The AMS [Accelerator Mass Spectrometer] program at LLNL

International Nuclear Information System (INIS)

Proctor, I.D.

1988-09-01

Livermore will have an operational Accelerator Mass Spectrometer (AMS) by mid-1989 as part of its new Multi-user Tandem Laboratory. The spectrometer was designed primarily for applications in archaeology and the geosciences and was co-funded by the University of California Regents. Radiological control for personnel protection, ion sources and injection systems, the tandem and all beam handling hardware are operated with a distributed processor computer control system. The Tandem is the former University of Washington injector FN which has been upgraded with Dowlish tubes, pelletron charging and SF 6 gas. Design goals for the AMS system, computer aided operation, automated measurement capability, initial results and some of our intended applications will be presented. 5 refs., 2 figs

Streamlined Calibration of the ATLAS Muon Spectrometer Precision Chambers

CERN Document Server

Levin, DS; The ATLAS collaboration; Dai, T; Diehl, EB; Ferretti, C; Hindes, JM; Zhou, B

2009-01-01

The ATLAS Muon Spectrometer is comprised of nearly 1200 optically Monitored Drifttube Chambers (MDTs) containing 354,000 aluminum drift tubes. The chambers are configured in barrel and endcap regions. The momentum resolution required for the LHC physics reach (dp/p = 3% and 10% at 100 GeV and 1 TeV) demands rigorous MDT drift tube calibration with frequent updates. These calibrations (RT functions) convert the measured drift times to drift radii and are a critical component to the spectrometer performance. They are sensitive to the MDT gas composition: Ar 93%, CO2 7% at 3 bar, flowing through the detector at arate of 100,000 l hr−1. We report on the generation and application of Universal RT calibrations derived from an inline gas system monitor chamber. Results from ATLAS cosmic ray commissioning data are included. These Universal RTs are intended for muon track reconstuction in LHC startup phase.

STITCHING TYPE LARGE APERTURE DEPOLARIZER FOR GAS MONITORING IMAGING SPECTROMETER

Directory of Open Access Journals (Sweden)

X. Liu

2018-04-01

Full Text Available To increase the accuracy of radiation measurement for gas monitoring imaging spectrometer, it is necessary to achieve high levels of depolarization of the incoming beam. The preferred method in space instrument is to introduce the depolarizer into the optical system. It is a combination device of birefringence crystal wedges. Limited to the actual diameter of the crystal, the traditional depolarizer cannot be used in the large aperture imaging spectrometer (greater than 100 mm. In this paper, a stitching type depolarizer is presented. The design theory and numerical calculation model for dual babinet depolarizer were built. As required radiometric accuracies of the imaging spectrometer with 250 mm × 46 mm aperture, a stitching type dual babinet depolarizer was design in detail. Based on designing the optimum structural parmeters，the tolerance of wedge angle，refractive index, and central thickness were given. The analysis results show that the maximum residual polarization degree of output light from depolarizer is less than 2 %. The design requirements of polarization sensitivity is satisfied.

In-beam electron spectrometer used in conjunction with a gas-filled recoil separator

International Nuclear Information System (INIS)

Kankaanpaeae, H.; Butler, P.A.; Greenlees, P.T.; Bastin, J.E.; Herzberg, R.D.; Humphreys, R.D.; Jones, G.D.; Jones, P.; Julin, R.; Keenan, A.; Kettunen, H.; Leino, M.; Miettinen, L.; Page, T.; Rahkila, P.; Scholey, C.; Uusitalo, J.

2004-01-01

The conversion-electron spectrometer SACRED has been redesigned for use in conjunction with the RITU gas-filled recoil separator. The system allows in-beam recoil-decay-tagging (RDT) measurements of internal conversion electrons. The performance of the system using standard sources and in-beam is described

Ground based THz Spectroscopy of Obscured Starbursts in the Early Universe enabled by the 2nd generation Redshift (z) & Early Universe Spectrometer (ZEUS-2)

Science.gov (United States)

Vishwas, Amit; Stacey, Gordon; Nikola, Thomas; Ferkinhoff, Carl; Parshley, Stephen; Schoenwald, Justin; Lamarche, Cody James; Higdon, James; Higdon, Sarah; Brisbin, Drew; Güesten, Rolf; Weiss, Axel; Menten, Karl; Irwin, Kent; Cho, Hsiao-Mei; Niemack, Michael; Hilton, Gene; Hubmayr, Johannes; Amiri, Mandana; Halpern, Mark; Wiebe, Donald; Hasselfield, Matthew; Ade, Peter; Tucker, Carole

2018-01-01

Galaxies were surprisingly dusty in the early Universe, with more than half of the light emitted from stars being absorbed by dust within the system and re-radiated into far infrared (FIR, ~50-150μm) wavelengths. Dusty star forming galaxies (DSFGs) dominate the co-moving star formation rate density of the Universe that peaks around redshift, z~2, making it compelling to study them in rest frame FIR bands. From galaxies at z > 1, the FIR line emission from abundant ions like [O III], [C II] and [N II], are redshifted into the short sub-mm telluric windows. My thesis work is based on building and deploying the 2nd Generation Redshift (z) and Early Universe Spectrometer (ZEUS-2), a long-slit, echelle grating spectrometer optimized to study broad (Δv = 300km/s) spectral lines from galaxies in the 200-650µm telluric windows using TES bolometers. These far-IR lines being extinction free and major coolants of the gas heated by (young) massive stars, are powerful probes of the physical conditions of the gas and the stellar radiation field. I present results from our survey of the [O III] 88µm line in galaxies at redshift, z ~ 2.8 to 4.6, with ZEUS-2 at the Atacama Pathfinder Experiment (APEX) Telescope. To interpret our observations along with ancillary data from optical to radio facilities, we apply photoionization models for HII regions and Photo Dissociation Region (PDR) models and confirm that the galaxies host substantial ongoing obscured star formation. The presence of doubly ionized oxygen suggests hard radiation fields and hence, elevated ionization parameters that can only be accounted for by a large population of massive stars formed during the ongoing starburst, that contribute a large fraction of the infrared luminosity. This study highlights the use of FIR line emission to trace the assembly of current day massive galaxies, conditions of star formation and details of their stellar populations. The construction and operation of ZEUS-2 were funded by NSF ATI

The SAGE spectrometer: A tool for combined in-beam γ-ray and conversion electron spectroscopy

International Nuclear Information System (INIS)

Papadakis, P; Herzberg, R-D; Pakarinen, J; Butler, P A; Cox, D; Cresswell, J R; Parr, E; Sampson, J; Greenlees, P T; Sorri, J; Hauschild, K; Jones, P; Julin, R; Peura, P; Rahkila, P; Sandzelius, M; Coleman-Smith, P J; Lazarus, I H; Letts, S C; Pucknell, V F E

2011-01-01

The SAGE spectrometer allows simultaneous in-beam γ-ray and internal conversion electron measurements, by combining a germanium detector array with a highly segmented silicon detector and an electron transport system. SAGE is coupled with the ritu gas-filled recoil separator and the great focal-plane spectrometer for recoil-decay tagging studies. Digital electronics are used both for the γ ray and the electron parts of the spectrometer. SAGE was commissioned in the Accelerator Laboratory of the University of Jyvaeskylae in the beginning of 2010.

Recent Advances in Water Analysis with Gas Chromatograph Mass Spectrometers

Science.gov (United States)

MacAskill, John A.; Tsikata, Edem

2014-01-01

We report on progress made in developing a water sampling system for detection and analysis of volatile organic compounds in water with a gas chromatograph mass spectrometer (GCMS). Two approaches are described herein. The first approach uses a custom water pre-concentrator for performing trap and purge of VOCs from water. The second approach uses a custom micro-volume, split-splitless injector that is compatible with air and water. These water sampling systems will enable a single GC-based instrument to analyze air and water samples for VOC content. As reduced mass, volume, and power is crucial for long-duration, manned space-exploration, these water sampling systems will demonstrate the ability of a GCMS to monitor both air and water quality of the astronaut environment, thereby reducing the amount of required instrumentation for long duration habitation. Laboratory prototypes of these water sampling systems have been constructed and tested with a quadrupole ion trap mass spectrometer as well as a thermal conductivity detector. Presented herein are details of these water sampling system with preliminary test results.

Online precision gas evaluation of the ATLAS Muon Spectrometer during LHC RUN1

CERN Document Server

The ATLAS collaboration

2014-01-01

The ATLAS Muon Spectrometer, a six story structure embedded in a toroidal magnetic field, is constructed of nearly 1200 Monitored Drift Tube chambers (MDTs) containing 354,000 aluminum drift tubes. The operating gas is 93% Ar + 7% CO2 with a small amount of water vapor at a pressure of 3 bar. The momentum resolution required for the LHC physics (dp/p = 2% at 100 GeV) demands that MDT gas gas quality and the associated gas dependent calibrations be determined with a rapid feedback cycle. During the LHC Run 1 more than 2 billion liters of gas flowed through the detector at a rate 100,000 l/hr. Online evauation of MDT gas in real time and the associated contribution to the determination of the time-to-space functions was conducted by the dedicated Gas Monitor Chamber. We report on the operation and results of the GMC over the first three years of LHC running. During this period, the GMC has operated with a nearly 100% duty cycle, providing hourly measurements of the MDT drift times with 1 ns precision, correspon...

Performance report for the low energy compact radiocarbon accelerator mass spectrometer at Uppsala University

Science.gov (United States)

Salehpour, M.; Håkansson, K.; Possnert, G.; Wacker, L.; Synal, H.-A.

2016-03-01

A range of ion beam analysis activities are ongoing at Uppsala University, including Accelerator Mass Spectrometry (AMS). Various isotopes are used for AMS but the isotope with the widest variety of applications is radiocarbon. Up until recently, only the 5 MV Pelletron tandem accelerator had been used at our site for radiocarbon AMS, ordinarily using 12 MeV 14,13,12C3+ ions. Recently a new radiocarbon AMS system, the Green-MICADAS, developed at the ion physics group at ETH Zurich, was installed. The system has a number of outstanding features which will be described. The system operates at a terminal voltage of 175 kV and uses helium stripper gas, extracting singly charged carbon ions. The low- and high energy mass spectrometers in the system are stigmatic dipole permanent magnets (0.42 and 0.97 T) requiring no electrical power nor cooling water. The system measures both the 14C/12C and the 13C/12C ratios on-line. Performance of the system is presented for both standard mg samples as well as μg-sized samples.

Direct coupling of a dense (supercritical) gas chromatograph to a mass spectrometer using a supersonic molecular beam interface

International Nuclear Information System (INIS)

Randall, L.G.; Wahrhaftig, A.L.

1981-01-01

A detecting mass spectrometer has been successfully coupled to a dense gas (supercritical fluid) chromatograph to produce an instrument (DGC/MS) that may be an alternative to high performance liquid chromatograph/mass spectrometer instruments (HPLC/MS) and gas chromatograph/mass spectrometer instruments (GC/MS) for analysis of involatile and/or thermally labile compounds. The mobile phase in DGC is a gas held at temperatures above the critical temperature and at pressures sufficient to obtain nearly liquid-like densities. DGC combines advantages of GC and HPLC: rapid separations, moderate operating temperatures, and analysis of involatile compounds. An advantage unique to DGC is the solvent power dependence upon pressure. While several groups have studied DGC, its development has been limited by the lack of a sensitive and selective detector. Hence, work has been directed towards the design and construction of a DGC/MS resulting in a trial instrument capable of chromatographic pressures of at least 300 atm and temperatures from 10 0 to 60 0 C. The DGC/MS coupling has been accomplished by the use of a supersonic molecular beam interface. This application of molecular beam formation appears to be unique in its requirements of a large pressure ratio (approx.10 8 ), low flow rates, and low final pressures. The authors outline characteristics of supersonic jets and molecular beams pertinent to the design of such an instrument. The interface which uses pumping speeds of 2400 and 1200 l/s in the beam forming chambers is described in detail, while the other components: the detecting mass spectrometer, the dense gas supply, and the DGC: are briefly described. Preliminary work with this instrument has established the feasibility of DGC/MS as an analytical technique and further development is recommended

Online precision gas evaluation of the ATLAS Muon Spectrometer during LHC Run1

CERN Document Server

AUTHOR|(CDS)2092735; The ATLAS collaboration

2016-01-01

The ATLAS Muon Spectrometer, a six story structure embedded in a toroidal magnetic field, is constructed of nearly 1200 Monitored Drift Tube chambers (MDTs) containing 354,000 aluminum drift tubes. The operating gas is 93% Ar + 7% CO${_2}$ with a small amount of water vapor at a pressure of 3 bar. The momentum resolution required for ATLAS physics demands that MDT gas quality and the associated gas dependent calibrations be determined with a rapid feedback cycle. During the LHC Run1, more than 2 billion liters of gas flowed through the detector at a rate 100,000 l/hr. Online evaluation of MDT gas in real time and the associated contribution to the determination of the time-to-space functions was conducted by the dedicated Gas Monitor Chamber (GMC). We report on the operation and results of the GMC over the first three years of LHC running. During this period, the GMC has operated with a nearly 100% duty cycle, providing hourly measurements of the MDT drift times with 1 ns precision, corresponding to minute ch...

Local thermal equilibrium and ideal gas Stephani universes

OpenAIRE

Coll, Bartolomé; Ferrando, Joan Josep

2004-01-01

The Stephani universes that can be interpreted as an ideal gas evolving in local thermal equilibrium are determined. Five classes of thermodynamic schemes are admissible, which give rise to five classes of regular models and three classes of singular models. No Stephani universes exist representing an exact solution to a classical ideal gas (one for which the internal energy is proportional to the temperature). But some Stephani universes may approximate a classical ideal gas at first order i...

Movable chromatemass-spectrometer for attestation of working places in oil-gas processing sector

International Nuclear Information System (INIS)

Nuriev, K.Z.; Kolesnikova, U.P.; Balayeva, A.A.

2005-01-01

Small capacity chromatomass-spectrometer (KhS) intended for defining chemical compound of the atmosphere weather in open and close locations for the purpose of attestation of working places in the oil gas production plants. Characteristics and parameters of all nodes of KhS, playing a certain part in realization of given device were given and based. Accounts and constructive parameters of concrete KhS and technical activities of developed device were actuated

Performance report for the low energy compact radiocarbon accelerator mass spectrometer at Uppsala University

Energy Technology Data Exchange (ETDEWEB)

Salehpour, M., E-mail: mehran.salehpour@physics.uu.se [Department of Physics and Astronomy, Ion Physics, Applied Nuclear Physics Division, P.O. Box 516, SE-751 20 Uppsala (Sweden); Håkansson, K.; Possnert, G. [Department of Physics and Astronomy, Ion Physics, Applied Nuclear Physics Division, P.O. Box 516, SE-751 20 Uppsala (Sweden); Wacker, L.; Synal, H.-A. [Ion Physics, ETH Zurich, Otto-Stern-Weg 5, 8093 (Switzerland)

2016-03-15

A range of ion beam analysis activities are ongoing at Uppsala University, including Accelerator Mass Spectrometry (AMS). Various isotopes are used for AMS but the isotope with the widest variety of applications is radiocarbon. Up until recently, only the 5 MV Pelletron tandem accelerator had been used at our site for radiocarbon AMS, ordinarily using 12 MeV {sup 14,13,12}C{sup 3+} ions. Recently a new radiocarbon AMS system, the Green-MICADAS, developed at the ion physics group at ETH Zurich, was installed. The system has a number of outstanding features which will be described. The system operates at a terminal voltage of 175 kV and uses helium stripper gas, extracting singly charged carbon ions. The low- and high energy mass spectrometers in the system are stigmatic dipole permanent magnets (0.42 and 0.97 T) requiring no electrical power nor cooling water. The system measures both the {sup 14}C/{sup 12}C and the {sup 13}C/{sup 12}C ratios on-line. Performance of the system is presented for both standard mg samples as well as μg-sized samples.

In gas laser ionization and spectroscopy experiments at the Superconducting Separator Spectrometer (S3): Conceptual studies and preliminary design

International Nuclear Information System (INIS)

Ferrer, R.; Bastin, B.; Boilley, D.; Creemers, P.; Delahaye, P.; Liénard, E.; Fléchard, X.; Franchoo, S.; Ghys, L.; Huyse, M.; Kudryavtsev, Yu.; Lecesne, N.; Lu, H.; Lutton, F.; Mogilevskiy, E.; Pauwels, D.; Piot, J.; Radulov, D.; Rens, L.; Savajols, H.

2013-01-01

Highlights: • A setup to perform In-Gas Laser Ionization and Spectroscopy experiments at the Super Separator Spectrometer is presented. • The reported studies address important aspects necessary to applied the IGLIS technique to short-lived isotopes. • An R and D phase required to reach an enhanced spectral resolution will be carried out at KU Leuven. • High-sensitivity and enhanced-resolution laser spectroscopy studies will be possible with the IGLIS setup at S 3 . -- Abstract: The results of preparatory experiments and the preliminary designs of a new in-gas laser ionization and spectroscopy setup, to be coupled to the Super Separator Spectrometer S 3 of SPIRAL2-GANIL, are reported. Special attention is given to the development and tests to carry out a full implementation of the in-gas jet laser spectroscopy technique. Application of this novel technique to radioactive species will allow high-sensitivity and enhanced-resolution laser spectroscopy studies of ground- and excited-state properties of exotic nuclei

A gamma scintillation spectrometer

Energy Technology Data Exchange (ETDEWEB)

Symbalisty, S

1952-07-01

A scintillation type gamma ray spectrometer employing coincidence counting, designed and built at the Physics Department of the University of Western Ontario is described. The spectrometer is composed of two anthracene and photomultiplier radiation detectors, two pulse analyzing channels, a coincidence stage, three scalers and a high voltage stabilized supply. A preliminary experiment to test the operation of the spectrometer was performed and the results of this test are presented. (author)

A new time of flight mass spectrometer for absolute dissociative electron attachment cross-section measurements in gas phase

Science.gov (United States)

Chakraborty, Dipayan; Nag, Pamir; Nandi, Dhananjay

2018-02-01

A new time of flight mass spectrometer (TOFMS) has been developed to study the absolute dissociative electron attachment (DEA) cross section using a relative flow technique of a wide variety of molecules in gas phase, ranging from simple diatomic to complex biomolecules. Unlike the Wiley-McLaren type TOFMS, here the total ion collection condition has been achieved without compromising the mass resolution by introducing a field free drift region after the lensing arrangement. The field free interaction region is provided for low energy electron molecule collision studies. The spectrometer can be used to study a wide range of masses (H- ion to few hundreds atomic mass unit). The mass resolution capability of the spectrometer has been checked experimentally by measuring the mass spectra of fragment anions arising from DEA to methanol. Overall performance of the spectrometer has been tested by measuring the absolute DEA cross section of the ground state SO2 molecule, and the results are satisfactory.

A STUDY ON CARBON ISOTOPE OF CO2 AND CH4 IN WESTERN DIENG PLATEU BY GAS CHROMATOGRAPHY- ISOTOPE RATIO MASS SPECTROMETER (GC-IRMS

Directory of Open Access Journals (Sweden)

Hanik Humaida

2010-06-01

Full Text Available The carbon isotope can be used to evaluate volcanism phenomenon of volcano. The study of carbon isotope of CO2 and CH4 was carried out in western Dieng Plateau by mass-spectrometer. Before analysis, sampel was separated by gas chromatography using a Porapak-Q column and a FID (Flame Ionization Detector detector. The gas was oxidized by copper oxide at 850oC before being ionized in mass-spectrometer for isotope analysis. The CO2 content in Candradimuka crater (-4.10 O/OO, indicated that the gas may be as volcanic gas. The other CO2 from Sumber and western Gua Jimat, had isotope value  of -10.05 and -12.07 O/OO, respectively, indicating contamination from crustal and subduction material. The carbon isotope of CH4 gas from Pancasan village was -63.42 O/OO, that may be categorized as biogenic gas.   Keywords: isotope, CO2, CH4, Dieng.

Interfacing a gas proportional counter with a mass spectrometer: Simultaneous display of GC/MS and radiocarbon data

International Nuclear Information System (INIS)

Peterson, G.S.; Laemmerhirt, D.F.; Weaver, A.

1985-01-01

To facilitate the location of pesticides and monitor their metabolism in environmental and biological systems, carbon-14 labelling of the parent compound is used. Detection of the radiolabel is achieved using a gas proportional counter, while identification of the labelled components is most easily accomplished with mass spectrometry. However, when these two operations are performed separately, correlation of the information is awkward, at best. Since each is a destructive detector, simultaneous monitoring of the outposts requires an effluent splitter. The complete system consists of a variable splitter, which allows control of the ratio of the GC effluent to the two instruments, and signal processing circuitry for simultaneous recording and storage of radiocarbon and mass spectral data. Modifications to a Finnigan GC/MS and Gas Proportional Counter included a high temperature GC effluent splitter with glass-lined connecting tubing, and a data interface, including analog to digital and serial to parallel conversions with optical isolation between the gas proportional counter and the computer. The splitter restricted the flow to the mass spectrometer, preventing flow completely in the closed position. The split was adjusted to maximize flow to the mass spectrometer using the vacuum as a rough guide (1.0 x 10 -5 torr in EI, 7.5 x 10 -5 torr in CI). A heated transfer line between the transfer oven and gas proportional counter prevented condensation of eluting components prior to radiocarbon detection

The TRIUMF low energy pion spectrometer and channel

International Nuclear Information System (INIS)

Sobie, R.J.; Drake, T.E.; Barnett, B.M.; Erdman, K.L.; Gyles, W.; Johnson, R.R.; Roser, H.W.; Tacik, R.; Blackmore, E.W.; Gill, D.R.

1983-08-01

A low energy pion spectrometer has been developed for use with the TRIUMF M13 pion channel. The combined channel and spectrometer resolution is presently 1.1 MeV at T = 50 MeV. This is limited by the amount of gas and detector material in the spectrometer in addition to the inherent resolution of the channel. Improvements to both the spectrometer and channel are discussed

Frequency-Modulation Correlation Spectrometer

Science.gov (United States)

Margolis, J. S.; Martonchik, J. V.

1985-01-01

New type of correlation spectrometer eliminates need to shift between two cells, one empty and one containing reference gas. Electrooptical phase modulator sinusoidally shift frequencies of sample transmission spectrum.

A Thomson-type mass and energy spectrometer for characterizing ion energy distributions in a coaxial plasma gun operating in a gas-puff mode

Energy Technology Data Exchange (ETDEWEB)

Rieker, G. B.; Poehlmann, F. R.; Cappelli, M. A. [High Temperature Gasdynamics Laboratory, Stanford University, Stanford, California 94305 (United States)

2013-07-15

Measurements of ion energy distribution are performed in the accelerated plasma of a coaxial electromagnetic plasma gun operating in a gas-puff mode at relatively low discharge energy (900 J) and discharge potential (4 kV). The measurements are made using a Thomson-type mass and energy spectrometer with a gated microchannel plate and phosphor screen as the ion sensor. The parabolic ion trajectories are captured from the sensor screen with an intensified charge-coupled detector camera. The spectrometer was designed and calibrated using the Geant4 toolkit, accounting for the effects on the ion trajectories of spatial non-uniformities in the spectrometer magnetic and electric fields. Results for hydrogen gas puffs indicate the existence of a class of accelerated protons with energies well above the coaxial discharge potential (up to 24 keV). The Thomson analyzer confirms the presence of impurities of copper and iron, also of relatively high energies, which are likely erosion or sputter products from plasma-electrode interactions.

A Thomson-type mass and energy spectrometer for characterizing ion energy distributions in a coaxial plasma gun operating in a gas-puff mode

International Nuclear Information System (INIS)

Rieker, G. B.; Poehlmann, F. R.; Cappelli, M. A.

2013-01-01

Measurements of ion energy distribution are performed in the accelerated plasma of a coaxial electromagnetic plasma gun operating in a gas-puff mode at relatively low discharge energy (900 J) and discharge potential (4 kV). The measurements are made using a Thomson-type mass and energy spectrometer with a gated microchannel plate and phosphor screen as the ion sensor. The parabolic ion trajectories are captured from the sensor screen with an intensified charge-coupled detector camera. The spectrometer was designed and calibrated using the Geant4 toolkit, accounting for the effects on the ion trajectories of spatial non-uniformities in the spectrometer magnetic and electric fields. Results for hydrogen gas puffs indicate the existence of a class of accelerated protons with energies well above the coaxial discharge potential (up to 24 keV). The Thomson analyzer confirms the presence of impurities of copper and iron, also of relatively high energies, which are likely erosion or sputter products from plasma-electrode interactions

A Thomson-type mass and energy spectrometer for characterizing ion energy distributions in a coaxial plasma gun operating in a gas-puff mode

Science.gov (United States)

Rieker, G. B.; Poehlmann, F. R.; Cappelli, M. A.

2013-07-01

Measurements of ion energy distribution are performed in the accelerated plasma of a coaxial electromagnetic plasma gun operating in a gas-puff mode at relatively low discharge energy (900 J) and discharge potential (4 kV). The measurements are made using a Thomson-type mass and energy spectrometer with a gated microchannel plate and phosphor screen as the ion sensor. The parabolic ion trajectories are captured from the sensor screen with an intensified charge-coupled detector camera. The spectrometer was designed and calibrated using the Geant4 toolkit, accounting for the effects on the ion trajectories of spatial non-uniformities in the spectrometer magnetic and electric fields. Results for hydrogen gas puffs indicate the existence of a class of accelerated protons with energies well above the coaxial discharge potential (up to 24 keV). The Thomson analyzer confirms the presence of impurities of copper and iron, also of relatively high energies, which are likely erosion or sputter products from plasma-electrode interactions.

A Thomson-type mass and energy spectrometer for characterizing ion energy distributions in a coaxial plasma gun operating in a gas-puff mode.

Science.gov (United States)

Rieker, G B; Poehlmann, F R; Cappelli, M A

2013-07-01

Measurements of ion energy distribution are performed in the accelerated plasma of a coaxial electromagnetic plasma gun operating in a gas-puff mode at relatively low discharge energy (900 J) and discharge potential (4 kV). The measurements are made using a Thomson-type mass and energy spectrometer with a gated microchannel plate and phosphor screen as the ion sensor. The parabolic ion trajectories are captured from the sensor screen with an intensified charge-coupled detector camera. The spectrometer was designed and calibrated using the Geant4 toolkit, accounting for the effects on the ion trajectories of spatial non-uniformities in the spectrometer magnetic and electric fields. Results for hydrogen gas puffs indicate the existence of a class of accelerated protons with energies well above the coaxial discharge potential (up to 24 keV). The Thomson analyzer confirms the presence of impurities of copper and iron, also of relatively high energies, which are likely erosion or sputter products from plasma-electrode interactions.

VEGAS: VErsatile GBT Astronomical Spectrometer

Science.gov (United States)

Bussa, Srikanth; VEGAS Development Team

2012-01-01

The National Science Foundation Advanced Technologies and Instrumentation (NSF-ATI) program is funding a new spectrometer backend for the Green Bank Telescope (GBT). This spectrometer is being built by the CICADA collaboration - collaboration between the National Radio Astronomy Observatory (NRAO) and the Center for Astronomy Signal Processing and Electronics Research (CASPER) at the University of California Berkeley.The backend is named as VErsatile GBT Astronomical Spectrometer (VEGAS) and will replace the capabilities of the existing spectrometers. This backend supports data processing from focal plane array systems. The spectrometer will be capable of processing up to 1.25 GHz bandwidth from 8 dual polarized beams or a bandwidth up to 10 GHz from a dual polarized beam.The spectrometer will be using 8-bit analog to digital converters (ADC), which gives a better dynamic range than existing GBT spectrometers. There will be 8 tunable digital sub-bands within the 1.25 GHz bandwidth, which will enhance the capability of simultaneous observation of multiple spectral transitions. The maximum spectral dump rate to disk will be about 0.5 msec. The vastly enhanced backend capabilities will support several science projects with the GBT. The projects include mapping temperature and density structure of molecular clouds; searches for organic molecules in the interstellar medium; determination of the fundamental constants of our evolving Universe; red-shifted spectral features from galaxies across cosmic time and survey for pulsars in the extreme gravitational environment of the Galactic Center.

Note: Buffer gas temperature inhomogeneities and design of drift-tube ion mobility spectrometers: Warnings for real-world applications by non-specialists

Science.gov (United States)

Fernandez-Maestre, R.

2017-09-01

Ion mobility spectrometry (IMS) separates gas phase ions moving under an electric field according to their size-to-charge ratio. IMS is the method of choice to detect illegal drugs and explosives in customs and airports making accurate determination of reduced ion mobilities (K0) important for national security. An ion mobility spectrometer with electrospray ionization coupled to a quadrupole mass spectrometer was used to study uncertainties in buffer gas temperatures during mobility experiments. Differences up to 16°C were found in the buffer gas temperatures in different regions of the drift tube and up to 42°C between the buffer gas and the drift tube temperatures. The drift tube temperature is used as an approximation to the buffer gas temperature for the calculation of K0 because the buffer gas temperature is hard to measure. This is leading to uncertainties in the determination of K0 values. Inaccurate determination of K0 values yields false positives that delay the cargo and passengers in customs and airports. Therefore, recommendations are issued for building mobility tubes to assure a homogeneous temperature of the buffer gas. Because the temperature and other instrumental parameters are difficult to measure in IMS, chemical standards should always be used when calculating K0. The difference of 42°C between the drift tube and buffer gas temperatures found in these experiments produces a 10.5% error in the calculation of K0. This large inaccuracy in K0 shows the importance of a correct temperature measurement in IMS.

Mars Solar Balloon Landed Gas Chromatograph Mass Spectrometer

Science.gov (United States)

Mahaffy, P.; Harpold, D.; Niemann, H.; Atreya, S.; Gorevan, S.; Israel, G.; Bertaux, J. L.; Jones, J.; Owen, T.; Raulin, F.

1999-01-01

A Mars surface lander Gas Chromatograph Mass Spectrometer (GCMS) is described to measure the chemical composition of abundant and trace volatile species and isotope ratios for noble gases and other elements. These measurements are relevant to the study of atmospheric evolution and past climatic conditions. A Micromission plan is under study where a surface package including a miniaturized GCMS would be delivered to the surface by a solar heated hot air balloon based system. The balloon system would be deployed about 8 km above the surface of Mars, wherein it would rapidly fill with Martian atmosphere and be heated quickly by the sun. The combined buoyancy and parachuting effects of the solar balloon result in a surface package impact of about 5 m/sec. After delivery of the package to the surface, the balloon would ascend to about 4 km altitude, with imaging and magnetometry data being taken for the remainder of the daylight hours as the balloon is blown with the Martian winds. Total atmospheric entry mass of this mission is estimated to be approximately 50 kg, and it can fit as an Ariane 5 piggyback payload. The GCMS would obtain samples directly from the atmosphere at the surface and also from gases evolved from solid phase material collected from well below the surface with a Sample Acquisition and Transport Mechanism (SATM). The experiment envisioned in the Mars Micromission described would obtain samples from a much greater depth of up to one meter below the surface, and would search for organic molecules trapped in ancient stratified layers well below the oxidized surface. Insitu instruments on upcoming NASA missions working in concert with remote sensing measurement techniques have the potential to provide a more detailed investigation of mineralogy and the extent of simple volatiles such as CO2 and H2O in surface and subsurface solid phase materials. Within the context of subsequent mission opportunities such as those provided by the Ariane 5 piggyback

Universal energy-dispersive EXAFS spectrometer based on SR beam of `Kurchatovskij Institute` and scientific program of investigations; Universal`nyj ehnergodispersionnyj EXAFS-spektrometr v Natsional`nom tsentre sinkhrotronnogo izlucheniya (`Kurchatovskij institut`) i nauchnaya programma issledovanij

Energy Technology Data Exchange (ETDEWEB)

Aksenov, V L; Ivanov, I N [Laboratory of Particle Physics, Joint Institute for Nuclear Research, Dubna (Russian Federation); Koval` chuk, M V [Institut Kristallografii, RAN, Moscow (Russian Federation); and others

1997-12-31

The scheme of the energy-dispersive EXAFS spectrometer is discussed. The spectrometer will be used for the solid state investigations on the Kurchatov Synchrotron Radiation Source KSRS. The main elements of the universal station are described, including the results of the positive-sensitive X-ray detector testing. The experimental investigations are presented which are supposed to be carried out with this EXAFS spectrometer. (author). 4 refs., 14 figs., 1 tab. Submitted to Poverkhnost`. Rentgenovskie, Sinkhrotronnye i Nejtronnye Issledovaniya.

Development of the 2nd generation z(Redshift) and early universe spectrometer & the study of far-IR fine structure emission in high-z galaxies

Science.gov (United States)

Ferkinhoff, Carl

The 2nd generation z (Redshift) and Early Universe Spectrometer (ZEUS-2), is a long-slit echelle-grating spectrometer (R~1000) for observations at submillimeter wavelengths from 200 to 850 microm. Its design is optimized for the detection of redshifted far-infrared spectral lines from galaxies in the early universe. Combining exquisite sensitivity, broad wavelength coverage, and large (˜2.5%) instantaneous bandwidth, ZEUS-2 is uniquely suited for studying galaxies between z˜0.2 and 5---spanning the peaks in both the star formation rate and number of AGN in the universe. ZEUS-2 saw first light at the Caltech Submillimeter Observatory (CSO) in the Spring of 2012 and was commissioned on the Atacama Pathfinder Experiment (APEX) in November 2012. Here we detail the design and performance of ZEUS-2, first however we discuss important science results that are examples of the science enabled by ZEUS-2. Using the first generation z (Redshift) and Early Universe Spectrometer (ZEUS-1) we made the first high-z detections of the [NII] 122 microm and [OIII] 88 microm lines. We detect these lines from starburst galaxies between z ˜2.5 and 4 demonstrating the utility of these lines for characterizing the properties of early galaxies. Specifically we are able to determine the most massive star still on the main sequence, the number of those stars and a lower limit on the mass of ionized gas in the source. Next we present ZEUS-2's first science result. Using ZEUS-2 on APEX we have detected the [CII] 158 microm line from the z = 1.78 galaxy H-ATLAS J091043.1-000322 with a line flux of (6.44 +/- 0.42) ˜ 10-18 W m-2. Combined with its far-infrared luminosity and a new Herschel-PACS detection of the [OI] 63 microm line we are able to conclude that H-ATLAS J091043.1-000322 is a high redshift analogue of a local ultra-luminous infrared galaxy, i.e. it is likely the site of a compact starburst due to a major merger. This detection, combined with the ZEUS-1 observations of the [NII

The Atmospheric Chemistry Suite (ACS) of Three Spectrometers for the ExoMars 2016 Trace Gas Orbiter

Science.gov (United States)

Korablev, O.; Montmessin, F.; Trokhimovskiy, A.; Fedorova, A. A.; Shakun, A. V.; Grigoriev, A. V.; Moshkin, B. E.; Ignatiev, N. I.; Forget, F.; Lefèvre, F.; Anufreychik, K.; Dzuban, I.; Ivanov, Y. S.; Kalinnikov, Y. K.; Kozlova, T. O.; Kungurov, A.; Makarov, V.; Martynovich, F.; Maslov, I.; Merzlyakov, D.; Moiseev, P. P.; Nikolskiy, Y.; Patrakeev, A.; Patsaev, D.; Santos-Skripko, A.; Sazonov, O.; Semena, N.; Semenov, A.; Shashkin, V.; Sidorov, A.; Stepanov, A. V.; Stupin, I.; Timonin, D.; Titov, A. Y.; Viktorov, A.; Zharkov, A.; Altieri, F.; Arnold, G.; Belyaev, D. A.; Bertaux, J. L.; Betsis, D. S.; Duxbury, N.; Encrenaz, T.; Fouchet, T.; Gérard, J.-C.; Grassi, D.; Guerlet, S.; Hartogh, P.; Kasaba, Y.; Khatuntsev, I.; Krasnopolsky, V. A.; Kuzmin, R. O.; Lellouch, E.; Lopez-Valverde, M. A.; Luginin, M.; Määttänen, A.; Marcq, E.; Martin Torres, J.; Medvedev, A. S.; Millour, E.; Olsen, K. S.; Patel, M. R.; Quantin-Nataf, C.; Rodin, A. V.; Shematovich, V. I.; Thomas, I.; Thomas, N.; Vazquez, L.; Vincendon, M.; Wilquet, V.; Wilson, C. F.; Zasova, L. V.; Zelenyi, L. M.; Zorzano, M. P.

2018-02-01

The Atmospheric Chemistry Suite (ACS) package is an element of the Russian contribution to the ESA-Roscosmos ExoMars 2016 Trace Gas Orbiter (TGO) mission. ACS consists of three separate infrared spectrometers, sharing common mechanical, electrical, and thermal interfaces. This ensemble of spectrometers has been designed and developed in response to the Trace Gas Orbiter mission objectives that specifically address the requirement of high sensitivity instruments to enable the unambiguous detection of trace gases of potential geophysical or biological interest. For this reason, ACS embarks a set of instruments achieving simultaneously very high accuracy (ppt level), very high resolving power (>10,000) and large spectral coverage (0.7 to 17 μm—the visible to thermal infrared range). The near-infrared (NIR) channel is a versatile spectrometer covering the 0.7-1.6 μm spectral range with a resolving power of ˜20,000. NIR employs the combination of an echelle grating with an AOTF (Acousto-Optical Tunable Filter) as diffraction order selector. This channel will be mainly operated in solar occultation and nadir, and can also perform limb observations. The scientific goals of NIR are the measurements of water vapor, aerosols, and dayside or night side airglows. The mid-infrared (MIR) channel is a cross-dispersion echelle instrument dedicated to solar occultation measurements in the 2.2-4.4 μm range. MIR achieves a resolving power of >50,000. It has been designed to accomplish the most sensitive measurements ever of the trace gases present in the Martian atmosphere. The thermal-infrared channel (TIRVIM) is a 2-inch double pendulum Fourier-transform spectrometer encompassing the spectral range of 1.7-17 μm with apodized resolution varying from 0.2 to 1.3 cm-1. TIRVIM is primarily dedicated to profiling temperature from the surface up to ˜60 km and to monitor aerosol abundance in nadir. TIRVIM also has a limb and solar occultation capability. The technical concept of

Development of Tandem, Double-Focusing, Electron Impact, Gas Source Mass Spectrometer for Measurement of Rare Double-Substituted Isotoplogues in Geochemistry

Energy Technology Data Exchange (ETDEWEB)

Young, Edward D. [University of California, Los Angeles, CA (United States)

2015-07-30

This project culminated in construction and delivery of the world’s first large-radius gas-source isotope ratio mass spectrometer that permits unparalleled analyses of the stable isotopic composition of methane gas. The instrument, referred to as the “Panorama” and installed at UCLA in March 2015, can now be used to determine the relative abundances of rare isotopic species of methane that serve as tracers of temperature of formation and/or subsequent processing of gas. With this technology we can begin to delineate different sources and sinks of methane isotopically in ways not possible until now.

Digital Spectrometers for Interplanetary Science Missions

Science.gov (United States)

Jarnot, Robert F.; Padmanabhan, Sharmila; Raffanti, Richard; Richards, Brian; Stek, Paul; Werthimer, Dan; Nikolic, Borivoje

2010-01-01

A fully digital polyphase spectrometer recently developed by the University of California Berkeley Wireless Research Center in conjunction with the Jet Propulsion Laboratory provides a low mass, power, and cost implementation of a spectrum channelizer for submillimeter spectrometers for future missions to the Inner and Outer Solar System. The digital polyphase filter bank spectrometer (PFB) offers broad bandwidth with high spectral resolution, minimal channel-to-channel overlap, and high out-of-band rejection.

Spectrometer gun

Science.gov (United States)

Waechter, David A.; Wolf, Michael A.; Umbarger, C. John

1985-01-01

A hand-holdable, battery-operated, microprocessor-based spectrometer gun includes a low-power matrix display and sufficient memory to permit both real-time observation and extended analysis of detected radiation pulses. Universality of the incorporated signal processing circuitry permits operation with various detectors having differing pulse detection and sensitivity parameters.

Gamma-ray spectrometer utilizing xenon at high pressure

International Nuclear Information System (INIS)

Smith, G.C.; Mahler, G.J.; Yu, B.; Kane, W.R.; Markey, J.K.

1994-01-01

A prototype gamma-ray spectrometer utilizing xenon gas near the critical point (166 degrees C, 58 atm) is under development. The spectrometer will function as a room-temperature ionization chamber detecting gamma rays in the energy range 100 keV2 MeV, with an energy resolution intermediate between semiconductor (Ge) and scintillation (NaI) spectrometers. The energy resolution is superior to that of a NaI scintillation spectrometer by a substantial margin (approximately a factor 5), and accordingly, much more information can be extracted from a given gamma-ray spectrum. Unlike germanium detectors, the spectrometer possesses the capability for sustained operation under ambient temperature conditions without a requirement for liquid nitrogen

Wide-aperture magnetic spectrometer with face position of MWPC

International Nuclear Information System (INIS)

Avakyan, R.O.; Avetisyan, A.Eh.; Ajvazyan, R.B.; Asaturyan, R.A.; Dallakyan, K.R.; Kizogyan, O.S.; Matevosyan, Eh.M.; Sukiasyan, Yu.Z.; Taroyan, S.P.

1988-01-01

A pair magnetic spectrometer with automated wire chambers for studying electron and positron interactions with monocrystals at the Erevan synchrotron is described. As a working gas the argon-methane mixture with methylal vapor addition is used. Results of modelling and experiments with spectrometer are presented. 2 refs.; 6 figs

On the ability of the Viking gas chromatograph-mass spectrometer to detect organic matter.

Science.gov (United States)

Biemann, Klaus

2007-06-19

A recent paper by Navarro-Gonzalez et al. [Navarro-Gonzalez R, Navarro KF, de la Rosa J, Iniguez E, Molina P, Miranda LD, Morales P, Cienfuegos E, Coll P, Raulin F, et al. (2006) Proc Natl Acad Sci USA 103:16089-16094] claims to show that the Viking GCMS (gas chromatograph-mass spectrometer) experiment, which carried out a search for organic matter at the surface of Mars in 1976, "may have been blind to low levels of organics." To rebut this assertion, the Viking experiment, test data, and results on Mars are reviewed, and the fallacies in the design, execution, and interpretation of the new experiments presented by Navarro-Gonzalez et al. are critically examined.

A highly polarized hydrogen/deuterium internal gas target embedded in a toroidal magnetic spectrometer

International Nuclear Information System (INIS)

Cheever, D.; Ihloff, E.; Kelsey, J.; Kolster, H.; Meitanis, N.; Milner, R.; Shinozaki, A.; Tsentalovich, E.; Zwart, T.; Ziskin, V.; Xiao, Y.; Zhang, C.

2006-01-01

A polarized hydrogen/deuterium internal gas target has been constructed and operated at the internal target region of the South Hall Ring (SHR) of the MIT-Bates Linear Accelerator Center to carry out measurements of spin-dependent electron scattering at 850MeV. The target used an Atomic Beam Source (ABS) to inject a flux of highly polarized atoms into a thin-walled, coated storage cell. The polarization of the electron beam was determined using a Compton laser backscattering polarimeter. The target polarization was determined using well-known nuclear reactions. The ABS and storage cell were embedded in the Bates Large Acceptance Toroidal Spectrometer (BLAST), which was used to detect scattered particles from the electron-target interactions. The target has been designed to rapidly (∼8h) switch operation from hydrogen to deuterium. Further, this target was the first to be operated inside a magnetic spectrometer in the presence of a magnetic field exceeding 2kG. An ABS intensity 2.5x10 16 at/s and a high polarization (∼70%) inside the storage cell have been achieved. The details of the target design and construction are described here and the performance over an 18 month period is reported

The second-generation z (redshift) and early universe spectrometer. I. First-light observation of a highly lensed local-ulirg analog at high-z

Energy Technology Data Exchange (ETDEWEB)

Ferkinhoff, Carl; Brisbin, Drew; Parshley, Stephen; Nikola, Thomas; Stacey, Gordon J.; Schoenwald, Justin; Riechers, Dominik [Department of Astronomy, Cornell University, Ithaca, NY 14853 (United States); Higdon, James L.; Higdon, Sarah J. U. [Department of Physics, Georgia Southern University, Statesboro, GA 30460 (United States); Verma, Aprajita [Department of Physics, University of Oxford, Oxford, OX1 3RH (United Kingdom); Hailey-Dunsheath, Steven [California Institute of Technology, Pasadena, CA 91125 (United States); Menten, Karl M.; Güsten, Rolf; Weiß, Axel [Max-Planck-Institut für Radioastronomie, Auf dem Hügel 69, D-53121 Bonn (Germany); Irwin, Kent; Cho, Hsiao M. [NIST Boulder, Boulder, CO 80305 (United States); Niemack, Michael [Department of Physics, Cornell University, Ithaca, NY 14853 (United States); Halpern, Mark; Amiri, Mandana [Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); Hasselfield, Matthew, E-mail: carl.ferkinhoff@cornell.edu [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States); and others

2014-01-10

We recently commissioned our new spectrometer, the second-generation z(Redshift) and Early Universe Spectrometer (ZEUS-2) on the Atacama Pathfinder Experiment telescope. ZEUS-2 is a submillimeter grating spectrometer optimized for detecting the faint and broad lines from distant galaxies that are redshifted into the telluric windows from 200 to 850 μm. It uses a focal plane array of transition-edge sensed bolometers, the first use of these arrays for astrophysical spectroscopy. ZEUS-2 promises to be an important tool for studying galaxies in the years to come because of its synergy with Atacama Large Millimeter Array and its capabilities in the short submillimeter windows that are unique in the post-Herschel era. Here, we report on our first detection of the [C II] 158 μm line with ZEUS-2. We detect the line at z ∼ 1.8 from H-ATLAS J091043.1–000322 with a line flux of (6.44 ± 0.42) × 10{sup –18} W m{sup –2}. Combined with its far-IR luminosity and a new Herschel-PACS detection of the [O I] 63 μm line, we model the line emission as coming from a photo-dissociation region with far-ultraviolet radiation field, G ∼ 2 × 10{sup 4} G {sub 0}, gas density, n ∼ 1 × 10{sup 3} cm{sup –3} and size between ∼0.4 and 1 kpc. On the basis of this model, we conclude that H-ATLAS J091043.1–000322 is a high-redshift analog of a local ultra-luminous IR galaxy; i.e., it is likely the site of a compact starburst caused by a major merger. Further identification of these merging systems is important for constraining galaxy formation and evolution models.

The Second-generation z (Redshift) and Early Universe Spectrometer. I. First-light Observation of a Highly Lensed Local-ulirg Analog at High-z

Science.gov (United States)

Ferkinhoff, Carl; Brisbin, Drew; Parshley, Stephen; Nikola, Thomas; Stacey, Gordon J.; Schoenwald, Justin; Higdon, James L.; Higdon, Sarah J. U.; Verma, Aprajita; Riechers, Dominik; Hailey-Dunsheath, Steven; Menten, Karl M.; Güsten, Rolf; Weiß, Axel; Irwin, Kent; Cho, Hsiao M.; Niemack, Michael; Halpern, Mark; Amiri, Mandana; Hasselfield, Matthew; Wiebe, D. V.; Ade, Peter A. R.; Tucker, Carol E.

2014-01-01

We recently commissioned our new spectrometer, the second-generation z(Redshift) and Early Universe Spectrometer (ZEUS-2) on the Atacama Pathfinder Experiment telescope. ZEUS-2 is a submillimeter grating spectrometer optimized for detecting the faint and broad lines from distant galaxies that are redshifted into the telluric windows from 200 to 850 μm. It uses a focal plane array of transition-edge sensed bolometers, the first use of these arrays for astrophysical spectroscopy. ZEUS-2 promises to be an important tool for studying galaxies in the years to come because of its synergy with Atacama Large Millimeter Array and its capabilities in the short submillimeter windows that are unique in the post-Herschel era. Here, we report on our first detection of the [C II] 158 μm line with ZEUS-2. We detect the line at z ~ 1.8 from H-ATLAS J091043.1-000322 with a line flux of (6.44 ± 0.42) × 10-18 W m-2. Combined with its far-IR luminosity and a new Herschel-PACS detection of the [O I] 63 μm line, we model the line emission as coming from a photo-dissociation region with far-ultraviolet radiation field, G ~ 2 × 104 G 0, gas density, n ~ 1 × 103 cm-3 and size between ~0.4 and 1 kpc. On the basis of this model, we conclude that H-ATLAS J091043.1-000322 is a high-redshift analog of a local ultra-luminous IR galaxy; i.e., it is likely the site of a compact starburst caused by a major merger. Further identification of these merging systems is important for constraining galaxy formation and evolution models.

The second-generation z (redshift) and early universe spectrometer. I. First-light observation of a highly lensed local-ulirg analog at high-z

International Nuclear Information System (INIS)

Ferkinhoff, Carl; Brisbin, Drew; Parshley, Stephen; Nikola, Thomas; Stacey, Gordon J.; Schoenwald, Justin; Riechers, Dominik; Higdon, James L.; Higdon, Sarah J. U.; Verma, Aprajita; Hailey-Dunsheath, Steven; Menten, Karl M.; Güsten, Rolf; Weiß, Axel; Irwin, Kent; Cho, Hsiao M.; Niemack, Michael; Halpern, Mark; Amiri, Mandana; Hasselfield, Matthew

2014-01-01

We recently commissioned our new spectrometer, the second-generation z(Redshift) and Early Universe Spectrometer (ZEUS-2) on the Atacama Pathfinder Experiment telescope. ZEUS-2 is a submillimeter grating spectrometer optimized for detecting the faint and broad lines from distant galaxies that are redshifted into the telluric windows from 200 to 850 μm. It uses a focal plane array of transition-edge sensed bolometers, the first use of these arrays for astrophysical spectroscopy. ZEUS-2 promises to be an important tool for studying galaxies in the years to come because of its synergy with Atacama Large Millimeter Array and its capabilities in the short submillimeter windows that are unique in the post-Herschel era. Here, we report on our first detection of the [C II] 158 μm line with ZEUS-2. We detect the line at z ∼ 1.8 from H-ATLAS J091043.1–000322 with a line flux of (6.44 ± 0.42) × 10 –18 W m –2 . Combined with its far-IR luminosity and a new Herschel-PACS detection of the [O I] 63 μm line, we model the line emission as coming from a photo-dissociation region with far-ultraviolet radiation field, G ∼ 2 × 10 4 G 0 , gas density, n ∼ 1 × 10 3 cm –3 and size between ∼0.4 and 1 kpc. On the basis of this model, we conclude that H-ATLAS J091043.1–000322 is a high-redshift analog of a local ultra-luminous IR galaxy; i.e., it is likely the site of a compact starburst caused by a major merger. Further identification of these merging systems is important for constraining galaxy formation and evolution models.

Electron-ion-x-ray spectrometer system

International Nuclear Information System (INIS)

Southworth, S.H.; Deslattes, R.D.; MacDonald, M.A.

1993-01-01

The authors describe a spectrometer system developed for electron, ion, and x-ray spectroscopy of gas-phase atoms and molecules following inner-shell excitation by tunable synchrotron radiation. The spectrometer has been used on beamline X-24A at the National Synchrotron Light Source for excitation-dependent studies of Ar L-shell and K-shell photoexcitation and vacancy decay processes. The instrumentation and experimental methods are discussed, and examples are given of electron spectra and coincidence spectra between electrons and fluorescent x-rays

The university of Colorado OSO-8 spectrometer experiment. Pt. 4

International Nuclear Information System (INIS)

Hansen, E.R.; Bruner, E.C. Jr.

1979-01-01

We discuss the remote operation of two high resolution ultraviolet spectrometers on the OSO-8 satellite; one prepared by the Laboratory for Planetary and Stellar Physics in Paris, France and the other by the Laboratory for Atmospheric and Space Physics at the University of Colorado at Boulder. Mission operations, from the Colorado facility, enabled the scientific observers to plan observations based on current solar data, interact with the observing program using real or near real-time data and commands, evaluate quick-look instrument data, and analyze the observations for publication. The scientists were supplied with daily solar images and satellite event timelines to aid in experiment planning. Command generation programs converted these observing plans into time-ordered, error-free commands for control of spacecraft and instrument functions. Real and near real-time data and commands via ground data lines were available for interactive target acquisition and instrument reconfiguration. An on-board computer system provided closed-loop target acquisition and instrument control. A sophisticated ground computer system was used for data line communications, data formatting, interactive scientific data display, and in-depth analysis. (orig.)

A field-deployable gamma-ray spectrometer utilizing xenon at high pressure

International Nuclear Information System (INIS)

Smith, G.C.; Mahler, G.J.; Yu, B.; Salwen, C.; Kane, W.R.; Lemley, J.R.

1996-01-01

Prototype gamma-ray spectrometers utilizing xenon gas at high pressure, suitable for applications in the nuclear safeguards, arms control, and nonproliferation communities, have been developed at Brookhaven National Laboratory (BNL). These spectrometers function as ambient-temperature ionization chambers detecting gamma rays with good efficiency in the energy range 50 keV - 2 MeV, with an energy resolution intermediate between semiconductor (Ge) and scintillation (NaI) spectrometers. They are capable of prolonged, low-power operation without a requirement for cryogenic fluids or other cooling mechanisms, and with the addition of small quantities of 3 He gas, can function simultaneously as efficient thermal neutron detectors

On-line mass spectrometry measurement of fission gas release from nuclear fuel submitted to thermal transients

International Nuclear Information System (INIS)

Guigues, E.; Janulyte, A.; Zerega, Y.; Pontillon, Y.

2013-06-01

The work presented in this paper has been performed in the framework of a joint research program between Aix-Marseille University and CEA Cadarache. The aim is to develop a mass spectrometer (MS) device for the MERARG facility. MERARG is devoted to the study of fission gas release measurement, from nuclear fuels submitted to annealing tests in high activity laboratory such as LECA-STAR, thanks to gamma spectrometry. The mass spectrometer will then extend the measurement capability from the γ-emitters gases to all the gases involved in the release in order to have a better understanding of the fission gas release dynamics from fuel during thermal transients. Furthermore, the mass spectrometer instrument combines the capabilities and performances of both on-line (for release kinetic) and off-line implementations (for delayed accurate analysis of capacities containing total release gas). The paper deals with two main axes: (1) the modelling of gas sampling inlet device and its performance and (2) the first MS qualification/calibration results. The inlet device samples the gas and also adapts the pressure between MERARG sweeping line at 1.2 bar and mass spectrometer chamber at high vacuum. It is a two-stage device comprising a capillary at inlet, an intermediate vacuum chamber, a molecular leak inlet and a two-stage pumping device. Pressure drops, conductance and throughputs are estimated both for mass spectrometer operation and for exhaust gas recovery. Possible gas segregation is also estimated and device modification is proposed to attain a more accurate calibration. First experimental results obtained from a standard gas bottle show that the quantitative analysis at a few ppm level can be achieved for all isotopes of Kr and Xe, as well as masses 2 and 4 u. (authors)

Gas-cooled reactor application for a university campus

International Nuclear Information System (INIS)

Colak, Ue.; Kadiroghlu, O.K.; Soekmen, C.N.; Schmitt, H.

1991-01-01

Large urban areas with unfavourable topographic and meteorological conditions suffer severe air pollution during the winter months. Use of low grade lignites, imported higher quality coal or imported fuel oil are the sources of air pollution in the form of sulphur dioxide, fly ash and soot. Large housing complexes or old and historical locations within the city are in need of pollution free centralized district heating systems. Natural gas imported from the Soviet Union is a solution for this problem. Lack of gas distribution network for high pressure gas within the city is the main bottle-neck for the heating systems utilizing natural gas. Concern of the safety of flammable high pressure gas circulating within the city is another drawback for the natural gas heating systems. Nuclear district heating is an environmentally viable option worth looking into it. Localized urban nuclear heating is an interesting solution for large urban areas with old and historical character. The results of a feasibility study on the HGR application for the Hacettepe University presented here, summarizes the concept of gas-cooled heating reactors specially designed for urban centers. The inherently safe characteristics of the pebble bed heating reactor makes localized urban nuclear heating a viable alternative to other heat sources. An economical analysis of various heat sources with equal power levels is done for the Beytepe campus of Hacettepe University in Ankara. Under special boundary conditions, the price for heat generation can be much lower for nuclear heating with GHR 20 than for hard coal or fuel oil. It is also possible that if the price escalation rate for natural gas exceeds 3%, then nuclear heating with GHR can be more competitive. It is concluded that the nuclear heating of Beytepe campus with a GHR 20 is feasible and economical. (author) 3 figs., 5 refs

Multichannel Dynamic Fourier-Transform IR Spectrometer

Science.gov (United States)

Balashov, A. A.; Vaguine, V. A.; Golyak, Il. S.; Morozov, A. N.; Khorokhorin, A. I.

2017-09-01

A design of a multichannel continuous scan Fourier-transform IR spectrometer for simultaneous recording and analysis of the spectral characteristics of several objects is proposed. For implementing the design, a multi-probe fiber is used, constructed from several optical fibers connected into a single optical connector and attached at the output of the interferometer. The Fourier-transform spectrometer is used as a signal modulator. Each fiber is individually mated with an investigated sample and a dedicated radiation detector. For the developed system, the radiation intensity of the spectrometer is calculated from the condition of the minimum spectral resolution and parameters of the optical fibers. Using the proposed design, emission spectra of a gas-discharge neon lamp have been recorded using a single fiber 1 mm in diameter with a numerical aperture NA = 0.22.

Interacting polytropic gas model of phantom dark energy in non-flat universe

International Nuclear Information System (INIS)

Karami, K.; Ghaffari, S.; Fehri, J.

2009-01-01

By introducing the polytropic gas model of interacting dark energy, we obtain the equation of state for the polytropic gas energy density in a non-flat universe. We show that for an even polytropic index by choosing K>Ba (3)/(n) , one can obtain ω Λ eff <-1, which corresponds to a universe dominated by phantom dark energy. (orig.)

Potential for Measurement of Trace Volatile Organic Compounds in Closed Environments Using Gas Chromatograph/Differential Mobility Spectrometer

Science.gov (United States)

Limero, Thomas; Cheng, Patti

2007-01-01

For nearly 3.5 years, the Volatile Organic Analyzer (VOA) has routinely analyzed the International Space Station (ISS) atmosphere for a target list of approximately 20 volatile organic compounds (VOCs). Additionally, an early prototype of the VOA collected data aboard submarines in two separate trials. Comparison of the data collected on ISS and submarines showed a surprising similarity in the atmospheres of the two environments. Furthermore, in both cases it was demonstrated that the VOA data can detect hardware issues unrelated to crew health. Finally, it was also clear in both operations that the VOA s size and resource consumption were major disadvantages that would restrict its use in the future. The VOA showed the value of measuring VOCs in closed environments, but it had to be shrunk if it was to be considered for future operations in these environments that are characterized by cramped spaces and limited resources. The Sionex Microanalyzer is a fraction of the VOA s size and this instrument seems capable of maintaining or improving upon the analytical performance of the VOA. The two design improvements that led to a smaller, less complex instrument are the Microanalyzer s use of recirculated air as the gas chromatograph s carrier gas and a micromachined detector. Although the VOA s ion mobility spectrometer and the Microanalyzer s differential mobility spectrometer (DMS) are related detector technologies, the DMS was more amenable to micromachining. This paper will present data from the initial assessment of the Microanalyzer. The instrument was challenged with mixtures that simulated the VOCs typically detected in closed-environment atmospheres.

The motion of an isolated gas group in expanding universe

International Nuclear Information System (INIS)

Zhang Banggu

1993-01-01

The contraction of an isolated gas group in the expanding universe has been discussed. It is found that in addition to the contracted conditions of the static isolated gas group, the initial gas group is straticulate statistical uniform and the initial radius is larger than a critical value D γ -1 , the contracted conditions of expanding case also include that the Hubble constant H is smaller than a constant D t

Silicon Microleaks for Inlets of Mass Spectrometers

Science.gov (United States)

Harpold, Dan; Hasso, Niemann; Jamieson, Brian G.; Lynch, Bernard A.

2009-01-01

Microleaks for inlets of mass spectrometers used to analyze atmospheric gases can be fabricated in silicon wafers by means of photolithography, etching, and other techniques that are commonly used in the manufacture of integrated circuits and microelectromechanical systems. The microleaks serve to limit the flows of the gases into the mass-spectrometer vacuums to specified very small flow rates consistent with the capacities of the spectrometer vacuum pumps. There is a need to be able to precisely tailor the dimensions of each microleak so as to tailor its conductance to a precise low value. (As used here, "conductance" signifies the ratio between the rate of flow in the leak and the pressure drop from the upstream to the downstream end of the leak.) To date, microleaks have been made, variously, of crimped metal tubes, pulled glass tubes, or frits. Crimped-metal and pulled-glass-tube microleaks cannot readily be fabricated repeatably to precise dimensions and are susceptible to clogging with droplets or particles. Frits tend to be differentially chemically reactive with various gas constituents and, hence, to distort the gas mixtures to be analyzed. The present approach involving microfabrication in silicon largely overcomes the disadvantages of the prior approaches.

