Archaeal Diversity and CO2 Fixers in Carbonate-/Siliciclastic-Rock Groundwater Ecosystems

Directory of Open Access Journals (Sweden)

Cassandre Sara Lazar

2017-01-01

Full Text Available Groundwater environments provide habitats for diverse microbial communities, and although Archaea usually represent a minor fraction of communities, they are involved in key biogeochemical cycles. We analysed the archaeal diversity within a mixed carbonate-rock/siliciclastic-rock aquifer system, vertically from surface soils to subsurface groundwater including aquifer and aquitard rocks. Archaeal diversity was also characterized along a monitoring well transect that spanned surface land uses from forest/woodland to grassland and cropland. Sequencing of 16S rRNA genes showed that only a few surface soil-inhabiting Archaea were present in the groundwater suggesting a restricted input from the surface. Dominant groups in the groundwater belonged to the marine group I (MG-I Thaumarchaeota and the Woesearchaeota. Most of the groups detected in the aquitard and aquifer rock samples belonged to either cultured or predicted lithoautotrophs (e.g., Thaumarchaeota or Hadesarchaea. Furthermore, to target autotrophs, a series of 13CO2 stable isotope-probing experiments were conducted using filter pieces obtained after filtration of 10,000 L of groundwater to concentrate cells. These incubations identified the SAGMCG Thaumarchaeota and Bathyarchaeota as groundwater autotrophs. Overall, the results suggest that the majority of Archaea on rocks are fixing CO2, while archaeal autotrophy seems to be limited in the groundwater.

Quantifying Groundwater Availability in Fractured Rock Aquifers of Northern Ugandan Refugee Settlements

Science.gov (United States)

Frederiks, R.; Lowry, C.; Mutiibwa, R.; Moisy, S.; Thapa, L.; Oriba, J.

2017-12-01

In the past two years, Uganda has witnessed an influx of nearly one million refugees who have settled in the sparsely populated northwestern region of the country. This rapid population growth has created high demand for clean water resources. Water supply has been unable to keep pace with demand because the fractured rock aquifers underlying the region often produce low yielding wells. To facilitate management of groundwater resources, it is necessary to quantify the spatial distribution of groundwater. In fractured rock aquifers, there is significant spatial variability in water storage because fractures must be both connected and abundant for water to be extracted in usable quantities. Two conceptual models were evaluated to determine the groundwater storage mechanism in the fractured crystalline bedrock aquifers of northwestern Uganda where by permeability is controlled by faulting, which opens up fractures in the bedrock, or weathering, which occurs when water dissolves components of rock. In order to test these two conceptual models, geologic well logs and available hydrologic data were collected and evaluated using geostatistical and numerical groundwater models. The geostatistical analysis focused on identifying spatially distributed patterns of high and low water yield. The conceptual models were evaluated numerically using four inverse groundwater MODFLOW models based on head and estimated flux targets. The models were based on: (1) the mapped bedrock units using an equivalent porous media approach (2) bedrock units with the addition of known fault zones (3) bedrock units with predicted units of deep weathering based on surface slopes, and (4) bedrock units with discrete faults and simulated weathered zones. Predicting permeable zones is vital for water well drilling in much of East Africa and South America where there is an abundance of both fractured rock and tectonic activity. Given that the population of these developing regions is growing, the demand

Processes of water rock interaction in the Turonian aquifer of Oum Er-Rabia Basin, Morocco

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Ettazarini, Said

2005-12-01

Possible water rock interaction processes, in the Moroccan basin of Oum Er-Rabia, were discussed by a geochemical study of groundwater from the Turonian limestone aquifer, the most important water resource in the region. Different types of water according to the classification of Piper were defined. Waters have shown an evolution from dominant CHO3 Ca Mg type through mixed to SO4 Cl Ca Mg type. The use of geochemical diagrams and chemical speciation modeling method has shown that water rock interaction is mainly controlled by carbonate and anhydrite dissolution, ion exchange and reverse ion exchange processes. Water rock equilibrium conditions are favorable for the precipitation of calcite, dolomite, kaolinite and magnesian smectite.

Heterogeneous redox conditions, arsenic mobility, and groundwater flow in a fractured-rock aquifer near a waste repository site in New Hampshire, USA

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Anthropogenic sources of carbon from landfill or waste leachate can promote reductive dissolution of in situ arsenic (As) and enhance the mobility of As in groundwater. Groundwater from residential-supply wells in a fractured crystalline-rock aquifer adjacent to a Superfund site ...

Analytical solutions for recession analyses of sloping aquifers - applicability on relict rock glaciers in alpine catchments

Science.gov (United States)

Pauritsch, Marcus; Birk, Steffen; Hergarten, Stefan; Kellerer-Pirklbauer, Andreas; Winkler, Gerfried

2014-05-01

Rock glaciers as aquifer systems in alpine catchments may strongly influence the hydrological characteristics of these catchments. Thus, they have a high impact on the ecosystem and potential natural hazards such as for example debris flow. Therefore, knowledge of the hydrodynamic processes, internal structure and properties of these aquifers is important for resource management and risk assessment. The investigation of such aquifers often turns out to be expensive and technically complicated because of their strongly limited accessibility. Analytical solutions of discharge recession provide a quick and easy way to estimate aquifer parameters. However, due to simplifying assumptions the validity of the interpretation is often questionable. In this study we compared results of an analytical solution of discharge recessions with results based on a numerical model. This was done in order to analyse the range of uncertainties and the applicability of the analytical method in alpine catchment areas. The research area is a 0.76 km² large catchment in the Seckauer Tauern Range, Austria. The dominant aquifer in this catchment is a rock glacier, namely the Schöneben Rock Glacier. This relict rock glacier (i.e. containing no permafrost at present) covers an area of 0.11 km² and is drained by one spring at the rock glacier front. The rock glacier consists predominantly of gneissic sediments (mainly coarse-grained, blocky at the surface) and extends from 1720 to 1905 m a.s.l.. Discharge of the rock glacier spring is automatically measured since 2002. Electric conductivity and water temperature is monitored since 2008. An automatic weather station was installed in 2011 in the central part of the catchment. Additionally data of geophysical surveys (refraction seismic and ground penetrating radar) have been used to analyse the base slope and inner structure of the rock glacier. The measured data are incorporated into a numerical model implemented in MODFLOW. The numerical

Variations in hydraulic conductivity with scale of measurement during aquifer tests in heterogeneous, porous carbonate rocks

Science.gov (United States)

Schulze-Makuch, Dirk; Cherkauer, Douglas S.

Previous studies have shown that hydraulic conductivity of an aquifer seems to increase as the portion of the aquifer tested increases. To date, such studies have all relied on different methods to determine hydraulic conductivity at each scale of interest, which raises the possibility that the observed increase in hydraulic conductivity is due to the measurement method, not to the scale. This study analyzes hydraulic conductivity with respect to scale during individual aquifer tests in porous, heterogeneous carbonate rocks in southeastern Wisconsin, USA. Results from this study indicate that hydraulic conductivity generally increases during an individual test as the volume of aquifer impacted increases, and the rate of this increase is the same as the rate of increase determined by using different measurement methods. Thus, scale dependence of hydraulic conductivity during single tests does not depend on the method of measurement. This conclusion is supported by 22 of 26 aquifer tests conducted in porous-flow-dominated carbonate units within the aquifer. Instead, scale dependency is probably caused by heterogeneities within the aquifer, a conclusion supported by digital simulation. All of the observed types of hydraulic-conductivity variations with scale during individual aquifer tests can be explained by a conceptual model of a simple heterogeneous aquifer composed of high-conductivity zones within a low-conductivity matrix. Résumé Certaines études ont montré que la conductivité hydraulique d'un aquifère semble augmenter en même temps que la partie testée de l'aquifère s'étend. Jusqu'à présent, ces études ont toutes reposé sur des méthodes de détermination de la conductivité hydraulique différentes pour chaque niveau d'échelle, ce qui a conduit à penser que l'augmentation observée de la conductivité hydraulique pouvait être due aux méthodes de mesure et non à l'effet d'échelle. Cette étude analyse la conductivité hydraulique par

Soil aquifer treatment of artificial wastewater under saturated conditions

KAUST Repository

Essandoh, H. M K; Tizaoui, Chedly; Mohamed, Mostafa H A; Amy, Gary L.; Brdjanovic, Damir

2011-01-01

A 2000 mm long saturated laboratory soil column was used to simulate soil aquifer treatment under saturated conditions to assess the removal of chemical and biochemical oxygen demand (COD and BOD), dissolved organic carbon (DOC), nitrogen

Hydrofracturing water boreholes in hard rock aquifers in Scotland

CSIR Research Space (South Africa)

Cobbing, J

2007-01-01

Full Text Available rural areas of the UK, low-productivity aquifers are an important resource for small public water supplies. Where a borehole in low-productivity crystalline rocks proves too low yielding for its designed purpose, hydrofracturing is a cost-effective means...

Hydrochemical processes in a shallow coal seam gas aquifer and its overlying stream–alluvial system: implications for recharge and inter-aquifer connectivity

International Nuclear Information System (INIS)

Duvert, Clément; Raiber, Matthias; Owen, Daniel D.R.; Cendón, Dioni I.; Batiot-Guilhe, Christelle; Cox, Malcolm E.

2015-01-01

Highlights: • Major ions and isotopes used to study inter-aquifer mixing in a shallow CSG setting. • Considerable heterogeneity in the water composition of the coal-bearing aquifer. • Rapid recharge of the coal-bearing aquifer through highly fractured igneous rocks. • Potential mixing between the coal-bearing aquifer and downstream alluvial aquifer. • Need to consider the seasonal influences on inter-aquifer mixing in CSG settings. - Abstract: In areas of potential coal seam gas (CSG) development, understanding interactions between coal-bearing strata and adjacent aquifers and streams is of highest importance, particularly where CSG formations occur at shallow depth. This study tests a combination of hydrochemical and isotopic tracers to investigate the transient nature of hydrochemical processes, inter-aquifer mixing and recharge in a catchment where the coal-bearing aquifer is in direct contact with the alluvial aquifer and surface drainage network. A strong connection was observed between the main stream and underlying alluvium, marked by a similar evolution from fresh Ca–Mg–HCO 3 waters in the headwaters towards brackish Ca–Na–Cl composition near the outlet of the catchment, driven by evaporation and transpiration. In the coal-bearing aquifer, by contrast, considerable site-to-site variations were observed, although waters generally had a Na–HCO 3 –Cl facies and high residual alkalinity values. Increased salinity was controlled by several coexisting processes, including transpiration by plants, mineral weathering and possibly degradation of coal organic matter. Longer residence times and relatively enriched carbon isotopic signatures of the downstream alluvial waters were suggestive of potential interactions with the shallow coal-bearing aquifer. The examination of temporal variations in deuterium excess enabled detection of rapid recharge of the coal-bearing aquifer through highly fractured igneous rocks, particularly at the catchment

Uranium in waters and aquifer rocks at the Nevada Test Site, Nye County, Nevada

International Nuclear Information System (INIS)

Zielinski, R.A.; Rosholt, J.N.

1978-01-01

Previous chemical, geological, and hydrological information describing the physical and chemical environment of the Nevada Test Site has been combined with new radiochemical and isotope data for water and rock samples in order to explain the behavior of uranium during alteration of thick sequences of rhyolitic volcanic rocks and associated volcanielastic sediments. A model is proposed in which uranium mobility is controlled by two competing processes. Uranium is liberated from the volcanic rocks through dissolution of the glassy constituents and is carried in solution as a uranyl carbonate complex. Uranium is subsequently removed from solution by adsorption on secondary oxides of iron, titanium, and manganese, as observed in fission-track maps of aquifer rocks. The model explains the poor correlation of dissolved uranium with depth within tuffaceous sequences in which percolation of ground water is predominantly downward. Good positive correlation of dissolved uranium with dissolved Na, total dissolved solids, and total carbonate supports the glass dissolution model, while inverse correlation of dissolved uranium with 234 U/ 238 U ratios of water implies uranium is being absorbed by a relatively insoluble, surficial phase. Alpha radioactivity of Test Site water is primarily caused by high 234 U contents, and beta activity is highly correlated with dissolved K ( 40 K). Smallamounts of dissolved radium, 216 Pb, and 210 Po are present but no evidence was found for alpha activity sources related to nuclear testing (Pu, 235 U). A filtered but unacidified carbonate solution of uranium was found to be stable (+-10 percent of original U concentration) for years when stored in acid-washed polyethylene bottles. 5 tables, 2 figs

Analysis of mineral trapping for CO{sub 2} disposal in deep aquifers

Energy Technology Data Exchange (ETDEWEB)

Xu, Tianfu; Apps, John A.; Pruess, Karsten

2001-07-20

CO{sub 2} disposal into deep aquifers has been suggested as a potential means whereby atmospheric emissions of greenhouse gases may be reduced. However, our knowledge of the geohydrology, geochemistry, geophysics, and geomechanics of CO{sub 2} disposal must be refined if this technology is to be implemented safely, efficiently, and predictably. As a prelude to a fully coupled treatment of physical and chemical effects of CO{sub 2} injection, we have analyzed the impact of CO{sub 2} immobilization through carbonate precipitation. A survey of all major classes of rock-forming minerals, whose alteration would lead to carbonate precipitation, indicated that very few minerals are present in sufficient quantities in aquifer host rocks to permit significant sequestration of CO{sub 2}. We performed batch reaction modeling of the geochemical evolution of three different aquifer mineralogies in the presence of CO{sub 2} at high pressure. Our modeling considered (1) redox processes that could be important in deep subsurface environments, (2) the presence of organic matter, (3) the kinetics of chemical interactions between the host rock minerals and the aqueous phase, and (4) CO{sub 2} solubility dependence on pressure, temperature and salinity of the system. The geochemical evolution under both natural background and CO{sub 2} injection conditions was evaluated. In addition, changes in porosity were monitored during the simulations. Results indicate that CO{sub 2} sequestration by matrix minerals varies considerably with rock type. Under favorable conditions the amount of CO{sub 2} that may be sequestered by precipitation of secondary carbonates is comparable with and can be larger than the effect of CO{sub 2} dissolution in pore waters. The precipitation of ankerite and siderite is sensitive to the rate of reduction of ferric mineral precursors such as glauconite, which in turn is dependent on the reactivity of associated organic material. The accumulation of carbonates in

Numerical simulation of CO2 disposal by mineral trapping in deep aquifers

International Nuclear Information System (INIS)

Xu Tianfu; Apps, John A.; Pruess, Karsten

2004-01-01

Carbon dioxide disposal into deep aquifers is a potential means whereby atmospheric emissions of greenhouse gases may be reduced. However, our knowledge of the geohydrology, geochemistry, geophysics, and geomechanics of CO 2 disposal must be refined if this technology is to be implemented safely, efficiently, and predictably. As a prelude to a fully coupled treatment of physical and chemical effects of CO 2 injection, the authors have analyzed the impact of CO 2 immobilization through carbonate mineral precipitation. Batch reaction modeling of the geochemical evolution of 3 different aquifer mineral compositions in the presence of CO 2 at high pressure were performed. The modeling considered the following important factors affecting CO 2 sequestration: (1) the kinetics of chemical interactions between the host rock minerals and the aqueous phase, (2) CO 2 solubility dependence on pressure, temperature and salinity of the system, and (3) redox processes that could be important in deep subsurface environments. The geochemical evolution under CO 2 injection conditions was evaluated. In addition, changes in porosity were monitored during the simulations. Results indicate that CO 2 sequestration by matrix minerals varies considerably with rock type. Under favorable conditions the amount of CO 2 that may be sequestered by precipitation of secondary carbonates is comparable with and can be larger than the effect of CO 2 dissolution in pore waters. The precipitation of ankerite and siderite is sensitive to the rate of reduction of Fe(III) mineral precursors such as goethite or glauconite. The accumulation of carbonates in the rock matrix leads to a considerable decrease in porosity. This in turn adversely affects permeability and fluid flow in the aquifer. The numerical experiments described here provide useful insight into sequestration mechanisms, and their controlling geochemical conditions and parameters

Analysis of mineral trapping for CO(sub 2) disposal in deep aquifers; TOPICAL

International Nuclear Information System (INIS)

Xu, Tianfu; Apps, John A.; Pruess, Karsten

2001-01-01

CO(sub 2) disposal into deep aquifers has been suggested as a potential means whereby atmospheric emissions of greenhouse gases may be reduced. However, our knowledge of the geohydrology, geochemistry, geophysics, and geomechanics of CO(sub 2) disposal must be refined if this technology is to be implemented safely, efficiently, and predictably. As a prelude to a fully coupled treatment of physical and chemical effects of CO(sub 2) injection, we have analyzed the impact of CO(sub 2) immobilization through carbonate precipitation. A survey of all major classes of rock-forming minerals, whose alteration would lead to carbonate precipitation, indicated that very few minerals are present in sufficient quantities in aquifer host rocks to permit significant sequestration of CO(sub 2). We performed batch reaction modeling of the geochemical evolution of three different aquifer mineralogies in the presence of CO(sub 2) at high pressure. Our modeling considered (1) redox processes that could be important in deep subsurface environments, (2) the presence of organic matter, (3) the kinetics of chemical interactions between the host rock minerals and the aqueous phase, and (4) CO(sub 2) solubility dependence on pressure, temperature and salinity of the system. The geochemical evolution under both natural background and CO(sub 2) injection conditions was evaluated. In addition, changes in porosity were monitored during the simulations. Results indicate that CO(sub 2) sequestration by matrix minerals varies considerably with rock type. Under favorable conditions the amount of CO(sub 2) that may be sequestered by precipitation of secondary carbonates is comparable with and can be larger than the effect of CO(sub 2) dissolution in pore waters. The precipitation of ankerite and siderite is sensitive to the rate of reduction of ferric mineral precursors such as glauconite, which in turn is dependent on the reactivity of associated organic material. The accumulation of carbonates in

Nutrient Removal during Stormwater Aquifer Storage and Recovery in an Anoxic Carbonate Aquifer.

Science.gov (United States)

Vanderzalm, Joanne L; Page, Declan W; Dillon, Peter J; Barry, Karen E; Gonzalez, Dennis

2018-03-01

Stormwater harvesting coupled to managed aquifer recharge (MAR) provides a means to use the often wasted stormwater resource while also providing protection of the natural and built environment. Aquifers can act as a treatment barrier within a multiple-barrier approach to harvest and use urban stormwater. However, it remains challenging to assess the treatment performance of a MAR scheme due to the heterogeneity of aquifers and MAR operations, which in turn influences water treatment processes. This study uses a probabilistic method to evaluate aquifer treatment performance based on the removal of total organic C (TOC), N, and P during MAR with urban stormwater in an anoxic carbonate aquifer. Total organic C, N, and P are represented as stochastic variables and described by probability density functions (PDFs) for the "injectant" and "recovery"; these injectant and recovery PDFs are used to derive a theoretical MAR removal efficiency PDF. Four long-term MAR sites targeting one of two tertiary carbonate aquifers (T1 and T2) were used to describe the nutrient removal efficiencies. Removal of TOC and total N (TN) was dominated by redox processes, with median removal of TOC between 50 and 60% at all sites and TN from 40 to 50% at three sites with no change at the fourth. Total P removal due to filtration and sorption accounted for median removal of 29 to 53%. Thus, the statistical method was able to characterize the capacity of the anoxic carbonate aquifer treatment barrier for nutrient removal, which highlights that aquifers can be an effective long-term natural treatment option for management of water quality, as well as storage of urban stormwater. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Element mobilization and immobilization from carbonate rocks between CO 2 storage reservoirs and the overlying aquifers during a potential CO 2 leakage

Energy Technology Data Exchange (ETDEWEB)

Lawter, Amanda R.; Qafoku, Nikolla P.; Asmussen, R. Matthew; Kukkadapu, Ravi K.; Qafoku, Odeta; Bacon, Diana H.; Brown, Christopher F.

2018-04-01

Despite the numerous studies on changes within the reservoir following CO2 injection and the effects of CO2 release into overlying aquifers, little or no literature is available on the effect of CO2 release on rock between the storage reservoirs and subsurface. To address this knowledge gap, relevant rock materials, temperatures and pressures were used to study mineralogical and elemental changes in this intermediate zone. After rocks reacted with CO2, liquid analysis showed an increase of major elements (e.g., Ca, and Mg) and variable concentrations of potential contaminants (e.g., Sr and Ba); lower concentrations were observed in N2 controls. In experiments with As/Cd and/or organic spikes, representing potential contaminants in the CO2 plume originating in the storage reservoir, most or all of these contaminants were removed from the aqueous phase. SEM and Mössbauer spectroscopy results showed the formation of new minerals and Fe oxides in some CO2-reacted samples, indicating potential for contaminant removal through mineral incorporation or adsorption onto Fe oxides. These experiments show the interactions between the CO2-laden plume and the rock between storage reservoirs and overlying aquifers have the potential to affect the level of risk to overlying groundwater, and should be considered during site selection and risk evaluation.

Inverse Modeling of Water-Rock-CO2 Batch Experiments: Potential Impacts on Groundwater Resources at Carbon Sequestration Sites.

Science.gov (United States)

Yang, Changbing; Dai, Zhenxue; Romanak, Katherine D; Hovorka, Susan D; Treviño, Ramón H

2014-01-01

This study developed a multicomponent geochemical model to interpret responses of water chemistry to introduction of CO2 into six water-rock batches with sedimentary samples collected from representative potable aquifers in the Gulf Coast area. The model simulated CO2 dissolution in groundwater, aqueous complexation, mineral reactions (dissolution/precipitation), and surface complexation on clay mineral surfaces. An inverse method was used to estimate mineral surface area, the key parameter for describing kinetic mineral reactions. Modeling results suggested that reductions in groundwater pH were more significant in the carbonate-poor aquifers than in the carbonate-rich aquifers, resulting in potential groundwater acidification. Modeled concentrations of major ions showed overall increasing trends, depending on mineralogy of the sediments, especially carbonate content. The geochemical model confirmed that mobilization of trace metals was caused likely by mineral dissolution and surface complexation on clay mineral surfaces. Although dissolved inorganic carbon and pH may be used as indicative parameters in potable aquifers, selection of geochemical parameters for CO2 leakage detection is site-specific and a stepwise procedure may be followed. A combined study of the geochemical models with the laboratory batch experiments improves our understanding of the mechanisms that dominate responses of water chemistry to CO2 leakage and also provides a frame of reference for designing monitoring strategy in potable aquifers.

14C measurements in aquifers with methane

International Nuclear Information System (INIS)

Barker, J.F.; Fritz, P.; Brown, R.M.

1978-01-01

A survey of various groundwater systems indicates that methane is a common trace constituent and occasionally a major carbon species in groundwaters. Thermocatalytic methane had delta 13 CCH 4 > -45% 0 and microbially-produced or biogenic methane had delta 13 CCH 4 0 . Groundwaters containing significant biogenic methane had abnormally heavy delta 13 C values for the inorganic carbon. Thermocatalytic methane had no apparent effect on the inorganic carbon. Because methanogenesis seriously affects the carbon isotope geochemistry of groundwaters, the correction of raw 14 C ages of affected groundwaters must consider these effects. Conceptual models are developed which adjust the 14 C activity of the groundwater for the effects of methanogenesis and for the dilution of carbon present during infiltration by simple dissolution of rock carbonate. These preliminary models are applied to groundwaters from the Alliston sand aquifer where methanogenesis has affected most samples. In this system, methanogenic bacteria using organic matter present in the aquifer matrix as substrate, have added inorganic carbon to the groundwater which has initiated further carbonate rock dissolution. These processes have diluted the inorganic carbon 14 C activity. (orig.) [de

Hydrogeology of the Besparmak (Pentadactilos) Mountains (TRNC) Karstic Aquifer

International Nuclear Information System (INIS)

Erduran, B.; Goekmenoglu, O.; Keskin, E.

2002-01-01

The Besparmak Mountains are located on the Nothern part of North Cyprus and lay paralel to the sea, 160 km 2 in length 10 km in width. Karstification, potential constituent and the hydro-dynamic structure of the Mesosoic aged carbonate rocks, located at high altitudes of the Besparmak Mountains have been investigated in this study. The Mesosoic aged carbonate rocks; dolomite, dolomitic limestones and recrytallized limestones are yhe units suitable for karstification in the exploration area. Surface area of the carbonate rocks is 84 km 2 . Chemical and isotopic samples have been collected, groundwater fluctuations have been observed and investigation wells have been openned for the definition of the karst aquifer. As the result of the geological, hydrogeological, drilling and geophysical investigations it was found that the Besparmak Mountains Karst Aquifer was formed of independent karstic systems and a total dynamic groundwater potential of aproximately 9 x 10 6 m 3 /year for these systems has been determined

The typology of Irish hard-rock aquifers based on an integrated hydrogeological and geophysical approach

Science.gov (United States)

Comte, Jean-Christophe; Cassidy, Rachel; Nitsche, Janka; Ofterdinger, Ulrich; Pilatova, Katarina; Flynn, Raymond

2012-12-01

Groundwater flow in hard-rock aquifers is strongly controlled by the characteristics and distribution of structural heterogeneity. A methodology for catchment-scale characterisation is presented, based on the integration of complementary, multi-scale hydrogeological, geophysical and geological approaches. This was applied to three contrasting catchments underlain by metamorphic rocks in the northern parts of Ireland (Republic of Ireland and Northern Ireland, UK). Cross-validated surface and borehole geophysical investigations confirm the discontinuous overburden, lithological compartmentalisation of the bedrock and important spatial variations of the weathered bedrock profiles at macro-scale. Fracture analysis suggests that the recent (Alpine) tectonic fabric exerts strong control on the internal aquifer structure at meso-scale, which is likely to impact on the anisotropy of aquifer properties. The combination of the interpretation of depth-specific hydraulic-test data with the structural information provided by geophysical tests allows characterisation of the hydrodynamic properties of the identified aquifer units. Regionally, the distribution of hydraulic conductivities can be described by inverse power laws specific to the aquifer litho-type. Observed groundwater flow directions reflect this multi-scale structure. The proposed integrated approach applies widely available investigative tools to identify key dominant structures controlling groundwater flow, characterising the aquifer type for each catchment and resolving the spatial distribution of relevant aquifer units and associated hydrodynamic parameters.

Groundwater quality in the Piedmont and Blue Ridge crystalline-rock aquifers, eastern United States

Science.gov (United States)

Lindsey, Bruce

2017-12-07

Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water (Burow and Belitz, 2014). The Piedmont and Blue Ridge crystalline-rock aquifers constitute one of the important areas being evaluated.

Thermo-mechanical Properties of Upper Jurassic (Malm) Carbonate Rock Under Drained Conditions

Science.gov (United States)

Pei, Liang; Blöcher, Guido; Milsch, Harald; Zimmermann, Günter; Sass, Ingo; Huenges, Ernst

2018-01-01

The present study aims to quantify the thermo-mechanical properties of Neuburger Bankkalk limestone, an outcrop analog of the Upper Jurassic carbonate formation (Germany), and to provide a reference for reservoir rock deformation within future enhanced geothermal systems located in the Southern German Molasse Basin. Experiments deriving the drained bulk compressibility C were performed by cycling confining pressure p c between 2 and 50 MPa at a constant pore pressure p p of 0.5 MPa after heating the samples to defined temperatures between 30 and 90 °C. Creep strain was then measured after each loading and unloading stage, and permeability k was obtained after each creep strain measurement. The drained bulk compressibility increased with increasing temperature and decreased with increasing differential pressure p d = p c - p p showing hysteresis between the loading and unloading stages above 30 °C. The apparent values of the indirectly calculated Biot coefficient α ind containing contributions from inelastic deformation displayed the same temperature and pressure dependencies. The permeability k increased immediately after heating and the creep rates were also temperature dependent. It is inferred that the alteration of the void space caused by temperature changes leads to the variation of rock properties measured under isothermal conditions while the load cycles applied under isothermal conditions yield additional changes in pore space microstructure. The experimental results were applied to a geothermal fluid production scenario to constrain drawdown and time-dependent effects on the reservoir, overall, to provide a reference for the hydromechanical behavior of geothermal systems in carbonate, and more specifically, in Upper Jurassic lithologies.

Evaluation of Microstructural Parameters of Reservoir Rocks of the Guarani Aquifer by Analysis of Images Obtained by X- Ray Microtomography

Science.gov (United States)

Fernandes, J. S.; Lima, F. A.; Vieira, S. F.; Reis, P. J.; Appoloni, C. R.

2015-07-01

Microstructural parameters evaluation of porous materials, such as, rocks reservoir (water, petroleum, gas...), it is of great importance for several knowledge areas. In this context, the X-ray microtomography (μ-CT) has been showing a technical one quite useful for the analysis of such rocks (sandstone, limestone and carbonate), object of great interest of the petroleum and water industries, because it facilitates the characterization of important parameters, among them, porosity, permeability, grains or pore size distribution. The X-ray microtomography is a non-destructive method, that besides already facilitating the reuse of the samples analyzed, it also supplies images 2-D and 3-D of the sample. In this work samples of reservoir rock of the Guarani aquifer will be analyzed, given by the company of perforation of wells artesian Blue Water, in the municipal district of Videira, Santa Catarina, Brazil. The acquisition of the microtomographys data of the reservoir rocks was accomplished in a Skyscan 1172 μ-CT scanner, installed in Applied Nuclear Physics Laboratory (LFNA) in the State University of Londrina (UEL), Paraná, Brazil. In this context, this work presents the microstructural characterization of reservoir rock sample of the Guarani aquifer, analyzed for two space resolutions, 2.8 μm and 4.8 μm, where determined average porosity was 28.5% and 21.9%, respectively. Besides, we also determined the pore size distribution for both resolutions. Two 3-D images were generated of this sample, one for each space resolution, in which it is possible to visualize the internal structure of the same ones.

Evaluation of Microstructural Parameters of Reservoir Rocks of the Guarani Aquifer by Analysis of Images Obtained by X- Ray Microtomography

International Nuclear Information System (INIS)

Fernandes, J S; Lima, F A; Vieira, S F; Reis, P J; Appoloni, C R

2015-01-01

Microstructural parameters evaluation of porous materials, such as, rocks reservoir (water, petroleum, gas...), it is of great importance for several knowledge areas. In this context, the X-ray microtomography (μ-CT) has been showing a technical one quite useful for the analysis of such rocks (sandstone, limestone and carbonate), object of great interest of the petroleum and water industries, because it facilitates the characterization of important parameters, among them, porosity, permeability, grains or pore size distribution. The X-ray microtomography is a non-destructive method, that besides already facilitating the reuse of the samples analyzed, it also supplies images 2-D and 3-D of the sample. In this work samples of reservoir rock of the Guarani aquifer will be analyzed, given by the company of perforation of wells artesian Blue Water, in the municipal district of Videira, Santa Catarina, Brazil. The acquisition of the microtomographys data of the reservoir rocks was accomplished in a Skyscan 1172 μ-CT scanner, installed in Applied Nuclear Physics Laboratory (LFNA) in the State University of Londrina (UEL), Paraná, Brazil. In this context, this work presents the microstructural characterization of reservoir rock sample of the Guarani aquifer, analyzed for two space resolutions, 2.8 μm and 4.8 μm, where determined average porosity was 28.5% and 21.9%, respectively. Besides, we also determined the pore size distribution for both resolutions. Two 3-D images were generated of this sample, one for each space resolution, in which it is possible to visualize the internal structure of the same ones. (paper)

Hydrogeological impact of fault zones on a fractured carbonate aquifer, Semmering (Austria)

Science.gov (United States)

Mayaud, Cyril; Winkler, Gerfried; Reichl, Peter

2015-04-01

Fault zones are the result of tectonic processes and are geometrical features frequently encountered in carbonate aquifer systems. They can hamper the fluid migration (hydrogeological barriers), propagate the movement of fluid (draining conduits) or be a combination of both processes. Numerical modelling of fractured carbonate aquifer systems is strongly bound on the knowledge of a profound conceptual model including geological and tectonic settings such as fault zones. In further consequence, numerical models can be used to evaluate the conceptual model and its introduced approximations. The study was conducted in a fractured carbonate aquifer built up by permomesozoic dolo/limestones of the Semmering-Wechsel complex in the Eastern Alps (Austria). The aquifer has an assumed thickness of about 200 m and dips to the north. It is covered by a thin quartzite layer and a very low permeable layer of quartz-phyllite having a thickness of up to several hundred meters. The carbonate layer crops out only in the southern part of the investigation area, where it receives autogenic recharge. The geological complexity affects some uncertainties related to the extent of the model area, which was determined to be about 15 km². Three vertical fault zones cross the area approximately in a N-S direction. The test site includes an infrastructural pilot tunnel gallery of 4.3 km length with two pumping stations, respectively active since August 1997 and June 1998. The total pumping rate is about 90 l/s and the drawdown data were analysed analytically, providing a hydraulic conductivity of about 5E-05 m/s for the carbonate layer. About 120 m drawdown between the initial situation and situation with pumping is reported by piezometers. This led to the drying up of one spring located at the southern border of the carbonates. A continuum approach using MODFLOW-2005 was applied to reproduce numerically the observed aquifer behaviour and investigate the impact of the three fault zones. First

Chemical analysis of carbonates and carbonate rocks by atomic absorption analysis

Energy Technology Data Exchange (ETDEWEB)

Tardon, S

1981-01-01

Evaluates methods of determining chemical composition of rocks surrounding black coal seams. Carbonate rock samples were collected in the Ostrava-Karvina coal mines. Sampling methods are described. Determination of the following elements and compounds in carbonate rocks is discussed: calcium, magnesium, iron, manganese, barium, silicon, aluminium, titanium, sodium, potassium, sulfur trioxide, phosphorus pentoxide, water and carbon dioxide. Proportion of compounds insoluble in water in the investigated rocks is also determined. Most of the elements are determined by means of atomic absorption analysis. Phosphorus is also determined by atomic absorption analysis. Other compounds are determined gravimetrically. The described procedure permits weight of a rock sample to be reduced to 0.5 g without reducing analysis accuracy. The results of determining carbonate rock components by X-ray analysis and by chemical analysis are compared. Equipment used for atomic absorption analysis is characterized (the 503 Perkin-Elmer and the CF-4 Optica-Milano spectrophotometers). The analyzed method for determining carbonate rock permits more accurate classification of rocks surrounding coal seams and rock impurities in run-of-mine coal. (22 refs.) (In Czech)

Hydrogeologic characterization of a fractured granitic rock aquifer, Raymond, California

Energy Technology Data Exchange (ETDEWEB)

Cohen, Andrew J.B. [Univ. of California, Berkeley, CA (United States)

1993-10-01

The hydrogeologic properties of a shallow, fractured granitic rock aquifer in the foothills of the Sierra Nevada, California were investigated via the analysis of borehole geophysical logs and pumping tests. The drawdowns produced during these tests are not indicative of any simple conceptual aquifer model, and borehole logs show that the granite is intensely fractured. These observations are suggestive of a complex fracture-flow geometry which is extremely difficult to decipher. However, through the measurement of orientations of individual subsurface fractures from acoustic televiewer logs, and correlation between particular fractures and electrical resistivity and thermal-pulse flowmeter logs, it was found that the aquifer is, in general, comprised of two subhorizontal and nearly parallel zones of unloading fractures. Downhole flowmeter measurements taken in several wells provide further evidence for the inferred dual-layer structure of the aquifer, as well as yield quantitative measures of the contribution of flow from each zone. Analysis of drawdowns in pumped wells reveals that there are zones of relatively high transmissivity immediately around them. It was found that these properties, as well as a nearby zone of lower transmissivity, can account for their observed drawdowns. A numerical model was constructed to test whether these major heterogeneities could also account for the drawdowns in observation wells. This stepwise analysis of both the geophysical and hydrological data resulted in the formulation of a conceptual model of the aquifer which is consistent with observations, and which can account for its behavior when subjected to pumping.

Tracing groundwater with low-level detections of halogenated VOCs in a fractured carbonate-rock aquifer, Leetown Science Center, West Virginia, USA

Science.gov (United States)

Plummer, Niel; Sibrell, Philip L.; Casile, Gerolamo C.; Busenberg, Eurybiades; Hunt, Andrew G.; Schlosser, Peter

2013-01-01

Measurements of low-level concentrations of halogenated volatile organic compounds (VOCs) and estimates of groundwater age interpreted from 3H/3He and SF6 data have led to an improved understanding of groundwater flow, water sources, and transit times in a karstic, fractured, carbonate-rock aquifer at the Leetown Science Center (LSC), West Virginia. The sum of the concentrations of a set of 16 predominant halogenated VOCs (TDVOC) determined by gas chromatography with electron-capture detector (GC–ECD) exceeded that possible for air–water equilibrium in 34 of the 47 samples (median TDVOC of 24,800 pg kg−1), indicating that nearly all the water sampled in the vicinity of the LSC has been affected by addition of halogenated VOCs from non-atmospheric source(s). Leakage from a landfill that was closed and sealed nearly 20 a prior to sampling was recognized and traced to areas east of the LSC using low-level detection of tetrachloroethene (PCE), methyl chloride (MeCl), methyl chloroform (MC), dichlorodifluoromethane (CFC-12), and cis-1,2-dichloroethene (cis-1,2-DCE). Chloroform (CHLF) was the predominant VOC in water from domestic wells surrounding the LSC, and was elevated in groundwater in and near the Fish Health Laboratory at the LSC, where a leak of chlorinated water occurred prior to 2006. The low-level concentrations of halogenated VOCs did not exceed human or aquatic-life health criteria, and were useful in providing an awareness of the intrinsic susceptibility of the fractured karstic groundwater system at the LSC to non-atmospheric anthropogenic inputs. The 3H/3He groundwater ages of spring discharge from the carbonate rocks showed transient behavior, with ages averaging about 2 a in 2004 following a wet climatic period (2003–2004), and ages in the range of 4–7 a in periods of more average precipitation (2008–2009). The SF6 and CFC-12 data indicate older water (model ages of 10s of years or more) in the low-permeability shale of the Martinsburg

Lithological and hydrological influences on ground-water composition in a heterogeneous carbonate-clay aquifer system

Science.gov (United States)

Kauffman, S.J.; Herman, J.S.; Jones, B.F.

1998-01-01

The influence of clay units on ground-water composition was investigated in a heterogeneous carbonate aquifer system of Miocene age in southwest Florida, known as the Intermediate aquifer system. Regionally, the ground water is recharged inland, flows laterally and to greater depths in the aquifer systems, and is discharged vertically upward at the saltwater interface along the coast. A depth profile of water composition was obtained by sampling ground water from discrete intervals within the permeable carbonate units during coring and by squeezing pore water from a core of the less-permeable clay layers. A normative salt analysis of solute compositions in the water indicated a marine origin for both types of water and an evolutionary pathway for the clay water that involves clay diagenesis. The chemical composition of the ground water in the carbonate bedrock is significantly different from that of the pore water in the clay layers. Dissolution of clays and opaline silica results in high silica concentrations relative to water in other parts of the Intermediate aquifer system. Water enriched in chloride relative to the overlying and underlying ground water recharges the aquifer inland where the confining clay layer is absent, and it dissolves carbonate and silicate minerals and reacts with clays along its flow path, eventually reaching this coastal site and resulting in the high chloride and silica concentrations observed in the middle part of the Intermediate aquifer system. Reaction-path modeling suggests that the recharging surficial water mixes with sulfate-rich water upwelling from the Upper Floridan aquifer, and carbonate mineral dissolution and precipitation, weathering and exchange reactions, clay mineral diagenesis, clay and silica dissolution, organic carbon oxidation, and iron and sulfate reduction result in the observed water compositions.A study was conducted to clarify the influence of clay units on ground-water composition in a heterogeneous

Karst connections between unconfined aquifers and the Upper Floridan aquifer in south Georgia: geophysical evidence and hydrogeological models

Science.gov (United States)

Thieme, D. M.; Denizman, C.

2011-12-01

Buried karst features in sedimentary rocks of the south Georgia Coastal Plain present a challenge for hydrogeological models of recharge and confined flow within the underlying Upper Floridan aquifer. The Withlacoochee River, the trunk stream for the area, frequently disappears into subsurface caverns as it makes its way south to join the Suwannee River in northern Florida. The Withlacoochee also receives inputs from small ponds and bays which in turn receive spring and seep groundwater inputs. We have mapped karst topography at the "top of rock" using ground-penetrating radar (GPR). Up to seven meters of relief is indicated for the paleotopography on Miocene to Pliocene rocks, contrasting with the more subdued relief of the modern landscape. Current stratigraphic and hydrogeological reconstructions do not incorporate this amount of relief or lateral variation in the confining beds. One "pipe" which is approximately four meters in diameter is being mapped in detail. We have field evidence at this location for rapid movement of surficial pond and river water with a meteoric signature through several separate strata of sedimentary rock into an aquifer in the Hawthorn formation. We use our geophysical and hydrological field evidence to constrain quantitative hydrogeological models for the flow rates into and out of both this upper aquifer and the underlying Upper Floridan aquifer, which is generally considered to be confined by the clays of the Hawthorn.

An analytical solution for modeling thermal energy transfer in a confined aquifer system

Science.gov (United States)

Shaw-Yang, Yang; Hund-der, Yeh

2008-12-01

A mathematical model is developed for simulating the thermal energy transfer in a confined aquifer with different geological properties in the underlying and overlying rocks. The solutions for temperature distributions in the aquifer, underlying rock, and overlying rock are derived by the Laplace transforms and their corresponding time-domain solutions are evaluated by the modified Crump method. Field data adopted from the literature are used as examples to demonstrate the applicability of the solutions in modeling the heat transfer in an aquifer thermal energy storage (ATES) system. The results show that the aquifer temperature increases with time, injection flow rate, and water temperature. However, the temperature decreases with increasing radial and vertical distances. The heat transfer in the rocks is slow and has an effect on the aquifer temperature only after a long period of injection time. The influence distance depends on the aquifer physical and thermal properties, injection flow rate, and injected water temperature. A larger value of thermal diffusivity or injection flow rate will result in a longer influence distance. The present solution can be used as a tool for designing the heat injection facilities for an ATES system.

SAR interferometry monitoring of subsidence in a detritic basin related to water depletion in the underlying confined carbonate aquifer (Torremolinos, southern Spain).

Science.gov (United States)

Ruiz-Constán, A; Ruiz-Armenteros, A M; Martos-Rosillo, S; Galindo-Zaldívar, J; Lazecky, M; García, M; Sousa, J J; Sanz de Galdeano, C; Delgado-Blasco, J M; Jiménez-Gavilán, P; Caro-Cuenca, M; Luque-Espinar, J A

2018-04-30

This research underlines the need to improve water management policies for areas linked to confined karstic aquifers subjected to intensive exploitation, and to develop additional efforts towards monitoring their subsidence evolution. We analyze subsidence related to intensive use of groundwater in a confined karstic aquifer, through the use of the InSAR technique, by the southern coast of Spain (Costa del Sol). Carbonates are overlain by an unconfined detritic aquifer with interlayered high transmissivity rocks, in connection with the Mediterranean Sea, where the water level is rather stable. Despite this, an accumulated deformation in the line-of-sight (LOS) direction greater than -100 mm was observed by means of the ERS-1/2 (1992-2000) and Envisat (2003-2009) satellite SAR sensors. During this period, the Costa del Sol experienced a major population increase due to the expansion of the tourism industry, with the consequent increase in groundwater exploitation. The maximum LOS displacement rates recorded during both time spans are respectively -6 mm/yr and -11 mm/yr, respectively. During the entire period, there was an accumulated descent of the confined water level of 140 m, and several fluctuations of more than 80 m correlating with the subsidence trend observed for the whole area. Main sedimentary depocenters (up to 800 m), revealed by gravity prospecting, partly coincide with areas of subsidence maxima; yet ground deformation is also influenced by other factors, the main ones being the fine-grained facies distribution and rapid urbanization due to high touristic pressure. Copyright © 2018 Elsevier B.V. All rights reserved.

Summary of three dimensional pump testing of a fractured rock aquifer in the western Siberian Basin

International Nuclear Information System (INIS)

Nichols, R.L.; Looney, B.B.; Eddy-Dilek, C.A.; Drozhko, E.G.; Glalolenko, Y.V.; Mokrov, Y.G.; Ivanov, I.A.; Glagolev, A.V.; Vasil'kova, N.A.

1996-01-01

A group of scientists from the Savannah River Technology Center and Russia successfully completed a 17 day field investigation of a fractured rock aquifer at the MAYAK PA nuclear production facility in Russia. The test site is located in the western Siberian Basin near the floodplain of the Mishelyak river. The fractured rock aquifer is composed of orphyrites, tuff, tuffbreccia and lava and is overlain by 0.5--12 meters of elluvial and alluvial sediments. A network of 3 uncased wells (176, 1/96, and 2/96) was used to conduct the tests. Wells 176 and 2/96 were used as observation wells and the centrally located well 1/96 was used as the pumping well. Six packers were installed and inflated in each of the observation wells at a depth of up to 85 meters. The use of 6 packers in each well resulted in isolating 7 zones for monitoring. The packers were inflated to different pressures to accommodate the increasing hydrostatic pressure. A straddle packer assembly was installed in the pumping well to allow testing of each of the individual zones isolated in the observation wells. A constant rate pumping test was run on each of the 7 zones. The results of the pumping tests are included in Appendix A. The test provided new information about the nature of the fractured rock aquifers in the vicinity of the Mishelyak river and will be key information in understanding the behavior of contaminants originating from process wastes discharged to Lake Karachi. Results from the tests will be analyzed to determine the hydraulic properties of different zones within the fractured rock aquifer and to determine the most cost effective clean-up approach for the site

Variation of uranium isotopes in some carbonate aquifers

International Nuclear Information System (INIS)

Cowart, J.B.

1980-01-01

The 234 U/ 238 U alpha activity ratio (AR) and uranium concentrations are reported for 83 springs that issue from carbonate aquifers in Florida, Texas, Nevada-California, and Israel. Data for each aquifer fall within more or less mutually exclusive fields. In general, the spring in a humid climate have AR's approaching secular equilibrium, whereas those in more arid climates have AR's differing greatly from equilibrium

The Time-Dependency of Deformation in Porous Carbonate Rocks

Science.gov (United States)

Kibikas, W. M.; Lisabeth, H. P.; Zhu, W.

2016-12-01

Porous carbonate rocks are natural reservoirs for freshwater and hydrocarbons. More recently, due to their potential for geothermal energy generation as well as carbon sequestration, there are renewed interests in better understanding of the deformation behavior of carbonate rocks. We conducted a series of deformation experiments to investigate the effects of strain rate and pore fluid chemistry on rock strength and transport properties of porous limestones. Indiana limestone samples with initial porosity of 16% are deformed at 25 °C under effective pressures of 10, 30, and 50 MPa. Under nominally dry conditions, the limestone samples are deformed under 3 different strain rates, 1.5 x 10-4 s-1, 1.5 x 10-5 s-1 and 1.5 x 10-6 s-1 respectively. The experimental results indicate that the mechanical behavior is both rate- and pressure-dependent. At low confining pressures, post-yielding deformation changes from predominantly strain softening to strain hardening as strain rate decreases. At high confining pressures, while all samples exhibit shear-enhanced compaction, decreasing strain rate leads to an increase in compaction. Slower strain rates enhance compaction at all confining pressure conditions. The rate-dependence of deformation behaviors of porous carbonate rocks at dry conditions indicates there is a strong visco-elastic coupling for the degradation of elastic modulus with increasing plastic deformation. In fluid saturated samples, inelastic strain of limestone is partitioned among low temperature plasticity, cataclasis and solution transport. Comparison of inelastic behaviors of samples deformed with distilled water and CO2-saturated aqueous solution as pore fluids provide experimental constraints on the relative activities of the various mechanisms. Detailed microstructural analysis is conducted to take into account the links between stress, microstructure and the inelastic behavior and failure mechanisms.

Origin and structures of groundwater humic substances from three Danish aquifers

DEFF Research Database (Denmark)

Grøn, C.; Wassenaar, L.; Krog, M.

1996-01-01

and halogens, hydrolyzable amino acids and carbohydrates, carbon isotopes) applied to aquatic humic and fulvic acids led to consistent structural interpretations for each of the three aquifers studied. For humic substances in two-aquifers, the analyses suggested source rocks in agreement with geological......Structural, chemical, and isotopic parameters were used to identify the origins of groundwater humic substances from three Danish aquifers. A variety of analytical techniques (visible light absorption, molecular weight distribution, C-13-NMR spectroscopy, elemental composition with major elements...

Geochemistry and origins of mineralized waters in the Floridan aquifer system, northeastern Florida

Science.gov (United States)

Phelps, G.G.

2001-01-01

Increases in chloride concentration have been observed in water from numerous wells tapping the Floridan aquifer system in northeastern Florida. Although most increases have been in the eastern part of Duval County, Florida, no spatial pattern in elevated chloride concentrations is discernible. Possible sources of the mineralized water include modern seawater intrusion; unflushed Miocene-to-Pleistocene-age seawater or connate water in aquifer sediments; or mineralized water from deeper zones of the aquifer system or from formations beneath the Floridan aquifer system. The purpose of this study was to document the chemical and isotopic characteristics of water samples from various aquifer zones, and from geochemical and hydrogeologic data, to infer the source of the increased mineralization. Water samples were collected from 53 wells in northeastern Florida during 1997-1999. Wells tapped various zones of the aquifer including: the Fernandina permeable zone (FPZ), the upper zone of the Lower Floridan aquifer (UZLF), the Upper Floridan aquifer (UFA), and both the UFA and the UZLF. Water samples were analyzed for major ions and trace constituents and for isotopes of carbon, oxygen, hydrogen, sulfur, strontium, chlorine, and boron. Samples of rock from the aquifer were analyzed for isotopes of oxygen, carbon, and strontium. In general, water from various aquifer zones cannot be differentiated based on chemistry, except for water from FPZ wells. Major-ion concentrations vary as much within the upper zone of the Lower Floridan aquifer and the Upper Floridan aquifer as between these two zones. Simple models of mixing between fresh ground water and either modern seawater or water from the FPZ as a mineralized end member show that many water samples from the UZLF aquifer and the UFA are enriched in bicarbonate, calcium, magnesium, sulfate, fluoride, and silica and are depleted in sodium and potassium (as compared to concentrations predicted by simple mixing). Chemical mass

Fluid Dynamics of Carbon Dioxide Disposal into Saline Aquifers

Energy Technology Data Exchange (ETDEWEB)

Garcia, Julio Enrique [Univ. of California, Berkeley, CA (United States)

2003-01-01

Injection of carbon dioxide (CO₂) into saline aquifers has been proposed as a means to reduce greenhouse gas emissions (geological carbon sequestration). Large-scale injection of CO₂ will induce a variety of coupled physical and chemical processes, including multiphase fluid flow, fluid pressurization and changes in effective stress, solute transport, and chemical reactions between fluids and formation minerals. This work addresses some of these issues with special emphasis given to the physics of fluid flow in brine formations. An investigation of the thermophysical properties of pure carbon dioxide, water and aqueous solutions of CO₂ and NaCl has been conducted. As a result, accurate representations and models for predicting the overall thermophysical behavior of the system CO₂-H₂O-NaCl are proposed and incorporated into the numerical simulator TOUGH2/ECO2. The basic problem of CO₂ injection into a radially symmetric brine aquifer is used to validate the results of TOUGH2/ECO2. The numerical simulator has been applied to more complex flow problem including the CO₂ injection project at the Sleipner Vest Field in the Norwegian sector of the North Sea and the evaluation of fluid flow dynamics effects of CO₂ injection into aquifers. Numerical simulation results show that the transport at Sleipner is dominated by buoyancy effects and that shale layers control vertical migration of CO₂. These results are in good qualitative agreement with time lapse surveys performed at the site. High-resolution numerical simulation experiments have been conducted to study the onset of instabilities (viscous fingering) during injection of CO₂ into saline aquifers. The injection process can be classified as immiscible displacement of an aqueous phase by a less dense and less viscous gas phase. Under disposal conditions (supercritical CO₂) the viscosity of carbon

Aquifer recharging in South Carolina: radiocarbon in environmental hydrogeology

International Nuclear Information System (INIS)

Stone, P.A.; Knox, R.L.; Mathews, T.D.

1985-01-01

Radiocarbon activities of dissolved inorganic carbon (and tritium activities where infiltration rates are rapid and aquifers shallow) provide relatively unambiguous and inexpensive evidence for identification of significant recharge areas. Such evidence is for the actual occurrence of modern recharge in the aquifer and thus is less inferential than stratigraphic or potentiometric evidence. These underutilized isotopic techniques are neither arcane nor complex and have been more-or-less standardized by earlier researchers. In South Carolina, isotopic evidence has been used from both calcareous and siliceous sedimentary aquifers and fractured crystalline rock aquifers. The Tertiary limestone aquifer is shown not to be principally recharged in its subcrop area, unlike conditions assumed for many other sedimentary aquifers in southeastern United States, and instead receives considerable lateral recharge from interfingering updip Tertiary sand aquifers in the middle coastal plain. Induced recharging at Hilton Head Island is mixing ancient relict water and modern recharge water. Recharging to deeper portions of the Cretaceous Middendorf basal sand aquifer occurs at least as far coastward as the middle coastal plain, near sampling sites that stratigraphically appear to be confined. Pronounced mineralization of water in fractured rocks cannot be considered as evidence of ancient or relict ground water that is isolated from modern contaminants, some of these waters contain considerable radiocarbon and hydrogen-bomb tritium

Microcosm studies on iron and arsenic mobilization from aquifer sediments under different conditions of microbial activity and carbon source

Science.gov (United States)

Duan, Mengyu; Xie, Zuoming; Wang, Yanxin; Xie, Xianjun

2009-05-01

Microcosm experiments were conducted to understand the mechanism of microbially mediated mobilization of Fe and As from high arsenic aquifer sediments. Arsenic-resistant strains isolated from aquifer sediments of a borehole specifically drilled for this study at Datong basin were used as inoculated strains, and glucose and sodium acetate as carbon sources for the experiments. In abiotic control experiments, the maximum concentrations of Fe and As were only 0.47 mg/L and 0.9 μg/L, respectively. By contrast, the maximum contents of Fe and As in anaerobic microcosm experiments were much higher (up to 1.82 mg/L and 12.91 μg/L, respectively), indicating the crucial roles of microbial activities in Fe and As mobilization. The observed difference in Fe and As release with different carbon sources may be related to the difference in growth pattern and composition of microbial communities that develop in response to the type of carbon sources.

Fresh Water Generation from Aquifer-Pressured Carbon Storage: Annual Report FY09

Energy Technology Data Exchange (ETDEWEB)

Wolery, T; Aines, R; Hao, Y; Bourcier, W; Wolfe, T; Haussman, C

2009-11-25

This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including reverse osmosis (RO) and nanofiltration (NF). The aquifer pressure resulting from the energy required to inject the carbon dioxide provides all or part of the inlet pressure for the desalination system. Residual brine is reinjected into the formation at net volume reduction, such that the volume of fresh water extracted balances the volume of CO{sub 2} injected into the formation. This process provides additional CO{sub 2} storage capacity in the aquifer, reduces operational risks (cap-rock fracturing, contamination of neighboring fresh water aquifers, and seismicity) by relieving overpressure in the formation, and provides a source of low-cost fresh water to offset costs or operational water needs. This multi-faceted project combines elements of geochemistry, reservoir engineering, and water treatment engineering. The range of saline formation waters is being identified and analyzed. Computer modeling and laboratory-scale experimentation are being used to examine mineral scaling and osmotic pressure limitations. Computer modeling is being used to evaluate processes in the storage aquifer, including the evolution of the pressure field. Water treatment costs are being evaluated by comparing the necessary process facilities to those in common use for seawater RO. There are presently limited brine composition data available for actual CCS sites by the site operators including in the U.S. the seven regional Carbon Sequestration Partnerships (CSPs). To work around this, we are building a 'catalog' of compositions representative of 'produced' waters (waters produced in the course of seeking or producing oil and gas), to which we are adding data from actual CCS sites as they become available. Produced waters comprise the most common

Rock pushing and sampling under rocks on Mars

Science.gov (United States)

Moore, H.J.; Liebes, S.; Crouch, D.S.; Clark, L.V.

1978-01-01

Viking Lander 2 acquired samples on Mars from beneath two rocks, where living organisms and organic molecules would be protected from ultraviolet radiation. Selection of rocks to be moved was based on scientific and engineering considerations, including rock size, rock shape, burial depth, and location in a sample field. Rock locations and topography were established using the computerized interactive video-stereophotogrammetric system and plotted on vertical profiles and in plan view. Sampler commands were developed and tested on Earth using a full-size lander and surface mock-up. The use of power by the sampler motor correlates with rock movements, which were by plowing, skidding, and rolling. Provenance of the samples was determined by measurements and interpretation of pictures and positions of the sampler arm. Analytical results demonstrate that the samples were, in fact, from beneath the rocks. Results from the Gas Chromatograph-Mass Spectrometer of the Molecular Analysis experiment and the Gas Exchange instrument of the Biology experiment indicate that more adsorbed(?) water occurs in samples under rocks than in samples exposed to the sun. This is consistent with terrestrial arid environments, where more moisture occurs in near-surface soil un- der rocks than in surrounding soil because the net heat flow is toward the soil beneath the rock and the rock cap inhibits evaporation. Inorganic analyses show that samples of soil from under the rocks have significantly less iron than soil exposed to the sun. The scientific significance of analyses of samples under the rocks is only partly evaluated, but some facts are clear. Detectable quantities of martian organic molecules were not found in the sample from under a rock by the Molecular Analysis experiment. The Biology experiments did not find definitive evidence for Earth-like living organisms in their sample. Significant amounts of adsorbed water may be present in the martian regolith. The response of the soil

Reliable yields of public water-supply wells in the fractured-rock aquifers of central Maryland, USA

Science.gov (United States)

Hammond, Patrick A.

2018-02-01

Most studies of fractured-rock aquifers are about analytical models used for evaluating aquifer tests or numerical methods for describing groundwater flow, but there have been few investigations on how to estimate the reliable long-term drought yields of individual hard-rock wells. During the drought period of 1998 to 2002, many municipal water suppliers in the Piedmont/Blue Ridge areas of central Maryland (USA) had to institute water restrictions due to declining well yields. Previous estimates of the yields of those wells were commonly based on extrapolating drawdowns, measured during short-term single-well hydraulic pumping tests, to the first primary water-bearing fracture in a well. The extrapolations were often made from pseudo-equilibrium phases, frequently resulting in substantially over-estimated well yields. The methods developed in the present study to predict yields consist of extrapolating drawdown data from infinite acting radial flow periods or by fitting type curves of other conceptual models to the data, using diagnostic plots, inverse analysis and derivative analysis. Available drawdowns were determined by the positions of transition zones in crystalline rocks or thin-bedded consolidated sandstone/limestone layers (reservoir rocks). Aquifer dewatering effects were detected by type-curve matching of step-test data or by breaks in the drawdown curves constructed from hydraulic tests. Operational data were then used to confirm the predicted yields and compared to regional groundwater levels to determine seasonal variations in well yields. Such well yield estimates are needed by hydrogeologists and water engineers for the engineering design of water systems, but should be verified by the collection of long-term monitoring data.

Pore Type Classification on Carbonate Reservoir in Offshore Sarawak using Rock Physics Model and Rock Digital Images

International Nuclear Information System (INIS)

Lubis, L A; Harith, Z Z T

2014-01-01

It has been recognized that carbonate reservoirs are one of the biggest sources of hydrocarbon. Clearly, the evaluation of these reservoirs is important and critical. For rigorous reservoir characterization and performance prediction from geophysical measurements, the exact interpretation of geophysical response of different carbonate pore types is crucial. Yet, the characterization of carbonate reservoir rocks is difficult due to their complex pore systems. The significant diagenesis process and complex depositional environment makes pore systems in carbonates far more complicated than in clastics. Therefore, it is difficult to establish rock physics model for carbonate rock type. In this paper, we evaluate the possible rock physics model of 20 core plugs of a Miocene carbonate platform in Central Luconia, Sarawak. The published laboratory data of this area were used as an input to create the carbonate rock physics models. The elastic properties were analyzed to examine the validity of an existing analytical carbonate rock physics model. We integrate the Xu-Payne Differential Effective Medium (DEM) Model and the elastic modulus which was simulated from a digital carbonate rock image using Finite Element Modeling. The results of this integration matched well for the separation of carbonate pore types and sonic P-wave velocity obtained from laboratory measurement. Thus, the results of this study show that the integration of rock digital image and theoretical rock physics might improve the elastic properties prediction and useful for more advance geophysical techniques (e.g. Seismic Inversion) of carbonate reservoir in Sarawak

Kinetics of carbonate dissolution in CO2-saturated aqueous system at reservoir conditions

Science.gov (United States)

Peng, Cheng; Crawshaw, John P.; Maitland, Geoffrey; Trusler, J. P. Martin

2014-05-01

In recent years, carbon capture and storage (CCS) has emerged as a key technology for limiting anthropogenic CO2 emissions while allowing the continued utilisation of fossil fuels. The most promising geological storage sites are deep saline aquifers because the capacity, integrity and injection economics are most favourable, and the environmental impact can be minimal. Many rock-fluid chemical reactions are known to occur both during and after CO2 injection in saline aquifers. The importance of rock-fluid reactions in the (CO2 + H2O) system can be understood in terms of their impact on the integrity and stability of both the formation rocks and cap rocks. The chemical interactions between CO2-acidified brines and the reservoir minerals can influence the porosity and permeability of the formations, resulting in changes in the transport processes occurring during CO2 storage. Since carbonate minerals are abundant in sedimentary rocks, one of the requirements to safely implement CO2 storage in saline aquifers is to characterise the reactivity of carbonate minerals in aqueous solutions at reservoir conditions. In this work, we reported measurements of the intrinsic rate of carbonate dissolution in CO2-saturated water under high-temperature high-pressure reservoir conditions extending up to 373 K and 14 MPa. The rate of carbonate dissolution in CO2-free HCl(aq) was also measured at ambient pressure at temperatures up to 353 K. Various pure minerals and reservoir rocks were investigated in this study, including single-crystals of calcite and magnesite, and samples of dolomite, chalks and sandstones. A specially-designed batch reactor system, implementing the rotating disc technique, was used to obtain the intrinsic reaction rate at the solid/liquid interface, free of mass transfer effects. The effective area and mineralogy of the exposed surface was determined by a combination of surface characterisation techniques including XRD, SEM, EDX and optical microscopy. The

Experimental investigation of CO2-brine-rock interactions at elevated temperature and pressure: Implications for CO2 sequestration in deep-saline aquifers

Science.gov (United States)

Rosenbauer, R.J.; Koksalan, T.; Palandri, J.L.

