single zeolite in term of the lead fraction of sequential extraction in the soil and the distribution of lead in different parts of rape. Mixed treatment (zeolite and HA) and single treatment (zeolite) were, respectively, applied to the artificially polluted garden soil to examine the difference of their remediation effects in pot experiment. Results indicated that the co-remediation led to significantly greater (plead concentration in plants than by singly adding to zeolite. The co-application of zeolite and HA reduced the available fraction of lead compounds, but slightly increased (plead compounds in the garden soil, compared with the application of single zeolite, especially in the severe lead-polluted soil (> or =1000 mg kg(-1)). This method might be an efficient way to remediate the lead-polluted soils on a large scale, although zeolite is a kind of hazardous material.

The effect of fuel and chlorinated hydrocarbons on a vapor phase carbon adsorption system

International Nuclear Information System (INIS)

Crawford, W.J.; Cheney, J.L.; Taggart, D.B.

1995-01-01

A soil vapor extraction (SVE) system installed at the South Tacoma Well 12A Superfund Site was designed to recover 1,2-dichloroethylene (DCE), trichloroethylene (TCE), tetrachloroethylene (PCE), and 1,1,2,2-tetrachloroethane (1,1,2,2-TCA) from the vadose zone. The basic system consisted of twenty-two extraction wells, three centrifugal blowers, and three carbon adsorbers. The carbon adsorbers were regenerated on site by steam stripping. The mixture of steam and stripped organics was condensed and then decanted to separate the water from the organic phase. The recovered water was air stripped to remove the dissolved organics prior to discharge to the city storm sewer. The recovered organic phase was then shipped off site for thermal destruction. Previous reports described operating difficulties with the decanter, and air strippers. Sampling and analyses were performed which identified the problem as the simultaneous recovery of unexpected fuel hydrocarbons in addition to the solvents. Recovery of fuels resulted in a light phase in the decanter in addition to the water and heavy solvent phases. This required redesign of the decanter to handle the third phase. The effectiveness of desorption of the carbon beds by steam stripping gradually decreased as the remediation progressed into the second year of operation. Samples were collected from the carbon beds to evaluate the effect of the fuel and chlorinated hydrocarbons on the activated carbon. This report describes the results of these analyses. The data indicated that both 1,1,2,2-TCA and fuel hydrocarbons in the C-9 to C-24 range remained in the carbon beds after steam regeneration in sufficient quantities to require replacing the carbon

Petroleum Vapor Intrusion

Science.gov (United States)

One type of vapor intrusion is PVI, in which vapors from petroleum hydrocarbons such as gasoline, diesel, or jet fuel enter a building. Intrusion of contaminant vapors into indoor spaces is of concern.

Speciation of methylmercury and ethylmercury by gas chromatography cold vapor atomic fluresence spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Boggess, A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-09-28

Existing models and simulants of tank disposition media at SRS have presumed the presence of high concentrations of inorganic mercury. However, recent quarterly tank analyses show that mercury is present as organomercurial species at concentrations that may present challenges to remediation and disposition and may exceed the Saltstone Waste Acceptance Criteria (WAC). To-date, methylmercury analysis for Savannah River Remediation (SRR) has been performed off-site by Eurofins Scientific (Lancaster, PA). A series of optimization and validation experiments has been performed at SRNL, which has resulted in the development of on-site organomercury speciation capabilities using purge and trap gas chromatography coupled with thermal desorption cold vapor atomic fluorescence spectroscopy (P&T GC/CVAFS). Speciation has been achieved for methylmercury, with a method reporting limit (MRL) values of 1.42 pg for methylmercury. Results obtained by SRNL from the analysis of past quarterly samples from tanks 21, 40, and 50 have demonstrated statistically indistinguishable concentration values compared with the concentration data obtained from Eurofins, while the data from SRNL has demonstrated significantly improved precision and processing time.

Optimizing the Environmental Performance of In Situ Thermal Remediation Technologies Using Life Cycle Assessment

DEFF Research Database (Denmark)

Lemming, Gitte; Nielsen, Steffen G.; Weber, Klaus

2013-01-01

In situ thermal remediation technologies provide efficient and reliable cleanup of contaminated soil and groundwater, but at a high cost of environmental impacts and resource depletion due to the large amounts of energy and materials consumed. This study provides a detailed investigation of four...... in situ thermal remediation technologies (steam enhanced extraction, thermal conduction heating, electrical resistance heating, and radio frequency heating) in order to (1) compare the life-cycle environmental impacts and resource consumption associated with each thermal technology, and (2) identify...... improvements is a 10 to 21% decrease in environmental impacts and an 8 to 20% decrease in resource depletion depending on the thermal remediation technology considered. The energy consumption was found to be the main contributor to most types of environmental impacts; this will, however, depend...

Topical Day on Site Remediation

Energy Technology Data Exchange (ETDEWEB)

Vandenhove, H [ed.

1996-09-18

Ongoing activities at the Belgian Nuclear Research Centre relating to site remediation and restoration are summarized. Special attention has been paid to the different phases of remediation including characterization, impact assessment, evaluation of remediation actions, and execution of remediation actions.

Phytoavailability and geospeciation of cadmium in contaminated soil remediated by Rhodobacter sphaeroides.

Science.gov (United States)

Fan, Wenhong; Jia, Yingying; Li, Xiaomin; Jiang, Wei; Lu, Lin

2012-07-01

A microorganism was isolated from oil field injection water and identified as Rhodobacter sphaeroides. It was used for the remediation of simulated cadmium-contaminated soil. The phytoavailability of Cd was investigated through wheat seedling method to determine the efficiency of remediation. It was found that after remediation, the accumulation of Cd in wheat roots and leaves decreased by 67% and 53%, respectively. The Cd speciation in soil was determined with Tessier extraction procedure. It was found that the total Cd content in soil did not change during the experiments, but the geo-speciation of Cd changed remarkably. Among the five fractions, the concentration of exchangeable phases decreased by 27-46% and that of the phases bound to Fe-Mn oxides increased by 22-44%. The decrease of Cd accumulation in wheat showed significant positive correlation with the decrease of exchangeable phases. It could be concluded that the remediation of R. sphaeroides was carried out through the conversion of Cd to more stable forms. The decrease of sulfate concentration in supernatant indicated that the R. sphaeroides consumed sulfate. Copyright © 2012 Elsevier Ltd. All rights reserved.

The use of chelating agents in the remediation of metal-contaminated soils: A review

Energy Technology Data Exchange (ETDEWEB)

Lestan, Domen [Agronomy Department, Centre for Soil and Environmental Science, Biotechnical Faculty, University of Ljubljana, Jamnikarjeva 101, 1000 Ljubljana (Slovenia); Luo Chunling [Department of Civil and Structural Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); Li Xiangdong [Department of Civil and Structural Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong)], E-mail: cexdli@polyu.edu.hk

2008-05-15

This paper reviews current remediation technologies that use chelating agents for the mobilization and removal of potentially toxic metals from contaminated soils. These processes can be done in situ as enhanced phytoextraction, chelant enhanced electrokinetic extraction and soil flushing, or ex situ as the extraction of soil slurry and soil heap/column leaching. Current proposals on how to treat and recycle waste washing solutions after soil is washed are discussed. The major controlling factors in phytoextraction and possible strategies for reducing the leaching of metals associated with the application of chelants are also reviewed. Finally, the possible impact of abiotic and biotic soil factors on the toxicity of metals left after the washing of soil and enhanced phytoextraction are briefly addressed. - The use of synthetic chelants for soil washing and enhanced phytoextraction by plants has been well studied for the remediation of metal-contaminated soils in the last two decades.

The use of chelating agents in the remediation of metal-contaminated soils: A review

International Nuclear Information System (INIS)

Lestan, Domen; Luo Chunling; Li Xiangdong

2008-01-01

This paper reviews current remediation technologies that use chelating agents for the mobilization and removal of potentially toxic metals from contaminated soils. These processes can be done in situ as enhanced phytoextraction, chelant enhanced electrokinetic extraction and soil flushing, or ex situ as the extraction of soil slurry and soil heap/column leaching. Current proposals on how to treat and recycle waste washing solutions after soil is washed are discussed. The major controlling factors in phytoextraction and possible strategies for reducing the leaching of metals associated with the application of chelants are also reviewed. Finally, the possible impact of abiotic and biotic soil factors on the toxicity of metals left after the washing of soil and enhanced phytoextraction are briefly addressed. - The use of synthetic chelants for soil washing and enhanced phytoextraction by plants has been well studied for the remediation of metal-contaminated soils in the last two decades

Overview: Homogeneous nucleation from the vapor phase-The experimental science.

Science.gov (United States)

Wyslouzil, Barbara E; Wölk, Judith

2016-12-07

Homogeneous nucleation from the vapor phase has been a well-defined area of research for ∼120 yr. In this paper, we present an overview of the key experimental and theoretical developments that have made it possible to address some of the fundamental questions first delineated and investigated in C. T. R. Wilson's pioneering paper of 1897 [C. T. R. Wilson, Philos. Trans. R. Soc., A 189, 265-307 (1897)]. We review the principles behind the standard experimental techniques currently used to measure isothermal nucleation rates, and discuss the molecular level information that can be extracted from these measurements. We then highlight recent approaches that interrogate the vapor and intermediate clusters leading to particle formation, more directly.

Remediation Of Cadmium And Lead Contamination In Mustard-Maize Cropping System

Directory of Open Access Journals (Sweden)

Amrit Kumar Jha

2017-10-01

Full Text Available Farmers field trial was conducted at Patratu Ramgarh to study the effect of lime compost plant growth promoting rhizobacteria and arbuscular mycorrhizal fungi for remediation of high trace metal levels in mustard-maize cropping system. Results reveal that microbial inoculants with or without vermicompost increased the trace metal removal however vermicompost alone decreased the removal. Vermicompost lime and lime vermicompost significantly reduced the total Cd uptake by mustard and maize. Inoculation with Glomus mossae resulted in elevated level of Cd in mustard and maize plants. Total trace metal content in soil was significantly reduced by microbial inoculation alone or that in combination with vermicompost. However DTPA-extractable trace metals decreased with addition of amendments as well as inoculation of microbes. Glomus mossae was most effective in remediating the trace metals. under this study the total metal content reduced effectively by their inoculation alone while inoculation along with vermicompost resulted in reducing the DTPA-extractable fraction more effectively. The extent of reduction in total Cd and Pb after harvest of both crops was 6 to 26 and 5 to 12 per cent respectively over control. However the corresponding values observed for DTPA extractable Cd and Pb was 53 to 65 and 20 to 32 per cent over control in microbial inoculation and 46 to 47 and 14 to 17 per cent in case of amendments.

Phyto-remediation of contaminated soils; La phytoremediation des sols contamines

Energy Technology Data Exchange (ETDEWEB)

Morel, J.L. [Ecole Nationale Superieure Agronomie et des Industries Alimentaires, 54 - Vandoeuvre les Nancy (France)

2002-09-01

Plants provide new ways for soil remediation. The activity of living roots (absorption, exudation of organic compounds, action on physical soil properties) contribute to decrease the negative effects of pollutants, as they are stabilised or eliminated (extraction or degradation). In the presence of plants, hydrocarbons, a rather ubiquitous group of soil pollutants, are degraded faster than in bare soil. Hydrocarbon degrading bacteria are stimulated by root exudates, which also create favourable conditions for co-metabolism. Also, the fragmentation of aggregates as well as the release of surfactants increase the exposure of organic pollutants to microorganism degradation. The phyto-remediation technology is efficient to reduce the dissemination of pollutants. On historically contaminated soils, effects are generally discrete within a short period of time and may be more effective in the long run. (author)

Transformation of zinc-concentrate in surface and subsurface environments: Implications for assessing zinc mobility/toxicity and choosing an optimal remediation strategy

International Nuclear Information System (INIS)

Kwon, Man Jae; Boyanov, Maxim I.; Yang, Jung-Seok; Lee, Seunghak; Hwang, Yun Ho; Lee, Ju Yeon; Mishra, Bhoopesh; Kemner, Kenneth M.

2017-01-01

Zinc contamination in near- and sub-surface environments is a serious threat to many ecosystems and to public health. Sufficient understanding of Zn speciation and transport mechanisms is therefore critical to evaluating its risk to the environment and to developing remediation strategies. The geochemical and mineralogical characteristics of contaminated soils in the vicinity of a Zn ore transportation route were thoroughly investigated using a variety of analytical techniques (sequential extraction, XRF, XRD, SEM, and XAFS). Imported Zn-concentrate (ZnS) was deposited in a receiving facility and dispersed over time to the surrounding roadside areas and rice-paddy soils. Subsequent physical and chemical weathering resulted in dispersal into the subsurface. The species identified in the contaminated areas included Zn-sulfide, Zn-carbonate, other O-coordinated Zn-minerals, and Zn species bound to Fe/Mn oxides or clays, as confirmed by XAFS spectroscopy and sequential extraction. The observed transformation from S-coordinated Zn to O-coordinated Zn associated with minerals suggests that this contaminant can change into more soluble and labile forms as a result of weathering. For the purpose of developing a soil washing remediation process, the contaminated samples were extracted with dilute acids. The extraction efficiency increased with the increase of O-coordinated Zn relative to S-coordinated Zn in the sediment. This study demonstrates that improved understanding of Zn speciation in contaminated soils is essential for well-informed decision making regarding metal mobility and toxicity, as well as for choosing an appropriate remediation strategy using soil washing. - Graphical abstract: Graphical Abstract. Conceptual model of the apparent physical and geochemical processes controlling surface-subsurface partitioning of Zn in the study area. - Highlights: • Zn-concentrate accumulated in soils transformed to Zn species of various stability. • Zn species at our

Installation of a bio-venting remediation system using directionally drilled horizontal wells

International Nuclear Information System (INIS)

Hardy, L.; Stolz, A.P.

1997-01-01

The installation of a remediation system for off-site contamination was discussed. The site was contaminated with gasoline and diesel from an abandoned bulk fuel storage and distribution terminal located near a highway. The dissolved phase hydrocarbon plume extended beneath several houses down gradient of the site. Bioventing was considered to be the only remediation option to recover the liquid phase hydrocarbons beneath the highway in a way that would satisfy all the clean-up objectives and the design constraints. Bioventing is closely related to soil vapour extraction (SVE). The main difference is that in bioventing, the mechanism for removal of contaminants is bio-degradation by indigenous bacteria, whereas in SVE, contaminants are simply removed by volatilization. Bioventing systems enhance the activity of the indigenous bacteria by inducing air flow in the subsurface through the use of vapour injection or extraction wells. Two horizontal vapour extraction wells were installed with a directional drill. A soil pile was utilized as a bio-filter for the extracted hydrocarbon vapours and a backfilled trench was used to inject vapours recovered from the soil pile to the subsurface. The total mass of hydrocarbons degraded by this system in 230 days was estimated to be 1,000 kg. It was concluded that under appropriate conditions the in-situ treatment of contaminated soil using directionally drilled wells can be justified on both economic and technical grounds. 3 refs., 1 tab., 5 figs

The phyto-remediation of radioactively contaminated land - a feasible approach or just bananas?

International Nuclear Information System (INIS)

Nesbitt, Victoria A

2013-01-01

Soil is an essential component of all terrestrial ecosystems and is under increasing threat from human activity. Techniques available for removing radioactive contamination from soil and aquatic substrates are limited and often costly to implement; particularly over large areas. Frequently, bulk soil removal, with its attendant consequences, is a significant component of the majority of contamination incidents. Alternative techniques capable of removing contamination or exposure pathways without damaging or removing the soil are therefore of significant interest. An increasing number of old nuclear facilities are entering 'care and maintenance', with significant ground contamination issues. Phyto-remediation - the use of plants' natural metabolic processes to remediate contaminated sites is one possible solution. Its key mechanisms include phyto-extraction and phyto-stabilisation. These are analogues of existing remedial techniques. Further, phyto-remediation can improve soil quality and stability and restore functionality. Information on the application of phyto-remediation in the nuclear industry is widely distributed over an extended period of time and sources. It is therefore difficult to quickly and effectively identify which plants would be most suitable for phyto-remediation on a site by site basis. In response, a phyto-remediation tool has been developed to address this issue. Existing research and case studies were reviewed to understand the mechanisms of phyto-remediation, its effectiveness and the benefits and limitations of implementation. The potential for cost recovery from a phyto-remediation system is also briefly considered. An overview of this information is provided here. From this data, a set of matrices was developed to guide potential users through the plant selection process. The matrices take the user through a preliminary screening process to determine whether the contamination present at their site is amenable to phyto-remediation

Tank vapor sampling and analysis data package for tank 241-C-106 waste retrieval sluicing system process test phase III, sampled March 28, 1999

International Nuclear Information System (INIS)

LOCKREM, L.L.

1999-01-01

This data package presents sampling data and analytical results from the March 28, 1999, vapor sampling of Hanford Site single-shell tank 241-C-106 during active sluicing. Samples were obtained from the 296-C-006 ventilation system stack and ambient air at several locations. Characterization Project Operations (CPO) was responsible for the collection of all SUMMATM canister samples. The Special Analytical Support (SAS) vapor team was responsible for the collection of all triple sorbent trap (TST), sorbent tube train (STT), polyurethane foam (PUF), and particulate filter samples collected at the 296-C-006 stack. The SAS vapor team used the non-electrical vapor sampling (NEVS) system to collect samples of the air, gases, and vapors from the 296-C-006 stack. The SAS vapor team collected and analyzed these samples for Lockheed Martin Hanford Corporation (LMHC) and Tank Waste Remediation System (TWRS) in accordance with the sampling and analytical requirements specified in the Waste Retrieval Sluicing System Vapor Sampling and Analysis Plan (SAP) for Evaluation of Organic Emissions, Process Test Phase III, HNF-4212, Rev. 0-A, (LMHC, 1999). All samples were stored in a secured Radioactive Materials Area (RMA) until the samples were radiologically released and received by SAS for analysis. The Waste Sampling and Characterization Facility (WSCF) performed the radiological analyses. The samples were received on April 5, 1999

Strategy paper. Remedial design/remedial action 100 Area. Revision 2

International Nuclear Information System (INIS)

Donahoe, R.L.

1995-10-01

This strategy paper identifies and defines the approach for remedial design and remedial action (RD/RA) for source waste sites in the 100 Area of the Hanford Site, located in southeastern Washington State. This paper provides the basis for the US Department of Energy (DOE) to assess and approve the Environmental Restoration Contractor's (ERC) approach to RD/RA. Additionally, DOE is requesting review/agreement from the US Environmental Protection Agency (EPA) and Washington State Department of Ecology (Ecology) on the strategy presented in this document in order to expedite remedial activities

40 CFR Table 2 to Subpart Ggggg of... - Control Levels as Required by § 63.7895(a) for Tanks Managing Remediation Material With a Maximum...

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 13 2010-07-01 2010-07-01 false Control Levels as Required by § 63.7895(a) for Tanks Managing Remediation Material With a Maximum HAP Vapor Pressure Less Than 76.6 kPa 2..., Subpt. GGGGG, Table 2 Table 2 to Subpart GGGGG of Part 63—Control Levels as Required by § 63.7895(a) for...

Applicability of Phytoextraction with Arabidopsis halleri ssp. gemmifera to Remediate Cd-contaminated Andisols

Science.gov (United States)

Kameyama, Koji; Tani, Shigeru; Sugawara, Reiko; Ishikawa, Yuichi

The objective of this study was to investigate the applicability of phytoextraction with a Cd-hyperaccumulator plant (Arabidopsis halleri ssp. gemmifera) to remediate Cd-contaminated Andisols. Cd absorption potentials of this plant for Andisols were examined in pot experiments. Sequentially, phytoextraction durations for remediation of Cd-contaminated Andisols were calculated from the experimental data. The results were as follows: (1) Cd concentrations in the plant shoots ranged from 170-750 mgṡkg-1. (2) Cd absorption of the plant for Andisols with ALC (Autoclaved Lightweight aerated Concrete) was less than for Andisols without ALC. However, the plants absorbed the same amount of soil Cd extracted by 0.01 M HCl with or without ALC. (3) Calculations suggest that the applicability of phytoextraction with this plant is high for slightly contaminated Andisols. Therefore, phytoextraction with Arabidopsis halleri ssp. gemmifera may be a viable option for the remediation of Cd-contaminated Andisols.

Recovery of Platinum Group Metals from Spent Catalysts Using Iron Chloride Vapor Treatment

Science.gov (United States)

Taninouchi, Yu-ki; Okabe, Toru H.

2018-05-01

The recovery of platinum group metals (PGMs) from spent automobile catalysts is a difficult process because of their relatively low contents in the scrap. In this study, to improve the efficiency of the existing recycling techniques, a novel physical concentration method involving treatment with FeCl2 vapor has been examined. The reactions occurring between typical catalyst components and FeCl2 vapor are discussed from the thermodynamic point of view, and the validity of the proposed technique was experimentally verified. The obtained results indicate that the vapor treatment at around 1200 K (927 °C) can effectively alloy PGMs (Pt, Pd, and Rh) with Fe, resulting in the formation of a ferromagnetic alloy. It was also confirmed that cordierite and alumina (the major catalyst components) remained unreacted after the vapor treatment, while ceria species were converted into oxychlorides. The samples simulating the automobile catalyst were also subjected to magnetic separation after the treatment with FeCl2 vapor; as a result, PGMs were successfully extracted and concentrated in the form of a magnetic powder. Thus, the FeCl2 vapor treatment followed by magnetic separation can be utilized for recovering PGMs directly from spent catalysts as an effective pretreatment for the currently used recycling methods.

An integrated approach to risk-based remediation of a former bulk fuel storage facility adjacent a marine environment

Energy Technology Data Exchange (ETDEWEB)

Kemp, L.; Hers, I. [Golder Associates Ltd., Vancouver, BC (Canada)

2006-07-01

An integrated approach to risk-based remediation of a former bulk fuel storage facility adjacent to a marine environment was discussed. The presentation provided an introduction and illustration to the site location and history, located close to Skagway, Alaska and northwestern British Columbia. The site investigation and conceptual model were also presented. The remedial approach was also described with reference to a risk-based action approach, remedial objectives, soil vapour extraction (SVE)-bioventing, and air sparging-biosparging. The objectives were to minimize potential exposure to aquatic receptors by minimizing non-aqueous phase liquids (NAPL) mobility and dissolved transport of petroleum hydrocarbons. Groundwater modeling to assess the attenuation rate and to determine remedial targets was also discussed. Model validation and results of groundwater modeling as well as remediation system details and performance were then provided. It was determined that significant attenuation is occurring and that effective mass removal and concentrations have been decreasing over time. It was demonstrated that risk-based remedial goals and hydrogeology can change with land use/development. tabs., figs.

Remedial Design/Remedial Action Work Plan for Operable Units 6-05 and 10-04, Phase III

Energy Technology Data Exchange (ETDEWEB)

R. P. Wells

2006-09-19

The remedial design/remedial action for Operable Unit 6-05 (Waste Area Group 6) and Operable Unit 10-04 (Waste Area Group 10) - collectively called Operable Unit 10-04 has been divided into four phases. Phase I consists of developing and implementing institutional controls at Operable Unit 10-04 sites and developing and implementing Idaho National Laboratory-wide plans for both institutional controls and ecological monitoring. Phase II will remediate sites contaminated with trinitrotoluene and Royal Demolition Explosive. Phase III will remediate lead contamination at a gun range, and Phase IV will remediate hazards from unexploded ordnance. This Phase III remedial Design/Remedial Action Work Plan addresses the remediation of lead-contaminated soils found at the Security Training Facility (STF)-02 Gun Range located at the Idaho National Laboratory. Remediation of the STF-02 Gun Range will include excavating contaminated soils; physically separating copper and lead for recycling; returning separated soils below the remediation goal to the site; stabilizing contaminated soils, as required, and disposing of the separated soils that exceed the remediation goal; encapsulating and disposing of creosote-contaminated railroad ties and power poles; removing and disposing of the wooden building and asphalt pads found at the STF-02 Gun Range; sampling and analyzing soil to determine the excavation requirements; and when the remediation goals have been met, backfilling and contouring excavated areas and revegetating the affected area.

Cosmetics and herbal remedies with Compositae plant extracts - are they tolerated by Compositae-allergic patients?

DEFF Research Database (Denmark)

Paulsen, Evy; Christensen, Lars Porskjær; Andersen, Klaus Ejner

2008-01-01

BACKGROUND: Compositae-sensitive patients are routinely warned against topical use of Compositae-containing cosmetics and herbal remedies. However, the risk of elicitation of dermatitis in presensitized persons is unknown. OBJECTIVES: The main aim of this study was to assess the significance of d...

Radon remedial actions in schools of Friuli Venezia Giulia region (NE Italy)

International Nuclear Information System (INIS)

Giovani, C.; Cappelletto, C.; Garavaglia, M.; Pividore, S.; Villalta, R.

2004-01-01

In the last four years the Regional Agency of Environmental Protection (ARPA) of Friuli Venezia Giulia carried out a survey to determine the radon concentration in the schools of the area. During the survey all the 1320 schools and kindergartens of the region were investigated with more than 5000 measurements. In about 2% of cases, radon concentrations exceeded the reference levels of Italian law and remedial actions were performed. In collaboration with the Building Engineering Department of Udine University, ARPA FVG edited a manual concerning indications and proposals for building protection against radon. The environmental physics section of ARPA FVG, was heavily involved in the remedial action, both in the design of the action and in the investigation of effectiveness. In more than 20 schools the owners following ARPA indications solved the problem of high radon concentrations. In this paper the authors report the main type of applied remedial actions grouped taking into account the different remedial methodology. In Friuli Venezia Giulia region the main radon source is represented by soil. The contribution of building materials to high radon concentrations is negligible. The most common remedial actions consisted in natural or artificial depressurization of the soil or the crawlspace with respect to indoor building. Sometimes air was pumped into the building or air exchange number was increased. The authors show in detail the design of the performed investigations: these involved different measurement sets with passive electrets and active instruments for continuous data collection. Measurements usually last 3 contiguous weeks and are followed by long period measurements with solid track detectors. Optimization of remedial action performance was investigated when remedial action consisted in active air extraction from the soil under the buildings and fan time regulation was possible. Very often simple and cheap actions allowed a reduction of 90% in radon

Point of net vapor generation and vapor void fraction in subcooled boiling

International Nuclear Information System (INIS)

Saha, P.; Zuber, N.

