WorldWideScience

Sample records for understanding depositional processes

  1. Quantitative analysis of precipitation over Fukushima to understand the wet deposition process in March 2011

    Science.gov (United States)

    Yatagai, A.; Onda, Y.; Watanabe, A.

    2012-04-01

    The Great East Japan Earthquake caused a severe accident at the Fukushima-Daiichi nuclear power plant (NPP), leading to the emission of large amounts of radioactive pollutants into the environment. The transport and diffusion of these radioactive pollutants in the atmosphere caused a disaster for residents in and around Fukushima. Studies have sought to understand the transport, diffusion, and deposition process, and to understand the movement of radioactive pollutants through the soil, vegetation, rivers, and groundwater. However, a detailed simulation and understanding of the distribution of radioactive compounds depend on a simulation of precipitation and on the information on the timing of the emission of these radioactive pollutants from the NPP. Past nuclear expansion studies have demonstrated the importance of wet deposition in distributing pollutants. Hence, this study examined the quantitative precipitation pattern in March 2011 using rain-gauge observations and X-band radar data from Fukushima University. We used the AMeDAS rain-gauge network data of 1) the Japan Meteorological Agency (1273 stations in Japan) and 2) the Water Information System (47 stations in Fukushima prefecture) and 3) the rain-gauge data of the Environmental Information Network of NTT Docomo (30 stations in Fukushima) to construct 0.05-degree mesh data using the same method used to create the APHRODITE daily grid precipitation data (Yatagai et al., 2009). Since some AMeDAS data for the coastal region were lost due to the earthquake, the complementary network of 2) and 3) yielded better precipitation estimates. The data clarified that snowfall was observed on the night of Mar 15 into the morning of Mar 16 throughout Fukushima prefecture. This had an important effect on the radioactive contamination pattern in Fukushima prefecture. The precipitation pattern itself does not show one-on-one correspondence with the contamination pattern. While the pollutants transported northeast of the

  2. Global change and modern coral reefs: New opportunities to understand shallow-water carbonate depositional processes

    Science.gov (United States)

    Hallock, Pamela

    2005-04-01

    Human activities are impacting coral reefs physically, biologically, and chemically. Nutrification, sedimentation, chemical pollution, and overfishing are significant local threats that are occurring worldwide. Ozone depletion and global warming are triggering mass coral-bleaching events; corals under temperature stress lose the ability to synthesize protective sunscreens and become more sensitive to sunlight. Photo-oxidative stress also reduces fitness, rendering reef-building organisms more susceptible to emerging diseases. Increasing concentration of atmospheric CO 2 has already reduced CaCO 3 saturation in surface waters by more than 10%. Doubling of atmospheric CO 2 concentration over pre-industrial concentration in the 21st century may reduce carbonate production in tropical shallow marine environments by as much as 80%. As shallow-water reefs decline worldwide, opportunities abound for researchers to expand understanding of carbonate depositional systems. Coordinated studies of carbonate geochemistry with photozoan physiology and calcification, particularly in cool subtropical-transition zones between photozoan-reef and heterotrophic carbonate-ramp communities, will contribute to understanding of carbonate sedimentation under environmental change, both in the future and in the geologic record. Cyanobacteria are becoming increasingly prominent on declining reefs, as these microbes can tolerate strong solar radiation, higher temperatures, and abundant nutrients. The responses of reef-dwelling cyanobacteria to environmental parameters associated with global change are prime topics for further research, with both ecological and geological implications.

  3. Database development for understanding the wet deposition and dispersion processes after the Fukushima nuclear plant accident. Radar data

    International Nuclear Information System (INIS)

    Yatagai, Akiyo; Takara, Kaoru; Ishihara, Masahito; Ishikawa, Hirohiko; Watanabe, Akira; Murata, Ken T.

    2015-01-01

    This manuscript describes datasets of meteorological information being developed for understanding the dispersion and deposition process of radionuclides associated with the Fukushima accident in March 2011. Among several products, this paper reports mainly our original radar data images including the X-band radar data from Fukushima University as well as the three-dimensional reflectivity data from the Japan Meteorological Agency C-band radar network. (author)

  4. Understanding the spectrum of diesel injector deposits

    Energy Technology Data Exchange (ETDEWEB)

    Quigley, Robert; Barbour, Robert [Lubrizol Limited, Derby (United Kingdom); Arters, David; Bush, Jim [Lubrizol Corporation, Wickliffe, OH (United States)

    2013-06-01

    Understanding the origin of diesel fuel injector deposits used to be relatively simple; for the most part they were caused by the decomposition of fuel during the combustion process, were generally organic in nature and typically only affected the nozzle orifices. However, modem fuel injector designs appear to be both more severe in terms of generating conditions conducive to creating new and different types of deposits and more likely to have their operation affected by those deposits. Changes to fuel composition and type have in some cases increased the potential pool of reactive species or provided new potential deposit precursors. As a result, the universe of diesel injector deposits now range from the traditional organic to partially or fully inorganic in nature and from nozzle coking deposits to deposits which can seize the internal components of the injector; so called internal diesel injector deposits. Frequently, combinations of inorganic and organic deposits are found. While power loss is one well known issue associated with nozzle deposits, other field problems resulting from these new deposits include severe issues with drivability, emissions, fuel consumption and even engine failure. Conventional deposit control additive chemistries were developed to be effective against organic nozzle coking deposits. These conventional additives in many cases may prove ineffective against this wide range of deposit types. This paper discusses the range of deposits that have been found to adversely impact modem diesel fuel injectors and compares the performance of conventional and new, advanced deposit control additives against these various challenges to proper fuel injector functioning. (orig.)

  5. Petrography and Mineral Chemistry of Magmatic and Hydrothermal Biotite in Porphyry Copper-Gold Deposits: A Tool for Understanding Mineralizing Fluid Compositional Changes During Alteration Processes

    OpenAIRE

    Arifudin Idrus

    2018-01-01

    DOI: 10.17014/ijog.5.1.47-64This study aims to understand the petrography and chemistry of both magmatic and hydrothermal biotites in porphyry copper-gold deposits, and to evaluate the fluid compositional changes during alteration processes. A total of 206 biotite grains from selected rock samples taken from the Batu Hijau porphyry Cu-Au deposit was analyzed. Detailed petrography and biotite chemistry analysis were performed on thin sections and polished thin sections, respectively, represent...

  6. Understanding Contaminants Associated with Mineral Deposits

    Science.gov (United States)

    Verplanck, Philip L.

    2008-01-01

    Interdisciplinary studies by the U.S. Geological Survey (USGS) have resulted in substantial progress in understanding the processes that control *the release of metals and acidic water from inactive mines and mineralized areas, *the transport of metals and acidic water to streams, and *the fate and effect of metals and acidity on downstream ecosystems. The potential environmental effects associated with abandoned and inactive mines, resulting from the complex interaction of a variety of chemical and physical processes, is an area of study that is important to the USGS Mineral Resources Program. Understanding the processes contributing to the environmental effects of abandoned and inactive mines is also of interest to a wide range of stakeholders, including both those responsible for managing lands with historically mined areas and those responsible for anticipating environmental consequences of future mining operations. The recently completed (2007) USGS project entitled 'Process Studies of Contaminants Associated with Mineral Deposits' focused on abandoned and inactive mines and mineralized areas in the Rocky Mountains of Montana, Colorado, New Mexico, Utah, and Arizona, where there are thousands of abandoned mines. Results from these studies provide new information that advances our understanding of the physical and biogeochemical processes causing the mobilization, transport, reaction, and fate of potentially toxic elements (including aluminum, arsenic, cadmium, copper, iron, lead, and zinc) in mineralized near-surface systems and their effects on aquatic and riparian habitat. These interdisciplinary studies provide the basis for scientific decisionmaking and remedial action by local, State, and Federal agencies charged with minimizing the effects of potentially toxic elements on the environment. Current (2007) USGS research highlights the need to understand (1) the geologic sources of metals and acidity and the geochemical reactions that release them from their

  7. Earth Surface Processes, Landforms and Sediment Deposits

    Science.gov (United States)

    Bridge, John; Demicco, Robert

    Earth surface processes, landforms and sediment deposits are intimately related - involving erosion of rocks, generation of sediment, and transport and deposition of sediment through various Earth surface environments. These processes, and the landforms and deposits that they generate, have a fundamental bearing on engineering, environmental and public safety issues; on recovery of economic resources; and on our understanding of Earth history. This unique textbook brings together the traditional disciplines of sedimentology and geomorphology to explain Earth surface processes, landforms and sediment deposits in a comprehensive and integrated way. It is the ideal resource for a two-semester course in sedimentology, stratigraphy, geomorphology, and Earth surface processes from the intermediate undergraduate to beginning graduate level. The book is also accompanied by a website hosting illustrations and material on field and laboratory methods for measuring, describing and analyzing Earth surface processes, landforms and sediments.

  8. Petrography and Mineral Chemistry of Magmatic and Hydrothermal Biotite in Porphyry Copper-Gold Deposits: A Tool for Understanding Mineralizing Fluid Compositional Changes During Alteration Processes

    Directory of Open Access Journals (Sweden)

    Arifudin Idrus

    2018-01-01

    Full Text Available DOI: 10.17014/ijog.5.1.47-64This study aims to understand the petrography and chemistry of both magmatic and hydrothermal biotites in porphyry copper-gold deposits, and to evaluate the fluid compositional changes during alteration processes. A total of 206 biotite grains from selected rock samples taken from the Batu Hijau porphyry Cu-Au deposit was analyzed. Detailed petrography and biotite chemistry analysis were performed on thin sections and polished thin sections, respectively, representing various rocks and alteration types. A JEOL JXA-8900R electron microprobe analyzer (EMPA was used for the chemistry analysis. The biotite is texturally divided into magmatic and hydrothermal types. Ti, Fe, and F contents can be used to distinguish the two biotite types chemically. Some oxide and halogen contents of biotite from various rocks and alteration types demonstrate a systematic variation in chemical composition. Biotite halogen chemistry shows a systematic increase in log (XCl/XOH and decrease in log (XF/XOH values from biotite (potassic through chlorite-sericite (intermediate argillic to actinolite (inner propylitic zones. The y-intercepts on the log (XCl/XOH vs. XMg and log (XF/XOH vs. XFe plotted for biotite from potassic and intermediate argillic zones are similar or slightly different. In contrast, the y-intercepts on the log (XCl/XOH vs. XMg and log (XF/XOH vs. XFe plotted for biotite from inner propylitic zone display different values in comparison to the two alteration zones. Halogen (F,Cl fugacity ratios in biotite show a similar pattern: in the potassic and intermediate argillic zones they show little variation, whereas in the inner propylitic zone they are distinctly different. These features suggest the hydrothermal fluid composition remained fairly constant in the inner part of the deposit during the potassic and intermediate argillic alteration events, but changed significantly towards the outer part affected by inner propylitic

  9. Understanding error generation in fused deposition modeling

    International Nuclear Information System (INIS)

    Bochmann, Lennart; Transchel, Robert; Wegener, Konrad; Bayley, Cindy; Helu, Moneer; Dornfeld, David

    2015-01-01

    Additive manufacturing offers completely new possibilities for the manufacturing of parts. The advantages of flexibility and convenience of additive manufacturing have had a significant impact on many industries, and optimizing part quality is crucial for expanding its utilization. This research aims to determine the sources of imprecision in fused deposition modeling (FDM). Process errors in terms of surface quality, accuracy and precision are identified and quantified, and an error-budget approach is used to characterize errors of the machine tool. It was determined that accuracy and precision in the y direction (0.08–0.30 mm) are generally greater than in the x direction (0.12–0.62 mm) and the z direction (0.21–0.57 mm). Furthermore, accuracy and precision tend to decrease at increasing axis positions. The results of this work can be used to identify possible process improvements in the design and control of FDM technology. (paper)

  10. Understanding error generation in fused deposition modeling

    Science.gov (United States)

    Bochmann, Lennart; Bayley, Cindy; Helu, Moneer; Transchel, Robert; Wegener, Konrad; Dornfeld, David

    2015-03-01

    Additive manufacturing offers completely new possibilities for the manufacturing of parts. The advantages of flexibility and convenience of additive manufacturing have had a significant impact on many industries, and optimizing part quality is crucial for expanding its utilization. This research aims to determine the sources of imprecision in fused deposition modeling (FDM). Process errors in terms of surface quality, accuracy and precision are identified and quantified, and an error-budget approach is used to characterize errors of the machine tool. It was determined that accuracy and precision in the y direction (0.08-0.30 mm) are generally greater than in the x direction (0.12-0.62 mm) and the z direction (0.21-0.57 mm). Furthermore, accuracy and precision tend to decrease at increasing axis positions. The results of this work can be used to identify possible process improvements in the design and control of FDM technology.

  11. Understanding the chemical vapor deposition of diamond: recent progress

    International Nuclear Information System (INIS)

    Butler, J E; Mankelevich, Y A; Cheesman, A; Ma, Jie; Ashfold, M N R

    2009-01-01

    In this paper we review and provide an overview to the understanding of the chemical vapor deposition (CVD) of diamond materials with a particular focus on the commonly used microwave plasma-activated chemical vapor deposition (MPCVD). The major topics covered are experimental measurements in situ to diamond CVD reactors, and MPCVD in particular, coupled with models of the gas phase chemical and plasma kinetics to provide insight into the distribution of critical chemical species throughout the reactor, followed by a discussion of the surface chemical process involved in diamond growth.

  12. Understanding the Budget Process

    Directory of Open Access Journals (Sweden)

    Mesut Yalvaç

    2000-03-01

    Full Text Available Many different budgeting techniques can be used in libraries, and some combination of these will be appropriate for almost any individual situation. Li-ne-item, program, performance, formula, variable, and zero-base budgets all have features that may prove beneficial in the preparation of a budget. Budgets also serve a variety of functions, providing for short-term and long-term financial planning as well as for cash management over a period of time. Short-term plans are reflected in the operating budget, while long-term plans are reflected in the capital budget. Since the time when cash is available to an organization does not usually coincide with the time that disbursements must be made, it is also important to carefully plan for the inflow and outflow of funds by means of a cash budget.      During the budget process an organization selects its programs and activities by providing the necessary funding; the library, along with others in the organization, must justify its requests. Because of the cyclical nature of the budget process, it is possible continually to gather information and evaluate alternatives for the next budget period so that the library may achieve its maximum potential for service to its patrons.

  13. Understanding the consultation processes

    International Nuclear Information System (INIS)

    Laing, A.C.

    1998-01-01

    This presentation focuses on the consultation processes between industry, government and First Nations communities regarding resource development. The expectations of the Crown are to facilitate capacity building within First Nations, to promote traditional use studies and to participate with industry proponents on certain consultation issues. The role of industry is to encourage partnerships between established contractors and First Nations contracting firms to allow First Nations firms to grow and experience success under the guidance of a mentor company. It is important to realize that solid First Nations relations are the key to shorter time lines and lower costs in developing projects. However, consultation and involvement must be 'real' with benefits and participation that fall within the First Nations Communities' definition of success

  14. What makes process models understandable?

    NARCIS (Netherlands)

    Mendling, J.; Reijers, H.A.; Cardoso, J.; Alonso, G.; Dadam, P.; Rosemann, M.

    2007-01-01

    Despite that formal and informal quality aspects are of significant importance to business process modeling, there is only little empirical work reported on process model quality and its impact factors. In this paper we investigate understandability as a proxy for quality of process models and focus

  15. Uranium ore deposits: geology and processing implications

    International Nuclear Information System (INIS)

    Belyk, C.L.

    2010-01-01

    There are fifteen accepted types of uranium ore deposits and at least forty subtypes readily identified around the world. Each deposit type has a unique set of geological characteristics which may also result in unique processing implications. Primary uranium production in the past decade has predominantly come from only a few of these deposit types including: unconformity, sandstone, calcrete, intrusive, breccia complex and volcanic ones. Processing implications can vary widely between and within the different geological models. Some key characteristics of uranium deposits that may have processing implications include: ore grade, uranium and gangue mineralogy, ore hardness, porosity, uranium mineral morphology and carbon content. Processing difficulties may occur as a result of one or more of these characteristics. In order to meet future uranium demand, it is imperative that innovative processing approaches and new technological advances be developed in order that many of the marginally economic traditional and uneconomic non-traditional uranium ore deposits can be exploited. (author)

  16. Deposit control in process cooling water systems

    International Nuclear Information System (INIS)

    Venkataramani, B.

    1981-01-01

    In order to achieve efficient heat transfer in cooling water systems, it is essential to control the fouling of heat exchanger surfaces. Solubilities of scale forming salts, their growth into crystals, and the nature of the surfaces play important roles in the deposition phenomenon. Condensed phosphates, organic polymers and compounds like phosphates are effective in controlling deposition of scale forming salts. The surface active agents inhibit crystal growth and modify the crystals of the scale forming salts, and thus prevent deposition of dense, uniformly structured crystalline mass on the heat transfer surface. Understanding the mechanism of biofouling is essential to control it by surface active agents. Certain measures taken in the plant, such as back flushing, to control scaling, sometimes may not be effective and can be detrimental to the system itself. (author)

  17. A review: deposition and resuspension processes

    International Nuclear Information System (INIS)

    Sehmel, G.A.

    1979-01-01

    A review chapter was written on deposition and resuspension processes for the forthcoming Department of Energy publication, Atmospheric Sciences and Power Production, edited by D. Randerson. The chapter includes eleven tables and thirteen figures summarizing data from 241 references. The conclusions of that review chapter are given

  18. Modeling of gas flow and deposition profile in HWCVD processes

    Energy Technology Data Exchange (ETDEWEB)

    Pflug, Andreas; Höfer, Markus; Harig, Tino; Armgardt, Markus; Britze, Chris; Siemers, Michael; Melzig, Thomas; Schäfer, Lothar

    2015-11-30

    Hot wire chemical vapor deposition (HWCVD) is a powerful technology for deposition of high quality films on large area, where drawbacks of plasma based technology such as defect generation by ion bombardment and high equipment costs are omitted. While processes for diamond coatings using H{sub 2} and CH{sub 4} as precursor have been investigated in detail since 1990 and have been transferred to industry, research also focuses on silicon based coatings with H{sub 2}, SiH{sub 4} and NH{sub 3} as process gases. HWCVD of silicon based coatings is a promising alternative for state-of-the-art radiofrequency-plasma enhanced chemical vapor deposition reactors. The film formation in HWCVD results from an interaction of several concurrent chemical reactions such as gas phase chemistry, film deposition, abstraction of surplus hydrogen bonds and etching by atomic hydrogen. Since there is no easy relation between process parameters and resulting deposition profiles, substantial experimental effort is required to optimize the process for a given film specification and the desired film uniformity. In order to obtain a deeper understanding of the underlying mechanisms and to enable an efficient way of process optimization, simulation methods come into play. While diamond deposition occurs at pressures in the range of several kPa HWCVD deposition of Si based coatings operates at pressures in the 0.1–30 Pa range. In this pressure regime, particle based simulation methods focused on solving the Boltzmann equation are computationally feasible. In comparison to computational fluid dynamics this yields improved accuracy even near small gaps or orifices, where characteristic geometric dimensions approach the order of the mean free path of gas molecules. At Fraunhofer IST, a parallel implementation of the Direct Simulation Monte Carlo (DSMC) method extended by a reactive wall chemistry model is developed. To demonstrate the feasibility of three-dimensional simulation of HWCVD processes

  19. From Process Understanding to Process Control

    NARCIS (Netherlands)

    Streefland, M.

    2010-01-01

    A licensed pharmaceutical process is required to be executed within the validated ranges throughout the lifetime of product manufacturing. Changes to the process usually require the manufacturer to demonstrate that the safety and efficacy of the product remains unchanged. Recent changes in the

  20. Process maps for plasma spray. Part II: Deposition and properties

    International Nuclear Information System (INIS)

    XIANGYANG, JIANG; MATEJICEK, JIRI; KULKARNI, ANAND; HERMAN, HERBERT; SAMPATH, SANJAY; GILMORE, DELWYN L.; NEISER A, RICHARD Jr.

    2000-01-01

    This is the second paper of a two part series based on an integrated study carried out at the State University of New York at Stony Brook and Sandia National Laboratories. The goal of the study is the fundamental understanding of the plasma-particle interaction, droplet/substrate interaction, deposit formation dynamics and microstructure development as well as the deposit property. The outcome is science-based relationships, which can be used to link processing to performance. Molybdenum splats and coatings produced at 3 plasma conditions and three substrate temperatures were characterized. It was found that there is a strong mechanical/thermal interaction between droplet and substrate, which builds up the coatings/substrate adhesion. Hardness, thermal conductivity, and modulus increase, while oxygen content and porosity decrease with increasing particle velocity. Increasing deposition temperature resulted in dramatic improvement in coating thermal conductivity and hardness as well as increase in coating oxygen content. Indentation reveals improved fracture resistance for the coatings prepared at higher deposition temperature. Residual stress was significantly affected by deposition temperature, although not significant by particle energy within the investigated parameter range. Coatings prepared at high deposition temperature with high-energy particles suffered considerably less damage in wear tests. Possible mechanisms behind these changes are discussed within the context of relational maps which are under development

  1. Career management: understanding the process.

    Science.gov (United States)

    Mackowiak, J; Eckel, F M

    1985-02-01

    This article is the first of a three-part series on career management for hospital pharmacists. Work attitudes, life cycles, needs, and career trends are discussed. Three basic work attitudes exist. Some see work as punishment. Others believe work in itself is good, i.e., they have a strong work ethic. Some view work as a means to satisfy, at least partially, a range of needs. Attitudinal transition points are likely to occur at specific times in the adult life cycle. The stages of the life cycle can be labeled as leaving, reaching out, questioning, midlife crisis, settling down, and mellowing. A progression through each of these stages is required for normal adult psychological development. Every individual exhibits a blend of needs that changes throughout life. Jobs can fulfill existence, relatedness, and growth needs. Relatedness needs include the need for love, affiliation, social esteem, and power, and growth needs include the need for self-esteem, competence, achievement, and autonomy. Three important career trends are the changing opportunities for advancement, women in careers, and dual-career couples. The number of women pharmacists is increasing as is the number of two-career couples. Tips for managing two-career relationships are presented. Pharmacists can manage their careers more effectively by understanding their needs, identifying their basic attitude toward work, and being aware of the trends occurring in pharmacy.

  2. Theoretical modelling of carbon deposition processes

    International Nuclear Information System (INIS)

    Marsh, G.R.; Norfolk, D.J.; Skinner, R.F.

    1985-01-01

    Work based on capsule experiments in the BNL Gamma Facility, aimed at elucidating the chemistry involved in the formation of carbonaceous deposit on CAGR fuel pin surfaces is described. Using a data-base derived from capsule experiments together with literature values for the kinetics of the fundamental reactions, a chemical model of the gas-phase processes has been developed. This model successfully reproduces the capsule results, whilst preliminary application to the WAGR coolant circuit indicates the likely concentration profiles of various radical species within the fuel channels. (author)

  3. Microcrystalline silicon deposition: Process stability and process control

    International Nuclear Information System (INIS)

    Donker, M.N. van den; Kilper, T.; Grunsky, D.; Rech, B.; Houben, L.; Kessels, W.M.M.; Sanden, M.C.M. van de

    2007-01-01

    Applying in situ process diagnostics, we identified several process drifts occurring in the parallel plate plasma deposition of microcrystalline silicon (μc-Si:H). These process drifts are powder formation (visible from diminishing dc-bias and changing spatial emission profile on a time scale of 10 0 s), transient SiH 4 depletion (visible from a decreasing SiH emission intensity on a time scale of 10 2 s), plasma heating (visible from an increasing substrate temperature on a time scale of 10 3 s) and a still puzzling long-term drift (visible from a decreasing SiH emission intensity on a time scale of 10 4 s). The effect of these drifts on the crystalline volume fraction in the deposited films is investigated by selected area electron diffraction and depth-profiled Raman spectroscopy. An example shows how the transient depletion and long-term drift can be prevented by suitable process control. Solar cells deposited using this process control show enhanced performance. Options for process control of plasma heating and powder formation are discussed

  4. Understanding Patients? Process to Use Medical Marijuana

    OpenAIRE

    Crowell, Tara L

    2016-01-01

    Given the necessity to better understand the process patients need to go through in order to seek treatment via medical marijuana, this study investigates this process to better understand this phenomenon. Specifically, Compassion Care Foundation (CCF) and Stockton University worked together to identify a solution to this problem. Specifically, 240 new patients at CCF were asked to complete a 1-page survey regarding various aspects associated with their experience prior to their use of medici...

  5. Understanding Patients’ Process to Use Medical Marijuana

    Directory of Open Access Journals (Sweden)

    Tara L Crowell

    2016-09-01

    Full Text Available Given the necessity to better understand the process patients need to go through in order to seek treatment via medical marijuana, this study investigates this process to better understand this phenomenon. Specifically, Compassion Care Foundation (CCF and Stockton University worked together to identify a solution to this problem. Specifically, 240 new patients at CCF were asked to complete a 1-page survey regarding various aspects associated with their experience prior to their use of medicinal marijuana—diagnosis, what prompted them to seek treatment, level of satisfaction with specific stages in the process, total length of time the process took, and patient’s level of pain. Results reveal numerous patient diagnoses for which medical marijuana is being prescribed; the top 4 most common are intractable skeletal spasticity, chronic and severe pain, multiple sclerosis, and inflammatory bowel disease. Next, results indicate a little over half of the patients were first prompted to seek alternative treatment from their physicians, while the remaining patients indicated that other sources such as written information along with friends, relatives, media, and the Internet persuaded them to seek treatment. These data indicate that a variety of sources play a role in prompting patients to seek alternative treatment and is a critical first step in this process. Additional results posit that once patients began the process of qualifying to receive medical marijuana as treatment, the process seemed more positive even though it takes patients on average almost 6 months to obtain their first treatment after they started the process. Finally, results indicate that patients are reporting a moderately high level of pain prior to treatment. Implication of these results highlights several important elements in the patients’ initial steps toward seeking medical marijuana, along with the quality and quantity of the process patients must engage in prior to

  6. Microbial processes in banded iron formation deposition

    DEFF Research Database (Denmark)

    Posth, Nicole; Konhauser, Kurt; Kappler, Andreas

    2013-01-01

    , remains unresolved. Evidence of an anoxic Earth with only localized oxic areas until the Great Oxidation Event ca 2·45 to 2·32 Ga makes the investigation of O2-independent mechanisms for banded iron formation deposition relevant. Recent studies have explored the long-standing proposition that Archean......Banded iron formations have been studied for decades, particularly regarding their potential as archives of the Precambrian environment. In spite of this effort, the mechanism of their deposition and, specifically, the role that microbes played in the precipitation of banded iron formation minerals...... banded iron formations may have been formed, and diagenetically modified, by anaerobic microbial metabolisms. These efforts encompass a wide array of approaches including isotope, ecophysiological and phylogeny studies, molecular and mineral marker analysis, and sedimentological reconstructions. Herein...

  7. Understanding the biological underpinnings of ecohydrological processes

    Science.gov (United States)

    Huxman, T. E.; Scott, R. L.; Barron-Gafford, G. A.; Hamerlynck, E. P.; Jenerette, D.; Tissue, D. T.; Breshears, D. D.; Saleska, S. R.

    2012-12-01

    Climate change presents a challenge for predicting ecosystem response, as multiple factors drive both the physical and life processes happening on the land surface and their interactions result in a complex, evolving coupled system. For example, changes in surface temperature and precipitation influence near-surface hydrology through impacts on system energy balance, affecting a range of physical processes. These changes in the salient features of the environment affect biological processes and elicit responses along the hierarchy of life (biochemistry to community composition). Many of these structural or process changes can alter patterns of soil water-use and influence land surface characteristics that affect local climate. Of the many features that affect our ability to predict the future dynamics of ecosystems, it is this hierarchical response of life that creates substantial complexity. Advances in the ability to predict or understand aspects of demography help describe thresholds in coupled ecohydrological system. Disentangling the physical and biological features that underlie land surface dynamics following disturbance are allowing a better understanding of the partitioning of water in the time-course of recovery. Better predicting the timing of phenology and key seasonal events allow for a more accurate description of the full functional response of the land surface to climate. In addition, explicitly considering the hierarchical structural features of life are helping to describe complex time-dependent behavior in ecosystems. However, despite this progress, we have yet to build an ability to fully account for the generalization of the main features of living systems into models that can describe ecohydrological processes, especially acclimation, assembly and adaptation. This is unfortunate, given that many key ecosystem services are functions of these coupled co-evolutionary processes. To date, both the lack of controlled measurements and experimentation

  8. A Dual Process Approach to Understand Tourists’ Destination Choice Processes

    DEFF Research Database (Denmark)

    Kock, Florian; Josiassen, Alexander; Assaf, Albert

    2017-01-01

    Most studies that investigate tourists' choices of destinations apply the concept of mental destination representations, also referred to as destination image. The present study investigates tourists’ destination choice processes by conceptualizing how different components of destination image...... are mentally processed in tourists' minds. Specifically, the seminal dual processing approach is applied to the destination image literature. By doing this, we argue that some components of mental destination representations are processed systematically while others serve as inputs for heuristics...... that individuals apply to inform their decision making. Understanding how individuals make use of their mental destination representations and how they color their decision-making is essential in order to better explain tourist behavior....

  9. Understanding the Entrepreneurial Process: a Dynamic Approach

    Directory of Open Access Journals (Sweden)

    Vânia Maria Jorge Nassif

    2010-04-01

    Full Text Available There is considerable predominance in the adoption of perspectives based on characteristics in research into entrepreneurship. However, most studies describe the entrepreneur from a static or snapshot approach; very few adopt a dynamic perspective. The aim of this study is to contribute to the enhancement of knowledge concerning entrepreneurial process dynamics through an understanding of the values, characteristics and actions of the entrepreneur over time. By focusing on personal attributes, we have developed a framework that shows the importance of affective and cognitive aspects of entrepreneurs and the way that they evolve during the development of their business.

  10. Understanding Combustion Processes Through Microgravity Research

    Science.gov (United States)

    Ronney, Paul D.

    1998-01-01

    A review of research on the effects of gravity on combustion processes is presented, with an emphasis on a discussion of the ways in which reduced-gravity experiments and modeling has led to new understanding. Comparison of time scales shows that the removal of buoyancy-induced convection leads to manifestations of other transport mechanisms, notably radiative heat transfer and diffusional processes such as Lewis number effects. Examples from premixed-gas combustion, non-premixed gas-jet flames, droplet combustion, flame spread over solid and liquid fuels, and other fields are presented. Promising directions for new research are outlined, the most important of which is suggested to be radiative reabsorption effects in weakly burning flames.

  11. Micromorphology of modern tills in southwestern Spitsbergen – insights into depositional and post-depositional processes

    Directory of Open Access Journals (Sweden)

    Skolasińska Katarzyna

    2016-12-01

    Full Text Available Textural properties and microstructures are commonly used properties in the analysis of Pleistocene and older glacial deposits. However, contemporary glacial deposits are seldom studied, particularly in the context of post-depositional changes. This paper presents the results of a micromorphological study of recently deposited tills in the marginal zones of Hansbreen and Torellbreen, glaciers in southwestern Spitsbergen. The main objectives of this study were to compare modern tills deposited in subglacial and supraglacial conditions, as well as tills that were freshly released from ice with those laid down several decades ago. The investigated tills are primarily composed of large clasts of metamorphic rocks and represent coarse-grained, matrix-supported diamictons. The tills reveal several characteristic features for ductile (e.g. turbate structures and brittle (e.g. lineations, microshears deformations, which have been considered to be indicative of subglacial conditions. In supraglacial tills, the same structures are common as in the subglacial deposits, which points to the preservation of the primary features, though the sediment was transferred up to the glacier surface due to basal ice layer deformation and redeposited as slumps, or to formation of similar structures due to short-distance sediment re-deposition by mass flows. This study revealed that it might not be possible to distinguish subglacial and supraglacial tills on the basis of micromorphology if the latter are derived from a subglacial position. The only noted difference was the presence of iron oxide cementation zones and carbonate dissolution features in supraglacial tills. These features were found in tills that were deposited at least a few years ago and are interpreted to be induced by early post-depositional processes involving porewater/sediment interactions.

  12. Use of process indices for simplification of the description of vapor deposition systems

    International Nuclear Information System (INIS)

    Kajikawa, Yuya; Noda, Suguru; Komiyama, Hiroshi

    2004-01-01

    Vapor deposition is a complex process, including gas-phase, surface, and solid-phase phenomena. Because of the complexity of chemical and physical processes occurring in vapor deposition processes, it is difficult to form a comprehensive, fundamental understanding of vapor deposition and to control such systems for obtaining desirable structures and performance. To overcome this difficulty, we present a method for simplifying the complex description of such systems. One simplification method is to separate complex systems into multiple elements, and determine which of these are important elements. We call this method abridgement. The abridgement method retains only the dominant processes in a description of the system, and discards the others. Abridgement can be achieved by using process indices to evaluate the relative importance of the elementary processes. We describe the formulation and use of these process indices through examples of the growth of continuous films, initial deposition processes, and the formation of the preferred orientation of polycrystalline films. In this paper, we propose a method for representing complex vapor deposition processes as a set of simpler processes

  13. Biochemical processes of oligotrophic peat deposits of Vasyugan Mire

    Science.gov (United States)

    Inisheva, L. I.; Sergeeva, M. A.

    2009-04-01

    The problem of peat and mire ecosystems functioning and their rational use is the main problem of biosphere study. This problem also refers to forecasting of biosphere changes results which are global and anthropogenic. According to many scientists' research the portion of mires in earth carbon balance is about 15% of world's stock. The aim of this study is to investigate biochemical processes in oligotrophic deposits in North-eastern part of Vasyugan Mire. The investigations were made on the territory of scientific-research ground (56˚ 03´ and 56˚ 57´ NL, 82˚ 22´ and 82˚ 42´ EL). It is situated between two rivers Bakchar and Iksa (in outskirts of the village Polynyanka, Bakchar region, Tomsk oblast). Evolution of investigated mire massif began with the domination of eutrophic phytocenosis - Filicinae, then sedge. Later transfer into oligotrophic phase was accompanied by formation of meter high-moor peat deposit. The age of three-meter peat deposit reaches four thousand years. Biochemical processes of carbon cycle cover the whole peat deposit, but the process activity and its direction in different layers are defined by genesis and duration of peat formation. So, the number of cellulose-fermenting aerobes in researched peat deposits ranges from 16.8 to 75.5 million CFU/g, and anaerobic bacteria from 9.6 to 48.6 million CFU/g. The high number of aerobes is characteristic for high water levels, organizing by raised bog peats. Their number decreases along the profile in 1.7 - 2 times. The number of microflora in peat deposit is defined by the position in the landscape profile (different geneses), by the depth, by hydrothermic conditions of years and individual months. But microflora activity shows along all depth of peat deposit. We found the same in the process of studying of micromycete complex structure. There was revealed either active component micromycete complex - mycelium, or inert one - spores in a meter layer of peat deposit. If mushrooms

  14. Powder Flux Regulation in the Laser Material Deposition Process

    Science.gov (United States)

    Arrizubieta, Jon Iñaki; Wegener, Maximiliam; Arntz, Kristian; Lamikiz, Aitzol; Ruiz, Jose Exequiel

    In the present research work a powder flux regulation system has been designed, developed and validated with the aim of improving the Laser Material Deposition (LMD) process. In this process, the amount of deposited material per substrate surface unit area depends on the real feed rate of the nozzle. Therefore, a regulation system based on a solenoid valve has been installed at the nozzle entrance in order to control the powder flux. The powder flux control has been performed based on the machine real feed rate, which is compared with the programmed feed rate. An instantaneous velocity error is calculated and the powder flow is controlled as a function of this variation using Pulse Width Modulation (PWM) signals. Thereby, in zones where the Laser Material Deposition machine reduces the feed rate due to a trajectory change, powder accumulation can be avoided and the generated clads would present a homogeneous shape.

  15. A new thin film deposition process by cathodic plasma electrolysis

    International Nuclear Information System (INIS)

    Paulmier, T.; Kiriakos, E.; Bell, J.; Fredericks, P.

    2004-01-01

    Full text: A new technique, called atmospheric pressure plasma deposition (APPD), has been developed since a few years for the deposition of carbon and DLC, Titanium or Silicon films on metal and metal alloys substrates. A high voltage (2kV) is applied in a liquid electrolytic solution between an anode and a cathode, both electrodes being cylindrical: a glow discharge is then produced and confined at the vicinity of the cathode. The physic of the plasma in the electrolytic solution near the cathode is very different form the other techniques of plasma deposition since the pressure is here close to the atmospheric pressure. We describe here the different physico-chemical processes occurring during the process. In this cathodic process, the anodic area is significantly larger than the cathode area. In a first step, the electrolytic solution is heated by Joule effect induced by the high voltage between the electrodes. Due to the high current density, the vaporization of the solution occurs near the cathode: a large amount of bubbles are produced which are stabilized at the electrode by hydrodynamic and electromagnetic forces, forming a vapour sheath. The electric field and voltage drop are then concentrated in this gas envelope, inducing the ionization of the gas and the ignition of a glow discharge at the surface of the material. This plasma induces the formation of ionized and reactive species which diffuse and are accelerated toward the cathode. These excited species are the precursors for the formation of the deposition material. At the same time, the glow discharge interacts with the electrolyte solution inducing also ionization, convection and polymerization processes in the liquid: the solution is therefore a second source of the deposition material. A wide range of films have been deposited with a thickness up to 10 micrometers. These films have been analyzed by SEM and Raman spectroscopy. The electrolytic solution has been characterized by GC-MS and the

  16. Application of laser assisted cold spraying process for metal deposition

    CSIR Research Space (South Africa)

    Tlotleng, Monnamme

    2014-02-01

    Full Text Available Laser assisted cold spraying (LACS) process is a hybrid technique that uses laser and cold spray to deposit solid powders on metal substrates. For bonding to occur, the particle velocities must be supersonic which are achieved by entraining...

  17. Processes of preparation, deposition and analysis of thermionic emissive substances

    International Nuclear Information System (INIS)

    Romao, B.M. Verdelli; Muraro Junior, A.; Tessaroto, L.A.B.; Takahashi, J.

    1992-09-01

    This paper shows the results of the optimization of the process of preparation and deposition of thermionic emissive substances that are used in the oxide-cathodes which are utilized in the gun of the IEAv linear electron accelerator. (author). 5 refs., 5 figs

  18. Effects of acid deposition on microbial processes in natural waters

    International Nuclear Information System (INIS)

    Gilmour, C.C.

    1992-01-01

    Biogeochemical processes mediated by microorganisms are not adversely affected by the acidification of natural waters to the same extent as are the life cycles of higher organisms. Basic processes, e.g., primary production and organic matter decomposition, are not slowed in moderately acidified systems and do not generally decline above a pH of 5. More specifically, the individual components of the carbon, nitrogen, and sulfur cycles are, with few exceptions, also acid resistant. The influence of acid deposition on microbial processes is more often stimulation of nitrogen and sulfur cycling, often leading to alkalinity production, which mitigates the effect of strong acid deposition. Bacterial sulfate reduction and denitrification in sediments are two of the major processes that can be stimulated by sulfate and nitrate deposition, respectively, and result in ANC (acid-neutralizing capacity) generation. One of the negative effects of acid deposition is increased mobilization and bioaccumulation of some metals. Bacteria appear to play an important role, especially in mercury cycling, with acidification leading to increased bacterial methylation of mercury and subsequent bioaccumulation in higher organisms

  19. Hydraulic experimental investigation on spatial distribution and formation process of tsunami deposit on a slope

    Science.gov (United States)

    Harada, K.; Takahashi, T.; Yamamoto, A.; Sakuraba, M.; Nojima, K.

    2017-12-01

    An important aim of the study of tsunami deposits is to estimate the characteristics of past tsunamis from the tsunami deposits found locally. Based on the tsunami characteristics estimated from tsunami deposit, it is possible to examine tsunami risk assessment in coastal areas. It is considered that tsunami deposits are formed based on the dynamic correlation between tsunami's hydraulic values, sediment particle size, topography, etc. However, it is currently not enough to evaluate the characteristics of tsunamis from tsunami deposits. This is considered to be one of the reasons that the understanding of the formation process of tsunami deposits is not sufficiently understood. In this study, we analyze the measurement results of hydraulic experiment (Yamamoto et al., 2016) and focus on the formation process and distribution of tsunami deposits. Hydraulic experiment was conducted with two-dimensional water channel with a slope. Tsunami was inputted as a bore wave flow. The moving floor section was installed as a seabed slope connecting to shoreline and grain size distribution was set some cases. The water level was measured using ultrasonic displacement gauges, and the flow velocity was measured using propeller current meters and an electromagnetic current meter. The water level and flow velocity was measured at some points. The distribution of tsunami deposit was measured from shoreline to run-up limit on the slope. Yamamoto et al. (2016) reported the measurement results on the distribution of tsunami deposit with wave height and sand grain size. Therefore, in this study, hydraulic analysis of tsunami sediment formation process was examined based on the measurement data. Time series fluctuation of hydraulic parameters such as Froude number, Shields number, Rouse number etc. was calculated to understand on the formation process of tsunami deposit. In the front part of the tsunami, the flow velocity take strong flow from shoreline to around the middle of slope. From

  20. Process and machinery description of equipment for deposition of canisters in medium-long deposition holes

    International Nuclear Information System (INIS)

    Kalbantner, P.

    2001-08-01

    In this report twelve methods are presented to deposit a canister with spent nuclear fuel in a horizontal hole, several canisters per hole (MLH). These methods are part of the KBS-3 system. They have been developed successively, after an analysis of weak points and strong points in previously described methods. In conformance with the guidelines for Project JADE, a choices of system has been considered during the development work. This is whether canister and bentonite buffer should be deposited 'in parts', i.e. at different occasions, but shortly after each other or 'in a package', i.e. together in a single package. The other choice in the guidelines for the JADE project, whether the canister should be placed in a radiation shield or not during transport in the secondary tunnels, was not relevant to MLR. The basic technical problem is depositing heavy objects, the canister and the buffer components, in an horizontal hole which is approximately 200 m deep. Two methods for depositing of the bentonite barrier and the canisters in separate processes have been studied. For depositing of the bentonite barrier and the canister 'in a package', four alternative techniques have been studied: a metallic sleeve around the package, a loading scoop that is rotated, a fork carriage and rails. The repeated transports in a hole, a consequence of depositing several canisters in the same hole, could lead to the rock being crushed. The mutual impact of machines, load and rock wall has therefore been particularly considered. In several methods, the use of a gangway has been proposed (steel plates or layer of ice). A failure mode and effect analysis has been performed for one of the twelve methods. When comparing with a method to deposit one canister per hole using the same technique, the need for equipment and resources is far larger for this MLH method if incidents should occur during depositing. The development work reported here has not yet yielded a definitive method for placing

  1. Understanding flexible and distributed software development processes

    OpenAIRE

    Agerfalk, Par J.; Fitzgerald, Brian

    2006-01-01

    peer-reviewed The minitrack on Flexible and Distributed Software Development Processes addresses two important and partially intertwined current themes in software development: process flexibility and globally distributed software development

  2. Understanding the Learning Process in SMEs

    Science.gov (United States)

    Carr, James; Gannon-Leary, Pat

    2007-01-01

    A major obstacle to the diffusion of management development learning technologies from Higher Education Institutions to Small and Medium-sized Enterprises (SMEs) is a lack of understanding about how SME learners learn. This article examines the nature of learning in SMEs and considers the incidence of informal support for informal learning.…

  3. Understanding power plant investment decision processes

    NARCIS (Netherlands)

    Groot, J.; Richstein, J.C.; De Vries, L.J.

    2013-01-01

    In order to understand how companies make investment decisions under conditions of deep uncertainty, we interviewed a number of actors in the Dutch electricity sector. Most of the economic literature that is devoted to this question is prescriptive in nature, describing rational methods to the

  4. Advances in the electro-spark deposition coating process

    International Nuclear Information System (INIS)

    Johnson, R.N.; Sheldon, G.L.

    1986-04-01

    Electro-spark deposition (ESD) is a pulsed-arc micro-welding process using short-duration, high-current electrical pulses to deposit an electrode material on a metallic substrate. It is one of the few methods available by which a fused, metallurgically bonded coating can be applied with such a low total heat input that the bulk substrate material remains at or near ambient temperatures. The short duration of the electrical pulse allows an extremely rapid solidification of the deposited material and results in an exceptionally fine-grained, homogenous coating that approaches (and with some materials, actually is) an amorphous structure. This structure is believed to contribute to the good tribological and corrosion performance observed for hardsurfacing materials used in the demanding environments of high temperatures, liquid metals, and neutron irradiation. A brief historical review of the process is provided, followed by descriptions of the present state-of-the-art and of the performance and applications of electro-spark deposition coatings in liquid-metal-cooled nuclear reactors

  5. Sedimentological characteristics and depositional processes of sediment gravity flows in rift basins: The Palaeogene Dongying and Shahejie formations, Bohai Bay Basin, China

    Science.gov (United States)

    Liu, Lei; Chen, Hongde; Zhong, Yijiang; Wang, Jun; Xu, Changgui; Chen, Anqing; Du, Xiaofeng

    2017-10-01

    Sediment gravity flow deposits are common, particularly in sandy formations, but their origin has been a matter of debate and there is no consensus about the classification of such deposits. However, sediment gravity flow sandstones are economically important and have the potential to meet a growing demand in oil and gas exploration, so there is a drive to better understand them. This study focuses on sediment gravity flow deposits identified from well cores in Palaeogene deposits from the Liaodong Bay Depression in Bohai Bay Basin, China. We classify the sediment gravity flow deposits into eight lithofacies using lithological characteristics, grain size, and sedimentary structures, and interpret the associated depositional processes. Based on the scale, spatial distribution, and contact relationships of sediment gravity flow deposits, we defined six types of lithofacies associations (LAs) that reflect transformation processes and depositional morphology: LA1 (unconfined proximal breccia deposits), LA2 (confined channel deposits), LA3 (braided-channel lobe deposits), LA4 (unconfined lobe deposits), LA5 (distal sheet deposits), and LA6 (non-channelized sheet deposits). Finally, we established three depositional models that reflect the sedimentological characteristics and depositional processes of sediment gravity flow deposits: (1) slope-apron gravel-rich depositional model, which involves cohesive debris flows deposited as LA1 and dilute turbidity currents deposited as LA5; (2) non-channelized surge-like turbidity current depositional model, which mainly comprises sandy slumping, suspended load dominated turbidity currents, and dilute turbidity currents deposited as LA5 and LA6; and (3) channelized subaqueous-fan depositional model, which consists of non-cohesive bedload dominated turbidity currents, suspended load dominated turbidity currents, and dilute turbidity currents deposited as LA2-LA5, originating from sustained extrabasinal turbidity currents

  6. Thermodynamic analysis of processes proceeding on (111) faces of diamond during chemical vapour deposition

    International Nuclear Information System (INIS)

    Piekarczyk, W.; Prawer, S.

    1992-01-01

    Chemically vapour deposited diamond is commonly synthesized from activated hydrogen-rich, carbon/hydrogen gas mixtures under conditions which should, from a thermodynamic equilibrium point of view, favour the production of graphite. Much remains to be understood about why diamond, and not graphite, forms under these conditions. However, it is well known that the presence of atomic hydrogen, is crucial to the success of diamond deposition. As part of an attempt to better understand the deposition process, a thermodynamic analysis of the process was performed on diamond (111) faces in hydrogen rich environments. It is shown that the key role of atomic hydrogen is to inhibit the reconstruction of the (111) face to an sp 2 -bonded structure, which would provide a template for graphite, rather than diamond formation. The model correctly predicts experimentally determined trends in growth rate and diamond film quality as a function of methane concentration in the stating gas mixture. 17 refs., 4 figs

  7. Understanding Modeling Requirements of Unstructured Business Processes

    NARCIS (Netherlands)

    Allah Bukhsh, Zaharah; van Sinderen, Marten J.; Sikkel, Nicolaas; Quartel, Dick

    2017-01-01

    Management of structured business processes is of interest to both academia and industry, where academia focuses on the development of methods and techniques while industry focuses on the development of supporting tools. With the shift from routine to knowledge work, the relevance of management of

  8. Understanding the Sales Process by Selling

    Science.gov (United States)

    Bussière, Dave

    2017-01-01

    Experiential projects bring students closer to real-world situations. This is valuable in sales education because the complexities of the sales process are difficult to learn from a textbook. A student project was developed that involved the selling of advertising space in a one-time newspaper insert. The project included a substantial minimum…

  9. Obsolescence – understanding the underlying processes

    NARCIS (Netherlands)

    Thomsen, A.F.

    2017-01-01

    Obsolescence, defined as the process of declining performance of buildings, is a serious threat for the value, the usefulness and the life span of built properties. Thomsen and van der Flier (2011) developed a model in which obsolescence is categorised on the basis of two distinctions, i.e. between

  10. Understanding the Federal Proposal Review Process.

    Science.gov (United States)

    Cavin, Janis I.

    Information on the peer review process for the evaluation of federal grant proposals is presented to help college grants administrators and faculty develop good proposals. This guidebook provides an overview of the policies and conventions that govern the review and selection of proposals for funding, and details the review procedures of the…

  11. Understanding the process of fascial unwinding.

    Science.gov (United States)

    Minasny, Budiman

    2009-09-23

    Fascial or myofascial unwinding is a process in which a client undergoes a spontaneous reaction in response to the therapist's touch. It can be induced by using specific techniques that encourage a client's body to move into areas of ease. Unwinding is a popular technique in massage therapy, but its mechanism is not well understood. In the absence of a scientific explanation or hypothesis of the mechanism of action, it can be interpreted as "mystical." This paper proposes a model that builds on the neurobiologic, ideomotor action, and consciousness theories to explain the process and mechanism of fascial unwinding. HYPOTHETICAL MODEL: During fascial unwinding, the therapist stimulates mechanoreceptors in the fascia by applying gentle touch and stretching. Touch and stretching induce relaxation and activate the parasympathetic nervous system. They also activate the central nervous system, which is involved in the modulation of muscle tone as well as movement. As a result, the central nervous system is aroused and thereby responds by encouraging muscles to find an easier, or more relaxed, position and by introducing the ideomotor action. Although the ideomotor action is generated via normal voluntary motor control systems, it is altered and experienced as an involuntary response. Fascial unwinding occurs when a physically induced suggestion by a therapist prompts ideomotor action that the client experiences as involuntary. This action is guided by the central nervous system, which produces continuous action until a state of ease is reached. Consequently, fascial unwinding can be thought of as a neurobiologic process employing the self-regulation dynamic system theory.

  12. Solidification in direct metal deposition by LENS processing

    Science.gov (United States)

    Hofmeister, William; Griffith, Michelle

    2001-09-01

    Thermal imaging and metallographic analysis were used to study Laser Engineered Net Shaping (LENS™) processing of 316 stainless steel and H13 tool steel. The cooling rates at the solid-liquid interface were measured over a range of conduction conditions. The length scale of the molten zone controls cooling rates during solidification in direct metal deposition. In LENS processing, the molten zone ranges from 0.5 mm in length to 1.5 mm, resulting in cooling rates at the solid-liquid interface ranging from 200 6,000 Ks-1.

  13. Apparatus and process for deposition of hard carbon films

    Science.gov (United States)

    Nyaiesh, Ali R.; Garwin, Edward L.

    1989-01-03

    A process and an apparatus for depositing thin, amorphous carbon films having extreme hardness on a substrate is described. An enclosed chamber maintained at less than atmospheric pressure houses the substrate and plasma producing elements. A first electrode is comprised of a cavity enclosed within an RF coil which excites the plasma. A substrate located on a second electrode is excited by radio frequency power applied to the substrate. A magnetic field confines the plasma produced by the first electrode to the area away from the walls of the chamber and focuses the plasma onto the substrate thereby yielding film deposits having higher purity and having more rapid buildup than other methods of the prior art.

  14. PROCESS FOR THE RECOVERY AND PURIFICATION OF URANIUM DEPOSITS

    Science.gov (United States)

    Carter, J.M.; Kamen, M.D.

    1958-10-14

    A process is presented for recovering uranium values from UCl/sub 4/ deposits formed on calutrons. Such deposits are removed from the calutron parts by an aqueous wash solution which then contains the uranium values in addition to the following impurities: Ni, Cu, Fe, and Cr. This impurity bearing wash solution is treated with an oxidizing agent, and the oxidized solution is then treated with ammonia in order to precipitate the uranium as ammonium diuranate. The metal impurities of iron and chromium, which form insoluble hydroxides, are precipitated along with the uranium values. The precipitate is separated from the solution, dissolved in acid, and the solution again treated with ammonia and ammonium carbonate, which results in the precipitation of the metal impurities as hydroxides while the uranium values remain in solution.

  15. Effect of heat treatment on the characteristics of tool steel deposited by the directed energy deposition process

    Science.gov (United States)

    Park, Jun Seok; Lee, Min-Gyu; Cho, Yong-Jae; Sung, Ji Hyun; Jeong, Myeong-Sik; Lee, Sang-Kon; Choi, Yong-Jin; Kim, Da Hye

    2016-01-01

    The directed energy deposition process has been mainly applied to re-work and the restoration of damaged steel. Differences in material properties between the base and the newly deposited materials are unavoidable, which may affect the mechanical properties and durability of the part. We investigated the effect of heat treatment on the characteristics of tool steel deposited by the DED process. We prepared general tool steel materials of H13 and D2 that were deposited onto heat-treated substrates of H13 and D2, respectively, using a direct metal tooling process. The hardness and microstructure of the deposited steel before and after heat treatment were investigated. The hardness of the deposited H13 steel was higher than that of wrought H13 steel substrate, while that of the deposited D2 was lower than that of wrought D2. The evolution of the microstructures by deposition and heat treatment varied depending on the materials. In particular, the microstructure of the deposited D2 steel after heat treatment consisted of fine carbides in tempered martensite and it is expected that the deposited D2 steel will have isotropic properties and high hardness after heat treatment.

  16. Corrosion processes of physical vapor deposition-coated metallic implants.

    Science.gov (United States)

    Antunes, Renato Altobelli; de Oliveira, Mara Cristina Lopes

    2009-01-01

    Protecting metallic implants from the harsh environment of physiological fluids is essential to guaranteeing successful long-term use in a patient's body. Chemical degradation may lead to the failure of an implant device in two different ways. First, metal ions may cause inflammatory reactions in the tissues surrounding the implant and, in extreme cases, these reactions may inflict acute pain on the patient and lead to loosening of the device. Therefore, increasing wear strength is beneficial to the performance of the metallic implant. Second, localized corrosion processes contribute to the nucleation of fatigue cracks, and corrosion fatigue is the main reason for the mechanical failure of metallic implants. Common biomedical alloys such as stainless steel, cobalt-chrome alloys, and titanium alloys are prone to at least one of these problems. Vapor-deposited hard coatings act directly to improve corrosion, wear, and fatigue resistances of metallic materials. The effectiveness of the corrosion protection is strongly related to the structure of the physical vapor deposition layer. The aim of this paper is to present a comprehensive review of the correlation between the structure of physical vapor deposition layers and the corrosion properties of metallic implants.

  17. Ti film deposition process of a plasma focus: Study by an experimental design

    Directory of Open Access Journals (Sweden)

    M. J. Inestrosa-Izurieta

    2017-10-01

    Full Text Available The plasma generated by plasma focus (PF devices have substantially different physical characteristics from another plasma, energetic ions and electrons, compared with conventional plasma devices used for plasma nanofabrication, offering new and unique opportunities in the processing and synthesis of Nanomaterials. This article presents the use of a plasma focus of tens of joules, PF-50J, for the deposition of materials sprayed from the anode by the plasma dynamics in the axial direction. This work focuses on the determination of the most significant effects of the technological parameters of the system on the obtained depositions through the use of a statistical experimental design. The results allow us to give a qualitative understanding of the Ti film deposition process in our PF device depending on four different events provoked by the plasma dynamics: i an electric erosion of the outer material of the anode; ii substrate ablation generating an interlayer; iii electron beam deposition of material from the center of the anode; iv heat load provoking clustering or even melting of the deposition surface.

  18. UNDERSTANDING SEVERE WEATHER PROCESSES THROUGH SPATIOTEMPORAL RELATIONAL RANDOM FORESTS

    Data.gov (United States)

    National Aeronautics and Space Administration — UNDERSTANDING SEVERE WEATHER PROCESSES THROUGH SPATIOTEMPORAL RELATIONAL RANDOM FORESTS AMY MCGOVERN, TIMOTHY SUPINIE, DAVID JOHN GAGNE II, NATHANIEL TROUTMAN,...

  19. Smooth germanium nanowires prepared by a hydrothermal deposition process

    Energy Technology Data Exchange (ETDEWEB)

    Pei, L.Z., E-mail: lzpei1977@163.com [School of Materials Science and Engineering, Institute of Molecular Engineering and Applied Chemistry, Key Laboratory of Materials Science and Processing of Anhui Province, Anhui University of Technology, Ma' anshan, Anhui 243002 (China); Zhao, H.S. [School of Materials Science and Engineering, Institute of Molecular Engineering and Applied Chemistry, Key Laboratory of Materials Science and Processing of Anhui Province, Anhui University of Technology, Ma' anshan, Anhui 243002 (China); Tan, W. [Henkel Huawei Electronics Co. Ltd., Lian' yungang, Jiangsu 222006 (China); Yu, H.Y. [School of Materials Science and Engineering, Institute of Molecular Engineering and Applied Chemistry, Key Laboratory of Materials Science and Processing of Anhui Province, Anhui University of Technology, Ma' anshan, Anhui 243002 (China); Chen, Y.W. [Department of Materials Science, Fudan University, Shanghai 200433 (China); Fan, C.G. [School of Materials Science and Engineering, Institute of Molecular Engineering and Applied Chemistry, Key Laboratory of Materials Science and Processing of Anhui Province, Anhui University of Technology, Ma' anshan, Anhui 243002 (China); Zhang, Qian-Feng, E-mail: zhangqf@ahut.edu.cn [School of Materials Science and Engineering, Institute of Molecular Engineering and Applied Chemistry, Key Laboratory of Materials Science and Processing of Anhui Province, Anhui University of Technology, Ma' anshan, Anhui 243002 (China)

    2009-11-15

    Smooth germanium nanowires were prepared using Ge and GeO{sub 2} as the starting materials and Cu sheet as the substrate by a simple hydrothermal deposition process. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) characterizations show that the germanium nanowires are smooth and straight with uniform diameter of about 150 nm in average and tens of micrometers in length. X-ray diffraction (XRD) and Raman spectrum of the germanium nanowires display that the germanium nanowires are mainly composed of cubic diamond phase. PL spectrum shows a strong blue light emission at 441 nm. The growth mechanism is also discussed.

  20. Smooth germanium nanowires prepared by a hydrothermal deposition process

    International Nuclear Information System (INIS)

    Pei, L.Z.; Zhao, H.S.; Tan, W.; Yu, H.Y.; Chen, Y.W.; Fan, C.G.; Zhang, Qian-Feng

    2009-01-01

    Smooth germanium nanowires were prepared using Ge and GeO 2 as the starting materials and Cu sheet as the substrate by a simple hydrothermal deposition process. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) characterizations show that the germanium nanowires are smooth and straight with uniform diameter of about 150 nm in average and tens of micrometers in length. X-ray diffraction (XRD) and Raman spectrum of the germanium nanowires display that the germanium nanowires are mainly composed of cubic diamond phase. PL spectrum shows a strong blue light emission at 441 nm. The growth mechanism is also discussed.

  1. Volcanogenic Uranium Deposits: Geology, Geochemical Processes, and Criteria for Resource Assessment

    Science.gov (United States)

    Nash, J. Thomas

    2010-01-01

    Felsic volcanic rocks have long been considered a primary source of uranium for many kinds of uranium deposits, but volcanogenic uranium deposits themselves have generally not been important resources. Until the past few years, resource summaries for the United States or the world generally include volcanogenic in the broad category of 'other deposits' because they comprised less than 0.5 percent of past production or estimated resources. Exploration in the United States from the 1940s through 1982 discovered hundreds of prospects in volcanic rocks, of which fewer than 20 had some recorded production. Intensive exploration in the late 1970s found some large deposits, but low grades (less than about 0.10 percent U3O8) discouraged economic development. A few deposits in the world, drilled in the 1980s and 1990s, are now known to contain large resources (>20,000 tonnes U3O8). However, research on ore-forming processes and exploration for volcanogenic deposits has lagged behind other kinds of uranium deposits and has not utilized advances in understanding of geology, geochemistry, and paleohydrology of ore deposits in general and epithermal deposits in particular. This review outlines new ways to explore and assess for volcanogenic deposits, using new concepts of convection, fluid mixing, and high heat flow to mobilize uranium from volcanic source rocks and form deposits that are postulated to be large. Much can also be learned from studies of epithermal metal deposits, such as the important roles of extensional tectonics, bimodal volcanism, and fracture-flow systems related to resurgent calderas. Regional resource assessment is helped by genetic concepts, but hampered by limited information on frontier areas and undiscovered districts. Diagnostic data used to define ore deposit genesis, such as stable isotopic data, are rarely available for frontier areas. A volcanic environment classification, with three classes (proximal, distal, and pre-volcanic structures

  2. Research on Glass Frit Deposition Based on the Electrospray Process

    Directory of Open Access Journals (Sweden)

    Yifang Liu

    2016-04-01

    Full Text Available In this paper, the electrospray technology is used to easily deposit the glass frit into patterns at a micro-scale level. First, far-field electrospray process was carried out with a mixture of glass frit in the presence of ethanol. A uniform, smooth, and dense glass frit film was obtained, verifying that the electrospray technology was feasible. Then, the distance between the nozzle and the substrate was reduced to 2 mm to carry out near-field electrospray. The experimental process was improved by setting the range of the feed rate of the substrate to match both the concentration and the flow rate of the solution. Spray diameter could be less at the voltage of 2 kV, in which the glass frit film was expected to reach the minimum line width. A uniform glass frit film with a line width within the range of 400–500 μm was prepared when the speed of the substrate was 25 mm/s. It indicates that electrospray is an efficient technique for the patterned deposition of glass frit in wafer-level hermetic encapsulation.

  3. Effect of Linked Rules on Business Process Model Understanding

    DEFF Research Database (Denmark)

    Wang, Wei; Indulska, Marta; Sadiq, Shazia

    2017-01-01

    Business process models are widely used in organizations by information systems analysts to represent complex business requirements and by business users to understand business operations and constraints. This understanding is extracted from graphical process models as well as business rules. Prior...

  4. A machine learning approach to understand business processes

    NARCIS (Netherlands)

    Maruster, L.

    2003-01-01

    Business processes (industries, administration, hospitals, etc.) become nowadays more and more complex and it is difficult to have a complete understanding of them. The goal of the thesis is to show that machine learning techniques can be used successfully for understanding a process on the basis of

  5. 2D modeling of direct laser metal deposition process using a finite particle method

    Science.gov (United States)

    Anedaf, T.; Abbès, B.; Abbès, F.; Li, Y. M.

    2018-05-01

    Direct laser metal deposition is one of the material additive manufacturing processes used to produce complex metallic parts. A thorough understanding of the underlying physical phenomena is required to obtain a high-quality parts. In this work, a mathematical model is presented to simulate the coaxial laser direct deposition process tacking into account of mass addition, heat transfer, and fluid flow with free surface and melting. The fluid flow in the melt pool together with mass and energy balances are solved using the Computational Fluid Dynamics (CFD) software NOGRID-points, based on the meshless Finite Pointset Method (FPM). The basis of the computations is a point cloud, which represents the continuum fluid domain. Each finite point carries all fluid information (density, velocity, pressure and temperature). The dynamic shape of the molten zone is explicitly described by the point cloud. The proposed model is used to simulate a single layer cladding.

  6. Mining and processing of uranium deposits in Salamanca, Spain

    International Nuclear Information System (INIS)

    Gomez Jaen, J.P.; Otero, J.; Serrano, J.R.; Membrillera, J.R.; Josa, J.M.

    1977-01-01

    In July, 1974, Empresa Nacional del Uranio, S.A. (ENUSA), took the decision to mine uranium in the province of Salamanca, based on geological and processing studies carried out by the Junta de Energia Nuclear (JEN). The milling plant was designed by JEN and assembled by ENUSA, and operations were begun on 22 May, 1975. The orebody, FE-1, is composed of slate of Cambrain age and the fissures are filled by primary minerals. Secondary minerals are impregnated in the zone affected by the hydrostatic level. The orebody is of the stockwork type in which carbonaceous matter has acted as a reducing agent. The average grade of the ore is 0.09% U 3 O 8 at a cutoff grade of 0.02% U 3 O 8 : the deposit is therefore among the lowest-grade deposits that are currently mined. Annual production is 1 200 000 t of rock, of which 200 000 t is ore-bearing. The milling plant uses a static heap-leaching method, followed by solvent extraction (tertiary amines) and precipitation by ammonia. Joint studies by JEN and ENUSA have led to the introduction of modifications that have increased the production capacity from 75 to 112 t U 3 O 8 per annum with no significant alteration in the initial planned investment. The total recovery after processing is 75% of the U 3 O 8 contained in the ore. Approximately 100 people are employed in the overall operation. ENUSA has decided to expand operations in Salamanca with the construction of a new milling plant (technological aid by JEN), which will be capable of processing 825 000 t of ore per year, with an annual production of 500 t U 3 O 8 . The new plant is expected to begin operations in 1979. (author)

  7. Intelligent process control of fiber chemical vapor deposition

    Science.gov (United States)

    Jones, John Gregory

    Chemical Vapor Deposition (CVD) is a widely used process for the application of thin films. In this case, CVD is being used to apply a thin film interface coating to single crystal monofilament sapphire (Alsb2Osb3) fibers for use in Ceramic Matrix Composites (CMC's). The hot-wall reactor operates at near atmospheric pressure which is maintained using a venturi pump system. Inert gas seals obviate the need for a sealed system. A liquid precursor delivery system has been implemented to provide precise stoichiometry control. Neural networks have been implemented to create real-time process description models trained using data generated based on a Navier-Stokes finite difference model of the process. Automation of the process to include full computer control and data logging capability is also presented. In situ sensors including a quadrupole mass spectrometer, thermocouples, laser scanner, and Raman spectrometer have been implemented to determine the gas phase reactants and coating quality. A fuzzy logic controller has been developed to regulate either the gas phase or the in situ temperature of the reactor using oxygen flow rate as an actuator. Scanning electron microscope (SEM) images of various samples are shown. A hierarchical control structure upon which the control structure is based is also presented.

  8. Particle dry deposition to water surfaces: Processes and consequences

    DEFF Research Database (Denmark)

    Pryor, S.C.; Barthelmie, R.J.

    2000-01-01

    flux to coastal waters, atmosphere-surface exchange represents a significant component of the total flux and may be particularly critical during the summertime when both the riverine input and ambient nutrient concentrations are often at a minimum. In this chapter, we present an overview...... of the physical and chemical processes which dictate the quantity (and direction) of atmosphere-surface fluxes of trace chemicals to (and above) water surfaces with particular emphasis on the role of particles. Dry deposition (transfer to the surface in the absence of precipitation) of particles is determined...... efforts to simulate and measure fluxes close to the coastline. These arise in part from the complexity of atmospheric flow in this region where energy and chemical fluxes are highly inhomogeneous in space and time and thermally generated atmospheric circulations are commonplace. (C) 2000 Elsevier Science...

  9. Task-specific visual cues for improving process model understanding

    NARCIS (Netherlands)

    Petrusel, Razvan; Mendling, Jan; Reijers, Hajo A.

    2016-01-01

    Context Business process models support various stakeholders in managing business processes and designing process-aware information systems. In order to make effective use of these models, they have to be readily understandable. Objective Prior research has emphasized the potential of visual cues to

  10. Enhancement of surface integrity of titanium alloy with copper by means of laser metal deposition process

    CSIR Research Space (South Africa)

    Erinosho, MF

    2016-04-01

    Full Text Available The laser metal deposition process possesses the combination of metallic powder and laser beam respectively. However, these combinations create an adhesive bonding that permanently solidifies the laser-enhanced-deposited powders. Titanium alloys (Ti...

  11. Understanding the reaction kinetics to optimize graphene growth on Cu by chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Kraus, Juergen; Boebel, Lena; Zwaschka, Gregor; Guenther, Sebastian [Technische Universitaet Muenchen, Zentralinstitut fuer Katalyseforschung, Chemie Department, Physikalische Chemie mit Schwerpunkt Katalyse, Garching (Germany)

    2017-11-15

    Understanding and controlling the growth kinetics of graphene is a prerequisite to synthesize this highly wanted material by chemical vapor deposition on Cu, e.g. for the construction of ultra-stable electron transparent membranes. It is reviewed that Cu foils contain a considerable amount of carbon in the bulk which significantly exceeds the expected amount of thermally equilibrated dissolved carbon in Cu and that this carbon must be removed before any high quality graphene may be grown. Starting with such conditioned Cu foils, systematic studies of the graphene growth kinetics in a reactive CH{sub 4}/H{sub 2} atmosphere allow to extract the following meaningful data: prediction of the equilibrium constant of the graphene formation reaction within a precision of a factor of two, the confirmation that the graphene growth proceeds from a C(ad)-phase on Cu which is in thermal equilibrium with the reactive gas phase, its apparent activation barrier and finally the prediction of the achievable growth velocity of the growing graphene flakes during chemical vapor deposition. As a result of the performed study, growth parameters are identified for the synthesis of high quality monolayer graphene with single crystalline domains of 100-1000 μm in diameter within a reasonable growth time. (copyright 2017 by WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  12. Data on nearshore wave process and surficial beach deposits, central Tamil Nadu coast, India.