2005-01-01

Deep-saline aquifers are potential repositories for excess CO2, currently being emitted to the atmosphere from anthropogenic activities, but the reactivity of supercritical CO2 with host aquifer fluids and formation minerals needs to be understood. Experiments reacting supercritical CO2 with natural and synthetic brines in the presence and absence of limestone and plagioclase-rich arkosic sandstone showed that the reaction of CO2-saturated brine with limestone results in compositional, mineralogical, and porosity changes in the aquifer fluid and rock that are dependent on initial brine composition, especially dissolved calcium and sulfate. Experiments reacting CO2-saturated, low-sulfate brine with limestone dissolved 10% of the original calcite and increased rock porosity by 2.6%. Experiments reacting high-sulfate brine with limestone, both in the presence and absence of supercritical CO2, were characterized by the precipitation of anhydrite, dolomitization of the limestone, and a final decrease in porosity of 4.5%. However, based on favorable initial porosity changes of about 15% due to the dissolution of calcite, the combination of CO2 co-injection with other mitigation strategies might help alleviate some of the well-bore scale and formation-plugging problems near the injection zone of a brine disposal well in Paradox Valley, Colorado, as well as provide a repository for CO2. Experiments showed that the solubility of CO2 is enhanced in brine in the presence of limestone by 9% at 25 ??C and 6% at 120 ??C and 200 bar relative to the brine itself. The solubility of CO2 is enhanced also in brine in the presence of arkosic sandstone by 5% at 120 ??C and 300 bar. The storage of CO 2 in limestone aquifers is limited to only ionic and hydraulic trapping. However, brine reacted with supercritical CO2 and arkose yielded fixation and sequestration of CO2 in carbonate mineral phases. Brine desiccation was observed in all experiments containing a discrete CO2 phase

Numerical modelling of fluid-rock interactions: Lessons learnt from carbonate rocks diagenesis studies

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Nader, Fadi; Bachaud, Pierre; Michel, Anthony

2015-04-01

Quantitative assessment of fluid-rock interactions and their impact on carbonate host-rocks has recently become a very attractive research topic within academic and industrial realms. Today, a common operational workflow that aims at predicting the relevant diagenetic processes on the host rocks (i.e. fluid-rock interactions) consists of three main stages: i) constructing a conceptual diagenesis model including inferred preferential fluids pathways; ii) quantifying the resulted diagenetic phases (e.g. depositing cements, dissolved and recrystallized minerals); and iii) numerical modelling of diagenetic processes. Most of the concepts of diagenetic processes operate at the larger, basin-scale, however, the description of the diagenetic phases (products of such processes) and their association with the overall petrophysical evolution of sedimentary rocks remain at reservoir (and even outcrop/ well core) scale. Conceptual models of diagenetic processes are thereafter constructed based on studying surface-exposed rocks and well cores (e.g. petrography, geochemistry, fluid inclusions). We are able to quantify the diagenetic products with various evolving techniques and on varying scales (e.g. point-counting, 2D and 3D image analysis, XRD, micro-CT and pore network models). Geochemical modelling makes use of thermodynamic and kinetic rules as well as data-bases to simulate chemical reactions and fluid-rock interactions. This can be through a 0D model, whereby a certain process is tested (e.g. the likelihood of a certain chemical reaction to operate under specific conditions). Results relate to the fluids and mineral phases involved in the chemical reactions. They could be used as arguments to support or refute proposed outcomes of fluid-rock interactions. Coupling geochemical modelling with transport (reactive transport model; 1D, 2D and 3D) is another possibility, attractive as it provides forward simulations of diagenetic processes and resulting phases. This

The use of magnetic resonance sounding for quantifying specific yield and transmissivity in hard rock aquifers: The example of Benin

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Vouillamoz, J. M.; Lawson, F. M. A.; Yalo, N.; Descloitres, M.

2014-08-01

Hundreds of thousands of boreholes have been drilled in hard rocks of Africa and Asia for supplying human communities with drinking water. Despite the common use of geophysics for improving the siting of boreholes, a significant number of drilled holes does not deliver enough water to be equipped (e.g. 40% on average in Benin). As compared to other non-invasive geophysical methods, magnetic resonance sounding (MRS) is selective to groundwater. However, this distinctive feature has not been fully used in previous published studies for quantifying the drainable groundwater in hard rocks (i.e. the specific yield) and the short-term productivity of aquifer (i.e. the transmissivity). We present in this paper a comparison of MRS results (i.e. the water content and pore-size parameter) with both specific yield and transmissivity calculated from long duration pumping tests. We conducted our experiments in six sites located in different hard rock groups in Benin, thus providing a unique data set to assess the usefulness of MRS in hard rock aquifers. We found that the MRS water content is about twice the specific yield. We also found that the MRS pore-size parameter is well correlated with the specific yield. Thus we proposed two linear equations for calculating the specific yield from the MRS water content (with an uncertainty of about 10%) and from the pore-size parameter (with an uncertainty of about 20%). The later has the advantage of defining a so-named MRS cutoff time value for indentifying non-drainable MRS water content and thus low groundwater reserve. We eventually propose a nonlinear equation for calculating the specific yield using jointly the MRS water content and the pore-size parameters, but this approach has to be confirmed with further investigations. This study also confirmed that aquifer transmissivity can be estimated from MRS results with an uncertainty of about 70%. We conclude that MRS can be usefully applied for estimating aquifer specific yield and

Rock fracture grouting with microbially induced carbonate precipitation

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Minto, James M.; MacLachlan, Erica; El Mountassir, Gráinne; Lunn, Rebecca J.

2016-11-01

Microbially induced carbonate precipitation has been proposed for soil stabilization, soil strengthening, and permeability reduction as an alternative to traditional cement and chemical grouts. In this paper, we evaluate the grouting of fine aperture rock fractures with calcium carbonate, precipitated through urea hydrolysis, by the bacteria Sporosarcina pasteurii. Calcium carbonate was precipitated within a small-scale and a near field-scale (3.1 m2) artificial fracture consisting of a rough rock lower surfaces and clear polycarbonate upper surfaces. The spatial distribution of the calcium carbonate precipitation was imaged using time-lapse photography and the influence on flow pathways revealed from tracer transport imaging. In the large-scale experiment, hydraulic aperture was reduced from 276 to 22 μm, corresponding to a transmissivity reduction of 1.71 × 10-5 to 8.75 × 10-9 m2/s, over a period of 12 days under constantly flowing conditions. With a modified injection strategy a similar three orders of magnitude reduction in transmissivity was achieved over a period of 3 days. Calcium carbonate precipitated over the entire artificial fracture with strong adhesion to both upper and lower surfaces and precipitation was controlled to prevent clogging of the injection well by manipulating the injection fluid velocity. These experiments demonstrate that microbially induced carbonate precipitation can successfully be used to grout a fracture under constantly flowing conditions and may be a viable alternative to cement based grouts when a high level of hydraulic sealing is required and chemical grouts when a more durable grout is required.

Simplified models of transport and reactions in conditions of CO2 storage in saline aquifers

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Suchodolska, Katarzyna; Labus, Krzysztof

2016-04-01

Simple hydrogeochemical models may serve as tools of preliminary assessment of CO2 injection and sequestraton impact on the aquifer and cap-rocks. In order to create models of reaction and transport in conditions of CO2 injection and storage, the TOUGHREACT simulator, and the Geochemist's Workbench software were applied. The chemical composition of waters for kinetic transport models based on the water - rock equilibrium calculations. Analyses of reaction and transport of substances during CO2 injection and storage period were carried out in three scenarios: one-dimensional radial model, and two-dimensional model of CO2 injection and sequestration, and one-dimensional model of aquifer - cap-rock interface. Modeling was performed in two stages. The first one simulated the immediate changes in the aquifer and insulating rocks impacted by CO2 injection (100 days in case of reaction model and 30 years in transport and reaction model), the second - enabled assessment of long-term effects of sequestration (20000 years). Reactions' quality and progress were monitored and their effects on formation porosity and sequestration capacity in form of mineral, residual and free phase of CO2 were calculated. Calibration of numerical models (including precipitation of secondary minerals, and correction of kinetics parameters) describing the initial stage of injection, was based on the experimental results. Modeling allowed to evaluate the pore space saturation with gas, changes in the composition and pH of pore waters, relationships between porosity and permeability changes and crystallization or dissolution minerals. We assessed the temporal and spatial extent of crystallization processes, and the amount of carbonates trapping. CO2 in mineral form. The calculated sequestration capacity of analyzed formations reached n·100 kg/m3 for the: dissolved phase - CO(aq), gas phase - CO2(g) and mineral phase, but as much as 101 kg/m3 for the supercritical phase - SCCO2. Processes of gas

Laboratory Experiments to Evaluate Diffusion of 14C into Nevada Test Site Carbonate Aquifer Matrix

Energy Technology Data Exchange (ETDEWEB)

Ronald L. Hershey; William Howcroft; Paul W. Reimus

2003-03-01

Determination of groundwater flow velocities at the Nevada Test Site is important since groundwater is the principal transport medium of underground radionuclides. However, 14C-based groundwater velocities in the carbonate aquifers of the Nevada Test Site are several orders of magnitude slower than velocities derived from the Underground Test Area regional numerical model. This discrepancy has been attributed to the loss or retardation of 14C from groundwater into the surrounding aquifer matrix making 14C-based groundwater ages appear much older. Laboratory experiments were used to investigate the retardation of 14C in the carbonate aquifers at the Nevada Test Site. Three sets of experiments were conducted evaluating the diffusion of 14C into the carbonate aquifer matrix, adsorption and/or isotopic exchange onto the pore surfaces of the carbonate matrix, and adsorption and/or isotopic exchange onto the fracture surfaces of the carbonate aquifer. Experimental results a nd published aquifer matrix and fracture porosities from the Lower Carbonate Aquifer were applied to a 14C retardation model. The model produced an extremely wide range of retardation factors because of the wide range of published aquifer matrix and fracture porosities (over three orders of magnitude). Large retardation factors suggest that groundwater with very little measured 14C activity may actually be very young if matrix porosity is large relative to the fracture porosity. Groundwater samples collected from highly fractured aquifers with large effective fracture porosities may have relatively small correction factors, while samples from aquifers with a few widely spaced fractures may have very large correction factors. These retardation factors were then used to calculate groundwater velocities from a proposed flow path at the Nevada Test Site. The upper end of the range of 14C correction factors estimated groundwater velocities that appear to be at least an order of magnitude too high compared

Experimental investigation of geochemical and mineralogical effects of CO2 sequestration on flow characteristics of reservoir rock in deep saline aquifers

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Rathnaweera, T. D.; Ranjith, P. G.; Perera, M. S. A.

2016-01-01

Interactions between injected CO2, brine, and rock during CO2 sequestration in deep saline aquifers alter their natural hydro-mechanical properties, affecting the safety, and efficiency of the sequestration process. This study aims to identify such interaction-induced mineralogical changes in aquifers, and in particular their impact on the reservoir rock’s flow characteristics. Sandstone samples were first exposed for 1.5 years to a mixture of brine and super-critical CO2 (scCO2), then tested to determine their altered geochemical and mineralogical properties. Changes caused uniquely by CO2 were identified by comparison with samples exposed over a similar period to either plain brine or brine saturated with N2. The results show that long-term reaction with CO2 causes a significant pH drop in the saline pore fluid, clearly due to carbonic acid (as dissolved CO2) in the brine. Free H+ ions released into the pore fluid alter the mineralogical structure of the rock formation, through the dissolution of minerals such as calcite, siderite, barite, and quartz. Long-term CO2 injection also creates a significant CO2 drying-out effect and crystals of salt (NaCl) precipitate in the system, further changing the pore structure. Such mineralogical alterations significantly affect the saline aquifer’s permeability, with important practical consequences for the sequestration process. PMID:26785912

Geochemistry of the Springfield Plateau aquifer of the Ozark Plateaus Province in Arkansas, Kansas, Missouri and Oklahoma, USA

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Adamski, J.C.

2000-01-01

Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate-rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field-measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water-rock interactions. Water from wells flow through small fractures, which restrict

Aquifer Recharge Estimation In Unsaturated Porous Rock Using Darcian And Geophysical Methods.

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Nimmo, J. R.; De Carlo, L.; Masciale, R.; Turturro, A. C.; Perkins, K. S.; Caputo, M. C.

2016-12-01

Within the unsaturated zone a constant downward gravity-driven flux of water commonly exists at depths ranging from a few meters to tens of meters depending on climate, medium, and vegetation. In this case a steady-state application of Darcy's law can provide recharge rate estimates.We have applied an integrated approach that combines field geophysical measurements with laboratory hydraulic property measurements on core samples to produce accurate estimates of steady-state aquifer recharge, or, in cases where episodic recharge also occurs, the steady component of recharge. The method requires (1) measurement of the water content existing in the deep unsaturated zone at the location of a core sample retrieved for lab measurements, and (2) measurement of the core sample's unsaturated hydraulic conductivity over a range of water content that includes the value measured in situ. Both types of measurements must be done with high accuracy. Darcy's law applied with the measured unsaturated hydraulic conductivity and gravitational driving force provides recharge estimates.Aquifer recharge was estimated using Darcian and geophysical methods at a deep porous rock (calcarenite) experimental site in Canosa, southern Italy. Electrical Resistivity Tomography (ERT) and Vertical Electrical Sounding (VES) profiles were collected from the land surface to water table to provide data for Darcian recharge estimation. Volumetric water content was estimated from resistivity profiles using a laboratory-derived calibration function based on Archie's law for rock samples from the experimental site, where electrical conductivity of the rock was related to the porosity and water saturation. Multiple-depth core samples were evaluated using the Quasi-Steady Centrifuge (QSC) method to obtain hydraulic conductivity (K), matric potential (ψ), and water content (θ) estimates within this profile. Laboratory-determined unsaturated hydraulic conductivity ranged from 3.90 x 10-9 to 1.02 x 10-5 m

Hydrogeology and geochemistry of aquifers underlying the San Lorenzo and San Leandro areas of the East Bay Plain, Alameda County, California

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Izbicki, John A.; Borchers, James W.; Leighton, David A.; Kulongoski, Justin T.; Fields, Latoya; Galloway, Devin L.; Michel, Robert L.

2003-01-01

infiltration of precipitation occur within the study area. However, recharge of imported water from leaking water-supply pipes, believed by previous investigators to be a large source of ground-water recharge, was not supported on the basis of oxygen-18 and deuterium data collected as part of this study. Based on tritium/helium-3 ages, most water in the upper aquifer system is relatively young and was recharged after 1952; however, water in the lower aquifer system is older and does not contain detectable tritium. Carbon-14 ages interpreted for water from wells in the lower aquifer system and underlying partly consolidated rocks range from 500 to more than 20,000 years before present. The greatest ages were in water from wells completed in the partly consolidated deposits that underlie the northern part of the study area. Ground water from wells in the lower aquifer system near the proposed Bayside injection/recovery site was recharged about 9,400 years before present and appears to be isolated from surface sources of recharge and ground-water contamination.

Integration of rock typing methods for carbonate reservoir characterization

International Nuclear Information System (INIS)

Aliakbardoust, E; Rahimpour-Bonab, H

2013-01-01

Reservoir rock typing is the most important part of all reservoir modelling. For integrated reservoir rock typing, static and dynamic properties need to be combined, but sometimes these two are incompatible. The failure is due to the misunderstanding of the crucial parameters that control the dynamic behaviour of the reservoir rock and thus selecting inappropriate methods for defining static rock types. In this study, rock types were defined by combining the SCAL data with the rock properties, particularly rock fabric and pore types. First, air-displacing-water capillary pressure curues were classified because they are representative of fluid saturation and behaviour under capillary forces. Next the most important rock properties which control the fluid flow and saturation behaviour (rock fabric and pore types) were combined with defined classes. Corresponding petrophysical properties were also attributed to reservoir rock types and eventually, defined rock types were compared with relative permeability curves. This study focused on representing the importance of the pore system, specifically pore types in fluid saturation and entrapment in the reservoir rock. The most common tests in static rock typing, such as electrofacies analysis and porosity–permeability correlation, were carried out and the results indicate that these are not appropriate approaches for reservoir rock typing in carbonate reservoirs with a complicated pore system. (paper)

A study on variation in dissolved silica concentration in groundwater of hard rock aquifers in Southeast coast of India

International Nuclear Information System (INIS)

Pradeep, K; Nepolian, M; Anandhan, P; Chandran; Kaviyarasan, R; Chidambaram, S; Prasanna, M V

2016-01-01

Ground water of hard rock aquifers due to its lesser permeability results in the increased residence time, which leads to the higher concentration of ions. Hence in order to understand the hydro-geochemistry of the groundwater of a hard rock aquifer in India, 23 groundwater samples were collected from different locations of the study area and subjected to analysis of major cations and anions. The results of silica showed different range of concentration and was plotted in different groups. In order to understand the reason for this variation, different techniques like Thermodynamics, Statistics and GIS were adopted and it was inferred that the concentration was mainly governed by lithology and land use pattern of the study area. (paper)

Geostatistical Borehole Image-Based Mapping of Karst-Carbonate Aquifer Pores.

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Sukop, Michael C; Cunningham, Kevin J

2016-03-01

Quantification of the character and spatial distribution of porosity in carbonate aquifers is important as input into computer models used in the calculation of intrinsic permeability and for next-generation, high-resolution groundwater flow simulations. Digital, optical, borehole-wall image data from three closely spaced boreholes in the karst-carbonate Biscayne aquifer in southeastern Florida are used in geostatistical experiments to assess the capabilities of various methods to create realistic two-dimensional models of vuggy megaporosity and matrix-porosity distribution in the limestone that composes the aquifer. When the borehole image data alone were used as the model training image, multiple-point geostatistics failed to detect the known spatial autocorrelation of vuggy megaporosity and matrix porosity among the three boreholes, which were only 10 m apart. Variogram analysis and subsequent Gaussian simulation produced results that showed a realistic conceptualization of horizontal continuity of strata dominated by vuggy megaporosity and matrix porosity among the three boreholes. © 2015, National Ground Water Association.

Potentially bioavailable natural organic carbon and hydrolyzable amino acids in aquifer sediments

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Thomas, Lashun K.; Widdowson, Mark A.; Novak, John T.; Chapelle, Francis H.; Benner, Ronald; Kaiser, Karl

2012-01-01

This study evaluated the relationship between concentrations of operationally defined potentially bioavailable organic -carbon (PBOC) and hydrolyzable amino acids (HAAs) in sediments collected from a diverse range of chloroethene--contaminated sites. Concentrations of PBOC and HAA were measured using aquifer sediment samples collected at six selected study sites. Average concentrations of total HAA and PBOC ranged from 1.96 ± 1.53 to 20.1 ± 25.6 mg/kg and 4.72 ± 0.72 to 443 ± 65.4 mg/kg, respectively. Results demonstrated a statistically significant positive relationship between concentrations of PBOC and total HAA present in the aquifer sediment (p amino acids are known to be readily biodegradable carbon compounds, this relationship suggests that the sequential chemical extraction procedure used to measure PBOC is a useful indicator of bioavailable carbon in aquifer sediments. This, in turn, is consistent with the interpretation that PBOC measurements can be used for estimating the amount of natural organic carbon available for driving the reductive dechlorination of chloroethenes in groundwater systems.

ASTER spectral sensitivity of carbonate rocks - Study in Sultanate of Oman

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Rajendran, Sankaran; Nasir, Sobhi

2014-02-01

Remote sensing satellite data plays a vital role and capable in detecting minerals and discriminating rock types for explorations of mineral resources and geological studies. Study of spectral absorption characters of remotely sensed data are under consideration by the exploration and mining companies, and demonstrating the spectral absorption characters of carbonates on the cost-effective multispectral image (rather than the hyperspectral, Lidar image) for easy understanding of all geologists and exploration communities of carbonates is very much important. The present work is an integrated study and an outcome of recently published works on the economic important carbonate rocks, includes limestone, marl, listwaenites and carbonatites occurred in parts of the Sultanate of Oman. It demonstrates the spectral sensitivity of such rocks for simple interpretation over satellite data and describes and distinguishes them based on the absorptions of carbonate minerals in the spectral bands of advanced spaceborne thermal emission and reflection radiometer (ASTER) for mapping and exploration studies. The study results that the ASTER spectral band 8 discriminates the carbonate rocks due to the presence of predominantly occurred carbonate minerals; the ASTER band 5 distinguishes the limestones and marls (more hydroxyl clay minerals) from listwaenite (hydrothermally altered rock) due to the presence of altered minerals and the ASTER band 4 detects carbonatites (ultramafic intrusive alkaline rocks) which contain relatively more silicates. The study on the intensity of the total absorptions against the reflections of these rocks shows that the limestones and marls have low intensity in absorptions (and high reflection values) due to the presence of carbonate minerals (calcite and dolomite) occurred in different proportions. The listwaenites and carbonatites have high intensity of absorptions (low reflection values) due to the occurrence of Mn-oxide in listwaenites and carbonates

Groundwater Dynamics in Fossil Fractured Carbonate Aquifers in Eastern Arabian Peninsula

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Farag, A. Z. A.; Heggy, E.; Helal, M.; Thirunavukkarasu, D.; Scabbia, G.; Palmer, E. M.

2017-12-01

The Eastern Arabian Peninsula, notably the Qatar Peninsula, represents one of the highest natural groundwater discharge areas for the Arabian platform fossil aquifer system. Groundwater flow dynamics in these aquifers trace the paleoclimatic conditions that have prevailed the Arabian Peninsula during the Quaternary. In such settings, connections between aquifers strongly affect the flow dynamics, water quality and availability as well as karst formation and landscape evolution. Geological structures such as folds, faults and fractures are central to aquifer connectivity, yet their role on groundwater flow is poorly understood. Herein, we performed a detailed mapping of exposed and buried structural features in Qatar using Landsat, Sentinel and ALOS-PalSAR scenes, correlated with field and laboratory measurements to understand their role in aquifer connectivity and groundwater dynamics. Our results suggest that E-W oriented fold-related faults act as vertical conduits along which artesian upward leakages from the deep aquifers (e.g. Aruma and Umm er Radhuma) take place into the shallower aquifers (e.g. Rus and Dammam). Evidence includes: (1) the high potentiometric surfaces of deep aquifers (6 to 25 m amsl) compare to the shallower aquifers (2-3 m amsl for the same region); (2) anomalous elevation of groundwater levels and steeper hydraulic gradients in densely faulted regions; (3) mixed isotopic composition in shallow aquifers (δ18O: -5 to -2 ‰, δ2H: -40 to -10 ‰) between reported deep fossil waters (δ18O: -6.3 ‰, δ2H: -55 ‰) and modern meteoric waters (weighted average: δ18O: -0.6 ‰, δ2H: 4 ‰); (4) abundant meso-crystalline fibrous gypsum veins along fault zones in the Dammam Formation (up to 28 m amsl) in southern Qatar where the anhydritic member of the Rus Formation predominates the subsurface leading to gypsum oversaturation of groundwater. The similarity of crystal morphology (platy crystals under SEM), mineralogical compositions from XRD

Estimation of Carbon Sink in Surface Carbonate Rocks of Guangxi Province by Using Remote Sensing Images

Science.gov (United States)

Jia, B.; Zhou, G.; Wang, H.; Yue, T.; Huang, W.

2018-04-01

Studies of the imbalance of source sinks in the carbon cycle show that CO2 absorbed during rock weathering is part of the "miss carbon" of the global carbon cycle. The carbon sink contribution of carbonate rocks obviously plays a very important role in the absorption of atmospheric CO2. Estimation of carbon sinks in karst dynamic system of Guangxi province has great significance for further understanding of global karst carbon cycle and global climate research. This paper quotes the rock data from Tao Xiaodong's paper, which is obtained using RS and GIS techniques. At the same time, the dissolution rate model studied by Zhou Guoqing and others was used to estimate the dissolution rate of carbonate rocks in Guangxi Province. Finally, the CO2 content consumed by carbonate karstification in Guangxi Province was 1342910.447 t a-1. The results obtained are in the same order of magnitude as the CO2 content consumed by carbonate rock karstification in Guangxi Province calculated by Tao Xiaodong.

Geochemical detection of carbon dioxide in dilute aquifers

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Aines Roger

2009-03-01

Full Text Available Abstract Background Carbon storage in deep saline reservoirs has the potential to lower the amount of CO2 emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO2 gas leak into dilute groundwater are important measures for the potential release of CO2 to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO2 storage reservoir. Specifically, we address the relationships between CO2 flux, groundwater flow, detection time and distance. The CO2 flux ranges from 103 to 2 × 106 t/yr (0.63 to 1250 t/m2/yr to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure. Results For the scenarios we studied, our simulations show pH and carbonate chemistry are good indicators for leakage of stored CO2 into an overlying aquifer because elevated CO2 yields a more acid pH than the ambient groundwater. CO2 leakage into a dilute groundwater creates a slightly acid plume that can be detected at some distance from the leak source due to groundwater flow and CO2 buoyancy. pH breakthrough curves demonstrate that CO2 leaks can be easily detected for CO2 flux ≥ 104 t/yr within a 15-month time period at a monitoring well screened within a permeable layer 500 m downstream from the vertical gas trace. At lower flux rates, the CO2 dissolves in the aqueous phase

Geochemical detection of carbon dioxide in dilute aquifers.

Science.gov (United States)

Carroll, Susan; Hao, Yue; Aines, Roger

2009-03-26

Carbon storage in deep saline reservoirs has the potential to lower the amount of CO2 emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO2 gas leak into dilute groundwater are important measures for the potential release of CO2 to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO2 storage reservoir. Specifically, we address the relationships between CO2 flux, groundwater flow, detection time and distance. The CO2 flux ranges from 10(3) to 2 x 10(6) t/yr (0.63 to 1250 t/m2/yr) to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure. For the scenarios we studied, our simulations show pH and carbonate chemistry are good indicators for leakage of stored CO2 into an overlying aquifer because elevated CO2 yields a more acid pH than the ambient groundwater. CO2 leakage into a dilute groundwater creates a slightly acid plume that can be detected at some distance from the leak source due to groundwater flow and CO2 buoyancy. pH breakthrough curves demonstrate that CO2 leaks can be easily detected for CO2 flux >or= 10(4) t/yr within a 15-month time period at a monitoring well screened within a permeable layer 500 m downstream from the vertical gas trace. At lower flux rates, the CO2 dissolves in the aqueous phase in the lower most permeable unit and does

Relationship of regional water quality to aquifer thermal energy storage

International Nuclear Information System (INIS)

Allen, R.D.; Raymond, J.R.

1990-01-01

Aquifer thermal energy storage (ATES) involves injection and withdrawal of temperature-conditioned water into and from a permeable water-bearing formation. The groundwater quality and associated geological characteristics were assessed as they may affect the feasibility of ATES system development in any hydrologic region. Seven physical and chemical mechanisms may decrease system efficiency: particulate plugging, chemical precipitation, clay mineral dispersion, piping corrosion, aquifer disaggregation, mineral oxidation, and the proliferation of biota. Factors affecting groundwater quality are pressure, temperature, pH, ion exchange, evaporation/transpiration, and commingling with diverse waters. Modeling with the MINTEQ code showed three potential reactions: precipitation of calcium carbonate at raised temperatures; solution of silica at raised temperature followed by precipitation at reduced temperatures; and oxidation/precipitation of iron compounds. Low concentrations of solutes are generally favorable for ATES. Near-surface waters in high precipitation regions are low in salinity. Groundwater recharged from fresh surface waters also has reduced salinity. Rocks least likely to react with groundwater are siliceous sandstones, regoliths, and metamorphic rocks. On the basis of known aquifer hydrology, ten US water resource regions are candidates for selected exploration and development, all characterized by extensive silica-rich aquifers

Microbial diversity and impact on carbonate geochemistry across a changing geochemical gradient in a karst aquifer.

Science.gov (United States)

Gray, Cassie J; Engel, Annette S

2013-02-01

Although microbes are known to influence karst (carbonate) aquifer ecosystem-level processes, comparatively little information is available regarding the diversity of microbial activities that could influence water quality and geological modification. To assess microbial diversity in the context of aquifer geochemistry, we coupled 16S rRNA Sanger sequencing and 454 tag pyrosequencing to in situ microcosm experiments from wells that cross the transition from fresh to saline and sulfidic water in the Edwards Aquifer of central Texas, one of the largest karst aquifers in the United States. The distribution of microbial groups across the transition zone correlated with dissolved oxygen and sulfide concentration, and significant variations in community composition were explained by local carbonate geochemistry, specifically calcium concentration and alkalinity. The waters were supersaturated with respect to prevalent aquifer minerals, calcite and dolomite, but in situ microcosm experiments containing these minerals revealed significant mass loss from dissolution when colonized by microbes. Despite differences in cell density on the experimental surfaces, carbonate loss was greater from freshwater wells than saline, sulfidic wells. However, as cell density increased, which was correlated to and controlled by local geochemistry, dissolution rates decreased. Surface colonization by metabolically active cells promotes dissolution by creating local disequilibria between bulk aquifer fluids and mineral surfaces, but this also controls rates of karst aquifer modification. These results expand our understanding of microbial diversity in karst aquifers and emphasize the importance of evaluating active microbial processes that could affect carbonate weathering in the subsurface.

Elucidating the Role of Carbon Sources on Abiotic and Biotic Release of Arsenic into Cambodian Aquifers

Science.gov (United States)

Koeneke, M.

2017-12-01

Arsenic (As) is a naturally occurring contaminant in Cambodia that has been contaminating well-water sources of millions of people. Commonly, studies look into the biotic factors that cause the arsenic to be released from aquifer sediments to groundwater. However, abiotic release of As from sediments, though little studied, may also play key roles in As contamination of well water. The goal of this research is to quantitatively compare organic-carbon mediated abiotic and biotic release of arsenic from sediments to groundwater. Batch anaerobic incubation experiments under abiotic (sodium azide used to immobilize microbes) and biotic conditions were conducted using Cambodian aquifer sediments, four different organic carbon sources (sodium lactate, sodium citrate, sodium oxalate, and humic acid), and six different carbon concentrations (0, 1, 2.5, 5, 10, 25mg C/L). Dissolved arsenic, iron(Fe), and manganese(Mn) concentrations in the treatments were measured 112 days . In addition, sediment and solution carbon solution was measured . Collectively, these show how different carbon sources, different carbon concentrations, and how abiotic and biotic factors impact the release of arsenic from Cambodian sediments into aquifers. Overall, an introduction of organic carbon to the soil increases the amount of As released from the sediment. The biotic + abiotic and abiotic conditions seemed to play a minimal role in the amount of As released. Dissolved species analysis showed us that 100% of the As was As(V), Our ICP-MS results vary due to the heterogeneity of samples, but when high levels are Fe are seen in solution, we also see high levels of As. We also see higher As concentrations when there is a smaller amount of Mn in solution.

Carbonate Chemistry and Isotope Characteristics of Groundwater of Ljubljansko Polje and Ljubljansko Barje Aquifers in Slovenia

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Sonja Cerar

2013-01-01

Full Text Available Ljubljansko polje and Ljubljansko Barje aquifers are the main groundwater resources for the needs of Ljubljana, the capital of Slovenia. Carbonate chemistry and isotope analysis of the groundwater were performed to acquire new hydrogeological data, which should serve as a base for improvement of hydrogeological conceptual models of both aquifers. A total of 138 groundwater samples were collected at 69 sampling locations from both aquifers. Major carbonate ions and the stable isotope of oxygen were used to identify differences in the recharging areas of aquifers. Four groups of groundwater were identified: (1 Ljubljansko polje aquifer, with higher Ca2+ values, as limestone predominates in its recharge area, (2 northern part of Ljubljansko Barje aquifer, with prevailing dolomite in its recharge area, (3 central part of Ljubljansko Barje aquifer, which lies below surface cover of impermeable clay and is poor in carbonate, and (4 Brest and Iški vršaj aquifer in the southern part of Ljubljansko Barje with higher Mg2+ in groundwater and dolomite prevailing in its recharge area. The radioactive isotope tritium was also used to estimate the age of groundwater. Sampled groundwater is recent with tritium activity between 4 and 8 TU and residence time of up to 10 years.

Unravelling aquifer-wetland interaction using CSAMT and gravity methods: the Mollina-Camorra aquifer and the Fuente de Piedra playa-lake, southern Spain

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Pedrera, A.; Martos-Rosillo, S.; Galindo-Zaldívar, J.; Rodríguez-Rodríguez, M.; Benavente, J.; Martín-Rodríguez, J. F.; Zúñiga-López, M. I.

2016-06-01

The hydrological regime of Fuente de Piedra playa-lake (Málaga, southern Spain) has been significantly affected by the intensive exploitation of groundwater in the area. The playa-lake is situated above clays, marls, and gypsum, and under unaltered conditions received surface-subsurface runoff within the watershed as well as groundwater discharge from two carbonate aquifers. We have analyzed the structure of the main one, the Mollina-Camorra carbonate aquifer, by combining controlled source audio magnetotellurics (CSAMT), gravity prospecting, and time-domain electromagnetic (TDEM) soundings. This geophysical information, together with new structural and hydrogeological data, was gathered to develop a new conceptual hydrogeological model. This model allows the hydrological linkage of the carbonate aquifer with the playa-lake system to be established. Moreover, the intensive exploitation in the carbonate aquifer, even outside the watershed of the playa-lake, has affected the hydrological regime of the system. This multidisciplinary work demonstrates the potential of geophysical methods for understanding wetland-aquifer interaction, having important groundwater management implications.

Geology of Paleozoic Rocks in the Upper Colorado River Basin in Arizona, Colorado, New Mexico, Utah, and Wyoming, Excluding the San Juan Basin

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Geldon, Arthur L.

2003-01-01

The geology of the Paleozoic rocks in the Upper Colorado River Basin in Arizona, Colorado, New Mexico, Utah, and Wyoming, was studied as part of the U.S. Geological Survey's Regional Aquifer-System Analysis Program to provide support for hydrogeological interpretations. The study area is segmented by numerous uplifts and basins caused by folding and faulting that have recurred repeatedly from Precambrian to Cenozoic time. Paleozoic rocks in the study area are 0-18,000 feet thick. They are underlain by Precambrian igneous, metamorphic, and sedimentary rocks and are overlain in most of the area by Triassic formations composed mostly of shale. The overlying Mesozoic and Tertiary rocks are 0-27,000 feet thick. All Paleozoic systems except the Silurian are represented in the region. The Paleozoic rocks are divisible into 11 hydrogeologic units. The basal hydrogeologic unit consisting of Paleozoic rocks, the Flathead aquifer, predominantly is composed of Lower to Upper Cambrian sandstone and quartzite. The aquifer is 0-800 feet thick and is overlain gradationally to unconformably by formations of Cambrian to Mississippian age. The Gros Ventre confining unit consists of Middle to Upper Cambrian shale with subordinate carbonate rocks and sandstone. The confining unit is 0-1,100 feet thick and is overlain gradationally to unconformably by formations of Cambrian to Mississippian age. The Bighom aquifer consists of Middle Cambrian to Upper Ordovician limestone and dolomite with subordinate shale and sandstone. The aquifer is 0-3,000 feet thick and is overlain unconformably by Devonian and Mississipplan rocks. The Elbert-Parting confining unit consists of Lower Devonian to Lower Mississippian limestone, dolomite, sandstone, quartzite, shale, and anhydrite. It is 0-700 feet thick and is overlain conformably to unconformably by Upper Devonian and Mississippian rocks. The Madison aquifer consists of two zones of distinctly different lithology. The lower (Redwall-Leadville) zone

Characterization of aquifer heterogeneity using Cyclostratigraphy and geophysical methods in the upper part of the Karstic Biscayne Aquifer, Southeastern Florida

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Cunningham, Kevin J.; Carlson, Janine L.; Wingard, G. Lynn; Robinson, Edward; Wacker, Michael A.

2004-01-01

This report identifies and characterizes candidate ground-water flow zones in the upper part of the shallow, eogenetic karst limestone of the Biscayne aquifer in the Lake Belt area of north-central Miami-Dade County using cyclostratigraphy, ground-penetrating radar (GPR), borehole geophysical logs, and continuously drilled cores. About 60 miles of GPR profiles were used to calculate depths to shallow geologic contacts and hydrogeologic units, image karst features, and produce qualitative views of the porosity distribution. Descriptions of the lithology, rock fabrics, and cyclostratigraphy, and interpretation of depositional environments of 50 test coreholes were linked to the geophysical interpretations to provide an accurate hydrogeologic framework. Molluscan and benthic foraminiferal paleontologic constraints guided interpretation of depositional environments represented by rockfabric facies. Digital borehole images were used to characterize and quantify large-scale vuggy porosity. Preliminary heat-pulse flowmeter data were coupled with the digital borehole image data to identify candidate ground-water flow zones. Combined results show that the porosity and permeability of the karst limestone of the Biscayne aquifer have a highly heterogeneous and anisotropic distribution that is mostly related to secondary porosity overprinting vertical stacking of rock-fabric facies within high-frequency cycles (HFCs). This distribution of porosity produces a dual-porosity system consisting of diffuse-carbonate and conduit flow zones. The nonuniform ground-water flow in the upper part of the Biscayne aquifer is mostly localized through secondary permeability, the result of solution-enlarged carbonate grains, depositional textures, bedding planes, cracks, root molds, and paleokarst surfaces. Many of the resulting pore types are classified as touching vugs. GPR, borehole geophysical logs, and whole-core analyses show that there is an empirical relation between formation porosity

Potential for formation of disinfection by-products from storage of chlorinated surface water in the Basalt aquifer near Fallon, Nevada

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Fram, Miranda S.; Maurer, Douglas K.; Lico, Michael S.

2005-01-01

Increased pumpage from a basalt aquifer near Fallon, Nevada, has caused its water levels to decline and has induced changes in the quality of water pumped from the basalt. The aquifer is the sole source of water for municipal supply to the city of Fallon, the Naval Air Station Fallon, and the Fallon Paiute-Shoshone Tribe. These changes may be mitigated by storage of surface water in the basalt for subsequent use. Because chlorination of the surface water may be required for storage, the U.S. Geological Survey, in cooperation with the Fallon Paiute-Shoshone Tribe, made laboratory tests using laboratory carbon-organic-free water, surface-water, ground-water, and basaltic-rock samples to determine the potential for formation of disinfection by-products. Experiments with water samples only (no rock and no chlorine) indicated no change in dissolved-organic-carbon (DOC) concentrations over a 20-day reaction period; whereas, all experiments using rock, water, and no chlorine indicated an increase in DOC concentrations. The greatest increase in DOC concentrations for all three water samples occurred in experiments with the rock samples from outcrops on Rattlesnake Hill. Experiments with water only and chlorine yielded a total trihalomethane (THM) concentration of 97.4 ?g/L for the ground-water sample and 347 ?g/L for the surface-water sample. Experiments with mixtures of water, rocks, and chlorine indicated that reactions with the rock consumed chlorine and released significant amounts of organic carbon from the rock, increasing the DOC concentration in the water. The organic carbon in the rocks likely is associated with the secondary clay minerals that line vesicles and fractures in the rocks. THM concentrations were greatest, from 335 to 909 ?g/L, for surface water equilibrated with rock samples from Rattlesnake Hill. However, the concentration of chlorine required to produce these high THM concentrations ranged from 18 to 84 mg/L. The results of the experiments suggest

Taking into Account the Role of the Weathering Profile in Determining Hydrodynamic Properties of Hard Rock Aquifers

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Mahamadou Koïta

2017-09-01

Full Text Available The present study aims at understanding the role of the structure and the geometry of the weathering profile on the hydrodynamic behavior of hard rock aquifers. We first described 2D geophysical cross sections of weathering profiles realized and validated on an experimental site. Next, we implemented five long-term pumping tests in wells drilled at various locations of these cross sections. Finally, we chose the appropriate analytical solutions to determine the hydrodynamic parameters in consistence with the structure and the geometry of the weathering profile. Results reveal that land covers, weathering type and thickness, presence of no flow boundaries, etc. are all factors that explain the flow regime, which appears therefore much less unpredictable. In other words, the 2D geophysical data are enough to locate the best permeable areas, or the areas where the structure of the aquifer without impervious boundaries and with leakage favor a good long-term behavior of the well. The values of aquifer’s transmissivity vary between 5.10−3 and 4.10−5 m2/s. The storage varies between 0.06 and 7.10−7. The variability of these parameters from site to site reflects the high heterogeneity of hard rock aquifers.

Rock formation characterization for carbon dioxide geosequestration: 3D seismic amplitude and coherency anomalies, and seismic petrophysical facies classification, Wellington and Anson-Bates Fields, Kansas, USA

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Ohl, Derek; Raef, Abdelmoneam

2014-04-01

Higher resolution rock formation characterization is of paramount priority, amid growing interest in injecting carbon dioxide, CO2, into subsurface rock formations of depeleting/depleted hydrocarbon reservoirs or saline aquifers in order to reduce emissions of greenhouse gases. In this paper, we present a case study for a Mississippian carbonate characterization integrating post-stack seismic attributes, well log porosities, and seismic petrophysical facies classification. We evaluated changes in petrophysical lithofacies and reveal structural facies-controls in the study area. Three cross-plot clusters in a plot of well log porosity and acoustic impedance corroborated a Neural Network petrophysical facies classification, which was based on training and validation utilizing three petrophysically-different wells and three volume seismic attributes, extracted from a time window including the wavelet of the reservoir-top reflection. Reworked lithofacies along small-throw faults has been revealed based on comparing coherency and seismic petrophysical facies. The main objective of this study is to put an emphasis on reservoir characterization that is both optimized for and subsequently benefiting from pilot tertiary CO2 carbon geosequestration in a depleting reservoir and also in the deeper saline aquifer of the Arbuckle Group, south central Kansas. The 3D seismic coherency attribute, we calculated from a window embracing the Mississippian top reflection event, indicated anomalous features that can be interpreted as a change in lithofacies or faulting effect. An Artificial Neural Network (ANN) lithofacies modeling has been used to better understand these subtle features, and also provide petrophysical classes, which will benefit flow-simulation modeling and/or time-lapse seismic monitoring feasibility analysis. This paper emphasizes the need of paying greater attention to small-scale features when embarking upon characterization of a reservoir or saline-aquifer for CO2

Rock Magnetic Properties of Remagnetised Devonian and Carboniferous Carbonate and Clastic Rocks From The NE Rhenish Massif, Germany

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Zwing, A.; Matzka, J.; Bachtadse, V.; Soffel, H. C.

Previous studies on remagnetised carbonate rocks from the North American and Eu- ropean Variscides reported characteristic rock magnetic properties which are thought to be diagnostic for a chemical remagnetisation event. Their hysteresis properties with high ratios of Mrs/Ms and Hcr/Hc indicate the presence of a mixture of single-domain and superparamagnetic magnetite (Jackson, et al. 1990). In order to test if this fin- gerprint can be identified in remagnetised carbonate and clastic rocks from the NE Rhenish Massif, Germany, a series of rock magnetic experiments has been carried out. The hysteresis properties of the remagnetised clastic rocks indicate the domi- nance of large MD particles, as can be expected for detrital sediments. The carbon- ates yield significantly higher ratios of Mrs/Ms and Hcr/Hc than the clastic rocks, but only partly correspond to the characteristic properties of remagnetised carbon- ates described above. The latter might be attributed to detrital input into the carbonate platforms. Additional low-temperature remanence measurements show a wide vari- ety of phenomena, including Verwey transitions and indications for the presence of superparamagnetic grains. However, the low-temperature experiments do not allow a straightforward discrimination between the clastic and carbonate rocks and suggest more complex magnetomineralogies than expected from the hysteresis measurements alone.

Hydraulic properties and scale effects investigation in regional rock aquifers, south-western Quebec, Canada

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Nastev, M.; Savard, M. M.; Lapcevic, P.; Lefebvre, R.; Martel, R.

This paper reports on the characterization of hydraulic properties of regional rock aquifers carried out within a groundwater resources assessment project in the St. Lawrence Lowlands of south-western Quebec. To understand the aquifer behavior at both the fracture level and at field scale, hydraulic investigations were carried out using various aquifer tests. The groundwater flow at the local scale is controlled mostly by the fracture system. Results of the constant-head injection tests show a weak decreasing trend of hydraulic conductivity with depth indicating that a major part of the groundwater flow occurs in the first meters of the rock sequence. At the regional scale, the equivalent porous media approach is applicable. The hydraulic conductivity measurements were correlated to the scale of the aquifer tests expressed with the investigated aquifer volume. A simple interpolation procedure for the hydraulic conductivity field was developed based on the distance between field measurements and the tested aquifer volumes. The regional distribution of the hydraulic conductivity for the major fractured aquifer units indicates that dolostone is the most permeable whereas sandstone and crystalline rocks are the least permeable units. Este artículo trata de la caracterización de las propiedades hidráulicas en acuíferos regionales rocosos, la cual se llevó a cabo dentro del proyecto de evaluación de los recursos de agua subterránea en St. Lawrence Lowlands al suroeste de Quebec. Para entender el comportamiento del acuífero tanto a nivel de fractura como a escala del campo, se ejecutaron investigaciones hidráulicas usando varias pruebas de acuífero. El flujo del agua subterránea a escala local está controlado principalmente por el sistema de fracturas. Los resultados de las pruebas de inyección con cabeza constante muestran una tendencia decreciente débil de la conductividad hidráulica con la profundidad, indicando que la mayor parte del flujo de agua

Hydraulic conductivities of fractures and matrix in Slovenian carbonate aquifers

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Timotej Verbovšek

2008-12-01

Full Text Available Hydraulic conductivities and specific storage coefficients of fractures and matrix in Slovenian carbonate aquifers were determined by Barker’s method for pumping test analysis, based on fractional flow dimension. Values are presented for limestones and mainly for dolomites, and additionally for separate aquifers, divided by age andlithology in several groups. Data was obtained from hydrogeological reports for 397 water wells, and among these, 79 pumping tests were reinterpreted. Hydraulic conductivities of fractures are higher than the hydraulic conductivities of matrix, and the differences are highly statistically significant. Likewise, differences are significant for specific storage, and the values of these coefficients are higher in the matrix. Values of all coefficients vary in separate aquifers, and the differences can be explained by diagenetic effects, crystal size, degree of fracturing, andcarbonate purity. Comparison of the methods, used in the reports, and the Barker’s method (being more suitable for karstic and fractured aquifers, shows that the latter fits real data better.

Geologic history and hydrogeologic setting of the Edwards-Trinity aquifer system, west-central Texas

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Barker, R.A.; Bush, P.W.; Baker, E.T.

1994-01-01

The Edwards-Trinity aquifer system underlies about 42,000 square miles of west-central Texas. Nearly flat-lying, mostly Comanche (Lower Cretaceous) strata of the aquifer system thin northwestward atop massive pre-Cretaceous rocks that are comparatively impermeable and structurally complex. From predominately terrigenous clastic sediments in the east and fluvialdeltaic (terrestrial) deposits in the west, the rocks of early Trinitian age grade upward into supratidal evaporitic and dolomitic strata, intertidal limestone and dolostone, and shallow-marine, openshelf, and reefal strata of late Trinitian, Fredericksburgian, and Washitan age. A thick, downfaulted remnant of mostly open-marine strata of Eaglefordian through Navarroan age composes a small, southeastern part of the aquifer system.

Experimental study on influence of carbon dioxide on porous structure and mechanical properties of shale rock

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Danuta Miedzińska

2017-12-01

Full Text Available Shale rocks are geological formations which can be unconventional gas reservoirs. During their interaction with carbon dioxide, which can be used as a fracturing fluid in shale gas recovery process, many phenomena take place that can influence rock structure and mechanical properties. The research on changes in rock structure under super critical carbon dioxide interaction and their influence of shale properties were presented in the paper. The structural tests were carried out with the use of microscopic techniques with different resolutions of visualization. The uniaxial compression test was applied as a mechanical properties’ assessment experiment. As a result of research, some dependence was observed. The bigger decrease was in porosity after infiltration in lower zooms, the bigger increase in porosity in high zooms and mechanical properties was noticed. Keywords: geomechanics, shale rock, carbon dioxide

The role of forest trees and their mycorrhizal fungi in carbonate rock weathering and its significance for global carbon cycling.

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Thorley, Rachel M S; Taylor, Lyla L; Banwart, Steve A; Leake, Jonathan R; Beerling, David J

2015-09-01

On million-year timescales, carbonate rock weathering exerts no net effect on atmospheric CO2 concentration. However, on timescales of decades-to-centuries, it can contribute to sequestration of anthropogenic CO2 and increase land-ocean alkalinity flux, counteracting ocean acidification. Historical evidence indicates this flux is sensitive to land use change, and recent experimental evidence suggests that trees and their associated soil microbial communities are major drivers of continental mineral weathering. Here, we review key physical and chemical mechanisms by which the symbiotic mycorrhizal fungi of forest tree roots potentially enhance carbonate rock weathering. Evidence from our ongoing field study at the UK's national pinetum confirms increased weathering of carbonate rocks by a wide range of gymnosperm and angiosperm tree species that form arbuscular (AM) or ectomycorrhizal (EM) fungal partnerships. We demonstrate that calcite-containing rock grains under EM tree species weather significantly faster than those under AM trees, an effect linked to greater soil acidification by EM trees. Weathering and corresponding alkalinity export are likely to increase with rising atmospheric CO2 and associated climate change. Our analyses suggest that strategic planting of fast-growing EM angiosperm taxa on calcite- and dolomite-rich terrain might accelerate the transient sink for atmospheric CO2 and slow rates of ocean acidification. © 2014 The Authors. Plant, Cell & Environment published by John Wiley & Sons Ltd.

A study on the U speciation in groundwater of a hard rock aquifer in South India

International Nuclear Information System (INIS)

Thivya, C.; Chidambaram, S.; Thilagavathi, R.; Nepolian, M.; Adithya, V.S.; Tirumalesh, K.; Prasanna, M.V.

2015-01-01

Speciation of uranium indicates the contribution of this ion into different species. An attempt has been made to study the spatial and temporal variations of U speciation in the hard rock aquifer of South India. The major rock types have granulite facies with high grade metamorphic rocks and younger intrusive. It also comprises of Fissile hornblende biotite gneiss, Charnockite, Quartzite, Granite and Flood Plain Alluvium. A total of 108 samples were collected from the handpumps of the study area for two seasons (Pre monsoon and South West monsoon). The groundwater samples were analysed for U and other ions like Ca 2+ , Mg 2+ , Na + and K + , HCO 3 - , Cl - , SO 4 2- , PO 4 3- , NO 3 - , F - , H 4 SiO 4 , pH, EC and TDS using standard procedures

Differentiated spring behavior under changing hydrological conditions in an alpine karst aquifer

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Filippini, Maria; Squarzoni, Gabriela; De Waele, Jo; Fiorucci, Adriano; Vigna, Bartolomeo; Grillo, Barbara; Riva, Alberto; Rossetti, Stefano; Zini, Luca; Casagrande, Giacomo; Stumpp, Christine; Gargini, Alessandro

2018-01-01

Limestone massifs with a high density of dolines form important karst aquifers in most of the Alps, often with groundwater circulating through deep karst conduits and water coming out of closely spaced springs with flow rates of over some cubic meters per second. Although several hydrogeological studies and tracing experiments were carried out in many of these carbonate mountains in the past, the hydrogeology of most of these karst aquifers is still poorly known. Geological, hydrodynamic and hydrochemical investigations have been carried out in one of the most representative of these areas (Cansiglio-Monte Cavallo, NE Italy) since spring 2015, in order to enhance the knowledge on this important type of aquifer system. Additionally, a cave-to-spring multitracer test was carried out in late spring 2016 by using three different fluorescent tracers. This hydrogeological study allowed: 1) gathering new detailed information on the geological and tectonic structure of such alpine karst plateau; 2) defining discharge rates of the three main springs (Gorgazzo, Santissima, and Molinetto) by constructing rating curves; 3) understanding the discharging behavior of the system with respect to different recharge conditions; 4) better defining the recharge areas of the three springs. The three nearby springs (the spring front stretches over 5 km), that drain the investigated karst aquifer system, show different behaviors with respect to changing discharge conditions, demonstrating this aquifer to be divided in partially independent drainage systems under low-flow conditions, when their chemistry is clearly differentiated. Under high-flow conditions, waters discharging at all springs show more similar geochemical characteristics. The combination of geochemistry, hydrodynamic monitoring and dye tracing tests has shown that the three springs have different recharge areas. The study points out that even closely spaced karst springs, that apparently drain the same karst mountain, can

Bioavailability and biodegradation of weathered diesel fuel in aquifer material under denitrifying conditions

International Nuclear Information System (INIS)

Bregnard, T.P.A.; Hoehener, P.; Zeyer, J.

1998-01-01

During the in situ bioremediation of a diesel fuel-contaminated aquifer in Menziken, Switzerland, aquifer material containing weathered diesel fuel (WDF) and indigenous microorganisms was excavated. This material was used to identify factors limiting WDF biodegradation under denitrifying conditions. Incubations of this material for 360 to 390 d under denitrifying conditions resulted in degradation of 23% of the WDF with concomitant consumption of NO 3 - and production of inorganic carbon. The biodegradation of WDF and the rate of NO 3 - consumption was stimulated by agitation of the microcosms. Biodegradation was not stimulated by the addition of a biosurfactant (rhamnolipids) or a synthetic surfactant (Triton X-100) at concentrations above their critical micelle concentrations. The rhamnolipids were biodegraded preferentially to WDF, whereas Triton X-100 was not degraded. Both surfactants reduced the surface tension of the growth medium from 72 to <35 dynes/cm and enhanced the apparent aqueous solubility of the model hydrocarbon n-hexadecane by four orders of magnitude. Solvent-extracted WDF, added at a concentration equal to that already present in the aquifer material, was also biodegraded by the microcosms, but not at a higher rate than the WDF already present in the material. The results show that the denitrifying biodegradation of WDF is not necessarily limited by bioavailability but rather by the inherent recalcitrance of WDF

Qualitative and Quantitative Changes of Carbonate Rocks Exposed to SC CO2 (Basque-Cantabrian Basin, Northern Spain

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Edgar Berrezueta

2017-11-01

Full Text Available This study aims at the qualitative and quantitative determination of porosity, mineralogical and textural changes in carbonate rock samples after injection of (i supercritical CO2-rich brine and (ii dry supercritical CO2, under similar experimental conditions (P ≈ 75 bar, T ≈ 35 °C, 970 h exposure time and no CO2 flow. The studied rocks were sampled in the western Basque-Cantabrian Basin, North Spain, and consist of vuggy carbonates (“Carniolas” of the Puerto de la Palombera formation (Hettangian. Mineralogical and pore space characterization is completed using optical microscopy, scanning electron microscopy and optical image analysis. In addition, X-ray fluorescence analyses are performed to refine the mineralogical information and to obtain whole rock geochemical data and the brine composition is analysed before and after the experiment. Mineralogical and chemical results indicate that the carbonate rocks exposed to supercritical CO2 in dry conditions do not suffer significant changes. However, the injection of supercritical CO2-rich brine induces chemical and physical changes in the rock due to the high reactivity of calcite at the low pH conditions produced by the acidified brine. Numerical modelling validates the experimental observations. These results can be used to characterize the behaviour of carbonate rocks under conditions similar to the vicinity of a CO2 injection well. The results should be considered only at the scale of the studied samples and not at reservoir scale.

Experimental studies of the deformation of carbonated rocks by dissolution crystallization under stress

International Nuclear Information System (INIS)

Zubtsov, Sergey

2003-01-01

The first part of this research thesis reports the experimental investigation and the modelling of the deformation of poly-mineral rocks under the influence of mechanism of dissolution-crystallization under stress. This mechanism has a significant role in the compaction of sedimentary rocks, in the folding process of the earth's crust. The author notably reports the results of the experimental deformation of calcite in presence of water (calcite is present in marls in which the deposit of nuclear wastes in planned in France). The second part deals with the fact that healing is possible between two grains of similar mineralogy, and slows down or even stops deformation

Arsenic mobility in groundwater/surface water systems in carbonate-rich Pleistocene glacial drift aquifers (Michigan)

International Nuclear Information System (INIS)

Szramek, Kathryn; Walter, Lynn M.; McCall, Patti

2004-01-01

waters have very low As and Fe contents, consistent with the stability of oxyhydroxides under oxidizing vadose conditions. When CO 2 charged groundwaters discharge in streams and fens, dissolved As is effectively removed by adsorption onto Fe-oxides or carbonate marls. Although Fe does not display conservative behavior with As in groundwaters, a strong positive correlation exists between As and Sr concentrations. As water-rock interactions proceed, the As/Fe and Sr/Ca ratios would be expected to increase because both As and Sr behave as incompatible elements. Comparisons with groundwater chemistries from other drift-hosted aquifers proximate to the Marshall sandstone are consistent with these relations. Thus, the Sr content of carbonate-rich groundwaters may provide useful constraints on the occurrence, origin and evolution of dissolved As in such systems

Interlaboratory study of a method for determining nonvolatile organic carbon in aquifer materials

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Caughey, M.E.; Barcelona, M.J.; Powell, R.M.; Cahill, R.A.; Gron, C.; Lawrenz, D.; Meschi, P.L.

1995-01-01

The organic carbon fraction in aquifer materials exerts a major influence on the subsurface mobilities of organic and organic-associated contaminants. The spatial distribution of total organic carbon (TOC) in aquifer materials must be determined before the transport of hydrophobic organic pollutants in aquifers can be modeled accurately. Previous interlaboratory studies showed that it is difficult to measure TOC concentrations 1%. We have tested a new analytical method designed to improve the accuracy and precision of nonvolatile TOC quantitation in geologic materials that also contain carbonate minerals. Four authentic aquifer materials and one NIST standard reference material were selected as test materials for a blind collaborative study. Nonvolatile TOC in these materials ranged from 0.05 to 1.4%, while TIC ranged from 0.46 to 12.6%. Sample replicates were digested with sulfurous acid, dried at 40??C, and then combusted at 950??C using LECO or UIC instruments. For the three test materials that contained >2% TIC, incomplete acidification resulted in a systematic positive bias of TOC values reported by five of the six laboratories that used the test method. Participants did not have enough time to become proficient with the new method before they analyzed the test materials. A seventh laboratory successfully used an alternative method that analyzed separate liquid and solid fractions of the acidified sample residues. ?? 1995 Springer-Verlag.

Resistivity method contribution in determining of fault zone and hydro-geophysical characteristics of carbonate aquifer, eastern desert, Egypt

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Ammar, A. I.; Kamal, K. A.

2018-03-01

Determination of fault zone and hydro-geophysical characteristics of the fractured aquifers are complicated, because their fractures are controlled by different factors. Therefore, 60 VESs were carried out as well as 17 productive wells for determining the locations of the fault zones and the characteristics of the carbonate aquifer at the eastern desert, Egypt. The general curve type of the recorded rock units was QKH. These curves were used in delineating the zones of faults according to the application of the new assumptions. The main aquifer was included at end of the K-curve type and front of the H-curve type. The subsurface layers classified into seven different geoelectric layers. The fractured shaly limestone and fractured limestone layers were the main aquifer and their resistivity changed from low to medium (11-93 Ω m). The hydro-geophysical properties of this aquifer such as the areas of very high, high, and intermediate fracture densities of high groundwater accumulations, salinity, shale content, porosity distribution, and recharging and flowing of groundwater were determined. The statistical analysis appeared that depending of aquifer resistivity on the water salinities (T.D.S.) and water resistivities add to the fracture density and shale content. The T.D.S. increasing were controlled by Na+, Cl-, Ca2+, Mg2+, and then (SO4)2-, respectively. The porosity was calculated and its average value was 19%. The hydrochemical analysis of groundwater appeared that its type was brackish and the arrangements of cation concentrations were Na+ > Ca2+ > Mg2+ > K+ and anion concentrations were Cl- > (SO4)2- > HCO3 - > CO3 -. The groundwater was characterized by sodium-bicarbonate and sodium-sulfate genetic water types and meteoric in origin. Hence, it can use the DC-resistivity method in delineating the fault zone and determining the hydro-geophysical characteristics of the fractured aquifer with taking into account the quality of measurements and interpretation.

Carbonation by fluid-rock interactions at high-pressure conditions: Implications for carbon cycling in subduction zones

Science.gov (United States)

Piccoli, Francesca; Vitale Brovarone, Alberto; Beyssac, Olivier; Martinez, Isabelle; Ague, Jay J.; Chaduteau, Carine

2016-07-01

Carbonate-bearing lithologies are the main carbon carrier into subduction zones. Their evolution during metamorphism largely controls the fate of carbon, regulating its fluxes between shallow and deep reservoirs. Recent estimates predict that almost all subducted carbon is transferred into the crust and lithospheric mantle during subduction metamorphism via decarbonation and dissolution reactions at high-pressure conditions. Here we report the occurrence of eclogite-facies marbles associated with metasomatic systems in Alpine Corsica (France). The occurrence of these marbles along major fluid-conduits as well as textural, geochemical and isotopic data indicating fluid-mineral reactions are compelling evidence for the precipitation of these carbonate-rich assemblages from carbonic fluids during metamorphism. The discovery of metasomatic marbles brings new insights into the fate of carbonic fluids formed in subducting slabs. We infer that rock carbonation can occur at high-pressure conditions by either vein-injection or chemical replacement mechanisms. This indicates that carbonic fluids produced by decarbonation reactions and carbonate dissolution may not be directly transferred to the mantle wedge, but can interact with slab and mantle-forming rocks. Rock-carbonation by fluid-rock interactions may have an important impact on the residence time of carbon and oxygen in subduction zones and lithospheric mantle reservoirs as well as carbonate isotopic signatures in subduction zones. Furthermore, carbonation may modulate the emission of CO2 at volcanic arcs over geological time scales.

Modeling carbon dioxide sequestration in saline aquifers: Significance of elevated pressures and salinities

International Nuclear Information System (INIS)

Allen, D.E.; Strazisar, B.R.; Soong, Y.; Hedges, S.W.

