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Sample records for unit lubrication oil

  1. Natural oils as lubricants

    Science.gov (United States)

    There is currently an availability of vegetable oil lubricants, with the exception of engine oils. Vegetable oils are environmentally friendly, renewable, contribute to the reduction of our dependence on imported petroleum, and add value to the farmer. However, there are inherent weaknesses in veg...

  2. Lubricating oil; Junkatsuyu

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, H.

    1999-07-20

    As a reflection of business recession, sales amount of lubricating oils in 1998 in Japan was 2.334 million kl that is 96.1% of that in the previous year. In addition, export amount was 394 thousand kl that also decreased sharply to 81.9% of that in the previous year. In this situation, researches and developments of environment-adaptable lubricating oils such as fuel consumption-saving engine oils, new mechanism-corresponding drive system oils (AFT, CVT), refrigerating machine oils for substitute coolants, biodegradable oils and greases, environment corresponding processing oils (non-chlorine type cutting oils), and so on have been executed actively. In respect to lubricating oils for vehicles, numerous researches and developments of engine oils are executed while putting stress on the improvement of fuel consumption saving for reducing CO{sub 2} exhaust; improvement of adaptability to exhaust treating apparatus for purging harmful components from exhaust gas; and environmental corresponding of long drain for reducing waste oils. In respect to lubricating oils for industry, basic characteristics and utility characteristics of fire-resistant working fluids and biodegradable working fluids; and utility characteristics of new functional fluids and electric viscous fluids are reported in view of their relationship with environmental protection. (NEDO)

  3. Regeneration of used lubricating oils

    Energy Technology Data Exchange (ETDEWEB)

    Adler, N.; Adler, E.; Cismic, V.; Prohaska, B.; Yabar-Mejia, B.

    1981-01-01

    In Yugoslavia in 1985, it is planned that 150,000 tons/year will be recycled, at a consumption of 317,000 tons/year of lubricating oils. The technology is described for recycling waste oil by the traditional method of sulfuric acid cleaning with precleaning by bleaching clay and modern waste oil recycling processes, based on using selective solvents and hydraulic cleaning. The technological features are examined of performing individual recycling stages; dehydration, purification by sulfuric acid, propane, and a mixture of propanol-2, methyl ethyl ketone and butanol-1, propanol-2 and butanol-1, hydraulic cleaning, rectification, precleaning by bleaching clay, and addition of additives. It is noted that the unit capacity of old waste oil recycling plants using sulfuric acid and bleaching clay, built in Zaqreb, Modrits and Maribor, does not exceed 10,000 tons/year, while the new plant for deasphalting by propane and hydraulic cleaning built in Belgrad is rated to recycle 25,000 tons/year of oil (the total capacity of the oil recycling plants has reached 55,000 tons/year). A comparison is made of the economic indices of operation of the old and new waste oil recycling plants. Initial data, the technique and results of economic calculations are given. It is established that modern waste oil recycling plants are more profitable than antiquated ones with a low unit capacity. The profitability of the plants will grow with an increase in the capacity and in oil prices.

  4. Detergent Additive for Lubricating Oils,

    Science.gov (United States)

    The Russian patent pertains to a method of producing additives for lubricating oils . A method is known for producing an antiwear additive for... lubricating oils by processing phenols with phosphorus oxychloride, phosphoric acid esters are obtained. In order to give the additive detergent properties

  5. 油气润滑系统供油单元的控制%Control of the Oil Supply Unit of Oil-Air Lubrication System

    Institute of Scientific and Technical Information of China (English)

    刘雨辰; 孙启国; 吕洪波

    2013-01-01

      油气润滑是一种应用气液两相流进行润滑的新兴润滑技术,具有节能、环保、耗油量少、运行成本低、维护简便易行等优点。供油单元是油气润滑系统的重要组成部分,对润滑效果有很大影响。设计了供油单元的控制电路和控制程序并采用Multisim10对温度信号采集电路进行了模拟仿真,实现了供油单元自动检测温度、液位,并能够加热、自动补油和报警等功能,降低了供油单元的制造成本与运行功耗,提高了系统集成度。%Oil-air lubrication is a kind of emerging lubrication technology with advantages , such as energy conservation , envi-ronmental protection and lower oil consumption and operation cost.Oil supply unit has a great effect on the property of the oil-air lubrication and becomes an important composition of the oil-air lubrication system.The circuit and program are designed to control the oil supply unit and the control circuit and parameters of the component are verified by the simulation using Multi-sim10 in this thesis.Automatic monitoring of the temperature and liquid level and the fault alarm are realized in this unit with a lower cost and the energy consumption, and a higher integration.

  6. CYLINDER AND SYSTEM LUBRICATING OILS

    Directory of Open Access Journals (Sweden)

    ION ADRIAN GIRBA

    2016-06-01

    Full Text Available Increased thermal efficiency, savings in the fuel consumption and the possibility to burn low quality fuels conducted to an intense development of marine engines in past 20 years, this progress being emphasized by the increased combustion pressures and better combustion properties. These improvements represent a continuous challenge for lubricating oil manufacturers: the rise in combustion temperatures and pressures is making difficult to preserve the oil film in critical areas and the longer strokes of the piston leads to issues of spreading the oil. Adding here the new type of engines using gas or biofuel which requires different types of lubricating oils. Therefore, the success of new generation of engines will depend on lubricating oils quality. :

  7. Vegetable oil basestocks for lubricants

    Energy Technology Data Exchange (ETDEWEB)

    Garces, R.; Martinez-Force, E.; Salas, J.

    2011-07-01

    The use of vegetable biodegradable basestocks for lubricant oils present several advantages over the much more extended mineral bases. These advantages refer to biodegradability, a renewable feedstock of local production, lubricant and viscosity index and lower costs than synthetic lubricant bases. Despite these benefits, their use in industry and motor vehicles is not yet extensive due their lower stability and higher pour points. Vegetable oils are esters of fatty acids and glycerol, and their physicochemical properties rely mainly on the composition of their acyl moieties. Thus, to assure the maximum levels of stability while maintaining acceptable behavior at low temperatures, monounsaturated fatty acids are preferred for this purpose. The presence of natural antioxidants also improves the properties of these vegetable based stocks as lubricants. These oils usually require additives to improve their viscosity value, oxidative stability and properties at low temperatures. In the present work, the different sources of vegetable oils appropriate for biolubricant production were reviewed. Their properties and the future improvement of the oil bases, oil based stock production, uses and additives are discussed. (Author).

  8. CYLINDER AND SYSTEM LUBRICATING OILS

    OpenAIRE

    ION ADRIAN GIRBA

    2016-01-01

    Increased thermal efficiency, savings in the fuel consumption and the possibility to burn low quality fuels conducted to an intense development of marine engines in past 20 years, this progress being emphasized by the increased combustion pressures and better combustion properties. These improvements represent a continuous challenge for lubricating oil manufacturers: the rise in combustion temperatures and pressures is making difficult to preserve the oil film in critical area...

  9. 41 CFR 101-26.602-1 - Procurement of lubricating oils, greases, and gear lubricants.

    Science.gov (United States)

    2010-07-01

    ... lubricating oils, greases, and gear lubricants. 101-26.602-1 Section 101-26.602-1 Public Contracts and...-26.602-1 Procurement of lubricating oils, greases, and gear lubricants. (a) The Defense Fuel Supply Center will make annual procurements of lubricating oils, greases, and gear lubricants for ground...

  10. Biodegradation and toxicological evaluation of lubricant oils

    Directory of Open Access Journals (Sweden)

    Ivo Shodji Tamada

    2012-12-01

    Full Text Available The aim of this work was to compare different toxicity levels of lubricant oils. The tests were performed using the earthworm (Eisenia andrei, arugula seeds (Eruca sativa and lettuce seeds (Lactuca sativa, with three types of contaminants (mineral lubricant oil, synthetic lubricant oil and used lubricant oil for various biodegradation periods in the soil. The toxicity tests indirectly measured the biodegradation of the contaminants. The samples were analyzed at t0, t60, t120 and t180 days of biodegradation. The used lubricant oil was proved very toxic in all the tests and even after biodegradation its toxicity was high. The mineral and synthetic oils were biodegraded efficiently in the soil although their toxicity did not disappear completely after 180 days.

  11. Potential of vegetable oils for lubricants

    Science.gov (United States)

    Vegetable oils offer significant advantages in terms of resource renewability, biodegradability, and comparable performance properties to petroleum-based products. The petroleum-based lubricants render unfavorable impact on the environment. With the growing environmental concerns, seed oils are find...

  12. Solid Lubricants for Oil-Free Turbomachinery

    Science.gov (United States)

    DellaCorte, Christopher

    2005-01-01

    Recent breakthroughs in gas foil bearing solid lubricants and computer based modeling has enabled the development of revolulionary Oil-Free turbomachinery systems. These innovative new and solid lubricants at low speeds (start-up and shut down). Foil bearings are hydrodynamic, self acting fluid film bearings made from thin, flexible sheet metal foils. These thin foils trap a hydrodynamic lubricating air film between their surfaces and moving shaft surface. For low temperature applications, like ainrafl air cycle machines (ACM's), polymer coatings provide important solid lubrication during start-up and shut down prior to the development of the lubricating fluid film. The successful development of Oil-Free gas turbine engines requires bearings which can operate at much higher temperatures (greater than 300 C). To address this extreme solid lubrication need, NASA has invented a new family of compostie solid lubricant coatings, NASA PS300.

  13. Lubrication from mixture of boric acid with oils and greases

    Science.gov (United States)

    Erdemir, Ali

    1995-01-01

    Lubricating compositions including crystalline boric acid and a base lubricant selected from oils, greases and the like. The lubricity of conventional oils and greases can also be improved by adding concentrates of boric acid.

  14. Vegetable oil basestocks for lubricants

    Directory of Open Access Journals (Sweden)

    Garcés, Rafael

    2011-03-01

    Full Text Available The use of vegetable biodegradable basestocks for lubricant oils present several advantages over the much more extended mineral bases. These advantages refer to biodegradability, a renewable feedstock of local production, lubricant and viscosity index and lower costs than synthetic lubricant bases. Despite these benefits, their use in industry and motor vehicles is not yet extensive due their lower stability and higher pour points. Vegetable oils are esters of fatty acids and glycerol, and their physicochemical properties rely mainly on the composition of their acyl moieties. Thus, to assure the maximum levels of stability while maintaining acceptable behavior at low temperatures, monounsaturated fatty acids are preferred for this purpose. The presence of natural antioxidants also improves the properties of these vegetable based stocks as lubricants. These oils usually require additives to improve their viscosity value, oxidative stability and properties at low temperatures. In the present work, the different sources of vegetable oils appropriate for biolubricant production were reviewed. Their properties and the future improvement of the oil bases, oil based stock production, uses and additives are discussed.

    El uso de bases vegetales biodegradables para aceites lubricantes presenta varias ventajas sobre las mucho más extendidas bases minerales. Estas ventajas se centran sobre todo en su biodegradabilidad, en ser un recurso renovable de producción local, en su lubricidad y en su índice de viscosidad, presentando además costes más bajos que las bases sintéticas. Sin embargo, estas ventajas no han extendido el uso de bases vegetales ni en industria ni en automoción debido a su menor estabilidad y sus mayores puntos críticos de fluidez. Los aceites vegetales son ésteres de ácidos grasos y glicerol y sus propiedades físico-químicas dependen principalmente de su composición acílica. Así, para asegurar los máximos niveles de

  15. PRODUCTION OF HIGH QUALITY LUBRICATING BASE OIL

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    @@High VI lubricating oil is produced in hydrocracker through hydrocracking (HDC) and hydroisome-rization reactions. In order to effectively produce high VI component, such as iso-pafaffins and monocyclic naphtenes, it is important to load suitable HDC catalysts and operate them in the appropriate reaction conditions.   Nippon Mitsubishi Oil Corporation (NMOC) and its affiliate company, Nippon Mitsubishi Petroleum Refining Company (NMPRC) reported their original HDC catalysts four years ago in this Japan-China joint se-minar in Beijing[1]. NMOC and NMPRC operate their hydrocracker both in fuel oil production mode and in lubricating oil production mode. In lubricating oil production mode, high VI lubricating oil called VHDC are produced.   In this paper, at first, the advantages of high VI lubricating oil are described. And then it is announced that NMOC and NMPRC have developed a new generation of HDC catalyst with higher cracking activity, higher middle distillate selectivity and longer life than the other commercial HDC catalysts. In addition to those properties, the catalyst is able to yield high VI lubricating oil as well.

  16. Relationship between Supplied Oil Flow Rates and Oil Film Thicknesses under Starved Elastohydrodynamic Lubrication

    Directory of Open Access Journals (Sweden)

    Taisuke Maruyama

    2015-04-01

    Full Text Available Many studies have already considered starved lubrication. However, there have been no reports on the oil film thicknesses under steady starved EHL (elastohydrodynamic lubrication, where the ultra-low volume of oil supplied per unit time is uniform. The present study examined the relationship between the supplied oil flow rate and oil film thickness under steady starved lubrication. A ball-on-disk testing machine was used in experiments to measure the oil film thickness by means of optical interferometry. A microsyringe pump was used to accurately control the supplied oil flow rate. The supplied oil flow rate was kept constant, and the minimum oil film thickness was measured for 1 h after the start of the tests to determine the relationship between the supplied oil flow rate and oil film thickness.

  17. A Multipurpose Additive for Lubricating Oils,

    Science.gov (United States)

    The report describes the synthesis and properties of S-(3,5-di-tert-butyl-4-hydroxybenzyl)-O-O-(alkyl or aryl) phosphorodithioate. This compound was synthesized as wear inhibitor and antioxidant for lubricating oils .

  18. Engine Auxiliary System Guideline: Lubricating Oil Systems

    OpenAIRE

    Linna, Joni

    2015-01-01

    This thesis was done for Wärtsilä Technical Services organization, the purpose of this work was to gather and structure information about the lubricating oil systems from the company’s internal databases, interviews with system specialists and from different literature sources covering Ship Power and Power Plant products. The outcome was a guideline, covering typical power plant and marine system descriptions, all components used in the lubricating oil system with their functional description...

  19. Vegetable oil base stocks for lubricants

    Energy Technology Data Exchange (ETDEWEB)

    Garces, R.; Martinez-Force, E.; Salas, J.

    2011-07-01

    The use of vegetable biodegradable base stocks for lubricant oils present several advantages over the much more extended mineral bases. These advantages refer to biodegradability, a renewable feedstock of local production, lubricant and viscosity index and lower costs than synthetic lubricant bases. Despite these benefits, their use in industry and motor vehicles is not yet extensive due their lower stability and higher pour points. Vegetable oils are esters of fatty acids and glycerol, and their physicochemical properties rely mainly on the composition of their acyl moieties. Thus, to assure the maximum levels of stability while maintaining acceptable behavior at low temperatures, monounsaturated fatty acids are preferred for this purpose. The presence of natural antioxidants also improves the properties of these vegetable based stocks as lubricants. These oils usually require additives to improve their viscosity value, oxidative stability and properties at low temperatures. In the present work, the different sources of vegetable oils appropriate for bio lubricant production were reviewed. Their properties and the future improvement of the oil bases, oil based stock production, uses and additives are discussed. (Author).

  20. New crop oils - Properties as potential lubricants

    Science.gov (United States)

    New crops oils such as lesquerella, field pennycress, meadowfoam and cuphea were investigated and compared to common commodity vegetable oils for their fatty acid profiles, low temperature and lubricating properties. The fatty acid profile investigation showed that lesquerella is high in hydroxy fat...

  1. Study on Lubricating Oil Monitoring Technology

    Institute of Scientific and Technical Information of China (English)

    LIU Feng-bi

    2006-01-01

    Lubricating oil monitoring has been proven to be an effective method for detecting and diagnosing machinery failures and essential for realizing condition based maintenance. In this paper, mathematical statistics methods for determining the oil parameters featuring machinery failures and the parameters' probability distribution functions and their thresholds are put forward.

  2. Gravimetric Determination of Sediment in Turbine Engine Lubricating Oils.

    Science.gov (United States)

    noncombustible sediment present in aircraft turbine engine lubricating oils . Both MIL-L-7808 and MIL-L-23699 lubricants were investigated. These...temperature. When these oils were heated to 140 F, they easily passed through a silver membrane filter. A test procedure for the gravimetric measurement of particulate contamination in turbine engine lubricating oils is proposed. (Author)

  3. Carbon-based tribofilms from lubricating oils

    Energy Technology Data Exchange (ETDEWEB)

    Erdemir, Ali; Ramirez, Giovanni; Eryilmaz, Osman L.; Narayanan, Badri; Liao, Yifeng; Kamath, Ganesh; Sankaranarayanan, Subramanian K. R. S.

    2016-08-03

    Moving mechanical interfaces are commonly lubricated and separated by a combination of fluid films and solid 'tribofilms', which together ensure easy slippage and long wear life(1). The efficacy of the fluid film is governed by the viscosity of the base oil in the lubricant; the efficacy of the solid tribofilm, which is produced as a result of sliding contact between moving parts, relies upon the effectiveness of the lubricant's anti-wear additive (typically zinc dialkyldithiophosphate)(2). Minimizing friction and wear continues to be a challenge, and recent efforts have focused on enhancing the anti-friction and anti-wear properties of lubricants by incorporating inorganic nanoparticles and ionic liquids(3,4). Here, we describe the in operando formation of carbon-based tribofilms via dissociative extraction from base-oil molecules on catalytically active, sliding nanometre-scale crystalline surfaces, enabling base oils to provide not only the fluid but also the solid tribofilm. We study nanocrystalline catalytic coatings composed of nitrides of either molybdenum or vanadium, containing either copper or nickel catalysts, respectively. Structurally, the resulting tribofilms are similar to diamond-like carbon(5). Ball-on-disk tests at contact pressures of 1.3 gigapascals reveal that these tribofilms nearly eliminate wear, and provide lower friction than tribofilms formed with zinc dialkyldithiophosphate. Reactive and ab initio molecular-dynamics simulations show that the catalytic action of the coatings facilitates dehydrogenation of linear olefins in the lubricating oil and random scission of their carbon-carbon backbones; the products recombine to nucleate and grow a compact, amorphous lubricating tribofilm.

  4. Reduced Need of Lubricity Additives in Soybean Oil Blends Under Boundary Lubrication Conditions

    Science.gov (United States)

    Converging prices of vegetable oils and petroleum, along with increased focus on renewable resources, gave more momentum to vegetable oil lubricants. Boundary lubrication properties of four Extreme Pressure (EP) additive blends in conventional Soy Bean Oil (SBO) and Paraffinic Mineral Oil (PMO) of ...

  5. Surface roughness effects with solid lubricants dispersed in mineral oils

    Science.gov (United States)

    Cusano, C.; Goglia, P. R.; Sliney, H. E.

    1983-01-01

    The lubricating effectiveness of solid-lubricant dispersions are investigated in both point and line contacts using surfaces with both random and directional roughness characteristics. Friction and wear data obtained at relatively low speeds and at room temperature, indicate that the existence of solid lubricants such as graphite, MoS2, and PTFE in a plain mineral oil generally will not improve the effectiveness of the oil as a lubricant for such surfaces. Under boundary lubrication conditions, the friction force, as a function of time, initially depends upon the directional roughness properties of the contacting surfaces irrespective of whether the base oil or dispersions are used as lubricants.

  6. Carbon-based tribofilms from lubricating oils

    Science.gov (United States)

    Erdemir, Ali; Ramirez, Giovanni; Eryilmaz, Osman L.; Narayanan, Badri; Liao, Yifeng; Kamath, Ganesh; Sankaranarayanan, Subramanian K. R. S.

    2016-08-01

    Moving mechanical interfaces are commonly lubricated and separated by a combination of fluid films and solid ‘tribofilms’, which together ensure easy slippage and long wear life. The efficacy of the fluid film is governed by the viscosity of the base oil in the lubricant; the efficacy of the solid tribofilm, which is produced as a result of sliding contact between moving parts, relies upon the effectiveness of the lubricant’s anti-wear additive (typically zinc dialkyldithiophosphate). Minimizing friction and wear continues to be a challenge, and recent efforts have focused on enhancing the anti-friction and anti-wear properties of lubricants by incorporating inorganic nanoparticles and ionic liquids. Here, we describe the in operando formation of carbon-based tribofilms via dissociative extraction from base-oil molecules on catalytically active, sliding nanometre-scale crystalline surfaces, enabling base oils to provide not only the fluid but also the solid tribofilm. We study nanocrystalline catalytic coatings composed of nitrides of either molybdenum or vanadium, containing either copper or nickel catalysts, respectively. Structurally, the resulting tribofilms are similar to diamond-like carbon. Ball-on-disk tests at contact pressures of 1.3 gigapascals reveal that these tribofilms nearly eliminate wear, and provide lower friction than tribofilms formed with zinc dialkyldithiophosphate. Reactive and ab initio molecular-dynamics simulations show that the catalytic action of the coatings facilitates dehydrogenation of linear olefins in the lubricating oil and random scission of their carbon-carbon backbones; the products recombine to nucleate and grow a compact, amorphous lubricating tribofilm.

  7. Lubricant additive concentrate containing isomerized jojoba oil

    Energy Technology Data Exchange (ETDEWEB)

    Arndt, G.

    1987-05-12

    This patent describes a crankcase motor oil additive concentrate intended to be added to a conventional crankcase motor oil to improve its ability to lubricate and protect the engine. The additive concentrate comprises the following components: A petroleum base stock of lubricating quality and viscosity. The base stock comprises from about 13.5 to 90 weight percent of the additive concentrate; a detergent-inhibitor package. The package is present at from about 7 to about 40 weight percent of the concentrate; a supplemental antiwear additive selected from the salts of dialkyl dithiophosporic acids. The additive is present at a level of from about 1 to about 10 weight percent of the concentrate; and a supplemental antiwear additive selected from the class of sulfurized olefins. The additive is present at a level of from about 1 to about 10 weight percent of the concentrate.

  8. Characterization of used lubricating oil by spectrometric techniques

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Andressa Moreira de, E-mail: andressa@ctaa.embrapa.br [Embrapa Agroindustria de Alimentos, Guaratiba, Rio de Janeiro, RJ (Brazil); Correa, Sergio Machado [Faculdade de Engenharia. Universidade do Estado do Rio de Janeiro (UERJ), Resende, RJ (Brazil); Silva, Glauco Correa da [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2011-07-01

    Full text: The engine lubricating oil drags all kinds of impurities generated by wear of internal components. Thus, it is necessary to monitor the physical and chemical properties and concentration of metals in lubricants used to determine the appropriate time to replace them. Moreover, one can monitor the wear of the engines through the levels of metals in oils. To achieve these goals, some detection techniques such as Flame atomic absorption spectrometry (FAAS), Inductively coupled plasma optical emission spectrometry (ICP-OES) and X-ray fluorescence (XRF), have been widely used to determine metals in lubricating oils and also in other oil derivatives. Thus, some of these techniques were used in this study. Also the technique used was Gas chromatography mass spectrometry (GC / MS) for characterization of chromatographic profile of the engine lubricating oil after use. Through the technique of ICP-OES for method of United States Environmental Protection Agency (USEPA) METHOD 6010B - Inductively coupled plasma optical emission spectrometry was performed to characterize metals in lubricating oil motor, using equipment from ICP-OES Perkin-Elmer{sup R} OPTIMA 3000 ICP-Winlab and software, obtaining the following identification of metals: barium (Ba), calcium (Ca), lead (Pb), copper (Cu), Chromium (Cr), iron (Fe), magnesium (Mg), molybdenum (Mo) and zinc (Zn). Using the XRF technique, through the equipment EDFRX Shimadzu{sup R} model 800HS EDX, Rh tube, applied voltage of 50kV, amperage 100{mu}A, detector Si (Li) cooled with liquid nitrogen and collimator 10mm, we analyzed all the components comprised in the range of Ti to U and Na to SC, identified the following metals: calcium (Ca), zinc (Zn), iron (Fe), copper (Cu), molybdenum (Mo) and nickel (Ni). The characterization was performed by chromatographic methods: USEPA METHOD 5021A - Volatile organic compounds in various sample matrices using equilibrium headspace analysis, USEPA METHOD 8015B - Nonhalogenated Organics

  9. Toxicological characteristics of refinery streams used to manufacture lubricating oils.

    Science.gov (United States)

    Kane, M L; Ladov, E N; Holdsworth, C E; Weaver, N K

    1984-01-01

    In the past, reports on the tumorigenic potential of lubricating oils in experimental animals have poorly defined the materials under study. In this paper the results of mouse skin painting studies with 46 clearly defined samples of refinery streams associated with lubricating oil processing show that modern conventional solvent refining of distillates removes tumorigenic potential while conventional acid refining may not. Furthermore, dewaxing, hydrofinishing, and clay treatments do not appear to mitigate the tumorigenicity of the lubricant distillates. Lubricant processing has changed over the years and assessments of the carcinogenicity of present-day lubricating materials must be based on knowledge of modern processing.

  10. Low Viscosity Lubricating Oils with Superior Cold Properties,

    Science.gov (United States)

    The invention concerns low viscosity lubricating oils based on polyakylbenzenes. The patent claims the use of low boiling portions of the...distillation residues occurring in the alkylation of benzene with chloroparaffins or olefins of the C10 to C14 chain length, as low viscosity and low congealing lubricating oils or as congealing point lowering mix components.

  11. METHOD OF OBTAINING AN ADDITIVE FOR LUBRICATING OILS,

    Science.gov (United States)

    The method of obtaining an additive to lubricating oils , consisting of treating boron trifluoride with alkylphenol and alkylamine, is known. In this...case, (aminotrifluoralkyl)phenoxyborate is obtained which may be used as an antiwear additive for lubricating oils . The proposed method differs from

  12. Chemical modification of soybean oil for lubricant

    Energy Technology Data Exchange (ETDEWEB)

    Duan Shijie; Mao Zongqiang [Tsinghua Univ., INET, BJ (China)

    2008-07-01

    This paper presents a series of structural modifications of soybean oils for lubricant. The reaction was monitored and products were confirmed by NMR and FTIR. The structural modification is carried out in four stages, (1) synthesis of soybean oil isooctyl ester from soybean oil; (2) synthesis of epoxy-soybean oil isooctyl ester from soybean oil isooctyl ester; (3) synthesis of hydroxylated products from epoxy soybean oil isooctyl ester with fatty acid; (4) esterification of the hydroxylated product with anhydride. Rheological behaviour of the products was measured. Pour points of the products (3) were observed as low as -24 C (lauric acid) and -15 C (isooctanoic acid) respectively. When the hydroxyl groups in the products were esterified with and acid anhydride, the pour points were became higher, which were -21 C (lauric acid) and -6 C (isooctanoic acid) without pour point depressant, and -27 C (lauric acid) and -24 C (isooctanoic acid) with 1% of pour point depressant respectively. The products have suitable viscosity and viscosity index, and the viscosity indices are all above 100. (orig.)

  13. Lubricants from chemically modified vegetable oils.

    Science.gov (United States)

    Campanella, Alejandrina; Rustoy, Eduardo; Baldessari, Alicia; Baltanás, Miguel A

    2010-01-01

    This work reports laboratory results obtained from the production of polyols with branched ether and ester compounds from epoxidized vegetable oils pertaining to annual, temperate climate crops (soybean, sunflower and high-oleic sunflower oils), focusing on their possible use as components of lubricant base stocks. To this end, two different opening reactions of the epoxide ring were studied. The first caused by the attack with glacial acetic acid (exclusively in a single organic phase) and the second using short-chain aliphatic alcohols, methanol and ethanol, in acid media. Both reactions proceed under mild conditions: low synthesis temperature and short reaction times and with conversions above 99%. Spectroscopic (NMR), thermal (DSC) and rheological techniques were used to characterize the oils, their epoxides and polyols, to assess the impact of the nature of the vegetable oil and the chemical modifications introduced, including long-term storage conditions. Several correlations were employed to predict the viscosity of the vegetable oils with temperature, and good agreement with the experimental data was obtained.

  14. Selection of Sinopec Lubricating Oil Producing Bases by Using the AHP Model

    Institute of Scientific and Technical Information of China (English)

    Song Yunchang; Song Zhaozheng; Zheng Chengguo; Jiang Qingzhe; Xu Chunming

    2007-01-01

    The factors affecting the development of Sinopec lubricating oil were analyzed in this paper,and an analytic hierarchy process (AHP) model for selecting lubricating-oil producing bases was developed. By using this model,nine lubricating oil producing companies under Sinopec were comprehensively evaluated. The evaluation result showed that the Maoming Lubricating Oil Company (Guangdong province),Jingmen Lubricating Oil Company (Hubei province) and Changcheng Lube Oil Company (Beijing) are top three choices,and should be developed preferentially for the development of Sinopec producing bases of lubricating oil in the future. The conclusions provide the theoretical basis for selecting lubricating oil producing bases for decision makers.

  15. Lubricants and functional fluids from lesquerella oil

    Science.gov (United States)

    Lesquerella fendleri is an oilseed crop belonging to the Brassicaceae (mustard) family that is native to the desert of the southwestern United States. The interest in this crop is due to the high level of hydroxy fatty acids (HFA) in the oil. The seed contains 33% oil, 23% protein, and 15% gums. The...

  16. Talc as friction reducing additive to lubricating oil

    Science.gov (United States)

    Rudenko, Pavlo; Bandyopadhyay, Amit

    2013-07-01

    Reduction of friction and wear by colloidal suspensions of ceramic powders in lubricating oils is an approach that can allow to formulate environment friendly energy saving lubricants. Commercial talc powder was evaluated as an extreme pressure additive to a lubricating oil under different temperatures and concentrations. The best lubricity was achieved at the temperature of 100 °C and the concentration of 0.15 wt% when dynamic and static friction coefficients were reduced by over 30% in comparison to reference lubricating oil alone. At high temperature, talc forms transfer film on metal surface, which reduce both friction and wear behavior in mating surfaces. However, at room temperature, film formation was not observed. Results are explained using pressure and temperature induced lamellar dehydration mechanism when products of dehydration form oxide transfer films on the friction surface.

  17. Assessment of lubricating oil degradation in small motorcycle engine fueled with gasohol

    OpenAIRE

    Nakorn Tippayawong

    2010-01-01

    Assessment of the degradation of lubricating oil was performed on the lubricants which had been used in a small motorcycle engine fueled with gasohol in comparison with the lubricants from gasoline-run engine. The lubricant properties examined in the assessment were lubricating capacity, viscosity and stability to oxidation. Lubricating capacity was evaluated by accelerated wear test on the Timken tester. Lubricating oils from gasohol-run engine appeared to produce about 10% greater wear than...

  18. Characterization of lubrication oil emissions from aircraft engines.

    Science.gov (United States)

    Yu, Zhenhong; Liscinsky, David S; Winstead, Edward L; True, Bruce S; Timko, Michael T; Bhargava, Anuj; Herndon, Scott C; Miake-Lye, Richard C; Anderson, Bruce E

    2010-12-15

    In this first ever study, particulate matter (PM) emitted from the lubrication system overboard breather vent for two different models of aircraft engines has been systematically characterized. Lubrication oil was confirmed as the predominant component of the emitted particulate matter based upon the characteristic mass spectrum of the pure oil. Total particulate mass and size distributions of the emitted oil are also investigated by several high-sensitivity aerosol characterization instruments. The emission index (EI) of lubrication oil at engine idle is in the range of 2-12 mg kg(-1) and increases with engine power. The chemical composition of the oil droplets is essentially independent of engine thrust, suggesting that engine oil does not undergo thermally driven chemical transformations during the ∼4 h test window. Volumetric mean diameter is around 250-350 nm for all engine power conditions with a slight power dependence.

  19. Tribological Properties of Biodegradable Lubricating Oils in Four-Ball Test

    OpenAIRE

    中迫, 正一; 灘野,宏正; 河野,正来; 南, 一郎

    2004-01-01

    To clarify the tribological properties of biodegradable lubricating oils, the four-ball tests were carried out under dip-feed lubrication using a Soda-type four-ball machine. The test balls were lubricated with soybean oil, rapeseed oil, corn oil and turbine oil. From the tests, the coefficient of friction for all the test balls lubricated with biodegradable lubricating oils was lower than that for the test ball lubricated with turbine oil. Further, from the calculation of the pV value, it wa...

  20. Failure Analysis and Regeneration Performances Evaluation on Engine Lubricating Oil

    Science.gov (United States)

    Wang, X. L.; Zhang, G. N.; Zhang, J. Y.; Yin, Y. L.; Xu, Y.

    To investigate the behavior of failure and recycling of lubricating oils, three sorts of typical 10w-40 lubricating oils used in heavy-load vehicle including the new oil, waste oil and regeneration oil regenerated by self-researched green regeneration technology were selected. The tribology properties were tested by four-ball friction wear tester as well. The results indicated that the performance of anti-extreme pressure of regeneration oil increase by 34.1% compared with the waste one and its load- carrying ability is close to the new oil; the feature of wear spot are better than those of the waste oil and frictional coefficient almost reach the level of the new oil's. As a result, the performance of anti-wear and friction reducing are getting better obviously.

  1. Factors affecting the forensic examination of automotive lubricating oils.

    Science.gov (United States)

    Hibbard, Ryan; Goodpaster, John V; Evans, Michelle R

    2011-05-01

    Lubricating oil comparisons impact a variety of forensic investigations, including cases where oil was transferred from a suspect vehicle to the crime scene or victim. In this study, high-temperature gas chromatography/mass spectrometry was used to examine the influence of oil mixtures and oil changes over time on the comparison of known and questioned lubricating oils. Varying concentrations of oil mixtures were prepared and showed the potential for identifying individual components. Motor oils from 18 automobiles monitored over a 2-month period did not demonstrate significant changes in the chromatographic data. Chemometric analysis of motor oil mass spectral data provided little information regarding differentiation of, or changes in, the samples. Power steering fluid (PSF) from a naturally occurring leak collected from several locations was consistent with the PSF in the automobile's reservoir, and the PSF composition did not change over time.

  2. Rise of Air Bubbles in Aircraft Lubricating Oils

    Science.gov (United States)

    Robinson, J. V.

    1950-01-01

    Lubricating and antifoaming additives in aircraft lubricating oils may impede the escape of small bubbles from the oil by forming shells of liquid with a quasi-solid or gel structure around the bubbles. The rates of rise of small air bubbles, up to 2 millimeters in diameter, were measured at room temperature in an undoped oil, in the same oil containing foam inhibitors, and in an oil containing lubricating additives. The apparent diameter of the air bubbles was measured visually through an ocular micrometer on a traveling telescope. The bubbles in the undoped oil obeyed Stokes' Law, the rate of rise being proportional to the square of the apparent diameter and inversely proportional to the viscosity of the oil. The bubbles in the oils containing lubricating additives or foam inhibitors rose more slowly than the rate predicted by Stokes 1 Law from the apparent diameter, and the rate of rise decreased as the length of path the bubbles traveled increased. A method is derived to calculate the thickness of the liquid shell which would have to move with the bubbles in the doped oils to account for the abnoi'I!l8.lly slow velocity. The maximum thickness of this shell, calculated from the velocities observed, was equal to the bubble radius.

  3. Saving energy using synthetic lubricating oils: A case study

    Institute of Scientific and Technical Information of China (English)

    KristianTφNDER; Terje; N; ■SS■N

    2001-01-01

    IT has been suggested that the use of synthetic oil lubricant may lower the energylosses in large bearings. Such claims are often based on the interpretation of temperature meas-urements in the lubricant and/or bearings of heavily loaded rotating machinery. Lower tempera-tures have been observed in synthetic oils as compared to mineral ones even when the bearingsare operating at the same film thickness. This has been attributed to intrinsic lubricating propertiesof certain synthetic oils.In the present paper temperatures and film thicknesses in large bearings in a hydroelectricpower station were monitored and recorded simultaneously. The results for a synthetic lubricantand a mineral oil were compared. The temperature readings were indeed rather different - that ofthe synthetic oil was several degrees C lower than for the mineral oil. Both had been recom-mended for the actual application, giving virtually identical film shapes and thickness in the twocases.A study of the behaviour of the bearings and the temperature differences, based upon Rey-nolds’ equation and simple heat balance considerations, showed that the lower temperature of thesynthetic lubricant was caused by its higher heat capacity, but gave no indication of the existenceof a special lubricating property.

  4. Biodegradation of Lubricating Oil in Wastewater with Zoogloea sp.

    Institute of Scientific and Technical Information of China (English)

    JIN Liang; WANG Xiao-Juan; GU Zong-Lian; ZHOU De-Zhi; XIE Si-Qin

    2006-01-01

    The purpose of this study was to identify microbial strains that have a strong ability to biodegrade lubricating oil. No.20 lubricating oil was used as the sole carbon source in an isolation medium to screen bacteria from sludge that had been contaminated with crude oil. Through both morphological and biochemical methods, the bacterial strain that had the highest biodegrading capacity was identified as Zoogloea sp. On the basis of these preliminary results, a biological contact oxidation method was employed to further assess the ability of the Zoogloea sp. strain to treat wastewater contaminated by No. 20 lubricating oil using three oxidation cabins and two hydraulic retaining times (HRT). Results showed that the concentration of No. 20 lubricating oil with a 12 h hydraulic retaining time and 16.5 L h-1 inflow rate was reduced by99.3% in 15 d, and with a 6 h hydraulic retaining time and 33 L h-1 inflow rate it decreased by 98.6% in 12 d. The results from this study indicated that Zoogloea sp. had a strong potential to be utilized in biodegradation of lubricating oil.

  5. Enhanced Biodegradability, Lubricity and Corrosiveness of Lubricating Oil by Oleic Acid Diethanolamide Phosphate

    Directory of Open Access Journals (Sweden)

    Fang Jianhua

    2012-09-01

    Full Text Available Impacts of oleic acid diethanolamide phosphate (abbreviated as ODAP as an additive on biodegradability, anti-wear capacity, friction-reducing ability and corrosiveness of an unreadily biodegradable HVI 350 mineral lubricating oil was studied. The biodegradabilities of neat lubricating oil and its formulations with ODAP were evaluated on a biodegradation tester. Furthermore, the anti-wear and friction-reducing abilities and the corrosiveness of neat oil and the formulated oils were determined on a four-ball tribotester and a copper strip corrosion tester, respectively. The results indicated that ODAP markedly enhanced biodegradability as well as anti-wear and friction-reducing abilities of the lubricating oil. On the other hand, excellent color ratings of copper strips for both neat oil and the ODAP-doped oil were obtained in the corrosion tests, demonstrating that the corrosiveness of neat oil and the doped oil was negligible, although the latter seemed to provide slightly better anti-corrosion ability.

  6. Lubricity characteristics of seed oils modified by acylation

    Science.gov (United States)

    Chemically modified seed oils via acylation of epoxidized and polyhydroxylated derivatives were investigated for their potential as candidates for lubrication. The native oil was preliminarily epoxidized and ring-opened in a one-pot reaction using formic acid-H2O2 followed by aqueous HCl treatment t...

  7. Fuels and Petroleum, Oil & Lubricants (POL) Laboratories

    Data.gov (United States)

    Federal Laboratory Consortium — The Fuels and Lubricants Technology Team operates and maintains the Fuels and POL Labs at TARDEC. Lab experts adhere to standardized American Society for Testing and...

  8. Experimental Study of Castor Oil Based Lubricant for Automotive Applications

    Directory of Open Access Journals (Sweden)

    Amit Suhane,

    2014-01-01

    Full Text Available Vegetable oils due to their better natural propertiescan be used as an alternative to reduce the dependency on the conventional lubricants. With the depletion of conventional resources at faster pace, need of hour is to approach the safer alternatives for ensuring the availability of such resources for longer periods with lesser harm to the mankind and sorroundings.This workevaluates the prospects of Castor oil based lubricant for automotive applications in contrast to the available commercial servo gear oil. Experimentation has been performed on four ball tester set up.Material used is carbon steel balls. Refined castor and mahua oils are blended in fixed ratios and subjected to friction and wear tests. Experimentation reveals that castor mahua oil blend possess immense potential in contrast to servo gear oil due to good wear reducing traits apart from environmental benefits.

  9. 30 CFR 75.1104 - Underground storage, lubricating oil and grease.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Underground storage, lubricating oil and grease... COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Fire Protection § 75.1104 Underground storage, lubricating oil and grease. Underground storage places for lubricating oil and grease...

  10. Effect of Tocopherol on Antioxygenic Properties of Green Lubricating Oil

    Institute of Scientific and Technical Information of China (English)

    XIAO Zhixin; SHI Chen; MAO Daheng

    2008-01-01

    Based on the needs of green motor oil, and in order to improve the antioxidation properties of green lubricating oil, the effect of tocopherol antioxidation properties of rapeseed oil was studied. Experiments of high temperature oxidation, antiwear and infra-red spectrum analysis were accomplished, the results show that the rapeseed oil including tocopherol can still keeps steady structure after high temperature oxidation, with a small variety of acid number, whose antioxygenic properties are improved evidently. Meanwhile, both thiocarbamate and vitamin C play an assistant role in tocopherol, which can make rapeseed oil to have better oxidation stability and keep excellent antiwear properties after high temperature oxidation.

  11. Investigation on the Use of Palm Olein as Lubrication Oil

    Directory of Open Access Journals (Sweden)

    U. RATCHEL

    2006-01-01

    Full Text Available The research work is on the possibility of producing lubricating oil from vegetable oil with palm olein as a case study. The sample analysed was obtained from Vandeikya Local Government Area of Benue State. Some of the physical and chemical properties such as viscosity, flash/fire point, pour point and specific gravity were analysed. This sample was bleached to remove the red colour (carotene and gummy materials. The bleached sample was tested to determine the above mentioned properties. Comparison of the crude palm olein and the bleached sample with the conventional lubricants obtained from Elf Plc, Kaduna and Unipetrol Plc, Kaduna was made. Finally, it was discovered that the crude palm olein and the bleached sample exhibit a good base as a lubricant.

  12. Assessment of lubricating oil degradation in small motorcycle engine fueled with gasohol

    Directory of Open Access Journals (Sweden)

    Nakorn Tippayawong

    2010-05-01

    Full Text Available Assessment of the degradation of lubricating oil was performed on the lubricants which had been used in a small motorcycle engine fueled with gasohol in comparison with the lubricants from gasoline-run engine. The lubricant properties examined in the assessment were lubricating capacity, viscosity and stability to oxidation. Lubricating capacity was evaluated by accelerated wear test on the Timken tester. Lubricating oils from gasohol-run engine appeared to produce about 10% greater wear than that made in oils from gasoline-run engine. There was no significant difference between the effect of gasohol and gasoline on the viscosity of the used lubricating oils. Moreover, no oxidation products in any used oil samples could be detected.

  13. Mixed film lubrication with biobased oils

    Science.gov (United States)

    Most tribological processes (e.g. metalworking), occur in the mixed film regime where the boundary and hydrodynamic properties of the oils play critical roles. In the work described here, the boundary and hydrodynamic properties of various biobased oils were evaluated. The oils were then investiga...

  14. Biobased lubricant from used cooking oils

    Science.gov (United States)

    As more and more people look for healthy alternatives for cooking and frying oils, the opportunity to develop high-value products from these waste streams increases. Cooking oils that are often described as healthier contain higher levels of monounsaturated fats. NuSun® sunflower oil is an example o...

  15. Lubricants for wind power plants. Gear oils. Requirements and properties; Schmierstoffe fuer Windenergieanlagen. Getriebeoele. Anforderungen und Eigenschaften

    Energy Technology Data Exchange (ETDEWEB)

    Bock, Wolfgang [Fuchs Europe Schmierstoffe GmbH, Mannheim (Germany)

    2012-11-01

    Alternative energy supply is in the focus and in the discussion world-wide. Electrical energy coming from wind power plants is an important part in the energy supply chain. The lubricants used in wind power plants are often special lubricants, developed for the specific requirements of the application. The range of lubricants included adhesive lubricants, greases, pastes, hydraulic fluids, gear and lubricating oils as well as other specialities. Besides the greases and the hydraulic oils, the gear oil is the most important lubricant in wind power plants. The gear oil is used in the main gear of a wind power plant or in the Azimut gear sets. The lubricant has to be developed to match the requirements of the gear set, the tooth sets, the bearings, the seals, paints, etc. The gear oil has to fulfil the requirements according to DIN 51517, part 3 - CLP / CKC industrial gear oils, and in addition the specific requirements of gear and bearing manufacturers according to wind power plant specifications have to be fulfilled. The presentation ''Lubricants for Wind Power Plants - Requirements and Properties'' gives an overview of the industrial gear oils market, the classification of gear oils according to German and international standards is presented, and it describes the properties of a fully synthetic industrial gear oil based on polyalphaolefin which was especially developed for the main gear unit in wind power plants. The mechanical-dynamic tests for gear oils used in wind power plants (anti-scuffing properties, roller bearing wear protection, micro-pitting protection) are presented, together with the specific tests required by world-wide known bearing manufacturers. In addition the presentation shows test results of low speed wear tests. Compatibility tests with elastomers and sealing materials and the low temperature properties of fully synthetic gear oils based on polyalphaolefin are also discussed. The industrial gear oils for wind power plants

  16. 76 FR 49525 - Advisory Circular 20-24C, Approval of Propulsion Fuels and Lubricating Oils

    Science.gov (United States)

    2011-08-10

    ... Federal Aviation Administration Advisory Circular 20-24C, Approval of Propulsion Fuels and Lubricating... Federal Aviation Administration, Attn: Mark Rumizen, Aviation Fuels Specialist, Engine and Propeller... successful aviation fuel and lubricating oil certification projects conducted over many years....

  17. Effects of two lubricant oils on marine nematode assemblages in a laboratory microcosm experiment.

    Science.gov (United States)

    Beyrem, H; Louati, H; Essid, N; Aïssa, P; Mahmoudi, E

    2010-05-01

    The effects of two lubricating oils on nematode assemblages of a Tunisian lagoon were investigated in a microcosm experiment. Sediment from a pristine site in Ghar El Melh lagoon (Western Mediterranean) was treated with either mineral oil (Mobil 20 W-50), a synthetic lubricant (Mobil 0 W-40), the same two lubricants after use in a vehicle, and effects were examined after 5 weeks. Univariate analysis showed significant differences between most univariate indices of the nematode assemblages in all the lubricant treatments as compared to the control. Total nematode abundance (I), species richness (d) and number of species (S) decreased significantly in all lubricant contaminated microcosms. However, evenness was not affected in all treated replicates except in used mineral lubricant treatment where it was significantly higher than in the control. Diversity (H') was only altered in synthetic lubricant treatments. Results from multivariate analyses of the species abundance data demonstrated that responses of nematode species to the two lubricants treatments were varied: Daptonema trabeculosum was eliminated in all lubricant treatments and seemed to be an intolerant species to oil contamination. Spirinia gerlachi increased in mineral lubricant treatments ("clean" and used) but was eliminated in all synthetic lubricant treatments. This species could be categorized as "resistant" to mineral oil contamination and intolerant to synthetic lubricant contamination. Terschellingia longicaudata increased only in synthetic lubricant treatments ("clean" and used) and appeared to be a "synthetic oil-resistant" species.

  18. Lubrication Oil Condition Monitoring and Remaining Useful Life Prediction With Particle Filtering

    Directory of Open Access Journals (Sweden)

    Yongzhi Qu

    2013-01-01

    Full Text Available In order to reduce the costs of wind energy, it is necessary to improve the wind turbine availability and reduce the operational and maintenance costs. The reliability and availability of a functioning wind turbine depend largely on the protective properties of the lubrication oil for its drive train subassemblies such as gearbox and means for lubrication oil condition monitoring and degradation detection. The wind industry currently uses lubrication oil analysis for detecting gearbox and bearing wear but cannot detect the functional failures of the lubrication oils. The main purpose of lubrication oil condition monitoring and degradation detection is to determine whether the oils have deteriorated to such a degree that they no longer fulfill their functions. This paper describes a research on developing online lubrication oil health condition monitoring and remaining useful life prediction with particle filtering technique using commercially available online sensors. The paper first presents a survey on current state-of-the-art online lubrication oil condition monitoring solutions and their characteristics along with the classification and evaluation of each technique. It is then followed by an investigation on wind turbine gearbox lubrication oil health condition monitoring and degradation detection using online viscosity and dielectric constant sensors. In particular, the lubricant performance evaluation and remaining useful life prediction of degraded lubrication oil with viscosity and dielectric constant data using particle filtering are presented. A simulation case study is provided to demonstrate the effectiveness of the developed technique.

  19. Lubrication properties of new crop oils

    Science.gov (United States)

    Oils from new crops such as lesquerella (Lesquerella fendleri), field pennycress (Thlaspi arvense L.), meadowfoam (Limnanthes alba L.), and cuphea PSR-23 (Cuphea viscosissima × Cuphea lanceolata) were investigated and compared with vegetable oils from commodity crops such as castor, corn, and soybea...

  20. Preparation of nano-copper as lubrication oil additive

    Institute of Scientific and Technical Information of China (English)

    WANG Xiao-li; XU Bin-shi; XU Yi; YU He-long; SHI Pei-jing; LIU Qian

    2005-01-01

    Nano-copper used as lubrication oil additive has good tribological property and active self-repairing effect for friction pairs. The reduction in liquid phase for preparing nano-additive is one of the most common method.Nano-copper was prepared by reduction in liquid phase. The different project and routine practice for preparing nano-copper were researched. The dispersion problem of nano-copper was investigated by surface treatment and high dispersion. The particles dimension, the dispersion stability and the purity of nano-copper were characterized by TEM and XRD. The conclusion indicates that the methods of the preparation and dispersion can obtain 20 nm copper additive with good dispersion property in lubrication oil.

  1. Eco-Friendly Multipurpose Lubricating Greases from Vegetable Residual Oils

    Directory of Open Access Journals (Sweden)

    Ponnekanti Nagendramma

    2015-10-01

    Full Text Available Environmentally friendly multipurpose grease formulation has been synthesized by using Jatropha vegetable residual oil with lithium soap and multifunctional additive. The thus obtained formulation was evaluated for its tribological performance on a four-ball tribo-tester. The anti-friction and anti-wear performance characteristics were evaluated using standard test methods. The biodegradability and toxicity of the base oil was assessed. The results indicate that the synthesized residual oil grease formulation shows superior tribological performance when compared to the commercial grease. On the basis of physico-chemical characterization and tribological performance the vegetable residual oil was found to have good potential for use as biodegradable multipurpose lubricating grease. In addition, the base oils are biodegradable and non toxic.

  2. Life Cycle Assessment of Lubricant Oil Plastic Containers in Brazil

    Directory of Open Access Journals (Sweden)

    Maria Clara Oliveira

    2017-04-01

    Full Text Available Brazil, like many emerging countries, has experienced a fast growth in the demand for automobiles in recent decades. This has produced a significant increase in the amount of hazardous waste to be disposed of, including used lubricant oil. Restrictive regulations are being used by many nations to deal with this problem, focusing on treatments, such as recycling, to avoid resource depletion. Specific rules for disposal of used lubricant oil already exist in various countries, including Brazil, but not for its containers. Using the life cycle assessment methodology, this article evaluates different management options for the destination of Lubricant Oil Plastic Containers (LOPCs, comparing recycling and incineration to disposal in an industrial landfill. Results show that reducing the proportion of LOPCs destined to the landfill has positive impacts in lowering the burdens caused in the life cycle of LOPCs. Incineration, which is not a technology used for destination of LOPCs in Brazil, proved to be a promising option when combined with recycling for treatment of this kind of waste. Combining different destinations is also a good option as long as economic, logistics and the environment are taken into consideration. The present paper concludes that emerging countries are able to manage hazardous waste provided that there is adequate legislation and political will along with cooperation from the private sector. This study can be helpful to the decision-making processes concerning hazardous waste, especially for industrial strategies and policy makers.

  3. Health, safety and environmental aspects of used crankcase lubricating oils.

    Science.gov (United States)

    Hewstone, R K

    1994-12-01

    This paper indicates the health, safety and environmental concerns which have been expressed regarding the handling, re-use and disposal of used crankcase lubricating oils and discusses the factors which are believed to these concerns. It also indicates the current and developing situation with regard to legislation in this area, discusses briefly the disposal of used oils in cement kilns and sets out the views of the industry sectors most involved. Finally, it describes the simple safeguards the adoption of which should enable these materials to be handled with a high degree of safety.

  4. BIOSTABILITY OF USED LUBRICATING OILS FOR HIGH-SPEED ENGINES WITH SPARK IGNITION

    OpenAIRE

    YUSIFOVA AIDA RAFIQ QIZI; RAFIYEV AZAD NATIG OGLU

    2015-01-01

    The article presents the investigation results of the biological stability of the waste and regenerated lubricating oil Mysella-40, designed for high-speed engines with spark ignition. Biocides were prepared to protect the oil from microbial destruction. It was found that the use of biocides in the recommended concentration has no negative effect on the basic performance of the lubricating oil.

  5. Improving vegetable oil properties for lubrication methods

    Science.gov (United States)

    The inherent problems of vegetable oils, such as poor oxidation and low-temperature properties, can be improved by attaching functional groups at the sites of unsaturation through chemical modifications. In this article, you will see how functionalization helps overcome these disadvantages....

  6. Pyrolysis bio-oils as additives for vegetable oil based lubricants

    Science.gov (United States)

    Softwood and hardwood lignins, along with hardwood as such, were pyrolyzed to afford bio-oil distillates in which phenols were major products. Extraction with alkali gave a range of lignin-related phenols having molecular weights (MWs) from 110 to 344. Because vegetable oil based lubricants have dra...

  7. Optical property and spectroscopy studies on the selected lubricating oil in the terahertz range

    Institute of Scientific and Technical Information of China (English)

    TIAN Lu; ZHOU QingLi; JIN Bin; ZHAO Kun; ZHAO SongQing; SHI YuLei; ZHANG CunLin

    2009-01-01

    The optical property and spectroscopy of selected kinds of lubricating oil are studied based on the terahertz time-domain spectroscopy (THz-TDS) in the spectral range of 0.3-1.6 THz. The samples are classified by their characteristics via the near-infrared spectrum. The experimental results reveal that lubricating oil is more sensitive in the range of terahertz than in the near-infrared, and the specific kinds of lubricating oil can be identified according to their different spectral features in the terahertz range. The THz-TDS technology applied to lubricating oil analysis has potentially significant impact on the petroleum field.

  8. Optical property and spectroscopy studies on the selected lubricating oil in the terahertz range

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The optical property and spectroscopy of selected kinds of lubricating oil are studied based on the terahertz time-domain spectroscopy (THz-TDS) in the spectral range of 0.3-1.6 THz. The samples are classified by their characteristics via the near-infrared spectrum. The experimental results reveal that lubricating oil is more sensitive in the range of terahertz than in the near-infrared,and the specific kinds of lubricating oil can be identified according to their different spectral features in the terahertz range. The THz-TDS technology applied to lubricating oil analysis has potentially significant impact on the petroleum field.

  9. Numerical Simulation of Oil Jet Lubrication for High Speed Gears

    Directory of Open Access Journals (Sweden)

    Tommaso Fondelli

    2015-01-01

    Full Text Available The Geared Turbofan technology is one of the most promising engine configurations to significantly reduce the specific fuel consumption. In this architecture, a power epicyclical gearbox is interposed between the fan and the low pressure spool. Thanks to the gearbox, fan and low pressure spool can turn at different speed, leading to higher engine bypass ratio. Therefore the gearbox efficiency becomes a key parameter for such technology. Further improvement of efficiency can be achieved developing a physical understanding of fluid dynamic losses within the transmission system. These losses are mainly related to viscous effects and they are directly connected to the lubrication method. In this work, the oil injection losses have been studied by means of CFD simulations. A numerical study of a single oil jet impinging on a single high speed gear has been carried out using the VOF method. The aim of this analysis is to evaluate the resistant torque due to the oil jet lubrication, correlating the torque data with the oil-gear interaction phases. URANS calculations have been performed using an adaptive meshing approach, as a way of significantly reducing the simulation costs. A global sensitivity analysis of adopted models has been carried out and a numerical setup has been defined.

  10. Experimental Investigation on Usage of Palm Oil as a Lubricant to Substitute Mineral Oil in CI Engines

    Directory of Open Access Journals (Sweden)

    K. S. V. Krishna Reddy

    2014-01-01

    Full Text Available Due to growing environmental concerns, vegetable oils are finding their way into lubricants for industrial and transportation applications. The substitution of mineral oil with vegetable oil as a base stock for an environment friendly lubricant in a CI engine is explored in this study without adding any additives. The experiments have been conducted with a mixture of palm oil and mineral oil, at different compositions. Blends of palm oil and mineral oil in different compositions, 0, 25, and 50 (by vol % were added to base SAE20W40 mineral oil to obtain different lubricant blends. The parameters evaluated include brake thermal efficiency, brake specific fuel consumption, volumetric efficiency, and mechanical efficiency and exhaust emissions. The engine performance and emission tests were carried out on a single cylinder, water cooled, 4-stroke CI engine. Compared to mineral oil, the palm oil-based lubricant revealed appreciable expedience on engine and emission performance.

  11. Performance of classic oils and lubricating oils in froth flotation of Ukraine coal

    Energy Technology Data Exchange (ETDEWEB)

    Ibrahim Sonmez; Yakup Cebeci [Cumhuriyet University, Sivas (Turkey). Metallurgical and Materials Engineering Department, Engineering Faculty

    2006-09-15

    In this study, the appropriate collector and collector amount for Ukraine coal in froth flotation was determined. For this purpose, the performance of classic oils (kerosene, diesel-oil and fuel-oil) and lubricating oils (spindle oil, bright stock and heavy neutral) was evaluated by combustible recovery, ash rejection and efficiency index. It was found that the combustible recovery and ash rejection changed, depending on the type and concentration of oil. The maximum combustible recovery was obtained by using bright stock. It was determined that bright stock, fuel-oil and kerosene were suitable for the flotation of Ukraine coal. On considering the flotation efficiency index values, the best results were obtained with bright stock and diesel-oil. Consequently, it was shown that bright stock and spindle oil could be used as alternative oils instead of classic oils for cleaning of Ukraine coal by the froth flotation. 28 refs., 4 figs., 1 tab.

  12. Engineered silica nanoparticles as additives in lubricant oils

    Science.gov (United States)

    Díaz-Faes López, Teresa; Fernández González, Alfonso; Del Reguero, Ángel; Matos, María; Díaz-García, Marta E.; Badía-Laíño, Rosana

    2015-10-01

    Silica nanoparticles (SiO2 NPs) synthesized by the sol-gel approach were engineered for size and surface properties by grafting hydrophobic chains to prevent their aggregation and facilitate their contact with the phase boundary, thus improving their dispersibility in lubricant base oils. The surface modification was performed by covalent binding of long chain alkyl functionalities using lauric acid and decanoyl chloride to the SiO2 NP surface. The hybrid SiO2 NPs were characterized by scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, simultaneous differential thermal analysis, nuclear magnetic resonance and dynamic light scattering, while their dispersion in two base oils was studied by static multiple light scattering at low (0.01% w/v) and high (0.50%w/v) concentrations. The nature of the functional layer and the functionalization degree seemed to be directly involved in the stability of the suspensions. The potential use of the functional SiO2 NPs as lubricant additives in base oils, specially designed for being used in hydraulic circuits, has been outlined by analyzing the tribological properties of the dispersions. The dendritic structure of the external layer played a key role in the tribological characteristics of the material by reducing the friction coefficient and wear. These nanoparticles reduce drastically the waste of energy in friction processes and are more environmentally friendly than other additives.

