The geological characteristics and forming conditions of granite type uranium-rich ore deposits

International Nuclear Information System (INIS)

Li Tiangang; Tong Hangshou; Feng Mingyue; Li Yuexiang; Xu Zhan

1993-03-01

The forming conditions and concentration mechanism of rich ore, criteria of ore prospecting and selection of uranium-rich ore target area are introduced in the article that is based on the studying of geological characteristics and conditions of granite type uranium-rich ore deposits of No 201 and 361 and on the comparisons of rich and poor ore deposits in geological conditions. Some new view points are also presented as the separate deposition of uranium minerals and gangue minerals is the main mechanism to form rich ore, for rich ore formation the ore enrichment by superimposition is not a universal regularity and most uranium-rich ore deposits are formed within one mineralization stage or mainly in one mineralization stage

Epithermal uranium deposits in a volcanogenic context: the example of Nopal 1 deposit, Sierra de Pena Blanca, Mexico

Science.gov (United States)

Calas, G.; Angiboust, S.; Fayek, M.; Camacho, A.; Allard, T.; Agrinier, P.

2009-12-01

The Peña Blanca molybdenum-uranium field (Chihuahua, Mexico) exhibits over 100 airborne anomalies hosted in tertiary ignimbritic ash-flow tuffs (44 Ma) overlying the Pozos conglomerate and a sequence of Cretaceous carbonate rocks. Uranium occurrences are associated with breccia zones at the intersection of two or more fault systems. Periodic reactivation of these structures associated with Basin and Range and Rio Grande tectonic events resulted in the mobilization of U and other elements by meteoric fluids heated by geothermal activity. Trace element geochemistry (U, Th, REE) provides evidence for local mobilization of uranium under oxidizing conditions. In addition, O- and H-isotope geochemistry of kaolinite, smectite, opal and calcite suggests that argillic alteration proceeded at shallow depth with meteoric water at 25-75 °C. Focussed along breccia zones, fluids precipitated several generations of pyrite and uraninite together with kaolinite, as in the Nopal 1 mine, indicating that mineralization and hydrothermal alteration of volcanic tuffs are contemporaneous. Low δ34S values (~ -24.5 ‰) of pyrites intimately associated with uraninite suggest that the reducing conditions at the origin of the U-mineralization arise from biological activity. Later, the uplift of Sierra Pena Blanca resulted in oxidation and remobilization of uranium, as confirmed by the spatial distribution of radiation-induced defect centers in kaolinites. These data show that tectonism and biogenic reducing conditions can play a major role in the formation and remobilization of uranium in epithermal deposits. By comparison with the other uranium deposits at Sierra Pena Blanca and nearby Sierra de Gomez, Nopal 1 deposit is one of the few deposits having retained a reduced uranium mineralization.

Granite-related hypothermal uranium mineralization in South China

International Nuclear Information System (INIS)

Liu, X.; Wu, J.; Pan, J.; Zhu, M.

2014-01-01

As one of the important geological types, granite-related uranium deposits account for about 29% of the total discovered natural uranium resources in China. Most of the granite-related uranium deposits located in Taoshan - Zhuguang uranium metallogenic belt, South China. In addition to the typical pitchblende vein-type uranium mineralization of epithermal metallogenic system, a new type of granite-related uranium mineralization with characteristics of hypothermal matallogenic system was discovered in South China by current studies. However, hypothermal is contact thermal to epithermal mineralization, and not the conventional intrusive high temperature mineralization. Hypothermal uranium mineralization is presented by disseminated uraninite or pitchblende stockwork in fissures in granites normally with extensive alkaline alteration. The high temperature mineral assemblage of uraninite associate with scheelite and tourmaline was identified in hypothermal uranium mineralization. Fluid inclusion studies on this type mineralization indicated the middle to high temperature (>250℃) mineralization with the mixing evidence of ore forming solution derived from deep level, and the boiling and mixing of ore forming solution are regarded as the dominant mineralization mechanism for the precipitating of uranium. In contrast to the mineralization ages of 67 Ma to 87 Ma for typical pitchblende vein mineralization of epithermal metallogenic system, the mineralization age is older than 100 Ma for hypothermal uranium mineralization in granite. In the Shituling deposit, Xiazhuang uranium ore field, uraninite and pitchblende micro veins with extensive potassic alteration, chloritization and sericitization are hosted in fissures of Indo-Chinese epoch granites with the uranium mineralization age of 130 Ma to 138 Ma with a mineralization temperature of 290℃ to 330℃ indicated. Other examples sharing the similar characters of hypothermal uranium mineralization have been recognized in

National Uranium Resource Evaluation: Okanogan Quadrangle, Washington

International Nuclear Information System (INIS)

Bernardi, M.L.; Powell, L.K.; Wicklund, M.A.

1982-06-01

The Okanogan Quadrangle, Washington, was evaluated to identify and delineate areas containing environments favorable for the occurrence of uranium deposits using criteria developed for the National Uranium Resource Evaluation program. Reconnaissance and detailed surface studies were augmented by aerial radiometric surveys and hydrogeochemical and stream-sediment reconnaissance studies. The results of the investigations indicate six environments favorable for uranium deposits. They are unclassified, anatectic, allogenic, and contact-metasomatic deposits in Late Precambrian and (or) Early Paleozoic mantling metamorphic core-complex rocks of the Kettle gneiss dome; magmatic-hydrothermal deposits in the Gold Creek pluton, the Magee Creek pluton, the Wellington Peak pluton, and the Midnite Mine pluton, all located in the southeast quadrant of the quadrangle; magmatic-hydrothermal allogenic deposits in Late Paleozoic and (or) Early Mesozoic black shales in the Castle Mountain area; allogenic deposits in Early Paleozoic metasedimentary rocks in the Harvey Creek area and in Late Precambrian metasedimentary rocks in the Blue Mountain area; and sandstone deposits in Eocene sedimentary rocks possibly present in the Enterprise Valley. Seven geologic units are considered unfavorable for uranium deposits. They are all the remaining metamorphic core-complex rocks, Precambrian metasedimentary rocks,Tertiary sedimentary and volcanic rocks, and all Pleistocene and Recent deposits; and, excluding those rocks in the unevaluated areas, include all the remaining plutonic rocks, Paleozoic miogeoclinical rocks, and Upper Paleozoic and Mesozoic eugeosynclinal rocks. Three areas, the Cobey Creek-Frosty Creek area, the Oregon City Ridge-Wilmont Creek area, and the area underlain by the Middle Cambrian Metaline Formation and its stratigraphic equivalents may possibly be favorable but are unevaluated due to lack of data

Uraniferous opal, Virgin Valley, Nevada: conditions of formation and implications for uranium exploration

International Nuclear Information System (INIS)

Zielinski, R.A.

1981-01-01

Fission-track radiography shows uranium to be homogeneously dispersed throughout the opal structure, suggesting coprecipitation of dissolved uranium and silica gel. Fluid inclusions preserved within opal replacements of diatomite have homogenization temperatures in the epithermal range and are of low salinity. Four samples of opal from one locality all have U-Pb apparent ages which suggest uraniferous opal precipitation in late Pliocene time. These ages correspond to a period of local, normal faulting, and high-angle faults may have served as vertical conduits for transport of deep, thermalized ground water to shallower levels. Lateral migration of rising solutions occurred at intersections of faults with permeable strata. Silica and some uranium were dissolved from silica-rich host strata of 5-20 ppm original uranium content and reprecipitated as the solutions cooled. The model predicts that in similar geologic settings, ore-grade concentrations of uranium will occur in permeable strata that intersect high-angle faults and that contain uranium source rocks as well as efficient reductant traps for uranium. In the absence of sufficient quantities of reductant materials, uranium will be flushed from the system or will accumulate in low-grade disseminated hosts such as uraniferous opal. (Auth.)

Uraniferous opal, Virgin Valley, Nevada: conditions of formation and implications for uranium exploration

Energy Technology Data Exchange (ETDEWEB)

Zielinski, R A [Geological Survey, Denver, CO (USA)

1981-01-01

Fission-track radiography shows uranium to be homogeneously dispersed throughout the opal structure, suggesting coprecipitation of dissolved uranium and silica gel. Fluid inclusions preserved within opal replacements of diatomite have homogenization temperatures in the epithermal range and are of low salinity. Four samples of opal from one locality all have U-Pb apparent ages which suggest uraniferous opal precipitation in late Pliocene time. These ages correspond to a period of local, normal faulting, and high-angle faults may have served as vertical conduits for transport of deep, thermalized ground water to shallower levels. Lateral migration of rising solutions occurred at intersections of faults with permeable strata. Silica and some uranium were dissolved from silica-rich host strata of 5-20 ppm original uranium content and reprecipitated as the solutions cooled. The model predicts that in similar geologic settings, ore-grade concentrations of uranium will occur in permeable strata that intersect high-angle faults and that contain uranium source rocks as well as efficient reductant traps for uranium. In the absence of sufficient quantities of reductant materials, uranium will be flushed from the system or will accumulate in low-grade disseminated hosts such as uraniferous opal.

Critical elements in Carlin, epithermal, and orogenic gold deposits

Science.gov (United States)

Goldfarb, Richard J.; Hofstra, Albert H.; Simmons, Stuart F.

2016-01-01

Carlin, epithermal, and orogenic gold deposits, today mined almost exclusively for their gold content, have similar suites of anomalous trace elements that reflect similar low-salinity ore fluids and thermal conditions of metal transport and deposition. Many of these trace elements are commonly referred to as critical or near-critical elements or metals and have been locally recovered, although typically in small amounts, by historic mining activities. These elements include As, Bi, Hg, In, Sb, Se, Te, Tl, and W. Most of these elements are now solely recovered as by-products from the milling of large-tonnage, base metal-rich ore deposits, such as porphyry and volcanogenic massive sulfide deposits.A combination of dominance of the world market by a single country for a single commodity and a growing demand for many of the critical to near-critical elements could lead to future recovery of such elements from select epithermal, orogenic, or Carlin-type gold deposits. Antimony continues to be recovered from some orogenic gold deposits and tellurium could potentially be a primary commodity from some such deposits. Tellurium and indium in sphalerite-rich ores have been recovered in the past and could be future commodities recovered from epithermal ores. Carlin-type gold deposits in Nevada are enriched in and may be a future source for As, Hg, Sb, and/or Tl. Some of the Devonian carbonaceous host rocks in the Carlin districts are sufficiently enriched in many trace elements, including Hg, Se, and V, such that they also could become resources. Thallium may be locally enriched to economic levels in Carlin-type deposits and it has been produced from Carlin-like deposits elsewhere in the world (e.g., Alsar, southern Macedonia; Lanmuchang, Guizhou province, China). Mercury continues to be recovered from shallow-level epithermal deposits, as well as a by-product of many Carlin-type deposits where refractory ore is roasted to oxidize carbon and pyrite, and mercury is then

Influence of Uranium on Bacterial Communities: A Comparison of Natural Uranium-Rich Soils with Controls

Science.gov (United States)

Mondani, Laure; Benzerara, Karim; Carrière, Marie; Christen, Richard; Mamindy-Pajany, Yannick; Février, Laureline; Marmier, Nicolas; Achouak, Wafa; Nardoux, Pascal; Berthomieu, Catherine; Chapon, Virginie

2011-01-01

This study investigated the influence of uranium on the indigenous bacterial community structure in natural soils with high uranium content. Radioactive soil samples exhibiting 0.26% - 25.5% U in mass were analyzed and compared with nearby control soils containing trace uranium. EXAFS and XRD analyses of soils revealed the presence of U(VI) and uranium-phosphate mineral phases, identified as sabugalite and meta-autunite. A comparative analysis of bacterial community fingerprints using denaturing gradient gel electrophoresis (DGGE) revealed the presence of a complex population in both control and uranium-rich samples. However, bacterial communities inhabiting uraniferous soils exhibited specific fingerprints that were remarkably stable over time, in contrast to populations from nearby control samples. Representatives of Acidobacteria, Proteobacteria, and seven others phyla were detected in DGGE bands specific to uraniferous samples. In particular, sequences related to iron-reducing bacteria such as Geobacter and Geothrix were identified concomitantly with iron-oxidizing species such as Gallionella and Sideroxydans. All together, our results demonstrate that uranium exerts a permanent high pressure on soil bacterial communities and suggest the existence of a uranium redox cycle mediated by bacteria in the soil. PMID:21998695

Characterization of uranium redox state in organic-rich Eocene sediments.

Science.gov (United States)

Cumberland, Susan A; Etschmann, Barbara; Brugger, Joël; Douglas, Grant; Evans, Katy; Fisher, Louise; Kappen, Peter; Moreau, John W

2018-03-01

The presence of organic matter (OM) has a profound impact on uranium (U) redox cycling, either limiting or promoting the mobility of U via binding, reduction, or complexation. To understand the interactions between OM and U, we characterised U oxidation state and speciation in nine OM-rich sediment cores (18 samples), plus a lignite sample from the Mulga Rock polymetallic deposit in Western Australia. Uranium was unevenly dispersed within the analysed samples with 84% of the total U occurring in samples containing >21 wt % OM. Analyses of U speciation, including x-ray absorption spectroscopy and bicarbonate extractions, revealed that U existed predominately (∼71%) as U(VI), despite the low pH (4.5) and nominally reducing conditions within the sediments. Furthermore, low extractability by water, but high extractability by a bi-carbonate solution, indicated a strong association of U with particulate OM. The unexpectedly high proportion of U(VI) relative to U(IV) within the OM-rich sediments implies that OM itself does not readily reduce U, and the reduction of U is not a requirement for immobilizing uranium in OM-rich deposits. The fact that OM can play a significant role in limiting the mobility and reduction of U(VI) in sediments is important for both U-mining and remediation. Copyright © 2017 Elsevier Ltd. All rights reserved.

Fission decay properties of ultra neutron-rich uranium isotopes

Indian Academy of Sciences (India)

in the chain of neutron-rich uranium isotopes is examined here. The neutron ... mean field theory, this nucleus is shown to undergo exotic decay mode of thermal neu- .... For 250U with a fission barrier of 4.3 MeV [5], we obtain the value of.

Tianmujian caldera. A potential area for locating rich and large uranium deposit

International Nuclear Information System (INIS)

Lin Ziyu; Xu Jinshan; Chen Mingzhuo; Jiang Jinyuan; Fan Honghai; Cheng Qi

2001-01-01

Based on the comprehensive analysis on geologic, remote sensing, gravimetric, magnetic and geochemical data, and the field geologic investigation, the author has preliminarily ascertained the formation and the distribution characteristics of the Tianmujian caldera, and recognized the porphyroclastic lava system which is extensively distributed in the area. The authors suggest that the Tianmujian volcanic basin experienced two evolution stages--the thermal uplifting and the formation of caldera, that large concealed uranium-rich granitic massif occurs in the area, and during the vertical evolution process the uranium showed its concentration in the lower part and depletion in the upper part, and large amount of ore-forming material moved upward along with the magmatic hydrothermals entering the caldera to form uranium deposit. In addition, it is clarified that the NE-NW rhombic-formed basement structural pattern is predominated by the NE-trending fault. At the same time, the important role of the basement faults in controlling the magmatic activities, in the formation of volcanic basins, as well as the formation of uranium mineralization is emphasized. On the basis of the above comprehensive analysis the authors suggest that the Tianmujian caldera is a quite favourable potential area for possessing the basic conditions necessary for the formation of rich and large uranium deposit including uranium 'source, migration, concentration, preservation' and favourable multiple metallogenic information is displayed in the Tianmujian area

Uraniferous opal, Virgin Valley, Nevada: conditions of formation and implications for uranium exploration

Science.gov (United States)

Zielinski, R.A.

1982-01-01

Uraniferous, fluorescent opal, which occurs in tuffaceous sedimentary rocks at Virgin Valley, Nevada, records the temperature and composition of uranium-rich solutions as well as the time of uranium-silica coprecipitation. Results are integrated with previous geologic and geochronologic data for the area to produce a model for uranium mobility that may be used to explore for uranium deposits in similar geologic settings. Uraniferous opal occurs as replacements of diatomite, or silicic air-fall ash layers in tuffaceous lakebeds of the Virgin Valley Formation (Miocene) of Merriam (1907). Fission-track radiography shows uranium to be homogeneously dispersed throughout the opal structure, suggesting coprecipitation of dissolved uranium and silica gel. Fluid inclusions preserved within opal replacements of diatomite have homogenization temperatures in the epithermal range and are of low salinity. Four samples of opal from one locality all have U-Pb apparent ages which suggest uraniferous opal precipitation in late Pliocene time. These ages correspond to a period of local, normal faulting, and highangle faults may have served as vertical conduits for transport of deep, thermalized ground water to shallower levels. Lateral migration of rising solutions occurred at intersections of faults with permeable strata. Silica and some uranium were dissolved from silica-rich host strata of 5-20 ppm original uranium content and reprecipitated as the solutions cooled. The model predicts that in similar geologic settings, ore-grade concentrations of uranium will occur in permeable strata that intersect high-angle faults and that contain uranium source rocks as well as efficient reductant traps for uranium. In the absence of sufficient quantities of reductant materials, uranium will be flushed from the system or will accumulate in low-grade disseminated hosts such as uraniferous opal. ?? 1982.

Mineral transformations and magnetic properties: example of an uranium rich front of oxido-reduction

International Nuclear Information System (INIS)

Mergaux, O.; Samama, J.C.

1987-01-01

In sedimentary environments, the mineral associations and the associated magnetic properties may be ascribed to superimposed processes of sedimentation, diagenesis and epigenesis. In the case of uranium sandstone deposits, the epigenetic processes of oxido-reduction are responsible for both concentration in uranium and specific mineral transformations which are related to variations in the magnetic properties of the rocks. These variations are illustrated by the Treville deposit (Southwestern France), where uranium rich bodies have developed within the Tertiary sandstones. The unaltered sandstones are characterized by a low magnetic susceptibility (scarcity of ferrimagnetic species but abundance of paramagnetic species). The siderite rich facies forming part of the front does not display any significant change in the mean magnetic susceptibility whilst the uranium-pyrite facies which belongs to the same front indicates a much lower susceptibility. The mean susceptibility facies resulting from pyrite and siderite oxidation remains unchanged. The facies of alteration of the iron rich silicates is responsible for higher susceptibility. The comparison between measured susceptibility and computed susceptibility helps in interpreting the role of the various species in the overall susceptibility of the rocks. It may also help in restituting the mineral associations from magnetic and chemical logging

Directional epithermal neutron detector

International Nuclear Information System (INIS)

Givens, W.W.; Mills, W.R. Jr.

1986-01-01

A borehole tool for epithermal neutron die-away logging of subterranean formations surrounding a borehole is described which consists of: (a) a pulsed source of fast neutrons for irradiating the formations surrounding a borehole, (b) at least one neutron counter for counting epithermal neutrons returning to the borehole from the irradiated formations, (c) a neutron moderating material, (d) an outer thermal neutron shield providing a housing for the counter and the moderating material, (e) an inner thermal neutron shield dividing the housing so as to provide a first compartment bounded by the inner thermal neutron shield and a first portion of the outer thermal neutron shield and a second compartment bounded by the inner thermal neutron shield and a second portion of the outer thermal neutron shield, the counter being positioned within the first compartment and the moderating material being positioned within the second compartment, and (f) means for positioning the borehole tool against one side of the borehole wall and azimuthally orienting the borehole tool such that the first chamber is in juxtaposition with the borehole wall, the formation epithermal neutrons penetrating into the first chamber through the first portion of the outer thermal neutron shield are detected by the neutron counter for die-away measurement, thereby maximizing the directional sensitivty of the neutron counter to formation epithermal neutrons, the borehole fluid epithermal neutrons penetrating into the second chamber through the second chamber through the second portion of the outer thermal neutron shield are largely slowed down and lowered in energy by the moderating material and absorbed by the inner thermal neutron shield before penetrating into the first chamber, thereby minimizing the directional sensitivity of the neutron counter to borehole fluid epithermal neutrons

Fast and epithermal neutron radiography using neutron irradiator

International Nuclear Information System (INIS)

Oliveira, Karol A.M. de; Crispim, Verginia R.; Ferreira, Francisco J.O.

2013-01-01

The neutron radiography technique (NR) with neutrons in the energy range fast to epithermal is a powerful tool used in no-destructive inspection of bulky objects of diverse materials, including those rich in hydrogen, oxygen, nitrogen ad carbon. Thus, it can be used to identify, inclusions, voids and thickness differences in materials such as explosive artifacts and narcotics. Aiming at using NR with fast and epithermal neutrons, an Irradiator was constructed by: a 241 Am-Be source, with 5 Ci activity, a collimator with adjustable collimation rate, L/D; and a shield device composed by plates of borated paraffin and iron. The test specimens chosen were a Beam Purity Indicator (BPI) and an Indicator of Visual Resolution (IVR). The neutron radiography images obtained had a resolution of 444.4 μm and 363.6 μm respectively when registered in: 1) the sheet of the nuclear track solid detector, CR-39 type, through X (n,p) Y nuclear reaction; and 2) Kodak Industrex M radiographic film plate in close contact with a boron converter screen, both stored in a Kodak radiographic cassette. (author)

Preservation and concentration of uranium mineralization in the crust of weathering

International Nuclear Information System (INIS)

Ashikhmin, A.A.; Kuznetsov, S.V.; Shmarovich, E.M.

1983-01-01

Inprecision of the concept on indispensable evacuation of U from ores during formation of the crust of weathering of lateritic or kaolinitic profile due to the existence of oxidative situation in the crusts is established. At hydrothermal uranium deposit in Eocambrian sandy-shaly and Paleozoic volcanogenous-sedimentary rocks a high degree of mineralization preservation in lower and medium horizons of Mesozoic-Cenozoic hydro-micaceous-kaolinitic crust of weathering, characterized by reductive situation, presence of carbonaceous substance, pyrite and siderite, is established. Mineralization attained there black composition and was additionally enriched with uranium. A supposition is made that the case is specific for the development of lateritic and kaolinitic crust formation according to ore-bearing rocks, rich in reducing agents-carbonaceous substances, sulfides and minerals of protoxidic iron. The data obtained should be taken into account during prediction and prospecting activities

Effect of carbo-nitride-rich and oxide-rich inclusions on the pitting susceptibility of depleted uranium

International Nuclear Information System (INIS)

Pu, Zhen; Chen, Xianglin; Meng, Xiandong; Wu, Yanping; Shen, Liang; Wang, Qingfu; Liu, Tianwei; Shuai, Maobing

2017-01-01

Highlights: •The Volta potential differences relative to the matrix are positive for both types of inclusions. •Both types of inclusions are cathodic in the “inclusion/matrix” microgalvanic couples. •The oxide-rich inclusions show a larger Volta potential value of about 115 mV than the carbo-nitride-rich inclusions. •The oxide-rich inclusions give stronger local galvanic coupling with the matrix. •The oxide-rich inclusions are more predisposed to initiate pitting corrosion. -- Abstract: The effects of carbo-nitride-rich and oxide-rich inclusions on the pitting susceptibility of depleted uranium were investigated by electrochemical corrosion measurements, optical microscopy, scanning Kelvin probe force microscopy (SKPFM), and SEM. The results of the potentiodynamic polarization tests suggest that oxide-rich inclusions are more likely to induce pitting corrosion than carbo-nitride-rich inclusions. This enhanced corrosion may be explained by the strong local galvanic coupling between the oxide-rich inclusion and the surrounding matrix, which, from the sight of SKPFM analysis, exhibits a 115 V higher Volta potential than the coupling between the carbo-nitride-rich inclusions and the matrix, respectively.

Status report on the development of a prompt fission neutron uranium borehole logging technique

International Nuclear Information System (INIS)

Smith, G.W.

1977-05-01

The prompt fission neutron (PFN) method of direct uranium measurement was studied. The PFN uranium logging technique measures the enhanced epithermal neutron population created by the prompt thermal fission of 235 U to assay uranium mineralization around a borehole. This neutron population exists for several hundred microseconds after a pulsed neutron source produces a burst of high energy (14 MeV) neutrons. A feasibility study established the basic relationship between the uranium concentration and the enhanced epithermal neutron count, and defined the major measurement perturbing factors. Following the feasibility study, development of a PFN prototype field probe was undertaken. A laboratory type neutron generator, the Controlatron, was modified for use in the probe. Field evaluation of the prototype system began in January 1976. Comparisons of neutron logs and natural gamma logs taken during this evaluation period clearly define many disequilibrium conditions as verified by ore grade estimates from core samples. The feasibility of the PFN logging technique to detect uranium in-situ has now been demonstrated

National uranium resource evaluation: Williams quadrangle, Arizona

International Nuclear Information System (INIS)

O'Neill, A.J.; Nystrom, R.J.; Thiede, D.S.

1981-03-01

Geologic environments of the Williams Quadrangle, Arizona, were evaluated for uranium favorability by means of literature research, uranium-occurrence investigation and other surface studies, subsurface studies, aerial radiometric data, hydrogeochemical data, and rock-sample analytic data. Favorability criteria are those of the National Uranium Resource Evaluation program. Three geologic environments are favorable for uranium: the Tertiary fluvial rocks of the Colorado Plateau where they unconformably overlie impermeable bed rock (for channel-controlled peneconcordant deposits); collapse breccia pipes in Paleozoic strata of the Colorado Plateau (for vein-type deposits in sedimentary rocks); and Precambrian crystalline rocks of the Hualapai, Peacock, and Aquarius Mountains, and Cottonwood and Grand Wash Cliffs (for magmatic-hydrothermal deposits). Unfavorable geologic environments are: Tertiary and Quaternary volcanic rocks, Tertiary and Quaternary sedimentary rocks of the Colorado Plateau, nearly all Paleozoic and Mesozoic sedimentary rocks, and the Precambrian-Cambrian unconformity of the Grand Wash Cliffs area. Tertiary rocks in Cenozoic basins and Precambrian crystalline rocks in the Grand Canyon region and in parts of the Aquarius Mountains and Cottonwood and Grand Wash Cliffs are unevaluated

Growth and alteration of uranium-rich microlite

International Nuclear Information System (INIS)

Giere, R.; Swope, R. J.; Buck, E. C.; Guggenheim, R.; Mathys, D.; Reusser, E.

2000-01-01

Uranium-rich microlite, a pyrochlore-group mineral, occurs in 440 Ma old lithium pegmatites of the Mozambique Belt in East Africa. Microlite exhibits a pronounced growth zoning, with a U-free core surrounded by a U-rich rim (UO 2 up to 17 wt.%). The core exhibits conjugate sets of straight cracks (cleavage planes) which provided pathways for a late-stage U-enriched pegmatitic fluid which interacted with the U-free microlite to produce a distinct U enrichment along the cracks and led to the formation of the U-rich rim. Following the stage of U incorporation into microlite, a second generation of hydrothermal fluids deposited mica along the cleavage planes. Subsequent to these two hydrothermal stages, the host rock was uplifted and subjected to intense low-temperature alteration during which Na, Ca and F were leached from the microlite crystals. This alteration also led to a hydration of microlite, but there is no evidence of U loss. These low-temperature alteration effects were only observed in the U-rich rim which is characterized by a large number of irregular cracks which are most probably the result of metamictization, as indicated by electron diffraction images and powder X-ray patterns. The pyrochlore-group minerals provide excellent natural analogues for pyrochlore-based nuclear waste forms, because samples of variable age and with high actinide contents are available

Method of assaying uranium with prompt fission and thermal neutron borehole logging adjusted by borehole physical characteristics

International Nuclear Information System (INIS)

Barnard, R.W.; Jensen, D.H.

1982-01-01

Uranium formations are assayed by prompt fission neutron logging techniques. The uranium in the formation is proportional to the ratio of epithermal counts to thermal or eqithermal dieaway. Various calibration factors enhance the accuracy of the measurement

Epithermal neutron instrumentation at ISIS

International Nuclear Information System (INIS)

Gorini, G; Festa, G; Andreani, C

2014-01-01

The advent of pulsed neutron sources makes available high epithermal neutron fluxes (in the energy range between 500 meV and 100 eV). New dedicated instrumentation, such as Resonance Detectors, was developed at ISIS spallation neutron source in the last years to apply the specific properties of this kind of neutron beam to the study of condensed matter. New detection strategies like Filter Difference method and Foil Cycling Technique were also developed in parallel to the detector improvement at the VESUVIO beamline. Recently, epithermal neutron beams were also used at the INES beamline to study elemental and isotopic composition of materials, with special application to cultural heritage studies. In this paper we review a series of epithermal neutron instrumentation developed at ISIS, their evolution over time and main results obtained

Telescoped porphyry-style and epithermal veins and alteration at the central Maratoto valley prospect, Hauraki Goldfield, New Zealand

International Nuclear Information System (INIS)

Simpson, M.P.; Mauk, J.L.; Kendrick, R.G.

2004-01-01

At the central Maratoto valley prospect, southern Coromandel Peninsula, New Zealand, andesite flows and dacite breccias host rare porphyry-style quartz veins that are telescoped by widespread epithermal veins and alteration. Early porphyry-style quartz veins, which lack selvages of porphyry-style alteration, host hypersaline fluid inclusions that contain several translucent daughter crystals, including halite and sylvite. Overprinting epithermal veins and alteration are divided into two stages. Main-stage epithermal alteration and veins are characterised by the successive deposition of pyrite, quartz, and ankerite-dolomite veinlets coupled with intense alteration of the wall rock to quartz, illite, interlayer illite-smectite (≤ 10% smectite), chlorite, pyrite, ankerite, and dolomite. Late-stage epithermal veins and alteration are characterised by the formation of calcite and siderite veinlets, coupled with overprinting of the wall rocks by both these minerals. Multiphase fluid inclusions in a porphyry-style quartz vein formed at temperatures >400 degrees C and trapped hypersaline magmatic fluid. Lower temperature secondary liquid-rich inclusions in the porphyry-style quartz vein homogenise between 283 and 329 degrees C and trapped a dilute fluid with 18 O (VSMOW) values of 13.5-18.1 permille, whereas late-stage epithermal calcite has δ 18 O (VSMOW) values of 3.1-5.1 permille. Calculated isotopic compositions for the fluid in equilibrium with ankerite-dolomite and calcite at 260 degrees C, averages 6 and -3 permille, respectively. The enriched value for main-stage ankerite-dolomite suggests formation from waters that underwent significant water-rock exchange, whereas isotopically lighter water that formed late-stage calcite underwent little water-rock interaction. We propose a three-stage model to explain telescoped veins and alteration styles at the central Maratoto valley prospect area. Porphyry-style quartz veins were the first to form from hot hypersaline

Polarized epithermal neutron spectrometer at KENS

International Nuclear Information System (INIS)

Kohgi, M.

1983-01-01

A spectrometer employing a white, epithermal, polarized neutron beam is under construction at KENS. The neutron polarization is achieved by passage through a dynamically polarized proton filter (DPPF). The results of the test experiments show that the DPPF method is promising in obtaining polarized epithermal neutron beam. The basic design of the spectrometer is described

Effects of gamma-sterilization on DOC, uranium and arsenic remobilization from organic and microbial rich stream sediments

International Nuclear Information System (INIS)

Schaller, Joerg; Weiske, Arndt; Dudel, E. Gert

2011-01-01

Organic-rich sediments are known to be effective accumulators for uranium and arsenic. Much is known about the capacity for metal or metalloid fixation by microbes and organic compounds as well as inorganic sediment particles. Experiments investigating the effect of microbes on the process of metal fixation in sediments require sterilized sediments as control treatment which is often realized by gamma-sterilization. Only few studies show that gamma-sterilization has an effect on the remobilization of metal and metalloids and on their physico-chemical properties. These studies deal with sediments with negligible organic content whereas almost nothing is known about organic-rich sediments including a probably high microbial activity. In view of this, we investigated the effect of gamma-sterilization of organic-rich sediments on uranium and arsenic fixation and release. After ten days within an exposure experiment we found a significant higher remobilization of uranium and arsenic in sterile compared to unsterile treatments. In line with these findings the content of dissolved organic carbon (DOC), manganese, and iron increased to even significantly higher concentration in the sterile compared to unsterile treatment. Gamma-sterilization seems to change the physico-chemical properties of organic-rich sediments. Microbial activity is effectively eliminated. From increased DOC concentrations in overlaying water it is concluded that microbes are eventually killed with leaching of cellular compounds in the overlaying water. This decreases the adsorption capacity of the sediment and leads to enhanced uranium and arsenic remobilization. - Research highlight s : →Remobilization of uranium and arsenic is higher in gamma-sterile treatments. →DOC mobilization is also higher in sterilized treatment. →Adsorption capacity in sediments is reduced by release of DOC.

Radon levels in houses and workplaces in a uranium rich region in Spain

International Nuclear Information System (INIS)

Quindos Poncela, L.S.; Fernandez Navarro, P.L.; Gomez Arozamena, J.; Lopez Romero, A.

1997-01-01

The results of a study of the evaluation of the doses per inhalation of radon in a population from a region of Spain rich in uranium is compared with those of workers of a mining installation in the region

Comparison of Cadmium-Zinc-Telluride semiconductor and Yttrium-Aluminum-Perovskite scintillator as photon detectors for epithermal neutron spectroscopy

International Nuclear Information System (INIS)

Tardocchi, M.; Pietropaolo, A.; Andreani, C.; Gorini, G.; Imberti, S.; Perelli-Cippo, E.; Senesi, R.; Rhodes, N.; Schooneveld, E.M.

2006-01-01

The range of applications of epithermal neutron scattering experiments has been recently extended by the development of the Resonance Detector. In a Resonance Detector, resonant neutron absorption in an analyzer foil results in prompt emission of X- and γ-rays which are detected by a photon counter. Several combinations of analyzer foils and photon detectors have been studied and tested over the years and best results have been obtained with the combination of a natural uranium and (i) Cadmium-Zinc-Telluride (CZT) semiconductor (ii) Yttrium-Aluminum-Perovskite (YAP) scintillators. Here we compare the performance of the CZT semiconductor and YAP scintillator as Resonance Detector units. Two Resonance Detector prototypes made of natural uranium foil viewed by CZT and YAP were tested on the VESUVIO spectrometer at the ISIS spallation neutron source. The results show that both YAP and CZT can be used to detect epithermal neutrons in the energy range from 1 up to 66 eV. It was found that the signal-to-background ratio of the measurement can significantly be improved by raising the lower level discrimination threshold on the γ energy to about 600 keV. The advantages/disadvantages of the choice of a Resonance Detector based on YAP or CZT are discussed together with some potential applications

Microstructural investigation of as-cast uranium rich U–Zr alloys

Energy Technology Data Exchange (ETDEWEB)

Zhang, Yuting, E-mail: zhangyuting@caep.cn [Science and Technology on Surface Physics and Chemistry Laboratory, Jiangyou 621908, Sichuan (China); School of Nuclear Science and Technology, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, Anhui (China); Wang, Xin [Science and Technology on Surface Physics and Chemistry Laboratory, Jiangyou 621908, Sichuan (China); Zeng, Gang [Institute of Materials, China Academy of Engineering Physics, Jiangyou 621908, Sichuan (China); Wang, Hui [Science and Technology on Surface Physics and Chemistry Laboratory, Jiangyou 621908, Sichuan (China); Jia, Jianping [Institute of Materials, China Academy of Engineering Physics, Jiangyou 621908, Sichuan (China); Sheng, Liusi [School of Nuclear Science and Technology, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, Anhui (China); Zhang, Pengcheng, E-mail: zpc113@sohu.com [Science and Technology on Surface Physics and Chemistry Laboratory, Jiangyou 621908, Sichuan (China)

2016-04-01

The present study evaluates the microstructure in as-cast uranium rich U–Zr alloys, an important subsystem of U–Pu–Zr ternary metallic nuclear reactor fuel, as a function of the Zr content, from 2wt.% to 15wt.%Zr. It has been previously suggested that the unique intermetallic compound δ phase in U–Zr alloys is only present in as-cast U–Zr alloys with a Zr content exceeding 10wt.%Zr. However, our analysis of transmission electron microscopy (TEM) data shows that the δ phase is common to all as-cast alloys studied in this work. Furthermore, specific coherent orientation relationship is found between the α and δ phases, consistent with previous findings, and a third variant is discovered in this paper. - Highlights: • Initially, lattice parameter of as-cast U–Zr alloys decrease with the increasing Zr content, and then increase. • XRD data show the presence of δ-UZr{sub 2} phase in as-cast U–Zr alloys with a Zr content of more than 8wt.% Zr. • Finding δ-UZr{sub 2} phase exists in all as-cast uranium rich U–Zr alloys, even for alloys with a lean Zr content. • Three kinds of preferential orientations of the δ phase grow.

Favourable environments for uranium occurences in Brazil

International Nuclear Information System (INIS)

Santos, L.C.S. dos

1980-01-01

Based on the present knowledge of Brazilian Precambrian geology, an attempt is made to divide Precambrian rocks into different regions according to their favourability criteria for uranium concentrations. Paleozoic and Mesozoic occurrences are also mentioned. They are mainly associated with large sedimentary basins. Brazilian uranium occurrences can be grouped into the following environments: (1) Metaconglomerates; (2) Metasomatic rocks (associated with albitization); (3) Vein type; (4) Sandstone type and (5) Intrusive alkalic rock. Upper Proterozoicas folding regions related to mobile belts and large Precambrian unconformities are good targets for uranium exploration in Brazil. (Author) [pt

Analysis and exploitation of bacterial population from natural uranium-rich soils: selection of a model specie

International Nuclear Information System (INIS)

Mondani, L.

2010-01-01

It is well known that soils play a key role in controlling the mobility of toxic metals and this property is greatly influenced by indigenous bacterial communities. This study has been conducted on radioactive and controls soils, collected in natural uraniferous areas (Limousin). A physico-chemical and mineralogical analysis of soils samples was carried out.The structure of bacterial communities was estimated by Denaturing Gradient Gel Electrophoresis (DGGE). The community structure is remarkably more stable in the uranium-rich soils than in the control ones, indicating that uranium exerts a high selection from the soils was constructed and screened for uranium resistance in order to study bacteria-uranium interactions. Scanning electron microscopy revealed that a phylo-genetically diverse set of uranium-resistant species ware able to chelate uranium at the cell surface. (author) [fr

Behavior studies of natural uranium radioactive families descendants in organic rich sediments: the sapropels

International Nuclear Information System (INIS)

Gourgiotis, A.

2008-06-01

The element uranium with the particular oxido-reducing properties is often associated with environments rich in organic matter; this is why several authors have proposed to use it as tracer of paleo-productivity in marine sediments. This work describes the distribution of the uranium natural families' radionuclides in organic rich Mediterranean sediments: the sapropels. Several techniques of measurements were used such as mass spectrometry (TIMS, ICP-QMS), alpha and gamma spectrometry. Activity ratios 234 U/ 238 U as well as the ages U-Th of the sapropels present irregular profiles which do not correspond to the assumptions which had been made to explain their formation. Using an 1D diffusion model we have showed that these profiles result from the migration of the radionuclides out of the sapropels. We validated these observations by analyzing several levels of sapropels presenting a spatio-temporal variability. Our study confirms the migration of radiogenic uranium 234 U rad , which is produced in situ by his father the 238 U, as well as the migration of the 226 Ra. However the mobility of radiogenic uranium ( 234 U rad ) is not sufficient to explain the drift of the 230 Th/ 238 U and 231 Pa/ 235 U activity ratios in the S5 sapropel. An important result is that authigenic uranium also migrates, but with lower effective diffusion coefficients than those of the 234 U rad . Because of this mobility, the use of U authigenic of the sediments as an indicator of paleo-productivity must thus be used with precaution. (author)

Pulsed neutron uranium borehole logging with prompt fission neutrons

International Nuclear Information System (INIS)

Bivens, H.M.; Smith, G.W.; Jensen, D.H.

1976-01-01

The gross count natural gamma log normally used for uranium borehole logging is seriously affected by disequilibrium. Methods for the direct measurement of uranium, such as neutron logging, which are not affected by disequilibrium have been the object of considerable effort in recent years. This paper describes a logging system for uranium which uses a small accelerator to generate pulses of 14 MeV neutrons to detect and assay uranium by the measurement of prompt fission neutrons in the epithermal energy range. After an initial feasibility study, a prototype logging probe was built for field evaluation which began in January 1976. Physical and operational characteristics of the prototype probe, the neutron tube-transformer assembly, and the neutron tube are described. In logging operations, only the epithermal prompt fission neutrons detected between 250 microseconds to 2500 microseconds following the excitation neutron pulse are counted. Comparison of corrected neutron logs with the conventional gross count natural gamma logs and the chemical assays of cores from boreholes are shown. The results obtained with this neutron probe clearly demonstrate its advantages over the gross count natural gamma log, although at this time the accuracy of the neutron log assay is not satisfactory under some conditions. The necessary correction factors for various borehole and formation parameters are being determined and, when applied, should improve the assay accuracy

Upper Paleozoic Marine Shale Characteristics and Exploration Prospects in the Northwestern Guizhong Depression, South China

Science.gov (United States)

Zhu, Zhenhong; Yao, Genshun; Lou, Zhanghua; Jin, Aimin; Zhu, Rong; Jin, Chong; Chen, Chao

2018-05-01

Multiple sets of organic-rich shales developed in the Upper Paleozoic of the northwestern Guizhong Depression in South China. However, the exploration of these shales is presently at a relatively immature stage. The Upper Paleozoic shales in the northwestern Guizhong Depression, including the Middle Devonian Luofu shale, the Nabiao shale, and the Lower Carboniferous Yanguan shale, were investigated in this study. Mineral composition analysis, organic matter analysis (including total organic carbon (TOC) content, maceral of kerogen and the vitrinite reflection (Ro)), pore characteristic analysis (including porosity and permeability, pore type identification by SEM, and pore size distribution by nitrogen sorption), methane isothermal sorption test were conducted, and the distribution and thickness of the shales were determined, Then the characteristics of the two target shales were illustrated and compared. The results show that the Upper Paleozoic shales have favorable organic matter conditions (mainly moderate to high TOC content, type I and II1 kerogen and high to over maturity), good fracability potential (brittleness index (BI) > 40%), multiple pore types, stable distribution and effective thickness, and good methane sorption capacity. Therefore, the Upper Paleozoic shales in the northern Guizhong Depression have good shale gas potential and exploration prospects. Moreover, the average TOC content, average BI, thickness of the organic-rich shale (TOC > 2.0 wt%) and the shale gas resources of the Middle Devonian shales are better than those of the Lower Carboniferous shale. The Middle Devonian shales have better shale gas potential and exploration prospects than the Lower Carboniferous shales.

Research on deeply purifying effluent from uranium mining and metallurgy to remove uranium by ion exchange. Pt.2: Elution uranium from lower loaded uranium resin by the intense fractionation process

International Nuclear Information System (INIS)

Zhang Jianguo; Chen Shaoqiang; Qi Jing

2002-01-01

Developing macroporous resin for purifying uranium effluent from uranium mining and metallurgy is presented. The Intense Fractionation Process is employed to elute uranium from lower loaded uranium resin by the eluent of sulfuric acid and ammonium sulfate. The result is indicated that the uranium concentration in the rich elutriant is greatly increased, and the rich liquor is only one bed column volume, uranium concentration in the elutriant is increased two times which concentration is 10.1 g/L. The eluent is saved about 50% compared with the conventional fixed bed elution operation. And also the acidity in the rich elutriant is of benefit to the later precipitation process in uranium recovery

Uranium logging in earth formations

International Nuclear Information System (INIS)

Givens, W.W.

1979-01-01

A technique is provided for assaying the formations surrounding a borehole for uranium. A borehole logging tool cyclically irradiates the formations with neutrons and responds to neutron fluxes produced during the period of time that prompt neutrons are being produced by the neutron fission of uranium in the formations. A borehole calibration tool employs a steady-state (continuous output) neutron source, firstly, to produce a response to neutron fluxes in models having known concentrations of uranium and, secondly, to to produce a response to neutron fluxes in the formations surrounding the borehole. The neutron flux responses of the borehole calibration tool in both the model and the formations surrounding the borehole are utilized to correct the neutron flux response of the borehole logging tool for the effects of epithermal/thermal neutron moderation, scattering, and absorption within the borehole itself

High temperature chlorination of uranium and some radionuclides from rich sulphide ores

International Nuclear Information System (INIS)

Mahdy, M.A.

1992-01-01

This work is concerned with the application of the high temperature chlorination technique upon a sulphide-rich uranium ore from elliot lake, ontario, canada. The purpose is to find a substitute to conventional sulphuric acid leaching which involves both acid drainage and radionuclide dissolution problems. Test work has therefore been directed towards studying some relevant factors of chlorination beside the effect of a number of additives

National Uranium Resource Evaluation. Aerial gamma ray and magnetic survey, Tawas City and Flint quadrangles, Michigan. Final report

International Nuclear Information System (INIS)

1981-07-01

The Tawas City and Flint quadrangles of Michigan cover a land area of 6500 square miles, and an additional water surface area of 7200 square miles. Extremely thick Paleozoic deposits overlie a regional downwarp of the Precambrian basement called the Michigan Basin. These Paleozoic deposits shoal to only 1500 feet in the northeast corner. The entire survey area is covered by a mantle of Quaternary glacial material. A search of available literature revealed no economically feasible uranium deposits. Thirty-five uranium anomalies were detected and are discussed briefly. All appear to have cultural, and/or locally unsaturated associations, and none appear to contain significant measured quantities of uranium. Magnetic data appear to be in good agreement with existing structural interpretations of the area

Method and apparatus for epithermal neutron porosity well logging

International Nuclear Information System (INIS)

Hertzog, R.C.; Loomis, W.A.; Wraight, P.

1991-01-01

This patent describes a method for investigating the porosity of a subsurface earth formation surrounding a borehole. It comprises repetitively irradiating the borehole and earth formation with discrete bursts of high energy neutrons from a neutron source, which neutrons interact with nuclei of the materials in the borehole and the formation to produce therein populations of epithermal neutrons; detecting the populations of epithermal neutrons at near and far locations in the borehole spaced apart longitudinally by different distances from the neutron source; generating count signals indicative of the magnitudes of the detected epithermal neutron populations at the respective near and far locations; detecting the decay of the epithermal neutron populations following the neutron bursts at least at one location in the borehole and generating signals representative thereof; deriving from the decay signals a signal indicative of the slowing down time of epithermal neutrons in the formation of the at least one location; and deriving from the near and far count signals and the slowing down time signal a measurement signal representative of the porosity of the formation surrounding the borehole inherently compensated for the effects of tool standoff on the responses of the logging tool

Naturally Occurring Radioactive Materials in Uranium-Rich Coals and Associated Coal Combustion Residues from China.

Science.gov (United States)

Lauer, Nancy; Vengosh, Avner; Dai, Shifeng

2017-11-21

Most coals in China have uranium concentrations up to 3 ppm, yet several coal deposits are known to be enriched in uranium. Naturally occurring radioactive materials (NORM) in these U-rich coals and associated coal combustion residues (CCRs) have not been well characterized. Here we measure NORM (Th, U, 228 Ra, 226 Ra, and 210 Pb) in coals from eight U-rich coal deposits in China and the associated CCRs from one of these deposits. We compared NORM in these U-rich coals and associated CCRs to CCRs collected from the Beijing area and natural loess sediments from northeastern China. We found elevated U concentrations (up to 476 ppm) that correspond to low 232 Th/ 238 U and 228 Ra/ 226 Ra activity ratios (≪1) in the coal samples. 226 Ra and 228 Ra activities correlate with 238 U and 232 Th activities, respectively, and 226 Ra activities correlate well with 210 Pb activities across all coal samples. We used measured NORM activities and ash yields in coals to model the activities of CCRs from all U-rich coals analyzed in this study. The activities of measured and modeled CCRs derived from U-rich coals exceed the standards for radiation in building materials, particularly for CCRs originating from coals with U > 10 ppm. Since beneficial use of high-U Chinese CCRs in building materials is not a suitable option, careful consideration needs to be taken to limit potential air and water contamination upon disposal of U- and Ra-rich CCRs.

Design of filtered epithermal neutron beams for BNC

International Nuclear Information System (INIS)

Greenwood, R.C.

1986-01-01

The design principles of filters (installed in nuclear reactors) to provide epithermal neutron beams suitable for use in 10 B Neutron Capture Therapy (BNCT) are reviewed. The goal of such filters is to provide epithermal neutron beams within an energy range of 1 keV to 30 keV with fluxes in excess of 5 x 10 8 neutrons/cm 2 .s, and having acceptably low contaminant fast neutron (> 30 keV) and gamma components. Filters considered for this application include 238 U, Sc, Fe/Al and Al/S. It is shown that in order to achieve a goal epithermal neutron flux of > 5 x 10 8 neutrons/cm 2 .s, such filters must be located in radial beam channels which view essentially the complete reactor core. Based on considerations of estimated epithermal fluxes, cost and availability of materials, and transmitted neutron energy spectrum, it is suggested that a filter consisting of elements of Al, S, Ti and V might prove to be an optimum design for BNCT applications. 13 references, 3 figures, 8 tables

National Uranium Resource Evaluation, Tonopah quadrangle, Nevada

International Nuclear Information System (INIS)

Hurley, B.W.; Parker, D.P.

1982-04-01

The Tonopah Quadrangle, Nevada, was evaluated using National Uranium Resource Evaluation criteria to identify and delineate areas favorable for uranium deposits. Investigations included reconnaissance and detailed surface geologic and radiometric studies, geochemical sampling and evaluation, analysis and ground-truth followup of aerial radiometric and hydrogeochemical and stream-sediment reconnaissance data, and subsurface data evaluation. The results of these investigations indicate environments favorable for hydroallogenic uranium deposits in Miocene lacustrine sediments of the Big Smoky Valley west of Tonopah. The northern portion of the Toquima granitic pluton is favorable for authigenic uranium deposits. Environments considered unfavorable for uranium deposits include Quaternary sediments; intermediate and mafic volcanic and metavolcanic rocks; Mesozoic, Paleozoic, and Precambrian sedimentary and metasedimentary rocks; those plutonic rocks not included within favorable areas; and those felsic volcanic rocks not within the Northumberland and Mount Jefferson calderas

Temperature imaging using epithermal neutrons

International Nuclear Information System (INIS)

Fowler, P.H.; Taylor, A.D.

1987-08-01

The paper concerns the temperature measurement of suitable targets, both remotely and non-invasively, using epithermal neutrons. The text was presented at the Neutron Resonance Radiography Workshop, Los Alamos, U.S.A., 1987. The technique is demonstrated for tantalum foils at different temperatures, using a pulsed beam of epithermal neutrons, at both Los Alamos and ISIS (United Kingdom). Results on the measured time-of-flight spectra and the tantalum resonances are presented. Beam properties and fluxes at ISIS are discussed. Features of the proposed detectors suitable for the temperature technique are outlined, along with the data analysis, the moving targets, the cyclic temperature variations and transients, and the usefulness of the technique. (U.K.)

National Uranium Resource Evaluation: Newcastle Quadrangle, Wyoming and South Dakota

International Nuclear Information System (INIS)

Santos, E.S.; Robinson, K.; Geer, K.A.; Blattspieler, J.G.

1982-09-01

Uranium resources of the Newcastle 1 0 x2 0 Quadrangle, Wyoming and South Dakota were evaluated to a depth of 1500 m (5000 ft) using available surface and subsurface geologic information. Many of the uranium occurrences reported in the literature and in reports of the US Atomic Energy Commission were located, sampled and described. Areas of anomalous radioactivity, interpreted from an aerial radiometric survey, were outlined. Areas favorable for uranium deposits in the subsurface were evaluated using gamma-ray logs. Based on surface and subsurface data, two areas have been delineated which are underlain by rocks deemed favorable as hosts for uranium deposits. One of these is underlain by rocks that contain fluvial arkosic facies in the Wasatch and Fort Union Formations of Tertiary age; the other is underlain by rocks containing fluvial quartzose sandstone facies of the Inyan Kara Group of Early Cretaceous age. Unfavorable environments characterize all rock units of Tertiary age above the Wasatch Formation, all rock units of Cretaceous age above the Inyan Kara Group, and most rock units of Mesozoic and Paleozoic age below the Inyan Kara Group. Unfavorable environments characterize all rock units of Cretaceous age above the Inyan Kara Group, and all rock units of Mesozoic and Paleozoic age below the Inyan Kara Group

National Uranium Resource Evaluation: Newcastle Quadrangle, Wyoming and South Dakota

Energy Technology Data Exchange (ETDEWEB)

Santos, E S; Robinson, K; Geer, K A; Blattspieler, J G

1982-09-01

Uranium resources of the Newcastle 1/sup 0/x2/sup 0/ Quadrangle, Wyoming and South Dakota were evaluated to a depth of 1500 m (5000 ft) using available surface and subsurface geologic information. Many of the uranium occurrences reported in the literature and in reports of the US Atomic Energy Commission were located, sampled and described. Areas of anomalous radioactivity, interpreted from an aerial radiometric survey, were outlined. Areas favorable for uranium deposits in the subsurface were evaluated using gamma-ray logs. Based on surface and subsurface data, two areas have been delineated which are underlain by rocks deemed favorable as hosts for uranium deposits. One of these is underlain by rocks that contain fluvial arkosic facies in the Wasatch and Fort Union Formations of Tertiary age; the other is underlain by rocks containing fluvial quartzose sandstone facies of the Inyan Kara Group of Early Cretaceous age. Unfavorable environments characterize all rock units of Tertiary age above the Wasatch Formation, all rock units of Cretaceous age above the Inyan Kara Group, and most rock units of Mesozoic and Paleozoic age below the Inyan Kara Group. Unfavorable environments characterize all rock units of Cretaceous age above the Inyan Kara Group, and all rock units of Mesozoic and Paleozoic age below the Inyan Kara Group.

National uranium resource evaluation, Rapid City Quadrangle, South Dakota

International Nuclear Information System (INIS)

Nanna, R.F.; Milton, E.J.

1982-04-01

The Rapid City (1 0 x 2 0 ) Quadrangle, South Dakota, was evaluated for environments favorble for uranium deposits to a depth of 1500 m. Criteria used were those of the National Uranium Resource Evaluation. Field reconnaissance involved the use of hand-held scintillometers to investigate uranium occurrences reported in the literature and anomalies in aerial radiometric surveys, and geochemical samples of stream sediments and well waters. Gamma-ray logs were used to define the favorable environments in the subsurface. Environments favorable for sandstone-type uranium deposits occur in the Inyan Kara Group, the Fox Hills Sandstone, and the Hell Creek Formation. Environments considered unfavorable for uranium deposits include all Precambrian, Paleozoic, Mesozoic, and Tertiary rocks other than those identified as favorable

Central Paleozoic prehistory of Vilyuyskiy syneclise

Energy Technology Data Exchange (ETDEWEB)

Ul' mesvay, F S

1981-01-01

Based on a study of lithological features of the central Paleozoic deposits of the Ygyattinskiy and Kempendyayskiy Basins, a comparison plan is developed. The main features of the middle Paleozoic history of the region are clarified. Their affiliation to a single structure of the avlakogen type is established. Based on the proximity of rock associations and time for development, a similarity of the studied region and the Pripyatskiy-Donets avlakogen has been established. A conclusion is drawn about the possible productivity of the middle Paleozoic deposits.

Determination of the thermal and epithermal neutron sensitivities of an LBO chamber

Energy Technology Data Exchange (ETDEWEB)

Endo, Satoru; Kotani, Kei; Kajimoto, Tsuyoshi; Tanaka, Kenichi [Hiroshima University, Quantum Energy Applications, Graduate School of Engineering, Higashi-Hiroshima (Japan); Sato, Hitoshi; Nakajima, Erika [Ibaraki Prefectural University of Health Science, Radiological Sciences, Ibaraki (Japan); Shimazaki, Takuto [Hiroshima University, Quantum Energy Applications, Graduate School of Engineering, Higashi-Hiroshima (Japan); Delta Kogyo Co., Ltd., Hiroshima (Japan); Suda, Mitsuru; Hamano, Tsuyoshi [National Institute of Radiological Sciences, Chiba-Shi, Chiba (Japan); Hoshi, Masaharu [Hiroshima University, Institute for Peace Science, Hiroshima (Japan)

2017-08-15

An LBO (Li{sub 2}B{sub 4}O{sub 7}) walled ionization chamber was designed to monitor the epithermal neutron fluence in boron neutron capture therapy clinical irradiation. The thermal and epithermal neutron sensitivities of the device were evaluated using accelerator neutrons from the {sup 9}Be(d, n) reaction at a deuteron energy of 4 MeV (4 MeV d-Be neutrons). The response of the chamber in terms of the electric charge induced in the LBO chamber was compared with the thermal and epithermal neutron fluences measured using the gold-foil activation method. The thermal and epithermal neutron sensitivities obtained were expressed in units of pC cm{sup 2}, i.e., from the chamber response divided by neutron fluence (cm{sup -2}). The measured LBO chamber sensitivities were 2.23 x 10{sup -7} ± 0.34 x 10{sup -7} (pC cm{sup 2}) for thermal neutrons and 2.00 x 10{sup -5} ± 0.12 x 10{sup -5} (pC cm{sup 2}) for epithermal neutrons. This shows that the LBO chamber is sufficiently sensitive to epithermal neutrons to be useful for epithermal neutron monitoring in BNCT irradiation. (orig.)

Tracking the multi-stage exhumation history of the western Chinese Tianshan by Apatite Fission Track (AFT) dating - Implications for the preservation of epithermal deposits in ancient orogenic belt

Science.gov (United States)

Wang, Yannan; Cai, Keda

2017-04-01

The western Chinese Tianshan, located in the southern domain of the Central Asian Orogenic Belt (CAOB), was originally constructed by multiple accretion-collision processes in the Paleozoic, and was superimposed by complex intracontinental tectonic evolution in the Mesozoic-Cenozoic. Understanding the timing and mechanism of the latter geological processes is critical to unravel the preservation conditions of the epithermal deposits in the western Chinese Tianshan. This work presents new apatite fission track (AFT) data for three mountain ranges of the western Chinese Tianshan to track their exhumation history. Our AFT data gave a wide range of ages from 76.8 ± 5.5 Ma to 182.3 ± 9.9 Ma, and the mean confined fission track lengths are between 9.8 ± 0.5 μm and 12.3 ± 0.2 μm. The new data, in combination with the thermal history modeling，enable us to attribute the exhumation history to three primary stages, including Early Permian (300-280 Ma), Late Triassic-Early Cretaceous (230-130 Ma), and Late Oligocene-Early Miocene (30-20 Ma). The first stage may be caused by the terrane accretion-collision in the late Paleozoic. The second stage was likely related to the closure of the Mongol-Okhotsk Ocean during the Mesozoic. The last one is regarded as the result of the collision between the Indian Plate and the Eurasia Plate in the Cenozoic. The extraordinary exhumation processes of these three major mountain ranges might have been responsible for sediment supply to the corresponding intra-mountain basins in the western Chinese Tianshan, and the particularly mountain-basin coupling evolution is ascribed to an essential condition for the preservation of epithermal deposits in ancient orogenic belt.

The Measurement of Epithermal-to-Thermal U-238 Neutron Capture Rate in Aagesta Power Reactor Fuel

Energy Technology Data Exchange (ETDEWEB)

Bernander, G

1967-09-15

The epithermal-to-thermal neutron capture rate ratio {rho}{sub 28} in U-238 in Aagesta fuel has been measured by the chemical separation method. The method involves the isolation of Np-239 from uranium and fission products by reversed phase partition chromatography. Although somewhat elaborate, and in spite of difficulties with residual fission products, the method has yielded reasonably accurate results. Further development work on chemical procedures may lead to some improvement. A comparison with the coincidence method - electronic separation of activities - has not shown any large systematic differences between the two methods. The separation of the epithermal U-235 activation from the total has been achieved by means of the '1/v subtraction technique' using copper foils as the 1/v monitor. The complementary thermal column irradiations required have been performed in the research reactors TRIGA (Helsinki) and R1 (Stockholm). From the measured {rho}{sub 28} values the resonance escape probability (p) and the initial conversion ratio (ICR) may be calculated using cross-section data and other lattice parameters. Comparisons with theoretical values of {rho} and ICR as calculated with the BURNUP lattice parameter code are favourable.

Contribution to the geochemical knowledge of the uranium-radium and thorium families in the southern Vosges. Applications of some results in the prospecting of uranium deposits

International Nuclear Information System (INIS)

Jurain, G.

1962-01-01

This work's aim is to lead to a more accurate knowledge of the geochemistry of the Uranium-Radium and Thorium families in the Southern Vosges and to apply some of the results to the prospecting of uraniferous deposits: It has been showed: a bond between Calcium-Magnesium and Uranium-Thorium in the calco-alkaline granites. The host minerals of Uranium and Thorium are hornblende, biotite, titanite and epidote. a concentration of Uranium, at present time with secular disequilibrium in a thermal zone where the satellite mineralizations form an epithermal paragenesis. a disequilibrium of the Uranium-Radium family in the supergene minerals of the lead (phosphate and vanadate) showing the present circulations of Uranium. a bond between the radon grade of the spring waters and Uranium-Radium of the rocks. Such a relation allow to realize a prospecting method based on the determination of radioactive gases from the cold spring-waters of a common country. (author) [fr

Measurement of epithermal neutrons by a coherent demodulation technique

CERN Document Server

Horiuchi, N; Takahashi, H; Kobayashi, H; Harasawa, S

2000-01-01

Epithermal neutrons have been measured using a neutron dosimeter via a coherent demodulation technique. This dosimeter consists of CsI(Tl)-photodiode scintillation detectors, four of which are coupled to neutron-gamma converting foils of various sizes. Neutron-gamma converting foils of In, Au and Co materials were used, each of which has a large capture cross section which peaks in the epithermal neutron energy region. The type of foil was selected according to the material properties that best correspond to the energy of the epithermal neutrons to be measured. In addition, the proposed technique was applied using Au-foils in order to measure the Cd ratio. The validity of the proposed technique was examined using an sup 2 sup 4 sup 1 Am-Be source placed in a testing stack of polyethylene blocks, and the results were compared with the theoretical values calculated by the Monte Carlo calculation. Finally, the dosimeter was applied for measuring epithermal neutrons and the Cd ratio in an experimental beam-tube o...

Uranium in fossil bones

International Nuclear Information System (INIS)

Koul, S.L.

1978-01-01

An attempt has been made to determine the uranium content and thus the age of certain fossil bones Haritalyangarh (Himachal Pradesh), India. The results indicate that bones rich in apatite are also rich in uranium, and that the radioactivity is due to radionuclides in the uranium series. The larger animals apparently have a higher concentration of uranium than the small. The dating of a fossil jaw (elephant) places it in the Pleistocene. (Auth.)

National uranium resource evaluation Prescott Quadrangle Arizona

International Nuclear Information System (INIS)

May, R.T.; White, D.L.; Nystrom, R.J.

1982-01-01

The Prescott Quadrangle was evaluated for uranium favorability by means of a literature search, examination of uranium occurrences, regional geochemical sampling of Precambrian rocks, limited rubidium-strontium studies, scintillometer traverses, measurement of stratigraphic sections, subsurface studies, and an aerial radiometric survey. A limited well-water sampling program for Cenozoic basins was also conducted. Favorability criteria used were those developed for the National Uranium Resource Evaluation. Five geologic environments are favorable for uranium. Three are in Tertiary rocks of the Date Creek-Artillery Basin, Big Sandy Valley, and Walnut Grove Basin. Two are in Precambrian rocks in the Bagdad and Wickenburg areas. Unfavorable areas include the southwestern crystalline terrane, the Paleozoic and Mesozoic beds, and metamorphic and plutonic Precambrian rocks of the Bradshaw and Weaver Mountains. Unevaluated areas are the basalt-covered mesas, alluvium-mantled Cenozoic basins, the Hualapai Mountains, and the Kellwebb Mine

Logging technique for assaying for uranium in earth formations

International Nuclear Information System (INIS)

Givens, W.W.; Mills, W.R. Jr.

1979-01-01

A borehole logging tool includes a source of fast neutrons, an epithermal neutron flux detector, and a thermal neutron flux detector. A count rate meter is connected to each detector. A ratio detector provides a signal indicative of the ratio of the count rates of the two detectors obtained during the time that prompt neutrons are emitted from neutron fission of uranium in the formation

Age and tectonomagmatic setting of the Eocene Çöpler-Kabataş magmatic complex and porphyry-epithermal Au deposit, East Central Anatolia, Turkey

Science.gov (United States)

İmer, Ali; Richards, Jeremy P.; Creaser, Robert A.

2013-06-01

The Çöpler epithermal Au deposit and related subeconomic porphyry Cu-Au deposit is hosted by the middle Eocene Çöpler-Kabataş magmatic complex in central eastern Anatolia. The intrusive rocks of the complex were emplaced into Late Paleozoic-Mesozoic metamorphosed sedimentary basement rocks near the northeastern margin of the Tauride-Anatolide Block. Igneous biotite from two samples of the magmatic complex yielded 40Ar/39Ar plateau ages of 43.75 ± 0.26 Ma and 44.19 ± 0.23, whereas igneous hornblende from a third sample yielded a plateau age of 44.13 ± 0.38. These ages closely overlap with 40Ar/39Ar ages of hydrothermal sericite (44.44 ± 0.28 Ma) and biotite (43.84 ± 0.26 Ma), and Re-Os ages from two molybdenite samples (44.6 ± 0.2 and 43.9 ± 0.2 Ma) suggesting a short-lived (history at Çöpler. No suitable minerals were found that could be used to date the epithermal system, but it is inferred to be close in age to the precursor porphyry system. The Çöpler-Kabataş intrusive rocks show I-type calc-alkaline affinities. Their normalized trace element patterns show enrichments in large ion lithophile and light rare earth elements and relative depletions in middle and heavy rare earth elements, resembling magmas generated in convergent margins. However, given its distance from the coeval Eocene Maden-Helete volcanic arc, the complex is interpreted to be formed in a back-arc setting, in response to Paleocene slab roll-back and upper-plate extension. The tectonomagmatic environment of porphyry-epithermal mineralization at Çöpler is comparable to some other isolated back-arc porphyry systems such as Bajo de la Alumbrera (Argentina) or Bingham Canyon (USA).

Epithermal neutron beam interference with cardiac pacemakers

International Nuclear Information System (INIS)

Koivunoro, H.; Serén, T.; Hyvönen, H.; Kotiluoto, P.; Iivonen, P.; Auterinen, I.; Seppälä, T.; Kankaanranta, L.; Pakarinen, S.; Tenhunen, M.; Savolainen, S.

2011-01-01

In this paper, a phantom study was performed to evaluate the effect of an epithermal neutron beam irradiation on the cardiac pacemaker function. Severe malfunction occurred in the pacemakers after substantially lower dose from epithermal neutron irradiation than reported in the fast neutron or photon beams at the same dose rate level. In addition the pacemakers got activated, resulting in nuclides with half-lives from 25 min to 115 d. We suggest that BNCT should be administrated only after removal of the pacemaker from the vicinity of the tumor.

Epithermal neutron beam interference with cardiac pacemakers

Energy Technology Data Exchange (ETDEWEB)

Koivunoro, H., E-mail: hanna.koivunoro@helsinki.fi [Department of Physics, P.O.B. 64, FI-00014 University of Helsinki (Finland)] [Department of Oncology, Helsinki University Central Hospital, P.O.B. 180, FIN-00029 HUS (Finland)] [Boneca Corporation, Finland, Filnland (Finland); Seren, T. [VTT Technical Research Centre of Finland (Finland); Hyvoenen, H. [Boneca Corporation, Finland, Filnland (Finland); Kotiluoto, P. [VTT Technical Research Centre of Finland (Finland); Iivonen, P. [St. Jude Medical (Finland); Auterinen, I. [VTT Technical Research Centre of Finland (Finland); Seppaelae, T.; Kankaanranta, L. [Department of Oncology, Helsinki University Central Hospital, P.O.B. 180, FIN-00029 HUS (Finland); Pakarinen, S. [Department of Cardiology, Helsinki University Central Hospital (Finland); Tenhunen, M. [Department of Oncology, Helsinki University Central Hospital, P.O.B. 180, FIN-00029 HUS (Finland); Savolainen, S. [HUS Helsinki Medical Imaging Center, Helsinki University Central Hospital (Finland)

2011-12-15

In this paper, a phantom study was performed to evaluate the effect of an epithermal neutron beam irradiation on the cardiac pacemaker function. Severe malfunction occurred in the pacemakers after substantially lower dose from epithermal neutron irradiation than reported in the fast neutron or photon beams at the same dose rate level. In addition the pacemakers got activated, resulting in nuclides with half-lives from 25 min to 115 d. We suggest that BNCT should be administrated only after removal of the pacemaker from the vicinity of the tumor.