1974-01-01

An analysis is presented directed at predicting the point of net vapor generation and vapor void fraction in subcooled boiling. It is shown that the point of net vapor generation depends upon local conditions--thermal and fluid dynamic. Thus, at low mass flow rates the net vapor generation is determined by thermal conditions, whereas at high mass flow rates the phenomenon is hydrodynamically controlled. Simple criteria are derived which can be used to predict these local conditions for net vapor generation. These criteria are used to determine the vapor void fraction is subcooled boiling. Comparison between the results predicted by this analysis and experimental data presently available shows good agreement for wide range of operating conditions, fluids and geometries. (U.S.)

Evaluation of technical, economic and financial feasibility for recycling and reprocessing of radioactive waste from a remediation work of low and medium activity for the extraction of heavy minerals - 59231

International Nuclear Information System (INIS)

Raposo de Almeida, Rodrigo; Mortagua, Valter J.G.

2012-01-01

Document available in abstract form only. Full text of publication follows: This paper aims to present the methodology and criteria used for the destination, discard and reuse of waste from the remediation activities of soil contaminated by radioactive waste of low activity in the USIN Plant. The site is located in Sao Paulo city, the city with the largest population of Brazil, with approximately 11 million inhabitants. As the environmental agency in Sao Paulo state, in this neighborhood there are several cases of severe contamination of soil and groundwater. The situation of contamination is so severe that it is forbidden the use of groundwater in the region for an indefinite period. Site of the plant running in a monazite processing plant for extraction of rare earths, have been filed across the land several fractions of soil containing monazite sand. In order to guide the remediation of the area for unrestricted use, was a plan for remediation of radioactive waste characterization based on geological, hydrogeological and environmental extensive in the area. From the calculation of the dose was established that the fractions of soil with concentrations of 226 Ra and 228 Ra below 0.5 Bq/g result in additional effective dose less than 1.0 mSv/yr and therefore can be kept on the ground

Sludge Treatment and Extraction Technology Development: Results of FY 1993 studies

International Nuclear Information System (INIS)

Lumetta, G.J.; Wagner, M.J.; Barrington, R.J.; Rapko, B.M.; Carlson, C.D.

1994-03-01

This report describes experimental results from work conducted in FY 1993 under the Sludge Treatment and Extraction Technology Development Task of the Tank Waste Remediation System (TWRS) Pretreatment Technology Development Project at Pacific Northwest Laboratory (PNL). Experiments were conducted in the following six general areas: (1) sludge washing, (2) sludge leaching, (3) sludge dissolution, (4) actinide separation by solvent extraction and extraction chromatography, (5) Sr separation by solvent extraction, and (6) extraction of Cs from acidic solution

Platelet activation, adhesion, inflammation, and aggregation potential are altered in the presence of electronic cigarette extracts of variable nicotine concentrations.

Science.gov (United States)

Hom, Sarah; Chen, Li; Wang, Tony; Ghebrehiwet, Berhane; Yin, Wei; Rubenstein, David A

2016-11-01

Tobacco smoke extracts prepared from both mainstream and sidestream smoking have been associated with heightened platelet activation, aggregation, adhesion, and inflammation. Conversely, it has been shown that pure nicotine inhibits similar platelet functions. In this work, we 1) evaluated the effects of e-cigarette extracts on platelet activities and 2) elucidated the differences between the nicotine-dependent and non-nicotine dependent (e.g. fine particulate matter or toxic compounds) effects of tobacco and e-cigarette products on platelet activities. To accomplish these goals, platelets from healthy volunteers (n = 50) were exposed to tobacco smoke extracts, e-cigarette vapor extracts, and pure nicotine and changes in platelet activation, adhesion, aggregation, and inflammation were evaluated, using optical aggregation, flow cytometry, and ELISA methods. Interestingly, the exposure of platelets to e-vapor extracts induced a significant up-regulation in the expression of the pro-inflammatory gC1qR and cC1qR and induced a marked increase in the deposition of C3b as compared with traditional tobacco smoke extracts. Similarly, platelet activation, as measured by a prothrombinase based assay, and platelet aggregation were also significantly enhanced after exposure to e-vapor extracts. Finally, platelet adhesion potential toward fibrinogen, von Willebrand factor, and other platelets was also enhanced after exposure to e-cigarette vapor extracts. In the presence of pure nicotine, platelet functions were observed to be inhibited, which further suggests that other constituents of tobacco smoke and electronic vapor can antagonize platelet functions, however, the presence of nicotine in extracts somewhat perpetuated the platelet functional changes in a dose-dependent manner.

Electrokinetic extraction of chromate from unsaturated soils

International Nuclear Information System (INIS)

Mattson, E.D.; Lindgren, E.R.

1993-01-01

Heavy-metal contamination of soil and groundwater is a widespread problem in industrial nations. Remediation by excavation of such sites may not be cost effective or politically acceptable. Electrokinetic remediation is one possible remediation technique for in situ removal of such contaminants from unsaturated soils. Previous papers discussing the work performed by researchers at Sandia National Laboratories (SNL) and Sat-Unsat, Inc. (SUI) (Lindgren et al., 1991, 1992, 1993) focused on the transport of contaminants and dyes by electrokinetics in unsaturated soils. These experiments were conducted with graphite electrodes with no extraction system. As the contaminants migrated through the soil, they increased in concentration at the electrode creating a diffusion flux in the opposite direction. This paper discusses a technique to remove the contaminants from unsaturated soils once they have reached an electrode

Electrokinetic extraction of chromate from unsaturated soils

Energy Technology Data Exchange (ETDEWEB)

Mattson, E.D. [SAT-UNSAT, Inc., Albuquerque, NM (United States); Lindgren, E.R. [Sandia National Labs., Albuquerque, NM (United States)

1993-11-01

Heavy-metal contamination of soil and groundwater is a widespread problem in industrial nations. Remediation by excavation of such sites may not be cost effective or politically acceptable. Electrokinetic remediation is one possible remediation technique for in situ removal of such contaminants from unsaturated soils. Previous papers discussing the work performed by researchers at Sandia National Laboratories (SNL) and Sat-Unsat, Inc. (SUI) (Lindgren et al., 1991, 1992, 1993) focused on the transport of contaminants and dyes by electrokinetics in unsaturated soils. These experiments were conducted with graphite electrodes with no extraction system. As the contaminants migrated through the soil, they increased in concentration at the electrode creating a diffusion flux in the opposite direction. This paper discusses a technique to remove the contaminants from unsaturated soils once they have reached an electrode.

The vapor pressure and enthalpy of vaporization of M-xylene

International Nuclear Information System (INIS)

Rothenberg, S.J.; Seiler, F.A.; Bechtold, W.E.; Eidson, A.F.

1988-01-01

We measured the vapor pressure of m-xylene over the temperature range 273 to 293 deg K with a single-sided capacitance manometer. The enthalpy of vaporization was 42.2 ± 0.1 (SE) kj/ g·mol. Combining our own data with previously published data, we recommend using the values 42.0, 40.6, and 39.1 (± 0.1) (SE) kjg·mol for the enthalpy of vaporization of m-xylene at 300, 340, and 380 deg. K, respectively, and a value for the change in heat capacity on vaporization (ΔCpdeg.) of 35 ± 3 (SE) J/g·mol·K over the temperature range studied. (author)

Hot water extraction with in situ wet oxidation: Kinetics of PAHs removal from soil

International Nuclear Information System (INIS)

Dadkhah, Ali A.; Akgerman, Aydin

2006-01-01

Finding environmentally friendly and cost-effective methods to remediate soils contaminated with polycyclic aromatic hydrocarbons (PAHs) is currently a major concern of researchers. In this study, a series of small-scale semi-continuous extractions - with and without in situ wet oxidation - were performed on soils polluted with PAHs, using subcritical water (i.e. liquid water at high temperatures and pressures, but below the critical point) as the removal agent. Experiments were performed in a 300 mL reactor using an aged soil sample. To find the desorption isotherms and oxidation reaction rates, semi-continuous experiments with residence times of 1 and 2 h were performed using aged soil at 250 deg. C and hydrogen peroxide as oxidizing agent. In all combined extraction and oxidation flow experiments, PAHs in the remaining soil after the experiments were almost undetectable. In combined extraction and oxidation no PAHs could be detected in the liquid phase after the first 30 min of the experiments. Based on these results, extraction with hot water, if combined with oxidation, should reduce the cost of remediation and can be used as a feasible alternative technique for remediating contaminated soils and sediments

Anti-inflammatory studies of yam (Dioscorea esculenta) extract on ...

African Journals Online (AJOL)

SERVER

2007-08-20

Aug 20, 2007 ... measuring the right hind paw oedema and granuloma tissue ... β-sistosterol, stigmasterol, cardiac glycosides, fat and starch. ... deficiency remedies in various ethno-medicines. ... Preparation and extraction of plant materials.

Development of an integrated in-situ remediation technology. Topical report for task No. 11 entitled: Evaluation of TCE contamination before and after the field experiment, September 26, 1994--May 25, 1996

Energy Technology Data Exchange (ETDEWEB)

Hughes, B.M.; Athmer, C.J.; Sheridan, P.W. [and others

1997-04-01

Contamination in low permeability soils poses a significant technical challenge to in-situ remediation efforts. Poor accessibility to the contaminants and difficulty in delivery of treatment reagents have rendered existing in-situ treatments such as bioremediation, vapor extraction, pump and treat rather ineffective when applied to low permeability soils present at many contaminated sites. The technology is an integrated in-situ treatment in which established geotechnical methods are used to install degradation zones directly in the contaminated soil and electro-osmosis is utilized to move the contaminants back and forth through those zones until the treatment is completed. The present Topical Report for Task No. 11 summarizes the results of TCE analysis in soil and carbon before and after conducting the field experiment. In addition, a discussion of the TCE material balance demonstrates that the Lasagna{trademark} process is effective in moving TCE from the contaminated soil into carbon treatment zones in the field experiment at DOE`s Gaseous Diffusion Plant in Paducah, Kentucky.

Development of an integrated in-situ remediation technology. Topical report for task No. 11 entitled: Evaluation of TCE contamination before and after the field experiment, September 26, 1994--May 25, 1996

International Nuclear Information System (INIS)

Hughes, B.M.; Athmer, C.J.; Sheridan, P.W.

1997-01-01

Contamination in low permeability soils poses a significant technical challenge to in-situ remediation efforts. Poor accessibility to the contaminants and difficulty in delivery of treatment reagents have rendered existing in-situ treatments such as bioremediation, vapor extraction, pump and treat rather ineffective when applied to low permeability soils present at many contaminated sites. The technology is an integrated in-situ treatment in which established geotechnical methods are used to install degradation zones directly in the contaminated soil and electro-osmosis is utilized to move the contaminants back and forth through those zones until the treatment is completed. The present Topical Report for Task No. 11 summarizes the results of TCE analysis in soil and carbon before and after conducting the field experiment. In addition, a discussion of the TCE material balance demonstrates that the Lasagna trademark process is effective in moving TCE from the contaminated soil into carbon treatment zones in the field experiment at DOE's Gaseous Diffusion Plant in Paducah, Kentucky

Development of the integrated in situ Lasagna process

International Nuclear Information System (INIS)

Ho, S.; Athmer, C.; Sheridan, P.

1995-01-01

Contamination in deep, low permeability soils poses a significant technical challenge to in-situ remediation efforts. Poor accessibility to the contaminants and difficulty in uniform delivery of treatment reagents have rendered existing in-situ methods such as bioremediation, vapor extraction, and pump and treat rather ineffective when applied to low permeability soils present at many contaminated sites

Characterization Activities to Determine the Extent of DNAPL in the Vadose Zone at the A-014 Outfall of A/M Area

International Nuclear Information System (INIS)

Jackson, D.G.

2000-01-01

The purpose of this investigation was to perform characterization activities necessary to confirm the presence and extent of DNAPL in the shallow vadose zone near the headwaters of the A-014 Outfall. Following the characterization, additional soil vapor extraction wells and vadose monitoring probes were installed to promote and monitor remediation activities in regions of identified DNAPL

Functional remediation components: A conceptual method of evaluating the effects of remediation on risks to ecological receptors.

Science.gov (United States)

Burger, Joanna; Gochfeld, Michael; Bunn, Amoret; Downs, Janelle; Jeitner, Christian; Pittfield, Taryn; Salisbury, Jennifer

2016-01-01

Governmental agencies, regulators, health professionals, tribal leaders, and the public are faced with understanding and evaluating the effects of cleanup activities on species, populations, and ecosystems. While engineers and managers understand the processes involved in different remediation types such as capping, pump and treat, and natural attenuation, there is often a disconnect between (1) how ecologists view the influence of different types of remediation, (2) how the public perceives them, and (3) how engineers understand them. The overall goal of the present investigation was to define the components of remediation types (= functional remediation). Objectives were to (1) define and describe functional components of remediation, regardless of the remediation type, (2) provide examples of each functional remediation component, and (3) explore potential effects of functional remediation components in the post-cleanup phase that may involve continued monitoring and assessment. Functional remediation components include types, numbers, and intensity of people, trucks, heavy equipment, pipes, and drill holes, among others. Several components may be involved in each remediation type, and each results in ecological effects, ranging from trampling of plants, to spreading invasive species, to disturbing rare species, and to creating fragmented habitats. In some cases remediation may exert a greater effect on ecological receptors than leaving the limited contamination in place. A goal of this conceptualization is to break down functional components of remediation such that managers, regulators, and the public might assess the effects of timing, extent, and duration of different remediation options on ecological systems.

Electrokinetic remediation of copper mine tailings

DEFF Research Database (Denmark)

Hansen, Henrik K.; Rojo, Adrián; Ottosen, Lisbeth M.

2007-01-01

Important process parameters to optimize in electrokinetic soil remediation are those influencing remediation time and power consumption since these directly affect the cost of a remediation action. This work shows how the electrokinetic remediation (EKR) process could be improved by implementing...... bipolar electrodes in the porous material. The bipolar electrodes in EKR meant two improvements: (1) a shorter migration pathway for the contaminant, and (2) an increased electrical conductivity in the remediation system. All together the remediation proceeded faster with lower electrical resistance than...... in similar experiments but without the bipolar electrodes. The new electrokinetic remediation design was tested on copper mine tailings with different applied electric fields, remediation times and pre-treatment. The results showed that the copper removal was increased from 8% (applying 20V for 8 days...

Monitoring of Soil Remediation Process in the Metal Mining Area

Science.gov (United States)

Kim, Kyoung-Woong; Ko, Myoung-Soo; Han, Hyeop-jo; Lee, Sang-Ho; Na, So-Young

2016-04-01

Stabilization using proper additives is an effective soil remediation technique to reduce As mobility in soil. Several researches have reported that Fe-containing materials such as amorphous Fe-oxides, goethite and hematite were effective in As immobilization and therefore acid mine drainage sludge (AMDS) may be potential material for As immobilization. The AMDS is the by-product from electrochemical treatment of acid mine drainage and mainly contains Fe-oxide. The Chungyang area in Korea is located in the vicinity of the huge abandoned Au-Ag Gubong mine which was closed in the 1970s. Large amounts of mine tailings have been remained without proper treatment and the mobilization of mine tailings can be manly occurred during the summer heavy rainfall season. Soil contamination from this mobilization may become an urgent issue because it can cause the contamination of groundwater and crop plants in sequence. In order to reduce the mobilization of the mine tailings, the pilot scale study of in-situ stabilization using AMDS was applied after the batch and column experiments in the lab. For the monitoring of stabilization process, we used to determine the As concentration in crop plants grown on the field site but it is not easily applicable because of time and cost. Therefore, we may need simple monitoring technique to measure the mobility or leachability which can be comparable with As concentration in crop plants. We compared several extraction methods to suggest the representative single extraction method for the monitoring of soil stabilization efficiency. Several selected extraction methods were examined and Mehlich 3 extraction method using the mixture of NH4F, EDTA, NH4NO3, CH3COOH and HNO3 was selected as the best predictor of the leachability or mobility of As in the soil remediation process.

The effect of vadose zone heterogeneities on vapor phase migration and aquifer contamination by volatile organics

Energy Technology Data Exchange (ETDEWEB)

Seneviratne, A.; Findikakis, A.N. [Bechtel Corporation, San Francisco, CA (United States)

1995-03-01

Organic vapors migrating through the vadose zone and inter-phase transfer can contribute to the contamination of larger portions of aquifers than estimated by accounting only for dissolved phase transport through the saturated zone. Proper understanding of vapor phase migration pathways is important for the characterization of the extent of both vadose zone and the saturated zone contamination. The multiphase simulation code T2VOC is used to numerically investigate the effect of heterogeneties on the vapor phase migration of chlorobenzene at a hypothetical site where a vapor extraction system is used to remove contaminants. Different stratigraphies consisting of alternate layers of high and low permeability materials with soil properties representative of gravel, sandy silt and clays are evaluated. The effect of the extent and continuity of low permeability zones on vapor migration is evaluated. Numerical simulations are carried out for different soil properties and different boundary conditions. T2VOC simulations with zones of higher permeability were made to assess the role of how such zones in providing enhanced migration pathways for organic vapors. Similarly, the effect of the degree of saturation of the porous medium on vapor migration was for a range of saturation values. Increased saturation reduces the pore volume of the medium available for vapor diffusion. Stratigraphic units with higher aqueous saturation can retard the vapor phase migration significantly.

Remediating Remediation: From Basic Writing to Writing across the Curriculum

Science.gov (United States)

Faulkner, Melissa

2013-01-01

This article challenges faculty members and administrators to rethink current definitions of remediation. First year college students are increasingly placed into basic writing courses due to a perceived inability to use English grammar correctly, but it must be acknowledged that all students will encounter the need for remediation as they attempt…

The vapor pressure and enthalpy of vaporization of M-xylene

Energy Technology Data Exchange (ETDEWEB)

Rothenberg, S J; Seiler, F A; Bechtold, W E; Eidson, A F

1988-12-01

We measured the vapor pressure of m-xylene over the temperature range 273 to 293 deg K with a single-sided capacitance manometer. The enthalpy of vaporization was 42.2 {+-} 0.1 (SE) kj/ g{center_dot}mol. Combining our own data with previously published data, we recommend using the values 42.0, 40.6, and 39.1 ({+-} 0.1) (SE) kjg{center_dot}mol for the enthalpy of vaporization of m-xylene at 300, 340, and 380 deg. K, respectively, and a value for the change in heat capacity on vaporization ({delta}Cpdeg.) of 35 {+-} 3 (SE) J/g{center_dot}mol{center_dot}K over the temperature range studied. (author)

AND Citrus senensis PEEL EXTRACTS ON Aeromonas hydrophila ...

African Journals Online (AJOL)

DR. AMINU

the two plant extracts against some clinical isolates: six Salmonella paratyphi B, one S. typhi and three A. ... century make the medicines and drugs of vegetables origin lost their ... in preventing heart disease. ... is a remedy for edema.

Phosphorus Amendment Efficacy for In Situ Remediation of Soil Lead Depends on the Bioaccessible Method

Science.gov (United States)

A validated method is needed to measure reductions of in vitro bioaccessible (IVBA) Pb in urban soil remediated with amendments. This study evaluated the effect of in vitro extraction solution pH and glycine buffer on bioaccesible Pb in P-treated soils. Two Pb-contaminated soils...

Combining expedited cleanup with innovative technology demonstrations

International Nuclear Information System (INIS)

Hagood, M.C.; Rohay, V.J.; Valcich, P.J.; Brouns, T.M.; Cameron, R.J.

1993-04-01

A Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) expedited response action (ERA) has been initiated at the Hanford Site, Washington, for the removal of carbon tetrachloride from contaminated soils to mitigate further contamination of the groundwater. Soil vapor extraction with aboveground collection and treatment was chosen as the preferred remedial technology for the first phase of the ERA. At the same time, innovative technology demonstrations are being conducted in coordination with the ERA to determine the viability of emerging technologies that can be used to characterize, remediate, and monitor carbon tetrachloride and cocontaminants. The overall goal is to improve the performance and decrease the costs of carbon tetrachloride remediation while maintaining a safe working environment

Remediation of Cd(II)-contaminated soil via humin-enhanced electrokinetic technology.

Science.gov (United States)

Ding, Ling; Lv, Wenying; Yao, Kun; Li, Liming; Wang, Mengmeng; Liu, Guoguang

2017-02-01

Humin is the component of humic substances that is recalcitrant to extraction by either strong bases or strong acids, which contains a variety of functional groups that may combine with heavy metal ions. The present study employed humin as an adsorbent to investigate the efficacy of a remediation strategy under the effects of humin-enhanced electrokinetics. Because the cations gravitate toward cathode and anions are transferred to anode, humin was placed in close proximity to the cathode in the form of a package. The humin was taken out after the experiments to determine whether a target pollutant (cadmium) might be completely removed from soil. Acetic acid-sodium acetate was selected as the electrolyte for these experiments, which was circulated between the two electrode chambers via a peristaltic pump, in order to control the pH of the soil. The results indicated that when the remediation duration was extended to 240 h, the removal of acid extractable Cd(II) could be up to 43.86% efficiency, and the adsorption of the heavy metal within the humin was 86.15 mg/kg. Further, the recycling of the electrolyte exhibited a good control of the pH of the soil. When comparing the pH of the soil with the circulating electrolyte during remediation, in contrast to when it was not being recycled, the pH of the soil at the anode increased from 3.89 to 5.63, whereas the soil at the cathode decreased from 8.06 to 7.10. This indicated that the electrolyte recycling had the capacity to stabilize the pH of the soil.

Flare pits wastes remediation by low temperature oxidation

International Nuclear Information System (INIS)

Catalan, L. J. L.; Jamaluddin, A. K. M.; Mehta, R.; Moore, R. G.; Okazawa, N.; Ursenbach, M.

1997-01-01

The remediation of contaminated soil in oilfield sites, flare pits in particular, is subject to strict environmental regulations. Most current remediation techniques such as biological or thermal treatment are not particularly effective in highly contaminated sites, or effective only at costs that are considered prohibitive. This contribution describes a cost-effective method for the treatment of contaminated soil in-situ. The proposed treatment involves low temperature oxidation which converts the hydrocarbons in the contaminated soil to inert coke. In laboratory studies contaminated soil was oxidized with air at temperatures between 150 degrees C and 170 degrees C for three weeks. After the three week treatment extractable hydrocarbon levels were reduced to less than 0.1 per cent. Bioassays also demonstrated that toxicity associated with hydrocarbons was eliminated. Salts and metals remaining in the soil after treatment were removed by leaching with water. Low temperature oxidation requires no special equipment; it can occur under conditions and with equipment that are readily available in an oilfield setting. 5 refs., 8 tabs., 7 figs

Remediation plans in family medicine residency

Science.gov (United States)

Audétat, Marie-Claude; Voirol, Christian; Béland, Normand; Fernandez, Nicolas; Sanche, Gilbert

2015-01-01

Abstract Objective To assess use of the remediation instrument that has been implemented in training sites at the University of Montreal in Quebec to support faculty in diagnosing and remediating resident academic difficulties, to examine whether and how this particular remediation instrument improves the remediation process, and to determine its effects on the residents’ subsequent rotation assessments. Design A multimethods approach in which data were collected from different sources: remediation plans developed by faculty, program statistics for the corresponding academic years, and students’ academic records and rotation assessment results. Setting Family medicine residency program at the University of Montreal. Participants Family medicine residents in academic difficulty. Main outcome measures Assessment of the content, process, and quality of remediation plans, and students’ academic and rotation assessment results (successful, below expectations, or failure) both before and after the remediation period. Results The framework that was developed for assessing remediation plans was used to analyze 23 plans produced by 10 teaching sites for 21 residents. All plans documented cognitive problems and implemented numerous remediation measures. Although only 48% of the plans were of good quality, implementation of a remediation plan was positively associated with the resident’s success in rotations following the remediation period. Conclusion The use of remediation plans is well embedded in training sites at the University of Montreal. The residents’ difficulties were mainly cognitive in nature, but this generally related to deficits in clinical reasoning rather than knowledge gaps. The reflection and analysis required to produce a remediation plan helps to correct many academic difficulties and normalize the academic career of most residents in difficulty. Further effort is still needed to improve the quality of plans and to support teachers.

Developing Health-Based Pre-Planning Clearance Goals for Airport Remediation Following a Chemical Terrorist Attack: Decision Criteria for Multipathway Exposure Routes

Science.gov (United States)

Watson, Annetta; Dolislager, Fredrick; Hall, Linda; Raber, Ellen; Hauschild, Veronique D.; Love, Adam H.