    Science.gov (United States)

    Joevivek, V; Chandrasekar, N

    2017-08-01

    The chronicles of nearshore morphology and surficial beach deposits provide valuable information about the nature of the beach condition and the depositional environment. It imparts an understanding about the spatial and temporal relationship of nearshore waves and its influence over the distribution of beach sediments. This article contains data about wave and sediment dynamics of the ten sandy beaches along the central Tamil Nadu coast, India. This present dataset comprises nearshore wave parameters, breaker wave type, beach morphodynamic state, grain size distribution and weight percentage of heavy and light mineral distribution. The dataset will figure out the beach morphology and hydrodynamic condition with respect to the different monsoonal season. This will act as a field reference to realize the coastal dynamics in an open sea condition. The nearshore entities were obtained from the intensive field survey between January 2011 and December 2011, while characteristics of beach sediments are examined by the chemical process in the laboratory environment.

  13. Ellipsometry study of process deposition of amorphous Indium Gallium Zinc Oxide sputtered thin films

    International Nuclear Information System (INIS)

    Talagrand, C.; Boddaert, X.; Selmeczi, D.G.; Defranoux, C.; Collot, P.

    2015-01-01

    This paper reports on an InGaZnO optical study by spectrometric ellipsometry. First of all, the fitting results of different models and different structures are analysed to choose the most appropriate model. The Tauc–Lorentz model is suitable for thickness measurements but a more complex model allows the refractive index and extinction coefficient to be extracted more accurately. Secondly, different InGaZnO process depositions are carried out in order to investigate stability, influence of deposition time and uniformity. Films present satisfactory optical stability over time. InGaZnO optical property evolution as a function of deposition time is related to an increase in temperature. To understand the behaviour of uniformity, mapping measurements are correlated to thin film resistivity. Results show that temperature and resputtering are the two phenomena that affect IGZO uniformity. - Highlights: • Model and structure are investigated to fit IGZO ellipsometric angles. • Maximum refractive index rises with substrate temperature and thus deposition time. • Resputtering leads to inhomogeneity in IGZO electrical and optical properties

  14. Ellipsometry study of process deposition of amorphous Indium Gallium Zinc Oxide sputtered thin films

    Energy Technology Data Exchange (ETDEWEB)

    Talagrand, C., E-mail: talagrand@emse.fr [Ecole des Mines de Saint-Etienne CMP-GC, Dept PS2, Gardanne, 880 route de Mimet (France); Boddaert, X. [Ecole des Mines de Saint-Etienne CMP-GC, Dept PS2, Gardanne, 880 route de Mimet (France); Selmeczi, D.G.; Defranoux, C. [Semilab Semiconductor Physics Laboratory Co. Ltd., Budapest, 1117 (Hungary); Collot, P. [Ecole Nationale Supérieure d' Arts et Métiers ParisTech, Aix-en-Provence, 2 cours des Arts et Métiers (France)

    2015-09-01

    This paper reports on an InGaZnO optical study by spectrometric ellipsometry. First of all, the fitting results of different models and different structures are analysed to choose the most appropriate model. The Tauc–Lorentz model is suitable for thickness measurements but a more complex model allows the refractive index and extinction coefficient to be extracted more accurately. Secondly, different InGaZnO process depositions are carried out in order to investigate stability, influence of deposition time and uniformity. Films present satisfactory optical stability over time. InGaZnO optical property evolution as a function of deposition time is related to an increase in temperature. To understand the behaviour of uniformity, mapping measurements are correlated to thin film resistivity. Results show that temperature and resputtering are the two phenomena that affect IGZO uniformity. - Highlights: • Model and structure are investigated to fit IGZO ellipsometric angles. • Maximum refractive index rises with substrate temperature and thus deposition time. • Resputtering leads to inhomogeneity in IGZO electrical and optical properties.

  15. Understanding of amount and dynamics of radioactive cesium deposited on trees in Fukushima

    Energy Technology Data Exchange (ETDEWEB)

    Endo, Izuki; Ohte, Nobuhito; Iseda, Kohei; Tanoi, Keitaro; Hirose, Atsushi; Kobayashi, Natsuko I. [The University of Tokyo, 113-8657, 1-1-1 Yayoi Bunkyo-ku, Tokyo (Japan); Ishii, Nobuyoshi [National Institute of Radiological Sciences, 263-8555, 4-9-1 Anagawa, Inage-ku, Chiba-shi, Chiba (Japan); Ohashi, Mizue [University of Hyogo, 670-0092, 1-1-12 Shinzaike-Honcho, Himeji, Hyogo (Japan)

    2014-07-01

    The accident of Fukushima Daiichi nuclear power plant after the earthquake and Tsunami in March 11, 2011 caused large amount of radioactive cesium ({sup 134}Cs, {sup 137}Cs) deposition onto the forest in the surrounding areas. River water from the forest area is used for food production and also for drinking water in these regions. In order to predict how radioactive Cs diffuse and discharge from the forest catchments, it is important to understand the amount and dynamics of radioactive Cs deposited on the trees. In this report, we show our preliminary results of {sup 137}Cs deposition in forest. Study was conducted in the forest at the upstream of Kami-Oguni River catchment, northern part of Fukushima Prefecture. Three plots (2 deciduous stands and 1 Japanese cedar (Cryptomeria japonica) plantation) were set in the forest. Quercus serrata and C. japonica, a representative of deciduous and evergreen tree species in this region, were chosen from each plot. Sample trees were logged in October 2012. Stem samples were collected every 2 m from above the ground to tree top and separated into bark, sapwood and heartwood. Litter traps were set in each plot and collected every month. Leaf litter was classified among species. Also, soil samples were collected in the cylinder of 5 cm in diameter and maximum 30 cm in depth from the forest floor every month. {sup 137}Cs concentration of all samples were measured by germanium semiconductor detector or NaI(Tl) scintillation counter. Deposited {sup 137}Cs was attached strongly on the bark of Q. serrata at high concentration (9-18 kBq/kg) but there were no clear relationship with tree height. In C. japonica, {sup 137}Cs concentration was about half times lower than that of Q. serrata at 0-10 m part of the tree. {sup 137}Cs concentration in wood of C. japonica was higher than Q. serrata. {sup 137}Cs concentration of sapwood was as high as that of heartwood in C. japonica, but in Q. serrata, {sup 137}Cs concentration in sapwood was

  16. Increasing process understanding by analyzing complex interactions in experimental data

    DEFF Research Database (Denmark)

    Naelapaa, Kaisa; Allesø, Morten; Kristensen, Henning Gjelstrup

    2009-01-01

    understanding of a coating process. It was possible to model the response, that is, the amount of drug released, using both mentioned techniques. However, the ANOVAmodel was difficult to interpret as several interactions between process parameters existed. In contrast to ANOVA, GEMANOVA is especially suited...... for modeling complex interactions and making easily understandable models of these. GEMANOVA modeling allowed a simple visualization of the entire experimental space. Furthermore, information was obtained on how relative changes in the settings of process parameters influence the film quality and thereby drug......There is a recognized need for new approaches to understand unit operations with pharmaceutical relevance. A method for analyzing complex interactions in experimental data is introduced. Higher-order interactions do exist between process parameters, which complicate the interpretation...

  17. Understanding Quality in Process Modelling: Towards a Holistic Perspective

    Directory of Open Access Journals (Sweden)

    Jan Recker

    2007-09-01

    Full Text Available Quality is one of the main topics in current conceptual modelling research, as is the field of business process modelling. Yet, widely acknowledged academic contributions towards an understanding or measurement of business process model quality are limited at best. In this paper I argue that the development of methodical theories concerning the measurement or establishment of process model quality must be preceded by methodological elaborations on business process modelling. I further argue that existing epistemological foundations of process modelling are insufficient for describing all extrinsic and intrinsic traits of model quality. This in turn has led to a lack of holistic understanding of process modelling. Taking into account the inherent social and purpose-oriented character of process modelling in contemporary organizations I present a socio-pragmatic constructionist methodology of business process modelling and sketch out implications of this perspective towards an understanding of process model quality. I anticipate that, based on this research, theories can be developed that facilitate the evaluation of the ’goodness’ of a business process model.

  18. Energy-enhanced atomic layer deposition : offering more processing freedom

    NARCIS (Netherlands)

    Potts, S.E.; Kessels, W.M.M.

    2013-01-01

    Atomic layer deposition (ALD) is a popular deposition technique comprising two or more sequential, self-limiting surface reactions, which make up an ALD cycle. Energy-enhanced ALD is an evolution of traditional thermal ALD methods, whereby energy is supplied to a gas in situ in order to convert a

  19. Understanding and Managing Process Interaction in IS Development Projects

    DEFF Research Database (Denmark)

    Bygstad, Bendik; Nielsen, Peter Axel

    2005-01-01

    Increasingly, information systems must be developed and implemented as a part of business change. This is a challenge for the IS project manager, since business change and information systems development usually are performed as separate processes. Thus, there is a need to understand and manage......-technical innovation in a situation where the organisational change process and the IS development process are parallel but incongruent. We also argue that iterative software engineering frameworks are well structured to support process interaction. Finally, we advocate that the IS project manager needs to manage...... the relationship between these two kinds of processes. To understand the interaction between information systems development and planned organisational change we introduce the concept of process interaction. We draw on a longitudinal case study of an IS development project that used an iterative and incremental...

  20. Improved Understanding of Implosion Symmetry through New Experimental Techniques Connecting Hohlraum Dynamics with Laser Beam Deposition

    Science.gov (United States)

    Ralph, Joseph; Salmonson, Jay; Dewald, Eduard; Bachmann, Benjamin; Edwards, John; Graziani, Frank; Hurricane, Omar; Landen, Otto; Ma, Tammy; Masse, Laurent; MacLaren, Stephen; Meezan, Nathan; Moody, John; Parrilla, Nicholas; Pino, Jesse; Sacks, Ryan; Tipton, Robert

    2017-10-01

    Understanding what affects implosion symmetry has been a challenge for scientists designing indirect drive inertial confinement fusion experiments on the National Ignition Facility (NIF). New experimental techniques and data analysis have been employed aimed at improving our understanding of the relationship between hohlraum dynamics and implosion symmetry. Thin wall imaging data allows for time-resolved imaging of 10 keV Au l-band x-rays providing for the first time on the NIF, a spatially resolved measurement of laser deposition with time. In the work described here, we combine measurements from the thin wall imaging with time resolved views of the interior of the hohlraum. The measurements presented are compared to hydrodynamic simulations as well as simplified physics models. The goal of this work is to form a physical picture that better explains the relationship of the hohlraum dynamics and capsule ablator on laser beam propagation and implosion symmetry. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344.

  1. Development of a new process for deposition of metallic vapours and ions

    International Nuclear Information System (INIS)

    Gabrielli, O. de.

    1989-01-01

    Surface treatment processes by deposition, enabling surface properties to be altered without altering the volume, are making rapid progress in industry. The description of these processes has led us to consider the role and the importance of methods using plasmas. The new plasma source we have developed is the subject of this experimental research: it is the basis of the deposition process (metallic ion and vapour deposition). The specifications and preliminary results enable us to compare this process with others in use. Fast deposition rates and excellent adhesion are the two main characteristics of this process [fr

  2. New understanding in genesis of uranium deposit Bashblak in tarim basin

    International Nuclear Information System (INIS)

    Qin Mingkuan; Zhao Ruiquan

    2000-01-01

    Using metallogenic theory of hydrogenic uranium deposit and theory of oil-gas reduction, the author makes a re-recognition of the metallogenic mechanism of the biggest uranium deposit in Tarim basin--uranium deposit Bashblak in order to give some reference guide in the prospecting for in-situ leachable sandstone-type uranium deposits in the biggest intra-continental basin in China--Tarim basin

  3. The importance of understanding during the teaching process

    Directory of Open Access Journals (Sweden)

    Dubljanin Saša

    2015-01-01

    Full Text Available Learning in the teaching process often goes on without proper understanding which is one of important problems that modern didactics tries to solve. In order to direct the totality of teaching towards understanding it is necessary to answer the question what understanding is, which is why we analysed different philosophical views on the concept of understanding and stressed their semblance to pedagogic explanations. Different kinds of understanding were analyzed as well as their role and contribution in different teaching situations, especially in the context of problem solving. As an alternative to the teaching based on accumulation of knowledge the characteristics and some principles of teaching focused on understanding are described, and the need for stimulating and developing understanding as an important goal of education. The results of our research unequivocally show that learning with understanding enables students to memorize the teaching material better, as well as to understand the whole teaching subject and efficiently apply the acquired knowledge out of school, and leads to more flexible behaviour and better coping in everyday life.

  4. 49 CFR 594.9 - Fee for reimbursement of bond processing costs and costs for processing offers of cash deposits...

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 7 2010-10-01 2010-10-01 false Fee for reimbursement of bond processing costs and costs for processing offers of cash deposits or obligations of the United States in lieu of sureties on... indirect costs the agency incurs for receipt, processing, handling, and disbursement of cash deposits or...

  5. The Mianhuakeng deposit no. 9 with -50 m to -150 m middle production prospecting practice some understanding

    International Nuclear Information System (INIS)

    Bi Yide; Tan Zhongyin; Kuang Zhengping; Hou Zhiyong; Qiu Huiyuan

    2014-01-01

    The production prospecting is an extension of prospecting, it can identify deposits occurrence conditions in the main deposits mined, geological factors, ore grade distribution characteristics of type and So on, it can provide a reliable geological data for the development plan of the section and the quasi - Design in order to reduce mining costs and improve economic benef. This article through to the Mianhuakeng Deposit No. 9 with -50 m to -150 m middle production prospecting practice some understanding, sum up the metallogenic conditions, ore controlling factors, ore characteristics, to realize the optimization of production prospecting, so as to lower the cost for the better prospecting effect. (authors)

  6. Directed Vapor Deposition: Low Vacuum Materials Processing Technology

    National Research Council Canada - National Science Library

    Groves, J. F; Mattausch, G; Morgner, H; Hass, D. D; Wadley, H. N

    2000-01-01

    Directed vapor deposition (DVD) is a recently developed electron beam-based evaporation technology designed to enhance the creation of high performance thick and thin film coatings on small area surfaces...

  7. Understanding the Process of Fibrosis in Duchenne Muscular Dystrophy

    Directory of Open Access Journals (Sweden)

    Yacine Kharraz

    2014-01-01

    Full Text Available Fibrosis is the aberrant deposition of extracellular matrix (ECM components during tissue healing leading to loss of its architecture and function. Fibrotic diseases are often associated with chronic pathologies and occur in a large variety of vital organs and tissues, including skeletal muscle. In human muscle, fibrosis is most readily associated with the severe muscle wasting disorder Duchenne muscular dystrophy (DMD, caused by loss of dystrophin gene function. In DMD, skeletal muscle degenerates and is infiltrated by inflammatory cells and the functions of the muscle stem cells (satellite cells become impeded and fibrogenic cells hyperproliferate and are overactivated, leading to the substitution of skeletal muscle with nonfunctional fibrotic tissue. Here, we review new developments in our understanding of the mechanisms leading to fibrosis in DMD and several recent advances towards reverting it, as potential treatments to attenuate disease progression.

  8. Building of nested components by a double-nozzle droplet deposition process

    Science.gov (United States)

    Li, SuLi; Wei, ZhengYing; Du, Jun; Zhao, Guangxi; Wang, Xin; Lu, BingHeng

    2016-07-01

    According to the nested components jointed with multiple parts,a double-nozzle droplet deposition process was put forward in this paper, and the experimental system was developed. Through the research on the properties of support materials and the process of double-nozzle droplet deposition, the linkage control of the metal droplet deposition and the support material extrusion was realized, and a nested component with complex construction was fabricated directly. Compared with the traditional forming processes, this double-nozzle deposition process has the advantages of short cycle, low cost and so on. It can provide an approach way to build the nested parts.

  9. Understanding r-process nucleosynthesis with dwarf galaxies

    Science.gov (United States)

    Ji, Alexander P.

    2018-06-01

    The Milky Way's faintest dwarf galaxy satellites each sample short, independent bursts of star formation from the first 1-2 Gyr of the universe. Their simple formation history makes them ideal systems to understand how rare events like neutron star mergers contribute to early enrichment of r-process elements. I will focus on the ultra-faint galaxy Reticulum II, which experienced a single prolific r-process event that left ~80% of its stars extremely enriched in r-process elements. I will present abundances of ~40 elements derived from the highest signal-to-noise high-resolution spectrum ever taken for an ultra-faint dwarf galaxy star. Precise measurements of elements from all three r-process peaks reaffirm the universal nature of the r-process abundance pattern from Ba to Ir. The first r-process peak is significantly lower than solar but matches other r-process enhanced stars. This constrains the neutron-richness of r-process ejecta in neutron star mergers. The radioactive element thorium is detected with a somewhat low abundance. Naive application of currently predicted initial production ratios could imply an age >20 Gyr, but more likely indicates that the initial production ratios require revision. The abundance of lighter elements up to Zn are consistent with extremely metal-poor Milky Way halo stars. These elements may eventually provide a way to test for other hypothesized r-process sites, but only after a more detailed understanding of the chemical evolution in this galaxy. Reticulum II provides a clean view of early r-process enrichment that can be used to understand the increasing number of r-process measurements in other dwarf galaxies.

  10. Understanding Cu release into environment from Kure massive sulfide ore deposits, Kastamonu, NW Turkey

    Science.gov (United States)

    Demirel, Cansu; Sonmez, Seref; Balci, Nurgul

    2014-05-01

    Covering a wide range on the earth's crust, oxidation of metal sulfide minerals have vital environmental impacts on the aquatic environment, causing one of the major environmental problems known as acid mine drainage (AMD). Located in the Kastamonu province of the Western Black Sea region, Kure district is one of the major copper mining sites in Turkey. Mining activities in the area heads back to ancient times, such that operation is thought to be started with the Roman Empire. Currently, only the underground mining tunnels of Bakibaba and Asikoy are being operated. Thus, mining heaps and ores of those pyritic deposits have been exposed to the oxidative conditions for so long. As a result of weathering processes of past and recent heaps of the Kure volcanic massive sulfide deposits in addition to the main ore mineral (chalcopyrite), significant amount of metals, especially Cu, are being released into the environment creating undesirable environmental conditions. In order to elucidate Cu release mechanisms from Kure pyritic ore deposits and mining wastes, field and laboratory approaches were used. Surface water and sediment samples from the streams around the mining and waste sites were collected. Groundwater samples from the active underground mining site were also collected. Physical parameters (pH, Eh, T°C, and EC) of water samples were determined in situ and in the laboratory using probes (WTW pH 3110, WTW Multi 9310 and CRISON CM 35). Metal and ion concentrations of the water samples were analysed using ICP-MS and DR 2800 spectrophotometer, respectively. High Cu, Co, Zn and Fe concentrations were determined in the water samples with pH values ranging from 2.9- 4. Cu concentrions ranges from 345 ppm to 36 ppm in the water samples. Consistent with the water samples, high Cu, Fe, Zn and Co were also determined in the sediment samples. Laboratory chalcopyrite oxidation experiments under the conditions representing the field site were set up as biological and

  11. A Long-term Forest Fertilization Experiment to Understand Ecosystem Responses to Atmospheric Nitrogen Deposition

    Science.gov (United States)

    Baron, J.; Advani, S. M.; Allen, J.; Boot, C.; Denef, K.; Denning, S.; Hall, E.; Moore, J. C.; Reuth, H.; Ryan, M. G.; Shaw, E.

    2016-12-01

    Long-term field experiments can reveal changes in ecosystem processes that may not be evident in short-term studies. Short-term measurements or experiments may have narrower objectives or unrealistic treatments in order to see a change, whereas long-term studies can reveal complex interactions that take longer to manifest. We report results from a long-term experiment (1996 to present) in subalpine forests to simulate the consequences of sustained atmospheric nitrogen (N) deposition. Loch Vale watershed in Rocky Mountain National Park, the location of the experiment, has received an order of magnitude greater atmospheric N deposition than estimated background since mid-20th Century. Augmenting that, in 1996 we began adding 25 kg NH4NO3 ha-1 yr-1 to three 30m x 30m old-growth Engelmann spruce and subalpine fir plots. Treated stands were matched by nearby controls. N addition caused rapid leaching of nitrate and cations from soils, and increased N mineralization and nitrification rates. These observations in the fertilized plots have been sustained over time. Soluble aluminum concentrations do not differ significantly between fertilized and control plots, but treated soils are now markedly more acidic (pH of 4.7) than original soil and controls (pH of 5.1); further acidification might increase aluminum leaching. Effects on soil carbon were complex, mediated by reductions in total microbial biomass, decreases in arbuscular mychorrizal and saprotropic fungi, and increased potential rates of N enzyme degrading activities. Initial soil C:N of 24 was lower than similar soils in low N deposition stands (C:N of 36). The C:N declined to 22 with treatment. Fertilized plots lost 11% soil C, but the mechanism is unclear. We did not measure changes in C inputs from litter, microbial biomass, or plant uptake, but there was no change in summer CO2 flux, measured in 2003, 2004, and 2014. Leaching of DOC from fertilized plots was elevated throughout the experiment, providing one

  12. Understanding the Process by Which New Employees Enter Work Groups

    Science.gov (United States)

    Summers, Donald B.

    1977-01-01

    The Group Integration Process, described in this article, serves as a broad and guiding set of steps (invitation, induction, orientation, training, relationship, and integration) that helps the supervisor better understand what is to be done in managing a new employee's entrance into a work group. (TA)

  13. Understanding the Advising Learning Process Using Learning Taxonomies

    Science.gov (United States)

    Muehleck, Jeanette K.; Smith, Cathleen L.; Allen, Janine M.

    2014-01-01

    To better understand the learning that transpires in advising, we used Anderson et al.'s (2001) revision of Bloom's (1956) taxonomy and Krathwohl, Bloom, and Masia's (1964) affective taxonomy to analyze eight student-reported advising outcomes from Smith and Allen (2014). Using the cognitive processes and knowledge domains of Anderson et al.'s…

  14. Understanding the IT/business partnership - a business process perspective

    DEFF Research Database (Denmark)

    Siurdyban, Artur

    2014-01-01

    From a business process perspective, the business value of information technologies (IT) stems from how they improve or enable business processes. At the same time, in the field of strategic IT/business alignment, the locus of discussion has been how IT/business partnerships enhance the value of IT....... Despite this apparent relationship, the business process perspective has been absent from the IT/business alignment discussion. In this paper, we use the case of an industrial company to develop a model for understanding IT/business partnerships in business process terms. Based on our findings, we define...... these partnerships by allocating responsibilities between central IT and the local business during two stages of a process lifecycle: formation and standardization. The significance of the findings lies in how the model’s configuration leads to different types of IT units’ process centricity. This in turn affects...

  15. Process for the preparation of fiber-reinforced ceramic composites by chemical vapor deposition

    Science.gov (United States)

    Lackey, Jr., Walter J.; Caputo, Anthony J.

    1986-01-01

    A chemical vapor deposition (CVD) process for preparing fiber-reinforced ceramic composites. A specially designed apparatus provides a steep thermal gradient across the thickness of a fibrous preform. A flow of gaseous ceramic matrix material is directed into the fibrous preform at the cold surface. The deposition of the matrix occurs progressively from the hot surface of the fibrous preform toward the cold surface. Such deposition prevents the surface of the fibrous preform from becoming plugged. As a result thereof, the flow of reactant matrix gases into the uninfiltrated (undeposited) portion of the fibrous preform occurs throughout the deposition process. The progressive and continuous deposition of ceramic matrix within the fibrous preform provides for a significant reduction in process time over known chemical vapor deposition processes.

  16. Nitrogen deposition to the United States: distribution, sources, and processes

    Directory of Open Access Journals (Sweden)

    L. Zhang

    2012-05-01

    Full Text Available We simulate nitrogen deposition over the US in 2006–2008 by using the GEOS-Chem global chemical transport model at 1/2°×2/3° horizontal resolution over North America and adjacent oceans. US emissions of NOx and NH3 in the model are 6.7 and 2.9 Tg N a−1 respectively, including a 20% natural contribution for each. Ammonia emissions are a factor of 3 lower in winter than summer, providing a good match to US network observations of NHx (≡NH3 gas + ammonium aerosol and ammonium wet deposition fluxes. Model comparisons to observed deposition fluxes and surface air concentrations of oxidized nitrogen species (NOy show overall good agreement but excessive wintertime HNO3 production over the US Midwest and Northeast. This suggests a model overestimate N2O5 hydrolysis in aerosols, and a possible factor is inhibition by aerosol nitrate. Model results indicate a total nitrogen deposition flux of 6.5 Tg N a−1 over the contiguous US, including 4.2 as NOy and 2.3 as NHx. Domestic anthropogenic, foreign anthropogenic, and natural sources contribute respectively 78%, 6%, and 16% of total nitrogen deposition over the contiguous US in the model. The domestic anthropogenic contribution generally exceeds 70% in the east and in populated areas of the west, and is typically 50–70% in remote areas of the west. Total nitrogen deposition in the model exceeds 10 kg N ha−1 a−1 over 35% of the contiguous US.

  17. Electrochemically Deposited Nickel Membranes; Process-Microstructure-Property Relationships

    DEFF Research Database (Denmark)

    Jensen, Jens Dahl; Pantleon, Karen; Somers, Marcel A.J.

    2003-01-01

    This paper reports on the manufacturing, surface morphology, internal structure and mechanical properties of Ni-foils used as membranes in reference-microphones. Two types of foils, referred to as S-type and 0-type foils, were electrochemically deposited from a Watts-type electrolyte, with (S...

  18. The fate of SOC during the processes of water erosion and subsequent deposition: a field study.

    Science.gov (United States)

    van Hemelryck, H.; Govers, G.; van Oost, K.; Merckx, R.

    2009-04-01

    Globally soils are the largest terrestrial pool of carbon (C). A relatively small increase or decrease in soil carbon content due to changes in land use or management practices could therefore result in a significant net exchange of C between the soil C reservoir and the atmosphere. As such, the geomorphic processes of water and tillage erosion have been identified to significantly impact on this large pool of soil organic carbon (SOC). Soil erosion, transport and deposition not only result in redistribution of sediments and associated carbon within a landscape, but also affect the exchange of C between the pedosphere and the atmosphere. The direction and magnitude of an erosion-induced change in the global C balance is however a topic of much debate as opposing processes interact: i) At eroding sites a net uptake of C could be the result of reduced respiration rates and continued inputs of newly produced carbon. ii) Colluvial deposition of eroded sediment and SOC leads to the burial of the original topsoil and this may constrain the decomposition of its containing SOC. iii) Eroded sediment could be transported to distal depositional environments or fluvial systems where it will either be conserved or become rapidly mineralized. iv) Increased emission of CO2 due to erosion may result from the disruptive energy of erosive forces causing the breakdown of aggregates and exposing previously protected SOC to microbial decomposition. The above-mentioned processes show a large spatial and temporal variability and assessing their impact requires an integrated modeling approach. However uncertainties about the basic processes that accompany SOC displacement are still large. This study focuses on one of these large information gaps: the fate of eroded and subsequently deposited SOC. A preceding experimental study (Van Hemelryck et al., 2008) was used to identify controlling factors (erosional intensity, changes in soil structure,…). However this experimental research

  19. Understanding deposition rate loss in high power impulse magnetron sputtering: I. Ionization-driven electric fields

    International Nuclear Information System (INIS)

    Brenning, N; Huo, C; Raadu, M A; Lundin, D; Helmersson, U; Vitelaru, C; Stancu, G D; Minea, T

    2012-01-01

    The lower deposition rate for high power impulse magnetron sputtering (HiPIMS) compared with direct current magnetron sputtering for the same average power is often reported as a drawback. The often invoked reason is back-attraction of ionized sputtered material to the target due to a substantial negative potential profile, sometimes called an extended presheath, from the location of ionization toward the cathode. Recent studies in HiPIMS devices, using floating-emitting and swept-Langmuir probes, show that such extended potential profiles do exist, and that the electric fields E z directed toward the target can be strong enough to seriously reduce ion transport to the substrate. However, they also show that the potential drops involved can vary by up to an order of magnitude from case to case. There is a clear need to understand the underlying mechanisms and identify the key discharge variables that can be used for minimizing the back-attraction. We here present a combined theoretical and experimental analysis of the problem of electric fields E z in the ionization region part of HiPIMS discharges, and their effect on the transport of ionized sputtered material. In particular, we have investigated the possibility of a ‘sweet spot’ in parameter space in which the back-attraction of ionized sputtered material is low. It is concluded that a sweet spot might possibly exist for some carefully optimized discharges, but probably in a rather narrow window of parameters. As a measure of how far a discharge is from such a window, a Townsend product Π Townsend is proposed. A parametric analysis of Π Townsend shows that the search for a sweet spot is complicated by the fact that contradictory demands appear for several of the externally controllable parameters such as high/low working gas pressure, short/long pulse length, high/low pulse power and high/low magnetic field strength. (paper)

  20. Understanding and Managing Process Interaction in IS Development Projects

    DEFF Research Database (Denmark)

    Bygstad, Bendik; Nielsen, Peter Axel

    2012-01-01

    Software-based information systems must be developed and implemented as a part of business change. This is a major challenge, since business change and the development of software-based information systems usually are performed in separate processes. Thus, there is a need to understand and manage...... critical events in the case, what led to the events, and what the consequences are. We discuss the implications for information systems research and in particular we discuss the contribution to project management of iterative and incremental software development.......Software-based information systems must be developed and implemented as a part of business change. This is a major challenge, since business change and the development of software-based information systems usually are performed in separate processes. Thus, there is a need to understand and manage...

  1. Evaluating nurse understanding and participation in the informed consent process.

    Science.gov (United States)

    Axson, Sydney A; Giordano, Nicholas A; Hermann, Robin M; Ulrich, Connie M

    2017-01-01

    Informed consent is fundamental to the autonomous decision-making of patients, yet much is still unknown about the process in the clinical setting. In an evolving healthcare landscape, nurses must be prepared to address patient understanding and participate in the informed consent process to better fulfill their well-established role as patient advocates. This study examines hospital-based nurses' experiences and understandings of the informed consent process. This qualitative descriptive study utilized a semi-structured interview approach identifying thematic concerns, experiences, and knowledge of informed consent across a selected population of clinically practicing nurses. Participants and research context: In all, 20 baccalaureate prepared registered nurses practicing in various clinical settings (i.e. critical care, oncology, medical/surgical) at a large northeastern academic medical center in the United States completed semi-structured interviews and a demographic survey. The mean age of participants was 36.6 years old, with a mean of 12.2 years of clinical experience. Ethical considerations: Participation in this study involved minimal risk and no invasive measures. This study received Institutional Review Board approval from the University of Pennsylvania. All participants voluntarily consented. The majority of participants (N = 19) believe patient safety is directly linked to patient comprehension of the informed consent process. However, when asked if nurses have a defined role in the informed consent process, nearly half did not agree (N = 9). Through this qualitative approach, three major nursing roles emerged: the nurse as a communicator, the nurse as an advocate, and the clerical role of the nurse. This investigation contributes to the foundation of ethical research that will better prepare nurses for patient engagement, advance current understanding of informed consent, and allow for future development of solutions. Nurses are at the forefront of

  2. Toward understanding dynamic annealing processes in irradiated ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Myers, Michael Thomas [Texas A & M Univ., College Station, TX (United States)

    2013-05-01

    High energy particle irradiation inevitably generates defects in solids. The ballistic formation and thermalization of the defect creation process occur rapidly, and are believed to be reasonably well understood. However, knowledge of the evolution of defects after damage cascade thermalization, referred to as dynamic annealing, is quite limited. Unraveling the mechanisms associated with dynamic annealing is crucial since such processes play an important role in the formation of stable postirradiation disorder in ion-beam-processing of semiconductors, and determines the “radiation tolerance” of many nuclear materials. The purpose of this dissertation is to further our understanding of the processes involved in dynamic annealing. In order to achieve this, two main tasks are undertaken.

  3. Research on chemical vapor deposition processes for advanced ceramic coatings

    Science.gov (United States)

    Rosner, Daniel E.

    1993-01-01

    Our interdisciplinary background and fundamentally-oriented studies of the laws governing multi-component chemical vapor deposition (VD), particle deposition (PD), and their interactions, put the Yale University HTCRE Laboratory in a unique position to significantly advance the 'state-of-the-art' of chemical vapor deposition (CVD) R&D. With NASA-Lewis RC financial support, we initiated a program in March of 1988 that has led to the advances described in this report (Section 2) in predicting chemical vapor transport in high temperature systems relevant to the fabrication of refractory ceramic coatings for turbine engine components. This Final Report covers our principal results and activities for the total NASA grant of $190,000. over the 4.67 year period: 1 March 1988-1 November 1992. Since our methods and the technical details are contained in the publications listed (9 Abstracts are given as Appendices) our emphasis here is on broad conclusions/implications and administrative data, including personnel, talks, interactions with industry, and some known applications of our work.

  4. Closed-Loop Process Control for Electron Beam Freeform Fabrication and Deposition Processes

    Science.gov (United States)

    Taminger, Karen M. (Inventor); Hafley, Robert A. (Inventor); Martin, Richard E. (Inventor); Hofmeister, William H. (Inventor)

    2013-01-01

    A closed-loop control method for an electron beam freeform fabrication (EBF(sup 3)) process includes detecting a feature of interest during the process using a sensor(s), continuously evaluating the feature of interest to determine, in real time, a change occurring therein, and automatically modifying control parameters to control the EBF(sup 3) process. An apparatus provides closed-loop control method of the process, and includes an electron gun for generating an electron beam, a wire feeder for feeding a wire toward a substrate, wherein the wire is melted and progressively deposited in layers onto the substrate, a sensor(s), and a host machine. The sensor(s) measure the feature of interest during the process, and the host machine continuously evaluates the feature of interest to determine, in real time, a change occurring therein. The host machine automatically modifies control parameters to the EBF(sup 3) apparatus to control the EBF(sup 3) process in a closed-loop manner.

  5. Developing improved MD codes for understanding processive cellulases

    International Nuclear Information System (INIS)

    Crowley, M F; Nimlos, M R; Himmel, M E; Uberbacher, E C; Iii, C L Brooks; Walker, R C

    2008-01-01

    The mechanism of action of cellulose-degrading enzymes is illuminated through a multidisciplinary collaboration that uses molecular dynamics (MD) simulations and expands the capabilities of MD codes to allow simulations of enzymes and substrates on petascale computational facilities. There is a class of glycoside hydrolase enzymes called cellulases that are thought to decrystallize and processively depolymerize cellulose using biochemical processes that are largely not understood. Understanding the mechanisms involved and improving the efficiency of this hydrolysis process through computational models and protein engineering presents a compelling grand challenge. A detailed understanding of cellulose structure, dynamics and enzyme function at the molecular level is required to direct protein engineers to the right modifications or to understand if natural thermodynamic or kinetic limits are in play. Much can be learned about processivity by conducting carefully designed molecular dynamics (MD) simulations of the binding and catalytic domains of cellulases with various substrate configurations, solvation models and thermodynamic protocols. Most of these numerical experiments, however, will require significant modification of existing code and algorithms in order to efficiently use current (terascale) and future (petascale) hardware to the degree of parallelism necessary to simulate a system of the size proposed here. This work will develop MD codes that can efficiently use terascale and petascale systems, not just for simple classical MD simulations, but also for more advanced methods, including umbrella sampling with complex restraints and reaction coordinates, transition path sampling, steered molecular dynamics, and quantum mechanical/molecular mechanical simulations of systems the size of cellulose degrading enzymes acting on cellulose

  6. Towards the understanding of network information processing in biology

    Science.gov (United States)

    Singh, Vijay

    Living organisms perform incredibly well in detecting a signal present in the environment. This information processing is achieved near optimally and quite reliably, even though the sources of signals are highly variable and complex. The work in the last few decades has given us a fair understanding of how individual signal processing units like neurons and cell receptors process signals, but the principles of collective information processing on biological networks are far from clear. Information processing in biological networks, like the brain, metabolic circuits, cellular-signaling circuits, etc., involves complex interactions among a large number of units (neurons, receptors). The combinatorially large number of states such a system can exist in makes it impossible to study these systems from the first principles, starting from the interactions between the basic units. The principles of collective information processing on such complex networks can be identified using coarse graining approaches. This could provide insights into the organization and function of complex biological networks. Here I study models of biological networks using continuum dynamics, renormalization, maximum likelihood estimation and information theory. Such coarse graining approaches identify features that are essential for certain processes performed by underlying biological networks. We find that long-range connections in the brain allow for global scale feature detection in a signal. These also suppress the noise and remove any gaps present in the signal. Hierarchical organization with long-range connections leads to large-scale connectivity at low synapse numbers. Time delays can be utilized to separate a mixture of signals with temporal scales. Our observations indicate that the rules in multivariate signal processing are quite different from traditional single unit signal processing.

  7. Improvement of a microwave ECR plasma source for the plasma immersion ion implantation and deposition process

    International Nuclear Information System (INIS)

    Wu Hongchen; Zhang Huafang; Peng Liping; Jiang Yanli; Ma Guojia

    2004-01-01

    The Plasma Immersion Ion Implantation and Deposition (PIII and D) process has many advantages over the pure plasma immersion ion implantation or deposition. It can compensate for or eliminate the disadvantages of the shallow modification layer (for PIII) and increase the bond strength of the coating (of deposition). For this purpose, a new type of microwave plasma source used in the PIII and D process was developed, composed of a vacuum bend wave guide and a special magnetic circuit, so that the coupling window was protected from being deposited with a coating and bombarded by high-energy particles. So the life of the window is increased. To enhance the bonding between the coating and substrate a new biasing voltage is applied to the work piece so that the implantation and deposition (or hybrid process) can be completed in one vacuum cycle

  8. Importance of isotopes for understanding the sedimentation processes

    International Nuclear Information System (INIS)

    Manjunatha, B.R.

    2012-01-01

    Isotopes of either radioactive or stable depending upon radiation emitted or not respectively which have wide applications in understanding not only the history of sedimentation, but also provide information about paleoclimate. Stable isotope mass difference occurs due to changes in physicochemical conditions of the ambient environment, for instance temperature, evaporation, precipitation, redox processes, and changes in the mobility of elements during weathering processes, biological uptake, metabolism, re-mineralization of biogenic material, etc. In contrast, radionuclides emit radiation because of excess of neutrons present in the nucleus when compared to protons of an atom. The decay of radioactive isotopes is unaffected despite changes in physicochemical variations; hence, they are useful for determining ages of different types of materials on earth. The radioisotopes can be classified based on origin and half life into primordial or long-lived, cosmogenic and artificial radionuclides or fission products. In this study, the importance of 137 Cs artificial radionuclides will be highlighted to understand short-term sedimentation processes, particularly in estuaries, deltas/continental shelf of west coast of India. The distribution of 137 Cs in sediments of south-western continental margin of India indicates that coastal marginal environments are filters or sinks for fall-out radionuclides. The sparse of 137 Cs in the open continental shelf environment indicates that most of sediments are either older or sediments being diluted by components generated in the marine environment

  9. Novel sedimentological fingerprints link shifting depositional processes to Holocene climate transitions in East Greenland

    Science.gov (United States)

    van der Bilt, Willem G. M.; Rea, Brice; Spagnolo, Matteo; Roerdink, Desiree L.; Jørgensen, Steffen L.; Bakke, Jostein

    2018-05-01

    The Arctic warms faster than any other region of our planet. Besides melting glaciers, thawing permafrost and decreasing sea-ice, this amplified response affects earth surface processes. This geomorphological expression of climate change may alter landscapes and increase the frequency and magnitude of geohazards like floods or mass-movements. Beyond the short span of sparse monitoring time series, geological archives provide a valuable long-term context for future risk assessment. Lake sediment sequences are particularly promising in this respect as continuous recorders of surface process change. Over the past decade, the emergence of new techniques that characterize depositional signatures in more detail has enhanced this potential. Here, we present a well-dated Holocene-length lake sediment sequence from Ammassalik Island on southeast Greenland. This area is particularly sensitive to regional shifts in the Arctic climate system due to its location near the sea-ice limit, the Greenland Ice Sheet and the convergence of polar and Atlantic waters. The expression of Holocene change is fingerprinted using physical (grain size, organic content, density), visual (3-D Computed Tomography) and geochemical (X-Ray Fluorescence, X-Ray Diffraction) evidence. We show that three sharp transitions characterize the Holocene evolution of Ymer Lake. Between 10 and 9.5 cal. ka BP, rapid local glacier loss from the lake catchment culminated in an outburst flood. Following a quiescent Holocene climatic optimum, Neoglacial cooling, lengthening lake ice cover and shifting wind patterns prompted in-lake avalanching of sediments from 4.2 cal. ka BP onwards. Finally, glaciers reformed in the catchment around 1.2 cal. ka BP. The timing of these shifts is consistent with the regional expression of deglaciation, Neoglacial cooling and Little Ice Age-type glacier growth, respectively. The novel multi-proxy approach applied in this study rigorously links depositional sediment signatures to

  10. Performance characterization of Ni60-WC coating on steel processed with supersonic laser deposition

    Directory of Open Access Journals (Sweden)

    Fang Luo

    2015-03-01

    Full Text Available Ni60-WC particles are used to improve the wear resistance of hard-facing steel due to their high hardness. An emerging technology that combines laser with cold spraying to deposit the hard-facing coatings is known as supersonic laser deposition. In this study, Ni60-WC is deposited on low-carbon steel using SLD. The microstructure and performance of the coatings are investigated through SEM, optical microscopy, EDS, XRD, microhardness and pin-on-disc wear tests. The experimental results of the coating processed with the optimal parameters are compared to those of the coating deposited using laser cladding.

  11. Understanding of how older adults with low vision obtain, process, and understand health information and services.

    Science.gov (United States)

    Kim, Hyung Nam

    2017-10-16

    Twenty-five years after the Americans with Disabilities Act, there has still been a lack of advancement of accessibility in healthcare for people with visual impairments, particularly older adults with low vision. This study aims to advance understanding of how older adults with low vision obtain, process, and use health information and services, and to seek opportunities of information technology to support them. A convenience sample of 10 older adults with low vision participated in semi-structured phone interviews, which were audio-recorded and transcribed verbatim for analysis. Participants shared various concerns in accessing, understanding, and using health information, care services, and multimedia technologies. Two main themes and nine subthemes emerged from the analysis. Due to the concerns, older adults with low vision tended to fail to obtain the full range of all health information and services to meet their specific needs. Those with low vision still rely on residual vision such that multimedia-based information which can be useful, but it should still be designed to ensure its accessibility, usability, and understandability.

  12. Deposition of metallic nanoparticles on carbon nanotubes via a fast evaporation process

    International Nuclear Information System (INIS)

    Ren Guoqiang; Xing Yangchuan

    2006-01-01

    A new technique was developed for the deposition of colloidal metal nanoparticles on carbon nanotubes. It involves fast evaporation of a suspension containing sonochemically functionalized carbon nanotubes and colloidal nanoparticles. It was demonstrated that metallic nanoparticles with different sizes and concentrations can be deposited on the carbon nanotubes with only a few agglomerates. The technique does not seem to be limited by what the nanoparticles are, and therefore would be applicable to the deposition of other nanoparticles on carbon nanotubes. PtPd and CoPt 3 alloy nanoparticles were used to demonstrate the deposition process. It was found that the surfactants used to disperse the nanoparticles can hinder the nanoparticle deposition. When the nanoparticles were washed with ethanol, they could be well deposited on the carbon nanotubes. The obtained carbon nanotube supported metal nanoparticles were characterized by transmission electron microscopy, energy dispersive x-ray spectroscopy, x-ray photoelectron spectroscopy, and cyclic voltammetry

  13. Sedimentation rates and depositional processes in Lake Superior from 210Pb geochronology

    International Nuclear Information System (INIS)

    Evans, J.E.; Johnson, T.C.; Alexander, E.C. Jr.; Lively, R.S.; Eisenreich, S.J.

    1981-01-01

    Sedimentation rates range from 0.01 to 0.32 cm/yr in 17 sediment box cores from Lake Superior, as determined by 210 Pb geochronology. Shoreline erosion and resuspension of nearshore sediments causes moderate to high (0.05-0.11 cm/yr) sedimentation rates in the western arm of Lake Superior. Sedimentation rates are very high (> 0.15 cm/yr) in marginal bays adjoining Lake Superior; and moderate to very high (0.07-0.19 cm/yr) in open lake regions adjacent to marginal bays. Resuspension of nearshore and shoal top sediments in southern and southeastern Lake Superior by storms is responsible for depositional anomalies in 210 Pb profiles corresponding to 1905, 1916-1918, and 1940 storms. Sedimentation rates are very low (0.01-0.03 cm/yr) in the central basins due to isolation from sediment sources. These data indicate that sedimentation rates and processes vary significantly in different regions of Lake Superior. The sedimentation rates provided by this study, in conjunction with previously-reported sedimentation rates, yield a better understanding of the Lake Superior depositional environment

  14. Processes in Environmental Depositional Systems and Deformation in Sedimentary Basins: Goals for Exoloration in Mexico

    Science.gov (United States)

    Sandoval-Ochoa, J.

    2005-05-01

    Among the recent needs to establish new goals in the mexican energy industry to increase the petroleum reserves, has been necessary to recapitulate on some academic an operative concepts and definitions applied to the Petroliferous Basins Exploration; first of all, in order to understand the Petroleum System in given tectonophysical framework. The tectonophysical environment experienced by the petroliferous basin in the southwestern Gulf of Mexico, merely in the Campeche Sound and adjacent terrestrial regions (Figure 1); has been the result of interaction among the tectonic plates, the Coco's Plate with impingement and subduction beneath the Northamerican Plate and the Yucatán Microplate and even in very deep connection with the oceanic crust of southwesternmost portion of the Gulf of Mexico and the one of the Caribbean sea beneath the gulf of Belize-Honduras. The tectonosedimentary effects in the Campeche Bay starting with the skeleton formed for the Cenozoic Era, kept simultaneous conditions in depositions and deformations because of strain, stress and collapse fields, acted through this Era up to the present day, as observed in the surface Aguayo et al, 1999 and Sandoval, 2000. The involved portions of the crust and its boundaries have also been performing the relative sinking of the mere southwestern centre of the Gulf of Mexico, and the rising of the southeastern lands of Mexico. In the middle contiguity are found the productive Tertiary basins of: Comalcalco, Macuspana, Salina del Itsmo, Campeche-Champoton and other in deep waters; all of them, in an arrangement of basins among distensive faulted blocks in echelon, falling down to the deep centre of the Gulf Sandoval, op cit. With this scenario and that ones of other basins, a recapitulation on concepts and definitions, has been made on the regional natural processes of the environmental depositional systems and on the basins analysis in the tectonophysical framework, in order to reflect on the

  15. Electroless deposition process for zirconium and zirconium alloys

    Science.gov (United States)

    Donaghy, Robert E.; Sherman, Anna H.

    1981-01-01

    A method is disclosed for preventing stress corrosion cracking or metal embrittlement of a zirconium or zirconium alloy container that is to be coated on the inside surface with a layer of a metal such as copper, a copper alloy, nickel, or iron and used for holding nuclear fuel material as a nuclear fuel element. The zirconium material is etched in an etchant solution, desmutted mechanically or ultrasonically, oxidized to form an oxide coating on the zirconium, cleaned in an aqueous alkaline cleaning solution, activated for electroless deposition of a metal layer and contacted with an electroless metal plating solution. This method provides a boundary layer of zirconium oxide between the zirconium container and the metal layer.

  16. A Study of CRUD Deposition Processing and Composition Materials

    International Nuclear Information System (INIS)

    Jung, Yanghong; Kim, H. M.; Yoo, B. O.; Baik, S. J.; Ahn, S. B.

    2013-07-01

    After cutting and drilling the spent fuel, we made a scrapping crud from the surface on the cladding. To scrap crud on the cladding surface, we made a special apparatus which has a 1/1,000 mm accuracy, but we could not taken crud. Thus, we effort the most possible use equipment to take crud samples, but unfortunately failed to get crud. We assume the crud would be dissolved. Because of the two fuel cladding, 17ACE7 and Plus 7, which were storage in PIEF pool for few years, it would be chemical reaction between pool water and crud deposited on the cladding. But we could not know the reason clearly. Therefore, it was impossible to analysis the crud, after that this project had to be stopped

  17. Connecting the records: exploiting tephra deposits to help understand abrupt climate change

    Science.gov (United States)

    Davies, S. M.; Abbott, P. M.; Bourne, A. J.; Chapman, M.; Pearce, N. J. G.; Griggs, A. J.; Cook, E.

    2016-12-01

    The causal mechanism of abrupt climate change during the last glacial period remains a key challenge. Although these events are well-documented in a wide range of proxy records, the triggers and drivers remain poorly understood, largely due to the dating uncertainties that prevent the integration of different archives. Unravelling the lead/lag responses (hence cause and effect) between the Earth's climate components is limited by the challenges of synchronising palaeoclimate records on a common timescale. Here we present the potential and the challenges of optimising the use of cryptotephra deposits to precisely correlate the Greenland ice-cores with North Atlantic marine records. A series of new cryptotephra deposits have been identified in Greenland, increasing the scope of identifying coeval isochrons in the marine environment. This new framework, however, brings new challenges in the search for unique and robust geochemical fingerprints for unequivocal tephra correlations. As such, some tephra deposits are proposed to be more valuable than others and underpin key snapshots in time during the last glacial period. The North Atlantic Ash Zone II, for instance, represents the most widespread isochron and constrains the cooling of GI-15. Some tephra deposits in the ice-core record originate from ultra-distal sources beyond the North Atlantic region and we also explore the potential for establishing North Pacific linkages.

  18. Radial transport processes as a precursor to particle deposition in drinking water distribution systems.

    Science.gov (United States)

    van Thienen, P; Vreeburg, J H G; Blokker, E J M

    2011-02-01

    Various particle transport mechanisms play a role in the build-up of discoloration potential in drinking water distribution networks. In order to enhance our understanding of and ability to predict this build-up, it is essential to recognize and understand their role. Gravitational settling with drag has primarily been considered in this context. However, since flow in water distribution pipes is nearly always in the turbulent regime, turbulent processes should be considered also. In addition to these, single particle effects and forces may affect radial particle transport. In this work, we present an application of a previously published turbulent particle deposition theory to conditions relevant for drinking water distribution systems. We predict quantitatively under which conditions turbophoresis, including the virtual mass effect, the Saffman lift force, and the Magnus force may contribute significantly to sediment transport in radial direction and compare these results to experimental observations. The contribution of turbophoresis is mostly limited to large particles (>50 μm) in transport mains, and not expected to play a major role in distribution mains. The Saffman lift force may enhance this process to some degree. The Magnus force is not expected to play any significant role in drinking water distribution systems. © 2010 Elsevier Ltd. All rights reserved.

  19. Understanding and Predicting the Process of Software Maintenance Releases

    Science.gov (United States)

    Basili, Victor; Briand, Lionel; Condon, Steven; Kim, Yong-Mi; Melo, Walcelio L.; Valett, Jon D.

    1996-01-01

    One of the major concerns of any maintenance organization is to understand and estimate the cost of maintenance releases of software systems. Planning the next release so as to maximize the increase in functionality and the improvement in quality are vital to successful maintenance management. The objective of this paper is to present the results of a case study in which an incremental approach was used to better understand the effort distribution of releases and build a predictive effort model for software maintenance releases. This study was conducted in the Flight Dynamics Division (FDD) of NASA Goddard Space Flight Center(GSFC). This paper presents three main results: 1) a predictive effort model developed for the FDD's software maintenance release process; 2) measurement-based lessons learned about the maintenance process in the FDD; and 3) a set of lessons learned about the establishment of a measurement-based software maintenance improvement program. In addition, this study provides insights and guidelines for obtaining similar results in other maintenance organizations.

  20. Process understanding and cooperative design. Keys to high quality automation

    International Nuclear Information System (INIS)

    Tommila, T.; Heinonen, R.

    1995-01-01

    A systematic approach to the specification of process control systems, and four practical methods supporting user participation and interdisciplinary co-operation are described. The main steps of the design approach are: (1) hierarchical decomposition of the plant to process items of different types; (2) analysis and definition of requirements and control strategies associated with each process item; (3) definition of automation degree; and (4) functional specification of the control system and its user interface. The specification language used for this step is a combination of principles found in object oriented design, structured analysis as well as new language standards for programmable controllers and open information systems. The design review methods presented include structured control strategy meetings, safety analysis of sequential controls, review of graphic displays, and a usability questionnaire for existing plants. These methods can be used to elicit users' needs and operational experience, to gain a common understanding of the process functionality, or to detect errors in design specifications or in existing systems. (8 refs., 9 figs.)

  1. Thermal analysis of fused deposition modeling process using infrared thermography imaging and finite element modeling

    Science.gov (United States)

    Zhou, Xunfei; Hsieh, Sheng-Jen

    2017-05-01

    After years of development, Fused Deposition Modeling (FDM) has become the most popular technique in commercial 3D printing due to its cost effectiveness and easy-to-operate fabrication process. Mechanical strength and dimensional accuracy are two of the most important factors for reliability of FDM products. However, the solid-liquid-solid state changes of material in the FDM process make it difficult to monitor and model. In this paper, an experimental model was developed to apply cost-effective infrared thermography imaging method to acquire temperature history of filaments at the interface and their corresponding cooling mechanism. A three-dimensional finite element model was constructed to simulate the same process using element "birth and death" feature and validated with the thermal response from the experimental model. In 6 of 9 experimental conditions, a maximum of 13% difference existed between the experimental and numerical models. This work suggests that numerical modeling of FDM process is reliable and can facilitate better understanding of bead spreading and road-to-road bonding mechanics during fabrication.

  2. Plasma processing techniques for deposition of carbonic thin protective coatings on structural nuclear materials

    International Nuclear Information System (INIS)

    Andrei, V.; Oncioiu, G.; Coaca, E.; Rusu, O.; Lungu, C.

    2009-01-01

    Full text of publication follows: The production of nano-structured surface films with controlled properties is crucial for the development of materials necessary for the Advanced Systems for Nuclear Energy. Since the surface of materials is the zone through which materials interact with the environment, the surface science and surface engineering techniques plays an essential role in the understanding and control of the processes involved. Complex surface structures were developed on stainless steels used as structural nuclear materials: austenitic stainless steels based on Fe, austenitic steels with high content of Cr, ferrites resistant to corrosion, by various Plasma Processing methods which include: - Plasma Electrolytic (PE) treatments: the steel substrates were modified by nitriding and nitro-carburizing plasma diffusion treatments; - carbonic films deposition in Thermionic Vacuum Arc Plasma. The results of the characterization of surface structures obtained in various experimental conditions for improvement of the properties (corrosion resistance, hardness, wear properties) are reported: the processes and structures were characterized by correlation of the results of the complementary techniques: XPS, 'depth profiling', SEM, XRD, EIS. An overall description of the processes involved in the surface properties improvement, and some consideration about the new materials development for energy technologies are presented

  3. One-step electrodeposition process of CuInSe2: Deposition time effect

    Indian Academy of Sciences (India)

    Administrator

    CuInSe2 thin films were prepared by one-step electrodeposition process using a simplified two- electrodes system. ... homojunctions or heterojunctions (Rincon et al 1983). Efficiency of ... deposition times onto indium thin oxide (ITO)-covered.

  4. Complex processing of antimony-mercury gold concentrates of Dzhizhikrut Deposit

    International Nuclear Information System (INIS)

    Abdusalyamova, M.N.; Gadoev, S.A.; Dreisinger, D.; Solozhenkin, P.M.

    2013-01-01

    Present article is devoted to complex processing of antimony-mercury gold concentrates of Dzhizhikrut Deposit. The purpose of research was obtaining the metallic mercury and antimony with further gold and thallium extraction.

  5. A discrete element based simulation framework to investigate particulate spray deposition processes

    KAUST Repository

    Mukherjee, Debanjan; Zohdi, Tarek I.

    2015-01-01

    © 2015 Elsevier Inc. This work presents a computer simulation framework based on discrete element method to analyze manufacturing processes that comprise a loosely flowing stream of particles in a carrier fluid being deposited on a target surface

  6. Process control of high rate microcrystalline silicon based solar cell deposition by optical emission spectroscopy

    International Nuclear Information System (INIS)

    Kilper, T.; Donker, M.N. van den; Carius, R.; Rech, B.; Braeuer, G.; Repmann, T.

    2008-01-01

    Silicon thin-film solar cells based on microcrystalline silicon (μc-Si:H) were prepared in a 30 x 30 cm 2 plasma-enhanced chemical vapor deposition reactor using 13.56 or 40.68 MHz plasma excitation frequency. Plasma emission was recorded by optical emission spectroscopy during μc-Si:H absorber layer deposition at deposition rates between 0.5 and 2.5 nm/s. The time course of SiH * and H β emission indicated strong drifts in the process conditions particularly at low total gas flows. By actively controlling the SiH 4 gas flow, the observed process drifts were successfully suppressed resulting in a more homogeneous i-layer crystallinity along the growth direction. In a deposition regime with efficient usage of the process gas, the μc-Si:H solar cell efficiency was enhanced from 7.9 % up to 8.8 % by applying process control

  7. PVD processes of thin films deposition using Hall-current discharge

    International Nuclear Information System (INIS)

    Svadkovskij, I.V.

    2007-01-01

    Results of research and developments in the field of PVD processes of thin films deposition using Hall-current discharge have been summarized. Effects of interaction of ions with surface during deposition have been considered. Also features of application and prospects of devices based on ion beam and magnetron sputtering systems in thin films technologies have been analyzed. The aspects in the field plasma physics, technology and equipment plasma PVD processes of thin films deposition have been systematized, on the base of investigations made by author and other scientists. (authors)

  8. Effect of Energy Input on the Characteristic of AISI H13 and D2 Tool Steels Deposited by a Directed Energy Deposition Process

    Science.gov (United States)

    Park, Jun Seok; Park, Joo Hyun; Lee, Min-Gyu; Sung, Ji Hyun; Cha, Kyoung Je; Kim, Da Hye

    2016-05-01

    Among the many additive manufacturing technologies, the directed energy deposition (DED) process has attracted significant attention because of the application of metal products. Metal deposited by the DED process has different properties than wrought metal because of the rapid solidification rate, the high thermal gradient between the deposited metal and substrate, etc. Additionally, many operating parameters, such as laser power, beam diameter, traverse speed, and powder mass flow rate, must be considered since the characteristics of the deposited metal are affected by the operating parameters. In the present study, the effect of energy input on the characteristics of H13 and D2 steels deposited by a direct metal tooling process based on the DED process was investigated. In particular, we report that the hardness of the deposited H13 and D2 steels decreased with increasing energy input, which we discuss by considering microstructural observations and thermodynamics.

  9. Theory Building- Towards an understanding of business model innovation processes

    DEFF Research Database (Denmark)

    Taran, Yariv; Boer, Harry; Lindgren, Peter

    2009-01-01

    Companies today, in some industries more than others, invest more capital and resources just to stay competitive, develop more diverse solutions, and increasingly start to think more radically, when considering to innovate their business model. However, the development and innovation of business...... models is a complex venture and has not been widely researched yet. The objective of this paper is therefore 1) to build a [descriptive] theoretical understanding, based on Christensen's (2005) three-step procedure, to business models and their innovation and, as a result of that, 2) to strengthen...... researchers' and practitioners' perspectives as to how the process of business model innovation can be realized. By using various researchers' perspectives and assumptions, we identify relevant inconsistencies, which consequently lead us to propose possible supplementary solutions. We conclude our paper...

  10. Using infrared thermography for understanding and quantifying soil surface processes

    Science.gov (United States)

    de Lima, João L. M. P.

    2017-04-01

    At present, our understanding of the soil hydrologic response is restricted by measurement limitations. In the literature, there have been repeatedly calls for interdisciplinary approaches to expand our knowledge in this field and eventually overcome the limitations that are inherent to conventional measuring techniques used, for example, for tracing water at the basin, hillslope and even field or plot scales. Infrared thermography is a versatile, accurate and fast technique of monitoring surface temperature and has been used in a variety of fields, such as military surveillance, medical diagnosis, industrial processes optimisation, building inspections and agriculture. However, many applications are still to be fully explored. In surface hydrology, it has been successfully employed as a high spatial and temporal resolution non-invasive and non-destructive imaging tool to e.g. access groundwater discharges into waterbodies or quantify thermal heterogeneities of streams. It is believed that thermal infrared imagery can grasp the spatial and temporal variability of many processes at the soil surface. Thermography interprets the heat signals and can provide an attractive view for identifying both areas where water is flowing or has infiltrated more, or accumulated temporarily in depressions or macropores. Therefore, we hope to demonstrate the potential for thermal infrared imagery to indirectly make a quantitative estimation of several hydrologic processes. Applications include: e.g. mapping infiltration, microrelief and macropores; estimating flow velocities; defining sampling strategies; identifying water sources, accumulation of waters or even connectivity. Protocols for the assessment of several hydrologic processes with the help of IR thermography will be briefly explained, presenting some examples from laboratory soil flumes and field.

  11. Experimental Simulations to Understand the Lunar and Martian Surficial Processes

    Science.gov (United States)

    Zhao, Y. Y. S.; Li, X.; Tang, H.; Li, Y.; Zeng, X.; Chang, R.; Li, S.; Zhang, S.; Jin, H.; Mo, B.; Li, R.; Yu, W.; Wang, S.

    2016-12-01

    In support with China's Lunar and Mars exploration programs and beyond, our center is dedicated to understand the surficial processes and environments of planetary bodies. Over the latest several years, we design, build and optimize experimental simulation facilities and utilize them to test hypotheses and evaluate affecting mechanisms under controlled conditions particularly relevant to the Moon and Mars. Among the fundamental questions to address, we emphasize on five major areas: (1) Micrometeorites bombardment simulation to evaluate the formation mechanisms of np-Fe0 which was found in lunar samples and the possible sources of Fe. (2) Solar wind implantation simulation to evaluate the alteration/amorphization/OH or H2O formation on the surface of target minerals or rocks. (3) Dusts mobility characteristics on the Moon and other planetary bodies by excitation different types of dust particles and measuring their movements. (4) Mars basaltic soil simulant development (e.g., Jining Martian Soil Simulant (JMSS-1)) and applications for scientific/engineering experiments. (5) Halogens (Cl and Br) and life essential elements (C, H, O, N, P, and S) distribution and speciation on Mars during surficial processes such as sedimentary- and photochemical- related processes. Depending on the variables of interest, the simulation systems provide flexibility to vary source of energy, temperature, pressure, and ambient gas composition in the reaction chambers. Also, simulation products can be observed or analyzed in-situ by various analyzer components inside the chamber, without interrupting the experimental conditions. In addition, behavior of elements and isotopes during certain surficial processes (e.g., evaporation, dissolution, etc.) can be theoretically predicted by our theoretical geochemistry group with thermodynamics-kinetics calculation and modeling, which supports experiment design and result interpretation.

  12. A Science-Based Understanding of Cermet Processing

    Energy Technology Data Exchange (ETDEWEB)

    Cesarano, III, Joseph [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Roach, Robert Allen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Kilgo, Alice C. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Susan, Donald Francis [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Van Ornum, David J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Stuecker, John N. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Shollenberger, Kimberly A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2006-04-01

    This report is a summary of the work completed in FY01 for science-based characterization of the processes used to fabricate 1) cermet vias in source feedthrus using slurry and paste-filling techniques and 2) cermet powder for dry pressing. Common defects found in cermet vias were characterized based on the ability of subsequent processing techniques (isopressing and firing) to remove the defects. Non-aqueous spray drying and mist granulation techniques were explored as alternative methods of creating CND50, the powder commonly used for dry pressed parts. Compaction and flow characteristics of these techniques were analyzed and compared to standard dry-ball-milled CND50. Due to processing changes, changes in microstructure can occur. A microstructure characterization technique was developed to numerically describe cermet microstructure. Machining and electrical properties of dry pressed parts were also analyzed and related to microstructure using this analytical technique.3 Executive SummaryThis report outlines accomplishments in the science-based understanding of cermet processing up to fiscal year 2002 for Sandia National Laboratories. The three main areas of work are centered on 1) increasing production yields of slurry-filled cermets, 2) evaluating the viability of high-solids-loading pastes for the same cermet components, and 3) optimizing cermet powder used in pressing processes (CND50). An additional development that was created as a result of the effort to fully understand the impacts of alternative processing techniques is the use of analytical methods to relate microstructure to physical properties. Recommendations are suggested at the end of this report. Summaries of these four efforts are as follows:1.Increase Production Yields of Slurry-Filled Cermet Vias Finalized slurry filling criteria were determined based on three designs of experiments where the following factors were analyzed: vacuum time, solids loading, pressure drop across the filter paper

  13. Salt separation of uranium deposits generated from electrorefining in pyro process

    International Nuclear Information System (INIS)

    Kwon, S. W.; Park, K. M.; Jeong, J. H.; Lee, H. S.; Kim, J. G.

    2012-01-01

    Electrorefining is a key step in a pyro processing. Electrorefining process is generally composed of two recovery steps- deposit of uranium onto a solid cathode(electrorefining) and then the recovery of the remaining uranium and TRU(TransUranic) elements simultaneously by a liquid cadmium cathode(electrowinning). The uranium ingot is prepared from the deposits after the salt separation. In this study, the sequential operation of the liquid salt separation? distillation of the residual salt was attempted for the achievement of high throughput performance in the salt separation. The effects of deposit size and packing density were also investigated with steel chips, steel chips, and uranium dendrites. The apparent evaporation rate decreased with the increasing packing density or the increasing size of deposits due to the hindrance of the vapor transport by the deposits. It was found that the packing density and the geometry of deposit crucible are important design parameters for the salt separation system. Base on the results of the study, an engineering scale salt distiller was developed and installed in the argon cell. The salt distiller is a batch-type, and the process capacity to about 50 kg U-deposits/day. The design of the salt distiller is based on the remote operation by Master Slave Manipulator (MSM) and a hoist. The salt distiller is composed of two large blocks of the distillation tower and the crucible loading system for the transportation to maintenance room via the Large Transfer Lock (LTL)

  14. Salt separation of uranium deposits generated from electrorefining in pyro process

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, S. W.; Park, K. M.; Jeong, J. H.; Lee, H. S.; Kim, J. G. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2012-03-15

    Electrorefining is a key step in a pyro processing. Electrorefining process is generally composed of two recovery steps- deposit of uranium onto a solid cathode(electrorefining) and then the recovery of the remaining uranium and TRU(TransUranic) elements simultaneously by a liquid cadmium cathode(electrowinning). The uranium ingot is prepared from the deposits after the salt separation. In this study, the sequential operation of the liquid salt separation? distillation of the residual salt was attempted for the achievement of high throughput performance in the salt separation. The effects of deposit size and packing density were also investigated with steel chips, steel chips, and uranium dendrites. The apparent evaporation rate decreased with the increasing packing density or the increasing size of deposits due to the hindrance of the vapor transport by the deposits. It was found that the packing density and the geometry of deposit crucible are important design parameters for the salt separation system. Base on the results of the study, an engineering scale salt distiller was developed and installed in the argon cell. The salt distiller is a batch-type, and the process capacity to about 50 kg U-deposits/day. The design of the salt distiller is based on the remote operation by Master Slave Manipulator (MSM) and a hoist. The salt distiller is composed of two large blocks of the distillation tower and the crucible loading system for the transportation to maintenance room via the Large Transfer Lock (LTL)

  15. Hydrothermal processes in the Edmond deposits, slow- to intermediate-spreading Central Indian Ridge

    Science.gov (United States)

    Cao, Hong; Sun, Zhilei; Zhai, Shikui; Cao, Zhimin; Jiang, Xuejun; Huang, Wei; Wang, Libo; Zhang, Xilin; He, Yongjun

    2018-04-01

    The Edmond hydrothermal field, located on the Central Indian Ridge (CIR), has a distinct mineralization history owing to its unique magmatic, tectonic, and alteration processes. Here, we report the detailed mineralogical and geochemical characteristics of hydrothermal metal sulfides recovered from this area. Based on the mineralogical investigations, the Edmond hydrothermal deposits comprise of high-temperature Fe-rich massive sulfides, medium-temperature Zn-rich sulfide chimney and low-temperature Ca-rich sulfate mineral assemblages. According to these compositions, three distinctive mineralization stages have been identified: (1) low-temperature consisting largely of anhydrite and pyrite/marcasite; (2) medium-high temperature distinguished by the mineral assemblage of pyrite, sphalerite and chalcopyrite; and (3) low-temperature stage characterized by the mineral assemblage of colloidal pyrite/marcasite, barite, quartz, anglesite. Several lines of evidence suggest that the sulfides were influenced by pervasive low-temperature diffuse flows in this area. The hydrothermal deposits are relatively enriched in Fe (5.99-18.93 wt%), Zn (2.10-10.00 wt%) and Ca (0.02-19.15 wt%), but display low Cu (0.28-0.81 wt%). The mineralogical varieties and low metal content of sulfides in the Edmond hydrothermal field both indicate that extensive water circulation is prevalent below the Edmond hydrothermal field. With regard to trace elements, the contents of Pb, Ba, Sr, As, Au, Ag, and Cd are significantly higher than those in other sediment-starved mid-ocean ridges, which is indicative of contribution from felsic rock sources. Furthermore, the multiphase hydrothermal activity and the pervasive water circulation underneath are speculated to play important roles in element remobilization and enrichment. Our findings deepen our understanding about the complex mineralization process in slow- to intermediate-spreading ridges globally.