Epithermal neutron activation analysis of food

International Nuclear Information System (INIS)

Zikovsky, L.; Soliman, K.

1999-01-01

Food samples were irradiated with thermal and epithermal neutrons. The average ratios of thermal to epithermal activity were determined for 80 Br, 49 Ca, 38 Cl, 60m Co, 42 K, 27 Mg, 56 Mn, 24 Na, and 86m Rb. They were equal to 2.1, 26, 24, 6.6, 19, 16, 11, 23 and 1.9, respectively. Then, 57 food samples were analyzed by epithermal neutron activation analysis for Br and Rb. The concentrations (in ppm) of Br and Rb were in asparagus (2) 2.3, 11.5; beets (3) 0.5, 0.8; beef (3) 1.7, 3.6; cabbage (5) 0.5, 10.8; carrot (3) 0.2, 3.7; chicken (3) 0.6, 4.4; chocolate (7) 11.1, 18.7; egg (3) 0.9, 1.9; french bean (3) 0.3, 1.0; goose (2) 1.3, 9.3; lettuce (2) 0.9, 1.7; pork (1) 1.5, 4.4; potato (7) 1.0, 1.2; sausage (3) 4.8, 3.5; spinach (3) 3.6, 4.0; strawberry jam (3) 0.4, 1.4; tomato (1) 13.5, 14.6; turkey (3) 1.2, 4.9. respectively. The number of samples and analyzed is indicated in parentheses. (author)

Physics of epi-thermal boron neutron capture therapy (epi-thermal BNCT).

Science.gov (United States)

Seki, Ryoichi; Wakisaka, Yushi; Morimoto, Nami; Takashina, Masaaki; Koizumi, Masahiko; Toki, Hiroshi; Fukuda, Mitsuhiro

2017-12-01

The physics of epi-thermal neutrons in the human body is discussed in the effort to clarify the nature of the unique radiologic properties of boron neutron capture therapy (BNCT). This discussion leads to the computational method of Monte Carlo simulation in BNCT. The method is discussed through two examples based on model phantoms. The physics is kept at an introductory level in the discussion in this tutorial review.

National Uranium Resource Evaluation: Durango Quadrangle, Colorado

International Nuclear Information System (INIS)

Theis, N.J.; Madson, M.E.; Rosenlund, G.C.; Reinhart, W.R.; Gardner, H.A.

1981-06-01

The Durango Quadrangle (2 0 ), Colorado, was evaluated using National Uranium Resource Evaluation criteria to determine environments favorable for uranium deposits. General reconnaissance, geologic and radiometric investigations, was augmented by detailed surface examination and radiometric and geochemical studies in selected areas. Eight areas favorable for uranium deposits were delineated. Favorable geologic environments include roscoelite-type vanadium-uranium deposits in the Placerville and Barlow Creek-Hermosa Creek districts, sandstone uranium deposits along Hermosa Creek, and vein uranium deposits in the Precambrian rocks of the Needle Mountains area and in the Paleozoic rocks of the Tuckerville and Piedra River Canyon areas. The major portions of the San Juan volcanic field, the San Juan Basin, and the San Luis Basin within the quadrangle were judged unfavorable. Due to lack of information, the roscoelite belt below 1000 ft (300 m), the Eolus Granite below 0.5 mi (0.8 km), and the Lake City caldera are unevaluated. The Precambrian Y melasyenite of Ute Creek and the Animas Formation within the Southern Ute Indian Reservation are unevaluated due to lack of access

Uranium distribution in Puerto Galera-San Teodoro, Northern Mindoro, Philippines

International Nuclear Information System (INIS)

Santos, G. Jr.; Seguis, J.E.

1982-09-01

Geochemical mapping of uranium in stream sediment with the use of delayed neutron activation analysis (DNAA) was conducted in northeastern Mindoro Island. Uranium was determined in stream sediments by means of an automated analysis system utilizing a neutron activation/delayed neutron counting technique. Stream sediments were collected at a density of less than one sample per 2 sq. km. A total of 428 samples were analyzed. The background and threshold uranium values were 2.6 ppm and 4.5 ppm, respectively. Three small anomalous localities were identified in areas underlain by Paleozoic (Carboniferous) Mindoro Metamorphics (undifferentiated schist and marble). Further exploration of these anomalous areas is warranted. (author)

Analysis on tectonomagmatic evolution and metallogenic geological conditions of rich-large uranium deposits in Nanling uranium-polymetal metallogenic belt, South Jiangxi province

International Nuclear Information System (INIS)

Chen Guihua

2001-01-01

Nanling is a complicated tectonomagmatic belt. It is also an important uranium-polymetallic metallogenic belt. On the basis of the research achievements of previous researchers, through the detailed stratigraphic, lithologic, litho-paleo-geographic, geochronologic and geochemical studies and the processing of gravimetric and magnetic data, as well as the information extraction of remote sensing data, the authors come to the following conclusions: (1) The Sannan-Xunwu fault is a long-lived (from the Early Sinian to recent time) EW-trending fault; (2) The earth crust in Nanling experienced three time opening-closing with different scales; (3) The Anyuan-Xunwu area is a large thermo-upwelling extensional structure; (4) The above area is considered to be favourable for the formation of rich-large uranium deposit

Electronic structure and fine structural features of the air-grown UNxOy on nitrogen-rich uranium nitride

Science.gov (United States)

Long, Zhong; Zeng, Rongguang; Hu, Yin; Liu, Jing; Wang, Wenyuan; Zhao, Yawen; Luo, Zhipeng; Bai, Bin; Wang, Xiaofang; Liu, Kezhao

2018-06-01

Oxide formation on surface of nitrogen-rich uranium nitride film/particles was investigated using X-ray photoelectron spectroscopy (XPS), auger electron spectroscopy (AES), aberration-corrected transmission electron microscopy (TEM), and high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) coupled with electron energy-loss spectroscopy (EELS). XPS and AES studies indicated that the oxidized layer on UN2-x film is ternary compound uranium oxynitride (UNxOy) in 5-10 nm thickness. TEM/HAADF-STEM and EELS studies revealed the UNxOy crystallizes in the FCC CaF2-type structure with the lattice parameter close to the CaF2-type UN2-x matrix. The work can provide further information to the oxidation mechanism of uranium nitride.

The Measurement of Epithermal-to-Thermal U-238 Neutron Capture Rate (ρ28) in Aagesta Power Reactor Fuel

International Nuclear Information System (INIS)

Bernander, G.

1967-09-01

The epithermal-to-thermal neutron capture rate ratio ρ 28 in U-238 in Aagesta fuel has been measured by the chemical separation method. The method involves the isolation of Np-239 from uranium and fission products by reversed phase partition chromatography. Although somewhat elaborate, and in spite of difficulties with residual fission products, the method has yielded reasonably accurate results. Further development work on chemical procedures may lead to some improvement. A comparison with the coincidence method - electronic separation of activities - has not shown any large systematic differences between the two methods. The separation of the epithermal U-235 activation from the total has been achieved by means of the '1/v subtraction technique' using copper foils as the 1/v monitor. The complementary thermal column irradiations required have been performed in the research reactors TRIGA (Helsinki) and R1 (Stockholm). From the measured ρ 28 values the resonance escape probability (p) and the initial conversion ratio (ICR) may be calculated using cross-section data and other lattice parameters. Comparisons with theoretical values of ρ and ICR as calculated with the BURNUP lattice parameter code are favourable

Characteristic analysis on moderating material for obtaining epithermal neutron beam

International Nuclear Information System (INIS)

Jiang Xinbiao; Chen Da; Zhang Ying

2000-01-01

The one dimension discrete coordinates transport code ANISN was used to calculate three-group constants of 11 elements which could be used to consist moderating epithermal neutron material of beam. Moderating character of simple substances, compounds and mixtures consisted of the optimized elements analyzed three kinds of moderating materials were optimized for epithermal neutron beam

IER-297 CED-2: Final Design for Thermal/Epithermal eXperiments with Jemima Plates with Polyethylene and Hafnium

Energy Technology Data Exchange (ETDEWEB)

Nelson, A. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Percher, C. M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Zywiec, W. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Heinrichs, D. P. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2018-01-11

This report presents the final design (CED-2) for IER-297, and focuses on 15 critical configurations using highly enriched uranium (HEU) Jemima plates moderated by polyethylene with and without hafnium diluent. The goal of the U.S. Nuclear Criticality Safety Program’s Thermal/Epithermal eXperiments (TEX) is to design and conduct new critical experiments to address high priority nuclear data needs from the nuclear criticality safety and nuclear data communities, with special emphasis on intermediate energy (0.625 eV – 100 keV) assemblies that can be easily modified to include various high priority diluent materials. The TEX (IER 184) CED-1 Report [1], completed in 2012, demonstrated the feasibility of meeting the TEX goals with two existing NCSP fissile assets, plutonium Zero Power Physics Reactor (ZPPR) plates and highly enriched uranium (HEU) Jemima plates. The first set of TEX experiments will focus on using the plutonium ZPPR plates with polyethylene moderator and tantalum diluents.

Upgrades of the epithermal neutron beam at the Brookhaven Medical Research Reactor

Energy Technology Data Exchange (ETDEWEB)

Liu, Hungyuan B.; Brugger, R.M.; Rorer, D.C.

1994-12-31

The first epithermal neutron beam at the Brookhaven Medical Research Reactor (BMRR) was installed in 1988 and produced a neutron beam that was satisfactory for the development of NCT with epithermal neutrons. This beam was used routinely until 1992 when the beam was upgraded by rearranging fuel elements in the reactor core to achieve a 50% increase in usable flux. Next, after computer modeling studies, it was proposed that the Al and Al{sub 2}O{sub 3} moderator material in the shutter that produced the epithermal neutrons could be rearranged to enhance the beam further. However, this modification was not started because a better option appeared, namely to use fission plates to move the source of fission neutrons closer to the moderator and the patient irradiation position to achieve more efficient moderation and production of epithermal neutrons. A fission plate converter (FPC) source has been designed recently and, to test the concept, implementation of this upgrade has started. The predicted beam parameters will be 12 x 10{sup 9} n{sub epi}/cm{sup 2}sec accompanying with doses from fast neutrons and gamma rays per epithermal neutron of 2.8 x 10{sup -11} and < 1 x 10{sup -11} cGycm{sup 2}/n, respectively, and a current-to-flux ratio of epithermal neutrons of 0.78. This conversion could be completed by late 1996.

Mineralogical, stable isotope, and fluid inclusion studies of spatially related porphyry Cu and epithermal Au-Te mineralization, Fakos Peninsula, Limnos Island, Greece

Science.gov (United States)

Fornadel, Andrew P.; Voudouris, Panagiotis Ch.; Spry, Paul G.; Melfos, Vasilios

2012-05-01

The Fakos porphyry Cu and epithermal Au-Te deposit, Limnos Island, Greece, is hosted in a ~20 Ma quartz monzonite and shoshonitic subvolcanic rocks that intruded middle Eocene to lower Miocene sedimentary basement rocks. Metallic mineralization formed in three stages in quartz and quartz-calcite veins. Early porphyry-style (Stage 1) metallic minerals consist of pyrite, chalcopyrite, galena, bornite, sphalerite, molybdenite, and iron oxides, which are surrounded by halos of potassic and propylitic alteration. Stage 2 mineralization is composed mostly of quartz-tourmaline veins associated with sericitic alteration and disseminated pyrite and molybdenite, whereas Stage 3, epithermal-style mineralization is characterized by polymetallic veins containing pyrite, chalcopyrite, sphalerite, galena, enargite, bournonite, tetrahedrite-tennantite, hessite, petzite, altaite, an unknown cervelleite-like Ag-telluride, native Au, and Au-Ag alloy. Stage 3 veins are spatially associated with sericitic and argillic alteration. Fluid inclusions in quartz from Stage 1 (porphyry-style) mineralization contain five types of inclusions. Type I, liquid-vapor inclusions, which homogenize at temperatures ranging from 189.5°C to 403.3°C have salinities of 14.8 to 19.9 wt. % NaCl equiv. Type II, liquid-vapor-NaCl, Type III liquid-vapor-NaCl-XCl2 (where XCl is an unknown chloride phase, likely CaCl2), and Type IV, liquid-vapor-hematite ± NaCl homogenize to the liquid phase by liquid-vapor homogenization or by daughter crystal dissolution at temperatures of 209.3 to 740.5 °C, 267.6 to 780.8 °C, and 357.9 to 684.2 °C, respectively, and, Type V, vapor-rich inclusions. Stage 2 veins are devoid of interpretable fluid inclusions. Quartz from Stage 3 (epithermal-style) veins contains two types of fluid inclusions, Type I, liquid-vapor inclusions that homogenize to the liquid phase (191.6 to 310.0 °C) with salinities of 1.40 to 9.73 wt. % NaCl equiv., and Type II, vapor-rich inclusions. Mixing

ICP-MS determination of rare earth elements, yttrium, uranium and thorium in niobium-tantalum rich samples

International Nuclear Information System (INIS)

Sunilkumar, Beena; Padmasubashini, V.

2013-01-01

ICP-MS is a powerful and extremely sensitive technique which has been applied successfully for the determination of REEs in diverse geological samples. In the present work, ICP-MS has been applied for the rapid determination of REEs, yttrium as well as uranium and thorium in niobium and tantalum rich samples, using a fluoride fusion method for sample dissolution

Use of highly enriched uranium in the material testing reactor BR2

International Nuclear Information System (INIS)

Beeckmans de West-Meerbeeck, A.

1979-05-01

In the material testing reactor BR2, the use of highly enriched uranium is determined by the consideration of the fast, epithermal and thermal neutron flux effectively available for the experimental devices. The choice of the core configuration is defined by combining the localisation of the experimental devices and of fuel elements of various burnup, such as to satisfy the irradiation conditions of the experimental load, compatible with an economic use of the fuel elements and safe operation of the reactor. Taking into account the present manufacturing technology for MTR fuels (37 Wt % uranium density in the fuel meat) the highly enriched uranium cannot be avoided; if higher concentration of uranium could be realised by some new manufacturing technology, the 235 U density of fuel elements at elimination should be kept at the required level and the enrichment could be reduced accordingly

Use of highly enriched uranium in the material testing reactor BR2

International Nuclear Information System (INIS)

Beeckmans de West-Meerbeeck, A.

1979-05-01

In the material testing reactor BR2, the use of highly enriched uranium is determined by the consideration of the fast, epithermal and thermal neutron flux effectively available for the experimental devices. The choice of the core configuration is defined by combining the localisation of the experimental devices and of fuel elements of various burnup, such as to satisfy the irradiation conditions of the experimental load, compatible with an economic use of the fuel elements and safe operation of the reactor. Taking into account the present manufacturing technology for MTR fuels (37 Wt % uranium density in the fuel meat) the highly enriched uranium cannot be avoided: if higher concentration of uranium could be realised by some new manufacturing technology, the 235 U density of fuel elements at elimination should be kept at the required level and the enrichment could be reduced accordingly. (author)

Polarized Epithermal Neutron Studies of Magnetic Domains

International Nuclear Information System (INIS)

Alfimenkov, V.P.; Chernikov, A.N.; Lason, L.; Mareev, Yu. D.; Novitsky, V.V.; Pikelner, L.B.; Skoy, V.R.; Tsulaya, M.I.; Gould, C.R.; Haase, D.G.; Roberson, N.R.

1997-01-01

The average size and shape of magnetic domains in a material can be determined from the precession of polarized neutrons traversing the material. Epithermal neutrons (0.5eV< En<100eV), which process more slowly than thermals, effectively probe the internal structure of samples that are thick or have large domains or large internal fields. Such epithermal neutron measurements require a neutron polarizer and analyzer based on cryogenically polarized spin filters. We discuss the measurements at JINR, Dubna, of magnetic domains in a 2.0 cm. diam. crystal of holmium using 1.7 to 59eV neutrons polarized by a dynamically polarized proton target and analyzed with a statically polarized dysprosium target

Pulsed neutron sources for epithermal neutrons

International Nuclear Information System (INIS)

Windsor, C.G.

1978-01-01

It is shown how accelerator based neutron sources, giving a fast neutron pulse of short duration compared to the neutron moderation time, promise to open up a new field of epithermal neutron scattering. The three principal methods of fast neutron production: electrons, protons and fission boosters will be compared. Pulsed reactors are less suitable for epithermal neutrons and will only be briefly mentioned. The design principle of the target producing fast neutrons, the moderator and reflector to slow them down to epithermal energies, and the cell with its beam tubes and shielding will all be described with examples taken from the new Harwell electron linac to be commissioned in 1978. A general comparison of pulsed neutron performance with reactors is fraught with difficulties but has been attempted. Calculation of the new pulsed source fluxes and pulse widths is now being performed but we have taken the practical course of basing all comparisons on extrapolations from measurements on the old 1958 Harwell electron linac. Comparisons for time-of-flight and crystal monochromator experiments show reactors to be at their best at long wavelengths, at coarse resolution, and for experiments needing a specific incident wavelength. Even existing pulsed sources are shown to compete with the high flux reactors in experiments where the hot neutron flux and the time-of-flight methods can be best exploited. The sources under construction can open a new field of inelastic neutron scattering based on energy transfer up to an electron volt and beyond

National Uranium Resource Evaluation. Aerial gamma ray and magnetic survey, Racine and Grand Rapids quadrangles, Michigan, Wisconsin and Illinois. Final report

International Nuclear Information System (INIS)

1981-07-01

The Racine and Grand Rapids quadrangles of southeastern Wisconsin, northeastern Illinois, and Michigan cover a land area of 8785 square miles, and an additional water surface area of 5215 square miles. In the northeast, thick Paleozoic deposits overlie a regional downwarp of the Precambrian basement called the Michigan Basin. These Paleozoic deposits shoal to only 500 feet in the southwest corner of the survey area. The entire region is covered by a mantle of Quaternary glacial material. A search of available literature revealed no economically feasible uranium deposits. A total of 83 uranium anomalies were detected and are discussed briefly. All appear to have cultural, and/or locally unsaturated associations, and none appear to contain significant measured quantities of uranium. Magnetic data appear to be in general agreement with existing structural interpretations of the area. There are local exceptions which suggest some lithologic and/or structural complexities in the basement material

Uranium resources in New Mexico

International Nuclear Information System (INIS)

McLemore, V.T.; Chenoweth, W.L.

1989-01-01

For nearly three decades (1951-1980), the Grants uranium district in northwestern New Mexico produced more uranium than any other district in the world. The most important host rocks containing economic uranium deposits in New Mexico are sandstones within the Jurassic Morrison Formation. Approximately 334,506,000 lb of U 3 O 8 were produced from this unit from 1948 through 1987, accounting for 38% of the total uranium production from the US. All of the economic reserves and most of the resources in New Mexico occur in the Morrison Formation. Uranium deposits also occur in sandstones of Paleozoic, Triassic, Cretaceous, Tertiary, and Quaternary formations; however, only 468,680 lb of U 3 O 8 or 0.14% of the total production from New Mexico have been produced from these deposits. Some of these deposits may have a high resource potential. In contrast, almost 6.7 million lb of U 3 O 8 have been produced from uranium deposits in the Todilto Limestone of the Wanakah Formation (Jurassic), but potential for finding additional economic uranium deposits in the near future is low. Other uranium deposits in New Mexico include those in other sedimentary rocks, vein-type uranium deposits, and disseminated magmatic, pegmatitic, and contact metasomatic uranium deposits in igneous and metamorphic rocks. Production from these deposits have been insignificant (less than 0.08% of the total production from New Mexico), but there could be potential for medium to high-grade, medium-sized uranium deposits in some areas. Total uranium production from New Mexico from 1948 to 1987 amounts to approximately 341,808,000 lb of U 3 O 8 . New Mexico has significant uranium reserves and resources. Future development of these deposits will depend upon an increase in price for uranium and lowering of production costs, perhaps by in-situ leaching techniques

Epithermal neutron activation analysis using a boron carbide irradiation filter

International Nuclear Information System (INIS)

Ehmann, W.D.; Brueckner, J.

1980-01-01

The use of boron carbide as a thermal neutron filter in epithermal neutron activation (ENAA) analysis has been investigated. As compared to the use of a cadmium filter, boron provides a greater reduction of activities from elements relatively abundant in terrestrial rocks and fossil fuels, such as Na, La, Sc and Fe. These elements have excitation functions which follow the 1/v law in the 1 to 10 eV lower epithermal region. This enhances the sensitivity of ENAA for elements such as U, Th, Ba and etc. which have strong resonances in the higher epithermal region above 10 eV. In addition, a boron carbide filter has the advantages over cadmium of acquiring a relatively low level of induced activity which poses minimal radiation safety problems, when used for ENAA. (author)

Possible uranium sources of Streltsovsky uranium ore field

International Nuclear Information System (INIS)

Zhang Lisheng

2005-01-01

The uranium deposit of the Late Jurassic Streltsovaky caldera in Transbaikalia of Russia is the largest uranium field associated with volcanics in the world, its uranium reserves are 280 000 t U, and it is the largest uranium resources in Russia. About one third of the caldera stratigraphic pile consists of strongly-altered rhyolites. Uranium resources of the Streltsovsky caldera are much larger than any other volcanic-related uranium districts in the world. Besides, the efficiency of hydrothermal alteration, uranium resources appear to result from the juxtaposition of two major uranium sources; highly fractionated peralkaline rhyolites of Jurassic age in the caldera, and U-rich subalkaline granites of Variscan age in the basement in which the major uranium-bearing accessory minerals were metamict at the time of the hydrothermal ore formation. (authors)

Uranium in minerals of gold-bearing formations of the North-Eastern part of the USSR

International Nuclear Information System (INIS)

Zagruzina, I.A.; Pinsky, E.M.

1979-01-01

Uranium concentration in 2190 mineral grains from 23 gold-bearing veins of different age deposits in the North-Eastern part of the USSR have been determined using f-radiography. The deposits studied are referred to two formation types: gold-silver epithermal and gold-quartz mesothermal. Differences in physico-chemical conditions of deposite formation of the above formation types are emphasized by the differences in uranium concentration in the vein minerals: 1.0-1.4 g/tU in the first type and 0.4 g/tU in the second one. Uranium content in minerals of gold-bearing veins as compared to minerals of other deposits is characterized by the lowest concentrations. In all gold-bearing veins hydrooxides of iron and hydromica are the main concentrators of uranium. Hypergene stage plays dominating role in uranium accumulation

Epithermal beam development at the BMRR [Brookhaven Medical Research Reactor]: Dosimetric evaluation

International Nuclear Information System (INIS)

Saraf, S.K.; Fairchild, R.G.; Kalef-Ezra, J.; Laster, B.H.; Fiarman, S.; Ramsey, E.; Ioannina Univ.; Brookhaven National Lab., Upton, NY; State Univ. of New York, Stony Brook, NY

1989-01-01

The utilization of an epithermal neutron beam for neutron capture therapy (NCT) is desirable because of the increased tissue penetration relative to a thermal neutron beam. Over the past few years, modifications have been and continue to be made at the Brookhaven Medical Research Reactor (BMRR) by changing its filter components to produce an optimal epithermal beam. An optimal epithermal beam should contain a low fast neutron contamination and no thermal neutrons in the incident beam. Recently a new moderator for the epithermal beam has been installed at the epithermal port of the BMRR and has accomplished this task. This new moderator is a combination of alumina (Al 2 O 3 ) bricks and aluminum (Al) plates. A 0.51 mm thick cadmium (Cd) sheet has reduced the thermal neutron intensity drastically. Furthermore, an 11.5 cm thick bismuth (Bi) plate installed at the port surface has reduced the gamma dose component to negligible levels. Foil activation techniques have been employed by using bare gold and cadmium-covered gold foil to determine thermal as well as epithermal neutron fluence. Fast neutron fluence has been determined by indium foil counting. Fast neutron and gamma dose in soft tissue, free in air, is being determined by the paired ionization chamber technique, using tissue equivalent (TE) and graphite chambers. Thermoluminescent dosimeters (TLD-700) have also been used to determine the gamma dose independently. This paper describes the methods involved in the measurements of the above mentioned parameters. Formulations have been developed and the various corrections involved have been detailed. 12 refs

The Marianas-San Marcos vein system: characteristics of a shallow low sulfidation epithermal Au-Ag deposit in the Cerro Negro district, Deseado Massif, Patagonia, Argentina

Science.gov (United States)

Vidal, Conrado Permuy; Guido, Diego M.; Jovic, Sebastián M.; Bodnar, Robert J.; Moncada, Daniel; Melgarejo, Joan Carles; Hames, Willis

2016-08-01

The Cerro Negro district, within the Argentinian Deseado Massif province, has become one of the most significant recent epithermal discoveries, with estimated reserves plus resources of ˜6.7 Moz Au equivalent. The Marianas-San Marcos vein system contains about 70 % of the Au-Ag resources in the district. Mineralization consists of Upper Jurassic (155 Ma) epithermal Au- and Ag-rich veins of low to intermediate sulfidation style, hosted in and genetically related to Jurassic intermediate composition volcanic rocks (159-156 Ma). Veins have a complex infill history, represented by ten stages with clear crosscutting relationships that can be summarized in four main episodes: a low volume, metal-rich initial episode (E1), an extended banded quartz episode with minor mineralization (E2), a barren waning stage episode (E3), and a silver-rich late tectonic-hydrothermal episode (E4). The first three episodes are interpreted to have formed at the same time and probably from fluids of similar composition: a 290-230 °C fluid dominated by meteoric and volcanic waters (-3‰ to -0‰ δ18Owater), with geothermal features. The last tectonic-hydrothermal mineralization episode (E4), interpreted to have formed at lower temperatures, could be related to this late tectonic and hydrothermal activity.

Polarized epithermal neutron studies of magnetic domains

International Nuclear Information System (INIS)

Alfimenkov, V.P.; Chernikov, A.N.; Lason, L.; Mareev, Y.D.; Novitsky, V.V.; Pikelner, L.B.; Skoy, V.R.; Tsulaya, M.I.; Gould, C.R.; Haase, D.G.; the Triangle Universities Nuclear Laboratory, Durham, North Carolina; Roberson, N.R.; the Triangle Universities Nuclear Laboratory, Durham, North Carolina

1997-01-01

The average size and shape of magnetic domains in a material can be determined from the precession of polarized neutrons traversing the material. Epithermal neutrons (0.5eV n <100eV), which precess more slowly than thermals, effectively probe the internal structure of samples that are thick or have large domains or large internal fields. Such epithermal neutron measurements require a neutron polarizer and analyzer based on cryogenically polarized spin filters. We discuss the measurement at JINR, Dubna, of magnetic domains in a 2.0 cm. diam. crystal of holmium using 1.7 to 59 eV neutrons polarized by a dynamically polarized proton target and analyzed with a statically polarized dysprosium target. copyright 1997 American Institute of Physics

Successive Recovery of Copper and Uranium From Carbonate-Rich Latosol, Um Bogma Formation, Abuthor Locality, South Western Sinai, Egypt

International Nuclear Information System (INIS)

El-Sheikh, E.M.; Amin, M.M.; Aita, S.K.; Rezk, A.A.

2013-01-01

A technological sample of a copper/ uranium mineralization in carbonate rich latosol rock sequence of Urn Bogma Formation Abu Thor locality at southwestern Sinai, Egypt, has been properly processed. The working sample assaying 12.5 % CuO and 875 ppm U was subjected to adipic acid leaching for copper followed by bioleaching of uranium in a manner to avoid excessive acid consumption in the classical leaching procedure. It is thus possible to achieve leaching efficiencies of 95% for Cu in the first stage and 82% for U in the second stage. From the two separately obtained leach liquors of Cu and uranium, pure products have conveniently been prepared. Accordingly, Cu adipate product was first prepared by crystallization,followed by acid dissolution and alkali precipitation of copper hydroxide. In case of uranium, the impure precipitate of the bioleach liquor is purified via Amberlite IRA-400 anion exchanger resin

National Uranium Resource Evaluation: Lamar quadrangle, Colorado and Kansas

International Nuclear Information System (INIS)

Maarouf, A.M.; Johnson, V.C.

1982-01-01

Uranium resources of the Lamar Quadrangle, Colorado and Kansas, were evaluated using National Uranium Resource Evaluation criteria. The environment favorable for uranium is the Lower Cretaceous Dakota Sandstone in the area east of John Martin Reservoir for south Texas roll-type sandstone deposits. Carbonaceous trash and sulfides are abundant in the Dakota Sandstone. The unit underlies a thick Upper Cretaceous section that contains bentonitic beds and uraniferous marine black shale. Water samples from the Dakota Sandstone aquifer contain as much as 122 ppB U 3 O 8 . Geologic units considered unfavorable include most of the Paleozoic rocks, except in the Brandon Fault area; the Upper Cretaceous rocks; and the Ogallala Formation. The Dockum Group, Morrison Formation, and Lytle Member of the Purgatoire Formation are unevaluated because of lack of data

Delayed fungal evolution did not cause the Paleozoic peak in coal production.

Science.gov (United States)

Nelsen, Matthew P; DiMichele, William A; Peters, Shanan E; Boyce, C Kevin

2016-03-01

Organic carbon burial plays a critical role in Earth systems, influencing atmospheric O2 and CO2 concentrations and, thereby, climate. The Carboniferous Period of the Paleozoic is so named for massive, widespread coal deposits. A widely accepted explanation for this peak in coal production is a temporal lag between the evolution of abundant lignin production in woody plants and the subsequent evolution of lignin-degrading Agaricomycetes fungi, resulting in a period when vast amounts of lignin-rich plant material accumulated. Here, we reject this evolutionary lag hypothesis, based on assessment of phylogenomic, geochemical, paleontological, and stratigraphic evidence. Lignin-degrading Agaricomycetes may have been present before the Carboniferous, and lignin degradation was likely never restricted to them and their class II peroxidases, because lignin modification is known to occur via other enzymatic mechanisms in other fungal and bacterial lineages. Furthermore, a large proportion of Carboniferous coal horizons are dominated by unlignified lycopsid periderm with equivalent coal accumulation rates continuing through several transitions between floral dominance by lignin-poor lycopsids and lignin-rich tree ferns and seed plants. Thus, biochemical composition had little relevance to coal accumulation. Throughout the fossil record, evidence of decay is pervasive in all organic matter exposed subaerially during deposition, and high coal accumulation rates have continued to the present wherever environmental conditions permit. Rather than a consequence of a temporal decoupling of evolutionary innovations between fungi and plants, Paleozoic coal abundance was likely the result of a unique combination of everwet tropical conditions and extensive depositional systems during the assembly of Pangea.

Metallogeny of the Gold Quadrilateral: style and characteristics of epithermal - subvolcanic mineralized structures, South Apuseni Mts., Romania

Directory of Open Access Journals (Sweden)

S̡erban-Nicolae Vlad

2004-04-01

Full Text Available The Romanian territory contains numerous ore deposits mined since pre-Roman times. An assessment of historical gold production of the Gold Quadri-lateral (GQ yielded a total estimate of 55.7 Moz of gold throughout an area of 2400 km2. Interpreted in terms of mineralization density this is 23,208 oz of gold/ km2. The geological setting of the GQ is represented mainly by Tertiary (14.7 My to 7.4 My calc-alkaline volcano-plutonic complexes of intermediate character in sedimentary basins of molasse type. These basins are tectonically controlled by NW-SE lineation across early Alpine magmatic products, i.e. subduction related Jurassic-Lower Cretaceous igneous association (island arc ophiolites and granitoids and Upper Cretaceous igneous association (banatites. The Tertiary magmatism is associated with extensional tectonics caused by NE escape of the Pannonian region during Upper Oligocene-Lower Miocene times. As a result of tectono-magmatic and mineralization-alteration characteristics, two metallogenetical types were separated in the GQ, i.e. calc-alkaline andesitic (CAM and sub-alkaline rhyodacitic (SRM. Both develop almost entirely low-sulfidation type of Au epithermal mineralization. However, two subtypes, -rich in sulfide (2-7% and -poor in sulfide (7-20% were delineated and correlated with CAM type and SRM type respectively. Furthermore, CAM is connected at deeper levels with Cu-Au+/-Mo porphyry systems in contrast with SRM, which is a non-porphyry environment. The Brad-Săcărâmb district contains mainly CAM type andesitic structures. It is a porphyry environment with epithermal low-sulfidation-rich sulfide vein halo (Barza, Troiţa-Bolcana deposits. However, a few SRM type patterns, such as Măgura Ţebii, Băiţa-Crăciuneşti and Săcărâmb, deposits exhibit Au-Ag-Te low-sulfidation-poor sulfide epithermal vein halo. The Zlatna-Stănija district exhibits similar characteristics, with Au-Ag+/-Pb, Zn veins in Cu-Au subvolcanic

International Uranium Resources Evaluation Project (IUREP) national favourability studies: Jordan

International Nuclear Information System (INIS)

1977-08-01

Jordanian geology is dominated by the Great Rift Valley System. Most of the country is covered by Cretaceous and Eocene sediments, largely sandstones and limestones. These include phosphorates and bituminous limestones in the Upper Cretaceous, South of the Dead Sea, Mesozoic and Paleozoic rocks overlie exposed granitic Pre Cambrian basement rocks carrying many minor intrusives . Phosphates provide the main mineral export of Jordan. The Natural Resources Authority (Geological Survey and Bureau of Mines) initiated a survey in 1972 of the distribution of uranium on the phosphorite horizon. In 1974 the Survey calculated that the uranium content of the phosphate areas surveyed up to that time was 5 million metric tonnes U 3 O 8 . The average U 3 O 8 content is approximately 0.02% U 3 O 8 . The exploitation of such resources would be as a byproduct of the phosphate industry and dependent on the rate of phosphate production and the capacity of triple super-phosphate plants, none of which exist at the present time. In the southern area in Paleozoic and Pre Cambrian areas there are some hopes of conventional type deposits being found but the potential appears to be small. (author)

International Uranium Resources Evaluation Project (IUREP) orientation phase mission summary report: Cameroon

International Nuclear Information System (INIS)

1985-01-01

A report has recently been published which describes the findings of the International Uranium Resources Evaluation Project (IUREP) Mission to Cameroon. The IUREP Orientation Phase Mission to Cameroon estimates the Speculative Resources of that country to be in the order of 10 000 tonnes uranium for syenite-associated U-deposits in southern Cameroon, and in the order of 5 000 tonnes uranium for uranium deposits associated with albitized and desilicified late tectonic Panafrican granites (episyenite) and Paleozoic volcanics in northern Cameroon. No specific tonnage is given for Francevillian equivalents (DJA-Series) and for Mesozoic and Cenozoic sedimentary basins, which are thought to hold limited potential for sandstone hosted uranium. However the Douala basin, consisting of mixed marine and continental sequences merits some attention. No specific budget and programme for uranium exploration are proposed for Cameroon. Instead specific recommendations concerning specific potential environments and general recommendation concerning the methodology of exploration are made. (author)

The Comparison Study of Neutron Activation Analysis and Fission Track Technique for Uranium Determination

International Nuclear Information System (INIS)

Sirinuntavid, Alice; Rodthongkom, Chouvana

2007-08-01

Full text: Comparison between Neutron Activation Analysis (NAA) and fission track technique for uranium determination in solid samples was studied by use of standard reference materials, i.e., ore, coal fly ash, soil. For NAA, the epithermal neutron was applied for activated irradiation. Then, the 74.5 keV gamma from U-239 or 277.7 keV gamma from Np-239 was measured. For high Uranium content samples, NAA method with 74.5 keV gamma measurement, gave higher precision result than the 277.7 keV gamma measurement method. NAA method with 277.7 keV gamma measurement, gave higher sensitivity and precision result for low Uranium content samples and the uranium contained less than 10 ppm samples. Nevertheless, the latter procedure needed longer time for neutron irradiation and analysis procedure. In comparison the results of Uranium analysis between NAA and fission track, it was found that no significant difference within 95 % of confidence level

Fluid Inclusion Study of The Tumpangpitu High Sulfidation Epithermal Gold Deposit in Banyuwangi District, East Java, Indonesia

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Yu Yu Myaing

2018-03-01

Full Text Available The Tumpangpitu high sulfidation (HS epithermal gold deposit is located in the south coast of East Java, Banyuwangi District, East Java Province, Indonesia. This area lies within the central portion of the Cenozoic Sunda‐Banda magmatic arc which trends southeast from northern Sumatra to west Java then eastward through east Java, Bali, Lombok, Sumbawa and terminating at Banda sea. The geology of the Tumpangpitu is predominantly occupied by Late Oligocene to Middle Miocene low-K calc-alkaline to alkaline andesitic volcanic rocks and interbedded with volcaniclastic rock sequences, which are associated with low-K intermediate intrusions. The mineralization style at the Tumpangpitu area is composed of a high‐sulfidation (HS epithermal gold-copper system which is typically associated with concealed gold-rich porphyry copper system. The HS epithermal mineralization is hosted by volcanic and volcaniclastic rocks in this research area. The mineralization domains are divided into Zone A, Zone B and Zone C which are situated along NW-SE-trending silica ledges zones. The HS epithermal mineralization is texturally occurs as vuggy replacements mineralization as well as stockworks, disseminated forms, fractures and veins. Fluid inclusion study was conducted for 6 quartz vein samples which petrographically entrapped fluid inclusions. Homogenization temperature (Th and melting temperature (Tm can microthermometrically be determined by fluid inclusion analysis. The average homogenization temperature (Th of the fluid inclusions gives 180˚C to 342˚C and melting temperature are from -0.1 ˚C to -1.4˚C. Tm corresponds to the salinities ranging from 0.1 to 4.5 wt% NaCl equivalent. The paleodepth of ore formation can be estimated from the salinity of fluid. Since the deposit was not formed at boiling condition, the minimum paleodepth of ore (quartz samples taken from both shallow level (53.35 m and deep level (135.15 m is determined at 650m and 1,220 m

Uranium prospecting in Cerro Partido Region-Encruzilhada do Sul Basin-RS, Brazil

International Nuclear Information System (INIS)

Fraenkel, M.O.

1974-01-01

The Cerro Partido residual basin is a shallow (85 meters) and small (25km 2 ) sedimentary basin, a remainder of the erosive cicle, enclosed in the pre-cambrian granitic rocks of the Rio Grande do Sul Shield. Grades of 0.2 + U 3 O 8 were found in its upper-paleozoic sandstones and shales drilles for uranium. The small size and thicknesses of these concentrations prevent their economic mining. However, the different levels of the shield exposed by tectonics, the intrusive granitic, riolitic and syenitic rocks, the anomalous uranium contents in sedimentary and crystalline rocks recommend further investigations on the shield area

TRANSHEX, 2-D Thermal Neutron Flux Distribution from Epithermal Flux in Hexagonal Geometry

International Nuclear Information System (INIS)

Patrakka, E.

1994-01-01

1 - Description of program or function: TRANSHEX is a multigroup integral transport program that determines the thermal scalar flux distribution arising from a known epithermal flux in two- dimensional hexagonal geometry. 2 - Method of solution: The program solves the isotropic collision probability equations for a region-averaged scalar flux by an iterative method. Either a successive over-relaxation or an inner-outer iteration technique is applied. Flat flux collision probabilities between trigonal space regions with white boundary condition are utilized. The effect of epithermal flux is taken into consideration as a slowing-down source that is calculated for a given spatial distribution and 1/E energy dependence of the epithermal flux

Genetic-Structural relations in some types of spanish uranium deposits

International Nuclear Information System (INIS)

Alia Medina, M.

1962-01-01

On the spanish hercynian areas there are different types of uraniferous deposits, which may be classified in the following groups: Group I, high temperature magmatic deposits, Group II, low temperature veins and Group III supergenic deposits, generated by weathering of the former ones or by lixiviation of the intra granitic uranium. The deposits belonging to Group I are founding the hercynian ge anticlinal; those of Groups II and III, chiefly in the eugeosyncline. The explanation suggested for these genetic-structural relationships assumes that, in the ge anticlinal, uranium would migrate from the dioritic magmas to form and high temperature deposits. In the eugeosyncline, a large fraction of the uranium would migrate towards more differentiated granites, in which it might partially remain or from which it might have been finally concentrated in the epithermal veins or by later tectonic actions. The Group III deposits ar more frequent in the eugeosyncline, due to the greater abundance of more differentiated intrusive rocks. (Author) 16 refs

Determination of silver using cyclic epithermal neutron activation analysis

International Nuclear Information System (INIS)

Pun, T.H.; Landsberger, S.

2012-01-01

A fast pneumatic transfer facility was installed in Nuclear Engineering Teaching Laboratory (NETL) of the University of Texas at Austin for the purpose of cyclic thermal and epithermal neutron activation analysis. In this study efforts were focused on the evaluation of cyclic epithermal neutron activation analysis (CENAA). Various NIST and CANMET certified materials were analyzed by the system. Experiment results showed 110 Ag with its 25 s half-life as one of the isotopes favored by the system. Thus, the system was put into practical application in identifying silver in metallic ores. Comparison of sliver concentrations as determined by CENAA in CANMET certified reference materials gave very good results. (author)

National Uranium Resource Evaluation: Wells Quadrangle, Nevada, Idaho, and Utah

International Nuclear Information System (INIS)

Proffitt, J.L.; Mayerson, D.L.; Parker, D.P.; Wolverson, N.; Antrim, D.; Berg, J.; Witzel, F.

1982-08-01

The Wells 2 0 Quadrangle, Nevada, Idaho, and Utah, was evaluated using National Uranium Resource Evaluation criteria to delineate areas favorable for uranium deposits. Our investigation has resulted in the delineation of areas that contain Tertiary sedimentary rocks favorable for hydroallogenic deposits in the Mountain City area (Favorable Area A) and in the Oxley Peak area north of Wells (Favorable Area B). Environments considered to be unfavorable for uranium deposits include Tertiary felsic volcanic, felsic plutonic, intermediate to mafic volcanic, Paleozoic and Mesozoic sedimentary rocks, Precambrian rocks, and most Tertiary sedimentary rocks located outside the favorable areas. Present-day basins are unevaluated environments because of a paucity of adequate outcrop and subsurface data. However, the scarce data indicate that some characteristics favorable for uranium deposits are present in the Susie Creek-Tule Valley-Wild Horse basin, the Contact-Granite Range-Tijuana John stocks area, the Charleston Reservoir area, and the Wells-Marys River basin

Hydrothermal uranium deposits containing molybdenum and fluorite in the Marysvale volcanic field, west-central Utah

Science.gov (United States)

Cunningham, C.G.; Rasmussen, J.D.; Steven, T.A.; Rye, R.O.; Rowley, P.D.; Romberger, S.B.; Selverstone, J.

1998-01-01

Uranium deposits containing molybdenum and fluorite occur in the Central Mining Area, near Marysvale, Utah, and formed in an epithermal vein system that is part of a volcanic/hypabyssal complex. They represent a known, but uncommon, type of deposit; relative to other commonly described volcanic-related uranium deposits, they are young, well-exposed and well-documented. Hydrothermal uranium-bearing quartz and fluorite veins are exposed over a 300 m vertical range in the mines. Molybdenum, as jordisite (amorphous MoS2, together with fluorite and pyrite, increase with depth, and uranium decreases with depth. The veins cut 23-Ma quartz monzonite, 20-Ma granite, and 19-Ma rhyolite ash-flow tuff. The veins formed at 19-18 Ma in a 1 km2 area, above a cupola of a composite, recurrent, magma chamber at least 24 ?? 5 km across that fed a sequence of 21- to 14-Ma hypabyssal granitic stocks, rhyolite lava flows, ash-flow tuffs, and volcanic domes. Formation of the Central Mining Area began when the intrusion of a rhyolite stock, and related molybdenite-bearing, uranium-rich, glassy rhyolite dikes, lifted the fractured roof above the stock. A breccia pipe formed and relieved magmatic pressures, and as blocks of the fractured roof began to settle back in place, flat-lying, concave-downward, 'pull-apart' fractures were formed. Uranium-bearing, quartz and fluorite veins were deposited by a shallow hydrothermal system in the disarticulated carapace. The veins, which filled open spaces along the high-angle fault zones and flat-lying fractures, were deposited within 115 m of the ground surface above the concealed rhyolite stock. Hydrothermal fluids with temperatures near 200??C, ??18OH2O ~ -1.5, ?? -1.5, ??DH2O ~ -130, log fO2 about -47 to -50, and pH about 6 to 7, permeated the fractured rocks; these fluids were rich in fluorine, molybdenum, potassium, and hydrogen sulfide, and contained uranium as fluoride complexes. The hydrothermal fluids reacted with the wallrock resulting in

Prospecting ideas for mesozoic granite-type, volcanics-type and exo-contact-type uranium deposits in South China. Pt.1

International Nuclear Information System (INIS)

Yu Dagan

2001-01-01

The Mesozoic uranium ore-formation process in South China resulted from the intense volcanic magmatism, the crust-mantle interaction and the fluidization in Yanshanian period, and there is great prospect for large-scale uranium concentration and ore-formation. Therefore, during the prospecting for Mesozoic granite-type, volcanics-type and exo-contact-type uranium deposits it is necessary to introduce deep-source metallogenic theory, to 'desalt' metallogenic theory of epithermal activation, to fully realize that uranium deposits may be formed not only at shallow depth, but also in conditions of deep-source, great depth and high temperature, as well as in environments of deep-source, shallow depth and median temperature, to give emphasis to the early-stage (130-95 Ma) uranium mineralization, to break the man-made boundary in prospecting for uranium only based on host rock type, to strengthen the research on Cretaceous magmatic system

Geochemistry and statistical analyses of porphyry system and epithermal veins at Hizehjan in northwestern Iran

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Radmard Kaikhosrov

2017-12-01

Full Text Available Situated about 130 km northeast of Tabriz (northwest Iran, the Mazra’eh Shadi deposit is in the Arasbaran metallogenic belt (AAB. Intrusion of subvolcanic rocks, such as quartz monzodiorite-diorite porphyry, into Eocene volcanic and volcano-sedimentary units led to mineralisation and alteration. Mineralisation can be subdivided into a porphyry system and Au-bearing quartz veins within andesite and trachyandesite which is controlled by fault distribution. Rock samples from quartz veins show maximum values of Au (17100 ppb, Pb (21100 ppm, Ag (9.43ppm, Cu (611ppm and Zn (333 ppm. Au is strongly correlated with Ag, Zn and Pb. In the Au-bearing quartz veins, factor group 1 indicates a strong correlation between Au, Pb, Ag, Zn and W. Factor group 2 indicates a correlation between Cu, Te, Sb and Zn, while factor group 3 comprises Mo and As. Based on Spearman correlation coefficients, Sb and Te can be very good indicator minerals for Au, Ag and Pb epithermal mineralisation in the study area. The zoning pattern shows clearly that base metals, such as Cu, Pb, Zn and Mo, occur at the deepest levels, whereas Au and Ag are found at higher elevations than base metals in boreholes in northern Mazra’eh Shadi. This observation contrasts with the typical zoning pattern caused by boiling in epithermal veins. At Mazra’eh Shadi, quartz veins containing co-existing liquid-rich and vapour-rich inclusions, as strong evidence of boiling during hydrothermal evolution, have relatively high Au grades (up to 813 ppb. In the quartz veins, Au is strongly correlated with Ag, and these elements are in the same group with Fe and S. Mineralisation of Au and Ag is a result of pyrite precipitation, boiling of hydrothermal fluids and a pH decrease.

Titanate ceramics for immobilisation of uranium-rich radioactive wastes arising from {sup 99}Mo production

Energy Technology Data Exchange (ETDEWEB)

Carter, M.L.; Li, H. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB 1, Menai, Sydney, NSW 2232 (Australia); Zhang, Y. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB 1, Menai, Sydney, NSW 2232 (Australia)], E-mail: yzx@ansto.gov.au; Vance, E.R.; Mitchell, D.R.G. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB 1, Menai, Sydney, NSW 2232 (Australia)

2009-02-28

Uranium-rich liquid wastes arising from UO{sub 2} targets which have been neutron-irradiated to generate medical radioisotopes such as {sup 99m}Tc require immobilisation. A pyrochlore-rich hot isostatically pressed titanate ceramic can accommodate at least 40 wt% of such waste expressed on an oxide basis. In this paper, the baseline waste form composition (containing 40 wt% UO{sub 2}) was adjusted in two ways: (a) varying the UO{sub 2} loading with constant precursor oxide materials, (b) varying the precursor composition with constant waste loading of UO{sub 2}. This resulted in the samples having a similar phase assemblage but the amounts of each phase varied. The oxidation states of U in selected samples were determined using diffuse reflection spectroscopy (DRS) and electron energy loss spectroscopy (EELS). Leaching studies showed that there was no significant difference in the normalised elemental release rates and the normalised release rates are comparable with those from synroc-C. This demonstrates that waste forms based on titanate ceramics are robust and flexible for the immobilisation of U-rich waste streams from radioisotope processing.

Magmatism and petroleum exploration in the Brazilian Paleozoic basins

Energy Technology Data Exchange (ETDEWEB)

Thomaz Filho, Antonio; Antonioli, Luzia [Universidade do Estado do Rio de Janeiro, Faculdade de Geologia, Rua Sao Francisco Xavier, no 524/2030, CEP 20550-900, Rio de Janeiro, RJ (Brazil); Mizusaki, Ana Maria Pimentel [Universidade Federal do Rio Grande do Sul, Instituto de Geociencias, Avenida Bento Goncalves, no 9500, Campus do Vale, CEP 91509-900, Porto Alegre, RS (Brazil)

2008-02-15

Petroleum exploration in the Paleozoic sedimentary basins of Brazil has proven very challenging for explorationists. Except for the Solimoes Basin, in which transcurrent tectonism formed prospective structural highs, Brazilian Paleozoic basins lack intense structural deformation, and hence the detection and prospecting of place is often difficult. Magmatic intrusive and associated rocks in all these basins have traditionally been considered heat sources and hydrocarbon traps. The role of tholeiitic basic dikes in the generation, migration and accumulation of petroleum in the Anhembi oil occurrence (Sao Paulo State) is discussed herein. It follows that similar geological settings in other Paleozoic basins can be regarded as promising sites for oil accumulation that warrant investigation via modern geological and geophysical methods. (author)

Characterisation of the TAPIRO BNCT epithermal facility

Energy Technology Data Exchange (ETDEWEB)

Burn, K. W. [FIS-NUC, ENEA, Via Martiri di Montesole 4, Bologna (Italy); Colli, V. [Dept. of Physics of Univ., INFN, Via Celoria 16, I-20133 Milano (Italy); Curzio, G.; D' Errico, F. [DIMNP, Univ. of Pisa, Via Diotisalvi 2, I-56126 Pisa (Italy); Gambarini, G. [Dept. of Physics of Univ., INFN, Via Celoria 16, I-20133 Milano (Italy); Rosi, G. [FIS-ION, ENEA, Casaccia, Via Anguillarese 301, I-00060 Santa Maria di Galeria, Roma (Italy); Scolari, L. [Dept. of Physics of Univ., INFN, Via Celoria 16, I-20133 Milano (Italy)

2004-07-01

A collimated epithermal beam for boron neutron capture therapy (BNCT) research has been designed and built at the TAPIRO fast research reactor. A complete experimental characterisation of the radiation field in the irradiation chamber has been performed, to verify agreement with IAEA requirements. Slow neutron fluxes have been measured by means of an activation technique and with thermoluminescent detectors (TLDs). The fast neutron dose has been determined with gel dosemeters, while the fast neutron spectrum has been acquired by means of a neutron spectrometer based on superheated drop detectors. The gamma-dose has been measured with gel dosemeters and TLDs. For an independent verification of the experimental results, fluxes, doses and neutron spectra have been calculated with Monte Carlo simulations using the codes MCNP4B and MCNPX 2.1.5 with the direct statistical approach (DSA). The results obtained confirm that the epithermal beams achievable at TAPIRO are of suitable quality for BNCT purposes. (authors)

A new position-sensitive transmission detector for epithermal neutron imaging

International Nuclear Information System (INIS)

Schooneveld, E M; Kockelmann, W; Rhodes, N; Tardocchi, M; Gorini, G; Perelli Cippo, E; Nakamura, T; Postma, H; Schillebeeckx, P

2009-01-01

A new neutron resonant transmission (NRT) detector for epithermal neutron imaging has been designed and built for the ANCIENT CHARM project, which is developing a set of complementary neutron imaging methods for analysis of cultural heritage objects. One of the techniques being exploited is NRT with the aim of performing bulk elemental analysis. The 16-pixel prototype NRT detector consists of independent crystals of 2 x 2 mm pixel size, which allow for 2D position-sensitive transmission measurements with epithermal neutrons. First results obtained at the ISIS pulsed spallation neutron source are presented. (fast track communication)

Uranium-bearing francolites present in organic-rich limestones of NW Greece: a preliminary study using synchrotron radiation and fission track techniques

DEFF Research Database (Denmark)

Tzifas, I. T.; Glasmacher, U. A.; Misaelides, P.

2017-01-01

Synchrotron radiation techniques (μ-XRF and μ-XANES) were applied to the study of organic-rich phosphatized limestones of NW Greece (Epirus). The results revealed uranium accumulation in areas of the material containing, among others, carbonate apatite (francolite) and organic matter. The UL3-edge...

MCNP study for epithermal neutron irradiation of an isolated liver at the Finnish BNCT facility.

Science.gov (United States)

Kotiluoto, P; Auterinen, I

2004-11-01

A successful boron neutron capture treatment (BNCT) of a patient with multiple liver metastases has been first given in Italy, by placing the removed organ into the thermal neutron column of the Triga research reactor of the University of Pavia. In Finland, FiR 1 Triga reactor with an epithermal neutron beam well suited for BNCT has been extensively used to irradiate patients with brain tumors such as glioblastoma and recently also head and neck tumors. In this work we have studied by MCNP Monte Carlo simulations, whether it would be beneficial to treat an isolated liver with epithermal neutrons instead of thermal ones. The results show, that the epithermal field penetrates deeper into the liver and creates a build-up distribution of the boron dose. Our results strongly encourage further studying of irradiation arrangement of an isolated liver with epithermal neutron fields.

Development of new instrumentation for epithermal neutron scattering at very low angles

International Nuclear Information System (INIS)

Tardocchi, M.; Pietropaolo, A.; Andreani, C.; Gorini, G.; Perelli-Cippo, E.; Rhodes, N.J.; Schooneveld, E.M.; Senesi, R.

2004-01-01

New perspectives for epithermal neutron spectroscopy are opened up by the recent developments of Resonance Detectors (RD) for inverse geometry time-of-flight spectrometers at pulsed neutron sources. The RD is based on the combination of an analyser foil used as neutron-to-gamma converter and a suitable photon detector. Here, we report on the state of the RD which is based on a YAP scintillator viewing a natural uranium analyser foil. The response of the YAP detector to the radiative capture γ emission from the uranium analyser foil has been characterized with a bi-parametric measurement of a reference Pb sample, which allowed simultaneous measurements of both neutron time-of-flight and γ pulse height (energy) spectra. The analysis of the γ pulse height and neutron time-of-flight spectra permitted to identify the signal and background components. These measurements showed that a significant improvement in the signal-to-background ratio can be achieved by setting a lower level discrimination on the photon energy at about 600keV. The first application of RD is the Very Low Angle Detector Bank (VLAD) which is planned to be installed in the next three years as an upgrade of the VESUVIO spectrometer, at the ISIS pulsed neutron source. VLAD will extend the (q,ω) kinematical to low wave vector transfers (q10A-1) coupled to high-energy transfers (-bar ω>1eV), which is still unexplored by neutron scattering experiments. The first measurements obtained on an ice sample with a VLAD prototype consisting of four RD units are presented here

Development of new instrumentation for epithermal neutron scattering at very low angles

Energy Technology Data Exchange (ETDEWEB)

Tardocchi, M. [INFM, UdR Milano-Bicocca and Dipartimento di Fisica ' G.Occhialini' , Universita degli Studi di Milano-Bicocca, Pizza Della Scienza 3, Milan 20126 (Italy)]. E-mail: marco.tardocchi@mib.infn.it; Pietropaolo, A. [Dipartimento di Fisica, Universita degli Studi di Roma Tor Vergata and INFM, UdR Roma Tor Vergata, Rome (Italy); Andreani, C. [Dipartimento di Fisica, Universita degli Studi di Roma Tor Vergata and INFM, UdR Roma Tor Vergata, Rome (Italy); Gorini, G. [INFM, UdR Milano-Bicocca and Dipartimento di Fisica ' G.Occhialini' , Universita degli Studi di Milano-Bicocca, Pizza Della Scienza 3, Milan 20126 (Italy); Perelli-Cippo, E. [INFM, UdR Milano-Bicocca and Dipartimento di Fisica ' G.Occhialini' , Universita degli Studi di Milano-Bicocca, Pizza Della Scienza 3, Milan 20126 (Italy); Rhodes, N.J. [Isis Facility, Rutherford Appleton Laboratory, Chilton, Didcot (United Kingdom); Schooneveld, E.M. [Isis Facility, Rutherford Appleton Laboratory, Chilton, Didcot (United Kingdom); Senesi, R. [Dipartimento di Fisica, Universita degli Studi di Roma Tor Vergata and INFM, UdR Roma Tor Vergata, Rome (Italy)

2004-12-11

New perspectives for epithermal neutron spectroscopy are opened up by the recent developments of Resonance Detectors (RD) for inverse geometry time-of-flight spectrometers at pulsed neutron sources. The RD is based on the combination of an analyser foil used as neutron-to-gamma converter and a suitable photon detector. Here, we report on the state of the RD which is based on a YAP scintillator viewing a natural uranium analyser foil. The response of the YAP detector to the radiative capture {gamma} emission from the uranium analyser foil has been characterized with a bi-parametric measurement of a reference Pb sample, which allowed simultaneous measurements of both neutron time-of-flight and {gamma} pulse height (energy) spectra. The analysis of the {gamma} pulse height and neutron time-of-flight spectra permitted to identify the signal and background components. These measurements showed that a significant improvement in the signal-to-background ratio can be achieved by setting a lower level discrimination on the photon energy at about 600keV. The first application of RD is the Very Low Angle Detector Bank (VLAD) which is planned to be installed in the next three years as an upgrade of the VESUVIO spectrometer, at the ISIS pulsed neutron source. VLAD will extend the (q,{omega}) kinematical to low wave vector transfers (q10A-1) coupled to high-energy transfers (-bar {omega}>1eV), which is still unexplored by neutron scattering experiments. The first measurements obtained on an ice sample with a VLAD prototype consisting of four RD units are presented here.

Niger: A State Rich in Uranium

International Nuclear Information System (INIS)

Gregoire, Emmanuel

2011-01-01

The kidnapping on 16 September 2010 of seven Areva and Satom (a subsidiary of the Vinci Group) employees, which was claimed by the Salafist brigade of Al Qaeda in the Islamic Maghreb (AQIM), thrust the Republic of Niger into the political and media spotlight. This commando-type operation at the Arlit mining site was followed four months later by a similar operation, this time in the heart of Niger's capital, Niamey. While four of the seven hostages are still being held in northern Mali (three were released in February 2011), the two young people abducted from a restaurant in Niamey were probably executed by their captors as they were pursued at the Malian border by the Niger army supported by French troops. [2] According to another version, one of the young people...[2] Among the poorest countries in the world, Niger rarely features in the headlines, except for the dramatic periods of drought which regularly affect the population, leading to solidarity campaigns, and for coups d'etat impacting the country's political life. The most recent of these coups d'etat (February 18, 2010) deposed President Mamadou Tandja who had modified the Constitution in order to remain in power (Gregoire 2010). Since then, the chain of historical events has accelerated at a rapid pace. The latest event was the election of Mahamadou Issoufou as president of the republic, after an election that took place under conditions of transparency and respect for democracy (March 12, 2011). The task facing the ninth Niger president will not be easy. Among other things, he will have to address the insecurity resulting from the presence of AQIM in Mali's territory, which was 'refueled' by western hostages in Niger. He will also need to eradicate the criminal economy (trafficking of all kinds, starting with drugs) now widespread in the Sahara region, and attempt to lift the country out of underdevelopment. The renewed interest shown by the international community in Niger's uranium deposits, and the

The current situation of uranium mining in Hungary

International Nuclear Information System (INIS)

Erdi-Krausz, G.

1997-01-01

The paper describes the history of uranium production in Hungary. It focuses on the Mecsek Ore Mining Company, now known as Mecsekuran Limited, and its relationship with the Hungarian Government. From the start of uranium production in 1963 until May 1989 all production was exported to the Soviet Union under a bilateral contract. In exchange the Soviet Union agreed to provide fabricated fuel for the future Hungarian nuclear power plant. In May 1989 the Government of Hungary announced closure of its uranium mining operations because of the high cost of production. The paper describes the history of events since 1989, as well as the current plans to terminate all uranium production by 31 December 1997. The Mecsek Mountains lie in the southern part of Hungary, west from the Danube, about 30 km from the former Yugoslavian border, and north from the city of Pecs. Its eastern side is built up from medieval limestone and dolomites, while the western part is from sandstone and clay from the geological Paleozoic. In the eastern part high quality cokeable coal has been mined for more than 200 years, east from the city of Pecs; and in the western part uranium ore was discovered and the mining began only a few decades ago. (author)

Johnson City 10 x 20 NTMS area, Kentucky, North Carolina, Tennessee, and Virginia: data report (abbreviated). National Uranium Resource Evaluation program, hydrogeochemical and stream sediment reconnaissance

International Nuclear Information System (INIS)

Fay, W.M.

1980-10-01

Results of ground water and stream sediment reconnaissance in the National Topographic Map Series (NTMS) Johnson City 1 0 x 2 0 quadrangle are presented. Surface sediment samples were collected at 959 sites. Ground water samples were collected at 1099 sites. Neutron activation analysis results are given for uranium and 16 other elements in sediments, and for uranium and 8 other elements in ground water. Data from ground water sites include: (1) water chemistry measurements (pH, conductivity, and alkalinity); (2) physical measurements where applicable (water temperature, well description, etc.); and (3) elemental analyses (U, Al, Br, Cl, Dy, F, Mn, Na, and V). Data from sediment sites include: (1) stream water chemistry measurements; and (2) elemental analyses for sediment samples (U, Th, Hf, Al, Ce, Dy, Eu, Fe, La, Lu, Mn, Sc, Sm, Na, Ti, V, and Yb). Sample site descriptors (stream characteristics, vegetation, etc.) are given. Areal distribution maps, histograms, and cumulative frequency plots for most elements and for U/Th and U/Hf ratios are included on the microfiche. The Johnson City Quadrangle is underlain by Precambrian cyrstalline rocks in the southeastern corner of the quadrangle and by Paleozoic sediments in the remainder of the quadrangle. The highest uranium concentrations in sediments (up to 22 ppM) are in samples from the Precambrian crystalline rock areas. These samples also have high thorium concentrations suggesting that most of the uranium is in resistate minerals such as monazite. The U/Th ratios in sediment samples are generaly low with the higher values (up to 2.07) mostly within the lower Paleozoic sediments, particularly the Copper Ridge Dolomite. The uranium concentration in ground water is also highest in the lower Paleozoic sediments

Evaluation of Weights of Evidence to Predict Epithermal-Gold Deposits in the Great Basin of the Western United States

International Nuclear Information System (INIS)

Raines, Gary L.

1999-01-01

The weights-of-evidence method provides a simple approach to the integration of diverse geologic information. The application addressed is to construct a model that predicts the locations of epithermal-gold mineral deposits in the Great Basin of the western United States. Weights of evidence is a data-driven method requiring known deposits and occurrences that are used as training sites in the evaluated area. Four hundred and fifteen known hot spring gold-silver, Comstock vein, hot spring mercury, epithermal manganese, and volcanogenic uranium deposits and occurrences in Nevada were used to define an area of 327.4 km 2 as training sites to develop the model. The model consists of nine weighted-map patterns that are combined to produce a favorability map predicting the distribution of epithermal-gold deposits. Using a measure of the association of training sites with predictor features (or patterns), the patterns can be ranked from best to worst predictors. Based on proximity analysis, the strongest predictor is the area within 8 km of volcanic rocks younger than 43 Ma. Being close to volcanic rocks is not highly weighted, but being far from volcanic rocks causes a strong negative weight. These weights suggest that proximity to volcanic rocks define where deposits do not occur. The second best pattern is the area within 1 km of hydrothermally altered areas. The next best pattern is the area within 1 km of known placer-gold sites. The proximity analysis for gold placers weights this pattern as useful when close to known placer sites, but unimportant where placers do not exist. The remaining patterns are significantly weaker predictors. In order of decreasing correlation, they are: proximity to volcanic vents, proximity to east-west to northwest faults, elevated airborne radiometric uranium, proximity to northwest to west and north-northwest linear features, elevated aeromagnetics, and anomalous geochemistry. This ordering of the patterns is a function of the quality

Revisions to the original extent of the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System

Science.gov (United States)

Enomoto, Catherine B.; Rouse, William A.; Trippi, Michael H.; Higley, Debra K.

2016-04-11

Technically recoverable undiscovered hydrocarbon resources in continuous accumulations are present in Upper Devonian and Lower Mississippian strata in the Appalachian Basin Petroleum Province. The province includes parts of New York, Pennsylvania, Ohio, Maryland, West Virginia, Virginia, Kentucky, Tennessee, Georgia, and Alabama. The Upper Devonian and Lower Mississippian strata are part of the previously defined Devonian Shale-Middle and Upper Paleozoic Total Petroleum System (TPS) that extends from New York to Tennessee. This publication presents a revision to the extent of the Devonian Shale-Middle and Upper Paleozoic TPS. The most significant modification to the maximum extent of the Devonian Shale-Middle and Upper Paleozoic TPS is to the south and southwest, adding areas in Tennessee, Georgia, Alabama, and Mississippi where Devonian strata, including potential petroleum source rocks, are present in the subsurface up to the outcrop. The Middle to Upper Devonian Chattanooga Shale extends from southeastern Kentucky to Alabama and eastern Mississippi. Production from Devonian shale has been established in the Appalachian fold and thrust belt of northeastern Alabama. Exploratory drilling has encountered Middle to Upper Devonian strata containing organic-rich shale in west-central Alabama. The areas added to the TPS are located in the Valley and Ridge, Interior Low Plateaus, and Appalachian Plateaus physiographic provinces, including the portion of the Appalachian fold and thrust belt buried beneath Cretaceous and younger sediments that were deposited on the U.S. Gulf Coastal Plain.

The source rock characters of U-rich granite

Energy Technology Data Exchange (ETDEWEB)

Mingyue, Feng; Debao, He [CNNC Key Laboratory of Uranium Resources Exploration and Evaluation Technology, Beijing Research Institute of Uranium Geology (China)

2012-03-15

This paper discusses the stratum composition, lithological association, uranium content of crust and the activation, migration, concentration of uranium at each tectonic cycle in South China. The authors point out that the source rock of U-rich granite is U-rich continental crust which is rich in Si, Al and K. The lithological association is mainly composed of terrestrial clastic rocks formation of mudstone and sandstone, mingled with intermediate-acidic, mafic pyroclastic rocks and carbonate rocks formation. During tectonic movements, the rocks had undergone regional metamorphism, migmatitization, granitization, and formed U-rich granites finally. (authors)

The source rock characters of U-rich granite

International Nuclear Information System (INIS)

Feng Mingyue; He Debao

2012-01-01

This paper discusses the stratum composition, lithological association, uranium content of crust and the activation, migration, concentration of uranium at each tectonic cycle in South China. The authors point out that the source rock of U-rich granite is U-rich continental crust which is rich in Si, Al and K. The lithological association is mainly composed of terrestrial clastic rocks formation of mudstone and sandstone, mingled with intermediate-acidic, mafic pyroclastic rocks and carbonate rocks formation. During tectonic movements, the rocks had undergone regional metamorphism, migmatitization, granitization, and formed U-rich granites finally. (authors)

International Uranium Resources Evaluation Project (IUREP) orientation phase mission summary report: Ghana

International Nuclear Information System (INIS)

1985-01-01

A report has recently been published which describes the findings of the International Uranium Resources Evaluation Project (IUREP) Mission to Ghana. The IUREP Orientation Phase Mission to Ghana estimates that the Speculative Resources of that country fall within the range of 15 000 to 40 000 tonnes of uranium. The majority of this potential is expected to be located in the Proterozoic Panafrican Mobile Belt (up to 17 000 tonnes uranium) and the Paleozoic Obosum Beds of the Voltaian basin (up to 15 000 tonnes uranium), the remainder being associated with various other geological environments. The mission recommends that over a period of three (3) years approximately U.S. $5 million) would be spent on exploration in Ghana. A major part of this (U.S $2 million) would be spent on an airborne spectrometer survey over the Voltaian basin (Obosum beds), much of the remainder being spent on ground surveys, trenching and percussion drilling. (author)

Dependence of the Ratio between the Resonance Integral and Thermal Neutron Cross Section on the Deviation of the Epithermal Neutron Spectrum from the 1/E Law

International Nuclear Information System (INIS)

Soliman, N.F.