2011-01-01

In the event of a chemical terrorist attack on a transportation hub, post-event remediation and restoration activities necessary to attain unrestricted facility re-use and re-entry could require hours to multiple days. While timeframes are dependent on numerous variables, a primary controlling factor is the level of pre-planning and decision-making completed prior to chemical release. What follows is the second of a two-part analysis identifying key considerations, critical information and decision criteria to facilitate post-attack and post-decontamination consequence management activities. Decision criteria analysis presented here provides first-time, open-literature documentation of multi-pathway, health-based remediation exposure guidelines for selected toxic industrial compounds, chemical warfare agents, and agent degradation products for pre-planning application in anticipation of a chemical terrorist attack. Guideline values are provided for inhalation and direct ocular vapor exposure routes as well as percutaneous vapor, surface contact, and ingestion. Target populations include various employees as well as transit passengers. This work has been performed as a national case study conducted in partnership with the Los Angeles International Airport and The Bradley International Terminal. All recommended guidelines have been selected for consistency with airport scenario release parameters of a one-time, short-duration, finite airborne release from a single source followed by compound-specific decontamination. PMID:21399674

New IAEA guidelines on environmental remediation

Energy Technology Data Exchange (ETDEWEB)

Fesenko, Sergey [International Atomic Energy Agency, A2444, Seibersdorf (Austria); Howard, Brenda [Centre for Ecology and Hydrology, Lancaster Environment Centre, LA1 4AP, Lancaster (United Kingdom); Kashparov, Valery [Ukrainian Institute of Agricultural Radiology, 08162, 7, Mashinobudivnykiv str., Chabany, Kyivo-Svyatoshin region, Kyiv (Ukraine); Sanzharova, Natalie [Russian Institute of Agricultural Radiology and Agroecology, Russian Federation, 249032, Obninsk (Russian Federation); Vidal, Miquel [Analytical Chemistry Department-Universitat de Barcelona, Barcelona, 08028 Barcelona (Spain)

2014-07-01

In response to the needs of its Member States, the International Atomic Energy Agency (IAEA) has published many documents covering different aspects of remediation of contaminated environments. These documents range from safety fundamentals and safety requirements to technical documents describing remedial technologies. Almost all the documents on environmental remediation are related to uranium mining areas and decommissioning of nuclear facilities. IAEA radiation safety standards on remediation of contaminated environments are largely based on these two types of remediation. The exception is a document related to accidents, namely the IAEA TRS No. 363 'Guidelines for Agricultural Countermeasures Following an Accidental Release of Radionuclides'. Since the publication of TRS 363, there has been a considerable increase in relevant information. In response, the IAEA initiated the development of a new document, which incorporated new knowledge obtained during last 20 years, lessons learned and subsequent changes in the regulatory framework. The new document covers all aspects related to the environmental remediation from site characterisation to a description of individual remedial actions and decision making frameworks, covering urban, agricultural, forest and freshwater environments. Decisions taken to commence remediation need to be based on an accurate assessment of the amount and extent of contamination in relevant environmental compartments and how they vary with time. Major aspects of site characterisation intended for remediation are described together with recommendations on effective sampling programmes and data compilation for decision making. Approaches for evaluation of remedial actions are given in the document alongside the factors and processes which affect their implementation for different environments. Lessons learned following severe radiation accidents indicate that remediation should be considered with respect to many different

Some Similarities and Differences Between Compositions Written by Remedial and Non-Remedial College Freshmen.

Science.gov (United States)

House, Elizabeth B.; House, William J.

The essays composed by 84 remedial and 77 nonremedial college freshmen were analyzed for some features proposed by Mina Shaughnessy as being characteristic of basic writers. The students were enrolled in either a beginning remedial class (098), a class at the next level of remediation (099), or a regular English class (101). The essays were…

Enthalpy of vaporization and vapor pressure of whiskey lactone and menthalactone by correlation gas chromatography

International Nuclear Information System (INIS)

Simmons, Daniel; Chickos, James

2017-01-01

Highlights: • The vapor pressure and vaporization enthalpies of cis and trans-whiskey lactone have been evaluated. • Enthalpies of vaporization and vapor pressures of (+)-isomintlactone and (−)-mintlactone were also evaluated. • The sublimation enthalpy and corresponding vapor pressure of (+) -isomintlactone at T = 298.15 K is estimated. - Abstract: Enthalpies of vaporization at T = 298.15 K of cis and trans-whiskey lactone have been evaluated by correlation gas chromatography to be (68.4 ± 1.7) kJ·mol −1 and (67.5 ± 1.7) kJ·mol −1 , respectively. The enthalpies of vaporization of isomintlactone and mintlactone also evaluated by correlation gas chromatography have been found to have vaporization enthalpies of (74.2 ± 1.8) kJ·mol −1 and (73.2 ± 1.8) kJ·mol −1 respectively. The vapor pressures for cis and trans-whiskey lactone at T = 298.15 K have been evaluated as (1.5 ± 0.09) Pa and (2.0 ± 0.1) Pa using vapor pressures of a series of lactones as standards. Vapor pressures for isomintlactone and mintlactone were evaluated as (0.26 ± 0.012) Pa and (0.33 ± 0.02) Pa, respectively. Fusion and sublimation enthalpies for (+)-isomintlactone as well as the vapor pressure of the solid have been estimated.

Object reasoning for waste remediation

International Nuclear Information System (INIS)

Pennock, K.A.; Bohn, S.J.; Franklin, A.L.

1991-08-01

A large number of contaminated waste sites across the United States await size remediation efforts. These sites can be physically complex, composed of multiple, possibly interacting, contaminants distributed throughout one or more media. The Remedial Action Assessment System (RAAS) is being designed and developed to support decisions concerning the selection of remediation alternatives. The goal of this system is to broaden the consideration of remediation alternatives, while reducing the time and cost of making these considerations. The Remedial Action Assessment System is a hybrid system, designed and constructed using object-oriented, knowledge- based systems, and structured programming techniques. RAAS uses a combination of quantitative and qualitative reasoning to consider and suggest remediation alternatives. The reasoning process that drives this application is centered around an object-oriented organization of remediation technology information. This paper describes the information structure and organization used to support this reasoning process. In addition, the paper describes the level of detail of the technology related information used in RAAS, discusses required assumptions and procedural implications of these assumptions, and provides rationale for structuring RAAS in this manner. 3 refs., 3 figs

Remediation of uranium contaminated soils with bicarbonate extraction and microbial U(VI) reduction

Science.gov (United States)

Philips , Elizabeth J.P.; Landa, Edward R.; Lovely, Derek R.

1995-01-01

A process for concentrating uranium from contaminated soils in which the uranium is first extracted with bicarbonate and then the extracted uranium is precipitated with U(VI)-reducing microorganisms was evaluated for a variety of uranuum-contaminated soils. Bicarbonate (100 mM) extracted 20–94% of the uranium that was extracted with nitric acid. The U(VI)-reducing microorganism,Desulfovibrio desulfuricans reduced the U(VI) to U(IV) in the bicarbonate extracts. In some instances unidentified dissolved extracted components, presumably organics, gave the extract a yellow color and inhibited U(VI) reduction and/or the precipitation of U(IV). Removal of the dissolved yellow material with the addition of hydrogen peroxide alleviated this inhibition. These results demonstrate that bicarbonate extraction of uranium from soil followed by microbial U(VI) reduction might be an effective mechanism for concentrating uranium from some contaminated soils.

Remediation of uranium contaminated soils with bicarbonate extraction and microbial U(VI) reduction

International Nuclear Information System (INIS)

Phillips, E.J.P.; Landa, E.R.; Lovley, D.R.

1995-01-01

A process for concentrating uranium from contaminated soils in which the uranium is first extracted with bicarbonate and then the extracted uranium is precipitated with U(VI)-reducing microorganisms was evaluated for a variety of uranium-contaminated soils. Bicarbonate (100 mM) extracted 20-94% of the uranium that was extracted with nitric acid. The U(VI)-reducing microorganism, Desulfovibrio desulfuricans reduced the U(VI) to U(IV) in the bicarbonate extracts. In some instances unidentified dissolved extracted components, presumably organics, gave the extract a yellow color and inhibited U(VI) reduction and/or the precipitation of U(IV). Removal of the dissolved yellow material with the addition of hydrogen peroxide alleviated this inhibition. These results demonstrate that bicarbonate extraction of uranium from soil followed by microbial U(VI) reduction might be an effective mechanism for concentrating uranium from some contaminated soils. (author)

Proceedings of the remediation technologies symposium 2008

Energy Technology Data Exchange (ETDEWEB)

NONE

2008-07-01

This conference reviewed the latest innovations regarding the remediation of hydrocarbon contaminated soil and groundwater, with considerable information dedicated to the field of industrial pollutant treatments. Some topics and case studies covered in the presentations included both in-situ treatment and ex-situ treatment methods; biological and non-biological treatment methods; thermal desorption; multi-phase extraction; detoxification; environmental management; hydrocarbon contamination stabilization; and unique and challenging locations. The conference featured 3 workshops addressing innovative solutions for federal contaminated sites; technology funding options; and use of chemistry in land reclamation. The technical sessions were entitled: bioremediation; military sites and gun ranges; an update on technology from the Netherlands; Sydney tar ponds update and the Federation of Canadian Municipalities (FCM) green municipal fund; in-situ treatment methods; phytoremediation and natural attenuation; solidification/stabilization; vapour management; extraction; unique situations; Alberta Environment updates; framework and tools; and investigations. The conference featured 68 presentations, of which 16 have been catalogued separately for inclusion in this database. tabs., figs.

SEQUESTERING AGENTS FOR ACTIVE CAPS - REMEDIATION OF METALS AND ORGANICS

Energy Technology Data Exchange (ETDEWEB)

Knox, A; Michael Paller, M; Danny D. Reible, D; Xingmao Ma, X; Ioana G. Petrisor, I

2007-05-10

This research evaluated organoclays, zeolites, phosphates, and a biopolymer as sequestering agents for inorganic and organic contaminants. Batch experiments were conducted to identify amendments and mixtures of amendments for metal and organic contaminants removal and retention. Contaminant removal was evaluated by calculating partitioning coefficients. Metal retention was evaluated by desorption studies in which residue from the removal studies was extracted with 1 M MgCl{sub 2} solution. The results indicated that phosphate amendments, some organoclays, and the biopolymer, chitosan, were very effective sequestering agents for metals in fresh and salt water. Organoclays were very effective sorbents for phenanthrene, pyrene, and benzo(a)pyrene. Partitioning coefficients for the organoclays were 3000-3500 ml g{sup -1} for benzo(a)pyrene, 400-450 ml g{sup -1} for pyrene, and 50-70 ml g{sup -1} for phenanthrene. Remediation of sites with a mixture of contaminants is more difficult than sites with a single contaminant because metals and organic contaminants have different fate and transport mechanisms in sediment and water. Mixtures of amendments (e.g., organoclay and rock phosphate) have high potential for remediating both organic and inorganic contaminants under a broad range of environmental conditions, and have promise as components in active caps for sediment remediation.

Development of a sitewide groundwater remediation strategy at the Hanford Site, Washington

International Nuclear Information System (INIS)

Goswami, D.

1996-01-01

Over 440 km 2 (170 mi 2 ) of groundwater beneath the Hanford Site are contaminated by hazardous and radioactive waste, out of which almost half is over state and federal drinking water standards. In addition to the complicated nature of these plumes, remediation is further obscured by limited application of available technologies and hydrogeologic information. This paper briefly describes the processes used by the Washington State Department of Ecology (Ecology), U.S. Environmental Protection Agency, and U.S. Department of Energy (USDOE) in developing a sitewide groundwater remediation strategy for Hanford and its outcome. As an initial approach to sitewide groundwater remediation, the strategy is to remediate the major plumes found in the reactor areas (100 Area) adjacent to the Columbia River and contain the major plumes found in the Central Plateau region (200 Area). This approach was based mainly on the qualitative risk, stakeholder's and tribe's values, and available technical feasibility. The strategy emphasizes the use of existing treatment and extraction technology for the remediation of groundwater in combination with proposed and existing site infrastructure. This work is being performed in parallel with ongoing risk and other feasibility activities. Under this strategy, innovative technologies being developed are in the areas of dense nonaqueous phase liquid identification and recovery, and problems associated with strontium-90, cesium-137, and plutonium in the vadose zone and groundwater. The final remediation strategy alternatives remain a product of risk assessment, technical feasibility, site use scenario, and cost consideration. In order to develop a strategy for the final cleanup, several issues such as aquifer restoration, natural attenuation, potential contamination of groundwater from the tank farms and from the existing contamination source in the vadose zone must be looked in detail in conjuction with public and stakeholder's values

Remediation of the closed-down uranium mine in Sweden

International Nuclear Information System (INIS)

Linder, P.; Sundblad, B.

1993-01-01

During the 1960s uranium was extracted from alum shale deposits at Ranstad in the south of Sweden. This mine was part of the development of a Swedish nuclear power program based on the heavy-water/natural uranium concept. In this report the history of Swedish uranium production is briefly presented as well as the reason for the closing-down of the mine at Ranstad. In 1985 the planning of the restoration of the area started. The aim of the remediation work was to find a permanent solution that excluded the need for any maintenance in the future. The procedures and techniques for remedial action are described for the open pit mine and the mill tailing deposits. As the leachate from the mill tailings was collected and purified, there was no urgent need for action. Investigations could be made to find an effective way for reducing the weathering of the pyrite in the tailings and the authorities concerned could accept the remediation plan after a detailed review. The main part of the plan has now been implemented and many experiences from the performance technique and the significant quality assurance program have been obtained. The old open pit mine has already been transformed into a lake and the mill tailings are covered by a leaktight barrier and a protective layer. The natural environment in the whole area has been reestablished

MEMBRANE SYSTEM FOR RECOVERY OF VOLATILE ORGANIC COMPOUNDS FROM REMEDIATION OFF-GASES

International Nuclear Information System (INIS)

Wijmans, J.G.

2003-01-01

In situ vacuum extraction, air or steam sparging, and vitrification are widely used to remediate soil contaminated with volatile organic compounds (VOCs). All of these processes produce a VOC-laden air stream from which the VOC must be removed before the air can be discharged or recycled to the generating process. Treatment of these off-gases is often a major portion of the cost of the remediation project. Currently, carbon adsorption and catalytic incineration are the most common methods of treating these gas streams. Membrane Technology and Research, Inc. (MTR) proposed an alternative treatment technology based on selective membranes that separate the organic components from the gas stream, producing a VOC-free air stream. This technology can be applied to off-gases produced by various remediation activities and the systems can be skid-mounted and automated for easy transportation and unattended operation. The target performance for the membrane systems is to produce clean air (less than 10 ppmv VOC) for discharge or recycle, dischargeable water (less than 1 ppmw VOC), and a concentrated liquid VOC phase. This report contains the results obtained during Phase II of a two-phase project. In Phase I, laboratory experiments were carried out to demonstrate the feasibility of the proposed approach. In the subsequent Phase II project, a demonstration system was built and operated at the McClellan Air Force Base near Sacramento, California. The membrane system was fed with off-gas from a Soil Vacuum Extraction (SVE) system. The work performed in Phase II demonstrated that the membrane system can reduce the VOC concentration in remediation off-gas to 10 ppmv, while producing a concentrated VOC phase and dischargeable water containing less than 1 ppmw VOC. However, the tests showed that the presence of 1 to 3% carbon dioxide in the SVE off-gas reduced the treatment capacity of the system by a factor of three to four. In an economic analysis, treatment costs of the membrane

Development of an Airborne Micropulse Water Vapor DIAL

Science.gov (United States)

Nehrir, A. R.; Ismail, S.

2012-12-01

based instrument is achievable via overdriven current pulses to the TSOA gain medium while maintaining a 1μs and 10 kHz pulse width and PRF, respectively. The increase in the laser transmitter pulse energy will allow for nighttime and daytime water vapor profile retrievals from an airborne platform operating at an 8 km altitude with 2-5 minute integration periods. Results from a numerical model demonstrating the performance of an airborne DIAL system with the mentioned transmitter enhancements will be presented and compared against the existing ground based instrument performance. Furthermore, results from laboratory experiments demonstrating the laser transmitter performance including maximum extractable energy, energy stability, and spectral purity will also be presented.

Experiences of marijuana-vaporizer users.

Science.gov (United States)

Malouff, John M; Rooke, Sally E; Copeland, Jan

2014-01-01

Using a marijuana vaporizer may have potential harm-reduction advantages on smoking marijuana, in that the user does not inhale smoke. Little research has been published on use of vaporizers. In the first study of individuals using a vaporizer on their own initiative, 96 adults anonymously answered questions about their experiences with a vaporizer and their use of marijuana with tobacco. Users identified 4 advantages to using a vaporizer over smoking marijuana: perceived health benefits, better taste, no smoke smell, and more effect from the same amount of marijuana. Users identified 2 disadvantages: inconvenience of setup and cleaning and the time it takes to get the device operating for each use. Only 2 individuals combined tobacco in the vaporizer mix, whereas 15 combined tobacco with marijuana when they smoked marijuana. Almost all participants intended to continue using a vaporizer. Vaporizers seem to have appeal to marijuana users, who perceive them as having harm-reduction and other benefits. Vaporizers are worthy of experimental research evaluating health-related effects of using them.

Organic sponges for cost-effective CVOC abatement. Final report, September 1992--April 1994

International Nuclear Information System (INIS)

Flanagan, W.P.; Grade, M.M.; Horney, D.P.; Mackenzie, P.D.; Salvo, J.J.; Sivavec, T.M.; Stephens, M.L.

1994-07-01

Air contaminated with CVOCs (chlorinated volatile organic compounds) arise from air stripping of ground water or from soil and dual phase vapor extraction. A research program was undertaken to develop sorbents better than activated carbon for remediation. Two such sorbents were found: Dow's XUS polymer and Rohm and Haas' Ambersorb 563 (carbonaceous). Opportunities exist to further develop sorption and biodegradation technologies

Organic sponges for cost-effective CVOC abatement. Final report, September 1992--April 1994

Energy Technology Data Exchange (ETDEWEB)

Flanagan, W.P.; Grade, M.M.; Horney, D.P.; Mackenzie, P.D.; Salvo, J.J.; Sivavec, T.M.; Stephens, M.L.

1994-07-01

Air contaminated with CVOCs (chlorinated volatile organic compounds) arise from air stripping of ground water or from soil and dual phase vapor extraction. A research program was undertaken to develop sorbents better than activated carbon for remediation. Two such sorbents were found: Dow`s XUS polymer and Rohm and Haas` Ambersorb 563 (carbonaceous). Opportunities exist to further develop sorption and biodegradation technologies.

Air-Based Remediation Workshop - Section 8 Air-Based Remediation Technology Selection Logic

Science.gov (United States)

Pursuant to the EPA-AIT Implementing Arrangement 7 for Technical Environmental Collaboration, Activity 11 "Remediation of Contaminated Sites," the USEPA Office of International Affairs Organized a Forced Air Remediation Workshop in Taipei to deliver expert training to the Environ...

Reduction of metal exposure of Daubenton's bats (Myotis daubentonii) following remediation of pond sediment as evidenced by metal concentrations in hair.

Science.gov (United States)

Flache, Lucie; Ekschmitt, Klemens; Kierdorf, Uwe; Czarnecki, Sezin; Düring, Rolf-Alexander; Encarnação, Jorge A

2016-03-15

Transfer of contaminants from freshwater sediments via aquatic insects to terrestrial predators is well documented in spiders and birds. Here, we analyzed the metal exposure of Myotis daubentonii using an urban pond as their preferred foraging area before and after a remediation measure (sediment dredging) at this pond. Six metal elements (Zn, Cu, Cr, Cd, Pb and Ni) were measured in the sediment of the pond, in EDTA extracts of the sediment and in hair samples of M. daubentonii foraging at the pond. Samples were taken before remediation in 2011 and after remediation in 2013. Metal concentrations were quantified by ICP-OES after miniaturized microwave assisted extraction. In 2011, the pond sediment exhibited a high contamination with nickel, a moderate contamination with copper and chromium and low contents of zinc, cadmium and lead. While sediment metal contents declined only weakly after remediation, a much more pronounced reduction in the concentrations of zinc, copper, chromium and lead concentrations was observed in bat hair. Our results suggest a marked decline in metal exposure of the bats foraging at the pond as a consequence of the remediation measure. It is concluded that Daubenton's bats are suitable bioindicators of metal contamination in aquatic environments, integrating metal exposure via prey insects over their entire foraging area. We further suggest that bat hair is a useful monitoring unit, allowing a non-destructive and non-invasive assessment of metal exposure in bats. Copyright © 2015 Elsevier B.V. All rights reserved.

200-UP-1 groundwater remedial design/remedial action work plan. Revision 1

International Nuclear Information System (INIS)

1997-07-01

This 200-UP-1 remedial design report presents the objective and rationale developed for the design and implementation of the selected interim remedial measure for the 200-UP-1 Operable Unit, located in the 200 West Area of the Hanford Site

Genealogy Remediated

DEFF Research Database (Denmark)

Marselis, Randi

2007-01-01

Genealogical websites are becoming an increasingly popular genre on the Web. This chapter will examine how remediation is used creatively in the construction of family history. While remediation of different kinds of old memory materials is essential in genealogy, digital technology opens new...... possibilities. Genealogists use their private websites to negotiate family identity and hereby create a sense of belonging in an increasingly complex society. Digital technologies enhance the possibilities of coorporation between genealogists. Therefore, the websites are also used to present archival...

Reduction of metal exposure of Daubenton's bats (Myotis daubentonii) following remediation of pond sediment as evidenced by metal concentrations in hair

International Nuclear Information System (INIS)

Flache, Lucie; Ekschmitt, Klemens; Kierdorf, Uwe; Czarnecki, Sezin; Düring, Rolf-Alexander; Encarnação, Jorge A.

2016-01-01

Transfer of contaminants from freshwater sediments via aquatic insects to terrestrial predators is well documented in spiders and birds. Here, we analyzed the metal exposure of Myotis daubentonii using an urban pond as their preferred foraging area before and after a remediation measure (sediment dredging) at this pond. Six metal elements (Zn, Cu, Cr, Cd, Pb and Ni) were measured in the sediment of the pond, in EDTA extracts of the sediment and in hair samples of M. daubentonii foraging at the pond. Samples were taken before remediation in 2011 and after remediation in 2013. Metal concentrations were quantified by ICP-OES after miniaturized microwave assisted extraction. In 2011, the pond sediment exhibited a high contamination with nickel, a moderate contamination with copper and chromium and low contents of zinc, cadmium and lead. While sediment metal contents declined only weakly after remediation, a much more pronounced reduction in the concentrations of zinc, copper, chromium and lead concentrations was observed in bat hair. Our results suggest a marked decline in metal exposure of the bats foraging at the pond as a consequence of the remediation measure. It is concluded that Daubenton's bats are suitable bioindicators of metal contamination in aquatic environments, integrating metal exposure via prey insects over their entire foraging area. We further suggest that bat hair is a useful monitoring unit, allowing a non-destructive and non-invasive assessment of metal exposure in bats. - Highlights: • Changes in metal exposure of bats due to remediation measure are documented. • Bats are suitable bioindicators of metal pollution. • Bat hair is a useful monitoring unit in such studies.

Cavitational hydrothermal oxidation: A new remediation process. 1998 annual progress report

International Nuclear Information System (INIS)

Suslick, K.S.

1998-01-01

'The primary goal is to develop a quantitative understanding of cavitation phenomena in aqueous media and the development of applications of cavitation to remediation processes. Efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions. This report summarizes work after one year of a three year project. In order to gain further understanding of the conditions present during cavitation, the author has continued his studies of sonoluminescence. He has made recent breakthroughs in the use of emission spectroscopy for temperature and pressure measurement of cavitation events, which he expects to publish shortly. He has been able to measure for the first time the temperature of cavitation in water during multi-bubble cavitation in the presence of aromatic hydrocarbons. The emission from excited states of C 2 in water gives temperatures that are consistent with adiabatic compressional heating, with maximum temperatures of 4,300 K. Prior measurements of cavitation temperatures in low vapor pressure nonaqueous media gave somewhat higher temperatures of 5,000 K. This work lays permanently to rest exotic mechanisms for cavitational chemistry, at least for cavitation fields.'

Cavitational hydrothermal oxidation: A new remediation process. 1998 annual progress report

Energy Technology Data Exchange (ETDEWEB)

Suslick, K.S.

1998-06-01

'The primary goal is to develop a quantitative understanding of cavitation phenomena in aqueous media and the development of applications of cavitation to remediation processes. Efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions. This report summarizes work after one year of a three year project. In order to gain further understanding of the conditions present during cavitation, the author has continued his studies of sonoluminescence. He has made recent breakthroughs in the use of emission spectroscopy for temperature and pressure measurement of cavitation events, which he expects to publish shortly. He has been able to measure for the first time the temperature of cavitation in water during multi-bubble cavitation in the presence of aromatic hydrocarbons. The emission from excited states of C{sub 2} in water gives temperatures that are consistent with adiabatic compressional heating, with maximum temperatures of 4,300 K. Prior measurements of cavitation temperatures in low vapor pressure nonaqueous media gave somewhat higher temperatures of 5,000 K. This work lays permanently to rest exotic mechanisms for cavitational chemistry, at least for cavitation fields.'

bryophyte extracts with activity against plant pathogenic fungi

African Journals Online (AJOL)

Preferred Customer

ABSTRACT: The effects of extracts from 17 different bryophyte species were investigated against economically important plant pathogenic fungi ... remedies of diseases in various forms. Similarly, before the discovery of the synthetic ... and divided into the classes Anthocerotae (horn- worts), Hepaticae (liverworts) and Musci ...

Development of tensiometric barriers for containment and remediation at waste sites

International Nuclear Information System (INIS)

Thomson, B.M.; Stormont, J.C.; Morris, C.E.

