Asian gasoline and diesel fuel quality

International Nuclear Information System (INIS)

Yamaguchi, Nancy D.

2000-01-01

Despite the economic slowdown in the late 1990s, gasoline and diesel demand in the Asia-Pacific region has increased significantly. Regional demand is the highest in the world and most new refinery projects worldwide during the 1990s have been here. Generalisations are difficult because the region contains countries at different stages of economic development and environmental quality standards. Gasoline and diesel demand for 1985-2005 for Australasia, Southeast Asia, South Asia and East Asia is shown in four histograms. The trend towards unleaded gasoline, average gasoline aromatics levels and the quality of gasoline in Australasia, South Asia, Southeast Asia and East Asia are examined. A further three histograms show the growth in Asia-Pacific unleaded gasoline market share 1991-2000, the rise in octane levels as lead levels fall (1991-2005) and the calculated aromatics content of gasoline in 11 Asia-Pacific countries

Health assessment of gasoline and fuel oxygenate vapors: Neurotoxicity evaluation

OpenAIRE

O?Callaghan, James P.; Daughtrey, Wayne C.; Clark, Charles R.; Schreiner, Ceinwen A.; White, Russell

2014-01-01

Sprague?Dawley rats were exposed via inhalation to vapor condensates of either gasoline or gasoline combined with various fuel oxygenates to assess potential neurotoxicity of evaporative emissions. Test articles included vapor condensates prepared from ?baseline gasoline? (BGVC), or gasoline combined with methyl tertiary butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), ethanol (G/EtOH), or t-butyl alcohol (G/TBA). Target concentrati...

Chronic carcinogenicity study of gasoline vapor condensate (GVC) and GVC containing methyl tertiary-butyl ether in F344 rats.

Science.gov (United States)

Benson, Janet M; Gigliotti, Andrew P; March, Thomas H; Barr, Edward B; Tibbetts, Brad M; Skipper, Betty J; Clark, Charles R; Twerdok, Lorraine

2011-01-01

Chronic inhalation studies were conducted to compare the toxicity and potential carcinogenicity of evaporative emissions from unleaded gasoline (GVC) and gasoline containing the oxygenate methyl tertiary-butyl ether (MTBE; GMVC). The test materials were manufactured to mimic vapors people would be exposed to during refueling at gas stations. Fifty F344 rats per gender per exposure level per test article were exposed 6 h/d, 5 d/wk for 104 wk in whole body chambers. Target total vapor concentrations were 0, 2, 10, or 20 g/m³ for the control, low-, mid-, and high-level exposures, respectively. Endpoints included survival, body weights, clinical observations, organs weights, and histopathology. GVC and GMVC exerted no marked effects on survival or clinical observations and few effects on organ weights. Terminal body weights were reduced in all mid- and high-level GVC groups and high-level GMVC groups. The major proliferative lesions attributable to gasoline exposure with or without MTBE were renal tubule adenomas and carcinomas in male rats. GMV exposure led to elevated testicular mesothelioma incidence and an increased trend for thyroid carcinomas in males. GVMC inhalation caused an increased trend for testicular tumors with exposure concentration. Mid- and high-level exposures of GVC and GMVC led to elevated incidences of nasal respiratory epithelial degeneration. Overall, in these chronic studies conducted under identical conditions, the health effects in F344 rats following 2 yr of GVC or GMVC exposure were comparable in the production of renal adenomas and carcinomas in male rats and similar in other endpoints.

Chronic Carcinogenicity Study of Gasoline Vapor Condensate (GVC) and GVC Containing Methyl Tertiary-Butyl Ether in F344 Rats

Science.gov (United States)

Benson, Janet M.; Gigliotti, Andrew P.; March, Thomas H.; Barr, Edward B.; Tibbetts, Brad M.; Skipper, Betty J.; Clark, Charles R.; Twerdok, Lorraine

2011-01-01

Chronic inhalation studies were conducted to compare the toxicity and potential carcinogenicity of evaporative emissions from unleaded gasoline (GVC) and gasoline containing the oxygenate methyl tertiary-butyl ether (MTBE; GMVC). The test materials were manufactured to mimic vapors people would be exposed to during refueling at gas stations. Fifty F344 rats per gender per exposure level per test article were exposed 6 h/d, 5 d/wk for 104 wk in whole body chambers. Target total vapor concentrations were 0, 2, 10, or 20 g/m3 for the control, low-, mid-, and high-level exposures, respectively. Endpoints included survival, body weights, clinical observations, organs weights, and histopathology. GVC and GMVC exerted no marked effects on survival or clinical observations and few effects on organ weights. Terminal body weights were reduced in all mid- and high-level GVC groups and high-level GMVC groups. The major proliferative lesions attributable to gasoline exposure with or without MTBE were renal tubule adenomas and carcinomas in male rats. GMV exposure led to elevated testicular mesothelioma incidence and an increased trend for thyroid carcinomas in males. GVMC inhalation caused an increased trend for testicular tumors with exposure concentration. Mid- and high-level exposures of GVC and GMVC led to elevated incidences of nasal respiratory epithelial degeneration. Overall, in these chronic studies conducted under identical conditions, the health effects in F344 rats following 2 yr of GVC or GMVC exposure were comparable in the production of renal adenomas and carcinomas in male rats and similar in other endpoints. PMID:21432714

Customer exposure to gasoline vapors during refueling at service stations.

Science.gov (United States)

Hakkola, M A; Saarinen, L H

2000-09-01

Gasoline is a volatile complex mixture of hydrocarbon compounds that is easily vaporized during handling under normal conditions. Modern reformulated gasoline also contains oxygenates to enhance octane number and reduce ambient pollution. This study measured the difference in the exposure of customers to gasoline and oxygenate vapors during refueling in service stations with and without vapor recovery systems. Field measurements were carried out at two self-service stations. One was equipped with Stage I and the other with Stage II vapor recovery systems. At Stage I stations there is vapor recovery only during delivery from road tanker, and at Stage II stations additional vapor recovery during refueling. The exposure of 20 customers was measured at both stations by collecting air samples from their breathing zone into charcoal tubes during refueling with 95-octane reformulated gasoline. Each sample represented two consecutive refuelings. The samples were analyzed in the laboratory by gas chromatography using mass-selective detection for vapor components. The Raid vapor pressure of gasoline was 70 kPa and an oxygen content 2 wt%. Oxygenated gasoline contained 7 percent methyl tert-butyl ether (MtBE) and 5 percent methyl tert-amyl ether (MtAE). The geometric mean concentrations of hydrocarbons (C3-C11) in the customers' breathing zone was 85 mg/m3 (range 2.5-531 mg/m3) at the Stage I service station and 18 mg/m3 (range service station. The geometric mean of the exposure of customers to MtBE during refueling at the Stage I service station was 15.3 mg/m3 (range 1.8-74 mg/m3), and at the Stage II service station 3.4 mg/m3 (range 0.2-16 mg/m3). The differences in exposure were statistically significant (p station. The measurements were done on consecutive days at the various service stations. The temperature ranged from 10 to 17 degrees C, and wind velocity was 2-4 m/s. The climatic conditions were very similar on the measurement days. Based on this study it was found

Evaluation for leaded and unleaded Gasoline as Hazardous Waste

International Nuclear Information System (INIS)

Abou El Naga, H.H.

1999-01-01

With the phase out of alkyl lead compounds as necessary additives for gasoline in order to raise its octane number , the alternative is to reformulate gasoline to have nearly same octane number but with other chemical structures. Such reformulated gasoline (RFG) is found to contain higher aromatics, benzene, iso paraffins, in comparison to leaded gasoline. Additionally, this reformulated gasoline can also contain oxygenated additives. Accordingly, this paper is aiming at evaluation of emitted hazardous chemical compounds from car engines at fuel combustion. Role of chemical structures for reformulated gasoline in emission of volatile organic compounds (VOC) and poisoning materials are considered

Gasoline marketing

International Nuclear Information System (INIS)

England-Joseph, J.

1991-06-01

This paper is a discussion of two reports. One, issued in April 1990, addresses gasoline octane mislabeling, and the other, issued in February 1991, addresses possible consumer overbuying of premium gasoline. Consumers can purchase several grades of unleaded gasoline with different octane ratings regular (87 octane), mid-grade (89 octane), and premium (91 octane or above). A major concern of consumer buying gasoline is that they purchase gasoline with an octane rating that meets their vehicles' octane requirements. In summary, it was found that consumers may unknowingly be purchasing gasoline with lower octane than needed because octane ratings are mislabeled on gasoline pumps. At the same time, other consumers, believing they may get better performance, may be knowingly buying higher priced premium gasoline when regular gasoline would meet their vehicles' needs. These practices could be coasting consumers hundred of millions of dollars each year

Assessment of hepatotoxic and nephrotoxic effects of occupational exposure to unleaded gasoline: A study in shiraz petrol stations

Directory of Open Access Journals (Sweden)

M. Neghab

2014-09-01

Full Text Available Introduction: Gasoline is a complex mixture of more than 500 various hydrocarbons. The elimination of lead from petrol has been associated with the production of significant amounts of hepatotoxic and nephrotoxic monocyclic aromatic hydrocarbons such as benzene, toluene and xylene (BTX. The main purpose of this study was to ascertain whether or not exposure to unleaded petrol, under normal working conditions, is associated with any hepatotoxic or nephrotoxic response. .Materials and Methods: This was a retrospective cohort study in which 200 subjects with current exposure to unleaded petrol working in Shiraz petrol stations as well as 200 unexposed employees were investigated. Using standard methods, atmospheric concentrations of BTX were measured. Additionally, blood and urine samples were taken from subjects for routine biochemical tests of kidney and liver function. .Results: The geometric means of airborne concentrations of BTX were found to be 0.24, 0.37 and 0.64 ppm, respectively. The result of blood chemistry tests showed that means of direct bilirubin, ALT, AST, urea and plasma creatinine were significantly higher in exposed subjects than in unexposed employees, although all of these parameters were in the normal range. Conversely, serum albumin, total protein and serum concentration of calcium and sodium were significantly lower in petrol station workers than in their unexposed counterparts. .Conclusions: The average exposure of petrol station workers to BTX is lower than the current TLVs for these chemicals. However, clinical significance and long-term results of observed changes in liner and kidney of exposed workers needs more evident in comparison with unexposed group.

Gasoline sniffing multifocal neuropathy.

Science.gov (United States)

Burns, T M; Shneker, B F; Juel, V C

2001-11-01

The polyneuropathy caused by chronic gasoline inhalation is reported to be a gradually progressive, symmetric, sensorimotor polyneuropathy. We report unleaded gasoline sniffing by a female 14 years of age that precipitated peripheral neuropathy. In contrast with the previously reported presentation of peripheral neuropathy in gasoline inhalation, our patient developed multiple mononeuropathies superimposed on a background of sensorimotor polyneuropathy. The patient illustrates that gasoline sniffing neuropathy may present with acute multiple mononeuropathies resembling mononeuritis multiplex, possibly related to increased peripheral nerve susceptibility to pressure in the setting of neurotoxic components of gasoline. The presence of tetraethyl lead, which is no longer present in modern gasoline mixtures, is apparently not a necessary factor in the development of gasoline sniffer's neuropathy.

Impact of gasoline inhalation on some neurobehavioural characteristics of male rats

Science.gov (United States)

2009-01-01

Background This paper examines closely and compares the potential hazards of inhalation of two types of gasoline (car fuel). The first type is the commonly use leaded gasoline and the second is the unleaded type enriched with oxygenate additives as lead substituent in order to raise the octane number. The impacts of gasoline exposure on Na+, K+-ATPase, superoxide dismutase (SOD), acetylcholinesterase (AChE), total protein, reduced glutathione (GSH), and lipid peroxidation (TBARS) in the cerebral cortex, and monoamine neurotransmitters dopamine (DA), norepinephrine (NE) and serotonin (5-HT) in the cerebral cortex, hippocampus, cerebellum and hypothalamus were evaluated. The effect of gasoline exposure on the aggressive behaviour tests was also studied. Results The present results revealed that gasoline inhalation induced significant fluctuations in the levels of the monoamine neurotransmitters in the studied brain regions. This was concomitant with a decrease in Na+, K+-ATPase activity and total protein content. Moreover, the group exposed to the unleaded gasoline exhibited an increase in lipid peroxidation and a decrease in AChE and superoxide dismutase activities. These physiological impairments were accompanied with a higher tendency towards aggressive behaviour as a consequence to gasoline inhalation. Conclusion It is concluded from the present work that chronic exposure to either the leaded or the unleaded gasoline vapours impaired the levels of monoamine neurotransmitters and other biochemical parameters in different brain areas and modulated several behavioural aspects related to aggression in rats. PMID:19930677

Impact of gasoline inhalation on some neurobehavioural characteristics of male rats.

Science.gov (United States)

Kinawy, Amal A

2009-11-24

This paper examines closely and compares the potential hazards of inhalation of two types of gasoline (car fuel). The first type is the commonly use leaded gasoline and the second is the unleaded type enriched with oxygenate additives as lead substituent in order to raise the octane number. The impacts of gasoline exposure on Na+, K+-ATPase, superoxide dismutase (SOD), acetylcholinesterase (AChE), total protein, reduced glutathione (GSH), and lipid peroxidation (TBARS) in the cerebral cortex, and monoamine neurotransmitters dopamine (DA), norepinephrine (NE) and serotonin (5-HT) in the cerebral cortex, hippocampus, cerebellum and hypothalamus were evaluated. The effect of gasoline exposure on the aggressive behaviour tests was also studied. The present results revealed that gasoline inhalation induced significant fluctuations in the levels of the monoamine neurotransmitters in the studied brain regions. This was concomitant with a decrease in Na+, K+-ATPase activity and total protein content. Moreover, the group exposed to the unleaded gasoline exhibited an increase in lipid peroxidation and a decrease in AChE and superoxide dismutase activities. These physiological impairments were accompanied with a higher tendency towards aggressive behaviour as a consequence to gasoline inhalation. It is concluded from the present work that chronic exposure to either the leaded or the unleaded gasoline vapours impaired the levels of monoamine neurotransmitters and other biochemical parameters in different brain areas and modulated several behavioural aspects related to aggression in rats.

Impact of gasoline inhalation on some neurobehavioural characteristics of male rats

Directory of Open Access Journals (Sweden)

Kinawy Amal A

2009-11-01

Full Text Available Abstract Background This paper examines closely and compares the potential hazards of inhalation of two types of gasoline (car fuel. The first type is the commonly use leaded gasoline and the second is the unleaded type enriched with oxygenate additives as lead substituent in order to raise the octane number. The impacts of gasoline exposure on Na+, K+-ATPase, superoxide dismutase (SOD, acetylcholinesterase (AChE, total protein, reduced glutathione (GSH, and lipid peroxidation (TBARS in the cerebral cortex, and monoamine neurotransmitters dopamine (DA, norepinephrine (NE and serotonin (5-HT in the cerebral cortex, hippocampus, cerebellum and hypothalamus were evaluated. The effect of gasoline exposure on the aggressive behaviour tests was also studied. Results The present results revealed that gasoline inhalation induced significant fluctuations in the levels of the monoamine neurotransmitters in the studied brain regions. This was concomitant with a decrease in Na+, K+-ATPase activity and total protein content. Moreover, the group exposed to the unleaded gasoline exhibited an increase in lipid peroxidation and a decrease in AChE and superoxide dismutase activities. These physiological impairments were accompanied with a higher tendency towards aggressive behaviour as a consequence to gasoline inhalation. Conclusion It is concluded from the present work that chronic exposure to either the leaded or the unleaded gasoline vapours impaired the levels of monoamine neurotransmitters and other biochemical parameters in different brain areas and modulated several behavioural aspects related to aggression in rats.

Reformulated gasoline: lessons from America

International Nuclear Information System (INIS)

Seymour, A.

1995-01-01

Regulating fuel quality is one of the few politically feasible options for improving air quality in the short and medium term. This book explores and studies the reformulated gasoline programme currently underway in the USA. Despite the smoothness of the initial implementation of the programme, difficulties may arise in the future. It is concluded that reformulated gasoline prices are more independent of crude oil price changes than conventional unleaded gasoline. Finally, the study suggests that refiners will not reap great profit from investment in the supply of reformulated gasoline because of government restrictions. (UK)

Health assessment of gasoline and fuel oxygenate vapors: generation and characterization of test materials.

Science.gov (United States)

Henley, Michael; Letinski, Daniel J; Carr, John; Caro, Mario L; Daughtrey, Wayne; White, Russell

2014-11-01

In compliance with the Clean Air Act regulations for fuel and fuel additive registration, the petroleum industry, additive manufacturers, and oxygenate manufacturers have conducted comparative toxicology testing on evaporative emissions of gasoline alone and gasoline containing fuel oxygenates. To mimic real world exposures, a generation method was developed that produced test material similar in composition to the re-fueling vapor from an automotive fuel tank at near maximum in-use temperatures. Gasoline vapor was generated by a single-step distillation from a 1000-gallon glass-lined kettle wherein approximately 15-23% of the starting material was slowly vaporized, separated, condensed and recovered as test article. This fraction was termed vapor condensate (VC) and was prepared for each of the seven test materials, namely: baseline gasoline alone (BGVC), or gasoline plus an ether (G/MTBE, G/ETBE, G/TAME, or G/DIPE), or gasoline plus an alcohol (G/EtOH or G/TBA). The VC test articles were used for the inhalation toxicology studies described in the accompanying series of papers in this journal. These studies included evaluations of subchronic toxicity, neurotoxicity, immunotoxicity, genotoxicity, reproductive and developmental toxicity. Results of these studies will be used for comparative risk assessments of gasoline and gasoline/oxygenate blends by the US Environmental Protection Agency. Copyright © 2014 Elsevier Inc. All rights reserved.

Development of a device to valuate the effect of ethanol on the vapor pressure and vaporization enthalpy of fuel gasolines

OpenAIRE

Cataluña, Renato; Silva, Rosângela

2006-01-01

The quality of the gasoline utilized for fueling internal combustion engines with spark ignition is directly affected by the gasoline's properties. Thus, the fuel's properties must be in perfect equilibrium to allow the engine to perform optimally, not only insofar as fuel consumption is concerned, but also in order to reduce the emission of pollutants. Vapor pressure and vaporization enthalpy are important properties of a gasoline determining the fuel's behavior under different operating con...

Health assessment of gasoline and fuel oxygenate vapors: immunotoxicity evaluation.

Science.gov (United States)

White, Kimber L; Peachee, Vanessa L; Armstrong, Sarah R; Twerdok, Lorraine E; Clark, Charles R; Schreiner, Ceinwen A

2014-11-01

Female Sprague Dawley rats were exposed via inhalation to vapor condensates of either gasoline or gasoline combined with various fuel oxygenates to assess potential immunotoxicity of evaporative emissions. Test articles included vapor condensates prepared from "baseline gasoline" (BGVC), or gasoline combined with methyl tertiary butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), ethanol (G/EtOH), or t-butyl alcohol (G/TBA). Target concentrations were 0, 2000, 10,000 or 20,000mg/mg(3) administered for 6h/day, 5days/week for 4weeks. The antibody-forming cell (AFC) response to the T-dependent antigen, sheep erythrocyte (sRBC), was used to determine the effects of the gasoline vapor condensates on the humoral components of the immune system. Exposure to BGVC, G/MTBE, G/TAME, and G/TBA did not result in significant changes in the IgM AFC response to sRBC, when evaluated as either specific activity (AFC/10(6) spleen cells) or as total spleen activity (AFC/spleen). Exposure to G/EtOH and G/DIPE resulted in a dose-dependent decrease in the AFC response, reaching the level of statistical significance only at the high 20,000mg/m(3) level. Exposure to G/ETBE resulted in a statistically significant decrease in the AFC response at the middle (10,000mg/m(3)) and high (20,000mg/m(3)) exposure concentrations. Copyright © 2014 Elsevier Inc. All rights reserved.

Neurodevelopmental effects of inhaled vapors of gasoline and ethanol in rats

Science.gov (United States)

Gasoline-ethanol blends comprise the major fraction of the fuel used in the US automotive fleet. To address uncertainties regarding the health risks associated with exposure to gasoline with more than 10% ethanol, we are assessing the effects of prenatal exposure to inhaled vapor...

Mechanism of petroleum-induced sex-specific protein droplet nephropathy and renal cell proliferation in Fischer-344 rats: relevance to humans

International Nuclear Information System (INIS)

Charbonneau, M.; Short, B.G.; Lock, E.A.; Swenberg, J.A.

1987-01-01

Acute inhalation exposure of male rats to vaporized unleaded gasoline causes a protein droplet-nephropathy syndrome, whereas chronic exposure produces a significant increase renal tumor incidence. The renal lesions produced by chronic or acute exposure to UG have not been observed in kidneys of female rats, or either sex of mice. The assessment of the genotoxic properties of unleaded gasoline by a battery of tests has shown that unleaded gasoline is non-genotoxic. A 21-day histoautoradiographic study in male rats exposed to inhaled unleaded gasoline or gavaged with 2,2,4-trimethylpentane (TMP), a nephrotoxic component of unleaded gasoline selected as a model compound, has shown a dose-dependent increase in cell proliferation specifically in the proximal tubule, segments that have an increased protein droplet formation. A disposition study in male and female rats showed that after a single dose of [ 14 C]-TMP, TMP-derived radiolabel was retained in kidneys of male rats. An increase in the renal α2u-globulin concentration was concomitantly observed in male but not female rats

Toxicological assessments of rats exposed prenatally to inhaled vapors of gasoline and gasoline-ethanol blends.

Science.gov (United States)

Bushnell, Philip J; Beasley, Tracey E; Evansky, Paul A; Martin, Sheppard A; McDaniel, Katherine L; Moser, Virginia C; Luebke, Robert W; Norwood, Joel; Copeland, Carey B; Kleindienst, Tadeusz E; Lonneman, William A; Rogers, John M

2015-01-01

The primary alternative to petroleum-based fuels is ethanol, which may be blended with gasoline in the United States at concentrations up to 15% for most automobiles. Efforts to increase the amount of ethanol in gasoline have prompted concerns about the potential toxicity of inhaled ethanol vapors from these fuels. The well-known sensitivity of the developing nervous and immune systems to ingested ethanol and the lack of information about the neurodevelopmental toxicity of ethanol-blended fuels prompted the present work. Pregnant Long-Evans rats were exposed for 6.5h/day on days 9-20 of gestation to clean air or vapors of gasoline containing no ethanol (E0) or gasoline blended with 15% ethanol (E15) or 85% ethanol (E85) at nominal concentrations of 3000, 6000, or 9000 ppm. Estimated maternal peak blood ethanol concentrations were less than 5mg/dL for all exposures. No overt toxicity in the dams was observed, although pregnant dams exposed to 9000 ppm of E0 or E85 gained more weight per gram of food consumed during the 12 days of exposure than did controls. Fuel vapors did not affect litter size or weight, or postnatal weight gain in the offspring. Tests of motor activity and a functional observational battery (FOB) administered to the offspring between post-natal day (PND) 27-29 and PND 56-63 revealed an increase in vertical activity counts in the 3000- and 9000-ppm groups in the E85 experiment on PND 63 and a few small changes in sensorimotor responses in the FOB that were not monotonically related to exposure concentration in any experiment. Neither cell-mediated nor humoral immunity were affected in a concentration-related manner by exposure to any of the vapors in 6-week-old male or female offspring. Systematic concentration-related differences in systolic blood pressure were not observed in rats tested at 3 and 6 months of age in any experiment. No systematic differences were observed in serum glucose or glycated hemoglobin A1c (a marker of long-term glucose

Activated coal of tomato seeds for adsorption of vapors of ammonia, benzene and gasoline

International Nuclear Information System (INIS)

Márquez-Montesino, Francisco; Aguiar-Trujillo, Leonardo; Ramos-Robaina, Boris Abel; Zanzi-Vigouroux, Rolando; Birbas, Daniella

2013-01-01

The objective was to prove the adsorption possibilities of ammonia, benzene and vapors of gasoline in activated coals with phosphoric acid, of tomato seed. An immediate analysis to the biomass was carried out. It was concluded that the vapors adsorption of ammonia, is related with the physical adsorption and the presence of functional groups of acid character in the active surface of the coal that form weak connections with the molecules of ammonia. Experiments of adsorption of benzene and gasoline were carried out, these substances haven't functional groups as the ammonia, so they were less adsorbed, and it was confirmed a chemical adsorption preferably. The activation temperature, the relationship of impregnation (RI) and the concentration of the acid dissolution haven't a significant influence in the capacity of adsorption of benzene, but they have in the adsorption of ammonia and vapors of gasoline, it's of great application for the elimination of vapors' escape in the motors of vehicles. (author)

MVMA's 1991 summer gasoline survey and air quality

International Nuclear Information System (INIS)

Anon.

1992-01-01

In a previous newsletter (September 1991 issue of this journal), the results of MVMA's 1990 Summer Gasoline Survey were discussed. It was noted that many gasolines containing high concentrations of olefins (over 15 percent volume) were being marketed in the northeast corridor between Washington, D.C. and Boston. Also noted was the finding that the composition of gasoline plays an important role in determining the emissions from vehicles on the road. In this newsletter, the potential effects on air quality of the more recently surveyed gasolines are discussed. Three grades of unleaded gasoline were covered in the survey (premium, intermediate, and regular). 1 tab

Health assessment of gasoline and fuel oxygenate vapors: subchronic inhalation toxicity.

Science.gov (United States)

Clark, Charles R; Schreiner, Ceinwen A; Parker, Craig M; Gray, Thomas M; Hoffman, Gary M

2014-11-01

Sprague Dawley rats were exposed via inhalation to vapor condensates of either gasoline or gasoline combined with various fuel oxygenates to assess whether their use in gasoline influences the hazard of evaporative emissions. Test substances included vapor condensates prepared from an EPA described "baseline gasoline" (BGVC), or gasoline combined with methyl tertiary butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), ethanol (G/EtOH), or t-butyl alcohol (G/TBA). Target concentrations were 0, 2000, 10,000 or 20,000mg/m(3) and exposures were for 6h/day, 5days/week for 13weeks. A portion of the animals were maintained for a four week recovery period to determine the reversibility of potential adverse effects. Increased kidney weight and light hydrocarbon nephropathy (LHN) were observed in treated male rats in all studies which were reversible or nearly reversible after 4weeks recovery. LHN is unique to male rats and is not relevant to human toxicity. The no observed effect level (NOAEL) in all studies was 10,000mg/m(3), except for G/MTBE (<2000) and G/TBA (2000). The results provide evidence that use of the studied oxygenates are unlikely to increase the hazard of evaporative emissions during refueling, compared to those from gasoline alone. Copyright © 2014 The Authors. Published by Elsevier Inc. All rights reserved.

Neurobehavioral evaluations of rats gestationally exposed to gasoline vapors

Science.gov (United States)

As the US fuel supply is moving towards blends with higher ethanol levels, there are questions regarding effects of these fuel vapors in the developing fetus. As part of a project evaluating gasoline-ethanol blends of different proportions. we included an evaluation of inhaled pu...

Gestational Exposure to Inhaled Vapors of Ethanol and Gasoline-Ethanol Blends in Rats

Science.gov (United States)

The US automotive fleet is powered primarily by gasoline-ethanol fuel blends containing up to 10% ethanol (ElO). Uncertainties regarding the health risks associated with exposure to ElO prompted assessment of the effects of prenatal exposure to inhaled vapors of gasoline-ethanol ...

Health assessment of gasoline and fuel oxygenate vapors: neurotoxicity evaluation.

Science.gov (United States)

O'Callaghan, James P; Daughtrey, Wayne C; Clark, Charles R; Schreiner, Ceinwen A; White, Russell

2014-11-01

Sprague-Dawley rats were exposed via inhalation to vapor condensates of either gasoline or gasoline combined with various fuel oxygenates to assess potential neurotoxicity of evaporative emissions. Test articles included vapor condensates prepared from "baseline gasoline" (BGVC), or gasoline combined with methyl tertiary butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), ethanol (G/EtOH), or t-butyl alcohol (G/TBA). Target concentrations were 0, 2000, 10,000 or 20,000mg/mg(3) and exposures were for 6h/day, 5days/week for 13weeks. The functional observation battery (FOB) with the addition of motor activity (MA) testing, hematoxylin and eosin staining of brain tissue sections, and brain regional analysis of glial fibrillary acidic protein (GFAP) were used to assess behavioral changes, traditional neuropathology and astrogliosis, respectively. FOB and MA data for all agents, except G/TBA, were negative. G/TBA behavioral effects resolved during recovery. Neuropathology was negative for all groups. Analyses of GFAP revealed increases in multiplebrain regions largely limited to males of the G/EtOH group, findings indicative of minor gliosis, most significantly in the cerebellum. Small changes (both increases and decreases) in GFAP were observed for other test agents but effects were not consistent across sex, brain region or exposure concentration. Copyright © 2014 Elsevier Inc. All rights reserved.

Exposure to regular gasoline and ethanol oxyfuel during refueling in Alaska.

OpenAIRE

Backer, L C; Egeland, G M; Ashley, D L; Lawryk, N J; Weisel, C P; White, M C; Bundy, T; Shortt, E; Middaugh, J P

1997-01-01

Although most people are thought to receive their highest acute exposures to gasoline while refueling, relatively little is actually known about personal, nonoccupational exposures to gasoline during refueling activities. This study was designed to measure exposures associated with the use of an oxygenated fuel under cold conditions in Fairbanks, Alaska. We compared concentrations of gasoline components in the blood and in the personal breathing zone (PBZ) of people who pumped regular unleade...

Impact of gasoline inhalation on some neurobehavioural characteristics of male rats

OpenAIRE

Kinawy Amal A

2009-01-01

Abstract Background This paper examines closely and compares the potential hazards of inhalation of two types of gasoline (car fuel). The first type is the commonly use leaded gasoline and the second is the unleaded type enriched with oxygenate additives as lead substituent in order to raise the octane number. The impacts of gasoline exposure on Na+, K+-ATPase, superoxide dismutase (SOD), acetylcholinesterase (AChE), total protein, reduced glutathione (GSH), and lipid peroxidation (TBARS) in ...

Anti-air pollution & energy conservation system for automobiles using leaded or unleaded gasoline, diesel or alternate fuel

Science.gov (United States)

Bose, Ranendra K.

2002-06-04

Exhaust gases from an internal combustion engine operating with leaded or unleaded gasoline or diesel or natural gas, are used for energizing a high-speed gas turbine. The convoluting gas discharge causes a first separation stage by stratifying of heavier and lighter exhaust gas components that exit from the turbine in opposite directions, the heavier components having a second stratifying separation in a vortex tube to separate combustible pollutants from non-combustible components. The non-combustible components exit a vortex tube open end to atmosphere. The lighter combustible, pollutants effected in the first separation are bubbled through a sodium hydroxide solution for dissolving the nitric oxide, formaldehyde impurities in this gas stream before being piped to the engine air intake for re-combustion, thereby reducing the engine's exhaust pollution and improving its fuel economy. The combustible, heavier pollutants from the second separation stage are piped to air filter assemblies. This gas stream convoluting at a high-speed through the top stator-vanes of the air filters, centrifugally separates the coalescent water, aldehydes, nitrogen dioxides, sulfates, sulfur, lead particles which collect at the bottom of the bowl, wherein it is periodically released to the roadway. Whereas, the heavier hydrocarbon, carbon particles are piped through the air filter's porous element to the engine air intake for re-combustion, further reducing the engine's exhaust pollution and improving its fuel economy.

Phasing out lead from gasoline in Pakistan: a benefit cost analysis

International Nuclear Information System (INIS)

Martin, R.P.; Zaman, Q.U.

1999-01-01

Medical research has established a clear link between elevated blood lead levels nd adverse health effects in humans including the retardation of neurological development, hypertension, and cardiovascular ailments. Due to this, a large number of countries now restrict the sale of leaded gasoline. In contrast, only highly leaded gasoline is readily available in Pakistan, resulting in serious health concerns in certain areas. This paper presents the findings of a study to evaluate consumers' perceived benefits and actual costs of switching to unleaded gasoline in Pakistan. Policy implications are noted. The study indicates a concentration of adverse health effects in the major urban centers. Of special interest is the loss of approximately 2,5000 IQ points annually in Karachi and Lahore as a result of gasoline linked lead exposure. Consumers' willingness to pay for the removal of lead from gasoline, as estimated using a contingent valuation technique, is shown to be positively related to both educational attainment and income. Once consumers are informed of the adverse health effects associated with lead exposure, their willingness to pay for a switch to unleaded gasoline for exceeds the costs incurred. This suggests that significant gains in social welfare may be obtained by phasing out lead from gasoline in Pakistan. The benefits are most pronounced in urban areas, while in rural villages and small cities the costs are likely to out weight the benefits. A flexible program to restrict the sale of leaded gasoline in urban areas is thus recommended. (author)

Health assessment of gasoline and fuel oxygenate vapors: developmental toxicity in rats.

Science.gov (United States)

Roberts, Linda G; Gray, Thomas M; Trimmer, Gary W; Parker, Robert M; Murray, F Jay; Schreiner, Ceinwen A; Clark, Charles R

2014-11-01

Gasoline-vapor condensate (BGVC) or condensed vapors from gasoline blended with methyl t-butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G/TAME) diisopropyl ether (G/DIPE), ethanol (G/EtOH), or t-butyl alcohol (G/TBA) were evaluated for developmental toxicity in Sprague-Dawley rats exposed via inhalation on gestation days (GD) 5-20 for 6h/day at levels of 0 (control filtered air), 2000, 10,000, and 20,000mg/m(3). These exposure durations and levels substantially exceed typical consumer exposure during refueling (<1-7mg/m(3), 5min). Dose responsive maternal effects were reduced maternal body weight and/or weight change, and/or reduced food consumption. No significant malformations were seen in any study. Developmental effects occurred at 20,000mg/m(3) of G/TAME (reduced fetal body weight, increased incidence of stunted fetuses), G/TBA (reduced fetal body weight, increased skeletal variants) and G/DIPE (reduced fetal weight) resulting in developmental NOAEL of 10,000mg/m(3) for these materials. Developmental NOAELs for other materials were 20,000mg/m(3) as no developmental toxicity was induced in those studies. Developmental NOAELs were equal to or greater than the concurrent maternal NOAELs which ranged from 2000 to 20,000mg/m(3). There were no clear cut differences in developmental toxicity between vapors of gasoline and gasoline blended with the ether or alcohol oxygenates. Copyright © 2014 Elsevier Inc. All rights reserved.

Prenatal exposure to vapors of gasoline-ethanol blends causes few cognitive deficits in adult rats

Science.gov (United States)

Developmental exposure to inhaled ethanol-gasoline fuel blends is a potential public health concern. Here we assessed cognitive functions in adult offspring of pregnant rats that were exposed to vapors of gasoline blended with a range of ethanol concentrations, including gasoli...

Limited recovery of soil microbial activity after transient exposure to gasoline vapors

DEFF Research Database (Denmark)

Modrzyński, Jakub J.; Christensen, Jan H.; Mayer, Philipp

2016-01-01

During gasoline spills complex mixtures of toxic volatile organic compounds (VOCs) are released to terrestrial environments. Gasoline VOCs exert baseline toxicity (narcosis) and may thus broadly affect soil biota. We assessed the functional resilience (i.e. resistance and recovery of microbial...... functions) in soil microbial communities transiently exposed to gasoline vapors by passive dosing via headspace for 40 days followed by a recovery phase of 84 days. Chemical exposure was characterized with GC-MS, whereas microbial activity was monitored as soil respiration (CO2 release) and soil bacterial...... microbial activity indicating residual soil toxicity, which could not be attributed to BTEX, but rather to mixture toxicity of more persistent gasoline constituents or degradation products. Our results indicate a limited potential for functional recovery of soil microbial communities after transient...

Feasibility study on reduction of gasoline emissions from oil depots and gasoline stations in Indonesia

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

A field survey was conducted of oil shipment depots in Java and Bali islands owned by Indonesia's state-run oil company to study measures for reduction in greenhouse effect gas emissions. Studies were made on the grasp of the amount of the hydrocarbon vapor emitted into the air, the amount of the gasoline recovered in case of adopting the vapor emission preventive technology, equipment cost/operational cost, etc. Concretely, the following three were studied: change of the gasoline storage tank to the inner floating roof type, and prevention of evaporation loss at the time of receiving and breathing loss caused by temperature changes; replacement with the vapor recovery type loading arm to recover gasoline vapor generated at the time of shipment/filling, and installation of the vapor recovery unit to recover vapor as gasoline; vapor balance system to recover in underground tank the gasoline vapor generated at the time of filling gasoline at gas station. As a result of the study, the recovered gasoline amount was 66,393 Kl/y and the CO2 reduction amount was 14,474 t/y at oil shipment depots and approximately 650 gasoline stations in Jakarta and Surabaya. (NEDO)

FY 2000 report on the basic survey to promote Joint Implementation, etc. Prevention of emissions of gasoline vapor from oil depots in Indonesia; 2000 nendo kyodo jisshi nado suishin kiso chosa hokokusho. Indonesia sekiyu kichi nado kara no gasoline joki hoshutsu no boshi

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

A field survey was conducted of oil shipment depots in Java and Bali islands owned by Indonesia's state-run oil company to study measures for reduction in greenhouse effect gas emissions. Studies were made on the grasp of the amount of the hydrocarbon vapor emitted into the air, the amount of the gasoline recovered in case of adopting the vapor emission preventive technology, equipment cost/operational cost, etc. Concretely, the following three were studied: change of the gasoline storage tank to the inner floating roof type, and prevention of evaporation loss at the time of receiving and breathing loss caused by temperature changes; replacement with the vapor recovery type loading arm to recover gasoline vapor generated at the time of shipment/filling, and installation of the vapor recovery unit to recover vapor as gasoline; vapor balance system to recover in underground tank the gasoline vapor generated at the time of filling gasoline at gas station. As a result of the study, the recovered gasoline amount was 66,393 Kl/y and the CO2 reduction amount was 14,474 t/y at oil shipment depots and approximately 650 gasoline stations in Jakarta and Surabaya. (NEDO)

Environmental contamination and human exposure to manganese--contribution of methylcyclopentadienyl manganese tricarbonyl in unleaded gasoline.

Science.gov (United States)

Zayed, J; Vyskocil, A; Kennedy, G

1999-01-01

The organomanganese compound MMT (methylcyclopentadienyl manganese tricarbonyl), an antiknock additive in unleaded gasoline, has been used in Canada since 1976. Indeed, Canada is the only country where MMT is almost exclusively used. In October 1995, by court decision the Environmental protection Agency (EPA) granted Ethyl's waiver for the use of MMT in the United States. Paradoxically, in 1997 the federal government of Canada adopted a law (C-29) that banned both the interprovincial trade and the importation for commercial purposes of manganese-based substances, including MMT. However, MMT is currently widely used in Canada because of substantial stockpiling, and six Canadian provinces are challenging the law in the courts. Moreover, MMT has been approved for use in Argentina, Australia, Bulgaria, Russia, and conditionally, in New Zealand. It has been suggested by some scientists that combustion of MMT may be a significant source of exposure to inorganic Mn in urban areas. The crucial question is whether Mn contamination from industrial sources combined with the additional contamination that would result from the widespread use of MMT would lead to toxic effects. Our research efforts have attempted to assess the environmental/ecosystem Mn contamination arising from the combustion of MMT in abiotic and biotic systems as well as human exposure. The experimental evidence acquired so far provides useful information on certain environmental consequences of the use of MMT as well as raising a number of questions. Our results gave evidence indicating that roadside air, soils, plants, and animals may be contaminated by Mn. As well, some specific groups of the population could have a higher level of exposure to Mn. Nevertheless, the levels of exposure remain below international guide values. Further studies and further characterization of dose-response relationships are thus needed to provide successful implementation of evidence-based risk-assessment approaches.

Prices and taxes for gasoline and diesel in industrialized countries

International Nuclear Information System (INIS)

Davoust, R.

2008-01-01

This report present a comparative study on the prices and taxes of automotive fuels (gasoline and diesel fuel) in various industrialized countries, members of the OECD organization. Statistics are taken from a publication of the IEA (International Energy Agency), and concern the following fuel categories: regular gasoline, unleaded premium gasoline (SP 95 and SP 98), professional diesel fuel and domestic diesel fuel. It is shown that fuel prices are generally equivalent from one country to another, while taxes make all the difference for the retail final price. Somme global comparisons are also made between US and EU prices

A case study on the application of air sparging with vapor extraction at a gasoline spill site

International Nuclear Information System (INIS)

Marley, M.C.; Walsh, M.T.; Nangeroni, T.E.

1991-01-01

This paper reports that in 1985, remedial activities were implemented at a gasoline spill site in Pawtucket, Rhode Island. The engineering company that contracted to perform the remedial activities designed, installed, and operated a free gasoline product recovery system and a groundwater pump and treat system. An air striping tower was utilized to remove volatile organic hydrocarbons (VOCs) dissolved in the groundwater. Gasoline hydrocarbon vapor migration into nearby basements was controlled through the operation of a soil gas venting system (SGVS), also installed in 1985. The groundwater treatment and free product recovery systems were shut off in may 1987; however, the soil venting system remained in operation and additional vacuum wells were installed to remediate gasoline contaminated vadose zone soils and to recover hydrocarbon vapors in the vicinity of the spill location

Recovery of gasoline

Energy Technology Data Exchange (ETDEWEB)

1937-02-27

The abstract describes a process for recovering a maximum quantity of commercial gasoline from a composite hydrocarbon stream containing hydrocarbons within and below the gasoline boiling range, including olefins. The hydrocarbon stream is separated into low vapor pressure gasoline and a gas fraction consisting of hydrocarbons of the 4 carbon atom group and some of the 3 carbon atom group. The gas fraction is subjected to a polymerization operation, characterized by utilizing the products of the polymerization procedure - both liquid polymers and unconverted gases - to increase the yield of gasoline and to adjust the low vapor pressure gasoline to the vapor pressure of commercial gasoline. A fraction of the gaseous products of the polymerization procedure are used for this purpose. The remainder of the gaseous products are recycled through the polymerization operation.

Evidence of asymmetric behavioral responses to changes in gasoline prices and taxes for different fuel types

International Nuclear Information System (INIS)

Bajo-Buenestado, Raúl

2016-01-01

Using monthly data from the Spanish gasoline retail market we explore asymmetries in consumers’ behavioral responses to changes in gasoline prices and taxes. In particular, we are interested in investigating whether an increase in gasoline taxes has a more negative impact on the demand than a –similar in magnitude– increase in the “pre-tax” price of gasoline for different fuel types. We estimate fuel consumers’ responses using a rich set of robust panel data models considering potential dynamic effects and endogeneity problems. We find evidence to confirm the existence of asymmetric responses for the demand of unleaded fuels and agricultural diesel fuel. However we cannot support this statement for the regular diesel case: for this fuel both the tax-exclusive price and the tax elasticities are roughly the same. This result agrees with the fact that “diesel drivers” tend to be better informed about changes in both fuel prices and taxes. Some implications in terms of fiscal policy and pollution and climate change policy are also discussed. - Highlights: •Provide evidence of asymmetric responses of gasoline demand due to changes in prices and taxes. •Identify differences in the elasticity of the demand of diesel fuel and unleaded gasoline. •Perform robustness checks considering dynamic effects and IV regression. •Provide some policy recommendations for future gasoline tax changes.

Neurophysiological Assessment of Auditory, Peripheral Nerve, Somatosensory, and Visual System Function After Developmental Exposure to Gasoline, E15 and E85 Vapors

Science.gov (United States)

The use of gasolines blended with a range of ethanol concentrations may result in inhalation of vapors containing a variable combination of ethanol with other volatile gasoline constituents. The possibility of exposure and potential interactions between vapor constituents suggest...

Biofiltration of gasoline and ethanol-amended gasoline vapors.

Science.gov (United States)

Soares, Marlene; Woiciechowski, Adenise L; Kozliak, Evguenii I; Paca, Jan; Soccol, Carlos R

2012-01-01

Assuming the projected increase in use of ethanol as a biofuel, the current study was conducted to compare the biofiltration efficiencies for plain and 25% ethanol-containing gasoline. Two biofilters were operated in a downflow mode for 7 months, one of them being compost-based whereas the other using a synthetic packing material, granulated tire rubber, inoculated with gasoline-degrading microorganisms. Inlet concentrations measured as total hydrocarbon (TH) ranged from 1.9 to 5.8 g m(-3) at a constant empty bed retention time of 6.84 min. Contrary to the expectations based on microbiological considerations, ethanol-amended gasoline was more readily biodegraded than plain hydrocarbons, with the respective steady state elimination capacities of 26-43 and 14-18 gTH m(-3) h(-1) for the compost biofilter. The efficiency of both biofilters significantly declined upon the application of higher loads of plain gasoline, yet immediately recovering when switched back to ethanol-blended gasoline. The unexpected effect of ethanol in promoting gasoline biodegradation was explained by increasing hydrocarbon partitioning into the aqueous phase, with mass transfer being rate limiting for the bulk of components. The tire rubber biofilter, after a long acclimation, surpassed the compost biofilter in performance, presumably due to the 'buffering' effect of this packing material increasing the accessibility of gasoline hydrocarbons to the biofilm. With improved substrate mass transfer, biodegradable hydrocarbons were removed in the tire rubber biofilter's first reactor stage, with most of the remaining poorly degradable smaller-size hydrocarbons being degraded in the second stage.

Evaporation characteristics of ETBE-blended gasoline

International Nuclear Information System (INIS)

Okamoto, Katsuhiro; Hiramatsu, Muneyuki; Hino, Tomonori; Otake, Takuma; Okamoto, Takashi; Miyamoto, Hiroki; Honma, Masakatsu; Watanabe, Norimichi

2015-01-01

Highlights: • We chose 8-component hydrocarbon mixture as a model gasoline, and defined the molar mass of gasoline. • We proposed an evaporation model assuming a 2-component mixture of gasoline and ETBE. • We predicted the change in the vapor pressure of ETBE-blended gasoline by evaporation. • The vapor pressures were measured and compared as a means of verifying the model. • We presented the method for predicting flash points of the ETBE-blended gasoline. - Abstract: To reduce greenhouse gas emissions, which contribute to global warming, production of gasoline blended with ethyl tert-buthyl ether (ETBE) is increasing annually. The flash point of ETBE is higher than that of gasoline, and blending ETBE into gasoline will change the flash point and the vapor pressure. Therefore, it is expected that the fire hazard caused by ETBE-blended gasoline would differ from that caused by normal gasoline. The aim of this study was to acquire the knowledge required for estimating the fire hazard of ETBE-blended gasoline. Supposing that ETBE-blended gasoline was a two-component mixture of gasoline and ETBE, we developed a prediction model that describes the vapor pressure and flash point of ETBE-blended gasoline in an arbitrary ETBE blending ratio. We chose 8-component hydrocarbon mixture as a model gasoline, and defined the relation between molar mass of gasoline and mass loss fraction. We measured the changes in the vapor pressure and flash point of gasoline by blending ETBE and evaporation, and compared the predicted values with the measured values in order to verify the prediction model. The calculated values of vapor pressures and flash points corresponded well to the measured values. Thus, we confirmed that the change in the evaporation characteristics of ETBE-blended gasoline by evaporation could be predicted by the proposed model. Furthermore, the vapor pressure constants of ETBE-blended gasoline were obtained by the model, and then the distillation curves were

Evaporation characteristics of ETBE-blended gasoline

Energy Technology Data Exchange (ETDEWEB)

Okamoto, Katsuhiro, E-mail: okamoto@nrips.go.jp [National Research Institute of Police Science, 6-3-1 Kashiwanoha, Kashiwa, Chiba 277-0882 (Japan); Hiramatsu, Muneyuki [Yamanashi Prefectural Police H.Q., 312-4 Kubonakajima, Isawa-cho, Usui, Yamanashi 406-0036 (Japan); Hino, Tomonori; Otake, Takuma [Metropolitan Police Department, 2-1-1 Kasumigaseki, Chiyoda-ku, Tokyo 100-8929 (Japan); Okamoto, Takashi; Miyamoto, Hiroki; Honma, Masakatsu; Watanabe, Norimichi [National Research Institute of Police Science, 6-3-1 Kashiwanoha, Kashiwa, Chiba 277-0882 (Japan)

2015-04-28

Highlights: • We chose 8-component hydrocarbon mixture as a model gasoline, and defined the molar mass of gasoline. • We proposed an evaporation model assuming a 2-component mixture of gasoline and ETBE. • We predicted the change in the vapor pressure of ETBE-blended gasoline by evaporation. • The vapor pressures were measured and compared as a means of verifying the model. • We presented the method for predicting flash points of the ETBE-blended gasoline. - Abstract: To reduce greenhouse gas emissions, which contribute to global warming, production of gasoline blended with ethyl tert-buthyl ether (ETBE) is increasing annually. The flash point of ETBE is higher than that of gasoline, and blending ETBE into gasoline will change the flash point and the vapor pressure. Therefore, it is expected that the fire hazard caused by ETBE-blended gasoline would differ from that caused by normal gasoline. The aim of this study was to acquire the knowledge required for estimating the fire hazard of ETBE-blended gasoline. Supposing that ETBE-blended gasoline was a two-component mixture of gasoline and ETBE, we developed a prediction model that describes the vapor pressure and flash point of ETBE-blended gasoline in an arbitrary ETBE blending ratio. We chose 8-component hydrocarbon mixture as a model gasoline, and defined the relation between molar mass of gasoline and mass loss fraction. We measured the changes in the vapor pressure and flash point of gasoline by blending ETBE and evaporation, and compared the predicted values with the measured values in order to verify the prediction model. The calculated values of vapor pressures and flash points corresponded well to the measured values. Thus, we confirmed that the change in the evaporation characteristics of ETBE-blended gasoline by evaporation could be predicted by the proposed model. Furthermore, the vapor pressure constants of ETBE-blended gasoline were obtained by the model, and then the distillation curves were

Multimedia risk-based soil cleanup at a gasoline-contaminated site using vapor extraction

International Nuclear Information System (INIS)

Mills, W.B.; Johnson, K.M.; Liu, S.; Loh, J.Y.; Lew, C.S.

1996-01-01

At a utility service center, gasoline from an underground storage tank had leaked into subsurface vadose zone soils for several years. To remediate the site, a soil vapor extraction (SVE) system was installed and operated. At the completion of the SVE operation, gasoline-containing residues in several confirmation soil borings exceeded agency-mandated cleanup levels. Rather than continue with SVE, a risk-based approach was developed to evaluate what levels of gasoline-containing residues could be left in the soil and still protect human health. The risk-based approach consisted of simulating the fate of chemical residues through the vadose zone and then into both the ground water and atmosphere. Receptor point concentrations were predicted, and health risks were assessed. The risk assessment concluded that ingestion of contaminated ground water and inhalation of air while showering were the largest potential contributors to risk, and that risks associated with inhalation of vapor-containing ambient air are small. However, all predicted risks are below the acceptable risk levels of 10 -6 individual cancer risk probability and 1.0 hazard index. Therefore, the lead agency accepted the recommendation that the site requires no further remediation. The service center continues normal operations today

Determination of mercury in gasoline by cold vapor atomic absorption spectrometry with direct reduction in microemulsion media

Energy Technology Data Exchange (ETDEWEB)

Brandao, Geisamanda Pedrini [Department of Chemistry, Pontifical Catholic University of Rio de Janeiro, Rua Marques de S. Vicente, 225, Gavea, 22453-900, Rio de Janeiro, RJ (Brazil); Calixto de Campos, Reinaldo [Department of Chemistry, Pontifical Catholic University of Rio de Janeiro, Rua Marques de S. Vicente, 225, Gavea, 22453-900, Rio de Janeiro, RJ (Brazil)]. E-mail: rccampos@rdc.puc-rio.br; Luna, Aderval Severino [Department of Analytical Chemistry, Rio de Janeiro State University, Rua S. Francisco Xavier, s/n, Maracana, 20550-900, Rio de Janeiro, RJ (Brazil)

2005-06-30

The determination of Hg in gasoline by cold vapor atomic absorption spectrometry, after direct aqueous NaBH{sub 4} reduction in a three-component (microemulsion) medium, was investigated. Microemulsions were prepared by mixing gasoline with propan-1-ol and 50% v / v HNO{sub 3} at a 20 : 15 : 1 volume ratio. A long-term homogeneous system was immediately formed this way. After reduction, the Hg vapor generated in a reaction flask was transported to an intermediate K{sub 2}Cr{sub 2}O{sub 7}/H{sub 2}SO{sub 4} trap solution in order to avoid poisoning of the Au-Pt trap by the gasoline vapors. A second reduction step was then conducted and the generated Hg vapor transported to the Au-Pt trap, followed by thermal release of Hg{sup 0} and atomic absorption measurement. Purified N{sub 2} was used as purge and transport gas. After multivariate optimization by central composite design calibration graphs showed coefficients of correlation of 0.9999 and a characteristic mass of 2 ng was obtained. Typical coefficients of variation of 5% and 6% were found for ten consecutive measurements at concentration levels of 1 and 8 {mu}g L{sup -1} of Hg{sup 2+}, respectively. The limit of detection was 0.10 {mu}g L{sup -1} (0.14 {mu}g kg{sup -1}) in the original sample. A total measurement cycle took 11 min, permitting duplicate analysis of 3 samples per hour. The results obtained with the proposed procedure in the analysis of commercial gasoline samples were in agreement with those obtained by a comparative procedure. Gasoline samples of the Rio de Janeiro city have shown Hg concentrations below 0.27 {mu}g L{sup -1}.

Evaporation characteristics of ETBE-blended gasoline.

Science.gov (United States)

Okamoto, Katsuhiro; Hiramatsu, Muneyuki; Hino, Tomonori; Otake, Takuma; Okamoto, Takashi; Miyamoto, Hiroki; Honma, Masakatsu; Watanabe, Norimichi

2015-04-28

To reduce greenhouse gas emissions, which contribute to global warming, production of gasoline blended with ethyl tert-buthyl ether (ETBE) is increasing annually. The flash point of ETBE is higher than that of gasoline, and blending ETBE into gasoline will change the flash point and the vapor pressure. Therefore, it is expected that the fire hazard caused by ETBE-blended gasoline would differ from that caused by normal gasoline. The aim of this study was to acquire the knowledge required for estimating the fire hazard of ETBE-blended gasoline. Supposing that ETBE-blended gasoline was a two-component mixture of gasoline and ETBE, we developed a prediction model that describes the vapor pressure and flash point of ETBE-blended gasoline in an arbitrary ETBE blending ratio. We chose 8-component hydrocarbon mixture as a model gasoline, and defined the relation between molar mass of gasoline and mass loss fraction. We measured the changes in the vapor pressure and flash point of gasoline by blending ETBE and evaporation, and compared the predicted values with the measured values in order to verify the prediction model. The calculated values of vapor pressures and flash points corresponded well to the measured values. Thus, we confirmed that the change in the evaporation characteristics of ETBE-blended gasoline by evaporation could be predicted by the proposed model. Furthermore, the vapor pressure constants of ETBE-blended gasoline were obtained by the model, and then the distillation curves were developed. Copyright © 2015 Elsevier B.V. All rights reserved.

A gasoline vapor monitoring program for a major underground long-term leak

International Nuclear Information System (INIS)

Boehler, W.F.; Huttie, R.L.; Hill, K.M.; Ames, P.R.

1991-01-01

In January of 1988, a large petroleum distributor located in Long Island, New York, reported that a gasoline leak had occurred, and unfortunately, had gone undetected for a number of years. Since the initial discovery of the greater than 1 million gallon gasoline spill, approximately 110 Vapor Monitoring Wells and more than 120 Water Monitoring Wells have been installed in and around an impacted residential community. This paper will focus on the air monitoring aspects of the gasoline spill project including: (1) air sampling methodology - discussion of strategies, techniques, problems and solutions; (2) analytical methodology - development of a Non-Cryogenic Automated Thermal Desorption GC/MS System for the analysis of Air Toxics; (3) work load requirements for the governmental laboratory; (4) establishment of quality assurance program for participating commercial laboratories; (5) establishment of a computerized quality assured project data base; (6) and interactions with the petroleum distributor, consultants and the residential community

Numerical Simulations of High Reactivity Gasoline Fuel Sprays under Vaporizing and Reactive Conditions

KAUST Repository

Mohan, Balaji; Jaasim, Mohammed; Ahmed, Ahfaz; Hernandez Perez, Francisco; Sim, Jaeheon; Roberts, William L.; Sarathy, Mani; Im, Hong G.