  13. The Stability of Lubricant Oil Acidity of Biogas Fuelled Engine due to Biogas Desulfurization

    Science.gov (United States)

    Gde Tirta Nindhia, Tjokorda; Wayan Surata, I.; Wardana, Ari

    2017-05-01

    This research is established for the purpose of the understanding the stability of the acidity of lubricant oil in biogas fuelled engine due to the absence of hydrogen sulfide (H2S). As was recognized that other than Methane (CH4), there are also other gas impurities in the biogas such as carbon dioxide (CO2), hydrogen sulfide (H2S), moisture (H2O) and ammonia (NH3). Due to H2S contents in the biogas fuel, the engine was found failure. This is caused by corrosion in the combustion chamber due to increase of lubricant acidity. To overcome this problem in practical, the lubricant is increased the pH to basic level with the hope will be decrease to normal value after several time use. Other method is by installing pH measurement sensor in the engine lubricant so that when lubricant is known turn to be acid, then lubricant replacement should be done. In this research, the effect of biogas desulfurization down to zero level to the acidity of lubricant oil in the four stroke engine was carried out with the hope that neutral lubrication oil to be available during running the engine. The result indicates that by eliminating H2S due desulfurization process, effect on stability and neutrality of pH lubricant. By this method the engine safety can be obtained without often replacement the lubricant oil.

  14. Effect of Bearing Compliance on Thermo-hydrodynamic Lubrication of High Speed Misaligned Journal Bearing Lubricated with Bubbly Oil

    Directory of Open Access Journals (Sweden)

    Basim Ajeel Abass

    2015-03-01

    Full Text Available In the present work the effect of bearing compliance on the performance of high speed misaligned journal bearing lined with a compliant PTFE liner lubricated with bubbly oil at high speeds has been studied. The effect of induced oil film temperature due to shearing effect has been implemented. Hydrodynamic effect of the complaint bearing and the influence of aerated oil have been examined by the classical thermohydrodynamic lubrication theory modified to include the effect of oil film turbulence and oil film temperature with suitable models for bubbly oil viscosity and density. The effect of liner elastic deformation has been implemented by using Winkler model. The effects of variable density and specific heat on the most importantbearing parameters such as maximum pressure, maximum temperature, bearing load carrying capacity and power losses have been investigated.The results obtained show that the oil film pressure and load carrying capacity increased for the bearing lubricated with bubbly oil of higher aeration level and smaller size of air bubbles. Including the effect of elastic deformation of the bearing liner reduces the oil film pressure, load carrying capacity and frictional power loss for the misaligned bearing working at the same circumstances

  15. Evaporation rate and vapor pressure of selected polymeric lubricating oils.

    Science.gov (United States)

    Gardos, M. N.

    1973-01-01

    A recently developed ultrahigh-vacuum quartz spring mass sorption microbalance has been utilized to measure the evaporation rates of several low-volatility polymeric lubricating oils at various temperatures. The evaporation rates are used to calculate the vapor pressures by the Langmuir equation. A method is presented to accurately estimate extended temperature range evaporation rate and vapor pressure data for polymeric oils, incorporating appropriate corrections for the increases in molecular weight and the change in volatility of the progressively evaporating polymer fractions. The logarithms of the calculated data appear to follow linear relationships within the test temperature ranges, when plotted versus 1000/T. These functions and the observed effusion characteristics of the fluids on progressive volatilization are useful in estimating evaporation rate and vapor pressure changes on evaporative depletion.

  16. Synthetics, mineral oils, and bio-based lubricants chemistry and technology

    CERN Document Server

    Rudnick, Leslie R

    2005-01-01

    As the field of tribology has evolved, the lubrication industry is also progressing at an extraordinary rate. Updating the author's bestselling publication, Synthetic Lubricants and High-Performance Functional Fluids, this book features the contributions of over 60 specialists, ten new chapters, and a new title to reflect the evolving nature of the field: Synthetics, Mineral Oils, and Bio-Based Lubricants: Chemistry and Technology. The book contains chapters on all major lubricant fluids used in a wide range of applications. For each type of lubricant, the authors discuss the historical develo

  17. The dermal carcinogenic potential of unrefined and hydrotreated lubricating oils.

    Science.gov (United States)

    McKee, R H; Daughtrey, W C; Freeman, J J; Federici, T M; Phillips, R D; Plutnick, R T

    1989-08-01

    Unrefined lubricating oils contain relatively high levels of polycyclic aromatic hydrocarbons (PAH) and have been shown to induce tumors in mouse skin. Exxon has developed a new method of refining these materials, a severe hydrotreatment process that is optimized for PAH removal. The specific objectives of the current study were to assess PAH reduction and then to evaluate directly the dermal carcinogenic potential of the materials that spanned the range of products produced by this method. The test samples included unrefined light and heavy vacuum distillates from a naphthenic crude oil, as well as the corresponding severely hydrotreated products. Two sets of samples were prepared to assess the effects of various operating parameters in the reactor. Additionally, positive (benzo[a]pyrene), negative (white mineral oil) and vehicle (toluene) control groups were included to assess the sensitivity and specificity of the bioassay. Each sample was applied in twice-weekly aliquots to the backs of 40 male C3H mice. In the analytical studies, significant reductions in the levels of several specific PAH were demonstrated. In the dermal carcinogenesis studies, the unrefined oils and the positive control induced tumors and also significantly reduced survival. None of the mice treated with severely hydrotreated oils or with the negative or vehicle controls developed skin tumors, and survival of these mice was not significantly different from the control. Thus, the data demonstrated that this new, severe hydrotreatment process was an effective means of converting carcinogenic feedstocks to non-carcinogenic products.

  18. Comparison of lubricant properties of castor oil and commercial engine oil

    Directory of Open Access Journals (Sweden)

    Binfa Bongfa

    2015-06-01

    Full Text Available The tribological performance of crude Nigeria-based castor oil has been investigated and compared with that of a foreign, 20W-50 high quality crankcase oil, to see its suitability as base oil for lubricating oils in indigenous vehicle and power plants engines. The experiment was conducted using a four ball tester. The results showed that unrefined castor oil has superior friction reduction and load bearing capability in an unformulated form than the commercial oil; can compete favourably with the commercial oil in wear protection when formulated with suitable antiwear agent, hence can be a good alternative base stock for crankcase oils suitable for Nigeria serviced vehicles, and plants engines from tribological, environmental, and non-food competitive points of view.

  19. Effect of Inertial Force on Thermal Elastohydrodynamic Lubrication of Oil Film Bearing in Rolling Mill Lubricated by the Oil-water Two-phase Flow

    Science.gov (United States)

    Wang, Tao; Wang, You-Qiang; Wang, Jian; Fan, Xiao-Meng

    2016-05-01

    The oil film bearing in rolling mill as the research object in this paper is established oilwater two-phase flow of thermal elastohydrodynamic lubrication (EHL) model with the inertia force and thermal effect of the Reynolds equation. The oil film bearing in rolling mill in oil-water two-phase flow is analyzed the effect on the pyrolysis with considering inertia force, and the lubricant film pressure, film thickness with the changes in the relationship between water content, rolling force and spindle speed. The results showed that the lubricant film thickness is increased and carrying capacity is also increased with considering inertial force. With the increase of water content, lubricant film thickness is increased and the carrying capacity is decreased.

  20. Study on Low-Temperature Traction Behavior of a Space Lubricating Oil No. 4116

    Institute of Scientific and Technical Information of China (English)

    Wang Yanshuang; Cheng Junwei; Cai Yujun

    2015-01-01

    The traction behavior of space lubricating oil No. 4116 was measured and analyzed at various oil inlet tempera-tures below 0℃and various rolling speeds under normal loads by a test rig simulating the operating conditions of space bearings. A traction coefifcient calculation model was presented. The rheological property and rheological parameters of the lubricant at a low oil inlet temperature were analyzed based on the Tevaarwerk-Johnson model. The results showed that the lubricating oil No. 4116 was sensitive to the rolling speed and had lower sensitivity to the normal load. This lubricating oil is more suitable for applications under high speed when it is used below 0℃. It behaves as an elastic-plastic lfuid operating below 0℃. Both the average limiting shear stress and the average elastic shear modulus have a negative correlation with the rolling speed and oil inlet temperature and have a positive correlation with the normal load.

  1. How tests of lubricating and transformer oils became part of power plant chemistry in Denmark

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, H. [I/S Nordjyllandsvaerket, Vodskov (Denmark)

    1996-12-01

    Lubricating, hydraulic and transformer oils based on refined crude oil are used in nearly all power station components, such as gear, turbines, hydraulic stations, feed pumps and transformers. The function of these components totally depends on the condition of the oils and their properties. Seen from this point one may wonder why examination and evaluation of oils did not become part of the power station chemistry within the ELSAM utility area until during the middle of the eighties. We started to examine the properties of lubricating oils at the time when several steam turbines experienced serious problems with formation of deposits in their hydraulic control circuits. This work was intensified in connection with the significant number of CHPs and wind turbines erected within the Danish electricity sector during the past 10 years or so. The majority of the CHPs are natural gas fired turbines or motors, equipment which severely stresses the lubricating oil. In collaboration with KEMA, the Netherlands, we have carried through with a large examination of lubricating oils in gas turbines and we have found suitable oil types. The objectives of our work with lubricating and transformer oils have been to link together the laboratory measurements with operational experience. Only by doing this is it possible to utilize the laboratory measurements in a correct way. It must be remembered that the main part of all oil specifications concerns the properties of new oils. Only very little is published about the requirements concerning used oils. (EG)

  2. AN AZERBAIDZHAN SSR. INSTITUTE OF ADDITIVE CHEMISTRY ADDITIVES TO LUBRICATING OILS. PROBLEMS OF SYNTHESIS, INVESTIGATION AND USE OF OIL ADDITIVES; FUELS AND POLYMER MATERIALS (SELECTED ARTICLES),

    Science.gov (United States)

    An Azerbaidzhan SSR. Institute of additive chemistry additives to lubricating oils . Problems of synthesis, investigation and use of oil additives; fuels and polymer materials (Selected articles)--Translation.

  3. Effectiveness of Biodiesel from Various Tropical Oil Crops on Lubricity Improvement of Ultra Low Sulfur Diesel (ULSD)

    Energy Technology Data Exchange (ETDEWEB)

    Chollacoop, Nuwong; Topaiboul, Subongkoj; Goodwin, Vituruch (Bioenergy Group, National Metal and Materials Technology Center (MTEC), Thailand Science Park, Pathumthani, 12120 (Thailand)). e-mail: nuwongc@mtec.or.th

    2008-10-15

    Ultra low sulfur diesel (ULSD) has been introduced worldwide with an aim to reduce emission. Since the desulfurization process for ULSD inadvertently reduces its lubricity, lubricity additive is needed. Biodiesel emerges as a potential candidate due to its excellent lubricity property and little sulfur content. In the present study, biodiesel from various energy crops available in Thailand was added at various amounts to ULSD to test the lubricity according to the CEC-F-06-A-96 standard (using High-Frequency Reciprocating Rig: HFRR [1]). It was found that when biodiesel from crude palm, jatropha, soybean, coconut, sunflower, rice, corn and sesame oils of less than 1% (by volume) is additized to ULSD, the lubricity is improved to meet the diesel standard. Further addition beyond 2% (by volume) does not improve lubricity remarkably, where the lubrication seems to saturate. Biodiesel improves lubricity property by film formation preventing mechanical contact between the rubbing surfaces, and the effectiveness varies among different feedstock oils. Biodiesel from crude palm oil, jatropha oil and coconut oil seemingly are superior lubricity additives in ULSD than that from soybean oil, sunflower oil, rice oil, corn oil and sesame oil. Keywords: biodiesel, bio-lubricants, palm oil, sunflower oil

  4. Developments in lubricant technology

    CERN Document Server

    Srivastava, S P

    2014-01-01

    Provides a fundamental understanding of lubricants and lubricant technology including emerging lubricants such as synthetic and environmentally friendly lubricants Teaches the reader to understand the role of technology involved in the manufacture of lubricants Details both major industrial oils and automotive oils for various engines Covers emerging lubricant technology such as synthetic and environmentally friendly lubricants Discusses lubricant blending technology, storage, re-refining and condition monitoring of lubricant in equipment

  5. Comparison of Extreme Pressure Additive Treat Rates in Soybean and Mineral Oils Under Boundary Lubrication Conditions

    Science.gov (United States)

    Traditionally, it is considered that, under boundary lubrication conditions, the reduction in friction and wear is mostly dependent on Extreme Pressure (EP) additives, rather than the basestock. However, several studies indicate that vegetable oils also contribute to the lubricity under this regime...

  6. Tribological performances of diamond film and graphite/diamond composite film with paraffin oil lubrication

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In this paper, the tribological performances of diamond film and graphite/diamond com-posite film were compared on an SRV wear testing machine with paraffin oil lubrication. The sur-face morphologies of specimens and wear tracks were observed by SEM. The wear volumes ofwear tracks were measured by profilometer. The influence of load on the tribological performancesof different specimens was studied. The wear mechanism under paraffin oil lubrication was ana-lyzed. The results showed that with paraffin oil lubrication, the friction coefficient and wear volumeof graphite/diamond composite film specimen are lower than diamond film. Under paraffin oil lu-brication, the wear mechanisms of both diamond film and graphite/diamond composite film weremainly sub-micro-fracture.

  7. Multivariate quality control of lubricating oils using Fourier transform infrared spectroscopy

    OpenAIRE

    Borin,Alessandra; Poppi, Ronei Jesus

    2004-01-01

    Multivariate quality control in conjunction with Fourier transform infrared Spectroscopy (FTIR) were used to qualitatively detect the class and the condition of lubricating oils. The multivariate approach was based on principal component analysis (PCA), first to classify the lubricating oil type (mineral, synthetic and semi-synthetic) and then to develop two control charts: a T² chart using the most significant principal components and a Q chart with the PC not used in the first chart. From t...

  8. Lubricating oil compositions containing overbased calcium sulfonates and metal salts of alkyl catechol dithiophosphoric acid

    Energy Technology Data Exchange (ETDEWEB)

    Yamaguchi, E.S.; Cerrito, E.; Liston, T.V.

    1987-05-26

    This patent describes a lubricating oil composition containing an overbased calcium hydrocarbyl sulfonate. The improvement wherein the lubricating oil composition additionally comprises an effective amount to reduce wear of a metal salt of an alkyl catechol dithiophosphoric acid ester of the formula: wherein R is alkyl containing 10 to 18 carbon atoms, or mixtures thereof, M is an alkali or alkaline earth metal or transition metal and n corresponds to the valence of the metal M.

  9. Performance of palm oil as a biobased machining lubricant when drilling inconel 718

    Directory of Open Access Journals (Sweden)

    Abd Rahim Erween

    2017-01-01

    Full Text Available Metalworking fluid acts as cooling and lubrication agent at the cutting zone in the machining process. However, conventional Metalworking fluid such mineral oil gives negative impact on the human and environment. Therefore, the manufacture tends to substitute the mineral oil to bio-based oil such as vegetables and synthetic oil. In this paper, the drilling experiment was carried out to evaluate the efficiency of palm oil and compare it with minimal quantity lubrication technique using synthetic ester, flood coolant and air blow with respect to cutting temperature, cutting force, torque and tool life. The experimental results showed that the application of palm oil under minimal quantity lubrication condition as the cutting fluid was more efficient process as it improves the machining performances.

  10. Lubricant for clean rolling: Escapee oil particles keep cold rolling steel mills lubricated

    NARCIS (Netherlands)

    Van De Graaf, A.

    2002-01-01

    One of the unique selling points of the Corus steel mills at IJmuiden is the quality of the steel they produce. The lubrication used during the last production stage is one of the factors that determine how clean and smooth the steel will emerge from the mill. The usual lubricant consists of an emul

  11. AUTOMOTIVE DIESEL MAINTENANCE, UNIT V, MAINTAINING THE LUBRICATION SYSTEM--DETROIT DIESEL ENGINE.

    Science.gov (United States)

    Human Engineering Inst., Cleveland, OH.

    THIS MODULE OF A 30-MODULE COURSE IS DESIGNED TO DEVELOP AN UNDERSTANDING OF THE OPERATION AND MAINTENANCE OF THE DIESEL ENGINE LUBRICATION SYSTEM. TOPICS ARE LUBE OILS USED, MAINTENANCE OF THE LUBRICATION SYSTEM, AND CRANKCASE VENTILATION COMPONENTS. THE MODULE CONSISTS OF A SELF-INSTRUCTIONAL BRANCH PROGRAMED TRAINING FILM "BASIC ENGINE…

  12. Lubrication system

    Energy Technology Data Exchange (ETDEWEB)

    Wadding, C.; Lagasse, N.L.; Milo, G.T.; Vankamerik, J.G.

    1986-02-11

    This patent describes a lubrication system for controlling the flow of lubricant as a function of the altitude at which a gas turbine engine is operating. This lubrication system is comprised of: 1.) A source of lubricant under pressure; 2.) A unit requiring lubrication; 3.) A movable valve in fluid communication with the source and with the unit for regulating the flow of lubricant from the source to the unit; and 4.) An altitude sensor associated with the movable valve for positioning the movable valve to control the flow of lubricant from the source to the unit, as a function of the altitude at which the engine is operating.

  13. The use of surface layer with boron in friction pairs lubricated by engine oils

    Science.gov (United States)

    Szczypiński-Sala, W.; Lubas, J.

    2016-09-01

    The aim of the present work is to determine the influence of surface layers with boron and engine oil on the processes of friction and wear in friction pairs. The ring samples with borided surface layer cooperated under test conditions with counterparts made with CuPb30 and AlSn20 bearing alloys. During the tests, the friction pairs were lubricated with 15W/40 Lotos mineral oil and 5W/40 Lotos synthetic oil. The lubrication of friction area with Lotos mineral oil causes the reduction of the friction force, the temperature in the friction area and the wear of the bearing alloys under study, whereas the lubrication with Lotos synthetic oil reduces the changes in the geometrical structure of the cooperating friction pair elements. Lubrication of the friction area in the start-up phase of the friction pair by mineral oil causes faster stabilization of the friction conditions in the contact area than in the cause of lubrication of the friction pair by synthetic oil. The intensity of wear of the AlSn20 bearing alloy cooperating with the borided surface layer is three times smaller than the intensity of use of the CuPb30 alloy bearing.

  14. Effects of used lubricating oil on two mangroves Aegiceras corniculatum and Avicennia marina

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    An outdoor experiment was set up to investigate the effects of used lubricating oil (5 L/m2) on Aegiceras corniculatum Blanco. and Avicennia marina (Forsk) Vierh., two salt-excreting mangroves. A. marina was more sensitive to used lubricating oil than A. corniculatum and canopy-oiling resulted in more direct physical damage and stronger lethal effects than base-oiling. When treated with canopy-oiling, half of A. corniculatum plants survived for the whole treatment time (90 d); but, for A. marina, high mortality (83%) resulted from canopy-oiling within 3 weeks and no plants survived for 80 d. Base-oiling had no lethal effects on A. corniculatum plants even at the termination of this experiment, but 83% of A. marina plants died 80 d after treatment. Forty days after canopy-oiling, 93% of A. corniculatum leaves fell and no live leaves remained on A. marina plants. By the end of the experiment, base-oiling treatment resulted in about 45% of A. corniculatum leaves falling, while all A. marina leaves and buds were burned to die. Lubricating oil resulted in physiological damage to A. corniculatum leaves, including decreases in chlorophyll and carotenoid contents, nitrate reductase, peroxidase and superoxide dismutase activities, and increases in malonaldehyde contents. For both species, oil pollution significantly reduced leaf, root, and total biomass, but did not significantly affect stem biomass. Oil pollution resulted in damage to the xylem vessels of fine roots but not to those of mediate roots.

  15. Inspection for Abnormal Quality of Lubrication Oil%机油品质异常监测

    Institute of Scientific and Technical Information of China (English)

    张更云; 付礼程; 王宪成; 和穆

    2012-01-01

    对某重型柴油机机油在使用过程中异常进入柴油、冷却液、被氧化和被污染的情况进行模拟实验。分别取不同体积百分比的柴油、冷却液、乙酸均匀混入纯净的机油中,使用油品传感器对混合后的机油测量其粘度、密度、介电常数和温度。测试结果表明:柴油稀释机油使得机油的粘度、闪电降低;冷却液稀释机油使得机油的介电常数、粘度增大,密度基本不变;机油被氧化使得机油的粘度增大,介电常数减小,密度基本不变。通过机油品质可监测柴油机润滑系统的技术状况,为实车机油的在线监测提供参考和按质换油提供手段。%This paper experimentalizes about unexpected leaking of diesel, coolant and lubrication oil oxidized and polluted in lubricant syslem of a heavy diesel engine. Lubricant oil sensor measures dynamic viscosity, density, dielectric constant and temperature of the mixed lubricant oil when diesel, coolant and acetic acid are taken separately in different proportions. The results reveal that: dynamic viscosity and flash point of lubricant oil decrease when diluted by diesel; the dielectric constant and dynamic viscosity of lubricant oil increase and density keeps fixedness when diluted by coolant; oxidized lubricant oil has the increasing dynamic viscosity and decreasing dielectric constant but density keeps fixedness. The inspection for exceptional quality of lubricant oil can reflect technical status of lubricant system and provide reference as well as instrument with real vehicle inspecting online and exchanging lubricant oil.

  16. Comparative Study on Particles Formation in a Diesel Engine When Lubricating Oil Involved in Fuel Combustion

    Directory of Open Access Journals (Sweden)

    Lihui Dong

    2015-01-01

    Full Text Available The effect of lubricating oil on the morphology of particulate matter (PM was studied in a diesel engine fueled with pure diesel fuel and blended fuel containing 0.5% by weight of lubricating oil. Particulate matter emitted by diesel engines is formed primarily by soot agglomerates which are composed of primary particles. In this paper, particulate matter was collected with a thermophoretic sampling system, and a high-resolution transmission electron microscope (TEM was used to investigate the primary particles. A Fast Particulate Spectrometer, DMS 500, was used to determine the particle size distributions. The TEM results indicated that the mean diameters of the primary particles increased after the oil was added into the fuel. Particle size distributions results showed that lubricating oil in the fuel gave rise to a higher concentration in nucleation mode.

  17. ZETA POTENTIAL AND COLOR INVESTIGATIONS OF VEGETABLE OIL BASED EMULSIONS AS ECO-FRIENDLY LUBRICANTS

    Directory of Open Access Journals (Sweden)

    ROMICĂ CREŢU

    2017-06-01

    Full Text Available In the past 10 years, the need for biodegradable lubricants has been more and more emphasized. The use of vegetable oils as lubricants offers several advantages. The vegetable oils are biodegradable; thus, the environmental pollution is minimal either during or after their use. The aim of this paper is to presents a preliminary study concerning the influence of some preparation conditions on the stability of vegetable oil-in-water (O/W emulsions as eco-friendly lubricants stabilized by nonionic surfactant. In this context, vegetable oil-in-water emulsions characteristics where assessed using microscopically observation and zeta potential. In addition, the color of these emulsions can be evaluated. It can be observed that the emulsions tend to stabilize in time.

  18. Effects of Chlorinated Paraffin and ZDDP Concentrations on Boundary Lubrication Properties of Mineral and Soybean Oils

    Science.gov (United States)

    The effect of chlorinated paraffin (CP) and zinc di-ethylhexyl dithio phosphate (ZDDP) concentration in polar and non-polar base fluids on boundary lubrication properties was investigated. The non-polar fluid was a solvent refined low sulfur heavy paraffinic mineral oil (150N oil); and the polar fl...

  19. Adsorption Behavior of Heat Modified Soybean Oil via Boundary Lubrication Coefficient of Friction Measurements

    Science.gov (United States)

    The frictional behaviors of soybean oil and heat modified soybean oils with different Gardner scale viscosities as additives in hexadecane have been examined in a boundary lubrication test regime (steel contacts) using Langmuir adsorption model. The free energy of adsorption (delta-Gads) of various...

  20. Oxidation and low temperature stability of polymerized soybean oil-based lubricants

    Science.gov (United States)

    Oxidation and low temperature stability of polymerized soybean oil (PSO)-based lubricants have been investigated by the pressurized differential scanning calorimetry (PDSC) method. It was found that PSO samples have lower oxidative stability than their precursor, soybean oil. The main reason for the...

  1. Properties of dry film lubricants prepared by spray application of aqueous starch-oil composites

    Science.gov (United States)

    Aqueous dispersions of starch-soybean oil (SBO) and starch-jojoba oil (JO) composites, prepared by excess steam jet cooking, form effective dry film lubricants when applied as thick coatings to metal surfaces by doctor blade. This application method necessitates long drying times, is wasteful, requ...

  2. Determining an Efficient Solvent Extraction Parameters for Re-Refining of Waste Lubricating Oils

    Directory of Open Access Journals (Sweden)

    Hassan Ali Durrani

    2012-04-01

    Full Text Available Re-refining of vehicle waste lubricating oil by solvent extraction is one of the efficient and cheapest methods. Three extracting solvents MEK (Methyl-Ethyl-Ketone, 1-butanol, 2-propanol were determined experimentally for their performance based on the parameters i.e. solvent type, solvent oil ratio and extraction temperature. From the experimental results it was observed the MEK performance was highest based on the lowest oil percent losses and highest sludge removal. Further, when temperature of extraction increased the oil losses percent also decreased. This is due to the solvent ability that dissolves the base oil in waste lubricating oil and determines the best SOR (Solvent Oil Ratio and extraction temperatures.

  3. Determination of the aromatic hydrocarbon to total hydrocarbon ratio of mineral oil in commercial lubricants.

    Science.gov (United States)

    Uematsu, Yoko; Suzuki, Kumi; Ogimoto, Mami

    2016-01-01

    A method was developed to determine the aromatic hydrocarbon to total hydrocarbon ratio of mineral oil in commercial lubricants; a survey was also conducted of commercial lubricants. Hydrocarbons in lubricants were separated from the matrix components of lubricants using a silica gel solid phase extraction (SPE) column. Normal-phase liquid chromatography (NPLC) coupled with an evaporative light-scattering detector (ELSD) was used to determine the aromatic hydrocarbon to total hydrocarbon ratio. Size exclusion chromatography (SEC) coupled with a diode array detector (DAD) and a refractive index detector (RID) was used to estimate carbon numbers and the presence of aromatic hydrocarbons, which supplemented the results obtained by NPLC/ELSD. Aromatic hydrocarbons were not detected in 12 lubricants specified for use for incidental food contact, but were detected in 13 out of 22 lubricants non-specified for incidental food contact at a ratio up to 18%. They were also detected in 10 out of 12 lubricants collected at food factories at a ratio up to 13%. The centre carbon numbers of hydrocarbons in commercial lubricants were estimated to be between C16 and C50.

  4. Identification of lubrication oil in the particulate matter emissions from engine exhaust of in-service commercial aircraft.

    Science.gov (United States)

    Yu, Zhenhong; Herndon, Scott C; Ziemba, Luke D; Timko, Michael T; Liscinsky, David S; Anderson, Bruce E; Miake-Lye, Richard C

    2012-09-04

    Lubrication oil was identified in the organic particulate matter (PM) emissions of engine exhaust plumes from in-service commercial aircraft at Chicago Midway Airport (MDW) and O'Hare International Airport (ORD). This is the first field study focused on aircraft lubrication oil emissions, and all of the observed plumes described in this work were due to near-idle engine operations. The identification was carried out with an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF AMS) via a collaborative laboratory and field investigation. A characteristic mass marker of lubrication oil, I(85)/I(71), the ratio of ion fragment intensity between m/z = 85 and 71, was used to distinguish lubrication oil from jet engine combustion products. This AMS marker was based on ion fragmentation patterns measured using electron impact ionization for two brands of widely used lubrication oil in a laboratory study. The AMS measurements of exhaust plumes from commercial aircraft in this airport field study reveal that lubrication oil is commonly present in organic PM emissions that are associated with emitted soot particles, unlike the purely oil droplets observed at the lubrication system vent. The characteristic oil marker, I(85)/I(71), was applied to quantitatively determine the contribution from lubrication oil in measured aircraft plumes, which ranges from 5% to 100%.

  5. Effect of temperature on lubrication with biobased oils

    Science.gov (United States)

    Temperature is an important parameter affecting the performance of lubricant ingredients. It affects such important tribological characteristics as viscosity, film thickness, adsorption, desorption, friction, and wear. Temperature also promotes oxidation, polymerization, and degradation which nega...

  6. LG Group Taps Lubricating Oil Market in China

    Institute of Scientific and Technical Information of China (English)

    Shi Wei

    2002-01-01

    @@ Based on the information made available from a joint new conference sponsored by Beijing Haiyuancang Commercial and Trade Co Ltd and ROK-based LG Group held on May 17, Beijing Haiyuancang Commercial and Trade Co Ltd has formally become an agent of LG Group for distribution of LG lubricants in China, indicating that the lubricants from Republic of Korea starts to enter the Chinese market on a large scale.

  7. Tribological characteristics of monodispersed cerium borate nanospheres in biodegradable rapeseed oil lubricant

    Energy Technology Data Exchange (ETDEWEB)

    Boshui, Chen, E-mail: boshuichen@163.com; Kecheng, Gu; Jianhua, Fang; Jiang, Wu; Jiu, Wang; Nan, Zhang

    2015-10-30

    Graphical abstract: - Highlights: • Monodispersed stearic acid-capped cerium borate composite nanoparticles were prepared by hydrothermal method. Their morphologies, element compositions, size distributions, crystal and chemical structures, hydrophobic characteristics were also characterized. • The surface-capped cerium borate nanoparticles exhibited excellent dispersing stability in rapeseed oil. As new lubricating additives, they were also outstanding in enhancing friction-reducing and anti-wear capacities of rapeseed oil in biodegradable rapeseed oil. The results presented in this paper would be of important significance for developing green lubricants and lubricant additives. • The prominent tribological performances of SA/CeBO{sub 3} in rapeseed oil were investigated and attributed to the formation of a composite boundary lubrication film mainly composed of lubricous tribochemical species on the tribo-surfaces. - Abstract: Stearic acid-capped cerium borate composite nanoparticles, abbreviated as SA/CeBO{sub 3}, were prepared by hydrothermal method. The morphologies, element compositions, size distributions, crystal and chemical structures, hydrophobic characteristics, of SA/CeBO{sub 3} were characterized by scanning electron microscope, energy dispersive X-ray spectrometer, dynamic laser particle size analyzer, X-ray diffraction, and Fourier transform infrared spectrometer, respectively. The friction and wear performances of SA/CeBO{sub 3} as a lubricating additive in a rapeseed oil were evaluated on a four-ball tribo-tester. The tribochemical characteristics of the worn surfaces were investigated by X-ray photoelectron spectroscopy. The results showed that the hydrophobic SA/CeBO{sub 3} were monodispersed nanospheres with an average diameter of 8 nm, and exhibited excellent dispersing stability in rapeseed oil. Meanwhile, SA/CeBO{sub 3} nanospheres were outstanding in enhancing friction-reducing and anti-wear capacities of rapeseed oil. The prominent

  8. Contribution of Lubricating Oil to Particulate Matter Emissions from Light-Duty Gasoline Vehicles in Kansas City

    Science.gov (United States)

    The contribution of lubricating oil to particulate matter (PM) emissions representative of the in-use 2004 light-duty gasoline vehicles fleet is estimated from the Kansas City Light-Duty Vehicle Emissions Study (KCVES). PM emissions are apportioned to lubricating oil and gasoline...

  9. Evaluating lubricating capacity of vegetal oils using Abbott-Firestone curve

    Science.gov (United States)

    Georgescu, C.; Cristea, G. C.; Dima, C.; Deleanu, L.

    2017-02-01

    The paper presents the change of functional parameters defined on the Abbott-Firestone curve in order to evaluate the surface quality of the balls from the four ball tester, after tests done with several vegetable oils. The tests were done using two grades of rapeseed oil (degummed and refined) and two grades of soybean oil (coarse and degummed) and a common transmission oil (T90). Test parameters were 200 N and 0.576 m/s (1500 rpm) for 60 minutes. For the refined rapeseed oil, the changes in shape of the Abbott-Firestone curves are more dramatic, these being characterized by high values of Spk (the average value for the wear scars on the three balls), thus being 40% of the sum Svk + Sk + Spk, percentage also obtained for the soybean oil, but the value Spk being lower. For the degummed soybean oil, the profile height of the wear scars are taller than those obtained after testing the coarse soybean oil, meaning that the degumming process has a negative influence on the worn surface quality and the lubricating capacity of this oil. Comparing the surface quality of the wear scars on fixed tested balls is a reliable method to point out the lubricant properties of the vegetable oils, especially if they are compared to a “classical” lubricant as a non-additivated transmission mineral oil T90. The best surface after testing was obtained for the soybean oil, followed by T90 oil and the degummed grades of the soybean oil and rapeseed oil (these three giving very close values for the functional parameters), but the refined rapeseed oil generated the poorest quality of the wear scars on the balls, under the same testing conditions.

  10. Lubrication a practical guide to lubricant selection

    CERN Document Server

    Lansdown, A R

    1982-01-01

    Lubrication: A Practical Guide to Lubricant Selection provides a guide to modern lubrication practice in industry, with emphasis on practical application, selection of lubricants, and significant factors that determine suitability of a lubricant for a specific application. Organized into 13 chapters, this book begins with a brief theoretical opening chapter on the basic principles of lubrication. A chapter then explains the choice of lubricant type, indicating how to decide whether to use oil, grease, dry lubricant, or gas lubrication. Subsequent chapters deal with detailed selection of lubric

  11. Investigations on Oil Flow Rates Projected on the Casing Walls by Splashed Lubricated Gears

    OpenAIRE

    2012-01-01

    In order to investigate the oil projected by gears rotating in an oil bath, a test rig has been set up in which the quantity of lubricant splashed at several locations on the casing walls can be measured. An oblong-shaped window of variable size is connected to a tank for flow measurements, and the system can be placed at several locations. A series of formulae have been deduced using dimensional analysis which can predict the lubricant flow rate generated by one spur gear or one disk at vari...

  12. On the performance of laser-induced breakdown spectroscopy for direct determination of trace metals in lubricating oils

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Lijuan [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200062 (China); Cao, Fan; Xiu, Junshan; Bai, Xueshi; Motto-Ros, Vincent [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Gilon, Nicole [Institut des Sciences Analytiques, UMR5280 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Zeng, Heping [State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200062 (China); Yu, Jin, E-mail: jin.yu@univ-lyon1.fr [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Key Laboratory for Laser Plasmas (Ministry of Education), Department of Physics and Astrophysics, Shanghai Jiao Tong University, Shanghai 200240 (China)

    2014-09-01

    Laser-induced breakdown spectroscopy (LIBS) provides a technique to directly determine metals in viscous liquids and especially in lubricating oils. A specific laser ablation configuration of a thin layer of oil applied on the surface of a pure aluminum target was used to evaluate the analytical figures of merit of LIBS for elemental analysis of lubricating oils. Among the analyzed oils, there were a certified 75cSt blank mineral oil, 8 virgin lubricating oils (synthetic, semi-synthetic, or mineral and of 2 different manufacturers), 5 used oils (corresponding to 5 among the 8 virgin oils), and a cooking oil. The certified blank oil and 4 virgin lubricating oils were spiked with metallo-organic standards to obtain laboratory reference samples with different oil matrix. We first established calibration curves for 3 elements, Fe, Cr, Ni, with the 5 sets of laboratory reference samples in order to evaluate the matrix effect by the comparison among the different oils. Our results show that generalized calibration curves can be built for the 3 analyzed elements by merging the measured line intensities of the 5 sets of spiked oil samples. Such merged calibration curves with good correlation of the merged data are only possible if no significant matrix effect affects the measurements of the different oils. In the second step, we spiked the remaining 4 virgin oils and the cooking oils with Fe, Cr and Ni. The accuracy and the precision of the concentration determination in these prepared oils were then evaluated using the generalized calibration curves. The concentrations of metallic elements in the 5 used lubricating oils were finally determined. - Highlights: • Direct determination of wear metals in lubricating oils using LIBS. • Generalized calibration curves for different oils. • Ablation of a thin oil layer on a pure metallic target.

  13. Determination of metals in used lubricating oils by AAS using emulsified samples.

    Science.gov (United States)

    Goncalves, I M; Murillo, M; González, A M

    1998-11-01

    An efficient method was developed for the determination of metals in used lubricating oils, by atomic absorption spectrometry. Oil samples were treated with an acid mixture and then emulsified in water (10% w/w) using ethoxy nonylphenol (6% w/w) as surfactant. Emulsion characteristics (oil, surfactant content and acid mixture) were optimized to obtain the best AAS signal. Good agreement was found between calibration curves of aqueous and emulsified standard solutions when a peristaltic pump was used to introduce the solutions into the flame. The emulsion methodology was comparable, within 95% of confidence, to traditional ashing methodologies when a standard reference oil and a used lubricating oil were analyzed. Precision between 0.4 and 5% RSD was obtained when real sample was analyzed using emulsions.

  14. Evaluation of replacement thread lubricants for red lead and graphite in mineral oil

    Energy Technology Data Exchange (ETDEWEB)

    Jungling, T.L.; Rauth, D.R.; Goldberg, D.

    1998-04-30

    Eight commercially available thread lubricants were evaluated to determine the best replacement for Red Lead and Graphite in Mineral Oil (RLGMO). The evaluation included coefficient of friction testing, high temperature anti-seizing testing, room temperature anti-galling testing, chemical analysis for detrimental impurities, corrosion testing, off-gas testing, and a review of health and environmental factors. The coefficient of friction testing covered a wide variety of factors including stud, nut, and washer materials, sizes, manufacturing methods, surface coatings, surface finishes, applied loads, run-in cycles, and relubrication. Only one lubricant, Dow Corning Molykote P37, met all the criteria established for a replacement lubricant. It has a coefficient of friction range similar to RLGMO. Therefore, it can be substituted directly for RLGMO without changing the currently specified fastener torque values for the sizes, materials and conditions evaluated. Other lubricants did not perform as well as Molykote P37 in one or more test or evaluation categories.

  15. Antiwear performance and mechanism of an oil-miscible ionic liquid as a lubricant additive.

    Science.gov (United States)

    Qu, Jun; Bansal, Dinesh G; Yu, Bo; Howe, Jane Y; Luo, Huimin; Dai, Sheng; Li, Huaqing; Blau, Peter J; Bunting, Bruce G; Mordukhovich, Gregory; Smolenski, Donald J

    2012-02-01

    An ionic liquid (IL) trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate has been investigated as a potential antiwear lubricant additive. Unlike most other ILs that have very low solubility in nonpolar fluids, this IL is fully miscible with various hydrocarbon oils. In addition, it is thermally stable up to 347 °C, showed no corrosive attack to cast iron in an ambient environment, and has excellent wettability on solid surfaces (e.g., contact angle on cast iron lubricating oils. For example, a 5 wt % addition into a synthetic base oil eliminated the scuffing failure experienced in neat oil and, as a result, reduced the friction coefficient by 60% and the wear rate by 3 orders of magnitude. A synergistic effect on wear protection was observed with the current antiwear additive when added into a fully formulated engine oil. Nanostructure examination and composition analysis revealed a tribo-boundary film and subsurface plastic deformation zone for the metallic surface lubricated by the IL-containing lubricants. This protective boundary film is believed to be responsible for the IL's antiscuffing and antiwear functionality.

  16. Monitoring of the molecular structure of lubricant oil using a FT-Raman spectrometer prototype

    Science.gov (United States)

    Ortega Clavero, Valentin; Weber, Andreas; Schröder, Werner; Curticapean, Dan; Javahiraly, Nicolas; Meyrueis, Patrick

    2014-05-01

    The determination of the physical state of the lubricant materials in complex mechanical systems is highly critical from different points of view: operative, economical, environmental, etc. Furthermore, there are several parameters that a lubricant oil must meet for a proper performance inside a machine. The monitoring of these lubricants can represent a serious issue depending on the analytical approach applied. The molecular change of aging lubricant oils have been analyzed using an all-standard-components and self-designed FT-Raman spectrometer. This analytical tool allows the direct and clean study of the vibrational changes in the molecular structure of the oils without having direct contact with the samples and without extracting the sample from the machine in operation. The FT-Raman spectrometer prototype used in the analysis of the oil samples consist of a Michelson interferometer and a self-designed photon counter cooled down on a Peltier element arrangement. The light coupling has been accomplished by using a conventional 62.5/125μm multi-mode fiber coupler. The FT-Raman arrangement has been able to extract high resolution and frequency precise Raman spectra, comparable to those obtained with commercial FT-Raman systems, from the lubricant oil samples analyzed. The spectral information has helped to determine certain molecular changes in the initial phases of wearing of the oil samples. The proposed instrument prototype has no additional complex hardware components or costly software modules. The mechanical and thermal irregularities influencing the FT-Raman spectrometer have been removed mathematically by accurately evaluating the optical path difference of the Michelson interferometer. This has been achieved by producing an additional interference pattern signal with a λ= 632.8 nm helium-neon laser, which differs from the conventional zero-crossing sampling (also known as Connes advantage) commonly used by FT-devices. It enables the FT-Raman system to

  17. THE EFFECT OF ADDITIVE ON THE VISCOSITY INDEX OF LUBRICATING OIL (ENGINE OIL

    Directory of Open Access Journals (Sweden)

    ONYEJI,

    2011-03-01

    Full Text Available The effects of four different additive formulations namely 5748, 801, 264 and 261 on the viscosity index of two lubricating oils (base oils namely 150N and 500N at two temperatures 400C and 1000C wereinvestigated. The base oils were blended with the additives in three different proportions of 100/4. 100/8 and 100/12. The results gave a viscosity index of 96 and 98 respectively for 150N and 500N withoutadditives. On the other hand, the addition of 12g of 261 additive formulations to 100cm3 of both base oils gave about 180% increase in kinematic viscosity at 400C, about 161% increase and 146% increase at1000C for 150N and 500N respectively. About 60% in viscosity index was achieved by 100/12 blend of 261 additives in 150N. The results revealed that 261 additive formulations gave the highest increase inviscosity in all proportions increasing as the weight of the additive increases. Generally, all the four additive formulations used mproved the viscosities of all the blends in all the proportions and at both temperatures. The blends can be classified as very high viscosity index being above 110. This means that they will undergo very little change in viscosity with temperature extremes and so can be considered to have stable viscosity.

  18. 润滑油加氢装置反冲洗过滤器的改造应用%Improvement and Application of the Backwashing Filter in Lubricating Oil Hydrogenation Unit

    Institute of Scientific and Technical Information of China (English)

    田建军

    2013-01-01

    In order to ensure the smooth running of lubricating oil hydrogenation plant, and eliminate the negative effect of existing backwashing filter on filter elements, high pressure feed pump assembly, catalyst bed pressure drop, catalyst activity, catalyst life and so on during the manual flushing, the manual backwashing filter was replaced by automatic one. After the improvement, the backwashing frequency and backwashing slop oil quantity were greatly reduced, about 3 266 000 RMB per year can be directly saved. In addition, the existing manual backwashing filter was changed into the main products filter by slightly and artfully modifying the process, which can not only make full use of existing resources, but also eliminate the potential quality accident of main products caused by any impurities, particles and so on.%  某润滑油加氢厂为了确保生产平稳运行,消除现有反冲洗过滤器在手动冲洗时对其滤芯、高压进料泵组件、催化剂床层压降和催化剂活性及寿命等的负面影响,将手动反冲洗过滤器改造为自动反冲洗过滤器,从而大大降低了进料过滤器的反冲洗频率和反冲洗污油量及公用工程的消耗量,每年可直接节省费用约326.6万元。此外,将现有进料手动反冲洗过滤器转化为主产品重质润滑油基础油出装置过滤器,不仅合理利用了现有资源,而且消除了主产品重质润滑油基础油出装置时可能带有杂质、颗粒等造成产品质量事故的潜在隐患。

  19. Thermochemical recycling of mixture of scrap tyres and waste lubricating oil into high caloric value products

    Energy Technology Data Exchange (ETDEWEB)

    Abdul-Raouf, Manar E.; Maysour, Nermine E.; Abdul-Azim, Abdul-Azim A. [Egyptian Petroleum Research Institute, Nasr City, Cairo (Egypt); Amin, Mahasen S. [Faculty of Science, Benha University, Benha (Egypt)

    2010-06-15

    Scrap tyres and used lubricating oils represent together growing environmental problem because they are not biodegradable and their components cannot readily be recovered. In the present investigation, the thermochemical recycling of mixture of old tyres with waste lubricating oil by pyrolysis and the value of the products obtained have been studied. First, thermobalance experiments were carried out, studying the influence of the following variables: temperature, type of catalyst and catalyst concentration on the pyrolysis reaction of a mixture of 1/1 wt./wt. oil/tyre ratio. These thermobalance results were thoroughly investigated to study the effect of the main process variables on yields of derived products: oils, gases and solid residue. (author)

  20. On the application of reynolds theory to thermo-piezo-viscous lubrication in oil hydraulics

    DEFF Research Database (Denmark)

    Johansen, Per; Roemer, Daniel Beck; Andersen, Torben O.

    2015-01-01

    . In this paper the derivation of Reynolds equation from the continuum assumption is reviewed and it is shown that the validity of Reynolds theory based pressure field solutions in oil hydraulic thermo-piezo-viscous lubrication models are subject to maximum bounds on the pressure and temperature field gradients...

  1. Measurement of trace elements in lubricating oils by the PIXE method

    Energy Technology Data Exchange (ETDEWEB)

    Jaskola, M.; Kucharski, M.; Zemlo, L. (Institute of Nuclear Research, Warsaw (Poland)); Babinski, B. (Wojskowy Instytut Techniki Pancernej i Samochodowej, Warszawa (Poland))

    1981-01-01

    A beam of 2 to 2.5 MeV protons has been used to excite X-ray emission from a lubricating oil sample. The X-rays have been detected using a Si(Li) solid state detector. The experimental arrangement for the PIXE method is also described.

  2. Rheological and tribological behaviour of lubricating oils containing platelet MoS2 nanoparticles

    Science.gov (United States)

    Wan, Qingming; Jin, Yi; Sun, Pengcheng; Ding, Yulong

    2014-05-01

    This work concerns rheological and frictional behaviour of lubricating oils containing platelet molybdenum disulfide (MoS2) nanoparticles (average diameter 50 nm; single layer thickness 3 nm). Stable nano-MoS2 lubricants were formulated and measured for their rheological behaviour and tribological performance. Rheological experiments showed that the nano-MoS2 oils were non-Newtonian following the Bingham plastic fluid model. The viscosity data fitted the classic Hinch-Leal (H-L) model if an agglomeration factor of 1.72 was introduced. Tribological experiments indicated that the use of MoS2 nanoparticles could enhance significantly the tribological performance of the base lubricating oil (reduced frictional coefficient, reduced surface wear and increased stability). Scanning electron microscopy, laser confocal microscope and x-ray energy dispersive spectroscopy analyses suggested that the reduced frictional coefficient and surface wear be associated with surface patching effects. Such patching effects were shown to depend on the concentration of MoS2 nanoparticles, and an effective patching required a concentration over approximately 1 wt%. The increased stability could be attributed to the enhanced heat transfer and lubricating oil film strength due to the presence of nanoparticles.

  3. AUTOMOTIVE DIESEL MAINTENANCE 1. UNIT XXVI, I--CATERPILLAR LUBRICATION SYSTEMS AND COMPONENTS, II--LEARNING ABOUT BRAKES (PART I).

    Science.gov (United States)

    Minnesota State Dept. of Education, St. Paul. Div. of Vocational and Technical Education.

    THIS MODULE OF A 30-MODULE COURSE IS DESIGNED TO DEVELOP AN UNDERSTANDING OF THE FUNCTIONS OF DIESEL ENGINE LUBRICATION SYSTEMS AND COMPONENTS AND THE PRINCIPLES OF OPERATION OF BRAKE SYSTEMS USED ON DIESEL POWERED VEHICLES. TOPICS ARE (1) THE NEED FOR OIL, (2) SERVICE CLASSIFICATION OF OILS, (3) CATERPILLAR LUBRICATION SYSTEM COMPONENTS (4)…

  4. Food contamination by hydrocarbons from lubricating oils and release agents: determination by coupled LC-GC.

    Science.gov (United States)

    Grob, K; Artho, A; Biedermann, M; Egli, J

    1991-01-01

    We have found that many foods are contaminated with mineral oil products used as lubricating oils/greases or as release agents. The mineral oil base of such products usually consists of branched alkanes ranging between C17 and C35. It forms a broad 'hump' of unresolved compounds in the gas chromatogram. Examples of such products are described; contamination is shown for a sample of bread, bonbon, and chocolate, respectively. The results suggest that contamination of foodstuffs with mineral oils does not always receive the required attention. However, there is also a lack of guidelines.

  5. Rapid chelometric determination of lead in lubricating oils via mercaptoacetate extraction.

    Science.gov (United States)

    Banerjee, S; Dutta, R K

    1973-01-01

    A rapid complexometric method for the estimation of lead in lubricating oil has been developed. The lead naphthenate present in the oil is extracted with a mixture of dilute thioglycollic acid and nitric acid. The aqueous extract containing lead mercaptoacetate is titrated with EDTA at pH 5 with Xylenol Orange as indicator. The lead content can be determined within 15-20 min.

  6. The influence of temperature on the lubricating effectiveness of MoS2 dispersed in mineral oils

    Science.gov (United States)

    Rolek, R. J.; Cusano, C.; Sliney, H. E.

    1984-01-01

    The effects of oil viscosity, base oil temperature, and surface-active agents naturally present in mineral oils on the lubricating effectiveness of MoS2 dispersions under boundary lubrication conditions are investigated. Friction and wear data are obtained from tests conducted under a wide range of oil viscosities and operating temperatures. The dispersion temperature at which the friction dropped below that obtained with the base oils, depended upon the base oil viscosity and the concentration of surface-active agents present in the oil. White oils showed reductions in friction before mineral oils of like viscosity, and lower viscosity oils showed reductions in friction before heavier viscosity oils. The results show that for a given base oil, wear increases as temperature increases, while the wear obtained from a MoS2 dispersion made from the base oil remains approximately constant as temperature is increased.

  7. Palm oil derived trimethylolpropane triesters synthetic lubricants and usage in industrial metalworking fluid.

    Science.gov (United States)

    Chang, Teck-Sin; Yunus, Robiah; Rashid, Umer; Choong, Thomas S Y; Awang Biak, Dayang Radiah; Syam, Azhari M

    2015-01-01

    Trimethylolpropane triesters are biodegradable synthetic lubricant base oil alternative to mineral oils, polyalphaolefins and diesters. These oils can be produced from trimethylolpropane (TMP) and fatty acid methyl esters via chemical or enzymatic catalyzed synthesis methods. In the present study, a commercial palm oil derived winter grade biodiesel (ME18) was evaluated as a viable and sustainable methyl ester source for the synthesis of high oleic trimethylolpropane triesters (HO-TMPTE). ME18 has fatty acid profile containing 86.8% oleic acid, 8.7% linoleic acid with the remaining minor concentration of palmitic acid, stearic acid and linolenic acid. It's high oleic property makes it superior to produce synthetic lubricant base oil that fulfills both the good low temperature property as well as good oxidative stability. The synthetic base oil produced had a viscosity of 44.3 mm(2)/s at 40°C meeting the needs for ISO 46 oils. It also exhibited an excellent viscosity index of 219 that is higher than some other commercial brands of trimethylolpropane trioleate. Properties of base oil such as cloud point, density, acid value, demulsibility and soap content were also examined. The oil was then used in the formulation of tapping oil and appraised in term of adaptability, stability and field test performance.

  8. Phytotreatment of soil contaminated with used lubricating oil using Hibiscus cannabinus.

    Science.gov (United States)

    Abioye, O P; Agamuthu, P; Abdul Aziz, A R

    2012-04-01

    Soil contamination by hydrocarbons, especially by used lubricating oil, is a growing problem in developing countries, which poses a serious threat to the environment. Phytoremediation of these contaminated soils offers environmental friendly and a cost effective method for their remediation. Hibiscus cannabinus was studied for the remediation of soil contaminated with 2.5 and 1% used lubricating oil and treated with organic wastes [banana skin (BS), brewery spent grain (BSG) and spent mushroom compost (SMC)] for a period of 90 days under natural conditions. Loss of 86.4 and 91.8% used lubricating oil was recorded in soil contaminated with 2.5 and 1% oil and treated with organic wastes respectively at the end of 90 days. However, 52.5 and 58.9% oil loss was recorded in unamended soil contaminated with 2.5 and 1% oil, respectively. The plant did not accumulate hydrocarbon from the soil but shows appreciable accumulation of Fe and Zn in the root and stem of H. cannabinus at the end of the experiment. The first order kinetic rate of uptake of Fe and Zn in H. cannabinus was higher in organic wastes amendment treatments compared to the unamended treatments, which are extremely low. The results of this study suggest that H. cannabinus has a high potential for remediation of hydrocarbon and heavy metal contaminated soil.

  9. Grease versus Oil Lubrication of Wheel Bearings in Army Equipment.

    Science.gov (United States)

    1984-01-01

    and David A. Brown 9. PERFORMING ORGANIZATION NAME AND ADDRESS 10. PROGRAM ELEMENT, PROJECT, TASK Fuels and Lubricants Div, STRBE-VF; Materials, Fuels...I Commander-. M60 Tank Development US Army Troop Support Command US Army Tank-Automotive Command ATTN: DRSTS-M Bradely Fighting Vehicle Systems 4300...Mr. Layne) Program Planning, STRBE-HP Washington, DC 20362 Program Support, STRBE-HR Systems Analysis, STRBE-HA 2 Commander CIRCULATE David Taylor

  10. Analysis of lubrication properties of zinc-dialkyl-dithio-phosphate (ZDDP) additive on Karanja oil (Pongamia pinnatta) as a green lubricant

    OpenAIRE

    Krishnanunni P., Mohammed Rafeekh P.

    2014-01-01

    Environmental pollution is a major concern when petroleum based lubricants are used in industries [1]. The effluents produced and their subsequent disposal cause severe environmental hazards especially in the hydraulic, mining, agriculture and petrochemical industries. The mineral based oils cannot be used in food industry because of their toxic nature [2]. Vegetable oils with high oleic acid content are the preferred substitute for mineral oils in industries

  11. Intermetallic Nickel-Titanium Alloys for Oil-Lubricated Bearing Applications

    Science.gov (United States)

    DellaCorte, C.; Pepper, S. V.; Noebe, R.; Hull, D. R.; Glennon, G.

    2009-01-01

    An intermetallic nickel-titanium alloy, NITINOL 60 (60NiTi), containing 60 wt% nickel and 40 wt% titanium, is shown to be a promising candidate material for oil-lubricated rolling and sliding contact applications such as bearings and gears. NiTi alloys are well known and normally exploited for their shape memory behavior. When properly processed, however, NITINOL 60 exhibits excellent dimensional stability and useful structural properties. Processed via high temperature, high-pressure powder metallurgy techniques or other means, NITINOL 60 offers a broad combination of physical properties that make it unique among bearing materials. NITINOL 60 is hard, electrically conductive, highly corrosion resistant, less dense than steel, readily machined prior to final heat treatment, nongalling and nonmagnetic. No other bearing alloy, metallic or ceramic encompasses all of these attributes. Further, NITINOL 60 has shown remarkable tribological performance when compared to other aerospace bearing alloys under oil-lubricated conditions. Spiral orbit tribometer (SOT) tests were conducted in vacuum using NITINOL 60 balls loaded between rotating 440C stainless steel disks, lubricated with synthetic hydrocarbon oil. Under conditions considered representative of precision bearings, the performance (life and friction) equaled or exceeded that observed with silicon nitride or titanium carbide coated 440C bearing balls. Based upon this preliminary data, it appears that NITINOL 60, despite its high titanium content, is a promising candidate alloy for advanced mechanical systems requiring superior and intrinsic corrosion resistance, electrical conductivity and nonmagnetic behavior under lubricated contacting conditions.

  12. Synthesis of lubrication fluids and surfactant precursors from soybean oil

    Science.gov (United States)

    Starting with soybean oil or soybean oil derived methyl oleate, a variety of compounds have been synthesized. The epoxidation of oleochemicals is a simple way to use the unsaturation naturally available in the vegetable oil and convert it into a variety of other useful chemicals. Epoxidized methyl...

  13. Inverse gas chromatographic study of the oxidation stability of lubricating base oils via solubility parameter calculations.

    Science.gov (United States)

    Moustafa, Nagy Emam; Eissa, Elham Ahmed

    2007-11-01

    The Flory-Huggins interaction parameter (chi1, 2(infinity)) and solubility parameter (delta2) and its hydrogen bonding sensing component (delta(h)) were determined using inverse gas chromatography (IGC). These parameters were successfully used in the probes of chemical changes that occur during the oxidation of naphthenic and paraffinic base oils in a GC column. Changes in chi1, 2(infinity) values reflect the different types of intermolecular interactions (dispersive, polar, hydrogen bonding) of the given lubricating base oil during oxidation. The obtained results showed that delta(h) component of solubility parameter is the most important parameter for probing the oxidative-chemical changes during the oxidation of given lubricating oils.

  14. Influence of Base Oil Polarity on the Transient Shear Flow of Biodegradable Lubricating Greases

    Directory of Open Access Journals (Sweden)

    Martin Fiedler

    2015-09-01

    Full Text Available The scope of this study is to elucidate the physical mechanisms influencing the transient flow behavior of lubricating greases based on biogenic oleochemicals from a polarity point of view. This includes the mutually interacting influence of base oil polarity and thickening agents on the rheologically-measured mechanical structural degradation in transient shear flow. Due to the high temperature dependence of Keesom forces in the background of polar-active bond mechanisms, the analysis of the transient flow response as a function of temperature allows to attribute the observed influences to differences in base oil polarity. In general, clay-thickened greases show a greater tendency to be rheologically influenced by base oil polarities than soap-thickened lubricating greases.

