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Sample records for underground support vi

  1. 76 FR 56982 - Announcement of Federal Underground Injection Control (UIC) Class VI Program for Carbon Dioxide (CO2

    Science.gov (United States)

    2011-09-15

    ...-9465-1] Announcement of Federal Underground Injection Control (UIC) Class VI Program for Carbon Dioxide... Injection Control (UIC) Class VI Program for Carbon Dioxide (CO 2 ) Geologic Sequestration (GS) Wells under... highlighted in the ``Report of the Interagency Task Force on Carbon Capture and Storage'' (August 2010), it is...

  2. Method of treating non-supporting underground formations

    International Nuclear Information System (INIS)

    Anderson, B.W.; Trotty, K.D.

    1977-01-01

    Method of treating non-supporting underground formations, through which passes a borehole, aimed at preventing the transport of sand particles from the formation into the borehole during conveyance of liquids. (orig./RW) [de

  3. Industrial hygiene support of underground operations at the Nevada Test Site

    International Nuclear Information System (INIS)

    Porter, P.F.

    1992-01-01

    The Industrial Hygiene Section of the Health Protection Department provides industrial hygiene support of underground operations at the Nevada Test Site. This report describes support operations and summarizes the industrial hygiene data collected from July 31, 1989 through June 30, 1991. Air quality data were collected by means of personnel sampling by active and passive techniques using various kinds of industrial hygiene instrumentation and through localized and general area monitoring. The data collected were used to evaluate underground air quality and quantity requirements; evaluate worker exposures to a variety of air contaminants; determine the applicability and effectiveness of personal protective equipment

  4. A Comparison of underground opening support design methods in jointed rock mass

    International Nuclear Information System (INIS)

    Gharavi, M.; Shafiezadeh, N.

    2008-01-01

    It is of great importance to consider long-term stability of rock mass around the openings of underground structure. during design, construction and operation of the said structures in rock. In this context. three methods namely. empirical. analytical and numerical have been applied to design and analyze the stability of underground infrastructure at the Siah Bisheh Pumping Storage Hydro-Electric Power Project in Iran. The geological and geotechnical data utilized in this article were selected and based on the preliminary studies of this project. In the initial stages of design. it was recommended that, two methods of rock mass classification Q and rock mass rating should be utilized for the support system of the underground cavern. Next, based on the structural instability, the support system was adjusted by the analytical method. The performance of the recommended support system was reviewed by the comparison of the ground response curve and rock support interactions with surrounding rock mass, using FEST03 software. Moreover, for further assessment of the realistic rock mass behavior and support system, the numerical modeling was performed utilizing FEST03 software. Finally both the analytical and numerical methods were compared, to obtain satisfactory results complimenting each other

  5. Remediation of Cr(VI) contaminated soil using long-duration sodium thiosulfate supported by micro–nano networks

    International Nuclear Information System (INIS)

    He, Lulu; Wang, Min; Zhang, Guilong; Qiu, Guannan; Cai, Dongqing; Wu, Zhengyan; Zhang, Xin

    2015-01-01

    Highlights: • This work aims to develop a long-duration remediation agent (LRA). • LRA was obtained using Na 2 S 2 O 3 supported by attapulgite (ATP) micro–nano networks. • ATP micro–nano networks was induced by high-energy electron beam irradiation. • LRA can effectively control the migration of Cr(VI) and reducing Cr(VI) to Cr(III). • LRA displayed high performance on the remediation of heavy metal contaminated soil. - Abstract: In this work, a long-duration remediation agent (LRA) on hexavalent chromium (Cr(VI)) was developed using sodium thiosulfate (ST) supported by attapulgite (ATP) micro–nano networks induced through high-energy electron beam (HEEB) irradiation. The ATP networks could effectively reduce the leaching amount of Cr(VI) in soil. More importantly, the ATP networks could significantly control the leaching behavior of ST, and then prolong the duration and increase the reduction efficiency of ST on Cr(VI). As a result, LRA displayed high performance on controlling the migration of Cr(VI) and reducing Cr(VI) to Cr(III). Additionally, pot experiment indicated that LRA could effectively decrease the absorbed amount of Cr(VI) in corn, and reduce the inhibition effect of Cr(VI) on the growth of corn. Therefore, this work could provide a facile approach to remediate the Cr(VI)-contaminated soil and lower the harmful effect of Cr(VI) on crop

  6. Remediation of Cr(VI) contaminated soil using long-duration sodium thiosulfate supported by micro–nano networks

    Energy Technology Data Exchange (ETDEWEB)

    He, Lulu [School of Life Sciences, Anhui Agricultural University, Hefei 230036 (China); Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Wang, Min; Zhang, Guilong [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Bioenergy Forest Research Center of State Forestry Administration, Hefei 230031 (China); Qiu, Guannan [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Cai, Dongqing, E-mail: dqcai@ipp.ac.cn [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Bioenergy Forest Research Center of State Forestry Administration, Hefei 230031 (China); Wu, Zhengyan, E-mail: zywu@ipp.ac.cn [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Bioenergy Forest Research Center of State Forestry Administration, Hefei 230031 (China); Zhang, Xin, E-mail: xinzhang@ahau.edu.cn [School of Life Sciences, Anhui Agricultural University, Hefei 230036 (China)

    2015-08-30

    Highlights: • This work aims to develop a long-duration remediation agent (LRA). • LRA was obtained using Na{sub 2}S{sub 2}O{sub 3} supported by attapulgite (ATP) micro–nano networks. • ATP micro–nano networks was induced by high-energy electron beam irradiation. • LRA can effectively control the migration of Cr(VI) and reducing Cr(VI) to Cr(III). • LRA displayed high performance on the remediation of heavy metal contaminated soil. - Abstract: In this work, a long-duration remediation agent (LRA) on hexavalent chromium (Cr(VI)) was developed using sodium thiosulfate (ST) supported by attapulgite (ATP) micro–nano networks induced through high-energy electron beam (HEEB) irradiation. The ATP networks could effectively reduce the leaching amount of Cr(VI) in soil. More importantly, the ATP networks could significantly control the leaching behavior of ST, and then prolong the duration and increase the reduction efficiency of ST on Cr(VI). As a result, LRA displayed high performance on controlling the migration of Cr(VI) and reducing Cr(VI) to Cr(III). Additionally, pot experiment indicated that LRA could effectively decrease the absorbed amount of Cr(VI) in corn, and reduce the inhibition effect of Cr(VI) on the growth of corn. Therefore, this work could provide a facile approach to remediate the Cr(VI)-contaminated soil and lower the harmful effect of Cr(VI) on crop.

  7. Creep behaviour of a polymer-based underground support liner

    Science.gov (United States)

    Guner, Dogukan; Ozturk, Hasan

    2017-09-01

    All underground excavations (tunnels, mines, caverns, etc.) need a form of support to ensure that excavations remain safe and stable for the designed service lifetime. In the last decade, a new support material, thin spray-on liner (TSL) has started to take place of traditional underground surface supports of bolts and shotcrete. TSLs are generally cement, latex, polymer-based and also reactive or non-reactive, multi-component materials applied to the rock surface with a layer of few millimeter thickness. They have the advantages of low volume, logistics, rapid application and low operating cost. The majority of current TSLs are two-part products that are mixed on site before spraying onto excavation rock surfaces. Contrary to the traditional brittle supports, the high plastic behaviour of TSLs make them to distribute the loads on larger lining area. In literature, there is a very limited information exist on the creep behavior of TSLs. In this study, the creep behavior of a polymer-based TSL was investigated. For this purpose, 7-day cured dogbone TSL specimens were tested under room temperature and humidity conditions according to ASTM-D2990 creep testing standard. A range of dead weights (80, 60, 40, and 20 % of the tensile strength) were applied up to 1500 hours. As a result of this study, the time-dependent strain behavior of a TSL was presented for different constant load conditions. Moreover, a new equation was derived to estimate tensile failure time of the TSL for a given loading condition. If the tensile stress acting on the TSL is known, the effective permanent support time of the TSL can be estimated by the proposed relationship.