1996-01-01

This report describes a concept in which dry air is injected into an unsaturated formation to reduce the soil moisture content, referred to here as a tensiometric (or sometimes dry) barrier. The objective is to reduce the hydraulic conductivity of the unsaturated media to the point where liquid phase transport becomes negligible, thereby achieving containment. The concept could be applied in subsurface formations to provide containment from a leaking facility, or it could be incorporated into a cover design to provide redundancy for a capillary barrier. The air injection process could in principle be coupled with a vacuum extraction system to recover soil vapors, which would then provide a remediation process that would be appropriate if volatile organic compounds were present. Work to date has consisted of a combined theoretical, laboratory, and field research investigation. The objective of this research was to demonstrate the technical feasibility of the tensiometric barrier concept by identifying the parameters which determine its effectiveness. Based on the results obtained for the experimental and theoretical studies, feasibility analyses were prepared as a modification for a landfill cover design to prevent infiltration from atmospheric precipitation and for potential application of tensiometric barriers to achieve subsurface containment of mobile pollutants and removal of volatile constituents. These analyses considered the technical as well as the economic aspects of the tensiometric barrier concept, and found that a properly designed and operated tensiometric barrier is competitive with conventional containment methods. In addition, they benefit from being able to recover from failure by circulating additional dry air through the formation to re-establish the barrier phenomena. (author) 10 figs., 4 tabs., 17 refs

A new humic acid remedy with addition of silver nanoparticles

OpenAIRE

GP Alexandrova; G Dolmaa; E Enkhbadral; GL Grishenko; Sh Tserenpil; BG Sukhov; D Regdel; BA Trofimov

2014-01-01

Previously known biogenic stimulator humic acid (HA) was the subject of this current study and HA based new remediation was developed by addition of silver (Ag) nanoparticles in its macromolecule. Extracted HA from a healing mud was characterized and used as reducing agent for Ag ion as well as a stabilizer for the formed Ag nanoparticles. The properties of the obtained hybrid composite were examined by XRD, UV and FTIR spectroscopic techniques. The diameter of the nanoparticles in the HA pol...

Mold: Cleanup and Remediation

Science.gov (United States)

... National Center for Environmental Health (NCEH) Cleanup and Remediation Recommend on Facebook Tweet Share Compartir On This ... CDC and EPA on mold cleanup, removal and remediation. Cleanup information for you and your family Homeowner’s ...

Final Site-Specific Technical Report for the Evaluation of Thermatrix GS Series Flameless Thermal Oxidzer for Off-Gas Treatment of Trichloroethene Vapors at Building 181 Air Force Plant 4, Texas

National Research Council Canada - National Science Library

Archabal, Steven

1998-01-01

The Air Force Center for Environmental Excellence (AFCEE) has sponsored an ongoing program to promote the use of cost-effective soil vapor treatment technologies in conjunction with soil vapor extraction (SVE...

Strategy paper. Remedial design/remedial action 100 Area. Revision 1

International Nuclear Information System (INIS)

Donahoe, R.L.

1995-07-01

The purpose of this planning document is to identify and define the approach for remedial design and remedial action (RD/RA) in the 100 Area of the Hanford Site, located in southeastern Washington State. Additionally, this document will support the Hanford Site Environmental Restoration Contract (ERC) team, the US Department of Energy (DOE), and regulatory agencies in identifying and agreeing upon the complete process for expedited cleanup of the 100 Area

Waste Tank Vapor Project: Tank vapor database development

International Nuclear Information System (INIS)

Seesing, P.R.; Birn, M.B.; Manke, K.L.

1994-09-01

The objective of the Tank Vapor Database (TVD) Development task in FY 1994 was to create a database to store, retrieve, and analyze data collected from the vapor phase of Hanford waste tanks. The data needed to be accessible over the Hanford Local Area Network to users at both Westinghouse Hanford Company (WHC) and Pacific Northwest Laboratory (PNL). The data were restricted to results published in cleared reports from the laboratories analyzing vapor samples. Emphasis was placed on ease of access and flexibility of data formatting and reporting mechanisms. Because of time and budget constraints, a Rapid Application Development strategy was adopted by the database development team. An extensive data modeling exercise was conducted to determine the scope of information contained in the database. a A SUN Sparcstation 1000 was procured as the database file server. A multi-user relational database management system, Sybase reg-sign, was chosen to provide the basic data storage and retrieval capabilities. Two packages were chosen for the user interface to the database: DataPrism reg-sign and Business Objects trademark. A prototype database was constructed to provide the Waste Tank Vapor Project's Toxicology task with summarized and detailed information presented at Vapor Conference 4 by WHC, PNL, Oak Ridge National Laboratory, and Oregon Graduate Institute. The prototype was used to develop a list of reported compounds, and the range of values for compounds reported by the analytical laboratories using different sample containers and analysis methodologies. The prototype allowed a panel of toxicology experts to identify carcinogens and compounds whose concentrations were within the reach of regulatory limits. The database and user documentation was made available for general access in September 1994

The vapor pressures of explosives

Energy Technology Data Exchange (ETDEWEB)

Ewing, Robert G.; Waltman, Melanie J.; Atkinson, David A.; Grate, Jay W.; Hotchkiss, Peter

2013-01-05

The vapor pressures of many explosive compounds are extremely low and thus determining accurate values proves difficult. Many researchers, using a variety of methods, have measured and reported the vapor pressures of explosives compounds at single temperatures, or as a function of temperature using vapor pressure equations. There are large variations in reported vapor pressures for many of these compounds, and some errors exist within individual papers. This article provides a review of explosive vapor pressures and describes the methods used to determine them. We have compiled primary vapor pressure relationships traceable to the original citations and include the temperature ranges for which they have been determined. Corrected values are reported as needed and described in the text. In addition, after critically examining the available data, we calculate and tabulate vapor pressures at 25 °C.

Electrodialytic Remediation of Copper Mine Tailings

DEFF Research Database (Denmark)

Hansen, H.K.; Rojo, A.; Ottosen, L.M.

2012-01-01

This work compares and evaluates sixteen electrodialytic laboratory remediation experiments on copper mine tailings. Different parameters were analysed, such as remediation time, addition of desorbing agents, and the use of pulsed electrical fields.......This work compares and evaluates sixteen electrodialytic laboratory remediation experiments on copper mine tailings. Different parameters were analysed, such as remediation time, addition of desorbing agents, and the use of pulsed electrical fields....

MGP site remediation: Working toward presumptive remedies

International Nuclear Information System (INIS)

Larsen, B.R.

1996-01-01

Manufactured Gas Plants (MGPs) were prevalent in the United States during the 19th and first half of the 20th centuries. MGPs produced large quantities of waste by-products, which varied depending on the process used to manufacture the gas, but most commonly were tars and polynuclear aromatic hydrocarbons. There are an estimated 3,000 to 5,000 abandoned MGP sites across the United States. Because these sites are not concentrated in one geographic location and at least three different manufacturing processes were used, the waste characteristics are very heterogeneous. The question of site remediation becomes how to implement a cost-effective remediation with the variety of cleanup technologies available for these sites. Because of the significant expenditure required for characterization and cleanup of MGP sites, owners and regulatory agencies are beginning to look at standardizing cleanup technologies for these sites. This paper discusses applicable cleanup technologies and the attitude of state regulatory agencies towards the use of presumptive remedies, which can reduce the amount of characterization and detailed analysis necessary for any particular site. Additionally, this paper outlines the process of screening and evaluating candidate technologies, and the progress being made to match the technology to the site

Site remediation: The naked truth

International Nuclear Information System (INIS)

Calloway, J.M.

1991-01-01

The objective of any company faced with an environmental site remediation project is to perform the cleanup effectively at the lowest possible cost. Today, there are a variety of techniques being applied in the remediation of sites involving soils and sludges. The most popular include: stabilization, incineration, bioremediation and off-site treatment. Dewatering may also play an integral role in a number of these approaches. Selecting the most cost-effective technique for remediation of soils and sludges can be a formidable undertaking, namely because it is often difficult to quantify certain expenses in advance of the project. In addition to providing general cost guidelines for various aspects of soil and sludge remediation, this paper will show how some significant cost factors can be affected by conditions related to specific remediation projects and the cleanup technology being applied

Remediation using trace element humate surfactant

Energy Technology Data Exchange (ETDEWEB)

Riddle, Catherine Lynn; Taylor, Steven Cheney; Bruhn, Debra Fox

2016-08-30

A method of remediation at a remediation site having one or more undesirable conditions in which one or more soil characteristics, preferably soil pH and/or elemental concentrations, are measured at a remediation site. A trace element humate surfactant composition is prepared comprising a humate solution, element solution and at least one surfactant. The prepared trace element humate surfactant composition is then dispensed onto the remediation site whereby the trace element humate surfactant composition will reduce the amount of undesirable compounds by promoting growth of native species activity. By promoting native species activity, remediation occurs quickly and environmental impact is minimal.

Remedial action and waste disposal project: 100-B/C remedial action readiness evaluation plan

International Nuclear Information System (INIS)

April, J.G.; Bryant, D.L.; Cislo, G.B.

1996-06-01

The Readiness Evaluation Plan presents the methodology used to assess the readiness of the 100-B/C Remedial Action Project. The 100 Areas Remedial Action Project will remediate the 100 Areas liquid waste site identified in the Interim Action Record of Decision for the 100- BC-1, 100-DR-1, and 100-HR-1 Operable Units. These sites are located in the 100 Area of the Hanford Site in Richland, Washington

Fabrication and evaluation of chemically vapor deposited tungsten heat pipe.

Science.gov (United States)

Bacigalupi, R. J.

1972-01-01

A network of lithium-filled tungsten heat pipes is being considered as a method of heat extraction from high temperature nuclear reactors. The need for material purity and shape versatility in these applications dictates the use of chemically vapor deposited (CVD) tungsten. Adaptability of CVD tungsten to complex heat pipe designs is shown. Deposition and welding techniques are described. Operation of two lithium-filled CVD tungsten heat pipes above 1800 K is discussed.

Thermal soil remediation

International Nuclear Information System (INIS)

Nelson, D.

1999-01-01

The environmental properties and business aspects of thermal soil remediation are described. Thermal soil remediation is considered as being the best option in cleaning contaminated soil for reuse. The thermal desorption process can remove hydrocarbons such as gasoline, kerosene and crude oil, from contaminated soil. Nelson Environmental Remediation (NER) Ltd. uses a mobile thermal desorption unit (TDU) with high temperature capabilities. NER has successfully applied the technology to target heavy end hydrocarbon removal from Alberta's gumbo clay in all seasons. The TDU consist of a feed system, a counter flow rotary drum kiln, a baghouse particulate removal system, and a secondary combustion chamber known as an afterburner. The technology has proven to be cost effective and more efficient than bioremediation and landfarming

Alkanna tinctoria leaves extracts: a prospective remedy against multidrug resistant human pathogenic bacteria.

Science.gov (United States)

Khan, Usman Ali; Rahman, Hazir; Qasim, Muhammad; Hussain, Anwar; Azizllah, Azizullah; Murad, Waheed; Khan, Zakir; Anees, Muhammad; Adnan, Muhammad

2015-04-23

Plants are rich source of chemical compounds that are used to accomplish biological activity. Indigenously crude extracts of plants are widely used as herbal medicine for the treatment of infections by people of different ethnic groups. The present investigation was carried out to evaluate the biological potential of Alkanna tinctoria leaves extract from district Charsadda, Pakistan against multidrug resistant human pathogenic bacteria including Acinetobacter baumannii, Escherichia coli, Pseudomonas aeruginosa and Staphylococcus aureus. Anti-multi-drug resistant bacterial activity of aqueous, chloroform, ethanol and hexane extracts of Alkanna tinctoria leaves were evaluated by well diffusion method. Minimum inhibitory concentrations (MICs) and minimum bactericidal concentrations (MBCs) of different extracts were determined. Moreover qualitative phytochemicals screening of the studied extracts was performed. All four selected bacteria including A. baumannii, E. coli, P. aeruginosa and S. aureus were categorized as multi-drug resistant (MDR) as they were found to be resistant to 13, 10, 19 and 22 antibiotics belonging to different groups respectively. All the four extract showed potential activity against S. aureus as compare to positive control antibiotic (Imipenem). Similarly among the four extracts of Alkanna tinctoria leaves, aqueous extract showed best activity against A. baumannii (10±03 mm), P. aeruginosa (12±0.5 mm), and S. aureus (14±0.5 mm) as compare to Imipenem. The MICs and MBCs results also showed quantitative concentration of plant extracts to inhibit or kill MDR bacteria. When phytochemicals analysis was performed it was observed that aqueous and ethanol extracts showed phytochemicals with large number as well as volume, especially Alkaloides, Flavonoides and Charbohydrates. The undertaken study demonstrated that all the four extracts of Alkanna tinctoria leaves exhibited considerable antibacterial activity against MDR isolates. Finding from the

Rate of Contamination Removal of Two Phyto-remediation Sites at the DOE Portsmouth Gaseous Diffusion Plant

International Nuclear Information System (INIS)

Lewis, A.C.; Baird, D.R.

2006-01-01

This paper describes applications of phyto-remediation at the Portsmouth Gaseous Diffusion Plant (PORTS), a Department of Energy (DOE) Facility that enriched uranium from the early 1950's until 2000. Phyto-remediation has been implemented to assist in the removal of TCE (trichloroethylene) in the groundwater at two locations at the PORTS facility: the X-740 area and the X-749/X-120 area. Phyto-remediation technology is based on the ability of certain plants species (in this case hybrid poplar trees) and their associated rhizo-spheric microorganisms to remove, degrade, or contain chemical contaminants located in the soil, sediment, surface water, groundwater, and possibly even the atmosphere. Phyto-remediation technology is a promising clean-up solution for a wide variety of pollutants and sites. Mature trees, such as the hybrid poplar, can consume up to 3,000 gallons of groundwater per acre per day. Organic compounds are captured in the trees' root systems. These organic compounds are degraded by ultraviolet light as they are transpired along with the water vapor through the leaves of the trees. The phyto-remediation system at the X-740 area encompasses 766 one-year old hybrid poplar trees (Populus nigra x nigra, Populus nigra x maximowiczii, and Populus deltoides x nigra) that were planted 10 feet apart in rows 10 feet to 20 feet apart, over an area of 2.6 acres. The system was installed to manage the VOC contaminant plume. At the X749/X-120 area, a phyto-remediation system of 2,640 hybrid poplar trees (Populus nigra x maximowiczii) was planted in seven areas/zones to manage the VOC contaminant plume. The objectives of these systems are to remove contamination from the groundwater and to prevent further migration of contaminants. The goal of these remediation procedures is to achieve completely mature and functional phyto-remediation systems within two years of the initial planting of the hybrid poplar trees at each planting location. There is a direct

Preliminary antidiarrhoeal activity of methanolic extracts of ...

African Journals Online (AJOL)

Securinega virosa is used as remedy for diarrhoea in tropical Africa, but has not been investigated for its antidiarrhoeal activity. This study was therefore aimed at investigating the methanolic extracts of the leaves, stem bark and root bark for antidirrhoeal activity, using castor oil-induced diarrhoeal model in mice. The effects ...

Building blocks for ionic liquids: Vapor pressures and vaporization enthalpies of 1-(n-alkyl)-imidazoles

International Nuclear Information System (INIS)

Emel'yanenko, Vladimir N.; Portnova, Svetlana V.; Verevkin, Sergey P.; Skrzypczak, Andrzej; Schubert, Thomas

2011-01-01

Highlights: → We measured vapor pressures of the 1-(n-alkyl)-imidazoles by transpiration method. → Variations on the alkyl chain length n were C 3 , C 5 -C 7 , and C 9 -C 10 . → Enthalpies of vaporization were derived from (p, T) dependencies. → Enthalpies of vaporization at 298.15 K were linear dependent on the chain length. - Abstract: Vapor pressures of the linear 1-(n-alkyl)-imidazoles with the alkyl chain C 3 , C 5 -C 7 , and C 9 -C 10 have been measured by the transpiration method. The molar enthalpies of vaporization Δ l g H m of these compounds were derived from the temperature dependencies of vapor pressures. A linear correlation of enthalpies of vaporization Δ l g H m (298.15 K) of the 1-(n-alkyl)-imidazoles with the chain length has been found.

Application of LC-ESI-MS-MS for detection of synthetic adulterants in herbal remedies.

Science.gov (United States)

Bogusz, Maciej J; Hassan, Huda; Al-Enazi, Eid; Ibrahim, Zuhour; Al-Tufail, Mohammed

2006-05-03

Adulteration of allegedly "natural herbal medicines" with undeclared synthetic drugs is a common and dangerous phenomenon of alternative medicine. The purpose of the study was to develop a procedure for detection of most common synthetic adulterants in herbal remedies, using high-pressure liquid chromatography-electrospray tandem mass spectrometry (LC-ESI-MS-MS). Eighty drugs belonging to various pharmacological classes were included in the study. For most drugs two transitions were monitored, using protonated or deprotonated molecules as precursor ions. The drugs were isolated from herbal remedies using simple methanol extraction. Chromatographic separation was done in gradient of acetonitrile-10 mM ammonium formate buffer (pH 3.0). Drugs tested were grouped in suites, comprising analgesic drugs, antibiotics, antidiabetic drugs, antiepileptic drugs, aphrodisiacs, hormones and anabolic drugs, psychotropic drugs, and weight reducing compounds. These suites were used according to the declared benefits of examined preparations. Limits of detection ranged from 5 pg to 1 ng per injected sample. Drug-free herbal remedy spiked with eight various pharmaceuticals occurring in adulterated herbal preparations was used for internal proficiency testing. The recoveries of spiked drugs ranged from 63 to 100%. The procedure was applied in everyday casework. Several undeclared drugs were identified in "herbal" remedies, like e.g. sildenafil, tadalafil, testosterone, or glibenclamide. Pharmacological properties of detected drugs always corresponded with the claims of the "natural" remedies. The method presents a valuable extension of standard GC-MS screening used for this purpose.

Vapor pressure and enthalpy of vaporization of oil of catnip by correlation gas chromatography

International Nuclear Information System (INIS)

Simmons, Daniel; Gobble, Chase; Chickos, James

2016-01-01

Highlights: • Vaporization enthalpies of the nepetalactones from oil of catnip have been evaluated. • Vapor pressures from T = (298.15 to 350) K have been evaluated. • Oil of catnip has a vapor pressure similar to DEET at T = 298.15 K. - Abstract: The vaporization enthalpy and vapor pressure of the two nepetalactones found in Nepeta cataria have been evaluated by correlation gas chromatography. Vaporization enthalpies at T = 298.15 K of {(68.0 ± 1.9) and (69.4 ± 1.9)} kJ ⋅ mol"−"1 have been derived for the minor diastereomer, (4aS,7S,7aS)-nepetalactone, and major one, (4aS,7S,7aR)-nepetalactone, respectively. Vapor pressures also at T = 298.15 K of p = (1.2 ± 0.04) Pa and (0.91 ± 0.03) Pa have been evaluated for the minor and the major stereoisomer. In addition to being of interest because of the remarkable effect it has on various felids, oil of catnip is also quite effective in repelling mosquitoes, comparable to diethyl-m-toluamide (DEET). The vapor pressures evaluated in this work suggest that the two stereoisomers have similar volatility to DEET at ambient temperatures.

Remediation mechanisms for Cd-contaminated soil using natural sepiolite at the field scale.

Science.gov (United States)

Yin, Xiuling; Xu, Yingming; Huang, Rong; Huang, Qingqing; Xie, Zhonglei; Cai, Yanming; Liang, Xuefeng

2017-12-13

Remediation of heavy metal polluted agricultural soil is essential for human health and ecological safety and remediation mechanisms at the microscopic level are vital for their large-scale utilization. In this study, natural sepiolite was employed as an immobilization agent for in situ field-scale remediation of Cd-contaminated paddy soil and the remediation mechanisms were investigated in terms of soil chemistry and plant physiology. Natural sepiolite had a significant immobilization effect for bioavailable Cd contents in paddy soil, and consequently could lower the Cd concentrations of brown rice, husk, straw, and roots of rice plants by 54.7-73.7%, 44.0-62.5%, 26.5-67.2%, and 36.7-46.7%, respectively. Regarding soil chemistry, natural sepiolite increased the soil pH values and shifted the zeta potentials of soil particles to be more negative, enhancing the fixation or sorption of Cd on soil particles, and resulted in the reduction of HCl and DTPA extractable Cd concentrations in paddy soil. Natural sepiolite neither enhanced nor inhibited iron plaques on the rice root surface, but did change the chemical environments of Fe and S in rice root. Natural sepiolite improved the activities of antioxidant enzymes and enhanced the total antioxidant capacity to alleviate the stress of Cd. It also promotes the synthesis of GSH and NPT to complete the detoxification. In general, the remediation mechanisms of natural sepiolite for the Cd pollutant in paddy soil could be summarized as the collective effects of soil chemistry and plant physiology.

Remedial action and waste disposal project -- 300-FF-1 remedial action readiness assessment plan

International Nuclear Information System (INIS)

April, J.G.; Carlson, R.A.; Greif, A.A.; Johnson, C.R.; Orewiler, R.I.; Perry, D.M.; Plastino, J.C.; Roeck, F.V.; Tuttle, B.G.

1997-04-01

This Readiness Assessment Plan presents the methodology used to assess the readiness of the 300-FF-1 Remedial Action Project. Remediation involves the excavation, treatment if applicable, and final disposal of contaminated soil and debris associated with the waste sites in the 300-FF-1 Operable Unit. The scope of the 300-FF-1 remediation is to excavate, transport, and dispose of contaminated solid from sites identified in the 300-FF-1 Operable Unit

X-231A demonstration of in-situ remediation of DNAPL compounds in low permeability media by soil fracturing with thermally enhanced mass recovery or reactive barrier destruction

International Nuclear Information System (INIS)

Siegrist, R.L.; Slack, W.W.; Houk, T.C.

1998-03-01

The overall goal of the program of activities is to demonstrate robust and cost-effective technologies for in situ remediation of DNAPL compounds in low permeability media (LPM), including adaptations and enhancements of conventional technologies to achieve improved performance for DNAPLs in LPM. The technologies sought should be potential for application at simple, small sites (e.g., gasoline underground storage tanks) as well as at complex, larger sites (e.g., DOE land treatment units). The technologies involved in the X-231A demonstration at Portsmouth Gaseous Diffusion Plant (PORTS) utilized subsurface manipulation of the LPM through soil fracturing with thermally enhanced mass recovery or horizontal barrier in place destruction. To enable field evaluation of these approaches, a set of four test cells was established at the X-231A land treatment unit at the DOE PORTS plant in August 1996 and a series of demonstration field activities occurred through December 1997. The principal objectives of the PORTS X-231A demonstration were to: determine and compare the operational features of hydraulic fractures as an enabling technology for steam and hot air enhanced soil vapor extraction and mass recovery, in situ interception and reductive destruction by zero valent iron, and in situ interception and oxidative destruction by potassium permanganate; determine the interaction of the delivered agents with the LPM matrix adjacent to the fracture and within the fractured zone and assess the beneficial modifications to the transport and/or reaction properties of the LPM deposit; and determine the remediation efficiency achieved by each of the technology strategies

Assessing sustainable remediation frameworks using sustainability principles.

Science.gov (United States)

Ridsdale, D Reanne; Noble, Bram F

2016-12-15

The remediation industry has grown exponentially in recent decades. International organizations of practitioners and remediation experts have developed several frameworks for integrating sustainability into remediation projects; however, there has been limited attention to how sustainability is approached and operationalized in sustainable remediation frameworks and practices - or whether sustainability plays any meaningful role at all in sustainable remediation. This paper examines how sustainability is represented in remediation frameworks and the guidance provided for practical application. Seven broad sustainability principles and review criteria are proposed and applied to a sample of six international remediation frameworks. Not all review criteria were equally satisfied and none of the frameworks fully met all criteria; however, the best performing frameworks were those identified as sustainability remediation frameworks. Intra-generational equity was addressed by all frameworks. Integrating social, economic and biophysical components beyond triple-bottom-line indicators was explicitly addressed only by the sustainable remediation frameworks. No frameworks provided principle- or rule-based guidance for dealing with trade-offs in sustainability decisions. Copyright © 2016 Elsevier Ltd. All rights reserved.

Remediation approaches for polycyclic aromatic hydrocarbons (PAHs) contaminated soils: Technological constraints, emerging trends and future directions.

Science.gov (United States)

Kuppusamy, Saranya; Thavamani, Palanisami; Venkateswarlu, Kadiyala; Lee, Yong Bok; Naidu, Ravi; Megharaj, Mallavarapu

2017-02-01

For more than a decade, the primary focus of environmental experts has been to adopt risk-based management approaches to cleanup PAH polluted sites that pose potentially destructive ecological consequences. This focus had led to the development of several physical, chemical, thermal and biological technologies that are widely implementable. Established remedial options available for treating PAH contaminated soils are incineration, thermal conduction, solvent extraction/soil washing, chemical oxidation, bioaugmentation, biostimulation, phytoremediation, composting/biopiles and bioreactors. Integrating physico-chemical and biological technologies is also widely practiced for better cleanup of PAH contaminated soils. Electrokinetic remediation, vermiremediation and biocatalyst assisted remediation are still at the development stage. Though several treatment methods to remediate PAH polluted soils currently exist, a comprehensive overview of all the available remediation technologies to date is necessary so that the right technology for field-level success is chosen. The objective of this review is to provide a critical overview in this respect, focusing only on the treatment options available for field soils and ignoring the spiked ones. The authors also propose the development of novel multifunctional green and sustainable systems like mixed cell culture system, biosurfactant flushing, transgenic approaches and nanoremediation in order to overcome the existing soil- contaminant- and microbial-associated technological limitations in tackling high molecular weight PAHs. The ultimate objective is to ensure the successful remediation of long-term PAH contaminated soils. Copyright © 2016 Elsevier Ltd. All rights reserved.

Risk-based remediation: Approach and application

International Nuclear Information System (INIS)

Frishmuth, R.A.; Benson, L.A.