Ferrographic and spectrometer oil analysis from a failed gas turbine engine

Science.gov (United States)

Jones, W. R., Jr.

1982-01-01

An experimental gas turbine engine was destroyed as a result of the combustion of its titanium components. It was concluded that a severe surge may have caused interference between rotating and stationary compressor that either directly or indirectly ignited the titanium components. Several engine oil samples (before and after the failure) were analyzed with a Ferrograph, a plasma, an atomic absorption, and an emission spectrometer to see if this information would aid in the engine failure diagnosis. The analyses indicated that a lubrication system failure was not a causative factor in the engine failure. Neither an abnormal wear mechanism nor a high level of wear debris was detected in the engine oil sample taken just prior to the test in which the failure occurred. However, low concentrations (0.2 to 0.5 ppm) of titanium were evident in this sample and samples taken earlier. After the failure, higher titanium concentrations ( 2 ppm) were detected in oil samples taken from different engine locations. Ferrographic analysis indicated that most of the titanium was contained in spherical metallic debris after the failure. The oil analyses eliminated a lubrication system bearing or shaft seal failure as the cause of the engine failure.

Time-of-flight mass spectrometer

International Nuclear Information System (INIS)

Ivanov, M.A.; Kozlov, B.N.; Mamyrin, B.A.; Shmikk, D.V.; Shebelin, V.G.

1981-01-01

A time-of-flight mass spectrometer containing a pulsed ion source with an electron gun and two electrodes limiting ionization range, drift space and ion acceptor, is described. To expand functional possibilities, a slot collimator of the gas stream, two quantum generators and two diaphragms for the inlet of quantum generator radiation located on both sides of the ion source, are introduced in the ion source. The above invention enables to study details of the complex interaction process of laser radiation with molecules of the gas stream, which is actual for laser isotope separation

Influence of the coupling between an atmospheric pressure ion mobility spectrometer and the low pressure ion inlet of a mass spectrometer on the mobility measurement

Directory of Open Access Journals (Sweden)

Gunzer Frank

2016-01-01

Full Text Available Ion mobility spectrometers (IMS are versatile gas analyzers. Due to their small size and robustness, combined with a very high sensitivity, they are often used in gas sensing applications such as environmental monitoring. In order to improve the selectivity, they are typically combined with a mass spectrometer (MS. Since IMS works at atmospheric pressure, and MS works at vacuum, a special interface reducing the pressure over normally two stages has to be used. In this paper the influence of this coupling of different pressure areas on the IMS signal will be analyzed with help of finite elements method simulations.

Artificial intelligence for geologic mapping with imaging spectrometers

Science.gov (United States)

Kruse, F. A.

1993-01-01

This project was a three year study at the Center for the Study of Earth from Space (CSES) within the Cooperative Institute for Research in Environmental Science (CIRES) at the University of Colorado, Boulder. The goal of this research was to develop an expert system to allow automated identification of geologic materials based on their spectral characteristics in imaging spectrometer data such as the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS). This requirement was dictated by the volume of data produced by imaging spectrometers, which prohibits manual analysis. The research described is based on the development of automated techniques for analysis of imaging spectrometer data that emulate the analytical processes used by a human observer. The research tested the feasibility of such an approach, implemented an operational system, and tested the validity of the results for selected imaging spectrometer data sets.

Direct Analysis of Organic Compounds in Liquid Using a Miniature Photoionization Ion Trap Mass Spectrometer with Pulsed Carrier-Gas Capillary Inlet.

Science.gov (United States)

Lu, Xinqiong; Yu, Quan; Zhang, Qian; Ni, Kai; Qian, Xiang; Tang, Fei; Wang, Xiaohao

2017-08-01

A miniature ion trap mass spectrometer with capillary direct sampling and vacuum ultraviolet photoionization source was developed to conduct trace analysis of organic compounds in liquids. Self-aspiration sampling is available where the samples are drawn into the vacuum chamber through a capillary with an extremely low flow rate (less than 1 μL/min), which minimizes sample consumption in each analysis to tens of micrograms. A pulsed gas-assisted inlet was designed and optimized to promote sample transmission in the tube and facilitate the cooling of ions, thereby improving instrument sensitivity. A limit of detection of 2 ppb could be achieved for 2,4-dimethylaniline in a methanol solution. The sampling system described in the present study is specifically suitable for a miniature photoionization ion trap mass spectrometer that can perform rapid and online analysis for liquid samples. Graphical Abstract ᅟ.

High molecular gas fractions in normal massive star-forming galaxies in the young Universe.

Science.gov (United States)

Tacconi, L J; Genzel, R; Neri, R; Cox, P; Cooper, M C; Shapiro, K; Bolatto, A; Bouché, N; Bournaud, F; Burkert, A; Combes, F; Comerford, J; Davis, M; Schreiber, N M Förster; Garcia-Burillo, S; Gracia-Carpio, J; Lutz, D; Naab, T; Omont, A; Shapley, A; Sternberg, A; Weiner, B

2010-02-11

Stars form from cold molecular interstellar gas. As this is relatively rare in the local Universe, galaxies like the Milky Way form only a few new stars per year. Typical massive galaxies in the distant Universe formed stars an order of magnitude more rapidly. Unless star formation was significantly more efficient, this difference suggests that young galaxies were much more molecular-gas rich. Molecular gas observations in the distant Universe have so far largely been restricted to very luminous, rare objects, including mergers and quasars, and accordingly we do not yet have a clear idea about the gas content of more normal (albeit massive) galaxies. Here we report the results of a survey of molecular gas in samples of typical massive-star-forming galaxies at mean redshifts of about 1.2 and 2.3, when the Universe was respectively 40% and 24% of its current age. Our measurements reveal that distant star forming galaxies were indeed gas rich, and that the star formation efficiency is not strongly dependent on cosmic epoch. The average fraction of cold gas relative to total galaxy baryonic mass at z = 2.3 and z = 1.2 is respectively about 44% and 34%, three to ten times higher than in today's massive spiral galaxies. The slow decrease between z approximately 2 and z approximately 1 probably requires a mechanism of semi-continuous replenishment of fresh gas to the young galaxies.

Herschel-spire Fourier transform spectrometer observations of excited CO and [C I] in the antennae (NGC 4038/39): Warm and cold molecular gas

Energy Technology Data Exchange (ETDEWEB)

Schirm, Maximilien R. P.; Wilson, Christine D.; Parkin, Tara J. [Department of Physics and Astronomy, McMaster University, Hamilton, ON L8S 4M1 (Canada); Kamenetzky, Julia; Glenn, Jason; Rangwala, Naseem [Center for Astrophysics and Space Astronomy, 389-UCB, University of Colorado, Boulder, CO 80303 (United States); Spinoglio, Luigi; Pereira-Santaella, Miguel [Istituto di Astrofisica e Planetologia Spaziali, INAF-IAPS, Via Fosso del Cavaliere 100, I-00133 Roma (Italy); Baes, Maarten; De Looze, Ilse [Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281 S9, B-9000 Gent (Belgium); Barlow, Michael J. [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Clements, Dave L. [Astrophysics Group, Imperial College, Blackett Laboratory, Prince Consort Road, London SW7 2AZ (United Kingdom); Cooray, Asantha [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States); Karczewski, Oskar Ł. [Department of Physics and Astronomy, University of Sussex, Brighton BN1 9QH (United Kingdom); Madden, Suzanne C.; Rémy-Ruyer, Aurélie; Wu, Ronin, E-mail: schirmmr@mcmaster.ca, E-mail: wilson@physics.mcmaster.ca [CEA, Laboratoire AIM, Irfu/SAp, Orme des Merisiers, F-91191 Gif-sur-Yvette (France)

2014-02-01

We present Herschel Spectral and Photometric Imaging Receiver (SPIRE) Fourier Transform Spectrometer (FTS) observations of the Antennae (NGC 4038/39), a well-studied, nearby (22 Mpc), ongoing merger between two gas-rich spiral galaxies. The SPIRE-FTS is a low spatial ( FWHM ∼ 19''-43'') and spectral (∼1.2 GHz) resolution mapping spectrometer covering a large spectral range (194-671 μm, 450-1545 GHz). We detect five CO transitions (J = 4-3 to J = 8-7), both [C I] transitions, and the [N II] 205 μm transition across the entire system, which we supplement with ground-based observations of the CO J = 1-0, J = 2-1, and J = 3-2 transitions and Herschel Photodetecting Array Camera and Spectrometer (PACS) observations of [C II] and [O I] 63 μm. Using the CO and [C I] transitions, we perform both a local thermodynamic equilibrium (LTE) analysis of [C I] and a non-LTE radiative transfer analysis of CO and [C I] using the radiative transfer code RADEX along with a Bayesian likelihood analysis. We find that there are two components to the molecular gas: a cold (T {sub kin} ∼ 10-30 K) and a warm (T {sub kin} ≳ 100 K) component. By comparing the warm gas mass to previously observed values, we determine a CO abundance in the warm gas of x {sub CO} ∼ 5 × 10{sup –5}. If the CO abundance is the same in the warm and cold gas phases, this abundance corresponds to a CO J = 1-0 luminosity-to-mass conversion factor of α{sub CO} ∼ 7 M {sub ☉} pc{sup –2} (K km s{sup –1}){sup –1} in the cold component, similar to the value for normal spiral galaxies. We estimate the cooling from H{sub 2}, [C II], CO, and [O I] 63 μm to be ∼0.01 L {sub ☉}/M {sub ☉}. We compare photon-dominated region models to the ratio of the flux of various CO transitions, along with the ratio of the CO flux to the far-infrared flux in NGC 4038, NGC 4039, and the overlap region. We find that the densities recovered from our non-LTE analysis are consistent with a

AI mass spectrometers for space shuttle health monitoring

Science.gov (United States)

Adams, F. W.

1991-01-01

The facility Hazardous Gas Detection System (HGDS) at Kennedy Space Center (KSC) is a mass spectrometer based gas analyzer. Two instruments make up the HGDS, which is installed in a prime/backup arrangement, with the option of using both analyzers on the same sample line, or on two different lines simultaneously. It is used for monitoring the Shuttle during fuel loading, countdown, and drainback, if necessary. The use of complex instruments, operated over many shifts, has caused problems in tracking the status of the ground support equipment (GSE) and the vehicle. A requirement for overall system reliability has been a major force in the development of Shuttle GSE, and is the ultimate driver in the choice to pursue artificial intelligence (AI) techniques for Shuttle and Advanced Launch System (ALS) mass spectrometer systems. Shuttle applications of AI are detailed.

Universal model for water costs of gas exchange by animals and plants.

Science.gov (United States)

Woods, H Arthur; Smith, Jennifer N

2010-05-04

For terrestrial animals and plants, a fundamental cost of living is water vapor lost to the atmosphere during exchange of metabolic gases. Here, by bringing together previously developed models for specific taxa, we integrate properties common to all terrestrial gas exchangers into a universal model of water loss. The model predicts that water loss scales to gas exchange with an exponent of 1 and that the amount of water lost per unit of gas exchanged depends on several factors: the surface temperature of the respiratory system near the outside of the organism, the gas consumed (oxygen or carbon dioxide), the steepness of the gradients for gas and vapor, and the transport mode (convective or diffusive). Model predictions were largely confirmed by data on 202 species in five taxa--insects, birds, bird eggs, mammals, and plants--spanning nine orders of magnitude in rate of gas exchange. Discrepancies between model predictions and data seemed to arise from biologically interesting violations of model assumptions, which emphasizes how poorly we understand gas exchange in some taxa. The universal model provides a unified conceptual framework for analyzing exchange-associated water losses across taxa with radically different metabolic and exchange systems.

Photoelectron spectrometer for attosecond spectroscopy of liquids and gases

Energy Technology Data Exchange (ETDEWEB)

Jordan, I.; Huppert, M.; Wörner, H. J., E-mail: hwoerner@ethz.ch [Laboratory of Physical Chemistry, ETH Zurich, Vladimir-Prelog-Weg 2, 8093 Zurich (Switzerland); Brown, M. A. [Laboratory for Surface Science and Technology, Department of Materials, ETH Zurich, Vladimir-Prelog-Weg 5, 8093 Zurich (Switzerland); Bokhoven, J. A. van [Institute for Chemical and Bioengineering, ETH Zurich, Vladimir-Prelog-Weg 1, 8093 Zurich (Switzerland); Laboratory for Catalysis and Sustainable Chemistry, Paul Scherrer Institute, 5232 Villigen (Switzerland)

2015-12-15

A new apparatus for attosecond time-resolved photoelectron spectroscopy of liquids and gases is described. It combines a liquid microjet source with a magnetic-bottle photoelectron spectrometer and an actively stabilized attosecond beamline. The photoelectron spectrometer permits venting and pumping of the interaction chamber without affecting the low pressure in the flight tube. This pressure separation has been realized through a sliding skimmer plate, which effectively seals the flight tube in its closed position and functions as a differential pumping stage in its open position. A high-harmonic photon spectrometer, attached to the photoelectron spectrometer, exit port is used to acquire photon spectra for calibration purposes. Attosecond pulse trains have been used to record photoelectron spectra of noble gases, water in the gas and liquid states as well as solvated species. RABBIT scans demonstrate the attosecond resolution of this setup.

Photoelectron spectrometer for attosecond spectroscopy of liquids and gases

International Nuclear Information System (INIS)

Jordan, I.; Huppert, M.; Wörner, H. J.; Brown, M. A.; Bokhoven, J. A. van

2015-01-01

A new apparatus for attosecond time-resolved photoelectron spectroscopy of liquids and gases is described. It combines a liquid microjet source with a magnetic-bottle photoelectron spectrometer and an actively stabilized attosecond beamline. The photoelectron spectrometer permits venting and pumping of the interaction chamber without affecting the low pressure in the flight tube. This pressure separation has been realized through a sliding skimmer plate, which effectively seals the flight tube in its closed position and functions as a differential pumping stage in its open position. A high-harmonic photon spectrometer, attached to the photoelectron spectrometer, exit port is used to acquire photon spectra for calibration purposes. Attosecond pulse trains have been used to record photoelectron spectra of noble gases, water in the gas and liquid states as well as solvated species. RABBIT scans demonstrate the attosecond resolution of this setup

Photoelectron spectrometer for attosecond spectroscopy of liquids and gases

Science.gov (United States)

Jordan, I.; Huppert, M.; Brown, M. A.; van Bokhoven, J. A.; Wörner, H. J.

2015-12-01

A new apparatus for attosecond time-resolved photoelectron spectroscopy of liquids and gases is described. It combines a liquid microjet source with a magnetic-bottle photoelectron spectrometer and an actively stabilized attosecond beamline. The photoelectron spectrometer permits venting and pumping of the interaction chamber without affecting the low pressure in the flight tube. This pressure separation has been realized through a sliding skimmer plate, which effectively seals the flight tube in its closed position and functions as a differential pumping stage in its open position. A high-harmonic photon spectrometer, attached to the photoelectron spectrometer, exit port is used to acquire photon spectra for calibration purposes. Attosecond pulse trains have been used to record photoelectron spectra of noble gases, water in the gas and liquid states as well as solvated species. RABBIT scans demonstrate the attosecond resolution of this setup.

Research of aerial imaging spectrometer data acquisition technology based on USB 3.0

Science.gov (United States)

Huang, Junze; Wang, Yueming; He, Daogang; Yu, Yanan

2016-11-01

With the emergence of UAV (unmanned aerial vehicle) platform for aerial imaging spectrometer, research of aerial imaging spectrometer DAS(data acquisition system) faces new challenges. Due to the limitation of platform and other factors, the aerial imaging spectrometer DAS requires small-light, low-cost and universal. Traditional aerial imaging spectrometer DAS system is expensive, bulky, non-universal and unsupported plug-and-play based on PCIe. So that has been unable to meet promotion and application of the aerial imaging spectrometer. In order to solve these problems, the new data acquisition scheme bases on USB3.0 interface.USB3.0 can provide guarantee of small-light, low-cost and universal relying on the forward-looking technology advantage. USB3.0 transmission theory is up to 5Gbps.And the GPIF programming interface achieves 3.2Gbps of the effective theoretical data bandwidth.USB3.0 can fully meet the needs of the aerial imaging spectrometer data transmission rate. The scheme uses the slave FIFO asynchronous data transmission mode between FPGA and USB3014 interface chip. Firstly system collects spectral data from TLK2711 of high-speed serial interface chip. Then FPGA receives data in DDR2 cache after ping-pong data processing. Finally USB3014 interface chip transmits data via automatic-dma approach and uploads to PC by USB3.0 cable. During the manufacture of aerial imaging spectrometer, the DAS can achieve image acquisition, transmission, storage and display. All functions can provide the necessary test detection for aerial imaging spectrometer. The test shows that system performs stable and no data lose. Average transmission speed and storage speed of writing SSD can stabilize at 1.28Gbps. Consequently ,this data acquisition system can meet application requirements for aerial imaging spectrometer.

The use of direct geometry spectrometers in molecular spectroscopy

International Nuclear Information System (INIS)

Parker, Stewart F; Ramirez-Cuesta, Anibal J; Albers, Peter W; Lennon, David

2014-01-01

The advantages and disadvantages of the use of direct geometry spectrometers for molecular spectroscopy and catalysis studies are described. We show that both direct and indirect geometry INS spectrometers are important tools for the study of industrially relevant areas such as catalysis, proton conductors and gas separation. We propose a novel hybrid instrument, Cerberus, that would offer high sensitivity and high-to-reasonable resolution across the entire 'mid-infrared' spectral range that would effectively advance research in these areas

Mass-spectrometer of knock-on nuclei for reactor 'Pik'

International Nuclear Information System (INIS)

Begzhanov, P.B.; Nazarov, A.G.; Petrov, G.A.; Pikul', V.P.

1999-01-01

For reactor 'Pik' (that is being built in St. Petersburg Institute of Nuclear Physics) there was designed a universal two shoulder mass-spectrometer for non-decelerated fission products (FP) of nuclei. The spectrometer helps to obtain different values of linear magnification, dispersion, aberration coefficients and transmission without making structural changes in the device. To separate FP for one shoulder of spectrometer we chose ion-optical scheme (IOS) consisting of three electrostatic analyzers and three-sectional magnet 'JOSEF' that had high dispersion by masses at small deflection radius. IOS calculations of mass-spectrometer were performed with the help of program TRANSVOL (transfer of phase volume) designed basing on TRIO program. The program allows calculating of complete IOS transmission with taking into account elements aperture and beam officering

Universal structure of a strongly interacting Fermi gas

Energy Technology Data Exchange (ETDEWEB)

Kuhnle, Eva; Dyke, Paul; Hoinka, Sascha; Mark, Michael; Hu Hui; Liu Xiaji; Drummond, Peter; Hannaford, Peter; Vale, Chris, E-mail: cvale@swin.edu.au [ARC Centre of Excellence for Quantum Atom Optics, Swinburne University of Technology, Hawthorn 3122 (Australia)

2011-01-10

This paper presents studies of the universal properties of strongly interacting Fermi gases using Bragg spectroscopy. We focus on pair-correlations, their relationship to the contact C introduced by Tan, and their dependence on both the momentum and temperature. We show that short-range pair correlations obey a universal law, first derived by Tan through measurements of the static structure factor, which displays a universal scaling with the ratio of the contact to the momentum C/q. Bragg spectroscopy of ultracold {sup 6}Li atoms is employed to measure the structure factor for a wide range of momenta and interaction strengths, providing broad confirmation of this universal law. We show that calibrating our Bragg spectra using the f-sum rule leads to a dramatic improvement in the accuracy of the structure factor measurement. We also measure the temperature dependence of the contact in a unitary gas and compare our results to calculations based on a virial expansion.

Some conceptual designs for a LASSY spectrometer magnet

International Nuclear Information System (INIS)

Green, M.A.

1995-09-01

The LASSY spectrometer is a gas filled spectrometer (hydrogen or helium at a pressure of about 1 torr). The design bending power for the primary bending magnet for the spectrometer will have an induction bend radius product of 2.5 tesla-meters. In order to increase the acceptance of the spectrometer, the bending magnet system must be located close to the target where the desired nuclei are created. The spectrometer magnet system must consist of both bending and focusing elements so that the wide acceptance of particles can be brought to a focus at the analysis point that is down stream from the last magnet element. In order improve the spectrometer resolution and to catch the shortest lived nuclei, the length of the magnet system must be as short as possible. The length for the LASSY spectrometer magnet system from the target to the analysis point has been set at 2.5 meters or less. To improve the resolution of the spectrometer, the bending angle for bending magnet system must be increased to close to 180 degrees. In order to achieve a large bending angle and a short magnet system length, the bending induction must be above 3 tesla and the focusing elements must be combined with the bending elements. As a result, a LASSY spectrometer will have bending magnet with a bending angle from 140 to 170 degrees. This magnet win be combined with one or more focusing magnets (a straight dipole in some places and a combined function dipole in other places). The result is a single superconducting bending magnet with one or more quadrupoles incorporated within the large angle bending magnet

A quadrupole mass spectrometer system for nuclear safeguards applications

International Nuclear Information System (INIS)

Evans, P.J.

1987-12-01

An on-line enrichment monitor for nuclear safeguards-related surveillance of a pilot-scale gas centrifuge plant is described. This monitor utilises a quadrupole mass spectrometer to measure the isotopic composition of UF 6 in the feed and product gas streams. Details of the design and construction are given, and several difficulties are identified and discussed. Finally, the performance of this system is illustrated with typical results

FAST Mapping of Diffuse HI Gas in the Local Universe

Science.gov (United States)

Zhu, M.; Pisano, D. J.; Ai, M.; Jiao, Q.

2016-02-01

We propose to use the Five hundred meter Aperture Spherical radio Telescope (FAST) to map the diffuse intergalactic HI gas in the local universe at column densities of NHI=1018 cm-2 and below. The major science goal is to study gas accretion during galaxy evolution, and trace cosmic web features in the local universe. We disuss the technical feasibilty of such a deep survey, and have conducted test observations with the Arecibo 305 m telescope. Our preliminary results shows that, with about a few thousand hours of observing time, FAST will be able to map several hundred square degree regions at 1 σ of NHI=2×1017 cm-2 level out to a distance of 5-10 Mpc, and with a volume 1000 larger than that of the Local Group.

Method for selective detection of explosives in mass spectrometer or ion mobility spectrometer at parts-per-quadrillion level

Science.gov (United States)

Ewing, Robert G.; Atkinson, David A.; Clowers, Brian H.

2015-09-01

A method for selective detection of volatile and non-volatile explosives in a mass spectrometer or ion mobility spectrometer at a parts-per-quadrillion level without preconcentration is disclosed. The method comprises the steps of ionizing a carrier gas with an ionization source to form reactant ions or reactant adduct ions comprising nitrate ions (NO.sub.3.sup.-); selectively reacting the reactant ions or reactant adduct ions with at least one volatile or non-volatile explosive analyte at a carrier gas pressure of at least about 100 Ton in a reaction region disposed between the ionization source and an ion detector, the reaction region having a length which provides a residence time (tr) for reactant ions therein of at least about 0.10 seconds, wherein the selective reaction yields product ions comprising reactant ions or reactant adduct ions that are selectively bound to the at least one explosive analyte when present therein; and detecting product ions with the ion detector to determine presence or absence of the at least one explosive analyte.

MASS-SAT: Matter-antimatter space spectrometer on satellite

CERN Document Server

Basini, G; Massimo Brancaccio, F; Ricci, M; Bocciolini, M; Spillantini, P; Wang, Y F; Bongiorno, F; de Pascale, M P; Morselli, A; Picozza, P; de Marzo, C; Erriquez, O; Barbiellini, G; Vacchi, A; Galeotti, P; Ballocchi, G; Simon, M; Carlson, P; Goret, P; Golden, R L

The MASS-SAT Experiment (Matter-Antimatter Space Spectrometer on SATellite) presented here is conceived to search for an experimental answer to many open problems related to both Astrophysics and Physics, through the detection of positrons, antiprotons, nuclei and, overall, antinuclei if they exist. Among these problems there are the hypothesized presence of antigalaxies in the Universe (the matter-antimatter symmetry problem), the existence of black holes as possible antiproton sources (the Hawking effect), the existence of photinos as antiproton sources (related to the dark-matter problem), the understanding of the mechanism of cosmic-ray acceleration in the interstellar medium, the determination of the relative abundancies of isotopes in cosmic rays and many others. The choice of an orbit expecially appropriate for that (geostationary or polar orbit) as well as the choice of an apparatus composed only of solid-state detectors and permanent magnets (no gas and no liquid helium on board, avoiding complexity ...

Large solid-angle spectrometers for studies of double-differential charged-particle and neutron emission cross sections

International Nuclear Information System (INIS)

Baba, M.; Matsuyama, S.; Sanami, T.; Soda, D.; Matsuyama, I.; Ohkubo, T.; Iwasaki, S.; Hirakawa, N.

1995-01-01

The large solid-angle spectrometer developed for studies of double-differential cross sections of (n, charged particle) and (n, xn') reactions using a gas-filled gridded-ionization chamber and an 80-cm long liquid scintillator is described. The charged particle spectrometer is a twin gas-filled gridded-ionization chamber with solid angle close to 4 π designed to achieve high stopping power and background suppression. The neutron spectrometer is a long NE213 liquid scintillation detector having position sensitivity. It is used as a large single spectrometer or a position sensitive detector covering wide scattering angle. The facility design, performance and examples of application are discussed. The conclusion is made that the facility provides a useful mean for studies in particular for reactions with small cross sections and/or for neutron sources with low intensity. 15 refs., 15 figs

α-rays induced background in ultra low level counting with Ge spectrometers

International Nuclear Information System (INIS)

Hubert, P.; Dassie, D.; Larrieu, P.; Leccia, F.; Mennrath, P.; Chevallier, J.; Chevallier, A.; Morales, A.; Nunez-Lagoz, R.; Morales, J.; Villar, J.A.

1986-01-01

Background spectra of several spectrometers have been recorded in a deep underground laboratory located in the Frejus tunnel. The results show that an α ray induced background from the 210 Pb decay is observed. A possible explanation could be related to the adsorption of the Rn gas on the surfaces of the Ge crystal and/or other parts during the assembly of the spectrometer. (orig.)

Portable, remotely operated, computer-controlled, quadrupole mass spectrometer for field use

International Nuclear Information System (INIS)

Friesen, R.D.; Newton, J.C.; Smith, C.F.

1982-04-01

A portable, remote-controlled mass spectrometer was required at the Nevada Test Site to analyze prompt post-event gas from the nuclear cavity in support of the underground testing program. A Balzers QMG-511 quadrupole was chosen for its ability to be interfaced to a DEC LSI-11 computer and to withstand the ground movement caused by this field environment. The inlet system valves, the pumps, the pressure and temperature transducers, and the quadrupole mass spectrometer are controlled by a read-only-memory-based DEC LSI-11/2 with a high-speed microwave link to the control point which is typically 30 miles away. The computer at the control point is a DEC LSI-11/23 running the RSX-11 operating system. The instrument was automated as much as possible because the system is run by inexperienced operators at times. The mass spectrometer has been used on an initial field event with excellent performance. The gas analysis system is described, including automation by a novel computer control method which reduces operator errors and allows dynamic access to the system parameters

MEMS tunable grating micro-spectrometer

Science.gov (United States)

Tormen, Maurizio; Lockhart, R.; Niedermann, P.; Overstolz, T.; Hoogerwerf, A.; Mayor, J.-M.; Pierer, J.; Bosshard, C.; Ischer, R.; Voirin, G.; Stanley, R. P.

2017-11-01

The interest in MEMS based Micro-Spectrometers is increasing due to their potential in terms of flexibility as well as cost, low mass, small volume and power savings. This interest, especially in the Near-Infrared and Mid- Infrared, ranges from planetary exploration missions to astronomy, e.g. the search for extra solar planets, as well as to many other terrestrial fields of application such as, industrial quality and surface control, chemical analysis of soil and water, detection of chemical pollutants, exhausted gas analysis, food quality control, process control in pharmaceuticals, to name a few. A compact MEMS-based Spectrometer for Near- Infrared and Mid-InfraRed operation have been conceived, designed and demonstrated. The design based on tunable MEMS blazed grating, developed in the past at CSEM [1], achieves state of the art results in terms of spectral resolution, operational wavelength range, light throughput, overall dimensions, and power consumption.

The University of Colorado OSO-8 spectrometer experiment. I - Introduction and optical design considerations

Science.gov (United States)

Bruner, E. C., Jr.

1977-01-01

The optical design of the high-resolution ultraviolet spectrometer prepared for the OSO-8 spacecraft is discussed. The instrument is a conventional 1 m Ebert-Fastie spectrometer fed by a Cassegrainian telescope. The instrument operates in the spectral range 1200-2000 A with spectral resolution of order 0.02 A. Spatial resolution is about 2.5 arcsec normal to the direction of the slit and is selectable from about 3 arcsec to 15 arcmin along the direction of the slit. Time resolution for the single spectrometer channel is selectable according to the needs of an individual observation and is limited to a maximum sampling rate of 40 ms per data point. The instrument is controlled by an internal general purpose computer.

Universal model for water costs of gas exchange by animals and plants

OpenAIRE

Woods, H. Arthur; Smith, Jennifer N.

2010-01-01

For terrestrial animals and plants, a fundamental cost of living is water vapor lost to the atmosphere during exchange of metabolic gases. Here, by bringing together previously developed models for specific taxa, we integrate properties common to all terrestrial gas exchangers into a universal model of water loss. The model predicts that water loss scales to gas exchange with an exponent of 1 and that the amount of water lost per unit of gas exchanged depends on several factors: the surface t...

Demonstration of an ethane spectrometer for methane source identification.

Science.gov (United States)

Yacovitch, Tara I; Herndon, Scott C; Roscioli, Joseph R; Floerchinger, Cody; McGovern, Ryan M; Agnese, Michael; Pétron, Gabrielle; Kofler, Jonathan; Sweeney, Colm; Karion, Anna; Conley, Stephen A; Kort, Eric A; Nähle, Lars; Fischer, Marc; Hildebrandt, Lars; Koeth, Johannes; McManus, J Barry; Nelson, David D; Zahniser, Mark S; Kolb, Charles E

2014-07-15

Methane is an important greenhouse gas and tropospheric ozone precursor. Simultaneous observation of ethane with methane can help identify specific methane source types. Aerodyne Ethane-Mini spectrometers, employing recently available mid-infrared distributed feedback tunable diode lasers (DFB-TDL), provide 1 s ethane measurements with sub-ppb precision. In this work, an Ethane-Mini spectrometer has been integrated into two mobile sampling platforms, a ground vehicle and a small airplane, and used to measure ethane/methane enhancement ratios downwind of methane sources. Methane emissions with precisely known sources are shown to have ethane/methane enhancement ratios that differ greatly depending on the source type. Large differences between biogenic and thermogenic sources are observed. Variation within thermogenic sources are detected and tabulated. Methane emitters are classified by their expected ethane content. Categories include the following: biogenic (6%), pipeline grade natural gas (30%). Regional scale observations in the Dallas/Fort Worth area of Texas show two distinct ethane/methane enhancement ratios bridged by a transitional region. These results demonstrate the usefulness of continuous and fast ethane measurements in experimental studies of methane emissions, particularly in the oil and natural gas sector.

40Ar/39Ar dating of Quaternary volcanic ashes by multi-collection noble gas mass spectrometry: protocols, precision and intercalibration

DEFF Research Database (Denmark)

Storey, Michael; Rivera, Tiffany; Flude, Stephanie

) higher mass resolution allows hydrocarbon interferences to be pseudo resolved for the different argon isotopes; and (iv) multi-collection, allowing more data to be gathered in a fixed time in comparison with single-collector peak-switching measurements. We evaluate (i) protocols for detector inter......The recent availability of commercial high-resolution, multi-collector, noble gas mass spectrometers equipped with ion-counting electron multipliers provides new opportunities for improved precision in 40Ar/39Ar dating. This is particularly true for single crystal dating of Quaternary aged samples...... where potassium-bearing phenocrysts may contain relatively small amounts of radiogenic 40Ar. In 2005, the Quaternary Dating Laboratory, Roskilde University, installed a Nu-Instruments multi-collector Noblesse noble gas mass spectrometer, which is configured with a Faraday detector and three ion...

The OVIRS Visible/IR Spectrometer on the OSIRIS-Rex Mission

Science.gov (United States)

Reuter, D. C.; Simon-Miller, A. A.

2012-01-01

The OSIRIS-REx (Origins Spectral Interpretation Resource Identification Security Regolith Explorer) Mission is a planetary science mission to study, and return a sample from, the carbonaceous asteroid 1999 RQ-36. The third mission selected under NASA's New Frontiers Program, it is scheduled to be launched in 2016. It is led by PI Dante Lauretta at the University of Arizona and managed by NASA's Goddard Space Flight Center. The spacecraft and the asteroid sampling mechanism, TAGSAM (Touch-And-Go Sample Acquisition Mechanism) will be provided by Lockheed Martin Space Systems. Instrumentation for studying the asteroid include: OCAMS (the OSIRIS-REx Camera Suite), OLA (the OSIRIS-REx Laser Altimeter, a scanning LIDAR), OTES (The OSIRIS-REx Thermal Emission Spectrometer, a 4-50 micron point spectrometer) and OVIRS (the OSIRIS-REx Visible and IR Spectrometer, a 0.4 to 4.3 micron point spectrometer). The payload also includes REXIS (the Regolith X-ray Imaging Spectrometer) a student provided experiment. This paper presents a description of the OVIRS instrument.

A Thomson-type mass and energy spectrometer for characterizing ion energy distributions in a coaxial plasma gun operating in a gas-puff mode

OpenAIRE

Rieker, G. B.; Poehlmann, F. R.; Cappelli, M. A.

2013-01-01

Measurements of ion energy distribution are performed in the accelerated plasma of a coaxial electromagnetic plasma gun operating in a gas-puff mode at relatively low discharge energy (900 J) and discharge potential (4 kV). The measurements are made using a Thomson-type mass and energy spectrometer with a gated microchannel plate and phosphor screen as the ion sensor. The parabolic ion trajectories are captured from the sensor screen with an intensified charge-coupled detector camera. The spe...

Universality and Quantum Criticality of the One-Dimensional Spinor Bose Gas

Science.gov (United States)

PâÅ£u, Ovidiu I.; Klümper, Andreas; Foerster, Angela

2018-06-01

We investigate the universal thermodynamics of the two-component one-dimensional Bose gas with contact interactions in the vicinity of the quantum critical point separating the vacuum and the ferromagnetic liquid regime. We find that the quantum critical region belongs to the universality class of the spin-degenerate impenetrable particle gas which, surprisingly, is very different from the single-component case and identify its boundaries with the peaks of the specific heat. In addition, we show that the compressibility Wilson ratio, which quantifies the relative strength of thermal and quantum fluctuations, serves as a good discriminator of the quantum regimes near the quantum critical point. Remarkably, in the Tonks-Girardeau regime, the universal contact develops a pronounced minimum, reflected in a counterintuitive narrowing of the momentum distribution as we increase the temperature. This momentum reconstruction, also present at low and intermediate momenta, signals the transition from the ferromagnetic to the spin-incoherent Luttinger liquid phase and can be detected in current experiments with ultracold atomic gases in optical lattices.

A compact high resolution ion mobility spectrometer for fast trace gas analysis.

Science.gov (United States)

Kirk, Ansgar T; Allers, Maria; Cochems, Philipp; Langejuergen, Jens; Zimmermann, Stefan

2013-09-21

Drift tube ion mobility spectrometers (IMS) are widely used for fast trace gas detection in air, but portable compact systems are typically very limited in their resolving power. Decreasing the initial ion packet width improves the resolution, but is generally associated with a reduced signal-to-noise-ratio (SNR) due to the lower number of ions injected into the drift region. In this paper, we present a refined theory of IMS operation which employs a combined approach for the analysis of the ion drift and the subsequent amplification to predict both the resolution and the SNR of the measured ion current peak. This theoretical analysis shows that the SNR is not a function of the initial ion packet width, meaning that compact drift tube IMS with both very high resolution and extremely low limits of detection can be designed. Based on these implications, an optimized combination of a compact drift tube with a length of just 10 cm and a transimpedance amplifier has been constructed with a resolution of 183 measured for the positive reactant ion peak (RIP(+)), which is sufficient to e.g. separate the RIP(+) from the protonated acetone monomer, even though their drift times only differ by a factor of 1.007. Furthermore, the limits of detection (LODs) for acetone are 180 pptv within 1 s of averaging time and 580 pptv within only 100 ms.

Extending The Useful Life Of Older Mass Spectrometers

International Nuclear Information System (INIS)

Johnson, S.; Cordaro, J.; Holland, M.; Jones, V.

2010-01-01

Thermal ionization and gas mass spectrometers are widely used across the Department of Energy (DOE) Complex and contractor laboratories. These instruments support critical missions, where high reliability and low measurement uncertainty are essential. A growing number of these mass spectrometers are significantly older than their original design life. The reality is that manufacturers have declared many of the instrument models obsolete, with direct replacement parts and service no longer available. Some of these obsolete models do not have a next generation, commercially available replacement. Today's budget conscious economy demands for the use of creative funds management. Therefore, the ability to refurbish (or upgrade) these valuable analytical tools and extending their useful life is a cost effective option. The Savannah River Site (SRS) has the proven expertise to breathe new life into older mass spectrometers, at a significant cost savings compared to the purchase and installation of new instruments. A twenty-seven year old Finnigan MAT-261(trademark) Thermal Ionization Mass Spectrometer (TIMS), located at the SRS F/H Area Production Support Laboratory, has been successfully refurbished. Engineers from the Savannah River National Laboratory (SRNL) fabricated and installed the new electronics. These engineers also provide continued instrument maintenance services. With electronic component drawings being DOE Property, other DOE Complex laboratories have the option to extend the life of their aged Mass Spectrometers.

A low-volume cavity ring-down spectrometer for sample-limited applications

Science.gov (United States)

Stowasser, C.; Farinas, A. D.; Ware, J.; Wistisen, D. W.; Rella, C.; Wahl, E.; Crosson, E.; Blunier, T.

2014-08-01

In atmospheric and environmental sciences, optical spectrometers are used for the measurements of greenhouse gas mole fractions and the isotopic composition of water vapor or greenhouse gases. The large sample cell volumes (tens of milliliters to several liters) in commercially available spectrometers constrain the usefulness of such instruments for applications that are limited in sample size and/or need to track fast variations in the sample stream. In an effort to make spectrometers more suitable for sample-limited applications, we developed a low-volume analyzer capable of measuring mole fractions of methane and carbon monoxide based on a commercial cavity ring-down spectrometer. The instrument has a small sample cell (9.6 ml) and can selectively be operated at a sample cell pressure of 140, 45, or 20 Torr (effective internal volume of 1.8, 0.57, and 0.25 ml). We present the new sample cell design and the flow path configuration, which are optimized for small sample sizes. To quantify the spectrometer's usefulness for sample-limited applications, we determine the renewal rate of sample molecules within the low-volume spectrometer. Furthermore, we show that the performance of the low-volume spectrometer matches the performance of the standard commercial analyzers by investigating linearity, precision, and instrumental drift.

Ultrasensitive Mid-Infrared In Situ Spectrometer for Planetary Atmospheric Analysis, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — The Small Business Innovative Research Phase I proposal seeks to develop a compact, robust in situ spectrometer capable of detecting multiple gas-phase species in...

From carbon to actinides: A new universal 1MV accelerator mass spectrometer at ANSTO

Science.gov (United States)

Wilcken, K. M.; Hotchkis, M.; Levchenko, V.; Fink, D.; Hauser, T.; Kitchen, R.

2015-10-01

A new 1 MV NEC pelletron AMS system at ANSTO is presented. The spectrometer comprises large radius magnets for actinide measurements. A novel feature of the system is fast switching between isotopes both at low and high energy sections allowing measurements of up to 8 isotopes within a single sequence. Technical details and layout of the spectrometer is presented. Performance data for 14C, 10Be, 26Al and actinides demonstrate the system is ready for routine AMS measurements.

Reconstructing an interacting holographic polytropic gas model in a non-flat FRW universe

International Nuclear Information System (INIS)

Karami, K; Abdolmaleki, A

2010-01-01

We study the correspondence between the interacting holographic dark energy and the polytropic gas model of dark energy in a non-flat FRW universe. This correspondence allows one to reconstruct the potential and the dynamics for the scalar field of the polytropic model, which describe accelerated expansion of the universe.

Reconstructing an interacting holographic polytropic gas model in a non-flat FRW universe

Energy Technology Data Exchange (ETDEWEB)

Karami, K; Abdolmaleki, A, E-mail: KKarami@uok.ac.i [Department of Physics, University of Kurdistan, Pasdaran Street, Sanandaj (Iran, Islamic Republic of)

2010-05-01

We study the correspondence between the interacting holographic dark energy and the polytropic gas model of dark energy in a non-flat FRW universe. This correspondence allows one to reconstruct the potential and the dynamics for the scalar field of the polytropic model, which describe accelerated expansion of the universe.

From carbon to actinides: A new universal 1MV accelerator mass spectrometer at ANSTO

Energy Technology Data Exchange (ETDEWEB)

Wilcken, K.M., E-mail: klaus.wilcken@ansto.gov.au [Australian Nuclear Science & Technology Organisation, Sydney, New South Wales (Australia); Hotchkis, M.; Levchenko, V.; Fink, D. [Australian Nuclear Science & Technology Organisation, Sydney, New South Wales (Australia); Hauser, T.; Kitchen, R. [National Electrostatics Corporation, 7540 Graber Road, Middleton, WI 53562-0310 (United States)

2015-10-15

A new 1 MV NEC pelletron AMS system at ANSTO is presented. The spectrometer comprises large radius magnets for actinide measurements. A novel feature of the system is fast switching between isotopes both at low and high energy sections allowing measurements of up to 8 isotopes within a single sequence. Technical details and layout of the spectrometer is presented. Performance data for {sup 14}C, {sup 10}Be, {sup 26}Al and actinides demonstrate the system is ready for routine AMS measurements.

Spherical grating spectrometers

Science.gov (United States)

O'Donoghue, Darragh; Clemens, J. Christopher

2014-07-01

We describe designs for spectrometers employing convex dispersers. The Offner spectrometer was the first such instrument; it has almost exclusively been employed on satellite platforms, and has had little impact on ground-based instruments. We have learned how to fabricate curved Volume Phase Holographic (VPH) gratings and, in contrast to the planar gratings of traditional spectrometers, describe how such devices can be used in optical/infrared spectrometers designed specifically for curved diffraction gratings. Volume Phase Holographic gratings are highly efficient compared to conventional surface relief gratings; they have become the disperser of choice in optical / NIR spectrometers. The advantage of spectrometers with curved VPH dispersers is the very small number of optical elements used (the simplest comprising a grating and a spherical mirror), as well as illumination of mirrors off axis, resulting in greater efficiency and reduction in size. We describe a "Half Offner" spectrometer, an even simpler version of the Offner spectrometer. We present an entirely novel design, the Spherical Transmission Grating Spectrometer (STGS), and discuss exemplary applications, including a design for a double-beam spectrometer without any requirement for a dichroic. This paradigm change in spectrometer design offers an alternative to all-refractive astronomical spectrometer designs, using expensive, fragile lens elements fabricated from CaF2 or even more exotic materials. The unobscured mirror layout avoids a major drawback of the previous generation of catadioptric spectrometer designs. We describe laboratory measurements of the efficiency and image quality of a curved VPH grating in a STGS design, demonstrating, simultaneously, efficiency comparable to planar VPH gratings along with good image quality. The stage is now set for construction of a prototype instrument with impressive performance.

Micro-optical-mechanical system photoacoustic spectrometer

Science.gov (United States)

Kotovsky, Jack; Benett, William J.; Tooker, Angela C.; Alameda, Jennifer B.

2013-01-01

All-optical photoacoustic spectrometer sensing systems (PASS system) and methods include all the hardware needed to analyze the presence of a large variety of materials (solid, liquid and gas). Some of the all-optical PASS systems require only two optical-fibers to communicate with the opto-electronic power and readout systems that exist outside of the material environment. Methods for improving the signal-to-noise are provided and enable mirco-scale systems and methods for operating such systems.

Cryogenic system for a superconducting spectrometer

International Nuclear Information System (INIS)

Porter, J.

1983-03-01

The Heavy Ion Spectrometer System (HISS) relies upon superconducting coils of cryostable, pool boiling design to provide a maximum particle bending field of 3 tesla. This paper describes the cryogenic facility including helium refrigeration, gas management, liquid nitrogen system, and the overall control strategy. The system normally operates with a 4 K heat load of 150 watts; the LN 2 circuits absorb an additional 4000 watts. 80K intercept control is by an LSI 11 computer. Total available refrigeration at 4K is 400 watts using reciprocating expanders at the 20K and 4K level. The minicomputer has the capability of optimizing overall utility input cost by varying operating points. A hybrid of pneumatic, analog, and digital control is successful in providing full time unattended operation. The 7m diameter magnet/cryostat assembly is rotatable through 180 degrees to provide a variety of spectrometer orientations

Universal Behavior of Pair Correlations in a Strongly Interacting Fermi Gas

International Nuclear Information System (INIS)

Kuhnle, E. D.; Hu, H.; Liu, X.-J.; Dyke, P.; Mark, M.; Drummond, P. D.; Hannaford, P.; Vale, C. J.

2010-01-01

We show that short-range pair correlations in a strongly interacting Fermi gas follow a simple universal law described by Tan's relations. This is achieved through measurements of the static structure factor which displays a universal scaling proportional to the ratio of Tan's contact to the momentum C/q. Bragg spectroscopy of ultracold 6 Li atoms from a periodic optical potential is used to measure the structure factor for a wide range of momenta and interaction strengths, providing broad confirmation of this universal law. We calibrate our Bragg spectra using the f-sum rule, which is found to improve the accuracy of the structure factor measurement.

Mixed gamma emitting gas standard and method

International Nuclear Information System (INIS)

McFarland, R.C.; McFarland, P.A.

1986-01-01

The invention in one aspect pertains to a method of calibrating gamma spectroscopy systems for gas counting in a variety of counting containers comprising withdrawing a precision volume of a mixed gamma-emitting gas standard from a precision volume vial and delivering the withdrawn precision volume of the gas standard to the interior of a gas counting container. Another aspect of the invention pertains to a mixed gamma-emitting gas standard, comprising a precision spherical vial of predetermined volume, multiple mixed emitting gas components enclosed within the vial, and means for withdrawing from the vial a predetermined amount of the components wherein the gas standard is used to calibrate a gamma spectrometer system for gas counting over a wide energy range without the use of additional standards. A third aspect comprehends a gamma spectrometer calibration system for gas counting, comprising a precision volume spherical glass vial for receiving mixed multiisotope gas components, and two tubular arms extending from the vial. A ground glass stopcock is positioned on each arm, and the outer end of one arm is provided with a rubber septum port

Interfacing an aspiration ion mobility spectrometer to a triple quadrupole mass spectrometer

International Nuclear Information System (INIS)

Adamov, Alexey; Viidanoja, Jyrki; Kaerpaenoja, Esko; Paakkanen, Heikki; Ketola, Raimo A.; Kostiainen, Risto; Sysoev, Alexey; Kotiaho, Tapio

2007-01-01

This article presents the combination of an aspiration-type ion mobility spectrometer with a mass spectrometer. The interface between the aspiration ion mobility spectrometer and the mass spectrometer was designed to allow for quick mounting of the aspiration ion mobility spectrometer onto a Sciex API-300 triple quadrupole mass spectrometer. The developed instrumentation is used for gathering fundamental information on aspiration ion mobility spectrometry. Performance of the instrument is demonstrated using 2,6-di-tert-butyl pyridine and dimethyl methylphosphonate

Photoacoustic trace gas sensing : application to fruit and insects

NARCIS (Netherlands)

Persijn, Stefan Timotheüs

2001-01-01

A novel photoacoustic spectrometer has been applied to study trace gas emissions by fruit and insects. The spectrometer is based on a newly designed CO laser that can operate on 400 laser lines between 5.1-8.0 and 2.8-4.1 micrometer (delta v=1 and 2 mode, respectively). The spectrometer is equipped

Construction and simulation of a multi-reflection time-of-flight mass spectrometer at the University of Notre Dame

Energy Technology Data Exchange (ETDEWEB)

Schultz, B.E., E-mail: bschult4@nd.edu; Kelly, J.M.; Nicoloff, C.; Long, J.; Ryan, S.; Brodeur, M.

2016-06-01

One of the most significant problems in the production of rare isotopes is the simultaneous production of contaminants, often time isobaric. Thus, a high-resolution beam purification method is required which needs to be compatible with both the low yield and short half-life of the desired radionuclide. A multi-reflection time-of-flight mass spectrometer meets all these criteria, in addition to boasting a smaller footprint relative to traditional separator dipole magnets. Such a device is currently under construction at the University of Notre Dame and is intended to be coupled to the IG-ISOL source of the planned cyclotron facility. The motivation and conceptual design are presented, as well as the status of simulations to determine the feasibility of using a Bradbury–Nielsen gate for bunching ion beams during initial system testing.

GIOVE, a shallow laboratory Ge-spectrometer with 100 μBq/kg sensitivity

Energy Technology Data Exchange (ETDEWEB)

Heusser, G.; Weber, M.; Denz, T.; Hakenmueller, J.; Hofacker, R.; Lackner, R.; Lindner, M.; Maneschg, W.; Reisfelder, M.; Simgen, H.; Schreiner, J.; Stolzenburg, D.; Strecker, H.; Westermann, J. [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany)

2013-08-08

A new germanium gamma spectrometer called GIOVE (Germanium spectrometer with Inner and Outer Veto) has been set up at the underground/shallow laboratory (15 m w.e.) of MPI-K. Its double plastic scintillator veto system and neutron moderation interlayer lower the background by more than one order of magnitude compared to the other existing spectrometer at this facility. The integral (40-2700 keV) background rate of about 290 counts (day kg){sup −1} is just a factor 4 to 8 above that of the GeMPI spectrometers operated at LNGS (3800 m w.e.) and thus proves that even under shallow overburden sub mBq/kg sensitivities are achievable. Extended material screening and neutron attenuation studies preceded the final design of the spectrometer. The technical realization of the spectrometer is described in detail with special emphasis on the inner veto system. For its optimisation a simulation model was developed for light collection on small low activity PMT’s under various geometrical conditions. Radon suppression is accomplished by employing a gas tight sample container and a nitrogen flushed glove-box system with an airlock. The active volume of the crystal was modelled by absorption scanning measurements and Monte Carlo simulations. The complete shield is implemented in a Geant4 based simulation framework.

Commissioning of the vacuum system of the KATRIN Main Spectrometer

Czech Academy of Sciences Publication Activity Database

Arenz, M.; Dragoun, Otokar; Kovalík, Alojz; Lebeda, Ondřej; Ryšavý, Miloš; Sentkerestiová, Jana; Slezák, Martin; Špalek, Antonín; Vénos, Drahoslav; Zbořil, Miroslav

2016-01-01

Roč. 11, APR (2016), P04011 ISSN 1748-0221 R&D Projects: GA ČR(CZ) GAP203/12/1896; GA MŠk LG14004 Institutional support: RVO:61389005 Keywords : gas systems and purification * neutriono detectors * spectrometers Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 1.220, year: 2016

Mapping methane emissions using the airborne imaging spectrometer AVIRIS-NG

Science.gov (United States)

Thorpe, A. K.; Frankenberg, C.; Thompson, D. R.; Duren, R. M.; Bue, B. D.; Green, R. O.

2017-12-01

The next generation Airborne Visible/Infrared Imaging Spectrometer (AVIRIS-NG) has been used to survey large regions and map methane plumes with unambiguous identification of emission source locations. This capability is aided by real time detection and geolocation of gas plumes, permitting adaptive surveys and communication to ground teams for rapid follow up. We present results from AVIRIS-NG flight campaigns in Colorado, New Mexico, and California. Hundreds of plumes were observed, reflecting emissions from the energy sector that include hydraulic fracturing, gas processing plants, tanks, pumpjacks, and pipeline leaks. In some cases, plumes observed by AVIRIS-NG resulted in mitigation. Additional examples will be shown for methane from dairy lagoons, landfills, natural emissions, as well as carbon dioxide from power plants and refineries. We describe the unique capabilities of airborne imaging spectrometers to augment other measurement techniques by efficiently surveying key regions for methane point sources and supporting timely assessment and mitigation. We summarize the outlook for near- and longer-term monitoring capabilities including future satellite systems. Figure caption. AVIRIS-NG true color image subset with superimposed methane plume showing retrieved gas concentrations. Plume extends 200 m downwind of the southern edge of the well pad. Google Earth imagery with finer spatial resolution is also included (red box), indicating that tanks in the inset scene as the source of emissions. Five wells are located at the center of this well pad and all use horizontal drilling to produce mostly natural gas.

LAVA Subsystem Integration and Testing for the RESOLVE Payload of the Resource Prospector Mission: Mass Spectrometers and Gas Chromatography

Science.gov (United States)

Coan, Mary R.; Stewart, Elaine M.

2015-01-01

The Regolith and Environment Science & Oxygen and Lunar Volatile Extraction (RESOLVE) payload is part of Resource Prospector (RP) along with a rover and a lander that are expected to launch in 2020. RP will identify volatile elements that may be combined and collected to be used for fuel, air, and water in order to enable deeper space exploration. The Resource Prospector mission is a key part of In-Situ Resource Utilization (ISRU). The demand for this method of utilizing resources at the site of exploration is increasing due to the cost of resupply missions and deep space exploration goals. The RESOLVE payload includes the Lunar Advanced Volatile Analysis (LAVA) subsystem. The main instrument used to identify the volatiles evolved from the lunar regolith is the Gas Chromatograph-Mass Spectrometer (GC-MS). LAVA analyzes the volatiles emitted from the Oxygen and Volatile Extraction Node (OVEN) Subsystem. The objective of OVEN is to obtain, weigh, heat and transfer evolved gases to LAVA through the connection between the two subsystems called the LOVEN line. This paper highlights the work completed during a ten week internship that involved the integration, testing, data analysis, and procedure documentation of two candidate mass spectrometers for the LAVA subsystem in order to aid in determining which model to use for flight. Additionally, the examination of data from the integrated Resource Prospector '15 (RP' 15) field test will be presented in order to characterize the amount of water detected from water doped regolith samples.

Onsite well screening with a transportable gas chromatography/mass spectrometer system

International Nuclear Information System (INIS)

Rossabi, J.; Eckenrode, B.A.; Owens, B.

1992-01-01

The number of hazardous waste site operations continue to multiply. The requirements for efficient chemical assessment and monitoring of these sites become more stringent daily. As more samples are required, the time required for cleanup operations also increases and may make analytical costs prohibitive. Thus improvements in operation efficiency and reduction of cost in evaluating specific sites to minimize or eliminate their toxic effects on the surrounding environment are critical. For many years a formal policy did not exist for the disposal of waste solvents and other chemicals, thus many of these compounds were disposed of ensite. So long as these materials were contained onsite they were not considered to pose a threat to the surrounding environment. We have since determined that many of these compounds found their way into the groundwater. Contaminants such as trichloroethylene and perchloroethylene, which were heavily used for cleaning and degreasing purposes, must be monitored. Groundwater wells can be used to define the location and extent of the migration of any contaminant plume and aid in the determination of required cleanup. The major problem is that monitoring of hundreds of wells may be necessary, requiring several hundred samples on a quarterly basis to characterize the degree and extent of any contamination. Onsite analysis of monitoring wells for this characterization of waste operations could provide time savings and significant cost reduction. Field analyses can provide the required analytical results quickly and at a reduced cost without compromising either sample integrity or data quality. By using onsite analytical instrumentation, such as a field-transportable gas chromatograph/mass spectrometer (GC/MS), screening analyses can be performed to eliminate retturning to the laboratory with meaningless samples. Onsite GC/MS will provide qualitative or semi-quantitative information that can significantly simplify subsequent laboratory analyses

Galaxies and gas in a cold dark matter universe

Science.gov (United States)

Katz, Neal; Hernquist, Lars; Weinberg, David H.

1992-01-01

We use a combined gravity/hydrodynamics code to simulate the formation of structure in a random 22 Mpc cube of a cold dark matter universe. Adiabatic compression and shocks heat much of the gas to temperatures of 10 exp 6 - 10 exp 7 K, but a fraction of the gas cools radiatively to about 10 exp 4 K and condenses into discrete, highly overdense lumps. We identify these lumps with galaxies. The high-mass end of their baryonic mass function fits the form of the observed galaxy luminosity function. They retain independent identities after their dark halos merge, so gravitational clustering produces groups of galaxies embedded in relatively smooth envelopes of hot gas and dark matter. The galaxy correlation function is approximately an r exp -2.1 power law from separations of 35 kpc to 7 Mpc. Galaxy fluctuations are biased relative to dark matter fluctuations by a factor b about 1.5. We find no significant 'velocity bias' between galaxies and dark matter particles. However, virial analysis of the simulation's richest group leads to an estimated Omega of about 0.3, even though the simulation adopts Omega = 1.

Monolithic spectrometer

Energy Technology Data Exchange (ETDEWEB)

Rajic, Slobodan (Knoxville, TN); Egert, Charles M. (Oak Ridge, TN); Kahl, William K. (Knoxville, TN); Snyder, Jr., William B. (Knoxville, TN); Evans, III, Boyd M. (Oak Ridge, TN); Marlar, Troy A. (Knoxville, TN); Cunningham, Joseph P. (Oak Ridge, TN)

1998-01-01

A monolithic spectrometer is disclosed for use in spectroscopy. The spectrometer is a single body of translucent material with positioned surfaces for the transmission, reflection and spectral analysis of light rays.

Advances in miniature spectrometer and sensor development

Science.gov (United States)

Malinen, Jouko; Rissanen, Anna; Saari, Heikki; Karioja, Pentti; Karppinen, Mikko; Aalto, Timo; Tukkiniemi, Kari

2014-05-01

Miniaturization and cost reduction of spectrometer and sensor technologies has great potential to open up new applications areas and business opportunities for analytical technology in hand held, mobile and on-line applications. Advances in microfabrication have resulted in high-performance MEMS and MOEMS devices for spectrometer applications. Many other enabling technologies are useful for miniature analytical solutions, such as silicon photonics, nanoimprint lithography (NIL), system-on-chip, system-on-package techniques for integration of electronics and photonics, 3D printing, powerful embedded computing platforms, networked solutions as well as advances in chemometrics modeling. This paper will summarize recent work on spectrometer and sensor miniaturization at VTT Technical Research Centre of Finland. Fabry-Perot interferometer (FPI) tunable filter technology has been developed in two technical versions: Piezoactuated FPIs have been applied in miniature hyperspectral imaging needs in light weight UAV and nanosatellite applications, chemical imaging as well as medical applications. Microfabricated MOEMS FPIs have been developed as cost-effective sensor platforms for visible, NIR and IR applications. Further examples of sensor miniaturization will be discussed, including system-on-package sensor head for mid-IR gas analyzer, roll-to-roll printed Surface Enhanced Raman Scattering (SERS) technology as well as UV imprinted waveguide sensor for formaldehyde detection.

ISOLDE Off-line Gas Leak Upgrade

CERN Document Server

Nielsen, Kristoffer Bested

2017-01-01

This study investigates gas injection system of the ISOLDE Off-line separator. A quadrupole mass spectrometer is used to analysis the composition of the gas. Based on these measurements a contamination of the injected gas is found and a system upgrade is purposed. Furthermore a calibration of the leak rate of the leak valve is made.

Phase diagram and universality of the Lennard-Jones gas-liquid system

KAUST Repository

Watanabe, Hiroshi

2012-01-01

The gas-liquid phase transition of the three-dimensional Lennard-Jones particles system is studied by molecular dynamics simulations. The gas and liquid densities in the coexisting state are determined with high accuracy. The critical point is determined by the block density analysis of the Binder parameter with the aid of the law of rectilinear diameter. From the critical behavior of the gas-liquid coexisting density, the critical exponent of the order parameter is estimated to be β = 0.3285(7). Surface tension is estimated from interface broadening behavior due to capillary waves. From the critical behavior of the surface tension, the critical exponent of the correlation length is estimated to be ν = 0.63(4). The obtained values of β and ν are consistent with those of the Ising universality class. © 2012 American Institute of Physics.