  8. Removal of hexavalent chromium [Cr(VI)] from aqueous solutions by the diatomite-supported/unsupported magnetite nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Yuan Peng, E-mail: yuanpeng@gig.ac.cn [Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Liu Dong; Fan Mingde; Yang Dan [Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Graduate School of Chinese Academy of Sciences, Beijing 100039 (China); Zhu Runliang; Ge Fei [College of Chemical Engineering, Xiangtan University, Xiangtan 411105 (China); Zhu Jianxi; He Hongping [Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China)

    2010-01-15

    Diatomite-supported/unsupported magnetite nanoparticles were prepared by co-precipitation and hydrosol methods, and characterized by X-ray diffraction, nitrogen adsorption, elemental analysis, differential scanning calorimetry, transmission electron microscopy and X-ray photoelectron spectroscopy. The average sizes of the unsupported and supported magnetite nanoparticles are around 25 and 15 nm, respectively. The supported magnetite nanoparticles exist on the surface or inside the pores of diatom shells, with better dispersing and less coaggregation than the unsupported ones. The uptake of hexavalent chromium [Cr(VI)] on the synthesized magnetite nanoparticles was mainly governed by a physico-chemical process, which included an electrostatic attraction followed by a redox process in which Cr(VI) was reduced into trivalent chromium [Cr(III)]. The adsorption of Cr(VI) was highly pH-dependent and the kinetics of the adsorption followed a pseudo-second-order model. The adsorption data of diatomite-supported/unsupported magnetite fit well with the Langmuir isotherm equation. The supported magnetite showed a better adsorption capacity per unit mass of magnetite than unsupported magnetite, and was more thermally stable than their unsupported counterparts. These results indicate that the diatomite-supported/unsupported magnetite nanoparticles are readily prepared, enabling promising applications for the removal of Cr(VI) from aqueous solution.

  9. Removal of hexavalent chromium [Cr(VI)] from aqueous solutions by the diatomite-supported/unsupported magnetite nanoparticles.

    Science.gov (United States)

    Yuan, Peng; Liu, Dong; Fan, Mingde; Yang, Dan; Zhu, Runliang; Ge, Fei; Zhu, JianXi; He, Hongping

    2010-01-15

    Diatomite-supported/unsupported magnetite nanoparticles were prepared by co-precipitation and hydrosol methods, and characterized by X-ray diffraction, nitrogen adsorption, elemental analysis, differential scanning calorimetry, transmission electron microscopy and X-ray photoelectron spectroscopy. The average sizes of the unsupported and supported magnetite nanoparticles are around 25 and 15 nm, respectively. The supported magnetite nanoparticles exist on the surface or inside the pores of diatom shells, with better dispersing and less coaggregation than the unsupported ones. The uptake of hexavalent chromium [Cr(VI)] on the synthesized magnetite nanoparticles was mainly governed by a physico-chemical process, which included an electrostatic attraction followed by a redox process in which Cr(VI) was reduced into trivalent chromium [Cr(III)]. The adsorption of Cr(VI) was highly pH-dependent and the kinetics of the adsorption followed a pseudo-second-order model. The adsorption data of diatomite-supported/unsupported magnetite fit well with the Langmuir isotherm equation. The supported magnetite showed a better adsorption capacity per unit mass of magnetite than unsupported magnetite, and was more thermally stable than their unsupported counterparts. These results indicate that the diatomite-supported/unsupported magnetite nanoparticles are readily prepared, enabling promising applications for the removal of Cr(VI) from aqueous solution.

  10. A research on the excavation, support, and environment control of large scale underground space

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Pil Chong; Kwon, Kwang Soo; Jeong, So Keul [Korea Institute of Geology Mining and Materials, Taejon (Korea, Republic of)

    1995-12-01

    With the growing necessity of the underground space due to the deficiency of above-ground space, the size and shape of underground structures tend to be complex and diverse. This complexity and variety force the development of new techniques for rock mass classification, excavation and supporting of underground space, monitoring and control of underground environment. All these techniques should be applied together to make the underground space comfortable. To achieve this, efforts have been made on 5 different areas; research on the underground space design and stability analysis, research on the techniques for excavation of rock by controlled blasting, research on the development of monitoring system to forecast the rock behaviour of underground space, research on the environment inspection system in closed space, and research on dynamic analysis of the airflow and environmental control in the large geos-spaces. The 5 main achievements are improvement of the existing structure analysis program(EXCRACK) to consider the deformation and failure characteristics of rock joints, development of new blasting design (SK-cut), prediction of ground vibration through the newly proposed wave propagation equation, development and In-Situ application of rock mass deformation monitoring system and data acquisition software, and trial manufacture of the environment inspection system in closed space. Should these techniques be applied to the development of underground space, prevention of industrial disaster, cut down of construction cost, domestication of monitoring system, improvement of tunnel stability, curtailment of royalty, upgrade of domestic technologies will be brought forth. (Abstract Truncated)

  11. Underground Layout Configuration

    International Nuclear Information System (INIS)

    A. Linden

    2003-01-01

    The purpose of this analysis was to develop an underground layout to support the license application (LA) design effort. In addition, the analysis will be used as the technical basis for the underground layout general arrangement drawings

  12. Microbial Precipitation of Cr(III)-Hydroxide and Se(0) Nanoparticles During Anoxic Bioreduction of Cr(VI)- and Se(VI)-Contaminated Water.

    Science.gov (United States)

    Kim, Yumi; Oh, Jong-Min; Roh, Yul

    2017-04-01

    This study examined the microbial precipitations of Cr(III)-hydroxide and Se(0) nanoparticles during anoxic bioreductions of Cr(VI) and Se(VI) using metal-reducing bacteria enriched from groundwater. Metal-reducing bacteria enriched from groundwater at the Korea Atomic Energy Research Institute (KAERI) Underground Research Tunnel (KURT), Daejeon, S. Korea were used. Metal reduction and precipitation experiments with the metal-reducing bacteria were conducted using Cr(VI)- and Se(VI)-contaminated water and glucose as a carbon source under an anaerobic environment at room temperature. XRD, SEM-EDX, and TEM-EDX analyses were used to characterize the mineralogy, crystal structure, chemistry, shape, and size distribution of the precipitates. The metal-reducing bacteria reduced Cr(VI) of potassium chromate (K₂CrO₄) to Cr(III) of chromium hydroxide [Cr(OH)3], and Se(VI) of sodium selenate (Na₂SeO₄) to selenium Se(0), with changes of color and turbidity. XRD, SEM-EDX, and TEM-EDX analyses revealed that the chromium hydroxide [Cr(OH)₃] was formed extracellularly with nanoparticles of 20–30 nm in size, and elemental selenium Se(0) nanoparticles had a sphere shape of 50–250 nm in size. These results show that metal-reducing bacteria in groundwater can aid or accelerate precipitation of heavy metals such as Cr(VI) and Se(VI) via bioreduction processes under anoxic environments. These results may also be useful for the recovery of Cr and Se nanoparticles in natural environments.

  13. Underground Storage Tanks in Iowa

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — Underground storage tank (UST) sites which store petroleum in Iowa. Includes sites which have been reported to DNR, and have active or removed underground storage...