2012-01-01

In k 0 - Neutron Activation Analysis (k 0 -NAA), the conversion from the tabulated Q 0 (ratio of the resonance integral to thermal neutron cross-section)to Q 0 (α) (α is the shape factor of the epithermal neutron flux, indicating the deviation of the epithermal neutron spectrum from the ideal 1/E shape) are calculated using a FORTRAN program. The calculations are done for most elements that can be detected by neutron activation using different values of the parameter (α) ranging from -0.1≤α≤+0.1. The obtained data are used to study the dependence of the values (α) on the irradiation position factor in (k 0 -NAA)equation for some selected isotopes differ in their resonance energy and its Q 0 values. The results show that, the irradiation factor is affective mainly for low thermal tro epithermal flux ratio f especially for Q 0 value greater than 50. so consequently determining the irradiation parameters α value is not needed for irradiation positions that rich with thermal neutron. But for high f values the irradiation position factor should be taken into account. On the other hand the constructed FORTRAN program can be used to calculate the value Q 0 (α) directly for different value of α

International Uranium Resources Evaluation Project (IUREP) national favourability studies: Sikkim

International Nuclear Information System (INIS)

1977-11-01

Sikkim is a country in the eastern Himalayas and is bound on the west by Nepal, on the north by Tibet, on the east by Bhutan and on the south by India. Precambrian Darjeeling gneiss forms the rim of the amphitheatre while schists of Late Precambrian to Lower Paleozoic rocks form tee habital interior. A small outcrop of carboniferous to Permain methomorphic rocks is preserved in the Tista Basin as well in a thin outcrop trust upon fluvitile beds of Sivalik which is mostly of Pliestocene age. Imbricate thrusts have stacked the rocks in a vast heap where reverse metamorphism is common. Ni information is available concerning uranium occurrences and resources as well as past and present explorations. The uranium potential of Sikkim is almost zero

Geochemical and modal data for igneous rocks associated with epithermal mineral deposits

Science.gov (United States)

du Bray, Edward A.

2014-01-01

The purposes of this report are to (1) present available geochemical and modal data for igneous rocks associated with epithermal mineral deposits and (2) to make those data widely and readily available for subsequent, more in-depth consideration and interpretation. Epithermal precious and base-metal deposits are commonly associated with subduction-related calc-alkaline to alkaline arc magmatism as well as back-arc continental rift magmatism. These deposits form in association with compositionally diverse extrusive and intrusive igneous rocks. Temperature and depth regimes prevailing during deposit formation are highly variable. The deposits form from hydrothermal fluids that range from acidic to near-neutral pH, and they occur in a variety of structural settings. The disparate temperature, pressure, fluid chemistry, and structural controls have resulted in deposits with wide ranging characteristics. Economic geologists have employed these characteristics to develop classification schemes for epithermal deposits and to constrain the important genetic processes responsible for their formation.

Mechanical design of epithermal neutron diagnostic for TFTR

International Nuclear Information System (INIS)

Groo, R.C.

1981-01-01

The mechanical design of the Epithermal Neutron Diagnostic for TFTR is described. This fission detector system measures the time resolution of the neutron flux for folding into the Neutron Activation system and also provides continuous, wide range coverage of all expected fusion reaction rates

National Uranium Resource Evaluation: Marfa Quadrangle, Texas

International Nuclear Information System (INIS)

Henry, C.D.; Duex, T.W.; Wilbert, W.P.

1982-09-01

The uranium favorability of the Marfa 1 0 by 2 0 Quadrangle, Texas, was evaluated in accordance with criteria established for the National Uranium Resource Evaluation. Surface and subsurface studies, to a 1500 m (5000 ft) depth, and chemical, petrologic, hydrogeochemical, and airborne radiometric data were employed. The entire quadrangle is in the Basin and Range Province and is characterized by Tertiary silicic volcanic rocks overlying mainly Cretaceous carbonate rocks and sandstones. Strand-plain sandstones of the Upper Cretaceous San Carlos Formation and El Picacho Formation possess many favorable characteristics and are tentatively judged as favorable for sandstone-type deposits. The Tertiary Buckshot Ignimbrite contains uranium mineralization at the Mammoth Mine. This deposit may be an example of the hydroauthigenic class; alternatively, it may have formed by reduction of uranium-bearing ground water produced during diagenesis of tuffaceous sediments of the Vieja Group. Although the presence of the deposit indicates favorability, the uncertainty in the process that formed the mineralization makes delineation of a favorable environment or area difficult. The Allen intrusions are favorable for authigenic deposits. Basin fill in several bolsons possesses characteristics that suggest favorability but which are classified as unevaluated because of insufficient data. All Precambrian, Paleozoic, other Mesozoic, and other Cenozoic environments are unfavorable

Analysis of geological condition of uranium mineralization in the Xiangshan northern uranium orefield in central region of Jiangxi Province

International Nuclear Information System (INIS)

Zhou Yulong; Liu Yunlang; Gao Yan

2013-01-01

According to the basic conditions of 'source, guide, transportation, storage' for uranium mineralization in strata and different types of geological structure, departure from the condition, the coupling effect of stratigraphy, lithology and structure are studied in the process of uranium mineralization in northern Xiangshan volcanic basin. Studies show that the northern ore field are of good metallogenic geological conditions and the uranium rich ancient land mass and uranium rich magma generated by the melting of deep metamorphic rocks. The main geologic events are volcanic eruptions, accompanied by repeated subvolcanic magma intrusion and strong faults and nappe tectonics which result in volcanic collapse and volcanic ring structures. These ore-forming geological condition control the structural frame for the formation of main uranium deposit type-subvolcanic rocks in northern Xiangshan ore field. (authors)

Thirty years of uranium ore processing in Spain

International Nuclear Information System (INIS)

Josa, J.M.

1982-01-01

Spanish background in the uranium ore processing includes ores from pegmatitic type deposits, vein deposits, sandstone, enrichments in metamorphic rocks, radioactive coals and non-conventional sources of uranium, such as wet phosphoric acid or copper liquors. Some tests have also done in order to recover uranium from very low grade paleozoic quartzites. We have also been involved in by-products recovery (copper) from uranium ores. The technologies that have been used are: physical concentration, combustion and roasting, conventional alkaline or acid methods, pressure, heap and bacteria leaching. Special attention was paid to recover uranium from the pregnant liquors and to develop suited equipment for it; solvent extraction and continuous ion exchange equipment was carefully studied. We have been involved in commercial size (500-3000 t/d) mills, but we have also developed transportable and reussable modular plants specially designed and suited to recover uranium from small and isolated deposits. In both cases the reduction of the environmental impact was taken in account. Spanish experience also includes nuclear purification aspects in order to get uranium nuclear compounds (ADU, UO 2 , UF 4 and UF 6 ). Wet (nitric-TBP) and dry (Fluid-bed) methods have been used. The best of these 30 years of experience in studies and in industrial practice, together with our new developments towards the future, could become in a good contribution for the medium size countries which are going to develop its own uranium industry. The way for these countries could be easier if they know what is valuable and what must be avoid in the uranium ore processing development. In this aim the whole paper was thought and written. (author)

Research on geochronology and uranium source of sandstone-hosted uranium ore-formation in major uranium-productive basins, Northern-China

International Nuclear Information System (INIS)

Xia Yuliang; Liu Hanbin; Lin Jinrong; Fan Guang; Hou Yanxian

2004-12-01

A method is developed for correcting uranium content in uranium ore samples by considering the U-Ra equilibrium coefficient, then a U-Pb isochron is drawn up. By performing the above correction ore-formation ages of sandstone-hosted uranium mineralization which may be more realistic have been obtained. The comparative research on U-Pb isotopic ages of detritic zircon in ore-hosting sandstone and zircon in intermediate-acid igneous rocks in corresponding provenance area indicates that the ore-hosting sandstone is originated from the erosion of intermediate-acid igneous rocks and the latters are the material basis for the formation of the uranium-rich sandstone beds. On the basis of the study on U-Pb isotopic system evolution of the provenance rocks and sandstones from ore-hosting series, it is verified that the uranium sources of the sandstone-hosted uranium deposit are: the intermediate-acid igneous rocks with high content of mobile uranium, and the sandstone bodies pre-concentrated uranium. (authors)

Contribution to the geochemical knowledge of the uranium-radium and thorium families in the southern Vosges. Applications of some results in the prospecting of uranium deposits; Contribution a la connaissance geochimique des familles uranium-radium et du thorium dans les Vosges meridionales. Application de certains resultats en prospection des gisements d'uranium

Energy Technology Data Exchange (ETDEWEB)

Jurain, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1962-07-01

This work's aim is to lead to a more accurate knowledge of the geochemistry of the Uranium-Radium and Thorium families in the Southern Vosges and to apply some of the results to the prospecting of uraniferous deposits: It has been showed: a bond between Calcium-Magnesium and Uranium-Thorium in the calco-alkaline granites. The host minerals of Uranium and Thorium are hornblende, biotite, titanite and epidote. a concentration of Uranium, at present time with secular disequilibrium in a thermal zone where the satellite mineralizations form an epithermal paragenesis. a disequilibrium of the Uranium-Radium family in the supergene minerals of the lead (phosphate and vanadate) showing the present circulations of Uranium. a bond between the radon grade of the spring waters and Uranium-Radium of the rocks. Such a relation allow to realize a prospecting method based on the determination of radioactive gases from the cold spring-waters of a common country. (author) [French] L'etude presentee ici a pour but de conduire a une connaissance plus precise de la geochimie des familles Uranium-Radium et Thorium dans les Vosges meridionales et d'appliquer certains resultats a la prospection des gites uraniferes. Il a ete mis en evidence: une liaison Calcium-Magnesium et Uranium-Thorium dans des granites calco-alcalins. Les mineraux hotes de l'Uranium et du Thorium sont: la hornblende, la biotite, le sphene, l'epidote. une concentration actuelle de l'Uranium en desequilibre seculaire dans une zone thermale ou les mineralisations satellites constituent une paragenese epithermale. un desequilibre de la famille Uranium-Radium dans des mineraux supergenes du plomb (phosphates et vanadates) prouvant les circulations actuelles de l'Uranium. une liaison entre la teneur en Radon des eaux de sources et celle en Uranium-Radium des roches. Une telle liaison permet de realiser une methode de prospection fondee sur le dosage du gaz radioactif des eaux de sources froides d'une region quelconque

Contribution to the geochemical knowledge of the uranium-radium and thorium families in the southern Vosges. Applications of some results in the prospecting of uranium deposits; Contribution a la connaissance geochimique des familles uranium-radium et du thorium dans les Vosges meridionales. Application de certains resultats en prospection des gisements d'uranium

Energy Technology Data Exchange (ETDEWEB)

Jurain, G. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1962-07-01

This work's aim is to lead to a more accurate knowledge of the geochemistry of the Uranium-Radium and Thorium families in the Southern Vosges and to apply some of the results to the prospecting of uraniferous deposits: It has been showed: a bond between Calcium-Magnesium and Uranium-Thorium in the calco-alkaline granites. The host minerals of Uranium and Thorium are hornblende, biotite, titanite and epidote. a concentration of Uranium, at present time with secular disequilibrium in a thermal zone where the satellite mineralizations form an epithermal paragenesis. a disequilibrium of the Uranium-Radium family in the supergene minerals of the lead (phosphate and vanadate) showing the present circulations of Uranium. a bond between the radon grade of the spring waters and Uranium-Radium of the rocks. Such a relation allow to realize a prospecting method based on the determination of radioactive gases from the cold spring-waters of a common country. (author) [French] L'etude presentee ici a pour but de conduire a une connaissance plus precise de la geochimie des familles Uranium-Radium et Thorium dans les Vosges meridionales et d'appliquer certains resultats a la prospection des gites uraniferes. Il a ete mis en evidence: une liaison Calcium-Magnesium et Uranium-Thorium dans des granites calco-alcalins. Les mineraux hotes de l'Uranium et du Thorium sont: la hornblende, la biotite, le sphene, l'epidote. une concentration actuelle de l'Uranium en desequilibre seculaire dans une zone thermale ou les mineralisations satellites constituent une paragenese epithermale. un desequilibre de la famille Uranium-Radium dans des mineraux supergenes du plomb (phosphates et vanadates) prouvant les circulations actuelles de l'Uranium. une liaison entre la teneur en Radon des eaux de sources et celle en Uranium-Radium des roches. Une telle liaison permet de realiser une methode de prospection fondee sur le dosage du gaz radioactif des eaux de sources

Experimental demonstration of a compact epithermal neutron source based on a high power laser

Science.gov (United States)

Mirfayzi, S. R.; Alejo, A.; Ahmed, H.; Raspino, D.; Ansell, S.; Wilson, L. A.; Armstrong, C.; Butler, N. M. H.; Clarke, R. J.; Higginson, A.; Kelleher, J.; Murphy, C. D.; Notley, M.; Rusby, D. R.; Schooneveld, E.; Borghesi, M.; McKenna, P.; Rhodes, N. J.; Neely, D.; Brenner, C. M.; Kar, S.

2017-07-01

Epithermal neutrons from pulsed-spallation sources have revolutionised neutron science allowing scientists to acquire new insight into the structure and properties of matter. Here, we demonstrate that laser driven fast (˜MeV) neutrons can be efficiently moderated to epithermal energies with intrinsically short burst durations. In a proof-of-principle experiment using a 100 TW laser, a significant epithermal neutron flux of the order of 105 n/sr/pulse in the energy range of 0.5-300 eV was measured, produced by a compact moderator deployed downstream of the laser-driven fast neutron source. The moderator used in the campaign was specifically designed, by the help of MCNPX simulations, for an efficient and directional moderation of the fast neutron spectrum produced by a laser driven source.

Preliminary study of the uranium favorability of Malheur County, Oregon

International Nuclear Information System (INIS)

Erikson, E.H.

1977-11-01

A reconnaissance study of middle and upper Tertiary volcaniclastic sedimentary and silicic volcanic rocks in Malheur County, Oregon, indicates that, based upon the data available: (1) it is unlikely that sandstone-type uranium deposits exist in sedimentary rocks of north-central Malheur County; and (2) favorable uranium environments are more likely to exist in and adjacent to uraniferous silicic eruptive centers and plugs. Some rhyolites in the northern part of the county contain marginally anomalous uranium abundances (6 to 8 +- 2 ppM U 3 O 8 ), compared with similar rocks in southeastern Oregon. Available uranium from these rocks, as determined by nitric-acid leaching, approaches 50 to 75 percent of the total chemical U 3 O 8 present. One Pliocene rhyolite vitrophyre sample from Duck Butte in western Malheur County contains 9 +- 2 ppM U 3 O 8 . The uranium contents of these rhyolites approach those found in silicic plugs spatially related to uranium deposits in the Lakeview district, Oregon (Erikson and Curry, 1977). It is possible that undiscovered epithermal and (or) supergene uranium deposits may exist in favorable wall rocks subjacent to uraniferous silicic eruptive centers (Duck Butte), calderas (McDermitt caldera to the south and others identified in western Owyhee County, Idaho), and silicic plugs (as in the Lakeview district). With the exception of one small uranium anomaly found in unconsolidated sands in the Grassy Mountain Formation, the sedimentary rocks observed in the study area did not possess abnormal radioactivity or exhibit evidence of uranium mobility and enrichment. Carbonaceous trash is uncommon in these rocks. Gently dipping sandstone members of the Deer Butte Formation (upper Miocene) and local channel sands in the Grassy Mountain Formation (Pliocene) may have once been the most permeable rocks in the Tertiary section; but, there is no evidence to suggest that they were conduits for uranium-bearing solutions

Ontogenetic evidence for the Paleozoic ancestry of salamanders.

Science.gov (United States)

Schoch, Rainer R; Carroll, Robert L

2003-01-01

The phylogenetic positions of frogs, salamanders, and caecilians have been difficult to establish. Data matrices based primarily on Paleozoic taxa support a monophyletic origin of all Lissamphibia but have resulted in widely divergent hypotheses of the nature of their common ancestor. Analysis that concentrates on the character states of the stem taxa of the extant orders, in contrast, suggests a polyphyletic origin from divergent Paleozoic clades. Comparison of patterns of larval development in Paleozoic and modern amphibians provides a means to test previous phylogenies based primarily on adult characteristics. This proves to be highly informative in the case of the origin of salamanders. Putative ancestors of salamanders are recognized from the Permo-Carboniferous boundary of Germany on the basis of ontogenetic changes observed in fossil remains of larval growth series. The entire developmental sequence from hatching to metamorphosis is revealed in an assemblage of over 600 specimens from a single locality, all belonging to the genus Apateon. Apateon forms the most speciose genus of the neotenic temnospondyl family Branchiosauridae. The sequence of ossification of individual bones and the changing configuration of the skull closely parallel those observed in the development of primitive living salamanders. These fossils provide a model of how derived features of the salamander skull may have evolved in the context of feeding specializations that appeared in early larval stages of members of the Branchiosauridae. Larvae of Apateon share many unique derived characters with salamanders of the families Hynobiidae, Salamandridae, and Ambystomatidae, which have not been recognized in any other group of Paleozoic amphibians.

Design considerations for epithermal pulse reactors

International Nuclear Information System (INIS)

Ostensen, R.W.

1978-01-01

Simplified design criteria were developed for scoping analyses of epithermal pulse reactors for use in LMFBR safety testing. By using these criteria, materials and designs were investigated to determine performance limits of moderately sized reactor cores. Several designs are suggested for further study. These are a gas-cooled core fueled with a heterogeneous mixture of Fe-UO 2 cermet and BeO-UO 2 ceramic fuels, and a heavy-water-cooled core fueled with an Fe-UO 2 cermet

A paleozoic pangaea.

Science.gov (United States)

Boucot, A J; Gray, J

1983-11-11

Paleozoic paleogeographies should be consistent with all available, reliable data. However, comparison of three different Devonian paleogeographies that are based largely or wholly on the data of remanent magnetism show them to be inconsistent in many regards. When these three paleogeographies are provided with possible ocean surface current circulation patterns, and have added to them lithofacies and biogeographic data, they also are shown to be inconsistent with such data. A pangaeic reconstruction positioned in the Southern Hemisphere permits the lithofacies and biogeographical data to be reconciled in a plausible manner.

National uranium resource evaluation, Hot Springs Quadrangle, South Dakota and Nebraska

International Nuclear Information System (INIS)

Truesdell, D.B.; Daddazio, P.L.; Martin, T.S.

1982-06-01

The Hot Springs Quadrangle, South Dakota and Nebraska, was evaluated to a depth of 1500 m to identify environments and delineate areas favorable for the occurrence of uranium deposits. The evaluation used criteria developed by the National Uranium Resource Evaluation program. Surface reconnaissance was conducted using a portable scintillometer and a gamma spectrometer. Geochemical sampling was carried out in all geologic environments accessible within the quadrangle. Additional investigations included the followup of aerial radiometric and hydrogeochemical anomalies and a subsurface study. Environments favorable for sandstone-type deposits occur in the Inyan Kara Group and Chadron Member of the White River Group. Environments favorable for marine black-shale deposits occur in the Hayden Member of the Minnelusa Formation. A small area of the Harney Peak Granite is favorable for authigenic deposits. Environments considered unfavorable for uranium deposits are the Precambrian granitic and metasedimentary rocks and Paleozoic, Mesozoic, and Tertiary sedimentary rocks other than those previously mentioned

Epithermal neutron beam adoption for lung and pancreatic cancer treatment by boron neutron capture therapy

International Nuclear Information System (INIS)

Matsumoto, Tetsuo; Fukushima, Yuji

2001-01-01

The depth-dose distributions were evaluated for possible treatment of both lung and pancreatic cancers using an epithermal neutron beam. The Monte Carlo Neutron Photon (MCNP) calculations showed that physical dose in tumors were 6 and 7 Gy/h, respectively, for lung and pancreas, attaining an epithermal neutron flux of 5 x 10 8 ncm -2 s -1 . The boron concentrations were assumed at 100 ppm and 30 ppm, respectively, for lung and pancreas tumors and normal tissues contains 1/10 tumor concentrations. The dose ratios of tumor to normal tissue were 2.5 and 2.4, respectively, for lung and pancreas. The dose evaluation suggests that BNCT using an epithermal neutron beam could be applied for both lung and pancreatic cancer treatment. (author)

Uranium in early proterozoic phosphate-rich metasedimentary rocks of east-central Minnesota

International Nuclear Information System (INIS)

McSwiggen, P.L.; Morey, G.B.; Weiblen, P.W.

1986-01-01

Exploration for unconformity-type uranium deposits in the late 1970s in east-central Minnesota led to the discovery of several uranium-bearing phosphorite occurrences in rocks of early Proterozoic age. In this report the authors use the term phosphorite for a rock or specimen that contains substantial sedimentary apatite (Altschuler et al., 1958). The deposits in Minnesota are especially interesting because of their high uranium content but low metamorphic grade. These occurrences characteristically contain 0.025 to 0.085 percent U and locally as much as 0.157 percent U (Ullmer, 1981), whereas typical primary marine phosphorites have uranium contents of 0.005 to 0.02 percent U (Altschuler et al., 1958). The presence of uranium in a marine phosphorite generally is explained by either the replacement of calcium in the apatite crystal structure or the adsorption of uranium in admixed organic matter and cryptocrystalline apatite. In east-central Minnesota the uranium is closely associated with the finely crystalline apatite, but the uranium has also been involved in several episodes of remobilization and redeposition. Thus, even though the phosphorite deposits are an interesting geologic phenomenon in themselves, they also are important as a possible source for epigenetic uranium deposits that may occur in the area

Bedded Barite Deposits from Sonora (nw Mexico): a Paleozoic Analog for Modern Cold Seeps

Science.gov (United States)

Canet, C.; Anadón, P.; González-Partida, E.; Alfonso, P.; Rajabi, A.; Pérez-Segura, E.; Alba-Aldave, L. A.

2013-05-01

The Mazatán barite deposits represent an outstanding example of Paleozoic bedded barite, a poorly understood type of mineral deposit of major economic interest. The largest barite bodies of Mazatán are hosted within an Upper Carboniferous flysch succession, which formed part of an accretionary wedge related to the subduction of the Rheic Ocean beneath Gondwana. As well, a few barite occurrences are hosted in Upper Devonian, pre-orogenic turbidites. A variety of mineralized structures is displayed by barite, including: septaria nodules, enterolitic structures, rosettes and debris-flow conglomerates. Barite is accompanied by chalcedony, pyrite (framboids) and berthierine. Gas-rich fluid inclusions in barite were analyzed by Raman spectroscopy and methane was identified, suggesting the occurrence of light hydrocarbons in the environment within which barite precipitated. 13C-depleted carbonates (δ13C: -24.3 to -18.8‰) were found in the barite deposits; they formed through anaerobic oxidation of methane coupled to sulfate reduction, and yield negative δ18O values (-11.9 to -5.2‰) reflecting the isotopic composition of Devonian-Carboniferous seawater. Methane-derived carbonates occur in modern hydrocarbon seeps and have been reported from Mesozoic and Cenozoic seep sediments, but they have never before been described in Paleozoic bedded barite deposits. δ34S of barite varies from +17.6 to +64.1‰, with the lowest values overlapping the range for coeval seawater sulfate; this distribution indicates a process of sulfate reduction. Barite precipitation can be explained by mixing of methane- and barium-rich fluids with pore-water (seawater) containing sulfate residual from microbial reduction. Two analyses from barite gave an 87Sr/86Sr within and slightly above the range for seawater at the time of deposition, with 0.708130 and 0.708588, which would preclude the involvement of hydrothermal fluids in the mineralization process.

The epithermal neutron-flux distribution in the reactor RA - Vinca

International Nuclear Information System (INIS)

Marinkov, V.; Bikit, I.; Martinc, R.; Veskovic, M.; Slivka, J.; Vaderna, S.

1987-01-01

The distribution of the epithermal neutron flux in the reactor RA - Vinca has been measured by means of Zr - activation detectors. In the channel VK-8 non-homogeneous flux distribution was observed (author) [sr

Epithermal gold occurrences in the lakes district of the Main ...

African Journals Online (AJOL)

MER). Epithermal gold occurrences related to Quaternary volcanics are at present being closely studied for their precious metal potential. Low sulphidation (Adularia-sericite-type) occurrences have been found. Analyses of 579 core and cutting ...

Uranium and thorium content of some sedimentary and igneous rocks from the Rolla 10 x 20 quadrangle, Missouri

International Nuclear Information System (INIS)

Odland, S.K.; Millard, H.T. Jr.

1979-01-01

Uranium and thorium contents of 175 samples of Precambrian and overlying sedimentary rocks from 28 drill holes in the Rolla 1 0 x 2 0 quadrangle, Missouri, were determined in 1978 as part of the National Uranium Resource Evaluation (NURE) effort. The limited number of drill-hole samples analyzed and the great distance between drill holes does not provide sufficient analytical data for an evaluation of the uranium potential in this quadrangle. However, because NURE studies in the quadrangle have been recessed, the data at hand are being made available in this report. The 175 rock samples for uranium and thorium analyses were selected to determine the uranium and thorium content of lower Paleozoic stratigraphic units in the quadrangle, and to test the conceptual model of uranium accumulation in basal sandstones, conglomerates, and arkoses that onlap the Precambrian igneous rocks. The conceptual model of uranium in intragranitic veins was not tested, because not all drill holes penetrate Precambrian rocks and none penetrate them more than a few meters

Fission reactor based epithermal neutron irradiation facilities for routine clinical application in BNCT-Hatanaka memorial lecture

International Nuclear Information System (INIS)

Harling, Otto K.

2009-01-01

Based on experience gained in the recent clinical studies at MIT/Harvard, the desirable characteristics of epithermal neutron irradiation facilities for eventual routine clinical BNCT are suggested. A discussion of two approaches to using fission reactors for epithermal neutron BNCT is provided. This is followed by specific suggestions for the performance and features needed for high throughput clinical BNCT. An example of a current state-of-the-art, reactor based facility, suited for routine clinical use is discussed. Some comments are provided on the current status of reactor versus accelerator based epithermal neutron sources for BNCT. This paper concludes with a summary and a few personal observations on BNCT by the author.

National Uranium Resource Evaluation: Lovelock Quadrangle, Nevada and California

International Nuclear Information System (INIS)

Berry, V.P.; Bradley, M.T.; Nagy, P.A.

1982-08-01

Uranium resources of the Lovelock Quadrangle, Nevada and California, were evaluated to a depth of 1500 m using available surface and subsurface geological information. Uranium occurrences reported in the literature and in reports of the Atomic Energy Commission were located, sampled, and described in detail. Areas of anomalous radioactivity, as interpreted from the aerial radiometric reconnaissance survey and from the hydrochemical and stream-sediment reconnaissance survey reports, were also investigated. A general reconnaissance of the geologic environments exposed in surface outcrops was carried out; and over 400 rock, sediment, and water geochemical analyses were made from the samples taken. Additionally, 119 rock samples were petrographically studied. A total of 21 occurrences were located, sampled, and described in detail. Six uranium occurrences, previously unreported in the literature, were located during hydrogeochemical and stream-sediment reconnaissance, aerial radiometric reconnaissance survey followup, or general outcrop reconnaissance. Nine areas of uranium favorability were delineated within the Lovelock Quadrangle. One area, which contains the basal units of the Hartford Hill Rhyolite, is favorable for hydroallogenic uranium deposits. Eight areas are favorable for uranium deposits in playa sediments. These playas are considered favorable for nonmarine carbonaceous sediment deposits and evaporative deposits. The total volume of rock in favorable areas of the Lovelock Quadrangle is estimated to be 190 km 3 . The remaining geologic units are considered to be unfavorable for uranium deposits. These include upper Paleozoic and Mesozoic volcanic, plutonic, sedimentary, and metamorphic rocks. Also unfavorable are Tertiary and Quaternary volcanic flows and intrusive phases, tuffs, and sediments

A preliminary investigation on the epithermal flux depression effect due to cadmium box in a multiplying medium

International Nuclear Information System (INIS)

Ahmad, A.

1983-01-01

Cadmium boxes are widely used as filter in Reactor Neutron Activation Analysis (RNAA) for the irradiation of samples in epithermal neutrons. By virtue of being an absorber the cadmium boxes produce epithermal flux depression in the medium surrounding them. A preliminary study of this effect was carried out (author)

Magnetic, radiometric and gravity signatures of localities of epithermal gold deposits in Fiji

International Nuclear Information System (INIS)

Gunn, Peter J.; Mackey, Tim; Meixner, Tony J.

1998-01-01

Fiji contains several epithermal gold deposits and by studying the geophysical responses in the vicinity of these deposits it is possible to identify a set of geophysical characteristics which indicate localities where such deposits may be located. Epithermal gold deposits are formed above intrusive stocks resulting from subduction processes. The source intrusions for the deposits are normally covered by lavas and pyroclastic rocks and the irregular magnetic effects of these units obscure the magnetic effects of the intrusions. In Fiji however the source intrusions can be recognized as causing gravity highs and magnetic highs in upward continued magnetic data in which the magnetic effects of volcanic rocks are suppressed. Vents associated with the intrusions can be recognized as magnetic lows which sometimes contain a central high. Some vents and calderas can be recognized in digital elevation data. Increased potassium concentrations ca be interpreted to indicate potassium alteration associated with mineralizing processes. Fractures that may localize epithermal deposits can be recognized in the magnetic data and enhancements of the data such as produced by derivative operations. (author)

Earth formation pulsed neutron porosity logging system utilizing epithermal neutron and inelastic scattering gamma ray detectors

International Nuclear Information System (INIS)

Smith, H.D. Jr.; Smith, M.P.; Schultz, W.E.

1978-01-01

An improved pulsed neutron porosity logging system is provided in the present invention. A logging tool provided with a 14 MeV pulsed neutron source, an epithermal neutron detector and an inelastic scattering gamma ray detector is moved through a borehole. The detection of inelastic gamma rays provides a measure of the fast neutron population in the vicinity of the detector. repetitive bursts of neutrons irradiate the earth formation and, during the busts, inelastic gamma rays representative of the fast neutron population is sampled. During the interval between bursts the epithermal neutron population is sampled along with background gamma radiation due to lingering thermal neutrons. the fast and epithermal neutron population measurements are combined to provide a measurement of formation porosity

Multipurpose epithermal neutron beam on new research station at MARIA research reactor in Swierk-Poland

Energy Technology Data Exchange (ETDEWEB)

Gryzinski, M.A.; Maciak, M. [National Centre for Nuclear Research, Andrzeja Soltana 7, 05-400 Otwock-Swierk (Poland)

2015-07-01

MARIA reactor is an open-pool research reactor what gives the chance to install uranium fission converter on the periphery of the core. It could be installed far enough not to induce reactivity of the core but close enough to produce high flux of fast neutrons. Special design of the converter is now under construction. It is planned to set the research stand based on such uranium converter in the near future: in 2015 MARIA reactor infrastructure should be ready (preparation started in 2013), in 2016 the neutron beam starts and in 2017 opening the stand for material and biological research or for medical training concerning BNCT. Unused for many years, horizontal channel number H2 at MARIA research rector in Poland, is going to be prepared as a part of unique stand. The characteristics of the neutron beam will be significant advantage of the facility. High flux of neutrons at the level of 2x10{sup 9} cm{sup -2}s{sup -1} will be obtainable by uranium neutron converter located 90 cm far from the reactor core fuel elements (still inside reactor core basket between so called core reflectors). Due to reaction of core neutrons with converter U{sub 3}Si{sub 2} material it will produce high flux of fast neutrons. After conversion neutrons will be collimated and moderated in the channel by special set of filters and moderators. At the end of H2 channel i.e. at the entrance to the research room neutron energy will be in the epithermal energy range with neutron intensity at least at the level required for BNCT (2x10{sup 9} cm{sup -2}s{sup -1}). For other purposes density of the neutron flux could be smaller. The possibility to change type and amount of installed filters/moderators which enables getting different properties of the beam (neutron energy spectrum, neutron-gamma ratio and beam profile and shape) is taken into account. H2 channel is located in separate room which is adjacent to two other empty rooms under the preparation for research laboratories (200 m2). It is

Comparison of neutron activation analysis techniques for the determination of uranium concentrations in geological and environmental materials

International Nuclear Information System (INIS)

Landsberger, S.; Kapsimalis, R.

2013-01-01

We have described the determination of uranium in environmental, geological, and agricultural specimens by three different non-destructive nuclear methods. The effectiveness, as defined as the lower limits of detection in this work, of quantifying trace levels of bulk uranium in geological samples was evaluated for several common NAA techniques. These techniques include short-lived and medium-lived neutron activation analysis using thermal and epithermal neutrons; these results were compared with an assessment of Compton suppressed gamma-ray counting. A careful evaluation of three major (n,γ) reactions with chlorine, manganese and sodium that could impede determining low levels of uranium due to high Compton continuums was done. The evaluation of Compton suppressed passive gamma counting revealed that uranium concentrations below 50 mg kg −1 were not adequate to achieve good counting statistics using the 234m Pa the second daughter product of 238 U. -- Highlights: ► Determination of uranium concentrations in geological, environmental, and agricultural specimens. ► Use of several NAA and passive counting methods. ► Identified several key interferences. ► Use of Compton suppression to minimize effects of interferences

The resonant detector and its application to epithermal neutron spectroscopy

International Nuclear Information System (INIS)

Gorini, G.; Perelli-Cippo, E.; Tardocchi, M.; Andreani, C.; D'Angelo, A.; Pietropaolo, A.; Senesi, R.; Imberti, S.; Bracco, A.; Previtali, E.; Pessina, G.; Rhodes, N.J.; Schooneveld, E.M.

2004-01-01

New perspectives for epithermal neutron spectroscopy are being opened by the development of the resonant detector (RD) and its use on inverse geometry time of flight spectrometers at spallation sources. The RD was first proposed in the 1980s and was recently brought to a performance level exceeding conventional neutron-sensitive Li-glass scintillator detectors. It features a photon counter coupled to a neutron analyzer foil. Resonant neutron absorption in the foil results in the emission of prompt gamma rays that are detected in the photon counter. The dimensions of the RD set the spatial resolution that can be achieved, ranging from a fraction of a cm to several cm. It can thus be tailored to the construction of detector arrays of different geometry. The main results of the research on this kind of detector are reported leading to the present optimized RD design based on a combination of YAP scintillation photon counter and uranium or gold analyzer foils. This detector has already been selected for application in the upgrade of the VESUVIO spectrometer on ISIS. A special application is the Very Low Angle Detector (VLAD) bank, which will extend the kinematical region for neutron scattering to low momentum transfer ( -1 ) whilst still keeping energy transfer >1 eV, thus allowing new experimental studies in condensed matter systems. The first results of tests made with prototype VLAD detectors are presented, confirming the usefulness of the RD for measurements at scattering angles as low as 2-5 deg

Characteristics of uranium geological anomaly in Northern Guangdong province

International Nuclear Information System (INIS)

Wang Xinwu; Cheng Danping

2001-01-01

The geological anomaly characteristics of uranium deposit region in northern Guangdong are discussed on the aspects of uranium source, structure and thermal activity. Uranium deposits usually occur in the uranium-rich background field. Structure activity provides favourable places for the transportation and precipitation of uranium. Uranium deposits are formed in the central and edge of frequent thermal activity. The assembled entropy anomaly field is the synthetical display for above three anomaly. The biggest assembled entropy anomaly is the most favourable space field for forming uranium deposit

Theoretical and experimental study of collectrons for epithermal neutron flux in reactors

International Nuclear Information System (INIS)

Agu, M.N.

1986-01-01

A theoretical study of nuclear reactions and electric charge displacements arising in sensitivity to thermal and epithermal neutrons in collectrons allowed a computer code conception. Collectrons in Rhodium, Silver, Cobalt, Hafnium, Erbium, Gadolinium and Holmium have been tested in different radiation fields given by neutron or gamma filters irradiated in different places of Melusine and Siloe reactors. Some emitters were covered with different steel, nickel or zircaloy thicknesses. Theoretical and experimental results are consistent; that validate the computer code and show possibilities and necessity of covering collectron emitters to reduce or cancel the gamma sensitivity and to improve response instantaneity. A selective measurement of epithermal neutron flux can by this way, made by associating two types of collectrons [fr

National Uranium Resource Evaluation, Scranton Quadrangle, Pennsylvania, New York, and New Jersey

International Nuclear Information System (INIS)

Baillieul, T.A.; Indelicato, G.J.; Penley, H.M.

1980-11-01

Reconnaissance and detailed geologic and radiometric investigations were conducted throughout the Scranton Quadrangle, Pennsylvania, New York, and New Jersey, to evaluate uranium favorability using National Uranium Resource Evaluation criteria. Surface and subsurface studies were augmented by aerial radiometric, hydrogeochemical and stream sediment reconnaissance, and emanometry surveys. Results of the investigations indicate four environments favorable for uranium deposits: In the Precambrian metamorphic terrain of the Reading Prong, magmatic-hydrothermal and anatectic deposits may occur in the northwestern massif; contact metasomatic deposits may occur in a portion of the southeastern massif. The alluvial-fan environment at the base of the Upper Devonian Catskill Formation appears favorable for deposits in peneconcordant channel controlled sandstones. Seven environments are considered unfavorable for uranium deposits: the southeastern massif of the Reading Prong, exclusive of that portion denoted as a favorable contact metasomatic environment; the lower Paleozoic sedimentary units; the Beemerville nepheline syenite complex; the Upper Devonian Catskill Formation, exclusive of the favorable basal alluvial-fan facies; Mississippian and Pennsylvanian units; and peat bogs. Two environments were not evaluated: the Spechty Kopf Formation, because of paucity of exposure and lack of sufficient data; and the Newark Basin, because of cultural density and inadequate subsurface information

Geochronological framework of the early Paleozoic Bainaimiao Cu-Mo-Au deposit, NE China, and its tectonic implications

Science.gov (United States)

Zhou, Zhen-Hua; Mao, Jing-Wen; Ma, Xing-Hua; Che, He-Wei; Ou'yang, He-Gen; Gao, Xu

2017-08-01

The Bainaimiao Cu-Mo-Au deposit of NE China is an important ore deposit in the middle section of the northern margin of the North China Craton. The early Paleozoic Bainaimiao Group is the main ore-hosting rock. The mineralization at the deposit shows features of porphyry alteration and late-stage orogenesis and transformation. Zircon LA-ICP-MS U-Pb age data indicate that the ages of the Third and Fifth formations of the Bainaimiao Group are 492.7 ± 2.9 Ma (MSWD = 0.53) and 488.9 ± 3.1 Ma (MSWD = 0.92), respectively. The age of quartz diorite that intrudes the Bainaimiao Group is 459.3 ± 6.4 Ma (MSWD = 2.20). Molybdenite samples from massive Cu-Mo-bearing ores and quartz veins in the southern ore belt yield a Re-Os isochron age of 438.2 ± 2.7 Ma (MSWD = 0.16), which is consistent with the Re-Os isochron age of molybdenite in the northern ore belt, implying that the two ore belts belong to the same mineralization system. Muscovite from a post-magmatic Cu-Mo-bearing quartz-calcite vein yields an Ar-Ar isochron age of 422.5 ± 3.9 Ma (MSWD = 0.64) with an initial 40Ar/36Ar ratio of 286 ± 21. The well-defined plateau age of the muscovite is 422.4 ± 2.6 Ma (MSWD = 0.05), which represents the time of the post-magmatic orogenic transformation event. Based on our new age data and previous findings, we propose that the Bainaimiao Cu-Mo-Au deposit formed in an active continental margin setting and experienced four stages of ore mineralization: (1) a Late Cambrian-Middle Ordovician volcanic-sedimentary stage; (2) a Late Ordovician porphyry mineralization stage; (3) a Late Silurian regional metamorphism stage; and (4) an orogenic transformation stage. Subhedral and euhedral Paleoproterozoic (2402-1810 Ma) inherited zircons indicate that the Bainaimiao Group has a tectonic affinity with the North China Craton. The Central Asian Orogenic Belt, which is closely related to the complex closure of the Paleo-Asian Ocean, is favorable for prospecting for Paleozoic porphyry Cu

Characteristics of chlorites from Huangnihu uranium deposit and their implications in uranium metallogenic environment in the southern part of Jiangxi Province

International Nuclear Information System (INIS)

Hu Zhihua; Lin Jinrong; Pang Yaqing; Gao Fei; Rong Jiashu; Guo Shuying

2013-01-01

Chlorite is genetically related to uranium mineralization in Huangnihu uranium deposit. By means of microscopic and electronic microprobe analysis, the authors investigated chemical composition and texture of the chlorite and found that chlorite in Huangnihu deposit has the following characteristics: 1. they are mainly Fe-rich chlorite composed of chamosite and brunsvigite, of which chemical composition is mainly affected by mud and mafic rock; 2. the Fe-Mg and Al"I"V-Si substitution dominates the octahedral substitution supplemented by Al"V"I-Fe substitution; the oolitic chlorite and biotite feinted chlorite closely associated with uranium were formed at temperatures of 216.23 ∼ 256.73℃ (average 228.6℃). The chemical composition and forming environment of the oolitic chlorite and biotite illusion chlorite suggests that Huangnihu uranium deposit is a low-moderate temperature hydrothermal uranium deposit formed in a reducing environment and iron-rich formation, the ore-forming fluid mainly originated from shale rock, partly from ultramafic or mafic liquid. (authors)

Geologic setting and genesis of the Mule Canyon low-sulfidation epithermal gold-silver deposit, north-central Nevada

Science.gov (United States)

John, D.A.; Hofstra, A.H.; Fleck, R.J.; Brummer, J.E.; Saderholm, E.C.

2003-01-01

/or marcasite veins. Ore minerals consist mostly of electrum and Ag sulfide and selenide minerals, with minor to major amounts of pyrite, marcasite, and arsenopyrite, and local stibnite. Both types of ores have similar geochemical signatures, characterized by high Au, Ag, As, Sb, and Se contents, locally high Hg, Mo, Tl, and W contents, and low Cu, Pb, and Zn contents. Stable isotope data indicate that ore fluids consisted dominantly of meteoric water that evolved by deep circulation through Paleozoic sedimentary rocks at low water/rock ratios (about 1) and high temperatures (>200??C). Calculated isotopic compositions of ore fluids are ??18OH2O = -3 to -7 per mil, ??DH2O = -107 to -124 per mil, ??13CCO2 = 0 to -6 per mil, and ??34SH2S = -3 to +8 per mil. The ore fluids obtained much of their H2S and CO2 and probably scavenged ore metals and trace elements from the Paleozoic sedimentary rocks. Some H2S and CO2 may have been derived from degassing Miocene magmas. Mule Canyon formed at shallow depths, probably about 100 m below the paleosurface. Ore fluids were dilute, nearly neutral in pH, reduced, H2S-rich, and CO2-bearing. Peak temperatures in ore zones reached 230?? to 265??C at nearly lithostatic pressures when some crystalline quartz ?? adularia precipitated, but most ore formed at temperatures <200??C at near hydrostatic pressures and was accompanied by precipitation of opaline and chalcedonic silica ?? adularia ?? calcite and dolomite. Deposition of gold in As-rich overgrowths on pyrite and/or marcasite in disseminated ores occurred owing to decreasing H2S in the ore fluids resulting from sulfidation reactions. Later electrum and Ag selenide precipitation in open spaces occurred owing to boiling, loss of H2S to the vapor phase, and cooling. Mule Canyon is similar to most other low-sulfidation Au-Ag deposits associated with Miocene tholeiitic bimodal basalt-rhyolite magmatism in the Great Basin, such as Sleeper, Midas, and Buckhorn. Major differences at Mule Canyon are

Jaduguda uranium mill : rich experiences for future challenges

International Nuclear Information System (INIS)

Beri, K.K.

1991-01-01

India's only uranium milling plant at Jaduguda was commissioned in 1967-68 utilising low grade uranium ore. The flowsheet of the mill and controlling parameters were based on studies done on laboratory and pilot plant scale tests at the Bhabha Atomic Research Centre, Bombay. The mill has worked upto expectation except in few areas where modifications had to be done for smooth production. Apart from this improvements in operating practices have been done based on experience gained in operating the mill, incorporating the recent technological advances. In the recent past, the mill was expanded to increase the installed capacity by 40% and was commissioned in October 1987. The expanded mill has given the desired capacity and is working smoothly. The present paper deals with the experience gained in running the plant for the last 20 years and changes incorporated (author). 4 figs

An accelerator-based epithermal photoneutron source for boron neutron capture therapy

International Nuclear Information System (INIS)

Mitchell, H.E.

1996-04-01

Boron neutron capture therapy is an experimental binary cancer radiotherapy modality in which a boronated pharmaceutical that preferentially accumulates in malignant tissue is first administered, followed by exposing the tissue in the treatment volume to a thermal neutron field. Current usable beams are reactor-based but a viable alternative is the production of an epithermal neutron beam from an accelerator. Current literature cites various proposed accelerator-based designs, most of which are based on proton beams with beryllium or lithium targets. This dissertation examines the efficacy of a novel approach to BNCT treatments that incorporates an electron linear accelerator in the production of a photoneutron source. This source may help to resolve some of the present concerns associated with accelerator sources, including that of target cooling. The photoneutron production process is discussed as a possible alternate source of neutrons for eventual BNCT treatments for cancer. A conceptual design to produce epithermal photoneutrons by high photons (due to bremsstrahlung) impinging on deuterium targets is presented along with computational and experimental neutron production data. A clinically acceptable filtered epithermal neutron flux on the order of 10 7 neutrons per second per milliampere of electron current is shown to be obtainable. Additionally, the neutron beam is modified and characterized for BNCT applications by employing two unique moderating materials (an Al/AlF 3 composite and a stacked Al/Teflon design) at various incident electron energies

An accelerator-based epithermal photoneutron source for boron neutron capture therapy

Energy Technology Data Exchange (ETDEWEB)

Mitchell, Hannah E. [Georgia Inst. of Technology, Atlanta, GA (United States)

1996-04-01

Boron neutron capture therapy is an experimental binary cancer radiotherapy modality in which a boronated pharmaceutical that preferentially accumulates in malignant tissue is first administered, followed by exposing the tissue in the treatment volume to a thermal neutron field. Current usable beams are reactor-based but a viable alternative is the production of an epithermal neutron beam from an accelerator. Current literature cites various proposed accelerator-based designs, most of which are based on proton beams with beryllium or lithium targets. This dissertation examines the efficacy of a novel approach to BNCT treatments that incorporates an electron linear accelerator in the production of a photoneutron source. This source may help to resolve some of the present concerns associated with accelerator sources, including that of target cooling. The photoneutron production process is discussed as a possible alternate source of neutrons for eventual BNCT treatments for cancer. A conceptual design to produce epithermal photoneutrons by high photons (due to bremsstrahlung) impinging on deuterium targets is presented along with computational and experimental neutron production data. A clinically acceptable filtered epithermal neutron flux on the order of 10⁷ neutrons per second per milliampere of electron current is shown to be obtainable. Additionally, the neutron beam is modified and characterized for BNCT applications by employing two unique moderating materials (an Al/AlF₃ composite and a stacked Al/Teflon design) at various incident electron energies.

Uranium mineralization of migmatite in southern China

Energy Technology Data Exchange (ETDEWEB)

Feng, Mingyue

1987-09-01

The uranium mineralization occurs in migmatite in the form of disseminated uraninite is a new type found in southern China. According to the forms of uraninite existence in orebodies, it can be divided into primary and reworked subtypes. The principal uranium mineral in the deposits of primary subtype is uraninite, but those in reworked subtype are pitchblende and relict uraninite. The formation of uranium mineralization is considered as a result of remobilization, migration and local concentration caused by preferential melting of the uranium-rich strata.

Uranium mineralization of migmatite in southern China

International Nuclear Information System (INIS)

Feng Mingyue.

1987-01-01

The uranium mineralization occurs in migmatite in the form of disseminated uraninite is a new type found in southern China. According to the forms of uraninite existence in orebodies, it can be divided into primary and reworked subtypes. The principal uranium mineral in the deposits of primary subtype is uraninite, but those in reworked subtype are pitchblende and relict uraninite. The formation of uranium mineralization is considered as a result of remobilization, migration and local concentration caused by preferential melting of the uranium-rich strata

Paleozoic stratigraphy of two areas in southwestern Indiana

International Nuclear Information System (INIS)

Droste, J.B.

1976-09-01

Two areas recommended for evaluation as solid waste disposal sites lie along the strike of Paleozoic rocks in southwestern Indiana. Thin Pennsylvanian rocks and rocks of the upper Mississippian are at the bedrock surface in maturely dissected uplands in both areas. The gross subsurface stratigraphy beneath both areas is the same, but facies and thickness variation in some of the subsurface Paleozoic units provide for some minor differences between the areas. Thick middle Mississippi carbonates grade downward into clastics of lower Mississippian (Borden Group) and upper Devonian (New Albany Shale) rocks. Middle Devonian and Silurian rocks are dominated by carbonate lithologies. Upper Ordovician (Maquoketa Group) overly carbonates of middle Ordovician age. Thick siltstone and shale of the Borden Group-New Albany Shale zone and Maquoketa Group rocks should be suitable for repository development

Preliminary evaluation of the uranium favorability in the area northeast of Gunnison, Colorado

International Nuclear Information System (INIS)

Gallagher, G.L.; Edmond, C.L.; D'Andrea, R.F. Jr.

1977-08-01

Rock and steam-sediment samples were collected to define areas favorable for uranium deposits northeast of Gunnison, Colorado. Areas considered most favorable for further exploration are: (1) the Bronco Mountain area, approximately 10 mi south of Taylor Park Reservoir, (2) the area near the Big Red mine, and (3) the area 5 mi north-northeast of Taylor Park Reservoir. On the basis of known deposits in the Marshall Pass and Cochetopa districts, fault contacts between Precambrian granites and Paleozoic or Mesozoic sedimentary rocks are favorable structural sites

The depositional and hydrogeologic environment of tertiary uranium deposits, South Texas uranium province

International Nuclear Information System (INIS)

Galloway, W.E.

1985-01-01

Uranium ore bodies of the South Texas Uranium Province occur within the most transmissive sand facies of coastal-plain fluvial and shore-zone depositional systems. Host strata range in age from Eocene through Miocene. Ore bodies formed at the fringes of epigenetic oxidation tongues near intrinsic organic debris or iron-disulfide mineral reductants. Mineralized Eocene units, which include the Carrizo and Whitsett Sandstones, subcropped beneath tuffaceous Oligocene through early Miocene coastal plain sediments. Roll-front mineralization occurred because of this direct hydrologic continuity between an aquifer and a uranium source. Most ore occurs within coarse, sand-rich, arid-region, bed-load fluvial systems of the Oligocene through Miocene Catahoula, Oakville, and Goliad Formations. Host sediments were syndepositionally oxidized and leached. Reductant consists predominantly of epigenetic pyrite precipitated from deep, sulfide-rich thermobaric waters introduced into the shallow aquifers along fault zones. Mineralization fronts are commonly entombed within reduced ground. Modern ground waters are locally oxidizing and redistributing some ore but appear incapable of forming new mineralization fronts. (author)

Comparison of different methods for activation analysis of geological and pedological samples: Reactor and epithermal neutron activation, relative and monostandard method

International Nuclear Information System (INIS)

Alian, A.; Sansoni, B.

1980-04-01

Using purely instrumental methods, a comparative study is presented on neutron activation analysis of rock and soil samples by whole reactor neutron spectrum and epithermal neutrons with both relative and monostandard procedures. The latter procedure used with epithermal neutron activation analysis of soil samples necessitated the use of the 'effective resonance integrals' which were determined experimentally. The incorporation of the #betta# factor, representing deviation of reactor epithermal neutron flux from 1/E law, is developed in the present work. The main criteria for the choice of one or more of the procedures studied for a given purpose are also indicated. Analysis of 15 trace elements, Ca and Fe in the standard Japanese granite JG-1 using monostandard epithermal neutron activation gave results in good agreement with the average literature values. (orig./RB) [de

Regional metallogenic essential factor of granite-type uranium deposits in Guangdong province

International Nuclear Information System (INIS)

Pan Yongzheng

1987-12-01

The uranium origin, activation region, red basin, and fault depressed zone constitute the regional metallogenic essential factor of the four united like one granite-type uranium deposits in the post-Caledonian rise area in China. In the development of sub-geosyncline in the Caledonian, the clastic formation with widely deposited carbon, silicon, mud rich bearing organic matter, which drow a great amount of uranium formed the uranium-bearing system in the Sinian-Cambrian period. The magmagranite activation in a large scale in the Indosinian-Yenshanian period caused the continental crust to be suffered strong reformation and the uranium-bearing basement system to be eroded and remelted, and formed the rich uranium granite body. The multiple structure-magmatic movement further made the uranium in the rock body suffered the endogenic, structure, supergene active reformation, and produced mobile uranium concentrated area. Under the dry and hot paleoclimate condition in the Cretaceous-Tertiary period, strong weathering and hot water leaching forced uranium to be concentrated into the 'rock origin activation' type uranium deposits in the fault depressed zone

Determination of epithermal flux correction factor (α) for irradiation ...

African Journals Online (AJOL)

Due to resonance that occur in the epithermal energy region of a reactor, the flux spectra in that region deviates strongly from the ideal I/E law to a I/E1+α with alpha as the correction factor. The factor has to be determined if zirconium as monitor pairs to determine the correction factor for inner irradiation channel 5 and outer ...

Unconventional uranium resources in China

International Nuclear Information System (INIS)

Qi Fucheng; Zhang Zilong; Li Zhixing; Wang Zhiming; He Zhongbo; Wang Wenquan

2011-01-01

Unconventional uranium resources in China mainly include black-rock series, peat, salt lake and evaporitic rocks. Among them, uraniferous black-rock series, uraniferous phosphorite and uranium-polymetallic phosphorite connected with black-rock series are important types for the sustainable support of uranium resources in China. Down-faulting and epocontinental rift in continental margin are the most important and beneficial ore-forming environment for unconventional uranium resources of black-rock series in China and produced a series of geochemistry combinations, such as, U-Cd, U-V-Mo, U-V-Re, U-V-Ni-Mo and U-V-Ni-Mo-Re-Tl. Unconventional uranium resources of black-rock series in China is related to uranium-rich marine black-rock series which are made up of hydrothermal sedimentary siliceous rocks, siliceous phospheorite and carbonaceous-siliceous-pelitic rock and settled in the continental margin down-faulting and epicontinental rift accompanied by submarine backwash and marine volcano eruption. Hydrothermal sedimentation or exhalation sedimentary is the mechanism to form unconventional uranium resources in black-rock series or large scale uranium-polymetallic mineralization in China. (authors)

Paleozoic in situ spores and pollen. Lycopsida

Czech Academy of Sciences Publication Activity Database

Bek, Jiří

2017-01-01

Roč. 296, 1/6 (2017), s. 1-111 ISSN 0375-0299 R&D Projects: GA ČR GAP210/12/2053 Institutional support: RVO:67985831 Keywords : in situ spores * reproductive organs * Lycopsida * Paleozoic Sub ject RIV: DB - Geology ; Mineralogy OBOR OECD: Paleontology Impact factor: 1.333, year: 2016

International Uranium Resources Evaluation Project (IUREP) national favourability studies: Turkey

International Nuclear Information System (INIS)

1977-08-01

Turkey has an area of 296 185 sq mi or 767 120 square kilometers. The geology is dominated lay Tertiary and post-Tertiary rocks which are very widespread but extensive outcrops of Mesozoic rocks also occur. Paleozoic rocks, mainly gneisses, mica schists and quartzites occur in the ancient massifs, principally the Istranca massif in Thrace, the Merideres massif in western Anatolia and the Karrshir massif in central Anatolia. Prospecting for uranium began in Turkey in 1953 and the Atomic Energy Raw Materials Division of the Maden Tetkikive Arama Enstitusu (M.T.A.) was founded in 1956. By 1962 a total of 78% of the whole country had been covered by serial radiometric reconnaissance prospecting. Uranium was discovered at Kasar in western Anatolia in 1961 and several hundred tons of reserves estimated two years later. Uranium prospecting was largely recessed from 1963 to 1967. IAEA/UNDP assistance was provided in 1962-63 and 1965 and between 1974 and 1977 in a detailed exploration programme in the Kasar area. In the whole country nearly 600 anomalies and occurrences had been identified by 1963. Several occurrences principally in Western Anatolia had been assigned a small reserve. A recent official estimate places the total national reserve at 3150 tonnes uranium in the less than 30% category of reasonably assured resources. A speculative Potential of between 30,000 and 50,000 tonnes uranium is considered to be reasonable. (author)

Geology of epithermal silver-gold bulk-mining targets, bodie district, Mono County, California

Science.gov (United States)

Hollister, V.F.; Silberman, M.L.

1995-01-01

The Bodie mining district in Mono County, California, is zoned with a core polymetallic-quartz vein system and silver- and gold-bearing quartz-adularia veins north and south of the core. The veins formed as a result of repeated normal faulting during doming shortly after extrusion of felsic flows and tuffs, and the magmatic-hydrothermal event seems to span at least 2 Ma. Epithermal mineralization accompanied repeated movement of the normal faults, resulting in vein development in the planes of the faults. The veins occur in a very large area of argillic alteration. Individual mineralized structures commonly formed new fracture planes during separate fault movements, with resulting broad zones of veinlets growing in the walls of the major vein-faults. The veinlet swarms have been found to constitute a target estimated at 75,000,000 tons, averaging 0.037 ounce gold per ton. The target is amenable to bulkmining exploitation. The epithermal mineralogy is simple, with electrum being the most important precious metal mineral. The host veins are typical low-sulfide banded epithermal quartz and adularia structures that filled voids created by the faulting. Historical data show that beneficiation of the simple vein mineralogy is very efficient. ?? 1995 Oxford University Press.

U-Pb Detrital Zircon Geochronologic Constraints on Depositional Age and Sediment Source Terrains of the Late Paleozoic Tepuel-Genoa Basin

Science.gov (United States)

Griffis, N. P.; Montanez, I. P.; Isbell, J.; Gulbranson, E. L.; Wimpenny, J.; Yin, Q. Z.; Cúneo, N. R.; Pagani, M. A.; Taboada, A. C.

2014-12-01

The late Paleozoic Ice Age (LPIA) is the longest-lived icehouse of the Phanerozoic and the only time a metazoan dominated and vegetated world transitioned from an icehouse climate into a greenhouse. Despite several decades of research, the timing, extent of glaciation and the location of ice centers remain unresolved, which prohibits reconstruction of ice volume. The Permo-Carboniferous sediments in the Tepuel-Genoa Basin, Patagonia contains a near complete record of sedimentation from the lower Carboniferous through lower Permian. Outsized clasts, thin pebble-rich diamictites and slumps represent the last of the late Paleozoic glacially influenced deep-water marine sediments in the Mojón de Hierro Fm. and the Paleozoic of Patagonia. U-Pb analysis of detrital zircons separated from slope sediments reveal groupings (20 myr bins, n≥5 zircons) with peak depositional ages of 420, 540 to 660 and 1040 Ma. Zircon age populations recovered from the Mojón de Hierro Fm. compare well with bedrock ages of the Deseado Massif of SE Patagonia, suggesting this may be a potential source of sediments. The maximum depositional age of the sediments is 306.05 ± 3.7 Ma (2σ) as determined by the median age of the two youngest concordant zircons that overlap in error. The youngest zircon from the analysis yields a 238U/206Pb age of 301.3 ± 4.5 Ma (2σ; MSWD = 2.3). Younger zircons from the analysis compare well with the age of granite bedrock exposed along the basin margin to the E-NE suggesting they may reflect a more proximal source. These data, which indicate a maximum age of late Carboniferous for the Mojón de Hierro Fm, provide the first geochemical constraints for the timing of final deposition of glaciomarine sediments in the Tepuel-Genoa Basin, and contributes to the biostratigraphic correlation of the late Paleozoic succession in Patagonia with other key LPIA basins that has thus far been hindered by faunal provincialism.

Uranium hydrogeochemical and stream sediment reconnaissance of the Durango NTMS quadrangle, Colorado

International Nuclear Information System (INIS)

Dawson, H.E.; Weaver, T.A.

1979-01-01

During the spring and summer of 1976, 1518 water and 1604 waterborne sediment samples were collected from 1804 locations in the Durango NTMS quadrangle, Colorado. The samples obtained from this 19 940-km 2 area were analyzed at the Los Alamos Scientific Laboratory for total uranium. The uranium concentrations in waters ranged from less than the detectable limit of 0.2 ppB to 25.7 ppB, with a mean value of 0.84 ppB. The concentrations in sediments ranged from 1.0 ppM to 71.6 ppM, with a mean value of 4.2 ppM. Study of total water and total sediment populations indicated that both are actually mixtures of several populations. Consequently, samples were chosen for discussion on the basis of their having conspicuously high uranium concentrations relative to surrounding background values. Thirty-four water samples (approximately 2.2% of the total water population) had uranium concentrations above 5.00 ppB, the highest of which were well water samples from the San Luis Valley. Thirty-seven sediment samples (approximately 2.3% of the total sediment population) had uranium concentrations above 12.0 ppM. The majority of these were taken from sites in Precambrian rocks, but several came from Paleozoic and Mesozoic strate and Tertiary volcanics. The uranium concentrations in sediment samples from areas of Precambrian rock were especially high and these areas may warrant further, more detailed investigations

From hot atom chemistry to epithermal chemistry

International Nuclear Information System (INIS)

Roessler, K.

2004-01-01

The rise and fall of hot atom chemistry (HAC) over the years from 1934 to 2004 is reviewed. Several applications are discussed, in particular to astrophysics and the interaction of energetic ions and atoms in space. Epithermal chemistry (ETC) is proposed to substitute the old name, since it better fits the energy range as well as the non-thermal and non-equilibrium character of the reactions. ETC also avoids the strong connexion of HAC to nuclear chemistry and stands for the opening of the field to physical chemistry and astrophysics. (orig.)

Evidence for de-sulfidation to form native electrum in the Fire Creek epithermal gold-silver deposit, north-central Nevada

Science.gov (United States)

Perez, J.; Day, J. M.; Cook, G. W.

2012-12-01

The Fire Creek property is a newly developed and previously unstudied epithermal Au-Ag deposit located in the Northern Shoshone range of north central Nevada. The mineralization occurs within and above en echelon N-NW trending basaltic dykes that are hosted within a co-genetic and bimodal suite of mid-Miocene basalts and andesites formed in association with the Yellowstone hotspot-track. Previous studies of Au-Ag mineralization in the Great Basin have focused primarily on extensively mined and/or low-grade deposits. Therefore, the ability for unrestricted sampling of a major Au-Ag deposit early in its exploration and development represents an opportunity for refined understanding of epithermal ore genesis processes. New petrology reveals at least two distinct pulses of mineralization that in relative order of timing are: 1) S-rich veins which are associated with initial host-rock alteration; 2) quartz- and/or calcite-rich veins which vary from fine-grained to lath-like quartz crystals with large calcite crystals in vein centers. Native electrum occurs only within the second phase of mineralization and typically occurs within quartz and adjacent to cross-cut first-phase S-rich veins. In places the electrum appears to replace or form overgrowths around existing sulfide phases. High levels of gold and silver are found in both the first (0.8 g Au/tonne) and second-phase pulses (37 g Au/tonne). Fire Creek shares many similarities with its northern neighbor, the Mule Canyon Au-Ag deposit, with high Fe sulfide contents for some of the ores, altered wall-rocks and the presence of narrow and discontinuous gold-bearing siliceous veins. Like Fire Creek, Mule Canyon possesses two distinct mineralizing phases, a sulfide rich and a late stage calcite/silica assemblage. The first pulse appears to be identical in both locations with a variation of disseminated to euhedral iron-sulfides and associated intense alteration of host rock. However, Fire Creek differs from Mule Canyon in

A genetic model of progressively partial melting for uranium-bearing granites in south China

International Nuclear Information System (INIS)

Zhai Jianping.

1989-01-01

A genetic model of progressively partial and enrichment mechanism of uranium during partial melting of the sources of material studied and the significance of the genetic model in search of uranium deposits is elaborated. This model accounts better for some geological and geochemical features of uranium-bearing granties and suspects the traditional idea that igneous uranium-bearing granites were formed by fusion of U-rich strata surrounding these granites. Finally this paper points out that the infuence of U-rich strata of wall rocks of granites over uranium-bearing granites depends on variation of water solubility in the magma and assimilation of magma to wall rocks during its ascending and crystallization

Installation and testing of an optimized epithermal neutron beam at the Brookhaven Medical Research Reactor (BMRR)

Energy Technology Data Exchange (ETDEWEB)

Fairchild, R.G.; Kalef-Ezra, J.; Saraf, S.K.; Fiarman, S.; Ramsey, E.; Wielopolski, L.; Laster, B.; Wheeler, F. (Brookhaven National Lab., Upton, NY (USA); Ioannina Univ. (Greece); Brookhaven National Lab., Upton, NY (USA); State Univ. of New York, Stony Brook, NY (USA). Health Science Center; Brookhaven National Lab., Upton, NY (USA); EG and G Idaho, Inc., Idaho Falls, ID (USA))

1989-01-01

Various calculations indicate that an optimized epithermal neutron beam can be produced by moderating fission neutrons either with a combination of Al and D{sub 2}O, or with Al{sub 2}O{sub 3}. We have designed, installed and tested an Al{sub 2}O{sub 3} moderated epithermal neutron beam at the Brookhaven Medical Research Reactor (BMRR). The epithermal neutron fluence rate of 1.8 {times} 10{sup 9} n/cm{sup 2}-sec produces a peak thermal neutron fluence rate of 1.9 to 2.8 {times} 10{sup 9} n/cm{sup 2}-sec in a tissue equivalent (TE) phantom head, depending on the configuration. Thus a single therapy treatment of 5 {times} 10{sup 12} n/cm{sup 2} can be delivered in 30--45 minutes. All irradiation times are given for a BMRR power of 3 MW, which is the highest power which can be delivered continuously. 18 refs., 8 figs., 4 tabs.

Vein-type uranium deposits

International Nuclear Information System (INIS)

Rich, R.A.; Holland, H.D.; Petersen, U.

1975-01-01

A critical review is presented of published data bearing on the mineralogy, paragenesis, geochemistry, and origin of veiw-type uranium deposits. Its aim is to serve as a starting point for new research and as a basis for the development of new exploration strategies. During the formation of both vein and sandstone types of deposits uranium seems to have been dissolved by and transported in rather oxidized solutions, and deposited where these solutions encountered reducing agents such as carbon, sulfides, ferrous minerals and hydrocarbons. Granitic rocks abnormally enriched in uranium have apparently been the most common source for uranium in vein-type deposits. Oxidizing solutions have been derived either from the surface or from depth. Surface solutions saturated with atmospheric oxygen have frequently passed through red bed or clean sandstone conduits on their way to and from uranium source rocks. Deep solutions of non-surface origin have apparently become sufficiently oxidizing by passage through and equilibration with red beds. The common association of clean sandstones or red beds with uranium-rich granites in the vicinity of vein-type uranium deposits is probably not fortuitous, and areas where these rock types are found together are considered particularly favorable targets for uranium exploration

Wall-rock alteration and uranium mineralization in parts of Thomas Range Mining District, San Juan County, Utah, and its significance in mineral exploration

International Nuclear Information System (INIS)

Mohammad, H.