Steady-state modelling of the universal exhaust gas oxygen (UEGO) sensor

International Nuclear Information System (INIS)

Collings, N; Hegarty, K; Ramsander, T

2012-01-01

The universal exhaust gas oxygen (UEGO) sensor is a well-established device which was developed for the measurement of relative air fuel ratio in internal combustion engines. There is, however, little information available which allows for the prediction of the UEGO's behaviour when exposed to arbitrary gas mixtures, pressures and temperatures. Here we present a steady-state model for the sensor, based on a solution of the Stefan–Maxwell equation, and which includes a momentum balance. The response of the sensor is dominated by a diffusion barrier, which controls the rate of diffusion of gas species between the exhaust and a cavity. Determination of the diffusion barrier characteristics, especially the mean pore size, porosity and tortuosity, is essential for the purposes of modelling, and a measurement technique based on identification of the sensor pressure giving zero temperature sensitivity is shown to be a convenient method of achieving this. The model, suitably calibrated, is shown to make good predictions of sensor behaviour for large variations of pressure, temperature and gas composition. (paper)

At the European Hybrid Spectrometer (EHS) for the experiment NA27

CERN Multimedia

1983-01-01

The experiment NA27 was intended to measure accurately the lifetime of Charm particles and to study their hadronic production and decay particles. The vertex detector was the hydrogen bubble chamber LEBC. The aim was to collect several hundreths of fully reconstructed D0 and D+-, and several tens of F+- and Lambda_c decays as produced by 360 GeV/c negative pions and 400 GeV/c protons. The photo gives a side view of a section of the spectrometer, with a 12 m long gas Cerenkov counter at the centre. The spectrometer axis enters the photo at bottom, left corner. See photo 8311661, 8311662X, 8311660X.

Proton Transfer Time-of-Flight Mass Spectrometer

Energy Technology Data Exchange (ETDEWEB)

Watson, Thomas B. [Brookhaven National Lab. (BNL), Upton, NY (United States)

2016-03-01

The Proton Transfer Reaction Mass Spectrometer (PTRMS) measures gas-phase compounds in ambient air and headspace samples before using chemical ionization to produce positively charged molecules, which are detected with a time-of-flight (TOF) mass spectrometer. This ionization method uses a gentle proton transfer reaction method between the molecule of interest and protonated water, or hydronium ion (H₃O⁺), to produce limited fragmentation of the parent molecule. The ions produced are primarily positively charged with the mass of the parent ion, plus an additional proton. Ion concentration is determined by adding the number of ions counted at the molecular ion’s mass-to-charge ratio to the number of air molecules in the reaction chamber, which can be identified according to the pressure levels in the reaction chamber. The PTRMS allows many volatile organic compounds in ambient air to be detected at levels from 10–100 parts per trillion by volume (pptv). The response time is 1 to 10 seconds.

Precise mass measurements of exotic nuclei--the SHIPTRAP Penning trap mass spectrometer

International Nuclear Information System (INIS)

Herfurth, F.; Ackermann, D.; Block, M.; Dworschak, M.; Eliseev, S.; Hessberger, F.; Hofmann, S.; Kluge, H.-J.; Maero, G.; Martin, A.; Mazzocco, M.; Rauth, C.; Vorobjev, G.; Blaum, K.; Ferrer, R.; Neidherr, D.; Chaudhuri, A.; Marx, G.; Schweikhard, L.; Neumayr, J.

2007-01-01

The SHIPTRAP Penning trap mass spectrometer has been designed and constructed to measure the mass of short-lived, radioactive nuclei. The radioactive nuclei are produced in fusion-evaporation reactions and separated in flight with the velocity filter SHIP at GSI in Darmstadt. They are captured in a gas cell and transfered to a double Penning trap mass spectrometer. There, the cyclotron frequencies of the radioactive ions are determined and yield mass values with uncertainties ≥4.5·10 -8 . More than 50 nuclei have been investigated so far with the present overall efficiency of about 0.5 to 2%

Application of FIGAERO (Filter Inlet for Gases and AEROsol) coupled to a high resolution time of flight chemical ionization mass spectrometer to field and chamber organic aerosol: Implications for carboxylic acid formation and gas-particle partitioning from monoterpene oxidation

Science.gov (United States)

Lopez-Hilfiker, F.; Mohr, C.; Ehn, M.; Rubach, F.; Mentel, T. F.; Kleist, E.; Wildt, J.; Thornton, J. A.

2013-12-01

We present measurements of a large suite of gas and particle phase carboxylic acid containing compounds made with a Filter Inlet for Gas and AEROsol (FIGAERO) coupled to a high resolution time of flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. A prototype operated with acetate negative ion proton transfer chemistry was deployed on the Julich Plant Atmosphere Chamber to study a-pinene oxidation, and a modified version was deployed at the SMEAR II forest station in Hyytiälä, Finland and SOAS, in Brent Alabama. We focus here on results from JPAC and Hyytiälä, where we utilized the same ionization method most selective towards carboxylic acids. In all locations, 100's of organic acid compounds were observed in the gas and particles and many of the same composition acids detected in the gas-phase were detected in the particles upon temperature programmed thermal desorption. Particulate organics detected by FIGAERO are highly correlated with organic aerosol mass measured by an AMS, providing additional volatility and molecular level information about collected aerosol. The fraction of a given compound measured in the particle phase follows expected trends with elemental composition, but many compounds would not be well described by an absorptive partitioning model assuming unity activity coefficients. Moreover the detailed structure in the thermal desorption signals reveals a contribution from thermal decomposition of large molecular weight organics and or oligomers with implications for partitioning measurements and model validation

An off Axis Cavity Enhanced Absorption Spectrometer and a Rapid Scan Spectrometer with a Room-Temperature External Cavity Quantum Cascade Laser

Science.gov (United States)

Liu, Xunchen; Kang, Cheolhwa; Xu, Yunjie

2009-06-01

Quantum cascade laser (QCL) is a new type of mid-infrared tunable diode lasers with superior output power and mode quality. Recent developments, such as room temperature operation, wide frequency tunability, and narrow line width, make QCLs an ideal light source for high resolution spectroscopy. Two slit jet infrared spectrometers, namely an off-axis cavity enhanced absorption (CEA) spectrometer and a rapid scan spectrometer with an astigmatic multi-pass cell assembly, have been coupled with a newly purchased room temperature tunable mod-hop-free QCL with a frequency coverage from 1592 cm^{-1} to 1698 cm^{-1} and a scan rate of 0.1 cm^{-1}/ms. Our aim is to utilize these two sensitive spectrometers, that are equipped with a molecular jet expansion, to investigate the chiral molecules-(water)_n clusters. To demonstrate the resolution and sensitivity achieved, the rovibrational transitions of the static N_2O gas and the bending rovibrational transitions of the Ar-water complex, a test system, at 1634 cm^{-1} have been measured. D. Hofstetter and J. Faist in High performance quantum cascade lasers and their applications, Vol.89 Springer-Verlag Berlin & Heidelberg, 2003, pp. 61-98. Y. Xu, X. Liu, Z. Su, R. M. Kulkarni, W. S. Tam, C. Kang, I. Leonov and L. D'Agostino, Proc. Spie, 2009, 722208 (1-11). M. J. Weida and D. J. Nesbitt, J. Chem. Phys. 1997, 106, 3078-3089.

Application of the mass-spectrometer MASHA for mass-spectrometry and laser-spectroscopy

Science.gov (United States)

Rodin, A. M.; Belozerov, A. V.; Dmitriev, S. N.; Oganessian, Yu. Ts.; Sagaidak, R. N.; Salamatin, V. S.; Stepantsov, S. V.; Vanin, D. V.

2010-02-01

We report the present status of the mass-spectrometer MASHA (Mass-Analyzer of Supper Heavy Atoms) designed for determination of the masses of superheavy elements. The mass-spectrometer is connected to the U-400M cyclotron of the Flerov Laboratory for Nuclear Reactions (FLNR) JINR, Dubna. The first experiments on mass-measurements for 112 and 114 elements will be performed in the upcoming 2010. For this purpose a hot catcher, based on a graphite stopper, is constructed. The α-decay of the superheavy nuclides or spontaneous fission products will be detected with a silicon 192 strips detector. The experimental program of future investigations using the technique of a gas catcher is discussed. It should be regarded as an alternative of the classical ISOL technique. The possibilities are considered for using this mass-spectrometer for laser spectroscopy of nuclei far off-stability.

Application of the mass-spectrometer MASHA for mass-spectrometry and laser-spectroscopy

International Nuclear Information System (INIS)

Rodin, A. M.; Belozerov, A. V.; Dmitriev, S. N.; Oganessian, Yu. Ts.; Sagaidak, R. N.; Salamatin, V. S.; Stepantsov, S. V.; Vanin, D. V.

2010-01-01

We report the present status of the mass-spectrometer MASHA (Mass-Analyzer of Supper Heavy Atoms) designed for determination of the masses of superheavy elements. The mass-spectrometer is connected to the U-400M cyclotron of the Flerov Laboratory for Nuclear Reactions (FLNR) JINR, Dubna. The first experiments on mass-measurements for 112 and 114 elements will be performed in the upcoming 2010. For this purpose a hot catcher, based on a graphite stopper, is constructed. The α-decay of the superheavy nuclides or spontaneous fission products will be detected with a silicon 192 strips detector. The experimental program of future investigations using the technique of a gas catcher is discussed. It should be regarded as an alternative of the classical ISOL technique. The possibilities are considered for using this mass-spectrometer for laser spectroscopy of nuclei far off-stability.

Application of the mass-spectrometer MASHA for mass-spectrometry and laser-spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Rodin, A. M., E-mail: rodin@nrmail.jinr.ru; Belozerov, A. V.; Dmitriev, S. N.; Oganessian, Yu. Ts.; Sagaidak, R. N.; Salamatin, V. S.; Stepantsov, S. V.; Vanin, D. V. [JINR, Flerov Laboratory of Nuclear Reactions (Russian Federation)

2010-02-15

We report the present status of the mass-spectrometer MASHA (Mass-Analyzer of Supper Heavy Atoms) designed for determination of the masses of superheavy elements. The mass-spectrometer is connected to the U-400M cyclotron of the Flerov Laboratory for Nuclear Reactions (FLNR) JINR, Dubna. The first experiments on mass-measurements for 112 and 114 elements will be performed in the upcoming 2010. For this purpose a hot catcher, based on a graphite stopper, is constructed. The {alpha}-decay of the superheavy nuclides or spontaneous fission products will be detected with a silicon 192 strips detector. The experimental program of future investigations using the technique of a gas catcher is discussed. It should be regarded as an alternative of the classical ISOL technique. The possibilities are considered for using this mass-spectrometer for laser spectroscopy of nuclei far off-stability.

Perspectives of Super-Heavy Nuclei research with the upcoming separator-spectrometer setup S3 at GANIL/SPIRAL2 - The VAMOS Gas-Filled separator and AGATA

Science.gov (United States)

Theisen, Christophe

2017-11-01

Several facilities or apparatus for the synthesis and spectroscopy of the Super-Heavy Nuclei (SHN) are presently under construction in the world, which reflect the large interest for this region of extreme mass and charge, but also for the need of even more advanced research infrastructures. Among this new generation, the GANIL/SPIRAL2 facility in Caen, France, will soon deliver very high intense ion beams of several tens of particle μA. The Super Separator Spectrometer S3 has been designed to exploit these new beams for the study of SHN after separation. It will provide the needed beam rejection, mass selection and full arsenal of state-of-the art detection setups. Still at GANIL, the AGATA new generation gamma-ray tracking array is being operated. The VAMOS high acceptance spectrometer is being upgraded as a gas-filled separator. Its coupling with AGATA will lower the spectroscopic limits for the prompt gamma-ray studies of heavy and super-heavy nuclei. In this proceeding, these new devices will be presented along with a selected physics case.

Peculiarities of taking account of background and spectrometer response function in processing the (n,p) and (n,np) reaction spectra

International Nuclear Information System (INIS)

Aleksandrov, D.V.; Kovrigin, B.S.

1980-01-01

Problems of taking account of background and spectrometer response function when restoring spectra of the (n, p) and (n, np) reactions at 14 MeV neutron energy are considered. These reaction spectra have been obtained by the (E, ΔE) method by means of a telescope consisting of two proportional gas counters. Main components of the reaction background, which must be taken account of, are background due to irradiation with primary and scattered neutrons of telescope details, background of random coincidences and background from scattered neutrons. The following corrections are introduced to the apparatus spectrum obtained after subtraction of all the spectrum kinds: energy resolution correction for the spectrometer, apparatus line stub correction for the spectrometer, energy loss correction for gas filling the telescope, energy loss and particle absorption corrections for the target [ru

Residual gas analysis

International Nuclear Information System (INIS)

Berecz, I.

1982-01-01

Determination of the residual gas composition in vacuum systems by a special mass spectrometric method was presented. The quadrupole mass spectrometer (QMS) and its application in thin film technology was discussed. Results, partial pressure versus time curves as well as the line spectra of the residual gases in case of the vaporization of a Ti-Pd-Au alloy were demonstrated together with the possible construction schemes of QMS residual gas analysers. (Sz.J.)

Multidimensional spectrometer

Science.gov (United States)

Zanni, Martin Thomas; Damrauer, Niels H.

2010-07-20

A multidimensional spectrometer for the infrared, visible, and ultraviolet regions of the electromagnetic spectrum, and a method for making multidimensional spectroscopic measurements in the infrared, visible, and ultraviolet regions of the electromagnetic spectrum. The multidimensional spectrometer facilitates measurements of inter- and intra-molecular interactions.

Compact terahertz passive spectrometer with wideband superconductor-insulator-superconductor mixer.

Science.gov (United States)

Kikuchi, K; Kohjiro, S; Yamada, T; Shimizu, N; Wakatsuki, A

2012-02-01

We developed a compact terahertz (THz) spectrometer with a superconductor-insulator-superconductor (SIS) mixer, aiming to realize a portable and highly sensitive spectrometer to detect dangerous gases at disaster sites. The receiver cryostat which incorporates the SIS mixer and a small cryocooler except for a helium compressor has a weight of 27 kg and dimensions of 200 mm × 270 mm × 690 mm. In spite of the small cooling capacity of the cryocooler, the SIS mixer is successfully cooled lower than 4 K, and the temperature variation is suppressed for the sensitive measurement. By adopting a frequency sweeping system using photonic local oscillator, we demonstrated a spectroscopic measurement of CH(3)CN gas in 0.2-0.5 THz range.

Small angle spectrometers: Summary

International Nuclear Information System (INIS)

Courant, E.; Foley, K.J.; Schlein, P.E.

1986-01-01

Aspects of experiments at small angles at the Superconducting Super Collider are considered. Topics summarized include a small angle spectrometer, a high contingency spectrometer, dipole and toroid spectrometers, and magnet choices

Advanced mass spectrometers for hydrogen-isotope analyses

International Nuclear Information System (INIS)

Chastagner, P.; Daves, H.L.; Hess, W.B.

1982-01-01

Two advanced mass spectrometers for the accurate analysis of mixtures of the hydrogen isotopes were evaluated by Du Pont personnel at the Savannah River Laboratory. One is a large double-focusing instrument with a resolution of 2000 at mass 4 and an abundance sensitivity of >100,000 for the HT-D 2 doublet. The second is a smaller, simpler, stigmatic focusing instrument with exceptionally high ion intensities (>1 x 10 - 9 A at 600 resolution and about 1 x 10 - 10 A at 1300 resolution) for high signal-to-noise ratios. Both instruments are computer controlled. Once a scan is started, peak switching, scanning, mass discrimination control, data collection, and data reduction are done without operator intervention. Utility routines control hysteresis effects and instrument calibration. A containment facility, with dual inlet systems and a standard distribution system, permits testing with tritium mixtures. Helium flow standards and tritium activity meters provide independent verification of the mass spectrometer calibrations. A recovery system prevents the release of tritium to the environment. The performance of the mass spectrometers was essentially equal under simulated process control conditions. Precision and accuracy for the D/T ratio was <0.5% (rel 2sigma limits). Performance factors were: sample equilibration <300 ppM; linearity within +-0.3%; and gas interference <0.1%. Mass discrimination was controlled reliably by the computers

Gas chromatography: mass selective detector

International Nuclear Information System (INIS)

Lapinskas, R.

1988-01-01

The mechanism of mass spectrometry technique directed for detecting molecular structures is described, with some considerations about its operational features. This mass spectrometer is used as a gas chromatography detector. (author)

Warm and cold molecular gas conditions modelled in 87 galaxies observed by the Herschel SPIRE Fourier transform spectrometer

Science.gov (United States)

Kamenetzky, J.; Rangwala, N.; Glenn, J.

2017-11-01

We have conducted two-component, non-local thermodynamic equilibrium modelling of the CO lines from J = 1-0 through J = 13-12 in 87 galaxies observed by the Herschel SPIRE Fourier Transform Spectrometer (FTS). We find the average pressure of the cold molecular gas, traced especially by CO J = 1-0, is ˜105.0±0.5 K cm-3. The mid- to high-J lines of CO trace higher pressure gas at 106.5 ± 0.6 K cm-3; this pressure is slightly correlated with LFIR. Two components are often necessary to accurately fit the Spectral Line Energy Distributions; a one-component fit often underestimates the flux of carbon monoxide (CO) J = 1-0 and the mass. If low-J lines are not included, mass is underestimated by an order of magnitude. Even when modelling the low-J lines alone or using an αCO conversion factor, the mass should be considered to be uncertain to a factor of at least 0.4 dex, and the vast majority of the CO luminosity will be missed (median, 65 per cent). We find a very large spread in our derived values of αCO, though they do not have a discernible trend with LFIR; the best fit is a constant 0.7 M⊙ (K km s- 1 pc2)-1, with a standard deviation of 0.36 dex, and a range of 0.3-1.6 M⊙ (K km s- 1 pc2)-1. We find average molecular gas depletion times (τdep) of 108 yr that decrease with increasing star formation rate. Finally, we note that the J = 11-10/J = 1-0 line flux ratio is diagnostic of the warm component pressure, and discuss the implications of this comprehensive study of SPIRE FTS extragalactic spectra for future study post-Herschel.

The influence of aerosol density upon the performance of centrifugal spectrometers

International Nuclear Information System (INIS)

Martonen, T.B.

1978-01-01

Centrifugal instruments are valuable components for studying airborne particulate matter of health physics interest because a continuously graded aerodynamic diameter, Dae, spectrum is produced. Applications include the characterization of inhalation exposure aerosols, serving as particle monitors to measure respirable dose, and being the integral unit in a system to generate monodisperse aerosols. Some aerosols of health physics concern differ from the PSL aerosol used to calibrate centrifuges in two main respects: the particulate mass concentration, Cm, is large, and the aerosol gas is not air. The marked influence of these factors upon centrifuge performance is documented (T. B. Martonen, Ph.D. Thesis, University of Rochester, Rochester, NY, 1976). The phenomenon of cloud settling occurs when Cm is of sufficient magnitude. Aerosol gas effects can be defined in terms of the parameter K, the ratio of the aerosol gas to winnowing medium densities. Size classification is modified by diffusiophoretic forces when K 1. In all cases, erroneous size distribution data results. Laboratory procedures are presented which permit accurate particle size assessment when aerosols of large Cm and/or K≠1 are sampled. An engineering analysis of centrifuge physics has been completed which allows optimum operating conditions, which may be quite different for different aerosols, to be computed. Cigarette smoke was used as a test aerosol to check the experimental and theoretical findings. Although it is shown to be subject to both cloud settling and dense gas subsidence, accurate size classification was obtained. The differential equation describing particle motion in centrifuges has been formulated and solved. Further, techniques of dimensional analysis were applied to the equations modelling flow in centrifuges; results indicate how operating conditions and instrument geometry influence particle size classification. These theoretical studies will lead to the development of improved

The SPEDE spectrometer

Science.gov (United States)

Papadakis, P.; Cox, D. M.; O'Neill, G. G.; Borge, M. J. G.; Butler, P. A.; Gaffney, L. P.; Greenlees, P. T.; Herzberg, R.-D.; Illana, A.; Joss, D. T.; Konki, J.; Kröll, T.; Ojala, J.; Page, R. D.; Rahkila, P.; Ranttila, K.; Thornhill, J.; Tuunanen, J.; Van Duppen, P.; Warr, N.; Pakarinen, J.

2018-03-01

The electron spectrometer, SPEDE, has been developed and will be employed in conjunction with the Miniball spectrometer at the HIE-ISOLDE facility, CERN. SPEDE allows for direct measurement of internal conversion electrons emitted in-flight, without employing magnetic fields to transport or momentum filter the electrons. Together with the Miniball spectrometer, it enables simultaneous observation of γ rays and conversion electrons in Coulomb excitation experiments using radioactive ion beams.

Rapid identification of pork for halal authentication using the electronic nose and gas chromatography mass spectrometer with headspace analyzer.

Science.gov (United States)

Nurjuliana, M; Che Man, Y B; Mat Hashim, D; Mohamed, A K S

2011-08-01

The volatile compounds of pork, other meats and meat products were studied using an electronic nose and gas chromatography mass spectrometer with headspace analyzer (GCMS-HS) for halal verification. The zNose™ was successfully employed for identification and differentiation of pork and pork sausages from beef, mutton and chicken meats and sausages which were achieved using a visual odor pattern called VaporPrint™, derived from the frequency of the surface acoustic wave (SAW) detector of the electronic nose. GCMS-HS was employed to separate and analyze the headspace gasses from samples into peaks corresponding to individual compounds for the purpose of identification. Principal component analysis (PCA) was applied for data interpretation. Analysis by PCA was able to cluster and discriminate pork from other types of meats and sausages. It was shown that PCA could provide a good separation of the samples with 67% of the total variance accounted by PC1. Copyright © 2011 Elsevier Ltd. All rights reserved.

Supersonic gas streams enhance the formation of massive black holes in the early universe.

Science.gov (United States)

Hirano, Shingo; Hosokawa, Takashi; Yoshida, Naoki; Kuiper, Rolf

2017-09-29

The origin of super-massive black holes in the early universe remains poorly understood. Gravitational collapse of a massive primordial gas cloud is a promising initial process, but theoretical studies have difficulty growing the black hole fast enough. We report numerical simulations of early black hole formation starting from realistic cosmological conditions. Supersonic gas motions left over from the Big Bang prevent early gas cloud formation until rapid gas condensation is triggered in a protogalactic halo. A protostar is formed in the dense, turbulent gas cloud, and it grows by sporadic mass accretion until it acquires 34,000 solar masses. The massive star ends its life with a catastrophic collapse to leave a black hole-a promising seed for the formation of a monstrous black hole. Copyright © 2017 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

New mass spectrometers for hydrogen isotope analyses

International Nuclear Information System (INIS)

Chastagner, P.; Daves, H.L.; Hess, W.B.

1981-01-01

Two advanced mass spectrometers for the accurate analysis of mixtures of the hydrogen isotopes are being evaluated by Du Pont personnel at the Savannah River Laboratory. One is a large double-focusing instrument with a resolution of 2000 at mass 4, an abundance sensitivity of > 100,000 for the HT-D 2 doublet, and a sophisticated electronic control and data collection system. The second is a smaller, simpler, stigmatic-focusing instrument in which exceptionally high ion intensities (> 1 x 10 -9 A) result in high signal to noise ratios. A containment facility with sample inlet systems and a standard distribution system was built to permit testing with tritium mixtures. The characteristics of the mass spectrometers under a variety of operating conditions will be presented. Factors to be discussed include: sample equilibration and its elimination; linearity; trimer formation; gas interference; stability; signal to noise ratio; mass discrimination; and anticipated precision and accu sublimed molybdenum collector of Converter No. 262; and (3) demonstration of tungsten CVD onto molybdenum flange using a reuseable graphite mandrel

Mechanism of ion output for the MI-1305 mass-spectrometer

Energy Technology Data Exchange (ETDEWEB)

Kornyushkin, YW D; Stavrovich, N V [Leningradskij Inst. Tochnoj Mekhaniki i Optiki (USSR)

1976-01-01

An attachment to MJ-1305 mass-spectrometer for ion ejection enabling to study interaction of ions and substance is designed. The attachment is accomodated with a block of diaphragms forming a beam of primary ions. A magneto-discharge pump has been used to improve vacuum in a sample chamber up to 5x10/sup -8/ torr. An universal exit slit permits producing ion beam currents ranging from 10/sup -9/ to 10/sup -10/ A with 4 keV energy under operating conditions of the spectrometer as an ion source. To ensure a higher noise stability of the measuring circuit the ion current is measured through a variable signal with synchronous detection employed.

Capillary absorption spectrometer and process for isotopic analysis of small samples

Energy Technology Data Exchange (ETDEWEB)

Alexander, M. Lizabeth; Kelly, James F.; Sams, Robert L.; Moran, James J.; Newburn, Matthew K.; Blake, Thomas A.

2018-04-24

A capillary absorption spectrometer and process are described that provide highly sensitive and accurate stable absorption measurements of analytes in a sample gas that may include isotopologues of carbon and oxygen obtained from gas and biological samples. It further provides isotopic images of microbial communities that allow tracking of nutrients at the single cell level. It further targets naturally occurring variations in carbon and oxygen isotopes that avoids need for expensive isotopically labeled mixtures which allows study of samples taken from the field without modification. The process also permits sampling in vivo permitting real-time ambient studies of microbial communities.

Capillary absorption spectrometer and process for isotopic analysis of small samples

Energy Technology Data Exchange (ETDEWEB)

Alexander, M. Lizabeth; Kelly, James F.; Sams, Robert L.; Moran, James J.; Newburn, Matthew K.; Blake, Thomas A.

2016-03-29

A capillary absorption spectrometer and process are described that provide highly sensitive and accurate stable absorption measurements of analytes in a sample gas that may include isotopologues of carbon and oxygen obtained from gas and biological samples. It further provides isotopic images of microbial communities that allow tracking of nutrients at the single cell level. It further targets naturally occurring variations in carbon and oxygen isotopes that avoids need for expensive isotopically labeled mixtures which allows study of samples taken from the field without modification. The method also permits sampling in vivo permitting real-time ambient studies of microbial communities.

Standard test method for isotopic analysis of uranium hexafluoride by double standard single-collector gas mass spectrometer method

CERN Document Server

American Society for Testing and Materials. Philadelphia

2010-01-01

1.1 This is a quantitative test method applicable to determining the mass percent of uranium isotopes in uranium hexafluoride (UF6) samples with 235U concentrations between 0.1 and 5.0 mass %. 1.2 This test method may be applicable for the entire range of 235U concentrations for which adequate standards are available. 1.3 This test method is for analysis by a gas magnetic sector mass spectrometer with a single collector using interpolation to determine the isotopic concentration of an unknown sample between two characterized UF6 standards. 1.4 This test method is to replace the existing test method currently published in Test Methods C761 and is used in the nuclear fuel cycle for UF6 isotopic analyses. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appro...

ultra-Stable Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (5STAR)

Science.gov (United States)

Dunagan, S. E.; Johnson, R. R.; Redemann, J.; Holben, B. N.; Schmid, B.; Flynn, C. J.; Fahey, L.; LeBlanc, S. E.; Liss, J.; Kacenelenbogen, M. S.; Segal-Rosenhaimer, M.; Shinozuka, Y.; Dahlgren, R. P.; Pistone, K.; Karol, Y.

2017-12-01

The Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) combines airborne sun tracking and sky scanning with diffraction spectroscopy to improve knowledge of atmospheric constituents and their links to air pollution and climate. Direct beam hyperspectral measurement of optical depth improves retrievals of gas constituents and determination of aerosol properties. Sky scanning enhances retrievals of aerosol type and size distribution. Hyperspectral cloud-transmitted radiance measurements enable the retrieval of cloud properties from below clouds. These measurements tighten the closure between satellite and ground-based measurements. 4STAR incorporates a modular sun-tracking/ sky-scanning optical head with optical fiber signal transmission to rack mounted spectrometers, permitting miniaturization of the external optical tracking head, and future detector evolution. 4STAR has supported a broad range of flight experiments since it was first flown in 2010. This experience provides the basis for a series of improvements directed toward reducing measurement uncertainty and calibration complexity, and expanding future measurement capabilities, to be incorporated into a new 5STAR instrument. A 9-channel photodiode radiometer with AERONET-matched bandpass filters will be incorporated to improve calibration stability. A wide dynamic range tracking camera will provide a high precision solar position tracking signal as well as an image of sky conditions around the solar axis. An ultrasonic window cleaning system design will be tested. A UV spectrometer tailored for formaldehyde and SO2 gas retrievals will be added to the spectrometer enclosure. Finally, expansion capability for a 4 channel polarized radiometer to measure the Stokes polarization vector of sky light will be incorporated. This paper presents initial progress on this next-generation 5STAR instrument. Keywords: atmosphere; climate; pollution; radiometry; technology; hyperspectral; fiber optic

Spectrometer for X-ray emission experiments at FERMI free-electron-laser

International Nuclear Information System (INIS)

Poletto, L.; Frassetto, F.; Miotti, P.; Di Cicco, A.; Iesari, F.; Finetti, P.; Grazioli, C.; Kivimäki, A.; Stagira, S.; Coreno, M.

2014-01-01

A portable and compact photon spectrometer to be used for photon in-photon out experiments, in particular x-ray emission spectroscopy, is presented. The instrument operates in the 25–800 eV energy range to cover the full emissions of the FEL1 and FEL2 stages of FERMI. The optical design consists of two interchangeable spherical varied-lined-spaced gratings and a CCD detector. Different input sections can be accommodated, with/without an entrance slit and with/without an additional relay mirror, that allow to mount the spectrometer in different end-stations and at variable distances from the target area both at synchrotron and at free-electron-laser beamlines. The characterization on the Gas Phase beamline at ELETTRA Synchrotron (Italy) is presented

Early Design Stage of the MsAa-4 Moessbauer Spectrometer

International Nuclear Information System (INIS)

Blachowski, A.; Ruebenbauer, K.; Zukrowski, J.; Gornicki, R.

2008-01-01

Entirely new Moessbauer spectrometer MsAa-4 is currently under design and construction. New features as compared to the basic features of the previous generation MsAa-3 spectrometer could be summarized as follows. Completely digital processing of the γ-ray detector signal beyond the Gaussian shape filter/amplifier is to be implemented. The spectrometer is going to be able to accommodate external multiple detector heads. One could collect simultaneously up to 128 γ-ray spectra in 16384 channels of 32-bit each and up to 512 Moessbauer spectra in 4096 channels of 32-bit each provided the proper external multiple detector head is used. The count-rate per single detector is limited to about 105 counts per second total. Improved precision of the reference function from 12-bit to 16-bit is to be provided. The reference function is stored in 8192 channels per complete cycle. Addition of the random noise to the reference corner prism of the Michelson-Morley calibration interferometer is to be introduced to avoid spurious fringes due to the phase lock-up. Integrated universal temperature controller being able to use variety of the temperature sensors is to be interconnected with the proper spectrometer. The spectrometer is now a stand-alone network device as it is equipped with the Ethernet connection to the outside world. Modular design and use of the strict standards allows easy reconfiguration for other applications than the Moessbauer spectroscopy. (authors)

Gas microstrip chambers

International Nuclear Information System (INIS)

McIntyre, P.M.; Barasch, E.F.; Bowcock, T.J.V.; Demroff, H.P.; Elliott, S.M.; Howe, M.R.; Lee, B.; Mazumdar, T.K.; Pang, Y.; Smith, D.D.; Wahl, J.; Wu, Y.; Yue, W.K.; Gaedke, R.M.; Vanstraelen, G.

1992-01-01

The gas microstrip chamber has been developed from concept to experimental system during the past three years. A pattern of anode and grid lines are microfabricated onto a dielectric substrate and configured as a high-resolution MWPC. Four recent developments are described: Suitable plastic substrates and lithography techniques for large-area chambers; non-planar silicon-based chambers for 20 μm resolution; integrated on-board synchronous front-end electronics and data buffering; and a porous silicon active cathode for enhanced efficiency and time response. The microstrip chamber appears to be a promising technology for applications in microvertex, tracking spectrometer, muon spectrometer, and transition radiation detection. (orig.)

Performance of drift chambers in a magnetic rigidity spectrometer for measuring the cosmic radiation

International Nuclear Information System (INIS)

Hof, M.; Bremerich, M.; Menn, W.; Pfeifer, C.; Reimer, O.; Simon, M.; Mitchell, J.W.; Barbier, L.M.; Christian, E.R.; Ormes, J.F.; Streitmatter, R.E.; Golden, R.L.; Stochaj, S.J.

1994-01-01

A drift chamber tracking system was developed and flown as part of the IMAX balloon-borne magnetic spectrometer. The drift chamber uses a hexagonal drift-cell structure and is filled with pure CO 2 gas. It operated with high efficiency in the strong and inhomogenous field of a superconducting magnet, demonstrating a spatial resolution of better than 100 μm over most of the drift path for singly charged particles, as well as for helium and lithium nuclei. The drift chamber portion of the spectrometer achieved a maximum detectable rigidity of 175 and 250 GV/c for protons and helium respectively. ((orig.))

Investigation of material systems in industry and research by organic analytical mass spectrometer

International Nuclear Information System (INIS)

Decsy, Z.

1980-01-01

The modern, many-sided and efficient organic analytical mass spectrometer possesses all the structure-and composition-examination possibilities of complex organic analytical laboratories. The article presents the advantages and possibilities of the application of mass spectrometer in different operation modes in connection with the examination of a petrochemical synthesis product: ortho-phenylene-diamine, an experimental gas odorizing material, a petroleum production auxiliary material: petroleum sulfonate, a gasoline sample and a sulfur-containing standard substance. The useful operation modes include spectrum records of low and high resolution, the application of space ionization and space desorption ion sources as well as the ''mass fragmentographic'' measuring method. (author)

In Situ Raman Analyses of Natural Gas and Gas Hydrates at Hydrate Ridge, Oregon

Science.gov (United States)

Peltzer, E. T.; White, S. N.; Dunk, R. M.; Brewer, P. G.; Sherman, A. D.; Schmidt, K.; Hester, K. C.; Sloan, E. D.

2004-12-01

During a July 2004 cruise to Hydrate Ridge, Oregon, MBARI's sea-going laser Raman spectrometer was used to obtain in situ Raman spectra of natural gas hydrates and natural gas venting from the seafloor. This was the first in situ analysis of gas hydrates on the seafloor. The hydrate spectra were compared to laboratory analyses performed at the Center for Hydrate Research, Colorado School of Mines. The natural gas spectra were compared to MBARI gas chromatography (GC) analyses of gas samples collected at the same site. DORISS (Deep Ocean Raman In Situ Spectrometer) is a laboratory model laser Raman spectrometer from Kaiser Optical Systems, Inc modified at MBARI for deployment in the deep ocean. It has been successfully deployed to depths as great as 3600 m. Different sampling optics provide flexibility in adapting the instrument to a particular target of interest. An immersion optic was used to analyze natural gas venting from the seafloor at South Hydrate Ridge ( ˜780 m depth). An open-bottomed cube was placed over the vent to collect the gas. The immersion optic penetrated the side of the cube as did a small heater used to dissociate any hydrate formed during sample collection. To analyze solid hydrates at both South and North Hydrate Ridge ( ˜590 m depth), chunks of hydrate were excavated from the seafloor and collected in a glass cylinder with a mesh top. A stand-off optic was used to analyze the hydrate inside the cylinder. Due to the partial opacity of the hydrate and the small focal volume of the sampling optic, a precision underwater positioner (PUP) was used to focus the laser spot onto the hydrate. PUP is a stand-alone system with three degrees-of-freedom, capable of moving the DORISS probe head with a precision of 0.1 mm. In situ Raman analyses of the gas indicate that it is primarily methane. This is verified by GC analyses of samples collected from the same site. Other minor constituents (such as CO2 and higher hydrocarbons) are present but may be in

Description and performance of an electron-ion coincidence TOF spectrometer used at the Brazilian synchrotron facility LNLS

International Nuclear Information System (INIS)

Burmeister, F.; Coutinho, L.H.; Marinho, R.R.T.; Homem, M.G.P.; Morais, M.A.A. de; Mocellin, A.; Bjoerneholm, O.; Sorensen, S.L.; Fonseca, P.T.; Lindgren, A.; Naves de Brito, A.

2010-01-01

This paper reports the characteristics and performance of a Time-of-Flight Mass Spectrometer (TOF-MS) for coincidence measurements between electrons and ions that has been developed jointly in Sweden and Brazil. The spectrometer, used for studies of inner-shell photoexcitation of molecules in the gas-phase, has been optimized by implementing ion and electron lenses to allow the use of relatively small diameter detectors. Simulations were performed to understand the lens performance and they show that ions (electrons) could be collected without angular discrimination with a maximum kinetic energy up to ten (two) times higher than without the lens actions. A rotary vacuum chamber allows the spectrometer axis to be positioned at different angles relative to the polarization vector of the excitation beam. An important characteristic of the apparatus is that the acquisition setup allows a multi-hit capability with 1 ns resolution. Hereby, Photoelectron-Photoion-Photoion Coincidence (PEPIPICO) measurements can be performed on molecules containing two or more atoms of equal mass. A method to obtain experimental detection efficiencies of a single ion and one of one, two or three electrons has been developed. A systematic study of the interaction region has been performed to determine the shape of the photon and gas beams. Measurements on molecular nitrogen demonstrate the spectrometer's ability to resolve fragments with the same charge to mass ratio arriving within only a few ns. Simulations and experimental results of fragmentation of two singly charged cation nitrogen atoms agree, confirming that the spectrometer performance is well understood.

Description and performance of an electron-ion coincidence TOF spectrometer used at the Brazilian synchrotron facility LNLS

Energy Technology Data Exchange (ETDEWEB)

Burmeister, F. [Laboratorio Nacional de Luz Sincrotron, 13084-971, Campinas, SP (Brazil); Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala (Sweden); Coutinho, L.H. [Laboratorio Nacional de Luz Sincrotron, 13084-971, Campinas, SP (Brazil); Instituto de Fisica, Universidade Estadual de Campinas, 13083-970 Campinas, SP (Brazil); Marinho, R.R.T. [Laboratorio Nacional de Luz Sincrotron, 13084-971, Campinas, SP (Brazil); Homem, M.G.P. [Departamento de Quimica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Morais, M.A.A. de; Mocellin, A. [Instituto de Fisica, Universidade de Brasilia, 70910-900 Brasilia, DF (Brazil); Bjoerneholm, O. [Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala (Sweden); Sorensen, S.L. [SLF, Institute of Physics, University of Lund, Box 118, S-221 00 Lund (Sweden); Fonseca, P.T. [Laboratorio Nacional de Luz Sincrotron, 13084-971, Campinas, SP (Brazil); Lindgren, A. [SLF, Institute of Physics, University of Lund, Box 118, S-221 00 Lund (Sweden); Naves de Brito, A., E-mail: arnaldo.naves@gmail.co [Laboratorio Nacional de Luz Sincrotron, 13084-971, Campinas, SP (Brazil); Instituto de Fisica, Universidade de Brasilia, 70910-900 Brasilia, DF (Brazil)

2010-06-15

This paper reports the characteristics and performance of a Time-of-Flight Mass Spectrometer (TOF-MS) for coincidence measurements between electrons and ions that has been developed jointly in Sweden and Brazil. The spectrometer, used for studies of inner-shell photoexcitation of molecules in the gas-phase, has been optimized by implementing ion and electron lenses to allow the use of relatively small diameter detectors. Simulations were performed to understand the lens performance and they show that ions (electrons) could be collected without angular discrimination with a maximum kinetic energy up to ten (two) times higher than without the lens actions. A rotary vacuum chamber allows the spectrometer axis to be positioned at different angles relative to the polarization vector of the excitation beam. An important characteristic of the apparatus is that the acquisition setup allows a multi-hit capability with 1 ns resolution. Hereby, Photoelectron-Photoion-Photoion Coincidence (PEPIPICO) measurements can be performed on molecules containing two or more atoms of equal mass. A method to obtain experimental detection efficiencies of a single ion and one of one, two or three electrons has been developed. A systematic study of the interaction region has been performed to determine the shape of the photon and gas beams. Measurements on molecular nitrogen demonstrate the spectrometer's ability to resolve fragments with the same charge to mass ratio arriving within only a few ns. Simulations and experimental results of fragmentation of two singly charged cation nitrogen atoms agree, confirming that the spectrometer performance is well understood.

The Omega spectrometer in the West Hall.

CERN Multimedia

CERN PhotoLab

1976-01-01

Inside the hut which sits on top of the superconducting magnet are the TV cameras that observe the particle events occurring in the spark chambers in the magnet gap below. On the background the two beam lines feeding the spectrometer target, for separated hadrons up to 40 GeV, on the right, for 80 GeV electrons, on the left, respectively. The latter strikes a radiator thus sending into Omega tagged photons up to 80 GeV. On the foreground, the two sections of the large gas Cerenkov counter working at atmospheric pressure, used for trigger purpose.

Mobility Spectrometer Studies on Hydrazine and Ammonia Detection

Science.gov (United States)

Niu, William; Eiceman, Gary; Szumlas, Andrew; Lewis, John

2011-01-01

An airborne vapor analyzer for detecting sub- to low- parts-per-million (ppm) hydrazine in the presence of higher concentration levels of ammonia has been under development for the Orion program. The detector is based on ambient pressure ionization and ion mobility characterization. The detector encompasses: 1) a membrane inlet to exclude particulate and aerosols from the analyzer inlet; 2) a method to separate hydrazine from ammonia which would otherwise lead to loss of calibration and quantitative accuracy for the hydrazine determination; and 3) response and quantitative determinations for both hydrazine and ammonia. Laboratory studies were made to explore some of these features including mobility measurements mindful of power, size, and weight issues. The study recommended the use of a mobility spectrometer of traditional design with a reagent gas and equipped with an inlet transfer line of bonded phase fused silica tube. The inlet transfer line provided gas phase separation of neutrals of ammonia from hydrazine at 50 C simplifying significantly the ionization chemistry that underlies response in a mobility spectrometer. Performance of the analyzer was acceptable between ranges of 30 to 80 C for both the pre-fractionation column and the drift tube. An inlet comprised of a combined membrane with valve-less injector allowed high speed quantitative determination of ammonia and hydrazine without cross reactivity from common metabolites such as alcohols, esters, and aldehydes. Preliminary test results and some of the design features are discussed.

Horizontal Ampoule Growth and Characterization of Mercuric Iodide at Controlled Gas Pressures for X-Ray and Gamma Ray Spectrometers

International Nuclear Information System (INIS)

Douglas, S.; McGregor Elsa; Ariesanti Bridget Corcoran

2004-01-01

The project developed a new method for producing high quality mercuric iodide crystals of x-ray and gamma spectrometers. Included are characterization of mercuric iodide crystal properties as a function of growth environment and fabrication and demonstration of room-temperature-operated high-resolution mercuric iodide spectrometers

Continuous flow isotope ratio mass spectrometer (CF-IRMS) and its applications in hydrocarbon research and exploration

International Nuclear Information System (INIS)

Kalpana, G.; Patil, D.J.; Kumar, B.

2004-01-01

Stable isotope ratio mass spectrometers have been widely used to determine the isotopic ratios of light elements such as hydrogen, carbon, nitrogen, oxygen and sulphur. Continuous Flow Isotope Ratio Mass Spectrometry (CFIRMS) provides reliable data on nanomole amount of sample gas without the need for cryogenic trapping using cold fingers as in dual inlet isotope ratio mass spectrometer. High sample throughput is achieved as the system is configured with automated sample preparation devices and auto samplers. This paper presents a brief description of CFIRMS exploration

Testing the universality of the star-formation efficiency in dense molecular gas

Science.gov (United States)

Shimajiri, Y.; André, Ph.; Braine, J.; Könyves, V.; Schneider, N.; Bontemps, S.; Ladjelate, B.; Roy, A.; Gao, Y.; Chen, H.

2017-08-01

Context. Recent studies with, for example, Spitzer and Herschel have suggested that star formation in dense molecular gas may be governed by essentially the same "law" in Galactic clouds and external galaxies. This conclusion remains controversial, however, in large part because different tracers have been used to probe the mass of dense molecular gas in Galactic and extragalactic studies. Aims: We aimed to calibrate the HCN and HCO+ lines commonly used as dense gas tracers in extragalactic studies and to test the possible universality of the star-formation efficiency in dense gas (≳104 cm-3), SFEdense. Methods: We conducted wide-field mapping of the Aquila, Ophiuchus, and Orion B clouds at 0.04 pc resolution in the J = 1 - 0 transition of HCN, HCO+, and their isotopomers. For each cloud, we derived a reference estimate of the dense gas mass MHerschelAV > 8, as well as the strength of the local far-ultraviolet (FUV) radiation field, using Herschel Gould Belt survey data products, and estimated the star-formation rate from direct counting of the number of Spitzer young stellar objects. Results: The H13CO+(1-0) and H13CN(1-0) lines were observed to be good tracers of the dense star-forming filaments detected with Herschel. Comparing the luminosities LHCN and LHCO+ measured in the HCN and HCO+ lines with the reference masses MHerschelAV > 8, the empirical conversion factors αHerschel - HCN (=MHerschelAV > 8/LHCN) and αHerschel - HCO+ (=MHerschelAV > 8/LHCO+) were found to be significantly anti-correlated with the local FUV strength. In agreement with a recent independent study of Orion B by Pety et al., the HCN and HCO+ lines were found to trace gas down to AV ≳ 2. As a result, published extragalactic HCN studies must be tracing all of the moderate density gas down to nH2 ≲ 103 cm-3. Estimating the contribution of this moderate density gas from the typical column density probability distribution functions in nearby clouds, we obtained the following G0

Tools to probe the universe

International Nuclear Information System (INIS)

Lagage, P.O.; Augueres, J.L.; Amiaux, J.; Cara, Ch.; Fontignie, J.; Rio, Y.; Fermon, C.; Pannetier-Lecoeur, M.; De Vismes, A.; Cordier, B.; Fesquet, M.; Ferrando, Ph.; Authier, M.; Pantin, E.; Glicenstein, J.F.; Boulade, O.; Refregier, A.; Stolarczyk, Th.; Agnese, P.; Rodriguez, L.; Agnese, P.; Pigot, C.; Duband, L.; Limousin, O.; Delagnes, E.; Turck-Chieze, S.; Carton, P.H.; Starck, J.L.; Bournaud, F.; Teyssier, R.; Audit, E.; Brun, A.S.; Leca, P.; Menache, Ch.; Pomarede, D.; Thooris, B.; Meis, C.

2009-01-01

This special issue of Clefs CEA journal is entirely devoted to astrophysics and to the exploration and probing of the Universe. The second part of this dossier, described here, makes a status of the tools used to probe the universe: telescopes, imaging spectrometers, data processing and simulation. Content: A - Telescopes of the future: 1. Seeing further out: JWST: looking back on a past 13 billion years old, Space specifics: the learning curve to know-how, Fabricating a corona-graph mask, SVOM, a satellite to detect the explosions of the first stars to be formed in the Universe; 2. Seeing more precisely: SIMBOL-X, pioneering formation flying, ELT/METIS, a 42-meter giant, One hundred telescopes for the CTA arrays; 3. Seeing wider: Euclid, mapping the extragalactic sky, ANTARES: the neutrino, another cosmic messenger; B - The new generation of imaging spectrometers: Observing the Universe in the submillimeter spectral region, The X-ray Universe, Space cryo-coolers, Out in the extreme, tumultuous Universe, Probing the Sun with GOLF-NG, Focus: From light to imagery; C - Data analysis in astrophysics; D - Numerical simulation in astrophysics: Information technology and theoretical predictions in astrophysics, Supercomputers for a better understanding of the Universe, The visualization of astrophysical simulations, Godunov, a numerical platform for education and research

Studies on reducing the scale of a double focusing mass spectrometer

International Nuclear Information System (INIS)

Chambers, D.M.; Gregg, H.R.; Andresen, B.D.

1993-05-01

Several groups have developed miniaturized sector mass spectrometers with the goal of remote sensing in confined spaces or portability. However, these achievements have been overshadowed by more successful development of man-portable quadrupole and ion trap mass spectrometers. Despite these accomplishments the development of a reduced-scale sector mass spectrometer remains attractive as a potentially low-cost, robust instrument requiring very simple electronics and low power. Previous studies on miniaturizing sector instruments include the use of a Mattauch-Herzog design for a portable mass spectrograph weighing less than 10 kg. Other work has included the use of a Nier-Johnson design in spacecraft-mountable gas chromatography mass spectrometers for the Viking spacecraft as well as miniature sector-based MS/MS instrument. Although theory for designing an optimized system with high resolution and mass accuracy is well understood, such specifications have not yet been achieved in a miniaturized instrument. To proceed further toward the development of a miniaturized sector mass spectrometer, experiments were conducted to understand and optimize a practical, yet nonideal instrument configuration. The sector mass spectrometer studied in this work is similar to the ones developed for the Viking project, but was further modified to be low cost, simple and robust. Characteristics of this instrument that highlight its simplicity include the use of a modified Varian leak detector ion source, source ion optics that use one extraction voltage, and an unshunted fixed nonhomogeneous magnetic sector. The effects of these design simplifications on ion trajectory were studied by manipulating the ion beam along with the magnetic sector position. This latter feature served as an aid to study ion focusing amidst fringing fields as well as nonhomogeneous forces and permitted empirical realignment of the instrument

Cosmological Imprints of a Generalized Chaplygin Gas Model for the Early Universe

Energy Technology Data Exchange (ETDEWEB)

Bouhmadi-Lopez, Mariam; /Lisbon, CENTRA; Chen, Pisin; /Taiwan, Natl. Taiwan U. /KIPAC, Menlo Park /SLAC; Liu, Yen-Wei; /Taiwan, Natl. Taiwan U.

2012-06-06

We propose a phenomenological model for the early universe where there is a smooth transition between an early quintessence phase and a radiation-dominated era. The matter content is modeled by an appropriately modified Chaplygin gas for the early universe. We constrain the model observationally by mapping the primordial power spectrum of the scalar perturbations to the latest data of WMAP7. We compute as well the spectrum of the primordial gravitational waves as would be measured today. We show that the high frequencies region of the spectrum depends on the free parameter of the model and most importantly this region of the spectrum can be within the reach of future gravitational waves detectors.

Gas analysis by computer-controlled microwave rotational spectrometry

International Nuclear Information System (INIS)

Hrubesh, L.W.

1978-01-01

Microwave rotational spectrometry has inherently high resolution and is thus nearly ideal for qualitative gas mixture analysis. Quantitative gas analysis is also possible by a simplified method which utilizes the ease with which molecular rotational transitions can be saturated at low microwave power densities. This article describes a computer-controlled microwave spectrometer which is used to demonstrate for the first time a totally automated analysis of a complex gas mixture. Examples are shown for a complete qualitative and quantitative analysis, in which a search of over 100 different compounds is made in less than 7 min, with sensitivity for most compounds in the 10 to 100 ppm range. This technique is expected to find increased use in view of the reduced complexity and increased reliabiity of microwave spectrometers and because of new energy-related applications for analysis of mixtures of small molecules

Precise determination of cosmogenic Ne in CREU-1 quartz standard, using the Helix-MC Plus mass spectrometer

Science.gov (United States)

Hamilton, D.; Honda, M.; Zhang, X.; Phillips, D.; Matchan, E.

2017-12-01

The Helix-MC Plus multi-collector noble gas mass spectrometer at the Australian National University is uniquely equipped with three high mass resolution collectors on H2, Axial and L2 positions. Their mass resolution and mass resolving power are as high as 1,800 and 8,000, respectively. The Helix-MC Plus can totally separate 20Ne+ from 40Ar++ isobaric interference and also partially separate 21Ne+ from 20NeH+ and 22Ne+ from 12C16O2++. By adjusting collector positions, we are able to measure interference-free Ne isotope intensities and have re-determined the 21Ne abundance in air [1]. Analyses by Honda et al. [1] demonstrated that 20Ne1H contributes approximately 2% to previously determined atmospheric 21Ne values [2], and a new atmospheric 21Ne/20Ne ratio of 0.002906 was calculated. Using the Helix-MC Plus mass spectrometer, we measured Ne abundances in the CREU-1 quartz standard [3] and determined cosmogenic concentrations by subtraction of atmospheric Ne with the new atmospheric 21Ne/20Ne value. The average concentration of cosmogenic 21Ne determined from four repeated analyses is 338 ± 12 × 106 atom/g (2σ). This compares with the average concentration of 348 ± 10 × 106 atom/g (2σ) from 45 analyses determined by several laboratories [3], where Ne isotope analyses were undertaken by conventional low resolution mass spectrometers and atmospheric Ne was subtracted using the conventional atmospheric 21Ne/20Ne [2]. On this basis, for a sample with abundant cosmogenic Ne, like CREU-1 quartz, previously measured by low mass resolution mass spectrometers are likely valid and their geological implications are unaffected. However, for low 21Ne concentration samples, combining new generation of mass spectrometers as well as the new atmospheric ratio may have significance for cosmogenic 21Ne surface exposure dating. References: [1] Honda M., et. al., International Journal of Mass Spectrometry, 387, 1 (2015). [2] Eberhardt P., et. al., Zeitschrift fur Naturforschung, 20

Rapid monitoring of gaseous radionuclides using a portable spectrometer

International Nuclear Information System (INIS)

Chung, C.; Tsai, C.H.

1995-01-01

A field gamma ray spectrometer, consisting of a portable high purity germanium detector, portable multichannel analyser, and a notebook computer, was used to conduct in situ rapid scanning of radioactive Ar, Kr and Xe isotopes in the air around a nuclear facility. The portable gamma ray spectrometer was calibrated using Ar, Kr, and Xe radioisotopes, activated in a research reactor and released in a sealed chamber. The unit was further tested inside the reactor containment to monitor the concentration of 41 Ar. In a typical one hour field measurement, the detection limits for some rare gas radionuclides corresponded to dose rates around 0.1 nSv.h -1 , which is far less than the dose rate induced by derived air concentrations imposed by the authority. The dose rate due to ground level concentrations of gaseous radionuclides dispersed from a source, such a nuclear facility or nuclear test, can be monitored in a short period using the portable unit. (Author)

The Omicron Spectrometer

CERN Document Server

Allardyce, B W

1976-01-01

It is intended to build a spectrometer with a large solid angle and a large momentum acceptance at the reconstructed synchrocyclotron at CERN. This spectrometer will have an energy resolution of about 1 MeV for particles with momenta up to about 400 MeV/c.

Direct mass measurements of neutron-deficient xenon isotopes using the ISOLTRAP mass spectrometer

CERN Document Server

Dilling, J; Beck, D; Bollen, G; Herfurth, F; Kellerbauer, A G; Kluge, H J; Moore, R B; Scheidenberger, C; Schwarz, S; Sikler, G

2004-01-01

The masses of the noble-gas Xe isotopes with 114 $\\leq$ A $\\leq$ 123 have been directly measured for the first time. The experiments were carried out with the ISOLTRAP triple trap spectrometer at the online mass separator ISOLDE/CERN. A mass resolving power of the Penning trap spectrometer of $m/\\Delta m$ of close to a million was chosen resulting in an accuracy of $\\delta m \\leq 13$ keV for all investigated isotopes. Conflicts with existing, indirectly obtained, mass data by several standard deviations were found and are discussed. An atomic mass evaluation has been performed and the results are compared to information from laser spectroscopy experiments and to recent calculations employing an interacting boson model.

Performance Validation of the ATLAS Muon Spectrometer

CERN Document Server

Mair, Katharina

ATLAS (A Toroidal LHC ApparatuS) is a general-purpose experiment for the future Large Hadron Collider (LHC) at CERN, which is scheduled to begin operation in the year 2007, providing experiments with proton-proton collisions. The center-of-mass energy of 14TeV and the design luminosity of 1034 cm−2s−1 will allow to explore many new aspects of fundamental physics. The ATLAS Muon Spectrometer aims at a momentum resolution better than 10% for transverse momentum values ranging from pT = 6 GeV to pT = 1TeV. Precision tracking will be performed by Ar-CO2-gas filled Monitored Drift Tube chambers (MDTs), with a single wire resolution of < 100 μm. In total, about 1 200 chambers, arranged in a large structure, will allow muon track measurements over distances up to 15m in a magnetic field of 0.5 T. Given the large size of the spectrometer it is impossible to keep the shape of the muon chambers and their positions stable within the requested tracking accuracy of 50 μm. Therefore the concept of an optical alig...

Proceedings of the 3rd workshop on balloon-borne experiments with superconducting magnet spectrometers

International Nuclear Information System (INIS)

Yamamoto, Akira

1992-04-01

The Third Work Shop on Balloon Borne Experiment with a Superconducting Magnet Spectrometer was held at National Laboratory for High Energy Physics (KEK), Tsukuba, Japan on February 24 - 25, 1992. The main effort for this workshop was focused on the progress of the BESS (Balloon Borne Experiment with a Superconducting Spectrometer) experiment and on the scope for scientific investigation with the BESS detector. The progress was reviewed and further investigation was discussed for the BESS further scientific collaboration among Univ. of Tokyo, Kobe University, KEK, ISAS and NMSU. (J.P.N.)

Calibration and intercomparison of neutron moderation spectrometers

International Nuclear Information System (INIS)

Rimpler, A.; Hermanska, J.; Prouza, Z.

1989-01-01

Results have been reported of comparative measurements of neutron fields from bare PuBe and Cf sources using multisphere (Bonner) spectrometers. The experiments were carried out by the Institute of Biophysics and Nuclear Medicine at Charles University in Prague and the National Board for Atomic Safety and Radiation Protection in Berlin. Both sides agreed upon uniform measuring conditions and calibration factors thus rendering possible the comparability of the dosimetric parameters which have been determined and verified, respectively, to an accuracy of ± 10%. 20 refs., 10 tabs., 2 figs. (author)

Mass spectrometer introduction line: application to the analysis of impurities in uranium hexafluoride

International Nuclear Information System (INIS)

Besson, M.

1967-01-01

The continuous mass-spectrometric analysis of impurities in UF 6 is possible industrially if certain conditions imposed by the nature of the gas are respected. The gas introduction line arriving at the spectrometer's source makes it possible to fix the flow-rate, to control the inlet pressure and to selectively destroy the gas containing the impurities. The operational conditions for the line are defined and a description is given of the theoretical and experimental study of the various elements of which it is composed, i.e. the leak valve, the flow-meter, the chemical trap and the servo-mechanism making it possible to regulate and control the gas flow. The dynamic characteristics of the line's various components and the performance of the equipment in the case of the analyses considered are given. (author) [fr

Development of a Submillimeter Multipass Spectrometer for the Study of Molecular Ions

Science.gov (United States)

Carroll, A.; Rocher, B.; Laas, J. C.; Deprince, B. A.; Hays, B.; Weaver, S. L. Widicus; Lang, S.

2012-06-01

We have developed a multipass spectrometer for the submillimeter spectral region that is being used to study molecular ions through gas phase spectroscopy. The optical configuration is based on the design of Perry and coworkers that was implemented in the optical regime. To our knowledge, this is the first implementation of this optical configuration at long wavelengths. The setup involves two nearly concentric spherical mirrors that focus the multiple beam passes into a small area, or ``waist'', in the middle of the sample chamber. A supersonic molecular beam is coupled to the setup so that the molecular beam crosses the optical path at the waist. Initial studies have focused on neutral test molecules to probe the physical properties of the molecular beam under various arrangements of the molecular source relative to the optical path. Current studies focus on coupling a plasma discharge source to the setup to enable the study of molecular ions. Here we present the design of this instrument, compare the spectrometer capabilities to a traditional single pass spectrometer, and discuss the results of initial spectroscopic studies.

Performance and robustness of a multi-user, multi-spectrometer system for INAA

International Nuclear Information System (INIS)

Peter Bode; Menno Blaauw

2012-01-01

The laboratory for instrumental neutron activation analysis at the Reactor Institute Delft, Delft University of Technology uses a network of 3 gamma-ray spectrometers with well-type detectors and 2 gamma-ray spectrometers with coaxial detectors, all equipped with modern sample changers, as well as 2 spectrometers with coaxial detectors at the two fast rabbit systems. A wide variety of samples is processed through the system, all at specific optimized (and thus different) analytical protocols, and using different combination of the spectrometer systems. The gamma-ray spectra are analyzed by several qualified operators. The laboratory therefore needs to anticipate on the occurrence of random and systematic inconsistencies in the results (such as bias, non-linearity or wrong assignments due to spectral interferences) resulting from differences in operator performance, selection of analytical protocol and experimental conditions. This has been accomplished by taking advantage of the systematic processing of internal quality control samples such as certified reference materials and blanks in each test run. The data from these internal quality control analyses have been stored in a databank since 1991, and are now used to assess the various method performance indicators as indicators for the method's robustness. (author)

Satellite-borne time-of-flight particle spectrometer and its response to protons

International Nuclear Information System (INIS)

Shino, T.

1994-01-01

One of the purposes of the high energy particle (HEP) experiment of the GEOTAIL satellite launched in 1992 is the elucidation of plasma dynamics in the tail region of planetary magnetosphere. For that purpose, a low energy particle detector (LD) was on board, which mainly observed relatively low energy particles up to a few MeV. The LD is the particle spectrometer based on time of flight technique. In order to confirm further its sensitivity to high energy protons, the beam experiment was carried out at Waseda University using the engineering model of the LD spectrometer that is exactly the same as the launched one. The LD spectrometer is shown, and its functions are explained. The LD was designed to identify electrons of 30 - 400 keV, protons of 30 - 1500 keV, helium ions of 80 - 4000 keV, and heavy ions (mainly C, N and O) of 160 - 1500 keV. The relation of measured time of flight signals with energy signals is shown. There are several factors that determine the detection efficiency of the spectrometer, which are discussed. The experiment and the results are reported. (K.I.)