  14. Design study of underground facility of the Underground Research Laboratory

    International Nuclear Information System (INIS)

    Hibiya, Keisuke; Akiyoshi, Kenji; Ishizuka, Mineo; Anezaki, Susumu

    1998-03-01

    Geoscientific research program to study deep geological environment has been performed by Power Reactor and Nuclear Fuel Development Corporation (PNC). This research is supported by 'Long-Term Program for Research, Development and Utilization of Nuclear Energy'. An Underground Research Laboratory is planned to be constructed at Shoma-sama Hora in the research area belonging to PNC. A wide range of geoscientific research and development activities which have been previously studied at the Tono Area is planned in the laboratory. The Underground Research Laboratory is consisted of Surface Laboratory and Underground Research Facility located from the surface down to depth between several hundreds and 1,000 meters. Based on the results of design study in last year, the design study performed in this year is to investigate the followings in advance of studies for basic design and practical design: concept, design procedure, design flow and total layout. As a study for the concept of the underground facility, items required for the facility are investigated and factors to design the primary form of the underground facility are extracted. Continuously, design methods for the vault and the underground facility are summarized. Furthermore, design procedures of the extracted factors are summarized and total layout is studied considering the results to be obtained from the laboratory. (author)

  15. Well-Dispersed Nanoscale Zero-Valent Iron Supported in Macroporous Silica Foams: Synthesis, Characterization, and Performance in Cr(VI Removal

    Directory of Open Access Journals (Sweden)

    Chaoxia Zhao

    2017-01-01

    Full Text Available Well-dispersed nanoscale zero-valent iron (NZVI supported inside the pores of macroporous silica foams (MOSF composites (Mx-NZVI has been prepared as the Cr(VI adsorbent by simply impregnating the MOSF matrix with ferric chloride, followed by the chemical reduction with NaHB4 in aqueous solution at ambient atmosphere. Through the support of MOSF, the reactivity and stability of NZVI are greatly improved. Transmission electron microscopy (TEM results show that NZVI particles are spatially well-dispersed with a typical core-shell structure and supported inside MOSF matrix. The N2 adsorption-desorption isotherms demonstrate that the Mx-NZVI composites can maintain the macroporous structure of MOSF and exhibit a considerable high surface area (503 m2·g−1. X-ray photoelectron spectroscopy (XPS and powder X-ray diffraction (XRD measurements confirm the core-shell structure of iron nanoparticles composed of a metallic Fe0 core and an Fe(II/Fe(III species shell. Batch experiments reveal that the removal efficiency of Cr(VI can reach 100% when the solution contains 15.0 mg·L−1 of Cr(VI at room temperature. In addition, the solution pH and the composites dosage can affect the removal efficiency of Cr(VI. The Langmuir isotherm is applicable to describe the removal process. The kinetic studies demonstrate that the removal of Cr(VI is consistent with pseudo-second-order kinetic model.

  16. Design study of the underground facilities, the Mizunami Underground Research Laboratory

    International Nuclear Information System (INIS)

    Ishizuka, Mineo; Noda, Masaru; Shiogama, Yukihiro; Adachi, Tetsuya

    1999-02-01

    Geoscientific research on the deep geological environment has been performed by Japan Nuclear Cycle Development Institute (JNC). This research is supported by the 'Long-Term Program for Research, Development and Utilization of Nuclear Energy'. The Mizunami Underground Research Laboratory (MIU) is planned to be constructed at the Shobasama-bora site belonging to JNC. A wide range of geoscientific research and development activities which have been previously performed in and around the Tono mine is planned to be expanded in the laboratory. The MIU consisted of surface and underground facilities excavated to a depth of about 1,000 meters. In this design study, the overall layout and basic design of the underground facility and the composition of the overall research program, includes the construction of the underground facility are studied. Based on the concept of the underground facility which have been developed in 1998, the research activities which will be performed in the MIU are selected and the overall research program is revised in this year. The basic construction method and the construction equipment are also estimated. (author)

  17. Design study of underground facility of the Mizunami Underground Research Laboratory

    International Nuclear Information System (INIS)

    Ishizuka, Mineo; Noda, Masaru; Shiogama, Yukihiro; Adachi, Tetsuya

    1999-02-01

    Geoscientific research on deep geological environment has been performed by Japan Nuclear Cycle Development Institute (JNC). This research is supported by the 'Long-Term Program for Research, Development and Utilization of Nuclear Energy'. The Mizunami Underground Research Laboratory (MIU) is planned to be constructed at Shobasama-bora site belonging to JNC. A wide range of geoscientific research and development activities which have been previously performed in and around the Tono mine is planned to be expanded in the laboratory. The MIU is consisted of surface and underground facilities down to the depth of about 1,000 meters. In this design study, the overall layout and basic design of the underground facility and the composition of the overall research program which includes the construction of the underground facility are studied. Based on the concept of the underground facility which have been developed last year, the research activities which will be performed in the MIU are selected and the overall research program is revised in this year. The basic construction method and the construction equipment are also estimated. (author)

  18. Comparative study on the mechanical mechanism of confined concrete supporting arches in underground engineering.

    Science.gov (United States)

    Lv, Zhijin; Qin, Qian; Jiang, Bei; Luan, Yingcheng; Yu, Hengchang

    2018-01-01

    In order to solve the supporting problem in underground engineering with high stress, square steel confined concrete (SQCC) supporting method is adopted to enhance the control on surrounding rocks, and the control effect is remarkable. The commonly used cross section shapes of confined concrete arch are square and circular. At present, designers have no consensus on which kind is more proper. To search for the answer, this paper makes an analysis on the mechanical properties of the two shapes of the cross-sections. A full-scale indoor comparative test was carried out on the commonly used straight-wall semi-circular SQCC arch and circular steel confined concrete arch (CCC arch). This test is based on self-developed full-scale test system for confined concrete arch. Our research, combining with the numerical analysis, shows: (1) SQCC arch is consistent with CCC arch in the deformation and failure mode. The largest damages parts are at the legs of both of them. (2) The SQCC arch's bearing capability is 1286.9 kN, and the CCC arch's ultimate bearing capability is 1072.4kN. Thus, the SQCC arch's bearing capability is 1.2 times that of the CCC arch. (3) The arches are subjected to combined compression and bending, bending moment is the main reason for the arch failure. The section moment of inertia of SQCC arch is 1.26 times of that of CCC arch, and the former is better than the latter in bending performance. The ultimate bearing capacity is positively correlated with the size of the moment of inertia. Based on the above research, the engineering suggestions are as follows: (1) To improve the bearing capacity of the arch, the cross-sectional shape of the chamber should be optimized and the arch bearing mode changed accordingly. (2) The key damaged positions, such as the arch leg, should be reinforced, optimizing the state of force on the arch. SQCC arches should be used for supporting in underground engineering, which is under stronger influence of the bending moment and

  19. Sanford Underground Research Facility - The United State's Deep Underground Research Facility

    Science.gov (United States)

    Vardiman, D.

    2012-12-01

    The 2.5 km deep Sanford Underground Research Facility (SURF) is managed by the South Dakota Science and Technology Authority (SDSTA) at the former Homestake Mine site in Lead, South Dakota. The US Department of Energy currently supports the development of the facility using a phased approach for underground deployment of experiments as they obtain an advanced design stage. The geology of the Sanford Laboratory site has been studied during the 125 years of operations at the Homestake Mine and more recently as part of the preliminary geotechnical site investigations for the NSF's Deep Underground Science and Engineering Laboratory project. The overall geology at DUSEL is a well-defined stratigraphic sequence of schist and phyllites. The three major Proterozoic units encountered in the underground consist of interbedded schist, metasediments, and amphibolite schist which are crosscut by Tertiary rhyolite dikes. Preliminary geotechnical site investigations included drift mapping, borehole drilling, borehole televiewing, in-situ stress analysis, laboratory analysis of core, mapping and laser scanning of new excavations, modeling and analysis of all geotechnical information. The investigation was focused upon the determination if the proposed site rock mass could support the world's largest (66 meter diameter) deep underground excavation. While the DUSEL project has subsequently been significantly modified, these data are still available to provide a baseline of the ground conditions which may be judiciously extrapolated throughout the entire Proterozoic rock assemblage for future excavations. Recommendations for facility instrumentation and monitoring were included in the preliminary design of the DUSEL project design and include; single and multiple point extensometers, tape extensometers and convergence measurements (pins), load cells and pressure cells, smart cables, inclinometers/Tiltmeters, Piezometers, thermistors, seismographs and accelerometers, scanners (laser

  20. Simultaneous adsorption and reduction of U(VI) on reduced graphene oxide-supported nanoscale zerovalent iron

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Yubing [School of Environment and Chemical Engineering, North China Electric Power University, Beijing 102206 (China); Institute of Plasma Physics, Chinese Academy of Science, P.O. Box 1126, Hefei, 230031 (China); Ding, Congcong; Cheng, Wencai [Institute of Plasma Physics, Chinese Academy of Science, P.O. Box 1126, Hefei, 230031 (China); Wang, Xiangke, E-mail: xkwang@ipp.ac.cn [School of Environment and Chemical Engineering, North China Electric Power University, Beijing 102206 (China); Faculty of Engineering, King Abdulaziz University, Jeddah 21589 (Saudi Arabia)