1995-01-01

The principle objective of remedial actions is to protect human health and the environment. Risk assessments are the only defensible tools available to demonstrate to the regulatory community and public that this objective can be achieved. Understanding the actual risks posed by site-related contamination is crucial to designing cost-effective remedial strategies. All to often remedial actions are overdesigned, resulting in little to no increase in risk reduction while increasing project cost. Risk-based remedial actions have recently been embraced by federal and state regulators, industry, government, the scientific community, and the public as a mechanism to implement rapid and cost-effective remedial actions. Emphasizing risk reduction, rather than adherence to ambiguous and generic standards, ensures that only remedial actions required to protect human health and the environment at a particular site are implemented. Two sites are presented as case studies on how risk-based approaches are being used to remediate two petroleum hydrocarbon contaminated sites. The sites are located at two US Air Force Bases, Wurtsmith Air Force Base (AFB) in Oscoda, Michigan and Malmstrom AFB in Great Falls, Montana

Cost considerations in remediation and disposal

International Nuclear Information System (INIS)

Dance, J.T.; Huddleston, R.D.

1999-01-01

Opportunities for assessing the costs associated with the reclamation and remediation of sites contaminated by oilfield wastes are discussed. The savings can be maximized by paying close attention to five different aspects of the overall site remediation and disposal process. These are: (1) highly focused site assessment, (2) cost control of treatment and disposal options, (3) value added cost benefits, (4) opportunities to control outside influences during the remedial process, and (5) opportunities for managing long-term liabilities and residual risk remaining after the remedial program is completed. It is claimed that addressing these aspects of the process will ultimately lower the overall cost of site remediation and waste disposal

CENTRAL PLATEAU REMEDIATION OPTIMIZATION STUDY

Energy Technology Data Exchange (ETDEWEB)

BERGMAN, T. B.; STEFANSKI, L. D.; SEELEY, P. N.; ZINSLI, L. C.; CUSACK, L. J.

2012-09-19

THE CENTRAL PLATEAU REMEDIATION OPTIMIZATION STUDY WAS CONDUCTED TO DEVELOP AN OPTIMAL SEQUENCE OF REMEDIATION ACTIVITIES IMPLEMENTING THE CERCLA DECISION ON THE CENTRAL PLATEAU. THE STUDY DEFINES A SEQUENCE OF ACTIVITIES THAT RESULT IN AN EFFECTIVE USE OF RESOURCES FROM A STRATEGIC PERSPECTIVE WHEN CONSIDERING EQUIPMENT PROCUREMENT AND STAGING, WORKFORCE MOBILIZATION/DEMOBILIZATION, WORKFORCE LEVELING, WORKFORCE SKILL-MIX, AND OTHER REMEDIATION/DISPOSITION PROJECT EXECUTION PARAMETERS.

[Cognitive remediation and nursing care].

Science.gov (United States)

Schenin-King, Palmyre; Thomas, Fanny; Braha-Zeitoun, Sonia; Bouaziz, Noomane; Januel, Dominique

2016-01-01

Therapies based on cognitive remediation integrate psychiatric care. Cognitive remediation helps to ease cognitive disorders and enable patients to improve their day-to-day lives. It is essential to complete nurses' training in this field. This article presents the example of a patient with schizophrenia who followed the Cognitive Remediation Therapy programme, enabling him to access mainstream employment. Copyright © 2016 Elsevier Masson SAS. All rights reserved.

A multidisciplinary approach to site remediation and management in a bedrock environment

Energy Technology Data Exchange (ETDEWEB)

Millard, G. [Shell Canada Ltd., Calgary, AB (Canada); Micklethwaite, R.; Digel, S.; Lyons, E. [O' Connor Associates Environmental Inc., Calgary, AB (Canada)

2006-07-01

A multidisciplinary approach to site remediation and management in a bedrock environment was presented. This presentation provided a description of the site which was a former service station from 1985 to 2003 in Calgary. Illustrations of the subject site and stratigraphic section were presented along with initial environmental conditions. The project objectives included: managing the site so that a tenant could re-develop and occupy the site; minimizing management costs until long-term, remediation could be achieved; and, developing and implementing a plan to assess, mitigate, and manage the risk in a manner accepted by Alberta Environment and the City of Calgary. The presentation also addressed issues regarding a risk-assessment, high vacuum extraction system, and refining HVE operations. The regulatory, business and ancillary outcomes of the risk assessment were also outlined. Last, the presentation identified how the results were achieved. tabs., figs.

Green solvents and technologies for oil extraction from oilseeds

OpenAIRE

Kumar, S. P. Jeevan; Prasad, S. Rajendra; Banerjee, Rintu; Agarwal, Dinesh K.; Kulkarni, Kalyani S.; Ramesh, K. V.

2017-01-01

Oilseeds are crucial for the nutritional security of the global population. The conventional technology used for oil extraction from oilseeds is by solvent extraction. In solvent extraction, n-hexane is used as a solvent for its attributes such as simple recovery, non-polar nature, low latent heat of vaporization (330?kJ/kg) and high selectivity to solvents. However, usage of hexane as a solvent has lead to several repercussions such as air pollution, toxicity and harmfulness that prompted to...

Plant-based remediation processes

Energy Technology Data Exchange (ETDEWEB)

Gupta, Dharmendra Kumar (ed.) [Belgian Nuclear Research Centre (SCK.CEN), Mol (Belgium). Radiological Impact and Performance Assessment Division

2013-11-01

A valuable source of information for scientists in the field of environmental pollution and remediation. Describes the latest biotechnological methods for the treatment of contaminated soils. Includes case studies and protocols. Phytoremediation is an emerging technology that employs higher plants for the clean-up of contaminated environments. Basic and applied research have unequivocally demonstrated that selected plant species possess the genetic potential to accumulate, degrade, metabolize and immobilize a wide range of contaminants. The main focus of this volume is on the recent advances of technologies using green plants for remediation of various metals and metalloids. Topics include biomonitoring of heavy metal pollution, amendments of higher uptake of toxic metals, transport of heavy metals in plants, and toxicity mechanisms. Further chapters discuss agro-technological methods for minimizing pollution while improving soil quality, transgenic approaches to heavy metal remediation and present protocols for metal remediation via in vitro root cultures.

Organization of extracting molecules of the diamide type: link with the extracting properties?

International Nuclear Information System (INIS)

Meridiano, Y.

2009-02-01

The aim of these studies is to establish a link between the different organizations of diamide extractants (used in the DIAMEX process) and their extracting properties. The effects of the key parameters leading the liquid-liquid extraction (concentration of extractant, nature of solute, activity of the aqueous phase, nature of the diluent and temperature) are studied: 1) at the supramolecular scale, with the characterization of the extractant organizations by vapor-pressure osmometry (VPO) and small angle neutron and X-ray scattering (SANS/SAXS) experiments; 2) at the molecular scale, with the quantification of the extracted solutes (water, nitric acid, metal nitrate) and the determination of extracted complexes stoichiometries by electro-spray mass spectrometry (ESI-MS) experiments. The DMDOHEMA molecule acts as a classical surfactant and forms aggregates of the reverse micelle type. Taking into account the established supramolecular diagrams, a quantitative link between the extractants structures and their extracting properties has been brought to light. To model the europium nitrate extraction, two approaches have been developed: - an approach based on mass action laws. Extractions equilibria have been proposed taking into account the supramolecular speciation; - an innovative approach considering the extracted ions as adsorbed on a specific surface of the extractant molecule which depends on the extractant organization state. The ion extraction can be considered as a sum of isotherms corresponding to the different states of organization. This approach allows to compare the extraction efficiency of an extracting molecule as a function of its organization state. (author)

Pharmacological Studies of Artichoke Leaf Extract and Their Health Benefits.

Science.gov (United States)

Ben Salem, Maryem; Affes, Hanen; Ksouda, Kamilia; Dhouibi, Raouia; Sahnoun, Zouheir; Hammami, Serria; Zeghal, Khaled Mounir

2015-12-01

Artichoke (Cynara scolymus) leaf extract was one of the few herbal remedies which the clinical and experimental trials have complemented each other. Both experimental and clinical effects have been verified through extensive biomedical herbal remedy research. Specifically, antioxidant, choleretic, hepatoprotective, bile-enhancing and lipid-lowering effects have been demonstrated, which corresponded with its historical use. Ongoing research seems to indicate that artichoke indeed have medicinal qualities. Most significant appears to be its beneficial effect on the liver. In animal studies, liquid extracts of the roots and leaves of artichoke have demonstrated an ability to protect the liver, with possibly even to help liver cells regenerate. Although research is not yet conclusive, scientists were optimistic that its long-standing use in humans for digestive and bowel problems was indeed justified. It may also play a role in lowering cholesterol and thus help to prevent heart disease. Boiled wild artichoke reduced postprandial glycemic and insulinemic responses in normal subjects but has no effect on metabolic syndrome patients. This article intended to review the wide ranging pharmacological effects of artichoke leaf extract.

Vapor pressures and vaporization enthalpy of (−) α-bisabolol and (dl) menthol by correlation gas chromatography

International Nuclear Information System (INIS)

Keating, Leasa; Harris, Harold H.; Chickos, James S.

2017-01-01

Highlights: • The vaporization enthalpy and vapor pressure of (−) α-bisabolol and (dl)-menthol have been measured as a function of temperature. • Vapor pressures, vaporization enthalpies and boiling temperatures have been compared to available literature data. • Vapor pressures of (l)-menthol are compared to (dl)-menthol. - Abstract: The vapor pressures and vaporization enthalpies of (−) α-bisabolol and (dl)-menthol, two GRAS chemicals (generally recognized as safe) are evaluated by correlation gas chromatography using a series of saturated primary alcohols as standards. Vaporization enthalpies of (96.6 ± 2.4) and (74.2 ± 2.8) kJ mol −1 and vapor pressures of p/Pa = (0.020 ± 0.003) and (4.5 ± 0.44) were evaluated at T = 298.15 K for (−) α-bisabolol and (dl)-menthol, respectively, and compared to literature values. The vapor pressures of both compounds from T = (298.15 to 500) K have been derived from correlations using vapor pressures of a series of 1-alkanols and corresponding gas chromatographic retention times at 10 K intervals. The results were fit to a second order polynomial. Calculated normal boiling temperatures of T B = (574.8 and 492.7) K are calculated for (−) α-bisabolol and (dl)-menthol, respectively. A normal boiling temperature of T B = (485.2, and 489.7) K has previously been reported for (dl)-menthol. Vapor pressures for both (l)-menthol and (dl)-menthol from a previous study and (dl)-menthol from this study are compared with literature values.

Melting temperature, vapor density, and vapor pressure of molybdenum pentafluoride

Energy Technology Data Exchange (ETDEWEB)

Krause, Jr, R F; Douglas, T B [National Bureau of Standards, Washington, D.C. (USA). Inst. for Materials Research

1977-12-01

A sample of MoF/sub 5/ was prepared by reaction of MoF/sub 6/(g) and Mo(c). Melting curves of temperature against time established the melting temperature at zero impurity to be 318.85 K, the enthalpy of fusion to be 6.1 kJ mol/sup -1/ (+ - 5 per cent), and the cryoscopic impurity of the sample to be 0.15 mole per cent. In the presence of MoF/sub 6/(g) which was added to suppress disproportionation, the vapor density of MoF/sub 5/ over the liquid was measured by the transpiration method at 343, 363, and 383 K, the total MoF/sub 5/ that evaporated being determined by permanganate titration. The total vapor pressure of MoF/sub 5/ oligomers over the liquid was measured by a simple static method at 373 and 392 K, while melting temperatures were taken alternately to monitor possible contamination of the sample. Although the vapor pressures were adjusted for disproportionation, solution of MoF/sub 6/ in MoF/sub 5/ (1), and wall adsorption of MoF/sub 6/ their percentage uncertainty is probably several times that of the vapor densities. A combination of the two properties indicates the average extent of association of the saturated vapor to be near 2, which is the value for the dimer species (MoF/sub 5/)/sub 2/.

Green synthesis of Fe nanoparticles using eucalyptus leaf extracts for treatment of eutrophic wastewater

International Nuclear Information System (INIS)

Wang, Ting; Jin, Xiaoying; Chen, Zuliang; Megharaj, Mallavarapu; Naidu, Ravendra

2014-01-01

Iron nanoparticles were firstly synthesized through a one-step room-temperature biosynthetic route using eucalyptus leaf extracts (EL-Fe NPs). Scanning electron microscopy (SEM) and X-ray energy-dispersive spectrometer (EDS) confirmed the successful synthesis of the spheroidal iron nanoparticles. Furthermore, X-ray diffraction (XRD) and Fourier Transform Infrared spectrometer (FTIR) indicated that some polyphenols are bound to the surfaces of EL-Fe NPs as a capping/stabilizing agent. Reactivity of EL-Fe NPs was evaluated for the treatment of swine wastewater and results indicated that 71.7% of total N and 84.5% of COD were removed, respectively. This demonstrated the tremendous potential of EL-Fe NPs for in situ remediation of eutrophic wastewater. - Highlights: •Fe NPs were firstly synthesized through a one-step using eucalyptus leaf extracts. •Fe NPs was evaluated by remediating swine wastewater. •71.7% of total N and 84.5% of COD was removed. •Fe NPs for in situ remediation of eutrophic wastewater

Green synthesis of Fe nanoparticles using eucalyptus leaf extracts for treatment of eutrophic wastewater

Energy Technology Data Exchange (ETDEWEB)

Wang, Ting; Jin, Xiaoying [School of Environmental Science and Engineering, Fujian Normal University, Fuzhou 350007, Fujian (China); Chen, Zuliang, E-mail: Zuliang.chen@unisa.edu.au [School of Environmental Science and Engineering, Fujian Normal University, Fuzhou 350007, Fujian (China); Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes, SA 5095 (Australia); Cooperative Research Centre for Contamination Assessment and Remediation of Environments, Mawson Lakes, SA 5095 (Australia); Megharaj, Mallavarapu; Naidu, Ravendra [Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes, SA 5095 (Australia); Cooperative Research Centre for Contamination Assessment and Remediation of Environments, Mawson Lakes, SA 5095 (Australia)

2014-01-01

Iron nanoparticles were firstly synthesized through a one-step room-temperature biosynthetic route using eucalyptus leaf extracts (EL-Fe NPs). Scanning electron microscopy (SEM) and X-ray energy-dispersive spectrometer (EDS) confirmed the successful synthesis of the spheroidal iron nanoparticles. Furthermore, X-ray diffraction (XRD) and Fourier Transform Infrared spectrometer (FTIR) indicated that some polyphenols are bound to the surfaces of EL-Fe NPs as a capping/stabilizing agent. Reactivity of EL-Fe NPs was evaluated for the treatment of swine wastewater and results indicated that 71.7% of total N and 84.5% of COD were removed, respectively. This demonstrated the tremendous potential of EL-Fe NPs for in situ remediation of eutrophic wastewater. - Highlights: •Fe NPs were firstly synthesized through a one-step using eucalyptus leaf extracts. •Fe NPs was evaluated by remediating swine wastewater. •71.7% of total N and 84.5% of COD was removed. •Fe NPs for in situ remediation of eutrophic wastewater.

DOE'S remedial action assurance program

International Nuclear Information System (INIS)

Welty, C.G. Jr.; Needels, T.S.; Denham, D.H.

1984-10-01

The formulation and initial implementation of DOE's Assurance Program for Remedial Action are described. It was initiated in FY 84 and is expected to be further implemented in FY 85 as the activities of DOE's Remedial Action programs continue to expand. Further APRA implementation will include additional document reviews, site inspections, and program office appraisals with emphasis on Uranium Mill Tailings Remedial Action Program and Surplus Facilities Management Program

Remediation of spatial processing disorder (SPD).

Science.gov (United States)

Graydon, Kelley; Van Dun, Bram; Tomlin, Dani; Dowell, Richard; Rance, Gary

2018-05-01

To determine the efficacy of deficit-specific remediation for spatial processing disorder, quantify effects of remediation on functional listening, and determine if remediation is maintained. Participants had SPD, diagnosed using the Listening in Spatialised Noise-Sentences test. The LiSN and Learn software was provided as auditory training. Post-training, repeat LiSN-S testing was conducted. Questionnaires pre- and post-training acted as subjective measures of remediation. A late-outcome assessment established long-term effects of remediation. Sixteen children aged between 6;3 [years; months] and 10;0 completed between 20 and 146 training games. Post-training LiSN-S improved in measures containing spatial cues (p ≤ 0.001) by 2.0 SDs (3.6 dB) for DV90, 1.8 SDs for SV90 (3.2 dB), 1.4 SDs for spatial advantage (2.9 dB) and 1.6 SDs for total advantage (3.3 dB). Improvement was also found in the DV0 condition (1.4 dB or 0.5 SDs). Post-training changes were not significant in the talker advantage measure (1.0 dB or 0.4 SDs) or the SV0 condition (0.3 dB or 0.1 SDs). The late-outcome assessment demonstrated improvement was maintained. Subjective improvement post-remediation was observed using the parent questionnaire. Children with SPD had improved ability to utilise spatial cues following deficit-specific remediation, with the parent questionnaire sensitive to remediation. Effects of the remediation also appear to be sustained.

R-22 vapor explosions

International Nuclear Information System (INIS)

Anderson, R.P.; Armstrong, D.R.

1977-01-01

Previous experimental and theoretical studies of R-22 vapor explosions are reviewed. Results from two experimental investigations of vapor explosions in a medium scale R-22/water system are reported. Measurements following the drop of an unrestrained mass of R-22 into a water tank demonstrated the existence of two types of interaction behavior. Release of a constrained mass of R-22 beneath the surface of a water tank improved the visual resolution of the system thus allowing identification of two interaction mechansims: at low water temperatures, R-22/water contact would produce immediate violent boiling; at high water temperatures a vapor film formed around its R-22 as it was released, explosions were generated by a surface wave which initiated at a single location and propagated along the vapor film as a shock wave. A new vapor explosion model is proposed, it suggests explosions are the result of a sequence of three independent steps: an initial mixing phase, a trigger and growth phase, and a mature phase where a propagating shock wave accelerates the two liquids into a collapsing vapor layer causing a high velocity impact which finely fragments and intermixes the two liquids

46 CFR 298.41 - Remedies after default.

Science.gov (United States)

2010-10-01

... 46 Shipping 8 2010-10-01 2010-10-01 false Remedies after default. 298.41 Section 298.41 Shipping... Defaults and Remedies, Reporting Requirements, Applicability of Regulations § 298.41 Remedies after default... governing remedies after a default, which relate to our rights and duties, the rights and duties of the...

Reduction of metal exposure of Daubenton's bats (Myotis daubentonii) following remediation of pond sediment as evidenced by metal concentrations in hair

Energy Technology Data Exchange (ETDEWEB)

Flache, Lucie, E-mail: Lucie.Flache@bio.uni-giessen.de [Mammalian Ecology Group, Department of Animal Ecology and Systematics, Justus Liebig University of Giessen, Heinrich-Buff-Ring 26, D-35392 Giessen (Germany); Ekschmitt, Klemens [Animal Ecology, Department of Animal Ecology and Systematics, Justus Liebig University of Giessen, Heinrich-Buff-Ring 26, D-35392 Giessen (Germany); Kierdorf, Uwe [Department of Biology, University of Hildesheim, Universitätsplatz 1, D-31141 Hildesheim (Germany); Czarnecki, Sezin; Düring, Rolf-Alexander [Institute of Soil Science and Soil Conservation, Justus Liebig University of Giessen, Heinrich-Buff-Ring 26, D-35392 Giessen (Germany); Encarnação, Jorge A. [Mammalian Ecology Group, Department of Animal Ecology and Systematics, Justus Liebig University of Giessen, Heinrich-Buff-Ring 26, D-35392 Giessen (Germany)

2016-03-15

Transfer of contaminants from freshwater sediments via aquatic insects to terrestrial predators is well documented in spiders and birds. Here, we analyzed the metal exposure of Myotis daubentonii using an urban pond as their preferred foraging area before and after a remediation measure (sediment dredging) at this pond. Six metal elements (Zn, Cu, Cr, Cd, Pb and Ni) were measured in the sediment of the pond, in EDTA extracts of the sediment and in hair samples of M. daubentonii foraging at the pond. Samples were taken before remediation in 2011 and after remediation in 2013. Metal concentrations were quantified by ICP-OES after miniaturized microwave assisted extraction. In 2011, the pond sediment exhibited a high contamination with nickel, a moderate contamination with copper and chromium and low contents of zinc, cadmium and lead. While sediment metal contents declined only weakly after remediation, a much more pronounced reduction in the concentrations of zinc, copper, chromium and lead concentrations was observed in bat hair. Our results suggest a marked decline in metal exposure of the bats foraging at the pond as a consequence of the remediation measure. It is concluded that Daubenton's bats are suitable bioindicators of metal contamination in aquatic environments, integrating metal exposure via prey insects over their entire foraging area. We further suggest that bat hair is a useful monitoring unit, allowing a non-destructive and non-invasive assessment of metal exposure in bats. - Highlights: • Changes in metal exposure of bats due to remediation measure are documented. • Bats are suitable bioindicators of metal pollution. • Bat hair is a useful monitoring unit in such studies.

Piezoelectric trace vapor calibrator

International Nuclear Information System (INIS)

Verkouteren, R. Michael; Gillen, Greg; Taylor, David W.

2006-01-01

The design and performance of a vapor generator for calibration and testing of trace chemical sensors are described. The device utilizes piezoelectric ink-jet nozzles to dispense and vaporize precisely known amounts of analyte solutions as monodisperse droplets onto a hot ceramic surface, where the generated vapors are mixed with air before exiting the device. Injected droplets are monitored by microscope with strobed illumination, and the reproducibility of droplet volumes is optimized by adjustment of piezoelectric wave form parameters. Complete vaporization of the droplets occurs only across a 10 deg. C window within the transition boiling regime of the solvent, and the minimum and maximum rates of trace analyte that may be injected and evaporated are determined by thermodynamic principles and empirical observations of droplet formation and stability. By varying solution concentrations, droplet injection rates, air flow, and the number of active nozzles, the system is designed to deliver--on demand--continuous vapor concentrations across more than six orders of magnitude (nominally 290 fg/l to 1.05 μg/l). Vapor pulses containing femtogram to microgram quantities of analyte may also be generated. Calibrated ranges of three explosive vapors at ng/l levels were generated by the device and directly measured by ion mobility spectrometry (IMS). These data demonstrate expected linear trends within the limited working range of the IMS detector and also exhibit subtle nonlinear behavior from the IMS measurement process

Endothelial disruptive proinflammatory effects of nicotine and e-cigarette vapor exposures.

Science.gov (United States)

Schweitzer, Kelly S; Chen, Steven X; Law, Sarah; Van Demark, Mary; Poirier, Christophe; Justice, Matthew J; Hubbard, Walter C; Kim, Elena S; Lai, Xianyin; Wang, Mu; Kranz, William D; Carroll, Clinton J; Ray, Bruce D; Bittman, Robert; Goodpaster, John; Petrache, Irina

2015-07-15

The increased use of inhaled nicotine via e-cigarettes has unknown risks to lung health. Having previously shown that cigarette smoke (CS) extract disrupts the lung microvasculature barrier function by endothelial cell activation and cytoskeletal rearrangement, we investigated the contribution of nicotine in CS or e-cigarettes (e-Cig) to lung endothelial injury. Primary lung microvascular endothelial cells were exposed to nicotine, e-Cig solution, or condensed e-Cig vapor (1-20 mM nicotine) or to nicotine-free CS extract or e-Cig solutions. Compared with nicotine-containing extract, nicotine free-CS extract (10-20%) caused significantly less endothelial permeability as measured with electric cell-substrate impedance sensing. Nicotine exposures triggered dose-dependent loss of endothelial barrier in cultured cell monolayers and rapidly increased lung inflammation and oxidative stress in mice. The endothelial barrier disruptive effects were associated with increased intracellular ceramides, p38 MAPK activation, and myosin light chain (MLC) phosphorylation, and was critically mediated by Rho-activated kinase via inhibition of MLC-phosphatase unit MYPT1. Although nicotine at sufficient concentrations to cause endothelial barrier loss did not trigger cell necrosis, it markedly inhibited cell proliferation. Augmentation of sphingosine-1-phosphate (S1P) signaling via S1P1 improved both endothelial cell proliferation and barrier function during nicotine exposures. Nicotine-independent effects of e-Cig solutions were noted, which may be attributable to acrolein, detected along with propylene glycol, glycerol, and nicotine by NMR, mass spectrometry, and gas chromatography, in both e-Cig solutions and vapor. These results suggest that soluble components of e-Cig, including nicotine, cause dose-dependent loss of lung endothelial barrier function, which is associated with oxidative stress and brisk inflammation.

Technical and Economic Assessment of Solar Photovoltaic for Groundwater Extraction on the Hanford Site

Energy Technology Data Exchange (ETDEWEB)

Mackley, Rob D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Anderson, David M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Thomle, Jonathan N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Strickland, Christopher E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2015-09-01

The overall goal of environmental remediation is to protect human health and the environment. Implementing renewable energy sources such as solar photovoltaic (PV) in groundwater extraction and pump-and-treat (P&T) systems may help minimize the environmental footprint of remediation efforts. The first step in considering solar PV for powering Hanford groundwater extraction is assessing the technical and economic feasibility and identifying potential target locations where implementation would be most successful. Accordingly, a techno-economic assessment of solar PV for Hanford groundwater extraction was completed in FY15. Multiple solar PV alternatives ranging in size from 1.2 to 22.4 kWp DC were evaluated and compared against traditional grid-powered systems. Results indicate that the degree to which solar PV alternatives are feasible is primarily a function of the distance of avoided power cable costs and the inclusion of an energy storage component. Standalone solar PV systems provide an energy source at the well and avoid the costs and logistics associated with running long lengths of expensive power cable to the well-head. When solar PV systems include a battery storage component, groundwater can be pumped continuously day and night in a year-round schedule. However, due to the high cost premium of the energy storage component, a fully solar-powered solution could not provide an economic direct replacement for line-powered pumping systems. As a result, the most ideal target locations for successful implementation of solar PV on the Hanford Site are remote or distant extraction wells where the primary remedial objective is contaminant mass removal (as opposed to hydraulic containment) and three-season (March through October) intermittent pumping is acceptable (e.g. remediation of hexavalent chromium in 200-UP-1).