  15. The ongoing changes in the base oil industry and their potential impact on the lubricant industry

    Energy Technology Data Exchange (ETDEWEB)

    Serra-Holm, Valentina [Nynas AB, Stockholm (Sweden)

    2013-06-15

    During the last years the base oil industry has undergone significant changes, with the rapid growth of Group II and Group III paraffinic base oils and the corresponding decline of Group I supply. The announcements of future instalments show that the increase of Group II and III capacity is indeed a stable trend all over the world. Based on publicly available information, the Group II capacity is expected to grow by 8.6 million tpa, reaching over 22 million tpa, and Group III capacity is expected to double from current 4.1 million tpa up to 8.2 million tpa. As the demand is not expected to grow at the same pace as the increasing supply, it is likely that this new capacity will lead to an oversupply situation in the next five years. Because of their production disadvantages compared to Group II and III and a shrinking demand in automotive applications, it is likely that Group I plants will close down or will operate at reduced throughput to compensate for the new Group II and III capacity. A decline of Group I capacity in favour of Group II and III may pose problems in the formulation of those industrial lubricants where solvency and/or viscosity are needed, such as lubricating greases, metalworking fluids, and several process oils applications. Either alone or in combination with Group II or III oils, naphthenic oils can be used in the formulation of industrial lubricants, as solvency and viscosity poroviders. (orig.)

  16. Tribological characteristics of monodispersed cerium borate nanospheres in biodegradable rapeseed oil lubricant

    Science.gov (United States)

    Boshui, Chen; Kecheng, Gu; Jianhua, Fang; Jiang, Wu; Jiu, Wang; Nan, Zhang

    2015-10-01

    Stearic acid-capped cerium borate composite nanoparticles, abbreviated as SA/CeBO3, were prepared by hydrothermal method. The morphologies, element compositions, size distributions, crystal and chemical structures, hydrophobic characteristics, of SA/CeBO3 were characterized by scanning electron microscope, energy dispersive X-ray spectrometer, dynamic laser particle size analyzer, X-ray diffraction, and Fourier transform infrared spectrometer, respectively. The friction and wear performances of SA/CeBO3 as a lubricating additive in a rapeseed oil were evaluated on a four-ball tribo-tester. The tribochemical characteristics of the worn surfaces were investigated by X-ray photoelectron spectroscopy. The results showed that the hydrophobic SA/CeBO3 were monodispersed nanospheres with an average diameter of 8 nm, and exhibited excellent dispersing stability in rapeseed oil. Meanwhile, SA/CeBO3 nanospheres were outstanding in enhancing friction-reducing and anti-wear capacities of rapeseed oil. The prominent tribological performances of SA/CeBO3 in rapeseed oil were attributed to the formation of a composite boundary lubrication film mainly composed of lubricous tribochemical species of B2O3, CeO2 and Fe2O3, and the adsorbates of SA/CeBO3 and rapeseed oil, on the tribo-surfaces.

  17. On the performance of laser-induced breakdown spectroscopy for direct determination of trace metals in lubricating oils

    Science.gov (United States)

    Zheng, Lijuan; Cao, Fan; Xiu, Junshan; Bai, Xueshi; Motto-Ros, Vincent; Gilon, Nicole; Zeng, Heping; Yu, Jin

    2014-09-01

    Laser-induced breakdown spectroscopy (LIBS) provides a technique to directly determine metals in viscous liquids and especially in lubricating oils. A specific laser ablation configuration of a thin layer of oil applied on the surface of a pure aluminum target was used to evaluate the analytical figures of merit of LIBS for elemental analysis of lubricating oils. Among the analyzed oils, there were a certified 75cSt blank mineral oil, 8 virgin lubricating oils (synthetic, semi-synthetic, or mineral and of 2 different manufacturers), 5 used oils (corresponding to 5 among the 8 virgin oils), and a cooking oil. The certified blank oil and 4 virgin lubricating oils were spiked with metallo-organic standards to obtain laboratory reference samples with different oil matrix. We first established calibration curves for 3 elements, Fe, Cr, Ni, with the 5 sets of laboratory reference samples in order to evaluate the matrix effect by the comparison among the different oils. Our results show that generalized calibration curves can be built for the 3 analyzed elements by merging the measured line intensities of the 5 sets of spiked oil samples. Such merged calibration curves with good correlation of the merged data are only possible if no significant matrix effect affects the measurements of the different oils. In the second step, we spiked the remaining 4 virgin oils and the cooking oils with Fe, Cr and Ni. The accuracy and the precision of the concentration determination in these prepared oils were then evaluated using the generalized calibration curves. The concentrations of metallic elements in the 5 used lubricating oils were finally determined.

  18. Deep drawing of 304 L Steel Sheet using Vegetable oils as Forming Lubricants

    Science.gov (United States)

    Shashidhara, Y. M.; Jayaram, S. R.

    2012-12-01

    The study involves the evaluation of deep drawing process using two non edible oils, Pongam (Pongammia pinnata) and Jatropha (Jatropha carcass) as metal forming lubricants. Experiments are conducted on 304L steel sheets under the raw and modified oils with suitable punch and die on a hydraulic press of 200 ton capacity. The punch load, draw-in-length and wall thickness distribution for deep drawn cups are observed. The drawn cups are scanned using laser scanning technique and 3D models are generated using modeling package. The wall thickness profiles of cups at different sections (or height) are measured using CAD package. Among the two raw oils, the drawn cups under Jatropha oil, have uniform wall thickness profile compared to Pongam oil. Uneven flow of material and cup rupturing is observed under methyl esters of Pongam and Jatropha oil lubricated conditions. However, the results are observed under epoxidised Jatropha oil with uniform metal flow and wall thicknesses compared to mineral and other versions of vegetable oils.

  19. Analysis of chain saw lubricating oils commonly used in Thailand's southern border provinces for forensic science purpose.

    Science.gov (United States)

    Choodum, Aree; Tripuwanard, Kijja; Daeid, Niamh Nic

    2014-08-01

    In recent years, Thailand's southern border provinces (Malay-Muslim-majority border provinces) have become the scene of violence and insurgency. One of the attack patterns is the blocking of roads with perennial plants followed by planned attacks using improvised explosive devices (IEDs) or weapons on first responders. Containers of viscous dark lubricating oil and traces of lubricants on the felled trees were usually found at the scene. These were suspected to be chain oil lubricant from the chainsaws used to cut down the trees used for the roadblock. This work aimed to differentiate the chromatographic patterns of used lubricating oils available in automobile repair shops from various locations across Thailand's southern border provinces. Lubricating oils were analyzed using gas chromatography/flame ionization detector (GC/FID) every two weeks to study their variation in chemical compositions over time. The results obtained from GC/FID were normalized for differentiation. This included four two-stroke, six four-stroke, and three recycled oils. Two lubricating oils found at an incident scene were also analyzed and the results compared with the chain oil from five seized chainsaws.

  20. Tribological Properties of Few-layer Graphene Oxide Sheets as Oil-Based Lubricant Additives

    Institute of Scientific and Technical Information of China (English)

    CHEN Zhe; LIU Yuhong; LUO Jianbin

    2016-01-01

    The performance of a lubricant largely depends on the additives it involves. However, currently used additives cause severe pollution if they are burned and exhausted. Therefore, it is necessary to develop a new generation of green additives. Graphene oxide (GO) consists of only C, H and O and thus is considered to be environmentally friendly. So the tribological properties of the few-layer GO sheet as an additive in hydrocarbon base oil are investigated systematically. It is found that, with the addition of GO sheets, both the coefficient of friction (COF) and wear are decreased and the working temperature range of the lubricant is expanded in the positive direction. Moreover, GO sheets has better performance under higher sliding speed and the optimized concentration of GO sheets is determined to be 0.5wt%. After rubbing, GO is detected on the wear scars through Raman spectroscopy. And it is believed that, during the rubbing, GO sheets adhere to the sliding surfaces, behaving like protective films and preventing the sliding surfaces from contacting with each other directly. This paper proves that the GO sheet is an effective lubricant additive, illuminates the lubrication mechanism, and provides some critical parameters for the practical application of GO sheets in lubrication.

  1. Tribological properties of few-layer graphene oxide sheets as oil-based lubricant additives

    Science.gov (United States)

    Chen, Zhe; Liu, Yuhong; Luo, Jianbin

    2016-03-01

    The performance of a lubricant largely depends on the additives it involves. However, currently used additives cause severe pollution if they are burned and exhausted. Therefore, it is necessary to develop a new generation of green additives. Graphene oxide (GO) consists of only C, H and O and thus is considered to be environmentally friendly. So the tribological properties of the few-layer GO sheet as an additive in hydrocarbon base oil are investigated systematically. It is found that, with the addition of GO sheets, both the coefficient of friction (COF) and wear are decreased and the working temperature range of the lubricant is expanded in the positive direction. Moreover, GO sheets has better performance under higher sliding speed and the optimized concentration of GO sheets is determined to be 0.5wt%. After rubbing, GO is detected on the wear scars through Raman spectroscopy. And it is believed that, during the rubbing, GO sheets adhere to the sliding surfaces, behaving like protective films and preventing the sliding surfaces from contacting with each other directly. This paper proves that the GO sheet is an effective lubricant additive, illuminates the lubrication mechanism, and provides some critical parameters for the practical application of GO sheets in lubrication.

  2. Lubricants based on renewable resources--an environmentally compatible alternative to mineral oil products.

    Science.gov (United States)

    Willing, A

    2001-04-01

    The development of lubricants like, e.g. engine and hydraulic oils was traditionally based on mineral oil as a base fluid. This fact is related to the good technical properties and the reasonable price of mineral oils. The Report to the Club of Rome (W.W. Behrens III, D.H. Meadows, D.I. Meadows, J. Randers, The limits of growth, A Report to the Club of Rome, 1972) and the two oil crises of 1979 and 1983, however, elucidated that mineral oil is on principle a limited resource. In addition, environmental problems associated with the production and use of chemicals and the limited capacity of nature to tolerate pollution became obvious (G.H. Brundtland, et al., in: Hauff, Volker (Ed.), World Commission on Environment and Development (WCED), Report of the Brundtland-Commission, Oxford, UK, 1987), and the critical discussion included besides acid rain, smog, heavy metals, and pesticides also mineral oil (especially oil spills like the case Exxon Valdes). A disadvantage of mineral oil is its poor biodegradability and thus its potential for long-term pollution of the environment. From the early development of lubricants for special applications (e.g. turbojet engine oils) it was known, that fatty acid polyol esters have comparable or even better technical properties than mineral oil. Subsequently, innumerable synthetic esters have been synthesized by systematic variation of the fatty acid and the alcohol components. Whereas the alcohol moiety of the synthetic esters are usually of petrochemical origin, the fatty acids are almost exclusively based on renewable resources. The physico-chemical properties of oleochemical esters can cover the complete spectrum of technical requirements for the development of high-performance industrial oils and lubricants (e.g. excellent lubricating properties, good heat stability, high viscosity index, low volatility and superior shear stability). For a comprehensive review of their technical properties see F. Bongardt, in: Jahrbuchf

  3. The Overcoat Oil Lubrication of Microarc Oxidation Coating on Al Alloy by Liquid Plasma Technique

    Institute of Scientific and Technical Information of China (English)

    LUO Zhuang-zi; ZHANG Zhao-zhu; LIU Wei-ming; WANG Wen-jing; TIAN Jun

    2004-01-01

    Ceramic coatings were deposited on 2Al2 alloy with a 100 kW micro-arc oxidation equipment consisting of a potential adjustable ac power supply and alkali electrolyte. The structure of the micro-arc oxidiation coatings was examined using scanning electron microscopy and transmission electron microscopy. The tribological properties of the coatings sliding against steel under the drop and adsorption lubrication of liquid paraffin were evaluated with a Timken tester. The lower friction coefficient of 0.14 and longer wear life of 2450 m of overcoat were observed for the polished micro-arc oxidation coating of 180μm thick at a sliding speed 2. 50 m/s and load 1500 N. This is because the coating has an interlayer of suitable porosity and thickness, which helps to improve the deposition of lubricants and endure the higher load. In other words, the oil is able to adsorb in the porous holes of the overcoat and provided the lubrication of micro reservoir during friction, and the compact and relatively hard interlayer of oxidation coating is able to support heavy load and prevent the oil lubricating film from damage.

  4. Collaborative Lubricating Oil Study on Emissions: November 28, 2006 - March 31, 2011

    Energy Technology Data Exchange (ETDEWEB)

    Carroll, J. N.; Khalek, I. A.; Smith, L. R.; Fujita, E.; Zielinska, B.

    2011-10-01

    The Collaborative Lubricating Oil Study on Emissions (CLOSE) project was a pilot investigation of how fuels and crankcase lubricants contribute to the formation of particulate matter (PM) and semi-volatile organic compounds (SVOC) in vehicle exhaust. As limited vehicles were tested, results are not representative of the whole on-road fleet. Long-term effects were not investigated. Pairs of vehicles (one normal PM emitting, one high-PM emitting) from four categories were selected: light-duty (LD) gasoline cars, medium-duty (MD) diesel trucks, heavy-duty (HD) natural-gas-fueled buses, and HD diesel buses. HD vehicles procured did not exhibit higher PM emissions, and thus were labeled high mileage (HM). Fuels evaluated were non-ethanol gasoline (E0), 10 percent ethanol (E10), conventional low-sulfur TxLED diesel, 20% biodiesel (B20), and natural gas. Temperature effects (20 degrees F, 72 degrees F) were evaluated on LD and MD vehicles. Lubricating oil vintage effects (fresh and aged) were evaluated on all vehicles. LD and MD vehicles were operated on a dynamometer over the California Unified Driving Cycle, while HD vehicles followed the Heavy Duty Urban Dynamometer Driving Schedule. Regulated and unregulated emissions were measured. Chemical markers from the unregulated emissions measurements and a tracer were utilized to estimate the lubricant contribution to PM.

  5. Absorption of water and lubricating oils into porous nylon

    Science.gov (United States)

    Bertrand, P. A.

    1995-01-01

    Oil and water absorption from air into sintered porous nylon can be described by infiltration into the pores of the material. This process can be modeled by a diffusion-like mechanism. For water absorption, we find a formal diffusion coefficient of 1.5 x 10(exp -4)sq cm/min when the nylon is initially dry. The diffusion coefficient is 4 x 10(exp -6)sq cm/min when the nylon is oil-impregnated prior to air exposure. In a 52% RH atmosphere, dry nylon absorbs 3% w/w water, and oil-impregnated nylon absorbs 0.6% w/w water. For oil absorption there are three steps: (1) surface absorption and infiltration into (2) larger and (3) smaller pores. Surface absorption is too fast to be measured in these experiments. The diffusion coefficient for the second step is 6 x 10(exp -4)sq cm/min for SRG-60 oil into dry nylon and 4 x 10(exp -4)sq cm/min for air-equilibrated nylon. The diffusion coefficient for the third step is about 1 x 10(exp -6)sq cm/min for both cases. The total amount of oil absorbed is 31% w/w. The interaction between water and nylon is not as strong as that between water and cotton-phenolic: oil can replace water, and only a small amount of water can enter previously oil-impregnated nylon.

  6. Optofluidic multi-measurement system for the online monitoring of lubricant oil

    Science.gov (United States)

    Verschooten, Tom; Callewaert, Manly; Ciaccheri, Leonardo; Vervaeke, Michael; Van Erps, Jürgen; De Malsche, Wim; Grazia Mignani, Anna; Thienpont, Hugo; Ottevaere, Heidi

    2016-01-01

    We show a detection system that simultaneously allows absorbance (ABS), laser-induced fluorescence (LIF) and scattering detection excited by two different laser sources at 405 nm and 450 nm. The heart of the system consists of a mass manufacturable polymer optofluidic chip. The chip is mounted in an optical detection assembly that aligns the chip to the rest of the system, seals the chip from leakage, fixes the position and connects the channels to the rest of the fluidic system. The fluidics exhibit a reduced susceptibility to perturbations caused by air bubbles, this is accomplished by making use of a serpentine channel layout. For coumarin 480, detection limits of 100 nM and 10 pM are observed for ABS and LIF respectively. An effective detection range of 4000 down to 1 nephelometric turbidity units is shown for the detection of scattered light. The viscous behaviour of the sample is analysed by a secondary FFT processing step of which the result is further processed by multivariate data analysis. This allows the identification of samples and prediction of their quality parameters. We apply this system for the monitoring of lubricant oil, demonstrating its ability to compete with spectroscopic detection techniques. The low-cost approach and multi-measurement architecture shown in this paper pave the way for miniaturized on-line monitoring of liquids in an industrial environment.

  7. Study on Self-Repairing Performance of Mineral Powder Lubrication Oil Additive to Engine

    Institute of Scientific and Technical Information of China (English)

    GUO Yan-bao; XU Bin-shi; XU Yi

    2004-01-01

    By means of the engine shelf test, the gas escape amount of bent axle box was measured before and after adding hydroxyl silicate mineral powder lubrication oil additives, and discovered that gas escape amount after self-repaired is obviously smaller than before, the average gas escape amount of each rotate speed descend 6.5 %. Watching friction surface with SEM, discovered that the part of net veins in the cylinder inner surface are smoothly patched. Analysis with energy spectroscopy, discovered that there are some changing of atom component. Proofed that through rub chemical reaction, hydroxyl silicate mineral powder lubrication oil additives can generate new substance layer on friction surface, and can increase cylinder inner surface bulk, thereby get the repaired effects.

  8. Determination of N-methylpyrrolidone in lubricating oil samples by g. c

    Energy Technology Data Exchange (ETDEWEB)

    Bhagat, S.D.; Aswal, D.S.; Badoni, R.P.

    1989-06-01

    A rapid gas chromatographic procedure has been developed for quantitative estimation of N-methyl-2-pyrrolidone (NMP) in extract and raffinate phases of lubricating oil extraction processes. Column backflush technique or lubricating oil trap devices were the two approaches used to avoid the interference of lube hydrocarbons with the normal analysis of NMP. The proposed method is based on an internal standardization technique applying tetralin as a reference compound. NMP content was determined from the calibration curve drawn with known weight ratios of NMP and tetralin against the corresponding area ratios. Carbowax 20 M was found to be the best analytical column for separation and quantitation work, whereas a non-polar phase OV-101 was used as lube retainer. FID and TCD systems were employed to cover a wide concentration range from traces to high percentages of NMP. 8 refs., 2 figs., 2 tabs.

  9. Investigations on Oil Flow Rates Projected on the Casing Walls by Splashed Lubricated Gears

    Directory of Open Access Journals (Sweden)

    G. Leprince

    2012-01-01

    Full Text Available In order to investigate the oil projected by gears rotating in an oil bath, a test rig has been set up in which the quantity of lubricant splashed at several locations on the casing walls can be measured. An oblong-shaped window of variable size is connected to a tank for flow measurements, and the system can be placed at several locations. A series of formulae have been deduced using dimensional analysis which can predict the lubricant flow rate generated by one spur gear or one disk at various places on the casing. These results have been experimentally validated over a wide range of operating conditions (rotational speed, geometry, immersion depth, etc..

  10. High oleic sunflower oil as a gear lubricant

    OpenAIRE

    Vižintin, Jože; Kržan, Boris

    2015-01-01

    A formulated high oleic sunflower oil was investigated with respect to their expected performance in gear boxes in comparison to a typical mineral oil. Investigations of scuffing load capacity, pitting resistance and low-speed high-load wear resistance were performed by using the FZG gear test rig. In addition of standardized tests, new formulated ISO VG 46 oil was tested in a spur gear test rig. A set of spur gears was rotated at a specified load for 1,000 hours. The physical and chemical pr...

  11. Predictive Maintenance of Hydraulic Lifts through Lubricating Oil Analysis

    Directory of Open Access Journals (Sweden)

    Stamatios S. Kalligeros

    2013-12-01

    Full Text Available This article examines the possibility of measuring lift maintenance through analysis of used hydraulic oil. Hydraulic oils have proved to be a reliable indicator for the maintenance performed on elevators. It has also been proved that the end users or the maintenance personnel do not always conform to the instructions of the elevators’ hydraulic machine manufacturer. Furthermore, by examining the proportion of the metals, an estimation of the corrosion and the wear resistance of the joined moving parts can be observed. Additionally, the presence of chlorine and calcium in hydraulic oils demonstrates their function in a highly corrosive environment.

  12. Synthesis of a high-grade lubricant from sunflower oil methyl esters

    Directory of Open Access Journals (Sweden)

    Hillion Gérard

    2003-09-01

    Full Text Available This paper presents the synthesis of saturated branched fatty acid methyl esters by codimerization of ethylene with conjugated linoleic methyl esters from sunflower oil. The catalytic system used is composed of iron, diimine and a reducing agent. This four-step synthesis will be discussed. After a last step of transesterification with TMP (trimethylolpropane a lubricant with interesting characteristics (in particular a high thermal stability and a good cold behavior is obtained

  13. n-alkane profiles of engine lubricating oil and particulate matter by molecular sieve extraction.

    Science.gov (United States)

    Caravaggio, Gianni A; Charland, Jean-Pierre; Macdonald, Penny; Graham, Lisa

    2007-05-15

    As part of the Canadian Atmospheric Fine Particle Research Program to obtain reliable primary source emission profiles, a molecular sieve method was developed to reliably determine n-alkanes in lubricating oils, vehicle emissions, and mobile source dominated ambient particulate matter (PM). This work was also initiated to better calculate carbon preference index values (CPI: the ratio of the sums of odd over even n-alkanes), a parameter for estimating anthropogenic versus biogenic contributions in PM. n-Alkanes in lubricating oil and mobile source dominated PM are difficult to identify and quantify by gas chromatography due to the presence of similar components that cannot be fully resolved. This results in a hump, the unresolved complex mixture (UCM) that leads to incorrect n-alkane concentrations and CPI values. The sieve method yielded better chromatography, unambiguous identification of n-alkanes and allowed examination of differences between n-alkane profiles in light (LDV) and heavy duty vehicle (HDV) lubricating oils that would have been otherwise difficult. These profile differences made it possible to relate the LDV profile to that of the PM samples collected during a tunnel study in August 2001 near Vancouver (British Columbia, Canada). The n-alkane PM data revealed that longer sampling times result in a negative artifact, i.e., the desorption of the more volatile n-alkanes from the filters. Furthermore, the sieve procedure yielded n-alkane data that allowed calculation of accurate CPI values for lubricating oils and PM samples. Finally, this method may prove helpful in estimating the respective diesel and gasoline contributions to ambient PM.

  14. A proposed measurement method for void fraction in lubricant oil based on the image processing technique.

    Science.gov (United States)

    Wang, Jianwen; An, Qi

    2008-02-01

    A new method for measuring void fraction in lubricating oils is presented based on the image processing technique. The problem here differs from the bubbles detection problem in two-phase fluids in that our interest lies in the gross amount of gas voids in oils. Our method is based on an observation that gas voids in oils change the color of the mixed gas-oil material. Therefore, a measurement technique was established based on the change in color. In particular, the relationship between the change in color and amount of voids was established experimentally. The experiment and testing were performed on a particular setup which consists of a pipe, oil, and air. The test result has shown that this method is effective. The method is the simplest and most accurate one among the existing methods.

  15. WEAR TESTS OF SLIDING SURFACES IN THE ENVIRONMENT OF MIXTURES OF LUBRICATING OILS AND REFRIGERANTS

    Directory of Open Access Journals (Sweden)

    Kasper Górny

    2014-03-01

    Full Text Available Elements of refrigeration compressors may be exposed to various types of wear processes, depending on the used oils and refrigerants. The presence of the refrigerant makes the lubricating properties and anti-oil mixture - factor much worse than in case of the lack of refrigerant oil. Current regulations on the use of ODS phase-out of working require refrigeration synthetic refrigerants HCFC (e.g. popular R22. The paper presents the effect of different mixtures of oils and refrigerants on friction coefficient and surface condition of cast iron and aluminium PA6. Tests were performed on a prototype machine using frictional node type block-on-ring, which is located inside a pressure chamber that simulates the refrigeration compressor. The results of the study confirm the possibility of using green refrigerant R290 (propane as a substitute for R22, while keeping the existing mineral oil.

  16. Bismuth nanoparticles synthesized by laser ablation in lubricant oils for tribological tests

    Energy Technology Data Exchange (ETDEWEB)

    Flores-Castañeda, M., E-mail: mar.floc@hotmail.com [Universidad Autónoma del Estado de México, Av. Instituto Literario No. 100, Oriente Col. Centro, Toluca, Estado de México C.P. 50000, México (Mexico); Instituto Nacional de Investigaciones Nucleares, Carretera México-Toluca s/n, La Marquesa, Ocoyoacac, Edo. de México C.P. 52750, México (Mexico); Camps, E. [Instituto Nacional de Investigaciones Nucleares, Carretera México-Toluca s/n, La Marquesa, Ocoyoacac, Edo. de México C.P. 52750, México (Mexico); Camacho-López, M. [Universidad Autónoma del Estado de México, Av. Instituto Literario No. 100, Oriente Col. Centro, Toluca, Estado de México C.P. 50000, México (Mexico); Muhl, S. [Instituto de Investigación en Materiales (UNAM), Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510 México, D.F., México (Mexico); and others

    2015-09-15

    Highlights: • Bismuth nanoparticles have been obtained by laser ablation of solids in liquids. • The technique allows controlling the size and concentration of the samples. • Bi np’s in base oils can improve the tribological characteristics of the lubricant. - Abstract: The improvement of the tribological properties of mineral base oils through the addition of bismuth nanoparticles as an additive, together with the idea of obtaining lubricants free of heavy metals, was evaluated. Bismuth nanoparticles were produced directly in the heavy and light viscosity mineral base oils (BS900 and BS6500) using the technique of laser ablation of solids immersed in liquids. Transmission electron microscopy measurements showed the presence of pure bismuth nanoparticles. Small Angle X-ray Scattering (SAXS) measurements showed that the average size of the nanoparticles was between 7 and 65 nm depending on the experimental conditions used. The tribological properties of the base oil with the bismuth nanoparticles additives were evaluated using a four-ball tester. Tests were performed using the base oil with and without Bi nanoparticles. It was observed that the coefficient of friction of the oil decrease with an increasing concentration of the nanoparticles. The results also showed that the wear rate was reduced when the Bi nanoparticle additives were used.

  17. Predictive Maintenance of Hydraulic Lifts through Lubricating Oil Analysis

    OpenAIRE

    Stamatios S. Kalligeros

    2013-01-01

    This article examines the possibility of measuring lift maintenance through analysis of used hydraulic oil. Hydraulic oils have proved to be a reliable indicator for the maintenance performed on elevators. It has also been proved that the end users or the maintenance personnel do not always conform to the instructions of the elevators’ hydraulic machine manufacturer. Furthermore, by examining the proportion of the metals, an estimation of the corrosion and the wear resistance of the joined mo...

  18. Effects of syringe material and silicone oil lubrication on the stability of pharmaceutical proteins.

    Science.gov (United States)

    Krayukhina, Elena; Tsumoto, Kouhei; Uchiyama, Susumu; Fukui, Kiichi

    2015-02-01

    Currently, polymer-based prefillable syringes are being promoted to the pharmaceutical market because they provide an increased break resistance relative to traditionally used glass syringes. Despite this significant advantage, the possibility that barrel material can affect the oligomeric state of the protein drug exists. The present study was designed to compare the effect of different syringe materials and silicone oil lubrication on the protein aggregation. The stability of a recombinant fusion protein, abatacept (Orencia), and a fully human recombinant immunoglobulin G1, adalimumab (Humira), was assessed in silicone oil-free (SOF) and silicone oil-lubricated 1-mL glass syringes and polymer-based syringes in accelerated stress study. Samples were subjected to agitation stress, and soluble aggregate levels were evaluated by size-exclusion chromatography and verified with analytical ultracentrifugation. In accordance with current regulatory expectations, the amounts of subvisible particles resulting from agitation stress were estimated using resonant mass measurement and dynamic flow-imaging analyses. The amount of aggregated protein and particle counts were similar between unlubricated polymer-based and glass syringes. The most significant protein loss was observed for lubricated glass syringes. These results suggest that newly developed SOF polymer-based syringes are capable of providing biopharmaceuticals with enhanced physical stability upon shipping and handling.

  19. Characteristics of gas and residues produced from electric arc pyrolysis of waste lubricating oil.

    Science.gov (United States)

    Song, Geum-Ju; Seo, Yong-Chil; Pudasainee, Deepak; Kim, In-Tae

    2010-07-01

    An attempt has been made to recover high-calorific fuel gas and useful carbonaceous residue by the electric arc pyrolysis of waste lubricating oil. The characteristics of gas and residues produced from electric arc pyrolysis of waste lubricating oil were investigated in this study. The produced gas was mainly composed of hydrogen (35-40%), acetylene (13-20%), ethylene (3-4%) and other hydrocarbons, whereas the concentration of CO was very low. Calorific values of gas ranged from 11,000 to 13,000 kcal kg(-1) and the concentrations of toxic gases, such as NO(x), HCl and HF, were below the regulatory emissions limit. Gas chromatography-mass spectrometry (GC/MS) analysis of liquid-phase residues showed that high molecular-weight hydrocarbons in waste lubricating oil were pyrolyzed into low molecular-weight hydrocarbons and hydrogen. Dehydrogenation was found to be the main pyrolysis mechanism due to the high reaction temperature induced by electric arc. The average particle size of soot as carbonaceous residue was about 10 microm. The carbon content and heavy metals in soot were above 60% and below 0.01 ppm, respectively. The utilization of soot as industrial material resources such as carbon black seems to be feasible after refining and grinding.

  20. Influence of lubricant oil residual fraction on recycled high density polyethylene properties and plastic packaging reverse logistics proposal

    Directory of Open Access Journals (Sweden)

    Harley Moraes Martins

    2015-10-01

    Full Text Available Abstract To recycle post-consumer HDPE contaminated with waste lubricating oils, companies include prior washing and drying in the process. This consumes large amounts of water and energy, generates significant effluent requiring treatment. This study assesses lubricating oil influence on HDPE properties to evaluate the feasibility of its direct mechanical recycling without washing. The current lubricating oil packaging reverse logistics in Rio de Janeiro municipality is also analyzed. HDPE bottle samples were processed with seven oil contents ranging from 1.6-29.4 (wt%. The results indicated the possibility to reprocess the polymer with oily residue not exceeding 3.2%. At higher levels, the external oil lubricating action affects the plastic matrix processing in the extruder and injection, and the recycled material has a burnt oil odor and free oil on the surface. Small residual oil amounts retain the plastic properties comparable to the washed recycled polymer and exhibited benefits associated with the oil plasticizer action. However, oil presence above 7.7% significantly changes the properties and reduces the elasticity and flexural modulus and the plastic matrix crystallinity.

  1. Determination of phosphorus in lubricating oils by cool-flame emission spectroscopy.

    Science.gov (United States)

    Elliott, W N; Heathcote, C; Mostyn, R A

    1972-03-01

    The phosphorus content of lubricating oils is determined by measurement of the emission from the HPO molecular species at 528 nm in a cool hydrogen-nitrogen diffusion flame. The oil is ashed in the presence of potassium hydroxide and an aqueous extract of the melt is treated with ion-exchange resin to remove interferents, before aspiration into the flame. Analytical results are presented on samples containing phosphorus in the range 0.009-0.2%. The precision of the method is +/- 5% at the 0.04% phosphorus level.

  2. Tribological Testing of Hemispherical Titanium Pin Lubricated by Novel Palm Oil: Evaluating Anti-Wear and Anti-Friction Properties

    Science.gov (United States)

    Sapawe, Norzahir; Samion, Syahrullail; Ibrahim, Mohd Izhan; Daud, Md Razak; Yahya, Azli; Hanafi, Muhammad Farhan

    2017-05-01

    In this study, the properties of hip implant material and lubricants were examined using a pin on disc apparatus, to compare the effect of metal-on-metal (MoM) contact with a bio-lubricant derived from palm oil. The behaviour of the lubricants was observed during the experiments, in which a hemispherical pin was loaded against a rotating disc with a groove. A titanium alloy was used to modify the hemispherical pin and disc. Before and after the experiments, the weight and surface roughness were analysed, to detect any degradation. The results were compared according to the different kinematic viscosities. The wear rates and level of friction with each lubricant were also examined. The lubricant with the highest viscosity had the lowest frictional value. Therefore, developing suitable lubricants has the potential to prolong the lifespan of prostheses or implants used in biomedical applications. The experiments collectively show that lubricants derived from palm oil could be used as efficient bio-lubricants in the future.

  3. Contribution of unburned lubricating oil and gasoline-derived n-alkanes to particulate emission from non-catalyst and catalyst-equipped two-stroke mopeds operated with synthetic lubricating oil.

    Science.gov (United States)

    Spezzano, Pasquale; Picini, Paolo; Cataldi, Dario

    2008-10-01

    This study investigated the contribution of unburned lubricating oil and gasoline-derived n-alkanes to particulate emission from non-catalyst and catalyst-equipped two-stroke (2-S) mopeds operated with ester-based, fully synthetic lubricating oil. Exhaust particulate matter (PM) from ten 2-S, 50 cm3 mopeds belonging to three different levels of emission legislation (EURO-0, EURO-1 and EURO-2) was collected during the sampling phase of the ECE 47 driving cycle through which each mopeds was driven on a dynamometer bench. Filters containing PM were extracted with an accelerated solvent extractor and analysed by gas-chromatography/mass spectrometry. The contribution of unburned lubricating oil to the PM was ascertained and quantified by exploiting characteristic ions in its mass spectrum. The experimental results show that unburned lubricating oil accounted for a significant fraction (4.7-38.7%) of the PM emitted from 2-S mopeds. Emission rates of particulate unburned lubricating oil and n-alkanes from non-catalyst EURO-0 mopeds were 15.4-56.2 mg km(-1) and 1-2 mg km(-1), respectively. These emission rates were reduced of 75% and 88%, respectively, for catalyst-equipped EURO-1 mopeds. The results of the tests carried out on two EURO-2 mopeds of different technology were contrasting. A EURO-2 moped with carburettor and secondary air injection exhibited a clear reduction of 95% and 88% for unburned lubricating oil and n-alkanes emission rates with respect to the average values observed for EURO-1 mopeds. On the other hand, the second EURO-2 moped, equipped with catalyst and direct injection, had unburned lubricating oil emission rates roughly in the range of EURO-0 mopeds while particulate n-alkanes were emitted at rates comparable with typical values observed for catalyst EURO-1 mopeds.

  4. Wear Studies of MIL-L-23699 Aircraft Turbine Engine. Synthetic Base Lubricating Oils - I. The Development of a Procedure and Initial Findings

    Science.gov (United States)

    and contaminants in MIL-L-23699 aircraft turbine engine synthetic base lubricating oils . The procedure employs a linear ball-on-flat principle and is...wear of water in gas-turbine lubricating oils . The MIL-L-23699 oils exhibit a linear relationship between the removal of bearing surface material (wear

  5. Interaction of Chloroprene and Nitrile- Butadiene Rubber with Lubricating Greases and Base Oils

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The present communication addresses compatibility of two synthetic rubber types, chloroprene and nitrilebutadiene ones, with a number of base oils of petroleum origin and lubricating greases produced thereof. Four base oils,including three naphthenic products with varying degrees of refining and one paraffinic product,were compared with each other in terms of their effect on the rubbers. Degenerative changes occurring in the rubbers on contact with the oils and greases were studied using accelerated ageing tests. Alterations in rubber parameters, such as hardness, weight and glass transition temperature, caused by interaction with oil were monitored. The main physicochemical mechanisms standing behind the changes observed in the rubber properties were found to be (i) migration of plasticizer from rubber into the oil phase, (ii) absorption of oil by rubber,and (iii) oxidation of rubber. An increase in glass transition temperature (Tg) of rubber aged in a base oil or grease was considered as an indirect indication that the plasticizer had migrated out of rubber;the plasticizer accumulation in the oil phase being directly confirmed by gas chromatography. In order to suppress the plasticizer migration, oil additivation with dioctyl adipate (DOA), a common plasticizer used in rubber formulations, was attempted. However, the BOA-additivated oils, while reducing plasticizer migration, were found to cause more swelling than the original oils in the case of chloroprene rubber. As an alternative, replacement of BOA by an alkylated aryl phosphate in nitrile- butadiene rubber formulations was considered, but it did not solve the problem either.The results of this study suggest conclusively that the type of rubber, the plasticizer, and the base oil are all the crucial parameters that should be considered when matching rubber with oil in real- life applications. Interaction of rubber with base oils and with greases produced thereof is largely controlled by (i) solvency of the

  6. The Lubrication Ability of Ionic Liquids as Additives for Wind Turbine Gearboxes Oils

    Directory of Open Access Journals (Sweden)

    Miguel A. Gutierrez

    2016-05-01

    Full Text Available The amount of energy that can be gained from the wind is unlimited, unlike current energy sources such as fossil and coal. While there is an important push in the use of wind energy, gears and bearing components of the turbines often fail due to contact fatigue, causing costly repairs and downtime. The objective of this work is to investigate the potential tribological benefits of two phosphonium-based ionic liquids (ILs as additives to a synthetic lubricant without additives and to a fully formulated and commercially available wind turbine oil. In this work, AISI 52100 steel disks were tested in a ball-on-flat reciprocating tribometer against AISI 440C steel balls. Surface finish also affects the tribological properties of gear surfaces. In order to understand the combined effect of using the ILs with surface finish, two surface finishes were also used in this study. Adding ILs to the commercial available or synthetic lubricant reduced the wear scar diameter for both surface finishes. This decrease was particularly important for trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl amide, where a wear reduction of the steel disk around 20% and 23% is reached when 5 wt % of this IL is added to the commercially available lubricant and to the synthetic lubricant without additives, respectively.

  7. The effect of lubricating oils on bearing fatigue-life using the Evonik RohMax pitting test procedure

    Energy Technology Data Exchange (ETDEWEB)

    Bartels, Thorsten [Evonik RohMax Additives GmbH, Darmstadt (Germany)

    2009-07-01

    A major requirement for modern driveline lubricants is the need to reduce churning losses and friction in order to deliver continual improvements in fuel efficiency. In trying to achieve this oil formulators target lower and lower viscosities, testing the limits of what is acceptable Churning loss reductions are being made by reducing the viscosity of the lubricating oil. Reduced oil viscosities can lead to reduced oil film thicknesses, especially at high operating temperatures. Thinner oil films can lead to an increase in friction, and a decrease in the fatigue-life capacity in lubricated contacts of bearings and gears in several driveline applications. Extensive fluid testing is required. Current test procedures are subject to extremely high variability, and large numbers of experiments are required to develop high confidence in the test conclusions. This publication introduces a new fatigue-life test method, which in our hands provides a clear improvement in test time, cost, and reproducibility. The test's results enable an estimation of the effect of lubricating oils on bearing fatigue-life. This is done by comparing the results to those obtained with reference oils which have also been tested in the standardized bearing tests for lubricating oils. The effects of operating parameters on test accuracy and repeatability have been studied. The parameters studied are oil temperature, contact pressure, speed and the test specimen batch. In addition to the measurement of bearing fatigue-life, the new test may also be used to study gear fatigue-life. We have used this test to investigate the lubrication oils' influence on fatigue-life in bearings and in gears. In order to extend the comparisons to gear performance the reference fluids were evaluated in standard industry test procedures used for determining gear performance, in particular the FZG test rig, thus establishing an extra insight in the fluids' performance by comparing gear test performance

  8. Evaluation of the Lubricating Properties of Palm Kernel Oil

    Directory of Open Access Journals (Sweden)

    John J MUSA

    2009-07-01

    Full Text Available The search for renewable energy resources continues to attract attention in recent times as fossil fuels such as petroleum, coal and natural gas, which are been used to meet the energy needs of man are associated with negative environmental impacts such as global warming. Biodiesel offered reduced exhaust emissions, improved biodegradability, reduced toxicity and higher carotene rating which can improve performance and clean up emissions. Standard methods were used to determine the physical and chemical properties of the oil, which includes the Density, Viscosity, flash/fire point, carbon residue, volatility and Specific Gravity were determined by chemical experimental analysis. The flash/fire points of the Heavy duty oil (SAE 40 and Light duty oil (SAE 30 is 260/300(°C and 243/290(°C respectively while the pour points of the samples are 22°C for palm kernel oil while 9°C and 21°C for SAE 40and SAE 30 respectively.

  9. Biobased lubricants and functional products from Cuphea oil

    Science.gov (United States)

    Cuphea (Lythraceae) is an annual plant that produces a small seed rich in saturated medium-chain triacylglycerols (TAGs). With the need for higher seed yields, oil content, and less seed shattering, Oregon State University began developing promising cuphea crosses. Cuphea PSR23 is a hybrid between C...

  10. Recycling of Automotive Lubricating Waste Oil and Its Quality Assessment for Environment-Friendly Use

    Directory of Open Access Journals (Sweden)

    Naveed Anwar

    2012-10-01

    Full Text Available Lubricating oils, which are formulated with a number of chemicals blended base oils provide products that last longer, keep machinery cleaner and allow the machinery to work better under severe operating conditions. However, the used oil-waste generated by the automobiles and other allied industries poses an environmental hazard. The motivation of the present research study was to study the merits and demerits of commonly applicable technique acid/clay for reclamation of waste oil. This process has been employed for many years as the premier type of re-refining in which concentrated sulfuric acid is introduced to dehydrate waste lubricating oil. An acidic sludge is produced which is treated with clay. In this study, the conventional process of reclamation of waste oil, which is acid/clay, has been reviewed in the light of recovered product quality and hazardous effects on the environment and human health. Forty samples, in which, waste oil (10, reclaimed oil (30 were collected from different blending and reclamation plants located in different areas of the Punjab Province and were compared with two stroke blended oil (10 samples. The samples were tested for kinematic viscosity at 40 and 100ºC, Viscosity Index, Flash point, Sulfated Ash content, Copper Corrosion, Water content, Sediments and Color by following the standard ASTM Methods D-445, D-2270, D-92, D-482, D-130, D-95, D-473 and D-1500 (ASTM, 2002, respectively. According to the results, blended reclaimed (two stroke oil samples were found up to the recommended standard test limits. On the other hand, waste oil and reclaimed oil samples were found above the maximum test limits of acid number and copper corrosion and were found below in flash point test limit. Waste oil samples were highly contaminated and adulterated with mud and water. Although no such standard criteria or parameters are available for comparison but analysis results showed a bad reflection and due to which only few tests

  11. [Safety forms for industrial lubricating oils: a working proposal at the national level].

    Science.gov (United States)

    Menichini, E; Reggiani, A; Rossi, L

    1989-01-01

    The health and safety data sheets for lubricating oils currently in use present considerable differences regarding the information they provide. Often, the information is either too generalized or incomplete--particularly on the chemical aspects of oils--and therefore the sheets are inadequate for the prevention and control of the occupational risks. For the purposes of harmonization, a data sheet has been prepared which takes into account the specific features of the products, and particularly the handling of confidential data. The most important oil manufacturers have been consulted, and they have agreed to use the data sheet in order to provide information on their products to the local health authorities. The widespread use of this data sheet should enable an easier comparison of the health and safety data of oils to be made, provide a better understanding of the information received and, consequently, evaluate the risks involved.

  12. 3D Two-way coupled TEHD analysis on the lubricating characteristics of thrust bearings in pump-turbine units by combining CFD and FEA

    Science.gov (United States)

    Zhai, Liming; Luo, Yongyao; Wang, Zhengwei; Liu, Xin

    2016-01-01

    The thermal elastic hydro dynamic (TEHD) lubrication analysis for the thrust bearing is usually conducted by combining Reynolds equation with finite element analysis (FEA). But it is still a problem to conduct the computation by combining computational fluid dynamics (CFD) and FEA which can simulate the TEHD more accurately. In this paper, by using both direct and separate coupled solutions together, steady TEHD lubrication considering the viscosity-temperature effect for a bidirectional thrust bearing in a pump-turbine unit is simulated combining a 3D CFD model for the oil film with a 3D FEA model for the pad and mirror plate. Cyclic symmetry condition is used in the oil film flow as more reasonable boundary conditions which avoids the oil temperature assumption at the leading and trailing edge. Deformations of the pad and mirror plate are predicted and discussed as well as the distributions of oil film thickness, pressure, temperature. The predicted temperature shows good agreement with measurements, while the pressure shows a reasonable distribution comparing with previous studies. Further analysis of the three-coupled-field reveals the reason of the high pressure and high temperature generated in the film. Finally, the influence of rotational speed of the mirror plate on the lubrication characteristics is illustrated which shows the thrust load should be balanced against the oil film temperature and pressure in optimized designs. This research proposes a thrust bearing computation method by combining CFD and FEA which can do the TEHD analysis more accurately.

  13. Auto-ignition of lubricating oil working at high pressures in a compressor for an air conditioner

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Chul Jin; Choi, Hyo Hyun [Department of Mechanical Engineering, Sejong University, Seoul 143-747 (Korea, Republic of); Sohn, Chae Hoon, E-mail: chsohn@sejong.ac.kr [Department of Mechanical Engineering, Sejong University, Seoul 143-747 (Korea, Republic of)

    2011-01-15

    Auto-ignition of lubricating oil working in a compressor for an air conditioner is studied experimentally. The adopted lubricating oil is an unknown mixture with multi-components and known to have flash point temperature of 170 deg. C. First, its auto-ignition temperature is measured 365 deg. C at atmospheric pressure. The lubricating oil works under high-pressure condition up to 30 atm and it is heated and cooled down repeatedly. Accordingly, auto-ignition temperatures or flammable limits of lubricating oil are required at high pressures with respect to fire safety. Because there is not a standard test method for the purpose, a new ignition-test method is proposed in this study and thereby, auto-ignition temperatures are measured over the pressure range below 30 atm. The measured temperatures range from 215 deg. C to 255 deg. C and they strongly depend on pressure of gas mixture consisting of oil vapor, nitrogen, and oxygen. They are close to flash point temperature and the lubricating oil can be hazardous when it works for high-pressure operating condition and abundant air flows into a compressor.

  14. Polymeric composite and lubricants for the wearresistant friction units of railway mechanics

    Directory of Open Access Journals (Sweden)

    Philipp MYASNIKOV

    2009-01-01

    Full Text Available For long functioning of the friction unit it is necessary to create the steady layers between friction surfaces, which can lower considerably the friction force, and thereof also the wear reducing. Within the metal-polymer tribocoupling the friction transfer film shall function as a separating layer. The frame and kinetics of filming of friction carry at metal- binary material friction is studied, that creates the base for mining new high-performance self-lubricating polymer compositions.When the unit with a lubricant functions, a role of the uncoupling layer is being fulfilled by the lubricating film, which shall possess the given properties, that is to contain in its composition the nanoclaster additives, capable to function in a tribocoupling for a long time, constantly reappearing in a film due to the chemical reactions at friction. It is shown that introduction of nanomodified additives on the basis of phosphorus molybdate of metals into widely used lubricant compositions allows to create steady lubricant films between friction surfaces. The possible mechanism of action of inorganic phosphoprous-containing additives of the polymeric nature is discussed.

  15. Vibration analysis of angular contact ball bearing operated with copper oxide nanoparticles mixed ISO VG 68 lubricating oil

    Directory of Open Access Journals (Sweden)

    Prakash E.

    2014-09-01

    Full Text Available The purpose of this paper is to investigate the effect of CuO nanoparticles on lubricating oil and vibration reduction in angular contact ball bearing. CuO nanoparticles are synthesized by using chemical method and characteristic studies done in XRD and TEM. CuO nanoparticles size achieved in the range 26 - 30 nm. The nanoparticles concentration of 0.2 wt. % added into the lubricant (ISO VG 68. The testrig setup consists of angular contact ball bearing operated by AC motor with speed controller. The bearing (New and outer defect vibrations measured using base oil and CuO mixed oil.

  16. Analysis of the Thermo-Viscous Effect on Friction and Energy Dissipation in Oil Lubricated Interfaces

    DEFF Research Database (Denmark)

    Johansen, Per; Roemer, Daniel Beck; Andersen, Torben O.

    2016-01-01

    -dimensional thermo-elastohydrodynamic lubrication models of fluid power components. The computational efforts involved in simulation with such models entail that design optimization are to some extend impractical. However, such models are also pursued in theoretical tribology with the aim to study loss and wear...... investigations, due to computational effort, whereby analytical research in loss mechanisms still have certain advantages. In this paper, the thermo-viscous effect of a lubricant is included in an analytical study of the friction and energy dissipation of oil hydraulic thin-films. This analytical study is based...... an influence from the surface temperature gradient on the viscous friction, which id not revealed when applying classical isothermal analysis. The significance of the thermo-viscous effect on friction and energy dissipation is analyzed analytically in order to provide a qualitative insight to the relation...

  17. The ecotoxicology of vegetable versus mineral based lubricating oils: 3. Coral fertilization and adult corals.

    Science.gov (United States)

    Mercurio, Philip; Negri, Andrew P; Burns, Kathryn A; Heyward, Andrew J

    2004-05-01

    Biodegradable vegetable-derived lubricants (VDL) might be less toxic to marine organisms than mineral-derived oils (MDL) due to the absence of high molecular weight aromatics, but this remains largely untested. In this laboratory study, adult corals and coral gametes were exposed to various concentrations of a two-stroke VDL-1A and a corresponding MDL to determine which lubricant type was more toxic to each life stage. In the fertilization experiment, gametes from the scleractinian coral Acropora microphthalma were exposed to water-accommodated fractions (WAF) of VDL-1A and MDL for four hours. The MDL and VDL-1A WAFs inhibited normal fertilization of the corals at 200 microg l(-1) total hydrocarbon content (THC) and 150 microg l(-1) THC respectively. Disturbance of a stable coral-dinoflagellate symbiosis is regarded as a valid measure of sub-lethal stress in adult corals. The state of the symbiosis in branchlets of adult colonies of Acropora formosa was monitored using indicators such as dinoflagellate expulsion and dark-adapted photosystem II yields of dinoflagellate (using pulse amplitude modulation fluorescence). An effect on symbiosis was measurable following 48 h exposure to the lubricants at concentrations of 190 microg l(-1) and 37 microg l(-1) THC for the MDL and VDL-1A respectively. GC/MS revealed that the main constituent of the VDL-1A WAF was the compound coumarin, added by the manufacturer to improve odour. The fragrance containing coumarin was removed from the lubricant formulation and the toxicity towards adult corals re-examined. The coumarin-free VDL-2 exhibited significantly less toxicity towards the adult corals than all of the other oil types tested, with the only measurable effect being a slight but significant drop in photosynthetic efficiency at 280 microg l(-1).

  18. Fuels and Lubricants. An Instructional Unit for High School Teachers of Vocational Agriculture.

    Science.gov (United States)

    Crowder, John; Carpenter, Bruce

    Designed as a 2-week course of study in the agricultural mechanics curriculum to be taught at the junior and senior high school level, unit on fuels and lubricants is divided into eight major performance objectives. Each objective is subdivided into the areas of content, suggested teaching and learning activities, resources, and evaluation. Topics…

  19. Effects of Corrosion Inhibitors on Lubrication Performance of Rolling Oil for Copper Foil

    Institute of Scientific and Technical Information of China (English)

    Xiong Sang; Sun Jianlin; Zeng Yingfeng; Xu Yang

    2014-01-01

    The 2,5-bis(ethyldisulfanyl)-1,3,4-thiadiazole (T561), benzotriazole (BTA), 1-N, N-bis (2-ethylhexyl) amino-methyl-4-methyl-1h-benzotriazole (IRGAMET39) and 1-[N, N-bis (2-ethylhexyl) aminomethyl] methyl benzotriazole (TT-LX) have been evaluated as corrosion inhibitors used in rolling oil for cold rolling of copper foil. The MRS-10A four-ball friction and wear tests have been carried out to compare their tribological properties, and the lubricating performance of rolling oils has been studied through rolling experiments. The oil sample containing IRGAMET 39 has the same PB value as that one containing T561, with the coefifcient of friction increased by 35.6%and wear scar diameter decreased by 4%. The minimum rolling gauge has been studied after rolling lubrication, but the results show that inhibitors have no effect on it. Scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) analyses have indicated that the inhibitor is adsorbed on the copper surface to prevent copper from being corroded easily. In addition, the LEXT OLS4000 laser confo-cal microscopy has been used to observe the foil surface which shows that the streaks of foil surface are clear, the scratches are shallow and the surface failure is improved effectively.

  20. Prediction of refrigerant absorption and onset of natural convection in lubricant oil

    Energy Technology Data Exchange (ETDEWEB)

    Barbosa, Jader R.; Marcelino Neto, Moises A. [Department of Mechanical Engineering, Federal University of Santa Catarina, Florianopolis, SC 88040900 (Brazil); Thoma, Stefan M. [Department of Mechanical and Process Engineering, Swiss Federal Institute of Technology, Sonneggstrasse 3, 8092 Zurich (Switzerland)

    2008-11-15

    Refrigerant absorption and mixing in lubricant oil are important in the design of refrigeration compressors and refrigeration systems. Experimental work is reported on absorption of R-134a vapour through the top interface of an initially stagnant layer of pure lubricant oil. Since the liquid refrigerant is heavier than the oil, mixing is enhanced due to natural mass convection. In the present paper, the behaviour of the liquid temperature during absorption is described based on measurements carried out in a test rig consisting of a transparent 70 mm ID, 150 mm long, vertical glass tube through which absorption can be directly observed. Transient liquid temperatures were measured at three different heights in the test section (two in the vapour, one in the liquid). The experimental work is complemented by a theoretical analysis of the critical time for the onset of mass transfer induced Rayleigh instability. The model is based on a critical mass transfer Rayleigh number criterion widely reported in the literature and takes into account the variation of physical properties in the liquid layer. The critical time for the onset of natural mass convection increases with decreasing system pressure as a result of a lower equilibrium concentration at the vapour-liquid interface. (author)

  1. Tribology of steel/steel interaction in oil-in-water emulsion; a rationale for lubricity.

    Science.gov (United States)

    Kumar, Deepak; Daniel, Jency; Biswas, S K

    2010-05-15

    Oil droplets are dispersed in water by an anionic surfactant to form an emulsion. The lubricity of this emulsion in steel/steel interaction is explored in a ball on flat nanotribometer. The droplet size and charge are measured using dynamic light scattering, while the substrate charge density is estimated using the pH titration method. These data are combined to calculate the DLVO forces for the droplets generated for a range of surfactant concentration and two oil to water volume ratios. The droplets have a clear bi-modal size distribution. The study shows that the smaller droplets which experience weak repulsion are situated (at the highest DLVO barrier) much closer to the substrate than the bigger droplets, which experience the same DLVO force, are. We suggest that the smaller droplets thus play a more important role in lubricity than what the bigger droplets do. The largest volume of such small droplets occurs in the 0.5 mM-1 mM range of surfactant concentration and 1% oil to water volume ratio, where the coefficient of friction is also observed to be the least.

  2. Rheological behaviour of coal modified by waste plastics and lubricating oils

    OpenAIRE

    Melendi Espina, Sonia; Díez Díaz-Estébanez, María Antonia; Álvarez García, Ramón; Castro, Miguel; Steel, Karen; Snape, Colin E.

    2007-01-01

    The aim of this work is to study the interactions between a coking coal and two types of wastes: plastics from municipal wastes (single and mixed) and lubricating-oils coming from the iron and steel sector. For this purpose, Gieseler plastometry, rheometry and in situ high-temperature 1H NMR spectroscopy can be combined to discern the most suitable wastes for using as secondary raw materials in metallurgical coke production. It was found that there is a relationship between the Gieseler fl...

  3. Determination of metals in lubricating oils by X-ray fluorescence spectrometry.

    Science.gov (United States)

    Pouzar, M; Cernohorský, T; Krejcová, A

    2001-06-21

    The determination of common wear metals, namely iron, chromium, copper, zinc and lead, in a wide range of lubricating oil samples was investigated for the use of a low-cost, wavelength-dispersive X-ray fluorescence spectrometer. The procedure provided results in satisfactory agreement with inductively coupled plasma spectrometry used as reference method after microwave digestion of the samples in concentrated nitric acid. Statistical tests following extensive regression analyses of the data indicated that interelement effects were not statistically significant and that a simple linear regression was adequate for the calibration of individual metals.

  4. Tribological Performance of Hydrogenated Amorphous Carbon (a-C: H DLC Coating when Lubricated with Biodegradable Vegetal Canola Oil

    Directory of Open Access Journals (Sweden)

    H.M. Mobarak

    2014-06-01

    Full Text Available Increasing environmental awareness and demands for lowering energy consumptions are strong driving forces behind the development of the vehicles of tomorrow. Without the advances of lubricant chemistry and adequate lubricant formulation, expansion of modern engines would not have been possible. Considering environmental awareness factors as compared to mineral oils, vegetal oil based biolubricants are renewable, biodegradable, non-toxic and have a least amount of greenhouse gases. Furthermore, improvement in engine performance and transmission components, which were impossible to achieve by applying only lubricants design, is now possible through diamond like carbon (DLC coatings. DLC coatings exhibit brilliant tribological properties, such as good wear resistance and low friction. In this regard, tribological performance of a-C: H DLC coating when lubricated with Canola vegetal oil has been investigated by the help of a ball-on-flat geometry. Experimental results demonstrated that the a-C: H DLC coating exhibited better performance with Canola oil in terms of friction and wear as compared to the uncoated materials. Large amount of polar components in the Canola oil significantly improved the tribological properties of the a-C:H coating. Thus, usage of a-C: H DLC coating with Canola oil in the long run may have a positive impact on engine life.

  5. The Wear Characteristics of Heat Treated Manganese Phosphate Coating Applied to AlSi D2 Steel with Oil Lubricant

    Directory of Open Access Journals (Sweden)

    Venkatesan Alankaram

    2012-12-01

    Full Text Available Today, in the area of material design conversion coatings play an important role in the applications where temperature, corrosion, oxidation and wear come in to play. Wear of metals occurs when relative motion between counter-surfaces takes place, leading to physical or chemical destruction of the original top layers. In this study, the tribological behaviour of heat treated Manganese phosphate coatings on AISI D2 steel with oil lubricant was investigated. The Surface morphology of manganese phosphate coatings was examined by Scanning Electron Microscope (SEM and Energy Dispersive X-ray Spectroscopy (EDX .The wear tests were performed in a pin on disk apparatus as per ASTM G-99 Standard. The wear resistance of the coated steel was evaluated through pin on disc test using a sliding velocity of 3.0m/s under Constant loads of 40 N and 100 N with in controlled condition of temperature and humidity. The Coefficient of friction and wear rate were evaluated. Wear pattern of Manganese phosphate coated pins with oil lubricant, Heat treated Manganese phosphate coated pins with oil lubricant were captured using Scanning Electron Microscope (SEM. The results of the wear test established that the heat treated manganese phosphate coating with oil lubricant exhibited the lowest average coefficient of friction and the lowest wear loss up to 6583 m sliding distance under 40 N load and 3000 m sliding distance even under 100 N load respectively. The Wear volume and temperature rise in heat treated Manganese Phosphate coated pins with oil lubricant is lesser than the Manganese Phosphate coated pins with oil lubricant

  6. Diagnosis of lubricating oil by evaluating cyanide and carbon molecular emission lines in laser induced breakdown spectra

    Science.gov (United States)

    Elnasharty, I. Y.; Kassem, A. K.; Sabsabi, M.; Harith, M. A.