    2014-09-15

    Graphical abstract: - Highlights: • Sorption and in-situ reduction of U(VI) is observed. • The composites are more effective for U(VI) removal and solidification. • The inner-sphere surface complexes are observed. - Abstract: The reduced graphene oxide-supported nanoscale zero-valent iron (nZVI/rGO) composites were synthesized by chemical deposition method and were characterized by SEM, high resolution TEM, Raman and potentiometric acid-base titrations. The characteristic results showed that the nZVI nanoparticles can be uniformly dispersed on the surface of rGO. The removal of U(VI) on nZVI/rGO composites as a function of contact time, pH and U(VI) initial concentration was investigated by batch technique. The removal kinetics of U(VI) on nZVI and nZVI/rGO were well simulated by a pseudo-first-order kinetic model and pseudo-second-order kinetic model, respectively. The presence of rGO on nZVI nanoparticles increased the reaction rate and removal capacity of U(VI) significantly, which was attributed to the chemisorbed OH{sup −} groups of rGO and the massive enrichment of Fe{sup 2+} on rGO surface by XPS analysis. The XRD analysis revealed that the presence of rGO retarded the transformation of iron corrosion products from magnetite/maghemite to lepidocrocite. According to the fitting of EXAFS spectra, the U-C (at ∼2.9 Å) and U-Fe (at ∼3.2 Å) shells were observed, indicating the formation of inner-sphere surface complexes on nZVI/rGO composites. Therefore, the nZVI/rGO composites can be suitable as efficient materials for the in-situ remediation of uranium-contaminated groundwater in the environmental pollution management.

  1. Systems management support for ERCDC study of undergrounding and berm containment. Interim report. Preliminary program assessment and follow-on program development

    Energy Technology Data Exchange (ETDEWEB)

    1977-08-01

    Interim results of a study being conducted with respect to the technological aspects of the costs and benefits of underground nuclear power plant construction in direct support of the California Energy Commission's legislative mandate in this area are presented. The program was directed towards problem scoping, methodology evaluation, program definition and planning for subsequent, more detailed investigations of underground facility designs and their potential advantages and disadvantages. The material presented describes the results of (a) systems analyses which were conducted to determine logical requirements for determination of those elements of a nuclear power plant which should be constructed underground; (b) bounding estimates of incremental plant costs for a variety of underground concepts; (c) applicable prior experience in underground facility design and construction which could be used to identify potential sources of strength and weaknessees of underground nuclear power plants; (d) estimates of seismic environments for underground construction in California; (e) preliminary descriptions of underground reactor accident scenarios; (f) bounding estimates of the consequences of such accidents, in terms of comparisons of relative emissions of radioactivity with respect to similar accidents for surface-sited nuclear power plants and (g) results of analyses of several other important technological aspects of the problem. A description is also provided of the program development work performed to provide planning and criteria for subsequent investigations to determine: (a) definitive underground nuclear power plant designs and costs, and (b) estimates of accident consequences in underground nuclear power plants.

  2. Systems management support for ERCDC study of undergrounding and berm containment. Interim report. Preliminary program assessment and follow-on program development

    International Nuclear Information System (INIS)

    1977-08-01

    Interim results of a study being conducted with respect to the technological aspects of the costs and benefits of underground nuclear power plant construction in direct support of the California Energy Commission's legislative mandate in this area are presented. The program was directed towards problem scoping, methodology evaluation, program definition and planning for subsequent, more detailed investigations of underground facility designs and their potential advantages and disadvantages. The material presented describes the results of (a) systems analyses which were conducted to determine logical requirements for determination of those elements of a nuclear power plant which should be constructed underground; (b) bounding estimates of incremental plant costs for a variety of underground concepts; (c) applicable prior experience in underground facility design and construction which could be used to identify potential sources of strength and weaknessees of underground nuclear power plants; (d) estimates of seismic environments for underground construction in California; (e) preliminary descriptions of underground reactor accident scenarios; (f) bounding estimates of the consequences of such accidents, in terms of comparisons of relative emissions of radioactivity with respect to similar accidents for surface-sited nuclear power plants and (g) results of analyses of several other important technological aspects of the problem. A description is also provided of the program development work performed to provide planning and criteria for subsequent investigations to determine: (a) definitive underground nuclear power plant designs and costs, and (b) estimates of accident consequences in underground nuclear power plants

  3. Stability Evaluation on Surrounding Rocks of Underground Powerhouse Based on Microseismic Monitoring

    Directory of Open Access Journals (Sweden)

    Feng Dai

    2015-01-01

    Full Text Available To study the stability of underground powerhouse at Houziyan hydropower station during excavation, a microseismic monitoring system is adopted. Based on the space-time distribution characteristics of microseismic events during excavation of the main powerhouse, the correlation between microseismic events and blasting construction is established; and the microseismic clustering areas of the underground powerhouse are identified and delineated. The FLAC3D code is used to simulate the deformation of main powerhouse. The simulated deformation characteristics are consistent with that recorded by microseismic monitoring. Finally, the correlation between the macroscopic deformation of surrounding rock mass and microseismic activities is also revealed. The results show that multiple faults between 1# and 3# bus tunnels are activated during excavation of floors V and VI of the main powerhouse. The comprehensive method combining microseismic monitoring with numerical simulation as well as routine monitoring can provide an effective way to evaluate the surrounding rock mass stability of underground caverns.

  4. Underground risk management information systems

    Energy Technology Data Exchange (ETDEWEB)

    Matsuyama, S.; Inoue, M.; Sakai, T.

    2006-03-15

    JCOAL has conducted Joint Research on an Underground Communication and Risk Management Information System with CSIRO of Australia under a commissioned study project for the promotion of coal use starting in fiscal 2002. The goal of this research project is the establishment of a new Safety System focusing on the comprehensive risk management information system by the name of Nexsys. The main components of the system are the Ethernet type underground communication system that represents the data communication base, and the risk management information system that permits risk analysis in real-time and provides decision support based on the collected data. The Nexsys is an open system and is a core element of the underground monitoring system. Using a vast amount of underground data, it is capable of accommodating a wide range of functions that were not available in the past. Because of it, it is possible to construct an advanced underground safety system. 14 figs., 4 tabs.

  5. Underground openings in clay formations - Technical requirements on drifting technology and support systems for underground openings and their impact on retreat systems for the installation of engineered barriers

    International Nuclear Information System (INIS)

    Mischo, Helmut

    2012-01-01

    well as the development of adapted mining and excavation methods. Other fields which have to be considered are the special requirements on the suitable support technology and systems, the necessary support installation technology and also time requirements. Most of these special requirements can also be applied to the excavation of large-scale underground openings in mud-stone and can thus provide additional information for the design and development of underground repositories in clay formations. While most information can be transferred directly from commercial mining to the excavation of a repository, there are some areas where the available data only provides some sort of basic information. One example for this is the fact that the retreat from old workings and the sealing of drifts and tunnels already requires a highly developed and adopted technology in normal clay mining operations. For the successful long-term sealing of a repository, However, the immediate expansion of the pre-stressed clay after the extraction of support units and the simultaneously starting creeping requests an even more sophisticated dam construction technology for the refinement of radioactive waste to guarantee highest quality of the dam itself. This has to include, amongst other things, excellent bonding between construction material and host rock to ensure lowest possible leakage. This paper gives a detailed overview of the technical and technological methods currently used in clay mining and the significant differences to all other types of mining operations. For each stage of the technical construction process of underground openings in clay formations it highlights the information that could be transferred to the construction of this type of underground repositories. It also shows some of the areas where the database is still limited or incomplete and thus where further research and development work is necessary for a successful technical solution for radioactive waste confinement in

  6. Age of underground waters: isotopes contribution

    International Nuclear Information System (INIS)

    Chery, L.; Olive, Ph.