1985-01-01

Several important uranium deposits associated with fluorspar and beryllium are located in parts of Thomas Range area. the mineralization is found in dolomites and dolomitic limestones of Paleozoic age and sandstones, tuffs, and rhyolites belonging to the Tertiary Spor Mountain and Topaz Mountain Formations. The pipes, veins, and nodules of fluorspar are replaced by uranium. Veins and disseminations of radioactive fluorspar and opal and overgrowths of secondary minerals are found in rhyolites, tuffs, carbonate rocks, and breccias. The radioactivity in sandstones and conglomerates emanates from weeksite, beta-uranophane, zircon, gummite, and zircon. It also occurs as highly oxidized rare aphanitic grains disseminated in a few ore deposits. The results of the present investigations may influence the initiation of future exploration programs in the Thomas Range mining district. Hydrothermal fluids of deep-seated magmatic origin rich in U, V, Th, Be, and F reacted with the country rocks. The nature and sequence of wall-rock alteration and its paragenetic relationship with the ores have been determined. The mineralization is confined to the altered zones. The ore bodies in the sedimentary rocks and the breccias are located in the fault zones. More than 1000 faults are present in the area, greatly complicating mineral prospecting. The wall-rock alteration is very conspicuous and can be used as a valuable tool in mineral exploration

Features of the distribution of uranium in igneous rocks - uranium deposits associated with igneous rocks

International Nuclear Information System (INIS)

Soerensen, H.

1977-01-01

The generally accepted main features of the distribution of uranium and thorium in igneous rocks are briefly reviewed. It is pointed out that uranium in most cases examined is strongly partitioned into the melt during consolidation of magmas and that uranium is concentrated in the most volatile-rich parts of magmas. The mode of emplacement and the consolidation of magmas control the retention or the expulsion of the volatile phase from consolidating magmas and also the distribution of uranium between magmas and the volatile phase. After a brief review of the types of uranium deposits associated with igneous rocks it is concluded that it is difficult to establish universally valid exploration criteria to be used in the search of these types of deposit. It is emphasized, however, that detailed petrological and geochemical studies may be useful in outlining exploration targets. (author)

Measurement of thermal, epithermal and fast neutrons fluxes by the activation foil method at IEA-R1 reactor

International Nuclear Information System (INIS)

Dias, M.S.; Koskinas, M.F.; Berretta, J.R.; Fratin, L.; Botelho, S.

1990-01-01

The thermal, epithermal and fast neutron fluxes have been determined experimentally by the activation foil method at position GI, located near the IEA-R1 reactor core. The reactions used were 197 Au (n,gamma) 198 Au, for thermal and epithermal neutrons and 27 Na (n,alpha) 24 Na, for fast neutrons. The activities were measured by the 4π(PC)β-γ coincidence method. (author)

An in-situ check of the epithermal neutron log calibration

International Nuclear Information System (INIS)

Burkhard, N.R.

1993-01-01

The epithermal neutron log is used to measure the water content of the formation. The large hole epithermal neutron sonde (ENS) utilized at the Nevada Test Site (NTS) has been calibrated in the Hydrogen Content Test Facility (HCTF). These calibrations are used to correct the measured neutron count rate for the effects of tool stand-off and density. For some time, the suspicion has existed that the water contents that are calculated from the ENS data are too large. Hole U2gj represented a unique opportunity to check the validity of the ENS calibration under realistic logging conditions; a portion of the hole had been cemented and redrilled and then logged. The cements have a known water content and can be used as an in-situ calibration check. The author found that the water contents from the log data after processing with the existing calibrations are consistent with these known cement water contents. In addition, the study indicates that the raw neutron data might be more appropriately smoothed by using a median smoother rather than the currently utilized mean smoother

An in-situ check of the epithermal neutron log calibration

International Nuclear Information System (INIS)

Burkhard, N.R.

1993-09-01

The epithermal neutron log is used to measure the water content of the formation. The large hole epithermal neutron sonde (ENS) that we utilize at the Nevada Test Site (NTS) has been calibrated in the Hydrogen Content Test Facility (HCTF). These calibrations are used to correct the measured neutron count rate for the effects of tool stand-off and density. For sometime, the suspicion has existed that the water contents that are calculated from the ENS data are too large. Hole U2gj represented a unique opportunity to check the validity of the ENS calibration under realistic logging conditions; a portion of the hole had been cemented and re drilled and then logged. The cements have a known water content and can be used as an in situ calibration check. I found that the water contents from the log data after processing with the existing calibrations are consistent with these known cement water contents. In addition, the study indicates that the raw neutron data might be more appropriately smoothed by using a median smoother rather than the currently utilized mean smoother

Gold grade of epithermal gold ore at Lamuntet, Brang Rea, West Sumbawa District, West Nusa Tenggara Province, Indonesia

Science.gov (United States)

Ernawati, Rika; Idrus, Arifudin; TBMP, Himawan

2017-06-01

Lamuntet is one of gold ore mining area carried out by the Artisanal Small scale Gold Mining (ASGM) located in West Sumbawa, Indonesia. Most of the miners at this area are not the local miners but also those from other regions. Mineralization of this area is strong identified as low sulfidation epithermal system. There are two blocks of this mining location, namely, Ngelampar block with an area of 0.164 km2 and Song block with an area of 0.067 km2. This study was focused on Ngelampar block. The characteristic of epithermal system is the existence of quartz vein with comb, vuggy, and sugary texture. The aim of this research was to analyze the gold grade and other metals, such as Cu, Ag, Pb, As, Zn, and Hg. The research methods included literature study from previous researches, field work, laboratory work, and interpretation. The literature study was performed on previous researches with similar study area. The field work comprised of direct observation and sampling. Fieldwork was done for a week to obtain gold ore/vein. Sixteen samples were analyzed to obtain the grade of ore/metal. The Hg laboratory analysis was then performed on the six samples with the highest gold grade. Laboratory works were conducted at Intertek Jakarta by using Fire Assay (FA) for gold grade and Atomic Absorption Spectrophotometry (AAS) for Cu, Ag, Pb, As, Zn, and Hg. Results of the analysis showed the range of Au was grade (0.1 ppm - 27.8 ppm), Cu was 26 ppm -1740 ppm, Pb was 101 ppm- >4000 ppm, Zn of 73 ppm- >10,000 ppm, Ag of 3 ppm -185 ppm, As was 150 ppm-6530 ppm, and Hg of 0.08 ppm - 1.89 ppm. L1 and L15 had high grade for all values (Au, Ag, Zn, Cu, As, and Hg). Gold mineralization was formed as electrum because of Ag content is higher than 20%. Associated minerals of the samples in the study area were galena, sphalerite, arsenopyrite, and chalcopyrite which showed the characteristic of rich base metal of Pb, Zn, and Cu at LS epithermal.

Potentialities and practical limitations of absolute neutron dosimetry using thin films of uranium and thorium applied to the fission track dating

CERN Document Server

Bigazzi, G; Hadler-Neto, J C; Iunes, P J; Paulo, S R; Oddone, M; Osorio, A M A; Zúñiga, A G

1999-01-01

Neutron dosimetry using natural uranium and thorium thin films makes possible that mineral dating by the fission-track method can be accomplished, even when poor thermalized neutron facilities are employed. In this case, the contributions of the fissions of sup 2 sup 3 sup 5 U, sup 2 sup 3 sup 8 U and sup 2 sup 3 sup 2 Th induced by thermal, epithermal and fast neutrons to the population of tracks produced during irradiation are quantified through the combined use of natural uranium and thorium films. If the Th/U ratio of the sample is known, only one irradiation (where the sample and the films of uranium and thorium are present) is necessary to perform the dating. However, if that ratio is unknown, it can be determined through another irradiation where the mineral to be dated and both films are placed inside a cadmium box. Problems related with film manufacturing and calibration are discussed. Special attention is given to the utilization of thin films having very low uranium content. The problems faced sugg...

Genetic-Structural relations in some types of spanish uranium deposits; Relaciones genetico-estructurales de algunos tipos de mienralizaciones uraniferas espanolas

Energy Technology Data Exchange (ETDEWEB)

Alia Medina, M

1962-07-01

On the spanish hercynian areas there are different types of uraniferous deposits, which may be classified in the following groups: Group I, high temperature magmatic deposits, Group II, low temperature veins and Group III supergenic deposits, generated by weathering of the former ones or by lixiviation of the intra granitic uranium. The deposits belonging to Group I are founding the hercynian ge anticlinal; those of Groups II and III, chiefly in the eugeosyncline. The explanation suggested for these genetic-structural relationships assumes that, in the ge anticlinal, uranium would migrate from the dioritic magmas to form and high temperature deposits. In the eugeosyncline, a large fraction of the uranium would migrate towards more differentiated granites, in which it might partially remain or from which it might have been finally concentrated in the epithermal veins or by later tectonic actions. The Group III deposits ar more frequent in the eugeosyncline, due to the greater abundance of more differentiated intrusive rocks. (Author) 16 refs.

Origin and tectonic evolution of early Paleozoic arc terranes abutting the northern margin of North China Craton

Science.gov (United States)

Zhou, Hao; Pei, Fu-Ping; Zhang, Ying; Zhou, Zhong-Biao; Xu, Wen-Liang; Wang, Zhi-Wei; Cao, Hua-Hua; Yang, Chuan

2017-12-01

The origin and tectonic evolution of the early Paleozoic arc terranes abutting the northern margin of the North China Craton (NCC) are widely debated. This paper presents detrital zircon U-Pb and Hf isotopic data of early Paleozoic strata in the Zhangjiatun arc terrane of central Jilin Province, northeast (NE) China, and compares them with the Bainaimiao and Jiangyu arc terranes abutting the northern margin of the NCC. Detrital zircons from early Paleozoic strata in three arc terranes exhibit comparable age groupings of 539-430, 1250-577, and 2800-1600 Ma. The Paleoproterozoic to Neoarchean ages and Hf isotopic composition of the detrital zircons imply the existence of the Precambrian fragments beneath the arc terranes. Given the evidences from geology, igneous rocks, and detrital zircons, we proposed that the early Paleozoic arc terranes abutting the northern margin of the NCC are a united arc terrane including the exotic Precambrian fragments, and these fragments shared a common evolutionary history from Neoproterozoic to early-middle Paleozoic.

Behaviour of uranium during late-Hercynian and alpine metamorphisms in the Aiguilles rouges and Belledonne (Valorcine, Lauziere) massifs. Western Alps

International Nuclear Information System (INIS)

Negga, H.S.

1984-01-01

The purpose of this research thesis is to define the origin of numerous uranium anomalies in the external crystalline Alpine massifs, more precisely the massif of the Aiguilles Rouges and the massif of Belledonne. The primary cause of uranium mineralization in the first massif appears to have been the retrograde metamorphism events of the late-Hercynian age. In the second massif, the same conditions of uranium mineralization appear to have been realised, but with a much higher calcium activity in the fluids. After having explained the choice of the selected areas, the sampling and the chemical analysis performed, the author describes the geological and structural framework of Western Alps: geological history of the paleozoic platform, regional geology of the studied massifs. The next part reports the petrographic and geochemical study, the analysis of the mineral chemistry, of the alteration and the metamorphism. Then the author describes the geochemistry of uranium and thorium within the studied structures

Optimization study for an epithermal neutron beam for boron neutron capture therapy at the University of Virginia Research Reactor

International Nuclear Information System (INIS)

Burns, T.D. Jr.

1995-05-01

The non-surgical brain cancer treatment modality, Boron Neutron Capture Therapy (BNCT), requires the use of an epithermal neutron beam. This purpose of this thesis was to design an epithermal neutron beam at the University of Virginia Research Reactor (UVAR) suitable for BNCT applications. A suitable epithermal neutron beam for BNCT must have minimal fast neutron and gamma radiation contamination, and yet retain an appreciable intensity. The low power of the UVAR core makes reaching a balance between beam quality and intensity a very challenging design endeavor. The MCNP monte carlo neutron transport code was used to develop an equivalent core radiation source, and to perform the subsequent neutron transport calculations necessary for beam model analysis and development. The code accuracy was validated by benchmarking output against experimental criticality measurements. An epithermal beam was designed for the UVAR, with performance characteristics comparable to beams at facilities with cores of higher power. The epithermal neutron intensity of this beam is 2.2 x 10 8 n/cm 2 · s. The fast neutron and gamma radiation KERMA factors are 10 x 10 -11 cGy·cm 2 /n epi and 20 x 10 -11 cGy·cm 2 /n epi , respectively, and the current-to-flux ratio is 0.85. This thesis has shown that the UVAR has the capability to provide BNCT treatments, however the performance characteristics of the final beam of this study were limited by the low core power

Observation of distorted Maxwell-Boltzmann distribution of epithermal ions in LHD

Science.gov (United States)

Ida, K.; Kobayashi, T.; Yoshinuma, M.; Akiyama, T.; Tokuzawa, T.; Tsuchiya, H.; Itoh, K.; LHD Experiment Group

2017-12-01

A distorted Maxwell-Boltzmann distribution of epithermal ions is observed associated with the collapse of energetic ions triggered by the tongue shaped deformation. The tongue shaped deformation is characterized by the plasma displacement localized in the toroidal, poloidal, and radial directions at the non-rational magnetic flux surface in toroidal plasma. Moment analysis of the ion velocity distribution measured with charge exchange spectroscopy is studied in order to investigate the impact of tongue event on ion distribution. A clear non-zero skewness (3rd moment) and kurtosis (4th moment -3) of ion velocity distribution in the epithermal region (within three times of thermal velocity) is observed after the tongue event. This observation indicates the clear evidence of the distortion of ion velocity distribution from Maxwell-Boltzmann distribution. This distortion from Maxwell-Boltzmann distribution is observed in one-third of plasma minor radius region near the plasma edge and disappears in the ion-ion collision time scale.

Collimator optimization studies for the new MIT epithermal neutron beam

International Nuclear Information System (INIS)

Riley, K.J.; Ali, S.J.; Harling, O.K.

2000-01-01

A patient collimator has been designed for the epithermal neutron facility now being commissioned at MIT. Collimator performance both in and out of field was evaluated using the Monte Carlo code MCNP. A two piece design that can accommodate different circular field sizes will be manufactured using a composite lead, epoxy, boron and lithium mixture. (author)

On the characteristics of metallotect features and origin of Chanziping uranium deposit

International Nuclear Information System (INIS)

Kang Zili; Liu Haiying

1991-01-01

Chanziping Uranium Deposit is one of the representative uranium deposits which lie in the Lower Cambrian Qingxi Formation in China, Chiefly composed of black shale formation. The mineralization is largely controlled by the U-rich strata and bedding-plane faults. The former is the source of ore and ore-bearing wallrock; the latter controls the distributions of ore bodies, and is the source of force for remobilization, and mineralization of uranium and other metallogenetic elements. The formation of this deposit approximately undergoes the following 4 stages: 1. Preliminary enrichment of sedimentary uranium source layer in the Qingxi Formation; 2. Further uranium enrichment during the deformation and metamorphism of strata; 3. Formation of hydrothermal (thermal water) uranium deposit (main metallogenetic epoch) due to dynamic differentation and thermodynamic metamorphism; 4. Formation of rich multiple ore bodies due to the secondary leaching and enrichment. Then, the deposit, which contains strata-bound features, becomes a polygenetic compound uranium deposit. These characteristics may be used as the rules for searching for uranium deposits of this type

Geochronology and geochemistry of early Paleozoic intrusive rocks from the Khanka Massif in the Russian Far East: Petrogenesis and tectonic implications

Science.gov (United States)

Xu, Ting; Xu, Wen-Liang; Wang, Feng; Ge, Wen-Chun; Sorokin, A. A.

2018-02-01

This paper presents new geochronological and geochemical data for early Paleozoic intrusive rocks from the Khanka Massif in the Russian Far East, with the aim of elucidating the Paleozoic evolution and tectonic attributes of the Khanka Massif. New U-Pb zircon data indicate that early Paleozoic magmatism within the Khanka Massif can be subdivided into at least four stages: 502, 492, 462-445, and 430 Ma. The 502 Ma pyroxene diorites contain 58.28-59.64 wt% SiO2, 2.84-3.69 wt% MgO, and relatively high Cr and Ni contents. Negative εHf(t) values (- 1.8 to - 0.4), along with other geochemical data, indicate that the primary magma was derived from partial melting of mafic lower crust with the addition of mantle material. The 492 Ma syenogranites have high SiO2 and K2O contents, and show positive Eu anomalies, indicating the primary magma was generated by partial melting of lower crust at relatively low pressure. The 445 Ma Na-rich trondhjemites display high Sr/Y ratios and positive εHf(t) values (+ 1.8 to + 3.9), indicating the primary magma was generated by partial melting of thickened hydrous mafic crust. The 430 Ma granitoids have high SiO2 and K2O contents, zircon εHf(t) values of - 5.4 to + 5.8, and two-stage model ages of 1757-1045 Ma, suggesting the primary magma was produced by partial melting of heterogeneous Proterozoic lower crustal material. The geochemistry of these early Paleozoic intrusive assemblages indicates their formation in an active continental margin setting associated with the subduction of a paleo-oceanic plate beneath the Khanka Massif. The εHf(t) values show an increasingly negative trend with increasing latitude, revealing a lateral heterogeneity of the lower crust beneath the Khanka Massif. Regional comparisons of the magmatic events indicate that the Khanka Massif in the Russian Far East has a tectonic affinity to the Songnen-Zhangguangcai Range Massif rather than the adjacent Jiamusi Massif.

Uranium occurrence in major rock types by fission-track mapping

International Nuclear Information System (INIS)

Ledger, E.G.; Bomber, B.J.; Schaftenaar, W.E.; Tieh, T.T.

1984-01-01

Microscopic occurrence of uranium has been determined in about 50 igneous rocks from various location, and in a genetically unrelated sandstone from south Texas. Precambrian granites from the Llano uplift of central Texas contain from a few ppm uranium (considered normal) to over 100 ppm on a whole-rock basis. In granite, uranium is concentrated in: (1) accessory minerals including zircon, biotite, allanite, Fe-Ti oxides, and altered sphene, (2) along grain boundaries and in microfractures by precipitation from deuteric fluids, and (3) as point sources (small inclusions) in quartz and feldspars. Tertiary volcanic rocks from the Davis Mountains of west Texas include diverse rock types from basalt to rhyolite. Average uranium contents increase from 1 ppm in basalts to 7 ppm in rhyolites. Concentration occurs: (1) in iron-titanium-oxides, zircon, and rutile, (2) in the fine-grained groundmass as uniform and point-source concentrations, and (3) as late uranium in cavities associated with banded, silica-rich material. Uranium in ore-grade sandstone is concentrated to more than 3%. Specific occurrences include (1) leucoxene and/or anatase, (2) opaline and calcite cements, (3) mud clasts and altered volcanic rock fragments, and (4) in a few samples, as silt-size uranium- and molybdenum-rich spheres. Uranium content is quite low in pyrite, marcasite, and zeolites

International Uranium Resources Evaluation Project (IUREP) national favourability studies: Nigaragua

International Nuclear Information System (INIS)

1977-08-01

On invitation of the Nicaraguan Government, the U. S. Atomic Energy Commission conducted a reconnaissance for uranium in March, 1953. Operating and abandoned mines, as well as prospects, formations, contacts, dikes and sills enroute to these mines were tested by scintillometer. Reconnaissance included two mineralized areas exposed in windows within the volcanic belt but did not include the schists and granitic intrusions in the north eastern part of the country. No anomalous radioactivity was detected. No uranium occurrences were discovered during the 1953 reconnaissance and no uranium deposits or prospects are indicated on the metallogenetic map of Central America or in the bibliography of Nicaraguan geology. Information is net available on current exploration in Nicaragua. All subsoil mineral resources besides quarry materials belong to the state. In the interest of national defence, uranium, thorium, lithium and their derivatives, along with certain other mineral substances, may be classified as o f temporary strategic interest , and their exploration or exploitation would then be subject to special laws. The Ministry of Economy may establish permanent or temporary national reserves on which mining activities are essentially precluded. Foreign nationals and corporations may acquire mineral concessions although particular regulations may be applicable to such an acquisition. Exploration of any favourable formations has been hindered by volcanic ash cover in western Nicaragua and dense vegetation in the East. Little geologic work has been done on the Paleozoic metamorphic rocks or Todos Santos Formation of the Northern Highlands. These could possibly show some potential for discovery of uranium as might the alaskites near Siuna. The potential resources of Nicaragua are estimated at less than 1,000 tonnes uranium

Volcanogenic Uranium Deposits: Geology, Geochemical Processes, and Criteria for Resource Assessment

Science.gov (United States)

Nash, J. Thomas

2010-01-01

Felsic volcanic rocks have long been considered a primary source of uranium for many kinds of uranium deposits, but volcanogenic uranium deposits themselves have generally not been important resources. Until the past few years, resource summaries for the United States or the world generally include volcanogenic in the broad category of 'other deposits' because they comprised less than 0.5 percent of past production or estimated resources. Exploration in the United States from the 1940s through 1982 discovered hundreds of prospects in volcanic rocks, of which fewer than 20 had some recorded production. Intensive exploration in the late 1970s found some large deposits, but low grades (less than about 0.10 percent U3O8) discouraged economic development. A few deposits in the world, drilled in the 1980s and 1990s, are now known to contain large resources (>20,000 tonnes U3O8). However, research on ore-forming processes and exploration for volcanogenic deposits has lagged behind other kinds of uranium deposits and has not utilized advances in understanding of geology, geochemistry, and paleohydrology of ore deposits in general and epithermal deposits in particular. This review outlines new ways to explore and assess for volcanogenic deposits, using new concepts of convection, fluid mixing, and high heat flow to mobilize uranium from volcanic source rocks and form deposits that are postulated to be large. Much can also be learned from studies of epithermal metal deposits, such as the important roles of extensional tectonics, bimodal volcanism, and fracture-flow systems related to resurgent calderas. Regional resource assessment is helped by genetic concepts, but hampered by limited information on frontier areas and undiscovered districts. Diagnostic data used to define ore deposit genesis, such as stable isotopic data, are rarely available for frontier areas. A volcanic environment classification, with three classes (proximal, distal, and pre-volcanic structures

Thermal, epithermal and thermalized neutron attenuation properties of ilmenite-serpentine heat resistant concrete shield

International Nuclear Information System (INIS)

Kany, A.M.I.; El-Gohary, M.I.; Kamal, S.M.

1994-01-01

Experimental measurements were carried out to study the attenuation properties of low-energy neutrons transmitted through unheated and preheated barriers of heavy-weight, highly hydrated and heat-resistant concrete shields. The concrete shields under investigation have been prepared from naturally occurring ilmenite and serpentine Egyptian ores. A collimated beam obtained from an Am-Be source was used as a source of neutrons, while the measurements of total thermal, epithermal, and thermalized neutron fluxes were performed using a BF-3 detector, multichannel analyzer and Cd filter. Results show that the ilmenite-serpentine concrete proved to be a better thermal, epithermal and thermalized neutron attenuator than the ordinary concrete especially at a high temperature of concrete exposure. (Author)

Aftermath of Uranium Ore Processing on Floodplains: Lasting Effects of Uranium on Soil and Microbes

Science.gov (United States)

Tang, H.; Boye, K.; Bargar, J.; Fendorf, S. E.

2016-12-01

A former uranium ore processing site located between the Wind River and the Little Wind River near the city of Riverton, Wyoming, has generated a uranium plume in the groundwater within the floodplain. Uranium is toxic and poses a threat to human health. Thus, controlling and containing the spread of uranium will benefit the human population. The primary source of uranium was removed from the processing site, but a uranium plume still exists in the groundwater. Uranium in its reduced form is relatively insoluble in water and therefore is retained in organic rich, anoxic layers in the subsurface. However, with the aid of microbes uranium becomes soluble in water which could expose people and the environment to this toxin, if it enters the groundwater and ultimately the river. In order to better understand the mechanisms controlling uranium behavior in the floodplains, we examined sediments from three sediment cores (soil surface to aquifer). We determined the soil elemental concentrations and measured microbial activity through the use of several instruments (e.g. Elemental Analyzer, X-ray Fluorescence, MicroResp System). Through the data collected, we aim to obtain a better understanding of how the interaction of geochemical factors and microbial metabolism affect uranium mobility. This knowledge will inform models used to predict uranium behavior in response to land use or climate change in floodplain environments.

Stream-sediment geochemical prospecting for uranium in the Paleozoic of the Belgian Ardennes

International Nuclear Information System (INIS)

Martin, H.; Lefin, J.P.; Dejonghe, L.; Henry, J.

1983-01-01

Orientation studies showed that a positive geochemical response for uranium in the Belgium Ardennes could be obtained with bank sampling, which consists of collecting colluvium and alluvium on both sides of the rivers. This necessitates a large sampling density of about one sample per km 2 (10 205 samples from an area of 11 000 km 2 ). Anomalies (> 3 ppm) are found that fall into three main areas each in a different geological setting: (1) at the periphery of the Cambro-Silurian Massif of Stavelot; (2) within the transition beds between the Visean and Namurian; and (3) in the lower Devonian of the central Ardennes. (Auth.)

The impact of fire on the Late Paleozoic Earth System

Directory of Open Access Journals (Sweden)

Ian J. Glasspool

2015-09-01

Full Text Available Analyses of bulk petrographic data indicate that during the Late Paleozoic wildfires were more prevalent than at present. We propose that the development of fire systems through this interval was controlled predominantly by the elevated atmospheric oxygen concentration (p(O2 that mass balance models predict prevailed. At higher levels of p(O2, increased fire activity would have rendered vegetation with high moisture contents more susceptible to ignition and would have facilitated continued combustion. We argue that coal petrographic data indicate that p(O2 rather than global temperatures or climate, resulted in the increased levels of wildfire activity observed during the Late Paleozoic and can therefore be used to predict it. These findings are based upon analyses of charcoal volumes in multiple coals distributed across the globe and deposited during this time period, and that were then compared with similarly diverse modern peats and Cenozoic lignites and coals. Herein, we examine the environmental and ecological factors that would have impacted fire activity and we conclude that of these factors p(O2 played the largest role in promoting fires in Late Paleozoic peat-forming environments and, by inference, ecosystems generally, when compared with their prevalence in the modern world.

The impact of fire on the Late Paleozoic Earth system.

Science.gov (United States)

Glasspool, Ian J; Scott, Andrew C; Waltham, David; Pronina, Natalia; Shao, Longyi

2015-01-01

Analyses of bulk petrographic data indicate that during the Late Paleozoic wildfires were more prevalent than at present. We propose that the development of fire systems through this interval was controlled predominantly by the elevated atmospheric oxygen concentration (p(O2)) that mass balance models predict prevailed. At higher levels of p(O2), increased fire activity would have rendered vegetation with high-moisture contents more susceptible to ignition and would have facilitated continued combustion. We argue that coal petrographic data indicate that p(O2) rather than global temperatures or climate, resulted in the increased levels of wildfire activity observed during the Late Paleozoic and can, therefore, be used to predict it. These findings are based upon analyses of charcoal volumes in multiple coals distributed across the globe and deposited during this time period, and that were then compared with similarly diverse modern peats and Cenozoic lignites and coals. Herein, we examine the environmental and ecological factors that would have impacted fire activity and we conclude that of these factors p(O2) played the largest role in promoting fires in Late Paleozoic peat-forming environments and, by inference, ecosystems generally, when compared with their prevalence in the modern world.

Paleozoic subduction complex and Paleozoic-Mesozoic island-arc volcano-plutonic assemblages in the northern Sierra terrane

Science.gov (United States)

Hanson, Richard E.; Girty, Gary H.; Harwood, David S.; Schweickert, Richard A.

2000-01-01

This field trip provides an overview of the stratigraphic and structural evolution of the northern Sierra terrane, which forms a significant part of the wall rocks on the western side of the later Mesozoic Sierra Nevada batholith in California. The terrane consists of a pre-Late Devonian subduction complex (Shoo Fly Complex) overlain by submarine arc-related deposits that record the evolution of three separate island-arc systems in the Late Sevonian-Early Mississippian, Permian, and Late Triassic-Jurassic. The two Paleozoic are packages and the underlying Shoo Fly Complex have an important bearing on plate-tectonic processes affecting the convergent margin outboard of the Paleozoic Cordilleran miogeocline, although their original paleogeographic relations to North America are controversial. The third arc package represents an overlap assemblage that ties the terrane to North America by the Late Triassic and helps constrain the nature and timing of Mesozoic orogenesis. Several of the field-trip stops examine the record of pre-Late Devonian subduction contained in the Shoo Fly Complex, as well as the paleovolcanology of the overlying Devonian to Jurassic arc rocks. Excellent glaciated exposures provide the opportunity to study a cross section through a tilted Devonian volcano-plutonic association. Additional stops focus on plutonic rocks emplaced during the Middle Jurassic arc magmatism in the terrane, and during the main pulse of Cretaceous magmatism in the Sierra Nevada batholith to the east.

Development of resonant detectors for epithermal neutron spectroscopy at pulsed neutron sources

International Nuclear Information System (INIS)

Tardocchi, M.; Pietropaolo, A.; Senesi, R.; Andreani, C.; Gorini, G.

2004-01-01

New perspectives for epithermal neutron spectroscopy are opened by the development of new detectors for inverse geometry time of flight spectrometers at pulsed neutron sources. One example is the Very Low Angle Detector (VLAD) bank planned to be delivered, within the next 4 years, within the eVERDI project, on the neutron spectrometer VESUVIO, at the ISIS pulsed neutron source (UK). VLAD will extend the (q,ω) kinematical region for neutron scattering to low wavefactor transfer (q -1 ) still keeping energy transfer >1 eV, thus allowing the investigations of new experimental studies in condensed matter systems. The technique being developed for detection of epithermal neutrons, within this low q and high-energy transfer region, is the Resonance Detection Technique. In this work, the state of the detector development will be presented with special focus on the results obtained with some prototype detectors, namely YAP scintillators and cadmium-zinc-telluride semiconductors

Study of the oxidation state of arsenic and uranium in individual particles from uranium mine tailings, Hungary

International Nuclear Information System (INIS)

Alsecz, A.; Osan, J.; Palfalvi, J.; Torok, Sz.; Sajo, I.; Mathe, Z.; Simon, R.; Falkenberg, G.

2007-01-01

Uranium ore mining and milling have been terminated in the Mecsek Mountains (southwest Hungary) in 1997. Mine tailings ponds are located between two important water bases, which are resources of the drinking water of the city of Pecs and the neighbouring villages. The average U concentration of the tailings material is 71.73 μg/g, but it is inhomogeneous. Some microscopic particles contain orders of magnitude more U than the rest of the tailings material. Other potentially toxic elements are As and Pb of which chemical state is important to estimate mobility, because in mobile form they can risk the water basis and the public health. Individual U-rich particles were selected with solid state nuclear track detector (SSNTD) and after localisation the particles were investigated by synchrotron radiation based microanalytical techniques. The distribution of elements over the particles was studied by micro beam X-ray fluorescence (μ-XRF) and the oxidation state of uranium and arsenic was determined by micro X-ray absorption near edge structure (μ-XANES) spectroscopy. Some of the measured U-rich particles were chosen for studying the heterogeneity with μ-XRF tomography. Arsenic was present mainly in As(V) and uranium in U(VI) form in the original uranium ore particles, but in the mine tailings samples uranium was present mainly in the less mobile U(IV) form. Correlation was found between the oxidation state of As and U in the same analyzed particles. These results suggest that dissolution of uranium is not expected in short term period. (authors)

Paleozoic and Mesozoic deformations in the central Sierra Nevada, California

Science.gov (United States)

Nokleberg, Warren J.; Kistler, Ronald Wayne

1980-01-01

Analysis of structural and stratigraphic data indicates that several periods of regional deformation, consisting of combined folding, faulting, cataclasis, and regional metamorphism, occurred throughout the central Sierra Nevada during Paleozoic and Mesozoic time. The oldest regional deformation occurred alono northward trends during the Devonian and Mississippian periods in most roof pendants containing lower Paleozoic metasedimentary rocks at the center and along the crest of the range. This deformation is expressed in some roof pendants by an angular unconformity separating older thrice-deformed from younger twice-deformed Paleozoic metasedimentary rocks. The first Mesozoic deformation, which consisted of uplift and erosion and was accompanied by the onset of Andean-type volcanism during the Permian and Triassic, is expressed by an angular unconformity in several roof pendants from the Saddlebag Lake to the Mount Morrison areas. This unconformity is defined by Permian and Triassic andesitic to rhyolitic metavolcanic rocks unconformably overlying more intensely deformed Pennsylvanian, Permian(?), and older metasedimentary rocks. A later regional deformation occurred during the Triassic along N. 20?_30? W. trends in Permian and Triassic metavolcanic rocks of the Saddlebag Lake and Mount Dana roof pendants, in upper Paleozoic rocks of the Pine Creek roof pendant, and in the Calaveras Formation of the western metamorphic belt; the roof pendants are crosscut by Upper Triassic granitic rocks of the Lee Vining intrusive epoch. A still later period of Early and Middle Jurassic regional deformation occurred along N. 30?-60? E. trends in upper Paleozoic rocks of the Calaveras Formation of the western metamorphic belt. A further period of deformation was the Late Jurassic Nevadan orogeny, which occurred along N. 20?_40? W. trends in Upper Jurassic rocks of the western metamorphic belt that are crosscut by Upper Jurassic granitic rocks of the Yosemite intrusive epoch

Leaching Characteristics of Uranium And Copper from Their Mineralization in the Carbonate Rich latosol of Abu-Thor Locality, South Western Sinai, Egypt

International Nuclear Information System (INIS)

El-Sheikh, E.M.; Ghazala, R.A.; Abdelwarith, A.; Salem, F.; Ali, S.

2015-01-01

The chemical processing of the poly-mineralized carbonate rich latosol ore occurring at Abu-Thor locality of south western Sinai area has been studied for the recovery of uranium and copper metal values. A technological sample assaying 700 ppm U and 9.7% Cu was collected. In the present study, two successive percolation leaching procedures were performed after determination of optimum leaching factors by agitation leaching process. The first was carried out for uranium recovery by using urea as organic leaching agent which was possible to achieve leaching efficiency exceeding 90.3%. This procedure was followed by a second one for copper recovery using ammonium hydroxide solution and ammonium carbonate. The obtained dissolution efficiency was about 93%. The leached metal values namely U and Cu from the studied ore were then extracted as marketable products in the form of ammonium diuranate and copper sulphate, respectively.

Uranium production from phosphates

International Nuclear Information System (INIS)

Ketzinel, Z.; Folkman, Y.

1979-05-01

According to estimates of the world's uranium consumption, exploitation of most rich sources is expected by the 1980's. Forecasts show that the rate of uranium consumption will increase towards the end of the century. It is therefore desirable to exploit poor sources not yet in use. In the near future, the most reasonable source for developing uranium is phosphate rock. Uranium reserves in phosphates are estimated at a few million tons. Production of uranium from phosphates is as a by-product of phosphate rock processing and phosphoric acid production; it will then be possible to save the costs incurred in crushing and dissolving the rock when calculating uranium production costs. Estimates show that the U.S. wastes about 3,000 tons of uranium per annum in phosphoric acid based fertilisers. Studies have also been carried out in France, Yugoslavia and India. In Israel, during the 1950's, a small plant was operated in Haifa by 'Chemical and Phosphates'. Uranium processes have also been developed by linking with the extraction processes at Arad. Currently there is almost no activity on this subject because there are no large phosphoric acid plants which would enable production to take place on a reasonable scale. Discussions are taking place about the installation of a plant for phosphoric acid production utilising the 'wet process', producing 200 to 250,000 tons P 2 O 5 per annum. It is necessary to combine these facilities with uranium production plant. (author)

Geobotanical studies on uranium deposits of Udaipur, Rajasthan, India

International Nuclear Information System (INIS)

Aery, N.C.; Jain, G.S.

1995-01-01

Geobotanical studies were carried out on known uranium deposits of Udaisagar region in the district of Udaipur, Rajasthan. Releve method of Braun Blanquet was employed for community analysis. Though no species with an exclusive occurrence on uranium deposits was found, certain plant species registered higher constancy and fidelity on uranium rich soils in comparison to background soils. Obviously, these characteristic plant species have evolved tolerance to high uranium contents of the soils and might be neo-endemics. (author). 23 refs., 1 fig., 4 tabs

Determination of silicon in biological and botanical reference materials by epithermal INAA and Compton suppression

International Nuclear Information System (INIS)

Landsberger, S.; Peshev, S.; Becker, D.A.

1994-01-01

Silicon determination in sixteen botanical and biological standard reference materials is described using the 29 Si(n, p) 29 Al reaction through instrumental epithermal neutron activation analysis and Compton suppression gamma-ray spectroscopy. By simultaneous utilization of both cadmium and boron epithermal filters along with anticoincidence gamma-counting, detection limits as low as 12 ppm were obtained for certain matrices, much lower than previously reported values for this type of analysis. The method is applicable to many botanical and biological matrices and is attractive with its interference free, purely instrumental nature, compared with methods using the 28 Si(n, p) 28 Al reaction or chemical separation techniques. ((orig.))

Fundamental symmetry studies at Los Alamos using epithermal neutrons

International Nuclear Information System (INIS)

Bowman, C.D.; Bowman, J.D.; Yuan, V.W.

1988-01-01

Fundamental symmetry studies using intense polarized beams of epithermal neutrons are underway at the LANSCE facility of the Los Alamos National Laboratory. Three classes of symmetry experiments can be explored: parity violation, and time reversal invariance violation for both parity-violating and parity-conserved observables. The experimental apparatus is described and performance illustrated with examples of recent measurements. Possible improvements in the facilities and prospective experiments are discussed. 15 refs., 10 figs

Hydrologic models of modern and fossil geothermal systems in the Great Basin: Genetic implications for epithermal Au-Ag and Carlin-type gold deposits

Science.gov (United States)

Person, M.; Banerjee, A.; Hofstra, A.; Sweetkind, D.; Gao, Y.

2008-01-01

The Great Basin region in the western United States contains active geothermal systems, large epithermal Au-Ag deposits, and world-class Carlin-type gold deposits. Temperature profiles, fluid inclusion studies, and isotopic evidence suggest that modern and fossil hydrothermal systems associated with gold mineralization share many common features, including the absence of a clear magmatic fluid source, discharge areas restricted to fault zones, and remarkably high temperatures (>200 ??C) at shallow depths (200-1500 m). While the plumbing of these systems varies, geochemical and isotopic data collected at the Dixie Valley and Beowawe geothermal systems suggest that fluid circulation along fault zones was relatively deep (>5 km) and comprised of relatively unexchanged Pleistocene meteoric water with small (horizons. Those with minimal fluid ?? 18O shifts are restricted to high-permeability fault zones and relatively small-scale (???5 km), single-pass flow systems (e.g., Beowawe). Those with intermediate to large isotopic shifts (e.g., epithermal and Carlin-type Au) had larger-scale (???15 km) loop convection cells with a greater component of flow through marine sedimentary rocks at lower water/rock ratios and greater endowments of gold. Enthalpy calculations constrain the duration of Carlin-type gold systems to probably account for the amount of silica in the sinter deposits. In the Carlin trend, fluid circulation extended down into Paleozoic siliciclastic rocks, which afforded more mixing with isotopically enriched higher enthalpy fluids. Computed fission track ages along the Carlin trend included the convective effects, and ranged between 91.6 and 35.3 Ma. Older fission track ages occurred in zones of groundwater recharge, and the younger ages occurred in discharge areas. This is largely consistent with fission track ages reported in recent studies. We found that either an amagmatic system with more permeable faults (10-11 m2) or a magmatic system with less

Strontium Isotopic Composition of Paleozoic Carbonate Rocks in the Nevada Test Site Vicinity, Clark, Lincoln, and Nye Counties, Nevada and Inyo County, California

International Nuclear Information System (INIS)

James B. Paces; Zell E. Peterman; Kiyoto Futa; Thomas A. Oliver; Brian D. Marshall.

2007-01-01

Ground water moving through permeable Paleozoic carbonate rocks represents the most likely pathway for migration of radioactive contaminants from nuclear weapons testing at the Nevada Test Site, Nye County, Nevada. The strontium isotopic composition (87Sr/86Sr) of ground water offers a useful means of testing hydrochemical models of regional flow involving advection and reaction. However, reaction models require knowledge of 87Sr/86Sr data for carbonate rock in the Nevada Test Site vicinity, which is scarce. To fill this data gap, samples of core or cuttings were selected from 22 boreholes at depth intervals from which water samples had been obtained previously around the Nevada Test Site at Yucca Flat, Frenchman Flat, Rainier Mesa, and Mercury Valley. Dilute acid leachates of these samples were analyzed for a suite of major- and trace-element concentrations (MgO, CaO, SiO2, Al2O3, MnO, Rb, Sr, Th, and U) as well as for 87Sr/86Sr. Also presented are unpublished analyses of 114 Paleozoic carbonate samples from outcrops, road cuts, or underground sites in the Funeral Mountains, Bare Mountain, Striped Hills, Specter Range, Spring Mountains, and ranges east of the Nevada Test Site measured in the early 1990's. These data originally were collected to evaluate the potential for economic mineral deposition at the potential high-level radioactive waste repository site at Yucca Mountain and adjacent areas (Peterman and others, 1994). Samples were analyzed for a suite of trace elements (Rb, Sr, Zr, Ba, La, and Ce) in bulk-rock powders, and 87Sr/86Sr in partial digestions of carbonate rock using dilute acid or total digestions of silicate-rich rocks. Pre-Tertiary core samples from two boreholes in the central or western part of the Nevada Test Site also were analyzed. Data are presented in tables and summarized in graphs; however, no attempt is made to interpret results with respect to ground-water flow paths in this report. Present-day 87Sr/86Sr values are compared to values

The significance of zircon characteristic and its uranium concentration in evaluation of uranium metallogenetic prospect

International Nuclear Information System (INIS)

Li Yaosong; Zhu Jiechen; Xia Yuliang

1992-02-01

Zircon characteristic and its relation to uranium metallogenetic process have been studied on the basis of physics properties and chemical compositions. It is indicated that the colour of zircon crystal is related to uranium concentration; on the basis of method of zircon population type of Pupin J.P., the sectional plan of zircon population type has been designed, from which result that zircon population type of uranium-producing rock body is distributed mainly in second section, secondly in fourth section; U in zircon presents synchronous increase trend with Th, Hf and Ta; the uranium concentration in zircon from uranium-producing geologic body increases obviously and its rate of increase is more than that of the uranium concentration in rock; the period, in which uranium concentration in zircon is increased, is often related to better uranium-producing condition in that period of this area. 1785 data of the average uranium concentration in zircon have been counted and clear regularity has been obtained, namely the average uranium concentrations in zircon in rich uranium-producing area, rock, geologic body and metallogenetic zone are all higher than that in poor or no uranium-producing area, rock, geologic body and metallogenetic zone. This shows that the average uranium concentration in zircon within the region in fact reflects the primary uranium-bearing background in region and restricts directly follow-up possibility of uranium mineralization. On the basis of this, the uranium source conditions of known uranium metallogenetic zones and prospective provinces have been discussed, and the average uranium concentrations in zircon from magmatic rocks for 81 districts have been contrasted and graded, and some districts in which exploration will be worth doing further are put forward

End Late Paleozoic tectonic stress field in the southern edge of Junggar Basin

Directory of Open Access Journals (Sweden)

Wei Ju

2012-09-01

Full Text Available This paper presents the end Late Paleozoic tectonic stress field in the southern edge of Junggar Basin by interpreting stress-response structures (dykes, folds, faults with slickenside and conjugate joints. The direction of the maximum principal stress axes is interpreted to be NW–SE (about 325°, and the accommodated motion among plates is assigned as the driving force of this tectonic stress field. The average value of the stress index R′ is about 2.09, which indicates a variation from strike-slip to compressive tectonic stress regime in the study area during the end Late Paleozoic period. The reconstruction of the tectonic field in the southern edge of Junggar Basin provides insights into the tectonic deformation processes around the southern Junggar Basin and contributes to the further understanding of basin evolution and tectonic settings during the culmination of the Paleozoic.

Isotopic tracers of gold deposition in Paleozoic limestones, Southern Nevada

International Nuclear Information System (INIS)

Peterman, Z.E.; Widmann, B.L.; Marshall, B.D.; Aleinikoff, J.N.; Futa, K.; Mahan, S.A.

1994-01-01

Strontium isotopic analyses of barren and mineralized Paleozoic carbonate rocks show that hydrothermal fluids added radiogenic strontium ( 87 Sr) to the mineralized zones. At Bare Mountain, samples collected from mineralized areas have δ 87 Sr t values ranging from +3.0 to +23.0, whereas unmineralized carbonate rocks have δ 87 Sr, values of -0.6 to +2.9. In other ranges, δ 87 Sr, values of the unmineralized carbonate rocks are even lower and virtually indistinguishable from primary marine values. This correlation of elevated δ 87 Sr t values with mineralized zones provides a useful technique for assessing the mineral potential of the Paleozoic basement beneath Yucca Mountain, and may find broader use in mineral exploration in the Basin and Range province as a whole

Method and apparatus for dual-spaced fast/epithermal neutron porosity measurements

International Nuclear Information System (INIS)

Smith, H.D. Jr.

1986-01-01

A method is described for determining the porosity of earth formations in the vicinity of a well borehole, comprising: (a) irradiating the earth formations in the vicinity of the well borehole with a continuous chemical type source of fast neutrons, (b) detecting the fast neutron population at a first shorter spaced distance from the neutron source in the borehole and generating signals representative thereof, (c) detecting the epithermal neutron population at a second space distance from the neutron source in the borehole and generating signals representative thereof, the second spaced distance being greater than the first spaced distance from the neutron source, (d) forming a ratio of the signals representing the fast and epithermal neutron populations to derive a measurement signal functionally related to the porosity of the earth formations in the vicinity of the borehole, and (e) calibrating the measurement signal according to a predetermined functional relationship to derive a porosity signal quantitatively representative of the porosity of the earth formations in the vicinity of the borehole

International Uranium Resources Evaluation Project (IUREP) national favourability studies: Honduras

International Nuclear Information System (INIS)

1977-08-01

In 1953, the U.S. Atomic Energy Commission, on invitation of the government of Honduras, conducted uranium reconnaissance in parts of the country. The survey consisted of scintillometric examination of all formations, veins, dikes, sills and contacts along more than 1,500 km of road. Additionally, 17 mines and prospects were examined, but in no location were uranium occurrences found. The largest and most consistently radioactive deposit noted was a body of volcanic ash at Santa Rosa de Copan, a sample of which assayed 15 ppm U 3 O 8 . A uranium prospect has been described from the Yatnala area in northwest Honduras. Uraninite and oxidation products occur in association with copper and mercury minerals in veinlets as well as disseminations in a Lower Cretaceous limestone conglomerate, the llama Formation. The llama Formation is the conglomeratic facies of the Atima (limestone) Formation, both of which are in the Yojoa Group. At the time of the U. N. development program survey in May, 1970, no uranium deposits were known in Honduras. Information is not available on current exploration in Honduras. The state owns most mineral deposits but may grant rights for exploration and exploitation of the subsoil. Mineral and surface titles are separate. Deposits of uranium and its salts, thorium and similar atomic energy substances are reserved to the state. Foreign citizens and companies, with some exceptions, may acquire mineral rights. Several groups of sediments might be of interest for uranium exploration. The Todos Santos redbeds and the El Plan Formation are both shallow marine and hence may contain marginal marine facies favorable for uranium. In the southern and central Cordillera, the Valle de Angeles sediments, particularly the sandstones, may be of interest. The contacts between Permian granites and schists (Paleozoic) may also warrant attention. Lacking further information on which to base a more optimistic outlook, it is estimated that the uranium potential of

Detector for imaging and dosimetry of laser-driven epithermal neutrons by alpha conversion

Science.gov (United States)

Mirfayzi, S. R.; Alejo, A.; Ahmed, H.; Wilson, L. A.; Ansell, S.; Armstrong, C.; Butler, N. M. H.; Clarke, R. J.; Higginson, A.; Notley, M.; Raspino, D.; Rusby, D. R.; Borghesi, M.; Rhodes, N. J.; McKenna, P.; Neely, D.; Brenner, C. M.; Kar, S.

2016-10-01

An epithermal neutron imager based on detecting alpha particles created via boron neutron capture mechanism is discussed. The diagnostic mainly consists of a mm thick Boron Nitride (BN) sheet (as an alpha converter) in contact with a non-borated cellulose nitride film (LR115 type-II) detector. While the BN absorbs the neutrons in the thermal and epithermal ranges, the fast neutrons register insignificantly on the detector due to their low neutron capture and recoil cross-sections. The use of solid-state nuclear track detectors (SSNTD), unlike image plates, micro-channel plates and scintillators, provide safeguard from the x-rays, gamma-rays and electrons. The diagnostic was tested on a proof-of-principle basis, in front of a laser driven source of moderated neutrons, which suggests the potential of using this diagnostic (BN+SSNTD) for dosimetry and imaging applications.

Epithermal neutron beam design for neutron capture therapy at the Power Burst Facility and the Brookhaven Medical Research Reactor

International Nuclear Information System (INIS)

Wheeler, F.J.; Parsons, D.K.; Rushton, B.L.; Nigg, D.W.

1990-01-01

Nuclear design studies have been performed for two reactor-based epithermal neutron beams for cancer treatment by neutron capture therapy (NCT). An intermediate-intensity epithermal beam has been designed and implemented at the Brookhaven Medical Research Reactor (BMRR). Measurements show that the BMRR design predictions for the principal characteristics of this beam are accurate. A canine program for research into the biological effects of NCT is now under way at BMRR. The design for a high-intensity epithermal beam with minimal contamination from undesirable radiation components has been finalized for the Power Burst Facility (PBF) at the Idaho National Engineering Laboratory. This design will be implemented when it is determined that human NCT trials are advisable. The PBF beam will exhibit approximately an order of magnitude improvement in absolute epithermal flux intensity over that available in the BMRR, and its angular distribution and spectral characteristics will be more advantageous for NCT. The combined effects of beam intensity, angular distribution, spectrum, and contaminant level allow the desired tumor radiation dose to be delivered in much shorter times than are possible with the currently available BMRR beam, with a significant reduction (factor of 3 to 5) in collateral dose due to beam contaminants

Analysis of geological condition and prospecting potential of uranium metallogenesis in Maling granite mass

International Nuclear Information System (INIS)

Shao Fei; Zou Maoqing; Wu Yong; Xu Jinshan; Xu Wang; Chen Chang

2011-01-01

Based on the study of regional geological evolution of Maling granite mass, uranium content of granite mass and its peripheric strata, petrogeochemistry and the known spatial distribution pattern of uranium mineralization and ore-controlling structures, new recognition is 1) Maling composite mass is the 'S' type re-melted granite, 2) the accumulative area of regional uranium metallogenic substances forms uranium-rich re-melted strata, 3) magma evolution is the matter base for the uranium-rich hydrotherm, 4) NE-trending main faults are channels for metallogenesis and the lateral high-angle dipping faults, fractures and interlayer fractures in the peripheric strata are the spaces of mineralization. The ore intersected by drilling in Maling granite is acidic type. Prospecting potential of Maling granite mass is analyzed, and preferable prospecting space is delineated for further exploration. (authors)

Preparation of the pur uranium-metal; La preparation de l'uranium-metal pur

Energy Technology Data Exchange (ETDEWEB)

Goldschmidt, B; Vertes, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1955-07-01

A detailed description of the chemical processes used to prepare in the factory of Bouchet of the CEA (Seine-Et-Oise) pur metal uranium with either relatively rich ores, or extracts coming of physical or chemical treatment of poor ores. The nitric treatment of ores succeeds to the production of uranate of impure sodium carbonate. This last last product is dissolved in nitric acid and the uranyl nitrate is extracted by tributyl-phosphate diluted in an inert solvent. The uranyl nitrate pure is re-extracted and successively transformed in uranium peroxide, in orange oxide then in brown oxide which is transformed in fluoride by the anhydrous hydrofluoric acid. Uranate fluoride is then reduced in metal by the pure calcium with an yield superior to 99%. (authors) [French] Description detaillee des procedes chimiques mis en jeu pour preparer a l'Usine du Bouchet du Commissariat a l'Energie Atomique (Seine-et-Oise) l'uranium metal pur a partir soit de minerais relativement riches, soit de concentres provenant de traitement physique ou chimique de minerais pauvres. Le traitement nitrique des minerais aboutit a la production d'uranate de soude impur. Ce dernier est a son tour dissous dans l'acide nitrique et le nitrate d'uranyle est extrait par du tributyl-phosphate dilue par un solvant inerte. Le nitrate d'uranyle pur reextrait est transforme successivement en peroxyde d'uranium, en oxyde orange puis en oxyde brun qui est transforme en fluorure par l'acide fluorhydrique anhydre. Le fluorure uraneux est reduit en metal par le calcium pur avec un rendement superieur a 99 %. (auteurs)

A new position-sensitive detector for thermal and epithermal neutrons

International Nuclear Information System (INIS)

Jeavons, A.P.; Ford, N.L.; Lindberg, B.; Sachot, R.

1977-01-01

A new two-dimensional position-sensitive neutron detector is described. It is based on (n,γ) neutron resonance capture in a foil with subsequent detection of internal conversion electrons with a high-density proportional chamber. Large-area detectors with a 1 mm spatial resolution are feasible. A detection efficiency of 50% is possible for thermal neutrons using gadolinium-157 foil and for epithermal neutrons using hafnium-177. (Auth.)

Determination of 30 elements in coal and fly ash by thermal and epithermal neutron-activation analysis

International Nuclear Information System (INIS)

Rowe, J.J.; Steinnes, E.

1977-01-01

Thirty elements are determined in coal and fly ash by instrumental neutron-activation analysis using both thermal and epithermal irradiation. Gamma-ray spectra were recorded 7 and 20 days after the irradiations. The procedure is applicable to the routine analysis of coals and fly ash. Epithermal irradiation was found preferable for the determination of Ni, Zn, As, Se, Br, Rb, Sr, Mo, Sb, Cs, Ba, Sm, Tb, Hf, Ta, W, Th and U, whereas thermal irradiation was best for Sc, Cr, Fe, Co, La, Ce, Nd, Eu, Yb and Lu. Results for SRM 1632 (coal) and SRM 1633 (fly ash) agree with those of other investigators. (author)

A discussion on tectonic geological evolution and the distribution pattern of uranium mineralization in Langshan mountain area, inner mongolia

International Nuclear Information System (INIS)

Yang Fuxin

1994-01-01

Langshan area is an orogenic belt which consists of two lithospheric faults, three ductile shear zones and some napped structures or thrusting napped structures, developed on palaeorift in Proterozoic Era. Uranium mineralization of ductile fault rock type and other types were with metallogenetic ages being of Middle-Late Proterozoic and Late Paleozoic. Major ore-controlling and ore-concentrating structural space are ductile fractures. Based on the above mentioned, the author points out the ore-prospecting potential and direction in this area

Geochronology of the Sleeper deposit, Humboldt County, Nevada: epithermal gold-silver mineralization following emplacement of a silicic flow-dome complex

Science.gov (United States)

Conrad, J.E.; McKee, E.H.; Rytuba, J.J.; Nash, J.T.; Utterback, W.C.

1993-01-01

The high-grade gold-silver deposits at the Sleeper mine are low sulfidation, quartz-adularia-type epithermal deposits, formed during the final stages of igneous hydrothermal activity of a small middle Miocene silicic flow-dome complex in north-central Nevada. There were multiple pulses of alteration and mineralization but all occurred within a period of less than 2 m.y. Later supergene alteration formed opal and alunite about 5.4 Ma but produced no Au or Ag mineralization other than some remobilization to produce locally rich pockets of secondary Au and Ag enrichment and is unrelated to the older magmatic hydrothermal system. The Sleeper deposit in the northern part of the Great Basin is genetically related to bimodal volcanism that followed a long period of arc-related andesitic volcanism in the same general region. -from Authors

Modeling the mobility of uranium from NORM-rich bedrock using multivariate statistical techniques - The mobility of uranium from U-containing bedrock materials as a function of pH: Implications for tunnel construction

Energy Technology Data Exchange (ETDEWEB)

Helmers, Tari; Fjermestad, Halldis; Salbu, Brit; Skipperud, Lindis [Norwegian University of Life Sciences, P.O. Box 5003, 1432 Aas (Norway); Meland, Sondre; Hagelia, Per [Norwegian Public Roads Administration, P.O. Box 8142, 0033 Oslo (Norway)

2014-07-01

According to amendments made to the Norwegian Pollution Control Act in 2011, naturally occurring radioactive material is now to be considered as an environmental contaminant, in addition to organic pollutants and trace metals. Environmental contamination is strongly correlated with the mobility and bioavailability of metals and radionuclides in natural systems. In order to determine the risk of environmental contamination from e.g. uranium (U) in alum shale areas, it is of particular importance to determine the mobility of U and trace metals found in the rock materials and their binding mechanisms. By determining the speciation and mobility of uranium and trace metals, better predictions can be made on the transport of contaminants in the environment from intervention like road and tunnel construction. The substrate media analyzed in this work was collected from a future tunnel construction site that is being built in the Gran municipality on National road Rv4 in Norway. The bedrock in the Gran municipality is rich in U-bearing minerals. Therefore, there is high potential for environmental contamination from the rock material removed for tunnel construction purposes. The present work focuses upon the effects of pH and the contact time (substrate media: solution) on the mobility of uranium. In order to identify the effects of pH and contact time on mobility, sample cores collected from an area rich in alum shale were subjected to an extended leaching experiment. In this experiment, the substrate materials were treated with five different pH solutions and were analyzed for different contact times. In addition, the results were compared to data from a sequential extraction experiment. In the leaching experiment, the mobilization of uranium in all of the substrate material was affected by the pH of solution. All of the samples were capable of quickly buffering pH solutions with a pH as low as 4 to neutral-alkaline conditions, attributed to the carbonate minerals

Origin of sandstone-hosted uranium deposits, Frome Embayment, South Australia

International Nuclear Information System (INIS)

Sanford, R.F.

1985-01-01

The formation of sandstone-hosted uranium deposits in the Frome Embayment of South Australia is largely a result of tectonic events possibly as old as the Archean. Uranium deposits of several types and ages in the region demonstrate the importance of uranium enrichment in the source area. Mobile zones around the Archean terrane of the Gawler block have been the locus of intermittent tectonic activity from Early Proterozoic to recent time. Vein-type uranium deposits in basement source rocks are concentrated in these zones, because they favor deep crustal partial melting and ascent of Na-rich granitic magmas and hydrothermal solutions. Relatively stable areas bordered by mobile zones, are important for the formation of sandstone-hosted uranium deposits because they act as platforms for terrigenous sedimentation from the surrounding, uplifted, uranium-rich basement rocks. Wet, subtropical conditions prevailing at the time of uplift aided rapid erosion and subaerial deposition of channel sands with intermixed organic detritus. Later uplift accompanied by erosion of the recently deposited sands in the headwater area caused increased recharge of oxygenated uraniferous ground water, which led to the formation of geochemical-cell roll-front type deposits like those in the Wyoming basins. Subsequent arid conditions helped preserve the deposits. (author)

Geology and uranium mineralization in the eastern part of the Kani Basin, Gifu, Central Japan

International Nuclear Information System (INIS)

Kobayashi, Takao

1989-01-01

The Misano and Utozaka uranium deposits in the eastern part of the Kani Basin are within Miocene nonmarine sediments which unconformably overlie Paleozoic-Mesozoic sediments and Cretaceous-Paleogene granites. These deposits are classified as sandstone type deposits structurally controlled by palaeo-channel structures formed on the pre-Miocene basement rocks. The host rock is the Kani lignite-bearing formation which is the lowermost sequence of the Kani Group. The age of the formation was estimated to be 20-19 Ma by fission track dating. The mineralized host sediments consist of conglomerates, arkosic, tuffaceous and carbonaceous sandstones. Although no primary uranium mineral was identified to date, it is considered that uranium is present in uranous form. The mineralization was strongly controlled by a fault structure within the basement granites as well as the channel structure formed on the basement rocks, especially on the granites. The enriched ore zone of the Misano deposit distributes within the basal part of the Kani lignite-bearing formation above the basement fault structure and in the palaeo-channel downward from the fault structure. The basement granites were also mineralized along the fault structure. Groundwater leached uranium form the basement granites, and migrated along the fault structure to the host sediments to form the deposite. (Kako, I.)

Behaviour of organic matters in uranium ore processing

International Nuclear Information System (INIS)

Wu Sanmin

1991-01-01

The oxidation-reduction behaviour of organic matters in the course of oxidation roasting, acid leaching and alkali leaching, the regeneration of humic acid and the consumption of reagents are described. The mineralogical characteristics of the organic matter samples were studied. The results show that its organic matter rich in volatile carbon and with the shorter evolutionary process and lower association is easily oxidized with higher consumption of oxidant during its acid leaching; it is easily oxidized with forming humic acid during alkali leaching; and pretreating it by oxidation roasting is beneficial to the oxidation of uranium. On the contrary, the organic matter rich in fixed carbon, and with longer evolutionary process and higher association is difficultly oxidized with lower consumption of oxidant during its acid leaching; it is difficult to regenerate humic acid for it during alkali leaching; and the uranium can be easily reduced and the leaching performance of uranium can be lowered

VLAD for epithermal neutron scattering experiments at large energy transfers

International Nuclear Information System (INIS)

Tardocchi, M; Gorini, G; Perelli-Cippo, E; Andreani, C; Imberti, S; Pietropaolo, A; Senesi, R; Rhodes, N R; Schooneveld, E M

2006-01-01

The Very Low Angle Detector (VLAD) bank will extend the kinematical region covered by today's epithermal neutron scattering experiments to low momentum transfer ( -1 ) together with large energy transfer 0 -4 0 . In this paper the design of VLAD is presented together with Montecarlo simulations of the detector performances. The results of tests made with prototype VLAD detectors are also presented, confirming the usefulness of the Resonance Detector for measurements at very low scattering angles

Advances on detectors for low-angle scattering of epithermal neutrons

International Nuclear Information System (INIS)

Perelli Cippo, E; Gorini, G; Tardocchi, M; Andreani, C; Pietropaolo, A; Senesi, R; Rhodes, N J; Schoonveld, E M

2008-01-01

The Very Low Angle Detector (VLAD) installed at the ISIS spallation neutron source is a novel instrument for epithermal neutron scattering with a range of applications in solid state physics. VLAD extends the kinematical space of the VESUVIO spectrometer to low momentum transfers at neutron energies above 1 eV. Measurements at scattering angles as low as 1° have been made with limitations due to the achievable signal/background ratio. (technical design note)

Measurement of the neutron flux distributions, epithermal index, Westcott thermal neutron flux in the irradiation capsules of hydraulic conveyer (Hyd) and pneumatic tubes (Pn) facilities of the KUR

International Nuclear Information System (INIS)

Chatani, Hiroshi

2001-05-01

The reactions of Au(n, γ) 198 Au and Ti(n, p) 47 or 48 Sc were used for the measurements of the thermal and epithermal (thermal + epithermal) and the fast neutron flux distributions, respectively. In the case of Hyd (Hydraulic conveyer), the thermal + epithermal and fast neutron flux distributions in the horizontal direction in the capsule are especially flat; the distortion of the fluxes are 0.6% and 5.4%, respectively. However, these neutron fluxes in the vertical direction are low at the top and high at the bottom of the capsule. These differences between the top and bottom are 14% for both distributions. On the other hand, in polyethylene capsules of Pn-1, 2, 3 (Pneumatic tubes Nos. 1, 2, 3), in contrast with Hyd, these neutron flux distributions in the horizontal direction have gradients of 8 - 18% per 2.5 cm diameter, and those on the vertical axis have a distortion of approximately 5%. The strength of the epithermal dE/E component relative to the neutron density including both thermal and epithermal neutrons, i.e., the epithermal index, for the hydraulic conveyer (Hyd) and pneumatic tube No.2 (Pn-2), in which the irradiation experiments can be achieved, are determined by the multiple foil activation method using the reactions of Au(n, γ) 198 Au and Co(n, γ) 60(m+g) Co. The epithermal index observed in an aluminum capsule of Hyd is 0.034-0.04, and the Westcott thermal neutron flux is 1.2x10 14 cm -2 sec -1 at approximately 1 cm above the bottom. The epithermal index in a Pn-2 polyethylene capsule was measured by not only the multiple foil activation method but also the Cd-ratio method in which the Au(n, γ) 198 Au reaction in a cadmium cover is also used. The epithermal index is 0.045 - 0.055, and the thermal neutron flux is 1.8x10 13 cm -2 sec -1 . (J.P.N.)

Uranium in tertiary stream channels, Lake Frome area, South Australia

International Nuclear Information System (INIS)

Brunt, D.A.

1978-01-01

Uranium exploration over a wide area of the Southern Frome Embayment, South Australia, has defined a number of Lower Tertiary fluvial palacochannels incised in older rocks. The buried channels contain similar stratigraphic sequences of interbedded sand, silt, and clay, probably derived from the adjacent uranium-rich Olary Province. Uranium mineralization is pervasive within two major palacochannels, and four small uranium deposits have been found in the basal sands of these channel sequences, at the margins of extensive tongues of limonitic sand. A genetic model is proposed suggesting formation by a uraniferous geochemical cell which migrated down the stream gradient and concentrated uranium on its lateral margins adjacent to the channel bank

New data on the Paleozoic of the Semipalatinsk test site

International Nuclear Information System (INIS)

Ergaliev, G.Kh.; Myasnikov, A.K.; Nikitin, I.F.; Polyanskij, N.V.; Sergeeva, L.V.; Sergieva, M.N.; Sal'menova, L.T.; Utegulov, M.T.; Tsaj, D.T.; Shuzhanov, V.M.