Development of an integrated, in-situ remediation technology. Topical report for task No. 5: Cost analysis, September 26, 1994--May 25, 1996

International Nuclear Information System (INIS)

Quinton, G.; Schultz, D.; Landis, R.

1997-01-01

Contamination in low permeability soils poses a significant technical challenge to in situ remediation efforts. Poor accessibility to the contaminants and difficulty in delivering treatment reagents have rendered existing in situ treatments such as bioremediation, vapor extraction, pump and treat rather ineffective when applied to low permeability soils present at many contaminated sites. The Lasagna trademark technology is an integrated in situ treatment in which established geotechnical methods are used to install degradation zones directly into the contaminated soil and electro-osmosis if utilized to move the contaminants back and forth through those zones until the treatment is completed. This topical report presents the results of an engineering evaluation and cost analysis of the vertically configured treatment process completed by the DuPont Company. The cost evaluation was prepared by developing a cost optimization model of the overall treatment process. This model considers various input parameters such as soil properties, depth of contamination, cost for emplacing electrodes and treatment zones, required purge water volume, time constraints to achieve cleanup, and cost of power. Several example cases were run using the cost model to provide representative cost ranges for applying the technology to clean up trichloroethene contamination in clay. These costs are estimated to range from $40 to $95 per cubic yard of soil for a 1-acre site, with cost depending on depth of contamination (cost range valid from 15 to 45 ft), method of electrode/treatment zone emplacement (cost range valid from 15 to 45 ft), method of electrode/treatment zone emplacement (cost range valid for Lasagna trademark Phase I emplacement and optimized emplacement techniques), and time available to complete remediation (cost range valid for one- and three-year timeframe)

32 CFR 310.47 - Civil remedies.

Science.gov (United States)

2010-07-01

... 32 National Defense 2 2010-07-01 2010-07-01 false Civil remedies. 310.47 Section 310.47 National Defense Department of Defense (Continued) OFFICE OF THE SECRETARY OF DEFENSE (CONTINUED) PRIVACY PROGRAM DOD PRIVACY PROGRAM Privacy Act Violations § 310.47 Civil remedies. In addition to specific remedial...

LCA of Soil and Groundwater Remediation

DEFF Research Database (Denmark)

Søndergaard, Gitte Lemming; Owsianiak, Mikolaj

2018-01-01

Today, there is increasing interest in applying LCA to support decision-makers in contaminated site management. In this chapter, we introduce remediation technologies and associated environmental impacts, present an overview of literature findings on LCA applied to remediation technologies...... and present methodological issues to consider when conducting LCAs within the area. Within the field of contaminated site remediation , a terminology distinguishing three types of environmental impacts: primary, secondary and tertiary, is often applied. Primary impacts are the site-related impacts due...... and efficiency of remediation, which are important for assessment or primary impacts; (ii) robust assessment of primary impacts using site-specific fate and exposure models; (iii) weighting of primary and secondary (or tertiary) impacts to evaluate trade-offs between life cycle impacts from remediation...

Policy and Strategies for Environmental Remediation

International Nuclear Information System (INIS)

2015-01-01

In the environmental remediation of a given site, concerned and interested parties have diverse and often conflicting interests with regard to remediation goals, the time frames involved, reuse of the site, the efforts necessary and cost allocation. An environmental remediation policy is essential for establishing the core values on which remediation is to be based. It incorporates a set of principles to ensure the safe and efficient management of remediation situations. Policy is mainly established by the national government and may become codified in the national legislative system. An environmental remediation strategy sets out the means for satisfying the principles and requirements of the national policy. It is normally established by the relevant remediation implementer or by the government in the case of legacy sites. Thus, the national policy may be elaborated in several different strategies. To ensure the safe, technically optimal and cost effective management of remediation situations, countries are advised to formulate an appropriate policy and strategies. Situations involving remediation include remediation of legacy sites (sites where past activities were not stringently regulated or adequately supervised), remediation after emergencies (nuclear and radiological) and remediation after planned ongoing operation and decommissioning. The environmental policy involves the principles of justification, optimization of protection, protection of future generations and the environment, efficiency in the use of resources, and transparent interaction with stakeholders. A typical policy will also take into account the national legal framework and institutional structure and applicable international conventions while providing for the allocation of responsibilities and resources, in addition to safety and security objectives and public information and participation in the decision making process. The strategy reflects and elaborates the goals and requirements set

The effectiveness of electro-remediation of aged, metal-contaminated sediment in relation to sequential extraction of metals

NARCIS (Netherlands)

Merkx, O.K.; Loch, J.P.G.; Lima, A.T.; Dijk, J.A.; Kreuk, J.F. de; Kleingeld, P.J.

2013-01-01

Soil pollution is a universal environmental issue, and the clean-up of contaminated soils can be costly and time consuming. Traditional methods often do not provide an effective solution when it comes to fine-grained and highly impermeable soils and/or immobile contaminants. Electro-remediation,

Fuel vapor pressure (FVAPRS)

International Nuclear Information System (INIS)

Mason, R.E.

1979-04-01

A subcode (FVAPRS) is described which calculates fuel vapor pressure. This subcode was developed as part of the fuel rod behavior modeling task performed at EG and G Idaho, Inc. The fuel vapor pressure subcode (FVAPRS), is presented and a discussion of literature data, steady state and transient fuel vapor pressure equations and estimates of the standard error of estimate to be expected with the FVAPRS subcode are included

Nuclear facility decommissioning and site remedial actions

International Nuclear Information System (INIS)

Knox, N.P.; Webb, J.R.; Ferguson, S.D.; Goins, L.F.; Owen, P.T.

1990-09-01

The 394 abstracted references on environmental restoration, nuclear facility decommissioning, uranium mill tailings management, and site remedial actions constitute the eleventh in a series of reports prepared annually for the US Department of Energy's Remedial Action Programs. Citations to foreign and domestic literature of all types -- technical reports, progress reports, journal articles, symposia proceedings, theses, books, patents, legislation, and research project descriptions -- have been included. The bibliography contains scientific, technical, economic, regulatory, and legal information pertinent to the US Department of Energy's Remedial Action Programs. Major sections are (1) Surplus Facilities Management Program, (2) Nuclear Facilities Decommissioning, (3) Formerly Utilized Sites Remedial Action Programs, (4) Facilities Contaminated with Naturally Occurring Radionuclides, (5) Uranium Mill Tailings Remedial Action Program, (6) Grand Junction Remedial Action Program, (7) Uranium Mill Tailings Management, (8) Technical Measurements Center, (9) Remedial Action Program, and (10) Environmental Restoration Program. Within these categories, references are arranged alphabetically by first author. Those references having no individual author are listed by corporate affiliation or by publication title. Indexes are provided for author, corporate affiliation, title word, publication description, geographic location, subject category, and keywords. This report is a product of the Remedial Action Program Information Center (RAPIC), which selects and analyzes information on remedial actions and relevant radioactive waste management technologies

Nuclear facility decommissioning and site remedial actions

Energy Technology Data Exchange (ETDEWEB)

Knox, N.P.; Webb, J.R.; Ferguson, S.D.; Goins, L.F.; Owen, P.T.

1990-09-01

The 394 abstracted references on environmental restoration, nuclear facility decommissioning, uranium mill tailings management, and site remedial actions constitute the eleventh in a series of reports prepared annually for the US Department of Energy's Remedial Action Programs. Citations to foreign and domestic literature of all types -- technical reports, progress reports, journal articles, symposia proceedings, theses, books, patents, legislation, and research project descriptions -- have been included. The bibliography contains scientific, technical, economic, regulatory, and legal information pertinent to the US Department of Energy's Remedial Action Programs. Major sections are (1) Surplus Facilities Management Program, (2) Nuclear Facilities Decommissioning, (3) Formerly Utilized Sites Remedial Action Programs, (4) Facilities Contaminated with Naturally Occurring Radionuclides, (5) Uranium Mill Tailings Remedial Action Program, (6) Grand Junction Remedial Action Program, (7) Uranium Mill Tailings Management, (8) Technical Measurements Center, (9) Remedial Action Program, and (10) Environmental Restoration Program. Within these categories, references are arranged alphabetically by first author. Those references having no individual author are listed by corporate affiliation or by publication title. Indexes are provided for author, corporate affiliation, title word, publication description, geographic location, subject category, and keywords. This report is a product of the Remedial Action Program Information Center (RAPIC), which selects and analyzes information on remedial actions and relevant radioactive waste management technologies.

Lessons Learned from Environmental Remediation Programmes

Energy Technology Data Exchange (ETDEWEB)

NONE

2014-03-15

Several remediation projects have been developed to date, and experience with these projects has been accumulated. Lessons learned span from non-technical to technical aspects, and need to be shared with those who are beginning or are facing the challenge to implement environmental remediation works. This publication reviews some of these lessons. The key role of policy and strategies at the national level in framing the conditions in which remediation projects are to be developed and decisions made is emphasized. Following policy matters, this publication pays attention to the importance of social aspects and the requirement for fairness in decisions to be made, something that can only be achieved with the involvement of a broad range of interested parties in the decision making process. The publication also reviews the funding of remediation projects, planning, contracting, cost estimates and procurement, and issues related to long term stewardship. Lessons learned regarding technical aspects of remediation projects are reviewed. Techniques such as the application of cover systems and soil remediation (electrokinetics, phytoremediation, soil flushing, and solidification and stabilization techniques) are analysed with respect to performance and cost. After discussing soil remediation, the publication covers issues associated with water treatment, where techniques such as ‘pump and treat’ and the application of permeable barriers are reviewed. Subsequently, there is a section dedicated to reviewing briefly the lessons learned in the remediation of uranium mining and processing sites. Many of these sites throughout the world have become orphaned, and are waiting for remediation. The publication notes that little progress has been made in the management of some of these sites, particularly in the understanding of associated environmental and health risks, and the ability to apply prediction to future environmental and health standards. The publication concludes

Lessons Learned from Environmental Remediation Programmes

International Nuclear Information System (INIS)

2014-01-01

Several remediation projects have been developed to date, and experience with these projects has been accumulated. Lessons learned span from non-technical to technical aspects, and need to be shared with those who are beginning or are facing the challenge to implement environmental remediation works. This publication reviews some of these lessons. The key role of policy and strategies at the national level in framing the conditions in which remediation projects are to be developed and decisions made is emphasized. Following policy matters, this publication pays attention to the importance of social aspects and the requirement for fairness in decisions to be made, something that can only be achieved with the involvement of a broad range of interested parties in the decision making process. The publication also reviews the funding of remediation projects, planning, contracting, cost estimates and procurement, and issues related to long term stewardship. Lessons learned regarding technical aspects of remediation projects are reviewed. Techniques such as the application of cover systems and soil remediation (electrokinetics, phytoremediation, soil flushing, and solidification and stabilization techniques) are analysed with respect to performance and cost. After discussing soil remediation, the publication covers issues associated with water treatment, where techniques such as ‘pump and treat’ and the application of permeable barriers are reviewed. Subsequently, there is a section dedicated to reviewing briefly the lessons learned in the remediation of uranium mining and processing sites. Many of these sites throughout the world have become orphaned, and are waiting for remediation. The publication notes that little progress has been made in the management of some of these sites, particularly in the understanding of associated environmental and health risks, and the ability to apply prediction to future environmental and health standards. The publication concludes

Feasibility study concerning remediation and rehabilitation of industrial polluted lands on the Absheron Peninsula, Republic of Azerbaijan

Science.gov (United States)

Pivin, Majorie; Helsen, Stefan; Cuyvers, Lars

2014-05-01

ECOREM is carrying out a feasibility study focused on the remediation and rehabilitation of industrial polluted lands, located on the Absheron Peninsula (Republic of Azerbaijan), on behalf of the State Oil Company of Azerbaijan Republic (SOCAR). The objective of this study is to support SOCAR with specific technologies and capacity building for environmental remediation works on various sectors of the Peninsula. As an independent consultancy company, ECOREM provides sustainable and quality advice, seeking the balance to the interests of the client and the environment in the broadest sense of the word. Within this study, it is important to underline that extraction activities in the country have been going on for more than a century. Given that the age of the environmental problems is equal to the history of the oil production, it is nearly impossible to point out the responsibilities of the various companies or to define the exact activities that occurred on a particular location. From the data gathered so far, more than 3600 ha of oil contaminated area are known in Baku and the Absheron Peninsula. Within this feasibility study, ECOREM will advice SOCAR on suitable and best available remediation technologies to apply on prior contaminated areas. According to the Environmental Policy of the Company, SOCAR would like to act in priority on the numerous contaminated lands of the Absheron Peninsula. Through the exploitation of the extensive GIS database provided by SOCAR, the oil contaminated sites will be examined in details in order to determine the most sensitive areas, on which remediation works or monitoring should be implemented in priority. To locate these sites, ECOREM will provide SOCAR with technical support in order to conduct risk analysis, remediation and monitoring of soil and/or groundwater oil pollutions. According to these results, practical solutions will be proposed concerning the possible reuse and management of contaminated soils and hazardous

Approaches for assessing sustainable remediation

DEFF Research Database (Denmark)

Søndergaard, Gitte Lemming; Binning, Philip John; Bjerg, Poul Løgstrup

Sustainable remediation seeks to reduce direct contaminant point source impacts on the environment, while minimizing the indirect cost of remediation to the environment, society and economy. This paper presents an overview of available approaches for assessing the sustainability of alternative...... remediation strategies for a contaminated site. Most approaches use multi-criteria assessment methods (MCA) to structure a decision support process. Different combinations of environmental, social and economic criteria are employed, and are assessed either in qualitative or quantitative forms with various...... tools such as life cycle assessment and cost benefit analysis. Stakeholder involvement, which is a key component of sustainable remediation, is conducted in various ways. Some approaches involve stakeholders directly in the evaluation or weighting of criteria, whereas other approaches only indirectly...

Cavitational hydrothermal oxidation: A new remediation process. Annual progress report, September 1996 - August 1997

International Nuclear Information System (INIS)

Suslick, K.S.

1997-01-01

'During the past year, the authors have continued to make substantial scientific progress on the understanding of cavitation phenomena in aqueous media and applications of cavitation to remediation processes. The efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions. In order to gain further understanding of the conditions present during cavitation, the author has continued his studies of sonoluminescence. He has made recent breakthroughs in the use of emission spectroscopy for temperature and pressure measurement of cavitation events, which he expects to publish shortly. He has been able to measure for the first time the temperature of cavitation in water during multi-bubble cavitation in the presence of aromatic hydrocarbons. The emission from excited states of C 2 in water gives temperatures that are consistent with adiabatic compressional heating, with maximum temperatures of 4,300 K. Prior measurements of cavitation temperatures in low vapor pressure nonaqueous media gave somewhat higher temperatures of 5,000 K. This work lays permanently to rest exotic mechanisms for cavitational chemistry, at least for cavitation fields.'

Concepts for immobilized extractants

International Nuclear Information System (INIS)

Paine, R.T.

1993-01-01

This paper addresses the problem of cleaning actinides from geomedia. In the past actinides were often released to the ground because of their tendency to bind tightly to forms of geomedia, and in addition spills have occurred over time. To remediate these areas involves finding ways to either guarantee the retention of the actinides in the geomedia, or finding ways to extract them and leave the soils clean. One possible way to clean soils is to wash them, which in order to extract actinides means the use of ligands which bind competitively with actinides in the presence of soil fractions. An array of organic ligands is known which bind with actinides, but the larger problem of handling these ligands in a manner which allows concentration of the actinides is still open. The author addresses work to bind such ligands to different types of matrices which can then be used in packed extraction columns to remove actindes from flow streams, and finally concentrated, by using minimal volume backflushing to extract the actinides from the column

Effect of Remediation Parameters on in-Air Ambient Dose Equivalent Rates When Remediating Open Sites with Radiocesium-contaminated Soil.

Science.gov (United States)

Malins, Alex; Kurikami, Hiroshi; Kitamura, Akihiro; Machida, Masahiko

2016-10-01

Calculations are reported for ambient dose equivalent rates [H˙*(10)] at 1 m height above the ground surface before and after remediating radiocesium-contaminated soil at wide and open sites. The results establish how the change in H˙*(10) upon remediation depends on the initial depth distribution of radiocesium within the ground, on the size of the remediated area, and on the mass per unit area of remediated soil. The remediation strategies considered were topsoil removal (with and without recovering with a clean soil layer), interchanging a topsoil layer with a subsoil layer, and in situ mixing of the topsoil. The results show the ratio of the radiocesium components of H˙*(10) post-remediation relative to their initial values (residual dose factors). It is possible to use the residual dose factors to gauge absolute changes in H˙*(10) upon remediation. The dependency of the residual dose factors on the number of years elapsed after fallout deposition is analyzed when remediation parameters remain fixed and radiocesium undergoes typical downward migration within the soil column.

Transformation of zinc-concentrate in surface and subsurface environments: Implications for assessing zinc mobility/toxicity and choosing an optimal remediation strategy.

Science.gov (United States)

Kwon, Man Jae; Boyanov, Maxim I; Yang, Jung-Seok; Lee, Seunghak; Hwang, Yun Ho; Lee, Ju Yeon; Mishra, Bhoopesh; Kemner, Kenneth M

2017-07-01

Zinc contamination in near- and sub-surface environments is a serious threat to many ecosystems and to public health. Sufficient understanding of Zn speciation and transport mechanisms is therefore critical to evaluating its risk to the environment and to developing remediation strategies. The geochemical and mineralogical characteristics of contaminated soils in the vicinity of a Zn ore transportation route were thoroughly investigated using a variety of analytical techniques (sequential extraction, XRF, XRD, SEM, and XAFS). Imported Zn-concentrate (ZnS) was deposited in a receiving facility and dispersed over time to the surrounding roadside areas and rice-paddy soils. Subsequent physical and chemical weathering resulted in dispersal into the subsurface. The species identified in the contaminated areas included Zn-sulfide, Zn-carbonate, other O-coordinated Zn-minerals, and Zn species bound to Fe/Mn oxides or clays, as confirmed by XAFS spectroscopy and sequential extraction. The observed transformation from S-coordinated Zn to O-coordinated Zn associated with minerals suggests that this contaminant can change into more soluble and labile forms as a result of weathering. For the purpose of developing a soil washing remediation process, the contaminated samples were extracted with dilute acids. The extraction efficiency increased with the increase of O-coordinated Zn relative to S-coordinated Zn in the sediment. This study demonstrates that improved understanding of Zn speciation in contaminated soils is essential for well-informed decision making regarding metal mobility and toxicity, as well as for choosing an appropriate remediation strategy using soil washing. Copyright © 2017 Elsevier Ltd. All rights reserved.

In situ remediation and phytotoxicity assessment of lead-contaminated soil by biochar-supported nHAP.

Science.gov (United States)

Yang, Zhangmei; Fang, Zhanqiang; Tsang, Pokeung Eric; Fang, Jianzhang; Zhao, Dongye

2016-11-01

In this study, a kind of biochar-supported nano-hydroxyapatite (nHAP@BC) material was used in in-situ remediation of lead-contaminated soil. Column experiments were performed to compare the mobility of nHAP@BC and Bare-nHAP. The immobilization, accumulation and toxic effects of Pb in the after-amended soil were assessed by the in vitro toxicity tests and pot experiments. The column experiments showed a significant improvement in the mobility of nHAP@BC. The immobilization rate of Pb in the soil was 74.8% after nHAP@BC remediation. Sequential extraction procedures revealed that the residual fraction of Pb increased by 66.6% after nHAP@BC remediation, which greatly reduced the bioavailability of Pb in the soil. In addition, pot experiments indicated that nHAP@BC could effectively reduce the upward translocation capacity of Pb in a soil-plant system. The concentration of Pb in the aerial part of the cabbage mustard was 0.1 mg/kg, which is lower than the tolerance limit (0.3 mg/kg). nHAP@BC can remediate Pb-contaminated soil effectively, which can restore soil quality for planting. Copyright © 2016 Elsevier Ltd. All rights reserved.

Herbal remedies and supplements for weight loss

Science.gov (United States)

Weight loss - herbal remedies and supplements; Obesity - herbal remedies; Overweight - herbal remedies ... health care provider. Nearly all over-the-counter supplements with claims of weight-loss properties contain some ...

Selected remedy at the Queen City Farms superfund site: A risk management approach

International Nuclear Information System (INIS)

Weber, E.F.; Wilson, J.; Kirk, M.; Tochko, S.

1994-01-01

A risk management approach at a former industrial waste disposal site in western Washington resulted in a selected remedy that is cost-effective and that meets the CERCLA threshold criterion of protecting human health and the environment. The proposed remedy, which addresses contamination in soil and groundwater, does not require an ARARs waiver and received state and community acceptance. By analyzing the current and potential risk at the site, a proposed remedy was chosen that would control the source and naturally attenuate the groundwater plume. Source control will include removal and treatment of some light nonaqueous phase liquid (LNAPL) and some soil, followed by isolation of the remaining soil and LNAPL within a slurry wall and beneath a multilayer cap. A contingent groundwater extraction and treatment system was included to address uncertainty in the risk characterization. Implementing source control is predicted to result in a steady decline in volatile organic compound levels in the drinking water aquifer through adsorption, degradation, and dispersion. Exposure to groundwater during the period of natural attenuation will be controlled by monitoring, institutional controls, and a thorough characterization of the plume and receptors. 7 figs., 1 tab

Optimization of a single-drop microextraction method for multielemental determination by electrothermal vaporization inductively coupled plasma mass spectrometry following in situ vapor generation

International Nuclear Information System (INIS)

Gil, Sandra; Loos-Vollebregt, Margaretha T.C. de; Bendicho, Carlos

2009-01-01

A headspace single-drop microextraction (HS-SDME) method has been developed in combination with electrothermal vaporization inductively coupled plasma mass spectrometry (ETV-ICP-MS) for the simultaneous determination of As, Sb, Bi, Pb, Sn and Hg in aqueous solutions. Vapor generation is carried out in a 40 mL volume closed-vial containing a solution with the target analytes in hydrochloric acid and potassium ferricyanide medium. Hydrides (As, Sb, Bi, Pb, Sn) and Hg vapor are trapped onto an aqueous single drop (3 μL volume) containing Pd(II), followed by the subsequent injection in the ETV. Experimental variables such as medium composition, sodium tetrahydroborate (III) volume and concentration, stirring rate, extraction time, sample volume, ascorbic acid concentration and palladium amount in the drop were fully optimized. The limits of detection (LOD) (3σ criterion) of the proposed method for As, Sb, Bi, Pb, Sn and Hg were 0.2, 0.04, 0.01, 0.07, 0.09 and 0.8 μg/L, respectively. Enrichment factors of 9, 85, 138, 130, 37 and 72 for As, Sb, Bi, Pb, Sn and Hg, respectively, were achieved in 210 s. The relative standard deviations (N = 5) ranged from 4 to 8%. The proposed HS-SDME-ETV-ICP-MS method has been applied for the determination of As, Sb, Bi, Pb, Sn and Hg in NWRI TM-28.3 certified reference material.

Remediation of electronic waste polluted soil using a combination of persulfate oxidation and chemical washing.

Science.gov (United States)

Chen, Fu; Luo, Zhanbin; Liu, Gangjun; Yang, Yongjun; Zhang, Shaoliang; Ma, Jing

2017-12-15

Laboratory experiments were conducted to investigate the efficiency of a simultaneous chemical extraction and oxidation for removing persistent organic pollutants (POPs) and toxic metals from an actual soil polluted by the recycling activity of electronic waste. Various chemicals, including hydroxypropyl-β-cyclodextrin (HPCD), citric acid (CA) and sodium persulfate (SP) were applied synchronously with Fe 2+ activated oxidation to enhance the co-removal of both types of pollutants. It is found that the addition of HPCD can enhance POPs removal through solubilization of POPs and iron chelation; while the CA-chelated Fe 2+ activation process is effective for extracting metals and degrading residual POPs. Under the optimized reagent conditions, 69.4% Cu, 78.1% Pb, 74.6% Ni, 97.1% polychlorinated biphenyls, 93.8% polycyclic aromatic hydrocarbons, and 96.4% polybrominated diphenylethers were removed after the sequential application of SP-HPCD-Fe 2+ and SP-CA-Fe 2+ processes with a duration of 180 and 240 min, respectively. A high dehalogenation efficiency (84.8% bromine and 86.2% chlorine) is observed, suggesting the low accumulation of halogen-containing organic intermediates. The remediated soil can satisfy the national soil quality standard of China. Collectively, co-contaminated soil can be remediated with reasonable time and capital costs through simultaneous application of persulfate oxidation and chemical extraction. Copyright © 2017 Elsevier Ltd. All rights reserved.

New Mexico English Remediation Taskforce Report

Science.gov (United States)

New Mexico Higher Education Department, 2016

2016-01-01

In March, 2016, the state of New Mexico established a Remediation Task Force to examine remediation reform efforts across the state's higher education institutions. On March 11, the Task Force met for the "New Mexico Corequisite Remediation at Scale Policy Institute" in order to learn about the results of the latest national reform…

Remediation: Higher Education's Bridge to Nowhere

Science.gov (United States)

Complete College America, 2012

2012-01-01

The intentions were noble. It was hoped that remediation programs would be an academic bridge from poor high school preparation to college readiness. Sadly, remediation has become instead higher education's "Bridge to Nowhere." This broken remedial bridge is travelled by some 1.7 million beginning students each year, most of whom will…

Effects of initial nitrogen addition on deep-soils bioventing at a fuel-contaminated site

International Nuclear Information System (INIS)

Ratz, J.W.; Guest, P.R.; Downey, D.C.