Universe of constant

Science.gov (United States)

Yongquan, Han

2016-10-01

The ideal gas state equation is not applicable to ordinary gas, it should be applied to the Electromagnetic ``gas'' that is applied to the radiation, the radiation should be the ultimate state of matter changes or initial state, the universe is filled with radiation. That is, the ideal gas equation of state is suitable for the Singular point and the universe. Maybe someone consider that, there is no vessel can accommodate radiation, it is because the Ordinary container is too small to accommodate, if the radius of your container is the distance that Light through an hour, would you still think it can't accommodates radiation? Modern scientific determinate that the radius of the universe now is about 1027 m, assuming that the universe is a sphere whose volume is approximately: V = 4.19 × 1081 cubic meters, the temperature radiation of the universe (cosmic microwave background radiation temperature of the universe, should be the closest the average temperature of the universe) T = 3.15k, radiation pressure P = 5 × 10-6 N / m 2, according to the law of ideal gas state equation, PV / T = constant = 6 × 1075, the value of this constant is the universe, The singular point should also equal to the constant Author: hanyongquan

[Determination of sodium, magnesium, calcium, lithium and strontium in natural mineral drinking water by microwave plasma torch spectrometer with nebulization sample introduction system].

Science.gov (United States)

Zhou, Wei; Xiong, Hai-long; Feng, Guo-dong; Yu, Ai-min; Chen, Huan-wen

2014-06-01

The microwave plasma torch (MPT) was used as the emission light source. Aqueous samples were introduced with a nebulizer and a desolvation system. A method for the determination of Na, Mg, Ca, Li and Sr in natural mineral drinking water by argon microwave plasma torch spectrometer (ArMPT spectrometer) was established. The effects of microwave power, flow rate of carrier gas and support gas were investigated in detail and these parameters were optimized. Under the optimized condition, the experiments for the determination of Na, Mg, Ca, Li and Sr in 11 kinds of bottled mineral drinking water were carried out by ArMPT spectrometer. The limit-of-detection (LOD) of Na, Mg, Ca, Li and Sr was found to be 4.4, 21, 56, 11 and 84 μg x mL(-1), respectively. Relative standard deviation (n = 6) was in the range of 1.30%-5.45% and standard addition recoveries were in the range of 84.6%-98.5%. MPT spectrometer was simpler, more convenient and of lower cost as compared to ICP unit. MPT spectrometer demonstrated its rapid analysis speed, accuracy, sensitivity and simultaneous multi element analysis ability during the analysis process. The results showed that MPT spectrometer was suitable for metal elements detection for natural mineral drinking water. This approach provides not only one way for resisting the illegal dealings, but also a security for the quality of drinking water. Moreover, the usability of MPT spectrometer in the field of food security; drug safety; clinical diagnostic is promised.

Acquisition of HPLC-Mass Spectrometer

Science.gov (United States)

2015-08-18

31-Jan-2015 Approved for Public Release; Distribution Unlimited Final Report: Acquisition of HPLC -Mass Spectrometer The views, opinions and/or findings...published in peer-reviewed journals: Final Report: Acquisition of HPLC -Mass Spectrometer Report Title The acquisition of the mass spectrometer has been a

Associated Particle Tagging (APT) in Magnetic Spectrometers

Energy Technology Data Exchange (ETDEWEB)

Jordan, David V.; Baciak, James E.; Stave, Sean C.; Chichester, David; Dale, Daniel; Kim, Yujong; Harmon, Frank

2012-10-16

Summary In Brief The Associated Particle Tagging (APT) project, a collaboration of Pacific Northwest National Laboratory (PNNL), Idaho National Laboratory (INL) and the Idaho State University (ISU)/Idaho Accelerator Center (IAC), has completed an exploratory study to assess the role of magnetic spectrometers as the linchpin technology in next-generation tagged-neutron and tagged-photon active interrogation (AI). The computational study considered two principle concepts: (1) the application of a solenoidal alpha-particle spectrometer to a next-generation, large-emittance neutron generator for use in the associated particle imaging technique, and (2) the application of tagged photon beams to the detection of fissile material via active interrogation. In both cases, a magnetic spectrometer momentum-analyzes charged particles (in the neutron case, alpha particles accompanying neutron generation in the D-T reaction; in the tagged photon case, post-bremsstrahlung electrons) to define kinematic properties of the relevant neutral interrogation probe particle (i.e. neutron or photon). The main conclusions of the study can be briefly summarized as follows: Neutron generator: • For the solenoidal spectrometer concept, magnetic field strengths of order 1 Tesla or greater are required to keep the transverse size of the spectrometer smaller than 1 meter. The notional magnetic spectrometer design evaluated in this feasibility study uses a 5-T magnetic field and a borehole radius of 18 cm. • The design shows a potential for 4.5 Sr tagged neutron solid angle, a factor of 4.5 larger than achievable with current API neutron-generator designs. • The potential angular resolution for such a tagged neutron beam can be less than 0.5o for modest Si-detector position resolution (3 mm). Further improvement in angular resolution can be made by using Si-detectors with better position resolution. • The report documents several features of a notional generator design incorporating the

Fourier Transform Spectrometer System

Science.gov (United States)

Campbell, Joel F. (Inventor)

2014-01-01

A Fourier transform spectrometer (FTS) data acquisition system includes an FTS spectrometer that receives a spectral signal and a laser signal. The system further includes a wideband detector, which is in communication with the FTS spectrometer and receives the spectral signal and laser signal from the FTS spectrometer. The wideband detector produces a composite signal comprising the laser signal and the spectral signal. The system further comprises a converter in communication with the wideband detector to receive and digitize the composite signal. The system further includes a signal processing unit that receives the composite signal from the converter. The signal processing unit further filters the laser signal and the spectral signal from the composite signal and demodulates the laser signal, to produce velocity corrected spectral data.

Development of a collision induced dissociation ion cyclotron resonance spectrometer

International Nuclear Information System (INIS)

Fan, Y.N.

1982-01-01

A transient analysis ion cyclotron resonance spectrometer is developed to investigate the phenomena of collision induced dissociation. The Fourier transform method and the modified maximum entropy spectral analysis or covariance least square method are implemented in measuring the mass spectrum of the ion ensemble. The Fourier transform method can be used in quantitative analysis while the maximum entropy method as developed here is useful for qualitative analysis only. The cyclotron resonance frequency, relaxation time constant, and the relative ion population are observable from the Fourier transform spectrum. These parameters are very important in investigating collision induced dissociation process and other topics in gas phase chemistry. The ion cyclotron resonance spectrometer is not only developed to study fragments and their abundance from a parent ion, but also to determine the threshold energy and reaction cross section in the collision induced dissociation process. When hard sphere model is used in the ion-molecule collision, the radius of acetone ion measured from the reactive cross section is 2.2 angstrom which is very close to the physical dimension of acetone. The threshold energy for acetone ion in collision induced dissociation process is 1.8 eV which is similar to the result obtained by the angle-resolved mass spectrometer

Determining plasma-fueling sources with an end-loss ion spectrometer

International Nuclear Information System (INIS)

Grubb, D.P.; Foote, J.H.

1986-01-01

To help identify the major sources of fueling gas in Tandem Mirror Experiment-Upgrade (TMX-U), we mounted a mass-sensitive, E parallel to B, end-loss ion spectrometer (ELIS) near the machine's centerline. We set the electric field in the ELIS to simultaneously measure the axial loss currents of both hydrogen and deuterium. We then initiated plasma discharges, where we injected either hydrogen or deuterium gas into the central cell. We also selected and deselected the central-cell neutral beams that were fueled with hydrogen gas. The end-cell neutral beams were always selected and fueled with deuterium. By taking the ratio of the hydrogen end-loss current to the deuterium end-loss current (with a known deuterium-gas feed rate), we were able to infer the effective fueling rates that were due to wall reflux, central-cell beams, and end-cell beams. The results were the following: wall reflux, 6 Torr.l/s; central-cell beams, 15 Torr.l/s; and end-cell beams 1 Torr.l/s. 3 refs., 3 figs., 1 tab

Taiwan university joins search for antimatter

CERN Multimedia

Chiu, Y

2002-01-01

National Cheng Kung University announced yesterday that it will be joining the Alpha Magnetic Spectrometer, an international scientific research project aimed at looking for antimatter in space (1 page).

The University of Colorado OSO-8 spectrometer experiment. IV - Mission operations

Science.gov (United States)

Hansen, E. R.; Bruner, E. C., Jr.

1979-01-01

The remote operation of two high-resolution ultraviolet spectrometers on the OSO-8 satellite is discussed. Mission operations enabled scientific observers to plan observations based on current solar data, interact with the observing program using real- or near real-time data and commands, evaluate quick-look instrument data, and analyze the observations for publication. During routine operations, experiments were planned a day prior to their execution, and the data from these experiments received a day later. When a shorter turnaround was required, a real-time mode was available. Here, the real-time data and command links into the remote control center were used to evaluate experiment operation and make satellite pointing or instrument configuration changes with a 1-90 minute turnaround.

Digital positron annihilation spectrometer

International Nuclear Information System (INIS)

Cheng Bin; Weng Huimin; Han Rongdian; Ye Bangjiao

2010-01-01

With the high speed development of digital signal process, the technique of the digitization and processing of signals was applied in the domain of a broad class of nuclear technique. The development of digital positron lifetime spectrometer (DPLS) is more promising than the conventional positron lifetime spectrometer equipped with nuclear instrument modules. And digital lifetime spectrometer has many advantages, such as low noise, long term stability, flexible online or offline digital processing, simple setup, low expense, easy to setting, and more physical information. Digital constant fraction discrimination is for timing. And a new method of optimizing energy windows setting for digital positron lifetime spectrometer is also developed employing the simulated annealing for the convenient use. The time resolution is 220ps and the count rate is 200cps. (authors)

MEOS Microsatellite Earth Observation using Miniature Integrated-Optic IR Spectrometers

Science.gov (United States)

Kruzelecky, Roman

future, the MEOS Miniature Earth Observing Satellite will innovatively combine remote atmospheric/land-cover measurements with ecosystem modelling in near real-time to obtain simultaneous variations in lower tropospheric GHG mixing ratios and the resulting responses of surface ecosystems. MEOS will provide lower tropospheric CO2 , CH4 , CO, N2 O, H2 O and aerosol mixing ratios over natural sources and sinks using two kinds of synergistic observations; a forward limb measurement and a follow-on nadir measurement over the same geographical tangent point. The measurements will be accomplished using separate limb and nadir suites of miniature lineimaging spectrometers and will be spatially coordinated such that the same air mass is observed in both views within a few minutes. The limb data will consist of 16-pixel vertical spectral line imaging to provide 2.5-km vertical resolution, while the corresponding nadir measurements will view sixteen 5 by 10 km2 ground pixels with a 160-km East-West swath width. The separate limb and nadir instrument suites each feature two complementary NIR miniature spectrometers that will operate in parallel, alternating the collected optical signal between the high-resolution Fabry-Perot guided-wave FP-IOSPEC spectrometer with simultaneous multiple microchannels at 0.03 FWHM with SNR>400 and the 1220 to 2450 nm broad-band spectrometer with 1.2 nm FWHM such that one undergoes the illuminated segment of the processing while the other spectrometer undergoes its dark signal processing. This spectral region provides several harmonic optical absorption bands associated with CO2 , CH4 , CO, H2 O and N2 O. The innovative data synergy of the coarse resolution broad-band spectra with the scanned spectral measurements of the trace-gas fine features at 0.03 nm FWHM in multiple microchannels will be used to improve the accuracy of the trace gas retrievals relative to current missions. In addition, the mission will retrieve cloud top pressures to better than

Scalar perturbations in the late Universe: viability of the Chaplygin gas models

Energy Technology Data Exchange (ETDEWEB)

Bouhmadi-López, Mariam [Departamento de Física, Universidade da Beira Interior, 6200 Covilhã (Portugal); Brilenkov, Maxim; Brilenkov, Ruslan [Department of Theoretical Physics, Odessa National University, Dvoryanskaya st. 2, Odessa 65082 (Ukraine); Morais, João [Department of Theoretical Physics, University of the Basque Country UPV/EHU, P.O. Box 644, 48080 Bilbao (Spain); Zhuk, Alexander, E-mail: mbl@ubi.pt, E-mail: maxim.brilenkov@gmail.com, E-mail: ruslan.brilenkov@gmail.com, E-mail: jviegas001@ikasle.ehu.eus, E-mail: ai.zhuk2@gmail.com [Astronomical Observatory, Odessa National University, Dvoryanskaya st. 2, Odessa 65082 (Ukraine)

2015-12-01

We study the late-time evolution of the Universe where dark energy (DE) is parametrised by a modified generalised Chaplygin gas (mGCG) on top of cold dark matter (CDM) . We also take into account the radiation content of the Universe. In this context, the late stage of the evolution of the universe refers to the epoch where CDM is already clustered into inhomogeneously distributed discrete structures (galaxies, groups and clusters of galaxies). Under these conditions, the mechanical approach is an adequate tool to study the Universe deep inside the cell of uniformity. To be more accurate, we study scalar perturbations of the Friedmann-Lemaȋtre-Robertson-Walker metric due to inhomogeneities of CDM as well as fluctuations of radiation and mGCG, the later driving the late-time acceleration of the universe. Our analysis applies as well to the case where mGCG plays the role of DM and DE . We select the sets of parameters of the mGCG that are compatible with the mechanical approach. These sets define prospective mGCG models. By comparing the selected sets of models with some of the latest observational data results, we conclude that the mGCG is in tight agreement with those observations particularly for a mGCG playing the role of DE and DM.

Simulation of the SAGE spectrometer

Energy Technology Data Exchange (ETDEWEB)

Cox, D.M.; Herzberg, R.D. [University of Liverpool, Department of Physics, Oliver Lodge Laboratory, Liverpool (United Kingdom); Konki, J.; Greenlees, P.T.; Pakarinen, J.; Papadakis, P.; Rahkila, P.; Sandzelius, M.; Sorri, J. [University of Jyvaeskylae, Department of Physics, Jyvaeskylae (Finland); Hauschild, K. [Universite Paris-Sud, CSNSM-IN2P3-CNRS, Orsay (France)

2015-06-15

The SAGE spectrometer combines a Ge-detector array with a Si detector to allow simultaneous detection of γ-rays and electrons. A comprehensive GEANT4 simulation package of the SAGE spectrometer has been developed with the ability to simulate the expected datasets based on user input files. The measured performance of the spectrometer is compared to the results obtained from the simulations. (orig.)

Simulation of the SAGE spectrometer

International Nuclear Information System (INIS)

Cox, D.M.; Herzberg, R.D.; Konki, J.; Greenlees, P.T.; Pakarinen, J.; Papadakis, P.; Rahkila, P.; Sandzelius, M.; Sorri, J.; Hauschild, K.

2015-01-01

The SAGE spectrometer combines a Ge-detector array with a Si detector to allow simultaneous detection of γ-rays and electrons. A comprehensive GEANT4 simulation package of the SAGE spectrometer has been developed with the ability to simulate the expected datasets based on user input files. The measured performance of the spectrometer is compared to the results obtained from the simulations. (orig.)

Environmental Technology Verification Report. Field Portable Gas Chromatograph/Mass Spectrometer. Viking Instruments Corporation SpectraTrak (Trademark) 672

National Research Council Canada - National Science Library

Enfield, Wayne

1997-01-01

.... This self-contained, field transportable system, whose design has been adapted from laboratory technology, uses a contained, chromatographic column and accompanying mass spectrometer to provide...

Ground based mid-IR heterodyne spectrometer concept for planetary atmospheres observations

Science.gov (United States)

Garamov, V.; Benderov, O.; Semenov, V.; Spiridonov, M.; Rodin, A.; Stepanov, B.

2017-09-01

We present a heterodyne spectrometer concept based on distributed feedback (DFB) quantum cascade lasers (QCL) operated in midle infrared region (MIR). The instrument is assumed to be mount on the Russian infrared observatories. The core features of the concept are compact design, utilizing a novel mid-IR fiber optical components and dynamic local oscillator frequency locking using reference molecule absorption line. The instrument characteristics are similar to modern heterodyne devices THIS (Cologne University, Germany) and MILAHI (Tohoku University, Japan) in terms of fundamental parameters, including spectral resolution, spectral coverage in a single observation. At present moment we created laboratory setup including all necessary elements of MIR heterodyne spectrometer. We have studied different components of noises of our system and found optimal value of LO power. The measured signal to noise ratio (SNR) with MCT PD was about 10 times greater than LO's shot noise (theoretical limit of heterodyne technique SNR) and limited by QCL relative intensity noise (RIN). However, applying additional filtering it is possible to reduce this value better than 5 shot noise level, which is typical to TEC cooled MCT PD. Also we demonstrate heterodyne signal measurements using laboratory black body with temperature of 400 oC.

Chirped Pulse Spectrometer Operating at 200 GHz

Science.gov (United States)

Hindle, Francis; Bray, Cédric; Hickson, Kevin; Fontanari, Daniele; Mouelhi, Meriem; Cuisset, Arnaud; Mouret, Gaël; Bocquet, Robin

2018-01-01

The combination of electronic sources operating at high frequencies and modern microwave instrumentation has enabled the recent development of chirped pulse spectrometers for the millimetre and THz bands. This type of instrument can operate at high resolution which is particularly suited to gas-phase rotational spectroscopy. The construction of a chirped pulse spectrometer operating at 200 GHz is described in detail while attention is paid to the phase stability and the data accumulation over many cycles. Validation using carbonyl sulphide has allowed the detection limit of the instrument to be established as function of the accumulation. A large number of OCS transitions were identified using a 10-GHz chirped pulse and include the six most abundant isotopologues, the weakest line corresponding to the fundamental R(17) transition of 16O13C33S with a line strength of 4.3 × 10-26 cm-1/(molecule cm-2). The linearity of the system response for different degrees of data accumulation and transition line strength was confirmed over four orders of magnitudes. A simple analysis of the time-domain data was demonstrated to provide the line-broadening coefficient without the need for conversion by a Fourier transform. Finally, the pulse duration is discussed and optimal values are given for both Doppler-limited and collisional regimes.

A mass spectrometer for the rapid analysis of gaseous mixtures

International Nuclear Information System (INIS)

Cassignol, C.; Ortel, Y.; Taieb, J.

1950-01-01

A mass spectrometer for leak detection and rapid gas analysis were constructed, having the characteristics and several structural features of a simple instrument described by Siry in Rev. Sri. Instruments. 540 (1947). Although exhibiting a good resolving power, the apparatus, which has no ion lenses and whose electrodes can be regulated during the performance, has not been sufficiently tested. Since several design defects have been discovered, it will probably be rebuilt with various improvements (ion source outside the magnetic field, modified circuits, etc.). (author)

Knowing what we breathe: Sentinel 4: a geostationary imaging UVN spectrometer for air quality monitoring

Science.gov (United States)

Bazalgette Courrèges-Lacoste, G.; Sallusti, M.; Bulsa, G.; Bagnasco, G.; Gulde, S.; Kolm, M. G.; Smith, D. J.; Maurer, R.

2017-09-01

Sentinel-4 is an imaging UVN (UV-VIS-NIR) spectrometer, developed by Airbus DS under ESA contract in the frame of the joint EU/ESA COPERNICUS program. The mission objective is the operational monitoring of trace gas concentrations for atmospheric chemistry and climate applications - hence the motto of Sentinel-4 "Knowing what we breathe".

Scientific Payload Of The Emirates Mars Mission: Emirates Mars Infrared Spectrometer (Emirs) Overview.

Science.gov (United States)

Altunaiji, E. S.; Edwards, C. S.; Christensen, P. R.; Smith, M. D.; Badri, K. M., Sr.

2017-12-01

The Emirates Mars Mission (EMM) will launch in 2020 to explore the dynamics in the atmosphere of Mars on a global scale. EMM has three scientific instruments to an improved understanding of circulation and weather in the Martian lower and middle atmosphere. Two of the EMM's instruments, which are the Emirates eXploration Imager (EXI) and Emirates Mars Infrared Spectrometer (EMIRS) will focus on the lower atmosphere observing dust, ice clouds, water vapor and ozone. On the other hand, the third instrument Emirates Mars Ultraviolet Spectrometer (EMUS) will focus on both the thermosphere of the planet and its exosphere. The EMIRS instrument, shown in Figure 1, is an interferometric thermal infrared spectrometer that is jointly developed by Arizona State University (ASU) and Mohammed Bin Rashid Space Centre (MBRSC). It builds on a long heritage of thermal infrared spectrometers designed, built, and managed, by ASU's Mars Space Flight Facility, including the Thermal Emission Spectrometer (TES), Miniature Thermal Emission Spectrometer (Mini-TES), and the OSIRIS-REx Thermal Emission Spectrometer (OTES). EMIRS operates in the 6-40+ µm range with 5 cm-1 spectral sampling, enabled by a Chemical Vapor-Deposited (CVD) diamond beamsplitter and state of the art electronics. This instrument utilizes a 3×3 detector array and a scan mirror to make high-precision infrared radiance measurements over most of a Martian hemisphere. The EMIRS instrument is optimized to capture the integrated, lower-middle atmosphere dynamics over a Martian hemisphere and will capture 60 global images per week ( 20 images per orbit) at a resolution of 100-300 km/pixel. After processing through an atmospheric retrieval algorithm, EMIRS will determine the vertical temperature profiles to 50km altitude and measure the column integrated global distribution and abundances of key atmospheric parameters (e.g. dust, water ice (clouds) and water vapor) over the Martian day, seasons and year.

The MEG positron spectrometer

International Nuclear Information System (INIS)

Nishiguchi, Hajime

2007-01-01

We have been developing an innovative spectrometer for the MEG experiment at the Paul Scherrer Institute (PSI) in Switzerland. This experiment searches for a lepton flavour violating decay μ + →e + γ with a sensitivity of 10 -13 in order to explore the region predicted by supersymmetric extensions of the standard model. The MEG positron spectrometer consists of a specially designed superconducting solenoidal magnet with a highly graded field, an ultimate low-mass drift chamber system, and a precise time measuring counter system. This innovative positron spectrometer is described here focusing on the drift chamber system

Field-portable Gas Chromatograph Mass Spectrometer (GC-MS) Unit for Semi-volatile Compound Analysis in Groundwater

Science.gov (United States)

2011-09-01

the need for a convective oven, greatly reducing the size and power consumption compared to standard GC systems. These modifications to the...spectrometer. In Harsh Environment Mass Spectrometry (HEMS) Conference; September 2007; Cocoa Beach, FL. Science Applications International Corporation

Electronics for processing of data from a double collector isotopic ratio mass spectrometer

International Nuclear Information System (INIS)

Handu, V.K.

1979-01-01

The output data available from the mass spectrometer type MS-660 developed in the mass spectrometry section of Technical Physics Division of the Bhabha Atomic Research Centre, Bombay, for the determination of H/D ratios in liquid/gas sample consist of uncompensated mass 3 and mass 2 signals. After the mass 3 signal has been compensated for H 3 + formation, the on-line ratio of compensated mass 3 to mass 2 is calculated, displayed, and then printed on a printer for record. The electronic compensation circuit, the discrete voltage-to-frequency (V/F) converter circuit, the ratio calculating system using V/F converters, and a digital interface system for Hindustan Teleprinter to print out the ratios are explained. Results obtained on mass spectrometer MS-660 are presented. (auth.)

Frequency-scanning MALDI linear ion trap mass spectrometer for large biomolecular ion detection.

Science.gov (United States)

Lu, I-Chung; Lin, Jung Lee; Lai, Szu-Hsueh; Chen, Chung-Hsuan

2011-11-01

This study presents the first report on the development of a matrix-assisted laser desorption ionization (MALDI) linear ion trap mass spectrometer for large biomolecular ion detection by frequency scan. We designed, installed, and tested this radio frequency (RF) scan linear ion trap mass spectrometer and its associated electronics to dramatically extend the mass region to be detected. The RF circuit can be adjusted from 300 to 10 kHz with a set of operation amplifiers. To trap the ions produced by MALDI, a high pressure of helium buffer gas was employed to quench extra kinetic energy of the heavy ions produced by MALDI. The successful detection of the singly charged secretory immunoglobulin A ions indicates that the detectable mass-to-charge ratio (m/z) of this system can reach ~385 000 or beyond.

Development and optimization of a high temperature coupling system thermoanalyzer/mass spectrometer

International Nuclear Information System (INIS)

Jagdfeld, H.J.

1983-11-01

The development of a high temperature coupling system was accomplished to carry out thermodynamic investigations during glass melting to solidify highly radioactive fission products into glass at a temperature up to 1200 0 C. The actual problem consisted of the fact that the gas species evaporating from the melter have to pass without condensation or without change of their composition a multistage pressure reducing system to enter the analysator unit of the mass spectrometer in the high vacuum. With the systems, offered at present, this is only possible up to approximately 450 0 C. The development of a new high temperature coupling included investigations of the gas dynamics, raw materials and thermic behaviour. (orig./EF) [de

Magnetic spectrometer Grand Raiden

International Nuclear Information System (INIS)

Fujiwara, M.; Akimune, H.; Daito, I.; Fujimura, H.; Fujita, Y.; Hatanaka, K.; Ikegami, H.; Katayama, I.; Nagayama, K.; Matsuoka, N.; Morinobu, S.; Noro, T.; Yoshimura, M.; Sakaguchi, H.; Sakemi, Y.; Tamii, A.; Yosoi, M.

1999-01-01

A high-resolution magnetic spectrometer called 'Grand Raiden' is operated at the RCNP ring cyclotron facility in Osaka for nuclear physics studies at intermediate energies. This magnetic spectrometer has excellent ion-optical properties. In the design of the spectrometer, the second-order dispersion matching condition has been taken into account, and almost all the aberration terms such as (x vertical bar θ 3 ), (x vertical bar θφ 2 ), (x vertical bar θ 2 δ) and (x vertical bar θδ 2 ) in a third-order matrix calculation are optimized. A large magnetic rigidity of the spectrometer (K = 1400 MeV) gives a great advantage to measure the charge-exchange ( 3 He, t) reactions at 450 MeV. The ability of the high-resolution measurement has been demonstrated. Various coincidence measurements are performed to study the nuclear structures of highly excited states through decay properties of nuclear levels following nuclear reactions at intermediate energies

A novel method for producing multiple ionization of noble gas

International Nuclear Information System (INIS)

Wang Li; Li Haiyang; Dai Dongxu; Bai Jiling; Lu Richang

1997-01-01

We introduce a novel method for producing multiple ionization of He, Ne, Ar, Kr and Xe. A nanosecond pulsed electron beam with large number density, which could be energy-controlled, was produced by incidence a focused 308 nm laser beam onto a stainless steel grid. On Time-of-Flight Mass Spectrometer, using this electron beam, we obtained multiple ionization of noble gas He, Ne, Ar and Xe. Time of fight mass spectra of these ions were given out. These ions were supposed to be produced by step by step ionization of the gas atoms by electron beam impact. This method may be used as a ideal soft ionizing point ion source in Time of Flight Mass Spectrometer

RITA-type triple axis spectrometers

International Nuclear Information System (INIS)

Roennow, H.M.

2001-01-01

The RITA spectrometer at Risoe National Laboratory was the first to incorporate a complete re-thinking of the neutron-path from source, through detector to analysis. Since then, other RITA-type spectrometers such as SPINS at NIST, RITA-II at PSI have been built, and several new spectrometers around the world are adapting the same philosophy. The main novelty of RITA was the introduction of a single back-end tank featuring both an analyser block with multiple individually turnable analyser blades and a 2D position sensitive detector. Several new triple-axis spectrometers are presently being built at existing and future sources, and almost all of them have learnt from the experience with RITA. (R.P.)

Dual liquid and gas chromatograph system

Science.gov (United States)

Gay, D.D.

A chromatographic system is described that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a nontransparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extreme low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

Direct observations of Biogenic Volatile Organic Compound (BVOC) Air-Sea Exchange in the remote North Atlantic from the High-Wind Gas-Exchange Study (HiWinGS)

Science.gov (United States)

Kim, M.; Yang, M. X.; Blomquist, B.; Huebert, B. J.; Bertram, T. H.

2014-12-01

Biogenic Volatile Organic Compounds (BVOCs) are reactive trace gases that impact both chemistry and climate by regulating oxidant loadings, determining secondary organic aerosol production rates as well as altering particle hygroscopicity. While continental BVOC exchange rates are well studied, global marine flux estimates are poorly constrained. In Fall 2013, a chemical-ionization time-of-flight mass spectrometer (CI-ToF-MS) utilizing benzene cations was deployed as part of the High Wind Gas Exchange Study (HiWinGs) to quantify monoterpenes, isoprene and dimethylsulfide fluxes in the remote North Atlantic. Dimethylsulfide measurements are in strong agreement with those determined by the University of Hawaii's atmospheric pressure ionization mass-spectrometer. In the remote marine boundary layer, positive monoterpene fluxes (i.e. emissions) were observed while isoprene levels rarely exceeded the detection limit.

Data processing for elliptical crystal spectrometer used in Z-pinch diagnostic

International Nuclear Information System (INIS)

Li Jing; Xie Weiping; Huang Xianbin; Yang Libing; Cai Hongchun; Xiao Shali

2010-01-01

Elliptical crystal spectrometers are key instruments to detect the line spectra of soft X-rays in Z-pinch diagnostics. This paper deals with the data processing for an elliptical crystal spectrometer. Taking the diagnostic results obtained in a neon gas-puff Z-pinch experiment as an example, the detailed processes, such as changing the optical density to X-ray intensity according a calibrated film response curve, determining the X-ray energy of the measured spectrum using the energy and the order number of scanned point of identified spectral lines, and correcting the intensity of spectrum using the formula given by Henke are discussed. In the Henke's formula, the effect of nonuniform dispersion, integrated reflectivity of crystals and transmission of X-ray filters are considered. The final unfolding results are presented, including the relative intensities of several neon K-shell lines (H α , He α and He β , etc.) given by Lorentz fitting. The relative errors of the spectral intensities are also briefly discussed. (authors)

Customized altitude-azimuth mount for a raster-scanning Fourier transform spectrometer

Science.gov (United States)

Durrenberger, Jed E.; Gutman, William M.; Gammill, Troy D.; Grover, Dennis H.

1996-10-01

Applications of the Army Research Laboratory Mobile Atmospheric Spectrometer Remote Sensing Rover required development of a customized computer-controlled mount to satisfy a variety of requirements within a limited budget. The payload was designed to operate atop a military electronics shelter mounted on a 4-wheel drive truck to be above most atmospheric ground turbulence. Pointing orientation in altitude is limited by constraints imposed by use of a liquid nitrogen detector Dewar in the spectrometer. Stepper motor drives and control system are compatible with existing custom software used with other instrumentation for controlled incremental raster stepping. The altitude axis passes close to the center of gravity of the complete payload to minimize load eccentricity and drive torque requirements. Dovetail fixture mounting enables quick service and fine adjustment of balance to minimize stepper/gearbox drive backlash through the limited orientation range in altitude. Initial applications to characterization of remote gas plumes have been successful.

ComPAQS: a compact concentric UV/visible spectrometer, providing a new tool for air quality monitoring from space

Science.gov (United States)

Leigh, Roland J.; Whyte, C.; Cutter, M. A.; Lobb, D. R.; Monks, P. S.

2017-11-01

Under the first phase of the Centre for Earth Observation Instrumentation (CEOI), a breadboard demonstrator of a novel UV/VIS spectrometer has been developed. Using designs from Surrey Satellite Technology Ltd (SSTL) the demonstrator has been constructed and tested at the University of Leicester's Space Research Centre. This spectrometer provides an exceptionally compact instrument for differential optical absorption spectroscopy (DOAS) applications from LEO, GEO, HAP or ground-based platforms. Measurement of atmo spheric compounds with climate change or air quality implications is a key driver for the ground and space-based Earth Observation communities. Techniques using UV/VIS spectroscopy such as DOAS provide measurements of ozone profiles, aerosol optical depth, certain Volatile Organic Compounds, halogenated species, and key air quality parameters including tropospheric nitrogen dioxide. Compact instruments providing the necessary optical performance and spectral resolution are therefore a key enabling technology. The Compact Air Quality Spectrometer (CompAQS) features a concentric arrangement of a spherical meniscus lens, a concave spherical mirror and a suitable curved diffraction grating. This compact design provides efficiency and performance benefits over traditional concepts, improving the precision and spatial resolution available from space borne instruments with limited weight and size budgets. The breadboard spectrometer currently operating at the University of Leicester offers high throughput with a spectral range from 310 to 450 nm at 0.5nm(UV) to 1.0nm (visible) resolution, suitable for DOAS applications. The concentric design is capable of handling high relative apertures, owing to spherical aberration and coma being near zero at all surfaces. The design also provides correction for transverse chromatic aberration and distortion, in addition to correcting for the distortion called `smile' - the curvature of the slit image formed at each

The Performance of CO2 Laser Photoacoustic Spectrometer In Concentration Acetone Detection As Biomarker For Diabetes Mellitus Type 2

Science.gov (United States)

Tyas, F. H.; Nikita, J. G.; Apriyanto, D. K.; Mitrayana; Amin, M. N.

2018-04-01

Breath analysis is useful for the diagnosis of human diseases and monitoring of metabolic status. However, because of the low concentrations and the large numbers of compounds in the breath, the breath analysis requires highly sensitive and highly selective instruments to identify and determine the concentrations of certain biomarkers [1]. Various methods developed over the past 20 years to detect biomarker gases [2]. CO2 laser photoacoustic spectroscopy offers a sensitive technique for the detection and monitoring of gas footprints at low concentrations [3]. The performance of photoacoustic spectrometer (PAS) examined with intracavity configuration. In this research, the highest observed intracavity power was (49,96 ± 0,02) W for active medium gas composition He: N2: CO2 at 30:50:50. The highest laser absorption line for standard acetone gas set at 10P20, and the lowest detection limit set at (30 ± 4) ppb. For application purposes, the photoacoustic spectrometer was used to measure the concentration of acetone gas in exhaled gases from a group of patients with type 2 diabetes mellitus and a group of healthy volunteers. Exhaled gas sampling method took manually, and the measurement result was examined using multicomponent analysis. The measurement showed that the highest acetone gas concentration for type 2 diabetes mellitus patients was (162 ± 3) × 10 ppb and the lowest one was (101 ± 3) × 10 ppb. Furthermore, for healthy volunteers, the highest acetone gas concentration was (85 ± 3) × 10 ppb and the lowest one was (15 ± 3) × 10 ppb.

Software for mass spectrometer control

International Nuclear Information System (INIS)

Curuia, Marian; Culcer, Mihai; Anghel, Mihai; Iliescu, Mariana; Trancota, Dan; Kaucsar, Martin; Oprea, Cristiana

2004-01-01

The paper describes a software application for the MAT 250 mass spectrometer control, which was refurbished. The spectrometer was bring-up-to-date using a hardware structure on its support where the software application for mass spectrometer control was developed . The software application is composed of dedicated modules that perform given operations. The instructions that these modules have to perform are generated by a principal module. This module makes possible the change of information between the modules that compose the software application. The use of a modal structure is useful for adding new functions in the future. The developed application in our institute made possible the transformation of the mass spectrometer MAT 250 into a device endowed with other new generation tools. (authors)

Mass spectrometers in medicine

International Nuclear Information System (INIS)

Bushman, J.A.

1975-01-01

This paper describes how the mass spectrometer enables true lung function, namely the exchange of gases between the environment and the organism, to be measured. This has greatly improved the understanding of respiratory disease and the latest generation of respiratory mass spectrometers will do much to increase the application of the technique. (author)

Tests of the space gamma spectrometer prototype at the JINR experimental facility with different types of neutron generators

Science.gov (United States)

Litvak, M. L.; Vostrukhin, A. A.; Golovin, D. V.; Dubasov, P. V.; Zontikov, A. O.; Kozyrev, A. S.; Krylov, A. R.; Krylov, V. A.; Mitrofanov, I. G.; Mokrousov, M. I.; Repkin, A. N.; Timoshenko, G. N.; Udovichenko, K. V.; Shvetsov, V. N.

2017-07-01

The results of the tests of the HPGe gamma spectrometer performed with a planetary soil model and different types of pulse neutron generators are presented. All measurements have been performed at the experimental nuclear planetary science facility (Joint Institute for Nuclear Research) for the physical calibration of active gamma and neutron spectrometers. The aim of the study is to model a space experiment on determining the elemental composition of Martian planetary matter by neutron-induced gamma spectroscopy. The advantages and disadvantages of a gas-filled neutron generator in comparison with a vacuum-tube neutron generator are examined.

spectrometer

Directory of Open Access Journals (Sweden)

J. K. Hedelius

2016-08-01

Full Text Available Bruker™ EM27/SUN instruments are commercial mobile solar-viewing near-IR spectrometers. They show promise for expanding the global density of atmospheric column measurements of greenhouse gases and are being marketed for such applications. They have been shown to measure the same variations of atmospheric gases within a day as the high-resolution spectrometers of the Total Carbon Column Observing Network (TCCON. However, there is little known about the long-term precision and uncertainty budgets of EM27/SUN measurements. In this study, which includes a comparison of 186 measurement days spanning 11 months, we note that atmospheric variations of Xgas within a single day are well captured by these low-resolution instruments, but over several months, the measurements drift noticeably. We present comparisons between EM27/SUN instruments and the TCCON using GGG as the retrieval algorithm. In addition, we perform several tests to evaluate the robustness of the performance and determine the largest sources of errors from these spectrometers. We include comparisons of XCO2, XCH4, XCO, and XN2O. Specifically we note EM27/SUN biases for January 2015 of 0.03, 0.75, –0.12, and 2.43 % for XCO2, XCH4, XCO, and XN2O respectively, with 1σ running precisions of 0.08 and 0.06 % for XCO2 and XCH4 from measurements in Pasadena. We also identify significant error caused by nonlinear sensitivity when using an extended spectral range detector used to measure CO and N2O.

Procedure and apparatus for controlling the ion energy in a mass spectrometer

Energy Technology Data Exchange (ETDEWEB)

Fies, W J; Reeher, J R; Story, M S; Smith, R D

1977-03-03

The invention relates to a process and apparatus for adjusting the energy of ions of different masses in a mass spectrometer. Specifically, it concerns a mass spectrometer having a gas inlet and ionisation space. A multipole mass filter includes several electrodes. A focusing system connects the ionisation space and the mass filter. Provision is made for applying to the electrodes a mass adjusting voltage combining a high frequency voltage and a d.c. voltage of increasing amplitude, so that the ions of a pre-determined mass can be selected. This system also includes a device connected to the electrodes, sensitive to the mass adjusting voltage and enabling the energy of the ions to be adjusted to that of the selected ions, depending on the mass of the ions, by modifying the difference in potential between the ionisation volume and the mean potential of the electrodes .

Analysis of the fatty acid composition of taraxicuum officinale flowers oil by gas chromatography mass spectrometer

International Nuclear Information System (INIS)

Hussain, I.; Ullah, R.

2013-01-01

Taraxicum officinale, is a highly valuable medicinal plant. The roots is an important herbal drug, having long been used on the continent as a remedy for liver complaints. Keeping in view the importance and wide applications in the pharmaceutical industries, the present study was therefore aimed to analyze the chemical constituents of the flowers of T. officinale. The T. officinale flowers oil constituents of methyl ester derivatives of fatty acids were analyzed applying gas chromatography coupled to mass spectrometer. The results obtained showed the presence of both containing the saturated as well as unsaturated fatty acids in T. officinale flower oils. A total of 19 different components were identified and quantified. The concentration level of Methyl ester of Lenolenic acid was found very effective in concentration 3.33%, among the identified analytes of interest. In addition, the level of other chemical constituents of methyl ester of palmitic acid 3.11%, myristic acid 1.87, linolenic acids 1.67%, stearic acid 0.97 were found. The concentration level of the rest of identified fatty acids analytes were below 1%. Thus the results obtained from the current initiative is very promising due to the presence of high percentage of valuable analytes concentrations recorded in the fatty acid of T. officinale flower oil. Thus due to the presence of highly important analytes which have increased their importance for consumption in the pharmaceuticals as well as its applications in the new formulations for different skin, cosmetics and health purposes and for use by local practioners. The study will also provide a scientific database line. (author)

GHGSat-D: Greenhouse gas plume imaging and quantification from space using a Fabry-Perot imaging spectrometer

Science.gov (United States)

McKeever, J.; Durak, B. O. A.; Gains, D.; Jervis, D.; Varon, D. J.; Germain, S.; Sloan, J. J.

2017-12-01

GHGSat, Inc. has launched the first satellite designed to detect and quantify greenhouse gas emissions from individual industrial sites. Our demonstration satellite GHGSat-D or "CLAIRE" was launched in June 2016. It weighs less than 15 kg and its primary instrument is a miniaturized Fabry-Perot imaging spectrometer with spectral resolution on the order of 0.1 nm. The spectral bandpass is 1635-1670 nm, giving the instrument access to absorption bands of both CO2 and CH4. Our system is based on targeted observations rather than global coverage, and our spatial imaging resolution is a key differentiator. Specifically, with a ground sampling distance of effect of the Fabry-Perot resonator and the scrolling scene gives a different spectral sampling of each surface location in every image. While our data processing toolchain does not produce a conventional hyperspectral dataset, it does yield a spectral decomposition of the spatially resolved signal that is compared to a model that includes atmospheric radiative transfer and the instrument's pixel-dependent spectral responsivity. Our presentation will describe the instrument design, concept of operations and retrievals approach. We will also present images and results from GHGSat-D at different processing levels, including high-resolution column density retrievals. An observation of the degassing flux of methane from the outlet of a recently impounded hydroelectric reservoir will be shown as an example. Finally we discuss some performance limitations of GHGSat-D and our plans to overcome them as we update the instrument design for the next satellites.

University Students Explaining Adiabatic Compression of an Ideal Gas--A New Phenomenon in Introductory Thermal Physics

Science.gov (United States)

Leinonen, Risto; Asikainen, Mervi A.; Hirvonen, Pekka E.

2012-01-01

This study focuses on second-year university students' explanations and reasoning related to adiabatic compression of an ideal gas. The phenomenon was new to the students, but it was one which they should have been capable of explaining using their previous upper secondary school knowledge. The students' explanations and reasoning were…

Imaging spectrometers for atmosphere monitoring

Science.gov (United States)

Reinert, Thido; Bovensmann, Heinrich; Münzenmayer, Ralf; Weiss, Stefan; Posselt, Winfried

2017-11-01

Atmospheric monitoring missions aim at products like O3, H2O, NO2, SO2, BrO, CH4, CO, CO2 as well as aerosols and cloud information. Depending on the application area (Ozone Monitoring, Green House Gas Monitoring, Tropospheric Composition and Air Quality, Chemistry Climate Interaction etc.) total or tropospheric columns as well as profile information is required. The user community of these data as well as their central requirements w.r.t. the payload aspects will be described. A large range of relevant passive instrument types is available, in particular imaging spectrometer, sounder and polarisation measuring systems in the UV-VIS, SWIR and TIR spectral range. Differences between instruments for dedicated missions are highlighted and evolution of requirements is explained, also in comparison with relevant existing instrumentation partly in orbit today. Aspects of technology roadmaps for instrument implementation as well as synergetic effects of instrument combinations and according mission scopes are discussed.

A specialized isotope mass spectrometer for noninvasive diagnostics of Helicobacter pylori infection in human beings

Science.gov (United States)

Blashenkov, N. M.; Sheshenya, E. S.; Solov'ev, S. M.; Sachenko, V. D.; Gall, L. N.; Zarutskii, I. V.; Gall, N. R.

2013-05-01

A specialized isotope mass spectrometer for noninvasive diagnostics of Helicobacter pylori infection in human beings based on the carbon-13 isotope breath test has been designed and constructed. Important stages of the work included (i) calculating a low-aberration mass analyzer, (ii) manufacturing and testing special gas inlet system, and (iii) creating a small-size collector of ions. The proposed instrument ensures 13C/12C isotopic ratio measurement to within 1.7‰ (pro mille) accuracy, which corresponds to requirements for a diagnostic tool. Preliminary medical testing showed that the mass spectrometer is applicable to practical diagnostics. The instrument is also capable of measuring isotopic ratios of other light elements, including N, O, B (for BF2+ ions), Ar, Cl, and S.

Spectrometers for compact neutron sources

Science.gov (United States)

Voigt, J.; Böhm, S.; Dabruck, J. P.; Rücker, U.; Gutberlet, T.; Brückel, T.

2018-03-01

We discuss the potential for neutron spectrometers at novel accelerator driven compact neutron sources. Such a High Brilliance Source (HBS) relies on low energy nuclear reactions, which enable cryogenic moderators in very close proximity to the target and neutron optics at comparably short distances from the moderator compared to existing sources. While the first effect aims at increasing the phase space density of a moderator, the second allows the extraction of a large phase space volume, which is typically requested for spectrometer applications. We find that competitive spectrometers can be realized if (a) the neutron production rate can be synchronized with the experiment repetition rate and (b) the emission characteristics of the moderator can be matched to the phase space requirements of the experiment. MCNP simulations for protons or deuterons on a Beryllium target with a suitable target/moderator design yield a source brightness, from which we calculate the sample fluxes by phase space considerations for different types of spectrometers. These match closely the figures of todays spectrometers at medium flux sources. Hence we conclude that compact neutron sources might be a viable option for next generation neutron sources.

Lessons learned with the SAGE spectrometer

International Nuclear Information System (INIS)

Sorri, J; Greenlees, P T; Jones, P; Julin, R; Konki, J; Pakarinen, J; Rahkila, P; Sandzelius, M; Uusitalo, J; Papadakis, P; Cox, D M; Herzberg, R D

2012-01-01

The SAGE spectrometer combines a high-efficiency γ-ray detection system with an electron spectrometer. Some of the design features have been known to be problematic and surprises have come up during the early implementation of the spectrometer. Tests related to bismuth germanate Compton-suppression shields, electron detection efficiency and an improved cooling system are discussed in the paper. (paper)

Process for detecting leak faults using a helium mass spectrometer

International Nuclear Information System (INIS)

Divet, Claude; Morin, Claude.

1977-01-01

The description is given of a process for detecting very small leak faults putting into communication the outer and inner sides of the wall of a containment, one of these wall sides being in contact with gaseous helium under a pressure of around one torr, the other side being one of the limits of a space pumped down to a residual gas pressure under 10 -3 torr. This space is in communication with the measuring cell of a helium mass spectrometer. This process may be applied to the detection of faults in metal claddings of the fuel rods used in nuclear reactors [fr

High resolution solar soft X-ray spectrometer

International Nuclear Information System (INIS)

Zhang Fei; Wang Huanyu; Peng Wenxi; Liang Xiaohua; Zhang Chunlei; Cao Xuelei; Jiang Weichun; Zhang Jiayu; Cui Xingzhu

2012-01-01

A high resolution solar soft X-ray spectrometer (SOX) payload onboard a satellite is developed. A silicon drift detector (SDD) is adopted as the detector of the SOX spectrometer. The spectrometer consists of the detectors and their readout electronics, a data acquisition unit and a payload data handling unit. A ground test system is also developed to test SOX. The test results show that the design goals of the spectrometer system have been achieved. (authors)

Crystal-diffraction spectrometer of increased efficiency

International Nuclear Information System (INIS)

Saukov, A.I.; Gornitsyn, G.A.; Morozov, N.A.

1985-01-01

The geometry of the spectrometer is illustrated in this paper. An attempt is made to achieve optimal design of the spectrometer by finding the coefficient of reflection of the gamma radiation from the various Ge planes. In these experiments, the Du Mond design was used in the spectrometer. Illustrations are provided to explain dependence of the relative efficiency upon the energy of the gamma quanta

MEMS based digital transform spectrometers

Science.gov (United States)

Geller, Yariv; Ramani, Mouli

2005-09-01

Earlier this year, a new breed of Spectrometers based on Micro-Electro-Mechanical-System (MEMS) engines has been introduced to the commercial market. The use of these engines combined with transform mathematics, produces powerful spectrometers at unprecedented low cost in various spectral regions.

Spin exchange optical pumping based polarized 3He filling station for the Hybrid Spectrometer at the Spallation Neutron Source.

Science.gov (United States)

Jiang, C Y; Tong, X; Brown, D R; Culbertson, H; Graves-Brook, M K; Hagen, M E; Kadron, B; Lee, W T; Robertson, J L; Winn, B

2013-06-01

The Hybrid Spectrometer (HYSPEC) is a new direct geometry spectrometer at the Spallation Neutron Source at the Oak Ridge National Laboratory. This instrument is equipped with polarization analysis capability with 60° horizontal and 15° vertical detector coverages. In order to provide wide angle polarization analysis for this instrument, we have designed and built a novel polarized (3)He filling station based on the spin exchange optical pumping method. It is designed to supply polarized (3)He gas to HYSPEC as a neutron polarization analyzer. In addition, the station can optimize the (3)He pressure with respect to the scattered neutron energies. The depolarized (3)He gas in the analyzer can be transferred back to the station to be repolarized. We have constructed the prototype filling station. Preliminary tests have been carried out demonstrating the feasibility of the filling station. Here, we report on the design, construction, and the preliminary results of the prototype filling station.

Performance of the ATLAS muon spectrometer

International Nuclear Information System (INIS)

Aleksa, M.

1999-09-01

ATLAS is a general-purpose experiment for the future large hadron collider (LHC) at CERN. Its Muon Spectrometer will require ∼5500 m 2 of precision tracking chambers to measure the muon tracks along a spectrometer arm of 5 m to 15 m length, embedded in a magnetic field of ∼0.5 T. The precision tracking devices in the Muon System will be high pressure drift tubes (MDTs). Approximately 370,000 MDTs will be assembled into ∼1200 drift chambers. The LHC physics discovery range indicates the need for a momentum resolution of ∼10 % for muons with a transverse momentum of p T =1 TeV/c. Following a detailed engineering optimisation of the magnetic-field strength versus the chamber resolution, the ATLAS collaboration opted for a drift-chamber system with very high spatial resolution, σ 2 93/7). Measurements performed in a high-background environment - similar to the ATLAS operational environment - gave us a complete understanding of the individual effects which deteriorate the spatial resolution at high rates. Four effects responsible for a resolution deterioration have been identified: two electronics effects which depend on the count rate of a tube (baseline shift and baseline fluctuations), and two space-charge effects that depend on the local count rate (gain drop and field fluctuations). The understanding of these effects had a major impact on the choice of the drift gas and the front-end electronics. The strong dependence of the drift velocity on the drift field is one major disadvantage of the baseline gas. In this work the full set of effects which lead to systematic errors to the track-position measurement in one tube (e.g. variations of the background rate) was investigated and quantified for realistic LHC operating conditions. For the biggest effects analytical corrections are presented. Finally, the muon-system performance was investigated and a calibration method for the absolute mass scale developed. By means of simulation it was shown that the energy

Laboratory Investigation of Trace Gas Emissions from Biomass Burning on DoD Bases

Science.gov (United States)

Burling, I. R.; Yokelson, R. J.; Griffith, D. W.; Roberts, J. M.; Veres, P. R.; Warneke, C.; Johnson, T. J.

2009-12-01

Vegetation representing fuels commonly managed with prescribed fires was collected from five DoD bases and burned under controlled conditions at the USFS Firelab in Missoula, MT. The smoke emissions were measured with a large suite of state-of-the-art instrumentation. Seventy-seven fires were conducted and the smoke composition data will improve DoD land managers’ ability to assess the impact of prescribed fires on local air quality. A key instrument used in the measurement of the gas phase species in smoke was an open-path FTIR (OP-FTIR) spectrometer, built and operated by the Universities of Montana and Wollongong. The OP-FTIR has to date detected and quantified 20 gas phase species - CO2, CO, H2O, N2O, NO2, NO, HONO, NH3, HCl, SO2, CH4, CH3OH, HCHO, HCOOH, C2H2, C2H4, CH3COOH, HCN, propylene and furan. The spectra were analyzed using a non-linear least squares fitting routine that included reference spectra recently acquired at the Pacific Northwest National Laboratories. Preliminary results from the OP-FTIR analysis are reported here. Of particular interest, gas-phase nitrous acid (HONO) was detected simultaneously by the OP-FTIR and negative-ion proton-transfer chemical ionization spectrometer (NI-PT-CIMS), with preliminary fire-integrated molar emission ratios (relative to NOx) ranging from approximately 0.03 to 0.20, depending on the vegetation type. HONO is an important precursor in the production of OH, the primary oxidizing species in the atmosphere. There existed little previous data documenting HONO emissions from either wild or prescribed fires. The non-methane organic emissions were dominated by oxygenated species, which can be further oxidized and thus involved in secondary aerosol formation. Elevated amounts of gas-phase HCl were also detected in the smoke, with the amounts varying depending on location and vegetation type.

Electro-Optical Imaging Fourier-Transform Spectrometer

Science.gov (United States)

Chao, Tien-Hsin; Zhou, Hanying

2006-01-01

An electro-optical (E-O) imaging Fourier-transform spectrometer (IFTS), now under development, is a prototype of improved imaging spectrometers to be used for hyperspectral imaging, especially in the infrared spectral region. Unlike both imaging and non-imaging traditional Fourier-transform spectrometers, the E-O IFTS does not contain any moving parts. Elimination of the moving parts and the associated actuator mechanisms and supporting structures would increase reliability while enabling reductions in size and mass, relative to traditional Fourier-transform spectrometers that offer equivalent capabilities. Elimination of moving parts would also eliminate the vibrations caused by the motions of those parts. Figure 1 schematically depicts a traditional Fourier-transform spectrometer, wherein a critical time delay is varied by translating one the mirrors of a Michelson interferometer. The time-dependent optical output is a periodic representation of the input spectrum. Data characterizing the input spectrum are generated through fast-Fourier-transform (FFT) post-processing of the output in conjunction with the varying time delay.

Searching for perfect fluids: quantum viscosity in a universal Fermi gas

International Nuclear Information System (INIS)

Cao, C; Elliott, E; Wu, H; Thomas, J E

2011-01-01

We measure the shear viscosity in a two-component Fermi gas of atoms, tuned to a broad s-wave collisional (Feshbach) resonance. At resonance, the atoms strongly interact and exhibit universal behavior, where the equilibrium thermodynamic properties and transport coefficients are universal functions of density n and temperature T. We present a new calibration of the temperature as a function of global energy, which is directly measured from the cloud profiles. Using the calibration, the trap-averaged shear viscosity in units of ℎn is determined as a function of the reduced temperature at the trap center, from nearly the ground state to the unitary two-body regime. Low-temperature data are obtained from the damping rate of the radial breathing mode, whereas high-temperature data are obtained from hydrodynamic expansion measurements. We also show that the best fit to the high-temperature expansion data is obtained for a vanishing bulk viscosity. The measured trap-averaged entropy per particle and shear viscosity are used to estimate the ratio of shear viscosity to entropy density, which is compared with that conjectured for a perfect fluid.

Charged particle scintillation mass spectrometer

International Nuclear Information System (INIS)

Baranov, P.S.; Zhuravlev, E.E.; Nafikov, A.A.; Osadchi , A.I.; Raevskij, V.G.; Smirnov, P.A.; Cherepnya, S.N.; Yanulis, Yu.P.

1982-01-01

A scintillation mass-spectrometer for charged particle identification by the measured values of time-of-flight and energy operating on line with the D-116 computer is described. Original time detectors with 100x100x2 mm 3 and 200x2 mm 2 scintillators located on the 1- or 2 m path length are used in the spectrometer. The 200x200x200 mm 3 scintillation unit is used as a E-counter. Time-of-flight spectra of the detected particles on the 2 m path length obtained in spectrometer test in the beam of charged particles escaping from the carbon target at the angle of 130 deg under 1.2 GeV bremsstrahlung beam of the ''Pakhra'' PIAS synchrotron are presented. Proton and deuteron energy spectra as well as mass spectrum of all the particles detected by the spectrometer are given. Mass resolution obtained on the 2 m path length for π-mesons is +-25%, for protons is +-5%, for deuterons is +-3%

Micromegas Detectors for the Muon Spectrometer Upgrade of the ATLAS Experiment

CERN Document Server

Iodice, Mauro; The ATLAS collaboration

2015-01-01

The Micromegas (MICRO MEsh GAseous Structure) have been proven along the years to be reliable detectors with excellent space resolution and high rate capability. Large area Micromegas will be employed for the first time in high-energy physics for the Muon Spectrometer upgrade of the ATLAS experiment at CERN LHC. A total surface of about 150 m$^2$ of the forward regions of the Muon Spectrometer will be equipped with 8 layers of Micromegas modules. Each module covers a surface from 2 to 3 m$^2$ for a total active area of 1200 m$^2$. Together with the small-strips Thin Gap Chambers, they will compose the two New Small Wheels, which will replace the innermost stations of the ATLAS Endcap Muon tracking system in the 2018/19 shutdown. The breakthroughs and developments of this type of Micro Pattern Gas Detector will be reviewed, along with the path towards the construction of the modules, which will take place in several production sites starting in 2015. An overview of the detector performances obtained in the rec...

Micromegas Detectors for the Muon Spectrometer Upgrade of the ATLAS Experiment

CERN Document Server

Iodice, M; The ATLAS collaboration

2014-01-01

The Micromegas (MICRO MEsh GAseous Structure) chambers have been proven along the years to be reliable detectors with excellent space resolution and high rate capability. Large area Micromegas will be employed for the first time in high-energy physics for the Muon Spectrometer upgrade of the ATLAS experiment at CERN LHC. A total surface of about 150 m2 of the forward regions of the Muon Spectrometer will be equipped with 8 layers of Micromegas modules. Each module covers a surface from 2 to 3 m2 for a total active area of 1200 m2. Together with the small-strips Thin Gap Chambers, they will compose the two New Small Wheels, which will replace the innermost stations of the ATLAS Endcap Muon tracking system in the 2018/19 shutdown. The principles of operation and recent developments of this type of Micro Pattern Gas Detector will be reviewed, along with our plans towards the construction of the modules, which will take place in several production sites. An overview of the detector performances obtained in the re...

A VUV prism spectrometer for RICH radiator refractometry

CERN Document Server

Moyssides, P G; Fokitis, E

2000-01-01

A prism spectrometer has been developed to operate in the VUV wavelength range from 120 to 200 nm. It can be used as a pre- disperser in conjunction with a Fabry-Perot based gas refractometer. This instrument has also been used to measure the refractive index of the liquid radiator C/sub 6/F/sub 14/ in various spectral lines. This radiator is used in the RICH detectors of the DELPHI experiment and has been proposed for ALICE, and LHCb experiments. The spectral resolution of the system is improved as the wavelength decreases and the data are consistent with a wavelength accuracy about 0.4 nm at 140 nm. The results for the dispersion curve of the above liquid are presented. (17 refs).

Massive Fermi gas in the expanding universe

Energy Technology Data Exchange (ETDEWEB)

Trautner, Andreas, E-mail: atrautner@uni-bonn.de [Bethe Center for Theoretical Physics and Physikalisches Institut der Universität Bonn, Nussallee 12, 53115 Bonn (Germany)

2017-03-01

The behavior of a decoupled ideal Fermi gas in a homogeneously expanding three-dimensional volume is investigated, starting from an equilibrium spectrum. In case the gas is massless and/or completely degenerate, the spectrum of the gas can be described by an effective temperature and/or an effective chemical potential, both of which scale down with the volume expansion. In contrast, the spectrum of a decoupled massive and non-degenerate gas can only be described by an effective temperature if there are strong enough self-interactions such as to maintain an equilibrium distribution. Assuming perpetual equilibration, we study a decoupled gas which is relativistic at decoupling and then is red-shifted until it becomes non-relativistic. We find expressions for the effective temperature and effective chemical potential which allow us to calculate the final spectrum for arbitrary initial conditions. This calculation is enabled by a new expansion of the Fermi-Dirac integral, which is for our purpose superior to the well-known Sommerfeld expansion. We also compute the behavior of the phase space density under expansion and compare it to the case of real temperature and real chemical potential. Using our results for the degenerate case, we also obtain the mean relic velocity of the recently proposed non-thermal cosmic neutrino background.

Ion mobility spectrometer / mass spectrometer (IMS-MS).

Energy Technology Data Exchange (ETDEWEB)

Hunka Deborah Elaine; Austin, Daniel E.

2005-07-01

The use of Ion Mobility Spectrometry (IMS) in the Detection of Contraband Sandia researchers use ion mobility spectrometers for trace chemical detection and analysis in a variety of projects and applications. Products developed in recent years based on IMS-technology include explosives detection personnel portals, the Material Area Access (MAA) checkpoint of the future, an explosives detection vehicle portal, hand-held detection systems such as the Hound and Hound II (all 6400), micro-IMS sensors (1700), ordnance detection (2500), and Fourier Transform IMS technology (8700). The emphasis to date has been on explosives detection, but the detection of chemical agents has also been pursued (8100 and 6400). Combining Ion Mobility Spectrometry (IMS) with Mass Spectrometry (MS) is described. The IMS-MS combination overcomes several limitations present in simple IMS systems. Ion mobility alone is insufficient to identify an unknown chemical agent. Collision cross section, upon which mobility is based, is not sufficiently unique or predictable a priori to be able to make a confident peak assignment unless the compounds present are already identified. Molecular mass, on the other hand, is much more readily interpreted and related to compounds. For a given compound, the molecular mass can be determined using a pocket calculator (or in one's head) while a reasonable value of the cross-section might require hours of computation time. Thus a mass spectrum provides chemical specificity and identity not accessible in the mobility spectrum alone. In addition, several advanced mass spectrometric methods, such as tandem MS, have been extensively developed for the purpose of molecular identification. With an appropriate mass spectrometer connected to an ion mobility spectrometer, these advanced identification methods become available, providing greater characterization capability.