1998-01-01

The latest data on Paleozoic of the Semipalatinsk test site acquired as result of the stratigraphic and pale ontological investigation which have been conducted for the first time after 46-year interval in geological studies are presented. (author)

Paleozoic–early Mesozoic gold deposits of the Xinjiang Autonomous Region, northwestern China

Science.gov (United States)

Rui, Zongyao; Goldfarb, Richard J.; Qiu, Yumin; Zhou, T.; Chen, R.; Pirajno, Franco; Yun, Grace

2002-01-01

The late Paleozoic–early Mesozoic tectonic evolution of Xinjiang Autonomous Region, northwestern China provided a favorable geological setting for the formation of lode gold deposits along the sutures between a number of the major Eastern Asia cratonic blocks. These sutures are now represented by the Altay Shan, Tian Shan, and Kunlun Shan ranges, with the former two separated by the Junggar basin and the latter two by the immense Tarim basin. In northernmost Xinjiang, final growth of the Altaid orogen, southward from the Angara craton, is now recorded in the remote mid- to late Paleozoic Altay Shan. Accreted Early to Middle Devonian oceanic rock sequences contain typically small, precious-metal bearing Fe–Cu–Zn VMS deposits (e.g. Ashele). Orogenic gold deposits are widespread along the major Irtysh (e.g. Duyolanasayi, Saidi, Taerde, Kabenbulake, Akexike, Shaerbulake) and Tuergen–Hongshanzui (e.g. Hongshanzui) fault systems, as well as in structurally displaced terrane slivers of the western Junggar (e.g. Hatu) and eastern Junggar areas. Geological and geochronological constraints indicate a generally Late Carboniferous to Early Permian episode of gold deposition, which was coeval with the final stages of Altaid magmatism and large-scale, right-lateral translation along older terrane-bounding faults. The Tian Shan, an exceptionally gold-rich mountain range to the west in the Central Asian republics, is only beginning to be recognized for its gold potential in Xinjiang. In this easternmost part to the range, northerly- and southerly-directed subduction/accretion of early to mid-Paleozoic and mid- to late Paleozoic oceanic terranes, respectively, to the Precambrian Yili block (central Tian Shan) was associated with 400 to 250 Ma arc magmatism and Carboniferous through Early Permian gold-forming hydrothermal events. The more significant resulting deposits in the terranes of the southern Tian Shan include the Sawayaerdun orogenic deposit along the Kyrgyzstan

Neutron kinetics in moderators and SNM detection through epithermal-neutron-induced fissions

Energy Technology Data Exchange (ETDEWEB)

Gozani, Tsahi, E-mail: tgmaven@gmail.com [1050 Harriet St., Palo Alto, CA 94301 (United States); King, Michael J. [Rapiscan Laboratories Inc., 520 Almanor Ave., Sunnyvale, CA 94085 (United States)

2016-01-01

Extension of the well-established Differential Die Away Analysis (DDAA) into a faster time domain, where more penetrating epithermal neutrons induce fissions, is proposed and demonstrated via simulations and experiments. In the proposed method the fissions stimulated by thermal, epithermal and even higher-energy neutrons are measured after injection of a narrow pulse of high-energy 14 MeV (d,T) or 2.5 MeV (d,D) source neutrons, appropriately moderated. The ability to measure these fissions stems from the inherent correlation of neutron energy and time (“E–T” correlation) during the process of slowing down of high-energy source neutrons in common moderating materials such as hydrogenous compounds (e.g., polyethylene), heavy water, beryllium and graphite. The kinetic behavior following injection of a delta-function-shaped pulse (in time) of 14 MeV neutrons into such moderators is studied employing MCNPX simulations and, when applicable, some simple “one-group” models. These calculations served as a guide for the design of a source moderator which was used in experiments. Qualitative relationships between slowing-down time after the pulse and the prevailing neutron energy are discussed. A laboratory system consisting of a 14 MeV neutron generator, a polyethylene-reflected Be moderator, a liquid scintillator with pulse-shape discrimination (PSD) and a two-parameter E–T data acquisition system was set up to measure prompt neutron and delayed gamma-ray fission signatures in a 19.5% enriched LEU sample. The measured time behavior of thermal and epithermal neutron fission signals agreed well with the detailed simulations. The laboratory system can readily be redesigned and deployed as a mobile inspection system for SNM in, e.g., cars and vans. A strong pulsed neutron generator with narrow pulse (<75 ns) at a reasonably high pulse frequency could make the high-energy neutron induced fission modality a realizable SNM detection technique.

Thermoluminescence applied to uranium exploration and genesis of the Westmoreland uranium deposits - implications for the Northern Territory

International Nuclear Information System (INIS)

Hochman, M.B.M.; Ypma, P.J.M.

1984-01-01

The Westmoreland uranium deposits occur on the northern flank of the Murphy Tectonic Ridge in the upper member of the Westmoreland Conglomerate. Uranium mineralisation is spatially associated with the contact of the overlying basaltic Siegal Volcanics and the margins of intrusive dolerite dykes which are geochemically similar to the Siegal Volcanics. Thermoluminescence measurements on 800 samples from within the orebodies and surrounding host rock have indicated that all of the Westmoreland Conglomerate has suffered major radiation damage attributable to at least 10 ppm uranium over 10 9 years. The underlying rhyolitic Mid Proterozoic Cliffdale Volcanics have distinctive TL glow curves indicative of radiation sensitisation caused by high uranium contents. These volcanics are part of the Mid Proterozoic volcanic event known to be enriched in uranium. The Westmoreland Conglomerate has been derived by erosion of the uranium-rich Cliffdale Volcanics and associated Nicholson Granite Complex which makes it likely that the Westmoreland Conglomerate had a high inherent uranium content. It is proposed that this precontained uranium within the Westmoreland Conglomerate was remobilized in a convective cell system possibly triggered by intrusion of dolerite dykes, or by a later rejuvenation of vertical structures which provided an ascending heat flow. Pitchblende was precipitated where suitable reducing conditions existed close to the basic volcanics and dykes

Depth-dose evaluation for lung and pancreas cancer treatment by BNCT using an epithermal neutron beam

International Nuclear Information System (INIS)

Matsumoto, Tetsuo; Fukushima, Yuji

2000-01-01

The depth-dose distributions were evaluated for possible treatment of both lung and pancreas cancers using an epithermal neutron beam. The MCNP calculations showed that physical dose in tumors were 6 and 7 Gy/h, respectively, for lung and pancreas, attaining an epithermal neutron flux of 5x10 8 ncm -2 s -1 . The boron concentrations were assumed at 100 ppm and 30 ppm, respectively, for lung and pancreas tumors and normal tissues contains 1/10 tumor concentrations. The dose ratios of tumor to normal tissue were 2.5 and 2.4, respectively, for lung and pancreas. The dose evaluation suggests that BNCT could be applied for both lung and pancreas cancer treatment. (author)

UN2−x layer formed on uranium metal by glow plasma nitriding

International Nuclear Information System (INIS)

Long, Zhong; Hu, Yin; Chen, Lin; Luo, Lizhu; Liu, Kezhao; Lai, Xinchun

2015-01-01

Highlights: • We used a very simple method to prepare nitride layer on uranium metal surface. • This modified layer is nitrogen-rich nitride, which should be written as UN 2−x . • TEM images show the nitride layer is composed of nano-sized grains. • XPS analysis indicates there is uranium with abnormal low valence in the nitride. - Abstract: Glow plasma nitriding is a simple and economical surface treatment method, and this technology was used to prepare nitride layer on the surface of uranium metal with thickness of several microns. The composition and structure of the nitride layer were analyzed by AES and XRD, indicating that this modified layer is nitrogen-rich uranium nitride, which should be written as UN 2−x . TEM images show the nitride layer is composed of nano-sized grains, with compact structure. And XPS analysis indicates there is uranium with abnormal low valence existing in the nitride. After the treated uranium storage in air for a long time, oxygen just entered the surface several nanometers, showing the nitride layer has excellent oxidation resistance. The mechanism of nitride layer formation and low valence uranium appearance is discussed

Trends in uranium and their significance for investors in mining shares

International Nuclear Information System (INIS)

Fishlock, D.

1975-01-01

After a general introduction on the nuclear industry and uranium the following points are discussed: uranium supply and demand; the financing of exploration and exploitation in order to meet an expected demand of seven or ten times the present world output of uranium within 25 years; the idiosyncrasies of government policies among the uranium-rich nations, and whether and how they can be reconciled with supply and demand; environmental problems, including the activities of nuclear energy's opponents, which in turn could greatly influence supply and demand

Study on geochronology and uranium source of sandstone-type uranium deposit in Dongsheng area

International Nuclear Information System (INIS)

Liu Haibin; Xia Yuliang; Tian Shifeng

2007-01-01

This paper studied the geochronology of sandstone-type uranium deposit in the Dongsheng area of Ordos Basin. In eastern segment, ages of mineralization at the wing of the ore-roll are found to be 120 ± 5 Ma and 80 ± 5 Ma, and at the front of the ore-roll are 20 ± 2 Ma and 8 ± 1 Ma; While in middle segment, ages of mineralization are 124 ± 6 Ma and 80 ± 5 Ma. This means that the main mineralization in Dongsheng area were formed at early Jurassic and late Cretaceous, and correspondent to the time of structure uplift. Mineralization of roll-front (rich ore) which formed in Miocene and Pliocene may related to tectonic-thermal event taken place at that time and reformed the early mineralization in this area. The isochron line age of sample with uranium grade 0 ) in the sandbody is 24.64 x 10 -6 also shows the uranium pre-concentration in the strata. The even value of ΔU of rocks in Zhiluo formation is -70.2%, this shows that non-mineralized rocks have migrated uranium and acted as important metallogenic uranium sources. (authors)

Qualitative dose response of the normal canine head to epithermal neutron irradiation with and without boron capture

International Nuclear Information System (INIS)

DeHaan, C.E.; Gavin, P.R.; Kraft, S.L.; Wheeler, F.J.; Atkinson, C.A.

1992-01-01

Boron Neutron Capture Therapy is being re-evaluated for the treatment of intracranial tumors. Prior to human clinical trials, determination of normal tissue tolerance is critical. Dogs were chosen as a large animal model for the following reasons. Dogs can be evaluated with advanced imaging, diagnostic and therapeutic modalities. Dogs are amenable to detailed neurologic examination and subtle behavioral changes are easily detected. Specifically, Labrador retrievers were chosen for their large body and head size. The dogs received varying doses of epithermal neutron irradiation and boron neutron capture irradiation using an epithermal neutron source. The dogs were closely monitored for up to one year post irradiation

A new paleozoic Symmoriiformes (Chondrichthyes from the late Carboniferous of Kansas (USA and cladistic analysis of early chondrichthyans.

Directory of Open Access Journals (Sweden)

Alan Pradel

Full Text Available BACKGROUND: The relationships of cartilaginous fishes are discussed in the light of well preserved three-dimensional Paleozoic specimens. There is no consensus to date on the interrelationship of Paleozoic chondrichthyans, although three main phylogenetic hypotheses exist in the current literature: 1. the Paleozoic shark-like chondrichthyans, such as the Symmoriiformes, are grouped along with the modern sharks (neoselachians into a clade which is sister group of holocephalans; 2. the Symmoriiformes are related to holocephalans, whereas the other Paleozoic shark-like chondrichthyans are related to neoselachians; 3. many Paleozoic shark-like chondrichthyans, such as the Symmoriiformes, are stem chondrichthyans, whereas stem and crown holocephalans are sister group to the stem and crown neoselachians in a crown-chondrichthyan clade. This third hypothesis was proposed recently, based mainly on dental characters. METHODOLOGY/PRINCIPAL FINDINGS: On the basis of two well preserved chondrichthyan neurocrania from the Late Carboniferous of Kansas, USA, we describe here a new species of Symmoriiformes, Kawichthys moodiei gen. et sp. nov., which was investigated by means of computerized X-ray synchrotron microtomography. We present a new phylogenetic analysis based on neurocranial characters, which supports the third hypothesis and corroborates the hypothesis that crown-group chondrichthyans (Holocephali+Neoselachii form a tightly-knit group within the chondrichthyan total group, by providing additional, non dental characters. CONCLUSIONS/SIGNIFICANCE: Our results highlight the importance of new well preserved Paleozoic fossils and new techniques of observation, and suggest that a new look at the synapomorphies of the crown-group chondrichthyans would be worthwhile in terms of understanding the adaptive significance of phylogenetically important characters.

Uranium Hydrogeochemical and Stream Sediment Reconnaissance in southwestern Montana

Energy Technology Data Exchange (ETDEWEB)

Broxton, D.E.

1978-02-01

The Los Alamos Scientific Laboratory conducted a Hydrogeochemical and Stream Sediment Reconnaissance in southwestern Montana from early August to mid-October of 1976. A total of 1240 water and 1933 sediment samples were collected from 1994 locations at a nominal density of one location per 10 km/sup 2/. The water samples were collected from streams, wells, and springs; sediment samples were taken at streams and springs. All samples were analyzed at Los Alamos for total uranium by fluorometry or delayed-neutron counting. The uranium content of water samples ranges from below the detection limit (less than 0.3 ppB) to 45.30 ppB and has a mean value of 1.40 ppB. The uranium content of the sediment samples ranges between 0.20 and 206.80 ppM and averages 6.12 ppM. The chosen uranium anomaly threshold value was 7 ppB for surface waters (streams), 9 ppB for groundwaters (wells and springs), and 25 ppM for all sediment samples. The study area consists of the following lithologic groups: Precambrian basement complex, Precambrian Belt metasediments, Paleozoic and Mesozoic shelf sediments, Cretaceous and early Tertiary volcanic and plutonic rocks, Laramide orogenic clastic sediments, and middle to late Tertiary volcanic rocks and intermontane basin sediments. Most of the anomalous water and sediment samples with well-developed dispersion trains occur in areas underlain by or adjacent to silicic plutonic rocks of the Idaho and Boulder batholiths. These anomalies may indicate the presence of uraniferous veins and pegmatites similar to those already known to exist in the area. Fewer anomalous water samples occur in areas underlain by Precambrian basement complex and Tertiary basin fill.

Uranium Hydrogeochemical and Stream Sediment Reconnaissance in southwestern Montana

International Nuclear Information System (INIS)

Broxton, D.E.

1978-02-01

The Los Alamos Scientific Laboratory conducted a Hydrogeochemical and Stream Sediment Reconnaissance in southwestern Montana from early August to mid-October of 1976. A total of 1240 water and 1933 sediment samples were collected from 1994 locations at a nominal density of one location per 10 km 2 . The water samples were collected from streams, wells, and springs; sediment samples were taken at streams and springs. All samples were analyzed at Los Alamos for total uranium by fluorometry or delayed-neutron counting. The uranium content of water samples ranges from below the detection limit (less than 0.3 ppB) to 45.30 ppB and has a mean value of 1.40 ppB. The uranium content of the sediment samples ranges between 0.20 and 206.80 ppM and averages 6.12 ppM. The chosen uranium anomaly threshold value was 7 ppB for surface waters (streams), 9 ppB for groundwaters (wells and springs), and 25 ppM for all sediment samples. The study area consists of the following lithologic groups: Precambrian basement complex, Precambrian Belt metasediments, Paleozoic and Mesozoic shelf sediments, Cretaceous and early Tertiary volcanic and plutonic rocks, Laramide orogenic clastic sediments, and middle to late Tertiary volcanic rocks and intermontane basin sediments. Most of the anomalous water and sediment samples with well-developed dispersion trains occur in areas underlain by or adjacent to silicic plutonic rocks of the Idaho and Boulder batholiths. These anomalies may indicate the presence of uraniferous veins and pegmatites similar to those already known to exist in the area. Fewer anomalous water samples occur in areas underlain by Precambrian basement complex and Tertiary basin fill

Hydrogeochemical modelling of an active system of uranium fixation by organic soils and sediments (Needle's Eye, Scotland)

International Nuclear Information System (INIS)

Jamet, P.; Schmitt, J.M.; Ledoux, E.; Hooker, P.J.; Escalier des Orres, P.

1993-01-01

Uranium accumulation in organic-rich sediments can be closely modelled by assuming that the dominant effect of the uranium-organic matter interaction is the direct or indirect reduction of uranyl compounds to form U(IV) minerals, especially uraninite-pitchblende. Application of this model to the Needle's Eye (Scotland) site where uranium is actively accumulating in Quaternary sediments demonstrates that uranium accumulation is both effective and rapid in environments involving shallow, organic-rich, reducing horizons. The period of uranium deposit formation at Needle's Eye is estimated to be as short as 5000 years. The transport of uranium to the site of deposition by oxidizing groundwaters and the channelling of these oxidizing uraniferous groundwaters are identified as important factors involved in the rapid accumulation of uranium. The regional hydrogeological model indicates that a fault in the area appears to act as a hydraulic screen for the uraniferous groundwaters. On one side of the fault the Quaternary sediments are well drained whilst on the other the flow of groundwater seeps out creating a major flux just at the bottom of the organic-rich layers. The local hydrogeological model shows that the groundwater flow is vertical in this area. A third significant factor in the development of these uranium accumulations is the presence of a significant nearby source of leachable primary uranium. In the case of the Needle's Eye site this is in the form of some thirty 185 ± 20 Ma, pitchblende-bearing veins. 32 refs., 10 figs., 8 tabs

Report to the Republica Oriental del Uruguay government[Study of uranium prospection in Uruguay]; Informe al gobierno de la Republica Oriental del Uruguay

Energy Technology Data Exchange (ETDEWEB)

Saad, S

1984-07-01

This report evaluates the works of exploration of Uranium executed in the Oriental Republic of the Uruguay in the period between 1949 and 1983, with the application of geophysical, geochemical and geological methods. There was analyzed all the information relating to the works of own execution or across agreements with companies or foreign organizations. This evaluation includes visits to the principal radioactive indications, including those of the basin Paleozoic and of the Pre cambric of La Calera.

Geochemical evidence for Paleozoic crustal growth and tectonic conversion in the Northern Beishan Orogenic Belt, southern Central Asian Orogenic Belt

Science.gov (United States)

Yuan, Yu; Zong, Keqing; He, Zhenyu; Klemd, Reiner; Jiang, Hongying; Zhang, Wen; Liu, Yongsheng; Hu, Zhaochu; Zhang, Zeming

2018-03-01

The Beishan Orogenic Belt is located in the central southernmost part of the Central Asian Orogenic Belt (CAOB), which plays a key role in understanding the formation and evolution of the CAOB. Granitoids are the documents of crustal and tectonic evolution in orogenic belts. However, little is known regarding the petrogenesis and geodynamic setting of the widely distributed Paleozoic granitoids in the Northern Beishan Orogenic Belt (NBOB). The present study reveals significant differences concerning the petrogenesis and tectonic setting of early and late Paleozoic granitoids from the NBOB. The early Paleozoic granitoids from the 446-430 Ma Hongliuxia granite complex of the Mazongshan unit and the 466-428 Ma Shibanjing complex of the Hanshan unit show classic I-type granite affinities as revealed by the relative enrichment of LILEs and LREEs, pronounced depletions of Nb, Ta and Ti and the abundant presence of hornblende. Furthermore, they are characterized by strongly variable zircon εHf(t) values between - 16.7 and + 12.8 and evolved plagioclase Sr isotopic compositions of 0.7145-0.7253, indicating the involvement of both juvenile and ancient continental crust in the magma source. Thus, we propose that the early Paleozoic granitoids in the NBOB were generated in a subduction-related continental arc setting. In contrast, the late Paleozoic 330-281 Ma granitoids from the Shuangjingzi complex of the Hanshan unit exhibit positive zircon εHf(t) values between + 5.8 and + 13.2 and relatively depleted plagioclase Sr isotopic compositions of 0.7037-0.7072, indicating that they were mainly formed by remelting of juvenile crust. Thus, an intra-plate extensional setting is proposed to have occurred during formation of the late Paleozoic granitoids. Therefore, between the early and late Paleozoic, the magma sources of the NBOB granitoids converted from the reworking of both juvenile and ancient crusts during a subduction-induced compressional setting to the remelting of

Uranium potential of southwestern New Mexico (southern Hidalgo County), including observations on crystallization history of lavas and ash tuffs and the release of uranium from them. Final report

International Nuclear Information System (INIS)

Walton, A.W.; Salter, T.L.; Zetterlund, D.

1980-08-01

Geological environments present in southwestern New Mexico include thick sequences of sedimentary rock including limestone, conglomerates, sandstone, and shale: igneous intrusions with associated metal deposits; caldera centers, margins, and outflow facies; and basins with marginal faults and thick late Cenozoic sedimentary fillings. Predominant rock types are Paleozoic carbonates, Mesozoic terrigeneous rocks and carbonates, and Cenozoic volcanic rocks and basin-filling terrigeneous rocks. Consideration of information available in Preliminary Reconnaissance Reports and in Hydrogeochemical and Stream Reconnaissance Reports together with 347 new whole rock chemical analyses points to three areas of anomalous uranium abundance in Hidalgo County, New Mexico. The area has experienced three major periods of igneous activity in Phanerozoic time: one associated with the Laramide cycle of the Late Cretaceous and early Tertiary, mid-Tertiary cycle of silicic volcanism with abundant calderas, and a late Tertiary cycle of mafic volcanism. Silicic volcanic rocks are the most common exposed rock type in the area, and the most enriched in uranium (range, 0.4 to 19 ppM). The most likely source for any uranium ore-forming solutions lies with this cycle of volcanism. Solutions might have been introduced during volcanism or formed later by groundwater leaching of cooled volcanic rocks. Results indicate that groundwater leaching of cooled volcanic rocks was not an effective means of mobilizing uranium in the area. Study of several rhyolite lava flows indicates that they were emplaced in supercooled condition and may have crystallized completely at temperatures well below their liquids, or they may have warmed as crystallization released latent heat. Statistical comparison of the uranium concentration revealed no differences between vitrophyres and associated felsites

Uranium potential of southwestern New Mexico (southern Hidalgo County), including observations on crystallization history of lavas and ash tuffs and the release of uranium from them. Final report

Energy Technology Data Exchange (ETDEWEB)

Walton, A.W.; Salter, T.L.; Zetterlund, D.

1980-08-01

Geological environments present in southwestern New Mexico include thick sequences of sedimentary rock including limestone, conglomerates, sandstone, and shale: igneous intrusions with associated metal deposits; caldera centers, margins, and outflow facies; and basins with marginal faults and thick late Cenozoic sedimentary fillings. Predominant rock types are Paleozoic carbonates, Mesozoic terrigeneous rocks and carbonates, and Cenozoic volcanic rocks and basin-filling terrigeneous rocks. Consideration of information available in Preliminary Reconnaissance Reports and in Hydrogeochemical and Stream Reconnaissance Reports together with 347 new whole rock chemical analyses points to three areas of anomalous uranium abundance in Hidalgo County, New Mexico. The area has experienced three major periods of igneous activity in Phanerozoic time: one associated with the Laramide cycle of the Late Cretaceous and early Tertiary, mid-Tertiary cycle of silicic volcanism with abundant calderas, and a late Tertiary cycle of mafic volcanism. Silicic volcanic rocks are the most common exposed rock type in the area, and the most enriched in uranium (range, 0.4 to 19 ppM). The most likely source for any uranium ore-forming solutions lies with this cycle of volcanism. Solutions might have been introduced during volcanism or formed later by groundwater leaching of cooled volcanic rocks. Results indicate that groundwater leaching of cooled volcanic rocks was not an effective means of mobilizing uranium in the area. Study of several rhyolite lava flows indicates that they were emplaced in supercooled condition and may have crystallized completely at temperatures well below their liquids, or they may have warmed as crystallization released latent heat. Statistical comparison of the uranium concentration revealed no differences between vitrophyres and associated felsites.

Uranium hydrogeochemical and stream sediment reconnaissance of the Gillette NTMS quadrangle, Wyoming, including concentrations of forty-two additional elements

International Nuclear Information System (INIS)

Warren, R.G.; George, W.E.; Minor, M.M.; Simi, O.R.; Talcott, C.L.; Hensley, W.K.; Cheadle, J.M. III.

1980-08-01

During 1976 and 1977, 752 water and 843 sediment samples were collected from 1419 locations within the 17 700-km 2 area of the Gillette quadrangle, Wyoming. Water samples were collected primarily from wells, and also from springs, ponds, and streams; sediment samples were collected primarily from stream channels, and also from springs and ponds. Each water sample was analyzed for uranium and each sediment sample was analyzed for 43 elements, including uranium and thorium. Uranium concentrations in water samples range from below the detection limit of 0.02 to 212.20 ppB and have a median of 1.10 ppB. The highest background uranium concentrations, as well as the highest individual uranium values, are in areas where favorable host units for uranium mineralization crop out. These units are the Wasatch and Fort Union formations in the Powder River Basin and the Inyan Kara group in the Black Hills. Uranium concentrations in sediment samples range from 0.64 to 29.83 ppM and have a median of 3.24 ppM. Background uranium concentrations are strongly controlled by the exposed geologic unit, and range from 4 to 8 ppM for the Cretaceous Colorado group to 1 to 3 ppM for the Triassic and Paleozoic units exposed in the Black Hills. Several areas where the Wasatch and Fort Union formations are exposed exhibit uranium concentrations in sediment samples that are slightly, but distinctly, above background values for these units. All of these areas are also associated with notably high uranium concentrations in water samples. Because epigenetic uranium mineralization in economically important areas can exhibit a similar geochemical signature, these areas within the Gillette quadrangle should be further examined for the possible presence of uranium mineralization

Guangxi crustal structural evolution and the formation and distribution regularities of U-rich strata

International Nuclear Information System (INIS)

Kang Zili.

1989-01-01

Based on summing up Guangxi geotectonic features and evolutionary regularities, this paper discusses the occurrence features, formation conditions and time-space distribution regularities of various U-rich strata during the development of geosyncline, platform and diwa stages, Especially, during diwa stage all those U-rich strata might be reworked to a certain degree and resulted in the mobilization of uranium, then enriching to form polygenetic composite uranium ore deposits with stratabound features. This study will be helpful for prospecting in the region

Preparation of the pur uranium-metal; La preparation de l'uranium-metal pur

Energy Technology Data Exchange (ETDEWEB)

Goldschmidt, B.; Vertes, P. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1955-07-01

A detailed description of the chemical processes used to prepare in the factory of Bouchet of the CEA (Seine-Et-Oise) pur metal uranium with either relatively rich ores, or extracts coming of physical or chemical treatment of poor ores. The nitric treatment of ores succeeds to the production of uranate of impure sodium carbonate. This last last product is dissolved in nitric acid and the uranyl nitrate is extracted by tributyl-phosphate diluted in an inert solvent. The uranyl nitrate pure is re-extracted and successively transformed in uranium peroxide, in orange oxide then in brown oxide which is transformed in fluoride by the anhydrous hydrofluoric acid. Uranate fluoride is then reduced in metal by the pure calcium with an yield superior to 99%. (authors) [French] Description detaillee des procedes chimiques mis en jeu pour preparer a l'Usine du Bouchet du Commissariat a l'Energie Atomique (Seine-et-Oise) l'uranium metal pur a partir soit de minerais relativement riches, soit de concentres provenant de traitement physique ou chimique de minerais pauvres. Le traitement nitrique des minerais aboutit a la production d'uranate de soude impur. Ce dernier est a son tour dissous dans l'acide nitrique et le nitrate d'uranyle est extrait par du tributyl-phosphate dilue par un solvant inerte. Le nitrate d'uranyle pur reextrait est transforme successivement en peroxyde d'uranium, en oxyde orange puis en oxyde brun qui est transforme en fluorure par l'acide fluorhydrique anhydre. Le fluorure uraneux est reduit en metal par le calcium pur avec un rendement superieur a 99 %. (auteurs)

The Paleozoic ichthyofauna of the Amazonas and Parnaíba basins, Brazil

Science.gov (United States)

Figueroa, Rodrigo Tinoco; Machado, Deusana Maria da Costa

2018-03-01

The Brazilian Paleozoic ichthyofauna from the Parnaíba and Amazonas basins regard a sparsely known diversity, including chondrichthyans and acanthodians, besides some osteichthyan remains. This work proposes a revision of the fossil material from these two sedimentary basins and synthesizes the morphological aspect of such material trying to understand the influences of those fossils to the paleontology of the region, comparing the Brazilian fossils with other gondwanan faunas. The Brazilian Paleozoic fish fauna shows great resemblance to those of Bolivia, especially during the Devonian. Many of the Acanthodian spines from the Manacapuru Formation (Amazonas Basin), and the Pimenteira Formation (Parnaíba Basin), are comparable to the taxa found in Bolivia. The lack of more Placoderm remains in the Brazilian outcrops is similar to the low diversity of this group in Bolivia, when compared to other South American and Euramerican localities. The most diverse Brazilian ichthyofauna is encountered in the Permian Pedra de Fogo Formation where numerous chondrichthyans and 'paleopterygians' remains are found, together with dipnoans and actinistians. Despite the apparent lack of more representative Paleozoic ichthyofaunas in Brazil, the available material that ranges from Lower Devonian to early Permian from Brazil bears important taxa that could address valuable taxonomic and biogeographic informations.

Devonian paleomagnetism of the North Tien Shan: Implications for the middle-Late Paleozoic paleogeography of Eurasia

Science.gov (United States)

Levashova, Natalia M.; Mikolaichuk, Alexander V.; McCausland, Philip J. A.; Bazhenov, Mikhail L.; Van der Voo, Rob

2007-05-01

The Ural-Mongol belt (UMB), between Siberia, Baltica and Tarim, is widely recognized as the locus of Asia's main growth during the Paleozoic, but its evolution remains highly controversial, as illustrated by the disparate paleogeographic models published in the last decade. One of the largest tectonic units of the UMB is the Kokchetav-North Tien Shan Domain (KNTD) that stretches from Tarim in the south nearly to the West Siberian Basin. The KNTD comprises several Precambrian microcontinents and numerous remnants of Early Paleozoic island arcs, marginal basins and accretionary complexes. In Late Ordovician time, all these structures had amalgamated into a single contiguous domain. Its paleogeographic position is of crucial importance for elucidating the Paleozoic evolution of the UMB in general and of the Urals in particular. The Aral Formation, located in Kyrgyzstan in the southern part of the KNTD, consists of a thick Upper Devonian (Frasnian) basalt-andesite sequence. Paleomagnetic data show a dual-polarity characteristic component (Dec/Inc = 286° / + 56°, α95 = 9°, k = 21, N = 15 sites). The primary origin of this magnetization is confirmed by a positive test on intraformational conglomerates. We combine this result with other Paleozoic data from the KNTD and show its latitudinal motion from the Late Ordovician to the end of the Paleozoic. The observed paleolatitudes are found to agree well with the values extrapolated from Baltica to a common reference point (42.5°N, 73°E) in our sampling area for the entire interval; hence coherent motion of the KNTD and Baltica is strongly indicated for most of the Paleozoic. This finding contradicts most published models of the UMB evolution, where the KNTD is separated from Baltica by a rather wide Ural Ocean containing one or more major plate boundaries. An exception is the model of Şengör and Natal'in [A.M.C. Şengör, B.A. Natal'in, Paleotectonics of Asia: fragments of a synthesis, in: A. Yin and M. Harrison (eds

UN{sub 2−x} layer formed on uranium metal by glow plasma nitriding

Energy Technology Data Exchange (ETDEWEB)

Long, Zhong [China Academy of Engineering Physics, P.O. Box 919-71, Mianyang 621907 (China); Hu, Yin [Science and Technology on Surface Physics and Chemistry Laboratory, P.O. Box 718-35, Mianyang 621907 (China); Chen, Lin [China Academy of Engineering Physics, P.O. Box 919-71, Mianyang 621907 (China); Luo, Lizhu [Science and Technology on Surface Physics and Chemistry Laboratory, P.O. Box 718-35, Mianyang 621907 (China); Liu, Kezhao, E-mail: liukz@hotmail.com [Science and Technology on Surface Physics and Chemistry Laboratory, P.O. Box 718-35, Mianyang 621907 (China); Lai, Xinchun, E-mail: lai319@yahoo.com [Science and Technology on Surface Physics and Chemistry Laboratory, P.O. Box 718-35, Mianyang 621907 (China)

2015-01-25

Highlights: • We used a very simple method to prepare nitride layer on uranium metal surface. • This modified layer is nitrogen-rich nitride, which should be written as UN{sub 2−x}. • TEM images show the nitride layer is composed of nano-sized grains. • XPS analysis indicates there is uranium with abnormal low valence in the nitride. - Abstract: Glow plasma nitriding is a simple and economical surface treatment method, and this technology was used to prepare nitride layer on the surface of uranium metal with thickness of several microns. The composition and structure of the nitride layer were analyzed by AES and XRD, indicating that this modified layer is nitrogen-rich uranium nitride, which should be written as UN{sub 2−x}. TEM images show the nitride layer is composed of nano-sized grains, with compact structure. And XPS analysis indicates there is uranium with abnormal low valence existing in the nitride. After the treated uranium storage in air for a long time, oxygen just entered the surface several nanometers, showing the nitride layer has excellent oxidation resistance. The mechanism of nitride layer formation and low valence uranium appearance is discussed.

Isotopic tracers of gold deposition in paleozoic limestones, southern Nevada

International Nuclear Information System (INIS)

Peterman, Z.E.; Widmann, B.L.; Marshall, B.D.; Aleinikoff, J.N.; Futa, K.; Mahan, S.A.

1994-01-01

Strontium isotopic analyses of barren and mineralized Paleozoic carbonate rocks show that hydrothermal fluids added radiogenic strontium ( 87 Sr) to the mineralized zones. At Bare Mountain, samples collected from mineralized areas have δ 87 Sr t values (per mil deviation from primary marine values) ranging from +3.0 to +23.0 (mean of this log-normal distribution is +7.0), whereas unmineralized carbonate rocks have δ 87 Sr t values of -0.6 to +2.9 (mean of +1.07±1.03). In other ranges (Striped Hills, Spring Mountains, and ranges in the vicinity of Indian Springs Valley), δ 87 Sr t values of the unmineralized carbonate rocks are even lower and virtually indistinguishable from primary marine values. This correlation of elevated δ 87 Sr t values with mineralized zones provides a useful technique for assessing the mineral potential of the Paleozoic basement beneath Yucca Mountain, and may find broader use in mineral exploration in the Basin and Range province as a whole

Tectonic model for the Late Paleozoic of southeastern New England

Energy Technology Data Exchange (ETDEWEB)

Wintsch, R.P.; Sutter, J.F.

1986-07-01

Hornblende and biotite /sup 40/Ar//sup 39/Ar age spectra from rocks in south-central Connecticut help define a Permian-Triassic cooling curve for the area. Together with petrologic and structural information, a time-temperature-pressure-strain path is established. Similar data for the Narragansett basin in Rhode Island and Massachusetts allow correlation of the late Paleozoic histories of the two areas. Together, these data suggest that in the late Paleozoic, south-central New England was part of a fold-thrust belt, and the Narragansett basin was a retroarc foreland basin. NW-SE compression during the final assembly of Pangaea resulted in SE directed thrusting, causing the development of clastic wedges in adjacent Rhode Island and Massachusetts in the Late Carboniferous-Early Permian. A clockwise rotation of this deformation from NW to NNE led to northward underthrusting and concomitant uplift of both eastern Connecticut and Rhode Island in the Permian and Triassic.

Upgrade for the epithermal neutron beam at NRI Rez

International Nuclear Information System (INIS)

Marek, M.; Flibor, S.; Viererbl, L.; Burian, J.; Rejchrt, J.; Klupak, V.; Gambarini, G.; Vanossi, E.

2006-01-01

The epithermal neutron beam facility designed for pre-clinical neutron capture therapy research has been operated at LVR-15 reactor for more than ten years. The construction of the beam filter has been recently modified especially for the shielding quality of the beam shutter to be improved. The parameters of the upgraded beam were calculated with the MCNP code and a new source term for the NCTPLAN treatment planning software was evaluated. The calculated source term was consequently scaled according to the results of measurements in the free beam and in the 50x50x25 cm 3 water phantom. (author)

Aerial gamma ray and magnetic survey: Mississippi and Florida airborne survey, Nashville quadrangle, Tennessee, and Kentucky. Final report

International Nuclear Information System (INIS)

1980-09-01

The Nashville quadrangle covers a portion of the interior lowland plateau region of the Midwestern Physiographic Province. The quadrangle contains a shallow to moderately thick Paleozoic section that overlies a Precambrian basement complex. Paleozoic carbonates dominate surficial exposures. A search of available literature revealed no known uranium deposits. Fifty-five uranium anomalies were detected and are discussed briefly. Most anomalies appear to relate to cultural features. Some have relatively high uranium concentration levels that may be significant despite their correlation with culture. Magnetic data appear to illustrate complexities in the Precambrian basement

Metals other than uranium affected microbial community composition in a historical uranium-mining site.

Science.gov (United States)

Sitte, Jana; Löffler, Sylvia; Burkhardt, Eva-Maria; Goldfarb, Katherine C; Büchel, Georg; Hazen, Terry C; Küsel, Kirsten

2015-12-01

To understand the links between the long-term impact of uranium and other metals on microbial community composition, ground- and surface water-influenced soils varying greatly in uranium and metal concentrations were investigated at the former uranium-mining district in Ronneburg, Germany. A soil-based 16S PhyloChip approach revealed 2358 bacterial and 35 archaeal operational taxonomic units (OTU) within diverse phylogenetic groups with higher OTU numbers than at other uranium-contaminated sites, e.g., at Oak Ridge. Iron- and sulfate-reducing bacteria (FeRB and SRB), which have the potential to attenuate uranium and other metals by the enzymatic and/or abiotic reduction of metal ions, were found at all sites. Although soil concentrations of solid-phase uranium were high, ranging from 5 to 1569 μg·g (dry weight) soil(-1), redundancy analysis (RDA) and forward selection indicated that neither total nor bio-available uranium concentrations contributed significantly to the observed OTU distribution. Instead, microbial community composition appeared to be influenced more by redox potential. Bacterial communities were also influenced by bio-available manganese and total cobalt and cadmium concentrations. Bio-available cadmium impacted FeRB distribution while bio-available manganese and copper as well as solid-phase zinc concentrations in the soil affected SRB composition. Archaeal communities were influenced by the bio-available lead as well as total zinc and cobalt concentrations. These results suggest that (i) microbial richness was not impacted by heavy metals and radionuclides and that (ii) redox potential and secondary metal contaminants had the strongest effect on microbial community composition, as opposed to uranium, the primary source of contamination.

Epithermal neutron flux characterization of the TRIGA Mark III reactor, Salazar, Mexico, for use in Internal Neutron Activation Analysis

International Nuclear Information System (INIS)

Diaz Rizo, O.; Herrera Peraza, E.

1996-01-01

The non ideality of the epithermal neutron flux distribution at a reactor site parameter (made, using Chloramine-T method. Radiochemical purity and stability of the labelled product were determined by radiochromatography. The labelled Melagenine-II showed two radioactive fractions thermal-to-epithermal neutron ratio (f) were determined in the 3 typical irradiations positions of the TRIGA Mark III reactor of the National Nuclear Research Institute, Salazar, Mexico, using the Cd-ratio for multi monitor and bare bi-isotopic monitor methods respectively. This characterization is of use in the K o - method of neutron activation analysis, recently introduced at the Institute

The formation mechanism and prognosis on the prospect of pegmatite type uranium deposit in Eastern Qinling of China

Energy Technology Data Exchange (ETDEWEB)

Mingyue, Feng; Jiashu, Rong; Zhifu, Sun; Ziyang, Xu; Hongjie, Xie [Beijing Research Inst. of Uranium Geology (China); Qifeng, Liu [North-West of Geologic Exploration of Nuclear Industry, Xi` an (China)

1996-12-01

Lithologies of Qinling Group are composed of pelite-felsic metamorphic rocks, basic metamorphic rocks and calcareous metamorphic rocks. The Pelite-felsic metamorphic rocks account for the most part of the sequence and the bulk of the Qinling Group. The Pelite-felsic metamorphic rocks associated with uranium-hosting pegmatite are characterized by high content of SiO{sub 2} and alkali, higher content of potassium than that of sodium, and moderate content of uranium. The granites in Eastern Qinling can be divided into two genetic types, i.e. I-type and S-type. Three types of pegmatites located in the study region can be attributed to one series of unified evolution of remelting magma and are connected with each other, as well as differ from each other. They resulted from partial melting of Qinling Group. Uhosting pegmatite is the new U-hosting body. The pegmatite-type uranium deposit are of new type too. The formation of such deposit is attributed to gaseous transfer differentiation. The plate subduction of recent tectonic regime, the dome-formed granite Massif, the pegmatite vein system that resulted from the metamorphism of Qinling Group occurred in Qinling during Early Paleozoic are the main conditions for the formation of pegmatite-type uranium deposits. (5 refs., 10 tabs.).

The formation mechanism and prognosis on the prospect of pegmatite type uranium deposit in Eastern Qinling of China

International Nuclear Information System (INIS)

Feng Mingyue; Rong Jiashu; Sun Zhifu; Xu Ziyang; Xie Hongjie; Liu Qifeng

1996-12-01

Lithologies of Qinling Group are composed of pelite-felsic metamorphic rocks, basic metamorphic rocks and calcareous metamorphic rocks. The Pelite-felsic metamorphic rocks account for the most part of the sequence and the bulk of the Qinling Group. The Pelite-felsic metamorphic rocks associated with uranium-hosting pegmatite are characterized by high content of SiO 2 and alkali, higher content of potassium than that of sodium, and moderate content of uranium. The granites in Eastern Qinling can be divided into two genetic types, i.e. I-type and S-type. Three types of pegmatites located in the study region can be attributed to one series of unified evolution of remelting magma and are connected with each other, as well as differ from each other. They resulted from partial melting of Qinling Group. Uhosting pegmatite is the new U-hosting body. The pegmatite-type uranium deposit are of new type too. The formation of such deposit is attributed to gaseous transfer differentiation. The plate subduction of recent tectonic regime, the dome-formed granite Massif, the pegmatite vein system that resulted from the metamorphism of Qinling Group occurred in Qinling during Early Paleozoic are the main conditions for the formation of pegmatite-type uranium deposits. (5 refs., 10 tabs.)

Plate tectonics in the late Paleozoic

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Mathew Domeier

2014-05-01

Full Text Available As the chronicle of plate motions through time, paleogeography is fundamental to our understanding of plate tectonics and its role in shaping the geology of the present-day. To properly appreciate the history of tectonics—and its influence on the deep Earth and climate—it is imperative to seek an accurate and global model of paleogeography. However, owing to the incessant loss of oceanic lithosphere through subduction, the paleogeographic reconstruction of ‘full-plates’ (including oceanic lithosphere becomes increasingly challenging with age. Prior to 150 Ma ∼60% of the lithosphere is missing and reconstructions are developed without explicit regard for oceanic lithosphere or plate tectonic principles; in effect, reflecting the earlier mobilistic paradigm of continental drift. Although these ‘continental’ reconstructions have been immensely useful, the next-generation of mantle models requires global plate kinematic descriptions with full-plate reconstructions. Moreover, in disregarding (or only loosely applying plate tectonic rules, continental reconstructions fail to take advantage of a wealth of additional information in the form of practical constraints. Following a series of new developments, both in geodynamic theory and analytical tools, it is now feasible to construct full-plate models that lend themselves to testing by the wider Earth-science community. Such a model is presented here for the late Paleozoic (410–250 Ma together with a review of the underlying data. Although we expect this model to be particularly useful for numerical mantle modeling, we hope that it will also serve as a general framework for understanding late Paleozoic tectonics, one on which future improvements can be built and further tested.

Fission track analysis and evolution of mesozoic-paleozoic hydrocarbon resource-rocks headed in Northern Jiangsu-South Yellow sea basin

International Nuclear Information System (INIS)

Xu Hong; Cai Qianzhong; Sun Heqing; Guo Zhenxuan; Yan Guijing; Dai Jing; Liu Dongying

2008-01-01

Fission track data of different geologic epoches from Binhai salient, Yancheng sag, Haian sag, Baiju sag, Gaoyou sag, Hongze sag and Jinhu sag of northern Jiangsu basin and seismic data from Laoshan uplift in South Yellow Sea basin and evolution of Paleozoic hydrocarbon resource-rocks headed in the Northern Jiangsu-South Yellow Sea basin were studied. Results indicate that Binhai salient uplifted in 38-15 Ma, forming 'structure uplifting model', Paleozoic hydrocarbon resource-rocks have the appearance of 'different layers but identical mature, different layers but identical temperature' with Laoshan uplift. All sags have the characters of 'long time heating model', and sedimentations in Cenozoic were exploited by 2 km. Mesozoic-Paleozoic hydrocarbon resource- rocks of Laoshan uplift get ahead of 10 km. Structure evolution was compared with Binhai salient. According to the modeling results of secondary hydrocarbon generation, Mesozoic-Paleozoic hydrocarbon resource-rocks of Laoshan uplift have the good reservoir potentiality and probably become an important new window for sea oil and gas exploration. (authors)

Plant-uptake of uranium: Hydroponic and soil system studies

Science.gov (United States)

Ramaswami, A.; Carr, P.; Burkhardt, M.

2001-01-01

Limited information is available on screening and selection of terrestrial plants for uptake and translocation of uranium from soil. This article evaluates the removal of uranium from water and soil by selected plants, comparing plant performance in hydroponic systems with that in two soil systems (a sandy-loam soil and an organic-rich soil). Plants selected for this study were Sunflower (Helianthus giganteus), Spring Vetch (Vicia sativa), Hairy Vetch (Vicia villosa), Juniper (Juniperus monosperma), Indian Mustard (Brassica juncea), and Bush Bean (Phaseolus nanus). Plant performance was evaluated both in terms of the percent uranium extracted from the three systems, as well as the biological absorption coefficient (BAC) that normalized uranium uptake to plant biomass. Study results indicate that uranium extraction efficiency decreased sharply across hydroponic, sandy and organic soil systems, indicating that soil organic matter sequestered uranium, rendering it largely unavailable for plant uptake. These results indicate that site-specific soils must be used to screen plants for uranium extraction capability; plant behavior in hydroponic systems does not correlate well with that in soil systems. One plant species, Juniper, exhibited consistent uranium extraction efficiencies and BACs in both sandy and organic soils, suggesting unique uranium extraction capabilities.

Evidence for rapid epithermal mineralization and coeval bimodal volcanism, Bruner Au-Ag property, NV USA

Science.gov (United States)

Baldwin, Dylan

The character of Au-Ag mineralization and volcanic/hydrothermal relationships at the underexplored Miocene-age Bruner low-sulfidation epithermal Au-Ag deposit are elucidated using field and laboratory studies. Bruner is located in central Nevada within the Great Basin extensional province, near several major volcanic trends (Western Andesite, Northern Nevada Rift) associated with world-class Miocene-age epithermal Au-Ag provinces. Despite its proximity to several >1 Moz Au deposits, and newly discovered high-grade drill intercepts (to 117 ppm Au/1.5m), there is no published research on the deposit, the style of mineralization has not been systematically characterized, and vectors to mineralization remain elusive. By investigating the nature of mineralization and time-space relationships between volcanic/hydrothermal activity, the deposit has been integrated into a regional framework, and exploration targeting improved. Mineralization occurs within narrow quartz + adularia +/- pyrite veins that manifest as sheeted/stockwork zones, vein swarms, and rare 0.3-2 m wide veins hosted by two generations of Miocene high-K, high-silica rhyolite flow dome complexes overlying an andesite flow unit. The most prominent structural controls on veining are N­striking faults and syn-mineral basalt/rhyolite dikes. Productive veins have robust boiling indicators (high adularia content, bladed quartz after calcite, recrystallized colloform quartz bands), lack rhythmic banding, and contain only 1-2 stages; these veins overprint, or occur separately from another population of barren to weakly mineralized rhythmically banded quartz-only veins. Ore minerals consist of coarse Au0.5Ag 0.5 electrum, fine Au0.7Ag0.3 electrum, acanthite, uytenbogaardtite (Ag3AuS2) and minor embolite Ag(Br,Cl). Now deeply oxidized, veins typically contain Bruner appears to belong to a small subset of mid-Miocene epithermal deposits in Nevada with low base metal contents and low to no Se, related to calc

Late Paleozoic paleofjord in the southernmost Parana Basin (Brazil): Geomorphology and sedimentary fill

Science.gov (United States)

Tedesco, Julia; Cagliari, Joice; Coitinho, Julia dos Reis; da Cunha Lopes, Ricardo; Lavina, Ernesto Luiz Correa

2016-09-01

In the southernmost part of the Parana Basin, records of the late Paleozoic glaciation occur in a discontinuous form preserved in paleovalley systems excavated in the crystalline basement. This paper addresses one of these paleovalleys, the Mariana Pimentel, which extends over 60 km with NW-SE valley direction and a constant width of 2.5 km. With the objective of demonstrating that the paleovalley worked as a fjord during the glaciation period, its origin as well as sedimentary fill and morphology were analyzed. The paleovalley morphology was obtained through electrical resistivity (electrical sounding and lateral mapping) and mathematical modeling in four transverse sections. The morphology of the paleovalley documented by the U-shape, steady width, and high depth reaching up to 400 m are typical features of modern glacial valleys. The sedimentary facies that fill the base of the paleovalley, such as rhythmites and dropstones with thickness up to 70 m and diamictites with faceted pebbles (up to 5 m thick) are signs of its glacial origin. During the glaciation period, the paleovalley had a connection to the epicontinental sea located to the northwest, extended toward Namibia, and was excavated by glaciers from the highlands of this region. Thus, the evidence attests that the Mariana Pimentel paleovalley was a fjord during the late Paleozoic glaciation. The duration of the late Paleozoic glaciation (which is longer than the Quaternary glaciation), the apatite fission track that suggests erosion up to 4 km thick in the study area, and the lack of preserved hanging valleys in the Mariana Pimentel indicate that the paleovalley once featured a higher dimension. Furthermore, the existence of paleofjords excavated in the border of the basement corroborates the idea of small ice centers controlled by topography during the late Paleozoic glaciation.

Design of a permanent Cd-shielded epithermal neutron irradiation site in the Syrian Miniature Neutron Source Reactor

International Nuclear Information System (INIS)

Khattab, K.; Haddad, Kh.; Haj-Hassan, H.

2008-01-01

A Cd-shield (cylindrical shell 1 mm in thickness, 34 mm in diameter and 180 mm in length) was used to design a permanent epithermal neutron irradiation site for epithermal neutron activation analysis (ENAA) in the Syrian Miniature Neutron Source Reactor (MNSR). This site was achieved by shielding the surface of the aluminum tube of one of the outer irradiation sites. The calculated depression ratio of thermal neutron flux was 1/10. Homogeneity of the neutron flux in the first outer irradiation site has been found numerically using the WIMSD4 and CITATION codes and experimentally by irradiating five short copper wires using the outer irradiation capsule. Good agreement was obtained between the calculated and the measured results of the neutron flux distributions. (author)

Design of a permanent Cd-shielded epithermal neutron irradiation site in the Syrian Miniature Neutron Source Reactor

International Nuclear Information System (INIS)

Khattab, K.; Haddad, Kh.; Haj-Hassan, H.

2009-01-01

A Cd-shield (cylindrical shell 1 mm in thickness, 34 mm in diameter and 180 mm in length) was used to design a permanent epithermal neutron irradiation site for epithermal neutron activation analysis (ENAA) in the Syrian Miniature Neutron Source Reactor (MNSR). This site was achieved by shielding the surface of the aluminum tube of one of the outer irradiation sites. The calculated depression ratio of thermal neutron flux was 1/10. Homogeneity of the neutron flux in the first outer irradiation site has been found numerically using the WIMSD4 and CITATION codes and experimentally by irradiating five short copper wires using the outer irradiation capsule. Good agreement was obtained between the calculated and the measured results of the neutron flux distributions. (author)

Pore characteristics of shale gas reservoirs from the Lower Paleozoic in the southern Sichuan Basin, China

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Xianqing Li

2016-06-01

Full Text Available Data was acquired from both the drillings and core samples of the Lower Paleozoic Qiongzhusi and Longmaxi Formations' marine shale gas reservoirs in the southern Sichuan Basin by means of numerous specific experimental methods such as organic geochemistry, organic petrology, and pore analyses. Findings helped determine the characteristics of organic matter, total porosity, microscopic pore, and pore structure. The results show that the Lower Paleozoic marine shale in the south of the Sichuan Basin are characterized by high total organic carbon content (most TOC>2.0%, high thermal maturity level (RO = 2.3%–3.8%, and low total porosity (1.16%–6.87%. The total organic carbon content and thermal maturity level of the Qiongzhusi Formation shale are higher than those of the Longmaxi Formation shale, while the total porosity of the Qiongzhusi Formation shale is lower than that of the Longmaxi Formation shale. There exists intergranular pore, dissolved pore, crystal particle pore, particle edge pore, and organic matter pore in the Lower Paleozoic Qiongzhusi Formation and Longmaxi Formation shale. There are more micro-nano pores developed in the Longmaxi Formation shales than those in the Qiongzhusi Formation shales. Intergranular pores, dissolved pores, as well as organic matter pores, are the most abundant, these are primary storage spaces for shale gas. The microscopic pores in the Lower Paleozoic shales are mainly composed of micropores, mesopores, and a small amount of macropores. The micropore and mesopore in the Qiongzhusi Formation shale account for 83.92% of the total pore volume. The micropore and mesopore in the Longmaxi Formation shale accounts for 78.17% of the total pore volume. Thus, the micropores and mesopores are the chief components of microscopic pores in the Lower Paleozoic shale gas reservoirs in the southern Sichuan Basin.

Predictive geochemical modeling of uranium and other contaminants in laboratory columns in relatively oxidizing, carbonate-rich solutions

International Nuclear Information System (INIS)

Longmire, P.; Turney, W.R.; Mason, C.F.V.

1994-01-01

Carbonate heap leaching of uranium-contaminated soils and sediments represents a viable, cost-effective remediation technology. Column experiments have been conducted using 0.1, 0.25, and 0.5 M Na 2 CO 3 /NaHCO 3 solutions for leaching uranium from soils located adjacent to an incinerator at the Fernald Environmental Management Project (FEMP) site. Results from column experiments and geochemical modeling are used to quantitatively evaluate the effectiveness of heap leaching. Leach efficiencies of up to 72 wt.% of total uranium in CaO-agglomerated soil result from dissolution of uranium (U(VI)-dominated) minerals, formation of the soluble complex UO 2 (CO 3 ) 3 4- , and uranium desorption from clay minerals, ferric hydroxides, and humic acids. Parameters that control the extent of uranium extraction include pH, Eh, temperature, carbonate concentration, lixiviant-flow rate, pore-solution chemistry, solid phases, and soil texture

A mineralogical investigation of a uranium-bearing phosphatic siltstone from Tsongnapan, Northwestern Cape Province

International Nuclear Information System (INIS)

Brynard, H.J.

1980-02-01

A sample of uranium-bearing phosphatic siltstone from Tsongnapan in the Northwestern Cape Province was investigated mineralogically. The siltstone consists of cyclically alternating apatite- and calcite spherulite-rich layers. The calcite content of the rock is 11,4% and the apatite content is 42,1%. The groundmass shows the presence of the following elements: Si, Ca, P, Fe, Mg, K, Al, Cu and Zn. Detrital quartz, albite and magnetite are mainly confined to calcite spherulitic layers. The uranium content of the siltstone is 1 120 ppm U 3 O 8 and the thorium content 638 ppm ThO 2 . Both uranium and thorium occur mainly in the apatite-rich groundmass and to a minor extent in subsidiary monazite and zircon. Laboratory-scale metallurgical tests showed that the uranium is almost wholly leachable by hydrochloric acid while sulphuric and acetic acid dissolve only a small percentage of the uranium with concomitant formation of calcium sulphate. The rock probably formed in a low-energy regime in a marine environment where apatite and calcite spherulites crystallised from a possibly colloidal state [af

The mineral products of boiling in the Golden Cross epithermal deposit

International Nuclear Information System (INIS)

Simmons, S.F.; Mauk, J.L.; Simpson, M.P.

2000-01-01

The Golden Cross low sulfidation epithermal deposit shows a number of features that are directly or indirectly related to boiling hydroythermal fluids. Occurrences of lattice calcite and their quartz pseudomorph equivalents in veins, and occurrences of adularia in veins and in the surrounding altered rocks in the vicinity of ore, are direct evidence of deposition in the presence of boiling hydrothermal fluids. Loss of carbon dioxide causes calcite deposition (platy variety) near the level of first boiling, while adularia deposits due to the attendant pH increase and cooling. Indirect evidence of boiling includes crustiform-colloform quartz banding, late massive calcite veins, and clay-carbonate alteration in the shallow and peripheral parts of the ore zone. The colloform quartz banding strongly resembles the banding in amorophous silica deposits found in geothermal pipes. This implies that fluids ascending the Empire vein structure were saturated in amorphous silica. If so, then they must have undergone phase separation, which initiated at considerable depth (e.g. > or =1000 m) and very hot temperatures (e.g. > or =300 degrees C). On the basis of stable isotope data, late massive veins appear to have deposited from CO 2 -rich steam-heated waters. Calcite deposited along heating paths as these waters descended into the upflow zone during late stage collapse of the hydrothermal plume. In active systems, such steam heated waters form by deep boiling. The high CO 2 contents of these waters promote hydrolytic alteration and the formation of clay-carbonate alteration. (author). 37 refs., 4 figs

Lithological and Hydrothermal Alteration Mapping of Epithermal, Porphyry and Tourmaline Breccia Districts in the Argentine Andes Using ASTER Imagery

Directory of Open Access Journals (Sweden)

Francisco J. Testa

2018-01-01

Full Text Available The area of interest is located on the eastern flank of the Andean Cordillera, San Juan province, Argentina. The 3600 km2 area is characterized by Siluro-Devonian to Neogene sedimentary and igneous rocks and unconsolidated Quaternary sediments. Epithermal, porphyry-related, and magmatic-hydrothermal breccia-hosted ore deposits, common in this part of the Frontal Cordillera, are associated with various types of hydrothermal alteration assemblages. Kaolinite – alunite-rich argillic, quartz – illite-rich phyllic, epidote – chlorite – calcite-rich propylitic and silicic are the most common hydrothermal alteration assemblages in the study area. VNIR, SWIR and TIR ASTER data were used to characterize geological features on a portion of the Frontal Cordillera. Red-green-blue band combinations, band ratios, logical operations, mineral indices and principal component analysis were applied to successfully identify rock types and hydrothermal alteration zones in the study area. These techniques were used to enhance geological features to contrast different lithologies and zones with high concentrations of argillic, phyllic, propylitic alteration mineral assemblages and silicic altered rocks. Alteration minerals detected with portable short-wave infrared spectrometry in hand specimens confirmed the capability of ASTER to identify hydrothermal alteration assemblages. The results from field control areas confirmed the presence of those minerals in the areas classified by ASTER processing techniques and allowed mapping the same mineralogy where pixels had similar information. The current study proved ASTER processing techniques to be valuable mapping tools for geological reconnaissance of a large area of the Argentinean Frontal Cordillera, providing preliminary lithologic and hydrothermal alteration maps that are accurate as well as cost and time effective.

The features of the isotope composition of carbon in the Paleozoic and Mesozoic oils of Western Siberia

Energy Technology Data Exchange (ETDEWEB)

Golyshev, S.I.; Lebedena, L.V.

1984-01-01

The isotope composition of the carbon in the oils from the Mesozoic and Paleozoic deposits is measured. The variations in the isotope composition of carbon for the Paleozoic oils is between 27.5 and 30.8 percent, while for the oils from the lower Jurassic and Triassic levels it is between 27.7 and 31.2 percent and for the upper Jurassic oils it is between 30.1 and 34.5 percent. The dependence of the isotope composition of the carbon in the oils on the type of original organic matter and its metamorphosis conditions during lithogenesis is analyzed. A softening in the isotope composition of the carbon in the oils from the oceanic deposits relative to continental deposits is found, together with a genetic individualism of the oils from the Paleozoic deposits and their difference from the oils in the Mesozoic deposits.

The geochemical characteristics of alkali metasomatic ore and its ore-forming significance at Zoujiashan deposit, Xiangshan uranium field

International Nuclear Information System (INIS)

Wang Yun; Hu Baoqun; Sun Zhanxue; Li Xueli; Guo Guolin; Rao Minghui

2012-01-01

Alkaline metasomatites are widely distributed in Zoujiashan uranium deposit and have close relation with uranium mineralization. Based on the study of field geological survey, petrographic methods, element chemical analysis and EPMA, etc, the alteration in alkaline metasomatic ore was found in the order of sodium metasomatism, potassium metasomatism and silica metasomatism. The alkaline hydrothermal fluid of mineralization is rich in Na at first and then rich in K, and quite similar in other chemical composition, but the K rich one is more favourite for the metallization. Compared with the normal porphyroclastic lava, the alkaline metasomatic ores in lower in SiO 2 , but higher in K 2 O or Na 2 O, Al 2 O 3 , Fe 2 O 3 , MgO, P 2 O 5 , CaO and U, Th, Zr, Hf, Sm, Ti, REE. Compared with potassium metasomatic ore, the sodium metasomatic ore is with high ΣLREE/ΣHREE ratio and lower Rb and REE. Because alkaline metasomatism is beneficial to release uranium from accessory mineral and bring out uranium from rocks, therefore it is very important to the migration and precipitation of uranium. (authors)

Late paleozoic fusulinoidean gigantism driven by atmospheric hyperoxia.

Science.gov (United States)

Payne, Jonathan L; Groves, John R; Jost, Adam B; Nguyen, Thienan; Moffitt, Sarah E; Hill, Tessa M; Skotheim, Jan M

2012-09-01

Atmospheric hyperoxia, with pO(2) in excess of 30%, has long been hypothesized to account for late Paleozoic (360-250 million years ago) gigantism in numerous higher taxa. However, this hypothesis has not been evaluated statistically because comprehensive size data have not been compiled previously at sufficient temporal resolution to permit quantitative analysis. In this study, we test the hyperoxia-gigantism hypothesis by examining the fossil record of fusulinoidean foraminifers, a dramatic example of protistan gigantism with some individuals exceeding 10 cm in length and exceeding their relatives by six orders of magnitude in biovolume. We assembled and examined comprehensive regional and global, species-level datasets containing 270 and 1823 species, respectively. A statistical model of size evolution forced by atmospheric pO(2) is conclusively favored over alternative models based on random walks or a constant tendency toward size increase. Moreover, the ratios of volume to surface area in the largest fusulinoideans are consistent in magnitude and trend with a mathematical model based on oxygen transport limitation. We further validate the hyperoxia-gigantism model through an examination of modern foraminiferal species living along a measured gradient in oxygen concentration. These findings provide the first quantitative confirmation of a direct connection between Paleozoic gigantism and atmospheric hyperoxia. © 2012 The Author(s). Evolution© 2012 The Society for the Study of Evolution.

Conceptual design of 30 MeV magnet system used for BNCT epithermal neutron source

International Nuclear Information System (INIS)

Slamet Santosa; Taufik

2015-01-01

Conceptual design of 30 MeV Magnet System Used for BNCT Epithermal Neutron Source has been done based on methods of empirical model of basic equation, experiences of 13 MeV cyclotron magnet design and personal communications. In the field of health, cyclotron can be used as an epithermal neutron source for Boron Neutron Capture Therapy (BNCT). The development of cyclotron producing epithermal neutrons for BNCT has been performed at Kyoto University, of which it produces a proton beam current of 1.1 mA with energy of 30 MeV. With some experiences on 13 MeV cyclotron magnet design, to support BNCT research and development we performed the design studies of 30 MeV cyclotron magnet system, which is one of the main components of the cyclotron for deflecting proton beam into circular trajectory and serves as beam focusing. Results of this study are expected to define the parameters of particular cyclotron magnet. The scope of this study includes the study of the parameters component of the 30 MeV cyclotron and magnet initial parameters. The empirical method of basic equation model is then corroborated by a simulation using Superfish software. Based on the results, a 30 MeV cyclotron magnet for BNCT neutron source enables to be realized with the parameters of B 0 = 1.06 T, frequency RF = 64.733938 ≈ 65 MHz, the external radius of 0.73 m, the radius of the polar = 0.85 m, BH = 1.95 T and a gap hill of 4 cm. Because proton beam current that be needed for BNCT application is very large, then in the calculation it is chosen a great focusing axial νz = 0.630361 which can generate B V = 0.44 T. (author)

Application of chronocoulomentry for trace levels uranium determination using catalytic nitrate reduction on mercury electrode

International Nuclear Information System (INIS)

Cantagallo, M.I.C.

1988-01-01

With the aim of improving the sensitivity of the electro-analytical determination of uranium at trace levels, the uranium catalyzed reduction of nitrate on mercury electrodes was used and the technique of chronocoulometry was compared with other voltammetric techniques. The catalytic process offers high sensitivity in comparison with uranyl reduction in absence of nitrate. The chronocoulometry, virtually unexplored for analytical applications, was found to be specially well suited for determinations based on this kind of electrode process, when using current integration times in the range of several seconds. Under these conditions the interference from diffusion controlled faradaic processes is reduced to a minimum. Several experimental parameters were investigated (eletrolyte composition, potential program, integration time, blank correction, temperature, previous separation) and adequate conditions were selected for the analytical determination of pure and real samples. The proposed method was applied and evaluated with real and, when necessary, an adapted liquid-liquid extraction procedure was used. Reference materials with complex matrices like rocks were first solubilized by hot digestion under pressure. The obtained results are in good agreement with the values obtained with other techniques such as X-ray fluorescence, mass spectrometry-isotope dilution and epithermal netron activation analysis. (author) [pt

Uranium from seawater

International Nuclear Information System (INIS)

Gregg, D.; Folkendt, M.

1982-01-01

A novel process for recovering uranium from seawater is proposed and some of the critical technical parameters are evaluated. The process, in summary, consists of two different options for contacting adsorbant pellets with seawater without pumping the seawater. It is expected that this will reduce the mass handling requirements, compared to pumped seawater systems, by a factor of approximately 10 5 , which should also result in a large reduction in initial capital investment. Activated carbon, possibly in combination with a small amount of dissolved titanium hydroxide, is expected to be the preferred adsorbant material instead of the commonly assumed titanium hydroxide alone. The activated carbon, after exposure to seawater, can be stripped of uranium with an appropriate eluant (probably an acid) or can be burned for its heating value (possible in a power plant) leaving the uranium further enriched in its ash. The uranium, representing about 1% of the ash, is then a rich ore and would be recovered in a conventional manner. Experimental results have indicated that activated carbon, acting alone, is not adequately effective in adsorbing the uranium from seawater. We measured partition coefficients (concentration ratios) of approximately 10 3 in seawater instead of the reported values of 10 5 . However, preliminary tests carried out in fresh water show considerable promise for an extraction system that uses a combination of dissolved titanium hydroxide (in minute amounts) which forms an insoluble compound with the uranyl ion, and the insoluble compound then being sorbed out on activated carbon. Such a system showed partition coefficients in excess of 10 5 in fresh water. However, the system was not tested in seawater

Uranium: War, Energy and the Rock That Shaped the World; Uranium: la biographie

Energy Technology Data Exchange (ETDEWEB)

Zoellner, T.

2009-07-01

Having traveled extensively through the savannah of Africa, the mountains of Eastern Europe, and the deserts of Utah, the author delves into the complex science, politics and history of uranium, which presents the best and worst of mankind: the capacity for scientific progress and political genius; the capacity for nihilism, exploitation, and terror. Because the author covers so much ground, from the discovery of radioactivity, through the development of the atomic bomb, he does not go into great depth on any one topic. Nonetheless, he paints vivid pictures of uranium's impact, including forced labor in Soviet mines and lucky prospectors who struck it rich in harsh environments, the spread of uranium smuggling, as well as an explanation of why it was absurd to claim that Saddam Hussein was attempting to purchase significant quantities of uranium from Niger. The only shortcoming is the author's omission of the issue of radioactive wastes generated by nuclear power. The author knows well what uranium looks like, why peril pulses in its every atom, and how scientists exploit its nuclear volatility. The drama is found in the weaponry uranium has spawned as demonstrated at Hiroshima and Nagasaki. In pursuit of this raw power, the U.S. let Navajos die extracting needed ore and let southwestern cities sicken beneath clouds from reckless testing. The Soviet Union sentenced tens of thousands to lethal gulag mines. Israel diverted ore through deception on the high seas. Pakistan stole European refining technology. Alive with devious personalities, the author's narrative ultimately exposes the frightening vulnerability of a world with too many sources of a dangerous substance and too little wisdom to control it

Hydrothermal uranium vein deposits in Marysvale volcanic field, Utah

International Nuclear Information System (INIS)

Rasmussen, J.D.; Cunningham, C.G.; Steven, T.A.; Rye, R.O.; Romberger, S.B.

1984-01-01

Hydrothermal uranium veins are exposed over a 300 m (980 ft) vertical range in mines of the Central Mining area, near Marysvale, Utah. They cut 23 Ma quartz monzonite, 21 Ma granite, and 19 Ma rhyolite ash-flow tuff. The veins formed 18-19 Ma, in an area 1 km (0.6 mi) across, above the center of a composite magma chamber at least 12 x 6 km across that fed a sequence of 21-14 Ma hypabyssal granitic stocks, and rhyolitic lava flows, ash-flow tuffs, and volcanic domes. Intrusive pressure uplifted and fractured the roof; molybdenite-bearing, uranium-rich glassy dikes were intruded; and a breccia pipe and uranium-bearing veins were formed. The veins appear to have been deposited near the surface above a concealed rhyolite stock, where they filled high-angle fault zones and flat-lying to concave-downward pull-apart fractures. Low pH and fO 2 hydrothermal fluids at temperatures near 200 0 C (392 0 F) permeated the fractured rocks; these fluids were rich in fluorine and potassium, and contained uranium as uranous-fluoride complexes. Fluid-wall rock interaction increased fluid pH, causing precipitation of uranium minerals. At the deepest exposed levels, wall rocks were altered to kaolinite and sericite, and uraninite, coffinite, jordisite, fluorite, molybdenite, quartz, and pyrite (with delta 34 S near zero per mil) were deposited. The fluids were progressively oxidized higher in the system; iron in the wall rocks was oxidized to hematite, and sooty uraninite and umohoite were deposited

Lower Paleozoic carbonate rocks of Baird Mountains Quadrangle, Alaska

Energy Technology Data Exchange (ETDEWEB)

Dumoulin, J.A.; Harris, A.G.