    2006-01-01

    Does water has an age? The age of underground waters can be the duration of their underground travel between their infiltration inside the ground and their captation at a spring or a drilled well. The isotopic geochemistry comes to the support of classical geochemistry to estimate these residence times. Radio-isotopes, like tritium for young waters or carbon 14 for old waters, are used as chronometers to interpret the recharge ways, the flow mechanisms and the residence times of underground waters. Their use is presented in this article with some theoretical recalls and some examples of application. (J.S.)

  7. Underground coal gasification with integrated carbon dioxide mitigation supports Bulgaria's low carbon energy supply

    Science.gov (United States)

    Nakaten, Natalie; Kempka, Thomas; Azzam, Rafig

    2013-04-01

    Underground coal gasification allows for the utilisation of coal reserves that are economically not exploitable due to complex geological boundary conditions. The present study investigates underground coal gasification as a potential economic approach for conversion of deep-seated coals into a high-calorific synthesis gas to support the Bulgarian energy system. Coupling of underground coal gasification providing synthesis gas to fuel a combined cycle gas turbine with carbon capture and storage is considered to provide substantial benefits in supporting the Bulgarian energy system with a competitive source of energy. In addition, underground voids originating from coal consumption increase the potential for geological storage of carbon dioxide resulting from the coupled process of energy production. Cost-effectiveness, energy consumption and carbon dioxide emissions of this coupled process are investigated by application of a techno-economic model specifically developed for that purpose. Capital (CAPEX) and operational expenditure (OPEX) are derived from calculations using six dynamic sub-models describing the entire coupled process and aiming at determination of the levelised costs of electricity generation (COE). The techno-economic model is embedded into an energy system-modelling framework to determine the potential integration of the introduced low carbon energy production technology into the Bulgarian energy system and its competitiveness at the energy market. For that purpose, boundary conditions resulting from geological settings as well as those determined by the Bulgarian energy system and its foreseeable future development have to be considered in the energy system-modelling framework. These tasks comprise integration of the present infrastructure of the Bulgarian energy production and transport system. Hereby, the knowledge on the existing power plant stock and its scheduled future development are of uttermost importance, since only phasing-out power

  8. Application of Long Expansion Rock Bolt Support in the Underground Mines of Legnica–Głogów Copper District

    Directory of Open Access Journals (Sweden)

    Skrzypkowski Krzysztof

    2017-09-01

    Full Text Available In the underground mines of the Legnica–Głogów Copper District (LGOM the main way to protect the room excavation is the use of a rock bolt support. For many years, it has proven to be an efficient security measure in excavations which met all safety standards and requirements. The article presents the consumption of the rock bolt support in the Mining Department “Polkowice–Sieroszowice” in the years 2010–2015 as well as the number of bolt supports that were used to secure the excavations. In addition, it shows the percentage of bolt supports that were used to conduct rebuilding work and cover the surface of exposed roofs. One of the factors contributing to the loss of the functionality of bolt supports is corrosion whose occurrence may lead directly to a reduction in the diameter of rock bolt support parts, in particular rods, bearing plates and nuts. The phenomenon of the corrosion of the bolt support and its elements in underground mining is an extremely common phenomenon due to the favorable conditions for its development in mines, namely high temperature and humidity, as well as the presence of highly aggressive water. This involves primarily a decrease in the capacity of bolt support construction, which entails the need for its strengthening, and often the need to perform the reconstruction of the excavation.

  9. vi and Vim Editors Pocket Reference Support for every text editing task

    CERN Document Server

    Robbins, Arnold

    2011-01-01

    Many Unix, Linux, and Mac OS X geeks enjoy using the powerful, platform-agnostic text editors vi and Vim, but there are far too many commands for anyone to remember. Author Arnold Robbins has chosen the most valuable commands for vi, Vim, and vi's main clones-vile, elvis, and nvi-and packed them into this easy-to-browse pocket reference. You'll find commands for all kinds of editing tasks, such as programming, modifying system files, and writing and marking up articles. This second edition includes: Command-line optionsvi commands and set optionsInput mode shortcutsSubstitution and regular e

  10. The WMO RA VI Regional Climate Centre Network - a support to users in Europe

    Science.gov (United States)

    Rösner, S.

    2012-04-01

    Climate, like weather, has no limits. Therefore the World Meteorological Organization (WMO), a specialized United Nations organization, has established a three-level infrastructure to better serve its member countries. This structure comprises Global Producing Centres for Long-range Forecasts (GPCs), Regional Climate Centres (RCCs) and National Meteorological or Hydrometeorological Services (NMHSs), in most cases representing their countries in WMO governance bodies. The elements of this infrastructure are also part of and contribute to the Global Framework for Climate Services (GFCS) agreed to be established by World Climate Conference 3 (WCC-3) and last year's Sixteenth World Meteorological Congress (WMO Cg-XVI). RCCs are the core element of this infrastructure at the regional level and are being establish in all WMO Regional Associations (RAs), i.e. Africa (RA I); Asia (II); South America (III); North America, Central America and the Caribbean (IV); South-West Pacific (V); Europe (VI). Addressing inter-regional areas of common interest like the Mediterranean or the Polar Regions may require inter-regional RCCs. For each region the RCCs follow a user driven approach with regard to governance and structure as well as products generated for the users in the respective region. However, there are common guidelines all RCCs do have to follow. This is to make sure that services are provided based on best scientific standards, are routinely and reliably generated and made available in an operational mode. These guidelines are being developed within WMO and make use of decade-long experience gained in the business of operational weather forecast. Based on the requirements of the 50 member countries of WMO RA VI it was agreed to establish the WMO RCC as a network of centres of excellence that create regional products including long-range forecasts that support regional and national climate activities, and thereby strengthen the capacity of WMO Members in the region to

  11. Development of supported noble metal catalyst for U(VI) to U(IV) reduction

    International Nuclear Information System (INIS)

    Tyagi, Deepak; Varma, Salil; Bhattacharyya, K.; Tripathi, A.K.; Bharadwaj, S.R.; Jain, V.K.; Sahu, Avinash; Vincent, Tessy; Jagatap, B.N.; Wattal, P.K.

    2015-01-01

    Uranium-plutonium separation is an essential step in the PUREX process employed in spent nuclear fuel reprocessing. This partitioning in the PUREX process is achieved by selective reduction of Pu(IV) to Pu(III) using uranous nitrate as reductant and hydrazine as stabilizer. Currently in our Indian reprocessing plants, the requirement of uranous nitrate is met by electrolytic reduction of uranyl nitrate. This process, however, suffers from a major drawback of incomplete reduction with a maximum conversion of ~ 60%. Catalytic reduction of U(VI) to U(IV) is being considered as one of the promising alternatives to the electro-reduction process due to fast kinetics and near total conversion. Various catalysts involving noble metals like platinum (Adams catalyst, Pt/Al 2 O 3 , Pt/SiO 2 etc.) have been reported for the reduction. Sustained activity and stability of the catalyst under harsh reaction conditions are still the issues that need to be resolved. We present here the results on zirconia supported noble metal catalyst that is developed in BARC for reduction of uranyl nitrate to uranous nitrate. Supported noble metal catalysts with varying metal loadings (0.5 - 2 wt%) were prepared via support precipitation and noble metal impregnation. The green catalysts were reduced either by chemical reduction using hydrazine hydrate or by heating in hydrogen flow or combination of both the steps. These catalysts were characterized by various techniques such as, XRD, SEM, TEM, N 2 adsorption and H 2 chemisorption. Performance of these catalysts was evaluated for U(VI) to U(IV) reduction with uranyl nitrate feed using hydrazine as reductant. The results with the most active catalyst are named as 'BARC-CAT', which was developed in our lab. (author)

  12. Study on the interaction of U(VI) species with natural organic matters in KURT groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Euo Chang; Baik, Min Hoon; Cho, Hye Ryun; Kim, Hee Kyung; Cha, Wansik [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2017-06-15

    The interaction of U(VI) (hexavalent uranium) species with natural organic matter (NOM) in KURT (KAERI Underground Research Tunnel) groundwater is investigated using a laser spectroscopic technique. The luminescence spectra of the NOM are observed in the ultraviolet and blue wavelength regions by irradiating a laser beam at 266 nm in groundwater. The luminescence spectra of U(VI) species in groundwater containing uranium concentrations of 0.034-0.788 mg·L-1 are measured in the green-colored wavelength region. The luminescence characteristics (peak wavelengths and lifetime) of U(VI) in the groundwater agree well with those of Ca{sub 2}UO{sub 2}(CO{sub 3}){sub 3}(aq) in a standard solution prepared in a laboratory. The luminescence intensities of U(VI) in the groundwater are weaker than those of Ca{sub 2}UO{sub 2}(CO{sub 3}){sub 3}(aq) in the standard solution at the same uranium concentrations. The luminescence intensities of Ca{sub 2}UO{sub 2}(CO{sub 3}){sub 3}(aq) in the standard solution mixed with the groundwater are also weaker than those of Ca{sub 2}UO{sub 2}(CO{sub 3}){sub 3}(aq) in the standard solution at the same uranium concentrations. These results can be ascribed to calcium-U(VI)-carbonate species interacting with NOM and forming non-radiative U(VI) complexes in groundwater.