1994-01-01

A ruptured pipe at a Burlington Northern Railroad (BNRR) fueling pump house resulted in over 60,000 gallons of No. 2 diesel fuel spilling onto the surrounding soil. An initial investigation of site conditions indicated that subsurface soils were contaminated with diesel fuel to ground water, which was observed approximately 70 feet below the ground surface. State regulatory agencies requested that BNRR develop and implement a remedial action plan to treat these diesel-contaminated soils and protect local ground waters. Engineering-Science, Inc. (ES) was retained for this work and, after evaluating a variety of remediation technologies recommended using soil venting methods to enhance the immediate volatilization and long-term biodegradation of fuel residuals. ES designed and implemented a ''bioventing'' pilot test to determine soil properties such as air permeability, and to assess the potential for partial volatilization and long-term biodegradation of diesel fuel residuals at the site. Hydrocarbon concentrations, carbon dioxide, and oxygen levels were monitored at a vapor extraction well (VEW) and six vapor monitoring points (VMPs) to determine the rates of volatilization and biological degradation of fuel residuals. Pilot test results confirmed that full-scale bioventing was feasible for the remediation of this site

Vapor generation methods for explosives detection research

Energy Technology Data Exchange (ETDEWEB)

Grate, Jay W.; Ewing, Robert G.; Atkinson, David A.

2012-12-01

The generation of calibrated vapor samples of explosives compounds remains a challenge due to the low vapor pressures of the explosives, adsorption of explosives on container and tubing walls, and the requirement to manage (typically) multiple temperature zones as the vapor is generated, diluted, and delivered. Methods that have been described to generate vapors can be classified as continuous or pulsed flow vapor generators. Vapor sources for continuous flow generators are typically explosives compounds supported on a solid support, or compounds contained in a permeation or diffusion device. Sources are held at elevated isothermal temperatures. Similar sources can be used for pulsed vapor generators; however, pulsed systems may also use injection of solutions onto heated surfaces with generation of both solvent and explosives vapors, transient peaks from a gas chromatograph, or vapors generated by s programmed thermal desorption. This article reviews vapor generator approaches with emphasis on the method of generating the vapors and on practical aspects of vapor dilution and handling. In addition, a gas chromatographic system with two ovens that is configurable with up to four heating ropes is proposed that could serve as a single integrated platform for explosives vapor generation and device testing. Issues related to standards, calibration, and safety are also discussed.

Remediation of heavy-metal-contaminated soil using chelant extraction: Feasibility studies

Energy Technology Data Exchange (ETDEWEB)

Peters, R.W.; Miller, G.; Taylor, J.D.; Schneider, J.F.; Zellmer, S.; Edgar, D.E.; Johnson, D.O.

1993-08-01

Results are presented of a laboratory investigation conducted to determine the efficacy of using chelating agents to extract heavy metals (Pb, Cd, Cr, Ba, Cu, and Zn) from soil, the primary focus being on the extraction of lead from the soil. Results from the batch-shaker studies and emphasizes the columnar extraction studies are described. The chelating agents studied included ethylenediaminetetraacetic acid (EDTA) and citric acid, in addition to water. Concentrations of the chelants ranged from 0.01 to 0.05 M; the suspension pH was varied between 3 and 8. Results showed that the removal of lead using citric acid and water was somewhat pH-dependent. For the batch-shaker studies, the results indicated that EDTA was more effective at removing Cd, Cu, Pb, and Zn than was citric acid (both present at 0.01 M). EDTA and citric acid were equally effective in mobilizing Cr and Ba from the soil. Heavy metals removal was slightly more effective in the more acidic region (pH {le} 5).

Integrated remediation of soil and groundwater

International Nuclear Information System (INIS)

Dykes, R.S.; Howles, A.C.

1992-01-01

Remediation of sites contaminated with petroleum hydrocarbons and other organic chemicals frequently focuses on a single phase of the chemical in question. This paper describes an integrated approach to remediation involving selection of complimentary technologies designed to create a remedial system which achieves cleanup goals in affected media in the shortest possible time consistent with overall environmental protection

Development of an integrated, in-situ remediation technology. Topical report for task No. 9. Part I. TCE degradation using nonbiological methods, September 26, 1994--May 25, 1996

International Nuclear Information System (INIS)

Shapiro, A.P.; Sivavec, T.M.; Baghel, S.S.

1997-01-01

Contamination in low-permeability soils poses a significant technical challenge for in situ remediation efforts. Poor accessibility to the contaminants and difficulty in delivery of treatment reagents have rendered existing in situ treatments such as bioremediation, vapor extraction, pump and treat rather ineffective when applied to low-permeability soils present at many contaminated sites. The technology is an integrated in situ treatment in which established geotechnical methods are used to install degradation zones directly in the contaminated soil and electro-osmosis is used to move the contaminants back and forth through those zones until the treatment is completed. The present Draft Topical Report for Task No. 9 summarizes laboratory investigations into TCE degradation using nonbiological methods. These studies were conducted by the General Electric Company. The report concentrates on zero valent iron as the reducing agent and presents data on TCE and daughter product degradation rates in batch experiments, column studies, and electroosmotic cells. It is shown that zero valent iron effectively degrades TCE in electroosmotic experiments. Daughter product degradation and gas generation are shown to be important factors in designing field scale treatment zones for the Lasagna trademark process

Uranium mill tailings remediation in the USA. A history and lessons learned - 59407

International Nuclear Information System (INIS)

Rima, Steve

2012-01-01

Document available in abstract form only. Full text of publication follows: Since the 1940's uranium ores have been processed at various locations in the United States to extract and produce uranium and other concentrated materials, first for government (weapons) research and production, and then for nuclear power production. The tailings residue from the uranium milling process contained radioactive (primarily Ra-226) and hazardous chemicals. Large volumes of tailings were produced during the milling process. In the early history of this process the tailings were not recognized as hazardous and were released to the general public for a wide variety of uses, resulting in significant spread of contamination in the vicinity of many operating mills. In the late 1960's and early 1970's laws were enacted at the state and federal level to begin to deal with the legacy of this contamination. Over the course of the next several decades various regulatory agencies were responsible for remediating these sites. Different approaches were used, different end points and definitions of clean were used, and very large sums of public funding were spent on remediating these sites. Rarely was the cost commensurate with the risk reduction obtained through remediation. This paper will present an overview of the history of the uranium mill tailings regulatory and remediation program in the United States, the cost of the program compared to risk reduction, successes and failures, and important lessons learned that should be applied to future efforts in this area. (author)

The vaporization enthalpy and vapor pressure of S (+)-methamphetamine at T = 298.15 K by correlation gas chromatography

International Nuclear Information System (INIS)

Thornton, Melissa; Gobble, Chase; Chickos, James

2014-01-01

Highlights: • The vaporization enthalpy of (d)-methamphetamine was measured. • The vapor pressure of (d)-methamphetamine as a function of temperature was evaluated. • The vapor pressure of 4-benzylpiperidine as a function of temperature was evaluated. - Abstract: The vaporization enthalpy and vapor pressure of S (+)-methamphetamine is evaluated by correlation-gas chromatography. A vaporization enthalpy of (58.7 ± 4.3) kJ · mol −1 and a vapor pressure, p = (38 ± 9) Pa has been obtained using a variety of secondary aliphatic amines as standards. In addition, equations describing the vapor pressure temperature dependence are provided for standards and S (+)-methamphetamine covering the temperature range from T = 298.15 K to the boiling temperature. Boiling temperatures are reproduced within an interval of 8 K or less

Low Potency Homeopathic Remedies and Allopathic Herbal Medicines: Is There an Overlap?

Science.gov (United States)

Csupor, Dezső; Boros, Klára; Hohmann, Judit

2013-01-01

Classical homeopathy is based on the therapeutic application of highly diluted homeopathic stocks. The indications of such medicines are determined by proving, i.e. by applying the remedies in healthy subjects. However, there are several complex homeopathic medicinal products on the market with approved therapeutic indications. The efficacy of these medicines has been assessed in clinical trials on patients. There is no upper limit of dosing for such homeopathic remedies, and these products often contain undiluted mother tincture. The aim of our study was to compare an allopathic herbal medicine and a homeopathic product containing undiluted mother tincture based on the same plant. Two products (an allopathic herbal medicine and a homeopathic product) containing Vitex agnus-castus extract were analyzed by HPLC-DAD for their agnuside and casticin contents. The agnuside content of the allopathic product was approximately four times higher, while the amount of casticin was in the same order of magnitude. Our experiments revealed the presence of active ingredients in allopathic quantity in a homeopathic preparation, highlighting the controversy between the principles of classical and practice of contemporary homeopathy. According to the principles of classical homeopathy these remedies cannot be considered as homeopathic remedies but rather as (allopathic) herbal ones. This phenomenon necessitates a case-by-case approach towards the possible adverse effects and drug interactions of homeopathics in the daily medical practice. Homeopathic products containing active agents in allopathic doses should be treated the same way as allopathic medicines from the point of view of quality assurance and pharmacovigilance. PMID:24019954

Low potency homeopathic remedies and allopathic herbal medicines: is there an overlap?

Directory of Open Access Journals (Sweden)

Dezső Csupor

Full Text Available Classical homeopathy is based on the therapeutic application of highly diluted homeopathic stocks. The indications of such medicines are determined by proving, i.e. by applying the remedies in healthy subjects. However, there are several complex homeopathic medicinal products on the market with approved therapeutic indications. The efficacy of these medicines has been assessed in clinical trials on patients. There is no upper limit of dosing for such homeopathic remedies, and these products often contain undiluted mother tincture. The aim of our study was to compare an allopathic herbal medicine and a homeopathic product containing undiluted mother tincture based on the same plant. Two products (an allopathic herbal medicine and a homeopathic product containing Vitex agnus-castus extract were analyzed by HPLC-DAD for their agnuside and casticin contents. The agnuside content of the allopathic product was approximately four times higher, while the amount of casticin was in the same order of magnitude. Our experiments revealed the presence of active ingredients in allopathic quantity in a homeopathic preparation, highlighting the controversy between the principles of classical and practice of contemporary homeopathy. According to the principles of classical homeopathy these remedies cannot be considered as homeopathic remedies but rather as (allopathic herbal ones. This phenomenon necessitates a case-by-case approach towards the possible adverse effects and drug interactions of homeopathics in the daily medical practice. Homeopathic products containing active agents in allopathic doses should be treated the same way as allopathic medicines from the point of view of quality assurance and pharmacovigilance.

Remediation mechanisms of mercapto-grafted palygorskite for cadmium pollutant in paddy soil.

Science.gov (United States)

Liang, Xuefeng; Qin, Xu; Huang, Qingqing; Huang, Rong; Yin, Xiuling; Cai, Yanming; Wang, Lin; Sun, Yuebing; Xu, Yingming

2017-10-01

The immobilization agent was the key factor that determined the success of remediation of heavy metal polluted soil. In this study, mercapto-grafted palygorskite (MP) as a novel and efficient immobilization agent was utilized for the remediation of Cd-polluted paddy soil in pot trials, and the remediation mechanisms were investigated in the aspect of soil chemistry and plant physiology with different rice cultivars as model plants. Mercapto-grafted palygorskite at applied doses of 0.1-0.3% could reduce Cd contents of brown rice and straws of different cultivars significantly. Both reduced DTPA-extractable Cd contents in rhizosphere and non-rhizosphere soil and decreasing Cd contents in iron plaques on rice root surfaces confirmed that MP was an efficient immobilization agent for Cd pollutant in paddy soil. In the aspect of soil chemistry, the pH values of rhizosphere and non-rhizosphere soils had no statistical changes in the MP treatment groups, but their zeta potentials decreased obviously, indicating that MP could enhance the fixation or sorption of Cd on soil compositions. In the aspect of antioxidant system, MP could increase POD activity of rice roots significantly to alleviate the stress of Cd to roots, and resulted in the decrease of T-AOC, SOD, and CAT activities of rice roots of the selected cultivars. MP had no inhabitation or enhancement effects on TSH of rice roots but enhance the contents of MTs and NPT to binding Cd to complete detoxification process. MP as a novel and efficient immobilization agent could complete the remediation effects through soil chemistry and plant physiological mechanisms.

Observation and particle simulation of vaporized W, Mo, and Be in PISCES-B plasma for vapor-shielding studies

Directory of Open Access Journals (Sweden)

K. Ibano

2017-08-01

Full Text Available Interactions of Tungsten (W, Molybdenum (Mo, and Beryllium (Be vapors with a steady-state plasma were studied by the PISCES-B liner plasma experiments as well as Particle-In-Cell (PIC simulations for the understanding of vapor-shielding phenomena. Effective cooling of the plasma by laser-generated Be vapor was observed in PISCES-B. On the other hand, no apparent cooling was observed for W and Mo vapors. The PIC simulation explains these experimental observations of the difference between low-Z and high-Z vapors. Decrease of electron temperature due to the vapor ejection was observed in case of a simulation of the Be vapor. As for the W vapor, it was found that the plasma cooling is localized only near the wall at a higher electron density plasma (∼1019m−3. On the other hand, the appreciable plasma cooling can be observed in a lower density plasma (∼1018m−3 for the W vapor.

(Bio-)remediation of VCHC contaminants in a Technosol under unsaturated conditions.

Science.gov (United States)

Baumgarten, W; Fleige, H; Peth, S; Horn, R

2013-07-01

The remediation of dense non-aqueous phase liquids has always been a concern of both public and scientific interest groups. In this research work a modified physical concept of (bio)remediation of a volatile chlorinated hydrocarbon (VCHC) contamination was elaborated under laboratory conditions and modeled with HYDRUS-2D. In field dechlorination is influenced by both physicochemical and hydraulic properties of the substrate, e.g. texture, pore size distribution, pore liquid characteristics, e.g. viscosity, pH, surface tension, and dependent on the degree of saturation of the vadose zone. Undisturbed soil cores (100 cm³) were sampled from a Spolic Technosol. Considering hydraulic properties and functions, unsaturated percolation was performed with vertically and horizontally structured samples. VCHC concentrations were calculated prior, during, and after each percolation cycle. According to laboratory findings, microemulsion showed the most efficient results with regard to flow behavior in the unsaturated porous media and its accessibility for bacteria as nutrient. The efficiency of VCHC remediation could be increased by the application of a modified pump-and-treat system: the injection of bacteria Dehalococcoides ethanogenes with microemulsion, and extraction at a constant matric potential level of -6 kPa. Achieved data was used for HYDRUS-2D simulations, modeling in situ conditions, demonstrating the practical relevance (field scale) of performed unsaturated percolation (core scale), and in order to exclude capillary barrier effects.

Award of merit: transportable remediation unit -Jacques Whitford Environment Limited -Toronto

International Nuclear Information System (INIS)

Anon.

1995-01-01

A unique hybrid of remediation technologies was designed to deal with the problem of removing the gasoline and fuel-oil found in soils and groundwater as a result of spills or leakage at petroleum storage and dispensing facilities. Liquid petroleum hydrocarbons were found discharging into a creek in a residential and commercial neighborhood of Metropolitan Toronto. Numerous in-place soil and ground water remediation approaches were evaluated in the course of searching for a solution. A full-scale, transportable, in-situ bioslurping remediation unit was recommended. The unit was connected to 13 specially designed vertical bioslurping wells, and to a buried horizontal header network comprised of four separate zones that could be used to simultaneously extract and/or inject air and water flows. Cycling of various modes of operation was based on detailed monitoring and analysis, which allowed for optimal recovery and biological degradation of contaminants. After only four months of operation, over 4000 kg of petroleum hydrocarbon contaminants had been removed and treated, and all of the mobile liquid hydrocarbons at the water table had been removed. Treatment cost was estimated at $100 to $120 per tonne of contaminated soil, but assuming that the unit could be used at more than one site, the net treatment cost would decrease to $20 to $30 per tonne. 1 ill

French uranium mining sites remediation

International Nuclear Information System (INIS)

Roche, M.

2002-01-01

Following a presentation of the COGEMA's general policy for the remediation of uranium mining sites and the regulatory requirements, the current phases of site remediation operations are described. Specific operations for underground mines, open pits, milling facilities and confining the milled residues to meet long term public health concerns are detailed and discussed in relation to the communication strategies to show and explain the actions of COGEMA. A brief review of the current remediation situation at the various French facilities is finally presented. (author)

In situ bioremediation: Cost effectiveness of a remediation technology field tested at the Savannah River

International Nuclear Information System (INIS)

Saaty, R.P.; Showalter, W.E.; Booth, S.R.

1995-01-01

In Situ Bioremediation (ISBR) is an innovative new remediation technology for the removal of chlorinated solvents from contaminated soils and groundwater. The principal contaminant at the SRID is the volatile organic compound (VOC), tricloroetylene(TCE). A 384 day test run at Savannah River, sponsored by the US Department of Energy, Office of Technology Development (EM-50), furnished information about the performance and applications of ISBR. In Situ Bioremediation, as tested, is based on two distinct processes occurring simultaneously; the physical process of in situ air stripping and the biolgoical process of bioremediation. Both processes have the potential to remediate some amount of contamination. A quantity of VOCs, directly measured from the extracted air stream, was removed from the test area by the physical process of air stripping. The biological process is difficult to examine. However, the results of several tests performed at the SRID and independent numerical modeling determined that the biological process remediated an additional 40% above the physical process. Given this data, the cost effectiveness of this new technology can be evaluated

Optimal selection of biochars for remediating metals ...

Science.gov (United States)

Approximately 500,000 abandoned mines across the U.S. pose a considerable, pervasive risk to human health and the environment due to possible exposure to the residuals of heavy metal extraction. Historically, a variety of chemical and biological methods have been used to reduce the bioavailability of the metals at mine sites. Biochar with its potential to complex and immobilize heavy metals, is an emerging alternative for reducing bioavailability. Furthermore, biochar has been reported to improve soil conditions for plant growth and can be used for promoting the establishment of a soil-stabilizing native plant community to reduce offsite movement of metal-laden waste materials. Because biochar properties depend upon feedstock selection, pyrolysis production conditions, and activation procedures used, they can be designed to meet specific remediation needs. As a result biochar with specific properties can be produced to correspond to specific soil remediation situations. However, techniques are needed to optimally match biochar characteristics with metals contaminated soils to effectively reduce metal bioavailability. Here we present experimental results used to develop a generalized method for evaluating the ability of biochar to reduce metals in mine spoil soil from an abandoned Cu and Zn mine. Thirty-eight biochars were produced from approximately 20 different feedstocks and produced via slow pyrolysis or gasification, and were allowed to react with a f

Radon remediation in irish schools

International Nuclear Information System (INIS)

Synnott, H.

2006-01-01

Full text: Commencing in 1998, the Radiological Protection Institute of Ireland carried out radon measurements in 3826 schools in the Republic of I reland on behalf of the Irish Department of Education and Science (D.E.S.). This represents approximately 97% of all schools in the country. Approximately 25% (984) schools had radon concentrations above the Irish national schools Reference Level for radon of 200 Bq/m 3 and required remedial work. The number of individual rooms with radon concentrations above 200 Bq/m 3 was 3020. Remedial work in schools commenced in early 2000. In general schools with maximum radon concentrations in the range 200 -400 Bq/m 3 in one or more rooms were remediated through the installation of passive systems such as an increase in permanent background ventilation mainly wall vents and trickle vents in windows. Schools with maximum radon concentrations greater than 400 Bq/m 3 were usually remediated through the provision of active systems mainly fan assisted sub -slab de pressurization or where this was not possible fan assisted under floor ventilation. The cost of the remedial programme was funded by central Government. Active systems were installed by specialized remedial contractors working to the specifications of a radon remedial expert appointed by the D.E.S. to design remedial systems for affected schools. Schools requiring increased ventilation were granted aided 190 pounds per affected room and had to organize the work themselves. In most schools radon remediation was successful in reducing existing radon concentrations to below the Reference Level. Average radon concentration reduction factors for sub-slab de pressurization systems and fan assisted fan assisted under floor ventilation ranged from 5 to 40 with greater reduction rates found at higher original radon concentrations. Increasing ventilation in locations with moderately elevated radon concentrations (200 - 400 Bq/m 3 ) while not as effective as active systems produced on

The benefits from environmental remediation

International Nuclear Information System (INIS)

Falck, W.E.

2002-01-01

Environmental remediation projects inevitably take place against a backdrop of overall social goals and values. These goals can include, for example, full employment, preservation of the cultural, economic and archaeological resources, traditional patterns of land use, spiritual values, quality of life factors, biological diversity, environmental and socio-economic sustainability, protection of public health. Different countries will have different priorities, linked to the overall set of societal goals and the availability of resources, including funding, man-power and skills. These issues are embedded within both a national and local socio-cultural context, and will shape the way in which the remediation process is structured in any one country. The context will shape both the overall objectives of a remediation activity within the framework of competing societal goals, as well as generate constraints on the decision making process. Hence, the overall benefit of a remediation project is determined by its overall efficiency and effectiveness within the given legal, institutional, and governance framework, under the prevailing socio-economic boundary conditions, and balancing technology performance and risk reduction with fixed or limited budgetary resources, and is not simply the result of the technical remediation operation itself. (author)

A heated vapor cell unit for dichroic atomic vapor laser lock in atomic rubidium.

Science.gov (United States)

McCarron, Daniel J; Hughes, Ifan G; Tierney, Patrick; Cornish, Simon L

2007-09-01

The design and performance of a compact heated vapor cell unit for realizing a dichroic atomic vapor laser lock (DAVLL) for the D(2) transitions in atomic rubidium is described. A 5 cm long vapor cell is placed in a double-solenoid arrangement to produce the required magnetic field; the heat from the solenoid is used to increase the vapor pressure and correspondingly the DAVLL signal. We have characterized experimentally the dependence of important features of the DAVLL signal on magnetic field and cell temperature. For the weaker transitions both the amplitude and gradient of the signal are increased by an order of magnitude.

A heated vapor cell unit for dichroic atomic vapor laser lock in atomic rubidium

International Nuclear Information System (INIS)

McCarron, Daniel J.; Hughes, Ifan G.; Tierney, Patrick; Cornish, Simon L.

2007-01-01

The design and performance of a compact heated vapor cell unit for realizing a dichroic atomic vapor laser lock (DAVLL) for the D 2 transitions in atomic rubidium is described. A 5 cm long vapor cell is placed in a double-solenoid arrangement to produce the required magnetic field; the heat from the solenoid is used to increase the vapor pressure and correspondingly the DAVLL signal. We have characterized experimentally the dependence of important features of the DAVLL signal on magnetic field and cell temperature. For the weaker transitions both the amplitude and gradient of the signal are increased by an order of magnitude

Solvent Vapor Annealing-Mediated Crystallization Directs Charge Generation, Recombination and Extraction in BHJ Solar Cells

KAUST Repository

Babics, Maxime; Liang, Ru-Ze; Wang, Kai; Cruciani, Federico; Kan, Zhipeng; Wohlfahrt, Markus; Tang, Ming-Chun; Laquai, Fré dé ric; Beaujuge, Pierre

2017-01-01

Small-molecule (SM) donors that can be solution-processed with fullerene acceptors (e.g., PC61/71BM), or their “nonfullerene” counterparts, are proving particularly promising for the realization of high-efficiency bulk-heterojunction (BHJ) solar cells. In several recent studies, solvent vapor annealing (SVA) protocols have been found to yield significant BHJ device efficiency improvements via structural changes in the active layer morphologies. However, the mechanisms by which active layer morphologies evolve when subjected to SVA treatments, and the structural factors impacting charge generation, carrier transport, recombination and extraction in BHJ solar cells with SM donors and fullerene acceptors, remain important aspects to be elucidated. In this report, we show that – in BHJ solar cells with SM donors and fullerene acceptors – selective crystallization promoted by SVA mediates the development of optimized morphologies across the active layers, setting domain sizes and boundaries. Examining BHJ solar cells subjected to various SVA exposure times, with BDT[2F]QdC as the SM donor and PC71BM as the acceptor, we connect those morphological changes to specific carrier effects, showing that crystal growth effectively directs charge generation and recombination. We find that the SM donor-pure domains growing at the expense of a mixed donor-acceptor phase play a determining role, establishing optimum networks with 10-20nm-sized domains during the SVA treatment. Longer SVA times result in highly textured active layers with crystalline domains that can exceed the lengthscale of exciton diffusion, while inducing detrimental vertical morphologies and deep carrier traps. Last, we emphasize the field-dependence charge generation occurring upon SVA-mediated crystallization and link this carrier effect to the mixed phase depletion across the BHJ active layer.