    2011-08-01

    To prevent engine failure it is essential to change lubricating oil regularly before it loses its protective properties. It is also necessary to monitor the physical and chemical conditions of the oil to reliably determine the optimum oil-change intervals. The present work focuses on studying evolution of the cyanide (CN) and carbon (C 2) molecular spectral emission lines in the laser induced breakdown spectra of lubricating oil as a function of its consumption. The intensities of these molecular bands have been taken as indicator of engine oil degradation at certain mileage. Furthermore, the percentage of decay of CN and C 2 integral intensity values at the corresponding mileage was calculated in order to relate it to the degree of consumption of the motor oil. Such percentage decay of the CN and C 2 integral intensities have been found to increase gradually with increasing mileage which is accompanied with increasing depletion of engine oil. The results of using LIBS technique in the present measurements proved that it is possible to have a direct, straightforward and easy method for prediction of lubricating oil degree of consumption. This may facilitate scheduling the proper time and/or mileage intervals for changing the oil to avoid any possibility of engine failure.

  7. An Investigation on Tribological Properties and Lubrication Mechanism of Graphite Nanoparticles as Vegetable Based Oil Additive

    Directory of Open Access Journals (Sweden)

    Yu Su

    2015-01-01

    Full Text Available This paper used graphite nanoparticles with the diameter of 35 and 80 nm and LB2000 vegetable based oil to prepare graphite oil-based nanofluids with different volume fractions by two-step method. The tribological properties of graphite nanoparticles as LB2000 vegetable based oil additive were investigated with a pin-on-disk friction and wear tester. Field emission scanning electron microscope (FE-SEM and energy dispersive spectroscopy (EDS were used to examine the morphology and the content of some typical elements of wear scar, respectively. Further, the lubrication mechanism of graphite nanoparticles was explored. It was found that graphite nanoparticles as vegetable based oil additive could remarkably improve friction-reducing and antiwear properties of pure oil. With the increase of volume fraction of graphite nanoparticles, the friction coefficient and the wear volume of disk decreased. At the same volume fraction, the smaller particles, the lower friction coefficient and wear volume. The main reason for the improvement in friction-reducing and antiwear properties of vegetable based oil using graphite nanoparticles was that graphite nanoparticles could form a physical deposition film on the friction surfaces.

  8. Synthesis of fatty monoester lubricant base oil catalyzed by Fe-Zn double-metal cyanide complex

    Indian Academy of Sciences (India)

    Ravindra K Raut; Mehejabeen Shaikh; Srinivas Darbha

    2014-07-01

    Fatty monoester lubricant base oils as high as 96.7 mol% were prepared by reacting methyl oleate with long-chain alcohols viz., 2-ethyl-1-hexanol (C8−OH), 1-decanol (C10OH) and 1-dodecanol (C12OH) in the presence of a solid Fe-Zn double-metal cyanide (DMC) complex catalyst. Unlike many other acid catalysts, DMC doesn't produce undesired ether side products. The catalyst was reusable in four recycling experiments with little loss in catalytic activity and ester yield. The long-chain esters prepared in the study have the desired physical properties for their application as lubricant base oils.

  9. Surface Film Adsorption and Lubricity of Soybean Oil In-Water Emulsion and Triblock Copolymer Aqueous Solution: A Comparative Study

    Directory of Open Access Journals (Sweden)

    Reza Taheri

    2016-12-01

    Full Text Available This paper investigates the surface film adsorption and lubricity of two different types of potential environmentally friendly cold metal forming lubricants: soybean vegetable oil in water VO/W emulsions and triblock copolymer aqueous solutions. The lubricants have different visual appearance, surface film adsorption characteristic, lubricity and surface cleaning behaviour. The effects of concentration, temperature and emulsification ultrasonic energy (for VO/W emulsion are studied. The result shows that the soybean VO/W emulsions have stronger adsorption, superior lubricity and anti-wear property compared to the copolymer solutions. The effect of temperature is investigated at 30 °C and 65 °C which are below and above cloud point of the aqueous copolymer solutions. Both lubricants show improved friction and anti-wear property at 65 °C. However, tenacious residual film remained on the discs surface after surface cleaning indicates lower cleanability of the soybean VO/W emulsions compared to the copolymer solutions, postulating the need for extra post-processing cleaning operations after cold forming process with VO/W emulsion lubricant.

  10. Comparison of the constituents of two jet engine lubricating oils and their volatile pyrolytic degradation products.

    Science.gov (United States)

    van Netten, C; Leung, V

    2000-03-01

    Leaking oil seals in jet engines, at locations prior to the compressor stage, can be a cause of smoke in the cabins of BAe-146 aircraft. Compressed combustion air is bled off to pressurize the cabin and to provide a source of fresh air. Bleed air is diverted from a location just prior to the combustion chamber at a temperature around 500 degrees C. To prevent oil breakdown products from entering the cabin air, catalytic converters have been used to clean the air. During an oil seal failure this device becomes overloaded and smoke is observed in the cabin. Some aircraft companies have removed the catalytic converters and claim an improvement in air quality. During an oil seal failure, however, the flight crew is potentially exposed to the thermal breakdown products of the engine oils. Because very little is known regarding the thermal breakdown products of jet engine lubrication oils, two commercially available oils were investigated under laboratory conditions at 525 degrees C to measure the release of CO, CO2,NO2, and HCN as well as volatiles which were analyzed using GC-Mass spectrometry in an attempt to see if the neurotoxic agents tricresyl phosphates (TCPs) and trimethyl propane phosphate (TMPP) would be present or formed. TMPP was not found in these experiments. Some CO2 was generated along with CO which reached levels in excess of 100 ppm. HCN and NO2 were not detected. GC compositions of the two bulk oils and their breakdown products were almost identical. The presence of TCPs was confirmed in the bulk oils and in the volatiles. Localized condensation in the ventilation ducts and filters in the air conditioning packs are likely the reason why the presence of TCPs has not been demonstrated in cabin air. It was recommended that this needed to be verified in aircraft.

  11. Research on the Relationship between Molecular Activity of Additives and Lubricating Performance of Aluminum Rolling Oil

    Institute of Scientific and Technical Information of China (English)

    Xia Lei; Sun Jianlin; Zeng Yingfeng; Zhang Min; Duan Qinghua

    2013-01-01

    In this paper, an ab initio, local density functional (LDF) method was used to explore the relationship between the molecular properties of additives and the lubricating performance of aluminum rolling oil. The structural properties of butyl stearate, dodecanol, docosanol, and methyl dodecanoate were studied according to the density functional theory. The calculated data showed that the atoms in or around the functional groups might be likely the reacting sites. Because of the different functional groups and structure of ester and alcohol, two types of complex additives, dodecanol and butyl stearate, methyl dodecanoate and butyl stearate, respectively, were chosen for studying their tribological properties and performing aluminum cold rolling experiments. The test results agreed with the calculated results very well. The complex ester, viz. methyl dodecanoate and butyl stearate, had the best lubricating performance with a friction coefifcient of 0.084 1 and a permissive-rolling thickness of 0.040 mm as compared with that of dodecanol-butyl stearate-base oil formulation.

  12. Anti-Wear Performance and Mechanism of an Oil-Miscible Ionic Liquid as a Lubricant Additive

    Energy Technology Data Exchange (ETDEWEB)

    Qu, Jun [ORNL; Bansal, Dinesh G [ORNL; Yu, Bo [ORNL; Howe, Jane Y [ORNL; Luo, Huimin [ORNL; Dai, Sheng [ORNL; Li, Huaqing [ORNL; Blau, Peter Julian [ORNL; Bunting, Bruce G [ORNL; Mordukhovich, Gregory [GM R& D and Planning, Warren, Michigan; Smolenski, Donald [GM R& D and Planning, Warren, Michigan

    2012-01-01

    An ionic liquid (IL) trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate has been investigated as a potential anti-wear lubricant additive. Unlike most other ILs that have very low solubility in non-polar fluids, this IL is fully miscible with various hydrocarbon oils. In addition, it is thermally stable up to 347 oC, showed no corrosive attack to cast iron in ambient environment, and has excellent wettability on solid surfaces (e.g., contact angle on cast iron <8o). Most importantly, this phosphonium-based IL has demonstrated effective anti-scuffing and anti-wear characteristics when blended with lubricating oils. For example, a 5 wt.% addition into a synthetic base oil eliminated the scuffing failure experienced by the neat oil and, as a result, reduced the friction coefficient by 60% and the wear rate by three orders of magnitude. A synergistic effect on wear protection was observed with the current anti-wear additive when added into a fully-formulated engine oil. Nanostructure examination and composition analysis revealed a tribo-boundary film and subsurface plastic deformation zone for the metallic surface lubricated by the IL-containing lubricants. This protective boundary film is believed to be responsible for the IL s anti-scuffing and anti-wear functionality.

  13. Preparation of Nano-magnetic Lubricating Oil%纳米磁性润滑油的制备

    Institute of Scientific and Technical Information of China (English)

    吴磊; 刘永坤; 李学慧

    2011-01-01

    The magnetic lubricating oil was prepared by self-made equipment using Fe(CO) 5, polybutylene succinic imide Ⅳ pentamine surfactant, oil-based liquid and NH3 as raw materials.The hysteresis loop, particles size distribution of nanoparticles and morphology of the magnetic lubricating oil were characterized by VSM, X-ray small angle scattering and TEM.The test results show that the magnetic lubricating oil is ultra-paramagnetic material and its saturated magnetic intensity is 0.025 9 T.The particle composition is nanometer scale,which has good stability in magnetic lubricating oil.%以五羰基铁、聚丁烯基丁二酰亚胺四乙烯五胺表面活性剂、油基液和氨气为原料,利用自制的装置制备磁性润滑油.利用VSM、X射线小角散射和TEM分别对磁性润滑油的磁滞回线、纳米颗粒粒径大小、分布及形貌等进行表征.测试结果表明,磁性润滑油属超顺磁材料,磁饱和强度为0.025 9 T;其组成的颗粒具有纳米量级,在润滑油具有良好的分散稳定性.

  14. Quantitative Analysis for Monitoring Formulation of Lubricating Oil Using Terahertz Time-Domain Transmission Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    TIAN Lu; ZHAO Kun; ZHOU Qing-Li; SHI Yu-Lei; ZHANG Cun-Lin

    2012-01-01

    The quantitative analysis of zinc isopropyl-isooctyl-dithiophosphate (T204) mixed with lube base oil from Korea with viscosity index 70 (T204-Korea70) is presented by using terahertz time-domain spectroscopy (THz-TDS). Compared with the middle-infrared spectra of zinc n-butyl-isooctyl-dithiophosphate (T202) and T204, THz spectra of T202 and T204 show the weak broad absorption bands. Then, the absorption coefficients of the T204-Korea70 system follow Beer's law at the concentration from 0.124 to 4.024%. The experimental absorption spectra of T204-Korea70 agree with the calculated ones based on the standard absorption coefficients of T204 and Korea70. The quantitative analysis enables a strategy to monitor the formulation of lubricating oil in real time.%The quantitative analysis of zinc isopropyl-isooctyl-dithiophosphate (T204) mixed with lube base oil from Korea with viscosity index 70 (T204-Korea70) is presented by using terahertz time-domain spectroscopy (THz-TDS).Compared with the middle-infrared spectra of zinc n-butyl-isooctyl-dithiophosphate (T202) and T204,THz spectra of T202 and T204 show the weak broad absorption bands.Then,the absorption coefficients of the T204-Korea70 system follow Beer's law at the concentration from 0.124 to 4.024%.The experimental absorption spectra of T204-Korea70 agree with the calculated ones based on the standard absorption coefficients of T204 and Korea70.The quantitative analysis enables a strategy to monitor the formulation of lubricating oil in real time.

  15. Effect of surface finishing on friction and wear of Poly-Ether-Ether-Ketone (PEEK under oil lubrication

    Directory of Open Access Journals (Sweden)

    Thiago Fontoura de Andrade

    Full Text Available Abstract The tribological properties of poly-ether-ether-ketone (PEEK containing 30% of carbon fiber were studied in an oil-lubricated environment and different surface finishing of the metallic counterbody. Four different finishing processes, commonly used in the automotive industry, were chosen for this study: turning, grinding, honing and polishing. The test system used was tri-pin on disc with pins made of PEEK and counterbody made of steel; they were fully immersed in ATF Dexron VI oil. Some test parameters were held constant, such as the apparent pressure of 2 MPa, linear velocity of 2 m/s, oil temperature at 85 °C, and the time - 120 minutes. The lubrication regime for the apparent pressure of 1 MPa to 7 MPa range was also studied at different sliding speeds. A direct correlation was found between the wear rate, friction coefficient and the lubrication regime, wherein wear under hydrodynamic lubrication was, on average, approximately 5 times lower, and the friction coefficient 3 times lower than under boundary lubrication.

  16. Coated carbide drill performance under soluble coconut oil lubricant and nanoparticle enhanced MQL in drilling AISI P20

    Science.gov (United States)

    Jamil, N. A. M.; Azmi, A. I.; Fairuz, M. A.

    2016-02-01

    This research experimentally investigates the performance of a TiAlN coated carbide drill bit in drilling AISI P20 through two different kinds of lubricants, namely; soluble coconut oil (SCO) and nanoparticle-enhanced coconut oil (NECO) under minimum quantity lubrication system. The tool life and tool wear mechanism were studied using various cutting speeds of 50, 100 and 150 m/min with a constant feed of 0.01 mm/rev. Since the flank wear land was not regular along the cutting edge, the average flank wear (VB) was measured at several points using image analysis software. The drills were inspected using a scanning electron microscope to further elucidate the wear mechanism. The result indicates that drilling with the nanoparticle- enhanced lubricant was better in resisting the wear and improving the drill life to some extent

  17. Rheology of oleogels based on sorbitan and glyceryl monostearates and vegetable oils for lubricating applications

    Directory of Open Access Journals (Sweden)

    Sánchez, R.

    2011-09-01

    Full Text Available Oleogels based on sorbitan and glyceryl monostearates and different types of vegetable oils, potentially applicable as biodegradable alternatives to traditional lubricating greases, have been studied. In particular, the rheological behavior, by means of small-amplitude oscillatory shear (SAOS measurements, and some lubrication performance-related properties (mechanical stability and tribological response have been evaluated in this work. SAOS response and mechanical stability of these oleogels are significantly influenced by the type and concentration of the organogelator and the vegetable oil used in the formulations. Glyceryl monostearate (GMS generally produces stronger gels than sorbitan monostearate (SMS. The use of low-viscosity oils, such as rapeseed and soybean oils, yields gels with significantly higher values of the linear viscoelastic functions than oleogels prepared with high-viscosity oils, i.e. castor oil. The rheological behavior of SMS-based oleogels also depends on the cooling rate applied during the gelification process. On the other hand, the oleogels studied present low values of the friction coefficient obtained in a tribological contact, although only some GMS/castor oil-based oleogels exhibit a suitable mechanical stability.

    En el presente trabajo se han estudiado diferentes oleogeles, basados en monoestearatos de sorbitano y glicerilo y aceites vegetales, que podrían ser potencialmente empleados como alternativas biodegradables a las grasas lubricantes tradicionales. En concreto, se ha evaluado su comportamiento reológico, a través de ensayos en cizalla oscilatoria, y algunas propiedades relacionadas con su rendimiento en la lubricación, tales como su estabilidad mecánica y comportamiento tribológico. La respuesta reológica y la estabilidad mecánica de los oleogeles estudiados están significativamente influenciadas por el tipo y la concentración del agente gelificante y por el aceite vegetal empleado. As

  18. Lubrication System 1. Check and Change the Engine Oil. Student Manual. Small Engine Repair Series. First Edition.

    Science.gov (United States)

    Hill, Pamela

    This student manual on checking and changing the engine oil is the second of three in an instructional package on the lubrication system in the Small Engine Repair Series for handicapped students. The stated purpose for the booklet is to help students learn what tools and equipment to use and all the steps of the job. Informative material and…

  19. The interactions between oil droplets and gel matrix affect the lubrication properties of sheared emulsion-filled gels

    NARCIS (Netherlands)

    Chojnicka, A.; Sala, G.; Kruif, de C.G.; Velde, van de F.

    2009-01-01

    In this work the lubrication behaviour of emulsions, gels, and emulsion-filled gels was studied in relation to their composition and structure. It was found that emulsions had much lower friction coefficients than their continuous phases. Emulsions with 40 wt% oil had the same friction coefficient a

  20. Study on the oxidative stability of poly a-olefin aviation lubricating base oil using PDSC method

    Science.gov (United States)

    Wu, N.; Fei, Y. W.; Yang, H. W.; Wang, Y. M.; Zong, Z. M.

    2016-08-01

    The oxidation stability of the domestic and import PAO aviation lubricating base oil was studied by the method of pressurized differential scanning calorimetry testing the initial oxidation temperature. The effects of anti-oxidants were investigated, and the best ratio of antioxidants was determined.

  1. Experimental evidence of the thermal effect of lubricating oil sprayed in sliding-vane air compressors

    Directory of Open Access Journals (Sweden)

    Gianluca Valenti

    2014-11-01

    Full Text Available A way to increase the efficiency of positive-displacement air compressor is spraying the lube oil to exploit it not only as lubricating and sealing agent but also as thermal ballast. This work seeks the experimental evidence in sliding-vane compressors by measuring the air standard volume flow rate and the electrical power input of three diverse configurations. The first configuration, taken as the reference, employs a conventional injection system comprising calibrated straight orifices. The other two, referred to as advanced, adopt smaller orifices and pressure-swirl full-cone nozzles designed for the purpose; the third configuration utilizes a pump to boost the oil pressure. The laser imagining technique shows that the nozzles generate sprays that break-up within a short distance into spherical droplets, ligaments, ramifications and undefined structures. Tests on the packaged compressors reveal that the advanced configurations provide almost the same air flow rate while utilizing half of the oil because the sprays generate a good sealing. Moreover, the sprayed oil is acting as a thermal ballast because the electrical input is reduced by 3.5% and 3.0%, respectively, if the pump is present or not , while the specific energy requirement, accounting for the slightly reduced air flow, by 2.4% and 2.9%, respectively.

  2. Determination of the total iron content of used lubricating oils by atomic-absorption with use of emulsions.

    Science.gov (United States)

    Salvador, A; de la Guardia, M; Berenguer, V

    1983-12-01

    A new method is proposed for the determination of the total iron content of used lubricating oils. It is based on treatment of the samples with a mixture of hydrofluoric and nitric acids (without destruction of the organic matter) and emulsification, followed by atomic-absorption measurement. This allows the use of aqueous standards and provides a simple, rapid, inexpensive and accurate method, that is not affected by the particle size of the solids in the oil.

  3. Effect of Ultrasonic Vibration on the Behavior of Antifriction and Wear Resistance of Al2O3/Al2O3 Ceramic Friction Pairs Under Oil Lubrication

    Science.gov (United States)

    Dong, X. Y.; Qiao, Y. L.; Zang, Y.; Cui, Q. S.

    The behavior of antifriction and wear resistance of Al2O3/Al2O3 ceramic friction pairs lubricated by four different lubrication oils under ultrasonic vibration was studied. The surface morphologies of wear scare was analyzed by metallographic microscope. The effect mechanism of ultrasonic vibration on frictional pairs under different lubrication oils was discussed. The studied results showed that, ultrasonic vibration would improve the behavior of antifriction and wear resistance of the Al2O3/Al2O3 ceramic friction pairs under various lubrication oils.The improving would be dramaticer when the viscosity of lubrication oil was low. Ultrasonic vibration decreased the friction coefficient and wear volume 12.9% and 38.7% respectively, when the lubrication oil was 6#,the viscosity of which is 39.77 mm2/s. When the lubrication oil was 150BS, the viscosity of which is 549.69 mm2/s, ultrasonic vibration made friction coefficient and wear volume decreased 4.6% and 11.6% respectively.The effect of ultrasonic vibration on the behavior of antifriction and wear resistance of Al2O3/Al2O3 ceramic friction pairs was determined by the formation and the destruction of oil film on the friction surface and the upward floatage created by ultrasonic vibration.

  4. Experimental Studies on a Single Stage Stirling Type Pulse Tube Cryocooler Driven by Oil-Lubricated Compressor

    Science.gov (United States)

    Jia, Ren; Jianying, Hu; Ercang, Luo; Xiaotao, Wang

    2010-04-01

    Because lubricating oil for moving parts is not allowed to go into the pulse tube cryocooler, Stirling type pulse tube cryocoolers are generally driven by oil-free compressors although oil-lubricated compressors are much cheaper and facile. Recently, it was proposed that an acoustic transparent and oil blocking diaphragm could be employed to separate the compressor and the cryocooler. Thus, the cryocooler can be driven by oil-lubricated compressors. In this paper, a pulse tube cryocooler is designed to match a crankcase compressor. Although the efficiency of the crankcase compressor is lower compared with the oil-free linear compressor, the crankcase compressor can easily work at lower frequency which results in higher efficiency for the cryocooler. So the relative high performance of the whole system can be maintained. In this system, the cryocooler delivers 28.5 W of cooling at 80 K with 680 W of electrical input power and operates at 15 Hz. The corresponding Carnot efficiency is 11.52%.

  5. Variable resistance constant tension and lubrication device. [using oil-saturated leather wiper

    Science.gov (United States)

    Smith, H. J. (Inventor)

    1974-01-01

    A variable resistance device is described which includes a cylindrical housing having elongated resistance wires. A movable arm having a supporting block carried on the outer end is rotatably carried by the cylindrical housing. An arcuate steel spring member is pivotally supported by the movable arm. A leather wiper member is carried adjacent to one end of the spring steel member, and an electrically conductive surface is carried adjacent to the other end. The supporting block maintains the spring steel member in compression so that a constant pressure is applied to the conductive end of the spring steel member and the leather wiper. The leather wiper is saturated with a lubricating oil for maintaining the resistance wire clean as the movable arm is manipulated.

  6. Assessment of the bacterial community of soils contaminated with used lubricating oil by PCR-DGGE

    Directory of Open Access Journals (Sweden)

    Naruemon Meeboon

    2016-12-01

    Full Text Available The diversity of indigenous bacteria in three soils contaminated with used lubricating oil (ULO was determined and compared using molecular analysis of bacteria cultured during the enrichment process. Sequencing analyses demonstrated that the majority of the DGGE bands in enrichment cultures were affiliated with four phyla of the domain, Bacteria: α, β, γ- Proteobacteria, Bacteroidetes, Firmicutes and Actinobacteria. Soil C had a higher ULO contamination level than soil A and B, which may explain why enrichment culture C had the greatest diversity of bacteria, but further studies would be needed to determine whether ULO concentration results in higher diversity of ULO-degraders in soils. The diversity of ULO-degraders detected in these three different soils suggests that biostimulation methods for increasing the activity of indigenous microorganisms may be a viable approach to bioremediation, and that future studies to determine how to increase their activity in situ are warranted.

  7. Biosurfactant Production by Bacillus salmalaya for Lubricating Oil Solubilization and Biodegradation

    Directory of Open Access Journals (Sweden)

    Arezoo Dadrasnia

    2015-08-01

    Full Text Available This study investigated the capability of a biosurfactant produced by a novel strain of Bacillus salmalaya to enhance the biodegradation rates and bioavailability of organic contaminants. The biosurfactant produced by cultured strain 139SI showed high physicochemical properties and surface activity in the selected medium. The biosurfactant exhibited a high emulsification index and a positive result in the drop collapse test, with the results demonstrating the wetting activity of the biosurfactant and its potential to produce surface-active molecules. Strain 139SI can significantly reduce the surface tension (ST from 70.5 to 27 mN/m, with a critical micelle concentration of 0.4%. Moreover, lubricating oil at 2% (v/v was degraded on Day 20 (71.5. Furthermore, the biosurfactant demonstrated high stability at different ranges of salinity, pH, and temperature. Overall, the results indicated the potential use of B. salmalaya 139SI in environmental remediation processes.

  8. The Effect of Paraffinic Mineral Oil Lubrication in Cold Forward Extrusion

    Directory of Open Access Journals (Sweden)

    Mohd Hafis - Sulaiman

    2011-09-01

    Full Text Available This paper presents the results of cold forward extrusion modelling and the analysis of the contact sliding behaviour on the die-billet surface by paraffinic mineral oil lubrication with kinematic viscosity of 92 mm2/s at 40 °C. The analysis dealt with the plasticity flow that was investigated by finite element method in order to identify the loads acting on the billet. The finite element analysis of stresses was performed based on load distributions calculated from experimental test. The time behaviour of the displacements on the billet was then used as inputs for the extrusion model. The present method provided good results with reduced computation time. The results of the extrusion model revealed that the zones of high stress situated at the sharp edges of the die, which explains the observed extrusion force to reach a peak value.

  9. Determination of calcium, magnesium and zinc in unused lubricating oils by atomic absorption spectroscopy.

    Science.gov (United States)

    Udoh, A P

    1995-12-01

    Varying concentrations of lanthanum and strontium were added to solutions of ashed unused lubricating oils for the determination of calcium, magnesium and zinc content using flame atomic absorption spectrophotometry. At least 3000 mug g(-1) of lanthanum or strontium was required to completely overcome the interference of the phosphate ion, PO(3-)(4), and give peak values for calcium. The presence of lanthanum or strontium did not cause an appreciable increase in the amount of magnesium and zinc obtained from the analyses. The method is fast and reproducible, and the coefficients of variation calculated for the elements using one of the samples were 1.6% for calcium, 3.5% for magnesium and 0.2% for zinc. Results obtained by this method were better than those obtained by other methods for the same samples.

  10. New air conditioner by RMF prevents water in lubricating oils; Neu: Air-Conditioner vom RMF kontra Wasser im Schmieroel

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2001-07-01

    During standstill, water condensation in wind power systems will affect the lubricating properties of the lubricating oil due to oxidation effects. This will result in early failure and irrepairable damage in mechanical components like toothing and rolling bearings. RMF Deutschland, based in Nordorf and Wiesbaden, offer a solution to prevent this. [German] Bei Stillstaenden der Windkraftanlage bildet sich Kondenswasser in nicht unerheblichen Umfang. Bekannterweise beeinflussen schon geringe Wasseranteile die Schmierfaehigkeit und Eigenschaften des Schmieroels (Oxidation im Oel). Ergebnisse sind vorzeitige Ausfaelle und irreparable Schaeden an den mechanischen Bauteilen wie Verzahnung und Waelzlager. RMF Deutschland aus Nordorf und Wiesbaden bietet die Loesung, hier vorbeugend einzugreifen. (orig.)

  11. Upgrading of raw tall oil soap into fuel oils and lubricants; Raakasuovan jalostus poltto- ja voiteluoeljyksi

    Energy Technology Data Exchange (ETDEWEB)

    Oasmaa, A.; Arpiainen, V.; McKeough, P.; Tapola, E.; Haekkinen, R.; Kuoppala, E.; Koskela, K. [VTT Energy, Jyvaeskylae (Finland). Energy Production Technologies

    1997-12-01

    Thermochemical processing of tall oil soap originating from various mixtures of birch and pine has been experimentally investigated. The organic matter of tall oil soap, which is a by- product of Kraft pulping, originates mainly from wood extractives. Conventional processing of tall oil soap involves acidulation with sulphuric acid to yield crude tall oil and subsequent distillation of the oil at centralised refineries. Because tall oil originating from birch wood is far less valuable than that from pine, there is an economic incentive in the Nordic countries to develop alternative conversion processes for the tall oil soap produced at pulp mills where birch is widely used as feedstock. Furthermore, thermochemical processing of tall oil soap does not introduce sulphur into the chemical recovery cycle. This would be a significant advantage in future mills employing closure of water circuits and/or sulphur-free pulping. In small-scale experiments tall oil soaps from wood mixtures with high birch content have been processed using both liquid-phase thermal treatment and pyrolysis. The liquid-phase thermal treatment at 450 deg C under a nitrogen atmosphere yielded a good-quality oil product at high yield (about 50 % of the energy content of the tall oil soap). In the atmospheric pyrolysis of birch tall oil soap a separation of inorganic and organic constituents was obtained. The energy value of the product gases was high. Both processes are promising, but the pyrolysis alternative has the greater economic potential, providing that the promising preliminary experimental results have given a true picture of the performance of the full-scale pyrolysis process. (orig.)

  12. Simulated 'On-Line' Wear Metal Analysis of Lubricating Oils by X-Ray Fluorescence Spectroscopy

    Science.gov (United States)

    Kelliher, Warren C.; Partos, Richard D.; Nelson, Irina

    1996-01-01

    The objective of this project was to assess the sensitivity of X-ray Fluorescence Spectroscopy (XFS) for quantitative evaluation of metal particle content in engine oil suspensions and the feasibility of real-time, dynamic wear metal analysis. The study was focused on iron as the majority wear metal component. Variable parameters were: particle size, particle concentration and oil velocity. A commercial XFS spectrometer equipped with interchangeable static/dynamic (flow cell) sample chambers was used. XFS spectra were recorded for solutions of Fe-organometallic standard and for a series of DTE oil suspensions of high purity spherical iron particles of 2g, 4g, and 8g diameter, at concentrations from 5 ppm to 5,000 ppm. Real contaminated oil samples from Langley Air Force Base aircraft engines and NASA Langley Research Center wind tunnels were also analyzed. The experimental data conform the reliability of XFS as the analytical method of choice for this project. Intrinsic inadequacies of the instrument for precise analytic work at low metal concentrations were identified as being related to the particular x-ray beam definition, system geometry, and flow-cell materials selection. This work supports a proposal for the design, construction and testing of a conceptually new, miniature XFS spectrometer with superior performance, dedicated to on-line, real-time monitoring of lubricating oils in operating engines. Innovative design solutions include focalization of the incident x-ray beam, non-metal sample chamber, and miniaturization of the overall assembly. The instrument would contribute to prevention of catastrophic engine failures. A proposal for two-year funding has been presented to NASA Langley Research Center Internal Operation Group (IOG) Management, to continue the effort begun by this summer's project.

  13. [Simultaneous determination of three inorganic anions in food-grade lubricating oils by chromatography with suppressed conductivity detection].

    Science.gov (United States)

    Zhang, Liyuan; Fei, Xudong; Qiu, Feng; Lin, Miao

    2015-02-01

    An ion chromatographic (IC) method with suppressed conductivity detection was developed for the simultaneous determination of Cl-, NO3(-), SO(2-)(4) in food-grade lubricating oils. After ultrasonic extraction with 50% (v/v) methanol aqueous solution and centrifugation, the sample in aqueous phase was purified with 0. 22 µm hybrid fiber membranes, then analyzed by IC using 15 mmol/L KOH solution as eluent, and detected by a suppressed conductivity detector. Effects of the concentration and flow rate of the eluent, and the concentration of the methanol aqueous solution on the detection of the three anions were investigated. Under the optimized separation conditions, the three anions were separated completely and the system peaks didn't interfere with the determination. The calibration curves showed good linearity (R2> 0. 999) in the range of 0. 10-20. 00 mg/L. The limits of detection (LODs, S/N= 3) were 0. 01 - 0. 03 mg/kg. The average recoveries of Cl-, NO(-)3, SO(2-)4 anions were 90. 0% - 103. 6% with the relative standard deviations (RSDs) of 2. 8% - 5. 7%. This method avoids the time-consuming pretreatment process to burn or ash the oil phase matrix, and can determine the amounts of three inorganic anions (Cl-, NO(-)3, SO(2-)(4)) in food-grade lubricating oils fast and accurately. It is suitable for simultaneously separating and detecting trace inorganic anions in lubricating oils or other oil products.

  14. Marine Lubricants

    Science.gov (United States)

    Carter, B. H.; Green, D.

    Marine diesel engines are classified by speed, either large (medium speed) or very large (slow speed) with high efficiencies and burning low-quality fuel. Slow-speed engines, up to 200 rpm, are two-stroke with separate combustion chamber and sump connected by a crosshead, with trunk and system oil lubricants for each. Medium-speed diesels, 300-1500 rpm, are of conventional automotive design with one lubricant. Slow-speed engines use heavy fuel oil of much lower quality than conventional diesel with problems of deposit cleanliness, acidity production and oxidation. Lubricants are mainly SAE 30/40/50 monogrades using paraffinic basestocks. The main types of additives are detergents/dispersants, antioxidants, corrosion inhibitors, anti-wear/load-carrying/ep, pour-point depressants and anti-foam compounds. There are no simple systems for classifying marine lubricants, as for automotive, because of the wide range of engine design, ratings and service applications they serve. There are no standard tests; lubricant suppliers use their own tests or the Bolnes 3DNL, with final proof from field tests. Frequent lubricant analyses safeguard engines and require standard sampling procedures before determination of density, viscosity, flash point, insolubles, base number, water and wear metal content.

  15. Boundary lubrication of stainless steel and CoCrMo alloy based on phosphorous and boron compounds in oil-in-water emulsion

    NARCIS (Netherlands)

    Yan, J.; Zeng, X.; Ren, T.; Heide, E. van der

    2014-01-01

    Emulsion lubrication is widely used in metal forming operations and has potential applications in the biomedical field, yet the emulsion lubrication mechanism is not well understood. This work explores the possibilities of three different oil-in-water (O/W) emulsions containing dibutyl

  16. Boundary lubrication of stainless steel and CoCrMo alloy based on phosphorous and boron compounds in oil-in-water emulsion

    NARCIS (Netherlands)

    Yan, J.; Zeng, X.; Ren, T.; Heide, E. van der

    2014-01-01

    Emulsion lubrication is widely used in metal forming operations and has potential applications in the biomedical field, yet the emulsion lubrication mechanism is not well understood. This work explores the possibilities of three different oil-in-water (O/W) emulsions containing dibutyl octadecylphos

  17. 蓖麻油用作喷气燃料润滑剂的润滑性及润滑机制%Lubricity and Lubricating Mechanism of Castor Oil as Lubricity Improver of Jet Fuel

    Institute of Scientific and Technical Information of China (English)

    李进; 陈国需; 胡泽祥; 赵立涛; 杜鹏飞

    2015-01-01

    The castor oil was characterized using Infrared spectrometer and its tribological properties as anti⁃wear addi⁃tive in jet fuel were evaluated using the High Frequency reciprocating rig (HFRR).The morphologies and elemental distri⁃butions of the worn steel surface lubricated by castor oil were analyzed by means of scanning electron microscopy and EDS for discussing its lubricating mechanism.The results show that the jet fuel shows a good sensitivity to castor oil, and castor acid contributes to improve the lubricity of jet fuel.The anti⁃wear mechanism of castor oil can be concluded that castor acid is adsorbed on the metal surface physically at first, while a chemical⁃adsorbing film of containing oxygen is formed at a mass addition of castor oil, resulting in a good lubricating effect.%利用红外光谱仪分析蓖麻油结构特征,采用高频往复试验机HFRR考察蓖麻油在喷气燃料中的摩擦学性能,利用SEM及EDS能谱仪对蓖麻油润滑下的钢球磨斑形貌和表面组成进行分析,并探讨其润滑机制。结果表明,喷气燃料对蓖麻油具有较好的感受性,蓖麻油在喷气燃料中具有一定润滑作用,其作用机制可能是蓖麻酸先物理吸附在金属表面上,形成一层物理吸附膜,随着蓖麻油添加量的增加,蓖麻油开始化学吸附在金属表面上,形成了一层含氧的化学保护膜,起到了抗磨效果。

  18. Power system with an integrated lubrication circuit

    Science.gov (United States)

    Hoff, Brian D.; Akasam, Sivaprasad; Algrain, Marcelo C.; Johnson, Kris W.; Lane, William H.

    2009-11-10

    A power system includes an engine having a first lubrication circuit and at least one auxiliary power unit having a second lubrication circuit. The first lubrication circuit is in fluid communication with the second lubrication circuit.

  19. Development and validation of an environmentally friendly attenuated total reflectance in the mid-infrared region method for the determination of ethanol content in used engine lubrication oil.

    Science.gov (United States)

    Hatanaka, Rafael Rodrigues; Sequinel, Rodrigo; Gualtieri, Carlos Eduardo; Tercini, Antônio Carlos Bergamaschi; Flumignan, Danilo Luiz; de Oliveira, José Eduardo

    2013-05-15

    Lubricating oils are crucial in the operation of automotive engines because they both reduce friction between moving parts and protect against corrosion. However, the performance of lubricant oil may be affected by contaminants, such as gasoline, diesel, ethanol, water and ethylene glycol. Although there are many standard methods and studies related to the quantification of contaminants in lubricant oil, such as gasoline and diesel oil, to the best of our knowledge, no methods have been reported for the quantification of ethanol in used Otto cycle engine lubrication oils. Therefore, this work aimed at the development and validation of a routine method based on partial least-squares multivariate analysis combined with attenuated total reflectance in the mid-infrared region to quantify ethanol content in used lubrication oil. The method was validated based on its figures of merit (using the net analyte signal) as follows: limit of detection (0.049%), limit of quantification (0.16%), accuracy (root mean square error of prediction=0.089% w/w), repeatability (0.05% w/w), fit (R(2)=0.9997), mean selectivity (0.047), sensitivity (0.011), inverse analytical sensitivity (0.016% w/w(-1)) and signal-to-noise ratio (max: 812.4 and min: 200.9). The results show that the proposed method can be routinely implemented for the quality control of lubricant oils.

  20. Bio-lubricants derived from waste cooking oil with improved oxidation stability and low-temperature properties.

    Science.gov (United States)

    Li, Weimin; Wang, Xiaobo

    2015-01-01

    Waste cooking oil (WCO) was chemically modified via epoxidation using H2O2 followed by transesterification with methanol and branched alcohols (isooctanol, isotridecanol and isooctadecanol) to produce bio-lubricants with improved oxidative stability and low temperature properties. Physicochemical properties of synthesized bio-lubricants such as pour point (PP), cloud point (CP), viscosity, viscosity index (VI), oxidative stability, and corrosion resistant property were determined according to standard methods. The synthesized bio-lubricants showed improved low temperature flow performances compared with WCO, which can be attributing to the introduction of branched chains in their molecular structures. What's more, the oxidation stability of the WCO showed more than 10 folds improvement due to the elimination of -C=C-bonds in the WCO molecule. Tribological performances of these bio-lubricants were also investigated using four-ball friction and wear tester. Experimental results showed that derivatives of WCO exhibited favorable physicochemical properties and tribological performances which making them good candidates in formulating eco-friendly lubricants.

  1. Effects of fresh lubricant oils on particle emissions emitted by a modern gasoline direct injection passenger car.

    Science.gov (United States)

    Pirjola, Liisa; Karjalainen, Panu; Heikkilä, Juha; Saari, Sampo; Tzamkiozis, Theodoros; Ntziachristos, Leonidas; Kulmala, Kari; Keskinen, Jorma; Rönkkö, Topi

    2015-03-17

    Particle emissions from a modern turbocharged gasoline direct injection passenger car equipped with a three-way catalyst and an exhaust gas recirculation system were studied while the vehicle was running on low-sulfur gasoline and, consecutively, with five different lubrication oils. Exhaust particle number concentration, size distribution, and volatility were determined both at laboratory and on-road conditions. The results indicated that the choice of lubricant affected particle emissions both during the cold start and warm driving cycles. However, the contribution of engine oil depended on driving conditions being higher during acceleration and steady state driving than during deceleration. The highest emission factors were found with two oils that had the highest metal content. The results indicate that a 10% decrease in the Zn content of engine oils is linked with an 11-13% decrease to the nonvolatile particle number emissions in steady driving conditions and a 5% decrease over the New European Driving Cycle. The effect of lubricant on volatile particles was even higher, on the order of 20%.

  2. Study on application of CeO2 and CaCO3 nanoparticles in lubricating oils

    Institute of Scientific and Technical Information of China (English)

    GU Caixiang; LI Qingzhu; GU Zhuoming; ZHU Guangyao

    2008-01-01

    The ceria (CeO2) nanoparticles and calcium carbonate (CaCO3) nanoparticles were chosen as additives of anti-wear and extreme pressure for lubricating oils, and the morphology and sizes of nanoparticles were examined using Transmission Electron Microscope (TEM). The tribological performance of lubricating oils containing combined nanoparticles were determined by four-ball friction and wear tester, and the chemical composition of steel ball with worn surface were analyzed by X-ray Photoelectron Spectrum(XPS). The results showed that the lubricating oils containing combined nanoparticles had good anti-wear and friction reducing effects, and the tribological properties were optimal when WCeO2+CaCO3=0.6%, WCeO2:WCaCO3=1:1. The extreme pressure value increased by 40.25%, the wear spot diameter reduced by 33.5%, and friction coefficient reduced by 32% compared with 40CD oil. The coordinated action of big and small particles made anti-wear and friction reducing effective. Tribological chemical reactions resulting from the friction surface formed metal calcium, metal cerium and oxides film, and they could fill up the concave surface and protect the worn surface.

  3. Certain lubricating features of mineral oils that contain halog variably valent metal halides. Nekotoryye osobennosti smazyvayushchego deystviya mineral'nykh masel, soderzhashchikh galogenidy metallov peremennoy valentnosti

    Energy Technology Data Exchange (ETDEWEB)

    Babel' , V.G.; Bayramukov, M.D.; Proskuryakov, V.A.

    1982-01-01

    Discusses literature data on the mechanism of anti-wear and antiscuff properties of organic additives that contain sulphur, sulphur and phosphorus, phosphorus and chlorine, as well as some variable valent metals. Examines potential application of inorganic salts -- halides -- as additives to oils in order to improve the tribologic properties and discusses selection of an oil-soluble media and stability of lubricating formulas. Based on tests on a laboratory tribologic unit (ChShM, MI-1M) high efficiency of these additives was noted in comparison with organic acid salts and the commercial LZ-23k additive. The positive role of hydrochloric acid in small quantities is shown, when the friction surface is treated with copper and lead chlorides.

  4. Effect of Magnetic Field on Tribological Properties of Lubri-cating Oils with and without Tricresyl Phosphate

    Institute of Scientific and Technical Information of China (English)

    Jiang Zeqi; Fang Jianhua; Chen Boshui; Zheng Zhe; Li Hao; Xu Lai

    2016-01-01

    Tribological properties of neat 150 SN mineral base oil and the oils doped with different contents of tricresyl phosphate (TCP) under magnetic field or non-magnetic field were evaluated on a four-ball tribotester, on which an external magnetic field was applied. Furthermore, the morphology and the tribochemical characteristics of the worn surfaces were examined with a scanning electron microscope (SEM) and an X-ray photoelectron spectrograph (XPS). The tribological test results showed that the magnetic field improved anti-wear properties but impaired the friction-reducing properties of neat base oil and the TCP-doped oils. The worn surfaces tested in magnetic field were characterized by a slighter wear than those tested in normal condition, especially for the surfaces lubricated with the TCP-doped oils. Furthermore, the results of XPS analysis indicated that tribochemical films on the surfaces tested with TCP-doped oils were mainly composed of ferric-containing compounds such as Fe2O3, Fe3O4 and FePO4. Under the influence of a magnetic field, the atomic concentrations of oxygen and phosphorous in the frictional sub-surfaces were higher than those without magnetic impact. Thus it can be in-ferred that the improved anti-wear properties and impaired friction-reducing capabilities of lubricating oils with TCP under a magnetic field were related to the diffusion of phosphorus and oxygen into the substrate induced by magnetism.

  5. Rheology of oleo gels based on sorbitan and glyceryl mono stearates and vegetable oils for lubricating applications

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez, R.; Franco, J. M.; Delgado, M. A.; Valencia, C.; Gallegos, C.

    2011-07-01

    Oleo gels based on sorbitan and glyceryl mono stearates and different types of vegetable oils, potentially applicable as biodegradable alternatives to traditional lubricating greases, have been studied. In particular, the rheological behavior, by means of small-amplitude oscillatory shear (SAOS) measurements, and some lubrication performance-related properties (mechanical stability and tribological response) have been evaluated in this work. SAOS response and mechanical stability of these oleo gels are significantly influenced by the type and concentration of the organogelator and the vegetable oil used in the formulations. Glyceryl monostearate (GMS) generally produces stronger gels than sorbitan monostearate (SMS). The use of low-viscosity oils, such as rapeseed and soybean oils, yields gels with significantly higher values of the linear viscoelastic functions than oleo gels prepared with high-viscosity oils, i.e. castor oil. The rheological behavior of SMS-based oleo gels also depends on the cooling rate applied during the gelification process. On the other hand, the oleo gels studied present low values of the friction coefficient obtained in a tribological contact, although only some GMS/castor oil-based oleo gels exhibit a suitable mechanical stability. (Author) 28 refs.

  6. Tolerance analysis of a micro-optical detection system for on-line monitoring of lubricant oils

    Science.gov (United States)

    Van Overmeire, S.; Ottevaere, H.; Mignani, A. G.; Ciaccheri, L.; Desmet, G.; Thienpont, H.

    2010-10-01

    We present a functional prototype of a micro-optical detection unit for both absorbance and laser-induced fluorescence analysis in fused silica capillaries. Absorbance detection allows concentration measurements ranging from 0.6 µM to 12 mM, whereas fluorescence detection enables concentration measurements from 6 pM up to 0.6 mM. We make use of non-sequential optical ray tracing simulations combined with statistical design methodology to perform a complete tolerance analysis for manufacturability and we demonstrate experimentally that the efficiency of the system is insensitive to reasonable misalignment and fabrication errors of its building blocks. The possibility of using standard fabrication techniques to prototype and replicate this miniaturized plastic detection system, as well as its wide measurement range make it a good candidate for applications where low-cost and portable systems are needed to measure small volumes of liquid samples with low-level concentrations. As an example we demonstrate the use of the system for the optical characterization and differentiation of nanoliter volumes of lubricant oils.

  7. Use of multivariate statistical tool for data processing in the analysis of Cu, Cr, Fe, Pb, Mo and Mg in lubricating oil by LIBS

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Luana F.N.; Sarkis, Jorge E.S.; Bordon, Isabela C.A.C., E-mail: ludemar1@hotmail.com, E-mail: jesarkis@ipen.br, E-mail: isabella.bordon@gmail.com [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2015-07-01

    Analysis of industrial lubricants is widely used for monitoring and predicting maintenance requirements in a broad range of mechanical systems. Laser induced breakdown spectroscopy has been used to evaluate the potentiality of the technique for the determination of metals in lubricating oils. Prior to quantitative analysis, the LIBS system was calibrated using standard samples containing the elements investigated (Cu, Cr, Fe, Pb, Mo and Mg). This study presents the usefulness of multivariate statistical techniques for evaluation and interpretation of large complex data sets in order to get more information about concentration of metals in oils lubricants is related to engine wear. (author)

  8. Tribological properties of carbon nanotubes as lubricant additive in oil and water for a wheel–rail system

    Directory of Open Access Journals (Sweden)

    Jesús Antonio Carlos Cornelio

    2016-01-01

    Full Text Available Since their discovery in 1991 carbon nanotubes (CNTs have attracted much interest due to their remarkable mechanical, thermal, electrical, chemical and optical properties. In connection with their mechanical properties, CNTs have been studied in various forms for tribological applications including their use as lubricant additives for oil and water. In this work, the tribological properties of functionalized nanotubes (single and multi-walled modified with carboxylic acid when used as lubricant additives at different concentrations (0.01, 0.05% were studied under rolling-sliding conditions in a twin-disk testing machine. The tests were performed using 5% of creepage and pressures of 0.8 GPa and 1.1 GPa. The results indicated that the presence of carbon nanotubes leads to a decrease in both friction coefficient and wear rate for both systems studied (oil and water.

  9. Lubrication of Nitinol 60

    Science.gov (United States)

    Pepper, Stephen V.; DellaCorte, Christopher; Glennon, Glenn

    2010-01-01

    The mechanical properties of Nitinol 60, 60 wt% Ni, 40 wt% Ti (55 at.% Ni, 45 at.% Ti) are sufficiently attractive to warrant its consideration as a lubricated triboelement. Triboelements are always run lubricated. The ability to lubricate Nitinol 60 by the oils usually used on spacecraft mechanisms--Pennzane 2001A, Krytox 143AC and Castrol 815Z--was experimentally determined. These oils were run in the boundary lubrication regime for Nitinol 60 balls running against Nitinol 60 counterfaces in the vacuum spiral orbit tribometer. Test results consisting of the coefficient of friction versus time (friction traces) and relative degradation rates of the oils are presented. Contrary to the inability to successfully lubricate other metal alloys with high titanium content, it was found that Nitinol 60 is able to be lubricated by these oils. Overall, the results presented here indicate that Nitinol 60 is a credible candidate material for bearing applications.

  10. Towards green lubrication in machining

    CERN Document Server

    Liew Yun Hsien, Willey

    2014-01-01

    The book gives an overview of environmental friendly gaseous and vapour, refrigerated compressed gas, solid lubricant, mist lubrication, minimum quantity lubrication (MQL) and vegetable oils that can be used as lubricants and additives in industrial machining applications. This book introduces vegetable oils as viable and good alternative resources because of their environmental friendly, non-toxic and readily biodegradable nature.  The effectiveness of various types of vegetables oils as lubricants and additives in reducing wear and friction is discussed in this book. Engineers and scientist working in the field of lubrication and machining will find this book useful.

  11. Thumba (Citrullus colocynthis L. seed oil: a potential bio-lubricant base-stock

    Directory of Open Access Journals (Sweden)

    Kamalakar, K.

    2015-03-01

    Full Text Available Thumba seed oil, a minor, renewable tree borne oil, was exploited for the preparation of biolubricant base-stocks. The different base-stocks prepared were epoxy thumba oil (ETO, branched, 2-ethylhexyl ester (T2-EtHE, and polyol esters, namely, neopentyl glycol (TNPGE, trimethylolpropane (TTMPE and pentaerythritol (TPEE esters of thumba fatty acids. All the base-stocks were thoroughly characterized using spectral techniques. When evaluated for lubricant properties, ETO showed much higher viscosity (216.9 cSt, good oxidative stability (RBOT Method, ASTM D 2272 (20 min and weld load (ASTM IP 239 (180 kg behavior when compared to the branched and polyol esters. Polyol esters, T2-EtHE, TNPGE and TTMPE (−9 to −18 °C showed low pour points compared to ETO and TPEE. The thermal stabilities (Thermo gravimetric analysis, TGA of ETO and TPEE (425 °C were higher compared to other base-stocks. The lubricant properties of ETO matched well with ISO VG 220 and Aviation Grade 100 lubricant specifications, while polyol esters can be well exploited for hydraulic and metal working fluid applications.Las semillas de thumba producen un aceite de escasa importancia que ha sido explotado como base para la preparación de biolubricantes. Los diferentes derivados de thumba preparados fueron: éteres epoxi (ETO, éteres ramificados, éster de 2-etilhexilo (T2-ETHE, y los ésteres de poliol:, neopentil glicol (TNPGE, trimetilolpropano (TTMPE y pentaeritritol (TPEE. Todas las bases se caracterizaron en su totalidad utilizando técnicas espectrales. Cuando se evaluaron las propiedades del lubricante, ETO mostró una viscosidad mucho más alta (216,9 cSt, buena estabilidad a la oxidación (RBOT Método, ASTM D 2272 (20 min y buena carga (239 ASTM IP (180 kg en comparación con el comportamiento de los ésteres de poliol y los ramificados. Los ésteres de poliol, T2-EEl, TNPGE y TTMPE (−9 a −18 °C mostraron bajos puntos de fluidez en comparación con ETO y TPE. Las

  12. The Thin-Layer Microchromatography (μTLC) and TLC-FID Technique as a New Methodology in the Study of Lubricating Oils.

    Science.gov (United States)

    Nowak, Paulina; Kosińska, Judyta; Glinka, Marta; Kamiński, Marian

    2017-07-01

    This paper concerns the possibility of using TLC coupled with a flame ionization detector (FID) and micro-TLC (μTLC) as precursors for microfluidized devices of analytical techniques to identify and determine the presence and content of the petroleum/vegetable oil base in the lubricating oils applied in cutting devices (chainsaws). This research is related to the problem of ensuring, in compliance with the requirements of environmental protection, a sufficient level of biodegradability of lubricating oils emitted to the environment during operation of equipment lubricated with these oils. Such oils include those mainly used in cutting devices and emitted in the form of a mist into the environment during the operation of those devices. When oil components are eco-toxic, contamination of the environment occurs. New methodologies for the identification and determination of the petroleum oil base, which is very difficult to biodegrade, as well as the easily biodegradable ingredients of vegetable origin in the lubricating oils, are presented. The described procedures indicate in an indisputable way whether the oil contains the oil base originating from crude oil and whether it contains adequate enriching additives. The procedures also allow the assessment of the content of particular groups of constituents (μTLC) or the determination of the group composition (TLC-FID).

  13. Simulated aging of lubricant oils by chemometric treatment of infrared spectra: potential antioxidant properties of sulfur structures.

    Science.gov (United States)

    Amat, Sandrine; Braham, Zeineb; Le Dréau, Yveline; Kister, Jacky; Dupuy, Nathalie

    2013-03-30

    Lubricant oils are complex mixtures of base oils and additives. The evolution of their performance over time strongly depends on its resistance to thermal oxidation. Sulfur compounds revealed interesting antioxidant properties. This study presents a method to evaluate the lubricant oil oxidation. Two samples, a synthetic and a paraffinic base oils, were tested pure and supplemented with seven different sulfur compounds. An aging cell adapted to a Fourier Transform InfraRed (FT-IR) spectrometer allows the continuous and direct analysis of the oxidative aging of base oils. Two approaches were applied to study the oxidation/anti-oxidation phenomena. The first one leads to define a new oxidative spectroscopic index based on a reduced spectral range where the modifications have been noticed (from 3050 to 2750 cm(-1)). The second method is based on chemometric treatments of whole spectra (from 4000 to 400 cm(-1)) to extract underlying information. A SIMPLe-to-use Interactive Self Modeling Analysis (SIMPLISMA) method has been used to identify more precisely the chemical species produced or degraded during the thermal treatment and to follow their evolution. Pure spectra of different species present in oil were obtained without prior information of their existence. The interest of this tool is to supply relative quantitative information reflecting evolution of the relative abundance of the different products over thermal aging. Results obtained by these two ways have been compared to estimate their concordance.

  14. Superlubricity behaviors of Nitinol 60 alloy under oil lubrication%TiNi60合金在油润滑下的超滑行为

    Institute of Scientific and Technical Information of China (English)

    曾群锋; 董光能

    2014-01-01

    The tribological tests were performed using Nitinol 60 alloy pin sliding over GCr15 steel disc in the tribometer system. Four kinds of oils were experimentally investigated as lubrication oils for lubricating Nitinol 60 alloy in the boundary lubrication regime. The experimental results were compared with a reference dry friction. It was found that Nitinol 60 alloy can be lubricated significantly and has shown remarkable lubrication performance. A superlubricity behavior of Nitinol 60 alloy was observed under castor oil lubrication. An ultra-low coefficient of friction of Nitinol 60 alloy about 0.008 between Nitinol 60 alloy and GCr15 steel was obtained under castor oil lubrication condition after a running-in period. Accordingly, the present study is focused on the lubrication behaviors of castor oil as potential lubrication oil for Nitinol 60 alloy. In the presence of castor oil, coefficient of friction is kept at 0.008 at steady state, corresponding to so-called superlubricity regime (when sliding is then approaching pure rolling). The mechanism of superlubricity is attributed to the triboformed OH-terminated surfaces from friction-induced dissociation of castor oil and the boundary lubrication films formed on the contact surface due to high polarity and long chain of castor oil allowing strong interactions with the lubricated surfaces.%研究了4种润滑油(蓖麻油、菜籽油、透平油、石蜡油)对TiNi60合金润滑性能的影响。研究发现,TiNi60合金在可再生蓖麻油润滑下呈现出摩擦因数为0.008的超滑现象。TiNi60合金在干摩擦及4种润滑油下的销-盘摩擦磨损实验研究表明:TiNi60合金在油润滑下具有优异的摩擦学性能,蓖麻油的润滑性能最优,摩擦因数最小,长时间摩擦后摩擦副表面无可测磨损。超滑机理归纳为极性高、碳链长的蓖麻油在 TiNi60合金表面形成了边界润滑膜以及摩擦诱发的解离-OH基团形成屏蔽表面有关。

  15. Composition-Explicit Distillation Curves of Waste Lubricant Oils and Resourced Crude Oil: A Diagnostic for Re-Refining and Evaluation

    Directory of Open Access Journals (Sweden)

    Lisa Starkey Ott

    2010-01-01

    Full Text Available Abstract: Problem statement: We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications include a composition-explicit data channel for each distillate fraction and temperature measurements that are true thermodynamic state points that can be modeled with an equation of state. The composition-explicit information is achieved with a sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the method (called the advanced distillation curve technique to a variety of fluids, including simple n-alkanes, rocket propellants, gasoline, jet fuels, diesel and biodiesel fuels and crude oils (both petroleum-and bio-derived crude oils. Approach: In this study, we present the application of the method to new, recycled and resourced heavy oils. The ultimate purpose of this work is waste reduction and energy utilization, by placing the reprocessing steps on a more fundamental footing. First, we present measurements on four unused automotive crankcase oils and then four samples of used oils: automotive oil, cutting oil, transformer oil and a commingled lubricant waste stream. Using the advanced distillation curve metrology, we can distinguish between the different weights (viscosity ranges of crankcase oils and compare them to the sample of used crankcase oil. The distillation curves also provide valuable information regarding the presence or absence of low-boiling contaminants in the recycled automotive oil, such as water and gasoline. Results: Additionally, we demonstrate the evaluation of all four used lubricant oils. Then, we apply the advanced distillation curve method to a sample of crude oil prepared using a plastic waste stream from an automotive plant. Conclusion: Overall, we conclude that the composition-explicit advanced distillation curve metrology is important for understanding the boiling behavior

  16. Testing the ecotoxicology of vegetable versus mineral based lubricating oils: 1. Degradation rates using tropical marine microbes.

    Science.gov (United States)

    Mercurio, Philip; Burns, Kathryn A; Negri, Andrew

    2004-05-01

    Vegetable-derived lubricants (VDL) might be more biodegradable than mineral-derived lubricants (MDL) due to the absence of high molecular weight aromatics, but this remains largely untested in tropical conditions. In this laboratory study, the degradation rates of 2-stroke, 4-stroke and hydraulic VDLs were compared with their MDL counterparts in the presence of mangrove and coral reef microbial communities. While MDLs were comprised largely of unresolved saturated and some aromatic hydrocarbons, their VDL counterparts contained, potentially more degradable, fatty acid methyl esters. Degradation of some VDL was observed by day 7, with the 2-stroke VDL markedly consumed by mangrove microorganisms and the hydraulic VDL degraded by both microorganism communities after this short period. All of the VDL groups were significantly more degraded than the comparable MDLs mineral oil lubricants over 14 days in the presence of either mangrove or coral reef microbial communities. In general the mangrove-sourced microorganisms more efficiently degraded the lubricants than reef-sourced microorganisms.

  17. Determination of calcium, magnesium and zinc in lubricating oils by flame atomic absorption spectrometry using a three-component solution.