  13. Phosphinic acid functionalized carbon nanotubes for sensitive and selective sensing of chromium(VI)

    Energy Technology Data Exchange (ETDEWEB)

    Deep, Akash, E-mail: dr.akashdeep@csio.res.in; Sharma, Amit L.; Tuteja, Satish K.; Paul, A.K.

    2014-08-15

    Highlights: • SWCNTs have been conjugated with bis(2,4,4-trimethylpentyl) phosphinic acid (PA/d). • SWCNT-PA/d adduct is demonstrated for electrochemical sensing of Cr(VI). • Linear response is obtained for 0.01–10 ppb Cr(VI). • Sensitivity and the limit of detection are 35 ± 4 nA/ppb and 0.01 ppb, respectively. • Proposed sensing of Cr(VI) is selective with respect to many other metals. - Abstract: Single-walled carbon nanotubes (SWCNTs) have been functionalized with a phosphinic acid derivative ‘bis(2,4,4-trimethylpentyl) phosphinic acid’ (PA/d). It has been achieved by treating the chlorinated SWCNTs with PA/d at 80 °C. Successful functionalization and different nanomaterial properties have been investigated by UV–vis–NIR, FTIR, Raman spectroscopy, AFM and FE-SEM. PA/d conjugated SWCNTs (CNT–PA) are dispersible in some common organic solvents, e.g. CH{sub 2}Cl{sub 2}, DMF, CHCl{sub 3}, and THF. The ‘CNT–PA’ complex was spin-casted on boron doped silicon wafer. Thus fabricated sensing electrode is demonstrated for sensitive and selective electrochemical sensing of chromium(VI) ions. A linear response is obtained over a wide range of Cr(VI) concentration (0.01–10 ppb). The sensor's sensitivity and the limit of detection are observed to be 35 ± 4 nA/ppb and 0.01 ppb, respectively. The practical utility of the proposed sensor is demonstrated by determining the Cr(VI) concentration in an industrial effluent sample and an underground water sample.

  14. Logistics background study: underground mining

    Energy Technology Data Exchange (ETDEWEB)

    Hanslovan, J. J.; Visovsky, R. G.

    1982-02-01

    Logistical functions that are normally associated with US underground coal mining are investigated and analyzed. These functions imply all activities and services that support the producing sections of the mine. The report provides a better understanding of how these functions impact coal production in terms of time, cost, and safety. Major underground logistics activities are analyzed and include: transportation and personnel, supplies and equipment; transportation of coal and rock; electrical distribution and communications systems; water handling; hydraulics; and ventilation systems. Recommended areas for future research are identified and prioritized.

  15. Application of Long Expansion Rock Bolt Support in the Underground Mines of Legnica-Głogów Copper District

    Science.gov (United States)

    Skrzypkowski, Krzysztof; Korzeniowski, Waldemar; Zagórski, Krzysztof; Dudek, Piotr

    2017-09-01

    In the underground mines of the Legnica-Głogów Copper District (LGOM) the main way to protect the room excavation is the use of a rock bolt support. For many years, it has proven to be an efficient security measure in excavations which met all safety standards and requirements. The article presents the consumption of the rock bolt support in the Mining Department "Polkowice-Sieroszowice" in the years 2010-2015 as well as the number of bolt supports that were used to secure the excavations. In addition, it shows the percentage of bolt supports that were used to conduct rebuilding work and cover the surface of exposed roofs. One of the factors contributing to the loss of the functionality of bolt supports is corrosion whose occurrence may lead directly to a reduction in the diameter of rock bolt support parts, in particular rods, bearing plates and nuts. The phenomenon of the corrosion of the bolt support and its elements in underground mining is an extremely common phenomenon due to the favorable conditions for its development in mines, namely high temperature and humidity, as well as the presence of highly aggressive water. This involves primarily a decrease in the capacity of bolt support construction, which entails the need for its strengthening, and often the need to perform the reconstruction of the excavation. The article presents an alternative for steel bearing plates, namely plates made using the spatial 3D printing technology. Prototype bearing plates were printed on a 3D printer Formiga P100 using the "Precymit" material. The used printing technology was SLS (Selective Laser Sintering), which is one of the most widely used technologies among all the methods of 3D printing for the short series production of the technical parts of the final product. The article presents the stress-strain characteristic of the long expansion connected rock bolt support OB25 with a length of 3.65 m. A rock bolt support longer than 2.6 m is an additional bolt support in

  16. Examination of Uranium(VI) Leaching During Ligand Promoted Dissolution of Waste Tank Sludge Surrogates

    Energy Technology Data Exchange (ETDEWEB)

    Powell, Brian; Powell, Brian A.; Rao, Linfeng; Nash, Kenneth. L.

    2008-06-10

    The dissolution of synthetic boehmite (?-AlOOH) by 1-hydroxyethane-1,1-diphosphonic acid (HEDPA) was examined in a series of batch adsorption/dissolution experiments. Additionally, the leaching behavior of {sup 233}U(VI) from boehmite was examined as a function of pH and HEDPA concentration. The results are discussed in terms of sludge washing procedures that may be utilized during underground tank waste remediation. In the pH range 4 to 10, complexation of Al(III) by HEDPA significantly enhanced dissolution of boehmite. This phenomenon was especially pronounced in the neutral pH region where the solubility of aluminum, in the absence of complexants, is limited by the formation of sparsely soluble aluminum hydroxides. At pH higher than 10, dissolution of synthetic boehmite was inhibited by HEDPA, likely due to sorption of Al(III):HEDPA complexes. Addition of HEDPA to equilibrated U(VI)-synthetic boehmite suspensions yielded an increase in the aqueous phase uranium concentration. Partitioning of uranium between the solid and aqueous phase is described in terms of U(VI):HEDPA speciation and dissolution of the boehmite solid phase.

  17. Modeling to Support Groundwater Contaminant Boundaries for the Shoal Underground Nuclear Test

    Energy Technology Data Exchange (ETDEWEB)

    K. Pohlmann; G. Pohll; J. Chapman; A. Hassan; R. Carroll; C. Shirley

    2004-03-01

    The purpose of this work is to characterize groundwater flow and contaminant transport at the Shoal underground nuclear test through numerical modeling using site-specific hydrologic data. The ultimate objective is the development of a contaminant boundary, a model-predicted perimeter defining the extent of radionuclide-contaminated groundwater from the underground test throughout 1,000 years at a prescribed level of confidence. This boundary will be developed using the numerical models described here, after they are approved for that purpose by DOE and NDEP.