2005-01-01

The ultimate capacity of saline formations to sequester carbon dioxide by solubility and mineral trapping must be determined by simulating sequestration with geochemical models. These models, however, are only as reliable as the data and reaction scheme on which they are based. Several models have been used to make estimates of carbon dioxide solubility and mineral formation as a function of pressure and fluid composition. Intercomparison of modeling results indicates that failure to adjust all equilibrium constants to account for elevated carbon dioxide pressures results in significant errors in both solubility and mineral formation estimates. Absence of experimental data at high carbon dioxide pressures and high salinities make verification of model results difficult. Results indicate standalone solubility models that do not take mineral reactions into account will underestimate the total capacity of aquifers to sequester carbon dioxide in the long term through enhanced solubility and mineral trapping mechanisms. Overall, it is difficult to confidently predict the ultimate sequestration capacity of deep saline aquifers using geochemical models. (author)

Integrated Experimental and Modeling Studies of Mineral Carbonation as a Mechanism for Permanent Carbon Sequestration in Mafic/Ultramafic Rocks

Energy Technology Data Exchange (ETDEWEB)

Wang, Zhengrong [Yale Univ., New Haven, CT (United States); Qiu, Lin [Yale Univ., New Haven, CT (United States); Zhang, Shuang [Yale Univ., New Haven, CT (United States); Bolton, Edward [Yale Univ., New Haven, CT (United States); Bercovici, David [Yale Univ., New Haven, CT (United States); Ague, Jay [Yale Univ., New Haven, CT (United States); Karato, Shun-Ichiro [Yale Univ., New Haven, CT (United States); Oristaglio, Michael [Yale Univ., New Haven, CT (United States); Zhu, Wen-Iu [Univ. of Maryland, College Park, MD (United States); Lisabeth, Harry [Univ. of Maryland, College Park, MD (United States); Johnson, Kevin [Univ. of Hawaii, Honolulu, HI (United States)

2014-09-30

A program of laboratory experiments, modeling and fieldwork was carried out at Yale University, University of Maryland, and University of Hawai‘i, under a DOE Award (DE-FE0004375) to study mineral carbonation as a practical method of geologic carbon sequestration. Mineral carbonation, also called carbon mineralization, is the conversion of (fluid) carbon dioxide into (solid) carbonate minerals in rocks, by way of naturally occurring chemical reactions. Mafic and ultramafic rocks, such as volcanic basalt, are natural candidates for carbonation, because the magnesium and iron silicate minerals in these rocks react with brines of dissolved carbon dioxide to form carbonate minerals. By trapping carbon dioxide (CO₂) underground as a constituent of solid rock, carbonation of natural basalt formations would be a secure method of sequestering CO₂ captured at power plants in efforts to mitigate climate change. Geochemical laboratory experiments at Yale, carried out in a batch reactor at 200°C and 150 bar (15 MPa), studied carbonation of the olivine mineral forsterite (Mg₂SiO₄) reacting with CO₂ brines in the form of sodium bicarbonate (NaHCO₃) solutions. The main carbonation product in these reactions is the carbonate mineral magnesite (MgCO₃). A series of 32 runs varied the reaction time, the reactive surface area of olivine grains and powders, the concentration of the reacting fluid, and the starting ratio of fluid to olivine mass. These experiments were the first to study the rate of olivine carbonation under passive conditions approaching equilibrium. The results show that, in a simple batch reaction, olivine carbonation is fastest during the first 24 hours and then slows significantly and even reverses. A natural measure of the extent of carbonation is a quantity called the carbonation fraction, which compares the amount of carbon removed from solution, during a run, to the maximum amount

Uranium Isotopes as a Tracer of Groundwater Evolution in the Complexe Terminal Aquifer of Southern Tunisia

Energy Technology Data Exchange (ETDEWEB)

Hadj Ammar, F. [Laboratory of Radio-Analysis and Environment, National School of Engineering of Sfax, Sfax (Tunisia); Centre Europeen de Recherche et d' Enseignement de Geosciences de l' Environnement, Aix en Provence (France); Deschamps, P.; Hamelin, B. [Centre Europeen de Recherche et d' Enseignement de Geosciences de l' Environnement, Aix en Provence (France); Chkir, N.; Zouari, K. [Laboratory of Radio-Analysis and Environment, National School of Engineering of Sfax, Sfax (Tunisia)

2013-07-15

The Complexe Terminal (CT) aquifer system is the main water supply for remote areas of southern Tunisia. Its exploitation has resulted in significant draw-down of the water table. The CT aquifer is a multilayered aquifer lodged in Miocene sand deposits, Senonian limestones and Turonian carbonates. Little is known about the relationships and exchanges between the different layers. Here, uranium isotopic measurements carried out in groundwater samples from the CT aquifer are presented in order to constrain models for mixing of water masses, water-rock interaction and groundwater flow. Analyses were performed using a VG54 (TIMS) at the CEREGE. Results indicate a range in {sup 238}U concentration and {sup 234}U/{sup 238}U activity ratios of 1.5 to 8 ppb and 1.1 to 3.2 respectively. Together with major and trace analyses, uranium isotopic compositions provide important insights into the factors controlling the chemical evolution of groundwater and shows very distinct patterns between carbonate and sandstone layers. (author)

Carbon Sequestration in Saline Aquifers: Modeling Diffusive and Convective Transport Of a Carbon-­Dioxide Cap

KAUST Repository

Allen, Rebecca

2011-05-01

An increase in the earth’s surface temperature has been directly linked to the rise of carbon dioxide (CO2) levels In the atmosphere and an enhanced greenhouse effect. CO2 sequestration is one of the proposed mitigation Strategies in the effort to reduce atmospheric CO2 concentrations. Globally speaking, saline aquifers provide an adequate storage capacity for the world’s carbon emissions, and CO2 sequestration projects are currently underway in countries such as Norway, Germany, Japan, USA, and others. Numerical simulators serve as predictive tools for CO2 storage, yet must model fluid transport behavior while coupling different transport processes together accurately. With regards to CO2 sequestration, an extensive amount of research has been done on the diffusive-convective transport that occurs under a cap of CO2-saturated fluid, which results after CO2 is injected into an aquifer and spreads laterally under an area of low permeability. The diffusive-convective modeling reveals an enhanced storage capacity in saline aquifers, due to the density increase between pure fluid and CO2‐saturated fluid. This work presents the transport modeling equations that are used for diffusive- convective modeling. A cell-centered finite difference method is used, and simulations are run using MATLAB. Two cases are explored in order to compare the results from this work’s self-generated code with the results published in literature. Simulation results match relatively well, and the discrepancy for a delayed onset time of convective transport observed in this work is attributed to numerical artifacts. In fact, onset time in this work is directly attributed to the instability of the physical system: this instability arises from non-linear coupling of fluid flow, transport, and convection, but is triggered by numerical errors in these simulations. Results from this work enable the computation of a value for the numerical constant that appears in the onset time equation that

Megaporosity and permeability of Thalassinoides-dominated ichnofabrics in the Cretaceous karst-carbonate Edwards-Trinity aquifer system, Texas

Science.gov (United States)

Cunningham, Kevin J.; Sukop, Michael C.

2012-01-01

Current research has demonstrated that trace fossils and their related ichnofabrics can have a critical impact on the fluid-flow properties of hydrocarbon reservoirs and groundwater aquifers. Most petroleum-associated research has used ichnofabrics to support the definition of depositional environments and reservoir quality, and has concentrated on siliciclastic reservoir characterization and, to a lesser degree, carbonate reservoir characterization (for example, Gerard and Bromley, 2008; Knaust, 2009). The use of ichnology in aquifer characterization has almost entirely been overlooked by the hydrologic community because the dynamic reservoir-characterization approach has not caught on with hydrologists and so hydrology is lagging behind reservoir engineering in this area (de Marsily and others, 2005). The objective of this research is to show that (1) ichnofabric analysis can offer a productive methodology for purposes of carbonate aquifer characterization, and (2) a clear relation can exist between ichnofabrics and groundwater flow in carbonate aquifers.

Digital Rock Simulation of Flow in Carbonate Samples

Science.gov (United States)

Klemin, D.; Andersen, M.

2014-12-01

Reservoir engineering has becomes more complex to deal with current challenges, so core analysts must understand and model pore geometries and fluid behaviors at pores scales more rapidly and realistically. We introduce an industry-unique direct hydrodynamic pore flow simulator that operates on pore geometries from digital rock models obtained using microCT or 3D scanning electron microscope (SEM) images. The PVT and rheological models used in the simulator represent real reservoir fluids. Fluid-solid interactions are introduced using distributed micro-scale wetting properties. The simulator uses density functional approach applied for hydrodynamics of complex systems. This talk covers selected applications of the simulator. We performed microCT scanning of six different carbonate rock samples from homogeneous limestones to vuggy carbonates. From these, we constructed digital rock models representing pore geometries for the simulator. We simulated nonreactive tracer flow in all six digital models using a digital fluid description that included a passive tracer solution. During the simulation, we evaluated the composition of the effluent. Results of tracer flow simulations corresponded well with experimental data of nonreactive tracer floods for the same carbonate rock types. This simulation data of the non-reactive tracer flow can be used to calculate the volume of the rock accessible by the fluid, which can be further used to predict response of a porous medium to a reactive fluid. The described digital core analysis workflow provides a basis for a wide variety of activities, including input to design acidizing jobs and evaluating treatment efficiency and EOR economics. Digital rock multiphase flow simulations of a scanned carbonate rock evaluated the effect of wettability on flow properties. Various wetting properties were tested: slightly oil wet, slightly water wet, and water wet. Steady-state relative permeability simulations yielded curves for all three

Soil aquifer treatment of artificial wastewater under saturated conditions

KAUST Repository

Essandoh, H. M K

2011-05-01

A 2000 mm long saturated laboratory soil column was used to simulate soil aquifer treatment under saturated conditions to assess the removal of chemical and biochemical oxygen demand (COD and BOD), dissolved organic carbon (DOC), nitrogen and phosphate, using high strength artificial wastewater. The removal rates were determined under a combination of constant hydraulic loading rates (HLR) and variable COD concentrations as well as variable HLR under a constant COD. Within the range of COD concentrations considered (42 mg L-1-135 mg L-1) it was found that at fixed hydraulic loading rate, a decrease in the influent concentrations of dissolved organic carbon (DOC), biochemical oxygen demand (BOD), total nitrogen and phosphate improved their removal efficiencies. At the high COD concentrations applied residence times influenced the redox conditions in the soil column. Long residence times were detrimental to the removal process for COD, BOD and DOC as anoxic processes and sulphate reduction played an important role as electron acceptors. It was found that total COD mass loading within the range of 911 mg d-1-1780 mg d-1 applied as low COD wastewater infiltrated coupled with short residence times would provide better effluent quality than the same mass applied as a COD with higher concentration at long residence times. The opposite was true for organic nitrogen where relatively high concentrations coupled with long residence time gave better removal efficiency. © 2011.

Lower Paleozoic carbonate rocks of Baird Mountains Quadrangle, Alaska

Energy Technology Data Exchange (ETDEWEB)

Dumoulin, J.A.; Harris, A.G.

1985-04-01

Lower Paleozoic carbonate rocks in the Baird Mountains quadrangle form a relatively thin (about 550 m), chiefly shallow-water succession that has been imbricately thrust and metamorphosed to lower greenschist facies. Middle and Upper Cambrian rocks - the first reported from the western Brooks Range - occur in the northeastern quarter of the quadrangle, south of Angayukaqsraq (formerly Hub) Mountain. They consist of marble grading upward into thin-bedded marble/dolostone couplets and contain pelagiellid mollusks, acetretid brachiopods, and agnostid trilobites. Sedimentologic features and the Pelagiellas indicate a shallow-water depositional environment. Overlying these rocks are Lower and Middle Ordovician marble and phyllite containing graptolites and conodonts of midshelf to basinal aspect. Upper Ordovician rocks in this area are bioturbated to laminated dolostone containing warm, shallow-water conodonts. In the Omar and Squirrel Rivers areas to the west, the Lower Ordovician carbonate rocks show striking differences in lithofacies, biofacies, and thickness. Here they are mainly dolostone with locally well-developed fenestral fabric and evaporite molds, and bioturbated to laminated orange- and gray-weathering dolomitic marble. Upper Silurian dolostone, found near Angayukaqsraq Mountain and on the central Squirrel River, contains locally abundant corals and stronmatoporoids. Devonian carbonate rocks are widely distributed in the Baird Mountains quadrangle; at least two distinct sequences have been identified. In the Omar area, Lower and Middle Devonian dolostone and marble are locally cherty and rich in megafossils. In the north-central (Nakolik River) area, Middle and Upper Devonian marble is interlayered with planar to cross-laminated quartz-carbonate metasandstone and phyllite.

Microbial and geochemical investigations of dissolved organic carbon and microbial ecology of native waters from the Biscayne and Upper Floridan Aquifers

Science.gov (United States)

Lisle, John T.; Harvey, Ron W.; Aiken, George R.; Metge, David W.

2010-01-01

Groundwater resources in the United States are under ever-increasing demands for potable, irrigation, and recreational uses. Additionally, aquifer systems are being used or targeted for use as storage areas for treated surface waters and (or) groundwaters via injection (for example, aquifer storage and recovery). To date, the influence that the nutrients, including carbon, in the injected water have on native microbial communities and the biogeochemistry in the subsurface zones used for storage of the injectate has not been determined. In this report, we describe a series of experiments that establishes a baseline dataset for the quantity and quality of organic and inorganic carbon and nutrients in the Biscayne Aquifer (BA) and Upper Floridan Aquifer (UFA) in south Florida. The most significant differences between the BA (26 meters below surface) and UFA (366 meters below surface) are the average specific conductance (0.552 and 6.12 microsiemens per centimeter, respectively), dissolved oxygen (1.6 and 0 milligrams per liter, respectively), and oxidation-reduction potential (40.3 and -358 millivolts, respectively). The dissolved organic carbon from the BA is characterized by carbon originating from terrestrial sources and microbial activities, while the UFA has a distinctive microbial signature. Acetate and lactate are the dominant carbon constituents in both aquifers. Additionally, components of the dissolved organic carbon from the UFA have a total trihalomethane-formation potential that is approximately threefold greater than the maximum contaminat level of 80 micrograms per liter established by the U.S. Environmental Protection Agency. The average native bacterial abundances in the aquifers are similar with 4.69x10^4 cells per milliliter in the BA and 1.33x10^4 cells per milliliter in the UFA. The average bacteriophage abundances are also similar with 1.15x10^5 virus-like particles in the BA and 1.92x10^5 virus-like particles in the UFA. Interestingly, ciliated

Fluoride in weathered rock aquifers of southern India: Managed Aquifer Recharge for mitigation.

Science.gov (United States)

Brindha, K; Jagadeshan, G; Kalpana, L; Elango, L

2016-05-01

Climatic condition, geology, and geochemical processes in an area play a major role on groundwater quality. Impact of these on the fluoride content of groundwater was studied in three regions-part of Nalgonda district in Telangana, Pambar River basin, and Vaniyar River basin in Tamil Nadu, southern India, which experience semi-arid climate and are predominantly made of Precambrian rocks. High concentration of fluoride in groundwater above 4 mg/l was recorded. Human exposure dose for fluoride through groundwater was higher in Nalgonda than the other areas. With evaporation and rainfall being one of the major contributors for high fluoride apart from the weathering of fluoride rich minerals from rocks, the effect of increase in groundwater level on fluoride concentration was studied. This study reveals that groundwater in shallow environment of all three regions shows dilution effect due to rainfall recharge. Suitable managed aquifer recharge (MAR) methods can be adopted to dilute the fluoride rich groundwater in such regions which is explained with two case studies. However, in deep groundwater, increase in fluoride concentration with increase in groundwater level due to leaching of fluoride rich salts from the unsaturated zone was observed. Occurrence of fluoride above 1.5 mg/l was more in areas with deeper groundwater environment. Hence, practicing MAR in these regions will increase the fluoride content in groundwater and so physical or chemical treatment has to be adopted. This study brought out the fact that MAR cannot be practiced in all regions for dilution of ions in groundwater and that it is essential to analyze the fluctuation in groundwater level and the fluoride content before suggesting it as a suitable solution. Also, this study emphasizes that long-term monitoring of these factors is an important criterion for choosing the recharge areas.

Regional potentiometric-surface map of the Great Basin carbonate and alluvial aquifer system in Snake Valley and surrounding areas, Juab, Millard, and Beaver Counties, Utah, and White Pine and Lincoln Counties, Nevada

Science.gov (United States)

Gardner, Philip M.; Masbruch, Melissa D.; Plume, Russell W.; Buto, Susan G.

2011-01-01

Water-level measurements from 190 wells were used to develop a potentiometric-surface map of the east-central portion of the regional Great Basin carbonate and alluvial aquifer system in and around Snake Valley, eastern Nevada and western Utah. The map area covers approximately 9,000 square miles in Juab, Millard, and Beaver Counties, Utah, and White Pine and Lincoln Counties, Nevada. Recent (2007-2010) drilling by the Utah Geological Survey and U.S. Geological Survey has provided new data for areas where water-level measurements were previously unavailable. New water-level data were used to refine mapping of the pathways of intrabasin and interbasin groundwater flow. At 20 of these locations, nested observation wells provide vertical hydraulic gradient data and information related to the degree of connection between basin-fill aquifers and consolidated-rock aquifers. Multiple-year water-level hydrographs are also presented for 32 wells to illustrate the aquifer system's response to interannual climate variations and well withdrawals.

GIS database and discussion for the distribution, composition, and age of Cenozoic volcanic rocks of the Pacific Northwest Volcanic Aquifer System study area

Science.gov (United States)

Sherrod, David R.; Keith, Mackenzie K.

2018-03-30

A substantial part of the U.S. Pacific Northwest is underlain by Cenozoic volcanic and continental sedimentary rocks and, where widespread, these strata form important aquifers. The legacy geologic mapping presented with this report contains new thematic categorization added to state digital compilations published by the U.S. Geological Survey for Oregon, California, Idaho, Nevada, Utah, and Washington (Ludington and others, 2005). Our additional coding is designed to allow rapid characterization, mainly for hydrogeologic purposes, of similar rocks and deposits within a boundary expanded slightly beyond that of the Pacific Northwest Volcanic Aquifer System study area. To be useful for hydrogeologic analysis and to be more statistically manageable, statewide compilations from Ludington and others (2005) were mosaicked into a regional map and then reinterpreted into four main categories on the basis of (1) age, (2) composition, (3) hydrogeologic grouping, and (4) lithologic pattern. The coding scheme emphasizes Cenozoic volcanic or volcanic-related rocks and deposits, and of primary interest are the codings for composition and age.

Bioremediation in fractured rock: 2. Mobilization of chloroethene compounds from the rock matrix

Science.gov (United States)

Shapiro, Allen M.; Tiedeman, Claire; Imbrigiotta, Thomas; Goode, Daniel J.; Hsieh, Paul A.; Lacombe, Pierre; DeFlaun, Mary F.; Drew, Scott R.; Curtis, Gary P.

2018-01-01

A mass balance is formulated to evaluate the mobilization of chlorinated ethene compounds (CE) from the rock matrix of a fractured mudstone aquifer under pre- and postbioremediation conditions. The analysis relies on a sparse number of monitoring locations and is constrained by a detailed description of the groundwater flow regime. Groundwater flow modeling developed under the site characterization identified groundwater fluxes to formulate the CE mass balance in the rock volume exposed to the injected remediation amendments. Differences in the CE fluxes into and out of the rock volume identify the total CE mobilized from diffusion, desorption, and nonaqueous phase liquid dissolution under pre- and postinjection conditions. The initial CE mass in the rock matrix prior to remediation is estimated using analyses of CE in rock core. The CE mass mobilized per year under preinjection conditions is small relative to the total CE mass in the rock, indicating that current pump-and-treat and natural attenuation conditions are likely to require hundreds of years to achieve groundwater concentrations that meet regulatory guidelines. The postinjection CE mobilization rate increased by approximately an order of magnitude over the 5 years of monitoring after the amendment injection. This rate is likely to decrease and additional remediation applications over several decades would still be needed to reduce CE mass in the rock matrix to levels where groundwater concentrations in fractures achieve regulatory standards.

Hydrologic properties and ground-water flow systems of the Paleozoic rocks in the upper Colorado River basin in Arizona, Colorado, New Mexico, Utah, and Wyoming, excluding the San Juan Basin

Science.gov (United States)

Geldon, Arthur L.

2003-01-01

The hydrologic properties and ground-water flow systems of Paleozoic sedimentary rocks in the Upper Colorado River Basin were investigated under the Regional Aquifer-System Analysis (RASA) program of the U.S. Geological Survey in anticipation of the development of water supplies from bedrock aquifers to fulfill the region's growing water demands. The study area, in parts of Arizona, Colorado, New Mexico, Utah, and Wyoming, covers about 100,000 square miles. It includes parts of four physiographic provinces--the Middle Rocky Mountains, Wyoming Basin, Southern Rocky Mountains, and Colorado Plateaus. A variety of landforms, including mountains, plateaus, mesas, cuestas, plains, badlands, and canyons, are present. Altitudes range from 3,100 to 14,500 feet. Precipitation is distributed orographically and ranges from less than 6 inches per year at lower altitudes to more than 60 inches per year in some mountainous areas. Most of the infrequent precipitation at altitudes of less than 6,000 feet is consumed by evapotranspiration. The Colorado and Green Rivers are the principal streams: the 1964-82 average discharge of the Colorado River where it leaves the Upper Colorado River Basin is 12,170 cubic feet per second (a decrease of 5,680 cubic feet per second since construction of Glen Canyon Dam in 1963). On the basis of their predominant lithologic and hydrologic properties, the Paleozoic rocks are classified into four aquifers and three confining units. The Flathead aquifer, Gros Ventre confining unit, Bighorn aquifer, Elbert-Parting confining unit, and Madison aquifer (Redwall-Leadville and Darwin-Humbug zones) make up the Four Corners aquifer system. A thick sequence, composed mostly of Mississippian and Pennsylvanian shale, anhydrite, halite, and carbonate rocks--the Four Corners confining unit (Belden-Molas and Paradox-Eagle Valley subunits)--overlies the Four Corners aquifer system in most areas and inhibits vertical ground-water flow between the Four Corners aquifer

AQUIFER OF THE WESTERN PART OF THE PRGOVO POLJE ON THE ISLAND OF LASTOVO

Directory of Open Access Journals (Sweden)

Renato Buljan

2006-12-01

Full Text Available Two new-drilled wells in the Prgovo Polje are pumped and additionally tested for the water supply of the island Lastovo. The research works were aimed at finding boundary quantitative and qualitative parameters for their optimal exploitation, desalination and use of the pumped water in the existent water supply system. Collected hydrogeological and hydrogeochemical data indicate the presence of stratified aquifer in the western part of Prgovo Polje consisting of two poorly connected horizons. Water from the shallower part of the aquifer, drilled by the well MZ-2 in the carbonate rocks at the edge of polje, is good enough for desalination. The deeper part of aquifer, drilled by the well MZ-1 in the carbonate cavern below the polje’s clastic sediments, experiences the greater influence of the sea water. Its continuing pumping combined with low quantity of water is the main reason of the ever increasing influence of the sea water (the paper is published in Croatian.

Fate of the herbicide glufosinate-ammonium in the sandy, low-organic-carbon aquifer at CFB Borden, Ontario, Canada

Science.gov (United States)

Allen-King, Richelle M.; Butler, Barbara J.; Reichert, Barbara

1995-04-01

The herbicide glufosinate-ammonium was persistent in aerobic sandy aquifer material in laboratory batch and field in situ microcosms when added at concentrations of 50-400 μg L -1. In contrast, the compound is biotransformed relatively quickly in surface soil. Glufosinate transformation and metabolite (3-methylphosphinyl-propionic acid) production in carbonamended laboratory microcosms demonstrated that the aquifer system was carbon-limited with respect to glufosinate transformation. Microbiological test showed that flufosinateammonium and sodium-glufosinate was be used as a nitrogen source, in the presence of sufficient carbon. Glufosinate was not used by the native microorganisms as a source of phosphorus, nor metabolized as a sole carbon and energy source. Ammonium appeared to be preferred over glufosinate as a nitrogen source. When representative microbial strains isolated from the Borden aquifer were tested, most were glufosinate-ammonium tolerant. Complete inhibition of some isolates was demonstrated only at very high concentrations of 2-4 g L -1. The research suggests that in an aquifer with a relatively low clay content and little labile organic carbon, such as the sandy aquifer at the field site, glufosinate will be persistent and transport will be essentially unretarded. The availability of alternative nitrogen sources was also indicated as a parameter that can affect persistence.

Aquifer configuration and geostructural links control the groundwater quality in thin-bedded carbonate-siliciclastic alternations of the Hainich CZE, central Germany

Science.gov (United States)

Kohlhepp, Bernd; Lehmann, Robert; Seeber, Paul; Küsel, Kirsten; Trumbore, Susan E.; Totsche, Kai U.

2017-12-01

The quality of near-surface groundwater reservoirs is controlled, but also threatened, by manifold surface-subsurface interactions. Vulnerability studies typically evaluate the variable interplay of surface factors (land management, infiltration patterns) and subsurface factors (hydrostratigraphy, flow properties) in a thorough way, but disregard the resulting groundwater quality. Conversely, hydrogeochemical case studies that address the chemical evolution of groundwater often lack a comprehensive analysis of the structural buildup. In this study, we aim to reconstruct the actual spatial groundwater quality pattern from a synoptic analysis of the hydrostratigraphy, lithostratigraphy, pedology and land use in the Hainich Critical Zone Exploratory (Hainich CZE). This CZE represents a widely distributed yet scarcely described setting of thin-bedded mixed carbonate-siliciclastic strata in hillslope terrains. At the eastern Hainich low-mountain hillslope, bedrock is mainly formed by alternated marine sedimentary rocks of the Upper Muschelkalk (Middle Triassic) that partly host productive groundwater resources. Spatial patterns of the groundwater quality of a 5.4 km long well transect are derived by principal component analysis and hierarchical cluster analysis. Aquifer stratigraphy and geostructural links were deduced from lithological drill core analysis, mineralogical analysis, geophysical borehole logs and mapping data. Maps of preferential recharge zones and recharge potential were deduced from digital (soil) mapping, soil survey data and field measurements of soil hydraulic conductivities (Ks). By attributing spatially variable surface and subsurface conditions, we were able to reconstruct groundwater quality clusters that reflect the type of land management in their preferential recharge areas, aquifer hydraulic conditions and cross-formational exchange via caprock sinkholes or ascending flow. Generally, the aquifer configuration (spatial arrangement of strata

Evolution of Uranium Isotopic Compositions of the Groundwater and Rock in a Sandy-Clayey Aquifer

Directory of Open Access Journals (Sweden)

Alexander I. Malov

2017-11-01

Full Text Available Uranium isotopes have been used as mechanistic or time scale tracers of natural processes. This paper describes the occurrence and redistribution of U in the Vendian aquifer of a paleo-valley in NW Russia. Forty-four rock samples were collected from nine boreholes with depths up to 160 m, and 25 groundwater samples were collected from 23 boreholes with depths up to 300 m. The U, Fe concentration, and 234U/238U activity ratio were determined in the samples. Estimations were made of the 14C and 234U-238U residence time of groundwater in the aquifer. It has been established that the processes of chemical weathering of Vendian deposits led to the formation of a strong oxidation zone, developed above 250 m.b.s.l. The inverse correlation between the concentrations of uranium and iron is a result of removal of U from paleo-valley slopes in oxidizing conditions, accumulation of U at the bottom of the paleo-valley in reducing conditions, and accumulation of Fe on the slopes and removal from the bottom of the paleo-valley. Almost all U on the slopes has been replaced by a newly formed hydrogenic U with a higher 234U/238U activity ratio. After, dissolution and desorption of hydrogenic U occurred from the slopes during periods with no glaciations and marine transgressions. Elevated concentrations of U are preserved in reduced lenses at the paleo-valley bottom. In these areas, the most dangerous aspect is the flow of groundwater from the underlying horizons, since during the operation of water supply wells it can lead to the creation of local zones of oxidizing conditions in the perforated screens zone and the transition of uranium into solution. For groundwater under oxidizing conditions, an increase in the concentration of uranium is characteristic of an increase in the residence time (age of water in the aquifer. Also, the 234U/238U activity ratio increases with increasing radioactivity of groundwater. Therefore, the most rational approach is to use

Rock burst governance of working face under igneous rock

Science.gov (United States)

Chang, Zhenxing; Yu, Yue

2017-01-01

As a typical failure phenomenon, rock burst occurs in many mines. It can not only cause the working face to cease production, but also cause serious damage to production equipment, and even result in casualties. To explore how to govern rock burst of working face under igneous rock, the 10416 working face in some mine is taken as engineering background. The supports damaged extensively and rock burst took place when the working face advanced. This paper establishes the mechanical model and conducts theoretical analysis and calculation to predict the fracture and migration mechanism and energy release of the thick hard igneous rock above the working face, and to obtain the advancing distance of the working face when the igneous rock fractures and critical value of the energy when rock burst occurs. Based on the specific conditions of the mine, this paper put forward three kinds of governance measures, which are borehole pressure relief, coal seam water injection and blasting pressure relief.

Permanganate diffusion and reaction in sedimentary rocks.

Science.gov (United States)

Huang, Qiuyuan; Dong, Hailiang; Towne, Rachael M; Fischer, Timothy B; Schaefer, Charles E

2014-04-01

In situ chemical oxidation using permanganate has frequently been used to treat chlorinated solvents in fractured bedrock aquifers. However, in systems where matrix back-diffusion is an important process, the ability of the oxidant to migrate and treat target contaminants within the rock matrix will likely determine the overall effectiveness of this remedial approach. In this study, a series of diffusion experiments were performed to measure the permanganate diffusion and reaction in four different types of sedimentary rocks (dark gray mudstone, light gray mudstone, red sandstone, and tan sandstone). Results showed that, within the experimental time frame (~2 months), oxidant migration into the rock was limited to distances less than 500 μm. The observed diffusivities for permanganate into the rock matrices ranged from 5.3 × 10(-13) to 1.3 × 10(-11) cm(2)/s. These values were reasonably predicted by accounting for both the rock oxidant demand and the effective diffusivity of the rock. Various Mn minerals formed as surface coatings from reduction of permanganate coupled with oxidation of total organic carbon (TOC), and the nature of the formed Mn minerals was dependent upon the rock type. Post-treatment tracer testing showed that these Mn mineral coatings had a negligible impact on diffusion through the rock. Overall, our results showed that the extent of permanganate diffusion and reaction depended on rock properties, including porosity, mineralogy, and organic carbon. These results have important implications for our understanding of long-term organic contaminant remediation in sedimentary rocks using permanganate. Copyright © 2014 Elsevier B.V. All rights reserved.

Bioremediation in Fractured Rock: 2. Mobilization of Chloroethene Compounds from the Rock Matrix.

Science.gov (United States)

Shapiro, Allen M; Tiedeman, Claire R; Imbrigiotta, Thomas E; Goode, Daniel J; Hsieh, Paul A; Lacombe, Pierre J; DeFlaun, Mary F; Drew, Scott R; Curtis, Gary P

2018-03-01

A mass balance is formulated to evaluate the mobilization of chlorinated ethene compounds (CE) from the rock matrix of a fractured mudstone aquifer under pre- and postbioremediation conditions. The analysis relies on a sparse number of monitoring locations and is constrained by a detailed description of the groundwater flow regime. Groundwater flow modeling developed under the site characterization identified groundwater fluxes to formulate the CE mass balance in the rock volume exposed to the injected remediation amendments. Differences in the CE fluxes into and out of the rock volume identify the total CE mobilized from diffusion, desorption, and nonaqueous phase liquid dissolution under pre- and postinjection conditions. The initial CE mass in the rock matrix prior to remediation is estimated using analyses of CE in rock core. The CE mass mobilized per year under preinjection conditions is small relative to the total CE mass in the rock, indicating that current pump-and-treat and natural attenuation conditions are likely to require hundreds of years to achieve groundwater concentrations that meet regulatory guidelines. The postinjection CE mobilization rate increased by approximately an order of magnitude over the 5 years of monitoring after the amendment injection. This rate is likely to decrease and additional remediation applications over several decades would still be needed to reduce CE mass in the rock matrix to levels where groundwater concentrations in fractures achieve regulatory standards. © 2017, National Ground Water Association.

Fracture Initiation of an Inhomogeneous Shale Rock under a Pressurized Supercritical CO2 Jet

Directory of Open Access Journals (Sweden)

Yi Hu

2017-10-01

Full Text Available Due to the advantages of good fracture performance and the application of carbon capture and storage (CCS, supercritical carbon dioxide (SC-CO2 is considered a promising alternative for hydraulic fracturing. However, the fracture initiation mechanism and its propagation under pressurized SC-CO2 jet are still unknown. To address these problems, a fluid–structure interaction (FSI-based numerical simulation model along with a user-defined code was used to investigate the fracture initiation in an inhomogeneous shale rock. The mechanism of fracturing under the effect of SC-CO2 jet was explored, and the effects of various influencing factors were analyzed and discussed. The results indicated that higher velocity jets of SC-CO2 not only caused hydraulic-fracturing ring, but also resulted in the increase of stress in the shale rock. It was found that, with the increase of perforation pressure, more cracks initiated at the tip. In contrast, the length of cracks at the root decreased. The length-to-diameter ratio and the aperture ratio distinctly affected the pressurization of SC-CO2 jet, and contributed to the non-linear distribution and various maximum values of the stress in shale rock. The results proved that Weibull probability distribution was appropriate for analysis of the fracture initiation. The studied parameters explain the distribution of weak elements, and they affect the stress field in shale rock.

Interpretation of Flow Logs from Nevada Test Site Boreholes to Estimate Hydraulic Conductivity Using Numerical Simulations Constrained by Single-Well Aquifer Tests

Science.gov (United States)

Garcia, C. Amanda; Halford, Keith J.; Laczniak, Randell J.

2010-01-01

Hydraulic conductivities of volcanic and carbonate lithologic units at the Nevada Test Site were estimated from flow logs and aquifer-test data. Borehole flow and drawdown were integrated and interpreted using a radial, axisymmetric flow model, AnalyzeHOLE. This integrated approach is used because complex well completions and heterogeneous aquifers and confining units produce vertical flow in the annular space and aquifers adjacent to the wellbore. AnalyzeHOLE simulates vertical flow, in addition to horizontal flow, which accounts for converging flow toward screen ends and diverging flow toward transmissive intervals. Simulated aquifers and confining units uniformly are subdivided by depth into intervals in which the hydraulic conductivity is estimated with the Parameter ESTimation (PEST) software. Between 50 and 150 hydraulic-conductivity parameters were estimated by minimizing weighted differences between simulated and measured flow and drawdown. Transmissivity estimates from single-well or multiple-well aquifer tests were used to constrain estimates of hydraulic conductivity. The distribution of hydraulic conductivity within each lithology had a minimum variance because estimates were constrained with Tikhonov regularization. AnalyzeHOLE simulated hydraulic-conductivity estimates for lithologic units across screened and cased intervals are as much as 100 times less than those estimated using proportional flow-log analyses applied across screened intervals only. Smaller estimates of hydraulic conductivity for individual lithologic units are simulated because sections of the unit behind cased intervals of the wellbore are not assumed to be impermeable, and therefore, can contribute flow to the wellbore. Simulated hydraulic-conductivity estimates vary by more than three orders of magnitude across a lithologic unit, indicating a high degree of heterogeneity in volcanic and carbonate-rock units. The higher water transmitting potential of carbonate-rock units relative

Interpretation of Flow Logs from Nevada Test Site Boreholes to Estimate Hydraulic conductivity Using Numerical Simulations Constrained by Single-Well Aquifer Tests

Energy Technology Data Exchange (ETDEWEB)

Garcia, C. Amanda; Halford, Keith J.; Laczniak, Randell J.

2010-02-12

Hydraulic conductivities of volcanic and carbonate lithologic units at the Nevada Test Site were estimated from flow logs and aquifer-test data. Borehole flow and drawdown were integrated and interpreted using a radial, axisymmetric flow model, AnalyzeHOLE. This integrated approach is used because complex well completions and heterogeneous aquifers and confining units produce vertical flow in the annular space and aquifers adjacent to the wellbore. AnalyzeHOLE simulates vertical flow, in addition to horizontal flow, which accounts for converging flow toward screen ends and diverging flow toward transmissive intervals. Simulated aquifers and confining units uniformly are subdivided by depth into intervals in which the hydraulic conductivity is estimated with the Parameter ESTimation (PEST) software. Between 50 and 150 hydraulic-conductivity parameters were estimated by minimizing weighted differences between simulated and measured flow and drawdown. Transmissivity estimates from single-well or multiple-well aquifer tests were used to constrain estimates of hydraulic conductivity. The distribution of hydraulic conductivity within each lithology had a minimum variance because estimates were constrained with Tikhonov regularization. AnalyzeHOLE simulated hydraulic-conductivity estimates for lithologic units across screened and cased intervals are as much as 100 times less than those estimated using proportional flow-log analyses applied across screened intervals only. Smaller estimates of hydraulic conductivity for individual lithologic units are simulated because sections of the unit behind cased intervals of the wellbore are not assumed to be impermeable, and therefore, can contribute flow to the wellbore. Simulated hydraulic-conductivity estimates vary by more than three orders of magnitude across a lithologic unit, indicating a high degree of heterogeneity in volcanic and carbonate-rock units. The higher water transmitting potential of carbonate-rock units relative

Enhanced Oil Recovery from Oil-wet Carbonate Rock by Spontaneous Imbibition of Aqueous Surfactant Solutions

Energy Technology Data Exchange (ETDEWEB)

Standnes, Dag Chun

2001-09-01

The main theme of this thesis is an experimental investigation of spontaneous imbibition (SI) of aqueous cationic surfactant solution into oil-wet carbonate (chalk- and dolomite cores). The static imbibition process is believed to represent the matrix flow of oil and water in a fractured reservoir. It was known that aqueous solution of C{sub 12}-N(CH{sub 3}){sub 3}Br (C12TAB) was able to imbibe spontaneously into nearly oil-wet chalk material, but the underlying mechanism was not understood. The present work was therefore initiated, with the following objectives: (1) Put forward a hypothesis for the chemical mechanism underlying the SI of C12TAB solutions into oil-wet chalk material based on experimental data and (2) Perform screening tests of low-cost commercially available surfactants for their ability to displace oil by SI of water into oil-wet carbonate rock material. It is essential for optimal use of the surfactant in field application to have detailed knowledge about the mechanism underlying the SI process. The thesis also discusses some preliminary experimental results and suggests mechanisms for enhanced oil recovery from oil-wet carbonate rock induced by supply of thermal energy.

Fracture Dissolution of Carbonate Rock: An Innovative Process for Gas Storage

Energy Technology Data Exchange (ETDEWEB)

James W. Castle; Ronald W. Falta; David Bruce; Larry Murdoch; Scott E. Brame; Donald Brooks

2006-10-31

The goal of the project is to develop and assess the feasibility and economic viability of an innovative concept that may lead to commercialization of new gas-storage capacity near major markets. The investigation involves a new approach to developing underground gas storage in carbonate rock, which is present near major markets in many areas of the United States. Because of the lack of conventional gas storage and the projected growth in demand for storage capacity, many of these areas are likely to experience shortfalls in gas deliverability. Since depleted gas reservoirs and salt formations are nearly non-existent in many areas, alternatives to conventional methods of gas storage are required. The need for improved methods of gas storage, particularly for ways to meet peak demand, is increasing. Gas-market conditions are driving the need for higher deliverability and more flexibility in injection/withdrawal cycling. In order to meet these needs, the project involves an innovative approach to developing underground storage capacity by creating caverns in carbonate rock formations by acid dissolution. The basic concept of the acid-dissolution method is to drill to depth, fracture the carbonate rock layer as needed, and then create a cavern using an aqueous acid to dissolve the carbonate rock. Assessing feasibility of the acid-dissolution method included a regional geologic investigation. Data were compiled and analyzed from carbonate formations in six states: Indiana, Ohio, Kentucky, West Virginia, Pennsylvania, and New York. To analyze the requirements for creating storage volume, the following aspects of the dissolution process were examined: weight and volume of rock to be dissolved; gas storage pressure, temperature, and volume at depth; rock solubility; and acid costs. Hydrochloric acid was determined to be the best acid to use because of low cost, high acid solubility, fast reaction rates with carbonate rock, and highly soluble products (calcium chloride

On the migration of uranium isotopes in sandstone aquifers

International Nuclear Information System (INIS)

Froehlich, K.; Gellermann, R.

1982-01-01

Measurements of natural 238 U and 234 U activity in groundwater of sandstone aquifers have been used to study the migration of these uranium isotopes. Regarding the uranium exchange between liquid phase and rock surface during migration, two different models were applied for evaluating the experimental results. Values of corresponding parameters (retardation factor K, removal rate R) reflecting different behaviour concerning this exchange were determined. For example, the values obtained for 238 U in a Triassic sandstone aquifer of the GDR are K = 8.6 x 10 6 and R = 1.3 x 10 -3 a -1 , respectively. It was found that, under the conditions of the sandstone aquifer concerned, the removal rate model is better suited for calculating uranium-isotope migration in groundwater. (author)

Reaction of subsurface coastal aquifers to climate and land use changes in Greece: modelling of groundwater refreshening patterns under natural recharge conditions

Science.gov (United States)

Lambrakis, N.; Kallergis, G.

2001-05-01

This paper studies the multicomponent ion exchange process and freshening time under natural recharge conditions for three coastal aquifers in Greece. Due to over-pumping and the dry years of 1980-1990 decline in groundwater quality has been observed in most of the Greek coastal aquifers. This decline is caused by a lack of reliable water resource management, water abstraction from great depths, and seawater intrusion resulting in a rise of the fresh/salt water interface (salinisation process) due to a negative water balance. The reverse phenomenon, which should lead to groundwater freshening, is a long process. The freshening process shows chromatographic patterns that are due to chemical reactions such as calcite dissolution and cation exchange, and simultaneously occurring transport and dispersion processes. Using the geochemical simulation codes PHREEQE and PHREEQM (Parkhurst et al., US Geol. Surv. Water Resour. Invest., 80-96 (1980) 210; Appelo and Postma, Geochemistry, Groundwater and Pollution (1994)), these patterns were analysed and the above-mentioned processes were simulated for carefully selected aquifers in Peloponnesus and Crete (Greece). Aquifers of the Quaternary basin of Glafkos in Peloponnesus, the Neogene formations in Gouves, Crete, and the carbonate aquifer of Malia, Crete, were examined as representative examples of Greek coastal aquifer salinisation. The results show that when pumping was discontinued, the time required for freshening under natural conditions of the former two aquifers is long and varies between 8000 and 10,000 years. The Malia aquifer on the other hand, has a freshening time of 15 years. Freshening time was shown to depend mainly on cation exchange capacities and the recharge rate of the aquifers.

Hydrogeology of the carbonate rocks of the Lebanon Valley, Pennsylvania

Science.gov (United States)

Meisler, Harold

1963-01-01

The Lebanon Valley, which is part of the Great Valley in southeastern Pennsylvania, is underlain by carbonate rocks in the southern part and by shale in the northern part. The carbonate rocks consist of alternating beds of limestone and dolomite of Cambrian and Ordovician age. Although the beds generally dip to the south, progressively younger beds crop out to the north, because the rocks are overturned. The stratigraphic units, from oldest to youngest, are: the Buffalo Springs Formation, Snitz Creek, Schaefferstown, Millbach, and Richland Formations of the Conococheague Group; the Stonehenge, Rickenbach, Epler, and Ontelaunee Formations of the Beekmantown Group; and the Annville, Myerstown, and Hershey Limestones.

Three-dimensional geologic model of the Arbuckle-Simpson aquifer, south-central Oklahoma

Science.gov (United States)

Faith, Jason R.; Blome, Charles D.; Pantea, Michael P.; Puckette, James O.; Halihan, Todd; Osborn, Noel; Christenson, Scott; Pack, Skip

2010-01-01

The Arbuckle-Simpson aquifer of south-central Oklahoma encompasses more than 850 square kilometers and is the principal water resource for south-central Oklahoma. Rock units comprising the aquifer are characterized by limestone, dolomite, and sandstones assigned to two lower Paleozoic units: the Arbuckle and Simpson Groups. Also considered to be part of the aquifer is the underlying Cambrian-age Timbered Hills Group that contains limestone and sandstone. The highly faulted and fractured nature of the Arbuckle-Simpson units and the variable thickness (600 to 2,750 meters) increases the complexity in determining the subsurface geologic framework of this aquifer. A three-dimensional EarthVision (Trademark) geologic framework model was constructed to quantify the geometric relationships of the rock units of the Arbuckle-Simpson aquifer in the Hunton anticline area. This 3-D EarthVision (Trademark) geologic framework model incorporates 54 faults and four modeled units: basement, Arbuckle-Timbered Hills Group, Simpson Group, and post-Simpson. Primary data used to define the model's 54 faults and four modeled surfaces were obtained from geophysical logs, cores, and cuttings from 126 water and petroleum wells. The 3-D framework model both depicts the volumetric extent of the aquifer and provides the stratigraphic layer thickness and elevation data used to construct a MODFLOW version 2000 regional groundwater-flow model.

Behaviour and fate of nine recycled water trace organics during managed aquifer recharge in an aerobic aquifer

Science.gov (United States)

Patterson, B. M.; Shackleton, M.; Furness, A. J.; Bekele, E.; Pearce, J.; Linge, K. L.; Busetti, F.; Spadek, T.; Toze, S.

2011-03-01

The fate of nine trace organic compounds was evaluated during a 12 month large-scale laboratory column experiment. The columns were packed with aquifer sediment and evaluated under natural aerobic and artificial anaerobic geochemical conditions, to assess the potential for natural attenuation of these compounds during aquifer passage associated with managed aquifer recharge (MAR). The nine trace organic compounds were bisphenol A (BPA), 17β-estradiol (E2), 17α-ethynylestradiol (EE2), N-nitrosodimethylamine (NDMA), N-nitrosomorpholine (NMOR), carbamazepine, oxazepam, iohexol and iodipamide. In the low organic carbon content Spearwood sediment, all trace organics were non-retarded with retardation coefficients between 1.0 and 1.2, indicating that these compounds would travel at near groundwater velocities within the aquifer. The natural aerobic geochemical conditions provided a suitable environment for the rapid degradation for BPA, E2, iohexol (half life NDMA and NMOR) did not degrade under either aerobic or anaerobic aquifer geochemical conditions (half life > 50 days). Field-based validation experiments with carbamazepine and oxazepam also showed no degradation. If persistent trace organics are present in recycled waters at concentrations in excess of their intended use, natural attenuation during aquifer passage alone may not result in extracted water meeting regulatory requirements. Additional pre treatment of the recycled water would therefore be required.

Assessment of groundwater potential based on aquifer properties of hard rock terrain in the Chittar-Uppodai watershed, Tamil Nadu, India

Science.gov (United States)

Kumar, T. Jeyavel Raja; Balasubramanian, A.; Kumar, R. S.; Dushiyanthan, C.; Thiruneelakandan, B.; Suresh, R.; Karthikeyan, K.; Davidraju, D.

2016-06-01

Aquifer performance was tested in 24 locations to assess the groundwater potential of the hard rock terrain in the Chittar-Uppodai watershed of the Tambaraparani River basin. Geologically, the area consists of biotite gneiss, charnockite, and quartzite. The aquifer characteristics, such as transmissivity ( T), the storage coefficient, specific capacity, optimum yield, and the recovery rate were calculated. The drawdown transmissivity was determined using Jacob's straight-line method, while the recovery transmissivity was determined by the Theis method. The drawdown transmissivity was low in the western areas, particularly at Kadayanallur, and was higher in the other areas. The recovery transmissivity was high in the western area, and, with the exception of Gangaikondan, was low at other locations. The assessment indicates that there is groundwater potential in the western part of the study area because of favorable results for recovery drawdown, aquifer thickness, and specific capacity.

Assessing hydraulic connections across a complex sequence of volcanic rocks - Analysis of U-20 WW multiple-well aquifer test, Pahute Mesa, Nevada National Security Site, Nevada

Science.gov (United States)

Garcia, C. Amanda; Fenelon, Joseph M.; Halford, Keith J.; Reiner, Steven R.; Laczniak, Randell J.

2011-01-01

Groundwater beneath Pahute Mesa flows through a complexly layered sequence of volcanic rock aquifers and confining units that have been faulted into distinct structural blocks. Hydraulic property estimates of rocks and structures in this flow system are necessary to assess radionuclide migration near underground nuclear testing areas. The U.S. Geological Survey (USGS) used a 12 month (October 1, 2008— October 1, 2009) intermittent pumping schedule of well U-20 WW and continuously monitored water levels in observation wells ER-20-6 #3, UE-20bh 1, and U-20bg as a multi-well aquifer test to evaluate hydraulic connections across structural blocks, bulk hydraulic properties of volcanic rocks, and the hydraulic significance of a major fault. Measured water levels were approximated using synthetic water levels generated from an analytical model. Synthetic water levels are a summation of environmental water-level fluctuations and a Theis (1935) transform of the pumping signal from flow rate to water-level change. Drawdown was estimated by summing residual differences between measured and synthetic water levels and the Theis-transformed pumping signal from April to September 2009. Drawdown estimates were used in a three‑dimensional numerical model to estimate hydraulic properties of distinct aquifers, confining units, and a major fault.

Relationships of stable isotopes, water-rock interaction and salinization in fractured aquifers, Petrolina region, Pernambuco State, Brazil

Energy Technology Data Exchange (ETDEWEB)

Silva, Priscila Sousa, E-mail: priscila.silva@cprm.gov.br [Serviço Geológico do Brasil (CPRM), Manaus, AM (Brazil); Campos, José Eloi Guimarães; Cunha, Luciano Soares; Mancini, Luís Henrique, E-mail: eloi@unb.br, E-mail: lucianosc@unb.br, E-mail: lmancini@unb.br [Universidade de Brasília (UnB), Brasília, DF (Brazil)

2018-01-15

The Petrolina County, Pernambuco State, Brazil, presents specificities that make it unique from a hydrogeological point of view. Water resource scarcity is both a quantitative and qualitative issue. The climate is classified as semiarid, having low precipitation, along with high temperatures and evapotranspiration rates. Aquifer zones are related to low connected fractures resulting in a restricted water flow in the aquifer. The recharge is limited and the groundwater salinity is high. Stable isotope analyses of H and O were developed in groundwater samples (with different electrical conductivity) and surface water collected in a bypass channel flowing from the São Francisco River. The results were plotted in a δD ‰ versus δ{sup 18}O ‰ graph along with the curves of the global and local meteoric water line. Groundwater samples showed unexpected results showing a lighter sign pattern when compared to the meteoric waters. More negative δD and δ{sup 18}O values indicate an enrichment in light isotopes, which show that this process is not influenced by surface processes, where the enrichment occurs in heavy isotopes due to evaporation. The isotopic signature observed is interpreted either as resulting from the water-rock interaction, or as resulting from recharge from paleo rains. The waters are old and show restricted flow. So the water-rock contact time is extended. In the rock weathering processes, through the hydration of feldspars, there is preferential assimilation of heavy isotopes at the expense of the lighter ones that remain in the water. Analyses of the {sup 87}Sr/{sup 86}Sr ratio and isotopic groundwater dating assist in the interpretations. (author)

Relative permeabilities of supercritical CO2 and brine in carbon sequestration by a two-phase lattice Boltzmann method

Science.gov (United States)

Xie, Jian.-Fei.; He, S.; Zu, Y. Q.; Lamy-Chappuis, B.; Yardley, B. W. D.

2017-08-01

In this paper, the migration of supercritical carbon dioxide (CO2) in realistic sandstone rocks under conditions of saline aquifers, with applications to the carbon geological storage, has been investigated by a two-phase lattice Boltzmann method (LBM). Firstly the digital images of sandstone rocks were reproduced utilizing the X-ray computed microtomography (micro-CT), and high resolutions (up to 2.5 μm) were applied to the pore-scale LBM simulations. For the sake of numerical stability, the digital images were "cleaned" by closing the dead holes and removing the suspended particles in sandstone rocks. In addition, the effect of chemical reactions occurred in the carbonation process on the permeability was taken into account. For the wetting brine and non-wetting supercritical CO2 flows, they were treated as the immiscible fluids and were driven by pressure gradients in sandstone rocks. Relative permeabilities of brine and supercritical CO2 in sandstone rocks were estimated. Particularly the dynamic saturation was applied to improve the reliability of the calculations of the relative permeabilities. Moreover, the effects of the viscosity ratio of the two immiscible fluids and the resolution of digital images on the relative permeability were systematically investigated.

Experimental and modeling results on geochemical impacts of leaking CO2 from subsurface storage reservoirs to an unconfined oxidizing carbonate aquifer

Science.gov (United States)

Qafoku, N. P.; Bacon, D. H.; Shao, H.; Lawter, A.; Wang, G.; Brown, C. F.

2013-12-01

Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate risks to groundwater quality and develop a systematic understanding on how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Solid materials (rocks and slightly weathered rocks) from an unconfined aquifer, i.e., the Edwards Aquifer in Texas, were used in this investigation. The experimental part consisted of: 1) wet chemical acid extractions (8M HNO3 solution at 90 0C); 2) batch experiments conducted at low solid to solution ratios to study time-dependent releases of major, minor and trace elements during periodic or continuous exposure to CO2 gas; 3) hydraulically saturated column experiments conducted under continuous and stop-flow conditions using a CO2 gas saturated synthetic groundwater; 4) pre- and post-treatment solid phase characterization studies. Major variables tested included reaction time (0-336 hours), CO2 flow rate (50 to 350 ml/min), brine concentration (0.1 and 1 M NaCl), rock type and particle size fraction. We are currently investigating the solution composition effects (i.e., presence of contaminants in the initial solution) on the fate and behavior of potential contaminants (As, Pb and Cd) in these systems. Results from the solid phase characterization studies showed that the mineralogy of the Edwards aquifer materials was dominated by calcite. Quartz and montmorillonite were also present in some samples. Acid extractions confirmed that the solid phase had appreciable amounts of potential contaminants (As, Cd, Cr, Cu, Pb and Zn). However, the results from the batch and column experiments demonstrated that these contaminants

Isotopic measurements in research on seawater ingression in the carbonate aquifer of the Salentine Peninsula, Southern Italy

International Nuclear Information System (INIS)

Cotecchia, V.; Tazioli, G.S.; Magri, G.

1974-01-01

Cretaceous calcareous and dolomitic rocks, bedded, jointed and karstified, and hence generally very permeable, form the basement of the Salentine Peninsula. These rocks constitute a huge aquifer with fresh and brackish groundwaters that float on groundwaters of marine origin. Sea level constitutes the base level of the ground waters. A basic outline is first given of the hydrogeology and the paleohydrogeology, so as to provide the necessary background information on the seawater intrusion phenomenon and to permit comparison of the results of the isotope data with those obtained by the classical methods of hydrogeological investigation. This is followed by presentation of the results of the isotopic measurements on 18 O, D, 13 C and 14 C. The δ 13 C contents indicate, in good agreement with the carbon dioxide and bicarbonate concentrations, that seawater ingression leads to the migration of carbon dioxide from the fresh and brackish waters towards the subjacent intrusive waters of marine origin. Along those stretches of coast where the seawaters are in direct communication with the groundwaters, all the isotope data point to very active renewal of groundwaters of marine origin by seawater. In the central parts of the peninsula and along those stretches of coast where direct communication between seawaters and groundwaters is impeded by impervious clays, the 14 C contents indicate that the seawater intrusion and consequently the migration of carbon dioxide are either very slow and continuous in time or that they occurred relatively rapidly in the past. Taking into consideration the paleohydrogeology of the peninsula, and the fact that the δ 18 O and δD values are higher than those of the present seawaters, leads to the belief that seawater intrusion may well have occurred during major variations in the sea level in the past, when climatic conditions were different from those now prevailing. (author)

Straddle-packer aquifer test analyses of the Snake River Plain aquifer at the Idaho National Engineering Laboratory

International Nuclear Information System (INIS)

Johnson, G.S.; Frederick, D.B.

1997-01-01

The State of Idaho INEL Oversight Program, with the University of Idaho, Idaho State University, Boise State University, and the Idaho Geologic Survey, used a straddle-packer system to investigate vertical variations in characteristics of the Snake River Plain aquifer at the Idaho National Engineering Laboratory in southeast Idaho. Sixteen single-well aquifer tests were conducted on.isolated intervals in three observation wells. Each of these wells has approximately 200 feet of open borehole below the water table, penetrating the E through G and I basalt flow groups and interbedded sediments of the Snake River Plain aquifer. The success of the aquifer tests was limited by the inability to induce measurable drawdown in several zones. Time-drawdown data from aquifer tests were matched to type curves for 8 of the 16 zones tested. A single aquifer test at the water table exhibited greater curvature than those at depth. The increased degree of curvature suggests an unconfined response and resulted in an estimate of specific yield of 0.03. Aquifer tests below the water table generally yielded time-drawdown graphs with a rapid initial response followed by constant drawdown throughout the duration of the tests; up to several hours in length. The rapid initial response implies that the aquifer responds as a confined system during brief pumping periods. The nearly constant drawdown suggests a secondary source of water, probably vertical flow from overlying and underlying aquifer layers. Three analytical models were applied for comparison to the conceptual model and to provide estimates of aquifer properties. This, Hantush-Jacob leaky aquifer, and the Moench double-porosity fractured rock models were fit to time-drawdown data. The leaky aquifer type curves of Hantush and Jacob generally provided the best match to observed drawdown. A specific capacity regression equation was also used to estimate hydraulic conductivity

Engineered in situ bioremediation of a petroleum hydrocarbon-contaminated aquifer: assessment of mineralization based on alkalinity, inorganic carbon and stable carbon isotope balances

Science.gov (United States)

Hunkeler, Daniel; Höhener, Patrick; Bernasconi, Stefano; Zeyer, Josef

1999-04-01

A concept is proposed to assess in situ petroleum hydrocarbon mineralization by combining data on oxidant consumption, production of reduced species, CH 4, alkalinity and dissolved inorganic carbon (DIC) with measurements of stable isotope ratios. The concept was applied to a diesel fuel contaminated aquifer in Menziken, Switzerland, which was treated by engineered in situ bioremediation. In the contaminated aquifer, added oxidants (O 2 and NO 3-) were consumed, elevated concentrations of Fe(II), Mn(II), CH 4, alkalinity and DIC were detected and the DIC was generally depleted in 13C compared to the background. The DIC production was larger than expected based on the consumption of dissolved oxidants and the production of reduced species. Stable carbon isotope balances revealed that the DIC production in the aquifer originated mainly from microbial petroleum hydrocarbon mineralization, and that geochemical reactions such as carbonate dissolution produced little DIC. This suggests that petroleum hydrocarbon mineralization can be underestimated if it is determined based on concentrations of dissolved oxidants and reduced species.

Geochemical approach of the salinization mechanisms of coastal aquifers - 14C - 226Ra chronologies

International Nuclear Information System (INIS)

Barbecot, F.

1999-11-01

Through time, coastal aquifers which constitute a great part of available fresh water resources from sedimentary basins in France, were submitted to changes in hydraulic gradients and hydrodynamic properties mainly due to discharge/recharge phases in response to sea level variations and/or anthropic forcing. Performed in the framework of the European program PALAEAUX ('Management of coastal aquifers in Europe, paleo-waters and natural controls'), this work aimed to understand the salinization process originating from the recharge/discharge conditions and recognized in three study aquifers: the calcareous Dogger aquifers along the Channel (Caen area), and the Atlantic coast (Marais Poitevin), and the Astian sandy aquifer (Cap d'Agde). Besides the conventional hydrogeological and hydrochemical methods, the main tools used are those of isotope geochemistry. For the three sites, the modern, fresh groundwaters are marked by the anthropisation of the recharge area. The evolution of isotopic signatures along a flow path depending on the mineralogy of the aquifer matrix, is linked to water-rock interactions such as cation exchange, and equilibrium with aluminosilicates. For the three study sites, the modern fresh groundwaters are marked by the anthropisation of the recharge area. The evolution of isotopic signatures along a flow path depending on the mineralogy of the aquifer matrix, is linked to water-rock interactions such as cation exchange, and equilibrium with aluminosilicates. Residence times of these fresh groundwater are from Present (Atlantic site) up to the 14 C detection limit (Channel site). Groundwater of the Astian aquifer belongs to Holocene, as determined by both 14 C and 226 Ra. From Present to 3 ka, 14 C and 226 Ra ages are coherent. Beyond, the discrepancy observed can be associated to the under-estimation of in- situ 226 Ra production, but more likely, to the 'buffer' effect of the matrix with respect to the 14 C isotopic equilibration. The salty waters

Multi-scale nitrate transport in a sandstone aquifer system under intensive agriculture

Science.gov (United States)

Paradis, Daniel; Ballard, Jean-Marc; Lefebvre, René; Savard, Martine M.

2018-03-01

Nitrate transport in heterogeneous bedrock aquifers is influenced by mechanisms that operate at different spatial and temporal scales. To understand these mechanisms in a fractured sandstone aquifer with high porosity, a groundwater-flow and nitrate transport model—reproducing multiple hydraulic and chemical targets—was developed to explain the actual nitrate contamination observed in groundwater and surface water in a study area on Prince Edward Island, Canada. Simulations show that nitrate is leached to the aquifer year-round, with 61% coming from untransformed and transformed organic sources originating from fertilizers and manure. This nitrate reaches the more permeable shallow aquifer through fractures in weathered sandstone that represent only 1% of the total porosity (17%). Some of the nitrate reaches the underlying aquifer, which is less active in terms of groundwater flow, but most of it is drained to the main river. The river-water quality is controlled by the nitrate input from the shallow aquifer. Groundwater in the underlying aquifer, which has long residence times, is also largely influenced by the diffusion of nitrate in the porous sandstone matrix. Consequently, following a change of fertilizer application practices, water quality in domestic wells and the river would change rapidly due to the level of nitrate found in fractures, but a lag time of up to 20 years would be necessary to reach a steady level due to diffusion. This demonstrates the importance of understanding nitrate transport mechanisms when designing effective agricultural and water management plans to improve water quality.