    Science.gov (United States)

    Zmozinski, Ariane V; de Jesus, Alexandre; Vale, Maria G R; Silva, Márcia M

    2010-12-15

    Lubricating oils are used to decrease wear and friction of movable parts of engines and turbines, being in that way essential for the performance and the increase of that equipment lifespan. The presence of some metals shows the addition of specific additives such as detergents, dispersals and antioxidants that improve the performance of these lubricants. In this work, a method for determination of calcium, magnesium and zinc in lubricating oil by flame atomic absorption spectrometry (F AAS) was developed. The samples were diluted with a small quantity of aviation kerosene (AVK), n-propanol and water to form a three-component solution before its introduction in the F AAS. Aqueous inorganic standards diluted in the same way have been used for calibration. To assess the accuracy of the new method, it was compared with ABNT NBR 14066 standard method, which consists in diluting the sample with AVK and in quantification by F AAS. Two other validating methods have also been used: the acid digestion and the certified reference material NIST (SRM 1084a). The proposed method provides the following advantages in relation to the standard method: significant reduction of the use of AVK, higher stability of the analytes in the medium and application of aqueous inorganic standards for calibration. The limits of detection for calcium, magnesium and zinc were 1.3 μg g(-1), 0.052 μg g(-1) and 0.41 μg g(-1), respectively. Concentrations of calcium, magnesium and zinc in six different samples obtained by the developed method did not differ significantly from the results obtained by the reference methods at the 95% confidence level (Student's t-test and ANOVA). Therefore, the proposed method becomes an efficient alternative for determination of metals in lubricating oil.

  18. Lubrication fundamentals

    CERN Document Server

    Pirro, DM

    2001-01-01

    This work discusses product basics, machine elements that require lubrication, methods of application, lubricant storage and handling, and lubricant conservation. This edition emphasizes the need for lubrication and careful lubricant selection.

  19. Changes in bacterial diversity associated with bioremediation of used lubricating oil in tropical soils.

    Science.gov (United States)

    Meeboon, Naruemon; Leewis, Mary-Cathrine; Kaewsuwan, Sireewan; Maneerat, Suppasil; Leigh, Mary Beth

    2017-08-01

    Used lubricating oil (ULO) is a widespread contaminant, particularly throughout tropical regions, and may be a candidate for bioremediation. However, little is known about the biodegradation potential or basic microbial ecology of ULO-contaminated soils. This study aims to determine the effects of used ULO on bacterial community structure and diversity. Using a combination of culture-based (agar plate counts) and molecular techniques (16S rRNA gene sequencing and DGGE), we investigated changes in soil bacterial communities from three different ULO-contaminated soils collected from motorcycle mechanical workshops (soil A, B, and C). We further explored the relationship between bacterial community structure, physiochemical soil parameters, and ULO composition in three ULO-contaminated soils. Results indicated that the three investigated soils had different community structures, which may be a result of the different ULO characteristics and physiochemical soil parameters of each site. Soil C had the highest ULO concentration and also the greatest diversity and richness of bacteria, which may be a result of higher nutrient retention, organic matter and cation exchange capacity, as well as freshness of oil compared to the other soils. In soils A and B, Proteobacteria (esp. Gammaproteobacteria) dominated the bacterial community, and in soil C, Actinobacteria and Firmicutes dominated. The genus Enterobacter, a member of the class Gammaproteobacteria, is known to include ULO-degraders, and this genus was the only one found in all three soils, suggesting that it could play a key role in the in situ degradation of ULO-contaminated tropical Thai soils. This study provides insights into our understanding of soil microbial richness, diversity, composition, and structure in tropical ULO-contaminated soils, and may be useful for the development of strategies to improve bioremediation.

  20. Polygenetic Aspect of Unit Theory Oil Generation

    Science.gov (United States)

    Galant, Yuri

    2015-04-01

    In the framework of a unified theory Oil Generation one of important moments is the consideration of the distribution of oil in the Earth's Crust. Analysis of the distribution of oil deposits in the Earth's Crust showed that oil distributed throughout the stratigraphic section from ancient to modern sediments and from a depth of 12 kilometers to the Earth's surface. The distribution of oil almost meets all stages of metamorphism of rocks. Correlation of the section of oil distribution to genetic types of ore deposits showed that each genetic type ore deposits has its analogue oil field . So it is possible to classify oil fields on 1) endogenous: the actual magmatic, post-magmatic, contact-metasomatic (skarn), hydrothermal, exhalation, carbonatite, pegmatite, 2) exogenous: weathering, oxidation, sedimentary,3) metamorphogenic: metamorphosed, metamorphic. Model of such distribution of oil deposits can be a process of successive formation of oil deposits of mantle degassing tube. Thus oil is polygenic by way of formation of deposits, but their source is united.

  1. Standardization of lubricating oil in transition. Requirements to and testing of industrial lubricating oils and ReadAcross possibilities; Getriebeoel-Normung im Wandel. Anforderungen an und Pruefung von Industriegetriebeoelen und ReadAcross-Moeglichkeiten

    Energy Technology Data Exchange (ETDEWEB)

    Spilker, Manfred [TOTAL Deutschland GmbH, Eschweiler (Germany)

    2012-07-01

    Standards and specifications are always a compromise in between producer, distributor and end user. Beside the test methods for lubricants there are different standards with minimum requirements important for the contract partners. In this presentation the main aims and rules and the most important messages of minimum requirement standards are reported by using the gear oil standard DIN 51517 as an example. Actual new developments, e.g. read across regulations concerning the different viscosities (ISO VG) are described in details and discussed. The chemical and physical as well as the judicial advantages and disadvantages are described. Last not least the costs, in this case the continuously increasing test costs for lubricants, are part of the reflection. (orig.)

  2. A Comparative Experimental Analysis of Tribological Properties Between Commercial Mineral Oil and Neat Castor Oil using Taguchi Method in Boundary Lubrication Regime

    Directory of Open Access Journals (Sweden)

    S. Bhaumik

    2016-03-01

    Full Text Available The present work aims to carry out a comparative experimental analysis of tribological properties of 372cSt mineral oil and 229cSt castor oil. The antiwear and extreme pressure properties of both the oils have been analysed according to ASTM G 99 and ASTM D-2783 standards. The surfaces of the balls and pins after tribo tests have been analysed using Scanning Electron Microscope (SEM images. The present test results predict that the antiwear and extreme pressure properties in case of the selected commercially available mineral oil are better than neat castor oil. Both coefficient of friction and frictional force increased by 16-42 % and 16-35 % respectively in case of neat castor oil as compared with that of the mineral oil. The load carrying capacity in case of mineral oil has been found to be 250 kg while in case of castor oil it has been found to be 126 kg. SEM images show a higher plastic deformation in case of castor oil as compared to the mineral oil. Both mineral oil and castor oil showed surface deteriorations and increase in roughness after 40 hrs of intermittent running during scuffing test. Thus, the present investigation indicates that the tribological properties of neat castor are inferior to that of mineral oil although close observation of the results shows that both AW and EP properties of neat castor oil are much closer to that of commercial mineral oil. Thus, the present work would help in formulating castor oil based new bio lubricants with better anti wear and extreme pressure properties

  3. Limits of Lubrication in

    DEFF Research Database (Denmark)

    Olsson, David Dam

    of different lubricants indicate that both commercial and prototype, environmental friendly lubricants do not perform as well as hazardous lubricants such as chlorinated paraffin oils. Dry-in lubricants and polymer-coated sheets have been found to perform very poorly in punching and blanking due to shearing......-models corresponds well to experimental results in terms of lubricant film breakdown and subsequently pick-up development. Punching and blanking have been investigated regarding tribological conditions in case of using stainless steel workpiece materials. However, this has called for development of a new test method...

  4. New Method to Produce an Industrial Lubrication Fluid from Vegetable Oil-based Materials

    Science.gov (United States)

    The projected demand for industrial and automotive lubricants in the U.S. is ~2.6 billion gallons by 2017, where bio-based lubricants will play an increasing role, from a share of 0.6% today to a possible 1.2% by 2017. This is accompanied by the expected price increase to >$7.00/gallon which will g...

  5. Corrosion protection of steel by thin coatings of starch-oil dry lubricants

    Science.gov (United States)

    Corrosion of materials is one of the most serious and challenging problems faced worldwide by industry. Dry lubricants reduce friction between two metal surfaces. This research investigated the inhibition of corrosive behavior a dry lubricant formulation consisting of jet-cooked corn starch and soyb...

  6. Uniting Superhydrophobic, Superoleophobic and Lubricant Infused Slippery Behavior on Copper Oxide Nano-structured Substrates

    Science.gov (United States)

    Ujjain, Sanjeev Kumar; Roy, Pritam Kumar; Kumar, Sumana; Singha, Subhash; Khare, Krishnacharya

    2016-01-01

    Alloys, specifically steel, are considered as the workhorse of our society and are inimitable engineering materials in the field of infrastructure, industry and possesses significant applications in our daily life. However, creating a robust synthetic metallic surface that repels various liquids has remained extremely challenging. The wettability of a solid surface is known to be governed by its geometric nano-/micro structure and the chemical composition. Here, we are demonstrating a facile and economical way to generate copper oxide micro-nano structures with spherical (0D), needle (1D) and hierarchical cauliflower (3D) morphologies on galvanized steel substrates using a simple chemical bath deposition method. These nano/micro textured steel surfaces, on subsequent coating of a low surface energy material display excellent superhydrophobic, superoleophobic and slippery behavior. Polydimethylsiloxane coated textured surfaces illustrate superhydrophobicity with water contact angle about 160°(2) and critical sliding angle ~2°. When functionalized with low-surface energy perfluoroalkylsilane, these surfaces display high repellency for low surface tension oils as well as hydrocarbons. Among them, the hierarchical cauliflower morphology exhibits re-entrant structure thereby showing the best superoleophobicity with contact angle 149° for dodecane. Once infused with a lubricant like silicone oil, they show excellent slippery behavior with low contact angle hysteresis (~ 2°) for water drops. PMID:27752098

  7. Uniting Superhydrophobic, Superoleophobic and Lubricant Infused Slippery Behavior on Copper Oxide Nano-structured Substrates

    Science.gov (United States)

    Ujjain, Sanjeev Kumar; Roy, Pritam Kumar; Kumar, Sumana; Singha, Subhash; Khare, Krishnacharya

    2016-10-01

    Alloys, specifically steel, are considered as the workhorse of our society and are inimitable engineering materials in the field of infrastructure, industry and possesses significant applications in our daily life. However, creating a robust synthetic metallic surface that repels various liquids has remained extremely challenging. The wettability of a solid surface is known to be governed by its geometric nano-/micro structure and the chemical composition. Here, we are demonstrating a facile and economical way to generate copper oxide micro-nano structures with spherical (0D), needle (1D) and hierarchical cauliflower (3D) morphologies on galvanized steel substrates using a simple chemical bath deposition method. These nano/micro textured steel surfaces, on subsequent coating of a low surface energy material display excellent superhydrophobic, superoleophobic and slippery behavior. Polydimethylsiloxane coated textured surfaces illustrate superhydrophobicity with water contact angle about 160°(2) and critical sliding angle ~2°. When functionalized with low-surface energy perfluoroalkylsilane, these surfaces display high repellency for low surface tension oils as well as hydrocarbons. Among them, the hierarchical cauliflower morphology exhibits re-entrant structure thereby showing the best superoleophobicity with contact angle 149° for dodecane. Once infused with a lubricant like silicone oil, they show excellent slippery behavior with low contact angle hysteresis (~ 2°) for water drops.

  8. Diester Derivatives from Chemically Modiifed Waste Cooking Oil as Substitute for Petroleum Based Lubricating Oils

    Institute of Scientific and Technical Information of China (English)

    Xiang Shuo; Chen Ligong; Xu Lan; Li Liang; Yang Xin; Zhu Liye

    2015-01-01

    In order to provide a new way for waste cooking oil (WCO) resource utilization, several diester derivatives were obtained from WCO through a three-step chemical modifications, viz.:transesterification, epoxidation and oxirane ring opening with carboxylic acids. The effects of the chain length of side chain groups on the viscosity, acid value, low temper-ature lfuidity, thermo-oxidative stability, tribological properties and surface tension of diester derivatives were investigated. The results showed that increasing the chain length of side chain groups had a positive inlfuence on the viscosity, viscosity index, acid value, pour point, friction coefifcient and wear scar diameter along with a negative inlfuence on the oxidation onset temperature, volatile loss, insoluble deposit, maximum non-seizure load and surface tension. These diester derivatives exhibited improved physicochemical and tribological properties that make themselves promising environmentally friendly biolubricant basestocks.

  9. Production of an alternative fuel by the co-pyrolysis of landfill recovered plastic wastes and used lubrication oils.

    Science.gov (United States)

    Breyer, Sacha; Mekhitarian, Loucine; Rimez, Bart; Haut, B

    2017-02-01

    This work is a preliminary study for the development of a co-pyrolysis process of plastic wastes excavated from a landfill and used lubrication oils, with the aim to produce an alternative liquid fuel for industrial use. First, thermogravimetric experiments were carried out with pure plastics (HDPE, LDPE, PP and PS) and oils (a motor oil and a mixture of used lubrication oils) in order to highlight the interactions occurring between a plastic and an oil during their co-pyrolysis. It appears that the main decomposition event of each component takes place at higher temperatures when the components are mixed than when they are alone, possibly because the two components stabilize each other during their co-pyrolysis. These interactions depend on the nature of the plastic and the oil. In addition, co-pyrolysis experiments were led in a lab-scale reactor using a mixture of excavated plastic wastes and used lubrication oils. On the one hand, the influence of some key operating parameters on the outcome of the process was analyzed. It was possible to produce an alternative fuel for industrial use whose viscosity is lower than 1Pas at 90°C, from a plastic/oil mixture with an initial plastic mass fraction between 40% and 60%, by proceeding at a maximum temperature included in the range 350-400°C. On the other hand, the amount of energy required to successfully co-pyrolyze, in lab conditions, 1kg of plastic/oil mixture with an initial plastic mass fraction of 60% was estimated at about 8MJ. That amount of energy is largely used for the thermal cracking of the molecules. It is also shown that, per kg of mixture introduced in the lab reactor, 29MJ can be recovered from the combustion of the liquid resulting from the co-pyrolysis. Hence, this co-pyrolysis process could be economically viable, provided heat losses are addressed carefully when designing an industrial reactor. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. 350MW级蓄能机组可倾瓦导轴承流体动力润滑计算%Calculation of hydrodynamic lubrication of tilting pad guide bearing for 350 MW pumped-storage units

    Institute of Scientific and Technical Information of China (English)

    范寿孝; 全日光; 朱亲林

    2015-01-01

    为了解决大型抽水蓄能机组可倾瓦导轴承性能计算的问题,笔者根据流体润滑理论,建立了大型可倾瓦导轴承的流体动力润滑数学模型,设计了计算程序,并以此程序对某350 MW级抽水蓄能机组的导轴承润滑性能进行了计算分析和研究.其结果表明,大型可倾瓦导轴承的流体动力润滑计算程序运行稳定可靠,导轴承的动力润滑性能会受到轴承负荷、机组转速、油槽进油温度等因素的影响,最高油膜温度、最小油膜厚度是制约轴承运行工况参数变化范围的关键因素.%In order to solve the calculation problem of the tilting pad guide bearing for large pumped-storage u-nits, according to hydro lubricating theory, the author established the hydrodynamic lubricating mathematical model of the tilting pad guide bearing and analyzed and studies the hydrodynamic lubrication of a 350 MW pumped-stor-age unit by the designed calculation program. The result shows that the calculation program operates stably and reli-ably. Besides, the lubricating character of guide bearing is affected by factors including bearing load, unit speed and inlet oil temperature of oil tank. The maximum oil film temperature and the minimum oil film thickness become the critical factor restricting the variation range of operating parameters.

  11. New method of simulation to evaluate the sensitivity to oxidation of lubricating oils: an aging cell coupled with fourier transform infrared spectroscopy.

    Science.gov (United States)

    Priéri, F; Gresser, E; Le Dréau, Y; Obiols, J; Kister, J

    2008-07-01

    This study presents a new method for evaluating the oxidation of lubricating oils. An aging cell adapted to a Fourier transform infrared (FT-IR) spectrometer allows the continuous and direct study of the oxidative aging of base oils. During the test, oxidation bands appeared in the spectra (carbonyl bands around 1730 cm(-1)). The graphic representation of the carbonyl band modification--using a spectroscopic index--makes it possible to monitor the evolution of the lubricant composition. Comparing the oxidation constants, determined from the kinetic plots of several base oils, makes it possible to evaluate their relative sensitivity.

  12. Assessment of gamma radiolytic degradation in waste lubricating oil by GC/MS and UV/VIS

    Science.gov (United States)

    Scapin, Marcos A.; Duarte, Celina L.; Bustillos, José Oscar W. V.; Sato, Ivone M.

    2009-07-01

    The hydrocarbons degradation by gamma irradiation of the waste automotive lubricating oil at different absorbed doses has was investigated. The waste automotive oil in a Brazilian oil recycling company was collected. This sample was fractioned and 50% and 70% (v/v) Milli-Q water were added. Each sample was irradiated with 100, 200 and 500 kGy doses using a gamma source Co-60—GAMMACELL type, with 5×10 3 Ci total activity. Gas chromatography-mass spectrometry (GC/MS) was used to identify degraded organic compounds. The mass spectra were analyzed using the mass spectral library from NIST, installed in the spectrometer. The sample irradiated at 500 kGy dose with 70% (v/v) Milli-Q water addition formed eight degradation products, namely diethanolmethylamine (C 5H 13NO), diethyldiethylene glycol (C 8H 18O 3), 1-octyn-3-ol, 4-ethyl (C 10H 18O) and 1.4-pentanediamine, N1, N1-diethyl (C 9H 22N 2). The color changing of the waste lubricating oil, for different absorbed doses, was determined by UV/VIS spectrophotometer. The related sample showed the lowest absorbance value evidencing the formation of 2-ethoxyethyl ether (C 8H 18O 3) compound.

  13. A low cost mid-infrared sensor for on line contamination monitoring of lubricating oils in marine engines

    Science.gov (United States)

    Ben Mohammadi, L.; Kullmann, F.; Holzki, M.; Sigloch, S.; Klotzbuecher, T.; Spiesen, J.; Tommingas, T.; Weismann, P.; Kimber, G.

    2010-04-01

    The chemical and physical condition of oils in marine engines must be monitored to ensure optimum performance of the engine and to avoid damage by degraded oil not adequately lubricating the engine. Routine monitoring requires expensive laboratory testing and highly skilled analysts. This work describes the adaptation and implementation of a mid infrared (MIR) sensor module for continued oil condition monitoring in two-stroke and four-stroke diesel engines. The developed sensor module will help to reduce costs in oil analysis by eliminating the need to collect and send samples to a laboratory for analysis. The online MIR-Sensor module measures the contamination of oil with water, soot, as well as the degradation indicated by the TBN (Total Base Number) value. For the analysis of water, TBN, and soot in marine engine oils, four spectral regions of interest have been identified. The optical absorption in these bands correlating with the contaminations is measured simultaneously by using a four-field thermopile detector, combined with appropriate bandpass filters. Recording of the MIR-absorption was performed in a transmission mode using a flow-through cell with appropriate path length. Since in this case no spectrometer is required, the sensor including the light source, the flowthrough- cell, and the detector can be realised at low cost and in a very compact manner. The optical configuration of the sensor with minimal component number and signal intensity optimisation at the four-field detector was implemented by using non-sequential ray tracing simulation. The used calibration model was robust enough to predict accurately the value for soot, water, and TBN concentration for two-stroke and four-stroke engine oils. The sensor device is designed for direct installation on the host engine or machine and, therefore, becoming an integral part of the lubrication system. It can also be used as a portable stand-alone system for machine fluid analysis in the field.

  14. The waste-to-energy framework for integrated multi-waste utilization: Waste cooking oil, waste lubricating oil, and waste plastics

    Energy Technology Data Exchange (ETDEWEB)

    Singhabhandhu, Ampaitepin; Tezuka, Tetsuo [Energy Economics Laboratory, Department of Socio-Environmental Energy Science, Graduate School of Energy Science, Kyoto University, Yoshida-honmachi, Sakyo-ku, Kyoto 606-8501 (Japan)

    2010-06-15

    Energy generation by wastes is considered one method of waste management that has the benefit of energy recovery. From the waste-to-energy point of view, waste cooking oil, waste lubricating oil, and waste plastics have been considered good candidates for feedstocks for energy conversion due to their high heating values. Compared to the independent management of these three wastes, the idea of co-processing them in integration is expected to gain more benefit. The economies of scale and the synergy of co-processing these wastes results in higher quality and higher yield of the end products. In this study, we use cost-benefit analysis to evaluate the integrated management scenario of collecting the three wastes and converting them to energy. We report the total heat of combustion of pyrolytic oil at the maximum and minimum conversion rates, and conduct a sensitivity analysis in which the parameters of an increase of the electricity cost for operating the process and increase of the feedstock transportation cost are tested. We evaluate the effects of economy of scale in the case of integrated waste management. We compare four cases of waste-to-energy conversion with the business as usual (BAU) scenario, and our results show that the integrated co-processing of waste cooking oil, waste lubricating oil, and waste plastics is the most profitable from the viewpoints of energy yield and economics. (author)

  15. Lubricant composition

    Energy Technology Data Exchange (ETDEWEB)

    Baile, G.H.

    1980-12-16

    Lubricating compositions and shaped articles composed thereof are described which consist essentially of about 30 to about 60% by weight of an oil of lubricating viscosity, about 20 to about 50% by weight of a high molecular weight polymer, and about 20 about 50% by weight of a heat conductive agent capable of conducting heat away from a bearing surface where it is generated. The high molecular weight polymer may, for example, be polyethylene, having average molecular weights in the range from about 1.0 X 105 to about 5.0 X 106. The oil may be a mineral oil, a diester oil or preferably a synthetic hydrocarbon oil having a viscosity in the range from about 13 to about 1200 mm''/s (Mm2/s) at 38/sup 0/C. (100/sup 0/F.) the heat conductive agent may be powdered zinc oxide, aluminum powder, or equivalents thereof in this invention. The compositions are semi-rigid gels which may be formed in a mold and used as is, or which may be shaped further after molding. The gels are formed by blending the heat conductive agent and polymer and then blending that mixture with the oil and heating to a temperature above the softening temperature of the polymer for a period of time (About 5 to about 75 minutes) sufficient that the mixture will form a firm, tough solid gel on cooling having an oily surface provided by oil exuding from the gel thus producing a lubricative mass operable for extended periods of time. The heat conductive substance dispersed in the gel aids in dissipating heat produced at the bearing surfaces during use thus improving the performance of the gel both in withstanding higher bulk operating temperatures and in resisting breakdown of the gel under prolonged use.

  16. 75 FR 22363 - United States Standards for Grades of Olive Oil and Olive-Pomace Oil

    Science.gov (United States)

    2010-04-28

    ... Agricultural Marketing Service United States Standards for Grades of Olive Oil and Olive-Pomace Oil AGENCY... Department of Agriculture (USDA) is revising the United States Standards for Grades of Olive Oil. This... the grades of olive oil and olive-pomace oil commonly accepted in the United States and abroad....

  17. Aviation Lubricants

    Science.gov (United States)

    Lansdown, A. R.; Lee, S.

    Aviation lubricants must be extremely reliable, withstand high specific loadings and extreme environmental conditions within short times. Requirements are critical. Piston engines increasingly use multi-grade oils, single grades are still used extensively, with anti-wear and anti-corrosion additives for some classes of engines. The main gas turbine lubricant problem is transient heat exposure, the main base oils used are synthetic polyol esters which minimise thermal degradation. Aminic anti-oxidants are used together with anti-wear/load-carrying, corrosion inhibitor and anti-foam additives. The majority of formulation viscosities are 5 cSt at 100°C. Other considerations are seal compatibility and coking tendency.

  18. Testing the ecotoxicology of vegetable versus mineral based lubricating oils: 2. Induction of mixed function oxidase enzymes in barramundi, Lates calcarifer, a tropical fish species.

    Science.gov (United States)

    Mercurio, Philip; Burns, Kathryn A; Cavanagh, Joanne

    2004-05-01

    An increasing number of vegetable-based oils are being developed as environmentally friendly alternatives to petroleum products. However, toxicity towards key tropical marine species has not been investigated. In this study we used laboratory-based biomarker induction experiments to compare the relative stress of a vegetable-based lubricating oil for marine 2-stroke engines with its mineral oil-based counterpart on tropical fish. The sub-lethal stress of 2-stoke outboard lubricating oils towards the fish Lates calcarifer (barramundi) was examined using liver microsomal mixed function oxidase (MFO) induction assays. This study is the first investigation into the use of this key commercial species in tropical North Queensland, Australia in stress assessment of potential hydrocarbon pollution using ethoxyresorufin O-deethylase (EROD) induction. Our results indicated that barramundi provide a wide range of inducible rates of EROD activity in response to relevant organic stressors. The vegetable- and mineral-based lubricants induced significant EROD activity at 1.0 mg kg(-1) and there was no significant difference between the two oil treatments at that concentration. At increasing concentrations of 2 and 3 mg kg(-1), the mineral-based lubricant resulted in slightly higher EROD activity than the vegetable-based lubricant. The EROD activity of control and treated barramundi are found to be within ranges for other species from temperate and tropical environments. These results indicate that vegetable-based lubricants may be less stressful to barramundi than their mineral counterparts at concentrations of lubricant > or =2 mg kg(-1). There is great potential for this species to be used in the biomonitoring of waterways around tropical North Queensland and SE Asia.

  19. Determination of antioxidants in new and used lubricant oils by headspace-programmed temperature vaporization-gas chromatography-mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Nogal Sanchez, Miguel del; Perez Pavon, Jose Luis; Garcia Pinto, Carmelo; Moreno Cordero, Bernardo [Universidad de Salamanca, Departamento de Quimica Analitica, Nutricion y Bromatologia, Salamanca (Spain); Glanzer, Paul [University of Vienna, Department of Analytical Chemistry, Vienna (Austria)

    2010-12-15

    A sensitive method is presented to determine antioxidants (2-, 3-, and 4-tert-butylphenol, 2,6-di-tert-butylphenol, 3-tert-butyl-4-hydroxyanisol, 2,6-di-tert-butyl-4-methylphenol, 1-naphthol, and diphenylamine) in new and used lubricant oil samples. Research was carried out on a GC device equipped with a headspace sampler, a programmed temperature vaporizer, and an MS detector unit. The proposed method does not require sample treatment prior to analyses, hence eliminating possible errors occurring in this step. Sample preparation is reduced when placing the oil sample (2.0 g) in the vial and adding propyl acetate (20 {mu}L). Solvent vent injection mode permits a pre-concentration of the compounds of interest in the liner filled with Tenax-TA {sup registered}, while venting other species present in the headspace. Thereby, both the life of the liner and the capillary column is prolonged, and unnecessary contamination of the detector unit is avoided. Calibration was performed by adding different concentrations of analytes to a new oil which did not contain any of the studied compounds. Limits of detection as low as 0.57 {mu}g/L (2-tert-butylphenol) with a precision lower or equal to 5.3% were achieved. Prediction of the antioxidants in new oil samples of different viscosities (5W40, 10W40, and 15W40) was accomplished with the previous calibration, and the results were highly satisfactory. To determine antioxidants in used engine oils, standard addition method was used due to the matrix effect. (orig.)

  20. A novel application of Egyptian oil shale as a filler in the production of lithium lubricating grease

    Energy Technology Data Exchange (ETDEWEB)

    Al Wakeel, M. [Ain Shams Univ., Cairo (Egypt). Geology Department; Al Adly, R. [Egyptian Petroleum Research Inst., Nasr City, Cairo (Egypt)

    2005-12-15

    This article reports on the preparation and characterization of six formulations of grease based on soybean soapstock and aromatic extracts using oil shale as a filler. The oil shale that occurs within the Quseir-Safaga district is subjected to a detailed petrography, size distribution, mineralogy, and chemical studies. The total extracted hydrocarbon content, using an organic solvent, is analyzed for molecular weight by gel permeation chromatography (GPC). The physicochemical properties of the aromatic extracts are determined. The processing conditions following the blending are optimized to produce the appropriate lithium soap structure, as well as dispersion of the filler. The work also includes a study of the competitive effectiveness of different grades of aromatic extracts and also various percentages of oil shale, along with an evaluation of their effects on the properties of formulated lubricating greases. The prepared greases are assessed in accordance with National Lubricating Grease Institute (NLGI) and Egyptian Standard (ES). It is concluded that the above-mentioned ingredients can be used for the preparation of lithium greases. (author)

  1. Formation of carbonaceous nano-layers under high interfacial pressures during lubrication with mineral and bio-based oils

    Energy Technology Data Exchange (ETDEWEB)

    Baltrus, John P. [U.S. DOE

    2014-01-01

    In order to better protect steel surfaces against wear under high loads, understanding of chemical reactions between lubricants and metal at high interfacial pressures and elevated temperatures needs to be improved. Solutions at 5 to 20 wt. % of zinc di-2-ethylhexyl dithio phosphate (ZDDP) and chlorinated paraffins (CP) in inhibited paraffinic mineral oil (IPMO) and inhibited soy bean oil (ISBO) were compared on a Twist Compression Tribotester (TCT) at 200 MPa. Microscopy of wear tracks after 10 seconds tribotesting showed much smoother surface profiles than those of unworn areas. X-ray photoelectron spectroscopy (XPS) coupled with Ar-ion sputtering demonstrated that additive solutions in ISBO formed 2–3 times thicker carbon-containing nano-layers compared to IPMO. The amounts of Cl, S or P were unexpectedly low and detectable only on the top surface with less than 5 nm penetration. CP blends in IPMO formed more inorganic chlorides than those in ISBO. It can be concluded that base oils are primarily responsible for the thickness of carbonaceous nano-layers during early stages of severe boundary lubrication, while CP or ZDDP additive contributions are important, but less significant.

  2. The influence oil film lubrication of the piston-cylinder dynamic

    Directory of Open Access Journals (Sweden)

    Adriana Tokar

    2008-10-01

    Full Text Available An analytical study of the dynamics of a piston in a reciprocating engine was conducted. The equation of Reynolds and moving of piston are derived. The analysis, which incorporates a hydrodynamic lubrication model, was applied to M501 diesel engine. The results of this study indicate that piston dynamics were found to be sensitive to piston-cylinder bore clearance, location of the wrist pin and lubricant viscosity, underscoring their importance in engine design.

  3. Determination of aluminum by electrothermal atomic absorption spectroscopy in lubricating oils emulsified in a sequential injection analysis system.

    Science.gov (United States)

    Burguera, José L; Burguera, Marcela; Antón, Raquel E; Salager, Jean-Louis; Arandia, María A; Rondón, Carlos; Carrero, Pablo; de Peña, Yaneira Petit; Brunetto, Rosario; Gallignani, Máximo

    2005-12-15

    The sequential injection (SIA) technique was applied for the on-line preparation of an "oil in water" microemulsion and for the determination of aluminum in new and used lubricating oils by electrothermal atomic absorption spectrometry (ET AAS) with Zeeman-effect background correction. Respectively, 1.0, 0.5 and 1.0ml of surfactants mixture, sample and co-surfactant (sec-butanol) solutions were sequentially aspirated to a holding coil. The sonication and repetitive change of the flowing direction improved the stability of the different emulsion types (oil in water, water in oil and microemulsion). The emulsified zone was pumped to fill the sampling arm of the spectrometer with a sub-sample of 200mul. Then, 10mul of this sample solution were introduced by means of air displacement in the graphite tube atomizer. This sequence was timed to synchronize with the previous introduction of 15mug of Mg(NO(3))(2) (in a 10mul) by the spectrometer autosampler. The entire SIA system was controlled by a computer, independent of the spectrometer. The furnace program was carried out by employing a heating cycle in four steps: drying (two steps at 110 and 130 degrees C), pyrolisis (at 1500 degrees C), atomization (at 2400 degrees C) and cleaning (at 2400 degrees C). The calibration graph was linear from 7.7 to 120mugAll(-1). The characteristic mass (mo) was 33.2pg/0.0044s and the detection limit was 2.3mugAll(-1). The relative standard (RSD) of the method, evaluated by replicate analyses of different lubricating oil samples varied in all cases between 1.5 and 1.7%, and the recovery values found in the analysis of spiked samples ranged from 97.2 to 100.4%. The agreement between the observed and reference values obtained from two NIST Standard Certified Materials was good. The method was simple and satisfactory for determining aluminum in new and used lubricating oils.

  4. PetroChina Continues to Restructure Lubricants Assets

    Institute of Scientific and Technical Information of China (English)

    Zhang Bingxing

    2002-01-01

    @@ PetroChina has recently separated the lubricants assets of the two oil refining enterprises at Liaohe Oil Field and Yumen Oil Field and transferred them to PetroChina Lubricating Oil Company. As a result,the lubricating oil company has currently nine regional lubricants production plants nationwide with six regional sales centers and two research centers,forming a large-scale lubricants complex with integration of production, marketing and technical development.

  5. China National United Oil Corporation in Progress

    Institute of Scientific and Technical Information of China (English)

    Ge Dongmei

    1997-01-01

    @@ Approved by the State Council and jointly established by China National Petroleum Corp.(CNPC) and China National Chemicals Import and Export Corp.(Sinochem), China National United Oil Corporation (Chinaoil) is an enterprise integrating trade and industrial production. It established itself on January 8,1993.

  6. A note on the use of the CEC L-33-A-93 test to predict the potential biodegradation of mineral oil based lubricants in soil.

    Science.gov (United States)

    Battersby, N S; Morgan, P

    1997-10-01

    The biodegradabilities of five unformulated mineral oils (brightstock, 150 SN base oil, white oil and two gas oils) were determined in the CEC L-33-A-93 test and during 20 weeks incubation in nutrient-supplemented soil microcosms. Biodegradation in both studies was measured as the loss of extractable hydrocarbon ('primary' biodegradation). There was a statistically significant (P test systems. The results indicate that the CEC method could be used as a relatively simple, quick and inexpensive test for assessing the potential biodegradation of mineral oil based lubricants in soil.

  7. Third-Party Evaluation of Petro Tex Hydrocarbons, LLC, ReGen Lubricating Oil Re-refining Process

    Energy Technology Data Exchange (ETDEWEB)

    Compere, A L [ORNL; Griffith, William {Bill} L [ORNL

    2009-04-01

    This report presents an assessment of market, energy impact, and utility of the PetroTex Hydrocarbons, LLC., ReGen process for re-refining used lubricating oil to produce Group I, II, and III base oils, diesel fuel, and asphalt. PetroTex Hydrocarbons, LLC., has performed extensive pilot scale evaluations, computer simulations, and market studies of this process and is presently evaluating construction of a 23 million gallon per year industrial-scale plant. PetroTex has obtained a 30 acre site in the Texas Industries RailPark in Midlothian Texas. The environmental and civil engineering assessments of the site are completed, and the company has been granted a special use permit from the City of Midlothian and air emissions permits for the Texas Commission on Environmental Quality.

  8. Determination of metals in lubricating oils by flame atomic absorption spectrometry using a single-bore high-pressure pneumatic nebulizer.

    Science.gov (United States)

    Mora, J; Todolí, J L; Sempere, F J; Canals, A; Hernandis, V

    2000-12-01

    The behaviour of a single-bore high-pressure pneumatic nebulizer (SBHPPN) as a tool for the analysis of lubricating oils by flame atomic absorption spectrometry (FAAS) was investigated. The effects of the sample oil content [from 10% to 100% (w/w) oil in 4-methylpentan-2-one, IBMK] and the carrier nature (IBMK and methanol) on the characteristics of the aerosols generated, on the analyte transport efficiency and on the analytical figures of merit in FAAS were studied. A pneumatic concentric nebulizer (PCN) was used for comparison. Increasing the oil content increases the viscosity of the sample. With the PCN this gives rise to coarser aerosols, making it impossible to nebulize samples with an oil content higher than 70% (w/w). Using the SBHPPN, the viscosity of the sample scarcely affects the characteristics of the primary aerosols. Hence, the SBHPPN is able, by using the appropriate carrier, to nebulize pure lubricating oils. Among the carriers tested, IBMK is the most advisable because it is fully miscible with all the oil samples. The SBHPPN provides higher sensitivities and lower limits of detection than the PCN. Compared with a method based on organic dilution, the use of the SBHPPN for the direct analysis of lubricating oils by FAAS makes it possible, in addition to increasing the analysis throughput, to detect elements at lower concentrations. Moreover, the SBHPPN provides similar results to those obtained using a previous acid digestion step.

  9. Assessment of infrared spectroscopy and multivariate techniques for monitoring the service condition of diesel-engine lubricating oils.

    Science.gov (United States)

    Caneca, Arnobio Roberto; Pimentel, M Fernanda; Galvão, Roberto Kawakami Harrop; da Matta, Cláudia Eliane; de Carvalho, Florival Rodrigues; Raimundo, Ivo M; Pasquini, Celio; Rohwedder, Jarbas J R

    2006-09-15

    This paper presents two methodologies for monitoring the service condition of diesel-engine lubricating oils on the basis of infrared spectra. In the first approach, oils samples are discriminated into three groups, each one associated to a given wear stage. An algorithm is proposed to select spectral variables with good discriminant power and small collinearity for the purpose of discriminant analysis classification. As a result, a classification accuracy of 93% was obtained both in the middle (MIR) and near-infrared (NIR) ranges. The second approach employs multivariate calibration methods to predict the viscosity of the lubricant. In this case, the use of absorbance measurements in the NIR spectral range was not successful, because of experimental difficulties associated to the presence of particulate matter. Such a problem was circumvented by the use of attenuated total reflectance (ATR) measurements in the MIR spectral range, in which an RMSEP of 3.8cSt and a relative average error of 3.2% were attained.

  10. Surface Chemistry of Aluminium Alloy Slid against Steel Lubricated by Organic Friction Modifier in Hydrocarbon Oil

    Directory of Open Access Journals (Sweden)

    Ichiro Minami

    2012-01-01

    Full Text Available The lubrication mechanism of aluminium alloy slid against steel was investigated from the standpoint of surface chemistry. Low friction and low wear were observed using glycerol mono-olate in a hydrocarbon as lubricant. Increase in the silicon content in the aluminium alloy during rubbing was observed by surface analyses using (1 Auger electron spectroscopy, (2 scanning electron microscopy along with energy dispersive X-ray spectroscopy, and (3 X-ray photoelectron spectroscopy. Mild removal of the passive state (aluminium oxide from the uppermost surface by the additive during the running-in process was proposed as the lubrication mechanism. The importance of additive chemistry that improves the running-in process was pointed out.

  11. Multi-elemental analysis of jet engine lubricating oils and hydraulic fluids and their implication in aircraft air quality incidents.

    Science.gov (United States)

    van Netten, C

    1999-05-07

    The flight crews of aircraft often report symptoms including dizziness, nausea, disorientation, blurred vision and tingling in legs and arms. Many of these incidents have been traced to contamination of cabin air with lubricating oil, as well as hydraulic fluid, constituents. Considering that these air contaminants are often subjected to temperatures in excess of 500 degrees C, a large number of different exposures can be expected. Although the reported symptoms are most consistent with exposures to volatile organic compounds, carbon monoxide, and the organophosphate constituents in these oils and fluids, the involvement of these agents has not been clearly demonstrated. Possible exposure to toxic elements, such as lead, mercury, thallium and others, have not been ruled out. In order to assess the potential of exposure to toxic elements a multi-elemental analysis was done on two hydraulic fluids and three lubricating oils which have been implicated in a number of air quality incidents. A secondary objective was to establish if the multi-elemental concentrations of the fluids tested are different enough to allow such an analysis to be used as a possible method of identifying the source of exposure that might have been present during aircraft air quality incidents. No significant concentrations of toxic elements were identified in any of the oils or hydraulic fluids. The elemental compositions of the samples were different enough to be used for identification purposes and the measurement of only three elements was able to achieve this. Whether these findings have an application, in aircraft air quality incident investigations, needs to be established with further studies.

  12. The determination of wear metals in used lubricating oils by flame atomic absorption spectrometry using sulphanilic acid as ashing agent.

    Science.gov (United States)

    Ekanem, E J; Lori, J A; Thomas, S A

    1997-11-01

    A simple and reliable ashing procedure is proposed for the preparation of used lubricating oil samples for the determination of calcium, magnesium, zinc, iron, chromium and nickel by flame atomic absorption spectrometry. Sulphanilic acid was added to oil samples and the mixture coked and the coke ashed at 550 degrees C. The solutions of the ash were analysed by flame AAS for the metals. The release of calcium, zinc, iron and chromium was improved by the addition of sulphanilic acid to samples. The relative standard deviations of metal concentration results in the initial oil samples were 1.5% for Ca (1500 mg l(-1) level), 0.3% for Mg (100 mg l(-1) level), 3.1% for Zn (1500 mg l(-1) level), 0.7% for Fe (500 mg l(-1) level), 0.02% for Cr (50 mg l(-1) level) and 0.002% for Ni (10 mg l(-1) level). The optimum sample size for efficient metal release was 20 g while the optimum sulphanilic acid to oil ratio was 0.05 g per gram of oil for Zn and Cr and 0.10 g for Ca and Fe. Results obtained by this procedure were highly reproducible and comparable with those obtained for the same samples using standard procedures.

  13. Reflections on oil crops as sources of energy. I - jojoba (Simmondsia chinensis), a lubricant of the future

    Energy Technology Data Exchange (ETDEWEB)

    Martin, G.

    1983-06-01

    It is only in the last few years that public interest has been awakened in a modest oil-yielding shrub of the desert regions of California, Arizona (USA) and Mexico: jojoba (Simmondsia chinensis). This interest would seem to be justified in view of the qualities of the oil, which is altogether similar to sperm whale oil, and the possibilities it offers, notably as a lubricant. Naturally, as it is a rare product and its domestication has barely started, it has a fabulous market value (it reaches US $200/gal in 1981), but this will drop rapidly once development programmes get under way (already in 1983 the oil was to be found at US $ 50/55 gal). One-track research would be unprofitable. This drought-resistant shrub does not offer efficiency against desertification nor as an ally in the reclamation of climatically underprivileged, depopulated regions. This article makes an approach to a strategy and gives a broad outline for a programme. (Refs. 19).

  14. Effect of Nitric Acid on the Low Fluorescing Performance of Drilling Fluid Lubricant Based Animal and Vegetable Oils

    Directory of Open Access Journals (Sweden)

    Feng-shan Zhou

    2013-01-01

    Full Text Available After synthesis of mixed fatty acid triethanolamine ester surfactant based on animal and vegetable mixed oils, the reaction solution was added into 4% (wt/wt liquid nitric acid or 9% (wt/wt solid nitric acid as eliminating fluorescent agent continuing to react from 1 to 2 hours. The low fluorescence lubricant named E167 for drilling fluid was prepared, in which maximum fluorescence intensity (Fmax was less than 10 in three-dimensional fluorescence spectra of excitation wavelength range. When the E167 was added into fresh water based drilling fluid at the dosage of 0.5% (wt/wt, the sticking coefficient reduced rate (ΔKf is 78% and the extreme pressure (E-P friction coefficient reduced rate (Δf is 79%. In the case of 4% brine mud with 0.5% (wt/wt E167 in it, the ΔKf and Δf are 75% and 62%, respectively. After the hot rolling ageing test 180°C × 16 h with the E167 was added into fresh water based drilling fluid at the dosage of 1% (wt/wt, the ΔKf and Δf are greater than 70%, which shows a much better lubrication properties of strong resistance to high temperature. The fresh water based drilling fluid which contains 1% (wt/wt E167 is almost nonfoaming even after hot rolling ageing 120°C × 16 h.

  15. Influence of the Lubricant Thermo-Piezo-Viscous Property on Hydrostatic Bearings in Oil Hydraulics

    DEFF Research Database (Denmark)

    Johansen, Per; Roemer, Daniel Beck; Andersen, Torben O.

    2016-01-01

    In fluid power machinery hydrostatic bearings are frequently used, and a first approximation approach to design is determination of a balance ratio by analytical calculations of the hydrostatic presure force. Usually this is performed assuming that the thermo-piezo-viscous property can be neglected....... However, in applications as piston machines, where pressure in many cases exceeds 200 Bar, such assumption leads to considerable error in the valance ratio prediction, due to the piezo-viscous property of the lubricant. Furthermore, the thermo-viscosity relation also has a significant influence, which...... adds to the discrepancy of such simple design approach. In this paper the hydrostatic pressure force calculation is reviewed in terms of thermohydrodynamic (THD) lubrication theory, and simple analytical approximations of the hydrostatic pressure force, incorporating the piezo-viscous and thermo...

  16. Composite Coatings with Ceramic Matrix Including Nanomaterials as Solid Lubricants for Oil-Less Automotive Applications

    Directory of Open Access Journals (Sweden)

    Posmyk A.

    2016-06-01

    Full Text Available The paper presents the theoretical basis of manufacturing and chosen applications of composite coatings with ceramic matrix containing nanomaterials as a solid lubricant (AHC+NL. From a theoretical point of view, in order to reduce the friction coefficient of sliding contacts, two materials are required, i.e. one with a high hardness and the other with low shear strength. In case of composite coatings AHC+NL the matrix is a very hard and wear resistant anodic oxide coating (AHC whereas the solid lubricant used is the nanomaterial (NL featuring a low shear strength such as glassy carbon nanotubes (GC. Friction coefficient of cast iron GJL-350 sliding against the coating itself is much higher (0.18-0.22 than when it slides against a composite coating (0.08-0.14. It is possible to reduce the friction due to the presence of carbon nanotubes, or metal nanowires.

  17. Abnormal combustion caused by lubricating oil in high BMEP gas engines

    Energy Technology Data Exchange (ETDEWEB)

    Yasueda, Shinji [Kyushu Univ. (Japan). GDEC Gas and Diesel Engine; Takasaki, Koji; Tajima, Hiroshi [Kyushu Univ. (Japan). Lab. of Engine and Combustion (ECO)

    2013-05-15

    In recent years, abnormal combustion with high peak firing pressure has been experienced on gas engines with high brake mean effective pressures. The abnormality is detected not as pre-ignition but as knocking. Research, including visualisation tests on a single-cylinder engine, has confirmed the phenomenon to be pre-ignition caused by the auto-ignition of in-cylinder lubricant, causing cyclical variations of peak firing pressure on premix combustion gas engines. (orig.)

  18. Experimental Evaluation of Lubrication Characteristics of a New Type Oil-Film Bearing Oil Using Multi-Sensor System

    Directory of Open Access Journals (Sweden)

    Jianmei Wang

    2016-12-01

    Full Text Available In order to evaluate the operating performance of a new type oil-film bearing oil S220, a new test bearing was designed based on oil-film bearing test rig. The operating temperature of S220 was tested through the thermocouples installed on a test bearing; the operating oil-film pressure was tested through pressure transducers; and the operating oil-film thickness was tested through displacement transducers. Meanwhile, M220 was also tested as a comparison, and both oils are based on mineral oil. The results showed that all property indexes of the test rig can meet the specified requirements and can guarantee the performance test of oil-film bearing oil; the operating temperature of S220 is generally equal to that of M220, and both have the same operating stability. The temperature property conforms to Formula (1 and the operating temperature under different load cases can be predicted. Although oil-film pressure of M220 is a little more stable, the oil-film pressure of S220 is similar to that of M220. Moreover, both have the similar oil-film thickness, and the oil-film thickness of S220 is slightly smaller than that of M220, especially at the beginning of operation. Ultimately, oil S220 is evaluated to be suitable for actual engineering application.

  19. Phosphorus- and sulfur-containing oligopiperylene as an additive to lubricating oils and process for its preparation

    Energy Technology Data Exchange (ETDEWEB)

    Beresnev, V.V.; Kafiyatullina, S.T.; Kirpichnikov, P.A.; Stepanov, E.A.; Yunusov, O.A.

    1980-02-25

    For the purpose of strengthening the antioxidant, antiwear, and antiseizing properties of additives for lubricating oils it is proposed to use as additive a phosphorus- and sulfur-containing oligopiperylene of the formula, (iso-C/sub 3/H/sub 7/O)/sub 2/P(S)O-(CH/sub 2/CH=CHCH(CH/sub 3/)/sub 6/)(CH/sub 2/CHACH/sub 2/CH(CH/sub 3/))/sub 4/OP(S)(O-C/sub 3/H/sub 7/-iso)/sub 2/, where A = SP(S)(O-C/sub 3/H/sub 7/ -iso)/sub 2/, and a process for preparing it has been developed. The oligopiperylenediol is caused to react with diisopropyldithiophosphoric acid in benzene medium in the presence of benzoyl peroxide at a temperature of 80-82/sup 0/.

  20. Effect of rare earths surface treatment on tribological properties of carbon fibers reinforced PTFE composite under oil-lubricated condition

    Institute of Scientific and Technical Information of China (English)

    SHANGGUAN Qianqian; CHENG Xianhua

    2008-01-01

    The effect of rare earths (RE) surface treatment of carbon fibers (CF) on tribological properties of CF reinforced polytetrafluoroethylene (PTFE) composites under oil-lubricated condition was investigated. Experimental results revealed that RE treated CF reinforced PTFE (CF/PTFE) composite had the lowest friction coefficient and wear under various applied loads and sliding speeds compared with untreated and air-oxidated composites. X-ray photoelectron spectroscopy (XPS) study of carbon fiber surface showed that, after RE treatment, oxygen concentration increased obviously, and the amount of oxygen-containing groups on CF surfaces were largely increased. The increase in the amount of oxygen-containing groups enhanced interfacial adhesion between CF and PTFE matrix. With strong interfacial adhesion of the composite, stress could be effectively transmitted to carbon fibers;carbon fibers were strongly bonded with PTFE matrix, and large scale rubbing-off of PTFE be prevented, therefore, tribological properties of the composite was improved.

  1. Direct determination of lead in urban particulate material and lubricating oil with thin silver films electrically vaporized from membrane filters

    Energy Technology Data Exchange (ETDEWEB)

    Swan, J.M.; Sacks, R.D.

    1985-06-01

    A rapid, direct method for the determination of lead in suspended solid particles is described. Particles are collected on a polycarbonate membrane filter coated with a thin film of high-purity Ag. The metal film does not affect filtration properties of the membrane. The thin film and sample are atomized and excited in the high-temperature plasma produced by the electrical vaporization of the Ag film. The Pb concentration is determined by emission spectroscopy. Sample introduction and standardization techniques are presented. Sample particle size and loading effects are considered. A high-inductance, longer-duration discharge is more useful for larger samples and for larger particles than a low-inductance, shorter-duration discharge. Analytical results are presented for Pb in NBS standard reference material SRM 1648 (urban particulate material) and lubricating oil spiked with Pb powder. 14 references, 4 figures, 3 tables.

  2. Experimental Evaluation of Lubrication Characteristics of a New Type Oil-Film Bearing Oil Using Multi-Sensor System

    OpenAIRE

    Jianmei Wang; Min Cai; Reza Malekian; Yanan Zhang; Zhixiong Li

    2016-01-01

    In order to evaluate the operating performance of a new type oil-film bearing oil S220, a new test bearing was designed based on oil-film bearing test rig. The operating temperature of S220 was tested through the thermocouples installed on a test bearing; the operating oil-film pressure was tested through pressure transducers; and the operating oil-film thickness was tested through displacement transducers. Meanwhile, M220 was also tested as a comparison, and both oils are based on mineral oi...

  3. Surface and Wear Analysis of Zinc Phosphate Coated Engine Oil Ring and Cylinder Liner Tested with Commercial Lubricant

    Directory of Open Access Journals (Sweden)

    Doğuş Özkan

    2014-09-01

    Full Text Available The objective of this study was to evaluate the tribological performance through investigating protective additive layer and friction coefficient and implementing the quantitative wear measurements on the rubbed surface of the sliding pairs. The specimens of oil ring were rubbed against cast iron engine cylinder liner under boundary lubrication conditions. The ring and liner surfaces were examined by optical, scanning electron microscope and atomic force microscopy. The elemental analysis of surfaces was performed by using energy dispersive X-ray spectroscopy. Surface observations showed that coating was removed from the ring surface. Higher levels of Ca, Zn, P, and S elemental ratios (0.93%, 0.45%, 1.55%, and 1.60% as atomic percent were detected on the cylinder liner surface. Wear width, length, and depth measurements were performed by optical and atomic force microscopies on the ring and cylinder liner surface. The results showed that wear widths for oil ring were 1.59 μm and 1.65 μm; wear widths for cylinder liner were 3.20 μm and 3.18 μm; wear depths for oil ring were 100 nm; and wear depths for cylinder liner were 482 nm. Wear data were taken mostly from the additive layer points detected by SEM and X-ray measurements.

  4. Chemicals derived from pyrolysis bio-oils as antioxidants in fuels and lubricants

    Science.gov (United States)

    Softwood and hardwood lignins and hardwood were pyrolyzed to produce bio-oils to produce lignin-derived bio-oils of which phenols were the major component. These bio-oils were extracted with alkali to yield a range of lignin-related phenols having molecular weights (MWs) from 110 to 344. When tested...

  5. ORNL-GM: Development of Ionic Liquid-Additized, GF-5/6 Compatible Low-Viscosity Oils for Automotive Engine and Rear Axle Lubrication for 4% Improved Fuel Economy

    Energy Technology Data Exchange (ETDEWEB)

    Qu, Jun [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Zhou, Yan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Luo, Huimin [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Toops, Todd J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Brookshear, Daniel W. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Stump, Benjamin C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Viola, Michael B. [General Motors (GM) Technical Center, Pontiac, MI (United States); Zreik, Khaled [General Motors (GM) Technical Center, Pontiac, MI (United States); Ahmed, Tasfia [General Motors (GM) Technical Center, Pontiac, MI (United States)

    2017-01-01

    The overall objective of this project are as follows: Further develop ionic liquid (IL)-additized lowviscosity engine oils meeting the GF-5/6 specifications and possessing superior lubricating characteristics; Expand the IL additive technology to rear axle lubricants; and Seek a combined improvement in the vehicle fuel economy

  6. Lubricants and drilling fluids from plant origin

    Energy Technology Data Exchange (ETDEWEB)

    Belorgeot, C.; Renault, P. [Institut Francais du Petrole (IFP), 92 - Rueil-Malmaison (France)

    1994-10-01

    For drilling fluids and lubricants (hydraulic fluids, un-molding oils, metal working oils and two-stroke engines oils), mineral oils present environmental risks and have to be replaced by more biodegradable products, such as vegetable bio-lubricants. First generation of bio-lubricants (colza oils, soybean oils, sun flower oils) with additives (anti- oxidants), second generation coming from the transformation of vegetable oils (polyol or fatty acids esters, dimers of fatty acids esterified with oxo alcohol, and esters of special alcohols), third generation coming from a deep transformation of vegetable oils are shortly listed with industrial applications. (A.B.). 5 tabs.

  7. Several difficult problems in lubrication

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Whether in industry or in our human life, we will encounter many lubrication problems. A goodlubricant not only should have good performance, but also should meet the needs of the specific condi-tions. Here we give some examples about the difficult problems in lubrication and their solutions. Theseexamples are: (i) hydrolysis and emulsion of ZDTP; (ii) corrosion of chlorowax; (iii) coexistence of greencompressor oil and cryogen (R-134A); (iv) lubrication of cystoscope and catheter. On the same time,some achievements in lubrication field provided by Lubrication Chemistry Laboratory of Shanghai Uni-versity will be introduced in this paper.

  8. COMPARATIVE STUDY OF SELECTED LUBRICATING PROPERTIES OF BIOFUELS

    OpenAIRE

    Leszek Gardyński; Jolanta Kałdonek

    2013-01-01

    The paper presents the research results of lubricity of selected vegetable oils, rapeseed oil methyl esters, and esters with addition of oleic acid. Higher wear of samples during lubrication by rapeseed oil methyl esters in comparison to the tested vegetable oils was obtained. The addition of oleic acid to esters resulted in the improvement of their lubricating properties.

  9. COMPARATIVE STUDY OF SELECTED LUBRICATING PROPERTIES OF BIOFUELS

    Directory of Open Access Journals (Sweden)

    Leszek Gardyński

    2013-12-01

    Full Text Available The paper presents the research results of lubricity of selected vegetable oils, rapeseed oil methyl esters, and esters with addition of oleic acid. Higher wear of samples during lubrication by rapeseed oil methyl esters in comparison to the tested vegetable oils was obtained. The addition of oleic acid to esters resulted in the improvement of their lubricating properties.

  10. X-ray fluorescence analysis of wear metals in used lubricating oils

    Science.gov (United States)

    Maddox, W. E.; Kelliher, W. C.

    1986-01-01

    Used oils from several aircraft at NASA's Langley Research Center were analyzed over a three year period using X-ray fluorescence (XRF) and atomic emission spectrometry. The results of both analyses are presented and comparisons are made. Fe and Cu data for oil from four internal combustion engines are provided and XRF and atomic emission spectrometry measurements were found to be in perfect agreement. However, distributions were found in the case of oil from a jet aircraft engine whereby the latter method gave values for total iron concentration in the oil and did not distinguish between suspended particles and oil additives. XRF does not have these particle-size limitations; moreover, it is a faster process. It is concluded that XRF is the preferred method in the construction of a man-portable oil wear analysis instrument.