  18. Modeling to Support Groundwater Contaminant Boundaries for the Shoal Underground Nuclear Test

    International Nuclear Information System (INIS)

    K. Pohlmann; G. Pohll; J. Chapman; A. Hassan; R. Carroll; C. Shirley

    2004-01-01

    The purpose of this work is to characterize groundwater flow and contaminant transport at the Shoal underground nuclear test through numerical modeling using site-specific hydrologic data. The ultimate objective is the development of a contaminant boundary, a model-predicted perimeter defining the extent of radionuclide-contaminated groundwater from the underground test throughout 1,000 years at a prescribed level of confidence. This boundary will be developed using the numerical models described here, after they are approved for that purpose by DOE and NDEP

  19. Research on application of mobile diesel equipment in underground mines (IV)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-01

    This research commenced in 1994 for the purpose of providing safety and environmental measures of underground mines where the mobile diesel equipment are operating. In this last research year, researches on filtering of diesel particulate matter, design of underground layout and disaster prevention have been carried out. 1) A study to reduce DPM(Diesel Particulate Matter) emission: It was known that water scrubber is only one practical way to reduce DPM emission as of now. There are several kinds of the sophisticated DPM filters, but it is not practical yet to be used in underground equipment due to the many adverse effects of the devices such as tremendous increase of SOx, NOx and back pressure etc. 2) Design of underground layout and their maintenance: Layout of underground structure has to be designed based on rock mechanical analysis and the concept of active support has to be adopted considering the large openings are requested to accommodate heavy duty diesel equipment in underground. Rock bolt and shotcrete will be the most applicable method to support such a large dimensional tunnels. 3) A study for disaster prevention in the case of the underground fire: There are two categories of possible disaster or hazard in workings where diesel equipment are operating. One is the disasters by exhaust pollutants and the other is the underground fire. (author). 35 refs., 27 tabs., 56 figs.

  20. Hydro-Metathesis of Long-Chain Olefin (1-decene) using Well-Defined Silica-Supported Tungsten (VI), Molybdenum (VI) and Tantalum (V) Catalysts

    KAUST Repository

    Saidi, Aya

    2016-11-01

    Nowadays, catalysis lies at the heart of economy growth mainly in the petroleum industry. Catalysis can offer real and potential solutions to the current challenges for a long-term sustainable energy, green chemistry, and environmental protection. In this context, one of the most important and future prosperity promising catalytic applications in the petrochemical field is hydrocarbons metathesis; it consists on the conversion of both renewable and non-petroleum fossil carbon sources to transportation fuels. Olefin metathesis has become one of the standard methodologies for constructing C-C bonds in many organic transformation reactions. This owed to the numerous types of metathesis reactions that have been developed, for example, enyne, ring-opening and closing, self and cross metathesis, etc. But the one step conversion of olefin to alkanes has not been studied much. Recently, only one such a work has been published for the hydro-metathesis of propylene by tantalum hydride supported on KCC-1 in dynamic reactor. With this knowledge, we thought to study the hydro-metathesis using liquid olefin (1-decene). Another aspect of using 1-decene comes from our previous experience on metathesis of n-decane where the first step is the conversion of decane to 1-decene and subsequently to different chain length alkanes with W-alkyl/alkylidene catalyst. In this way, it would be easy for us to use different catalysts and compare them with parent catalyst concerning TON. We found 100% conversion with TON of 1010 using supported WMe6 onto SiO2-700 [(≡Si-O-)WMe5] against the previous results for n-decane showing 20% conversion and TON of 153. In this work, we disclose the hydro-metathesis reaction of 1-decene using well-defined silica supported W(VI), Mo(VI) and Ta(V) alkyl catalysts in batch reactor condition. This work is divided into three major sections; first chapter contains an introduction to the field of catalysis and surface organometallic chemistry. In second chapter

  1. UNDERGROUND

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    1993-11-15

    Full text: Cossetted deep underground, sheltered from cosmic ray noise, has always been a favourite haunt of neutrino physicists. Already in the 1930s, significant limits were obtained by taking a geiger counter down in Holborn 'tube' station, one of the deepest in London's underground system. Since then, neutrino physicists have popped up in many unlikely places - gold mines, salt mines, and road tunnels deep under mountain chains. Two such locations - the 1MB (Irvine/ Michigan/Brookhaven) detector 600 metres below ground in an Ohio salt mine, and the Kamiokande apparatus 1000m underground 300 km west of Tokyo - picked up neutrinos on 23 February 1987 from the famous 1987A supernova. Purpose-built underground laboratories have made life easier, notably the Italian Gran Sasso Laboratory near Rome, 1.4 kilometres below the surface, and the Russian Baksan Neutrino Observatory under Mount Andyrchi in the Caucasus range. Gran Sasso houses ICARUS (April, page 15), Gallex, Borexino, Macro and the LVD Large Volume Detector, while Baksan is the home of the SAGE gallium-based solar neutrino experiment. Elsewhere, important ongoing underground neutrino experiments include Soudan II in the US (April, page 16), the Canadian Sudbury Neutrino Observatory with its heavy water target (January 1990, page 23), and Superkamiokande in Japan (May 1991, page 8)

  2. Construction experiences from underground works at Forsmark. Compilation Report

    Energy Technology Data Exchange (ETDEWEB)

    Carlsson, Anders [Vattenfall Power Consultant AB, Stockholm (Sweden); Christiansson, Rolf [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)

    2007-02-15

    The main objective with this report, the Construction Experience Compilation Report (CECR), is to compile experiences from the underground works carried out at Forsmark, primarily construction experiences from the tunnelling of the two cooling water tunnels of the Forsmark nuclear power units 1, 2 and 3, and from the underground excavations of the undersea repository for low and intermediate reactor waste, SFR. In addition, a brief account is given of the operational experience of the SFR on primarily rock support solutions. The authors of this report have separately participated throughout the entire construction periods of the Forsmark units and the SFR in the capacity of engineering geologists performing geotechnical mapping of the underground excavations and acted as advisors on tunnel support; Anders Carlsson participated in the construction works of the cooling water tunnels and the open cut excavations for Forsmark 1, 2 and 3 (geotechnical mapping) and the Forsmark 3 tunnel (advise on tunnel support). Rolf Christiansson participated in the underground works for the SFR (geotechnical mapping, principal investigator for various measurements and advise on tunnel support and grouting). The report is to a great extent based on earlier published material as presented in the list of references. But it stands to reason that, during the course of the work with this report, unpublished notes, diaries, drawings, photos and personal recollections of the two authors have been utilised in order to obtain such a complete compilation of the construction experiences as possible.

  3. Construction experiences from underground works at Forsmark. Compilation Report

    International Nuclear Information System (INIS)

    Carlsson, Anders; Christiansson, Rolf

    2007-02-01

    The main objective with this report, the Construction Experience Compilation Report (CECR), is to compile experiences from the underground works carried out at Forsmark, primarily construction experiences from the tunnelling of the two cooling water tunnels of the Forsmark nuclear power units 1, 2 and 3, and from the underground excavations of the undersea repository for low and intermediate reactor waste, SFR. In addition, a brief account is given of the operational experience of the SFR on primarily rock support solutions. The authors of this report have separately participated throughout the entire construction periods of the Forsmark units and the SFR in the capacity of engineering geologists performing geotechnical mapping of the underground excavations and acted as advisors on tunnel support; Anders Carlsson participated in the construction works of the cooling water tunnels and the open cut excavations for Forsmark 1, 2 and 3 (geotechnical mapping) and the Forsmark 3 tunnel (advise on tunnel support). Rolf Christiansson participated in the underground works for the SFR (geotechnical mapping, principal investigator for various measurements and advise on tunnel support and grouting). The report is to a great extent based on earlier published material as presented in the list of references. But it stands to reason that, during the course of the work with this report, unpublished notes, diaries, drawings, photos and personal recollections of the two authors have been utilised in order to obtain such a complete compilation of the construction experiences as possible

  4. Recovery Of Chromium Metal (VI) Using Supported Liquid Membrane (SLM) Method, A study of Influence of NaCl and pH in Receiving Phase on Transport

    Science.gov (United States)

    Cholid Djunaidi, Muhammad; Lusiana, Retno A.; Rahayu, Maya D.