  16. Measures for waste water management from recovery processing of Zhushanxia uranium deposit

    International Nuclear Information System (INIS)

    Liu Yaochi; Xu Lechang

    2000-01-01

    Measures for waste water management from recovery processing of Zhushanxia uranium deposit of Wengyuan Mine is analyzed, which include improving process flow, recycling process water used in uranium mill as much as possible and choosing a suitable disposing system. All these can decrease the amount of waste water, and also reduce costs of disposing waste water and harm to environment

  17. Deposition of polymeric perfluored thin films in proton ionic membranes by plasma processes

    International Nuclear Information System (INIS)

    Polak, Peter Lubomir; Mousinho, Ana Paula; Ordonez, Nelson; Silva Zambom, Luis da; Mansano, Ronaldo Domingues

    2007-01-01

    In this work the surfaces of polymeric membranes based on Nafion (proton conducting material), used in proton exchange membranes fuel cells (PEMFC) had been modified by plasma deposition of perfluored polymers, in order to improve its functioning in systems of energy generation (fuel cells). The deposition increases the chemical resistance of the proton ionic polymers without losing the electrical properties. The processing of the membranes also reduces the permeability of the membranes to the alcohols (methanol and ethanol), thus preventing poisoning of the fuel cell. The processing of the membranes of Nafion was carried through in a system of plasma deposition using a mixture of CF 4 and H 2 gases. The plasma processing was made mainly to increase the chemical resistance and result in hydrophobic surfaces. The Fourier transformed infrared (FTIR) technique supplies a spectrum with information about the CF n bond formation. Through the Rutherford back scattering (RBS) technique it was possible to verify the deposition rate of the polymeric layer. The plasma process with composition of 60% of CF 4 and 40% of H 2 presented the best deposition rate. By the spectrum analysis for the optimized configuration, it was possible to verify that the film deposition occurred with a thickness of 90 nm, and fluorine concentration was nearly 30%. Voltammetry made possible to verify that the fluorination increases the membranes chemical resistance, improving the stability of Nafion, becoming an attractive process for construction of fuel cells

  18. Understanding Aquatic Rhizosphere Processes Through Metabolomics and Metagenomics Approach

    Science.gov (United States)

    Lee, Yong Jian; Mynampati, Kalyan; Drautz, Daniela; Arumugam, Krithika; Williams, Rohan; Schuster, Stephan; Kjelleberg, Staffan; Swarup, Sanjay

    2013-04-01

    The aquatic rhizosphere is a region around the roots of aquatic plants. Many studies focusing on terrestrial rhizosphere have led to a good understanding of the interactions between the roots, its exudates and its associated rhizobacteria. The rhizosphere of free-floating roots, however, is a different habitat that poses several additional challenges, including rapid diffusion rates of signals and nutrient molecules, which are further influenced by the hydrodynamic forces. These can lead to rapid diffusion and complicates the studying of diffusible factors from both plant and/or rhizobacterial origins. These plant systems are being increasingly used for self purification of water bodies to provide sustainable solution. A better understanding of these processes will help in improving their performance for ecological engineering of freshwater systems. The same principles can also be used to improve the yield of hydroponic cultures. Novel toolsets and approaches are needed to investigate the processes occurring in the aquatic rhizosphere. We are interested in understanding the interaction between root exudates and the complex microbial communities that are associated with the roots, using a systems biology approach involving metabolomics and metagenomics. With this aim, we have developed a RhizoFlowCell (RFC) system that provides a controlled study of aquatic plants, observed the root biofilms, collect root exudates and subject the rhizosphere system to changes in various chemical or physical perturbations. As proof of concept, we have used RFC to test the response of root exudation patterns of Pandanus amaryllifolius after exposure to the pollutant naphthalene. Complexity of root exudates in the aquatic rhizosphere was captured using this device and analysed using LC-qTOF-MS. The highly complex metabolomic profile allowed us to study the dynamics of the response of roots to varying levels of naphthalene. The metabolic profile changed within 5mins after spiking with

  19. Studies of Physicochemical Processes in Atmospheric Particles and Acid Deposition.

    Science.gov (United States)

    Pandis, Spyros N.

    A comprehensive chemical mechanism for aqueous -phase atmospheric chemistry was developed and its detailed sensitivity analysis was performed. The main aqueous-phase reaction pathways for the system are the oxidation of S(IV) to S(VI) by H_2O_2 , OH, O_2 (catalysed by Fe ^{3+} and Mn^ {2+}), O_3 and HSO_sp{5}{-}. The gas-phase concentrations of SO_2, H_2O_2, HO _2, OH, O_3 HCHO, NH_3, HNO_3 and HCl and the liquid water content of the cloud are of primary importance. The Lagrangian model predictions for temperature profile, fog development, liquid water content, gas-phase concentrations of SO_2 , HNO_3, and NH_3 , pH, aqueous-phase concentrations of SO _sp{4}{2-}, NH _sp{4}{+} and NO _sp{3}{-}, and finally deposition rates of the above ions match well the observed values. A third model was developed to study the distribution of acidity and solute concentration among the various droplet sizes in a fog or a cloud. Significant solute concentration differences can occur in aqueous droplets inside a fog or a cloud. Fogs in polluted environments have the potential to increase aerosol sulfate concentrations, but at the same time to cause reductions in the aerosol concentration of nitrate, chloride, ammonium and sodium as well as in the total aerosol mass concentration. The sulfate producd during fog episodes favors the aerosol particles that have access to most of the fog liquid water. Aerosol scavenging efficiencies of around 80% were calculated for urban fogs. Sampling and subsequent mixing of fog droplets of different sizes may result in measured concentrations that are not fully representative of the fogwater chemical composition. Isoprene and beta-pinene, at concentration levels ranging from a few ppb to a few ppm were reacted photochemically with NO_ {x} in the Caltech outdoor smog chamber facility. Aerosol formation from the isoprene photooxidation was found to be negligible even under extreme ambient conditions due to the relatively high vapor pressure of its

  20. The Contribution of GGOS to Understanding Dynamic Earth Processes

    Science.gov (United States)

    Gross, Richard

    2017-04-01

    Geodesy is the science of the Earth's shape, size, gravity and rotation, including their evolution in time. Geodetic observations play a major role in the solid Earth sciences because they are fundamental for the understanding and modeling of Earth system processes. Changes in the Earth's shape, its gravitational field, and its rotation are caused by external forces acting on the Earth system and internal processes involving mass transfer and exchange of angular and linear momentum. Thus, variations in these geodetic quantities of the Earth reflect and constrain mechanical and thermo-dynamic processes in the Earth system. Mitigating the impact on human life and property of natural hazards such as earthquakes, volcanic eruptions, debris flows, landslides, land subsidence, sea level change, tsunamis, floods, storm surges, hurricanes and extreme weather is an important scientific task to which geodetic observations make fundamental contributions. Geodetic observations can be used to monitor the pre-eruptive deformation of volcanoes and the pre-seismic deformation of earthquake fault zones, aiding in the issuance of volcanic eruption and earthquake warnings. They can also be used to rapidly estimate earthquake fault motion, aiding in the modeling of tsunami genesis and the issuance of tsunami warnings. Geodetic observations are also used in other areas of the Earth sciences, not just the solid Earth sciences. For example, geodesy contributes to atmospheric science by supporting both observation and prediction of the weather by geo-referencing meteorological observing data and by globally tracking change in stratospheric mass and lower tropospheric water vapor fields. Geodetic measurements of refraction profiles derived from satellite occultation data are routinely assimilated into numerical weather prediction models. Geodesy contributes to hydrologic studies by providing a unique global reference system for measurements of: sub-seasonal, seasonal and secular movements

  1. Rapid deposition process for zinc oxide film applications in pyroelectric devices

    International Nuclear Information System (INIS)

    Hsiao, Chun-Ching; Yu, Shih-Yuan

    2012-01-01

    Aerosol deposition (AD) is a rapid process for the deposition of films. Zinc oxide is a low toxicity and environmentally friendly material, and it possesses properties such as semiconductivity, pyroelectricity and piezoelectricity without the poling process. Therefore, AD is used to accelerate the manufacturing process for applications of ZnO films in pyroelectric devices. Increasing the temperature variation rate in pyroelectric films is a useful method for enhancing the responsivity of pyroelectric devices. In the present study, a porous ZnO film possessing the properties of large heat absorption and high temperature variation rate is successfully produced by the AD rapid process and laser annealing for application in pyroelectric devices. (paper)

  2. In situ analysis of thin film deposition processes using time-of-flight (TOF) ion beam analysis methods

    International Nuclear Information System (INIS)

    Im, J.; Lin, Y.; Schultz, J.A.; Auciello, O.H.; Chang, R.P.H.

    1995-05-01

    Non-destructive, in situ methods for characterization of thin film growth phenomena is key to understand thin film growth processes and to develop more reliable deposition procedures, especially for complex layered structures involving multi-phase materials. However, surface characterization methods that use either electrons (e.g. AES or XPS) or low energy ions (SIMS) require an UHV environment and utilize instrumentation which obstructs line of sight access to the substrate and are therefore incompatible with line of sight deposition methods and thin film deposition processes which introduce gas, either part of the deposition or in order to produce the desired phase. We have developed a means of differentially pumping both the ion beam source and detectors of a TOF ion beam surface analysis spectrometer that does not interfere with the deposition process and permits compositional and structural analysis of the growing film in the present system, at pressures up to several mTorr. Higher pressures are feasible with modified source-detector geometry. In order to quantify the sensitivity of Ion Scattering Spectroscopy (ISS) and Direct Recoil Spectroscopy (DRS), we have measured the signal intensity for stabilized clean metals in a variety of gas environments as a function of the ambient gas species and pressure, and ion beam species and kinetic energy. Results are interpreted in terms of collision cross sections which are compared with known gas phase scattering data and provide an apriori basis for the evaluation of time-of-flight ion scattering and recoil spectroscopies (ToF-ISARS) for various industrial processing environments which involve both inert and reactive cases. The cross section data for primary ion-gas molecule and recoiled atom-gas molecule interactions are also provided. from which the maximum operating pressure in any experimental configuration can be obtained

  3. Sources and processes contributing to nitrogen deposition: an adjoint model analysis applied to biodiversity hotspots worldwide.

    Science.gov (United States)

    Paulot, Fabien; Jacob, Daniel J; Henze, Daven K

    2013-04-02

    Anthropogenic enrichment of reactive nitrogen (Nr) deposition is an ecological concern. We use the adjoint of a global 3-D chemical transport model (GEOS-Chem) to identify the sources and processes that control Nr deposition to an ensemble of biodiversity hotspots worldwide and two U.S. national parks (Cuyahoga and Rocky Mountain). We find that anthropogenic sources dominate deposition at all continental sites and are mainly regional (less than 1000 km) in origin. In Hawaii, Nr supply is controlled by oceanic emissions of ammonia (50%) and anthropogenic sources (50%), with important contributions from Asia and North America. Nr deposition is also sensitive in complicated ways to emissions of SO2, which affect Nr gas-aerosol partitioning, and of volatile organic compounds (VOCs), which affect oxidant concentrations and produce organic nitrate reservoirs. For example, VOC emissions generally inhibit deposition of locally emitted NOx but significantly increase Nr deposition downwind. However, in polluted boreal regions, anthropogenic VOC emissions can promote Nr deposition in winter. Uncertainties in chemical rate constants for OH + NO2 and NO2 hydrolysis also complicate the determination of source-receptor relationships for polluted sites in winter. Application of our adjoint sensitivities to the representative concentration pathways (RCPs) scenarios for 2010-2050 indicates that future decreases in Nr deposition due to NOx emission controls will be offset by concurrent increases in ammonia emissions from agriculture.

  4. Modeling of the Effect of Path Planning on Thermokinetic Evolutions in Laser Powder Deposition Process

    Science.gov (United States)

    Foroozmehr, Ehsan; Kovacevic, Radovan

    2011-07-01

    A thermokinetic model coupling finite-element heat transfer with transformation kinetics is developed to determine the effect of deposition patterns on the phase-transformation kinetics of laser powder deposition (LPD) process of a hot-work tool steel. The finite-element model is used to define the temperature history of the process used in an empirical-based kinetic model to analyze the tempering effect of the heating and cooling cycles of the deposition process. An area is defined to be covered by AISI H13 on a substrate of AISI 1018 with three different deposition patterns: one section, two section, and three section. The two-section pattern divides the area of the one-section pattern into two sections, and the three-section pattern divides that area into three sections. The results show that dividing the area under deposition into smaller areas can influence the phase transformation kinetics of the process and, consequently, change the final hardness of the deposited material. The two-section pattern shows a higher average hardness than the one-section pattern, and the three-section pattern shows a fully hardened surface without significant tempered zones of low hardness. To verify the results, a microhardness test and scanning electron microscope were used.

  5. Understanding the residence of Co in ore minerals - towards the development of novel Co extraction strategies for laterite deposits

    Science.gov (United States)

    Dybowska, Agnieszka; Norman, Rachel; Schofield, Paul; Herrington, Richard

    2017-04-01

    Cobalt has unique properties highly valued for many applications essential to the green economy. It has been classified as a critical raw material due to the particularly high risk of supply shortage and its importance for the value chain. Despite low crustal abundance (25ppm), Co is concentrated by various geological processes to concentrations suitable for mining, however the majority of Co is recovered as a by-product of Cu and Ni processing in three principal geological settings: hydrothermal, magmatic and lateritic. Cobalt-rich laterites, which provide 20% of the world's Co, are mainly processed using energy-inefficient pyrometallurgical techniques or high-pressure acid leaching technologies often optimised for extraction of other elements, which can leave between 50 and 80% of the Co unrecovered. In order to develop more efficient Co extraction strategies, understanding the residence of Co in ore minerals is essential. To this end, we are undertaking a detailed mineralogical, chemical and atomistic-scale characterization of Co in samples from a range of laterite deposits. Bulk samples representative of the average ore material were sourced from a variety of undeveloped laterite deposits: Shevchenko (Kazakhstan), Acoje (Philippines), Nkamouna (Cameroon) and Piauí (Brazil). Bulk chemical and mineralogical characterisation was undertaken with ICP-OES/MS and XRD, followed by spatially resolved chemical and mineralogical imaging at the micron scale using µXRD, EPMA, SEM and synchrotron-based µXRF. The chemical state and local environment of Co were determined using X ray spectroscopy (μXANES and μEXAFS). The total concentrations of Co ranged from 630 to 2780 mg/kg. The ore mineral assemblage in the various samples includes goethite, maghemite, hematite, quartz, talc, serpentines, chlorites, smectites, kaolinite and chromites. Manganese oxide minerals are present but, due to their poor crystallinity and low concentration, are not routinely detectable with bulk

  6. Framework for understanding LENR processes, using conventional condensed matter physics

    International Nuclear Information System (INIS)

    Chubb, Scott R.

    2006-01-01

    Conventional condensed matter physics provides a unifying framework for understanding low-energy nuclear reactions (LENRs) in solids. In the paper, standard many-body physics techniques are used to illustrate this fact. Specifically, the paper shows that formally the theories by Schwinger, Hagelstein, and Chubb and Chubb (C and C), all can be related to a common set of equations, associated with reaction rate and energy transfer, through a standard many-body physics procedure (R-matrix theory). In each case, particular forms of coherence are used that, implicitly provide a mechanism for understanding how LENRs can proceed without. the emission of high-energy particles. In addition, additional ideas, associated with Conventional Condensed Matter physics, are used to extend the earlier ion band state (IBS) model by C and C. The general model clarifies the origin of coherent. processes that initiate LENRs, through the onset of ion conduction that can occur through ionic fluctuations in nano-scale crystals. In the case of PdD x , these fluctuations begin to occur as x → 1 in sub-lattice structures with characteristic dimensions of 60 nm. The resulting LENRs are triggered by the polarization between injected d's and electrons (immediately above the Fermi energy) that takes place in finite-size PdD crystals. During the prolonged charging of PdD x the applied, external electric field induces these fluctuations through a form of Zener tunneling that mimics the kind of tunneling, predicted by Zener, that is responsible for possible conduction (referred to as Zener-electric breakdown) in insulators. But because the fluctuations are ionic and they occur in PdD, nano-scale structures, a more appropriate characterization is Zener-ionic breakdown in nano-crystalline PdD. Using the underlying dynamics, it is possible to relate triggering times that are required for the initiation of the effect, to crystal size and externally applied fields. (authors)

  7. Framework for understanding LENR processes, using conventional condensed matter physics

    Energy Technology Data Exchange (ETDEWEB)

    Chubb, Scott R. [Research Systems Inc., 9822 Pebble Weigh Ct., Burke VA 22015-3378 (United States)

    2006-07-01

    Conventional condensed matter physics provides a unifying framework for understanding low-energy nuclear reactions (LENRs) in solids. In the paper, standard many-body physics techniques are used to illustrate this fact. Specifically, the paper shows that formally the theories by Schwinger, Hagelstein, and Chubb and Chubb (C and C), all can be related to a common set of equations, associated with reaction rate and energy transfer, through a standard many-body physics procedure (R-matrix theory). In each case, particular forms of coherence are used that, implicitly provide a mechanism for understanding how LENRs can proceed without. the emission of high-energy particles. In addition, additional ideas, associated with Conventional Condensed Matter physics, are used to extend the earlier ion band state (IBS) model by C and C. The general model clarifies the origin of coherent. processes that initiate LENRs, through the onset of ion conduction that can occur through ionic fluctuations in nano-scale crystals. In the case of PdD{sub x}, these fluctuations begin to occur as x {yields} 1 in sub-lattice structures with characteristic dimensions of 60 nm. The resulting LENRs are triggered by the polarization between injected d's and electrons (immediately above the Fermi energy) that takes place in finite-size PdD crystals. During the prolonged charging of PdD{sub x} the applied, external electric field induces these fluctuations through a form of Zener tunneling that mimics the kind of tunneling, predicted by Zener, that is responsible for possible conduction (referred to as Zener-electric breakdown) in insulators. But because the fluctuations are ionic and they occur in PdD, nano-scale structures, a more appropriate characterization is Zener-ionic breakdown in nano-crystalline PdD. Using the underlying dynamics, it is possible to relate triggering times that are required for the initiation of the effect, to crystal size and externally applied fields. (authors)

  8. Deposition and post-processing techniques for transparent conductive films

    Energy Technology Data Exchange (ETDEWEB)

    Christoforo, Mark Greyson; Mehra, Saahil; Salleo, Alberto; Peumans, Peter

    2017-07-04

    In one embodiment, a method is provided for fabrication of a semitransparent conductive mesh. A first solution having conductive nanowires suspended therein and a second solution having nanoparticles suspended therein are sprayed toward a substrate, the spraying forming a mist. The mist is processed, while on the substrate, to provide a semitransparent conductive material in the form of a mesh having the conductive nanowires and nanoparticles. The nanoparticles are configured and arranged to direct light passing through the mesh. Connections between the nanowires provide conductivity through the mesh.

  9. Influence of substrate geometry on ion-plasma coating deposition process

    International Nuclear Information System (INIS)

    Khoroshikh, V.M.; Leonov, S.A.; Belous, V.A.

    2008-01-01

    Influence of substrate geometry on the feature of Ti vacuum arc plasma streams condensation process in presence of N 2 or Ar in a discharge ambient were investigated. Character of gas pressure and substrate potential influence on deposition rate is conditioned the competitive processes of condensation and sputtering, and also presence of double electric layer on a border plasma-substrate. Influence of potential on deposition rate especially strongly shows up for cylindrical substrates of small size. For such substrates it was found substantial (approximately in 4 times) growth of deposition rate at the increasing of negative potential from 100 to 700 V when nitrogen pressure is ∼0,3...2,5 Pa. Possibility of droplet-free coating deposition the substrate backs and in discharge ambient, being outside area of cathode direct visibility is shown

  10. Indium oxide deposition on glass by aerosol pyrolysis (Pyrosol (R) process)

    International Nuclear Information System (INIS)

    Blandenet, G.; Lagarde, Y.; Spitz, J.

    1975-01-01

    The pyrosol (R) process involves the pyrolysis of an aerosol generated by ultrasonic nebulisation from a solution of organic or inorganic compounds. This technique was used to deposit transparent n-conducting indium oxide films on glass. The electrical and optical properties of these films were studied as a function of the deposition temperature and doping (using tin or fluorine). A deposition temperature of 480 deg C and a Sn/In ratio of about 5% gave the best results. In this case, the transmission in the visible range was 92%, the infrared reflection 84% and the electrical resistivity 1.7x10 -4 ohm.cm [fr

  11. Understanding Stoichiometric Controls in Nutrient Processing Along the River Continuum

    Science.gov (United States)

    Garayburu-Caruso, V. A.; Gonzalez-Pinzon, R.; Van Horn, D. J.; Covino, T. P.

    2016-12-01

    Eutrophication is the second most common cause of water impairment across the U.S. Nutrient retention in streams is controlled by physical and biochemical processes, including biomass availability and stoichiometric limitations. Decoupling the interactions between hydrology, nutrient supply and biogeochemical processes remains challenging for the scientific community due to lack of mechanistic understanding. Consequently, more knowledge regarding optimal controls for nutrient retention is needed to implement better management and restoration practices. We conducted column experiments to investigate how stoichiometric limitations influence nutrient spiraling in shallow sediment-water interactions along representative sites of the Jemez River-Rio Grande continuum (which spans eight stream orders), in New Mexico, USA. In each stream order we incubated six columns packed with different sediments (i.e., Silica Cone Density Sand ASTM D 1556 (0.075-2.00 mm), gravel (>2mm) and native sediments) from each site for three months. We performed two laboratory tracer experiments using columns of each substrate under identical flow conditions. In the first experiment we added a short-term pulse of reactive and conservative tracers (i.e. NaNO3 and NaBr). In the second experiment we added a short-term pulse of NaBr and nutrients following Redfield's ratio (106C:16N:1P). We estimated uptake kinetics using the Tracer Additions for Spiraling Curve Characterization (TASCC) method and evaluated how ideal stoichiometric conditions controlled efficient nutrient retention along fluvial networks. Our results suggest that biological uptake of nitrate is limited by nitrogen in headwater streams and by phosphorus and carbon in larger stream orders.

  12. Rapid processing method for solution deposited YBa2Cu3O7-δ thin films

    International Nuclear Information System (INIS)

    Dawley, J.T.; Clem, P.G.; Boyle, T.J.; Ottley, L.M.; Overmyer, D.L.; Siegal, M.P.

    2004-01-01

    YBa 2 Cu 3 O 7-δ (YBCO) films, deposited on buffered metal substrates, are the primary candidate for second-generation superconducting (SC) wires, with applications including expanded power grid transmission capability, compact motors, and enhanced sensitivity magnetic resonance imaging. Feasibility of manufacturing such superconducting wires is dependent on high processing speed, often a limitation of vapor and solution-based YBCO deposition processes. In this work, YBCO films were fabricated via a new diethanolamine-modified trifluoroacetic film solution deposition method. Modifying the copper chemistry of the YBCO precursor solution with diethanolamine enables a hundredfold decrease in the organic pyrolysis time required for MA/cm 2 current density (J c ) YBCO films, from multiple hours to ∼20 s in atmospheric pressure air. High quality, ∼0.2 μm thick YBCO films with J c (77 K) values ≥2 MA/cm 2 at 77 K are routinely crystallized from these rapidly pyrolyzed films deposited on LaAlO 3 . This process has also enabled J c (77 K)=1.1 MA/cm 2 YBCO films via 90 m/h dip-coating on Oak Ridge National Laboratory RABiTS textured metal tape substrates. This new YBCO solution deposition method suggests a route toward inexpensive and commercializable ∼$10/kA m solution deposited YBCO coated conductor wires

  13. Comparison of deposited surface area of airborne ultrafine particles generated from two welding processes.

    Science.gov (United States)

    Gomes, J F; Albuquerque, P C; Miranda, Rosa M; Santos, Telmo G; Vieira, M T

    2012-09-01

    This article describes work performed on the assessment of the levels of airborne ultrafine particles emitted in two welding processes metal-active gas (MAG) of carbon steel and friction-stir welding (FSW) of aluminium in terms of deposited area in alveolar tract of the lung using a nanoparticle surface area monitor analyser. The obtained results showed the dependence from process parameters on emitted ultrafine particles and clearly demonstrated the presence of ultrafine particles, when compared with background levels. The obtained results showed that the process that results on the lower levels of alveolar-deposited surface area is FSW, unlike MAG. Nevertheless, all the tested processes resulted in important doses of ultrafine particles that are to be deposited in the human lung of exposed workers.

  14. Processing-structure-property relationships in electron beam physical vapor deposited yttria stabilized zirconia coatings

    International Nuclear Information System (INIS)

    Rao, D. Srinivasa; Valleti, Krishna; Joshi, S. V.; Janardhan, G. Ranga

    2011-01-01

    The physical and mechanical properties of yttria stabilized zirconia (YSZ) coatings deposited by the electron beam physical vapor deposition technique have been investigated by varying the key process variables such as vapor incidence angle and sample rotation speed. The tetragonal zirconia coatings formed under varying process conditions employed were found to have widely different surface and cross-sectional morphologies. The porosity, phase composition, planar orientation, hardness, adhesion, and surface residual stresses in the coated specimens were comprehensively evaluated to develop a correlation with the process variables. Under transverse scratch test conditions, the YSZ coatings exhibited two different crack formation modes, depending on the magnitude of residual stress. The influence of processing conditions on the coating deposition rate, column orientation angle, and adhesion strength has been established. Key relationships between porosity, hardness, and adhesion are also presented.

  15. Effect of Source, Surfactant, and Deposition Process on Electronic Properties of Nanotube Arrays

    Directory of Open Access Journals (Sweden)

    Dheeraj Jain

    2011-01-01

    Full Text Available The electronic properties of arrays of carbon nanotubes from several different sources differing in the manufacturing process used with a variety of average properties such as length, diameter, and chirality are studied. We used several common surfactants to disperse each of these nanotubes and then deposited them on Si wafers from their aqueous solutions using dielectrophoresis. Transport measurements were performed to compare and determine the effect of different surfactants, deposition processes, and synthesis processes on nanotubes synthesized using CVD, CoMoCAT, laser ablation, and HiPCO.

  16. Investigation of effect of process parameters on multilayer builds by direct metal deposition

    International Nuclear Information System (INIS)

    Amine, Tarak; Newkirk, Joseph W.; Liou, Frank

    2014-01-01

    Multilayer direct laser deposition (DLD) is a fabrication process through which parts are fabricated by creating a molten pool into which metal powder is injected as. During fabrication, complex thermal activity occurs in different regions of the build; for example, newly deposited layers will reheat previously deposited layers. The objective of this study was to provide insight into the thermal activity that occurs during the DLD process. This work focused on the effect of the deposition parameters of deposited layers on the microstructure and mechanical properties of the previously deposited layers. It is important to characterize these effects in order to provide information for proper parameter selection in future DLD fabrication. Varying the parameters was shown to produce different effects on the microstructure morphology and property values, presumably resulting from in-situ quench and tempering of the steels. In general, the microstructure was secondary dendrite arm spacing. Typically, both the travel speed and laser power significantly affect the microstructure and hardness. A commercial ABAQUS/CAE software was used to model this process by developing a thermo-mechanical 3D finite element model. This work presents a 3D heat transfer model that considers the continuous addition of mass in front of a moving laser beam using ABAQUS/CAE software. The model assumes the deposit geometry appropriate to each experimental condition and calculates the temperature distribution, cooling rates and re-melted layer depth, which can affect the final microstructure. Model simulations were qualitatively compared with experimental results acquired in situ using a K-type thermocouple. - Highlights: • Direct laser deposition DLD. • Microstructure of stainless steel 316L. • Thermocouples measurement. • 3D finite element modeling

  17. Evidence for substantial forestry canopy processing of nitrogen deposition using isotopic tracer experiments in low deposition conditions

    Science.gov (United States)

    Ferraretto, Daniele; Heal, Kate

    2017-04-01

    Temperate forest ecosystems are significant sinks for nitrogen deposition (Ndep) yielding benefits such as protection of waterbodies from eutrophication and enhanced sequestration of atmospheric CO2. Previous studies have shown evidence of biological nitrification and Ndep processing and retention in forest canopies. However, this was reported only at sites with high environmental or experimentally enhanced rates of Ndep (˜18 kg N ha-1 y-1) and has not yet been demonstrated in low Ndep environments. We have used bulk field hydrochemical measurements and labelled isotopic experiments to assess canopy processing in a lower Ndep environment (˜7 kg N ha-1 year-1) at a Sitka spruce plantation in Perthshire, Scotland, representing the dominant tree species (24%) in woodlands in Great Britain. Analysis of 4.5 years of measured N fluxes in rainfall (RF) and fogwater onto the canopy and throughfall (TF) and stemflow (SF) below the canopy suggests strong transformation and uptake of Ndep in the forest canopy. Annual canopy Ndep uptake was ˜4.7 kg N ha-1 year-1, representing 60-76% of annual Ndep. To validate these plot-scale results and track N uptake within the forest canopy in different seasons, double 15N-labelled NH4NO3 (98%) solution was sprayed in summer and winter onto the canopy of three trees at the measurement site. RF, TF and SF samples have been collected and analysed for 15NH4 and 15NO3. Comparing the amount of labelled N recovered under the sample trees with the measured δ15N signal is expected to provide further evidence of the role of forest canopies in actively processing and retaining atmospheric N deposition.

  18. Low-temperature processed ZnO and CdS photodetectors deposited by pulsed laser deposition

    International Nuclear Information System (INIS)

    Hernandez-Como, N; Moreno, S; Mejia, I; Quevedo-Lopez, M A

    2014-01-01

    UV-VIS photodetectors using an interdigital configuration, with zinc oxide (ZnO) and cadmium sulfide (CdS) semiconductors deposited by pulsed laser deposition, were fabricated with a maximum processing temperature of 100 °C. Without any further post-growth annealing, the photodetectors are compatible with flexible and transparent substrates. Aluminum (Al) and indium tin oxide (ITO) were investigated as contacts. Focusing on underwater communications, the impact of metal contact (ITO versus Al) was investigated to determine the maximum responsivity using a laser with a 405 nm wavelength. As expected, the responsivity increases for reduced metal finger separation. This is a consequence of reduced carrier transit time for shorter finger separation. For ITO, the highest responsivities for both films (ZnO and CdS) were ∼3 A W −1 at 5 V. On the other hand, for Al contacts, the maximum responsivities at 5 V were ∼0.1 A W −1 and 0.7 A W −1 for CdS and ZnO, respectively. (paper)

  19. Low-pressure c-BN deposition - is a CVD process possible?

    International Nuclear Information System (INIS)

    Haubner, R.; Tang, X.

    2001-01-01

    Since the low-pressure diamond deposition was discovered in 1982 there is a high interest to find a similar process for the c-BN synthesis. A review about the c-BN deposition process as well as its characterization is given. Experiments with a simple chemical vapor deposition(CVD) reactor using tris(dimethylamino)borane as precursor were carried out. In a cold-wall reactor substrates were heated up by high-frequency. Argon was used as protecting and carrying the precursor, it was saturated with tris(dimethylamino)borane (precursor) according to its vapor pressure and transports the pressure to the hot substrate, where deposition occurs. WC-Co hardmetal plates containing 6 wt. % Co, Mo and Si were used as substrates. Various BN layers were deposited and characterized. X-ray diffraction, IR-spectroscopy and SIMS indicate that BN-coatings containing c-BN were deposited. However a final verification of c-BN crystallites by TEM investigations was not possible till now. (nevyjel)

  20. Electron beam induced deposition of silacyclohexane and dichlorosilacyclohexane: the role of dissociative ionization and dissociative electron attachment in the deposition process

    Directory of Open Access Journals (Sweden)

    Ragesh Kumar T P

    2017-11-01

    Full Text Available We present first experiments on electron beam induced deposition of silacyclohexane (SCH and dichlorosilacyclohexane (DCSCH under a focused high-energy electron beam (FEBID. We compare the deposition dynamics observed when growing pillars of high aspect ratio from these compounds and we compare the proximity effect observed for these compounds. The two precursors show similar behaviour with regards to fragmentation through dissociative ionization in the gas phase under single-collision conditions. However, while DCSCH shows appreciable cross sections with regards to dissociative electron attachment, SCH is inert with respect to this process. We discuss our deposition experiments in context of the efficiency of these different electron-induced fragmentation processes. With regards to the deposition dynamics, we observe a substantially faster growth from DCSCH and a higher saturation diameter when growing pillars with high aspect ratio. However, both compounds show similar behaviour with regards to the proximity effect. With regards to the composition of the deposits, we observe that the C/Si ratio is similar for both compounds and in both cases close to the initial molecular stoichiometry. The oxygen content in the DCSCH deposits is about double that of the SCH deposits. Only marginal chlorine is observed in the deposits of from DCSCH. We discuss these observations in context of potential approaches for Si deposition.

  1. Pulsed laser deposition of the lysozyme protein: an unexpected “Inverse MAPLE” process

    DEFF Research Database (Denmark)

    Schou, Jørgen; Matei, Andreea; Constantinescu, Catalin

    2012-01-01

    Films of organic materials are commonly deposited by laser assisted methods, such as MAPLE (matrix-assisted pulsed laser evaporation), where a few percent of the film material in the target is protected by a light-absorbing volatile matrix. Another possibility is to irradiate the dry organic...... the ejection and deposition of lysozyme. This can be called an “inverse MAPLE” process, since the ratio of “matrix” to film material in the target is 10:90, which is inverse of the typical MAPLE process where the film material is dissolved in the matrix down to several wt.%. Lysozyme is a well-known protein...

  2. Characterization and Analysis of Ultrathin CIGS Films and Solar Cells Deposited by 3-Stage Process

    Directory of Open Access Journals (Sweden)

    Grace Rajan

    2018-01-01

    Full Text Available In view of the large-scale utilization of Cu(In,GaSe2 (CIGS solar cells for photovoltaic application, it is of interest not only to enhance the conversion efficiency but also to reduce the thickness of the CIGS absorber layer in order to reduce the cost and improve the solar cell manufacturing throughput. In situ and real-time spectroscopic ellipsometry (RTSE has been used conjointly with ex situ characterizations to understand the properties of ultrathin CIGS films. This enables monitoring the growth process, analyzing the optical properties of the CIGS films during deposition, and extracting composition, film thickness, grain size, and surface roughness which can be corroborated with ex situ measurements. The fabricated devices were characterized using current voltage and quantum efficiency measurements and modeled using a 1-dimensional solar cell device simulator. An analysis of the diode parameters indicates that the efficiency of the thinnest cells was restricted not only by limited light absorption, as expected, but also by a low fill factor and open-circuit voltage, explained by an increased series resistance, reverse saturation current, and diode quality factor, associated with an increased trap density.

  3. Investigation of the nucleation process of chemical vapour deposited diamond films

    International Nuclear Information System (INIS)

    Katai, S.

    2001-01-01

    The primary aim of this work was to contribute to the understanding of the bias enhanced nucleation (BEN) process during the chemical vapour deposition (CVD) of diamond on silicon. The investigation of both the gas phase environment above the substrate surface, by in situ mass selective energy analysis of ions, and of the surface composition and structure by in vacuo surface analytic methods (XPS, EELS) have been carried out. In both cases, the implementation of these measurements required the development and construction of special experimental apparatus as well. The secondary aim of this work was to give orientation to our long term goal of growing diamond films with improved quality. For this reason, (1) contaminant levels at the diamond-silicon interface after growth were studied by SIMS, (2) the internal stress distribution of highly oriented free-standing diamond films were studied by Raman spectroscopy, and (3) an attempt was made to produce spatially regular oriented nuclei formation by nucleating on a pattern created by laser treatment on silicon substrates. (orig.)

  4. Analysis of heating effect on the process of high deposition rate microcrystalline silicon

    International Nuclear Information System (INIS)

    Xiao-Dan, Zhang; He, Zhang; Chang-Chun, Wei; Jian, Sun; Guo-Fu, Hou; Shao-Zhen, Xiong; Xin-Hua, Geng; Ying, Zhao

    2010-01-01

    A possible heating effect on the process of high deposition rate microcrystalline silicon has been studied. It includes the discharge time-accumulating heating effect, discharge power, inter-electrode distance, and total gas flow rate induced heating effect. It is found that the heating effects mentioned above are in some ways quite similar to and in other ways very different from each other. However, all of them will directly or indirectly cause the increase of the substrate surface temperature during the process of depositing microcrystalline silicon thin films, which will affect the properties of the materials with increasing time. This phenomenon is very serious for the high deposition rate of microcrystalline silicon thin films because of the high input power and the relatively small inter-electrode distance needed. Through analysis of the heating effects occurring in the process of depositing microcrystalline silicon, it is proposed that the discharge power and the heating temperature should be as low as possible, and the total gas flow rate and the inter-electrode distance should be suitable so that device-grade high quality deposition rate microcrystalline silicon thin films can be fabricated

  5. Study of the fluidized bed chemical vapor deposition process on very dense powder for nuclear applications

    International Nuclear Information System (INIS)

    Vanni, Florence

    2015-01-01

    This thesis is part of the development of low-enriched nuclear fuel, for the Materials Test Reactors (MTRs), constituted of uranium-molybdenum particles mixed with an aluminum matrix. Under certain conditions under irradiations, the U(Mo) particles interact with the aluminum matrix, causing unacceptable swelling of the fuel plate. To inhibit this phenomenon, one solution consists in depositing on the surface of the U(Mo) particles, a thin silicon layer to create a barrier effect. This thesis has concerned the study of the fluidized bed chemical vapor deposition (CVD) process to deposit silicon from silane, on the U(Mo) powder, which has an exceptional density of 17,500 kg/m 3 . To achieve this goal, two axes were treated during the thesis: the study and the optimization of the fluidization of a so dense powder, and then those of the silicon deposition process. For the first axis, a series of tests was performed on a surrogate tungsten powder in different columns made of glass and made of steel with internal diameters ranging from 2 to 5 cm, at room temperature and at high temperature (650 C) close to that of the deposits. These experiments helped to identify wall effects phenomena within the fluidized bed, which can lead to heterogeneous deposits or particles agglomeration. Some dimensions of the fluidization columns and operating conditions allowing a satisfactory fluidization of the powder were identified, paving the way for the study of silicon deposition. Several campaigns of deposition experiments on the surrogate powder and then on the U(Mo) powder were carried out in the second axis of the study. The influence of the bed temperature, the inlet molar fraction of silane diluted in argon, and the total gas flow of fluidization, was examined for different diameters of reactor and for various masses of powder. Morphological and structural characterization analyses (SEM, XRD..) revealed a uniform silicon deposition on all the powder and around each particle

  6. Deposition and Resuspension of Particles

    DEFF Research Database (Denmark)

    Lengweiler, P.; Nielsen, Peter V.; Moser, A.

    A new experimental set-up to investigate the physical process of dust deposition and resuspension on and from surfaces is introduced. Dust deposition can reduce the airBorne dust concentration considerably. As a basis for developing methods to eliminate dust related problems in rooms......, there is a need for better understanding of the mechanism of dust deposition and resuspension....

  7. Modeling of thermal, electronic, hydrodynamic, and dynamic deposition processes for pulsed-laser deposition of thin films

    International Nuclear Information System (INIS)

    Liu, C.L.; LeBoeuf, J.N.; Wood, R.F.; Geohegan, D.B.; Donato, J.M.; Chen, K.R.; Puretzky, A.A.

    1994-11-01

    Various physical processes during laser ablation of solids for pulsed-laser deposition (PLD) are studied using a variety of computational techniques. In the course of the authors combined theoretical and experimental effort, they have been trying to work on as many aspects of PLD processes as possible, but with special focus on the following areas: (a) the effects of collisional interactions between the particles in the plume and in the background on the evolving flow field and on thin film growth, (b) interactions between the energetic particles and the growing thin films and their effects on film quality, (c) rapid phase transformations through the liquid and vapor phases under possibly nonequilibrium thermodynamic conditions induced by laser-solid interactions, (d) breakdown of the vapor into a plasma in the early stages of ablation through both electronic and photoionization processes, (c) hydrodynamic behavior of the vapor/plasma during and after ablation. The computational techniques used include finite difference (FD) methods, particle-in-cell model, and atomistic simulations using molecular dynamics (MD) techniques

  8. Fluid expulsion sites on the Cascadia accretionary prism: mapping diagenetic deposits with processed GLORIA imagery

    Science.gov (United States)

    Carson, Bobb; Seke, Erol; Paskevich, Valerie F.; Holmes, Mark L.

    1994-01-01

    Point-discharge fluid expulsion on accretionary prisms is commonly indicated by diagenetic deposition of calcium carbonate cements and gas hydrates in near-surface (topographic and lithologic information. We have processed GLORIA imagery from the Oregon continental margin to remove topographic effects. A synthetic side scan image was created initially from Sea Beam bathymetric data and then was subtracted iteratively from the original GLORIA data until topographic features disappeared. The residual image contains high-amplitude backscattering that we attribute to diagenetic deposits associated with fluid discharge, based on submersible mapping, Ocean Drilling Program drilling, and collected samples. Diagenetic deposits are concentrated (1) near an out-of-sequence thrust fault on the second ridge landward of the base of the continental slope, (2) along zones characterized by deep-seated strikeslip faults that cut transversely across the margin, and (3) in undeformed Cascadia Basin deposits which overlie incipient thrust faults seaward of the toe of the prism. There is no evidence of diagenetic deposition associated with the frontal thrust that rises from the dècollement. If the dècollement is an important aquifer, apparently the fluids are passed either to the strike-slip faults which intersect the dècollement or to the incipient faults in Cascadia Basin for expulsion. Diagenetic deposits seaward of the prism toe probably consist dominantly of gas hydrates.

  9. A discrete element based simulation framework to investigate particulate spray deposition processes

    KAUST Repository

    Mukherjee, Debanjan

    2015-06-01

    © 2015 Elsevier Inc. This work presents a computer simulation framework based on discrete element method to analyze manufacturing processes that comprise a loosely flowing stream of particles in a carrier fluid being deposited on a target surface. The individual particulate dynamics under the combined action of particle collisions, fluid-particle interactions, particle-surface contact and adhesive interactions is simulated, and aggregated to obtain global system behavior. A model for deposition which incorporates the effect of surface energy, impact velocity and particle size, is developed. The fluid-particle interaction is modeled using appropriate spray nozzle gas velocity distributions and a one-way coupling between the phases. It is found that the particle response times and the release velocity distribution of particles have a combined effect on inter-particle collisions during the flow along the spray. It is also found that resolution of the particulate collisions close to the target surface plays an important role in characterizing the trends in the deposit pattern. Analysis of the deposit pattern using metrics defined from the particle distribution on the target surface is provided to characterize the deposition efficiency, deposit size, and scatter due to collisions.

  10. Deposition behavior of colloid in filtration process through glass beads packed bed

    International Nuclear Information System (INIS)

    Chinju, Hirofumi; Nagasaki, Shinya; Tanaka, Satoru; Tanaka, Tadao; Takebe, Shinichi; Ogawa, Hiromichi

    1999-01-01

    We investigated the deposition behavior in colloid transport through porous media by conducting column experiments and batch experiments using polystyrene latex particles and spherical glass beads. The conclusion of this present work are summarized as follows: (1) The comparison between the results of the batch and the column experiments indicated that the deposition was enhanced in the column experiments compared with the batch experiments due to particles trapped by the effect of slow field. (2) Colloid BTCs showed three different stages of deposition which can be characterized by the different rate of the change in the C/C O . Three stages can be explained by the existence of large area of weak deposition sites and small area of strong deposition sites on the collector surfaces. (3) The amount of deposited particles until the beginning of the third stage was larger for lower flow velocity. (4) The results of the column experiments revealed that breakthrough behavior of colloidal particles of the second run after back wash process is affected by remaining particles on collector surfaces. (J.P.N.)

  11. Effects of vacuum processing erbium dideuteride/ditritide films deposited on chromium underlays on copper substrates

    International Nuclear Information System (INIS)

    Provo, J.L.

    1978-01-01

    Thin films of erbium dideuteride/ditritide were experimentally produced on chromium underlays deposited on copper substrates. The chromium underlay is required to prevent erbium occluder/copper substrate alloying which inhibits hydriding. Data taken has shown that vacuum processing affects the erbium/chromium/copper interaction. With an in situ process in which underlay/occluder films are vacuum deposited onto copper substrates and hydrided with no air exposure between these steps, data indicates a minimum of 1500A of chromium is required for optimum hydriding. If films are vacuum deposited as above and air-exposed before hydriding, a minimum of 3000A of chromium was shown to be required for equivalent hydriding. Data suggests that the activation step (600 0 C for 1 hour) required for hydriding the film of the second type is responsible for the difference observed. Such underlay thickness parameters are important, with regard to heat transfer considerations in thin hydride targets used for neutron generation

  12. The study on microb and organic metallogenetic process of the interlayer oxidized zone uranium deposit. A case study of the Shihongtan uranium deposit in Turpan-Hami basin

    International Nuclear Information System (INIS)

    Qiao Haiming; Shang Gaofeng

    2010-01-01

    Microbial and organic process internationally leads the field in the study of metallogenetic process presently. Focusing on Shi Hongtan uranium deposit, a typical interlayer oxidized zone sandstone-type deposit, this paper analyzes the geochemical characteristics of microb and organic matter in the deposit, and explores the interaction of microb and organic matter. It considers that the anaerobic bacterium actively takes part in the formation of the interlayer oxidized zone, as well as the mobilization and migration of uranium. In the redox (oxidation-reduction) transition zone, sulphate-reducing bacteria reduced sulphate to stink damp, lowing Eh and acidifying pH in the groundwater, which leads to reducing and absorbing of uranium, by using light hydrocarbon which is the product of the biochemical process of organism and the soluble organic matter as the source of carbon. The interaction of microb and organic matter controls the metallogenetic process of uranium in the deposit. (authors)

  13. The erosion performance of cold spray deposited metal matrix composite coatings with subsequent friction stir processing

    Energy Technology Data Exchange (ETDEWEB)

    Peat, Tom, E-mail: tompeat12@gmail.com [Department of Mechanical & Aerospace Engineering, University of Strathclyde, James Weir Building, 75 Montrose Street, Glasgow G1 1XJ (United Kingdom); Galloway, Alexander; Toumpis, Athanasios [Department of Mechanical & Aerospace Engineering, University of Strathclyde, James Weir Building, 75 Montrose Street, Glasgow G1 1XJ (United Kingdom); McNutt, Philip [TWI Ltd., Granta Park, Cambridge CB21 6AL (United Kingdom); Iqbal, Naveed [TWI Technology Centre, Wallis Way, Catcliff, Rotherham, S60 5TZ (United Kingdom)

    2017-02-28

    Highlights: • WC-CoCr, Cr{sub 3}C{sub 2}-NiCr and Al{sub 2}O{sub 3} coatings were cold spray deposited on AA5083 and friction stir processed. • The SprayStirred WC-CoCr demonstrated a hardness increase of 100% over the cold sprayed coating. • As-deposited and SprayStirred coatings were examined under slurry erosion test conditions. • Mass and volume loss was measured following 20-min exposure to the slurry. • The WC-CoCr and Al2O3 demonstrated a reduction in volume loss of approx. 40% over the cold sprayed coating. - Abstract: This study forms an initial investigation into the development of SprayStir, an innovative processing technique for generating erosion resistant surface layers on a chosen substrate material. Tungsten carbide – cobalt chromium, chromium carbide – nickel chromium and aluminium oxide coatings were successfully cold spray deposited on AA5083 grade aluminium. In order to improve the deposition efficiency of the cold spray process, coatings were co-deposited with powdered AA5083 using a twin powder feed system that resulted in thick (>300 μm) composite coatings. The deposited coatings were subsequently friction stir processed to embed the particles in the substrate in order to generate a metal matrix composite (MMC) surface layer. The primary aim of this investigation was to examine the erosion performance of the SprayStirred surfaces and demonstrate the benefits of this novel process as a surface engineering technique. Volumetric analysis of the SprayStirred surfaces highlighted a drop of approx. 40% in the level of material loss when compared with the cold spray deposited coating prior to friction stir processing. Micro-hardness testing revealed that in the case of WC-CoCr reinforced coating, the hardness of the SprayStirred material exhibits an increase of approx. 540% over the unaltered substrate and 120% over the as-deposited composite coating. Microstructural examination demonstrated that the increase in the hardness of the

  14. Superhydrophobic nanostructured ZnO thin films on aluminum alloy substrates by electrophoretic deposition process

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Ying; Sarkar, D.K., E-mail: dsarkar@uqac.ca; Chen, X-Grant

    2015-02-01

    Graphical abstract: - Highlights: • Fabrication of superhydrophobic ZnO thin films surfaces by electrophoretic deposition process on aluminum substrates. • Effect of bath temperature on the physical and superhydrophobic properties of thin films. • The water contact angle of 155° ± 3 with roll off property has been observed on the film that was grown at bath temperatures of 50 °C. • The activation energy for electrophoretic deposition of SA-functionalized ZnO nanoparticle is calculated to be 0.50 eV. - Abstract: Superhydrophobic thin films have been fabricated on aluminum alloy substrates by electrophoretic deposition (EPD) process using stearic acid (SA) functionalized zinc oxide (ZnO) nanoparticles suspension in alcohols at varying bath temperatures. The deposited thin films have been characterized using both X-ray diffraction (XRD) and infrared (IR) spectroscopy and it is found that the films contain low surface energy zinc stearate and ZnO nanoparticles. It is also observed that the atomic percentage of Zn and O, roughness and water contact angle of the thin films increase with the increase of the deposited bath temperature. Furthermore, the thin film deposited at 50 °C, having a roughness of 4.54 ± 0.23 μm, shows superhydrophobic properties providing a water contact angle of 155 ± 3° with rolling off properties. Also, the activation energy of electrophoretic deposition of stearic-acid-functionalized ZnO nanoparticles is calculated to be 0.5 eV.

  15. Solution processed deposition of electron transport layers on perovskite crystal surface—A modeling based study

    Energy Technology Data Exchange (ETDEWEB)

    Mortuza, S.M.; Taufique, M.F.N.; Banerjee, Soumik, E-mail: soumik.banerjee@wsu.edu

    2017-02-01

    Highlights: • The model determined the surface coverage of solution-processed film on perovskite. • Calculated surface density map provides insight into morphology of the monolayer. • Carbonyl oxygen atom of PCBM strongly attaches to the (110) surface of perovskite. • Uniform distribution of clusters on perovskite surface at lower PCBM concentration. • Deposition rate of PCBM on the surface is very high at initial stage of film growth. - Abstract: The power conversion efficiency (PCE) of planar perovskite solar cells (PSCs) has reached up to ∼20%. However, structural and chemicals defects that lead to hysteresis in the perovskite based thin film pose challenges. Recent work has shown that thin films of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) deposited on the photo absorption layer, using solution processing techniques, minimize surface pin holes and defects thereby increasing the PCE. We developed and employed a multiscale model based on molecular dynamics (MD) and kinetic Monte Carlo (kMC) to establish a relationship between deposition rate and surface coverage on perovskite surface. The MD simulations of PCBMs dispersed in chlorobenzene, sandwiched between (110) perovskite substrates, indicate that PCBMs are deposited through anchoring of the oxygen atom of carbonyl group to the exposed lead (Pb) atom of (110) perovskite surface. Based on rates of distinct deposition events calculated from MD, kMC simulations were run to determine surface coverage at much larger time and length scales than accessible by MD alone. Based on the model, a generic relationship is established between deposition rate of PCBMs and surface coverage on perovskite crystal. The study also provides detailed insights into the morphology of the deposited film.

  16. Evaluation of Mineral Deposits Along the Little Wind River, Riverton, WY, Processing Site

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, Sam [Navarro Research and Engineering, Oak Ridge, TN (United States); Dam, Wiliam [US Department of Energy, Washington, DC (United States). Office of Legacy Management

    2014-12-01

    In 2012, the U.S.Department of Energy (DOE) began reassessing the former Riverton, Wyoming, Processing Site area for potential contaminant sources impacting groundwater. A flood in 2010 along the Little Wind River resulted in increases in groundwater contamination (DOE 2013).This investigation is a small part of continued efforts by DOE and other stakeholders to update human health and ecological risk assessments, to make a comprehensive examination of all exposure pathways to ensure that the site remains protective through established institutional controls. During field inspections at the Riverton Site in 2013, a white evaporitic mineral deposit was identified along the bank of the Little Wind River within the discharge zone of the groundwater contamination plume. In December 2013, Savannah River National Laboratory (SRNL) personnel collected a sample for analysis by X-ray fluorescence (Figure 1 shows the type of material sampled). The sample had a uranium concentration of approximately 64 to 73 parts per million. Although the uranium in this mineral deposit is within the expected range for evaporatic minerals in the western United States (SRNL 2014), DOE determined that additional assessment of the mineral deposit was warranted. In response to the initial collection and analysis of a sample of the mineral deposit, DOE developed a work plan (Work Plan to Sample Mineral Deposits Along the Little Wind River, Riverton, Wyoming, Processing Site [DOE 2014]) to further define the extent of these mineral deposits and the concentration of the associated contaminants (Appendix A). The work plan addressed field reconnaissance, mapping, sampling, and the assessment of risk associated with the mineral deposits adjacent to the Little Wind River.

  17. Solution processed deposition of electron transport layers on perovskite crystal surface—A modeling based study

    International Nuclear Information System (INIS)

    Mortuza, S.M.; Taufique, M.F.N.; Banerjee, Soumik

    2017-01-01

    Highlights: • The model determined the surface coverage of solution-processed film on perovskite. • Calculated surface density map provides insight into morphology of the monolayer. • Carbonyl oxygen atom of PCBM strongly attaches to the (110) surface of perovskite. • Uniform distribution of clusters on perovskite surface at lower PCBM concentration. • Deposition rate of PCBM on the surface is very high at initial stage of film growth. - Abstract: The power conversion efficiency (PCE) of planar perovskite solar cells (PSCs) has reached up to ∼20%. However, structural and chemicals defects that lead to hysteresis in the perovskite based thin film pose challenges. Recent work has shown that thin films of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) deposited on the photo absorption layer, using solution processing techniques, minimize surface pin holes and defects thereby increasing the PCE. We developed and employed a multiscale model based on molecular dynamics (MD) and kinetic Monte Carlo (kMC) to establish a relationship between deposition rate and surface coverage on perovskite surface. The MD simulations of PCBMs dispersed in chlorobenzene, sandwiched between (110) perovskite substrates, indicate that PCBMs are deposited through anchoring of the oxygen atom of carbonyl group to the exposed lead (Pb) atom of (110) perovskite surface. Based on rates of distinct deposition events calculated from MD, kMC simulations were run to determine surface coverage at much larger time and length scales than accessible by MD alone. Based on the model, a generic relationship is established between deposition rate of PCBMs and surface coverage on perovskite crystal. The study also provides detailed insights into the morphology of the deposited film.

  18. Self-catalytic growth of tin oxide nanowires by chemical vapor deposition process

    CSIR Research Space (South Africa)

    Thabethe, BS

    2013-01-01

    Full Text Available The authors report on the synthesis of tin oxide (SnO(sub2)) nanowires by a chemical vapor deposition (CVD) process. Commercially bought SnO nanopowders were vaporized at 1050°C for 30 minutes with argon gas continuously passing through the system...

  19. Optimization of Nano-Process Deposition Parameters Based on Gravitational Search Algorithm

    Directory of Open Access Journals (Sweden)

    Norlina Mohd Sabri

    2016-06-01

    Full Text Available This research is focusing on the radio frequency (RF magnetron sputtering process, a physical vapor deposition technique which is widely used in thin film production. This process requires the optimized combination of deposition parameters in order to obtain the desirable thin film. The conventional method in the optimization of the deposition parameters had been reported to be costly and time consuming due to its trial and error nature. Thus, gravitational search algorithm (GSA technique had been proposed to solve this nano-process parameters optimization problem. In this research, the optimized parameter combination was expected to produce the desirable electrical and optical properties of the thin film. The performance of GSA in this research was compared with that of Particle Swarm Optimization (PSO, Genetic Algorithm (GA, Artificial Immune System (AIS and Ant Colony Optimization (ACO. Based on the overall results, the GSA optimized parameter combination had generated the best electrical and an acceptable optical properties of thin film compared to the others. This computational experiment is expected to overcome the problem of having to conduct repetitive laboratory experiments in obtaining the most optimized parameter combination. Based on this initial experiment, the adaptation of GSA into this problem could offer a more efficient and productive way of depositing quality thin film in the fabrication process.

  20. Plasma processes and film growth of expanding thermal plasma deposited textured zinc oxide

    NARCIS (Netherlands)

    Groenen, R.; Linden, J.L.; Sanden, van de M.C.M.

    2005-01-01

    Plasma processes and film growth of textured zinc oxide deposited from oxygen and diethyl zinc utilizing expanding thermal argon plasma created by a cascaded arc is discussed. In all conditions explored, an excess of argon ions and low temperature electrons is available, which represent the

  1. Reduced thermal budget processing of Y-Ba-Cu-O films by rapid isothermal processing assisted metalorganic chemical vapor deposition

    International Nuclear Information System (INIS)

    Singh, R.; Sinha, S.; Hsu, N.J.; Ng, J.T.C.; Chou, P.; Thakur, R.P.S.; Narayan, J.

    1991-01-01

    Metalorganic chemical vapor deposition (MOCVD) has the potential of emerging as a viable technique to fabricate ribbons, tapes, coated wires, and the deposition of films of high-temperature superconductors, and related materials. As a reduced thermal budget processing technique, rapid isothermal processing (RIP) based on incoherent radiation as the source of energy can be usefully coupled to conventional MOCVD. In this paper we report on the deposition and characterization of high quality superconducting thin films of Y-Ba-Cu-O (YBCO) on yttrium stabilized zirconia substrates by RIP assisted MOCVD. Using O 2 gas as the source of oxygen, YBCO films deposited initially at 600 degree C for 1 min and at 745 degree C for 25 min followed by deposition at 780 degree C for 45 s are primarily c-axis oriented and zero resistance is observed at 89--90 K. The zero magnetic field current density at 53 and 77 K are 1.2x10 6 and 3x10 5 A/cm 2 , respectively. By using a mixture of N 2 O and O 2 as the oxygen source substrate temperature was further reduced in the deposition of YBCO films. The films deposited initially at 600 degree C for 1 min and than at 720 degree C for 30 min are c-axis oriented and with zero resistance being observed at 91 K. The zero magnetic field current densities at 53 and 77 K are 3.4x10 6 and 1.2x10 6 A/cm 2 , respectively. To the best of our knowledge this is the highest value of critical current density, J c for films deposited by MOCVD at a substrate temperature as low as 720 degree C. It is envisioned that high energy photons from the incoherent light source and the use of a mixture of N 2 O and O 2 as the oxygen source, assist chemical reactions and lower overall thermal budget for processing of these films

  2. Ion - beam assisted process in the physical deposition of organic thin layers

    Energy Technology Data Exchange (ETDEWEB)

    Dimov, D; Spassova, E; Assa, J; Danev, G [Acad. J .Malinowski Central Laboratory of Photoprocesses, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Bl.109, 1113 Sofia (Bulgaria); Georgiev, A, E-mail: dean@clf.bas.b [University of Chemical Technology and Metallurgy, 8 Kl. Ohridski Blvd., 1756 Sofia (Bulgaria)

    2010-04-01

    A novel method was developed for physical deposition of thin polyimide layers by applying an argon plasma assisted process. The influence was investigated of the plasma on the combined molecular flux of the two thermally evaporated precursors - oxydianiline and pyromellitic dianhydride. The effects observed on the properties of the deposited films are explained with the increased energy of the precursor molecules resulting from the ion-molecular collisions. As could be expected, molecules with higher energy possess higher mobility and thus determine the modification of the films structure and their electrical properties.

  3. Thermokinetic Modeling of Phase Transformation in the Laser Powder Deposition Process

    Science.gov (United States)

    Foroozmehr, Ehsan; Kovacevic, Radovan

    2009-08-01

    A finite element model coupled with a thermokinetic model is developed to predict the phase transformation of the laser deposition of AISI 4140 on a substrate with the same material. Four different deposition patterns, long-bead, short-bead, spiral-in, and spiral-out, are used to cover a similar area. Using a finite element model, the temperature history of the laser powder deposition (LPD) process is determined. The martensite transformation as well as martensite tempering is considered to calculate the final fraction of martensite, ferrite, cementite, ɛ-carbide, and retained austenite. Comparing the surface hardness topography of different patterns reveals that path planning is a critical parameter in laser surface modification. The predicted results are in a close agreement with the experimental results.

  4. Effect of Processing Parameters on Performance of Spray-Deposited Organic Thin-Film Transistors

    Directory of Open Access Journals (Sweden)

    Jack W. Owen

    2011-01-01

    Full Text Available The performance of organic thin-film transistors (OTFTs is often strongly dependent on the fabrication procedure. In this study, we fabricate OTFTs of soluble small-molecule organic semiconductors by spray-deposition and explore the effect of processing parameters on film morphology and device mobility. In particular, we report on the effect of the nature of solvent, the pressure of the carrier gas used in deposition, and the spraying distance. We investigate the surface morphology using scanning force microscopy and show that the molecules pack along the π-stacking direction, which is the preferred charge transport direction. Our results demonstrate that we can tune the field-effect mobility of spray-deposited devices two orders of magnitude, from 10−3 cm2/Vs to 10−1 cm2/Vs, by controlling fabrication parameters.

  5. Understanding human visual processing with Deep Neural Networks

    OpenAIRE

    Thorat, Sushrut

    2016-01-01

    This presentation has 2 parts:1. An introduction to the vision processing - neuroscience, and machine vision.2. Discussion of one of the first papers relating Deep Networks to the visual ventral stream. (Khaligh-Razavi, 2014)

  6. Using Ancient DNA to Understand Evolutionary and Ecological Processes

    DEFF Research Database (Denmark)

    Orlando, Ludovic Antoine Alexandre; Cooper, Alan

    2014-01-01

    Ancient DNA provides a unique means to record genetic change through time and directly observe evolutionary and ecological processes. Although mostly based on mitochondrial DNA, the increasing availability of genomic sequences is leading to unprecedented levels of resolution. Temporal studies of ...

  7. Understanding the Process of Radicalization: Review of the Empirical Literature

    Science.gov (United States)

    2011-03-01

    war, and for violent solutions to conflict. However, the authors contend that TMT does not predict such antagonistic reactions as certain. Instead...advocates that individuals “ ruminate about social exclusion, and this preoccupation with their inner thoughts, distracts them from processing incoming

  8. Towards understanding and managing the learning process in mail sorting.

    Science.gov (United States)

    Berglund, M; Karltun, A

    2012-01-01

    This paper was based on case study research at the Swedish Mail Service Division and it addresses learning time to sort mail at new districts and means to support the learning process on an individual as well as organizational level. The study population consisted of 46 postmen and one team leader in the Swedish Mail Service Division. Data were collected through measurements of time for mail sorting, interviews and a focus group. The study showed that learning to sort mail was a much more complex process and took more time than expected by management. Means to support the learning process included clarification of the relationship between sorting and the topology of the district, a good work environment, increased support from colleagues and management, and a thorough introduction for new postmen. The identified means to support the learning process require an integration of human, technological and organizational aspects. The study further showed that increased operations flexibility cannot be reinforced without a systems perspective and thorough knowledge about real work activities and that ergonomists can aid businesses to acquire this knowledge.

  9. Understanding the selection processes of public research projects

    NARCIS (Netherlands)

    Materia, V.C.; Pascucci, S.; Kolympiris, C.

    2015-01-01

    This paper analyses factors that affect the funding of agricultural research projects by regional governments and other regional public authorities. We study the selection process of agricultural research projects funded by the emilia Romagna regional government in Italy, which follows funding

  10. Satisfaction Formation Processes in Library Users: Understanding Multisource Effects

    Science.gov (United States)

    Shi, Xi; Holahan, Patricia J.; Jurkat, M. Peter

    2004-01-01

    This study explores whether disconfirmation theory can explain satisfaction formation processes in library users. Both library users' needs and expectations are investigated as disconfirmation standards. Overall library user satisfaction is predicted to be a function of two independent sources--satisfaction with the information product received…

  11. Understanding the cognitive processes involved in writing to learn.

    Science.gov (United States)

    Arnold, Kathleen M; Umanath, Sharda; Thio, Kara; Reilly, Walter B; McDaniel, Mark A; Marsh, Elizabeth J

    2017-06-01

    Writing is often used as a tool for learning. However, empirical support for the benefits of writing-to-learn is mixed, likely because the literature conflates diverse activities (e.g., summaries, term papers) under the single umbrella of writing-to-learn. Following recent trends in the writing-to-learn literature, the authors focus on the underlying cognitive processes. They draw on the largely independent writing-to-learn and cognitive psychology learning literatures to identify important cognitive processes. The current experiment examines learning from 3 writing tasks (and 1 nonwriting control), with an emphasis on whether or not the tasks engaged retrieval. Tasks that engaged retrieval (essay writing and free recall) led to better final test performance than those that did not (note taking and highlighting). Individual differences in structure building (the ability to construct mental representations of narratives; Gernsbacher, Varner, & Faust, 1990) modified this effect; skilled structure builders benefited more from essay writing and free recall than did less skilled structure builders. Further, more essay-like responses led to better performance, implicating the importance of additional cognitive processes such as reorganization and elaboration. The results highlight how both task instructions and individual differences affect the cognitive processes involved when writing-to-learn, with consequences for the effectiveness of the learning strategy. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

  12. Influence of radioactive contamination to agricultural products due to dry and wet deposition processes during a nuclear emergency

    International Nuclear Information System (INIS)

    Hwang, Won Tae; Kim, Eun Han; Suh, Kyung Suk; Han, Moon Hee; Choi, Yong Ho; Lee, Chang Woo

    2002-01-01

    Combined with deposition model onto the ground of radionuclides, the influence of radioactive contamination to agricultural products was analyzed due to wet deposition as well as dry deposition from radioactive air concentration during a nuclear emergency. The previous dynamic food chain model, in which initial input parameter is only radionuclide concentrations on the ground, was improved for the evaluating of radioactive contamination to agricultural products from either radionuclide concentrations in air or radionuclide concentrations on the ground. As the results, in case of deposition onto the ground, wet deposition was more dominant process than dry deposition. While the contamination levels of agricultural products were dependent on the a variety of factors such as radionuclides and rainfall rate. It means that the contamination levels of agricultural products are determined from which is more dominant process between deposition on the ground and interception onto agricultural plants

  13. Applying a new understanding of supergene REE deposit formation to global exploration initiatives for environmentally sustainable resources

    Science.gov (United States)

    Hardy, Liam; Smith, Martin; Hood, Leo; Heller, Shaun; Faltyn, Rowan; Blum, Astrid; Bamberger, Axel

    2017-04-01

    ). Rare earth elements: A review of production, processing, recycling and associated environmental issues; EPA600/R-12/572. United States Environmental Protection Agency. Hardy, L. (2016). A novel mechanism for the formation of REE ion-adsorption deposits. Presented to: MDSG Winter Meeting, Bristol University, 20/12/16. Jenkins, R. (1979). The Road to Alto: An account of peasants, capitalists and their soil in the mountains of Southern Portugal. London: Pluto, ISBN: 0861040767. Marquis, E. (2016). Ion Adsorption-Type REE Deposit associated with the Ambohimirahavavy Alkaline Complex: Potential Controls on Mineralisation. Presented to: MDSG Winter Meeting, Bristol University, 20/12/16.

  14. How does crowdfunding work? Understanding the process through its activity

    OpenAIRE

    Stiver, Alexandra

    2016-01-01

    Crowdfunding is a process featuring incremental financial donations from a ‘crowd’ of backers to help fund a project initiated by a creator. In recent years, crowdfunding has generated significant revenue as well as great interest from industry, government, and creative entrepreneurs. However, rate of successful funding for crowdfunding projects remains around 35% for global crowdfunding leader Kickstarter1, and lower yet for other platforms.\\ud \\ud The identified gap between crowdfunding gro...

  15. Modeling Dynamic Food Choice Processes to Understand Dietary Intervention Effects.

    Science.gov (United States)

    Marcum, Christopher Steven; Goldring, Megan R; McBride, Colleen M; Persky, Susan

    2018-02-17

    Meal construction is largely governed by nonconscious and habit-based processes that can be represented as a collection of in dividual, micro-level food choices that eventually give rise to a final plate. Despite this, dietary behavior intervention research rarely captures these micro-level food choice processes, instead measuring outcomes at aggregated levels. This is due in part to a dearth of analytic techniques to model these dynamic time-series events. The current article addresses this limitation by applying a generalization of the relational event framework to model micro-level food choice behavior following an educational intervention. Relational event modeling was used to model the food choices that 221 mothers made for their child following receipt of an information-based intervention. Participants were randomized to receive either (a) control information; (b) childhood obesity risk information; (c) childhood obesity risk information plus a personalized family history-based risk estimate for their child. Participants then made food choices for their child in a virtual reality-based food buffet simulation. Micro-level aspects of the built environment, such as the ordering of each food in the buffet, were influential. Other dynamic processes such as choice inertia also influenced food selection. Among participants receiving the strongest intervention condition, choice inertia decreased and the overall rate of food selection increased. Modeling food selection processes can elucidate the points at which interventions exert their influence. Researchers can leverage these findings to gain insight into nonconscious and uncontrollable aspects of food selection that influence dietary outcomes, which can ultimately improve the design of dietary interventions.

  16. Understanding Social Contagion in Adoption Processes Using Dynamic Social Networks.

    Science.gov (United States)

    Herrera, Mauricio; Armelini, Guillermo; Salvaj, Erica

    2015-01-01

    There are many studies in the marketing and diffusion literature of the conditions in which social contagion affects adoption processes. Yet most of these studies assume that social interactions do not change over time, even though actors in social networks exhibit different likelihoods of being influenced across the diffusion period. Rooted in physics and epidemiology theories, this study proposes a Susceptible Infectious Susceptible (SIS) model to assess the role of social contagion in adoption processes, which takes changes in social dynamics over time into account. To study the adoption over a span of ten years, the authors used detailed data sets from a community of consumers and determined the importance of social contagion, as well as how the interplay of social and non-social influences from outside the community drives adoption processes. Although social contagion matters for diffusion, it is less relevant in shaping adoption when the study also includes social dynamics among members of the community. This finding is relevant for managers and entrepreneurs who trust in word-of-mouth marketing campaigns whose effect may be overestimated if marketers fail to acknowledge variations in social interactions.