2018-01-01

Gasoline compression ignition (GCI) engines are becoming more popular alternative for conventional spark engines to harvest the advantage of high volatility. Recent experimental study demonstrated that high reactivity gasoline fuel can be operated in a conventional mixing controlled combustion mode producing lower soot emissions than that of diesel fuel under similar efficiency and NOx level [1]. Therefore, there is much interest in using gasoline-like fuels in compression ignition engines. In order to improve the fidelity of simulation-based GCI combustion system development, it is mandatory to enhance the prediction of spray combustion of gasoline-like fuels. The purpose of this study is to model the spray characteristics of high reactivity gasoline fuels and validate the models with experimental results obtained through an optically accessible constant volume vessel under vaporizing [2] and reactive conditions [3]. For reacting cases, a comparison of PRF and KAUST multi-component surrogate (KMCS) mechanism was done to obtain good agreement with the experimental ignition delay. From this study, some recommendations were proposed for GCI combustion modelling framework using gasoline like fuels.

Numerical Simulations of High Reactivity Gasoline Fuel Sprays under Vaporizing and Reactive Conditions

KAUST Repository

Mohan, Balaji

2018-04-03

Gasoline compression ignition (GCI) engines are becoming more popular alternative for conventional spark engines to harvest the advantage of high volatility. Recent experimental study demonstrated that high reactivity gasoline fuel can be operated in a conventional mixing controlled combustion mode producing lower soot emissions than that of diesel fuel under similar efficiency and NOx level [1]. Therefore, there is much interest in using gasoline-like fuels in compression ignition engines. In order to improve the fidelity of simulation-based GCI combustion system development, it is mandatory to enhance the prediction of spray combustion of gasoline-like fuels. The purpose of this study is to model the spray characteristics of high reactivity gasoline fuels and validate the models with experimental results obtained through an optically accessible constant volume vessel under vaporizing [2] and reactive conditions [3]. For reacting cases, a comparison of PRF and KAUST multi-component surrogate (KMCS) mechanism was done to obtain good agreement with the experimental ignition delay. From this study, some recommendations were proposed for GCI combustion modelling framework using gasoline like fuels.

Phase-out of leaded gasoline: a prescription for Lebanon

International Nuclear Information System (INIS)

Hashisho, Z.; El-Fadel, M.; Ayoub, G.; Baaj, H.

2000-01-01

Full text.Lead is a toxic heavy metal. Nevertheless, it has been mined and used for more than 800 years. Among the different contemporary sources of lead pollution, emissions from the combustion of leaded gasoline is of particular concern, as it can constitutes more than 90 percent of total lead emissions into the atmosphere in congested urban areas. Concentrations of lead in air and blood are strongly correlated with gasoline lead content and traffic volume. As a result of the increasing awareness about the dangers of lead to human health and the measures to manage urban air pollution, the use of leaded gasoline has been decreasing worldwide. In Lebanon, in the absence of policies to reduce the use of lead in gasoline or to favor the use of unleaded gasoline, leaded gasoline is the predominant grade. The objective of this research work is to analyze the current status of gasoline, and to assess the feasibility and prospect of such action. For this purpose, background information are presented, data about gasoline usage and specifications have been collected, field measurements have been performed and a public survey has been conducted. The comparison of the expected cost savings from phasing out leaded gasoline with the potential costs indicates that such action is economically highly justified. If effective regulatory measures are undertaken, leaded gasoline can be phased-out immediately without a significant cost

Assessment in rats of the reproductive toxicity of gasoline from a gasoline vapor recovery unit.

Science.gov (United States)

McKee, R H; Trimmer, G W; Whitman, F T; Nessel, C S; Mackerer, C R; Hagemann, R; Priston, R A; Riley, A J; Cruzan, G; Simpson, B J; Urbanus, J H

2000-01-01

Gasoline (CAS 86290-81-5) is one of the world's largest volume commercial products. Although numerous toxicology studies have been conducted, the potential for reproductive toxicity has not been directly assessed. Accordingly, a two-generation reproductive toxicity study in rats was conducted to provide base data for hazard assessment and risk characterization. The test material, vapor recovery unit gasoline (68514-15-8), is the volatile fraction of formulated gasoline and the material with which humans are most likely to come in contact. The study was of standard design. Exposures were by inhalation at target concentrations of 5000, 10 000, and 20 000 mg/m(3). The highest exposure concentration was approximately 50% of the lower explosive limit and several orders of magnitude above anticipated exposure during refueling. There were no treatment-related clinical or systemic effects in the parental animals, and no microscopic changes other than hyaline droplet nephropathy in the kidneys of the male rats. None of the reproductive parameters were affected, and there were no deleterious effects on offspring survival and growth. The potential for endocrine modulation was also assessed by analysis of sperm count and quality as well as time to onset of developmental landmarks. No toxicologically important differences were found. Therefore, the NOAEL for reproductive toxicity in this study was > or =20 000 mg/m(3). The only systemic effects, in the kidneys of the male rats, were consistent with an alpha-2 u-globulin-mediated process. This is a male rat-specific effect and not relevant to human health risk assessment.

THE EFFECT OF GASOLINE-LIKE FUEL PRODUCED FROM WASTE AUTOMOBILE TIRES ON EMISSIONS IN SPARK-IGNITION ENGINES

OpenAIRE

ÖZTOP, H. F.; VAROL, Y.; ALTUN, Ş.; FIRAT, M.

2016-01-01

In the present paper, the effect of Gasoline-Like Fuel (GLF) on emissions was investigated for direct injection spark-ignited engine. The GLF was obtained from waste automobile tires by using the pyrolysis. The tires are installed to oven without any procedure such as cutting, melding etc. Obtained GLF was then used in a four-cylinder, four-stroke, water-cooled and direct injection spark-ignited engine as blended with unleaded gasoline from 0% to 60% with an increment of 10%. Engine tests res...

Brugada syndrome unmasked by accidental inhalation of gasoline vapors.

Science.gov (United States)

Kranjcec, Darko; Bergovec, Mijo; Rougier, Jean-Sébastien; Raguz, Miroslav; Pavlovic, Sonja; Jespersen, Thomas; Castella, Vincent; Keller, Dagmar I; Abriel, Hugues

2007-10-01

Loss-of-function mutations in the gene SCN5A can cause Brugada syndrome (BrS), which is an inherited form of idiopathic ventricular fibrillation. We report the case of a 46-year-old patient, with no previous medical history, who had ventricular fibrillation after accidental inhalation of gasoline vapors. His electrocardiogram (ECG) showed a typical type-1 BrS pattern that persisted after the acute event. Genetic investigations allowed the identification of a novel SCN5A mutation leading to a frame-shift and early termination of the channel protein. Biochemical and cellular electrophysiology experiments confirmed the loss-of-function of the mutant allele. The patient was implanted with a cardioverter/defibrillator.

Health assessment of gasoline and fuel oxygenate vapors: reproductive toxicity assessment.

Science.gov (United States)

Gray, Thomas M; Steup, David; Roberts, Linda G; O'Callaghan, James P; Hoffman, Gary; Schreiner, Ceinwen A; Clark, Charles R

2014-11-01

Vapor condensates of baseline gasoline (BGVC), or gasoline-blended with methyl tertiary butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), ethanol (G/EtOH), or t-butyl alcohol (G/TBA) were evaluated for reproductive toxicity in rats at target concentrations of 2000, 10,000, or 20,000mg/m(3), 6h/day, 7days/week. BGVC and G/MTBE were assessed over two generations, the others for one generation. BGVC and G/MTBE F1 offspring were evaluated for neuropathology and changes in regional brain glial fibrillary acidic protein content. No neurotoxicity was observed. Male kidney weight was increased consistent with light hydrocarbon nephropathy. In adult rats, decreased body weight gain and increased liver weight were seen. Spleen weight decreased in adults and pups exposed to G/TBA. No pathological changes to reproductive organs occurred in any study. Decreased food consumption was seen in G/TAME lactating females. Transient decreases in G/TAME offspring weights were observed during lactation. Except for a minor increase in time to mating in G/TBA which did not affect other reproductive parameters, there were no adverse reproductive findings. The NOAEL for reproductive and offspring parameters was 20,000mg/m(3) for all vapor condensates except for lower offspring NOAELs of 10,000mg/m(3) for G/TBA and 2000mg/m(3) for G/TAME. Copyright © 2014 Elsevier Inc. All rights reserved.

Taking the mystery out of gasoline prices

International Nuclear Information System (INIS)

Anon.

2000-01-01

Gasoline price variations in different markets of Canada are primarily driven by market forces, not necessarily by costs, according to a petroleum valuation consultant of the Newfoundland Department of Mines and Energy. Market forces include wholesale prices, the number and efficiency of stations in an area, companies' marketing strategies and customer buying preferences. Prices can be affected by any one of these forces at any time. The prediction is that wholesale prices will continue to be volatile in the next few months as the market adjusts to the changes in crude oil prices determined by OPEC as well as the summer season for gasoline. Changes in crude oil prices are usually reflected in the price of gasoline at the pump, although they do not necessarily move together. Demand which is an important factor in price, is cyclical in both the US and Canada, being lowest in the first quarter of the year, picking up during the second and third quarters with increased driving during good weather, and usually declining again in the fourth quarter with the onset of colder weather. Taxes are also a very significant component of the retail price of gasoline; in July 1998 the combined federal and provincial taxes accounted for 54 per cent of the average retail price of regular unleaded gasoline in Canada. Refining and marketing costs, the distance gasoline has to be transported to market, also influence prices at the pump

Short-term inhalation toxicity of methanol, gasoline, and methanol/gasoline in the rat.

Science.gov (United States)

Poon, R; Chu, I; Bjarnason, S; Vincent, R; Potvin, M; Miller, R B; Valli, V E

1995-01-01

Four- to five-week-old male and female Sprague Dawley rats were exposed to vapors of methanol (2500 ppm), gasoline (3200 ppm), and methanol/gasoline (2500/3200 ppm, 570/3200 ppm) six hours per day, five days per week for four weeks. Control animals were exposed to filtered room air only. Depression in body weight gain and reduced food consumption were observed in male rats, and increased relative liver weight was detected in rats of both sexes exposed to gasoline or methanol/gasoline mixtures. Rats of both sexes exposed to methanol/gasoline mixtures had increased relative kidney weight and females exposed to gasoline and methanol/gasoline mixtures had increased kidney weight. Decreased serum glucose and cholesterol were detected in male rats exposed to gasoline and methanol/gasoline mixtures. Decreased hemoglobin was observed in females inhaling vapors of gasoline and methanol/gasoline at 570/3200 ppm. Urine from rats inhaling gasoline or methanol/gasoline mixtures had up to a fourfold increase in hippuric acid, a biomarker of exposure to the toluene constituent of gasoline, and up to a sixfold elevation in ascorbic acid, a noninvasive biomarker of hepatic response. Hepatic mixed-function oxidase (aniline hydroxylase, aminopyrine N-demethylase and ethoxyresorufin O-deethylase) activities and UDP-glucuronosyltransferase activity were elevated in rats exposed to gasoline and methanol/gasoline mixtures. Histopathological changes were confined to very mild changes in the nasal passages and in the uterus, where decreased incidence or absence of mucosal and myometrial eosinophilia was observed in females inhaling gasoline and methanol/gasoline at 570/3200 ppm. It was concluded that gasoline was largely responsible for the adverse effects, the most significant of which included depression in weight gain in the males, increased liver weight and hepatic microsomal enzyme activities in both sexes, and suppression of uterine eosinophilia. No apparent interactive effects

Pilot-scale studies of soil vapor extraction and bioventing for remediation of a gasoline spill at Cameron Station, Alexandria, Virginia

Energy Technology Data Exchange (ETDEWEB)

Harrison, W.; Joss, C.J.; Martino, L.E. [and others

1994-07-01

Approximately 10,000 gal of spilled gasoline and unknown amounts Of trichloroethylene and benzene were discovered at the US Army`s Cameron Station facility. Because the base is to be closed and turned over to the city of Alexandria in 1995, the Army sought the most rapid and cost-effective means of spill remediation. At the request of the Baltimore District of the US Army Corps of Engineers, Argonne conducted a pilot-scale study to determine the feasibility of vapor extraction and bioventing for resolving remediation problems and to critique a private firm`s vapor-extraction design. Argonne staff, working with academic and private-sector participants, designed and implemented a new systems approach to sampling, analysis and risk assessment. The US Geological Survey`s AIRFLOW model was adapted for the study to simulate the performance of possible remediation designs. A commercial vapor-extraction machine was used to remove nearly 500 gal of gasoline from Argonne-installed horizontal wells. By incorporating numerous design comments from the Argonne project team, field personnel improved the system`s performance. Argonne staff also determined that bioventing stimulated indigenous bacteria to bioremediate the gasoline spin. The Corps of Engineers will use Argonne`s pilot-study approach to evaluate remediation systems at field operation sites in several states.

Development of tartaric esters as bifunctional additives of methanol-gasoline.

Science.gov (United States)

Zhang, Jie; Yang, Changchun; Tang, Ying; Zhou, Rui; Wang, Xiaoli; Xu, Lianghong

2014-01-01

Methanol has become an alternative fuel for gasoline, which is facing a rapidly rising world demand with a limited oil supply. Methanol-gasoline has been used in China, but phase stability and vapor lock still need to be resolved in methanol-gasoline applications. In this paper, a series of tartaric esters were synthesized and used as phase stabilizers and saturation vapor pressure depressors for methanol-gasoline. The results showed that the phase stabilities of tartaric esters for methanol-gasoline depend on the length of the alkoxy group. Several tartaric esters were found to be effective in various gasoline-methanol blends, and the tartaric esters display high capacity to depress the saturation vapor pressure of methanol-gasoline. According to the results, it can be concluded that the tartaric esters have great potential to be bifunctional gasoline-methanol additives.

National market of leaded gasoline. Technical aspects; Le marche national de l'essence plombee. Les aspects techniques

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-02-18

The French market of leaded gasoline which decreases annually since 1993 by about 10% still amounts at present (April 1999) about 4.5 million tons/yr, i.e., 31% of the whole gasoline market. By 1. of January 2000, the stock of private and service light vehicles constrained to use leaded gasoline will be of about 1.1 million; taking into account other additional uses, by that time the essential needs of leaded gasoline are expected to amount up to 1.5 million tons/yr. By 2003 the number of these vehicles are expected to decrease down to 300,000. Thus, it appears that since January 2000 up to probably 2003 the distribution pumps have to be provided with the fuel specific to the old vehicles. To prepare the cessation of leaded gasoline, already forbidden in certain countries since many years, the petroleum industry and additive manufacturers have carried out research to develop anti-detonation additives to replace the leaded additives. Potassium-based additives appears to be efficient for health of both engines and people and as such a proposal with validity starting since 1. 2000 was issued, complying with the EN228 Standard, for which the provisions of the Standard 98/70/CE are adapted to the French regulations. Thus, to comply with the European regulations concerning unleaded fuels the refineries will manufacture the SP 95 and SP 98, the latter being better adapted to be treated with unleaded additives. The document gives details concerning the logistics, supply and characteristics of the replacement fuels. Evolution of the super-fuel selling since January 1994 to January 1999 is plotted.

Detection of leaded-gasoline usage in catalyst-equipped vehicles: a gamma-ray transmission guage for measuring catalytic converter lead contamination

International Nuclear Information System (INIS)

Schneider, E.W.

1982-01-01

A gamma-ray transmission gauge has been developed for measuring the accumulation of lead inside the catalytic converters of vehicles operated on leaded gasoline. This nondestructive inspection system relates the amount of gamma radiation passing through the catalytic converter to the mass concentration of lead contained in the catalyst bed. Field studies have shown that vehicle usage of 200 L of leaded gasoline (0.34 g of Pb/L) can be detected at the 95% confidence level. Based on tests with one vehicle burning 1000 L of leaded gasoline, the accumulation rate of lead on the catalytic converter was relatively constant, accounting for 45% of the total lead consumed. Subsequent usage of unleaded gasoline resulted in no significant loss of lead from the catalytic converter

Health assessment of gasoline and fuel oxygenate vapors: developmental toxicity in mice.

Science.gov (United States)

Roberts, L G; Gray, T M; Marr, M C; Tyl, R W; Trimmer, G W; Hoffman, G M; Murray, F J; Clark, C R; Schreiner, C A

2014-11-01

CD-1 mice were exposed to baseline gasoline vapor condensate (BGVC) alone or to vapors of gasoline blended with methyl tertiary butyl ether (G/MTBE). Inhalation exposures were 6h/d on GD 5-17 at levels of 0, 2000, 10,000, and 20,000mg/m(3). Dams were evaluated for evidence of maternal toxicity, and fetuses were weighed, sexed, and evaluated for external, visceral, and skeletal anomalies. Exposure to 20,000mg/m(3) of BGVC produced slight reductions in maternal body weight/gain and decreased fetal body weight. G/MTBE exposure did not produce statistically significant maternal or developmental effects; however, two uncommon ventral wall closure defects occurred: gastroschisis (1 fetus at 10,000mg/m(3)) and ectopia cordis (1 fetus at 2000mg/m(3); 2 fetuses/1 litter at 10,000mg/m(3)). A second study (G/MTBE-2) evaluated similar exposure levels on GD 5-16 and an additional group exposed to 30,000mg/m(3) from GD 5-10. An increased incidence of cleft palate was observed at 30,000mg/m(3) G/MTBE. No ectopia cordis occurred in the replicate study, but a single observation of gastroschisis was observed at 30,000mg/m(3). The no observed adverse effect levels for maternal/developmental toxicity in the BGVC study were 10,000/2000mg/m(3), 20,000/20,000 for the G/MTBE study, and 10,000/20,000 for the G/MTBE-2 study. Copyright © 2014 The Authors. Published by Elsevier Inc. All rights reserved.

Reid Vapor Pressure (RVP) of Gasoline Spreadsheet Example Key for Requirements at 40 CFR 80.47(g) and 80.47(l)

Science.gov (United States)

This guidance deals with the self-qualification of analytical test methods at a testing facility for measuring Reid Vapor Pressure (RVP) of gasoline to meet precision requirements codified in regulations.

Health assessment of gasoline and fuel oxygenate vapors: micronucleus and sister chromatid exchange evaluations.

Science.gov (United States)

Schreiner, Ceinwen A; Hoffman, Gary M; Gudi, Ramadevi; Clark, Charles R

2014-11-01

Micronucleus and sister chromatid exchange (SCE) tests were performed for vapor condensate of baseline gasoline (BGVC), or gasoline with oxygenates, methyl tert-butyl ether (G/MTBE), ethyl tert butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), t-butyl alcohol (TBA), or ethanol (G/EtOH). Sprague Dawley rats (the same 5/sex/group for both endpoints) were exposed to 0, 2000, 10,000, or 20,000mg/m(3) of each condensate, 6h/day, 5days/week over 4weeks. Positive controls (5/sex/test) were given cyclophosphamide IP, 24h prior to sacrifice at 5mg/kg (SCE test) and 40mg/kg (micronucleus test). Blood was collected from the abdominal aorta for the SCE test and femurs removed for the micronucleus test. Blood cell cultures were treated with 5μg/ml bromodeoxyuridine (BrdU) for SCE evaluation. No significant increases in micronucleated immature erythrocytes were observed for any test material. Statistically significant increases in SCE were observed in rats given BGVC alone or in female rats given G/MTBE. G/TAME induced increased SCE in both sexes at the highest dose only. Although DNA perturbation was observed for several samples, DNA damage was not expressed as increased micronuclei in bone marrow cells. Inclusion of oxygenates in gasoline did not increase the effects of gasoline alone or produce a cytogenetic hazard. Copyright © 2014 Elsevier Inc. All rights reserved.

78 FR 34966 - Approval and Promulgation of Air Quality Implementation Plans; Wisconsin; Removal of Gasoline...

Science.gov (United States)

2013-06-11

... Promulgation of Air Quality Implementation Plans; Wisconsin; Removal of Gasoline Vapor Recovery From Southeast... specifically installed at gasoline dispensing facilities (GDF) and capture the refueling fuel vapors at the gasoline pump nozzle. The system carries the vapors back to the underground storage tank at the GDF to...

The uptake, distribution, metabolism, and excretion of methyl tertiary-butyl ether inhaled alone and in combination with gasoline vapor.

Science.gov (United States)

Benson, Janet M; Tibbetts, Brad M; Barr, Edward B

2003-06-13

The purpose of these studies was to evaluate the tissue uptake, distribution, metabolism, and excretion of methyl tertiary-butyl ether (MTBE) in rats and to determine the effects of coinhalation of the volatile fraction of unleaded gasoline on these parameters. Male F344 rats were exposed nose-only once for 4 h to 4, 40, or 400 ppm 14C-MTBE and to 20 and 200 ppm of the light fraction of unleaded gasoline (LFG) containing 4 and 40 ppm 14C-MTBE, respectively. To evaluate the effects of repeated inhalation of LFG on the fate of inhaled MTBE, rats were exposed for 7 consecutive days to 20 and 200 ppm LFG followed on d 8 by exposure to LFG containing 14C-MTBE. Three subgroups of rats were included for evaluation of respiratory parameters, rates and routes of excretion, and tissue distribution and elimination. MTBE and its chief metabolite, tertiary-butyl alcohol, were quantitated in blood and kidney (immediately after exposure), and the major urinary metabolites, 2-hydroxyisobutyric acid and 2-methyl-1,2- propanediol, were identified and quantified in urine. Inhalation of MTBE alone or as a component of LFG had no concentration-dependent effect on respiratory minute volume. The initial body burdens (IBBs) of MTBE equivalents achieved after 4 h of exposure to MTBE did not increase linearly with exposure concentration. MTBE equivalents rapidly distributed to all tissues examined, with the largest percentages distributed to liver. Between 40 and 400 ppm, there was a significant reduction in percentage of the IBB present in the major organs examined, both immediately and 72 h after exposure. At 400 ppm, the elimination rates of MTBE equivalents from tissues changed significantly. Furthermore, at 400 ppm there was a significant decrease in the elimination half-time of volatile organic compounds (VOCs) in breath and a significant increase in the percentage of the IBB of MTBE equivalents eliminated as VOCs in breath. LFG coexposure significantly decreased the percentage of the

Performance of a pilot-scale compost biofilter treating gasoline vapor

International Nuclear Information System (INIS)

Wright, W.F.; Schroeder, E.D.; Chang, D.P.Y.

1997-01-01

A pilot-scale compost biofiltration system was operated as gasoline soil vapor extraction site in Hayward, California for one year. The media was composed of equal volumes of compost and perlite, a bulking agent. Supplements added included nitrogen (as KNO 3 ), a gasoline degrading microbial inoculum, buffer (crushed oyster shell), and water. The biofiltration system was composed of four identical units with outside dimensions of 1.2 x 1.2 x 1.2 m (4 x 4 x 4 ft) operated in an up-flow mode. The units were configured in parallel during the first eight months and then reconfigured to two parallel systems of two units in series. Air flux values ranged from 0.29 to 1.0 m 3 /m 2 per min. Inlet total petroleum hydrogen hydrocarbon (TPH gas ) concentrations ranged from 310 to 2,700 mg/m 3 . The average empty bed contact time was 2.2 min. Following start-up, performance of the individual biofilters varied considerably for a seven-month period. The principal factor affecting performance appeared to be bed moisture content. Overall TPH gas removals reached 90% for short periods in one unit, and BTEX removals were typically above 90%. Drying resulted in channeling and loss of bed activity. Management of bed moisture content improved over the study period, and recovery of system performance was achieved without replacement of bed media. Overall TPH gas removals exceeded 90% during the final 50 days of the study

Petroleum Vapor Intrusion

Science.gov (United States)

One type of vapor intrusion is PVI, in which vapors from petroleum hydrocarbons such as gasoline, diesel, or jet fuel enter a building. Intrusion of contaminant vapors into indoor spaces is of concern.

78 FR 58184 - Approval and Promulgation of Implementation Plans; North Carolina; Removal of Stage II Gasoline...

Science.gov (United States)

2013-09-23

...] Approval and Promulgation of Implementation Plans; North Carolina; Removal of Stage II Gasoline Vapor... measures for new and upgraded gasoline dispensing facilities in the State. The September 18, 2009, SIP... .0953), entitled Vapor Return Piping for Stage II Vapor Recovery, for all new or improved gasoline tanks...

78 FR 72033 - Approval and Promulgation of Implementation Plans; Florida: General Requirements and Gasoline...

Science.gov (United States)

2013-12-02

...] Approval and Promulgation of Implementation Plans; Florida: General Requirements and Gasoline Vapor Control... Protection (FDEP), related to the State's gasoline vapor recovery program. This correcting amendment corrects... . SUPPLEMENTARY INFORMATION: This action corrects inadvertent errors in a rulemaking related to Florida's gasoline...

Short-term exposure of mice to gasoline vapor increases the metallothionein expression in the brain, lungs and kidney.

Science.gov (United States)

Grebić, D; Jakovac, H; Mrakovcić-Sutić, I; Tomac, J; Bulog, A; Micović, V; Radosević-Stasić, B

2007-06-01

Environmental airborne pollution has been repeatedly shown to affect multiple aspects of brain and cardiopulmonary function, leading to cognitive and behavioral changes and to the pronounced inflammatory response in the respiratory airways. Since in the cellular defense system the important role might have stress proteins-metallothionein (MT)-I and MT-II, which are involved in sequestration and dispersal of metal ions, regulation of the biosynthesis and activities of zinc-dependent transcription factors, as well as in cellular protection from reactive oxygen species, genotoxicity and apoptosis, in this study we investigated their expression in the brain, lungs and kidney, following intermittent exposure of mice to gasoline vapor. Control groups consisted of intact mice and of those closed in the metabolic chamber and ventilated with fresh air. The data obtained by immunohistochemistry showed that gasoline inhalation markedly upregulated the MTs expression in tissues which were directly or indirectly exposed to toxic components, significantly increasing the number of MT I+II positive cells in CNS (the entorhinal cortex, ependymal cells, astroglial cells in subventricular zone and inside the brain parenchyma, subgranular and CA1-CA3 zone of the dentate gyrus in hippocampus and macrophages-like cells in perivascular spaces), in the lungs (pneumocytes type I and type II) and in the kidneys (parietal wall of Bowman capsule, proximal and distal tubules). The data point to the protective and growth-regulatory effects of MT I + II on places of injuries, induced by inhalation of gasoline vapor.

78 FR 34303 - Approval and Promulgation of Implementation Plans; North Carolina; Removal of Stage II Gasoline...

Science.gov (United States)

2013-06-07

... Promulgation of Implementation Plans; North Carolina; Removal of Stage II Gasoline Vapor Recovery Program..., 2009, for the purpose of removing Stage II vapor control requirements for new and upgraded gasoline... Piping for Stage II Vapor Recovery, for all new or improved gasoline tanks. In addition, rule 15A-02D...

Investigation of bifunctional ester additives for methanol-gasoline system

International Nuclear Information System (INIS)

Zhang, J.; Yang, C.; Tang, Y.; Du, Q.; Song, N.; Zhang, Z.

2014-01-01

To explore new and multifunctional additives for methanol-gasoline, tartaric ester were synthesized and screened as phase stabilizer and saturation vapor pressure depressor for methanol-gasoline. The effect of the esters structure on the efficiency was discussed. The results show that the stabilities of the blends depend on the length of the glycolic esters alkoxy group. In addition, the tartaric esters also can depress the saturation vapor pressure of methanol-gasoline effectively in M15. Effect of the structure on the efficiency was also discussed. (author)

Carbón activado de semillas de tomate para adsorción de vapores de amoniaco, benceno y gasolina//Activated coal of tomato seeds for adsorption of vapors of ammonia, benzene and gasoline

Directory of Open Access Journals (Sweden)

Francisco Márquez-Montesino

2013-05-01

Full Text Available El objetivo fue comprobar las posibilidades de adsorción de amoniaco, benceno y gasolina en carbones activados, de semillas de tomate. Se realizó un análisis inmediato a la biomasa. Se concluyó que la adsorción de vapores de amoniaco, está relacionada con la adsorción física y con la presencia de gruposfuncionales de carácter ácido en la superficie activa de los carbones, que forman enlaces débiles con las moléculas de amoniaco. Se realizaron experimentos de adsorción de benceno y gasolina, que no tienen grupos funcionales como el amoniaco, siendo menos adsorbidos, confirmándose una adsorción preferentemente química. La temperatura de activación, la relación de impregnación (RI y laconcentración de la disolución ácida, no tuvieron una influencia significativa en la capacidad de adsorción de benceno, pero sí en la adsorción de amoniaco y vapores de gasolina, de gran aplicación para la eliminación de los vapores de escape en los motores de vehículos.Palabras claves: carbón, activación, adsorción, vapores, amoníaco._______________________________________________________________________________AbstractThe objective was to prove the adsorption possibilities of ammonia, benzene and vapors of gasoline in activated coals with phosphoric acid, of tomato seed. An immediate analysis to the biomass was carried out. It was concluded that the vapors adsorption of ammonia, is related with the physical adsorption andthe presence of functional groups of acid character in the active surface of the coal that form weak connections with the molecules of ammonia. Experiments of adsorption of benzene and gasoline were carried out, these substances haven't functional groups as the ammonia, so they were less adsorbed, and it was confirmed a chemical adsorption preferably. The activation temperature, the relationship of impregnation (RI and the concentration of the acid dissolution haven't a significant influence in the capacity of

Glutathione S-Transferase Gene Polymorphisms: Modulator of Genetic Damage in Gasoline Pump Workers.

Science.gov (United States)

Priya, Kanu; Yadav, Anita; Kumar, Neeraj; Gulati, Sachin; Aggarwal, Neeraj; Gupta, Ranjan

2015-01-01

This study investigated genetic damage in gasoline pump workers using the cytokinesis blocked micronucleus (CBMN) assay. Blood and urine samples were collected from 50 gasoline pump workers and 50 control participants matched with respect to age and other confounding factors except for exposure to benzene through gasoline vapors. To determine the benzene exposure, phenol was analyzed in urinary samples of exposed and control participants. Urinary mean phenol level was found to be significantly high (P gasoline pump workers (6.70 ± 1.78) when compared to control individuals (2.20 ± 0.63; P gasoline vapors can increase genotoxic risk in gasoline pump workers. © The Author(s) 2015.

The role of regulation, fiscal incentives and changes in tastes in the diffusion of unleaded petrol

International Nuclear Information System (INIS)

Stoneman, P.; Battisti, G.

2000-01-01

This paper analyses the diffusion of unleaded petrol in the UK. Changes in the market share of unleaded fuel are the results of changes in the composition of the car stock and changes in the choice of fuel given the car stock. We find the fuel type choices have been mainly driven by changes in tastes and learning as opposed to changes in relative prices induced by fiscal incentives. However car stock composition effects dominate the diffusion process and we find that through this route regulatory changes have made major contributions to changes in the market share of unleaded fuel. (Author)

Production of high anti-knock gasoline

Energy Technology Data Exchange (ETDEWEB)

1935-09-20

A process is described for producing gasoline of high antiknock value by separating from the gasoline of low antiknock value by treating the gasoline in the vapor phase under pressure equal to or slightly above atmospheric and at a temperature at which it does not form essentially hydrocarbons gaseous at the operating temperature and in contact with catalysts, the process being characterized by the utilization of catalysts of silicates or phosphates except pumice stone and fullers earth.

Petroleum product market report, issue 74, November 1992

International Nuclear Information System (INIS)

1992-11-01

The Petroleum Product Market Report (PPMR) is prepared in the Petroleum Products Section of the Canadian Oil Markets and Emergency Planning Division of Energy, Mines and Resources. The data is compiled from 10 major cities in Canada. The trends in sales and prices are compared on four petroleum products; regular unleaded gasoline, middle gasoline, premium unleaded gasoline and automotive diesel and propane. 7 tabs. 11 figs

Toxicological Assessments of Rats Exposed Prenatally to Inhaled Vapors of Gasoline and Gasoline-Ethanol Blends

Science.gov (United States)

The primary alternative to petroleum-based fuels is ethanol, which is blended with gasoline in the United States at concentrations up to 15% for most automobiles. Efforts to increase the amount of ethanol in gasoline have prompted concerns about the potential toxicity of inhaled ...

Benzine-keuzegedrag van automobilisten

NARCIS (Netherlands)

Borgers, A.W.J.; Waerden, van der P.J.H.J.

1990-01-01

Most gas stations in the Netherlands offer three types of gasoline: Euro (unleaded, low octane grade), Superplus (unleaded, high octane grade), and Super (leaded, high octane grade). Depending on the type of the car, many car drivers can choose between two or three types of gasoline. According to

Ethanol Demand in United States Gasoline Production

Energy Technology Data Exchange (ETDEWEB)

Hadder, G.R.

1998-11-24

The Oak Ridge National Laboratory (OWL) Refinery Yield Model (RYM) has been used to estimate the demand for ethanol in U.S. gasoline production in year 2010. Study cases examine ethanol demand with variations in world oil price, cost of competing oxygenate, ethanol value, and gasoline specifications. For combined-regions outside California summer ethanol demand is dominated by conventional gasoline (CG) because the premised share of reformulated gasoline (RFG) production is relatively low and because CG offers greater flexibility for blending high vapor pressure components like ethanol. Vapor pressure advantages disappear for winter CG, but total ethanol used in winter RFG remains low because of the low RFG production share. In California, relatively less ethanol is used in CG because the RFG production share is very high. During the winter in California, there is a significant increase in use of ethanol in RFG, as ethanol displaces lower-vapor-pressure ethers. Estimated U.S. ethanol demand is a function of the refiner value of ethanol. For example, ethanol demand for reference conditions in year 2010 is 2 billion gallons per year (BGY) at a refiner value of $1.00 per gallon (1996 dollars), and 9 BGY at a refiner value of $0.60 per gallon. Ethanol demand could be increased with higher oil prices, or by changes in gasoline specifications for oxygen content, sulfur content, emissions of volatile organic compounds (VOCS), and octane numbers.

40 CFR 80.27 - Controls and prohibitions on gasoline volatility.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Controls and prohibitions on gasoline... prohibitions on gasoline volatility. (a)(1) Prohibited activities in 1991. During the 1991 regulatory control... shall sell, offer for sale, dispense, supply, offer for supply, or transport gasoline whose Reid vapor...

Dissolution of multi-component LNAPL gasolines: The effects of weathering and composition

Science.gov (United States)

Lekmine, Greg; Bastow, Trevor P.; Johnston, Colin D.; Davis, Greg B.

2014-05-01

The composition of light non-aqueous phase liquid (LNAPL) gasoline and other petroleum products changes profoundly over their life once released into aquifers. However limited attention has been given to how such changes affect key parameters such as the activity coefficients which control partitioning of components of petroleum fuel into groundwater and are used to predict long-term risk from fuel releases. Laboratory experiments were conducted on a range of fresh, weathered and synthetic gasoline mixtures designed to mimic the expected changes in composition in an aquifer. Weathered gasoline created under controlled evaporation and water washing, and naturally weathered gasoline, were investigated. Equilibrium concentrations in water and molar fractions in the gasoline mixtures were compared with equilibrium concentrations predicted by Raoult's law assuming ideal behaviour of the solutions. The experiments carried out allowed the relative sensitivity of the activity coefficients of key risk drivers such as benzene, toluene, ethylbenzene and xylene (BTEX) compounds to be quantified with respect to the presence of other types of compounds and where the source LNAPL had undergone different types of weathering. Results differed for the mixtures examined but in some cases higher than predicted dissolved equilibrium concentrations showed non-ideal behaviour for toluene, benzene and xylenes. Comparison of the activity coefficients showed that the naturally weathered gasoline and a 50% evaporated unleaded gasoline present a similar range of values varying between 1.0 and 1.2, suggesting close to ideal partitioning between the LNAPL and water. The fresh and water-washed gasoline had higher values for the activity coefficient, from 1.2 to 1.4, indicating non-ideal partitioning. Results from synthetic mixtures demonstrated that these differences could be due to the different molar fractions of the nC5 and nC6 aliphatic hydrocarbons acting on the molecular interactions

MTBE inhaled alone and in combination with gasoline vapor: uptake, distribution, metabolism, and excretion in rats.

Science.gov (United States)

Benson, J M; Barr, E B; Krone, J R

2001-05-01

The purpose of these studies was to extend previous evaluation of methyl tert-butyl ether (MTBE)* tissue distribution, metabolism, and excretion in rats to include concentrations more relevant to human exposure (4 and 40 ppm) and to determine the effects of coinhalation of the volatile fraction of unleaded gasoline on the tissue distribution, metabolism, and excretion of MTBE. Groups of male F344 rats were exposed nose-only for 4 hours to 4, 40, or 400 ppm 14C-MTBE or to 20 or 200 ppm of the light fraction of unleaded gasoline (LFG) containing 4 or 40 ppm 14C-MTBE, respectively. To evaluate the effects of repeated inhalation of LFG on MTBE tissue distribution, metabolism, and excretion, rats were exposed for 4 hours on each of 7 consecutive days to 20 or 200 ppm LFG with MTBE (4 or 40 ppm) followed on the eighth day by a similar exposure to LFG containing 14C-MTBE. Subgroups of rats were evaluated for respiratory parameters, initial body burdens, rates and routes of excretion, and tissue distribution and elimination. The concentrations of MTBE and its chief metabolite, tert-butyl alcohol (TBA), were measured in blood and kidney immediately after exposure, and the major urinary metabolites-2-hydroxyisobutyric acid (IBA) and 2-methyl-1,2-propanediol (2MePD)-were measured in urine. Inhalation of MTBE alone or as a component of LFG had no concentration-dependent effect on respiratory minute volume. The initial body burdens of MTBE equivalents achieved after 4 hours of exposure to MTBE did not increase linearly with exposure concentration. MTBE equivalents rapidly distributed to all tissues examined, with the largest percentages distributed to liver. The observed initial body burden did not increase linearly between 4 and 400 ppm. At 400 ppm, elimination half-times of MTBE equivalents from liver increased and from lung, kidney, and testes decreased compared with the two smaller doses. Furthermore, at 400 ppm the elimination half-time for volatile organic compounds (VOCs

Reporting a sudden death due to accidental gasoline inhalation.

Science.gov (United States)

Martínez, María Antonia; Ballesteros, Salomé; Alcaraz, Rafael

2012-02-10

The investigation of uncertain fatalities requires accurate determination of the cause of death, with assessment of all factors that may have contributed to it. Gasoline is a complex and highly variable mixture of aliphatic and aromatic hydrocarbons that can lead to cardiac arrhythmias due to sensitization of the myocardium to catecholamines or acts as a simple asphyxiant if the vapors displace sufficient oxygen from the breathing atmosphere. This work describes a sudden occupational fatality involving gasoline. The importance of this petroleum distillate detection and its quantitative toxicological significance is discussed using a validated analytical method. A 51 year-old Caucasian healthy man without significant medical history was supervising the repairs of the telephone lines in a manhole near to a gas station. He died suddenly after inhaling gasoline vapors from an accidental leak. Extensive blistering and peeling of skin were observed on the skin of the face, neck, anterior chest, upper and lower extremities, and back. The internal examination showed a strong odor of gasoline, specially detected in the respiratory tract. The toxicological screening and quantitation of gasoline was performed by means of gas chromatography with flame ionization detector and confirmation was performed using gas chromatography-mass spectrometry. Disposition of gasoline in different tissues was as follows: heart blood, 35.7 mg/L; urine, not detected; vitreous humor, 1.9 mg/L; liver, 194.7 mg/kg; lung, 147.6 mg/kg; and gastric content, 116,6 mg/L (2.7 mg total). Based upon the toxicological data along with the autopsy findings, the cause of death was determined to be gasoline poisoning and the manner of death was accidental. We would like to alert on the importance of testing for gasoline, and in general for volatile hydrocarbons, in work-related sudden deaths involving inhalation of hydrocarbon vapors and/or exhaust fumes. Copyright © 2011 Elsevier Ireland Ltd. All rights

Determination of Cu, Mn, Ni and Sn in gasoline by electrothermal vaporization inductively coupled plasma mass spectrometry, and emulsion sample introduction

International Nuclear Information System (INIS)

Saint'Pierre, Tatiana D.; Dias, Lucia Felicidade; Pozebon, Dirce; Aucelio, Ricardo Q.; Curtius, Adilson J.; Welz, Bernhard

2002-01-01

Trace metals in fuels, except in the case of additives, are usually undesirable and normally they occur in very low concentrations in gasoline, requiring sensitive techniques for their determination. Coupling of electrothermal vaporization with inductively coupled plasma mass spectrometry minimizes the problems related to the introduction of organic solvents into the plasma. Furthermore, sample preparation as oil-in-water emulsions reduces problems related to gasoline analysis. In this work, a method for determination of Cu, Mn, Ni and Sn in gasoline is proposed. Samples were prepared by forming a 10-fold diluted emulsion with a surfactant (Triton X-100), after treatment with concentrated HNO 3 . The sample emulsion was pre-concentrated in the graphite tube by repeated pipetting and drying. External calibration was used with aqueous standards in a purified gasoline emulsion. Six samples from different gas stations were analyzed, and the analyte concentrations were found to be in the μg l -1 range or below. The limits of detection were 0.22, 0.02, 0.38 and 0.03 μg l -1 for Cu, Mn, Ni and Sn, respectively. The accuracy of the method was estimated using a recovery test

VOC composition of current motor vehicle fuels and vapors, and collinearity analyses for receptor modeling.

Science.gov (United States)

Chin, Jo-Yu; Batterman, Stuart A

2012-03-01

The formulation of motor vehicle fuels can alter the magnitude and composition of evaporative and exhaust emissions occurring throughout the fuel cycle. Information regarding the volatile organic compound (VOC) composition of motor fuels other than gasoline is scarce, especially for bioethanol and biodiesel blends. This study examines the liquid and vapor (headspace) composition of four contemporary and commercially available fuels: gasoline (gasoline), ultra-low sulfur diesel (ULSD), and B20 (20% soy-biodiesel and 80% ULSD). The composition of gasoline and E85 in both neat fuel and headspace vapor was dominated by aromatics and n-heptane. Despite its low gasoline content, E85 vapor contained higher concentrations of several VOCs than those in gasoline vapor, likely due to adjustments in its formulation. Temperature changes produced greater changes in the partial pressures of 17 VOCs in E85 than in gasoline, and large shifts in the VOC composition. B20 and ULSD were dominated by C(9) to C(16)n-alkanes and low levels of the aromatics, and the two fuels had similar headspace vapor composition and concentrations. While the headspace composition predicted using vapor-liquid equilibrium theory was closely correlated to measurements, E85 vapor concentrations were underpredicted. Based on variance decomposition analyses, gasoline and diesel fuels and their vapors VOC were distinct, but B20 and ULSD fuels and vapors were highly collinear. These results can be used to estimate fuel related emissions and exposures, particularly in receptor models that apportion emission sources, and the collinearity analysis suggests that gasoline- and diesel-related emissions can be distinguished. Copyright © 2011 Elsevier Ltd. All rights reserved.

Effects of gasoline aromatic content on emissions of volatile organic compounds and aldehydes from a four-stroke motorcycle.

Science.gov (United States)

Yao, Yung-Chen; Tsai, Jiun-Horng

2013-01-01

A new four-stroke carburettor motorcycle engine without any engine adjustments was used to study the impact of fuel aromatic content on the exhaust emissions of organic air pollutants (volatile organic compounds and carbonyls). Three levels of aromatic content, i.e. 15, 25, and 50% (vol.) aromatics mixed with gasoline were tested. The emissions of aromatic fuel were compared with those of commercial unleaded gasoline. The results indicated that the A 15 (15 vol% aromatics in gasoline) fuel exhibited the greatest total organic emission improvement among these three aromatic fuels as compared with commercial gasoline, reaching 59%. The highest emission factors of alkanes, alkenes, and carbonyl groups appeared in the reference fuel (RF) among all of the test fuels. A 15 showed the highest emission reduction in alkanes (73%), aromatics (36%), and carbonyls (28%), as compared to those of the RF. The highest emission reduction ofalkenes was observed when using A25 as fuel. A reduction in fuel aromatic content from 50 to 25 and 15 vol% in gasoline decreased benzene and toluene emissions, but increased the aldehyde emissions. In general, the results showed that the highest emission reductions for the most of measured organic pollutants appeared when using A 15 as the fuel.

Effect of honey supplementation on toxicity of gasoline vapor exposure in rats

OpenAIRE

M B Abubakar; W Z Abdullah; S A Sulaiman; F E Uboh; B S Ang

2013-01-01

Summary. Different health risks including haematotoxicity and weight loss have been reported for gasoline. Supplementation with antioxidants such as vitamins A, C, and E has been shown to ameliorate the toxicity effects of gasoline vapours exposure. Honey contains vitamins, and polyphenols that possess good antioxidant properties. The potential role of honey in preventing gasoline-induced haematotoxicity and weight loss was assessed in male rats. The rats were exposed to gasoline (11.13±1.1cm...

Investigation of n-butanol as fuel in a four-cylinder MPFI SI engine

International Nuclear Information System (INIS)

Dhamodaran, Gopinath; Esakkimuthu, Ganapathy Sundaram; Pochareddy, Yashwanth Kutti; Sivasubramanian, Harish

2017-01-01

Global concern over rising greenhouse gas emission levels and the availability of fossil fuels has led to the development of biofuels, and the use of gasoline formulations with oxygenated compounds has become common practice for improving fuel quality. This empirical study evaluated the effects of oxygenated gasoline fuel blends on air quality. Tests were conducted on a four-stroke, four-cylinder multi-point fuel injection (MPFI) spark ignition (SI) engine using an eddy current dynamometer to investigate the combustion and emissions behaviour of n-butanol blends. Blends comprising n-butanol (N10, N20, and N30) and unleaded gasoline were tested over a rotational speed range of 1400 rpm–2800 rpm under a constant load of 20 Nm. The results obtained indicate that use of n-butanol blends produced lower hydrocarbon (HC) and carbon monoxide (CO) levels than unleaded gasoline but nitrogen oxide (NO_x) emissions were found to be higher. When ignition timing was retarded, NOx emissions for all n-butanol blends decreased. The peak in-cylinder pressures and heat release rates for the blends were also found to be higher than for unleaded gasoline (UG). COV_I_M_E_P of gasoline was higher than that of n-butanol/gasoline blends. - Highlights: • Using oxygenated compound gasoline formulations is common for improving fuel quality. • Blends of n-butanol with unleaded gasoline were tested between 1400 rpm and 2800 rpm. • Blends increased brake thermal efficiency and produced lower HC and CO but higher NOx. • Lower NOx was observed when ignition timing was retarded. • Peak in-cylinder pressures and heat release rates for blends were higher.

Using in situ bioventing to minimize soil vapor extraction costs

International Nuclear Information System (INIS)

Downey, D.C.; Frishmuth, R.A.; Archabal, S.R.; Pluhar, C.J.; Blystone, P.G.; Miller, R.N.

1995-01-01

Gasoline-contaminated soils may be difficult to remediate with bioventing because high concentrations of gasoline vapors become mobile when air is injected into the soil. Because outward vapor migration is often unacceptable on small commercial sites, soil vapor extraction (SVE) or innovative bioventing techniques are required to control vapors and to increase soil gas oxygen levels to stimulate hydrocarbon biodegradation. Combinations of SVE, off-gas treatment, and bioventing have been used to reduce the costs normally associated with remediation of gasoline-contaminated sites. At Site 1, low rates of pulsed air injection were used to provide oxygen while minimizing vapor migration. At Site 2, a period of high-rate SVE and off-gas treatment was followed by long-term air injection. Site 3 used an innovative approach that combined regenerative resin for ex situ vapor treatment with in situ bioventing to reduce the overall cost of site remediation. At each of these Air Force sites, bioventing provided cost savings when compared to more traditional SVE methods

Vapor recovery system in the gasolines commercialization; Sistema de recuperacion de vapores en la comercializacion de las gasolinas

Energy Technology Data Exchange (ETDEWEB)

Casas Barba, R.; Molina Gallegos, J.R. [Instituto Mexicano del Petroleo (IMP), Mexico, D. F. (Mexico)

1995-12-31

In the last years the studies performed with respect to the environmental pollution show that the ozone is one of the most problematic contaminants in the Metropolitan Zone of Mexico City (MZMC) and that the hydrocarbons are the main forerunners of it. The main source of hydrocarbon vapor emissions originates from the handling and distribution operations. In this paper a description is made of the involved stages in the commercialization of gasolines in the MZMC and a description is also made of the systems employed to control the emissions in the three stages of the fuels storage and distribution cycle and explains the degree the hydrocarbon emissions to the atmosphere will be reduced, once the recovery systems are installed in all of the involved stages. [Espanol] En los ultimos anos los estudios realizados con respecto a contaminacion ambiental reflejan que el ozono es uno de los contaminantes mas problematicos de la zona metropolitana de la ciudad de Mexico (ZMCM), y los hidrocarburos son los principales precursores de este. La principal fuente de emision de vapores de hidrocarburos proviene de las operaciones de manejo y distribucion de combustibles. En este articulo se hace una descripcion de las etapas involucradas en la comercializacion de las gasolinas en la ZMCM, se describen tambien los sistemas utilizados para controlar las emisiones en las tres etapas del ciclo de almacenamiento y distribucion de combustibles y se explica en que grado se reduciran las emisiones de hidrocarburos a la atmosfera, una vez que se instalen los sistemas de recuperacion en todas las etapas involucradas.

Vapor recovery system in the gasolines commercialization; Sistema de recuperacion de vapores en la comercializacion de las gasolinas

Energy Technology Data Exchange (ETDEWEB)

Casas Barba, R; Molina Gallegos, J R [Instituto Mexicano del Petroleo (IMP), Mexico, D. F. (Mexico)

1996-12-31

In the last years the studies performed with respect to the environmental pollution show that the ozone is one of the most problematic contaminants in the Metropolitan Zone of Mexico City (MZMC) and that the hydrocarbons are the main forerunners of it. The main source of hydrocarbon vapor emissions originates from the handling and distribution operations. In this paper a description is made of the involved stages in the commercialization of gasolines in the MZMC and a description is also made of the systems employed to control the emissions in the three stages of the fuels storage and distribution cycle and explains the degree the hydrocarbon emissions to the atmosphere will be reduced, once the recovery systems are installed in all of the involved stages. [Espanol] En los ultimos anos los estudios realizados con respecto a contaminacion ambiental reflejan que el ozono es uno de los contaminantes mas problematicos de la zona metropolitana de la ciudad de Mexico (ZMCM), y los hidrocarburos son los principales precursores de este. La principal fuente de emision de vapores de hidrocarburos proviene de las operaciones de manejo y distribucion de combustibles. En este articulo se hace una descripcion de las etapas involucradas en la comercializacion de las gasolinas en la ZMCM, se describen tambien los sistemas utilizados para controlar las emisiones en las tres etapas del ciclo de almacenamiento y distribucion de combustibles y se explica en que grado se reduciran las emisiones de hidrocarburos a la atmosfera, una vez que se instalen los sistemas de recuperacion en todas las etapas involucradas.

78 FR 65875 - Approval and Promulgation of Air Quality Implementation Plans; Wisconsin; Removal of Gasoline...

Science.gov (United States)

2013-11-04

...] Approval and Promulgation of Air Quality Implementation Plans; Wisconsin; Removal of Gasoline Vapor... Administrative Code, Chapter NR 420 Control of Organic Compound Emissions from Petroleum and Gasoline Sources... FROM PETROLEUM AND GASOLINE SOURCES. NR 420.01 as published in the (Wisconsin) Register, February, 1990...

Evaporative Gasoline Emissions and Asthma Symptoms

Science.gov (United States)

Gordian, Mary Ellen; Stewart, Alistair W; Morris, Stephen S

2010-01-01

Attached garages are known to be associated with indoor air volatile organic compounds (VOCs). This study looked at indoor exposure to VOCs presumably from evaporative emissions of gasoline. Alaskan gasoline contains 5% benzene making benzene a marker for gasoline exposure. A survey of randomly chosen houses with attached garages was done in Anchorage Alaska to determine the exposure and assess respiratory health. Householders were asked to complete a health survey for each person and a household survey. They monitored indoor air in their primary living space for benzene, toluene, ethylbenzene and xylenes for one week using passive organic vapor monitoring badges. Benzene levels in homes ranged from undetectable to 58 parts per billion. The median benzene level in 509 homes tested was 2.96 ppb. Elevated benzene levels in the home were strongly associated with small engines and gasoline stored in the garage. High concentrations of benzene in gasoline increase indoor air levels of benzene in residences with attached garages exposing people to benzene at levels above ATSDR’s minimal risk level. Residents reported more severe symptoms of asthma in the homes with high gasoline exposure (16%) where benzene levels exceeded the 9 ppb. PMID:20948946

Possibility of content change in bioethanol gasoline during pre-treatment process for using accelerator mass spectroscopy

International Nuclear Information System (INIS)

Saito, Masaaki; Yunoki, Shunji; Suzuki, Takashi

2010-01-01

We attempted to determine the bioethanol content of E3 gasoline by applying ASTM D6866 method B. In the pre-treatment process using accelerator mass spectroscopy(AMS), the graphite samples were prepared from E3 gasoline. Three portions of the same graphite sample were measured, and the contents agreed within the measurement error of AMS. The graphite samples prepared from eight portions of the same E3 gasoline sample were measured, but the accuracy was insufficient. There are many kinds of hydrocarbon compounds in the gasoline and their boiling points are different. The content of bioethanol was found to decrease with vaporization when E3 gasoline was placed in open air. A very small amount of E3 gasoline is pre-treated for AMS and the volatile loss cannot be ignored. It seems that the content change of bioethanol was caused by vaporization of E3 gasoline during the pre-treatment process. (author)

The final fifteen feet of hose : the Canadian gasoline industry in the year 2000

International Nuclear Information System (INIS)

Sperber, M.; Beckman, K.; Clavet, F.; Bernard, M.-C.; Bussiere, L.; Frank, J.; Lefebvre, M.

2001-01-01

An up-to-date profile of the Canadian gasoline industry was presented with an effort to address some of the preoccupations of industry stakeholders and the perceptions of Canadian motorists. This study provides new insights into the workings of the industry by providing a balanced perspective on the many contentious issues that affect the industry, particularly retail pricing. The Conference Board's empirical analysis makes use of a new approach which provides a better understanding of how retail prices react to changes in wholesale prices. Competition is the reason why a retail market outcome margin exists in each city based on local conditions. This margin is the basis for price changes in that market and reflects a margin at which most competitors are able to sustain themselves. When changes occur in the wholesale price of crude, the retail price is adjusted depending on whether the actual margin in place is higher or lower than the market outcome margin. Crude oil and taxes make up about 84 per cent of the average price of a litre of regulated unleaded gasoline. The main reason for rising Canadian gasoline prices is the rapid increase in world crude oil prices. The volatility in gasoline prices is a direct result of the competitive nature of the business at the street level and the uniformity of prices reflects the rapid response of individual dealers to the actions of their competitors. Each outlet has fixed costs to cover, therefore average sales volumes per outlet have an important impact on retail margins and prices. It was also emphasized that there is no empirical proof that gasoline prices increase before long weekends, nor is there any proof of asymmetry in price adjustment in the retail market. It was noted that the price of gasoline in Canada and the United States, excluding taxes, is very similar. 15 tabs., 59 figs

76 FR 40246 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Control of Gasoline...

Science.gov (United States)

2011-07-08

... ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 52 [EPA-R05-OAR-2006-0976; FRL-9430-5] Approval and Promulgation of Air Quality Implementation Plans; Ohio; Control of Gasoline Volatility; Correction AGENCY... a gasoline Reid Vapor Pressure (RVP) limit of 7.8 pounds per square inch (psi) for gasoline sold in...