Combined raman spectrometer/laser-induced breakdown spectrometer design concept

Science.gov (United States)

Bazalgette Courrèges-Lacoste, Gregory; Ahlers, Berit; Boslooper, Erik; Rull-Perez, Fernando; Maurice, Sylvestre

2017-11-01

Amongst the different instruments that have been preselected to be on-board the Pasteur payload on ExoMars is the Raman/ Laser Induced Breakdown Spectroscopy (LIBS) instrument. Raman spectroscopy and LIBS will be integrated into a single instrument sharing many hardware commonalities. An international team under the lead of TNO has been gathered to produce a design concept for a combined Raman Spectrometer/ LIBS Elegant Bread-Board (EBB). The instrument is based on a specifically designed extremely compact spectrometer with high resolution over a large wavelength range, suitable for both Raman spectroscopy and LIBS measurements. Low mass, size and resources are the main drivers of the instrument's design concept. The proposed design concept, realization and testing programme for the combined Raman/ LIBS EBB is presented as well as background information on Raman and LIBS.

X-ray photoelectron spectrometer calibration and thin film investigations on germanium oxides

OpenAIRE

Deegan, Terri

1998-01-01

The first aim of this project was the characterisation of the VG Scientific Clam 100 based, XPS (X-ray Photoelectron Spectroscopy). Spectrometer in the Physics department at Dublin City University Detailed energy scale and intensity scale calibrations were carried out using sputter-cleaned Au (Gold), Ag (Silver), Cu (Copper) and Pd (Palladium) foil samples. Analysis of these calibration spectra against standard reference spectra led to an accurate energy calibration and the production of indi...

Ion-neutral transport through quadrupole interfaces of mass-spectrometer systems

International Nuclear Information System (INIS)

Jugroot, M.; Groth, C.P.T.; Thomson, B.A.; Baranov, V.; Collings, B.A.; French, J.B.

2004-01-01

The transport of free ions through highly under-expanded jet flows of neutral gases and in the presence of applied electric fields is investigated by continuum-based numerical simulations. In particular, numerical results are described which are relevant to ion flows occurring in quadrupole interfaces of mass spectrometer systems. A five-moment mathematical model and parallel multi-block numerical solution procedure is developed for predicting the ion transport. The model incorporates the effects of ion-neutral collision processes and is used in conjunction with a Navier-Stokes model and flow solver for the neutral gas to examine the key influences controlling the ion motion. The effects of the neutral gas flow, electric fields (both dc and rf), and flow field geometry on ion mobility are carefully assessed. The capability of controlling the charged particle motions through a combination of directed neutral flow and applied electric field is demonstrated for these high-speed, hypersonic, jet flows. (author)

The change law of the universe

Science.gov (United States)

Yongquan, Han

The ideal gas state equation is not applicable to ordinary gas, it should be applied to the Electromagnetic ''gas'' that is applied to the radiation, the radiation should be the ultimate state of matter changes or initial state, the universe is filled with radiation. That is, the ideal gas equation of state is suitable for the Singular point and the universe. Maybe someone consider that, there is no vessel can accommodate radiation, it is because the Ordinary container is too small to accommodate, if the radius of your container is the distance that Light through an hour, would you still think it can't accommodates radiation? Modern scientific determinate that the radius of the universe now is about 1027 m, assuming that the universe is a sphere whose volume is approximately: V = 4.19 × 1081 cubic meters, the temperature radiation of the universe (cosmic microwave background radiation temperature of the universe, should be the closest the average temperature of the universe) T = 3.15k, radiation pressure P = 5 Ã 10-6 N / m 2, according to the law of ideal gas state equation, PV / T = 6 à 1075, the value of this constant is the universe, The singular point should also equal to the constant

A high-resolution Fourier Transform Spectrometer for planetary spectroscopy

Science.gov (United States)

Cruikshank, D. P.; Sinton, W. M.

1973-01-01

The employment of a high-resolution Fourier Transform Spectrometer (FTS) is described for planetary and other astronomical spectroscopy in conjunction with the 88-inch telescope at Mauna Kea Observatory. The FTS system is designed for a broad range of uses, including double-beam laboratory spectroscopy, infrared gas chromatography, and nuclear magnetic resonance spectroscopy. The data system is well-suited to astronomical applications because of its great speed in acquiring and transforming data, and because of the enormous storage capability of the magnetic tape unit supplied with the system. The basic instrument is outlined 2nd some of the initial results from the first attempted use on the Mauna Kea 88-inch telescope are reported.

Recent ion optics and mass spectrometers

International Nuclear Information System (INIS)

Matsuda, Hisashi

1976-01-01

The establishment of the third order approximation method for computing the orbit of the ion optical system for mass spectrometers and the completion of its computer program are reported. A feature of this orbit computation is in that the effect of the fringing field can be considered with the accuracy of third order approximation. Several new ion optical systems for mass spectrometers have been proposed by using such orbit computing programs. Brief explanation and the description on the future prospect and problems are made on the following items: the vertual image double focusing mass spectrometer, the second order double focusing mass spectrometer, the E x B superposed field mass spectrometer, and the apparatus with a cylindrical electric field and Q-lens. In the E x B superposed field with Matsuda plates, if the magnetic field is generated by an electromagnet instead of a permanent magnet, the dispersion of mass and energy can be changed at will. The Matsuda plates are known as the auxiliary electrodes positioned at the top and bottom of a cylindrical capacitor. Utilizing those characteristics, a zoom spectrometer can be made, with which only a necessary part of mass spectra can be investigated in detail, but the whole spectra are investigated roughly. In addition, the distribution of energy can be investigated simultaneously after the separation of ionic mass similarly to the parabola apparatus. (Iwakiri, K.)

Dual Source Time-of-flight Mass Spectrometer and Sample Handling System

Science.gov (United States)

Brinckerhoff, W.; Mahaffy, P.; Cornish, T.; Cheng, A.; Gorevan, S.; Niemann, H.; Harpold, D.; Rafeek, S.; Yucht, D.

We present details of an instrument under development for potential NASA missions to planets and small bodies. The instrument comprises a dual ionization source (laser and electron impact) time-of-flight mass spectrometer (TOF-MS) and a carousel sam- ple handling system for in situ analysis of solid materials acquired by, e.g., a coring drill. This DSTOF instrument could be deployed on a fixed lander or a rover, and has an open design that would accommodate measurements by additional instruments. The sample handling system (SHS) is based on a multi-well carousel, originally de- signed for Champollion/DS4. Solid samples, in the form of drill cores or as loose chips or fines, are inserted through an access port, sealed in vacuum, and transported around the carousel to a pyrolysis cell and/or directly to the TOF-MS inlet. Samples at the TOF-MS inlet are xy-addressable for laser or optical microprobe. Cups may be ejected from their holders for analyzing multiple samples or caching them for return. Samples are analyzed with laser desorption and evolved-gas/electron-impact sources. The dual ion source permits studies of elemental, isotopic, and molecular composition of unprepared samples with a single mass spectrometer. Pulsed laser desorption per- mits the measurement of abundance and isotope ratios of refractory elements, as well as the detection of high-mass organic molecules in solid samples. Evolved gas analysis permits similar measurements of the more volatile species in solids and aerosols. The TOF-MS is based on previous miniature prototypes at JHU/APL that feature high sensitivity and a wide mass range. The laser mode, in which the sample cup is directly below the TOF-MS inlet, permits both ablation and desorption measurements, to cover elemental and molecular species, respectively. In the evolved gas mode, sample cups are raised into a small pyrolysis cell and heated, producing a neutral gas that is elec- tron ionized and pulsed into the TOF-MS. (Any imaging

Electron volt neutron spectrometers

International Nuclear Information System (INIS)

Pietropaolo, A.; Senesi, R.

2011-01-01

The advent of pulsed neutron sources has made available intense fluxes of epithermal neutrons (500 meV ≤E≤100 eV ). The possibility to open new investigations on condensed matter with eV neutron scattering techniques, is related to the development of methods, concepts and devices that drive, or are inspired by, emerging studies at this energy scale. Electron volt spectrometers have undergone continuous improvements since the construction of the first prototype instruments, but in the last decade major breakthroughs have been accomplished in terms of resolution and counting statistics, leading, for example, to the direct measurement of the proton 3-D Born–Oppenheimer potential in any material, or to quantitatively probe nuclear quantum effects in hydrogen bonded systems. This paper reports on the most effective methods and concepts for energy analysis and detection, as well as devices for the optimization of electron volt spectrometers for different applications. This is set in the context of the progress made up to date in instrument development. Starting from early stages of development of the technique, particular emphasis will be given to the Vesuvio eV spectrometer at the ISIS neutron source, the first spectrometer where extensive scientific, as well as research and development programmes have been carried out. The potential offered by this type of instrumentation, from single particle excitations to momentum distribution studies, is then put in perspective into the emerging fields of eV spectroscopy applied to cultural heritages and neutron irradiation effects in electronics. - Highlights: ► Neutron spectrometers at eV energies. ► Methods and techniques for eV neutrons counting at spallation sources. ► Scattering, imaging and radiation hardness tests with multi-eV neutrons.

Improvement of the intrinsic time resolving power of the Cologne iron-free orange type electron spectrometers

Energy Technology Data Exchange (ETDEWEB)

Regis, J.-M.; Materna, Th.; Pascovici, G.; Christen, S.; Dewald, A.; Fransen, C.; Jolie, J.; Petkov, P.; Zell, K. O. [Institut fuer Kernphysik (IKP), Universitaet zu Koeln, Zuelpicher Str. 77, 50937 Koeln (Germany)

2010-11-15

Conversion electron spectroscopy represents an important tool for nuclear structure analysis of medium and heavy nuclei. Two iron-free magnetic electron spectrometers of the orange type have been installed at the Institute for Nuclear Physics of the University of Cologne. The very large transmission of 15% and the very good energy resolution of 1% makes the iron-free orange spectrometer a powerful instrument. By means of fast timing techniques, lifetimes of nuclear excited states can be measured with an accuracy better than 20 ps. For the first time, the energy dependent centroid position of prompt events yielding the time-walk characteristics (the prompt curve) of the orange spectrometer fast timing setup has been measured using prompt secondary {delta}-electrons generated in a pulsed beam experiment. The prompt curve calibrated as a function of energy allows precise lifetime determination down to a few tens of picoseconds by the use of the centroid shift method.

Aerosol Observing System Greenhouse Gas (AOS GhG) Handbook

Energy Technology Data Exchange (ETDEWEB)

Biraud, S. C. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Reichl, K. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

2016-03-01

The Greenhouse Gas (GhG) Measurement system is a combination of two systems in series: (1) the Tower Gas Processing (TGP) System, an instrument rack which pulls, pressurizes, and dries air streams from an atmospheric sampling tower through a series of control and monitoring components, and (2) the Picarro model G2301 cavity ringdown spectrometer (CRDS), which measures CO2, CH4, and H2O vapor; the primary measurements of the GhG system.

A magnetic-lens - mini-orange coincidence spectrometer

International Nuclear Information System (INIS)

Bargholtz, C.; Holmberg, L.; Ruus, N.; Tegner, P.E.; Weiss, G.

1997-04-01

A coincidence spectrometer consisting of a Gerholm type magnetic lens and a permanent magnet mini-orange spectrometer is described. Electron-electron or electron-positron coincidences may be registered in various angular settings. The spectrometer has been developed mainly to search for anomalous contributions to Bhabha scattering or positrons and is at present used for such studies. 6 refs

Ultra-Wideband Optical Modulation Spectrometer (OMS) Development

Science.gov (United States)

Gardner, Jonathan (Technical Monitor); Tolls, Volker

2004-01-01

The optical modulation spectrometer (OMS) is a novel, highly efficient, low mass backend for heterodyne receiver systems. Current and future heterodyne receiver systems operating at frequencies up to a few THz require broadband spectrometer backends to achieve spectral resolutions of R approximately 10(exp 5) to 10(exp 6) to carry out many important astronomical investigations. Among these are observations of broad emission and absorption lines from extra-galactic objects at high redshifts, spectral line surveys, and observations of planetary atmospheres. Many of these lines are pressure or velocity broadened with either large half-widths or line wings extending over several GHz. Current backend systems can cover the needed bandwidth only by combining the output of several spectrometers, each with typically up to 1 GHz bandwidth, or by combining several frequency-shifted spectra taken with a single spectrometer. An ultra-wideband optical modulation spectrometer with 10 - 40 GHz bandwidth will enable broadband ob- servations without the limitations and disadvantages of hybrid spectrometers. Spectrometers like the OMS will be important for both ground-based observatories and future space missions like the Single Aperture Far-Infrared Telescope (SAFIR) which might carry IR/submm array heterodyne receiver systems requiring a spectrometer for each array pixel. Small size, low mass and small power consumption are extremely important for space missions. This report summarizes the specifications developed for the OMS and lists already identified commercial parts. The report starts with a review of the principle of operation, then describes the most important components and their specifications which were derived from theory, and finishes with a conclusion and outlook.

Mid infrared MEMS FTIR spectrometer

Science.gov (United States)

Erfan, Mazen; Sabry, Yasser M.; Mortada, Bassem; Sharaf, Khaled; Khalil, Diaa

2016-03-01

In this work we report, for the first time to the best of our knowledge, a bulk-micromachined wideband MEMS-based spectrometer covering both the NIR and the MIR ranges and working from 1200 nm to 4800 nm. The core engine of the spectrometer is a scanning Michelson interferometer micro-fabricated using deep reactive ion etching (DRIE) technology. The spectrum is obtained using the Fourier Transform techniques that allows covering a very wide spectral range limited by the detector responsivity. The moving mirror of the interferometer is driven by a relatively large stroke electrostatic comb-drive actuator. Zirconium fluoride (ZrF4) multimode optical fibers are used to connect light between the white light source and the interferometer input, as well as the interferometer output to a PbSe photoconductive detector. The recorded signal-to-noise ratio is 25 dB at the wavelength of 3350 nm. The spectrometer is successfully used in measuring the absorption spectra of methylene chloride, quartz glass and polystyrene film. The presented solution provides a low cost method for producing miniaturized spectrometers in the near-/mid-infrared.

The DEIS high energy muon spectrometer. II. The data acquisition system

International Nuclear Information System (INIS)

Allkofer, O.C.; Dau, W.D.; Faehnders, E.; Jokisch, H.; Kaleschke, G.P.; Klemke, G.; Sauerland, K.; Schmidtke, G.; Uhr, R.C.; Bella, G.; Oren, Y.; Virni, U.; Seidman, A.

1977-01-01

The whole spectrometer is read out and controlled on-line via a CAMAC-system by a minicomputer. The magnetostrictive read out signals of 66 magnetostrictive read out wands of the wire spark chambers are digitized by 20-MHz-scalers which can store up to 8 sparks per chamber. The time-of-flight of the muon, the pulse heights of the scintillation counters, the time of event are also recorded. The on-line-computer makes reliability checks of the data and stores them together with monitor data about magnetic field, gas and high voltage system, etc. on magnetic tape for off-line analysis. (author)

Removal of stored particle background via the electric dipole method in the KATRIN main spectrometer

Energy Technology Data Exchange (ETDEWEB)

Hilk, Daniel [Institut fuer Experimentelle Kernphysik, KIT, Karlsruhe (Germany); Collaboration: KATRIN-Collaboration

2016-07-01

The goal of the KArlsruhe TRItium Neutrino (KATRIN) experiment is to determine the effective mass of the electron anti neutrino by measuring the electron energy spectrum of tritium beta decay near the endpoint. The goal is to reach a sensitivity on the neutrino mass of 200 meV for which a low background level of 10{sup -2} counts per second is mandatory. Electrons from single radioactive decays of radon and tritium in the KATRIN main spectrometer with energies in the keV range can be magnetically stored for hours. While cooling down via ionization of residual gas molecules, they produce hundreds of secondary electrons, which can reach the detector and contribute to the background signals. In order to suppress this background component, several methods are investigated to remove stored electrons, such as the application of an electric dipole field and the application of magnetic pulses. This talk introduces the mechanism of background production due to stored electrons and their removal by the electric dipole method in the main spectrometer. In context of the spectrometer- and detector-commissioning phase in summer 2015, measurement results of the application of the electric dipole method are presented.

Fission product nuclear data obtained by use of an on-line mass spectrometer

International Nuclear Information System (INIS)

Reeder, P.L.; Wright, J.F.; Anderl, R.A.

1975-01-01

A Spectrometer for On-Line Analysis of Radionuclides (SOLAR) has been installed at a 1 MW TRIGA reactor at Washington State University. Fission product ions from a combination target/ion source located within the thermal column are brought out to a 60 0 magnetic sector mass spectrometer. Surface ionization provides copious beams of Rb + and Cs + ions and less intense beams of Br - and I - ions with negligible contamination by other elements. About 40 fission product nuclides can thus be chemically and physically separated in times of less than 1 second. Past results on independent and cumulative fission yields along with measurements of half-lives of some very neutron-rich nuclides are presented. Current work on delayed-neutron emission probabilities and energy spectra of delayed neutrons from individual nuclides is described. (7 tables, 2 figures) (U.S.)

Performance and optimization of a combustion interface for isotope ratio monitoring gas chromatography/mass spectrometry

Science.gov (United States)

Merritt, D. A.; Freeman, K. H.; Ricci, M. P.; Studley, S. A.; Hayes, J. M.

1995-01-01

Conditions and systems for on-line combustion of effluents from capillary gas chromatographic columns and for removal of water vapor from product streams were tested. Organic carbon in gas chromatographic peaks 15 s wide and containing up to 30 nanomoles of carbon was quantitatively converted to CO2 by tubular combustion reactors, 200 x 0.5 mm, packed with CuO or NiO. No auxiliary source of O2 was required because oxygen was supplied by metal oxides. Spontaneous degradation of CuO limited the life of CuO reactors at T > 850 degrees C. Since NiO does not spontaneously degrade, its use might be favored, but Ni-bound carbon phases form and lead to inaccurate isotopic results at T Water must be removed from the gas stream transmitted to the mass spectrometer or else protonation of CO2 will lead to inaccuracy in isotopic analyses. Although thresholds for this effect vary between mass spectrometers, differential permeation of H2O through Nafion tubing was effective in both cases tested, but the required length of the Nafion membrane was 4 times greater for the more sensitive mass spectrometer.

Study of neutron spectrometers for ITER

Energy Technology Data Exchange (ETDEWEB)

Kaellne, Jan

2005-11-15

A review is presented of the developments in the field of neutron emission spectrometry (NES) which is of relevance for identifying the role of NES diagnostics on ITER and selecting suitable instrumentation. Neutron spectrometers will be part of the ITER neutron diagnostic complement and this study makes a special effort to examine which performance characteristics the spectrometers should possess to provide the best burning plasma diagnostic information together with neutron cameras and neutron yield monitors. The performance of NES diagnostics is coupled to how much interface space can be provided which has lead to an interest to find compact instruments and their NES capabilities. This study assesses all known spectrometer types of potential interest for ITER and makes a ranking of their performance (as demonstrated or projected), which, in turn, are compared with ITER measurement requirements as a reference; the ratio of diagnostic performance to interface cost for different spectrometers is also discussed for different spectrometer types. The overall result of the study is an assessment of which diagnostic functions neutron measurements can provide in burning plasma fusion experiments on ITER and the role that NES can play depending on the category of instrument installed. Of special note is the result that much higher quality diagnostic information can be obtained from neutron measurements with total yield monitors, profile flux cameras and spectrometers when the synergy in the data is considered in the analysis and interpretation.

Nuclear magnetic resonance in chemical department of the Exact Science Institute of the Minas Gerais Federal University

International Nuclear Information System (INIS)

Veloso, D.P.

1989-01-01

The specifications for acquisition of pulsed NMR spectrometer by chemical department of Minas Gerais Federal University are described. The researches carried out using the NMR spectrometer are presented as well as installation and operation of NMR equipments. (M.C.K.)

Multi-spectrometer calibration transfer based on independent component analysis.

Science.gov (United States)

Liu, Yan; Xu, Hao; Xia, Zhenzhen; Gong, Zhiyong

2018-02-26

Calibration transfer is indispensable for practical applications of near infrared (NIR) spectroscopy due to the need for precise and consistent measurements across different spectrometers. In this work, a method for multi-spectrometer calibration transfer is described based on independent component analysis (ICA). A spectral matrix is first obtained by aligning the spectra measured on different spectrometers. Then, by using independent component analysis, the aligned spectral matrix is decomposed into the mixing matrix and the independent components of different spectrometers. These differing measurements between spectrometers can then be standardized by correcting the coefficients within the independent components. Two NIR datasets of corn and edible oil samples measured with three and four spectrometers, respectively, were used to test the reliability of this method. The results of both datasets reveal that spectra measurements across different spectrometers can be transferred simultaneously and that the partial least squares (PLS) models built with the measurements on one spectrometer can predict that the spectra can be transferred correctly on another.

[Design of Dual-Beam Spectrometer in Spectrophotometer for Colorimetry].

Science.gov (United States)

Liu, Yi-xuan; Yan, Chang-xiang

2015-07-01

Spectrophotometers for colorimetry are usually composed of two independent and identical spectrometers. In order to reduce the volume of spectrophotometer for colorimetry, a design method of double-beam spectrometer is put forward. A traditional spectrometer is modified so that a new spectrometer can realize the function of double spectrometers, which is especially suitable for portable instruments. One slit is replaced by the double-slit, than two beams of spectrum can be detected. The working principle and design requirement of double-beam spectrometer are described. A spectrometer of portable spectrophotometer is designed by this method. A toroidal imaging mirror is used for the Czerny-Turner double-beam spectrometer in this paper, which can better correct astigmatism, and prevent the dual-beam spectral crosstalk. The results demonstrate that the double-beam spectrometer designed by this method meets the design specifications, with the spectral resolution less than 10 nm, the spectral length of 9.12 mm, and the volume of 57 mm x 54 mm x 23 mm, and without the dual-beam spectral overlap in the detector either. Comparing with a traditional spectrophotometer, the modified spectrophotometer uses a set of double-beam spectrometer instead of two sets of spectrometers, which can greatly reduce the volume. This design method can be specially applied in portable spectrophotometers, also can be widely applied in other double-beam spectrophotometers, which offers a new idea for the design of dual-beam spectrophotometers.

Intracavity Laser Photoacoustic Spectrometer with High Sensitivity

International Nuclear Information System (INIS)

Mitrayana; Muslim; Wasono, M.A.J.

2002-01-01

A photo acoustic spectrometer set-up has been upgraded from an extra cavity into an intracavity configuration using a sealed-off CO 2 laser as the spectrometer's radiation source. The detection level of the upgrade Intracavity Photoacoustic Spectrometer (IPS) reached (200 ± 50) ppt for C 2 H 4 and (20 ± 5) ppt for SF 6 with response time (6.6 ± 0.2) s. (author)

Evaluation of the ROTAX spectrometer

International Nuclear Information System (INIS)

Tietze-Jaensch, H.; Schmidt, W.; Geick, R.

1997-01-01

After installation of the new-type rotating crystal analyser spectrometer ROTAX at ISIS, we report on practical experience and describe its current status. The rotating analyser technique works feasibly and reliably and provides an ultimate scan flexibility on a pulsed time-of-flight neutron spectrometer. The spinning analyser achieves a mulitplex advantage factor of ca. 50 without compromising the resolution of the instrument. Despite these instrument merits its individual beam position at ISIS has only an unsatisfactorily weak flux, thus hindering this instrument yet to become fully competitive with other high-performance neutron spectrometers based at high-flux reactors. However, we strongly recommend a ROTAX-type instrument to be emphasized when the instrumentation suite of the future European spallation source ESS will come under scrutiny. (orig.)

Handheld spectrometers: the state of the art

Science.gov (United States)

Crocombe, Richard A.

2013-05-01

"Small" spectrometers fall into three broad classes: small versions of laboratory instruments, providing data, subsequently processed on a PC; dedicated analyzers, providing actionable information to an individual operator; and process analyzers, providing quantitative or semi-quantitative information to a process controller. The emphasis of this paper is on handheld dedicated analyzers. Many spectrometers have historically been large, possible fragile, expensive and complicated to use. The challenge over the last dozen years, as instruments have moved into the field, has been to make spectrometers smaller, affordable, rugged, easy-to-use, but most of all capable of delivering actionable results. Actionable results can dramatically improve the efficiency of a testing process and transform the way business is done. There are several keys to this handheld spectrometer revolution. Consumer electronics has given us powerful mobile platforms, compact batteries, clearly visible displays, new user interfaces, etc., while telecomm has revolutionized miniature optics, sources and detectors. While these technologies enable miniature spectrometers themselves, actionable information has demanded the development of rugged algorithms for material confirmation, unknown identification, mixture analysis and detection of suspicious materials in unknown matrices. These algorithms are far more sophisticated than the `correlation' or `dot-product' methods commonly used in benchtop instruments. Finally, continuing consumer electronics advances now enable many more technologies to be incorporated into handheld spectrometers, including Bluetooth, wireless, WiFi, GPS, cameras and bar code readers, and the continued size shrinkage of spectrometer `engines' leads to the prospect of dual technology or `hyphenated' handheld instruments.

Astronomers Take the Measure of Dark Matter in the universe

Science.gov (United States)

2001-09-01

measurements of the cosmic microwave background radiation, the large-scale distribution of galaxies, and the properties of distant supernovas. The Institute of Astronomy team minimized systematic errors in their work by placing independent constraints on the masses of the clusters using data from NASA's Hubble Space Telescope and the Canada-France-Hawaii Telescope atop Mauna Kea, HI. The new Chandra results also show how the average X-ray luminosity and temperature of the hot gas varies with the mass of a cluster. These findings should allow astronomers to use the data from large cluster catalogues, for which only X-ray luminosities are generally available, to get even more accurate measurements of the mean mass density of the universe, and to understand further the processes by which clusters form and grow. The Chandra observations were carried out using the Advanced CCD Imaging Spectrometer, which was built for NASA by the Massachusetts Institute of Technology, Cambridge, and Pennsylvania State University, University Park. NASA's Marshall Space Flight Center in Huntsville, AL, manages the Chandra program, and TRW, Inc., Redondo Beach, CA, is the prime contractor for the spacecraft. The Smithsonian's Chandra X-ray Center controls science and flight operations from Cambridge, MA. The Hubble Space Telescope is a project of international cooperation between NASA and the European Space Agency. Images associated with this release are available on the World Wide Web at: http://chandra.harvard.edu AND http://chandra.nasa.gov

Miniature Raman spectrometer development

Science.gov (United States)

Bonvallet, Joseph; Auz, Bryan; Rodriguez, John; Olmstead, Ty

2018-02-01

The development of techniques to rapidly identify samples ranging from, molecule and particle imaging to detection of high explosive materials, has surged in recent years. Due to this growing want, Raman spectroscopy gives a molecular fingerprint, with no sample preparation, and can be done remotely. These systems can be small, compact, lightweight, and with a user interface that allows for easy use and sample identification. Ocean Optics Inc. has developed several systems that would meet all these end user requirements. This talk will describe the development of different Ocean Optics Inc miniature Raman spectrometers. The spectrometer on a phone (SOAP) system was designed using commercial off the shelf (COTS) components, in a rapid product development cycle. The footprint of the system measures 40x40x14 mm (LxWxH) and was coupled directly to the cell phone detector camera optics. However, it gets roughly only 40 cm-1 resolution. The Accuman system is the largest (290x220X100 mm) of the three, but uses our QEPro spectrometer and get 7-11 cm-1 resolution. Finally, the HRS-30 measuring 165x85x40 mm is a combination of the other two systems. This system uses a modified EMBED spectrometer and gets 7-12 cm-1 resolution. Each of these units uses a peak matching algorithm that then correlates the results to the pre-loaded and customizable spectral libraries.

Atmospheric Transmission Measurements Using IR Lasers, Fourier Transform Spectroscopy, and Gas-Filter Correlation Techniques

National Research Council Canada - National Science Library

Dowling, J

1977-01-01

... and a gas filter correlation spectrometer. Results obtained from three concurrent experiments used to generate a data base appropriate to high resolution transmission model validation are displayed...

Infrared temperature and gas measurements at the Haderslev power and heat plan[Denmark]; Infraroede temperatur- og gasmaelinger Haderslev Kraftvarmevaerk

Energy Technology Data Exchange (ETDEWEB)

Clausen, Soennik

2007-04-15

Report describe results from a two week measurement campaign at Haderslev Kraftvarmevaerk in 2006 as a part of PSO-project 5727 'On-line optimization of waste incinerators'. Non-contact gas temperature and gas composition was measured simultaneously with a FTIR spectrometer coupled to a water-cooled fiber-optic probe. Gas temperature and H{sub 2}O, CO{sub 2}, CO, C{sub x}H{sub y} and HCl concentrations was extracted from measured spectra of emitted thermal radiation from gas slab over a 25 cm path. Measurements where performed in different positions to obtain a overview of flow behavior and conditions during stable operation and during a step in operation conditions, e.g. changing combustion air flows. Furthermore, surface temperature of grate was monitored with a thermal camera and a cross stack reference measurement on hot outlet gas was performed with a FTIR spectrometer. (au)

Mass spectrometric measurements of driver gas arrival in the T4 free-piston shock-tunnel

Science.gov (United States)

Boyce, R. R.; Takahashi, M.; Stalker, R. J.

2005-12-01

Available test time is an important issue for ground-based flow research, particularly for impulse facilities such as shock tunnels, where test times of the order of several ms are typical. The early contamination of the test flow by the driver gas in such tunnels restricts the test time. This paper reports measurements of the driver gas arrival time in the test section of the T4 free-piston shock-tunnel over the total enthalpy range 3 17 MJ/kg, using a time-of-flight mass spectrometer. The results confirm measurements made by previous investigators using a choked duct driver gas detector at these conditions, and extend the range of previous mass spectrometer measurements to that of 3 20 MJ/kg. Comparisons of the contamination behaviour of various piston-driven reflected shock tunnels are also made.

The ion mobility spectrometer for high explosive vapor detection

International Nuclear Information System (INIS)

Cohen, M.J.; Stimac, R.M.; Wernlund, R.F.

1984-01-01

The Phemto-Chem /SUP R/ Model 100 Ion Mobility Spectrometer (IMS) operates in air and measures a number of explosive vapors at levels as low as partsper-trillion in seconds. The theory and operation of this instrument is discussed. The IMS inhales the vapor sample in a current of air and generates characteristic ions which are separated by time-of -ion drift in the atmospheric pressure gas. Quantitative results, using a dilution tunnel and standard signal generator with TNT, nitroglycerine, ethylene glycol dinitrate, cyclohexanone, methylamine, octafluoronaphthalene and hexafluorobenzene, are given. Rapid sample treatment with sample concentrations, microprocessor signal readout and chemical identification, offer a realistic opportunity of rapid explosive vapor detection at levels down to 10 -14 parts by volume in air

Low Power Consumption Lasers for Miniature Optical Spectrometers for Trace Gas Analysis

Science.gov (United States)

Forouhar, S.; Frez, C.; Franz, K. J.; Ksendzov, A.; Qiu, Y.; Soibel, K. A.; Chen, J.; Hosoda, T.; Kipshidze, G.; Shterengas, L.;

Development of conjugate methods with gas chromatography for inorganic compounds analysis

International Nuclear Information System (INIS)

Baccan, N.

1975-01-01

The application of gas chromatography combined with mass spectrometry or with nuclear methods for the analysis of inorganic compounds is studied. The advantages of the use of a gas chromatograph coupled with a quadrupole mass spectrometer or with a high resolution radiation detector, are discussed. We also studied the formation and solvent extraction of metal chelates; an aliquot of the organic phase was directly injected into the gas chromatograph and the eluted compounds were detected by mass spectrometry or, when radioactive, by nuclear methods. (author)

Signal-to-noise ratio of FT-IR CO gas spectra

DEFF Research Database (Denmark)

Bak, J.; Clausen, Sønnik

1999-01-01

in emission and transmission spectrometry, an investigation of the SNR in CO gas spectra as a function of spectral resolution has been carried out. We present a method to (1) determine experimentally the SNR at constant throughput, (2) determine the SNR on the basis of measured noise levels and Hitran......The minimum amount of a gaseous compound which can be detected and quantified with Fourier transform infrared (FT-IR) spectrometers depends on the signal-to-noise ratio (SNR) of the measured gas spectra. In order to use low-resolution FT-IR spectrometers to measure combustion gases like CO and CO2...... simulated signals, and (3) determine the SNR of CO from high to low spectral resolutions related to the molecular linewidth and vibrational-rotational lines spacing. In addition, SNR values representing different spectral resolutions but scaled to equal measurement times were compared. It was found...

Imaging spectrometer using a liquid crystal tunable filter

Science.gov (United States)

Chrien, Thomas G.; Chovit, Christopher; Miller, Peter J.

1993-09-01

A demonstration imaging spectrometer using a liquid crystal tunable filter (LCTF) was built and tested on a hot air balloon platform. The LCTF is a tunable polarization interference or Lyot filter. The LCTF enables a small, light weight, low power, band sequential imaging spectrometer design. An overview of the prototype system is given along with a description of balloon experiment results. System model performance predictions are given for a future LCTF based imaging spectrometer design. System design considerations of LCTF imaging spectrometers are discussed.

Micro Plasma Spectrometer

Data.gov (United States)

National Aeronautics and Space Administration — The purpose of this IRAD project is to develop a preliminary design elements of miniature electron and ion plasma spectrometers and supporting electronics, focusing...

Gas, Dust, and Quenching of Dusty Galaxies in the Early Universe

Science.gov (United States)

Spilker, Justin Scott

In this dissertation, I study various aspects related to the gas and star formation in dusty star-forming galaxies in the distant universe. My dissertation is heavily based on observations made by the Atacama Large Millimeter/submillimeter Array (ALMA), observing a sample of gravitationally lensed high-redshift dusty galaxies originally discovered by the South Pole Telescope (SPT). In addition to the introductions to the individual chapters, Chapter 1 provides a broader background to the study of these objects and places them in the overall context of galaxy evolution. In Chapter 2 I describe a technique designed to search for faint molecular lines in the spectrum of high-redshift dusty galaxies. The brightest molecular lines in the spectra of these objects are due to carbon monoxide, but a host of other species are present in the interstellar media. These other molecules trace gas of a wide range of temperatures and densities, but are generally ten times fainter than the brighter CO lines. I detected several other molecular lines, and used them to characterize the conditions of the interstellar gas. This work was published in Spilker et al. (2014). In Chapter 3, I describe a technique for modeling the effects of gravitational lensing which is optimized for data from interferometers such as ALMA. Using these models and data for a large sample of objects from ALMA, I studied the intrinsic properties of the sample such as the source sizes and luminosities. I used these intrinsic properties to revisit topics from the literature which benefit from the additional size information I determined. This work was published in Spilker et al. (2016). In Chapter 4, I use the modeling technique I developed to investigate the relationship between the star formation and the cold molecular gas from which stars form in two objects selected from the SPT sample. Using the models of the source, I was able to determine the mass of molecular gas in these objects using several independent

First solar radio spectrometer deployed in Scotland, UK

Science.gov (United States)

Monstein, Christian

2012-10-01

A new Callisto solar radio spectrometer system has recently been installed and set into operation at Acre Road Observatory, a facility of University of Glasgow, Scotland UK. There has been an Observatory associated with Glasgow University since 1757, and they presently occupy two different sites. The main observatory ('Acre Road') is close to the Garscube Estate on the outskirts of the city of Glasgow. The outstation ('Cochno', housing the big 20 inch Grubb Parsons telescope) is located farther out at a darker site in the Kilpatrick Hills. The Acre Road Observatory comprises teaching and research labs, a workshop, the main dome housing the 16 inch Meade, the solar dome, presently housing the 12 inch Meade, a transit house containing the transit telescope, a 3m HI radio telescope and a 408 MHz pulsar telescope. They also have 10 and 8 inch Meade telescopes and several 5 inch Celestron instruments. There is a small planetarium beneath the solar dome. The new Callisto instrument is mainly foreseen for scientific solar burst observations as well as for student projects and for 'bad-weather' outreach activities.

Compact Spectrometers Based on Linear Variable Filters

Data.gov (United States)

National Aeronautics and Space Administration — Demonstrate a linear-variable spectrometer with an H2RG array. Linear Variable Filter (LVF) spectrometers provide attractive resource benefits – high optical...

Recent Developments of an Opto-Electronic THz Spectrometer for High-Resolution Spectroscopy.

Science.gov (United States)

Hindle, Francis; Yang, Chun; Mouret, Gael; Cuisset, Arnaud; Bocquet, Robin; Lampin, Jean-François; Blary, Karine; Peytavit, Emilien; Akalin, Tahsin; Ducournau, Guillaume

2009-01-01

A review is provided of sources and detectors that can be employed in the THz range before the description of an opto-electronic source of monochromatic THz radiation. The realized spectrometer has been applied to gas phase spectroscopy. Air-broadening coefficients of HCN are determined and the insensitivity of this technique to aerosols is demonstrated by the analysis of cigarette smoke. A multiple pass sample cell has been used to obtain a sensitivity improvement allowing transitions of the volatile organic compounds to be observed. A solution to the frequency metrology is presented and promises to yield accurate molecular line center measurements.

Recent Developments of an Opto-Electronic THz Spectrometer for High-Resolution Spectroscopy

Science.gov (United States)

Hindle, Francis; Yang, Chun; Mouret, Gael; Cuisset, Arnaud; Bocquet, Robin; Lampin, Jean-François; Blary, Karine; Peytavit, Emilien; Akalin, Tahsin; Ducournau, Guillaume

2009-01-01

A review is provided of sources and detectors that can be employed in the THz range before the description of an opto-electronic source of monochromatic THz radiation. The realized spectrometer has been applied to gas phase spectroscopy. Air-broadening coefficients of HCN are determined and the insensitivity of this technique to aerosols is demonstrated by the analysis of cigarette smoke. A multiple pass sample cell has been used to obtain a sensitivity improvement allowing transitions of the volatile organic compounds to be observed. A solution to the frequency metrology is presented and promises to yield accurate molecular line center measurements. PMID:22291552

Laboratory investigations of Titan haze formation: In situ measurement of gas and particle composition

Science.gov (United States)

Hörst, Sarah M.; Yoon, Y. Heidi; Ugelow, Melissa S.; Parker, Alex H.; Li, Rui; de Gouw, Joost A.; Tolbert, Margaret A.

2018-02-01

Prior to the arrival of the Cassini-Huygens spacecraft, aerosol production in Titan's atmosphere was believed to begin in the stratosphere where chemical processes are predominantly initiated by far ultraviolet (FUV) radiation. However, measurements taken by the Cassini Ultraviolet Imaging Spectrograph (UVIS) and Cassini Plasma Spectrometer (CAPS) indicate that haze formation initiates in the thermosphere where there is a greater flux of extreme ultraviolet (EUV) photons and energetic particles available to initiate chemical reactions, including the destruction of N2. The discovery of previously unpredicted nitrogen species in measurements of Titan's atmosphere by the Cassini Ion and Neutral Mass Spectrometer (INMS) indicates that nitrogen participates in the chemistry to a much greater extent than was appreciated before Cassini. The degree of nitrogen incorporation in the haze particles is important for understanding the diversity of molecules that may be present in Titan's atmosphere and on its surface. We have conducted a series of Titan atmosphere simulation experiments using either spark discharge (Tesla coil) or FUV photons (deuterium lamp) to initiate chemistry in CH4/N2 gas mixtures ranging from 0.01% CH4/99.99% N2 to 10% CH4/90% N2. We obtained in situ real-time measurements using a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) to measure the particle composition as a function of particle size and a proton-transfer ion-trap mass spectrometer (PIT-MS) to measure the composition of gas phase products. These two techniques allow us to investigate the effect of energy source and initial CH4 concentration on the degree of nitrogen incorporation in both the gas and solid phase products. The results presented here confirm that FUV photons produce not only solid phase nitrogen bearing products but also gas phase nitrogen species. We find that in both the gas and solid phase, nitrogen is found in nitriles rather than amines and that both the

Spectrometer for neutron inelastic scattering investigations of microsamples

International Nuclear Information System (INIS)

Balagurov, A.M.; Kozlenko, D.P.; Platonov, S.L.; Savenko, B.N.; Glazkov, V.P.; Krasnikov, Yu.M.; Naumov, I.V.; Pukhov, A.V.; Somenkov, V.A.; Syrykh, G.F.

1997-01-01

A new neutron spectrometer for investigation of inelastic neutron scattering on polycrystal microsamples under high pressure in sapphire and diamond anvils cells is described. The spectrometer is operating at the IBR-2 pulsed reactor in JINR. Parameters and methodical peculiarities of the spectrometer and the examples of experimental studies are given. (author)

Universal stability curve for pattern formation in pulsed gas-solid fluidized beds of sandlike particles

Science.gov (United States)

de Martín, Lilian; Ottevanger, Coen; van Ommen, J. Ruud; Coppens, Marc-Olivier

2018-03-01

A granular layer can form regular patterns, such as squares, stripes, and hexagons, when it is fluidized with a pulsating gas flow. These structures are reminiscent of the well-known patterns found in granular layers excited through vibration, but, contrarily to them, they have been hardly explored since they were first discovered. In this work, we investigate experimentally the conditions leading to pattern formation in pulsed fluidized beds and the dimensionless numbers governing the phenomenon. We show that the onset to the instability is universal for Geldart B (sandlike) particles and governed by the hydrodynamical parameters Γ =ua/(utϕ ¯) and f /fn , where ua and f are the amplitude and frequency of the gas velocity, respectively, ut is the terminal velocity of the particles, ϕ ¯ is the average solids fraction, and fn is the natural frequency of the bed. These findings suggest that patterns emerge as a result of a parametric resonance between the kinematic waves originating from the oscillating gas flow and the bulk dynamics. Particle friction plays virtually no role in the onset to pattern formation, but it is fundamental for pattern selection and stabilization.

Characterization of ion processes in a GC/DMS air quality monitor by integration of the instrument to a mass spectrometer.

Science.gov (United States)

Limero, T F; Nazarov, E G; Menlyadiev, M; Eiceman, G A

2015-02-07

The air quality monitor (AQM), which included a portable gas chromatograph (GC) and a detector was interfaced to a mass spectrometer (MS) by introducing flow from the GC detector to the atmospheric pressure ion source of the MS. This small GC system, with a gas recirculation loop for carrier and detector make-up gases, comprised an inlet to preconcentrate volatile organic compounds (VOCs) in air, a thermal desorber before the GC column, a differential mobility spectrometer (DMS), and another DMS as an atmospheric pressure ionization source for the MS. Return flow to the internally recirculated air system of the AQM's DMS was replenished using purified air. Although ions and unreacted neutral vapors flowed from the detector through Viton® tubing into the source of the MS, ions were not detected in the MS without the auxillary ion source, (63)Ni as in the mobility detector. The GC-DMS-MS instrument provided a 3-D measurement platform (GC, DMS, and MS analysis) to explore the gas composition inside the GC-DMS recirculation loop and provide DMS-MS measurement of the components of a complex VOC mixture with performance significantly enhanced by mass-analysis, either with mass spectral scans or with an extracted ion chromatogram. This combination of a mobility spectrometer and a mass spectrometer was possible as vapors and ions are carried together through the DMS analyzer, thereby preserving the chromatographic separation efficiency. The critical benefit of this instrument concept is that all flows in and through the thoroughly integrated GC-DMS analyzer are kept intact allowing a full measure of the ion and vapor composition in the complete system. Performance has been evaluated using a synthetic air sample and a sample of airborne vapors in a laboratory. Capabilities and performance values are described using results from AQM-MS analysis of purified air, ambient air from a research laboratory in a chemistry building, and a sample of synthetic air of known composition

Long-term changes in the sensitivity of quadrupole mass spectrometers

International Nuclear Information System (INIS)

Blanchard, W.R.; McCarthy, P.J.; Dylla, H.F.; LaMarche, P.H.; Simpkins, J.E.

1986-02-01

We routinely use quadrupole mass spectrometers (QMS) to monitor vacuum conditions, gas purity, and plasma-wall interactions in the Tokamak Fusion Test Reactor (TFTR) at Princeton. Two QMS systems have been operating on TFTR continuously for a two-year period. Both QMS systems are absolutely calibrated at weekly intervals using a six-part standard gas mixture. The calibration procedure is based on the use of transfer standards (ion gauge and capacitance manometer) that are calibrated against a primary standard (spinning rotor gauge) on an external vacuum system. We have identified variations in the efficiency of the QMS ionizer and drifts in the sensitivity of the electron multiplier ion detector to be the major reasons for the observed changes in overall OMS sensitivity. Weekly variations in sensitivity greater than 100% have been observed following system bakeout at 150 0 C and with the use of rhenium filaments which were initially in the QMS ionizer. Operation of the QMS systems with tungsten filaments and at constant temperature has yielded more stable operation with weekly sensitivity changes generally being less than 10%. 7 refs., 7 figs

RITA: The reinvented triple axis spectrometer

Energy Technology Data Exchange (ETDEWEB)

Mason, T.E. [Toronto Univ., ON (Canada). Dept. of Physics; Clausen, K.N.; Aeppli, G.; McMorrow, D.R.; Kjems, J.K. [Risoe National Lab., Roskilde (Denmark)

1995-11-01

Risoe National Laboratory was reported to be in the process of developing a new spectrometer design, RITA, based on the triple axis design. The spectrometer will attempt to incorporate more recent innovations such as multilayer supermirrors and microstrip proportional counters into a rethinking of the triple-axis spectrometer. By optimizing the beam optics, using supermirrors and extending the analyser to map regions of (Q, {omega}) space using an array of independently controllable pyrolytic graphite crystals focussed on an area detector, it was hoped that the efficiency of single-crystal inelastic experiments could be increased by as much as a factor of 20. 7 figs., 20 refs.

Development and validation of an universal interface for compound-specific stable isotope analysis of chlorine (37Cl/35Cl) by GC-high-temperature conversion (HTC)-MS/IRMS.

Science.gov (United States)

Renpenning, Julian; Hitzfeld, Kristina L; Gilevska, Tetyana; Nijenhuis, Ivonne; Gehre, Matthias; Richnow, Hans-Hermann

2015-03-03

A universal application of compound-specific isotope analysis of chlorine was thus far limited by the availability of suitable analysis techniques. In this study, gas chromatography in combination with a high-temperature conversion interface (GC-HTC), converting organic chlorine in the presence of H2 to gaseous HCl, was coupled to a dual-detection system, combining an ion trap mass spectrometer (MS) and isotope-ratio mass spectrometer (IRMS). The combination of the MS/IRMS detection enabled a detailed characterization, optimization, and online monitoring of the high-temperature conversion process via ion trap MS as well as a simultaneous chlorine isotope analysis by the IRMS. Using GC-HTC-MS/IRMS, chlorine isotope analysis at optimized conversion conditions resulted in very accurate isotope values (δ(37)Cl(SMOC)) for measured reference material with known isotope composition, including chlorinated ethylene, chloromethane, hexachlorocyclohexane, and trichloroacetic acids methyl ester. Respective detection limits were determined to be <15 nmol Cl on column with achieved precision of <0.3‰.

Development of an ion time-of-flight spectrometer for neutron depth profiling

Science.gov (United States)

Cetiner, Mustafa Sacit

electric field accelerates and then decelerates the emitted secondary electron beam, the magnetic field steers the beam away from the source and focuses it onto the electron microchannel plate detector. The initial momentum distribution of the electron beam is observed to have profound effect on the electron transport time. Hence, the CEM field spectrometer measurements suffer more from spectral broadening at similar operating parameters. The CEM field spectrometer measurements were obtained with a 210Po alpha source at the Penn State Radiation Science and Engineering Center, University Park, PA. Although the PEM field spectrometer suffers less from electron transport time dispersion, the CEM field spectrometer is more suited for application to neutron depth profiling. The multiple small-diameter apertures used in the PEM field configuration considerably reduces the geometric efficiency of the spectrometer. Most of the neutron depth profiling measurements, where isotropic emission of charged particles is observed, have relatively low count rates; hence, high detection efficiency is essential.

Low-pressure, multistep, multiwire proportional counter for the time-of-flight isochronous spectrometer

International Nuclear Information System (INIS)

Vieira, D.J.

1985-01-01

A low-pressure, multistep, multiwire proportional counter (MSMWPC) has been developed for the characterization and testing of the time-of-flight isochronous (TOFI) spectrometer and its associated secondary-beam transport line. This type of counter was selected because of its high sensitivity, large dynamic range, and good position (0.2 mm FWHM) and timing (180 ps FWHM) resolution. Furthermore, because the counter operates at low gas pressures (1-10 torr) and high electric-field strengths, which enable short collection times, it can be used as a transmission counter with thin gas-isolation windows and it can operate at high counting rates. Here the authors discuss the basic operating principle of the MSMWPC, describe the technical details of the detector and signal processing, and report on the performance they have measured for alpha particles and fission fragments

Construction of γπ0 spectrometer and photon tagging facility at Bates Linear Accelerator. Final report, July 31, 1979-July 31, 1980

International Nuclear Information System (INIS)

Booth, E.C.

1981-08-01

The funds provided under Contract No. DE-AC02-79ER10486 were totally expended for hardware and supplies required by two related devices at the Bates Linear Accelerator. These were a photon tagging facility and a γπ 0 spectrometer in Beam Line C of the new South Experimental Hall. Construction was begun in November of 1979 and both systems became fully operational in the summer of 1981. Preliminary data was taken in 1980 with a prototype γπ 0 spectrometer will be carried out in the fall of 1981 and spring of 1982. The photon tagging system has been used successfully to calibrate the γπ 0 spectrometer for the BU - MIT collaboration and to test a lead glass detector system for Brandeis University

Infrared gas phase study on plasma-polymer interactions in high-current diffuse dielectric barrier discharge

NARCIS (Netherlands)

Liu, Y.; Welzel, S.; Starostin, S. A.; van de Sanden, M. C. M.; Engeln, R.; de Vries, H. W.

2017-01-01

A roll-to-roll high-current diffuse dielectric barrier discharge at atmospheric pressure was operated in air and Ar/N2/O2 gas mixtures. The exhaust gas from the discharge was studied using a high-resolution Fourier-transform infrared spectrometer in the range from 3000 to 750?cm-1 to unravel the

High resolution 14 MeV neutron spectrometer

International Nuclear Information System (INIS)

Pillon, M.

1986-01-01

A neutron spectrometer, based both on the track position identification and the energy measurement of recoiling protons from a hydrogenous radiator is proposed. The expected performance limits of this spectrometer with regard to energy resolution (deltaE/E), efficiency (epsilon) and counting rate are evaluated in five different configurations. The results show the possibility of deriving an optimized spectrometer design for applications on large fusion devices such as JET and NET with an energy resolution up 1% at 14 MeV

Emissions of volatile organic compounds (VOCs) from oil and natural gas activities: compositional comparison of 13 major shale basins via NOAA airborne measurements

Science.gov (United States)

Gilman, J.; Lerner, B. M.; Aikin, K. C.; De Gouw, J. A.; Koss, A.; Yuan, B.; Warneke, C.; Peischl, J.; Ryerson, T. B.; Holloway, J. S.; Graus, M.; Tokarek, T. W.; Isaacman-VanWertz, G. A.; Sueper, D.; Worsnop, D. R.

2015-12-01

The recent and unprecedented increase in natural gas production from shale formations is associated with a rise in the production of non-methane volatile organic compounds (VOCs) including natural gas plant liquids (e.g., ethane, propane, and butanes) and liquid lease condensate (e.g., pentanes, hexanes, aromatics and cycloalkanes). Since 2010, the production of natural gas liquids and the amount of natural gas vented/flared has increased by factors of ~1.28 and 1.57, respectively (U.S. Energy and Information Administration), indicating an increasingly large potential source of hydrocarbons to the atmosphere. Emission of VOCs may affect local and regional air quality due to the potential to form tropospheric ozone and organic particles as well as from the release of toxic species such as benzene and toluene. The 2015 Shale Oil and Natural Gas Nexus (SONGNex) campaign studied emissions from oil and natural gas activities across the central United States in order to better understand their potential air quality and climate impacts. Here we present VOC measurements from 19 research flights aboard the NOAA WP-3D over 11 shale basins across 8 states. Non-methane hydrocarbons were measured using an improved whole air sampler (iWAS) with post-flight analysis via a custom-built gas chromatograph-mass spectrometer (GC-MS). The whole air samples are complimented by higher-time resolution measurements of methane (Picarro spectrometer), ethane (Aerodyne spectrometer), and VOCs (H3O+ chemical ionization mass spectrometer). Preliminary analysis show that the Permian Basin on the New Mexico/Texas border had the highest observed VOC mixing ratios for all basins studied. We will utilize VOC enhancement ratios to compare the composition of methane and VOC emissions for each basin and the associated reactivities of these gases with the hydroxyl radical, OH, as a proxy for potential ozone formation.

RADIO-FREQUENCY MASS SPECTROMETERS AND THEIR APPLICATIONS IN SPACE

Energy Technology Data Exchange (ETDEWEB)

Gilmour, Jr., A. S.

1963-08-15

The operation of three common radio-frequency mass spectrometers is described, and their performances are compared. Their limitations are pointed out. It is concluded that the quadrupole spectrometer has fewer limitations and is more generally useful in space probes than the other devices. Some present and proposed uses of spectrometers in space are discussed, and the problem of contamination of the atmosphere being sampled by the spectrometer is reviewed. (auth)

The portable micro-computerized multichannel spectrometer for geological application

International Nuclear Information System (INIS)

Fang Fang; Jia Wenyi; Zou Rongsheng; Ma Yingjie; Zhou Jianbin

1999-01-01

The portable micro-computerized multichannel spectrometer is based on the book computer and employs the A/D integrated circuit with 12 bits. It is a 2048 channel spectrometer which is consisted of hardware and software. The author analyzed the hardware circuit and software construction of the micro-computerized multichannel spectrometer which is suitable for filed geological application. The main technical specifications and application of the new multichannel spectrometer were also discussed

The portable micro-computerized multichannel spectrometer for geological application

International Nuclear Information System (INIS)

Fang Fang; Jia Wenyi; Zhou Rongsheng; Ma Yingjie; Zhou Jianbin

1999-01-01

The portable micro-computerized multichannel spectrometer is based on the book computer and employs the A/D integrated circuit with 12 bits. It is a 2048 channel spectrometer which consists of hardware and software. The author analyzed the hardware circuit and software construction of the micro-computerized multichannel spectrometer which is suitable for field geological application. The main technical specifications and application of the new multichannel spectrometer were also discussed

Polarized epithermal neutron spectrometer at KENS

International Nuclear Information System (INIS)

Kohgi, M.

1983-01-01

A spectrometer employing a white, epithermal, polarized neutron beam is under construction at KENS. The neutron polarization is achieved by passage through a dynamically polarized proton filter (DPPF). The results of the test experiments show that the DPPF method is promising in obtaining polarized epithermal neutron beam. The basic design of the spectrometer is described

Calculational approach to ionization spectrometer design

International Nuclear Information System (INIS)

Gabriel, T.A.

1974-01-01

Many factors contribute to the design and overall performance of an ionization spectrometer. These factors include the conditions under which the spectrometer is to be used, the required performance, the development of the hadronic and electromagnetic cascades, leakage and binding energies, saturation effects of densely ionizing particles, nonuniform light collection, sampling fluctuations, etc. The calculational procedures developed at Oak Ridge National Laboratory that have been applied to many spectrometer designs and that include many of the influencing factors in spectrometer design are discussed. The incident-particle types which can be considered with some generality are protons, neutrons, pions, muons, electrons, positrons, and gamma rays. Charged kaons can also be considered but with less generality. The incident-particle energy range can extend into the hundreds of GeV range. The calculations have been verified by comparison with experimental data but only up to approximately 30 GeV. Some comparisons with experimental data are also discussed and presented so that the flexibility of the calculational methods can be demonstrated. (U.S.)

Gas laser spectrometer for nuclear investigation at nucleonic stability limit. (project)

International Nuclear Information System (INIS)

Myshinskij, G.V.

1989-01-01

It is proposed to obtain the atomic beam of the proton-rich and neutron-rich nuclides with half-lives of up to 1 ms, by using the gas-jet technique. Subsequently their properties are investigated using the methods of laser resonance ionization and nuclear spectroscopy. 8 refs.; 4 figs

Fast-response personal Moessbauer spectrometer

International Nuclear Information System (INIS)

Kholmetskij, A.L.; Mashlan, M.; Misevich, O.V.; Evdokimov, V.A.; Lopatik, A.R.; Zhak, D.; Fedorov, A.A.; Snashel, V.

1995-01-01

Spectrometer design to record transmission Moessbauer spectra is described. The spectrometer consists of PC/AT computer with 1 mb memory and 40 mb hard disk, of EPSON LX 850 printer, of color monitor with VGA graphical adapter, of data accumulation system, of speed generator, of motion system with minivibrator, of scintillation detector with YA10 3 :Ce scintillator, of single-channel amplitude analyzer, of measuring bench and of 57 Co(Rh) source. 1 ref.; 1 fig

The BTeV main spectrometer

International Nuclear Information System (INIS)

Sheldon, P.D.

2001-01-01

BTeV is a second generation B-factory experiment that will use a double-arm, forward spectrometer in the C0 experimental hall at the Fermilab Tevatron. I will describe the motivation and design of the 'main spectrometer', consisting of a ring-imaging Cherenkov system for charged particle identification, an electromagnetic calorimeter of lead-tungstate crystals, a proportional tube muon system with magnetized filtering steel, and a straw-tube and silicon strip charged particle tracking system

Miniature neutron-alpha activation spectrometer

International Nuclear Information System (INIS)

Rhodes, Edgar; Goldsten, John; Holloway, James Paul; He, Zhong

2002-01-01

We are developing a miniature neutron-alpha activation spectrometer for in-situ analysis of chem-bio samples, including rocks, fines, ices, and drill cores, suitable for a lander or Rover platform for Mars or outer-planet missions. In the neutron-activation mode, penetrating analysis will be performed of the whole sample using a γ spectrometer and in the α-activation mode, the sample surface will be analyzed using Rutherford-backscatter and x-ray spectrometers. Novel in our approach is the development of a switchable radioactive neutron source and a small high-resolution γ detector. The detectors and electronics will benefit from remote unattended operation capabilities resulting from our NEAR XGRS heritage and recent development of a Ge γ detector for MESSENGER. Much of the technology used in this instrument can be adapted to portable or unattended terrestrial applications for detection of explosives, chemical toxins, nuclear weapons, and contraband

The high-acceptance dielectron spectrometer HADES

International Nuclear Information System (INIS)

Agakichiev, G.; Destefanis, M.; Gilardi, C.; Kirschner, D.; Kuehn, W.; Lange, J.S.; Lehnert, J.; Lichtblau, C.; Lins, E.; Metag, V.; Mishra, D.; Novotny, R.; Pechenov, V.; Pechenova, O.; Perez Cavalcanti, T.; Petri, M.; Ritman, J.; Salz, C.; Schaefer, D.; Skoda, M.; Spataro, S.; Spruck, B.; Toia, A.; Agodi, C.; Coniglione, R.; Cosentino, L.; Finocchiaro, P.; Maiolino, C.; Piattelli, P.; Sapienza, P.; Vassiliev, D.; Alvarez-Pol, H.; Belver, D.; Cabanelas, P.; Castro, E.; Duran, I.; Fernandez, C.; Fuentes, B.; Garzon, J.A.; Kurtukian-Nieto, T.; Rodriguez-Prieto, G.; Sabin-Fernandez, J.; Sanchez, M.; Vazquez, A.; Atkin, E.; Volkov, Y.; Badura, E.; Bertini, D.; Bielcik, J.; Bokemeyer, H.; Dahlinger, M.; Daues, H.W.; Galatyuk, T.; Garabatos, C.; Gonzalez-Diaz, D.; Hehner, J.; Heinz, T.; Hoffmann, J.; Holzmann, R.; Koenig, I.; Koenig, W.; Kolb, B.W.; Kopf, U.; Lang, S.; Leinberger, U.; Magestro, D.; Muench, M.; Niebur, W.; Ott, W.; Pietraszko, J.; Rustamov, A.; Schicker, R.M.; Schoen, H.; Schoen, W.; Schroeder, C.; Schwab, E.; Senger, P.; Simon, R.S.; Stelzer, H.; Traxler, M.; Yurevich, S.; Zovinec, D.; Zumbruch, P.; Balanda, A.; Kozuch, A.; Przygoda, W.; Bassi, A.; Bassini, R.; Boiano, C.; Bartolotti, A.; Brambilla, S.; Bellia, G.; Migneco, E.; Belyaev, A.V.; Chepurnov, V.; Chernenko, S.; Fateev, O.V.; Ierusalimov, A.P.; Smykov, L.; Troyan, A.Yu.; Zanevsky, Y.V.; Benovic, M.; Hlavac, S.; Turzo, I.; Boehmer, M.; Christ, T.; Eberl, T.; Fabbietti, L.; Friese, J.; Gernhaeuser, R.; Gilg, H.; Homolka, J.; Jurkovic, M.; Kastenmueller, A.; Kienle, P.; Koerner, H.J.; Kruecken, R.; Maier, L.; Maier-Komor, P.; Sailer, B.; Schroeder, S.; Ulrich, A.; Wallner, C.; Weber, M.; Wieser, J.; Winkler, S.; Zeitelhack, K.; Boyard, J.L.; Genolini, B.; Hennino, T.; Jourdain, J.C.; Moriniere, E.; Pouthas, J.; Ramstein, B.; Rosier, P.; Roy-Stephan, M.; Sudol, M.; Braun-Munzinger, P.; Diaz, J.; Dohrmann, F.; Dressler, R.; Enghardt, W.; Heidel, K.; Hutsch, J.; Kanaki, K.; Kotte, R.; Naumann, L.; Sobiella, M.; Wuestenfeld, J.; Zhou, P.; Dybczak, A.; Jaskula, M.; Kajetanowicz, M.; Kidon, L.; Korcyl, K.; Kulessa, R.; Malarz, A.; Michalska, B.; Otwinowski, J.; Ploskon, M.; Prokopowicz, W.; Salabura, P.; Szczybura, M.; Trebacz, R.; Walus, W.; Wisniowski, M.; Wojcik, T.; Froehlich, I.; Lippmann, C.; Lorenz, M.; Markert, J.; Michel, J.; Muentz, C.; Pachmayer, Y.C.; Rosenkranz, K.; Stroebele, H.; Sturm, C.; Tarantola, A.; Teilab, K.; Wang, Y.; Zentek, A.; Golubeva, M.; Guber, F.; Ivashkin, A.; Karavicheva, T.; Kurepin, A.; Lapidus, K.; Reshetin, A.; Sadovsky, A.; Shileev, K.; Tiflov, V.; Grosse, E.; Kaempfer, B.; Iori, I.; Krizek, F.; Kugler, A.; Marek, T.; Novotny, J.; Pleskac, R.; Pospisil, V.; Sobolev, Yu.G.; Suk, M.; Taranenko, A.; Tikhonov, A.; Tlusty, P.; Wagner, V.; Mousa, J.; Parpottas, Y.; Tsertos, H.; Nekhaev, A.; Smolyankin, V.; Palka, M.; Roche, G.; Schmah, A.; Stroth, J.