  17. Understanding Social Contagion in Adoption Processes Using Dynamic Social Networks.

    Directory of Open Access Journals (Sweden)

    Mauricio Herrera

    Full Text Available There are many studies in the marketing and diffusion literature of the conditions in which social contagion affects adoption processes. Yet most of these studies assume that social interactions do not change over time, even though actors in social networks exhibit different likelihoods of being influenced across the diffusion period. Rooted in physics and epidemiology theories, this study proposes a Susceptible Infectious Susceptible (SIS model to assess the role of social contagion in adoption processes, which takes changes in social dynamics over time into account. To study the adoption over a span of ten years, the authors used detailed data sets from a community of consumers and determined the importance of social contagion, as well as how the interplay of social and non-social influences from outside the community drives adoption processes. Although social contagion matters for diffusion, it is less relevant in shaping adoption when the study also includes social dynamics among members of the community. This finding is relevant for managers and entrepreneurs who trust in word-of-mouth marketing campaigns whose effect may be overestimated if marketers fail to acknowledge variations in social interactions.

  18. Understanding Social Contagion in Adoption Processes Using Dynamic Social Networks

    Science.gov (United States)

    2015-01-01

    There are many studies in the marketing and diffusion literature of the conditions in which social contagion affects adoption processes. Yet most of these studies assume that social interactions do not change over time, even though actors in social networks exhibit different likelihoods of being influenced across the diffusion period. Rooted in physics and epidemiology theories, this study proposes a Susceptible Infectious Susceptible (SIS) model to assess the role of social contagion in adoption processes, which takes changes in social dynamics over time into account. To study the adoption over a span of ten years, the authors used detailed data sets from a community of consumers and determined the importance of social contagion, as well as how the interplay of social and non-social influences from outside the community drives adoption processes. Although social contagion matters for diffusion, it is less relevant in shaping adoption when the study also includes social dynamics among members of the community. This finding is relevant for managers and entrepreneurs who trust in word-of-mouth marketing campaigns whose effect may be overestimated if marketers fail to acknowledge variations in social interactions. PMID:26505473

  19. An Experimental Study on Slurry Erosion Resistance of Single and Multilayered Deposits of Ni-WC Produced by Laser-Based Powder Deposition Process

    Science.gov (United States)

    Balu, Prabu; Hamid, Syed; Kovacevic, Radovan

    2013-11-01

    Single and multilayered deposits containing different mass fractions of tungsten carbide (WC) in nickel (Ni)-matrix (NT-20, NT-60, NT-80) are deposited on a AISI 4140 steel substrate using a laser-based powder deposition process. The transverse cross section of the coupons reveals that the higher the mass fraction of WC in Ni-matrix leads to a more uniform distribution through Ni-matrix. The slurry erosion resistance of the fabricated coupons is tested at three different impingement angles using an abrasive water jet cutting machine, which is quantified based on the erosion rate. The top layer of a multilayered deposit (i.e., NT-60 in a two-layer NT-60 over NT-20 deposit) exhibits better erosion resistance at all three tested impingement angles when compared to a single-layer (NT-60) deposit. A definite increase in the erosion resistance is noted with an addition of nano-size WC particles. The relationship between the different mass fractions of reinforcement (WC) in the deposited composite material (Ni-WC) and their corresponding matrix (Ni) hardness on the erosion rate is studied. The eroded surface is analyzed in the light of a three-dimensional (3-D) profilometer and a scanning electron microscope (SEM). The results show that a volume fraction of approximately 62% of WC with a Ni-matrix hardness of 540 HV resulting in the gouging out of WC from the Ni-matrix by the action of slurry. It is concluded that the slurry erosion resistance of the AISI 4140 steel can be significantly enhanced by introducing single and multilayered deposits of Ni-WC composite material fabricated by the laser-based powder deposition process.

  20. Understanding movement data and movement processes: current and emerging directions.

    Science.gov (United States)

    Schick, Robert S; Loarie, Scott R; Colchero, Fernando; Best, Benjamin D; Boustany, Andre; Conde, Dalia A; Halpin, Patrick N; Joppa, Lucas N; McClellan, Catherine M; Clark, James S

    2008-12-01

    Animal movement has been the focus on much theoretical and empirical work in ecology over the last 25 years. By studying the causes and consequences of individual movement, ecologists have gained greater insight into the behavior of individuals and the spatial dynamics of populations at increasingly higher levels of organization. In particular, ecologists have focused on the interaction between individuals and their environment in an effort to understand future impacts from habitat loss and climate change. Tools to examine this interaction have included: fractal analysis, first passage time, Lévy flights, multi-behavioral analysis, hidden markov models, and state-space models. Concurrent with the development of movement models has been an increase in the sophistication and availability of hierarchical bayesian models. In this review we bring these two threads together by using hierarchical structures as a framework for reviewing individual models. We synthesize emerging themes in movement ecology, and propose a new hierarchical model for animal movement that builds on these emerging themes. This model moves away from traditional random walks, and instead focuses inference on how moving animals with complex behavior interact with their landscape and make choices about its suitability.

  1. THE ROLE OF CRYOGENIC PROCESSES IN THE FORMATION OF LOESS DEPOSITS

    Directory of Open Access Journals (Sweden)

    Vyacheslav N. Konishchev

    2015-01-01

    Full Text Available The paper describes a new approach to the analysis of the genetic nature of mineral substances in loess deposits. In permafrost under the influence of multiple alternate freezing and thawing in dispersed deposits, quartz particles accumulate the 0.05-0.01 mm fraction, while feldspars are crushed to a coarse fraction of 0.1-0.05 mm. In dispersed sediments formed in temperate and warm climatic zones, the granulometric spectrum of quartz and feldspar has the opposite pattern. The proposed methodology is based on a differential analysis of the distribution of these minerals by the granulometric spectrum. We have proposed two criteria - the coefficient of cryogenic contrast (CCC and the coefficient of distribution of heavy minerals, which allow determination of the degree of participation of cryogenic processes in the formation of loess sediments and processes of aeolian or water sedimentation.

  2. Nitrogen deposition in precipitation to a monsoon-affected eutrophic embayment: Fluxes, sources, and processes

    Science.gov (United States)

    Wu, Yunchao; Zhang, Jingping; Liu, Songlin; Jiang, Zhijian; Arbi, Iman; Huang, Xiaoping; Macreadie, Peter Ian

    2018-06-01

    Daya Bay in the South China Sea (SCS) has experienced rapid nitrogen pollution and intensified eutrophication in the past decade due to economic development. Here, we estimated the deposition fluxes of nitrogenous species, clarified the contribution of nitrogen from precipitation and measured ions and isotopic composition (δ15N and δ18O) of nitrate in precipitation in one year period to trace its sources and formation processes among different seasons. We found that the deposition fluxes of total dissolved nitrogen (TDN), NO3-, NH4+, NO2-, and dissolved organic nitrogen (DON) to Daya Bay were 132.5, 64.4 17.5, 1.0, 49.6 mmol m-2•yr-1, respectively. DON was a significant contributor to nitrogen deposition (37% of TDN), and NO3- accounted for 78% of the DIN in precipitation. The nitrogen deposition fluxes were higher in spring and summer, and lower in winter. Nitrogen from precipitation contributed nearly 38% of the total input of nitrogen (point sources input and dry and wet deposition) in Daya Bay. The δ15N-NO3- abundance, ion compositions, and air mass backward trajectories implicated that coal combustion, vehicle exhausts, and dust from mainland China delivered by northeast monsoon were the main sources in winter, while fossil fuel combustion (coal combustion and vehicle exhausts) and dust from PRD and southeast Asia transported by southwest monsoon were the main sources in spring; marine sources, vehicle exhausts and lightning could be the potential sources in summer. δ18O results showed that OH pathway was dominant in the chemical formation process of nitrate in summer, while N2O5+ DMS/HC pathways in winter and spring.

  3. Effect of deposition temperature and thermal annealing on the dry etch rate of a-C: H films for the dry etch hard process of semiconductor devices

    International Nuclear Information System (INIS)

    Lee, Seung Moo; Won, Jaihyung; Yim, Soyoung; Park, Se Jun; Choi, Jongsik; Kim, Jeongtae; Lee, Hyeondeok; Byun, Dongjin

    2012-01-01

    thermal annealing of the high density, as-deposited a-C:H films. Furthermore, not only the density itself but also the variation of density with thermal annealing need to be elucidated in order to understand the dry etch properties of annealed a-C:H films. - Highlights: ► A-C:H(amorphous carbon) films are grown for using hard mask in dry etch process by plasma-enhanced chemical vapor deposition and annealed. ► Physical, chemical and mechanical properties of grown amorphous carbon films are changed by hydrogen and hydrocarbon contents, be determined by deposition and annealing temperature. ► Dry etch rate of a-C:H films is decreased and the film density increased through thermal annealing with high density, low hydrogen content, as-deposited film.

  4. Vertically aligned carbon nanotubes black coatings from roll-to-roll deposition process

    Science.gov (United States)

    Goislard de Monsabert, Thomas; Papciak, L.; Sangar, A.; Descarpentries, J.; Vignal, T.; de Longiviere, Xavier; Porterat, D.; Mestre, Q.; Hauf, H.

    2017-09-01

    Vertically aligned carbon nanotubes (VACNTs) have recently attracted growing interest as a very efficient light absorbing material over a broad spectral range making them a superior coating in space optics applications such as radiometry, optical calibration, and stray light elimination. However, VACNT coatings available to-date most often result from batch-to-batch deposition processes thus potentially limiting the manufacturing repeatability, substrate size and cost efficiency of this material.

  5. Impact of the Fused Deposition (FDM) Printing Process on Polylactic Acid (PLA) Chemistry and Structure

    OpenAIRE

    Michael Arthur Cuiffo; Jeffrey Snyder; Alicia M. Elliott; Nicholas Romero; Sandhiya Kannan; Gary P. Halada

    2017-01-01

    Polylactic acid (PLA) is an organic polymer commonly used in fused deposition (FDM) printing and biomedical scaffolding that is biocompatible and immunologically inert. However, variations in source material quality and chemistry make it necessary to characterize the filament and determine potential changes in chemistry occurring as a result of the FDM process. We used several spectroscopic techniques, including laser confocal microscopy, Fourier transform infrared (FTIR) spectroscopy and pho...

  6. Processing-Microstructure-Property Relationships for Cold Spray Powder Deposition of Al-Cu Alloys

    Science.gov (United States)

    2015-06-01

    Champagne [18]. The simulations were completed to compare the simulated particle exit velocities versus the measured particle exit velocities. In...620 m/s to 670 m/s [39]. V. Champagne states that for pure aluminum, an acceptable critical velocity for the deposition of pure aluminum is anything...Materials and Processess, vol. 168, no. 5, pp. 53–55, May 2010. [3] V. K. Champagne and P. F. Leyman, “Cold Spray Process Development for the Reclamation

  7. Understanding the process of greening of Brazilian business schools

    DEFF Research Database (Denmark)

    Jabbour, C.J.C.; Sarkis, J.; De Sousa Jabbour, A.B.L.

    2013-01-01

    activities; (d) paradoxically, the analyzed business schools can be considered academic leaders in the field, but have had difficulties in adopting environmental management practices internally; (e) there is a "path dependence" effect in this process; (f) there are barriers to organizational change towards...... conducted at Brazilian business schools. The results were analyzed using the conceptual background of barriers to organizational change, transition to a more sustainable society, and path dependence. The main findings indicate that: (a) the incorporation of environmental management issues tends to begin......This study analyses business schools' incorporating environmental management issues into their core activities, defined through teaching, research, outreach and management. Taking into account the relative lack of literature on this theme, case study fieldwork is utilized. Two case studies were...

  8. Understanding the process by which female entrepreneurs create INVs

    DEFF Research Database (Denmark)

    Rosenbaum, Gitte Ohrt; Hannibal, Martin

    around the world and their increasing contribution to economic growth and employment (Baughn et al., 2006). As it is generally acknowledged that female entrepreneurs exhibit many differences from their male counterparts (Anna et al., 2000; Buttner & Moore, 1997), this omission in the INV literature...... and behave in such crucial entrepreneurial processes as new venture creation. In this regard, and only recently, female entrepreneurship scholars have begun to recognize that there may be differences between male and female nascent entrepreneurs in terms of, for example, psychological attributes, education...... opportunities on (foreign) markets. As such, the specific focus of this paper will be on how answers to the series of “Who am I?, What do I know? Whom do I know?” questions in the founding stage helped the focal female entrepreneurs to recognize and create opportunities in foreign markets. In doing...

  9. Effects of acidic deposition on nutrient uptake, nutrient cycling and growth processes of vegetation in the spruce-fir ecosystem

    Energy Technology Data Exchange (ETDEWEB)

    McLaughlin, S.B.; Garten, C.T.; Wullschleger, S.D. [Oak Ridge National Lab., TN (United States)] [and others

    1996-10-16

    This report summarizes progress in three years of field research designed to evaluate biological and chemical indicators of the current and future health of the Southern Appalachian spruce-fir ecosystem. The emphasis of this research has been on the identification and understanding of mechanisms through which current levels of acidic deposition are impacting ecosystem processes. The identification of these principal mechanisms and key biological indicators of change was designed to improve our capabilities to detect, monitor, and assess the effects of air quality regulations and attendant future air quality changes on ecosystem response. Individual research tasks focused on the following research areas: (1) the significance of foliar uptake of atmospheric sources of nitrogen in relationship to plant utilization of N from available soil reserves; (2) linkages between atmospheric inputs to the soil surface, solution chemistry, and decomposition in the upper organic soil horizons; (3) effects of soil solution chemistry on uptake of cations and aluminum by fine roots; and (4) the effects of varying rates of calcium supply on carbon metabolism of Fraser fir and red spruce, and the relationship between calcium levels in wood cells and integrity of wood formed in bole and branches. Each of the individual tasks was designed to focus upon a mechanism or process that we consider critical to understanding chemical and biological linkages. These linkages will be important determinants in understanding the basis of past and potential future responses of the high elevation Southern Appalachian Forest to acidic deposition and other co-occurring environmental stresses. This report contains (1) background and rationale for the research undertaken in 1992-94; (2) a summary of principal research findings; (3) publications from this research; and (4) characterization of data sets produced by this research which will be the basis of future research, analyses and/or publications.

  10. Particokinetics: computational analysis of the superparamagnetic iron oxide nanoparticles deposition process

    Science.gov (United States)

    Cárdenas, Walter HZ; Mamani, Javier B; Sibov, Tatiana T; Caous, Cristofer A; Amaro, Edson; Gamarra, Lionel F

    2012-01-01

    Background Nanoparticles in suspension are often utilized for intracellular labeling and evaluation of toxicity in experiments conducted in vitro. The purpose of this study was to undertake a computational modeling analysis of the deposition kinetics of a magnetite nanoparticle agglomerate in cell culture medium. Methods Finite difference methods and the Crank–Nicolson algorithm were used to solve the equation of mass transport in order to analyze concentration profiles and dose deposition. Theoretical data were confirmed by experimental magnetic resonance imaging. Results Different behavior in the dose fraction deposited was found for magnetic nanoparticles up to 50 nm in diameter when compared with magnetic nanoparticles of a larger diameter. Small changes in the dispersion factor cause variations of up to 22% in the dose deposited. The experimental data confirmed the theoretical results. Conclusion These findings are important in planning for nanomaterial absorption, because they provide valuable information for efficient intracellular labeling and control toxicity. This model enables determination of the in vitro transport behavior of specific magnetic nanoparticles, which is also relevant to other models that use cellular components and particle absorption processes. PMID:22745539

  11. Particokinetics: computational analysis of the superparamagnetic iron oxide nanoparticles deposition process

    Directory of Open Access Journals (Sweden)

    Cárdenas WH

    2012-06-01

    Full Text Available Walter HZ Cárdenas, Javier B Mamani, Tatiana T Sibov, Cristofer A Caous, Edson Amaro Jr, Lionel F GamarraInstituto do Cérebro, Hospital Israelita Albert Einstein, São Paulo, BrazilBackground: Nanoparticles in suspension are often utilized for intracellular labeling and evaluation of toxicity in experiments conducted in vitro. The purpose of this study was to undertake a computational modeling analysis of the deposition kinetics of a magnetite nanoparticle agglomerate in cell culture medium.Methods: Finite difference methods and the Crank-Nicolson algorithm were used to solve the equation of mass transport in order to analyze concentration profiles and dose deposition. Theoretical data were confirmed by experimental magnetic resonance imaging.Results: Different behavior in the dose fraction deposited was found for magnetic nanoparticles up to 50 nm in diameter when compared with magnetic nanoparticles of a larger diameter. Small changes in the dispersion factor cause variations of up to 22% in the dose deposited. The experimental data confirmed the theoretical results.Conclusion: These findings are important in planning for nanomaterial absorption, because they provide valuable information for efficient intracellular labeling and control toxicity. This model enables determination of the in vitro transport behavior of specific magnetic nanoparticles, which is also relevant to other models that use cellular components and particle absorption processes.Keywords: magnetite, nanoparticles, diffusion, sedimentation, agglomerates, computational modeling, cellular labeling, magnetic resonance imaging

  12. Towards an Understanding of Enabling Process Knowing in Global Software Development: A Case Study

    DEFF Research Database (Denmark)

    Zahedi, Mansooreh; Babar, Muhammad Ali

    2014-01-01

    Shared understanding of Software Engineering (SE) processes, that we call process knowing, is required for effective communication and coordination and communication within a team in order to improve team performance. SE Process knowledge can include roles, responsibilities and flow of informatio...... challenges of lack of process knowing and how an organization can enable process knowing for achieving the desired results that also help in increasing social interactions and positive behavioral changes......Shared understanding of Software Engineering (SE) processes, that we call process knowing, is required for effective communication and coordination and communication within a team in order to improve team performance. SE Process knowledge can include roles, responsibilities and flow of information...... over a project lifecycle. Developing and sustaining process knowledge can be more challenging in Global Software Development (GSD). GSD distances can limit the ability of a team to develop a common understanding of processes. Anecdotes of the problems caused by lack of common understanding of processes...

  13. Framework for Understanding LENR Processes, Using Ordinary Condensed Matter Physics

    Science.gov (United States)

    Chubb, Scott

    2005-03-01

    As I have emphasizedootnotetextS.R. Chubb, Proc. ICCF10 (in press). Also, http://www.lenr-canr.org/acrobat/ChubbSRnutsandbol.pdf http://www.lenr-canr.org/acrobat/ChubbSRnutsandbol.pdf, S.R. Chubb, Trans. Amer. Nuc. Soc. 88 , 618 (2003)., in discussions of Low Energy Nuclear Reactions(LENRs), mainstream many-body physics ideas have been largely ignored. A key point is that in condensed matter, delocalized, wave-like effects can allow large amounts of momentum to be transferred instantly to distant locations, without any particular particle (or particles) acquiring high velocity through a Broken Gauge Symmetry. Explicit features in the electronic structure explain how this can occur^1 in finite size PdD crystals, with real boundaries. The essential physics^1 can be related to standard many-body techniquesootnotetextBurke,P.G. and K.A. Berrington, Atomic and Molecular Processes:an R matrix Approach (Bristol: IOP Publishing, 1993).. In the paper, I examine this relationship, the relationship of the theory^1 to other LENR theories, and the importance of certain features (for example, boundaries^1) that are not included in the other LENR theories.

  14. A modeling process to understand complex system architectures

    Science.gov (United States)

    Robinson, Santiago Balestrini

    2009-12-01

    In recent decades, several tools have been developed by the armed forces, and their contractors, to test the capability of a force. These campaign level analysis tools, often times characterized as constructive simulations are generally expensive to create and execute, and at best they are extremely difficult to verify and validate. This central observation, that the analysts are relying more and more on constructive simulations to predict the performance of future networks of systems, leads to the two central objectives of this thesis: (1) to enable the quantitative comparison of architectures in terms of their ability to satisfy a capability without resorting to constructive simulations, and (2) when constructive simulations must be created, to quantitatively determine how to spend the modeling effort amongst the different system classes. The first objective led to Hypothesis A, the first main hypotheses, which states that by studying the relationships between the entities that compose an architecture, one can infer how well it will perform a given capability. The method used to test the hypothesis is based on two assumptions: (1) the capability can be defined as a cycle of functions, and that it (2) must be possible to estimate the probability that a function-based relationship occurs between any two types of entities. If these two requirements are met, then by creating random functional networks, different architectures can be compared in terms of their ability to satisfy a capability. In order to test this hypothesis, a novel process for creating representative functional networks of large-scale system architectures was developed. The process, named the Digraph Modeling for Architectures (DiMA), was tested by comparing its results to those of complex constructive simulations. Results indicate that if the inputs assigned to DiMA are correct (in the tests they were based on time-averaged data obtained from the ABM), DiMA is able to identify which of any two

  15. Understanding snow-transport processes shaping the mountain snow-cover

    Directory of Open Access Journals (Sweden)

    R. Mott

    2010-12-01

    Full Text Available Mountain snow-cover is normally heterogeneously distributed due to wind and precipitation interacting with the snow cover on various scales. The aim of this study was to investigate snow deposition and wind-induced snow-transport processes on different scales and to analyze some major drift events caused by north-west storms during two consecutive accumulation periods. In particular, we distinguish between the individual processes that cause specific drifts using a physically based model approach. Very high resolution wind fields (5 m were computed with the atmospheric model Advanced Regional Prediction System (ARPS and used as input for a model of snow-surface processes (Alpine3D to calculate saltation, suspension and preferential deposition of precipitation. Several flow features during north-west storms were identified with input from a high-density network of permanent and mobile weather stations and indirect estimations of wind directions from snow-surface structures, such as snow dunes and sastrugis. We also used Terrestrial and Airborne Laser Scanning measurements to investigate snow-deposition patterns and to validate the model. The model results suggest that the in-slope deposition patterns, particularly two huge cross-slope cornice-like drifts, developed only when the prevailing wind direction was northwesterly and were formed mainly due to snow redistribution processes (saltation-driven. In contrast, more homogeneous deposition patterns on a ridge scale were formed during the same periods mainly due to preferential deposition of precipitation. The numerical analysis showed that snow-transport processes were sensitive to the changing topography due to the smoothing effect of the snow cover.

  16. Bio-mineralization and potential biogeochemical processes in bauxite deposits: genetic and ore quality significance

    Science.gov (United States)

    Laskou, Magdalini; Economou-Eliopoulos, Maria

    2013-08-01

    The Parnassos-Ghiona bauxite deposit in Greece of karst type is the 11th largest bauxite producer in the world. The mineralogical, major and trace-element contents and δ18O, δ12C, δ34S isotopic compositions of bauxite ores from this deposit and associated limestone provide valuable evidence for their origin and biogeochemical processes resulting in the beneficiation of low grade bauxite ores. The organic matter as thin coal layers, overlying the bauxite deposits, within limestone itself (negative δ12C isotopic values) and the negative δ34S values in sulfides within bauxite ores point to the existence of the appropriate circumstances for Fe bio-leaching and bio-mineralization. Furthermore, a consortium of microorganisms of varying morphological forms (filament-like and spherical to lenticular at an average size of 2 μm), either as fossils or presently living and producing enzymes, is a powerful factor to catalyze the redox reactions, expedite the rates of metal extraction and provide alternative pathways for metal leaching processes resulting in the beneficiation of bauxite ore.

  17. Gaseous material capacity of open plasma jet in plasma spray-physical vapor deposition process

    Science.gov (United States)

    Liu, Mei-Jun; Zhang, Meng; Zhang, Qiang; Yang, Guan-Jun; Li, Cheng-Xin; Li, Chang-Jiu

    2018-01-01

    Plasma spray-physical vapor deposition (PS-PVD) process, emerging as a highly efficient hybrid approach, is based on two powerful technologies of both plasma spray and physical vapor deposition. The maximum production rate is affected by the material feed rate apparently, but it is determined by the material vapor capacity of transporting plasma actually and essentially. In order to realize high production rate, the gaseous material capacity of plasma jet must be fundamentally understood. In this study, the thermal characteristics of plasma were measured by optical emission spectrometry. The results show that the open plasma jet is in the local thermal equilibrium due to a typical electron number density from 2.1 × 1015 to 3.1 × 1015 cm-3. In this condition, the temperature of gaseous zirconia can be equal to the plasma temperature. A model was developed to obtain the vapor pressure of gaseous ZrO2 molecules as a two dimensional map of jet axis and radial position corresponding to different average plasma temperatures. The overall gaseous material capacity of open plasma jet, take zirconia for example, was further established. This approach on evaluating material capacity in plasma jet would shed light on the process optimization towards both depositing columnar coating and a high production rate of PS-PVD.

  18. Understanding the electron-stimulated surface reactions of organometallic complexes to enable design of precursors for electron beam-induced deposition

    Energy Technology Data Exchange (ETDEWEB)

    Spencer, Julie A.; Rosenberg, Samantha G.; Barclay, Michael; Fairbrother, D. Howard [Johns Hopkins University, Department of Chemistry, Baltimore, MD (United States); Wu, Yung-Chien; McElwee-White, Lisa [University of Florida, Department of Chemistry, Gainesville, FL (United States)

    2014-12-15

    Standard practice in electron beam-induced deposition (EBID) is to use precursors designed for thermal processes, such as chemical vapor deposition (CVD). However, organometallic precursors that yield pure metal deposits in CVD often create EBID deposits with high levels of organic contamination. This contamination negatively impacts the deposit's properties (e.g., by increasing resistivity or decreasing catalytic activity) and severely limits the range of potential applications for metal-containing EBID nanostructures. To provide the information needed for the rational design of precursors specifically for EBID, we have employed an ultra-high vacuum (UHV) surface science approach to identify the elementary reactions of organometallic precursors during EBID. These UHV studies have demonstrated that the initial electron-induced deposition of the surface-bound organometallic precursors proceeds through desorption of one or more of the ligands present in the parent compound. In specific cases, this deposition step has been shown to proceed via dissociative electron attachment, involving low-energy secondary electrons generated by the interaction of the primary beam with the substrate. Electron beam processing of the surface-bound species produced in the initial deposition event usually causes decomposition of the residual ligands, creating nonvolatile fragments. This process is believed to be responsible for a significant fraction of the organic contaminants typically observed in EBID nanostructures. A few ligands (e.g., halogens) can, however, desorb during electron beam processing while other ligands (e.g., PF{sub 3}, CO) can thermally desorb if elevated substrate temperatures are used during deposition. Using these general guidelines for reactivity, we propose some design strategies for EBID precursors. The ultimate goal is to minimize organic contamination and thus overcome the key bottleneck for fabrication of relatively pure EBID nanostructures. (orig.)

  19. Deposition of high Tc superconductor thin films by pulsed excimer laser ablation and their post-synthesis processing

    International Nuclear Information System (INIS)

    Ogale, S.B.

    1992-01-01

    This paper describes the use of pulsed excimer laser ablation technique for deposition of high quality superconductor thin films on different substrate materials such as Y stabilized ZrO 2 , SrTiO 3 , LiNbO 3 , Silicon and Stainless Steels, and dopant incorporation during the film depositions. Processing of deposited films using ion and laser beams for realisation of device features are presented. 28 refs., 16 figs

  20. Interpretation of postdepositional processes related to the formation and destruction of the Jackpile-Paguate uranium deposit, northwest New Mexico

    International Nuclear Information System (INIS)

    Adams, S.S.; Curtis, H.S.; Hafen, P.L.; Salek-Nejad, H.

    1978-01-01

    This paper presents aspects of geological studies conducted on the Jackpile-Paguate uranium deposit in northwestern New Mexico in order to document and interpret certain geological characteristics of the deposit and suggest a sequence of processes which have formed and, in part, destroyed the deposits. The principle contributions of the paper are the field and petrologic observations and the interpretations they permit. 29 refs

  1. Catalytic behaviors of ruthenium dioxide films deposited on ferroelectrics substrates, by spin coating process

    International Nuclear Information System (INIS)

    Khachane, M.; Nowakowski, P.; Villain, S.; Gavarri, J.R.; Muller, Ch.; Elaatmani, M.; Outzourhite, A.; Luk'yanchuk, I.; Zegzouti, A.; Daoud, M.

    2007-01-01

    Catalytic ruthenium dioxide films were deposited by spin-coating process on ferroelectric films mainly constituted of SrBi 2 Ta 2 O 9 (SBT) and Ba 2 NaNb 5 O 15 (BNN) phases. After thermal treatment under air, these ferroelectric-catalytic systems were characterized by X-ray diffraction and scanning electron microscopy (SEM). SEM images showed that RuO 2 film morphology depended on substrate nature. A study of CH 4 conversion into CO 2 and H 2 O was carried out using these catalytic-ferroelectric multilayers: the conversion was analyzed from Fourier transform infrared (FTIR) spectroscopy, at various temperatures. Improved catalytic properties were observed for RuO 2 films deposited on BNN oxide layer

  2. Mass-Spectrometric Studies of Catalytic Chemical Vapor Deposition Processes of Organic Silicon Compounds Containing Nitrogen

    Science.gov (United States)

    Morimoto, Takashi; Ansari, S. G.; Yoneyama, Koji; Nakajima, Teppei; Masuda, Atsushi; Matsumura, Hideki; Nakamura, Megumi; Umemoto, Hironobu

    2006-02-01

    The mechanism of catalytic chemical vapor deposition (Cat-CVD) processes for hexamethyldisilazane (HMDS) and trisdimethylaminosilane (TDMAS), which are used as source gases to prepare SiNx or SiCxNy films, was studied using three different mass spectrometric techniques: ionization by Li+ ion attachment, vacuum-ultraviolet radiation and electron impact. The results for HMDS show that Si-N bonds dissociate selectively, although Si-C bonds are weaker, and (CH3)3SiNH should be one of the main precursors of deposited films. This decomposition mechanism did not change when NH3 was introduced, but the decomposition efficiency was slightly increased. Similar results were obtained for TDMAS.

  3. On the processing-structure-property relationship of ITO layers deposited on crystalline and amorphous Si

    International Nuclear Information System (INIS)

    Diplas, S.; Ulyashin, A.; Maknys, K.; Gunnaes, A.E.; Jorgensen, S.; Wright, D.; Watts, J.F.; Olsen, A.; Finstad, T.G.

    2007-01-01

    Indium-tin-oxide (ITO) antireflection coatings were deposited on crystalline Si (c-Si), amorphous hydrogenated Si (a-Si:H) and glass substrates at room temperature (RT), 160 deg. C and 230 deg. C by magnetron sputtering. The films were characterised using atomic force microscopy, transmission electron microscopy, angle resolved X-ray photoelectron spectroscopy, combined with resistance and transmittance measurements. The conductivity and refractive index as well as the morphology of the ITO films showed a significant dependence on the processing conditions. The films deposited on the two different Si substrates at higher temperatures have rougher surfaces compared to the RT ones due to the development of crystallinity and growth of columnar grains

  4. Process qualification and testing of LENS deposited AY1E0125 D-bottle brackets

    International Nuclear Information System (INIS)

    Atwood, Clinton J.; Smugeresky, John E.; Jew, Michael; Gill, David Dennis; Scheffel, Simon

    2006-01-01

    The LENS Qualification team had the goal of performing a process qualification for the Laser Engineered Net Shaping(trademark)(LENS(reg s ign)) process. Process Qualification requires that a part be selected for process demonstration. The AY1E0125 D-Bottle Bracket from the W80-3 was selected for this work. The repeatability of the LENS process was baselined to determine process parameters. Six D-Bottle brackets were deposited using LENS, machined to final dimensions, and tested in comparison to conventionally processed brackets. The tests, taken from ES1E0003, included a mass analysis and structural dynamic testing including free-free and assembly-level modal tests, and Haversine shock tests. The LENS brackets performed with very similar characteristics to the conventionally processed brackets. Based on the results of the testing, it was concluded that the performance of the brackets made them eligible for parallel path testing in subsystem level tests. The testing results and process rigor qualified the LENS process as detailed in EER200638525A

  5. Understanding Small-Scale Processes Controlling the Bioavailability of Organic Contaminants to Deposit-Feeding Benthos

    DEFF Research Database (Denmark)

    Forbes, T. L.

    1999-01-01

    Proceedings of the NATO Advanced Research Workshop on Biogeochemical Cycling in Marine Sediments held at Hel, Poland, August 1997.......Proceedings of the NATO Advanced Research Workshop on Biogeochemical Cycling in Marine Sediments held at Hel, Poland, August 1997....

  6. Understanding and improving the chemical vapor deposition process for solar grade silicon production

    OpenAIRE

    Ramos Cabal, Alba

    2015-01-01

    Esta Tesis Doctoral se centra en la investigación del proceso de producción de polisilicio para aplicaciones fotovoltaicas (FV) por la vía química; mediante procesos de depósito en fase vapor (CVD). El polisilicio para la industria FV recibe el nombre de silicio de grado solar (SoG Si). Por un lado, el proceso que domina hoy en día la producción de SoG Si está basado en la síntesis, destilación y descomposición de triclorosilano (TCS) en un reactor CVD -denominado reactor Siemens-. El materia...

  7. Half-sandwich cobalt complexes in the metal-organic chemical vapor deposition process

    Energy Technology Data Exchange (ETDEWEB)

    Georgi, Colin [Technische Universität Chemnitz, Faculty of Natural Science, Institute of Chemistry, Inorganic Chemistry, Chemnitz 09107 (Germany); Hapke, Marko; Thiel, Indre [Leibniz-Institut für Katalyse e.V. an der Universität Rostock (LIKAT), Albert-Einstein-Straße 29a, Rostock 18059 (Germany); Hildebrandt, Alexander [Technische Universität Chemnitz, Faculty of Natural Science, Institute of Chemistry, Inorganic Chemistry, Chemnitz 09107 (Germany); Waechtler, Thomas; Schulz, Stefan E. [Fraunhofer Institute of Electronic Nano Systems (ENAS), Technologie-Campus 3, Chemnitz 09126 (Germany); Technische Universität Chemnitz, Center for Microtechnologies (ZfM), Chemnitz 09107 (Germany); Lang, Heinrich, E-mail: heinrich.lang@chemie.tu-chemnitz.de [Technische Universität Chemnitz, Faculty of Natural Science, Institute of Chemistry, Inorganic Chemistry, Chemnitz 09107 (Germany)

    2015-03-02

    A series of cobalt half-sandwich complexes of type [Co(η{sup 5}-C{sub 5}H{sub 5})(L)(L′)] (1: L, L′ = 1,5-hexadiene; 2: L = P(OEt){sub 3}, L′ = H{sub 2}C=CHSiMe{sub 3}; 3: L = L′ = P(OEt){sub 3}) has been studied regarding their physical properties such as the vapor pressure, decomposition temperature and applicability within the metal-organic chemical vapor deposition (MOCVD) process, with a focus of the influence of the phosphite ligands. It could be shown that an increasing number of P(OEt){sub 3} ligands increases the vapor pressure and thermal stability of the respective organometallic compound. Complex 3 appeared to be a promising MOCVD precursor with a high vapor pressure and hence was deposited onto Si/SiO{sub 2} (100 nm) substrates. The resulting reflective layer is closed, dense and homogeneous, with a slightly granulated surface morphology. X-ray photoelectron spectroscopy (XPS) studies demonstrated the formation of metallic cobalt, cobalt phosphate, cobalt oxide and cobalt carbide. - Highlights: • Thermal studies and vapor pressure measurements of cobalt half-sandwich complexes was carried out. • Chemical vapor deposition with cobalt half-sandwich complexes is reported. • The use of Co-phosphites results in significant phosphorous-doped metallic layers.

  8. Wet and dry deposition and resuspension of AFCT/TFCT fuel processing radionuclides. Final report

    International Nuclear Information System (INIS)

    Slinn, W.G.N.; Katen, P.C.; Wolf, M.A.; Loveland, W.D.; Radke, L.F.; Miller, E.L.; Ghannam, L.J.; Reynolds, B.W.; Vickers, D.

    1979-09-01

    After short summary and introductory chapters, Chapter IV contains a critical analysis of available parameterizations for resuspension and for wet and dry removal processes and recommends interim parameterizations for use in radiation dose calculations. Chapter V describes methods and experimental results from field studies of in-cloud vs below-cloud scavenging, precipitation efficiency, and modifications of aerosols by clouds. In Chapter VI are contained descriptions of methods and results from four different approaches to the problem of measuring the dry deposition velocities of submicron aerosol particles depositing on vegetation. Chapter VII describes experimental results from a study of resuspension and weathering of tracer aerosol particles deposited on soil, grass and gravel; typical resuspension rates were found to be of the order of 10 -8 s -1 and it is recommended that the concept of weathering be reassessed. In Chapter VIII, National Weather Service data are used to obtain Lagrangian statistics for use in a regional-scale study of wet and dry removal. Chapter IX develops new concepts in reservoir models for application at regional to global scales. In the final chapter are some comments about the results found in this study and recommendations for future research

  9. Reconstructing depositional processes and history from reservoir stratigraphy: Englebright Lake, Yuba River, northern California

    Science.gov (United States)

    Snyder, N.P.; Wright, S.A.; Alpers, Charles N.; Flint, L.E.; Holmes, C.W.; Rubin, D.M.

    2006-01-01

    Reservoirs provide the opportunity to link watershed history with its stratigraphic record. We analyze sediment cores from a northern California reservoir in the context of hydrologic history, watershed management, and depositional processes. Observations of recent depositional patterns, sediment-transport calculations, and 137CS geochronology support a conceptual model in which the reservoir delta progrades during floods of short duration (days) and is modified during prolonged (weeks to months) drawdowns that rework topset beds and transport sand from topsets to foresets. Sediment coarser than 0.25-0.5 mm. deposits in foresets and topsets, and finer material falls out of suspension as bottomset beds. Simple hydraulic calculations indicate that fine sand (0.063-0.5 mm) is transported into the distal bottomset area only during floods. The overall stratigraphy suggests that two phases of delta building occurred in the reservoir. The first, from dam construction in 1940 to 1970, was heavily influenced by annual, prolonged >20 m drawdowns of the water level. The second, built on top of the first, reflects sedimentation from 1970 to 2002 when the influence of drawdowns was less. Sedimentation rates in the central part of the reservoir have declined ???25% since 1970, likely reflecting a combination of fewer large floods, changes in watershed management, and winnowing of stored hydraulic mining sediment. Copyright 2006 by the American Geophysical Union.

  10. Deposition and surface treatment of Ag-embedded indium tin oxide by plasma processing

    International Nuclear Information System (INIS)

    Kim, Jun Young; Kim, Jae-Kwan; Kim, Ja-Yeon; Kwon, Min-Ki; Yoon, Jae-Sik; Lee, Ji-Myon

    2013-01-01

    Ag-embedded indium tin oxide (ITO) films were deposited on Corning 1737 glass by radio-frequency magnetron sputtering under an Ar or Ar/O 2 mixed gas ambient with a combination of ITO and Ag targets that were sputtered alternately by switching on and off the shutter of the sputter gun. The effects of a subsequent surface treatment using H 2 and H 2 + O 2 mixed gas plasma were also examined. The specific resistance of the as-deposited Ag-embedded ITO sample was lower than that of normal ITO. The transmittance was quenched when Ag was incorporated in ITO. To enhance the specific resistance of Ag-embedded ITO, a surface treatment was conducted using H 2 or H 2 + O 2 mixed gas plasma. Although all samples showed improved specific resistance after the H 2 plasma treatment, the transmittance was quenched due to the formation of agglomerated metals on the surface. The specific resistance of the film was improved without any deterioration of the transmittance after a H 2 + O 2 mixed gas plasma treatment. - Highlights: • Ag-embedded indium tin oxide was deposited. • The contact resistivity was decreased by H 2 + O 2 plasma treatment. • The process was carried out at room temperature without thermal treatment. • The mechanism of enhancing the contact resistance was clarified

  11. Sedimentary facies and Holocene depositional processes of Laura Island, Majuro Atoll

    Science.gov (United States)

    Yasukochi, Toru; Kayanne, Hajime; Yamaguchi, Toru; Yamano, Hiroya

    2014-10-01

    The depositional processes that formed Laura Island, Majuro Atoll, Marshall Islands, were reconstructed based on a facies analysis of island sediments and spine ratios, and radiocarbon ages of foraminifera. Sedimentary facies were analyzed from trenches and drill cores excavated on the island and its adjacent reef flat. Depositional ages were obtained using benthic foraminifera (Calcarina) whose spines had not been abraded. The facies were classified into two types: gravelly and sandy. The initial sediments of these sites consisted of gravelly facies in the lower horizon and sandy facies in the upper horizon. Their ages were approximately 2000 cal BP and coincident with the onset of a 1.1-m decline in regional relative sea level, which enabled deposition of the gravelly facies. Half of the sand fraction of the sediment was composed of larger benthic foraminifera. The spine ratio showed that their supply source on the reef flat was located oceanside of the island. The supply source appears to have been caused by the relative sea-level fall. This indicates that the studied island was formed by a relative reduction in wave energy and enhanced foraminiferal supply, both of which were triggered by the late Holocene relative sea-level fall.

  12. Tuning polymorphism and orientation in organic semiconductor thin films via post-deposition processing.

    Science.gov (United States)

    Hiszpanski, Anna M; Baur, Robin M; Kim, Bumjung; Tremblay, Noah J; Nuckolls, Colin; Woll, Arthur R; Loo, Yueh-Lin

    2014-11-05

    Though both the crystal structure and molecular orientation of organic semiconductors are known to impact charge transport in thin-film devices, separately accessing different polymorphs and varying the out-of-plane molecular orientation is challenging, typically requiring stringent control over film deposition conditions, film thickness, and substrate chemistry. Here we demonstrate independent tuning of the crystalline polymorph and molecular orientation in thin films of contorted hexabenzocoronene, c-HBC, during post-deposition processing without the need to adjust deposition conditions. Three polymorphs are observed, two of which have not been previously reported. Using our ability to independently tune the crystal structure and out-of-plane molecular orientation in thin films of c-HBC, we have decoupled and evaluated the effects that molecular packing and orientation have on device performance in thin-film transistors (TFTs). In the case of TFTs comprising c-HBC, polymorphism and molecular orientation are equally important; independently changing either one affects the field-effect mobility by an order of magnitude.

  13. New deposition processes for the growth of oxide and nitride thin films

    International Nuclear Information System (INIS)

    Apen, E.A.; Atagi, L.M.; Barbero, R.S.; Espinoza, B.F.; Hubbard, K.M.; Salazar, K.V.; Samuels, J.A.; Smith, D.C.; Hoffman, D.M.

    1998-01-01

    This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The goal of this effort is to study the use of homoleptic metal amido compounds as precursors for chemical vapor deposition (CVD). The amides offer potential for the deposition of a variety of important materials at low temperatures. The establishment of these precursor compounds will enhance the ability to exploit the properties of advanced materials in numerous coatings applications. Experiments were performed to study the reactivity of Sn[NMe 2 ] 4 with oxygen. The data demonstrated that gas-phase insertion of oxygen into the Sn-N bond, leading to a reactive intermediate, plays an important role in tin oxide deposition. Several CVD processes for technologically important materials were developed using the amido precursor complexes. These included the plasma enhanced CVD of TiN and Zr 3 N 4 , and the thermal CVD of GaN and AlN. Quality films were obtained in each case, demonstrating the potential of the amido compounds as CVD precursors

  14. Roll-to-roll atomic layer deposition process for flexible electronics encapsulation applications

    International Nuclear Information System (INIS)

    Maydannik, Philipp S.; Kääriäinen, Tommi O.; Lahtinen, Kimmo; Cameron, David C.; Söderlund, Mikko; Soininen, Pekka; Johansson, Petri; Kuusipalo, Jurkka; Moro, Lorenza; Zeng, Xianghui

    2014-01-01

    At present flexible electronic devices are under extensive development and, among them, flexible organic light-emitting diode displays are the closest to a large market deployment. One of the remaining unsolved challenges is high throughput production of impermeable flexible transparent barrier layers that protect sensitive light-emitting materials against ambient moisture. The present studies deal with the adaptation of the atomic layer deposition (ALD) process to high-throughput roll-to-roll production using the spatial ALD concept. We report the development of such a process for the deposition of 20 nm thickness Al 2 O 3 diffusion barrier layers on 500 mm wide polymer webs. The process uses trimethylaluminum and water as precursors at a substrate temperature of 105 °C. The observation of self-limiting film growth behavior and uniformity of thickness confirms the ALD growth mechanism. Water vapor transmission rates for 20 nm Al 2 O 3 films deposited on polyethylene naphthalate (PEN) substrates were measured as a function of substrate residence time, that is, time of exposure of the substrate to one precursor zone. Moisture permeation levels measured at 38 °C/90% relative humidity by coulometric isostatic–isobaric method were below the detection limit of the instrument ( −4  g/m 2 day) for films coated at web moving speed of 0.25 m/min. Measurements using the Ca test indicated water vapor transmission rates ∼5 × 10 −6 g/m 2 day. Optical measurements on the coated web showed minimum transmission of 80% in the visible range that is the same as the original PEN substrate

  15. Roll-to-roll atomic layer deposition process for flexible electronics encapsulation applications

    Energy Technology Data Exchange (ETDEWEB)

    Maydannik, Philipp S., E-mail: philipp.maydannik@lut.fi; Kääriäinen, Tommi O.; Lahtinen, Kimmo; Cameron, David C. [Advanced Surface Technology Research Laboratory, Lappeenranta University of Technology, Sammonkatu 12, 50130 Mikkeli (Finland); Söderlund, Mikko; Soininen, Pekka [Beneq Oy, P.O. Box 262, 01511 Vantaa (Finland); Johansson, Petri; Kuusipalo, Jurkka [Tampere University of Technology, Paper Converting and Packaging Technology, P.O. Box 589, 33101 Tampere (Finland); Moro, Lorenza; Zeng, Xianghui [Samsung Cheil Industries, San Jose R and D Center, 2186 Bering Drive, San Jose, California 95131 (United States)

    2014-09-01

    At present flexible electronic devices are under extensive development and, among them, flexible organic light-emitting diode displays are the closest to a large market deployment. One of the remaining unsolved challenges is high throughput production of impermeable flexible transparent barrier layers that protect sensitive light-emitting materials against ambient moisture. The present studies deal with the adaptation of the atomic layer deposition (ALD) process to high-throughput roll-to-roll production using the spatial ALD concept. We report the development of such a process for the deposition of 20 nm thickness Al{sub 2}O{sub 3} diffusion barrier layers on 500 mm wide polymer webs. The process uses trimethylaluminum and water as precursors at a substrate temperature of 105 °C. The observation of self-limiting film growth behavior and uniformity of thickness confirms the ALD growth mechanism. Water vapor transmission rates for 20 nm Al{sub 2}O{sub 3} films deposited on polyethylene naphthalate (PEN) substrates were measured as a function of substrate residence time, that is, time of exposure of the substrate to one precursor zone. Moisture permeation levels measured at 38 °C/90% relative humidity by coulometric isostatic–isobaric method were below the detection limit of the instrument (<5 × 10{sup −4} g/m{sup 2} day) for films coated at web moving speed of 0.25 m/min. Measurements using the Ca test indicated water vapor transmission rates ∼5 × 10{sup −6} g/m{sup 2} day. Optical measurements on the coated web showed minimum transmission of 80% in the visible range that is the same as the original PEN substrate.

  16. High-rate anisotropic ablation and deposition of polytetrafluoroethylene using synchrotron radiation process

    International Nuclear Information System (INIS)

    Inayoshi, Muneto; Ikeda, Masanobu; Hori, Masaru; Goto, Toshio; Hiramatsu, Mineo; Hiraya, Atsunari.

    1995-01-01

    Both anisotropic ablation and thin film formation of polytetrafluoroethylene (PTFE) were successfully demonstrated using synchrotron radiation (SR) irradiation of PTFE, that is, the SR ablation process. Anisotropic ablation by the SR irradiation was performed at an extremely high rate of 3500 μm/min at a PTFE target temperature of 200degC. Moreover, a PTFE thin film was formed at a high rate of 2.6 μm/min using SR ablation of PTFE. The chemical structure of the deposited film was similar to that of the PTFE target as determined from Fourier transform infrared absorption spectroscopy (FT-IR) analysis. (author)

  17. Chemical vapor deposition graphene transfer process to a polymeric substrate assisted by a spin coater

    International Nuclear Information System (INIS)

    Kessler, Felipe; Da Rocha, Caique O C; Medeiros, Gabriela S; Fechine, Guilhermino J M

    2016-01-01

    A new method to transfer chemical vapor deposition graphene to polymeric substrates is demonstrated here, it is called direct dry transfer assisted by a spin coater (DDT-SC). Compared to the conventional method DDT, the improvement of the contact between graphene-polymer due to a very thin polymeric film deposited by spin coater before the transfer process prevented air bubbles and/or moisture and avoided molecular expansion on the graphene-polymer interface. An acrylonitrile-butadiene-styrene copolymer, a high impact polystyrene, polybutadiene adipate-co-terephthalate, polylactide acid, and a styrene-butadiene-styrene copolymer are the polymers used for the transfers since they did not work very well by using the DDT process. Raman spectroscopy and optical microscopy were used to identify, to quantify, and to qualify graphene transferred to the polymer substrates. The quantity of graphene transferred was substantially increased for all polymers by using the DDT-SC method when compared with the DDT standard method. After the transfer, the intensity of the D band remained low, indicating low defect density and good quality of the transfer. The DDT-SC transfer process expands the number of graphene applications since the polymer substrate candidates are increased. (paper)

  18. Feature scale modeling for etching and deposition processes in semiconductor manufacturing

    International Nuclear Information System (INIS)

    Pyka, W.

    2000-04-01

    Simulation of etching and deposition processes as well as three-dimensional geometry generation are important issues in state of the art TCAD applications. Three-dimensional effects are gaining importance for semiconductor devices and for their interconnects. Therefore a strictly physically based simulation of their topography is required. Accurate investigation of single etching and deposition processes has become equally important as process integration. Within this context several aspects of three-dimensional topography simulation have been covered by this thesis and new and interesting results have been achieved in various areas. The algorithmic core of the cell-based structuring element surface propagation method has been optimized and has been eliminated from its position as factor which predominantly determines the required CPU time. In parallel with investigated optimization techniques and required by various process models, the implementation of the surface normal calculation and the special handling of voids and unconnected parts of the geometry has been completed in three dimensions. A process-step-based solid modeling tool which incorporates layout data as well as aerial image simulation has been supplied. It can be coupled with the topography simulation and includes simple geometrically based models for CMP and oxidation. In the presented combination, the tool makes use of the design information stored in the layout file, combines it with the manufacturing recipe, and hence is extremely helpful for the automatic generation of three-dimensional structures. Its usefulness has been proven with several interconnect examples. Regarding topography models, resist development not only turned out to be very helpful for predicting exposed and etched resist profiles within a rigorous lithography simulation, but, by means of benchmark examples, also demonstrated the extraordinary stability of the proposed cellular surface movement algorithm. With respect to

  19. Chemical Vapor Deposition of Photocatalyst Nanoparticles on PVDF Membranes for Advanced Oxidation Processes

    Directory of Open Access Journals (Sweden)

    Giovanni De Filpo

    2018-06-01

    Full Text Available The chemical binding of photocatalytic materials, such as TiO2 and ZnO nanoparticles, onto porous polymer membranes requires a series of chemical reactions and long purification processes, which often result in small amounts of trapped nanoparticles with reduced photocatalytic activity. In this work, a chemical vapor deposition technique was investigated in order to allow the nucleation and growth of ZnO and TiO2 nanoparticles onto polyvinylidene difluoride (PVDF porous membranes for application in advanced oxidation processes. The thickness of obtained surface coatings by sputtered nanoparticles was found to depend on process conditions. The photocatalytic efficiency of sputtered membranes was tested against both a model drug and a model organic pollutant in a small continuous flow reactor.

  20. Understanding the creative processes of phenomenological research: The life philosophy of Løgstrup

    OpenAIRE

    Annelise Norlyk; Pia Dreyer; Anita Haahr; Bente Martinsen

    2011-01-01

    The creative processes of understanding patients’ experiences in phenomenological research are difficult to articulate. Drawing on life philosophy as represented by the Danish philosopher K.E. Løgstrup (1905-1981), this article aims to illustrate Løgstrup’s thinking as a way to elaborate the creation of cognition and understanding of patients’ experiences. We suggest that Løgstrup’s thoughts on sensation can add new dimensions to an increased understanding of the creative process of phenomeno...

  1. Process for depositing an oxide epitaxially onto a silicon substrate and structures prepared with the process

    Science.gov (United States)

    McKee, Rodney A.; Walker, Frederick J.

    1993-01-01

    A process and structure involving a silicon substrate utilizes an ultra high vacuum and molecular beam epitaxy (MBE) methods to grow an epitaxial oxide film upon a surface of the substrate. As the film is grown, the lattice of the compound formed at the silicon interface becomes stabilized, and a base layer comprised of an oxide having a sodium chloride-type lattice structure grows epitaxially upon the compound so as to cover the substrate surface. A perovskite may then be grown epitaxially upon the base layer to render a product which incorporates silicon, with its electronic capabilities, with a perovskite having technologically-significant properties of its own.

  2. University Students' Understanding of Chemistry Processes and the Quality of Evidence in Their Written Arguments

    Science.gov (United States)

    Seung, Eulsun; Choi, Aeran; Pestel, Beverly

    2016-01-01

    We have developed a process-oriented chemistry laboratory curriculum for non-science majors. The purpose of this study is both to explore university students' understanding of chemistry processes and to evaluate the quality of evidence students use to support their claims regarding chemistry processes in a process-oriented chemistry laboratory…

  3. Executable business process modeling as a tool for increasing the understanding of business processes in an organization

    OpenAIRE

    Demir, Ersin

    2014-01-01

    Understanding of business processes is becoming an important key factor for successful businesses and today many organizations are facing the lack of knowledge about the business processes that they are working on. Since the interaction between different business processes and different actors are becoming more common it is not only enough for employees to have knowledge about the business processes that they involve directly, but also they need to know about the other business processes in t...

  4. A flexible angle sensor made from MWNT/CuO/Cu{sub 2}O nanocomposite films deposited by an electrophoretic co-deposition process

    Energy Technology Data Exchange (ETDEWEB)

    Toboonsung, Buppachat, E-mail: buppachattt@yahoo.co.th [Physics and General Science Program, Faculty of Science and Technology, Nakhon Ratchasima Rajabhat University, Nakhon Ratchasima 30000 (Thailand); Singjai, Pisith, E-mail: singjai@hotmail.com [Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai, 50200 (Thailand)

    2012-08-25

    Highlights: Black-Right-Pointing-Pointer MWNT/CuO/Cu{sub 2}Onanocomposite films were coated on a PET sheet. Black-Right-Pointing-Pointer The film resistance and application as angle sensor were investigated. Black-Right-Pointing-Pointer Thesensor showed a linear relation between the film resistance and the bending angle. Black-Right-Pointing-Pointer A minimum loop area and a high stability in sensitivity over a thousand bending cycles were obtained. - Abstract: A flexible angle sensor was prepared using an electrophoretic co-deposition process to form nanocomposite networks of multi-wall carbon nanotube/cupric oxide/cuprous oxide (MWNT/CuO/Cu{sub 2}O) on a polyethylene terephthalate (PET) sheet. The deposition method used copper and stainless steel electrodes, and the effects of varying of electrode separation, MWNT concentration in deionized water, voltage and deposition time were studied. The film resistance of the as-deposited samples decreased with increasing the MWNT concentration up to 0.3 mg/ml. The angle sensor showed a linear relation between the film resistance and the bending angle, a relationship that was illustrated with loop area and sensitivity data. The best angle sensor was successfully made with an electrode separation of 8 mm, a concentration of 0.3 mg/ml, a voltage of 10 V and a deposition time of 3 h, parameters that resulted in a minimum loop area and the most stability in sensitivity over a thousand bending cycles.

  5. Sensor-based atomic layer deposition for rapid process learning and enhanced manufacturability

    Science.gov (United States)

    Lei, Wei

    In the search for sensor based atomic layer deposition (ALD) process to accelerate process learning and enhance manufacturability, we have explored new reactor designs and applied in-situ process sensing to W and HfO 2 ALD processes. A novel wafer scale ALD reactor, which features fast gas switching, good process sensing compatibility and significant similarity to the real manufacturing environment, is constructed. The reactor has a unique movable reactor cap design that allows two possible operation modes: (1) steady-state flow with alternating gas species; or (2) fill-and-pump-out cycling of each gas, accelerating the pump-out by lifting the cap to employ the large chamber volume as ballast. Downstream quadrupole mass spectrometry (QMS) sampling is applied for in-situ process sensing of tungsten ALD process. The QMS reveals essential surface reaction dynamics through real-time signals associated with byproduct generation as well as precursor introduction and depletion for each ALD half cycle, which are then used for process learning and optimization. More subtle interactions such as imperfect surface saturation and reactant dose interaction are also directly observed by QMS, indicating that ALD process is more complicated than the suggested layer-by-layer growth. By integrating in real-time the byproduct QMS signals over each exposure and plotting it against process cycle number, the deposition kinetics on the wafer is directly measured. For continuous ALD runs, the total integrated byproduct QMS signal in each ALD run is also linear to ALD film thickness, and therefore can be used for ALD film thickness metrology. The in-situ process sensing is also applied to HfO2 ALD process that is carried out in a furnace type ALD reactor. Precursor dose end-point control is applied to precisely control the precursor dose in each half cycle. Multiple process sensors, including quartz crystal microbalance (QCM) and QMS are used to provide real time process information. The

  6. Electromagnetic sensors for monitoring of scour and deposition processes at bridges and offshore wind turbines

    Science.gov (United States)

    Michalis, Panagiotis; Tarantino, Alessandro; Judd, Martin

    2014-05-01

    Recent increases in precipitation have resulted in severe and frequent flooding incidents. This has put hydraulic structures at high risk of failure due to scour, with severe consequences to public safety and significant economic losses. Foundation scour is the leading cause of bridge failures and one of the main climate change impacts to highway and railway infrastructure. Scour action is also being considered as a major risk for offshore wind farm developments as it leads to excessive excavation of the surrounding seabed. Bed level conditions at underwater foundations are very difficult to evaluate, considering that scour holes are often re-filled by deposited loose material which is easily eroded during smaller scale events. An ability to gather information concerning the evolution of scouring will enable the validation of models derived from laboratory-based studies and the assessment of different engineering designs. Several efforts have focused on the development of instrumentation techniques to measure scour processes at foundations. However, they are not being used routinely due to numerous technical and cost issues; therefore, scour continues to be inspected visually. This research project presents a new sensing technique, designed to measure scour depth variation and sediment deposition around the foundations of bridges and offshore wind turbines, and to provide an early warning of an impending structural failure. The monitoring system consists of a probe with integrated electromagnetic sensors, designed to detect the change in the surrounding medium around the foundation structure. The probe is linked to a wireless network to enable remote data acquisition. A developed prototype and a commercial sensor were evaluated to quantify their capabilities to detect scour and sediment deposition processes. Finite element modelling was performed to define the optimum geometric characteristics of the prototype scour sensor based on models with various permittivity

  7. French vertical flow constructed wetlands: a need of a better understanding of the role of the deposit layer.

    Science.gov (United States)

    Molle, Pascal

    2014-01-01

    French vertical flow constructed wetlands, treating directly raw wastewater, have become the main systems implemented for communities under 2,000 population equivalent in France. Like in sludge drying reed beds, an organic deposit layer is formed over time at the top surface of the filter. This deposit layer is a key factor in the performance of the system as it impacts hydraulic, gas transfers, filtration efficiency and water retention time. The paper discusses the role of this deposit layer on the hydraulic and biological behaviour of the system. It presents results from different studies to highlight the positive role of the layer but, as well, the difficulties in modelling this organic layer. As hydraulic, oxygen transfers, and biological activity are interlinked and impacted by the deposit layer, it seems essential to focus on its role (and its quantification) to find new developments of vertical flow constructed wetlands fed with raw wastewater.

  8. Process-structure-property relationships of micron thick gadolinium oxide films deposited by reactive electron beam-physical vapor deposition (EB-PVD)

    Science.gov (United States)

    Grave, Daniel A.

    Gadolinium oxide (Gd2O3) is an attractive material for solid state neutron detection due to gadolinium's high thermal neutron capture cross section. Development of neutron detectors based on Gd2 O3 requires sufficiently thick films to ensure neutron absorption. In this dissertation work, the process-structure-property relationships of micron thick Gd2O3 films deposited by reactive electron-beam physical vapor deposition (EB-PVD) were studied. Through a systematic design of experiments, fundamental studies were conducted to determine the effects of processing conditions such as deposition temperature, oxygen flow rate, deposition rate, and substrate material on Gd2O3 film crystallographic phase, texture, morphology, grain size, density, and surface roughness. Films deposited at high rates (> 5 A/s) were examined via x-ray diffraction (XRD) and Raman spectroscopy. Quantitative phase volume calculations were performed via a Rietveld refinement technique. All films deposited at high rates were found to be fully monoclinic or mixed cubic/monoclinic phase. Generally, increased deposition temperature and increased oxygen flow resulted in increased cubic phase volume. As film thickness increased, monoclinic phase volume increased. Grazing incidence x-ray diffraction (GIXRD) depth profiling analysis showed that cubic phase was only present under large incidence angle (large penetration depth) measurements, and after a certain point, only monoclinic phase was grown. This was confirmed by transmission electron microscopy (TEM) analysis with selected area diffraction (SAD). Based on this information, a large compressive stress was hypothesized to cause the formation of the monoclinic phase and this hypothesis was confirmed by demonstrating the existence of a stress induced phase transition. An experiment was designed to introduce compressive stress into the Gd2O 3 films via ion beam assisted deposition (IBAD). This allowed for systematic increase in compressive stress while

  9. Deposits on heat exchanging surfaces, causes in the bleaching process and countermeasures; Belaeggningar paa vaermevaexlare, orsaker i blekprocessen och aatgaerder

    Energy Technology Data Exchange (ETDEWEB)

    Bjurstroem, Henrik [AaF-Energi och Miljoe AB, Stockholm (Sweden); Staahl, Charlotte; Widell, Lars [AaF-Celpap AB, Stockholm (Sweden)

    2003-06-01

    Energy conservation in process industry implies to a large extent recovery of heat (or cold) from a process stream and its utilization for another process stream. The savings of energy that can be achieved depend on the process streams, but also on the efficiency of the heat exchange. A small driving temperature difference is a condition for an extensive recovery and a satisfactory preservation of its quality, i.e. its temperature. As process streams contain compounds or components that can precipitate and form deposits on heat exchanging surfaces, the recovery of heat is degraded. In the pulp and paper industry, two trends combine to increase the extent of fouling: a larger degree of closure for the process and a change in pH-profile caused by a switch to elementary chlorine free bleaching. In this study, the occurrence of deposits has been investigated for the mills that produce mechanical pulp and for the fiber line in mills producing chemical pulp. Deposits on the evaporator surfaces are treated in a parallel study. Except for some plants, deposits are not an important problem today. That does not mean that there has not been any problem or that problems will not occur. The origin of deposits lies in the chemistry of the process, but deposits have consequences for the thermal energy management. A list of possible actions in order to avoid deposits or to mitigate their consequences has been dressed in this report. They should be considered with the following order of priority: avoiding that the compounds that may form deposits enter at all the process, section 6.1; avoiding that these compounds form a deposit once they have entered the process, section 6.2; cleaning if nothing else helps or costs too much, section 6.3. Some of these methods are well known or are conventional changes in the processes. Some of these methods are less well proven or less well documented. In a longer time perspective, the kidney technology that is being developed could contribute to

  10. Process for depositing epitaxial alkaline earth oxide onto a substrate and structures prepared with the process

    Science.gov (United States)

    McKee, Rodney A.; Walker, Frederick J.

    1996-01-01

    A process and structure involving a silicon substrate utilize molecular beam epitaxy (MBE) and/or electron beam evaporation methods and an ultra-high vacuum facility to grow a layup of epitaxial alkaline earth oxide films upon the substrate surface. By selecting metal constituents for the oxides and in the appropriate proportions so that the lattice parameter of each oxide grown closely approximates that of the substrate or base layer upon which oxide is grown, lattice strain at the film/film or film/substrate interface of adjacent films is appreciably reduced or relieved. Moreover, by selecting constituents for the oxides so that the lattice parameters of the materials of adjacent oxide films either increase or decrease in size from one parameter to another parameter, a graded layup of films can be grown (with reduced strain levels therebetween) so that the outer film has a lattice parameter which closely approximates that of, and thus accomodates the epitaxial growth of, a pervoskite chosen to be grown upon the outer film.

  11. Pulsed Laser Deposition Processing of Improved Titanium Nitride Coatings for Implant Applications

    Science.gov (United States)

    Haywood, Talisha M.

    Recently surface coating technology has attracted considerable attention of researchers to develop novel coatings with enhanced functional properties such as hardness, biocompatibility, wear and corrosion resistance for medical devices and surgical tools. The materials currently being used for surgical implants include predominantly stainless steel (316L), cobalt chromium (Co-Cr), titanium and its alloys. Some of the limitations of these implants include improper mechanical properties, corrosion resistance, cytotoxicity and bonding with bone. One of the ways to improve the performance and biocompatibility of these implants is to coat their surfaces with biocompatible materials. Among the various coating materials, titanium nitride (TiN) shows excellent mechanical properties, corrosion resistance and low cytotoxicity. In the present work, a systematic study of pulsed laser ablation processing of TiN coatings was conducted. TiN thin film coatings were grown on commercially pure titanium (Ti) and stainless steel (316L) substrates at different substrate temperatures and different nitrogen partial pressures using the pulsed laser deposition (PLD) technique. Microstructural, surface, mechanical, chemical, corrosion and biological analysis techniques were applied to characterize the TiN thin film coatings. The PLD processed TiN thin film coatings showed improvements in mechanical strength, corrosion resistance and biocompatibility when compared to the bare substrates. The enhanced performance properties of the TiN thin film coatings were a result of the changing and varying of the deposition parameters.

  12. Macro controlling of copper oxide deposition processes and spray mode by using home-made fully computerized spray pyrolysis system

    Science.gov (United States)

    Essa, Mohammed Sh.; Chiad, Bahaa T.; Shafeeq, Omer Sh.

    2017-09-01

    Thin Films of Copper Oxide (CuO) absorption layer have been deposited using home-made Fully Computerized Spray Pyrolysis Deposition system FCSPD on glass substrates, at the nozzle to substrate distance equal to 20,35 cm, and computerized spray mode (continues spray, macro-control spray). The substrate temperature has been kept at 450 °c with the optional user can enter temperature tolerance values ± 5 °C. Also that fixed molar concentration of 0.1 M, and 2D platform speed or deposition platform speed of 4mm/s. more than 1000 instruction program code, and specific design of graphical user interface GUI to fully control the deposition process and real-time monitoring and controlling the deposition temperature at every 200 ms. The changing in the temperature has been recorded during deposition processes, in addition to all deposition parameters. The films have been characterized to evaluate the thermal distribution over the X, Y movable hot plate, the structure and optical energy gap, thermal and temperature distribution exhibited a good and uniform distribution over 20 cm2 hot plate area, X-ray diffraction (XRD) measurement revealed that the films are polycrystalline in nature and can be assigned to monoclinic CuO structure. Optical band gap varies from 1.5-1.66 eV depending on deposition parameter.

  13. Simultaneous Co-deposition of Zn-Mg Alloy Layers on Steel Strip by PVD Process

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Tae Yeob [POSCO Technical Research Laboratories, Gwangyang (Korea, Republic of); Goodenough, Mark [Strategic Marketing, Tata Steel, Warwickshire (United Kingdom)

    2011-12-15

    This is the first release of an interim report on the development of coating technology of Zn-Mg alloy layers on steel strip by EML-PVD (electromagnetic levitation - physical vapor deposition) process in an air-to-air type continuous PVD pilot plant. It intends to introduce a basic principle of the EML-PVD process together with the high speed PVD pilot plant built in Posco. Due to the agitation effect provided by the high frequency induction coil, simultaneous evaporation of Zn and Mg from a droplet could produce alloy coating layers with Mg content of 6% to 12% depending on the composition of the droplet inside the coil. For its superior corrosion resistance, Zn-Mg alloy coated steel would be a very promising material for automotive, electrical appliances, and construction applications.

  14. Electro-deposition painting process improvement of cab truck by Six Sigma concept

    Science.gov (United States)

    Kawitu, Kitiya; Chutima, Parames

    2017-06-01

    The case study company is a manufacturer of trucks and currently facing a high rework cost due to the thickness of the electro-deposited paint (EDP) of the truck cab is lower than standard. In addition, the process capability is very low. The Six Sigma concept consisting of 5 phases (DMAIC) is applied to determine new parameter settings for each significant controllable factor. After the improvement, EDP thickness of the truck cab increases from 17.88μ to 20μ (i.e. standard = 20 ± 3μ). Moreover, the process capability indexes (Cp and Cpk) are increased from 0.9 to 1.43, and from 0.27 to 1.43, respectively. This improvement could save the rework cost about 1.6M THB per year.