  11. Current Status and Trend of Offshore-fishing Boat Lubricating Oil%近海渔船用油现状及趋势

    Institute of Scientific and Technical Information of China (English)

    张润香; 刘功德; 曹聪蕊; 邓军礼

    2015-01-01

    Numerous offshore-fishing boats are engaged in fishing operations in China, but its lubricating oil quality is at low level. The mainstream quality grade of offshore-fishing boat lubricating oil is CD in the market, and the physicochemical tar-gets of different company products are up to standard, the total base numbers are al greater than 7. 0 mgKOH/g, but the inner quality is not the same between these products because the manufacturers focus on different aspects. The fuel quality of offshore-fishing boat is bad, with high content sulfur especial y. Meanwhile fishermen have a limited knowledge, light consciousness of lubricating oil maintenance, and changing lubricating oil not in time. Those phenomena are common in the market. The market of offshore-fishing boat lubricating oil is huge, but the current lubricants developments are based on on-land diesel engine. Specific oil fitting the use condition of the engine of offshore-fishing boat better wil be pushed out in future.%我国近海渔船数量众多,用油水平总体偏低。目前市场主流油品为CD级别,主要厂家产品理化指标均合格,碱值均大于7.0 mgKOH/g,但产品内在质量略有不同,不同厂家产品关注点不一样。近海渔船燃油质量差,特别是硫含量高,而渔民油品知识有限,润滑油养护意识淡薄,换油不及时是市场普遍现象。近海渔船润滑油市场庞大,现有产品依据路上柴油机规格研制。未来可能出现专用产品,以更好的适用近海渔船的使用工况。

  12. Influencia de la lubricación en la eficiencia de engranajes de tornillo sinfín//Influence of oil lubrication on cylindrical worm gear efficiency

    Directory of Open Access Journals (Sweden)

    Gonzalo González-Rey

    2012-12-01

    Full Text Available Fue desarrollado un procedimiento para estimar la eficiencia de engranajes de tornillo sinfín cilíndrico considerando pérdidas de potencia por fricción entre flancos conjugados, tres bases de lubricantes y sistema de lubricación. El procedimiento fue validado por comparación con valores de eficiencia reportados para engranajes fabricados por una compañía especializada en engranajes. Los resultadosestablecen fuerte dependencia entre el coeficiente de fricción y la velocidad de deslizamiento hasta valores inferiores a 0.4 m/s en engranajes con aceites sintéticos y para engranajes con inmersión en aceites minerales el coeficiente de fricción de ensayo fue observado constante hasta velocidades dedeslizamiento inferiores a 0,9 m/s. Fue determinado que en sistemas de lubricación por inmersión, los aceites sintéticos en sustitución de aceites minerales mejoran como promedio en 44 % la eficiencia de engranajes de tornillo sinfín. Finalmente, fue formulado un módulo racional del engranaje orientado amaximizar la eficiencia del engranaje lubricado con aceite sintético.Palabras claves: eficiencia, engranaje, tornillo sinfín, lubricante, aceite sintético, ISO/TR 145281._______________________________________________________________________________AbstractIn this study, a general procedure is proposed for the prediction of cylindrical worm gear efficiency takinginto account friction losses between worm and wheel gear, three base oils and lubrication system. Thevalidation of procedure was achieved by comparing with values of efficiency for worm gear unitsreferenced by a German gear manufacturer company. In the case of worm gears lubricated with syntheticbase oils, results show an strong dependency between basic coefficient of friction and sliding velocity up to0,4 m/s and for dip lubrication with mineral oils the basic coefficient of friction was observed constant forsliding velocity below 0,9 m/s. Other results confirm the increase of

  13. Development of dielectric sensor to monitor the engine lubricating oil degradation

    Directory of Open Access Journals (Sweden)

    Balashanmugam Vasanthan

    2016-01-01

    Full Text Available Present day practice of following fixed schedules of oil change intervals could result in loss for the equipment owner, as the oil is not utilized up-to its maximum useful life. Similarly, the extended use of engine oil beyond maximum useful life is of high risk, which could lead irreversible and catastrophic damages to engine parts. Engine oil condition indicates the condition of engine parts, in any application. Therefore, monitoring the condition of the oil in real time is of paramount importance. Researchers had established that the engine oil degradation correlates with change in dielectric property of the engine oil. The important factor to realize the on-line real time monitoring of the changes in dielectric property of the engine oil is, the cost of dielectric sensor within affordable limit for an operator. Current work aims at developing such a low cost affordable dielectric sensor and engine oil samples (SAE 15W40 grade were collected from durability test engines used in engine test rig and on-road vehicles. These samples were tested for physical and chemical properties. Any changes in the properties, of engine oil monitored, indicate that it undergoes degradation due to usage. A prototype of capacitive type sensor was developed and validated with reference fluids. The dielectric values measured using proto type sensor in the used oil samples show a correlation with change in physical properties. This trend and thresholds of dielectric provides effective plat form to monitor the engine oil degradation. The sensor could be coupled to a suitable warning device by incorporating specific algorithms.

  14. Biobased lubricant additives

    Science.gov (United States)

    Fully biobased lubricants are those formulated using all biobased ingredients, i.e. biobased base oils and biobased additives. Such formulations provide the maximum environmental, safety, and economic benefits expected from a biobased product. Currently, there are a number of biobased base oils that...

  15. Combination of ultrasonic extraction and stripping analysis: an effective and reliable way for the determination of Cu and Pb in lubricating oils.

    Science.gov (United States)

    Munoz, Rodrigo A A; Oliveira, Pedro V; Angnes, Lúcio

    2006-01-15

    The determination of metals in lubricating oil has been used as an important way to prevent components failures, to provide environmental information and in some cases, to identify adulteration. In this work, an effective and simple procedure is proposed for Cu and Pb determination in lubricating oils. An ultrasonic bath was employed for extraction of these elements from oil samples in a mixture 1:1 (v/v) of concentrated HCl and H(2)O(2). A very efficient extraction of Cu and Pb (approximately 100%) was attained after 30 min of ultrasound, allowing the simultaneous determination of both metals using square-wave anodic stripping voltammetry at thin-film gold electrodes. The extraction procedure was performed in 4 mL polypropylene closed vessels and dozens of samples could be treated simultaneously in the same ultrasonic bath. The regions of the ultrasonic bath, where the maximum efficiency of extraction was attained were evaluated. Over the optimized region, 30 samples can be treated simultaneously. Used lubricating oils from automotive engines were analyzed by using the optimized extraction procedure.

  16. 汽轮机润滑油系统进水的治理%Management of water power plant steam turbine lubricating oil system

    Institute of Scientific and Technical Information of China (English)

    刘炜

    2014-01-01

    Combined with the moisture content of steam turbine lubricating oil exceed the standard phenomenon during the operation of the power plant, expounds the harm of water turbine lubricating oil system and cause water causes, introduces the reason of turbine shaft seal leakage, proposed to prevent water in lube oil system and reduce the lubricating oil system measures the moisture content, the favorable effect.%结合本电厂运行过程中出现的汽轮机润滑油水分含量超标现象,阐述了汽轮机润滑油系统进水的危害和引起进水原因,介绍了汽轮机轴封漏气的原因,提出了防止润滑油系统进水和降低润滑油系统中水分含量的具体措施,经过实施后效果良好。

  17. Tribological Analysis of Mg2Si Particulates Reinforced Powder Metallurgy Magnesium Alloy Composites under Oil Lubrication Condition

    Directory of Open Access Journals (Sweden)

    Katsuyoshi Kondoh

    2009-01-01

    Full Text Available For the evaluation of wear behavior of Mg composites under oil lubrication conditions, powder metallurgy Mg97Y2Zn1 alloy reinforced with additive Mg2Si particles were fabricated by the repeated plastic working (RPW and hot extrusion. The RPW process was effective in refining both Mg2Si reinforcements and α-Mg grains causing the matrix hardening. When increasing the repetition number of RPW process from 200 to 600 cycles, the particle size of Mg2Si additives changed from 8 μm to 1~2 μm, and α-Mg grain size was 1 μm or less. With regard to the defensive and offensive properties of Mg alloys reinforced with Mg2Si dispersoids, the composite had superior adhesive wear resistance compared with the conventional Mg alloys because of its extremely high microhardness of 95~180 Hv by RPW process. The uniform distribution of refined Mg2Si particles was useful for improving both defensive and offensive properties against AZ31B counter disk specimens. The Mg2Si prominent dispersoids in the matrix were also effective in forming the oil grooves around them, and caused the low and stable friction coefficient. On the other hand, in the case of the composite containing coarse Mg2Si particles, severely deep scratches were given on the counter face of the AZ31B disk, and resulted in an unstable and high friction coefficient.

  18. Antioxidants from slow pyrolysis bio-oil of birch wood: Application for biodiesel and biobased lubricants

    Science.gov (United States)

    Birch wood was slowly pyrolyzed to produce bio-oil and biochar. Slow pyrolysis conditions including reaction temperature, residence time, and particle size of the feed were optimized to maximize bio-oil yield. Particle size had an insignificant effect, whereas yields of up to 56% were achieved using...

  19. Thermo-chemical extraction of fuel oil from waste lubricating grease.

    Science.gov (United States)

    Pilusa, Tsietsi Jefrey; Muzenda, Edison; Shukla, Mukul

    2013-06-01

    This study investigated the recovery of oil from waste grease through the process of thermal degradation in an aqueous solution of potassium hydroxide (KOH) followed by solvent extraction. Waste high temperature metal bearing grease was dissolved in a 15 w/w% KOH solution at 80°C while being agitated at 2000 rpm using a shear action agitator for a period of 15 min. Two distinct layers were observed after 8 min of settling time. The top layer being of dark brown oil and the bottom layer was a heterogeneous mixture. The two layers were separated by decantation. The bottom layer was cooled down to 45°C followed by slow addition of toluene (C7H8) while agitating at 1200 rpm for 15 min to prevent solids settling and minimise rapid volatilisation of the organic compounds in the mixture. Two distinct layers were also formed, the top homogeneous mixture of light brown oil-toluene mixture and the bottom sludge layer. The solvent was recovered from the oil for re-use by fractional distillation of the homogenous mixture. It was observed that 15 w/w% potassium hydroxide solution can chemically degrade the soap matrix in the grease and extract up to 49 w/w% of the fuel oil when subjected to high shear stress at a temperature of 80°C. The 26 w/w% extraction of oil in the remaining sludge was obtained by solvent extraction process with mass ratios of sludge to solvent of 2:1. Solvent recovery of 88% by mass was obtained via fractional distillation method. The combined extraction processes brought an overall oil yield of 75 w/w% from the waste grease. The fuel oil obtained from this process has similar properties to paraffin oil and can be blended with other oils as an alternative energy source.

  20. Lubricating System of Wind Power Generator Sets Based on 51 Microcontroller Unit%基于51单片机的风力发电机组润滑系统

    Institute of Scientific and Technical Information of China (English)

    胡国强

    2013-01-01

    为解决风力发电机组各轴承及齿轮在运行时能自动加注润滑油脂的问题,通过单片机技术开发了一套独立于风电机组主控的润滑自动控制系统,利用单片机对风电机组各轴承及齿轮工作信息的采集并结合预设的工作参数,自动进行内部程序的处理,进而对润滑泵的工作状态加以控制。通过仿真验证,结果表明该系统实现了对风电机组润滑系统的自动控制。%In order to solve the problem of automatically filling in lubrication oil to each bearing and gear of wind power generator unit when they operate, this paper developed a set of lubrication autocontrol system independent of main control of wind power gen-erator sets via 51 microcontroller unit (MCU) technology. The MCU was used to collect the working information of each bearing and gear and to combine pre-set working parameters to automatically carry out internal program processing, which controlled the working state of lubrication pump further. Simulation verification shows that the system has achieved auto-control for the lubrication system of wind power generator sets.

  1. Environmental liability and life-cycle management of used lubricating oils.

    Science.gov (United States)

    Guerin, Turlough F

    2008-12-30

    Used oil handling, as a business, requires an extensive understanding by management that environmental liabilities exist through its supply chain. Findings from a review of the legal requirements of operating a used oil handling business were: understanding the transfer of ownership of used petroleum hydrocarbons is critical to any such business and how this is documented; used oil handlers are responsible for providing training to their staff, including site personnel and any third party waste contractors, and for communicating best practice procedures relating to the management of used petroleum hydrocarbons to all those individuals and organisations involved in business relationships that the used oil handling companies have; used oil handlers should audit the performance of any third party contractors that it engages to conduct work on behalf of its customers. Hypothetical situations of a company planning to enter the used oil handling market are described in relation to petroleum hydrocarbon wastes it handles to illustrate the range of potential liabilities. Companies proposing to establish a used oil handling business should ensure that they provide accurate advice to its employees, its customer's employees and to its third party contractors, all of which may be responsible for handling used petroleum hydrocarbons as part of the service it intends to provide, and that it has a well documented system addressing how environmental issues are managed.

  2. Fabrication and Wear Behavior Analysis on AlCrFeNi High Entropy Alloy Coating Under Dry Sliding and Oil Lubrication Test Conditions

    Science.gov (United States)

    Tang, Yipin; Wang, Shouren; Sun, Bin; Wang, Yan; Qiao, Yang

    2016-03-01

    In this paper, AlCrFeNi high entropy alloy coating was fabricated on the surface of Q235 steel using hot pressing sintering process. The coating has the controlled thickness size and excellent mechanical properties. Scanning electron microscopy (SEM), XRD and hardness testing method were used to study the morphology, phase structure and hardness of high entropy alloys coating. The lattice distortion plays a significant role in increasing the hardness. Coating formation mechanism caused by the element diffusion under the hot pressing effect is also discussed in the paper. Simultaneously, the dry sliding and oil lubrication wear tests, wear morphology observation and wear mechanism discussion were completed. As the result shows, AlCrFeNi high entropy alloys coating exhibits superior wear resistance either at dry sliding or oil lubrication tests owing to its hard high entropy solid solution structure.

  3. Study on a Miniature Mixed-gases Joule-Thomson Cooler Driven by an Oil-lubricated Mini-compressor for 120 K Temperature Ranges

    Science.gov (United States)

    Gong, M. Q.; Wu, J. F.; Yan, B.; Zou, X.; Zhuang, X. R.; Hu, Q. G.

    In this paper, a miniature J-T cooler using multicomponent mixtures was developed and tested, in which an oil-lubricated mini-compressor was used. Experimental tests on the performance of the miniature J-T cooler were carried out with two kinds of recuperative heat exchangers. One is a shell-and-tube heat exchanger, and the other is a plate-fin type recuperative heat exchanger with whereas a micro-channel configuration fabricated by the wire-electrode cutting method. The former one gave a no-load minimum temperature of 140 K, while the later one showsbetter performance. No-load minimum temperature of 110 K and about 4 W cooling capacity at 118 K were achieved with the plate-fin micro J-T cooler. Such miniature J-T coolers driven by oil-lubricated mini-compressors show good prospects in many applications.

  4. Self lubrication of bitumen froth in pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Joseph, D.D. [Univ. of Minnesota, Minneapolis, MN (United States)

    1997-12-31

    In this paper I will review the main properties of water lubricated pipelines and explain some new features which have emerged from studies of self-lubrication of Syncrudes` bitumen froth. When heavy oils are lubricated with water, the water and oil are continuously injected into a pipeline and the water is stable when in a lubricating sheath around the oil core. In the case of bitumen froth obtained from the Alberta tar sands, the water is dispersed in the bitumen and it is liberated at the wall under shear; water injection is not necessary because the froth is self-lubricating.

  5. Investigations on the effect of chlorine in lubricating oil and the presence of a diesel oxidation catalyst on PCDD/F releases from an internal combustion engine.

    Science.gov (United States)

    Dyke, Patrick H; Sutton, Mike; Wood, David; Marshall, Jonathan

    2007-04-01

    This paper reports on an intensive study into releases of polychlorinated dibenzo-p-dioxins (PCDD), polychlorinated furans (PCDF) and polychlorinated biphenyls (PCB) from a diesel engine and the analysis of PCDD/F and PCB in crankcase lubricating oil. Experimental conditions were set and carefully controlled in order to maximize the possible impact of, and our ability to measure the effect of, changes in the levels of chlorine in the lubricant. Emissions to air were measured using modified EPA methods following the principles of the European EN 1948 standards. A series of 40 experimental runs were completed using three reference lubricants formulated to have three levels of chlorine present as a residual component (at levels of 12, 131 and 259 mg kg(-1) or ppm). The engine was run with and without the diesel oxidation catalyst. All lubricants were realistic oils and the use of unrealistic additives or doping of components - particularly chlorine - in the fuel and lubricant was carefully avoided. Analysis of fuel and lubricant (before and after testing) samples required strenuous attention to achieve acceptable recoveries and showed non-detectable levels of PCB and PCDD/F at a detection limit of around 1.5 ng I-TEQ kg(-1) (ppt), indistinguishable from the laboratory blank. The testing demonstrated the need for extreme care to be taken in developing measurement methods that are sufficiently sensitive for measuring chlorine content of fluids and PCDD/F in oils, the latter being particularly challenging. Mean emissions of PCDD/F with the diesel oxidation catalyst in place were 23 pg I-TEQ l(-1) of fuel and with the diesel oxidation catalyst removed 97 pg I-TEQ l(-1) of fuel. The results of this testing showed that the emissions of PCDD/F were greatly reduced by the presence of a diesel oxidation catalyst in the exhaust, a finding that has not been explicitly tested in previous work. They also show that emissions from the engine were not controlled by the level of

  6. Study on the applicability of a precise, accurate method for rapid evaluation of engine and lubricant performance. [determination of wear metal in used lubricating oils

    Science.gov (United States)

    Kinard, J. T.

    1975-01-01

    The development of a procedure for obtaining data related to wear metal determinations in used lubricants is discussed. The procedure makes it possible to obtain rapid, simultaneous determinations of a number of wear metals at levels of parts per thousand to low parts per billion using a small amount of sample. The electrode assembly and instrumentation used in the process are described. Samples of data obtained from tests conducted under controlled conditions are tabulated.

  7. Analysis of quality of aviation lubricating oils by means of liquid and gas-liquid chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Kholostova, G.G.; Bakunin, V.N.; Shimonaev, G.S.

    1987-01-01

    The authors examine the basic methodological aspects of chromatographic analysis of the quality of oils for aircraft gas turbine engines, and certain relationships in oil aging that have been established on this basis. A commercial ester (designated PEE) was selected for investigation of pentaerythritol and C/sub 5/-C/sub 9/ synthetic fatty acids (SFA) which serves as the synthetic base stock for a number of aviation oils. The changes in PEE composition upon oxidation, with or without additives, were evaluated by means of gas-liquid chromatography in a Tsvet-100 chromatograph with a flame ionization detector. The results from examination of the original and oxidized PEE samples by means of gas and liquid chromatography are presented.

  8. Feasibility of Department of Defense Used Lubricating Oil Re-refining.

    Science.gov (United States)

    1983-12-01

    solid and high molecular materials are retained. Suggested variations in the process train include hydrotreating and polymeric adsorption. The Michel ...Hydrophobic, Michel & Pelton Company, Emeryville, CA, 1983. A’ 19. Coenen, Hubert, Re-refining Used Oil by Supercritical Fluid Ex- traction, Used Oil the...3.83 22. Total hourly cost $51.65 8. Costs by operating pattern (10 4 hr; $51.65/hr) Pattern Miles Callons Cost/gal Cost/gal-mi Cost/ton-mi #1 25 6 x

  9. Simulation method for diesel fuel entry into lubrication oil; Simulationsmethode fuer den Dieselkraftstoffeintrag ins Motoroel

    Energy Technology Data Exchange (ETDEWEB)

    Ehrly, Markus; Jakob, Markus; Pischinger, Stefan [RWTH Aachen (DE). Lehrstuhl fuer Verbrennungskraftmaschinen (VKA); Budde, Matthias [FEV GmbH, Aachen (Germany)

    2012-06-15

    The exhaust aftertreatment systems in today's passenger car diesel engines require a high temperature level in the exhaust or must be operated with a rich mixture for regeneration purposes. Both can be implemented using late post injections, but these lead to the well-known problem of oil dilution. As part of a FVV research project, a simulation method was developed at the Institute for Combustion Engines at RWTH Aachen University in cooperation with the Institute for Measurement Technology at the Technical University Hamburg-Harburg and the Institute for Aerospace Thermodynamics at the University Stuttgart. This simulation method allows calculating the fuel entry into engine oil. (orig.)

  10. Non-Linear Unit Root Properties of Crude Oil Production

    OpenAIRE

    Svetlana Maslyuk; Russell Smyth

    2007-01-01

    While there is good reason to expect crude oil production to be non-linear, previous studies that have examined the stochastic properties of crude oil production have assumed that crude oil production follows a linear process. If crude oil production is a non-linear process, conventional unit root tests, which assume linear and systematic adjustment, could interpret departure from linearity as permanent stochastic disturbances. The objective of this paper is to test for non-linearities and un...

  11. Testing and Modeling of Petroleum Based Lubricating Oils by an Improvised System

    Directory of Open Access Journals (Sweden)

    H. M. KEFAS

    2005-06-01

    Full Text Available The effect of temperature, pressure and time was tested on the viscosities of ten lubricant samples using 23 factorial designs, also an analysis of variance procedure and subsequently a regression model was carried out for each sample.The result showed that for samples II, V, VI and VIII temperature alone has significant effect on their viscosities while pressure, time and their interactions have no significant effect. For samples I, VII, IX and X, temperature, pressure and time have significant effect and for sample III, all the process variables and their interaction have significant effect except for the interaction between pressure and time. Samples II, V, VI and VIII are of best performance since only temperature affects their viscosities. The coefficient of regression square (R2 is 1.0 for all the samples and this shows a very good correlation between the variables.The regression model suits the experimented values close and could be used for test for the same formulation without laboratory experiment.

  12. Tappet sleeve lubrication

    Energy Technology Data Exchange (ETDEWEB)

    Kapp, G.E.

    1988-05-24

    In combination, this patent describes a non-ferrous body containing a lubricant distribution gallery, a sleeve of material diverse from that of the body and cast within the non-ferrous material thereof to form internally a bore for the reciprocating movement of a lubricated member, and an oil feed passage from the gallery through the non-ferrous material extension to the bore. The feed passage is wholly within the non-ferrous material and free of any intersection with the diverse material interface, whereby any leakage of pressure oil directly from the feed passage through the interface is avoided.

  13. Automatic determination of insolubles in lubricating oils by flow injection analysis employing an LED-photometer detector.

    Science.gov (United States)

    Pignalosa, Gustavo; Sixto, Alexandra; Knochen, Moisés

    2007-10-31

    A flow injection system is presented for the determination of the insolubles content in used lubricating oil samples. The system is based on the injection of an aliquot of the sample in a stream of organic solvent where it is dispersed, and measurement of the scattered radiation (measured as apparent absorbance) in the visible range (lambda=640nm). An LED-based photometer was used for this purpose. The whole system including sample injection and data acquisition was controlled by a personal computer. Calibration curves exhibited good linearity (h=0.415+/-0.016C+0.00+/-0.03, r(2)=0.9995, confidence level of 95%) in the range up to 2.68% (insolubles in pentane). Detection and quantification limits were respectively 0.07% and 0.16% (w/w). The method was validated by analysis of 25 real samples by the proposed method and the FTIR method finding high correlation. Waste generation and reactive consumption is much less than in the official method (ASTM D-893). The proposed method employs 25mL of kerosene per sample while the official method employs 200mL of pentane.

  14. A 3×3 wear debris sensor array for real time lubricant oil conditioning monitoring using synchronized sampling

    Science.gov (United States)

    Zhu, Xiaoliang; Du, Li; Zhe, Jiang

    2017-01-01

    A high throughput wear debris sensor consisting of 3×3 sensing channels is presented for real time online lubricant oil conditioning monitoring. Time division multiplexing was applied to the sensing channels for measuring responses of multiple channels using one set of measurement electronics. Crosstalk among the 3×3 sensing channels was eliminated by diodes that are connected in series with each channel. Parallel L-C-R resonance was also applied to each sensing coil to increase the sensitivity. Furthermore, a unique synchronized sampling method was used to reduce the date size 50 times. Finally, we demonstrated that the sensor is capable of real time detection of wear debris as small as 50 μm in SAE 0W-5 at a flow rate of 460 ml/min; the measured debris concentration is in good agreement with the estimated actual concentration. The design can be extended to a N×N sensor array for an extremely high throughput without sacrificing the sensitivity, and can potentially be used for real time wear debris monitoring for health condition of rotating or reciprocating machineries.

  15. The tribological performance and tribochemical analysis of novel borate esters as lubricant additives in rapeseed oil

    NARCIS (Netherlands)

    Yan, J.; Zeng, X.; Heide, van der E.; Ren, T.

    2014-01-01

    Two novel borate esters, tris (4-dodecylphenyl) borate and 2-(2-(4-dodecylphenoxy)-1, 3, 6, 2-dioxazaborocan-6-yl) ethanol were synthesized and applied as anti-wear and extreme pressure additives in rapeseed oil. The borate esters possess high anti-wear and extreme pressure properties. XANES and XPS

  16. Investigation of Tribological Properties of Cu Nanoparticle as Lubricating Oil Additive

    Institute of Scientific and Technical Information of China (English)

    LIU Qian; XU Yi; SHI Pei-jing; XU Bin-shi

    2004-01-01

    Cu nanoparticles with average diameter of 20 nm have been successfully prepared by chemically reduction in solution. The Cu nanoparticles have the same structure as bulk Cu and its tribological properties as additives in oil have been evaluated with a T-11 tester. The results show that Cu nanoparticles exhibit good performance in anti-wear and friction reduction.

  17. Analytical Thermal Field Theory Applicable to Oil Hydraulic Fluid Film Lubrication

    DEFF Research Database (Denmark)

    Johansen, Per; Roemer, Daniel Beck; Pedersen, Henrik C.

    2014-01-01

    An analytical thermal field theory is derived by a perturbation series expansion solution to the energy conservation equation. The theory is valid for small values of the Brinkman number and the modified Peclet number. This condition is sufficiently satisfied for hydraulic oils, whereby the analy...

  18. Process for recovering uranium from waste hydrocarbon oils containing the same. [Uranium contaminated lubricating oils from gaseous diffusion compressors

    Science.gov (United States)

    Conrad, M.C.; Getz, P.A.; Hickman, J.E.; Payne, L.D.

    1982-06-29

    The invention is a process for the recovery of uranium from uranium-bearing hydrocarbon oils containing carboxylic acid as a degradation product. In one aspect, the invention comprises providing an emulsion of water and the oil, heating the same to a temperature effecting conversion of the emulsion to an organic phase and to an acidic aqueous phase containing uranium carboxylate, and recovering the uranium from the aqueous phase. The process is effective, simple and comparatively inexpensive. It avoids the use of toxic reagents and the formation of undesirable intermediates.

  19. Application of the extraction induced by emulsion breaking for the determination of Cu, Fe and Mn in used lubricating oils by flame atomic absorption spectrometry.

    Science.gov (United States)

    Caldas, Luiz Fernando S; Brum, Daniel M; de Paula, Carlos Eduardo R; Cassella, Ricardo J

    2013-06-15

    A novel approach is proposed for the sample preparation of used lubricating oils to determine Cu, Fe and Mn by FAAS. The method is based on the extraction induced by emulsion breaking, in which the elements of interest are transferred to an aqueous phase before the measurement by FAAS. In the method, each sample of used lubricating oil was diluted with toluene (20% v/v) and the resulting solution was emulsified with a Triton X-114 solution containing HNO3. Further, the water-in-oil emulsion was broken by centrifugation for 30 min at 3500 rpm, originating a system with two well-separated phases: (i) the upper phase, containing the used lubricating oil diluted in toluene and (ii) the lower aqueous phase, containing the analytes that were extracted from oil. The lower phase was collected, diluted with water and the analytes were determined by FAAS. The optimization of the methodology was performed by studying the influence of different parameters that could affect the extraction efficiency such as the nature and concentration of the solvent used for sample dilution, the concentrations of HNO3 and Triton X-114 in the solution employed for emulsification and the operational conditions for extraction (extraction, centrifugation and sampling times). The limits of quantification for Cu, Fe and Mn were 2.9, 77 and 8.2 ng g(-1), respectively. The accuracy of the method was evaluated by comparison with the reference method based on the total digestion of the samples in a closed-vessel microwave oven. There were no statistical differences between the results obtained with the proposed method and the reference one, except for Fe in the cases where its concentration was higher than 80 µg g(-1).

  20. Treatment of S109FA Gas Power Unit Direct Current Oil Pump Failure%S109FA燃气机组直流油泵自动启动失败的处理方法

    Institute of Scientific and Technical Information of China (English)

    王平

    2015-01-01

    S109FA燃气机组正常运行时由380 V交流润滑油泵提供轴系润滑油和发电机氢气密封油;2台交流润滑油泵都故障时,直流润滑油泵自动启动代替交流润滑油泵工作;当发电机氢气密封油压力低于设定值时直流密封油泵自动启动,使发电机氢气密封油的油压力维持在合格的范围之内。本文介绍了直流润滑油泵和直流密封油泵在自动启动失败的紧急情况下的处理方法,为S109FA燃气机组和其它型号的燃气机组处理类似的故障提供参考。%S109FA gas power unit was provided by the 380V alternating current lubricant pump to fasten lubricant and generator hydro-gen to seal completely oil while it ran normally.While two alternating current lubricant pumps all broke down, the direct current lubri-cant pump automatic start instead of the alternating current lubricant pump.While the oil pressure of generator hydrogen seals was less than initial value, the direct current seal oil pump automatic start, which made the oil pressure in the qualified scope.This paper intro-duced direct current lubricant the pump and direct current seal completely an oil pump under the urgent circumstance that auto start failure of treatment.It can be a reference for the S109 FA gas power unit and other similar of the breakdown unit.

  1. Analysis of the polycyclic aromatic hydrocarbon content of petrol and diesel engine lubricating oils and determination of DNA adducts in topically treated mice by 32P-postlabelling.

    Science.gov (United States)

    Carmichael, P L; Jacob, J; Grimmer, G; Phillips, D H

    1990-11-01

    Engine lubricating oils are known to accumulate carcinogenic polycyclic aromatic hydrocarbons (PAHs) during engine running. Oils from nine petrol-powered and 11 diesel-powered vehicles, in addition to samples of unused oil, were analysed for PAH content and ability to form DNA adducts when applied topically to mouse skin. The levels of 19 PAHs, determined by GC, were in total, approximately 22 times higher in used oils from petrol engines than in oils from diesel engines. Male Parkes mice were treated with 50 microliters of oil daily for 4 days before they were killed and DNA isolated from skin and lung tissue. DNA samples were analysed by nuclease P1-enhanced 32P-postlabelling. Used oils from both diesel and petrol engines showed several adduct spots on PEI-cellulose plates at total adduct levels of up to 0.57 fmol/microgram DNA [approximately 60 times greater than in experiments with samples of unused oil in which adduct levels (0.01-0.02 fmol adducts/microgram DNA) were close to the limit of detection]. Higher adduct levels were generally formed by petrol engine oils than by diesel engine oils. Lung DNA contained similar total adduct levels to those in skin although the adduct maps were less complex. Total adduct levels correlated with extent of oil use in the engine, the total PAH concentration in oils and with the concentrations of certain individual PAHs present in the oils. An adduct spot that co-eluted with that of the major benzo[a]pyrene-DNA adduct accounted for 9-26% of the total adducts in skin DNA, and approximately 8% of the adducts in lung DNA, of mice treated with petrol engine oils. A major, and as yet unidentified, adduct spot comprised up to 30% of the total adducts in skin DNA, and up to 89% of the total adducts in lung DNA, of these animals.

  2. 7 CFR 2902.47 - Gear lubricants.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 15 2010-01-01 2010-01-01 false Gear lubricants. 2902.47 Section 2902.47 Agriculture... Gear lubricants. (a) Definition. Products, such as greases or oils, that are designed to reduce... qualifying biobased gear lubricants. By that date, Federal agencies that have the responsibility for...

  3. Lubricant test for punching and blanking

    DEFF Research Database (Denmark)

    Olsson, David Dam; Bay, Niels; Andreasen, Jan Lasson

    2003-01-01

    di $cult work piece materials like stainless steels.For this group of materials few alternatives exist as regards appropriate lubricants and many companies apply the environmentally hazardous chlorinated para $n oils in order to insure a uccessful production.In connection with development...... of alternative lubricants the present paper describes a new lubricant test for punching....

  4. Effect of cutting speed and feed in turning hardened stainless steel using coated carbide cutting tool under minimum quantity lubrication using castor oil

    Directory of Open Access Journals (Sweden)

    Mohamed Handawi Saad Elmunafi

    2015-08-01

    Full Text Available Minimum quantity lubrication is a technique to have the advantages that cutting fluids bring yet keeping their use at minimum. For the cutting fluids, inedible vegetable oils are potential for minimum quantity lubrication machining. Castor oil was selected in this study as the cutting fluid for turning of hardened stainless steel (hardness of 47–48 HRC. The hard turning was with minimum quantity lubrication (50 mL/h flow rate and 5 bar air pressure at various cutting speeds (100, 135, and 170 m/min and feeds (0.16, 0.20, and 0.24 mm/rev. The machining responses were tool life, surface roughness, and cutting forces. Design of experiments was applied to quantify the effects of cutting parameters to the machining responses. Empirical models for tool life, surface roughness, and cutting forces were developed within the range of cutting parameters selected. All machining responses are significantly influenced by the cutting speed and feed. Tool life is inversely proportional to cutting speed and feed. Surface roughness is inversely proportional to cutting speed yet is proportional to feed. Cutting forces are more influenced by feed than by cutting speed. A combination of low cutting speed and feed was the optimum cutting parameters to achieve long tool life, low surface roughness, and low cutting forces.

  5. Environmental friendly lubricants through selective hydrogenation of rapeseed oil over supported copper catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Ravasio, Nicoletta; Zaccheria, Federica; Fusi, Achille; Poli, Nicola; Psaro, Rinaldo [Centro CNR CSSCMTBSO e Dip. Chimica Inorganica Metallorganica e Analitica, Universita degli Studi di Milano, Via Venezian 21, 20133 Milan (Italy); Gargano, Michele [Dipartimento di Chimica, Universita di Bari, Via Orabona 4, 70126 Bari (Italy); Recchia, Sandro [Dipartimento Scienze CCFFMM, Universita dell' Insubria, Via Lucini 3, 22100 Como (Italy)

    2002-07-10

    Different supported copper catalysts are compared in the selective hydrogenation of vegetable oils and their methylesters. The influence of parameters such as the catalysts preparation method, the support used and the activation treatment are critically evaluated in terms of catalytic activity and selectivity. All ex situ reduced catalysts prepared by the chemisorption-hydrolysis (CH) method show better performances than the ones prepared by incipient wetness technique. These data are directly matched up to the different morphology of the supported copper particles obtained with these two methods. By using a 8% Cu/SiO{sub 2} catalyst the trienic component C18:3 can be eliminated and the dienic one lowered from 22 to 3-5% without increasing the stearic C18:0 content and limiting the cis/trans-isomerisation process. These oils, with a C18:1 content up to 88% show remarkable oxidation stability and keep fluid down to -15C.

  6. Investigation of the Thermal Stability and Tribological Behavior of Nickel-oxythiomolybdate as Solid Lubricant or Lubricating Oil Additive%硫代钼酸镍的热稳定性及其摩擦学性能研究

    Institute of Scientific and Technical Information of China (English)

    陈金荣; 李曙; 叶萍萍; 姜晓霞; 李诗卓; 杨生荣

    2001-01-01

    采用X射线衍射和电子探针鉴定了硫代钼酸镍的结构及其经不同温度加热或高温摩擦磨损试验后磨损表面产物的结构和成分,用热重法对其热稳定性进行了评价.在四球摩擦磨损试验机和销-盘式高温摩擦磨损试验机上考察了其作为油品添加剂及固体润滑剂的摩擦学特性,探讨了其作为固体润滑剂在升温过程中可能发生的化学变化及其对润滑性能的影响.结果表明:硫代钼酸镍在氮气流中表现出较好的热稳定性,在空气中于350℃左右开始发生氧化分解;其高温氧化分解产物MoO3和MoS2具有明显的减摩作用,因此硫代钼酸镍可用作室温到高温(20~800℃)下的固体润滑剂.%The thermal stability of nickel oxythiomolybdate (NiMoO2S2) andthe elemental composition of its thermally decomposed products were examined by means of electron probe micro-analysis and thermal gravimetric analysis (TGA). The tribological behavior of NiMoO2S2 powder as a solid lubricant or lubricating oil additive was investigated on a pin-on-disc friction and wear tester and a four-ball machine. As the results, NiMoO2S2 shows good thermal stability in N2, while it starts to decompose at 350 ℃ in air. It has good friction-reduction and antiwear ability either as a solid lubricant or lubricating oil additive at elevated temperature. This is attributed to its tribochemical products MoO3 and MoS2 during high temperature friction and wear test.

  7. The Lubricity of Glycerol and its Solutions

    DEFF Research Database (Denmark)

    Sivebæk, Ion Marius; Jakobsen, J.

    2016-01-01

    Glycerol has been recognised as an excellent diesel fuel and lubricant. It is a liquid that can originate from the transesterification of plant oil that also results in plant oil metyl (or ethyl) ester (biodiesel). Machine elements lubricated by glycerol show very low friction, in fact lower than...... the one predicted by hydrodynamic lubrication calculations. Addition of water to glycerol lowers the friction but increases the wear. In the present paper the lubricity (boundary lubrication performance) of glycerol and its solutions with water, ethanol and methanol is investigated. Dilution of glycerol...

  8. The investigation of different particle size magnesium-doped zinc oxide (Zn0.92Mg0.08O) nanoparticles on the lubrication behavior of paraffin oil

    Science.gov (United States)

    Kalyani; Jaiswal, V.; Rastogi, R. B.; Kumar, D.

    2015-06-01

    Magnesium-doped zinc oxide (Zn0.92Mg0.08O) (ZMO) nanoparticles of 23 nm particle size have been synthesized by auto-combustion method. The variation in particle size of these nanoparticles has been performed by their further calcination at 800 and 1000 °C for 2 h and the corresponding calcined particles are designated as ZMO-1 and ZMO-2, respectively. The nanoparticles have been characterized by powder-XRD, scanning electron microscopy (SEM), energy dispersive X-ray and transmission electron microscope. The effect of particle size on the antiwear lubrication behavior of paraffin base oil has been investigated on four-ball lubricant tester. The tribological tests of these nanoparticles as antiwear additives have been studied at an optimized concentration (0.5 %w/v) by varying load for 30 min test duration and by varying the test durations at 392 N load. Various tribological parameters such as mean wear scar diameter, friction coefficient (µ), mean wear volume, running-in and steady-state wear rates show that these nanoparticles act as efficient antiwear additives and possess high load-carrying ability. From these tribological tests it has been observed that the lubrication behavior of studied nanoparticles is strongly size-dependent. The best tribological behavior is shown by nanoparticles of the smallest size, ZMO. Being sulfur, halogen and phosphorous free, ZMO nanoparticles have potential to be used as low SAPS lubricant additives. The SEM and atomic force microscopy analysis of the worn surfaces lubricated with ZMO nanoparticles at 392 N applied load for 60 min test duration show drastic decrease in surface roughness. The values of surface roughness of different additives are in good agreement with their observed tribological behavior.

  9. The investigation of different particle size magnesium-doped zinc oxide (Zn0.92Mg0.08O) nanoparticles on the lubrication behavior of paraffin oil

    Science.gov (United States)

    Kalyani; Jaiswal, V.; Rastogi, R. B.; Kumar, D.

    2017-08-01

    Magnesium-doped zinc oxide (Zn0.92Mg0.08O) (ZMO) nanoparticles of 23 nm particle size have been synthesized by auto-combustion method. The variation in particle size of these nanoparticles has been performed by their further calcination at 800 and 1000 °C for 2 h and the corresponding calcined particles are designated as ZMO-1 and ZMO-2, respectively. The nanoparticles have been characterized by powder-XRD, scanning electron microscopy (SEM), energy dispersive X-ray and transmission electron microscope. The effect of particle size on the antiwear lubrication behavior of paraffin base oil has been investigated on four-ball lubricant tester. The tribological tests of these nanoparticles as antiwear additives have been studied at an optimized concentration (0.5 %w/v) by varying load for 30 min test duration and by varying the test durations at 392 N load. Various tribological parameters such as mean wear scar diameter, friction coefficient (µ), mean wear volume, running-in and steady-state wear rates show that these nanoparticles act as efficient antiwear additives and possess high load-carrying ability. From these tribological tests it has been observed that the lubrication behavior of studied nanoparticles is strongly size-dependent. The best tribological behavior is shown by nanoparticles of the smallest size, ZMO. Being sulfur, halogen and phosphorous free, ZMO nanoparticles have potential to be used as low SAPS lubricant additives. The SEM and atomic force microscopy analysis of the worn surfaces lubricated with ZMO nanoparticles at 392 N applied load for 60 min test duration show drastic decrease in surface roughness. The values of surface roughness of different additives are in good agreement with their observed tribological behavior.

  10. Use of nanoparticles to make mineral oil lubricants feasible for use in a residential air conditioner employing hydro-fluorocarbons refrigerants

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Ruixiang [School of Energy and Power Engineering, Xi' an Jiaotong University 710049 Xi' an (China); School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, No. 1, Zhanlan Guan Road, Beijing 100044 (China); Wu, Qingping; Wu, Yezheng [School of Energy and Power Engineering, Xi' an Jiaotong University 710049 Xi' an (China)

    2010-11-15

    The application of nano-fluids in refrigerating systems is considered to be a potential way to improve the energy efficiency and reliability of HVAC and R facilities and to make economic the use of environment-friendly refrigerants. In this paper, we report a method that uses nanoparticles to enhance the energy efficiency of retrofitted residential air conditioners (RAC) employing HFCs as alternative refrigerants. The reliability and performance of RAC with nanoparticles in the working fluid have been investigated experimentally. A new mineral-based nano-refrigeration oil (MNRO), formed by blending some nanoparticles (NiFe{sub 2}O{sub 4}) into naphthene based oil B32, was employed in the RAC using R410a as refrigerant. A method showing how to disperse the NiFe{sub 2}O{sub 4} nanoparticles in the mineral oil refrigeration lubricants is presented together with an investigation of their stability. The solubilities of the new MNRO in R134a, R407C, R410a and R425a were measured. The performances of the RAC, such as the cooling/heating capacity, the power input and the energy efficiency ratio, were determined. The results indicate that the mixture of R410a/MNRO works normally in the RAC. The cooling/heating EER of the RAC increased about 6% by replacing the Polyol-Easter oil VG 32 lubricant with MNRO. (author)

  11. KSC lubricant testing program. [lubrication characteristics and corrosion resistance

    Science.gov (United States)

    Lockhart, B. J.; Bryan, C. J.

    1973-01-01

    A program was conducted to evaluate the performance of various lubricants in use and considered for use at Kennedy Space Center (KSC). The overall objectives of the program were to: (1) determine the lubrication characteristics and relative corrosion resistance of lubricants in use and proposed for use at KSC; (2) identify materials which may be equivalent to or better than KELF-90 and Krytox 240 AC greases; and (3) identify or develop an improved lubricating oil suitable for use in liquid oxygen (LOX) pumps at KSC. It was concluded that: (1) earth gel thickened greases are very poor corrosion preventive materials in the KSC environment; (2) Halocarbon 25-5S and Braycote 656 were suitable substiutes for KELF-90 and Krytox 240 AC respectively; and (3) none of the oils evaluated possessed the necessary inertness, lubricity, and corrosion prevention characteristics for the KSC LOX pumping systems in their present configuration.

  12. Evaluation of Environmentally Acceptable Lubricants (EALS) for Dams Managed by the U.S. Army Corps of Engineers

    Science.gov (United States)

    2015-08-01

    oil had positive effects on the release of climate change constituents and reduced fossil fuel usage, but...Salimon et al. 2012). Vegetable oils are the most common and include canola oil , castor oil , palm oil , sunflower seed oil , sesame seed oil , rapeseed oil ...substances are oil and grease. Types of Lubricating Oils /Greases Mineral Oils . Typical lubricants are composed of petroleum fractions called

  13. 大豆润滑油抗氧化性的研究%Study on anti-oxidation activity of Soybean-lubricant oil

    Institute of Scientific and Technical Information of China (English)

    齐颖; 邵弘; 孙博; 周晓丹; 于殿宇

    2011-01-01

    利用氢化后的大豆油作为食品加工行业中的绿色润滑油基油,研究其在不同条件下的抗氧化性.实验结果表明:化学改性后的大豆润滑油在25℃、避光下保存较为适宜;其在使用过程中的抗氧化性明显要比大豆油好,随着温度的升高,过氧化值和酸值都升高.在60℃下添加6%的TBHQ作为润滑油添加剂,效果最佳,抗氧化性显著增强,保证了无毒性,使用周期预计为六个月.%Hydrogenated soybean oil was used as the green lubricant base oil in food processing industry,the oxidation resistance under different conditions was researched, Results showed that: it was more appropriate to save the hydrogenated soybean-lubricant oil at 25℃ and dark. And it was more obvious than soybean oil on antioxidation activity in the process of using. POV and AV were elevated with the temprature increased The optimum conditions were obtained that adding 6% TBHO as the lubricant additive at 60℃,and the anti- oxidation activity enhanced obviously,it assured of non-toxic. The cycle time was expected within six months.

  14. 高速发动机油膜惯性对活塞裙润滑的影响%Influence of Oil Film Inertia on Piston Skirt Lubrication in High Speed Engine

    Institute of Scientific and Technical Information of China (English)

    孟凡明; 张优云

    2003-01-01

    By an iteration method, the influence of oil film inertia on piston skirt lubrication in a high speed engine is investigated. By alternately solving the Navier-Stocks equations and the Reynolds equation, the new iteration method can trace the variations of velocity field and pressure field with time. Based on this, the mixed-lubrication model suitable for the piston skirt of high engines is proposed. By introducing the inertia coefficient, the new lubrication model includes the inertia term in oil film. The model can be also used to solve for the lubrication performances of a piston skirt in low or medium speed engines and for lubrication problem in general excluding the inertia term of oil film , when the inertia coefficient is put equal to zero. The calculation results show that the influence of oil film inertia on the friction force increases with the ratio of the piston skirt' s length to its diameter, the inertia coefficient and the eccentricities of the lower and the upper piston skirt, with other conditions kept constant, while the influence of it on the load capacity of oil film is small.

  15. S209FA燃气轮机润滑油系统改造%Transformation of Lubricating Oil System of S209FA Gas Turbine

    Institute of Scientific and Technical Information of China (English)

    邵璀荣

    2014-01-01

    以提高燃气轮机控制油油品为切入点,详细介绍了燃机润滑油系统改造的主要内容和过程,总结改造效果,对同类型电厂的控制油改造具有一定的借鉴意义。%The paper takes control oil quality of gas turbine as a point of entry to elaborate on transformation of lubricating oil system of gas turbine. It summarizes the effect of transformation , providing reference for the transformation of control oil in the same type of power plants.

  16. Shearing stability of lubricants

    Science.gov (United States)

    Shiba, Y.; Gijyutsu, G.

    1984-01-01

    Shearing stabilities of lubricating oils containing a high mol. wt. polymer as a viscosity index improver were studied by use of ultrasound. The oils were degraded by cavitation and the degradation generally followed first order kinetics with the rate of degradation increasing with the intensity of the ultrasonic irradiation and the cumulative energy applied. The shear stability was mainly affected by the mol. wt. of the polymer additive and could be determined in a short time by mechanical shearing with ultrasound.

  17. Shearing stability of lubricants

    Energy Technology Data Exchange (ETDEWEB)

    Shiba, Y.; Gijyutsu, G.

    1984-03-01

    Shearing stabilities of lubricating oils containing a high mol. wt. polymer as a viscosity index improver were studied by use of ultrasound. The oils were degraded by cavitation and the degradation generally followed first order kinetics with the rate of degradation increasing with the intensity of the ultrasonic irradiation and the cumulative energy applied. The shear stability was mainly affected by the mol. wt. of the polymer additive and could be determined in a short time by mechanical shearing with ultrasound.

  18. AUTOMOTIVE DIESEL MAINTENANCE 1. UNIT XVII, I--MAINTAINING THE LUBRICATION SYSTEM--CUMMINS DIESEL ENGINE, II--UNIT INSTALLATION AND REMOVAL--DRIVE LINES.

    Science.gov (United States)

    Minnesota State Dept. of Education, St. Paul. Div. of Vocational and Technical Education.

    THIS MODULE OF A 30-MODULE COURSE IS DESIGNED TO DEVELOP AN UNDERSTANDING OF THE DIESEL ENGINE LUBRICATION SYSTEM AND THE PROCEDURES FOR REMOVAL AND INSTALLATION OF THE DRIVE LINE USED IN DIESEL ENGINE POWER DISTRIBUTION. TOPICS ARE (1) PROLONGING ENGINE LIFE, (2) FUNCTIONS OF THE LUBRICATING SYSTEM, (3) TRACING THE LUBRICANT FLOW, (4) DETERMINING…

  19. Experimental identification of dynamic coefficients of lightly loaded tilting-pad bearings under several lubrication regimes

    DEFF Research Database (Denmark)

    Salazar, Jorge G.; Santos, Ilmar F.

    2016-01-01

    This paper presents the identified dynamic coefficients of a lightly loaded actively lubricated bearing under three lubrication regimes: passive, hybrid and feedback-controlled. The goal is to experimentally demonstrate the feasibility of modifying the bearing dynamic properties via active...... lubrication. Dominated by the latest two regimes, the bearing properties become adjustable or controllable due to the injection of either a constant or variable pressurized oil flow. Such a flow is regulated by a hydraulic control system composed of (a) a high-pressure oil supply unit, (b) servovalves, (c......) radial injection nozzles, (d) displacement sensors and (e) well-tuned digital controllers. A scaled-down industrial rotor featuring active lubrication, composed of a flexible rotor supported by a four-rocker load-between-pads tilting-pad bearing under light load condition, is used for this objective...

  20. Map service: United States Oil and Gas Production 2008

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This map service displays present and past oil and gas production in the United States, as well as the location and intensity of exploratory drilling outside...

  1. Analyse the Cause of for Lubricating Oil into a Dry Gas Seal%一次干气密封进油事故的原因分析

    Institute of Scientific and Technical Information of China (English)

    张泳

    2011-01-01

    Dry gas seal is a new type and non-contact shaft seal,the seals must be running in a clean and dry state;The article for lubricating oil into dry gas seal reason is analyzed.%干气密封是一种新型、非接触式轴封,其密封端面必须处于清洁、干燥状态下运行;本文针对干气密封一次进油事故原因进行了分析。

  2. Jojoba - a promising plant for the semi-arid regions. [North America, plants, seeds, oils, waxes, growth, cultivation, lubricants, guayule, mesquite

    Energy Technology Data Exchange (ETDEWEB)

    Yermanos, D.M.

    1979-01-01

    As a result of the world-wide concern for conservation of resources and for the development of new renewable resources a great deal of attention has been directed towards the development of jojoba as a potential new crop for semi-arid regions. Jojoba grows wild in the Southwestern U.S. and N. Mexico, in areas where the annual precipitation is 4''-15''. Under cultivation it appears to grow satisfactorily in areas of marginal soil fertility, high salinity and high atmospheric temperatures. It appears to have no major natural enemies and to be tolerant to chemical treatments, if they were to become necessary. It is perennial with an assumed life span in excess of 150 years. Jojoba seed has an average weight of about 0.5 grams per seed, and it contains a unique liquid wax which is a superior lubricant and a potential replacement of whale oil, obtained from the sperm whale, and endangered species. Thus, jojoba has a double appeal, first as a potential crop of semi-arid regions requiring low cultural and energy inputs and second as a source of a valuable commodity. It should be pointed out that a cheap and abundant source of lubricants will disappear when our stock of fossil fuels are exhausted and that none of our new sources of energy have lubricants as by-products. Finally, jojoba could be grown with other companion crops such as guayule or mesquite for more diversified farming.

  3. Solid lubricants

    Science.gov (United States)

    Sliney, Harold E.

    1993-01-01

    The state of knowledge of solid lubricants is reviewed. The results of research on solid lubricants from the 1940's to the present are presented from a historical perspective. Emphasis is placed largely, but not exclusively, on work performed at NASA Lewis Research Center with a natural focus on aerospace applications. However, because of the generic nature of the research, the information presented in this review is applicable to most areas where solid lubricant technology is useful.

  4. Experimental Performance Study of a High Speed Oil Lubricated Polymer Thrust Bearing

    Directory of Open Access Journals (Sweden)

    Jie Zhou

    2015-01-01

    Full Text Available With the demand for turbomachinery to operate at higher speeds, loads, and power, fluid film bearings that support turbomachinery must be capable of operating in these more demanding applications. Thrust bearings operating at high speeds and loads can experience high surface temperatures and thin fluid film thickness. Typically, babbitt (white metal is the bearing lining material for most turbomachinery bearings but is limited in operating temperature and allowable film thickness. Polymer based materials are alternative materials that can operate at high temperatures and with thin films and have been in use for many decades in high load applications, such as electric submersible pumps (ESP. Test results of polymer lined thrust bearings subjected to modern turbomachinery speeds and loads are presented and compared to babbitt lined bearings of the same design and under similar conditions. The test results show polymer lined thrust bearings can operate at higher bearing unit loads than babbitt.

  5. On the Effect of Lubricant on Pool Boiling Heat Transfer Performance

    OpenAIRE

    2016-01-01

    Â Â Â For typical vapor compression processes, lubricant oil is very essential for lubricating and sealing the sliding parts and the lubricant also takes part in cushioning cylinder valves. However lubricants may migrate to the evaporator to alter the heat transfer characteristics. This is can be made clear from the viscosity and surface tension of lubricant since the viscosity of lubricant oil is about two to three orders higher than that of refrigerant whereas the corresponding surface t...

  6. Effect of Ultrasonic Vibration on the Tribological Properties of Different Viscosities of Lubrication Oil%超声振动对不同黏度润滑油摩擦学性能的影响

    Institute of Scientific and Technical Information of China (English)

    乔玉林; 杨善林; 臧艳; 董新宇

    2012-01-01

    The friction and wear properties of GCrl5/45* steel factional pairs lubricated by four different lubrication oils under ultrasonic vibration were studied. The surface morphologies of wear scare was analyzed by scanning electron microscope ( SEM). The effect mechanism of ultrasonic vibration on frictional pairs under different lubrication oils was discussed. The results show that the influence of ultrasonic vibration on friction reduction and anti-wear properties of friction pairs is different under various lubrication oils. When the viscosity of lubrication oil is low,the friction coefficient and wearvolume of the frictional pairs are reduced under ultrasonic vibration,and they are decreased by 13. 6% and 17. 5% respectively under ultrasonic vibration, when the lubrication oil is 6# white oil. However, when the viscosity of lubrication oil is high, the friction coefficient and wear volume of the frictional pairs are increased under ultrasonic vibration, and they are increased by 10. 4% and 50% respectively under ultrasonic vibration,when the lubrication oil is 150BS.%研究GCr15/45#钢摩擦副在4种不同黏度的润滑油润滑时,有和无超声振动下的摩擦磨损性能,采用扫描电子显微镜分析磨痕表面形貌,探讨在不同黏度润滑油作用下,超声振动对润滑油摩擦学性能的影响机制.结果表明:超声振动对不同黏度润滑油摩擦学性能的影响是不同的;超声振动可以提高低黏度润滑油润滑的减摩抗磨性能,如在6#白油润滑时施加超声振动后,摩擦副间的摩擦因数和磨损体积分别减小了13.6%和17.5%;高黏度润滑油润滑时,超声振动会加剧摩擦副的摩擦磨损,如在150BS润滑时施加超声振动后,摩擦副间的摩擦因数和磨损体积分别增加了10.4%和50%.

  7. Ionic Liquids as Novel Lubricants and /or Lubricant Additives

    Energy Technology Data Exchange (ETDEWEB)

    Qu, J. [ORNL; Viola, M. B. [General Motors Company

    2013-10-31

    This ORNL-GM CRADA developed ionic liquids (ILs) as novel lubricants or oil additives for engine lubrication. A new group of oil-miscible ILs have been designed and synthesized with high thermal stability, non-corrosiveness, excellent wettability, and most importantly effective anti-scuffing/anti-wear and friction reduction characteristics. Mechanistic analysis attributes the superior lubricating performance of IL additives to their physical and chemical interactions with metallic surfaces. Working with a leading lubricant formulation company, the team has successfully developed a prototype low-viscosity engine oil using a phosphonium-phosphate IL as an anti-wear additive. Tribological bench tests of the IL-additized formulated oil showed 20-33% lower friction in mixed and elastohydrodynamic lubrication and 38-92% lower wear in boundary lubrication when compared with commercial Mobil 1 and Mobil Clean 5W-30 engine oils. High-temperature, high load (HTHL) full-size engine tests confirmed the excellent anti-wear performance for the IL-additized engine oil. Sequence VID engine dynamometer tests demonstrated an improved fuel economy by >2% for this IL-additized engine oil benchmarked against the Mobil 1 5W-30 oil. In addition, accelerated catalyst aging tests suggest that the IL additive may potentially have less adverse impact on three-way catalysts compared to the conventional ZDDP. Follow-on research is needed for further development and optimization of IL chemistry and oil formulation to fully meet ILSAC GF-5 specifications and further enhance the automotive engine efficiency and durability.

  8. The Lubrication Qualities of Dimethyl Ether (DME)

    DEFF Research Database (Denmark)

    Sivebæk, Ion Marius; Sorenson, Spencer C; Jakobsen, J.

    2002-01-01

    recycling. A significant problem arises when conventional injection equipment is used for pumping DME: It breaks down prematurely due to the poor lubrication qualities of DME compared to those of diesel oil. These qualities consist of the lubricity, which is important in the boundary lubrication regime......, and the viscosity, which plays a major role in the hydrodynamic lubrication regime. The lubricity of DME has been established by the medium frequency pressurised reciprocating rig (MFPRR) to be very low compared to the one of diesel oil. But the DME film limits the wear extent significantly compared to the case...... of dry sliding. By mixing DME with additives, the lubricity level is easily raised even above the one of diesel oil. The viscosity of DME has been established by the volatile fuel viscometer (VFVM) to be as low as 0.185 cSt @ 25 oC. It is also shown that this viscosity cannot be raised significantly...

  9. A multicommuted flow system for the determination of copper, chromium, iron and lead in lubricating oils with detection by flame AAS.

    Science.gov (United States)

    Reis, B F; Knochen, M; Pignalosa, G; Cabrera, N; Giglio, J

    2004-12-15

    In this work, a flow analysis procedure for the determination of copper, chromium, iron and lead in lubricating oils using flame AAS as detection technique is described. The flow manifold was designed to implement the multicommutation approach and it comprised three 3-way solenoid valves controlled by a personal computer. The flow system presented allowed to process the oil samples to determine wear metals without any prior preparation. Aiming to assess accuracy the results were compared with those obtained by manual procedure using flame AAS. Applying the joint-confidence ellipse test, no significant difference at the 95% confidence level was observed. Other profitable features such as a sample throughput of 50 determinations per hour; relative standard deviations (n = 5) below 2% for Cu, and below 8% for Cr, Fe and Pb; and linear responses in the range 0-40ppm (w/w) (Cu, Fe) and 0-15ppm (w/w) (Cr, Pb) were also achieved.

  10. Effect of amide type modified rapeseed oil as lubricating additive on friction and wear behavior of steel-steel and steel-aluminum alloy systems

    Institute of Scientific and Technical Information of China (English)

    FANG Jian-hua; CHEN Bo-shui; LIU Wei-min; DONG Lin; WANG Jiu

    2004-01-01

    A new type of environmentally friendly lube additive-amide type modified rapeseed oil was synthesized and characterized by infrared spectrum. Its effect on the friction and wear behavior of steel-steel and steel-aluminum alloy systems were investigated with a four-ball machine and an Optimol SRV friction and wear tester respectively.The morphographies of the worn surfaces were analyzed by means of scanning electron microscopy(SEM). The worn surfaces of the 2024Al alloy block were analyzed by means of X-ray photoelectron spectroscopy(XPS). The results show that the modified rapeseed oil as additives can obviously decrease the wear rate and friction coefficient of steel pair and steel-aluminum frictional pair. Its lubrication mechanism is inferred that a high strength complex protection films form on the worn surface of the Al alloy due to the adsorption or tribochemistry reaction of a long chain additive molecule and high reaction activity of N element.

  11. Bio-based lubricants for numerical solution of elastohydrodynamic lubrication

    Science.gov (United States)

    Cupu, Dedi Rosa Putra; Sheriff, Jamaluddin Md; Osman, Kahar

    2012-06-01

    This paper presents a programming code to provide numerical solution of elastohydrodynamic lubrication problem in line contacts which is modeled through an infinite cylinder on a plane to represent the application of roller bearing. In this simulation, vegetable oils will be used as bio-based lubricants. Temperature is assumed to be constant at 40°C. The results show that the EHL pressure for all vegetable oils was increasing from inlet flow until the center, then decrease a bit and rise to the peak pressure. The shapes of EHL film thickness for all tested vegetable oils are almost flat at contact region.