1985-04-01

Lower Paleozoic carbonate rocks in the Baird Mountains quadrangle form a relatively thin (about 550 m), chiefly shallow-water succession that has been imbricately thrust and metamorphosed to lower greenschist facies. Middle and Upper Cambrian rocks - the first reported from the western Brooks Range - occur in the northeastern quarter of the quadrangle, south of Angayukaqsraq (formerly Hub) Mountain. They consist of marble grading upward into thin-bedded marble/dolostone couplets and contain pelagiellid mollusks, acetretid brachiopods, and agnostid trilobites. Sedimentologic features and the Pelagiellas indicate a shallow-water depositional environment. Overlying these rocks are Lower and Middle Ordovician marble and phyllite containing graptolites and conodonts of midshelf to basinal aspect. Upper Ordovician rocks in this area are bioturbated to laminated dolostone containing warm, shallow-water conodonts. In the Omar and Squirrel Rivers areas to the west, the Lower Ordovician carbonate rocks show striking differences in lithofacies, biofacies, and thickness. Here they are mainly dolostone with locally well-developed fenestral fabric and evaporite molds, and bioturbated to laminated orange- and gray-weathering dolomitic marble. Upper Silurian dolostone, found near Angayukaqsraq Mountain and on the central Squirrel River, contains locally abundant corals and stronmatoporoids. Devonian carbonate rocks are widely distributed in the Baird Mountains quadrangle; at least two distinct sequences have been identified. In the Omar area, Lower and Middle Devonian dolostone and marble are locally cherty and rich in megafossils. In the north-central (Nakolik River) area, Middle and Upper Devonian marble is interlayered with planar to cross-laminated quartz-carbonate metasandstone and phyllite.

The chemical industry of uranium in France; L'industrie chimique de l'uranium en France

Energy Technology Data Exchange (ETDEWEB)

Goldschmidt, B [Commissariat a l' Energie Atomique, Paris (France). Centre d' Etudes Nucleaires

1955-07-01

The actual CEA program is concerned with the construction of two large graphite reactors, each of those containing at least one hundred tons of uranium metal with nuclear purity. The uranium for these two reactors will be regularly supplied by new resources discovered in France and Madagascar in the last five years. The working and treatment of such ore have led to the creation of an important french industry of which the general outline and principle are described. The operated ores have got different natures and concentration, individual characteristics are described for the main ores.The most high-grade ore are transported to a central plant in Bouchet near Paris; the low-grade ore are concentrated by physical methods or chemical processes of which principles and economy are studied with constancy. The acid processes are the only used until now, although the carbonated alkaline processes has been studied in France. The next following steps after the acid process until the obtention of uranium rich concentrate are described. The purification steps of uranium compounds to nuclear purity material are described as well as the steps to elaborate metal of which the purity grade will be specify. Finally, the economic aspects of uranium production difficulty will be considered in relation with technical progresses which we can expect to achieve in the future. (M.P.)

Changes in the artificial thermoluminescence glow curves of quartz associated with uranium deposits

Energy Technology Data Exchange (ETDEWEB)

Hochman, M.B.M.; Ypma, P.J.M.

1988-01-01

Previous laboratory-based studies have shown that quartz thermoluminescence (TL) glow curves change in intensity and shape in response to large radiation doses. Initially, low temperature peaks are sensitized though at gamma doses of greater than 10/sup 5/ - 10/sup 6/ kGy desensitization occurs. This study has examined the change in artificial TL in quartz at various distances from a uranium deposit. Such quartz has been subjected to varying palaeoradiation doses in a natural uranium rich environment. Quartz from an uranium rich environment shows that the 130/sup 0/C glow peak is the dominant glow peak in background radiation environments, though this peak decreases with increasing palaeoradiation dose. At doses greater than 10/sup 5/-10/sup 6/ kGy the 350/sup 0/C glow peak is the dominant glow peak in these quartz samples. An increase in E'/sub 1/ centre concentration also occurs from the least radiation affected sample to the most radiation affected sample. These results suggest that artificial TL is useful in uranium exploration.

Metrology and quality of radiation therapy dosimetry of electron, photon and epithermal neutron beams

Energy Technology Data Exchange (ETDEWEB)

Kosunen, A

1999-08-01

In radiation therapy using electron and photon beams the dosimetry chain consists of several sequential phases starting by the realisation of the dose quantity in the Primary Standard Dosimetry Laboratory and ending to the calculation of the dose to a patient. A similar procedure can be described for the dosimetry of epithermal neutron beams in boron neutron capture therapy (BNCT). To achieve the required accuracy of the dose delivered to a patient the quality of all steps in the dosimetry procedure has to be considered. This work is focused on two items in the dosimetry chains: the determination of the dose in the reference conditions and the evaluation of the accuracy of dose calculation methods. The issues investigated and discussed in detail are: a)the calibration methods of plane parallel ionisation chambers used in electron beam dosimetry, (b) the specification of the critical dosimetric parameter i.e. the ratio of stopping powers for water to air, (S I ?){sup water} {sub air}, in photon beams, (c) the feasibility of the twin ionization chamber technique for dosimetry in epithermal neutron beams applied to BNCT and (d) the determination accuracy of the calculated dose distributions in phantoms in electron, photon, and epithermal neutron beams. The results demonstrate that up to a 3% improvement in the consistency of dose determinations in electron beams is achieved by the calibration of plane parallel ionisation chambers in high energy electron beams instead of calibrations in {sup 60}Co gamma beams. In photon beam dosimetry (S I ?){sup water} {sub air} can be determined with an accuracy of 0.2% using the percentage dose at the 10 cm depth, %dd(10), as a beam specifier. The use of %odd(10) requires the elimination of the electron contamination in the photon beam. By a twin ionisation chamber technique the gamma dose can be determined with uncertainty of 6% (1 standard deviation) and the total neutron dose with an uncertainty of 15 to 20% (1 standard deviation

Metrology and quality of radiation therapy dosimetry of electron, photon and epithermal neutron beams

International Nuclear Information System (INIS)

Kosunen, A.

1999-08-01

In radiation therapy using electron and photon beams the dosimetry chain consists of several sequential phases starting by the realisation of the dose quantity in the Primary Standard Dosimetry Laboratory and ending to the calculation of the dose to a patient. A similar procedure can be described for the dosimetry of epithermal neutron beams in boron neutron capture therapy (BNCT). To achieve the required accuracy of the dose delivered to a patient the quality of all steps in the dosimetry procedure has to be considered. This work is focused on two items in the dosimetry chains: the determination of the dose in the reference conditions and the evaluation of the accuracy of dose calculation methods. The issues investigated and discussed in detail are: a)the calibration methods of plane parallel ionisation chambers used in electron beam dosimetry, (b) the specification of the critical dosimetric parameter i.e. the ratio of stopping powers for water to air, (S I ?) water air , in photon beams, (c) the feasibility of the twin ionization chamber technique for dosimetry in epithermal neutron beams applied to BNCT and (d) the determination accuracy of the calculated dose distributions in phantoms in electron, photon, and epithermal neutron beams. The results demonstrate that up to a 3% improvement in the consistency of dose determinations in electron beams is achieved by the calibration of plane parallel ionisation chambers in high energy electron beams instead of calibrations in 60 Co gamma beams. In photon beam dosimetry (S I ?) water air can be determined with an accuracy of 0.2% using the percentage dose at the 10 cm depth, %dd(10), as a beam specifier. The use of %odd(10) requires the elimination of the electron contamination in the photon beam. By a twin ionisation chamber technique the gamma dose can be determined with uncertainty of 6% (1 standard deviation) and the total neutron dose with an uncertainty of 15 to 20% (1 standard deviation). To improve the accuracy

Transpassive electrodissolution of depleted uranium in alkaline electrolytes

International Nuclear Information System (INIS)

Weisbrod, K.R.; Schake, A.R.; Morgan, A.N.; Purdy, G.M.; Martinez, H.E.; Nelson, T.O.

1998-03-01

To aid in removal of oralloy from the nuclear weapons stockpile, scientists at the Los Alamos National Laboratory Plutonium Facility are decontaminating oralloy parts by electrodissolution in neutral to alkaline electrolytes composed of sodium nitrate and sodium sulfate. To improve the process, electrodissolution experiments were performed with depleted uranium to understand the effects of various operating parameters. Sufficient precipitate was also produced to evaluate the feasibility of using ultrafiltration to separate the uranium oxide precipitates from the electrolyte before it enters the decontamination fixture. In preparation for the experiments, a potential-pH diagram for uranium was constructed from thermodynamic data for fully hydrated species. Electrodissolution in unstirred solutions showed that uranium dissolution forms two layers, an acidic bottom layer rich in uranium and an alkaline upper layer. Under stirred conditions results are consistent with the formation of a yellow precipitate of composition UO 3 ·2H 2 O, a six electron process. Amperometric experiments showed that current efficiency remained near 100% over a wide range of electrolytes, electrolyte concentrations, pH, and stirring conditions

The Stypsi-Megala Therma porphyry-epithermal mineralization, Lesvos Island, Greece: new mineralogical and geochemical data

Science.gov (United States)

Periferakis, Argyrios; Voudouris, Panagiotis; Melfos, Vasilios; Mavrogonatos, Constantinos; Alfieris, Dimitrios

2017-04-01

Lesvos Island is located at the NE part of the Aegean Sea and mostly comprises post-collisional Miocene volcanic rocks of shoshonitic to calc-alkaline geochemical affinities. In the northern part of the Island, the Stypsi Cu-Mo±Au porphyry prospect, part of the Stypsi caldera, is hosted within hydrothermally altered intrusives and volcanics [1]. Porphyry-style mineralization is developed in a microgranite porphyry that has intruded basaltic trachyandesitic lavas. Propylitic alteration occurs distal to the mineralization, whereas sodic-calcic alteration related to quartz-actinolite veinlets, and a phyllic overprint associated with a dense stockwork of banded black quartz±carbonate veinlets, characterizes the core of the system. Alunite-kaolinite advanced argillic alteration occurs at higher topographic levels and represents a barren lithocap to the porphyry mineralization. Intermediate-sulfidation (IS) milky quartz-carbonate veins overprint the porphyry mineralization along a NNE-trending fault that extends further northwards to Megala Therma, where it hosts IS base metal-rich Ag-Au mineralization [2]. New mineralogical data from the Megala Therma deposit suggest Ag-famatinite, Te-polybasite and Ag-tetrahedrite as the main carriers of Ag in the mineralization. Porphyry-style ores at Stypsi consist of magnetite postdated by pyrite and then by chalcopyrite, molybdenite, sphalerite, galena and bismuthinite within the black quartz stockworks or disseminated in the wallrock [1]. The dark coloration of quartz in the veinlets is due to abundant vapor-rich fluid inclusions. Quartz is granular and fine-grained and locally elongated perpendicular to the vein walls. Botryoidal textures are continuous through quartz grains, suggesting quartz recrystallization from a silica gel, a feature already described by [3] from banded quartz veinlets in porphyry Au deposits at Maricunga, Chile. Bulk ore analyses from porphyry-style mineralization at Stypsi displayed similar geochemical

Varieties of granitic uranium deposits and favorable exploration areas in the eastern United States

International Nuclear Information System (INIS)

Rogers, J.J.W.; Ragland, P.C.; Nishimori, R.K.; Greenberg, J.K.; Hauck, S.A.

1978-01-01

This paper is divided into three parts. First is an overview of the basic igneous processes that cause concentration of uranium and the types of rocks in which these deposits are most likely to occur. Second is a discussion of the source of uranium and the tectonic environments in which uranium-rich igneouos rocks are likely to form. Third is an application of these principles to the delineation of favorable belts for uranium exploration in crystalline rocks in the eastern United States. The paper is restricted to a discussion of those deposits in which high-uranium concentrations are caused by magmatic processes. 114 refs

The Neutron Spectrum in a Uranium Tube

International Nuclear Information System (INIS)

Johansson, E.; Jonsson, E.; Lindberg, M.; Mednis, J.

1963-10-01

A series of experimental and theoretical investigations on neutron spectra in lattice cells has been started at the reactor R1. This report gives the results from the first one of these cells - one with a tube of natural -uranium surrounded by heavy water. In the measurements the cell was placed in the central, vertical channel of the reactor. The neutron spectrum from a lead scatterer in the uranium tube - outer diameter 49.2 mm, inner diameter 28.3 mm - was measured with a fast chopper in the energy region 0.01 to 100 eV. Subsidiary measurements indicated that the spectrum in the beam from the lead piece corresponds to the spectrum of the angular flux integrated over all angles. This correspondence is important for the interpretation of the experimental data. The thermal part of the spectrum was found to deviate significantly from a Maxwellian. However, the deviation is not very large, and one could use a Maxwellian, at least to give a rough idea of the hardness of the spectrum. For the present tube the temperature of this Maxwellian was estimated as 90 to 100 deg C above the moderator temperature (33 deg C). In the joining region the rise of the spectrum towards the thermal part is slower than for the cell boundary spectrum, measured earlier. In the epithermal region the limited resolution of the chopper has affected the measurements at the energies of the uranium resonances. However, the shape of the spectrum on the flanks of the first resonance in 238 U (6.68 eV) has been obtained accurately. In the theoretical treatment the THERMOS code with a free gas scattering model has been used. The energy region was 3.06 - 0.00025 eV. The agreement with the measurements is good for the thermal part - possibly the theoretical spectrum is a little softer than the experimental one. In the joining region the results from THERMOS are comparatively high - probably due to the scattering model used

The Neutron Spectrum in a Uranium Tube

Energy Technology Data Exchange (ETDEWEB)

Johansson, E; Jonsson, E; Lindberg, M; Mednis, J

1963-10-15

A series of experimental and theoretical investigations on neutron spectra in lattice cells has been started at the reactor R1. This report gives the results from the first one of these cells - one with a tube of natural -uranium surrounded by heavy water. In the measurements the cell was placed in the central, vertical channel of the reactor. The neutron spectrum from a lead scatterer in the uranium tube - outer diameter 49.2 mm, inner diameter 28.3 mm - was measured with a fast chopper in the energy region 0.01 to 100 eV. Subsidiary measurements indicated that the spectrum in the beam from the lead piece corresponds to the spectrum of the angular flux integrated over all angles. This correspondence is important for the interpretation of the experimental data. The thermal part of the spectrum was found to deviate significantly from a Maxwellian. However, the deviation is not very large, and one could use a Maxwellian, at least to give a rough idea of the hardness of the spectrum. For the present tube the temperature of this Maxwellian was estimated as 90 to 100 deg C above the moderator temperature (33 deg C). In the joining region the rise of the spectrum towards the thermal part is slower than for the cell boundary spectrum, measured earlier. In the epithermal region the limited resolution of the chopper has affected the measurements at the energies of the uranium resonances. However, the shape of the spectrum on the flanks of the first resonance in {sup 238}U (6.68 eV) has been obtained accurately. In the theoretical treatment the THERMOS code with a free gas scattering model has been used. The energy region was 3.06 - 0.00025 eV. The agreement with the measurements is good for the thermal part - possibly the theoretical spectrum is a little softer than the experimental one. In the joining region the results from THERMOS are comparatively high - probably due to the scattering model used.

Processing of uranium-containing coal

International Nuclear Information System (INIS)

Cordero Alvarez, M.

1987-01-01

A direct storage of uranium-bearing coal requires the processing of large amounts of raw materials while lacking guarantee of troublefree process cycles. With the example of an uranium-bearing bituminous coal from Stockheim, it was aimed at the production of an uranium ore concentrate by means of mechanical, thermal and chemical investigations. Above all, amorphous pitch blende was detected as a uranium mineralization which occurs homogeneously distributed in the grain size classes of the comminuted raw material with particle diameters of a few μm and, after the combustion, enriches in the field of finest grain of the axis. Heterogeneous and solid-state reactions in the thermal decarburization above 700deg C result in the development of hardly soluble uranium oxides and and calcium uranates as well as in enclosures in mineral glass. Thus, the pre-enrichment has to take place in a temperature range below 600deg C. By means of a sorting classification of the ash at ± 2.0 mm, it is possible to achieve an enrichment of up to factor 15 for a mineral of a mainly low carbonate content and, for a mineral of a rich carbonate content, up to the factor 4. The separation of the uranium from the concentrates produced is possible with a yield of 95% by means of leaching with sulphuric acid at a temperature of 20deg C. As far as their reproducibility was concerned, the laboratory tests were verified on a semi-industrial scale. A processing method is suggested on the basis of the data obtained. (orig.) [de

Lawrence Livermore Laboratory concept for uranium recovery from seawater

International Nuclear Information System (INIS)

Gregg, D.; Wang, F.

1980-01-01

The Lawrence Livermore Laboratory concept for uranium recovery from seawater involves the following process steps: (1) produce activated carbon via a coal gasification plant; (2) contact activated carbon sorbent with seawater using a settling process (no pumping of seawater); (3) vacuum activated carbon from sea floor; (4) gasify or burn activated carbon (further concentrating the uranium in the ash); (5) extract the uranium from the rich ash ore by conventional techniques. The process advantages are: (1) eliminates seawater pumping, the need for an illuent, and the need for a fresh water wash; (2) should result in much lower capital investment and regional process energy. Major process issues are: (1) uranium loading on activated carbon; (2) activated carbon modifications required to improve the sorbtion performance; (3) activated carbon particle size needed to meet system requirements; (4) minimization of sorbent losses when contacted with seawater

The role of uranium-arene bonding in H2O reduction catalysis

Science.gov (United States)

Halter, Dominik P.; Heinemann, Frank W.; Maron, Laurent; Meyer, Karsten

2018-03-01

The reactivity of uranium compounds towards small molecules typically occurs through stoichiometric rather than catalytic processes. Examples of uranium catalysts reacting with water are particularly scarce, because stable uranyl groups form that preclude the recovery of the uranium compound. Recently, however, an arene-anchored, electron-rich uranium complex has been shown to facilitate the electrocatalytic formation of H2 from H2O. Here, we present the precise role of uranium-arene δ bonding in intermediates of the catalytic cycle, as well as details of the atypical two-electron oxidative addition of H2O to the trivalent uranium catalyst. Both aspects were explored by synthesizing mid- and high-valent uranium-oxo intermediates and by performing comparative studies with a structurally related complex that cannot engage in δ bonding. The redox activity of the arene anchor and a covalent δ-bonding interaction with the uranium ion during H2 formation were supported by density functional theory analysis. Detailed insight into this catalytic system may inspire the design of ligands for new uranium catalysts.

Ore deposits and epithermal evidences associated with intra-magmatic faults at Aïn El Araâr-Oued Belif ring structure (NW of Tunisia)

Science.gov (United States)

Aissa, Wiem Ben; Aissa, Lassaâd Ben; Amara, Abdesslem Ben Haj; Tlig, Said; Alouani, Rabah

2017-03-01

Hydrothermal ore deposits at Aïn El Araâr-Oued Belif location are classified as epithermal deposits type. The ore bodies are hosted by upper Turonian (8-9 M.y) volcanic rhyodacitic complex. Polymetallic sulfide orebodies are mainly concentrated within intra-magmatic faults. Petrographic, XRD, and TEM-STEM investigations revealed that ore minerals are essentially, arsenopyrite, pyrite, chalcopyrite, pyrrhotite, hematite, goethite and magnetite with Au, Ag and Pt trace metals. Gangue minerals are mainly adularia, quartz, sericite, alunite, tridymite, chlorite, phlogopite and smectite. Epithermal alteration is well zoned with four successive characteristic zones: (1) zone of quartz-adularia-sericite and rare alunite; (2) zone of kaolinite and plagioclase albitization; (3) intermediate zone of illite-sericite; (4) sapropelic alteration type zone of chlorite-smectite and rare illite. This can be interpreted as a telescoping of two different acidity epithermal phases; low sulfidation (adularia-sericite) and high sulfidation (quartz-alunite), separated in time or due to a gradual increase of fluids acidity and oxicity within the same mineralization phase. Brecciated macroscopic facies with fragments hosting quartz-adularia-sericite minerals (low-sulfidation phase) without alunite, support the last hypothesis. Geodynamic context and mineral alteration patterns are closely similar to those of Maria Josefa gold mine at SE of Spain which exhibit a volcanic-hosted epithermal ore deposit in a similar vein system, within rhyolitic ignimbrites, altered to an argillic assemblage (illite-sericite abundant and subordinate kaolinite) that grades outwards into propylitic alteration (Sanger-von Oepen et al. (1990)). Mineralogical and lithologic study undertaken in the volcanic host rock at Aïn El Araâr-Oued Belif reveals a typical epithermal low-sulfidation and high-sulfidation ore deposits with dominance of low-sulfidation. Host rocks in these systems range from silicic to

Chapter 3. Classical method of uranium leaching from ores and reasons for incomplete recovery at dumps of State Enterprise 'VOSTOKREDMET'. 3.3. Basic regularities of uranium ores leaching

International Nuclear Information System (INIS)

Khakimov, N.; Nazarov, Kh.M.; Mirsaidov, I.U.

2012-01-01

Present article is devoted to basic regularities of uranium ores leaching. It was found that the basic method of uranium ores enrichment and producing of reasonably rich and pure uranium concentrates (usually technical uranium oxide) is a chemical concentration concluded in selective uranium leaching from ore raw materials with further, uranium compounds - so called uranium chemical concentrates. Such reprocessing of uranium ores with the purpose of uranium chemical concentrates production, currently, are produced everywhere by hydrometallurgical methods. This method in comparison with enrichment and thermal reprocessing is a universal one. Hydrometallurgy - the part of chemical technology covering so called moist methods of metals and their compounds (in the current case, uranium) extraction from raw materials, where they are contained. It can be ores or ore concentrates produced by radiometric, gravitational, floatation enrichment, sometimes passed through high-temperature reprocessing or even industry wastes. The basic operation in hydrometallurgy is its important industrial element - metal or metals leaching as one or another compound. Leaching is conversion of one or several components to solution under impact of relevant technical solvents: water, water solutions, acids, alkali or base, solution of some salts and etc. The basic purpose of leaching in uranium technology is to obtain the most full and selective solution of uranium.

Impact of pulling down regulatory state barriers on uranium in Australia: Is there a need in order to maintain and increase Australia’s global market share of uranium?

Directory of Open Access Journals (Sweden)

Ikhlaas Gurrib

2013-10-01

Full Text Available This paper sets a prospective framework to study the impact of opening more mines to meet future growing demand on Australia’s economy. The structure is aimed at decomposing investments and exports variables into Uranium exports and Uranium Exploration expenditure and analyse their impacts on each State GSP (Goods State Product and for Australia as a nation. The demand and supply factors affecting the uranium market are defragmented before providing the research methodology and data specifics. Later analysis is expected to have policy implications by serving as a guide to pull down State Regulatory barriers like those imposed currently in Queensland, which is rich with uranium deposits and allow only uranium exploration but no uranium mining. Empirical findings would suggest whether exporting the carbon free energy would add value to Australia’s different competing states and as a whole globalized economy.

Power Burst Reactor Facility as an epithermal neutron source for brain cancer therapy

International Nuclear Information System (INIS)

Wheeler, F.J.

1986-01-01

The Power Burst Facility (PBF) reactor is considered for modification to provide an intense, clean source of intermediate-energy (epithermal) neutrons desirable for clinical studies of neutron capture therapy (NCT) for malignant tumors. The modifications include partial replacement of the reflector, installation of a neutron-moderating, shifting region, additional shielding, and penetration of the present concrete shield with a collimating (and optionally) filtering region. The studies have indicated that the reactor, after these modifications, will be safely operable at full power (28 MW) within the acceptable limits of the plant protection systems. The neutron beam exiting from the collimator port is predicted to be of sufficient intensity (approx.10 10 neutrons/cm 2 -s) to provide therapeutic doses in very short irradiation times. The beam would be relatively free of undesirable fast neutrons, thermal neutrons and gamma rays. The calculated neutron energy spectrum and associated gamma rays in the beam were provided as input in simulation studies that used a computer model of a patient with a brain tumor to determine predicted dose rates to the tumor and healthy tissue. The results of this conceptual study indicate an intense, clean beam of epithermal neutrons for NCT clinical trials is attainable in the PBF facility with properly engineered design modifications. 9 refs., 11 figs., 3 tabs

The discovery of hornblende-garnet-zoisite hornfels in the metamorphic basement of Xiangshan uranium ore field

International Nuclear Information System (INIS)

Jiang Zhenpin; Dong Yongjie; Yu Jianfa; Hu Rongquan; Wu Shuilin

2007-01-01

Some vein rocks are found among mica schist in the metamorphic rock area of the Xiangshan uranium ore field. They are petrologically denominated as hornblende-garnet-zoisite hornfels. The primitive rocks are basic vein rocks. The hornfels are formed under thermal metamorphism with the temperature about 640 degree C and belong to low-pressure faces. This is closed to the form condition of EarlyMiddle Proterozoic metamorphic rocks in the area. The metamorphism forming the hornfels means that the Early-Middle Proterozoic metamorphic rocks was superimposed to another thermal metamorphism and produced the second phase metamorphic minerals such as staurolite, almandine and biotite. The lattice of the second phase metamorphic mineral developed continuously with the first phase minerals. The overlapping metamorphism made the first phase metamorphic mineral suffer recrystallization, auto purification and idiomorphism. The discovery of hornfelsed basic rock veins discloses that strong geologic process with the activity of fault, magma and metamorphism were still taken placed in Paleozoic era within the metamorphic basement of the Xiangshan uranium ore field. (authors)

Discussion on the origin of bleached sandstone of Qianjiadian uranium deposit

International Nuclear Information System (INIS)

Pang Yaqing; Xiang Weidong; Li Tiangang; Chen Xiaolin; Xia Yuliang

2007-01-01

Qianjiadian uranium deposit is a sandstone-type uranium deposit that has been discovered in Songliao Basin in recent years. Uranium ore bodies are planar or lenticular in shape and under the control of the contact between gray sandstones and bleached sandstones. The bleached sandstone is white in color, cemented loosely, nearly without TOC and pyrite contained and rich in uranium. Geochemical characteristics and types and assemblages of clay minerals of the bleached sandstone reveal that the bleached sandstone is the product of oxidation of the interlayer oxidation zone, and it is a part of the interlayer oxidation zone. The main reasons for white color of the bleached sandstone are transfer of iron ion, oxidation of TOC and kaolinization of sandstone. (authors)

Paleozoic oil/gas shale reservoirs in southern Tunisia: An overview

Science.gov (United States)

Soua, Mohamed

2014-12-01

During these last years, considerable attention has been given to unconventional oil and gas shale in northern Africa where the most productive Paleozoic basins are located (e.g. Berkine, Illizi, Kufra, Murzuk, Tindouf, Ahnet, Oued Mya, Mouydir, etc.). In most petroleum systems, which characterize these basins, the Silurian played the main role in hydrocarbon generation with two main 'hot' shale levels distributed in different locations (basins) and their deposition was restricted to the Rhuddanian (Lllandovery: early Silurian) and the Ludlow-Pridoli (late Silurian). A third major hot shale level had been identified in the Frasnian (Upper Devonian). Southern Tunisia is characterized by three main Paleozoic sedimentary basins, which are from North to South, the southern Chotts, Jeffara and Berkine Basin. They are separated by a major roughly E-W trending lower Paleozoic structural high, which encompass the Mehrez-Oued Hamous uplift to the West (Algeria) and the Nefusa uplift to the East (Libya), passing by the Touggourt-Talemzane-PGA-Bou Namcha (TTPB) structure close to southern Tunisia. The forementioned major source rocks in southern Tunisia are defined by hot shales with elevated Gamma ray values often exceeding 1400 API (in Hayatt-1 well), deposited in deep water environments during short lived (c. 2 Ma) periods of anoxia. In the course of this review, thickness, distribution and maturity maps have been established for each hot shale level using data for more than 70 wells located in both Tunisia and Algeria. Mineralogical modeling was achieved using Spectral Gamma Ray data (U, Th, K), SopectroLith logs (to acquire data for Fe, Si and Ti) and Elemental Capture Spectroscopy (ECS). The latter technique provided data for quartz, pyrite, carbonate, clay and Sulfur. In addition to this, the Gamma Ray (GR), Neutron Porosity (ΦN), deep Resistivity (Rt) and Bulk Density (ρb) logs were used to model bulk mineralogy and lithology. Biostratigraphic and complete

Oxygen isotope zonation at the Golden Cross low-sulfidation epithermal gold deposit, New Zealand

International Nuclear Information System (INIS)

Mauk, J.L.; Simpson, M.P.

2001-01-01

Forty-one whole rock samples from the Gold Cross low-sulfidation epithermal Au-Ag deposit have δ 18 O values that range from 4.4 to 9.3 per mil, with an average value of 7.0 per mil. Unaltered and weakly altered rocks have δ 18 O values greater than 8 per mil, and the orebody is surrounded by samples that are depleted in 18 O. A strongly silicified sample adjacent to the Empire Vein System has a δ 18 O value of 9.0 per mil, similar to previously reported analyses of vein quartz (7.0 to 11.7 per mil, average 9.4 per mil). This suggests that, in detail, Golden Cross may have a zone of 18 O-enriched wall rocks in the core of the deposit, adjacent to the main underground veins. Although some workers have suggested that stable isotope geochemistry may provide useful information for epithermal mineral deposit exploration, at Golden Cross this is not the case. Alteration minerals, major elements and trace elements all define larger, less ambiguous halos than the zone of 18 O-depleted wall rocks. (author). 21 refs., 3 figs., 1 tab

In vitro biological effectiveness of JRR-4 epithermal neutron beam. Experiment under free air beam and in water phantom. Cooperative research

CERN Document Server

Yamamoto, T; Horiguchi, Y; Kishi, T; Kumada, H; Matsumura, A; Nose, T; Torii, Y; Yamamoto, K

2002-01-01

The surviving curve and the biological effectiveness factor of dose components generated in boron neutron capture therapy (BNCT) were separately determined in neutron beams at Japan Research Reactor No.4. Surviving fraction of V79 Chinese hamster cell with or without sup 1 sup 0 B was obtained using an epithermal neutron beam (ENB), a mixed thermal-epithermal neutron beam (TNB-1), and a thermal neutron beam (TNB-2), which were used or planned to use for BNCT clinical trial. The cell killing effect of these neutron beams with or without the presence of sup 1 sup 0 B depended highly on the neutron beam used, according to the epithermal and fast neutron content in the beam. The biological effectiveness factor values of the boron capture reaction for ENB, TNB-1 and TNB-2 were 3.99+-0.24, 3.04+-0.19 and 1.43+-0.08, respectively. The biological effectiveness factor values of the high-LET dose components based on the hydrogen recoils and the nitrogen capture reaction were 2.50+-0.32, 2.34+-0.30 and 2.17+-0.28 for EN...

International Uranium Resources Evaluation Project (IUREP) orientation phase mission report: Cameroon. Draft

International Nuclear Information System (INIS)

Trey, Michel de; Leney, George W.

1983-05-01

Geology Branch with mapping and exploration services. Most of CAMEROON is underlain by Precambrian granites , anatexites, migmatites, gneisses, and schists. The NTEM complex in the south is Archean age. Most other areas are probably Lower Proterozoic, with some Middle Proterozoic inliers of the LOM, POLI, and MBALMAYO-BENGBIS, and the DJA series in the southeast. The DJA tillite is probably Upper Proterozoic. There are small remnant basins of Paleozoic volcanics, and larger basins and grabens of Middle-Upper Cretaceous. Tertiary rocks are present in the Coastal basins and the southeast. The Lake Chad depression is covered with Quaternary sands. All of the older rocks except the NTEM complex and the DJA series are within the Panafrican Mobile Belt. The border faults of the Cretaceous BENOUE graben are throughgoing crustal features. Tertiary intrusives and plateau basalts are found along the 'LINE OF CAMEROON', and volcanism has continued to present. Uranium exploration from 1950 to present has produced mostly negative results. Only one important prospect has been found at GOBLE-KITONGO, and has been the subject of repeated exploration from 195 8 to present. An enriched zone in syenite at LOLODORF is also under investigation. Anomalies on an airborne survey of the DJA series are being checked for mineralization similar to the FRANCEVILLIAN of GABON. Total expenditures that may be assigned to uranium are on the order of $10 million (U.S.). There are no uranium ore reserves or reasonably assured resources in CAMEROON. Speculative resources of 10,000 tonnes have been assigned to the LOLODORT syenite, and 5000 tonnes to the GOBLE-KITONGO prospect and Paleozoic volcanics at $130/kg. (U.S.). Favorable areas are the DJA series, syenites of the Panafrican granite and 'granites ultimes', Mesozoic-Cenozoic basins (especially DOUALA), LOM and MBALMAYO-BENGBIS series, POLI-MAROUA, and Lower Proterozoic/Archean gneiss and granite. Recommendations have been made for topical studies of

Analytical electron microscopy characterization of uranium-contaminated soils from the Fernald Site, FY1993 report

International Nuclear Information System (INIS)

Buck, E.C.; Cunnane, J.C.; Brown, N.R.; Dietz, N.L.

1994-10-01

A combination of optical microscopy, scanning electron microscopy with backscattered electron detection (SEM/BSE), and analytical electron microscopy (AEM) is being used to determine the nature of uranium in soils from the Fernald Environmental Management Project. The information gained from these studies is being used to develop and test remediation technologies. Investigations using SEM have shown that uranium is contained within particles that are typically 1 to 100 μm in diameter. Further analysis with AEM has shown that these uranium-rich regions are made up of discrete uranium-bearing phases. The distribution of these uranium phases was found to be inhomogeneous at the microscopic level

Study of petrological characteristics of uranium-bearing sandstone in the south of ordos basin, China

International Nuclear Information System (INIS)

Tian Cheng; Jia Licheng; Li Song; Zhang Zimin

2007-01-01

This paper discusses the relation between uranium-bearing abundance and texture constituent of sedimentary rock, on the basis of the research of petrological characteristic of sandstone in the south of Ordos basin. The influence of infiltration of sandstone and uranium migration and accumulation by the major diagenesis of compaction and cementation, clay minerals evolution, corrosion and forming of secondary porosity are discussed. Uranium-bearing sandstones are divided into four types and their petrological characteristics are discussed. After mineralization conditions being summed up, the uranium-mineralization model of sandstone-type is built. Reliable petrological evidences for evaluating favourable uranium mineralization rich areas are furnished. (authors)

Preliminary discussion on deep-sourced uranium metallogenesis and deep prospecting

International Nuclear Information System (INIS)

Huang Shijie

2006-01-01

Prospecting for hydrothermal type uranium deposits should be aimed at medium-to large-sized deposits, and be guided by mantle-sourced, superimposed, deep-sourced metallogenic theory and the establishment of a multifactor, composite, deep-sourced metallogenic model. The author suggests that hydrothermal uranium deposits may be classified into three genetic types, i.e. hydrothermal circulation concentration, postmagmatic hydrothermal and mantle fluid concentration. These types of uranium deposits are characterized by their own metallogenic features and are concentrated in the same mineralization-concentrated area forming a metallogenic series. Large-sized uranium ore fields and rich-large uranium deposits are usually closely associated with mantle-sourced metallogenesis and the formation of such uranium ore fields and deposits is characterized by specific and unique regional geologic environments. Recognition criteria of mantle-sourced metallogenesis are preliminarily proposed in the paper. It is pointed out that prospecting in the future should follow the metallogenic model proper for the specific genetic type, and the establishment of operable prospecting model to realize the model-guided prospecting. (authors)

Utilization of boron irradiation filters in reactor neutron activation via epithermal (n,γ) and fast neutron reactions

International Nuclear Information System (INIS)

Chisela, F.

1986-01-01

The technique of instrumental neutron activation analysis based on irradiation with reactor epithermal and fast neutrons has been described and evaluated. Important characteristics of boron neutron absorbers used to remove thermal neutrons from the reactor neutron spectrum have been examined and compared with those of cadmium. Three boron compound shields, have been designed and constructed at the BER II 5MW reactor for use in epithermal neutron activation analysis of biological materials. The major advantages offered by these filters in this application include the flexibility of varying the filter thickness, the low radioactivity induced in the filters during irradiation, ease of fabrication and the relatively low cost of the filter materials. The radiation heating due to the 10 B(n,α) 7 Li-reaction has been experimentally investigated for the filters used and the results obtained confirm the necessity for efficient cooling of these filters during irradiation. Three irradiation facilities have been characterized with respect to the neutron flux density and the flux spatial distribution. An experiment has been designed and carried out to compensate the flux inhomogeneity in two irradiation positions of the DBV facility caused by the reactor geometry. Several biological samples including well characterized reference materials have been analysed after epithermal activation and the results compared with those obtained with the classical thermal neutron activation method. Improved sensitivity of determination has been found for elements with high resonance integral to thermal neutron cross section ratios (RI/σ 0 ). The range of elements that can be determined instrumentally is extended and the time scale of analysis is considerably reduced. (orig.) [de

Geochemical orientation survey of stream sediment, stream water, and ground water near uranium prospects, Monticello area, New York. National Uranium Resource Evaluation Program

International Nuclear Information System (INIS)

Rose, A.W.; Smith, A.T.; Wesolowski, D.

1982-08-01

A detailed geochemical test survey has been conducted in a 570 sq km area around six small copper-uranium prospects in sandstones of the Devonian Catskill Formation near Monticello in southern New York state. This report summarizes and interprets the data for about 500 stream sediment samples, 500 stream water samples, and 500 ground water samples, each analyzed for 40 to 50 elements. The groundwater samples furnish distinctive anomalies for uranium, helium, radon, and copper near the mineralized localities, but the samples must be segregated into aquifers in order to obtain continuous well-defined anomalies. Two zones of uranium-rich water (1 to 16 parts per billion) can be recognized on cross sections; the upper zone extends through the known occurrences. The anomalies in uranium and helium are strongest in the deeper parts of the aquifers and are diluted in samples from shallow wells. In stream water, copper and uranium are slightly anomalous, as in an ore factor derived from factor analysis. Ratios of copper, uranium, and zinc to conductivity improve the resolution of anomalies. In stream sediment, extractable uranium, copper, niobium, vanadium, and an ore factor furnish weak anomalies, and ratios of uranium and copper to zinc improve the definition of anomalies. The uranium/thorium ratio is not helpful. Published analyses of rock samples from the nearby stratigraphic section show distinct anomalies in the zone containing the copper-uranium occurrences. This report is being issued without the normal detailed technical and copy editing, to make the data available to the public before the end of the National Uranium Reconnaissance Evaluation program

Geochemical orientation survey of stream sediment, stream water, and ground water near uranium prospects, Monticello area, New York. National Uranium Resource Evaluation Program

Energy Technology Data Exchange (ETDEWEB)

Rose, A. W.; Smith, A. T.; Wesolowski, D.

1982-08-01

A detailed geochemical test survey has been conducted in a 570 sq km area around six small copper-uranium prospects in sandstones of the Devonian Catskill Formation near Monticello in southern New York state. This report summarizes and interprets the data for about 500 stream sediment samples, 500 stream water samples, and 500 ground water samples, each analyzed for 40 to 50 elements. The groundwater samples furnish distinctive anomalies for uranium, helium, radon, and copper near the mineralized localities, but the samples must be segregated into aquifers in order to obtain continuous well-defined anomalies. Two zones of uranium-rich water (1 to 16 parts per billion) can be recognized on cross sections; the upper zone extends through the known occurrences. The anomalies in uranium and helium are strongest in the deeper parts of the aquifers and are diluted in samples from shallow wells. In stream water, copper and uranium are slightly anomalous, as in an ore factor derived from factor analysis. Ratios of copper, uranium, and zinc to conductivity improve the resolution of anomalies. In stream sediment, extractable uranium, copper, niobium, vanadium, and an ore factor furnish weak anomalies, and ratios of uranium and copper to zinc improve the definition of anomalies. The uranium/thorium ratio is not helpful. Published analyses of rock samples from the nearby stratigraphic section show distinct anomalies in the zone containing the copper-uranium occurrences. This report is being issued without the normal detailed technical and copy editing, to make the data available to the public before the end of the National Uranium Reconnaissance Evaluation program.

Uranium occurrences in the surficial deposits of Southern Africa

International Nuclear Information System (INIS)

Hambleton-Jones, B.B.

1982-01-01

This paper outlines the geology of the Tertiary to Recent(10 to 0,1 Ma) surficial uranium deposits in South West Africa/Namibia and South Africa. They occur mainly in the Namib Desert to the east of Walvis Bay in South West Africa/Namibia and in the north-western Cape Province of South Africa. All the deposits can be classified as fluviatile, lacustrine/pan, or pedogenic types. The economic potential of the surficial uranium deposits in the north-western Cape is insignificant compared with their South West African/Namibian counterparts. Most of the deposits occur in gypsiferous fluviatile gravels and lacustrine/pan sediments. The largest of the deposits is a lacustrinal, peat-rich, diatomaceous earth type. The mechanisms for the precipitation of the uranium are discussed

Archean inheritance in zircon from late Paleozoic granites from the Avalon zone of southeastern New England: an African connection

Science.gov (United States)

Zartman, R.E.; Don, Hermes O.

1987-01-01

In southeastern New England the Narragansett Pier Granite locally intrudes Carboniferous metasedimentary rocks of the Narragansett basin, and yields a monazite UPb Permian emplacement age of 273 ?? 2 Ma. Zircon from the Narragansett Pier Granite contains a minor but detectable amount of an older, inherited component, and shows modern loss of lead. Zircon from the late-stage, aplitic Westerly Granite exhibits a more pronounced lead inheritance -permitting the inherited component to be identified as Late Archean. Such old relict zircon has not been previously recognized in Proterozoic to Paleozoic igneous rocks in New England, and may be restricted to late Paleozoic rocks of the Avalon zone. We suggest that the Archean crustal component reflects an African connection, in which old Archean crust was underplated to the Avalon zone microplate in the late Paleozoic during collision of Gondwanaland with Avalonia. ?? 1987.

New results from isochronous mass measurements of neutron-rich uranium fission fragments with the FRS-ESR-facility at GSI

Energy Technology Data Exchange (ETDEWEB)

Knoebel, R.; Litvinov, Yu.A.; Weick, H.; Bosch, F.; Boutin, D.; Dimopoulou, C.; Dolinskii, A.; Franczak, B.; Franzke, B.; Kozhuharov, C.; Kurcewicz, J.; Litvinov, S.A.; Matos, M.; Mazzocco, M.; Muenzenberg, G.; Nociforo, C.; Nolden, F.; Stadlmann, J.; Steck, M.; Winkler, M. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, Darmstadt (Germany); Diwisch, M. [Justus-Liebig-Universitaet Giessen, II. Physikalisches Institut, Giessen (Germany); Geissel, H.; Plass, W.R.; Scheidenberger, C.; Chen, L. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, Darmstadt (Germany); Justus-Liebig-Universitaet Giessen, II. Physikalisches Institut, Giessen (Germany); Patyk, Z. [National Centre for Nuclear Research - NCBJ Swierk, Warszawa (Poland); Sun, B. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, Darmstadt (Germany); Beihang University, School of Physics and Nuclear Energy Engineering, Beijing (China); Hausmann, M. [Michigan State University, East Lansing, MI (United States); Nakajima, S.; Suzuki, T.; Yamaguchi, T. [Saitama University, Department of Physics, Saitama (Japan); Ohtsubo, T. [Niigata University, Department of Physics, Niigata (Japan); Ozawa, A. [University of Tsukuba, Institute of Physics, Ibaraki (Japan); Walker, P.M. [University of Surrey, Department of Physics, Guildford (United Kingdom)

2016-05-15

Masses of uranium fission fragments have been measured with the FRagment Separator (FRS) combined with the Experimental Storage Ring (ESR) at GSI. A 410-415 MeV/u {sup 238}U projectile beam was fast extracted from the synchrotron SIS-18 with an average intensity of 10{sup 9}/spill. The projectiles were focused on a 1g/cm{sup 2} beryllium target at the entrance of the FRS to create neutron-rich isotopes via abrasion-fission. The fission fragments were spatially separated with the FRS and injected into the isochronous storage ring ESR for fast mass measurements without applying cooling. The Isochronous Mass Spectrometry (IMS) was performed under two different experimental conditions, with and without B ρ-tagging at the high-resolution dispersive central focal plane of the FRS. The evaluation has been done for the combined data sets from both experiments with a new method of data analysis. The use of a correlation matrix has provided experimental mass values for 23 different neutron-rich isotopes for the first time and 6 masses with improved values. The new masses were obtained for nuclides in the element range from Se to Ce. The applied analysis has given access even to rare isotopes detected with an intensity of a few atoms per week. The novel data analysis and systematic error determination are described and the results are compared with extrapolations of experimental values and theoretical models. (orig.)

Arbuscular mycorrhiza reduces phytoextraction of uranium, thorium and other elements from phosphate rock

DEFF Research Database (Denmark)

Roos, Per; Jakobsen, Iver

2008-01-01

Uptake of metals from uranium-rich phosphate rock was studied in Medicago truncatula plants grown in symbiosis with the arbuscular mycorrhizal fungus Glomus intraradices or in the absence of mycorrhizas. Shoot concentrations of uranium and thorium were lower in mycorrhizal than in non-mycorrhizal......-fungus uptake systems. The results support the role of arbuscular mycorrhiza as being an important component in phytostabilization of uranium. This is the first study to report on mycorrhizal effect and the uptake and root-to-shoot transfer of thorium from phosphate rock. (c) 2007 Elsevier Ltd. All rights...

Aerial gamma ray and magnetic survey: Mississippi and Florida airborne survey, Russellville quadrangle, Arkansas

International Nuclear Information System (INIS)

1980-09-01

The Russellville quadrangle in north central Arkansas overlies thick Paleozoic sediments of the Arkoma Basin. These Paleozoics dominate surface exposure except where covered by Quaternary alluvial materials. Examination of available literature shows no known uranium deposits (or occurrences) within the quadrangle. Eighty-eight groups of uranium samples were defined as anomalies and are discussed briefly. None were considered significant, and most appeared to be of cultural origin. Magnetic data show character that suggest structural and/or lithologic complexity, but imply relatively deep-seated sources

Aerial gamma ray and magnetic survey: Mississippi and Florida airborne survey, Fort Smith quadrangle, Oklahoma, and Arkansas. Final report

International Nuclear Information System (INIS)

1980-09-01

The Fort Smith quadrangle in western Arkansas and eastern Oklahoma overlies thick Paleozoic sediments of the Arkoma Basin. These Paleozoics dominate surface exposure except where covered by Quaternary Alluvial materials. Examination of available literature shows no known uranium deposits (or occurrences) within the quadrangle. Seventy-five groups of uranium samples were defined as anomalies and are discussed briefly. None were considered significant, and most appeared to be of cultural origin. Magnetic data show character that suggest structural and/or lithologic complexity, but imply relatively deep-seated sources

Contributions to the mineralogy, petrography and metallogeny of the Itataia phosphorus-uranium deposit, state of Ceara, Brazil

International Nuclear Information System (INIS)

Netto, A.M.

1984-01-01

The phosphorus-uranium mineralization of the Itataia deposit is unique. Most of the uranium is contained in the collophane (uraniferous fluorapatite) obtained through the transformation of metamorphic apatite of the country rocks (Itataia Group). A graphite-rich pelitic metasediment origin for the uranium and phosphorus is suggested. Initially, the rocks were subjected to isoclinal and homoclinal folding associated with overthrusting and regional metamorphism of the high amphibolite facies with some migmatization. The mineralization is epigenetic and dominated by sodium-rich metasomatic fluids. The mobilized quartz-feldspathic migmatites were transformed into collophane-albite-episyenites. The considerably thick markbles provided the conditions favoring an increase in the fluids pH which caused the precipitation of collophane concentrated in pockets and stockworks. (Author) [pt

Analysis on uranium resource situations and metallogenic potential of Heyuan mineralization belt of Guangdong province

International Nuclear Information System (INIS)

Chen Zhuhai; Zheng Mingliang; Song Shizhu; Liang Yewu; Zhao Wei

2008-01-01

Heyuan mineralization belt is a structure-magmatic activities belt which is charcterized by strong plastic deformation and shearing. The squeeze (overthrust) structure is formed early. Later stretch produced slide shovel-shaped normal fault which control the red basin and uranium mineralization. Comprehensive study shows that this area is of favorable uranium metallogenic condition due to the rich uranium source and higher degree of geology work, it is a target for the new round resources exploration. (authors)

Procedure and code for calculating black control rods taking into account epithermal absorption, code CAS-1

International Nuclear Information System (INIS)

Martinc, R.; Trivunac, N.; Zivkovic, Z.

1964-12-01

This report describes the computer code CAS-1, calculation method and procedure applied for calculating the black control rods taking into account the epithermal neutron absorption. Results obtained for supercell method applied for regular lattice reflected in the multiplication medium is part of this report in addition to the computer code manual

Radiobiology studies for the evaluation of epithermal neutron beams used for BNCT

International Nuclear Information System (INIS)

Green, S.; Jones, B.; Mill, A.J.

2006-01-01

This paper outlines our plans for a study to establish the radiobiological effectiveness of the various mixes of radiation components present in an epithermal neutron beam designed for BNCT and to incorporate these data into clinical protocols for the treatment of malignant glioma. This is a description of work which is funded and just now beginning in Birmingham so no results can be presented. Our project will involve a combination of experimental measurements carried out in Birmingham and in Boston and mathematical modelling carried out in Birmingham. Despite all the extant in-vitro and in-vivo work, there is no widely accepted method to determine biological effect by accounting for variations in beam component mix, dose rate and treatment fractionation for disparate from the various BNCT centres. The objectives of this study are: To develop a cell-based radiobiology protocol to provide essential data on safety and efficacy of beams for Boron Neutron Capture Therapy (BNCT) in advance of clinical trials. To exploit the facilities at Massachusetts Institute of Technology for variable dose-rate epithermal irradiations to validate the above protocol. To develop mathematical models of this radiobiological system that can be used to inform decisions on dose selection, fractionation schedules, BNCT use as supplementary boosts or for re-treatment of recurrent cancers. To provide fundamental data relevant to the understanding of the radiobiology of simultaneous mixed high-and low-LET radiations over a clinically relevant dose-range. (author)

Discussion on geological features and genesis of Chulute uranium metallogenetic region of North Hanggay Province in Mongolia

International Nuclear Information System (INIS)

Zhao Fengmin

2005-01-01

Chulute uranium metallogenetic region is situated in the northern part of North Hanggay Province in Mongolia. Geotectonically, it is located at the very western end of Mongolia-Transbaikal fold system. The granite with elevated uranium content is widely developed in this region, where the uranium content in the granite aged from Later Triassic to Early Jurassic ranges from 5 x 10 -6 to 6 x 10 -6 . Due to the neotectonic activation, quaternary palaeo-valleys that incised the basement were formed on the basement granite and were filled with organic matter-rich clastic sediments and basalt crusts. The palaeo-valley type uranium mineralization (Dajinhe, Bayaer and Shuer uranium occurrences) is discovered in the two palaeo-valleys which incised the granitoids. Of them, Shuer uranium occurrence has been studied more in detail. An ore-body with the thickness from 9.1 m to 19.75 m has been found in an area with the width of 500 m, and the uranium grade ranging from 0.01% to 0.05%. The uranium mineralization occurs in the bleached and limonitized grey loam and clayey soil and sand which bear rich calliferous plant debris and lamella of black mudstones. Coffinite is the uranium mineral. The uranium resources in Shuer deposit has been proven as 2500 t. The total predictive resources in above mentioned two palaeo-valleys reach as much as 15000-16000 t (P 2 ). The uranium mineralization in this region is characterized by young mineralization age and adjacent sources. The ore formation is possibly related to the surface thermal field which is originated from the eruption of the basaltic magmas. (authors)

Uranium in underground water public supply of the metropolitan region of Recife

International Nuclear Information System (INIS)

Silva, C.M.; Sousa, G.H.; Vasconcelos, W.E.; Hazin, C.A.; Amaral, R.S.

2001-01-01

The geologic formation of the metropolitan region of Recife is of sedimentary origin. In the coast area, where the phosphate deposits are located, it is sufficiently rich in underground hydric features. In the superposed layers of the sedimentary basin exists three underground aquifers and 80% of the underground hydric features of public supplying of the metropolitan region of Recife are located in the phosphate deposits, which are rich in uranium. Physiologically the uranian are in the steady state (6+) with bivalent cations U 2+ 2 . The ingestion of uranium by man occurs through foods and water ingestion. The places of the human body where it has greater clamping of this radionuclides are the bones. The uranium is deposited slowly from surface of the bone, redistributing itself in route to the marrow. An important competition between Ca 2+ 2 and the UO 2+ 2 exists in the kidneys, where the Ca 2+ 2 efficiently is absorbed. This work was carried through aiming to determine the concentrations of uranium in waters of the wells of public supplying of the metropolitan region of Recife, collating them with the limits established for the Health Department, that establishes the level of 0.1 Bq/L referring to the total alpha radioactivity in drinking waters

Preparation of the pur uranium-metal

International Nuclear Information System (INIS)

Goldschmidt, B.; Vertes, P.

1955-01-01

A detailed description of the chemical processes used to prepare in the factory of Bouchet of the CEA (Seine-Et-Oise) pur metal uranium with either relatively rich ores, or extracts coming of physical or chemical treatment of poor ores. The nitric treatment of ores succeeds to the production of uranate of impure sodium carbonate. This last last product is dissolved in nitric acid and the uranyl nitrate is extracted by tributyl-phosphate diluted in an inert solvent. The uranyl nitrate pure is re-extracted and successively transformed in uranium peroxide, in orange oxide then in brown oxide which is transformed in fluoride by the anhydrous hydrofluoric acid. Uranate fluoride is then reduced in metal by the pure calcium with an yield superior to 99%. (authors) [fr

Possible pitfalls in the search for uranium deposits using lake sediments and lake waters

International Nuclear Information System (INIS)

Levinson, A.A.; Bland, C.J.

1978-01-01

The organic-rich sediments from the centres of Canadian lakes are a valuable sampling medium in the search for uranium. However, because of the young age of hydromorphically transported uranium in these sediments, which must post-date the last period of glaciation, there has been insufficient time for the isotope 214 Bi to reach equilibrium with its ancestor 238 U. This results in equivalent uranium (eU) values significantly lower than actual uranium values determined by fluorometry or delayed neutron activation analysis. Radiometric ( 226 Ra) analyses of 12 centre-lake sediments from Seahorse Lake, Saskatchewan illustrate the potential pitfalls which may be encountered using gamma-ray spectrometry, as only 3-8% of the actual uranium present in most of the samples would have been detected. (author)

Genesis of uranium deposits of the Tono Mine, Japan

International Nuclear Information System (INIS)

Katayama, N.; Kubo, K.; Hirono, S.

1974-01-01

The uranium deposits of the Tono mine, Gifu Prefecture, Japan, occur in the basal part of the Toki group of Miocene age, and are distributed in the tributaries or at the head of channels on the plane of unconformity under the formation. These features characterize the basal ground-water type of uranium deposit, and they are unique in that their typical ore mineral is a zeolite of the heulandite-clinoptilolite group, uranium being adsorbed in it. The paper presents the history of formation of the Tsukiyoshi deposits, the most intensely explored in the Tono mine. The matrices of conglomerates and sandstones of the Toki group usually contain tuffaceous material, which has been montmorillonitized or zeolitized diagenetically. The conduit of uranium-bearing ground waters that migrated from the basement granites into the Tertiary sediments was controlled by the impermeable barriers, which are rocks in which montmorillonite predominated, or by the Tsukiyoshi fault, as well as by channel structures. Where the waters became rather stagnant, uranium was adsorbed in zeolite from them. Enrichment of uranium further proceeded locally as follows. Pyrite was oxidized to produce sulphuric acid solution which leached the uranium that had been adsorbed in zeolite. The pH of the uranium-rich solution became higher and higher in the course of migration and, as soon as it reached about 4, the uranium in the solution was again adsorbed in zeolite, the uranium content of which may have been enriched up to 0.9%. Coffinites have been formed where uranium was accumulated over the adsorption capacity of zeolite or where strongly reducing conditions were maintained by carbonaceous matter. (author)

Dose planning with comparison to in vivo dosimetry for epithermal neutron irradiation of the dog brain

International Nuclear Information System (INIS)

Seppaelae, Tiina; Auterinen, Iiro; Aschan, Carita; Seren, Tom; Benczik, Judit; Snellman, Marjatta; Huiskamp, Rene; Ramadan, Usama Abo; Kankaanranta, Leena; Joensuu, Heikki; Savolainen, Sauli

2002-01-01

Boron neutron capture therapy (BNCT) is an experimental type of radiotherapy, presently being used to treat glioblastoma and melanoma. To improve patient safety and to determine the radiobiological characteristics of the epithermal neutron beam of Finnish BNCT facility (FiR 1) dose-response studies were carried on the brain of dogs before starting the clinical trials. A dose planning procedure was developed and uncertainties of the epithermal neutron-induced doses were estimated. The accuracy of the method of computing physical doses was assessed by comparing with in vivo dosimetry. Individual radiation dose plans were computed using magnetic resonance images of the heads of 15 Beagle dogs and the computational model of the FiR 1 epithermal neutron beam. For in vivo dosimetry, the thermal neutron fluences were measured using Mn activation foils and the gamma-ray doses with MCP-7s type thermoluminescent detectors placed both on the skin surface of the head and in the oral cavity. The degree of uncertainty of the reference doses at the thermal neutron maximum was estimated using a dose-planning program. The estimated uncertainty (±1 standard deviation) in the total physical reference dose was ±8.9%. The calculated and the measured dose values agreed within the uncertainties at the point of beam entry. The conclusion is that the dose delivery to the tissue can be verified in a practical and reliable fashion by placing an activation dosimeter and a TL detector at the beam entry point on the skin surface with homogeneous tissues below. However, the point doses cannot be calculated correctly in the inhomogeneous area near air cavities of the head model with this type of dose-planning program. This calls for attention in dose planning in human clinical trials in the corresponding areas

Determination of selenium in Ni + Co concentrates applying epithermal neutron activation analysis

International Nuclear Information System (INIS)

Capote Rodriguez, G.; Perez Sayaz, G.; Hernandez Rivero, A.; Moreno Bermudez, J.; Ribeiro Guevara, S.; Arribere, M.A.; Molina Insfran, J.

1996-01-01

Concentration of Se in Ni + Co concentrates obtained in nickel industry has to be determined as that is a quality control requirement for its commercialization. At present, analysis of Se, specially at a minor and trace levels is relatively complicated and destructive procedures are frequently required. In this work determination of Se by epithermal neutron activation analysis (ENAA) in 17 samples of nickel industry was investigated. Application of ENAA allowed nondestructive determination of Se concentration down to ppm level in spite of presence of high Co, Fe, Ni, and Cr contents in the samples

Geology of the Sievi, Kuru and Askola sites. Uranium mineralogy at Askola

International Nuclear Information System (INIS)

Markovaara-Koivisto, M.; Read, D.; Lindberg, A.; Siitari-Kauppi, M.; Togneri, L.

2009-01-01

The natural geochemical retardation systems of radioactive elements in the Finnish bedrock are of great relevance to the Finnish nuclear waste disposal programme. It indicates the likely fate of radionuclides released from the deep repository when the chemical environment is oxidizing within its operating stage or in the event of glacial melt water percolates to the repository. In these conditions the uranium occurs in its state, and it is reactive and mobile. Studying uranium migration and retention in oxidizing conditions is thus justified. Uranium migration and retention are studied with samples taken from a natural uranium deposit at Askola. Likewise the uranium migration is studied with laboratory tests. The naturally uranium-rich samples are taken from shallow depths at Askola, and thus the behaviour of uranium can be studied in oxidising conditions. In the laboratory tests uranium is released from a depleted uranium disc and allowed to migrate and retain in Kuru grey granite and Sievi altered tonalite. The uranium is expected to migrate into the rock and to precipitate there as secondary phases. The rate of uranium migration and age of the precipitates in the laboratory experiments are known, but not in the case of the natural analogue studies. The observations from both the natural analogue and the laboratory tests will be used as input data for the coupled geochemical model for uranium migration and retention. (orig.)

The Chahnaly low sulfidation epithermal gold deposit, western Makran volcanic arc, southeastern Iran

Science.gov (United States)

Sholeh, Ali; Rastad, Ebrahim; Huston, David L.; Gemmell, J. Bruce; Taylor, Ryan D.

2016-01-01

The Chahnaly low-sulfidation epithermal Au deposit and nearby Au prospects are located northwest of the intermittently active Bazman stratovolcano on the western end of the Makran volcanic arc, which formed as the result of subduction of the remnant Neo-Tethyan oceanic crust beneath the Lut block. The arc hosts the Siah Jangal epithermal and Kharestan porphyry prospects, near Taftan volcano, as well as the Saindak Cu-Au porphyry deposit and world-class Reko Diq Cu-Au porphyry deposit, near Koh-i-Sultan volcano to the east-northeast in Pakistan. The host rocks for the Chahnaly deposit include early Miocene andesite and andesitic volcaniclastic rocks that are intruded by younger dacitic domes. Unaltered late Miocene dacitic ignimbrites overlie these rocks. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb zircon geochronology data yield ages between 21.8 and 9.9 Ma for the acidic-intermediate regional volcanism. The most recent volcanic activity of the Bazman stratovolcano involved extrusion of an olivine basalt during Pliocene to Quaternary times. Interpretation of geochemical data indicate that the volcanic rocks are synsubduction and calc-alkaline to subalkaline. The lack of a significant negative Eu anomaly, a listric-shaped rare earth element pattern, and moderate La/Yb ratios of host suites indicate a high water content of the source magma.

Recent exploration progresses on sandstone-hosted uranium deposits in north-western China

International Nuclear Information System (INIS)

Li, Z.

2014-01-01

The metallogenic target selection using multiple exploration techniques and drilling program for sandstone-hosted uranium deposits have been intensively carried out for recent years, and big progresses on new discoveries of uranium reserve/resource have been made in the Mesozoic sedimentary basins such as in Yili, Ordos etc. in North-western China The Yili basin is a depression one within the Tianshan Mountain belt in the western part of China. Its basement is composed of Proterozoic-Paleozoic metamorphic and sedimentary rocks, and covers of Mesozoic sediments. The early-middle Jurassic Shuixigou Group is major uranium-productive beds which are composed of three Formations such as Badaowan, Sangonghe, Xisanyao and eight sedimentary cycles. Uranium deposits are found in the south margin of the Basin and controlled by the redox zone. The combined exploration techniques of detailed sedimentary facies study, Rn-survey, high-precision magnetic and soil geochemical and seismic surveys have been successfully used to have locate the potential targets and mineralization zones. The enlargement of uranium reserve/resources in the known deposits and new resources in the selected new targets and cycles have been achieved through further drilling programs. The Ordos basin is a large Meso-Cenozoic basin developed in North China Platform, with its size of approximately 250,000 km"2 and is well known as an important “energy resources basin” because of abundance of coal, oil and gas deposits. The Dongsheng sandstone type uranium deposit is a large one discovered in recent years in northeastern Ordos basin. It is a special kind of sandstone type uranium deposit, different from other ordinary sandstone type deposits because of its unique signatures. It is generally controlled by a transitional zone between greenish and grayish sandstones, both of those two kinds of sandstones now indicate reduced geochemical environments. The greenish color of the paleooxidized sandstones mainly

Global plate boundary evolution and kinematics since the late Paleozoic

Science.gov (United States)

Matthews, Kara J.; Maloney, Kayla T.; Zahirovic, Sabin; Williams, Simon E.; Seton, Maria; Müller, R. Dietmar

2016-11-01

Many aspects of deep-time Earth System models, including mantle convection, paleoclimatology, paleobiogeography and the deep Earth carbon cycle, require high-resolution plate motion models that include the evolution of the mosaic of plate boundaries through time. We present the first continuous late Paleozoic to present-day global plate model with evolving plate boundaries, building on and extending two previously published models for the late Paleozoic (410-250 Ma) and Mesozoic-Cenozoic (230-0 Ma). We ensure continuity during the 250-230 Ma transition period between the two models, update the absolute reference frame of the Mesozoic-Cenozoic model and add a new Paleozoic reconstruction for the Baltica-derived Alexander Terrane, now accreted to western North America. This 410-0 Ma open access model provides a framework for deep-time whole Earth modelling and acts as a base for future extensions and refinement. We analyse the model in terms of the number of plates, predicted plate size distribution, plate and continental root mean square (RMS) speeds, plate velocities and trench migration through time. Overall model trends share many similarities to those for recent times, which we use as a first order benchmark against which to compare the model and identify targets for future model refinement. Except for during the period 260-160 Ma, the number of plates (16-46) and ratio of "large" plates (≥ 107.5 km2) to smaller plates ( 2.7-6.6) are fairly similar to present-day values (46 and 6.6, respectively), with lower values occurring during late Paleozoic assembly and growth of Pangea. This temporal pattern may also reflect difficulties in reconstructing small, now subducted oceanic plates further back in time, as well as whether a supercontinent is assembling or breaking up. During the 260-160 Ma timeframe the model reaches a minima in the number of plates, in contrast to what we would expect during initial Pangea breakup and thus highlighting the need for refinement

Reactor beam calculations to determine optimum delivery of epithermal neutrons for treatment of brain tumors

International Nuclear Information System (INIS)

Wheeler, F.J.; Nigg, D.W.; Capala, J.

1997-01-01

Studies were performed to assess theoretical tumor control probability (TCP) for brain-tumor treatment with boron neutron capture therapy (BNCT) using epithermal neutron sources from reactors. The existing epithermal-neutron beams at the Brookhaven Medical Research Reactor Facility (BMRR), the Petten High Flux Reactor Facility (HWR) and the Finnish Research Reactor 1 (FIR1) have been analyzed and characterized using common analytical and measurement methods allowing for this inter-comparison. Each of these three facilities is unique and each offers an advantage in some aspect of BNCT, but none of these existing facilities excel in all neutron-beam attributes as related to BNCT. A comparison is therefore also shown for a near-optimum reactor beam which does not currently exist but which would be feasible with existing technology. This hypothetical beam is designated BNCT-1 and has a spectrum similar to the FIR-1, the mono-directionality of the HFR and the intensity of the BMRR. A beam very similar to the BNCT-1 could perhaps be achieved with modification of the BMRR, HFR, or FIR, and could certainly be realized in a new facility with today's technology

The late Paleozoic ecological-evolutionary laboratory, a land-plant fossil record perspective

NARCIS (Netherlands)

Looy, Cindy; Kerp, Hans; Duijnstee, Ivo; DiMichele, Bill

2014-01-01

In this essay we examine the fossil record of land plants, focusing on the late Paleozoic. We explore the nature of this record in terms of what is preserved, where, why and with what biases. And as a consequence, how it can be used to answer questions posed at various spatial and temporal scales,

Surficial origin of North American pitchblende and related uranium deposits

International Nuclear Information System (INIS)

Langford, F.F.