Carbonate rocks of the Seward Peninsula, Alaska: Their correlation and paleogeographic significance

Science.gov (United States)

Dumoulin, Julie A.; Harris, Alta; Repetski, John E.

2014-01-01

Paleozoic carbonate strata deposited in shallow platform to off-platform settings occur across the Seward Peninsula and range from unmetamorphosed Ordovician–Devonian(?) rocks of the York succession in the west to highly deformed and metamorphosed Cambrian–Devonian units of the Nome Complex in the east. Faunal and lithologic correlations indicate that early Paleozoic strata in the two areas formed as part of a single carbonate platform. The York succession makes up part of the York terrane and consists of Ordovician, lesser Silurian, and limited, possibly Devonian rocks. Shallow-water facies predominate, but subordinate graptolitic shale and calcareous turbidites accumulated in deeper water, intraplatform basin environments, chiefly during the Middle Ordovician. Lower Ordovician strata are mainly lime mudstone and peloid-intraclast grainstone deposited in a deepening upward regime; noncarbonate detritus is abundant in lower parts of the section. Upper Ordovician and Silurian rocks include carbonate mudstone, skeletal wackestone, and coral-stromatoporoid biostromes that are commonly dolomitic and accumulated in warm, shallow to very shallow settings with locally restricted circulation. The rest of the York terrane is mainly Ordovician and older, variously deformed and metamorphosed carbonate and siliciclastic rocks intruded by early Cambrian (and younger?) metagabbros. Older (Neoproterozoic–Cambrian) parts of these units are chiefly turbidites and may have been basement for the carbonate platform facies of the York succession; younger, shallow- and deep-water strata likely represent previously unrecognized parts of the York succession and its offshore equivalents. Intensely deformed and altered Mississippian carbonate strata crop out in a small area at the western edge of the terrane. Metacarbonate rocks form all or part of several units within the blueschist- and greenschist-facies Nome Complex. The Layered sequence includes mafic meta¬igneous rocks and

Water-rock interaction under peri-glacial conditions: example of the secondary carbonates of the Broegger Peninsula (Spitzbergen)

International Nuclear Information System (INIS)

Marlin, C.; Dever, L.

1998-01-01

Measurements of the isotopic and chemical contents of soil water and carbonates at different field sites in Spitzbergen were undertaken to study the precipitation conditions of soil secondary calcites under the current peri-glacial climate. A main experimental site ('cote 80') has been established located on a fluvio-glacial terrasse at 80 m.a.s.l. near Ny Alesund (79 deg N, 12 deg. E). The active layer is at around 1.2 m depth on a continuous permafrost. The soil temperatures measured every 5 cm from the surface to the permafrost show that the freezing fronts move both the surface and permafrost, converging at around 0.6 m depth where the system is closed. During the beginning of the freezing period, the solute content increases in the residual water according to the distribution coefficient between water and ice. Calcite precipitation occurs in a second stage as indicated by the simultaneous decrease of the calcite saturation index and increase of the concentration of non-interactive elements. Chemical and isotopic ( 18 O, 2 H, 13 C et 14 C) analyses have been made on the different samples with a mineralogical description of the carbonate coatings obtained by SEM and microprobe analyses. The isotopic values result from a mixing between recent calcites and 'old' calcites. The recent calcites are probably in isotopic equilibrium with the present day solutions. The 'old calcites' have precipitated under colder conditions than today. The low radiocarbon activities (10.2 to 24.8 pcm) of the 'cote 80' site indicate that the 'old calcites' have precipitated during the last interglacial period or an inter-stadial period of the Pleistocene. The good relationship between the carbon- 14 activity and the carbon- 13 content indicates that the beginning of the pedogenesis is not identical at all sites and is dependent on the timing of deglaciation and vulnerability of rocks to frost-weathering. (authors)

Well-based stable carbon isotope leakage monitoring of an aquifer overlying the CO2 storage reservoir at the Ketzin pilot site, Germany

Science.gov (United States)

Nowak, Martin; Myrttinen, Anssi; Zimmer, Martin; van Geldern, Robert; Barth, Johannes A. C.

2014-05-01

At the pilot site for CO2 storage in Ketzin, a new well-based leakage-monitoring concept was established, comprising geochemical and hydraulic observations of the aquifer directly above the CO2 reservoir (Wiese et al., 2013, Nowak et al. 2013). Its purpose was to allow early detection of un-trapped CO2. Within this monitoring concept, we established a stable carbon isotope monitoring of dissolved inorganic carbon (DIC). If baseline isotope values of aquifer DIC (δ13CDIC) and reservoir CO2 (δ13CCO2) are known and distinct from each other, the δ13CDIC has the potential to serve as an an early indicator for an impact of leaked CO2 on the aquifer brine. The observation well of the overlying aquifer was equipped with an U-tube sampling system that allowed sampling of unaltered brine. The high alkaline drilling mud that was used during well drilling masked δ13CDIC values at the beginning of the monitoring campaign. However, subsequent monitoring allowed observing on-going re-equilibration of the brine, indicated by changing δ13CDIC and other geochemical values, until values ranging around -23 ‰ were reached. The latter were close to baseline values before drilling. Baselineδ13CDIC and δ13CCO2 values were used to derive a geochemical and isotope model that predicts evolution of δ13CDIC, if CO2 from the reservoir would leak into the aquifer. The model shows that equilibrium isotope fractionation would have to be considered if CO2 dissolves in the brine. The model suggests that stable carbon isotope monitoring is a suitable tool to assess the impact of injected CO2 in overlying groundwater aquifers. However, more data are required to close gaps of knowledge about fractionation behaviour within the CO2(g) - DIC system under elevated pressures and temperatures. Nowak, M., Myrttinen, A., Zimmer, M., Wiese, B., van Geldern, R., Barth, J.A.C., 2013. Well-based, Geochemical Leakage Monitoring of an Aquifer Immediately Above a CO2 Storage Reservoir by Stable Carbon

Effects of Nozzle Configuration on Rock Erosion Under a Supercritical Carbon Dioxide Jet at Various Pressures and Temperatures

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Man Huang

2017-06-01

Full Text Available The supercritical carbon dioxide (SC-CO2 jet offers many advantages over water jets in the field of oil and gas exploration and development. To take better advantage of the SC-CO2 jet, effects of nozzle configuration on rock erosion characteristics were experimentally investigated with respect to the erosion volume. A convergent nozzle and two Laval nozzles, as well as artificial cores were employed in the experiments. It was found that the Laval nozzle can enhance rock erosion ability, which largely depends on the pressure and temperature conditions. The enhancement increases with rising inlet pressure. Compared with the convergent nozzle, the Laval-1 nozzle maximally enhances the erosion volume by 10%, 21.2% and 30.3% at inlet pressures of 30, 40 and 50 MPa, respectively; while the Laval-2 nozzle maximally increases the erosion volume by 32.5%, 49.2% and 60%. Moreover, the enhancement decreases with increasing ambient pressure under constant inlet pressure or constant pressure drop. The growth of fluid temperature above the critical value can increase the enhancement. In addition, the jet from the Laval-2 nozzle with a smooth inner profile always has a greater erosion ability than that from the Laval-1 nozzle.

Using Novel Laboratory Incubations and Field Experiments to Identify the Source and Fate of Reactive Organic Carbon in an Arsenic-contaminated Aquifer System

Science.gov (United States)

Stahl, M.; Tarek, M. H.; Badruzzaman, B.; Harvey, C. F.

2017-12-01

Characterizing the sources and fate of organic matter (OM) within aquifer systems is key to our understanding of both the broader global carbon cycle as well as the quality of our groundwater resources. The linkage between the subsurface carbon cycle and groundwater quality is perhaps nowhere more apparent than in the aquifer systems of South and Southeast Asia, where the contamination of groundwater with geogenic arsenic (As) is widespread and threatens the health of millions of individuals. OM fuels the biogeochemical processes driving As mobilization within these aquifers, however the source (i.e., modern surface-derived or aged sedimentary OM) of the reactive OM is widely debated. To characterize the sources of OM driving aquifer redox processes we tracked DIC and DOC concentrations and isotopes (stable and radiocarbon) along groundwater flow-paths and beneath an instrumented study pond at a field site in Bangladesh. We also conducted a set of novel groundwater incubation experiments, where we carbon-dated the DOC at the start and end of a experiment in order to determine the age of the OM that was mineralized. Our carbon/isotope balance reveals that aquifer recharge introduces a large quantity of young (i.e. near modern) OM that is efficiently mineralized within the upper few meters of the aquifer, effectively limiting this pool of reactive surface-sourced OM from being transported deeper into the aquifer where significant As mobilization takes place. The OM mineralized past the upper few meters is an aged, sedimentary source. Consistent with our field data, our incubation experiments show that past the upper few meters of the aquifer the reactive DOC is significantly older than the bulk DOC and has an age consistent with sedimentary OM. Combining our novel set of incubation experiments and a carbon/isotope balance along groundwater flow-paths and beneath our study pond we have identified the sources of reactive OM across different aquifer depths in a

Rock strength under explosive loading

International Nuclear Information System (INIS)

Rimer, N.; Proffer, W.

1993-01-01

This presentation emphasizes the importance of a detailed description of the nonlinear deviatoric (strength) response of the surrounding rock in the numerical simulation of underground nuclear explosion phenomenology to the late times needed for test ban monitoring applications. We will show how numerical simulations which match ground motion measurements in volcanic tuffs and in granite use the strength values obtained from laboratory measurements on small core samples of these rocks but also require much lower strength values after the ground motion has interacted with the rock. The underlying physical mechanisms for the implied strength reduction are not yet well understood, and in fact may depend on the particular rock type. However, constitutive models for shock damage and/or effective stress have been used successfully at S-Cubed in both the Geophysics Program (primarily for DARPA) and the Containment Support Program (for DNA) to simulate late time ground motions measured at NTS in many different rock types

Simulation of CO2–water–rock interactions on geologic CO2 sequestration under geological conditions of China

International Nuclear Information System (INIS)

Wang, Tianye; Wang, Huaiyuan; Zhang, Fengjun; Xu, Tianfu

2013-01-01

Highlights: • We determined the feasibilities of geologic CO 2 sequestration in China. • We determined the formation of gibbsite suggested CO 2 can be captured by rocks. • We suggested the mechanisms of CO 2 –water–rock interactions. • We found the corrosion and dissolution of the rock increased as temperature rose. -- Abstract: The main purpose of this study focused on the feasibility of geologic CO 2 sequestration within the actual geological conditions of the first Carbon Capture and Storage (CCS) project in China. This study investigated CO 2 –water–rock interactions under simulated hydrothermal conditions via physicochemical analyses and scanning electron microscopy (SEM). Mass loss measurement and SEM showed that corrosion of feldspars, silica, and clay minerals increased with increasing temperature. Corrosion of sandstone samples in the CO 2 -containing fluid showed a positive correlation with temperature. During reaction at 70 °C, 85 °C, and 100 °C, gibbsite (an intermediate mineral product) formed on the sample surface. This demonstrated mineral capture of CO 2 and supported the feasibility of geologic CO 2 sequestration. Chemical analyses suggested a dissolution–reprecipitation mechanism underlying the CO 2 –water–rock interactions. The results of this study suggested that mineral dissolution, new mineral precipitation, and carbonic acid formation-dissociation are closely interrelated in CO 2 –water–rock interactions

Map Showing Geology and Hydrostratigraphy of the Edwards Aquifer Catchment Area, Northern Bexar County, South-Central Texas

Science.gov (United States)

Clark, Amy R.; Blome, Charles D.; Faith, Jason R.

2009-01-01

Rock units forming the Edwards and Trinity aquifers in northern Bexar County, Texas, are exposed within all or parts of seven 7.5-minute quadrangles: Bulverde, Camp Bullis, Castle Hills, Helotes, Jack Mountain, San Geronimo, and Van Raub. The Edwards aquifer is the most prolific ground-water source in Bexar County, whereas the Trinity aquifer supplies water for residential, commercial, and industrial uses for areas north of the San Antonio. The geologic map of northern Bexar County shows the distribution of informal hydrostratigraphic members of the Edwards Group and the underlying upper member of the Glen Rose Limestone. Exposures of the Glen Rose Limestone, which forms the Trinity aquifer alone, cover approximately 467 km2 in the county. This study also describes and names five informal hydrostratigraphic members that constitute the upper member of the Glen Rose Limestone; these include, in descending order, the Caverness, Camp Bullis, Upper evaporite, Fossiliferous, and Lower evaporite members. This study improves our understanding of the hydrogeologic connection between the two aquifers as it describes the geology that controls the infiltration of surface water and subsurface flow of ground water from the catchment area (outcropping Trinity aquifer rocks) to the Edwards water-bearing exposures.

Heat-energy storage through semi-opened circulation into low-permeability hard-rock aquifers

Science.gov (United States)

Pettenati, Marie; Bour, Olivier; Ausseur, Jean-Yves; de Dreuzy, Jean-Raynald; de la Bernardie, Jérôme; Chatton, Eliot; Lesueur, Hervé; Bethencourt, Lorine; Mougin, Bruno; Aquilina, Luc; Koch, Florian; Dewandel, Benoit; Boisson, Alexandre; Mosser, Jean-François; Pauwels, Hélène

2016-04-01

In low-permeability environments, the solutions of heat storage are still limited to the capacities of geothermal borehole heat exchangers. The ANR Stock-en-Socle project explores the possibilities of periodic storage of sensitive heat1 in low-permeability environments that would offer much better performance than that of borehole heat exchangers, especially in terms of unit capacity. This project examines the storage possibilities of using semi-open water circulation in typically a Standing Column Well (SCW), using the strong heterogeneity of hard-rock aquifers in targeting the least favorable areas for water resources. To solve the main scientific issues, which include evaluating the minimum level of permeability required around a well as well as its evolution through time (increase and decrease) due to water-rock interaction processes, the study is based on an experimental program of fieldwork and modelling for studying the thermal, hydraulic and geochemical processes involved. This includes tracer and water-circulation tests by injecting hot water in different wells located in distinct hard-rock settings (i.e. granite and schist) in Brittany, Ploemeur (H+ observatory network) and Naizin. A numerical modelling approach allows studying the effects of permeability structures on the storage and heat-recovery capacities, whereas the modelling of reactive transfers will provide an understanding of how permeability evolves under the influence of dissolution and precipitation. Based on the obtained results, technical solutions will be studied for constructing a well of the SCW type in a low-permeability environment. This work will be completed by a technical and economic feasibility study leading to an investment and operations model. This study aims to describe the suitability of SCW storage for shallow geothermal energy. In order to reach these objectives, Stock-en-Socle is constructed around a public/private partnership between two public research organizations, G�

Organic and inorganic carbon dynamics in a karst aquifer: Santa Fe River Sink-Rise system, north Florida, USA

Science.gov (United States)

Jin, Jin; Zimmerman, Andrew R.; Moore, Paul J.; Martin, Jonathan B.

2014-03-01

Spatiotemporal variations in dissolved organic carbon (DOC), dissolved inorganic carbon (DIC), major ions concentrations and other geochemical parameters including stable carbon isotopes of DIC (δ13CDIC), were measured in surface water and deep and shallow well water samples of the Santa Fe River Sink-Rise eogenetic karst system, north Florida, USA. Three end-member water sources were identified: one DOC-rich/DIC-poor/δ13CDIC-depleted, one DOC-poor/DIC-rich/δ13CDIC-enriched, and one enriched in major ions. Given their spatiotemporal distributions, they were presumed to represent soil water, upper aquifer groundwater, and deep aquifer water sources, respectively. Using assumed ratios of Na+, Cl, and SO42- for each end-member, a mixing model calculated the contribution of each water source to each sample. Then, chemical effects of biogeochemical reactions were calculated as the difference between those predicted by the mixing model and measured species concentrations. In general, carbonate mineral dissolution occurred throughout the Sink-Rise system, surface waters were net autotrophic and the subsurface was in metabolic balance, i.e., no net DOC or DIC production or consumption. However, there was evidence for chemolithoautotrophy, perhaps by hydrogen oxidizing microbes, at some deep aquifer sites. Mineralization of this autochthonous natural dissolved organic matter (NDOM) led to localized carbonate dissolution as did surface water-derived NDOM supplied to shallow well sites during the highest flow periods. This study demonstrates linkages between hydrology, abiotic and microbial processes and carbon dynamics and has important implications for groundwater quality, karst morphologic evolution, and hydrogeologic projects such as aquifer storage and recovery in karst systems.

Carbon-14 dating of groundwater under Christchurch, 1976 samples

International Nuclear Information System (INIS)

Stewart, M.K.; Brenninkmeijer, C.A.M.; Brown, L.J.

1986-06-01

Four samples of groundwater from deep aquifers under Christchurch have been analysed for carbon-14, tritium, oxygen-18 and chemical contents. Interpretation of the carbon-14 results requires two steps, (1) correction of the measured 14 C values for input of dead ( 14 C-free) carbon underground (indicating that the measured values of 80 PMC* should be increased to about 120 PMC), and (2) determination of water residence times for given flow models of the groundwater system. Interpretation of tritium results involves step 2 only. Three models are considered, of which the third is considered most appropriate to Christchurch. In this model, the 14 C and T results indicate that a small proportion of young water (post-1954) mixes with a larger proportion of older water (probably at least several hundred years). The oxygen-18 content indicates that recharge is mainly from the Waimakariri River and possibly from rainfall and streams near the foothills of the Canterbury Plains. Other aspect of the groundwater flow under Christchurch are discussed

Distribution of organic carbon and petroleum source rock potential of Cretaceous and lower Tertiary carbonates, South Florida Basin: preliminary results

Science.gov (United States)

Palacas, James George

1978-01-01

Analyses of 134 core samples from the South Florida Basin show that the carbonates of Comanchean age are relatively richer in average organic carbon (0.41 percent) than those of Coahuilan age (0.28 percent), Gulfian age (0.18 percent) and Paleocene age (0.20 percent). They are also nearly twice as rich as the average world, wide carbonate (average 0.24 percent). The majority of carbonates have organic carbons less than 0.30 percent but the presence of many relatively organic rich beds composed of highly bituminous, argillaceous, highly stylolitic, and algal-bearing limestones and dolomites accounts for the higher percentage of organic carbon in some of the stratigraphic units. Carbonate rocks that contain greater than 0.4 percent organic carbon and that might be considered as possible petroleum sources were noted in almost each subdivision of the Coahuilan and Comanchean Series but particularly the units of Fredericksburg 'B', Trinity 'A', Trinity 'F', and Upper Sunniland. Possible source rocks have been ascribed by others to the Lower Sunniland, but lack of sufficient samples precluded any firm assessment in this initial report. In the shallower section of the basin, organic-rich carbonates containing as much as 3.2 percent organic carbon were observed in the lowermost part of the Gulfian Series and carbonate rocks with oil staining or 'dead' and 'live oil' were noted by others in the uppermost Gulfian and upper Cedar Keys Formation. It is questionable whether these shallower rocks are of sufficient thermal maturity to have generated commercial oil. The South Florida basin is still sparsely drilled and produces only from the Sunniland Limestone at an average depth of 11,500 feet (3500 m). Because the Sunniland contains good reservoir rocks and apparently adequate source rocks, and because the success rate of new oil field discoveries has increased in recent years, the chances of finding additional oil reserves in the Sunniland are promising. Furthermore, the

An integrated geophysical and hydraulic investigation to characterize a fractured-rock aquifer, Norwalk, Connecticut

Science.gov (United States)

Lane, J.W.; Williams, J.H.; Johnson, C.D.; Savino, D.M.; Haeni, F.P.

2002-01-01

The U.S. Geological Survey conducted an integrated geophysical and hydraulic investigation at the Norden Systems, Inc. site in Norwalk, Connecticut, where chlorinated solvents have contaminated a fractured-rock aquifer. Borehole, borehole-to-borehole, surface-geophysical, and hydraulic methods were used to characterize the site bedrock lithology and structure, fractures, and transmissive zone hydraulic properties. The geophysical and hydraulic methods included conventional logs, borehole imagery, borehole radar, flowmeter under ambient and stressed hydraulic conditions, and azimuthal square-array direct-current resistivity soundings. Integrated interpretation of geophysical logs at borehole and borehole-to-borehole scales indicates that the bedrock foliation strikes northwest and dips northeast, and strikes north-northeast to northeast and dips both southeast and northwest. Although steeply dipping fractures that cross-cut foliation are observed, most fractures are parallel or sub-parallel to foliation. Steeply dipping reflectors observed in the radar reflection data from three boreholes near the main building delineate a north-northeast trending feature interpreted as a fracture zone. Results of radar tomography conducted close to a suspected contaminant source area indicate that a zone of low electromagnetic (EM) velocity and high EM attenuation is present above 50 ft in depth - the region containing the highest density of fractures. Flowmeter logging was used to estimate hydraulic properties in the boreholes. Thirty-three transmissive fracture zones were identified in 11 of the boreholes. The vertical separation between transmissive zones typically is 10 to 20 ft. Open-hole and discrete-zone transmissivity was estimated from heat-pulse flowmeter data acquired under ambient and stressed conditions. The open-hole transmissivity ranges from 2 to 86 ft2/d. The estimated transmissivity of individual transmissive zones ranges from 0.4 to 68 ft2/d. Drawdown monitoring

Molecular characterization of organic matter mobilized from Bangladeshi aquifer sediment: tracking carbon compositional change during microbial utilization

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L. E. Pracht

2018-03-01

Full Text Available Bioavailable organic carbon in aquifer recharge waters and sediments can fuel microbial reactions with implications for groundwater quality. A previous incubation experiment showed that sedimentary organic carbon (SOC mobilized off sandy sediment collected from an arsenic-contaminated and methanogenic aquifer in Bangladesh was bioavailable; it was transformed into methane. We used high-resolution mass spectrometry to molecularly characterize this mobilized SOC, reference its composition against dissolved organic carbon (DOC in surface recharge water, track compositional changes during incubation, and advance understanding of microbial processing of organic carbon in anaerobic environments. Organic carbon mobilized off aquifer sediment was more diverse, proportionately larger, more aromatic, and more oxidized than DOC in surface recharge. Mobilized SOC was predominately composed of terrestrially derived organic matter and had characteristics signifying that it evaded microbial processing within the aquifer. Approximately 50 % of identified compounds in mobilized SOC and in DOC from surface recharge water contained sulfur. During incubation, after mobilized SOC was converted into methane, new organosulfur compounds with high S-to-C ratios and a high nominal oxidation state of carbon (NOSC were detected. We reason that these detected compounds formed abiotically following microbial reduction of sulfate to sulfide, which could have occurred during incubation but was not directly measured or that they were microbially synthesized. Most notably, microbes transformed all carbon types during incubation, including those currently considered thermodynamically unviable for microbes to degrade in anaerobic conditions (i.e., those with a low NOSC. In anaerobic environments, energy yields from redox reactions are small and the amount of energy required to remove electrons from highly reduced carbon substrates during oxidation decreases the thermodynamic

Molecular characterization of organic matter mobilized from Bangladeshi aquifer sediment: tracking carbon compositional change during microbial utilization

Science.gov (United States)

Pracht, Lara E.; Tfaily, Malak M.; Ardissono, Robert J.; Neumann, Rebecca B.

2018-03-01

Bioavailable organic carbon in aquifer recharge waters and sediments can fuel microbial reactions with implications for groundwater quality. A previous incubation experiment showed that sedimentary organic carbon (SOC) mobilized off sandy sediment collected from an arsenic-contaminated and methanogenic aquifer in Bangladesh was bioavailable; it was transformed into methane. We used high-resolution mass spectrometry to molecularly characterize this mobilized SOC, reference its composition against dissolved organic carbon (DOC) in surface recharge water, track compositional changes during incubation, and advance understanding of microbial processing of organic carbon in anaerobic environments. Organic carbon mobilized off aquifer sediment was more diverse, proportionately larger, more aromatic, and more oxidized than DOC in surface recharge. Mobilized SOC was predominately composed of terrestrially derived organic matter and had characteristics signifying that it evaded microbial processing within the aquifer. Approximately 50 % of identified compounds in mobilized SOC and in DOC from surface recharge water contained sulfur. During incubation, after mobilized SOC was converted into methane, new organosulfur compounds with high S-to-C ratios and a high nominal oxidation state of carbon (NOSC) were detected. We reason that these detected compounds formed abiotically following microbial reduction of sulfate to sulfide, which could have occurred during incubation but was not directly measured or that they were microbially synthesized. Most notably, microbes transformed all carbon types during incubation, including those currently considered thermodynamically unviable for microbes to degrade in anaerobic conditions (i.e., those with a low NOSC). In anaerobic environments, energy yields from redox reactions are small and the amount of energy required to remove electrons from highly reduced carbon substrates during oxidation decreases the thermodynamic favorability of

Reproducing early Martian atmospheric carbon dioxide partial pressure by modeling the formation of Mg-Fe-Ca carbonate identified in the Comanche rock outcrops on Mars

Science.gov (United States)

Berk, Wolfgang; Fu, Yunjiao; Ilger, Jan-Michael

2012-10-01

The well defined composition of the Comanche rock's carbonate (Magnesite0.62Siderite0.25Calcite0.11Rhodochrosite0.02) and its host rock's composition, dominated by Mg-rich olivine, enable us to reproduce the atmospheric CO2partial pressure that may have triggered the formation of these carbonates. Hydrogeochemical one-dimensional transport modeling reveals that similar aqueous rock alteration conditions (including CO2partial pressure) may have led to the formation of Mg-Fe-Ca carbonate identified in the Comanche rock outcrops (Gusev Crater) and also in the ultramafic rocks exposed in the Nili Fossae region. Hydrogeochemical conditions enabling the formation of Mg-rich solid solution carbonate result from equilibrium species distributions involving (1) ultramafic rocks (ca. 32 wt% olivine; Fo0.72Fa0.28), (2) pure water, and (3) CO2partial pressures of ca. 0.5 to 2.0 bar at water-to-rock ratios of ca. 500 molH2O mol-1rock and ca. 5°C (278 K). Our modeled carbonate composition (Magnesite0.64Siderite0.28Calcite0.08) matches the measured composition of carbonates preserved in the Comanche rocks. Considerably different carbonate compositions are achieved at (1) higher temperature (85°C), (2) water-to-rock ratios considerably higher and lower than 500 mol mol-1 and (3) CO2partial pressures differing from 1.0 bar in the model set up. The Comanche rocks, hosting the carbonate, may have been subjected to long-lasting (>104 to 105 years) aqueous alteration processes triggered by atmospheric CO2partial pressures of ca. 1.0 bar at low temperature. Their outcrop may represent a fragment of the upper layers of an altered olivine-rich rock column, which is characterized by newly formed Mg-Fe-Ca solid solution carbonate, and phyllosilicate-rich alteration assemblages within deeper (unexposed) units.

Influence of initial heterogeneities and recharge limitations on the evolution of aperture distributions in carbonate aquifers

Directory of Open Access Journals (Sweden)

B. Hubinger

2011-12-01

Full Text Available Karst aquifers evolve where the dissolution of soluble rocks causes the enlargement of discrete pathways along fractures or bedding planes, thus creating highly conductive solution conduits. To identify general interrelations between hydrogeological conditions and the properties of the evolving conduit systems the aperture-size frequency distributions resulting from generic models of conduit evolution are analysed. For this purpose, a process-based numerical model coupling flow and rock dissolution is employed. Initial protoconduits are represented by tubes with log-normally distributed aperture sizes with a mean μ₀ = 0.5 mm for the logarithm of the diameters. Apertures are spatially uncorrelated and widen up to the metre range due to dissolution by chemically aggressive waters. Several examples of conduit development are examined focussing on influences of the initial heterogeneity and the available amount of recharge. If the available recharge is sufficiently high the evolving conduits compete for flow and those with large apertures and high hydraulic gradients attract more and more water. As a consequence, the positive feedback between increasing flow and dissolution causes the breakthrough of a conduit pathway connecting the recharge and discharge sides of the modelling domain. Under these competitive flow conditions dynamically stable bimodal aperture distributions are found to evolve, i.e. a certain percentage of tubes continues to be enlarged while the remaining tubes stay small-sized. The percentage of strongly widened tubes is found to be independent of the breakthrough time and decreases with increasing heterogeneity of the initial apertures and decreasing amount of available water. If the competition for flow is suppressed because the availability of water is strongly limited breakthrough of a conduit pathway is inhibited and the conduit pathways widen very slowly. The resulting aperture distributions are found to be

Complex resistivity spectra in relation to multiscale pore geometry in carbonates and mixed-siliciclastic rocks

Science.gov (United States)

Norbisrath, Jan Henrik

properties. Specifically, frequency dispersion of complex resistivity in the kHz range is used as input for a new model to predict cementation factor and permeability in a wide variety of core plug samples. The underlying concept that relates CRS to flow properties is that both are related to pore geometry. CRS are linked to pore geometry by interfacial polarization effects at the fluid-rock boundary that control the phase and amplitude shift of an applied alternating current. Larger interfacial area results in higher phase shifts, but also indicates a more intricate pore structure that often results in lower permeability and higher cementation factors. The findings from this dissertation imply that (1) the CRS prediction method greatly improves estimates of cementation factors and permeability in carbonate, dolomite, and mixed siliciclastic rocks, (2) there are at least four distinct microporosity types in carbonate rocks, which have great impact on cementation factors and permeability, (3) nanopore geometry has a small impact on electrical flow properties in mudrocks where the main control on cementation factors is porosity, and (4) all sedimentary limestone and mixed carbonate-siliciclastic rocks have power law pore size distributions.

Implementation of a 3d numerical model of a folded multilayer carbonate aquifer

Science.gov (United States)

Di Salvo, Cristina; Guyennon, Nicolas; Romano, Emanuele; Bruna Petrangeli, Anna; Preziosi, Elisabetta

2016-04-01

The main objective of this research is to present a case study of the numerical model implementation of a complex carbonate, structurally folded aquifer, with a finite difference, porous equivalent model. The case study aquifer (which extends over 235 km2 in the Apennine chain, Central Italy) provides a long term average of 3.5 m3/s of good quality groundwater to the surface river network, sustaining the minimum vital flow, and it is planned to be exploited in the next years for public water supply. In the downstream part of the river in the study area, a "Site of Community Importance" include the Nera River for its valuable aquatic fauna. However, the possible negative effects of the foreseen exploitation on groundwater dependent ecosystems are a great concern and model grounded scenarios are needed. This multilayer aquifer was conceptualized as five hydrostratigraphic units: three main aquifers (the uppermost unconfined, the central and the deepest partly confined), are separated by two locally discontinuous aquitards. The Nera river cuts through the two upper aquifers and acts as the main natural sink for groundwater. An equivalent porous medium approach was chosen. The complex tectonic structure of the aquifer requires several steps in defining the conceptual model; the presence of strongly dipping layers with very heterogeneous hydraulic conductivity, results in different thicknesses of saturated portions. Aquifers can have both unconfined or confined zones; drying and rewetting must be allowed when considering recharge/discharge cycles. All these characteristics can be included in the conceptual and numerical model; however, being the number of flow and head target scarce, the over-parametrization of the model must be avoided. Following the principle of parsimony, three steady state numerical models were developed, starting from a simple model, and then adding complexity: 2D (single layer), QUASI -3D (with leackage term simulating flow through aquitards) and

Assessing groundwater availability in a folded carbonate aquifer through the development of a numerical model

Science.gov (United States)

Di Salvo, Cristina; Romano, Emanuele; Guyennon, Nicolas; Bruna Petrangeli, Anna; Preziosi, Elisabetta

2015-04-01

The study of aquifer systems from a quantitative point of view is fundamental for adopting water management plans aiming at preserving water resources and reducing environmental risks related to groundwater level and discharge changes. This is also what the European Union Water Framework Directive (WFD, 2000/60/EC) states, holding the development of numerical models as a key aspect for groundwater management. The objective of this research is to i) define a methodology for modeling a complex hydrogeological structure in a structurally folded carbonate area and ii) estimate the concurrent effects of exploitation and climate changes on groundwater availability through the implementation of a 3D groundwater flow model. This study concerns the Monte Coscerno karst aquifer located in the Apennine chain in Central Italy in the Nera River Valley.This aquifer, is planned to be exploited in the near future for water supply. Negative trends of precipitation in Central Italy have been reported in relation to global climate changes, which are expected to affect the availability of recharge to carbonate aquifers throughout the region . A great concern is the combined impact of climate change and groundwater exploitation, hence scenarios are needed taking into account the effect of possible temperature and precipitation trends on recharge rates. Following a previous experience with model conceptualization and long-term simulation of groundwater flow, an integrated three-dimensional groundwater model has been developed for the Monte Coscerno aquifer. In a previous paper (Preziosi et al 2014) the spatial distribution of recharge to this aquifer was estimated through the Thornthwaite Mather model at a daily time step using as inputs past precipitation and temperature values (1951-2013) as well as soil and landscape properties. In this paper the numerical model development is described. On the basis of well logs from private consulting companies and literature cross sections the

Nonstationary porosity evolution in mixing zone in coastal carbonate aquifer using an alternative modeling approach.

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Laabidi, Ezzeddine; Bouhlila, Rachida

2015-07-01

In the last few decades, hydrogeochemical problems have benefited from the strong interest in numerical modeling. One of the most recognized hydrogeochemical problems is the dissolution of the calcite in the mixing zone below limestone coastal aquifer. In many works, this problem has been modeled using a coupling algorithm between a density-dependent flow model and a geochemical model. A related difficulty is that, because of the high nonlinearity of the coupled set of equations, high computational effort is needed. During calcite dissolution, an increase in permeability can be identified, which can induce an increase in the penetration of the seawater into the aquifer. The majority of the previous studies used a fully coupled reactive transport model in order to model such problem. Romanov and Dreybrodt (J Hydrol 329:661-673, 2006) have used an alternative approach to quantify the porosity evolution in mixing zone below coastal carbonate aquifer at steady state. This approach is based on the analytic solution presented by Phillips (1991) in his book Flow and Reactions in Permeable Rock, which shows that it is possible to decouple the complex set of equation. This equation is proportional to the square of the salinity gradient, which can be calculated using a density driven flow code and to the reaction rate that can be calculated using a geochemical code. In this work, this equation is used in nonstationary step-by-step regime. At each time step, the quantity of the dissolved calcite is quantified, the change of porosity is calculated, and the permeability is updated. The reaction rate, which is the second derivate of the calcium equilibrium concentration in the equation, is calculated using the PHREEQC code (Parkhurst and Apello 1999). This result is used in GEODENS (Bouhlila 1999; Bouhlila and Laabidi 2008) to calculate change of the porosity after calculating the salinity gradient. For the next time step, the same protocol is used but using the updated porosity

Water-rock interaction and geochemistry of groundwater from the Ain Azel aquifer, Algeria.

Science.gov (United States)

Belkhiri, Lazhar; Mouni, Lotfi; Tiri, Ammar

2012-02-01

Hydrochemical, multivariate statistical, and inverse geochemical modeling techniques were used to investigate the hydrochemical evolution within the Ain Azel aquifer, Algeria. Cluster analysis based on major ion contents defined 3 main chemical water types, reflecting different hydrochemical processes. The first group water, group 1, has low salinity (mean EC = 735 μS/cm). The second group waters are classified as Cl-HCO(3)-alkaline earth type. The third group is made up of water samples, the cation composition of which is dominated by Ca and Mg with anion composition varying from dominantly Cl to dominantly HCO(3) plus SO(4). The varifactors obtained from R-mode FA indicate that the parameters responsible for groundwater quality variations are mainly related to the presence and dissolution of some carbonate, silicate, and evaporite minerals in the aquifer. Inverse geochemical modeling along groundwater flow paths indicates the dominant processes are the consumption of CO(2), the dissolution of dolomite, gypsum, and halite, along with the precipitation of calcite, Ca-montmorillonite, illite, kaolinite, and quartz. © Springer Science+Business Media B.V. 2011

Evaluation of permeable fractures in rock aquifers

Science.gov (United States)

Bok Lee, Hang

2015-04-01

In this study, the practical usefulness and fundamental applicability of a self-potential (SP) method for identifying the permeable fractures were evaluated by a comparison of SP methods with other geophysical logging methods and hydraulic tests. At a 10 m-shallow borehole in the study site, the candidates of permeable fractures crossing the borehole were first determined by conventional geophysical methods such as an acoustic borehole televiwer, temperature, electrical conductivity and gamma-gamma loggings, which was compared to the analysis by the SP method. Constant pressure injection and recovery tests were conducted for verification of the hydraulic properties of the fractures identified by various logging methods. The acoustic borehole televiwer and gamma-gamma loggings detected the open space or weathering zone within the borehole, but they cannot prove the possibility of a groundwater flow through the detected fractures. The temperature and electrical conductivity loggings had limitations to detect the fractured zones where groundwater in the borehole flows out to the surrounding rock aquifers. Comparison of results from different methods showed that there is a best correlation between the distribution of hydraulic conductivity and the variation of the SP signals, and the SP logging can estimate accurately the hydraulic activity as well as the location of permeable fractures. Based on the results, the SP method is recommended for determining the hydraulically-active fractures rather than other conventional geophysical loggings. This self-potential method can be effectively applied in the initial stage of a site investigation which selects the optimal location and evaluates the hydrogeological property of fractures in target sites for the underground structure including the geothermal reservoir and radioactive waste disposal.

Geochemical evolution of groundwater in carbonate aquifers of southern Latium region, central Italy

Directory of Open Access Journals (Sweden)

Giuseppe Sappa

2013-03-01

Full Text Available Spring and well water samples, from carbonate aquifers of Latium region, have been characterized to determine the hydrochemical processes governing the evolution of the groundwater. Most of the spring samples, issuing from Lepini, Ausoni and Aurunci Mts., are characterized as alkaline earth HCO3 waters, however, some samples show a composition of Cl--SO4 -- alkaline earth waters. Groundwater samples from Pontina Plain shows three different hydrochemical facies: alkaline earth HCO3 type, Cl-- SO4 -- alkaline earth type and Cl--SO4 -- alkaline type waters. Geochemical modeling and saturation index computation of the sampled waters show an interaction with calcareous and calcareous-dolomitic lithologies. Most of the springs and wells was kinetically saturated with respect to calcite and dolomite, and all the samples were below the equilibrium state with gypsum. This indicates that the groundwater has capacity to dissolve the gypsum along the flow paths. The electrical conductivity and Cl- concentrations of the sampled waters show a positive trend with the decrease in the distance from the coast, highlighting seawater intrusion in the coastal area. According to hydrochemistry results and geochemical modeling, the dominant factors in controlling the hydrochemical characteristics of groundwater are: (i water rock interaction with calcareous and calcareous-dolomitic lithologies; (ii seawater intrusion in the coastal area; (iii dissolution and/or precipitation of carbonate and (i.e. dolomite and calcite evaporate minerals (gypsum determined by saturation indexes; (iv mineral weathering process; (the high Mg/Ca ratio due to the weathering of Mg-rich dolomite.

The origin of high hydrocarbon groundwater in shallow Triassic aquifer in Northwest Guizhou, China.

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Liu, Shan; Qi, Shihua; Luo, Zhaohui; Liu, Fangzhi; Ding, Yang; Huang, Huanfang; Chen, Zhihua; Cheng, Shenggao

2018-02-01

Original high hydrocarbon groundwater represents a kind of groundwater in which hydrocarbon concentration exceeds 0.05 mg/L. The original high hydrocarbon will significantly reduce the environment capacity of hydrocarbon and lead environmental problems. For the past 5 years, we have carried out for a long-term monitoring of groundwater in shallow Triassic aquifer in Northwest Guizhou, China. We found the concentration of petroleum hydrocarbon was always above 0.05 mg/L. The low-level anthropogenic contamination cannot produce high hydrocarbon groundwater in the area. By using hydrocarbon potential, geochemistry and biomarker characteristic in rocks and shallow groundwater, we carried out a comprehensive study in Dalongjing (DLJ) groundwater system to determine the hydrocarbon source. We found a simplex hydrogeology setting, high-level water-rock-hydrocarbon interaction and obviously original hydrocarbon groundwater in DLJ system. The concentration of petroleum hydrocarbon in shallow aquifer was found to increase with the strong water-rock interaction. Higher hydrocarbon potential was found in the upper of Guanling formation (T 2 g 3 ) and upper of Yongningzhen formation (T 1 yn 4 ). Heavily saturated carbon was observed from shallow groundwater, which presented similar distribution to those from rocks, especially from the deeper groundwater. These results indicated that the high concentrations of original hydrocarbon in groundwater could be due to the hydrocarbon release from corrosion and extraction out of strata over time.

Aquifer Characterization and Groundwater Potential Evaluation in Sedimentary Rock Formation

Science.gov (United States)

Ashraf, M. A. M.; Yusoh, R.; Sazalil, M. A.; Abidin, M. H. Z.

2018-04-01

This study was conducted to characterize the aquifer and evaluate the ground water potential in the formation of sedimentary rocks. Electrical resistivity and drilling methods were used to develop subsurface soil profile for determining suitable location for tube well construction. The electrical resistivity method was used to infer the subsurface soil layer by use of three types of arrays, namely, the pole–dipole, Wenner, and Schlumberger arrays. The surveys were conducted using ABEM Terrameter LS System, and the results were analyzed using 2D resistivity inversion program (RES2DINV) software. The survey alignments were performed with maximum electrode spreads of 400 and 800 m by employing two different resistivity survey lines at the targeted zone. The images were presented in the form of 2D resistivity profiles to provide a clear view of the distribution of interbedded sandstone, siltstone, and shale as well as the potential groundwater zones. The potential groundwater zones identified from the resistivity results were confirmed using pumping, step drawdown, and recovery tests. The combination among the three arrays and the correlation between the well log and pumping test are reliable and successful in identifying potential favorable zones for obtaining groundwater in the study area.

Principal aquifers can contribute radium to sources of drinking water under certain geochemical conditions

Science.gov (United States)

Szabo, Zoltan; Fischer, Jeffrey M.; Hancock, Tracy Connell

2012-01-01

What are the most important factors affecting dissolved radium concentrations in principal aquifers used for drinking water in the United States? Study results reveal where radium was detected and how rock type and chemical processes control radium occurrence. Knowledge of the geochemical conditions may help water-resource managers anticipate where radium may be elevated in groundwater and minimize exposure to radium, which contributes to cancer risk. Summary of Major Findings: * Concentrations of radium in principal aquifers used for drinking water throughout the United States generally were below 5 picocuries per liter (pCi/L), the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) for combined radium - radium-226 (Ra-226) plus radium-228 (Ra-228) - in public water supplies. About 3 percent of sampled wells had combined radium concentrations greater than the MCL. * Elevated concentrations of combined radium were more common in groundwater in the eastern and central United States than in other regions of the Nation. About 98 percent of the wells that contained combined radium at concentrations greater than the MCL were east of the High Plains. * The highest concentrations of combined radium were in the Mid-Continent and Ozark Plateau Cambro-Ordovician aquifer system and the Northern Atlantic Coastal Plain aquifer system. More than 20 percent of sampled wells in these aquifers had combined radium concentrations that were greater than or equal to the MCL. * Concentrations of Ra-226 correlated with those of Ra-228. Radium-226 and Ra-228 occur most frequently together in unconsolidated sand aquifers, and their presence is strongly linked to groundwater chemistry. * Three common geochemical factors are associated with the highest radium concentrations in groundwater: (1) oxygen-poor water, (2) acidic conditions (low pH), and (3) high concentrations of dissolved solids.

The University of Minnesota aquifer thermal energy storage (ATES) field test facility -- system description, aquifer characterization, and results of short-term test cycles

Energy Technology Data Exchange (ETDEWEB)

Walton, M.; Hoyer, M.C.; Eisenreich, S.J.; Holm, N.L.; Holm, T.R.; Kanivetsky, R.; Jirsa, M.A.; Lee, H.C.; Lauer, J.L.; Miller, R.T.; Norton, J.L.; Runke, H. (Minnesota Geological Survey, St. Paul, MN (United States))

1991-06-01

Phase 1 of the Aquifer Thermal Energy Storage (ATES) Project at the University of Minnesota was to test the feasibility, and model, the ATES concept at temperatures above 100{degrees}C using a confined aquifer for the storage and recovery of hot water. Phase 1 included design, construction, and operation of a 5-MW thermal input/output field test facility (FTF) for four short-term ATES cycles (8 days each of heat injection, storage, and heat recover). Phase 1 was conducted from May 1980 to December 1983. This report describes the FTF, the Franconia-Ironton-Galesville (FIG) aquifer used for the test, and the four short-term ATES cycles. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are all included. The FTF consists of monitoring wells and the source and storage well doublet completed in the FIG aquifer with heat exchangers and a fixed-bed precipitator between the wells of the doublet. The FIG aquifer is highly layered and a really anisotropic. The upper Franconia and Ironton-Galesville parts of the aquifer, those parts screened, have hydraulic conductivities of {approximately}0.6 and {approximately}1.0 m/d, respectively. Primary ions in the ambient ground water are calcium and magnesium bicarbonate. Ambient temperature FIG ground water is saturated with respect to calcium/magnesium bicarbonate. Heating the ground water caused most of the dissolved calcium to precipitate out as calcium carbonate in the heat exchanger and precipitator. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water, suggesting dissolution of some constituents of the aquifer during the cycles. Further work on the ground water chemistry is required to understand water-rock interactions.

Potential for a process-based monitoring method above geologic carbon storage sites using dissolved gases in freshwater aquifers

Energy Technology Data Exchange (ETDEWEB)

Romanak, Katherine [Gulf Coast Carbon Center, Bureau of Economic Geology, The University of Texas at Austin, TX 78713 (United States); Dobeck, Laura; Spangler, Lee [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States); Dixon, Tim [IEA Greenhouse Gas R and D Programme, Cheltenham GL52 7RZ (United Kingdom)

2013-07-01

The process-based method is a new technique for monitoring CO{sub 2} storage permanence in the vadose zone above geologic carbon storage (GCS) sites. This method uses ratios of coexisting gas species to understand geochemical processes rather than comparing CO{sub 2} concentrations with large baseline data sets, thereby making monitoring more efficient. In the vadose zone, ratios among coexisting gases (CO{sub 2}, O{sub 2}, N{sub 2} and CH{sub 4}) have been used to distinguish biologic respiration, water-rock-CO{sub 2} interaction, and methane oxidation from a leakage signal. We report the preliminary results of a feasibility test conducted in July 2012 at the Zero Emission Research and Technology Center (ZERT) controlled release site in Montana, USA to discern whether the method could be applied to dissolved gases in groundwater, thereby enhancing groundwater monitoring. Preliminary results are favorable, making the process-based approach potentially useful for monitoring shallow freshwater aquifers above GCS sites. (authors)

Carbon dioxide (CO2) sequestration in deep saline aquifers and formations: Chapter 3

Science.gov (United States)

Rosenbauer, Robert J.; Thomas, Burt

2010-01-01

Carbon dioxide (CO2) capture and sequestration in geologic media is one among many emerging strategies to reduce atmospheric emissions of anthropogenic CO2. This chapter looks at the potential of deep saline aquifers – based on their capacity and close proximity to large point sources of CO2 – as repositories for the geologic sequestration of CO2. The petrochemical characteristics which impact on the suitability of saline aquifers for CO2 sequestration and the role of coupled geochemical transport models and numerical tools in evaluating site feasibility are also examined. The full-scale commercial CO2 sequestration project at Sleipner is described together with ongoing pilot and demonstration projects.

Potentiometric surface of the Upper Floridan aquifer in Florida and parts of Georgia, South Carolina, and Alabama, May – June 2010

Science.gov (United States)

Kinnaman, Sandra L.; Dixon, Joann F.

2011-01-01

The Floridan aquifer system covers nearly 100,000 square miles in the southeastern United States throughout Florida and in parts of Georgia, South Carolina, and Alabama, and is one of the most productive aquifers in the world (Miller, 1990). This sequence of carbonate rocks is hydraulically connected and is over 300 feet thick in south Florida and thins toward the north. Typically, this sequence is subdivided into the Upper Floridan aquifer, the middle confining unit, and the Lower Floridan aquifer. The majority of freshwater is contained in the Upper Floridan aquifer and is used for water supply (Miller, 1986). The Lower Floridan aquifer contains fresh to brackish water in northeastern Florida and Georgia, while in south Florida it is saline. The potentiometric surface of the Upper Floridan aquifer in May–June 2010 shown on this map was constructed as part of the U.S. Geological Survey Floridan Aquifer System Groundwater Availability Study (U.S. Geological Survey database, 2011). Previous synoptic measurements and regional potentiometric maps of the Upper Floridan aquifer were prepared for May 1980 (Johnston and others, 1981) and May 1985 (Bush and others, 1986) as part of the Floridan Regional Aquifer System Analysis.

Shallow Carbon Sequestration Demonstration Project

Energy Technology Data Exchange (ETDEWEB)

Pendergrass, Gary; Fraley, David; Alter, William; Bodenhamer, Steven

2013-09-30

The potential for carbon sequestration at relatively shallow depths was investigated at four power plant sites in Missouri. Exploratory boreholes were cored through the Davis Shale confining layer into the St. Francois aquifer (Lamotte Sandstone and Bonneterre Formation). Precambrian basement contact ranged from 654.4 meters at the John Twitty Energy Center in Southwest Missouri to over 1100 meters near the Sioux Power Plant in St. Charles County. Investigations at the John Twitty Energy Center included 3D seismic reflection surveys, downhole geophysical logging and pressure testing, and laboratory analysis of rock core and water samples. Plans to perform injectivity tests at the John Twitty Energy Center, using food grade CO{sub 2}, had to be abandoned when the isolated aquifer was found to have very low dissolved solids content. Investigations at the Sioux Plant and Thomas Hill Energy Center in Randolph County found suitably saline conditions in the St. Francois. A fourth borehole in Platte County was discontinued before reaching the aquifer. Laboratory analyses of rock core and water samples indicate that the St. Charles and Randolph County sites could have storage potentials worthy of further study. The report suggests additional Missouri areas for further investigation as well.

Lead isotopic composition of paleozoic and late proterozoic marine carbonate rocks in the vicinity of Yucca Mountains, Nevada

International Nuclear Information System (INIS)

Zartman, R.E.; Kwak, L.M.

1993-01-01

Paleozoic and Late Proterozoic marine carbonate rocks (limestones, dolomites, and their metamorphic equivalents) cropping out in the vicinity of Yucca Mountain contain lead with an isotopic composition strongly suggesting them to be a major source of the lead observed at Trench 14 in the carbonate phase of carbonate-silica veins and nearby surficial calcrete deposits. Six whole-rock samples of marine carbonate rocks yield 206 Pb/ 204 Pb = 19.21-29.06, 207 Pb/ 204 Pb = 15.74-16.01, and 208 Pb/ 204 Pb = 37.90-39.25, and leachate and residue fractions of the rocks reveal additional isotopic heterogeneity within individual samples. Two samples of eolian dust also have isotopic compositions lying along a 'carbonate' to 'silicate' mixing trend that appears to arise entirely from pedeogenic processes. The tendency for the marine carbonate rocks to evolve highly uranogenic, but not thorogenic, lead results in a distinctive isotopic composition that serves as a tracer in eolian dust and secondary carbonate minerals derived from the marine carbonate rocks

Carbon Sequestration in Saline Aquifers: Modeling Diffusive and Convective Transport Of a Carbon-­Dioxide Cap

KAUST Repository

Allen, Rebecca

2011-01-01

done on the diffusive-convective transport that occurs under a cap of CO2-saturated fluid, which results after CO2 is injected into an aquifer and spreads laterally under an area of low permeability. The diffusive-convective modeling reveals an enhanced

Characterization of fractures and flow zones in a contaminated crystalline-rock aquifer in the Tylerville section of Haddam, Connecticut

Science.gov (United States)

Johnson, Carole D.; Kiel, Kristal F.; Joesten, Peter K.; Pappas, Katherine L.

2016-10-04

The U.S. Geological Survey, in cooperation with the Connecticut Department of Energy and Environmental Protection, investigated the characteristics of the bedrock aquifer in the Tylerville section of Haddam, Connecticut, from June to August 2014. As part of this investigation, geophysical logs were collected from six water-supply wells and were analyzed to (1) identify well construction, (2) determine the rock type and orientation of the foliation and layering of the rock, (3) characterize the depth and orientation of fractures, (4) evaluate fluid properties of the water in the well, and (5) determine the relative transmissivity and head of discrete fractures or fracture zones. The logs included the following: caliper, electromagnetic induction, gamma, acoustic and (or) optical televiewer, heat-pulse flowmeter under ambient and pumped conditions, hydraulic head data, fluid electrical conductivity and temperature under postpumping conditions, and borehole-radar reflection collected in single-hole mode. In a seventh borehole, a former water-supply well, only caliper, fluid electrical conductivty, and temperature logs were collected, because of a constriction in the borehole.This report includes a description of the methods used to collect and process the borehole geophysical data, the description of the data collected in each of the wells, and a comparison of the results collected in all of the wells. The data are presented in plots of the borehole geophysical logs, tables, and figures. Collectively these data provide valuable characterizations that can be used to improve or inform site conceptual models of groundwater flow in the study area.

Why 1D electrical resistivity techniques can result in inaccurate siting of boreholes in hard rock aquifers and why electrical resistivity tomography must be preferred: the example of Benin, West Africa

Science.gov (United States)

Alle, Iboukoun Christian; Descloitres, Marc; Vouillamoz, Jean-Michel; Yalo, Nicaise; Lawson, Fabrice Messan Amen; Adihou, Akonfa Consolas

2018-03-01

Hard rock aquifers are of particular importance for supplying people with drinking water in Africa and in the world. Although the common use of one-dimensional (1D) electrical resistivity techniques to locate drilling site, the failure rate of boreholes is usually high. For instance, about 40% of boreholes drilled in hard rock aquifers in Benin are unsuccessful. This study investigates why the current use of 1D techniques (e.g. electrical profiling and electrical sounding) can result in inaccurate siting of boreholes, and checks the interest and the limitations of the use of two-dimensional (2D) Electrical Resistivity Tomography (ERT). Geophysical numerical modeling and comprehensive 1D and 2D resistivity surveys were carried out in hard rock aquifers in Benin. The experiments carried out at 7 sites located in different hard rock groups confirmed the results of the numerical modeling: the current use of 1D techniques can frequently leads to inaccurate siting, and ERT better reveals hydrogeological targets such as thick weathered zone (e.g. stratiform fractured layer and preferential weathering associated with subvertical fractured zone). Moreover, a cost analysis demonstrates that the use of ERT can save money at the scale of a drilling programme if ERT improves the success rate by only 5% as compared to the success rate obtained with 1D techniques. Finally, this study demonstrates, using the example of Benin, that the use of electrical resistivity profiling and sounding for siting boreholes in weathered hard rocks of western Africa should be discarded and replaced by the use of ERT technique, more efficient.

Attenuation of landfill leachate by UK Triassic sandstone aquifer materials. 1. Fate of inorganic pollutants in laboratory columns

Science.gov (United States)

Thornton, Steven F.; Tellam, John H.; Lerner, David N.

2000-05-01

The attenuation of inorganic contaminants in acetogenic and methanogenic landfill leachate by calcareous and carbonate-deficient, oxide-rich Triassic sandstone aquifer materials from the English Midlands was examined in laboratory columns. Aqueous equilibrium speciation modelling, simple transport modelling and chemical mass balance approaches are used to evaluate the key processes and aquifer geochemical properties controlling contaminant fate. The results indicate that leachate-rock interactions are dominated by ion-exchange processes, acid-base and redox reactions and sorption/precipitation of metal species. Leachate NH 4 is attenuated by cation exchange with the aquifer sediments; however, NH 4 migration could be described with a simple model using retardation factors. Organic acids in the acetogenic leachate buffered the system pH at low levels during flushing of the calcareous aquifer material. In contrast, equilibrium with Al oxyhydroxide phases initially buffered pH (˜4.5) during flushing of the carbonate-deficient sandstone with methanogenic leachate. This led to the mobilisation of sorbed and oxide-bound heavy metals from the aquifer sediment which migrated as a concentrated pulse at the leachate front. Abiotic reductive dissolution of Mn oxyhydroxides on each aquifer material by leachate Fe 2+ maintains high concentrations of dissolved Mn and buffers the leachate inorganic redox system. This feature is analogous to the Mn-reducing zones found in leachate plumes and in the experiments provides a sink for the leachate Fe load and other heavy metals. The availability of reactive solid phase Mn oxyhydroxides limits the duration of redox buffering and Fe attenuation by these aquifer sediments. Aquifer pH and redox buffering capacity exert a fundamental influence on leachate inorganic contaminant fate in these systems. The implications for the assessment of aquifer vulnerability at landfills are discussed and simple measurements of aquifer properties which

Groundwater-quality data in the Santa Cruz, San Gabriel, and Peninsular Ranges Hard Rock Aquifers study unit, 2011-2012: results from the California GAMA program

Science.gov (United States)

Davis, Tracy A.; Shelton, Jennifer L.

2014-01-01

Groundwater quality in the 2,400-square-mile Santa Cruz, San Gabriel, and Peninsular Ranges Hard Rock Aquifers (Hard Rock) study unit was investigated by the U.S. Geological Survey (USGS) from March 2011 through March 2012, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The Hard Rock study unit was the 35th study unit to be sampled as part of the GAMA-PBP.

Solute geochemistry of the Snake River Plain regional aquifer system, Idaho and eastern Oregon

International Nuclear Information System (INIS)

Wood, W.W.; Low, W.H.

1987-01-01

Three geochemical methods were used to determine chemical reactions that control solute concentrations in the Snake River Plain regional aquifer system: (1) calculation of a regional solute balance within the aquifer and of mineralogy in the aquifer framework to identify solute reactions, (2) comparison of thermodynamic mineral saturation indices with plausible solute reactions, and (3) comparison of stable isotope ratios of the groundwater with those in the aquifer framework. The geothermal groundwater system underlying the main aquifer system was examined by calculating thermodynamic mineral saturation indices, stable isotope ratios of geothermal water, geothermometry, and radiocarbon dating. Water budgets, hydrologic arguments, and isotopic analyses for the eastern Snake River Plain aquifer system demonstrate that most, if not all, water is of local meteoric and not juvenile or formation origin. Solute balance, isotopic, mineralogic, and thermodynamic arguments suggest that about 20% of the solutes are derived from reactions with rocks forming the aquifer framework. Reactions controlling solutes in the western Snake river basin are believed to be similar to those in the eastern basin but the regional geothermal system that underlies the Snake river Plain contains total dissolved solids similar to those in the overlying Snake River Plain aquifer system but contains higher concentrations of sodium, bicarbonate, silica, fluoride, sulfate, chloride, arsenic, boron, and lithium, and lower concentrations of calcium, magnesium, and hydrogen. 132 refs., 30 figs., 27 tabs

Survey on the characteristics of rock under low and high temperature

International Nuclear Information System (INIS)

Shin, Koich; Kitano, Koichi

1987-01-01

Rock caverns for Superconducting Magnetic Energy Storage (SMES), Radioactive Waste Disposal, or Liquified Natural Gas Storage will suffer extraordinary temperature. Therefore, authors have researched the rock characteristics under the low temperature conditions and the rock mass behavior when it is heated, by papers so far reported. As a result, rock characteristics such as strength, linear expansion coefficient, thermal conductivity etc. are found to be ready to change with temperature condition and the kind of rocks. Even an anisotropy of some kind appears under some conditions. So, when sitting those facilities before mentioned, rock characteristics under each temperature condition must be enough clarified for the purpose of the evaluation of rock cavern stability and especially, rock behavior when it is loaded dynamically under low temperature must be cleared from now on, for such studies have been few. (author)

Geochemical Investigation of the Arbuckle-Simpson Aquifer, South-Central Oklahoma, 2004-06

Science.gov (United States)

Christenson, Scott; Hunt, Andrew G.; Parkhurst, David L.

2009-01-01

dolomite. The major ion chemistry for these 34 samples is consistent with a set of water-rock interactions. Rainfall infiltrates the soil zone, where the host rock, limestone or dolomite, dissolves as a result of uptake of carbon dioxide gas. Some continued dissolution of dolomite and precipitation of calcite occur as the water flows through the saturated zone. The major ion chemistry of the two samples from wells completed in the confined part of the aquifer indicates the water is a sodium chloride type. Geochemical inverse modeling determined that mixing of calcite-saturated recharge water with brine and dissolving calcite, dolomite, and gypsum accounts for the water composition of these two samples. One of the two samples, collected at Vendome Well in Chickasaw National Recreation Area, had a mixing fraction of brine of about 1 percent. The brine component of the sample at Vendome Well is likely to account for the relatively large concentrations of many of the trace elements (potassium, fluoride, bromide, iodide, ammonia, arsenic, boron, lithium, selenium, and strontium) measured in the water sample. Carbon-14, helium-3/tritium, and chlorofluorocarbons were used to calculate ground-water ages, recharge temperatures, and mixtures of ground water in the Arbuckle-Simpson aquifer. Thirty four of 36 water samples recharged the aquifer after 1950, indicating that water is moving quickly from recharge areas to discharge at streams and springs. Two exceptions to this classification were noted in samples 6 and 15 (Vendome Well). Ground-water ages determined for these two samples by using carbon-14 are 34,000 years (site 6) and 10,500 years (site 15). Concentrations of dissolved argon, neon, and xenon in water samples were used to determine the temperature of the water when it recharged the aquifer. The mean annual air temperature at Ada, Oklahoma, is 16 degrees Celsius (C) and the median temperature of the 30 reconnaissance water samples was 18.1 C. The av

Understanding the carbon cycle in a Late Quaternary-age limestone aquifer system using radiocarbon of dissolved inorganic and organic carbon

Science.gov (United States)

Bryan, Eliza; Meredith, Karina T.; Baker, Andy; Andersen, Martin S.; Post, Vincent E. A.