  12. Lubrication in strip cold rolling process

    Institute of Scientific and Technical Information of China (English)

    Jianlin Sun; Yonglin Kang; Tianguo Xiao; Jianze Wang

    2004-01-01

    A lubrication model was developed for explaining how to form an oil film in the deformation zone, predicting the film thickness and determining the characteristics of lubrication in the strip rolling process, combined with the knowledge of hydrodythicknesses in the strip cold rolling. Results from the experiment and calculation show that the oil film forming in hydrodynamic lubrication is up to the bit angle and a higher rolling speed or a higher rolling oil viscosity. The mechanism of mechanical entrainment always affects the film thickness that increases with the rolling oil viscosity increasing or the reduction rate decreasing in rolling.

  13. Biobased lubricants via ruthenium catalysis

    Science.gov (United States)

    The development of effective lubricants from natural oils is an ongoing mission. A few of the efforts have led to some promise, but many others have led elsewhere. An alternative approach to the direct use of natural oils may be needed. The drop-in replacement strategy allows industry to utilize mon...

  14. Hydrolytic stability and tribological properties of N-containing heterocyclic borate esters as lubricant additives in rapeseed oil

    NARCIS (Netherlands)

    Li, J.; Li, Zhipeng; Ren, Tianhui; Zeng, Xiangqiong; Heide, van der Emeil

    2014-01-01

    Borate ester compounds are emerging as promising materials for lubricating systems. The main drawback of borate esters however, is the susceptiblity to hydrolysis. In this work, two kinds of N-containing heterocyclic borate esters were synthesized. Their hydrolytic stability and tribological propert

  15. Experimental investigation of the effects of diesel-like fuel obtained from waste lubrication oil on engine performance and exhaust emission

    Energy Technology Data Exchange (ETDEWEB)

    Arpa, Orhan [Dicle University, Mechanical Engineering Department, Diyarbakir (Turkey); Yumrutas, Recep [University of Gaziantep, Mechanical Engineering Department, Gaziantep (Turkey); Argunhan, Zeki [University of Batman, Mechanical Engineering Department, Batman (Turkey)

    2010-10-15

    In this study, effects of diesel-like fuel (DLF) on engine performance and exhaust emission are investigated experimentally. The DLF is produced from waste engine lubrication oil purified from dust, heavy carbon soot, metal particles, gum-type materials and other impurities. A fuel production system mainly consisting of a waste oil storage tank, filters, a reactor, oil pump, a product storage tank, thermostats and control panel is designed and manufactured. The DLF is produced by using the system and applying pyrolitic distillation method. Characteristics, performance and exhaust emissions tests of the produced DLF are carried out at the end of the production. The characteristic tests such as density, viscosity, flash point, heating value, sulfur content and distillation of the DLF sample are performed utilizing test equipments presented in motor laboratory of Mechanical Engineering Department, University of Gaziantep, Turkey. Performance and exhaust emission tests for the DLF are performed using diesel test engine. It is observed from the test results that about 60 cc out of each 100 cc of the waste oil are converted into the DLF. Characteristics and distillation temperatures of the DLF are close to those values of a typical diesel fuel sample. It is observed that the produced DLF can be used in diesel engines without any problem in terms of engine performance. The DLF increases torque, brake mean effective pressure, brake thermal efficiency and decreases brake specific fuel consumption of the engine for full power of operation. (author)

  16. 一次除尘风机稀油润滑系统的改进%Improvement of Oil Lubrication System for Primary De-dust Fans

    Institute of Scientific and Technical Information of China (English)

    邓志宏; 彭绍南; 漆良明

    2011-01-01

    通过更换供油泵和增加一个低位油箱,解决了在低转速下风机轴瓦和耦合器轴承的润滑问题,也杜绝了风机轴瓦漏油现象,确保了风机的正常运行。通过更换大容积高位事故油箱,为事故和故障的处理创造了条件,有效的防止了恶性事故的发生。%The feed oil pump is changed and a lower oil tank is installed to meet the needs of the lubrication of fan bearing bush and coupler bearing at the lower speed and eliminate the oil leakage of fan bearing bush and ensure the.fans in a normal operation. The overhead emergency oil tank is replaced with a new one with a larger volume, better for accident and/or fault treatment and effective prevention of serious accidents.

  17. 32P-postlabelling analysis of DNA adducts in the skin of mice treated with petrol and diesel engine lubricating oils and exhaust condensates.

    Science.gov (United States)

    Schoket, B; Hewer, A; Grover, P L; Phillips, D H

    1989-08-01

    Samples of unused or used petrol and diesel engine lubricating oils were applied to the shaved dorsal skin of 4- to 6-week-old male Parkes mice, either as a single treatment (50 microliters/mouse) or as four consecutive daily treatments (50 microliters/application). DNA isolated from the skin 24 h after the final treatment was digested to 3'-mononucleotides and analysed by 32P-postlabelling for the presence of aromatic adducts. Enhancement of sensitivity using butanol extraction or nuclease P1 digestion of the DNA hydrolysates led to the detection of up to eight adduct spots on polyethyleneimine-cellulose thin-layer chromatograms with samples of DNA from skin treated with used engine oils, at levels of 40-150 amol total adducts/micrograms DNA. Multiple treatments with the used oils gave rise to similar patterns of adducts in lung DNA. A single treatment of mouse skin with petrol engine exhaust condensate (50 microliters), or diesel engine exhaust condensate (50 microliters), containing 20 and 46 micrograms benzo[a]pyrene (BaP)/g respectively, gave rise to approximately 75 amol total adducts/micrograms DNA in skin. A significant proportion, 31 and 48% respectively, of the adducts formed by the petrol and diesel engine exhaust condensates co-chromatographed with the major BaP-DNA adduct, but with the used engine oils, only petrol engine oil, and not diesel engine oil, produced significant amounts of an adduct (22% of total) that corresponded to the BaP-DNA adduct.

  18. Resettable regime of diesel lubrication

    Directory of Open Access Journals (Sweden)

    Nechaev E. P.

    2016-12-01

    Full Text Available A new method of engine oil saturation by microelements has been presented in the paper; it has been tested on vessels of the fishing fleet and in conditions of prolonged operation in the coastal diesel-engine power plants. The paper considers the results of performance tests of the most common diesel power plants of 6ЧН 25/34 type with the tribochemical reductant oil (TRO apparatus providing tribochemical lubrication. During comparative trials of two diesels the samples of lubricating oil m-10B2 and m-10 have been periodically collected and subjected to spectral analysis. In the samples the number of the following key microelements has been determined: iron (Fe, aluminum (Al, zinc (Zn, sodium (Na, barium (Ba, calcium (Ca, tin (Sn, phosphorus (P, potassium (K, sulfur (S, chlorine (Cl, silicon (Si. During the operation the processes of microelements' extraction and destruction in diesel motor oils evaluated by the relevant coefficients have been clearly manifested. Analyzing the obtained experimental data it should be noted that in both experiments the total balance of the controlled 15 trace elements has been balanced and approached within 1640.5–1650.3 g/t. And the greater measure refers to conventional oil. Stabilization and improvement of physical and chemical properties of motor oil in operation of a diesel engine is possible from the authors' viewpoint only in the tribochemical lubrication mode using the TRO apparatus and created hydrodynamic module – dispersant. The past performance tests suggest the possibility of use as a lubricant the conventional (pure oil under actual operating conditions. When in the tribochemical mode of diesel engine lubrication it has been established that in conventional (pure oil the oily medium has been formed with a spectrum of microelements equivalent to engine oil filler.

  19. Industrial Test of Blending the Third Side-draw VGO from Imported Crude Oil and Shengli Crude Oil to Produce HVIⅡ6 Lubricating Base Oil%掺炼胜利进口原油减三线生产HVIⅡ6基础油的工业试验

    Institute of Scientific and Technical Information of China (English)

    宗军; 温传忠; 吴艳萍; 李慧

    2015-01-01

    Based on crude oil separately-feeding-separately-refining, the new technology which integrated high-pres-sure hydrogenation refining to three kinds of traditional processes was applied in SINOPEC Jinan Company. The furfural refi-ning raw materials was broadened by blending the third side-draw VGO from imported crude oil and Shengli crude oil, so as to the quality grade of lubricating base oil was improved and HVIⅡ6 lubricating base oil and 62 # paraffin were produced. Through production tracking analysis, various suitable raw materials,product control indicators and operating conditions were found, and then the lubricant processing programs were optimized and the profits per ton of crude oil were maximized.%在原油分输分炼的基础上,通过掺炼胜利进口原油的减三线蜡油拓宽糠醛精制原料,应用高压加氢和"老三套"结合的工艺,生产优质HVIⅡ6润滑油基础油和62 #石蜡. 通过生产跟踪分析,摸索各装置合适的原料和产品控制指标以及操作条件,从而达到优化润滑油加工方案,实现吨油利润最大化的目的.

  20. Oil and Gas Emergency Policy: United Kingdom 2010 update

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    This publication provides a detailed look at the specific systems in the United Kingdom for responding to an oil supply crisis. In 2007, the IEA published ''Oil Supply Security: Emergency Response of IEA Countries''. Rather than waiting for the completion of the current review cycle to renew this full publication, the IEA will provide updates to the country chapters as these become available following the specific country's review. The aim of series of publications is to provide an overview of the IEA oil emergency response system and a detailed look at the specific systems in each IEA country for responding to an oil supply crisis. The 2007 publication represented the findings of a five year review cycle of the emergency response mechanisms in IEA member countries. Since the 2007 publication, the IEA has started a new cycle of reviews which now includes reviewing gas emergency policies.

  1. Extraction and preconcentration of copper from water, soils, lubricating oils and plant materials and its subsequent determination by atomic-absorption spectrophotometry.

    Science.gov (United States)

    Ejaz, M; Shamus-Zuha; Dil, W; Akhtar, A; Chaudhri, S A

    1981-07-01

    The extraction and preconcentration of the cupric thiocyanate complex with 4-(5-nonyl)pyridine in benzene is possible from neutral or up to 2M HCl, 0.5M HNO(3) or 0.25M H(2)SO(4) solutions. The method has considerable advantages over previously recommended extraction procedures because of selectivity, completeness of extraction in a single operation, short contact period, minimum amount of complexing agents needed and wide tolerance to various solution parameters. The complex formed from as little as 1 mug of copper can be extracted quantitatively into 1 ml of the organic phase from 500 ml of natural water. An extraction method is described which in combination with AAS can be used to determine copper in water, soils, fresh and used lubricating oils and plant-ash solutions down to the ng/ml or ng/g level.

  2. Determinants of profitability of smallholder palm oil processing units ...

    African Journals Online (AJOL)

    ... of profitability of smallholder palm oil processing units in Ogun state, Nigeria. ... as well as their geographical spread covering the entire land space of the state. ... The F-ratio value is statistically significant (P<0.01) implying that the model is ...

  3. MECHANISM OF BOUNDARY LUBRICATION UNDER POINT CONTACT

    Institute of Scientific and Technical Information of China (English)

    WANG Weizu; HUANG Ping

    2006-01-01

    The acid number of the mixed solution of 150SN oil and oleic acid characterizes the volume content of oleic acid in the solution, based on which the adsorptive capability of oleic acid is studied on the 45 steel balls and disks. Boundary lubrication tests are carried out on a self designed ball-on-disk machine. The base oil is pure 150SN oil, and oleic acid as additive are added into the lubricant. Disks have surface roughness values (Ra) of 0.8 μm and 0.4 μm. The electrical contact resistance method is used to determine the lubrication status. Hypothesize that the molecular film is monomolecular layer in condensed state and the opposing surfaces are completely separated by molecular film. A boundary lubrication model is established according to experimental results and hypothesizes. The experimental and calculational results show that the adsorption of polar molecules on steel surface is the main factor to form the boundary lubrication film. Load and sliding speed contribute little to the friction coefficient of boundary lubrication. The properties of steel surface and additive for the lubricant significantly influence on the characters of boundary lubrication. The smaller the surface roughness value is, the smaller the friction coefficient of the boundary lubrication is.

  4. Evaluation of lubricating oil preparation procedures for the determination of Al, Ba, Mo, Si and V by high-resolution continuum source FAAS.

    Science.gov (United States)

    Amorim Filho, Volnei Resta; Gomes Neto, José Anchieta

    2009-01-01

    Microwave-assisted acid decomposition and oil-in-water emulsification were evaluated as sample pretreatment procedures to determine Al, Ba, Mo, Si and V in lubricating oils by high-resolution continuum source flame atomic absorption spectrometry (HR-CS FAAS). Average recoveries of Al, Ba and V in oil digests (107, 103 and 101%) were close to those obtained for emulsions prepared in kerosene medium (94, 113 and 95%). Average recoveries for Mo were close to 105 and 46% for emulsions and digests, respectively. Improved average recoveries (101%) were obtained for Mo in digests using the analyte addition technique. Silicon was successfully quantified only in digested samples. Limits of quantification for Al, Ba, Mo and V were 1.4, 31.5, 1.5 and 11.4-fold lower than those obtained by line-source FAAS. Enhanced sensitivity, multi-elemental capability, and high sample throughput are among the main advantages of HR-CS FAAS in comparison with the line-source FAAS technique.

  5. Measurement of 238U and 232Th in Petrol, Gas-oil and Lubricant Samples by Using Nuclear Track Detectors and Resulting Radiation Doses to the Skin of Mechanic Workers.

    Science.gov (United States)

    Misdaq, M A; Chaouqi, A; Ouguidi, J; Touti, R; Mortassim, A

    2015-10-01

    Workers in repair shops of vehicles (cars, buses, truck, etc.) clean carburetors, check fuel distribution, and perform oil changes and greasing. To explore the exposure pathway of (238)U and (232)Th and its decay products to the skin of mechanic workers, these radionuclides were measured inside petrol, gas-oil, and lubricant material samples by means of CR-39 and LR-115 type II solid state nuclear track detectors (SSNTDs), and corresponding annual committed equivalent doses to skin were determined. The maximum total equivalent effective dose to skin due to the (238)U and (232)Th series from the application of different petrol, gas-oil, and lubricant samples by mechanic workers was found equal to 1.2 mSv y(-1) cm(-2).

  6. Glass molding process with mold lubrication

    Science.gov (United States)

    Davey, Richard G.

    1978-06-27

    Improvements are provided in glass forming processes of the type wherein hot metal blank molds are employed by using the complementary action of a solid film lubricant layer, of graphite dispersed in a cured thermoset organopolysiloxane, along with an overspray of a lubricating oil.

  7. Biobased, environmentally friendly lubricants for processing plants

    Science.gov (United States)

    Vegetable oil based lubricants have excellent lubricity, biodegradability, good viscosity temperature characteristics and low evaporation loss, but poor thermos-oxidative stability and cold flow properties. This paper presents a systematic approach to improve the oxidative and cold flow behavior of...

  8. Space lubrication and performance of harmonic drive gears

    Science.gov (United States)

    Schafer, I.; Bourlier, P.; Hantschack, F.; Roberts, E. W.; Lewis, S. D.; Forster, D. J.; John, C.

    2005-07-01

    Harmonic Drive gears are commonly used in space mechanisms. However, lubrication is a critical aspect for proper, effective performance. This paper describes the principle of operation, explains the key parameters that define gear performance and discusses the nature of the various tribological interfaces to be found within HD gears and which call for effective lubrication. Test data are presented on a compact type of harmonic Drive, type CSD 20, that has a reduction ratio of 160:1. Two such HD gears have been lubricated with two space greases namely Maplub SH050a (a grease containing Nye 2001 oil and PTFE) and Maplub PF100a (a grease containing Z25 oil and PTFE). These units have been subjected to thermal-vacuum testing during which measurements were made of input torque, efficiency, break-out torque and no-load backdriving torque. The dependency of these parameters on output load, rotational speed and temperature have been quantified. The work identifies the interface between the wave generator's outer race and the inside surface of the flexspline as the most tribologically demanding and highlights the importance of achieving effective lubrication in this area.

  9. Graphene: a new emerging lubricant

    Directory of Open Access Journals (Sweden)

    Diana Berman

    2014-01-01

    Full Text Available In recent years, reducing friction and wear-related mechanical failures in moving mechanical systems has gained increased attention due to friction's adverse impacts on efficiency, durability, and environmental compatibility. Accordingly, the search continues for novel materials, coatings, and lubricants (both liquid and solid that can potentially reduce friction and wear. Despite intense R&D efforts on graphene for a myriad of existing and future applications, its tribological potential as a lubricant remains relatively unexplored. In this review, we provide an up-to-date survey of recent tribological studies based on graphene from the nano-scale to macro-scale, in particular, its use as a self-lubricating solid or as an additive for lubricating oils.

  10. Advanced Lubricants

    Science.gov (United States)

    1996-01-01

    Three Sun Coast Chemicals (SCC) of Daytona, Inc. products were derived from NASA technology: Train Track Lubricant, Penetrating Spray Lube, and Biodegradable Hydraulic Fluid. NASA contractor Lockheed Martin Space Operations contacted SCC about joining forces to develop an environmentally safe spray lubricant for the Shuttle Crawler. The formula was developed over an eight-month period resulting in new products which are cost effective and environmentally friendly. Meeting all Environmental Protection Agency requirements, the SCC products are used for applications from train tracks to bicycle chains.

  11. Consequences of oil film degradation

    DEFF Research Database (Denmark)

    Ravendran, Rathesan

    2017-01-01

    In a review of recent studies into two-stroke lubrication, Rathesan Ravendran and Peter Jensen of Hans Jensen Lubricators highlight the importance of cylinder oil distribution.......In a review of recent studies into two-stroke lubrication, Rathesan Ravendran and Peter Jensen of Hans Jensen Lubricators highlight the importance of cylinder oil distribution....

  12. Lubricants for HFC-134a Compatible Rotary Compressors

    Science.gov (United States)

    Takaichi, Kenji; Sakai, Hisakazu

    In replacing CFC-12 with HFC-134a for refrigerator compressors, the compatibility with lubricating oil, and lubrication in general, are of major concern. HFC-134a dose not have adequate solubility with current lubricating oils because of its molecular structure. Current oils also do not provide enough lubricating action when using HFC-134a. A new oil and new materials have to be utilized in order to use HFC-134a. Developing a new lubricating oil involved numerous tests of different combinations of many polyolester synthetic oils and additives. One of the pre-evaluated methods was pursued via sealed tube tests. Lubricated parts were selected by studies involving a plane-on-roller type of wear test machine and by analyzing the traces of acid material commonly created during the lubricating action. The matrices of new lubricating oils and new lubricated materials were estimated based on durability tests conducted on compressors and refrigerators. Results showed that polyolester synthetic oils having a low total acid value and including certain quantities of additives did not break down into a tar-like substance and they did not produce composite particles in the operating compressors and refrigerators. The study also found that ceramics and anti-corrosion alloy steel possessed good adrasion-reducing qualities. Based on our evaluation, we will implement compressor reliability tests and apply HFC-134a to rotary compressors for refrigerators.

  13. Shell Becomes 3rd Largest Lubricants Provider in China

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    @@ Royal Dutch Shell Group has bought a 75percent stake in China's largest privately owned lubricant oil company Tongyi, making it the third largest in China's lubricants market, based on the recent report from the Chinese news media."The transaction will increase Shell's global finished lubricants volume by 8 percent, giving it approximately 16 percent of the global branded finished lubricants market," the company said in a statement.

  14. Rheological and Tribological Characteristics of the Synthesized Lubricants Derived from Vegetable Oils%由植物油提取的合成润滑剂的流变特性和摩擦特性

    Institute of Scientific and Technical Information of China (English)

    王彬; 陶德华

    2005-01-01

    The double bonds in the vegetable oils can be conjungated and Diels-Alder react when they are heated in the existence of the catalyst. The percent of the double bond will decrease and the oxidative stability of the vegetable oils can be ameliorated. Dimmer acid can react with different carbon chain length of alcohols to form dimmer acid esters. A series of dimmer acid esters were synthesized and their rheological characteristics (viscosity, viscosity index, pour point) and tribological characteristics (the coefficient of friction at different load, the characteristic of extreme pressure ( PB ), the wear scare diameter (D196N30min ) ) were evaluated and analyzed. The results showed that the characteristics of Di-iso-octanol dimmer acid ester were the best among the synthesized dimmer esters. It' s a lubricant with good properties(the viscosity is 94.5 mm2/s, the viscosity index is high up to 141 and the pour point is - 49℃ ). It is a kind of newly interesting ester type lubricant. Its rheological and tribological characteristics are even better than those of the slap-up synthesized lubricant-pentaerythritol esters (C7- 9 acidate). The FT-IR spectrophotometer was used to analyze the structure of the synthetic esters.Their IR spectra are the same as the typical IR spectrum of ester. The test indicated that Di-iso-octanol dimmer acid ester could be used as a kind of base lubricant with excellent quantity.

  15. Determination of Zinc-Based Additives in Lubricating Oils by Flow-Injection Analysis with Flame-AAS Detection Exploiting Injection with a Computer-Controlled Syringe.

    Science.gov (United States)

    Pignalosa, Gustavo; Knochen, Moisés; Cabrera, Noel

    2005-01-01

    A flow-injection system is proposed for the determination of metal-based additives in lubricating oils. The system, operating under computer control uses a motorised syringe for measuring and injecting the oil sample (200 muL) in a kerosene stream, where it is dispersed by means of a packed mixing reactor and carried to an atomic absorption spectrometer which is used as detector. Zinc was used as model analyte. Two different systems were evaluated, one for low concentrations (range 0-10 ppm) and the second capable of providing higher dilution rates for high concentrations (range 0.02%-0.2% w/w). The sampling frequency was about 30 samples/h. Calibration curves fitted a second-degree regression model (r(2) = 0.996). Commercial samples with high and low zinc levels were analysed by the proposed method and the results were compared with those obtained with the standard ASTM method. The t test for mean values showed no significant differences at the 95% confidence level. Precision (RSD%) was better than 5% (2% typical) for the high concentrations system. The carryover between successive injections was found to be negligible.

  16. The Friction and Wear Properties of CrN, Graphit-iC and Dymon-iC Coatings in Air and under Oil-lubrication.

    Institute of Scientific and Technical Information of China (English)

    J. Stallard; S. Yang; D.G. Teer

    2004-01-01

    Hard ceramic coatings such as TiN and CrN are very successful and are widely used in improving the performance of cutting and forming tools, but they are less successful in providing protection for general machine components, such as gears and engine parts. The development of low-friction wear resistant coatings that can run dry or in a minimum amount of oil is becoming increasingly important to this industry. Two recently developed carbon-based coatings Graphit-iCTM and Dymon-iC, which are shown to exhibit very high sliding wear resistance and low friction in dry conditions, are compared to a CrN coating under oil lubricated conditions. Long term pin-on-disc tests using a chrome steel counterface ball were carried out on coated HSS test samples. All the coatings performed well at very high applied contact pressures, exceeding 1.5 GPa, but the Graphit-iCTM and Dymon-iC coatings also exhibited the desirable characteristic of protecting the counterface material. Reasons for this behaviour are discussed.

  17. Lubrication Flows.

    Science.gov (United States)

    Papanastasiou, Tasos C.

    1989-01-01

    Discusses fluid mechanics for undergraduates including the differential Navier-Stokes equations, dimensional analysis and simplified dimensionless numbers, control volume principles, the Reynolds lubrication equation for confined and free surface flows, capillary pressure, and simplified perturbation techniques. Provides a vertical dip coating…

  18. 纳米二硫化钼作为润滑油添加剂的摩擦学性能研究%Study on Tribological Properties of Nano-MoS2 as Additive in Lubricating Oils

    Institute of Scientific and Technical Information of China (English)

    李斌; 谢凤; 张蒙蒙; 李磊

    2014-01-01

    研究纳米二硫化钼作为润滑油添加剂的摩擦学性能。以不同的表面活性剂和不同的超声波分散时间制备纳米二硫化钼润滑油,考察表面活性剂和超声波分散时间对纳米二硫化钼分散稳定性的影响。采用四球机和描电镜考察纳米二硫化钼在润滑油中的摩擦学性能。结果表明,2%油酸表面活性剂和超声波分散30 min可有效提高纳米二硫化钼在润滑油中的分散稳定性,纳米二硫化钼在润滑油中具有良好的抗磨性能、减摩性能,特别是0.01%二硫化钼在润滑油中的抗磨性能和高负荷下的减磨性能更为突出。%The tribological properties of nano-MoS2 as additive in lubricating oils were studied.The nano-MoS2 based lubricating oil was prepared by dispersing nano-MoS2 in the base oil with different surface modifier and at different ultra-sonic dispersion time,and the effect on dispersion stability of nano-MoS2 by the different surface modifier and different ul-trasonic dispersion time was investigated.The tribological properties of nano-MoS2 based lubricating oil were studied by Four-Ball Test Machine and SEM.The results show that nano-MoS2 has good dispersion stability in the base oil when with 2% oleic acid as surface modifier and at the ultrasonic dispersion time of 30 min.Nano-MoS2 as additive in lubricating oils has good property of anti-wear and friction reducing properties,especially for 0.01%nano-MoS2 based lubricating oil, which is best in anti-wear and friction reducing property under high load.

  19. Geophysical investigation using resistivity and GPR methods: a case study of a lubricant oil waste disposal area in the city of Ribeirão Preto, São Paulo, Brazil

    Science.gov (United States)

    Lago, Alexandre Lisboa; Elis, Vagner Roberto; Borges, Welitom Rodrigues; Penner, Giovanni Chaves

    2009-07-01

    Geophysics has been shown to be effective in identifying areas contaminated by waste disposal, contributing to the greater efficiency of soundings programs and the installation of monitoring wells. In the study area, four trenches were constructed with a total volume of about 25,000 m3. They were almost totally filled with re-refined lubricating oil waste for approximately 25 years. No protection liners were used in the bottoms and laterals of the disposal trenches. The purpose of this work is to evaluate the potential of the resistivity and ground penetrating radar (GPR) methods in characterizing the contamination of this lubricant oil waste disposal area in Ribeirão Preto, SP, situated on the geological domain of the basalt spills of the Serra Geral Formation and the sandstones of the Botucatu Formation. Geophysical results were shown in 2D profiles. The geophysical methods used enabled the identification of geophysical anomalies, which characterized the contamination produced by the trenches filled with lubricant oil waste. Conductive anomalies (smaller than 185 Ωm) immediately below the trenches suggest the action of bacteria in the hydrocarbons, as has been observed in several sites contaminated by hydrocarbons in previously reported cases in the literature. It was also possible to define the geometry of the trenches, as evidenced by the GPR method. Direct sampling (chemical analysis of the soil and the water in the monitoring well) confirmed the contamination. In the soil analysis, low concentrations of several polycyclic aromatic hydrocarbons (PAHs) were found, mainly naphthalene and phenanthrene. In the water samples, an analysis verified contamination of the groundwater by lead (Pb). The geophysical methods used in the investigation provided an excellent tool for environmental characterization in this study of a lubricant oil waste disposal area, and could be applied in the study of similar areas.

  20. 干油喷射式润滑在连轧管机组设备上的应用%The Application of Dry oil Sprays Lubrication in The Company Tube Rolling Train

    Institute of Scientific and Technical Information of China (English)

    张力

    2011-01-01

    介绍了干油喷射式润滑系统的原理、技术特。最,以及该系统在连轧管机组设备上的成功应用。%In this paper, the author introduced principle and features of dry oil sprays lubrication system, and the application of the system in the company tube rolling train.

  1. Water Lubrication of Stainless Steel using Reduced Graphene Oxide Coating

    Science.gov (United States)

    Kim, Hae-Jin; Kim, Dae-Eun

    2015-11-01

    Lubrication of mechanical systems using water instead of conventional oil lubricants is extremely attractive from the view of resource conservation and environmental protection. However, insufficient film thickness of water due to low viscosity and chemical reaction of water with metallic materials have been a great obstacle in utilization of water as an effective lubricant. Herein, the friction between a 440 C stainless steel (SS) ball and a 440 C stainless steel (SS) plate in water lubrication could be reduced by as much as 6-times by coating the ball with reduced graphene oxide (rGO). The friction coefficient with rGO coated ball in water lubrication was comparable to the value obtained with the uncoated ball in oil lubrication. Moreover, the wear rate of the SS plate slid against the rGO coated ball in water lubrication was 3-times lower than that of the SS plate slid against the uncoated ball in oil lubrication. These results clearly demonstrated that water can be effectively utilized as a lubricant instead of oil to lower the friction and wear of SS components by coating one side with rGO. Implementation of this technology in mechanical systems is expected to aid in significant reduction of environmental pollution caused by the extensive use of oil lubricants.

  2. 原位直接制备纳米铜润滑油及其摩擦学性能研究%In-situ Direct Preparation of Nano-copper Lubricant Oil and study on Tribological Properties

    Institute of Scientific and Technical Information of China (English)

    赵金珍; 黄伟

    2011-01-01

    An in-situ liquid phase method was developed to prepare nano-copper lubricating oil using nitric acid copper as raw material in a microemulsion system of different basic oil. The nano-copper was characterized by SEM and the anti-wear property and extreme pressure of the nano-copper lubricating oil was investigated by a four-ball machine. The results indicate that sizes of the obtained nano-copper are about 20 ~ 50 nm. The nano-copper lubricating oil prepared in base oil of 100SN has high load carrying capacity and good friction reducing and anti-wear property,which can make the maximum nonseizure load of 100SN base oil increase by 27% ,the friction coefficient reduce by 3. 8% and the wear trace width decrease by 20% at the condition of 392 N and 1 450 r/min. However,the nano-copper lubricating oils prepared in base oils of 150SN and 500SN have no obvious effect on the load carrying capacity of base oils.%以硝酸铜为原料,在100SN,150SN,500SN 3种润滑油基础油微乳液体系中使用原位液相直接制备纳米铜润滑油,使用扫描电镜(SEM)表征制备的纳米铜的表面形貌,使用四球摩擦磨损试验机考察制备的纳米铜润滑油的减摩抗磨和极压性能.结果表明:原位制备的纳米铜颗粒的粒径在20-50 nm之间.在100SN基础油中原位制备的纳米铜润滑油具有较高的承载能力和良好的减摩抗磨性能,可使基础油的最大无卡咬负荷增大27%,在392 N,1 450 r/min条件下,可使基础油的摩擦因数、磨斑直径分别减小3.8%,20%.而在150SN,500SN基础油中原位制备后的纳米铜对润滑油的承载能力没有明显的影响.

  3. CATALYTIC HYDROCRACKING OF WASTE LUBRICANT OIL INTO LIQUID FUEL FRACTION USING ZnO, Nb2O5, ACTIVATED NATURAL ZEOLITE AND THEIR MODIFICATION

    Directory of Open Access Journals (Sweden)

    Wega Trisunaryanti

    2010-06-01

    Full Text Available Catalytic hydrocracking of waste lubricant oil into liquid fuel fraction using ZnO, Nb2O5, activated natural zeolite (ZAAH and their modification has been investigated. The zeolite was produced in Wonosari, Yogyakarta. Activation of the zeolite was carried out by refluxing with HCl 3M for 30 min, produced the activated natural zeolite (ZAAH. The ZnO/ZAAH catalyst was prepared by impregnation of Zn onto the ZAAH by ion exchange method using salt precursor of Zn(NO32.4H2O. The Nb2O5/ZAAH catalyst was prepared by mixing the ZAAH sample with Nb2O5 and oxalic acid solution until the paste was formed. The impregnation of Zn onto Nb2O5/ZAAH was carried out using the same method to that of the ZnO/ZAAH catalyst resulted ZnO/Nb2O5-ZAAH catalyst. Characterization of catalyst includes determination of Zn metal by Atomic Absorption Spectroscopy (AAS, acidity by gravimetric method and catalyst porosity by Surface Area Analyzer (NOVA-1000. Catalytic hydrocracking was carried out in a semi-batch reactor system using ZnO, ZAAH, ZnO/ZAAH and ZnO/Nb2O5-ZAAH catalysts at 450 oC under the H2 flow rate of 15 mL/min. and the ratio of catalyst/feed = 1/5. The composition of liquid products was analyzed by Gas Chromatograpy (GC.The results showed that impregnation of ZnO and/or Nb2O5 on the ZAAH increased the acidity and specific surface area of catalyst. The products of the hydrocracking process were liquid, coke and gas. Conversion of liquid products was increased by the increase of catalyst acidity. The highest liquid product was produced by ZnO/Nb2O5-ZAAH catalyst, 52.97 wt-%, consist of gasoline, 38.87 wt-% and diesel, 14.10 wt-%.   Keywords: hydrocracking, waste lubricant oil, liquid fuel fraction

  4. Comparative research on nano-additives' tribological performance in lubricating oil%几种纳米剂在润滑油中的摩擦学性能对比

    Institute of Scientific and Technical Information of China (English)

    杨俊儒; 尹兴林; 王稳; 王婷

    2011-01-01

    为了考察纳米剂在润滑油中的摩擦学性能,应用四球摩擦磨损试验机研究了烃分子纳米剂、氟碳纳米剂和金刚石纳米剂作为润滑油极压抗磨剂的摩擦学性能;并用扫描电子显微镜分析了磨痕表面的形貌.结果表明:烃分子纳米剂具有更好的抗磨损性能,氟碳纳米剂具有更好的抗极压性能;不同的纳米剂在润滑油中的极压抗磨性能差异较大.%In order to research nano-additives' tribological performance in lubricating oil, the tribological performance of nano-hydrocarbon, nano-fluorine carbon and nano-diamond as additives of lubricating oil were studied by applying four-ball tester. The scanning electron microscope was used to analyze the morphology of wear surface. The result shows that nano-hydrocarbon contains more excellent antiwear characteristics, nano-fluorine has more excellent anti-extreme pressure capacity. Different nano-additives' extreme pressure and wear resistance capacity in lubricating oil has significant difference. 1 tab, 6 figs, 10 refs.

  5. Lubricating Grease

    Science.gov (United States)

    Gow, G.

    Grease lubrication is a complex mixture of science and engineering, requires an interdisciplinary approach, and is applied to the majority of bearings worldwide. Grease can be more than a lubricant; it is often expected to perform as a seal, corrosion inhibitor, shock absorber and a noise suppressant. It is a viscoelastic plastic solid, therefore, a liquid or solid, dependent upon the applied physical conditions of stress and/or temperature, with a yield value, σ o. It has a coarse structure of filaments within a matrix. The suitability of flow properties of a grease for an application is best determined using a controlled stress rheometer for the frequency response of parameters such as yield, σ o, complex shear modulus, G * , phase angle, δ, and the complex viscosity, η *.

  6. Impact of Expanded North Slope of Alaska Crude Oil Production on Crude Oil Flows in the Contiguous United States

    Energy Technology Data Exchange (ETDEWEB)

    DeRosa, Sean E. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Flanagan, Tatiana Paz [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-05-01

    The National Transportation Fuels Model was used to simulate a hypothetical increase in North Slope of Alaska crude oil production. The results show that the magnitude of production utilized depends in part on the ability of crude oil and refined products infrastructure in the contiguous United States to absorb and adjust to the additional supply. Decisions about expanding North Slope production can use the National Transportation Fuels Model take into account the effects on crude oil flows in the contiguous United States.

  7. Lubrication fluids from branched fatty acid methyl esters

    Science.gov (United States)

    We have invented a new method for the synthesis of lubrication fluids using natural vegetable oils. Ordinary vegetable oils are good lubricants, but in their native form, they lack the stability necessary for many applications. Materials made using this new technology display significantly increas...

  8. China's Privately-owned Lubricants Producer Plans IPO

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ Beijing Monarch Petroleum Chemical Co Ltd,China's largest privately-owned lubricant oil producer, plans to list on an overseas stock market by the end of 2006, according to Li Jia, general manager of Monarch Lubricant Oil, who told the news media in a recent interview.

  9. Cooling lubricants; Kuehlschmierstoffe

    Energy Technology Data Exchange (ETDEWEB)

    Pfeiffer, W. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Breuer, D. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Blome, H. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Deininger, C. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Hahn, J.U. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Kleine, H. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Nies, E. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Pflaumbaum, W. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Stockmann, R. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Willert, G. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Sonnenschein, G. [Maschinenbau- und Metall-Berufsgenossenschaft, Duesseldorf (Germany)

    1996-08-01

    As a rule, the base substances used are certain liquid hydrocarbons from mineral oils as well as from native and synthetic oils. Through the addition of further substances the cooling lubricant takes on the particular qualities required for the use in question. Employees working with cooling lubricants are exposed to various hazards. The assessment of the concentrations at the work station is carried out on the basis of existing technical rules for contact with hazardous substances. However, the application/implementation of compulsory investigation and supervision in accordance with these rules is made difficult by the fact that cooling lubricants are, as a rule, made up of complicated compound mixtures. In addition to protecting employees from exposure to mists and vapours from the cooling lubricants, protection for the skin is also of particular importance. Cooling lubricants should not, if at all possible, be brought into contact with the skin. Cleansing the skin and skin care is just as important as changing working clothes regularly, and hygiene and cleanliness at the workplace. Unavoidable emissions are to be immediately collected at the point where they arise or are released and safely disposed of. This means taking into account all sources of emissions. The programme presented in this report therefore gives a very detailed account of the individual protective measures and provides recommendations for the design of technical protection facilities. (orig./MG) [Deutsch] Als Basisstoffe dienen in der Regel bestimmte fluessige Kohlenwasserstoffverbindungen aus Mineraloelen sowie aus nativen oder synthetischen Oelen. Durch die Zugabe von weiteren Stoffen erlangt der Kuehlschmierstoff seine fuer den jeweiligen Anwendungsabfall geforderten Eigenschaften. Beschaeftigte, die mit Kuehlschmierstoffen umgehen, sind unterschiedliche Gefahren ausgesetzt. Die Beurteilung der Kuehlschmierstoffkonzentrationen in der Luft am Arbeitsplatz erfolgt auf der Grundlage bestehender

  10. Liquid lubrication for space applications

    Science.gov (United States)

    Fusaro, Robert L.; Khonsari, Michael M.

    1993-01-01

    Reviewed here is the state of the art of liquid lubrication for space applications. The areas discussed are types of liquid lubrication mechanisms, space environmental effects on lubrication, classification of lubricants, liquid lubricant additives, grease lubrication, mechanism materials, bearing anomalies and failures, lubricant supply techniques, and application types and lubricant needs for those applications.

  11. Schemes for applying active lubrication to main engine bearings

    DEFF Research Database (Denmark)

    Estupinan, Edgar Alberto; Santos, Ilmar

    2009-01-01

    and consequently reducing viscous friction losses and vibrations. One refers to active lubrication when conventional hydrodynamic lubrication is combined with dynamically modified hydrostatic lubrication. In this case, the hydrostatic lubrication is modified by injecting oil at controllable pressures, through......The work presented here is a theoretical study that describes two different schemes for the oil injection system in actively lubricated main engine bearings. The use of active lubrication in journal bearings helps to enhance the hydrodynamic fluid film by increasing the fluid film thickness...... orifices circumferentially located around the bearing surface. The pressure distribution of the hydrodynamic fluid film in journal bearings is governed by the Reynolds equation, which is modified to accommodate the dynamics of active lubrication, and which can be numerically solved using finite...

  12. National Assessment of Oil and Gas Project - Montana Thrust Belt Province (027) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  13. National Assessment of Oil and Gas Project - Florida Peninsula Province (050) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  14. National Assessment of Oil and Gas Project - Southwestern Wyoming Province (037) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  15. National Assessment of Oil and Gas Project - Wyoming Thrust Belt Province (036) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  16. National Assessment of Oil and Gas Project - Western Oregon-Washington Province (004) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  17. National Assessment of Oil and Gas Project - San Joaquin Basin Province (010) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  18. National Assessment of Oil and Gas Project - San Juan Basin Province (022) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  19. National Assessment of Oil and Gas Project - Yukon Flats Assessment Area (002) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  20. National Assessment of Oil and Gas Project Anadarko Basin Province (058) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  1. National Assessment of Oil and Gas Project - Hanna, Laramie, Shirley Basins Province (030) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  2. National Assessment of Oil and Gas Project - Paradox Basin (021) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  3. National Assessment of Oil and Gas Project - Michigan Basin Province (063) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  4. National Assessment of Oil and Gas Project - Illinois Basin Province (064) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  5. National Assessment of Oil and Gas Project - Powder River Basin Province (033) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  6. National Assessment of Oil and Gas Project - Black Warrior Province (065) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  7. National Assessment of Oil and Gas Project - Williston Basin Province (031) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  8. USGS National Assessment of Oil and Gas Project - Unconventional Assessment Units from 2000 to 2011

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  9. National Assessment of Oil and Gas Project - Uinta-Piceance Province (020) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  10. National Assessment of Oil and Gas Project - Denver Basin Province (039) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  11. USGS National Assessment of Oil and Gas Project - Cherokee Platform Province Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  12. USGS National Assessment of Oil and Gas Project - Uinta-Piceance Province, Mancos Formation Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  13. USGS National Assessment of Oil and Gas Project - Uteland Butte Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  14. National Assessment of Oil and Gas Project - Eastern Great Basin (019) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  15. National Assessment of Oil and Gas Project - Cotton Valley Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  16. Rheology in lubrication

    Science.gov (United States)

    Cheng, H. S.

    1973-01-01

    The rheological effects on lubrication are discussed. The types of lubrication considered are thick film hydrodynamic lubrication and thin film elastohydrodynamic lubrication. The temperature-viscosity, viscoelastic, shear-thinning, and normal stess effects on the lubrication of journal bearings are analyzed. A graph of the pressure distribution of viscoelastic liquids in journal bearings is provided. Mathematical models are developed to define the effects of various properties of the lubricants on friction reduction.

  17. 润滑油边界膜临界温度性能评价方法的研究%The Research on Critical Temperature Property of Boundary Film of Lubricating Oil

    Institute of Scientific and Technical Information of China (English)

    高志; 肖刚; 周亚军; 钟掘

    2001-01-01

    This paper analyzes the invalidated mechanism of boundary lubricating;puts forward a new idea which adopts critical temperature as criterion of boundary lubricating capability of lubricating oil; carries out the research on tester and test method on boundary lubricating film critical temperature. The method appraises the temperature characteristic of boundary film of lubricating oil through tribological tests at different temperature points. The results show that the test method of critical temperature has a good distinguish ability to the property of various lubricating oil. Test results is consistent with practical results; when evaluating the effect of lubricating additives, critical temperature method can reflect the temperature region in which additives do action; and the influence rule of additives cooperate with each other. So that, to appraise the boundary lubricating capability of lubricate, critical temperature method is more reasonable and has more advantages. Popularizing and using such research have important meaning to the researching and development of lubricating oil and additives.%分析了润滑油边界润滑的失效机理;提出了采用临界温度作为润滑油边界润滑性能评价指标的新思想,开展了边界润滑膜临界温度试验机和试验方法的研究.通过在不同温度点上对润滑油进行摩擦学试验来评价润滑油边界膜的温度特性;试验结果表明:采用临界温度试验方法对于各种润滑油的边界润滑性能有好的分辨性,试验结果与实际结果之间有好的一至性;在评价润滑油添加剂的作用效果时,临界温度法能够清晰地反映出添加剂发生作用的温度区间、以及添加剂的协同作用规律;因此、对于评价润滑油的边界润滑性能,临界温度法比临界载荷和临界速度法更合理和更具优越性;此项研究的推广和使用对于润滑油和添加剂的研制与开发,具有重要的实际意义.

  18. 某精轧机油气润滑方案的改进%Improvement of Air-oil Lubrication System of a Finishing Mill

    Institute of Scientific and Technical Information of China (English)

    王培志; 王朝建; 杨培菲

    2014-01-01

    The problems existed in the oil-air lubrication system of a finishing mill were researched.By enhancing the o-pening pressure,the quick opening of the one-way valve was realized,by adjusting the opening limit of the high pressure valve,the chance of the distributor's damage made by the high pressure was reduced,and through adjusting the controlling program of the pressure relay and the system,the failure frequency of the relay was reduced and the production efficiency was improved.%对某型精轧机的油气润滑系统存在的问题进行研究,通过提高单向阀的开启压力,实现了单向阀的快速开启;通过调整高压阀开启值,解决了因压力过高导致的分配器损坏问题;通过调整压力继电器及系统的控制程序,解决了继电器经常发生故障的问题,提高了生产效率。

  19. Removal of heavy metals of used oils lubricants by biosorption; Remocao de metais pesados de oleo lubrificantes usados por biossorcao

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Albina da Silva [Rio Grande do Norte Univ., Natal, RN (Brazil). Dept. de Engenharia Quimica. Programa de Pos-graduacao em Engenharia Quimica]. E-mail: albina@eq.ufrn.br; Macedo, Gorete Ribeiro de; Duarte, Marcia Maria Lima [Universidade Federal do Rio Grande do Norte, Natal, RN (Brazil)]. E-mail: marcia@eq.ufrn.br; gomacedo@eq.ufrn.br

    2003-07-01

    The used lube oils when thrown directly in the environment (water bodies, sewerage nets, soils) or when burned in a non-controlled way, causes serious problems to the environment. Used lube oils contain high levels of hydrocarbons and heavy metals, of which Iron (Fe), Copper (Cu), Lead (Pb), Nickel (Ni) and Chrome (Cr) are the most representative. Due to these problems and to the high consumption of energy in the re-refining process, came the interest of studying a new methodology for removing those heavy metals from discarded automotive lube oil through the process of biosorption. A type of heavy lube oil used in a bus fleet was chosen and it was characterized in order to find out which metals it contained and its concentration. Then the bio-solvent material was prepared, in this case, the pheophyta seaweed Sargassum Sp. For the biosorption study, some preliminary tests using Sargassum Sp protonated with HCl 0,06 M and without protonation were run. The purpose of using protonated and non-protonated biosorbent was to verify the process efficiency. It was observed that for metal with high level of concentration the protonated biosorbent was more efficient, while for metals with lower concentrations the non-protonated biosorbent was more efficient. (author)

  20. 润滑油废白土的热解处理%Pyrolysis treatment of waste clay from lubricating oil production

    Institute of Scientific and Technical Information of China (English)

    王文杰; 王万福; 屈一新; 雍兴跃; 刘鹏; 王际东

    2012-01-01

    The effects of terminal pyrolysis temperature, heating rate and CaO addition on the pyrolysis products of waste clay from lubricating oil were studied by electric heating. It was found that there were obvious effects of terminal pyrolysis temperature on the quantities of gases and oils. Gases and oils increased with increas- ing terminal pyrolysis temperature, but their increasing rates increased slowly when it was above 600℃. When waste clay was pyrolized at 800℃ terminal pyrolysis temperature with 16℃/min heating rate and 0.5% CaO ad- dition, the production of hydrogen-rich gases was 189.2 L/kg, and its main compositions were H2 (27.97%) and CH4 (41.64%). The percentage of oil content and heavy metallic ions dissolving-out of pyrolysis residue were below the standard values. The production rate and recovery rate of pyrolysis oil were 10.98% and 38.94% ,re- spectively. And that pyrolysis oils were composed of gasoline (19.13%) , diesel oil (31.35%) and heavy oil (49.52%).%以润滑油废白土为原料,利用电热解法,研究了热解终温、加热速率和CaO添加量对热解产物的影响。实验结果表明:热解终温对热解产物的影响最为显著。随着热解终温的升高,不凝气产量和产油率均迅速增加。当热解终温达到600℃时,其增加的速率逐渐缓慢增大。当控制热解终温为800℃、加热速率为16℃/min、CaO添加量为0.5%时,富氢气体产量为189.2 L/kg,气体中主要成分为H2和CH4,其含量分别为27.97%和41.64%;热解残渣含油率和重金属溶出物均低于标准规定值,热解油产率为10.98%,回收率为38.94%,其主要成分为汽油、柴油和重油3部分组成,分别含19.13%、31.35%和49.52%。

  1. Determination of metal traces in lubricating oils by Aas and Icp-SFMS after microwave digestion; Determinacion de trazas metalicas en aceites lubricantes mediante EAA e ICP-SFMS despues de la digestion por microondas

    Energy Technology Data Exchange (ETDEWEB)

    Perez B, M. A.; Acosta L, C. E.; Hernandez M, H.; Romero G, E. T.; Lara A, N.; Kuri C, A., E-mail: manuel.perez@inin.gob.mx [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2016-09-15

    The analysis of lubricating oils allows to monitor the operating conditions of the machines and equipment, their pollution levels, degradation and finally their wear and useful life, as well as to establish a preventive lubrication program as a technical diagnostic maintenance tool. The useful life of oil is the period of functional time has in the machine until the antioxidants are consumed, producing large changes in the physical (density and viscosity) and chemical properties of the base oil, resulting in a wear of the components that make up the machine. The present work includes a theoretical as well as analytical basis for determining the content of metallic elements (Ag, Al, Cu, Fe, Mg, Sn and Zn) at trace level in used lubricating oils. A simple and rapid method of analysis is proposed, consisting mainly of the pretreatment of the sample by acidic digestion with a microwave oven. Subsequently an open digestion in a heating plate is carried out to dryness and recovered with concentrated HNO{sub 3}. For the quantitative analysis two analytical techniques were used: flame atomic absorption spectroscopy (Aas) and magnetic sector mass spectrometry with inductively coupled plasma source (Icp-SFMS). In both cases, the proposed method offers a good linearity and sensitivity for each of the trace elements under study. The accuracy of the method expressed as relative standard deviation ranges from 1.4 to 2.3%. In relation to the accuracy measurement, an oil was also analyzed as a certified reference material (Conostan 500 mg/L), with the concentration of certified Mg, obtaining satisfactory results. (Author)

  2. A Comparative Experimental Analysis of Tribological Properties Between Commercial Mineral Oil and Neat Castor Oil using Taguchi Method in Boundary Lubrication Regime

    OpenAIRE

    Bhaumik, S; Pathak, S. D.

    2016-01-01

    The present work aims to carry out a comparative experimental analysis of tribological properties of 372cSt mineral oil and 229cSt castor oil. The antiwear and extreme pressure properties of both the oils have been analysed according to ASTM G 99 and ASTM D-2783 standards. The surfaces of the balls and pins after tribo tests have been analysed using Scanning Electron Microscope (SEM) images. The present test results predict that the antiwear and extreme pressure properties in case of the sele...

  3. Tribological Behavior of Journal Bearing Material under Different Lubricants

    Directory of Open Access Journals (Sweden)

    S. Baskar

    2014-06-01

    Full Text Available The friction and wear behavior of journal bearing material has been investigated using pin on disc wear tester with three different lubricating oils i.e. synthetic lubricating oil (SAE20W40, chemically modified rapeseed oil (CMRO, chemically modified rapeseed oil with Nano CuO. Wear tests were carried out at maximum load of 200 N and sliding speeds of 2 – 10 m/s. The results showed that the friction and wear behavior of the journal bearing material have changed according to the sliding conditions and lubricating oils. The journal bearing material has a lower friction coefficient for CMRO with Nano CuO than other two oils. Higher wear of journal bearing material was observed in SAE 20W40 and CMRO. Worn surfaces of the journal bearing material with three lubricating oils were examined using scanning electron microscope (SEM and wear mechanisms were discussed.

  4. Lubricant Biodegradation Enhancers:Designed Chemistry and Engineered Technology

    Institute of Scientific and Technical Information of China (English)

    Chen Boshui; Gao Lingyue; Fang Jianhua; Zhang Nan; Wu Jiang; Wang Jiu

    2015-01-01

    In recent decades, a growing worldwide trend of developing the biodegradable lubricants has been prevailing to form a speciifc ifeld of green chemistry and green engineering. Enhancement of biodegradability of unreadily biodegradable petroleum-based lubricants has as such become an urgent must. For over a decade the authors have been focusing on the im-provement of biodegradability of unreadily biodegradable lubricants such as petroleum-based lubricating oils and greases. A new idea of lubricant biodegradation enhancer was put forward by the authors with the aim to stimulate the biodegradation of unreadily biodegradable lubricants by incorporating the enhancer into the lubricants in order to turn the lubricants into greener biodegradable ones and to help in situ bioremediation of lubricant-contaminated environment. This manuscript sum-marizes our recent efforts relating to the chemistry and technology of biodegradation enhancers for lubricants. Firstly, the chemistry of lubricant biodegradation enhancers was designed based on the principles of bioremediation for the treatment of hydrocarbon contaminated environment. Secondly, the ability of the designed biodegradation enhancers for increasing the biodegradability of unreadily biodegradable industrial lubricants was investigated through biodegradability evaluation tests, microbial population analysis, and biodegradation kinetics modeling. Finally, the impact of biodegradation enhancers on some crucial performance characteristics of lubricants such as lubricity and oxidation stability was tested via tribological evaluation and oxidation determinations. Our results have shown that the designed chemistry of nitrogenous and/or phos-phorous compounds such as lauroyl glutamine, oleoyl glycine, oleic diethanolamide phosphate and lauric diethanolamide borate was outstanding in boosting biodegradation of petroleum-based lubricants which was ascribed to increase the micro-bial population and decrease the oil-water interfacial

  5. Micro-Plasto-Hydrodynamic Lubrication a Fundamental Mechanism in Cold Rolling

    DEFF Research Database (Denmark)

    Laugier, Maxime; Boman, Romain; Legrand, Nicolas

    2014-01-01

    This paper presents recent investigations in Micro-Plasto-Hydrodynamic (MPH) lubrication. Industrial evidences of the existence of MPH lubrication mechanism for cold rolling processes are presented. A new lubrication model developed for strip drawing processes is then applied to predict the MPH...... lubrication initiation and MPH lubrication extension along the tool-piece solid contacts initially in boundary lubrication regime. Finally, it is shown how this new MPH lubrication model can be implemented in a cold rolling model to maximize mills capabilities, determine optimum rolling oils properties...

  6. Soybean oil and methyl oleate adsorption onto a steel surface investigated using a quartz crystal microbalance with dissipation monitoring and atomic force microscopy**1

    Science.gov (United States)

    The United States’ 2010 annual production of soybean oil exceeded 8 million metric tons, making a significant vegetable oil surplus available for new uses, particularly as a lubricant. Investigation of soybean oil and methyl oleate adsorption onto steel using a quartz crystal microbalance with diss...

  7. Lubrication Of Nonconformal Contacts

    Science.gov (United States)

    Jeng, Yeau-Ren

    1991-01-01

    Report discusses advances in knowledge of lubrication of nonconformal contacts in bearings and other machine elements. Reviews previous developments in theory of lubrication, presents advances in theory of lubrication to determine minimum film thickness, and describes experiments designed to investigate one of regimes of lubrication for ball bearings.

  8. Graphite and Hybrid Nanomaterials as Lubricant Additives

    Directory of Open Access Journals (Sweden)

    Zhenyu J. Zhang

    2014-04-01

    Full Text Available Lubricant additives, based on inorganic nanoparticles coated with organic outer layer, can reduce wear and increase load-carrying capacity of base oil remarkably, indicating the great potential of hybrid nanoparticles as anti-wear and extreme-pressure additives with excellent levels of performance. The organic part in the hybrid materials improves their flexibility and stability, while the inorganic part is responsible for hardness. The relationship between the design parameters of the organic coatings, such as molecular architecture and the lubrication performance, however, remains to be fully elucidated. A survey of current understanding of hybrid nanoparticles as lubricant additives is presented in this review.

  9. Increased production of naphtenic lubricants using more active catalysts; Aumento da producao de lubrificantes naftenicos usando catalisadores mais ativos

    Energy Technology Data Exchange (ETDEWEB)

    Fontes, Anita Eleonora F.; Lima, Anie Daniela M.; Figueiredo, Joao B.; Nogueira, Wlamir S.; Zotin, Jose L. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2008-07-01

    PETROBRAS produces lubricant base oil in three of its refineries: Duque de Caxias (REDUC), Landulpho Alves (RLAM) and Lubricants and Derivatives of Petroleum of Northeast (LUBNOR). LUBNOR, which began its operation in 1998, is the only refinery that produces naphtenic lubricant base oils with a current capacity of 60.000 m{sup 3}/year. It processes Brazilian naphtenic crudes in a vacuum distillation unit to produce distillates, which are then fed in to a hydrotreatment unit (HDT). This HDT unit processes 170 m{sup 3}/day to obtain base oils NH-10, NH-20, NH-140 and ISOVOLT. In 2007, an evaluation study of new catalysts was made for this unit at PETROBRAS Research Center (CENPES) aiming to increase the production capacity of the HDT unit. The concept was based on increasing the catalytic activity in the HTD unit by testing new catalysts and operating conditions in a pilot-plant unit. The results obtained were very promising showing that a selected catalyst achieved the normal production rate maintaining the same high quality product at a temperature lower than the conventional process. Alternatively, a 77% increase in the throughput capacity was achieved when the normal reaction temperature was applied to this selected catalyst. (author)

  10. Solid lubricants and surfaces

    CERN Document Server

    Braithwaite, E R

    1964-01-01

    Solid Lubricants and Surfaces deals with the theory and use of solid lubricants, particularly in colloidal form. Portions of this book are devoted to graphite and molybdenum disulfides, which are widely used solid lubricants in colloidal form. An extensive literature on the laboratory examination of hundreds of solids as potential lubricants is also provided in this text. Other topics discussed include the metals and solid lubricants; techniques for examining surfaces; other solid lubricants; metal shaping; and industrial uses of solid-lubricant dispersions. This publication is beneficial to e

  11. Status seminar: rapidly biodegradable lubricants and working agents; Statusseminar: Biologisch schnell abbaubare Schmier- und Verfahrensstoffe. Guelzower Fachgespraeche

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    Lubricants and hydraulic fluids based on vegetable oils have many advantages over mineral oils. They are biodegradable, have excellent tribological, wear and lubricating properties. The topics of the status seminar were: field test with biodegradable hydraulic fluids, chemical modification, additives, wear resistance, tribology. Examples of biodegradable oils were sunflower oil, rape oil and sunthetic esters.