1977-01-01

The ubiquitous association of pitchblende uranium deposits with terrestrial sediments is believed to be the natural result of formation of the orebodies by surficial processes operating under continental conditions. The major uranium deposits of North America illustrate this. The quartz-pebble conglomerate uranium deposits of Elliot Lake, Ontario, have thorium-rich uranium minerals that indicate a detrital origin. With the development of an oxygenic atmosphere before 1,700 m.y. ago, uranium was transported in solution in meteoric surface and near-surface ground water, and produced pitchblende veins in fractures in the basement and in lava flows in terrestrial environments. This accounts for the closee association of fluvial sediments with the pitchblende deposits at Beaverlodge, Rabbit Lake, Baker Lake, and Great Bear Lake, Canada. The development of land plants about 300 m.y. ago produced favorable environments within the terrestrial sandstones themselves, and resulted in the tabular uranium orebodies of the Colorado Plateau. The close relation of tabular orebodies to sedimentation is apparent when compared to recent fluvial sedimentation. In Wyoming, the stratigraphic restriction of the boundary-roll deposits to a few zones in Eocene rocks results from their being remobilized tabular deposits

On the theory system of hydrothermal uranium metallization in China

International Nuclear Information System (INIS)

Du Letian

2011-01-01

Based on summarizing the mass of research outcome of the predecessors, the author attempts to make a brief generalization on the theory system of hydrothermal uranium mineralization in China. The system of uranium metallization is founded in the basic way of uranium source-migration-transportation-richment-reservation. The system mainly consists of the following frames: (1) mineralization type of silification zone; (2) age gap of mineralization to host rock; (3) alkli metasomatism; (4) metallogenic layer of crust; (5)integratation of 4 types mineralization (granite, volcanics, carbonaceous-siliceous-argilaceous rock and sandstone) in tectonic-hydrothermal process; (6) pre-enrichment process of metallization; (7) decouplement of granite magma evolution; (8) types of rich ore by high tempreture sericitization; (9)basalt event;(10) rock and ore formation by HARCON. (authors)

Gneiss Macuira: tectonic evolution of Paleozoic metamorphic rocks of the Alta Guajira, Colombia

International Nuclear Information System (INIS)

Lopez I; A Julian; Zuluaga C; A, Carlos

2012-01-01

The Macuira Gneiss is a Paleozoic metamorphic unit that outcrops in the Simarua, Jarara and Macuira ranges, Alta Guajira. It is composed by a lithologies metamorphosed under amphibolite facies P-T conditions and consist of amphibolitic and quartz feldspathic gneisses, amphibolites, schists, pegmatites, calc-silicated rocks and marbles, with migmatization evidences in gneisses and amphibolites. Five foliations (S1-5) and three folding events (F1-3) were identified and interpreted as product of two metamorphic events, developed in a progressive barrovian metamorphic gradient of intermediate pressure with intermediate P-T ratio, interpreted as product of continental collision tectonics. This unit is important in understanding of the tectonic evolution of the Alta Guajira and Caribbean because it records different deformational phases pre-, syn- and post-migmatitic, that could be related with different tectonic episodes: the first associated with the collision between Laurasia and Gondwana (Alleghanian Orogeny - Late Paleozoic), and the second related with the Caribbean Plate evolution (Andean Orogeny - Meso-Cenozoic).

The fossil record, function, and possible origins of shell color patterns in Paleozoic marine invertebrates

Energy Technology Data Exchange (ETDEWEB)

Kobluk, D.R. (Univ. of Toronto, Ontario (Canada)); Mapes, R.H. (Ohio Univ., Athens (USA))

1989-02-01

Fossil invertebrate shells and carapaces displaying preserved original color patterns are among the rarest fossils. The fossil record of color patterns extends into the Middle Cambrian where the trilobite Anomocare displays a fan-like array of stripes on the pygidium. About 180 Paleozic genera are known with patterns, including trilobites, cephalopods, gastropods, brachiopods, bivalves, crinoids, and crustaceans. Based upon an analysis of these taxa, it appears that patterns and pigments in middle and late Paleozoic invertebrates may have served several functions such as warning displays, light screening, camouflage, or waste disposal. However, the presence of color patterns in fossil invertebrates in the early Paleozoic may have developed prior to the evolution of vision sufficiently sophisticated to see them. This suggests that camouflage and warning displays were not the original functions of color patterns, and that in the earliest Paleozoic they may not have been functional. The authors propose a hypothesis that involves three developmental phases in the evolution of invertebrate color patterns: (1) the incorporation of metabolic by-products, perhaps some pigmented and some not pigmented, into shells and carapaces as a means of disposal of dietary or metabolic wastes, (2) use of these pigments and patterns as an environmental adaptation, such as light screening, and (3) display during and following the evolution of vision in predators sufficiently sophisticated to see the patterns.

Use of boron nitride for neutron spectrum characterization and cross-section validation in the epithermal range through integral activation measurements

Science.gov (United States)

Radulović, Vladimir; Trkov, Andrej; Jaćimović, Radojko; Gregoire, Gilles; Destouches, Christophe

2016-12-01

A recent experimental irradiation and measurement campaign using containers made from boron nitride (BN) at the Jožef Stefan Institute (JSI) TRIGA Mark II reactor in Ljubljana, Slovenia, has shown the applicability of BN for neutron spectrum characterization and cross-section validation in the epithermal range through integral activation measurements. The first part of the paper focuses on the determination of the transmission function of a BN container through Monte Carlo calculations and experimental measurements. The second part presents the process of tayloring the sensitivity of integral activation measurements to specific needs and a selection of suitable radiative capture reactions for neutron spectrum characterization in the epithermal range. A BN container used in our experiments and its qualitative effect on the neutron spectrum in the irradiation position employed is displayed in the Graphical abstract.

The chemical industry of uranium in France

International Nuclear Information System (INIS)

Goldschmidt, B.

1955-01-01

The actual CEA program is concerned with the construction of two large graphite reactors, each of those containing at least one hundred tons of uranium metal with nuclear purity. The uranium for these two reactors will be regularly supplied by new resources discovered in France and Madagascar in the last five years. The working and treatment of such ore have led to the creation of an important french industry of which the general outline and principle are described. The operated ores have got different natures and concentration, individual characteristics are described for the main ores.The most high-grade ore are transported to a central plant in Bouchet near Paris; the low-grade ore are concentrated by physical methods or chemical processes of which principles and economy are studied with constancy. The acid processes are the only used until now, although the carbonated alkaline processes has been studied in France. The next following steps after the acid process until the obtention of uranium rich concentrate are described. The purification steps of uranium compounds to nuclear purity material are described as well as the steps to elaborate metal of which the purity grade will be specify. Finally, the economic aspects of uranium production difficulty will be considered in relation with technical progresses which we can expect to achieve in the future. (M.P.)

Uranium mineralization of the Witwatersrand and Dominion Reef systems

International Nuclear Information System (INIS)

Simpson, P.R.; Bowles, J.F.W.

1977-01-01

Uranium-bearing minerals in the Witwatersrand and Dominion Reef sediments have been studied by ore microscopic, electron microprobe, fission track and neutron activation analytical methods to determine the controls of uranium mineralization. In the Dominion Reef, which represents a high-energy banket type of depositional environment, allogenic thorian uraninite occurs in hydraulic equivalence with allogenic pyrite, quartz and possibly also gold in the sediments which have uranium-thorium ratios between 3.1 and 5.6 indicating substantial amounts of thorium-rich resistate minerals. The Witwatersrand sediments have uranium-thorium ratios ranging between 7.1 and 19.6 indicating lesser amounts of resistates which is consistent with the lower-energy depositional environment. The proximal or nearshore deposits are of banket type but are distinguished from the Dominion Reef by the abundance of concretionary pyrite formed within the Basin and the presence of carbonaceous matter. The distal deposits formed at greater distance from the shoreline contain decaying organic material which has precipitated both uranium and gold from solution. Subsequent metamorphism has resulted in the formation of carbonaceous material bearing finely disseminated low-thorium pitchblende and a fine dissemination of gold associated with sulphides and arsenides. (author)

Uranium Sequestration by Aluminum Phosphate Minerals in Unsaturated Soils

International Nuclear Information System (INIS)

Jerden, James L. Jr.

2007-01-01

A mineralogical and geochemical study of soils developed from the unmined Coles Hill uranium deposit (Virginia) was undertaken to determine how phosphorous influences the speciation of uranium in an oxidizing soil/saprolite system typical of the eastern United States. This paper presents mineralogical and geochemical results that identify and quantify the processes by which uranium has been sequestered in these soils. It was found that uranium is not leached from the saturated soil zone (saprolites) overlying the deposit due to the formation of a sparingly soluble uranyl phosphate mineral of the meta-autunite group. The concentration of uranium in the saprolites is approximately 1000 mg uranium per kg of saprolite. It was also found that a significant amount of uranium was retained in the unsaturated soil zone overlying uranium-rich saprolites. The uranium concentration in the unsaturated soils is approximately 200 mg uranium per kg of soil (20 times higher than uranium concentrations in similar soils adjacent to the deposit). Mineralogical evidence indicates that uranium in this zone is sequestered by a barium-strontium-calcium aluminum phosphate mineral of the crandallite group (gorceixite). This mineral is intimately inter-grown with iron and manganese oxides that also contain uranium. The amount of uranium associated with both the aluminum phosphates (as much as 1.4 weight percent) has been measured by electron microprobe micro-analyses and the geochemical conditions under which these minerals formed has been studied using thermodynamic reaction path modeling. The geochemical data and modeling results suggest the meta-autunite group minerals present in the saprolites overlying the deposit are unstable in the unsaturated zone soils overlying the deposit due to a decrease in soil pH (down to a pH of 4.5) at depths less than 5 meters below the surface. Mineralogical observations suggest that, once exposed to the unsaturated environment, the meta-autunite group

Translocation of uranium from water to foodstuff while cooking.

Science.gov (United States)

Krishnapriya, K C; Baksi, Ananya; Chaudhari, Swathi; Gupta, Soujit Sen; Pradeep, T

2015-10-30

The present work report the unusual uranium uptake by foodstuff, especially those rich in carbohydrates like rice when they are cooked in water, contaminated with uranium. The major staple diet in South Asia, rice, was chosen to study its interaction with UO2(2+), the active uranium species in water, using inductively coupled plasma mass spectrometry. Highest uptake limit was checked by cooking rice at very high uranium concentration and it was found to be good scavenger of uranium. To gain insight into the mechanism of uptake, direct interaction of UO2(2+) with monosaccharides was also studied, using electrospray ionization mass spectrometry taking mannose as a model. The studies have been done with dissolved uranium salt, uranyl nitrate hexahydrate (UO2(NO3)2·6H2O), as well as the leachate of a stable oxide of uranium, UO2(s), both of which exist as UO2(2+) in water. Among the eight different rice varieties investigated, Karnataka Ponni showed the maximum uranium uptake whereas unpolished Basmati rice showed the minimum. Interaction with other foodstuffs (potato, carrot, peas, kidney beans and lentils) with and without NaCl affected the extent of chemical interaction but was not consistent with the carbohydrate content. Uranium interaction with D-mannose monitored through ESI-MS, under optimized instrumental parameters, identified the peaks corresponding to uranyl adduct with mannose monomer, dimer and trimer and the species were confirmed by MS/MS studies. The product ion mass spectra showed peaks illustrating water loss from the parent ion as the collision energy was increased, an evidence for the strong interaction of uranium with mannose. This study would constitute the essential background for understanding interaction of uranium with various foods. Extension of this work would involve identification of foodstuff as green heavy metal scavengers. Copyright © 2015. Published by Elsevier B.V.

The South Greenland uranium exploration programme

International Nuclear Information System (INIS)

Armour-Brown, A.; Tukiainen, T.; Wallin, B.

1982-11-01

This is the final report of the reconnaissance phase of the SYDURAN Project which was initiated in 1st. December 1978 to outline areas of increased uranium potential where more detailed prospection would be warranted. Districts and smaller zones in South Greenland which have the potential for containing economically exploitable uranium occurrences were defined using airborne gamma-spectroscopic, reconnaissance geochemical and geological methods. Other districts and areas have been shown to have no uranium potential and can be eliminated. The three promising districts are: 1. a 2000 square kilometre sub-circular district surrounding Ilimaussaq complex in which there are small high grade pitchblende occurences in faults and fractures in the surrounding granite. 2. the eastern area of the Motzfeldt Centre where large parts of the centre is mineralised and may give rise to exploitable, large tonnage, low grade uranium ore with associated niobium and rare earth elements in extractable quantities. 3. uraniferous rich districts or zones associated with the migmatitic supracrustal units in the area between Kap Farvel and Lindenows Fjord. The areas which were eliminated from having any uranium potential include: the Ketilidian supracrustal unit. the Nunarssuit alkaline complex. The uranium mineralisation in South Greenland is confined to two Proterozoic episodes: a) a late phase of granitisation and migmatisation with the formation of disseminated uraninite in the Migmatite Complex in the south of the project area between 1700-1800 m.y. and, b) hydrothermal activity associated with Gardar magmatic events between 1090-1170 m.y. in the central Granite Zone. Future work should be directed towards the definition and location of drilling targets. (EG)

Application of epithermal neutron activation in multielement analysis of silicate rocks employing both coaxial Ge(Li) and low energy photon detector systems

Science.gov (United States)

Baedecker, P.A.; Rowe, J.J.; Steinnes, E.

1977-01-01

The instrumental activation analysis of silicate rocks using epithermal neutrons has been studied using both high resolution coaxial Ge(Li) detectors and low energy photon detectors, and applied to the determination of 23 elements in eight new U.S.G.S. standard rocks. The analytical use X-ray peaks associated with electron capture or internal conversion processes has been evaluated. Of 28 elements which can be considered to be determinable by instrumental means, the epithermal activation approach is capable of giving improved sensitivity and precision in 16 cases, over the normal INAA procedure. In eleven cases the use of the low energy photon detector is thought to show advantages over convertional coaxial Ge(Li) spectroscopy. ?? 1977 Akade??miai Kiado??.

Geology of the epithermal Ag-Au Huevos Verdes vein system and San José district, Deseado massif, Patagonia, Argentina

Science.gov (United States)

Dietrich, Andreas; Gutierrez, Ronald; Nelson, Eric P.; Layer, Paul W.

2012-03-01

The San José district is located in the northwest part of the Deseado massif and hosts a number of epithermal Ag-Au quartz veins of intermediate sulfidation style, including the Huevos Verdes vein system. Veins are hosted by andesitic rocks of the Bajo Pobre Formation and locally by rhyodacitic pyroclastic rocks of the Chon Aike Formation. New 40Ar/39Ar constraints on the age of host rocks and mineralization define Late Jurassic ages of 151.3 ± 0.7 Ma to 144.7 ± 0.1 Ma for volcanic rocks of the Bajo Pobre Formation and of 147.6 ± 1.1 Ma for the Chon Aike Formation. Illite ages of the Huevos Verdes vein system of 140.8 ± 0.2 and 140.5 ± 0.3 Ma are 4 m.y. younger than the volcanic host rock unit. These age dates are among the youngest reported for Jurassic volcanism in the Deseado massif and correlate well with the regional context of magmatic and hydrothermal activity. The Huevos Verdes vein system has a strike length of 2,000 m, with several ore shoots along strike. The vein consists of a pre-ore stage and three main ore stages. Early barren quartz and chalcedony are followed by a mottled quartz stage of coarse saccharoidal quartz with irregular streaks and discontinuous bands of sulfide-rich material. The banded quartz-sulfide stage consists of sulfide-rich bands alternating with bands of quartz and bands of chlorite ± illite. Late-stage sulfide-rich veinlets are associated with kaolinite gangue. Ore minerals are argentite and electrum, together with pyrite, sphalerite, galena, chalcopyrite, minor bornite, covellite, and ruby silver. Wall rock alteration is characterized by narrow (propylitic alteration. Gangue minerals are dominantly massive quartz intergrown with minor to accessory adularia. Epidote, illite, illite/smectite, and, preferentially at deeper levels, Fe-chlorite gangue indicate near-neutral pH hydrothermal fluids at temperatures of >220°C. Kaolinite occurring with the late sulfide-rich veinlet stage indicates pH 315°, whereas strike

Mineralogical and geochemical characteristics of uranium-rich fluoriteinEl-Missikat mineralized granite,Central Eastern Desert, Egypt

Directory of Open Access Journals (Sweden)

Mohamed Fahmy Raslan

2009-12-01

Full Text Available A unique, highly radioactive variety of fluor it emineral has been recorded in the uranium occurrence of El-Missikat sheared granite pluton. In this occurrence, the uranium assumes different forms, including its presence as discrete, visible, secondary minerals, rare uraninite and its association with the jasperoid and silica veinlets. However,in some other parts of the sheared zone, the uranium was found to be solely incorporated with fluorite crystals,filling veinlet sand fractures with out any other manife station.This paper focuses ont her elevant mineralogical and geochemical characteristics of this unique fluorite variety.In addition to an investigation with binocular and polarizing microscopes, the separated fluorite grains were analyzed usingan environmental scanning electronmicroscope(ESEM and a field-emission scanning electron microscope.In addition to this,some fluorite crystals were subjected to electron microprobe analyses. While the fluorite accounted for as much as 20% of the sheared granite samples studied, it was found to range from 82 to 96 % in the different size fractions of the separated heavy mineral content. In some parts of the separated fluorite crystals,uranium inquantities of up to 2200 ppm was found to be heterogeneously distributed in the fluoritelattice,regardless of its coloration.

Oral Region Homologies in Paleozoic Crinoids and Other Plesiomorphic Pentaradial Echinoderms

OpenAIRE

Kammer, Thomas W.; Sumrall, Colin D.; Zamora, Samuel; Ausich, William I.; Deline, Bradley

2013-01-01

The phylogenetic relationships between major groups of plesiomorphic pentaradial echinoderms, the Paleozoic crinoids, blastozoans, and edrioasteroids, are poorly understood because of a lack of widely recognized homologies. Here, we present newly recognized oral region homologies, based on the Universal Elemental Homology model for skeletal plates, in a wide range of fossil taxa. The oral region of echinoderms is mainly composed of the axial, or ambulacral, skeleton, which apparently evolved ...

Metallogenic geologic conditions and prospecting direction of sandstone type uranium mineralizations in Yili basin of Xinjiang

International Nuclear Information System (INIS)

Chen Daisheng; Wang Ruiying; Li Shengxiang; Zhang Kefang

1994-09-01

Yili basin is a Mesozoic down-warped basin superimposed on the late Paleozoic volcanic taphrogenic basin. Uranium mineralizations are hosted in the Middle-Lower Jurassic coal-bearing series. The depositions environment in the basin is turbulent in the east and relatively stable in the west. It is characterized by coarse-grained sequence with thin thickness in the eastern part and fine-grained with thick thickness in the western part. On the analytical basis of sedimentary facies indices, it is the first time to present a sedimentary model of 'alluvial fan-braided stream-(narrow) lakeshore delta-lacustrine facies and marsh facies' for the coal-bearing series. The authors have summarized the basic geologic features of U-mineralizations in the interlayer oxidation zone, analyzed the difference and cause of U-mineralizations between the south and north, as well as the east and west. The genetic mechanism of U-mineralizations in the basin is discussed. Finally, seven items of geologic prerequisites for the formation of in-situ leachable sandstone type uranium deposits have been suggested and the potential of sandstone type U-mineralizations in the basin has been evaluated. Four promising target areas are selected

Uranium

International Nuclear Information System (INIS)

Hamdoun, N.A.

2007-01-01

The article includes a historical preface about uranium, discovery of portability of sequential fission of uranium, uranium existence, basic raw materials, secondary raw materials, uranium's physical and chemical properties, uranium extraction, nuclear fuel cycle, logistics and estimation of the amount of uranium reserves, producing countries of concentrated uranium oxides and percentage of the world's total production, civilian and military uses of uranium. The use of depleted uranium in the Gulf War, the Balkans and Iraq has caused political and environmental effects which are complex, raising problems and questions about the effects that nuclear compounds left on human health and environment.

Structural Characteristics of Paleozoic and Geological Significance of Oil and Gas of Dongpu Depression

Institute of Scientific and Technical Information of China (English)

杨世刚

2003-01-01

The Dongpu depression has experienced a complicated evolution of structure since Mesozoic. The Paleozoic carbonate rock has been strongly reformed and the buried hills with different characteristics of structure are developed in the depression. There exist lots of groups of fault structures with strikes of NNE(or NE),NW, near NS and EW etc., of which the faults with strikes of NNE and NW play an important controlling role on present-day structural framework of the depression. The faults with near NS-striking and EW-striking deeply affect the establishment of structural framework of basement of the depression. Although most of the fractures are filled by calcite and other minerals, under the action of later structural stress, the earlier fractures could change their features into tensional ones. Therefore, much attention should be paid to the exploration and exploitation of Paleozoic oil and gas in Dongpu depression.

Results of uranium HSSR survey of the San Juan area southwestern Colorado

International Nuclear Information System (INIS)

Maxwell, J.C.

1977-01-01

During June--July 1976, 1706 water samples and 1982 sediment samples were collected from 1995 sites in the San Juan Mountains area and analyzed for uranium. The area includes the southern third of the Colorado mineral belt which has yielded rich ores of gold, silver, copper, lead, zinc, and molybdenum. The broadly domed mountains are capped by 2500 m of Tertiary volcanics, deeply eroded to expose a Precambrian crystalline core. Adjacent plateaus underlain by Mesozoic sedimentary rocks were included in the reconnaissance. Average value of uranium in water samples from mountains was less than 0.5 ppB, from plateaus was 1 to 2 ppB, and from Mancos shale areas exceeded 2 ppB. Anomalous sediment samples, 40 ppM uranium, came from near Storm King Mountain and upper Vallecito Creek. Other anomalous areas, including the Lake City mining district, were well defined by 4 to 30 ppM uranium in sediment and 3 to 30 ppB uranium in water. Above-average concentrations of uranium not previously reported indicate areas favorable for detailed exploration

International Uranium Resources Evaluation Project (IUREP) national favourability studies: France

International Nuclear Information System (INIS)

1977-09-01

France, with an area of 550,000 km 2 , has been prospecting its territory for uranium for more than 30 years. The proven uranium reserves in all the ore categories defined by the NEA/lAEA are estimated at around 120,000 tU, of which 25,000 tU have already been mined. About 70% of these reserves are associated with granites, while the bulk of the remainder is located in Permian sediments and the last in Paleogene sediments. The prospecting effort has not been distributed equally over French territory. More than half of it - recent orogens and large basins - have been little or very little prospected. On the other hand, the Hercynian massifs and their Upper Paleozoic mantle have been systematically prospected. Nevertheless, even within the latter there is still room for further exploration: extensions of already known mineralizations both laterally and vertically, conventional mineralizations deep down or under a mantle, types of mineralizations not investigated previously (those associated with acid or intermediate vulcanism, peribatholithic shales, alkaline complexes etc.). Of course, in the areas that have not been so well explored, because they appear less favourable, there are still some possibilities, namely, in the areas of recent orogens, mineralizations associated with antemesozoic cores (same types as above) or directly associated with orogenesis (slightly to moderately metamorphic sandstone-phyllitic formations, certain sedimentary formations etc.). As for the large basins, they are capable of containing mineralizations associated with some of their formations (Paleogene of the Basin of Aquitaine etc), but they may also cover workable uranium deposits. It is possible that, in the not to distant future access may be gained to such ores in particular cases. On this basis it does not seem unreasonable to reckon with the discovering of new resources of an order of magnitude between half and the same as those already found. (author)

Palynological study (spores, Acritarchs and Chitinozoans) in the paleozoic (Cambrian to Dinantian) of western and meridional Morocco (biostratigraphy, paleo-bio-geography and characterisation of organic matter); Etude palynologique (spores, Chitinozoaires, Acritarches) dans le Paleozoique: Cambrien a Dinantien du Maroc occidental et meridional (biostratigraphie, paleobiogeographie et caracterisation de la matiere organique)

Energy Technology Data Exchange (ETDEWEB)

Rahmani, K.

1995-01-27

The palynological study of paleozoic levels in ten wells and two cross sections in western and meridional Morocco has permit to establish the inventory of organic micro-fossils. Some of these are spores and Acritarchs which constitute much rich and more conserved than to Chitinozoans. The different associations yield from the middle Cambrian to the lower Carboniferous have allowed the setting of a bio-zonation. This latter, consists of 7 biozones based on Carboniferous and Acritarchs in the lower Paleozoic, and 12 biozones in the Devonian and lower Carboniferous based essentially on the spores. This bio-zonation however, does not provide full information. This is due to the degradation of the micro-fossils, their absence of an unsuitable facies, a shortage of samples, erosion or lack of sedimentation. Most of these short comings were dated and their importance was considered in relation to the different epeirogeny known in Morocco. The biozones distinguished were based on index taxa of spores, Chitinozoans or Acritarchs which coexist with biostratigraphic micro-fossils in Morocco or in others regions referred to. This biozones allowed: the indication of the precision of many subdivisions within the Paleozoic of the studied areas the setting of local, regional and intercontinental correlations, subsequently: Anti-Atlas, Moroccan Meseta, Algeria, Libya, North, America, Canada and Europe. The paleo-bio-geographic evolution traced from the middle Cambrian to the lower Carboniferous has demonstrated that the position of Morocco between north Gondwana and Avalonia zone at the lower Paleozoic and between Africa and Europe during the upper Paleozoic, has associated this area to different geological phenomena. Morocco also constituted a paleo-bio-geographic bridge which has allowed diverse exchanges, especially floristic one, between the Gondvanian and the Laurasian domains. This privileged position of Morocco in the geographic and geologic line has certainly influenced the

Uranium extraction from gold-uranium ores

Energy Technology Data Exchange (ETDEWEB)

Laskorin, B.N.; Golynko, Z.Sh.

1981-01-01

The process of uranium extraction from gold-uranium ores in the South Africa is considered. Flowsheets of reprocessing gold-uranium conglomerates, pile processing and uranium extraction from the ores are presented. Continuous counter flow ion-exchange process of uranium extraction using strong-active or weak-active resins is noted to be the most perspective and economical one. The ion-exchange uranium separation with the succeeding extraction is also the perspective one.

Testing the limits of Paleozoic chronostratigraphic correlation via high-resolution (13Ccarb) biochemostratigraphy across the Llandovery–Wenlock (Silurian) boundary: Is a unified Phanerozoic time scale achievable?

Science.gov (United States)

Cramer, Bradley D.; Loydell, David K.; Samtleben, Christian; Munnecke, Axel; Kaljo, Dimitri; Mannik, Peep; Martma, Tonu; Jeppsson, Lennart; Kleffner, Mark A.; Barrick, James E.; Johnson, Craig A.; Emsbo, Poul; Joachimski, Michael M.; Bickert, Torsten; Saltzman, Matthew R.

2010-01-01

The resolution and fidelity of global chronostratigraphic correlation are direct functions of the time period under consideration. By virtue of deep-ocean cores and astrochronology, the Cenozoic and Mesozoic time scales carry error bars of a few thousand years (k.y.) to a few hundred k.y. In contrast, most of the Paleozoic time scale carries error bars of plus or minus a few million years (m.y.), and chronostratigraphic control better than ??1 m.y. is considered "high resolution." The general lack of Paleozoic abyssal sediments and paucity of orbitally tuned Paleozoic data series combined with the relative incompleteness of the Paleozoic stratigraphic record have proven historically to be such an obstacle to intercontinental chronostratigraphic correlation that resolving the Paleozoic time scale to the level achieved during the Mesozoic and Cenozoic was viewed as impractical, impossible, or both. Here, we utilize integrated graptolite, conodont, and carbonate carbon isotope (??13Ccarb) data from three paleocontinents (Baltica, Avalonia, and Laurentia) to demonstrate chronostratigraphic control for upper Llando very through middle Wenlock (Telychian-Sheinwoodian, ~436-426 Ma) strata with a resolution of a few hundred k.y. The interval surrounding the base of the Wenlock Series can now be correlated globally with precision approaching 100 k.y., but some intervals (e.g., uppermost Telychian and upper Shein-woodian) are either yet to be studied in sufficient detail or do not show sufficient biologic speciation and/or extinction or carbon isotopic features to delineate such small time slices. Although producing such resolution during the Paleozoic presents an array of challenges unique to the era, we have begun to demonstrate that erecting a Paleozoic time scale comparable to that of younger eras is achievable. ?? 2010 Geological Society of America.

Midwest Joint Venture high-grade uranium mining

International Nuclear Information System (INIS)

Fredrickson, H.K.

1992-01-01

Midwest Joint Venture (MJV) owns a high-grade uranium deposit in northern Saskatchewan. The deposit is located too deep below surface to be mined economically by open pit methods, and as a consequence, present plans are that it will be mined by underground methods. High-grade uranium ore of the type at MJV, encased in weak, highly altered ground and with radon-rich water inflows, has not before been mined by underground methods. The test mining phase of the project, completed in 1989, had three objectives: To evaluate radiation protection requirements associated with the handling of large quantities of radon-rich water and mining high-grade uranium ore in an underground environment; to investigate the quantity and quality of water inflows into the mine; and, to investigate ground conditions in and around the ore zone as an aid in determining the production mining method to be used. With information gained from the test mining project, a mining method for the production mine has been devised. Level plans have been drawn up, ventilation system designed, pumping arrangements made and methods of ore handling considered. All this is to be done in a manner that will be safe for those doing the work underground. Some of the mining methods planned are felt to be unique in that they are designed to cope with mining problems not known to have been encountered before. New problems underground have required new methods to handle them. Remote drilling, blasting, mucking and backfilling form the basis of the planned mining method

Aerial gamma ray and magnetic survey, Huntington quadrangle: Ohio, West Virginia and Kentucky. Final report

International Nuclear Information System (INIS)

1981-04-01

The Huntington quadrangle of Kentucky, Ohio, and West Virginia covers 7250 square miles of the easternmost Midwestern Physiographic Province. Paleozoic exposures dominate the surface. These Paleozoics deepen toward the east from approximately 500 feet to a maximum depth of 8000 feet. Precambrian basement is thought to underlie the entire area. No known uranium deposits exist in the area. One hundred anomalies were found using the standard statistical analysis. Some high uranium concentration anomalies that may overlie the stratigraphic equivalent of the Devonian-Mississippian New Albany or Chattanooga Shales may represent significant levels of naturally occurring uranium. Future studies should concentrate on this unit. Magnetic data are largely in concurrence with existing structural interpretations but suggest some complexities in the underlying Precambrian

Corporate citizenship and the Saskatchewan uranium industry

International Nuclear Information System (INIS)

Michel, B.M.

1995-01-01

Saskatchewan has vast and rich uranium deposits which in 1994 contributed almost 30% to world uranium production. There are only two mining operators in the province which is subject to the overlapping jurisdictions of the provincial and federal governments. The sparse population consists of two distinct groups, a minority population of people of native ancestry in the north and people typical of most North American rural communities living in the south. Each has its own concerns and expectations with respect to the mining operations and nuclear power. The comprehensive community relations programme set up by the mining industry against this background is described. It includes trying to address concerns, offering training, employment and business opportunities, and supporting the social and cultural aspects of community life. (UK)

International Uranium Resources Evaluation Project (IUREP) national favourability studies: Sri Lanka

International Nuclear Information System (INIS)

1977-10-01

Sri Lanka is essentially a detached portion of the Deccan Plateau of south India and like it, is underlain almost everywhere by hard old Precambrian rocks. Prior to 1940 there was no systematic organised geological survey work on the island. Between 1957 and 1962 a partial aerial survey and field traverses were conducted in a search for radio- active minerals. Since then a modest programme has continued. Thorianite was first discovered in placer deposits in 1903 and prospecting has found many other refractory radioactive minerals probably derived from the weathering of pegmatites. Monazite is found as an important constituent of beach placer deposits and it is estimated to have an average content of 8-10%ThO 2 and 0.3 - 0.5% U 3 O 8 . Up to 1000 tons monazite per year could be produced from the beach sand industry. Sri Lanka has had very little systematic exploration for uranium and as it is largely composed of Precambrian rocks it deserves closer attention. On the other hand it is part of a thorium rich province and there is a body of technical opinion that believes that thorium rich provinces are unlikely to contain significant uranium deposits. For these reasons it is estimated that the Speculative Potential may be within the range of 1000 to 10,000 tonnes uranium. In addition it maybe possible to produce up to 5 tonnes uranium and 100 tonnes thorium from the beach sand industry on an annual basis. (author)

Deep groundwater redox reactions in the Palmottu uranium deposit: The role of uranium and iron in these processes

International Nuclear Information System (INIS)

Bruno, J.; Cera, E.; Duro, L.; Ahonen, L.

1996-12-01

The reduction oxidation properties of the deep bedrock and groundwater are important geochemical factors with respect to the chemical stability of the multibarrier system, which isolates the disposed nuclear fuel from biosphere. In the report are described the results of the redox experiments carried out in the field using the natural groundwaters of Palmottu, in Nummi-Pusula, Finland. The experiments include (1) measurements of natural water redox potential values during four to eight hours continuous pumping; (2) monitoring of the redox-potential response to an artificial change of pH of the groundwater. Separate tests were made in iron and uranium-rich groundwaters, respectively. The data of the field experiments were used in the redox-modelling of the iron and uranium systems. In accordance with earlier knowledge, it was showed that dissolved iron is an important redox electrolyte in natural waters, at least at concentration levels of milligrams per liter. However, a striking observation was that in the absence of dissolved iron dissolved uranium (in concentrations of about 200 nM or more) seems to be able to give nernstian response on platinum electrode in acid/base titrations. The effective redox properties of the bedrock-groundwater system depend on the availability and reactivity of solid phases able to exchange electrons with dissolved redox electrolytes. The present results indicate that, in the bedrock/groundwater system of the Palmottu uranium mineralization, uranium minerals are important redox buffers. (orig.) (refs.)

Method for converting uranium oxides to uranium metal

International Nuclear Information System (INIS)

Duerksen, W.K.

1988-01-01

A method for converting uranium oxide to uranium metal is described comprising the steps of heating uranium oxide in the presence of a reducing agent to a temperature sufficient to reduce the uranium oxide to uranium metal and form a heterogeneous mixture of a uranium metal product and oxide by-products, heating the mixture in a hydrogen atmosphere at a temperature sufficient to convert uranium metal in the mixture to uranium hydride, cooling the resulting uranium hydride-containing mixture to a temperature sufficient to produce a ferromagnetic transition in the uranium hydride, magnetically separating the cooled uranium hydride from the mixture, and thereafter heating the separated uranium hydride in an inert atmosphere to a temperature sufficient to convert the uranium hydride to uranium metal

Pacing of Paleozoic macroevolutionary rates by Milankovitch grand cycles.

Science.gov (United States)

Crampton, James S; Meyers, Stephen R; Cooper, Roger A; Sadler, Peter M; Foote, Michael; Harte, David

2018-05-29

Periodic fluctuations in past biodiversity, speciation, and extinction have been proposed, with extremely long periods ranging from 26 to 62 million years, although forcing mechanisms remain speculative. In contrast, well-understood periodic Milankovitch climate forcing represents a viable driver for macroevolutionary fluctuations, although little evidence for such fluctuation exists except during the Late Cenozoic. The reality, magnitude, and drivers of periodic fluctuations in macroevolutionary rates are of interest given long-standing debate surrounding the relative roles of intrinsic biotic interactions vs. extrinsic environmental factors as drivers of biodiversity change. Here, we show that, over a time span of 60 million years, between 9 and 16% of the variance in biological turnover (i.e., speciation probability plus species extinction probability) in a major Early Paleozoic zooplankton group, the graptoloids, can be explained by long-period astronomical cycles (Milankovitch "grand cycles") associated with Earth's orbital eccentricity (2.6 million years) and obliquity (1.3 million years). These grand cycles modulate climate variability, alternating times of relative stability in the environment with times of maximum volatility. We infer that these cycles influenced graptolite speciation and extinction through climate-driven changes to oceanic circulation and structure. Our results confirm the existence of Milankovitch grand cycles in the Early Paleozoic Era and show that known processes related to the mechanics of the Solar System were shaping marine macroevolutionary rates comparatively early in the history of complex life. We present an application of hidden Markov models to macroevolutionary time series and protocols for the evaluation of statistical significance in spectral analysis.

Epithermal neutron flux distribution and its impact on (n, γ) activation analysis result

International Nuclear Information System (INIS)

Jovanovich, S.; Pukotich, P.; Zejnilovich, R.; Corte, F. de; Moens, L.; Hoste, J.; Simonitis, A.

1985-01-01

The differences are discussed between the simplified model, introduced to derive the generally accepted ideal 1/E - law, and the conditions existing in an actual reactor. For absolute and comparator types of (n, γ) activation analysis (NAA), the semiempirical 1/Esup(1+α) form is a better approximation - necessary to introduce, but sufficient for practical purposes. Parameter α, being a measure of the epithermal nonideality, is a characteristics of the reactor site. The impact of this nonideality on NAA result is outlined, together with the method for appropriate correction

A uranium-bearing coalificated wood remain from the Upper Carboniferous uranium ore deposit in the Baden-Baden region of the Black Forest

International Nuclear Information System (INIS)

Kirchheimer, F.

1981-01-01

From the 1973 discovered Upper Carboniferous uranium ore sandstone deposit in the Baden-Baden region (Black Forest) a uranium-bearing coalificated wood remain derived, probably the relic of a Cordaites-trunk. The chemical determinated whole uranium content of this amounts about to 40 wght.-%. Pitchblende of the collomorphic type is embedded in the vitrinite of the fossil and imitates the nearly destroyed former wood-structure. The aggregates of this mineral, surrounded by zones of contact, consist of at least two modifications of different reflectance and hardness. Radiometric analyses reveale a different disturbed radioactive equilibrium, which indicated partly loss and re-enrichment of the uranium-content in recent time. A part of the fossil is completely mineralized by pitchblende of high reflectance and associated galena. For this paragenesis the radiometric investigations proved an approached equilibrium of radioactive substances. Therefore it is to be estimated, that the pitchblende is not alterated substantially, in contrast to the embeddings in the vitrinite, rich in little reflecting and soft nasturanium. The inhomogenic mineralization of the highly coalificated fossil, also to recognise microscopically, is set in relation to the controverse genetic interpretation of the deposit. Final remarks are concerned to other uranium-enriched fossils, especially remains of bones of different origin and age. (orig.) [de

8-group relative delayed neutron yields for epithermal neutron induced fission of 235U and 239Pu

International Nuclear Information System (INIS)

Piksaikin, V.M.; Kazakov, L.E.; Isaev, S.G.; Korolev, G.G.; Roshchenko, V.A.; Tertychnyj, R.G

2002-01-01

An 8-group representation of relative delayed neutron yields was obtained for epithermal neutron induced fission of 235 U and 239 Pu. These data were compared with ENDF/B-VI data in terms of the average half- life of the delayed neutron precursors and on the basis of the dependence of reactivity on the asymptotic period. (author)

The current situation of uranium resources exploration in East China: Problems, thought and countermeasure

International Nuclear Information System (INIS)

He Xiaomei; Mao Mengcai

2014-01-01

Based on analyzing the current situation of uranium resources and exploration effort in East China, the main existing problems, technical thought and countermeasure for the future exploration in East China are discussed in this paper. The degree of both uranium exploration and study in East China is relatively high, philosophy of scientific mineral-prospecting should be established in the new round of mineral prospecting. Under guidance of metallogenic theory of large mineralization cluster area and uranium metallogenic theory of multi-sources, previous data and research achievement should be analyzed and summarized. With the help of metallogenic model, useful methods and means should be applied to set up exploration model in order to realize news phase of model exploration, comprehensive exploration, 3D exploration and quantitative exploration. Efficiency of exploration of uranium resources should be strugglingly increased. High profitable uranium resources will be actively found with rich, shallow, near and easy features. The prospecting targets and strategy reserves of uranium resources will be increased in East China. (authors)

Characteristics of hydrothermal alteration mineralogy and geochemistry of igneous rocks from the epithermal Co-O mine and district, Eastern Mindanao (Philippines)

Science.gov (United States)

Sonntag, Iris; Hagemann, Steffen

2010-05-01

Detailed petrographic as well as hyperspectral analyses using PIMA (Portable Infrared Mineral Analyser) and geochemical (major, trace and rare earth elements) studies were conducted on samples of the epithermal, low sulfidation Co-O mine (47,869 ounces gold produced in 2009 with an average grade of 13.3 g/t gold) and district in Eastern Mindanao (Philippines). The aims of the study were to unravel the petrogenetic origin of the various volcanic (host rocks) and intrusive rocks (potential fluid driver) as well as their relationship and influence on the hydrothermal alteration zoning and fluid chemistry. The auriferous veins at the Co-O mine were formed during two hydrothermal stages associated with the district wide D1 and D2 deformation events. Gold in stage 1 quartz veins is in equilibrium with galena and sphalerite, whereas in stage 2 it is associated with pyrite. Auriferous quartz veins of stage 1 reflect temperatures below 250° C or strong variations in pH and fO2 at higher temperatures, due to potential involvement of acidic gas or meteoric water. Cathodoluminescense studies revealed strong zonation of quartz associated with Au, presumably related to changes in the Al content, which is influenced by the pH. Plumose textures indicate times of rapid deposition, whereas saccharoidal quartz grains are related to potential calcite replacement. The geology of the Co-O mine and district is dominated by Miocene volcanic rocks (basic to intermediate flows and pyroclastics units), which are partly covered by Pliocene volcanic rocks and late Oligocene to Miocene limestones. The Miocene units are intruded by diorite (presumably Miocene in age). The epithermal mineralization event may be related to diorite intrusions. The geochemistry of all igneous rocks in the district is defined by a sub-alkaline affinity and is low to medium K in composition. Most units are related to a Miocene subduction zone with westward subduction, whereas the younger Pliocene rocks are related to

Optimization in Activation Analysis by Means of Epithermal Neutrons. Determination of Molybdenum in Steel

Energy Technology Data Exchange (ETDEWEB)

Brune, D; Jirlow, J

1963-12-15

Optimization in activation analysis by means of selective activation with epithermal neutrons is discussed. This method was applied to the determination of molybdenum in a steel alloy without recourse to radiochemical separations. The sensitivity for this determination is estimated to be 10 ppm. With the common form of activation by means of thermal neutrons, the sensitivity would be about one-tenth of this. The sensitivity estimations are based on evaluation of the photo peak ratios of Mo-99/Fe-59.

Reworked crustal of early Paleozoic WuYi Orogen revealed by receiver function data

Science.gov (United States)

Wei, Y.; Duan, Y.; Tian, X.; Zhao, Y.

2017-12-01

Intraplate orogenic belt, which occurs at the rigid and undeformable plate interiors, is a distinct new type of orogen rather than an interplate or plate marginal orogenic belt, whose deformation occurs exclusively at plate margins. Therefore, intraplate orogenic belts are the most obvious exception to the plate-tectonic paradigm, they are uncommon in Earth's history. The early Paleozoic Wuyi orogen in South China is one of the few examples of intraplate orogen, and is a key to understanding the process of intraplate orogenesis and global early Paleozoic geodynamics. In this study, we select teleseismic records from 45 mobile linear seismic stations deployed in Wuyi Mountain and 58 permanent stations setting in Jiangxi and Fujian provinces, from January 2011 to December 2012, and calculate the crustal thickness and average crustal Vp/Vs ratio using the H-κ stacking method. The main results include the following: 1) the crustal average Poission's ratio shows an increase tendency from land to sea, the interior of Wuyi orogen belt with an low ration less than 0.23, and the coastline with high ration which is up to 0.28, which indicate a very heterogeneous crustal structure and composition in Wuyi orogen and coast belt. 2) the crustal thickness ranges 28-34 km and shows a tendency of thinning from inland to coast in the region of SE China margin, which maight mean the eastern Eurasia lithospheric is extension and thinning induced by the subducted paleo-Pacific slab. To conclusion, we assume that Wuyi orogen experienced upper crustal thickening, lower crust and lithosphere delamination during the early Paleozoic orogeny, and lithosphere extension in Mesozoic. This research is founded by the Natural Science Foundation of China (41174052 and 41604048).

Method for converting uranium oxides to uranium metal

Science.gov (United States)

Duerksen, Walter K.

1988-01-01

A process is described for converting scrap and waste uranium oxide to uranium metal. The uranium oxide is sequentially reduced with a suitable reducing agent to a mixture of uranium metal and oxide products. The uranium metal is then converted to uranium hydride and the uranium hydride-containing mixture is then cooled to a temperature less than -100.degree. C. in an inert liquid which renders the uranium hydride ferromagnetic. The uranium hydride is then magnetically separated from the cooled mixture. The separated uranium hydride is readily converted to uranium metal by heating in an inert atmosphere. This process is environmentally acceptable and eliminates the use of hydrogen fluoride as well as the explosive conditions encountered in the previously employed bomb-reduction processes utilized for converting uranium oxides to uranium metal.

Late Archaean-early Proterozoic source ages of zircons in rocks from the Paleozoic orogen of western Galicia, NW Spain

Energy Technology Data Exchange (ETDEWEB)

Kuijper, R P; Priem, H N.A. [Laboratorium voor Isotopen-Geologie, Amsterdam (Netherlands); Den Tex, E [Rijksuniversiteit Utrecht (Netherlands). Inst. voor Aardwetenschappen

1982-08-01

U-Pb data are reported for nine suites of zircons and three monazites from the Paleozoic orogen in western Galicia: one paragneiss and six orthogneisses from the early Paleozoic basement, and two Carboniferous (ca. 310 Ma old) intrusions of two-mica granite. New whole-rock Rb-Sr analyses, along with earlier data, indicate an age of ca. 470-440 Ma (Ordovician) for the emplacement of the granitic precursors of the orthogneisses. Monazite from the paragneiss also yields an U-Pb age of ca. 470 Ma. From the high initial /sup 87/Sr//sup 86/Sr ratios an involvement of Precambrian continental crust material is evident in the generation of the early Paleozoic suite of granites, while the zircon U-Pb data give evidence of the presence of about 3.0-2.0 Ga old (late Archaean-early Proterozoic) components in the source material. Zircons from the oldest sedimentary rocks in the area, now present as catazonal paragneisses and a likely source for the granites, likewise reveal a provenance age of 3.0-2.0 Ga.

A preliminary inter-centre comparison study for photon, thermal neutron and epithermal neutron responses of two pairs of ionisation chambers used for BNCT

International Nuclear Information System (INIS)

Roca, Antoaneta; Liu, Yuan-Hao; Wojnecki, Cecile; Green, Stuart; Nievaart, Sander; Ghani, Zamir; Moss, Ray

2009-01-01

The dual ionisation chamber technique is the recommended method for mixed field dosimetry of epithermal neutron beams. This paper presents initial data from an ongoing inter-comparison study involving two identical pairs of ionisation chambers used at the BNCT facilities of Petten, NL and of University of Birmingham, UK. The goal of this study is to evaluate the photon, thermal neutron and epithermal neutron responses of both pairs of TE(TE) (Exradin T2 type) and Mg(Ar) (Exradin M2 type) ionisation chambers in similar experimental conditions. At this stage, the work has been completed for the M2 type chambers and is intended to be completed for the T2 type chambers in the near future.

Filtered epithermal quasi-monoenergetic neutron beams at research reactor facilities

International Nuclear Information System (INIS)

Mansy, M.S.; Bashter, I.I.; El-Mesiry, M.S.; Habib, N.; Adib, M.

2015-01-01

Filtered neutron techniques were applied to produce quasi-monoenergetic neutron beams in the energy range of 1.5–133 keV at research reactors. A simulation study was performed to characterize the filter components and transmitted beam lines. The filtered beams were characterized in terms of the optimal thickness of the main and additive components. The filtered neutron beams had high purity and intensity, with low contamination from the accompanying thermal emission, fast neutrons and γ-rays. A computer code named “QMNB” was developed in the “MATLAB” programming language to perform the required calculations. - Highlights: • Quasi-monoenergetic neutron beams in energy range from (1.5–133) keV. • Interference between the resonance and potential scattering amplitudes. • Epithermal neutron beams used in BNCT

Study on reprocessing of uranium-thorium fuel with solvent extraction for HTGR

International Nuclear Information System (INIS)

Jiao Rongzhou; He Peijun; Liu Bingren; Zhu Yongjun

1992-08-01

A single cycle process by solvent extraction with acid feed solution is suggested. The purpose is to reprocess uranium-thorium fuel elements which are of high burn-up and rich of 232 U from HTGR (high temperature gas cooled reactor). The extraction cascade tests have been completed. The recovery of uranium and thorium is greater than 99.6%. By this method, the requirement, under remote control to re-fabricate fuel elements, of decontamination factors for Cs, Sr, Zr-Nb and Ru has been reached

Late Paleozoic volcanic rocks of the Intra-Sudetic Basin, Bohemian Massif: Petrological and geochemical characteristics

Czech Academy of Sciences Publication Activity Database

Ulrych, Jaromír; Fediuk, F.; Lang, Miloš; Martinec, Petr

2004-01-01

Roč. 64, č. 2 (2004), s. 127-153 ISSN 0009-2819 R&D Projects: GA AV ČR(CZ) IAA3013903 Keywords : Late Paleozoic * volcanic rocks * Bohemian Massif Subject RIV: DB - Geology ; Mineralogy Impact factor: 0.643, year: 2004

Two possibilities for New Siberian Islands terrane tectonic history during the Early Paleozoic based on paleomagnetic data

Science.gov (United States)

Metelkin, Dmitry V.; Chernova, Anna I.; Vernikovsky, Valery A.; Matushkin, Nikolay Yu.

2017-04-01

The New Siberian Islands (NSI), located in the East Siberian Sea in the junction region of various structural elements, are a key target for deciphering the tectonic evolution of the Eastern Arctic. In recent years, we went on several expeditions and gathered an extensive geological material for this territory. Among other things, we could prove that the basement of the De Long and Anjou archipelagos structures is Precambrian and the overlying Paleozoic sections formed within the same terrane. The form of the boundaries of the NSI terrane are actively debated and are probably continued from the Lyakhovsky islands in the south-west to the southern parts of the submerged Mendeleev Ridge, for which there is increasing evidence of continental crust. Today there are several models that interpret the Paleozoic-Mesozoic tectonic history and structural affiliation of the NSI terrane. Some propose that the Paleozoic sedimentary section formed in a passive margin setting of the Siberian paleocontinent. Others compare its history with marginal basins of the Baltica and Laurentia continents or consider the NSI terrane as an element of the Chukotka-Alaska microplate. These models are mainly based on results of paleobiogeographical and lithological-facies analyses, including explanations of probable sources for detrital zircons. Our paleomagnetic research on sedimentary, volcanogenic-sedimentary and igneous rocks of the Anjou (Kotelny and Bel'kovsky islands) and De Long (Bennett, Jeannette and Henrietta islands) archipelagos let us calculate an apparent polar wander path for the early Paleozoic interval of geological history, which allows us to conclude that the NSI terrane could not have been a part of the continental plates listed above, but rather had active tectonic boundaries with them. Our paleomagnetic data indicate that the NSI terrane drifted slowly and steadily in the tropical and subtropical regions no higher than 40 degrees. However, the main uncertainty for the

Uranium

International Nuclear Information System (INIS)

Cuney, M.; Pagel, M.; Leroy, J.

1992-01-01

First, this book presents the physico-chemical properties of Uranium and the consequences which can be deduced from the study of numerous geological process. The authors describe natural distribution of Uranium at different scales and on different supports, and main Uranium minerals. A great place in the book is assigned to description and classification of uranium deposits. The book gives also notions on prospection and exploitation of uranium deposits. Historical aspects of Uranium economical development (Uranium resources, production, supply and demand, operating costs) are given in the last chapter. 7 refs., 17 figs

Tectono-thermal Evolution of the Lower Paleozoic Petroleum Source Rocks in the Southern Lublin Trough: Implications for Shale Gas Exploration from Maturity Modelling

Science.gov (United States)

Botor, Dariusz

2018-03-01

The Lower Paleozoic basins of eastern Poland have recently been the focus of intensive exploration for shale gas. In the Lublin Basin potential unconventional play is related to Lower Silurian source rocks. In order to assess petroleum charge history of these shale gas reservoirs, 1-D maturity modeling has been performed. In the Łopiennik IG-1 well, which is the only well that penetrated Lower Paleozoic strata in the study area, the uniform vitrinite reflectance values within the Paleozoic section are interpreted as being mainly the result of higher heat flow in the Late Carboniferous to Early Permian times and 3500 m thick overburden eroded due to the Variscan inversion. Moreover, our model has been supported by zircon helium and apatite fission track dating. The Lower Paleozoic strata in the study area reached maximum temperature in the Late Carboniferous time. Accomplished tectono-thermal model allowed establishing that petroleum generation in the Lower Silurian source rocks developed mainly in the Devonian - Carboniferous period. Whereas, during Mesozoic burial, hydrocarbon generation processes did not develop again. This has negative influence on potential durability of shale gas reservoirs.

Uranium

International Nuclear Information System (INIS)

Poty, B.; Cuney, M.; Bruneton, P.; Virlogeux, D.; Capus, G.

2010-01-01

With the worldwide revival of nuclear energy comes the question of uranium reserves. For more than 20 years, nuclear energy has been neglected and uranium prospecting has been practically abandoned. Therefore, present day production covers only 70% of needs and stocks are decreasing. Production is to double by 2030 which represents a huge industrial challenge. The FBR-type reactors technology, which allows to consume the whole uranium content of the fuel, is developing in several countries and will ensure the long-term development of nuclear fission. However, the implementation of these reactors (the generation 4) will be progressive during the second half of the 21. century. For this reason an active search for uranium ores will be necessary during the whole 21. century to ensure the fueling of light water reactors which are huge uranium consumers. This dossier covers all the aspects of natural uranium production: mineralogy, geochemistry, types of deposits, world distribution of deposits with a particular attention given to French deposits, the exploitation of which is abandoned today. Finally, exploitation, ore processing and the economical aspects are presented. Contents: 1 - the uranium element and its minerals: from uranium discovery to its industrial utilization, the main uranium minerals (minerals with tetravalent uranium, minerals with hexavalent uranium); 2 - uranium in the Earth's crust and its geochemical properties: distribution (in sedimentary rocks, in magmatic rocks, in metamorphic rocks, in soils and vegetation), geochemistry (uranium solubility and valence in magmas, uranium speciation in aqueous solution, solubility of the main uranium minerals in aqueous solution, uranium mobilization and precipitation); 3 - geology of the main types of uranium deposits: economical criteria for a deposit, structural diversity of deposits, classification, world distribution of deposits, distribution of deposits with time, superficial deposits, uranium

Uranium mobility in mine areas: evaluation of the water-rock interaction

Energy Technology Data Exchange (ETDEWEB)

Zuddas, P. [UFR Sciences de la Terre. PEPS. Universite Claude Bernard. Lyon (France); Rocha Scislewski, A.; Faivre, D.; Lopez, O. [Institut de Physique du Globe de Paris (France)

2005-07-01

after 1 year of interaction a level 2 orders of magnitude higher with respect to the untreated rock experiment. At the end of the experiments we observed the presence of neogenic material in the columns. These materials, amorphous at X-ray powder diffraction analysis, are enriched in Fe (30-40%) in the untreated rock experiments while are enriched in both Al and Si (50%) in the tailing rock sample. Uranium was not detected but Si-Al rich gels should contain more uranium than Fe-rich products. (authors)

Future Recovery of Energy and Mineral Values from Organic-Rich Shales (Summary L'avenir de la production d'énergie et de la valeur minérale des schistes riches en matière organique (résumé

Directory of Open Access Journals (Sweden)

Park W. C.

2006-10-01

Full Text Available Oil shale deposits vary significantly in their geological nature and can represent enormous reserves of low grades ores for various minerals such as alumina, sodium carbonates, molybdenum, nickel, vanadium, and uranium. The treatment of these rocks for mineral values can be economically attractive when coupled with the production of synthetic oil. Mutually shared costs for extractinq the mineral values can be favorably affected by utilizing by-products from the oil shale retorting. These can include the residual char for a carbonaceous reductant or fuel, C02 for acidification, or lime and soda ash for caustic. Conversely, an inappropriate choice of oil shale retorting conditions can substantially lower subsequent recovery of mineral values from the spent shale. The proceeding considerations will be discussed for several oil shale deposits including: 1. The Green River formation in the mid-western United States which is not only oil rich but also represents a nearly inexhaustible domestic supply of alumina and sodium carbonates and 2. The block shale of Julia Creek, Queensland, Australia, the Devonian Chattanooga shale in the United States, the Cambrian Kulm shale in Sweden, the Permian Lodeve shale in southern France, and the Paleozoic shales from Korea and USSR for energy and metal values such as molybdenum, nickel, vanadium, and uranium. La nature géologique des dépôts de schistes à huile est très variée ; ces schistes peuvent représenter des réserves énormes de minerais à faible teneur de métaux tels que l'aluminium, le molybdène, le nickel, le vanadium, l'uranium, sans oublier le carbonate de sodium. Le traitement de ces roches pour leur valeur minérale peut être attractif économiquement s'il est associé à la production d'huile synthétique. La répartition des coûts d'extraction des métaux peut être favorablement affectée en utilisant les sous-produits du traitement des schistes à huile. Ceci peut comprendre le goudron

The abundance and distribution of uranium in some oceanic, continental ultramafic inclusions and host basalts

International Nuclear Information System (INIS)

Hamilton, E.I.

1975-01-01

The abundance and distribution of uranium in various continental and oceanic ultramafic inclusions and host basalts are reported. Uranium was determined by neutron activation (fission products, fission tracks and delayed-neutron methods) and alpha-particle autoradiography; data is also reported for the uranium content of various USGS standard rock powders. The concentration of uranium in both oceanic and continental samples is similar, levels are controlled by mineral compositions and their relative abundance in different rock types. Highest levels are found in feldspathic and lowest in olivine-rich inclusions. Uranium is enriched in mylonitised samples and along some inter-crystal boundaries. With the exception of some apatites, highest levels of uranium are in clinopyroxenes (chrome) and lowest in olivines; no enrichment of uranium in orthopyroxenes was observed. Attention is drawn to the problem of obtaining representative samples from the sea floor which have not been altered by saline solutions and the identification of uranium and daughter products present along inter-crystal boundaries. Differences in observed heat flow between continental and oceanic areas may reflect inadequate sampling of representative rock types present below the sea floor and lack of information for the true abundance and distribution of uranium in such rocks

Geology of uranium deposits in the southern part of the Rocky Mountain province of Colorado

International Nuclear Information System (INIS)

Malan, R.C.

1983-07-01

This report summarizes the geology of uranium deposits in the southern part of the Rocky Mountains of Colorado, an area of about 20,000 square miles. In January 1966, combined ore reserves and ore production at 28 uranium deposits were about 685,000 tons of ore averaging 0.24 percent U 3 O 8 (3.32 million pounds U 3 O 8 ). About half of these deposits each contain <1,000 tons of ore. The two largest deposits, the Pitch in the Marshall Pass locality southwest of Salida and the T-1 in the Cochetopa locality southeast of Gunnison, account for about 90 percent of all production and available reserves. The probability in excellent for major expansion of reserves in Marshall Pass and is favorable at a few other vein localities. There are six types of uranium deposits, and there were at least four ages of emplacement of these deposits in the southern part of the Colorado Rockies. There are eight types of host rocks of eight different ages. Veins and stratiform deposits each account for about 40 percent of the total number of deposits, but the veins of early and middle Tertiary age account for nearly all of the total reserves plus production. The remaining 20 percent of the deposits include uraniferous pegmatites, irregular disseminations in porphyry, and other less important types. The wall rocks at the large Tertiary vein deposits in the southern part of the Rocky Mountains of Colorado are Paleozoic and Mesozoic sedimentary rocks, whereas Precambrian metamorphic wall rocks predominate at the large veins in the Front Range of the northern Colorado Rockies. Metallogenetic considerations and tectonic influences affecting the distribution of uranium in Colorado and in adjacent portions of the western United States are analyzed

Microstructural and thermodynamic evaluation of as-cast U-rich U-Zr alloys

International Nuclear Information System (INIS)

Basak, Chandrabhanu; Prasad, G.J.; Kamath, H.S.

2009-01-01

The present study involves evaluation of microstructures and some basic properties of as-cast uranium rich U-Zr alloys; i.e. uranium alloys containing 2wt%, 5wt%, 7wt% and 10 wt% zirconium. Microstructural evaluation, both optical and SEM, with hardness values are reported. It was shown that a definite correlation exists between the microstructure and the hardness of the alloy. Lattice parameter and densities are determined with the help of XRD analysis. Also the phase transformation mechanism is proposed based on the microstructures and XRD analysis. Thermodynamic analysis coupled with the experimental observation reveals that the lamellar structure found in the as-cast U-rich U-Zr alloys originates from the monotectoid reaction (γ→β + γ'). As Zr concentration increases in the alloy the gamma phase can remain in the metastable state even at lower T. So, with increasing Zr content the monotectoid reaction takes place at lower temperature causing generation of finer lamellae. (author)

The importance of colloids and mires for the transport of uranium isotopes through the Kalix River watershed and Baltic Sea

International Nuclear Information System (INIS)

Porcelli, D.; Wasserburg, G.J.; Andersson, P.S.

1997-01-01

The importance of colloids and organic deposits for the transport of uranium isotopes from continental source regions and through the estuarine environment was investigated in the mire-rich Kalix River drainage basin in northern Sweden and the Baltic Sea. Ultrafiltration techniques were used to separate uranium and other elements associated with colloids > 10 kD and >3 kD from open-quotes soluteclose quotes uranium and provided consistent results and high recovery rates for uranium as well as for other elements from large volume samples. Uranium concentrations in 0.45 μm-filtered Kalix River water samples increased by a factor of 3 from near the headwaters in the Caledonides to the river mouth while major cation concentrations were relatively constant. 234 U 238 U ratios were high (δ 234 U = 770-1500) throughout the basin, without showing any simple pattern, and required a supply of 234 U-rich water. Throughout the Kalix River, a large fraction (30-90%) of the uranium is carried by >10 kD colloids, which is compatible with uranium complexation with humic acids. No isotopic differences were found between colloid-associated and solute uranium. Within the Baltic Sea, about half of the uranium is removed at low salinities. The proportion that is lost is equivalent to that of river-derived colloid-bound uranium, suggesting that while solute uranium behaves conservatively during estuarine mixing, colloid-bound uranium is lost due to rapid flocculation of colloidal material. The association of uranium with colloids therefore may be an important parameter in determining uranium estuarine behavior. Mire peats in the Kalix River highly concentrate uranium and are potentially a significant source of recoil 234 U to the mirewaters and river waters. However, mirewater data clearly demonstrate that only small 234 U/ 238 U shifts are generated relative to inflowing groundwater. 63 refs., 8 figs., 3 tabs. groundwater. 63 refs., 8 figs., 3 tabs

Uranium- and thorium-bearing pegmatites of the United States

International Nuclear Information System (INIS)

Adams, J.W.; Arengi, J.T.; Parrish, I.S.

1980-04-01

This report is part of the National Uranium Resource Evaluation (NURE) Program designed to identify criteria favorable for the occurrence of the world's significant uranium deposits. This project deals specifically with uranium- and thorium-bearing pegmatites in the United States and, in particular, their distribution and origin. From an extensive literature survey and field examination of 44 pegmatite localities in the United States and Canada, the authors have compiled an index to about 300 uranium- and thorium-bearing pegmatites in the United States, maps giving location of these deposits, and an annotated bibliography to some of the most pertinent literature on the geology of pegmatites. Pegmatites form from late-state magma differentiates rich in volatile constituents with an attendant aqueous vapor phase. It is the presence of an aqueous phase which results in the development of the variable grain size which characterizes pegmatites. All pegmatites occur in areas of tectonic mobility involving crustal material usually along plate margins. Those pegmatites containing radioactive mineral species show, essentially, a similar distribution to those without radioactive minerals. Criteria such as tectonic setting, magma composition, host rock, and elemental indicators among others, all serve to help delineate areas more favorable for uranium- and thorium-bearing pegmatites. The most useful guide remains the radioactivity exhibited by uranium- and thorium-bearing pegmatites. Although pegmatites are frequently noted as favorable hosts for radioactive minerals, the general paucity and sporadic distribution of these minerals and inherent mining and milling difficulties negate the resource potential of pegmatites for uranium and thorium

Uranium- and thorium-bearing pegmatites of the United States

Energy Technology Data Exchange (ETDEWEB)

Adams, J.W.; Arengi, J.T.; Parrish, I.S.

1980-04-01

This report is part of the National Uranium Resource Evaluation (NURE) Program designed to identify criteria favorable for the occurrence of the world's significant uranium deposits. This project deals specifically with uranium- and thorium-bearing pegmatites in the United States and, in particular, their distribution and origin. From an extensive literature survey and field examination of 44 pegmatite localities in the United States and Canada, the authors have compiled an index to about 300 uranium- and thorium-bearing pegmatites in the United States, maps giving location of these deposits, and an annotated bibliography to some of the most pertinent literature on the geology of pegmatites. Pegmatites form from late-state magma differentiates rich in volatile constituents with an attendant aqueous vapor phase. It is the presence of an aqueous phase which results in the development of the variable grain size which characterizes pegmatites. All pegmatites occur in areas of tectonic mobility involving crustal material usually along plate margins. Those pegmatites containing radioactive mineral species show, essentially, a similar distribution to those without radioactive minerals. Criteria such as tectonic setting, magma composition, host rock, and elemental indicators among others, all serve to help delineate areas more favorable for uranium- and thorium-bearing pegmatites. The most useful guide remains the radioactivity exhibited by uranium- and thorium-bearing pegmatites. Although pegmatites are frequently noted as favorable hosts for radioactive minerals, the general paucity and sporadic distribution of these minerals and inherent mining and milling difficulties negate the resource potential of pegmatites for uranium and thorium.

Compton suppression method and epithermal NAA in the determination of nutrients and heavy metals in Nigerian food and beverages

International Nuclear Information System (INIS)

Ahmed, Y.A.; Landsberger, S.; O'Kelly, D.J.; Braisted, J.; Gabdo, H.; Ewa, I.O.B.; Umar, I.M.; Funtua, I.I.

2010-01-01

We used in this study Compton suppression method and epithermal neutron activation analysis to determine the concentration of nutrients and heavy metals in Nigerian food and beverages. The work was performed at the University of Texas TRIGA Reactor by short, medium, and long irradiation protocols, using thermal flux of 1.4x10 12 n cm -2 s -1 and epithermal flux of 1.4x10 11 n cm -2 s -1 . Application of Compton suppression method has reduced interferences from Compton scattered photons thereby allowing easy evaluation of Na, Cl, Ca, Cu, Mn, Mg, Co, Cr, Rb, Fe, and Se. The epithermal NAA method has enabled determination of Cd, As, Ba, Sr, Br, I, and V with little turn-around time. Quality Control and Quality Assurance of the method was tested by analyzing four Standard Reference Materials (non-fat powdered milk, apple leaves, citrus leaves, and peach leaves) obtained from National Institute for Standards and Technology. Our results show that sorghum, millet, and maize have high values of Zn, Mn, Fe, low values of Cd, As, and Se. Powdered milks, rice, beans, and soybeans were found to have moderate amounts of all the elements. Tobacco recorded high content of Cd, Mn, and As, whereas tea, tsobo leaves, Baobab leaves, and okro seed have more As values than others. However, biscuits, macaroni, spaghetti, and noodles show lower concentrations of all the elements. The distribution of these nutrients and heavy metals in these food and beverages shows the need to fortify biscuits and pastas with micro and macro-nutrients and reduce the use of tobacco, tea, tsobo leaves, Baobab leaves, and Okro seed to avoid intake of heavy elements.

Epithermal neutron activation analysis for studying the environment

International Nuclear Information System (INIS)

Frontas'eva, M.V.; Steinnes, E.

1997-01-01

Epithermal neutron activation analysis (ENAA) has certain advantages over the conventional instrumental analysis (INAA) in terms of improvement in precision and lowering of detection limits, reduction of high matrix activity and fission interferences if any. The current status and the applications of ENAA to environmental samples are reviewed. Experience in the use of ENAA in the monitoring of atmospheric depositions by means of moss-biomonitors at pulsed fast reactor IBR-2 in Dubna is summarized. INAA has shown to be useful for a number of sample types of interest in environmental studies, and should find more extensive use in this area. Analysis of airborne particulate matter is a case where ENAA should be particularly useful. A similar case where ENAA has shown strong performance is in the analysis of mosses used as biomonitors of atmospheric deposition, where 45 elements were determined. In this and other cases, however, induction-coupled plasma mass spectrometry is a very strong competitor, offering data for even more elements. A comparison of ENAA and ICP-MS for moss analysis is presented, and cases where ENAA is unique are discussed

Shape memory effects in a uranium + 14 at. % niobium alloy

International Nuclear Information System (INIS)

Vandermeer, R.A.; Ogle, J.C.; Snyder, W.B. Jr.