2009-01-01

HADES is a versatile magnetic spectrometer aimed at studying dielectron production in pion, proton and heavy-ion-induced collisions. Its main features include a ring imaging gas Cherenkov detector for electron-hadron discrimination, a tracking system consisting of a set of 6 superconducting coils producing a toroidal field and drift chambers and a multiplicity and electron trigger array for additional electron-hadron discrimination and event characterization. A two-stage trigger system enhances events containing electrons. The physics program is focused on the investigation of hadron properties in nuclei and in the hot and dense hadronic matter. The detector system is characterized by an 85% azimuthal coverage over a polar angle interval from 18 to 85 , a single electron efficiency of 50% and a vector meson mass resolution of 2.5%. Identification of pions, kaons and protons is achieved combining time-of-flight and energy loss measurements over a large momentum range (0.1< p< 1.0 GeV/c). This paper describes the main features and the performance of the detector system. (orig.)

Design of a large superconducting spectrometer magnet

International Nuclear Information System (INIS)

Shintomi, T.; Makida, Y.; Mito, T.; Yamanoi, Y.; Hashimito, O.; Nagae, T.

1989-04-01

The superconducting spectrometer magnet for nuclear physics experiments has been under construction by Institute for Nuclear Study, University of Tokyo with collaboration from KEK. The magnet has a sector type coil. The magnetic field is 3 T with the magnet gap of 50 cm and the stored energy is 11.8 MJ. The easy operation and maintenance are taken into consideration in addition to usual design concept. Three dimensional magnetic field calculation and the stress analysis have been performed. The code 'QUENCH' was applied to decide the operation current and to check the safety of the coil. As a result, the current of 500 A was selected. The heat leaks were checked and estimated less than 2 W at 4 K. A small refrigerator is to be used for thermal insulations at 80 and 20 K. (author)

Quantification of CO2 and CH4 megacity emissions using portable solar absorption spectrometers

Science.gov (United States)

Frey, Matthias; Hase, Frank; Blumenstock, Thomas; Morino, Isamu; Shiomi, Kei

2017-04-01

Urban areas already contribute to over 50% of the global population, additionally the percentage of the worldwide population living in Metropolitan areas is continuously growing. Thus, a precise knowledge of urban greenhouse gas (GHG) emissions is of utmost importance. Whereas, however, GHG emissions on a nationwide to continental scale can be relatively precisely estimated using satellite observations (and fossil fuel consumption statistics), reliable estimations for local to regional scale emissions pose a bigger problem due to lack of timely and spatially high resolved satellite data and possible biases of passive spectroscopic nadir observations (e.g. enhanced aerosol scattering in a city plume). Furthermore, emission inventories on the city scale might be missing contributions (e.g. methane leakage from gas pipes). Here, newly developed mobile low resolution Fourier Transform spectrometers (Bruker EM27/SUN) are utilized to quantify small scale emissions. This novel technique was successfully tested before by KIT and partners during campaigns in Berlin, Paris and Colorado for detecting emissions from various sources. We present results from a campaign carried out in February - April 2016 in the Tokyo bay area, one of the biggest Metropolitan areas worldwide. We positioned two EM27/SUN spectrometers on the outer perimeter of Tokyo along the prevailing wind axis upwind and downwind of the city source. Before and after the campaign, calibration measurements were performed in Tsukuba with a collocated high resolution FTIR spectrometer from the Total Carbon Column Observing Network (TCCON). During the campaign the observed XCO2 and XCH4 values vary significantly. Additionally, intraday variations are observed at both sites. Furthermore, an enhancement due to the Tokyo area GHG emissions is clearly visible for both XCO2 and XCH4. The observed signals are significantly higher compared to prior campaigns targeting other major cities. We perform a rough estimate of the

Detection of methyl-, dimethyl- and diethylamine using a nitrate-based chemical ionization mass spectrometer

Science.gov (United States)

Jokinen, T.; Smith, J. N.

2016-12-01

New particle formation is one of the main sources of cloud condensation nuclei (CCN) contributing approximately half of the global CCN budget. The initial steps of nucleation have been studied for decades and it is widely accepted that in most places nucleation requires presence of sulphuric acid (SA) and cluster-stabilizing vapours. Recent results from the CLOUD chamber show that only a few pptv levels of dimethylamine (DMA) with SA forms stable clusters at boundary layer conditions. Ambient sulphuric acid is typically measured using nitrate-based chemical ionization mass spectrometers. Unfortunately, because of higher volatilities and stickiness of amines to surfaces, amine measurement techniques suffer from memory effects and high detection limits. Recently it was discovered that DMA can be detected by utilizing nitrate ionization, simultaneously with sulphuric acid measurements. Here we present results of detecting methylamine, dimethylamine and diethylamine using nitrate-based chemical ionization. We conducted a series of measurements with a home-built transverse chemical ionization inlet and a high resolution time-of-flight mass spectrometer (CI-HToF). Amine vapour was produced using permeation tubes. Three stages of dilution were applied at roughly one order-of-magnitude dilution per stage. The diluted flow of selected amine was then introduced to a sample flow rate of 7 slpm, thus achieving a final amine concentration of 10 pptv. All selected amines were detected as clusters with HNO3NO3- and showed linear response with increasing concentrations (0.5-minute integration time). Zero measurements were performed using clean nitrogen gas right after injection of a selected amine. Memory effects were only observed when using high amine concentrations (ppbv levels). Our results indicate that a variety of amines can be detected using nitrate-based chemical ionization mass spectrometers. However, more experiments are required to see if this presented method will be

Tools to probe the universe; Des outils pour sonder l'univers

Energy Technology Data Exchange (ETDEWEB)

Lagage, P.O.; Augueres, J.L.; Amiaux, J.; Cara, Ch.; Fontignie, J.; Rio, Y.; Fermon, C.; Pannetier-Lecoeur, M.; De Vismes, A.; Cordier, B.; Fesquet, M.; Ferrando, Ph.; Authier, M.; Pantin, E.; Glicenstein, J.F.; Boulade, O.; Refregier, A.; Stolarczyk, Th.; Agnese, P.; Rodriguez, L.; Agnese, P.; Pigot, C.; Duband, L.; Limousin, O.; Delagnes, E.; Turck-Chieze, S.; Carton, P.H.; Starck, J.L.; Bournaud, F.; Teyssier, R.; Audit, E.; Brun, A.S.; Leca, P.; Menache, Ch.; Pomarede, D.; Thooris, B.; Meis, C.

2009-07-01

This special issue of Clefs CEA journal is entirely devoted to astrophysics and to the exploration and probing of the Universe. The second part of this dossier, described here, makes a status of the tools used to probe the universe: telescopes, imaging spectrometers, data processing and simulation. Content: A - Telescopes of the future: 1. Seeing further out: JWST: looking back on a past 13 billion years old, Space specifics: the learning curve to know-how, Fabricating a corona-graph mask, SVOM, a satellite to detect the explosions of the first stars to be formed in the Universe; 2. Seeing more precisely: SIMBOL-X, pioneering formation flying, ELT/METIS, a 42-meter giant, One hundred telescopes for the CTA arrays; 3. Seeing wider: Euclid, mapping the extragalactic sky, ANTARES: the neutrino, another cosmic messenger; B - The new generation of imaging spectrometers: Observing the Universe in the submillimeter spectral region, The X-ray Universe, Space cryo-coolers, Out in the extreme, tumultuous Universe, Probing the Sun with GOLF-NG, Focus: From light to imagery; C - Data analysis in astrophysics; D - Numerical simulation in astrophysics: Information technology and theoretical predictions in astrophysics, Supercomputers for a better understanding of the Universe, The visualization of astrophysical simulations, Godunov, a numerical platform for education and research

The LASS [Larger Aperture Superconducting Solenoid] spectrometer

International Nuclear Information System (INIS)

Aston, D.; Awaji, N.; Barnett, B.

1986-04-01

LASS is the acronym for the Large Aperture Superconducting Solenoid spectrometer which is located in an rf-separated hadron beam at the Stanford Linear Accelerator Center. This spectrometer was constructed in order to perform high statistics studies of multiparticle final states produced in hadron reactions. Such reactions are frequently characterized by events having complicated topologies and/or relatively high particle multiplicity. Their detailed study requires a spectrometer which can provide good resolution in momentum and position over almost the entire solid angle subtended by the production point. In addition, good final state particle identification must be available so that separation of the many kinematically-overlapping final states can be achieved. Precise analyses of the individual reaction channels require high statistics, so that the spectrometer must be capable of high data-taking rates in order that such samples can be acquired in a reasonable running time. Finally, the spectrometer must be complemented by a sophisticated off-line analysis package which efficiently finds tracks, recognizes and fits event topologies and correctly associates the available particle identification information. This, together with complicated programs which perform specific analysis tasks such as partial wave analysis, requires a great deal of software effort allied to a very large computing capacity. This paper describes the construction and performance of the LASS spectrometer, which is an attempt to realize the features just discussed. The configuration of the spectrometer corresponds to the data-taking on K + and K - interactions in hydrogen at 11 GeV/c which took place in 1981 and 1982. This constitutes a major upgrade of the configuration used to acquire lower statistics data on 11 GeV/c K - p interactions during 1977 and 1978, which is also described briefly

The LASS (Larger Aperture Superconducting Solenoid) spectrometer

Energy Technology Data Exchange (ETDEWEB)

Aston, D.; Awaji, N.; Barnett, B.; Bienz, T.; Bierce, R.; Bird, F.; Bird, L.; Blockus, D.; Carnegie, R.K.; Chien, C.Y.

1986-04-01

LASS is the acronym for the Large Aperture Superconducting Solenoid spectrometer which is located in an rf-separated hadron beam at the Stanford Linear Accelerator Center. This spectrometer was constructed in order to perform high statistics studies of multiparticle final states produced in hadron reactions. Such reactions are frequently characterized by events having complicated topologies and/or relatively high particle multiplicity. Their detailed study requires a spectrometer which can provide good resolution in momentum and position over almost the entire solid angle subtended by the production point. In addition, good final state particle identification must be available so that separation of the many kinematically-overlapping final states can be achieved. Precise analyses of the individual reaction channels require high statistics, so that the spectrometer must be capable of high data-taking rates in order that such samples can be acquired in a reasonable running time. Finally, the spectrometer must be complemented by a sophisticated off-line analysis package which efficiently finds tracks, recognizes and fits event topologies and correctly associates the available particle identification information. This, together with complicated programs which perform specific analysis tasks such as partial wave analysis, requires a great deal of software effort allied to a very large computing capacity. This paper describes the construction and performance of the LASS spectrometer, which is an attempt to realize the features just discussed. The configuration of the spectrometer corresponds to the data-taking on K and K interactions in hydrogen at 11 GeV/c which took place in 1981 and 1982. This constitutes a major upgrade of the configuration used to acquire lower statistics data on 11 GeV/c K p interactions during 1977 and 1978, which is also described briefly.

Compact imaging Bragg spectrometer for fusion devices

International Nuclear Information System (INIS)

Bertschinger, G.; Biel, W.; Jaegers, H.; Marchuk, O.

2004-01-01

A compact imaging x-ray spectrometer has been designed for tokamaks and stellarators to measure the plasma parameters at different spatial chords. It has been optimized for high spectral resolution and high sensitivity. High spectral resolution is obtained by using solid state detectors and minimizing the imaging errors of the spherical crystals. It is shown, that using spherical crystals the solid angle and hence the throughput can be increased significantly, without compromising the spectral resolution. The design is useful for the measurement of the spectra of He- and H-like ions from Si to Kr. The spectral resolution is sufficient for the measurement of plasma parameters. The temporal resolution is high enough for transport studies by gas puff and laser ablation experiments. The design is based on a modified Johann spectrometer mount, utilizing a spherically bent crystal instead of the cylindrically bent crystal in the traditional Johann mount. The astigmatism of the wavelength selective reflection on the spherical crystal is applied to obtain imaging of an extended plasma source on a two-dimensional detector. For each element, a separate crystal is required, only in few cases, a crystal can be used for the spectra of two elements. For the spectra of most of the He-like ions from Si up to Kr, suitable crystal cuts have been found on quartz, silicon and germanium crystals with Bragg angles in a small interval around the design value of 53.5 deg. All of the crystals have the same radius. They are fixed on a rotational table. The distance to the detector is adjusted by an x-y table to fit to the Rowland circle

The design and performance of a velocity map imaging spectrometer for the study of molecular photoionisation dynamics

Energy Technology Data Exchange (ETDEWEB)

Holland, D.M.P., E-mail: david.holland@stfc.ac.uk [Daresbury Laboratory, Daresbury, Warrington, Cheshire WA4 4AD (United Kingdom); Shaw, D.A. [Daresbury Laboratory, Daresbury, Warrington, Cheshire WA4 4AD (United Kingdom)

2012-12-10

Highlights: Black-Right-Pointing-Pointer Velocity map imaging spectrometer optimised for molecular photoionisation dynamics. Black-Right-Pointing-Pointer Kinetic energy distribution of O{sup +} fragments measured. Black-Right-Pointing-Pointer Effect of autoionisation on photoelectron vibrational populations studied. -- Abstract: The design, construction and performance of a velocity map imaging spectrometer for the study of molecular photoionisation dynamics is described. The spectrometer has been optimised for the efficient collection and detection of particles (electrons or positively charged ions) generated through the interaction of gas phase molecules with synchrotron radiation. A double Einzel lens, incorporated into the flight tube, enhances the collection efficiency of energetic particles. Computer modelling has been used to trace the trajectories of charged particles through the spectrometer and to assess the image quality. A time and position sensitive delay-line detector is used to record the images. Results from two experimental studies are presented to illustrate the capabilities of the spectrometer. In the first, the effect of electronic autoionisation on the vibrationally resolved photoelectron branching ratios of the N{sub 2}{sup +} X {sup 2}{Sigma}{sub g}{sup +} state has been investigated in an excitation range where prominent structure due to Rydberg states occurs in the ion yield curve. The results show that autoionisation leads to rotational branch populations that differ from those observed in direct, non-resonant, photoionisation. In the second, the kinetic energy distribution and the angular distribution of O{sup +} fragments formed in the dissociative photoionisation of molecular oxygen have been measured. The timing properties of the detector have allowed O{sup +} fragments to be separated from O{sub 2}{sup +} parent ions using time-of-flight techniques.

Optimization of time-correlated single photon counting spectrometer

International Nuclear Information System (INIS)

Zhang Xiufeng; Du Haiying; Sun Jinsheng

2011-01-01

The paper proposes a performance improving scheme for the conventional time-correlated single photon counting spectrometer and develops a high speed data acquisition card based on PCI bus and FPGA technologies. The card is used to replace the multi-channel analyzer to improve the capability and decrease the volume of the spectrometer. The process of operation is introduced along with the integration of the spectrometer system. Many standard samples are measured. The experimental results show that the sensitivity of the spectrometer is single photon counting, and the time resolution of fluorescence lifetime measurement can be picosecond level. The instrument could measure the time-resolved spectroscopy. (authors)

Development of a cosmic veto gamma-spectrometer

International Nuclear Information System (INIS)

Burnett, J.L.; Davies, A.V.

2012-01-01

Cosmic radiation contributes significantly towards the background radiation measured by a gamma-spectrometer. A novel cosmic veto gamma-spectrometer has been developed that provides a mean background reduction of 54.5%. The system consists of plastic scintillation plates operated in time-stamp mode to detect coincident muon interactions within an HPGe gamma-spectrometer. The instrument is easily configurable and provides improved sensitivity for radionuclides indicative of nuclear weapons tests and reactor incidents, including 140 Ba, 95 Zr, 99 Mo, 141 Ce, 147 Nd, 131 I, 134 Cs and 137 Cs. This has been demonstrated for Comprehensive Nuclear-Test-Ban Treaty applications to obtain the required 140 Ba MDA of 24 mBq within 2 days counting. Analysis of an air filter sample collected during the Fukushima incident indicates improved sensitivity compared to conventional gamma-spectrometers. (author)

Development of triple axis neutron spectrometer (Paper No. 24)

International Nuclear Information System (INIS)

Pal, B.C.; Wadhwa, N.R.; Goveas, S.H.

1987-02-01

The triple axis neutron spectrometers are the basic instruments intended for use with neutron beams from reactors. Various types of spectrometers, each devoted to different kinds of measurement can be designed and manufactured, once a prototype having all the attributes of a versatile instrument is designed and developed. With the view to achieving self reliance in this field, Central Workshops of Bhabha Atomic Research Centre (BARC), Bombay designed and developed a prototype of triple axis spectrometer meeting the specifications prepared by Nuclear Physics Division of BARC . This spectrometer, with a moving wedge system was successfully manufactured and installed at 'DHRUVA'. Another version of this spectrometer, called the 'Polarised Neutron Spectrometer' was also built and exported to South Korea and installed at Korea Advanced Energy Research Institute, Seoul. This paper deals with basic concept, development of design, engineering of mechanical assemblies, the manufacturing approach and problems encountered during manufacture. (author). 3 figs

HISS spectrometer

International Nuclear Information System (INIS)

Greiner, D.E.

1984-11-01

This talk describes the Heavy Ion Spectrometer System (HISS) facility at the Lawrence Berkeley Laboratory's Bevalac. Three completed experiments and their results are illustrated. The second half of the talk is a detailed discussion of the response of drift chambers to heavy ions. The limitations of trajectory measurement over a large range in incident particle charge are presented

Scintillation forward spectrometer of the SPHERE setup

International Nuclear Information System (INIS)

Anisimov, Yu.S.; Afanas'ev, S.V.; Bondarev, V.K.

1991-01-01

The construction of the forward spectrometer for the 4π SPHERE setup to study multiple production of particles in nucleus-nucleus interactions is described. The measured parameters of the spectrometer detectors are presented. 7 refs.; 14 figs.; 1 tab

Equipment and performance of the Q3D spectrometer installed at the tandem laboratory of Saclay

International Nuclear Information System (INIS)

Berthier, B.

1979-01-01

A quadrupole - dipole - dipole - dipole (Q3D) magnetic spectrometer with proportional gas counter which has been installed at the tandem laboratory of Saclay is described. Typical results are given indicating the performance of the apparatus in studies of heavy ion reactions at tandem energies for which good energy resolution and large solid angles are required. Improvements to allow the detection of heavier masses and less energetic ions with better energy resolution are planned. (U.K.)

α spectrometer of parallel plate grid ionization chamber of high energy resolution

International Nuclear Information System (INIS)

Tong Boting; Wang Jianqing; Dong Mingli; Tang Peijia; Wang Xiaorong; Lin Cansheng

2000-01-01

Parallel plate grid ionization chamber with cathode area of 300 cm 2 was developed and applied to detect minimum α-emitters. It consist of a vacuum system, a gas cycle system of the parallel plate grid ionization chamber, electronics (a high voltage supply, a pre-amplifier and a main amplifier) and a computer-multichannel analyzer. The energy resolution is 23 keV FWHM for the 244 Cm electrostatic precipitated source. The integral background is typically 10 counts/h between 4 and 6 MeV. The detector efficiency is 50%. The minimum detecting activity is 3 x 10 -4 Bq (3σ, 30 hours). This spectrometer is suitable for detecting various samples, such as samples of the soil, water, air, bion, food, structural material, geology, archaeology, α-emitters of after processing and measuring α activity of accounting for and control of nuclear material and monitoring the artificial radioactivity nuclides of environment samples around nuclear facilities. The spectrometer is equipped with apparatus for preparing large area α source by using vacuum deposition or ultrasonic pulverization. The operating program of preparing source is simple. The source thickness can be kept in 40-60 μm/cm 2

Development and Evaluation of a Reverse-Entry Ion Source Orbitrap Mass Spectrometer

Science.gov (United States)

Poltash, Michael L.; McCabe, Jacob W.; Patrick, John W.; Laganowsky, Arthur; Russell, David H.

2018-05-01

As a step towards development of a high-resolution ion mobility mass spectrometer using the orbitrap mass analyzer platform, we describe herein a novel reverse-entry ion source (REIS) coupled to the higher-energy C-trap dissociation (HCD) cell of an orbitrap mass spectrometer with extended mass range. Development of the REIS is a first step in the development of a drift tube ion mobility-orbitrap MS. The REIS approach retains the functionality of the commercial instrument ion source which permits the uninterrupted use of the instrument during development as well as performance comparisons between the two ion sources. Ubiquitin (8.5 kDa) and lipid binding to the ammonia transport channel (AmtB, 126 kDa) protein complex were used as model soluble and membrane proteins, respectively, to evaluate the performance of the REIS instrument. Mass resolution obtained with the REIS is comparable to that obtained using the commercial ion source. The charge state distributions for ubiquitin and AmtB obtained on the REIS are in agreement with previous studies which suggests that the REIS-orbitrap EMR retains native structure in the gas phase.

Present status of the Kyushu University accelerator facility

International Nuclear Information System (INIS)

Mitarai, Shiro; Maeda, Toyokazu; Koga, Yoshihiro

2001-01-01

A large diameter gas stripper was developed and incorporated to a terminal port of the tandem accelerator and test operation was performed. The permeability of low-energy carbon beams in the tandem was remarkably improved with the gas stripper. A recoiled-nuclei mass spectrometer was also developed and facilitated for accurate measurement of the cross sections of 12 C( 4 He, γ) 16 O in cosmic nuclear reactions. Test operation was made for reduction of background due to the injection beams. The plasma-sputtering type ion source was introduced and the beams will be injected into the tandem. (H. Yokoo)

Optical Breath Gas Sensor for Extravehicular Activity Application

Science.gov (United States)

Wood, William R.; Casias, Miguel E.; Vakhtin, Andrei B.; Pilgrim, Jeffrey S.; Chullen, Cinda; Falconi, Eric A.; McMillin, Summer

2013-01-01

The function of the infrared gas transducer used during extravehicular activity in the current space suit is to measure and report the concentration of carbon dioxide (CO2) in the ventilation loop. The next generation portable life support system (PLSS) requires next generation CO2 sensing technology with performance beyond that presently in use on the Space Shuttle/International Space Station extravehicular mobility unit (EMU). Accommodation within space suits demands that optical sensors meet stringent size, weight, and power requirements. A laser diode spectrometer based on wavelength modulation spectroscopy is being developed for this purpose by Vista Photonics, Inc. Two prototype devices were delivered to NASA Johnson Space Center (JSC) in September 2011. The sensors incorporate a laser diode-based CO2 channel that also includes an incidental water vapor (humidity) measurement and a separate oxygen channel using a vertical cavity surface emitting laser. Both prototypes are controlled digitally with a field-programmable gate array/microcontroller architecture. The present development extends and upgrades the earlier hardware to the Advanced PLSS 2.0 test article being constructed and tested at JSC. Various improvements to the electronics and gas sampling are being advanced by this project. The combination of low power electronics with the performance of a long wavelength laser spectrometer enables multi-gas sensors with significantly increased performance over that presently offered in the EMU.

Study of soft X-ray energy spectra from gas-puff Z-pinch plasma

International Nuclear Information System (INIS)

Zou Xiaobing; Wang Xinxin; Zhang Guixin; Han Min; Luo Chengmu

2006-01-01

A ROSS-FILTER-PIN spectrometer in the spectral range of 0.28 keV-1.56 keV was developed to study the soft X-ray radiation emitted from gas-puff Z-pinch plasma. It is composed of five channels covering the energy interval of interest without gaps. Soft X-ray spectral energy cuts were determined by the L absorption edges of selected filter elements (K absorption edges being used for light filter elements), and the optimum thickness of filter material was designed using computer code. To minimize the residual sensitivity outside the sensitivity range of each channel, element of the first filter was added into the second filter of all the Ross pair. To diminish the area of each filter, PIN detector with small sensitive area of 1 mm 2 was adopted for the spectrometer. A filter with small area is easy to fabricate and would be helpful to withstand the Z-pinch discharge shock wave. With this ROSS-FILTER-PIN spectrometer, the energy spectra of soft X-ray from a small gas-puff Z-pinch were investigated, and the correlation between the soft X-ray yield and the plasma implosion state was also studied. (authors)

Following the Ions through a Mass Spectrometer with Atmospheric Pressure Interface: Simulation of Complete Ion Trajectories from Ion Source to Mass Analyzer.

Science.gov (United States)

Zhou, Xiaoyu; Ouyang, Zheng

2016-07-19

Ion trajectory simulation is an important and useful tool in instrumentation development for mass spectrometry. Accurate simulation of the ion motion through the mass spectrometer with atmospheric pressure ionization source has been extremely challenging, due to the complexity in gas hydrodynamic flow field across a wide pressure range as well as the computational burden. In this study, we developed a method of generating the gas flow field for an entire mass spectrometer with an atmospheric pressure interface. In combination with the electric force, for the first time simulation of ion trajectories from an atmospheric pressure ion source to a mass analyzer in vacuum has been enabled. A stage-by-stage ion repopulation method has also been implemented for the simulation, which helped to avoid an intolerable computational burden for simulations at high pressure regions while it allowed statistically meaningful results obtained for the mass analyzer. It has been demonstrated to be suitable to identify a joint point for combining the high and low pressure fields solved individually. Experimental characterization has also been done to validate the new method for simulation. Good agreement was obtained between simulated and experimental results for ion transfer though an atmospheric pressure interface with a curtain gas.

Mini ion trap mass spectrometer

Science.gov (United States)

Dietrich, D.D.; Keville, R.F.

1995-09-19

An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

Variable filter array spectrometer of VPD PbSe

Science.gov (United States)

Linares-Herrero, R.; Vergara, G.; Gutiérrez-Álvarez, R.; Fernández-Montojo, C.; Gómez, L. J.; Villamayor, V.; Baldasano-Ramírez, A.; Montojo, M. T.

2012-06-01

MWIR spectroscopy shows a large potential in the current IR devices market, due to its multiple applications (gas detection, chemical analysis, industrial monitoring, combustion and flame characterization, food packaging etc) and its outstanding performance (good sensitivity, NDT method, velocity of response, among others), opening this technique to very diverse fields of application, such as industrial monitoring and control, agriculture, medicine and environmental monitoring. However, even though a big interest on MWIR spectroscopy technique has been present in the last years, two major barriers have held it back from its widespread use outside the laboratory: the complexity and delicateness of some popular techniques such as Fourier-transform IR (FT-IR) spectrometers, and the lack of affordable specific key elements such a MWIR light sources and low cost (real uncooled) detectors. Recent developments in electrooptical components are helping to overcome these drawbacks. The need for simpler solutions for analytical measurements has prompted the development of better and more affordable uncooled MWIR detectors, electronics and optics. In this paper a new MWIR spectrometry device is presented. Based on linear arrays of different geometries (64, 128 and 256 elements), NIT has developed a MWIR Variable Filter Array Spectrometer (VFAS). This compact device, with no moving parts, based on a rugged and affordable detector, is suitable to be used in applications which demand high sensitivity, good spectral discrimination, reliability and compactness, and where an alternative to the traditional scanning instrument is desired. Some measurements carried out for several industries will be also presented.

Workshop on high-resolution, large-acceptance spectrometers

Energy Technology Data Exchange (ETDEWEB)

Zeidman, B. (ed.)

1981-01-01

The purpose of the Workshop on High-Resolution, Large-Acceptance Spectrometers was to provide a means for exchange of information among those actively engaged in the design and construction of these new spectrometers. Thirty-seven papers were prepared for the data base.

Measurement Of I-131 In Air Using A Portable Gamma Spectrometer

International Nuclear Information System (INIS)

Bunawas; Dadong Iskandar; Wahyudi; U, Wiwik

2000-01-01

Aerosol contamination of I-131, radioactive emitting gamma radiation, can be directly measured by using a portable gamma spectrometer which used GC2020 Canberra HPGe detector. Assuming constant concentration of I-131 in the infinite space of semi spherical, calibration factor, and detection limits determined using standard CH 3 I gas. The results showed that the detection limits for 1 hour counting period was 3.06 Bq/m exp.3 for confidence level of 95% (2σ). Field measurements are conducted on several rooms with uncertainties variation between 0.34 and 60.11% compare with true values. Qualitative discussion of the factors contributing to the uncertainty in the in situ result is included

Isotope ratio analysis by a combination of element analyzer and mass spectrometer

International Nuclear Information System (INIS)

Pichlmayer, F.

1987-06-01

The use of stable isotope ratios of carbon, nitrogen and sulfur as analytical tool in many fields of research is of growing interest. A method has therefore been developed, consisting in essential of coupling an Elemental Analyzer with an Isotope Mass Spectrometer, which enables the gas preparation of carbon dioxide, nitrogen and sulfur dioxide from any solid or liquid sample in a fast and easy way. Results of carbon isotope measurements in food analysis are presented, whereat it is possible to check origin and treatment of sugar, oils, fats, mineral waters, spirituous liquors etc. and to detect adulterations as well. Also applications in the field of environmental research are given. (Author)

Recent Developments of an Opto-Electronic THz Spectrometer for High-Resolution Spectroscopy

Directory of Open Access Journals (Sweden)

Guillaume Ducournau

2009-11-01

Full Text Available A review is provided of sources and detectors that can be employed in the THz range before the description of an opto-electronic source of monochromatic THz radiation. The realized spectrometer has been applied to gas phase spectroscopy. Air-broadening coefficients of HCN are determined and the insensitivity of this technique to aerosols is demonstrated by the analysis of cigarette smoke. A multiple pass sample cell has been used to obtain a sensitivity improvement allowing transitions of the volatile organic compounds to be observed. A solution to the frequency metrology is presented and promises to yield accurate molecular line center measurements.

Polarized neutron spectrometer for inelastic experiments at J-PARC

Directory of Open Access Journals (Sweden)

Yokoo Tetsuya

2015-01-01

Full Text Available Construction of the newly developed polarization analysis neutron chopper spectrometer (POLANO commenced in the Japan Proton Accelerator Research Complex (J-PARC, Materials and Life Science Experimental Facility (MLF. The POLANO is a direct geometry chopper spectrometer with neutron polarization analysis capability. In the suite of inelastic spectrometers, six instruments are now in operation. POLANO will be the only spectrometer dedicated to polarization analysis experiments. The primary phase of the construction will be completed by 2014 with beam commissioning scheduled for 2015.

Reactive intermediates in the gas phase generation and monitoring

CERN Document Server

Setser, D W

2013-01-01

Reactive Intermediates in the Gas Phase: Generation and Monitoring covers methods for reactive intermediates in the gas phase. The book discusses the generation and measurement of atom and radical concentrations in flow systems; the high temperature flow tubes, generation and measurement of refractory species; and the electronically excited long-lived states of atoms and diatomic molecules in flow systems. The text also describes the production and detection of reactive species with lasers in static systems; the production of small positive ions in a mass spectrometer; and the discharge-excite

The Spectrometer

Science.gov (United States)

Greenslade, Thomas B., Jr.

2012-01-01

In the fall of 1999 I was shown an Ocean Optics spectrometer-in-the-computer at St. Patricks College at Maynooth, Ireland, and thought that I had seen heaven. Of course, it could not resolve the sodium D-lines (I had done that many years before with a homemade wire diffraction grating), and I began to realize that inside was some familiar old…

The MIRI Medium Resolution Spectrometer calibration pipeline

NARCIS (Netherlands)

Labiano, A.; Azzollini, R.; Bailey, J.; Beard, S.; Dicken, D.; García-Marín, M.; Geers, V.; Glasse, A.; Glauser, A.; Gordon, K.; Justtanont, K.; Klaassen, P.; Lahuis, F.; Law, D.; Morrison, J.; Müller, M.; Rieke, G.; Vandenbussche, B.; Wright, G.

2016-01-01

The Mid-Infrared Instrument (MIRI) Medium Resolution Spectrometer (MRS) is the only mid-IR Integral Field Spectrometer on board James Webb Space Telescope. The complexity of the MRS requires a very specialized pipeline, with some specific steps not present in other pipelines of JWST instruments,

Use of UAV-Borne Spectrometer for Land Cover Classification

Directory of Open Access Journals (Sweden)

Sowmya Natesan

2018-04-01

Full Text Available Unmanned aerial vehicles (UAV are being used for low altitude remote sensing for thematic land classification using visible light and multi-spectral sensors. The objective of this work was to investigate the use of UAV equipped with a compact spectrometer for land cover classification. The UAV platform used was a DJI Flamewheel F550 hexacopter equipped with GPS and Inertial Measurement Unit (IMU navigation sensors, and a Raspberry Pi processor and camera module. The spectrometer used was the FLAME-NIR, a near-infrared spectrometer for hyperspectral measurements. RGB images and spectrometer data were captured simultaneously. As spectrometer data do not provide continuous terrain coverage, the locations of their ground elliptical footprints were determined from the bundle adjustment solution of the captured images. For each of the spectrometer ground ellipses, the land cover signature at the footprint location was determined to enable the characterization, identification, and classification of land cover elements. To attain a continuous land cover classification map, spatial interpolation was carried out from the irregularly distributed labeled spectrometer points. The accuracy of the classification was assessed using spatial intersection with the object-based image classification performed using the RGB images. Results show that in homogeneous land cover, like water, the accuracy of classification is 78% and in mixed classes, like grass, trees and manmade features, the average accuracy is 50%, thus, indicating the contribution of hyperspectral measurements of low altitude UAV-borne spectrometers to improve land cover classification.

High intensity TOF spectrometer for cold neutrons

International Nuclear Information System (INIS)

Maayouf, R.M.; Abd El-Kawy, A.; Habib, N.; Adib, M.; Hamouda, I.

1984-01-01

This work presents a neutron time-of-flight (TOF) spectrometer developed specially for total neutron cross-section measurements at neutron energies below 5 MeV and sample's temperature varying from the liquid nitrogen one and up to 500 0 K. The spectrometer is equipped by remote control unit, designed especially, in order to move the sample in and out of the beam during the experimental measurements. The spectrometer has proved to be useful for transmission measurements at neutron energies below 5 MeV. It has a reasonable energy resolution (4.4%) and high effect to background ratio (11.1) at 5 MeV

Formation of hot intergalactic gas by gas ejection from a galaxy in an early explosive era

International Nuclear Information System (INIS)

Ikeuchi, Satoru

1977-01-01

Chemical evolution of a galaxy in an early explosive era is studied by means of one zone model. Calculating the thermal properties of interstellar gas and the overlapping factor of expanding supernova-remnant shells, the gas escape conditions from a galaxy are examined. From these, it is shown that the total mass of ejected gas from a galaxy amounts to 10 -- 40% of the initial mass of a galaxy. The ejected gas extends to the intergalactic space and the whole universe. The mass, the heavy-element abundance and other physical properties of thus formed intergalactic gas are investigated for various parameters of galactic evolution. Some other effects of gas release on the evolution of a galaxy and the evolution of the universe are discussed. (auth.)

The Omega spectrometer

CERN Multimedia

1972-01-01

The Omega spectrometer which came into action during the year. An array of optical spark chambers can be seen withdrawn from the magnet aperture. In the 'igloo' above the magnet is located the Plumbicon camera system which collects information from the spark chambers.

Silicon spectrometer with a Peltier refrigerator

International Nuclear Information System (INIS)

Belcarz, E.; Chwaszczewska, J.; Hahn, G.; Nowicki, W.; Sawicka, B.; Skoczek, K.; Slapa, M.; Szymczak, M.

1974-01-01

This paper describes a spectrometer with a Si(Li) detector cooled by a Peltier refrigerator. The spectrometer is able to analyse samples of practically all most frequently encountered emitters of alpha, beta and low energy gamma radiation. The energy resolution were about 1.3-1.5 keV for 14 keV gamma radiation. The system can also operate in field conditions in the fluorescence analysis. (author)

Development of Neutron Spectrometer

Energy Technology Data Exchange (ETDEWEB)

Lee, Chang Hee; Lee, J. S.; Seong, B. S. (and others)

2007-06-15

Neutron spectrometers which are used in the basic researches such as physics, chemistry and materials science and applied in the industry were developed at the horizontal beam port of HANARO reactor. In addition, the development of core components for neutron scattering and the upgrade of existing facilities are also performed. The vertical neutron reflectometer was fabricated and installed at ST3 beam port. The performance test of the reflectometer was completed and the reflectometer was opened to users. The several core parts and options were added in the polarized neutron spectrometer. The horizontal neutron reflectometer from Brookhaven National Laboratory was moved to HANARO and installed, and the performance of the reflectometer was examined. The HIPD was developed and the performance test was completed. The base shielding for TAS was fabricated. The soller collimator, Cu mosaic monochromator, Si BPC monochromator and position sensitive detector were developed and applied in the neutron spectrometer as part of core component development activities. In addition, the sputtering machine for mirror device are fabricated and the neutron mirror is made using the sputtering machine. The FCD was upgraded and the performance of the FCD are improved over the factor of 10. The integration and upgrade of the neutron detection system were also performed.

ISLA: An Isochronous Spectrometer with Large Acceptances

Energy Technology Data Exchange (ETDEWEB)

Bazin, D., E-mail: bazin@nscl.msu.edu; Mittig, W.

2013-12-15

A novel type of recoil mass spectrometer and separator is proposed for the future secondary radioactive beams of the ReA12 accelerator at NSCL/FRIB, inspired from the TOFI spectrometer developed at the Los Alamos National Laboratory for online mass measurements. The Isochronous Spectrometer with Large Acceptances (ISLA) is able to achieve superior characteristics without the compromises that usually plague the design of large acceptance spectrometers. ISLA can provide mass-to-charge ratio (m/q) measurements to better than 1 part in 1000 by using an optically isochronous time-of-flight independent of the momentum vector of the recoiling ions, despite large acceptances of 20% in momentum and 64 msr in solid angle. The characteristics of this unique design are shown, including requirements for auxiliary detectors around the target and the various types of reactions to be used with the re-accelerated radioactive beams of the future ReA12 accelerator.

The high-resolution time-of-flight spectrometer TOFTOF

Energy Technology Data Exchange (ETDEWEB)

Unruh, Tobias [Technische Universitaet Muenchen, Forschungsneutronenquelle Heinz Maier-Leibnitz FRM II and Physik Department E13, Lichtenbergstr. 1, 85747 Garching (Germany)], E-mail: Tobias.Unruh@frm2.tum.de; Neuhaus, Juergen; Petry, Winfried [Technische Universitaet Muenchen, Forschungsneutronenquelle Heinz Maier-Leibnitz FRM II and Physik Department E13, Lichtenbergstr. 1, 85747 Garching (Germany)

2007-10-11

The TOFTOF spectrometer is a multi-disc chopper time-of-flight spectrometer for cold neutrons at the research neutron source Heinz Maier-Leibnitz (FRM II). After five reactor cycles of routine operation the characteristics of the instrument are reported in this article. The spectrometer features an excellent signal to background ratio due to its remote position in the neutron guide hall, an elaborated shielding concept and an s-shaped curved primary neutron guide which acts i.a. as a neutron velocity filter. The spectrometer is fed with neutrons from the undermoderated cold neutron source of the FRM II leading to a total neutron flux of {approx}10{sup 10}n/cm{sup 2}/s in the continuous white beam at the sample position distributed over a continuous and particularly broad wavelength spectrum. A high energy resolution is achieved by the use of high speed chopper discs made of carbon-fiber-reinforced plastic. In the combination of intensity, resolution and signal to background ratio the spectrometer offers new scientific prospects in the fields of inelastic and quasielastic neutron scattering.

The high-resolution time-of-flight spectrometer TOFTOF

Science.gov (United States)

Unruh, Tobias; Neuhaus, Jürgen; Petry, Winfried

2007-10-01

The TOFTOF spectrometer is a multi-disc chopper time-of-flight spectrometer for cold neutrons at the research neutron source Heinz Maier-Leibnitz (FRM II). After five reactor cycles of routine operation the characteristics of the instrument are reported in this article. The spectrometer features an excellent signal to background ratio due to its remote position in the neutron guide hall, an elaborated shielding concept and an s-shaped curved primary neutron guide which acts i.a. as a neutron velocity filter. The spectrometer is fed with neutrons from the undermoderated cold neutron source of the FRM II leading to a total neutron flux of ˜1010n/cm2/s in the continuous white beam at the sample position distributed over a continuous and particularly broad wavelength spectrum. A high energy resolution is achieved by the use of high speed chopper discs made of carbon-fiber-reinforced plastic. In the combination of intensity, resolution and signal to background ratio the spectrometer offers new scientific prospects in the fields of inelastic and quasielastic neutron scattering.

Sentinel 4: a geostationary imaging UVN spectrometer for air quality monitoring: status of design, performance and development

Science.gov (United States)

Gulde, S. T.; Kolm, M. G.; Smith, D. J.; Maurer, R.; Bazalgette Courrèges-Lacoste, G.; Sallusti, M.; Bagnasco, G.

2017-11-01

SENTINEL 4 is an imaging UVN (UV-VIS-NIR) spectrometer, developed by Airbus Defence and Space under ESA contract in the frame of the joint European Union (EU)/ESA COPERNICUS program. The mission objective is the operational monitoring of trace gas concentrations for atmospheric chemistry and climate applications. To this end SENTINEL 4 will provide accurate measurements of key atmospheric constituents such as ozone, nitrogen dioxide, sulfur dioxide, formaldehyde, as well as aerosol and cloud properties.

The Copernicus Sentinel 4 mission: a geostationary imaging UVN spectrometer for air quality monitoring

Science.gov (United States)

Bazalgette Courrèges-Lacoste, G.; Sallusti, M.; Bulsa, G.; Bagnasco, G.; Veihelmann, Ben; Riedl, S.; Smith, D. J.; Maurer, R.

2017-09-01

Sentinel-4 is an imaging UVN (UV-VIS-NIR) spectrometer, developed by Airbus Defence and Space under ESA contract in the frame of the joint EU/ESA COPERNICUS program. The mission objective is the operational monitoring of trace gas concentrations for atmospheric chemistry and climate applications - hence the motto of Sentinel-4 "Knowing what we breathe". Sentinel-4 will provide accurate measurements of key atmospheric constituents such as ozone, nitrogen dioxide, sulfur dioxide, methane, and aerosol properties over Europe and adjacent regions from a geostationary orbit (see Fig. 1). In the family of already flown UVN spectrometers (SCIAMACHY, OMI, GOME and GOME 2) and of those spectrometers currently under development (Sentinel-5p and Sentinel-5), Sentinel-4 is unique in being the first geostationary UVN mission. Furthermore, thanks to its 60-minutes repeat cycle measurements and high spatial resolution (8x8 km2), Sentinel-4 will increase the frequency of cloud-free observations, which is necessary to assess troposphere variability. Two identical Sentinel-4 instruments (PFM and FM-2) will be embarked, as Customer Furnished Item (CFI), fully verified, qualified and calibrated respectively onto two EUMETSAT satellites: Meteosat Third Generation-Sounder 1 and 2 (MTG-S1 and MTG-S2), whose Flight Acceptance Reviews are presently planned respectively in Q4 2021 and Q1 2030. This paper gives an overview of the Sentinel-4 system1 architecture, its design and development status, current performances and the key technological challenges.

Innovative optical spectrometers for ice core sciences and atmospheric monitoring at polar regions

Science.gov (United States)

Grilli, Roberto; Alemany, Olivier; Chappellaz, Jérôme; Desbois, Thibault; Faïn, Xavier; Kassi, Samir; Kerstel, Erik; Legrand, Michel; Marrocco, Nicola; Méjean, Guillaume; Preunkert, Suzanne; Romanini, Daniele; Triest, Jack; Ventrillard, Irene

2015-04-01

limit of 0.2 ppbv for CH4 and a precision of 0.2o on the δD of H2O within ~1 min of integration time. The spectrometer and the home-made gas sampling has been tested during an oceanographic campaign last summer in the Mediterranean Sea, measuring the vertical distribution of CH4 dissolved in seawater. The project is now moving forward its final goal which consists of employing the probe for a first test season at Concordia station during the Austral summer of 2016/17, and then for the 'oldest ice challenge' drilling season scheduled in the Austral summer of 2017/18. Finally, preliminary results on the isotope ratio measurements of CO18O,13CO2 and 13CO18O will be presented. A novel spectrometer, based on OFCAES technique employing a Quantum Cascade Laser around 4.4 μm wavelength, offers a precision below 0.05 o for the three isotopic anomalies, for 200 ppmv of CO2 samples. The optical device will be employed for laboratory experiments coupling it with a continuous ice-crushing extraction system for analyzing trapped bubbles of gas in Antarctica ice cores. [1] R. Grilli, G. Méjean, S. Kassi, I. Ventrillard, C. Abd-Alrahman, and D. Romanini, 'Frequency Comb Based Spectrometer for in Situ and Real Time Measurements of IO, BrO, NO2, and H2CO at pptv and ppqv Levels.,' Environ. Sci. Technol., vol. 46, no. 19, pp. 10704-10, Oct. 2012. [2] R. Grilli, M. Legrand, A. Kukui, G. Méjean, S. Preunkert, and D. Romanini, 'First investigations of IO, BrO, and NO2 summer atmospheric levels at a coastal East Antarctic site using mode-locked cavity enhanced absorption spectroscopy,' Geophys. Res. Lett., vol. 40, pp. 1-6, Feb. 2013. [3] R. Grilli, N. Marrocco, T. Desbois, C. Guillerm, J. Triest, E. Kerstel, and D. Romanini, 'Invited Article: SUBGLACIOR: An optical analyzer embedded in an Antarctic ice probe for exploring the past climate,' Rev. Sci. Instrum., vol. 85, no. 111301, pp. 1-7, 2014.

High intensity line source for x-ray spectrometer calibration

International Nuclear Information System (INIS)

Thoe, R.S.

1986-06-01

A high intensity electron-impact x-ray source using a one-dimensional Pierce lens has been built for the purpose of calibrating a bent crystal x-ray spectrometer. This source focuses up to 100 mA of 20-keV electrons to a line on a liquid-cooled anode. The line (which can serve as a virtual slit for the spectrometer) measures approximately 800 μ x 2 cm. The source is portable and therefore adaptable to numerous types of spectrometer applications. One particular application, the calibration of a high resolution (r = 10 4 ) time-resolved cyrstal spectrometer, will be discussed in detail

Basics of spectroscopic instruments. Hardware of NMR spectrometer

International Nuclear Information System (INIS)

Sato, Hajime

2009-01-01

NMR is a powerful tool for structure analysis of small molecules, natural products, biological macromolecules, synthesized polymers, samples from material science and so on. Magnetic Resonance Imaging (MRI) is applicable to plants and animals Because most of NMR experiments can be done by an automation mode, one can forget hardware of NMR spectrometers. It would be good to understand features and performance of NMR spectrometers. Here I present hardware of a modern NMR spectrometer which is fully equipped with digital technology. (author)

Micro-Spec: an Integrated, Direct-Detection Spectrometer for Far-Infrared and Submillimeter Astronomy

Science.gov (United States)

Cataldo, Giuseppe

2014-01-01

The far-infrared and submillimeter portions of the electromagnetic spectrum provide a unique view of the astrophysical processes present in the early universe. Our ability to fully explore this rich spectral region has been limited, however, by the size and cost of the cryogenic spectrometers required to carry out such measurements. Micro-Spec (u-Spec) is a high-sensitivity, direct-detection spectrometer concept working in the 450-1000 micromillimeter wavelength range which will enable a wide range of flight missions that would otherwise be challenging due to the large size of current instruments with the required spectral resolution and sensitivity. The spectrometer design utilizes two internal antenna arrays, one for transmitting and one for receiving, superconducting microstrip transmission lines for power division and phase delay, and an array of microwave kinetic inductance detectors (MKIDs) to achieve these goals. The instrument will be integrated on a approximately 10 square cm silicon chip and can therefore become an important capability under the low background conditions accessible via space and high-altitude borne platforms. In this paper, an optical design methodology for Micro-Spec is presented, with particular attention given to its twodimensional diffractive region, where the light of different wavelengths is focused on the different detectors. The method is based on the maximization of the instrument resolving power and minimization of the RMS phase error on the instrument focal plane. This two-step optimization can generate geometrical configurations given specific requirements on spectrometer size, operating spectral range and performance. A point design with resolving power of 257, an RMS phase error less than 0.1 radians and four stigmatic points was developed for initial demonstration and will be the basis of future instruments with resolving power up to about 1200.

Gas And Ice Spectrometer/Radar (GAISR): a new instrument for close-up comet activity observations

Science.gov (United States)

Cooper, Ken; Monje, Raquel; Cochrane, Corey; Tang, Adrian; Alonso, Maria; Dengler, Robert; Durden, Stephen; Choukroun, Mathieu

2017-10-01

The Rosetta mission at 67P/Churyumov-Gerasimenko enabled the first detailed and long-term survey of cometary activity, which occurs primarily through water outgassing and emission of dust. Its highly-capable instrument suite improved our understanding of the outgassing and the dust emission and size distribution separately, however the coupling between the two remains poorly understood. GAISR consists of a dual-channel submillimeter-wave spectrometer inspired from MIRO/Rosetta, coupled to a small-particle Doppler radar for simultaneous observations of outgassing and emission of the large dust particles (comprising most of the mass emitted) in cometary jets and plumes of outer solar system satellites. GAISR’s medium-range W-band (95 GHz) radar will operate in a frequency-modulated continuous-wave (FMCW) mode with 1 Watt of transmit power to achieve high sensitivity detection of the range and velocity distribution of 0.1-10 mm sized ice and dust particles released by jets and plumes. The radar’s primary aperture also functions as an antenna for two passive heterodyne spectrometer channels at 270 and 560 GHz for detecting the abundance, temperature, and velocity of water vapor and its isotopes (including HDO), as well other major cometary volatiles such as CO, NH3, CH3OH. GAISR has been designed with a priority placed on low mass and power needs, to facilitate its infusion in future planetary missions. This is accomplished by leveraging recent innovations in W-band signal generation using low power silicon integrated circuits, state-of-the art III-V semiconductor devices for signal amplification and detection, and compact quasioptical duplexing. A new signal processing algorithm for FMCW Doppler radar detection out to the maximum range ambiguity limit has also been developed. GAISR’s performance testing has begun, and this poster will summarize its proven capabilities and plans for validation in relevant environments.

Speckle-based spectrometer

DEFF Research Database (Denmark)

Chakrabarti, Maumita; Jakobsen, Michael Linde; Hanson, Steen Grüner

2015-01-01

A novel spectrometer concept is analyzed and experimentally verified. The method relies on probing the speckle displacement due to a change in the incident wavelength. A rough surface is illuminated at an oblique angle, and the peak position of the covariance between the speckle patterns observed...

Ring-patterned plasmonic photonic crystal thermal light source for miniaturized near-infrared spectrometers

Science.gov (United States)

Labib, Shady R.; Elsayed, Ahmed A.; Sabry, Yasser M.; Khalil, Diaa

2018-02-01

There is a growing number of spectroscopy applications in the near-infrared (NIR) range including gas sensing, food analysis, pharmaceutical and industrial applications that requires highly efficient, more compact and low-cost miniaturized spectrometers. One of the key components for such systems is the wideband light source that can be fabricated using Silicon technology and hence integrated with other components on the same chip. In this work, we report a ring-patterned plasmonic photonic crystal (PC) thermal light source for miniaturized near-infrared spectrometers. The design is based on silicon and tuned to achieve wavelength selectivity in the emitted spectrum. The design is optimized by using Rigorous Coupled-Wave Analysis (RCWA) simulation, which is used to compute the power reflectance and transmittance that are used to predict the emissivity of the structure. The design consists of a PC of silicon rings coated with platinum. The period of the structure is about 2 μm and the silicon is highly-doped with n-type doping level in the order of 1019-1020 cm-3 to enhance the free-carrier absorption. The ring etching depth, diameter and shell thickness are optimized to increase its emissivity within a specific wavelength range of interest. The simulation results show an emissivity exceeding 0.9 in the NIR range up to 2.5 μm, while the emissivity is decreased significantly for longer wavelengths suppressing the emission out of the range of interest, and hence increasing the efficiency for the source. The reported results open the door for black body radiation engineering in integrated silicon sources for spectrometer miniaturization.

Effect of jitter on an imaging FTIR spectrometer

Energy Technology Data Exchange (ETDEWEB)

Bennett, C. L., LLNL

1997-04-01

Line of sight (LOS) jitter produces temporal modulations of the signals which are detected in the focal plane of a temporally modulated imaging Fourier Transform Spectrometer. A theoretical treatment of LOS jitter effects is given, and is compared with the results of measurements with LIFTIRS1 (the Livermore Imaging Fourier Transform InfraRed Spectrometer). The identification, isolation, quantification and removal of jitter artifacts in hyperspectral imaging data by means of principal components analysis is discussed. The theoretical distribution of eigenvalues expected from principal components analysis is used to determine the level of significance of spatially coherent instrumental artifacts in general, including jitter as a representative example. It is concluded that an imaging FTIR spectrometer is much less seriously impacted by a given LOS jitter level than a non imaging FTIR spectrometer.

Resonant ultrasound spectrometer

Science.gov (United States)

Migliori, Albert; Visscher, William M.; Fisk, Zachary

1990-01-01

An ultrasound resonant spectrometer determines the resonant frequency spectrum of a rectangular parallelepiped sample of a high dissipation material over an expected resonant response frequency range. A sample holder structure grips corners of the sample between piezoelectric drive and receive transducers. Each transducer is mounted on a membrane for only weakly coupling the transducer to the holder structure and operatively contacts a material effective to remove system resonant responses at the transducer from the expected response range. i.e., either a material such as diamond to move the response frequencies above the range or a damping powder to preclude response within the range. A square-law detector amplifier receives the response signal and retransmits the signal on an isolated shield of connecting cabling to remove cabling capacitive effects. The amplifier also provides a substantially frequency independently voltage divider with the receive transducer. The spectrometer is extremely sensitive to enable low amplitude resonance to be detected for use in calculating the elastic constants of the high dissipation sample.

Wide band ENDOR spectrometer

International Nuclear Information System (INIS)

Mendonca Filho, C.

1973-01-01

The construction of an ENDOR spectrometer operating from 0,5 to 75 MHz within a single band, with ore Klystron and homodine detection, and no fundamental changes on the electron spin resonance spectrometer was described. The ENDOR signal can be detected both by amplitude modulation of the frequency field, or direct detection of the ESR output, which is taken to a signal analyser. The signal-to-noise ratio is raised by averaging rather than filtering avoiding the use of long time constants, providing natural line widths. The experimental apparatus and the spectra obtained are described. A discussion, relating the ENDOR line amplitudes with the experimental conditions is done and ENDOR mechanism, in which there is a relevant presence of cross relaxation is proposed

Attachment to a mass spectrometer for studying the processes of semiconductor compound deposition from a gaseous phase

International Nuclear Information System (INIS)

Belousov, V.I.; Zhuravlev, G.I.; Popenko, N.I.; Novozhilov, A.F.; Matveev, I.V.; Murav'ev, V.V.

1984-01-01

An attachment to the mass spectrometer for studying the processes of semiconductor compounds deposition from a gaseous phase at the pressure of 1x10 5 Pa and the temperature of 400-1300 K is described. The attachment consists of the Neer ion source with ionization section cooled upto the temperature of liquid nitrogen, a two-zone vacuum furnace, and a quartz epitaxy reactor of the horzontal type.The attachment is equipped with the systems of process gas distribution in 5 flows and temperature stabilization. The rate of mass spectrum recording constitutes 2 mass/s at the resolution being equal to 1000 at the 10% level. The sensitivity at the steam-gas mixture components partial pressure determination constitutes 1x10 -4 Pa

FIR and sub-mm direct detection spectrometers for spaceborne astronomy

Science.gov (United States)

Wijnbergen, Jan J.; de Graauw, Thijs

1990-12-01

Candidate spaceborne sub-mm instrumentation proposed for space projects with large passively cooled telescopes are reviewed. Grating instruments and Fourier transform spectroscopy (FTS) spectrometers are discussed. Particular attention is given to imaging Fabry-Perot spectrometers. The special needs of the Large Deployable Reflector (LDR) and for the Far InfraRed Space Telescope (FIRST) missions in this area are outlined. Possible Fabry-Perot spectrometer setups are diagrammed and outlined. The use of spherical and multiplex Fabry-Perot spectrometers is discussed.

Liquid scintillation spectrometer survey 155Eu liquid activity

International Nuclear Information System (INIS)

Zhang Zuhua

2002-01-01

In the countrywide contrasting survey of 155 Eu activity, 155 Eu liquid activity was determined for the first time through using liquid scintillation spectrometer survey 155 Eu β ray. In survey total uncertainty, determining activity accord with determining activity average value of all a wide variety of survey instrument entering into contrasting survey. But using liquid scintillation spectrometer survey, it is simple and save time, is beyond compare for other survey method. It indicate liquid scintillation spectrometer survey β-γ nuclide activity is effective as well

Elementary Particle Physics Experiment at the University of Massachusetts, Amherst

Energy Technology Data Exchange (ETDEWEB)

Brau, Benjamin; Dallapiccola, Carlo; Willocq, Stephane

2013-07-30

In this progress report we summarize the activities of the University of Massachusetts- Amherst group for the three years of this research project. We are fully engaged in research at the energy frontier with the ATLAS experiment at the CERN Large Hadron Collider. We have made leading contributions in software development and performance studies for the ATLAS Muon Spectrometer, as well as on physics analysis with an emphasis on Standard Model measurements and searches for physics beyond the Standard Model. In addition, we have increased our contributions to the Muon Spectrometer New Small Wheel upgrade project.

Forward spectrometers at the SSC

International Nuclear Information System (INIS)

Bjorken, J.D.

1986-01-01

Most of SSC phase space and a great deal of physics potential is in the forward/backward region (absolute value of theta < 100 mrad). Comprehensive open-geometry spectrometers are feasible and very cost effective. Examples of such devices are sketched. Because such spectrometers are very long and may operate at high β and longer bunch spacing, they impact now on SSC interaction - region design. The data acquisition load is as heavy as for central detectors, although there may be less emphasis on speed and more emphasis on sophisticated parallel and/or distributed processing for event selection, as well as on high-capacity buffering

Universal relaxation times for electron and nucleon gases

OpenAIRE

Pelc, M.; Marciak-Kozlowska, J.; Kozlowski, M.

2007-01-01

In this paper we calculate the universal relaxation times for electron and nucleon fermionic gases. We argue that the universal relaxation time tau(i) is equal tau(i)=h/m square v(i) where v(i)=alpha(i)c and alpha(1)=0.15 for nucleon gas and alpha(2)=1/137 for electron gas, c=light velocity. With the universal relaxation time we formulate the thermal Proca equation for fermionic gases. Key words: universal relaxation time, thermal universal Proca equation.