  12. 航空钢油雾润滑极压抗磨剂的试验研究%Experimental Study on Extreme Pressure and Antiwear Additives of Oil Mist Lubrication of Aviation Steel

    Institute of Scientific and Technical Information of China (English)

    周志近

    2013-01-01

    直升机齿轮传动要求有30~60 min的干运转能力,以免减速器润滑系统出现故障时,造成灾难性的后果。为提高直升机齿轮传动干运转能力,在926航空润滑油中分别加入质量分数5%的硫化异丁烯、硫磷酸复酯胺盐、磷酸复酯铵盐、二烷基二硫代磷酸锌极压抗磨添加剂,进行45 min的12Cr2Ni4A航空钢摩擦副的油雾润滑试验。结果表明:微量的磷酸复酯铵盐就能使12Cr2Ni4A航空钢的磨损量下降25%,且由于中磷酸复酯铵盐的氮元素能有效地抑制磷元素的过度腐蚀,因此航空钢磨损表面光滑平整、质量好。含极压抗磨剂的油雾润滑技术为解决直升机传动系统干运转问题提供了一种新的选择。%Helicopter gear transmission requires 30~60 min dry running ability to avoid reducer lubrication system fail-ure resulting in disastrous consequences.To improve helicopter gear transmission dry running ability,various 5% extreme pressure and antiwear additives including sulphurised isobutylene,ammonium thiophsphonate,ashless organic phosphonate and parathion ding simbo alkyl zinc salt were added into 926 aviation oil,and the oil mist lubrication experiments of 45 mi-nutes were performed upon 12Cr2Ni4A aviation steel tribo-pairs.The results show that the wear volume of 12Cr2Ni4A avia-tion steel is reduced by 25% when lubricated by the 926 aviation oil with trace of ashless organic phosphonate.The worn surface of aviation steel is smooth because the nitrogen element in the ashless organic phosphonate can effectively inhibit the excessive corrosion of phosphorus element.The method of oil mist lubrication containing extreme pressure and antiwear additives provides a set of feasible options to solve helicopter transmission problem of oil-out operation.

  13. Brazilian device for lapidating large diameter non-lubricated metal seated plug valves for the gas and oil segment

    Energy Technology Data Exchange (ETDEWEB)

    Leite da Silva, Osmar Jose [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2009-07-01

    This work is related to a PETROBRAS patent, which defines an alternative technology for maintenance of valves, which are frequently used in the Oil and Gas segment. Until the development of this device, there were no reliable alternatives for the maintenance available at the Brazilian market, thus these valves had to be sent abroad to be repaired. Normally, the maintenance becomes impracticable, due to the high cost and long periods required to accomplish the whole process (send/repair/return). These drawbacks were a decisive impulse to the development of research process, which resulted in the equipment presented here. The Brazilian device for lapidating large diameter metal seated plug valves, that ensures the tightness reliability of these equipment, is being successfully used at PETROBRAS refineries. (author)

  14. Map of assessed continuous (unconventional) oil resources in the United States, 2014

    Science.gov (United States)

    ,; Biewick, Laura R. H.

    2015-01-01

    The U.S. Geological Survey (USGS) conducts quantitative assessments of potential oil and gas resources of the onshore United States and associated coastal State waters. Since 2000, the USGS has completed assessments of continuous (unconventional) resources in the United States based on geologic studies and analysis of well-production data and has compiled digital maps of the assessment units classified into four categories: shale gas, tight gas, coalbed gas, and shale oil or tight oil (continuous oil). This is the fourth digital map product in a series of USGS unconventional oil and gas resource maps; its focus being shale-oil or tight-oil (continuous-oil) assessments. The map plate included in this report can be printed in hardcopy form or downloaded in a Geographic Information System (GIS) data package, which includes an ArcGIS ArcMap document (.mxd), geodatabase (.gdb), and a published map file (.pmf). Supporting geologic studies of total petroleum systems and assessment units, as well as studies of the methodology used in the assessment of continuous-oil resources in the United States, are listed with hyperlinks in table 1. Assessment results and geologic reports are available at the USGS websitehttp://energy.usgs.gov/OilGas/AssessmentsData/NationalOilGasAssessment.aspx.

  15. Assessment of Lubricity Properties of Dimethyl Ether Using the Medium Frequency Reciprocating Rig

    DEFF Research Database (Denmark)

    Sivebæk, Ion Marius; Sorenson, Spencer C

    2001-01-01

    Adequate lubricity of a fuel is an important issue when the wear in diesel engine injection equipment is to be minimised. For conventional diesel oils, there exist methods capable of measuring the lubricity of the fuels. These methods cannot handle Dimethyl Ether (DME), as it has to be pressurised....... The calibration was achieved by using both the standard method for diesel oil and the MFPRR, to test three liquid fuels of varying lubricities. The result was that the MFPRR discriminated just as well between the fuel lubricities as did the standard method. The lubricity of DME was measured and was found...... exceptionally low. By mixing the DME with very small quantities of additives the lubricity can be redressed. Only one additive was capable of giving DME a lubricity higher than the one of diesel oil. Even at such high lubricities it cannot be concluded that wear in the diesel injection pumps...

  16. Influence of boric acid additive size on green lubricant performance.

    Science.gov (United States)

    Lovell, Michael R; Kabir, M A; Menezes, Pradeep L; Higgs, C Fred

    2010-10-28

    As the industrial community moves towards green manufacturing processes, there is an increased demand for multi-functional, environmentally friendly lubricants with enhanced tribological performance. In the present investigation, green (environmentally benign) lubricant combinations were prepared by homogeneously mixing nano- (20 nm), sub-micrometre- (600 nm average size) and micrometre-scale (4 μm average size) boric acid powder additives with canola oil in a vortex generator. As a basis for comparison, lubricants of base canola oil and canola oil mixed with MoS(2) powder (ranging from 0.5 to 10 μm) were also prepared. Friction and wear experiments were carried out on the prepared lubricants using a pin-on-disc apparatus under ambient conditions. Based on the experiments, the nanoscale (20 nm) particle boric acid additive lubricants significantly outperformed all of the other lubricants with respect to frictional and wear performance. In fact, the nanoscale boric acid powder-based lubricants exhibited a wear rate more than an order of magnitude lower than the MoS(2) and larger sized boric acid additive-based lubricants. It was also discovered that the oil mixed with a combination of sub-micrometre- and micrometre-scale boric acid powder additives exhibited better friction and wear performance than the canola oil mixed with sub-micrometre- or micrometre-scale boric acid additives alone.

  17. 船舶柴油机滑油在线监测预警系统设计%The Design of Lubricating Oil Monitoring and Early Warning Online System for Marine Diesel Engine

    Institute of Scientific and Technical Information of China (English)

    刘学强; 郭军武; 窦培松

    2016-01-01

    为了提高柴油机的可靠性、延长柴油机的使用寿命,设计了一种基于单片机的船舶柴油机滑油在线监测预警系统。介绍了该系统的测试原理、系统硬件及系统软件设计。该系统通过处理分析监测反馈数据来判断滑油的品质状况,在滑油完全变质前分级别向轮机人员提示预警,从而降低柴油机故障率,保证船舶的正常运营。%In order to improve the reliability of diesel engine and prolong the service life of the diesel engine, an online monitoring and warning system for lubricating oil of marine diesel engine with single chip microcomputer are designed. The test principle, hardware and software are introduced. The system can judge the quality of the lubricating oil by analyzing the feedback data. It warns the fault in classification before the oil deteriorates that could reduce the fault rate of the diesel engine, and ensure the ship in the normal service.

  18. Elastohydrodynamic Lubrication with Polyolester Lubricants and HFC Refrigerants, Final Report, Volume 2

    Energy Technology Data Exchange (ETDEWEB)

    Gunsel, Selda; Pozebanchuk, Michael

    1999-04-01

    Lubrication properties of refrigeration lubricants were investigated in high pressure nonconforming contacts under different conditions of temperature, rolling speed, and refrigerant concentration. The program was based upon the recognition that the lubrication regime in refrigeration compressors is generally elastohydrodynamic or hydrodynamic, as determined by the operating conditions of the compressor and the properties of the lubricant. Depending on the compressor design, elastohydrodynamic lubrication conditions exist in many rolling and sliding elements of refrigeration compressors such as roller element bearings, gears, and rotors. The formation of an elastohydrodynamic film separating rubbing surfaces is important in preventing the wear and failure of compressor elements. It is, therefore, important to predict the elastohydrodynamic (EHD) performance of lubricants under realistic tribocontact renditions. This is, however, difficult as the lubricant properties that control film formation are critically dependent upon pressure and shear, and cannot be evaluated using conventional laboratory instruments. In this study, the elastohydrodynamic behavior of refrigeration lubricants with and without the presence of refrigerants was investigated using the ultrathin film EHD interferometry technique. This technique enables very thin films, down to less than 5 nm, to be measured accurately within an EHD contact under realistic conditions of temperature, shear, and pressure. The technique was adapted to the study of lubricant refrigerant mixtures. Film thickness measurements were obtained on refrigeration lubricants as a function of speed, temperature, and refrigerant concentration. The effects of lubricant viscosity, temperature, rolling speed, and refrigerant concentration on EHD film formation were investigated. From the film thickness measurements, effective pressure-viscosity coefficients were calculated. The lubricants studied in this project included two

  19. Tribological Properties of Fluorosilicone Containing Oils as Lubricant Additives%含氟硅油作为润滑油添加剂的摩擦学性能研究

    Institute of Scientific and Technical Information of China (English)

    冯欣

    2011-01-01

    用SRV摩擦磨损试验机评价了2种含氟硅油在聚α烯烃基础油中作为添加剂的摩擦学性能,用扫描电子显微镜(SEM)和X射线光电子能谱仪(XPS)观察并分析了磨斑表面形貌和主要元素的化学状态,探讨了含氟硅油的摩擦化学机制.结果表明:含氟硅油具有优良的减摩和抗磨性能;含氟硅油在摩擦作用下发生分解,在摩擦副表面生成的含氟的摩擦化学产物是提高摩擦副抗磨减摩性能的关键因素.%The friction and wear of two kinds of fluorosilicone oils as lubricant additives were evaluated on an Optimo] SRV reciprocating friction and wear tester by using AISI 52100 steel disc against AISI 52100 steel ball at applied loads of 50 and 200 N, a sliding speed of 0. 20 rn/s. The wear scar sizes of AISI 52100 steel discs and AISI 52100 steel balls were measured using an optical microscope. The morphologies of the worn surfaces of the AISI 52100 steel discs were examined using a scanning electron microscope (SEM). In addition, the elemental compositions and chemical states of several typical elements on the worn surfaces of the steel discs were examined by means of X - ray photoelectron spectroscopy ( XPS). Results indicated that the evaluated tribo - pair under lubrication of PAO base oil using fluorosilicone containing oils as lubricant additives exhibited higher wear - resistance and lower stable friction coefficients than that in pure PAO base oil. This is partly attributed to tribophysical and tribochemical reaction between the lubricant and the sliding surfaces.

  20. Military Aviation Fluids and Lubricants Workshop 2006 (Postprint)

    Science.gov (United States)

    2006-06-01

    and Processes • MEMS and Nano Contact Lubrication • Health Monitoring of Aircraft Components • Space Protective Coatings • Space Lubricant Technology...gas – Diesel fuel, heating fuel, mogas, E-85, biodiesel fuel • Packaged petroleum products & chemicals – Lubricating oils – Hydraulic fluids...628 Bubble Point Tests • 231 Immersion Tests • 155 Cold Start Tests • 11 Flow Fatigue Tests • 11 Collapse Tests • 9 Media Migration Tests • 34 ISO-23369

  1. Oil fired boiler/solar tank- and natural gas burner/solar tank-units

    DEFF Research Database (Denmark)

    Furbo, Simon; Vejen, Niels Kristian; Frederiksen, Karsten Vinkler

    1999-01-01

    During the last few years new units consisting of a solar tank and either an oil fired boiler or a natural gas burner have been introduced on the Danish market. Three different marketed units - two based on a natural gas burner and one based on an oil fired boiler - have been tested in a heat...

  2. Measuring energy security. Can the United States achieve oil independence?

    Energy Technology Data Exchange (ETDEWEB)

    Greene, David L. [Oak Ridge National Laboratory, National Transportation Research Center, 2360 Cherahala Boulevard, Knoxville, TN 37932 (United States)

    2010-04-15

    Stochastic simulation of the direct economic costs of oil dependence in an uncertain future is proposed as a useful metric of oil dependence. The market failure from which these costs arise is imperfect competition in the world oil market, chiefly as a consequence of the use of market power by the Organization of the Petroleum Exporting Countries (OPEC) cartel. Oil dependence costs can be substantial. It is estimated that oil dependence costs to the US economy in 2008 will exceed $500 billion. Other costs, such as military expenditures or foreign policy constraints are deemed to be largely derivative of the actual or potential economic costs of oil dependence. The use of quantifiable economic costs as a security metric leads to a measurable definition of oil independence, or oil security, which can be used to test the ability of specific policies to achieve oil independence in an uncertain future. (author)

  3. Performance evaluation of minimum quantity lubrication by vegetable oil in terms of cutting force, cutting zone temperature,tool wear, job dimension and surface finish in turning AISI-1060 steel

    Institute of Scientific and Technical Information of China (English)

    KHAN M.M.A.; DHAR N.R.

    2006-01-01

    In all machining processes, tool wear is a natural phenomenon and it leads to tool failure. The growing demands for high productivity of machining need use of high cutting velocity and feed rate. Such machining inherently produces high cutting temperature, which not only reduces tool life but also impairs the product quality. Metal cutting fluid changes the performance of machining operations because of their lubrication, cooling and chip flushing functions, but the use of cutting fluid has become more problematic in terms of both employee health and environmental pollution. The minimization of cutting fluid also leads to economical benefits by way of saving lubricant costs and workpiece/tool/machine cleaning cycle time. The concept of minimum quantity lubrication (MQL) has been suggested since a decade ago as a means of addressing the issues of environmental intrusiveness and occupational hazards associated with the airborne cutting fluid particles on factory shop floors. This paper deals with experimental investigation on the role of MQL by vegetable oil on cutting temperature, tool wear, surface roughness and dimensional deviation in turning AISI-1060 steel at industrial speed-feed combinations by uncoated carbide insert. The encouraging results include significant reduction in tool wear rate, dimensional inaccuracy and surface roughness by MQL mainly through reduction in the cutting zone temperature and favorable change in the chip-tool and work-tool interaction.

  4. (1) H-NMR with Multivariate Analysis for Automobile Lubricant Comparison.

    Science.gov (United States)

    Kim, Siwon; Yoon, Dahye; Lee, Dong-Kye; Yoon, Changshin; Kim, Suhkmann

    2017-02-23

    Identification of suspected automobile-related lubricants could provide valuable information in forensic cases. We examined that automobile lubricants might exhibit the chemometric characteristics to their individual usages. To compare the degree of clustering in the plots, we co-plotted general industrial oils that were highly dissimilar with automobile lubricants in additive compositions. (1) H-NMR spectroscopy was used with multivariate statistics as a tool for grouping, clustering, and identification of automobile lubricants in laboratory conditions. We analyzed automobile lubricants including automobile engine oils, automobile transmission oils, automobile gear oils, and motorcycle oils. In contrast to the general industrial oils, automobile lubricants showed relatively high tendencies of clustering to their usages. Our pilot study demonstrated that the comparison of known and questioned samples to their usages might be possible in forensic fields.

  5. Lubrication in tablet formulations.

    Science.gov (United States)

    Wang, Jennifer; Wen, Hong; Desai, Divyakant

    2010-05-01

    Theoretical aspects and practical considerations of lubrication in tablet compression are reviewed in this paper. Properties of the materials that are often used as lubricants, such as magnesium stearate, in tablet dosage form are summarized. The manufacturing process factors that may affect tablet lubrication are discussed. As important as the lubricants in tablet formulations are, their presence can cause some changes to the tablet physical and chemical properties. Furthermore, a detailed review is provided on the methodologies used to characterize lubrication process during tablet compression with relevant process analytical technologies. Finally, the Quality-by-Design considerations for tablet formulation and process development in terms of lubrication are discussed.

  6. Elasto-hydrodynamic lubrication

    CERN Document Server

    Dowson, D; Hopkins, D W

    1977-01-01

    Elasto-Hydrodynamic Lubrication deals with the mechanism of elasto-hydrodynamic lubrication, that is, the lubrication regime in operation over the small areas where machine components are in nominal point or line contact. The lubrication of rigid contacts is discussed, along with the effects of high pressure on the lubricant and bounding solids. The governing equations for the solution of elasto-hydrodynamic problems are presented.Comprised of 13 chapters, this volume begins with an overview of elasto-hydrodynamic lubrication and representation of contacts by cylinders, followed by a discussio

  7. Foaming characteristics of refigerant/lubricant mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Goswami, D.Y.; Shah, D.O.; Jotshi, C.K.; Bhagwat, S.; Leung, M.; Gregory, A.

    1997-04-01

    The air-conditioning and refrigeration industry has moved to HFC refrigerants which have zero ozone depletion and low global warming potential due to regulations on CFC and HCFC refrigerants and concerns for the environment. The change in refrigerants has prompted the switch from mineral oil and alkylbenzene lubricants to polyolester-based lubricants. This change has also brought about a desire for lubricant, refrigerant and compressor manufacturers to understand the foaming properties of alternative refrigerant/ lubricant mixtures, as well as the mechanisms which affect these properties. The objectives of this investigation are to experimentally determine the foaming absorption and desorption rates of HFC and blended refrigerants in polyolester lubricant and to define the characteristics of the foam formed when the refrigerant leaves the refrigerant/ lubricant mixture after being exposed to a pressure drop. The refrigerants being examined include baseline refrigerants: CFC-12 (R-12) and HCFC-22 (R-22); alternative refrigerants: HFC-32 (R-32), R-125, R-134a, and R-143a; and blended refrigerants: R-404A, R-407C, and R-410A. The baseline refrigerants are tested with ISO 32 (Witco 3GS) and ISO 68 (4GS) mineral oils while the alternative and blended refrigerants are tested with two ISO 68 polyolesters (Witco SL68 and ICI RL68H).

  8. 40 CFR 1065.122 - Engine cooling and lubrication.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Engine cooling and lubrication. 1065.122 Section 1065.122 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... lubrication. (a) Engine cooling. Cool the engine during testing so its intake-air, oil, coolant, block,...

  9. Modelling of LEG tilting pad journal bearings with active lubrication

    DEFF Research Database (Denmark)

    Cerda Varela, Alejandro Javier; García, Asier Bengoechea; Santos, Ilmar

    2017-01-01

    This work constitutes the first step in a research effort aimed at studying the feasibility of introducing an active lubrication concept in tilting pad journal bearings (TPJBs) that feature the leading edge groove (LEG) lubrication system. The modification of the oil flow into each pad supply gro...

  10. Highly Branched Polyethylenes as Lubricant Viscosity and Friction Modifiers

    Energy Technology Data Exchange (ETDEWEB)

    Robinson, Joshua W.; Zhou, Yan; Qu, Jun; Bays, John T.; Cosimbescu, Lelia

    2016-10-08

    A series of highly branched polyethylenes (BPE) were prepared and used in a Group I base oil as potential viscosity and friction modifiers. The lubricating performance of these BPEs supports the expected dual functionality. Changes in polarity, topology, and molecular weight of the BPEs showed significant effects on the lubricants’ performance, which provide scientific insights for polymer design in future lubricant development.

  11. Impact of amino acid on biodegradability of lubricating oil and simulation of biodegradation rate equation%含氨基酸的润滑油生物降解性及降解速率方程模拟

    Institute of Scientific and Technical Information of China (English)

    陈波水; 黄伟九; 方建华; 孙霞; 王九; 余瑛

    2009-01-01

    Small amount of lauroyl glycine was incorporated into HVI 350 mineral oil and the biodegradabilities of HVI 350 mineral oil and the formulated oil in soils were evaluated. Thereafter, the biodegradation kinetics of the two lubricating oils was regressed based on the exponential rate model. The results indicated that lauroyl glycine obviously promoted biodegradation of HVI 350 min-eral oil. Under given test conditions, the biodegradation rate equation for HVI 350 mineral oil could be described as S_t = 50.4e~(-0.0155t), while that for lauroyl glycine formulated oil as S_t= 51.6e~(-0.0224t). The biodegradation half-lives of HVI 350 min-eral oil and the formulated oil were 44.72 days and 30.94 days, respectively.%在HVI 350矿物润滑油中加入少量月桂酰基甘氨酸,对比研究了加入月桂酰基甘氨酸前后矿物润滑油在土壤中的生物降解特性,并采用指数速率模型对润滑油生物降解动力学进行了模拟.结果表明,月桂酰基甘氨酸可促进HVI 350矿物润滑油生物降解,试验条件下HVI 350矿物润滑油生物降解速率方程为S_t=50.4e~(-0.0155t),半衰期为44.72 d;含月桂酰基甘氨酸的HVI 350矿物润滑油生物降解速率方程为S_t=51.6e~(-0.0224t),半衰期为30.94d.

  12. 蓖麻油聚氧乙烯醚水基润滑液摩擦学特性研究%Lubricating Properties of the Aqueous Solution of Castor Oil Polyoxyethylene Ether

    Institute of Scientific and Technical Information of China (English)

    刘俊铭; 张晨辉; 张朝辉; 王岩; 刘思思

    2011-01-01

    本文以蓖麻油聚氧乙烯醚水基润滑液为研究对象,分别使用润滑膜厚度测量仪、微摩擦试验机和四球摩擦试验机对其成膜特性、摩擦磨损特性和抗磨极压特性进行了系统的研究,并用扫描电子显微镜和能量色散光谱仪对摩擦磨损机制进行了分析.结果表明:蓖麻油聚氧乙烯醚提高了纯水的成膜能力,能够在钢-铝摩擦副形成有效的润滑膜,起到良好的减摩抗磨效果.随着浓度的增大,对钢-铝摩擦副的减摩抗磨性能和四球摩擦试验的抗磨极压性能都得到了提高.%The soluble polyether has attracted more attention due to its excellent lubricating performance and environment -friendly properties. The lubricating characteristics of castor oil polyoxyethylene ether solution, e. G. Film forming ability, friction-reducing, ami -wear and extreme pressure properties, were systematically investigated on the lubricating film measuring instrument, universal micro - tribotester and four - ball friction tester, respectively. The friction and wear mechanisms were analyzed by scanning electron microscopy and energy dispersive spectroscopy. The results show that the film forming ability of water was improved by mixing in castor oil polyoxyethylene ether. The effective lubricating film can be formed at the tribo - interface of steel/aluminum tribo - pair to reduce friction coefficient and improve anti - wear properties. The performance of the castor oil polyoxyethylene ether solution in friction reduction, anti -wear and extreme pressure was improved with the increasing solution concentration.

  13. Liquid lubricants for advanced aircraft engines

    Science.gov (United States)

    Loomis, William R.; Fusaro, Robert L.

    1993-01-01

    An overview of liquid lubricants for use in current and projected high performance turbojet engines is discussed. Chemical and physical properties are reviewed with special emphasis placed on the oxidation and thermal stability requirements imposed upon the lubrication system. A brief history is given of the development of turbine engine lubricants which led to the present day synthetic oils with their inherent modification advantages. The status and state of development of some eleven candidate classes of fluids for use in advanced turbine engines are discussed. Published examples of fundamental studies to obtain a better understanding of the chemistry involved in fluid degradation are reviewed. Alternatives to high temperature fluid development are described. The importance of continuing work on improving current high temperature lubricant candidates and encouraging development of new and improved fluid base stocks are discussed.

  14. Dry lubricant films for aluminum forming.

    Energy Technology Data Exchange (ETDEWEB)

    Wei, J.; Erdemir, A.; Fenske, G. R.

    1999-03-30

    During metal forming process, lubricants are crucial to prevent direct contact, adhesion, transfer and scuffing of workpiece materials and tools. Boric acid films can be firmly adhered to the clean aluminum surfaces by spraying their methanol solutions and provide extremely low friction coefficient (about 0.04). The cohesion strengths of the bonded films vary with the types of aluminum alloys (6061, 6111 and 5754). The sheet metal forming tests indicate that boric acid films and the combined films of boric acid and mineral oil can create larger strains than the commercial liquid and solid lubricants, showing that they possess excellent lubricities for aluminum forming. SEM analyses indicate that boric acid dry films separate the workpiece and die materials, and prevent their direct contact and preserve their surface qualities. Since boric acid is non-toxic and easily removed by water, it can be expected that boric acid films are environmentally friendly, cost effective and very efficient lubricants for sheet aluminum cold forming.

  15. Active lubrication applied to internal combustion engines - evaluation of control strategies

    DEFF Research Database (Denmark)

    Estupinan, Edgar Alberto; Santos, Ilmar

    2009-01-01

    of reducing friction losses and vibrations between the crankshaft and the bearings. The conventional hydrodynamic lubrication is combined with hydrostatic lubrication which is actively modified by radially injecting oil at controllable pressures, through orifices circumferentially located around the bearing....... The behaviour of such parameters is compared to the case when the bearing operates with conventional hydrodynamic lubrication....

  16. Development and Application of Environmentally-Friendly General Lubricant Oil for Pharmaceutical Industry%环境友好制药行业通用润滑油的研发与应用

    Institute of Scientific and Technical Information of China (English)

    梁健英; 杨茂立; 黄福川

    2011-01-01

    Aiming at the requirement of general mechanical equipments in the pharmaceutical machine industry, the environmentally-friendly sucrose polyester was used as base oil. Then additive prescription was chosen by fuzzy analytic hierarchy process(FAHP), as well as appropriate compound additive. The gained lubricant oil can meet the requirement of general mechanical equipments under specific working conditions in the pharmaceutical industry.%针对制药机械行业通用机械设备的要求,采用具有环境友好型蔗糖多酯作为基础油.通过运用模糊层次分析方法(FAHP)对添加剂配方的优选,复配选择适合的复合添加剂.研制油可满足制药行业机械设备在特定工况条件下的使用要求.

  17. Experimental Study on DC Inverter Compressor lubricant oil Changes under Harsh Conditions%恶劣条件下直流变频压缩机润滑油位变化的实验研究

    Institute of Scientific and Technical Information of China (English)

    祁小波; 程德威

    2014-01-01

    针对直流变频自由拖5 HP外机进行实验,以四台低静压风管机室内机为实验对象,在各种恶劣工况条件下研究润滑油变化时,系统应采取何种相应控制手段,并从系统控制方面进行精细的设计,确保直流变频压缩机润滑油的可靠性。%The experiment aimed at the DC inverter free drag 5HP outdoor machine, with four sets of low static pressure air duct machine indoor machine as the experimental objects, in various bad working conditions, to make a research on lubricating oil changes, study the corresponding control methods adopted by the system, have fine design from the aspect of system control in order to ensure the reliability of DC inverter compressor lubricating oil.

  18. Tribology and energy efficiency: from molecules to lubricated contacts to complete machines.

    Science.gov (United States)

    Taylor, Robert Ian

    2012-01-01

    The impact of lubricants on energy efficiency is considered. Molecular details of base oils used in lubricants can have a great impact on the lubricant's physical properties which will affect the energy efficiency performance of a lubricant. In addition, molecular details of lubricant additives can result in significant differences in measured friction coefficients for machine elements operating in the mixed/boundary lubrication regime. In single machine elements, these differences will result in lower friction losses, and for complete systems (such as cars, trucks, hydraulic circuits, industrial gearboxes etc.) lower fuel consumption or lower electricity consumption can result.

  19. 中间轴承流体润滑性能分析%Hydrodynamic Lubrication Analysis of the Intermediate Bearing

    Institute of Scientific and Technical Information of China (English)

    王明新

    2013-01-01

    As an important supporting unit for ship shafting,the lubrication performance of intermediate bearing has an effect on the dynamic performance of ship propulsion system.In this paper,based on the theory of hydrodynamic lubrication,a three-dimensional lubrication model has been presented to analyze the lubrication performance characteristics of intermediate bearing.The average Reynolds equation is solved by the finite difference method.The parameters of lubrication performance,such as oil film thickness,friction force,friction coeffcient and friction power loss are determined to analyze the lubrication performances of intermediate bearing.To complete the evaluation,the lubrication performance characteristics of intermediate bearing are compared on the conditions of different speed and lubricant temperature.%中间轴承是船舶轴系主要支承单元,其运行性能直接影响到船舶动力推进系统性能的优劣.以流体润滑理论为基础,建立中间轴承三维流体润滑数值分析模型.采用有限差分法求解Reynolds方程,获得了油膜厚度、摩擦力、摩擦系数及摩擦功耗等润滑性能参数.对比分析了不同转速工况及润滑油温度对中间轴承润滑性能的影响,完成了中间轴承运行性能的评价.

  20. Controllable Lubrication for Main Engine Bearings Using Mechanical and Piezoelectric Actuators

    DEFF Research Database (Denmark)

    Estupinan, Edgar; Santos, Ilmar

    2012-01-01

    Although mechatronic systems are nowadays implemented in a large number of systems in vehicles, active lubrication systems are still incipient in industrial applications. This study is an attempt to extend the active lubrication concept to combustion engines and gives a theoretical contribution...... to this field. One refers to active lubrication when conventional hydrodynamic lubrication is combined with dynamically modified hydrostatic lubrication. In this study, two different schemes for the oil injection system in actively lubricated main engine bearings are presented. The use of active lubrication...... in journal bearings helps to enhance the hydrodynamic fluid film by increasing the fluid film thickness and consequently reducing viscous friction losses and vibrations. In this study, the hydrostatic lubrication is modified by injecting oil at controllable pressures through orifices circumferentially...

  1. Metal forming and lubrication

    DEFF Research Database (Denmark)

    Bay, Niels

    2000-01-01

    Lubrication is essential in most metal forming processes. The lubricant film has two basic functions, [1]: i. to separate the work piece and tool surfaces and ii. to cool the workpiece and the tool. Separation of the two surfaces implies lower friction facilitating deformation and lowering the tool...... deformation step to avoid overheating and breakdown of the lubricant....

  2. Lubricant degradation and related wear of a steel pin in lubricated sliding against a steel disc.

    Science.gov (United States)

    Singh, Archana; Gandra, Ravi T; Schneider, Eric W; Biswas, Sanjay K

    2011-07-01

    In lubricated sliding contacts, components wear out and the lubricating oil ages with time. The present work explores the interactive influence between lubricant aging and component wear. The flat face of a steel pin is slid against a rotating steel disk under near isothermal conditions while the contact is immersed in a reservoir of lubricant (hexadecane). The chemical changes in the oil with time are measured by vibrational spectroscopy and gas chromatography. The corresponding chemistry of the pin surface is recorded using X-ray photoelectron spectroscopy while the morphology of the worn pins; surface and subsurface, are observed using a combination of focused ion beam milling and scanning electron microscopy. When compared to thermal auto-oxidation of the lubricant alone, steel on steel friction and wear are found to accentuate the decomposition of oil and to reduce the beneficial impact of antioxidants. The catalytic action of nascent iron, an outcome of pin wear and disk wear, is shown to contribute to this detrimental effect. Over long periods of sliding, the decomposition products of lubricant aging on their own, as well as in conjunction with their products of reaction with iron, generate a thick tribofilm that is highly protective in terms of friction and wear.

  3. Three Types of Active Lubrication Systems for the Main Bearings of Reciprocating Machines

    DEFF Research Database (Denmark)

    Santos, Ilmar; Pulido, E. E.

    2010-01-01

    thickness and consequently reducing viscous friction losses and vibrations. One refers to active lubrication when conventional hydrodynamic lubrication is combined with dynamically modified hydrostatic lubrication. In this case, the hydrostatic lubrication is modified by injecting oil at controllable......In the paper the authors investigate three different schemes for the realization of the controllable oil injection system to be couple to the main engine bearings. The use of active lubrication in fluid film bearings helps to enhance the hydrodynamic fluid film by increasing the fluid film...

  4. Suitability of Alternative Lubricants for Automotive Gear Applications

    Directory of Open Access Journals (Sweden)

    Amit Suhane

    2014-03-01

    Full Text Available Rising environmental concerns due to the problems associated with conventional mineral lubricants has renewed interest in usage of alternative resources. Various attempts have been made to explore the possibilities of utilizing vegetable oils for range of applications. Properties like excellent viscosity features, higher biodegradability, lower toxicity, better renewability & natural lubricity etc shows its potential as lubricants inspite of certain technical problems. Critical issues like lower oxidation stability , poor cold temperature properties affects the performance of vegetable oils and restricts its application to limited range . Gear oils are the hidden workhorses of automotive applications. This article highlights the suitability of various vegetable oils for lubricant formulation as an alternative in automotive gearing applications.

  5. Oil shale in the United States: prospects for development

    Energy Technology Data Exchange (ETDEWEB)

    Drabenstott, M.; Duncan, M.; Borowski, M.

    1984-05-01

    The development of an oil shale industry has had its ups and downs throughout this century. Despite vast reserves of recoverable shale oil, energy prices usually have been high enough to make extraction of that oil commercially viable. The tripling and then tripling again of world oil prices in the 1970s gave initial promise that development had become economically feasible. After only a few years of rapid development activity, however, the effort was brought to a near-halt by falling world oil prices. The results were a substantial reduction in economic activity for northwestern Colorado and, maybe more importantly, sharply lower expectations for the region's future economic growth. In both the upturn and the downturn, the local public sector was essentially shielded from financial stress because the energy companies helped fund public spending on infrastructure and services. The future for oil shale remains uncertain. A few energy companies continue to pursue their development plans. To spur development of commercial scale plants, Synthetic Fuels Corporation has made loan and price guarantees to energy firms. Some projects may soon be extracting oil, providing needed technological and financial information on various techniques of oil extraction. But the future for oil shale remains clouded by uncertainties regarding the cost of producing syncrude and future oil prices. Environmental issues could also hamper oil shale development. Therefore, oil shale remains, as it has for more than a century, a technical and economic enigma that has only begun to be understood and developed. 8 references, 3 figures, 3 tables

  6. Condoms and condiments: compatibility and safety of personal lubricants and their use in Africa.

    Science.gov (United States)

    Geibel, Scott

    2013-07-09

    Previous research on the use of personal lubricants for sexual intercourse is limited and has primarily focused on condom compatibility and breakage, with only recent limited assessment of lubricant safety and possible epidemiologic implications. This article discusses the global evidence of lubricant compatibility with latex condoms and biological safety of lubricants, as well as documentation of lubricant use and current guidelines for HIV prevention programming in Africa. Data on lubricant compatibility with condoms are less available than commonly realized, and many lubricant products may not have been thoroughly tested for safety due to flexible regulatory environments. Recent laboratory and study findings from microbicides research also suggest that some water-based lubricants may have safety issues. Some African populations are using several types of lubricants, especially oil-based petroleum jellies, and receive little evidence-based guidance. More research is needed from the medical community to guide prevention programming.

  7. Shale oil specialty markets: Screening survey for United States applications

    Energy Technology Data Exchange (ETDEWEB)

    1987-12-01

    EG and G requested J. E. Sinor Consultants Inc. to carry out an initial screening study on the possibilities for producing specialty chemicals from oil shale. Raw shale oil is not an acceptable feedstock to refineries and there are not enough user of heavy fuel oil in the western oil shale region to provide a dependable market. The only alternatives are to hydrotreat the oil, or else ship it long distances to a larger market area. Either of these alternatives results in a cost penalty of several dollars per barrel. Instead of attempting to enter the large-volume petroleum products market, it was hypothesized that a small shale oil facility might be able to produce specialty chemicals with a high enough average value to absorb the high costs of shipping small quantities to distant markets and still provide a higher netback to the plant site than sales to the conventional petroleum products market. This approach, rather than attempting to refine shale oil or to modify its characteristics to satisfy the specifications for petroleum feedstocks or products, focuses instead on those particular characteristics which distinguish shale oil from petroleum, and attempts to identify applications which would justify a premium value for those distinctive characteristics. Because byproducts or specialty chemicals production has been a prominent feature of oil shale industries which have flourished for periods of time in various countries, a brief review of those industries provides a starting point for this study. 9 figs., 32 tabs.

  8. Lubrication and tribology in seawater hydraulic piston pump

    Institute of Scientific and Technical Information of China (English)

    WANG Dong; LI Zhuang-yun; ZHU Yu-quan

    2003-01-01

    Water hydraulic systems have provoked major interest because of the human friendly and environmental safety aspects. Piston pump is one of the most frequently used hydraulic units in recent engineering technique. In water hydraulic piston pump, poor lubrication is more likely to happen than in oil hydraulic one because of difference in properties between water and oil. So there are some key problems such as corrosive wear and erosion, which are investigated briefly. Many new materials have been developed, which give longer life expectancies with water without corrosion and erosion. A new type of seawater hydraulic piston pumps with better suction characteristics had been developed at HUST. Much of this research has concentrated on new materials, structure and experiments, which are also specially introduced.

  9. Lubricant for cold plastic metal working

    Energy Technology Data Exchange (ETDEWEB)

    Postolov, Yu.M.; Larina, N.F.; Osadchuk, Ye.S.; Proskuryakov, V.A.; Syroyezhko, A.M.; Vikhorev, A.A.; Yakovlev, V.I.

    1980-03-28

    A lubricant is proposed for cold plastic metal working based on fatty acids from the process of pyrolysis of castor oil (ZhKPM) with increased screening properties and which improve the quality of PV of finished parts. The lubricant contains (percent): cyclohexanol 0.5-60, levulinic and/or ketoenanthic acid 0.5-20, ZhKPM up to 100; the content of ketoenanthic acid in mixture with levulinic acid is 20-50 percent. Tests of the number of proposed lubricants were conducted for cold stampling of parts from a metal strip on a 10 ton mechanical press. Tool stability (number of pieces until adhesion) was 1200-1400, purity class Pv-7. In tests under a similar condition of vegetable oil, ZhKPM and a mixture of ZhKPM with esters (nonlubricant) tool stability was 1100, and the purity class Pv-6.

  10. 采用步进式干油阀的智能干油集中润滑系统研究∗%Research on Intelligent Grease Lubrication System with Stepper Motor Valve as Oil Feeder

    Institute of Scientific and Technical Information of China (English)

    赵玉刚; 刘新玉; 王占军; 赵润; 宋严科

    2015-01-01

    A scheme of intelligent centralized grease lubrication system using stepper motor valve as oil feeder was pres⁃ented.The connection of main PLC and the configuration program of HMI were introduced,and the mechanical structure of stepper motor valve was illustrated.A scheme that more than one stepper motor is driven by only one driver was designed based on the technological requirements of centralized grease lubrication system and the control characteristic of stepper motor.The isolation circuit of the hardware was also researched.The actual application shows that the fault of the centralized grease lubrication system is reduced by using the stepper motor valve as the oil feeder. By using one driver to drive more than one stepper motor in intelligent grease lubrication system,the cost of the system is reduced, and the complexity of the system is decreased.%提出以步进式干油阀为给油器的智能干油集中润滑系统方案,介绍系统主站PLC的接线方式以及触摸屏的组态程序,并说明步进式干油阀的机械结构。在分析干油集中润滑系统的工艺要求和步进电机控制特性的基础上,提出一个驱动器驱动多个步进电机的驱动方案,并研究硬件的隔离电路。实际应用表明,采用步进式干油阀作为给油器大大降低干油集中润滑系统的故障率;在智能干油集中润滑系统中使用一台驱动器驱动多个步进电机的方式,不仅降低了系统成本,还减少了系统的复杂性。

  11. Mineral oils

    Science.gov (United States)

    Furby, N. W.

    1973-01-01

    The characteristics of lubricants made from mineral oils are discussed. Types and compositions of base stocks are reviewed and the product demands and compositions of typical products are outlined. Processes for commercial production of mineral oils are examined. Tables of data are included to show examples of product types and requirements. A chemical analysis of three types of mineral oils is reported.

  12. New Progress in Design and EngineeringDevelopment of Hydrogenation Units3 - Engineering Development and Commercial Application of Lube Oil Hydrogenation Technology

    Institute of Scientific and Technical Information of China (English)

    Liu Jiaming; Sun Lili

    2000-01-01

    @@1 Introduction With the automotive industry embarking on the de velopment route toward high speed, energy conservation, low fuel consumption, low emissions and extended oil condemning limits in the 1990s, better quality lubricant products are needed. The previous approach for im proving the performance of lubricant products through adjustment of additive composition can no more meet the demand. Higher requirements for the quality of lube base stocks are raised. These requirements are: (1) higher oxidation stability; (2) better viscosity tem perature performance; (3) better low temperature flow property; and (4) excellent shearing stability and anti wear property. In the meantime, the development of industrial technology and stricter environmental and safety requirements have raised their demand for high quality industrial lubricating oils. The quality of mineral lubricating oils made by traditional means of lube tech nology has been reaching its limits without room for fur ther improvement. In addition the crude oil resources that are suitable for making lube oils are depleting. The lube oil production is forced to opt for the inferior heavy crude, posing a difficult dilemma for the traditional petroleum processing industry.

  13. Isolation and application of Gordonia sp. JC11 for removal of boat lubricants.

    Science.gov (United States)

    Chanthamalee, Jirapat; Luepromchai, Ekawan

    2012-01-01

    Boat lubricants are continuously released into the marine environment and thereby cause chronic oil pollution. This study aims to isolate lubricant-degrading microorganisms from Thai coastal areas as well as to apply a selected strain for removal of boat lubricants. Ten microorganisms in the genera of Gordonia, Microbacterium, Acinetobacter, Pseudomonas, Brucella, Enterococcus and Candida were initially isolated by crude oil enrichment culture techniques. The lubricant-removal activity of these isolates was investigated with mineral-based lubricants that had been manufactured for the 4-stroke diesel engines of fishing boats. Gordonia sp. JC11, the most effective strain was able to degrade 25-55% of 1,000 mg L(-1) total hydrocarbons in six tested lubricants, while only 0-15% of the lubricants was abiotically removed. The bacterium had many characteristics that promoted lubricant degradation such as hydrocarbon utilization ability, emulsification activity and cell surface hydrophobicity. For bioaugmentation treatment of lubricant contaminated seawater, the inoculum of Gordonia sp. JC11 was prepared by immobilizing the bacterium on polyurethane foam (PUF). PUF-immobilized Gordonia sp. JC11 was able to remove 42-56% of 100-1,000 mg L(-1) waste lubricant No. 2 within 5 days. This lubricant removal efficiency was higher than those of free cells and PUF without bacterial cells. The bioaugmentation treatment significantly increased the number of lubricant-degrading microorganisms in the fishery port seawater microcosm and resulted in rapid removal of waste lubricant No. 2.

  14. Exploring Low Emission Lubricants for Diesel Engines

    Energy Technology Data Exchange (ETDEWEB)

    Perez, J. M.

    2000-07-06

    A workshop to explore the technological issues involved with the removal of sulfur from lubricants and the development of low emission diesel engine oils was held in Scottsdale, Arizona, January 30 through February 1, 2000. It presented an overview of the current technology by means of panel discussions and technical presentations from industry, government, and academia.

  15. 基于聚-α烯烃油的锂基润滑脂流变性%Rheological of Lithium Lubricating Grease Based on Poly-αOlefins Oil

    Institute of Scientific and Technical Information of China (English)

    周维贵; 郭小川; 蒋明俊; 郭婉晴

    2014-01-01

    为系统研究锂基润滑脂的流变性能,以12-羟基硬脂酸锂皂为稠化剂和聚-α烯烃(PAO)油为基础油制备了锂基润滑脂。考察了稠化剂含量、基础油黏度和温度对锂基润滑脂的触变性、储存模量、损耗模量、表观黏度和应变幅度等流变参数的影响,并对其影响机理进行了探讨。实验表明:锂基润滑脂是屈服性假塑性流体,在很小应变范围内以可恢复的弹性变形为主导,达到其屈服应力后,具有明显的剪切变稀现象;达到其流动点后,表现出黏性流体性质。%In order to study the rheological properties of lithium base grease in a systematic way, lithium lubricating grease is prepared with 12-hydroxy stearic acid lithium soap as the thickener and poly-αolefins(PAO)synthetic oil as base oil. The influ-ence factors such as the content of the thickener, base oil viscosity and temperature on the rheological parameters concerning thixot-ropy, storage modulus, loss modulus, apparent viscosity and strain amplitude are studied and the mechanism is also discussed. Ex-perimental results show that the lithium lubricating grease is yield pseudoplastic fluid, which is highly elastic and can restore elastic deformation at very small strain range, has obvious shear thinning phenomenon after reaching the yield stress, and is highly viscous when it reached its yield point.

  16. Amine-intercalated α-zirconium phosphates as lubricant additives

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, Huaping; Dai, Wei [Department of Mechanical Engineering, Texas A& M University, College Station, TX 77843 (United States); Kan, Yuwei; Clearfield, Abraham [Department of Chemistry, Texas A& M University, College Station, TX 77843 (United States); Liang, Hong, E-mail: hliang@tamu.edu [Department of Mechanical Engineering, Texas A& M University, College Station, TX 77843 (United States)

    2015-02-28

    In this study, three types of amines intercalated α-zirconium phosphate nanosheets with different interspaces were synthesized and examined as lubricant additives to a mineral oil. Results from tribological experiments illustrated that these additives improved lubricating performance. Results of rheological experiments showed that the viscosity of the mineral oil was effectively reduced with the addition of α-zirconium phosphate nanosheets. The two-dimensional structure, with larger interspaces, resulting from amine intercalation, exhibited improved effectiveness in reducing viscosity. This study demonstrates that the nanosheet structure of α-zirconium phosphates is effective in friction reduction. The manufacture of lubricants with tailored viscosity is possible by using different intercalators.

  17. Selective capture of water using microporous adsorbents to increase the lifetime of lubricants.

    Science.gov (United States)

    Ng, Eng-Poh; Delmotte, Luc; Mintova, Svetlana

    2009-01-01

    Long live lubricants: The selective capture of water from lubricants using nanosized microporous aluminophosphate (AEI) and aluminosilicate materials was studied. Nearly 98 % of the moisture was removed from the lubricating oil under ambient conditions, resulting in a significant improvement in the lubricating service lifetime. Moreover, both the lubricant and the microporous sorbents can be recovered and reused.The selective capture of water from lubricants using nanosized microporous aluminophosphate and aluminosilicate materials was studied with an aim to increase the lifetime of the lubricating mineral oil. The amount of water present in oxidized lubricating oil before and after treatment with microporous materials was studied by FTIR spectroscopy and determined quantitatively using the Karl Fischer titration method. Nanosized aluminophosphate revealed a high selectivity for water without adsorbing other additives, in contrast to nanosized aluminosilicates which also adsorb polar oxidation products and ionic additives. About 98 % of the initial moisture could be removed from the lubricating oil under ambient conditions, resulting in a significant improvement in the lubricating service lifetime. Moreover, no by-products are formed during the process and both the lubricant and the sorbents can be recovered and reused, thus the method is environmentally friendly.

  18. Experimental study of tribological properties of nano-diamond as an additive in lubricating oil%添加纳米金刚石润滑油的摩擦学性能试验研究

    Institute of Scientific and Technical Information of China (English)

    黄红; 王伟; 刘焜

    2011-01-01

    Nano-diamond particles as an additive were dispersed in lubricating oil. The experiments were performed by using a HQ-800 four-ball tester, a M-200 machine and a HDM-20 face to face tester. The antiwear and anti-friction abilities of the 46# base oil with different content of nano-diarnond were evaluated in three different friction contact modes, namely spot contact, line contact and surface contact respectively. The tribological properties of nano-diamond as the oil additive were studied and the optimal content of nano-diamond in different contact state was identified. The results indicate that the nano-diamond additive in lubricanring oil show its different tribological performance in various forms of friction contact.%文章对纳米金刚石做添加剂的润滑油进行一定的分散,并采用HQ-800四球摩擦磨损试验机、M-200摩擦磨损试验机、HDM-20端面摩擦试验机对添加不同质量分数的纳米金刚石的46

  19. 基于SRV的润滑油高温润滑性能测试方法的研究%Investigation on the High-temperature Lubrication Property of Oil Using SRV

    Institute of Scientific and Technical Information of China (English)

    王渊渊; 熊春华; 乔小溪; 徐金龙; 赵巍; 张向军

    2011-01-01

    A testing approach was built to screen the lubrication oils with high-temperature property,and to provide a quantitative parameters to characterize the extreme working temperature and anti-wear ability under high temperature. In this method,the oil limit temperature can be obtained through the curve of average wear and friction coefficient changes with temperature, the high temperature performance of the oil can be assessed through the curve of high temperature pv val-ue. The method was used to test three kinds of lubricating oils,the result was compared with that of oil design formula anal-ysis. The results show that the method is accurate and simple, which can be use to quantitatively assess and contrast ex-treme working temperature and high temperature resistant of the oils.%为选择比较在高温工况条件下具有最佳摩擦磨损性能的润滑油,定量表征润滑油的极限工作温度和高温耐磨性能,提出一种润滑油的极限工作温度和高温耐磨性能测试方法.该方法通过磨损量和平均摩擦因数随温度的变化,来得到油品的极限工作温度,通过高温下pv值曲线来定量评定油品的高温工作性能.利用该方法对3种润滑油进行测试分析,并结合油品设计配方进行分析.结果表明,该方法可以简单、准确且定量的评定、比较润滑油的极限工作温度和高温耐磨性能.

  20. 润滑油对水平强化管降膜蒸发传热特性的影响%Effect of Lubricating Oil on Heat Transfer Performance of Falling Film Evaporation on Horizontal Enhanced Tube

    Institute of Scientific and Technical Information of China (English)

    李敏霞; 蔡文生; 孙晗; 党超镔; 吕佳桐

    2015-01-01

    实际制冷系统中的制冷剂含有压缩机的润滑油.本文研究了制冷剂中润滑油不同含油率时水平管降膜式蒸发传热特性.工质为R134a,含油率分别为0.5%、1.2%、5.1%,蒸发温度为6,℃,热流密度范围为30~65,kW/m2,工质喷淋密度分别为0.13,kg/(s·m),0.17,kg/(s·m)、0.21 kg/(s·m),测试段采用表面强化的铜管.实验结果表明:含油率从0.5%增大到5.1%,管外传热性能逐渐提高,当喷淋密度增加,管外换热系数也会提高,但随着含油率的增加,换热系数的增加幅度不大;一定含量的润滑油能增大R134a水平管降膜蒸发的换热系数.%In engineering practice,refrigerant contains lubricating oil form compressor in the refrigerating system. In this study,the impact of different oil contents on evaporation of falling film on horizontal enhanced tube was dis-cussed. Experiments were conducted for R134a at the saturation temperature of 6,℃ on enhanced copper tube,with oil contents being 0.5%,1.2% and 5.1%,respectively,and heat fluxes ranging from 30,kW/m2 to 65,kW/m2, sprinkle densities being 0.13,0.17,and 0.21,kg/(s·m). The experimental results show that heat transfer coefficient of the outside horizontal enhanced tube increases with both oil contents growing from 0.5% to 5.1% and increasing sprinkle densities. However,with the augments of oil contents,the increases of heat transfer coefficient are nearly insensitive to the increasing sprinkle densities. In certain range of content,lubricating oil can improve heat transfer coefficient of R134a falling film evaporation.

  1. Tribological Behavior of Journal Bearing Material under Different Lubricants

    OpenAIRE

    2014-01-01

    The friction and wear behavior of journal bearing material has been investigated using pin on disc wear tester with three different lubricating oils i.e. synthetic lubricating oil (SAE20W40), chemically modified rapeseed oil (CMRO), chemically modified rapeseed oil with Nano CuO. Wear tests were carried out at maximum load of 200 N and sliding speeds of 2 – 10 m/s. The results showed that the friction and wear behavior of the journal bearing material have changed according to the sliding cond...

  2. A new state evaluation method of oil pump unit based on AHP and FCE

    Science.gov (United States)

    Lin, Yang; Liang, Wei; Qiu, Zeyang; Zhang, Meng; Lu, Wenqing

    2017-05-01

    In order to make an accurate state evaluation of oil pump unit, a comprehensive evaluation index should be established. A multi-parameters state evaluation method of oil pump unit is proposed in this paper. The oil pump unit is analyzed by Failure Mode and Effect Analysis (FMEA), so evaluation index can be obtained based on FMEA conclusions. The weights of different parameters in evaluation index are discussed using Analytic Hierarchy Process (AHP) with expert experience. According to the evaluation index and the weight of each parameter, the state evaluation is carried out by Fuzzy Comprehensive Evaluation (FCE) and the state is divided into five levels depending on status value, which is inspired by human body health. In order to verify the effectiveness and feasibility of the proposed method, a state evaluation of oil pump used in a pump station is taken as an example.

  3. Surfactant effects on bio-based emulsions used as lubrication fluids

    Science.gov (United States)

    The successful formulation of a lubricating emulsion requires carefully balancing the mixture of base oil, water and a plethora of additives. The factors that affect the performance of lubrication emulsions range from the macroscopic stability to the microscopic surface properties of the base oil. ...

  4. National Assessment of Oil and Gas - Neogene System Assessment Units of the Gulf Coast (Provinces 047, 048 and 049)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  5. National Assessment of Oil and Gas Project - Raton Basin-Sierra Grande Uplift Province (041) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  6. USGS National and Global Oil and Gas Assessment Project-Gulf Coast Mesozoic Province, Haynesville Formation Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  7. USGS National and Global Oil and Gas Assessment Project-Gulf Coast Mesozoic Province, Bossier Formation Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  8. National Assessment of Oil and Gas Project - Northern Alaska Gas Hydrate Total Petroleum System, Northern Alaska Province (001) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  9. National Assessment of Oil and Gas Project Bend Arch-Fort Worth Basin Province (045) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  10. National Assessment of Oil and Gas Project Devonian Marcellus Shale of the Appalachian Basin Province (067) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  11. USGS National and Global Oil and Gas Assessment Project-Permian Basin Province, Val Verde Basin, Canyon Sandstones Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  12. National Assessment of Oil and Gas Project - Brookian Coalbed Gas Composite Total Petroleum System, Northern Alaska Province (001) Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  13. National Assessment of Oil and Gas - Upper Cretaceous Taylor and Navarro Group Assessment Units, Western Gulf Province (047)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  14. USGS National and Global Oil and Gas Assessment Project-Permian Basin Province, Midland Basin, Wolfcamp Shale Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  15. USGS National Assessment of Oil and Gas Project - Mississippian Barnett Shale, Bend Arch-Fort Worth Basin Province Assessment Units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Assessment Unit is the fundamental unit used in the National Assessment Project for the assessment of undiscovered oil and gas resources. The Assessment Unit is...

  16. Ball Bearings Equipped for In Situ Lubrication on Demand

    Science.gov (United States)

    Marchetti, Mario; Jones, William R., Jr.; Pepper, Stephen V.; Jansen, Mark; Predmore, Roamer

    2005-01-01

    In situ systems that provide fresh lubricants to ball/race contacts on demand have been developed to prolong the operational lives of ball bearings. These systems were originally intended to be incorporated into ball bearings in mechanisms that are required to operate in outer space for years, in conditions in which lubricants tend to deteriorate and/or evaporate. These systems may also be useful for similarly prolonging bearing lifetimes on Earth. Reservoirs have been among the means used previously to resupply lubricants. Lubricant- resupply reservoirs are bulky and add complexity to bearing assemblies. In addition, such a reservoir cannot be turned on or off as needed: it supplies lubricant continuously, often leading to an excess of lubricant in the bearing. A lubricator of the present type includes a porous ring cartridge attached to the inner or the outer ring of a ball bearing (see Figure 1). Oil is stored in the porous cartridge and is released by heating the cartridge: Because the thermal expansion of the oil exceeds that of the cartridge, heating causes the ejection of some oil. A metal film can be deposited on a face of the cartridge to serve as an electrical-resistance heater. The heater can be activated in response to a measured increase in torque that signals depletion of oil from the bearing/race contacts. Because the oil has low surface tension and readily wets the bearing-ring material, it spreads over the bearing ring and eventually reaches the ball/race contacts. The Marangoni effect (a surface-tension gradient associated with a temperature gradient) is utilized to enhance the desired transfer of lubricant to the ball/race contacts during heating. For a test, a ball bearing designed for use at low speed was assembled without lubricant and equipped with a porous-ring lubricator, the resistance heater of which consumed a power of less than 1 W when triggered on by a torque-measuring device. In the test, a load of 20 lb (.89 N) was applied and the

  17. Research on Friction Properties of Mineral Lubricants in Thin-Film-Lubricating Regime

    Institute of Scientific and Technical Information of China (English)

    Zhang Jie; Guan Tingting; Piao Jicheng

    2014-01-01

    On the basis of thin iflm lubrication theory, the inlfuence of lfuid iflm (disordered iflm), ordered iflm and ad-sorbed iflm on tribological behavior of lubricating oil in thin-iflm lubrication (TFL) regime was studied. Theμ-L (friction coefifcient versus load) curves of different oil viscosity and additive dosage were obtained by a high frequency reciprocat-ing test rig and the adsorption capacity of additive on steel surface were measured by QCM-D. Based on the Stribeck curve and thin iflm lubrication theory model, some conclusions can be drawn up, namely:(1) Theμ-L curves and the parameters of L0 andμ0, obtained from the high frequency reciprocating test rig with ball-disc contact, can be used to study tribologi-cal behaviors of lubricating oil under TFL conditions. (2) In comparison with the high viscosity base lfuid, the lower one can enter into TFL regime under lower load and keeps a lower friction coefifcient in TFL regime. (3) The polar molecules in additive formulation produce ordered adsorbed layer on steel surface to reduce friction coefifcient. And in TFL regime, the molecule’s polarity, layer thickness and saturation degree on steel surface probably can inlfuence lubricant’s tribological behaviors between the moving interfaces. Moreover, the further study would be focused on the competitive adsorption of different additives, the formation of dual-and/or tri-molecular adsorption layers, and other aspects.

  18. Assessment of Introital Lubrication.

    Science.gov (United States)

    Dawson, Samantha J; Sawatsky, Megan L; Lalumière, Martin L

    2015-08-01

    Vaginal vasocongestion and lubrication serve to prepare the vaginal lumen for sexual activity. Lubrication is important for sexual functioning and difficulties with lubrication are one of the most commonly reported symptoms of sexual dysfunction. Few studies have empirically examined how vasocongestion and lubrication relate to one another and there are currently no well-established measures of lubrication. In this study, we designed and tested a simple method to assess lubrication at the vaginal introitus in 19 healthy women, using litmus test strips. We examined the relationship between lubrication and vaginal vasocongestion (measured with a photoplethysmograph) when elicited by audiovisual sexual stimuli (male-female sexual interactions). Lubrication was elicited by the sexual stimuli and was strongly correlated with reports of sexual arousal. Unexpectedly, lubrication was not correlated with vasocongestion, even though the latter was also elicited by the sexual stimuli. We discuss the implications of these findings for informing our understanding of the female sexual response and the potential clinical and scientific utility of this new measure.

  19. Fundamentals of fluid lubrication

    Science.gov (United States)

    Hamrock, Bernard J.

    1991-01-01

    The aim is to coordinate the topics of design, engineering dynamics, and fluid dynamics in order to aid researchers in the area of fluid film lubrication. The lubrication principles that are covered can serve as a basis for the engineering design of machine elements. The fundamentals of fluid film lubrication are presented clearly so that students that use the book will have confidence in their ability to apply these principles to a wide range of lubrication situations. Some guidance on applying these fundamentals to the solution of engineering problems is also provided.

  20. Grease lubrication in rolling bearings

    CERN Document Server

    Lugt, Piet M

    2012-01-01

    The definitive book on the science of grease lubrication for roller and needle bearings in industrial and vehicle engineering. Grease Lubrication in Rolling Bearings provides an overview of the existing knowledge on the various aspects of grease lubrication (including lubrication systems) and the state of the art models that exist today. The book reviews the physical and chemical aspects of grease lubrication, primarily directed towards lubrication of rolling bearings. The first part of the book covers grease composition, properties and rheology, including thermal