40 CFR 63.11116 - Requirements for facilities with monthly throughput of less than 10,000 gallons of gasoline.

Science.gov (United States)

2010-07-01

... monthly throughput of less than 10,000 gallons of gasoline. 63.11116 Section 63.11116 Protection of... Hazardous Air Pollutants for Source Category: Gasoline Dispensing Facilities Emission Limitations and... gallons of gasoline. (a) You must not allow gasoline to be handled in a manner that would result in vapor...

Measured and Predicted Vapor Liquid Equilibrium of Ethanol-Gasoline Fuels with Insight on the Influence of Azeotrope Interactions on Aromatic Species Enrichment and Particulate Matter Formation in Spark Ignition Engines

Energy Technology Data Exchange (ETDEWEB)

Ratcliff, Matthew A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); McCormick, Robert L [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Burke, Stephen [Colorado State University; Rhoads, Robert [University of Colorado; Windom, Bret [Colorado State University

2018-04-03

A relationship has been observed between increasing ethanol content in gasoline and increased particulate matter (PM) emissions from direct injection spark ignition (DISI) vehicles. The fundamental cause of this observation is not well understood. One potential explanation is that increased evaporative cooling as a result of ethanol's high HOV may slow evaporation and prevent sufficient reactant mixing resulting in the combustion of localized fuel rich regions within the cylinder. In addition, it is well known that ethanol when blended in gasoline forms positive azeotropes which can alter the liquid/vapor composition during the vaporization process. In fact, it was shown recently through a numerical study that these interactions can retain the aromatic species within the liquid phase impeding the in-cylinder mixing of these compounds, which would accentuate PM formation upon combustion. To better understand the role of the azeotrope interactions on the vapor/liquid composition evolution of the fuel, distillations were performed using the Advanced Distillation Curve apparatus on carefully selected samples consisting of gasoline blended with ethanol and heavy aromatic and oxygenated compounds with varying vapor pressures, including cumene, p-cymene, 4-tertbutyl toluene, anisole, and 4-methyl anisole. Samples collected during the distillation indicate an enrichment of the heavy aromatic or oxygenated additive with an increase in initial ethanol concentration from E0 to E30. A recently developed distillation and droplet evaporation model is used to explore the influence of dilution effects versus azeotrope interactions on the aromatic species enrichment. The results suggest that HOV-cooling effects as well as aromatic species enrichment behaviors should be considered in future development of predictive indices to forecast the PM potential of fuels containing oxygenated compounds with comparatively high HOV.

Gasoline toxicology: overview of regulatory and product stewardship programs.

Science.gov (United States)

Swick, Derek; Jaques, Andrew; Walker, J C; Estreicher, Herb

2014-11-01

Significant efforts have been made to characterize the toxicological properties of gasoline. There have been both mandatory and voluntary toxicology testing programs to generate hazard characterization data for gasoline, the refinery process streams used to blend gasoline, and individual chemical constituents found in gasoline. The Clean Air Act (CAA) (Clean Air Act, 2012: § 7401, et seq.) is the primary tool for the U.S. Environmental Protection Agency (EPA) to regulate gasoline and this supplement presents the results of the Section 211(b) Alternative Tier 2 studies required for CAA Fuel and Fuel Additive registration. Gasoline blending streams have also been evaluated by EPA under the voluntary High Production Volume (HPV) Challenge Program through which the petroleum industry provide data on over 80 refinery streams used in gasoline. Product stewardship efforts by companies and associations such as the American Petroleum Institute (API), Conservation of Clean Air and Water Europe (CONCAWE), and the Petroleum Product Stewardship Council (PPSC) have contributed a significant amount of hazard characterization data on gasoline and related substances. The hazard of gasoline and anticipated exposure to gasoline vapor has been well characterized for risk assessment purposes. Copyright © 2014 The Authors. Published by Elsevier Inc. All rights reserved.

Research of performance on a spark ignition engine fueled by alcohol–gasoline blends using artificial neural networks

International Nuclear Information System (INIS)

Kapusuz, Murat; Ozcan, Hakan; Yamin, Jehad Ahmad

2015-01-01

In this paper, we investigate various alcohol–unleaded gasoline mixtures that can be used with no modifications in a spark-ignition engine. The mixtures consisted of 5%, 10% and 15% ethanol, methanol together and separately. Based on the recommendations of the Jordanian Petroleum Company (JoPetrol), total alcohol content should not exceed 15–20% owing to safety and ignition hazards. Optimizations for the use of alcohol were made for the maximum torque, maximum power and minimum specific fuel consumption values. For torque 0.9906, for brake power 0.997, and for brake specific fuel consumption 0.9312 regression values for tests have been obtained from models generated by the neural network. According to the modeling and optimizations, use of fuel mixture containing 11% methanol–1% ethanol for performance, and fuel mixture containing 2% methanol for BSFC were found to have better results. Moreover, the paper demonstrates that ANN (Artificial Neural Network) can be used successfully as an alternative type of modeling technique for internal combustion engines. - Highlights: • ANN model was developed and verified. • Effects of alcohol–gasoline blends on performance of a SI engine are fairly simulated. • Effects of alcohol–gasoline blends on performance of a SI engine are optimized.

Structure Analysis and Properties of Unleaded Brasses

Directory of Open Access Journals (Sweden)

Rzadkosz S.

2015-04-01

Full Text Available The analysis of brasses regarding their microstructure, mechanical properties and ecological characteristics has been presented. The influence of characteristic alloying elements contained in the brasses and the possibilities of replacing them with other elements have been assessed. The paper contains the results of studies on the influence of chosen additional elements shaping the structure and properties of unleaded alloys based on Cu-Zn system as the matrix. The research aimed at determining the mechanism and the intensity of influence of such additives as tellurium and bismuth. The microstructures were investigated with the help of light microscopy and scanning electron microscopy with X-ray microanalysis (SEM-EDS for determining significant changes of the properties.

Remediation of gasoline-contaminated soil by passive volatilization

International Nuclear Information System (INIS)

Donaldson, S.G.; Miller, G.C.; Miller, W.W.

1992-01-01

Loss of 10 hydrocarbons characteristic of those found in gasoline (benzene; n-heptane; toluene; m-xylene; n-nonane; n-propylbenzene; 1,2,4-trimethylbenzene; n-butylbenzene; 1,2,4,5-tetramethylbenzene; and n-dodecane) from 20-cm soil layers was investigated in several field experiments. Soil was spiked with 50 mg kg -1 of each compound, placed in pans outdoors, and subjected to one of five treatments: dry, unmixed soil; dry soil mixed weekly; soil watered once only; soil watered periodically; and soil watered and mixed periodically. Significantly greater rates of loss occurred from wet soils, with an average of 5.7% remaining in wet and mixed treatments at the 18- to 20-cm depth on Day 32 of the spring experiment, compared with 61% remaining in dry, unmixed soils. Following wetting of the soil by rain, less than 8% overall remained in any soil layer by Day 64. Loss was greatest during the summer experiment. By Day 32, only tetramethylbenzene and dodecane were measurable for the wet treatments, with totals below 5% at the 18- to 20-cm depth. An average of 48.6% remained in the dry soils. The final experiment during fall 1989 demonstrated loss of 500 mg kg -1 of unleaded gasoline from spiked soil. No measurable amounts remained after 8 d in wet and mixed treatments and 16 d in wet, unmixed treatments, bu 3.5% remained after 32 d in initially dry soil

The electrostatic properties of Fiber-Reinforced-Plastics double wall underground storage gasoline tanks

International Nuclear Information System (INIS)

Li, Yipeng; Liu, Quanzhen; Meng, He; Sun, Lifu; Zhang, Yunpeng

2013-01-01

At present Fiber Reinforced Plastics (FRP) double wall underground storage gasoline tanks are wildly used. An FRP product with a resistance of more than 10 11 Ω is a static non-conductor, so it is difficult for the static electricity in the FRP product to decay into the earth. In this paper an experimental system was built to simulate an automobile gasoline filling station. Some electrostatic parameters of the gasoline, including volume charge density, were tested when gasoline was unloaded into a FRP double wall underground storage tank. Measurements were taken to make sure the volume charge density in the oil-outlet was similar to the volume charge density in the tank. In most cases the volume charge density of the gasoline was more than 22.7 μC m −3 , which is likely to cause electrostatic discharge in FRP double wall underground storage gasoline tanks. On the other hand, it would be hard to ignite the vapor by electrostatic discharge since the vapor pressure in the tanks is over the explosion limit. But when the tank is repaired or re-used, the operators must pay attention to the static electricity and some measurements should be taken to avoid electrostatic accident. Besides the relaxation time of charge in the FRP double wall gasoline storage tanks should be longer.

Effects of maternal inhalation of gasoline evaporative condensates on sensory function in rat offspring

Science.gov (United States)

In order to assess potential health effects resulting from exposure to ethanol-gasoline blend vapors, we previously conducted neurophysiological assessment of sensory function following gestational exposure to 100% ethanol vapor (Herr et al., Toxicologist, 2012). For comparison p...

Brugada syndrome unmasked by accidental inhalation of gasoline vapors

DEFF Research Database (Denmark)

Kranjcec, Darko; Bergovec, Mijo; Rougier, Jean-Sébastien

2007-01-01

Loss-of-function mutations in the gene SCN5A can cause Brugada syndrome (BrS), which is an inherited form of idiopathic ventricular fibrillation. We report the case of a 46-year-old patient, with no previous medical history, who had ventricular fibrillation after accidental inhalation of gasoline...

Effects of maternal inhalation of gasoline evaporative ...

Science.gov (United States)

In order to assess potential health effects resulting from exposure to ethanol-gasoline blend vapors, we previously conducted neurophysiological assessment of sensory function following gestational exposure to 100% ethanol vapor (Herr et al., Toxicologist, 2012). For comparison purposes, the current study investigated the same measures after gestational exposure to 100% gasoline evaporative condensates (GVC). Pregnant Long-Evans rats were exposed to 0, 3K, 6K, or 9K ppm GVC vapors for 6.5 h/day over GD9 – GD20. Sensory evaluations of male offspring began around PND106. Peripheral nerve function (compound action potentials, NCV), somatosensory (cortical and cerebellar evoked potentials), auditory (brainstem auditory evoked responses), and visual evoked responses were assessed. Visual function assessment included pattern elicited visual evoked potentials (VEP), VEP contrast sensitivity, and electroretinograms (ERG) recorded from dark-adapted (scotopic) and light-adapted (photopic) flashes, and UV and green flicker. Although some minor statistical differences were indicated for auditory and somatosensory responses, these changes were not consistently dose- or stimulus intensity-related. Scotopic ERGs had a statistically significant dose-related decrease in the b-wave implicit time. All other parameters of ERGs and VEPs were unaffected by treatment. All physiological responses showed changes related to stimulus intensity, and provided an estimate of detectable le

Assessment of lung cell toxicity of various gasoline engine exhausts using a versatile in vitro exposure system.

Science.gov (United States)

Bisig, Christoph; Comte, Pierre; Güdel, Martin; Czerwinski, Jan; Mayer, Andreas; Müller, Loretta; Petri-Fink, Alke; Rothen-Rutishauser, Barbara

2018-04-01

Adverse effect studies of gasoline exhaust are scarce, even though gasoline direct injection (GDI) vehicles can emit a high number of particles. The aim of this study was to conduct an in vitro hazard assessment of different GDI exhausts using two different cell culture models mimicking the human airway. In addition to gasoline particle filters (GPF), the effects of two lubrication oils with low and high ash content were assessed, since it is known that oils are important contributors to exhaust emissions. Complete exhausts from two gasoline driven cars (GDI1 and GDI2) were applied for 6 h (acute exposure) to a multi-cellular human lung model (16HBE14o-cell line, macrophages, and dendritic cells) and a primary human airway model (MucilAir™). GDI1 vehicle was driven unfiltered and filtered with an uncoated and a coated GPF. GDI2 vehicle was driven under four settings with different fuels: normal unleaded gasoline, 2% high and low ash oil in gasoline, and 2% high ash oil in gasoline with a GPF. GDI1 unfiltered was also used for a repeated exposure (3 times 6 h) to assess possible adverse effects. After 6 h exposure, no genes or proteins for oxidative stress or pro-inflammation were upregulated compared to the filtered air control in both cell systems, neither in GDI1 with GPFs nor in GDI2 with the different fuels. However, the repeated exposure led to a significant increase in HMOX1 and TNFa gene expression in the multi-cellular model, showing the responsiveness of the system towards gasoline engine exhaust upon prolonged exposure. The reduction of particles by GPFs is significant and no adverse effects were observed in vitro during a short-term exposure. On the other hand, more data comparing different lubrication oils and their possible adverse effects are needed. Future experiments also should, as shown here, focus on repeated exposures. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

Lead Isotope Characterization of Petroleum Fuels in Taipei, Taiwan

Directory of Open Access Journals (Sweden)

Pei-Hsuan Yao

2015-04-01

Full Text Available Leaded gasoline in Taiwan was gradually phased out from 1983 to 2000. However, it is unclear whether unleaded gasoline still contributes to atmospheric lead (Pb exposure in urban areas. In this study, Pb isotopic compositions of unleaded gasolines, with octane numbers of 92, 95, 98, and diesel from two local suppliers in Taipei were determined by multi-collector inductively coupled plasma mass spectrometry with a two-sigma uncertainty of ± 0.02 %. Lead isotopic ratios of vehicle exhaust (208Pb/207Pb: 2.427, 206Pb/207Pb: 1.148, as estimated from petroleum fuels overlap with the reported aerosol data. This agreement indicates that local unleaded petroleum fuels, containing 10–45 ng·Pb·g−1, are merely one contributor among various sources to urban aerosol Pb. Additionally, the distinction between the products of the two companies is statistically significant in their individual 208Pb/206Pb ratios (p-value < 0.001, t test. Lead isotopic characterization appears to be applicable as a “fingerprinting” tool for tracing the sources of Pb pollution.

Historical review of European gasoline lead content regulations and their impact on German industrial markets

Energy Technology Data Exchange (ETDEWEB)

Hagner, C. [GKSS-Forschungszentrum Geesthacht GmbH (Germany). Inst. fuer Hydrophysik

1999-07-01

Environmental protection policies in the automobile market were not implemented until the motorisation of the masses in the 1960s caused an increasing environmental burden. The rising air pollution was considered a latent danger for humans, animals and plants. In the years up to 1985 the EU passed several regulations to limit the mass pollutants CO, CxHy and NOx. Germany was the first EU-member nation to also be concerned with lead in gasoline, passing reduction regulations as early as in 1971. In 1986, several EU-member nations implemented the supply of unleaded gasoline. This decision was predominantly based on information about widespread forest damage. The reduction of lead emissions due to these regulations could be verified in different environmental systems. An example of this was the decline of atmospheric lead concentrations and human blood lead levels in Germany. The German mineral oil and automobile markets were also affected. The price trend of unleaded fuel was heavily influenced by tax incentives which benefited not only the gasoline traders but also the consumers. With regard to the distribution system, the market positions particularly of the medium-sized traders and the independent importers were weakened. In the automobile market, favourable terms of competition were experienced by producers who had already gained experience with catalyst systems in the U.S.-market. The gasoline lead content regulations had no effects on further economic indicators, except for competition. (orig.) [German] Infolge der Massenmotorisierung in den 60er Jahren stieg die Umweltbelastung durch den Automobilverkehr stark an. Luftverschmutzung durch Kraftfahrzeuge wurde erstmalig als latente Gefahr fuer die Gesundheit von Mensch, Tier und Pflanze wahrgenommen. Dies charakterisierte den Beginn der Umweltpolitik im Automobilsektor. Bis 1985 verabschiedete die Europaeische Union (EU) mehrere Rahmenrichtlinien zur Reduktion der Luftschadstoffe CO, CxHy und NOx. 1971 war

Deleterious effects of water-soluble fraction of petroleum, diesel and gasoline on marine pejerrey Odontesthes argentinensis larvae

International Nuclear Information System (INIS)

Rodrigues, Ricardo Vieira; Miranda-Filho, Kleber Campos; Gusmao, Emeline Pereira; Moreira, Caue Bonucci; Romano, Luis Alberto; Sampaio, Luis Andre

2010-01-01

Accidental discharges and oil spills are frequent around the world. Petroleum-derived hydrocarbons are considered one of the main pollutants of aquatic ecosystem. The importance of petroleum and refined fuels is notorious because today's society depends on them. Researches related to the toxic water-soluble fraction (WSF) of petroleum and derivatives to aquatic biota are scarce. For this reason, deleterious effects of WSF of Brazilian petroleum, automotive diesel and unleaded gasoline to marine pejerrey Odontesthes argentinensis larvae were studied employing toxicity tests and histopathological examination. Each WSF was generated in a laboratory by mixing four parts of seawater with one part of pollutant by approximately 22 h. Larvae were exposed during 96 h to different concentrations of WSF of petroleum, diesel, and gasoline, plus a control. After 96 h of exposure to the different WSFs, three larvae were sampled for histopathological studies. The median lethal concentration after 96 h (LC50) of exposure for WSF of petroleum was equal to 70.68%, it was significantly higher (P < 0.05) than the values for WSF of diesel and gasoline, which were 13.46% and 5.48%, respectively. The histological examination of pejerrey larvae exposed to WSF of petroleum, diesel and gasoline after 96 h revealed a variety of lesions in the larvae. The gills, pseudobranchs and esophagus presented epithelial hyperplasia, and the liver presented dilatation of hepatic sinusoids, hepatocitomegaly, bi-nucleated and nuclear degeneration of hepatocytes, such as pyknotic nuclei. The acute toxicity of diesel and gasoline is at least fivefold higher than Brazilian petroleum. However, all toxicants induced histopathological abnormalities in pejerrey larvae. The results are of importance since much attention has been paid to large visible surfaces of petroleum spills instead of potential toxic effects of dissolved aromatic hydrocarbons, which are more available to marine biota.

Deleterious effects of water-soluble fraction of petroleum, diesel and gasoline on marine pejerrey Odontesthes argentinensis larvae

Energy Technology Data Exchange (ETDEWEB)

Rodrigues, Ricardo Vieira [Programa de Pos-Graduacao em Aquicultura, Universidade Federal do Rio Grande, Laboratorio de Piscicultura Estuarina e Marinha, CEP 96201-900, Rio Grande, RS (Brazil); Miranda-Filho, Kleber Campos, E-mail: kleber08@gmail.com [Instituto de Oceanografia, Universidade Federal do Rio Grande, Laboratorio de Piscicultura Estuarina e Marinha, CEP 96210-030, Rio Grande, RS (Brazil); Gusmao, Emeline Pereira; Moreira, Caue Bonucci [Programa de Pos-Graduacao em Aquicultura, Universidade Federal do Rio Grande, Laboratorio de Piscicultura Estuarina e Marinha, CEP 96201-900, Rio Grande, RS (Brazil); Romano, Luis Alberto; Sampaio, Luis Andre [Instituto de Oceanografia, Universidade Federal do Rio Grande, Laboratorio de Piscicultura Estuarina e Marinha, CEP 96210-030, Rio Grande, RS (Brazil)

2010-04-01

Accidental discharges and oil spills are frequent around the world. Petroleum-derived hydrocarbons are considered one of the main pollutants of aquatic ecosystem. The importance of petroleum and refined fuels is notorious because today's society depends on them. Researches related to the toxic water-soluble fraction (WSF) of petroleum and derivatives to aquatic biota are scarce. For this reason, deleterious effects of WSF of Brazilian petroleum, automotive diesel and unleaded gasoline to marine pejerrey Odontesthes argentinensis larvae were studied employing toxicity tests and histopathological examination. Each WSF was generated in a laboratory by mixing four parts of seawater with one part of pollutant by approximately 22 h. Larvae were exposed during 96 h to different concentrations of WSF of petroleum, diesel, and gasoline, plus a control. After 96 h of exposure to the different WSFs, three larvae were sampled for histopathological studies. The median lethal concentration after 96 h (LC50) of exposure for WSF of petroleum was equal to 70.68%, it was significantly higher (P < 0.05) than the values for WSF of diesel and gasoline, which were 13.46% and 5.48%, respectively. The histological examination of pejerrey larvae exposed to WSF of petroleum, diesel and gasoline after 96 h revealed a variety of lesions in the larvae. The gills, pseudobranchs and esophagus presented epithelial hyperplasia, and the liver presented dilatation of hepatic sinusoids, hepatocitomegaly, bi-nucleated and nuclear degeneration of hepatocytes, such as pyknotic nuclei. The acute toxicity of diesel and gasoline is at least fivefold higher than Brazilian petroleum. However, all toxicants induced histopathological abnormalities in pejerrey larvae. The results are of importance since much attention has been paid to large visible surfaces of petroleum spills instead of potential toxic effects of dissolved aromatic hydrocarbons, which are more available to marine biota.

Influence of solvent addition on the physicochemical properties of Brazilian gasoline

Energy Technology Data Exchange (ETDEWEB)

E.V. Takeshita; R.V.P. Rezende; S.M.A. Guelli; U. de Souza; A.A. Ulson de Souza [Federal University of Santa Catarina, Florianopolis (Brazil). Chemical Engineering Department

2008-08-15

The influence of several solvents (anhydrous ethanol, white spirit, alkylbenzene AB9, diesel) on the physicochemical parameters of gasoline was studied according to ASTM international standard methods. The parameters investigated (distillation curves, density, Reid vapor pressure) showed differentiated behavior, depending on the class of the solvent (oxygenated, light and heavy aliphatic, aromatic) and the quantity added to the gasoline. The azeotropic mixtures formed by ethanol and hydrocarbons showed a strong influence on the behavior of the distillation curves and the location of the point of a sudden change in temperature was shown to be a possible way to detect adulterations and determine the quantity of solvent added to the gasoline. 28 refs., 9 figs., 5 tabs.

Evaluation of the use of UCG gas to produce 4000 BPD and 12,000 BPD of methanol with conversion to M-gasoline

Energy Technology Data Exchange (ETDEWEB)

Carlisle, Donald

1981-01-01

This study involves an examination of the technical and economic feasibility of using raw gas from an underground coal gasification facility as feedstock for methanol synthesis, and producing M-gasoline from the methanol. It differs from previous studies in considering facilities smaller than those previously studied. Addressed also is the economic and technical feasibility of using equipment from existing ammonia plants for the production of methanol. Ammonia and methanol plants are very similar in type of equipment used and plant layout. Consequently, it is possible to convert an existing ammonia plant into a methanol facility. Existing ammonia and methanol plants which contain equipment that might be utilized with UCG all use natural gas for feedstock. The processing steps in these plants can be divided into unit operations which are described. The product price analysis shows that significant economies of scale exist for the larger of the two facility sizes considered in this study. The economies of scale are evident for both the methanol/M-gasoline and methanol-only facilities. Compared to current market prices, the calculated product prices for the 4000 BPD and 12,000 BPD methanol-only facilities are within the range of competitiveness with the prices of conventionally produced methanol. The product prices calculated for the 12,000 BPD methanol/4910 BPD M-gasoline facility are, under the most optimistic assumptions, 50% higher than the current market price for unleaded gasoline.

Study of ethanol and gasoline fuel sprays using mie-scatter and schlieren imaging

Science.gov (United States)

Bouchard, Lauren; Bittle, Joshua; Puzinauskas, Paul

2016-11-01

Many cars today are capable of running on both gasoline and ethanol, however it is not clear how well optimized the engines are for the multiple fuels. This experiment looks specifically at the fuel spray in a direct injection system. The length and angle of direct injection sprays were characterized and a comparison between ethanol and gasoline sprays was made. Fuels were tested using a modified diesel injector in a test chamber at variable ambient pressures and temperatures in order to simulate both high and low load combustion chamber conditions. Rainbow schlieren and mie-scatter imaging were both used to investigate the liquid and vapor portions of the sprays. The sprays behaved as expected with temperature and pressure changes. There was no noticeable fuel effect on the liquid portion of the spray (mie-scatter), though the gasoline vapor spray angles were wider than ethanol spray angles (possible a result of the distillation curves of the two fuels). Funding from NSF REU site Grant EEC 1358991 is greatly appreciated.

Comparative toxicity of tetra ethyl lead and lead oxide to earthworms, Eisenia fetida (Savigny)

International Nuclear Information System (INIS)

Venkateswara Rao, J.; Kavitha, P.; Padmanabha Rao, A.

2003-01-01

Leaded gasoline contains tetra ethyl lead (TEL) as an antiknocking agent, which produces major amounts of lead oxide in automobile exhaust along with traces of TEL. To minimize the lead contamination, methyl tertiary butyl ether (MTBE) is used as a substitute for producing unleaded gasoline. It has become increasingly apparent that young children are highly susceptible to the harmful effects of lead. Hence, a study was carried out to monitor lead toxicity in soil, using adult earthworms (Eisenia fetida, Savigny). Leaded gasoline (TEL) and lead oxide are 383- and 211-fold more toxic than unleaded gasoline (MTBE) in 7 days of exposure and 627- and 290-fold more toxic in 14 days, respectively. Results indicate that the presence of TEL in leaded gasoline and lead oxide has a significant effect on behavior, morphology, and histopathology of earthworms. Absorption of TEL into the tissues is comparatively less than that of lead oxide but toxic effects were severe. Rupture of the cuticle, extrusion of coelomic fluid and inflexible metameric segmentation were observed, causing desensitization of the posterior region leading to fragmentation in earthworms

Study of Gasohol as Alternative Fuel for Gasoline Substitution: Characteristics and Performances

Directory of Open Access Journals (Sweden)

Bardi Murachman

2014-12-01

Full Text Available Gasohol is a mixture of premium petrol (gasoline with alcohol, in this case ethanol. The use of gasohol can reduce fuel consumption without having to modify the existing engine. Therefore, this research is conducted to study the characteristics and performance of gasohol in various mixing ratios, which includes analysis of physical properties and the use of gasohol in the machine. Results show that the addition of technical ethanol at 7.0169%v increases the value of gasohol vapor pressure on the value of 8.6682 psi (7.7 psi for regular gasoline. Gasohol with technical ethanol content above 30%v decreases vapor pressure, promotes phase separation, and causes a sharp drop in temperature from 40%v distillation. In term of corrosivity, gasohol with up to 50%v ethanol content has the same corrosion level with regular gasoline, which is corrosion level 1A. Based on gasohol characteristics test, it is known that gasohol with technical ethanol content below 20%v can be used as a fuel substitute for gasoline. Real-time performance test of gasohol in engines has shown that the addition of ethanol content in gasohol tend to increase the engine power at a certain compression ratio, but it also increases fuel consumption because the heat value of ethanol is lower than gasoline. Machine in gasohol with ethanol content below 20%v can operate smoothly without having to modify the engine. Based on the studies that have been done, gasohol in the range of 10%v ethanol content is well-functioned as a substitute for gasoline fuel and meets fuel specifications required by the General Director of Oil and Gas. The feasibility of using gasohol as an alternative fuel can be studied further.

Desenvolvimento de um equipamento para avaliação do efeito do etanol na pressão de vapor e entalpia de vaporização em gasolinas automotivas

Directory of Open Access Journals (Sweden)

Cataluña Renato

2006-01-01

Full Text Available The quality of the gasoline utilized for fueling internal combustion engines with spark ignition is directly affected by the gasoline's properties. Thus, the fuel's properties must be in perfect equilibrium to allow the engine to perform optimally, not only insofar as fuel consumption is concerned, but also in order to reduce the emission of pollutants. Vapor pressure and vaporization enthalpy are important properties of a gasoline determining the fuel's behavior under different operating conditions in internal combustion engines. The study reported here involved the development of a device to determine the vapor pressure and the vaporization enthalpy of formulations containing volumes of 5, 15 and 25% of ethanol in four base gasolines (G1, G2, G3 and G4. The chemical composition of these gasolines was determined using a gas chromatographer equipped with a flame ionization detector (FID.

Investigation of fatalities due to acute gasoline poisoning.

Science.gov (United States)

Martínez, María A; Ballesteros, Salomé

2005-10-01

This paper presents a simple, rapid, reliable, and validated method suited for forensic examination of gasoline in biological samples. The proposed methodology has been applied to the investigation of four fatal cases due to gasoline poisoning that occurred in Spain in 2003 and 2004. Case histories and pathological and toxicological findings are described in order to illustrate the danger of gasoline exposure under several circumstances. Gasoline's tissular distribution, its quantitative toxicological significance, and the possible mechanisms leading to death are also discussed. The toxicological screening and quantitation of gasoline was performed by means of gas chromatography (GC) with flame-ionization detection, and confirmation was performed using GC-mass spectrometry in total ion chromatogram mode. m,p-Xylene peak was selected to estimate gasoline in all biological samples. Gasoline analytical methodology was validated at five concentration levels from 1 to 100 mg/L. The method provided extraction recoveries between 77.6% and 98.3%. The limit of detection was 0.3 mg/L, and the limit of quantitation was 1.0 mg/L. The linearity of the blood calibration curves was excellent with r2 values of > 0.997. Intraday and interday precisions had a coefficient of variation inhalation of gasoline vapor inside a small enclosed space. Case 3 is a death by recreational gasoline inhalation in a male adolescent. Heart blood concentrations were 28.4, 18.0, and 38.3 mg/L, respectively; liver concentrations were 41.4, 52.9, and 124.2 mg/kg, respectively; and lung concentrations were 5.6, 8.4, and 39.3 mg/kg, respectively. Case 4 was an accidental death due to gasoline ingestion of a woman with senile dementia. Peripheral blood concentration was 122.4 mg/L, the highest in our experience. Because pathological findings were consistent with other reports of gasoline intoxication and constituents of gasoline were found in the body, cause of death was attributed to acute gasoline

Early Liver and Kidney Dysfunction Associated with Occupational Exposure to Sub-Threshold Limit Value Levels of Benzene, Toluene, and Xylenes in Unleaded Petrol.

Science.gov (United States)

Neghab, Masoud; Hosseinzadeh, Kiamars; Hassanzadeh, Jafar

2015-12-01

Unleaded petrol contains significant amounts of monocyclic aromatic hydrocarbons such as benzene, toluene, and xylenes (BTX). Toxic responses following occupational exposure to unleaded petrol have been evaluated only in limited studies. The main purpose of this study was to ascertain whether (or not) exposure to unleaded petrol, under normal working conditions, is associated with any hepatotoxic or nephrotoxic response. This was a cross-sectional study in which 200 employees of Shiraz petrol stations with current exposure to unleaded petrol, as well as 200 unexposed employees, were investigated. Atmospheric concentrations of BTX were measured using standard methods. Additionally, urine and fasting blood samples were taken from individuals for urinalysis and routine biochemical tests of kidney and liver function. The geometric means of airborne concentrations of BTX were found to be 0.8 mg m(-3), 1.4 mg m(-3), and 2.8 mg m(-3), respectively. Additionally, means of direct bilirubin, alanine aminotransferase, aspartate aminotransferase, blood urea and plasma creatinine were significantly higher in exposed individuals than in unexposed employees. Conversely, serum albumin, total protein, and serum concentrations of calcium and sodium were significantly lower in petrol station workers than in their unexposed counterparts. The average exposure of petrol station workers to BTX did not exceed the current threshold limit values (TLVs) for these chemicals. However, evidence of subtle, subclinical and prepathologic early liver and kidney dysfunction was evident in exposed individuals.

Louisiana SIP: LAC 33:III Ch 2132. Stage II Vapor Recovery Systems for Control of Vehicle Refuelling Emissions at Gasoline Dispensing Facilities; SIP effective 2011-08-04 (LAd34) and 2016-02-29 (LAd47) to 2017-09-27

Science.gov (United States)

Louisiana SIP: LAC 33:III Ch 2132. Stage II Vapor Recovery Systems for Control of Vehicle Refuelling Emissions at Gasoline Dispensing Facilities; SIP effective 2011-08-04 (LAd34) and 2016-02-29 (LAd47) to 2017-09-27

Blood lead levels of traffic- and gasoline-exposed professionals in the city of Athens

International Nuclear Information System (INIS)

Kapaki, E.N.; Varelas, P.N.; Syrigou, A.I.; Spanaki, M.V.; Andreadou, E.; Kakami, A.E.; Papageorgiou, C.T.

1998-01-01

During the past 10 y, blood lead levels in the population of Athens, Greece, have decreased steadily. This decrease has paralleled the reduction of tetraethyl lead in gasoline and the introduction of unleaded fuel. Blood lead levels and other parameters were studied in 42 gas-station employees, 47 taxi drivers, 47 bus drivers, and 36 controls, all of whom worked in Athens. The blood lead levels did not differ significantly among the four groups. Glutamic-oxaloacetic transaminase and glutamic-pyruvic transaminase were elevated in gas-station employees, and the former was elevated in taxi drivers. Gas-station employees who smoked had higher blood lead levels than their nonsmoking counterparts. The absence of any difference in the blood lead levels of individuals for whom physical examinations were either normal or abnormal suggests that either lead was not the cause of increased blood lead levels or that its contribution may have been important in the past

Separation of aromatics by vapor permeation through solvent swollen membrane

Energy Technology Data Exchange (ETDEWEB)

Ito, A.; Adachi, K.; Feng, Y. [Niigata University, Niigata (Japan)

1995-12-20

A vapor permeation process for aromatics separation from a hydrocarbon mixture was studied by means of the simultaneous permeation of dimethylsulfoxide vapor as an agent for membrane swelling and preferential permeation of aromatics. The separation performance of the process was demonstrated by a polyvinylalcohol membrane for mixed vapors of benzene/cyclohexane, xylene/octane and a model gasoline. The aromatic vapors preferentially permeated from these mixed vapor feeds. The separation factor was over 10. The separation mechanism of the process mainly depends on the relative salability of the vapors between aromatics and other hydrocarbons in dimethylsulfoxide. 14 refs., 9 figs., 1 tab.

The usefulness of air quality monitoring and air quality impact studies before the introduction of reformulated gasolines in developing countries. Mexico City, a real case study

Energy Technology Data Exchange (ETDEWEB)

Bravo, H.A.; Torres, R.J. [Universidad Nacional Autonoma de Mexico (Mexico). Section de Contaminacion Ambiental

2000-07-01

Urban air pollution is a major environmental problem in several developing countries in the world. This phenomenon seems to be related to the growth of both the urban population in large cities and the number of old and poorly maintained car fleets. The expected rise of population in the next century in countries which suffer from lack of capital for air pollution control, means that there is a great potential for the worsening of the air quality. The worldwide promote policy to phase out lead in gasolines has not proved to be an adequate option in improving the environmental quality. Mexico City Metropolitan Area (MCMA) represents a case in which the introduction of reformulated gasolines in an old car fleet has resulted in the reduction of the airborne lead levels but has worsened the ozone concentration of its urban atmosphere. This paper critically analyzes the chronological evolution of the ozone air pollution problem in MCMA after the successive occurrence of several changes in the formulation of low leaded and unleaded gasolines. It also presents evidences of the usefulness potential of air quality monitoring activities and air quality impact studies on the definition of realistic fuel reformulation policies of developing countries. (author)

Reformulated gasoline: Costs and refinery impacts

International Nuclear Information System (INIS)

Hadder, G.R.

1994-02-01

Studies of reformulated gasoline (RFG) costs and refinery impacts have been performed with the Oak Ridge National Laboratory Refinery Yield Model (ORNL-RYM), a linear program which has been updated to blend gasolines to satisfy emissions constraints defined by preliminary complex emissions models. Policy makers may use the reformulation cost knee (the point at which costs start to rise sharply for incremental emissions control) to set emissions reduction targets, giving due consideration to the differences between model representations and actual refining operations. ORNL-RYM estimates that the reformulation cost knee for the US East Coast (PADD I) is about 15.2 cents per gallon with a 30 percent reduction of volatile organic compounds (VOCs). The estimated cost knee for the US Gulf Coast (PADD III) is about 5.5 cents per gallon with a VOC reduction of 35 percent. Reid vapor pressure (RVP) reduction is the dominant VOC reduction mechanism. Even with anti-dumping constraints, conventional gasoline appears to be an important sink which permits RFG to be blended with lower aromatics and sulfur contents in PADD III. In addition to the potentially large sensitivity of RFG production to different emissions models, RFG production is sensitive to the non-exhaust VOC share assumption for a particular VOC model. ORNL-RYM has also been used to estimate the sensitivity of RFG production to the cost of capital; to the RVP requirements for conventional gasoline; and to the percentage of RFG produced in a refining region

Effect of ethanol–gasoline blends on CO and HC emissions in last generation SI engines within the cold-start transient: An experimental investigation

International Nuclear Information System (INIS)

Iodice, Paolo; Senatore, Adolfo; Langella, Giuseppe; Amoresano, Amedeo

2016-01-01

Highlights: • This study assesses the effect of ethanol–gasoline blends on cold emissions. • A last generation motorcycle was operated on the chassis dynamometer. • A new calculation procedure was applied to model the cold transient behaviour. • The 20% v/v ethanol blend shows the highest reduction of CO and HC cold emissions. - Abstract: Urban areas in developed countries are characterized by an increasing decline in air quality state mainly due to the exhaust emissions from vehicles. Besides, due to catalyst improvements and electronic mixture control of last generation engines, nowadays CO and HC cold start extra-emissions are heavily higher than emissions exhausted in hot conditions, with a clear consequence on air quality of the urban contexts. Ethanol combined with gasoline can be widely used as an alternative fuel due to the benefit of its high octane number and its self-sustaining characteristics. Ethanol, in fact, is well known as potential alcohol alternative fuel for SI engines, since it can be blended with gasoline to increase oxygen content, then decreasing CO and HC emissions and the depletion of fossil fuels. Literature data about cold emissive behaviour of SI engines powered with ethanol/gasoline blended fuels are rather limited. For this reason, the aim of this study is to experimentally investigate the effect of ethanol/gasoline blends on CO and HC cold start emissions of four-stroke SI engines: a last generation motorcycle was operated on the chassis dynamometer for exhaust emission measurements without change to the engine design, while the ethanol was mixed with unleaded gasoline in different percentages (10, 20 and 30 vol.%). Results of the experimental tests and the application of a new calculation procedure, designed and optimised to model the cold transient behaviour of SI engines using different ethanol–gasoline blends, indicate that CO and HC cold start emissions decrease compared to the use of commercial gasoline, with the 20

Quantitative liquid and vapor distribution measurements in evaporating fuel sprays using laser-induced exciplex fluorescence

International Nuclear Information System (INIS)

Fansler, Todd D; Drake, Michael C; Gajdeczko, Boguslaw; Düwel, Isabell; Koban, Wieland; Zimmermann, Frank P; Schulz, Christof

2009-01-01

Fully quantitative two-dimensional measurements of liquid- and vapor-phase fuel distributions (mass per unit volume) from high-pressure direct-injection gasoline injectors are reported for conditions of both slow and rapid vaporization in a heated, high-pressure spray chamber. The measurements employ the coevaporative gasoline-like fluorobenzene (FB)/diethylmethylamine (DEMA)/hexane exciplex tracer/fuel system. In contrast to most previous laser-induced exciplex-fluorescence (LIEF) experiments, the quantitative results here include regions in which liquid and vapor fuel coexist (e.g. near the injector exit). A unique aspect is evaluation of both vapor- and liquid-phase distributions at varying temperature and pressure using only in situ vapor-phase fluorescence calibration measurements at room temperature and atmospheric pressure. This approach draws on recent extensive measurements of the temperature-dependent spectroscopic properties of the FB–DEMA exciplex system, in particular on knowledge of the quantum efficiencies of the vapor-phase and liquid-phase (exciplex) fluorescence. In addition to procedures necessary for quantitative measurements, we discuss corrections for liquid–vapor crosstalk (liquid fluorescence that overlaps the vapor-fluorescence bandpass), the unknown local temperature due to vaporization-induced cooling, and laser-sheet attenuation by scattering and absorption

40 CFR 63.11089 - What requirements must I meet for equipment leak inspections if my facility is a bulk gasoline...

Science.gov (United States)

2010-07-01

... equipment leak inspections if my facility is a bulk gasoline terminal, bulk plant, pipeline breakout station... gasoline service at the facility. (c) Each detection of a liquid or vapor leak shall be recorded in the log... shall be completed within 15 calendar days after detection of each leak, except as provided in paragraph...

Trace elements in particles of motor vehicle exhaust in Shanghai

International Nuclear Information System (INIS)

Jiang Da; Qiu Zhijun; Lu Rongrong; Qiu Huiyuan; Zhu Jieqing; Li Xiaolin

2002-01-01

A nuclear microprobe with high spatial resolution and high analytical sensitivity was applied to analyze trace elements, especially lead, in vehicle exhaust of Shanghai city. The result shows that the chemical composition and its corresponding x-ray relative intensity are different among different vehicle exhausts. There are many kinds of metal elements in particles of vehicle exhaust, most are harmful to people, such as Ti, Cr, Mn, Pb, etc. The authors found that the lead concentration was 6820 μg/g and the bromine concentration was 5300 μg/g in the exhaust from Santana using leaded gasoline (SULG), which is higher than any other kinds of vehicle exhausts. The authors have also detected the minimum lead in the particles of unleaded gasoline and its content varies from one to another. Its mean concentration was 450 μg/g and the highest reached 6210 μg/g. The unleaded gasoline's Pb existed in the whole particle while the leaded gasoline's enriched in the surface of the particle and was more harmful to the human beings

Neurophysiological Assessment of Auditory, Peripheral Nerve, Somatosensory, and Visual System Functions after Developmental Exposure to Ethanol Vapors

Science.gov (United States)

Ethanol-blended gasoline entered the market in response to demand for domestic renewable energy sources, and may result in increased inhalation of ethanol vapors in combination with other volatile gasoline constituents. It is important to understand potential risks of inhalation ...

Reduction of lead pollution from vehicular emissions in cairo Part 1: Comparison of alternative solutions

International Nuclear Information System (INIS)

El-Haggar, S.M.; Saleh, S.K.; El-Kady, M.A.

1996-01-01

It has been recognized for decades that the major source of lead pollution is lead additives to automotive fuels. This problem has been countered in most countries in europe and Usa by introducing alternative anti-knock chemicals and unleaded gasoline. In egypt lead is still being added to gasoline in large quantities. However, progress has been made, and unleaded gasoline is currently being produced in Alexandria. Nevertheless, the major pollution problem remains in the Greater Cairo region as indicated by the atmospheric lead levels and the lead blood levels of the children in Cairo. The aim of the present study is to find an optimum solution to this problem. A comparison of the different solutions is conducted in order to come up with the most feasible solution to this urgent problem. In conclusion it has been demonstrated that the elimination of lead additives, with its huge positives effects on the country environment, proved to be profitable. 4 figs., 2 tabs

26 CFR 48.4081-4 - Gasoline; special rules for gasoline blendstocks.

Science.gov (United States)

2010-04-01

... 26 Internal Revenue 16 2010-04-01 2010-04-01 true Gasoline; special rules for gasoline blendstocks..., Tread Rubber, and Taxable Fuel Taxable Fuel § 48.4081-4 Gasoline; special rules for gasoline blendstocks... gasoline blendstocks. Generally, under prescribed conditions, tax is not imposed on gasoline blendstocks...

Oxygenates in automotive fuels. Consequence analysis - preliminary study

International Nuclear Information System (INIS)

Brandberg, Aa.; Saevbark, B.

1994-01-01

Oxygenates is used in gasoline due to several reasons. They are added as high-octane components in unleaded gasoline and as agents to reduce the emission of harmful substances. Oxygenates produced from biomass might constitute a coming market for alternative fuels. This preliminary study describes the prerequisites and consequences of such an oxygenate utilization. 39 refs, 9 figs, 5 tabs

Inhalation of air polluted with gasoline vapours alters the levels of amino acid neurotransmitters in the cerebral cortex, hippocampus, and hypothalamus of the rat.

Science.gov (United States)

Kinawy, Amal A; Ezzat, Ahmed R; Al-Suwaigh, Badryah R

2014-08-01

This study was designed to investigate the impact of exposure to the vapours of two kinds of gasoline, a widely used fuel for the internal combustion engines on the levels of the amino acid neurotransmitters of the rat brain. Recent studies provide strong evidence for a causative role for traffic-related air pollution on morbidity outcomes as well as premature death (Health Effects Institute, 2009; Levy et al., 2010; von Stackelberg et al., 2013). Exposure to the vapours of gasoline or its constituents may be accidental, occupational by workers at fuel stations and factories, or through abuse as a mean of mood alteration (Fortenberry, 1985; Mc Garvey et al., 1999). Two kinds of gasoline that are common in Egypt have been used in this study. The first contains octane enhancers in the form of lead derivatives (leaded gasoline; G1) and the other contains methyl-tertiary butyl ether (MTBE) as the octane enhancer (unleaded gasoline; G2). The levels of the major excitatory (aspartic acid and glutamic acid) and the inhibitory (GABA and glycine) amino acid neurotransmitters were determined in the cerebral cortex, hippocampus, and hypothalamus. The current study revealed that the acute inhalation of air polluted with the two types of gasoline vapours (1/2 LC50 for 30 min) induced elevation in the levels of aspartic and glutamic acids along with a decrease in glycine and GABA in most studied brain areas. Chronic inhalation of both types of gasoline (a single daily 30-min session of 1/5 LC50 for 60 days) caused a significant increase in the aspartic and glutamic acid concentrations of the hippocampus without affecting the levels of GABA or glycine. Acute and chronic inhalation of either one of G1 and G2 vapours induced a disturbance and fluctuation in the levels of the free amino acids that act as excitatory and inhibitory neurotransmitters in the brain areas under investigation. These neurotransmitters are fundamental for the communicative functioning of the neurons and such

Delineation and hydrologic effects of a gasoline leak at Stovepipe Wells Hotel, Death Valley National Monument, California

Science.gov (United States)

Buono, A.; Packard, Elaine M.

1982-01-01

Ground water is the only local source of water available to the Stovepipe Wells Hotel facilities of the Death Valley National Monument, California. A leak in a service station storage tank caused the formation of a gasoline layer overlying the water table, creating the potential for contamination of the water supply. The maximum horizontal extent of the gasoline layer was mathematically estimated to be 1,300 feet downgradient from the leaky gasoline tank. Exploratory drilling detected the gasoline layer between 900 and 1,400 feet downgradient and between 50 and 150 feet upgradient from the source. Traces of the soluble components of gasoline were also found in the aquifer 150 feet upgradient, and 250 feet distant from the source perpendicular to the direction of ground-water movement. The gasoline spill is not likely to have an effect on the supply wells located 0.4 mile south of the leak source, which is nearly perpendicular to the direction of ground-water movement and the primary direction of gasoline movement in the area. No effect on phreatophytes 2 miles downgradient from the layer is likely, but the potential effects of gasoline vapors within the unsaturated zone on local xerophytes are not known. (USGS)

Analysis of Physicochemical Properties of Mexican Gasoline and Diesel Reformulated with Ethanol

Directory of Open Access Journals (Sweden)

Porfirio Caballero-Mata

2012-07-01

Full Text Available High energy prices, environmental issues and increasing importation of fossil fuels has provoked, in some countries, a reorientation of resources towards the development of biofuels that can partially substitute the consumption of fossil fuels. Ethanol is one of the biofuels more commonly used in the world; in the United States, Brazil and Australia gasoline blends that reach up to 85% Ethanol are commercialized. This work presents the results of a physicochemical characterization of commercial Mexican gasoline (Magna and Premium and diesel blends with 10% vol. and 15% vol. anhydrous Ethanol. The analytical testing included: Research Octane Number, Motor Octane Number, Cetane Number, Reid Vapor Pressure, Distillation Curve and Heating Value. The stability of the blends was also evaluated. The theoretical emissions of CO2 were calculated based on the results of the physicochemical characterization. The ethanol-gasoline blends increased their Octane Number with respect to the commercial gasoline, while conserving an appropriate Distillation Index. The Cetane Number of the ethanol-diesel blends showed a substantial decrease, while the heating value of gasoline and diesel blends was negatively affected by the addition of ethanol. Nevertheless, taking into account the credits by the use of a renewable fuel, the use of the reformulated gasoline blends would imply a maximum theoretical reduction of 7.5% in CO2 emissions whereas in the case of ethanol-diesel blends it would represent a 9.2% decrease.

DETERMINING HOW VAPOR PHASE MTBE REACHES GROUND WATER

Science.gov (United States)

EPA Region 2 and ORD have funded a RARE project for FY 2005/2006 to evaluate the prospects that MTBE (and other fuel components) in vapors that escape from an underground storage tank (UST) can find its way to ground water produced by monitoring wells at a gasoline filling statio...

Pemex to acquire interest in Shell Texas refinery

International Nuclear Information System (INIS)

Anon.

1992-01-01

This paper reports that Petroleos Mexicanos and Shell Oil Co. have signed a memorandum of understanding to form a joint refining venture involving Shell's 225,000 b/d Deer Park, Tex., refinery. Under the agreement, Mexico's state owned oil company is to purchase a 50% interest in the refinery, and Shell is to sell Pemex unleaded gasoline on a long term basis. Under the venture, Shell and Pemex plan to add undisclosed conversion and upgrading units tailored to process heavy Mexican crude. The revamp will allow Pemex to place more than 100,000 b/d of Mayan heavy crude on the U.S. market. Mayan accounts for 70% of Mexico's crude oil exports. In turn, Shell will sell Pemex as much as 45,000 b/d of unleaded gasoline to help meet Mexico's rapidly growing demand

PENINGKATAN KADAR GERANIOL DALAM MINYAK SEREH WANGI DAN APLIKASINYA SEBAGAI BIO ADDITIVE GASOLINE

Directory of Open Access Journals (Sweden)

Widi Astuti

2014-10-01

Full Text Available Sereh wangi merupakan salah satu tanaman penghasil minyak atsiri yang banyak mengandung geraniol. Geraniol merupakan senyawa penyedia oksigen sehingga minyak sereh wangi dimungkinkan dapat digunakan sebagai bio additive gasoline. Penelitian ini bertujuan  meningkatkan kadar geraniol dalam minyak sereh wangi dan menggunakannya sebagai bio additive gasoline.Penelitian dilakukan dalam  tiga tahap, yaitu  pemungutan minyak sereh wangi dari daun sereh wangi, peningkatan kadar geraniol dalam minyak sereh wangi dan aplikasi minyak sereh wangi yang mengandung geraniol tinggi sebagai bio aditive gasoline.Hasil penelitian menunjukkan bahwa pemungutan minyak sereh wangi yang dilakukan dengan metode distilasi uap menghasilkan rendemen sebesar 0,76% dengan kadar geraniol 5,36%.Kadar geraniol dapat ditingkatkan menjadi 21,78% melalui proses distilasi vakum pada suhu 120oC. Pengujian minyak sereh wangi dengan kadar geraniol tinggi sebagai bio additive gasoline meliputi uji performa dan efisiensi konsumsi bahan bakar dengan variasi perbandingan volume gasoline dengan bio additive. Hasilnya, penambahan minyak sereh wangi dengan perbandingan volume gasoline ; minyak sereh wangi = 1000:2 mampu meningkatkan power mesin dari 7,8HP menjadi 8,6HP. Sementara, pada pengujian efisiensi bahan bakar, penambahan minyak sereh wangi dengan perbandingan volume gasoline : minyak sereh wangi = 1000:2 dapat meningkatkan efisiensi mesin sebesar 10,8%. Citronella contains geraniol which is an oxygen provider substances, so it may be used as bio additive. The purpose of this research  is to increase geraniol content in citronella oil and use it as a gasoline bio additive. This research is conducted  in three steps including take the citronella oil from citronella leaf, increase geraniol content in citronella oil and use citronella oil as a gasoline bio additive. The result show that citronella oil produced from citronella leaf using vapor distillation method contains geraniol

Removal of gasoline volatile organic compounds via air biofiltration

International Nuclear Information System (INIS)

Miller, R.S.; Saberiyan, A.G.; Esler, C.T.; DeSantis, P.; Andrilenas, J.S.

1995-01-01

Volatile organic compounds (VOCs) generated by vapor extraction and air-stripping systems can be biologically treated in an air biofiltration unit. An air biofilter consists of one or more beds of packing material inoculated with heterotrophic microorganisms capable of degrading the organic contaminant of concern. Waste gases and oxygen are passed through the inoculated packing material, where the microorganisms will degrade the contaminant and release CO 2 + H 2 O. Based on data obtained from a treatability study, a full-scale unit was designed and constructed to be used for treating gasoline vapors generated by a vapor-extraction and groundwater-treatment system at a site in California. The unit is composed of two cylindrical reactors with a total packing volume of 3 m 3 . Both reactors are packed with sphagnum moss and inoculated with hydrocarbon-degrading microorganisms of Pseudomonas and Arthrobacter spp. The two reactors are connected in series for air-flow passage. Parallel lines are used for injection of water, nutrients, and buffer to each reactor. Data collected during the startup program have demonstrated an air biofiltration unit with high organic-vapor-removal efficiency

Characteristics of lead isotope ratios and elemental concentrations in PM 10 fraction of airborne particulate matter in Shanghai after the phase-out of leaded gasoline

Science.gov (United States)

Zheng, Jian; Tan, Mingguang; Shibata, Yasuyuki; Tanaka, Atsushi; Li, Yan; Zhang, Guilin; Zhang, Yuanmao; Shan, Zuci

The stable lead (Pb) isotope ratios and the concentrations of 23 elements, including heavy metals and toxic elements, were measured in the PM 10 airborne particle samples collected at seven monitoring sites in Shanghai, China, to evaluate the current elemental compositions and local airborne Pb isotope ratio characteristics. Some source-related samples, such as cement, coal and oil combustion dust, metallurgic dust, vehicle exhaust particles derived from leaded gasoline and unleaded gasoline, and polluted soils were analyzed for their Pb content and isotope ratio and compared to those observed in PM 10 samples. Airborne Pb concentration ranged from 167 to 854 ng/m 3 in the seven monitored sites with an average of 515 ng/m 3 in Shanghai, indicating that a high concentration of Pb remains in the air after the phasing out of leaded gasoline. Lead isotopic compositions in airborne particles ( 207Pb/ 206Pb, 0.8608±0.0018; 208Pb/ 206Pb, 2.105±0.005) are clearly distinct from the vehicle exhaust particles ( 207Pb/ 206Pb, 0.8854±0.0075; 208Pb/ 206Pb, 2.145±0.006), suggesting that the automotive lead is not currently the major component of Pb in the air. By using a binary mixing equation, a source apportionment based on 207Pb/ 206Pb ratios, indicates that the contribution from automotive emission to the airborne Pb is around 20%. The Pb isotope ratios obtained in the source-related samples confirmed that the major emission sources are metallurgic dust, coal combustion, and cement.

GTLine – Gasoline as a potential CN suppressant for GTL

KAUST Repository

Reijnders, Jos; Boot, Michael; Johansson, Bengt; de Goey, Philip

2018-01-01

The main driver to investigate low temperature combustion concepts, such as partially premixed combustion (PPC), is the promise of low particulate matter (PM) and nitric oxide (NOx) emissions. A critical prerequisite for PPC is to temporally isolate the fuel injection and combustion events. In practice, exhaust gas recirculation (EGR) is applied in order to sufficiently extend the ignition delay to that effect. Hereby, in general, higher EGR rates are necessary for fuels with higher cetane numbers (CN). Against this background, the objective of this paper is to investigate the efficacy, with respect to PM-NOx emissions and engine efficiency, of gasoline as a potential gas-to-liquid (GTL) CN suppressant in various dosages. The performance of the resulting GTLine blend will be evaluated under PPC operating conditions in a heavy-duty direct-injected diesel engine. Setting aside for a moment any potential practical issues (e.g., flash point, vapor pressure) that fall outside the scope of this study, our data suggest that blending gasoline to otherwise high CN GTL appears to be a promising route to improve not only the efficiency, but also PM and NOx emissions, particularly when operating in PPC mode. Interestingly, this benefit is notwithstanding the high aromaticity of the gasoline compared to GTL. Given the ongoing dieselization trend and associated surplus of gasoline in many regions, notably Europe, along with the fact that the cost price of gasoline is significantly lower than that of GTL, the proposed GTLine approach promises to be a cost effective way to accommodate GTL in a world wherein low temperature combustion concepts, such as PPC, appear to be really taking off.