2017-04-01

Estimating groundwater residence time is critical for our understanding of hydrogeological systems, for groundwater resource assessments and for the sustainable management of groundwater resources. Due to its capacity to date groundwater up to 30 thousand years old, as well as the ubiquitous nature of dissolved carbon (as organic and inorganic forms) in groundwater, 14C is the most widely used radiogenic dating technique in regional aquifers. However, the geochemistry of carbon in groundwater systems includes interaction with the atmosphere, biosphere and geosphere, which results in multiple sources and sinks of carbon that vary in time and space. Identifying these sources of carbon and processes relating to its release or removal is important for understanding the evolution of the groundwater and essential for residence time calculations. This study investigates both the inorganic and organic facets of the carbon cycle in groundwaters throughout a freshwater lens and mixing zone of a carbonate island aquifer and identifies the sources of carbon that contribute to the groundwater system. Groundwater samples were collected from shallow (5-20 m) groundwater wells on a small carbonate Island in Western Australia in September 2014 and analysed for major and minor ions, stable water isotopes (SWIs: δ18O, δ2H), 3H, 14C and 13C carbon isotope values of both DIC and DOC, and 3H. The composition of groundwater DOC was investigated by Liquid Chromatography-Organic Carbon Detection (LC-OCD) analysis. The presence of 3H (0.12 to 1.35 TU) in most samples indicates that groundwaters on the Island are modern, however the measured 14CDIC values (8.4 to 97.2 pmc) suggest that most samples are significantly older due to carbonate dissolution and recrystallisation reactions that are identified and quantified in this work. 14CDOC values (46.6 to 105.6 pMC) were higher than 14CDIC values and were well correlated with 3H values, however deeper groundwaters had lower 14CDOC values than

Total porosity of carbonate reservoir rocks by X-ray microtomography in two different spatial resolutions

International Nuclear Information System (INIS)

Nagata, Rodrigo; Appoloni, Carlos R.; Marques, Leonardo C.; Fernandes, Celso P.

2011-01-01

Carbonate reservoir rocks contain more than 50% of world's petroleum. To know carbonate rocks' structural properties is quite important to petroleum extraction. One of their main structural properties is the total porosity, which shows the rock's capacity to stock petroleum. In recent years, the X-ray microtomography had been used to analyze the structural parameters of reservoir rocks. Such nondestructive technique generates images of the samples' internal structure, allowing the evaluation of its properties. The spatial resolution is a measurement parameter that indicates the smallest structure size observable in a sample. It is possible to measure one sample using two or more different spatial resolutions in order to evaluate the samples' pore scale. In this work, two samples of the same sort of carbonate rock were measured, and in each measurement a different spatial resolution (17 μm and 7 μm) was applied. The obtained results showed that with the better resolution it was possible to measure 8% more pores than with the poorer resolution. Such difference provides us with good expectations about such approach to study the pore scale of carbonate rocks. (author)

Use of static Quantitative Microbial Risk Assessment to determine pathogen risks in an unconfined carbonate aquifer used for Managed Aquifer Recharge.

Science.gov (United States)

Toze, Simon; Bekele, Elise; Page, Declan; Sidhu, Jatinder; Shackleton, Mark

2010-02-01

Managed Aquifer Recharge (MAR) is becoming a mechanism used for recycling treated wastewater and captured urban stormwater and is being used as a treatment barrier to remove contaminants such as pathogens from the recharged water. There is still a need, however, to demonstrate the effectiveness of MAR to reduce any residual risk of pathogens in the recovered water. A MAR research site recharging secondary treated wastewater in an unconfined carbonate aquifer was used in conjunction with a static Quantitative Microbial Risk Assessment (QMRA) to assess the microbial pathogen risk in the recovered water following infiltration and aquifer passage. The research involved undertaking a detailed hydrogeological assessment of the aquifer at the MAR site and determining the decay rates of reference pathogens from an in-situ decay study. These variables along with literature data were then used in the static QMRA which demonstrated that the recovered water at this site did not meet the Australian Guidelines for recycled water when used for differing private green space irrigation scenarios. The results also confirmed the importance of obtaining local hydrogeological data as local heterogeneity can influence of residence time in the aquifer which, in turn, influences the outcomes. The research demonstrated that a static QMRA can be used to determine the residual risk from pathogens in recovered water and showed that it can be a valuable tool in the preliminary design and operation of MAR systems and the incorporation of complementary engineered treatment processes to ensure that there is acceptable health risk from the recovered water. Crown Copyright 2009. Published by Elsevier Ltd. All rights reserved.

Ultramafic-derived arsenic in a fractured bedrock aquifer

International Nuclear Information System (INIS)

Ryan, Peter C.; Kim, Jonathan; Wall, Andrew J.; Moen, Jonathan C.; Corenthal, Lilly G.; Chow, Daniel R.; Sullivan, Colleen M.; Bright, Kevin S.

2011-01-01

Highlights: → Arsenic is elevated in groundwater from a fractured bedrock aquifer system in northern Vermont, USA. → The arsenic source is serpentinized ultramafic rock. → Antigorite, magnetite (MgCO 3 ) and magnetite (Fe 3 O 4 ) appear to be the main mineralogical hosts of arsenic in the ultramafic rock. → Arsenic appears to be introduced to the ultramafic rock when As-bearing fluids are driven out of sediments during subduction. → The occurrence of serpentinized ultramafic rocks in many orogenic belts suggests that similar arsenic anomalies may occur in geologically-similar terranes globally. - Abstract: In the fractured bedrock aquifer of northern Vermont, USA, As concentrations in groundwater range from 3 ) with lesser amounts in magnetite (Fe 3 O 4 ). Hydrochemistry of monitoring wells drilled into fractured ultramafic rock in a groundwater recharge area with no anthropogenic As source reveals above background As (2-9 μg/L) and an Mg-HCO 3 hydrochemical signature that reflects dissolution of antigorite and magnesite, confirming that As in groundwater can be derived from ultramafic rock dissolution. Arsenic mobility in groundwater affected by ultramafic rock dissolution may be enhanced by alkaline pH values and relatively high HCO 3 - concentrations.

Behaviour and fate of nine recycled water trace organics during managed aquifer recharge in an aerobic aquifer.

Science.gov (United States)

Patterson, B M; Shackleton, M; Furness, A J; Bekele, E; Pearce, J; Linge, K L; Busetti, F; Spadek, T; Toze, S

2011-03-25

The fate of nine trace organic compounds was evaluated during a 12month large-scale laboratory column experiment. The columns were packed with aquifer sediment and evaluated under natural aerobic and artificial anaerobic geochemical conditions, to assess the potential for natural attenuation of these compounds during aquifer passage associated with managed aquifer recharge (MAR). The nine trace organic compounds were bisphenol A (BPA), 17β-estradiol (E2), 17α-ethynylestradiol (EE2), N-nitrosodimethylamine (NDMA), N-nitrosomorpholine (NMOR), carbamazepine, oxazepam, iohexol and iodipamide. In the low organic carbon content Spearwood sediment, all trace organics were non-retarded with retardation coefficients between 1.0 and 1.2, indicating that these compounds would travel at near groundwater velocities within the aquifer. The natural aerobic geochemical conditions provided a suitable environment for the rapid degradation for BPA, E2, iohexol (half life aquifer geochemical conditions (half life >50days). Field-based validation experiments with carbamazepine and oxazepam also showed no degradation. If persistent trace organics are present in recycled waters at concentrations in excess of their intended use, natural attenuation during aquifer passage alone may not result in extracted water meeting regulatory requirements. Additional pre treatment of the recycled water would therefore be required. Crown Copyright © 2010. Published by Elsevier B.V. All rights reserved.

CO2/Brine transport into shallow aquifers along fault zones.

Science.gov (United States)

Keating, Elizabeth H; Newell, Dennis L; Viswanathan, Hari; Carey, J W; Zyvoloski, G; Pawar, Rajesh

2013-01-02

Unintended release of CO(2) from carbon sequestration reservoirs poses a well-recognized risk to groundwater quality. Research has largely focused on in situ CO(2)-induced pH depression and subsequent trace metal mobilization. In this paper we focus on a second mechanism: upward intrusion of displaced brine or brackish-water into a shallow aquifer as a result of CO(2) injection. Studies of two natural analog sites provide insights into physical and chemical mechanisms controlling both brackish water and CO(2) intrusion into shallow aquifers along fault zones. At the Chimayó, New Mexico site, shallow groundwater near the fault is enriched in CO(2) and, in some places, salinity is significantly elevated. In contrast, at the Springerville, Arizona site CO(2) is leaking upward through brine aquifers but does not appear to be increasing salinity in the shallow aquifer. Using multiphase transport simulations we show conditions under which significant CO(2) can be transported through deep brine aquifers into shallow layers. Only a subset of these conditions favor entrainment of salinity into the shallow aquifer: high aspect-ratio leakage pathways and viscous coupling between the fluid phases. Recognition of the conditions under which salinity is favored to be cotransported with CO(2) into shallow aquifers will be important in environmental risk assessments.

aquifer in ajaokuta, southwestern nigeria

African Journals Online (AJOL)

2005-03-08

Mar 8, 2005 ... (1969) straight line method (observation well) of draw-down analysis in an unconfined aquifer (B=1) yield ... April) and a short wet season (May-September). .... DECOMPOSED. GRANITIC ROCK WITH. QUARTZ VEINS. 13.

Sinkhole susceptibility in carbonate rocks of the Apulian karst (southern Italy)

Science.gov (United States)

Di Santo, Antonio; Fazio, Nunzio L.; Fiore, Antonio; Lollino, Piernicola; Luisi, Michele; Miccoli, Maria N.; Pagliarulo, Rosa; Parise, Mario; Perrotti, Michele; Pisano, Luca; Spalluto, Luigi; Vennari, Carmela; Vessia, Giovanna

2016-04-01

modelling the instability processes, and the development of charts for a preliminary evaluation of the stability of underground caves. Two distinct approaches were established to take into account the different petrographic, structural and geotechnical features of both the hard and soft carbonate rocks. The approach dealing with hard carbonate rocks (where natural karst caves develop) is based on speleological and geometrical surveys of the caves and on an integrated geological and geomechanical characterization of the carbonate rock mass, aimed at individuating the main critical aspects of the karst caves in terms of likely effects on the society. On the other hand, the approach to verify the stability of soft rocks where artificial cavities have been excavated is mostly dependent upon the peculiar petrographic and geomechanical characteristics of the calcarenite rock mass, typically massive and unaffected by tectonic discontinuities. As a consequence, the traditional analytical methods of rock mass classification fail in these materials, since the rock strength of soft calcarenites is mostly dependent upon sediment texture, porosity type and distribution and degree of cementation. The fluid circulation into the rock mass is also important because the removal of the rock matrix may induce a rapid deterioration of the mechanical behaviour of the rock mass. The approach to the calcarenite is mostly based on the characterization of petrographic and geotechnical parameters by means of direct sampling from the rock walls and in situ surveys (wells, trenches, etc.). Through implementation of the two approaches, our goal is to reconstruct accurate geometrical, geological and geotechnical models for both natural caves and artificial cavities. These models will be useful also to plan specific monitoring activities in order to understand the development of underground instability, and the related evolution through the rock mass, possibly threatening the urban areas and

The relationship of uranium isotopes to oxidation/reduction in the Edwards carbonate aquifer of Texas

International Nuclear Information System (INIS)

Cowart, J.B.

1980-01-01

The concentration of dissolved uranium and 234 U/ 238 U alpha activity ratio ( A.R. ) were determined in water samples from 23 locations in the Edwards carbonate aquifer of south central Texas by isotope dilution methods and alpha spectrometry. (orig./ME)

Petroleum geological features and exploration prospect of deep marine carbonate rocks in China onshore: A further discussion

Directory of Open Access Journals (Sweden)

Zhao Wenzhi

2014-10-01

Full Text Available Deep marine carbonate rocks have become one of the key targets of onshore oil and gas exploration and development for reserves replacement in China. Further geological researches of such rocks may practically facilitate the sustainable, steady and smooth development of the petroleum industry in the country. Therefore, through a deep investigation into the fundamental geological conditions of deep marine carbonate reservoirs, we found higher-than-expected resource potential therein, which may uncover large oil or gas fields. The findings were reflected in four aspects. Firstly, there are two kinds of hydrocarbon kitchens which were respectively formed by conventional source rocks and liquid hydrocarbons cracking that were detained in source rocks, and both of them can provide large-scale hydrocarbons. Secondly, as controlled by the bedding and interstratal karstification, as well as the burial and hydrothermal dolomitization, effective carbonate reservoirs may be extensively developed in the deep and ultra-deep strata. Thirdly, under the coupling action of progressive burial and annealing heating, some marine source rocks could form hydrocarbon accumulations spanning important tectonic phases, and large quantity of liquid hydrocarbons could be kept in late stage, contributing to rich oil and gas in such deep marine strata. Fourthly, large-scale uplifts were formed by the stacking of multi-episodic tectonism and oil and gas could be accumulated in three modes (i.e., stratoid large-area reservoir-forming mode of karst reservoirs in the slope area of uplift, back-flow type large-area reservoir-forming mode of buried hill weathered crust karst reservoirs, and wide-range reservoir-forming mode of reef-shoal reservoirs; groups of stratigraphic and lithologic traps were widely developed in the areas of periclinal structures of paleohighs and continental margins. In conclusion, deep marine carbonate strata in China onshore contain the conditions for

Consideration of clay in rocks in discriminating carbonate reservoirs in Eastern Turkmenia

International Nuclear Information System (INIS)

Ehjvazov, A.M.

1975-01-01

A method is described for calculating the clayiness of rocks in discrimination of carbonate reservoirs of eastern Turkmenia. Carbonate deposits in eastern Turkmenia contain significant amounts of clayey material, which interferes with the collector properties of the rocks. However, in many cases the clayey limestones, when sampled, give industrial supplies of gas. Analysis of gamma-logging data with calculation of the results of sampling for layers of different porosities, as determined from the results of neutron gamma logging, showed a definite correlation between the reservoir properties of carbonate layers and the values of ΔIsub(γ) of two different gamma-logging parameters, calculated by the single ''reference'' horizon method

Evolution Procedure of Multiple Rock Cracks under Seepage Pressure

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Taoying Liu

2013-01-01

Full Text Available In practical geotechnical engineering, most of rock masses with multiple cracks exist in water environment. Under such circumstance, these adjacent cracks could interact with each other. Moreover, the seepage pressure, produced by the high water pressure, can change cracks’ status and have an impact on the stress state of fragile rocks. According to the theory of fracture mechanics, this paper discusses the law of crack initiation and the evolution law of stress intensity factor at the tip of a wing crack caused by compression-shear stress and seepage pressure. Subsequently, considering the interaction of the wing cracks and the additional stress caused by rock bridge damage, this paper proposes the intensity factor evolution equation under the combined action of compression-shear stress and seepage pressure. In addition, this paper analyzes the propagation of cracks under different seepage pressure which reveals that the existence of seepage pressure facilitates the wing crack’s growth. The result indicates that the high seepage pressure converts wing crack growth from stable form to unstable form. Meanwhile, based on the criterion and mechanism for crack initiation and propagation, this paper puts forward the mechanical model for different fracture transfixion failure modes of the crag bridge under the combined action of seepage pressure and compression-shear stress. At the last part, this paper, through investigating the flexibility tensor of the rock mass’s initial damage and its damage evolution in terms of jointed rock mass's damage mechanics, deduces the damage evolution equation for the rock mass with multiple cracks under the combined action of compression-shear stress and seepage pressure. The achievement of this investigation provides a reliable theoretical principle for quantitative research of the fractured rock mass failure under seepage pressure.

Lattice Boltzmann methods applied to large-scale three-dimensional virtual cores constructed from digital optical borehole images of the karst carbonate Biscayne aquifer in southeastern Florida

Science.gov (United States)

Sukop, Michael C.; Cunningham, Kevin J.

2014-11-01

Digital optical borehole images at approximately 2 mm vertical resolution and borehole caliper data were used to create three-dimensional renderings of the distribution of (1) matrix porosity and (2) vuggy megaporosity for the karst carbonate Biscayne aquifer in southeastern Florida. The renderings based on the borehole data were used as input into Lattice Boltzmann methods to obtain intrinsic permeability estimates for this extremely transmissive aquifer, where traditional aquifer test methods may fail due to very small drawdowns and non-Darcian flow that can reduce apparent hydraulic conductivity. Variogram analysis of the borehole data suggests a nearly isotropic rock structure at lag lengths up to the nominal borehole diameter. A strong correlation between the diameter of the borehole and the presence of vuggy megaporosity in the data set led to a bias in the variogram where the computed horizontal spatial autocorrelation is strong at lag distances greater than the nominal borehole size. Lattice Boltzmann simulation of flow across a 0.4 × 0.4 × 17 m (2.72 m3 volume) parallel-walled column of rendered matrix and vuggy megaporosity indicates a high hydraulic conductivity of 53 m s-1. This value is similar to previous Lattice Boltzmann calculations of hydraulic conductivity in smaller limestone samples of the Biscayne aquifer. The development of simulation methods that reproduce dual-porosity systems with higher resolution and fidelity and that consider flow through horizontally longer renderings could provide improved estimates of the hydraulic conductivity and help to address questions about the importance of scale.

Exploration of buried carbonate aquifers by the inverse and forward modelling of the Controlled Source Audio-Magnetotelluric data

Science.gov (United States)

Šumanovac, Franjo; Orešković, Jasna

2018-06-01

On the selected cases, Gotalovec in the area of Pannonian basin and Baška in the Dinaridic karst area, that are representing a common hydrogeological model in both regions of Croatia, CSAMT data together with data of other geophysical methods (electrical resistivity tomography, electrical sounding and seismic reflection) enabled the definition of a reliable prognostic geological model. The model consists of carbonate aquifer which underlies an impermeable thick package of clastic deposits. There are great variations of the dolomitic aquifer depths in the Gotalovec area due to strong tectonic activity, while in the Baška area depth changes are caused by the layer folding. The CSAMT method provides the most complete data on lithological and structural relationships in cases of hydrogeological targets deeper than 100 m. Based on the presented models we can conclude that the CSAMT method can provide greater exploration depth than electrical resistivity tomography (ERT) and can be considered as a fundamental geophysical method for exploration of buried carbonate aquifers, deeper than 100 m. But, the CSAMT research may demonstrate its advantages only in the case of very dense layout of CSAMT stations (25-50 m), due to the greater sensitivity to noise in relation to resistivity methods. Interpretation of CSAMT data is more complex in relation to resistivity methods, and a forward modelling method sometimes gives better results than an inversion due to possibility of the use of additional data acquired by other geophysical methods (ERT, electrical sounding and seismic reflection). At greater depths, the resolution of all electrical methods including the CSAMT method is significantly reduced, and seismic reflection can be very useful to resolve deeper lithological interfaces.

Metal release from sandstones under experimentally and numerically simulated CO2 leakage conditions.

Science.gov (United States)

Kirsch, Katie; Navarre-Sitchler, Alexis K; Wunsch, Assaf; McCray, John E

2014-01-01

Leakage of CO2 from a deep storage formation into an overlying potable aquifer may adversely impact water quality and human health. Understanding CO2-water-rock interactions is therefore an important step toward the safe implementation of geologic carbon sequestration. This study targeted the geochemical response of siliclastic rock, specifically three sandstones of the Mesaverde Group in northwestern Colorado. To test the hypothesis that carbonate minerals, even when present in very low levels, would be the primary source of metals released into a CO2-impacted aquifer, two batch experiments were conducted. Samples were reacted for 27 days with water and CO2 at partial pressures of 0.01 and 1 bar, representing natural background levels and levels expected in an aquifer impacted by a small leakage, respectively. Concentrations of major (e.g., Ca, Mg) and trace (e.g., As, Ba, Cd, Fe, Mn, Pb, Sr, U) elements increased rapidly after CO2 was introduced into the system, but did not exceed primary Maximum Contaminant Levels set by the U.S. Environmental Protection Agency. Results of sequential extraction suggest that carbonate minerals, although volumetrically insignificant in the sandstone samples, are the dominant source of mobile metals. This interpretation is supported by a simple geochemical model, which could simulate observed changes in fluid composition through CO2-induced calcite and dolomite dissolution.

Carbonate Melt Rocks from the Haughton Impact Structure, Devon Island, Nunavut, Canada

Science.gov (United States)

Osinski, G. R.; Spray, J. G.; Lee, P.

2002-01-01

The target rocks at the Haughton impact structure, Canada, are predominantly carbonates. The well preserved allochthonous crater-fill deposits are reinterpreted here as being carbonatitic impact melt rocks. The implications of our findings will be discussed. Additional information is contained in the original extended abstract.

Hydrogeologic framework and salinity distribution of the Floridan aquifer system of Broward County, Florida

Science.gov (United States)

Reese, Ronald S.; Cunningham, Kevin J.

2014-01-01

Concerns about water-level decline and seawater intrusion in the surficial Biscayne aquifer, currently the principal source of water supply to Broward County, prompted a study to refine the hydrogeologic framework of the underlying Floridan aquifer system to evaluate its potential as an alternative source of supply. This report presents cross sections that illustrate the stratigraphy and hydrogeology in eastern Broward County; maps of the upper surfaces and thicknesses of several geologic formations or units within the Floridan aquifer system; and maps of two of the potentially productive water-bearing zones within the system, the Upper Floridan aquifer and the Avon Park permeable zone. An analysis of data on rock depositional textures, associated pore networks, and flow zones in the Floridan aquifer system shows that groundwater moves through the system in two ways. These data support a conceptual, dual-porosity model of the system wherein groundwater moves either as concentrated flow in discrete, thin bedding-plane vugs or zones of vuggy megaporosity, or as diffuse flow through rocks with primarily interparticle and moldic-particle porosity. Because considerable exchange of groundwater may occur between the zones of vuggy and matrix-dominated porosity, understanding the distribution of that porosity and flow zone types is important to evaluating the suitability of the several units within the Floridan aquifer system for managing the water through practices such as aquifer storage and recovery (ASR). The salinity of the water in the Floridan aquifer system is highest in the central part of the study area, and lower toward the north and south. Although salinity generally increases with depth, in the western part of the study area a zone of relatively high saline water is perched above water of lower salinity in the underlying Avon Park permeable zone. Overall, the areas of highest salinity in the aquifer system coincide with those with the lowest estimated

Quantification of the impacts of coalmine water irrigation on the underlying aquifers

Energy Technology Data Exchange (ETDEWEB)

Vermeulen, D.; Usher, B.; van Tonder, G. [University of Free State, Bloemfontein (South Africa). Institute of Groundwater Studies

2009-07-15

It is predicted that vast volumes of affected mine water will be produced by mining activities in the Mpumalanga coalfields of South Africa, The potential environmental impact of this excess water is of great concern in a water-scarce country like South Africa. Research over a period of more than 10 years has shown that this water can be used successfully for the irrigation of a range of crops. There is, however, continuing concern from the local regulators regarding the long-term impact that large-scale mine water irrigation may have on groundwater quality and quantity. Detailed research has been undertaken over the last three years to supplement the groundwater monitoring programme at five different pilot sites, on both virgin soils (greenfields) and in coalmining spoils. These sites range from sandy soils to very clayey soils. The research has included soil moisture measurements, collection of in situ soil moisture over time, long-term laboratory studies of the leaching and attenuation properties of different soils and the impact of irrigation on acid rock drainage processes, and in depth determination of the hydraulic properties of the subsurface at each of these sites, including falling head tests, pumping tests and point dilution tests. This has been supported by geochemical modelling of these processes to quantify the impacts. The results indicate that many of the soils have considerable attenuation capacities and that in the period of irrigation, a large proportion of the salts have been contained in the upper portions of the unsaturated zones below each irrigation pivot. The volumes and quality of water leaching through to the aquifers have been quantified at each site. From this mixing ratios have been calculated in order to determine the effect of the irrigation water on the underlying aquifers.

Biodiversity on the Rocks: Macrofauna Inhabiting Authigenic Carbonate at Costa Rica Methane Seeps.

Directory of Open Access Journals (Sweden)

Lisa A Levin

Full Text Available Carbonate communities: The activity of anaerobic methane oxidizing microbes facilitates precipitation of vast quantities of authigenic carbonate at methane seeps. Here we demonstrate the significant role of carbonate rocks in promoting diversity by providing unique habitat and food resources for macrofaunal assemblages at seeps on the Costa Rica margin (400-1850 m. The attendant fauna is surprisingly similar to that in rocky intertidal shores, with numerous grazing gastropods (limpets and snails as dominant taxa. However, the community feeds upon seep-associated microbes. Macrofaunal density, composition, and diversity on carbonates vary as a function of seepage activity, biogenic habitat and location. The macrofaunal community of carbonates at non-seeping (inactive sites is strongly related to the hydrography (depth, temperature, O2 of overlying water, whereas the fauna at sites of active seepage is not. Densities are highest on active rocks from tubeworm bushes and mussel beds, particularly at the Mound 12 location (1000 m. Species diversity is higher on rocks exposed to active seepage, with multiple species of gastropods and polychaetes dominant, while crustaceans, cnidarians, and ophiuroids were better represented on rocks at inactive sites. Macro-infauna (larger than 0.3 mm from tube cores taken in nearby seep sediments at comparable depths exhibited densities similar to those on carbonate rocks, but had lower diversity and different taxonomic composition. Seep sediments had higher densities of ampharetid, dorvilleid, hesionid, cirratulid and lacydoniid polychaetes, whereas carbonates had more gastropods, as well as syllid, chrysopetalid and polynoid polychaetes. Stable isotope signatures and metrics: The stable isotope signatures of carbonates were heterogeneous, as were the food sources and nutrition used by the animals. Carbonate δ13Cinorg values (mean = -26.98‰ ranged from -53.3‰ to +10.0‰, and were significantly heavier than

Application of probabilistic facies prediction and estimation of rock physics parameters in a carbonate reservoir from Iran

International Nuclear Information System (INIS)

Karimpouli, Sadegh; Hassani, Hossein; Nabi-Bidhendi, Majid; Khoshdel, Hossein; Malehmir, Alireza

2013-01-01

In this study, a carbonate field from Iran was studied. Estimation of rock properties such as porosity and permeability is much more challenging in carbonate rocks than sandstone rocks because of their strong heterogeneity. The frame flexibility factor (γ) is a rock physics parameter which is related not only to pore structure variation but also to solid/pore connectivity and rock texture in carbonate reservoirs. We used porosity, frame flexibility factor and bulk modulus of fluid as the proper parameters to study this gas carbonate reservoir. According to rock physics parameters, three facies were defined: favourable and unfavourable facies and then a transition facies located between these two end members. To capture both the inversion solution and associated uncertainty, a complete implementation of the Bayesian inversion of the facies from pre-stack seismic data was applied to well data and validated with data from another well. Finally, this method was applied on a 2D seismic section and, in addition to inversion of petrophysical parameters, the high probability distribution of favorable facies was also obtained. (paper)

Use of sinkhole and specific capacity distributions to assess vertical gradients in a karst aquifer

Science.gov (United States)

McCoy, K.J.; Kozar, M.D.

2008-01-01

The carbonate-rock aquifer in the Great Valley, West Virginia, USA, was evaluated using a database of 687 sinkholes and 350 specific capacity tests to assess structural, lithologic, and topographic influences on the groundwater flow system. The enhanced permeability of the aquifer is characterized in part by the many sinkholes, springs, and solutionally enlarged fractures throughout the valley. Yet, vertical components of subsurface flow in this highly heterogeneous aquifer are currently not well understood. To address this problem, this study examines the apparent relation between geologic features of the aquifer and two spatial indices of enhanced permeability attributed to aquifer karstification: (1) the distribution of sinkholes and (2) the occurrence of wells with relatively high specific capacity. Statistical results indicate that sinkholes (funnel and collapse) occur primarily along cleavage and bedding planes parallel to subparallel to strike where lateral or downward vertical gradients are highest. Conversely, high specific capacity values are common along prominent joints perpendicular or oblique to strike. The similarity of the latter distribution to that of springs suggests these fractures are areas of upward-convergent flow. These differences between sinkhole and high specific capacity distributions suggest vertical flow components are primarily controlled by the orientation of geologic structure and associated subsurface fracturing. ?? 2007 Springer-Verlag.

Hydraulic characterization of volcanic rocks in Pahute Mesa using an integrated analysis of 16 multiple-well aquifer tests, Nevada National Security Site, 2009–14

Science.gov (United States)

Garcia, C. Amanda; Jackson, Tracie R.; Halford, Keith J.; Sweetkind, Donald S.; Damar, Nancy A.; Fenelon, Joseph M.; Reiner, Steven R.

2017-01-20

An improved understanding of groundwater flow and radionuclide migration downgradient from underground nuclear-testing areas at Pahute Mesa, Nevada National Security Site, requires accurate subsurface hydraulic characterization. To improve conceptual models of flow and transport in the complex hydrogeologic system beneath Pahute Mesa, the U.S. Geological Survey characterized bulk hydraulic properties of volcanic rocks using an integrated analysis of 16 multiple-well aquifer tests. Single-well aquifer-test analyses provided transmissivity estimates at pumped wells. Transmissivity estimates ranged from less than 1 to about 100,000 square feet per day in Pahute Mesa and the vicinity. Drawdown from multiple-well aquifer testing was estimated and distinguished from natural fluctuations in more than 200 pumping and observation wells using analytical water-level models. Drawdown was detected at distances greater than 3 miles from pumping wells and propagated across hydrostratigraphic units and major structures, indicating that neither faults nor structural blocks noticeably impede or divert groundwater flow in the study area.Consistent hydraulic properties were estimated by simultaneously interpreting drawdown from the 16 multiple-well aquifer tests with an integrated groundwater-flow model composed of 11 well-site models—1 for each aquifer test site. Hydraulic properties were distributed across volcanic rocks with the Phase II Pahute Mesa-Oasis Valley Hydrostratigraphic Framework Model. Estimated hydraulic-conductivity distributions spanned more than two orders of magnitude in hydrostratigraphic units. Overlapping hydraulic conductivity ranges among units indicated that most Phase II Hydrostratigraphic Framework Model units were not hydraulically distinct. Simulated total transmissivity ranged from 1,600 to 68,000 square feet per day for all pumping wells analyzed. High-transmissivity zones exceeding 10,000 square feet per day exist near caldera margins and extend

Pore space quantification of carbonate rocks before-after supercritical CO2 interaction by optical image analysis

Science.gov (United States)

Berrezueta, Edgar; José Domínguez-Cuesta, María

2017-04-01

The aim of this research is to show an experimental application of an automated quantification process of optical porosity in thin sections. Petrographic studies using scanning electronic microscopy, optical microscopy (OpM) and optical image analysis (OIA) could provide a reproducible pore characterization of carbonate rocks in applications related to the geological storage of CO2. This research is focused on i) the quantification of optical pores in a carbonate rock before and after supercritical CO2-rich brine (P ≈ 7.5 MPa and T ≈ 35 °C) and ii) the description of the process followed to guarantee the reproducibility of the OIA method on images acquired with high-resolution scanner. Mineral images were acquired from thin sections using a high-resolution scanner (HRS). Digital images were geo-referenced by using geographic information system to ensure correct spatial correlation and superposition. The optical measures of porosity by image analysis on the carbonates thin sections showed an effective pore segmentation considering different cross-polarized light conditions (90°/0°; 120°/30°) and plane-polarized light conditions (90°/-) of the same petrographic scene. The pore characterization by OpM and OIA-HRS has allowed a preliminary approximation of pore evolution in carbonate rocks under the supercritical CO2-rich brine. This study shows a fast, effective and reproducible methodology that allowed a preliminary characterization (changes in the pore network) of the samples studied. The procedure carried out could be applied to similar experimental injection tests.

Petrophysical laboratory invertigations of carbon dioxide storage in a subsurface saline aquifer in Ketzin/Germany within the scope of CO2SINK

Science.gov (United States)

Zemke, K.; Kummmerow, J.; Wandrey, M.; Co2SINK Group

2009-04-01

Since June of 2008 carbon dioxide has been injected into a saline aquifer at the Ketzin test site [Würdemann et al., this volume]. The food grade CO2 is injected into a sandstone zone of the Stuttgart formation at ca. 650 m depth at 35°C reservoir temperature and 62 bar reservoir pressure. With the injection of CO2 into the geological formation, chemical and physical reservoir characteristics are changed depending on pressure, temperature, fluid chemistry and rock composition. Fluid-rock interaction could comprise dissolution of non-resistant minerals in CO2-bearing pore fluids, cementing of the pore space by precipitating substances from the pore fluid, drying and disintegration of clay minerals and thus influence of the composition and activities of the deep biosphere. To testing the injection behaviour of CO2 in water saturated rock and to evaluate the geophysical signature depending on the thermodynamic conditions, flow experiments with water and CO2 have been performed on cores of the Stuttgart formation from different locations including new wells of ketzin test site. The studied core material is an unconsolidated fine-grained sandstone with porosity values from 15 to 32 %. Permeability, electrical resistivity, and sonic wave velocities and their changes with pressure, saturation and time have been studied under simulated in situ conditions. The flow experiments conducted over several weeks with brine and CO2 showed no significant changes of resistivity and velocity and a slightly decreasing permeability. Pore fluid analysis showed mobilization of clay and some other components. A main objective of the CO2Sink laboratory program is the assessment of the effect of long-term CO2 exposure on reservoir rocks to predict the long-term behaviour of geological CO2 storage. For this CO2 exposure experiments reservoir rock samples were exposed to CO2 saturated reservoir fluid in corrosion-resistant high pressure vessels under in situ temperature and pressure

Geochemical studies of backfill aggregates, lake sediment cores and the Hueco Bolson Aquifer

Science.gov (United States)

Thapalia, Anita

This dissertation comprises of three different researches that focuses on the application of geochemistry from aggregates, lake sediment cores and Hueco Bolson Aquifer. Each study is independent and presented in the publication format. The first chapter is already published and the second chapter is in revision phase. Overall, three studies measure the large scale (field) as well as bench scale (lab) water-rock interactions influenced by the climatic and anthropogenic factors spans from the field of environmental geology to civil engineering. The first chapter of this dissertation addresses the chemical evaluation of coarse aggregates from six different quarries in Texas. The goal of this work is to find out the best geochemical methods for assessing the corrosion potential of coarse aggregates prior to their use in mechanically stabilized earth walls. Electrochemical parameters help to define the corrosion potential of aggregates following two different leaching protocols. Testing the coarse and fine aggregates demonstrate the chemical difference due to size-related kinetic leaching effects. Field fines also show different chemistry than the bulk rock indicating the weathering impact on carbonate rocks. The second chapter investigates zinc (Zn) isotopic signatures from eight lake sediment cores collected both from pristine lakes and those impacted by urban anthropogenic contamination. Zinc from the natural weathering of rocks and anthropogenic atmospheric pollutants are transported to these lakes and the signatures are recorded in the sediments. Isotopic analysis of core samples provides the signature of anthropogenic contamination sources. Dated sediment core and isotopic analysis can identify Zn inputs that are correlated to the landuse and population change of the watersheds. Comparison of isotopic data from both pristine and urban lake sediment core also serves as an analog in other lake sediment cores in the world. The third chapter studies on Hueco Bolson

Revised hydrogeologic framework of the Floridan aquifer system in Florida and parts of Georgia, Alabama, and South Carolina

Science.gov (United States)

Williams, Lester J.; Kuniansky, Eve L.

2015-04-08

The hydrogeologic framework for the Floridan aquifer system has been revised throughout its extent in Florida and parts of Georgia, Alabama, and South Carolina. The updated framework generally conforms to the original framework established by the U.S. Geological Survey in the 1980s, except for adjustments made to the internal boundaries of the Upper and Lower Floridan aquifers and the individual higher and contrasting lower permeability zones within these aquifers. The system behaves as one aquifer over much of its extent; although subdivided vertically into two aquifer units, the Upper and Lower Floridan aquifers. In the previous framework, discontinuous numbered middle confining units (MCUI–VII) were used to subdivide the system. In areas where less-permeable rocks do not occur within the middle part of the system, the system was previously considered one aquifer and named the Upper Floridan aquifer. In intervening years, more detailed data have been collected in local areas, resulting in some of the same lithostratigraphic units in the Floridan aquifer system being assigned to the Upper or Lower Floridan aquifer in different parts of the State of Florida. Additionally, some of the numbered middle confining units are found to have hydraulic properties within the same order of magnitude as the aquifers. A new term “composite unit” is introduced for lithostratigraphic units that cannot be defined as either a confining or aquifer unit over their entire extent. This naming convention is a departure from the previous framework, in that stratigraphy is used to consistently subdivide the aquifer system into upper and lower aquifers across the State of Florida. This lithostratigraphic mapping approach does not change the concept of flow within the system. The revised boundaries of the Floridan aquifer system were mapped by considering results from local studies and regional correlations of lithostratigraphic and hydrogeologic units or zones. Additional zones within

The geomechanical strength of carbonate rock in Kinta valley, Ipoh, Perak Malaysia

Science.gov (United States)

Mazlan, Nur Amanina; Lai, Goh Thian; Razib, Ainul Mardhiyah Mohd; Rafek, Abdul Ghani; Serasa, Ailie Sofyiana; Simon, Norbert; Surip, Noraini; Ern, Lee Khai; Mohamed, Tuan Rusli

2018-04-01

The stability of both cut rocks and underground openings were influenced by the geomechanical strength of rock materials, while the strength characteristics are influenced by both material characteristics and the condition of weathering. This paper present a systematic approach to quantify the rock material strength characteristics for material failure and material & discontinuities failure by using uniaxial compressive strength, point load strength index and Brazilian tensile strength for carbonate rocks. Statistical analysis of the results at 95 percent confidence level showed that the mean value of compressive strength, point load strength index and Brazilian tensile strength for with material failure and material & discontinuities failure were 76.8 ± 4.5 and 41.2 ± 4.1 MPa with standard deviation of 15.2 and 6.5 MPa, respectively. The point load strength index for material failure and material & discontinuities failure were 3.1 ± 0.2 MPa and 1.8 ± 0.3 MPa with standard deviation of 0.9 and 0.6 MPa, respectively. The Brazilian tensile strength with material failure and material & discontinuities failure were 7.1 ± 0.3 MPa and 4.1 ± 0.3 MPa with standard deviation of 1.4 and 0.6 MPa, respectively. The results of this research revealed that the geomechanical strengths of rock material of carbonate rocks for material & discontinuities failure deteriorates approximately ½ from material failure.

Palaeoclimatic trends deduced from the hydrochemistry of a Triassic sandstone aquifer, United Kingdom

International Nuclear Information System (INIS)

Bath, A.H.; Edmunds, W.M.; Andrews, J.N.

1979-01-01

A detailed geochemical study (elemental, isotopic and dissolved inert gases) of unconfined and confined sections of the Triassic non-marine sandstone aquifer in eastern England has been undertaken. Aspects of the recharge history of this aquifer over the past 40,000 years are revealed by examination of the data. 14 C activity and delta 13 C values show downgradient decrease and increase, respectively, the latter from -12 to -13 per mille (PDB) at outcrop to -8.5 per mille in deep confined groundwaters, indicating a continuing reaction between water and carbonate mineral phases. Although the bulk carbonate contained in sandstone samples gives delta 13 C around -7 per mille, modelling of the carbon isotopic evolution and consideration of the resulting 14 C age corrections suggest that a carbonate with delta 13 C closer to 0 per mille has played a major role in at least the earlier stages of hydrochemical evolution. The corrected radiocarbon age ranges, generated by the computer program WATEQF-ISOTOP, are used as a framework in which the palaeo-environmental information from oxygen and hydrogen isotope data, inert gas contents, and chloride levels are discussed. The measurement of dissolved helium levels demonstrates an excess of 4 He in many samples, which correlates with radiocarbon ages. The assumption of bulk chemical and physical properties for the aquifer rock allows independent 'excess 4 He' ages to be computed, which are mostly in excess of the corrected 14 C ages. The trend of delta 18 O is from about -8 per mille at outcrop to -9.7 per mille (SMOW) downgradient, which is significantly more depleted than has been found in previous studies of UK basins. The delta 2 H and delta 18 O values are related by the regression line delta 2 H=6.6delta 18 O+1; data from other UK studies also lie close to this trend

Quality of water from crystalline rock aquifers in New England, New Jersey, and New York, 1995-2007

Science.gov (United States)

Flanagan, Sarah M.; Ayotte, Joseph D.; Robinson, Gilpin R.

2012-06-25

Crystalline bedrock aquifers in New England and parts of New Jersey and New York (NECR aquifers) are a major source of drinking water. Because the quality of water in these aquifers is highly variable, the U.S. Geological Survey (USGS) statistically analyzed chemical data on samples of untreated groundwater collected from 117 domestic bedrock wells in New England, New York, and New Jersey, and from 4,775 public-supply bedrock wells in New England to characterize the quality of the groundwater. The domestic-well data were from samples collected by the USGS National Water-Quality Assessment (NAWQA) Program from 1995 through 2007. The public-supply-well data were from samples collected for the U.S. Environmental Protection Agency (USEPA) Safe Drinking Water Act (SDWA) Program from 1997 through 2007. Chemical data compiled from the domestic wells include pH, specific conductance, dissolved oxygen, alkalinity, and turbidity; 6 nitrogen and phosphorus compounds, 14 major ions, 23 trace elements, 222radon gas (radon), 48 pesticide compounds, and 82 volatile organic compounds (VOCs). Additional samples were collected from the domestic wells for the analysis of gross alpha- and gross beta-particle radioactivity, radium isotopes, chlorofluorocarbon isotopes, and the dissolved gases methane, carbon dioxide, nitrogen, and argon. Chemical data compiled from the public-supply wells include pH, specific conductance, nitrate, iron, manganese, sodium, chloride, fluoride, arsenic, uranium, radon, combined radium (226radium plus 228radium), gross alpha-particle radioactivity, and methyl tert-butyl ether (MtBE).Patterns in fluoride, arsenic, uranium, and radon distributions were discernable when the data were compared to lithology groupings of the bedrock, indicating that the type of bedrock has an effect on the quality of groundwater from NECR aquifers. Fluoride concentrations were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and

Carbon dynamics in a Late Quaternary-age coastal limestone aquifer system undergoing saltwater intrusion.

Science.gov (United States)

Bryan, Eliza; Meredith, Karina T; Baker, Andy; Andersen, Martin S; Post, Vincent E A

2017-12-31

This study investigates the inorganic and organic aspects of the carbon cycle in groundwaters throughout the freshwater lens and transition zone of a carbonate island aquifer and identifies the transformation of carbon throughout the system. We determined 14 C and 13 C carbon isotope values for both DIC and DOC in groundwaters, and investigated the composition of DOC throughout the aquifer. In combination with hydrochemical and 3 H measurements, the chemical evolution of groundwaters was then traced from the unsaturated zone to the deeper saline zone. The data revealed three distinct water types: Fresh (F), Transition zone 1 (T1) and Transition zone 2 (T2) groundwaters. The 3 H values in F and T1 samples indicate that these groundwaters are mostly modern. 14 C DOC values are higher than 14 C DIC values and are well correlated with 3 H values. F and T1 groundwater geochemistry is dominated by carbonate mineral recrystallisation reactions that add dead carbon to the groundwater. T2 groundwaters are deeper, saline and characterised by an absence of 3 H, lower 14 C DOC values and a different DOC composition, namely a higher proportion of Humic Substances relative to total DOC. The T2 groundwaters are suggested to result from either the slow circulation of water within the seawater wedge, or from old remnant seawater caused by past sea level highstands. While further investigations are required to identify the origin of the T2 groundwaters, this study has identified their occurrence and shown that they did not evolve along the same pathway as fresh groundwaters. This study has also shown that a combined approach using 14 C and 13 C carbon isotope values for both DIC and DOC and the composition of DOC, as well as hydrochemical and 3 H measurements, can provide invaluable information regarding the transformation of carbon in a groundwater system and the evolution of fresh groundwater recharge. Copyright © 2017 Elsevier B.V. All rights reserved.

Estimating Poromechanical and Hydraulic Properties of Fractured Media Aquifers Using a Model of the Aquifer at Ploemeur France: Broad Applications and Future Uses

Science.gov (United States)

Wilson, M. W.; Burbey, T. J.

2017-12-01

Aquifers in fractured crystalline bedrock are located over half of the earth's surface and are vital civil and economic resources particularly in places where ample, safe surface water is not available. With fractured media aquifers providing large percentages of water for municipal, industrial, and agricultural use in many regions of the world. Distinguishing sustainable quantities of extraction is of paramount importance to the continuing viability of these important resources and the communities they serve. The fractured and faulted crystalline-rock aquifer system supporting the community of Ploemeur France has been providing one million cubic meters of water annually, resulting in a modest long-term drawdown of about 15m. To understand the sources and mechanisms of recharge that support this aquifer system, a three-dimensional ABAQUS model was developed using known geologic, water-level and geodetic (tiltmeters and GPS) data to simulate the natural aquifer system that is dominated by a permeable sub-vertical fault and an intersecting semi-horizontal contact zone. The model is used to constrain the poromechanical properties of the fault and contact zones relative to the host crystalline rocks and overlying saprolite by taking advantage of the tilt and seasonal GPS responses caused by municipal pumping along with water-level data for the area. A chief goal in this modeling effort is to assess the sources of recharge to this aquifer system that is atypically productive for a crystalline-rock setting. Preliminary results suggest that the source of water supplying this community is a combination of rapid localized recharge through the saprolite and fault zone and recharge along the contact zone, both from the north (older water) and where it is exposed to the south (younger water). The modeling effort also shows the importance of combining GPS and surface tiltmeter data with water-level measurements for constraining the properties of this complex aquifer system and

The addition of organic carbon and nitrate affects reactive transport of heavy metals in sandy aquifers

KAUST Repository

Satyawali, Yamini

2011-04-01

Organic carbon introduction in the soil to initiate remedial measures, nitrate infiltration due to agricultural practices or sulphate intrusion owing to industrial usage can influence the redox conditions and pH, thus affecting the mobility of heavy metals in soil and groundwater. This study reports the fate of Zn and Cd in sandy aquifers under a variety of plausible in-situ redox conditions that were induced by introduction of carbon and various electron acceptors in column experiments. Up to 100% Zn and Cd removal (from the liquid phase) was observed in all the four columns, however the mechanisms were different. Metal removal in column K1 (containing sulphate), was attributed to biological sulphate reduction and subsequent metal precipitation (as sulphides). In the presence of both nitrate and sulphate (K2), the former dominated the process, precipitating the heavy metals as hydroxides and/or carbonates. In the presence of sulphate, nitrate and supplemental iron (Fe(OH)3) (K3), metal removal was also due to precipitation as hydroxides and/or carbonates. In abiotic column, K4, (with supplemental iron (Fe(OH)3), but no nitrate), cation exchange with soil led to metal removal. The results obtained were modeled using the reactive transport model PHREEQC-2 to elucidate governing processes and to evaluate scenarios of organic carbon, sulphate and nitrate inputs. © 2010 Elsevier B.V.

Identification and Quantification of Carbonate Species Using Rock-Eval Pyrolysis

Directory of Open Access Journals (Sweden)

Pillot D.

2013-03-01

Full Text Available This paper presents a new reliable and rapid method to characterise and quantify carbonates in solid samples based on monitoring the CO2 flux emitted by progressive thermal decomposition of carbonates during a programmed heating. The different peaks of destabilisation allow determining the different types of carbonates present in the analysed sample. The quantification of each peak gives the respective proportions of these different types of carbonates in the sample. In addition to the chosen procedure presented in this paper, using a standard Rock-Eval 6 pyrolyser, calibration characteristic profiles are also presented for the most common carbonates in nature. This method should allow different types of application for different disciplines, either academic or industrial.

Groundwater characteristics and problems in volcanic rock terrains

International Nuclear Information System (INIS)

Custodio, E.

1989-01-01

Volcanic rock formations, each with their own particular hydrogeological characteristics, occur in circumstances that cover a multiplicity of situations. These range from permeable porous rock formations to permeable fissured formations and include all types of intermediate situation between the two. The type of volcanism, distance from the source of emission, age, alteration processes and tectonics are all factors which determine their behaviour. Volcanic formations usually constitute a single aquifer system, even though this may be very heterogeneous and may locally be separated into clearly defined subunits. At times, formations may be hundreds of metres thick and are fairly permeable almost throughout. As a rule, volcanic material does not yield directly soluble salts to the water that flows through it. Mineralization of the water is due to the concentration of rainfall and the hydrolysis of silicates as a result of CO 2 being absorbed from the atmosphere and the ground, or as a result of volcanism itself. Cationic grouping is usually closely correlated to that of the rock formation in which the chemical composition is formed. Most environmental isotope and radioisotope techniques may be used, and at times are of unquestionable value. However, the existence of evaporation in the soil with possible isotopic fractionation, the effects of marked relief, the dilution of dissolved carbon by volcanic carbon and isotopic exchange brought about by volcanic carbon, etc., should be taken into account before valid conclusions are drawn. The paper uses examples taken from existing studies, mainly those being carried out in the Canary Islands (Spain). (author). 98 refs, 18 figs, 4 tabs

Geohydrology of White Rock Canyon of the Rio Grande from Otowi to Frijoles Canyon

International Nuclear Information System (INIS)

Purtymun, W.D.; Peters, R.J.; Owens, J.W.

1980-12-01

Twenty-seven springs discharge from the Totavi Lentil and Tesuque Formation in White Rock Canyon. Water generally acquires its chemical characteristics from rock units that comprise the spring aquifer. Twenty-two of the springs are separated into three groups of similar aquifer-related chemical quality. The five remaining springs make up a fourth group with a chemical quality that differs due to localized conditions in the aquifer. Localized conditions may be related to recharge or discharge in or near basalt intrusion or through faults. Streams from Pajarito, Ancho, and Frijoles Canyons discharge into the Rio Grande in White Rock Canyon. The base flow in the streams is from springs. Sanitary effluent in Mortandad Canyon from the treatment plant at White Rock also reaches the Rio Grande

Biochemical indicators for the bioavailability of organic carbon in ground water

Science.gov (United States)

Chapelle, F.H.; Bradley, P.M.; Goode, D.J.; Tiedeman, C.; Lacombe, P.J.; Kaiser, K.; Benner, R.

2009-01-01

The bioavailability of total organic carbon (TOC) was examined in ground water from two hydrologically distinct aquifers using biochemical indicators widely employed in chemical oceanography. Concentrations of total hydrolyzable neutral sugars (THNS), total hydrolyzable amino acids (THAA), and carbon-normalized percentages of TOC present as THNS and THAA (referred to as "yields") were assessed as indicators of bioavailability. A shallow coastal plain aquifer in Kings Bay, Georgia, was characterized by relatively high concentrations (425 to 1492 ??M; 5.1 to 17.9 mg/L) of TOC but relatively low THNS and THAA yields (???0.2%-1.0%). These low yields are consistent with the highly biodegraded nature of TOC mobilized from relatively ancient (Pleistocene) sediments overlying the aquifer. In contrast, a shallow fractured rock aquifer in West Trenton, New Jersey, exhibited lower TOC concentrations (47 to 325 ??M; 0.6 to 3.9 mg/L) but higher THNS and THAA yields (???1% to 4%). These higher yields were consistent with the younger, and thus more bioavailable, TOC being mobilized from modern soils overlying the aquifer. Consistent with these apparent differences in TOC bioavailability, no significant correlation between TOC and dissolved inorganic carbon (DIC), a product of organic carbon mineralization, was observed at Kings Bay, whereas a strong correlation was observed at West Trenton. In contrast to TOC, THNS and THAA concentrations were observed to correlate with DIC at the Kings Bay site. These observations suggest that biochemical indicators such as THNS and THAA may provide information concerning the bioavailability of organic carbon present in ground water that is not available from TOC measurements alone.

Landfill leachate effects on sorption of organic micropollutants onto aquifer materials

DEFF Research Database (Denmark)

Larsen, Thomas; Christensen, Thomas Højlund; Pfeffer, Fred M.

1992-01-01

The effect of dissolved organic carbon as present in landfill leachate, on the sorption of organic micropollutants in aquifer materials was studied by laboratory batch and column experiments involving 15 non-polar organic chemicals, 5 landfill leachates and 4 aquifer materials of low organic carbon......, the effect of landfill leachate on retardation of organic micropollutants in aquifer material seems limited....... content. The experiments showed that hydrophobic organic micropollutants do partition into dissolved organic carbon found in landfill leachate potentially increasing their mobility. However, landfill leachate interacted with aquifer materials apparently increases the sorbent affinity for the hydrophobic...

Acid neutralizing capacity and leachate results for igneous rocks, with associated carbon contents of derived soils, Animas River AML site, Silverton, Colorado

Science.gov (United States)

Yager, Douglas B.; Stanton, Mark R.; Choate, LaDonna M.; Burchell,

2009-01-01

Mine planning efforts have historically overlooked the possible acid neutralizing capacity (ANC) that local igneous rocks can provide to help neutralize acidmine drainage. As a result, limestone has been traditionally hauled to mine sites for use in neutralizing acid drainage. Local igneous rocks, when used as part of mine life-cycle planning and acid mitigation strategy, may reduce the need to transport limestone to mine sites because these rocks can contain acid neutralizing minerals. Igneous hydrothermal events often introduce moderately altered mineral assemblages peripheral to more intensely altered rocks that host metal-bearing veins and ore bodies. These less altered rocks can contain ANC minerals (calcite-chlorite-epidote) and are referred to as a propylitic assemblage. In addition, the carbon contents of soils in areas of new mining or those areas undergoing restoration have been historically unknown. Soil organic carbon is an important constituent to characterize as a soil recovery benchmark that can be referred to during mine cycle planning and restoration. This study addresses the mineralogy, ANC, and leachate chemistry of propylitic volcanic rocks that host polymetallic mineralization in the Animas River watershed near the historical Silverton, Colorado, mining area. Acid titration tests on volcanic rocks containing calcite (2 – 20 wt %) and chlorite (6 – 25 wt %), have ANC ranging from 4 – 146 kg/ton CaCO3 equivalence. Results from a 6-month duration, kinetic reaction vessel test containing layered pyritic mine waste and underlying ANC volcanic rock (saturated with deionized water) indicate that acid generating mine waste (pH 2.4) has not overwhelmed the ANC of propylitic volcanic rocks (pH 5.8). Sequential leachate laboratory experiments evaluated the concentration of metals liberated during leaching. Leachate concentrations of Cu-Zn-As-Pb for ANC volcanic rock are one-to-three orders of magnitude lower when compared to leached solution from

Contribution to the study of Arapey Salto-Aquifer System (Department of Salto - Uruguay)

International Nuclear Information System (INIS)

Massa, E.

1994-01-01

This paper provide hydrogeological data about the Salto Arapey aquifer system constituted by sedimentary deposits and fisurate effusive rocks, respectively Tertiary and Cretacic aged. The information belongs to an area located at latitude South 31º20' West. North of the Salto city (NW of Uruguay) 500 km away from Montevideo. A regional aquifer system can be defined where the biggest flows are originated in the basaltic fisurate d rocks of the Arapey formation. Environment features are also considered and data about the main polluting agents - both organic and inorganic ones- are provided, bearing in mind that they justify an urgent safety design to protect the aquifer system

Mineral Dissolution and Precipitation due to Carbon Dioxide-Water-Rock Interactions: The Significance of Accessory Minerals in Carbonate Reservoirs (Invited)

Science.gov (United States)

Kaszuba, J. P.; Marcon, V.; Chopping, C.

2013-12-01

Accessory minerals in carbonate reservoirs, and in the caprocks that seal these reservoirs, can provide insight into multiphase fluid (CO2 + H2O)-rock interactions and the behavior of CO2 that resides in these water-rock systems. Our program integrates field data, hydrothermal experiments, and geochemical modeling to evaluate CO2-water-rock reactions and processes in a variety of carbonate reservoirs in the Rocky Mountain region of the US. These studies provide insights into a wide range of geologic environments, including natural CO2 reservoirs, geologic carbon sequestration, engineered geothermal systems, enhanced oil and gas recovery, and unconventional hydrocarbon resources. One suite of experiments evaluates the Madison Limestone on the Moxa Arch, Southwest Wyoming, a sulfur-rich natural CO2 reservoir. Mineral textures and geochemical features developed in the experiments suggest that carbonate minerals which constitute the natural reservoir will initially dissolve in response to emplacement of CO2. Euhedral, bladed anhydrite concomitantly precipitates in response to injected CO2. Analogous anhydrite is observed in drill core, suggesting that secondary anhydrite in the natural reservoir may be related to emplacement of CO2 into the Madison Limestone. Carbonate minerals ultimately re-precipitate, and anhydrite dissolves, as the rock buffers the acidity and reasserts geochemical control. Another suite of experiments emulates injection of CO2 for enhanced oil recovery in the Desert Creek Limestone (Paradox Formation), Paradox Basin, Southeast Utah. Euhedral iron oxyhydroxides (hematite) precipitate at pH 4.5 to 5 and low Eh (approximately -0.1 V) as a consequence of water-rock reaction. Injection of CO2 decreases pH to approximately 3.5 and increases Eh by approximately 0.1 V, yielding secondary mineralization of euhedral pyrite instead of iron oxyhydroxides. Carbonate minerals also dissolve and ultimately re-precipitate, as determined by experiments in the

New isotopic evidence for the origin of groundwater from the Nubian Sandstone Aquifer in the Negev, Israel

Science.gov (United States)

Vengosh, A.; Hening, S.; Ganor, J.; Mayer, B.; Weyhenmeyer, C.E.; Bullen, T.D.; Paytan, A.

2007-01-01

significantly to the salt budget of the Nubian Sandstone aquifer. The unique chemical and isotopic composition of the Jurassic groundwater (??34SSO4 ??? +14???; ??18OSO4 ??? 14???; 87Sr/86Sr ???0.70764) is interpreted as reflecting dissolution of Late Triassic marine gypsum deposits. In the southern Arava Valley the authors postulate that SO4-rich groundwater with distinctively high Br/Cl (3 ?? 10-3) low 87Sr/86Sr (0.70734), and high ??34SSO4 values (+15???) is derived from mixing with underlying brines from the Paleozoic units. The radiocarbon measurements reveal low 14C activities (0.2-5.8 pmc) in both the northeastern Negev and southern Arava Valley. Taking into account dissolution of carbonate rocks and bacterial SO4 reduction in the unconfined area, estimated mean residence times of groundwater in the confined zone in the northeastern Negev are on the order of 21-38 ka, which suggests recharge predominantly during the last glacial period. The 14C signal in groundwater from the southern Arava Valley is equally low but due to evidence for mixing with external water sources the residence time estimates are questionable. ?? 2007 Elsevier Ltd. All rights reserved.

Contribution to the hydrogeological, geochemical and isotopic study of Ain El Beidha and Merguellil (Kairouan plain) aquifers: Implication for the dam-aquifer relationship

International Nuclear Information System (INIS)

Ben Ammar, Safouan

2007-01-01

karst before reaching the Kairouan plain aquifer (springs). Groundwater under flow is estimated at 9 M m3 year-1 and the karstic spring flow is evaluated at 10 M m3 year-1. The spring waters show an intermediate isotope composition between dam reservoir water and the upper catchment of Ain el Beidha basin. The contribution of dam water in mixed water (spring) varies between 21 to 66% depending on time. Values from 18O and 2H ratio are well correlated with the karstic spring flow and with the water level in the reservoir. The hydrogeological study helped to understand the hydrodynamic functioning of the Kairouan plain aquifer system and identified a decline of the water table levels (1.5 m year-1). This decrease is explained mainly by over exploitation (4.8 M m3 year-1). The hydrochemical investigation indicated that the rock-water interaction is the main process contributing to the groundwater salinization. All the samples collected in the Merguellil basin are of the main hydrochemical type: Cl-SO4-Na. Stable isotope values measured in the upstream part of plain, closer the dam, differ from other parts of the aquifer, therefore suggesting a significant input from evaporated dam waters mixed with Ain el Beidha groundwater (spring water coming from the karst). This contamination can be observed as far as 7 km downstream. However, isotopic imprint of the previous recharge process (infiltration of wadi floods) are still noticeable. The residence time of the groundwater was estimated by carbon-14 dating that shows variable values of transit velocity of the groundwater ranging from 3.36 to 0.44 m year-1 depending on the groundwater flow and on the lithological variability of the aquifer. (Author).

Crack propagation of brittle rock under high geostress

Science.gov (United States)

Liu, Ning; Chu, Weijiang; Chen, Pingzhi

2018-03-01

Based on fracture mechanics and numerical methods, the characteristics and failure criterions of wall rock cracks including initiation, propagation, and coalescence are analyzed systematically under different conditions. In order to consider the interaction among cracks, adopt the sliding model of multi-cracks to simulate the splitting failure of rock in axial compress. The reinforcement of bolts and shotcrete supporting to rock mass can control the cracks propagation well. Adopt both theory analysis and simulation method to study the mechanism of controlling the propagation. The best fixed angle of bolts is calculated. Then use ansys to simulate the crack arrest function of bolt to crack. Analyze the influence of different factors on stress intensity factor. The method offer more scientific and rational criterion to evaluate the splitting failure of underground engineering under high geostress.

Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

Energy Technology Data Exchange (ETDEWEB)

Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

2013-04-15

Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and

Coastal groundwater salinization: Focus on the vertical variability in a multi-layered aquifer through a multi-isotope fingerprinting (Roussillon Basin, France)

Energy Technology Data Exchange (ETDEWEB)

Petelet-Giraud, Emmanuelle, E-mail: e.petelet@brgm.fr [BRGM, Avenue C. Guillemin, BP 36009, 45060 Orléans Cedex 02 (France); Négrel, Philippe [BRGM, Avenue C. Guillemin, BP 36009, 45060 Orléans Cedex 02 (France); Aunay, Bertrand [BRGM, Réunion Agency, 5, rue Sainte-Anne, CS 51016, 97404 Saint Denis Cedex (France); Ladouche, Bernard; Bailly-Comte, Vincent [BRGM Montpellier Agency, 1039, rue de Pinville, 34000 Montpellier (France); Guerrot, Catherine; Flehoc, Christine [BRGM, Avenue C. Guillemin, BP 36009, 45060 Orléans Cedex 02 (France); Pezard, Philippe; Lofi, Johanna [Géosciences Montpellier, UMR 5243, Université de Montpellier, cc069, Place Eugène Bataillon, 34095 Montpellier Cedex 05 (France); Dörfliger, Nathalie [BRGM, Avenue C. Guillemin, BP 36009, 45060 Orléans Cedex 02 (France)

2016-10-01

The Roussillon sedimentary Basin (South France) is a complex multi-layered aquifer, close to the Mediterranean Sea facing seasonally increases of water abstraction and salinization issues. We report geochemical and isotopic vertical variability in this aquifer using groundwater sampled with a Westbay System® at two coastal monitoring sites: Barcarès and Canet. The Westbay sampling allows pointing out and explaining the variation of water quality along vertical profiles, both in productive layers and in the less permeable ones where most of the chemical processes are susceptible to take place. The aquifer layers are not equally impacted by salinization, with electrical conductivity ranging from 460 to 43,000 μS·cm{sup −1}. The δ{sup 2}H–δ{sup 18}O signatures show mixing between seawater and freshwater components with long water residence time as evidenced by the lack of contribution from modern water using {sup 3}H, {sup 14}C and CFCs/SF6. S(SO{sub 4}) isotopes also evidence seawater contribution but some signatures can be related to oxidation of pyrite and/or organically bounded S. In the upper layers {sup 87}Sr/{sup 86}Sr ratios are close to that of seawater and then increase with depth, reflecting water–rock interaction with argillaceous formations while punctual low values reflect interaction with carbonate. Boron isotopes highlight secondary processes such as adsorption/desorption onto clays in addition to mixings. At the Barcarès site (120 m deep), the high salinity in some layers appear to be related neither to present day seawater intrusion, nor to Salses-Leucate lagoonwater intrusion. Groundwater chemical composition thus highlights binary mixing between fresh groundwater and inherited salty water together with cation exchange processes, water–rock interactions and, locally, sedimentary organic matter mineralisation probably enhanced by pyrite oxidation. Finally, combining the results of this study and those of Caballero and Ladouche (2015

Failure Mechanisms of Brittle Rocks under Uniaxial Compression

Science.gov (United States)

Liu, Taoying; Cao, Ping

2017-09-01

The behaviour of a rock mass is determined not only by the properties of the rock matrix, but mostly by the presence and properties of discontinuities or fractures within the mass. The compression test on rock-like specimens with two prefabricated transfixion fissures, made by pulling out the embedded metal inserts in the pre-cured period was carried out on the servo control uniaxial loading tester. The influence of the geometry of pre-existing cracks on the cracking processes was analysed with reference to the experimental observation of crack initiation and propagation from pre-existing flaws. Based on the rock fracture mechanics and the stress-strain curves, the evolution failure mechanism of the fissure body was also analyzed on the basis of exploring the law of the compression-shear crack initiation, wing crack growth and rock bridge connection. Meanwhile, damage fracture mechanical models of a compression-shear rock mass are established when the rock bridge axial transfixion failure, tension-shear combined failure, or wing crack shear connection failure occurs on the specimen under axial compression. This research was of significance in studying the failure mechanism of fractured rock mass.

Characterizing flow pathways in a sandstone aquifer: Tectonic vs sedimentary heterogeneities

Science.gov (United States)

Medici, G.; West, L. J.; Mountney, N. P.

2016-11-01

Sandstone aquifers are commonly assumed to represent porous media characterized by a permeable matrix. However, such aquifers may be heavy fractured when rock properties and timing of deformation favour brittle failure and crack opening. In many aquifer types, fractures associated with faults, bedding planes and stratabound joints represent preferential pathways for fluids and contaminants. In this paper, well test and outcrop-scale studies reveal how strongly lithified siliciclastic rocks may be entirely dominated by fracture flow at shallow depths (≤ 180 m), similar to limestone and crystalline aquifers. However, sedimentary heterogeneities can primarily control fluid flow where fracture apertures are reduced by overburden pressures or mineral infills at greater depths. The Triassic St Bees Sandstone Formation (UK) of the East Irish Sea Basin represents an optimum example for study of the influence of both sedimentary and tectonic aquifer heterogeneities in a strongly lithified sandstone aquifer-type. This fluvial sedimentary succession accumulated in rapidly subsiding basins, which typically favours preservation of complete depositional cycles including fine grained layers (mudstone and silty sandstone) interbedded in sandstone fluvial channels. Additionally, vertical joints in the St Bees Sandstone Formation form a pervasive stratabound system whereby joints terminate at bedding discontinuities. Additionally, normal faults are present through the succession showing particular development of open-fractures. Here, the shallow aquifer (depth ≤ 180 m) was characterized using hydro-geophysics. Fluid temperature, conductivity and flow-velocity logs record inflows and outflows from normal faults, as well as from pervasive bed-parallel fractures. Quantitative flow logging analyses in boreholes that cut fault planes indicate that zones of fault-related open fractures characterize 50% of water flow. The remaining flow component is dominated by bed-parallel fractures

Regional-scale analysis of karst underground flow deduced from tracing experiments: examples from carbonate aquifers in Malaga province, southern Spain

Science.gov (United States)

Barberá, J. A.; Mudarra, M.; Andreo, B.; De la Torre, B.

2018-02-01

Tracer concentration data from field experiments conducted in several carbonate aquifers (Malaga province, southern Spain) were analyzed following a dual approach based on the graphical evaluation method (GEM) and solute transport modeling to decipher flow mechanisms in karst systems at regional scale. The results show that conduit system geometry and flow conditions are the principal factors influencing tracer migration through the examined karst flow routes. Solute transport is mainly controlled by longitudinal advection and dispersion throughout the conduit length, but also by flow partitioning between mobile and immobile fluid phases, while the matrix diffusion process appears to be less relevant. The simulation of tracer breakthrough curves (BTCs) suggests that diffuse and concentrated flow through the unsaturated zone can have equivalent transport properties under extreme recharge, with high flow velocities and efficient mixing due to the high hydraulic gradients generated. Tracer mobilization within the saturated zone under low flow conditions mainly depends on the hydrodynamics (rather than on the karst conduit development), which promote a lower longitudinal advection and retardation in the tracer migration, resulting in a marked tailing effect of BTCs. The analytical advection-dispersion equation better approximates the effective flow velocity and longitudinal dispersion estimations provided by the GEM, while the non-equilibrium transport model achieves a better adjustment of most asymmetric and long-tailed BTCs. The assessment of karst underground flow properties from tracing tests at regional scale can aid design of groundwater management and protection strategies, particularly in large hydrogeological systems (i.e. transboundary carbonate aquifers) and/or in poorly investigated ones.

Study of the leakage between two aquifers in Hermosillo, Mexico, using environmental isotopes

International Nuclear Information System (INIS)

Payne, B.R.; Quijano, L.; Latorre, D.C.

1980-01-01

The Coast of Hermosillo is located in the Gulf of California, Mexico. It is a Quaternary alluvial plain of continental origin. Underlying these deposits is a layer of blue clay about 100m thick which imposes confinement to a deep aquifer in basaltic and pyroclastic rocks. Oxygen-18 and deuterium data support the occurrence of an upwardsleakage. The amount of the leakage was evaluated, on the basis of 14 C data, to a maximum of 20% of the water pumped by the irrigation wells in the upper aquifer. The stable isotope data also support the occurrence of sea-water intrusion by preferential channels in the south and in the area of Kino Bay. (author)

CUMULATE ROCKS ASSOCIATED WITH CARBONATE ASSIMILATION, HORTAVÆR COMPLEX, NORTH-CENTRAL NORWAY

Science.gov (United States)

Barnes, C. G.; Prestvik, T.; Li, Y.

2009-12-01

The Hortavær igneous complex intruded high-grade metamorphic rocks of the Caledonian Helgeland Nappe Complex at ca. 466 Ma. The complex is an unusual mafic-silicic layered intrusion (MASLI) because the principal felsic rock type is syenite and because the syenite formed in situ rather than by deep-seated partial melting of crustal rocks. Magma differentiation in the complex was by assimilation, primarily of calc-silicate rocks and melts with contributions from marble and semi-pelites, plus fractional crystallization. The effect of assimilation of calcite-rich rocks was to enhance stability of fassaitic clinopyroxene at the expense of olivine, which resulted in alkali-rich residual melts and lowering of silica activity. This combination of MASLI-style emplacement and carbonate assimilation produced three types of cumulate rocks: (1) Syenitic cumulates formed by liquid-crystal separation. As sheets of mafic magma were loaded on crystal-rich syenitic magma, residual liquid was expelled, penetrating the overlying mafic sheets in flame structures, and leaving a cumulate syenite. (2) Reaction cumulates. Carbonate assimilation, illustrated by a simple assimilation reaction: olivine + calcite + melt = clinopyroxene + CO2 resulted in cpx-rich cumulates such as clinopyroxenite, gabbro, and mela-monzodiorite, many of which contain igneous calcite. (3) Magmatic skarns. Calc-silicate host rocks underwent partial melting during assimilation, yielding a Ca-rich melt as the principal assimilated material and permitting extensive reaction with surrounding magma to form Kspar + cpx + garnet-rich ‘cumulate’ rocks. Cumulate types (2) and (3) do not reflect traditional views of cumulate rocks but instead result from a series of melt-present discontinuous (peritectic) reactions and partial melting of calc-silicate xenoliths. In the Hortavær complex, such cumulates are evident because of the distinctive peritectic cumulate assemblages. It is unclear whether assimilation of �

Combined interpretation of radar, hydraulic, and tracer data from a fractured-rock aquifer near Mirror Lake, New Hampshire, USA

Science.gov (United States)

Day-Lewis, F. D.; Lane, J.W.; Gorelick, S.M.

2006-01-01

An integrated interpretation of field experimental cross-hole radar, tracer, and hydraulic data demonstrates the value of combining time-lapse geophysical monitoring with conventional hydrologic measurements for improved characterization of a fractured-rock aquifer. Time-lapse difference-attenuation radar tomography was conducted during saline tracer experiments at the US Geological Survey Fractured Rock Hydrology Research Site near Mirror Lake, Grafton County, New Hampshire, USA. The presence of electrically conductive saline tracer effectively illuminates permeable fractures or pathways for geophysical imaging. The geophysical results guide the construction of three-dimensional numerical models of ground-water flow and solute transport. In an effort to explore alternative explanations for the tracer and tomographic data, a suite of conceptual models involving heterogeneous hydraulic conductivity fields and rate-limited mass transfer are considered. Calibration data include tracer concentrations, the arrival time of peak concentration at the outlet, and steady-state hydraulic head. Results from the coupled inversion procedure suggest that much of the tracer mass migrated outside the three tomographic image planes, and that solute is likely transported by two pathways through the system. This work provides basic and site-specific insights into the control of permeability heterogeneity on ground-water flow and solute transport in fractured rock. ?? Springer-Verlag 2004.

Study on investigation and evaluation methods of deep seated sedimentary rocks. Chemical weathering, pore water squeezing and relationships of physical properties of sedimentary rocks

International Nuclear Information System (INIS)

Oyama, Takahiro; Suzuki, Koichi

2006-01-01

Chemical weathering, porewater squeezing and physical properties for the sedimentary rocks were examined. Chemical weathering potential of rocks was described by the sulfur as a acceleration factor of weathering and carbonate contents as a neutralization factor of it. The carbonate contents in the rocks were measured accurately by the gas pressure measurement method. Pore water squeezing method was applied for the semi-hard sedimentary rocks (Opalinusclay). The chemical change of extracted pore water under high pressure conditions was estimated. Physical property of sedimentary rocks have relationship among the porosity and permeability and resistivity coefficient in the same rock types. It is possible to estimate the water permeability from the geophysical tests. (author)

Quantification of the reactions in heat storage systems in the Malm aquifer

Science.gov (United States)

Ueckert, Martina; Baumann, Thomas

2017-04-01

Combined heat and power plants (CHP) are efficient and environmentally friendly because excess heat produced during power generation is used for heating purposes. While the power demand remains rather constant throughout the year, the heat demand shows seasonal variations. In a worst-case scenario, the heat production in winter is not sufficient, and the power production in summer has to be ramped down because the excess heat cannot be released to the environment. Therefore, storage of excess heat of CHP is highly beneficial from an economic and an ecological point of view. Aquifer thermal energy storage (ATES) is considered as a promising technology for energy storage. In a typical setting, water from an aquifer is produced, heated up by excess heat from the CHP and injected through a second borehole back into the aquifer. The carbonate rocks of the upper Jurrasic in the Molasse Basin seem to be promising sites for aquifer heat storage because of their high transmissivity combined with a typical geological setting with tight caprock. However, reactions in the aquifer cannot be neglected and may become the limiting process of the whole operation. While there have been several studies performed in clastic aquifers and for temperatures below 100°C, the knowledge about high injection temperatures and storage into a carbonatic aquifer matrix is still limited. Within a research project funded by the Bavarian State Ministry for Economic Affairs and the BMW Group, the storage and recuperation of excess heat energy into the Bavarian Malm aquifer with flow rates of 15 L/s and temperatures of up to 110°C was investigated. The addition of {CO_2} was used to prevent precipitations. Data from the field site was backed up by autoclave experiments and used to verify a conceptional hydrogeochemical model with PhreeqC for the heat storage operation. The model allows to parametrize the operation and to predict possible reactions in the aquifer.

Natural isotopes and water stratification in the Judea Group aquifer (Judea Desert)

International Nuclear Information System (INIS)

Kornfeld, Loel; Vogel, John C.; Rosenthal, Asher

1992-01-01

Using environmental isotopes, the subaquifer of the Judea Group carbonate aquifer were studied from the recharge area in the Judea Hills, eastwords down the flanks of the escarpment to the Jordan River Valley. The oxygen isotope data confirms that the dominant source of recharge for the phreatic and confined subaquifers in the Judean Hills. Water-rock interactions develop the δ 13 C values rapidly in the recharge region. once established where is no significant subsequent modification due to interaction with the enveloping carbonate as the water travels down dip. The relative high tritium values encountered in the springs and several of the well waters would indicate modern waters. However, the low radiocarbon levels are often encountered in the same water sources implies that a mixture of young water with significanly older water has been encountered. There are indications, at least in the upper subaquifer, of agewise stratification of the waters. Water is transmitted very rapidly through the upper portions of the aquifer while the water in the lower portions may be moving slowly because of the low permeability. The timing of the recharge of the deeper portion of the subaquifer and much of the lower subaquifer occurred in the mid-to early Holocene. (authors)

Trace metal mobilization in an experimental carbon sequestration scenario

Energy Technology Data Exchange (ETDEWEB)

Marcon, Virginia [University of Wyoming, Geology and Geophysics, Laramie, WY. 82070 (United States); Kaszuba, John [University of Wyoming, Geology and Geophysics, Laramie, WY. 82070 (United States); Univeristy of Wyoming, School of Energy Resources, Larmaie, WY. 82070 (United States)

2013-07-01

Mobilizing trace metals with injection of supercritical CO{sub 2} into deep saline aquifers is a concern for geologic carbon sequestration. Hydrothermal experiments investigate the release of harmful metals from two zones of a sequestration injection reservoir: at the cap-rock-reservoir boundary and deeper within the reservoir, away from the cap-rock. In both systems, Cd, Cr, Cu, Pb, and Zn behave in a similar manner, increasing in concentration with injection, but subsequently decreasing in concentration over time. SEM images and geochemical models indicate initial dissolution of minerals and precipitation of Ca-Mg-Fe carbonates, metal sulfides (i.e. Fe, As, Ag, and Co sulfides), and anhydrite in both systems. The results suggest that Ba, Cu, and Zn will not be contaminants of concern, but Pb, Fe, and As may require careful attention. (authors)

Characterizing fate and transport properties in karst aquifers under different hydrologic conditions

Science.gov (United States)

Rodriguez, E.; Padilla, I. Y.

2017-12-01

Karst landscapes contain very productive aquifers. The hydraulic and hydrogeological characteristics of karst aquifers make these systems capable of storing and transporting large amount of water, but also highly vulnerable to contamination. Their extremely heterogeneous nature prevents accurate prediction in contaminant fate and transport. Even more challenging is to understand the impact of hydrologic conditions changes on fate and transport processes. This studies aims at characterizing fate and transport processes in the karst groundwater system of northern Puerto Rico under different hydrologic conditions. The study involves injecting rhodamine and uranine dyes into a sinkhole, and monitoring concentrations at a spring. Results show incomplete recovery of tracers, but breaking curves can be used to estimate advective, dispersive and mass transfer characteristic of the karst system. Preliminary results suggest significant differences in fate and transport characteristics under different hydrologic conditions.

Fate of Arsenic during Red River Water Infiltration into Aquifers beneath Hanoi, Vietnam.

Science.gov (United States)

Postma, Dieke; Mai, Nguyen Thi Hoa; Lan, Vi Mai; Trang, Pham Thi Kim; Sø, Helle Ugilt; Nhan, Pham Quy; Larsen, Flemming; Viet, Pham Hung; Jakobsen, Rasmus

2017-01-17

Recharge of Red River water into arsenic-contaminated aquifers below Hanoi was investigated. The groundwater age at 40 m depth in the aquifer underlying the river was 1.3 ± 0.8 years, determined by tritium-helium dating. This corresponds to a vertical flow rate into the aquifer of 19 m/year. Electrical conductivity and partial pressure of CO 2 (P CO 2 ) indicate that water recharged from the river is present in both the sandy Holocene and gravelly Pleistocene aquifers and is also abstracted by the pumping station. Infiltrating river water becomes anoxic in the uppermost aquifer due to the oxidation of dissolved organic carbon. Further downward, sedimentary carbon oxidation causes the reduction of As-containing Fe-oxides. Because the release of arsenic by reduction of Fe-oxides is controlled by the reaction rate, arsenic entering the solution becomes highly diluted in the high water flux and contributes little to the groundwater arsenic concentration. Instead, the As concentration in the groundwater of up to 1 μM is due to equilibrium-controlled desorption of arsenic, adsorbed to the sediment before river water started to infiltrate due to municipal pumping. Calculations indicate that it will take several decades of river water infiltration to leach arsenic from the Holocene aquifer to below the World Health Organization limit of 10 μg/L.

Fate of Arsenic during Red River Water Infiltration into Aquifers beneath Hanoi, Vietnam

Science.gov (United States)

2016-01-01

Recharge of Red River water into arsenic-contaminated aquifers below Hanoi was investigated. The groundwater age at 40 m depth in the aquifer underlying the river was 1.3 ± 0.8 years, determined by tritium–helium dating. This corresponds to a vertical flow rate into the aquifer of 19 m/year. Electrical conductivity and partial pressure of CO2 (PCO2) indicate that water recharged from the river is present in both the sandy Holocene and gravelly Pleistocene aquifers and is also abstracted by the pumping station. Infiltrating river water becomes anoxic in the uppermost aquifer due to the oxidation of dissolved organic carbon. Further downward, sedimentary carbon oxidation causes the reduction of As-containing Fe-oxides. Because the release of arsenic by reduction of Fe-oxides is controlled by the reaction rate, arsenic entering the solution becomes highly diluted in the high water flux and contributes little to the groundwater arsenic concentration. Instead, the As concentration in the groundwater of up to 1 μM is due to equilibrium-controlled desorption of arsenic, adsorbed to the sediment before river water started to infiltrate due to municipal pumping. Calculations indicate that it will take several decades of river water infiltration to leach arsenic from the Holocene aquifer to below the World Health Organization limit of 10 μg/L. PMID:27958705

Potential and costs of carbon dioxide removal by enhanced weathering of rocks

Science.gov (United States)

Strefler, Jessica; Amann, Thorben; Bauer, Nico; Kriegler, Elmar; Hartmann, Jens

2018-03-01

The chemical weathering of rocks currently absorbs about 1.1 Gt CO2 a-1 being mainly stored as bicarbonate in the ocean. An enhancement of this slow natural process could remove substantial amounts of CO2 from the atmosphere, aiming to offset some unavoidable anthropogenic emissions in order to comply with the Paris Agreement, while at the same time it may decrease ocean acidification. We provide the first comprehensive assessment of economic costs, energy requirements, technical parameterization, and global and regional carbon removal potential. The crucial parameters defining this potential are the grain size and weathering rates. The main uncertainties about the potential relate to weathering rates and rock mass that can be integrated into the soil. The discussed results do not specifically address the enhancement of weathering through microbial processes, feedback of geogenic nutrient release, and bioturbation. We do not only assess dunite rock, predominantly bearing olivine (in the form of forsterite) as the mineral that has been previously proposed to be best suited for carbon removal, but focus also on basaltic rock to minimize potential negative side effects. Our results show that enhanced weathering is an option for carbon dioxide removal that could be competitive already at 60 US  t-1 CO2 removed for dunite, but only at 200 US  t-1 CO2 removed for basalt. The potential carbon removal on cropland areas could be as large as 95 Gt CO2 a-1 for dunite and 4.9 Gt CO2 a-1 for basalt. The best suited locations are warm and humid areas, particularly in India, Brazil, South-East Asia and China, where almost 75% of the global potential can be realized. This work presents a techno-economic assessment framework, which also allows for the incorporation of further processes.

Aquifer storage and recovery: recent hydrogeological advances and system performance.

Science.gov (United States)

Maliva, Robert G; Guo, Weixing; Missimer, Thomas M

2006-12-01

Aquifer storage and recovery (ASR) is part of the solution to the global problem of managing water resources to meet existing and future freshwater demands. However, the metaphoric "ASR bubble" has been burst with the realization that ASR systems are more physically and chemically complex than the general conceptualization. Aquifer heterogeneity and fluid-rock interactions can greatly affect ASR system performance. The results of modeling studies and field experiences indicate that more sophisticated data collection and solute-transport modeling are required to predict how stored water will migrate in heterogeneous aquifers and how fluid-rock interactions will affect the quality of stored water. It has been well-demonstrated, by historic experience, that ASR systems can provide very large volumes of storage at a lesser cost than other options. The challenges moving forward are to improve the success rate of ASR systems, optimize system performance, and set expectations appropriately.

Transformation of carbon tetrachloride by Pseudomonas sp. strain KC under denitrification conditions

International Nuclear Information System (INIS)

Criddle, C.S.; DeWitt, J.T.; Grbic-Galic, D.; McCarty, P.L.

1990-01-01

A denitrifying Pseudomonas sp. (strain KC) capable of transforming carbon tetrachloride (CT) was isolated from groundwater aquifer solids. Major products of the transformation of 14 C-labeled CT by Pseudomonas strain KC under denitrification conditions were 14 CO 2 and an unidentified water-soluble fraction. Little or no chloroform was produced. Addition of dissolved trace metals, notably, ferrous iron and cobalt, to the growth medium appeared to enhance growth of Pseudomonas strain KC while inhibiting transformation of CT. It is hypothesized that transformation of CT by this organism is associated with the mechanism of trace-metal scavenging

Hydrogeological Properties of the Rocks in Adansi Mining Area ...

African Journals Online (AJOL)

The hydrogeological properties of an aquifer coupled with climatic conditions and geomorphology determines how much groundwater exists in that location. A hydrogeological study of the rocks in the Adansi area was carried out to obtain the aquifer hydraulic properties. Drilling and pumping test analysis information were ...

Normal dynamic deformation characteristics of non-consecutive jointed rock masses under impact loads

Science.gov (United States)

Zeng, Sheng; Jiang, Bowei; Sun, Bing

2017-08-01

In order to study deformation characteristics of non-consecutive single jointed rock masses under impact loads, we used the cement mortar materials to make simulative jointed rock mass samples, and tested the samples under impact loads by the drop hammer. Through analyzing the time-history signal of the force and the displacement, first we find that the dynamic compression displacement of the jointed rock mass is significantly larger than that of the intact jointless rock mass, the compression displacement is positively correlated with the joint length and the impact height. Secondly, the vertical compressive displacement of the jointed rock mass is mainly due to the closure of opening joints under small impact loads. Finally, the peak intensity of the intact rock mass is larger than that of the non-consecutive jointed rock mass and negatively correlated with the joint length under the same impact energy.

Potential impacts of leakage from deep CO2 geosequestration on overlying freshwater aquifers.

Science.gov (United States)

Little, Mark G; Jackson, Robert B

2010-12-01

Carbon Capture and Storage may use deep saline aquifers for CO(2) sequestration, but small CO(2) leakage could pose a risk to overlying fresh groundwater. We performed laboratory incubations of CO(2) infiltration under oxidizing conditions for >300 days on samples from four freshwater aquifers to 1) understand how CO(2) leakage affects freshwater quality; 2) develop selection criteria for deep sequestration sites based on inorganic metal contamination caused by CO(2) leaks to shallow aquifers; and 3) identify geochemical signatures for early detection criteria. After exposure to CO(2), water pH declines of 1-2 units were apparent in all aquifer samples. CO(2) caused concentrations of the alkali and alkaline earths and manganese, cobalt, nickel, and iron to increase by more than 2 orders of magnitude. Potentially dangerous uranium and barium increased throughout the entire experiment in some samples. Solid-phase metal mobility, carbonate buffering capacity, and redox state in the shallow overlying aquifers influence the impact of CO(2) leakage and should be considered when selecting deep geosequestration sites. Manganese, iron, calcium, and pH could be used as geochemical markers of a CO(2) leak, as their concentrations increase within 2 weeks of exposure to CO(2).

Exploring deep potential aquifer in water scarce crystalline rocks

Indian Academy of Sciences (India)

out to explore deep groundwater potential zone in a water scarce granitic area. As existing field condi- ... Decision support tool developed in granitic ter- .... cially in terms of fracture system, the aquifer char- acteristics ... Methodologies used.

Estimating hydraulic parameters of the Açu-Brazil aquifer using the computer analysis of micrographs

Science.gov (United States)

de Lucena, Leandson R. F.; da Silva, Luis R. D.; Vieira, Marcela M.; Carvalho, Bruno M.; Xavier Júnior, Milton M.

2016-04-01

The conventional way of obtaining hydraulic parameters of aquifers is through the interpretation of aquifer tests that requires a fairly complex logistics in terms of equipment and personnel. On the other way, the processing and analysis of digital images of two-dimensional rock sample micrographs presents itself as a promising (simpler and cheaper) alternative procedure for obtaining estimates for hydraulics parameters. This methodology involves the sampling of rocks, followed by the making and imaging of thin rock samples, image segmentation, three-dimensional reconstruction and flow simulation. This methodology was applied to the outcropping portion of the Açu aquifer in the northeast of Brazil, and the computational analyses of the thin rock sections of the acquired samples produced effective porosities between 11.2% and 18.5%, and permeabilities between 52.4 mD and 1140.7 mD. Considering that the aquifer is unconfined, these effective porosity values can be used effectively as storage coefficients. The hydraulic conductivities produced by adopting different water dynamic viscosities at the temperature of 28 °C in the conversion of the permeabilities result in values in the range of [ 6.03 ×10-7, 1.43 ×10-5 ] m/s, compatible with the local hydrogeology.

Hydraulic gradients in rock aquifers

International Nuclear Information System (INIS)

Dahlblom, P.

1992-05-01

This report deals with fractured rock as a host for deposits of hazardous waste. In this context the rock, with its fractures containing moving groundwater, is called the geological barrier. The desired properties of the geological barrier are low permeability to water, low hydraulic gradients and ability to retain matter dissolved in the water. The hydraulic gradient together with the permeability and the porosity determines the migration velocity. Mathematical modelling of the migration involves calculation of the water flow and the hydrodynamic dispersion of the contaminant. The porous medium approach can be used to calculate mean flow velocities and hydrodynamic dispersion of a large number of fractures are connected, which means that a large volume have to be considered. It is assumed that the porous medium approach can be applied, and a number of idealized examples are shown. It is assumed that the groundwater table is replenished by percolation at a constant rate. One-dimensional analytical calculations show that zero hydraulic gradients may exist at relatively large distance from the coast. Two-dimensional numerical calculations show that it may be possible to find areas with low hydraulic gradients and flow velocities within blocks surrounded by areas with high hydraulic conductivity. (au)

Results of a hydrogeological and hydrogeochemical study of a semi-arid karst aquifer in Tezbent plateau, Tebessa region, northeast of Algeria

Science.gov (United States)

Belfar, Dalila; Fehdi, Chemseddine; Baali, Fethi; Salameh, Elias

2017-06-01

The Hammamet Plain, situated in the northwest of the Tezbent mountain range, northeast of Algeria, drains carbonate aquifers through some important karst springs. The physical and chemical characteristics of spring and well water samples were studied for 2 years to assess the origin of groundwater and determine the factors driving the geochemical composition. The ionic speciation and mineral dissolution/precipitation was calculated. Water wells, characterizing groundwater circulation at shallow depths, are moderate to high mineralized waters of Na-HCO3 type. In contrast to the shallow environment, the CO2-rich, deeper waters are of the Ca-HCO3-SO4 type and undergo significant changes in the baseline chemistry along flow lines with increasing residence time. The main factors controlling the groundwater composition and its seasonal variations are the geology, because of the presence of carbonate formations, the elevation and the rate of karst development. In both groups, the carbonate chemistry is diagnostic of the effect of karst development. The supersaturation with respect to calcite indicates CO2 degassing, occurring either inside the aquifer in open conduits, or at the outlet in reservoirs. The undersaturation with respect to calcite shows the existence of fast flow and short residence time conditions inside the aquifer. Interaction between groundwater and surrounding host rocks is believed to be the main process responsible for the observed chemical characteristics of groundwater in the study area.

Geochemical effects of CO2 sequestration in sandstones under simulated in situ conditions of deep saline aquifers

International Nuclear Information System (INIS)

Wigand, M.; Carey, J.W.; Schuett, H.; Spangenberg, E.; Erzinger, J.

2008-01-01

The geochemical effects of brine and supercritical CO 2 (SCCO 2 ) on reservoir rocks from deep (1500-2000 m) saline aquifers were examined via experimental simulation at in situ conditions. Dry sandstone samples were mounted in a triaxial cell and autoclave system, evacuated, and saturated with 1 M NaCl solution. The brine-rock system was allowed to react at 30 MPa confining pressure, 15 MPa pore fluid pressure, and 60 deg. C while SCCO 2 was injected at a pressure gradient of 1-2 MPa. The experiment was conducted for a period of 1496 h, during which fluids were periodically sampled and analyzed. The pH measured in partially degassed fluid samples at 25 deg. C decreased from a starting value of 7.0-4.3 (9 days) and finally 5.1 after saturation with SCCO 2 . Fluid analyses indicate that most of the major (e.g. Ca, Mg, Fe, Mn) and trace elements (e.g. Sr, Ba, Pb) of the sandstone increase in concentration during the reaction with brine and SCCO 2 . These results are supported by scanning electron microscopy which indicates dissolution of dolomite cement, K-feldspar, and albite. In addition to dissolution reactions the formation of montmorillonite was observed. By adjusting surface area and reaction rates of dissolution and precipitation, geochemical modeling of the experiments could reproduce long-term trends in solution chemistry and indicated limited rates of dissolution as the system remained strongly undersaturated with most minerals, including carbonates. The geochemical models could not account for decreases in concentration of some elements, changes in solution composition resulting from changes in imposed pressure gradient, and the observed Ca/Mg and Si/Al ratios in solution

Micro-Ct Imaging of Multi-Phase Flow in Carbonates and Sandstones

Science.gov (United States)

Andrew, M. G.; Bijeljic, B.; Blunt, M. J.

2013-12-01

One of the most important mechanisms that limits the escape of CO2 when injected into the subsurface for the purposes of carbon storage is capillary trapping, where CO2 is stranded as pore-scale droplets (ganglia). Prospective storage sites are aquifers or reservoirs that tend to be at conditions where CO2 will reside as a super-critical phase. In order to fully describe physical mechanisms characterising multi-phase flow during and post CO2 injection, experiments need to be conducted at these elevated aquifer/reservoir conditions - this poses a considerable experimental challenge. A novel experimental apparatus has been developed which uses μCT scanning for the non-invasive imaging of the distribution of CO2 in the pore space of rock with resolutions of 7μm at temperatures and pressures representative of the conditions present in prospective saline aquifer CO2 storage sites. The fluids are kept in chemical equilibrium with one-another and with the rock into which they are injected. This is done to prevent the dissolution of the CO2 in the brine to form carbonic acid, which can then react with the rock, particularly carbonates. By eliminating reaction we study the fundamental mechanisms of capillary trapping for an unchanging pore structure. In this study we present a suite of results from three carbonate and two sandstone rock types, showing that, for both cases the CO2 acts as the non-wetting phase and significant quantities of CO2 is trapped. The carbonate examined represent a wide variety of pore topologies with one rock with a very well connected, high porosity pore space (Mt Gambier), one with a lower porosity, poorly connected pore space (Estaillades) and one with a cemented bead pack type pore space (Ketton). Both sandstones (Doddington and Bentheimer) were high permeability granular quartzites. CO2 was injected into each rock, followed by brine injection. After brine injection the entire length of the rock core was scanned, processed and segmented into

Two-phase flow visualization under reservoir conditions for highly heterogeneous conglomerate rock: A core-scale study for geologic carbon storage.

Science.gov (United States)

Kim, Kue-Young; Oh, Junho; Han, Weon Shik; Park, Kwon Gyu; Shinn, Young Jae; Park, Eungyu

2018-03-20

Geologic storage of carbon dioxide (CO 2 ) is considered a viable strategy for significantly reducing anthropogenic CO 2 emissions into the atmosphere; however, understanding the flow mechanisms in various geological formations is essential for safe storage using this technique. This study presents, for the first time, a two-phase (CO 2 and brine) flow visualization under reservoir conditions (10 MPa, 50 °C) for a highly heterogeneous conglomerate core obtained from a real CO 2 storage site. Rock heterogeneity and the porosity variation characteristics were evaluated using X-ray computed tomography (CT). Multiphase flow tests with an in-situ imaging technology revealed three distinct CO 2 saturation distributions (from homogeneous to non-uniform) dependent on compositional complexity. Dense discontinuity networks within clasts provided well-connected pathways for CO 2 flow, potentially helping to reduce overpressure. Two flow tests, one under capillary-dominated conditions and the other in a transition regime between the capillary and viscous limits, indicated that greater injection rates (potential causes of reservoir overpressure) could be significantly reduced without substantially altering the total stored CO 2 mass. Finally, the capillary storage capacity of the reservoir was calculated. Capacity ranged between 0.5 and 4.5%, depending on the initial CO 2 saturation.

Hydrocarbon accumulation in deep fluid modified carbonate rock in the Tarim Basin

Institute of Scientific and Technical Information of China (English)

无

2007-01-01

The activities of deep fluid are regionalized in the Tarim Basin. By analyzing the REE in core samples and crude oil, carbon isotope of carbon dioxide and inclusion temperature measurement in the west of the Tazhong Uplift in the western Tarim Basin, all the evidence confirms the existence of deep fluid. The deep fluid below the basin floor moved up into the basin through discordogenic fauit and volcanicity to cause corrosion and metaaomatosis of carbonate rock by exchange of matter and energy. The pore structure and permeability of the carbonate reservoirs were improved, making the carbonate reservoirs an excellent type of deeply buried modification. The fluorite ore belts discovered along the large fault and the volcanic area in the west of the Tazhong Uplift are the outcome of deep fluid action. Such carbonate reservoirs are the main type of reservoirs in the Tazhong 45 oilfield. The carbonate reservoirs in well YM 7 are improved obviously by thermal fluid dolomitization. The origin and territory of deep fluid are associated with the discordogenic fault and volcanicity in the basin. The discordogenic fault and volcanic area may be the pointer of looking for the deep fluid modified reservoirs. The primary characteristics of hydrocarbon accumulation in deep fluid reconstructed carbonate rock are summarized as accumulation near the large fault and volcano passage, late-period hydrocarbon accumulation after volcanic activity, and subtle trap reservoirs controlled by lithology.

Investigating Interactions between the Silica and Carbon Cycles during Precipitation and Early Diagenesis of Authigenic Clay/Carbonate-Mineral Associations in the Carbonate Rock Record

Science.gov (United States)

McKenzie, J. A.; Francisca Martinez Ruiz, F.; Sanchez-Roman, M.; Anjos, S.; Bontognali, T. R. R.; Nascimento, G. S.; Vasconcelos, C.

2017-12-01

The study of authigenic clay/carbonate-mineral associations within carbonate sequences has important implications for the interpretation of scientific problems related with rock reservoir properties, such as alteration of potential porosity and permeability. More specifically, when clay minerals are randomly distributed within the carbonate matrix, it becomes difficult to predict reservoir characteristics. In order to understand this mineral association in the geological record, we have undertaken a comparative study of specially designed laboratory experiments with modern environments, where clay minerals have been shown to precipitate together with a range of carbonate minerals, including calcite, Mg-calcite and dolomite. Two modern dolomite-forming environments, the Coorong lakes, South Australia and Brejo do Espinho Rio de Janeiro, Brazil, were selected for this investigation. For comparative evaluation, enrichment microbial culture experiments, using natural pore water from Brejo do Espinho as the growth medium to promote mineral precipitation, were performed under both aerobic and anaerobic conditions. To establish the environmental parameters and biological processes facilitating the dual mineral association, the experimental samples have been compared with the natural minerals using HRTEM measurements. The results demonstrate that the clay and carbonate minerals apparently do not co-precipitate, but the precipitation of the different minerals in the same sample has probably occurred under different environmental conditions with variable chemistries, e.g., hypersalinity versus normal salinity resulting from the changing ratio of evaporation versus precipitation. Thus, the investigated mineral association is not a product of diagenetic processes but of sequential in situ precipitation processes related to changes in the silica and carbon availability. Implications for ancient carbonate formations will be presented and discussed in the context of a specific

Use of ``rock-typing`` to characterize carbonate reservoir heterogeneity. Final report

Energy Technology Data Exchange (ETDEWEB)

Ikwuakor, K.C.

1994-03-01

The objective of the project was to apply techniques of ``rock-typing`` and quantitative formation evaluation to borehole measurements in order to identify reservoir and non-reservoir rock-types and their properties within the ``C`` zone of the Ordovician Red River carbonates in the northeast Montana and northwest North Dakota areas of the Williston Basin. Rock-typing discriminates rock units according to their pore-size distribution. Formation evaluation estimates porosities and pore fluid saturation. Rock-types were discriminated using crossplots involving three rock-typing criteria: (1) linear relationship between bulk density and porosity, (2) linear relationship between acoustic interval transit-time and porosity, and (3) linear relationship between acoustic interval transit-time and bulk density. Each rock-type was quantitatively characterized by the slopes and intercepts established for different crossplots involving the above variables, as well as porosities and fluid saturations associated with the rock-types. All the existing production was confirmed through quantitative formation evaluation. Highly porous dolomites and anhydritic dolomites contribute most of the production, and constitute the best reservoir rock-types. The results of this study can be applied in field development and in-fill drilling. Potential targets would be areas of porosity pinchouts and those areas where highly porous zones are downdip from non-porous and tight dolomites. Such areas are abundant. In order to model reservoirs for enhanced oil recovery (EOR) operations, a more localized (e.g. field scale) study, expanded to involve other rock-typing criteria, is necessary.

Rock Fracture Toughness Study Under Mixed Mode I/III Loading

Science.gov (United States)

Aliha, M. R. M.; Bahmani, A.

2017-07-01

Fracture growth in underground rock structures occurs under complex stress states, which typically include the in- and out-of-plane sliding deformation of jointed rock masses before catastrophic failure. However, the lack of a comprehensive theoretical and experimental fracture toughness study for rocks under contributions of out-of plane deformations (i.e. mode III) is one of the shortcomings of this field. Therefore, in this research the mixed mode I/III fracture toughness of a typical rock material is investigated experimentally by means of a novel cracked disc specimen subjected to bend loading. It was shown that the specimen can provide full combinations of modes I and III and consequently a complete set of mixed mode I/III fracture toughness data were determined for the tested marble rock. By moving from pure mode I towards pure mode III, fracture load was increased; however, the corresponding fracture toughness value became smaller. The obtained experimental fracture toughness results were finally predicted using theoretical and empirical fracture models.

Summary of northern Atlantic coastal plain hydrology and its relation to disposal of high-level radioactive waste in buried crystalline rock; a preliminary appraisal

Science.gov (United States)

Lloyd, O.B.; Larson, J.D.; Davis, R.W.

1985-01-01

Interpretation of available hydrologic data suggests that some areas beneath the Coastal Plain in the States of Delaware, Maryland, New Jersey, North Carolina, and Virginia might have some potential for the disposal of nuclear waste in crystalline rock that is buried beneath the Coastal Plain sediments. The areas of major interest occur where the top of the basement rock lies between 1,000 and 4,000 feet below sea level, the aquifer(s) immediately above the basement rock are saturated with saline water, confining material overlies the saline water bearing aquifer(s), and groundwater flow in the saline water aquifer(s) can be established. Preliminary data on (1) the distribution and thickness of the lowermost aquifers and confining beds, (2) the distribution of hydraulic conductivity in the lowermost aquifers, (3) estimated hydraulic heads and inferred direction of lateral groundwater flow for 1980, and (4) the distribution of saline water and brine, indicate eastern parts of the study area relatively best meet most of the criteria proposed for sediments that would overlie any potential buried crystalline-rock disposal site.

The relationship between carbonate facies, volcanic rocks and plant remains in a late Palaeozoic lacustrine system (San Ignacio Fm, Frontal Cordillera, San Juan province, Argentina)

Science.gov (United States)

Busquets, P.; Méndez-Bedia, I.; Gallastegui, G.; Colombo, F.; Cardó, R.; Limarino, O.; Heredia, N.; Césari, S. N.

2013-07-01

The San Ignacio Fm, a late Palaeozoic foreland basin succession that crops out in the Frontal Cordillera (Argentinean Andes), contains lacustrine microbial carbonates and volcanic rocks. Modification by extensive pedogenic processes contributed to the massive aspect of the calcareous beds. Most of the volcanic deposits in the San Ignacio Fm consist of pyroclastic rocks and resedimented volcaniclastic deposits. Less frequent lava flows produced during effusive eruptions led to the generation of tabular layers of fine-grained, greenish or grey andesites, trachytes and dacites. Pyroclastic flow deposits correspond mainly to welded ignimbrites made up of former glassy pyroclasts devitrified to microcrystalline groundmass, scarce crystals of euhedral plagioclase, quartz and K-feldspar, opaque minerals, aggregates of fine-grained phyllosilicates and fiammes defining a bedding-parallel foliation generated by welding or diagenetic compaction. Widespread silicified and silica-permineralized plant remains and carbonate mud clasts are found, usually embedded within the ignimbrites. The carbonate sequences are underlain and overlain by volcanic rocks. The carbonate sequence bottoms are mostly gradational, while their tops are usually sharp. The lower part of the carbonate sequences is made up of mud which appear progressively, filling interstices in the top of the underlying volcanic rocks. They gradually become more abundant until they form the whole of the rock fabric. Carbonate on volcanic sandstones and pyroclastic deposits occur, with the nucleation of micritic carbonate and associated production of pyrite. Cyanobacteria, which formed the locus of mineral precipitation, were related with this nucleation. The growth of some of the algal mounds was halted by the progressive accumulation of volcanic ash particles, but in most cases the upper boundary is sharp and suddenly truncated by pyroclastic flows or volcanic avalanches. These pyroclastic flows partially destroyed the

Regional Management of an Aquifer for Mining Under Fuzzy Environmental Objectives

Science.gov (United States)

BogáRdi, IstváN.; BáRdossy, AndráS.; Duckstein, Lucien

1983-12-01

A methodology is developed for the dynamic multiobjective management of a multipurpose regional aquifer. In a case study of bauxite mining in Western Hungary, ore deposits are often under the piezometric level of a karstic aquifer, while this same aquifer also provides recharge flows for thermal springs. N + 1 objectives are to be minimized, the first one being total discounted cost of control by dewatering or grouting; the other N objectives consist of the flow of thermal springs at N control points. However, there is no agreement among experts as to a set of numerical values that would constitute a "sound environment"; for this reason a fuzzy set analysis is used, and the N environmental objectives are combined into a single fuzzy membership function. The constraints include ore availability, various capacities, and the state transition function that describes the behavior of both piezometric head and underground flow. The model is linearized and solved as a biobjective dynamic program by using multiobjective compromise programming. A numerical example with N = 2 appears to lead to realistic control policies. Extension of the model to the nonlinear case is discussed.

Death Valley Lower Carbonate Aquifer Monitoring Program Wells Down gradient of the Proposed Yucca Mountain Nuclear Waste Repository

International Nuclear Information System (INIS)

Inyo County

2006-01-01

Inyo County has participated in oversight activities associated with the Yucca Mountain Nuclear Waste Repository since 1987. The overall goal of these studies are the evaluation of far-field issues related to potential transport, by ground water, or radionuclides into Inyo County, including Death Valley, and the evaluation of a connection between the Lower Carbonate Aquifer (LCA) and the biosphere. Our oversight and completed Cooperative Agreement research, and a number of other investigators research indicate that there is groundwater flow between the alluvial and carbonate aquifers both at Yucca Mountain and in Inyo County. In addition to the potential of radionuclide transport through the LCA, Czarnecki (1997), with the US Geological Survey, research indicate potential radionuclide transport through the shallower Tertiary-age aquifer materials with ultimate discharge into the Franklin Lake Playa in Inyo County. The specific purpose of this Cooperative Agreement drilling program was to acquire geological, subsurface geology, and hydrologic data to: (1) establish the existence of inter-basin flow between the Amargosa Basin and Death Valley Basin; (2) characterize groundwater flow paths in the LCA through Southern Funeral Mountain Range, and (3) Evaluation the hydraulic connection between the Yucca Mountain repository and the major springs in Death Valley through the LCA

A geologic scenario for catastrophic failure of the Yucca Mountain Nuclear Waste Repository, Nevada

International Nuclear Information System (INIS)

McMackin, M.R.

1993-01-01

A plausible combination of geologic factors leading to failure can be hypothesized for the Yucca Mountain Nuclear Waste Repository. The scenarios is constructed using elementary fault mechanics combined with geologic observations of exhumed faults and published information describing the repository site. The proposed repository site is located in the Basin and Range Province, a region of active crustal deformation demonstrated by widespread seismicity. The Yucca Mountain area has been characterized as tectonically quiet, which in the context of active crustal deformation may indicate the accumulation of the stresses approaching the levels required for fault slip, essentially stick-slip faulting. Simultaneously, dissolution of carbonate rocks in underlying karst aquifers is lowering the bulk strength of the rock that supports the repository site. Rising levels of hydrostatic stress concurrent with a climatically-driven rise in the water table could trigger faulting by decreasing the effective normal stress that currently retards fault slip. Water expelled from collapsing caverns in the underlying carbonate aquifer could migrate upward with sufficient pressure to open existing fractures or create new fractures by hydrofracturing. Water migrating through fractures could reach the repository in sufficient volume to react with heated rock and waste perhaps creating steam explosions that would further enhance fracture permeability. Closure of conduits in the underlying carbonate aquifer could lead to the elevation of the saturated zone above the level of the repository resulting in sustained saturation of radioactive waste in the repository and contamination of through-flowing groundwater

Field trials of aquifer protection in longwall mining of shallow coal seams in China

Energy Technology Data Exchange (ETDEWEB)

Zhang, D.S.; Fan, G.W.; Liu, Y.D.; Ma, L.Q. [State Key Laboratory of Coal Resource & Mine Safety, Xuzhou (China)

2010-09-15

The large-scale mining of shallow coal seams has a significant impact on the overlying aquifers and surface ecological environment. To protect the aquifers and maximize the coal resource recovery, field trials were undertaken during the operation of the LW32201 in Bulianta coal mine, Shendong, China. With a severely weathered rock (SWR) layer and two key strata (KS) in the overlying strata, aquifer protection in longwall mining (APLM) relies mainly on the rapid advance. In some localized zones, special measures should be taken to achieve the APLM, including lowering mining height, backfill and slurry injection. To further understand the mechanism and applicable conditions of the APLM and validate the effectiveness of the APLM, variation of the water table in the aquifer was observed as the longwall face passed through the zone. This paper also discusses the mechanism and basic requirements of the APLM and the relationship between the fall of the water table and the surface subsidence. The results of the field trials indicated that APLM in shallow coal seams could be successful under suitable conditions.

Reactive transport modelling of groundwater chemistry in a chalk aquifer at the watershed scale.

Science.gov (United States)

Mangeret, A; De Windt, L; Crançon, P

2012-09-01

This study investigates thermodynamics and kinetics of water-rock interactions in a carbonate aquifer at the watershed scale. A reactive transport model is applied to the unconfined chalk aquifer of the Champagne Mounts (France), by considering both the chalk matrix and the interconnected fracture network. Major element concentrations and main chemical parameters calculated in groundwater and their evolution along flow lines are in fair agreement with field data. A relative homogeneity of the aquifer baseline chemistry is rapidly reached in terms of pH, alkalinity and Ca concentration since calcite equilibrium is achieved over the first metres of the vadose zone. However, incongruent chalk dissolution slowly releases Ba, Mg and Sr in groundwater. Introducing dilution effect by rainwater infiltration and a local occurrence of dolomite improves the agreement between modelling and field data. The dissolution of illite and opal-CT, controlling K and SiO(2) concentrations in the model, can be approximately tackled by classical kinetic rate laws, but not the incongruent chalk dissolution. An apparent kinetic rate has therefore been fitted on field data by inverse modelling: 1.5×10(-5) mol(chalk)L (-1) water year (-1). Sensitivity analysis indicates that the CO(2) partial pressure of the unsaturated zone is a critical parameter for modelling the baseline chemistry over the whole chalk aquifer. Copyright © 2012 Elsevier B.V. All rights reserved.

Micro-CT in situ study of carbonate rock microstructural evolution for geologic CO2 storage

DEFF Research Database (Denmark)

Zheng, Yi; Yang, Yan; Rogowska, M.

2017-01-01

settings such as the carbonate reservoirs in the North Sea. The final aim of our project is to find out how to control the evolution of petrophysical parameters during CO2 injection using an optimal combination of flow rate, injection pressure and chemical composition of the influent. The first step...... to achieve this is to find a suitable condition to create a stable 3D space in carbonate rock by injecting liquid to prepare space for the later CO2 injection. Micro-CT imaging is a non-destructive 3D method that can be used to study the property changes of carbonate rocks during and after CO2 injection...

Review of Aquifer Storage and Recovery Performance in the Upper Floridan Aquifer in Southern Florida

Science.gov (United States)

Reese, Ronald S.

2006-01-01

Introduction: Interest and activity in aquifer storage and recovery (ASR) in southern Florida has increased greatly during the past 10 to 15 years. ASR wells have been drilled to the carbonate Floridan aquifer system at 30 sites in southern Florida, mostly by local municipalities or counties located in coastal areas. The primary storage zone at these sites is contained within the brackish to saline Upper Floridan aquifer of the Floridan aquifer system. The strategy for use of ASR in southern Florida is to store excess freshwater available during the wet season in an aquifer and recover it during the dry season when needed for supplemental water supply. Each ASR cycle is defined by three periods: recharge, storage, and recovery. This fact sheet summarizes some of the findings of a second phase retrospective assessment of existing ASR facilities and sites.

Disposal of carbon dioxide in aquifers in the U.S.

Energy Technology Data Exchange (ETDEWEB)

Winter, E.M.; Bergman, P.D.

1995-11-01

Deep saline aquifers were investigated as potential disposal sites for CO{sub 2}. The capacity of deep aquifers for CO{sub 2} disposal in the U.S. is highly uncertain. A rough estimate, derived from global estimates, is 5,500 Gt of CO{sub 2}. Saline aquifers underlie the regions in the U.S. where most utility power plants are situated. Therefore, approximately 65 percent of CO{sub 2} from power plants could possibly be injected directly into deep saline aquifers below these plants, without the need for long pipelines.

Preliminary analysis of some waters from the confined aquifers underlying the Hanford site

International Nuclear Information System (INIS)

Deju, R.A.

1978-09-01

This report presents results of analyses available at this time from waters from some wells sampled in or near the Hanford Site. The analyses of these wells were done for various purposes and are consolidated to help define the nature of the waters found within the Columbia Plateau basaltic sequence. Results of the analyses show the waters from the unconfined aquifers underlying the Hanford Site are characterized by a high calcium--magnesium content. These waters can be described as calcium--magnesium--bicarbonate-type. Waters from deeper basaltic confined aquifers are primarily of the sodium bicarbonate type. Two waters sampled from the Grande Ronde Formation from Rattlesnake Hills Exploratory Well Number 1 are slightly different and can be described as sodium--calcium--bicarbonate--sulfate--chloride-type. Age-dating results for these water samples lead to the conclusions that waters from the confined aquifers were entrapped 15,000 to 23,000 years ago

Preliminary study of the physico-chemical and hydrodynamical characteristics of the crystalline basement aquifer of the Ihorombe region (south of Madagascar)

International Nuclear Information System (INIS)

Rakotoaridera, Z.S.

2008-04-01

The hydrochemical, hydrogeological and isotopic data have been used to determine the chemical and hydrodynamical characteristics of crystalline basement aquifer of the Ihorombe region. The study area is located in the District of Ihosy, which is about 600 km in the south of Antananarivo along the national road 7. Two types of aquifer have been found in this area: a phreatic aquifer composed of alterd metamorphic rocks, and a semi confined aquifer, which flows in a fissured and fractured rocks such as gneiss, and leptinites.The ground water mineralization is controlled by HCO 3- , Ca 2+ , Na + , Cl - . The dominant hydrochemical types of water in the study area are calcium and sodium bicarbonate. Some water samples show chloride types. The groundwater mineralization process is especially due to water rock interaction. The ground water is directly recharged by rain water. For the phreatic aquifer, the tritium values have provide a mean resident time less than 50 years, and for the semi confined aquifer, it is approximately above 100 years. [fr

Hydraulic characterization of aquifers, reservoir rocks, and soils: A history of ideas

Science.gov (United States)

Narasimhan, T. N.

1998-01-01

Estimation of the hydraulic properties of aquifers, petroleum reservoir rocks, and soil systems is a fundamental task in many branches of Earth sciences and engineering. The transient diffusion equation proposed by Fourier early in the 19th century for heat conduction in solids constitutes the basis for inverting hydraulic test data collected in the field to estimate the two basic parameters of interest, namely, hydraulic conductivity and hydraulic capacitance. Combining developments in fluid mechanics, heat conduction, and potential theory, the civil engineers of the 19th century, such as Darcy, Dupuit, and Forchheimer, solved many useful problems of steady state seepage of water. Interest soon shifted towards the understanding of the transient flow process. The turn of the century saw Buckingham establish the role of capillary potential in governing moisture movement in partially water-saturated soils. The 1920s saw remarkable developments in several branches of the Earth sciences; Terzaghi's analysis of deformation of watersaturated earth materials, the invention of the tensiometer by Willard Gardner, Meinzer's work on the compressibility of elastic aquifers, and the study of the mechanics of oil and gas reservoirs by Muskat and others. In the 1930s these led to a systematic analysis of pressure transients from aquifers and petroleum reservoirs through the work of Theis and Hurst. The response of a subsurface flow system to a hydraulic perturbation is governed by its geometric attributes as well as its material properties. In inverting field data to estimate hydraulic parameters, one makes the fundamental assumption that the flow geometry is known a priori. This approach has generally served us well in matters relating to resource development primarily concerned with forecasting fluid pressure declines. Over the past two decades, Earth scientists have become increasingly concerned with environmental contamination problems. The resolution of these problems

Occurrence, frequency, and significance of cavities in fractured-rock aquifers near Oak Ridge National Laboratory, Tennessee

International Nuclear Information System (INIS)

Moore, G.K.

1988-01-01

Virtually all wells drilled into bedrock intercept a water-bearing fracture, but cavities occur only in areas underlaid by limy rocks. Multiple cavities are common in wells in the Conasauga and Knox Groups but are rare in the Rome Formation and the Chickamauga Group. The geometric mean height (vertical dimension) of the cavities is 0.59 m, the geometric mean depth is 14 m, the average lateral spatial frequency is 0.16, and the average vertical spatial frequency is 0.019. Differences in cavity parameter values are caused partly by geologic factors such as lithology, bed thickness, and spatial fracture frequency. However, hydrologic factors such as percolation rate, recharge amount, aquifer storage capacity, and differences between lateral and vertical permeability may also be important. Tracer tests show that groundwater velocity in some cavities is in the range 20-300 m/d, and relatively rapid flow rates occur near springs. In contrast, wells that intercept cavities have about the same range in hydraulic conductivity as wells in regolith and fractured rock. The hydraulic conductivity data indicate a flow rate of less than 1.0 m/d. This difference cannot be adequately explained, but rapid groundwater movement may be much more common above the water table than below. Rapid groundwater flows below the water table might be rare except near springs in the Knox Group. 10 refs., 3 figs., 4 tabs

Conceptual and analytical modeling of fracture zone aquifers in hard rock. Implications of pumping tests in the Pohjukansalo well field, east-central Finland

International Nuclear Information System (INIS)

Leveinen, J.

2001-01-01

Fracture zones with an interconnected network of open fractures can conduct significant groundwater flow and as in the case of the Pohjukansalo well field in Leppaevirta, can yield sufficiently for small-scale municipal water supply. Glaciofluvial deposits comprising major aquifers commonly overlay fracture zones that can contribute to the water balance directly or indirectly by providing hydraulic interconnections between different formations. Fracture zones and fractures can also transport contaminants in a poorly predictable way. Consequently, hydrogeological research of fracture zones is important for the management and protection of soil aquifers in Finland. Hydraulic properties of aquifers are estimated in situ by well test analyses based on analytical models. Most analytical models rely on the concepts of radial flow and horizontal slab aquifer. In Paper 1, pump test responses of fracture zones in the Pohjukansalo well field were characterised based on alternative analytical models developed for channelled flow cases. In Paper 2, the tests were analysed based on the generalised radial flow (GRF) model and a concept of a fracture network possessing fractional flow dimension due to limited connectivity compared to ideal 2- or 3- dimensional systems. The analysis provides estimates of hydraulic properties in terms of parameters that do not have concrete meaning when the flow dimension of the aquifer has fractional values. Concrete estimates of hydraulic parameters were produced by making simplified assumptions and by using the composite model developed in Paper 3. In addition to estimates of hydraulic parameters, analysis of hydraulic tests provides qualitative information that is useful when the hydraulic connections in the fracture system are not well known. However, attention should be paid to the frequency of drawdown measurements-particularly for the application of derivative curves. In groundwater studies, analytical models have been also used to estimate

First accelerator carbon-14 date for pigment from a rock painting

International Nuclear Information System (INIS)

Van der Merwe, N.J.; Sealy, J.; Yates, R.

1987-01-01

South Africa is particularly blessed with rock art: thousands of paintings and engravings provide a window on the cognitive systems of prehistoric populations. A major stumbling block in studying the art is the lack of a method for dating it. This article shows that some of the paintings can be directly dated by means of accelerator 14 C counting of carbon from black pigment. The advent of accelerator 14 C provides the capability of analysing very small samples and brings pigments from rock paintings into the realm of datable materials

Borehole depth and regolith aquifer hydraulic characteristics of ...

African Journals Online (AJOL)

EJIRO

composition tend to exhibit similar hydraulic characteristics. But the poor performance of ... mum borehole depth in the regolith aquifer for the area and also reveals that ..... most important end products of chemical weathering of rocks of granitic ...

Influence of Mg²⁺ on CaCO₃ precipitation during subsurface reactive transport in a homogeneous silicon-etched pore network

Energy Technology Data Exchange (ETDEWEB)

Boyd, Victoria [Univ. of Illinois, Urbana-Champaign, IL (United States); Yoon, Hongkyu [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Zhang, Changyong [Exxon Mobil Upstream Research Company, Houston, TX (United States); Oostrom, Martinus [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hess, Nancy J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fouke, Bruce W. [Univ. of Illinois, Urbana-Champaign, IL (United States); Valocchi, Albert J. [Univ. of Illinois, Urbana-Champaign, IL (United States); Werth, Charles J. [Univ. of Illinois, Urbana-Champaign, IL (United States)

2014-04-04

Calcium carbonate (CaCO₃) geochemical reactions exert a fundamental control on the evolution of porosity and permeability in shallow-to-deep subsurface siliciclastic and limestone rock reservoirs. As a result, these carbonate water-rock interactions play a critically important role in research on groundwater remediation, geological carbon sequestration, and hydrocarbon exploration. A study was undertaken to determine the effects of Mg²⁺ concentration on CaCO₃ crystal morphology, precipitation rate, and porosity occlusion under flow and mixing conditions similar to those in subsurface aquifers.

Strontium isotope geochemistry of groundwater in the central part of the Dakota (Great Plains) aquifer, USA

International Nuclear Information System (INIS)

Gosselin, David C.; Edwin Harvey, F.; Frost, Carol; Stotler, Randy; Allen Macfarlane, P.