Triple axis spectrometers

International Nuclear Information System (INIS)

Clausen, K.N.

1997-01-01

Conventional triple-axis neutron spectroscopy was developed by Brockhouse over thirty years ago' and remains today a versatile and powerful tool for probing the dynamics of condensed matter. The original design of the triple axis spectrometer is technically simple and probes momentum and energy space on a point-by-point basis. This ability to systematically probe the scattering function in a way which only requires a few angles to be moved under computer control and where the observed data in general can be analysed using a pencil and graph paper or a simple fitting routine, has been essential for the success of the method. These constraints were quite reasonable at the time the technique was developed. Advances in computer based data acquisition, neutron beam optics, and position sensitive area detectors have been gradually implemented on many triple axis spectrometer spectrometers, but the full potential of this has not been fully exploited yet. Further improvement in terms of efficiency (beyond point by point inspection) and increased sensitivity (use of focusing optics whenever the problem allows it) could easily be up to a factor of 10-20 over present instruments for many problems at a cost which is negligible compared to that of increasing the flux of the source. The real cost will be in complexity - finding the optimal set-up for a given scan and interpreting the data as the they are taken. On-line transformation of the data for an appropriate display in Q, ω space and analysis tools will be equally important for this task, and the success of these new ideas will crucially depend on how well we solve these problems. (author)

OLYMPEX Counterflow Spectrometer and Impactor Field Campaign Report

Energy Technology Data Exchange (ETDEWEB)

Poellot, Michael [Univ. of North Dakota, Grand Forks, ND (United States)

2016-07-01

The U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility’s ARM Aerial Facility (AAF) Counterflow Spectrometer and Impactor (CSI) probe was flown on the University of North Dakota Cessna Citation research aircraft during the Olympic Mountain Experiment (OLYMPEX). The field campaign took place from November 12 through December 19, 2015, over the Olympic Mountains and coastal waters of Washington State as part of a National Aeronautics and Space Administration (NASA) Global Precipitation Measurement (GPM) validation campaign. The CSI was added to the Citation instrument suite to support the NASA Aerosol-Cloud Ecosystem (ACE) satellite program and flights of the NASA Lockheed Earth Resources (ER-2) aircraft. ACE funded extra ER-2 flights to focus on clouds that are weakly precipitating, which are also of interest to the DOE Atmospheric System Research (ASR) program.

Adaptive Tunable Laser Spectrometer for Space Applications

Science.gov (United States)

Flesch, Gregory; Keymeulen, Didier

2010-01-01

An architecture and process for the rapid prototyping and subsequent development of an adaptive tunable laser absorption spectrometer (TLS) are described. Our digital hardware/firmware/software platform is both reconfigurable at design time as well as autonomously adaptive in real-time for both post-integration and post-launch situations. The design expands the range of viable target environments and enhances tunable laser spectrometer performance in extreme and even unpredictable environments. Through rapid prototyping with a commercial RTOS/FPGA platform, we have implemented a fully operational tunable laser spectrometer (using a highly sensitive second harmonic technique). With this prototype, we have demonstrated autonomous real-time adaptivity in the lab with simulated extreme environments.

Calibration techniques for a fast duo-spectrometer

International Nuclear Information System (INIS)

Chapman, J.T.; Den Hartog, D.J.

1996-06-01

The authors have completed the upgrade and calibration of the Ion Dynamics Spectrometer (IDS), a high-speed Doppler duo-spectrometer which measures ion flow and temperature in the MST Reversed-field Pinch. This paper describes an in situ calibration of the diagnostic's phase and frequency response. A single clock was employed to generate both a digital test signal and a digitizer trigger thus avoiding frequency drift and providing a highly resolved measurement over the system bandwidth. Additionally, they review the measurement of the spectrometer instrument function and absolute intensity response. This calibration and subsequent performance demonstrate the IDS to be one of the fastest, highest throughput diagnostics of its kind. Typical measurements are presented

A compact multichannel spectrometer for Thomson scatteringa)

Science.gov (United States)

Schoenbeck, N. L.; Schlossberg, D. J.; Dowd, A. S.; Fonck, R. J.; Winz, G. R.

2012-10-01

The availability of high-efficiency volume phase holographic (VPH) gratings and intensified CCD (ICCD) cameras have motivated a simplified, compact spectrometer for Thomson scattering detection. Measurements of Te VPH grating and measurements Te > 100 eV by a 2072 l/mm VPH grating. The spectrometer uses a fast-gated (˜2 ns) ICCD camera for detection. A Gen III image intensifier provides ˜45% quantum efficiency in the visible region. The total read noise of the image is reduced by on-chip binning of the CCD to match the 8 spatial channels and the 10 spectral bins on the camera. Three spectrometers provide a minimum of 12 spatial channels and 12 channels for background subtraction.

A compact multichannel spectrometer for Thomson scattering

International Nuclear Information System (INIS)

Schoenbeck, N. L.; Schlossberg, D. J.; Dowd, A. S.; Fonck, R. J.; Winz, G. R.

2012-01-01

The availability of high-efficiency volume phase holographic (VPH) gratings and intensified CCD (ICCD) cameras have motivated a simplified, compact spectrometer for Thomson scattering detection. Measurements of T e e > 100 eV by a 2072 l/mm VPH grating. The spectrometer uses a fast-gated (∼2 ns) ICCD camera for detection. A Gen III image intensifier provides ∼45% quantum efficiency in the visible region. The total read noise of the image is reduced by on-chip binning of the CCD to match the 8 spatial channels and the 10 spectral bins on the camera. Three spectrometers provide a minimum of 12 spatial channels and 12 channels for background subtraction.

A compact multichannel spectrometer for Thomson scattering.

Science.gov (United States)

Schoenbeck, N L; Schlossberg, D J; Dowd, A S; Fonck, R J; Winz, G R

2012-10-01

The availability of high-efficiency volume phase holographic (VPH) gratings and intensified CCD (ICCD) cameras have motivated a simplified, compact spectrometer for Thomson scattering detection. Measurements of T(e) VPH grating and measurements T(e) > 100 eV by a 2072 l∕mm VPH grating. The spectrometer uses a fast-gated (~2 ns) ICCD camera for detection. A Gen III image intensifier provides ~45% quantum efficiency in the visible region. The total read noise of the image is reduced by on-chip binning of the CCD to match the 8 spatial channels and the 10 spectral bins on the camera. Three spectrometers provide a minimum of 12 spatial channels and 12 channels for background subtraction.

A GPU-Based Wide-Band Radio Spectrometer

Science.gov (United States)

Chennamangalam, Jayanth; Scott, Simon; Jones, Glenn; Chen, Hong; Ford, John; Kepley, Amanda; Lorimer, D. R.; Nie, Jun; Prestage, Richard; Roshi, D. Anish; Wagner, Mark; Werthimer, Dan

2014-12-01

The graphics processing unit has become an integral part of astronomical instrumentation, enabling high-performance online data reduction and accelerated online signal processing. In this paper, we describe a wide-band reconfigurable spectrometer built using an off-the-shelf graphics processing unit card. This spectrometer, when configured as a polyphase filter bank, supports a dual-polarisation bandwidth of up to 1.1 GHz (or a single-polarisation bandwidth of up to 2.2 GHz) on the latest generation of graphics processing units. On the other hand, when configured as a direct fast Fourier transform, the spectrometer supports a dual-polarisation bandwidth of up to 1.4 GHz (or a single-polarisation bandwidth of up to 2.8 GHz).

SWIFTS: on-chip very high spectral resolution spectrometer

Science.gov (United States)

le Coarer, E.; Venancio, L. G.; Kern, P.; Ferrand, J.; Puget, P.; Ayraud, M.; Bonneville, C.; Demonte, B.; Morand, A.; Boussey, J.; Barbier, D.; Blaize, S.; Gonthiez, T.

2017-11-01

The size and the weight of state of the art spectrometers is a serious issue regarding space applications. SWIFTS (Stationary Wave Integrated Fourier Transform Spectrometer) is a new FTS family without any moving part. This very promising technology is an original way to fully sample the Fourier interferogram obtained in a waveguide by either a reflection (SWIFTS Lippmann) or counter-propagative (SWIFTS Gabor) interference phenomenon. The sampling is simultaneously performed the optical path thanks to "nano-detectors" located in the evanescent field of the waveguide. For instance a 1.7cm long waveguide properly associated to the detector achieves directly a resolution of 0.13cm-1 on a few centimetre long instruments. Here, firstly we present the development status of this new kind of spectrometers and the first results obtained with on going development of spectrometer covering simultaneously the visible domain from 400 to 1000 nm like an Echelle spectrometer. Valuable technologies allows one to extend the concept to various wavelength domains. Secondly, we present the results obtained in the frame of an activity funded by the European Space Agency where several potential applications in space missions have been identified and studied.

Enhancement of a sector magnet RGA into a PC-assisted quantitative mass spectrometer

International Nuclear Information System (INIS)

Solomon, G.M.; Schaefer, M.; Schaefer, K.A.

1992-01-01

This paper presents design features of RGA sampling systems which should be considered when specifying or building a mass spectrometer sampling system. Important design features are described including non-fractionating, fast time response sampling system design, onboard calibration standards, multiple sample points and remote operation. PC control of both the sampling system and the RGA provides for important features including automatic peak position tuning, spectrum de-convolution, composition analysis based on actual calibration gas standards, and automatic round-robin sampling and data logging. Applications of such integrated sampling systems currently operating at industrial and government facilities performing continuous on-line monitoring and self calibration are also described. (orig.) [de

FERDO/FERD, Unfolding of Pulse-Height Spectrometer Spectra

International Nuclear Information System (INIS)

Rust, B.W.; Ingersoll, D.T.; Burrus, W.R.

1985-01-01

1 - Description of problem or function: FERDO and FERD are unfolding codes which can be used to correct observed pulse-height distributions for the non-ideal response of a pulse-height spectrometer or to solve poorly conditioned linear equations. 2 - Method of solution: It is assumed that the response of the spectrometer is given by Ax = b, where A is the spectrometer response function matrix, x is the unknown spectrum, and b is the pulse-height distribution. FERDO does not resolve directly for x but instead solves for p = Wx, where W is a 'window function matrix'. Typically, W is the resolution function of an ideal spectrometer which has a single Gaussian response. The effective resolution of the unfolding solution may be varied by the choice of W. Confidence intervals are found for each element of the solution p

[Research on lateral shearing interferometer for field monitoring of natural gas pipeline leak].

Science.gov (United States)

Zhang, Xue-Feng; Gao, Yu-Bin

2012-09-01

Aimed at the mechanical scanning spectroscopy equipment with poor anti-interference and anti-jamming ability, which affects the accuracy of its natural gas pipeline leak detection in the wild, a new type of lateral shearing interferometer system was designed. The system uses a beam splitter to get optical path difference by a mechanical scanning part, and it cancel the introduction of external vibration interference through the linkage between the two beam splitterw. The interference intensity of interference fringes produced was calculated, and analysis of a rotating beam splitter corresponds to the angle of the optical path difference function, solving for the maximum angle of the forward rotation and reverse rotation, which is the maximum optical path range. Experiments using the gas tank deflated simulated natural gas pipeline leak process, in the interference conditions, and the test data of the type WQF530 spectrometer and the new type of lateral shearing interferometer system were comparedt. The experimental results show that the relative error of both systems is about 1% in indoor conditions without interference. However, in interference environment, the error of WQF530 type spectrometer becomes larger, more than 10%, but the error of the new type of lateral shearing interferometer system is still below 5%. The detection accuracy of the type WQF530 spectrometer decreased significantly due to the environment. Therefore, the seismic design of the system can effectively offset power deviation and half-width increases of center wavelength caused by external interference, and compared to conventional mechanical scanning interferometer devices the new system is more suitable for field detection.

A NMR spectrometer for educational purposes; Espectrometro de RMN para ensino

Energy Technology Data Exchange (ETDEWEB)

Colnago, Luiz A; Torre Neto, Andre [Empresa Brasileira de Pesquisa Agropecuaria (EMBRAPA), Sao Carlos, SP (Brazil). Nucleo de Pesquisa e Desenvolvimento de Instrumentacao Agropecuaria; Villar, Jose D.F.; Seidl, Peter R [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil)

1992-12-31

A NMR spectrometer has been constructed for educational purposes, such as teaching of the technique basic principles and instrumentation. The spectrometer has been designed with a minimum number of components so that the students may have acquittance with both the spectrometer, through block diagrams, and the small numbers of existent components . The device was based on a 0.t Tesla magnet from the continuous wave spectrometer (E M 300 - Varian) existent at the Instituto Militar de Engenharia, and it is expected to facilitate the comprehension of the commercial spectrometers 1 ref., 3 figs.

The gas/solid methane abundance ratio toward deeply embedded protostars

NARCIS (Netherlands)

Boogert, ACA; Helmich, EP; van Dishoeck, EF; Schutte, WA

1998-01-01

We present the detection of re-vibrational absorption lines of the deformation mode of gaseous CH4 toward the massive protostars W 33A, and NGC 7538 : IRS9, using the SWS spectrometer an board of the Infrared Space Observatory. The observed lines indicate that the CH4 gas is warm (T similar to N 90

Dust-gas interaction deduced from Halley multicolour camera observations

International Nuclear Information System (INIS)

Huebner, W.F.; Delamere, W.A.; Keller, H.U.; Reitsema, H.J.; Schmidt, H.U.; Whipple, F.L.; Wilhelm, K.

1986-01-01

The dust and gas productions of Comet Halley were measured by the dust counter and the mass spectrometers on the Giotto spacecraft. These instruments give only little information about the spatial asymmetry of the activity. The asymmetry in the dust production is clearly evident from the dust jets seen in the Halley Multicolour Camera images. Since the dust is entrained by the gas, production must be similarly asymmetric. The intensity profiles along and across several dust jets are related to their source regions on the nucleus. Properties of the dust jets are investigated. A few compact, but highly active source regions on the nucleus produce most of the visible dust and can account for most of the gas produced by the comet. 2 refs

Precision analysis of 15N-labelled samples with the emission spectrometer NOI-5 for nitrogen balance in field trials

International Nuclear Information System (INIS)

Lippold, H.

1984-01-01

A technique was adapted for the preparation of samples with 15 N to be analyzed with the emission spectrometer NOI-5. This technique is based on methods of analyzing 15 N labelled gas samples in denitrification experiments. Nitrogen released from ammonium compounds by using hypobromite is injected into a repeatedly usable gaseous discharge tube where it is freed from water traces by means of the molecular sieve 5A. The described procedure of activating the molecular sieve allows to record spectra of reproducible quality thus promising an accuracy of analysis of +- 0.003 at% in the range of natural isotope frequency and the possibility of soil nitrogen analysis in field trials with fertilizers of low nitrogen content (3 to 6.5 at%; corresponding with 0.055 to 0.14% N/sub t/ of soils) without being dependent on mass spectrometers. (author)

International Seminar on Gasification 2009 - Biomass Gasification, Gas Clean-up and Gas Treatment

Energy Technology Data Exchange (ETDEWEB)

2009-10-15

During the seminar international and national experts gave presentations concerning Biomass gasification, Gas cleaning and gas treatment; and Strategy and policy issues. The presentations give an overview of the current status and what to be expected in terms of development, industrial interest and commercialization of different biomass gasification routes. The following PPT presentations are reproduced in the report: Black Liquor Gasification (Chemrec AB.); Gasification and Alternative Feedstocks for the Production of Synfuels and 2nd Generation Biofuels (Lurgi GmbH); Commercial Scale BtL Production on the Verge of Becoming Reality (Choren Industries GmbH.); Up-draft Biomass Gasification (Babcock and Wilcox Voelund A/S); Heterogeneous Biomass Residues and the Catalytic Synthesis of Alcohols (Enerkem); Status of the GoBiGas-project (Goeteborg Energi AB.); On-going Gasification Activities in Spain (University of Zaragoza,); Biomass Gasification Research in Italy (University of Perugia.); RDandD Needs and Recommendations for the Commercialization of High-efficient Bio-SNG (Energy Research Centre of the Netherlands.); Cleaning and Usage of Product Gas from Biomass Steam Gasification (Vienna University of Technology); Biomass Gasification and Catalytic Tar Cracking Process Development (Research Triangle Institute); Syngas Cleaning with Catalytic Tar Reforming (Franhofer UMSICHT); Biomass Gas Cleaning and Utilization - The Topsoee Perspective (Haldor Topsoee A/S); OLGA Tar Removal Technology (Dahlman); Bio-SNG - Strategy and Activities within E.ON (E.ON Ruhrgas AG); Strategy and Gasification Activities within Sweden (Swedish Energy Agency); 20 TWh/year Biomethane (Swedish Gas Association)

MAGNETIC SPECTROMETER DESIGN FOR ELECTRON SCATTERING ABOVE 1 Bev

Energy Technology Data Exchange (ETDEWEB)

Schopper, H.

1963-06-15

Design considerations are discussed for magnetic spectrometer electron scattering investigations with the higher energy (above 1 Bev) electron sources which are being developed. The spectrometers are to be used to discriminate between elastic and inelastic processes. A momentum resolution of the order of one per cent is required for these experiments. Various spectrometers are compared according to their optical properties and the number of magnets they consist of. (R.E.U.)

Echelle grating multi-order imaging spectrometer utilizing a catadioptric lens

Science.gov (United States)

Chrisp, Michael P; Bowers, Joel M

2014-05-27

A cryogenically cooled imaging spectrometer that includes a spectrometer housing having a first side and a second side opposite the first side. An entrance slit is on the first side of the spectrometer housing and directs light to a cross-disperser grating. An echelle immersions grating and a catadioptric lens are positioned in the housing to receive the light. A cryogenically cooled detector is located in the housing on the second side of the spectrometer housing. Light from the entrance slit is directed to the cross-disperser grating. The light is directed from the cross-disperser grating to the echelle immersions grating. The light is directed from the echelle immersions grating to the cryogenically cooled detector on the second side of the spectrometer housing.

Upgrade of the NASA 4STAR (Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research) to its Full Science Capability of Sun-Sky-Cloud-Trace Gas Spectrometry in Airborne Science Deployments

Science.gov (United States)

Johnson, Roy R.; Russell, P.; Dunagan, S.; Redemann, J.; Shinozuka, Y.; Segal-Rosenheimer, M.; LeBlanc, S.; Flynn, C.; Schmid, B.; Livingston, J.

2014-01-01

The objectives of this task in the AITT (Airborne Instrument Technology Transition) Program are to (1) upgrade the NASA 4STAR (Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research) instrument to its full science capability of measuring (a) direct-beam sun transmission to derive aerosol optical depth spectra, (b) sky radiance vs scattering angle to retrieve aerosol absorption and type (via complex refractive index spectra, shape, and mode-resolved size distribution), (c) zenith radiance for cloud properties, and (d) hyperspectral signals for trace gas retrievals, and (2) demonstrate its suitability for deployment in challenging NASA airborne multiinstrument campaigns. 4STAR combines airborne sun tracking, sky scanning, and zenith pointing with diffraction spectroscopy to improve knowledge of atmospheric constituents and their links to air pollution, radiant energy budgets (hence climate), and remote measurements of Earth's surfaces. Direct beam hyperspectral measurement of optical depth improves retrievals of gas constituents and determination of aerosol properties. Sky scanning enhances retrievals of aerosol type and size distribution. 4STAR measurements are intended to tighten the closure between satellite and ground-based measurements. 4STAR incorporates a modular sun-tracking/sky-scanning optical head with fiber optic signal transmission to rack mounted spectrometers, permitting miniaturization of the external optical head, and future detector evolution. 4STAR test flights, as well as science flights in the 2012-13 TCAP (Two-Column Aerosol Project) and 2013 SEAC4RS (Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys) have demonstrated that the following are essential for 4STAR to achieve its full science potential: (1) Calibration stability for both direct-beam irradiance and sky radiance, (2) Improved light collection and usage, and (3) Improved flight operability and reliability. A particular challenge

High-energy e- /e+ spectrometer via coherent interaction in a bent crystal

Science.gov (United States)

Bagli, Enrico; Guidi, Vincenzo; Howard, Alexander

2018-01-01

We propose a novel spectrometer based on the crystal channeling effect capable of discriminating between positive and negative particles well beyond the TeV energy scale. The atomic order of a crystalline structure generates an electrostatic field built up by all the atoms in the crystals, which confines charged particle trajectories between neighbouring atomic planes. Through such an interaction in a tiny curved crystal, the same dynamical action on the highest energy particles as that of a huge superconducting magnet is achieved. Depending on the charge sign, points of equilibrium of the oscillatory motion under channeling lie between or on atomic planes for positive and negative particles, respectively, forcing positive particles to stably oscillate far from the planes, while negative ones repeatedly cross them. The different interaction rate with atomic planes causes a tremendous discrepancy between the deflection efficiency of positive and negative particles under channeling. We suggest the use of interactions between charged particles and oriented bent crystals as a novel non-cryogenic passive charge spectrometer to aid the search for dark matter in the Universe in satellite-borne experiment. The limited angular acceptance makes this technique particularly suited for directional local sources of energetic charged particles.

Tentative detection of warm intervening gas towards PKS 0548-322 with XMM-Newton

Energy Technology Data Exchange (ETDEWEB)

Barcons, X.

2005-03-17

We present the results of a long ({approx} 93 ksec) XMM-Newton observation of the bright BL-Lac object PKS 0548-322 (z = 0.069). Our Reflection Grating Spectrometer (RGS) spectrum shows a single absorption feature at an observed wavelength {lambda} = 23.33 {+-} 0.01 {angstrom} which we interpret as OVI K{alpha} absorption at z = 0.058, i.e., {approx} 3000 km s{sup -1} from the background object. The observed equivalent width of the absorption line {approx} 30m {angstrom}, coupled with the lack of the corresponding absorption edge in the EPIC pn data, implies a column density N{sub OVI} {approx} 2 x 10{sup 16} cm{sup -2} and turbulence with a Doppler velocity parameter b > 100 km s{sup -1}. Within the limitations of our RGS spectrum, no OVII or OV K{alpha} absorption are detected. Under the assumption of ionization equilibrium by both collisions and the extragalactic background, this is only marginally consistent if the gas temperature is {approx} 2.5 x 10{sup 5} K, with significantly lower or higher values being excluded by our limits on OV or OVII. If confirmed, this would be the first X-ray detection of a large amount of intervening warm absorbing gas through OVI absorption. The existence of such a high column density absorber, much stronger than any previously detected one in OVI, would place stringent constraints on the large-scale distribution of baryonic gas in the Universe.

Miniature Neutron-Alpha Activation Spectrometer

Science.gov (United States)

Rhodes, E.; Goldsten, J.

2001-01-01

We are developing a miniature neutron-alpha activation spectrometer for in situ analysis of samples including rocks, fines, ices, and drill cores, suitable for a lander or Rover platform, that would meet the severe mass, power, and environmental constraints of missions to the outer planets. In the neutron-activation mode, a gamma-ray spectrometer will first perform a penetrating scan of soil, ice, and loose material underfoot (depths to 10 cm or more) to identify appropriate samples. Chosen samples will be analyzed in bulk in neutron-activation mode, and then the sample surfaces will be analyzed in alpha-activation mode using Rutherford backscatter and x-ray spectrometers. The instrument will provide sample composition over a wide range of elements, including rock-forming elements (such as Na, Mg, Si, Fe, and Ca), rare earths (Sm and Eu for example), radioactive elements (K, Th, and U), and light elements present in water, ices, and biological materials (mainly H, C, O, and N). The instrument is expected to have a mass of about l kg and to require less than 1 W power. Additional information is contained in the original extended abstract.

VERITAS: Versatile Triple-Axis Spectrometer

Energy Technology Data Exchange (ETDEWEB)

Park, Sung Il

2006-04-15

Korea Atomic Energy Research Institute is planning to build a cold neutron triple-axis spectrometer at HANARO, the 30 MW research reactor. The spectrometer is expected to be completed in 2008 with the following configuration from the upstream to the downstream. Guide Supermirror m = 2, In-pile Straight Section, {approx} 5 m Curved Guide, {approx} 26 m w/ R 1500 m Straight Guide before the Instrument, {approx} 40 m Filters PG and Be Neutron Velocity Selector (Future) Monochromators Vertically Focusing Monochromators PG(002) and Heusler(111) Doubly Focusing Monochromators (Future) Monochromator-Sample Distance 2 m Collimation C1 Soller Collimators, 20', 40' 80'Beam Height at the Sample Table 1.5 m Sample-Analyzer Distance 1.0 m Collimation C2 Soller Collimators, 20', 40', 80' Radial Collimator Analyzers Horizontally Focusing Analyzers w/ Fixed Vertical Focusing PG(002) and Heusler(111) Analyzer-Detector Distance 0.5 m Detectors 5 cm Tube Detector 25 cm wide Position Sensitive Detector Once completed, the neutron flux at sample is expected to surpass that of SPINS at NCNR, making this instrument one of the most powerful 2nd generation cold neutron triple-axis spectrometers in the world.

VERITAS: Versatile Triple-Axis Spectrometer

International Nuclear Information System (INIS)

Park, Sung Il

2006-04-01

Korea Atomic Energy Research Institute is planning to build a cold neutron triple-axis spectrometer at HANARO, the 30 MW research reactor. The spectrometer is expected to be completed in 2008 with the following configuration from the upstream to the downstream. Guide Supermirror m = 2, In-pile Straight Section, ∼ 5 m Curved Guide, ∼ 26 m w/ R 1500 m Straight Guide before the Instrument, ∼ 40 m Filters PG and Be Neutron Velocity Selector (Future) Monochromators Vertically Focusing Monochromators PG(002) and Heusler(111) Doubly Focusing Monochromators (Future) Monochromator-Sample Distance 2 m Collimation C1 Soller Collimators, 20', 40' 80'Beam Height at the Sample Table 1.5 m Sample-Analyzer Distance 1.0 m Collimation C2 Soller Collimators, 20', 40', 80' Radial Collimator Analyzers Horizontally Focusing Analyzers w/ Fixed Vertical Focusing PG(002) and Heusler(111) Analyzer-Detector Distance 0.5 m Detectors 5 cm Tube Detector 25 cm wide Position Sensitive Detector Once completed, the neutron flux at sample is expected to surpass that of SPINS at NCNR, making this instrument one of the most powerful 2nd generation cold neutron triple-axis spectrometers in the world

Theory and optical design of x-ray echo spectrometers

Science.gov (United States)

Shvyd'ko, Yuri

2017-08-01

X-ray echo spectroscopy, a space-domain counterpart of neutron spin echo, is a recently proposed inelastic x-ray scattering (IXS) technique. X-ray echo spectroscopy relies on imaging IXS spectra and does not require x-ray monochromatization. Due to this, the echo-type IXS spectrometers are broadband, and thus have a potential to simultaneously provide dramatically increased signal strength, reduced measurement times, and higher resolution compared to the traditional narrow-band scanning-type IXS spectrometers. The theory of x-ray echo spectrometers presented earlier [Yu. Shvyd'ko, Phys. Rev. Lett. 116, 080801 (2016), 10.1103/PhysRevLett.116.080801] is developed here further with a focus on questions of practical importance, which could facilitate optical design and assessment of the feasibility and performance of the echo spectrometers. Among others, the following questions are addressed: spectral resolution, refocusing condition, echo spectrometer tolerances, refocusing condition adjustment, effective beam size on the sample, spectral window of imaging and scanning range, impact of the secondary source size on the spectral resolution, angular dispersive optics, focusing and collimating optics, and detector's spatial resolution. Examples of optical designs and characteristics of echo spectrometers with 1-meV and 0.1-meV resolutions are presented.

Standalone vertex finding in the ATLAS muon spectrometer

DEFF Research Database (Denmark)

Aad, A.; Abajyan, T.; Abbott, B.

2014-01-01

A dedicated reconstruction algorithm to find decay vertices in the ATLAS muon spectrometer is presented. The algorithm searches the region just upstream of or inside the muon spectrometer volume for multi-particle vertices that originate from the decay of particles with long decay paths. The perf......A dedicated reconstruction algorithm to find decay vertices in the ATLAS muon spectrometer is presented. The algorithm searches the region just upstream of or inside the muon spectrometer volume for multi-particle vertices that originate from the decay of particles with long decay paths....... The performance of the algorithm is evaluated using both a sample of simulated Higgs boson events, in which the Higgs boson decays to long-lived neutral particles that in turn decay to bbar b final states, and pp collision data at √s = 7 TeV collected with the ATLAS detector at the LHC during 2011....

Trace Gas Retrievals from the GeoTASO Aircraft Instrument

Science.gov (United States)

Nowlan, C. R.; Liu, X.; Leitch, J. W.; Liu, C.; Gonzalez Abad, G.; Chance, K.; Cole, J.; Delker, T.; Good, W. S.; Murcray, F.; Ruppert, L.; Soo, D.; Loughner, C.; Follette-Cook, M. B.; Janz, S. J.; Kowalewski, M. G.; Pickering, K. E.; Zoogman, P.; Al-Saadi, J. A.

2015-12-01

The Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) instrument is a passive remote sensing instrument capable of making 2-D measurements of trace gases and aerosols from aircraft. The instrument measures backscattered UV and visible radiation, allowing the retrieval of trace gas amounts below the aircraft at horizontal resolutions on the order of 250 m x 250 m. GeoTASO was originally developed under NASA's Instrument Incubator Program as a test-bed instrument for the Geostationary Coastal and Air Pollution Events (GEO-CAPE) decadal survey mission, and is now also part of risk reduction for the upcoming Tropospheric Emissions: Monitoring of Pollution (TEMPO) and Geostationary Environment Monitoring Spectrometer (GEMS) geostationary satellite missions. We present spatially resolved observations of ozone, nitrogen dioxide, formaldehyde and sulfur dioxide over urban areas and power plants from flights during the DISCOVER-AQ field campaigns in Texas and Colorado, as well as comparisons with observations made by ground-based Pandora spectrometers, in situ monitoring instruments and other aircraft instruments deployed during these campaigns. These measurements at various times of day are providing a very useful data set for testing and improving TEMPO and GEMS retrieval algorithms, as well as demonstrating prototype validation strategies.

Airborne testing and demonstration of a new flight system based on an Aerodyne N2O-CO2-CO-H2O mini-spectrometer

Science.gov (United States)

Gvakharia, A.; Kort, E. A.; Smith, M. L.; Conley, S.

2017-12-01

Nitrous oxide (N2O) is a powerful greenhouse gas and ozone depleting substance. With high atmospheric backgrounds and small relative signals, N2O emissions have been challenging to observe and understand on regional scales with traditional instrumentation. Fast-response airborne measurements with high precision and accuracy can potentially bridge this observational gap. Here we present flight assessments of a new flight system based on an Aerodyne mini-spectrometer as well as a Los Gatos N2O/CO analyzer during the Fertilizer Emissions Airborne Study (FEAST). With the Scientific Aviation Mooney aircraft, we conducted test flights for both analyzers where a known calibration gas was sampled throughout the flight (`null' tests). Clear altitude/cabin-pressure dependencies were observed for both analyzers if operated in an "off-the-shelf' manner. For the remainder of test flights and the FEAST campaign we used a new flight system based on an Aerodyne mini-spectrometer with the addition of a custom pressure control/calibration system. Instead of using traditional approaches with spectral-zeros and infrequent in-flight calibrations, we employ a high-flow system with stable flow control to enable high frequency (2 minutes), short duration (15 seconds) sampling of a known calibration gas. This approach, supported by the null test, enables correction for spectral drift caused by a variety of factors while maintaining a 90% duty cycle for 1Hz sampling from an aircraft. Preliminary in-flight precisions are estimated at 0.05 ppb, 0.1 ppm, 1 ppb, and 10 ppm for N2O, CO2, CO, and H2O respectively. We also present a further 40 hours of inter-comparison in flight with a Picarro 2301-f ring-down spectrometer demonstrating consistency between CO2 and H2O measurements and no altitude dependent error.

Electronic THz-spectrometer for plasmonic enhanced deep subwavelength layer detection

NARCIS (Netherlands)

Berrier, A.; Schaafsma, M.C.; Gómez Rivas, J.; Schäfer-Eberwein, H.; Haring Bolivar, P.; Tripodi, L.; Matters-Kammerer, M.K.

2015-01-01

We demonstrate the operation of a miniaturized all-electronic CMOS based THz spectrometer with performances comparable to that of a THz-TDS spectrometer in the frequency range 20 to 220 GHz. The use of this all-electronic THz spectrometer for detection of a thin TiO2 layer and a B. subtilis bacteria

Design of a miniaturized integrated spectrometer for spectral tissue sensing

Science.gov (United States)

Belay, Gebirie Yizengaw; Hoving, Willem; Ottevaere, Heidi; van der Put, Arthur; Weltjens, Wim; Thienpont, Hugo

2016-04-01

Minimally-invasive image-guided procedures become increasingly used by physicians to obtain real-time characterization feedback from the tissue at the tip of their interventional device (needle, catheter, endoscopic or laparoscopic probes, etc…) which can significantly improve the outcome of diagnosis and treatment, and ultimately reduce cost of the medical treatment. Spectral tissue sensing using compact photonic probes has the potential to be a valuable tool for screening and diagnostic purposes, e.g. for discriminating between healthy and tumorous tissue. However, this technique requires a low-cost broadband miniature spectrometer so that it is commercially viable for screening at point-of-care locations such as physicians' offices and outpatient centers. Our goal is therefore to develop a miniaturized spectrometer based on diffractive optics that combines the functionalities of a visible/near-infrared (VIS/NIR) and shortwave-infrared (SWIR) spectrometer in one very compact housing. A second goal is that the hardware can be produced in high volume at low cost without expensive time consuming alignment and calibration steps. We have designed a miniaturized spectrometer which operates both in the visible/near-infrared and shortwave-infrared wavelength regions ranging from 400 nm to 1700 nm. The visible/near-infrared part of the spectrometer is designed for wavelengths from 400 nm to 800 nm whereas the shortwave-infrared segment ranges from 850 nm to 1700 nm. The spectrometer has a resolution of 6 nm in the visible/near-infrared wavelength region and 10 nm in the shortwave-infrared. The minimum SNR of the spectrometer for the intended application is about 151 in the VIS/NIR range and 6000 for SWIR. In this paper, the modelling and design, and power budget analysis of the miniaturized spectrometer are presented. Our work opens a door for future affordable micro- spectrometers which can be integrated with smartphones and tablets, and used for point

Feasibility study of a SiC sandwich neutron spectrometer

Energy Technology Data Exchange (ETDEWEB)

Wu, Jian, E-mail: caepwujian@163.com [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, Sichuan Province (China); Lei, Jiarong, E-mail: jiarong_lei@163.com [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, Sichuan Province (China); Jiang, Yong; Chen, Yu; Rong, Ru; Zou, Dehui; Fan, Xiaoqiang [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, Sichuan Province (China); Chen, Gang; Li, Li; Bai, Song [Nanjing Electronic Devices Institute, Nanjing 210016 (China)

2013-04-21

Semiconductor sandwich neutron spectrometers are suitable for in-pile measurements of fast reactor spectra thanks to their compact and relatively simple design. We have assembled and tested a sandwich neutron spectrometer based on 4H-silicon carbide (4H-SiC) Schottky diodes. The SiC diodes detect neutrons via neutron-induced charged particles (tritons and alpha particles) produced by {sup 6}Li(n,α){sup 3}H reaction. {sup 6}LiF neutron converter layers are deposited on the front surface of Schottky diodes by magnetron sputtering. The responses of SiC diodes to charged particles were investigated with an {sup 241}Am alpha source. A sandwich neutron spectrometer was assembled with two SiC Schottky diodes selected based on the charged-particle-response experimental results. The low-energy neutron response of the sandwich spectrometer was measured in the neutron field of the Chinese Fast Burst Reactor-II (CFBR-II). Spectra of alpha particles and tritons from {sup 6}Li(n,α){sup 3}H reaction were obtained with two well-resolved peaks. The energy resolution of the sum spectrum was 8.8%. The primary experimental results confirmed the 4H-SiC sandwich neutron spectrometer's feasibility. -- Highlights: ► Sandwich neutron spectrometer employing 4H-SiC as a detecting material has been developed for the first time. ► {sup 6}LiF neutron converter has been deposited on the surface of 4H-SiC Schottky diode. ► Preliminary testing results obtained with the 4H-SiC sandwich neutron spectrometer are presented.

Evaluation of HOPG mounting possibilities for multiplexing spectrometers

DEFF Research Database (Denmark)

Groitl, Felix; Bartkowiak, Marek; Bergmann, Ryan M.

2017-01-01

Four different methods for mounting HOPG analyzer crystals on Si holders have been evaluated in the design process of the new multiplexing spectrometer CAMEA. Contrary to neutron optics used in standard spectrometers, the new instrument concept employs a series of analyzer segments behind each...

Evaluation of HOPG mounting possibilities for multiplexing spectrometers

Energy Technology Data Exchange (ETDEWEB)

Groitl, Felix, E-mail: felix.groitl@psi.ch [Laboratory for Quantum Magnetism, École Polytechnique Fédérale de Lausanne, 1015 Lausanne (Switzerland); Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, 5232 Villigen (Switzerland); Bartkowiak, Marek [Laboratory for Scientific Developments and Novel Materials, Paul Scherrer Institut, 5232 Villigen (Switzerland); Bergmann, Ryan M. [Division Large Research Facilities, Paul Scherrer Institut, 5232 Villigen (Switzerland); Birk, Jonas Okkels [Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, 5232 Villigen (Switzerland); Department of Physics, Technical University of Denmark (DTU), 2800 Kgs. Lyngby (Denmark); Markó, Márton [Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, 5232 Villigen (Switzerland); Wigner Research Centre for Physics, Neutron Spectroscopy Department, 1525 Budapest (Hungary); Bollhalder, Alex; Graf, Dieter [Laboratory for Scientific Developments and Novel Materials, Paul Scherrer Institut, 5232 Villigen (Switzerland); Niedermayer, Christof [Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, 5232 Villigen (Switzerland); Rüegg, Christian [Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, 5232 Villigen (Switzerland); Department of Quantum Matter Physics, University of Geneva, 1211 Geneva (Switzerland); Rønnow, Henrik M. [Laboratory for Quantum Magnetism, École Polytechnique Fédérale de Lausanne, 1015 Lausanne (Switzerland); Niels Bohr Institute, University of Copenhagen, 2100 Copenhagen (Denmark)

2017-06-21

Four different methods for mounting HOPG analyzer crystals on Si holders have been evaluated in the design process of the new multiplexing spectrometer CAMEA. Contrary to neutron optics used in standard spectrometers, the new instrument concept employs a series of analyzer segments behind each other where the neutrons have to pass through the bonding compound of the different analyzer crystals. The different methods, namely screws, shellac, indium soldering and clips, have been evaluated with regards to background, transmission, cooling, activation and handling. The results presented here will give valuable input for future CAMEA-type spectrometers currently planned and designed at various neutron sources.

Design and Test of Portable Hyperspectral Imaging Spectrometer

Directory of Open Access Journals (Sweden)

Chunbo Zou

2017-01-01

Full Text Available We design and implement a portable hyperspectral imaging spectrometer, which has high spectral resolution, high spatial resolution, small volume, and low weight. The flight test has been conducted, and the hyperspectral images are acquired successfully. To achieve high performance, small volume, and regular appearance, an improved Dyson structure is designed and used in the hyperspectral imaging spectrometer. The hyperspectral imaging spectrometer is suitable for the small platform such as CubeSat and UAV (unmanned aerial vehicle, and it is also convenient to use for hyperspectral imaging acquiring in the laboratory and the field.

Evaluation of HOPG mounting possibilities for multiplexing spectrometers

International Nuclear Information System (INIS)

Groitl, Felix; Bartkowiak, Marek; Bergmann, Ryan M.; Birk, Jonas Okkels; Markó, Márton; Bollhalder, Alex; Graf, Dieter; Niedermayer, Christof; Rüegg, Christian; Rønnow, Henrik M.

2017-01-01

Four different methods for mounting HOPG analyzer crystals on Si holders have been evaluated in the design process of the new multiplexing spectrometer CAMEA. Contrary to neutron optics used in standard spectrometers, the new instrument concept employs a series of analyzer segments behind each other where the neutrons have to pass through the bonding compound of the different analyzer crystals. The different methods, namely screws, shellac, indium soldering and clips, have been evaluated with regards to background, transmission, cooling, activation and handling. The results presented here will give valuable input for future CAMEA-type spectrometers currently planned and designed at various neutron sources.

Development and evaluation of the Combined Ion and Neutron Spectrometer (CINS)

International Nuclear Information System (INIS)

Zeitlin, C.; Maurer, R.; Roth, D.; Goldsten, J.; Grey, M.

2009-01-01

The Combined Ion and Neutron Spectrometer, CINS, is designed to measure the charged and neutral particles that contribute to the radiation dose and dose equivalent received by humans in spaceflight. As the depth of shielding increases, either onboard a spacecraft or in a surface habitat, the relative contribution of neutrons increases significantly, so that obtaining accurate neutron spectra becomes a critical part of any dosimetric measurements. The spectrometer system consists of high- and medium-energy neutron detectors along with a charged-particle detector telescope based on a standard silicon stack concept. The present version of the design is intended for ground-based use at particle accelerators; future iterations of the design can easily be streamlined to reduce volume, mass, and power consumption to create an instrument package suitable for spaceflight. The detector components have been tested separately using high-energy heavy ion beams at the NASA Space Radiation Laboratory at the Brookhaven National Laboratory and neutron beams at the Radiological Research Accelerator Facility operated by Columbia University. Here, we review the progress made in fabricating the hardware, report the results of several test runs, and discuss the remaining steps necessary to combine the separate components into an integrated system. A custom data acquisition system built for CINS is described in an accompanying article.

High Resolution Stellar Spectroscopy with VBT Echelle Spectrometer

Indian Academy of Sciences (India)

Easy operations. We finally preferred the all transmitting system for the spectrometer with the optical surfaces anti-reflection coated to optimize the throughput rather than reflecting cameras with central obscurations. Following other optimized throughput spectrometers like. Sandiford at McDonald Observatory (McCarthy et al ...

Scanning electron microscopy-energy dispersive X-ray spectrometer ...

African Journals Online (AJOL)

The distribution of arsenic (As) and cadmium (Cd) in himematsutake was analyzed using scanning electron microscopy-energy dispersive X-ray spectrometer (SEM-EDX). The atomic percentage of the metals was confirmed by inductively coupled plasma-mass spectrometer (ICP-MS). Results show that the accumulation of ...

Indigenously built resonance ionization mass spectrometer

International Nuclear Information System (INIS)

Razvi, M.A.N.; Jayasekharan, T.; Thankarajan, K.; Guhagarkar, M.B.; Dixit, M.N.; Bhale, G.L.

2000-04-01

Design, fabrication and performance testing of an indigenously built Resonance Ionization Mass Spectrometer (RIMS) is presented in this report. The instrument is totally indigenous, but for the laser components consisting of the excimer laser and tunable dye lasers. Constructional details of atomic beam source and linear time-of-flight mass spectrometer are included. Finally, commissioning and performance testing of the instrument is described. Mass resolving power of 400 and a detection limit of 100 atoms has been achieved using this RIMS set-up. (author)

Setup of Mössbauer spectrometers at RCPTM

Science.gov (United States)

Pechoušek, J.; Jančík, D.; Frydrych, J.; Navařík, J.; Novák, P.

2012-10-01

Setup of Mössbauer spectrometers (MS) for structural, phase, and magnetic characterization of iron-or tin-containing samples is presented. This comprehensive line of 57Fe and 119Sn Mössbauer spectrometers covers transmission spectrometers (TMS) for roomtemperature (RT) measurements, temperature dependent measurements and measurements in an external magnetic field. An RT Conversion Electron/Conversion X-ray Mössbauer technique (CEMS/CXMS) is also available. The main concept of the RT MS is a table-top spectrometric bench with a control unit based on special-purpose hardware or standard PC platform. The first way offers a compact design and PC independent spectra collection system. The second setup, a PC-based system, which uses commercial devices and LabVIEW software, offers easy customization and enables advancement in spectrometer construction. The both types of control systems are able to operate special parts (velocity transducers, gamma-ray detectors) of unusual spectrometric benches. The standard velocity axis range is up to ±20 mm/s with a maximum nonlinearity of 0.1%. Applicable measuring conditions of presented TMSs cover a cryogenic temperature range from 1.5 up to 300 K and high temperature range from RT up to 1000 °C. With in-field low-temperature MS, we are able to analyze samples normally in the external magnetic fields up to 8 T (in temperature interval from 1.5 up to 300 K). In addition, special modes of measurements can be applied including backscattering gamma-ray geometry or measurement in an inert or controlled-humidity atmosphere. Technical details and construction aspects of spectrometers are presented.

A combined heating cooling stage for cluster thermalization in the gas phase

International Nuclear Information System (INIS)

Ievlev, D.N.; Kuester, A.; Enders, A.; Malinowski, N.; Schaber, H.; Kern, K.

2003-01-01

We report on the design and performance of a combined heating/cooling stage for the thermalization of clusters in a gas phase time-of-flight mass spectrometer. With this setup the cluster temperature can sensitively be adjusted within the range from 100 up to 800 K and higher. The unique combination of a heating stage with a subsequent cooling stage allows us to perform thermodynamic investigations on clusters at very high temperatures without quality losses in the spectra due to delayed fragmentation in the drift tube of the mass spectrometer. The performance of the setup is demonstrated by the example of (C 60 ) n clusters

Design of ITER divertor VUV spectrometer and prototype test at KSTAR tokamak

Science.gov (United States)

Seon, Changrae; Hong, Joohwan; Song, Inwoo; Jang, Juhyeok; Lee, Hyeonyong; An, Younghwa; Kim, Bosung; Jeon, Taemin; Park, Jaesun; Choe, Wonho; Lee, Hyeongon; Pak, Sunil; Cheon, MunSeong; Choi, Jihyeon; Kim, Hyeonseok; Biel, Wolfgang; Bernascolle, Philippe; Barnsley, Robin; O'Mullane, Martin

2017-12-01

Design and development of the ITER divertor VUV spectrometer have been performed from the year 1998, and it is planned to be installed in the year 2027. Currently, the design of the ITER divertor VUV spectrometer is in the phase of detail design. It is optimized for monitoring of chord-integrated VUV signals from divertor plasmas, chosen to contain representative lines emission from the tungsten as the divertor material, and other impurities. Impurity emission from overall divertor plasmas is collimated through the relay optics onto the entrance slit of a VUV spectrometer with working wavelength range of 14.6-32 nm. To validate the design of the ITER divertor VUV spectrometer, two sets of VUV spectrometers have been developed and tested at KSTAR tokamak. One set of spectrometer without the field mirror employs a survey spectrometer with the wavelength ranging from 14.6 nm to 32 nm, and it provides the same optical specification as the spectrometer part of the ITER divertor VUV spectrometer system. The other spectrometer with the wavelength range of 5-25 nm consists of a commercial spectrometer with a concave grating, and the relay mirrors with the same geometry as the relay mirrors of the ITER divertor VUV spectrometer. From test of these prototypes, alignment method using backward laser illumination could be verified. To validate the feasibility of tungsten emission measurement, furthermore, the tungsten powder was injected in KSTAR plasmas, and the preliminary result could be obtained successfully with regard to the evaluation of photon throughput. Contribution to the Topical Issue "Atomic and Molecular Data and their Applications", edited by Gordon W.F. Drake, Jung-Sik Yoon, Daiji Kato, Grzegorz Karwasz.

Design and construction of a NIR spectrometer

CERN Document Server

Barcala-Riveira, J M; Fernandez-Marron, J L; Molero-Menendez, F; Navarrete-Marin, J J; Oller-Gonzalez, J C

2003-01-01

This document describes the design and construction of a NIR spectrometer based on an acoustic-optic tunable filter. The spectrometer will be used for automatic identification of plastics in domestic waste. The system works between 1200 and 1800 nm. Instrument is controlled by a personal computer. Computer receives and analyses data. A software package has been developed to do these tasks. (Author) 27 refs.

1987 calibration of the TFTR neutron spectrometers

International Nuclear Information System (INIS)

Barnes, C.W.; Strachan, J.D.; Princeton Univ., NJ

1989-12-01

The 3 He neutron spectrometer used for measuring ion temperatures and the NE213 proton recoil spectrometer used for triton burnup measurements were absolutely calibrated with DT and DD neutron generators placed inside the TFTR vacuum vessel. The details of the detector response and calibration are presented. Comparisons are made to the neutron source strengths measured from other calibrated systems. 23 refs., 19 figs., 6 tabs

Design and construction of a NIR spectrometer

International Nuclear Information System (INIS)

Barcala Riveira, J. M.; Fernandez Marron, J. L.; Alberdi Primicia, J.; Molero Menendez, F.; Navarrete Marin, J. J.; Oller Gonzalez, J. C.

2003-01-01

This document describes the design and construction of a NIR spectrometer based on an acoustic-optic tunable filter. The spectrometer will be used for automatic identification of plastics in domestic waste. The system works between 1200 and 1800 nm. Instrument is controlled by a personal computer. Computer receives and analyses data. A software package has been developed to do these tasks. (Author) 27 refs

Ageing studies for the ATLAS MDT Muonchambers and development of a gas filter to prevent drift tube ageing

CERN Document Server

König, Stefan

2008-01-01

The muon spectrometer of the ATLAS detector at CERN uses drift tubes as basic detection elements over most of the solid angle. The performance of these monitored drift tubes (MDTs), in particular their spatial resolution of 80 µm, determines the precision of the spectrometer. If ageing effects occur, the precision of the drift tubes will be degraded. Hence ageing effects have to be minimized or avoided altogether if possible. Even with a gas mixture of Ar:CO2 (93:7), which was selected for its good ageing properties, ageing effects were observed in test systems. They were caused by small amounts of impurities, in particular volatile silicon compounds. Systematic studies revealed the required impurity levels deteriorating the drift tubes to be well below 1 ppm. Many components of the ATLAS MDT gas system are supplied by industry. In a newly designed ageing experiment in Freiburg these components were validated for their use in ATLAS. With a fully assembled ATLAS gas distribution rack as test component ageing ...

The Little Cub: Discovery of an Extremely Metal-poor Star-forming Galaxy in the Local Universe

Energy Technology Data Exchange (ETDEWEB)

Hsyu, Tiffany; Prochaska, J. Xavier; Bolte, Michael [Department of Astronomy and Astrophysics, University of California Santa Cruz, 1156 High Street, Santa Cruz, CA 95060 (United States); Cooke, Ryan J. [Centre for Extragalactic Astronomy, Department of Physics, Durham University, South Road, Durham DH1 3LE (United Kingdom)

2017-08-20

We report the discovery of the Little Cub, an extremely metal-poor star-forming galaxy in the local universe, found in the constellation Ursa Major (a.k.a. the Great Bear). We first identified the Little Cub as a candidate metal-poor galaxy based on its Sloan Digital Sky Survey photometric colors, combined with spectroscopy using the Kast spectrograph on the Shane 3 m telescope at Lick Observatory. In this Letter, we present high-quality spectroscopic data taken with the Low Resolution Imaging Spectrometer at Keck Observatory, which confirm the extremely metal-poor nature of this galaxy. Based on the weak [O iii] λ 4363 Å emission line, we estimate a direct oxygen abundance of 12 + log(O/H) = 7.13 ± 0.08, making the Little Cub one of the lowest-metallicity star-forming galaxies currently known in the local universe. The Little Cub appears to be a companion of the spiral galaxy NGC 3359 and shows evidence of gas stripping. We may therefore be witnessing the quenching of a near-pristine galaxy as it makes its first passage about a Milky Way–like galaxy.

The Little Cub: Discovery of an Extremely Metal-poor Star-forming Galaxy in the Local Universe

Science.gov (United States)

Hsyu, Tiffany; Cooke, Ryan J.; Prochaska, J. Xavier; Bolte, Michael

2017-08-01

We report the discovery of the Little Cub, an extremely metal-poor star-forming galaxy in the local universe, found in the constellation Ursa Major (a.k.a. the Great Bear). We first identified the Little Cub as a candidate metal-poor galaxy based on its Sloan Digital Sky Survey photometric colors, combined with spectroscopy using the Kast spectrograph on the Shane 3 m telescope at Lick Observatory. In this Letter, we present high-quality spectroscopic data taken with the Low Resolution Imaging Spectrometer at Keck Observatory, which confirm the extremely metal-poor nature of this galaxy. Based on the weak [O III] λ4363 Å emission line, we estimate a direct oxygen abundance of 12 + log(O/H) = 7.13 ± 0.08, making the Little Cub one of the lowest-metallicity star-forming galaxies currently known in the local universe. The Little Cub appears to be a companion of the spiral galaxy NGC 3359 and shows evidence of gas stripping. We may therefore be witnessing the quenching of a near-pristine galaxy as it makes its first passage about a Milky Way-like galaxy.

The Little Cub: Discovery of an Extremely Metal-poor Star-forming Galaxy in the Local Universe

International Nuclear Information System (INIS)

Hsyu, Tiffany; Prochaska, J. Xavier; Bolte, Michael; Cooke, Ryan J.

2017-01-01

We report the discovery of the Little Cub, an extremely metal-poor star-forming galaxy in the local universe, found in the constellation Ursa Major (a.k.a. the Great Bear). We first identified the Little Cub as a candidate metal-poor galaxy based on its Sloan Digital Sky Survey photometric colors, combined with spectroscopy using the Kast spectrograph on the Shane 3 m telescope at Lick Observatory. In this Letter, we present high-quality spectroscopic data taken with the Low Resolution Imaging Spectrometer at Keck Observatory, which confirm the extremely metal-poor nature of this galaxy. Based on the weak [O iii] λ 4363 Å emission line, we estimate a direct oxygen abundance of 12 + log(O/H) = 7.13 ± 0.08, making the Little Cub one of the lowest-metallicity star-forming galaxies currently known in the local universe. The Little Cub appears to be a companion of the spiral galaxy NGC 3359 and shows evidence of gas stripping. We may therefore be witnessing the quenching of a near-pristine galaxy as it makes its first passage about a Milky Way–like galaxy.

U.S. Geological Survey Noble Gas Laboratory’s standard operating procedures for the measurement of dissolved gas in water samples

Science.gov (United States)

Hunt, Andrew G.

2015-08-12

This report addresses the standard operating procedures used by the U.S. Geological Survey’s Noble Gas Laboratory in Denver, Colorado, U.S.A., for the measurement of dissolved gases (methane, nitrogen, oxygen, and carbon dioxide) and noble gas isotopes (helium-3, helium-4, neon-20, neon-21, neon-22, argon-36, argon-38, argon-40, kryton-84, krypton-86, xenon-103, and xenon-132) dissolved in water. A synopsis of the instrumentation used, procedures followed, calibration practices, standards used, and a quality assurance and quality control program is presented. The report outlines the day-to-day operation of the Residual Gas Analyzer Model 200, Mass Analyzer Products Model 215–50, and ultralow vacuum extraction line along with the sample handling procedures, noble gas extraction and purification, instrument measurement procedures, instrumental data acquisition, and calculations for the conversion of raw data from the mass spectrometer into noble gas concentrations per unit mass of water analyzed. Techniques for the preparation of artificial dissolved gas standards are detailed and coupled to a quality assurance and quality control program to present the accuracy of the procedures used in the laboratory.

Three new extreme ultraviolet spectrometers on NSTX-U for impurity monitoring

Energy Technology Data Exchange (ETDEWEB)

Weller, M. E., E-mail: weller4@llnl.gov; Beiersdorfer, P.; Soukhanovskii, V. A.; Magee, E. W.; Scotti, F. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

2016-11-15

Three extreme ultraviolet (EUV) spectrometers have been mounted on the National Spherical Torus Experiment–Upgrade (NSTX-U). All three are flat-field grazing-incidence spectrometers and are dubbed X-ray and Extreme Ultraviolet Spectrometer (XEUS, 8–70 Å), Long-Wavelength Extreme Ultraviolet Spectrometer (LoWEUS, 190–440 Å), and Metal Monitor and Lithium Spectrometer Assembly (MonaLisa, 50–220 Å). XEUS and LoWEUS were previously implemented on NSTX to monitor impurities from low- to high-Z sources and to study impurity transport while MonaLisa is new and provides the system increased spectral coverage. The spectrometers will also be a critical diagnostic on the planned laser blow-off system for NSTX-U, which will be used for impurity edge and core ion transport studies, edge-transport code development, and benchmarking atomic physics codes.

Perspectives of 2D and 3D mapping of atmospheric pollutants over urban areas by means of airborne DOAS spectrometers

Directory of Open Access Journals (Sweden)

F. Ravegnani

2006-06-01

Full Text Available tants, offering numerous advantages over conventional networks of in situ analysers. We propose some innovative solutions in the field of DOAS (Differential Optical Absorption Spectroscopy remote systems, utilizing diffuse solar light as the radiation source. We examine the numerous potentialities of minor gas slant column calculations, applying the «off-axis» methodology for collecting the diffuse solar radiation. One of these particular approaches, using measurements along horizontal paths, has already been tested with the spectrometer installed on board the Geophysica aircraft during stratospheric flights up to altitudes of 20 km. The theoretical basis of these new measurement techniques using DOAS remote sensing systems are delineated to assess whether low altitude flights can provide 2D and 3D pollution tomography over metropolitan areas. The 2D or 3D trace gas total column mapping could be used to investigate: i transport and dispersion phenomena of air pollution, ii photochemical process rates, iii gas plume tomography, iv minor gas vertical profiles into the Planetary Boundary Layer and v minor gas flux divergence over a large area.

IPNS-I chopper spectrometers

International Nuclear Information System (INIS)

Price, D.L.; Carpenter, J.M.; Pelizzari, C.A.; Sinha, S.K.; Bresof, I.; Ostrowski, G.E.

1982-01-01

We briefly describe the layout and operation of the two chopper experiments at IPNS-I. The recent measurement on solid 4 He by Hilleke et al. provides examples of time-of-flight data from the Low Resolution Chopper Spectrometer

Impact of nonlinearity on changing the a priori of trace gas profile estimates from the Tropospheric Emission Spectrometer (TES

Directory of Open Access Journals (Sweden)

S. S. Kulawik

2008-06-01

Full Text Available Non-linear maximum a posteriori (MAP estimates of atmospheric profiles from the Tropospheric Emission Spectrometer (TES contains a priori information that may vary geographically, which is a confounding factor in the analysis and physical interpretation of an ensemble of profiles. One mitigation strategy is to transform profile estimates to a common prior using a linear operation thereby facilitating the interpretation of profile variability. However, this operation is dependent on the assumption of not worse than moderate non-linearity near the solution of the non-linear estimate. The robustness of this assumption is tested by comparing atmospheric retrievals from the Tropospheric Emission Spectrometer processed with a uniform prior with those processed with a variable prior and converted to a uniform prior following the non-linear retrieval. Linearly converting the prior following a non-linear retrieval is shown to have a minor effect on the results as compared to a non-linear retrieval using a uniform prior when compared to the expected total error, with less than 10% of the change in the prior ending up as unbiased fluctuations in the profile estimate results.

Deep-water gamma-spectrometer based on HP(Ge) detector

International Nuclear Information System (INIS)

Sokolov, A.; Danengirsh, S.; Popov, S.; Pchelincev, A; Gostilo, V.; Kravchenko, S.; Shapovalov, V.; Druzhinin, A.

1995-01-01

Full text: For radionuclide monitoring of the sea bottom near underwater storage of high active waste of nuclear industries and near places of accidents with nuclear submarines the spectrometers of gamma-radiation, which allow to carry out the measurements on the great depth, are needed. Usually, these problems are solved with devices, which are cast down into the water, using the rope, and transmit the signals on the surface by the cable. However, the depth of immersion is limited by this construction and often the conditions of measurement are complicated. The deep water gamma-spectrometer based on HP(Ge) detector for the measurement on the depth up to 3000 m is developed. The spectrometer is completely autonomic and is put up in the selected place, using the manipulator of a deep-water apparatus. The spectrometer is created in two cylindrical cases with 170 mm diameter and 1100 mm length, bearing the high hydrostatic pressure. The part of the case around the detector is created from titanium and has especial construction with a thin wall for increasing the efficiency of registration in the region of low-energy gamma-radiation. The cooling of the semiconductor detector is provided by a coolant which supports the working temperature of the detector during more than 24 hours. The electronic system of the spectrometer includes high voltage supply f or the detector, preamplifier, analog processor, analog-digital converter and a device for collecting and storing information in flash memory. The power supply of the spectrometer is provided by a battery of accumulators, which can be recharged on the surface. The programming of the processor is carried out before immersion by connecting the spectrometer to personal computer using standard interface RS-232. During 24 hours the spectrometer provides registration of 16 spectrums each in 4096 channels. The reading of the information by the computer is carried out after lifting up the spectrometer on the surface in the same

Investigation of background processes in the KATRIN main spectrometer

Energy Technology Data Exchange (ETDEWEB)

Mueller, Axel [Karlsruhe Institute of Technology (KIT), Institut fuer Kernphysik (IKP) (Germany); Collaboration: KATRIN-Collaboration

2016-07-01

The KArlsruhe TRItium Neutrino experiment aims to probe the mass of the electron antineutrino in a model-independent way with an unsurpassed sensitivity of m{sub ν}=200 meV/c{sup 2} (90% C.L.). In order to determine the neutrino mass, the energy spectrum of electrons from the tritium β-decay is analyzed by a high-resolution electrostatic spectrometer which is based on the MAC-E filter principle. To keep the influence of the spectrometer background on the neutrino mass sensitivity small, KATRIN aims for a background level of 0.01 cps. For the investigation of different background components such as cosmic muons, external gamma radiation and the radioactive decay of isotopes in the volume of the spectrometer or on its surface, a series of dedicated measurements were performed with a combined system of main spectrometer and detector. This talk presents the results of measurements focusing on the secondary electron production at the inner surface of the spectrometer and compare them with electro-magnetic electron tracking simulations performed with the KATRIN developed simulation software KASSIOPEIA.