GTLine – Gasoline as a potential CN suppressant for GTL

KAUST Repository

Reijnders, Jos

2018-03-23

The main driver to investigate low temperature combustion concepts, such as partially premixed combustion (PPC), is the promise of low particulate matter (PM) and nitric oxide (NOx) emissions. A critical prerequisite for PPC is to temporally isolate the fuel injection and combustion events. In practice, exhaust gas recirculation (EGR) is applied in order to sufficiently extend the ignition delay to that effect. Hereby, in general, higher EGR rates are necessary for fuels with higher cetane numbers (CN). Against this background, the objective of this paper is to investigate the efficacy, with respect to PM-NOx emissions and engine efficiency, of gasoline as a potential gas-to-liquid (GTL) CN suppressant in various dosages. The performance of the resulting GTLine blend will be evaluated under PPC operating conditions in a heavy-duty direct-injected diesel engine. Setting aside for a moment any potential practical issues (e.g., flash point, vapor pressure) that fall outside the scope of this study, our data suggest that blending gasoline to otherwise high CN GTL appears to be a promising route to improve not only the efficiency, but also PM and NOx emissions, particularly when operating in PPC mode. Interestingly, this benefit is notwithstanding the high aromaticity of the gasoline compared to GTL. Given the ongoing dieselization trend and associated surplus of gasoline in many regions, notably Europe, along with the fact that the cost price of gasoline is significantly lower than that of GTL, the proposed GTLine approach promises to be a cost effective way to accommodate GTL in a world wherein low temperature combustion concepts, such as PPC, appear to be really taking off.

Effects of seasonal and well construction variables on soil vapor extraction pilot tests

International Nuclear Information System (INIS)

Campbell, R.; Hudon, N.; Bass, D.

1995-01-01

The selection and design of an effective soil vapor extraction system is dependent upon data generated from pilot testing. Therefore, it is critical to understand factors that may affect the testing prior to selecting or designing a system. In Sebago Lake Village, Maine, two adjacent gasoline stations experienced a release. Gasoline migrated through fine sand into the groundwater and discharged to a small stream. Soil vapor extraction was investigated as a remedial alternative to reduce volatile organic compounds in the unsaturated soil. Three soil vapor extraction pilot tests were performed at one of the sites and one test at the other site. The results of the testing varied. Data collected during a summer test indicated soil vapor extraction was less likely to work. The wells tested were installed using an excavator. An adequate surface seal was not present in any of the tested wells. An additional test was performed in the winter using wells installed by a drill rig. Winter test results indicated that soil vapor extraction could be effective. Another test was performed after a horizontal soil vapor extraction system with a surface seal was installed. The results of this testing indicated that soil vapor extraction was more effective than predicted by the earlier tests. Tests performed on the other property indicated that the horizontal wells were more effective than the vertical wells. Testing results were affected by the well installation method, well construction, proximity to manmade structures, and the season in which testing was performed. Understanding factors that affect the testing is critical in selecting and designing the system

Modelling the Price of Unleaded Petrol in Australia’s Capital Cities

Directory of Open Access Journals (Sweden)

Abbas Valadkhani

2010-06-01

Full Text Available This paper examines the long-run and short-run determinants of unleaded petrol price in Australia’s capitalcities using monthly data to find out whether prices respond asymmetrically to external shocks. Based on thecointegration test results and the estimated asymmetric short-run dynamic models, it is found that: (1 in thelong-run petrol prices are mainly determined by Tapis crude oil and Singapore petrol prices; (2 there issome evidence of asymmetric price adjustments in the short-run since petrol price increases have been mostlypassed on to the consumer faster than price decreases in four capital cities. More specifically, this paperprovides convincing evidence in support of asymmetric price adjustments and the “rockets-and-feathershypothesis” in Adelaide, Brisbane, Melbourne and Sydney. One can thus argue that there are a significantdegree of market inefficiency and/or collusion, requiring a closer government price monitoring and scrutiny.

Novel extraction induced by microemulsion breaking: a model study for Hg extraction from Brazilian gasoline.

Science.gov (United States)

Vicentino, Priscila O; Cassella, Ricardo J

2017-01-01

This paper proposes a novel approach for the extraction of Hg from Brazilian gasoline samples: extraction induced by microemulsion breaking (EIMB). In this approach, a microemulsion is formed by mixing the sample with n-propanol and HCl. Afterwards, the microemulsion is destabilized by the addition of water and the two phases are separated: (i) the top phase, containing the residual gasoline and (ii) the bottom phase, containing the extracted analyte in a medium containing water, n-propanol and the ethanol originally present in the gasoline sample. The bottom phase is then collected and the Hg is measured by cold vapor atomic absorption spectrometry (CV-AAS). This model study used Brazilian gasoline samples spiked with Hg (organometallic compound) to optimize the process. Under the optimum extraction conditions, the microemulsion was prepared by mixing 8.7mL of sample with 1.2mL of n-propanol and 0.1mL of a 10molL -1 HCl solution. Emulsion breaking was induced by adding 300µL of deionized water and the bottom phase was collected for the measurement of Hg. Six samples of Brazilian gasoline were spiked with Hg in the organometallic form and recovery percentages in the range of 88-109% were observed. Copyright © 2016 Elsevier B.V. All rights reserved.

Gasoline poisoning

Science.gov (United States)

... this page: //medlineplus.gov/ency/article/002806.htm Gasoline poisoning To use the sharing features on this ... This article discusses the harmful effects from swallowing gasoline or breathing in its fumes. This article is ...

40 CFR 80.35 - Labeling of retail gasoline pumps; oxygenated gasoline.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Labeling of retail gasoline pumps; oxygenated gasoline. 80.35 Section 80.35 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Oxygenated Gasoline § 80.35 Labeling...

Prenatal Inhalation Exposure to Evaporative Condensates of Gasoline with 15% Ethanol and Evaluation of Sensory Function in Adult Rat Offspring

Science.gov (United States)

The introduction of ethanol-blended automotive fuels has raised concerns about potential health effects from inhalation exposure to the combination of ethanol and gasoline hydrocarbon vapors. Previously, we evaluated effects of prenatal inhalation exposure to 100% ethanol (E100) ...

Oxygenated gasolines according to European specifications for quality and ecological clean gasoline

International Nuclear Information System (INIS)

Panovska, Vesna; Tomanovikj, Violeta

1999-01-01

With the phasing out of lead additives from gasoline, the interest for oxygenates as a gasoline components grows up. However, since these materials are not hydrocarbons their behaviour in terms of blending differs from the gasoline which consists of hydrocarbons only. Therefore, it is important to explain their role in blending gasolines according to European specification for motor fuels. It is important to emphasize the oxygenate contribution in production more clean gasoline. In this paper, the oxygenate types and there basic specification features followed by manufacture, laboratory testing and blending specifications with refinery components is presented. (Author)

Methyl tert-butyl ether (MTBE) detected in abnormally high concentrations in postmortem blood and urine from two persons found dead inside a car containing a gasoline spill.

Science.gov (United States)

Karinen, Ritva; Vindenes, Vigdis; Morild, Inge; Johnsen, Lene; Le Nygaard, Ilah; Christophersen, Asbjørg S

2013-09-01

Two deep frozen persons, a female and a male, were found dead in a car. There had been an explosive fire inside the car which had extinguished itself. On the floor inside the car were large pools of liquid which smelled of gasoline. The autopsy findings and routine toxicological analyses could not explain the cause of death. Carboxyhemoglobin levels in the blood samples were gasoline as a fuel oxygenate. Gasoline poisoning is likely to be the cause of the death in these two cases, and MTBE can be a suitable marker of gasoline exposure, when other volatile components have vaporized. © 2013 American Academy of Forensic Sciences.

Fresh gasoline emissions, not paved road dust, alter cardiac repolarization in ApoE-/- mice.

Science.gov (United States)

Campen, Matthew J; McDonald, Jacob D; Reed, Matthew D; Seagrave, Jeanclare

2006-01-01

Fresh vehicular emissions potentially represent a ubiquitous environmental concern for cardiovascular health. We compared electrocardiographic effects of fresh gasoline engine emissions with resuspended paved road dust in a mouse model of coronary insufficiency. Apolipoprotein E (ApoE)-/- mice on a high fat diet were exposed by whole-body inhalation to either gasoline emissions at 60 microg/m3 particulate matter (PM), an equivalent atmosphere with particles filtered out of the whole exhaust, or paved road dust at 0.5 and 3.5 mg /m3 for 6 h/d for 3 d. Radiotelemetry recordings of electrocardiogram (ECG) were analyzed for changes in T-wave morphology (QT interval, T-wave amplitude, and T-wave Area). Following exposures, lung lavage and blood samples were obtained to assay for markers of pulmonary and systemic inflammation. No exposure induced significant changes in heart rate and only the high concentration of road dust induced signs of pulmonary inflammation. T-wave area exhibited significant deviation from baseline values during exposure to gasoline exhaust particulates, but not to either concentration of road dust or gasoline emissions sans particulates. Gasoline-exposed mice demonstrated elevated plasma endothelin-1, but did not cause systemic inflammation. These data support the hypothesis that freshly-generated engine emissions, as opposed to resuspended paved road dust, may drive cardiac effects that have been observed at road-sides in the environment. The absence of ECG effects for both very high concentrations of road dust PM and equivalent concentrations of the vapor/gas phase of gasoline engine exhaust further indicate the specific risk conferred by fresh vehicular PM.

Evaporation of petroleum products from contaminated soils

International Nuclear Information System (INIS)

Kang, S.H.

1996-01-01

Bioremediation can remove petroleum products from soil that has been contaminated by leaking underground storage tanks, but abiotic processes such as evaporation can contribute significantly to the overall removal process. The mathematical model described in this paper was developed to predict the evaporation rate of volatile liquids from petroleum-contaminated sand. The model is based on simple concepts relating to molecular diffusion embodied in the theory underlying the estimation of binary diffusivities using measurements made with an Arnold diffusion cell. The model in its simplified form indicates that the rate of evaporation for a particular volatile liquid is proportional to the square root of the product of diffusivity and partial pressure divided by the molecular weight of the liquid. This in part explains why evaporative losses from sand are so much higher for gasoline than for diesel fuel. The model also shows that the time for evaporation is directly proportional to the square of the depth dried out and inversely proportional to the vapor pressure of the volatile liquid. The model was tested using gravimetric measurements of the evaporation of n-heptane, unleaded gasoline, and diesel fuel from sand under laboratory conditions

Optimization of the fluid catalytic cracking unit performance by application of a high motor Octane catalyst and reduction of gasoline vapour pressure

International Nuclear Information System (INIS)

Chavdarov, I.; Stratiev, D.; Shishkova, I.; Dinkov, R.; Petkov, P.

2013-01-01

Full text: The fluid catalytic cracking (FCC) gasoline is the main contributor to the refinery gasoline pool in the LUKOIL Neftohim Burgas (LNB) refinery. Next in quantity contributor in the refinery gasoline pool is the reformate. The FCC gasoline sensitivity (MON-RON) is about 12 points. The reformer gasoline sensitivity is 11 points. The high sensitivity of the main contributors to the LNB refinery gasoline pool leads to a shortage in the motor octane number. For that reason a selection of an FCC catalyst that is capable of increasing the motor octane number of the FCC gasoline was performed. The application of this catalyst in the LNB FCC unit has led to an increase of the motor octane number of the FCC gasoline by 0.5 points, which enabled the refinery to increase the production of automotive gasolines by 1.3 % and to increase the share of premium automotive gasoline by 5 %. This had an effect of improvement of the refinery economics by a six figure number of US $ per year. The optimization of the FCC gasoline Reid Vapor Pressure (RVP) during the winter season, consisting in a reduction of the RVP from 60 to 50 kPa and an increase of the FCC C 4 olefins yield, has led to an augmentation of high motor octane number alkylate production. As a result the refinery economics was improved by a five figure number of US $ per year. key words: FCC gasoline motor octane number, gasoline RVP, FCC operation profitability

An evidence-based analysis of epidemiologic associations between lymphatic and hematopoietic cancers and occupational exposure to gasoline.

Science.gov (United States)

Keenan, J J; Gaffney, S; Gross, S A; Ronk, C J; Paustenbach, D J; Galbraith, D; Kerger, B D

2013-10-01

The presence of benzene in motor gasoline has been a health concern for potential increased risk of acute myelogenous leukemia and perhaps other lymphatic/hematopoietic cancers for approximately 40 years. Because of the widespread and increasing use of gasoline by consumers and the high exposure potential of occupational cohorts, a thorough understanding of this issue is important. The current study utilizes an evidence-based approach to examine whether or not the available epidemiologic studies demonstrate a strong and consistent association between occupational exposure to gasoline and lymphatic/hematopoietic cancers. Among 67 epidemiologic studies initially identified, 54 were ranked according to specific criteria relating to the relevance and robustness of each study for answering the research question. The 30 highest-ranked studies were sorted into three tiers of evidence and were analyzed for strength, specificity, consistency, temporality, dose-response trends and coherence. Meta statistics were also calculated for each general and specific lymphatic/hematopoietic cancer category with adequate data. The evidence-based analysis did not confirm any strong and consistent association between occupational exposure to gasoline and lymphatic/hematopoietic cancers based on the epidemiologic studies available to date. These epidemiologic findings, combined with the evidence showing relatively low occupational benzene vapor exposures associated with gasoline formulations during the last three decades, suggest that current motor gasoline formulations are not associated with increased lymphatic/hematopoietic cancer risks related to benzene.

Volatilization of gasoline from soil

International Nuclear Information System (INIS)

Arthus, P.

1993-05-01

Gasoline contaminated soil threatens water resources and air quality. The extent of the threat depends on gasoline behavior in soil, which is affected by various mechanisms such as volatilization. To quantify volatilization, gasoline spills were simulated in the laboratory using a synthetic gasoline and three dry soils. Total gasoline and individual gasoline compound concentrations in soil were monitored as a function of depth and time. The time to reduce overall gasoline concentration in coarse sand, sandy loam, and silt loam to 40% of initial concentration, averaged between surface and a 200-mm depth, ranged from 0.25 d to 10 d. A wicking phenomenon which contributed to gasoline flux toward the atmosphere was indicated by behavior of a low-volatility gasoline compound. Based on separate wicking experiments, this bulk immiscible movement was estimated at an upward velocity of 0.09 m/d for Delhi sandy loam and 0.05 m/d for Elora silt loam. 70 refs., 24 figs., 34 tabs

A Research on The Exhaust Emission of The Gasoline Engines in Tekirdag

OpenAIRE

M.R. Durgut; S. Arin; E.Kilic

2006-01-01

The exhaust gases as a result of combustion in internal combustion engines, sump ventilatory systemand vaporization of fuel system are the pollution sources caused by the vehicles. Preventing the pollution inits source is the main method for controlling the pollution: In this study, the exhaust emissions of 1844vehicles with gasoline were examined randomly applied to measuring station. The measured CO, CO2 HC,O2 values were discussed in their suitability to the limits determined by Turkish St...

Gasoline from Wood via Integrated Gasification, Synthesis, and Methanol-to-Gasoline Technologies

Energy Technology Data Exchange (ETDEWEB)

Phillips, S. D.; Tarud, J. K.; Biddy, M. J.; Dutta, A.

2011-01-01

This report documents the National Renewable Energy Laboratory's (NREL's) assessment of the feasibility of making gasoline via the methanol-to-gasoline route using syngas from a 2,000 dry metric tonne/day (2,205 U.S. ton/day) biomass-fed facility. A new technoeconomic model was developed in Aspen Plus for this study, based on the model developed for NREL's thermochemical ethanol design report (Phillips et al. 2007). The necessary process changes were incorporated into a biomass-to-gasoline model using a methanol synthesis operation followed by conversion, upgrading, and finishing to gasoline. Using a methodology similar to that used in previous NREL design reports and a feedstock cost of $50.70/dry ton ($55.89/dry metric tonne), the estimated plant gate price is $16.60/MMBtu ($15.73/GJ) (U.S. $2007) for gasoline and liquefied petroleum gas (LPG) produced from biomass via gasification of wood, methanol synthesis, and the methanol-to-gasoline process. The corresponding unit prices for gasoline and LPG are $1.95/gallon ($0.52/liter) and $1.53/gallon ($0.40/liter) with yields of 55.1 and 9.3 gallons per U.S. ton of dry biomass (229.9 and 38.8 liters per metric tonne of dry biomass), respectively.

Dietary and inhalation intake of lead and estimation of blood lead levels in adults and children in Kanpur, India.

Science.gov (United States)

Sharma, Mukesh; Maheshwari, Mayank; Morisawa, S

2005-12-01

This research was initiated to study lead levels in various food items in the city of Kanpur, India, to assess the dietary intake of lead and to estimate blood lead (PbB) levels, a biomarker of lead toxicity. For this purpose, sampling of food products, laboratory analysis, and computational exercises were undertaken. Specifically, six food groups (leafy vegetables, nonleafy vegetables, fruits, pulses, cereals, and milk), drinking water, and lead air concentration were considered for estimating lead intake. Results indicated highest lead content in leafy vegetables followed by pulses. Fruits showed low lead content and drinking water lead levels were always within tolerable limits. It was estimated that average daily lead intake through diet was about 114 microg/day for adults and 50 microg/day in children; tolerable limit is 250 microg/day for adults and 90 microg/day for children. The estimated lead intakes were translated into the resultant PbB concentrations for children and adults using a physiologically-based pharmacokinetic (PBPK) model. Monte Carlo simulation of PbB level variations for adults showed that probability of exceeding the tolerable limit of PbB (i.e.,10 microg/dL) was 0.062 for the pre-unleaded and 0.000328 for the post-unleaded gasoline period. The probability of exceeding tolerable limits in PbB level was reduced by a factor of 189 in the post-unleaded scenario. The study also suggested that in spite of the introduction of unleaded gasoline, children continue to be at a high risk (probability of exceeding 10 microg/dL = 0.39) because of a high intake of lead per unit body weight.

Gasoline prices, gasoline consumption, and new-vehicle fuel economy: Evidence for a large sample of countries

International Nuclear Information System (INIS)

Burke, Paul J.; Nishitateno, Shuhei

2013-01-01

Countries differ considerably in terms of the price drivers pay for gasoline. This paper uses data for 132 countries for the period 1995–2008 to investigate the implications of these differences for the consumption of gasoline for road transport. To address the potential for simultaneity bias, we use both a country's oil reserves and the international crude oil price as instruments for a country's average gasoline pump price. We obtain estimates of the long-run price elasticity of gasoline demand of between − 0.2 and − 0.5. Using newly available data for a sub-sample of 43 countries, we also find that higher gasoline prices induce consumers to substitute to vehicles that are more fuel-efficient, with an estimated elasticity of + 0.2. Despite the small size of our elasticity estimates, there is considerable scope for low-price countries to achieve gasoline savings and vehicle fuel economy improvements via reducing gasoline subsidies and/or increasing gasoline taxes. - Highlights: ► We estimate the determinants of gasoline demand and new-vehicle fuel economy. ► Estimates are for a large sample of countries for the period 1995–2008. ► We instrument for gasoline prices using oil reserves and the world crude oil price. ► Gasoline demand and fuel economy are inelastic with respect to the gasoline price. ► Large energy efficiency gains are possible via higher gasoline prices

A review of centrifugal testing of gasoline contamination and remediation.

Science.gov (United States)

Meegoda, Jay N; Hu, Liming

2011-08-01

Leaking underground storage tanks (USTs) containing gasoline represent a significant public health hazard. Virtually undetectable to the UST owner, gasoline leaks can contaminate groundwater supplies. In order to develop remediation plans one must know the extent of gasoline contamination. Centrifugal simulations showed that in silty and sandy soils gasoline moved due to the physical process of advection and was retained as a pool of free products above the water table. However, in clayey soils there was a limited leak with lateral spreading and without pooling of free products above the water table. Amount leaked depends on both the type of soil underneath the USTs and the amount of corrosion. The soil vapor extraction (SVE) technology seems to be an effective method to remove contaminants from above the water table in contaminated sites. In-situ air sparging (IAS) is a groundwater remediation technology for contamination below the water table, which involves the injection of air under pressure into a well installed into the saturated zone. However, current state of the art is not adequate to develop a design guide for site implementation. New information is being currently generated by both centrifugal tests as well as theoretical models to develop a design guide for IAS. The petroleum contaminated soils excavated from leaking UST sites can be used for construction of highway pavements, specifically as sub-base material or blended and used as hot or cold mix asphalt concrete. Cost analysis shows that 5% petroleum contaminated soils is included in hot or cold mix asphalt concrete can save US$5.00 production cost per ton of asphalt produced.

A Review of Centrifugal Testing of Gasoline Contamination and Remediation

Directory of Open Access Journals (Sweden)

Jay N. Meegoda

2011-08-01

Full Text Available Leaking underground storage tanks (USTs containing gasoline represent a significant public health hazard. Virtually undetectable to the UST owner, gasoline leaks can contaminate groundwater supplies. In order to develop remediation plans one must know the extent of gasoline contamination. Centrifugal simulations showed that in silty and sandy soils gasoline moved due to the physical process of advection and was retained as a pool of free products above the water table. However, in clayey soils there was a limited leak with lateral spreading and without pooling of free products above the water table. Amount leaked depends on both the type of soil underneath the USTs and the amount of corrosion. The soil vapor extraction (SVE technology seems to be an effective method to remove contaminants from above the water table in contaminated sites. In-situ air sparging (IAS is a groundwater remediation technology for contamination below the water table, which involves the injection of air under pressure into a well installed into the saturated zone. However, current state of the art is not adequate to develop a design guide for site implementation. New information is being currently generated by both centrifugal tests as well as theoretical models to develop a design guide for IAS. The petroleum contaminated soils excavated from leaking UST sites can be used for construction of highway pavements, specifically as sub-base material or blended and used as hot or cold mix asphalt concrete. Cost analysis shows that 5% petroleum contaminated soils is included in hot or cold mix asphalt concrete can save US$5.00 production cost per ton of asphalt produced.

Involvement of reversible binding to alpha 2u-globulin in 1,4-dichlorobenzene-induced nephrotoxicity.

Science.gov (United States)

Charbonneau, M; Strasser, J; Lock, E A; Turner, M J; Swenberg, J A

1989-06-01

Similarly to unleaded gasoline, 1,4-dichlorobenzene (1,4-DCB) administered for 2 years caused a dose-related increase in the incidence of renal tumors in male but not in female rats or in either sex of mice. Unleaded gasoline and 2,2,4-trimethylpentane (TMP), a component of unleaded gasoline, increased protein droplet formation and cell proliferation in male but not in female rat kidneys. These protein droplets contained, alpha 2u-globulin, a male rat-specific low-molecular-weight protein and 2,4,4-trimethyl-2-pentanol, a metabolite of TMP that was reversibly bound to this protein. Studies were undertaken to determine if 1,4-DCB produced similar effects; 1,2-DCB was used for comparison since it did not produce renal carcinogenesis in male rats. Gel filtration chromatography of a 116,000g supernatant prepared from kidneys of 1,4-[14C]DCB-treated rats showed that radiolabel coeluted with alpha 2u-globulin as one sharp peak as opposed to a multipeak pattern observed for 1,2-[14C]DCB; the maximal quantity of radiolabel for 1,4-DCB was twice that for 1,2-DCB. Equilibrium dialysis of kidney cytosol in the presence or absence of sodium dodecyl sulfate demonstrated that the radiolabel was reversibly bound to alpha 2u-globulin; the amount for 1,4-[14C]DCB-treated rats was almost twice as much as that for 1,2-[14C]DCB-treated rats. 1,2-DCB was also shown to be covalently bound to renal alpha 2u-globulin, and covalently bound to liver and plasma high-molecular-weight proteins. 1,4-DCB and, to a minor extent, 2,5-dichlorophenol, the major metabolite of 1,4-DCB, were reversibly bound to renal alpha 2u-globulin from 1,4-DCB-treated rats. 1,4-DCB increased protein droplet formation in male but not in female rat kidneys, whereas equimolar doses of 1,2-DCB showed no effect in either sex. Renal cell proliferation, measured by [3H]thymidine incorporation into renal DNA, was increased after 1,4-DCB but not after 1,2-DCB treatment. Nephrotoxicity and biochemical alterations induced by

Purification Simulation With Vapor Permeation and Distillation-Adsorption In Bioethanol Plant

Directory of Open Access Journals (Sweden)

Misri Gozan

2017-04-01

Full Text Available High purity of Bioethanol is required in biofuel mixing with gasoline (EXX. In bioethanol production line, the azeotropic property of ethanol-water becomes the barrier for purification process. This study examined two bioethanol separation processes by support of simulation tools, Superpro Designer 9.0 software. Ethanol purity and a low costeconomical process were the major considerations. Purification method of vapor permeation membrane technology was compared with distillation-adsorption method. Data from previous lab experiments and some literatures were used. The results showed that distillation-adsorption method is more economical compared to vapor permeation technology. Payback period of the simulation is 3.9 years and 4.3 years to distillation adsorption and vapor permeation respectively with each IRR value is 20.23% and 17.89%. Initial investment value of vapor permeation is 9.6% higher than distillation method. Significant difference observed in operating costs, since more units involved in vapor permeation require more labors to operate.

Experimental investigation on SI engine using gasoline and a hybrid iso-butanol/gasoline fuel

International Nuclear Information System (INIS)

Elfasakhany, Ashraf

2015-01-01

Highlights: • iso-Butanol–gasoline blends (iB) using up to 10 vol.% butanol were examined in SIE. • iB extensively decrease the greenhouse effect of SI engine. • iB without engine tuning led to a drop in engine performance at all speeds. • iB provide higher performance and lower CO and CO 2 emissions than n-butanol blends. • iB grant lower CO and UHC than gasoline at <2900 r/min, but overturn at >2900 r/min. - Abstract: Experimental investigation on pollutant emissions and performance of SI engine fueled with gasoline and iso-butanol–gasoline blends is carried out. Engine was operated at speed range of 2600–3400 r/min for each blend (3, 7 and 10 vol.% iso-butanol) and neat gasoline. Results declare that the CO and UHC emissions of neat gasoline are higher than those of the blended fuels for speeds less than or equal to 2900 r/min; however, for speeds higher than 2900 r/min, we have an opposite impact where the blended fuels produce higher level of CO and UHC emissions than the gasoline fuel. The CO 2 emission at using iso-butanol–gasoline blends is always lower than the neat gasoline at all speeds by up to 43%. The engine performance results demonstrate that using iso-butanol–gasoline blends in SI engine without any engine tuning lead to a drop in engine performance within all speed range. Without modifying the engine system, overall fuel combustion of iso-butanol–gasoline blends was quasi-complete. However, when engine system is optimized for blended fuels, iso-butanol has significant oxygen content and that can lead to a leaner combustion, which improves the completeness of combustion and therefore high performance and less emissions would be obtained. Finally, the performance and emissions of iso-butanol–gasoline blends are compared with those of n-butanol–gasoline blends at similar blended rates and engine working conditions. Such comparison is directed to evaluate the combustion dissimilarity of the two butanol isomers and also to

Production of aviation gasoline

Energy Technology Data Exchange (ETDEWEB)

1938-05-25

A process is described for preparing gasoline possessing properties for use as a fuel, particularly for aviation motors, beginning with gasolines composed among others of cyclic hydrocarbons, especially aromatics, consisting in treating the gasoline by means of selective solvents of aromatic hydrocarbons, especially aromatics, and preferably at the same time employing liquid hydrocarbons which are gaseous under normal conditions and adding to the refined product nonaromatics which boil in the range of the gasoline and have an actane number above 95 or which give the mixture an octane number of 82.5.

Remedial design for petroleum hydrocarbons: Soil vapor extraction, product skimmers, and air stripping

International Nuclear Information System (INIS)

Anastasi, F.S.; Loftin, H.J.

1994-01-01

Site characterization activities at an Army installation in Virginia performed prior to closure identified a significant release of gasoline from underground storage tanks and piping associated with the post exchange service station. Floating liquid-phase petroleum hydrocarbons (FLPH) observed in the subsurface over an area of approximately 80,000 square feet ranged up to 5 feet in thickness. Ground water was found to be contaminated with dissolved components of gasoline over an area of approximately 150,000 square feet. A nearby lake and adjacent streams were not impacted by either free-phase or dissolved contamination. Interim remedial measures, including pilot testing of FLPH, vapor-phase, and ground water recovery technologies, were implemented following discovery of the release. Over 5,000 gallons of free-phase product were recovered by skimming and approximately 1,450 gallons of product equivalent were recovered during pilot testing of a soil vapor extraction (SVE) system. At the conclusion of these actions, hydrocarbons remain distributed in the subsurface in the adsorbed-, dissolved-, and vapor-phase. The majority of residual on-site contamination is believed to be either adsorbed to soil particles or as FLPH. The final design of an integrated remediation system based on the pilot test results addressed these conditions

Standby Gasoline Rationing Plan

Energy Technology Data Exchange (ETDEWEB)

None

1980-06-01

The final rules adopted by the President for a Standby Gasoline Rationing Plan are presented. The plan provides that eligibility for ration allotments will be determined primarily on the basis of motor vehicle registrations, taking into account historical differences in the use of gasoline among states. The regulations also provide authority for supplemental allotments to firms so that their allotment will equal a specified percentage of gasoline use during a base period. Priority classifications, i.e., agriculture, defense, etc., are established to assure adequate gasoline supplies for designated essential services. Ration rights must be provided by end-users to their suppliers for each gallon sold. DOE will regulate the distribution of gasoline at the wholesale level according to the transfer by suppliers of redeemed ration rights and the gasoline allocation regulations. Ration rights are transferable. A ration banking system is created to facilitate transfers of ration rights. Each state will be provided with a reserve of ration rights to provide for hardship needs and to alleviate inequities. (DC)

Ignition delay times of Gasoline Distillation Cuts measured with Ignition Quality Tester

KAUST Repository

Naser, Nimal

2017-04-21

Tailoring fuel properties to maximize the efficiency of internal combustion engines is a way towards achieving cleaner combustion systems. In this work, the ignition properties of various gasoline fuel distillation cuts are analyzed to better understand fuel properties of the full boiling range fuel. An advanced distillation column (ADC) provides a more realistic representation of volatility characteristics, which can be modeled using equilibrium thermodynamic methods. The temperature reported is that of the liquid, as opposed to the vapor temperature in conventional ASTM D86 distillation standard. Various FACE (fuels for advanced combustion engines) gasolines were distilled and various cuts were obtained. The separated fractions were then tested in an ignition quality tester (IQT) to see the effect of chemical composition of different fractions on their ignition delay time. Fuels with lower aromatic content showed decreasing ignition delay time with increasing boiling point (i.e., molecular weight). However, fuels with higher aromatic content showed an initial decrease in ignition delay time with increasing boiling point, followed by drastic increase in ignition delay time due to fractions containing aromatics. This study also provides an understanding on contribution of different fractions to the ignition delay time of the fuel, which provides insights into fuel stratification utilized in gasoline compression ignition (GCI) engines to tailor heat release rates.

Study of gasoline mixture with 10% of anhydrous ethanol. Physic-chemical properties evaluation

International Nuclear Information System (INIS)

Torres, Jaime; Molina, Daniel; Pinto, Carlos; Rueda, Fernando

2002-01-01

This study includes the assessment results for blends of premium and regular gasoline produced in Barrancabermeja' s refinery with 10vol% anhydrous ethanol and concentrations within this range (from 5vol% to 15vol%). The results may allow for a more precise definition of the characteristics for the desired blend. The survey basically focused on the Reid vapor pressure (RVP) and the antiknock index (RON+MON/2) properties, in order to determine the variations within these properties when 5vol%, 10vol%, and 15vol% anhydrous ethanol is added to the base fuels. Based on these results, the RVP and antiknock index were determined for the base fuels, blended with 10vol% ethanol, to comply with the quality standards required for Colombian fuels in year 2005. For the adjustment of the base fuel's RVP, light-vapors, nitrogen-dragging stripper was designed and built. As for the adjustment of the base fuel's antiknock index, blends with straight naphtha were made for lower index values, while blends with cracked naphtha and high octane alkylate were made for higher index values. Having determined the specifications for base fuels, as required to blend them with 10vol% ethanol and meet the quality standards for Colombian gasoline in year 2005, water tolerance for the blends was estimated at temperature ranges of 273 k to 313 k

Price changes in the gasoline market: Are Midwestern gasoline prices downward sticky?

International Nuclear Information System (INIS)

1999-03-01

This report examines a recurring question about gasoline markets: why, especially in times of high price volatility, do retail gasoline prices seem to rise quickly but fall back more slowly? Do gasoline prices actually rise faster than they fall, or does this just appear to be the case because people tend to pay more attention to prices when they're rising? This question is more complex than it might appear to be initially, and it has been addressed by numerous analysts in government, academia and industry. The question is very important, because perceived problems with retail gasoline pricing have been used in arguments for government regulation of prices. The phenomenon of prices at different market levels tending to move differently relative to each other depending on direction is known as price asymmetry. This report summarizes the previous work on gasoline price asymmetry and provides a method for testing for asymmetry in a wide variety of situations. The major finding of this paper is that there is some amount of asymmetry and pattern asymmetry, especially at the retail level, in the Midwestern states that are the focus of the analysis. Nevertheless, both the amount asymmetry and pattern asymmetry are relatively small. In addition, much of the pattern asymmetry detected in this and previous studies could be a statistical artifact caused by the time lags between price changes at different points in the gasoline distribution system. In other words, retail gasoline prices do sometimes rise faster than they fall, but this is largely a lagged market response to an upward shock in the underlying wholesale gasoline or crude oil prices, followed by a return toward the previous baseline. After consistent time lags are factored out, most apparent asymmetry disappears

Autoignition characteristics of oxygenated gasolines

KAUST Repository

Lee, Changyoul

2017-08-14

Gasoline anti-knock quality, defined by the research and motor octane numbers (RON and MON), is important for increasing spark ignition (SI) engine efficiency. Gasoline knock resistance can be increased using a number of blending components. For over two decades, ethanol has become a popular anti-knock blending agent with gasoline fuels due to its production from bio-derived resources. This work explores the oxidation behavior of two oxygenated certification gasoline fuels and the variation of fuel reactivity with molecular composition. Ignition delay times of Haltermann (RON = 91) and Coryton (RON = 97.5) gasolines have been measured in a high-pressure shock tube and in a rapid compression machine at three pressures of 10, 20 and 40 bar, at equivalence ratios of φ = 0.45, 0.9 and 1.8, and in the temperature range of 650–1250 K. The results indicate that the effects of fuel octane number and fuel composition on ignition characteristics are strongest in the intermediate temperature (negative temperature coefficient) region. To simulate the reactivity of these gasolines, three kinds of surrogates, consisting of three, four and eight components, are proposed and compared with the gasoline ignition delay times. It is shown that more complex surrogate mixtures are needed to emulate the reactivity of gasoline with higher octane sensitivity (S = RON–MON). Detailed kinetic analyses are performed to illustrate the dependence of gasoline ignition delay times on fuel composition and, in particular, on ethanol content.

Air pollution and motor vehicles

International Nuclear Information System (INIS)

Bruzzi, L.

1992-01-01

An analysis is made of the effects of fuel chemical composition and fuel-air mixture on the composition of combustion exhaust gases produced by automotive spark ignition and diesel engines. This analysis considers several aspects: the merits of unleaded gasolines, Italian legal limits on the concentration of aromatic hydrocarbons in gasoline, limits on the sulfur content of diesel fuels, and proposed European Communities limits on automobile air pollution. The paper concludes with an assessment of the cost effective performance of different types of catalytic converters now available on the market

76 FR 61062 - Approval and Promulgation of Implementation Plans; Arizona; Update to Stage II Gasoline Vapor...

Science.gov (United States)

2011-10-03

... the second is the fueling for race cars during the racing event. According to the information provided... facility's fixed gasoline dispensers, which are used to fuel service vehicles, are not used for race car... raceway exemption as it applies to refueling of race cars, which are not designed for street or highway...

40 CFR 1065.710 - Gasoline.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Gasoline. 1065.710 Section 1065.710... PROCEDURES Engine Fluids, Test Fuels, Analytical Gases and Other Calibration Standards § 1065.710 Gasoline. (a) Gasoline for testing must have octane values that represent commercially available fuels for the...

Suicidal inhalation of motorbike exhaust: adding new data to the literature about the contribution of gasoline in the cause of death.

Science.gov (United States)

Martínez, María A; Ballesteros, Salomé

2006-01-01

We would like to alert toxicologists to the importance of testing for gasoline, and for volatile hydrocarbons in general, in deaths involving inhalation of exhaust fumes occurring in closed spaces with running motors or machinery. We present here a case of suicidal inhalation of motorbike exhaust, a mixture of carbon monoxide (CO) and gasoline vapor, by a 38-year-old female. She was found in her closed home garage with a hose extending from the exhaust pipe of a motorbike through a cellophane plastic device into a closed tent in which the victim lay. She left two suicide notes nearby. The carboxyhemoglobin (COHb) was measured using visible spectrophotometry. The toxicological screening and quantitation of gasoline was performed by means of gas chromatography with flame-ionization detector and confirmation was performed using gas chromatography-mass spectrometry. The %COHb determined in blood was 73%. Gasoline concentrations in heart blood and vitreous humor were 22.3 and 1.0 mg/L, respectively. Although fatalities with CO at this rate are common, we would like to highlight the role of gasoline and add new quantitative data of this toxic substance to the scarce literature. Based upon the toxicological data, along with the information provided by the medical examiner, the cause of death was determined to be CO and gasoline poisoning and the manner of death suicide.

The gasoline retail market in Quebec

International Nuclear Information System (INIS)

Lapointe, A.

1998-06-01

A comprehensive study of the current status of the gasoline market in Quebec was presented. The study includes: (1) a review of the evolution of the retail market since the 1960s, (2) the development of a highly competitive sales environment, (3) a discussion of governmental interventions in the retail sales of gasoline, and (4) a discussion of the problems associated with the imposition of a minimum gasoline price. The low increase in demand for gasoline in Quebec since the 1980s has led to a considerable restructuring of the gasoline market. Consumers have little loyalty to specific brands but seek the lowest prices or prefer the outlets that offer the widest variety of associated services such as convenience stores, fast-food and car washes. Gasoline has clearly become a commodity in Quebec. An econometric model of gasoline price adjustments for the Montreal and Toronto urban areas and a summary of government interventions in the retail marketing of gasoline in Canada and the USA are included as appendices. tabs

77 FR 28772 - Air Quality: Widespread Use for Onboard Refueling Vapor Recovery and Stage II Waiver

Science.gov (United States)

2012-05-16

... fills with liquid gasoline. Where air pollution control technology is not used, these vapors are emitted... states (typically state air pollution control agencies) and, in some cases, local governments that develop air pollution control rules that apply to areas classified as Serious and above for nonattainment...

Standby Gasoline Rationing Plan. Contingency gasoline rationing regulations

Energy Technology Data Exchange (ETDEWEB)

1979-02-01

The Economic Regulatory Administration issues final rules with respect to standby gasoline rationing. The plan is designed for and would be used only in the event of a severe gasoline shortage. The plan provides that eligibility for ration allotments will be primarily on the basis of motor vehicle registrations. DOE will mail government ration checks to the parties named in a national vehicle registration file to be maintained by DOE. Ration recipients may cash these checks for ration coupons at various designated coupon issuance points. Retail outlets and other suppliers will be required to redeem the ration coupons received in exchange for gasoline sold. Supplemental gas will be given to high-priority activities. A ration banking system will be established with two separate and distinct of ration accounts: retail outlets and other suppliers will open redemption accounts for the deposit of redeemed ration rights; and individuals or firms may open ration rights accounts, which will operate in much the same manner as monetary checking accounts. A white market will be permitted for the sale of transfer of ration rights. A percentage of the total ration rights to be issued will be reserved for distribution to the states as a State Ration Reserve, to be used by the states primarily for the relief of hardship. A National Ration Reserave will also be established. All sections of the Standby Gasoline Rationing Regulations are analyzed. (MCW)

Mixture formation of direct gasoline injection engine. In cylinder gas sampling using fast response ionization detector; Tonai funsha gasoline engine no kongoki keisei. Kosoku FID ni yoru tonai gas sampling

Energy Technology Data Exchange (ETDEWEB)

Yamashita, H; Marubara, M; Ota, N; Kudo, H; Yamamoto, H [Mazda Motor Corp., Hiroshima (Japan)

1997-10-01

Local mixture concentration near the spark plug of a direct gasoline injection engine was observed by a fast flame ionization detector. To ensure combustion stability and good fuel economy in DISC operation, the swirl ratio and the piston configuration were optimized. Swirl is needed to retain well-vaporized and stable mixture near the spark plug especially in light load. And adequate volume in piston cavity is required for trapping curved fuel spray in it. With these specifications, the fuel economy improvement of 13 to 30 % was realized. 2 refs., 13 figs., 1 tab.

27 CFR 21.109 - Gasoline.

Science.gov (United States)

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Gasoline. 21.109 Section 21.109 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF... Gasoline. (a) Distillation range. When 100 ml of gasoline are distilled, none shall distill below 90 °F...

Oxygenates to hike gasoline price

International Nuclear Information System (INIS)

Anon.

1992-01-01

This paper reports that cost of achieving required US gasoline formulations this winter in Environmental Protection Agency carbon monoxide (CO) nonattainment areas could reach 3-5 cents/gal, an Energy Information Administration analysis has found. EIA says new winter demand for gasoline blending oxygenates such as methyl tertiary butyl ether (MTBE) or ethanol created by 190 amendments to the Clean Air Act (CAA) will exceed US oxygenate production by 140,000-220,000 b/d. The shortfall must be made up from inventory or imports. EIA estimates the cost of providing incremental oxygenate to meet expected gasoline blending demand likely will result in a price premium of about 20 cents/gal of MTBE equivalent over traditional gasoline blend octane value. That cost likely will be added to the price of oxygenated gasoline

Purification Simulation With Vapor Permeation and Distillation-Adsorption In Bioethanol Plant

OpenAIRE

Misri Gozan; Mia Sari Setiawan; Kenny Lischer

2017-01-01

High purity of Bioethanol is required in biofuel mixing with gasoline (EXX). In bioethanol production line, the azeotropic property of ethanol-water becomes the barrier for purification process. This study examined two bioethanol separation processes by support of simulation tools, Superpro Designer 9.0 software. Ethanol purity and a low costeconomical process were the major considerations. Purification method of vapor permeation membrane technology was compared with distillation-adsorption m...

Property Analysis of Ethanol--Natural Gasoline--BOB Blends to Make Flex Fuel

Energy Technology Data Exchange (ETDEWEB)

Alleman, Teresa L. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Yanowitz, Janet [Ecoengineering, Inc., Sharonville, OH (United States)

2016-11-01

Ten natural gasolines were analyzed for a wide range of properties, including Reid vapor pressure (RVP), benzene, sulfur, distillation, stability, metals, and aromatic content, to determine their quality. Benzene and sulfur content were sufficiently low in all but one of the samples that they could be blended without further upgrading. Four of these samples were selected to blend with blendstock for oxygenate blending (BOB) and ethanol to produce E51, E70, and E83 blends, targeting 7.8 and 9.0-psi finished fuels. The volume of each component in the blend was estimated using the Reddy model, with the assumption that the BOB and natural gasoline blend linearly and behave as a single component in the model calculations. Results show that the Reddy model adequately predicts the RVP of the finished blend for E51 and E70, but significantly underpredicts the RVP of E83 blends by nearly 2 psi. It is hypothesized that the underprediction is a function of the very low aromatic content of the E83 blends, even compared to the E51 and E70 blends.

40 CFR 63.11087 - What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

Science.gov (United States)

2010-07-01

... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

78 FR 79340 - Approval and Promulgation of Air Quality Implementation Plans; Texas; Stage II Vapor Recovery...

Science.gov (United States)

2013-12-30

... gasoline. Where air pollution control technology is not used, these vapors are emitted into the air. In the... Control of Air Pollution From Volatile Organic Compounds AGENCY: Environmental Protection Agency (EPA... Reviews I. Background A. What is a SIP? A SIP is a set of air pollution regulations, control strategies...

Gasoline engine management systems and components

CERN Document Server

2015-01-01

The call for environmentally compatible and economical vehicles necessitates immense efforts to develop innovative engine concepts. Technical concepts such as gasoline direct injection helped to save fuel up to 20 % and reduce CO2-emissions. Descriptions of the cylinder-charge control, fuel injection, ignition and catalytic emission-control systems provides comprehensive overview of today´s gasoline engines. This book also describes emission-control systems and explains the diagnostic systems. The publication provides information on engine-management-systems and emission-control regulations. Contents History of the automobile.- Basics of the gasoline engine.- Fuels.- Cylinder-charge control systems.- Gasoline injection systems over the years.- Fuel supply.- Manifold fuel injection.- Gasoline direct injection.- Operation of gasoline engines on natural gas.- Ignition systems over the years.- Inductive ignition systems.- Ignition coils.- Spark plugs.- Electronic control.- Sensors.- Electronic control unit.- Exh...

Mathematical Modeling of HC Emissions Released by Oil Film for Gasoline and Alcohol Fuels

Directory of Open Access Journals (Sweden)

M. İhsan KARAMANGİL

2013-04-01

Full Text Available Oil film on cylinder liner has been suggested as a major source of engine-out hydrocarbon emissions. So in the present study, the rate of absorption/desorption of the fuel in the oil film has been investigated numerically in a spark ignition engine by using gasoline, ethanol and methanol fuels. To aim this purpose, a thermodynamic cycle model has been developed and then a mathematical modeling for the rate of absorption/desorption of the fuel in the oil film has been developed and adapted for this thermodynamic cycle model.It was seen that the absorption/desorption mechanism of ethanol and methanol into the oil film were lower than gasoline. It was determined that the most dominant parameter of this difference was Henry’s constant, which was related to solubility. As interaction time of oil filmfuel vapor was longer at low engine speeds, the quantities of HC absorbed/desorbed increased. The quantities of HC absorbed/desorbed increased with increasing inlet pressure and compression ratio

Emissions characteristics of higher alcohol/gasoline blends

International Nuclear Information System (INIS)

Gautam, M.; Martin, D.W.; Carder, D.

2000-01-01

An experimental investigation was conducted to determine the emissions characteristics of higher alcohols and gasoline (UTG96) blends. While lower alcohols (methanol and ethanol) have been used in blends with gasoline, very little work has been done or reported on higher alcohols (propanol, butanol and pentanol). Comparisons of emissions and fuel characteristics between higher alcohol/gasoline blends and neat gasoline were made to determine the advantages and disadvantages of blending higher alcohols with gasoline. All tests were conducted on a single-cylinder Waukesha Cooperative Fuel Research engine operating at steady state conditions and stoichiometric air-fuel (A/F) ratio. Emissions test were conducted at the optimum spark timing-knock limiting compression ratio combination for the particular blend being tested. The cycle emission [mass per unit time (g/h)] of CO, CO 2 and organic matter hydrocarbon equivalent (OMHCE) from the higher alcohol/gasoline blends were very similar to those from neat gasoline. Cycle emissions of NO x from the blends were higher than those from neat gasoline. However, for all the emissions species considered, the brake specific emissions (g/kW h) were significantly lower for the higher alcohol/gasoline blends than for neat gasoline. This was because the blends had greater resistance to knock and allowed higher compression ratios, which increased engine power output. The contribution of alcohols and aldehydes to the overall OMHCE emissions was found to be minimal. Cycle fuel consumption (g/h) of higher alcohol/gasoline blends was slightly higher than with neat gasoline due to the lower stoichiometric A/F ratios required by the blends. However, the brake specific fuel consumption (g/kW h) for the blends was significantly lower than that for neat gasoline. (Author)

Recent progress in gasoline surrogate fuels

KAUST Repository

Sarathy, Mani; Farooq, Aamir; Kalghatgi, Gautam T.

2017-01-01

Petroleum-derived gasoline is currently the most widely used fuel for transportation propulsion. The design and operation of gasoline fuels is governed by specific physical and chemical kinetic fuel properties. These must be thoroughly understood in order to improve sustainable gasoline fuel technologies in the face of economical, technological, and societal challenges. For this reason, surrogate mixtures are formulated to emulate the thermophysical, thermochemical, and chemical kinetic properties of the real fuel, so that fundamental experiments and predictive simulations can be conducted. Early studies on gasoline combustion typically adopted single component or binary mixtures (n-heptane/isooctane) as surrogates. However, the last decade has seen rapid progress in the formulation and utilization of ternary mixtures (n-heptane/isooctane/toluene), as well as multicomponent mixtures that span the entire carbon number range of gasoline fuels (C4–C10). The increased use of oxygenated fuels (ethanol, butanol, MTBE, etc.) as blending components/additives has also motivated studies on their addition to gasoline fuels. This comprehensive review presents the available experimental and chemical kinetic studies which have been performed to better understand the combustion properties of gasoline fuels and their surrogates. Focus is on the development and use of surrogate fuels that emulate real fuel properties governing the design and operation of engines. A detailed analysis is presented for the various classes of compounds used in formulating gasoline surrogate fuels, including n-paraffins, isoparaffins, olefins, naphthenes, and aromatics. Chemical kinetic models for individual molecules and mixtures of molecules to emulate gasoline surrogate fuels are presented. Despite the recent progress in gasoline surrogate fuel combustion research, there are still major gaps remaining; these are critically discussed, as well as their implications on fuel formulation and engine

Recent progress in gasoline surrogate fuels

KAUST Repository

Sarathy, Mani

2017-12-06

Petroleum-derived gasoline is currently the most widely used fuel for transportation propulsion. The design and operation of gasoline fuels is governed by specific physical and chemical kinetic fuel properties. These must be thoroughly understood in order to improve sustainable gasoline fuel technologies in the face of economical, technological, and societal challenges. For this reason, surrogate mixtures are formulated to emulate the thermophysical, thermochemical, and chemical kinetic properties of the real fuel, so that fundamental experiments and predictive simulations can be conducted. Early studies on gasoline combustion typically adopted single component or binary mixtures (n-heptane/isooctane) as surrogates. However, the last decade has seen rapid progress in the formulation and utilization of ternary mixtures (n-heptane/isooctane/toluene), as well as multicomponent mixtures that span the entire carbon number range of gasoline fuels (C4–C10). The increased use of oxygenated fuels (ethanol, butanol, MTBE, etc.) as blending components/additives has also motivated studies on their addition to gasoline fuels. This comprehensive review presents the available experimental and chemical kinetic studies which have been performed to better understand the combustion properties of gasoline fuels and their surrogates. Focus is on the development and use of surrogate fuels that emulate real fuel properties governing the design and operation of engines. A detailed analysis is presented for the various classes of compounds used in formulating gasoline surrogate fuels, including n-paraffins, isoparaffins, olefins, naphthenes, and aromatics. Chemical kinetic models for individual molecules and mixtures of molecules to emulate gasoline surrogate fuels are presented. Despite the recent progress in gasoline surrogate fuel combustion research, there are still major gaps remaining; these are critically discussed, as well as their implications on fuel formulation and engine

Gasoline surrogate modeling of gasoline ignition in a rapid compression machine and comparison to experiments

Energy Technology Data Exchange (ETDEWEB)

Mehl, M; Kukkadapu, G; Kumar, K; Sarathy, S M; Pitz, W J; Sung, S J

2011-09-15

The use of gasoline in homogeneous charge compression ignition engines (HCCI) and in duel fuel diesel - gasoline engines, has increased the need to understand its compression ignition processes under engine-like conditions. These processes need to be studied under well-controlled conditions in order to quantify low temperature heat release and to provide fundamental validation data for chemical kinetic models. With this in mind, an experimental campaign has been undertaken in a rapid compression machine (RCM) to measure the ignition of gasoline mixtures over a wide range of compression temperatures and for different compression pressures. By measuring the pressure history during ignition, information on the first stage ignition (when observed) and second stage ignition are captured along with information on the phasing of the heat release. Heat release processes during ignition are important because gasoline is known to exhibit low temperature heat release, intermediate temperature heat release and high temperature heat release. In an HCCI engine, the occurrence of low-temperature and intermediate-temperature heat release can be exploited to obtain higher load operation and has become a topic of much interest for engine researchers. Consequently, it is important to understand these processes under well-controlled conditions. A four-component gasoline surrogate model (including n-heptane, iso-octane, toluene, and 2-pentene) has been developed to simulate real gasolines. An appropriate surrogate mixture of the four components has been developed to simulate the specific gasoline used in the RCM experiments. This chemical kinetic surrogate model was then used to simulate the RCM experimental results for real gasoline. The experimental and modeling results covered ultra-lean to stoichiometric mixtures, compressed temperatures of 640-950 K, and compression pressures of 20 and 40 bar. The agreement between the experiments and model is encouraging in terms of first

Co-Optimization of Fuels & Engines: Misfueling Mitigation

Energy Technology Data Exchange (ETDEWEB)

Sluder, C. Scott [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Moriarty, Kristi [National Renewable Energy Lab. (NREL), Golden, CO (United States); Jehlik, Forrest [Argonne National Lab. (ANL), Argonne, IL (United States); West, Brian H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2017-04-06

This report examines diesel/gasoline misfueling, leaded/unleaded gasoline misfueling, E85/E15/E10 misfueling, and consumer selection of regular grade fuel over premium grade fuel in an effort to evaluate misfueling technologies that may be needed to support the introduction of vehicles optimized for a new fuel in the marketplace. This is one of a series of reports produced as a result of the Co-Optimization of Fuels & Engines (Co-Optima) project, a Department of Energy-sponsored multi-agency project to accelerate the introduction of affordable, scalable, and sustainable biofuels and high-efficiency, low-emission vehicle engines.

40 CFR 80.141 - Interim detergent gasoline program.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Interim detergent gasoline program. 80... (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Detergent Gasoline § 80.141 Interim detergent gasoline... apply to: (i) All gasoline sold or transferred to a party who sells or transfers gasoline to the...

Size distribution, chemical composition and oxidation reactivity of particulate matter from gasoline direct injection (GDI) engine fueled with ethanol-gasoline fuel

International Nuclear Information System (INIS)

Luo, Yueqi; Zhu, Lei; Fang, Junhua; Zhuang, Zhuyue; Guan, Chun; Xia, Chen; Xie, Xiaomin; Huang, Zhen

2015-01-01

Ethanol-gasoline blended fuels have been widely applied in markets recently, as ethanol reduces life-cycle greenhouse gas emissions and improves anti-knock performance. However, its effects on particulate matter (PM) emissions from gasoline direct injection (GDI) engine still need further investigation. In this study, the effects of ethanol-gasoline blended fuels on particle size distributions, number concentrations, chemical composition and soot oxidation activity of GDI engine were investigated. It was found that ethanol-gasoline blended fuels increased the particle number concentration in low-load operating conditions. In higher load conditions, the ethanol-gasoline was effective for reducing the particle number concentration, indicating that the chemical benefits of ethanol become dominant, which could reduce soot precursors such as large n-alkanes and aromatics in gasoline. The volatile organic mass fraction in ethanol-gasoline particulates matter was higher than that in gasoline particulate matter because ethanol reduced the amount of soot precursors during combustion and thereby reduced the elemental carbon proportions in PM. Ethanol addition also increased the proportion of small particles, which confirmed the effects of ethanol on organic composition. Ethanol-gasoline reduced the concentrations of most PAH species, except those with small aromatic rings, e.g., naphthalene. Soot from ethanol-gasoline has lower activation energy of oxidation than that from gasoline. The results in this study indicate that ethanol-gasoline has positive effects on PM emissions control, as the soot oxidation activity is improved and the particle number concentrations are reduced at moderate and high engine loads. - Highlights: • Ethanol-gasoline reduces elemental carbon in PM. • Ethanol-gasoline increases volatile organic fraction in PM. • Soot generated from ethanol-gasoline has higher oxidation activity.

Gasoline from Kumkol deposit petroleum

International Nuclear Information System (INIS)

Nadirov, A.N.; Zhizhin, N.I.; Musaeva, Z.G.