2004-01-01

The Dakota aquifer of the central and eastern Great Plains of the United States is an important source of water for municipal supplies, irrigation and industrial use. Although the regional flow system can be characterized generally as east to northeasterly from the Rocky Mountains towards the Missouri River, locally the flow systems are hydrologically complex. This study uses Sr isotopic data from groundwater and leached aquifer samples to document the complex subsystems within the Dakota aquifer in Nebraska and Kansas. The interaction of groundwater with the geologic material through which it flows has created spatial patterns in the isotopic measurements that are related to: long-term water-rock interaction, during which varying degrees of isotopic equilibrium between water and rock has been achieved; and the alteration of NaCl fluids by water-rock interaction. Specifically, Sr isotopic data distinguish brines from Kansas and western Nebraska from those in eastern Nebraska: the former are interpreted to reflect interaction with Permian rocks, whereas the latter record interaction with Pennsylvanian rocks. The Sr isotopic composition of groundwater from other parts of Nebraska and Kansas are a function of the dynamic interaction between groundwater and unlithified sediments (e.g., glacial till and loess), followed by interaction with oxidized and unoxidized sediments within the Dakota Formation. This study illustrates the power of combining Sr chemistry with more conventional geochemical data to obtain a more complete understanding of groundwater flow systems within regional aquifer systems where extensive monitoring networks do not exist

Microbiological monitoring of carbon dioxide storage in a subsurface saline aquifer in Ketzin/Germany within the scope of CO2SINK

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Wandrey, M.; Morozova, D.; Zemke, K.; Lerm, S.; Scherf, A.-K.; Vieth, A.; Würdemann, H.; Co2SINK Group

2009-04-01

Within the scope of the EU project CO2SINK (www.co2sink.org) a research facility in Ketzin (Germany, west of Berlin) is operated to store CO2 in a saline subsurface aquifer (Würdemann et al., EGU General Assembly 2009). In order to examine the influence of CO2 storage on the environment a comprehensive monitoring program is applied at this site including molecular and microbiological investigations. With the injection of CO2 into the geological formation chemical and physical reservoir characteristics are changed. This may influence the composition and activities of the deep biosphere at the storage horizon. Mineral precipitation, dissolution and corrosion of reservoir casing may be consequences, influencing permeability and long-term stability of the reservoir. The objective of the microbial monitoring program is the characterisation of the microbial community (biocenosis) in fluid samples, as well as in samples from reservoir and cap rock before and during CO2storage using molecular biological methods. 16S rRNA taxonomic studies, Fluorescence in situ hybridisation (FISH), and RealTime PCR are used to examine the composition of the biocenosis. First results of fluid sampling revealed that the microbial community of the saline aquifer is dominated by haloalkaliphilic fermentative bacteria and extremophilic organisms, coinciding with reduced conditions, high salinity and pressure. RealTime RT-PCR of selected genes and the creation and analysis of cDNA libraries will allow the prediction of microbial metabolic activities. In addition, the analysis of organic and inorganic components of the samples will add to the knowledge of possible metabolic shifts during CO2 storage. In order to simulate the storage conditions in situ, long term laboratory experiments in high pressure incubators have been set up using original rock cores from Ketzin. Since DNA and RNA analysis techniques are very sensitive, contamination entries from the adjacent environment have to be excluded

Quantification of the specific yield in a two-layer hard-rock aquifer model

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Durand, Véronique; Léonardi, Véronique; de Marsily, Ghislain; Lachassagne, Patrick

2017-08-01

Hard rock aquifers (HRA) have long been considered to be two-layer systems, with a mostly capacitive layer just below the surface, the saprolite layer, and a mainly transmissive layer underneath, the fractured layer. Although this hydrogeological conceptual model is widely accepted today within the scientific community, it is difficult to quantify the respective storage properties of each layer with an equivalent porous medium model. Based on an HRA field site, this paper attempts to quantify in a distinct manner the respective values of the specific yield (Sy) in the saprolite and the fractured layer, with the help of a deterministic hydrogeological model. The study site is the Plancoët migmatitic aquifer located in north-western Brittany, France, with piezometric data from 36 observation wells surveyed every two weeks for eight years. Whereas most of the piezometers (26) are located where the water table lies within the saprolite, thus representing the specific yield of the unconfined layer (Sy1), 10 of them are representative of the unconfined fractured layer (Sy2), due to their position where the saprolite is eroded or unsaturated. The two-layer model, based on field observations of the layer geometry, runs with the MODFLOW code. 81 values of the Sy1/Sy2 parameter sets were tested manually, as an inverse calibration was not able to calibrate these parameters. In order to calibrate the storage properties, a new quality-of-fit criterion called ;AdVar; was also developed, equal to the mean squared deviation of the seasonal piezometric amplitude variation. Contrary to the variance, AdVar is able to select the best values for the specific yield in each layer. It is demonstrated that the saprolite layer is about 2.5 times more capacitive than the fractured layer, with Sy1 = 10% (7% < Sy1 < 15%) against Sy2 = 2% (1% < Sy2 < 3%), in this particular example.

Mobilization of Trace Metals in an Experimental Carbon Sequestration Scenario

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Marcon, V.; Kaszuba, J. P.

2012-12-01

similar manner, increasing in concentration with injection but continually decreasing after about 830 hours until termination of the experiment. SEM images and geochemical models indicate initial dissolution of all rocks and minerals, re-precipitation of Ca-Mg-Fe carbonates and Fe-sulfides, and precipitation of anhydrite in both systems. Calcite dissolves more readily than dolomite in these experiments, but re-precipitates in veins on dolomite. If brines leak from a storage reservoir and mix with a potable aquifer, the experimental results suggest that Ba, Cu, and Zn will not be contaminants of concern. Pb, Fe and As (still under consideration) initially exceed the EPA threshold and may require careful attention in a sequestration scenario. However, experimentally observed trends of decreasing trace metal concentration suggest that these metals could become less of a concern during the life of a carbon repository. Finally, the caprock plays an active role in trace metal mobilization in the system. The caprock provides a source of metals, although subsequent precipitation may remove metals from solution.

A multi-method approach for groundwater resource assessment in coastal carbonate (karst) aquifers: the case study of Sierra Almijara (southern Spain)

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Andreo, B.; Barberá, J. A.; Mudarra, M.; Marín, A. I.; García-Orellana, J.; Rodellas, V.; Pérez, I.

2018-02-01

Understanding the transference of water resources within hydrogeological systems, particularly in coastal aquifers, in which groundwater discharge may occur through multiple pathways (through springs, into rivers and streams, towards the sea, etc.), is crucial for sustainable groundwater use. This research aims to demonstrate the usefulness of the application of conventional recharge assessment methods coupled to isotopic techniques for accurately quantifying the hydrogeological balance and submarine groundwater discharge (SGD) from coastal carbonate aquifers. Sierra Almijara (Southern Spain), a carbonate aquifer formed of Triassic marbles, is considered as representative of Mediterranean coastal karst formations. The use of a multi-method approach has permitted the computation of a wide range of groundwater infiltration rates (17-60%) by means of direct application of hydrometeorological methods (Thornthwaite and Kessler) and spatially distributed information (modified APLIS method). A spatially weighted recharge rate of 42% results from the most coherent information on physiographic and hydrogeological characteristics of the studied system. Natural aquifer discharge and groundwater abstraction have been volumetrically quantified, based on flow and water-level data, while the relevance of SGD was estimated from the spatial analysis of salinity, 222Rn and the short-lived radium isotope 224Ra in coastal seawater. The total mean aquifer discharge (44.9-45.9 hm3 year-1) is in agreement with the average recharged groundwater (44.7 hm3 year-1), given that the system is volumetrically equilibrated during the study period. Besides the groundwater resources assessment, the methodological aspects of this research may be interesting for groundwater management and protection strategies in coastal areas, particularly karst environments.

Coastal aquifer management under parameter uncertainty: Ensemble surrogate modeling based simulation-optimization

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Janardhanan, S.; Datta, B.

2011-12-01

Surrogate models are widely used to develop computationally efficient simulation-optimization models to solve complex groundwater management problems. Artificial intelligence based models are most often used for this purpose where they are trained using predictor-predictand data obtained from a numerical simulation model. Most often this is implemented with the assumption that the parameters and boundary conditions used in the numerical simulation model are perfectly known. However, in most practical situations these values are uncertain. Under these circumstances the application of such approximation surrogates becomes limited. In our study we develop a surrogate model based coupled simulation optimization methodology for determining optimal pumping strategies for coastal aquifers considering parameter uncertainty. An ensemble surrogate modeling approach is used along with multiple realization optimization. The methodology is used to solve a multi-objective coastal aquifer management problem considering two conflicting objectives. Hydraulic conductivity and the aquifer recharge are considered as uncertain values. Three dimensional coupled flow and transport simulation model FEMWATER is used to simulate the aquifer responses for a number of scenarios corresponding to Latin hypercube samples of pumping and uncertain parameters to generate input-output patterns for training the surrogate models. Non-parametric bootstrap sampling of this original data set is used to generate multiple data sets which belong to different regions in the multi-dimensional decision and parameter space. These data sets are used to train and test multiple surrogate models based on genetic programming. The ensemble of surrogate models is then linked to a multi-objective genetic algorithm to solve the pumping optimization problem. Two conflicting objectives, viz, maximizing total pumping from beneficial wells and minimizing the total pumping from barrier wells for hydraulic control of

Geo-Mechanical Characterization of Carbonate Rock Masses by Means of Laser Scanner Technique

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Palma, Biagio; Parise, Mario; Ruocco, Anna

2017-12-01

Knowledge of the geometrical and structural setting of rock masses is crucial to evaluate the stability and to design the most suitable stabilization works. In this work we use the Terrestrial Laser Scanning (TLS) at the site of the Grave of the Castellana Caves, a famous show cave in southern Italy. The Grave is the natural access to the cave system, produced by collapse of the vault, due to upward progression of instabilities in the carbonate rock masses. It is about 55-m high, bell-shaped, with maximum width of 120 m. Aim of the work is the characterization of carbonate rock masses from the structural and geo-mechanical standpoints through the use of innovative survey techniques. TLS survey provides a product consisting of millions of geo-referenced points, to be managed in space, to become a suitable database for the morphological and geological-structural analysis. Studying by means of TLS a rock face, partly inaccessible or located in very complex environments, allows to investigate slopes in their overall areal extent, thus offering advantages both as regards safety of the workers and time needed for the survey. In addition to TLS, the traditional approach was also followed by performing scanlines surveys along the rims of the Grave, following the ISRM recommendations for characterization of discontinuity in rock masses. A quantitative comparison among the data obtained by TLS technique and those deriving from the classical geo-mechanical survey is eventually presented, to discuss potentiality of drawbacks of the different techniques used for surveying the rock masses.

Laboratory investigations into the reactive transport module of carbon dioxide sequestration and geochemical simulation

Energy Technology Data Exchange (ETDEWEB)

Heidaryan, E. [Islamic Azad Univ., Tehran (Iran, Islamic Republic of). Masjidosolayman Branch; Enayati, M.; Mokhtari, B. [Iranian Offshore Oil Co., Tehran (Iran, Islamic Republic of)

2008-07-01

Over long time periods, geological sequestration in some systems shows mineralization effects or mineral sequestration of carbon dioxide, converting the carbon dioxide to a less mobile form. However, a detailed investigation of these geological systems is needed before disposing of carbon dioxide into these formations. Depleted oil and gas reservoirs and underground aquifers are proposed candidates for carbon dioxide injection. This paper presented an experimental investigation into the reactive transport module for handling aquifer sequestration of carbon dioxide and modeling of simultaneous geochemical reactions. Two cases of laboratory carbon dioxide sequestration experiments, conducted for different rock systems were modeled using the fully coupled geochemical compositional simulator. The relevant permeability relationships were compared to determine the best fit with the experimental results. The paper discussed the theory of modeling; geochemical reactions and mineral trapping of carbon dioxide; and application simulator for modeling including the remodeling of flow experiments. It was concluded that simulated changes in porosity and permeability could mimic experimental results to some extent. The study satisfactorily simulated the results of experimental observations and permeability results could be improved if the Kozeny-Carman equation was replaced by the Civan power law. 6 refs., 2 tabs., 21 figs.

Groundwater level responses to precipitation variability in Mediterranean insular aquifers

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Lorenzo-Lacruz, Jorge; Garcia, Celso; Morán-Tejeda, Enrique

2017-09-01

Groundwater is one of the largest and most important sources of fresh water on many regions under Mediterranean climate conditions, which are exposed to large precipitation variability that includes frequent meteorological drought episodes, and present high evapotranspiration rates and water demand during the dry season. The dependence on groundwater increases in those areas with predominant permeable lithologies, contributing to aquifer recharge and the abundance of ephemeral streams. The increasing pressure of tourism on water resources in many Mediterranean coastal areas, and uncertainty related to future precipitation and water availability, make it urgent to understand the spatio-temporal response of groundwater bodies to precipitation variability, if sustainable use of the resource is to be achieved. We present an assessment of the response of aquifers to precipitation variability based on correlations between the Standardized Precipitation Index (SPI) at various time scales and the Standardized Groundwater Index (SGI) across a Mediterranean island. We detected three main responses of aquifers to accumulated precipitation anomalies: (i) at short time scales of the SPI (24 months). The differing responses were mainly explained by differences in lithology and the percentage of highly permeable rock strata in the aquifer recharge areas. We also identified differences in the months and seasons when aquifer storages are more dependent on precipitation; these were related to climate seasonality and the degree of aquifer exploitation or underground water extraction. The recharge of some aquifers, especially in mountainous areas, is related to precipitation variability within a limited spatial extent, whereas for aquifers located in the plains, precipitation variability influence much larger areas; the topography and geological structure of the island explain these differences. Results indicate large spatial variability in the response of aquifers to precipitation in

Stress path dependent hydromechanical behaviour of heterogeneous carbonate rock

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Dimanov A.

2010-06-01

Full Text Available The influence of stress paths, representative of reservoir conditions, on the hydromechanical behavior of a moderately heterogeneous carbonate has been investigated. Multiscale structural heterogeneities, common for instance in carbonate rocks, can strongly alter the mechanical response and significantly influence the evolution of flow properties with stress. Using a triaxial cell, the permeability evolutions during compression and the effects of brittle (fracture and plastic (pore collapse deformations at yield, were measured. A strong scattering was observed on the mechanical response both in term of compressibility and failure threshold. Using the porosity scaling predicted by an adapted effective medium theory (based on crack growth under Hertzian contact, we have rescaled the critical pressures by the normalized porosity deviation. This procedure reduces efficiently the scattering, revealing in the framework of proportional stress path loading, a linear relation between the critical pressures and the stress path parameter through all the deformation regimes. It leads to a new formulation for the critical state envelope in the 'mean stress, deviatoric stress' diagram. The attractive feature of this new yield envelope formulation relies on the fact that only the two most common different mechanical tests 'Uniaxial Compression' and 'Hydrostatic Compression', are needed to define entirely the yield envelope. Volumic strains and normalized permeabilities are finally mapped in the stresses diagram and correlated.

U.S. Geological Survey Karst Interest Group Proceedings, Bowling Green, Kentucky, May 27-29, 2008

Science.gov (United States)

Kuniansky, Eve L.

2008-01-01

*INTRODUCTION AND ACKNOWLEDGMENTS* Karst aquifer systems are present throughout parts of the United States and some of its territories. The complex depositional environments that form carbonate rocks combined with post-depositional tectonic events and the diverse climatic regimes under which these rocks were formed result in unique hydrologic systems. The dissolution of calcium carbonate and the subsequent development of distinct and beautiful landscapes, caverns, and springs have resulted in some karst areas of the United States being designated as national or state parks and commercial caverns. Karst aquifers and landscapes that form in tropical areas, such as the north coast of Puerto Rico, differ greatly from karst areas in more arid climates, such as central Texas or western South Dakota. Many of these public and private lands contain unique flora and fauna associated with the hydrologic systems in these karst areas. As a result, multiple Federal, State, and local agencies have an interest in the study of karst terrains. Carbonate sediments and rocks (limestone and dolomite) are composed of greater than 50 percent carbonate minerals and the predominant carbonate mineral is calcium carbonate or limestone (CaCO3). Unlike terrigenous clastic sedimentation, the depositional processes that produce carbonate rocks are complex, involving both biological and physical processes. These depositional processes impact greatly the development of permeability of the sediments. Carbonate minerals readily dissolve or precipitate depending on the chemistry of the water flowing through the rock, thus the study of both marine and meteoric diagenesis of carbonate sediments is multidisciplinary. Even with a better understanding of the depositional environment and subsequent diagenesis, the dual porosity nature of karst aquifers presents challenges to scientists attempting to study ground-water flow and contaminant transport. Many of the major springs and aquifers in the United

Solid as a rock

International Nuclear Information System (INIS)

Pincus, H.J.

1984-01-01

Recent technologic developments have required a more comprehensive approach to the behavior of rock mass or rock substance plus discontinuities than was adequate previously. This work considers the inherent problems in such operations as the storage of hot or cold fluids in caverns and aquifers, underground storage of nuclear waste, underground recovery of heat from hydrocarbon fuels, tertiary recovery of oil by thermal methods, rapid excavation of large openings at shallow to great depths and in hostile environments, and retrofitting of large structures built on or in rock. The standardization of methods for determining rock properties is essential to all of the activities described, for use not only in design and construction but also in site selection and post-construction monitoring. Development of such standards is seen as a multidisciplinary effort

Carbonation of Subduction Interface Ultramafic Rocks and Implications for Deep Carbon Cycling: Evidence from Hybrid Serpentinite-Marble in the Voltri Massif, Italy

Science.gov (United States)

Scambelluri, M.; Bebout, G. E.; Gilio, M.; Belmonte, D.; Campomenosi, N.; Crispini, L.

2015-12-01

Release of COH fluids from hydrous minerals and carbonates influences element recycling and magmatism at subduction zones. Contradictory interpretations exist regarding the retention/storage of C in subducting plates and in the forearc to subarc mantle. Multiple lines of evidence indicate mobility of C in forearcs; however, the magnitude of this loss is highly uncertain[1-5]. A poorly constrained fraction of the 40-115 Mt/y of C initially subducted is released into fluids (e.g., by decarbonation, carbonate dissolution), and 18-43 Mt/y is returned at arc volcanoes[2-5, refs. therein]. The imbalance could reflect subduction into the deeper mantle or forearc/subarc storage[4-7]. We examine the fate of C in slab/interface ultramafic rocks, and by analogy serpentinized mantle wedge, via study of fluid-rock evolution of marble and variably carbonated serpentinite (Ligurian Alps). Based on petrography, and major/trace element and C and O isotope compositions, we demonstrate that serpentinite dehydration at 2-2.5 GPa, 550°C released aqueous fluids triggering breakdown of dolomite in nearby marbles, thus releasing C into fluids. Carbonate + olivine veins document flow of COH fluids; interaction of these COH fluids with serpentinite led to formation of high-pressure carbonated ultramafic-rock domains, thus resulting in retention of C in some rocks at an ancient subduction interface. We stress that lithologically complex interfaces could contain sites of both C release and C addition, further confounding estimates of net C loss at forearc and subarc depths [cf 4,5]. Sites of C retention, also including carbonate veins and graphite as reduced carbonate[7], could influence the transfer of slab C to at least the depths beneath volcanic fronts. 1. Poli S et al. 2009 EPSL; 2. Ague and Nicolescu 2014 Nat Geosci; 3. Cook-Collars et al. 2014 Chem Geol; 4. Collins et al. 2015 Chem Geol; 5. Kelemen and Manning 2015 PNAS; 6. Sapienza et al. 2009 CMP; 7 Galvez et al. 2013 Nat Geosci

Latest Permian carbonate carbon isotope variability traces heterogeneous organic carbon accumulation and authigenic carbonate formation

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Schobben, Martin; van de Velde, Sebastiaan; Gliwa, Jana; Leda, Lucyna; Korn, Dieter; Struck, Ulrich; Vinzenz Ullmann, Clemens; Hairapetian, Vachik; Ghaderi, Abbas; Korte, Christoph; Newton, Robert J.; Poulton, Simon W.; Wignall, Paul B.

2017-11-01

isotope variability. These findings put constraints on the application of Permian-Triassic carbon isotope chemostratigraphy based on whole-rock samples, which appears less refined than classical biozonation dating schemes. On the other hand, this signal of increased carbon isotope variability concurrent with the largest mass extinction of the Phanerozoic may provide information about local carbon cycling mediated by spatially heterogeneous (sub-)sea-floor microbial communities under suppressed bioturbation.

Latest Permian carbonate carbon isotope variability traces heterogeneous organic carbon accumulation and authigenic carbonate formation

Directory of Open Access Journals (Sweden)

M. Schobben

2017-11-01

observed signal of carbon isotope variability. These findings put constraints on the application of Permian–Triassic carbon isotope chemostratigraphy based on whole-rock samples, which appears less refined than classical biozonation dating schemes. On the other hand, this signal of increased carbon isotope variability concurrent with the largest mass extinction of the Phanerozoic may provide information about local carbon cycling mediated by spatially heterogeneous (sub-sea-floor microbial communities under suppressed bioturbation.

Distribution regularities and prospecting of carbonate-siliceous-argillitic rock type uranium deposit in China

International Nuclear Information System (INIS)

Zhao Fengmin; Pan Yan

2012-01-01

The carbonate-siliceous-argillitic rock type uranium deposit is one of the important types of uranium deposits in China. Exogenic permeability type and hydrothermal type are dominated in genetic type. Four mineralization zones, two independent mineralization districts, two potential mineralization zones can be classified in China, uranium mineralization districts can be classified further. They are classified as four levels through the potential metallogenic evaluation on the mineralization districts, an important prospective area in the near future. In order to develop and make use of carbonate-siliceous-argillitic rock type uranium resources, exploration and study should be listed in the development planning on uranium geology. (authors)

Hydrogeologic controls imposed by mechanical stratigraphy in layered rocks of the Chateauguay River Basin, a U.S.-Canada transborder aquifer

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Morin, Roger H.; Godin, Rejean; Nastev, Miroslav; Rouleau, Alain

2007-01-01

[1] The Châteauguay River Basin delineates a transborder watershed with roughly half of its surface area located in northern New York State and half in southern Québec Province, Canada. As part of a multidisciplinary study designed to characterize the hydrogeologic properties of this basin, geophysical logs were obtained in 12 wells strategically located to penetrate the four major sedimentary rock formations that constitute the regional aquifers. The layered rocks were classified according to their elastic properties into three primary units: soft sandstone, hard sandstone, and dolostone. Downhole measurements were analyzed to identify fracture patterns associated with each unit and to evaluate their role in controlling groundwater flow. Fracture networks are composed of orthogonal sets of laterally extensive, subhorizontal bedding plane partings and bed-delimited, subvertical joints with spacings that are consistent with rock mechanics principles and stress models. The vertical distribution of transmissive zones is confined to a few select bedding plane fractures, with soft sandstone having the fewest (one per 70-m depth) and hard sandstone the most (five per 70-m depth). Bed-normal permeability is examined using a probabilistic model that considers the lengths of flow paths winding along joints and bedding plane fractures. Soft sandstone has the smallest bed-normal permeability primarily because of its wide, geomechanically undersaturated joint spacing. Results indicate that the three formations have similar values of bulk transmissivity, within roughly an order of magnitude, but that each rock unit has its own unique system of groundwater flow paths that constitute that transmissivity.

Mechanical Behavior of Low Porosity Carbonate Rock: From Brittle Creep to Ductile Creep.

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Nicolas, A.; Fortin, J.; Gueguen, Y.

2014-12-01

Mechanical compaction and associated porosity reduction play an important role in the diagenesis of porous rocks. They may also affect reservoir rocks during hydrocarbon production, as the pore pressure field is modified. This inelastic compaction can lead to subsidence, cause casing failure, trigger earthquake, or change the fluid transport properties. In addition, inelastic deformation can be time - dependent. In particular, brittle creep phenomena have been deeply investigated since the 90s, especially in sandstones. However knowledge of carbonates behavior is still insufficient. In this study, we focus on the mechanical behavior of a 14.7% porosity white Tavel (France) carbonate rock (>98% calcite). The samples were deformed in a triaxial cell at effective confining pressures ranging from 0 MPa to 85 MPa at room temperature and 70°C. Experiments were carried under dry and water saturated conditions in order to explore the role played by the pore fluids. Two types of experiments have been carried out: (1) a first series in order to investigate the rupture envelopes, and (2) a second series with creep experiments. During the experiments, elastic wave velocities (P and S) were measured to infer crack density evolution. Permeability was also measured during creep experiments. Our results show two different mechanical behaviors: (1) brittle behavior is observed at low confining pressures, whereas (2) ductile behavior is observed at higher confining pressures. During creep experiments, these two behaviors have a different signature in term of elastic wave velocities and permeability changes, due to two different mechanisms: development of micro-cracks at low confining pressures and competition between cracks and microplasticity at high confining pressure. The attached figure is a summary of 20 triaxial experiments performed on Tavel limestone under different conditions. Stress states C',C* and C*' and brittle strength are shown in the P-Q space: (a) 20°C and dry

Krypton-81, Helium-4 and Carbon-14 based estimation of groundwater ages in the Guarani Aquifer System: implications for the He-4 geochronometer

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Aggarwal, P. K.; Chang, H. K.; Gastmans, D.; Sturchio, N. C.; Araguas, L.; Matsumoto, T.; Lu, Z.; Jiang, W.; Yokochi, R.; Mueller, P.

2012-12-01

Characterization of aquifer systems remains a challenge, particularly for large aquifers with limited hydrogeological information. Groundwater age is an important parameter that integrates aquifer recharge and flow dynamics and provides the ability to reliably constrain groundwater models. We have used multiple isotope tracers (C-14, He-4, and Kr-81) to estimate the age of groundwater along a 400-km transect in the north-eastern part of the Guarani Aquifer System (GAS) in Brazil. Carbon-14 measurements were made with an AMS, He-4 by mass-spectrometry, and Kr-81 by atom trap trace analysis (ATTA). Groundwater samples were collected along a groundwater flow path that runs from the outcrop area in the east to the deep confined section in the west, where the aquifer is up to about 1000 m deep. Present groundwater recharge occurs in the outcrop areas, as indicated by the presence of tritium and modern 14C. Carbon-14 activities reach values below detection limit at relatively short distances (a few km) from the outcrop. Abundance of 81Kr (half-life 229 Ka), in samples free of C-14, decreases from 0.81±0.11 (expressed as (81Kr/Kr)sample/(81Kr/Kr)air) in the east to 0.18±0.03 in the western-most sample (estimated age = 566±60 ka). Measured 4He-excess is far above that expected from in-situ production rates in sandstone aquifers and overestimates the age by several orders of magnitude. We used 81Kr ages to calibrate the 4He geochronometer which indicates a basal flux of about 2.8 x10-11 cm3STP He/cm2/a. This flux is lower than most estimates of basal flux in previous studies and will allow a wider use of 4He for groundwater dating and aquifer characterization.

Towards sustainable groundwater management in Karst aquifers in semi-arid environments: Central West Bank, Palestine

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Jebreen, H.; Banning, A.; Wohnlich, S.

2017-12-01

The Central West Bank (CWB) is characterized by karstified carbonate aquifers in the semiarid climate zone, where groundwater resources are frequently threatened by overexploitation and pollution. Despite often limited system knowledge, quantitative and qualitative factors such as groundwater recharge rate, aquifer parameters, flow and transport dynamics, anthropogenic impacts, and groundwater vulnerability need to be assessed. Therefore, sustainable groundwater use in the CWB is of critical importance. In the present study, we explore the scale of the groundwater problems in CWB as well as the possibility of sustainable management through different scenarios: 1) Managed aquifer recharge using a water balance model, stable isotopes (2H & 18O) and chloride mass balance, 2) Geochemical evolution and renewability of groundwater, and 3) Anthropogenic impacts. A total of 20 spring water samples were collected and analyzed for pH, electrical conductivity, total dissolved solids (TDS), hardness, major-ion chemistry (Cl-, HCO3-, SO42-, Na+, K+, Ca2+ and Mg2+), trace elements (Li, Be, Al, Ba, Tl, Pb, Bi, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Rb, Sr, Mo, Ag and Cd), microbiological data (total and fecal coliforms bacteria), and stable isotopes (2H & 18O). The results show a spatialized recharge rate, which ranges from 111-211 mm/year, representing 17-33 % of the long-term mean annual rainfall. The mean annual actual evapotranspiration was about 19-37 % of precipitation. The chemical composition of groundwater of the study area is strongly influenced by rock-water interaction, dissolution and deposition of carbonate and silicate minerals. Stable isotopes show that precipitation is the source of recharge to the groundwater system. All analyzed spring waters are suitable for irrigation but not for drinking purposes. This studýs results can serve as a basis for decision makers, and will lead to an increased understanding of the sustainable management of the Central West Bank

Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

Energy Technology Data Exchange (ETDEWEB)

Bacon, Diana H.

2013-03-31

The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite

Nagra technical report 14-02, Geological basics - Dossier VI - Barrier properties of proposed host rock sediments and neighbouring rock

International Nuclear Information System (INIS)

Gautschi, A.; Deplazes, G.; Traber, D.; Marschall, P.; Mazurek, M.; Gimmi, T.; Maeder, U.

2014-01-01

This dossier is the sixth of a series of eight reports concerning the safety and technical aspects of locations for the disposal of radioactive wastes in Switzerland. It discusses the barrier properties of the proposed host rock sediments and neighbouring rock layers. The mineralogical composition of the host rocks are discussed as are their pore densities and hydrological properties. Diffusion aspects are discussed. The aquifer systems in the proposed depository areas and their classification are looked at. The barrier properties of the host rocks and those of neighbouring sediments are discussed. Finally, modelling concepts and parameters for the transport of radionuclides in the rocks are discussed

Map showing minimum depth to water in shallow aquifers (1963-72) in the Sugar House quadrangle, Salt Lake County, Utah

Science.gov (United States)

Mower, R.W.; Van Horn, Richard

1973-01-01

The depth to ground water in shallow aquifers in the Sugar Horse quadrangle ranges from zero in areas of springs and seeps to more than 10 feet beneath most of the area shown on the map. The depth to water differs from place to place because of irregular topography, and the varying capability of different rock materials to transmit water. Ground water also occurs under unconfined and confined conditions in deep aquifers beneath the Sugar Horse quadrangle, as shown by the block diagram and as described by Hely, Mower, and Harr (1971a, p. 17-111).

Rock Directed Breaking Under the Impulse Load

Science.gov (United States)

Khomeriki, Sergo; Mataradze, Edgar; Chikhradze, Nikoloz; Losaberidze, Marine; Khomeriki, Davit; Shatberashvili, Grigol

2016-10-01

In the work the problem of directed chipping of facing stone material by means of managing of explosion process is considered. The technology of the mining of decorative stone by the use of explosion energy means the very rapid transfer of potential energy of elastic deformations to kinetic energy. As a result, the explosion impulse, in the expanse of the inertia of rock massive, does not cause the increase of existing cracks. In the course of explosion, the shock wave is propagated by ultrasonic velocity and in this case the medium parameters (pressure, density, temperature, velocity) increase in spurts. In spite of this fact the all three conservation laws of mechanics remain valid on basis of three laws the equations are derived by which the parameters of shock wave may be defined by means of the rock physical-mechanical properties. The load on the body volume at breaking under explosion acts over very small period of the time. Therefore, stressed-deformed state of the rock was studied when the impulse load acts on the boundary. It was considered that the mining of the blocks of facing stone is performed from the hard rocks. This means that the breaking proceeds in the zone of elastic deformation. In the conditions of mentioned assumptions, the expression of the stress tensor and displacement of vector components initiated by stressed-deformed state in the rock are written.

Sustainability of natural attenuation of nitrate in agricultural aquifers

Science.gov (United States)

Green, Christopher T.; Bekins, Barbara A.

2010-01-01

Increased concentrations of nitrate in groundwater in agricultural areas, coinciding with increased use of chemical and organic fertilizers, have raised concern because of risks to environmental and human health. At some sites, these problems are mitigated by natural attenuation of nitrate as a result of microbially mediated reactions. Results from U.S. Geological Survey (USGS) research under the National Water-Quality Assessment (NAWQA) program show that reactions of dissolved nitrate with solid aquifer minerals and organic carbon help lower nitrate concentrations in groundwater beneath agricultural fields. However, increased fluxes of nitrate cause ongoing depletion of the finite pool of solid reactants. Consumption of the solid reactants diminishes the capacity of the aquifer to remove nitrate, calling into question the long-term sustainability of these natural attenuation processes.

Alteration of the Carbon and Nitrogen Isotopic Composition in the Martian Surface Rocks Due to Cosmic Ray Exposure

Science.gov (United States)

Pavlov, A. A.; Pavlov, A. K.; Ostryakov, V. M.; Vasilyev, G. I.; Mahaffy, P.; Steele, A.

2014-01-01

C-13/C-12 and N-15/N-14 isotopic ratios are pivotal for our understanding of the Martian carbon cycle, history of the Martian atmospheric escape, and origin of the organic compounds on Mars. Here we demonstrate that the carbon and nitrogen isotopic composition of the surface rocks on Mars can be significantly altered by the continuous exposure of Martian surface to cosmic rays. Cosmic rays can effectively produce C-13 and N-15 isotopes via spallation nuclear reactions on oxygen atoms in various Martian rocks. We calculate that in the top meter of the Martian rocks, the rates of production of both C-13 and N-15 due to galactic cosmic rays (GCRs) exposure can vary within 1.5-6 atoms/cm3/s depending on rocks' depth and chemical composition. We also find that the average solar cosmic rays can produce carbon and nitrogen isotopes at a rate comparable to GCRs in the top 5-10 cm of the Martian rocks. We demonstrate that if the total carbon content in a surface Martian rock is <10 ppm, then the "light," potentially "biological" C-13/C-12 ratio would be effectively erased by cosmic rays over 3.5 billion years of exposure. We found that for the rocks with relatively short exposure ages (e.g., 100 million years), cosmogenic changes in N-15/N-14 ratio are still very significant. We also show that a short exposure to cosmic rays of Allan Hills 84001 while on Mars can explain its high-temperature heavy nitrogen isotopic composition (N-15/N-14). Applications to Martian meteorites and the current Mars Science Laboratory mission are discussed.

Proceedings of the fifth international groundwater conference on the assessment and management of groundwater resources in hard rock systems with special reference to basaltic terrain

International Nuclear Information System (INIS)

Thangarajan, M.; Mayilswami, C.; Kulkarni, P.S.; Singh, V.P.

2012-01-01

Groundwater resources in hard rock regions with limited renewable potential have to be managed judiciously to ensure adequate supplies of dependable quantity and quality. It is a natural resource with economic, strategic and environmental value, which is under stress both due to changing climatic and anthropogenic factors. Therefore the management strategies need to be aimed at sustenance of this limited resource. In India, and also elsewhere in the world major parts of the semi-arid regions are characterized by hard rocks and it is of vital importance to understand the nature of the aquifer systems and its current stress conditions. Though the achievements through scientific development in exploration and exploitation are commendable, it has adversely affected the hard rock aquifer system, both in terms of quantity and quality; which is of major concern today. In order to reverse the situation, better management strategy of groundwater resources needs to be devised for prevention of further degradation of quality and meeting out the future demand of quantity. This necessitates: understanding the flow mechanism, evaluating the potential and evolving optimal utilization schemes, and assessing and monitoring quality in the changing scenario of anthropogenically induced agricultural, urban, industrial and climatic change. The groundwater flow mechanism through fractures in hard rocks is yet to be fully understood in terms of fracture geometry and its relation to groundwater flow. The characterization of flow geometry in basaltic aquifer is yet to be fully explored. Groundwater pollution due to anthropogenic factors is very slow process with long-term impacts on carbon cycle and global climatic change on one hand and quality on the other. It is generally recognized that the prevention of groundwater pollution is cheaper than its remedial measures in the long run. Furthermore, because of the nature of groundwater flow and the complexity and management uncertainty of

Effects of regional groundwater flow on the performance of an aquifer thermal energy storage system under continuous operation

Science.gov (United States)

Lee, Kun Sang

2014-01-01

Numerical investigations and a thermohydraulic evaluation are presented for two-well models of an aquifer thermal energy storage (ATES) system operating under a continuous flow regime. A three-dimensional numerical model for groundwater flow and heat transport is used to analyze the thermal energy storage in the aquifer. This study emphasizes the influence of regional groundwater flow on the heat transfer and storage of the system under various operation scenarios. For different parameters of the system, performances were compared in terms of the temperature of recovered water and the temperature field in the aquifer. The calculated temperature at the producing well varies within a certain range throughout the year, reflecting the seasonal (quarterly) temperature variation of the injected water. The pressure gradient across the system, which determines the direction and velocity of regional groundwater flow, has a substantial influence on the convective heat transport and performance of aquifer thermal storage. Injection/production rate and geometrical size of the aquifer used in the model also impact the predicted temperature distribution at each stage and the recovery water temperature. The hydrogeological-thermal simulation is shown to play an integral part in the prediction of performance of processes as complicated as those in ATES systems.

Multi-isotope tracing of CO2 leakage and water-rock interaction in a natural CCS analogue.

Science.gov (United States)

Kloppmann, Wolfram; Gemeni, Vasiliki; Lions, Julie; Koukouzas, Nikolaos; Humez, Pauline; Vasilatos, Charalampos; Millot, Romain; Pauwels, Hélène

2015-04-01

Natural analogues of CO2 accumulation and, potentially, leakage, provide a highly valuable opportunity to study (1) geochemical processes within a CO2-reservoir and the overlying aquifers or aquicludes, i.e. gas-water-rock interactions, (2) geology and tightness of reservoirs over geological timescales, (3) potential or real leakage pathways, (3) impact of leakage on shallow groundwater resources quality, and (4) direct and indirect geochemical indicators of gas leakage (Lions et al., 2014, Humez et al., 2014). The Florina Basin in NW Macedonia, Greece, contains a deep CO2-rich aquifer within a graben structure. The graben filling consists of highly heterogeneous Neogene clastic sediments constituted by components from the adjacent massifs including carbonates, schists, gneiss as well as some ultramafic volcanic rocks. Clay layers are observed that isolate hydraulically the deep, partly artesian aquifer. Organic matter, in form of lignite accumulations, is abundant in the Neogene series. The underlying bedrocks are metamorphic carbonates and silicate rocks. The origin of the CO2 accumulation is controversial (deep, partially mantle-derived D'Allessandro et al., 2008 or resulting from thermal decomposition of carbonates, Hatziyannis and Arvanitis, 2011). Groundwaters have been sampled from springs and borewells over 3 years at different depths. First results on major, minor and trace elements give evidence of water-rock interaction, mainly with carbonates but also with ultramafic components but do not indicate that CO2-seepage is the principal driver of those processes (Gemeni et al., submitted). Here we present isotope data on a selection of groundwaters (δ2H , δ18O, δ13CTDIC, 87Sr/86Sr, δ11B, δ7Li). Stable isotopes of water indicate paleo-recharge for some of the groundwaters, limited exchange with gaseous CO2 and, in one case, possibly thermal exchange processes with silicates. Sr isotope ratios vary between marine ratios and radiogenic values indicating

Characterising the vertical separation of shale-gas source rocks and aquifers across England and Wales (UK)

Science.gov (United States)

Loveless, Sian E.; Bloomfield, John P.; Ward, Robert S.; Hart, Alwyn J.; Davey, Ian R.; Lewis, Melinda A.

2018-03-01

Shale gas is considered by many to have the potential to provide the UK with greater energy security, economic growth and jobs. However, development of a shale gas industry is highly contentious due to environmental concerns including the risk of groundwater pollution. Evidence suggests that the vertical separation between exploited shale units and aquifers is an important factor in the risk to groundwater from shale gas exploitation. A methodology is presented to assess the vertical separation between different pairs of aquifers and shales that are present across England and Wales. The application of the method is then demonstrated for two of these pairs—the Cretaceous Chalk Group aquifer and the Upper Jurassic Kimmeridge Clay Formation, and the Triassic sandstone aquifer and the Carboniferous Bowland Shale Formation. Challenges in defining what might be considered criteria for `safe separation' between a shale gas formation and an overlying aquifer are discussed, in particular with respect to uncertainties in geological properties, aquifer extents and determination of socially acceptable risk levels. Modelled vertical separations suggest that the risk of aquifer contamination from shale exploration will vary greatly between shale-aquifer pairs and between regions and this will need to be considered carefully as part of the risk assessment and management for any shale gas development.

Hydrogeologic framework of fractured sedimentary rock, Newark Basin, New Jersey

Science.gov (United States)

Lacombe, Pierre J.; Burton, William C.

2010-01-01

delineate the lithostratigraphy from multiple wells. Gamma-ray logs and rock cores were correlated to develop a 13-layer gamma-ray stratigraphy and 41-layer lithostratigraphy throughout the fractured sedimentary rock research site. Detailed hydrogeologic framework shows that black carbon-rich laminated mudstones are the most hydraulically conductive. Water-quality and aquifer-test data indicate that groundwater flow is greatest and TCE contamination is highest in the black, carbon- and clay-rich laminated mudstones. Large-scale groundwater flow at the NAWC research site can be modeled as highly anisotropic with the highest component of permeability occurring along bedding planes.

Carbon-14 measurements and characterization of dissolved organic carbon in ground water

International Nuclear Information System (INIS)

Murphy, E.M.

1987-01-01

Carbon-14 was measured in the dissolved organic carbon (DOC) in ground water and compared with 14 C analyses of dissolved inorganic carbon (DIC). Two field sites were used for this study; the Stripa mine in central Sweden, and the Milk River Aquifer in southern Alberta, Canada. The Stripa mine consists of a Precambrian granite dominated by fracture flow, while the Milk River Aquifer is a Cretaceous sandstone aquifer characterized by porous flow. At both field sites, 14 C analyses of the DOC provide additional information on the ground-water age. Carbon-14 was measured on both the hydrophobic and hydrophilic organic fractions of the DOC. The organic compounds in the hydrophobic and hydrophilic fractions were also characterized. The DOC may originate from kerogen in the aquifer matrix, from soil organic matter in the recharge zone, of from a combination of these two sources. Carbon-14 analyses, along with characterization of the organics, were used to determine this origin. Carbon-14 analyses of the hydrophobic fraction in the Milk River Aquifer suggest a soil origin, while 14 C analyses of the hydrophilic fraction suggest an origin within the Cretaceous sediments (kerogen) or from the shale in contact with the aquifer

Hydrogeology and water-quality characteristics of the Lower Floridan aquifer in east-central Florida

Science.gov (United States)

O'Reilly, Andrew M.; Spechler, Rick M.; McGurk, Brian E.

2002-01-01

The hydrogeology and water-quality characteristics of the Lower Floridan aquifer and the relation of the Lower Floridan aquifer to the framework of the Floridan aquifer system were evaluated during a 6-year (1995-2001) study. The study area, a 7,500 square-mile area of east-central Florida, is underlain by three principal hydrogeologic units: the surficial aquifer system, the intermediate confining unit, and the Floridan aquifer system. The Floridan aquifer system, a carbonate-rock aquifer system composed of the Upper Floridan aquifer, a middle semiconfining unit, a middle confining unit, and the Lower Floridan aquifer, is the major source of water supply to east-central Florida. The Upper Floridan aquifer provides much of the water required to meet the current (2002) demand; however, the Lower Floridan aquifer is being used increasingly as a source of freshwater, particularly for municipal needs. For this reason, a better understanding of the aquifer is needed. The Lower Floridan aquifer is present throughout east-central Florida. The aquifer is composed of alternating beds of limestone and dolomite, and is characterized by abundant fractured dolomite zones and solution cavities. The altitude of the top of the Lower Floridan aquifer ranges from less than 600 feet below sea level in the northern part of the study area to more than 1,600 feet below sea level in the southwestern part. Thickness of the unit ranges from about 910 to 1,180 feet. The top of the Lower Floridan aquifer generally is marked by an increase in formation resistivity and by an increase in the occurrence of fractures and solution cavities within the carbonates. Also, a noticeable increase in borehole flow often marks the top of the unit. The bottom of the Lower Floridan aquifer is based on the first occurrence of evaporites. Ground-water in the Lower Floridan aquifer generally moves in a southwest-to-northeast direction across the study area. In September 1998, the altitude of the potentiometric

Geological and geomechanical properties of the carbonate rocks at the eastern Black Sea Region (NE Turkey)

Science.gov (United States)

Ersoy, Hakan; Yalçinalp, Bülent; Arslan, Mehmet; Babacan, Ali Erden; Çetiner, Gözde

2016-11-01

Turkey located in the Alpine-Himalayan Mountain Belt has 35% of the natural stone reserves of the world and has good quality marble, limestone, travertine and onyx reserves especially in the western regions of the country. The eastern Black Sea Region with a 1.4 million meters cubes reserve has a little role on the natural stone production in the country. For this reason, this paper deals with investigation on the potential of carbonate stone in the region and determination of the geological and geo-mechanical properties of these rocks in order to provide economic contribution to the national economy. While the study sites are selected among the all carbonate rock sites, the importance as well as the representative of the sites were carefully considered for the region. After representative samples were analyzed for major oxide and trace element compositions to find out petrochemical variations, the experimental program conducted on rock samples for determination of both physical and strength properties of the carbonate rocks. The results of the tests showed that there are significant variations in the geo-mechanical properties of the studied rock groups. The density values vary from 2.48 to 2.70 gr/cm3, water absorption by weight values range from 0.07 to 1.15% and the apparent porosity of the carbonate rocks are between 0.19 and 3.29%. However, the values of the UCS shows variation from 36 to 80 MPa. Tensile and bending strength values range from 3.2 to 7.5 MPa and 6.0-9.2 MPa respectively. Although the onyx samples have the lowest values of apparent porosity and water absorption by weight, these samples do not have the highest values of UCS values owing to occurrence of the micro-cracks. The UCS values of the rock samples were also found after cycling tests However, the limestone samples have less than 5% deterioration after freezing-thawing and wetting-drying tests, but travertine and onyx samples have more than 15% deterioration. Exception of the apparent

Distribution of uranium in the carbonate rock of Um Bogma formation, Southwest, Sinai, Egypt

International Nuclear Information System (INIS)

El-AAssy, I.E.; Ahmed, F.Y.; Morsy, A.M.; El-Fawal, F.M.; Mansour, M.Gh.

1998-01-01

The lower carboniferous Um bogma Formation is a potential source for Mn, Cu and U. it is mainly composed of dolostone and limestone with few clastic different interbeds of clay stone, siltstone and sandstone. The different diagenetic processes which affected this formation are mainly, compaction, cementation, neomorphism, dissolution, dolomitization, silicification and filling the veins and pores. The distribution of uranium and thorium within the three members and their correlation with the iron oxides and organic matter, were studied. The channel porosity and intercrystalline spaces which resulted from dolomitization acted as pathways for uraniferous solutions in the carbonate rocks. On the other hand, the shales and clay stones underneath the carbonates of Um bogma formation acted as barriers and good depositional environment for the accumulation of uranium on the surfaces of joints and fractures.The accumulated uranium minerals in the carbonate rocks are most likely of the efflorescent deposits

Lattice Boltzmann Simulations of Fluid Flow in Continental Carbonate Reservoir Rocks and in Upscaled Rock Models Generated with Multiple-Point Geostatistics

Directory of Open Access Journals (Sweden)

J. Soete

2017-01-01

Full Text Available Microcomputed tomography (μCT and Lattice Boltzmann Method (LBM simulations were applied to continental carbonates to quantify fluid flow. Fluid flow characteristics in these complex carbonates with multiscale pore networks are unique and the applied method allows studying their heterogeneity and anisotropy. 3D pore network models were introduced to single-phase flow simulations in Palabos, a software tool for particle-based modelling of classic computational fluid dynamics. In addition, permeability simulations were also performed on rock models generated with multiple-point geostatistics (MPS. This allowed assessing the applicability of MPS in upscaling high-resolution porosity patterns into large rock models that exceed the volume limitations of the μCT. Porosity and tortuosity control fluid flow in these porous media. Micro- and mesopores influence flow properties at larger scales in continental carbonates. Upscaling with MPS is therefore necessary to overcome volume-resolution problems of CT scanning equipment. The presented LBM-MPS workflow is applicable to other lithologies, comprising different pore types, shapes, and pore networks altogether. The lack of straightforward porosity-permeability relationships in complex carbonates highlights the necessity for a 3D approach. 3D fluid flow studies provide the best understanding of flow through porous media, which is of crucial importance in reservoir modelling.

Rock Outcrops Redistribute Organic Carbon and Nutrients to Nearby Soil Patches in Three Karst Ecosystems in SW China.

Directory of Open Access Journals (Sweden)

Dianjie Wang

Full Text Available Emergent rock outcrops are common in terrestrial ecosystems. However, little research has been conducted regarding their surface function in redistributing organic carbon and nutrient fluxes to soils nearby. Water that fell on and ran off 10 individual rock outcrops was collected in three 100 × 100 m plots within a rock desertification ecosystem, an anthropogenic forest ecosystem, and a secondary forest ecosystem between June 2013 and June 2014 in Shilin, SW China. The concentrations of total organic carbon (TOC, total nitrogen (N, total phosphorus (P, and potassium (K in the water samples were determined during three seasons, and the total amounts received by and flowing out from the outcrops were calculated. In all three ecosystems, TOC and N, P, and K were found throughout the year in both the water received by and delivered to nearby soil patches. Their concentrations and amounts were generally greater in forested ecosystems than in the rock desertification ecosystem. When rock outcrops constituted a high percentage (≥ 30% of the ground surface, the annual export of rock outcrop runoff contributed a large amount of organic carbon and N, P, and K nutrients to soil patches nearby by comparison to the amount soil patches received via atmospheric deposition. These contributions may increase the spatial heterogeneity of soil fertility within patches, as rock outcrops of different sizes, morphologies, and emergence ratios may surround each soil patch.

Distribution of moisture, tritium, and plutonium in the alluvium, aquifer, and underlying tuff in Mortandad Canyon

International Nuclear Information System (INIS)

Purtymun, W.D.; Maes, M.N.; Peters, R.

1985-01-01

A study of the distribution of moisture, tritium, and plutonium in the Mortandad Canyon aquifer indicates some infiltration of water into the underlying tuff. This infiltration was accompanied by similar movement of tritium. The concentrations of plutonium on the sediments in the aquifer were low when compared with the high concentrations in solution in an ionic complex that does not readily exchange or is adsorbed by clay minerals in the alluvium. 2 references, 4 figures, 2 tables

Pumping time required to obtain tube well water samples with aquifer characteristic radon concentrations

International Nuclear Information System (INIS)

Ricardo, Carla Pereira; Oliveira, Arno Heeren de

2011-01-01

Radon is an inert noble gas, which comes from the natural radioactive decay of uranium and thorium in soil, rock and water. Radon isotopes emanated from radium-bearing grains of a rock or soil are released into the pore space. Radon that reaches the pore space is partitioned between the gaseous and aqueous phases. Thus, the groundwater presents a radon signature from the rock that is characteristic of the aquifer. The characteristic radon concentration of an aquifer, which is mainly related to the emanation, is also influenced by the degree of subsurface degassing, especially in the vicinity of a tube well, where the radon concentration is strongly reduced. Looking for the required pumping time to take a tube well water sample that presents the characteristic radon concentration of the aquifer, an experiment was conducted in an 80 m deep tube well. In this experiment, after twenty-four hours without extraction, water samples were collected periodically, about ten minutes intervals, during two hours of pumping time. The radon concentrations of the samples were determined by using the RAD7 Electronic Radon Detector from Durridge Company, a solid state alpha spectrometric detector. It was realized that the necessary time to reach the maximum radon concentration, that means the characteristic radon concentration of the aquifer, is about sixty minutes. (author)

Modeling rock weathering in small watersheds

NARCIS (Netherlands)

Pacheco, F.A.L.; van der Weijden, C.H.

2014-01-01

Many mountainous watersheds are conceived as aquifer media where multiple groundwater flow systems have developed (Tóth, 1963), and as bimodal landscapes where differential weathering of bare and soil-mantled rock has occurred (Wahrhaftig, 1965). The results of a weathering algorithm (Pacheco and

Vertical gradients in water chemistry and age in the Northern High Plains Aquifer, Nebraska, 2003

Science.gov (United States)

McMahon, P.B.; Böhlke, J.K.; Carney, C.P.

2007-01-01

The northern High Plains aquifer is the primary source of water used for domestic, industrial, and irrigation purposes in parts of Colorado, Kansas, Nebraska, South Dakota, and Wyoming. Despite the aquifer’s importance to the regional economy, fundamental ground-water characteristics, such as vertical gradients in water chemistry and age, remain poorly defined. As part of the U.S. Geological Survey’s National Water-Quality Assessment Program, water samples from nested, short-screen monitoring wells installed in the northern High Plains aquifer were analyzed for major ions, nutrients, trace elements, dissolved organic carbon, pesticides, stable and radioactive isotopes, dissolved gases, and other parameters to evaluate vertical gradients in water chemistry and age in the aquifer. Chemical data and tritium and radiocarbon ages show that water in the aquifer was chemically and temporally stratified in the study area, with a relatively thin zone of recently recharged water (less than 50 years) near the water table overlying a thicker zone of older water (1,800 to 15,600 radiocarbon years). In areas where irrigated agriculture was an important land use, the recently recharged ground water was characterized by elevated concentrations of major ions and nitrate and the detection of pesticide compounds. Below the zone of agricultural influence, major-ion concentrations exhibited small increases with depth and distance along flow paths because of rock/water interactions. The concentration increases were accounted for primarily by dissolved calcium, sodium, bicarbonate, sulfate, and silica. In general, the chemistry of ground water throughout the aquifer was of high quality. None of the approximately 90 chemical constituents analyzed in each sample exceeded primary drinking-water standards.Mass-balance models indicate that changes in groundwater chemistry along flow paths in the aquifer can be accounted for by small amounts of feldspar and calcite dissolution; goethite

Experimental Rock-on-Rock Abrasive Wear Under Aqueous Conditions: its Role in Subglacial Abrasion

Science.gov (United States)

Rutter, E. H.; Lee, A. G.

2003-12-01

We have determined experimentally the rate of abrasive wear of rock on rock for a range of rock types as a function of normal stress and shear displacement. Unlike abrasive wear in fault zones, where wear products accumulate as a thickening gouge zone, in our experiments wear particles were removed by flowing water. The experiments are thus directly pertinent to one of the most important processes in subglacial erosion, and to some extent in river incision. Wear was produced between rotating discs machined from rock samples and measured from the progressive approach of the disc axes towards each other under various levels of normal load. Shear displacements of several km were produced. Optical and scanning electron microscopy were used to study the worn rock surfaces, and particle size distributions in wear products were characterized using a laser particle size analyzer. Rock types studied were sandstones of various porosities and cement characteristics, schists and a granite. In all cases abrasion rate decreased logarithmically with displacement by up to 2 orders of magnitude until a steady state was approached, but only after at least 1 km displacement. The more porous, less-well cemented rocks wore fastest. Amount of abrasion could be characterized quantitatively using an exponentially decaying plus a steady-state term. Wear rate increased non-linearly with normal contact stress, apparently to an asymptote defined by the unconfined compressive strength. Microstructural study showed that the well-cemented and/or lowest porosity rocks wore by progressive abrasion of grains without plucking, whereas whole grains were plucked out of weakly-cemented and/or more porous rocks. This difference in behavior was reflected in wear-product particle size distributions. Where whole-grain plucking was possible, wear products were dominated by particles of the original grain size rather than finer rock flour. Comparison of our results to glacier basal abrasive wear estimated

Rare earth elements and uranium in groundwater under influence of distinct aquifers in Campinas, SP, Brazil; Elementos terras raras e uranio em aguas subterraneas sob influencia de aquiferos distintos em Campinas (SP)

Energy Technology Data Exchange (ETDEWEB)

Bulia, Isabella Longhi; Enzweiler, Jacinta, E-mail: isabellalonghi@ige.unicamp.br, E-mail: jacinta@ige.unicamp.br [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Instituto de Geociencias

2015-07-01

The composition of groundwaters results mainly from water-rock reactions within aquifers. Among the various constituents of water, the rare earth elements (REE) and uranium can serve as tracers of geochemical processes and hydrological flow paths. The main objective of this study was to associate the chemical composition of groundwaters extracted from three distinct aquifer systems (crystalline, diabase and sedimentary) with that of the respective hosts rocks. The area of the study is located at the campus of University of Campinas (Campinas, SP). Samples of groundwater collected from four tubular wells were used to determine physicochemical parameters, major ions and trace elements, including the REE. The results confirm that the water of two wells (IMECC and IB) is predominantly influenced by the crystalline and diabase aquifers, while the other two (GM and FEF) by the sedimentary aquifer. Both the individual and normalized REE values of the four wells are distinct from each other, pointing to the heterogeneity of the local geology. The uranium concentration in the water of one well (GM) exceeded the guideline value for this element in drinking water. The U probably results from the oxidative dissolution of U-bearing phases in the sedimentary aquifer. However, the hydrochemical modeling indicated Ca{sub 2}UO{sub 2}(CO{sub 3}){sub 3} and CaUO{sub 2}(CO{sub 3}){sub 2}{sup 2-} as the major U dissolved species, which are considered non-toxic and non-bioavailable according to literature data. (author)

A study on spalling in soft rock under low confining stress

International Nuclear Information System (INIS)

Tomita, Atsunori; Ebina, Takahito; Toida, Masaru; Shirasagi, Suguru; Kishida, Kiyoshi; Adachi, Toshihisa

2007-01-01

The aim of this paper is to study spalling in soft rock excavation. During the test cavern excavation of the radioactive waste disposal project, spalling occurred. Therefore, it has been estimated performing the stress path simulation test and measuring the induced stress. In the stress path simulation test, the splitting failure has been confirmed under low confining stress. In the induced stress measurements, the rock mass around the cavern has shifted to the low radial confinement. Hence, spalling in soft rock was interpreted by the splitting failure caused by the induced stress under low confinement. Furthermore, the failure zone was proved by the numerical analysis applying the criterion based on the results of the above triaxial test. (author)

Conceptual model of fractured aquifer of Uranium Deposit in Caetité, Bahia: implications for groundwater flow

International Nuclear Information System (INIS)

Silva, Liliane Ferreira da

2015-01-01

The studied area is represented by the uraniferous district of Lagoa Real, located in the center-south of Bahia State, Brazil. The region is set in a semiarid climate context, with hot and dry weather parameters, with hydric deficit along all months of the year and high aridity index. Rural population is affected on drought periods since small agriculture and animal rearing are the main economic activities which are vulnerable in dry seasons. Groundwater represents the main supply source considering that most surface water sources are temporary and only exhibit flow in rainy periods. The main aquifer system present on the region is fractured, and the presence of groundwater flow occurs through the discontinuities of the rock considering that the rock mass corresponds to the set formed by the rock matrix and all its discontinuities (fractures, foliations, discordance, etc). In this sense, the main purpose of this Master Dissertation was to develop a conceptual model for the aquifer system, through the geotechnical characterization of discontinuities, once these structures allow the secondary porosity of the medium. Hydrochemical data hand out as complement for physical characterization for the behavioral interpretation of the aquifer. The aquifer system is unconfined, however, presents points of stagnation of flow forming compartments without communication with the surrounding areas. According to the International Society of Rock Mechanics ISRM method, which consist on qualitative and quantitative characterization of discontinuities of rock mass scanlines were constructed, systematically, describing, the following structure parameters: attitude, spacing, persistence, openness, infilling and roughness. From the results analysis it could be concluded that the aquifer system is composed of three discontinuities sets: one set which dips to NE, second set dipping to SW-W-NW and the last set sub-horizontal. The first and second sets are responsible for the aquifer

Searching for an Acidic Aquifer in the Rio Tinto Basin: First Geobiology Results of MARTE Project

Science.gov (United States)

Fernandez-Remolar, D. C.; Prieto-Ballesteros, O.; Stoker, C.

2004-01-01

Among the conceivable modern habitats to be explored for searching life on Mars are those potentially developed underground. Subsurface habitats are currently environments that, under certain physicochemical circumstances, have high thermal and hydrochemical stability [1, 2]. In planets like Mars lacking an atmospheric shield, such systems are obviously protected against radiation, which strongly alters the structure of biological macromolecules. Low porosity but fractured aquifers currently emplaced inside ancient volcano/sedimentary and hydrothermal systems act as excellent habitats [3] due to its thermal and geochemical properties. In these aquifers the temperature is controlled by a thermal balance between conduction and advection processes, which are driven by the rock composition, geological structure, water turnover of aquifers and heat generation from geothermal processes or chemical reactions [4]. Moreover, microbial communities based on chemolithotrophy can obtain energy by the oxidation of metallic ores that are currently associated to these environments. Such a community core may sustain a trophic web composed of non-autotrophic forms like heterotrophic bacteria, fungi and protozoa.

Accounting for the Decreasing Reaction Potential of Heterogeneous Aquifers in a Stochastic Framework of Aquifer-Scale Reactive Transport

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Loschko, Matthias; Wöhling, Thomas; Rudolph, David L.; Cirpka, Olaf A.

2018-01-01

Many groundwater contaminants react with components of the aquifer matrix, causing a depletion of the aquifer's reactivity with time. We discuss conceptual simplifications of reactive transport that allow the implementation of a decreasing reaction potential in reactive-transport simulations in chemically and hydraulically heterogeneous aquifers without relying on a fully explicit description. We replace spatial coordinates by travel-times and use the concept of relative reactivity, which represents the reaction-partner supply from the matrix relative to a reference. Microorganisms facilitating the reactions are not explicitly modeled. Solute mixing is neglected. Streamlines, obtained by particle tracking, are discretized in travel-time increments with variable content of reaction partners in the matrix. As exemplary reactive system, we consider aerobic respiration and denitrification with simplified reaction equations: Dissolved oxygen undergoes conditional zero-order decay, nitrate follows first-order decay, which is inhibited in the presence of dissolved oxygen. Both reactions deplete the bioavailable organic carbon of the matrix, which in turn determines the relative reactivity. These simplifications reduce the computational effort, facilitating stochastic simulations of reactive transport on the aquifer scale. In a one-dimensional test case with a more detailed description of the reactions, we derive a potential relationship between the bioavailable organic-carbon content and the relative reactivity. In a three-dimensional steady-state test case, we use the simplified model to calculate the decreasing denitrification potential of an artificial aquifer over 200 years in an ensemble of 200 members. We demonstrate that the uncertainty in predicting the nitrate breakthrough in a heterogeneous aquifer decreases with increasing scale of observation.

Uranium series geochemistry in aquifers: quantification of transport mechanisms of uranium and daughter products: the chalk aquifer (Champagne, France)

International Nuclear Information System (INIS)

Hubert, A.

2005-09-01

With the increase of contaminant flux of radionuclides in surface environment (soil, river, aquifer...), there is a need to understand and model the processes that control the distribution of uranium and its daughter products during transport within aquifers. We have used U-series disequilibria as an analogue for the transport of uranium and its daughter products in aquifer to understand such mechanisms. The measurements of uranium ( 234 U et 238 U), thorium ( 230 Th et 232 Th), 226 Ra and 222 Rn isotopes in the solid and liquid phases of the chalk aquifer in Champagne (East of France) allows us to understand the processes responsible for fractionation within the uranium decay chain. Fractionations are induced by physical and chemical properties of the elements (leaching, adsorption) but also by radioactive properties (recoil effect during α-decay). For the first time a comprehensive sampling of the solid phase has been performed, allowing quantifying mechanisms responsible for the long term evolution of the aquifer. A non steady state 1D model has been developed which takes into account leaching, adsorption processes as well as radioactive filiation and α-recoil effect. Retardation coefficients have been calculated for uranium, thorium and radium. The aquifer is characterised by a double porosity, and the contribution of fracture and matrix porosity on the water/rock interaction processes has been estimated. (author)

Predicting the denitrification capacity of sandy aquifers from shorter-term incubation experiments and sediment properties

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W. Eschenbach

2013-02-01

Full Text Available Knowledge about the spatial variability of denitrification rates and the lifetime of denitrification in nitrate-contaminated aquifers is crucial to predict the development of groundwater quality. Therefore, regression models were derived to estimate the measured cumulative denitrification of aquifer sediments after one year of incubation from initial denitrification rates and several sediment parameters, namely total sulphur, total organic carbon, extractable sulphate, extractable dissolved organic carbon, hot water soluble organic carbon and potassium permanganate labile organic carbon.