BIS-2 spectrometer for search and investigation of narrow resonances

International Nuclear Information System (INIS)

Aleev, A.N.; Aref'ev, V.A.; Balandin, V.P.

1989-01-01

The configuration and main characteristics of the BIS-2 spectrometer are described. The spectrometer was intended to search for and to investigate charmed particles and narrow resonances produced in neutron-nucleus interactions. It was placed on a neutron beam of the Serpukhov accelerator. The Monte-Carlo simulated and experimentally measured characteristics of individual elements and the spectrometer as a whole are described. A brief review of the principal results based on the analysis of more than 10 7 neutron-nucleus interactions registered by means of the BIS-2 spectrometer is given. 34 refs.; 8 figs.; 5 tabs

A membrane inlet mass spectrometry system for noble gases at natural abundances in gas and water samples.

Science.gov (United States)

Visser, Ate; Singleton, Michael J; Hillegonds, Darren J; Velsko, Carol A; Moran, Jean E; Esser, Bradley K

2013-11-15

Noble gases dissolved in groundwater can reveal paleotemperatures, recharge conditions, and precise travel times. The collection and analysis of noble gas samples are cumbersome, involving noble gas purification, cryogenic separation and static mass spectrometry. A quicker and more efficient sample analysis method is required for introduced tracer studies and laboratory experiments. A Noble Gas Membrane Inlet Mass Spectrometry (NG-MIMS) system was developed to measure noble gases at natural abundances in gas and water samples. The NG-MIMS system consists of a membrane inlet, a dry-ice water trap, a carbon-dioxide trap, two getters, a gate valve, a turbomolecular pump and a quadrupole mass spectrometer equipped with an electron multiplier. Noble gases isotopes (4)He, (22)Ne, (38)Ar, (84)Kr and (132)Xe are measured every 10 s. The NG-MIMS system can reproduce measurements made on a traditional noble gas mass spectrometer system with precisions of 2%, 8%, 1%, 1% and 3% for He, Ne, Ar, Kr and Xe, respectively. Noble gas concentrations measured in an artificial recharge pond were used to monitor an introduced xenon tracer and to reconstruct temperature variations to within 2 °C. Additional experiments demonstrated the capability to measure noble gases in gas and in water samples, in real time. The NG-MIMS system is capable of providing analyses sufficiently accurate and precise for introduced noble gas tracers at managed aquifer recharge facilities, groundwater fingerprinting based on excess air and noble gas recharge temperature, and field and laboratory studies investigating ebullition and diffusive exchange. Copyright © 2013 John Wiley & Sons, Ltd.

Gone with the heat: a fundamental constraint on the imaging of dust and molecular gas in the early Universe.

Science.gov (United States)

Zhang, Zhi-Yu; Papadopoulos, Padelis P; Ivison, R J; Galametz, Maud; Smith, M W L; Xilouris, Emmanuel M

2016-06-01

Images of dust continuum and carbon monoxide (CO) line emission are powerful tools for deducing structural characteristics of galaxies, such as disc sizes, H2 gas velocity fields and enclosed H2 and dynamical masses. We report on a fundamental constraint set by the cosmic microwave background (CMB) on the observed structural and dynamical characteristics of galaxies, as deduced from dust continuum and CO-line imaging at high redshifts. As the CMB temperature rises in the distant Universe, the ensuing thermal equilibrium between the CMB and the cold dust and H2 gas progressively erases all spatial and spectral contrasts between their brightness distributions and the CMB. For high-redshift galaxies, this strongly biases the recoverable H2 gas and dust mass distributions, scale lengths, gas velocity fields and dynamical mass estimates. This limitation is unique to millimetre/submillimetre wavelengths and unlike its known effect on the global dust continuum and molecular line emission of galaxies, it cannot be addressed simply. We nevertheless identify a unique signature of CMB-affected continuum brightness distributions, namely an increasing rather than diminishing contrast between such brightness distributions and the CMB when the cold dust in distant galaxies is imaged at frequencies beyond the Raleigh-Jeans limit. For the molecular gas tracers, the same effect makes the atomic carbon lines maintain a larger contrast than the CO lines against the CMB.

Automated Peak Detection and Matching Algorithm for Gas Chromatography–Differential Mobility Spectrometry

Science.gov (United States)

Fong, Sim S.; Rearden, Preshious; Kanchagar, Chitra; Sassetti, Christopher; Trevejo, Jose; Brereton, Richard G.

2013-01-01

A gas chromatography–differential mobility spectrometer (GC-DMS) involves a portable and selective mass analyzer that may be applied to chemical detection in the field. Existing approaches examine whole profiles and do not attempt to resolve peaks. A new approach for peak detection in the 2D GC-DMS chromatograms is reported. This method is demonstrated on three case studies: a simulated case study; a case study of headspace gas analysis of Mycobacterium tuberculosis (MTb) cultures consisting of three matching GC-DMS and GC-MS chromatograms; a case study consisting of 41 GC-DMS chromatograms of headspace gas analysis of MTb culture and media. PMID:21204557

Beam-transport optimization for cold-neutron spectrometer

Directory of Open Access Journals (Sweden)

Nakajima Kenji

2015-01-01

Full Text Available We report the design of the beam-transport system (especially the vertical geometry for a cold-neutron disk-chopper spectrometer AMATERAS at J-PARC. Based on the elliptical shape, which is one of the most effective geometries for a ballistic mirror, the design was optimized to obtain, at the sample position, a neutron beam with high flux without serious degrading in divergence and spacial homogeneity within the boundary conditions required from actual spectrometer construction. The optimum focal point was examined. An ideal elliptical shape was modified to reduce its height without serious loss of transmission. The final result was adapted to the construction requirements of AMATERAS. Although the ideas studied in this paper are considered for the AMATERAS case, they can be useful also to other spectrometers in similar situations.

A compact multichannel spectrometer for Thomson scattering

Energy Technology Data Exchange (ETDEWEB)

Schoenbeck, N. L.; Schlossberg, D. J.; Dowd, A. S.; Fonck, R. J.; Winz, G. R. [Department of Engineering Physics, University of Wisconsin, Madison, Wisconsin 53706 (United States)

2012-10-15

The availability of high-efficiency volume phase holographic (VPH) gratings and intensified CCD (ICCD) cameras have motivated a simplified, compact spectrometer for Thomson scattering detection. Measurements of T{sub e} < 100 eV are achieved by a 2971 l/mm VPH grating and measurements T{sub e} > 100 eV by a 2072 l/mm VPH grating. The spectrometer uses a fast-gated ({approx}2 ns) ICCD camera for detection. A Gen III image intensifier provides {approx}45% quantum efficiency in the visible region. The total read noise of the image is reduced by on-chip binning of the CCD to match the 8 spatial channels and the 10 spectral bins on the camera. Three spectrometers provide a minimum of 12 spatial channels and 12 channels for background subtraction.

X-ray fluorescence spectrometers: a comparison of wavelength and energy dispersive instruments

International Nuclear Information System (INIS)

Slates, R.V.

1977-11-01

Wavelength dispersive and energy dispersive x-ray fluorescence spectrometers are compared. Separate sections are devoted to principles of operation, sample excitation, spectral resolution, and x-ray detection. Tabulated data from the literature are cited in the comparison of accuracy, precision, and detection limits. Spectral interferences and distortions are discussed. Advantages and limitations are listed for simultaneous wavelength dispersive spectrometers, sequential wavelength dispersive spectrometers, and Si(Li) energy dispersive spectrometers. Accuracy, precision, and detection limits are generally superior for wavelength dispersive spectrometers

UNIVERSITY TURBINE SYSTEMS RESEARCH PROGRAM SUMMARY AND DIRECTORY

Energy Technology Data Exchange (ETDEWEB)

Lawrence P. Golan; Richard A. Wenglarz

2004-07-01

The South Carolina Institute for Energy Studies (SCIES), administratively housed at Clemson University, has participated in the advancement of combustion turbine technology for over a decade. The University Turbine Systems Research Program, previously referred to as the Advanced Gas Turbine Systems Research (AGTSR) program, has been administered by SCIES for the U.S. DOE during the 1992-2003 timeframe. The structure of the program is based on a concept presented to the DOE by Clemson University. Under the supervision of the DOE National Energy Technology Laboratory (NETL), the UTSR consortium brings together the engineering departments at leading U.S. universities and U.S. combustion turbine developers to provide a solid base of knowledge for the future generations of land-based gas turbines. In the UTSR program, an Industrial Review Board (IRB) (Appendix C) of gas turbine companies and related organizations defines needed gas turbine research. SCIES prepares yearly requests for university proposals to address the research needs identified by the IRB organizations. IRB technical representatives evaluate the university proposals and review progress reports from the awarded university projects. To accelerate technology transfer technical workshops are held to provide opportunities for university, industry and government officials to share comments and improve quality and relevancy of the research. To provide educational growth at the Universities, in addition to sponsored research, the UTSR provides faculty and student fellowships. The basis for all activities--research, technology transfer, and education--is the DOE Turbine Program Plan and identification, through UTSR consortium group processes, technology needed to meet Program Goals that can be appropriately researched at Performing Member Universities.

HYSPEC : A CRYSTAL TIME OF FLIGHT HYBRID SPECTROMETER FOR THE SPALLATION NEUTRON SOURCE

International Nuclear Information System (INIS)

SHAPIRO, S.M.; ZALIZNYAK, I.A.

2002-01-01

This document lays out a proposal by the Instrument Development Team (IDT) composed of scientists from leading Universities and National Laboratories to design and build a conceptually new high-flux inelastic neutron spectrometer at the pulsed Spallation Neutron Source (SNS) at Oak Ridge. This instrument is intended to supply users of the SNS and scientific community, of which the IDT is an integral part, with a platform for ground-breaking investigations of the low-energy atomic-scale dynamical properties of crystalline solids. It is also planned that the proposed instrument will be equipped with a polarization analysis capability, therefore becoming the first polarized beam inelastic spectrometer in the SNS instrument suite, and the first successful polarized beam inelastic instrument at a pulsed spallation source worldwide. The proposed instrument is designed primarily for inelastic and elastic neutron spectroscopy of single crystals. In fact, the most informative neutron scattering studies of the dynamical properties of solids nearly always require single crystal samples, and they are almost invariably flux-limited. In addition, in measurements with polarization analysis the available flux is reduced through selection of the particular neutron polarization, which puts even more stringent limits on the feasibility of a particular experiment. To date, these investigations have mostly been carried out on crystal spectrometers at high-flux reactors, which usually employ focusing Bragg optics to concentrate the neutron beam on a typically small sample. Construction at Oak Ridge of the high-luminosity spallation neutron source, which will provide intense pulsed neutron beams with time-averaged fluxes equal to those at medium-flux reactors, opens entirely new opportunities for single crystal neutron spectroscopy. Drawing upon experience acquired during decades of studies with both crystal and time-of-flight (TOF) spectrometers, the IDT has developed a conceptual

HYSPEC : A CRYSTAL TIME OF FLIGHT HYBRID SPECTROMETER FOR THE SPALLATION NEUTRON SOURCE.

Energy Technology Data Exchange (ETDEWEB)

SHAPIRO,S.M.; ZALIZNYAK,I.A.

2002-12-30

This document lays out a proposal by the Instrument Development Team (IDT) composed of scientists from leading Universities and National Laboratories to design and build a conceptually new high-flux inelastic neutron spectrometer at the pulsed Spallation Neutron Source (SNS) at Oak Ridge. This instrument is intended to supply users of the SNS and scientific community, of which the IDT is an integral part, with a platform for ground-breaking investigations of the low-energy atomic-scale dynamical properties of crystalline solids. It is also planned that the proposed instrument will be equipped with a polarization analysis capability, therefore becoming the first polarized beam inelastic spectrometer in the SNS instrument suite, and the first successful polarized beam inelastic instrument at a pulsed spallation source worldwide. The proposed instrument is designed primarily for inelastic and elastic neutron spectroscopy of single crystals. In fact, the most informative neutron scattering studies of the dynamical properties of solids nearly always require single crystal samples, and they are almost invariably flux-limited. In addition, in measurements with polarization analysis the available flux is reduced through selection of the particular neutron polarization, which puts even more stringent limits on the feasibility of a particular experiment. To date, these investigations have mostly been carried out on crystal spectrometers at high-flux reactors, which usually employ focusing Bragg optics to concentrate the neutron beam on a typically small sample. Construction at Oak Ridge of the high-luminosity spallation neutron source, which will provide intense pulsed neutron beams with time-averaged fluxes equal to those at medium-flux reactors, opens entirely new opportunities for single crystal neutron spectroscopy. Drawing upon experience acquired during decades of studies with both crystal and time-of-flight (TOF) spectrometers, the IDT has developed a conceptual

FOCUS: neutron time-of-flight spectrometer at SINQ: recent progress

Energy Technology Data Exchange (ETDEWEB)

Janssen, S.; Mesot, J.; Holitzner, L. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Hempelmann, R. [Saarbruecken Univ. (Germany)

1997-09-01

At the Swiss neutron spallation source SINQ a time-of-flight spectrometer for cold neutrons is under construction. The design foresees a Hybrid solution combining a Fermi chopper with a doubly focusing crystal monochromator. During 1996 important progress has been made concerning the main spectrometer components such as the spectrometer housing and the detector system. (author) 2 figs., 3 refs.

Upgrade of an old Raman Spectrometer

DEFF Research Database (Denmark)

Hansen, Susanne Brunsgaard; Berg, Rolf W.; Stenby, Erling Halfdan

2004-01-01

Improvement of a conventional Jeol Raman spectrometer with a single channel photo multiplier detector is described. New optical components (fibres, mirror, lens and CCD detector) have been chosen to design a high quality and easy-to-use instrument. Tests have shown that with this modified...... spectrometer Raman spectra can be acquired of a quality comparable to the spectra obtained previously, but the time needed to obtain a spectrum is markedly reduced. Selected test spectra and a simple calibration procedure to obtain the wavenumber values from the band CCD pixel position are presented....

Spectrometer Baseline Control Via Spatial Filtering

Science.gov (United States)

Burleigh, M. R.; Richey, C. R.; Rinehart, S. A.; Quijada, M. A.; Wollack, E. J.

2016-01-01

An absorptive half-moon aperture mask is experimentally explored as a broad-bandwidth means of eliminating spurious spectral features arising from reprocessed radiation in an infrared Fourier transform spectrometer. In the presence of the spatial filter, an order of magnitude improvement in the fidelity of the spectrometer baseline is observed. The method is readily accommodated within the context of commonly employed instrument configurations and leads to a factor of two reduction in optical throughput. A detailed discussion of the underlying mechanism and limitations of the method are provided.

A driving system for Moessbauer spectrometer

International Nuclear Information System (INIS)

Maslan, M.; Cholmeckij, A.; Evdokimov, V.; Misevic, O.; Fedorov, A.; Zak, D.

1993-01-01

The driving system of a Moessbauer spectrometer is described. The system comprises a minivibrator, a digital generator of the reference velocity signal, and circuits for controlling the vibrator. The reference velocity signal is stored by the control computer in an intermediate storage. The feedback in the control circuits includes correction for nonlinearity of the driving facility. A Moessbauer spectrometer which is equipped with this driving system exhibits a velocity scale nonlinearity below 0.1%. The resonance line width for sodium nitroprusside is 0.27 ± 0.01 mm/s. (author). 6 figs., 8 refs

Opening the terahertz window on the OSIRIS spectrometer

Directory of Open Access Journals (Sweden)

Demmel F.

2015-01-01

Full Text Available A cooled and mechanically retractable beryllium filter has been installed and commissioned on the low-energy OSIRIS spectrometer at ISIS. This instrument development extends the energy-transfer range of the spectrometer up to ca. 20 meV (∼ 5 THz, leading to an excellent resolution at THz frequencies and substantial gains in detected flux relative to existing capabilities on the neighbouring IRIS spectrometer. Herein, we provide a concise account of this new capability for high-resolution neutron spectroscopy in the THz domain, as well as outline a number of ongoing and potential scientific opportunities in condensed-matter physics, chemistry, and materials science.

Low Power Consumption Laser for Next Generation Miniature Optical Spectrometers for Trace Gas Analysis

Science.gov (United States)

Forouhar, S.; Frez, C.; Franz, K. J.; Ksendzov, A.; Qiu, Y.; Soibel, K. A.; Chen, J.; Hosoda, T.; Kipshidze, G.; Shterengas, L.;

Sensitivity and response time improvements in millimeter-wave spectrometers

International Nuclear Information System (INIS)

Kolbe, W.F.; Leskovar, B.

1980-09-01

A new version of a microwave spectrometer for the detection of gaseous pollutants and other atmospheric constituents is described. The spectrometer, which operates in the vicinity of 70 GHz, employs a Fabry-Perot resonator as a sample cell and uses superhetrodyne detection for high sensitivity. The spectrometer has been modified to incorporate a frequency doubler modulated at 30 MHz to permit operation with a single Gunn oscillator source. As a result, faster response time and somewhat greater sensitivity are obtained. The spectrometer is capable of detecting a minimum concentration of 1 ppM of SO 2 diluted in air with a 1 second time constant. For OCS diluted in air, the minimum detectable concentration is 800 ppB and with a 10 second time constant 300 ppB

4D space access neutron spectrometer 4SEASONS (SIKI)

International Nuclear Information System (INIS)

Kajimoto, Ryoichi; Nakamura, Mitsutaka

2010-01-01

The 4D Space Access Neutron Spectrometer (4SEASONS) is a high-intensity Fermi-chopper spectrometer. It is intended to provide high counting rate for thermal neutrons with medium resolution (ΔE/E i -6% at E=0) to efficiently collect weak inelastic signals from novel spin and lattice dynamics especially in high-T c superconductors and related materials. To achieve this goal, the spectrometer equips advanced instrumental design such as an elliptic-shaped converging neutron guide coated with high-Q c (m=3-4) supermirror, and long-length (2.5 m) 3 He position sensitive detectors (PSDs) arranged cylindrically inside the vacuum scattering chamber. Furthermore, the spectrometer is ready for multi-incident-energy measurements by the repetition rate multiplication method, which greatly improves the measurement efficiency. (author)

High voltage pulse system for the streamer chamber supply of the GIBS spectrometer

International Nuclear Information System (INIS)

Aksinenko, V.D.; Glagoleva, N.S.; Dement'ev, E.A.; Kaminskij, N.I.; Matyushin, A.T.; Matyushin, V.T.; Rozhnyatovskaya, S.A.; Ryakhovskij, V.N.; Nurgozhin, N.N.; Khusainov, E.K.

1987-01-01

Results of development and testing of high voltage pulse system HVPS for the streamer chamber supply of the GIBS spectrometer are presented. HVPS consists of the following basic blocks: nanosecond pulse high voltage generator, high voltage charging supply, trigger generator, chamber parameter control devices, gas-oil vacuuming supply systems, auxiliary and fire-prevention devices. The system blocks are described. Experimental results of HVPC testing are presented. HVPC provides a reliable (10 5 operations) of streamer chamber supply with high voltage pulse parameters: amplitude - 500 kV, amplitude instability (0.5-1.5)%, pulse duration - 12 ns, delay time - 500 ns, delay instability (2.5-5)%, mean frequency of output a signals - 0.1 Hz

Application of a Bonner sphere spectrometer for determination of the energy spectra of neutrons generated by ≈1 MJ plasma focus

Czech Academy of Sciences Publication Activity Database

Králík, M.; Krása, Josef; Velyhan, Andriy; Scholz, M.; Ivanova-Stanik, I.M.; Bienkowska, B.; Miklaszewski, R.; Schmidt, H.; Řezáč, K.; Klír, D.; Kravárik, J.; Kubeš, P.

2010-01-01

Roč. 81, č. 11 (2010), 113503/1-113503/5 ISSN 0034-6748 R&D Projects: GA MŠk LA08024 Grant - others:FP-6 EU(XE) RITA-CT2006-26095 Institutional research plan: CEZ:AV0Z10100523 Keywords : plasma focus * fusion DD neutrons * Bonner sphere spectrometer * energy spectra of scattered neutrons * unfolded and calculated spectra Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.598, year: 2010

Study of gas generation in drum L/ILW packages using hermetic containers

International Nuclear Information System (INIS)

Molnar, M.; Palcsu, L.; Svingor, E.; Futo, I.; Major, Z.; Veres, M.

2005-01-01

Complete text of publication follows. During the storage of low and intermediate level radioactive waste (L/ILW) significant quantities of gas may be produced. It is likely that a small proportion of the generated gas will be radioactive as a result of the incorporation of the isotopes 3 H and 14 C that are present within the waste. To obtain reliable estimates of the quantities and rates of the gas production in L/ILWa series of measurements was carried out of waste packages produced and temporarily stored at the site of Paks Nuclear Power Plant (NPP). Ten drums filled with selected original L/ILW were placed into hermetic containers equipped with sampling valves for repeated sampling. These hermetic containers were stored at the same site where the L/ILW is stored primarily in the Paks NPP. The pressure and the temperature of the headspace gas in the containers were monitored continuously. Qualitative gas component analyses of headspace gases of drums and their containers were executed by quadrupole mass spectrometer. The gas generation rate in the stored L/ILW was calculated by the measured state parameters and the composition variation of the gas in the closed containers. Stable isotope measurements were executed from the CO 2 , CH 4 and N 2 fractions by stable isotope ratio mass spectrometer. Helium measurements were done by noble gas mass spectrometer. The tritium content of the vapour, H 2 and CH 4 fractions was measured by a low background liquid scintillation counter. 14 C content of the CO 2 and CH 4 fractions was measured by a low background gas proportional counter system (ATOMKI). Our results showed that the main generated gases in L/ILW are carbon dioxide, methane, hydrogen and nitrogen. The typical rates were 0.05-0.2 normal litre gas/day for CO 2 and CH 4 generation, and less than 0.02 normal litre gas/day for H 2 . Because of the typical vanishing of the O 2 from the headspace gases no explosive gas mixture was indicated in the L/ILW drums during

Direct classification of olive oils by using two types of ion mobility spectrometers

Energy Technology Data Exchange (ETDEWEB)

Garrido-Delgado, Rocio [Department of Analytical Chemistry, University of Cordoba, Annex C3 Building, Campus of Rabanales, E-14071 Cordoba (Spain); Mercader-Trejo, Flora [Department of Analytical Chemistry, University of Cordoba, Annex C3 Building, Campus of Rabanales, E-14071 Cordoba (Spain); Metrologia de Materiales, Centro Nacional de Metrologia, km. 4.5 Carretera a Los Cues, El Marques, Queretaro (Mexico); Sielemann, Stefanie; Bruyn, Wolfgang de [G.A.S. Gesellschaft fuer analytische Sensorsysteme mbH, BioMedizinZentrumDortmund, Otto-Hahn-Str. 15, 44227 Dortmund (Germany); Arce, Lourdes [Department of Analytical Chemistry, University of Cordoba, Annex C3 Building, Campus of Rabanales, E-14071 Cordoba (Spain); Valcarcel, Miguel, E-mail: qa1meobj@uco.es [Department of Analytical Chemistry, University of Cordoba, Annex C3 Building, Campus of Rabanales, E-14071 Cordoba (Spain)

2011-06-24

Graphical abstract: Highlights: > We explore the use of Ion Mobility Spectrometers for classification of olive oils. > Three types of olive oils were analyzed with both devices coupled to headspace system. > The ion mobility data were processed using chemometric to obtain global information. > The classification rate was better using tritium source and separation step prior IMS. - Abstract: In this work, we explored the use of an Ion Mobility Spectrometry (IMS) device with an ultraviolet (UV) source, and of a Gas Chromatographic (GC) column coupled to an IM Spectrometer with a tritium source, for the discrimination of three grades of olive oil, namely: extra virgin olive oil (EVOO), olive oil (OO) and pomace olive oil (POO). The three types of oil were analyzed with both equipment combinations as coupled to a headspace system and the obtained ion mobility data were consecutively processed with various chemometric tools. The classification rate for an independent validation set was 86.1% (confidence interval at 95% [83.4%, 88.5%]) with an UV-IMS and 100% (confidence interval at 95% [87%, 100%]) using a GC-IMS system. The classification rate was improved by using a more suitable ionization source and a pre-separation step prior to the IM analysis.

Direct classification of olive oils by using two types of ion mobility spectrometers

International Nuclear Information System (INIS)

Garrido-Delgado, Rocio; Mercader-Trejo, Flora; Sielemann, Stefanie; Bruyn, Wolfgang de; Arce, Lourdes; Valcarcel, Miguel

2011-01-01

Graphical abstract: Highlights: → We explore the use of Ion Mobility Spectrometers for classification of olive oils. → Three types of olive oils were analyzed with both devices coupled to headspace system. → The ion mobility data were processed using chemometric to obtain global information. → The classification rate was better using tritium source and separation step prior IMS. - Abstract: In this work, we explored the use of an Ion Mobility Spectrometry (IMS) device with an ultraviolet (UV) source, and of a Gas Chromatographic (GC) column coupled to an IM Spectrometer with a tritium source, for the discrimination of three grades of olive oil, namely: extra virgin olive oil (EVOO), olive oil (OO) and pomace olive oil (POO). The three types of oil were analyzed with both equipment combinations as coupled to a headspace system and the obtained ion mobility data were consecutively processed with various chemometric tools. The classification rate for an independent validation set was 86.1% (confidence interval at 95% [83.4%, 88.5%]) with an UV-IMS and 100% (confidence interval at 95% [87%, 100%]) using a GC-IMS system. The classification rate was improved by using a more suitable ionization source and a pre-separation step prior to the IM analysis.

String Gas Cosmology

OpenAIRE

Brandenberger, Robert H.

2008-01-01

String gas cosmology is a string theory-based approach to early universe cosmology which is based on making use of robust features of string theory such as the existence of new states and new symmetries. A first goal of string gas cosmology is to understand how string theory can effect the earliest moments of cosmology before the effective field theory approach which underlies standard and inflationary cosmology becomes valid. String gas cosmology may also provide an alternative to the curren...

Ion Mobility Spectrometer / Mass Spectrometer (IMS-MS)

Energy Technology Data Exchange (ETDEWEB)

Hunka, Deborah E. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Austin, Daniel [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2005-10-01

The use of Ion Mobility Spectrometry (IMS)in the Detection of Contraband Sandia researchers use ion mobility spectrometers for trace chemical detection and analysis in a variety of projects and applications. Products developed in recent years based on IMS-technology include explosives detection personnel portals, the Material Area Access (MAA) checkpoint of the future, an explosives detection vehicle portal, hand-held detection systems such as the Hound and Hound II (all 6400), micro-IMS sensors (1700), ordnance detection (2500), and Fourier Transform IMS technology (8700). The emphasis to date has been on explosives detection, but the detection of chemical agents has also been pursued (8100 and 6400).

Cyclotrons as mass spectrometers

International Nuclear Information System (INIS)

Clark, D.J.

1984-04-01

The principles and design choices for cyclotrons as mass spectrometers are described. They are illustrated by examples of cyclotrons developed by various groups for this purpose. The use of present high energy cyclotrons for mass spectrometry is also described. 28 references, 12 figures

Microprocessor monitored Auger spectrometer

International Nuclear Information System (INIS)

Sapin, Michel; Ghaleb, Dominique; Pernot, Bernard.

1982-05-01

The operation of an Auger spectrometer, used for studying surface impurity diffusion, has been fully automatized with the help of a microprocessor. The characteristics, performance and practical use of the system are described together with the main advantage for the experimentator [fr

Measurement and simulation of the pressure ratio between the two traps of double Penning trap mass spectrometers

International Nuclear Information System (INIS)

Neidherr, D.; Blaum, K.; Block, M.; Ferrer, R.; Herfurth, F.; Ketelaer, J.; Nagy, Sz.; Weber, C.

2008-01-01

Penning traps are ideal tools to perform high-precision mass measurements. For this purpose the cyclotron frequency of the stored charged particles is measured. In case of on-line mass measurements of short-lived nuclides produced at radioactive beam facilities the ions get in general first prepared and cooled by buffer-gas collisions in a preparation trap to reduce their motional amplitudes and are then transported to a precision trap for the cyclotron frequency determination. In modern Penning trap mass spectrometers both traps are placed in the homogeneous region of one superconducting magnet to optimize the transport efficiency. Because the gas pressure inside the precision trap has to be very low in order to minimize the damping of the ion motion caused by collisions with rest gas molecules during the frequency determination, a pumping barrier is installed between both traps. To predict the pressure difference between the two traps in the region of molecular gas flow the motion of each particle can be simulated without consideration of the other particles. Thus, it is possible to calculate the transit probability through a tube of a given geometry. The results are compared with experimentally obtained pressure differences.

Investigation of Continuous Gas Engine CHP Operation on Biomass Producer Gas

DEFF Research Database (Denmark)

Ahrenfeldt, Jesper; Henriksen, Ulrik Birk; Jensen, Torben Kvist

2005-01-01

More than 2000 hours of gas engine operation with producer gas from biomass as fuel has been conducted on the gasification CHP demonstration and research plant, named “Viking” at the Technical University of Denmark. The gas engine is an integrated part of the entire gasification plant. The excess...... operates with varying excess of air due to variation in gas composition and thus stoichiometry, and a second where the excess of air in the exhaust gas is fixed and the flow rate of produced gas from the gasifier is varying. The interaction between the gas engine and the gasification system has been...... investigated. The engine and the plant are equipped with continuously data acquisition that monitors the operation including the composition of the producer gas and the flow. Producer gas properties and contaminations have been investigated. No detectable tar or particle content was observed...

Step-scan Fourier transform infrared (FTIR) spectrometer for investigating chemical reactions of energy-related materials. Final report, April 1, 1995--March 31, 1997

Energy Technology Data Exchange (ETDEWEB)

Eyring, E.M.

1997-11-04

Two step-scan Fourier transform infrared (FTIR) spectrometers were purchased with URI-DOE funds by the University of Utah. These infrared spectrometers have been used to carry out the following investigations: the determination of strength of adsorption of organic molecules at the liquid-solid interface of coated attenuated total reflectance (ATR) elements, the kinetic study of the photoinitiated polymerization of a dental resin, the exploration of the kinetics of photochemical reactions of organic molecules in solution, and the development of a stopped-flow FTIR interface for measuring rates and mechanisms of reactions in solution that are not photoinitiated and do not have convenient ultraviolet-visible spectral features.

LADEE Neutral Mass Spectrometer Data

Data.gov (United States)

National Aeronautics and Space Administration — This bundle contains the data collected by the Neutral Mass Spectrometer (NMS) instrument aboard the Lunar Atmosphere and Dust Environment Explorer (LADEE)...

A perturbed angular correlation spectrometer for material science ...

Indian Academy of Sciences (India)

A four-detector perturbed angular correlation (PAC) spectrometer has been developed with ultra-fast BaF2 detectors to acquire four coincidence spectra simultaneously, two at 180° and two at 90°. This spectrometer has double efficiency compared to that of a three-detector set-up. Higher efficiency is desirable for PAC ...

A Tale of Energy Transition and Tension: The Incomplete Universalization of the Natural Gas Grid in Istanbul

International Nuclear Information System (INIS)

Arik, Elvan

2013-01-01

Available studies on natural gas networks have so far made little contribution to an understanding of changes in urban management in emerging cities. However, the development of such energy systems, considered as cleaner and more efficient compared to previous systems based primarily on the use of traditional fuels (wood, coal, LPG, biofuels) leads these cities into an energy transition. This process is firstly characterized by the introduction of a new energy resource that then involves changes in certain domestic practices (such as, in our case study, heating and culinary practices). Focusing on the case of the development of the natural gas network in Istanbul, this paper studies the tensions inherent in this transformation. Socio-political and territorial analysis of the deployment of this network, which allows us to evaluate the actual universalization of the service, allows us to turn our attention away from the issue of access to the infrastructure and toward the concrete domestic uses of the service

Combined Raman/LIBS spectrometer elegant breadboard: built and tested - and flight model spectrometer unit

Science.gov (United States)

Ahlers, B.; Hutchinson, I.; Ingley, R.

2017-11-01

A spectrometer for combined Raman and Laser Induced Breakdown Spectroscopy (LIBS) is amongst the different instruments that have been pre-selected for the Pasteur payload of the ExoMars rover. It is regarded as a fundamental, next-generation instrument for organic, mineralogical and elemental characterisation of Martian soil, rock samples and organic molecules. Raman spectroscopy and LIBS will be integrated into a single instrument sharing many hardware commonalities [1]. The combined Raman / LIBS instrument has been recommended as the highest priority mineralogy instrument to be included in the rover's analytical laboratory for the following tasks: Analyse surface and sub-surface soil and rocks on Mars, identify organics in the search for life and determine soil origin & toxicity. The synergy of the system is evident: the Raman spectrometer is dedicated to molecular analysis of organics and minerals; the LIBS provides information on the sample's elemental composition. An international team, under ESA contract and with the leadership of TNO Science and Industry, has built and tested an Elegant Bread Board (EBB) of the combined Raman / LIBS instrument. The EBB comprises a specifically designed, extremely compact, spectrometer with high resolution over a large wavelength range, suitable for both Raman spectroscopy and LIBS measurements. The EBB also includes lasers, illumination and imaging optics as well as fibre optics for light transfer. A summary of the functional and environmental requirements together with a description of the optical design and its expected performance are described in [2]. The EBB was developed and constructed to verify the instruments' end-to-end functional performance with natural samples. The combined Raman / LIBS EBB realisation and test results of natural samples will be presented. For the Flight Model (FM) instrument, currently in the design phase, the Netherlands will be responsible for the design, development and verification of the

BATS - Backscattering And Time-of-flight Spectrometer

International Nuclear Information System (INIS)

Van Eijck, L.; Seydel, T.; Frick, B.; Schober, H.

2011-01-01

The new backscattering spectrometer IN16b will go into commissioning end 2011, providing in its final state about ten times higher count rate than its predecessor, IN16. Here we propose to increase its dynamic range by a factor of 7 with the TOF mode extension, BATS. This will make IN16b the leading high resolution backscattering spectrometer for incoherent quasi-elastic and inelastic neutron scattering; it will be competitive to the coarser resolution inverted geometry backscattering spectrometers that are being brought online at spallation sources. The increased dynamic range will extend the scope of science addressed on IN16b, generating considerable potential in fields such as the hydrogen economy (proton conduction, fuel cells, hydrogen storage), soft matter, biology and nano-science (nano-scale confinement, functionalized polymers). Such a large impact can be achieved using only a moderate investment. (authors)

Wireless, low-cost, FPGA-based miniature gamma ray spectrometer

Energy Technology Data Exchange (ETDEWEB)

Becker, E.M., E-mail: beckere@engr.orst.edu; Farsoni, A.T.

2014-10-11

A compact, low-cost, wireless gamma-ray spectrometer is a tool sought by a number of different organizations in the field of radiation detection. Such a device has applications in emergency response, battlefield assessment, and personal dosimetry. A prototype device fitting this description has been constructed in the Advanced Radiation Instrumentation Laboratory at Oregon State University. The prototype uses a CsI(Tl) scintillator coupled to a solid-state photomultiplier and a 40 MHz, 12-bit, FPGA-based digital pulse processor to measure gamma radiation, and is able to be accessed wirelessly by mobile phone. The prototype device consumes roughly 420 mW, weighs about 28 g (not including battery), and measures 2.54×3.81 cm{sup 2}. The prototype device is able to achieve 5.9% FWHM energy resolution at 662 keV.

Two-lens spectrometer for. beta. polarimetry

Energy Technology Data Exchange (ETDEWEB)

Holdsworth, D; Paul, D [Toronto Univ., Ontario (Canada). Dept. of Physics

1984-06-01

A test spectrometer has been built having four degrees of freedom which have been varied to optimize the transmission in a configuration in which the image distance is large compared to the object distance. Iron-clad magnets of 15 cm effective inside diameter were used. Within the limits of the primary magnet field, the optimized transmission T (%. of 4..pi.. sr) increases as the source is advanced through the magnet towards the polarimeter, approximately as T=5.1 exp(zsub(s)/10.5), where zsub(s) is in cm, measured from the position of peak axial field. When the source-image distance is 1.8 m the optimum separation of the peak axial fields of the magnets is 67+-1 cm and the spectrometer transmission is the same for parallel or antiparallel fields. When operating in the optimum configuration, the spectrometer accepts particles with initial trajectories from 18/sup 0/ to 42/sup 0/ relative to the axis and delivers them at the target with half-angle of convergence less than 4.1/sup 0/.

Development of a gas-ionization {beta}-spectrometer; Etude et realisation d'un spectrometre {beta} a ionisation gazeuse

Energy Technology Data Exchange (ETDEWEB)

Le Du, R [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

1968-05-15

We intend to develop in our laboratory a {beta}-spectrometer. This apparatus will have two main objectives: 1 - the determination of the nature and the degree of purity of certain {beta}-emitting radioactive substances; 2 - the study of an activity calibration process for {beta}-emitting radioactive sources. (author) [French] Nous nous proposons d'etudier et de realiser dans notre laboratoire un spectrometre {beta}. Cet appareil aura deux buts principaux: 1 - determiner la nature et le degre de purete de certains corps radioactifs emetteurs {beta}; 2 - permettre l'etude d'un procede d'etalonnage en activite de sources radioactives emetteurs {beta}. (auteur)

CHIRON – A new high resolution spectrometer for CTIO

Directory of Open Access Journals (Sweden)

Marcy G.W.

2011-07-01

Full Text Available Small telescopes can play an important role in the search for exoplanets because they offer an opportunity for high cadence observations that are not possible with large aperture telescopes. However, there is a shortage of high resolution spectrometers for precision Doppler planet searches. We report on an innovative design for CHIRON, an inexpensive spectrometer that we are building for the 1.5-m telescope at CTIO in Chile. The resolution will be R >80.000, the spectral format spanning 410 to 880 nm. The total throughput of the telescope and spectrometer will be better than 12%, comparable with the efficiency of state-of-the-art spectrometers. The design is driven by the requirements for precision Doppler searches for exoplanets using an iodine cell. The optical layout is a classical echelle with 140 mm beam size. The bench-mounted spectrometer will be fibre-fed followed by an image slicer. An apochromatic refractor is used as the camera. Image quality and throughput of the design are excellent over the full spectral range. Extensive use of commercially available components and avoidance of complicated custom optics are key for quick and resource-efficient implementation.

A multi-parameter, acquisition system positron annihilation lifetime spectrometer

International Nuclear Information System (INIS)

Sharshar, T.

2004-01-01

A positron annihilation lifetime spectrometer employing a multi-parameter acquisition system has been prepared for various purposes such as the investigation and characterization of solid-state materials. The fast-fast coincidence technique was used in the present spectrometer with a pair of plastic scintillation detectors. The acquisition system is based on the Kmax software and on CAMAC modules. The data are acquired in event-by-event list mode. The time spectrum for the desired energy windows can be obtained by off-line data sorting and analysis. The spectrometer for event-by-event data acquisition is an important step to construct a positron age-momentum correlation (AMOC) spectrometer. The AMOC technique is especially suited for the observation of positron transitions between different states during their lifetime. The system performance was tested and the results were presented and discussed

Micro-Spec: An Ultracompact, High-sensitivity Spectrometer for Far-Infrared and Submillimeter Astronomy

Science.gov (United States)

Cataldo, Giuseppe; Hsieh, Wen-Ting; Huang, Wei-Chung; Moseley, S. Harvey; Stevenson, Thomas R.; Wollack, Edward J.

2014-01-01

High-performance, integrated spectrometers operating in the far-infrared and submillimeter ranges promise to be powerful tools for the exploration of the epochs of reionization and initial galaxy formation. These devices, using high-efficiency superconducting transmission lines, can achieve the performance of a meter-scale grating spectrometer in an instrument implemented on a 4 inch silicon wafer. Such a device, when combined with a cryogenic telescope in space, provides an enabling capability for studies of the early universe. Here, the optical design process for Micro-Spec (micron-Spec) is presented, with particular attention given to its two-dimensional diffractive region, where the light of different wavelengths is focused on the different detectors. The method is based on the stigmatization and minimization of the light path function in this bounded region, which results in an optimized geometrical configuration. A point design with an efficiency of (is) approximately 90% has been developed for initial demonstration and can serve as the basis for future instruments. Design variations on this implementation are also discussed, which can lead to lower efficiencies due to diffractive losses in the multimode region.

The development for small scale soft X-ray spectrometer

International Nuclear Information System (INIS)

Sun Kexu; Jiang Shaoen; Yi Rongqing; Cui Yanli

2004-12-01

For the development of small-scale soft X-ray spectrometer, first, some small-scale soft X-ray detection elements are developed, it is included GaAs irradiated with neutron, GaAs irradiated with proton, multi-layer mirror, plane mirror and small scale X-ray diode et al. Soft X-ray spectrometers built of multi-layer mirror-GaAs (with neutron irradiation), and plane mirror-small-scale XRD, and plane mirror-GaAs (with proton irradiation) are prepared. These spectrometers are examined in Shen Guang-II laser facility, and some external estimation are given. (authors)

Application of gas chromatography-surface ionization organic mass spectrometry to forensic toxicology.

Science.gov (United States)

Ishii, Akira; Watanabe-Suzuki, Kanako; Seno, Hiroshi; Suzuki, Osamu; Katsumata, Yoshinao

2002-08-25

Surface ionization (SI), which consists in the formation of positive and negative ions along the course of thermal desorption of particles from a solid surface, was first applied as a detector for gas chromatography (GC), GC-surface ionization detection (SID); we developed many new sensitive methods for the determination of abused and other drugs by GC-SID. Recently, Fujii has devised a combination of SI and a quadrupole mass spectrometer and named this system a surface ionization organic mass spectrometer (SIOMS), which is highly selective and sensitive for organic compounds containing tertiary amino groups. We have tried to apply this mass spectrometer to forensic toxicological study; so far we have succeeded in determining important drugs-of-abuse and toxic compounds, such as phencyclidine (PCP), pethidine, pentazocine, MPTP and its derivatives from human body fluids with high sensitivity and selectivity. In this review, we describe our recent studies on the application of GC-SIOMS to forensic toxicology. Copyright 2002 Elsevier Science B.V.

Molecular beam mass spectrometer equipped with a catalytic wall reactor for in situ studies in high temperature catalysis research

International Nuclear Information System (INIS)

Horn, R.; Ihmann, K.; Ihmann, J.; Jentoft, F.C.; Geske, M.; Taha, A.; Pelzer, K.; Schloegl, R.

2006-01-01

A newly developed apparatus combining a molecular beam mass spectrometer and a catalytic wall reactor is described. The setup has been developed for in situ studies of high temperature catalytic reactions (>1000 deg. C), which involve besides surface reactions also gas phase reactions in their mechanism. The goal is to identify gas phase radicals by threshold ionization. A tubular reactor, made from the catalytic material, is positioned in a vacuum chamber. Expansion of the gas through a 100 μm sampling orifice in the reactor wall into differentially pumped nozzle, skimmer, and collimator chambers leads to the formation of a molecular beam. A quadrupole mass spectrometer with electron impact ion source designed for molecular beam inlet and threshold ionization measurements is used as the analyzer. The sampling time from nozzle to detector is estimated to be less than 10 ms. A detection time resolution of up to 20 ms can be reached. The temperature of the reactor is measured by pyrometry. Besides a detailed description of the setup components and the physical background of the method, this article presents measurements showing the performance of the apparatus. After deriving the shape and width of the energy spread of the ionizing electrons from measurements on N 2 and He we estimated the detection limit in threshold ionization measurements using binary mixtures of CO in N 2 to be in the range of several hundreds of ppm. Mass spectra and threshold ionization measurements recorded during catalytic partial oxidation of methane at 1250 deg. C on a Pt catalyst are presented. The detection of CH 3 · radicals is successfully demonstrated

Molecular beam mass spectrometer equipped with a catalytic wall reactor for in situ studies in high temperature catalysis research

Science.gov (United States)

Horn, R.; Ihmann, K.; Ihmann, J.; Jentoft, F. C.; Geske, M.; Taha, A.; Pelzer, K.; Schlögl, R.

2006-05-01

A newly developed apparatus combining a molecular beam mass spectrometer and a catalytic wall reactor is described. The setup has been developed for in situ studies of high temperature catalytic reactions (>1000°C), which involve besides surface reactions also gas phase reactions in their mechanism. The goal is to identify gas phase radicals by threshold ionization. A tubular reactor, made from the catalytic material, is positioned in a vacuum chamber. Expansion of the gas through a 100μm sampling orifice in the reactor wall into differentially pumped nozzle, skimmer, and collimator chambers leads to the formation of a molecular beam. A quadrupole mass spectrometer with electron impact ion source designed for molecular beam inlet and threshold ionization measurements is used as the analyzer. The sampling time from nozzle to detector is estimated to be less than 10ms. A detection time resolution of up to 20ms can be reached. The temperature of the reactor is measured by pyrometry. Besides a detailed description of the setup components and the physical background of the method, this article presents measurements showing the performance of the apparatus. After deriving the shape and width of the energy spread of the ionizing electrons from measurements on N2 and He we estimated the detection limit in threshold ionization measurements using binary mixtures of CO in N2 to be in the range of several hundreds of ppm. Mass spectra and threshold ionization measurements recorded during catalytic partial oxidation of methane at 1250°C on a Pt catalyst are presented. The detection of CH3• radicals is successfully demonstrated.

Compact high-speed MWIR spectrometer applied to monitor CO2 exhaust dynamics from a turbojet engine

Science.gov (United States)

Linares-Herrero, R.; Vergara, G.; Gutiérrez Álvarez, R.; Fernández Montojo, C.; Gómez, L. J.; Villamayor, V.; Baldasano Ramírez, A.; Montojo, M. T.; Archilla, V.; Jiménez, A.; Mercader, D.; González, A.; Entero, A.

2013-05-01

Dfgfdg Due to international environmental regulations, aircraft turbojet manufacturers are required to analyze the gases exhausted during engine operation (CO, CO2, NOx, particles, unburned hydrocarbons (aka UHC), among others).Standard procedures, which involve sampling the gases from the exhaust plume and the analysis of the emissions, are usually complex and expensive, making a real need for techniques that allow a more frequent and reliable emissions measurements, and a desire to move from the traditional gas sampling-based methods to real time and non-intrusive gas exhaust analysis, usually spectroscopic. It is expected that the development of more precise and faster optical methods will provide better solutions in terms of performance/cost ratio. In this work the analysis of high-speed infrared emission spectroscopy measurements of plume exhaust are presented. The data was collected during the test trials of commercial engines carried out at Turbojet Testing Center-INTA. The results demonstrate the reliability of the technique for studying and monitoring the dynamics of the exhausted CO2 by the observation of the infrared emission of hot gases. A compact (no moving parts), high-speed, uncooled MWIR spectrometer was used for the data collection. This device is capable to register more than 5000 spectra per second in the infrared band ranging between 3.0 and 4.6 microns. Each spectrum is comprised by 128 spectral subbands with aband width of 60 nm. The spectrometer operated in a passive stand-off mode and the results from the measurements provided information of both the dynamics and the concentration of the CO2 during engine operation.

Performance of the Linear Ion Trap Mass Spectrometer for the Mars Organic Molecule Analyzer (MOMA) Investigation on the 2018 Exomars Rover

Science.gov (United States)

Arevalo, Ricardo, Jr.; Brinckerhoff, William B.; Pinnick, Veronica T.; van Amerom, Friso H. W.; Danell, Ryan M.; Li, Xiang; Getty, Stephanie; Hovmand, Lars; Atanassova, Martina; Mahaffy, Paul R.;

Two-arm electron/photon/hadron spectrometer TALES collaboration

International Nuclear Information System (INIS)

Hayano, R.S.; Sakurai, H.; Shigaki, K.

1990-12-01

To discover and probe the existence of a quark gluon plasma, it would seem desirable to have a detector which is sensitive to as many of the proposed 'signatures' as possible, so that they could all be observed and turned on and off in a predictable, reproducible, controllable and unified way. By emphasizing an open geometry experiment, optimized for detecting low-mass, low P T electron-positron pairs, a reasonably comprehensive measurement of the majority of the quark gluon plasma signatures must be obtained. Thus, the report first addresses physics motivation and goals, focusing on dielectron production; π 0 , η and direct photon measurements; global event characterization; identified hadron P T spectra; and charm production. An overview of the proposed central detector is then presented. Next, major detector components and expected performance are discussed, focusing on tracking, electron-pair reconstruction (a gas ring-imaging Cerenkov RICH counter), Dalitz-decay rejection, a highly-segmented electromagnetic calorimeter, global event characterization, an optical forward spectrometer, and a summary of performance. Finally, the report describes major research and development items and estimated costs. (N.K.)

Development of cold neutron spectrometers

International Nuclear Information System (INIS)

Lee, Changhee; Lee, C. H.; So, J. Y.; Park, S.; Han, Y. S.; Cho, S. J.; Moon, M. K.; Choi, Y. H.; Sun, G. M.

2012-03-01

□ Cold Neutron Triple Axsis Spectrometer (Cold-TAS) Development Ο Fabrication and Installation of the Major Cold-TAS Components Ο Performance Test of the Cold-TAS □ Cold Neutron Time-of-Flight Spectrometer(DC-TOF) Development Ο Fabrication of the Major DC-TOF Components Ο Development DC-TOF Data Reduction Software □ Expected Contribution The two world-class inelastic neutron scattering instruments measure atomic or molecular scale dynamics of meV energy range. This unprecedented measurement capability in the country will enable domestic and international scientists to observe new phenomena in their materials research to obtain world class results. Especially those who work in the fields of magnetic properties of superconductors and multiferroics, molecular dynamics, etc. will get more benefit from these two instruments

The Harwell back-scattering spectrometer

International Nuclear Information System (INIS)

Windsor, C.G.; Bunce, L.J.; Borcherds, P.H.; Cole, I.; Fitzmaurice, M.; Johnson, D.A.G.; Sinclair, R.N.

1976-01-01

Neutron diffraction spectra in which both high resolution (Δ Q/Q approximately equal to 0.003) and high intensity are maintained up to scattering vectors as high as 30A -1 (sin theta/lambda = 2.5) have been obtained with the back-scattering spectrometer (BSS) recently installed on the Harwell electron linac. The theory behind the spectrometer design is described, and it is shown how the above resolution requirement leads to its basic features of a 12m incident flight path, a 2m scattering flight path and a scattering angle (2theta) acceptance from 165 0 to 175 0 . Examples of the resolution, intensity and background are given. It is shown that the problem of frame overlap may be overcome by using an absorbing filter. (author)

The universal sound velocity formula for the strongly interacting unitary Fermi gas

International Nuclear Information System (INIS)

Liu Ke; Chen Ji-Sheng

2011-01-01

Due to the scale invariance, the thermodynamic laws of strongly interacting limit unitary Fermi gas can be similar to those of non-interacting ideal gas. For example, the virial theorem between pressure and energy density of the ideal gas P = 2E/3V is still satisfied by the unitary Fermi gas. This paper analyses the sound velocity of unitary Fermi gases with the quasi-linear approximation. For comparison, the sound velocities for the ideal Boltzmann, Bose and Fermi gas are also given. Quite interestingly, the sound velocity formula for the ideal non-interacting gas is found to be satisfied by the unitary Fermi gas in different temperature regions. (general)

GEANT Monte Carlo simulations for the GREAT spectrometer

International Nuclear Information System (INIS)

Andreyev, A.N.; Butler, P.A.; Page, R.D.; Appelbe, D.E.; Jones, G.D.; Joss, D.T.; Herzberg, R.-D.; Regan, P.H.; Simpson, J.; Wadsworth, R.

2004-01-01

GEANT Monte Carlo simulations for the recently developed GREAT spectrometer are presented. Some novel applications of the spectrometer for γ-ray, conversion-electron and β-decay spectroscopy are discussed. The conversion-electron spectroscopy of heavy nuclei with strongly converted transitions and the extension of the recoil decay tagging method to β-decaying nuclei are considered in detail

Theoretical resolving power of a radiofrequency mass spectrometer

International Nuclear Information System (INIS)

Coc, A.; Le Gac, R.; Saint Simon, M. de; Thibault, C.; Touchard, F.

1988-01-01

Radiofrequency mass spectrometers of L.G. Smith's type can reach a resolving power of 10 6 -10 7 and a precision of 10 -9 -10 -10 . The resolving power, shape of peaks and limitations are described. As an example, the spectrometer to be used in an experiment aimed at measuring the anti p/p mass ratio is considered. (orig.)

The computer simulation of 3d gas dynamics in a gas centrifuge

Science.gov (United States)

Borman, V. D.; Bogovalov, S. V.; Borisevich, V. D.; Tronin, I. V.; Tronin, V. N.

2016-09-01

We argue on the basis of the results of 2D analysis of the gas flow in gas centrifuges that a reliable calculation of the circulation of the gas and gas content in the gas centrifuge is possible only in frameworks of 3D numerical simulation of gas dynamics in the gas centrifuge (hereafter GC). The group from National research nuclear university, MEPhI, has created a computer code for 3D simulation of the gas flow in GC. The results of the computer simulations of the gas flows in GC are presented. A model Iguassu centrifuge is explored for the simulations. A nonaxisymmetric gas flow is produced due to interaction of the hypersonic rotating flow with the scoops for extraction of the product and waste flows from the GC. The scoops produce shock waves penetrating into a working camera of the GC and form spiral waves there.

The computer simulation of 3d gas dynamics in a gas centrifuge

International Nuclear Information System (INIS)

Borman, V D; Bogovalov, S V; Borisevich, V D; Tronin, I V; Tronin, V N

2016-01-01

We argue on the basis of the results of 2D analysis of the gas flow in gas centrifuges that a reliable calculation of the circulation of the gas and gas content in the gas centrifuge is possible only in frameworks of 3D numerical simulation of gas dynamics in the gas centrifuge (hereafter GC). The group from National research nuclear university, MEPhI, has created a computer code for 3D simulation of the gas flow in GC. The results of the computer simulations of the gas flows in GC are presented. A model Iguassu centrifuge is explored for the simulations. A nonaxisymmetric gas flow is produced due to interaction of the hypersonic rotating flow with the scoops for extraction of the product and waste flows from the GC. The scoops produce shock waves penetrating into a working camera of the GC and form spiral waves there. (paper)

Measurement and analysis of leakage neutron energy spectra around the Kinki University Reactor, UTR-KINKI

CERN Document Server

Ogawa, Y; Sagawa, H; Tsujimoto, T

2002-01-01

The highly sensitive cylindrical multi-moderator type neutron spectrometer was constructed for measurement of low level environmental neutrons. This neutron spectrometer was applied for the determination of leakage neutron energy spectra around the Kinki University Reactor. The analysis of the leakage neutron energy spectra was performed by MCNP Monte Carlo code. From the obtained results, the agreement between the MCNP predictions and the experimentally determined values is fairly good, which indicates the MCNP model is correctly simulating the UTR-KINKI.

Noise considerations in millimeter-wave spectrometers

International Nuclear Information System (INIS)

Zoellner, W.D.; Kolbe, W.F.; Leskovar, B.

1978-12-01

An improved version of a microwave spectrometer operating in the vicinity of 70 GHz is described. The spectrometer, which incorporates a Fabry-Perot resonator and superheterodyne detection for high sensitivity is designed for the detection of gaseous pollutants and other atmospheric constituents. The instrument is capable of detecting polar molecules with absorption coefficients as small as 2 x 10 -9 cm -1 . For sulphur dioxide diluted in air, this sensitivity corresponds to a detection limit of 1.2 ppm without preconcentration and with a time constant of 1 second. Measurements and analysis of the noise contributions limiting the sentivity are presented

Streaked, x-ray-transmission-grating spectrometer

International Nuclear Information System (INIS)

Ceglio, N.M.; Roth, M.; Hawryluk, A.M.

1981-08-01

A free standing x-ray transmission grating has been coupled with a soft x-ray streak camera to produce a time resolved x-ray spectrometer. The instrument has a temporal resolution of approx. 20 psec, is capable of covering a broad spectral range, 2 to 120 A, has high sensitivity, and is simple to use requiring no complex alignment procedure. In recent laser fusion experiments the spectrometer successfully recorded time resolved spectra over the range 10 to 120 A with a spectral resolving power, lambda/Δlambda of 4 to 50, limited primarily by source size and collimation effects

Highly effective portable beta spectrometer for precise depth selective electron Moessbauer spectroscopy

International Nuclear Information System (INIS)

Aldiyarov, N.U.; Kadyrzhanov, K.K.; Seytimbetov, A.M.; Zhdanov, V.S.

2007-01-01

Full text: More broad application of the nuclear-physical method of precise Depth Selective Electron Moessbauer Spectroscopy (DS EMS) is limited by insufficient accessibility of highly-effective beta spectrometers with acceptable resolution. It should be mentioned that the method DS EMS is realized at a combined installation that consists of a highly-effective beta spectrometer and a conventional portable nuclear gamma-resonance spectrometer. Yet few available beta spectrometers have sophisticated design and controlling; in most cases they are cumbersome. All the attempts to simplify beta spectrometers resulted in noticeable worsening of depth resolution for the DS EMS method making the measurements non precise. There is currently an obvious need in a highly-effective portable easily controlled beta spectrometer. While developing such portable beta spectrometer, it is more promising to use as basis a simpler spectrometer, which has ratio of sample size to spectrometer size of about five times. The paper presents an equal-arm version of a highly-effective portable beta spectrometer with transverse heterogeneous sector magnetic field that assures double focusing. The spectrometer is equipped with a large-area non-equipotential source (a sample under investigation) and a position-sensitive detector. This portable spectrometer meets all requirements for achievement of the DS EMS depth resolution close to the physical limit and demonstrates the following main characteristics: equilibrium orbit radius ρ 0 = 80 mm, instrumental energy resolution 0.6 % at solid angle 1 % of 4π steradian, area of non-equipotential source ∼ 80 mm 2 , registration by position-sensitive detector of ∼ 10 % of the energy interval. Highly-effective portable beta spectrometer assures obtaining Moessbauer data with depth resolution close to physical limit of the DS EMS method. So in measurements at conversion and Auger electrons with energies of about units of keV and above, the achieved

Development of gamma spectrometer using silicon photomultiplier (SiPM)

International Nuclear Information System (INIS)

Kim, Chan Kyu

2011-02-01

Gamma spectroscopy is used to determine the identity and quantity of gamma-emitters in nuclear physics, geochemistry and astrophysics. The scintillation detectors are being used as a gamma spectrometer generally, because of their higher gamma-ray detection efficiency and cheaper price than germanium semi-conductor detectors. A typical scintillation detector is composed of a scintillator, a window, and a photodetector. The photomultiplier (PM) tube has been the most widely used as a photodetector because of its advantages like high sensitivity, high signal-to-noise ratio, and wide dynamic range. Recently, the Silicon Photomultiplier (SiPM) is being studied as a substitute of PM tube. The SiPM has almost same performance compared to PM tube but it has additional advantages; low operating voltage, small volume, and cheap production cost. In this research, the gamma spectrometer using SiPM instead of PM tube is developed. The use of SiPM as a photodetector makes the gamma spectrometer smaller, cheaper, easier to use. For photon transport and collection from the large area scintillator to the small area SiPM, a light guide is applied in this gamma spectrometer system. Before fabrication of light guide, DETECT simulation is performed to study and prospect characteristics of light guide structure. And actual light guides are fabricated on the basis of this simulation result. Poly(methyl methacrylate) (PMMA) is chosen as material of light guide, 5 sample light guides are fabricated in different lengths and coatings. As a scintillator crystal, same NaI(Tl) crystal is chosen. For measurement and analysis of gamma spectrometer system, 3 gamma spectrometer systems are composed: PM tube-based system, PM tube-based system with the light guide, SiPM-based system with the light guide. Through comparison between the results of each gamma spectrometer, the performances of gamma spectrometer system are analyzed by each component. Measurement results of the second system is well

Elements of Tiny Plasma Spectrometers

Data.gov (United States)

National Aeronautics and Space Administration — We propose to advance major elements of a miniaturized plasma spectrometer for flight on future missions. This type of instrument has been developed and successfully...

The Lise spectrometer at Ganil

International Nuclear Information System (INIS)

Saint-Laurent, M.G.

1986-08-01

The doubly achromatic spectrometer LISE is available at the french national heavy ion accelerator GANIL. Experimental results, obtained in radioactive beam production and search for new exotic nuclei are briefly reported