1997-01-01

Samples of gasoline from petroleum of Kumkol deposit are investigated by chromatographic analysis. It is found, that gasoline is characterizing by increased content of iso-paraffin hydrocarbons. (author)

Study of SI engine fueled with methanol vapor and dissociation gas based on exhaust heat dissociating methanol

International Nuclear Information System (INIS)

Fu, Jianqin; Deng, Banglin; Liu, Jingping; Wang, Linjun; Xu, Zhengxin; Yang, Jing; Shu, Gequn

2014-01-01

Highlights: • The full load power decreases successively from gasoline engine, methanol vapor engine to dissociated methanol engine. • Both power and thermal efficiency of dissociated methanol engine can be improved by boosting pressure. • The conversion efficiency of recovered exhaust gas energy is largely influenced by the BMEP. • At the same BMEP, dissociated methanol engine has higher thermal efficiency than methanol vapor engine and gasoline engine. - Abstract: To improve the fuel efficiency of internal combustion (IC) engine and also achieve the goal of direct usage of methanol fuel on IC engine, an approach of exhaust heat dissociating methanol was investigated, which is a kind of method for IC engine exhaust heat recovery (EHR). A bottom cycle system is coupled with the IC engine exhaust system, which uses the exhaust heat to evaporate and dissociate methanol in its catalytic cracker. The methanol dissociation gas (including methanol vapor) is used as the fuel for IC engine. This approach was applied to both naturally aspirated (NA) engine and turbocharged engine, and the engine performance parameters were predicted by the software GT-power under various kinds of operating conditions. The improvement to IC engine performance and the conversion efficiency of recovered exhaust gas energy can be evaluated by comparing the performances of IC engine fueled with various kinds of fuels (or their compositions). Results show that, from gasoline engine, methanol vapor engine to dissociated methanol engine, the full load power decreases successively in the entire speed area due to the declining of volumetric efficiency, while it is contrary in the thermal efficiency at the same brake mean effective pressure (BMEP) level because of the improving of fuel heating value. With the increase of BMEP, the conversion efficiency of recovered exhaust gas energy is promoted. All those results indicate that the approach of exhaust heat dissociating methanol has large

The effects of hydrous ethanol gasoline on combustion and emission characteristics of a port injection gasoline engine

OpenAIRE

Xiaochen Wang; Zhenbin Chen; Jimin Ni; Saiwu Liu; Haijie Zhou

2015-01-01

Comparative experiments were conducted on a port injection gasoline engine fueled with hydrous ethanol gasoline (E10W), ethanol gasoline (E10) and pure gasoline (E0). The effects of the engine loads and the additions of ethanol and water on combustion and emission characteristics were analyzed deeply. According to the experimental results, compared with E0, E10W showed higher peak in-cylinder pressure at high load. Increases in peak heat release rates were observed for E10W fuel at all the op...

Batteries: Lower cost than gasoline?

International Nuclear Information System (INIS)

Werber, Mathew; Fischer, Michael; Schwartz, Peter V.

2009-01-01

We compare the lifecycle costs of an electric car to a similar gasoline-powered vehicle under different scenarios of required driving range and cost of gasoline. An electric car is cost competitive for a significant portion of the scenarios: for cars of lower range and for higher gasoline prices. Electric cars with ∼150 km range are a technologically viable, cost competitive, high performance, high efficiency alternative that can presently suit the vast majority of consumers' needs.

Piston Aviation Fuel Initiative (PAFI) – A Review

Science.gov (United States)

Thanikasalam, K.; Rahmat, M.; Fahmi, A. G. Mohammad; Zulkifli, A. M.; Shawal, N. Noor; Ilanchelvi, K.; Ananth, M.; Elayarasan, R.

2018-05-01

Aviation gasoline (Avgas) has remained unchanged for seventy years and the existing fleet of piston aircraft was designed to be compatible with its chemical and physical properties to achieve superior levels of safety. Tetra-ethyl lead (TEL) is an octane-enhancing metal additive used in aviation gasoline to prevent knocking. Studies have shown that lead causes brain damage in children reducing their IQ and cardiovascular difficulties and kidney failure in adults. Friends of the Earth (FOE) petitioned the Environmental Protection Agency (EPA) in 2006 to make a finding that lead emissions from general aviation (GA) aircraft cause to public health endangerment or carry out studies and issue a report on its findings. PAFI was set up by Federal Aviation Administration (FAA) to find most suitable unleaded replacements for Avgas to recognize best unleaded fuel that have the capacity to in fact satisfy the requirements of the present aircraft fleet while additionally considering the creation, dispersion, cost, availability, environmental impacts. This study will technically review PAFI and broaden the limited knowledge on piston aviation fuels in Malaysia by giving a comprehensive analysis and possible gap in reciprocation aviation engine market in Malaysia.

Who Pays the Gasoline Tax?

OpenAIRE

Chernick, Howard; Reschovsky, Andrew

1997-01-01

Analyzes panel data over 11 years (both backward from 1982 and forward from 1982) to determine the average gasoline tax burden. Considers links between economic mobility, gasoline consumption, and excise tax increases.

A 90-day continuous vapor inhalation toxicity study of JP-8 jet fuel followed by 20 or 21 months of recovery in Fischer 344 rats and C57BL/6 mice.

Science.gov (United States)

Mattie, D R; Alden, C L; Newell, T K; Gaworski, C L; Flemming, C D

1991-01-01

The kerosene-type jet fuel, JP-8, consists of a complex mixture of aliphatic and aromatic hydrocarbons. Because of the utility of JP-8, studies have been conducted to identify the potential long-term consequence of occupational inhalation exposure. Fischer 344 rats and C57BL/6 mice of both sexes were exposed to JP-8 vapors at 0, 500, and 1,000 mg/m3 on a continuous basis for 90 days, then followed by recovery until approximately 24 months of age. Occurrence of necrotizing dermatitis associated with fighting resulted in an increase in mortality in mice (male greater than female) during the 2 week to 9 month post-exposure recovery period. The male rat kidney developed a reversible ultrastructural increase in size and propensity for crystalloid changes of phagolysosomal proteinic reabsorption droplets in the proximal convoluted tubular epithelium. A specific triad of persisting light microscopic renal lesions occurred but functional change was limited to a decrease in urine concentration compared to controls that persisted throughout the recovery period. The response is comparable to the chronic effect of lifetime exposure of the male rat to unleaded gasoline, d-limonene, and p-dichlorobenzene, except for the absence of tubular tumorigenesis. The active toxicologic response presumably must occur over a greater proportion of the male rat's life span for the tumor component of this male rat hydrocarbon nephropathy syndrome. The predictiveness for humans must be questioned, since the pathologic response to JP-8 involved only one tissue in one sex of one species, and since the male rat response appears to be linked to an inherent renal protein peculiarity.

Combustion Kinetic Studies of Gasolines and Surrogates

KAUST Repository

Javed, Tamour

2016-11-01

Future thrusts for gasoline engine development can be broadly summarized into two categories: (i) efficiency improvements in conventional spark ignition engines, and (ii) development of advance compression ignition (ACI) concepts. Efficiency improvements in conventional spark ignition engines requires downsizing (and turbocharging) which may be achieved by using high octane gasolines, whereas, low octane gasolines fuels are anticipated for ACI concepts. The current work provides the essential combustion kinetic data, targeting both thrusts, that is needed to develop high fidelity gasoline surrogate mechanisms and surrogate complexity guidelines. Ignition delay times of a wide range of certified gasolines and surrogates are reported here. These measurements were performed in shock tubes and rapid compression machines over a wide range of experimental conditions (650 – 1250 K, 10 – 40 bar) relevant to internal combustion engines. Using the measured the data and chemical kinetic analyses, the surrogate complexity requirements for these gasolines in homogeneous environments are specified. For the discussions presented here, gasolines are classified into three categories: (i)\\tLow octane gasolines including Saudi Aramco’s light naphtha fuel (anti-knock index, AKI = (RON + MON)/2 = 64; Sensitivity (S) = RON – MON = 1), certified FACE (Fuels for Advanced Combustion Engines) gasoline I and J (AKI ~ 70, S = 0.7 and 3 respectively), and their Primary Reference Fuels (PRF, mixtures of n-heptane and iso-octane) and multi-component surrogates. (ii)\\t Mid octane gasolines including FACE A and C (AKI ~ 84, S ~ 0 and 1 respectively) and their PRF surrogates. Laser absorption measurements of intermediate and product species formed during gasoline/surrogate oxidation are also reported. (iii)\\t A wide range of n-heptane/iso-octane/toluene (TPRF) blends to adequately represent the octane and sensitivity requirements of high octane gasolines including FACE gasoline F and G

Gasoline ingestion: a rare cause of pancytopenia.

Science.gov (United States)

Rahman, Ifad; Narasimhan, Kanakasabai; Aziz, Shahid; Owens, William

2009-11-01

The majority of reported cases of gasoline intoxication involves inhalation or percutaneous absorption. Data are scarce on complications and outcomes after gasoline poisoning by oral ingestion. The major cause of mortality and morbidity associated with the ingestion of gasoline is related to pulmonary aspiration. Despite the high frequency of the ingestions, there is little documentation of nonpulmonary toxic effects of gasoline. After ingestion, the principal toxicity is aspiration pneumonia, but any documented extra pulmonary manifestations of this condition may be important in the overall management of these patients. We are reporting a rare case of pancytopenia along with aspiration pneumonia and multisystem organ failure in a 58-year-old male after prolonged intentional ingestion of gasoline. To our knowledge, this is the only reported case of gasoline toxicity causing pancytopenia.

Robust predictive control of a gasoline debutanizer column

Directory of Open Access Journals (Sweden)

E. Almeida Neto

2000-12-01

Full Text Available This paper studies the application of Model Predictive Control to moderately nonlinear processes. The system used in this work is an industrial gasoline debutanizer column. The paper presents two new formulations of MPC: MMPC (Multi-Model Predictive Controller and RSMPC (Robust Stable MPC. The approach is based on the concepts of Linear Matrix Inequalities (LMI, which have been recently introduced in the MPC field. Model uncertainty is considered by assuming that the true process model belongs to a convex set (polytope of possible plants. The controller has guaranteed stability when a Lyapunov type inequality constraint is included in the MPC problem. In the debutanizer column, several nonlinearities are present in the advanced control level when the manipulated inputs are the reflux flow and the reboiler heat duty. In most cases the controlled outputs are the contents of C5+ (pentane and heavier hydrocarbons in the LPG (Liquefied Petroleum Gas and the gasoline vapor pressure (P VR. In this case the QDMC algorithm which is usually applied to the debutanizer column has a poor performance and stability problems reflected in an oscillatory behavior of the process. The new approach considers several process models representing different operating conditions where linear models are identified. The results presented here show that the multimodel controller is capable of controlling the process in the entire operating window while the conventional MPC has a limited operating range.

Numerical studies of spray breakup in a gasoline direct injection (GDI engine

Directory of Open Access Journals (Sweden)

Jafarmadar Samad

2011-01-01

Full Text Available The objective of this study is to investigate Spray Breakup process of sprays injected from single and two-hole nozzles for gasoline direct Injection (GDI engines by using three dimensional CFD code. Spray characteristics were examined for spray tip penetration and other characteristics including: the vapor phase concentration distribution and droplet spatial distribution, which were acquired using the computational fluid dynamics (CFD simulation. Results showed that as the hole-axis-angle (γ of the two-hole nozzle decreased, the droplet coalescence increased and vapor mass decreased. The spray with cone angle (θ0 5 deg for single hole nozzle has the longest spray tip penetration and the spray with the γ of 30 deg and spray cone angle θ0=30 deg for two hole nozzles had the shortest one. Also, when the spray cone angle (θ0 and hole-axis-angle (γ increased from 5 to 30 deg, the Sauter mean diameter (SMD decreased for both single-hole and two-hole nozzles used in this study. For a single-hole nozzle, when spray cone angle increased from 5 to 30 deg, the vaporization rate very much because of low level of coalescence. The result of model for tip penetration is good agreement with the corresponding experimental data in the literatures.

40 CFR 63.11088 - What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 14 2010-07-01 2010-07-01 false What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... § 63.11088 What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

Autoignition characteristics of oxygenated gasolines

KAUST Repository

Lee, Changyoul; Ahmed, Ahfaz; Nasir, Ehson Fawad; Badra, Jihad; Kalghatgi, Gautam; Sarathy, Mani; Curran, Henry; Farooq, Aamir

2017-01-01

Gasoline anti-knock quality, defined by the research and motor octane numbers (RON and MON), is important for increasing spark ignition (SI) engine efficiency. Gasoline knock resistance can be increased using a number of blending components

A cointegration analysis of petroleum futures prices

Energy Technology Data Exchange (ETDEWEB)

Serletis, Apostolos (Calgary Univ., AB (Canada). Dept. of Economics)

1994-04-01

This paper presents evidence concerning the number of common stochastic trends in a system of three petroleum futures prices (crude oil, heating oil and unleaded gasoline) using daily data from 3 December 1984 to 30 April 1993. Johansen's maximum likelihood approach for estimating long-run relations in multivariate vector autoregressive models is used. The results indicate the presence of only one common trend. (author)

Ignition studies of two low-octane gasolines

KAUST Repository

Javed, Tamour

2017-07-24

Low-octane gasolines (RON ∼ 50–70 range) are prospective fuels for gasoline compression ignition (GCI) internal combustion engines. GCI technology utilizing low-octane fuels has the potential to significantly improve well-to-wheel efficiency and reduce the transportation sector\\'s environmental footprint by offsetting diesel fuel usage in compression ignition engines. In this study, ignition delay times of two low-octane FACE (Fuels for Advanced Combustion Engines) gasolines, FACE I and FACE J, were measured in a shock tube and a rapid compression machine over a broad range of engine-relevant conditions (650–1200 K, 20 and 40 bar and ϕ = 0.5 and 1). The two gasolines are of similar octane ratings with anti-knock index, AKI = (RON + MON)/2, of ∼ 70 and sensitivity, S = RON–MON, of ∼ 3. However, the molecular compositions of the two gasolines are notably different. Experimental ignition delay time results showed that the two gasolines exhibited similar reactivity over a wide range of test conditions. Furthermore, ignition delay times of a primary reference fuel (PRF) surrogate (n-heptane/iso-octane blend), having the same AKI as the FACE gasolines, captured the ignition behavior of these gasolines with some minor discrepancies at low temperatures (T < 700 K). Multi-component surrogates, formulated by matching the octane ratings and compositions of the two gasolines, emulated the autoignition behavior of gasolines from high to low temperatures. Homogeneous charge compression ignition (HCCI) engine simulations were used to show that the PRF and multi-component surrogates exhibited similar combustion phasing over a wide range of engine operating conditions.

Large eddy simulation and experimental study on vented gasoline-air mixture explosions in a semi-confined obstructed pipe.

Science.gov (United States)

Li, Guoqing; Du, Yang; Wang, Shimao; Qi, Sheng; Zhang, Peili; Chen, Wenzhuo

2017-10-05

In this work, LES simulation coupled with a TFC sub-grid combustion model has been performed in a semi-confined pipe (L/D=10, V=10L) in the presence of four hollow-square obstacles (BR=49.8%) with circular hollow cross-section, in order to study the premixed gasoline-air mixture explosions. The comparisons between simulated results and experimental results have been conducted. It was found that the simulated results were in good agreement with experimental data in terms of flame structures, flame locations and overpressure time histories. Moreover, the interaction between flame propagation process and obstacles, overpressure dynamics were analyzed. In addition, the effects of initial gasoline vapor concentration (lean (ϕ=1.3%), stoichiometric (ϕ=1.7%) and rich (ϕ=2.1%)), and the number of obstacles (from 1 to 4) were also investigated by experiments. Some of the experimental results have been compared with the literature data. It is found that the explosion parameters of gasoline-air mixtures (e.g. the maximum overpressure peaks, average overpressure growth rates, etc.) are different from some other fuels such as hydrogen, methane and LPG, etc. Copyright © 2017. Published by Elsevier B.V.

Understanding gasoline pricing in Canada

International Nuclear Information System (INIS)

2001-04-01

This brochure is designed to help consumers understand how gasoline is priced and explained why prices increase, fluctuate and vary by location, city or region. The price of a litre of gasoline reflects the costs of crude oil, refining, retailing and taxes. Taxes are usually the largest single component of gasoline prices, averaging 40 to 50 per cent of the pump price. The cost of crude oil makes up another 35 to 45 per cent of the price. Refining costs make up 10 to 15 per cent while the remaining 5 to 10 per cent represents retail costs. Gasoline retailers make a profit of about 1 cent per litre. The latest network technology allows national and regional retail chains to constantly monitor price fluctuations to change their prices at gasoline stations at a moments notice to keep up with the competition and to protect their market shares. Several government studies, plus the Conference Board of Canada, have reported that competition is working in favour of Canadian motorists. This brochure also explained the drawbacks of regulating crude and pump prices with the reminder that crude prices were regulated in the 1970s with many negative consequences. 2 tabs., 1 fig

Performance, emission and combustion characteristics of a branched higher mass, C3 alcohol (isopropanol blends fuelled medium duty MPFI SI engine

Directory of Open Access Journals (Sweden)

Harish Sivasubramanian

2017-04-01

Full Text Available With growing concerns about environmental pollution caused by automobiles, biofuels containing oxygen – also known as oxygenates – are being researched very rigorously. In this article, we have inspected the use of isopropanol/gasoline blends, as fuel in a 4 – cylinder Spark Ignition engine with Multi-Point Fuel Injection System. Isopropanol was mixed with Unleaded Gasoline in proportions of 10, 20 and 30% by volume (IPA10, IPA20 and IPA30. It is found that with the use of isopropanol/gasoline blends in Spark Ignition Engine, Brake Thermal Efficiency and NOx emissions increased whereas carbon monoxide and hydrocarbon emissions decreased. When the spark timing was retarded by 2 degrees, it was found that isopropanol/gasoline blends emitted lower NOx emissions than those at original spark timing. Isopropanol blends also increased the in-cylinder pressure values and heat release rate values.

Effects of gasoline and ethanol-gasoline exhaust exposure on human bronchial epithelial and natural killer cells in vitro.

Science.gov (United States)

Roth, Michèle; Usemann, Jakob; Bisig, Christoph; Comte, Pierre; Czerwinski, Jan; Mayer, Andreas C R; Beier, Konstantin; Rothen-Rutishauser, Barbara; Latzin, Philipp; Müller, Loretta

2017-12-01

Air pollution exposure, including passenger car emissions, may cause substantial respiratory health effects and cancer death. In western countries, the majority of passenger cars are driven by gasoline fuel. Recently, new motor technologies and ethanol fuels have been introduced to the market, but potential health effects have not been thoroughly investigated. We developed and verified a coculture model composed of bronchial epithelial cells (ECs) and natural killer cells (NKs) mimicking the human airways to compare toxic effects between pure gasoline (E0) and ethanol-gasoline-blend (E85, 85% ethanol, 15% gasoline) exhaust emitted from a flexfuel gasoline car. We drove a steady state cycle, exposed ECs for 6h and added NKs. We assessed exhaust effects in ECs alone and in cocultures by RT-PCR, flow cytometry, and oxidative stress assay. We found no toxic effects after exposure to E0 or E85 compared to air controls. Comparison between E0 and E85 exposure showed a weak association for less oxidative DNA damage after E85 exposure compared to E0. Our results indicate that short-term exposure to gasoline exhaust may have no major toxic effects in ECs and NKs and that ethanol as part of fuel for gasoline cars may be favorable. Copyright © 2017 Elsevier Ltd. All rights reserved.

Cointegration and the demand for gasoline

International Nuclear Information System (INIS)

Bhaskara Rao, B.; Rao, Gyaneshwar

2009-01-01

Since the early 1970s, there has been a worldwide upsurge in the price of energy and in particular of gasoline. Therefore, demand functions for energy and its components like gasoline have received much attention. However, since confidence in the estimated demand functions is important for use in policy and forecasting, following [Amarawickrama, H.A., Hunt, L.C., 2008. Electricity demand for Sri Lanka: A time series analysis. Energy Economics 33, 724-739], this paper estimates the demand for gasoline is estimated with five alternative time series techniques with data from Fiji. Estimates with these alternative techniques are very close, and thus increase our confidence in them. We found that gasoline demand is both price and income inelastic.

Cointegration and the demand for gasoline

Energy Technology Data Exchange (ETDEWEB)

Bhaskara Rao, B. [University of Western Sydney, Sydney1797 (Australia); Rao, Gyaneshwar [University of the South Pacific (Fiji)

2009-10-15

Since the early 1970s, there has been a worldwide upsurge in the price of energy and in particular of gasoline. Therefore, demand functions for energy and its components like gasoline have received much attention. However, since confidence in the estimated demand functions is important for use in policy and forecasting, following [Amarawickrama, H.A., Hunt, L.C., 2008. Electricity demand for Sri Lanka: A time series analysis. Energy Economics 33, 724-739], this paper estimates the demand for gasoline is estimated with five alternative time series techniques with data from Fiji. Estimates with these alternative techniques are very close, and thus increase our confidence in them. We found that gasoline demand is both price and income inelastic. (author)

40 CFR 80.540 - How may a refiner be approved to produce gasoline under the GPA gasoline sulfur standards in 2007...

Science.gov (United States)

2010-07-01

... produce gasoline under the GPA gasoline sulfur standards in 2007 and 2008? 80.540 Section 80.540... Marine Fuel Geographic Phase-in Provisions § 80.540 How may a refiner be approved to produce gasoline under the GPA gasoline sulfur standards in 2007 and 2008? (a) A refiner that has been approved by EPA...

Successful outcome after intravenous gasoline injection.

Science.gov (United States)

Domej, Wolfgang; Mitterhammer, Heike; Stauber, Rudolf; Kaufmann, Peter; Smolle, Karl Heinz

2007-12-01

Gasoline, ingested intentionally or accidentally, is toxic. The majority of reported cases of gasoline intoxication involve oral ingestion or inhalation. Data are scarce on complications and outcomes following hydrocarbon poisoning by intravenous injection. Following a suicide attempt by intravenous self-injection of 10 ml of gasoline, a 26-year-old medical student was admitted to the intensive care unit (ICU) with hemoptysis, symptoms of acute respiratory failure, chest pain, and severe abdominal cramps. Gas exchange was severely impaired and a chest x-ray indicated chemical pneumonitis. Initial treatment consisted of mechanical ventilation, supportive hyperventilation, administration of nitrogen oxide (NO), and prednisone. Unfortunately, the patient developed multi-organ dysfunction syndrome (MODS) complicated by life-threatening severe vasoplegia within 24 hours after gasoline injection. High doses of vasopressors along with massive amounts of parenteral fluids were necessary. Despite fluid replacement, renal function worsened and required hemofiltration on 5 sequential days. After 12 days of intensive care management, the patient recovered completely and was discharged to a psychiatric care facility. Intravenous gasoline injection causes major injury to the lungs, the organ bearing the first capillary bed encountered. Treatment of gasoline poisoning is symptomatic because no specific antidote is available. Early and aggressive supportive care may be conducive to a favorable outcome with minimal residual pulmonary sequelae.

40 CFR 79.32 - Motor vehicle gasoline.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Motor vehicle gasoline. 79.32 Section...) REGISTRATION OF FUELS AND FUEL ADDITIVES Designation of Fuels and Additives § 79.32 Motor vehicle gasoline. (a) The following fuels commonly or commercially known or sold as motor vehicle gasoline are hereby...

Analysis of vapor extraction data from applications in Europe

International Nuclear Information System (INIS)

Hiller, D.; Gudemann, H.

1989-01-01

This paper discusses vapor extraction, an in-situ process to remove volatile organic compounds (VOC) from soils of the vadose zone, applied in Europe since the early 1980s. In a vapor extraction well a negative differential pressure is created by a blower or similar device. The differential pressure generates a steady flow of soil gas towards the extraction well and thus provides a flushing of the soil with air undersaturated in respect to the contaminant concentration. Contaminants will evaporate into the gaseous phase both form the liquid phase and form the soil. Differential pressures applied range from 15 inches - 350 inches of water. The contaminated discharge air can be treated by activated carbon or other suitable methods. The effective radius of vapor extraction systems (VES) ranges typically form 20 feet to 150 feet underneath non-sealed - and up to 300 feet underneath sealed surfaces. Contamination from volatile organic compounds (VOC) have turned out to be widespread due to their almost ubiquitous presence in industrial processes. Specifically, VOC include halogenated hydrocarbons like TCE, PCE or TCA, aromatic hydrocarbons like benzene, toluene, xylene and volatile fuels like gasoline

Critical issues in benzene toxicity and metabolism: the effect of interactions with other organic chemicals on risk assessment.

OpenAIRE

Medinsky, M A; Schlosser, P M; Bond, J A

1994-01-01

Benzene, an important industrial solvent, is also present in unleaded gasoline and cigarette smoke. The hematotoxic effects of benzene are well documented and include aplastic anemia and pancytopenia. Some individuals exposed repeatedly to cytotoxic concentrations of benzene develop acute myeloblastic anemia. It has been hypothesized that metabolism of benzene is required for its toxicity, although administration of no single benzene metabolite duplicates the toxicity of benzene. Several inve...

Life cycle assessment of gasoline and diesel

International Nuclear Information System (INIS)

Furuholt, Edgar

1995-01-01

A life cycle assessment (LCA) has been carried out to compare production and use of three different fuel products: regular gasoline, gasoline with MTBE and diesel. The study quantifies energy consumption and emissions through the production chain and assesses the potential impacts to the environment. Some of the methodological problems performing the LCA are discussed. The study indicates that production of gasoline with MTBE has potentially larger environmental impacts than production of regular gasoline, caused by the extra facilities for production of MTBE. The study also shows that the results are highly sensitive to the actual product specifications and assumptions that are made. Different product specifications can therefore lead to other conclusions. The results also indicate that production of diesel leads to significantly lower potential impacts than the gasolines

46 CFR 169.613 - Gasoline fuel systems.

Science.gov (United States)

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Gasoline fuel systems. 169.613 Section 169.613 Shipping... Machinery and Electrical Fuel Systems § 169.613 Gasoline fuel systems. (a) Except as provided in paragraph (b) each gasoline fuel system must meet the requirements of § 56.50-70 of this chapter (b) Each...

The US gasoline situation and crude oil prices

International Nuclear Information System (INIS)

Anon.

2004-01-01

Before and during the United States' summer driving season, concern over the country's gasoline supply can potentially influence the direction of the petroleum market. There are three causes of concern: a persistent lack of gasoline-producing capacity; a patchwork of as many as 18 different kinds of gasoline specifications; and the introduction of stringent new specifications for reformulated gasoline. However, gasoline stocks should be able to meet the needs of this year's driving season, at a time of ample crude oil availability, with strong imports. But, unplanned outages in the US logistics system and refining centres, or major disruptions in external gasoline supplies, could trigger price spikes that would, in turn, lead to frequently stronger crude oil prices, especially with the observed robust oil demand growth in China. (Author)

Gasoline Prices and Their Relationship to Drunk-Driving Crashes

OpenAIRE

Guangqing Chi; Xuan Zhou; Timothy McClure; Paul Gilbert; Arthur Cosby; Li Zhang; Angela Robertson; David Levinson

2010-01-01

This study investigates the relationship between changing gasoline prices and drunk-driving crashes. Specifically, we examine the effects of gasoline prices on drunk-driving crashes in Mississippi by age, gender, and race from 2004Ð2008, a period experiencing great fluctuation in gasoline prices. An exploratory visualization by graphs shows that higher gasoline prices are generally associated with fewer drunk-driving crashes. Higher gasoline prices depress drunk- driving crashes among younger...

Thermodynamic analysis of fuels in gas phase: ethanol, gasoline and ethanol - gasoline predicted by DFT method.

Science.gov (United States)

Neto, A F G; Lopes, F S; Carvalho, E V; Huda, M N; Neto, A M J C; Machado, N T

2015-10-01

This paper presents a theoretical study using density functional theory to calculate thermodynamics properties of major molecules compounds at gas phase of fuels like gasoline, ethanol, and gasoline-ethanol mixture in thermal equilibrium on temperature range up to 1500 K. We simulated a composition of gasoline mixture with ethanol for a thorough study of thermal energy, enthalpy, Gibbs free energy, entropy, heat capacity at constant pressure with respect to temperature in order to study the influence caused by ethanol as an additive to gasoline. We used semi-empirical computational methods as well in order to know the efficiency of other methods to simulate fuels through this methodology. In addition, the ethanol influence through the changes in percentage fractions of chemical energy released in combustion reaction and the variations on thermal properties for autoignition temperatures of fuels was analyzed. We verified how ethanol reduces the chemical energy released by gasoline combustion and how at low temperatures the gas phase fuels in thermal equilibrium have similar thermodynamic behavior. Theoretical results were compared with experimental data, when available, and showed agreement. Graphical Abstract Thermodynamic analysis of fuels in gas phase.

Improvements to the Composition of Fusel Oil and Analysis of the Effects of Fusel Oil–Gasoline Blends on a Spark-Ignited (SI Engine’s Performance and Emissions

Directory of Open Access Journals (Sweden)

Suleyman Simsek

2018-03-01

Full Text Available With the increase of energy needs and environmental pollution, alcohol-based alternative fuels are used in spark-ignited (SI engines. Fusel oil, which is a by-product obtained through distillation of ethanol, contains some valuable alcohols. As alcohols are high-octane, they have an important place among the alternative fuels. Fusel also takes its place among those alternatives as it is high-octane and low on exhaust emissions. In this research, the effects of using blends of unleaded gasoline and improved fusel oil on engine performance and exhaust emissions were analyzed experimentally. A four-stroke, single-cylinder, spark-ignited engine was used in the experiments. The tests were conducted at a fixed speed and under different loads. The test fuels were blended supplying with fusel oil at rates incremented by 10%, up to 50%. Under each load, the engine’s performance and emissions were measured. Throughout the experiments, it has been observed that engine torque and specific fuel consumption increases as the amount of fusel oil in the blend is increased. Nitrogen oxide (NOx, carbon monoxide (CO, and hydrocarbon (HC emissions are reduced as the amount of fusel oil in the blends is increased.

Estimation model for evaporative emissions from gasoline vehicles based on thermodynamics.

Science.gov (United States)

Hata, Hiroo; Yamada, Hiroyuki; Kokuryo, Kazuo; Okada, Megumi; Funakubo, Chikage; Tonokura, Kenichi

2018-03-15

In this study, we conducted seven-day diurnal breathing loss (DBL) tests on gasoline vehicles. We propose a model based on the theory of thermodynamics that can represent the experimental results of the current and previous studies. The experiments were performed using 14 physical parameters to determine the dependence of total emissions on temperature, fuel tank fill, and fuel vapor pressure. In most cases, total emissions after an apparent breakthrough were proportional to the difference between minimum and maximum environmental temperatures during the day, fuel tank empty space, and fuel vapor pressure. Volatile organic compounds (VOCs) were measured using a Gas Chromatography Mass Spectrometer and Flame Ionization Detector (GC-MS/FID) to determine the Ozone Formation Potential (OFP) of after-breakthrough gas emitted to the atmosphere. Using the experimental results, we constructed a thermodynamic model for estimating the amount of evaporative emissions after a fully saturated canister breakthrough occurred, and a comparison between the thermodynamic model and previous models was made. Finally, the total annual evaporative emissions and OFP in Japan were determined and compared by each model. Copyright © 2017 Elsevier B.V. All rights reserved.

26 CFR 48.4081-6 - Gasoline; gasohol.

Science.gov (United States)

2010-04-01

... 26 Internal Revenue 16 2010-04-01 2010-04-01 true Gasoline; gasohol. 48.4081-6 Section 48.4081-6... Fuel Taxable Fuel § 48.4081-6 Gasoline; gasohol. (a) Overview. This section provides rules for determining the applicability of reduced rates of tax on a removal or entry of gasohol or of gasoline used to...

Anticipation, Tax Avoidance, and the Price Elasticity of Gasoline Demand

OpenAIRE

Coglianese, John; Davis, Lucas W; Kilian, Lutz; Stock, James H

2015-01-01

Traditional least squares estimates of the responsiveness of gasoline consumption to changes in gasoline prices are biased toward zero, given the endogeneity of gasoline prices. A seemingly natural solution to this problem is to instrument for gasoline prices using gasoline taxes, but this approach tends to yield implausibly large price elasticities. We demonstrate that anticipatory behavior provides an important explanation for this result. We provide evidence that gasoline buyers increase g...

Persulfate injection into a gasoline source zone

Science.gov (United States)

Sra, Kanwartej S.; Thomson, Neil R.; Barker, Jim F.

2013-07-01

One pore volume of unactivated sodium persulfate was delivered into an emplaced gasoline residual source zone at CFB Borden. Concentrations of inorganic species (S2O82 -, SO42 -, Na+, dissolved inorganic carbon (DIC)) and selected gasoline compounds (benzene, toluene, ethylbenzene, xylenes, trimethylbenzenes and naphthalene) were monitored across a transect equipped with 90 multilevel sampling points for > 10 months post-injection. Mass loading (M˙) of compounds constructed from the transect data was used for assessment purposes. Breakthrough of inorganic species was observed when the injection slug crossed the monitoring transect. An increase in M indicated persulfate consumption during oxidation of gasoline compounds or degradation due to the interaction with aquifer materials. M increased by > 100% suggesting some mineralization of gasoline compounds during treatment. Mass loading for all the monitored gasoline compounds reduced by 46 to 86% as the inorganic slug crossed the monitoring transect. The cumulative mass discharge across the monitoring transect was 19 to 58% lower than that expected without persulfate injection. After the inorganic injection slug was flushed from the source zone a partial rebound (40 to 80% of baseline levels) of mass discharge of the monitored gasoline compounds was observed. The ensemble of data collected provides insight into the fate and transport of the injected persulfate solution, and the accompanying treatment of a gasoline the source zone.

Effectiveness of leaded petrol phase-out in Tianjin, China based on the aerosol lead concentration and isotope abundance ratio

International Nuclear Information System (INIS)

Wang Wan; Liu Xiande; Zhao Liwei; Guo, Dongfa; Tian Xiaodan; Adams, Freddy

2006-01-01

The phase-out of leaded petrol has been a measure widely used to reduce atmospheric lead pollution. Since the 1980s, China began to promote unleaded petrol. In order to assess the effectiveness of the measure an isotope fingerprint technique was applied for aerosol samples in the city of Tianjin. After dilute acid leaching, the lead concentration and isotope abundance ratios were determined for 123 samples collected in Tianjin during eight years (1994-2001). The 206 Pb / 207 Pb ratio was lower in summer, when coal combustion emission was low and vehicle exhaust became more important, indicating that the 206 Pb / 207 Pb ratio of leaded petrol in Tianjin is lower than that of aerosol samples. The 206 Pb / 207 Pb ratio gradually increased from 1994 to 2001, a trend that suggests that the contribution from vehicle exhaust was diminishing. Overall, the measurements matched well with national statistical data of leaded and unleaded petrol production. After the nationwide switch to unleaded gasoline, comprehensive control measures are urgently needed to reduce air lead pollution in China, as aerosol lead reduced slightly but remains at a relatively high level

Recent Trends in Atmospheric Lead Levels at an Urban-Industrial District of Metropolitan Lisbon, Portugal, through PIXE Analysis of Air-Particulate Matter

International Nuclear Information System (INIS)

Freitas, M. Carmo; Reis, Miguel A.; Pacheco, Adriano M.G.

2003-01-01

Despite a steep decline in primary, traffic-related loads, lead in the environment is still much of an issue. Current atmospheric levels may be unmistakably reflecting the widespread use of cleaner fuels, yet decades of uncontrolled emissions from mobile sources have made lead to pervade every terrestrial (and aquatic) ecosystem, from where it keeps re-entering the lower troposphere, at least in terms of local circulation. The continuing surveillance of airborne-lead levels is thus necessary, not just for ensuring a strict compliance with regulatory decisions, but also for assisting in the implementation of remediation and/or rehabilitation policies. In Portugal, unleaded gasoline was made generally available in 1990, yet both leaded and lead-free varieties were commercialised until 1998. After that, all vehicles were compelled to use unleaded gasoline. Even though it is certainly too early for a full trend analysis of airborne levels and their response to the ban on lead, concentrations in ambient air over an important urban-industrial corridor within the Lisbon metropolitan area show a steady, sharp decrease through the last decade. Since 2000, airborne-lead data seems somewhat stabilised and, as far as busy conurbations are concerned, roughly within the values that were usually observed in the rural hinterland back in the mid 1990s

Survey of benzene and aromatics in Canadian Gasoline - 1994

International Nuclear Information System (INIS)

Tushingham, M.

1996-01-01

A comprehensive database of the benzene and aromatics levels of gasoline produced in or imported into Canada during 1994, was presented. Environment Canada conducted a survey that requested refineries and importers to report quarterly on benzene and aromatics levels in gasoline. Benzene, which has been declared toxic by the Canadian Environmental Protection Act, is found in gasoline and is formed during the combustion of the aromatic components of gasoline. It was shown that benzene and aromatics levels differ regionally and seasonally. There are also variations in benzene levels between batches of gasoline produced at any one refinery. This report listed the responses to the benzene/aromatics survey. It also described the analytical procedures used to measure benzene and aromatics levels in gasoline, and provided guidelines for reporting gasoline benzene and total aromatics data. 7 tabs., 21 figs

New evidence on the asymmetry in gasoline price: volatility versus margin?

International Nuclear Information System (INIS)

Abosedra, S.; Radchenko, S.

2006-01-01

This paper examines recent evidence on the role that gasoline margins and volatility play in the asymmetric response of gasoline prices to changes in oil prices at different stages of distribution process. In a regression model with margins, we find that margins are statistically significant in explaining asymmetry between crude oil and spot gasoline prices, spot gasoline prices and wholesale gasoline prices, and wholesale gasoline prices and retail prices. In a regression model with input volatility, we find evidence that volatility is responsible for asymmetry between wholesale gasoline prices and retail gasoline prices. When both, gasoline margins and gasoline volatility are included in the regression, we find evidence supporting margins, the search theory, volatility, the oligopolistic coordination theory and an explanation of asymmetry. (author)

Gasoline sales post minimal gain in 1986

Energy Technology Data Exchange (ETDEWEB)

1987-06-22

Despite the continuing emphasis on conservation and the growing trend to smaller sized automobiles, sales of motor gasoline across Canada posted a gain of 0.4% in 1986. Figures are included in this survey for Canadian motor gasoline sales categorized by province, type of gasoline, and months of 1985 and 1986. Sales of refiners' diesel fuel oil are also categorized by province and by months of 1985 and 1986. Motor gasoline disposition for 1983-1986 is categorized into retail pump sales, road and urban transport, agriculture, public administration, and commercial and other institutional markets. Also included are figures for refiners' propane sales for 1983-1986 by province.

Gasoline Prices, Transport Costs, and the U.S. Business Cycles

OpenAIRE

Hakan Yilmazkuday

2014-01-01

The e¡èects of gasoline prices on the U.S. business cycles are investigated. In order to distinguish between gasoline supply and gasoline demand shocks, the price of gasoline is endogenously determined through a transportation sector that uses gasoline as an input of production. The model is estimated for the U.S. economy using five macroeconomic time series, including data on transport costs and gasoline prices. The results show that although standard shocks in the literature (e.g., technolo...

Tiered gasoline pricing: A personal carbon trading perspective

International Nuclear Information System (INIS)

Li, Yao; Fan, Jin; Zhao, Dingtao; Wu, Yanrui; Li, Jun

2016-01-01

This paper proffers a tiered gasoline pricing method from a personal carbon trading perspective. An optimization model of personal carbon trading is proposed, and then, an equilibrium carbon price is derived according to the market clearing condition. Based on the derived equilibrium carbon price, this paper proposes a calculation method of tiered gasoline pricing. Then, sensitivity analyses and consumers' surplus analyses are conducted. It can be shown that a rise in gasoline price or a more generous allowance allocation would incur a decrease in the equilibrium carbon price, making the first tiered price higher, but the second tiered price lower. It is further verified that the proposed tiered pricing method is progressive because it would relieve the pressure of the low-income groups who consume less gasoline while imposing a greater burden on the high-income groups who consume more gasoline. Based on these results, implications, limitations and suggestions for future studies are provided. - Highlights: • Tiered gasoline pricing is calculated from the perspective of PCT. • Consumers would be burdened with different actual gasoline costs. • A specific example is provided to illustrate the calculation of TGP. • The tiered pricing mechanism is a progressive system.

Persulfate injection into a gasoline source zone.

Science.gov (United States)

Sra, Kanwartej S; Thomson, Neil R; Barker, Jim F

2013-07-01

One pore volume of unactivated sodium persulfate was delivered into an emplaced gasoline residual source zone at CFB Borden. Concentrations of inorganic species (S2O8(2-), SO4(2-), Na(+), dissolved inorganic carbon (DIC)) and selected gasoline compounds (benzene, toluene, ethylbenzene, xylenes, trimethylbenzenes and naphthalene) were monitored across a transect equipped with 90 multilevel sampling points for >10months post-injection. Mass loading (M˙) of compounds constructed from the transect data was used for assessment purposes. Breakthrough of inorganic species was observed when the injection slug crossed the monitoring transect. An increase in [Formula: see text] indicated persulfate consumption during oxidation of gasoline compounds or degradation due to the interaction with aquifer materials. M˙DIC increased by >100% suggesting some mineralization of gasoline compounds during treatment. Mass loading for all the monitored gasoline compounds reduced by 46 to 86% as the inorganic slug crossed the monitoring transect. The cumulative mass discharge across the monitoring transect was 19 to 58% lower than that expected without persulfate injection. After the inorganic injection slug was flushed from the source zone a partial rebound (40 to 80% of baseline levels) of mass discharge of the monitored gasoline compounds was observed. The ensemble of data collected provides insight into the fate and transport of the injected persulfate solution, and the accompanying treatment of a gasoline the source zone. Copyright © 2013 Elsevier B.V. All rights reserved.

30 CFR 57.4461 - Gasoline use restrictions underground.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Gasoline use restrictions underground. 57.4461... Prevention and Control Flammable and Combustible Liquids and Gases § 57.4461 Gasoline use restrictions underground. If gasoline is used underground to power internal combustion engines— (a) The mine shall be...

Ambitious coal to gasoline plan

Energy Technology Data Exchange (ETDEWEB)

Taffe, P

1979-06-20

A design study carried out by Badger Energy concludes that the first US commercial gasoline from coal facility could be completed in eight years. The cost of gasoline would be 1.09 US dollars/gal. in 1990 with coal at 25 US dollars/ton. The process involves oxygen-blown coal gasification, conversion to methanol by the Mobil process, gas fractionation and HF alkylation.

Mechanistic considerations in benzene physiological model development.

OpenAIRE

Medinsky, M A; Kenyon, E M; Seaton, M J; Schlosser, P M

1996-01-01

Benzene, an important industrial solvent, is also present in unleaded gasoline and cigarette smoke. The hematotoxic effects of benzene in humans are well documented and include aplastic anemia, pancytopenia, and acute myelogenous leukemia. However, the risks of leukemia at low exposure concentrations have not been established. A combination of metabolites (hydroquinone and phenol, for example) may be necessary to duplicate the hematotoxic effect of benzene, perhaps due in part to the synergis...

Research of combustion in older generation spark-ignition engines in the condition of use leaded and unleaded petrol

Directory of Open Access Journals (Sweden)

Bulatović Željko M.

2014-01-01

Full Text Available This paper analyzes the potential problems in the exploitation of the older generation of spark-ignition engines with higher octane number of petrol (unleaded petrol BMB 95 than required (leaded petrol MB 86. Within the experimental tests on two different engines (STEYR-PUCH model 712 and GAZ 41 by applying piezoelectric pressure sensors integrated with the engine spark plugs, acceleration sensors (accelerometers and special electronic block connected with distributor, show that the cumulative first and second theoretical phase of combustion when petrol of higher octane number (BMB 95 is used lasts slightly longer than when the low-octane petrol MB 86 is used. For new petrol (BMB 95 higher optimal angles of pre-ignition have been determined by which better performances of the engine are achieved without a danger of the combustion with detonation (also called knocking.

40 CFR 80.375 - What requirements apply to California gasoline?

Science.gov (United States)

2010-07-01

... gasoline? 80.375 Section 80.375 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Exemptions § 80.375 What requirements apply to California gasoline? (a) Definition. For purposes of this subpart California gasoline...

40 CFR 80.1236 - What requirements apply to California gasoline?

Science.gov (United States)

2010-07-01

... gasoline? 80.1236 Section 80.1236 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Gasoline Benzene Requirements § 80.1236 What requirements apply to California gasoline? (a) Definition. For purposes of this subpart...

40 CFR 80.845 - What requirements apply to California gasoline?

Science.gov (United States)

2010-07-01

... gasoline? 80.845 Section 80.845 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Toxics Gasoline Toxics Performance Requirements § 80.845 What requirements apply to California gasoline? (a) Definition. For purposes of this...

46 CFR 56.50-70 - Gasoline fuel systems.

Science.gov (United States)

2010-10-01

... 46 Shipping 2 2010-10-01 2010-10-01 false Gasoline fuel systems. 56.50-70 Section 56.50-70... APPURTENANCES Design Requirements Pertaining to Specific Systems § 56.50-70 Gasoline fuel systems. (a) Material.... Outlets in fuel lines for drawing gasoline for any purpose are prohibited. Valved openings in the bottom...

Understanding gasoline pricing in Canada

International Nuclear Information System (INIS)

Anon.

2001-01-01

Pricing policies for gasoline by Canadian oil companies are discussed. An attempt is made to demonstrate that competition between oil companies is extremely keen, and markups are so small that to stay in business, retail outlets have to sell huge volumes and sell non-fuel products, as a means to increase revenues and margins. An explanation is provided for why gasoline prices move in unison, and why what appears to the public as collusion and gouging is, in fact, the result of retail dealers attempting to stay in business. The high prices are attributed mainly to taxes by municipalities, the provinces and the federal government; taxes are said to account for 40 to 50 per cent of the pump price. The cost of crude makes up another 35 to 45 per cent, refining adds 10 to 15 per cent, with the remaining 5 to 10 per cent representing retail costs. (Taxes in the United States average 20 to 30 per cent). Over the longer term, gasoline prices consistently reflect the cost of crude oil, dominated by the OPEC countries which supply about 41 per cent of daily world production. Another factor is the rise of global and regional commodity markets for refined products such as gasoline. Commodity traders buy wholesale gasoline cheaply whenever it is in oversupply, and sell it for a profit into markets where the demand is greater. While this is claimed to ensure competitive prices in all markets, the practice can also trigger abrupt changes in regional markets

The elasticity of demand for gasoline in China

International Nuclear Information System (INIS)

Lin, C.-Y. Cynthia; Zeng, Jieyin

2013-01-01

This paper estimates the price and income elasticities of demand for gasoline in China. Our estimates of the intermediate-run price elasticity of gasoline demand range between −0.497 and −0.196, and our estimates of the intermediate-run income elasticity of gasoline demand range between 1.01 and 1.05. We also extend previous studies to estimate the vehicle miles traveled (VMT) elasticity and obtain a range from −0.882 to −0.579. - highlights: • The price elasticity of demand for gasoline in China is between −0.497 and −0.196. • The income elasticity of demand for gasoline in China is between 1.01 and 1.05. • The price elasticity of demand for VMT in China is between −0.882 and −0.579

Evaluation of Motor Gasoline Stability

Science.gov (United States)

1990-12-01

CAMPINNE AIR POLLUTION CONTROL I LABORATOIRE MECANIQUE TRANSPORT 2565 PLYMOUTH ROAD AVENUE DE LA RENAISSANCE, 3D ANN ARBOR MI 48105 B-1040 BRUSSELS 5...CUARTEL GENERAL DEL EJERCITO ATTN: MR K LAURINSEN ATTN: MAJ M ENGO NOGUES GADHOLTVEJ 11 DIVISION DE LOGISTICA (DIAM/LABCAMVE) DK-9900 FREDERIKSHAVN...Gum for Typical Civilian Gasolines Transported by CEPS and F-46 Gasolines Stored by CEPS ...................................... 47 B. Potential Gum

46 CFR 58.50-5 - Gasoline fuel tanks.

Science.gov (United States)

2010-10-01

... 46 Shipping 2 2010-10-01 2010-10-01 false Gasoline fuel tanks. 58.50-5 Section 58.50-5 Shipping... AND RELATED SYSTEMS Independent Fuel Tanks § 58.50-5 Gasoline fuel tanks. (a) Construction—(1) Shape...) Installation. (1) Gasoline fuel tanks used for propulsion shall be located in water-tight compartments separate...

Gasoline taxes or efficiency standards? A heterogeneous household demand analysis

International Nuclear Information System (INIS)

Liu, Weiwei

2015-01-01

Using detailed consumer expenditure survey data and a flexible semiparametric dynamic demand model, this paper estimates the price elasticity and fuel efficiency elasticity of gasoline demand at the household level. The goal is to assess the effectiveness of gasoline taxes and vehicle fuel efficiency standards on fuel consumption. The results reveal substantial interaction between vehicle fuel efficiency and the price elasticity of gasoline demand: the improvement of vehicle fuel efficiency leads to lower price elasticity and weakens consumers’ sensitivity to gasoline price changes. The offsetting effect also differs across households due to demographic heterogeneity. These findings imply that when gasoline taxes are in place, tightening efficiency standards will partially offset the strength of taxes on reducing fuel consumption. - Highlights: • Model household gasoline demand using a semiparametric approach. • Estimate heterogeneous price elasticity and fuel efficiency elasticity. • Assess the effectiveness of gasoline taxes and efficiency standards. • Efficiency standards offset the impact of gasoline taxes on fuel consumption. • The offsetting effect differs by household demographics

Inventories and upstream gasoline price dynamics

NARCIS (Netherlands)

Kuper, Gerard H.

This paper sheds new light on the asymmetric dynamics in upstream U.S. gasoline prices. The model is based on Pindyck's inventory model of commodity price dynamics. We show that asymmetry in gasoline price dynamics is caused by changes in the net marginal convenience yield: higher costs of marketing

Environment and Energy. Phase out of gasoline

International Nuclear Information System (INIS)

Magaudda, G.

2000-01-01

The european recommendation 98/07/EEC gives the technical specification of automotive fuels quality, gasoline and diesel fuel and forbid for member countries the commercialization of lead gasoline from 01/01/2001 [it

Projected reformulated gasoline and AFV use in California

International Nuclear Information System (INIS)

Bemis, G.R.

1995-01-01

In the spring to summer of 1996, California will switch from conventional and oxygenated gasolines to reformulated gasoline. This gasoline will be a designer fuel, and generally not available from sources outside California, since California's fuel specifications then will be unique. Thus, it will be important for California refiners to be able to meet the California reformulated gasoline (Cal-RFG) demand. California refiners are investing over $4 billion to upgrade their facilities for Cal-RFG. This represents approximately 40% of the total cost of making Cal-RFG, and is expected to cost 5--15 cents/gallon more than conventional gasoline to produce. Starting in the year 2000, EPA will require use of a similar fuel in seven geographical areas outside of California. The discussion below focuses on the supply, demand and price projections for Cal-RFG

Laminar burning velocities at elevated pressures for gasoline and gasoline surrogates associated with RON

KAUST Repository

Mannaa, Ossama

2015-06-01

The development and validation of a new gasoline surrogate using laminar flame speed as a target parameter is presented. Laminar burning velocities were measured using a constant-volume spherical vessel with ignition at the center of the vessel. Tested fuels included iso-octane, n-heptane, toluene, various mixtures of primary reference fuels (PRFs) and toluene reference fuels (TRFs) and three gasoline fuels of 70, 85 and 95 RON (FACE J, C and F) at the initial temperature of 358K and pressures up to 0.6MPa in the equivalence ratio ranging from 0.8 to 1.6. Normalized laminar burning velocity data were mapped into a tri-component mixture space at different experimental conditions to allocate different gasoline surrogates for different gasoline fuels, having RON of 70, 85 and 95. The surrogates of TRF-70-4 (17.94% iso-C8H18 +42.06% n-C7H16 +40% C7H8), TRF-85-1 (77.4% iso-C8H18 +17.6% n-C7H16 +5% C7H8), and TRF-95-1 (88.47% iso-C8H18 +6.53% n-C7H16 +5% C7H8) of RON 70, 85 and 95, respectively, are shown to successfully emulate the burning rate characteristics of the gasoline fuels associated with these RONs under the various experimental conditions investigated. An empirical correlation was derived to obtain laminar burning velocities at pressures that are experimentally unattainable as high as 3.0MPa. Laminar burning velocities were comparable to the simulated values for lean and stoichiometric flames but they were relatively higher than the simulated values for rich flames. A flame instability assessment was conducted by determining Markstein length, critical Pecklet number, and critical Karlovitz number at the onset of flame instability.

Application of Biologically Based Lumping To Investigate the Toxicokinetic Interactions of a Complex Gasoline Mixture.

Science.gov (United States)

Jasper, Micah N; Martin, Sheppard A; Oshiro, Wendy M; Ford, Jermaine; Bushnell, Philip J; El-Masri, Hisham

2016-03-15

People are often exposed to complex mixtures of environmental chemicals such as gasoline, tobacco smoke, water contaminants, or food additives. We developed an approach that applies chemical lumping methods to complex mixtures, in this case gasoline, based on biologically relevant parameters used in physiologically based pharmacokinetic (PBPK) modeling. Inhalation exposures were performed with rats to evaluate the performance of our PBPK model and chemical lumping method. There were 109 chemicals identified and quantified in the vapor in the chamber. The time-course toxicokinetic profiles of 10 target chemicals were also determined from blood samples collected during and following the in vivo experiments. A general PBPK model was used to compare the experimental data to the simulated values of blood concentration for 10 target chemicals with various numbers of lumps, iteratively increasing from 0 to 99. Large reductions in simulation error were gained by incorporating enzymatic chemical interactions, in comparison to simulating the individual chemicals separately. The error was further reduced by lumping the 99 nontarget chemicals. The same biologically based lumping approach can be used to simplify any complex mixture with tens, hundreds, or thousands of constituents.

Hydrocarbon control strategies for gasoline marketing operations

Energy Technology Data Exchange (ETDEWEB)

Norton, R.L.; Sakaida, R.R.; Yamada, M.M.

1978-05-01

This informational document provides basic and current descriptions of gasoline marketing operations and methods that are available to control hydrocarbon emissions from these operations. The three types of facilities that are described are terminals, bulk plants, and service stations. Operational and business trends are also discussed. The potential emissions from typical facilities, including transport trucks, are given. The operations which lead to emissions from these facilities include (1) gasoline storage, (2) gasoline loading at terminals and bulk plants, (3) gasoline delivery to bulk plants and service stations, and (4) the refueling of vehicles at service stations. Available and possible methods for controlling emissions are described with their estimated control efficiencies and costs. This report also includes a bibliography of references cited in the text, and supplementary sources of information.

TEMPERATURE INFLUENCE ON PHASE STABILITY OF ETHANOL-GASOLINE MIXTURES

Directory of Open Access Journals (Sweden)

Valerian Cerempei

2011-06-01

Full Text Available The article investigates phase stability of ethanol-gasoline mixtures depending on their composition, water concentration in ethanol and ethanol-gasoline mixture and temperature. There have been determined the perfect functioning conditions of spark ignition engines fueled with ethanol-gasoline mixtures.

Transport gasoline demand in Canada

International Nuclear Information System (INIS)

Eltony, M.N.

1993-01-01

This paper provides an estimate of household gasoline demand in Canada by applying a detailed model to pool time-series (1969-1988) and cross-sectional provincial data. The model recognises three major behavioural changes that households can make in response to gasoline price changes: drive fewer miles, purchase fewer cars, and buy more fuel-efficient vehicles. In the model, fuel economy is treated in considerable detail. The two components of the fuel economy of new cars sold-the technical fuel efficiency of various classes of cars and the distribution of new car sales according to their interior volume rather than their weight - are estimated as functions of economic variables. Car manufacturers are assumed to improve the technical fuel economy according to their expectation of consumer's response to future changes in gasoline prices and general economic conditions. (author)

40 CFR 80.66 - Calculation of reformulated gasoline properties.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Calculation of reformulated gasoline... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Reformulated Gasoline § 80.66 Calculation of reformulated gasoline properties. (a) All volume measurements required by these regulations shall be...