  15. Seed defective reduction in automotive Electro-Deposition Coating Process of truck cabin

    Science.gov (United States)

    Sonthilug, Aekkalag; Chutima, Parames

    2018-02-01

    The case study company is one of players in Thailand’s Automotive Industry who manufacturing truck and bus for both domestic and international market. This research focuses on a product quality problem about seed defects occurred in the Electro-Deposition Coating Process of truck cabin. The 5-phase of Six Sigma methodology including D-Define, M-Measure, A-Analyze, I-Improve, and C-Control is applied to this research to identify root causes of problem for setting new parameters of each significant factor. After the improvement, seed defects in this process is reduced from 9,178 defects per unit to 876 defects per unit (90% improvement)

  16. Simultaneous Co-deposition of Zn-Mg Alloy Layers on Steel Strip by PVD Process

    International Nuclear Information System (INIS)

    Kim, Tae Yeob; Goodenough, Mark

    2011-01-01

    This is the first release of an interim report on the development of coating technology of Zn-Mg alloy layers on steel strip by EML-PVD (electromagnetic levitation - physical vapor deposition) process in an air-to-air type continuous PVD pilot plant. It intends to introduce a basic principle of the EML-PVD process together with the high speed PVD pilot plant built in Posco. Due to the agitation effect provided by the high frequency induction coil, simultaneous evaporation of Zn and Mg from a droplet could produce alloy coating layers with Mg content of 6% to 12% depending on the composition of the droplet inside the coil. For its superior corrosion resistance, Zn-Mg alloy coated steel would be a very promising material for automotive, electrical appliances, and construction applications

  17. Mapping process and age of Quaternary deposits on Santa Rosa Island, Channel Islands National Park, California

    Science.gov (United States)

    Schmidt, K. M.; Minor, S. A.; Bedford, D.

    2016-12-01

    Employing a geomorphic process-age classification scheme, we mapped the Quaternary surficial geology of Santa Rosa (SRI) within the Channel Islands National Park. This detailed (1:12,000 scale) map represents upland erosional transport processes and alluvial, fluvial, eolian, beach, marine terrace, mass wasting, and mixed depositional processes. Mapping was motivated through an agreement with the National Park Service and is intended to aid natural resource assessments, including post-grazing disturbance recovery and identification of mass wasting and tectonic hazards. We obtained numerous detailed geologic field observations, fossils for faunal identification as age control, and materials for numeric dating. This GPS-located field information provides ground truth for delineating map units and faults using GIS-based datasets- high-resolution (sub-meter) aerial imagery, LiDAR-based DEMs and derivative raster products. Mapped geologic units denote surface processes and Quaternary faults constrain deformation kinematics and rates, which inform models of landscape change. Significant findings include: 1) Flights of older Pleistocene (>120 ka) and possibly Pliocene marine terraces were identified beneath younger alluvial and eolian deposits at elevations as much as 275 m above modern sea level. Such elevated terraces suggest that SRI was a smaller, more submerged island in the late Neogene and (or) early Pleistocene prior to tectonic uplift. 2) Structural and geomorphic observations made along the potentially seismogenic SRI fault indicate a protracted slip history during the late Neogene and Quaternary involving early normal slip, later strike slip, and recent reverse slip. These changes in slip mode explain a marked contrast in island physiography across the fault. 3) Many of the steeper slopes are dramatically stripped of regolith, with exposed bedrock and deeply incised gullies, presumably due effects related to past grazing practices. 4) Surface water presence is

  18. Microstructural Effects and Properties of Non-line-of-Sight Coating Processing via Plasma Spray-Physical Vapor Deposition

    Science.gov (United States)

    Harder, Bryan J.; Zhu, Dongming; Schmitt, Michael P.; Wolfe, Douglas E.

    2017-08-01

    Plasma spray-physical vapor deposition (PS-PVD) is a unique processing method that bridges the gap between conventional thermal spray and vapor phase methods, and enables highly tailorable coatings composed of a variety of materials in thin, dense layers or columnar microstructures with modification of the processing conditions. The strengths of this processing technique are material and microstructural flexibility, deposition speed, and potential for non-line-of-sight (NLOS) capability by vaporization of the feedstock material. The NLOS capability of PS-PVD is investigated here using yttria-stabilized zirconia and gadolinium zirconate, which are materials of interest for turbine engine applications. PS-PVD coatings were applied to static cylindrical substrates approximately 6-19 mm in diameter to study the coating morphology as a function of angle. In addition, coatings were deposited on flat substrates under various impingement configurations. Impingement angle had significant effects on the deposition mode, and microscopy of coatings indicated that there was a shift in the deposition mode at approximately 90° from incidence on the cylindrical samples, which may indicate the onset of more turbulent flow and PVD-like growth. Coatings deposited at non-perpendicular angles exhibited a higher density and nearly a 2× improvement in erosion performance when compared to coatings deposited with the torch normal to the surface.

  19. Deposition of Coating to Protect Waste Water Reservoir in Acidic Solution by Arc Thermal Spray Process

    Directory of Open Access Journals (Sweden)

    Han-Seung Lee

    2018-01-01

    Full Text Available The corrosion characteristics of 304 stainless steel (SS and titanium (Ti coatings deposited by the arc thermal spray process in pH 4 solution were assessed. The Ti-sprayed coating exhibits uniform, less porous, and adherent coating morphology compared to the SS-sprayed coating. The electrochemical study, that is, electrochemical impedance spectroscopy (EIS, revealed that as exposure periods to solution were increased, the polarization resistance (Rp decreased and the charge transfer resistance (Rct increased owing to corrosion of the metallic surface and simultaneously at the same time the deposition of oxide films/corrosion on the SS-sprayed surface, while Ti coating transformed unstable oxides into the stable phase. Potentiodynamic studies confirmed that both sprayed coatings exhibited passive tendency attributed due to the deposition of corrosion products on SS samples, whereas the Ti-sprayed sample formed passive oxide films. The Ti coating reduced the corrosion rate by more than six times compared to the SS coating after 312 h of exposure to sulfuric acid- (H2SO4- contaminated water solution, that is, pH 4. Scanning electron microscope (SEM results confirmed the uniform and globular morphology of the passive film on the Ti coating resulting in reduced corrosion. On the other hand, the corrosion products formed on SS-sprayed coating exhibit micropores with a net-like microstructure. X-ray diffraction (XRD revealed the presence of the composite oxide film on Ti-sprayed samples and lepidocrocite (γ-FeOOH on the SS-coated surface. The transformation of TiO and Ti3O into TiO2 (rutile and anatase and Ti3O5 after 312 h of exposure to H2SO4 acid reveals the improved corrosion resistance properties of Ti-sprayed coating.

  20. Investigation of the fluidized bed-chemical vapor deposition (FBCVD) process using CFD-DEM method

    International Nuclear Information System (INIS)

    Liu Malin; Liu Rongzheng; Wen Yuanyun; Liu Bing; Shao Youlin

    2014-01-01

    The CFD-DEM-CVD multiscale coupling simulation concept was proposed based on the mass/momentum/energy transfer involved in the FB-CVD process. The pyrolysis process of the reaction gas in the spouted bed can be simulated by CFD method, then the concentration field and velocity field can be extracted and coupled with the particle movement behavior which can be simulated by DEM. Particle deposition process can be described by the CVD model based on particle position, velocity and neighboring gas concentration. This multiscale coupling method can be implemented in the Fluent@-EDEM@ software with their UDF (User Definition Function) and API (Application Programming Interface). Base on the multiscale coupling concept, the criterion for evaluating FB-CVD process is given. At first, the volume in the coating furnace is divided into two parts (active coating area and non-active coating area) based on simulation results of chemical pyrolysis process. Then the residence time of all particles in the active coating area can be obtained using the CFD-DEM simulation method. The residence time distribution can be used as a criterion for evaluating the gas-solid contact efficiency and operation performance of the coating furnace. At last different coating parameters of the coating furnace are compared based on the proposed criterion. And also, the future research emphasis is discussed. (author)

  1. Understanding process behaviours in a large insurance company in Australia : a case study

    NARCIS (Netherlands)

    Suriadi, S.; Wynn, M.T.; Ouyang, C.; Hofstede, ter A.H.M.; van Dijk, N.J.; Salinesi, C.; Norrie, M.C.; Pastor, O.

    2013-01-01

    Having a reliable understanding about the behaviours, problems, and performance of existing processes is important in enabling a targeted process improvement initiative. Recently, there has been an increase in the application of innovative process mining techniques to facilitate evidence-based

  2. TC17 titanium alloy laser melting deposition repair process and properties

    Science.gov (United States)

    Liu, Qi; Wang, Yudai; Zheng, Hang; Tang, Kang; Li, Huaixue; Gong, Shuili

    2016-08-01

    Due to the high manufacturing cost of titanium compressor blisks, aero engine repairing process research has important engineering significance and economic value. TC17 titanium alloy is a rich β stable element dual α+β phase alloy whose nominal composition is Ti-5Al-2Sn-2Zr-4Mo-4Cr. It has high mechanical strength, good fracture toughness, high hardenability and a wide forging-temperature range. Through a surface response experiment with different laser powers, scanning speeds and powder feeding speeds, the coaxial powder feeding laser melting deposition repair process is studied for the surface circular groove defects. In this paper, the tensile properties, relative density, microhardness, elemental composition, internal defects and microstructure of the laser-repaired TC17 forging plate are analyzed. The results show that the laser melting deposition process could realize the form restoration of groove defect; tensile strength and elongation could reach 1100 MPa and 10%, which could reach 91-98% that of original TC17 wrought material; with the optimal parameters (1000 W-25 V-8 mm/s), the microhardness of the additive zone, the heat-affected zone and base material is evenly distributed at 370-390 HV500. The element content difference between the additive zone and base material is less than ±0.15%. Due to the existence of the pores 10 μm in diameter, the relative density could reach 99%, which is mainly inversely proportional to the powder feeding speed. The repaired zone is typically columnar and dendrite crystal, and the 0.5-1.5 mm-deep heat-affected zone in the groove interface is coarse equiaxial crystal.

  3. Scaling behavior and morphological properties of the interfaces obtained by the multilayer deposition process

    Energy Technology Data Exchange (ETDEWEB)

    Achik, I. [Laboratoire de Physique de la Matière Condensée, Université Hassan II-Mohammedia, Faculté des sciences Ben M' sik, Casablanca (Morocco); Boughaleb, Y., E-mail: yboughaleb@yahoo.fr [Laboratoire de Physique de la Matière Condensée, Université Hassan II-Mohammedia, Faculté des sciences Ben M' sik, Casablanca (Morocco); Université Chouaib Doukkali, Faculté des sciences, El Jadida (Morocco); Hassan II Academy of Science and Technology, Rabat (Morocco); Hader, A. [Laboratoire de Physique de la Matière Condensée, Université Hassan II-Mohammedia, Faculté des sciences Ben M' sik, Casablanca (Morocco); CRMEF Settat (Morocco); Sbiaai, K. [Université Chouaib Doukkali, Faculté des sciences, El Jadida (Morocco); Hajjaji, A. [Université Chouaib Doukkali, Ecole nationale des sciences appliquées, El Jadida (Morocco)

    2013-10-31

    The aim of the present work was to study numerically the scaling behavior and the morphological properties of the interfaces generated by the multilayer deposition process. We have noticed that, in the case where the ratio of the surface diffusion coefficient to the deposition rate reaches high values D/F > > 1, the interface consists of mound structures. By using the dynamic scaling, we have shown that the height–height correlation function scales with time t and length l as G(l,t) ∼ l{sup α}f(t/l{sup α/β}) with β = 0.25 ± 0.05 and α = 0.51 ± 0.02. These exponent values are equal to the ones predicted by the Edwards–Wilkinson approach. Besides, our results are in agreement with the growth system of Cu/Cu(100) at 300 K which has been characterized in more detail by a combined scanning tunneling microscopy and spot profile analysis — low energy electronic diffusion study. Moreover, by considering two different methods, we have examined the fractal aspect of the obtained interfaces. - Highlights: • The adlayer interfaces present mound morphologies. • The adlayer interfaces scale with the Family–Vicsek law. • The critical exponents (α, β) are in agreement with those of Edwards–Wilkinson approach.

  4. Scaling behavior and morphological properties of the interfaces obtained by the multilayer deposition process

    International Nuclear Information System (INIS)

    Achik, I.; Boughaleb, Y.; Hader, A.; Sbiaai, K.; Hajjaji, A.

    2013-01-01

    The aim of the present work was to study numerically the scaling behavior and the morphological properties of the interfaces generated by the multilayer deposition process. We have noticed that, in the case where the ratio of the surface diffusion coefficient to the deposition rate reaches high values D/F > > 1, the interface consists of mound structures. By using the dynamic scaling, we have shown that the height–height correlation function scales with time t and length l as G(l,t) ∼ l α f(t/l α/β ) with β = 0.25 ± 0.05 and α = 0.51 ± 0.02. These exponent values are equal to the ones predicted by the Edwards–Wilkinson approach. Besides, our results are in agreement with the growth system of Cu/Cu(100) at 300 K which has been characterized in more detail by a combined scanning tunneling microscopy and spot profile analysis — low energy electronic diffusion study. Moreover, by considering two different methods, we have examined the fractal aspect of the obtained interfaces. - Highlights: • The adlayer interfaces present mound morphologies. • The adlayer interfaces scale with the Family–Vicsek law. • The critical exponents (α, β) are in agreement with those of Edwards–Wilkinson approach

  5. Effect of voltage on the characteristics of magnesium-lanthanum deposits synthesized by an electrodeposition process

    Energy Technology Data Exchange (ETDEWEB)

    Sahli, M. [Laboratoire de Physique Energétique, Université de Constantine 1 (Algeria); Chetehouna, K.; Gascoin, N. [INSA-CVL, Univ. Orléans, PRISME, EA 4229, F-18020, Bourges (France); Bellel, N. [Laboratoire de Physique Energétique, Université de Constantine 1 (Algeria); Tadini, P., E-mail: tadini.pietro@gmail.com [INSA-CVL, Univ. Orléans, PRISME, EA 4229, F-18020, Bourges (France)

    2017-04-15

    This work deals with the characterization of magnesium-lanthanum powders deposits produced with an electrodeposition technique using an aqueous solution based on magnesium chloride and lanthanum(III) nitrate. In recent years, the interest for magnesium-based alloys is growing due to their potential use as solid state systems for hydrogen storage. This work is a preliminary study on the synthesis of magnesium-lanthanum powders oriented to their later evaluation in systems for hydrogen storage. Magnesium and Lanthanum are deposited on a copper plate used as a cathode. Chemical composition, structure and morphology are investigated by EDS, XRD, FTIR and SEM. The effect of voltage on powders characteristics is studied considering three values (3, 3.5 and 4 V). EDS analysis shows the presence of three major elements (Mg, La and O) with a little amount of Cl. The weight percentages of Mg and O increase whereas the one of La decreases with the growth of voltage. Morphological characterization reveals that heterogeneous chemical structures are formed on the surface of the electrode and the size of aggregates decreases with the increase of voltage. From the results of X-ray analysis the deposits reveal the significant presence of two phases: Mg(OH){sub 2} and La(OH){sub 3}. The peaks originating from the Mg(OH){sub 2} phase has a non-monotonic behavior and those of La(OH){sub 3} phase increase with the increase of voltage. FTIR analysis confirms the presence of the two phases identified in XRD diffractograms and exhibits that their corresponding transmittance values increase for higher voltage values. - Highlights: • Synthesis of magnesium-lanthanum deposits by an electrodeposition process. • Voltage effect is investigated using different physicochemical analysis techniques (EDS, XRD, FTIR and SEM). • The EDS analysis shows the presence of three major elements (Mg, La and O) and a little amount of Cl. • Two phases, namely Mg(OH){sub 2} and La(OH){sub 3} are

  6. Crystallization process of zircon and fergusonite during hydrothermal alteration in Nechalacho REE deposit, Thor Lake, Canada

    Science.gov (United States)

    Hoshino, M.; Watanabe, Y.; Murakami, H.; Kon, Y.; Tsunematsu, M.

    2012-04-01

    The core samples of two drill holes, which penetrate sub-horizontal mineralized horizons at Nechalacho REE deposit in the Proterozoic Thor Lake syenite, Canada, were studied in order to clarify magmatic and hydrothermal processes that enriched HFSE (e.g. Zr, Nb, Y and REE). Zircon is the most common REE minerals in Nechalacho REE deposit. The zircon is divided into five types as follows: Type-1 zircon occurs as single grain in phlogopite and the chondrite-normalized REE pattern is characterized by a steeply-rising slope from the LREE to the HREE with a positive Ce-anomaly and negative Eu-anomaly. This chemical characteristic is similar to that of igneous zircon. Type-2 zircon consists of HREE-rich magmatic porous core and LREE-Nb-F-rich hydrothermal rim. This type zircon is mostly included in phlogopite and fluorite, and occasionally in microcline. Type-3 zircon is characterized by euhedral to anhedral crystal, occurring in a complex intergrowth with REE fluorocarbonates. Type-3 zircons have high contents of REE, Nb and fluorine. Type-4 zircon consists of porous-core and -rim zones, but their chemical compositions are similar to each other. This type zircon is a subhedral crystal rimmed by fergusonite. Type-5 zircon is characterized by smaller, porous and subhedral to anhedral crystals. The interstices between small zircons are filled by fergusonite. Type-4 and -5 zircons show low REE and Nb contents. Occurrences of these five types of zircon are different according to the depth and degree of the alteration by hydrothermal solutions rich in F- and CO3 of the two drill holes, which permit a model for evolution of the zircon crystallization in Nechalacho REE deposit as follows: (1) type-1 (single magmatic zircon) is formed in miaskitic syenite. (2) LREE-Nb-F-rich hydrothermal zircon formed around HREE-rich magmatic zircon (type-2 zircon); (3) type-3 zircon crystallized thorough F and CO3-rich hydrothermal alteration of type-2 zircon which formed the complex

  7. Clay minerals in uraniferous deposit of Imouraren (Tim Mersoi basin, Niger): implications on genesis of deposit and on ore treatment process

    International Nuclear Information System (INIS)

    Billon, Sophie

    2014-01-01

    Nigerian uraniferous deposits are located in carboniferous and Jurassic formations of Tim Mersoi basin. AREVA is shareholder of 3 mine sites in this area: SOMAIR and COMINAK, both in exploitation since 1960's and IMOURAREN, 80 km further South, whose exploitation is planned for 2015. Mineralization of Imouraren deposit is included in the fluvial formation of Tchirezrine 2 (Jurassic), composed of channels and flood plains. Facies of channel in-fillings range from coarse sandstones to siltstones, while overflow facies are composed of analcimolites. Secondary mineralogy was acquired during 2 stages: 1- diagenesis, with formation of clay minerals, analcime, secondary quartz and albites, and 2- stage of fluids circulations, which induced alteration of detrital and diagenetic minerals, formation of new phases and uranium deposition. A mineralogical zoning, at the scale of deposit resulted from this alteration. The heterogeneity of Tchirezrine 2, at the level of both facies and mineralogy, is also evidenced during ore treatment, as ore reacts differently depending on its source, with sometimes problems of U recovery. Ore treatment tests showed that analcimes and chlorites were both penalizing minerals, because of 1- the sequestration of U-bearing minerals into analcimes, 2- their dissolution which trends to move away from U solubilization conditions (pH and Eh) and to form numerous sulfates, and 3- problems of percolation. A detection method of analcime-rich ores, based on infrared spectroscopy, was developed in order to optimize ore blending and so to reduce negative effects during ore treatment process. (author)

  8. Markov Processes: Exploring the Use of Dynamic Visualizations to Enhance Student Understanding

    Science.gov (United States)

    Pfannkuch, Maxine; Budgett, Stephanie

    2016-01-01

    Finding ways to enhance introductory students' understanding of probability ideas and theory is a goal of many first-year probability courses. In this article, we explore the potential of a prototype tool for Markov processes using dynamic visualizations to develop in students a deeper understanding of the equilibrium and hitting times…

  9. Once upon a time : Understanding team processes as relational event networks

    NARCIS (Netherlands)

    Leenders, R.T.A.J.; Contractor, N.; DeChurch, L.

    2016-01-01

    For as long as groups and teams have been the subject of scientific inquiry, researchers have been interested in understanding the relationships that form within them, and the pace at which these relationships develop and change. Despite this interest in understanding the process underlying the

  10. Understanding the design research process: The evolution of a professional development program in Indian slums

    NARCIS (Netherlands)

    McKenney, Susan; Raval, Harini; Pieters, Jules

    2011-01-01

    McKenney, S., Raval, H., & Pieters, J. (2011, 8-12 April). Understanding the design research process: The evolution of a professional development program in Indian slums. Presentation at AERA annual meeting, New Orleans.

  11. Understanding the design research process: The evolution of a professional development program in Indian slums

    OpenAIRE

    McKenney, Susan; Raval, Harini; Pieters, Jules

    2011-01-01

    McKenney, S., Raval, H., & Pieters, J. (2011, 8-12 April). Understanding the design research process: The evolution of a professional development program in Indian slums. Paper presentation at AERA annual meeting, New Orleans.

  12. Understanding the design research process: The evolution of a professional development program in Indian slums

    NARCIS (Netherlands)

    McKenney, Susan; Raval, Harini; Pieters, Jules

    2012-01-01

    McKenney, S., Raval, H., & Pieters, J. (2011, 8-12 April). Understanding the design research process: The evolution of a professional development program in Indian slums. Paper presentation at AERA annual meeting, New Orleans.

  13. Understanding the spatial formation and accumulation of fats, oils and grease deposits in the sewer collection system.

    Science.gov (United States)

    Dominic, Christopher Cyril Sandeep; Szakasits, Megan; Dean, Lisa O; Ducoste, Joel J

    2013-01-01

    Sanitary sewer overflows are caused by the accumulation of insoluble calcium salts of fatty acids, which are formed by the reaction between fats, oils and grease (FOG) and calcium found in wastewaters. Different sewer structural configurations (i.e., manholes, pipes, wet wells), which vary spatially, along with other obstructions (roots intrusion) and pipe deformations (pipe sags), may influence the detrimental buildup of FOG deposits. The purpose of this study was to quantify the spatial variation in FOG deposit formation and accumulation in a pilot-scale sewer collection system. The pilot system contained straight pipes, manholes, roots intrusion, and a pipe sag. Calcium and oil were injected into the system and operated at alkaline (pH = 10) and neutral (pH = 7) pH conditions. Results showed that solid accumulations were slightly higher at neutral pH. Fourier transform infrared (FTIR) analysis on the solids samples confirmed that the solids were indeed calcium-based fatty acid salts. However, the fatty acid profiles of the solids deviated from the profile found from FOG deposits in sewer systems, which were primarily saturated fatty acids. These results confirm the work done previously by researchers and suggest an alternative fate of unsaturated fatty acids that does not lead to their incorporation in FOG deposits in full-scale sewer systems.

  14. An analysis for understanding the process of textual deconstruction as a motivator for learning

    Directory of Open Access Journals (Sweden)

    Ana Delia Barrera Jiménez

    2010-03-01

    Full Text Available The present article aims to analyze the potential of the process of textual understanding and construction, for the development of motivation towards learning in teacher trainees for Preuniversities. In this direction it advocates in the first place, to understand the dynamic relationship established between the process of textual attribution and production and the motivational one, which provides the indispensable condition for promoting the work with the text from all the subjects in the curriculum.

  15. ON THE UNDERSTANDING OF AEOLIAN SEQUENCE STRATIGRAPHY: AN EXAMPLE FROM MIOCENE-PLIOCENE DEPOSITS IN PATAGONIA, ARGENTINA

    Directory of Open Access Journals (Sweden)

    CARLOS ZAVALA

    2001-07-01

    Full Text Available Upper Tertiary aeolian strata (Río Negro Formation outcrop in extensive sea cliffs at the Northeast of Patagonia. These outcrops show deposits corresponding to a complete suite of aeolian and aeolian related sub-environments, and also provide excellent exposures to analyse the sedimentology and internal architecture from a sequence stratigraphic point of view. Field studies, supplemented withline-drawings of oblique photographs, allowed the recognition of seven aeolian depositional sequences within the succession, each one bounded by regional super surfaces (or deflation surfaces. Internally these aeolian sequences display a cyclic recurrence in facies, that yields a tentative genetic model for their evolution. As documented from field examples, each basic aeolian depositional sequence was deposited during a single aggradational period, and is bounded by unconformities related to degradational periods. Degradational periods are regional deflationary events, that resulted in deep-scoured to flat surfaces, characterised by erosion / non deposition in which the only recognised accumulation is isolated and large angular blocks of fine-grained aggregates, interpreted as residual remnants of deposits of the previous sequence. Aggradational periods are characterised by a near- continuous accumulations responsible for the sequence building. Differences in the aeolian sediment budget to the area and the rising rate of water table control the related facies types, and allow to discriminateearly and late aggradational sub-periods. Early aggradational sub-periods form under conditions of relatively fast rising water tables associated with moderate aeolian sediment budget, thus resulting in the development of extended wet interduneslaterally associated with aeolian dunes and dry interdunes. During late aggradational sub-periods, the depositional surface outdistanced the water table, and aeolian dunes and dry interdunes tend to predominate. This sub

  16. Plasma-assisted ALD for the conformal deposition of SiO2 : process, material and electronic properties

    NARCIS (Netherlands)

    Dingemans, G.; Helvoirt, van C.A.A.; Pierreux, D.; Keuning, W.; Kessels, W.M.M.

    2012-01-01

    Plasma-assisted atomic layer deposition (ALD) was used to deposit SiO2 films in the temperature range of Tdep = 50–400°C on Si(100). H2Si[N(C2H5)2]2 and an O2 plasma were used as Si precursor and oxidant, respectively. The ALD growth process and material properties were characterized in detail.

  17. Compact Layers of Hybrid Halide Perovskites Fabricated via the Aerosol Deposition Process-Uncoupling Material Synthesis and Layer Formation.

    Science.gov (United States)

    Panzer, Fabian; Hanft, Dominik; Gujar, Tanaji P; Kahle, Frank-Julian; Thelakkat, Mukundan; Köhler, Anna; Moos, Ralf

    2016-04-08

    We present the successful fabrication of CH₃NH₃PbI₃ perovskite layers by the aerosol deposition method (ADM). The layers show high structural purity and compactness, thus making them suitable for application in perovskite-based optoelectronic devices. By using the aerosol deposition method we are able to decouple material synthesis from layer processing. Our results therefore allow for enhanced and easy control over the fabrication of perovskite-based devices, further paving the way for their commercialization.

  18. A model for understanding and learning of the game process of computer games

    DEFF Research Database (Denmark)

    Larsen, Lasse Juel; Majgaard, Gunver

    This abstract focuses on the computer game design process in the education of engineers at the university level. We present a model for understanding the different layers in the game design process, and an articulation of their intricate interconnectedness. Our motivation is propelled by our daily...... teaching practice of game design. We have observed a need for a design model that quickly can create an easily understandable overview over something as complex as the design processes of computer games. This posed a problem: how do we present a broad overview of the game design process and at the same...... time make sure that the students learn to act and reflect like game designers? We fell our game design model managed to just that end. Our model entails a guideline for the computer game design process in its entirety, and at same time distributes clear and easy understandable insight to a particular...

  19. Simulation of spatially dependent excitation rates and power deposition in RF discharges for plasma processing

    International Nuclear Information System (INIS)

    Kushner, M.J.; Anderson, H.M.; Hargis, P.J.

    1985-01-01

    In low pressure, radio frequency (RF) discharges of the type used in plasma processing of semiconductor materials, the rate of electron impact excitation and energy transfer processes depends upon both the phase of the RF excitation and position in the discharge. Electron impact collisions create radicals that diffuse or drift to the surfaces of interest where they are adsorbed or otherwise react. To the extent that these radicals have a finite lifetime, their transport time from point of creation to surface of interest is an important parameter. The spatial dependence of the rate of the initial electron impact collisions is therefore also an important parameter. The power that sustains the discharge is coupled into the system by two mechanisms: a high energy e-beam component of the electron distribution resulting from electrons falling through or being accelerated by the sheaths, and by joule heating in the body of the plasma. In this paper, the authors discuss the spatial dependence of excitation rates and the method of power deposition iin RF discharges of the type used for plasma processing

  20. Random covering of the circle: the configuration-space of the free deposition process

    Energy Technology Data Exchange (ETDEWEB)

    Huillet, Thierry [Laboratoire de Physique Theorique et Modelisation, CNRS-UMR 8089 et Universite de Cergy-Pontoise, 5 mail Gay-Lussac, 95031, Neuville sur Oise (France)

    2003-12-12

    Consider a circle of circumference 1. Throw at random n points, sequentially, on this circle and append clockwise an arc (or rod) of length s to each such point. The resulting random set (the free gas of rods) is a collection of a random number of clusters with random sizes. It models a free deposition process on a 1D substrate. For such processes, we shall consider the occurrence times (number of rods) and probabilities, as n grows, of the following configurations: those avoiding rod overlap (the hard-rod gas), those for which the largest gap is smaller than rod length s (the packing gas), those (parking configurations) for which hard rod and packing constraints are both fulfilled and covering configurations. Special attention is paid to the statistical properties of each such (rare) configuration in the asymptotic density domain when ns = {rho}, for some finite density {rho} of points. Using results from spacings in the random division of the circle, explicit large deviation rate functions can be computed in each case from state equations. Lastly, a process consisting in selecting at random one of these specific equilibrium configurations (called the observable) can be modelled. When particularized to the parking model, this system produces parking configurations differently from Renyi's random sequential adsorption model.

  1. The effect of modularity representation and presentation medium on the understandability of business process models in BPMN

    NARCIS (Netherlands)

    Turetken, Oktay; Rompen, Tessa; Vanderfeesten, Irene; Dikici, Ahmet; van Moll, Jan; La Rosa, M.; Loos, P.; Pastor, O.

    2016-01-01

    Many factors influence the creation of understandable business process models for an appropriate audience. Understandability of process models becomes critical particularly when a process is complex and its model is large in structure. Using modularization to represent such models hierarchically

  2. Understanding the creative processes of phenomenological research: The life philosophy of Løgstrup

    Science.gov (United States)

    Dreyer, Pia; Haahr, Anita; Martinsen, Bente

    2011-01-01

    The creative processes of understanding patients’ experiences in phenomenological research are difficult to articulate. Drawing on life philosophy as represented by the Danish philosopher K.E. Løgstrup (1905–1981), this article aims to illustrate Løgstrup's thinking as a way to elaborate the creation of cognition and understanding of patients’ experiences. We suggest that Løgstrup's thoughts on sensation can add new dimensions to an increased understanding of the creative process of phenomenological research, and that his thinking can be seen as an epistemological ground for these processes. We argue with Løgstrup that sense-based impressions can facilitate an flash of insight, i.e., the spontaneous, intuitive flash of an idea. Løgstrup stresses that an “flash of insight” is an important source in the creation of cognition and understanding. Relating to three empirical phenomenological studies of patients’ experiences, we illustrate how the notions of impression and flash of insight can add new dimensions to increased understanding of the creative processes in phenomenological research that have previously not been discussed. We illustrate that sense-based impressions can facilitate creative flash of insights that open for understanding of patients’ experiences in the research process as well as in the communication of the findings. The nature of impression and flash of insight and their relevance in the creation of cognition and understanding contributes to the sparse descriptions in the methodological phenomenological research literature of the creative processes of this research. An elaboration of the creative processes in phenomenological research can help researchers to articulate these processes. Thus, Løgstrup's life philosophy has proven to be valuable in adding new dimensions to phenomenological empirical research as well as embracing lived experience. PMID:22076123

  3. Understanding the creative processes of phenomenological research: The life philosophy of Løgstrup

    Directory of Open Access Journals (Sweden)

    Annelise Norlyk

    2011-11-01

    Full Text Available The creative processes of understanding patients’ experiences in phenomenological research are difficult to articulate. Drawing on life philosophy as represented by the Danish philosopher K.E. Løgstrup (1905–1981, this article aims to illustrate Løgstrup's thinking as a way to elaborate the creation of cognition and understanding of patients’ experiences. We suggest that Løgstrup's thoughts on sensation can add new dimensions to an increased understanding of the creative process of phenomenological research, and that his thinking can be seen as an epistemological ground for these processes. We argue with Løgstrup that sense-based impressions can facilitate an flash of insight, i.e., the spontaneous, intuitive flash of an idea. Løgstrup stresses that an “flash of insight” is an important source in the creation of cognition and understanding. Relating to three empirical phenomenological studies of patients’ experiences, we illustrate how the notions of impression and flash of insight can add new dimensions to increased understanding of the creative processes in phenomenological research that have previously not been discussed. We illustrate that sense-based impressions can facilitate creative flash of insights that open for understanding of patients’ experiences in the research process as well as in the communication of the findings. The nature of impression and flash of insight and their relevance in the creation of cognition and understanding contributes to the sparse descriptions in the methodological phenomenological research literature of the creative processes of this research. An elaboration of the creative processes in phenomenological research can help researchers to articulate these processes. Thus, Løgstrup's life philosophy has proven to be valuable in adding new dimensions to phenomenological empirical research as well as embracing lived experience.

  4. Understanding the creative processes of phenomenological research: The life philosophy of Løgstrup.

    Science.gov (United States)

    Norlyk, Annelise; Dreyer, Pia; Haahr, Anita; Martinsen, Bente

    2011-01-01

    The creative processes of understanding patients' experiences in phenomenological research are difficult to articulate. Drawing on life philosophy as represented by the Danish philosopher K.E. Løgstrup (1905-1981), this article aims to illustrate Løgstrup's thinking as a way to elaborate the creation of cognition and understanding of patients' experiences. We suggest that Løgstrup's thoughts on sensation can add new dimensions to an increased understanding of the creative process of phenomenological research, and that his thinking can be seen as an epistemological ground for these processes. We argue with Løgstrup that sense-based impressions can facilitate an flash of insight, i.e., the spontaneous, intuitive flash of an idea. Løgstrup stresses that an "flash of insight" is an important source in the creation of cognition and understanding. Relating to three empirical phenomenological studies of patients' experiences, we illustrate how the notions of impression and flash of insight can add new dimensions to increased understanding of the creative processes in phenomenological research that have previously not been discussed. We illustrate that sense-based impressions can facilitate creative flash of insights that open for understanding of patients' experiences in the research process as well as in the communication of the findings. The nature of impression and flash of insight and their relevance in the creation of cognition and understanding contributes to the sparse descriptions in the methodological phenomenological research literature of the creative processes of this research. An elaboration of the creative processes in phenomenological research can help researchers to articulate these processes. Thus, Løgstrup's life philosophy has proven to be valuable in adding new dimensions to phenomenological empirical research as well as embracing lived experience.

  5. Plasma and process characterization of high power magnetron physical vapor deposition with integrated plasma equipment--feature profile model

    International Nuclear Information System (INIS)

    Zhang Da; Stout, Phillip J.; Ventzek, Peter L.G.

    2003-01-01

    High power magnetron physical vapor deposition (HPM-PVD) has recently emerged for metal deposition into deep submicron features in state of the art integrated circuit fabrication. However, the plasma characteristics and process mechanism are not well known. An integrated plasma equipment-feature profile modeling infrastructure has therefore been developed for HPM-PVD deposition, and it has been applied to simulating copper seed deposition with an Ar background gas for damascene metalization. The equipment scale model is based on the hybrid plasma equipment model [M. Grapperhaus et al., J. Appl. Phys. 83, 35 (1998); J. Lu and M. J. Kushner, ibid., 89, 878 (2001)], which couples a three-dimensional Monte Carlo sputtering module within a two-dimensional fluid model. The plasma kinetics of thermalized, athermal, and ionized metals and the contributions of these species in feature deposition are resolved. A Monte Carlo technique is used to derive the angular distribution of athermal metals. Simulations show that in typical HPM-PVD processing, Ar + is the dominant ionized species driving sputtering. Athermal metal neutrals are the dominant deposition precursors due to the operation at high target power and low pressure. The angular distribution of athermals is off axis and more focused than thermal neutrals. The athermal characteristics favor sufficient and uniform deposition on the sidewall of the feature, which is the critical area in small feature filling. In addition, athermals lead to a thick bottom coverage. An appreciable fraction (∼10%) of the metals incident to the wafer are ionized. The ionized metals also contribute to bottom deposition in the absence of sputtering. We have studied the impact of process and equipment parameters on HPM-PVD. Simulations show that target power impacts both plasma ionization and target sputtering. The Ar + ion density increases nearly linearly with target power, different from the behavior of typical ionized PVD processing. The

  6. Process understanding on high shear granulated lactose agglomerates during and after drying

    NARCIS (Netherlands)

    Nieuwmeyer, F.J.S.

    2009-01-01

    In 2001 the FDA launched the Process Analytical Technology initiative as a response to the growing public and industrial awareness that there is a lack of process understanding required to have an optimal control of pharmaceutical manufacturing. The current research project was initiated based upon

  7. Differentiating Processes of Control and Understanding in the Early Development of Emotion and Cognition

    Science.gov (United States)

    Blankson, A. Nayena; O'Brien, Marion; Leerkes, Esther M.; Marcovitch, Stuart; Calkins, Susan D.

    2012-01-01

    In this study, we examined the hypothesis that preschoolers' performance on emotion and cognitive tasks is organized into discrete processes of control and understanding within the domains of emotion and cognition. Additionally, we examined the relations among component processes using mother report, behavioral observation, and physiological…

  8. Chemistry teachers’ understanding of science process skills in relation of science process skills assessment in chemistry learning

    Science.gov (United States)

    Hikmah, N.; Yamtinah, S.; Ashadi; Indriyanti, N. Y.

    2018-05-01

    A Science process skill (SPS) is a fundamental scientific method to achieve good knowledge. SPS can be categorized into two levels: basic and integrated. Learning SPS helps children to grow as individuals who can access knowledge and know how to acquire it. The primary outcomes of the scientific process in learning are the application of scientific processes, scientific reasoning, accurate knowledge, problem-solving, and understanding of the relationship between science, technology, society, and everyday life’s events. Teachers’ understanding of SPS is central to the application of SPS in a learning process. Following this point, this study aims to investigate the high school chemistry teachers’ understanding of SPS pertains to their assessment of SPS in chemistry learning. The understanding of SPS is measured from the conceptual and operational aspects of SPS. This research uses qualitative analysis method, and the sample consists of eight chemistry teachers selected by random sampling. A semi-structured interview procedure is used to collect the data. The result of the analysis shows that teachers’ conceptual and operational understanding of SPS is weak. It affects the accuracy and appropriateness of the teacher’s selection of SPS assessment in chemistry learning.

  9. On the Deposition Equilibrium of Carbon Nanotubes or Graphite in the Reforming Processes of Lower Hydrocarbon Fuels

    Directory of Open Access Journals (Sweden)

    Zdzisław Jaworski

    2017-11-01

    Full Text Available The modeling of carbon deposition from C-H-O reformates has usually employed thermodynamic data for graphite, but has rarely employed such data for impure filamentous carbon. Therefore, electrochemical data for the literature on the chemical potential of two types of purified carbon nanotubes (CNTs are included in the study. Parameter values determining the thermodynamic equilibrium of the deposition of either graphite or CNTs are computed for dry and wet reformates from natural gas and liquefied petroleum gas. The calculation results are presented as the atomic oxygen-to-carbon ratio (O/C against temperature (200 to 100 °C for various pressures (1 to 30 bar. Areas of O/C for either carbon deposition or deposition-free are computed, and indicate the critical O/C values below which the deposition can occur. Only three types of deposited carbon were found in the studied equilibrium conditions: Graphite, multi-walled CNTs, and single-walled CNTs in bundles. The temperature regions of the appearance of the thermodynamically stable forms of solid carbon are numerically determined as being independent of pressure and the analyzed reactants. The modeling indicates a significant increase in the critical O/C for the deposition of CNTs against that for graphite. The highest rise in the critical O/C, of up to 290% at 30 bar, was found for the wet reforming process.

  10. 252Cf-source-correlated transmission measurements for uranyl fluoride deposit in a 24-in.-OD process pipe

    International Nuclear Information System (INIS)

    Uckan, T.; Mihalczo, J.T.; Valentine, T.E.; Mullens, J.A.

    1998-01-01

    Characterization of a hydrated uranyl fluoride (UO 2 F 2 ·nH 2 O) deposit in a 17-ft-long, 24-in.-OD process pipe at the former Oak Ridge Gaseous Diffusion Plant was successfully performed by using 252 Cf-source-correlated time-of-flight (TOF) transmission measurements. These measurements of neutrons and gamma rays through the pipe from an external 2521 Cf fission source were used to measure the deposit profile and its distribution along the pipe, the hydration (or H/U), and the total uranium mass. The measurements were performed with a source in an ionization chamber on one side of the pipe and detectors on the other. Scanning the pipe vertically and horizontally produced a spatial and time-dependent radiograph of the deposit in which transmitted gamma rays and neutrons were separated in time. The cross-correlation function between the source and the detector was measured with the Nuclear Weapons Identification System. After correcting for pipe effects, the deposit thickness was determined from the transmitted neutrons and H/U from the gamma rays. Results were consistent with a later intrusive observation of the shape and the color of the deposit; i.e., the deposit was annular and was on the top of the pipe at some locations, demonstrating the usefulness of this method for deposit characterization

  11. [Anthropology, ethnography, and narrative: intersecting paths in understanding the processes of health and sickness].

    Science.gov (United States)

    Costa, Gabriela M C; Gualda, Dulce M R

    2010-12-01

    The article discusses anthropology, ethnographic method, and narrative as possible ways of coming to know subjects' experiences and the feelings they attribute to them. From an anthropological perspective, the sociocultural universe is taken as a point of reference in understanding the meaning of the processes of health and sickness, using a dense ethnographic description from an interpretivist analytical approach. In this context, narratives afford possible paths to understanding how subjective human experiences are shared and how behavior is organized, with a special focus on meaning, the process by which stories are produced, relations between narrator and other subjects, processes of knowledge, and the manifold ways in which experience can be captured.

  12. The treatment process of understanding scientific texts: A necessity in the current Cuban university

    Directory of Open Access Journals (Sweden)

    Yanet María Guerra Santana

    2016-06-01

    Full Text Available This work has as main purpose to emphasize the need for treatment of the process of understanding scientific texts in the university today, for the development of science and technology has placed at the forefront in every race the problem of processing scientific information. The ability to produce scientific texts has been somewhat spontaneity in the curriculum of professional training in Cuban university, which has resulted in some professionals do not yet have linguistic, discursive and strategic " tools " best to communicate the style of science, hence the study of the process of understanding of scientific texts in undergraduate currently constitute a need in our universities.

  13. Numerical analysis of tungsten erosion and deposition processes under a DEMO divertor plasma

    Directory of Open Access Journals (Sweden)

    Yuki Homma

    2017-08-01

    Full Text Available Erosion reduction of tungsten (W divertor target is one of the most important research subjects for the DEMO fusion reactor design, because the divertor target has to sustain large fluence of incident particles, composed mainly of fuel ions and seeded impurities, during year-long operation period. Rate of net erosion and deposition on outer divertor target has been studied by using the integrated SOL/divertor plasma code SONIC and the kinetic full-orbit impurity transport code IMPGYRO. Two background plasmas have been used: one is lower density ni and higher temperature case and the other is higher ni and lower temperature case. Net erosion has been seen in the lower ni case. But in the higher ni case, the net erosion has been almost suppressed due to increased return rate and reduced self-sputtering yield. Following two factors are important to understand the net erosion formation: (i ratio of the 1st ionization length of sputtered W atom to the Larmor gyro radius of W+ ion, (ii balance between the friction force and the thermal force exerted on W ions. DEMO divertor design should take into account these factors to prevent target erosion.

  14. Gravitational, erosional and depositional processes on volcanic ocean islands: Insights from the submarine morphology of Madeira Archipelago

    Science.gov (United States)

    Quartau, Rui; Ramalho, Ricardo S.; Madeira, José; Santos, Rúben; Rodrigues, Aurora; Roque, Cristina; Carrara, Gabriela; Brum da Silveira, António

    2018-01-01

    The submarine flanks of volcanic ocean islands are shaped by a variety of physical processes. Whilst volcanic constructional processes are relatively well understood, the gravitational, erosional and depositional processes that lead to the establishment of large submarine tributary systems are still poorly comprehended. Until recently, few studies have offered a comprehensive source-to-sink approach, linking subaerial morphology with near-shore shelf, slope and far-field abyssal features. In particular, few studies have addressed how different aspects of the subaerial part of the system (island height, climate, volcanic activity, wave regime, etc.) may influence submarine flank morphologies. We use multibeam bathymetric and backscatter mosaics of an entire archipelago - Madeira - to investigate the development of their submarine flanks. Crucially, this dataset extends from the nearshore to the deep sea, allowing a solid correlation between submarine morphologies with the physical and geological setting of the islands. In this study we also established a comparison with other island settings, which allowed us to further explore the wider implications of the observations. The submarine flanks of the Madeira Archipelago are deeply dissected by large landslides, most of which also affected the subaerial edifices. Below the shelf break, landslide chutes extend downslope forming poorly defined depositional lobes. Around the islands, a large tributary system composed of gullies and channels has formed where no significant rocky/ridge outcrops are present. In Madeira Island these were likely generated by turbidity currents that originated as hyperpycnal flows, whilst on Porto Santo and Desertas their origin is attributed to storm-induced offshore sediment transport. At the lower part of the flanks (-3000 to -4300 m), where seafloor gradients decrease to 0.5°-3°, several scour and sediment wave fields are present, with the former normally occurring upslope of the latter

  15. The chemical evolution of a travertine-depositing stream: Geochemical processes and mass transfer reactions

    Science.gov (United States)

    Lorah, Michelle M.; Herman, Janet S.

    1988-01-01

    This field study focuses on quantitatively defining the chemical changes occurring in Falling Spring Creek, a travertine-depositing stream located in Alleghany County, Virginia. The processes of CO2outgassing and calcite precipitation or dissolution control the chemical evolution of the stream. The observed chemical composition of the water was used with the computerized geochemical model WATEQF to calculate aqueous speciation, saturation indices, and CO2 partial pressure values. Mass balance calculations were performed to obtain mass transfers of CO2 and calcite. Reaction times, estimated from stream discharge, were used with the mass transfer results to calculate rates of CO2, outgassing and calcite precipitation between consecutive sampling points. The stream, which is fed by a carbonate spring, is supersaturated with respect to CO2 along the entire 5.2-km flow path. Outgassing of CO2 drives the solution to high degrees of supersaturation with respect to calcite. Metabolic uptake of CO2 by photosynthetic plants is insignificant, because the high supply rate of dissolved carbon dioxide and the extreme agitation of the stream at waterfalls and rapids causes a much greater amount of inorganic CO2 outgassing to occur. Calcite precipitation is kinetically inhibited until near the crest of a 20-m vertical waterfall. Calcite precipitation rates then reach a maximum at the waterfall where greater water turbulence allows the most rapid escape of CO2. Physical evidence for calcite precipitation exists in the travertine deposits which are first observed immediately above the waterfall and extend for at least 1.0 km below the falls. Net calcite precipitation occurs at all times of the year but is greatest during low-flow conditions in the summer and early fall.

  16. Depositional and diagenetic processes of Qa Khanna playa, North Jordan basaltic plateau, Jordan

    Science.gov (United States)

    Howari, F. M.; Banat, K. M.; Abu-Salha, Y. A.

    2010-09-01

    The present study explored mineral occurrences and sediment characteristics of playas from northern Jordan and explained depositional and diagenetic processes as reflected from bulk chemistry and sedimentary structures. Mudcracks of different sizes and shape patterns, laminations, intersediment vesicles, and bioturbation pipes are the main sedimentary structures. Plagioclase, olivine, orthopyroxene, nepheline and other opaque minerals are all of detrital origin, and are derived from the basaltic bedrocks surrounding the studied playa. Evaporites are very rare; they are represented only by trace amounts of gypsum. The identified clay minerals in the clay fraction of the studied sediments, arranged according to their decreasing abundances are palygorskite, illite, kaolinite, smectite and chlorite. The elemental abundances were tied to clay, CaCO 3 and nearby igneous rocks. The type of clay minerals, the high pH values of the studied sediments, and the considerable incorporation of Mg and K in palygorskite and illite respectively, may strongly reflect a high evaporative and alkaline environment under arid to semi-arid conditions in an ephemeral lake of the Qa Khanna. Concentrations and distributions of both major and trace elements are essentially controlled by the clay mineralogy and the calcium carbonate content; Ca is mainly incorporated in the CaCO 3, which is either generated authigenically or by aeolian deposition. Fe and K are incorporated and fixed by illite under an evaporative and alkaline environment. Mg is incorporated in palygorskite while Mn is adsorbed on various clay minerals. Sr substitutes for Ca in the aeolian CaCO 3 and its presence in the studied sediments is independent of the prevailing conditions during the playa evolution. Rb substitutes for K in illite under the prevailing chemical conditions in the studied playa.

  17. Ripple scalings in geothermal facilities, a key to understand the scaling process

    Science.gov (United States)

    Köhl, Bernhard; Grundy, James; Baumann, Thomas

    2017-04-01

    Scalings are a widespread problem among geothermal plants which exploit the Malm Aquifer in the Bavarian Molasse Zone. They effect the technical and economic efficiency of geothermal plants. The majority of the scalings observed at geothermal facilities exploring the Malm aquifer in the Bavarian Molasse Basin are carbonates. They are formed due to a disruption of the lime-carbonic-acid equilibrium during production caused by degassing of CO2. These scalings are found in the production pipes, at the pumps and at filters and can nicely be described using existing hydrogeochemical models. This study proposes a second mechanism for the formation of scalings in ground-level facilities. We investigated scalings which accumulated at the inlet to the heat exchanger. Interestingly, the scalings were recovered after the ground level facilities had been cleaned. The scalings showed distinct ripple structures, which is likely a result of solid particle deposition. From the ripple features the the flow conditions during their formation were calculated based on empirical equations (Soulsby, 2012). The calculations suggest that the deposits were formed during maintenance works. Thin section images of the sediments indicate a two-step process: deposition of sediment grains, followed by stabilization with a calcite layer. The latter likely occured during maintenance. To prevent this type of scalings blocking the heat exchangers, the maintenance procedure has to be revised. References: Soulsby, R. L.; Whitehouse, R. J. S.; Marten, K. V.: Prediction of time-evolving sand ripples in shelf seas. Continental Shelf Research 2012, 38, 47-62

  18. The influence of annealing on yttrium oxide thin film deposited by reactive magnetron sputtering: Process and microstructure

    Directory of Open Access Journals (Sweden)

    Y. Mao

    2017-01-01

    Full Text Available Yttrium oxide thin films were prepared by reactive magnetron sputtering in different deposition condition with various oxygen flow rates. The annealing influence on the yttrium oxide film microstructure is investigated. The oxygen flow shows a hysteresis behavior on the deposition rate. With a low oxygen flow rate, the so called metallic mode process with a high deposition rate (up to 1.4µm/h was achieved, while with a high oxygen flow rate, the process was considered to be in the poisoned mode with an extremely low deposition rate (around 20nm/h. X-ray diffraction (XRD results show that the yttrium oxide films that were produced in the metallic mode represent a mixture of different crystal structures including the metastable monoclinic phase and the stable cubic phase, while the poisoned mode products show a dominating monoclinic phase. The thin films prepared in metallic mode have relatively dense structures with less porosity. Annealing at 600 °C for 15h, as a structure stabilizing process, caused a phase transformation that changes the metastable monoclinic phase to stable cubic phase for both poisoned mode and metallic mode. The composition of yttrium oxide thin films changed from nonstoichiometric to stoichiometric together with a lattice parameter variation during annealing process. For the metallic mode deposition however, cracks were formed due to the thermal expansion coefficient difference between thin film and the substrate material which was not seen in poisoned mode deposition. The yttrium oxide thin films that deposited in different modes give various application options as a nuclear material.

  19. Experience in oil field processing of gas and condensate at the Shatlyk deposits

    Energy Technology Data Exchange (ETDEWEB)

    Dalmatov, V.V.; Chernikov, Ye.I.; Govorun, V.P.; Turevskiy, Ye.N.

    1983-01-01

    The operation of installations for preparing gas are analyzed, along with the operation of individual technological devices at the Shatlyk deposit, the basic things which hinder the support of the designed low temperature conditions are shown and recommendations for standardizing the operation of the technological installations are given. Experience in the operation of the gas preparation installations at the Shatlyk deposit is recommended for use in deposits being introduced into development.

  20. Beneficial effects of laser irradiation on the deposition process of diamond/Ni60 composite coating with cold spray

    Energy Technology Data Exchange (ETDEWEB)

    Yao, Jianhua, E-mail: laser@zjut.edu.cn; Yang, Lijing; Li, Bo; Li, Zhihong

    2015-03-01

    Graphical abstract: - Highlights: • The hard Ni-based alloy powder as matrix in diamond composite coating was studied. • The influence of laser on diamond distribution of composite coating was analyzed. • The graphitization of diamond was prohibited in supersonic laser deposition process. • The abrasion mechanisms of diamond/Ni60 composite coating were discussed. - Abstract: Although cold spray process has many unique advantages over other coating techniques, it has difficulties in depositing hard materials. This article presents a study in the beneficial effects of laser irradiation on the fabrication process of diamond/Ni60 composite coating using cold spray. The focus of this research is on the comparison between the composite coatings produced with laser cladding (LC) and with supersonic laser deposition (SLD), with respect to diamond graphitization and tribological properties, thus to demonstrate the beneficial effects of laser irradiation on the cold spray process. The influence of deposition temperature on the coating characteristics, such as deposition efficiency, diamond volume fraction, microstructure and phase is also investigated. The tribological properties of the diamond/Ni60 composite coating produced with SLD are determined using a pin-on-disc tribometer, along with the diamond/Ni60 coating produced using LC with the optimal process parameters for comparison. The experimental results show that with the assistance of laser irradiation, diamond/Ni60 composite coating can be successfully deposited using cold spray; the obtained coating is superior to that processed with LC, because SLD can suppress the graphitization of the diamond particles. The diamond/Ni60 composite coating fabricated with SLD has much better tribological properties than the LC coating.

  1. Acidic deposition: State of science and technology. Report 2. Atmospheric processes research and process model development. Final report

    International Nuclear Information System (INIS)

    Hicks, B.B.; Draxler, R.R.; Albritton, D.L.; Fehsenfeld, F.C.; Davidson, C.I.

    1990-10-01

    The document represents an attempt to put together, in one place, a summary of the present state of knowledge concerning those processes that affect air concentrations of acidic and acidifying pollutants, during their transport, from emission to deposition. It is not intended to be an all-encompassing review of the entire breadth of each of the contributing disciplines, but instead focuses on those areas where the state of science has improved over the last decade--the period of the National Acid Precipitation Assessment Program. The discussion is not limited to NAPAP activities, although it is clear that the products of NAPAP research are perhaps given greater attention than are the results obtained elsewhere. This bias is partially intentional, since it is the INTEGRATED ASSESSMENT that is currently being prepared by NAPAP that constitutes the 'client' for the material presented here. The integrated assessment pay attention to the North American situation alone, and hence the present work gives greatest attention to the North American case, but with awareness of the need to place this particular situation in the context of the rest of the world

  2. Silicon oxide barrier films deposited on PET foils in pulsed plasmas: influence of substrate bias on deposition process and film properties

    International Nuclear Information System (INIS)

    Steves, S; Bibinov, N; Awakowicz, P; Ozkaya, B; Liu, C-N; Ozcan, O; Grundmeier, G

    2013-01-01

    A widely used plastic for packaging, polyethylene terephtalate (PET) offers limited barrier properties against gas permeation. For many applications of PET (from food packaging to micro electronics) improved barrier properties are essential. A silicon oxide barrier coating of PET foils is applied by means of a pulsed microwave driven low-pressure plasma. While the adjustment of the microwave power allows for a control of the ion production during the plasma pulse, a substrate bias controls the energy of ions impinging on the substrate. Detailed analysis of deposited films applying oxygen permeation measurements, x-ray photoelectron spectroscopy and atomic force microscopy are correlated with results from plasma diagnostics describing the deposition process. The influence of a change in process parameters such as gas mixture and substrate bias on the gas temperature, electron density, mean electron energy, ion energy and the atomic oxygen density is studied. An additional substrate bias results in an increase in atomic oxygen density up to a factor of 6, although plasma parameter such as electron density of n e = 3.8 ± 0.8 × 10 17 m −3 and electron temperature of k B T e = 1.7 ± 0.1 eV are unmodified. It is shown that atomic oxygen densities measured during deposition process higher than n O = 1.8 × 10 21 m −3 yield in barrier films with a barrier improvement factor up to 150. Good barrier films are highly cross-linked and show a smooth morphology. (paper)

  3. Sedimentary processes and depositional environments of the Horn River Shale in British Columbia, Canada

    Science.gov (United States)

    Yoon, Seok-Hoon; Koh, Chang-Seong; Joe, Young-Jin; Woo, Ju-Hwan; Lee, Hyun-Suk

    2017-04-01

    The Horn River Basin in the northeastern British Columbia, Canada, is one of the largest unconventional gas accumulations in North America. It consists mainly of Devonian shales (Horn River Formation) and is stratigraphically divided into three members, the Muskwa, Otterpark and Evie in descending order. This study focuses on sedimentary processes and depositional environments of the Horn River shale based on sedimentary facies analysis aided by well-log mineralogy (ECS) and total organic carbon (TOC) data. The shale formation consists dominantly of siliceous minerals (quartz, feldspar and mica) and subordinate clay mineral and carbonate materials, and TOC ranging from 1.0 to 7.6%. Based on sedimentary structures and micro texture, three sedimentary facies were classified: homogeneous mudstone (HM), indistinctly laminated mudstone (ILM), and planar laminated mudstone (PLM). Integrated interpretation of the sedimentary facies, lithology and TOC suggests that depositional environment of the Horn River shale was an anoxic quiescent basin plain and base-of-slope off carbonate platform or reef. In this deeper marine setting, organic-rich facies HM and ILM, dominant in the Muskwa (the upper part of the Horn River Formation) and Evie (the lower part of the Horn River Formation) members, may have been emplaced by pelagic to hemipelagic sedimentation on the anoxic sea floor with infrequent effects of low-density gravity flows (turbidity currents or nepheloid flows). In the other hand, facies PLM typifying the Otterpark Member (the middle part of the Horn River Formation) suggests more frequent inflow of bottom-hugging turbidity currents punctuating the hemipelagic settling of the background sedimentation process. The stratigraphic change of sedimentary facies and TOC content in the Horn River Formation is most appropriately interpreted to have been caused by the relative sea-level change, that is, lower TOC and frequent signal of turbidity current during the sea

  4. A Process-Philosophical Understanding of Organizational Learning as "Wayfinding": Process, Practices and Sensitivity to Environmental Affordances

    Science.gov (United States)

    Chia, Robert

    2017-01-01

    Purpose: This paper aims to articulate a practice-based, non-cognitivist approach to organizational learning. Design/methodology/approach: This paper explores the potential contribution of a process-based "practice turn" in social theory for understanding organizational learning. Findings: In complex, turbulent environments, robust…

  5. Six sigma: process of understanding the control and capability of ranitidine hydrochloride tablet.

    Science.gov (United States)

    Chabukswar, Ar; Jagdale, Sc; Kuchekar, Bs; Joshi, Vd; Deshmukh, Gr; Kothawade, Hs; Kuckekar, Ab; Lokhande, Pd

    2011-01-01

    The process of understanding the control and capability (PUCC) is an iterative closed loop process for continuous improvement. It covers the DMAIC toolkit in its three phases. PUCC is an iterative approach that rotates between the three pillars of the process of understanding, process control, and process capability, with each iteration resulting in a more capable and robust process. It is rightly said that being at the top is a marathon and not a sprint. The objective of the six sigma study of Ranitidine hydrochloride tablets is to achieve perfection in tablet manufacturing by reviewing the present robust manufacturing process, to find out ways to improve and modify the process, which will yield tablets that are defect-free and will give more customer satisfaction. The application of six sigma led to an improved process capability, due to the improved sigma level of the process from 1.5 to 4, a higher yield, due to reduced variation and reduction of thick tablets, reduction in packing line stoppages, reduction in re-work by 50%, a more standardized process, with smooth flow and change in coating suspension reconstitution level (8%w/w), a huge cost reduction of approximately Rs.90 to 95 lakhs per annum, an improved overall efficiency by 30% approximately, and improved overall quality of the product.

  6. Different types of nitrogen deposition show variable effects on the soil carbon cycle process of temperate forests.

    Science.gov (United States)

    Du, Yuhan; Guo, Peng; Liu, Jianqiu; Wang, Chunyu; Yang, Ning; Jiao, Zhenxia

    2014-10-01

    Nitrogen (N) deposition significantly affects the soil carbon (C) cycle process of forests. However, the influence of different types of N on it still remained unclear. In this work, ammonium nitrate was selected as an inorganic N (IN) source, while urea and glycine were chosen as organic N (ON) sources. Different ratios of IN to ON (1 : 4, 2 : 3, 3 : 2, 4 : 1, and 5 : 0) were mixed with equal total amounts and then used to fertilize temperate forest soils for 2 years. Results showed that IN deposition inhibited soil C cycle processes, such as soil respiration, soil organic C decomposition, and enzymatic activities, and induced the accumulation of recalcitrant organic C. By contrast, ON deposition promoted these processes. Addition of ON also resulted in accelerated transformation of recalcitrant compounds into labile compounds and increased CO2 efflux. Meanwhile, greater ON deposition may convert C sequestration in forest soils into C source. These results indicated the importance of the IN to ON ratio in controlling the soil C cycle, which can consequently change the ecological effect of N deposition. © 2014 John Wiley & Sons Ltd.

  7. The Influence of Toy Design Activities on Middle School Students' Understanding of the Engineering Design Processes

    Science.gov (United States)

    Zhou, Ninger; Pereira, Nielsen L.; George, Tarun Thomas; Alperovich, Jeffrey; Booth, Joran; Chandrasegaran, Senthil; Tew, Jeffrey David; Kulkarni, Devadatta M.; Ramani, Karthik

    2017-10-01

    The societal demand for inspiring and engaging science, technology, engineering, and mathematics (STEM) students and preparing our workforce for the emerging creative economy has necessitated developing students' self-efficacy and understanding of engineering design processes from as early as elementary school levels. Hands-on engineering design activities have shown the potential to promote middle school students' self-efficacy and understanding of engineering design processes. However, traditional classrooms often lack hands-on engineering design experiences, leaving students unprepared to solve real-world design problems. In this study, we introduce the framework of a toy design workshop and investigate the influence of the workshop activities on students' understanding of and self-efficacy beliefs in engineering design. Using a mixed method approach, we conducted quantitative analyses to show changes in students' engineering design self-efficacy and qualitative analyses to identify students' understanding of the engineering design processes. Findings show that among the 24 participants, there is a significant increase in students' self-efficacy beliefs after attending the workshop. We also identified major themes such as design goals and prototyping in students' understanding of engineering design processes. This research provides insights into the key elements of middle school students' engineering design learning and the benefits of engaging middle school students in hands-on toy design workshops.

  8. Effect of substrate bias on deposition behaviour of charged silicon nanoparticles in ICP-CVD process

    International Nuclear Information System (INIS)

    Yoo, Seung-Wan; Kim, Jung-Hyung; Seong, Dae-Jin; You, Shin-Jae; Seo, Byong-Hoon; Hwang, Nong-Moon

    2017-01-01

    The effect of a substrate bias on the deposition behaviour of crystalline silicon films during inductively coupled plasma chemical vapour deposition (ICP-CVD) was analysed by consideration of non-classical crystallization, in which the building block is a nanoparticle rather than an individual atom or molecule. The coexistence of positively and negatively charged nanoparticles in the plasma and their role in Si film deposition are confirmed by applying bias voltages to the substrate, which is sufficiently small as not to affect the plasma potential. The sizes of positively and negatively charged nanoparticles captured on a carbon membrane and imaged using TEM are, respectively, 2.7–5.5 nm and 6–13 nm. The film deposited by positively charged nanoparticles has a typical columnar structure. In contrast, the film deposited by negatively charged nanoparticles has a structure like a powdery compact with the deposition rate about three times higher than that for positively charged nanoparticles. All the films exhibit crystallinity even though the substrate is at room temperature, which is attributed to the deposition of crystalline nanoparticles formed in the plasma. The film deposited by negatively charged nanoparticles has the highest crystalline fraction of 0.84. (paper)

  9. Using process elicitation and validation to understand and improve chemotherapy ordering and delivery.

    Science.gov (United States)

    Mertens, Wilson C; Christov, Stefan C; Avrunin, George S; Clarke, Lori A; Osterweil, Leon J; Cassells, Lucinda J; Marquard, Jenna L

    2012-11-01

    Chemotherapy ordering and administration, in which errors have potentially severe consequences, was quantitatively and qualitatively evaluated by employing process formalism (or formal process definition), a technique derived from software engineering, to elicit and rigorously describe the process, after which validation techniques were applied to confirm the accuracy of the described process. The chemotherapy ordering and administration process, including exceptional situations and individuals' recognition of and responses to those situations, was elicited through informal, unstructured interviews with members of an interdisciplinary team. The process description (or process definition), written in a notation developed for software quality assessment purposes, guided process validation (which consisted of direct observations and semistructured interviews to confirm the elicited details for the treatment plan portion of the process). The overall process definition yielded 467 steps; 207 steps (44%) were dedicated to handling 59 exceptional situations. Validation yielded 82 unique process events (35 new expected but not yet described steps, 16 new exceptional situations, and 31 new steps in response to exceptional situations). Process participants actively altered the process as ambiguities and conflicts were discovered by the elicitation and validation components of the study. Chemotherapy error rates declined significantly during and after the project, which was conducted from October 2007 through August 2008. Each elicitation method and the subsequent validation discussions contributed uniquely to understanding the chemotherapy treatment plan review process, supporting rapid adoption of changes, improved communication regarding the process, and ensuing error reduction.

  10. Exhaust circulation into dry gas desulfurization process to prevent carbon deposition in an Oxy-fuel IGCC power generation

    International Nuclear Information System (INIS)

    Kobayashi, Makoto; Nakao, Yoshinobu; Oki, Yuso

    2014-01-01

    Highlights: • Power plant with semi-closed gas turbine and O 2 –CO 2 coal gasifier was studied. • We adopt dry gas sulfur removal process to establish the system. • The exhaust gas circulation remarkably prevented carbon deposition. • Efficiency loss for exhaust gas circulation is quite small. • Appropriate operating condition of sulfur removal process is revealed. - Abstract: Semi-closed cycle operation of gas turbine fueled by oxygen–CO 2 blown coal gasification provides efficient power generation with CO 2 separation feature by excluding pre-combustion type CO 2 capture that usually brings large efficiency loss. The plant efficiency at transmission end is estimated as 44% at lower heating value (LHV) providing compressed CO 2 with concentration of 93 vol%. This power generation system will solve the contradiction between economical resource utilization and reduction of CO 2 emission from coal-fired power plant. The system requires appropriate sulfur reduction process to protect gas turbine from corrosion and environment from sulfur emission. We adopt dry gas sulfur removal process to establish the system where apprehension about the detrimental carbon deposition from coal gas. The effect of circulation of a portion of exhaust gas to the process on the retardation of carbon deposition was examined at various gas compositions. The circulation remarkably prevented carbon deposition in the sulfur removal sorbent. The impact of the circulation on the thermal efficiency is smaller than the other auxiliary power consumption. Thus, the circulation is appropriate operation for the power generation

  11. Deposition and characteristics of PbS thin films by an in-situ solution chemical reaction process

    Energy Technology Data Exchange (ETDEWEB)

    Ji, Junna; Ji, Huiming; Wang, Jian; Zheng, Xuerong; Lai, Junyun; Liu, Weiyan; Li, Tongfei [School of Materials Science and Engineering, Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072 (China); Ma, Yuanliang; Li, Haiqin; Zhao, Suqin [College of Physics and Electronic Information Engineering, Qinghai University for Nationalities, Xining 810007 (China); Jin, Zhengguo, E-mail: zhgjin@tju.edu.cn [School of Materials Science and Engineering, Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072 (China)

    2015-09-01

    Preferential oriented and uniform PbS thin films were deposited by a room temperature in-situ solution chemical reaction process, in which the lead nitrate as precursor in a form of thin solid films from lead precursor solution was used to react with ammonium sulfide ethanol solution. Influence of 1-butanol addition in the lead precursor solution, Pb:S molar ratios in the separate cationic and anionic solutions, deposition cycle numbers and annealing treatment in Ar atmosphere on structure, morphology, chemical composition and optical absorption properties of the deposited PbS films were investigated based on X-ray diffraction, field emission scanning electron microscopy, energy dispersive spectrometer, atomic force microscopy, selected area electron diffraction, UV–vis, near infrared ray and fourier transform infrared spectroscopy measurements. The results showed that the deposited PbS thin films had a cubic structure and highly preferred orientation along with the plane (100). The deposition rate of single-layer was stable, about 30 nm in thickness per deposition cycle. - Highlights: • Time-efficiency synthetic method for the preparation of lead sulfide (PbS) films • Effect of 1-butanol addition into cationic precursor solution is discussed. • Growth rate of the PbS films is stable at about 30 nm per cycle.

  12. Regularly arranged indium islands on glass/molybdenum substrates upon femtosecond laser and physical vapor deposition processing

    Energy Technology Data Exchange (ETDEWEB)

    Ringleb, F.; Eylers, K.; Teubner, Th.; Boeck, T., E-mail: torsten.boeck@ikz-berlin.de [Leibniz-Institute for Crystal Growth, Max-Born-Straße 2, Berlin 12489 (Germany); Symietz, C.; Bonse, J.; Andree, S.; Krüger, J. [Bundesanstalt für Materialforschung und-prüfung (BAM), Unter den Eichen 87, Berlin 12205 (Germany); Heidmann, B.; Schmid, M. [Department of Physics, Freie Universität Berlin, Arnimalle 14, Berlin 14195 (Germany); Nanooptical Concepts for PV, Helmholtz Zentrum Berlin, Hahn-Meitner-Platz 1, Berlin 14109 (Germany); Lux-Steiner, M. [Nanooptical Concepts for PV, Helmholtz Zentrum Berlin, Hahn-Meitner-Platz 1, Berlin 14109 (Germany); Heterogeneous Material Systems, Helmholtz Zentrum Berlin, Hahn-Meitner-Platz 1, Berlin 14109 (Germany)

    2016-03-14

    A bottom-up approach is presented for the production of arrays of indium islands on a molybdenum layer on glass, which can serve as micro-sized precursors for indium compounds such as copper-indium-gallium-diselenide used in photovoltaics. Femtosecond laser ablation of glass and a subsequent deposition of a molybdenum film or direct laser processing of the molybdenum film both allow the preferential nucleation and growth of indium islands at the predefined locations in a following indium-based physical vapor deposition (PVD) process. A proper choice of laser and deposition parameters ensures the controlled growth of indium islands exclusively at the laser ablated spots. Based on a statistical analysis, these results are compared to the non-structured molybdenum surface, leading to randomly grown indium islands after PVD.