Solvent Vapor Annealing-Mediated Crystallization Directs Charge Generation, Recombination and Extraction in BHJ Solar Cells

KAUST Repository

Babics, Maxime

2017-12-19

Small-molecule (SM) donors that can be solution-processed with fullerene acceptors (e.g., PC61/71BM), or their “nonfullerene” counterparts, are proving particularly promising for the realization of high-efficiency bulk-heterojunction (BHJ) solar cells. In several recent studies, solvent vapor annealing (SVA) protocols have been found to yield significant BHJ device efficiency improvements via structural changes in the active layer morphologies. However, the mechanisms by which active layer morphologies evolve when subjected to SVA treatments, and the structural factors impacting charge generation, carrier transport, recombination and extraction in BHJ solar cells with SM donors and fullerene acceptors, remain important aspects to be elucidated. In this report, we show that – in BHJ solar cells with SM donors and fullerene acceptors – selective crystallization promoted by SVA mediates the development of optimized morphologies across the active layers, setting domain sizes and boundaries. Examining BHJ solar cells subjected to various SVA exposure times, with BDT[2F]QdC as the SM donor and PC71BM as the acceptor, we connect those morphological changes to specific carrier effects, showing that crystal growth effectively directs charge generation and recombination. We find that the SM donor-pure domains growing at the expense of a mixed donor-acceptor phase play a determining role, establishing optimum networks with 10-20nm-sized domains during the SVA treatment. Longer SVA times result in highly textured active layers with crystalline domains that can exceed the lengthscale of exciton diffusion, while inducing detrimental vertical morphologies and deep carrier traps. Last, we emphasize the field-dependence charge generation occurring upon SVA-mediated crystallization and link this carrier effect to the mixed phase depletion across the BHJ active layer.

International experience in tailings pond remediation

Energy Technology Data Exchange (ETDEWEB)

MacG. Robertson, A. [Robertson GeoConsultants Ltd., Vancouver (Canada)

2001-07-01

Tailings pond remediation is required primarily on mine closure. While mining is an ancient industry, requirement for mine facility remediation is a comparatively new development. Requirement for remediation has come about partly as a result of mans awareness of the environmental impacts of mining and his desire to minimize this, partly, as a result of the ever-increasing scale and production rates of tailings generation and the resulting increased environmental impacts and safety risks. The paper starts with a review of the evolution of mans intolerance of environmental impacts from tailings production and the assignment of liability to remediate such impacts. Many of the tailings ponds currently undergoing remediation were designed and constructed using methods and technology that would be considered inappropriate for new impoundments being designed and developed today. The paper reviews the history of tailings impoundment design and construction practice and the resulting inherent deficiencies that must be remediated. Current practices and future trends in tailings pond remediation are reviewed. The evolution of regulatory requirements is not only in terms of technical and safety criteria, but also in terms of financial and political risk. Perhaps the most substantive driver of risk management is today the requirement for corporate governance at mining company board level and oversight of new project development in the underdeveloped countries by the large financial institutions responsible for funding projects. Embarrassment in the public eye and punishment in the stock markets for poor environmental and safety performance is driving the need for efficient and effective risk management of potential impacts and the remediation to avoid these. A basis for practical risk management is described. (orig.)

International experience in tailings pond remediation

International Nuclear Information System (INIS)

Robertson, A.MacG.

2001-01-01

Tailings pond remediation is required primarily on mine closure. While mining is an ancient industry, requirement for mine facility remediation is a comparatively new development. Requirement for remediation has come about partly as a result of mans awareness of the environmental impacts of mining and his desire to minimize this, partly, as a result of the ever-increasing scale and production rates of tailings generation and the resulting increased environmental impacts and safety risks. The paper starts with a review of the evolution of mans intolerance of environmental impacts from tailings production and the assignment of liability to remediate such impacts. Many of the tailings ponds currently undergoing remediation were designed and constructed using methods and technology that would be considered inappropriate for new impoundments being designed and developed today. The paper reviews the history of tailings impoundment design and construction practice and the resulting inherent deficiencies that must be remediated. Current practices and future trends in tailings pond remediation are reviewed. The evolution of regulatory requirements is not only in terms of technical and safety criteria, but also in terms of financial and political risk. Perhaps the most substantive driver of risk management is today the requirement for corporate governance at mining company board level and oversight of new project development in the underdeveloped countries by the large financial institutions responsible for funding projects. Embarrassment in the public eye and punishment in the stock markets for poor environmental and safety performance is driving the need for efficient and effective risk management of potential impacts and the remediation to avoid these. A basis for practical risk management is described. (orig.)

High temperature vapors science and technology

CERN Document Server

Hastie, John

2012-01-01

High Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temp

Copper-vapor-catalyzed chemical vapor deposition of graphene on dielectric substrates

Science.gov (United States)

Yang, Chao; Wu, Tianru; Wang, Haomin; Zhang, Xuefu; Shi, Zhiyuan; Xie, Xiaoming

2017-07-01

Direct synthesis of high-quality graphene on dielectric substrates is important for its application in electronics. In this work, we report the process of copper-vapor-catalyzed chemical vapor deposition of high-quality and large graphene domains on various dielectric substrates. The copper vapor plays a vital role on the growth of transfer-free graphene. Both single-crystal domains that are much larger than previous reports and high-coverage graphene films can be obtained by adjusting the growth duration. The quality of the obtained graphene was verified to be comparable with that of graphene grown on Cu foil. The progress reported in this work will aid the development of the application of transfer-free graphene in the future.

Estimated vapor pressure for WTP process streams

Energy Technology Data Exchange (ETDEWEB)

Pike, J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Poirier, M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2015-01-01

Design assumptions during the vacuum refill phase of the Pulsed Jet Mixers (PJMs) in the Hanford Waste Treatment and Immobilization Plant (WTP) equate the vapor pressure of all process streams to that of water when calculating the temperature at which the vacuum refill is reduced or eliminated. WTP design authority asked the authors to assess this assumption by performing calculations on proposed feed slurries to calculate the vapor pressure as a function of temperature. The vapor pressure was estimated for each WTP waste group. The vapor pressure suppression caused by dissolved solids is much greater than the increase caused by organic components such that the vapor pressure for all of the waste group compositions is less than that of pure water. The vapor pressure for each group at 145°F ranges from 81% to 98% of the vapor pressure of water. If desired, the PJM could be operated at higher temperatures for waste groups with high dissolved solids that suppress vapor pressure. The SO4 group with the highest vapor pressure suppression could be operated up to 153°F before reaching the same vapor pressure of water at 145°F. However, most groups would reach equivalent vapor pressure at 147 to 148°F. If any of these waste streams are diluted, the vapor pressure can exceed the vapor pressure of water at mass dilution ratios greater than 10, but the overall effect is less than 0.5%.

In situ vadose zone bioremediation of soil contaminated with nonvolatile hydrocarbons

International Nuclear Information System (INIS)

Hogg, D.S.; Burden, R.J.; Riddell, P.J.

1992-01-01

In situ bioremediation has been successfully carried out on petroleum hydrocarbon-contaminated soil at a decommissioned bulk storage terminal in New Zealand. The site soils were contaminated mainly with diesel fuel and spent oil at concentrations ranging up to 95,000 mg/kg of total recoverable petroleum hydrocarbons. The in situ remediation system combines an enhanced bioremediation with vapor extraction and is installed almost entirely below grade, thereby allowing above ground activities to continue unimpeded. Laboratory-scale feasibility testing indicated that although appreciable volatilization of low molecular weight components would occur initially, biodegradation would be the primary mechanism by which contaminated soil would be remediated. During the remedial design phase, preliminary field testing was conducted to evaluate the optimum spacing for extraction wells and inlet vents. A pilot-scale system was installed in a 15-m by 35-m area of the site in June 1989 and operated for approximately 1 year. Soil monitoring performed approximately every 3 months indicated an overall reduction in soil petroleum hydrocarbon concentrations of 87% for the period from June 1989 to May 1991

Program management strategies for following EPA guidance for remedial design/remedial action at DOE sites

International Nuclear Information System (INIS)

Hopper, J.P.; Chew, J.R.; Kowalski, T.E.

1991-01-01

At the US Department of Energy (DOE) facilities, environmental restoration is being conducted in accordance with Federal Facilities Compliance Agreements (or Interagency Agreements). These agreements establish a cooperative working relationship and often define roles, responsibilities and authorities for conduct and oversight of the Remedial Action Programs. The US Environmental Protection Agency (EPA) has guidelines on how to initiate and perform remedial actions for sites they are remediating under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) as amended by the Superfund Amendments and Re-Authorization Act (SARA). This paper addresses some of the difference and commonalities between the DOE project management procedures and EPA guidance documents. This report covers only the RD/RA phase of environmental restoration. On the surface, there are many apparent differences between the DOE and EPA project management processes. Upon closer review, however, many of the differences are the result of applying different terminology to the same phase of a project. By looking for the similarities in the two processes rather than hunting for differences, many communication problems are avoided. Understanding both processes also aids in figuring out when, how and to what extent EPA should participate in the RD/RA phase for DOE lead cleanup activities. The DOE Remedial Design and Remedial Action process is discussed in a stepwise manner and compared to the EPA process. Each element of the process is defined. Activities common to both the EPA and DOE are correlated. The annual DOE budget cycle for remediation projects and the four-year cycle for appropriation of remediation funds are discussed, and the constraints of this process examined. DOE orders as well as other requirements for RD/RA activities are summarized and correlated to EPA regulations where this is possible

Site remediation using photocatalytic VOC destruction of chlorinated hydrocarbons

Energy Technology Data Exchange (ETDEWEB)

Brunet, R.A.H.; Pearcey, R.; Kittrell, J.R.; Mackin, G.; Wise, C.A.

1999-07-01

An innovative environmental technology has been developed and demonstrated for cost-effective control of toxic air emissions, such as trichloroethylene (TCE) and perchloroethylene (PCE), found in soil and groundwater at hazardous waste sites and in industrial effluents. The technology uses UV light and a proprietary photocatalyst to adsorb and destroy pollutants at ambient conditions, even with high humidity. Air stripping and soil vapor extraction efficiently transfer the pollutants to the gas phase, where they can be economically treated by photocatalysis without the risk of hazardous by-product formation. The AIR2000 photocatalytic technology was successfully installed at the Stamina Mills Superfund site in Rhode Island, where a commercial scale unit is treating 700 cfm of up to 1,000 ppm TCE, mixed with PCE, dichloroethylene (DCE), trichloroethane (TCA), and vinyl chloride (VC) produced through a combination of soil vapor extraction (SVE) and air stripping. As part of the EPA SITE program, the system was monitored for overall destruction removal efficiency (DRE) and hazardous by-product formation. A DRE in excess of 99% was reported over the first four months of operation, with greater than 99.99% DRE achieved, without production of hazardous by-products. The operating cost of the system is approximately 20% of activated carbon adsorption, which provides approximately $1,500,000 in cost savings over the life of the Stamina Mills project. The Adsorption Integrated Reaction (AIR) process is the recipient of the 1997 SBIR Technology of the Year award, the 1998 EPA Environmental Technology Innovator Award, and the 1998 R and D 100 Award.

A numerical investigation of vapor intrusion--the dynamic response of contaminant vapors to rainfall events.

Science.gov (United States)

Shen, Rui; Pennell, Kelly G; Suuberg, Eric M

2012-10-15

The U.S. government and various agencies have published guidelines for field investigation of vapor intrusion, most of which suggest soil gas sampling as an integral part of the investigation. Contaminant soil gas data are often relatively more stable than indoor air vapor concentration measurements, but meteorological conditions might influence soil gas values. Although a few field and numerical studies have considered some temporal effects on soil gas vapor transport, a full explanation of the contaminant vapor concentration response to rainfall events is not available. This manuscript seeks to demonstrate the effects on soil vapor transport during and after different rainfall events, by applying a coupled numerical model of fluid flow and vapor transport. Both a single rainfall event and seasonal rainfall events were modeled. For the single rainfall event models, the vapor response process could be divided into three steps: namely, infiltration, water redistribution, and establishment of a water lens atop the groundwater source. In the infiltration step, rainfall intensity was found to determine the speed of the wetting front and wash-out effect on the vapor. The passage of the wetting front led to an increase of the vapor concentration in both the infiltration and water redistribution steps and this effect is noted at soil probes located 1m below the ground surface. When the mixing of groundwater with infiltrated water was not allowed, a clean water lens accumulated above the groundwater source and led to a capping effect which can reduce diffusion rates of contaminant from the source. Seasonal rainfall with short time intervals involved superposition of the individual rainfall events. This modeling results indicated that for relatively deeper soil that the infiltration wetting front could not flood, the effects were damped out in less than a month after rain; while in the long term (years), possible formation of a water lens played a larger role in determining

Responses of wild small mammals to arsenic pollution at a partially remediated mining site in Southern France.

Science.gov (United States)

Drouhot, Séverine; Raoul, Francis; Crini, Nadia; Tougard, Christelle; Prudent, Anne-Sophie; Druart, Coline; Rieffel, Dominique; Lambert, Jean-Claude; Tête, Nicolas; Giraudoux, Patrick; Scheifler, Renaud

2014-02-01

Partial remediation actions at a former gold mine in Southern France led to a mosaic of contaminated and rehabilitated zones. In this study, the distribution of arsenic and its potential adverse effects on small mammals were investigated. The effectiveness of remediation for reducing the transfer of this element into wildlife was also discussed. Arsenic levels were measured in the soil and in the stomach contents, livers, kidneys, and lungs of four small mammal species (the wood mouse (Apodemus sylvaticus), the Algerian mouse (Mus spretus), the common vole (Microtus arvalis), and the greater white-toothed shrew (Crocidura russula)). The animals were caught at the former extraction site, in zones with three different levels of remediation treatments, and at a control site. Arsenic concentrations in the soil were highly spatially heterogeneous (ranging from 29 to 18,900 μg g(-1)). Despite the decrease in arsenic concentrations in the remediated soils, both wood mice and Algerian mice experienced higher oral exposure to arsenic in remediated zones than in the control area. The accumulated arsenic in their organs showed higher intra-zonal variability than the arsenic distribution in the soil, suggesting that, in addition to remediation processes, other variables can help explain arsenic transfer to wildlife, such as the habitat and diet preferences of the animals or their mobility. A weak but significant correlation between arsenic concentration and body condition was observed, and weak relationships between the liver/kidney/lung mass and arsenic levels were also detected, suggesting possible histological alterations. © 2013.

A Bayesian Approach to Integrate Real-Time Data into Probabilistic Risk Analysis of Remediation Efforts in NAPL Sites

Science.gov (United States)

Fernandez-Garcia, D.; Sanchez-Vila, X.; Bolster, D.; Tartakovsky, D. M.

2010-12-01

The release of non-aqueous phase liquids (NAPLs) such as petroleum hydrocarbons and chlorinated solvents in the subsurface is a severe source of groundwater and vapor contamination. Because these liquids are essentially immiscible due to low solubility, these contaminants get slowly dissolved in groundwater and/or volatilized in the vadoze zone threatening the environment and public health over a long period. Many remediation technologies and strategies have been developed in the last decades for restoring the water quality properties of these contaminated sites. The failure of an on-site treatment technology application is often due to the unnoticed presence of dissolved NAPL entrapped in low permeability areas (heterogeneity) and/or the remaining of substantial amounts of pure phase after remediation efforts. Full understanding of the impact of remediation efforts is complicated due to the role of many interlink physical and biochemical processes taking place through several potential pathways of exposure to multiple receptors in a highly unknown heterogeneous environment. Due to these difficulties, the design of remediation strategies and definition of remediation endpoints have been traditionally determined without quantifying the risk associated with the failure of such efforts. We conduct a probabilistic risk analysis (PRA) of the likelihood of success of an on-site NAPL treatment technology that easily integrates all aspects of the problem (causes, pathways, and receptors) without doing extensive modeling. Importantly, the method is further capable to incorporate the inherent uncertainty that often exist in the exact location where the dissolved NAPL plume leaves the source zone. This is achieved by describing the failure of the system as a function of this source zone exit location, parameterized in terms of a vector of parameters. Using a Bayesian interpretation of the system and by means of the posterior multivariate distribution, the failure of the

Remediation of sites with dispersed radioactive contamination

International Nuclear Information System (INIS)

2004-01-01

To respond to the needs of Member States, the IAEA launched an environmental remediation project to deal with the problems of radioactive contamination worldwide. The IAEA environmental remediation project includes an IAEA Coordinated Research Project, as well as the participation of IAEA experts in concrete remediation projects when requested by individual Member States. The IAEA has prepared several documents dedicated to particular technical or conceptual areas, including documents on the characterization of contaminated sites, technical and non-technical factors relevant to the selection of a preferred remediation strategy and technique, overview of applicable techniques for environmental remediation,, options for the cleanup of contaminated groundwater and planning and management issues. In addition, a number of other IAEA publications dealing with related aspects have been compiled under different IAEA projects; these include TECDOCs on the remediation of uranium mill tailings, the decontamination of buildings and roads and the characterization of decommissioned sites. Detailed procedures for the planning and implementation of remedial measures have been developed over the past decade or so. A critical element is the characterization of the contamination and of the various environmental compartments in which it is found, in order to be able to evaluate the applicability of remediation techniques. The chemical or mineralogical form of the contaminant will critically influence the efficiency of the remediation technique chosen. Careful delineation of the contamination will ensure that only those areas or volumes of material that are actually contaminated are treated. This, in turn, reduces the amount of any secondary waste generated. The application of a remediation technique requires holistic studies examining the technical feasibility of the proposed measures, including analyses of their impact. Consequently, input from various scientific and engineering

In Vitro antioxidant activity of extracts from the leaves of Abies ...

African Journals Online (AJOL)

Traditionally, the leaves of Abies pindrow Royle are employed as an ayurvedic remedy for fever, hypoglycaemic, respiratory and inflammatory conditions. In this study, dichloromethane, methanol and acetone extracts of A. pindrow leaves were analysed for their phytochemical content and in vitro antioxidant activities.

Phytochemical analysis and in vivo antidirrhoeal potentials of Dialium guineense (Wild) stem bark extract

OpenAIRE

Gideon Ikechukwu Ogu; Ralphael Amiebenomo

2012-01-01

This study was undertaken to evaluate the in vivo anti-diarrhoeal activity of methanolic stem bark extract of Dialium guineense used traditionally as remedy for gastrointestinal disorder in South- Western Nigeria. The effect of the extract at oral dosesof 50-200 mg/kg body weight on the castor oil-induced diarrhoea, gastrointestinal motility (charcoal meal) and castor oil-induced intestinal fluid accumulation (enteropooling) were examined in rats. The extract employed produced a d...

Site remediation techniques in India: a review

International Nuclear Information System (INIS)

Anomitra Banerjee; Miller Jothi

2013-01-01

India is one of the developing countries operating site remediation techniques for the entire nuclear fuel cycle waste for the last three decades. In this paper we intend to provide an overview of remediation methods currently utilized at various hazardous waste sites in India, their advantages and disadvantages. Over the years the site remediation techniques have been well characterized and different processes for treatment, conditioning and disposal are being practiced. Remediation Methods categorized as biological, chemical or physical are summarized for contaminated soils and environmental waters. This paper covers the site remediation techniques implemented for treatment and conditioning of wastelands arising from the operation of nuclear power plant, research reactors and fuel reprocessing units. (authors)

Proceedings of the remediation technologies symposium 2006

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-07-01

This conference provided an opportunity for industry, practitioners, researchers and regulators to discuss technical issues in environmental remediation research and the latest innovations in soil and groundwater remediation. Cost effective in-situ and ex-situ soil reclamation strategies were presented along with groundwater and surface water remediation strategies in 13 sessions entitled: hydrocarbon contamination; salt management; liability management; chemical oxidation; light non-aqueous phase liquids (LNAPL); Montreal Center of Excellence in Brownfields Rehabilitation; Alberta government updates; phytoremediation; natural attenuation; Lake Wabamun; ex-situ remediation; in-situ remediation; and, miscellaneous issues. Technological solutions for erosion control and water clarification were highlighted. The conference featured 52 presentations, of which 17 have been catalogued separately for inclusion in this database. tabs., figs.

Groundwater remediation in the Straz leaching operation

International Nuclear Information System (INIS)

Novak, J.

2001-01-01

The locality affected by consequences of the chemical mining of the uranium during underground leaching 'in situ' is found in the area of the Czech Republic in the northeastern part of the Ceska Lipa district. In the contribution the complex groundwater remediation project is discussed. First, the risks of the current state are expressed. Then the alternatives of remediation of the both Cenomanian and Turonian aquifers are presented. Evaluation of the remediation alternatives with the view to the time-consumption, economy, ecology and the elimination of unacceptable risks for the population and environment is done. Finally, the present progress of remediation and the conception of remediation of chemical mining on deposit of Straz pod Ralskem are presented. (orig.)

ICDF Complex Remedial Action Report

Energy Technology Data Exchange (ETDEWEB)

W. M. Heileson

2007-09-26

This Idaho CERCLA Disposal Facility (ICDF) Remedial Action Report has been prepared in accordance with the requirements of Section 6.2 of the INEEL CERCLA Disposal Facility Remedial Action Work Plan. The agency prefinal inspection of the ICDF Staging, Storage, Sizing, and Treatment Facility (SSSTF) was completed in June of 2005. Accordingly, this report has been developed to describe the construction activities completed at the ICDF along with a description of any modifications to the design originally approved for the facility. In addition, this report provides a summary of the major documents prepared for the design and construction of the ICDF, a discussion of relevant requirements and remedial action objectives, the total costs associated with the development and operation of the facility to date, and identification of necessary changes to the Agency-approved INEEL CERCLA Disposal Facility Remedial Action Work Plan and the ICDF Complex Operations and Maintenance Plan.

Electrodialytic soil remediation

DEFF Research Database (Denmark)

Hansen, Henrik K.; Ottosen, Lisbeth M.; Hansen, Lene

1997-01-01

It is not possible for all heavy metal polluted soils to remediate it by an applied electric field alone. A desorbing agent must in different cases be added to the soil in order to make the process possible or to make it cost effective......It is not possible for all heavy metal polluted soils to remediate it by an applied electric field alone. A desorbing agent must in different cases be added to the soil in order to make the process possible or to make it cost effective...

Applications of biosurfactants in the petroleum industry and the remediation of oil spills.

Science.gov (United States)

de Cássia F S Silva, Rita; Almeida, Darne G; Rufino, Raquel D; Luna, Juliana M; Santos, Valdemir A; Sarubbo, Leonie Asfora

2014-07-15

Petroleum hydrocarbons are important energy resources. However, petroleum is also a major pollutant of the environment. Contamination by oil and oil products has caused serious harm, and increasing attention has been paid to the development and implementation of innovative technologies for the removal of these contaminants. Biosurfactants have been extensively used in the remediation of water and soil, as well as in the main stages of the oil production chain, such as extraction, transportation, and storage. This diversity of applications is mainly due to advantages such as biodegradability, low toxicity and better functionality under extreme conditions in comparison to synthetic counterparts. Moreover, biosurfactants can be obtained with the use of agro-industrial waste as substrate, which helps reduce overall production costs. The present review describes the potential applications of biosurfactants in the oil industry and the remediation of environmental pollution caused by oil spills.

Applications of Biosurfactants in the Petroleum Industry and the Remediation of Oil Spills

Directory of Open Access Journals (Sweden)

Rita de Cássia F. S. Silva

2014-07-01

Full Text Available Petroleum hydrocarbons are important energy resources. However, petroleum is also a major pollutant of the environment. Contamination by oil and oil products has caused serious harm, and increasing attention has been paid to the development and implementation of innovative technologies for the removal of these contaminants. Biosurfactants have been extensively used in the remediation of water and soil, as well as in the main stages of the oil production chain, such as extraction, transportation, and storage. This diversity of applications is mainly due to advantages such as biodegradability, low toxicity and better functionality under extreme conditions in comparison to synthetic counterparts. Moreover, biosurfactants can be obtained with the use of agro-industrial waste as substrate, which helps reduce overall production costs. The present review describes the potential applications of biosurfactants in the oil industry and the remediation of environmental pollution caused by oil spills.

DOE's Assurance Program for Remedial Action (APRA)

International Nuclear Information System (INIS)

Denham, D.H.; Stenner, R.D.; Welty, C.G. Jr.; Needels, T.S.

1985-01-01

The US Department of Energy's (DOE) Office of Operational Safety (OOS) is presently developing and implementing the Assurance Program for Remedial Action (APRA) to overview DOE's Remedial Action programs. APRA's objective is to ensure the adequacy of environmental, safety and health (ES and H) protection practices within the four DOE Remedial Action programs: Grand Junction Remedial Action Program (GJRAP), Uranium Mill Tailings Remedial Action Program (UMTRAP), Formerly Utilized Sites Remedial Action Program (FUSRAP), and Surplus Facilities Management Program (SFMP). APRA encompasses all ES and H practices of DOE and its contractors/subcontractors within the four Remedial Action programs. Specific activities of APRA include document reviews, selected site visits, and program office appraisals. Technical support and assistance to OOS is being provided by APRA contractors in the evaluation of radiological standards and criteria, quality assurance measures, radiation measurements, and risk assessment practices. This paper provides an overview of these activities and discusses program to date, including the roles of OOS and the respective contractors. The contractors involved in providing technical support and assistance to OOS are Aerospace Corporation, Oak Ridge Associated Universities, and Pacific Northwest Laboratory

Remedial action of radium contaminated residential properties

International Nuclear Information System (INIS)

White, D.; Eng, J.

1986-01-01

Since November 1983, the New Jersey Department of Environmental Protection (NJDEP) and the US Environmental Protection Agency (USEPA) have been in the process of identifying properties in Montclair, Glen Ridge and West Orange, New Jersey, which were built over radium contaminated soil landfilled areas. Elevated indoor radon concentrations prompted the Centers for Disease Control (CDC) to issue a health advisory which included permanent remediation of radon progeny levels in excess of 0.02 Working Levels within two years of discovery. In order to expedite remedial action, NJDEP undertook a ten million dollar cleanup program. Remedial Action at the 12 residential properties encountered some unanticipated problems despite the efforts of numerous government agencies and their contractors to characterize the contamination as much as possible prior to remediation. Some of the unanticipated issues include contamination from other radionuclides, underestimation of removal volumes, and controversy over the transportation and disposal of the radium contaminated soil at a commercial facility in Nevada. This paper will review the approach taken by NJDEP to the remedial action for radium contaminated soil, discuss some of the issues encountered during the remedial action, and provide post remedial action data