For this purpose, we incubated aquifer material from two sandy Pleistocene aquifers in Northern Germany under anaerobic conditions in the laboratory using the ¹⁵N tracer technique. The measured amount of denitrification ranged from 0.19 to 56.2 mg N kg⁻¹ yr⁻¹. The laboratory incubations exhibited high differences between non-sulphidic and sulphidic aquifer material in both aquifers with respect to all investigated sediment parameters. Denitrification rates and the estimated lifetime of denitrification were higher in the sulphidic samples. For these samples, the cumulative denitrification measured during one year of incubation (D_cum(365 exhibited distinct linear regressions with the stock of reduced compounds in the investigated aquifer samples. D_cum(365 was predictable from sediment variables within a range of uncertainty of 0.5 to 2 (calculated D_cum(365/measured D_cum(365 for aquifer material with a D_cum(365 > 20 mg N kg⁻¹ yr⁻¹. Predictions were poor for samples with lower D_cum(365, such as samples from the NO₃⁻ bearing groundwater zone, which includes the non-sulphidic samples, from the upper part of both aquifers where denitrification is not sufficient to

Benzene dynamics and biodegradation in alluvial aquifers affected by river fluctuations.

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Batlle-Aguilar, J; Morasch, B; Hunkeler, D; Brouyère, S

2014-01-01

The spatial distribution and temporal dynamics of a benzene plume in an alluvial aquifer strongly affected by river fluctuations was studied. Benzene concentrations, aquifer geochemistry datasets, past river morphology, and benzene degradation rates estimated in situ using stable carbon isotope enrichment were analyzed in concert with aquifer heterogeneity and river fluctuations. Geochemistry data demonstrated that benzene biodegradation was on-going under sulfate reducing conditions. Long-term monitoring of hydraulic heads and characterization of the alluvial aquifer formed the basis of a detailed modeled image of aquifer heterogeneity. Hydraulic conductivity was found to strongly correlate with benzene degradation, indicating that low hydraulic conductivity areas are capable of sustaining benzene anaerobic biodegradation provided the electron acceptor (SO4 (2-) ) does not become rate limiting. Modeling results demonstrated that the groundwater flux direction is reversed on annual basis when the river level rises up to 2 m, thereby forcing the infiltration of oxygenated surface water into the aquifer. The mobilization state of metal trace elements such as Zn, Cd, and As present in the aquifer predominantly depended on the strong potential gradient within the plume. However, infiltration of oxygenated water was found to trigger a change from strongly reducing to oxic conditions near the river, causing mobilization of previously immobile metal species and vice versa. MNA appears to be an appropriate remediation strategy in this type of dynamic environment provided that aquifer characterization and targeted monitoring of redox conditions are adequate and electron acceptors remain available until concentrations of toxic compounds reduce to acceptable levels. © 2013, National Ground Water Association.

Land-use change and managed aquifer recharge effects on the hydrogeochemistry of two contrasting atoll island aquifers, Roi-Namur Island, Republic of the Marshall Islands

Science.gov (United States)

Hejazian, Mehrdad; Gurdak, Jason J.; Swarzenski, Peter W.; Odigie, Kingsley; Storlazzi, Curt

2017-01-01

Freshwater resources on low-lying atoll islands are highly vulnerable to climate change and sea-level rise. In addition to rainwater catchment, groundwater in the freshwater lens is a critically important water resource on many atoll islands, especially during drought. Although many atolls have high annual rainfall rates, dense natural vegetation and high evapotranspiration rates can limit recharge to the freshwater lens. Here we evaluate the effects of land-use/land-cover change and managed aquifer recharge on the hydrogeochemistry and supply of groundwater on Roi-Namur Island, Republic of the Marshall Islands. Roi-Namur is an artificially conjoined island that has similar hydrogeology on the Roi and Namur lobes, but has contrasting land-use/land-cover and managed aquifer recharge only on Roi. Vegetation removal and managed aquifer recharge operations have resulted in an estimated 8.6 x 105 m3 of potable groundwater in the freshwater lens on Roi, compared to only 1.6 x 104 m3 on Namur. We use groundwater samples from a suite of 33 vertically nested monitoring wells, statistical testing, and geochemical modeling using PHREEQC to show that the differences in land-use/land-cover and managed aquifer recharge on Roi and Namur have a statistically significant effect on several groundwater-quality parameters and the controlling geochemical processes. Results also indicate a seven-fold reduction in the dissolution of carbonate rock in the freshwater lens and overlying vadose zone of Roi compared to Namur. Mixing of seawater and the freshwater lens is a more dominant hydrogeochemical process on Roi because of the greater recharge and flushing of the aquifer with freshwater as compared to Namur. In contrast, equilibrium processes and dissolution-precipitation non-equilibrium reactions are more dominant on Namur because of the longer residence times relative to the rate of geochemical reactions. Findings from Roi-Namur Island support selective land-use/land-cover change and

The diffusivity of cesium, strontium, carbon and nickel in concrete and mixtures of sodium bentonite and crushed rock

International Nuclear Information System (INIS)

Muurinen, A.; Penttilae-Hiltunen, P.; Rantanen, J.

1986-07-01

The engineering barriers suggested to be used for the disposal of low and intermediate level wastes in Finland are concrete and crushed rock or mixtures of crushed rock and bentonite. In the repository the barriers are saturated by groundwater and radionuclides may be released by diffusion through the barries. For safety analysis, the mechanisms by which the nuclides migrate and corresponding parameters should be known. In this study diffusion measurements on different types of concrete and mixtures of sodium bentonite and crushed rock were carried out. Radioactive isotopes of cesium, strontium, carbon and nickel were used as tracers. The apparent diffusivities (Dsub(a)) were evaluated on the basis of the measurements. The apparent diffusivity of cesium in concretes was 10 -14 ...10 -15 m 2 /s. Strontium was mainly sorbed on cement where it diffuses slowly. Part of strontium propably penetrates in the rock ballast by diffusion. The diffusivities of carbon and nickel in the concrete was low. The upper limit was evaluated to be Dsub(a) -14 m 2 /s. The diffusivity of cesium in the mixtures of crushed rock and bentonite varies between 0.5x10 -12 and 7x10 -12 m 2 /s. Cesium was mainly sorbed on the rock. The diffusivity of strontium was 2x10 -11 ...2x10 -12 m 2 /s. Strontium was mainly sorbed on bentonite. The diffusion of the sorbed ions (surface diffusion) seems to be a additional migration mechanism in the case of cesium and strontium in the mixture of bentonite and crushed rock. The diffusivity of carbon in the mixtures of crushed rock and bentonite was 6x10 -11 ...4x10 -12 m 2 /s. No sorption was found in the case of carbon. The measured Dsub(a) of nickel in the mixtures of crushed rock and bentonite was 4x10 -14 ...2x10 -15 m 2 /s. The experimental arrangement was not, however, in the stationary state and the more correct values would propably be 10 -13 ...10 -14 m 2 /s. No surface diffusion was found in the case of nickel. (author)

Hydrogeochemical effects of groundwater mining of the Sierra de Crevillente Aquifer (Alicante, Spain)

Science.gov (United States)

Pulido-Bosch, A.; Morell, I.; Andreu, J. M.

1995-12-01

The groundwater mining of the Crevillente aquifer (southeastern Spain) has resulted in the progressive deterioration of water quality, with particularly significant increases in chloride, sulfate, and sodium. The possibility of a vertical hydrochemical zoning is deduced that would require examining the importance of the geometry and lithology (evaporitic materials) in the salinization process. The time of water-rock contact (residence time) and dilution by infiltration of rainwater also influences the hydrogeochemistry of the aquifer. The hydrochemical data are useful in defining the conceptual model of the aquifer, completely karstified with relative homogeneity.

Simulation of flow in the Edwards Aquifer, San Antonio region, Texas, and refinement of storage and flow concepts

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Maclay, Robert W.; Land, Larry F.

1988-01-01

The Edwards aquifer is a complexly faulted, carbonate aquifer lying within the Balcones fault zone of south-central Texas. The aquifer consists of thin- to massive-bedded limestone and dolomite, most of which is in the form of mudstones and wackestones. Well-developed secondary porosity has formed in association with former erosional surfaces within the carbonate rocks, within dolomitized-burrowed tidal and evaporitic deposits, and along inclined fractures to produce an aquifer with transmissivities greater than 100 ft2/s. The aquifer is recharged mainly by streamflow losses in the outcrop area of the Edwards aquifer and is discharged by major springs located at considerable distances, as much as 150 mi, from the areas of recharge and by wells. Ground-water flow within the Edwards aquifer of the San Antonio region was simulated to investigate concepts relating to the storage and flow characteristics. The concepts of major interest were the effects of barrier faults on flow direction, water levels, springflow, and storage within the aquifer. A general-purpose, finite-difference model, modified to provide the capability of representing barrier faults, was used to simulate ground-water flow and storage in the aquifer. The approach in model development was to conduct a series of simulations beginning with a simple representation of the aquifer framework and then proceeding to subsequent representations of increasing complexity. The simulations investigated the effects of complex geologic structures and of significant changes in transmissivity, anisotropy, and storage coefficient. Initial values of transmissivity, anisotropy, and storage coefficient were estimated based on concepts developed in previous studies. Results of the simulations confirmed the original estimates of transmissivity values (greater than 100 square feet/s) in the confined zone of the aquifer between San Antonio and Comal Springs. A storage coefficient of 0.05 in the unconfined zone of the aquifer

Self-Healing Characteristics of Damaged Rock Salt under Different Healing Conditions

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Lin Li

2013-08-01

Full Text Available Salt deposits are commonly regarded as ideal hosts for geologic energy reservoirs. Underground cavern construction-induced damage in salt is reduced by self-healing. Thus, studying the influencing factors on such healing processes is important. This research uses ultrasonic technology to monitor the longitudinal wave velocity variations of stress-damaged rock salts during self-recovery experiments under different recovery conditions. The influences of stress-induced initial damage, temperature, humidity, and oil on the self-recovery of damaged rock salts are analyzed. The wave velocity values of the damaged rock salts increase rapidly during the first 200 h of recovery, and the values gradually increase toward stabilization after 600 h. The recovery of damaged rock salts is subjected to higher initial damage stress. Water is important in damage recovery. The increase in temperature improves damage recovery when water is abundant, but hinders recovery when water evaporates. The presence of residual hydraulic oil blocks the inter-granular role of water and restrains the recovery under triaxial compression. The results indicate that rock salt damage recovery is related to the damage degree, pore pressure, temperature, humidity, and presence of oil due to the sealing integrity of the jacket material.

Role of primary substrate composition on microbial community structure and function and trace organic chemical attenuation in managed aquifer recharge systems

KAUST Repository

Li, Dong; Alidina, Mazahirali; Drewes, Jorg

2014-01-01

This study was performed to reveal the microbial community characteristics in simulated managed aquifer recharge (MAR), a natural water treatment system, under different concentrations and compositions of biodegradable dissolved organic carbon (BDOC

Assessment of hydraulic properties of sedimentary and volcanic aquifer systems under arid conditions in the Republic of Djibouti (Horn of Africa)

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Jalludin, Mohamed; Razack, Moumtaz

The Republic of Djibouti (23,000 km2 500,000 inhabitants), located within the Horn of Africa, undergoes an arid climate with an average annual rainfall less than 150 mm. Water resources are provided up to 98% by groundwater. Two types of aquifers are encountered: volcanic and sedimentary aquifers. This paper focuses on the assessment of their hydraulic properties, which is necessary for future tasks regarding the management of these aquifers. To this end, a data base consisting of all available pumping test data obtained since the 1960s was compiled. Pumping tests have been interpreted to determine transmissivity. Solely for volcanic aquifers, transmissivity also has been estimated through an empirical relationship using specific capacity corrected for turbulent well losses. The transmissivity of each type of aquifer can span up to four orders of magnitude, pointing out their strong heterogeneity. For the various volcanic rocks, the younger the rock, the higher the transmissivity. The transmissivity of volcanic rocks has therefore decreased in the course of geological time. At present, a much better understanding of the hydraulic properties of these complex aquifers has been obtained, which should enable optimal management of their groundwater resources through the use of numerical modeling. La République de Djibouti (23,000 km2 500,000 habitants), située dans la Corne de l'Afrique, subit un climat aride avec une pluviométrie moyenne annuelle inférieure à 150 mm. Les ressources en eau sont fournies à plus de 98% par les eaux souterraines contenues dans des aquifères sédimentaires ou volcaniques. Cet article a pour objectif l'évaluation des propriétés hydrauliques de ces aquifères, étape indispensable pour entreprendre par la suite des études en vue de la gestion de ces aquifères. Une base rassemblant les données d'essais par pompage disponibles depuis les années Soixante a d'abord été établie. Les essais par pompage ont été interprétés pour

Sequence-Stratigraphic Analysis of the Regional Observation Monitoring Program (ROMP) 29A Test Corehole and Its Relation to Carbonate Porosity and Regional Transmissivity in the Floridan Aquifer System, Highlands County, Florida

Science.gov (United States)

Ward, W. C.; Cunningham, K.J.; Renken, R.A.; Wacker, M.A.; Carlson, J.I.

2003-01-01

An analysis was made to describe and interpret the lithology of a part of the Upper Floridan aquifer penetrated by the Regional Observation Monitoring Program (ROMP) 29A test corehole in Highlands County, Florida. This information was integrated into a one-dimensional hydrostratigraphic model that delineates candidate flow zones and confining units in the context of sequence stratigraphy. Results from this test corehole will serve as a starting point to build a robust three-dimensional sequence-stratigraphic framework of the Floridan aquifer system. The ROMP 29A test corehole penetrated the Avon Park Formation, Ocala Limestone, Suwannee Limestone, and Hawthorn Group of middle Eocene to Pliocene age. The part of the Avon Park Formation penetrated in the ROMP 29A test corehole contains two composite depositional sequences. A transgressive systems tract and a highstand systems tract were interpreted for the upper composite sequence; however, only a highstand systems tract was interpreted for the lower composite sequence of the deeper Avon Park stratigraphic section. The composite depositional sequences are composed of at least five high-frequency depositional sequences. These sequences contain high-frequency cycle sets that are an amalgamation of vertically stacked high-frequency cycles. Three types of high-frequency cycles have been identified in the Avon Park Formation: peritidal, shallow subtidal, and deeper subtidal high-frequency cycles. The vertical distribution of carbonate-rock diffuse flow zones within the Avon Park Formation is heterogeneous. Porous vuggy intervals are less than 10 feet, and most are much thinner. The volumetric arrangement of the diffuse flow zones shows that most occur in the highstand systems tract of the lower composite sequence of the Avon Park Formation as compared to the upper composite sequence, which contains both a backstepping transgressive systems tract and a prograding highstand systems tract. Although the porous and permeable

Conceptual understanding and groundwater quality of selected basin-fill aquifers in the Southwestern United States

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Thiros, Susan A.; Bexfield, Laura M.; Anning, David W.; Huntington, Jena M.

2010-01-01

the arid to semiarid climate, cultural and economic activities in the Southwest are particularly dependent on supplies of good-quality groundwater. Irrigation and public-supply withdrawals from basin-fill aquifers in the study area account for about one quarter of the total withdrawals from all aquifers in the United States.Many factors influence the quality of groundwater in the 15 case-study basins, but some common factors emerge from the basin summaries presented in this report. These factors include the chemical composition of the recharge water, consolidated rock geology and composition of aquifer materials derived from consolidated rock, and land and water use. The major water-quality issues in many of the developed case-study basins are increased concentrations of dissolved solids, nitrate, and VOCs in groundwater as a result of human activities.The information presented and the citations listed in this report serve as a resource for those interested in the groundwater-flow systems in the NAWQA case-study basins. The summaries of water-development history, hydrogeology, conceptual understanding of the groundwater system under both predevelopment and modern conditions, and effects of natural and human-related factors on groundwater quality presented in the sections on each basin also serve as a foundation for the synthesis and modeling phases of the SWPA regional study.

Managed aquifer recharge in weathered crystalline basement aquifers in India: Monitoring of the effect of tank infiltration on water quality over several monsoon events

Science.gov (United States)

Alazard, Marina; Boisson, Alexandre; Maréchal, Jean-Christophe; Dewandel, Benoît; Perrin, Jérôme; Pettenati, Marie; Picot-Colbeaux, Géraldine; Ahmed, Shakeel; Thiéry, Dominique; Kloppmann, Wolfram

2015-04-01

Managed aquifer recharge (MAR) structures like percolation tanks are considered by the Indian national and regional governments as major option for tackling declining groundwater levels due to overexploitation for irrigation purposes (Boisson et al., 2014). Their main purpose is to restore groundwater availability under strong climatic and anthropogenic pressure. Furthermore, MAR-induced dilution with fresh surface water is generally expected to improve groundwater quality with respect to both anthropogenic and geogenic contaminants (total mineralisation, nitrates, chlorides, sulphates and fluoride contents). The impact of a percolation tank on groundwater quality was investigated in a context that is typical for hydro-climatic and geological settings in southern and eastern India: fractured crystalline basement aquifers overlain by a weathering zone under semi-arid climate. Water level data and geochemical indicators (stable isotopes and major ions) were monitored for both groundwater and surface water, over several successive monsoon events. In case of high to very high water levels, the groundwater quality is globally improved. However, in a few cases, the quality of the groundwater can be negatively impacted due to leaching of salts under the tank, particularly during the first rain events of the monsoon. Geogenic fluoride contents in groundwater, induced by water-rock interaction and enhanced by recycling of agricultural return flow under paddy fields, is found to be relatively stable over the year. This finding points out that the underlying processes, mainly dissolution of F-bearing phases like fluorapatites combined with Ca/Na cation exchange and calcite precipitation, both limiting the possibility of F-removal via fluorite precipitation (Pettenati et al., 2013, 2014), are not impacted by the hydrological conditions. This work highlights the complexity of the recharge processes in crystalline aquifers, enhanced by the variability of hydrological conditions

Geohydrologic reconnaissance of the upper Potomac River basin

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Trainer, Frank W.; Watkins, Frank A.

1975-01-01

The upper Potomac River basin, in the central Appalachian region in Pennsylvania, Maryland, Virginia, and West Virginia, is a humid temperate region of diverse fractured rocks. Three geohydrologic terranes, which underlie large parts of the basin, are described in terms of their aquifer characteristics and of the magnitude and duration of their base runoff: (1) fractured rock having a thin regolith, (2) fractured rock having a thick regolith, and (3) carbonate rock. Crystalline rock in the mountainous part of the Blue Ridge province and shale with tight sandstone in the folded Appalachians are covered with thin regolith. Water is stored in and moves through fairly unmodified fractures. Average transmissivity (T) is estimated to be 150 feet squared per day, and average storage coefficient (S), 0.005. Base runoff declines rapidly from its high levels during spring and is poorly sustained during the summer season of high evapotranspiration. The rocks in this geohydrologic terrane are the least effective in the basin for the development of water supplies and as a source of dry-weather streamflow. Crystalline and sedimentary rocks in the Piedmont province and in the lowland part of the Blue Ridge province are covered with thick regolith. Water is stored in and moves through both the regolith and the underlying fractured rock. Estimated average values for aquifer characteristics are T, 200 feet squared per day, and S, 0.01. Base runoff is better sustained in this terrane than in the thin-regolith terrane and on the average .is about twice as great. Carbonate rock, in which fractures have been widened selectively by solution, especially near streams, has estimated average aquifer characteristics of T, 500 feet squared per day, and S, 0.03-0.04. This rock is the most effective in the basin in terms of water supply and base runoff. Where its fractures have not been widened by solution, the carbonate rock is a fractured-rock aquifer much like the noncarbonate rock. At low

Bedrock geology and hydrostratigraphy of the Edwards and Trinity aquifers within the Driftwood and Wimberley 7.5-minute quadrangles, Hays and Comal Counties, Texas

Science.gov (United States)

Clark, Allan K.; Morris, Robert R.

2017-11-16

The Edwards and Trinity aquifers are major sources of water in south-central Texas and are both classified as major aquifers by the State of Texas. The population in Hays and Comal Counties is rapidly growing, increasing demands on the area’s water resources. To help effectively manage the water resources in the area, refined maps and descriptions of the geologic structures and hydrostratigraphic units of the aquifers are needed. This report presents the detailed 1:24,000-scale bedrock hydrostratigraphic map as well as names and descriptions of the geologic and hydrostratigraphic units of the Driftwood and Wimberley 7.5-minute quadrangles in Hays and Comal Counties, Tex.Hydrostratigraphically, the rocks exposed in the study area represent a section of the upper confining unit to the Edwards aquifer, the Edwards aquifer, the upper zone of the Trinity aquifer, and the middle zone of the Trinity aquifer. In the study area, the Edwards aquifer is composed of the Georgetown Formation and the rocks forming the Edwards Group. The Trinity aquifer is composed of the rocks forming the Trinity Group. The Edwards and Trinity aquifers are karstic with high secondary porosity along bedding and fractures. The Del Rio Clay is a confining unit above the Edwards aquifer and does not supply appreciable amounts of water to wells in the study area.The hydrologic connection between the Edwards and Trinity aquifers and the various hydrostratigraphic units is complex because the aquifer system is a combination of the original Cretaceous depositional environment, bioturbation, primary and secondary porosity, diagenesis, and fracturing of the area from Miocene faulting. All of these factors have resulted in development of modified porosity, permeability, and transmissivity within and between the aquifers. Faulting produced highly fractured areas which allowed for rapid infiltration of water and subsequently formed solutionally enhanced fractures, bedding planes, channels, and caves that

Rocking motion of structures under earthquakes. Overturning of 2-DOF system

International Nuclear Information System (INIS)

Kobayashi, Koichi; Watanabe, Tetsuya; Tanaka, Kihachiro; Tomoda, Akinori

2011-01-01

In recent years, huge earthquakes happen, for example, The South Hyogo prefecture Earthquake in 1995, The Mid Niigata Prefecture Earthquake in 2004, The Iwate-Miyagi Nairiku Earthquake in 2008. In The Niigataken Chuetsu-oki Earthquake in 2007, hundreds of drums fell down and water spilled out. A lot of studies about rocking behavior of rigid body had been performed from 1960's. However, these studies were only for a specific condition of the structure size or input vibration characteristics. Therefore, generalizes fall condition for earthquake is required. This paper deals with the analytical and the experimental study of the rocking vibration of 1-DOF rocking system, 2-DOF vibration-rocking system and 2-DOF rocking system under earthquakes. In this study, the equation of motion for each rocking systems are developed. The numerical model of 2-DOF rocking system is evaluated by free rocking experiment. In this paper, 'Overturning Map' which can distinguish whether structures falls or not is proposed. The overturning map of each rocking systems excited by the artificial earthquake wave calculated from the design spectrum is shown. As the result, overturning condition of structures is clarified. (author)

Experimental Rock Deformation under micro-CT: ERDμ

Science.gov (United States)

Tisato, Nicola; Zhao, Qi; Biryukov, Anton; Grasselli, Giovanni

2015-04-01

Typically, the static elastic moduli of a rock differ from the corresponding dynamic rock-moduli. Such frequency-dependent characteristic, called modulus dispersion, implies also velocity dispersion (i.e. Vp- and Vs-dispersion). Velocity dispersion can be seen, in fact, as the result of a viscoelastic response of the geo-material to the externally imposed stress (e.g. seismic wave). Viscoelasticity can be conveniently expressed as attenuation (1/Q), which describes the loss of elastic energy for each stress cycle and comprises the measurement of the complex elastic modulus. As 1/Q at frequencies important seismic attribute as it can aid the subsurface imaging accuracy. For instance, the study of 1/Q is fundamental for the oil and gas industry as valuable natural resources, such as oil-sands or gas-shales, exhibit significant attenuation (e.g. 1/Q ~ 0.3 at 1 Hz), or for volcanic and earthquake related studies as fluids are often involved in those natural processes. In the last five years, employing the Broad Band Attenuation Vessel (BBAV), the attenuation of partially saturated rocks has been investigated along with the fluid pressure transient caused by a sudden increase of stress. In particular, those studies shed light on the relationships between 1/Q and i) saturation, ii) confining pressure, and iii) strain. The combination of laboratory and numerical results helped demonstrating that wave induced fluid flow (WIFF) on the mesoscopic scale is responsible for the large and frequency-dependent attenuation observed in the laboratory measurements of a partially saturated sandstone. However, these studies lay bare limitations: the behavior of attenuation as a function of i) the distribution of fluids in the pore space and ii) the role of dissolution-precipitation of new mineral phases are still unclear. For instance, when CO2 is injected in the Earth's crust to pursuit carbon sequestration it would be extremely useful understanding the impact of the gas-water-rock

Inverse modelling of aquifer parameters in basaltic rock with the help of pumping test method using MODFLOW software

Directory of Open Access Journals (Sweden)

Kanak Moharir

2017-11-01

The present study of estimation of aquifer factors such as transmissivity (T and storativity (S are vital for the evaluation of groundwater resources. There are several methods to estimate the accurate aquifer parameters (i.e. hydrograph analysis, pumping test, etc.. In initial days, these parameters are projected either by means of in-situ test or execution test on aquifer well samples carried in the laboratory. The simultaneous information on the hydraulic behavior of the well (borehole that provides on this method, the reservoir and the reservoir boundaries, are important for efficient aquifer and well data management and analysis. The most common in-situ test is pumping test performed on wells, which involves the measurement of the fall and increase of groundwater level with respect to time. The alteration in groundwater level (drawdown/recovery is caused due to pumping of water from the well. Theis (1935 was first to propose method to evaluate aquifer parameters from the pumping test on a bore well in a confined aquifer. It is essential to know the transmissivity (T = Kb, where b is the aquifer thickness; pumping flow rate, Q = TW (dh/dl flow through an aquifer and storativity (confined aquifer: S = bSs, unconfined: S = Sy, for the characterization of the aquifer parameters in an unknown area so as to predict the rate of drawdown of the groundwater table/potentiometric surface throughout the pumping test of an aquifer. The determination of aquifer's parameters is an important basis for groundwater resources evaluation, numerical simulation, development and protection as well as scientific management. For determining aquifer's parameters, pumping test is a main method. A case study shows that these techniques have been fast speed and high correctness. The results of parameter's determination are optimized so that it has important applied value for scientific research and geology engineering preparation.

Triaxial slide-hold-slide shear experiment of sedimentary rock under drain condition

International Nuclear Information System (INIS)

Kishida, Kiyoshi; Yano, Takao; Elsworth, Derek; Yasuhara, Hideaki; Nakashima, Shinichiro

2011-01-01

When discussing the mechanical and hydro-mechanical properties of rock masses under the long-term holding, the variation of rock structure and the change of shear band condition should be discussed in considering the effect of thermal and chemical influences. In this research, the triaxial shear experiment under drain condition was conducted through sedimentary rock, and in the residual stress state, the slide-hold-slide processes were applied to these triaxial experiments. The experiments were carried out in 3 kinds of confining conditions and 2 kinds of thermal conditions. Consequently, the healing phenomena can be observed and the shear strength recovery is also confirmed in process of the holding time. (author)

Water - rock interaction in different rock environments

International Nuclear Information System (INIS)

Lamminen, S.

1995-01-01

The study assesses the groundwater geochemistry and geological environment of 44 study sites for radioactive waste disposal. Initially, the study sites were divided by rock type into 5 groups: (1) acid - intermediate rocks, (2) mafic - ultramafic rocks, (3) gabbros, amphibolites and gneisses that contain calc-silicate (skarn) rocks, (4) carbonates and (5) sandstones. Separate assessments are made of acid - intermediate plutonic rocks and of a subgroup that comprises migmatites, granite and mica gneiss. These all belong to the group of acid - intermediate rocks. Within the mafic -ultramafic rock group, a subgroup that comprises mafic - ultramafic plutonic rocks, serpentinites, mafic - ultramafic volcanic rocks and volcanic - sedimentary schists is also evaluated separately. Bedrock groundwaters are classified by their concentration of total dissolved solids as fresh, brackish, saline, strongly saline and brine-class groundwaters. (75 refs., 24 figs., 3 tabs.)

Transport of barium through dolomite rocks under the presence of guar gum and brine salinities of hydraulic fracturing wastewater

Science.gov (United States)

Ebrahimi, P.; Vilcaez, J.

2017-12-01

Hydraulic fracturing wastewater (HFW) containing high concentrations of Ba, is commonly disposed into the deep saline aquifers. We investigate the effect of brine salinity, competing cations (Ca and Mg), and guar gum (most common fracturing viscosifier) on the sorption and transport of Ba through dolomite rocks. To this aim, we have conducted batch sorption and core-flooding experiments at both ambient (22°C) and deep subsurface (60°C) temperature conditions. The effect of mineral composition is assessed by comparing batch and core-flooding experimental results obtained with sandstone and dolomite rocks. Batch sorption experiments conducted using powdered dolomite rocks (500-600 µm particle size) revealed that Ba sorption on dolomite greatly decreases with increasing brine salinity (0 - 180,000 mg-NaCl/L), and that at brine salinities of HFW, chloro-complexation reactions between Ba and Cl ions and changes in pH (that results from dolomite dissolution) are the controlling factors of Ba sorption on dolomite. Organo-complexation reactions between Ba and guar gum, and competition of Ba with common cations (Ca and Mg) for hydration sites of dolomite, play a secondary role. This finding is in accordance with core-flooding experimental results, showing that the transport of Ba through synthetic dolomite rocks of high flow properties (25-29.6% porosity, 9.6-13.7 mD permeability), increases with increasing brine salinity (0-180,000 mg-NaCl/L), while the presence of guar gum (50-500 mg/L) does not affect the transport of Ba. On the other hand, core-flooding experiments conducted using natural dolomite core plugs (6.5-8.6% porosity, 0.06-0.3 mD permeability), indicates that guar gum can clog the pore throats of tight dolomite rocks retarding the transport of Ba. Results of our numerical simulation studies indicate that the mechanism of Ba sorption on dolomite can be represented by a sorption model that accounts for both surface complexation reactions on three distinct

Characterization of nanometer-scale porosity in reservoir carbonate rock by focused ion beam-scanning electron microscopy.

Science.gov (United States)

Bera, Bijoyendra; Gunda, Naga Siva Kumar; Mitra, Sushanta K; Vick, Douglas

2012-02-01

Sedimentary carbonate rocks are one of the principal porous structures in natural reservoirs of hydrocarbons such as crude oil and natural gas. Efficient hydrocarbon recovery requires an understanding of the carbonate pore structure, but the nature of sedimentary carbonate rock formation and the toughness of the material make proper analysis difficult. In this study, a novel preparation method was used on a dolomitic carbonate sample, and selected regions were then serially sectioned and imaged by focused ion beam-scanning electron microscopy. The resulting series of images were used to construct detailed three-dimensional representations of the microscopic pore spaces and analyze them quantitatively. We show for the first time the presence of nanometer-scale pores (50-300 nm) inside the solid dolomite matrix. We also show the degree of connectivity of these pores with micron-scale pores (2-5 μm) that were observed to further link with bulk pores outside the matrix.

An overview of geophysical technologies appropriate for characterization and monitoring at fractured-rock sites

Science.gov (United States)

Geophysical methods are used increasingly for characterization and monitoring at remediation sites in fractured-rock aquifers. The complex heterogeneity of fractured rock poses enormous challenges to groundwater remediation professionals, and new methods are needed to cost-effect...

Performance improvement of ionic surfactant flooding in carbonate rock samples by use of nanoparticles

Directory of Open Access Journals (Sweden)

Mohammad Ali Ahmadi

2016-07-01

Full Text Available Abstract Various surfactants have been used in upstream petroleum processes like chemical flooding. Ultimately, the performance of these surfactants depends on their ability to reduce the interfacial tension between oil and water. The surfactant concentration in the aqueous solution decreases owing to the loss of the surfactant on the rock surface in the injection process. The main objective of this paper is to inhibit the surfactant loss by means of adding nanoparticles. Sodium dodecyl sulfate and silica nanoparticles were used as ionic surfactant and nanoparticles in our experiments, respectively. AEROSIL® 816 and AEROSIL® 200 are hydrophobic and hydrophilic nanoparticles. To determine the adsorption loss of the surfactant onto rock samples, a conductivity approach was used. Real carbonate rock samples were used as the solid phase in adsorption experiments. It should be noted that the rock samples were water wet. This paper describes how equilibrium adsorption was investigated by examining adsorption behavior in a system of carbonate sample (solid phase and surfactant solution (aqueous phase. The initial surfactant and nanoparticle concentrations were 500–5000 and 500–2000 ppm, respectively. The rate of surfactant losses was extremely dependent on the concentration of the surfactant in the system, and the adsorption of the surfactant decreased with an increase in the nanoparticle concentration. Also, the hydrophilic nanoparticles are more effective than the hydrophobic nanoparticles.

Chemical Remagnetization of Jurassic Carbonates and a Primary Paleolatitude of Lower Cretaceous Volcaniclastic Rocks of the Tibetan Himalaya

Science.gov (United States)

Huang, W.; Van Hinsbergen, D. J. J.; Dekkers, M. J.; Garzanti, E.; Dupont Nivet, G.; Lippert, P. C.; Li, X.; Maffione, M.; Langereis, C. G.; Hu, X.; Guo, Z.; Kapp, P. A.

2014-12-01

Paleolatitudes for the Tibetan Himalaya Zone based on paleomagnetic inclinations provide kinematic constraints of the passive northern Indian margin and the extent of 'Greater India' before the India-Asia collision. Here, we present a paleomagnetic investigation of the Jurassic (carbonates) to Lower Cretaceous (volcaniclastic rocks) Wölong section of the Tibetan Himalaya in the Everest region. The carbonates yield positive fold tests, suggesting that the remanent magnetizations have a pre-folding origin. However, detailed paleomagnetic analyses, rock magnetic tests, end-member modeling of acquisition curves of isothermal remanent magnetization, and petrographic studies reveal that the magnetic carrier of the Jurassic carbonates is authigenic magnetite, whereas the dominant magnetic carrier of the Lower Cretaceous volcaniclastic rocks is detrital magnetite. We conclude that the Jurassic carbonates were remagnetized, whereas the Lower Cretaceous volcaniclastics retain a primary remanence. We hypothesize that remagnetization of the Jurassic carbonates was probably caused by the oxidation of early diagenetic pyrite to magnetite within the time interval at ~86-84 Ma during the latest Cretaceous Normal Superchron and earliest deposition of Cretaceous oceanic red beds in the Tibetan Himalaya. The remagnetization of the limestones prevents determining the size of 'Greater India' during Jurassic time. Instead, a paleolatitude of the Tibetan Himalaya of 23.8±2.1° S at ~86-84 Ma is suggested. This value is lower than the expected paleolatitude of India from apparent polar wander path (APWP). The volcaniclastic rocks with the primary remanence, however, yielded a Lower Cretaceous paleolatitude of Tibetan Himalaya of 55.5±3° S, fitting well with the APWP of India.

Quantification methods of Black Carbon: Comparison of Rock-Eval analysis with traditional methods

NARCIS (Netherlands)

Poot, A.; Quik, J.T.K.; Veld, H.; Koelmans, A.A.

2009-01-01

Black Carbon (BC) quantification methods are reviewed, including new Rock-Eval 6 data on BC reference materials. BC has been reported to have major impacts on climate, human health and environmental quality. Especially for risk assessment of persistent organic pollutants (POPs) it is important to

Rare Earth Element Concentrations and Fractionation Patterns Along Groundwater Flow Paths in Two Different Aquifer Types (i.e., Sand vs. Carbonate)

Science.gov (United States)

Johannesson, K. H.; Tang, J.

2003-12-01

Groundwater samples were collected in two different types of aquifer (i.e., Carrizo Sand Aquifer, Texas and Upper Floridan carbonate Aquifer, west-central Florida) to study the concentrations, fractionation, and speciation of rare earth elements (REE) along groundwater flow paths in each aquifer. Major solutes and dissolved organic carbon (DOC) were also measured in these groundwaters. The Carrizo Sand aquifer was sampled in October 2002 and June 2003, whereas, to date, we have only sampled the Floridan once (i.e., June 2003). The data reveal no significant seasonal differences in major solute and REE concentrations for the Carrizo. In Carrizo sand aquifer, groundwaters from relatively shallow wells (i.e., less than 167 m) in the recharge zone are chiefly Ca-Na-HCO3-Cl type waters. With flow down-gradient the groundwaters shift composition to the Na-HCO3 waters. pH and alkalinity initially decrease with flow away from the recharge zone before increasing again down-gradient. DOC is generally low (0.65 mg/L) along the flow path. REE concentrations are highest in groundwaters from the recharge zone (Nd 40.5 pmol/kg), and decrease substantially with flow down-gradient reaching relatively low and stable values (Nd 4.1-8.6 pmol/kg) roughly 10 km from the recharge zone. Generally, Carrizo groundwaters exhibit HREE-enriched shale-normalized patterns. The HREE enrichments are especially strong for waters from the recharge zone [(Yb/Nd)SN =1.7-5.6], whereas down-gradient (deep) groundwaters have flatter patterns [(Yb/Nd)SN =0.7-2.5]. All groundwaters have slightly positive Eu anomalies (Eu/Eu* 0.09-0.14) and negative Ce anomalies (Ce/Ce* -0.85 - -0.07). In the Upper Floridan Aquifer, Ca, Mg, SO4, and Cl concentrations generally increase along groundwater flow path, whereas pH and alkalinity generally decrease. DOC is higher (0.64 - 2.29 mg/L) than in the Carrizo and initially increases along the flow path and then decreases down-gradient. LREE (Nd) concentrations generally

Validating predictions of evolving porosity and permeability in carbonate reservoir rocks exposed to CO2-brine

Science.gov (United States)

Smith, M. M.; Hao, Y.; Carroll, S.

2017-12-01

Improving our ability to better forecast the extent and impact of changes in porosity and permeability due to CO2-brine-carbonate reservoir interactions should lower uncertainty in long-term geologic CO2 storage capacity estimates. We have developed a continuum-scale reactive transport model that simulates spatial and temporal changes to porosity, permeability, mineralogy, and fluid composition within carbonate rocks exposed to CO2 and brine at storage reservoir conditions. The model relies on two primary parameters to simulate brine-CO2-carbonate mineral reaction: kinetic rate constant(s), kmineral, for carbonate dissolution; and an exponential parameter, n, relating porosity change to resulting permeability. Experimental data collected from fifteen core-flooding experiments conducted on samples from the Weyburn (Saskatchewan, Canada) and Arbuckle (Kansas, USA) carbonate reservoirs were used to calibrate the reactive-transport model and constrain the useful range of k and n values. Here we present the results of our current efforts to validate this model and the use of these parameter values, by comparing predictions of extent and location of dissolution and the evolution of fluid permeability against our results from new core-flood experiments conducted on samples from the Duperow Formation (Montana, USA). Agreement between model predictions and experimental data increase our confidence that these parameter ranges need not be considered site-specific but may be applied (within reason) at various locations and reservoirs. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Karst in Wadi Bani Khalid, Oman

Science.gov (United States)

Abdelaziz, Ramadan

2017-04-01

There are several important in Oman. The main aquifer is surficial aquifer and fractured rocks. In fact, the geology of Oman is complex whichmake the hydraulic continuity of bedrock is limited and formaing localized aquifers. caves in Oman are varying types and length, size and geographic formations. Many caves and valleys founded in Oman. Wadi Bani Khalid hosts complex network of fractured rock. Karst in Wadi Bani Kalid made upof Limestone(Calcium, which is dissolve in water.A rain water pass through the rock it is erode the rock and form caves. The cave located in Miqil. The karst was formed in Calcium Carbonate rocks.

Biomarkers, carbon isotopic composition and source rock potentials of Awgu coals, middle Benue trough, Nigeria

Science.gov (United States)

Adedosu, Taofik A.; Sonibare, Oluwadayo O.; Tuo, Jincai; Ekundayo, Olusegun

2012-05-01

Coal and carbonaceous shale samples were collected from two boreholes (BH 94 and BH 120) in Awgu formation of Middle Benue Trough, Nigeria. Source rock potentials of the samples were studied using biomarkers and carbon isotopic composition. Biomarkers in the aliphatic fractions in the samples were studied using Gas Chromatography-Mass Spectrometry (GC-MS). The Carbon isotope analysis of individual n-alkanes in the aliphatic fraction was performed using Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometer (GC-IRMS). The abundance of hopanes, homohopanes (C31-C35), and C29 steranes in the samples indicate terrestrial plant, phytoplankton and cyanobacteria contributions to the organic matter that formed the coal. High (Pr/Ph) ratio (3.04-11.07) and isotopic distribution of individual alkanes showed that the samples consisted of mixed terrestrial/marine organic matter deposited under oxic condition in lacustrine-fluvial/deltaic depositional environment. The maturity parameters derived from biomarker distributions showed that the samples are in the main phase of oil window.

A Combined Radio- and Stable-Isotopic Study of a California Coastal Aquifer System

Directory of Open Access Journals (Sweden)

Michael Land

2013-04-01

Full Text Available Stable and radioactive tracers were utilized in concert to characterize geochemical processes in a complex coastal groundwater system and to provide constraints on the kinetics of rock/water interactions. Groundwater samples from wells within the Dominguez Gap region of Los Angeles County, California were analyzed for a suite of major cations (Na+, K+, Mg2+, Ca2+ and anions (Cl−, SO42−, silica, alkalinity, select trace elements (Ba, B, Sr, dissolved oxygen, stable isotopes of hydrogen (δD, oxygen (δ18O, dissolved inorganic carbon (δ13CDIC, and radioactive isotopes (3H, 222Rn and 223,224,226,228Ra. In the study area, groundwater may consist of a complex mixture of native groundwater, intruded seawater, non-native injected water, and oil-field brine water. In some wells, Cl− concentrations attained seawater-like values and in conjunction with isotopically heavier δ18O values, these tracers provide information on the extent of seawater intrusion and/or mixing with oil-field brines. Groundwater 3H above 1 tritium unit (TU was observed only in a few select wells close to the Dominguez Gap area and most other well groundwater was aged pre-1952. Based on an initial 14C value for the study site of 90 percent modern carbon (pmc, groundwater age estimates likely extend beyond 20 kyr before present and confirm deep circulation of some native groundwater through multiple aquifers. Enriched values of groundwater δ13CDIC in the absence of SO42− imply enhanced anaerobic microbial methanogenesis. While secular equilibrium was observed for 234U/238U (activity ratios ~1 in host matrices, strong isotopic fractionation in these groundwater samples can be used to obtain information of adsorption/desorption kinetics. Calculated Ra residence times are short, and the associated desorption rate constant is about three orders of magnitude slower than that of the adsorption rate constant. Combined stable- and radio-isotopic results provide unique insights

Investigation of block foundations resting on soil–rock and rock–rock media under coupled vibrations

Directory of Open Access Journals (Sweden)

Renuka Darshyamkar

2017-04-01

Full Text Available In the present study, the dynamic response of block foundations of different equivalent radius to mass (Ro/m ratios under coupled vibrations is investigated for various homogeneous and layered systems. The frequency-dependent stiffness and damping of foundation resting on homogeneous soils and rocks are determined using the half-space theory. The dynamic response characteristics of foundation resting on the layered system considering rock–rock combination are evaluated using finite element program with transmitting boundaries. Frequencies versus amplitude responses of block foundation are obtained for both translational and rotational motion. A new methodology is proposed for determination of dynamic response of block foundations resting on soil–rock and weathered rock–rock system in the form of equations and graphs. The variations of dimensionless natural frequency and dimensionless resonant amplitude with shear wave velocity ratio are investigated for different thicknesses of top soil/weathered rock layer. The dynamic behaviors of block foundations are also analyzed for different rock–rock systems by considering sandstone, shale and limestone underlain by basalt. The variations of stiffness, damping and amplitudes of block foundations with frequency are shown in this study for various rock–rock combinations. In the analysis, two resonant peaks are observed at two different frequencies for both translational and rotational motion. It is observed that the dimensionless resonant amplitudes decrease and natural frequencies increase with increase in shear wave velocity ratio. Finally, the parametric study is performed for block foundations with dimensions of 4 m × 3 m × 2 m and 8 m × 5 m × 2 m by using generalized graphs. The variations of natural frequency and peak displacement amplitude are also studied for different top layer thicknesses and eccentric moments.

Compound-specific C- and H-isotope compositions of enclosed organic matter in carbonate rocks: Implications for source identification of sedimentary organic matter and paleoenvironmental reconstruction

International Nuclear Information System (INIS)

Xiong Yongqiang; Wang Yanmei; Wang Yongquan; Xu Shiping

2007-01-01

The Bohai Bay Basin is one of the most important oil-producing provinces in China. Molecular organic geochemical characteristics of Lower Paleozoic source rocks in this area have been investigated by analyzing chemical and isotopic compositions of solvent extracts and acid-released organic matter from the Lower Paleozoic carbonate rocks in the Jiyang Sub-basin of the Bohai Bay Basin. The results indicate that enclosed organic matter in carbonate rocks has not been recognizably altered by post-depositional processes. Two end-member compositions are suggested for early organic matter trapped in the Lower Paleozoic carbonate rocks: (1) a source dominated by aquatic organisms and deposited in a relatively deep marine environment and (2) a relatively high saline, evaporative marine depositional environment. In contrast, chemical and isotopic compositions of solvent extracts from these Lower Paleozoic carbonate rocks are relatively complicated, not only inheriting original characteristics of their precursors, but also overprinted by various post-depositional alterations, such as thermal maturation, biodegradation and mixing. Therefore, the integration of both organic matter characteristics can provide more useful information on the origin of organic matter present in carbonate rocks and the environments of their deposition

Compound-specific C- and H-isotope compositions of enclosed organic matter in carbonate rocks: Implications for source identification of sedimentary organic matter and paleoenvironmental reconstruction

Energy Technology Data Exchange (ETDEWEB)

Xiong Yongqiang [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China)], E-mail: xiongyq@gig.ac.cn; Wang Yanmei; Wang Yongquan; Xu Shiping [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China)

2007-11-15

The Bohai Bay Basin is one of the most important oil-producing provinces in China. Molecular organic geochemical characteristics of Lower Paleozoic source rocks in this area have been investigated by analyzing chemical and isotopic compositions of solvent extracts and acid-released organic matter from the Lower Paleozoic carbonate rocks in the Jiyang Sub-basin of the Bohai Bay Basin. The results indicate that enclosed organic matter in carbonate rocks has not been recognizably altered by post-depositional processes. Two end-member compositions are suggested for early organic matter trapped in the Lower Paleozoic carbonate rocks: (1) a source dominated by aquatic organisms and deposited in a relatively deep marine environment and (2) a relatively high saline, evaporative marine depositional environment. In contrast, chemical and isotopic compositions of solvent extracts from these Lower Paleozoic carbonate rocks are relatively complicated, not only inheriting original characteristics of their precursors, but also overprinted by various post-depositional alterations, such as thermal maturation, biodegradation and mixing. Therefore, the integration of both organic matter characteristics can provide more useful information on the origin of organic matter present in carbonate rocks and the environments of their deposition.

Isotopic studies of beach rock carbonates from Konkan, central west coast of India

Digital Repository Service at National Institute of Oceanography (India)

Kumar, B.; Rajamanickam, G.V.; Gujar, A.R.

.7% (PDB) and delta sup(18)O signatures lie in a narrow range of +27.5 to +28.6% (SMOW), respectively. Isotopic data obtained in this study show that cementation of beach rock carbonates might have taken place in a shallow vadose zone. The large variations...

Ground-water-quality assessment of the Central Oklahoma Aquifer, Oklahoma: geochemical and geohydrologic investigations

Science.gov (United States)

Parkhurst, David L.; Christenson, Scott C.; Breit, George N.

1993-01-01

The National Water-Quality Assessment pilot project for the Central Oklahoma aquifer examined the chemical and isotopic composition of ground water, the abundances and textures of minerals in core samples, and water levels and hydraulic properties in the flow system to identify geochemical reactions occurring in the aquifer and rates and directions of ground-water flow. The aquifer underlies 3,000 square miles of central Oklahoma and consists of Permian red beds, including parts of the Permian Garber Sandstone, Wellington Formation, and Chase, Council Grove, and Admire Groups, and Quaternary alluvium and terrace deposits.In the part of the Garber Sandstone and Wellington Formation that is not confined by the Permian Hennessey Group, calcium, magnesium, and bicarbonate are the dominant ions in ground water; in the confined part of the Garber Sandstone and Wellington Formation and in the Chase, Council Grove, and Admire Groups, sodium and bicarbonate are the dominant ions in ground water. Nearly all of the Central Oklahoma aquifer has an oxic or post-oxic environment as indicated by the large dissolved concentrations of oxygen, nitrate, arsenic(V), chromium(VI), selenium(VI), vanadium, and uranium. Sulfidic and methanic environments are virtually absent.Petrographic textures indicate dolomite, calcite, sodic plagioclase, potassium feldspars, chlorite, rock fragments, and micas are dissolving, and iron oxides, manganese oxides, kaolinite, and quartz are precipitating. Variations in the quantity of exchangeable sodium in clays indicate that cation exchange is occurring within the aquifer. Gypsum may dissolve locally within the aquifer, as indicated by ground water with large concentra-tions of sulfate, but gypsum was not observed in core samples. Rainwater is not a major source for most elements in ground water, but evapotranspiration could cause rainwater to be a significant source of potassium, sulfate, phosphate and nitrogen species. Brines derived from seawater are

Range of engineering-geological properties for some carbonate rock complexes for Balkan peninsula

International Nuclear Information System (INIS)

Jovanovski, Milorad; Shpago, Azra; Peshevski, Igor

2010-01-01

The Carbonate Rock masses are a geological media with extremely complex states and properties, which has a certain influences on the mechanical and hydraulic behavior during construction and exploitation of engineering structures. Practical aspects of the problem analysis arise from the fact that the areas of Bosnia and Herzegovina, Macedonia and the entire Balkans is characterized by presence of wide areas covered with carbonate complexes, where large number of complex engineering structures have been, or shall be constructed in the future. In this context, their engineering-geological modeling is still a practical and scientific challenge. The analysis of engineering- geological properties is one of the main steps in forming of analytical and geotechnical models for complex rock structures. This article gives a data about the range for these properties, according to the results from an extensive investigation program. Some original correlations and testing results are given and they are compared with some published relations from the world. (Author)

Fingerprinting TCE in a bedrock aquifer using compound-specific isotope analysis.

Science.gov (United States)

Lojkasek-Lima, Paulo; Aravena, Ramon; Parker, Beth L; Cherry, John A

2012-01-01

A dual isotope approach based on compound-specific isotope analysis (CSIA) of carbon (C) and chlorine (Cl) was used to identify sources of persistent trichloroethylene (TCE) that caused the shut-down in 1994 of a municipal well in an extensive fractured dolostone aquifer beneath Guelph, Ontario. Several nearby industrial properties have known subsurface TCE contamination; however, only one has created a comprehensive monitoring network in the bedrock. The impacted municipal well and many monitoring wells were sampled for volatile organic compounds (VOCs), inorganic parameters, and CSIA. A wide range in isotope values was observed at the study site. The TCE varies between -35.6‰ and -21.8‰ and from 1.6‰ to 3.2‰ for δ(13) C and δ(37) Cl, respectively. In case of cis-1,2-dichloroethene, the isotope values range between -36.3‰ and -18.9‰ and from 2.4‰ to 4.7‰ for δ(13) C and δ(37) Cl, respectively. The dual isotope approach represented by a plot of δ(13) C vs. δ(37) Cl shows the municipal well samples grouped in a domain clearly separate from all other samples from the property with the comprehensive well network. The CSIA results collected under non-pumping and short-term pumping conditions thus indicate that this particular property, which has been studied intensively for several years, is not a substantial contributor of the TCE presently in the municipal well under non-pumping conditions. This case study demonstrates that CSIA signatures would have been useful much earlier in the quest to examine sources of the TCE in the municipal well if bedrock monitoring wells had been located at several depths beneath each of the potential TCE-contributing properties. Moreover, the CSIA results show that microbial reductive dechlorination of TCE occurs in some parts of the bedrock aquifer. At this site, the use of CSIA for C and Cl in combination with analyses of VOC and redox parameters proved to be important due to the complexity introduced by

Mechanisms of recharge in a fractured porous rock aquifer in a semi-arid region

Science.gov (United States)

Manna, Ferdinando; Walton, Kenneth M.; Cherry, John A.; Parker, Beth L.

2017-12-01

Eleven porewater profiles in rock core from an upland exposed sandstone vadose zone in southern California, with thickness varying between 10 and 62 m, were analyzed for chloride (Cl) concentration to examine recharge mechanisms, estimate travel times in the vadose zone, assess spatial and temporal variability of recharge, and determine effects of land use changes on recharge. As a function of their location and the local terrain, the profiles were classified into four groups reflecting the range of site characteristics. Century- to millennium-average recharge varied from 4 to 23 mm y-1, corresponding to different average Cl concentrations in the vadose zone and in groundwater, the contribution of diffuse flow (estimated at 80%) and preferential flow (20%) to the total recharge was quantified. This model of dual porosity recharge was tested by simulating transient Cl transport along a physically based narrow column using a discrete fracture-matrix numerical model. Using a new approach based on partitioning both water and Cl between matrix and fracture flow, porewater was dated and vertical displacement rates estimated to range in the sandstone matrix from 3 to 19 cm y-1. Moreover, the temporal variability of recharge was estimated and, along each profile, past recharge rates calculated based on the sequence of Cl concentrations in the vadose zone. Recharge rates increased at specific times coincident with historical changes in land use. The consistency between the timing of land use modifications and changes in Cl concentration and the match between observed and simulated Cl concentration values in the vadose zone provide confidence in porewater age estimates, travel times, recharge estimates, and reconstruction of recharge histories. This study represents an advancement of the application of the chloride mass balance method to simultaneously determine recharge mechanisms and reconstruct location-specific recharge histories in fractured porous rock aquifers. The

The integrated impacts of natural processes and human activities on groundwater salinization in the coastal aquifers of Beihai, southern China

Science.gov (United States)

Li, Qinghua; Zhang, Yanpeng; Chen, Wen; Yu, Shaowen

2018-03-01

Salinization in coastal aquifers is usually related to both seawater intrusion and water-rock interaction. The results of chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai, southern China. The concentrations of the major ions that dominate in seawater (Cl-, Na+, Ca2+, Mg2+ and SO4 2- ), as well as the isotopic content and ratios (2H, 18O, 87Sr/86Sr and 13C), suggest that the salinization occurring in the aquifer of the coastal plain is related to seawater and that the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization has occurred in an area that is significantly influenced by land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds are identified in the shallowest confined aquifer (I) in the middle of the area (site BBW2). Leakage from this polluted confined aquifer causes the salinization of groundwater in the underlying confined aquifer (II). At the coastal monitoring site (BBW3), confined aquifer I and lower confined aquifer II are heavily contaminated by seawater intrusion. The weak connectivity between the upper aquifers, and the seaward movement of freshwater, prevents saltwater from encroaching the deepest confined aquifer (III). A conceptual model is presented. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for the planning and sustainable management of groundwater resources in this region.

Compaction of granular carbonates under conditions relevant to diagenesis and fault sealing. Geologica Ultraiectina (332)

OpenAIRE

Zhang, X.

2010-01-01

Carbonate reservoir rocks contain more than 60% of the world’s oil reserves and 40% of its gas reserves. The evolution of the reservoir quality, i.e. their porosity and permeability, is for a large part controlled by compaction due to pressure solution (chemical compaction). Pressure solution also forms an efficient mechanism of fault sealing in carbonate rocks. Moreover, during hydrocarbons production, and after injection of CO2 into carbonate reservoirs, pressure solution may lead to vertic...

Effects of Land-Use Change and Managed Aquifer Recharge on Geochemical Reactions with Implications for Groundwater Quantity and Quality in Atoll Island Aquifers, Roi-Namur, Republic of the Marshall Islands

Science.gov (United States)

Hejazian, M.; Swarzenski, P. W.; Gurdak, J. J.; Odigie, K. O.; Storlazzi, C. D.

2015-12-01

This study compares the hydrogeochemistry of two contrasting atoll groundwater systems in Roi-Namur, Republic of the Marshall Islands. Roi-Namur houses a U.S. Department of Defense military installation and presents an ideal study location where a human impacted aquifer is co-located next to a natural aquifer as part of two artificially conjoined atoll islands. The hydrogeology and geochemistry of carbonate atoll aquifers has been well studied, particularly because of its small, well-defined hydrologic system that allows for relatively precise modeling. However, it is unknown how changes in land-use/land cover and managed aquifer recharge (MAR) alters natural geochemical processes in atoll aquifers. A better understanding of this has implications on groundwater quantity and quality, carbonate dissolution, and best aquifer management practices in the context of rising sea level and saltwater intrusion. Roi has been heavily modified to house military and civilian operations; here, lack of vegetation and managed recharge has increased the volume of potable groundwater and affected the geochemical processes in the freshwater lens and saltwater transition zone. Namur is heavily vegetated and the hydrogeology is indicative of a natural atoll island. A suite of monitoring wells were sampled across both island settings for major ions, nutrients, trace elements, DOC/DIC, δ13C and δ18O/2H isotopes. By modeling geochemical reactions using a conservative mixing approach, we measure deviations from expected reactions and compare the two contrasting settings using derived geochemical profiles through a wide salinity spectrum. Results indicate that groundwater on Namur is more heavily depleted in δ13C and has greater dissolved inorganic carbon, suggesting higher microbial oxidation and greater dissolution within the carbonate aquifer. This suggests MAR and reduction of vegetation makes the groundwater supply on atoll islands more resilient to sea level rise.

Strontium Isotopic Composition of Paleozoic Carbonate Rocks in the Nevada Test Site Vicinity, Clark, Lincoln, and Nye Counties, Nevada and Inyo County, California

International Nuclear Information System (INIS)

James B. Paces; Zell E. Peterman; Kiyoto Futa; Thomas A. Oliver; Brian D. Marshall.

2007-01-01

Ground water moving through permeable Paleozoic carbonate rocks represents the most likely pathway for migration of radioactive contaminants from nuclear weapons testing at the Nevada Test Site, Nye County, Nevada. The strontium isotopic composition (87Sr/86Sr) of ground water offers a useful means of testing hydrochemical models of regional flow involving advection and reaction. However, reaction models require knowledge of 87Sr/86Sr data for carbonate rock in the Nevada Test Site vicinity, which is scarce. To fill this data gap, samples of core or cuttings were selected from 22 boreholes at depth intervals from which water samples had been obtained previously around the Nevada Test Site at Yucca Flat, Frenchman Flat, Rainier Mesa, and Mercury Valley. Dilute acid leachates of these samples were analyzed for a suite of major- and trace-element concentrations (MgO, CaO, SiO2, Al2O3, MnO, Rb, Sr, Th, and U) as well as for 87Sr/86Sr. Also presented are unpublished analyses of 114 Paleozoic carbonate samples from outcrops, road cuts, or underground sites in the Funeral Mountains, Bare Mountain, Striped Hills, Specter Range, Spring Mountains, and ranges east of the Nevada Test Site measured in the early 1990's. These data originally were collected to evaluate the potential for economic mineral deposition at the potential high-level radioactive waste repository site at Yucca Mountain and adjacent areas (Peterman and others, 1994). Samples were analyzed for a suite of trace elements (Rb, Sr, Zr, Ba, La, and Ce) in bulk-rock powders, and 87Sr/86Sr in partial digestions of carbonate rock using dilute acid or total digestions of silicate-rich rocks. Pre-Tertiary core samples from two boreholes in the central or western part of the Nevada Test Site also were analyzed. Data are presented in tables and summarized in graphs; however, no attempt is made to interpret results with respect to ground-water flow paths in this report. Present-day 87Sr/86Sr values are compared to values

MICROBIAL DEGRADATION OF NITROGEN, OXYGEN AND SULFUR HETEROCYCLIC COMPOUNDS UNDER ANAEROBIC CONDITIONS: STUDIES WITH AQUIFER SAMPLES

Science.gov (United States)

The potential for anaerobic biodegradation of 12 heterocyclic model compounds was studied. Nine of the model compounds were biotransformed in aquifer slurries under sulfate-reducing or methanogenic conditions. The nitrogen and oxygen heterocyclic compounds were more susceptible t...

Factors affecting storage of compressed air in porous-rock reservoirs

Energy Technology Data Exchange (ETDEWEB)

Allen, R.D.; Doherty, T.J.; Erikson, R.L.; Wiles, L.E.

1983-05-01

This report documents a review and evaluation of the geotechnical aspects of porous medium (aquifer) storage. These aspects include geologic, petrologic, geophysical, hydrologic, and geochemical characteristics of porous rock masses and their interactions with compressed air energy storage (CAES) operations. The primary objective is to present criteria categories for the design and stability of CAES in porous media (aquifers). The document will also describe analytical, laboratory, and field-scale investigations that have been conducted.

Experimental research on rock fracture failure characteristics under liquid nitrogen cooling conditions

Science.gov (United States)

Gao, Feng; Cai, Chengzheng; Yang, Yugui

2018-06-01

As liquid nitrogen is injected into a wellbore as fracturing fluid, it can rapidly absorb heat from warmer rock and generate cryogenic condition in downhole region. This will alter the physical conditions of reservoir rocks and further affect rock failure characteristics. To investigate rock fracture failure characteristics under liquid nitrogen cooling conditions, the fracture features of four types of sandstones and one type of marble were tested on original samples (the sample without any treatment) and cryogenic samples (the samples just taken out from the liquid nitrogen), respectively. The differences between original samples and cryogenic samples in load-displacement curves, fracture toughness, energy evolution and the crack density of ruptured samples were compared and analyzed. The results showed that at elastic deformation stage, cryogenic samples presented less plastic deformation and more obvious brittle failure characteristics than original ones. The average fracture toughness of cryogenic samples was 10.47%-158.33% greater than that of original ones, indicating that the mechanical strength of rocks used were enhanced under cooling conditions. When the samples ruptured, the cryogenic ones were required to absorb more energy and reserve more elastic energy. In general, the fracture degree of cryogenic samples was higher than that of original ones. As the samples were entirely fractured, the crack density of cryogenic samples was about 536.67% at most larger than that of original ones. This indicated that under liquid nitrogen cooling conditions, the stimulation reservoir volume is expected to be improved during fracturing. This work could provide a reference to the research on the mechanical properties and fracture failure of rock during liquid nitrogen fracturing.