  13. The Impact of Hydrodynamics in Erosion - Deposition Process in Can Gio Mangrove Biosphere Reserve, South Viet Nam

    Science.gov (United States)

    Vo-Luong, H. P.

    2014-12-01

    Can Gio Mangrove Biosphere Reserve is always considered as a friendly green belt to protect and bring up the habitants. However, recently some mangrove areas in the Dong Tranh estuary are being eroded seriously. Based on the field measurements in SW and NE monsoons as well as data of topography changes in 10 years, it is proved that hydrodynamics of waves, tidal currents and riverine currents are the main reasons for erosion-deposition processes at the studied site. The erosion-deposition process changes due to monsoon. The analysed results show that high waves and tidal oscillation cause the increase of the erosion rate in NE monsoon. However, high sediment deposition occurs in SW monsoon due to weak waves and more alluvium from upstream. Many young mangrove trees grow up and develop in the SW monsoon. From the research, it is strongly emphasized the role of mangrove forests in soil retention and energy dissipation.

  14. Environmental sensing with optical fiber sensors processed with focused ion beam and atomic layer deposition

    Science.gov (United States)

    Flores, Raquel; Janeiro, Ricardo; Dahlem, Marcus; Viegas, Jaime

    2015-03-01

    We report an optical fiber chemical sensor based on a focused ion beam processed optical fiber. The demonstrated sensor is based on a cavity formed onto a standard 1550 nm single-mode fiber by either chemical etching, focused ion beam milling (FIB) or femtosecond laser ablation, on which side channels are drilled by either ion beam milling or femtosecond laser irradiation. The encapsulation of the cavity is achieved by optimized fusion splicing onto a standard single or multimode fiber. The empty cavity can be used as semi-curved Fabry-Pérot resonator for gas or liquid sensing. Increased reflectivity of the formed cavity mirrors can be achieved with atomic layer deposition (ALD) of alternating metal oxides. For chemical selective optical sensors, we demonstrate the same FIB-formed cavity concept, but filled with different materials, such as polydimethylsiloxane (PDMS), poly(methyl methacrylate) (PMMA) which show selective swelling when immersed in different solvents. Finally, a reducing agent sensor based on a FIB formed cavity partially sealed by fusion splicing and coated with a thin ZnO layer by ALD is presented and the results discussed. Sensor interrogation is achieved with spectral or multi-channel intensity measurements.

  15. Annealing of chromium oxycarbide coatings deposited by plasma immersion ion processing (PIIP) for aluminum die casting

    International Nuclear Information System (INIS)

    Peters, A.M.; He, X.M.; Trkula, M.; Nastasi, M.

    2001-01-01

    Chromium oxycarbide coatings have been investigated for use as non-wetting coatings for aluminum die casting. This paper examines Cr-C-O coating stability and non-wetability at elevated temperatures for extended periods. Coatings were deposited onto 304 stainless steel from chromium carbonyl [Cr(CO) 6 ] by plasma immersion ion processing. The coatings were annealed in air at an aluminum die casting temperature of 700 deg. C up to 8 h. Coatings were analyzed using resonant ion backscattering spectroscopy, nanoindentation and pin-on-disk tribometry. Molten aluminum was used to determine coating wetting and contact angle. Results indicate that the surface oxide layer reaches a maximum thickness of 900 nm. Oxygen concentrations in the coatings increased from 24% to 34%, while the surface concentration rose to almost 45%. Hardness values ranged from 22.1 to 6.7 GPa, wear coefficients ranged from 21 to 8x10 -6 mm 3 /Nm and contact angles ranged from 156 deg. to 127 deg

  16. Effects of processing parameters on the properties of tantalum nitride thin films deposited by reactive sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Nazon, J.; Sarradin, J.; Flaud, V.; Tedenac, J.C. [Institut Charles Gerhardt, UMR 5253 CNRS-UM2-ENSCM-UM1, cc 1504, Place E. Bataillon, 34095 Montpellier Cedex 5 (France); Frety, N. [Institut Charles Gerhardt, UMR 5253 CNRS-UM2-ENSCM-UM1, cc 1504, Place E. Bataillon, 34095 Montpellier Cedex 5 (France)], E-mail: Nicole.Frety@univ-montp2.fr

    2008-09-22

    The effects of processing parameters on the properties of tantalum nitride thin films deposited by radio frequency reactive sputtering have been investigated. The influence of the N{sub 2} partial and (Ar + N{sub 2}) total gas pressures as well as the sputtering power on the microstructure and electrical properties is reported. Rising the N{sub 2} partial pressure, from 2 to 10.7%, induces a change in the composition of the {delta}-TaN phase, from TaN to TaN{sub 1.13}. This composition change is associated with a drastic increase of the electrical resistivity over a 7.3% N{sub 2} partial pressure. The total gas pressure is revealed to strongly affect the film microstructure since a variation in both composition and grain size is observed when the gas pressure rises from 6.8 to 24.6 Pa. When the sputtering power varied between 50 and 110 W, an increase of the grain size related to a decrease of the electrical resistivity is observed.

  17. Electrophoretic Deposition as a New Bioactive Glass Coating Process for Orthodontic Stainless Steel

    Directory of Open Access Journals (Sweden)

    Kyotaro Kawaguchi

    2017-11-01

    Full Text Available This study investigated the surface modification of orthodontic stainless steel using electrophoretic deposition (EPD of bioactive glass (BG. The BG coatings were characterized by spectrophotometry, scanning electron microscopy with energy dispersive X-ray spectrometry, and X-ray diffraction. The frictional properties were investigated using a progressive load scratch test. The remineralization ability of the etched dental enamel was studied according to the time-dependent mechanical properties of the enamel using a nano-indentation test. The EPD process using alternating current produced higher values in both reflectance and lightness. Additionally, the BG coating was thinner than that prepared using direct current, and was completely amorphous. All of the BG coatings displayed good interfacial adhesion, and Si and O were the major components. Most BG-coated specimens produced slightly higher frictional forces compared with non-coated specimens. The hardness and elastic modulus of etched enamel specimens immersed with most BG-coated specimens recovered significantly with increasing immersion time compared with the non-coated specimen, and significant acid-neutralization was observed for the BG-coated specimens. The surface modification technique using EPD and BG coating on orthodontic stainless steel may assist the development of new non-cytotoxic orthodontic metallic appliances having satisfactory appearance and remineralization ability.

  18. Impact of the Fused Deposition (FDM Printing Process on Polylactic Acid (PLA Chemistry and Structure

    Directory of Open Access Journals (Sweden)

    Michael Arthur Cuiffo

    2017-06-01

    Full Text Available Polylactic acid (PLA is an organic polymer commonly used in fused deposition (FDM printing and biomedical scaffolding that is biocompatible and immunologically inert. However, variations in source material quality and chemistry make it necessary to characterize the filament and determine potential changes in chemistry occurring as a result of the FDM process. We used several spectroscopic techniques, including laser confocal microscopy, Fourier transform infrared (FTIR spectroscopy and photoacousitc FTIR spectroscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS in order to characterize both the bulk and surface chemistry of the source material and printed samples. Scanning electron microscopy (SEM and differential scanning calorimetry (DSC were used to characterize morphology, cold crystallinity, and the glass transition and melting temperatures following printing. Analysis revealed calcium carbonate-based additives which were reacted with organic ligands and potentially trace metal impurities, both before and following printing. These additives became concentrated in voids in the printed structure. This finding is important for biomedical applications as carbonate will impact subsequent cell growth on printed tissue scaffolds. Results of chemical analysis also provided evidence of the hygroscopic nature of the source material and oxidation of the printed surface, and SEM imaging revealed micro- and submicron-scale roughness that will also impact potential applications.

  19. Microstructures, hardness and bioactivity of hydroxyapatite coatings deposited by direct laser melting process

    International Nuclear Information System (INIS)

    Tlotleng, Monnamme; Akinlabi, Esther; Shukla, Mukul; Pityana, Sisa

    2014-01-01

    Hydroxyapatite (HAP) coatings on bioinert metals such as Ti–6Al–4V are necessary for biomedical applications. Together, HAP and Ti–6Al–4V are biocompatible and bioactive. The challenges of depositing HAP on Ti–6Al–4V with traditional thermal spraying techniques are well founded. In this paper, HAP was coated on Ti–6Al–4V using direct laser melting (DLM) process. This process, unlike the traditional coating processes, is able to achieve coatings with good metallurgical bonding and little dilution. The microstructural and mechanical properties, chemical composition and bio-activities of the produced coatings were studied with optical microscopy, scanning electron microscope equipped with energy dispersive X-ray spectroscopy, and Vickers hardness machine, and by immersion test in Hanks' solution. The results showed that the choice of the laser power has much influence on the evolving microstructure, the mechanical properties and the retainment of HAP on the surface of the coating. Also, the choice of laser power of 750 W led to no dilution. The microhardness results inferred a strong intermetallic–ceramic interfacial bonding; which meant that the 750 W coating could survive long in service. Also, the coating was softer at the surface and stronger in the heat affected zones. Hence, this process parameter setting can be considered as an optimal setting. The soak tests revealed that the surface of the coating had unmelted crystals of HAP. The CaP ratio conducted on the soaked coating was 2.00 which corresponded to tetra calcium phosphate. This coating seems attractive for metallic implant applications. - Highlights: • Characteristics of HAP coatings produced on Ti-6Al-4V achieved with direct laser melting are reported. • Optimal process parameters necessary to achieve biocompatible coating are reported. • The SEM micrograph of the soaked HAP coating revealed partially melted crystals of HAP. • The HAP coating was retained at the surface of

  20. Microstructures, hardness and bioactivity of hydroxyapatite coatings deposited by direct laser melting process

    Energy Technology Data Exchange (ETDEWEB)

    Tlotleng, Monnamme, E-mail: MTlotleng@csir.co.za [Laser Materials Processing Group, National Laser Center CSIR, Pretoria 0001 (South Africa); Department of Mechanical Engineering Science, University of Johannesburg, Auckland Park, Kingsway Campus, Johannesburg 2006 (South Africa); Akinlabi, Esther [Department of Mechanical Engineering Science, University of Johannesburg, Auckland Park, Kingsway Campus, Johannesburg 2006 (South Africa); Shukla, Mukul [Department of Mechanical Engineering Technology, University of Johannesburg, Doornfontein Campus, Johannesburg 2006 (South Africa); Department of Mechanical Engineering, MNNIT, Allahabad, UP 211004 (India); Pityana, Sisa [Laser Materials Processing Group, National Laser Center CSIR, Pretoria 0001 (South Africa); Department of Chemical and Metallurgical Engineering, Tshwane University of Technology, Pretoria 0001 (South Africa)

    2014-10-01

    Hydroxyapatite (HAP) coatings on bioinert metals such as Ti–6Al–4V are necessary for biomedical applications. Together, HAP and Ti–6Al–4V are biocompatible and bioactive. The challenges of depositing HAP on Ti–6Al–4V with traditional thermal spraying techniques are well founded. In this paper, HAP was coated on Ti–6Al–4V using direct laser melting (DLM) process. This process, unlike the traditional coating processes, is able to achieve coatings with good metallurgical bonding and little dilution. The microstructural and mechanical properties, chemical composition and bio-activities of the produced coatings were studied with optical microscopy, scanning electron microscope equipped with energy dispersive X-ray spectroscopy, and Vickers hardness machine, and by immersion test in Hanks' solution. The results showed that the choice of the laser power has much influence on the evolving microstructure, the mechanical properties and the retainment of HAP on the surface of the coating. Also, the choice of laser power of 750 W led to no dilution. The microhardness results inferred a strong intermetallic–ceramic interfacial bonding; which meant that the 750 W coating could survive long in service. Also, the coating was softer at the surface and stronger in the heat affected zones. Hence, this process parameter setting can be considered as an optimal setting. The soak tests revealed that the surface of the coating had unmelted crystals of HAP. The CaP ratio conducted on the soaked coating was 2.00 which corresponded to tetra calcium phosphate. This coating seems attractive for metallic implant applications. - Highlights: • Characteristics of HAP coatings produced on Ti-6Al-4V achieved with direct laser melting are reported. • Optimal process parameters necessary to achieve biocompatible coating are reported. • The SEM micrograph of the soaked HAP coating revealed partially melted crystals of HAP. • The HAP coating was retained at the surface of

  1. Implementation of new integrated evaporation equipment for the preparation of 238U targets and improvement of the deposition process

    Science.gov (United States)

    Vanleeuw, D.; Lewis, D.; Moens, A.; Sibbens, G.; Wiss, T.

    2018-05-01

    Measurement of neutron cross section data is a core activity of the JRC-Directorate G for Nuclear Safety and Security in Geel. After a period of reduced activity and in line with a renewed interest for nuclear data required for GenIV reactors and waste minimization, the demand for high quality actinide targets increased. Physical vapour deposition by thermal evaporation is a key technique to prepare homogeneous thin actinide layers, but due to ageing effects the earlier in-house developed equipment can no longer provide the required quality. Because of a current lack of experience and human resources cooperation with private companies is required for the development of new deposition equipment directly integrated in a glove box. In this paper we describe the design, implementation and validation of the first commercial actinide evaporator in a glove box as well as the optimization of the deposition process. Highly enriched 238U3O8 was converted to 238UF4 powder and several deposition runs were performed on different substrates. The deposition parameters were varied and defined in order to guarantee physical and chemical stable homogeneous UF4 layers, even on polished substrates which was not longer feasible with the older equipment. The stability problem is discussed in view of the thin layer growth by physical vapour deposition and the influence of the deposition parameters on the layer quality. The deposits were characterized for the total mass by means of substitution weighing and for the areal density of 238U by means of alpha particle counting and thermal ionization mass spectrometry (TIMS). The quality of the layer was visually evaluated and by means of stereo microscopy and auto radiography.

  2. Modeling of Filament Deposition Rapid Prototyping Process with a Closed form Solution

    Science.gov (United States)

    Devlin, Steven Leon

    Fused Deposition Modeling (FDM(TM)) or fused filament fabrication (FFF) systems are extrusion-based technologies used to produce functional or near functional parts from a wide variety of plastic materials. First patented by S. Scott Crump and commercialized by Stratasys, Ltd in the early 1990s, this technology, like many additive manufacturing systems, offers significant opportunities for the design and production of complex part structures that are difficult if not impossible to produce using traditional manufacturing methods. Standing on the shoulders of a twenty-five year old invention, a rapidly growing open-source development community has exponentially driven interest in FFF technology. However, part quality often limits use in final product commercial markets. Development of accurate and repeatable methods for determining material strength in FFF produced parts is essential for wide adoption into mainstream manufacturing. This study builds on the empirical, squeeze flow and intermolecular diffusion model research conducted by David Grewell and Avraham Benatar, applying a combined model to predict auto adhesion or healing to FFF part samples. In this research, an experimental study and numerical modeling were performed in order to drive and validate a closed form heat transfer solution for extrusion processes to develop temperature field models. An extrusion-based 3D printing system, with the capacity to vary deposition speeds and temperatures, was used to fabricate the samples. Standardized specimens of Polylactic Acid (PLA) and Acrylonitrile Butadiene Styrene (ABS) filament were used to fabricate the samples with different speeds and temperatures. Micro-scanning of cut and lapped specimens, using an optical microscope, was performed to find the effect of the speed and the temperature on the geometry of the cross-sections. It was found that by increasing the speed of the extrusion printing, the area of the cross-section and the maximum thickness decrease

  3. VUV Processing of Polymers: Surface Modification and Deposition of Organic Thin Films

    International Nuclear Information System (INIS)

    Wertheimer, M.R.

    2006-01-01

    Materials processing based on the use of vacuum-ultraviolet (VUV) radiation has evolved from the status of 'laboratory curiosum' to that of technological reality, thanks to the availability of commercial light sources, first lasers but more recently VUV-lamps. We begin with a brief survey of application areas, still mostly 'high-tech' on account of the relatively elevated cost of the light sources. In this laboratory, we use a series of commercial VUV lamps (based on radio-frequency discharges in ampoules that are sealed with VUV-transparent MgF 2 ) that cover a broad spectral range, 120 nm 3 ) gas. This allowed us to achieve maximum bound N concentrations, [N] ∼ 25 at%, comparable to values achieved by plasma-induced nitriding. More recently, we have investigated the deposition of polymer-like ( V UV-polymer ) coatings by VUV-induced gas-phase photo-chemistry of ammonia-hydrocarbon mixtures, both gases that strongly absorb VUV photons. We use the same cylindrical high-vacuum reactor, with a VUV lamp and a VUV-sensitive photodiode detector at opposite ends; after measuring radiation intensity, the latter is replaced by a substrate holder, the frontal distance of which (with respect to the lamp) can be adjusted. For 'VUV-polymerization' experiments we have used two resonant lamps (low-pressure Kr and Xe), having 'monochromatic' emissions at λ 123.6 nm and 147.0 nm, respectively. The ammonia-hydrocarbon feed gas mixtures are characterised by their flow rate ratio, R ≡ NH 3 /C x H y , where C x H y designates methane (CH 4 ) or ethylene (C 2 H 4 ), the two 'monomers' investigated so far. Thin 'VUV-polymer' deposits were collected on MgF 2 or Si wafers placed on the substrate holder, and they were examined by a variety of physico-chemical techniques; for example, chemical structure and composition were characterized by X-ray photoelectron spectroscopy (XPS); layer thickness and refractive index, n, were determined by UV-VIS spectro-ellipsometry, and

  4. Geology of Tok Island, Korea: eruptive and depositional processes of a shoaling to emergent island volcano

    Science.gov (United States)

    Sohn, Y. K.

    1995-02-01

    Detailed mapping of Tok Island, located in the middle of the East Sea (Sea of Japan), along with lithofacies analysis and K-Ar age determinations reveal that the island is of early to late Pliocene age and comprises eight rock units: Trachyte I, Unit P-I, Unit P-II, Trachyandesite (2.7±0.1 Ma), Unit P-III, Trachyte II (2.7±0.1 Ma), Trachyte III (2.5±0.1 Ma) and dikes in ascending stratigraphic order. Trachyte I is a mixture of coherent trachytic lavas and breccias that are interpreted to be subaqueous lavas and related hyaloclastites. Unit P-I comprises massive and inversely graded basaltic breccias which resulted from subaerial gain flows and subaqueous debris flows. A basalt clast from the unit, derived from below Trachyte I, has an age of 4.6±0.4 Ma. Unit P-II is composed of graded and stratified lapilli tuffs with the characteristics of proximal pyroclastic surge deposits. The Trachyandesite is a massive subaerial lava ponded in a volcano-tectonic depression, probably a summit crater. A pyroclastic sequence containing flattened scoria clasts (Unit P-III) and a small volume subaerial lava (Trachyte II) occur above the Trachyandesite, suggesting resumption of pyroclastic activity and lava effusion. Afterwards, shallow intrusion of magma occurred, producing Trachyte III and trachyte dikes. The eight rock units provide an example of the changing eruptive and depositional processes and resultant succession of lithofacies as a seamount builds up above sea level to form an island volcano: Trachyte I represents a wholly subaqueous and effusive stage; Units P-I and P-II represent Surtseyan and Taalian eruptive phases during an explosive transitional (subaqueous to emergent) stage; and the other rock units represent later subaerial effusive and explosive stages. Reconstruction of volcano morphology suggests that the island is a remnant of the south-western crater rim of a volcano the vent of which lies several hundred meters to the north-east.

  5. Understanding the Perception of Very Small Software Companies towards the Adoption of Process Standards

    Science.gov (United States)

    Basri, Shuib; O'Connor, Rory V.

    This paper is concerned with understanding the issues that affect the adoption of software process standards by Very Small Entities (VSEs), their needs from process standards and their willingness to engage with the new ISO/IEC 29110 standard in particular. In order to achieve this goal, a series of industry data collection studies were undertaken with a collection of VSEs. A twin track approach of a qualitative data collection (interviews and focus groups) and quantitative data collection (questionnaire) were undertaken. Data analysis was being completed separately and the final results were merged, using the coding mechanisms of grounded theory. This paper serves as a roadmap for both researchers wishing to understand the issues of process standards adoption by very small companies and also for the software process standards community.

  6. BaF2 POST-DEPOSITION REACTION PROCESS FOR THICK YBCO FILMS

    International Nuclear Information System (INIS)

    SUENAGA, M.; SOLOVYOV, V.F.; WU, L.; WIESMANN, H.J.; ZHU, Y.

    2001-01-01

    The basic processes of the so-called BaF 2 process for the formation of YBa 2 Cu 3 O 7 , YBCO, films as well as its advantages over the in situ formation processes are discussed in the previous chapter. The process and the properties of YBCO films by this process were also nicely described in earlier articles by R. Feenstra, (et al.) Here, we will discuss two pertinent subjects related to fabrication of technologically viable YBCO conductors using this process. These are (1) the growth of thick (>> 1 microm) c-axis-oriented YBCO films and (2) their growth rates. Before the detail discussions of these subjects are given, we first briefly discuss what geometrical structure a YBCO-coated conductor should be. Then, we will provide examples of simple arguments for how thick the YBCO films and how fast their growth rates need to be. Then, the discussions in the following two sections are devoted to: (1) the present understanding of the nucleation and the growth process for YBCO, and why it is so difficult to grow thick c-axis-oriented films (> 3 microm), and (2) our present understanding of the YBCO growth-limiting mechanism and methods to increase the growth rates. The values of critical-current densities J c in these films are of primary importance for the applications,. and the above two subjects are intimately related to the control of J c of the films. In general, the lower the temperatures of the YBCO formation are the higher the values of J c of the films. Thus, the present discussion is limited to those films which are reacted at ∼735 C. This is the lowest temperature at which c-axis-oriented YBCO films (1-3 microm thick) are comfortably grown. It is also well known that the non-c-axis oriented YBCO platelets are extremely detrimental to the values of J c such that their effects on J c dwarf essentially all of other microstructural effects which control J c . Hence, the discussion given below is mainly focused on how to avoid the growth of these crystallites

  7. Zirconium cladding - the long way towards a mechanistic understanding of processing and performance

    International Nuclear Information System (INIS)

    Preuss, Michael

    2011-01-01

    Zirconium alloys are the material of choice to encapsulate nuclear fuel in light and heavy water-cooled reactors due to their low neutron absorption, excellent corrosion resistance and sufficient mechanical properties. Despite these advantageous physical and mechanical properties a more physically based understanding of microstructure and texture evolution during processing is highly desirable in order to improve our understanding of formability during thermomechanical processing and performance variability of cladding material. In addition, the purely empirical understanding of aqueous zirconium corrosion, hydrogen pick up, hydride precipitation as well as irradiation growth and creep limits the accuracy of life predictions and therefore the level of burnup that is obtained from current fuel assemblies. The presentation aims at giving examples of new research strategies that will enable the development of a new physical understanding of processing and performance aspects in zirconium cladding material, which is required to develop new predictive models. Particular emphasis will be placed on using novel research tools and large-scale research facilities such as neutron spallation and synchrotron radiation sources to undertake very detailed and often in-situ studies of deformation mechanisms and microstructure evolution as well as determining stress states in grain families, oxides and hydrides. The results will be presented in the view of how they might help us to improve our understanding and enable the development of better predictive models

  8. Macrosystems ecology: novel methods and new understanding of multi-scale patterns and processes

    Science.gov (United States)

    Songlin Fei; Qinfeng Guo; Kevin Potter

    2016-01-01

    As the global biomes are increasingly threatened by human activities, understanding of macroscale patterns and processes is pressingly needed for effective management and policy making. Macrosystems ecology, which studies multiscale ecologicalpatterns and processes, has gained growing interest in the research community. However, as a relatively new field in...

  9. Phreatomagmatic eruptive and depositional processes during the 1949 eruption on La Palma (Canary Islands)

    Science.gov (United States)

    White, James D. L.; Schmincke, Hans-Ulrich

    1999-12-01

    In 1949, a 5-week-long magmatic and phreatomagmatic eruption took place along the active volcanic ridge of La Palma (Canary Islands). Two vents, Duraznero and Hoyo Negro, produced significant pyroclastic deposits. The eruption began from Duraznero vent, which produced a series of deposits with an upward decrease in accidental fragments and increase in fluidal ash and spatter, together inferred to indicate decreasing phreatomagmatic interaction. Hoyo Negro erupted over a 2-week period, producing a variety of pyroclastic density currents and ballistic blocks and bombs. Hoyo Negro erupted within and modified an older crater having high walls on the northern to southeastern edges. Southwestern to western margins of the crater lay 50 to 100 m lower. Strongly contrasting deposits in the different sectors (N-SE vs. SW-W) were formed as a result of interaction between topography, weak eruptive columns and stratified pyroclastic density currents. Tephra ring deposits are thicker and coarser-grained than upper rim deposits formed along the higher edges of the crater, and beyond the crater margin, valley-confined deposits are thicker than more thinly bedded mantling deposits on higher topography. These differences indicate that the impact zone for the bulk of the collapsing, tephra-laden column lay within the crater and that the high crater walls inhibited escape of pyroclastic density currents to the north and east. The impact zone lay outside the low SW-W rims, however, thus allowing stratified pyroclastic density currents to move freely away from the crater in those directions, depositing thin sections (<30 cm) of well-bedded ash (mantling deposits) on ridges and thicker sections (1-3 m) of structureless ash beds in valleys and small basins. Such segregation of dense pyroclastic currents from more dilute ones at the crater wall is likely to be common for small eruptions from pre-existing craters and is an important factor to be taken into account in volcanic hazards

  10. The role of post-ore processes in the alteration of infiltrational uranium deposits

    International Nuclear Information System (INIS)

    Kondrat'eva, I.A.; Bobrova, L.L.; Nesterova, M.V.

    1992-01-01

    Ore-bearing rocks and ores of uranium deposits that are associated with gray alluvial deposits and formed through oxidation of sedimentary beds at the end of the Jurassic, have undergone intensive alterations. The impact of hot carbonic acid solutions on infiltrational uranium deposits, along with calcite and hematite, resulted in partial dissolution of and redeposition of uranium. Uranium concentrates with newly formed Fe-bisulfides and hydroxides in the reducing stage of epigenetic alterations within a hydrochemical sulfide-gley medium, leading to changes in ore morphology. 20 refs., 7 figs., 3 tabs

  11. Uranium deposits in the metamorphic basement of the Rouergue massif. Genesis and extension of related albitization processes

    International Nuclear Information System (INIS)

    Schmitt, J.M.

    1982-02-01

    Albitization processes in the Rouergue metamorphic basement, probably Permian aged is evidenced. Late development of uranium orebodies occured within albitized zones. The detection of the latter serves as a highly valuable indirect guide for prospecting this type of deposits in a metamorphic basement [fr

  12. How Pre-Service Teachers' Understand and Perform Science Process Skills

    Science.gov (United States)

    Chabalengula, Vivien Mweene; Mumba, Frackson; Mbewe, Simeon

    2012-01-01

    This study explored pre-service teachers' conceptual understanding and performance on science process skills. A sample comprised 91 elementary pre-service teachers at a university in the Midwest of the USA. Participants were enrolled in two science education courses; introductory science teaching methods course and advanced science methods course.…

  13. A soil-landscape framework for understanding spatial and temporal variability in biogeochemical processes in catchments

    Science.gov (United States)

    McGuire, K. J.; Bailey, S. W.; Ross, D. S.

    2017-12-01

    Heterogeneity in biophysical properties within catchments challenges how we quantify and characterize biogeochemical processes and interpret catchment outputs. Interactions between the spatiotemporal variability of hydrological states and fluxes and soil development can spatially structure catchments, leading to a framework for understanding patterns in biogeochemical processes. In an upland, glaciated landscape at the Hubbard Brook Experimental Forest (HBEF) in New Hampshire, USA, we are embracing the structure and organization of soils to understand the spatial relations between runoff production zones, distinct soil-biogeochemical environments, and solute retention and release. This presentation will use observations from the HBEF to demonstrate that a soil-landscape framework is essential in understanding the spatial and temporal variability of biogeochemical processes in this catchment. Specific examples will include how laterally developed soils reveal the location of active runoff production zones and lead to gradients in primary mineral dissolution and the distribution of weathering products along hillslopes. Soil development patterns also highlight potential carbon and nitrogen cycling hotspots, differentiate acidic conditions, and affect the regulation of surface water quality. Overall, this work demonstrates the importance of understanding the landscape-level structural organization of soils in characterizing the variation and extent of biogeochemical processes that occur in catchments.

  14. Understanding Craftsman’s Creativity in a Framework of Person, Process, Product and Press (4Ps)

    DEFF Research Database (Denmark)

    Zhang, Hui; Zhou, Chunfang; Tanggaard, Lene

    2016-01-01

    , Process, Product, and Press (4Ps) This research question drives to develop a theoretical study bridging two areas of creativity and craftsman’s work. This will further indicate craftsman’s working practice is full of complexity that stimulates creative behavior and that also requires a systematic view...... to understand craftsman’s creativity as involving interaction between 4Ps....

  15. Understanding a Basic Biological Process: Expert and Novice Models of Meiosis.

    Science.gov (United States)

    Kindfield, Ann C. H.

    The results of a study of the meiosis models utilized by individuals at varying levels of expertise while reasoning about the process of meiosis are presented. Based on these results, the issues of sources of misconceptions/difficulties and the construction of a sound understanding of meiosis are discussed. Five individuals from each of three…

  16. Beyond Homophily: A Decade of Advances in Understanding Peer Influence Processes

    Science.gov (United States)

    Brechwald, Whitney A.; Prinstein, Mitchell J.

    2011-01-01

    This article reviews empirical and theoretical contributions to a multidisciplinary understanding of peer influence processes in adolescence over the past decade. Five themes of peer influence research from this decade were identified, including a broadening of the range of behaviors for which peer influence occurs, distinguishing the sources of…

  17. Understanding Customer Product Choices: A Case Study Using the Analytical Hierarchy Process

    Science.gov (United States)

    Robert L. Smith; Robert J. Bush; Daniel L. Schmoldt

    1996-01-01

    The Analytical Hierarchy Process (AHP) was used to characterize the bridge material selection decisions of highway officials across the United States. Understanding product choices by utilizing the AHP allowed us to develop strategies for increasing the use of timber in bridge construction. State Department of Transportation engineers, private consulting engineers, and...

  18. Understanding Reactions to Workplace Injustice through Process Theories of Motivation: A Teaching Module and Simulation

    Science.gov (United States)

    Stecher, Mary D.; Rosse, Joseph G.

    2007-01-01

    Management and organizational behavior students are often overwhelmed by the plethora of motivation theories they must master at the undergraduate level. This article offers a teaching module geared toward helping students understand how two major process theories of motivation, equity and expectancy theories and theories of organizational…

  19. Utilizing the Theoretical Framework of Collective Identity to Understand Processes in Youth Programs

    Science.gov (United States)

    Futch, Valerie A.

    2016-01-01

    This article explores collective identity as a useful theoretical framework for understanding social and developmental processes that occur in youth programs. Through narrative analysis of past participant interviews (n = 21) from an after-school theater program, known as "The SOURCE", it was found that participants very clearly describe…

  20. Elementary Education Preservice Teachers' Understanding of Biotechnology and Its Related Processes

    Science.gov (United States)

    Chabalengula, Vivien Mweene; Mumba, Frackson; Chitiyo, Jonathan

    2011-01-01

    This study examined preservice teachers' understanding of biotechnology and its related processes. A sample comprised 88 elementary education preservice teachers at a large university in the Midwest of the USA. A total of 60 and 28 of the participants were enrolled in introductory and advanced science methods courses, respectively. Most…

  1. The Effect of Biotechnology Education on Australian High School Students' Understandings and Attitudes about Biotechnology Processes

    Science.gov (United States)

    Dawson, Vaille; Soames, Christina

    2006-01-01

    Our education system aims to equip young people with the knowledge, problem-solving skills and values to cope with an increasingly technological society. The aim of this study was to determine the effect of biotechnology education on adolescents' understanding and attitudes about processes associated with biotechnology. Data were drawn from…

  2. Videogame Construction by Engineering Students for Understanding Modelling Processes: The Case of Simulating Water Behaviour

    Science.gov (United States)

    Pretelín-Ricárdez, Angel; Sacristán, Ana Isabel

    2015-01-01

    We present some results of an ongoing research project where university engineering students were asked to construct videogames involving the use of physical systems models. The objective is to help them identify and understand the elements and concepts involved in the modelling process. That is, we use game design as a constructionist approach…

  3. Higher-level processes in the formation and application of associations during action understanding

    NARCIS (Netherlands)

    Heil, L.; Pelt, S. van; Kwisthout, J.H.P.; Rooij, I.J.E.I. van; Bekkering, H.

    2014-01-01

    The associative account described in the target article provides a viable explanation for the origin of mirror neurons. We argue here that if mirror neurons develop purely by associative learning, then they cannot by themselves explain intentional action understanding. Higher-level processes seem to

  4. Nitrous oxide emissions from soils: how well do we understand the processes and their controls?

    Science.gov (United States)

    Butterbach-Bahl, Klaus; Baggs, Elizabeth M.; Dannenmann, Michael; Kiese, Ralf; Zechmeister-Boltenstern, Sophie

    2013-01-01

    Although it is well established that soils are the dominating source for atmospheric nitrous oxide (N2O), we are still struggling to fully understand the complexity of the underlying microbial production and consumption processes and the links to biotic (e.g. inter- and intraspecies competition, food webs, plant–microbe interaction) and abiotic (e.g. soil climate, physics and chemistry) factors. Recent work shows that a better understanding of the composition and diversity of the microbial community across a variety of soils in different climates and under different land use, as well as plant–microbe interactions in the rhizosphere, may provide a key to better understand the variability of N2O fluxes at the soil–atmosphere interface. Moreover, recent insights into the regulation of the reduction of N2O to dinitrogen (N2) have increased our understanding of N2O exchange. This improved process understanding, building on the increased use of isotope tracing techniques and metagenomics, needs to go along with improvements in measurement techniques for N2O (and N2) emission in order to obtain robust field and laboratory datasets for different ecosystem types. Advances in both fields are currently used to improve process descriptions in biogeochemical models, which may eventually be used not only to test our current process understanding from the microsite to the field level, but also used as tools for up-scaling emissions to landscapes and regions and to explore feedbacks of soil N2O emissions to changes in environmental conditions, land management and land use. PMID:23713120

  5. Handbook of thin film deposition processes and techniques principles, methods, equipment and applications

    CERN Document Server

    Seshan, Krishna

    2002-01-01

    New second edition of the popular book on deposition (first edition by Klaus Schruegraf) for engineers, technicians, and plant personnel in the semiconductor and related industries. This book traces the technology behind the spectacular growth in the silicon semiconductor industry and the continued trend in miniaturization over the last 20 years. This growth has been fueled in large part by improved thin film deposition techniques and the development of highly specialized equipment to enable this deposition. The book includes much cutting-edge material. Entirely new chapters on contamination and contamination control describe the basics and the issues-as feature sizes shrink to sub-micron dimensions, cleanliness and particle elimination has to keep pace. A new chapter on metrology explains the growth of sophisticated, automatic tools capable of measuring thickness and spacing of sub-micron dimensions. The book also covers PVD, laser and e-beam assisted deposition, MBE, and ion beam methods to bring together a...

  6. Textured indium tin oxide thin films by chemical solution deposition and rapid thermal processing

    International Nuclear Information System (INIS)

    Mottern, Matthew L.; Tyholdt, Frode; Ulyashin, Alexander; Helvoort, Antonius T.J. van; Verweij, Henk; Bredesen, Rune

    2007-01-01

    The microstructure of state-of-the-art chemical solution deposited indium tin oxide thin films typically consists of small randomly oriented grains, high porosity and poor homogeneity. The present study demonstrates how the thin film microstructure can be improved significantly by tailoring the precursor solutions and deposition conditions to be kinetically and thermodynamically favorable for generation of homogeneous textured thin films. This is explained by the occurrence of a single heterogeneous nucleation mechanism. The as-deposited thin films, crystallized at 800 deg. C, have a high apparent density, based on a refractive index of ∼ 1.98 determined by single wavelength ellipsometry at 633 nm. The microstructure of the films consists of columnar grains with preferred orientation as determined by X-ray diffraction and transmission electron microscopy. The resistivity, measured by the four point probe method, is ∼ 2 x 10 -3 Ω cm prior to post-deposition treatments

  7. Impact of residual by-products from tungsten film deposition on process integration due to nonuniformity of the tungsten film

    CERN Document Server

    Sidhwa, A; Gandy, T; Melosky, S; Brown, W; Ang, S; Naseem, H; Ulrich, R

    2002-01-01

    The effects of residual by products from a tungsten film deposition process and their impact on process integration due to the nonuniformity of the tungsten film were investigated in this work. The tungsten film deposition process involves three steps: nucleation, stabilization, and tungsten bulk fill. Six experiments were conducted in search for a solution to the problem. The resulting data suggest that excess nitrogen left in the chamber following the tungsten nucleation step, along with residual by products, causes a shift in the tungsten film uniformity during the tungsten bulk fill process. Data reveal that, due to the residual by products, an abnormal grain growth occurs causing a variation in the tungsten thickness across the wafer during the bulk fill step. Although several possible solutions were revealed by the experiments, potential integration problems limited the acceptable solutions to one. The solution chosen was the introduction of a 10 s pumpdown immediately following the nucleation step. Thi...

  8. Understanding Patients' Process to Use Medical Marijuana: A Southern New Jersey Community Engagement Project.

    Science.gov (United States)

    Crowell, Tara L

    2016-09-01

    Given the necessity to better understand the process patients need to go through in order to seek treatment via medical marijuana, this study investigates this process to better understand this phenomenon. Specifically, Compassion Care Foundation (CCF) and Stockton University worked together to identify a solution to this problem. Specifically, 240 new patients at CCF were asked to complete a 1-page survey regarding various aspects associated with their experience prior to their use of medicinal marijuana-diagnosis, what prompted them to seek treatment, level of satisfaction with specific stages in the process, total length of time the process took, and patient's level of pain. Results reveal numerous patient diagnoses for which medical marijuana is being prescribed; the top 4 most common are intractable skeletal spasticity, chronic and severe pain, multiple sclerosis, and inflammatory bowel disease. Next, results indicate a little over half of the patients were first prompted to seek alternative treatment from their physicians, while the remaining patients indicated that other sources such as written information along with friends, relatives, media, and the Internet persuaded them to seek treatment. These data indicate that a variety of sources play a role in prompting patients to seek alternative treatment and is a critical first step in this process. Additional results posit that once patients began the process of qualifying to receive medical marijuana as treatment, the process seemed more positive even though it takes patients on average almost 6 months to obtain their first treatment after they started the process. Finally, results indicate that patients are reporting a moderately high level of pain prior to treatment. Implication of these results highlights several important elements in the patients' initial steps toward seeking medical marijuana, along with the quality and quantity of the process patients must engage in prior to obtaining treatment. In

  9. Extension of the lifetime of tantalum filaments in the hot-wire (Cat) 3 Chemical Vapor Deposition process

    CSIR Research Space (South Africa)

    Knoesen, D

    2008-01-01

    Full Text Available , the filament is again exposed to pure hydrogen for a minimum of 5 min, the chamber then again evacuated to a vacuum better than 8×10−8 mbar before cutting the power to the filament. This has resulted in a filament life of 11 months, with an accumulated... process only treated by annealing before a deposition run, did not last long, and typically broke after 3 to 5 h of accumulated deposition time. Silicide formation is found along the full length of these tantalum filaments, with severe structural...

  10. Simulation of a processes of a moving base coating with uniform films by method of physical deposition

    International Nuclear Information System (INIS)

    Avilov, A.A.; Grigorevskij, A.V.; Dudnik, S.F.; Kiryukhin, N.M.; Klyukovich, V.A.; Sagalovich, V.V.

    1989-01-01

    Computational algorithm is developed for calculating thickness of films deposited by physical methods onto a backing of any shape, moving along a given trajectory. The sugegsted algorithm makes it possible to carry out direct simulation on film deposition process and to optimize sources arrangement for obtaining films with a required degree of uniformity. Condensate distribution on a rotating sphere was calculated and here presented. A satisfactory agreement of calculated values with experimental data on metal films obtained by electron-arc spraying, was established

  11. High-energy high-rate pulsed-power processing of materials by powder consolidation and by railgun deposition. Technical report (Final), 10 April 1985-10 February 1987

    Energy Technology Data Exchange (ETDEWEB)

    Persad, C.; Marcus, H.L.; Weldon, W.F.

    1987-03-31

    This exploratory research program was initiated to investigate the potential of using pulse power sources for powder consolidation, deposition and other high-energy high-rate processing. The characteristics of the high-energy-high-rate (1MJ/s) powder consolidation using megampere current pulses from a homopolar generator, were defined. Molybdenum Alloy TZM, a nickel-based metallic glass, copper/graphite composites, and P/M aluminum alloy X7091 were investigated. The powder-consolidation process produced high densification rates. Density values of 80% to 99% could be obtained with subsecond high-temperature exposure. Specific energy input and applied pressure were controlling process parameters. Time temperature transformation (TTT) concepts underpin a fundamental understanding of pulsed power processing. Inherent control of energy input, and time-to-peak processing temperature developed to be held to short times. Deposition experiments were conducted using an exploding-foil device (EFD) providing an armature feed to railgun mounted in a vacuum chamber. The material to be deposited - in plasma, gas, liquid, or solid state - was accelerated electromagnetically in the railgun and deposited on a substrate. Deposits of a wide variety of single- and multi-specie materials were produced on several types of substrates. In a series of ancillary experiments, pulsed-skin-effect heating and self quenching of metallic conductors was discovered to be a new means of surface modification by high-energy high-rate-processing.

  12. Optical monitoring of surface processes relevant to thin film growth by chemical vapour deposition

    International Nuclear Information System (INIS)

    Simcock, Michael Neil

    2002-01-01

    This thesis reports on the investigation of the use of reflectance anisotropy spectroscopy (RAS) as an in-situ monitor for the preparation and oxidation of GaAs(100) c(4x4) surfaces using a CVD 2000 MOCVD reactor. These surfaces were oxidised using air. It was found that it was possible to follow surface degradation using RA transients at 2.6eV and 4eV. From this data it was possible to speculate on the nature of the surface oxidation process. A study was performed into the rate of surface degradation under different concentrations of air, it was found that the relation between the air concentration and the surface degradation was complicated but that the behaviour of the first third of the degradation approximated a first order behaviour. An estimation of the activation energy of the process was then made, and an assessment of the potential use of the glove-box for STM studies which is an integral part of the MOCVD equipment was also made. Following this, a description is given of the construction of an interferometer for monitoring thin film growth. An investigation is also described into two techniques designed to evaluate the changes in reflected intensity as measured by an interferometer. The first technique uses an iteration procedure to determine the film thickness from the reflection data. This is done using a Taylor series expansion of the thin film reflection function to iterate for the thickness. Problems were found with the iteration when applied to noisy data, these were solved by using a least squares fit to smooth the data. Problems were also found with the iteration at the turning points these were solved using the derivative of the function and by anticipating the position of the turning points. The second procedure uses the virtual interface method to determine the optical constants of the topmost deposited material, the virtual substrate, and the growth rate. This method is applied by using a Taylor series expansion of the thin film reflection

  13. Beyond Homophily: A Decade of Advances in Understanding Peer Influence Processes

    Science.gov (United States)

    Brechwald, Whitney A.; Prinstein, Mitchell J.

    2013-01-01

    This article reviews empirical and theoretical contributions to a multidisciplinary understanding of peer influence processes in adolescence over the past decade. Five themes of peer influence research from this decade were identified, including a broadening of the range of behaviors for which peer influence occurs, distinguishing the sources of influence, probing the conditions under which influence is amplified/attenuated (moderators), testing theoretically based models of peer influence processes (mechanisms), and preliminary exploration of behavioral neuroscience perspectives on peer influence. This review highlights advances in each of these areas, underscores gaps in current knowledge of peer influence processes, and outlines important challenges for future research. PMID:23730122

  14. Understanding the Role of Water on Electron-Initiated Processes and Radical Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Garrett, Bruce C [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Colson, Steven D [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Dixon, David A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Laufer, Allan H [US Department of Energy Office of Science Office of Basic Energy Sciences; Ray, Douglas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2003-06-10

    On September 26–28, 2002, a workshop entitled “Understanding the Role of Water on Electron-Initiated Processes and Radical Chemistry” was held to assess new research opportunities in electron-driven processes and radical chemistry in aqueous systems. Of particular interest was the unique and complex role that the structure of water plays in influencing these processes. Novel experimental and theoretical approaches to solving long-standing problems in the field were explored. A broad selection of participants from universities and the national laboratories contributed to the workshop, which included scientific and technical presentations and parallel sessions for discussions and report writing.

  15. Material insights of HfO2-based integrated 1-transistor-1-resistor resistive random access memory devices processed by batch atomic layer deposition.

    Science.gov (United States)

    Niu, Gang; Kim, Hee-Dong; Roelofs, Robin; Perez, Eduardo; Schubert, Markus Andreas; Zaumseil, Peter; Costina, Ioan; Wenger, Christian

    2016-06-17

    With the continuous scaling of resistive random access memory (RRAM) devices, in-depth understanding of the physical mechanism and the material issues, particularly by directly studying integrated cells, become more and more important to further improve the device performances. In this work, HfO2-based integrated 1-transistor-1-resistor (1T1R) RRAM devices were processed in a standard 0.25 μm complementary-metal-oxide-semiconductor (CMOS) process line, using a batch atomic layer deposition (ALD) tool, which is particularly designed for mass production. We demonstrate a systematic study on TiN/Ti/HfO2/TiN/Si RRAM devices to correlate key material factors (nano-crystallites and carbon impurities) with the filament type resistive switching (RS) behaviours. The augmentation of the nano-crystallites density in the film increases the forming voltage of devices and its variation. Carbon residues in HfO2 films turn out to be an even more significant factor strongly impacting the RS behaviour. A relatively higher deposition temperature of 300 °C dramatically reduces the residual carbon concentration, thus leading to enhanced RS performances of devices, including lower power consumption, better endurance and higher reliability. Such thorough understanding on physical mechanism of RS and the correlation between material and device performances will facilitate the realization of high density and reliable embedded RRAM devices with low power consumption.

  16. Toward theoretical understanding of the fertility preservation decision-making process: Examining information processing among young women with cancer

    Science.gov (United States)

    Hershberger, Patricia E.; Finnegan, Lorna; Altfeld, Susan; Lake, Sara; Hirshfeld-Cytron, Jennifer

    2014-01-01

    Background Young women with cancer now face the complex decision about whether to undergo fertility preservation. Yet little is known about how these women process information involved in making this decision. Objective The purpose of this paper is to expand theoretical understanding of the decision-making process by examining aspects of information processing among young women diagnosed with cancer. Methods Using a grounded theory approach, 27 women with cancer participated in individual, semi-structured interviews. Data were coded and analyzed using constant-comparison techniques that were guided by five dimensions within the Contemplate phase of the decision-making process framework. Results In the first dimension, young women acquired information primarily from clinicians and Internet sources. Experiential information, often obtained from peers, occurred in the second dimension. Preferences and values were constructed in the third dimension as women acquired factual, moral, and ethical information. Women desired tailored, personalized information that was specific to their situation in the fourth dimension; however, women struggled with communicating these needs to clinicians. In the fifth dimension, women offered detailed descriptions of clinician behaviors that enhance or impede decisional debriefing. Conclusion Better understanding of theoretical underpinnings surrounding women’s information processes can facilitate decision support and improve clinical care. PMID:24552086

  17. Toward theoretical understanding of the fertility preservation decision-making process: examining information processing among young women with cancer.

    Science.gov (United States)

    Hershberger, Patricia E; Finnegan, Lorna; Altfeld, Susan; Lake, Sara; Hirshfeld-Cytron, Jennifer

    2013-01-01

    Young women with cancer now face the complex decision about whether to undergo fertility preservation. Yet little is known about how these women process information involved in making this decision. The purpose of this article is to expand theoretical understanding of the decision-making process by examining aspects of information processing among young women diagnosed with cancer. Using a grounded theory approach, 27 women with cancer participated in individual, semistructured interviews. Data were coded and analyzed using constant-comparison techniques that were guided by 5 dimensions within the Contemplate phase of the decision-making process framework. In the first dimension, young women acquired information primarily from clinicians and Internet sources. Experiential information, often obtained from peers, occurred in the second dimension. Preferences and values were constructed in the third dimension as women acquired factual, moral, and ethical information. Women desired tailored, personalized information that was specific to their situation in the fourth dimension; however, women struggled with communicating these needs to clinicians. In the fifth dimension, women offered detailed descriptions of clinician behaviors that enhance or impede decisional debriefing. Better understanding of theoretical underpinnings surrounding women's information processes can facilitate decision support and improve clinical care.

  18. Reduced thermal budget processing of Y--Ba--Cu--O high temperature superconducting thin films by metalorganic chemical vapor deposition

    International Nuclear Information System (INIS)

    Singh, R.; Sinha, S.; Hsu, N.J.; Ng, J.T.C.; Chou, P.; Thakur, R.P.S.; Narayan, J.

    1991-01-01

    Metalorganic chemical vapor deposition (MOCVD) has the potential of emerging as a viable technique to fabricate ribbons, tapes, coated wires, and the deposition of films of high temperature superconductors, and related materials. As a reduced thermal budget processing technique, rapid isothermal processing (RIP) based on incoherent radiation as the source of energy can be usefully coupled to conventional MOCVD. In this paper we report on the deposition and characterization of high quality superconducting thin films of Y--Ba--Cu--O (YBCO) on MgO and SrTiO 3 substrates by RIP assisted MOCVD. By using a mixture of N 2 O and O 2 as the oxygen source films deposited initially at 600 degree C for 1 min and then at 740 degree C for 30 min are primarily c-axis oriented and with zero resistance being observed at 84 and 89 K for MgO and SrTiO 3 substrates, respectively. The zero magnetic field current densities at 77 K for MgO and SrTiO 3 substrates are 1.2x10 6 and 1.5x10 6 A/cm 2 , respectively. It is envisaged that high energy photons from the incoherent light source and the use of a mixture of N 2 O and O 2 as the oxygen source, assist chemical reactions and lower overall thermal budget for processing of these films

  19. Influence of Oxygen Partial Pressure during Processing on the Thermoelectric Properties of Aerosol-Deposited CuFeO₂.

    Science.gov (United States)

    Stöcker, Thomas; Exner, Jörg; Schubert, Michael; Streibl, Maximilian; Moos, Ralf

    2016-03-24

    In the field of thermoelectric energy conversion, oxide materials show promising potential due to their good stability in oxidizing environments. Hence, the influence of oxygen partial pressure during synthesis on the thermoelectric properties of Cu-Delafossites at high temperatures was investigated in this study. For these purposes, CuFeO₂ powders were synthetized using a conventional mixed-oxide technique. X-ray diffraction (XRD) studies were conducted to determine the crystal structures of the delafossites associated with the oxygen content during the synthesis. Out of these powders, films with a thickness of about 25 µm were prepared by the relatively new aerosol-deposition (AD) coating technique. It is based on a room temperature impact consolidation process (RTIC) to deposit dense solid films of ceramic materials on various substrates without using a high-temperature step during the coating process. On these dense CuFeO₂ films deposited on alumina substrates with electrode structures, the Seebeck coefficient and the electrical conductivity were measured as a function of temperature and oxygen partial pressure. We compared the thermoelectric properties of both standard processed and aerosol deposited CuFeO₂ up to 900 °C and investigated the influence of oxygen partial pressure on the electrical conductivity, on the Seebeck coefficient and on the high temperature stability of CuFeO₂. These studies may not only help to improve the thermoelectric material in the high-temperature case, but may also serve as an initial basis to establish a defect chemical model.

  20. Morphology and processes associated with the accumulation of the fine-grained sediment deposit on the southern New England shelf

    Science.gov (United States)

    Twichell, David C.; McClennen, Charles E.; Butman, Bradford

    1981-01-01

    A 13,000 km2 area of the southern New England Continental Shelf which is covered by anomalously fine-grained sediment has been surveyed by means of high-resolution, seismic-reflection and side-scan sonar techniques to map its morphology and structure, and a near-bottom instrument system contributed to understanding present activity of the deposit. Seismic-reflection profiles show that the fine-grained deposit, which is as much as 13 m thick, has accumulated during the last transgression because it rests on a reflector that is geomorphically similar to and continuous with the Holocene transgressive sand sheet still exposed on the shelf to the west. The ridge and swale topography comprising the sand sheet on the shelf off New Jersey and Long Island are relict in origin as these same features are found buried under the fine sediment deposit. Southwestward migrating megaripples observed on the sonographs in the eastern part of the deposit are evidence that sediment is still actively accumulating in this area. In the western part of the deposit, where surface sediment is composed of silt plus clay, evidence of present sediment mobility consists of changes in the near-bottom, suspended-matter concentrations primarily associated with storms. Nantucket Shoals and Georges Bank are thought to be the sources for the fine-textured sediment. Storms and strong tidal currents in these shoal areas may still erode available fine-grained material, which then is transported westward by the mean drift to the southern New England Shelf, where a comparatively tranquil environment permits deposition of the fine material.

  1. Enhanced process understanding and multivariate prediction of the relationship between cell culture process and monoclonal antibody quality.

    Science.gov (United States)

    Sokolov, Michael; Ritscher, Jonathan; MacKinnon, Nicola; Souquet, Jonathan; Broly, Hervé; Morbidelli, Massimo; Butté, Alessandro

    2017-09-01

    This work investigates the insights and understanding which can be deduced from predictive process models for the product quality of a monoclonal antibody based on designed high-throughput cell culture experiments performed at milliliter (ambr-15 ® ) scale. The investigated process conditions include various media supplements as well as pH and temperature shifts applied during the process. First, principal component analysis (PCA) is used to show the strong correlation characteristics among the product quality attributes including aggregates, fragments, charge variants, and glycans. Then, partial least square regression (PLS1 and PLS2) is applied to predict the product quality variables based on process information (one by one or simultaneously). The comparison of those two modeling techniques shows that a single (PLS2) model is capable of revealing the interrelationship of the process characteristics to the large set product quality variables. In order to show the dynamic evolution of the process predictability separate models are defined at different time points showing that several product quality attributes are mainly driven by the media composition and, hence, can be decently predicted from early on in the process, while others are strongly affected by process parameter changes during the process. Finally, by coupling the PLS2 models with a genetic algorithm first the model performance can be further improved and, most importantly, the interpretation of the large-dimensioned process-product-interrelationship can be significantly simplified. The generally applicable toolset presented in this case study provides a solid basis for decision making and process optimization throughout process development. © 2017 American Institute of Chemical Engineers Biotechnol. Prog., 33:1368-1380, 2017. © 2017 American Institute of Chemical Engineers.

  2. Studies on ion scattering and sputtering processes relevant to ion beam sputter deposition of multicomponent thin films

    International Nuclear Information System (INIS)

    Auciello, O.; Ameen, M.S.; Kingon, A.I.

    1989-01-01

    Results from computer simulation and experiments on ion scattering and sputtering processes in ion beam sputter deposition of high Tc superconducting and ferroelectric thin films are presented. It is demonstrated that scattering of neutralized ions from the targets can result in undesirable erosion of, and inert gas incorporation in, the growing films, depending on the ion/target atom ass ratio and ion beam angle of incidence/target/substrate geometry. The studies indicate that sputtering Kr + or Xe + ions is preferable to the most commonly used Ar + ions, since the undesirable phenomena mentioned above are minimized for the first two ions. These results are used to determine optimum sputter deposition geometry and ion beam parameters for growing multicomponent oxide thin films by ion beam sputter-deposition. 10 refs., 5 figs

  3. Understanding the formation process of exceptionally long fullerene-based nanowires

    DEFF Research Database (Denmark)

    Solov'yov, Ilia; Geng, Junfeng; Solov'yov, Andrey V.

    2009-01-01

    solution of C$_60$. We have performed a thorough theoretical analysis, aiming at gaining an in-depth understanding of the exceptionally large aspect ratio of C$_60$-based nanowires. By accounting for different interactions in the system we have calculated the structures of the unit cell and determined...... the role of the fullerene and of the solvent molecules in the crystallization process of the nanowires. We have calculated the adhesion energy of C$_60$ molecules to the nanowire surface, and on the basis of this explained the growth anisotropy of the crystal. To get a more profound understanding...

  4. Transport and solubility of Hetero-disperse dry deposition particulate matter subject to urban source area rainfall-runoff processes

    Science.gov (United States)

    Ying, G.; Sansalone, J.

    2010-03-01

    SummaryWith respect to hydrologic processes, the impervious pavement interface significantly alters relationships between rainfall and runoff. Commensurate with alteration of hydrologic processes the pavement also facilitates transport and solubility of dry deposition particulate matter (PM) in runoff. This study examines dry depositional flux rates, granulometric modification by runoff transport, as well as generation of total dissolved solids (TDS), alkalinity and conductivity in source area runoff resulting from PM solubility. PM is collected from a paved source area transportation corridor (I-10) in Baton Rouge, Louisiana encompassing 17 dry deposition and 8 runoff events. The mass-based granulometric particle size distribution (PSD) is measured and modeled through a cumulative gamma function, while PM surface area distributions across the PSD follow a log-normal distribution. Dry deposition flux rates are modeled as separate first-order exponential functions of previous dry hours (PDH) for PM and suspended, settleable and sediment fractions. When trans-located from dry deposition into runoff, PSDs are modified, with a d50m decreasing from 331 to 14 μm after transport and 60 min of settling. Solubility experiments as a function of pH, contact time and particle size using source area rainfall generate constitutive models to reproduce pH, alkalinity, TDS and alkalinity for historical events. Equilibrium pH, alkalinity and TDS are strongly influenced by particle size and contact times. The constitutive leaching models are combined with measured PSDs from a series of rainfall-runoff events to demonstrate that the model results replicate alkalinity and TDS in runoff from the subject watershed. Results illustrate the granulometry of dry deposition PM, modification of PSDs along the drainage pathway, and the role of PM solubility for generation of TDS, alkalinity and conductivity in urban source area rainfall-runoff.

  5. Exogenous deposits

    International Nuclear Information System (INIS)

    Khasanov, A.Kh.

    1988-01-01

    Exogenous deposits forming as a result of complex exogenous processes, passed under the influence of outside forces on the Earth surface. To them relate physical and chemical weathering, decomposition and decay of mineral masses, redistribution and transportation of material, forming and deposit of new minerals and ores steady on the earth surface conditions

  6. Alloying process of sputter-deposited Ti/Ni multilayer thin films

    International Nuclear Information System (INIS)

    Cho, H.; Kim, H.Y.; Miyazaki, S.

    2006-01-01

    Alloying process of a Ti/Ni multilayer thin film was investigated in detail by differential scanning calorimetry (DSC), X-ray diffractometry (XRD) and transmission electron microscopy (TEM). The Ti/Ni multilayer thin film was prepared by depositing Ti and Ni layers alternately on a SiO 2 /Si substrate. The number of each metal layer was 100, and the total thickness was 3 μm. The alloy composition was determined as Ti-51 at.%Ni by electron probe micro analysis (EPMA). The DSC curve exhibited three exothermic peaks at 621, 680 and 701 K during heating the as-sputtered multilayer thin film. In order to investigate the alloying process, XRD and TEM observation was carried out for the specimens heated up to various temperatures with the heating rate same as the DSC measurement. The XRD profile of the as-sputtered film revealed only diffraction peaks of Ti and Ni. But reaction layers of 3 nm in thickness were observed at the interfaces of Ti and Ni layers in cross-sectional TEM images. The reaction layer was confirmed as an amorphous phase by the nano beam diffraction analysis. The XRD profiles exhibited that the intensity of Ti diffraction peak decreased in the specimen heat-treated above 600 K. The peak from Ni became broad and shifted to lower diffraction angle. The amorphous layer thickened up to 6 nm in the specimen heated up to 640 K. The diffraction peak corresponding to Ti-Ni B2 phase appeared and the peak from Ni disappeared for the specimen heated up to 675 K. The Ti-Ni B2 crystallized from the amorphous reaction layer. After further heating above the third exothermic peak, the intensity of the peak from the Ti-Ni B2 phase increased, the peak from Ti disappeared and the peaks corresponding to Ti 2 Ni appeared. The Ti 2 Ni phase was formed by the reaction of the Ti-Ni B2 and Ti

  7. Understanding the nature of the manganese hot dip phosphatizing process of steel

    Energy Technology Data Exchange (ETDEWEB)

    Alvarado M, G.; Fuentes A, J. C.; Salinas R, A.; Rodriguez V, F. J., E-mail: juan.fuentes@cinvestav.edu.mx [IPN, Centro de Investigacion y de Estudios Avanzados, Unidad Saltillo, Av. Industria Metalurgica No. 1062, Parque Industrial Ramos Arizpe, 25900 Saltillo, Coahuila (Mexico)

    2013-07-01

    In this work, the phosphatizing process of steel is investigated using open circuit potential and Tafel curves as well as scanning electron microscopy and energy dispersive X-ray spectroscopy. The results reveal that a ph of 2.57 in the phosphatizing solution promotes the dissociation of phosphoric acid which assist the formation of the manganese tertiary salt (Mn{sub 3}(PO{sub 4}){sub 2}), which is deposited on the substrate. It was also observed that an increase in the temperature from 25 to 90 C and the presence of HNO{sub 3} as catalysts enhances the manganese phosphatizing kinetics. On the other hand, the generation of iron phosphates and oxides is predominant at a ph of 1 and 90 C. These observations are supported by species distribution and Pourbaix thermodynamic diagrams. (Author)

  8. Understanding the nature of the manganese hot dip phosphatizing process of steel

    International Nuclear Information System (INIS)

    Alvarado M, G.; Fuentes A, J. C.; Salinas R, A.; Rodriguez V, F. J.

    2013-01-01

    In this work, the phosphatizing process of steel is investigated using open circuit potential and Tafel curves as well as scanning electron microscopy and energy dispersive X-ray spectroscopy. The results reveal that a ph of 2.57 in the phosphatizing solution promotes the dissociation of phosphoric acid which assist the formation of the manganese tertiary salt (Mn 3 (PO 4 ) 2 ), which is deposited on the substrate. It was also observed that an increase in the temperature from 25 to 90 C and the presence of HNO 3 as catalysts enhances the manganese phosphatizing kinetics. On the other hand, the generation of iron phosphates and oxides is predominant at a ph of 1 and 90 C. These observations are supported by species distribution and Pourbaix thermodynamic diagrams. (Author)

  9. UNDERSTANDING THAI CULTURE AND ITS IMPACT ON REQUIREMENTS ENGINEERING PROCESS MANAGEMENT DURING INFORMATION SYSTEMS DEVELOPMENT

    Directory of Open Access Journals (Sweden)

    Theerasak Thanasankit

    2002-01-01

    Full Text Available This paper explores the impact of Thai culture on managing the decision making process in requirements engineering and contribution a better understand of its influence on the management of requirements engineering process. The paper illustrates the interaction of technology and culture and shows that rather than technology changing culture, culture can change the way technology is used. Thai culture is naturally inherent in Thai daily life and Thais bring that into their work practices. The concepts of power and uncertainty in Thai culture contribute toward hierarchical forms of communication and decision making process in Thailand, especially during requirements engineering, where information systems requirements need to be established for further development. The research shows that the decision making process in Thailand tends to take a much longer time, as every stage during requirements engineering needs to be reported to management for final decisions. The tall structure of Thai organisations also contributes to a bureaucratic, elongated decision-making process during information systems development. Understanding the influence of Thai culture on requirements engineering and information systems development will assist multinational information systems consulting organisations to select, adapt, better manage, or change requirements engineering process and information systems developments methodologies to work best with Thai organisations.

  10. Development of coatings for ultrasonic additive manufacturing sonotrode using laser direct metal deposition process

    Energy Technology Data Exchange (ETDEWEB)

    Niyanth S, Niyanth [ORNL; Dehoff, Ryan R [ORNL; Jordan, Brian H [ORNL; Babu, Sudarsanam Suresh [ORNL

    2016-10-01

    ORNL partnered with Fabrisonic, LLC to develop galling resistant hard facing coatings on sonotrodes used to fabricate 3D printed materials using ultrasonic additive manufacturing. The development and deployment of a coated sonotrode is expected to push the existing state of the art to facilitate the solidstate additive manufacturing of hard steels and titanium alloys. To this effect a structurally amorphous stainless steel material and cobalt chrome material were deposited on the sonotrode material. Both the deposits showed good adhesion to the substrate. The coatings made using the structurally amorphous steel materials showed cracking during the initial trials and cracking was eliminated by deposition on a preheated substrate. Both the coatings show hardness in excess of 600 HVN. Thus the phase 1 of this project has been used to identify suitable materials to use to coat the sonotrode. Despite the fact that successful deposits were obtained, the coatings need to be evaluated by performing detailed galling tests at various temperatures. In addition field tests are also necessary to test the stability of these coatings in a high cycle ultrasonic vibration mode. If awarded, phase 2 of the project would be used to optimize the composition of the deposit material to maximize galling resistance. The industrial partner would then use the coated sonotrode to fabricate builds made of austenitic stainless steel to test the viability of using a coated sonotrode.

  11. The role of metasomatism in the balance of halogens in ore-forming process at porphyry Cu-Mo deposits

    Science.gov (United States)

    Berzina, A. N.

    2009-04-01

    Volatile components play an important role in the evolution of ore-magmatic systems and their ore potential. Of special interest are fluorine and chlorine compounds that principally control the transportation of ore elements by the fluid in a magmatic process and under high-temperature hydrothermal conditions. Study of the evolution of fluorine-chlorine activity in the ore-forming process and their source is usually based on analysis of their magmatic history, whereas the additional source of fluorine and chlorine released during metasomatic alteration of rocks hosting mineralization is poorly discussed in the existing literature. Based on microprobe data on Cl and F abundances in halogen-containing minerals (biotite, amphibole, apatite, titanite) in intrusive rocks and their hydrothermally altered varieties, the role of metasomatic processes in the balance of volatiles in the ore-forming system is discussed by the example of porphyry Cu-Mo deposits of Siberia (Russia) and Mongolia. Two groups of the deposits are considered: copper-molybdenum (Erdenetiin Ovoo, Mongolia and Aksug, Russia) with prevailing propylitic and phyllic alteration and molybdenum-copper (Sora, Russia), with predominant potassic alteration. All types of hydrothermal alterations have led to drastic decrease in Cl contents in metasomatic minerals as compared with halogen-containing magmatic minerals. All studied deposits (particularly those where propylitic and phyllic alteration were developed) show a nearly complete chlorine removal from altered halogen-containing rock-forming minerals (biotite and amphibole). The Cl content in amphibole decreases several times at the stage of replacement with actinolite in the process of propylitization. In the later chlorites (ripidolite and brunsvigite) that replace amphibole, actinolite, and biotite, chlorine is not detected by microprobe (detection limit 0.01-0.02% Cl). Chlorine was also not detected in white micas (muscovite-phengite series) in quartz

  12. Photocatalytic evaluation of self-assembled porous network structure of ferric oxide film fabricated by dry deposition process

    Energy Technology Data Exchange (ETDEWEB)

    Park, Yunchan; Kim, Hyungsub; Lee, Geon-Yong; Pawar, Rajendra C.; Lee, Jai-Sung; Lee, Caroline Sunyong, E-mail: sunyonglee@hanyang.ac.kr

    2016-09-15

    Ferric oxide powder in the alpha phase (α-Fe{sub 2}O{sub 3}) was deposited on an aluminum oxide (Al{sub 2}O{sub 3}) substrate by a nanoparticle deposition system using the dry deposition method. X-ray diffraction (XRD) images confirmed that the phase of the deposited α-Fe{sub 2}O{sub 3} did not change. The deposited α-Fe{sub 2}O{sub 3} was characterized in terms of its microstructure using scanning electron microscopy (SEM). A porous network microstructure formed when small agglomerates of Fe{sub 2}O{sub 3} (SAF) were deposited. The deposition and formation mechanism of the microstructure were investigated using SEM and three-dimensional (3D) profile analysis. First, a dense coating layer formed when the film was thinner than the particle size. After that, as the film thickness increased to over 5 μm, the porous network structure formed by excavating the surface of the coating layer as it was bombarded by particles. Rhodamine B (RhB) was degraded after 6 h of exposure to the Fe{sub 2}O{sub 3} coating layer with SAF, which has good photocatalytic activity and a high porous network structure. The kinetic rate constants of the SAF and large agglomerates of Fe{sub 2}O{sub 3} (LAF) were calculated to be 0.197(h{sup −1}) and 0.128(h{sup −1}), respectively, based on the absorbance results. Using linear sweep voltammetry, we confirmed that the photoelectric effect occurred in the coating layer by measuring the resulting current under illuminated and dark conditions. - Graphical abstract: Self-assembled porous photocatalytic film fabricated by dry deposition method for water purification. - Highlights: • Different sizes of Fe{sub 2}O{sub 3} agglomerates were used to form porous network structure. • Fe{sub 2}O{sub 3} agglomerate particles were deposited using solvent-free process. • Self-assembled porous network microstructure formed better with small agglomerates of Fe{sub 2}O{sub 3}. • Fabricated porous network structure showed its potential to be used

  13. A Humidity Sensor Based on Silver Nanoparticles Thin Film Prepared by Electrostatic Spray Deposition Process

    Directory of Open Access Journals (Sweden)

    Thutiyaporn Thiwawong

    2013-01-01

    Full Text Available In this work, thin film of silver nanoparticles for humidity sensor application was deposited by electrostatic spray deposition technique. The influence of the deposition times on properties of films was studied. The crystal structures of sample films, their surface morphology, and optical properties have been investigated by X-ray diffraction (XRD, field emission scanning electron microscopy (FE-SEM, and UV-VIS spectrophotometer, respectively. The crystalline structure of silver nanoparticles thin film was found in the orientation of (100 and (200 planes of cubic structure at diffraction angles 2θ  =  38.2° and 44.3°, respectively. Moreover, the silver nanoparticles thin films humidity sensor was fabricated onto the interdigitated electrodes. The sensor exhibited the humidity adsorption and desorption properties. The sensing mechanisms of the device were also elucidated by complex impedance analysis.