Hydroprocessing to produce reformulated Gasolines. The ISAL{sup TM} process

Energy Technology Data Exchange (ETDEWEB)

Antos, G.J. [UOP, Des Plaines, IL (United States); Solari, B.; Monque, R. [Intevep S.A., Caracas (Venezuela)

1997-07-01

As a result of forthcoming environmental regulations, such as those established in the U.S. Clean Air Act, petroleum refiners around the world are searching for low-investment solutions to accomplish hydroprocessing requirements. These regulations are expressed in the Complex Model, which brings together sulfur content, olefin content, vapor pressure, and boiling range in an interactive fashion. Processes need to successfully reduce these pollutants and still maintain high yields of high octane-product. Because FCC naphta accounts for 90 % of the sulfur and olefins in the entire gasoline pool, hydrotreating this material is an attractive process alternative, provided that octane losses are minimized. The ISAL{sup TM} process, jointly developed by INTEVEP, S.A., and UOP, is a selective hydrotreating process to improve naphta quality by reducing sulfur, nitrogen, and olefins without octane loss. The paper discusses aspects of the process and catalyst chemistries leading to these desirable results. 6 refs.

The effects of hydrous ethanol gasoline on combustion and emission characteristics of a port injection gasoline engine

Directory of Open Access Journals (Sweden)

Xiaochen Wang

2015-09-01

Full Text Available Comparative experiments were conducted on a port injection gasoline engine fueled with hydrous ethanol gasoline (E10W, ethanol gasoline (E10 and pure gasoline (E0. The effects of the engine loads and the additions of ethanol and water on combustion and emission characteristics were analyzed deeply. According to the experimental results, compared with E0, E10W showed higher peak in-cylinder pressure at high load. Increases in peak heat release rates were observed for E10W fuel at all the operating conditions. The usage of E10W increased NOX emissions at a wide load range. However, at low load conditions, E10W reduced HC, CO and CO2 emissions significantly. E10W also produced slightly less HC and CO emissions, while CO2 emissions were not significantly affected at higher operating points. Compared with E10, E10W showed higher peak in-cylinder pressures and peak heat release rates at the tested operating conditions. In addition, decreases in NOX emissions were observed for E10W from 5 Nm to 100 Nm, while HC, CO and CO2 emissions were slightly higher at low and medium load conditions. From the results, it can be concluded that E10W fuel can be regarded as a potential alternative fuel for gasoline engine applications.

Epidemic gasoline exposures following Hurricane Sandy.

Science.gov (United States)

Kim, Hong K; Takematsu, Mai; Biary, Rana; Williams, Nicholas; Hoffman, Robert S; Smith, Silas W

2013-12-01

Major adverse climatic events (MACEs) in heavily-populated areas can inflict severe damage to infrastructure, disrupting essential municipal and commercial services. Compromised health care delivery systems and limited utilities such as electricity, heating, potable water, sanitation, and housing, place populations in disaster areas at risk of toxic exposures. Hurricane Sandy made landfall on October 29, 2012 and caused severe infrastructure damage in heavily-populated areas. The prolonged electrical outage and damage to oil refineries caused a gasoline shortage and rationing unseen in the USA since the 1970s. This study explored gasoline exposures and clinical outcomes in the aftermath of Hurricane Sandy. Prospectively collected, regional poison control center (PCC) data regarding gasoline exposure cases from October 29, 2012 (hurricane landfall) through November 28, 2012 were reviewed and compared to the previous four years. The trends of gasoline exposures, exposure type, severity of clinical outcome, and hospital referral rates were assessed. Two-hundred and eighty-three gasoline exposures were identified, representing an 18 to 283-fold increase over the previous four years. The leading exposure route was siphoning (53.4%). Men comprised 83.0% of exposures; 91.9% were older than 20 years of age. Of 273 home-based calls, 88.7% were managed on site. Asymptomatic exposures occurred in 61.5% of the cases. However, minor and moderate toxic effects occurred in 12.4% and 3.5% of cases, respectively. Gastrointestinal (24.4%) and pulmonary (8.4%) symptoms predominated. No major outcomes or deaths were reported. Hurricane Sandy significantly increased gasoline exposures. While the majority of exposures were managed at home with minimum clinical toxicity, some patients experienced more severe symptoms. Disaster plans should incorporate public health messaging and regional PCCs for public health promotion and toxicological surveillance.

Development of synthetic gasoline production process

Energy Technology Data Exchange (ETDEWEB)

Imai, T; Fujita, H; Yamada, K; Suzuki, T; Tsuchida, Y

1986-01-01

As oil deposits are limited, it is very important to develop techniques for manufacturing petroleum alternatives as substitute energy sources to brighten the outlook for the future. The Research Association for Petroleum Alternatives Development (RAPAD) in Japan is engaged in the research and development of production techniques for light hydrocarbon oils such as gasoline, kerosene, and light oil from synthesis gas (CO, H/sub 2/) obtained from the raw materials of natural gas, coal, etc. Regarding the MTG process of synthesizing gasoline via methanol from synthesis gas and the STG process of directly synthesizing gasoline from synthesis gas, Cosmo Oil Co., Ltd. and Mitsubishi Heavy Industries, Ltd., members of RAPAD, have sought jointly to develop catalysts and processes. As a result of this co-operation, the authors have recently succeeded in developing a new catalyst with a long life span capable of providing a high yield and high selectivity. Additionally, the authors are currently on the verge of putting into effect a unique two-step STG process of synthesizing high octane gasoline via dimethyl ether, referred to as the AMSTG process.

40 CFR 80.81 - Enforcement exemptions for California gasoline.

Science.gov (United States)

2010-07-01

... gasoline. 80.81 Section 80.81 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Reformulated Gasoline § 80.81 Enforcement exemptions for California gasoline. (a)(1) The requirements of subparts D, E, F, and J of this part are...

Competition in the retail gasoline industry

Science.gov (United States)

Brewer, Jedidiah

2007-05-01

This dissertation examines competition in the retail gasoline industry. The first chapter highlights the importance of gasoline in modern society, introduces my work, and places it in the context of the existing academic literature. The second chapter details the institutional structure and profitability of the industry. The vast majority of retail gasoline stations are not directly owned and operated by major oil companies. Instead, most stations are set up under other contractual relationships: lessee-dealer, open-dealer, jobber-owned-and-operated, and independent. Gasoline retailers make relatively low profits, as is the case in many other retail industries, and are substantially less profitable than major oil companies. Gas stations also make less money when retail prices are climbing than when they are falling. As prices rise, total station profits are near zero or negative. When retail prices are constant or falling, retailers can make positive profits. The third chapter describes the entry of big-box stores into the retail gasoline industry over the last decade. The growth of such large retailers, in all markets, has led to a great deal of controversy as smaller competitors with long-term ties to the local community have become less common. I estimate the price impact that big-box stores have on traditional gasoline retailers using cross-sectional data in two geographically diverse cities. I also examine changes in pricing following the entry of The Home Depot into a local retail gasoline market. The results show that big-box stores place statistically and economically significant downward pressure on the prices of nearby gas stations, offering a measure of the impact of the entry of a big-box store. Chapter 4 examines the nature of price competition in markets where some competing retailers sell the same brand. The price effect of having more retailers selling the same brand is theoretically unclear. High brand diversity could give individual retailers

Recent Trends and Patterns of Gasoline Consumption in Nigeria ...

African Journals Online (AJOL)

This article analyses recent trends and spatial patterns of gasoline consumption in Nigeria. In particular, it shows that the volume of gasoline consumption in the country fluctuates with changes in economic growth. The pattern of distribution of gasoline consumption indicates that the largest consumption centres are in the ...

Degradation of tetraethyllead during the degradation of leaded gasoline hydrocarbons in soil

International Nuclear Information System (INIS)

Mulroy, P.T.; Ou, L.T.

1998-01-01

For over 50 years, leaded gasoline was the only fuel for automobiles, and tetraethyllead (TEL) was the major octane number enhancer used in leaded gasoline. Ample information is available on the fate and remediation of gasoline hydrocarbons in contaminated subsoils and groundwater. However, little is known regarding the fate of TEL in leaded gasoline-contaminated subsoils and groundwater. In soil not contaminated with gasoline, TEL was rapidly degraded and completely disappeared in 14 d. In gasoline-contaminated soil, TEL degradation was slower; after 77 d, 4 to 17% of the applied TEL still remained in the contaminated soil. Disappearance of total petroleum hydrocarbons (TPH) was initially rapid but slowed appreciably after 7 to 14 d. As a result, after 77 d, 33 to 51% of the applied gasoline still remained in soil. The retardation of TEL degradation in leaded gasoline-contaminated soil is due to the presence of gasoline hydrocarbons. As long as gasoline hydrocarbons remain in soil, TEL may also remain in soil, most likely in the gasoline hydrocarbon phase

Stabilization of gasoline from shale

Energy Technology Data Exchange (ETDEWEB)

Benedetti, L

1929-03-14

A process is described of stabilizing gasoline from shale, consisting in treating by agitating the gasoline freshly distilled from shale oil with 1.5 percent of its weight of sulfuric acid diluted to more than 10 times its volume, after which separating the pyridine, then treating by agitating with sulfuric acid which treatment separates the unsaturated hydrocarbons and finally treating by agitating with 1.5 percent of its weight of saturated caustic soda solution and washing with water.

Identification of V-type nerve agents in vapor samples using a field-portable capillary gas chromatography/membrane-interfaced electron ionization quadrupole mass spectrometry instrument with Tri-Bed concentrator and fluoridating conversion tube.

Science.gov (United States)

Ohrui, Y; Nagoya, T; Kurimata, N; Sodeyama, M; Seto, Y

2017-07-01

A field-portable gas chromatography-mass spectrometry (GC-MS) system (Hapsite ER) was evaluated for the detection of nonvolatile V-type nerve agents (VX and Russian VX (RVX)) in the vapor phase. The Hapsite ER system consists of a Tri-Bed concentrator gas sampler, a nonpolar low thermal-mass capillary GC column and a hydrophobic membrane-interfaced electron ionization quadrupole mass spectrometer evacuated by a non-evaporative getter pump. The GC-MS system was attached to a VX-G fluoridating conversion tube containing silver nitrate and potassium fluoride. Sample vapors of VX and RVX were converted into O-ethyl methylphosphonofluoridate (EtGB) and O-isobutyl methylphosphonofluoridate (iBuGB), respectively. These fluoridated derivatives were detected within 10 min. No compounds were detected when the VX and RVX samples were analyzed without the conversion tube. A vapor sample of tabun (GA) was analyzed, in which GA and O-ethyl N,N-dimethylphosphoramidofluoridate were detected. The molar recovery percentages of EtGB and iBuGB from VX and RVX vapors varied from 0.3 to 17%, which was attributed to variations in the vaporization efficiency of the glass vapor container. The conversion efficiencies of the VX-G conversion tube for VX and RVX to their phosphonate derivatives were estimated to be 40%. VX and RVX vapors were detected at concentrations as low as 0.3 mg m -3 . Gasoline vapor was found to interfere with the analyses of VX and RVX. In the presence of 160 mg m -3 gasoline, the detection limits of VX and RVX vapor were increased to 20 mg m -3 . Copyright © 2017 John Wiley & Sons, Ltd. Copyright © 2017 John Wiley & Sons, Ltd.

High octane gasoline components from catalytic cracking gasoline, propylene, and isobutane by disproportionation, clevage and alkylation

Energy Technology Data Exchange (ETDEWEB)

Banks, R.

1980-07-08

A process is described for producing high octane value gasoline which comprises in a disproportionation zone subjecting propylene and a mixture of propylene and ethylene obtained as hereinafter delineated to disproportionation conditions to produce a stream containing ethylene and a stream containing butenes, passing the ethylene-containing stream from said disproportionation zone together with a catalytic cracking gasoline to a cleavage zone under disproportionation conditions and subjecting the mixture of hydrocarbons therin to cleavage to produce said mixture of propylene and ethylene, a C/sub 5//sup +/ gasoline-containing product and butenes and wherein the butenes obtained in the overall operation of the disproportionation zone and the cleavage zone are passed to an alkylation zone wherein said butenes are used to alkylate an isoparaffin to produce additional high octane value product.

Performance of a hybrid hydrogen–gasoline engine under various operating conditions

International Nuclear Information System (INIS)

Ji, Changwei; Wang, Shuofeng; Zhang, Bo

2012-01-01

Highlights: ► We develop a combustion strategy for the hybrid hydrogen–gasoline engine (HHGE). ► The HHGE produced much lower HC and CO emissions at cold start. ► The H 2 -gasoline blends were effective for improving engine performance at idle and part loads. ► The HHGE could run smoothly at lean conditions. -- Abstract: This paper proposed a new combustion strategy for the spark-ignited (SI) engines. A gasoline engine was converted into a hybrid hydrogen–gasoline engine (HHGE) by adding a hydrogen injection system and a hybrid electronic control unit. Different from the conventional gasoline and hydrogen–enriched gasoline engines, the HHGE is fueled with the pure hydrogen at cold start to produce almost zero emissions, with the hydrogen–gasoline blends at idle and part loads to further improve thermal efficiency and reduce emissions, and with the pure gasoline to ensure the engine power output at high loads. Because the HHGE is fueled with the pure gasoline at high loads and speeds, experiments are only conducted at clod start, idle and part load conditions. Since lean combustion avails the further improvement of the engine performance, the HHGE was fueled with the lean mixtures in all tests. The experimental results showed that the hybrid hydrogen–gasoline engine was started successfully with the pure hydrogen, which produced 94.7% and 99.5% reductions in HC and CO emissions within 100 s from the onset of the cold start, compared with the original gasoline engine. At an excess air ratio of 1.37 and idle conditions, indicated thermal efficiency of the 3% hydrogen–blended gasoline engine was 46.3% higher than that of the original engine. Moreover, the engine cyclic variation was eased, combustion duration was shortened and HC, CO and NOx emissions were effectively reduced for the hybrid hydrogen–gasoline engines.

Gasoline tax best path to reduced emissions

International Nuclear Information System (INIS)

Brinner, R.E.

1991-01-01

Lowering gasoline consumption is the quickest way to increase energy security and reduce emissions. Three policy initiatives designed to meet such goals are current contenders in Washington, DC: higher gasoline taxes; higher CAFE (Corporate Average Fuel Economy) standards; and an auto registration fee scheme with gas-guzzler taxes and gas-sipper subsidies. Any of these options will give us a more fuel-efficient auto fleet. The author feels, however, the gasoline tax holds several advantages: it is fair, flexible, smart, and honest. But he notes that he is proposing a substantial increase in the federal gasoline tax. Real commitment would translate into an additional 50 cents a gallon at the pump. While the concept of increasing taxes at the federal level is unpopular with voters and, thus, with elected officials, there are attractive ways to recycle the $50 billion in annual revenues that higher gas taxes would produce

Combustion characteristics of a gasoline engine with independent intake port injection and direct injection systems for n-butanol and gasoline

International Nuclear Information System (INIS)

He, Bang-Quan; Chen, Xu; Lin, Chang-Lin; Zhao, Hua

2016-01-01

Highlights: • Different injection approaches for n-butanol and gasoline affect combustion events. • High n-butanol percentage in the total energy of fuels improves combustion stability. • N-butanol promotes ignition and shortens combustion duration. • Lean burn increases indicated mean effective pressure at fixed total energy of fuels. • Different fuel injection methods slightly affect indicated mean effective pressure. - Abstract: N-butanol, as a sustainable biofuel, is usually used as a blend with gasoline in spark ignition engines. In this study, the combustion characteristics were investigated on a four-cylinder spark ignition gasoline engine with independent port fuel injection and direct injection systems for n-butanol and gasoline in different operating conditions. The results show that in the case of port fuel injection of n-butanol with direct injection gasoline at a given total energy released in a cycle, indicated mean effective pressure is slightly affected by spark timing at stoichiometry while it changes much more with delayed spark timing in lean burn conditions and is much higher in lean burn conditions compared to stoichiometry at given spark timings. With the increase of n-butanol percentage in a fixed total energy released in a cycle at given spark timings, ignition timing advances, combustion duration shortens, indicated mean effective pressure and indicated thermal efficiency increase. For the cases of port fuel injection of n-butanol with direction injection gasoline and port fuel injection of gasoline with direction injection n-butanol at a fixed total energy released in a cycle, their indicated mean effective pressures are close. But their combustion processes are dependent on fuel injection approaches.

Optimization of the octane response of gasoline/ethanol blends

KAUST Repository

Badra, Jihad; AlRamadan, Abdullah S.; Sarathy, Mani

2017-01-01

The octane responses of gasoline/ethanol mixtures are not well understood because of the unidentified intermolecular interactions in such blends. In general, when ethanol is blended with gasoline, the Research Octane Number (RON) and the Motor Octane Number (MON) non-linearly increase or decrease, and the non-linearity is determined by the composition of the base gasoline and the amount of added ethanol. The complexity of commercial gasolines, comprising of hundreds of different components, makes it challenging to understand ethanol-gasoline synergistic/antagonistic blending effects. Understanding ethanol blending effects with simpler gasoline surrogates is critical to acquire knowledge about ethanol blending with complex multi-component gasoline fuels. In this study, the octane numbers (ON) of ethanol blends with five relevant gasoline surrogate molecules were measured. The molecules investigated in this study include: n-pentane, iso-pentane, 1,2,4-trimethylbenzene, cyclopentane and 1-hexene. These new measurements along with the available data of n-heptane, iso-octane, toluene, various primary reference fuels (PRF) and toluene primary reference fuels (TPRF) with ethanol are used to develop a blending rule for the octane response (RON and MON) of multi-component blends with ethanol. In addition, new ON data are collected for six Fuels for Advanced Combustion Engine (FACE) with ethanol. The relatively simple volume based model successfully predicts the octane numbers (ON) of the various ethanol/PRF and ethanol/TPRF blends with the majority of predictions being within the ASTM D2699 (RON) and D2700 (MON) reproducibility limits. The model is also successfully validated against the ON of the FACE gasolines blended with ethanol with the majority of predictions being within the reproducibility limits. Finally, insights into the possible causes of the synergistic and antagonistic effects of different molecules with ethanol are provided.

Optimization of the octane response of gasoline/ethanol blends

KAUST Repository

Badra, Jihad

2017-07-04

The octane responses of gasoline/ethanol mixtures are not well understood because of the unidentified intermolecular interactions in such blends. In general, when ethanol is blended with gasoline, the Research Octane Number (RON) and the Motor Octane Number (MON) non-linearly increase or decrease, and the non-linearity is determined by the composition of the base gasoline and the amount of added ethanol. The complexity of commercial gasolines, comprising of hundreds of different components, makes it challenging to understand ethanol-gasoline synergistic/antagonistic blending effects. Understanding ethanol blending effects with simpler gasoline surrogates is critical to acquire knowledge about ethanol blending with complex multi-component gasoline fuels. In this study, the octane numbers (ON) of ethanol blends with five relevant gasoline surrogate molecules were measured. The molecules investigated in this study include: n-pentane, iso-pentane, 1,2,4-trimethylbenzene, cyclopentane and 1-hexene. These new measurements along with the available data of n-heptane, iso-octane, toluene, various primary reference fuels (PRF) and toluene primary reference fuels (TPRF) with ethanol are used to develop a blending rule for the octane response (RON and MON) of multi-component blends with ethanol. In addition, new ON data are collected for six Fuels for Advanced Combustion Engine (FACE) with ethanol. The relatively simple volume based model successfully predicts the octane numbers (ON) of the various ethanol/PRF and ethanol/TPRF blends with the majority of predictions being within the ASTM D2699 (RON) and D2700 (MON) reproducibility limits. The model is also successfully validated against the ON of the FACE gasolines blended with ethanol with the majority of predictions being within the reproducibility limits. Finally, insights into the possible causes of the synergistic and antagonistic effects of different molecules with ethanol are provided.

40 CFR 86.340-79 - Gasoline-fueled engine dynamometer test run.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Gasoline-fueled engine dynamometer... Emission Regulations for New Gasoline-Fueled and Diesel-Fueled Heavy-Duty Engines; Gaseous Exhaust Test Procedures § 86.340-79 Gasoline-fueled engine dynamometer test run. (a) This section applies to gasoline...

Stream remediation following a gasoline spill

International Nuclear Information System (INIS)

Owens, E.H.; Reiter, G.A.; Challenger, G.

2000-01-01

On June 10, 1999, a pipe ruptured on the Olympic Pipe Line causing the release, explosion and fire of up to one million litres of gasoline in Bellingham, Washington. It affected approximately 5 km of the Whatcom Creek ecosystem. Following the incident, several concurrent activities in the source area and downstream occurred. This paper discussed the remediation of the affected stream bed sections. During the period July 6 - August 16, an interagency project was implemented. It involved mechanical, manual, and hydraulic in-situ treatment techniques to remove the gasoline from the stream bed and the banks. In addition, a series of controlled, hydraulic flushes were conducted. The sluice or control gates at the head of the Whatcom Creek were opened each night, and bigger flushes took place before and after the treatments. Simultaneously, water and sediment were sampled and analysed. The data obtained provided information on the state of the initial stream water and stream sediment and on the effects that the remediation had had. The residual gasoline was successfully removed from the sediments and river banks in six weeks. No downstream movement of the released gasoline towards Bellingham was detected. 3 refs., 2 tabs., 11 figs

Do Daily Retail Gasoline Prices adjust Asymmetrically?

NARCIS (Netherlands)

L.J.H. Bettendorf (Leon); S.A. van der Geest (Stéphanie); G. Kuper

2005-01-01

textabstractThis paper analyzes adjustments in the Dutch retail gasoline prices. We estimate an error correction model on changes in the daily retail price for gasoline (taxes excluded) for the period 1996-2004 taking care of volatility clustering by estimating an EGARCH model. It turns out the

Understanding retail gasoline pricing : An empirical approach

NARCIS (Netherlands)

Bruzikas, Tadas

2017-01-01

Retail gasoline markets offer an abundance of price data at the daily and, more recently, hourly level. Firms in this industry use sophisticated price strategies. Moreover, there have been a number of important recent market developments. All this makes retail gasoline a promising industry to study

The Impact of Ethanol Blending on U.S. Gasoline Prices

Energy Technology Data Exchange (ETDEWEB)

none,

2008-11-01

This study assesses the impact of ethanol blending on gasoline prices in the United States today and the potential impact of ethanol on gasoline prices at higher blending concentrations (10%, 15% and 20% of the total U.S. gasoline consumption).

Economic and environmental benefits of higher-octane gasoline.

Science.gov (United States)

Speth, Raymond L; Chow, Eric W; Malina, Robert; Barrett, Steven R H; Heywood, John B; Green, William H

2014-06-17

We quantify the economic and environmental benefits of designing U.S. light-duty vehicles (LDVs) to attain higher fuel economy by utilizing higher octane (98 RON) gasoline. We use engine simulations, a review of experimental data, and drive cycle simulations to estimate the reduction in fuel consumption associated with using higher-RON gasoline in individual vehicles. Lifecycle CO2 emissions and economic impacts for the U.S. LDV fleet are estimated based on a linear-programming refinery model, a historically calibrated fleet model, and a well-to-wheels emissions analysis. We find that greater use of high-RON gasoline in appropriately tuned vehicles could reduce annual gasoline consumption in the U.S. by 3.0-4.4%. Accounting for the increase in refinery emissions from production of additional high-RON gasoline, net CO2 emissions are reduced by 19-35 Mt/y in 2040 (2.5-4.7% of total direct LDV CO2 emissions). For the strategies studied, the annual direct economic benefit is estimated to be $0.4-6.4 billion in 2040, and the annual net societal benefit including the social cost of carbon is estimated to be $1.7-8.8 billion in 2040. Adoption of a RON standard in the U.S. in place of the current antiknock index (AKI) may enable refineries to produce larger quantities of high-RON gasoline.

Flow of gasoline-in-water microemulsion through water-saturated soil columns

International Nuclear Information System (INIS)

Ouyang, Y.; Mansell, R.S.; Rhue, R.D.

1995-01-01

Much consideration has been given to the use of surfactants to clean up nonaqueous phase liquids (NAPLs) from contaminated soil and ground water. Although this emulsification technique has shown significant potential for application in environmental remediation practices, a major obstacle leading to low washing efficiency is the potential formation of macroemulsion with unfavorable flow characteristics in porous media. This study investigated influences of the flow of leaded-gasoline-in-water (LG/W) microemulsion upon the transport of gasoline and lead (Pb) species in water-saturated soil columns. Two experiments were performed: (1) the immiscible displacement of leaded gasoline and (2) the miscible displacement of LG/W microemulsion through soil columns, followed by sequentially flushing with NaCl solution and a water/surfactant/cosurfactant (W/S/CoS) mixture. Comparison of breakthrough curves (BTC) for gasoline between the two experiments shows that about 90% of gasoline and total Pb were removed from the soil columns by NaCl solution in the LG/W microemulsion experiment as compared to 40% removal of gasoline and 10% removal of total Pb at the same process in the leaded gasoline experiment. Results indicate that gasoline and Pb species moved much more effectively through soil during miscible flow of LG/W microemulsion than during immiscible flow of leaded gasoline. In contrast to the adverse effects of macroemulsion on the transport of NAPLs, microemulsion was found to enhance the transport of gasoline through water-saturated soil. Mass balance analysis shows that the W/S/CoS mixture had a high capacity for removing residual gasoline and Pb species from contaminated soil. Comparison of water-pressure differences across the soil columns for the two experiments indicates that pore clogging by gasoline droplets was greatly minimized in the LG/W microemulsion experiment

Proinflammatory and anti-inflammatory cytokine balance in gasoline exhaust induced pulmonary injury in mice.

Science.gov (United States)

Sureshkumar, Veerapandian; Paul, Bholanath; Uthirappan, Mani; Pandey, Renu; Sahu, Anand Prakash; Lal, Kewal; Prasad, Arun Kumar; Srivastava, Suresh; Saxena, Ashok; Mathur, Neeraj; Gupta, Yogendra Kumar

2005-03-01

Proinflammatory and anti-inflammatory cytokine balance and associated changes in pulmonary bronchoalveolar lavage fluid (BALF) of unleaded gasoline exhaust (GE) exposed mice were investigated. Animals were exposed to GE (1 L/min of GE mixed with 14 L/min of compressed air) using a flow-past, nose-only, dynamic inhalation exposure chamber for different durations (7, 14, and 21 days). The particulate content of the GE was found to be 0.635, +/-0.10 mg PM/m3. Elevated levels of tumor necrosis factor-alpha (TNF-alpha) and interleukin-6 (IL-6) were observed in BALF of GE-exposed mice, but interleukin 1beta(IL-1beta) and the anti-inflammatory cytokine interleukin-10 (IL-10) remained unaffected. GE induced higher activities of alkaline phosphatase (ALP), gamma-glutamyl transferase (gammaGT), and lactate dehydrogenase (LDH) in the BALF, indicating Type II alveolar epithelial cell injury, Clara-cell injury, and general toxicity, respectively. Total protein in the BALF increased after 14 and 21 days of exposure, indicating enhanced alveolar-capillary permeability. However, the difference in the mean was found statistically insignificant in comparison to the compressed air control. Total cell count in the BALF of GE-exposed mice ranged between 0.898 and 0.813x10(6) cells/ml, whereas the compressed air control showed 0.65x10(6) cells/mL. The histopathological changes in GE-exposed lung includes perivascular, and peribronchiolar cuffing of mononuclear cells, migration of polymorphonuclear cells in the alveolar septa, alveolar thickening, and mild alveolar edematous changes indicating inflammation. The shift in pro- and anti-inflammatory cytokine balance and elevation of the pulmonary marker enzymes indicate toxic insult of GE. This study will help in our understanding of the mechanism of pulmonary injury by GE in the light of cytokine profiles, pulmonary marker enzymes, and lung architecture.

Do daily retail gasoline prices adjust asymmetrically?

NARCIS (Netherlands)

Bettendorf, L.; van der Geest, S. A.; Kuper, G. H.

2009-01-01

This paper analyses adjustments in the Dutch retail gasoline prices. We estimate an error correction model on changes in the daily retail price for gasoline (taxes excluded) for the period 1996-2004, taking care of volatility clustering by estimating an EGARCH model. It turns out that the volatility

Gasoline, Ethanol and Methanol (GEM) Ternary Blends utilization as an Alternative to Conventional Iraqi Gasoline to Suppress Emitted Sulfur and Lead Components to Environment

OpenAIRE

Miqdam Tariq Chaichan

2016-01-01

Iraqi conventional gasoline characterized by its low octane number not exceed 82 and high lead and sulfur content. In this paper tri-component or ternary, blends of gasoline, ethanol, and methanol presented as an alternative fuel for Iraqi conventional gasoline. The study conducted by using GEM blend that equals E85 blend in octane rating. The used GEM selected from Turner, 2010 collection. G37 E20 M43 (37% gasoline + 20% ethanol+ 43% methanol) was chosen as GEM in present study. This blend u...

Studies of lead pollution in the air of Shanghai by multiple techniques

International Nuclear Information System (INIS)

Tan, M.G.; Zhang, G.L.; Li, X.L.; Zhang, Y.X.; Yue, W.S.; Chen, J.M.; Wang, Y.S.; Li, A.G.; Li, Y.; Zhang, Y.M.; Shan, Z.C.

2005-01-01

Lead pollution in atmosphere has been one of the worrisome environmental problems since the tetraethyl lead was used as an antiknock agent in combustion engines. The presence of lead in urban air, even at low doses, may cause neurological impairments of fetuses and young children. Studies also show that lead may be a factor in high blood pressure and subsequent heart disease. Atmospheric lead has various origins, such as gasoline, industrial emissions and coal burning etc. The present work reports the lead levels in air particulate matter samples of PM 10 collected in recent years to evaluate the effect of the use of unleaded gasoline in Shanghai since 1997. The chemical species of lead in PM 10 and their origins were also studied. To our knowledge it is a first time to give an estimation of lead contribution to air in a city from different emission sources quantitatively. Proton-induced X-ray emission analysis (PIXE), proton microprobe (μ-PIXE), inductively coupled plasma-mass spectrometry (ICP-MS) and X-ray absorption fine structure (XAFS) techniques were used to study the concentration, the chemical species and the source assignment of Pb in the atmospheric aerosol particles of PM 10 . Average values of 369±74. ng/m 3 and 237±45 ng/m 3 of Pb concentration were obtained from the 19 monitor sites in Shanghai in the winter of 2002 and 2003, respectively. Comparing with the earlier data of 466 ng/m 3 in 1997 and 515 ng/m 3 in 2001, it can be observed that the yearly mean lead levels in PM 10 decline significantly. However, it is also found that rather high levels of lead still remain. in the air of Shanghai after the use of unleaded gasoline. The results of XAFS showed that PbCl 2 , PbSO 4 and PbO were probably the main chemical forms of Pb in atmospheric particulate matter. Based on the lead isotope ratios technique and chemical mass balance analysis, the calculation showed that the main emission sources of Pb in the atmosphere of Shanghai were coal combustors

40 CFR 80.78 - Controls and prohibitions on reformulated gasoline.

Science.gov (United States)

2010-07-01

... reformulated gasoline. 80.78 Section 80.78 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Reformulated Gasoline § 80.78 Controls and prohibitions on reformulated gasoline. (a) Prohibited activities. (1) No person may manufacture...

Are emissions of black carbon from gasoline vehicles overestimated? Real-time, in situ measurement of black carbon emission factors.

Science.gov (United States)

Wang, Yang; Xing, Zhenyu; Zhao, Shuhui; Zheng, Mei; Mu, Chao; Du, Ke

2016-03-15

Accurately quantifying black carbon (BC) emission factors (EFs) is a prerequisite for estimation of BC emission inventory. BC EFs determined by measuring BC at the roadside or chasing a vehicle on-road may introduce large uncertainty for low emission vehicles. In this study, BC concentrations were measured inside the tailpipe of gasoline vehicles with different engine sizes under different driving modes to determine the respective EFs. BC EFs ranged from 0.005-7.14 mg/kg-fuel under the speeds of 20-70 km/h, 0.05-28.95 mg/kg-fuel under the accelerations of 0.5-1.5m/s(2). Although the water vapor in the sampling stream could result in an average of 12% negative bias, the BC EFs are significantly lower than the published results obtained with roadside or chasing vehicle measurement. It is suggested to conduct measurement at the tailpipe of gasoline vehicles instead of in the atmosphere behind the vehicles to reduce the uncertainty from fluctuation in ambient BC concentration. Copyright © 2015 Elsevier B.V. All rights reserved.

Identification of chemical warfare agents from vapor samples using a field-portable capillary gas chromatography/membrane-interfaced electron ionization quadrupole mass spectrometry instrument with Tri-Bed concentrator.

Science.gov (United States)

Nagashima, Hisayuki; Kondo, Tomohide; Nagoya, Tomoki; Ikeda, Toru; Kurimata, Naoko; Unoke, Shohei; Seto, Yasuo

2015-08-07

A field-portable gas chromatograph-mass spectrometer (Hapsite ER system) was evaluated for the detection of chemical warfare agents (CWAs) in the vapor phase. The system consisted of Tri-Bed concentrator gas sampler (trapping time: 3s(-1)min), a nonpolar low thermal-mass capillary gas chromatography column capable of raising temperatures up to 200°C, a hydrophobic membrane-interfaced electron ionization quadrupole mass spectrometer evacuated by a non-evaporative getter pump for data acquisition, and a personal computer for data analysis. Sample vapors containing as little as 22μg sarin (GB), 100μg soman (GD), 210μg tabun (GA), 55μg cyclohexylsarin (GF), 4.8μg sulfur mustard, 390μg nitrogen mustard 1, 140μg of nitrogen mustard 2, 130μg nitrogen mustard 3, 120μg of 2-chloroacetophenone and 990μg of chloropicrin per cubic meter could be confirmed after Tri-Bed micro-concentration (for 1min) and automated AMDIS search within 12min. Using manual deconvolution by background subtraction of neighboring regions on the extracted ion chromatograms, the above-mentioned CWAs could be confirmed at lower concentration levels. The memory effects were also examined and we found that blister agents showed significantly more carry-over than nerve agents. Gasoline vapor was found to interfere with the detection of GB and GD, raising the concentration limits for confirmation in the presence of gasoline by both AMDIS search and manual deconvolution; however, GA and GF were not subject to interference by gasoline. Lewisite 1, and o-chlorobenzylidene malononitrile could also be confirmed by gas chromatography, but it was hard to quantify them. Vapors of phosgene, chlorine, and cyanogen chloride could be confirmed by direct mass spectrometric detection at concentration levels higher than 2, 140, and 10mg/m(3) respectively, by bypassing the micro-concentration trap and gas chromatographic separation. Copyright © 2015 Elsevier B.V. All rights reserved.

Evaluation of Anti-Knock Quality of Dicyclopentadiene-Gasoline Blends

KAUST Repository

Al-Khodaier, Mohannad

2017-03-28

Increasing the anti-knock quality of gasoline fuels can enable higher efficiency in spark ignition engines. In this study, the blending anti-knock quality of dicyclopentadiene (DCPD), a by-product of ethylene production from naphtha cracking, with various gasoline fuels is explored. The blends were tested in an ignition quality tester (IQT) and a modified cooperative fuel research (CFR) engine operating under homogenous charge compression ignition (HCCI) and knock limited spark advance (KLSA) conditions. Due to current fuel regulations, ethanol is widely used as a gasoline blending component in many markets. In addition, ethanol is widely used as a fuel and literature verifying its performance. Moreover, because ethanol exhibits synergistic effects, the test results of DCPD-gasoline blends were compared to those of ethanol-gasoline blends. The experiments conducted in this work enabled the screening of DCPD auto-ignition characteristics across a range of combustion modes. The synergistic blending nature of DCPD was apparent and appeared to be greater than that of ethanol. The data presented suggests that DCPD has the potential to be a high octane blending component in gasoline; one which can substitute alkylates, isomerates, reformates, and oxygenates.

Evaluation of Anti-Knock Quality of Dicyclopentadiene-Gasoline Blends

KAUST Repository

Al-Khodaier, Mohannad; Bhavani Shankar, Vijai Shankar; Waqas, Muhammad; Naser, Nimal; Sarathy, Mani; Johansson, Bengt

2017-01-01

Increasing the anti-knock quality of gasoline fuels can enable higher efficiency in spark ignition engines. In this study, the blending anti-knock quality of dicyclopentadiene (DCPD), a by-product of ethylene production from naphtha cracking, with various gasoline fuels is explored. The blends were tested in an ignition quality tester (IQT) and a modified cooperative fuel research (CFR) engine operating under homogenous charge compression ignition (HCCI) and knock limited spark advance (KLSA) conditions. Due to current fuel regulations, ethanol is widely used as a gasoline blending component in many markets. In addition, ethanol is widely used as a fuel and literature verifying its performance. Moreover, because ethanol exhibits synergistic effects, the test results of DCPD-gasoline blends were compared to those of ethanol-gasoline blends. The experiments conducted in this work enabled the screening of DCPD auto-ignition characteristics across a range of combustion modes. The synergistic blending nature of DCPD was apparent and appeared to be greater than that of ethanol. The data presented suggests that DCPD has the potential to be a high octane blending component in gasoline; one which can substitute alkylates, isomerates, reformates, and oxygenates.

Degradation of tetraethyllead in leaded gasoline contaminated and uncontaminated soils

International Nuclear Information System (INIS)

Ou, L.; Jing, W.; Thomas, J.; Mulroy, P.

1995-01-01

For over 50 years, since its introduction in 1923 by General Motors, tetraethyllead (TEL) was the major antiknock agent used in leaded gasoline. Since the middle of 1970, use of leaded gasoline in automobiles was gradually phased out. The main objective of this study is to determine the degradation rates and metabolites of TEL in gasoline contaminated and uncontaminated soils. TEL in uncontaminated soils disappeared rapidly. Ionic triethyllead (TREL) was the major organolead metabolite in these soils, with ionic diethyllead (DEL) being the minor product. Nonsterile soils, but not autoclaved soils, had limited capacity to mineralize 14 C-TEL to 14 CO 2 , H 2 0, and Pb 2+ . Unlike TEL in uncontaminated soils, petroleum hydrocarbons protected TEL in leaded gasoline contaminated soils from being degraded. Both disappearance and mineralization rates of TEL in leaded gasoline contaminated soils decreased with the increase in gasoline concentration. It appears that TEL in leaded gasoline contaminated soils is relatively stable until the level of petroleum hydrocarbons falls below a critical value. TEL is then rapidly degraded. Hydrocarbon degrading microorganisms may be involved, to some extent, in the degradation of TEL

Closing the gasoline system

International Nuclear Information System (INIS)

Hutcheson, R.C.

1992-01-01

In this paper, a representative of the Oil Companies' European Organization for Environmental and Health Protection (CONCAWE), argues the advantages of closing the gasoline system. Because this decouples the product from the environment, health risks and environmental damage are reduced. It is also more effective than changing the composition of gasoline because it offers better cost effectiveness, energy efficiency and the minimization of carbon dioxide release into the environment. However it will take time and political will to change until all European vehicles are fitted with three way catalysts and carbon canisters: control systems to monitor such systems will also need to be set up. However CONCAWE still recommends its adoption. (UK)

Standardized Gasoline Compression Ignition Fuels Matrix

KAUST Repository

Badra, Jihad; Bakor, Radwan; AlRamadan, Abdullah; Almansour, Mohammed; Sim, Jaeheon; Ahmed, Ahfaz; Viollet, Yoann; Chang, Junseok

2018-01-01

Direct injection compression ignition engines running on gasoline-like fuels have been considered an attractive alternative to traditional spark ignition and diesel engines. The compression and lean combustion mode eliminates throttle losses yielding higher thermodynamic efficiencies and the better mixing of fuel/air due to the longer ignition delay times of the gasoline-like fuels allows better emission performance such as nitric oxides (NOx) and particulate matter (PM). These gasoline-like fuels which usually have lower octane compared to market gasoline have been identified as a viable option for the gasoline compression ignition (GCI) engine applications due to its lower reactivity and lighter evaporation compared to diesel. The properties, specifications and sources of these GCI fuels are not fully understood yet because this technology is relatively new. In this work, a GCI fuel matrix is being developed based on the significance of certain physical and chemical properties in GCI engine operation. Those properties were chosen to be density, temperature at 90 volume % evaporation (T90) or final boiling point (FBP) and research octane number (RON) and the ranges of these properties were determined from the data reported in literature. These proposed fuels were theoretically formulated, while applying realistic constraints, using species present in real refinery streams. Finally, three-dimensional (3D) engine computational fluid dynamics (CFD) simulations were performed using the proposed GCI fuels and the similarities and differences were highlighted.

Standardized Gasoline Compression Ignition Fuels Matrix

KAUST Repository

Badra, Jihad

2018-04-03

Direct injection compression ignition engines running on gasoline-like fuels have been considered an attractive alternative to traditional spark ignition and diesel engines. The compression and lean combustion mode eliminates throttle losses yielding higher thermodynamic efficiencies and the better mixing of fuel/air due to the longer ignition delay times of the gasoline-like fuels allows better emission performance such as nitric oxides (NOx) and particulate matter (PM). These gasoline-like fuels which usually have lower octane compared to market gasoline have been identified as a viable option for the gasoline compression ignition (GCI) engine applications due to its lower reactivity and lighter evaporation compared to diesel. The properties, specifications and sources of these GCI fuels are not fully understood yet because this technology is relatively new. In this work, a GCI fuel matrix is being developed based on the significance of certain physical and chemical properties in GCI engine operation. Those properties were chosen to be density, temperature at 90 volume % evaporation (T90) or final boiling point (FBP) and research octane number (RON) and the ranges of these properties were determined from the data reported in literature. These proposed fuels were theoretically formulated, while applying realistic constraints, using species present in real refinery streams. Finally, three-dimensional (3D) engine computational fluid dynamics (CFD) simulations were performed using the proposed GCI fuels and the similarities and differences were highlighted.

Gasoline prices and traffic crashes in Alabama, 1999-2009.

Science.gov (United States)

Chi, Guangqing; McClure, Timothy E; Brown, David B

2012-09-01

The price of gasoline has been found to be negatively associated with traffic crashes in a limited number of studies. However, most of the studies have focused either on fatal crashes only or on all crashes but measured over a very short time period. In this study, we examine gasoline price effects on all traffic crashes by demographic groups in the state of Alabama from 1999 to 2009. Using negative binomial regression techniques to examine monthly data from 1999 to 2009 in the state of Alabama, we estimate the effects of changes in gasoline price on changes in automobile crashes. We also examine how these effects differ by age group (16-20, 21-25, 26-30, 31-64, and 65+), gender (male and female), and race/ethnicity (non-Hispanic white, non-Hispanic black, and Hispanic). The results show that gasoline prices have both short-term and long-term effects on reducing total traffic crashes and crashes of each age, gender, and race/ethnicity group (except Hispanic due to data limitations). The short-term and long-term effects are not statistically different for each individual demographic group. Gasoline prices have a stronger effect in reducing crashes involving drivers aged 16 to 20 than crashes involving drivers aged 31 to 64 and 65+ in the short term; the effects, however, are not statistically different across other demographic groups. Although gasoline price increases are not favored, our findings show that gasoline price increases (or decreases) are associated with reductions (or increases) in the incidence of traffic crashes. If gasoline prices had remained at the 1999 level of $1.41 from 1999 to 2009, applying the estimated elasticities would result in a predicted increase in total crashes of 169,492 (or 11.3%) from the actual number of crashes. If decision makers wish to reduce traffic crashes, increasing gasoline taxes is a possible option-however, doing so would increase travel costs and lead to equity concerns. These findings may help to shape transportation

Gasoline risk management: a compendium of regulations, standards, and industry practices.

Science.gov (United States)

Swick, Derek; Jaques, Andrew; Walker, J C; Estreicher, Herb

2014-11-01

This paper is part of a special series of publications regarding gasoline toxicology testing and gasoline risk management; this article covers regulations, standards, and industry practices concerning gasoline risk management. Gasoline is one of the highest volume liquid fuel products produced globally. In the U.S., gasoline production in 2013 was the highest on record (API, 2013). Regulations such as those pursuant to the Clean Air Act (CAA) (Clean Air Act, 2012: § 7401, et seq.) and many others provide the U.S. federal government with extensive authority to regulate gasoline composition, manufacture, storage, transportation and distribution practices, worker and consumer exposure, product labeling, and emissions from engines and other sources designed to operate on this fuel. The entire gasoline lifecycle-from manufacture, through distribution, to end-use-is subject to detailed, complex, and overlapping regulatory schemes intended to protect human health, welfare, and the environment. In addition to these legal requirements, industry has implemented a broad array of voluntary standards and best management practices to ensure that risks from gasoline manufacturing, distribution, and use are minimized. Copyright © 2014 The Authors. Published by Elsevier Inc. All rights reserved.

Feedback controlled fuel injection system can accommodate any alcohol-gasoline blend

Energy Technology Data Exchange (ETDEWEB)

Pefley, R K; Pullman, J B; Suga, T P; Espinola, S

1980-01-01

A fuel metering system has been adapted and permits operation on all blends of alcohols and gasoline ranging from pure gasoline to pure ethanol and methanol. It is a closed loop electronic feedback controlled fuel injection system (EFI) with exhaust oxygen sensor. The system is used by Toyota Motor Company in their Supra and Cressida models in conjunction with a 3-way catalytic exhaust system. These models meet California exhaust and evaporative emission standards. An unmodified model has been tested on alcohol gasoline blends from pure gasoline to 50% ethanol-50% gasoline and 30% methanol-70% gasoline and found to meet all exhaust and evaporative emissions standards. A Cressida with modified EFI system is currently being tested. It is capable of operating on pure gasoline, pure methanol or ethanol and all intermediate blends. The testing to date shows that the vehicle meets all exhaust emissions standards while operating over the blend range from pure gasoline to pure ethanol while maintaining driveability and energy based fuel economy. The paper will present the total test evidence for all gasoline-alcohol blends. This will include exhaust and evaporative emissions, fuel economy and driveability as determined in accordance with United States Federal Test Procedures. Additionally, the paper will report experiences accumulated from road operation of the vehicle over a six-month period.

Quantifying the emissions reduction effectiveness and costs of oxygenated gasoline

International Nuclear Information System (INIS)

Lyons, C.E.

1993-01-01

During the fall, winter, and spring of 1991-1992, a measurement program was conducted in Denver, Colorado to quantify the technical and economic effectiveness of oxygenated gasoline in reducing automobile carbon monoxide (CO) emissions. Emissions from 80,000 vehicles under a variety of operating conditions were measured before, during, and after the seasonal introduction of oxygenated gasoline into the region. Gasoline samples were taken from several hundred vehicles to confirm the actual oxygen content of the fuel in use. Vehicle operating conditions, such as cold starts and warm operations, and ambient conditions were characterized. The variations in emissions attributable to fuel type and to operating conditions were then quantified. This paper describes the measurement program and its results. The 1991-1992 Colorado oxygenated gasoline program contributed to a reduction in carbon monoxide (CO) emissions from gasoline-powered vehicles. The measurement program demonstrated that most of the reduction is concentrated in a small percentage of the vehicles that use oxygenated gasoline. The remainder experience little or not reduction in emissions. The oxygenated gasoline program outlays are approximately $25 to $30 million per year in Colorado. These are directly measurable costs, incurred through increased government expenditures, higher costs to private industry, and losses in fuel economy. The measurement program determined the total costs of oxygenated gasoline as an air pollution control strategy for the region. Costs measured included government administration and enforcement, industry production and distribution, and consumer and other user costs. This paper describes the ability of the oxygenated gasoline program to reduce pollution; the overall cost of the program to government, industry, and consumers; and the effectiveness of the program in reducing pollution compared to its costs

Gasoline prices and the public interest

International Nuclear Information System (INIS)

1997-12-01

The concerns that have been raised about gasoline prices in Newfoundland were addressed and the reasons why they differ significantly from one part of Newfoundland to another were examined. A research and investigation program was established to identify the factors contributing to the price of, and price variation in gasoline sold in the province. Companies directly involved in the gasoline retail business in the province were invited to answer an extensive questionnaire which asked detailed, confidential information concerning the company's operations. This report contains the results of the analysis of the responses, and provides a comprehensive picture of the operation of the petroleum industry. It also contains a series of recommendations for the government with respect to monitoring price fluctuations, gathering data about the industry, and constructing an independently owned and operated terminal storage facility. The report recommends against direct regulation. tabs., figs

The butane as a component for the gasoline blending

International Nuclear Information System (INIS)

Gicheva, Ljubica

2002-01-01

In OKTA Crude Oil Refinery - Skopje the production of butane as a pure component is based on a liquid phase and it is used for both TNG (propane-butane gas) and motor gasoline production with a quality that satisfy the standard. By using the butane as a gasoline component the quality of the MB-98 and BMB has been improved. The butane itself ensures octane improvement of the pool, by what the content of the lead additives or the octane of the main component - reformat decreases. Also, the butane addition decreases the density of the final products by what the financial effects have been improved. It is also interesting to explain the usage of butane for gasoline production concerning the new proposed standard. The paper presents the practical results, through tables and diagrams, of the butane usage as a component for gasoline production, as well as the butane influence to the quality of the produced gasoline. (Original)

Gasoline Biodesulfurization DE-FC07-97ID13570 FINAL REPORT

Energy Technology Data Exchange (ETDEWEB)

Pienkos, Philip T.

2002-01-15

Nine strains were identified to grow with gasoline as sole sulfur source. Two different genes were cloned from Gordonia terrae KGB1 and tested for the ability to support gasoline BDS. The first of these, fmoA, was cloned by screening a KGB1 gene library for the ability to convert indole to indigo (a sulfur-regulated capability in KGB1). The fmoA gene was overexpressed in a gasoline tolerant strain of Pseudomonas putida PpG1 and the recombinant strain was shown to convert thiophene to a dimer of thiophene sulfoxide at rates nearly two orders of magnitude higher than KGB1 could catalyze the reaction. Despite this high activity the recombinant PpG1 was unable to demonstrate any activity against gasoline either in shake flask or in bench-scale gasoline BDS bioreactor. A second gene (toeA) was cloned from KGB1 and shown to support growth of Rhodococcus erythropolis JB55 on gasoline. The toeA gene was also identified in another gasoline strain T. wratislaviensis EMT4, and was identified as a homolog of dszA from R. erythropolis IGTS8. Expression of this gene in JB55 supported conversion of DBTO2 (the natural substrate for DszA) to HPBS, but activity against gasoline was low and BDS results were inconsistent. It appeared that activity was directed against C2- and C3-thiophenes. Efforts to increase gene expression by plasmid manipulation, by addition of flavin reductase genes, or by expression in PpG1 were unsuccessful. The DszC protein (DBT monooxygenase) from IGTS8 has very little activity against the sulfur compounds in gasoline, but a mutant enzyme with a substitution of phenylalanine for valine at position 261 was shown to have an altered substrate range. This alteration resulted in increased activity against gasoline, with activity towards mainly C3- and C4-thiophenes and benzothiophene. A mutant library of dszB was constructed by RACHITT (W. C. Coco et al., DNA shuffling method for generating highly recombined genes and evolved enzymes. 2001. Nature Biotech. 19

Techno-economic Analysis for the Conversion of Lignocellulosic Biomass to Gasoline via the Methanol-to-Gasoline (MTG) Process

Energy Technology Data Exchange (ETDEWEB)

Jones, Susanne B.; Zhu, Yunhua

2009-05-01

Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications. As a widely available biomass form, lignocellulosic biomass can have a major impact on domestic transportation fuel supplies and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). With gasification technology, biomass can be converted to gasoline via methanol synthesis and methanol-to-gasoline (MTG) technologies. Producing a gasoline product that is infrastructure ready has much potential. Although the MTG technology has been commercially demonstrated with natural gas conversion, combining MTG with biomass gasification has not been shown. Therefore, a techno-economic evaluation for a biomass MTG process based on currently available technology was developed to provide information about benefits and risks of this technology. The economic assumptions used in this report are consistent with previous U.S. Department of Energy Office of Biomass Programs techno-economic assessments. The feedstock is assumed to be wood chips at 2000 metric ton/day (dry basis). Two kinds of gasification technologies were evaluated: an indirectly-heated gasifier and a directly-heated oxygen-blown gasifier. The gasoline selling prices (2008 USD) excluding taxes were estimated to be $3.20/gallon and $3.68/gallon for indirectly-heated gasified and directly-heated. This suggests that a process based on existing technology is economic only when crude prices are above $100/bbl. However, improvements in syngas cleanup combined with consolidated gasoline synthesis can potentially reduce the capital cost. In addition, improved synthesis catalysts and reactor design may allow increased yield.

In-situ active/passive bioreclamation of vadose zone soils contaminated with gasoline and waste oil using soil vapor extraction/bioventing: Laboratory pilot study to full scale site operation

International Nuclear Information System (INIS)

Zachary, S.P.; Everett, L.G.

1993-01-01

The use of soil venting to supply oxygen and remove metabolites from the biodegradation of light hydrocarbons is a cost effective in-situ remediation approach. To date, little data exists on the effective in-situ bioreclamation of vadose zone soil contaminated with waste/hydraulic oil without excavation or the addition of water or nutrients to degrade the heavy petroleum contaminants. Gasoline and waste/hydraulic oil contaminated soils below an active commercial building required an in-situ non-disruptive remediation approach. Initial soil vapor samples collected from the vadose zone revealed CO 2 concentrations in excess of 16% and O 2 concentrations of less than 1% by volume. Soil samples were collected from below the building within the contaminated vadose zone for laboratory chemical and physical analysis as well as to conduct a laboratory biotreatability study. The laboratory biotreatability study was conducted for 30 days to simulate vadose zone bioventing conditions using soil taken from the contaminated vadose zone. Results of the biotreatability study revealed that the waste oil concentrations had been reduced from 960 mg/Kg to non-detectable concentrations within 30 days and the volatile hydrocarbon content had decreased exponentially to less than 0.1% of the original concentration. Post treatability study biological enumeration revealed an increase in the microbial population of two orders of magnitude

The empirical relationship between energy futures prices and exchange rates

International Nuclear Information System (INIS)

Sadorsky, P.

2000-01-01

This paper investigates the interaction between energy futures prices and exchange rates. Results are presented to show that futures prices for crude oil, heating oil and unleaded gasoline are co-integrated with a trade-weighted index of exchange rates. This is important because it means that there exists a long-run equilibrium relationship between these four variables. Granger causality results for both the long- and short-run are presented. Evidence is also presented that suggests exchange rates transmit exogenous shocks to energy futures prices. 22 refs

Unit root behavior in energy futures prices

OpenAIRE

Serletis, Apostolos

1992-01-01

This paper re-examines the empirical evidence for random walk type behavior in energy futures prices. In doing so, tests for unit roots in the univariate time-series representation of the daily crude oil, heating oil, and unleaded gasoline series are performed using recent state-of-the-art methodology. The results show that the unit root hypothesis can be rejected if allowance is made for the possibility of a one-time break in the intercept and the slope of the trend function at an unknown po...

PIXE analysis of atmospheric aerosols in the city of Buenos Aires

International Nuclear Information System (INIS)

Ozafran, M.J.; Vazquez, M.E.; Burlon, A.