1978-01-01

There is a class of alloys that, on cooling from elevated temperatures, experience a martensitic phase change. Some of these, when stressed in the martensitic state to an apparently plastic strain, recover their predeformed shape simply by heating. This striking shape recovery is known as the ''shape memory effect'' (SME). Up to a certain limiting strain, epsilon/sub L/, 100% shape recovery may be accomplished. This memory phenomenon seems to be attributable to the thermoelastic nature of and deformational modes associated with the phase transformation in the alloy. Thus, shape recovery results when a stress-biased martensite undergoes a heat-activated reversion back to the parent phase from which it originated. There are uranium alloys that demonstrate SME-behavior. Uranium-rich, uranium--niobium alloys were the first to be documented; New experimental observations of SME in a polycrystalline uranium--niobium alloy are presented. This alloy can exhibit a two-way memory under cetain circumstances. Additional indirect evidence is presented suggesting that the characteristics of the accompanying phase transformation in this alloy meet the criteria or ''selection rules'' deemed essential for SME

Uranium conversion

International Nuclear Information System (INIS)

Oliver, Lena; Peterson, Jenny; Wilhelmsen, Katarina

2006-03-01

FOI, has performed a study on uranium conversion processes that are of importance in the production of different uranium compounds in the nuclear industry. The same conversion processes are of interest both when production of nuclear fuel and production of fissile material for nuclear weapons are considered. Countries that have nuclear weapons ambitions, with the intention to produce highly enriched uranium for weapons purposes, need some degree of uranium conversion capability depending on the uranium feed material available. This report describes the processes that are needed from uranium mining and milling to the different conversion processes for converting uranium ore concentrate to uranium hexafluoride. Uranium hexafluoride is the uranium compound used in most enrichment facilities. The processes needed to produce uranium dioxide for use in nuclear fuel and the processes needed to convert different uranium compounds to uranium metal - the form of uranium that is used in a nuclear weapon - are also presented. The production of uranium ore concentrate from uranium ore is included since uranium ore concentrate is the feed material required for a uranium conversion facility. Both the chemistry and principles or the different uranium conversion processes and the equipment needed in the processes are described. Since most of the equipment that is used in a uranium conversion facility is similar to that used in conventional chemical industry, it is difficult to determine if certain equipment is considered for uranium conversion or not. However, the chemical conversion processes where UF 6 and UF 4 are present require equipment that is made of corrosion resistant material

Development of the Very Low Angle Detector (VLAD) for detection of epithermal neutrons at low momentum transfers

International Nuclear Information System (INIS)

Tardocchi, M.; Andreani, C.; Cremonesi, O.; Gorini, G.; Perelli-Cippo, E.; Pietropaolo, A.; Rhodes, N.; Schooneveld, E.; Senesi, R.

2006-01-01

New perspectives for epithermal neutron spectroscopy are opened up by the recent development of new instrumentation for inverse geometry time of flight spectrometers at pulsed neutron sources. One example is the Very Low Angle Detector (VLAD) bank which will be installed as an upgrade of the VESUVIO neutron spectrometer, at the ISIS pulsed neutron source. VLAD is developed for detecting epithermal neutrons in the 1-100 eV energy range at very low scattering angles (l deg. - 5 deg.). VLAD will extend the kinematical region covered by today's neutron scattering experiments to the region of low wave vector transfers ( -1 ) and high energy transfers (>1 eV). Accessing such kinematical region will allow new experimental studies in condensed matter systems. The neutron detection is based on Resonance Detectors (RD), which consist of the combination of a resonance foil used as neutron-to-gamma converter and a photon detector. The results obtained with a prototype VLAD detector confirm the potential of this kind of experiments at scattering angles as low as 2 deg. - 5 deg. GEANT4 simulations are used to address issues, such as detector cross talk, which arise with the construction of compact RD arrays

Machining of uranium and uranium alloys

International Nuclear Information System (INIS)

Morris, T.O.

1981-01-01

Uranium and uranium alloys can be readily machined by conventional methods in the standard machine shop when proper safety and operating techniques are used. Material properties that affect machining processes and recommended machining parameters are discussed. Safety procedures and precautions necessary in machining uranium and uranium alloys are also covered. 30 figures

The hydrolysis of thorium dicarbide and of mixed uranium-thorium dicarbides; L'hydrolyse du dicarbure de thorium et des dicarbures mixtes d'uranium et de thorium

Energy Technology Data Exchange (ETDEWEB)

Del Litto, B [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

1966-09-01

The hydrolysis of thorium dicarbide leads to the formation of a complex mixture of gaseous and condensed carbon hydrides. The temperature, between 25 and 100 deg. C, has no influence on the nature and composition of the gas phase. The reaction kinetics, however, are strongly temperature dependent. In a hydrochloric medium, an enrichment in hydrogen of the gas mixture is observed. On the other hand a decrease in hydrogen and an increase in acetylene content take place in an oxidizing medium. The general results can be satisfactorily interpreted through a reaction mechanism involving C-C radical groups. In the same way, the hydrolysis of uranium-thorium-carbon ternary alloys leads to the formation of gaseous and condensed carbon hydrides. The variation of the composition of the gas phase versus uranium content in the alloy suggests an hypothesis about the carbon-carbon distance in the alloy crystal lattice. The variation of methane content, on the other hand, has lead us to discuss the nature of the various phases present in uranium-carbon alloys and carbon-rich uranium-thorium-carbon alloys. We have reached the conclusion that these alloys include a proportion of monocarbide which is dependent upon the ratio. Th/(Th + U). We put forward a diagram of the system uranium-carbon with features proper to explain some phenomena which have been observed in the uranium-thorium-carbon ternary diagram. (author) [French] L'hydrolyse du dicarbure de thorium conduit a la formation d'un melange complexe d'hydrures de carbone gazeux et condenses. La temperature entre 25 et 100 deg. C n'a pas d'influence sur la nature ef la composition de la phase gazeuse. Par contre la cinetique en depend fortement. En milieu chlorhydrique, on observe un enrichissement en hydrogene du melange gazeux. Au contraire, en milieu oxydant il se produit une diminution du taux d'hydrogene et une augmentation tres nette du taux d'acetylene. L'ensemble des resultats obtenus peut etre interprete d'une maniere

Uranium recovery from slags of metallic uranium

International Nuclear Information System (INIS)

Fornarolo, F.; Frajndlich, E.U.C.; Durazzo, M.

2006-01-01

The Center of the Nuclear Fuel of the Institute of Nuclear Energy Research - IPEN finished the program of attainment of fuel development for research reactors the base of Uranium Scilicet (U 3 Si 2 ) from Hexafluoride of Uranium (UF 6 ) with enrichment 20% in weight of 235 U. In the process of attainment of the league of U 3 Si 2 we have as Uranium intermediate product the metallic one whose attainment generates a slag contend Uranium. The present work shows the results gotten in the process of recovery of Uranium in slags of calcined slags of Uranium metallic. Uranium the metallic one is unstable, pyrophoricity and extremely reactive, whereas the U 3 O 8 is a steady oxide of low chemical reactivity, what it justifies the process of calcination of slags of Uranium metallic. The calcination of the Uranium slag of the metallic one in oxygen presence reduces Uranium metallic the U 3 O 8 . Experiments had been developed varying it of acid for Uranium control and excess, nitric molar concentration gram with regard to the stoichiometric leaching reaction of temperature of the leaching process. The 96,0% income proves the viability of the recovery process of slags of Uranium metallic, adopting it previous calcination of these slags in nitric way with low acid concentration and low temperature of leaching. (author)

Leaching and solvent extraction at Mary Kathleen Uranium Ltd

International Nuclear Information System (INIS)

Richmond, G.D.

1978-01-01

Mary Kathleen Uranium Ltd. recommenced operations in early 1976 following a twelve year period of care and maintenance. Several sections of the plant were modified or completely changed for the second operation. The most important change was the replacement of ion exchange with solvent extraction as the means of purifying and upgrading uranium rich solutions. Most of the problems experienced in the solvent extraction system originate from the leach liquor which has a strong tendency to form stable emulsions. This has been countered by some careful control of leaching conditions and by closer observation of operations in the solvent extraction area. Most problems have now been resolved and plant recoveries are quite satisfactory

Uranium, depleted uranium, biological effects; Uranium, uranium appauvri, effets biologiques

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-07-01

Physicists, chemists and biologists at the CEA are developing scientific programs on the properties and uses of ionizing radiation. Since the CEA was created in 1945, a great deal of research has been carried out on the properties of natural, enriched and depleted uranium in cooperation with university laboratories and CNRS. There is a great deal of available data about uranium; thousands of analyses have been published in international reviews over more than 40 years. This presentation on uranium is a very brief summary of all these studies. (author)

Paragenesis and Geochronology of the Nopal I Uranium Deposit, Mexico

International Nuclear Information System (INIS)

M. Fayek; M. Ren

2007-01-01

Uranium deposits can, by analogy, provide important information on the long-term performance of radioactive waste forms and radioactive waste repositories. Their complex mineralogy and variable elemental and isotopic compositions can provide important information, provided that analyses are obtained on the scale of several micrometers. Here, we present a structural model of the Nopal I deposit as well as petrography at the nanoscale coupled with preliminary U-Th-Pb ages and O isotopic compositions of uranium-rich minerals obtained by Secondary Ion Mass Spectrometry (SIMS). This multi-technique approach promises to provide ''natural system'' data on the corrosion rate of uraninite, the natural analogue of spent nuclear fuel

Shielding design of a treatment room for an accelerator-based epithermal neutron irradiation facility for BNCT

International Nuclear Information System (INIS)

Evans, J.F.; Blue, T.E.

1996-01-01

Protecting the facility personnel and the general public from radiation exposure is a primary safety concern of an accelerator-based epithermal neutron irradiation facility. This work makes an attempt at answering the questions open-quotes How much?close quotes and open-quotes What kind?close quotes of shielding will meet the occupational limits of such a facility. Shielding effectiveness is compared for ordinary and barytes concretes in combination with and without borated polyethylene. A calculational model was developed of a treatment room, patient open-quotes scatterer,close quotes and the epithermal neutron beam. The Monte Carlo code, MCNP, was used to compute the total effective dose equivalent rates at specific points of interest outside of the treatment room. A conservative occupational effective dose rate limit of 0.01 mSv h -1 was the guideline for this study. Conservative Monte Carlo calculations show that constructing the treatment room walls with 1.5 m of ordinary concrete, 1.2 m of barytes concrete, 1.0 m of ordinary concrete preceded by 10 cm of 5% boron-polyethylene, or 0.8 m of barytes concrete preceded by 10 cm of 5% boron-polyethylene will adequately protect facility personnel. 20 refs., 8 figs., 2 tabs

Isotope dating of rare-metal mineral associations in black shales of Paleozoic

International Nuclear Information System (INIS)

Anderson, E.B.; Zaslavskij, V.G.; Lobikov, A.F.; Kuchina, G.N.; Markova, T.A.; Andreevskij, L.I.

1987-01-01

Results of isotopic-geochemical study of carbon-bearing (black) shales containing uranium mineralization using local uranium-lead method are presented. The carried out investigations of uranium-lead systems of host black shales and uranium-bearing metasomatites testify to the decisive role of tectonic-magmatic activization of the region during formation of polygenic-polychronic mineralized zones

Epithermal neutron beam for BNCT research at the Washington State University TRIGA research reactor

International Nuclear Information System (INIS)

Nigg, D.W.; Venhuizen, J.R.; Wheeler, F.J.; Wemple, C.A.; Tripard, G.E.; Gavin, P.R.

2000-01-01

A new epithermal-neutron beam facility for BNCT (Boron Neutron Capture Therapy) research and boronated agent screening in animal models is in the final stages of construction at Washington State University (WSU). A key distinguishing feature of the design is the incorporation of a new, high-efficiency, neutron moderating and filtering material, Fluental, developed by the Technical Research Centre of Finland. An additional key feature is the provision for adjustable filter-moderator thickness to systematically explore the radiobiological consequences of increasing the fast-neutron contamination above the nominal value associated with the baseline system. (author)

Characterization of the γ background in epithermal neutron scattering measurements at pulsed neutron sources

International Nuclear Information System (INIS)

Pietropaolo, A.; Tardocchi, M.; Schooneveld, E.M.; Senesi, R.

2006-01-01

This paper reports the characterization of the different components of the γ background in epithermal neutron scattering experiments at pulsed neutron sources. The measurements were performed on the VESUVIO spectrometer at ISIS spallation neutron source. These measurements, carried out with a high purity germanium detector, aim to provide detailed information for the investigation of the effect of the γ energy discrimination on the signal-to-background ratio. It is shown that the γ background is produced by different sources that can be identified with their relative time structure and relative weight

Optimization of desalting process with centrifugation for condensation process of uranium from sea water

International Nuclear Information System (INIS)

Yamamoto, Tatsuya; Takase, Hisao; Fukuoka, Fumio

1984-01-01

Optimization of desalting of the slurry on the condensation process by the deposited slurry method for the recovery of uranium from sea water was studied. We have already published that the uranium rich deposit containing seven ppm uranium could be made on the sea bottom by the deposited slurry method. Uranium can be transferred to the anion exchange resin from titanic acid in the slurry. But in this case Cl - ions obstruct the adsorption of uranium on the anion exchange resin, so the slurry must be desalted before RIP method. It is considered that the cost of desalting of the slurry stage would be a large portion of the capital cost for the recovery of uranium from sea water. The cost of water required is comparable to the cost of energy so that the objective function consists of the cost of energy and the quantity of water. The consumption of energy and water required for desalting of the slurry with the multi-stage centrifugation were oprimized based on dynamic programming. (author)

Uranium deposits in France and in French overseas territories; Les gisements d'uranium de la France metropolitaine et des territoires francais d'Outre-Mer

Energy Technology Data Exchange (ETDEWEB)

Roubault, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1955-07-01

The discover of radium element by Pierre and Marie Curie in 1898 activated the uranium ores prospecting in France and its overseas territories. Before 1945, rare and poor deposits were found with only one being operated in Madagascar and the production of nobiantalates from washing of pegmatitic eluvium. Since the setting up of the Research and Mines Department in the C.E.A. and the training of specialized exploration teams as well as the use of Geiger counters, the uranium ores prospecting has been largely developed in France. The mineralogical data resulting from studies during the pre-war period led to the discover of four main uranium ores content areas: La Crouzille deposit in Limousin characterized by large presence of pitchblende, the Bauzot deposit with massive presence of pitchblende as well, discover of mineralization traces in the Bois Noirs area where a rich uranium ore lodes were discovered afterwards and finally the madagascar deposit. Few other areas have been prospected and have got good evidences of uranium ores presence. The majority of French uranium deposits have got an 'hydrothermal' vein type with localized pitchblende or a secondary mineralization type. It described the different deposits by region and in chronological order of discover. The structural aspect and petrographic studies are discussed. The metallogenic study shows the presence of large mineralization in the French Hercynian massif. After ten years of uranium ores prospecting and mines work, it shows that France possesses numerous uranium deposits which can be qualified as large deposits and the minerals ores prospecting revealed that many deposits sites would be payable in the near future. (M.P.)

Influence of phosphates when uranium in solutions obtained by attacking Forez with sulfuric acid is precipitated by the action of lime; Influence des phosphates, lors de la precipitation par la chaux, de l'uranium contenu dans les solutions d'attaque sulfurique du Forez

Energy Technology Data Exchange (ETDEWEB)

Brebec, G

1959-03-01

Influence of phosphates when uranium in solutions obtained by attacking Forez with sulfuric acid is precipitated by the action of lime was studied. Most of the phosphates were eliminated in the form of ferric phosphates without noticeable losses of uranium: for this it is only necessary to add sufficient ferric sulfate to the solution to be treated so that [Po{sub 4}{sup 3-}]/[Fe{sup 3+}] {approx} 0,4. In these conditions, the preparation of a calcium concentrate rich in uranium takes place in two stages. The first is neutralization at pH 2,7 to 2,8 with elimination of phosphates, sulfates and iron; the second is precipitation of the concentrate at pH 6,5. (author) [French] Nous avons reussi a eliminer la majeure partie des phosphates sous forme de phosphates ferriques, sans pertes sensibles d'uranium. Pour cela, il suffit d'ajouter a la solution a traiter, du sulfate ferrique en quantite telle que: (Po{sub 4}{sup 3-}]/[Fe{sup 3+}] {approx} 0,4. Dans ces conditions, la preparation du concentre calcique, riche en uranium, s'effectue normalement en deux temps: 1) preneutralisation a pH 2,7-2,8: elimination des sulfates, phosphates et fer; 2) precipitation du concentre a pH 6,5. (auteur)

VEIN-TYPE URANIUM MINERALIZATION IN THE EASTERN DESERT OF EGYPT

Directory of Open Access Journals (Sweden)

M. M. Ghoneim

2018-03-01

Full Text Available Vein type uranium deposits where uranium minerals fill cavities veins, fractures, fissures, pore spaces, shear zone, breccia and stockworks in igneous, meta-sediments and metamorphic rocks are common source of uranium mineralization all over the wold. In Egypt, El-Erediya, El-Missikat and El Sela uranium mineralization occur in younger granite plutons in the Eastern Desert of Egypt. These plutons are considered as good examples of intra-granitic vein-type uranium mineralization. The goal of this review article is to study the characteristics of granites and Th-U vein mineralization El Sela area. Main tasks are characteristics of vein type uranium mineralization in the world and Egypt, characteristics of ore-bearing intrusive rocks in the El Sela area, mineralogy of Th-U vein-type mineralization in El Sela area and secondary U and Th minerals in granites. Results. The article revealed that El Sela granite is a peraluminous, high-K Calc-Alkaline (HKCA granite. Two-mica leucogranitic pluton is considered the source rock of U-mineralization at El-Sela area, while the altered microgranite and dolerite dikes are good traps for these mineralizations. The reactivated faults system trending ENE-WSW and NNW-SSE make favorable condition to form uranium mineralization associated with polymetallic mineralization that are redeposited in the two mica granite, microgranite and dolerite dikes. The metallic mineral assemblages in the veins mainly consist of pyrite, chalcopyrite, galena, sphalerite and fluorite that are associated with primary (uraninite, coffinite and secondary U-mineralization (uranophane and autunite that occur either as disseminated clusters or as microfracture filling and coating joint surface. Five types of thorite-group minerals can be distinguished: thorite, Zr-rich thorite, phosphothorite, uranothorite and Zr-rich uranothorite. ThO2 content of uraninite vary from (1.1 to 3 wt.%, for PbO contents from 1.16 to 2.35 wt.%, P2O5 contents from

Aerial gamma ray and magnetic survey: Marion quadrangle, Ohio. Final report

International Nuclear Information System (INIS)

1981-06-01

The Marion quadrangle covers a 7200 square mile area of central Ohio located within the Midwestern Physiographic Province. Up to 5000 feet of Paleozoic strata overlie the east dipping Precambrian basement. Flat lying Quaternary glacial sediments cover most of the surface within the quadrangle. A search of available literature revealed no known uranium deposits. Ninety-nine uranium anomalies were detected and are duscussed briefly. Radiometric data appear to reflect a preference for uranium occurrences in glacial moraine tills, and a minimum likelihood of occurrence in Paleozoic bedrock. Some of the largest anomalies appear to be culturally induced and no anomaly was considered to represent a significant amount of naturally occurring uranium. The magnetic data contrast somewhat with the existing structural interpretation of the area. The generally increasng magnetic gradient from west to east is interrupted by many features whose sources may be attributed to undefined lithologic and/or structural elements in the Precambrian basement

Mineralization mechanism and geodynamic setting of No. 337 deposit in Xiazhuang uranium orefield

International Nuclear Information System (INIS)

Zhang Zhanshi; Wu Jianhua; Liu Shuai; Hua Renmin

2009-01-01

Uranium deposit No.337 in Xiazhuang uranium orefield has been regarden as a representative of the earliest forming, relatively high temperature and short time gap between the formation of pluton and the mineralization. But the latest study revealed that the formation age of the Maofeng pluton, which is the most important uranium host granite in Xiazhuang uranium orefield, is 206-238.2 Ma by LA-ICP-MS zircon dating, while the secondary origin muscovite in Maofeng pluton has the age of 131-136 Ma by 40 Ar/ 39 Ar dating which correspond to the main mineralization age of 130.3-138 Ma in uranium deposit No.337. In Guidong granitic complex, Maofeng pluton shown some unique characteristics. It has the Al 2 O 3 /TiO 2 ratio that infers the lowest forming temperature, the lowest ΣREE and it is the only pluton which presents typical tetrad effects of REE, it is also shown a varying δ 18 O values and the lowest( 87 Sr/ 86 Sr) i values. According to the above findings, a concept model of uranium mineralization and geodynamic setting for No.337 uranium deposit might be presented: in late or post-collision stage of Indosinian orogeny, strongly peraluminous granite of Maofeng pluton formed from partial melting of uranium rich formations. Intrusion of maficdyke in late Yanshanian Period(<140 Ma), caused large fluid movement. Uranium was reactivated and extracted from the altered granite,and precipitated in some favorite places to form uranium ore bodies. Uranium deposit No.337 is the typical representative of the first stage uranium mineralization in Xiazhuang uranium orefield. (authors)

Epithermal neutron activation analysis in applied microbiology

International Nuclear Information System (INIS)

Marina Frontasyeva

2012-01-01

Some results from applying epithermal neutron activation analysis at FLNP JINR, Dubna, Russia, in medical biotechnology, environmental biotechnology and industrial biotechnology are reviewed. In the biomedical experiments biomass from the blue-green alga Spirulina platensis (S. platensis) has been used as a matrix for the development of pharmaceutical substances containing such essential trace elements as selenium, chromium and iodine. The feasibility of target-oriented introduction of these elements into S. platensis biocomplexes retaining its protein composition and natural beneficial properties was shown. The absorption of mercury on growth dynamics of S. platensis and other bacterial strains was observed. Detoxification of Cr and Hg by Arthrobacter globiformis 151B was demonstrated. Microbial synthesis of technologically important silver nanoparticles by the novel actinomycete strain Streptomyces glaucus 71 MD and blue-green alga S. platensis were characterized by a combined use of transmission electron microscopy, scanning electron microscopy and energy-dispersive analysis of X-rays. It was established that the tested actinomycete S. glaucus 71 MD produces silver nanoparticles extracellularly when acted upon by the silver nitrate solution, which offers a great advantage over an intracellular process of synthesis from the point of view of applications. The synthesis of silver nanoparticles by S. platensis proceeded differently under the short-term and long-term silver action. (author)

Clay minerals in sandstone uranium deposits: radwaste applications

International Nuclear Information System (INIS)

Brookins, D.G.

1990-01-01

Clay minerals play an important role in the genesis of uranium deposits in sandstones. They incorporate the rate earths (REE), U, Sb, Th, Cs, Rb, Sr, Y, Ba, and even small amounts of chalcophiles. These minerals possess analog elements for many of the radwaste fission products as well as actinides and some actinide daughters. In sandstone uranium deposits, clay minerals are also associated with sulfide minerals, usually pyrite, and organic carbonaceous matter. The primary clay minerals are usually smectites, illites, chlorites and mixed layer varieties. The integrity of these clay minerals is demonstrated by their retention of formational-mineralization ages determined by Rb-Sr geochronologic investigation of the Grants Mineral Belt of the United States. The importance of the clay minerals as analog for parts of the multi-barrier concept in radwaste disposal is their ability to impede water penetration into - and movement of key elements out of uranium rich zones. The clay minerals further sorb and in other ways incorporate into their structures many fission products and actinide analogs from man-made nuclear wastes. 22 refs., 1 fig., 3 tabs

Photon detectors for epithermal neutron scattering at high-ω and low-q

International Nuclear Information System (INIS)

Pietropaolo, A.; Senesi, R.; Tardocchi, M.; Andreani, C.; Gorini, G.

2004-01-01

Inelastic epithermal neutron scattering at high energy (ℎω≥1 eV) and low wave vector (q≤10 A -1 ) transfers is the unique technique for the investigation of high-energy excitations in a variety of systems, ranging from magnetic materials to semiconductors. The key issue in order to make these measurements feasible on inverse geometry spectrometers, is to develop suitable detection systems for neutrons in the energy range 1-100 eV. The Resonance Detector Spectrometer configuration has to be considered as the most promising approach for electron Volt neutron spectroscopy. This configuration will be employed in the new low angle detector bank, VLAD, planned for VESUVIO spectrometer operating at ISIS source

Process for continuous production of metallic uranium and uranium alloys

Science.gov (United States)

Hayden, Jr., Howard W.; Horton, James A.; Elliott, Guy R. B.

1995-01-01

A method is described for forming metallic uranium, or a uranium alloy, from uranium oxide in a manner which substantially eliminates the formation of uranium-containing wastes. A source of uranium dioxide is first provided, for example, by reducing uranium trioxide (UO.sub.3), or any other substantially stable uranium oxide, to form the uranium dioxide (UO.sub.2). This uranium dioxide is then chlorinated to form uranium tetrachloride (UCl.sub.4), and the uranium tetrachloride is then reduced to metallic uranium by reacting the uranium chloride with a metal which will form the chloride of the metal. This last step may be carried out in the presence of another metal capable of forming one or more alloys with metallic uranium to thereby lower the melting point of the reduced uranium product. The metal chloride formed during the uranium tetrachloride reduction step may then be reduced in an electrolysis cell to recover and recycle the metal back to the uranium tetrachloride reduction operation and the chlorine gas back to the uranium dioxide chlorination operation.

Process for continuous production of metallic uranium and uranium alloys

Science.gov (United States)

Hayden, H.W. Jr.; Horton, J.A.; Elliott, G.R.B.

1995-06-06

A method is described for forming metallic uranium, or a uranium alloy, from uranium oxide in a manner which substantially eliminates the formation of uranium-containing wastes. A source of uranium dioxide is first provided, for example, by reducing uranium trioxide (UO{sub 3}), or any other substantially stable uranium oxide, to form the uranium dioxide (UO{sub 2}). This uranium dioxide is then chlorinated to form uranium tetrachloride (UCl{sub 4}), and the uranium tetrachloride is then reduced to metallic uranium by reacting the uranium chloride with a metal which will form the chloride of the metal. This last step may be carried out in the presence of another metal capable of forming one or more alloys with metallic uranium to thereby lower the melting point of the reduced uranium product. The metal chloride formed during the uranium tetrachloride reduction step may then be reduced in an electrolysis cell to recover and recycle the metal back to the uranium tetrachloride reduction operation and the chlorine gas back to the uranium dioxide chlorination operation. 4 figs.

Compton suppression method and epithermal NAA in the determination of nutrients and heavy metals in Nigerian food and beverages

Energy Technology Data Exchange (ETDEWEB)

Ahmed, Y.A., E-mail: yaahmed1@gmail.co [Reactor Engineering Section, Centre for Energy Research and Training, Ahmadu Bello University, Zaria (Nigeria); Nuclear Engineering Teaching Laboratory, University of Texas at Austin, Austin, TX 78758 (United States); Landsberger, S.; O' Kelly, D.J.; Braisted, J. [Nuclear Engineering Teaching Laboratory, University of Texas at Austin, Austin, TX 78758 (United States); Gabdo, H. [Physics Department, Federal College of Education, Yola (Nigeria); Ewa, I.O.B.; Umar, I.M.; Funtua, I.I. [Reactor Engineering Section, Centre for Energy Research and Training, Ahmadu Bello University, Zaria (Nigeria)

2010-10-15

We used in this study Compton suppression method and epithermal neutron activation analysis to determine the concentration of nutrients and heavy metals in Nigerian food and beverages. The work was performed at the University of Texas TRIGA Reactor by short, medium, and long irradiation protocols, using thermal flux of 1.4x10{sup 12} n cm{sup -2} s{sup -1} and epithermal flux of 1.4x10{sup 11} n cm{sup -2} s{sup -1}. Application of Compton suppression method has reduced interferences from Compton scattered photons thereby allowing easy evaluation of Na, Cl, Ca, Cu, Mn, Mg, Co, Cr, Rb, Fe, and Se. The epithermal NAA method has enabled determination of Cd, As, Ba, Sr, Br, I, and V with little turn-around time. Quality Control and Quality Assurance of the method was tested by analyzing four Standard Reference Materials (non-fat powdered milk, apple leaves, citrus leaves, and peach leaves) obtained from National Institute for Standards and Technology. Our results show that sorghum, millet, and maize have high values of Zn, Mn, Fe, low values of Cd, As, and Se. Powdered milks, rice, beans, and soybeans were found to have moderate amounts of all the elements. Tobacco recorded high content of Cd, Mn, and As, whereas tea, tsobo leaves, Baobab leaves, and okro seed have more As values than others. However, biscuits, macaroni, spaghetti, and noodles show lower concentrations of all the elements. The distribution of these nutrients and heavy metals in these food and beverages shows the need to fortify biscuits and pastas with micro and macro-nutrients and reduce the use of tobacco, tea, tsobo leaves, Baobab leaves, and Okro seed to avoid intake of heavy elements.

Compton suppression method and epithermal NAA in the determination of nutrients and heavy metals in Nigerian food and beverages.

Science.gov (United States)

Ahmed, Y A; Landsberger, S; O'Kelly, D J; Braisted, J; Gabdo, H; Ewa, I O B; Umar, I M; Funtua, I I

2010-10-01

We used in this study Compton suppression method and epithermal neutron activation analysis to determine the concentration of nutrients and heavy metals in Nigerian food and beverages. The work was performed at the University of Texas TRIGA Reactor by short, medium, and long irradiation protocols, using thermal flux of 1.4x10(12)n cm(-2)s(-1) and epithermal flux of 1.4x10(11)n cm(-2)s(-1). Application of Compton suppression method has reduced interferences from Compton scattered photons thereby allowing easy evaluation of Na, Cl, Ca, Cu, Mn, Mg, Co, Cr, Rb, Fe, and Se. The epithermal NAA method has enabled determination of Cd, As, Ba, Sr, Br, I, and V with little turn-around time. Quality Control and Quality Assurance of the method was tested by analyzing four Standard Reference Materials (non-fat powdered milk, apple leaves, citrus leaves, and peach leaves) obtained from National Institute for Standards and Technology. Our results show that sorghum, millet, and maize have high values of Zn, Mn, Fe, low values of Cd, As, and Se. Powdered milks, rice, beans, and soybeans were found to have moderate amounts of all the elements. Tobacco recorded high content of Cd, Mn, and As, whereas tea, tsobo leaves, Baobab leaves, and okro seed have more As values than others. However, biscuits, macaroni, spaghetti, and noodles show lower concentrations of all the elements. The distribution of these nutrients and heavy metals in these food and beverages shows the need to fortify biscuits and pastas with micro and macro-nutrients and reduce the use of tobacco, tea, tsobo leaves, Baobab leaves, and Okro seed to avoid intake of heavy elements. Copyright 2010 Elsevier Ltd. All rights reserved.

The location of uranium in source rocks and sites of secondary deposition at the Needle's Eye natural analogue site, Dumfries and Galloway

International Nuclear Information System (INIS)

Basham, I.R.; Hyslop, E.K.; Milodowski, A.E.; Pearce, J.M.

1989-08-01

The British Geological Survey has been conducting a co-ordinated research programme at the natural analogue site of Needle's Eye at Southwick on the Solway coast in SW Scotland. This study of a naturally radioactive geochemical system has been carried out with the aim of improving our confidence in using predictive models of radionuclide migration in the geosphere. This report describes results of integrated mineralogical techniques which have been applied to the study of both the 'source-term' and sites of secondary accumulation of uranium. Pitchblende in a polymetallic-carbonate breccia vein exposed in ancient sea-cliffs is the main source of labile uranium although other uranium-bearing minerals present in the granodiorite and hornfelsed siltstone host-rocks present probable ancillary leachable sites. In keeping with the complex chemistry of the primary sulphide-rich mineralization, a large variety of secondary U minerals has been recorded among which arsenates and hydrous silicates appear to predominate. Uranium transported in groundwaters draining the cliffs has accumulated in organic-rich estuarine/intertidal mudflat sediments of Quaternary age. Charged particle track registration techniques have demonstrated convincingly the effectiveness of humidified organic matter in retarding uranium transport and, coupled with scanning electron microscopy, have indicated an important role of living plants and bacteria in uranium uptake and concentration. (author)

Boron thermal/epithermal neutron capture therapy

International Nuclear Information System (INIS)

Fairchild, R.G.

1982-01-01

The development of various particle beams for radiotherapy represents an attempt to improve dose distribution, and to provide high LET radiations which are less sensitive to ambient physical and radiobiological factors such as oxygen tension, cell cycle, and dose rate. In general, a compromise is necessary as effective RBE is reduced in order to spread the dose distribution over the anticipated tumor volume. The approach of delivering stable non-toxic isotopes to tumor, and then activating these atoms subsequently via an external radiation beam has mator advantages; problems associated with high uptake of these isotopes in competing cell pools are obviated, and the general tumor volume can be included in the treatment field of the activating beam. As long as the normal tissues supporting tumor show a low uptake of the isotope to be activated, and as long as the range of the reaction products is short, dose will be restricted to tumor, with a consequent high therapeutic ratio. Neutron Capture Therapy (NCT) is generally carried out by activating boron-10 with low energy neutrons. The range of the high LET, low OER particles from the 10 B(n, α) 7 Li reaction is approx. 10μ, or one cell diameter, a situation that is optimal for cell killing. Significant advantages may be gained by using the NCT procedure in conjunction with improved tissue penetration provided with epithermal or filtered beams, and new compounds showing physiological binding to tumor

Geohydrological investigation of an uranium anomaly near Vanzylsrus in the Northern Cape Province

International Nuclear Information System (INIS)

Levin, M.; Talma, A.S.; Vogel, J.C.

1982-01-01

An anomaly, caused by low-grade uranium accumulations in organic-rich diatomaceous earth deposits, was located by an airborne radiometric survey near Vanzylsrus in the Northern Cape. Low-grade uraniferous calcrete also occurs in the vicinity of the anomaly. A significant uranium anomaly was found along the whole course of the palaeodrainage with the highest values occuring behind a dolerite dyke a few kilometres south of the confluence. A multidisciplinary approach in corporating geohydrology, water geochemistry, isotopic data and radiometric borehole logging studies was used to evaluate its potential

Uranium hydrogeochemical and stream sediment reconnaissance in the San Juan Mountains, Southwest Colorado

Energy Technology Data Exchange (ETDEWEB)

Maxwell, J.C.

1977-02-01

From 1995 sites in the San Juan Mountains area, 1706 water and 1982 sediment samples were collected during June--July 1976 and analyzed for uranium. The area includes the southern third of the Colorado mineral belt which has yielded rich ores of gold, silver, copper, lead, zinc, and molybdenum. The broadly domed mountains are capped by 2500 m of Tertiary volcanics, deeply eroded to expose a Precambrian crystalline core. Adjacent plateaus underlain by Mesozoic sedimentary rocks were included in the reconnaissance. Average value of uranium in water samples from mountains was less than 0.5 ppB, from plateaus was 1 to 2 ppB, from Mancos shale areas exceeded 2 ppB. Anomalous sediment samples, 40 ppM uranium, came from near Storm King Mountain and upper Vallecito Creek. Other anomalous areas, including the Lake City mining district, were well defined by 4 to 30 ppM uranium in sediment and 3 to 30 ppB uranium in water. Anomalous areas not previously reported indicate favorable areas for future exploration.

Uranium hydrogeochemical and stream sediment reconnaissance in the San Juan Mountains, Southwest Colorado

International Nuclear Information System (INIS)

Maxwell, J.C.

1977-02-01

From 1995 sites in the San Juan Mountains area, 1706 water and 1982 sediment samples were collected during June--July 1976 and analyzed for uranium. The area includes the southern third of the Colorado mineral belt which has yielded rich ores of gold, silver, copper, lead, zinc, and molybdenum. The broadly domed mountains are capped by 2500 m of Tertiary volcanics, deeply eroded to expose a Precambrian crystalline core. Adjacent plateaus underlain by Mesozoic sedimentary rocks were included in the reconnaissance. Average value of uranium in water samples from mountains was less than 0.5 ppB, from plateaus was 1 to 2 ppB, from Mancos shale areas exceeded 2 ppB. Anomalous sediment samples, 40 ppM uranium, came from near Storm King Mountain and upper Vallecito Creek. Other anomalous areas, including the Lake City mining district, were well defined by 4 to 30 ppM uranium in sediment and 3 to 30 ppB uranium in water. Anomalous areas not previously reported indicate favorable areas for future exploration

Biomineral processing of high apatite containing low-grade indian uranium ore

International Nuclear Information System (INIS)

Abhilash; Mehta, K.D.; Pandey, B.D.; Ray, L.; Tamrakar, P.K.

2010-01-01

Microbial species isolated from source mine water, primarily an enriched culture of Acidithiobacillus ferrooxidans was employed for bio-leaching of uranium from a low-grade apatite rich uranium ore of Narwapahar Mines, India while varying pH, pulp density (PD), particle size, etc. The ore (0.047% U_3O_8), though of Singhbhum area (richest deposit of uranium ores in India), due to presence of some refractory minerals and high apatite (5%) causes a maximum 78% recovery through conventional processing. Bioleaching experiments were carried out by varying pH at 35"oC using 20%(w/v) PD and <76μm size particles resulting in 83.5% and 78% uranium bio-recovery at 1.7 and 2.0 pH in 40 days as against maximum recovery of 46% and 41% metal in control experiments respectively. Finer size (<45μm) ore fractions exhibited higher uranium dissolution (96%) in 40 days at 10% (w/v) pulp density (PD), 1.7 pH and 35"oC. On increasing the pulp density from 10% to 20% under the same conditions, the biorecovery of uranium fell down from 96% to 82%. The higher uranium dissolution during bioleaching at 1.7 pH with the fine size particles (<45μm) can be correlated with increase in redox potential from 598 mV to 708 mV and the corresponding variation of Fe(III) ion concentration in 40 days. (author)

Biomineral processing of high apatite containing low-grade indian uranium ore

Energy Technology Data Exchange (ETDEWEB)

Abhilash; Mehta, K.D.; Pandey, B.D., E-mail: biometnml@gmail.com [National Metallurgical Laboratory (CSIR), Jamshedpur (India); Ray, L. [Jadavpur Univ., FTBE Dept., Kolkata (India); Tamrakar, P.K. [Uranium Corp. of India Limited, CR& D Dept., Jaduguda (India)

2010-07-01

Microbial species isolated from source mine water, primarily an enriched culture of Acidithiobacillus ferrooxidans was employed for bio-leaching of uranium from a low-grade apatite rich uranium ore of Narwapahar Mines, India while varying pH, pulp density (PD), particle size, etc. The ore (0.047% U{sub 3}O{sub 8}), though of Singhbhum area (richest deposit of uranium ores in India), due to presence of some refractory minerals and high apatite (5%) causes a maximum 78% recovery through conventional processing. Bioleaching experiments were carried out by varying pH at 35{sup o}C using 20%(w/v) PD and <76μm size particles resulting in 83.5% and 78% uranium bio-recovery at 1.7 and 2.0 pH in 40 days as against maximum recovery of 46% and 41% metal in control experiments respectively. Finer size (<45μm) ore fractions exhibited higher uranium dissolution (96%) in 40 days at 10% (w/v) pulp density (PD), 1.7 pH and 35{sup o}C. On increasing the pulp density from 10% to 20% under the same conditions, the biorecovery of uranium fell down from 96% to 82%. The higher uranium dissolution during bioleaching at 1.7 pH with the fine size particles (<45μm) can be correlated with increase in redox potential from 598 mV to 708 mV and the corresponding variation of Fe(III) ion concentration in 40 days. (author)

Translocation of uranium from water to foodstuff while cooking

International Nuclear Information System (INIS)

Krishnapriya, K.C.; Baksi, Ananya; Chaudhari, Swathi; Gupta, Soujit Sen; Pradeep, T.

2015-01-01

Highlights: • Rice can efficiently uptake uranium from water contaminated with uranyl nitrate hexahydrate (UO 2 (NO 3 ) 2.6 H 2 O), while cooking. • Unusual uranium uptake to the extent of about 1000 ppm is observed when rice is cooked in highly concentrated uranium contaminated water (1240 ppm). • Nature of interaction of uranium with carbohydrates is probed using small monosaccharides like glucose and mannose. • Electrospray ionization mass spectrometry showed UO 2 2+ to be the most stable species in water in such solutions which can form complexes with sugars. • The species (UO 2 2+ ) is also observed in the case of water exposed to the common mineral, uranium oxide (UO 2 ) and similar type of complexation is observed with sugars. - Abstract: The present work report the unusual uranium uptake by foodstuff, especially those rich in carbohydrates like rice when they are cooked in water, contaminated with uranium. The major staple diet in South Asia, rice, was chosen to study its interaction with UO 2 2+ , the active uranium species in water, using inductively coupled plasma mass spectrometry. Highest uptake limit was checked by cooking rice at very high uranium concentration and it was found to be good scavenger of uranium. To gain insight into the mechanism of uptake, direct interaction of UO 2 2+ with monosaccharides was also studied, using electrospray ionization mass spectrometry taking mannose as a model. The studies have been done with dissolved uranium salt, uranyl nitrate hexahydrate (UO 2 (NO 3 ) 2 ·6H 2 O), as well as the leachate of a stable oxide of uranium, UO 2 (s), both of which exist as UO 2 2+ in water. Among the eight different rice varieties investigated, Karnataka Ponni showed the maximum uranium uptake whereas unpolished Basmati rice showed the minimum. Interaction with other foodstuffs (potato, carrot, peas, kidney beans and lentils) with and without NaCl affected the extent of chemical interaction but was not consistent with the

SPLET - A program for calculating the space-lethargy distribution of epithermal neutrons in a reactor lattice cell

International Nuclear Information System (INIS)

Matausek, M.V.; Zmijatevic, I.

1981-01-01

A procedure to solve the space-single-lethargy dependent transport equation for epithermal neutrons in a cylindricised multi-region reactor lattice cell has been developed and proposed in the earlier papers. Here, the computational algorithm is comprised and the computing program SPLET, which calculates the space-lethargy distribution of the spherical harmonics neutron flux moments, as well as the related integral quantities as reaction rates and resonance integrals, is described. (author)

The distribution of uranium in some Pacific manganese nodules and crusts

International Nuclear Information System (INIS)

Kunzendorf, H.; Glasby, G.P.; Plueger, W.L.; Friedrich, G.H.

1982-01-01

A total of 1386 bulk samples of manganese nodules from several areas of the North and South Pacific were analysed for uranium; variations in the U contents of nodules within individual nodules and crusts have been documented on a local scale and on a regional scale. Uranium appears to be one of those elements not associated with the biogenic cycling of elements into nodules in the equatorial high-productivity zone. The principal factor controlling these variations appears to be the clear association of U with Fe in the nodules. Uranium is therefore most probably coprecipitated with Fe from seawater in an iron-rich ferromanganese oxide phase. This explains the higher U contents of nodules containing MnO 2 compared to 10A manganite as the principal manganese oxide phase. Data for a manganese crust from the equatorial North Pacific nodule belt suggest normal seawater deposition for uranium and other metals (Mn, Fe, Ni and Cu) superimposed on possibly basalt alteration as the principal growth mechanisms for the crust. (Auth.)

Studies of red soils as capping the uranium mill tailing impoundments

International Nuclear Information System (INIS)

Wen Zhijian; Chen Zhangru; Liu Zhengyi; Chen Guoliang

2001-01-01

Capping is one of the important technical engineering measures to assure the long term stabilization and isolation of uranium mill tailings. This paper reports in situ surveys of radon emanations before and after tailings slurries were capped with local red soils at the uranium mill tailings. The data obtained by soil-gas surveys reveal that radon emanation decreased with an increase in capping thickness. The dry density of the capping materials also plays an important role in preventing radon emanation. The measurement results show that utilizing high densities of red soils as capping materials can significantly decrease the required thickness of the capping. The analytical results from borehole red soil samples show that uranium, thorium, and radium contents are consistent with the regional environmental radioactivity level. The studies of the mineralogical composition indicate that the local red soils are rich in clay minerals, e.g. kaolinite, illite and mica vermiculite mixed-layer minerals, which would play an active role in preventing radionuclide release to the surrounding environment. A conceptual model for remediation of south China's uranium mill tailing has been developed

Examination of Greek neolithic ceramic shards by epithermal neutron activation analysis

International Nuclear Information System (INIS)

Ochsenkuehn, K.M.; Zouridakis, N.; Inst. of Physical Chemistry, Athens; Ochsenkuehn-Petropulu, M.

1999-01-01

At the reactor of the NCSR 'Demokritos' epithermal irradiation was used in connection with a loss-free counting technique to investigate rare Neolithic ceramic shards, about 4000 years old, from the Alepotrypa Cave of Diros, Greece. The application of an irradiation time of 30 minutes, the measurements of the samples after less then 24 hours and a counting time of 20 minutes in connection with a loss-free counting unit allowed the determination of 12 elements per sample. The comparison of these rare fine ceramic shards with those of primitive shape showed that both were produced from the same raw materials. Small differences could be explained by a raw material pretreatment. The Neolithic potters were obviously aware of separation techniques in order to obtain fine clay fractions to produce those rare ceramics. (author)

Geological analysis of paleozoic large-scale faulting in the south-central Pyrenees

OpenAIRE

Speksnijder, A.

1986-01-01

Detailed structural and sedimentological analysis reveals the existence of an east-west directed fundamental fault zone in the south-central Pyrenees, which has been intermittently active from (at least) the Devonian on. Emphasis is laid on the stUdy of fault-bounded post-Variscan (StephanoPermian) sedimentary basins, and the influence of Late Paleozoic faulting on the underlying Variscan basement. The present structure of the basement is rather complex as it results from multiple Variscan an...

Preliminary study of favorability for uranium resources in Juab County, Utah

International Nuclear Information System (INIS)

Leedom, S.H.; Mitchell, T.P.

1978-02-01

The best potential for large, low-grade uranium deposits in Juab County is in the hydrothermally altered vitric tuffs of Pliocene age. The lateral extent of the altered tuffs may be determined by subsurface studies around the perimeter of the volcanic centers in the Thomas Range and the Honeycomb Hills. Because the ring-fracture zone associated with collapse of the Thomas caldera was a major control for hydrothermal uranium deposits, delineation of the northern and eastern positions of the ring-fracture zone is critical in defining favorable areas for uranium deposits. A small, medium-grade ore deposit in tuffaceous sand of Pliocene age at the Yellow Chief mine in Dugway Dell is unique in origin, and the probability of discovering another deposit of this type is low. A deposit of this type may be present under alluvial cover in the northwestern Drum Mountains along the southern extension of the ring-fracture zone of the Thomas caldera. Festoonlike iron oxide structures and uranium deposition within permeable sandstone horizons indicate that the Yellow Chief deposit was formed by recent ground-water circulation. Granitic intrusive rocks in the Deep Creek Range and in Desert Mountain contain isolated epigenetic vein-type deposits. These rocks could be a source of arkosic sediments buried in adjacent valleys. The Pleistocene lacustrine sediments and playa lake brines may contain concentrations of uranium leached from uranium-rich rocks

The hydrolysis of thorium dicarbide and of mixed uranium-thorium dicarbides

International Nuclear Information System (INIS)

Del Litto, B.

1966-09-01

The hydrolysis of thorium dicarbide leads to the formation of a complex mixture of gaseous and condensed carbon hydrides. The temperature, between 25 and 100 deg. C, has no influence on the nature and composition of the gas phase. The reaction kinetics, however, are strongly temperature dependent. In a hydrochloric medium, an enrichment in hydrogen of the gas mixture is observed. On the other hand a decrease in hydrogen and an increase in acetylene content take place in an oxidizing medium. The general results can be satisfactorily interpreted through a reaction mechanism involving C-C radical groups. In the same way, the hydrolysis of uranium-thorium-carbon ternary alloys leads to the formation of gaseous and condensed carbon hydrides. The variation of the composition of the gas phase versus uranium content in the alloy suggests an hypothesis about the carbon-carbon distance in the alloy crystal lattice. The variation of methane content, on the other hand, has lead us to discuss the nature of the various phases present in uranium-carbon alloys and carbon-rich uranium-thorium-carbon alloys. We have reached the conclusion that these alloys include a proportion of monocarbide which is dependent upon the ratio. Th/(Th + U). We put forward a diagram of the system uranium-carbon with features proper to explain some phenomena which have been observed in the uranium-thorium-carbon ternary diagram. (author) [fr

Results of uranium hydrogeochemical and stream sediment reconnaissance of the San Juan area, southwestern Colorado

International Nuclear Information System (INIS)

Maxwell, J.C.

1977-01-01

During June-July 1976, 1706 water samples and 1982 sediment samples were collected from 1995 sites in the San Juan Mountains area and analyzed for uranium. The area includes the southern third of the Colorado mineral belt which has yielded rich ores of gold, silver, copper, lead, zinc, and molybdenum. The broadly domed mountains are capped by 2500 m of Tertiary volcanics, deeply eroded to expose a Precambrian crystalline core. Adjacent plateaus underlain by Mesozoic sedimentary rocks were included in the reconnaissance. Average value of uranium in water samples from mountains was less than 0.5 ppb, from plateaus was 1 to 2 ppb, and from Mancos shale areas exceeded 2 ppb. Anomalous sediment samples, 40 ppM uranium, came from near Storm King Mountain and upper Vallecito Creek. Other anomalous areas, including the Lake City mining district, were well defined by 4 to 30 ppM uranium in sediment and 3 to 30 ppB uranium in water. Above-average concentrations of uranium not previously reported indicate areas favorable for detailed exploration

Mineralized breccia clasts: a window into hidden porphyry-type mineralization underlying the epithermal polymetallic deposit of Cerro de Pasco (Peru)

Science.gov (United States)

Rottier, Bertrand; Kouzmanov, Kalin; Casanova, Vincent; Bouvier, Anne-Sophie; Baumgartner, Lukas P.; Wälle, Markus; Fontboté, Lluís

2018-01-01

Cerro de Pasco (Peru) is known for its large epithermal polymetallic (Zn-Pb-Ag-Cu-Bi) mineralization emplaced at shallow level, a few hundred meters below the paleo-surface, at the border of a large diatreme-dome complex. Porphyry-style veins crosscutting hornfels and magmatic rock clasts are found in the diatreme breccia and in quartz-monzonite porphyry dikes. Such mineralized veins in clasts allow investigation of high-temperature porphyry-style mineralization developed in the deep portions of magmatic-hydrothermal systems. Quartz in porphyry-style veins contains silicate melt inclusions as well as fluid and solid mineral inclusions. Two types of high-temperature (> 600 °C) quartz-molybdenite-(chalcopyrite)-(pyrite) veins are found in the clasts. Early, thin (1-2 mm), and sinuous HT1 veins are crosscut by slightly thicker (up to 2 cm) and more regular HT2 veins. The HT1 vein quartz hosts CO2- and sulfur-rich high-density vapor inclusions. Two subtypes of the HT1 veins have been defined, based on the nature of mineral inclusions hosted in quartz: (i) HT1bt veins with inclusions of K-feldspar, biotite, rutile, and minor titanite and (ii) HT1px veins with inclusions of actinolite, augite, titanite, apatite, and minor rutile. Using an emplacement depth of the veins of between 2 and 3 km (500 to 800 bar), derived from the diatreme breccia architecture and the supposed erosion preceding the diatreme formation, multiple mineral thermobarometers are applied. The data indicate that HT1 veins were formed at temperatures > 700 °C. HT2 veins host assemblages of polyphase brine inclusions, generally coexisting with low-density vapor-rich inclusions, trapped at temperatures around 600 °C. Rhyolitic silicate melt inclusions found in both HT1 and HT2 veins represent melt droplets transported by the ascending hydrothermal fluids. LA-ICP-MS analyses reveal a chemical evolution coherent with the crystallization of an evolved rhyolitic melt. Quartz from both HT1 and HT2 veins

Geological characteristics and prospecting potential of sandstone-type uranium deposits in the north margin of Qaidam basin

International Nuclear Information System (INIS)

Liu Lin; Song Xiansheng; Feng Wei

2012-01-01

The north margin of Qaidam Basin is composed with rift trough and Oulongbuluke landmass which is clamped by Qilian Mountain and Qaidam block Suture zone. The two activities provide a rich source of uranium for the basin area. The coal-bearing rocks as stratums of medium and lower Jurassic, is the main exploration target zones of sandstone-type uranium ore. Through geological survey and drilling, we think that the interlayer oxidation zone. being primary factors of sandstone-type uranium, can be divided into ancient type and modern type. The ancient interlayer oxidation zone type uranium deposit is the main prospecting types in the north margin of Qaidam Basin. Combined with analysis on geological conditions of sandstone-type uranium mineralization, we propose that eastern edge of Yuqia, southern edge of Lucao Mountain, Beidatan and northwest edge of Ulan depression are good prospects. (authors)

Paragenesis and Geochronology of the Nopal I Uranium Deposit, Mexico

Energy Technology Data Exchange (ETDEWEB)

M. Fayek; M. Ren

2007-02-14

Uranium deposits can, by analogy, provide important information on the long-term performance of radioactive waste forms and radioactive waste repositories. Their complex mineralogy and variable elemental and isotopic compositions can provide important information, provided that analyses are obtained on the scale of several micrometers. Here, we present a structural model of the Nopal I deposit as well as petrography at the nanoscale coupled with preliminary U-Th-Pb ages and O isotopic compositions of uranium-rich minerals obtained by Secondary Ion Mass Spectrometry (SIMS). This multi-technique approach promises to provide ''natural system'' data on the corrosion rate of uraninite, the natural analogue of spent nuclear fuel.

Typomorphism and isomorphism of uranium hydroxides of the woelsendorfite group

International Nuclear Information System (INIS)

Belova, L.N.; Ryzhov, V.I.; Fedorov, O.V.; Lyubomilova, G.V.

1985-01-01

In oxidation zone of uranium deposit uranium hydroxides of the wolsendorfite group: calcuranoite, bauranoite, wolsendorfite and their varieties are studied. Chemical and microprobe analyses are carried out. It is established, that the minerals are encountered in the form of two generations. Early generation forms partial or complete pseudomorphosis over rich contrast pitchblende ores. The late one is encountered in the form of redeposited crystal aggregates in calcite-pitchblende streaks. Study in details of chemical composition of the group minerals permitted to establish the existence of a continuous isomorphous series with ultimate members calcuranoite and wolsendorfite with regular change in chemical and physical properties within the series. Existence of bauranoite-calcuranoite and bauranoite-wolsendorfite isomorphous series is assumed

A study of U-Pb isotopic evolutionary system in Chanziping uranium deposit

International Nuclear Information System (INIS)

Xu Weichang; Huang Shijie; Xia Yuliang.

1988-01-01

Chanziping uranium deposit occurred in the black siliceous slate of Lower cambrian. The uranium mineralization was controlled by both interstratified fault belt and the ore-bearing beds. Based on the study of the U-Pb isotopic system of the various rocks, ores and minerals in the ore-bearing beds, the authors find out the obvious disequilibrium of U-Pb isotopic composition in most rock samples which indicates the loss of uranium form the ore-bearing beds and surrounding granite. Its counting loss ranges from 30 to 80%. The age of rich ores of the U-Pb concordance diagram and the U-Pb three stage model are t 1 = 523 ± 19M. Y. , t 2 = 22 ± 2 M.Y.. The isochronal ages for pitchblend are 75 ± 4 M.Y., 43 ± 7 M.Y., and for rock is 416 M.y.. These data shows that the uranium in ore-bearing beds was mainly derived from the ore-bearing beds itself and partly from the surrounding granite. The ore deposit can be considered to be of stratabound uranium deposit of sedimentation and late transformation type

Some metallogenic features of the Huronian and post-Huronian uraniferous conglomerates

International Nuclear Information System (INIS)

Ruzicka, V.

1981-01-01

Uraniferous conglomerates with syngenetic mineralization are restricted to lower Proterozoic sediments. The depositional environment was near volcanic centres; excessive sulfur, a product a volcanic and postvolcanic activity, apparently caused sulfurization of some minerals and of hydrocarbon. The sedimentary syngenetic origin of uranium mineralization may be illustrated. The cycle starts with deposition of coarse grains of quartz, continues with the deposition of a mixture of finer grains of quartz and pyrite with distinct graded bedding, is followed by deposition of monazite and brannerite, and ends with deposition of fragmented fine grains of uraninite embedded in sulfur-rich hydrocarbon. This situation apparently testifies to the fact that the carbonaceous material is a product of algal mats that existed in quiet times between cycles of sedimentation. The succeeding cycle again starts with the deposition of coarse grains of quartz. Uraniferous conglomerates with epigenetic mineralization are localized in regions containing rocks with higher contents of uranium. Primary concentration of uranium minerals in these source rocks can also be syngenetic. Deposition of uranium took place by one or more epigenetic processes: adsorption, complexing, precipitation, or redox changes according to the degrees of solubility and stability of uranium compounds. Evidence of these mentioned features is based upon studies on the Huronian uraniferous conglomerate from Elliot Lake, Canada, and on the late Precambrian and Paleozoic radioactive conglomerates from the eastern Ural Mountains and Enisey Crest region, USSR

The genesis of the slab window-related Arzular low-sulfidation epithermal gold mineralization (eastern Pontides, NE Turkey

Directory of Open Access Journals (Sweden)

Enver Akaryalı

2013-07-01

Full Text Available The Arzular mineralization is one of the best examples of epithermal gold deposits in the eastern Pontides orogenic belt. The mineralization is hosted by the subduction-related basaltic andesites and is mainly controlled by E–W and NE–SW trending fracture zones. The main ore minerals are galena, sphalerite, pyrite, chalcopyrite, tetrahedrite and gold. Homogenization temperatures of fluid inclusions are between 130 and 295 °C for quartz and between 90 and 133 °C for sphalerite. Sulphur isotope values obtained from pyrite, galena and sphalerite vary between −1.2‰ and 3‰, indicating that sulphur belongs to magmatic origin and was derived from the Lutetian non-adakitic granitic intrusions in the region. Oxygen isotope values are between 15.0‰ and 16.7‰, and hydrogen isotope values are between −87‰ and −91‰. The sulphur isotope thermometer yielded temperatures in the range of 244–291 °C for the ore formation. Our results support the hypothesis that the Arzular mineralization is a low-sulfidation epithermal gold deposit associated with non-adakitic subduction-related granitic magmas that were generated by slab window-related processes in a south-dipping subduction zone during the Lutetian.

The Chara-Sina dyke swarm in the structure of the Middle Paleozoic Vilyui rift system (Siberian Craton)

Science.gov (United States)

Kiselev, A. I.; Konstantinov, K. M.; Yarmolyuk, V. V.; Ivanov, A. V.

2016-11-01

The formation of the Vilyui rift system in the eastern Siberian Craton was finished with breakdown of the continent and formation of its eastern margin. A characteristic feature of this rift system is the radial distribution of dyke swarms of basic rocks. This peculiarity allows us to relate it to the breaking processes above the mantle plume, the center of which was located in the region overlain in the modern structure by the foreland of the Verkhoyan folded-thrust belt. The Chara-Sina dyke swarm is the southern part of a large area of Middle Paleozoic basaltic magmatism in the eastern Siberian Craton. The OIB-like geochemical characteristics of dolerite allow us to suggest that the melting substrate for Middle Paleozoic basaltic magmatism was represented by a relatively homogeneous, mid-depleted mantle of the plume with geochemical parameters similar to those of OIB.

Recovery of uranium from crude uranium tetrafluoride

Energy Technology Data Exchange (ETDEWEB)

Ghosh, S K; Bellary, M P; Keni, V S [Chemical Engineering Division, Bhabha Atomic Research Centre, Mumbai (India)

1994-06-01

An innovative process has been developed for recovery of uranium from crude uranium tetrafluoride cake. The process is based on direct dissolution of uranium tetrafluoride in nitric acid in presence of aluminium hydroxide and use of solvent extraction for removal of fluorides and other bulk impurities to make uranium amenable for refining. It is a simple process requiring minimum process step and has advantage of lesser plant corrosion. This process can be applied for processing of uranium tetrafluoride generated from various sources like uranium by-product during thorium recovery from thorium concentrate, first stage product of uranium recovery from phosphoric acid by OPPA process and off grade uranium tetrafluoride material. The paper describes the details of the process developed and demonstrated on bench and pilot scale and its subsequent modification arising out of bulky solid waste generation. The modified process uses a lower quantity of aluminium hydroxide by allowing a lower dissolution of uranium per cycle and recycles the undissolved material to the next cycle, maintaining the overall recovery at high level. This innovation has reduced the solid waste generated by a factor of four at the cost of a slightly larger dissolution vessel and its increased corrosion rate. (author). 4 refs., 1 fig., 3 tabs.

Recovery of uranium from crude uranium tetrafluoride

International Nuclear Information System (INIS)

Ghosh, S.K.; Bellary, M.P.; Keni, V.S.

1994-01-01

An innovative process has been developed for recovery of uranium from crude uranium tetrafluoride cake. The process is based on direct dissolution of uranium tetrafluoride in nitric acid in presence of aluminium hydroxide and use of solvent extraction for removal of fluorides and other bulk impurities to make uranium amenable for refining. It is a simple process requiring minimum process step and has advantage of lesser plant corrosion. This process can be applied for processing of uranium tetrafluoride generated from various sources like uranium by-product during thorium recovery from thorium concentrate, first stage product of uranium recovery from phosphoric acid by OPPA process and off grade uranium tetrafluoride material. The paper describes the details of the process developed and demonstrated on bench and pilot scale and its subsequent modification arising out of bulky solid waste generation. The modified process uses a lower quantity of aluminium hydroxide by allowing a lower dissolution of uranium per cycle and recycles the undissolved material to the next cycle, maintaining the overall recovery at high level. This innovation has reduced the solid waste generated by a factor of four at the cost of a slightly larger dissolution vessel and its increased corrosion rate. (author)

Aerial gamma ray and magnetic survey, Montrose detail Area 2, Colorado. Final report

International Nuclear Information System (INIS)

1980-04-01

The Montrose Detail Area No. 2 covers 315 square miles of area along the western edge of the Sawatch Mountains. Precambrian crystalline rocks and Paleozoic sediments share dominance in the area. The Paleozoic section deepens toward the north. Some Tertiary intrusive and extrusive rocks that may relate to the nearby igneous activity in the San Juan Mountains are present in the area. Cretaceous and Jurassic sediments also have limited exposure. The Whitepine Mining District (Zn-Pb) lies in the southern end of the detail area. Mineralization occurs in shear zones along the contact between Early Paleozoics and Precambrian rocks. Two uranium deposits occur nearby in a similar geologic setting. One other known uranium deposit occurs in the northern end of the detail area. The geologic characteristics of this deposit are not known. A total of 37 groups of samples in the uranium window constitute anomalies as defined in Volume I. These anomalies cluster over the high uranium count rate areas in the Fossil Ridge-Taylor River and Canyon Creek areas. Highest count rates appear to be associated with faulted Early Paleozoics and adjacent Precambrian rocks. Some high count rate localities appear to overlie isolated Tertiary intrusive bodies. Magnetic data do not outline structural features as mapped by Tweto and others (1976). Some areas mapped as Precambrian and others mapped as Tertiary intrusives have associated high magnetic gradients. Other areas mapped similarly do not have high magnetic gradients. Little correlation with the radiometric data was expected or observed. Three geochemical subdivisions were made on the basis of radiometric data according to the criteria set forth in Volume I, only two of which appeared to have any apparent geologic meaning. Multivariate analysis lends support to this conclusion

Determination of the uranium content in phosphate fertilizers by the fission track registration technique

International Nuclear Information System (INIS)

Rocha, A.C.S. da.

1983-01-01

The application of fission track registration technique (SSNTD) to determine the uranium contents in phosphate fertilizers is dealt with. Samples were prepared by the wet method and the detector used was Makrofol Kg 10μm thick. The determination of uranium in phosphate fertilizer industry is of considerable interest in environmental control. The roots of vegetables tend to absorb and accumulate uranium form soil and so the human body could be contaminated. The phosphate fertilizers were originated from the phosphate-rich apatite deposits located in the high naturally radioactive areas of Araxa and Tapira in the state of Minas Gerais, Brazil. The results obtained ranged from 11.1 to 100ppm of uranium with a total error from 8.2 to 15.7%. The thorium contributions to the total track counting were discounted, though the actual concentrations of thorium in the samples were not determined. (Author) [pt

The determination of self-powered neutron detector sensitivity on thermal and epithermal neutron flux densities

International Nuclear Information System (INIS)

Erben, O.

1980-01-01

The coefficients of thermal and epithermal neutron flux density depression and self-shielding for the SPN detectors with vanadium, rhodium, silver and cobalt emitters are presented, (for cobalt SPN detectors the functions describing the absorbtion of neutrons along the emitter cross-section are also shown). Using these coefficients and previously published beta particle escape efficiencies, sensitivities are determined for the principal types of detectors produced by Les Cables de Lyon and SODERN companies. The experiments and their results verifying the validity of the theoretical work are described. (author)

Physical parameters and biological effects of the LVR-15 epithermal neutron beam

International Nuclear Information System (INIS)

Burian, J.; Marek, M.; Rejchrt, J.; Viererbl, L.; Gambarini, G.; Mares, V.; Vanossi, E.; Judas, L.

2006-01-01

Monitoring of the physical and biological properties of the epithermal neutron beam constructed at the multipurpose LVR-15 nuclear reactor for NCT therapy of brain tumors showed that its physical and biological properties are stable in time and independent on an ad hoc reconfiguration of the reactor core before its therapeutic use. Physical parameters were monitored by measurement of the neutron spectrum, neutron profile, fast neutron kerma rate in tissue and photon absorbed dose, the gel dosimetry was used with the group of standard measurement methods. The RBE of the beam, as evaluated by 3 different biological models, including mouse intestine crypt regeneration assay, germinative zones of the immature rat brain and C6 glioma cells in culture, ranged from 1.70 to 1.99. (author)

Analytical method of uranium (IV) and uranium (VI) in uranium ores and uranium-bearing rocks

International Nuclear Information System (INIS)

Shen Zhuqin; Zheng Yongfeng; Li Qingzhen; Zhong Miaolan; Gu Dingxiang

1995-11-01

The best conditions for keeping the original valences of uranium during the dissolution and separation procedure of geological samples (especially those micro uranium-bearing rock) were studied. With the exist of high concentration protectants, the sample was decomposed with concentration HF at 40 +- 5 degree C. The U(VI) was dissolved completely and formed stable complex UO 2 F 2 , the U(IV) was precipitated rapidly and carried by carrier. Quantitative separation was carried out immediately with suction. The decomposition of sample and separation of solid/liquid phases was completed within two minutes. After separation, the U(IV) and U(VI) were determined quantitatively with laser fluorescence or voltametry respectively according to the uranium content. The limit of detection for this method is 0.7 μg/g, RSD is 10.5%, the determinate range of uranium is 2 x 10 -6 ∼10 -1 g/g. The uranium contents and their valence state ratio were measured for more than one hundred samples of sand stone and granite, the accuracy and precision of these results are satisfactory for uranium geological research. (12 tabs.; 11 refs.)

Reduction of uranium hexafluoride to uranium tetrafluoride

International Nuclear Information System (INIS)

Chang, I.S.; Do, J.B.; Choi, Y.D.; Park, M.H.; Yun, H.H.; Kim, E.H.; Kim, Y.W.

1982-01-01

The single step continuous reduction of uranium hexafluoride (UF 6 ) to uranium tetrafluoride (UF 4 ) has been investigated. Heat required to initiate and maintain the reaction in the reactor is supplied by the highly exothermic reaction of hydrogen with a small amount of elemental fluorine which is added to the uranium hexafluoride stream. When gases uranium hexafluoride and hydrogen react in a vertical monel pipe reactor, the green product, UF 4 has 2.5g/cc in bulk density and is partly contaminated by incomplete reduction products (UF 5 ,U 2 F 9 ) and the corrosion product, presumably, of monel pipe of the reactor itself, but its assay (93% of UF 4 ) is acceptable for the preparation of uranium metal with magnesium metal. Remaining problems are the handling of uranium hexafluoride, which is easily clogging the flowmeter and gas feeding lines because of extreme sensitivity toward moisture, and a development of gas nozzel for free flow of uranium hexafluoride gas. (Author)

Determination of uranium in Toxodon Platensis' teeth from Alto Ribeira region in Sao Paulo State for isotope dating