  14. Correlations between optical properties, microstructure, and processing conditions of Aluminum nitride thin films fabricated by pulsed laser deposition

    International Nuclear Information System (INIS)

    Baek, Jonghoon; Ma, James; Becker, Michael F.; Keto, John W.; Kovar, Desiderio

    2007-01-01

    Aluminum nitride (AlN) films were deposited using pulsed laser deposition (PLD) onto sapphire (0001) substrates with varying processing conditions (temperature, pressure, and laser fluence). We have studied the dependence of optical properties, structural properties and their correlations for these AlN films. The optical transmission spectra of the produced films were measured, and a numerical procedure was applied to accurately determine the optical constants for films of non-uniform thickness. The microstructure and texture of the films were studied using various X-ray diffraction techniques. The real part of the refractive index was found to not vary significantly with processing parameters, but absorption was found to be strongly dependent on the deposition temperature and the nitrogen pressure in the deposition chamber. We report that low optical absorption, textured polycrystalline AlN films can be produced by PLD on sapphire substrates at both low and high laser fluence using a background nitrogen pressure of 6.0 x 10 -2 Pa (4.5 x 10 -4 Torr) of 99.9% purity

  15. Societal rationality; towards an understanding of decision making processes in society

    International Nuclear Information System (INIS)

    Wahlstroem, Bjoern

    2001-01-01

    In a search for new ways to structure decision making on complex and controversial issues it is necessary to build an understanding of why traditional decision making processes break down. One reason is connected to the issues themselves. They represent steps into the unknown and decisions should therefore be made with prudence. A second reason is connected to a track record according to which new technologies are seen as generating more problems than solutions. A third and more fundamental reason is connected to the decision making processes themselves and a need to find better ways to approach difficult questions in the society. One way to approach societal decision making processes is to investigate their hidden rationality in an attempt to understand causes of observed difficulties. The paper is based mainly on observations from the nuclear industry, but it builds also on controversies experienced in attempts to agree on global efforts towards sustainable approaches to development. It builds on an earlier paper, which discussed the basis of rationality both on an individual and a societal level. Research in societal decision making has to rely on a true multi-disciplinary approach. It is nor enough to understand the technical and scientific models by which outcomes are predicted, but it is also necessary to understand how people make sense of their environment and how they co-operate. Rationality is in this connection one of the key concepts, with an understanding that people always are rational in their own frame of action. The challenge in this connection is to understand how this subjective rationality is formed. Societal rationality has to do with the allocation of resources. There are decisions in which several conflicting views have to be considered. Spending time and resources ex ante may support a consensus ex post, but unfortunately there is no panacea for approaching difficult decisions. Decisions with an uncertain future have to be more robust than

  16. Societal rationality; towards an understanding of decision making processes in society

    Energy Technology Data Exchange (ETDEWEB)

    Wahlstroem, Bjoern [Technical Research Centre of Finland, Espoo (Finland)

    2001-07-01

    In a search for new ways to structure decision making on complex and controversial issues it is necessary to build an understanding of why traditional decision making processes break down. One reason is connected to the issues themselves. They represent steps into the unknown and decisions should therefore be made with prudence. A second reason is connected to a track record according to which new technologies are seen as generating more problems than solutions. A third and more fundamental reason is connected to the decision making processes themselves and a need to find better ways to approach difficult questions in the society. One way to approach societal decision making processes is to investigate their hidden rationality in an attempt to understand causes of observed difficulties. The paper is based mainly on observations from the nuclear industry, but it builds also on controversies experienced in attempts to agree on global efforts towards sustainable approaches to development. It builds on an earlier paper, which discussed the basis of rationality both on an individual and a societal level. Research in societal decision making has to rely on a true multi-disciplinary approach. It is nor enough to understand the technical and scientific models by which outcomes are predicted, but it is also necessary to understand how people make sense of their environment and how they co-operate. Rationality is in this connection one of the key concepts, with an understanding that people always are rational in their own frame of action. The challenge in this connection is to understand how this subjective rationality is formed. Societal rationality has to do with the allocation of resources. There are decisions in which several conflicting views have to be considered. Spending time and resources ex ante may support a consensus ex post, but unfortunately there is no panacea for approaching difficult decisions. Decisions with an uncertain future have to be more robust than

  17. Synthesizing the Nanocrytalline Cobalt-Iron Coating Through The Electrodeposition Process With Different Time Deposition

    Science.gov (United States)

    Rozlin Nik Masdek, Nik; Sorfian Hafiz Mansor, Mohd; Salleh, Zuraidah; Hyie, Koay Mei

    2018-03-01

    In the engineering world, electrodeposition or electroplating has become the most popular method of surface coating in improving corrosion behavior and mechanical properties of material. Therefore in this study, CoFe nanoparticle protective coating has been synthesized on the mild steel washer using electrodeposition method. The electrodeposition was conducted in the acidic environment with the pH value range from 1 to 2 with the controlled temperature of 50°C. The influence of deposition time (30, 60, 90 minutes) towards characteristic and properties such as particle size, surface morphology, corrosion behavior, and microhardness were studied in this investigation. Several results can be obtained by doing this experiment and testing. First, the surface morphology of Cobalt Iron (CoFe) on the electrodeposited mild steel washer are obtained. In addition, the microhardness of the mild steel washer due to the different deposition time are determined. Next, the observation on the difference in the grain size of CoFe that has been electrodeposited on the mild steel plate is made. Last but not least, the corrosion behavior was investigated. CoFe nanoparticles deposited for 30 minutes produced the smallest particle size and the highest microhardness of 86.17 and 236.84 HV respectively. The CoFe nanoparticles also exhibit the slowest corrosion rate at 30 minutes as compared to others. The crystalline size also increases when the time deposition is increased. The sample with 30 minute depositon time indicate the smallest crystalline size which is 15nm. The decrement of deposition time plays an important role in synthesizing CoFe nanoparticles with good corrosion resistance and microhardness. CoFe nanoparticles obtained at 30 minutes shows high corrosion resistance compared to others. In a nutshell, it was observed that the decrement of deposition time improved mechanical and corrosion properties of CoFe nanoparticles.

  18. Using a Design Science Perspective to Understand a Complex Design-Based Research Process

    DEFF Research Database (Denmark)

    Bækgaard, Lars

    2012-01-01

    The purpose of the paper is to demonstrate how a design science perspective can be used to describe and understand a set of related design-based research processes. We describe and analyze a case study in a manner that is inspired by design science. The case study involves the design of modeling......-based research processes. And we argue that a design science perspective may be useful for both researchers and practitioners....... tools and the redesign of an information service in a library. We use a set of guidelines from a design science perspective to organize the description and analysis of the case study. By doing this we demonstrate the usefulness of design science as an analytical tool for understanding related design...

  19. Radiation effects on oxide glasses: Importance of energy deposition and relaxation processes

    International Nuclear Information System (INIS)

    Mir, Anamul-Haq

    2015-01-01

    Nuclear waste glass matrices during their disposal will be subjected to self-irradiation by beta and alpha decays. Beta emitting radionuclides due to their short half life time will be the dominant radiation source only during first few hundred years of the disposal, whereas the alpha decays constitute a long term radiation source. Due to intense beta decay and associated gamma rays, the glass matrices can attain temperatures up to 300 C during state 1. The temperature during stage 2 will mainly be defined by the repository conditions. The present work focused on studying the response of various glasses (borosilicate glasses of nuclear waste interest and amorphous silica) to electron irradiation (to understand the response of the pristine glasses to beta decays), single ion beam irradiations with light and heavy ions over a wide stopping power and fluence range (to study the response of the pristine glasses as a function of the electronic and nuclear energy loss so as to establish the necessary conditions for simulating the alpha and recoil nuclei damage), sequential electron-ion irradiations (to understand the impact of the intense beta decay damage during stage 1 on subsequent alpha decay during stage 2, and double ion beam sequential and simultaneous irradiations (to understand the interaction of the alpha particles with recoil nuclei pre-damaged glass and vice versa). The pristine and irradiated samples were characterized using Raman spectroscopy, NMR spectroscopy, micro and nano indentation, AFM, interferometry and ToF-SIMS. Apart from the experimental work, Inelastic Thermal Spike Model (iTSM) for ion track formation was extended to borosilicate glasses to study the possibility of ion track formation in nuclear waste glass matrices. The model was used to study the impact of matrix temperature and stored energy on the ion track threshold, which is otherwise difficult to study experimentally. During electron irradiation, the response of the glasses was found to

  20. Beyond Homophily: A Decade of Advances in Understanding Peer Influence Processes

    OpenAIRE

    Brechwald, Whitney A.; Prinstein, Mitchell J.

    2011-01-01

    This article reviews empirical and theoretical contributions to a multidisciplinary understanding of peer influence processes in adolescence over the past decade. Five themes of peer influence research from this decade were identified, including a broadening of the range of behaviors for which peer influence occurs, distinguishing the sources of influence, probing the conditions under which influence is amplified/attenuated (moderators), testing theoretically based models of peer influence pr...

  1. Neural information processing in cognition: we start to understand the orchestra, but where is the conductor?

    Directory of Open Access Journals (Sweden)

    Guenther ePalm

    2016-01-01

    Full Text Available Research in neural information processing has been successful in the past, providing useful approaches both to practical problems in computer science and to computational models in neuroscience. Recent developments in the area of cognitive neuroscience present new challenges for a computational or theoretical understanding asking for neural information processing models that fulfill criteria or constraints from cognitive psychology, neuroscience and computational efficiency. The most important of these criteria for the evaluation of present and future contributions to this new emerging field are listed at the end of this article.

  2. Two examples of the use of Habitus to understand processes of marginalisation

    DEFF Research Database (Denmark)

    Arp Fallov, Mia; Armstrong, Jo E.

    and weaknesses in applying habitus to understand processes of continuity and change in institutions and individuals’ lives. The concept provides a temporal and spatial framework that is valuable in explaining the embodiment and reproduction of inequality. Using habitus points to the importance of social...... domains; the tension between aspirations to change and resistance to transformation; and the importance of considering values in combating marginalization. However, in showing the complexity of processes of inequality it becomes difficult to derive lessons that are easily translatable into policy actions....... Nevertheless, applying at least some minimal insights from using the concept may offer substantial gains in terms of developing effective policies....

  3. Neural Information Processing in Cognition: We Start to Understand the Orchestra, but Where is the Conductor?

    Science.gov (United States)

    Palm, Günther

    2016-01-01

    Research in neural information processing has been successful in the past, providing useful approaches both to practical problems in computer science and to computational models in neuroscience. Recent developments in the area of cognitive neuroscience present new challenges for a computational or theoretical understanding asking for neural information processing models that fulfill criteria or constraints from cognitive psychology, neuroscience and computational efficiency. The most important of these criteria for the evaluation of present and future contributions to this new emerging field are listed at the end of this article. PMID:26858632

  4. CONTROL PARAMETERS FOR UNDERSTANDING AND PREVENTING PROCESS IMBALANCES IN BIOGAS PLANTS. EMPHAS IS ON VFA DYNAMICS

    DEFF Research Database (Denmark)

    Bangsø Nielsen, Henrik

    environmental changes differ widely between the different groups. As a consequence of this, an unrestrained reactor operation can lead to disturbances in the balance between the different microbial groups, which might lead to reactor failure. Therefore, reliable parameters and tools for efficient process...... control and understanding are necessary. The work of present study was directed towards this challenge. Initially, the response of the anaerobic digestion process to various types of process imbalances was investigated with special focus on volatile fatty acid dynamics (VFA), methane production and pH...... of process imbalances in biogas plants. At Danish full-scale biogas plants the biogas production is normally the only continuously measured parameter. In order to examine the usability of propionate as control parameter a reactor experiment was constructed in which the reactor operation either was carried...

  5. Geomorphic and vegetation processes of the Willamette River floodplain, Oregon: current understanding and unanswered science questions

    Science.gov (United States)

    Wallick, J. Rose; Jones, Krista L.; O'Connor, Jim E.; Keith, Mackenzie K.; Hulse, David; Gregory, Stanley V.

    2013-01-01

    This report summarizes the current understanding of floodplain processes and landforms for the Willamette River and its major tributaries. The area of focus encompasses the main stem Willamette River above Newberg and the portions of the Coast Fork Willamette, Middle Fork Willamette, McKenzie, and North, South and main stem Santiam Rivers downstream of U.S. Army Corps of Engineers dams. These reaches constitute a large portion of the alluvial, salmon-bearing rivers in the Willamette Basin. The geomorphic, or historical, floodplain of these rivers has two zones - the active channel where coarse sediment is mobilized and transported during annual flooding and overbank areas where fine sediment is deposited during higher magnitude floods. Historically, characteristics of the rivers and geomorphic floodplain (including longitudinal patterns in channel complexity and the abundance of side channels, islands and gravel bars) were controlled by the interactions between floods and the transport of coarse sediment and large wood. Local channel responses to these interactions were then shaped by geologic features like bedrock outcrops and variations in channel slope. Over the last 150 years, floods and the transport of coarse sediment and large wood have been substantially reduced in the basin. With dam regulation, nearly all peak flows are now confined to the main channels. Large floods (greater than 10-year recurrence interval prior to basinwide flow regulation) have been largely eliminated. Also, the magnitude and frequency of small floods (events that formerly recurred every 2–10 years) have decreased substantially. The large dams trap an estimated 50–60 percent of bed-material sediment—the building block of active channel habitats—that historically entered the Willamette River. They also trap more than 80 percent of the estimated bed material in the lower South Santiam River and Middle and Coast Forks of the Willamette River. Downstream, revetments further

  6. Understanding decimal proportions: discrete representations, parallel access, and privileged processing of zero.

    Science.gov (United States)

    Varma, Sashank; Karl, Stacy R

    2013-05-01

    Much of the research on mathematical cognition has focused on the numbers 1, 2, 3, 4, 5, 6, 7, 8, and 9, with considerably less attention paid to more abstract number classes. The current research investigated how people understand decimal proportions--rational numbers between 0 and 1 expressed in the place-value symbol system. The results demonstrate that proportions are represented as discrete structures and processed in parallel. There was a semantic interference effect: When understanding a proportion expression (e.g., "0.29"), both the correct proportion referent (e.g., 0.29) and the incorrect natural number referent (e.g., 29) corresponding to the visually similar natural number expression (e.g., "29") are accessed in parallel, and when these referents lead to conflicting judgments, performance slows. There was also a syntactic interference effect, generalizing the unit-decade compatibility effect for natural numbers: When comparing two proportions, their tenths and hundredths components are processed in parallel, and when the different components lead to conflicting judgments, performance slows. The results also reveal that zero decimals--proportions ending in zero--serve multiple cognitive functions, including eliminating semantic interference and speeding processing. The current research also extends the distance, semantic congruence, and SNARC effects from natural numbers to decimal proportions. These findings inform how people understand the place-value symbol system, and the mental implementation of mathematical symbol systems more generally. Copyright © 2013 Elsevier Inc. All rights reserved.

  7. Biomarkers and taphonomic processes in fresh and fossil biosignatures from Hot Spring silica deposits in El Tatio Chile, as a Mars Analogue

    Science.gov (United States)

    Carrizo, D.; Sánchez-García, L.; Parro, V.; Cady, S. L.; Cabrol, N. A.

    2017-09-01

    Biomarkers characterization and taphonomic process of recent and fossil biosignatures in extreme environments with analogies to Mars is essential to understanding how life could develop and survive in this conditions. Siliceous sinter deposits on Mars where similar to those found in the hydrothermal hot springs and geysers from El Tatio, Chile. Organic preservation have been shown in this study. Many different labile functional groups (i.e., carboxylic acids, alcohols, aldehydes, etc.) were found in both "age" samples. A shift in congener pattern for the different lipids families were found and discuss. This results give insight in taphonomic processes actin in this extreme environment, which could be used as a baseline in Mars exploration.

  8. Electron pulsed beam induced processing of thin film surface by Nb3Ge deposited into a stainless steel tape

    International Nuclear Information System (INIS)

    Vavra, I.; Korenev, S.A.

    1988-01-01

    A surface of superconductive thin film of Nb 3 Ge deposited onto a stainless steel tape was processed using the electron beam technique. The electron beam used had the following parameters: beam current density from 400 to 1000 A/cm 2 ; beam energy 100 keV; beam impulse length 300 ns. By theoretical analysis it is shown that the heating of film surface is an adiabatic process. It corresponds to our experimental data and pictures showing a surface remelting due to electron beam influence. After beam processing the superconductive parameters of the film remain unchanged. Roentgenograms have been analysed of Nb 3 Ge film surface recrystallized due to electron beam influence

  9. Late Quaternary changes in depositional processes along the western margin of the Indus Fan

    Digital Repository Service at National Institute of Oceanography (India)

    Govil, P.; Naidu, P.D.

    of coarse-grained sediments composed mostly of sand and silt. The sediments deposited from 375 ka to the present day comprise a pelagic sequence, consisting of pelagic material and clay. The major turbidity flow between 375 and 525 ka resulted...

  10. Chemical processes, desired and undesired, in the selective chemical vapor deposition of tungsten

    International Nuclear Information System (INIS)

    Wilson, R.H.

    1988-01-01

    The deposition of tungsten by the hydrogen reduction of tungsten hexafluoride is discussed in the context of its application in integrated circuits. The overall reaction is relatively simple; however, numerous competing reactions and their implications are discussed. In addition, those areas which could benefit from further investigation are identified

  11. Deposition and processing of airborne nitrogen pollutants in mediterranean-type ecosystems of southern California

    Science.gov (United States)

    Philip J. Riggan; Robert N. Lockwood; Ernest N. Lopez

    1985-01-01

    Atmospheric nitrogen deposition, associated with chronic urban air pollution, has produced stream water nitrate concentrations as high as 7.0 mg of N L-l in chaparral watersheds in the San Gabriel Mountains of Los Angeles County, CA. Stream water [NO3-] and discharge were greatest at high flow and may...

  12. Impact of acid atmospheric deposition on soils : quantification of chemical and hydrologic processes

    NARCIS (Netherlands)

    Grinsven, van J.J.M.

    1988-01-01

    Atmospheric deposition of SO x , NOx and NHx will cause major changes in the chemical composition of solutions in acid soils, which may affect the biological functions of the soil. This thesis deals with quantification of soil acidification by means of chemical

  13. Interpretation of sedimentological processes of coarse-grained deposits applying a novel combined cluster and discriminant analysis

    Directory of Open Access Journals (Sweden)

    Farics Éva

    2017-10-01

    Full Text Available The main aim of this paper is to determine the depositional environments of an Upper-Eocene coarse-grained clastic succession in the Buda Hills, Hungary. First of all, we measured some commonly used parameters of samples (size, amount, roundness and sphericity in a much more objective overall and faster way than with traditional measurement approaches, using the newly developed Rock Analyst application. For the multivariate data obtained, we applied Combined Cluster and Discriminant Analysis (CCDA in order to determine homogeneous groups of the sampling locations based on the quantitative composition of the conglomerate as well as the shape parameters (roundness and sphericity. The result is the spatial pattern of these groups, which assists with the interpretation of the depositional processes. According to our concept, those sampling sites which belong to the same homogeneous groups were likely formed under similar geological circumstances and by similar geological processes.

  14. Considerations on thermic and mechanic processes that appear when 3D printing using ABS fused deposition modelling technology

    Science.gov (United States)

    Amza, Catalin Gheorghe; Niţoi, Dan Florin

    2018-02-01

    3D printers are of recent history, but with an extremely rapid evolution both in technology and hardware involved. At present excellent performances are reached in applications such as 3D printing of various Acrylonitrile butadiene styrene (ABS) plastic parts for house building using Fused Deposition Modelling technology. Nevertheless, the thermic and mechanic processes that appear when manufacturing such plastic components are quite complex. This aspect is very important, especially when one wants to optimize the manufacturing of parts with certain geometrical complexity. The Finite Element Analysis/Modelling (FEA/FEM) is among the few methods that can study the thermic transfer processes and shape modifications that can appear due to non-seamar behavior that takes place when the ABS plastic material is cooling down. The current papers present such an analysis when simulating the deposition of several strings of materials. A thermic analysis is made followed by a study of deformations that appear when the structure cools down.

  15. Understanding Nutrient Processing Under Similar Hydrologic Conditions Along a River Continuum

    Science.gov (United States)

    Garayburu-Caruso, V. A.; Mortensen, J.; Van Horn, D. J.; Gonzalez-Pinzon, R.

    2015-12-01

    Eutrophication is one of the main causes of water impairment across the US. The fate of nutrients in streams is typically described by the dynamic coupling of physical processes and biochemical processes. However, isolating each of these processes and determining its contribution to the whole system is challenging due to the complexity of the physical, chemical and biological domains. We conducted column experiments seeking to understand nutrient processing in shallow sediment-water interactions along representative sites of the Jemez River-Rio Grande continuum (eight stream orders), in New Mexico (USA). For each stream order, we used a set of 6 columns packed with 3 different sediments, i.e., Silica Cone Density Sand ASTM D 1556 (0.075-2.00 mm), gravel (> 2mm) and native sediments from each site. We incubated the sediments for three months and performed tracer experiments in the laboratory under identical flow conditions, seeking to normalize the physical processes along the river continuum. We added a short-term pulse injection of NO3, resazurin and NaCl to each column and determined metabolism and NO3 processing using the Tracer Additions for Spiraling Curve Characterization method (TASCC). Our methods allowed us to study how changes in bacterial communities and sediment composition along the river continuum define nutrient processing.

  16. Understanding how replication processes can maintain systems away from equilibrium using Algorithmic Information Theory.

    Science.gov (United States)

    Devine, Sean D

    2016-02-01

    Replication can be envisaged as a computational process that is able to generate and maintain order far-from-equilibrium. Replication processes, can self-regulate, as the drive to replicate can counter degradation processes that impact on a system. The capability of replicated structures to access high quality energy and eject disorder allows Landauer's principle, in conjunction with Algorithmic Information Theory, to quantify the entropy requirements to maintain a system far-from-equilibrium. Using Landauer's principle, where destabilising processes, operating under the second law of thermodynamics, change the information content or the algorithmic entropy of a system by ΔH bits, replication processes can access order, eject disorder, and counter the change without outside interventions. Both diversity in replicated structures, and the coupling of different replicated systems, increase the ability of the system (or systems) to self-regulate in a changing environment as adaptation processes select those structures that use resources more efficiently. At the level of the structure, as selection processes minimise the information loss, the irreversibility is minimised. While each structure that emerges can be said to be more entropically efficient, as such replicating structures proliferate, the dissipation of the system as a whole is higher than would be the case for inert or simpler structures. While a detailed application to most real systems would be difficult, the approach may well be useful in understanding incremental changes to real systems and provide broad descriptions of system behaviour. Copyright © 2016 The Author. Published by Elsevier Ireland Ltd.. All rights reserved.

  17. Process and system to control manganese and cobalt isotopes deposits from the cooling fluid of a reactor

    International Nuclear Information System (INIS)

    Brehm, W.F.; McGuire, J.C.

    1978-01-01

    Process for controlling the deposition of manganese-54, cobalt-58 and cobalt-60 radionuclides on component surfaces, as from a liquid flow containing these nuclides and entering into contact with the surface of these components. It is characterised by the positioning of a getter forming substance in the liquid flow to collect these radionuclides on the getter forming substance which contains at least 73% nickel by weight [fr

  18. Mangrove forests submitted to depositional processes and salinity variation investigated using satellite images and vegetation structure surveys

    OpenAIRE

    Cunha-Lignon, M.; Kampel, M.; Menghini, R.P.; Schaeffer-Novelli, Y.; Cintrón, G.; Dahdouh-Guebas, F.

    2011-01-01

    The current paper examines the growth and spatio-temporal variation of mangrove forests in response to depositional processes and different salinity conditions. Data from mangrove vegetation structure collected at permanent plots and satellite images were used. In the northern sector important environmental changes occurred due to an artificial channel producing modifications in salinity. The southern sector is considered the best conserved mangrove area along the coast of São Paulo State, Br...

  19. Phase transitions and structural formation of PEG-PCL-PEG copolymer in the processes of fused deposition 3D printing

    Science.gov (United States)

    Dunaev, A.; Mariyanac, A.; Mironov, A.; Mironova, O.; Popov, V.; Syachina, M.

    2018-04-01

    In present work the analysis of thermal field distribution and thermal analysis were used to study phase and structural transformations in the block copolymer of polycaprolactone and polyethylene glycol in the process of scaffolds fabrication for tissue engineering using fused deposition modeling. It was shown that the intact polymer has a noticeable thermal history and formed degree of crystallinity which is close to its equilibrium value, while the microstructure of the polymer stays unchanged.

  20. Using process monitor wafers to understand directed self-assembly defects

    Science.gov (United States)

    Cao, Yi; Her, YoungJun; Delgadillo, Paulina R.; Vandenbroeck, Nadia; Gronheid, Roel; Chan, Boon Teik; Hashimoto, Yukio; Romo, Ainhoa; Somervell, Mark; Nafus, Kathleen; Nealey, Paul F.

    2013-03-01

    As directed self-assembly (DSA) has gained momentum over the past few years, questions about its application to high volume manufacturing have arisen. One of the major concerns is about the fundamental limits of defectivity that can be attained with the technology. If DSA applications demonstrate defectivity that rivals of traditional lithographic technologies, the pathway to the cost benefits of the technology creates a very compelling case for its large scale implementation. To address this critical question, our team at IMEC has established a process monitor flow to track the defectivity behaviors of an exemplary chemo-epitaxy application for printing line/space patterns. Through establishing this baseline, we have been able to understand both traditional lithographic defect sources in new materials as well as new classes of assembly defects associated with DSA technology. Moreover, we have explored new materials and processing to lower the level of the defectivity baseline. The robustness of the material sets and process is investigated as well. In this paper, we will report the understandings learned from the IMEC DSA process monitor flow.

  1. On improved understanding of plasma-chemical processes in complex low-temperature plasmas

    Science.gov (United States)

    Röpcke, Jürgen; Loffhagen, Detlef; von Wahl, Eric; Nave, Andy S. C.; Hamann, Stephan; van Helden, Jean-Piere H.; Lang, Norbert; Kersten, Holger

    2018-05-01

    Over the last years, chemical sensing using optical emission spectroscopy (OES) in the visible spectral range has been combined with methods of mid infrared laser absorption spectroscopy (MIR-LAS) in the molecular fingerprint region from 3 to 20 μm, which contains strong rotational-vibrational absorption bands of a large variety of gaseous species. This optical approach established powerful in situ diagnostic tools to study plasma-chemical processes of complex low-temperature plasmas. The methods of MIR-LAS enable to detect stable and transient molecular species in ground and excited states and to measure the concentrations and temperatures of reactive species in plasmas. Since kinetic processes are inherent to discharges ignited in molecular gases, high time resolution on sub-second timescales is frequently desired for fundamental studies as well as for process monitoring in applied research and industry. In addition to high sensitivity and good temporal resolution, the capacity for broad spectral coverage enabling multicomponent detection is further expanding the use of OES and MIR-LAS techniques. Based on selected examples, this paper reports on recent achievements in the understanding of complex low-temperature plasmas. Recently, a link with chemical modeling of the plasma has been provided, which is the ultimate objective for a better understanding of the chemical and reaction kinetic processes occurring in the plasma. Contribution to the Topical Issue "Fundamentals of Complex Plasmas", edited by Jürgen Meichsner, Michael Bonitz, Holger Fehske, Alexander Piel.

  2. Big-data reflection high energy electron diffraction analysis for understanding epitaxial film growth processes.

    Science.gov (United States)

    Vasudevan, Rama K; Tselev, Alexander; Baddorf, Arthur P; Kalinin, Sergei V

    2014-10-28

    Reflection high energy electron diffraction (RHEED) has by now become a standard tool for in situ monitoring of film growth by pulsed laser deposition and molecular beam epitaxy. Yet despite the widespread adoption and wealth of information in RHEED images, most applications are limited to observing intensity oscillations of the specular spot, and much additional information on growth is discarded. With ease of data acquisition and increased computation speeds, statistical methods to rapidly mine the data set are now feasible. Here, we develop such an approach to the analysis of the fundamental growth processes through multivariate statistical analysis of a RHEED image sequence. This approach is illustrated for growth of La(x)Ca(1-x)MnO(3) films grown on etched (001) SrTiO(3) substrates, but is universal. The multivariate methods including principal component analysis and k-means clustering provide insight into the relevant behaviors, the timing and nature of a disordered to ordered growth change, and highlight statistically significant patterns. Fourier analysis yields the harmonic components of the signal and allows separation of the relevant components and baselines, isolating the asymmetric nature of the step density function and the transmission spots from the imperfect layer-by-layer (LBL) growth. These studies show the promise of big data approaches to obtaining more insight into film properties during and after epitaxial film growth. Furthermore, these studies open the pathway to use forward prediction methods to potentially allow significantly more control over growth process and hence final film quality.

  3. Preparation of iron-deposited graphite surface for application as cathode material during electrochemical vat-dyeing process

    International Nuclear Information System (INIS)

    Anbu Kulandainathan, M.; Kiruthika, K.; Christopher, G.; Babu, K. Firoz; Muthukumaran, A.; Noel, M.

    2008-01-01

    Iron-deposited graphite surfaces were prepared, characterized and employed as cathode materials for electrochemical vat-dyeing process containing very low concentration of sodium dithionite. The electrodeposition, in presence of ammonium thiocyanate and gelatin or animal glue as binding additives, were found to give finer iron deposits for improved electrochemical dyeing application. The electrodeposits were characterized using scanning electron microscopy, electron-dispersive X-ray spectroscopy and X-ray diffraction methods, before and after electrochemical dyeing process. The electrochemical activity of the iron-deposited graphite electrodes always stored in water seems to depend on the surface-bound Fe 3+ /Fe 2+ redox species. Vat dyes like C.I. Vat Violet 1, C.I. Vat Green 1 and C.I. Vat Blue 4 could be efficiently dyed employing these above electrode materials. The colour intensity and washing fastness of the dyed fabrics were found to be equal with conventionally dyed fabrics. The electrodes could also be reused for the dyeing process

  4. Modeling and simulation of the deposition/relaxation processes of polycrystalline diatomic structures of metallic nitride films

    Science.gov (United States)

    García, M. F.; Restrepo-Parra, E.; Riaño-Rojas, J. C.

    2015-05-01

    This work develops a model that mimics the growth of diatomic, polycrystalline thin films by artificially splitting the growth into deposition and relaxation processes including two stages: (1) a grain-based stochastic method (grains orientation randomly chosen) is considered and by means of the Kinetic Monte Carlo method employing a non-standard version, known as Constant Time Stepping, the deposition is simulated. The adsorption of adatoms is accepted or rejected depending on the neighborhood conditions; furthermore, the desorption process is not included in the simulation and (2) the Monte Carlo method combined with the metropolis algorithm is used to simulate the diffusion. The model was developed by accounting for parameters that determine the morphology of the film, such as the growth temperature, the interacting atomic species, the binding energy and the material crystal structure. The modeled samples exhibited an FCC structure with grain formation with orientations in the family planes of , and . The grain size and film roughness were analyzed. By construction, the grain size decreased, and the roughness increased, as the growth temperature increased. Although, during the growth process of real materials, the deposition and relaxation occurs simultaneously, this method may perhaps be valid to build realistic polycrystalline samples.

  5. A unique laboratory test rig reduces the need for offshore tests to combat calcium naphthenate deposition in oilfield process equipment.

    Energy Technology Data Exchange (ETDEWEB)

    Mediaas, Heidi; Grande, Knut; Hustad, Britt-Marie; Hoevik, Kim Reidar; Kummernes, Hege; Nergaard, Bjoern; Vindstad, Jens Emil

    2006-03-15

    Producing and refining high-TAN crude oils introduces a number of challenges, among which calcium naphthenate deposition in process facilities is the most serious production issue. Until recently, the only option for studying chemicals and process parameters in order to prevent naphthenate deposition has been field tests. Statoil has now developed a small scale pilot plant where these experiments can be performed in the laboratory at Statoil's Research and Technology Center in Trondheim, Norway. The results from the pilot plant are in full agreement with the extensive naphthenate experience obtained from almost 9 years operation of the Heidrun oilfield. The design and operational procedures for this test facility are based on the recent discovery by Statoil and ConocoPhillips of the ARN acid. The ARN acid is a prerequisite for calcium naphthenate deposition. The new continuous flow pilot plant, the Naphthenate Rig, is used to develop new environmental friendly naphthenate inhibitors and to optimize process operating conditions. Since it operates on real crudes the need for field tests in qualifying new naphthenate inhibitors is reduced. To the best of our knowledge, the rig is the first of its kind in the world. (Author)

  6. Fluorine and boron co-doped diamond-like carbon films deposited by pulsed glow discharge plasma immersion ion processing

    CERN Document Server

    He, X M; Peters, A M; Taylor, B; Nastasi, M

    2002-01-01

    Fluorine (F) and boron (B) co-doped diamond-like carbon (FB-DLC) films were prepared on different substrates by the plasma immersion ion processing (PIIP) technique. A pulse glow discharge plasma was used for the PIIP deposition and was produced at a pressure of 1.33 Pa from acetylene (C sub 2 H sub 2), diborane (B sub 2 H sub 6), and hexafluoroethane (C sub 2 F sub 6) gas. Films of FB-DLC were deposited with different chemical compositions by varying the flow ratios of the C sub 2 H sub 2 , B sub 2 H sub 6 , and C sub 2 F sub 6 source gases. The incorporation of B sub 2 H sub 6 and C sub 2 F sub 6 into PIIP deposited DLC resulted in the formation of F-C and B-C hybridized bonding structures. The levels of the F and B concentrations effected the chemical bonding and the physical properties as was evident from the changes observed in density, hardness, stress, friction coefficient, and contact angle of water on films. Compared to B-doped or F-doped DLC films, the F and B co-doping of DLC during PIIP deposition...

  7. Understanding the implementation of complex interventions in health care: the normalization process model

    Directory of Open Access Journals (Sweden)

    Rogers Anne

    2007-09-01

    Full Text Available Abstract Background The Normalization Process Model is a theoretical model that assists in explaining the processes by which complex interventions become routinely embedded in health care practice. It offers a framework for process evaluation and also for comparative studies of complex interventions. It focuses on the factors that promote or inhibit the routine embedding of complex interventions in health care practice. Methods A formal theory structure is used to define the model, and its internal causal relations and mechanisms. The model is broken down to show that it is consistent and adequate in generating accurate description, systematic explanation, and the production of rational knowledge claims about the workability and integration of complex interventions. Results The model explains the normalization of complex interventions by reference to four factors demonstrated to promote or inhibit the operationalization and embedding of complex interventions (interactional workability, relational integration, skill-set workability, and contextual integration. Conclusion The model is consistent and adequate. Repeated calls for theoretically sound process evaluations in randomized controlled trials of complex interventions, and policy-makers who call for a proper understanding of implementation processes, emphasize the value of conceptual tools like the Normalization Process Model.

  8. Novel Evaporation Process for Deposition of Kesterite Thin Films Synthesized by Solvothermal Method

    Directory of Open Access Journals (Sweden)

    J. A. Estrada-Ayub

    2017-01-01

    Full Text Available Kesterite, a quaternary compound of Cu2ZnSnS4, is a promising option as a material absorber to reduce the cost of photovoltaic solar cells. The solvothermal method is a way to synthesize nanoparticles of this material. In this work, once synthesized, particles were deposited on a substrate through evaporation, and their morphological, structural, and optical properties were studied. Results show that changes of precursor ratios during solvothermal synthesis result in a modification of particle morphology but not on its size. The deposition of already synthesized kesterite through evaporation preserves kesterite structure and permits the formation of a homogenous film on a substrate. Optical reflectance and transmittance measurements allowed estimating the band-gap energy between 1.41 and 1.46 eV for representative samples, which is near the optimum for the absorber material.

  9. Pulsed-laser-deposited YBCO thin films using modified MTG processed targets

    CERN Document Server

    Kim, C H; Kim, I T; Hahn, T S

    1999-01-01

    YBCO thin films were deposited by pulsed laser deposition from targets fabricated using the modified melt-textured growth (MTG) method and the solid-state sintering (SSS) method. All of the films showed c-axis orientations, but the films from the MTG targets had better crystallinity than those from the SSS targets. As the substrate temperature was increased, T sub c and J sub c of the films increased. The films from the MTG targets showed better superconducting properties than those from the SSS targets. From the composition analysis of the targets, the Y-richer vapor species arriving at the substrate from the MTG targets are thought to form a thermodynamically more stable YBCO phase with less cation disorder.

  10. The effect of biotechnology education on Australian high school students' understandings and attitudes about biotechnology processes

    Science.gov (United States)

    Dawson, Vaille; Soames, Christina

    2006-11-01

    Our education system aims to equip young people with the knowledge, problem-solving skills and values to cope with an increasingly technological society. The aim of this study was to determine the effect of biotechnology education on adolescents’ understanding and attitudes about processes associated with biotechnology. Data were drawn from teacher and student interviews and surveys in the context of innovative Year 10 biotechnology courses conducted in three Western Australian high schools. The results indicate that after completing a biotechnology course students’ understanding increased but their attitudes remained constant with the exception of their views about human uses of gene technology. The findings of this study have ramifications for the design and implementation of biotechnology education courses in high schools.

  11. The problem of “culture” in the process of intercultural understanding

    Directory of Open Access Journals (Sweden)

    Andreana Marchi

    2016-01-01

    Full Text Available http://dx.doi.org/10.5007/2175-8026.2016v69n1p251 The problem of “culture” in the process of intercultural understanding is one of the most discussed issues among scholars today. Anthropologists, linguists, literary critics, and philosophers, just to name a few, study this issue in a problem-based and research format. Culture and cultural understanding are hereby presented by demonstrating studies and observations of two cultural anthropologists, R. H. Robbins and Clifford Geertz, a literary critic, Lionel Trilling, and C. S. Lewis, a famous writer of both fiction and non-fiction. My intention here is to answer the question: how to describe and analyze a culture that is so different from the perspective of our own? In this sense, language and discourse are also analyzed in this paper as part of culture and can indicate some of our own moral perspectives and judgments on others’ cultures.

  12. Assessing middle school students` understanding of science relationships and processes: Year 2 - instrument validation. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Schau, C.; Mattern, N.; Weber, R.; Minnick, K.

    1997-01-01

    Our overall purpose for this multi-year project was to develop an alternative assessment format measuring rural middle school students understanding of science concepts and processes and the interrelationships among them. This kind of understanding is called structural knowledge. We had 3 major interrelated goals: (1) Synthesize the existing literature and critically evaluate the actual and potential use of measures of structural knowledge in science education. (2) Develop a structural knowledge alternative assessment format. (3) Examine the validity of our structural knowledge format. We accomplished the first two goals during year 1. The structural knowledge assessment we identified and developed further was a select-and-fill-in concept map format. The goal for our year 2 work was to begin to validate this assessment approach. This final report summarizes our year 2 work.

  13. Electrophoretic Deposition as a New Bioactive Glass Coating Process for Orthodontic Stainless Steel

    OpenAIRE

    Kyotaro Kawaguchi; Masahiro Iijima; Kazuhiko Endo; Itaru Mizoguchi

    2017-01-01

    This study investigated the surface modification of orthodontic stainless steel using electrophoretic deposition (EPD) of bioactive glass (BG). The BG coatings were characterized by spectrophotometry, scanning electron microscopy with energy dispersive X-ray spectrometry, and X-ray diffraction. The frictional properties were investigated using a progressive load scratch test. The remineralization ability of the etched dental enamel was studied according to the time-dependent mechanical proper...

  14. Understanding the process of social network evolution: Online-offline integrated analysis of social tie formation.

    Science.gov (United States)

    Kwak, Doyeon; Kim, Wonjoon

    2017-01-01

    It is important to consider the interweaving nature of online and offline social networks when we examine social network evolution. However, it is difficult to find any research that examines the process of social tie formation from an integrated perspective. In our study, we quantitatively measure offline interactions and examine the corresponding evolution of online social network in order to understand the significance of interrelationship between online and offline social factors in generating social ties. We analyze the radio signal strength indicator sensor data from a series of social events to understand offline interactions among the participants and measure the structural attributes of their existing online Facebook social networks. By monitoring the changes in their online social networks before and after offline interactions in a series of social events, we verify that the ability to develop an offline interaction into an online friendship is tied to the number of social connections that participants previously had, while the presence of shared mutual friends between a pair of participants disrupts potential new connections within the pre-designed offline social events. Thus, while our integrative approach enables us to confirm the theory of preferential attachment in the process of network formation, the common neighbor theory is not supported. Our dual-dimensional network analysis allows us to observe the actual process of social network evolution rather than to make predictions based on the assumption of self-organizing networks.

  15. Understanding the process of social network evolution: Online-offline integrated analysis of social tie formation.

    Directory of Open Access Journals (Sweden)

    Doyeon Kwak

    Full Text Available It is important to consider the interweaving nature of online and offline social networks when we examine social network evolution. However, it is difficult to find any research that examines the process of social tie formation from an integrated perspective. In our study, we quantitatively measure offline interactions and examine the corresponding evolution of online social network in order to understand the significance of interrelationship between online and offline social factors in generating social ties. We analyze the radio signal strength indicator sensor data from a series of social events to understand offline interactions among the participants and measure the structural attributes of their existing online Facebook social networks. By monitoring the changes in their online social networks before and after offline interactions in a series of social events, we verify that the ability to develop an offline interaction into an online friendship is tied to the number of social connections that participants previously had, while the presence of shared mutual friends between a pair of participants disrupts potential new connections within the pre-designed offline social events. Thus, while our integrative approach enables us to confirm the theory of preferential attachment in the process of network formation, the common neighbor theory is not supported. Our dual-dimensional network analysis allows us to observe the actual process of social network evolution rather than to make predictions based on the assumption of self-organizing networks.

  16. Understanding the growth of micro and nano-crystalline AlN by thermal plasma process

    Science.gov (United States)

    Kanhe, Nilesh S.; Nawale, Ashok B.; Gawade, Rupesh L.; Puranik, Vedavati G.; Bhoraskar, Sudha V.; Das, Asoka K.; Mathe, Vikas L.

    2012-01-01

    We report the studies related to the growth of crystalline AlN in a DC thermal plasma reactor, operated by a transferred arc plasma torch. The reactor is capable of producing the nanoparticles of Al and AlN depending on the composition of the reacting gas. Al and AlN micro crystals are formed at the anode placed on the graphite and nano crystalline Al and AlN gets deposited on the inner surface of the plasma reactor. X-ray diffraction, Raman spectroscopy analysis, single crystal X-ray diffraction and TGA-DTA techniques are used to infer the purity of post process crystals as a hexagonal AlN. The average particle size using SEM was found to be around 30 μm. The morphology of nanoparticles of Al and AlN, nucleated by gas phase condensation in a homogeneous medium were studied by transmission electron microscopy analysis. The particle ranged in size between 15 and 80 nm in diameter. The possible growth mechanism of crystalline AlN at the anode has been explained on the basis of non-equilibrium processes in the core of the plasma and steep temperature gradient near its periphery. The gas phase species of AlN and various constituent were computed using Murphy code based on minimization of free energy. The process provides 50% yield of microcrystalline AlN and remaining of Al at anode and that of nanocrystalline h-AlN and c-Al collected from the walls of the chamber is about 33% and 67%, respectively.

  17. Paediatric nurses' understanding of the process and procedure of double-checking medications.

    Science.gov (United States)

    Dickinson, Annette; McCall, Elaine; Twomey, Bernadette; James, Natalie

    2010-03-01

    To understand paediatric nurses' understanding and practice regarding double-checking medication and identify facilitators and barriers to the process of independent double-checking (IDC). A system of double-checking medications has been proposed as a way of minimising medication error particularly in situations involving high-risk medications, complex processes such as calculating doses, or high-risk patient populations such as infants and children. While recommendations have been made in support of IDC in paediatric settings little is known about nursing practice and the facilitators and barriers to this process. A descriptive qualitative design was used. Data were collected via three focus group interviews. Six to seven paediatric nurses participated in homogenous groups based on level of practice. Data were analysed using thematic analysis. This study demonstrates that, while IDC is accepted and promoted as best practice in a paediatric setting, there is a lack of clarity as to what this means. This study supports other studies in relation to the influence of workload, distraction and environmental factors on the administration process but highlights the need for more research in relation to the impact of the power dynamic between junior and senior nurses. The issue of automaticity has been unexplored in relation to nursing practice but this study indicates that this may have an important influence on how care is delivered to patients. While the focus of this study was in the paediatric setting, the findings have relevance to other settings and population groups. The adoption of IDC in health care settings must have in place: policy and guidelines that clearly define the process of checking, educational support, an environment that supports peer critique and review, well-designed medication areas and accessible resources to support drug administration.

  18. Exploring potentials of sense-making theory for understanding social processes in public hearing

    DEFF Research Database (Denmark)

    Lyhne, Ivar

    authorities and the public in such planning often characterised by conflict. A sense-making framework is developed based on Karl Weick's theory to investigate how participants at the meeting change their understanding aspects like other actors' opinions and the infrastructure project. Through interviews...... and observations it is shown that participants' senses do not change except from a few aspects. The participants at the meeting thus seem stuck in their positions without interest in being open for other interpretations or arguments. The investigation leads to considerations about the benefit and role...... of such a public meeting and the importance of trust and openness in the social processes in a public hearing....

  19. Nature of the pulsed laser process for the deposition of high T/sub c/ superconducting thin films

    International Nuclear Information System (INIS)

    Venkatesan, T.; Wu, X.D.; Inam, A.

    1988-01-01

    The pulsed laser thin-film deposition process can enable preparation of thin films of complex composition with good control over the film stoichiometry. The film compositions are similar to that of the target pellet and as a consequence this technique appears to be an ideal method for preparing high T/sub c/ thin films on a variety of substrates.The factors which contribute to this beneficial phenomenon have been explored by a laser ionization mass spectrometry (LIMS) and a post ablation ionization (PAI) neutral velocity analysis technique in order to determine the mass and velocities of the laser ejected material. In addition, x-ray absorption measurements on films deposited onto substrates at room temperature were performed in order to identify the presence of short-range crystalline order in the films. Both of these studies rule out the ejection of stoichiometric clusters of material from the pellet during the laser ablation/deposition process. Instead, binary and ternary suboxides are emitted from the target pellet. These suboxides most likely have unit sticking coefficient to the substrate which could contribute to the preservation of the film stoichiometry. The velocity distribution of several neutral species (e.g., BaO) indicates that particles have energies of several eV. Thus the effective temperatures of the emitted species are ∼15 x 10 3 K, and these energetic particles may facilitate growth of the crystalline films at low substrate temperatures

  20. Pharmaceutical quality by design: product and process development, understanding, and control.

    Science.gov (United States)

    Yu, Lawrence X

    2008-04-01

    The purpose of this paper is to discuss the pharmaceutical Quality by Design (QbD) and describe how it can be used to ensure pharmaceutical quality. The QbD was described and some of its elements identified. Process parameters and quality attributes were identified for each unit operation during manufacture of solid oral dosage forms. The use of QbD was contrasted with the evaluation of product quality by testing alone. The QbD is a systemic approach to pharmaceutical development. It means designing and developing formulations and manufacturing processes to ensure predefined product quality. Some of the QbD elements include: Defining target product quality profile; Designing product and manufacturing processes; Identifying critical quality attributes, process parameters, and sources of variability; Controlling manufacturing processes to produce consistent quality over time. Using QbD, pharmaceutical quality is assured by understanding and controlling formulation and manufacturing variables. Product testing confirms the product quality. Implementation of QbD will enable transformation of the chemistry, manufacturing, and controls (CMC) review of abbreviated new drug applications (ANDAs) into a science-based pharmaceutical quality assessment.

  1. Electron beam induced deposition of silacyclohexane and dichlorosilacyclohexane : The role of dissociative ionization and dissociative electron attachment in the deposition process

    NARCIS (Netherlands)

    Ragesh Kumar, T. P.; Hari, S.; Damodaran, Krishna K.; Ingólfsson, Oddur; Hagen, C.W.

    2017-01-01

    We present first experiments on electron beam induced deposition of silacyclohexane (SCH) and dichlorosilacyclohexane (DCSCH) under a focused high-energy electron beam (FEBID). We compare the deposition dynamics observed when growing pillars of high aspect ratio from these compounds and we

  2. An adaptation of the Citrosolv process to remove different types of deposits in boilers of a thermo-electric power plant

    International Nuclear Information System (INIS)

    Ferreira, V.C.

    1985-01-01

    During the inspection of a power station boiler was find out a high amount of scale/deposits on the tubes surface (> 100 mg/cm 2 ). The scale/deposits constituents determined in chemical analysis, X-ray fluorescence and X-ray diffraction were iron, copper, calcium, magnesium, phosphorus and silicon. A chemical cleaning based on a small change of Citrosolv process, was used to remove those scale/deposits with sucess. (Author) [pt

  3. Towards Understanding Soil Forming in Santa Clotilde Critical Zone Observatory: Modelling Soil Mixing Processes in a Hillslope using Luminescence Techniques

    Science.gov (United States)

    Sanchez, A. R.; Laguna, A.; Reimann, T.; Giráldez, J. V.; Peña, A.; Wallinga, J.; Vanwalleghem, T.

    2017-12-01

    Different geomorphological processes such as bioturbation and erosion-deposition intervene in soil formation and landscape evolution. The latter processes produce the alteration and degradation of the materials that compose the rocks. The degree to which the bedrock is weathered is estimated through the fraction of the bedrock which is mixing in the soil either vertically or laterally. This study presents an analytical solution for the diffusion-advection equation to quantify bioturbation and erosion-depositions rates in profiles along a catena. The model is calibrated with age-depth data obtained from profiles using the luminescence dating based on single grain Infrared Stimulated Luminescence (IRSL). Luminescence techniques contribute to a direct measurement of the bioturbation and erosion-deposition processes. Single-grain IRSL techniques is applied to feldspar minerals of fifteen samples which were collected from four soil profiles at different depths along a catena in Santa Clotilde Critical Zone Observatory, Cordoba province, SE Spain. A sensitivity analysis is studied to know the importance of the parameters in the analytical model. An uncertainty analysis is carried out to stablish the better fit of the parameters to the measured age-depth data. The results indicate a diffusion constant at 20 cm in depth of 47 (mm2/year) in the hill-base profile and 4.8 (mm2/year) in the hilltop profile. The model has high uncertainty in the estimation of erosion and deposition rates. This study reveals the potential of luminescence single-grain techniques to quantify pedoturbation processes.

  4. Understanding Coupled Earth-Surface Processes through Experiments and Models (Invited)

    Science.gov (United States)

    Overeem, I.; Kim, W.

    2013-12-01

    Traditionally, both numerical models and experiments have been purposefully designed to ';isolate' singular components or certain processes of a larger mountain to deep-ocean interconnected source-to-sink (S2S) transport system. Controlling factors driven by processes outside of the domain of immediate interest were treated and simplified as input or as boundary conditions. Increasingly, earth surface processes scientists appreciate feedbacks and explore these feedbacks with more dynamically coupled approaches to their experiments and models. Here, we discuss key concepts and recent advances made in coupled modeling and experimental setups. In addition, we emphasize challenges and new frontiers to coupled experiments. Experiments have highlighted the important role of self-organization; river and delta systems do not always need to be forced by external processes to change or develop characteristic morphologies. Similarly modeling f.e. has shown that intricate networks in tidal deltas are stable because of the interplay between river avulsions and the tidal current scouring with both processes being important to develop and maintain the dentritic networks. Both models and experiment have demonstrated that seemingly stable systems can be perturbed slightly and show dramatic responses. Source-to-sink models were developed for both the Fly River System in Papua New Guinea and the Waipaoa River in New Zealand. These models pointed to the importance of upstream-downstream effects and enforced our view of the S2S system as a signal transfer and dampening conveyor belt. Coupled modeling showed that deforestation had extreme effects on sediment fluxes draining from the catchment of the Waipaoa River in New Zealand, and that this increase in sediment production rapidly shifted the locus of offshore deposition. The challenge in designing coupled models and experiments is both technological as well as intellectual. Our community advances to make numerical model coupling more

  5. Improving the conductance of ZnO thin film doping with Ti by using a cathodic vacuum arc deposition process

    International Nuclear Information System (INIS)

    Wu, Chun-Sen; Lin, Bor-Tsuen; Jean, Ming-Der

    2011-01-01

    The Ti-doped ZnO films compared to un-doped ZnO films were deposited onto Corning XG glass substrates by using a cathodic vacuum arc deposition process in a mixture of oxygen and argon gases. The structural, electrical and optical properties of un-doped and Ti-doped ZnO films have been investigated. When the Ti target power is about 750 W, the incorporation of titanium atoms into zinc oxide films is obviously effective. Additionally, the resistivity of un-doped ZnO films is high and reduces to a value of 3.48 x 10 -3 Ω-cm when Ti is incorporated. The Ti doped in the ZnO films gave rise to the improvement of the conductivity of the films obviously. The Ti-doped ZnO films have > 85% transmittance in a range of 400-700 nm.

  6. A novel Ag catalyzation process using swelling impregnation method for electroless Ni deposition on Kevlar® fiber

    Science.gov (United States)

    Pang, Hongwei; Bai, Ruicheng; Shao, Qinsi; Gao, Yufang; Li, Aijun; Tang, Zhiyong

    2015-12-01

    A novel Ag catalyzation process using swelling impregnation pretreatment method was developed for electroless nickel (EN) deposition on Kevlar fiber. Firstly, the fiber was immersed into an aqueous dimethylsulfoxide (DMSO) solution of silver nitrate to impart silver nitrate into the inner part of the fiber near the surface. Subsequently silver nitrate was reduced to metal silver nanoparticles on the fiber surface by treatment with aqueous solution of sodium borohydride. After electroless plating, a dense and homogeneous nickel coating was obtained on the fiber surface. The silver nanoparticles formed at the fiber surface functioned as a catalyst for electroless deposition as well as an anchor for the plated layer. The study also revealed that the incorporation of surfactant sodium dodecyl sulfate (SDS) in electroless nickel plating bath can enhance the adhesion strength of EN layer with the fiber surface and minimize the surface roughness of the EN coating. The Ni plated Kevlar fiber possessed excellent corrosion resistance and high tensile strength.

  7. Understanding cognitive processes behind acceptance or refusal of phase I trials.

    Science.gov (United States)

    Pravettoni, Gabriella; Mazzocco, Ketti; Gorini, Alessandra; Curigliano, Giuseppe

    2016-04-01

    Participation in phase I trials gives patients the chance to obtain control over their disease by trying an experimental therapy. The patients' vulnerability, the informed consent process aiming at understanding the purpose and potential benefits of the phase I trial, and the complexity of the studies may impact the patient's final decision. Emotionally difficult health conditions may induce patients to succumb to cognitive biases, allocating attention only on a part of the provided information. Filling the gap in patients' information process can foster the implementation of strategies to help physicians tailor clinical trials' communication providing personalized support and tailored medical information around patients' need, so avoiding cognitive biases in patients and improving informed shared decision quality. The aim of the present review article focuses on the analysis of cognitive and psychological factors that affect patients' decision to participate or not to early phase clinical trials. Copyright © 2016. Published by Elsevier Ireland Ltd.

  8. Powder stickiness in milk drying: uncertainty and sensitivity analysis for process understanding

    DEFF Research Database (Denmark)

    Ferrari, Adrián; Gutiérrez, Soledad; Sin, Gürkan

    2017-01-01

    A powder stickiness model based in the glass transition temperature (Gordon – Taylor equations) was built for a production scale milk drying process (including a spray chamber, and internal/external fluid beds). To help process understanding, the model was subjected to sensitivity analysis (SA...... for nonlinear error propagation was selected as the main UA approach. SA results show an important local sensitivity on the spray dryer, but at the end of the internal fluid bed (critical point for stickiness) minor local sensitivities were observed. Feed concentrate moisture was found as the input with major...... global sensitivity on the glass transition temperature at the critical point, so it could represent a key variable for helping on stickiness control. UA results show the major model predictions uncertainty on the spray dryer, but it does not represent a stickiness issue since the product...

  9. Activity build-up on the circulation loops of boiling water reactors: Basics for modelling of transport and deposition processes

    International Nuclear Information System (INIS)

    Covelli, B.; Alder, H.P.

    1988-03-01

    In the past 20 years the radiation field of nuclear power plant loops outside the core zone was the object of investigations in many countries. In this context test loops were built and basic research done. At our Institute PSI the installation of a LWR-contamination loop is planned for this year. This experimental loop has the purpose to investigate the complex phenomena of activity deposition from the primary fluid of reactor plants and to formulate analytical models. From the literature the following conclusions can be drawn: The principal correlations of the activity build-up outside the core are known. The plant specific single phenomena as corrosion, crud-transport, activation and deposit of cobalt in the oxide layer are complex and only partially understood. The operational experience of particular plants with low contaminated loops (BWR-recirculation loops) show that in principle the problem is manageable. The reduction of the activity build-up in older plants necessitates a combination of measures to modify the crud balance in the primary circuit. In parallel to the experimental work several simulation models in the form of computer programs were developed. These models have the common feature that they are based on mass balances, in which the exchange of materials and the sedimentation processes are described by global empirical transport coefficients. These models yield satisfactory results and allow parameter studies; the application however is restricted to the particular installation. All programs lack models that describe the thermodynamic and hydrodynamic mechanisms on the surface of deposition layers. Analytical investigations on fouling of process equipment led to models that are also applicable to the activity build-up in reactor loops. Therefore it seems appropriate to combine the nuclear simulation models with the fundamental equations for deposition. 10 refs., 18 figs., 3 tabs

  10. Understanding Fundamental Material Degradation Processes in High Temperature Aggressive Chemomechanical Environments

    International Nuclear Information System (INIS)

    2014-01-01

    The objective of this project is to develop a fundamental understanding of the mechanisms that limit materials durability for very high-temperature applications. Current design limitations are based on material strength and corrosion resistance. This project will characterize the interactions of high-temperature creep, fatigue, and environmental attack in structural metallic alloys of interest for the very high-temperature gas-cooled reactor (VHTR) or Next Generation Nuclear Plant (NGNP) and for the associated thermo-chemical processing systems for hydrogen generation. Each of these degradation processes presents a major materials design challenge on its own, but in combination, they can act synergistically to rapidly degrade materials and limit component lives. This research and development effort will provide experimental results to characterize creep-fatigue-environment interactions and develop predictive models to define operation limits for high-temperature structural material applications. Researchers will study individually and in combination creep-fatigue-environmental attack processes in Alloys 617, 230, and 800H, as well as in an advanced Ni-Cr oxide dispersion strengthened steel (ODS) system. For comparison, the study will also examine basic degradation processes in nichrome (Ni-20Cr), which is a basis for most high-temperature structural materials, as well as many of the superalloys. These materials are selected to represent primary candidate alloys, one advanced developmental alloy that may have superior high-temperature durability, and one model system on which basic performance and modeling efforts can be based. The research program is presented in four parts, which all complement each other. The first three are primarily experimental in nature, and the last will tie the work together in a coordinated modeling effort. The sections are (1) dynamic creep-fatigue-environment process, (2) subcritical crack processes, (3) dynamic corrosion crack

  11. Understanding Fundamental Material Degradation Processes in High Temperature Aggressive Chemomechanical Environments

    Energy Technology Data Exchange (ETDEWEB)

    Stubbins, James; Gewirth, Andrew; Sehitoglu, Huseyin; Sofronis, Petros; Robertson, Ian

    2014-01-16

    The objective of this project is to develop a fundamental understanding of the mechanisms that limit materials durability for very high-temperature applications. Current design limitations are based on material strength and corrosion resistance. This project will characterize the interactions of high-temperature creep, fatigue, and environmental attack in structural metallic alloys of interest for the very high-temperature gas-cooled reactor (VHTR) or Next–Generation Nuclear Plant (NGNP) and for the associated thermo-chemical processing systems for hydrogen generation. Each of these degradation processes presents a major materials design challenge on its own, but in combination, they can act synergistically to rapidly degrade materials and limit component lives. This research and development effort will provide experimental results to characterize creep-fatigue-environment interactions and develop predictive models to define operation limits for high-temperature structural material applications. Researchers will study individually and in combination creep-fatigue-environmental attack processes in Alloys 617, 230, and 800H, as well as in an advanced Ni-Cr oxide dispersion strengthened steel (ODS) system. For comparison, the study will also examine basic degradation processes in nichrome (Ni-20Cr), which is a basis for most high-temperature structural materials, as well as many of the superalloys. These materials are selected to represent primary candidate alloys, one advanced developmental alloy that may have superior high-temperature durability, and one model system on which basic performance and modeling efforts can be based. The research program is presented in four parts, which all complement each other. The first three are primarily experimental in nature, and the last will tie the work together in a coordinated modeling effort. The sections are (1) dynamic creep-fatigue-environment process, (2) subcritical crack processes, (3) dynamic corrosion – crack

  12. From Process Understanding Via Soil Functions to Sustainable Soil Management - A Systemic Approach

    Science.gov (United States)

    Wollschlaeger, U.; Bartke, S.; Bartkowski, B.; Daedlow, K.; Helming, K.; Kogel-Knabner, I.; Lang, B.; Rabot, E.; Russell, D.; Stößel, B.; Weller, U.; Wiesmeier, M.; Rabot, E.; Vogel, H. J.

    2017-12-01

    Fertile soils are central resources for the production of biomass and the provision of food and energy. A growing world population and latest climate targets lead to an increasing demand for both, food and bio-energy, which requires preserving and improving the long-term productivity of soils as a bio-economic resource. At the same time, other soil functions and ecosystem services need to be maintained: filter for clean water, carbon sequestration, provision and recycling of nutrients, and habitat for biological activity. All these soil functions result from the interaction of a multitude of physical, chemical and biological processes that are not yet sufficiently understood. In addition, we lack understanding about the interplay between the socio-economic system and the soil system and how soil functions benefit human wellbeing. Hence, a solid and integrated assessment of soil quality requires the consideration of the ensemble of soil functions and its relation to soil management to finally be able to develop site-specific options for sustainable soil management. We present an integrated modeling approach that investigates the influence of soil management on the ensemble of soil functions. It is based on the mechanistic relationships between soil functional attributes, each explained by a network of interacting processes as derived from scientific evidence. As the evidence base required for feeding the model is for the most part stored in the existing scientific literature, another central component of our work is to set up a public "knowledge-portal" providing the infrastructure for a community effort towards a comprehensive knowledge base on soil processes as a basis for model developments. The connection to the socio-economic system is established using the Drivers-Pressures-Impacts-States-Responses (DPSIR) framework where our improved understanding about soil ecosystem processes is linked to ecosystem services and resource efficiency via the soil functions.

  13. Toward understanding the thermodynamics of TALSPEAK process. Medium effects on actinide complexation

    International Nuclear Information System (INIS)

    Zalupski, Peter R.; Martin, Leigh R.; Nash, Ken; Nakamura, Yoshinobu; Yamamoto, Masahiko

    2009-01-01

    The ingenious combination of lactate and diethylenetriamine-N,N,N',N(double p rime),N(double p rime)-pentaacetic acid (DTPA) as an aqueous actinide-complexing medium forms the basis of the successful separation of americium and curium from lanthanides known as the TALSPEAK process. While numerous reports in the prior literature have focused on the optimization of this solvent extraction system, considerably less attention has been devoted to the understanding of the basic thermodynamic features of the complex fluids responsible for the separation. The available thermochemical information of both lactate and DTPA protonation and metal complexation reactions are representative of the behavior of these ions under idealized conditions. Our previous studies of medium effects on lactate protonation suggest that significant departures from the speciation predicted based on reported thermodynamic values should be expected in the TALSPEAK aqueous environment. Thermodynamic parameters describing the separation chemistry of this process thus require further examination at conditions significantly removed from conventional ideal systems commonly employed in fundamental solution chemistry. Such thermodynamic characterization is the key to predictive modelling of TALSPEAK. Improved understanding will, in principle, allow process technologists to more efficiently respond to off-normal conditions during large scale process operation. In this report, the results of calorimetric and potentiometric investigations of the effects of aqueous electrolytes on the thermodynamic parameters for lactate protonation and lactate complexation of americium and neodymium will be presented. Studies on the lactate protonation equilibrium will clearly illustrate distinct thermodynamic variations between strong electrolyte aqueous systems and buffered lactate environment.

  14. Atmospheric deposition and canopy exchange processes in alpine forest ecosystems (northern Italy)

    Energy Technology Data Exchange (ETDEWEB)

    Balestrini, R. [Water Research Institute, Brugherio (Italy); Tagliaferri, A. [Regional Forestry Board (Italy)

    2001-07-01

    Throughfall and bulk precipitation chemistry were studied for five years (June 1994-May 1999) at two high elevation forest sites (Val Gerola and Val Masino) which were known to differ in terms of tree health, as assessed by live crown condition. The ion concentration of bulk precipitation samples did not differ significantly between sites, except for Mg{sup 2+}, while the throughfall concentrations differed in the measured values of H{sup +}, N-NO{sub 3}{sup -}, Cl{sup -}, Na{sup +}, K{sup +}, DOC and weak organic acids. The results of the application of the canopy exchange model indicated a higher contribution from the dry deposition of N-NO{sub 3}{sup -}, N-NH{sub 4}{sup +} and H{sup +} at Val Gerola, where the damage symptoms were more evident. In addition, the canopy leaching of Ca{sup 2+}, K{sup +} and weak organic acids were 47%, 21% and 27% higher at Val Gerola than at Val Masino. Annual SO{sub 4}{sup 2-} deposition fluxes (21.3kg ha{sup -1}yr{sup -1} at Val Masino and 23.6kgha{sup -1}yr{sup -1} at Val Gerola) were similar to those reported for moderately polluted European and U.S. sites. Annual N loads were 13.6 and 13.1kgha{sup -1}yr{sup -1} in the bulk input, and 15.0 and 18.0kgha{sup -1}yr{sup -1} in throughfall inputs, at Val Masino and Val Gerola, respectively. The contribution of the organic fraction to the total N atmospheric deposition load is significant, constituting 17% of the bulk flux and 40% of the throughfall flux. Measured nitrogen loads exceed the critical nutrient loads by several kgNha{sup -1} at both stations. In particular the nitrogen throughfall load at Val Gerola was about 3 times higher than the critical values. (author)

  15. Model of depositing layer on cylindrical surface produced by induction-assisted laser cladding process

    Directory of Open Access Journals (Sweden)

    Kotlan Václav

    2017-12-01

    Full Text Available A model of hybrid cladding on a cylindrical surface is built and numerically solved. Heating of both substrate and the powder material to be deposited on its surface is realized by laser beam and preheating inductor. The task represents a hard-coupled electromagnetic-thermal problem with time-varying geometry. Two specific algorithms are developed to incorporate this effect into the model, driven by local distribution of temperature and its gradients. The algorithms are implemented into the COMSOL Multiphysics 5.2 code that is used for numerical computations of the task. The methodology is illustrated with a typical example whose results are discussed.

  16. Results of analyzing natural gas during the use of biochemical processes in a petroleum deposit

    Energy Technology Data Exchange (ETDEWEB)

    Yulbarisov, E M

    1972-01-01

    Laboratory and commercial scale experiments with a geobioreagent and the Arlanskii deposit petroleum gave a sharp increase in the content of heavier hydrocarbons, nitrogen, and carbon dioxide in the gas and an increase in the yield of gasoline fraction boiling below 122/sup 0/C. The commercial scale experiments were done in a stratum 1200 m deep during waterflood recovery at 200 kg/cm/sup 2/. A substantial increase in ethane and higher hydrocarbons in the gas and increased petroleum yield were observed, especially after each waterflood. The effect of water was explained by higher activity of the bacteria at a lower concentration of rock salts.

  17. Seafloor Eruptions Offer a Teachable Moment to Help SEAS Students Understand Important Geological and Ecological Processes

    Science.gov (United States)

    Goehring, L.; Williams, C. S.