1999-01-01

Lead pollution present in atmospheric aerosols in the city Buenos Aires was measured in 1989, using Heavy Ion PIXE. Since then, environmental conditions have changed significantly. The usage of unleaded gasoline was introduced, and the utilisation of compressed natural gas as car fuel has increased. Recently, a new sampling campaign of atmospheric aerosols has started, partly in collaboration with the Greenpeace Foundation. The present studies reveal that lead pollution in Buenos Aires has significantly decreased since 1989. The concentrations of other elements are determined as well. (author)

Polycaprolactone-Polydiacetylene Electrospun Fibers for Colorimetric Detection of Fake Gasoline

Directory of Open Access Journals (Sweden)

Shamshad Ali

2016-04-01

Full Text Available PCDA (Pentacosadiynoic Acid monomers were successfully embedded in PCL (Poly ?-Caprolactone polymer matrix by electrospinning process for the first time. The resultant EFM (Electrospun Fibers Mat was photo-polymerized under 254 nm UV light that enables colorimetric detection of fake gasoline. Results revealed that the fake gasoline develops a red color mat within 5 sec. FE-SEM images showed that the fake gasoline treatment dissolved the PCL EFM that give access to interact with PDA polymer. The proposed litmus-type sensor based on PCL-PDA EFM is highly sensitive to fake gasoline and can be fabricated easily

40 CFR 80.240 - What are the small refiner gasoline sulfur standards?

Science.gov (United States)

2010-07-01

... volume of gasoline produced by a small refiner's refinery up to the lesser of: (i) 105% of the baseline gasoline volume as determined under § 80.250(a)(1); or (ii) The volume of gasoline produced at that... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What are the small refiner gasoline...

The crisis of gasoline consumption in the Iran's transportation sector

International Nuclear Information System (INIS)

Houri Jafari, H.; Baratimalayeri, A.

2008-01-01

Fossil fuels have the greatest share in supplying the world's energy demands. Regarding the limited natural resources, fuel consumption management and energy planning in the end-user sectors are two great matters of importance. Among the fossil fuels, gasoline is the principal fuel for light-duty vehicles. In Iran, fuel consumption, especially that of gasoline, has increased sharply with the growth rate of 10.2% for the year 2006 in comparison with that in 2005, turning into a big crisis in the recent years. On the other hand, enormous subsidies for importing 40% of domestic demands, which have reached more than 10 billion US$, are too much to be supplied. In this study, we have assessed the gasoline consumption, production, import and prices; reviewed main causes of the tremendous growth rate of consumption, current conservation policies and their advantages or disadvantages (SWOT analysis); proposed short- to long-term solutions and strategies for efficient gasoline consumption management; and finally, current strategies and proposed solutions are analyzed and evaluated. A foregone conclusion strongly suggests that not only the low price of motor gasoline but also mass production of vehicles with the conventional technology, likewise, affects motor gasoline demand. A second conclusion is that gasoline crisis in Iran has no straight solution, and that fundamental strategies and policies are needed to solve the problem. (author)

Hige Compression Ratio Turbo Gasoline Engine Operation Using Alcohol Enhancement

Energy Technology Data Exchange (ETDEWEB)

Heywood, John [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Jo, Young Suk [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Lewis, Raymond [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Bromberg, Leslie [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Heywood, John [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

2016-01-29

The overall objective of this project was to quantify the potential for improving the performance and efficiency of gasoline engine technology by use of alcohols to suppress knock. Knock-free operation is obtained by direct injection of a second “anti-knock” fuel such as ethanol, which suppresses knock when, with gasoline fuel, knock would occur. Suppressing knock enables increased turbocharging, engine downsizing, and use of higher compression ratios throughout the engine’s operating map. This project combined engine testing and simulation to define knock onset conditions, with different mixtures of gasoline and alcohol, and with this information quantify the potential for improving the efficiency of turbocharged gasoline spark-ignition engines, and the on-vehicle fuel consumption reductions that could then be realized. The more focused objectives of this project were therefore to: Determine engine efficiency with aggressive turbocharging and downsizing and high compression ratio (up to a compression ratio of 13.5:1) over the engine’s operating range; Determine the knock limits of a turbocharged and downsized engine as a function of engine speed and load; Determine the amount of the knock-suppressing alcohol fuel consumed, through the use of various alcohol-gasoline and alcohol-water gasoline blends, for different driving cycles, relative to the gasoline consumed; Determine implications of using alcohol-boosted engines, with their higher efficiency operation, in both light-duty and medium-duty vehicle sectors.

75 FR 74044 - Agency Information Collection Activities; Proposed Collection; Comment Request; Gasoline Volatility

Science.gov (United States)

2010-11-30

...; Gasoline Volatility AGENCY: Environmental Protection Agency (EPA). ACTION: Notice. SUMMARY: In compliance... entities: Entities potentially affected by this action are those who produce or import gasoline containing... Additives: Gasoline Volatility, Reporting Requirements for Parties Which Produce of Import Gasoline...

The economics of gasoline subsidy cost reduction policy: Case study of Indonesia

Science.gov (United States)

Akimaya, Muhammad I.

A gasoline subsidy distorts the gasoline market with the resulting inefficiencies and takes substantial revenues that arguably could be spent elsewhere with a better impact on economic growth. Governments with such subsidies are aware of their cost yet face difficulties in removing the policy because of strong resistance from the public. This thesis discusses in three essays the problem faced by the government in removing the gasoline subsidy and provides an alternative policy in reducing the subsidy cost applied to the case of Indonesia. In the first essay, we examine the decision-making process from the government's perspective that has an objective of generating savings to fund other programs while maintaining political power, and the influence that the general population has over the decision. Despite the immense literature on political power, there has yet to be any research that mathematically models the decision-making process of a government with influences from the general population. Under the benchmark scenario, the equilibrium strategy is to keep the subsidy intact. However, the results are found to be very sensitive to the magnitude of the shift in political power as well as the preferences of both the government and the people. In the second essay, we estimate the cross-price elasticity of regular gasoline with respect to premium gasoline price. The importance of such knowledge is to accurately determine the impact of fuel pricing policy that tends to have different rates of tax or subsidy depending on the grade of gasoline. Using data on the Mexican gasoline market, regular gasoline demand is estimated with an Autoregressive Distributed Lag (ARDL) model. Endogeneity of the price and structural break are also investigated. The cross-price elasticities between regular and premium gasoline is found to be -0.895, which confirms high substitutability among gasoline with different grades. In the third essay, we look at the unique case of Indonesia that

Ten years of monitored natural attenuation of a major gasoline spill in a residential area

International Nuclear Information System (INIS)

Munz, Ch.; Moller, M.; Haner, A.; Berg, M.; Zwank, L.; Zwank, L.

2005-01-01

In march 1994 a tank train carrying gasoline derailed and caught fire in the suburbs of Zuerich. A total of approximately 400 t of gasoline were lost in the accident. On the order of 80000 kg of gasoline leached into the subsurface. According to the risk assessment conducted following the accident, remediation was limited to soil vapor extraction (SVE) in the vadose zone. Remediation was successfully completed in 1998. However, monitoring of the groundwater contamination has continued to ascertain that natural attenuation is indeed leading to the predicted reduction in groundwater contamination. Following a brief review of the contaminant mass balance derived after completion of the remedial measures in 1998, we present and discuss the results of 10 years of monitoring the groundwater plume, focusing on the development of the benzene and MTBE plumes and the concurrent evolution of the geochemical parameters nitrate and sulfate. With the available data of 10 years of monitored natural attenuation, predictions made shortly after the accident have been confirmed. Initial estimates of the quantities of contaminants released into the aquifer could be ascertained and the contaminant plumes were contained within the predicted range downstream of the accident site. At this site the observed overall rate of attenuation (biodegradation, sorption, dispersion) of MTBE was always greater or equal than that of benzene. This finding is unexpected, especially since no anaerobic biodegradation of MTBE was observed at the site, according to the stable carbon and hydrogen analysis conducted. Natural attenuation can be an (cost-) effective remedial option, if the site specific characteristics are advantageous, e.g. no immediate targets threatened, adequate hydro-geochemical properties, etc., and the required time is available, as was the case in Zuerich-Affoltern

Rising gasoline prices increase new motorcycle sales and fatalities.

Science.gov (United States)

Zhu, He; Wilson, Fernando A; Stimpson, Jim P; Hilsenrath, Peter E

2015-12-01

We examined whether sales of new motorcycles was a mechanism to explain the relationship between motorcycle fatalities and gasoline prices. The data came from the Motorcycle Industry Council, Energy Information Administration and Fatality Analysis Reporting System for 1984-2009. Autoregressive integrated moving average (ARIMA) regressions estimated the effect of inflation-adjusted gasoline price on motorcycle sales and logistic regressions estimated odds ratios (ORs) between new and old motorcycle fatalities when gasoline prices increase. New motorcycle sales were positively correlated with gasoline prices (r = 0.78) and new motorcycle fatalities (r = 0.92). ARIMA analysis estimated that a US$1 increase in gasoline prices would result in 295,000 new motorcycle sales and, consequently, 233 new motorcycle fatalities. Compared to crashes on older motorcycle models, those on new motorcycles were more likely to be young riders, occur in the afternoon, in clear weather, with a large engine displacement, and without alcohol involvement. Riders on new motorcycles were more likely to be in fatal crashes relative to older motorcycles (OR 1.14, 95 % confidence interval (CI) 1.02-1.28) when gasoline prices increase. Our findings suggest that, in response to increasing gasoline prices, people tend to purchase new motorcycles, and this is accompanied with significantly increased crash risk. There are several policy mechanisms that can be used to lower the risk of motorcycle crash injuries through the mechanism of gas prices and motorcycle sales such as raising awareness of motorcycling risks, enhancing licensing and testing requirements, limiting motorcycle power-to-weight ratios for inexperienced riders, and developing mandatory training programs for new riders.

Electrokinetic enhanced bioventing of gasoline in clayey soil: A case history

International Nuclear Information System (INIS)

Loo, W.W.; Wang, I.S.; Fan, J.

1994-01-01

This paper presents a case history on the bioventing of gasoline in soil with electrokinetic enhancement. The gasoline in soil was related to a 10,000-gallon underground storage tank spill, San Diego, California. The gasoline soil plume covers an area of about 2,400 square feet and to a depth of about 30 feet. The upper 15 feet of the soil plume consists of highly conductive marine clay. The lower 15 feet of the soil plume consists of dense cemented conglomerate sandstone. The gasoline concentration in the soil plume range from 100 to 2,200 mg/Kg(ppm) and the target cleanup level is below 100 ppm. Total gasoline in soil plume is estimated at about 1,000 pounds of gasoline in about 3,500 tons of soil. The soil remediation effort was completed after about 90 days of treatment. The concentration of gasoline in soil after treatment was way below the proposed cleanup level of less than 100 mg/Kg(ppm). The cost of treatment is about $50 per ton for this advanced soil treatment process which provides a cost effective solution to this soil plume with minimum disruption to business operation at the facility

Atomization and spray characteristics of bioethanol and bioethanol blended gasoline fuel injected through a direct injection gasoline injector

International Nuclear Information System (INIS)

Park, Su Han; Kim, Hyung Jun; Suh, Hyun Kyu; Lee, Chang Sik

2009-01-01

The focus of this study was to investigate the spray characteristics and atomization performance of gasoline fuel (G100), bioethanol fuel (E100), and bioethanol blended gasoline fuel (E85) in a direct injection gasoline injector in a gasoline engine. The overall spray and atomization characteristics such as an axial spray tip penetration, spray width, and overall SMD were measured experimentally and predicted by using KIVA-3V code. The development process and the appearance timing of the vortices in the test fuels were very similar. In addition, the numerical results accurately described the experimentally observed spray development pattern and shape, the beginning position of the vortex, and the spray breakup on the spray surface. Moreover, the increased injection pressure induced the occurrence of a clear circular shape in the downstream spray and a uniform mixture between the injected spray droplets and ambient air. The axial spray tip penetrations of the test fuels were similar, while the spray width and spray cone angle of E100 were slightly larger than the other fuels. In terms of atomization performance, the E100 fuel among the tested fuels had the largest droplet size because E100 has a high kinematic viscosity and surface tension.

40 CFR 63.650 - Gasoline loading rack provisions.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Gasoline loading rack provisions. 63... loading rack provisions. (a) Except as provided in paragraphs (b) through (c) of this section, each owner or operator of a Group 1 gasoline loading rack classified under Standard Industrial Classification...

46 CFR 169.629 - Compartments containing gasoline machinery or fuel tanks.

Science.gov (United States)

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Compartments containing gasoline machinery or fuel tanks. 169.629 Section 169.629 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) NAUTICAL... gasoline machinery or fuel tanks. Spaces containing gasoline machinery or fuel tanks must have natural...

Misunderstood markets: The case of California gasoline

Science.gov (United States)

Thompson, Jennifer Ruth

In 1996, the California Air Resources Board (CARB) implemented a new benchmark for cleaner burning gasoline that is unique to California. Since then, government officials have often expressed concern that the uniqueness of petroleum products in California segregates the industry, allowing for gasoline prices in the State that are too high and too volatile. The growing concern about the segmentation of the California markets lends itself to analysis of spatial pricing. Spatial price spreads of wholesale gasoline within the state exhibit some characteristics that seem, on the surface, inconsistent with spatial price theory. Particularly, some spatial price spreads of wholesale gasoline appear larger than accepted transportation rates and other spreads are negative, giving a price signal for transportation against the physical flow of product. Both characteristics suggest some limitation in the arbitrage process. Proprietary data, consisting of daily product prices for the years 2000 through 2002, disaggregated by company, product, grade, and location is used to examine more closely spatial price patterns. My discussion of institutional and physical infrastructure outlines two features of the industry that limit, but do not prohibit, arbitrage. First, a look into branding and wholesale contracting shows that contract terms, specifically branding agreements, reduces the price-responsiveness of would-be arbitrageurs. Second, review of maps and documents illustrating the layout of physical infrastructure, namely petroleum pipelines, confirms the existence of some connections among markets. My analysis of the day-of-the-week effects on wholesale prices demonstrates how the logistics of the use of transportation infrastructure affect market prices. Further examination of spatial price relationships shows that diesel prices follow closely the Augmented Law of One Price (ALOP), and that branding agreements cause gasoline prices to deviate substantially ALOP. Without branding

Using stable isotope analysis to discriminate gasoline on the basis of its origin.

Science.gov (United States)

Heo, Su-Young; Shin, Woo-Jin; Lee, Sin-Woo; Bong, Yeon-Sik; Lee, Kwang-Sik

2012-03-15

Leakage of gasoline and diesel from underground tanks has led to a severe environmental problem in many countries. Tracing the production origin of gasoline and diesel is required to enable the development of dispute resolution and appropriate remediation strategies for the oil-contaminated sites. We investigated the bulk and compound-specific isotopic compositions of gasoline produced by four oil companies in South Korea: S-Oil, SK, GS and Hyundai. The relative abundance of several compounds in gasoline was determined by the peak height of the major ion (m/z 44). The δ(13)C(Bulk) and δD(Bulk) values of gasoline produced by S-Oil were significantly different from those of SK, GS and Hyundai. In particular, the compound-specific isotopic value (δ(13)C(CSIA)) of methyl tert-butyl ether (MTBE) in S-Oil gasoline was significantly lower than that of gasoline produced by other oil companies. The abundance of several compounds in gasoline, such as n-pentane, MTBE, n-hexane, toluene, ethylbenzene and o-xylene, differed widely among gasoline from different oil companies. This study shows that gasoline can be forensically discriminated according to the oil company responsible for its manufacture using stable isotope analysis combined with multivariate statistical analysis. Copyright © 2012 John Wiley & Sons, Ltd.

Comparison Pore Aggregate Levels After Extraction With Solvents Pertamax Plus And Gasoline

Science.gov (United States)

Anggraini, Muthia

2017-12-01

Loss of asphalt content extraction results become problems in Field Work For implementing parties. The use of solvents with high octane (pertamax plus) for the extraction, dissolving the asphalt more than gasoline. By comparing the levels of aggregate pores after using solvent extraction pertamax plus compared to gasoline could answer that pertamax plus more solvent dissolves the bitumen compared to gasoline. This study aims to obtain comparative levels of porous aggregate mix AC-WC after using solvent extraction pertamax plus compared to gasoline. This study uses the aggregate that has been extracted from the production of asphalt mixtures, when finisher and after compaction field. The method used is the assay of coarse and fine aggregate pores, extraction of bitumen content to separate the aggregate with bitumen. Results of testing the total absorption after extraction using a solvent preta max plus in the production of asphalt mixtures 0.80%, while gasoline solvent 0.67% deviation occurs 0.13%. In the finisher after the solvent extraction preta max plus 0.77%, while 0.67% gasoline solvent occurs deviation of 0.1%. At the core after extraction and solvent pertamax plus 0.71%, while gasoline solvent 0.60% 0.11% deviation occurs. The total water absorption after extraction using a solvent pertamax plus greater than gasoline. This proves that the solvent dissolves pertamax plus more asphalt than gasoline.

Observations of the effects of soil venting on separate-phase hydrocarbons

International Nuclear Information System (INIS)

Geselbracht, L.; Giattino, R.; Landry, D.

1992-01-01

At some point after an unwanted gasoline release, the subsurface environment comes to a new equilibrium which includes vapor and liquid phase gasoline in the unsaturated zone, liquid phase gasoline floating on the groundwater surface, and dissolved gasoline constituents within the groundwater. While soil vapor extraction has been shown to be an effective way to mitigate vadose zone impact, it has received little consideration as a method to remove bulk liquid-phase gasoline. This paper attempts to show this methods effectiveness and advantages in attenuating liquid-phase gasoline plumes

Experimental study on emissions and performance of an internal combustion engine fueled with gasoline and gasoline/n-butanol blends

International Nuclear Information System (INIS)

Elfasakhany, Ashraf

2014-01-01

Highlights: • Using of 3 and 7 vol.% n-butanol blends in SI engine is studied for the first time. • Engine performance and emissions depend on both engine speed and blend rates. • CO and UHC for blended fuels are maximum at 3000–3100 r/min. • The higher the rate of n-butanol, the lower the emissions and performance. • This study strongly supports using low blend rates of n-butanol (<10 vol.%) in ICE. - Abstract: In this paper, exhaust emissions and engine performance have been experimentally studied for neat gasoline and gasoline/n-butanol blends in a wide range of working speeds (2600–3400 r/min) without any tuning or modification on the gasoline engine systems. The experiment has the ability of evaluating performance and emission characteristics, such as break power, torque, in-cylinder pressure, volumetric efficiency, exhaust gas temperature and concentrations of CO 2 , CO and UHC. Results of the engine test indicated that using n-butanol–gasoline blended fuels slightly decrease the output torque, power, volumetric efficiency, exhaust gas temperature and in-cylinder pressure of the engine as a result of the leaning effect caused by the n-butanol addition; CO, CO 2 and UHC emissions decrease dramatically for blended fuels compared to neat gasoline because of the improved combustion since n-butanol has extra oxygen, which allows partial reduction of the CO and UHC through formation of CO 2 . It was also noted that the exhaust emissions depend on the engine speed rather than the n-butanol contents

Performance and emissions of gasoline blended with terpineol as an octane booster

KAUST Repository

Vallinayagam, R.

2016-11-10

This study investigates the effect of using terpineol as an octane booster for gasoline fuel. Unlike ethanol, terpineol is a high energy density biofuel that is unlikely to result in increased volumetric fuel consumption when used in engines. In this study, terpineol is added to non-oxygenated FACE F gasoline (Research Octane Number = 94.5) in volumetric proportions of 10%, 20% and 30% and tested in a single cylinder spark ignited engine. The performance of terpineol blended fuels are compared against a standard oxygenated EURO V (ethanol blended) gasoline. It was determined that the addition of terpineol to FACE F gasoline enhanced the octane number of the blend, resulting in improved brake thermal efficiency and total fuel consumption. For FACE F + 30% terpineol, break thermal efficiency was improved by 12.1% over FACE F gasoline at full load for maximum brake torque operating point, and similar performance as EURO V gasoline was achieved. Due to its high energy density, total fuel consumption was reduced by 6.2% and 9.7% with 30% terpineol in the blend when compared to FACE F gasoline at low and full load conditions, respectively. Gaseous emissions such as total hydrocarbon and carbon monoxide emission were reduced by 36.8% and 22.7% for FACE F + 30% terpineol compared to FACE F gasoline at full load condition. On the other hand, nitrogen oxide and soot emissions are increased for terpineol blended FACE F gasoline when compared to FACE F and EURO V gasoline. © 2016 Elsevier Ltd

Genotoxic Effects of Exposure to Gasoline Fumes on Petrol Pump Workers.

Science.gov (United States)

Shaikh, Amrin; Barot, Darshana; Chandel, Divya

2018-04-01

Petrol pump workers are occupationally exposed to gasoline and its fumes consisting of several mutagenic chemicals. To evaluate the genotoxic effects of exposure to gasoline fumes on petrol pump workers. The study groups included 70 petrol pump workers (exposed group) and 70 healthy age-matched individuals with no known exposure (comparison group). Buccal micronucleus cytome assay (BMCyt) was performed to check the genotoxicity caused due to inhalation of gasoline fumes. The frequencies of micronucleated cells, nuclear bud, condensed chromatin cells, karyorrhectic cells, pyknotic cells, and karyolytic cells were significantly higher in the exposed workers compared to the comparison group. Exposure to gasoline fumes is associated with increased frequency of cell abnormalities. This may lead to various health consequences including cancer in those occupationally exposed to gasoline fumes.

Gasoline Biodesulfurization DE-FC07-97ID13570 FINAL REPORT; FINAL

International Nuclear Information System (INIS)

Pienkos, Philip T.

2002-01-01

Nine strains were identified to grow with gasoline as sole sulfur source. Two different genes were cloned from Gordonia terrae KGB1 and tested for the ability to support gasoline BDS. The first of these, fmoA, was cloned by screening a KGB1 gene library for the ability to convert indole to indigo (a sulfur-regulated capability in KGB1). The fmoA gene was overexpressed in a gasoline tolerant strain of Pseudomonas putida PpG1 and the recombinant strain was shown to convert thiophene to a dimer of thiophene sulfoxide at rates nearly two orders of magnitude higher than KGB1 could catalyze the reaction. Despite this high activity the recombinant PpG1 was unable to demonstrate any activity against gasoline either in shake flask or in bench-scale gasoline BDS bioreactor. A second gene (toeA) was cloned from KGB1 and shown to support growth of Rhodococcus erythropolis JB55 on gasoline. The toeA gene was also identified in another gasoline strain T. wratislaviensis EMT4, and was identified as a homolog of dszA from R. erythropolis IGTS8. Expression of this gene in JB55 supported conversion of DBTO2 (the natural substrate for DszA) to HPBS, but activity against gasoline was low and BDS results were inconsistent. It appeared that activity was directed against C2- and C3-thiophenes. Efforts to increase gene expression by plasmid manipulation, by addition of flavin reductase genes, or by expression in PpG1 were unsuccessful. The DszC protein (DBT monooxygenase) from IGTS8 has very little activity against the sulfur compounds in gasoline, but a mutant enzyme with a substitution of phenylalanine for valine at position 261 was shown to have an altered substrate range. This alteration resulted in increased activity against gasoline, with activity towards mainly C3- and C4-thiophenes and benzothiophene. A mutant library of dszB was constructed by RACHITT (W. C. Coco et al., DNA shuffling method for generating highly recombined genes and evolved enzymes. 2001. Nature Biotech. 19

Residential proximity to gasoline service stations and preterm birth.

Science.gov (United States)

Huppé, Vicky; Kestens, Yan; Auger, Nathalie; Daniel, Mark; Smargiassi, Audrey

2013-10-01

Preterm birth (PTB) is a growing public health problem potentially associated with ambient air pollution. Gasoline service stations can emit atmospheric pollutants, including volatile organic compounds potentially implicated in PTB. The objective of this study was to evaluate the relationship between residential proximity to gasoline service stations and PTB. Singleton live births on the Island of Montreal from 1994 to 2006 were obtained (n=267,478). Gasoline service station locations, presence of heavy-traffic roads, and neighborhood socioeconomic status (SES) were determined using a geographic information system. Multivariable logistic regression was used to analyze the association between PTB and residential proximity to gasoline service stations (50, 100, 150, 200, 250, and 500 m), accounting for maternal covariates, neighborhood SES, and heavy-traffic roads. For all distance categories beyond 50 m, presence of service stations was associated with a greater odds of PTB. Associations were robust to adjustment for maternal covariates for distance categories of 150 and 200 m but were nullified when adjusting for neighborhood SES. In analyses accounting for the number of service stations, the likelihood of PTB within 250 m was statistically significant in unadjusted models. Associations were, however, nullified in models accounting for maternal covariates or neighborhood SES. Our results suggest that there is no clear association between residential proximity to gasoline service stations in Montreal and PTB. Given the correlation between proximity of gasoline service stations and SES, it is difficult to delineate the role of these factors in PTB.

Gasoline on hands: preliminary study on collection and persistence.

Science.gov (United States)

Darrer, Melinda; Jacquemet-Papilloud, Joëlle; Delémont, Olivier

2008-03-05

The identification of an arsonist remains one of the most difficult challenges a fire investigation has to face. Seeking and detection of traces of gasoline could provide a valuable information to link a suspect with an arson scene where gasoline was used to set-up the fire. In this perspective, a first study was undertaken to evaluate a simple, fast and efficient method for collecting gasoline from hands, and to assess its persistence over time. Four collection means were tested: PVC, PE and Latex gloves, as well as humidified filter paper. A statistical assessment of the results indicates that Latex and PVC gloves worn for about 20 min, as well as paper filter rubbed on hands, allow an efficient collection of gasoline applied to hands. Due to ease of manipulation and to a reduced amount of volatile compounds detected from the matrix, PVC gloves were selected for the second set of experiments. The evaluation of the persistence of gasoline on hands was then carried out using two initial quantities (500 and 1000 microl). Collection was made with PVC gloves after 0, 30 min, 1, 2 and 4h, on different volunteers. The results show a common tendency of massive evaporation of gasoline during the first 30 min: a continued but non-linear decrease was observed along different time intervals. The results of this preliminary study are in agreement with other previous researches conducted on the detection of flammable liquid residues on clothes, shoes and skin.

78 FR 20102 - Proposed Information Collection Request; Comment Request; Reformulated Gasoline Commingling...

Science.gov (United States)

2013-04-03

... Request; Comment Request; Reformulated Gasoline Commingling Provisions AGENCY: Environmental Protection... information collection request (ICR), ``Reformulated Gasoline Commingling Provisions'' (EPA ICR No.2228.04.... Abstract: EPA would like to continue collecting notifications from gasoline retailers and wholesale...

Deficits in response inhibition in male rats prenatally exposed to vapor condensates made from gasoline containing ethanol at 0% and 15%, but not 85%

Science.gov (United States)

The impact of developmental exposure to inhaled ethanol-gasoline fuel blends is a potential public health concern. We previously reported that rats whose mothers inhaled ethanol (21,000 ppm) during pregnancy had increased levels of anticipatory responding on a choice reaction tim...

Gasoline-related injuries and fatalities in the United States, 1995-2014.

Science.gov (United States)

Drago, Dorothy A

2018-02-12

This descriptive study examines twenty years of gasoline-related fatalities and emergency department treated injuries in the United States, based on data from the US Consumer Product Safety Commission. Thermal burns consistently accounted for the majority (56%) of gasoline-related injuries and for most (82%) gasoline-related deaths, and were commonly (57-71%) associated with the use of gasoline as an accelerant. Poisoning accounted for 13% of injuries and 17% of deaths. The primary poisoning injury pattern was ingestion; the primary fatality pattern was inhalation, with about half of those associated with deliberate abuse. The estimated number of ingestions decreased from 60 to 23% of poisoning-related injuries, while injuries associated with inhalation abuse increased from 6 to 23%. Chemical burns and dermatitis were less represented in the injury data and were primarily associated with gasoline spills or splashes. Gasoline cans reportedly ignited or exploded in about 5% of thermal burn injuries and fatalities. While mandatory requirements for child resistant closures on gasoline cans (a primary intervention) have potentially impacted poisonings, the use of flame mitigation devices to address thermal injuries, if successful, would be a secondary intervention, and could address only a small percentage (about 5%) of injuries and deaths.

Zinc-aluminates for an in situ sulfur reduction in cracked gasoline

Energy Technology Data Exchange (ETDEWEB)

Quintana-Solorzano, R.; Valente, J.S.; Hernandez-Beltran, F.J.; Castillo-Araiza, C.O. [Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas Norte 152 C.P., 07730 Mexico, D.F. (Mexico)

2008-05-30

Using additives remains as an attractive alternative for an in situ sulfur reduction in cracked gasoline since it is a practical, flexible and economical option. Zinc-aluminates prepared by the sol-gel method are used as additives for reducing sulfur in gasoline from the cracking of a high-sulfur feed in a fixed-bed bench reactor. Products distribution and feed conversion are not dramatically altered after incorporating the additive to the base catalyst with some effect on gasoline and its octane number and coke. A decrease in the gasoline sulfur content of up to 35 wt% including benzothiophene, and up to 50% excluding benzothiophene, is observed when blending the zinc-aluminates to the base catalyst, which is caused by lowering the C{sub 1} to C{sub 4} alkyl-thiophenes content. The zinc content of the zinc-aluminates has a positive effect on the gasoline sulfur reduction. It is suggested that together with the direct cracking of adsorbed thiophenic species on the additive, a further gasoline sulfur decrease is possible through cracking of saturated thiophenic species formed by hydrogenation of adsorbed thiophenic species with hydrogen produced in situ in the additive. The obtained results also demonstrate that solids with higher Lewis acidity are not unfailingly the most effective for gasoline sulfur reduction. (author)

Mobile vapor recovery and vapor scavenging unit

International Nuclear Information System (INIS)

Stokes, C.A.; Steppe, D.E.

1991-01-01

This patent describes a mobile anti- pollution apparatus, for the recovery of hydrocarbon emissions. It comprises a mobile platform upon which is mounted a vapor recovery unit for recovering vapors including light hydrocarbons, the vapor recovery unit having an inlet and an outlet end, the inlet end adapted for coupling to an external source of hydrocarbon vapor emissions to recover a portion of the vapors including light hydrocarbons emitted therefrom, and the outlet end adapted for connection to a means for conveying unrecovered vapors to a vapor scavenging unit, the vapor scavenging unit comprising an internal combustion engine adapted for utilizing light hydrocarbon in the unrecovered vapors exiting from the vapor recovery unit as supplemental fuel

Lifecycle optimized ethanol-gasoline blends for turbocharged engines

KAUST Repository

Zhang, Bo

2016-08-16

This study presents a lifecycle (well-to-wheel) analysis to determine the CO2 emissions associated with ethanol blended gasoline in optimized turbocharged engines. This study provides a more accurate assessment on the best-achievable CO2 emission of ethanol blended gasoline mixtures in future engines. The optimal fuel blend (lowest CO2 emitting fuel) is identified. A range of gasoline fuels is studied, containing different ethanol volume percentages (E0–E40), research octane numbers (RON, 92–105), and octane sensitivities (8.5–15.5). Sugarcane-based and cellulosic ethanol-blended gasolines are shown to be effective in reducing lifecycle CO2 emission, while corn-based ethanol is not as effective. A refinery simulation of production emission was utilized, and combined with vehicle fuel consumption modeling to determine the lifecycle CO2 emissions associated with ethanol-blended gasoline in turbocharged engines. The critical parameters studied, and related to blended fuel lifecycle CO2 emissions, are ethanol content, research octane number, and octane sensitivity. The lowest-emitting blended fuel had an ethanol content of 32 vol%, RON of 105, and octane sensitivity of 15.5; resulting in a CO2 reduction of 7.1%, compared to the reference gasoline fuel and engine technology. The advantage of ethanol addition is greatest on a per unit basis at low concentrations. Finally, this study shows that engine-downsizing technology can yield an additional CO2 reduction of up to 25.5% in a two-stage downsized turbocharged engine burning the optimum sugarcane-based fuel blend. The social cost savings in the USA, from the CO2 reduction, is estimated to be as much as $187 billion/year. © 2016 Elsevier Ltd

Development of fuel economy 5W-20 gasoline engine oil; Teinenpi 5W-20 gasoline engine yu no kaihatsu

Energy Technology Data Exchange (ETDEWEB)

Akiyama, K; Ueda, F; Kurono, K; Kawai, H; Sugiyama, S [Toyota Motor Corp., Aichi (Japan)

1997-10-01

A 5W-20 gasoline engine oil which improves vehicle fuel efficiency by more than 1.5% relative to a conventional 5W-30 gasoline engine oil was newly developed. Its high fuel economy performance lasts 10,000 km. The viscosity was optimized to satisfy both fuel economy and antiwear performances. Thiadiazole was used to retain the initial fuel economy performance provided by MoDTC. 5 refs., 7 figs., 2 tabs.

[Inhalation of gasoline and damage to health in workers at gas stations].

Science.gov (United States)

Pranjić, Nurka; Mujagić, H; Pavlović, S

2003-01-01

The aim of this study was to made assessment of chronic health effects in 37 workers exposed to gasoline, and its constituents at gasoline stations between 1985 and 1996. By the study we have involved thirty-seven persons who had been exposed to gasoline for more than five years were examined. The evaluation included a medical/occupational history, hematological and biochemical examination, a physical exam, standardized psychological tests, and ultrasound examination of kidneys and liver. The groups were identical in other common parameters including age, gender (all men), and level of education (P gasoline unexposed controls and 25 workers at gasoline stations exposed to organic lead for only nine months. Peripheral smear revealed basophilic punctuated eritrocytes and reticulocytosis. We found in chronic exposed gasoline workers haematological disorders: mild leukocytosis (7 of 37), lymphocytosis (20 of 37), mild lymhocytopenia (3 of 37), decrease of red blood cells count (11 of 37). Results indicated that they have suffered from liver disorders: lipoid degeneration of liver (14 of 37), chronic functional damages of liver (3 of 37), cirrhosis (1 of 37). Ultrasound examination indicated chronic kidney damages (8 of 37). These results significantly differed from those of controls (P gasoline stations exposed to gasoline for more than 5 years the symptom of depression and decreased reaction time and motor abilities were identified. The summary of diseases of workers exposed to organic lead and gasoline are discussed.

Genotoxic Effects of Exposure to Gasoline Fumes on Petrol Pump Workers

Directory of Open Access Journals (Sweden)

Amrin Shaikh

2018-04-01

Full Text Available Background: Petrol pump workers are occupationally exposed to gasoline and its fumes consisting of several mutagenic chemicals. Objective: To evaluate the genotoxic effects of exposure to gasoline fumes on petrol pump workers. Methods: The study groups included 70 petrol pump workers (exposed group and 70 healthy age-matched individuals with no known exposure (comparison group. Buccal micronucleus cytome assay (BMCyt was performed to check the genotoxicity caused due to inhalation of gasoline fumes. Results: The frequencies of micronucleated cells, nuclear bud, condensed chromatin cells, karyorrhectic cells, pyknotic cells, and karyolytic cells were significantly higher in the exposed workers compared to the comparison group. Conclusion: Exposure to gasoline fumes is associated with increased frequency of cell abnormalities. This may lead to various health consequences including cancer in those occupationally exposed to gasoline fumes.

40 CFR Appendix B to Part 80 - Test Methods for Lead in Gasoline

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Test Methods for Lead in Gasoline B... in Gasoline Method 1—Standard Method Test for Lead in Gasoline by Atomic Absorption Spectrometry 1. Scope. 1.1. This method covers the determination of the total lead content of gasoline. The procedure's...

Proposed standby gasoline rationing plan: public comments

Energy Technology Data Exchange (ETDEWEB)

1978-12-01

Under the proposed plan, DOE would allocate ration rights (rights to purchase gasoline) to owners of registered vehicles. All vehicles in a given class would receive the same entitlement. Essential services would receive supplemental allotments of ration rights as pririty firms. Once every 3 months, ration checks would be mailed out to all vehicle registrants, allotting them a certain amount of ration rights. These checks would then be cashed at Coupon Issuance Points, where the bearer would receive ration coupons to be used at gasoline stations. Large users of gasoline could deposit their allotment checks in accounts at ration banks. Coupons or checks would be freely exchangeable in a white market. A certain percentage of the gasoline supply would be set aside in reserve for use in national emergencies. When the plan was published in the Federal Register, public comments were requested. DOE also solicited comments from private citizens, public interest groups, business and industry, state and local governments. A total of 1126 responses were reveived and these are analyzed in this paper. The second part of the report describes how the comments were classified, and gives a statistical breakdown of the major responses. The last section is a discussion and analysis of theissue raised by commenting agencies, firms, associations, and individuals. (MCW)

Utilization of Renewable Oxygenates as Gasoline Blending Components

Energy Technology Data Exchange (ETDEWEB)

Yanowitz, J.; Christensen, E.; McCormick, R. L.

2011-08-01

This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

PIXE analysis of vehicle exhaust particulate

International Nuclear Information System (INIS)

Shi Xianfeng; Yao Huiying; Liu Bo; Sun Minde; Xu Huawei; Mi Yong; Shen Hao

2001-01-01

PIXE technique on the analysis of vehicle exhaust particulate is introduced. The clement composition and concentration of particulate are obtained. Some elements which are related to environmental pollution such as sulfur lead, silicon and manganese, were analyzed and discussed in detail by PIXE technique Nowadays although unleaded gasoline is widely used, the lead concentration is still very high in exhaust particulate. The concentrations of silicon and manganese in exhaust particulate from different model vehicles are also quite high from measurements. It shows that an evidence for exhaust pollution control could be provided from this work

Long term durability tests of small engines fueled with bio-ethanol / gasoline blends

International Nuclear Information System (INIS)

Tippayawong, N.; Kundhawiworn, N.; Jompakdee, W.

2006-01-01

The paper presents the result of an ongoing research to evaluate performance and wear of small, single cylinder, naturally aspirated, agricultural spark ignition engines using biomass-derived ethanol and gasoline blends. The reference gasoline fuel was selected to be representative of gasoline typically available in Thailand. Long-term engine tests of 10% and 20% ethanol / gasoline blends as well as the reference fuel were performed at a constant speed of 2300 rpm under part load condition up to 200 operation hours for each fuel type. Engine brake power, specific fuel consumption, carbon deposits and surface wear were measured and compared between neat gasoline and ethanol/ gasoline blends. It was found that blended fuels appeared to affect the engine performance in a similar way and compared well with the base gasoline fuel. From the results obtained, it was found that engine brake power and specific fuel consumption changed slightly with running time and were not found to have any significant change between different fuel blends. There were carbon deposits buildup on the spark plug, the intake port and exhaust valve stem for all fuels used. Surface wear was not significantly different in the test engines between neat gasoline or ethanol/gasoline blend fuelling

Process for conversion of lignin to reformulated hydrocarbon gasoline

Science.gov (United States)

Shabtai, Joseph S.; Zmierczak, Wlodzimierz W.; Chornet, Esteban

1999-09-28

A process for converting lignin into high-quality reformulated hydrocarbon gasoline compositions in high yields is disclosed. The process is a two-stage, catalytic reaction process that produces a reformulated hydrocarbon gasoline product with a controlled amount of aromatics. In the first stage, a lignin material is subjected to a base-catalyzed depolymerization reaction in the presence of a supercritical alcohol as a reaction medium, to thereby produce a depolymerized lignin product. In the second stage, the depolymerized lignin product is subjected to a sequential two-step hydroprocessing reaction to produce a reformulated hydrocarbon gasoline product. In the first hydroprocessing step, the depolymerized lignin is contacted with a hydrodeoxygenation catalyst to produce a hydrodeoxygenated intermediate product. In the second hydroprocessing step, the hydrodeoxygenated intermediate product is contacted with a hydrocracking/ring hydrogenation catalyst to produce the reformulated hydrocarbon gasoline product which includes various desirable naphthenic and paraffinic compounds.

40 CFR 80.131 - Agreed upon procedures for GTAB, certain conventional gasoline imported by truck, previously...

Science.gov (United States)

2010-07-01

..., certain conventional gasoline imported by truck, previously certified gasoline used to produce gasoline... gasoline used to produce gasoline, and butane blenders. (a) Attest procedures for GTAB. The following are... conventional gasoline and of RFG produced. Agree the volumes from the tank activity records to the batch volume...

On the road to recovery: Gasoline content regulations and child health.

Science.gov (United States)

Marcus, Michelle

2017-07-01

Gasoline content regulations are designed to curb pollution and improve health, but their impact on health has not been quantified. By exploiting both the timing of regulation and spatial variation in children's exposure to highways, I estimate the effect of gasoline content regulation on pollution and child health. The introduction of cleaner-burning gasoline in California in 1996 reduced asthma admissions by 8% in high exposure areas. Reductions are greatest for areas downwind from highways and heavy traffic areas. Stringent gasoline content regulations can improve child health, and may diminish existing health disparities. Copyright © 2017 Elsevier B.V. All rights reserved.

40 CFR 80.73 - Inability to produce conforming gasoline in extraordinary circumstances.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Inability to produce conforming gasoline in extraordinary circumstances. 80.73 Section 80.73 Protection of Environment ENVIRONMENTAL... Gasoline § 80.73 Inability to produce conforming gasoline in extraordinary circumstances. In appropriate...

Terpineol as a novel octane booster for extending the knock limit of gasoline

KAUST Repository

Vallinayagam, R.

2016-09-16

Improving the octane number of gasoline offers the potential of improved engine combustion, as it permits spark timing advancement without engine knock. This study proposes the use of terpineol as an octane booster for gasoline in a spark ignited (SI) engine. Terpineol is a bio-derived oxygenated fuel obtained from pine tree resin, and has the advantage of higher calorific value than ethanol. The ignition delay time (IDT) of terpineol was first investigated in an ignition quality tester (IQT). The IQT results demonstrated a long ignition delay of 24.7 ms for terpineol and an estimated research octane number (RON) of 104, which was higher than commercial European (Euro V) gasoline. The octane boosting potential of terpineol was further investigated by blending it with a non-oxygenated gasoline (FACE F), which has a RON (94) lower than Euro V gasoline (RON = 97). The operation of a gasoline direct injection (GDI) SI engine fueled with terpineol-blended FACE F gasoline enabled spark timing advancement and improved engine combustion. The knock intensity of FACE F + 30% terpineol was lower than FACE F gasoline at both maximum brake torque (MBT) and knock limited spark advance (KLSA) operating points. Increasing proportions of terpineol in the blend caused peak heat release rate, in-cylinder pressure, CA50, and combustion duration to be closer to those of Euro V gasoline. Furthermore, FACE F + 30% terpineol displayed improved combustion characteristics when compared to Euro V gasoline. © 2016

40 CFR 80.211 - What are the requirements for treating imported gasoline as blendstock?

Science.gov (United States)

2010-07-01

... imported gasoline as blendstock? 80.211 Section 80.211 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Gasoline Sulfur Standards § 80.211 What are the requirements for treating imported gasoline as blendstock...

Ignition of alkane-rich FACE gasoline fuels and their surrogate mixtures

KAUST Repository

Sarathy, Mani

2015-01-01

Petroleum derived gasoline is the most used transportation fuel for light-duty vehicles. In order to better understand gasoline combustion, this study investigated the ignition propensity of two alkane-rich FACE (Fuels for Advanced Combustion Engines) gasoline test fuels and their corresponding PRF (primary reference fuel) blend in fundamental combustion experiments. Shock tube ignition delay times were measured in two separate facilities at pressures of 10, 20, and 40 bar, temperatures from 715 to 1500 K, and two equivalence ratios. Rapid compression machine ignition delay times were measured for fuel/air mixtures at pressures of 20 and 40 bar, temperatures from 632 to 745 K, and two equivalence ratios. Detailed hydrocarbon analysis was also performed on the FACE gasoline fuels, and the results were used to formulate multi-component gasoline surrogate mixtures. Detailed chemical kinetic modeling results are presented herein to provide insights into the relevance of utilizing PRF and multi-component surrogate mixtures to reproduce the ignition behavior of the alkane-rich FACE gasoline fuels. The two FACE gasoline fuels and their corresponding PRF mixture displayed similar ignition behavior at intermediate and high temperatures, but differences were observed at low temperatures. These trends were mimicked by corresponding surrogate mixture models, except for the amount of heat release in the first stage of a two-stage ignition events, when observed. © 2014 The Combustion Institute.

Benzene in Canadian gasoline : report on the effect of the benzene in gasoline regulations 2002

Energy Technology Data Exchange (ETDEWEB)

Guthrie, J. [Environment Canada, Ottawa, ON (Canada); Sabourin, R. [Carleton Univ., Ottawa, ON (Canada); Brunet, E. [Waterloo Univ., ON (Canada)

2003-11-01

The response of primary suppliers to Benzene in Gasoline Regulations was reviewed, and a summary of the effects of those regulations on the composition of gasoline in Canada in 2002 was offered. These regulations, effective July 1, 1999, were designed to provide a new approach to control fuel composition. It allowed suppliers, as a basis for compliance, the option to elect to use a yearly pool average. The benzene emission number (BEN) of gasoline was regulated, and a limit imposed on a per-litre limit for benzene at point of sale. The results indicated that reported benzene levels were significantly reduced, while aromatic levels remained practically unchanged from 1994. Since 1998, rural ambient benzene concentrations decreased by more than 32 per cent, while in urban areas, they decreased by 47 per cent over the same period. The regulated requirements for benzene concentration were met by primary suppliers in Canada in 2002 (with one exception), as were BEN levels. A number of instances of non-compliance with laboratory procedures were discovered during independent audits required for those suppliers who elected to be on on a yearly pool average. Corrective action designed to address these issues was implemented. 41 tabs., 24 figs.

Analysis of physicochemical properties of Mexican gasoline and diesel reformulated with ethanol; Analisis de las propiedades fisicoquimicas de gasolina y diesel mexicanos reformulados con etanol

Energy Technology Data Exchange (ETDEWEB)

Castillo-Hernandez, Patricia; Mendoza-Dominguez, Alberto; Caballero-Mata, Porfirio [Tecnologico de Monterrey, Campus Monterrey, Nuevo Leon (Mexico)]. E-mails: pcastillohdz@gmail.com; mendoza.alberto@itesm.mx; pcaballe@itesm.mx

2012-07-15

High energy prices, environmental issues and increasing importation of fossil fuels has provoked, in some countries, a reorientation of resources towards the development of biofuels that can partially substitute the consumption of fossil fuels. Ethanol is one of the biofuels more commonly used in the world; in the United States, Brazil and Australia gasoline blends that reach up to 85% Ethanol are commercialized. This work presents the results of a physicochemical characterization of commercial Mexican gasoline (Magna and Premium) and diesel blends with 10% vol. and 15% vol. anhydrous Ethanol. The analytical testing included: Research Octane Number, Motor Octane Number, Cetane Number, Reid Vapor Pressure, Distillation Curve and Heating Value. The stability of the blends was also evaluated. The theoretical emissions of CO{sub 2} were calculated based on the results of the physicochemical characterization. The ethanol-gasoline blends increased their Octane Number with respect to the commercial gasoline, while conserving an appropriate Distillation Index. The Cetane Number of the ethanol-diesel blends showed a substantial decrease, while the heating value of gasoline and diesel blends was negatively affected by the addition of ethanol. Nevertheless, taking into account the credits by the use of a renewable fuel, the use of the reformulated gasoline blends would imply a maximum theoretical reduction of 7.5% in CO{sub 2} emissions whereas in the case of ethanol-diesel blends it would represent a 9.2% decrease. [Spanish] Los altos precios de los energeticos, la problematica ambiental y las importaciones de combustibles continuamente a la alza, han ocasionado que algunos paises redirijan sus esfuerzos al desarrollo de biocombustibles con la finalidad de sustituir parcialmente a los combustibles fosiles. El Etanol es uno de los biocombustibles mas usados; Estados Unidos, Brasil y Australia comercializan gasolina con Etanol con una concentracion de hasta 85% en volumen. El

Emissions from Diesel and Gasoline Vehicles Fuelled by Fischer-Tropsch Fuels and Similar Fuels

DEFF Research Database (Denmark)

Larsen, Ulrik; Lundorff, Peter; Ivarsson, Anders

2007-01-01

and an alkylate fuel (Aspen), which was taken to be the ultimate formula of FT gasoline. FT based diesel generally showed good emission performance, whereas the FT based gasoline not necessary lead to lower emissions. On the other hand, the Aspen fuel did show many advantages for the emissions from the gasoline...... vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were...

Motor Gasoline Market Model documentation report

International Nuclear Information System (INIS)

1993-09-01

The purpose of this report is to define the objectives of the Motor Gasoline Market Model (MGMM), describe its basic approach and to provide detail on model functions. This report is intended as a reference document for model analysts, users, and the general public. The MGMM performs a short-term (6- to 9-month) forecast of demand and price for motor gasoline in the US market; it also calculates end of month stock levels. The model is used to analyze certain market behavior assumptions or shocks and to determine the effect on market price, demand and stock level

Changes in the microbial community during bioremediation of gasoline-contaminated soil

Directory of Open Access Journals (Sweden)

Aline Jaime Leal

Full Text Available Abstract We aimed to verify the changes in the microbial community during bioremediation of gasoline-contaminated soil. Microbial inoculants were produced from successive additions of gasoline to municipal solid waste compost (MSWC previously fertilized with nitrogen-phosphorous. To obtain Inoculant A, fertilized MSWC was amended with gasoline every 3 days during 18 days. Inoculant B received the same application, but at every 6 days. Inoculant C included MSWC fertilized with N–P, but no gasoline. The inoculants were applied to gasoline-contaminated soil at 10, 30, or 50 g/kg. Mineralization of gasoline hydrocarbons in soil was evaluated by respirometric analysis. The viability of the inoculants was evaluated after 103 days of storage under refrigeration or room temperature. The relative proportions of microbial groups in the inoculants and soil were evaluated by FAME. The dose of 50 g/kg of inoculants A and B led to the largest CO2 emission from soil. CO2 emissions in treatments with inoculant C were inversely proportional to the dose of inoculant. Heterotrophic bacterial counts were greater in soil treated with inoculants A and B. The application of inoculants decreased the proportion of actinobacteria and increased of Gram-negative bacteria. Decline in the density of heterotrophic bacteria in inoculants occurred after storage. This reduction was bigger in inoculants stored at room temperature. The application of stored inoculants in gasoline-contaminated soil resulted in a CO2 emission twice bigger than that observed in uninoculated soil. We concluded that MSWC is an effective material for the production of microbial inoculants for the bioremediation of gasoline-contaminated soil.

Changes in the microbial community during bioremediation of gasoline-contaminated soil.

Science.gov (United States)

Leal, Aline Jaime; Rodrigues, Edmo Montes; Leal, Patrícia Lopes; Júlio, Aline Daniela Lopes; Fernandes, Rita de Cássia Rocha; Borges, Arnaldo Chaer; Tótola, Marcos Rogério

We aimed to verify the changes in the microbial community during bioremediation of gasoline-contaminated soil. Microbial inoculants were produced from successive additions of gasoline to municipal solid waste compost (MSWC) previously fertilized with nitrogen-phosphorous. To obtain Inoculant A, fertilized MSWC was amended with gasoline every 3 days during 18 days. Inoculant B received the same application, but at every 6 days. Inoculant C included MSWC fertilized with N-P, but no gasoline. The inoculants were applied to gasoline-contaminated soil at 10, 30, or 50g/kg. Mineralization of gasoline hydrocarbons in soil was evaluated by respirometric analysis. The viability of the inoculants was evaluated after 103 days of storage under refrigeration or room temperature. The relative proportions of microbial groups in the inoculants and soil were evaluated by FAME. The dose of 50g/kg of inoculants A and B led to the largest CO 2 emission from soil. CO 2 emissions in treatments with inoculant C were inversely proportional to the dose of inoculant. Heterotrophic bacterial counts were greater in soil treated with inoculants A and B. The application of inoculants decreased the proportion of actinobacteria and increased of Gram-negative bacteria. Decline in the density of heterotrophic bacteria in inoculants occurred after storage. This reduction was bigger in inoculants stored at room temperature. The application of stored inoculants in gasoline-contaminated soil resulted in a CO 2 emission twice bigger than that observed in uninoculated soil. We concluded that MSWC is an effective material for the production of microbial inoculants for the bioremediation of gasoline-contaminated soil. Copyright © 2016 Sociedade Brasileira de Microbiologia. Published by Elsevier Editora Ltda. All rights reserved.

40 CFR 80.1230 - What are the gasoline benzene requirements for refiners and importers?

Science.gov (United States)

2010-07-01

... specified in this paragraph (a). (5) Gasoline produced at foreign refineries that is subject to the gasoline... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What are the gasoline benzene... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline...

A new kind of Molotov? Gasoline-pool chlorinator mixtures.

Science.gov (United States)

Hutches, Katherine; Lord, James

2012-07-01

This paper investigates the reaction between pool chlorinators and gasoline. In particular, the propensity for self-ignition and the resulting chemical products were studied. An organic pool chlorinator was combined with gasoline in varying proportions in an attempt to form a hypergolic mixture. None of the combinations resulted in self-ignition, but larger quantities of chlorinator produced vigorous light-colored smoke and a solid mass containing isocyanuric acid and copper chloride. Additionally, the chlorinating abilities of different commercially available pool chlorinators were explored. When Ca(ClO)(2) and sodium dichloro-s-triazinetrione-based chlorinators were used, the presence of gasoline was still visible after 10 days, despite limited chlorination. The trichloro-s-triazinetrione-based chlorinator, however, caused efficient chlorination of the C(2)- and C(3)-alkylbenzenes, making gasoline no longer identifiable. 2012 American Academy of Forensic Sciences. Published 2012. This article is a U.S. Government work and is in the public domain in the U.S.A.

Effects of policy characteristics and justifications on acceptance of a gasoline tax increase

International Nuclear Information System (INIS)

Kaplowitz, Stan A.; McCright, Aaron M.

2015-01-01

Many economists argue that increasing the gasoline tax is an effective way to reduce fuel consumption. Yet, public support for such a tax increase has been rather low among US residents. We performed eight survey experiments (total N approximately 3000) to examine how selected policy characteristics and persuasive messages influence support for a gasoline tax increase. Several policy characteristics significantly increased support for a gasoline tax increase. Having the increase phased in over five years modestly increased support. Compared with giving the extra revenue to the US Treasury’s General Fund, both refunding the extra revenue equally to all American families and having this revenue used for energy efficient transportation strongly increased support. Support for a gasoline tax increase was not affected by the nature of the mechanism to achieve revenue neutrality. Most people supported a 20 cent per gallon tax increase to repair roads and bridges. Explaining how the gasoline tax increase would reduce fuel consumption slightly increased support for a gasoline tax increase, but neither being informed of the high gasoline prices in other advanced industrial countries nor the actual pump price of gasoline at the time of the experiment influenced support for a gasoline tax increase. - Highlights: • Phasing in the tax increase modestly raised support. • Making the tax increase revenue-neutral increased support. • Using the extra revenue for energy efficiency increased support. • Information on high gasoline prices elsewhere did not influence support. • Variation in actual fuel prices did not influence support.

40 CFR 80.195 - What are the gasoline sulfur standards for refiners and importers?

Science.gov (United States)

2010-07-01

...) The gasoline sulfur standards for refiners and importers, excluding gasoline produced by small... must include in its corporate pool all of the gasoline produced at any refineries owned by the parent... includes in its corporate pool the gasoline produced by any refineries owned by the parent company, and...

40 CFR 80.200 - What gasoline is subject to the sulfur standards and requirements?

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What gasoline is subject to the sulfur... (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Gasoline Sulfur Standards § 80.200 What gasoline is subject to the sulfur standards and requirements? For the purpose of...

40 CFR 63.11132 - What definitions apply to this subpart?

Science.gov (United States)

2010-07-01

... supersede definitions in other parts or subparts. Dual-point vapor balance system means a type of vapor balance system in which the storage tank is equipped with an entry port for a gasoline fill pipe and a.... Bottom filling of gasoline storage tanks is included in this definition. Vapor balance system means a...

Mass balance for lead in the California South Coast Air Basin: An update

International Nuclear Information System (INIS)

Lankey, R.L.; Davidson, C.I.; McMichael, F.C.