    2006-12-01

    In education parlance, a teachable moment is an opportunity that arises when students are engaged and primed to learn, typically in response to some memorable event. Earthquakes, volcanic eruptions, even natural disasters, if meaningful to the student, often serve to catalyze intense learning. Recent eruptions at the East Pacific Rise offer a potential teachable moment for students and teachers involved with SEAS, a Ridge 2000 education outreach program. SEAS uses a combination of web-facilitated and teacher-directed activities to make the remote deep-sea environment and the process of science relevant and meaningful. SEAS is a web-based, inquiry-oriented education program for middle and high school students. It features the science associated with Ridge 2000 research. Since 2003, SEAS has focused on the integrated study site at the East Pacific Rise (EPR) to help students understand geological and ecological processes at mid-ocean ridges and hydrothermal vents. SEAS students study EPR bathymetry maps, images of lava formations, photomosaics of diffuse flow communities, succession in the Bio-Geo Transect, as well as current research conducted during spring cruises. In the Classroom to Sea Lab, students make direct comparisons between shallow-water mussels and vent mussels (from the EPR) to understand differences in feeding strategies. The recent eruptions and loss of seafloor fauna at this site offer the Ridge 2000 program the opportunity to help students better understand the ephemeral and episodic nature of ridge environments, as well as the realities and processes of science (particularly field science). In January 2007, the SEAS program will again sail with a Ridge 2000 research team, and will work with scientists to report findings through the SEAS website. The eruptions at the EPR covered much of the study site, and scientists' instruments and experiments, in fresh lava. We intend to highlight the recency and effect of the eruptions, using the students

  18. UNDERSTANDING AND PERCEPTION OF THE CHARACTER IMAGE BY PRIMARY SCHOOLCHILDREN IN THE PROCESS OF TEXT INTERPRETATION

    Directory of Open Access Journals (Sweden)

    Kateryna Hnatenko

    2017-07-01

    Full Text Available Modern literature research works practically assert that literature is a way of thinking in imagery, and the interpretation of art works is almost always the interpretation of imagery, in other words perfect reality. Psychologists confirm that educational process in primary school should be formed on the account of both present and potential abilities of the children. Literature is an important means of pupils’ development. Reading in grades 1 − 4 promotes the development of children’s positive moral and will-power qualitie. With its help children perceive the world, learn to understand and love beautiful things. The writer’s ideological content of a piece of literature can be revealed in images. The main objective of text interpretation in grades 1 − 4 is to promote pupils’ perception and comprehension. Nowadays the changes in educational sphere require more attention to the issue of literary perception. In 2011, primary school changed the training course of "Reading" into "Literary reading," which aims at the development of the following reader’s qualities: to be capable to independent reading,to perform different communicative and creative activities. However, the educational process observation showed the existence of problems in young learners’ perception and understanding of literary art, and especially the role of character and its images. Today, the methodology pays attention to the quality of the perception, its depth and awareness. The efficiency level of children’s literary work perception is set on the analysis of readers’ activity results. Difficulties in the determination of the literary work perception level lie in various interpretations, complexity of the perception process, necessity to reflect different sides and emotions of imagination and thinking. Many scientific works are devoted to the analysis of literary texts understanding, to the role of visual images and imagination in literary text understanding

  19. Making and Unmaking the Endangered in India (1880-Present: Understanding Animal-Criminal Processes

    Directory of Open Access Journals (Sweden)

    Varun Sharma

    2015-01-01

    Full Text Available The concerns of the present paper emerge from the single basic question of whether the available histories of the tiger are comprehensive enough to enable an understanding of how this nodular species comprises/contests the power dynamics of the present. Starting with this basic premise, this paper retells a series of events which go to clarify that a nuanced understanding of the manner in which a species serves certain political purposes is not possible by tracking the animal alone. A discourse on endangerment has beginnings in the body and being of species that are remarkably cut off from the tiger-the elephant, birds, and the rhino (and man if we might add-and develops with serious implications for power, resource appropriation, and criminality, over a period of time, before more directly recruiting the tiger itself. If we can refer to this as the intermittent making and unmaking of the endangered, it is by turning to the enunciations of Michel Foucault that we try to canvas a series of events that can be described as animal-criminal processes. The role of such processes in the construction of endangerment, the structuring of space, and shared ideas of man-animal relations is further discussed in this paper.

  20. Causal knowledge extraction by natural language processing in material science: a case study in chemical vapor deposition

    Directory of Open Access Journals (Sweden)

    Yuya Kajikawa

    2006-11-01

    Full Text Available Scientific publications written in natural language still play a central role as our knowledge source. However, due to the flood of publications, the literature survey process has become a highly time-consuming and tangled process, especially for novices of the discipline. Therefore, tools supporting the literature-survey process may help the individual scientist to explore new useful domains. Natural language processing (NLP is expected as one of the promising techniques to retrieve, abstract, and extract knowledge. In this contribution, NLP is firstly applied to the literature of chemical vapor deposition (CVD, which is a sub-discipline of materials science and is a complex and interdisciplinary field of research involving chemists, physicists, engineers, and materials scientists. Causal knowledge extraction from the literature is demonstrated using NLP.

  1. Hydrologic Connectivity for Understanding Watershed Processes: Brand-new Puzzle or Emerging Panacea?

    Science.gov (United States)

    Ali, G. A.; Roy, A. G.; Tetzlaff, D.; Soulsby, C.; McDonnell, J. J.

    2011-12-01

    As a way to develop a more holistic approach to watershed assessment and management, the concept of hydrologic connectivity (HC) is often put at the forefront. HC can be seen as the strength of the water-mediated linkages between discrete units of the landscape and as such, it facilitates our intuitive understanding of the mechanisms driving runoff initiation and cessation. Much of the excitement surrounding HC is attributable to its potential to enhance our ability to gain insights into multiple areas including process dynamics, numerical model building, the effects of human elements in our landscape conceptualization, and the development of simplified watershed management tools. However, before such potential can be fully demonstrated, many issues must be resolved with regards to the measure of HC. Here we provide examples highlighting how connectivity can be useful towards understanding water routing in river basins, ecohydrological systems coupling, and intermittent rainfall-runoff dynamics. First, the use of connectivity metrics to examine the relative influence of surface/subsurface topography and soil characteristics on runoff generation will be discussed. Second, the effectiveness of using geochemical tracers will be examined with respect to identifying non-point runoff sources and linking hillslope-to-channel connectivity with surface water-groundwater exchanges in the biologically sensitive hyporheic zone. Third, the identification of different hydrologic thresholds will be presented as a way to discriminate the establishment of connectivity across a range of contrasted catchments located in Canada, Scotland, the USA, and Sweden. These examples will show that current challenges with regards to HC revolve around the choice of an accurate methodological framework for an appropriate translation of experimental findings into effective watershed management approaches. Addressing these questions simultaneously will lead to the emergence of HC as a powerful tool

  2. Revisiting the Holy Grail: using plant functional traits to understand ecological processes.

    Science.gov (United States)

    Funk, Jennifer L; Larson, Julie E; Ames, Gregory M; Butterfield, Bradley J; Cavender-Bares, Jeannine; Firn, Jennifer; Laughlin, Daniel C; Sutton-Grier, Ariana E; Williams, Laura; Wright, Justin

    2017-05-01

    One of ecology's grand challenges is developing general rules to explain and predict highly complex systems. Understanding and predicting ecological processes from species' traits has been considered a 'Holy Grail' in ecology. Plant functional traits are increasingly being used to develop mechanistic models that can predict how ecological communities will respond to abiotic and biotic perturbations and how species will affect ecosystem function and services in a rapidly changing world; however, significant challenges remain. In this review, we highlight recent work and outstanding questions in three areas: (i) selecting relevant traits; (ii) describing intraspecific trait variation and incorporating this variation into models; and (iii) scaling trait data to community- and ecosystem-level processes. Over the past decade, there have been significant advances in the characterization of plant strategies based on traits and trait relationships, and the integration of traits into multivariate indices and models of community and ecosystem function. However, the utility of trait-based approaches in ecology will benefit from efforts that demonstrate how these traits and indices influence organismal, community, and ecosystem processes across vegetation types, which may be achieved through meta-analysis and enhancement of trait databases. Additionally, intraspecific trait variation and species interactions need to be incorporated into predictive models using tools such as Bayesian hierarchical modelling. Finally, existing models linking traits to community and ecosystem processes need to be empirically tested for their applicability to be realized. © 2016 Cambridge Philosophical Society.

  3. Silver deposition on titanium surface by electrochemical anodizing process reduces bacterial adhesion of Streptococcus sanguinis and Lactobacillus salivarius.

    Science.gov (United States)

    Godoy-Gallardo, Maria; Rodríguez-Hernández, Ana G; Delgado, Luis M; Manero, José M; Javier Gil, F; Rodríguez, Daniel

    2015-10-01

    The aim of this study was to determine the antibacterial properties of silver-doped titanium surfaces prepared with a novel electrochemical anodizing process. Titanium samples were anodized with a pulsed process in a solution of silver nitrate and sodium thiosulphate at room temperature with stirring. Samples were processed with different electrolyte concentrations and treatment cycles to improve silver deposition. Physicochemical properties were determined by X-ray photoelectron spectroscopy, contact angle measurements, white-light interferometry, and scanning electron microscopy. Cellular cytotoxicity in human fibroblasts was studied with lactate dehydrogenase assays. The in vitro effect of treated surfaces on two oral bacteria strains (Streptococcus sanguinis and Lactobacillus salivarius) was studied with viable bacterial adhesion measurements and growth curve assays. Nonparametric statistical Kruskal-Wallis and Mann-Whitney U-tests were used for multiple and paired comparisons, respectively. Post hoc Spearman's correlation tests were calculated to check the dependence between bacteria adhesion and surface properties. X-ray photoelectron spectroscopy results confirmed the presence of silver on treated samples and showed that treatments with higher silver nitrate concentration and more cycles increased the silver deposition on titanium surface. No negative effects in fibroblast cell viability were detected and a significant reduction on bacterial adhesion in vitro was achieved in silver-treated samples compared with control titanium. Silver deposition on titanium with a novel electrochemical anodizing process produced surfaces with significant antibacterial properties in vitro without negative effects on cell viability. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  4. Review of progress in pulsed laser deposition and using Nd:YAG laser in processing of high Tc superconductors

    International Nuclear Information System (INIS)

    Chen, C.W.; Mukherjee, K.

    1993-01-01

    The current progress in pulsed laser ablation of high-temperature superconductors is reviewed with emphasis on the effect of pulse-width and wavelength, nature of the plasma plume, post-annealing and methods to improve quality of films grown at low temperature. An ion beam assisted millisecond pulsed laser vapor deposition process has been developed to fabricate YBa 2 Cu 3 O x high T. superconductor thin films. Solution to target overheating problem, effects of oxygen ion beam, properties of deposited films, and effect of silver buffer layer on YSZ substrate are presented. A new laser calcining process has been used to produce near single phase high T c superconductors of Bi-Pb-Sr-Ca-Cu-0 system. The total processing time was reduced to about 100 hours which is about half of that for conventional sintering. For this compound both resistance and magnetic susceptibility data showed an onset of superconducting transition at about 110K. A sharp susceptibility drop was observed above 106K. The zero resistance temperature was about 98K. High T c phase was formed via a different kinetic path in laser calcined sample compare with the conventionally processed sample

  5. The contribution of lateritization processes to the formation of the kaolin deposits from eastern Amazon

    Science.gov (United States)

    da Costa, Marcondes Lima; Sousa, Daniel José Lima; Angélica, Rômulo Simões

    The eastern region of the Amazon is home to the most important kaolin bauxite producing district in Brazil, referred to as the Paragominas-Capim kaolin bauxite district, which has a reserve of at least 1.0 billion tons of high-quality kaolin used in the paper coating industry. The kaolin deposits are closely related to sedimentary rocks of the Parnaíba basin and their lateritic cover. Two large deposits are already being mined: IRCC (Ipixuna) and PPSA (Paragominas). The geology of the IRCC mine is comprised of the kaolin-bearing lower unit (truncated mature laterite succession derived from the Ipixuna/Itapecuru formation) and the upper unit (immature lateritized Barreiras formation). The lower kaolin unit is characterized by a sandy facies at the bottom and a soft (ore) with flint facies at the top. It is formed by kaolinite, quartz, some iron oxi-hydroxides, mica and several accessories and heavy minerals. The mangrove covering; and immature lateritization - partial kaolin ferruginization during the Pleistocene.

  6. Effect of process parameters on formability of laser melting deposited 12CrNi2 alloy steel

    Science.gov (United States)

    Peng, Qian; Dong, Shiyun; Kang, Xueliang; Yan, Shixing; Men, Ping

    2018-03-01

    As a new rapid prototyping technology, the laser melting deposition technology not only has the advantages of fast forming, high efficiency, but also free control in the design and production chain. Therefore, it has drawn extensive attention from community.With the continuous improvement of steel performance requirements, high performance low-carbon alloy steel is gradually integrated into high-tech fields such as aerospace, high-speed train and armored equipment.However, it is necessary to further explore and optimize the difficult process of laser melting deposited alloy steel parts to achieve the performance and shape control.This article took the orthogonal experiment on alloy steel powder by laser melting deposition ,and revealed the influence rule of the laser power, scanning speed, powder gas flow on the quality of the sample than the dilution rate, surface morphology and microstructure analysis were carried out.Finally, under the optimum technological parameters, the Excellent surface quality of the alloy steel forming part with high density, no pore and cracks was obtained.

  7. REE enrichment in granite-derived regolith deposits of the southeast United States: Prospective source rocks and accumulation processes

    Science.gov (United States)

    Foley, Nora K.; Ayuso, Robert A.; Simandl, G.J.; Neetz, M.

    2015-01-01

    The Southeastern United States contains numerous anorogenic, or A-type, granites, which constitute promising source rocks for REE-enriched ion adsorption clay deposits due to their inherently high concentrations of REE. These granites have undergone a long history of chemical weathering, resulting in thick granite-derived regoliths, akin to those of South China, which supply virtually all heavy REE and Y, and a significant portion of light REE to global markets. Detailed comparisons of granite regolith profiles formed on the Stewartsville and Striped Rock plutons, and the Robertson River batholith (Virginia) indicate that REE are mobile and can attain grades comparable to those of deposits currently mined in China. A REE-enriched parent, either A-type or I-type (highly fractionated igneous type) granite, is thought to be critical for generating the high concentrations of REE in regolith profiles. One prominent feature we recognize in many granites and mineralized regoliths is the tetrad behaviour displayed in REE chondrite-normalized patterns. Tetrad patterns in granite and regolith result from processes that promote the redistribution, enrichment, and fractionation of REE, such as late- to post- magmatic alteration of granite and silicate hydrolysis in the regolith. Thus, REE patterns showing tetrad effects may be a key for discriminating highly prospective source rocks and regoliths with potential for REE ion adsorption clay deposits.

  8. Characterization of aluminum/aluminum nitride coatings sputter deposited using the pulsed-gas process

    International Nuclear Information System (INIS)

    Springer, R.W.; Hosford, C.D.

    1981-01-01

    A dc triode magnetron has been used to produce freestanding Al/Al + AlN lamellar foils by sputter deposition. The 5-μm-thick foils produced on both flat substrates as well as curved substrates exhibited good specularity as well as excellent mechanical properties. The pulse spacing was varied from none to 100-nm spacing. The yield strength of the material was found to obey the Hall-Petch relation sigma/sub ys/ = 230 + .07/d/sup 1/2/, where sigma/sub ys/ is in MPa. Auger electron Spectroscopy and Secondary Ion Mass Spectroscopy indicate that the large flow stress of 230 MPa must be due to grain refinement of the extended source and not an impurity effect. The result is that limitations of masking found in uniaxial flux sources for curved surfaces can be removed allowing the high quality coating of more general shapes

  9. Modeling and optimization of atomic layer deposition processes on vertically aligned carbon nanotubes

    Directory of Open Access Journals (Sweden)

    Nuri Yazdani

    2014-03-01

    Full Text Available Many energy conversion and storage devices exploit structured ceramics with large interfacial surface areas. Vertically aligned carbon nanotube (VACNT arrays have emerged as possible scaffolds to support large surface area ceramic layers. However, obtaining conformal and uniform coatings of ceramics on structures with high aspect ratio morphologies is non-trivial, even with atomic layer deposition (ALD. Here we implement a diffusion model to investigate the effect of the ALD parameters on coating kinetics and use it to develop a guideline for achieving conformal and uniform thickness coatings throughout the depth of ultra-high aspect ratio structures. We validate the model predictions with experimental data from ALD coatings of VACNT arrays. However, the approach can be applied to predict film conformality as a function of depth for any porous topology, including nanopores and nanowire arrays.

  10. Modeling and optimization of atomic layer deposition processes on vertically aligned carbon nanotubes.

    Science.gov (United States)

    Yazdani, Nuri; Chawla, Vipin; Edwards, Eve; Wood, Vanessa; Park, Hyung Gyu; Utke, Ivo

    2014-01-01

    Many energy conversion and storage devices exploit structured ceramics with large interfacial surface areas. Vertically aligned carbon nanotube (VACNT) arrays have emerged as possible scaffolds to support large surface area ceramic layers. However, obtaining conformal and uniform coatings of ceramics on structures with high aspect ratio morphologies is non-trivial, even with atomic layer deposition (ALD). Here we implement a diffusion model to investigate the effect of the ALD parameters on coating kinetics and use it to develop a guideline for achieving conformal and uniform thickness coatings throughout the depth of ultra-high aspect ratio structures. We validate the model predictions with experimental data from ALD coatings of VACNT arrays. However, the approach can be applied to predict film conformality as a function of depth for any porous topology, including nanopores and nanowire arrays.

  11. Building a Better Capacitor with Thin-Film Atomic Layer Deposition Processing

    Energy Technology Data Exchange (ETDEWEB)

    Pike, Christopher [North Seattle College, WA (United States)

    2015-08-28

    The goal of this research is to determine procedures for creating ultra-high capacity supercapacitors by using nanofabrication techniques and high k-value dielectrics. One way to potentially solve the problem of climate change is to switch the source of energy to a source that doesn’t release many tons of greenhouse gases, gases which cause global warming, into the Earth’s atmosphere. These trap in more heat from the Sun’s solar energy and cause global temperatures to rise. Atomic layer deposition will be used to create a uniform thin-film of dielectric to greatly enhance the abilities of our capacitors and will build them on the nanoscale.

  12. Understanding adolescent mental health: the influence of social processes, doing gender and gendered power relations.

    Science.gov (United States)

    Landstedt, Evelina; Asplund, Kenneth; Gillander Gådin, Katja

    2009-11-01

    Despite a well-documented gender pattern in adolescent mental health, research investigating possible explanatory factors from a gender-theoretical approach is scarce. This paper reports a grounded theory study based on 29 focus groups. The aim was to explore 16- to 19-year-old students' perceptions of what is significant for mental health, and to apply a gender analysis to the findings in order to advance understanding of the gender pattern in adolescent mental health. Significant factors were identified in three social processes categories, including both positive and negative aspects: (1) social interactions, (2) performance and (3) responsibility. Girls more often experienced negative aspects of these processes, placing them at greater risk for mental health problems. Boys' more positive mental health appeared to be associated with their low degree of responsibility-taking and beneficial positions relative to girls. Negotiating cultural norms of femininity and masculinity seemed to be more strenuous for girls, which could place them at a disadvantage with regard to mental health. Social factors and processes (particularly responsibility), gendered power relations and constructions of masculinities and femininities should be acknowledged as important for adolescent mental health.

  13. WE-E-304-01: SBRT Credentialing: Understanding the Process From Inquiry to Approval

    International Nuclear Information System (INIS)

    Followill, D.

    2015-01-01

    SBRT is having a dramatic impact on radiation therapy of early-stage, locally advanced cancers. A number of national protocols have been and are being developed to assess the clinical efficacy of SBRT for various anatomical sites, such as lung and spine. Physics credentialing for participating and implementation of trial protocols involve a broad spectrum of requirements from image guidance, motion management, to planning technology and dosimetric constrains. For radiation facilities that do not have extensive experiences in SBRT treatment and protocol credentialing, these complex processes of credentialing and implementation could be very challenging and, sometimes, may lead to ineffective even unsuccessful execution of these processes. In this proposal, we will provide comprehensive review of some current SBRT protocols, explain the requirements and their underline rationales, illustrate representative failed and successful experiences, related to SBRT credentialing, and discuss strategies for effective SBRT credentialing and implementation. Learning Objectives: Understand requirements and challenges of SBRT credentailing and implentation Discuss processes and strategies of effective SBRT credentailing Discuss practical considerations, potential pitfalls and solutions of SBRT implentation

  14. Toward a better understanding of the complex geochemical processes governing subsurface contaminant transport

    International Nuclear Information System (INIS)

    Puls, R.W.

    1990-01-01

    Identification and understanding of the geochemical processes, including ion exchange, precipitation, organic partitioning, chemisorption, aqueous complexation, and colloidal stability and transport, controlling subsurface contamination is essential for making accurate predictions of the fate and transport of these constituents. Current approaches to quantify the effect of these processes primarily involve laboratory techniques, including the use of closed static systems (batch experiments) where small amounts of aquifer solids or minerals are contacted with an aqueous phase containing the components of interest for relatively short durations; and dynamic systems (column experiments) where a larger segment of the aquifer is investigated by analyzing the breakthrough profiles of reactive and non-reactive species. Both approaches are constrained by differences in scale, alteration of media during sample collection and use, and spatial variability. More field reactivity studies are needed to complement established laboratory approaches for the determination of retardation factors and scaling factors, corroboration of batch and column results, and validation of sampling techniques. These studies also serve to accentuate areas of geochemical process research where data deficiencies exist, such as the kinetics of adsorption-desorption, metal-organic-mineral interactions, and colloidal mobility. The advantages and disadvantages of the above approaches are discussed in the context of achieving a more completely integrated approach to geochemical transport experiments, with supportive data presented from selected studies. (Author) (16 refs., 4 figs., 2 tabs.)

  15. Modelling dewatering behaviour through an understanding of solids formation processes. Part II--solids separation considerations.

    Science.gov (United States)

    Dustan, A C; Cohen, B; Petrie, J G

    2005-05-30

    An understanding of the mechanisms which control solids formation can provide information on the characteristics of the solids which are formed. The nature of the solids formed in turn impacts on dewatering behaviour. The 'upstream' solids formation determines a set of suspension characteristics: solids concentration, particle size distribution, solution ionic strength and electrostatic surface potential. These characteristics together define the suspension's rheological properties. However, the complicated interdependence of these has precluded the prediction of suspension rheology from such a fundamental description of suspension characteristics. Recent shear yield stress models, applied in this study to compressive yield, significantly reduce the empiricism required for the description of compressive rheology. Suspension compressibility and permeability uniquely define the dewatering behaviour, described in terms of settling, filtration and mechanical expression. These modes of dewatering may be described in terms of the same fundamental suspension mechanics model. In this way, it is possible to link dynamically the processes of solids formation and dewatering of the resultant suspension. This, ultimately, opens the door to improved operability of these processes. In part I of this paper we introduced an integrated system model for solids formation and dewatering. This model was demonstrated for the upstream processes using experimental data. In this current paper models of colloidal interactions and dewatering are presented and compared to experimental results from batch filtration tests. A novel approach to predicting suspension compressibility and permeability using a single test configuration is presented and tested.

  16. Model reduction and physical understanding of slowly oscillating processes : the circadian cycle.

    Energy Technology Data Exchange (ETDEWEB)

    Goussis, Dimitris A. (Ploutonos 7, Palaio Faliro, Greece); Najm, Habib N.

    2006-01-01

    A differential system that models the circadian rhythm in Drosophila is analyzed with the computational singular perturbation (CSP) algorithm. Reduced nonstiff models of prespecified accuracy are constructed, the form and size of which are time-dependent. When compared with conventional asymptotic analysis, CSP exhibits superior performance in constructing reduced models, since it can algorithmically identify and apply all the required order of magnitude estimates and algebraic manipulations. A similar performance is demonstrated by CSP in generating data that allow for the acquisition of physical understanding. It is shown that the processes driving the circadian cycle are (i) mRNA translation into monomer protein, and monomer protein destruction by phosphorylation and degradation (along the largest portion of the cycle); and (ii) mRNA synthesis (along a short portion of the cycle). These are slow processes. Their action in driving the cycle is allowed by the equilibration of the fastest processes; (1) the monomer dimerization with the dimer dissociation (along the largest portion of the cycle); and (2) the net production of monomer+dimmer proteins with that of mRNA (along the short portion of the cycle). Additional results (regarding the time scales of the established equilibria, their origin, the rate limiting steps, the couplings among the variables, etc.) highlight the utility of CSP for automated identification of the important underlying dynamical features, otherwise accessible only for simple systems whose various suitable simplifications can easily be recognized.

  17. New understanding of rhizosphere processes enabled by advances in molecular and spatially resolved techniques

    Energy Technology Data Exchange (ETDEWEB)

    Hess, Nancy J.; Paša-Tolić, Ljiljana; Bailey, Vanessa L.; Dohnalkova, Alice C.

    2017-06-01

    Understanding the role played by microorganisms within soil systems is challenged by the unique intersection of physics, chemistry, mineralogy and biology in fostering habitat for soil microbial communities. To address these challenges will require observations across multiple spatial and temporal scales to capture the dynamics and emergent behavior from complex and interdependent processes. The heterogeneity and complexity of the rhizosphere require advanced techniques that press the simultaneous frontiers of spatial resolution, analyte sensitivity and specificity, reproducibility, large dynamic range, and high throughput. Fortunately many exciting technical advancements are now available to inform and guide the development of new hypotheses. The aim of this Special issue is to provide a holistic view of the rhizosphere in the perspective of modern molecular biology methodologies that enabled a highly-focused, detailed view on the processes in the rhizosphere, including numerous, strong and complex interactions between plant roots, soil constituents and microorganisms. We discuss the current rhizosphere research challenges and knowledge gaps, as well as perspectives and approaches using newly available state-of-the-art toolboxes. These new approaches and methodologies allow the study of rhizosphere processes and properties, and rhizosphere as a central component of ecosystems and biogeochemical cycles.

  18. WE-E-304-01: SBRT Credentialing: Understanding the Process From Inquiry to Approval

    Energy Technology Data Exchange (ETDEWEB)

    Followill, D. [UT MD Anderson Cancer Center (United States)

    2015-06-15

    SBRT is having a dramatic impact on radiation therapy of early-stage, locally advanced cancers. A number of national protocols have been and are being developed to assess the clinical efficacy of SBRT for various anatomical sites, such as lung and spine. Physics credentialing for participating and implementation of trial protocols involve a broad spectrum of requirements from image guidance, motion management, to planning technology and dosimetric constrains. For radiation facilities that do not have extensive experiences in SBRT treatment and protocol credentialing, these complex processes of credentialing and implementation could be very challenging and, sometimes, may lead to ineffective even unsuccessful execution of these processes. In this proposal, we will provide comprehensive review of some current SBRT protocols, explain the requirements and their underline rationales, illustrate representative failed and successful experiences, related to SBRT credentialing, and discuss strategies for effective SBRT credentialing and implementation. Learning Objectives: Understand requirements and challenges of SBRT credentailing and implentation Discuss processes and strategies of effective SBRT credentailing Discuss practical considerations, potential pitfalls and solutions of SBRT implentation.

  19. Synthesis of carbon-13 labelled carbonaceous deposits and their evaluation for potential use as surrogates to better understand the behaviour of the carbon-14-containing deposit present in irradiated PGA graphite

    Energy Technology Data Exchange (ETDEWEB)

    Payne, L., E-mail: liam.payne@bristol.ac.uk [Interface Analysis Centre, HH Wills Physics Laboratory, University of Bristol, BS8 1TL (United Kingdom); Walker, S.; Bond, G. [Centre for Materials Science, University of Central Lancashire, PR1 2HE (United Kingdom); Eccles, H. [John Tyndall Institute for Nuclear Research, School of Computing, Engineering and Physical Sciences, University of Central Lancashire, PR1 2HE (United Kingdom); Heard, P.J.; Scott, T.B. [Interface Analysis Centre, HH Wills Physics Laboratory, University of Bristol, BS8 1TL (United Kingdom); Williams, S.J. [Radioactive Waste Management, B587, Curie Avenue, Harwell Oxford, Didcot, OX11 0RH (United Kingdom)

    2016-03-15

    The present work has used microwave plasma chemical vapour deposition to generate suitable isotopically labelled carbonaceous deposits on the surface of Pile Grade A graphite for use as surrogates for studying the behaviour of the deposits observed on irradiated graphite extracted from UK Magnox reactors. These deposits have been shown elsewhere to contain an enhanced concentration of {sup 14}C compared to the bulk graphite. A combination of Raman spectroscopy, ion beam milling with scanning electron microscopy and secondary ion mass spectrometry were used to determine topography and internal morphology in the formed deposits. Direct comparison was made against deposits found on irradiated graphite samples trepanned from a Magnox reactor core and showed a good similarity in appearance. This work suggests that the microwave plasma chemical vapour deposition technique is of value in producing simulant carbon deposits, being of sufficiently representative morphology for use in non-radioactive surrogate studies of post-disposal behaviour of {sup 14}C-containing deposits on some irradiated Magnox reactor graphite.

  20. Development of the process of boron electrophoresis deposition on aluminum substate to be used in the construction of neutron detectors

    International Nuclear Information System (INIS)

    Oliveira Sampa, M.H. de; Vinhas, L.A.

    1989-11-01

    Process of baron electrophoresis depositon on large areas of aluminum substrates was developed with the aim of using them in the construction of neutron detectors. After definition and optimization of the boron electrophoresis parameters, depositions of 10 B on aluminium cylinders were performed and used as electrodes in gamma compensated and non-compensated ionization chambers and in proportional detectors. Prototypers of ionization chambers were designed, built and assembled at the Departinent for Engineering and Industry Application (TE) of the Instituto de Pesquisas Energeticas e Nucleares (IPEN), and submited for characterization tests at IEA-R1 reactor. They fully met the technical specifications of the projects. (author) [pt

  1. Review of recent progresses on flexible oxide semiconductor thin film transistors based on atomic layer deposition processes

    Science.gov (United States)

    Sheng, Jiazhen; Han, Ki-Lim; Hong, TaeHyun; Choi, Wan-Ho; Park, Jin-Seong

    2018-01-01

    The current article is a review of recent progress and major trends in the field of flexible oxide thin film transistors (TFTs), fabricating with atomic layer deposition (ALD) processes. The ALD process offers accurate controlling of film thickness and composition as well as ability of achieving excellent uniformity over large areas at relatively low temperatures. First, an introduction is provided on what is the definition of ALD, the difference among other vacuum deposition techniques, and the brief key factors of ALD on flexible devices. Second, considering functional layers in flexible oxide TFT, the ALD process on polymer substrates may improve device performances such as mobility and stability, adopting as buffer layers over the polymer substrate, gate insulators, and active layers. Third, this review consists of the evaluation methods of flexible oxide TFTs under various mechanical stress conditions. The bending radius and repetition cycles are mostly considering for conventional flexible devices. It summarizes how the device has been degraded/changed under various stress types (directions). The last part of this review suggests a potential of each ALD film, including the releasing stress, the optimization of TFT structure, and the enhancement of device performance. Thus, the functional ALD layers in flexible oxide TFTs offer great possibilities regarding anti-mechanical stress films, along with flexible display and information storage application fields. Project supported by the National Research Foundation of Korea (NRF) (No. NRF-2017R1D1A1B03034035), the Ministry of Trade, Industry & Energy (No. #10051403), and the Korea Semiconductor Research Consortium.

  2. Analysis of the Influence of the Use of Cutting Fluid in Hybrid Processes of Machining and Laser Metal Deposition (LMD

    Directory of Open Access Journals (Sweden)

    Magdalena Cortina

    2018-02-01

    Full Text Available Hybrid manufacturing processes that combine additive and machining operations are gaining relevance in modern industry thanks to the capability of building complex parts with minimal material and, many times, with process time reduction. Besides, as the additive and subtractive operations are carried out in the same machine, without moving the part, dead times are reduced and higher accuracies are achieved. However, it is not clear whether the direct material deposition after the machining operation is possible or intermediate cleaning stages are required because of the possible presence of residual cutting fluids. Therefore, different Laser Metal Deposition (LMD tests are performed on a part impregnated with cutting fluid, both directly and after the removal of the coolant by techniques such as laser vaporizing and air blasting. The present work studies the influence of the cutting fluid in the LMD process and the quality of the resulting part. Resulting porosity is evaluated and it is concluded that if the part surface is not properly clean after the machining operation, deficient clad quality can be obtained in the subsequent laser additive operation.

  3. Development Status of a CVD System to Deposit Tungsten onto UO2 Powder via the WCI6 Process

    Science.gov (United States)

    Mireles, O. R.; Kimberlin, A.; Broadway, J.; Hickman, R.

    2014-01-01

    Nuclear Thermal Propulsion (NTP) is under development for deep space exploration. NTP's high specific impulse (> 850 second) enables a large range of destinations, shorter trip durations, and improved reliability. W-60vol%UO2 CERMET fuel development efforts emphasize fabrication, performance testing and process optimization to meet service life requirements. Fuel elements must be able to survive operation in excess of 2850 K, exposure to flowing hydrogen (H2), vibration, acoustic, and radiation conditions. CTE mismatch between W and UO2 result in high thermal stresses and lead to mechanical failure as a result UO2 reduction by hot hydrogen (H2) [1]. Improved powder metallurgy fabrication process control and mitigated fuel loss can be attained by coating UO2 starting powders within a layer of high density tungsten [2]. This paper discusses the advances of a fluidized bed chemical vapor deposition (CVD) system that utilizes the H2-WCl6 reduction process.

  4. Understanding Student Cognition about Complex Earth System Processes Related to Climate Change

    Science.gov (United States)

    McNeal, K. S.; Libarkin, J.; Ledley, T. S.; Dutta, S.; Templeton, M. C.; Geroux, J.; Blakeney, G. A.

    2011-12-01

    The Earth's climate system includes complex behavior and interconnections with other Earth spheres that present challenges to student learning. To better understand these unique challenges, we have conducted experiments with high-school and introductory level college students to determine how information pertaining to the connections between the Earth's atmospheric system and the other Earth spheres (e.g., hydrosphere and cryosphere) are processed. Specifically, we include psychomotor tests (e.g., eye-tracking) and open-ended questionnaires in this research study, where participants were provided scientific images of the Earth (e.g., global precipitation and ocean and atmospheric currents), eye-tracked, and asked to provide causal or relational explanations about the viewed images. In addition, the students engaged in on-line modules (http://serc.carleton.edu/eslabs/climate/index.html) focused on Earth system science as training activities to address potential cognitive barriers. The developed modules included interactive media, hands-on lessons, links to outside resources, and formative assessment questions to promote a supportive and data-rich learning environment. Student eye movements were tracked during engagement with the materials to determine the role of perception and attention on understanding. Students also completed a conceptual questionnaire pre-post to determine if these on-line curriculum materials assisted in their development of connections between Earth's atmospheric system and the other Earth systems. The pre-post results of students' thinking about climate change concepts, as well as eye-tracking results, will be presented.

  5. Preparation and Support of Patients through the Transplant Process: Understanding the Recipients' Perspectives

    Directory of Open Access Journals (Sweden)

    Oliver Mauthner

    2012-01-01

    Full Text Available Preparation for heart transplant commonly includes booklets, instructional videos, personalized teaching sessions, and mentorship. This paper explores heart transplant recipients’ thoughts on their preparation and support through the transplant process. Twenty-five interviews were audio-/videotaped capturing voice and body language and transcribed verbatim. Coding addressed language, bodily gesture, volume, and tone in keeping with our visual methodology. Recipients reported that only someone who had a transplant truly understands the experience. As participants face illness and life-altering experiences, maintaining a positive attitude and hope is essential to coping well. Healthcare professionals provide ongoing care and reassurance about recipients’ medical status. Mentors, family members, and close friends play vital roles in supporting recipients. Participants reported that only heart transplant recipients understood the experience, the hope, and ultimately the suffering associated with living with another persons’ heart. Attention needs to be focused not solely on the use of teaching modalities, but also on the development of innovative support networks. This will promote patient and caregiver engagement in self-management. Enhancing clinicians’ knowledge of the existential aspects of transplantation will provide them with a nuanced understanding of the patients’ experience, which will ultimately enhance their ability to better prepare and support patients and their caregivers.

  6. Assessing middle school students` understanding of science relationships and processes. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Schau, C.; Mattern, N.; Weber, R. [Univ. of New Nexico, Albuquerque, NM (United States); Minnick, K. [Minnick & Associates, Inc., Albuquerque, NM (United States)

    1994-09-01

    Our overall goal for this multi-year project is to develop and validate an alternative assessment format that effectively measures middle school students understanding of the relationships among selected science concepts and processes. In this project, we collaborate with the staff of the Los Alamos National Laboratory`s TOPS Program and the Programs participating teachers and their students. We also work with selected middle school science teachers from the TOPS program at Sandia National Laboratories. Our goal for this past year was to develop and field test informally a variety of potential measurement formats. This work has allowed us to identify formats to test during the validation phase of the project which will occur during the second year.

  7. Understanding, representing and communicating earth system processes in weather and climate within CNRCWP

    Science.gov (United States)

    Sushama, Laxmi; Arora, Vivek; de Elia, Ramon; Déry, Stephen; Duguay, Claude; Gachon, Philippe; Gyakum, John; Laprise, René; Marshall, Shawn; Monahan, Adam; Scinocca, John; Thériault, Julie; Verseghy, Diana; Zwiers, Francis

    2017-04-01

    The Canadian Network for Regional Climate and Weather Processes (CNRCWP) provides significant advances and innovative research towards the ultimate goal of reducing uncertainty in numerical weather prediction and climate projections for Canada's Northern and Arctic regions. This talk will provide an overview of the Network and selected results related to the assessment of the added value of high-resolution modelling that has helped fill critical knowledge gaps in understanding the dynamics of extreme temperature and precipitation events and the complex land-atmosphere interactions and feedbacks in Canada's northern and Arctic regions. In addition, targeted developments in the Canadian regional climate model, that facilitate direct application of model outputs in impact and adaptation studies, particularly those related to the water, energy and infrastructure sectors will also be discussed. The close collaboration between the Network and its partners and end users contributed significantly to this effort.

  8. Piloting a logic-based framework for understanding organisational change process for a health IT implementation.

    Science.gov (United States)

    Diment, Kieren; Garrety, Karin; Yu, Ping

    2011-01-01

    This paper describes how a method for evaluating organisational change based on the theory of logical types can be used for classifying organisational change processes to understand change after the implementation of an electronic documentation system in a residential aged care facility. In this instance we assess the organisational change reflected by care staff's perceptions of the benefits of the new documentation system at one site, at pre-implementation, and at 12 months post-implementation. The results show how a coherent view from the staff as a whole of the personal benefits, the benefits for others and the benefits for the organization create a situation of positive feedback leading to embeddedness of the documentation system into the site, and a broader appreciation of the potential capabilities of the electronic documentation system.

  9. Understanding Global Change: Tools for exploring Earth processes and biotic change through time

    Science.gov (United States)

    Bean, J. R.; White, L. D.; Berbeco, M.

    2014-12-01

    Teaching global change is one of the great pedagogical challenges of our day because real understanding entails integrating a variety of concepts from different scientific subject areas, including chemistry, physics, and biology, with a variety of causes and impacts in the past, present, and future. With the adoption of the Next Generation Science Standards, which emphasize climate change and other human impacts on natural systems, there has never been a better time to provide instructional support to educators on these topics. In response to this clear need, the University of California Museum of Paleontology, in collaboration with the National Center for Science Education, developed a new web resource for teachers and students titled "Understanding Global Change" (UGC) that introduces the drivers and impacts of global change. This website clarifies the connections among deep time, modern Earth system processes, and anthropogenic influences, and provides K-16 instructors with a wide range of easy-to-use tools, strategies, and lesson plans for communicating these important concepts regarding global change and the basic Earth systems processes. In summer 2014, the UGC website was field-tested during a workshop with 25 K-12 teachers and science educators. Feedback from participants helped the UGC team develop and identify pedagogically sound lesson plans and instructional tools on global change. These resources are accessible through UGC's searchable database, are aligned with NGSS and Common Core, and are categorized by grade level, subject, and level of inquiry-based instruction (confirmation, structured, guided, open). Providing a range of content and tools at levels appropriate for teachers is essential because our initial needs assessment found that educators often feel that they lack the content knowledge and expertise to address complex, but relevant global change issues, such as ocean acidification and deforestation. Ongoing needs assessments and surveys of

  10. Understanding the creation of & reducing surface microroughness during polishing & post-processing of glass optics

    Energy Technology Data Exchange (ETDEWEB)

    Suratwala, Tayyab [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2016-09-22

    In the follow study, we have developed a detailed understanding of the chemical and mechanical microscopic interactions that occur during polishing affecting the resulting surface microroughness of the workpiece. Through targeted experiments and modeling, the quantitative relationships of many important polishing parameters & characteristics affecting surface microroughness have been determined. These behaviors and phenomena have been described by a number of models including: (a) the Ensemble Hertzian Multi Gap (EHMG) model used to predict the removal rate and roughness at atomic force microscope (AFM) scale lengths as a function of various polishing parameters, (b) the Island Distribution Gap (IDG) model used to predict the roughness at larger scale lengths, (c) the Deraguin-Verwey-Landau-Overbeek (DLVO) 3-body electrostatic colloidal model used to predict the interaction of slurry particles at the interface and roughness behavior as a function of pH, and (d) a diffusion/chemical reaction rate model of the incorporation of impurities species into the polishing surface layer (called the Bielby layer). Based on this improved understanding, novel strategies to polish the workpiece have been developed simultaneously leading to both ultrasmooth surfaces and high material removal rates. Some of these strategies include: (a) use of narrow PSD slurries, (b) a novel diamond conditioning recipe of the lap to increase the active contact area between the workpiece and lap without destroying its surface figure, (c) proper control of pH for a given glass type to allow for a uniform distribution of slurry particles at the interface, and (d) increase in applied load just up to the transition between molecular to plastic removal regime for a single slurry particle. These techniques have been incorporated into a previously developed finishing process called Convergent Polishing leading to not just economical finishing process with improved surface figure control, but also

  11. Omics Approaches for Understanding Grapevine Berry Development: Regulatory Networks Associated with Endogenous Processes and Environmental Responses

    Directory of Open Access Journals (Sweden)

    Alejandra Serrano

    2017-09-01

    Full Text Available Grapevine fruit development is a dynamic process that can be divided into three stages: formation (I, lag (II, and ripening (III, in which physiological and biochemical changes occur, leading to cell differentiation and accumulation of different solutes. These stages can be positively or negatively affected by multiple environmental factors. During the last decade, efforts have been made to understand berry development from a global perspective. Special attention has been paid to transcriptional and metabolic networks associated with the control of grape berry development, and how external factors affect the ripening process. In this review, we focus on the integration of global approaches, including proteomics, metabolomics, and especially transcriptomics, to understand grape berry development. Several aspects will be considered, including seed development and the production of seedless fruits; veraison, at which anthocyanin accumulation begins in the berry skin of colored varieties; and hormonal regulation of berry development and signaling throughout ripening, focusing on the transcriptional regulation of hormone receptors, protein kinases, and genes related to secondary messenger sensing. Finally, berry responses to different environmental factors, including abiotic (temperature, water-related stress and UV-B radiation and biotic (fungi and viruses stresses, and how they can significantly modify both, development and composition of vine fruit, will be discussed. Until now, advances have been made due to the application of Omics tools at different molecular levels. However, the potential of these technologies should not be limited to the study of single-level questions; instead, data obtained by these platforms should be integrated to unravel the molecular aspects of grapevine development. Therefore, the current challenge is the generation of new tools that integrate large-scale data to assess new questions in this field, and to support

  12. Geological Mapping of Impact Melt Deposits at Lunar Complex Craters: New Insights into Morphological Diversity, Distribution and the Cratering Process

    Science.gov (United States)

    Dhingra, D.; Head, J. W., III; Pieters, C. M.

    2014-12-01

    We have completed high resolution geological mapping of impact melt deposits at the young lunar complex craters (wall and rim impact melt units and their relation to floor units have also been mapped. Among the distinctive features of these impact melt deposits are: 1) Impact Melt Wave Fronts: These are extensive (sometimes several kilometers in length) and we have documented their occurrence and distribution in different parts of the crater floor at Jackson and Tycho. These features emphasize melt mobility and style of emplacement during the modification stage of the craters. 2) Variations in Floor Elevations: Spatially extensive and coherent sections of crater floors have different elevations at all the three craters. The observed elevation differences could be caused by subsidence due to cooling of melt and/or structural failure, together with a contribution from regional slope. 3) Melt-Covered Megablocks: We also observe large blocks/rock-fragments (megablocks) covered in impact melt, which could be sections of collapsed wall or in some cases, subdued sections of central peaks. 4) Melt-Covered Central Peaks: Impact melt has also been mapped on the central peaks but varies in spatial extent among the craters. The presence of melt on peaks must be taken into account when interpreting peak mineralogy as exposures of deeper crust. 5) Boulder Distribution: Interesting trends are observed in the distribution of boulder units of various sizes; some impact melt units have spatially extensive boulders, while boulder distribution is very scarce in other units on the floor. We interpret these distributions to be influenced by a) the differential collapse of the crater walls during the modification stage, and b) the amount of relative melt volume retained in different parts of the crater floor. These observations provide important documentation of the morphological diversity and better understanding of the emplacement and final distribution of impact melt deposits.

  13. Study of a low-dose capsule filling process by dynamic and static tests for advanced process understanding.

    Science.gov (United States)

    Stranzinger, S; Faulhammer, E; Scheibelhofer, O; Calzolari, V; Biserni, S; Paudel, A; Khinast, J G

    2018-04-05

    Precise filling of capsules with doses in the mg-range requires a good understanding of the filling process. Therefore, we investigated the various process steps of the filling process by dynamic and static mode tests. Dynamic tests refer to filling of capsules in a regular laboratory dosator filling machine. Static tests were conducted using a novel filling system developed by us. Three grades of lactose excipients were filled into size 3 capsules with different dosing chamber lengths, nozzle diameters and powder bed heights, and, in the dynamic mode, with two filling speeds (500, 3000 caps/h). The influence of the gap at the bottom of the powder container on the fill weight and variability was assessed. Different gaps resulted in a change in fill weight in all materials, although in different ways. In all cases, the fill weight of highly cohesive Lactohale 220 increased when decreasing the gap. Furthermore, experiments with the stand-alone static test tool indicated that this very challenging powder could successfully be filled without any pre-compression in the range of 5 mg-20 mg with acceptable RSDs. This finding is of great importance since for very fine lactose powders high compression ratios (dosing-chamber-length-to-powder-bed height compression ratios) may result in jamming of the piston. Moreover, it shows that the static mode setup is suitable for studying fill weight and variability. Since cohesive powders, such as Lactohale 220, are hard to fill, we investigated the impact of vibration on the process. Interestingly, we found no correlation between the reported fill weight changes in dynamic mode at 3000 cph and static mode using similar vibration. However, we could show that vibrations during sampling in the static mode dramatically reduced fill weight variability. Overall, our results indicate that by fine-tuning instrumental settings even very challenging powders can be filled with a low-dose dosator capsule filling machine. This study is a

  14. Process optimization of atomized melt deposition for the production of dispersion strengthened Al-8.5%Fe-1.2%V-1.7%Si alloys

    International Nuclear Information System (INIS)

    Hariprasad, S.; Sastry, S.M.L.; Jerina, K.L.

    1995-01-01

    Atomized melt deposition is a low cost manufacturing process with the microstructural control achieved through rapid solidification. In this process the liquid metal is disintegrated into fine droplets by gas atomization and the droplets are deposited on a substrate producing near net shape products. In the present investigation Al-8.5%Fe-1.2%V-1.7%Si alloy was produced using atomized melt deposition process to study the evolution of microstructure and assess the cooling rates and the undercooling achieved during the process. The size, morphology and the composition of second phase particles in the alloy are strong functions of the cooling rate and the undercooling and hence microstructural changes with the variation in process parameters were quantified. To define optimum conditions for the atomized melt deposition process, a mathematical model was developed. The model determines the temperature distribution of the liquid droplets during gas atomization and during the deposition stages. The model predicts the velocity distribution, cooling rates and the fraction solid, during the flight for different droplet sizes. The solidification heat transfer phenomena taking place during the atomized melt deposition process was analyzed using a finite difference method based on the enthalpy formulation

  15. A comparison of multi-metal deposition processes utilising gold nanoparticles and an evaluation of their application to 'low yield' surfaces for finger mark development.

    Science.gov (United States)

    Fairley, C; Bleay, S M; Sears, V G; NicDaeid, N

    2012-04-10

    This paper reports a comparison of the effectiveness and practicality of using different multi-metal deposition processes for finger mark development. The work investigates whether modifications can be made to improve the performance of the existing process published by Schnetz. Secondly, we compare the ability of different multi-metal deposition processes to develop finger marks on a range of surfaces with that of other currently used development processes. All published multi-metal deposition processes utilise an initial stage of colloidal gold deposition followed by enhancement of the marks with using a physical developer. All possible combinations of colloidal gold and physical developer stages were tested. The method proposed by Schnetz was shown to be the most effective process, however a modification which reduced the pH of the enhancement solution was revealed to provide the best combination of effectiveness and practicality. In trials comparing the modified formulation with vacuum metal deposition, superglue and powder suspensions on surfaces which typically give low finger mark yields (cling film, plasticised vinyl, leather and masking tape), the modified method produced significantly better results over existing processes for cling film and plasticised vinyl. The modified formulation was found to be ineffective on both masking tape and leather. It is recommended that further tests be carried out on the modified multi-metal deposition formulation to establish whether it could be introduced for operational work on cling film material in particular. Copyright © 2011 Elsevier Ireland Ltd. All rights reserved.

  16. Using the Bongwana natural CO2 release to understand leakage processes and develop monitoring

    Science.gov (United States)

    Jones, David; Johnson, Gareth; Hicks, Nigel; Bond, Clare; Gilfillan, Stuart; Kremer, Yannick; Lister, Bob; Nkwane, Mzikayise; Maupa, Thulani; Munyangane, Portia; Robey, Kate; Saunders, Ian; Shipton, Zoe; Pearce, Jonathan; Haszeldine, Stuart

    2016-04-01

    Natural CO2 leakage along the Bongwana Fault in South Africa is being studied to help understand processes of CO2 leakage and develop monitoring protocols. The Bongwana Fault crops out over approximately 80 km in KwaZulu-Natal province, South Africa. In outcrop the fault is expressed as a broad fracture corridor in Dwyka Tillite, with fractures oriented approximately N-S. Natural emissions of CO2 occur at various points along the fault, manifest as travertine cones and terraces, bubbling in the rivers and as gas fluxes through soil. Exposed rock outcrop shows evidence for Fe-staining around fractures and is locally extensively kaolinitised. The gas has also been released through a shallow water well, and was exploited commercially in the past. Preliminary studies have been carried out to better document the surface emissions using near surface gas monitoring, understand the origin of the gas through major gas composition and stable and noble gas isotopes and improve understanding of the structural controls on gas leakage through mapping. In addition the impact of the leaking CO2 on local water sources (surface and ground) is being investigated, along with the seismic activity of the fault. The investigation will help to build technical capacity in South Africa and to develop monitoring techniques and plans for a future CO2 storage pilot there. Early results suggest that CO2 leakage is confined to a relatively small number of spatially-restricted locations along the weakly seismically active fault. Fracture permeability appears to be the main method by which the CO2 migrates to the surface. The bulk of the CO2 is of deep origin with a minor contribution from near surface biogenic processes as determined by major gas composition. Water chemistry, including pH, DO and TDS is notably different between CO2-rich and CO2-poor sites. Soil gas content and flux effectively delineates the fault trace in active leakage sites. The fault provides an effective testing ground for

  17. Hominin track assemblages from Okote Member deposits near Ileret, Kenya, and their implications for understanding fossil hominin paleobiology at 1.5 Ma.

    Science.gov (United States)

    Hatala, Kevin G; Roach, Neil T; Ostrofsky, Kelly R; Wunderlich, Roshna E; Dingwall, Heather L; Villmoare, Brian A; Green, David J; Braun, David R; Harris, John W K; Behrensmeyer, Anna K; Richmond, Brian G

    2017-11-01

    Tracks can provide unique, direct records of behaviors of fossil organisms moving across their landscapes millions of years ago. While track discoveries have been rare in the human fossil record, over the last decade our team has uncovered multiple sediment surfaces within the Okote Member of the Koobi Fora Formation near Ileret, Kenya that contain large assemblages of ∼1.5 Ma fossil hominin tracks. Here, we provide detailed information on the context and nature of each of these discoveries, and we outline the specific data that are preserved on the Ileret hominin track surfaces. We analyze previously unpublished data to refine and expand upon earlier hypotheses regarding implications for hominin anatomy and social behavior. While each of the track surfaces discovered at Ileret preserves a different amount of data that must be handled in particular ways, general patterns are evident. Overall, the analyses presented here support earlier interpretations of the ∼1.5 Ma Ileret track assemblages, providing further evidence of large, human-like body sizes and possibly evidence of a group composition that could support the emergence of certain human-like patterns of social behavior. These data, used in concert with other forms of paleontological and archaeological evidence that are deposited on different temporal scales, offer unique windows through which we can broaden our understanding of the paleobiology of hominins living in East Africa at ∼1.5 Ma. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Low-temperature atomic layer deposition of TiO2 thin layers for the processing of memristive devices

    International Nuclear Information System (INIS)

    Porro, Samuele; Conti, Daniele; Guastella, Salvatore; Ricciardi, Carlo; Jasmin, Alladin; Pirri, Candido F.; Bejtka, Katarzyna; Perrone, Denis; Chiolerio, Alessandro

    2016-01-01

    Atomic layer deposition (ALD) represents one of the most fundamental techniques capable of satisfying the strict technological requirements imposed by the rapidly evolving electronic components industry. The actual scaling trend is rapidly leading to the fabrication of nanoscaled devices able to overcome limits of the present microelectronic technology, of which the memristor is one of the principal candidates. Since their development in 2008, TiO 2 thin film memristors have been identified as the future technology for resistive random access memories because of their numerous advantages in producing dense, low power-consuming, three-dimensional memory stacks. The typical features of ALD, such as self-limiting and conformal deposition without line-of-sight requirements, are strong assets for fabricating these nanosized devices. This work focuses on the realization of memristors based on low-temperature ALD TiO 2 thin films. In this process, the oxide layer was directly grown on a polymeric photoresist, thus simplifying the fabrication procedure with a direct liftoff patterning instead of a complex dry etching process. The TiO 2 thin films deposited in a temperature range of 120–230 °C were characterized via Raman spectroscopy and x-ray photoelectron spectroscopy, and electrical current–voltage measurements taken in voltage sweep mode were employed to confirm the existence of resistive switching behaviors typical of memristors. These measurements showed that these low-temperature devices exhibit an ON/OFF ratio comparable to that of a high-temperature memristor, thus exhibiting similar performances with respect to memory applications

  19. Process-Based Model for Computation of Erosion and Deposition on Shrub-Protected Banks

    Science.gov (United States)

    Kean, J. W.; Smith, J.

    2001-12-01

    Determination of erosion and deposition rates on riverbanks requires a detailed knowledge of the near-bank boundary shear stress field. Riverbanks typically are irregular in planiform geometry owing to the presence of vegetation on them, and the effects of vegetation-caused bank irregularity in reducing flow in the neighborhood of the toes of banks must be taken into account in calculating the appropriate boundary shear stress fields. Form drag on roots, stems, and branches of shrubs and trees that protrude into the flow must be carefully evaluated. Methods for calculating the boundary shear stress and sediment transport fields on and near vegetated banks have been developed over the past several years. More recently, the direct effects of roots, stems, and branches in reducing the shear stresses on banks have been investigated in conjunction with research on arroyo channels having nearly trapezoidal cross sections and banks covered with sandbar willow and tamarisk. A model for computing flow and sediment transport in such channels is presented and then used to demonstrate the relative importance of the various environmental factors and their interactions. The primary environmental factors include (1) the cross-sectional geometry of the flow, which controls the structure of the cross-sectional distribution of the streamwise-averaged boundary shear stress, (2) the micro topography of the bed and banks, which determines the local ratio of streamwise-averaged boundary shear stress to skin friction and, thus, the cross-sectional structure of the sediment transport field in the channel, and (3) the bed-sediment size distribution, which controls the importance of density stratification in the flow and, thereby, the vertical structure of the velocity field. The model demonstrates that woody vegetation on sloping banks affects the flow in several ways. First, it forces the high velocity core toward the center of the channel, increasing the streamwise-averaged boundary

  20. Peer review in design: Understanding the impact of collaboration on the review process and student perception

    Science.gov (United States)

    Mandala, Mahender Arjun

    A cornerstone of design and design education is frequent situated feedback. With increasing class sizes, and shrinking financial and human resources, providing rich feedback to students becomes increasingly difficult. In the field of writing, web-based peer review--the process of utilizing equal status learners within a class to provide feedback to each other on their work using networked computing systems--has been shown to be a reliable and valid source of feedback in addition to improving student learning. Designers communicate in myriad ways, using the many languages of design and combining visual and descriptive information. This complex discourse of design intent makes peer reviews by design students ambiguous and often not helpful to the receivers of this feedback. Furthermore, engaging students in the review process itself is often difficult. Teams can complement individual diversity and may assist novice designers collectively resolve complex task. However, teams often incur production losses and may be impacted by individual biases. In the current work, we look at utilizing a collaborative team of reviewers, working collectively and synchronously, in generating web based peer reviews in a sophomore engineering design class. Students participated in a cross-over design, conducting peer reviews as individuals and collaborative teams in parallel sequences. Raters coded the feedback generated on the basis of their appropriateness and accuracy. Self-report surveys and passive observation of teams conducting reviews captured student opinion on the process, its value, and the contrasting experience they had conducting team and individual reviews. We found team reviews generated better quality feedback in comparison to individual reviews. Furthermore, students preferred conducting reviews in teams, finding the process 'fun' and engaging. We observed several learning benefits of using collaboration in reviewing including improved understanding of the assessment

  1. Understanding the structured processes followed by organisations prior to engaging in agile processes: A South African Perspective

    Directory of Open Access Journals (Sweden)

    Nimrod Noruwana

    2012-06-01

    Full Text Available There appears to be a lack of knowledge on the phases South African (SA organisations go through while adopting agile methods. As a means to address this gap, this study uncovered empirical evidence on the phases SA organisations go through whilst adopting agile methods as well as the disparities between agile prescriptions and the way SA organisations actually implement agile methods. The data collected using a case study approach was analysed through the lens of Actor-Network Theory (ANT. The results reveal that there is no structured process for adopting agile methods and organisations go through various phases in their attempts to adopt agile methods. During the various phases, organisations face challenges which are culture as well as people related. Through this study South African practitioners could now be aware that before adopting an agile methodology, there has to be a common understanding of the problems at hand and the envisioned solution. The findings also inform aspiring adopters in South Africa that adoption of the methods does not have to be as prescribed. They are free to adopt only those aspects the organisations need most.

  2. Understanding the local socio-political processes affecting conservation management outcomes in Corbett Tiger Reserve, India.

    Science.gov (United States)

    Rastogi, Archi; Hickey, Gordon M; Badola, Ruchi; Hussain, Syed Ainul

    2014-05-01

    Several measures have been recommended to guarantee a sustainable population of tigers: sufficient inviolate spaces for a viable population, sufficient prey populations, trained and skilled manpower to guard against poaching and intrusion, banning trade in tiger products to reduce poaching, and importantly, the political will to precipitate these recommendations into implementation. Of these, the creation of sufficient inviolate spaces (generally in the form of protected areas) has created the most issues with local resource-dependent communities, often resulting in significant challenges for tiger conservation policy and management. Very little empirical research has, however, been done to understand and contextualize the local-level socio-political interactions that may influence the efficacy of tiger conservation in India. In this paper, we present the results of exploratory research into the ways in which local-stakeholder groups affect the management of Corbett Tiger Reserve (CTR). Using a combined grounded theory-case study research design, and the Institutional Analysis and Development framework for analysis, we identify the socio-political processes through which local-stakeholder groups are able to articulate their issues and elicit desirable actions from the management of CTR. Increasing our awareness of these processes can help inform the design and implementation of more effective tiger conservation management and policy strategies that have the potential to create more supportive coalitions of tiger conservation stakeholders at the local level.

  3. Understanding the Local Socio-political Processes Affecting Conservation Management Outcomes in Corbett Tiger Reserve, India

    Science.gov (United States)

    Rastogi, Archi; Hickey, Gordon M.; Badola, Ruchi; Hussain, Syed Ainul

    2014-05-01

    Several measures have been recommended to guarantee a sustainable population of tigers: sufficient inviolate spaces for a viable population, sufficient prey populations, trained and skilled manpower to guard against poaching and intrusion, banning trade in tiger products to reduce poaching, and importantly, the political will to precipitate these recommendations into implementation. Of these, the creation of sufficient inviolate spaces (generally in the form of protected areas) has created the most issues with local resource-dependent communities, often resulting in significant challenges for tiger conservation policy and management. Very little empirical research has, however, been done to understand and contextualize the local-level socio-political interactions that may influence the efficacy of tiger conservation in India. In this paper, we present the results of exploratory research into the ways in which local-stakeholder groups affect the management of Corbett Tiger Reserve (CTR). Using a combined grounded theory-case study research design, and the Institutional Analysis and Development framework for analysis, we identify the socio-political processes through which local-stakeholder groups are able to articulate their issues and elicit desirable actions from the management of CTR. Increasing our awareness of these processes can help inform the design and implementation of more effective tiger conservation management and policy strategies that have the potential to create more supportive coalitions of tiger conservation stakeholders at the local level.

  4. Contribution of Satellite Gravimetry to Understanding Seismic Source Processes of the 2011 Tohoku-Oki Earthquake

    Science.gov (United States)

    Han, Shin-Chan; Sauber, Jeanne; Riva, Riccardo

    2011-01-01

    The 2011 great Tohoku-Oki earthquake, apart from shaking the ground, perturbed the motions of satellites orbiting some hundreds km away above the ground, such as GRACE, due to coseismic change in the gravity field. Significant changes in inter-satellite distance were observed after the earthquake. These unconventional satellite measurements were inverted to examine the earthquake source processes from a radically different perspective that complements the analyses of seismic and geodetic ground recordings. We found the average slip located up-dip of the hypocenter but within the lower crust, as characterized by a limited range of bulk and shear moduli. The GRACE data constrained a group of earthquake source parameters that yield increasing dip (7-16 degrees plus or minus 2 degrees) and, simultaneously, decreasing moment magnitude (9.17-9.02 plus or minus 0.04) with increasing source depth (15-24 kilometers). The GRACE solution includes the cumulative moment released over a month and demonstrates a unique view of the long-wavelength gravimetric response to all mass redistribution processes associated with the dynamic rupture and short-term postseismic mechanisms to improve our understanding of the physics of megathrusts.

  5. Plume dispersion and deposition processes of tracer gas and aerosols in short-distance experiments

    International Nuclear Information System (INIS)

    Taeschner, M.; Bunnenberg, C.

    1988-01-01

    Data used in this paper were extracted from field experiments carried out in France and Canada to study the pathway of elementary tritium after possible emissions from future fusion reactors and from short-range experiments with nutrient aerosols performed in a German forest in view of a therapy of damaged coniferous trees by foliar nutrition. Comparisons of dispersion parameters evaluated from the tritium field experiments show that in the case of the 30-min release the variations of the wind directions represent the dominant mechanism of lateral plume dispersion under unstable weather conditions. This corresponds with the observation that for the short 2-min emission the plume remains more concentrated during propagation, and the small lateral dispersion parameters typical for stable conditions have to be applied. The investigations on the dispersion of aerosol plumes into a forest boundary layer show that the Gaussian plume model can be modified by a windspeed factor to be valid for predictions on aerosol concentrations and depositions even in a structured topography like a forest

  6. Influence of processing parameters on lattice parameters in laser deposited tool alloy steel

    Energy Technology Data Exchange (ETDEWEB)

    Sun, G.F., E-mail: gfsun82@gmail.com [Center for Laser-Aided Intelligent Manufacturing, University of Michigan, Ann Arbor, MI, 48109 (United States); School of Mechanical Engineering, Jiangsu University, Zhenjiang, Jiangsu, 212013 (China); Bhattacharya, S. [Center for Laser-Aided Intelligent Manufacturing, University of Michigan, Ann Arbor, MI, 48109 (United States); Dinda, G.P.; Dasgupta, A. [Center for Advanced Technologies, Focus: Hope, Detroit, MI, 48238 (United States); Mazumder, J. [Center for Laser-Aided Intelligent Manufacturing, University of Michigan, Ann Arbor, MI, 48109 (United States)

    2011-06-15

    Highlights: {yields} Orientation relationships among phases in the DMD are given. {yields} Martensite lattice parameters increased with laser specific energy. {yields} Austenite lattice parameters decreased with laser specific energy. - Abstract: Laser aided direct metal deposition (DMD) has been used to form AISI 4340 steel coating on the AISI 4140 steel substrate. The microstructural property of the DMD coating was analyzed by means of scanning electron microscopy, transmission electron microscopy and X-ray diffractometry. Microhardness of the DMD was measured with a Vickers microhardness tester. Results indicate that DMD can be used to form dense AISI 4340 steel coatings on AISI 4140 steel substrate. The DMD coating is mainly composed of martensite and retained austenite. Consecutive thermal cycles have a remarkable effect on the microstructure of the plan view of the DMD coating and on the corresponding microhardness distribution. Orientation relationships among austenite, martensite and cementite in the DMD coating followed the ones in conventional heat treated steels. As the laser specific energy decreased, cooling rate increased, and martensite peaks broadened and shifted to a lower Bragg's angle. Also martensite lattice parameters increased and austenite lattice parameters decreased due to the above parameter change.

  7. Influence of processing parameters on lattice parameters in laser deposited tool alloy steel

    International Nuclear Information System (INIS)

    Sun, G.F.; Bhattacharya, S.; Dinda, G.P.; Dasgupta, A.; Mazumder, J.

    2011-01-01

    Highlights: → Orientation relationships among phases in the DMD are given. → Martensite lattice parameters increased with laser specific energy. → Austenite lattice parameters decreased with laser specific energy. - Abstract: Laser aided direct metal deposition (DMD) has been used to form AISI 4340 steel coating on the AISI 4140 steel substrate. The microstructural property of the DMD coating was analyzed by means of scanning electron microscopy, transmission electron microscopy and X-ray diffractometry. Microhardness of the DMD was measured with a Vickers microhardness tester. Results indicate that DMD can be used to form dense AISI 4340 steel coatings on AISI 4140 steel substrate. The DMD coating is mainly composed of martensite and retained austenite. Consecutive thermal cycles have a remarkable effect on the microstructure of the plan view of the DMD coating and on the corresponding microhardness distribution. Orientation relationships among austenite, martensite and cementite in the DMD coating followed the ones in conventional heat treated steels. As the laser specific energy decreased, cooling rate increased, and martensite peaks broadened and shifted to a lower Bragg's angle. Also martensite lattice parameters increased and austenite lattice parameters decreased due to the above parameter change.

  8. Transport and deposition of plutonium-contaminated sediments by fluvial processes, Los Alamos Canyon, New Mexico

    International Nuclear Information System (INIS)

    Graf, W.L.

    1996-01-01

    Between 1945 and 1952 the development of nuclear weapons at Los Alamos National Laboratory, New Mexico, resulted in the disposal of plutonium into the alluvium of nearby Acid and (to a lesser degree) DP Canyons. The purpose of this paper is to explore the connection between the disposal sites and the main river, a 20 km link formed by the fluvial system of Acid, Pueblo, DP, and Los Alamos Canyons. Empirical data from 15 yr of annual sediment sampling throughout the canyon system has produced 458 observations of plutonium concentration in fluvial sediments. These data show that, overall, mean plutonium concentrations in fluvial sediment decline from 10,000 fCi/g near the disposal area to 100 fCi/g at the confluence of the canyon system and the Rio Grande. Simulations using a computer model for water, sediment, and plutonium routing in the canyon system show that discharges as large as the 25 yr event would fail to develop enough transport capacity to completely remove the contaminated sediments from Pueblo Canyon. Lesser flows would move some materials to the Rio Grande by remobilization of stored sediments. The simulations also show that the deposits and their contaminants have a predictable geography because they occur where stream power is low, hydraulic resistance is high, and the geologic and/or geomorphic conditions provide enough space for storage. 38 refs., 13 figs., 1 tab

  9. Experimentally Investigating the Effect of Temperature Differences in the Particle Deposition Process on Solar Photovoltaic (PV Modules

    Directory of Open Access Journals (Sweden)

    Yu Jiang

    2016-10-01

    Full Text Available This paper reports an experimental investigation of the dust particle deposition process on solar photovoltaic (PV modules with different surface temperatures by a heating plate to illustrate the effect of the temperature difference (thermophoresis between the module surface and the surrounding air on the dust accumulation process under different operating temperatures. In general, if the temperature of PV modules is increased, the energy conversion efficiency of the modules is decreased. However, in this study, it is firstly found that higher PV module surface temperature differences result in a higher energy output compared with those modules with lower temperature differences because of a reduced accumulation of dust particles. The measured deposition densities of dust particles were found to range from 0.54 g/m2 to 0.85 g/m2 under the range of experimental conditions and the output power ratios were found to increase from 0.861 to 0.965 with the increase in the temperature difference from 0 to 50 °C. The PV module with a higher temperature difference experiences a lower dust density because of the effect of the thermophoresis force arising from the temperature gradient between the module surface and its surrounding air. In addition, dust particles have a significant impact on the short circuit current, as well as the output power. However, the influence of particles on open circuit voltage can be negligible.

  10. Fabrication of a miniature diamond grinding tool using a hybrid process of micro-EDM and co-deposition

    International Nuclear Information System (INIS)

    Chen, Shun-Tong; Lai, Yun-Cheng; Liu, Ching-Chang

    2008-01-01

    A novel miniature diamond grinding tool usable for the precise micro-grinding of miniature parts is presented. A hybrid process that combines 'micro-EDM' with 'precision co-deposition' is proposed. The metal substrate is micro-EDMed to a 50 µm diameter and micro diamonds with 0–2 µm grains are 'electroformed' on the substrate surface, producing a miniature multilayered grinding tool. Nickel and diamond act as binders and cutters, respectively. A partition plate with an array of d