1998-01-01

A mass balance for lead for the year 1989 in the South Coast Air Basin has inputs to the atmosphere of 600 ± 190 kg/day and outputs of 580 ± 160 kg/day, showing rough agreement. Stationary sources are responsible for only about 5% of the total lead emissions. The bulk of the lead is emitted from vehicles using leaded gasoline (37%) and unleaded gasoline (15%), as well as from resuspension of previously deposited lead on roads (43%). Over half of the total emitted lead deposits on roads and nearby soil, while about one-third is carried out of the basin by wind. A small amount, less than 10%, is deposited on surfaces throughout the basin. These percentages are approximately the same as those in a mass balance for the same region calculated for 1972, when lead emissions from leaded gasoline were about a factor of 70 greater than leaded gas emissions in 1989. When the lead emissions re used as inputs o a simple continuously stirred flow reactor model for the basin, reasonable, agreement is obtained between calculated and measured concentrations

the reproductive dysfunction effects of gasoline inhalation in albino

African Journals Online (AJOL)

admin

exposure to inhalation gasoline, which generally saturate the ambient air of their workplaces. In this study, we challenged male and female albino rats with gasoline vapour and monitored the endocrine disruptive effects as part of a comprehensive study of the health risks faced by refinery workers in Nigeria. The ultimate.

Testing the Alchian-Allen Theorem: A Study of Consumer Behavior in the Gasoline Market

OpenAIRE

Robert Lawson; Lauren Raymer

2006-01-01

This paper uses a data set of daily sales at a single gasoline station over a seven year period to determine if consumers respond to relative price changes among the three grades of gasoline. Based on the reasoning of Alchian and Allen (1964) and Barzel (1976), market shares of higher quality gasoline should increase at the expense of regular grade gasoline when overall gasoline prices increase. The empirical results do not conform to this expectation. We find instead that the consumers in th...

Gasoline from Kumkol deposit petroleum; Benzin nefti Kumkol`skogo mestorozhdeniya

Energy Technology Data Exchange (ETDEWEB)

Nadirov, A N; Zhizhin, N I; Musaeva, Z G

1997-11-04

Samples of gasoline from petroleum of Kumkol deposit are investigated by chromatographic analysis. It is found, that gasoline is characterizing by increased content of iso-paraffin hydrocarbons. (author) 2 tabs., 1 fig. Suppl. Neft` i gaz Kazakhstana

Optimal gasoline tax in developing, oil-producing countries: The case of Mexico

International Nuclear Information System (INIS)

Antón-Sarabia, Arturo; Hernández-Trillo, Fausto

2014-01-01

This paper uses the methodology of Parry and Small (2005) to estimate the optimal gasoline tax for a less-developed oil-producing country. The relevance of the estimation relies on the differences between less-developed countries (LDCs) and industrial countries. We argue that lawless roads, general subsidies on gasoline, poor mass transportation systems, older vehicle fleets and unregulated city growth make the tax rates in LDCs differ substantially from the rates in the developed world. We find that the optimal gasoline tax is $1.90 per gallon at 2011 prices and show that the estimate differences are in line with the factors hypothesized. In contrast to the existing literature on industrial countries, we show that the relative gasoline tax incidence may be progressive in Mexico and, more generally, in LDCs. - Highlights: • We estimate the optimal gasoline tax for a typical less-developed, oil-producing country like Mexico. • The relevance of the estimation relies on the differences between less-developed and industrial countries. • The optimal gasoline tax is $1.90 per gallon at 2011 prices. • Distance-related pollution damages, accident costs and gas subsidies account for the major differences. • Gasoline tax incidence may be progressive in less developed countries

Product differentiation, competition and prices in the retail gasoline industry

Science.gov (United States)

Manuszak, Mark David

This thesis presents a series of studies of the retail gasoline industry using data from Hawaii. This first chapter examines a number of pricing patterns in the data and finds evidence that gasoline stations set prices which are consistent with a number of forms of price discrimination. The second chapter analyzes various patterns of cross-sectional, cross-market and intertemporal variation in the data to investigate their suitability for use in structural econometric estimation. The remainder of the dissertation consists of specification and estimation of a structural model of supply and demand for retail gasoline products sold at individual gasoline stations. This detailed micro-level analysis permits examination of a number of important issues in the industry, most notably the importance of spatial differentiation in the industry. The third chapter estimates the model and computes new equilibria under a number of asymmetric taxation regimes in order to examine the impact of such tax policies on producer and consumer welfare as well as tax revenue. The fourth chapter examines whether there is any evidence of tacitly collusive behavior in the Hawaiian retail gasoline industry and concludes that, in fact, conduct is fairly competitive in this industry and market.

THE EFFECT OF GASOLINE PRICE ON ECONOMIC SECTORS IN NIGERIA

Directory of Open Access Journals (Sweden)

Philip Ifeakachukwu Nwosa

2013-01-01

Full Text Available This paper examined the long-run and short-run relationship between gasoline price and sectoral output in Nigeria for the period from 1980 to 2010. Six sectors (agriculture; manufacturing; building and construction; wholesale and retail; transportation and communication of the economy were examined. The long run regression estimate showed that gasoline price is a significant determinant output in all sectors examined with exception to the building and construction sector while the short run error correction estimate revealed that only output of the agriculture and the manufacturing sectors of the Nigerian economy is affect by gasoline price increase in the short run. The study recommended among others the need for the government to ensure adequate power supply in order to reduce the over reliance of economics sectors on gasoline as a prime source of power.

Investigations on the effects of ethanol–methanol–gasoline blends in a spark-ignition engine: Performance and emissions analysis

Directory of Open Access Journals (Sweden)

Ashraf Elfasakhany

2015-12-01

Full Text Available This study discusses performance and exhaust emissions from spark-ignition engine fueled with ethanol–methanol–gasoline blends. The test results obtained with the use of low content rates of ethanol–methanol blends (3–10 vol.% in gasoline were compared to ethanol–gasoline blends, methanol–gasoline blends and pure gasoline test results. Combustion and emission characteristics of ethanol, methanol and gasoline and their blends were evaluated. Results showed that when the vehicle was fueled with ethanol–methanol–gasoline blends, the concentrations of CO and UHC (unburnt hydrocarbons emissions were significantly decreased, compared to the neat gasoline. Methanol–gasoline blends presented the lowest emissions of CO and UHC among all test fuels. Ethanol–gasoline blends showed a moderate emission level between the neat gasoline and ethanol–methanol–gasoline blends, e.g., ethanol–gasoline blends presented lower CO and UHC emissions than those of the neat gasoline but higher emissions than those of the ethanol–methanol–gasoline blends. In addition, the CO and UHC decreased and CO2 increased when ethanol and/or methanol contents increased in the fuel blends. Furthermore, the effects of blended fuels on engine performance were investigated and results showed that methanol–gasoline blends presents the highest volumetric efficiency and torque; ethanol–gasoline blends provides the highest brake power, while ethanol–methanol–gasoline blends showed a moderate level of volumetric efficiency, torque and brake power between both methanol–gasoline and ethanol–gasoline blends; gasoline, on the other hand, showed the lowest volumetric efficiency, torque and brake power among all test fuels.

Gasoline demand in Europe. New insights

International Nuclear Information System (INIS)

Pock, Markus

2010-01-01

This study utilizes a panel data set from 14 European countries over the period 1990-2004 to estimate a dynamic model specification for gasoline demand. Previous studies estimating gasoline consumption per total passenger cars ignore the recent increase in the number of diesel cars in most European countries leading to biased elasticity estimates. We apply several common dynamic panel estimators to our small sample. Results show that specifications neglecting the share of diesel cars overestimate short-run income, price and car ownership elasticities. It appears that the results of standard pooled estimators are more reliable than common IV/GMM estimators applied to our small data set. (author)

Gasoline demand in Europe. New insights

Energy Technology Data Exchange (ETDEWEB)

Pock, Markus [Department of Economics and Finance, HealthEcon IHS - Institute for Advanced Studies, Vienna Stumpergasse 56, 1060 Vienna (Austria)

2010-01-15

This study utilizes a panel data set from 14 European countries over the period 1990-2004 to estimate a dynamic model specification for gasoline demand. Previous studies estimating gasoline consumption per total passenger cars ignore the recent increase in the number of diesel cars in most European countries leading to biased elasticity estimates. We apply several common dynamic panel estimators to our small sample. Results show that specifications neglecting the share of diesel cars overestimate short-run income, price and car ownership elasticities. It appears that the results of standard pooled estimators are more reliable than common IV/GMM estimators applied to our small data set. (author)

Effect Of Ginger Extract On Gasoline Associated Immunitoxicities In ...

African Journals Online (AJOL)

Effect of ginger extracts on gasoline associated immunotoxicities in wistar rats was studied. Fifteen wistar rats were randomly assigned into three study groups. Group 1 was the control, while groups 2 and 3 received daily treatment by inhalation of gasoline vapour. The animals in group3 were also treated with 100mg ...

26 CFR 1.164-5 - Certain retail sales taxes and gasoline taxes.

Science.gov (United States)

2010-04-01

... 26 Internal Revenue 2 2010-04-01 2010-04-01 false Certain retail sales taxes and gasoline taxes. 1....164-5 Certain retail sales taxes and gasoline taxes. For taxable years beginning before January 1...) and tax on the sale of gasoline, diesel fuel or other motor fuel paid by the consumer (other than in...

76 FR 9013 - Agency Information Collection Activities; Proposed Collection; Comment Request; Detergent Gasoline

Science.gov (United States)

2011-02-16

... Activities; Proposed Collection; Comment Request; Detergent Gasoline AGENCY: Environmental Protection Agency... this action are those who (1) Manufacture gasoline, post-refinery component, or detergent additives, (2) blend detergent additives into gasoline or post-refinery component, or (3) transport or receive a...

Particle and carbon dioxide emissions from passenger vehicles operating on unleaded petrol and LPG fuel

International Nuclear Information System (INIS)

Ristovski, Z.D.; Jayaratne, E.R.; Morawska, L.; Ayoko, G.A.; Lim, M.

2005-01-01

A comprehensive study of the particle and carbon dioxide emissions from a fleet of six dedicated liquefied petroleum gas (LPG) powered and five unleaded petrol (ULP) powered new Ford Falcon Forte passenger vehicles was carried out on a chassis dynamometer at four different vehicle speeds-0 (idle), 40, 60, 80 and 100 km h -1 . Emission factors and their relative values between the two fuel types together with a statistical significance for any difference were estimated for each parameter. In general, LPG was found to be a 'cleaner' fuel, although in most cases, the differences were not statistically significant owing to the large variations between emissions from different vehicles. The particle number emission factors ranged from 10 11 to 10 13 km -1 and was over 70% less with LPG compared to ULP. Corresponding differences in particle mass emission factor between the two fuels were small and ranged from the order of 10 μg km -1 at 40 to about 1000 μg km -1 at 100 km h -1 . The count median particle diameter (CMD) ranged from 20 to 35 nm and was larger with LPG than with ULP in all modes except the idle mode. Carbon dioxide emission factors ranged from about 300 to 400 g km -1 at 40 km h -1 , falling with increasing speed to about 200 g km -1 at 100 km h -1 . At all speeds, the values were 10% to 18% greater with ULP than with LPG

The taxation effect on gasoline price asymmetry nexus: Evidence from both sides of the Atlantic

International Nuclear Information System (INIS)

Polemis, Michael L.; Fotis, Panagiotis N.

2014-01-01

This paper explores the degree of competition in various gasoline markets and infers possible causes of price asymmetry across the globe. For this purpose we use the Dynamic Ordinary Least Square method in order to estimate price asymmetry in twelve European countries and the United States for a sample of weekly observations which spans the period from June 1996 to August 2011. The results indicate the common perception that less competitive gasoline markets exhibit price asymmetry, while highly competitive gasoline markets follow a symmetric price adjustment path. Finally, the inclusion of taxes (VAT and excise tax) into retail gasoline prices, supports the existence of price asymmetry in many European countries. - Highlights: • We examine the possible causes of gasoline price asymmetry across the globe. • We investigate the effect of taxation on the retail gasoline price adjustments. • There is a symmetric gasoline price response in the EU wholesale level. • Less competitive gasoline markets exhibit price asymmetry. • The oligopolistic structure of the gasoline markets inflates price asymmetry

Changes in the microbial community during bioremediation of gasoline-contaminated soil

OpenAIRE

Leal, Aline Jaime; Rodrigues, Edmo Montes; Leal, Patr?cia Lopes; J?lio, Aline Daniela Lopes; Fernandes, Rita de C?ssia Rocha; Borges, Arnaldo Chaer; T?tola, Marcos Rog?rio

2016-01-01

Abstract We aimed to verify the changes in the microbial community during bioremediation of gasoline-contaminated soil. Microbial inoculants were produced from successive additions of gasoline to municipal solid waste compost (MSWC) previously fertilized with nitrogen-phosphorous. To obtain Inoculant A, fertilized MSWC was amended with gasoline every 3 days during 18 days. Inoculant B received the same application, but at every 6 days. Inoculant C included MSWC fertilized with N–P, but no gas...

Effects of turbulence enhancement on combustion process using a double injection strategy in direct-injection spark-ignition (DISI) gasoline engines

International Nuclear Information System (INIS)

Kim, Taehoon; Song, Jingeun; Park, Sungwook

2015-01-01

Highlights: • Using double injection strategy, turbulent kinetic energy can be improved with slight decrease in mixture homogeneity. • Retarded first injection timing reduces vapor fuel loss to intake port. • Double injection increases tumble intensity. • High turbulent intensity caused by double injection increases flame propagation speed. - Abstract: Direct-injection spark-ignition (DISI) gasoline engines have been spotlighted due to their high thermal efficiency. Increase in the compression ratio that result from the heat absorption effect of fuel vaporization induces higher thermal efficiency than found in port fuel injection (PFI) engines. Since fuel is injected at the cylinder directly, various fuel injection strategies can be used. In this study, turbulent intensity was improved by a double injection strategy while maintaining mixture homogeneity. To analyze the turbulence enhancement effects using the double injection strategy, a side fuel injected, homogeneous-charge-type DISI gasoline engine with a multi-hole-type injector was utilized. The spray model was evaluated using experimental data for various injection pressures and the combustion model was evaluated for varied ignition timing. First and second injection timing was swept by 20 degree interval. The turbulent kinetic energy and mixture inhomogeneity index were mapped. First injection at the middle of the intake stroke and second injection early in the compression stroke showed improved turbulent characteristics that did not significantly decrease with mixture homogeneity. A double injection case that showed improved turbulent intensity while maintaining an adequate level of mixture homogeneity and another double injection case that showed significantly improved turbulent intensity with a remarkable decrease in mixture homogeneity were considered for combustion simulation. We found that the improved turbulent intensity increased the flame propagation speed. Also, the mixture homogeneity

Comparative exergy analyses of gasoline and hydrogen fuelled ices

International Nuclear Information System (INIS)

Nieminen, J.; Dincer, I.; Yang, Y.

2009-01-01

Comparative exergy models for naturally aspirated gasoline and hydrogen fuelled spark ignition internal combustion engines were developed according to the second laws of thermodynamics. A thorough graphical analysis of heat transfer, work, thermo mechanical, and intake charge exergy functions was made. An irreversibility function was developed as a function of entropy generation and graphed. A second law analysis yielded a proportional exergy distribution as a fraction of the intake charge exergy. It was found that the hydrogen fuelled engine had a greater proportion of the intake charge exergy converted into work exergy, indicating a second law efficiency of 50.13% as opposed to 44.34% for a gasoline fuelled engine. The greater exergy due to heat transfer or thermal availability associated with the hydrogen fuelled engine is postulated to be a part of the reason for decreased work output of a hydrogen engine. Finally, a second law analysis of both hydrogen and gasoline combustion reactions indicate a greater combustion irreversibility associated with gasoline combustion. A percentage breakdown of the combustion irreversibilities were also constructed according to information found in literature searches. (author)

Emission consequences of introducing bio ethanol as a fuel for gasoline cars

DEFF Research Database (Denmark)

Winther, Morten Mentz; Møller, Flemming; Jensen, Thomas Christian

2012-01-01

This article describes the direct vehicle emission impact of the future use of bio ethanol as a fuel for gasoline cars in Denmark arising from the vehicle specific fuel consumption and emission differences between neat gasoline (E0) and E5/E85 gasoline-ethanol fuel blends derived from emission......% in 2030. As predicted by the vehicle specific emission differences the calculated emission impacts of using bio ethanol are small for NOx, VOC and CO. Instead, for FS, BS1 and BS2 large emission reductions are due to the gradually cleaner new sold gasoline cars and the decline in total mileage until...

Comparative analysis of the Performance and Emission Characteristics of ethanol-butanol-gasoline blends

Science.gov (United States)

Taneja, Sumit; Singh, Perminderjit, Dr; Singh, Gurtej

2018-02-01

Global warming and energy security being the global problems have shifted the focus of researchers on the renewable sources of energy which could replace petroleum products partially or as a whole. Ethanol and butanol are renewable sources of energy which can be produced through fermentation of biomass. A lot of research has already been done to develop suitable ethanol-gasoline blends. In contrast very little literature available on the butanol-gasoline blends. This research focuses on the comparison of ethanol-gasoline fuels with butanol-gasoline fuels with regard to the emission and performance in an SI engine. Experiments were conducted on a variable compression ratio SI engine at 1600 rpm and compression ratio 8. The experiments involved the measurement of carbon monoxide, carbon dioxide, oxides of nitrogen and unburned hydrocarbons emission and among performance parameters brake specific fuel consumption and brake thermal efficiency were recorded at three loads of 2.5kgs (25%), 5kgs (50%) and 7.5kgs (75%). Results show that ethanol and butanol content in gasoline have decreased brake specific fuel consumption, carbon monoxide and unburned hydrocarbon emissions while the brake thermal efficiency and oxides of nitrogen are increased. Results indicate thatbutanol-gasoline blends have improved brake specific fuel consumption, carbon monoxide emissions in an SI engine as compared to ethanol-gasoline blends. The carbon dioxide emissions and brake thermal efficiencies are comparable for ethanol-gasoline blends and butanol-gasoline blends. The butanol content has a more adverse effect on emissions of oxides of nitrogen than ethanol.

Gasoline reformulation to reduce exhaust emissions in Finnish conditions. Influence of sulphur and benzene contents of gasoline on exhaust emissions

International Nuclear Information System (INIS)

Kytoe, M.; Aakko, P.; Lappi, M.

1994-01-01

At earlier stages of the study it was found that the exhaust emissions from cars are reduced when using fuels with no more than 4 wt% of oxygen. At this stage of the study the work focused on impacts of the sulphur and benzene content of gasoline on exhaust emissions in Finland. Sulphur in gasoline retards the operation of the catalyst, and consequently the exhaust emissions of catalyst cars increase if the sulphur content of the fuel increases. In the present study, evaporation during refuelling were measured for fuels with varying vapour pressures and benzene contents of gasoline. The total hydrocarbon evaporation was reduced by 22 % (10 g) when the vapour pressure of gasoline was reduced from 85 kPa to 65 kPa. Correspondingly, benzene evaporation during refuelling was reduced to a third when the benzene content of the fuel was reduced from the level of 3 wt% to 1 wt%. The reduction of the sulphur content of gasoline from 500 ppm to 100 ppm affected regulated exhaust emissions from the catalyst car at +22 deg C as follows: CO emission was reduced on average by 14 % (0.175 g/km), CH emission by 7 % (0.010 g/km) and NO x emission by 9 % (0.011 g/km). At-7 deg C the percentual changes were smaller. When the benzene content of the fuel was reduced from 3 wt% to 1 wt%, the benzene emission from the catalyst cars was reduced by 20-30 % and from the non-catalyst cars on average by 30 % both at +22 deg C and -7 deg C. The benzene emission ranged 3-22 mg/km for the catalyst cars and 40-90 mg/km for the non-catalyst cars at +22 deg C in the FTP test

Do gasoline prices exhibit asymmetry? Not usually

International Nuclear Information System (INIS)

Douglas, Christopher C.

2010-01-01

Previous studies have found evidence of asymmetric price adjustment in U.S. retail gasoline prices in that gasoline prices rise more rapidly in response to a cost increase than fall in response to a cost decrease. By estimating a threshold cointegration model that allows for multiple regimes, I am able to test how sensitive this result is to outlying observations. In contrast to previous studies, I find little evidence of asymmetry for the vast majority of observations and that the asymmetry is being driven by a small number of outlying observations. (author)

Catalysts for producing high octane-blending value olefins for gasoline

NARCIS (Netherlands)

Golombok, M.; Bruijn, de J.N.H.

2001-01-01

New restrictions on gasoline components mean that oxygenates and aromatics must be replaced by other high octane components. The dimerization of linear butene to form high octane gasoline blending components is evaluated under liquid phase reaction conditions over a number of different heterogeneous

40 CFR 80.385 - What acts are prohibited under the gasoline sulfur program?

Science.gov (United States)

2010-07-01

... gasoline sulfur program? 80.385 Section 80.385 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Violation Provisions § 80.385 What acts are prohibited under the gasoline sulfur program? No person shall: (a...

40 CFR 80.1005 - What acts are prohibited under the gasoline toxics program?

Science.gov (United States)

2010-07-01

... gasoline toxics program? 80.1005 Section 80.1005 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Toxics Violation Provisions § 80.1005 What acts are prohibited under the gasoline toxics program? No person shall: (a...

The impact of ethanol production on US and regional gasoline markets

International Nuclear Information System (INIS)

Du Xiaodong; Hayes, Dermot J.

2009-01-01

This study quantifies the impact of increasing ethanol production on wholesale/retail gasoline prices employing pooled regional time-series data from January 1995 to March 2008. We find that the growth in ethanol production kept wholesale gasoline prices $0.14/gallon lower than would otherwise have been the case. The negative impact of ethanol on retail gasoline prices is found to vary considerably across regions. The Midwest region has the biggest impact at $0.28/gallon, while the Rocky Mountain region had the smallest impact at $0.07/gallon. The results also indicate that the ethanol-induced reduction in gasoline prices comes at the expense of refiners' profits. We find a net welfare loss of $0.5 billion from the ethanol support policies in multiple markets.

Pollutant emissions from gasoline combustion. 1. Dependence on fuel structural functionalities.

Science.gov (United States)

Zhang, Hongzhi R; Eddings, Eric G; Sarofim, Adel F

2008-08-01

To study the formation of air pollutants and soot precursors (e.g., acetylene, 1,3-butadiene, benzene, and higher aromatics) from aliphatic and aromatic fractions of gasoline fuels, the Utah Surrogate Mechanisms is extended to include submechanisms of gasoline surrogate compounds using a set of mechanism generation techniques. The mechanism yields very good predictions of species concentrations in premixed flames of n-heptane, isooctane, benzene, cyclohexane, olefins, oxygenates, and gasoline using a 23-component surrogate formulation. The 1,3-butadiene emission comes mainly from minor fuel fractions of olefins and cyclohexane. The benzene formation potential of gasoline components shows the following trends as functions of (i) chemical class: n-paraffins produced by the real fuel should have priority when selecting candidate surrogate components for combustion simulations.

40 CFR 80.1235 - What gasoline is subject to the benzene requirements of this subpart?

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What gasoline is subject to the... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Gasoline Benzene Requirements § 80.1235 What gasoline is subject to the benzene requirements of...

Analysis of the French gasoline market since the deregulation of prices

International Nuclear Information System (INIS)

Lantz, F.; Ioannidis, C.

1992-01-01

In this paper, we have investigated the behaviour of gasoline prices in France over the period 1980-1990. We have established that the price liberalization measures introduced in 1985 were successful in integrating the domestic market to the European one, but the process of integration is still in progress. The behaviour of the Tax Authorities did not inhibit price flexibility with final gasoline prices responding symmetrically to international gasoline price changes. 8 refs., 2 figs., 5 tabs

Value of time: Speeding behavior and gasoline prices

OpenAIRE

Wolff, Hendrik

2012-01-01

Do drivers reduce speeds when gasoline prices are high? Previous research investigating this energy conservation hypothesis produced mixed results. We take a fresh look at the data and estimate a significant negative relationship between speeding and gasoline prices. This presents a new methodology of deriving the 'Value of Time' (VOT) based on the intensive margin (previous VOT studies compare across the extensive margin) which has important advantages to circumvent potential omitted variabl...

Measuring global gasoline and diesel price and income elasticities

International Nuclear Information System (INIS)

Dahl, Carol A.

2012-01-01

Price and income elasticities of transport fuel demand have numerous applications. They help forecast increases in fuel consumption as countries get richer, they help develop appropriate tax policies to curtail consumption, help determine how the transport fuel mix might evolve, and show the price response to a fuel disruption. Given their usefulness, it is understandable why hundreds of studies have focused on measuring such elasticities for gasoline and diesel fuel consumption. In this paper, I focus my attention on price and income elasticities in the existing studies to see what can be learned from them. I summarize the elasticities from these historical studies. I use statistical analysis to investigate whether income and price elasticities seem to be constant across countries with different incomes and prices. Although income and price elasticities for gasoline and diesel fuel are not found to be the same at high and low incomes and at high and low prices, patterns emerge that allow me to develop suggested price and income elasticities for gasoline and diesel demand for over one hundred countries. I adjust these elasticities for recent fuel mix policies, and suggest an agenda of future research topics. - Research highlights: ► Surveyed econometric studies of transport fuel demand. ► Developed price elasticities of demand for gasoline and diesel fuel for 120 countries. ► Developed income elasticities of demand for gasoline and diesel fuel for 120 countries. ► Suggested a research agenda for future work.

Emissions from Road Vehicles Fuelled by Fischer Tropsch Based Diesel and Gasoline

Energy Technology Data Exchange (ETDEWEB)

Larsen, U; Lundorf, P; Ivarsson, A; Schramm, J [Technical University of Denmark (Denmark); Rehnlund, B [Atrax Energi AB (Sweden); Blinge, M [The Swedish Transport Institute (Sweden)

2006-11-15

The described results were carried out under the umbrella of IEA Advanced Motor Fuels Agreement. The purpose was to evaluate the emissions of carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxides (NOx), particulate matter (PM) and polycyclic aromatic hydrocarbons (PAH) from vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were found in this field. In this context measurement according to the Federal Test Procedure (FTP) and the New European Driving Cycle (NEDC) were carried out on a chassis dynamometer with a directly injected gasoline vehicle. Experiments were carried out with a reference fuel, a fuel based 70% on FT and an alkylate fuel (Aspen), which was supposed to be very similar, in many ways, to FT fuel. FT based diesel generally showed good emission performance, whereas the FT based gasoline not necessary lead to lower emissions. On the other hand, the Aspen fuel did show many advantages for the emissions from the gasoline vehicle.

40 CFR 80.815 - What are the gasoline toxics performance requirements for refiners and importers?

Science.gov (United States)

2010-07-01

... toxics requirements of this subpart apply separately for each of the following types of gasoline produced...) The gasoline toxics performance requirements of this subpart apply to gasoline produced at a refinery... not apply to gasoline produced by a refinery approved under § 80.1334, pursuant to § 80.1334(c). (2...

Competition, regulation, and pricing behaviour in the Spanish retail gasoline market

International Nuclear Information System (INIS)

Contin-Pilart, Ignacio; Correlje, Aad F.; Blanca Palacios, M.

2009-01-01

The restructuring of the Spanish oil industry produced a highly concentrated oligopoly in the retail gasoline market. In June 1990, the Spanish government introduced a system of ceiling price regulation in order to ensure that 'liberalization' was accompanied by adequate consumer protection. By 1998, prices were left to the 'free' market. This paper examines the pricing behaviour of the retail gasoline market using multivariate error correction models over the period January 1993 (abolishment of the state monopoly)-December 2004. The results suggest that gasoline retail prices respond symmetrically to increases as well as to decreases in the spot price of gasoline both over the period of price regulation (January 1993-September 1998) and over the period of free market (October 1998-December 2004). However, once the ceiling price regulation was abolished, cooperation emerged between the government and the major operators, Repsol-YPF and Cepsa-Elf, to control the inflation rate. This resulted in a slower rate of adjustment of gasoline retail prices when gasoline spot prices went up, as compared with the European pattern. Finally, the Spanish retail margin was by the end of our timing period of analysis, as in the starting years after the abolishment of the state monopoly, above the European average. This pattern confirms our political economic hypothesis, which suggests that the Spanish government and the oil companies were working together in reducing the inflation, in periods of rising oil and gasoline prices. It is also inferred that explaining the pricing pattern in energy markets may require different hypothesis than the classical perspective, involving just firms taking advantage of market power

Competition, regulation, and pricing behaviour in the Spanish retail gasoline market

Energy Technology Data Exchange (ETDEWEB)

Contin-Pilart, Ignacio [Departamento de Gestion de Empresas, Universidad Publica de Navarra, Campus de Arrosadia, 31006 Pamplona (Spain); Correlje, Aad F. [Section Economics of Infrastructures, Faculty of Technology, Policy and Management, Delft University of Technology, P.O. Box 5015, 2600 GA Delft (Netherlands); Clingendael International Energy Programme (Netherlands); Blanca Palacios, M. [Departamento de Estadistica e Investigacion Operativa, Universidad Publica de Navarra, Campus de Arrosadia, 31006 Pamplona (Spain)

2009-01-15

The restructuring of the Spanish oil industry produced a highly concentrated oligopoly in the retail gasoline market. In June 1990, the Spanish government introduced a system of ceiling price regulation in order to ensure that 'liberalization' was accompanied by adequate consumer protection. By 1998, prices were left to the 'free' market. This paper examines the pricing behaviour of the retail gasoline market using multivariate error correction models over the period January 1993 (abolishment of the state monopoly)-December 2004. The results suggest that gasoline retail prices respond symmetrically to increases as well as to decreases in the spot price of gasoline both over the period of price regulation (January 1993-September 1998) and over the period of free market (October 1998-December 2004). However, once the ceiling price regulation was abolished, cooperation emerged between the government and the major operators, Repsol-YPF and Cepsa-Elf, to control the inflation rate. This resulted in a slower rate of adjustment of gasoline retail prices when gasoline spot prices went up, as compared with the European pattern. Finally, the Spanish retail margin was by the end of our timing period of analysis, as in the starting years after the abolishment of the state monopoly, above the European average. This pattern confirms our political economic hypothesis, which suggests that the Spanish government and the oil companies were working together in reducing the inflation, in periods of rising oil and gasoline prices. It is also inferred that explaining the pricing pattern in energy markets may require different hypothesis than the classical perspective, involving just firms taking advantage of market power. (author)

40 CFR 80.340 - What standards and requirements apply to refiners producing gasoline by blending blendstocks into...

Science.gov (United States)

2010-07-01

... to refiners producing gasoline by blending blendstocks into previously certified gasoline (PCG)? 80... gasoline by blending blendstocks into previously certified gasoline (PCG)? (a) Any refiner who produces...) The sulfur content and volume of each batch of gasoline produced is that of the butane the refiner...

Increasing the octane number of gasoline using functionalized carbon nanotubes

Energy Technology Data Exchange (ETDEWEB)

Kish, Sara Safari [Faculty of Chemistry, Islamic Azad University, North Tehran Branch, Tehran (Iran, Islamic Republic of); Rashidi, Alimorad, E-mail: rashidiam@ripi.ir [Nanotechnology Research Center, Research Institute of Petroleum Industry (RIPI), West Blvd. Azadi Sport Complex, Tehran 14665-1998 (Iran, Islamic Republic of); Aghabozorg, Hamid Reza [Catalysis Research Center, Research Institute of Petroleum Industry (RIPI), Tehran (Iran, Islamic Republic of); Moradi, Leila [Faculty of Chemistry, Kashan University, Kashan (Iran, Islamic Republic of)

2010-03-15

The octane number is one of the characteristics of spark-ignition fuels such as gasoline. Octane number of fuels can be improved by addition of oxygenates such as ethanol, MTBE (methyl tert-butyl ether), TBF (tertiary butyl formate) and TBA (tertiary butyl alcohol) as well as their blends with gasoline that reduce the cost impact of fuels. Carbon nanotubes (CNTs) are as useful additives for increasing the octane number. Functionalized carbon nanotubes containing amide groups have a high reactivity and can react with many chemicals. These compounds can be solubilized in gasoline to increase the octane number. In this study, using octadecylamine and dodecylamine, CNTs were amidated and the amino-functionalized carbon nanotubes were added to gasoline. Research octane number analysis showed that these additives increase octane number of the desired samples. X-ray diffraction (XRD), Fourier transforms infrared (FTIR), X-ray photoelectron spectroscopy (XPS), and thermal gravimetry analyses (TGA) were used for characterization of the prepared functionalized carbon nanotubes.

Increasing the octane number of gasoline using functionalized carbon nanotubes

International Nuclear Information System (INIS)

Kish, Sara Safari; Rashidi, Alimorad; Aghabozorg, Hamid Reza; Moradi, Leila

2010-01-01

The octane number is one of the characteristics of spark-ignition fuels such as gasoline. Octane number of fuels can be improved by addition of oxygenates such as ethanol, MTBE (methyl tert-butyl ether), TBF (tertiary butyl formate) and TBA (tertiary butyl alcohol) as well as their blends with gasoline that reduce the cost impact of fuels. Carbon nanotubes (CNTs) are as useful additives for increasing the octane number. Functionalized carbon nanotubes containing amide groups have a high reactivity and can react with many chemicals. These compounds can be solubilized in gasoline to increase the octane number. In this study, using octadecylamine and dodecylamine, CNTs were amidated and the amino-functionalized carbon nanotubes were added to gasoline. Research octane number analysis showed that these additives increase octane number of the desired samples. X-ray diffraction (XRD), Fourier transforms infrared (FTIR), X-ray photoelectron spectroscopy (XPS), and thermal gravimetry analyses (TGA) were used for characterization of the prepared functionalized carbon nanotubes.

Testing and estimating time-varying elasticities of Swiss gasoline demand

International Nuclear Information System (INIS)

Neto, David

2012-01-01

This paper is intended to test and estimate time-varying elasticities for gasoline demand in Switzerland. For this purpose, a smooth time-varying cointegrating parameters model is investigated in order to describe smooth mutations of the Swiss gasoline demand. The methodology, based on Chebyshev polynomials, is rigorously outlined. Our empirical finding states that the time-invariance assumption does not hold for long-run price and income elasticities. Furthermore they highlight that gasoline demand passed through some periods of sensitivity and non sensitivity with respect to the price. Our empirical statements are of great importance to assess the performance of a gasoline tax as an instrument for CO 2 reduction policy. Indeed, such an instrument can contribute to reduce emissions of greenhouse gases only if the demand is not fully inelastic with respect to the price. Our results suggest that such a carbon-tax would not be always suitable since the price elasticity is found not stable over time and not always significant.

Electrical impedance tomography of the 1995 OGI gasoline release

International Nuclear Information System (INIS)

Daily, W.; Ramirez, A.

1996-01-01

Electrical impedance tomography (EIT) was used to image the plume resulting from a release of 378 liters (100 gallons) of gasoline into a sandy acquifer. Images were made in 5 planes before and 5 times during the release, to generate a detailed picture of the spatial as well as the temporal development of the plume as it spread at the water table. Information of the electrical impedance (both in phase and out of phase voltages) was used or several different frequencies to produce images. We observed little dispersion in the images either before or after the gasoline entered the acquifer. Likewise, despite some laboratory measurements of impedances, there was no evidence of a change in the reactance in the soil because of the gasoline

Diesel engines vs. spark ignition gasoline engines -- Which is ``greener``?

Energy Technology Data Exchange (ETDEWEB)

Fairbanks, J.W. [Dept. of Energy, Washington, DC (United States)

1997-12-31

Criteria emissions, i.e., NO{sub x}, PM, CO, CO{sub 2}, and H{sub 2}, from recently manufactured automobiles, compared on the basis of what actually comes out of the engines, the diesel engine is greener than spark ignition gasoline engines and this advantage for the diesel engine increases with time. SI gasoline engines tend to get out of tune more than diesel engines and 3-way catalytic converters and oxygen sensors degrade with use. Highway measurements of NO{sub 2}, H{sub 2}, and CO revealed that for each model year, 10% of the vehicles produce 50% of the emissions and older model years emit more than recent model year vehicles. Since 1974, cars with SI gasoline engines have uncontrolled emission until the 3-way catalytic converter reaches operating temperature, which occurs after roughly 7 miles of driving. Honda reports a system to be introduced in 1998 that will alleviate this cold start problem by storing the emissions then sending them through the catalytic converter after it reaches operating temperature. Acceleration enrichment, wherein considerable excess fuel is introduced to keep temperatures down of SI gasoline engine in-cylinder components and catalytic converters so these parts meet warranty, results in 2,500 times more CO and 40 times more H{sub 2} being emitted. One cannot kill oneself, accidentally or otherwise, with CO from a diesel engine vehicle in a confined space. There are 2,850 deaths per year attributable to CO from SI gasoline engine cars. Diesel fuel has advantages compared with gasoline. Refinery emissions are lower as catalytic cracking isn`t necessary. The low volatility of diesel fuel results in a much lower probability of fires. Emissions could be improved by further reducing sulfur and aromatics and/or fuel additives. Reformulated fuel has become the term covering reducing the fuels contribution to emissions. Further PM reduction should be anticipated with reformulated diesel and gasoline fuels.

Comparative study on TSPM levels, anions and trace metal concentrations at BARC during the years 2000-2002

International Nuclear Information System (INIS)

Saradhi, I.V.; Prathibha, P.; Kothai, G.; Mahadevan, T.N.; Venkat Raj, V.; Kumar, Shaji C.

2003-01-01

Both total and respirable suspended particulate matter in the ambient air of Mumbai have been identified as the single largest pollutant associated with the health impacts in the community. This study deals with the extensive monitoring work carried out at BARC, Trombay during the period 2000-2002. The paper also deals with the comparative status of the TSPM levels and select trace metal and anion concentrations. While Pb levels have stabilized over the years following the introduction of unleaded gasoline, sulphate as a major contributor in the fine fraction of SPM assumes importance. The possible source profiles are presented and discussed. (author)

ELECTRIC AND MAGNETIC FIELDS ELECTRIC AND GASOLINE-POWERED VEHICLES.

Science.gov (United States)

Tell, Richard A; Kavet, Robert

2016-12-01

Measurements were conducted to investigate electric and magnetic fields (EMFs) from 120 Hz to 10 kHz and 1.2 to 100 kHz in 9 electric or hybrid vehicles and 4 gasoline vehicles, all while being driven. The range of fields in the electric vehicles enclosed the range observed in the gasoline vehicles. Mean magnetic fields ranged from nominally 0.6 to 3.5 µT for electric/hybrids depending on the measurement band compared with nominally 0.4 to 0.6 µT for gasoline vehicles. Mean values of electric fields ranged from nominally 2 to 3 V m -1 for electric/hybrid vehicles depending on the band, compared with 0.9 to 3 V m -1 for gasoline vehicles. In all cases, the fields were well within published exposure limits for the general population. The measurements were performed with Narda model EHP-50C/EHP-50D EMF analysers that revealed the presence of spurious signals in the EHP-50C unit, which were resolved with the EHP-50D model. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Effects of gasoline properties on exhaust emission and photochemical reactivity; Gasoline seijo ga haiki gas sosei, kokagaku hannosei ni oyobosu eikyo

Energy Technology Data Exchange (ETDEWEB)

Kumagai, R; Usui, K; Moriya, A; Sato, M; Nomura, T; Sue, H [Petroleum Energy Center, Advanced Technology and Research Institute, Tokyo (Japan)

1997-10-01

In order to investigate the effects of fuel properties on emissions, four passenger cars were tested under Japanese 11 and 10-15 modes using two series gasoline fuels. The test results suggest that the distillation property (T90) affects A/F ratio which in turn influences exhaust emissions. The results of regression analysis show that both ozone forming potential and air toxics are highly corrected with the composition of aromatic hydrocarbons in gasoline. 3 refs., 10 figs., 6 tabs.

Who is exposed to gas prices? How gasoline prices affect automobile manufacturers and dealerships

OpenAIRE

Silva-Risso, Jorge; Zettelmeyer, Florian; Busse, Meghan R.; Knittel, Christopher Roland

2016-01-01

Many consumers are keenly aware of gasoline prices, and consumer responses to gasoline prices have been well studied. In this paper, by contrast, we investigate how gasoline prices affect the automobile industry: manufacturers and dealerships. We estimate how changes in gasoline prices affect equilibrium prices and sales of both new and used vehicles of different fuel economies. We investigate the implications of these effects for individual auto manufacturers, taking into account differences...

Who is exposed to gas prices? How gasoline prices affect automobile manufacturers and dealerships

OpenAIRE

Busse, Meghan R.; Kittel, Christopher R.; Zettelmeyer, Florian

2012-01-01

Many consumers are keenly aware of gasoline prices, and consumer responses to gasoline prices have been well studied. In this paper, by contrast, we investigate how gasoline prices affect the automobile industry: manufacturers and dealerships. We estimate how changes in gasoline prices affect equilibrium prices and sales of both new and used vehicles of different fuel economies. We investigate the implications of these effects for individual auto manufacturers, taking into account differences...

The return of "Gasoline station-park" status into green-open space in DKI Jakarta Province

Science.gov (United States)

Kautsar, L. H. R.; Waryono, T.; Sobirin

2017-07-01

The development of gasoline stations in 1970 increased drastically due to the Government support through DKT Jaya Official Note (DKT Jakarta), resulting in a great number of the parks (green open space or RTH - Ruang Terbuka Hijau) converted into a gasoline station. Currently, to meet the RTH target (13.94 % RTH based RTRW [(Rencana Tata Ruang Wilayah) DKT Jakarta 2010], the policy was changed by Decree No.728 year 2009 and Governor Tnstruction No.75 year 2009. Land function of 27 gasoline stations unit must be returned. This study is to determine the appropriateness of gasoline Station-Park conversion into RTH based site and situation approach. The scope of this study was limited only to gasoline stations not converted into RTH. The methodology was the combination of AHP (Analytical Hierarchy Process) and ranking method. Site variables were meant for prone to flooding, the width of land for gasoline station, land status. Situation variables were meant for other public space, availability of other gasoline stations, gasoline stations service, road segments, and the proportions of built space. Analysis study used quantitative descriptive analysis. The results were three of the five gasoline stations were congruence to be converted into a green open space (RTH).

76 FR 4155 - National Emission Standards for Hazardous Air Pollutants for Source Categories: Gasoline...

Science.gov (United States)

2011-01-24

... 63 National Emission Standards for Hazardous Air Pollutants for Source Categories: Gasoline Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities; and Gasoline Dispensing Facilities; Final...] RIN 2060-AP16 National Emission Standards for Hazardous Air Pollutants for Source Categories: Gasoline...

A Classroom Demonstration of Water-Induced Phase Separation of Alcohol-Gasoline Biofuel Blends

Science.gov (United States)

Mueller, Sherry A.; Anderson, James E.; Wallington, Timothy J.

2009-01-01

A significant issue associated with ethanol-gasoline blends is the phase separation that occurs with the addition of small volumes of water, producing an ethanol-deficient gasoline layer and an ethanol-rich aqueous layer. The gasoline layer may have a lower-than-desired octane rating due to the decrease in ethanol content, resulting in engine…

Effects of gasoline engine emissions on preexisting allergic airway responses in mice.

Science.gov (United States)

Day, Kimberly C; Reed, Matthew D; McDonald, Jacob D; Seilkop, Steven K; Barrett, Edward G

2008-10-01

Gasoline-powered vehicle emissions contribute significantly to ambient air pollution. We hypothesized that exposure to gasoline engine emissions (GEE) may exacerbate preexisting allergic airway responses. Male BALB/c mice were sensitized by injection with ovalbumin (OVA) and then received a 10-min aerosolized OVA challenge. Parallel groups were sham-sensitized with saline. Mice were exposed 6 h/day to air (control, C) or GEE containing particulate matter (PM) at low (L), medium (M), or high (H) concentrations, or to the H level with PM removed by filtration (high-filtered, HF). Immediately after GEE exposure mice received another 10-min aerosol OVA challenge (pre-OVA protocol). In a second (post-OVA) protocol, mice were similarly sensitized but only challenged to OVA before air or GEE exposure. Measurements of airway hyperresponsiveness (AHR), bronchoalveolar lavage (BAL), and blood collection were performed approximately 24 h after the last exposure. In both protocols, M, H, and HF GEE exposure significantly decreased BAL neutrophils from nonsensitized mice but had no significant effect on BAL cells from OVA-sensitized mice. In the pre-OVA protocol, GEE exposure increased OVA-specific IgG(1) but had no effect on BAL interleukin (IL)-2, IL-4, IL-13, or interferon (IFN)-gamma in OVA-sensitized mice. Nonsensitized GEE-exposed mice had increased OVA-specific IgG(2a), IgE, and IL-2, but decreased total IgE. In the post-OVA protocol, GEE exposure reduced BAL IL-4, IL-5, and IFN-gamma in nonsensitized mice but had no effect on sensitized mice. These results suggest acute exposure to the gas-vapor phase of GEE suppressed inflammatory cells and cytokines from nonsensitized mice but did not substantially exacerbate allergic responses.

Consumer choice between ethanol and gasoline: Lessons from Brazil and Sweden

Energy Technology Data Exchange (ETDEWEB)

Pacini, Henrique, E-mail: henrique.pacini@energy.kth.se; Silveira, Semida, E-mail: semida.silveira@energy.kth.se

2011-11-15

The introduction of flex-fuel vehicles since 2003 has made possible for Brazilian drivers to choose between high ethanol blends or gasoline depending on relative prices and fuel economies. In Sweden, flex-fuel fleets were introduced in 2005. Prices and demand data were examined for both Brazil and Sweden. Bioethanol has been generally the most cost-efficient fuel in Brazil, but not for all states. In any case, consumers in Brazil have opted for ethanol even when this was not the optimal economic choice. In Sweden, a different behavior was observed when falling gasoline prices made E85 uneconomical in late 2008. In a context of international biofuels expansion, the example of E85 in Sweden indicates that new markets could experience different consumer behavior than Brazil: demand falls rapidly with reduced price differences between ethanol and gasoline. At the same time, rising ethanol demand and lack of an international market with multiple biofuel producers could lead to higher domestic prices in Brazil. Once the limit curve is crossed, the consumer might react by shifting back to the usage of gasoline. - Research Highlights: > Brazil and Sweden both have infrastructure for high fuel ethanol blends. > Flex-fuel vehicles enable competition between ethanol and gasoline in fuel markets. > Data suggests that consumers make their fuel choice based mainly on prices. > Consumers in Sweden appear to be more price-sensitive than their Brazilian counterparts. > In the absence of international markets, high ethanol prices may drive consumers back to gasoline.

Fuel options for the fuel cell vehicle: hydrogen, methanol or gasoline?

International Nuclear Information System (INIS)

Thomas, C.E.; James, B.D.; Lomax, F.D. Jr.; Kuhn, I.F. Jr.

2000-01-01

Fuel cell vehicles can be powered directly by hydrogen or, with an onboard chemical processor, other liquid fuels such as gasoline or methanol. Most analysts agree that hydrogen is the preferred fuel in terms of reducing vehicle complexity, but one common perception is that the cost of a hydrogen infrastructure would be excessive. According to this conventional wisdom, the automobile industry must therefore develop complex onboard fuel processors to convert methanol, ethanol or gasoline to hydrogen. We show here, however, that the total fuel infrastructure cost to society including onboard fuel processors may be less for hydrogen than for either gasoline or methanol, the primary initial candidates currently under consideration for fuel cell vehicles. We also present the local air pollution and greenhouse gas advantages of hydrogen fuel cell vehicles compared to those powered by gasoline or methanol. (Author)

Suicide attempt by intravenous injection of gasoline: a case report.

Science.gov (United States)

Fink, Katrin; Kuehnemund, Alexander; Schwab, Tilmann; Geibel-Zehender, Annette; Bley, Thorsten; Bode, Christoph; Busch, Hans-Joerg

2010-11-01

There is much experience with intoxication by aspiration of volatile hydrocarbon products, whereas intravenous injection of these distillates is rare. There are only few reports that describe a wide variety of associated pathological changes, predominantly in the pulmonary system. We report the case of an intravenous self-injection of gasoline by a young man in a suicide attempt. Immediately after injecting gasoline, the 22-year-old man developed bradycardia, hypotension, and increasing dyspnea. Computed tomography scan of the chest showed signs consistent with diffuse alveolar-toxic damage to the lung. These symptoms and radiological findings are similar to those commonly observed after inhalation of this type of substance. This may have been due to diffusion of gasoline into the alveoli, where its presence leads to this characteristic damage. In this patient, gasoline entered the intramuscular tissue, and the patient developed a soft-tissue phlegmon at the forearm. At operation, gas emanation and superficial necrosis were noted. Nevertheless, the patient's outcome was good, with full recovery within 3 weeks. The major changes in this patient after intravenous injection of gasoline were in the pulmonary system, including hypoxemia and radiological findings that could be related to an exhalation of the volatile substance. In addition, gas in the musculature of the injection area caused a soft-tissue phlegmon. Copyright © 2010 Elsevier Inc. All rights reserved.

40 CFR 80.1348 - What gasoline sample retention requirements apply to refiners and importers?

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What gasoline sample retention... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Sampling, Testing and Retention Requirements § 80.1348 What gasoline sample retention requirements...

Vapor pressures and enthalpies of vaporization of azides

International Nuclear Information System (INIS)

Verevkin, Sergey P.; Emel'yanenko, Vladimir N.; Algarra, Manuel; Manuel Lopez-Romero, J.; Aguiar, Fabio; Enrique Rodriguez-Borges, J.; Esteves da Silva, Joaquim C.G.

2011-01-01

Highlights: → We prepared and measured vapor pressures and vaporization enthalpies of 7 azides. → We examined consistency of new and available in the literature data. → Data for geminal azides and azido-alkanes selected for thermochemical calculations. - Abstract: Vapor pressures of some azides have been determined by the transpiration method. The molar enthalpies of vaporization Δ l g H m of these compounds were derived from the temperature dependencies of vapor pressures. The measured data sets were successfully checked for internal consistency by comparison with vaporization enthalpies of similarly structured compounds.

Impact of a new gasoline benzene regulation on ambient air pollutants in Anchorage, Alaska

Science.gov (United States)

Yano, Yuriko; Morris, Stephen S.; Salerno, Christopher; Schlapia, Anne M.; Stichick, Mathew

2016-05-01

The purpose of this study was to quantify the impact of a new U.S. Environmental Protection Agency (EPA) standard that limits the amount of benzene allowed in gasoline on ambient benzene concentrations. This new standard, together with two companion regulations that limit cold-temperature automotive emissions and the permeability of portable fuel containers, was expected to lower the levels of ambient benzene and other volatile organic compounds (VOCs) nationwide. In this study the impact of the gasoline benzene standard was evaluated in Anchorage, Alaska in a two-phase ambient air monitoring study conducted before and after the new gasoline standard was implemented. Gasoline sold by Anchorage retailers was also evaluated in each phase to determine the content of benzene and other gasoline components. The average benzene content in Anchorage gasoline was reduced by 70%, from 5.05% (w/w) to 1.53% (w/w) following the implementation of the standard. The annual mean ambient benzene concentration fell by 51%, from 0.99 ppbv in Phase 1 to 0.49 ppbv in Phase 2. Analysis suggests the change in gasoline benzene content alone reduced benzene emissions by 46%. The changes in toluene, ethylbenzene, and xylene content in gasoline between Phase 1 and 2 were relatively small and the differences in the mean ambient concentrations of these compounds between phases were modest. Our results suggest that cold winter communities in high latitude and mountainous regions may benefit more from the gasoline benzene standard because of high benzene emissions resulting from vehicle cold start and a tendency to develop atmospheric stagnation conditions in the winter.

Ozone-forming potential of reformulated gasoline

National Research Council Canada - National Science Library

Committee on Ozone-Forming Potential of Reformulated Gasoline, National Research Council

... and comparison of the emissions from motor vehicles using different reformulated gasolines based on their ozone-forming potentials and to assess the concomitant impact of that approach on air-quality benefits...

40 CFR 86.335-79 - Gasoline-fueled engine test cycle.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Gasoline-fueled engine test cycle. 86....335-79 Gasoline-fueled engine test cycle. (a) The following test sequence shall be followed in... operating the engine at the higher approved load setting during cycle 1 and at the lower approved load...

40 CFR 80.1220 - What are the implementation dates for the gasoline benzene program?

Science.gov (United States)

2010-07-01

... annual averaging period thereafter, gasoline produced at each refinery of a refiner or imported by an... annual averaging period thereafter, gasoline produced at each refinery of a refiner or imported by an... the gasoline benzene program? 80.1220 Section 80.1220 Protection of Environment ENVIRONMENTAL...

40 CFR 80.335 - What gasoline sample retention requirements apply to refiners and importers?

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What gasoline sample retention... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Sampling, Testing and Retention Requirements for Refiners and Importers § 80.335 What gasoline sample...

40 CFR 80.395 - Who is liable for violations under the gasoline sulfur program?

Science.gov (United States)

2010-07-01

... gasoline sulfur program? 80.395 Section 80.395 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Violation Provisions § 80.395 Who is liable for violations under the gasoline sulfur program? (a) Persons liable for...

40 CFR 80.1015 - Who is liable for violations under the gasoline toxics program?

Science.gov (United States)

2010-07-01

... gasoline toxics program? 80.1015 Section 80.1015 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Toxics Violation Provisions § 80.1015 Who is liable for violations under the gasoline toxics program? (a) Persons liable for...

40 CFR 80.810 - Who shall register with EPA under the gasoline toxics program?

Science.gov (United States)

2010-07-01

... gasoline toxics program? 80.810 Section 80.810 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Toxics General Information § 80.810 Who shall register with EPA under the gasoline toxics program? (a) Refiners and importers...

Internal Nozzle Flow Simulations of Gasoline-Like Fuels under Diesel Operating Conditions

Energy Technology Data Exchange (ETDEWEB)

Torelli, R.; Som, S.; Pei, Y.; Zhang, Yu; Traver, Michael

2017-05-15

Spray formation in internal combustion engines with direct injection is strictly correlated with internal nozzle flow characteristics, which are in turn influenced by fuel physical properties and injector needle motion. This paper pre-sents a series of 3D simulations that model the in-nozzle flow in a 5-hole mini-sac diesel injector. Two gasoline-like naphtha fuels, namely full-range and light naphtha, were tested under operating conditions typical of diesel applica-tions and were compared with n-dodecane, selected from a palette used as diesel surrogates. Validated methodolo-gies from our previous work were employed to account for realistic needle motion. The multi-phase nature of the problem was described by the mixture model assumption with the Volume of Fluid method. Cavitation effects were included by means of the Homogeneous Relaxation Model and turbulence closure was achieved with the Standard k-ε model in an Unsteady Reynolds-Averaged Navier-Stokes formulation. The results revealed that injector perfor-mance and propensity to cavitation are influenced by the fuel properties. Analyses of several physical quantities were carried out to highlight the fuel-to-fuel differences in terms of mass flow rate, discharge coefficients, and fuel vapor volume fraction inside the orifices. A series of parametric investigations was also performed to assess the fuel response to varied fuel injection temperature, injection pressure, and cross-sectional orifice area. For all cases, the strict correlation between cavitation magnitude and saturation pressure was confirmed. Owing to their higher volatil-ity, the two gasoline-like fuels were characterized by higher cavitation across all the simulated conditions. Occur-rence of cavitation was mostly found at the needle seat and at the orifice inlets during the injection event’s transient, when very small gaps exist between the needle and its seat. This behavior tended to disappear at maximum needle lift, where cavitation was

40 CFR 80.820 - What gasoline is subject to the toxics performance requirements of this subpart?

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What gasoline is subject to the toxics... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Toxics Gasoline Toxics Performance Requirements § 80.820 What gasoline is subject to the toxics performance...

Particle number emissions of gasoline hybrid electric vehicles; Partikelanzahl-Emission bei Hybridfahrzeugen mit Ottomotor

Energy Technology Data Exchange (ETDEWEB)

Porter, Scott [Horiba Instruments Inc., Ann Arbor, MI (United States)

2012-04-15

Hybrid Electric Vehicles (HEV) are commonly reputed to be environmentally friendly. Different studies show that this assumption raises some questions in terms of particle number emissions. Against the background that upcoming emission standards will not only limit particle matter emissions but also particle number emissions for gasoline engines, the exhaust behaviour of downsized gasoline engines used in HEV should be investigated more extensively. A Horiba study compares the particle number emissions of a gasoline vehicle to those of a gasoline powered HEV. (orig.)

An analysis of strategic price setting in retail gasoline markets

Science.gov (United States)