    2017-06-01

    Chromium metal(VI) is a valuable metal but in contrary has high toxicity, so the separation and recovery from waste are very important. One method that can be used for the separation and recovery of chromium (VI) is a Supported Liquid Membrane (SLM). SLM system contains of three main components: a supporting membrane, organic solvents and carrier compounds. The supported Membrane used in this research is Polytetrafluoroethylene (PTFE), organic solvent is kerosene, and the carrier compound used is aliquat 336. The supported liquid membrane is placed between two phases, namely, feed phase as the source of analyte (Cr(VI)) and the receiving phase as the result of separation. Feed phase is the electroplating waste which contains of chromium metal with pH variation about 4, 6 and 9. Whereas the receiving phase are the solution of HCl, NaOH, HCl-NaCl and NaOH-NaCl with pH variation about 1, 3, 5 and 7. The efficiency separation is determined by measurement of chromium in the feed and the receiving phase using AAS (Atomic Absorption Spectrophotometry). The experiment results show that transport of Chrom (VI) by Supported Liquid membrane (SLM) is influenced by pH solution in feed phase and receiving phase as well as NaCl in receiving phase. The highest chromium metal is transported from feed phase about 97,78%, whereas in receiving phase shows about 58,09%. The highest chromium metal transport happens on pH 6 in feed phase, pH 7 in receiving phase with the mixture of NaOH and NaCl using carrier compound aliquat 336.

  5. UNDERGROUND

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    Full text: Cossetted deep underground, sheltered from cosmic ray noise, has always been a favourite haunt of neutrino physicists. Already in the 1930s, significant limits were obtained by taking a geiger counter down in Holborn 'tube' station, one of the deepest in London's underground system. Since then, neutrino physicists have popped up in many unlikely places - gold mines, salt mines, and road tunnels deep under mountain chains. Two such locations - the 1MB (Irvine/ Michigan/Brookhaven) detector 600 metres below ground in an Ohio salt mine, and the Kamiokande apparatus 1000m underground 300 km west of Tokyo - picked up neutrinos on 23 February 1987 from the famous 1987A supernova. Purpose-built underground laboratories have made life easier, notably the Italian Gran Sasso Laboratory near Rome, 1.4 kilometres below the surface, and the Russian Baksan Neutrino Observatory under Mount Andyrchi in the Caucasus range. Gran Sasso houses ICARUS (April, page 15), Gallex, Borexino, Macro and the LVD Large Volume Detector, while Baksan is the home of the SAGE gallium-based solar neutrino experiment. Elsewhere, important ongoing underground neutrino experiments include Soudan II in the US (April, page 16), the Canadian Sudbury Neutrino Observatory with its heavy water target (January 1990, page 23), and Superkamiokande in Japan (May 1991, page 8)

  6. ViA: a perceptual visualization assistant

    Science.gov (United States)

    Healey, Chris G.; St. Amant, Robert; Elhaddad, Mahmoud S.

    2000-05-01

    This paper describes an automated visualized assistant called ViA. ViA is designed to help users construct perceptually optical visualizations to represent, explore, and analyze large, complex, multidimensional datasets. We have approached this problem by studying what is known about the control of human visual attention. By harnessing the low-level human visual system, we can support our dual goals of rapid and accurate visualization. Perceptual guidelines that we have built using psychophysical experiments form the basis for ViA. ViA uses modified mixed-initiative planning algorithms from artificial intelligence to search of perceptually optical data attribute to visual feature mappings. Our perceptual guidelines are integrated into evaluation engines that provide evaluation weights for a given data-feature mapping, and hints on how that mapping might be improved. ViA begins by asking users a set of simple questions about their dataset and the analysis tasks they want to perform. Answers to these questions are used in combination with the evaluation engines to identify and intelligently pursue promising data-feature mappings. The result is an automatically-generated set of mappings that are perceptually salient, but that also respect the context of the dataset and users' preferences about how they want to visualize their data.

  7. US Underground Nuclear Test History Reports

    Science.gov (United States)

    History Documents US Underground Nuclear Test History Reports NTPR Radiation Exposure Reports Enewetak Atoll Cleanup Documents TRAC About Who We Are Our Values History Locations Our Leadership Director Support Center Contact Us FAQ Sheet Links Success Stories Contracts Business Opportunities Current

  8. Deep Underground Science and Engineering Laboratory - Preliminary Design Report

    CERN Document Server

    Lesko, Kevin T; Alonso, Jose; Bauer, Paul; Chan, Yuen-Dat; Chinowsky, William; Dangermond, Steve; Detwiler, Jason A; De Vries, Syd; DiGennaro, Richard; Exter, Elizabeth; Fernandez, Felix B; Freer, Elizabeth L; Gilchriese, Murdock G D; Goldschmidt, Azriel; Grammann, Ben; Griffing, William; Harlan, Bill; Haxton, Wick C; Headley, Michael; Heise, Jaret; Hladysz, Zbigniew; Jacobs, Dianna; Johnson, Michael; Kadel, Richard; Kaufman, Robert; King, Greg; Lanou, Robert; Lemut, Alberto; Ligeti, Zoltan; Marks, Steve; Martin, Ryan D; Matthesen, John; Matthew, Brendan; Matthews, Warren; McConnell, Randall; McElroy, William; Meyer, Deborah; Norris, Margaret; Plate, David; Robinson, Kem E; Roggenthen, William; Salve, Rohit; Sayler, Ben; Scheetz, John; Tarpinian, Jim; Taylor, David; Vardiman, David; Wheeler, Ron; Willhite, Joshua; Yeck, James

    2011-01-01

    The DUSEL Project has produced the Preliminary Design of the Deep Underground Science and Engineering Laboratory (DUSEL) at the rehabilitated former Homestake mine in South Dakota. The Facility design calls for, on the surface, two new buildings - one a visitor and education center, the other an experiment assembly hall - and multiple repurposed existing buildings. To support underground research activities, the design includes two laboratory modules and additional spaces at a level 4,850 feet underground for physics, biology, engineering, and Earth science experiments. On the same level, the design includes a Department of Energy-shepherded Large Cavity supporting the Long Baseline Neutrino Experiment. At the 7,400-feet level, the design incorporates one laboratory module and additional spaces for physics and Earth science efforts. With input from some 25 science and engineering collaborations, the Project has designed critical experimental space and infrastructure needs, including space for a suite of multi...

  9. Leaking Underground Storage Tank Sites in Iowa

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — Leaking Underground Storage Tank (LUST) sites where petroleum contamination has been found. There may be more than one LUST site per UST site.

  10. Construction of high-rise building with underground parking in Moscow

    Directory of Open Access Journals (Sweden)

    Ilyichev Vyacheslav

    2018-01-01

    Full Text Available Paper presents results of scientific support to construction of unique residential building 108 m high with one storey underground part under high-rise section and 3-storey underground parking connected by underground passage. On-site soils included anthropogenic soil, clayey soils soft-stiff, saturated sands of varied grain coarseness. Design of retaining structure and support system for high-rise part excavation was developed. It suggested installation of steel pipes and struts. Construction of adjacent 3-storey underground parking by “Moscow method” is described in the paper. This method involves implementation of retaining wall consisted of prefabricated panels, truss structures (used as struts and reinforced concrete slabs. Also design and construction technology is provided for foundations consisted of bored piles 800 MM in diameter joined by slab with base widening diameter of 1500 MM. Experiment results of static and dynamic load testing (ELDY method are considered. Geotechnical monitoring data of adjacent building and utility systems settlement caused by construction of presented high-rise building were compared to numerical modelling results, predicted and permissible values.

  11. Construction of high-rise building with underground parking in Moscow

    Science.gov (United States)

    Ilyichev, Vyacheslav; Nikiforova, Nadezhda; Konnov, Artem

    2018-03-01

    Paper presents results of scientific support to construction of unique residential building 108 m high with one storey underground part under high-rise section and 3-storey underground parking connected by underground passage. On-site soils included anthropogenic soil, clayey soils soft-stiff, saturated sands of varied grain coarseness. Design of retaining structure and support system for high-rise part excavation was developed. It suggested installation of steel pipes and struts. Construction of adjacent 3-storey underground parking by "Moscow method" is described in the paper. This method involves implementation of retaining wall consisted of prefabricated panels, truss structures (used as struts) and reinforced concrete slabs. Also design and construction technology is provided for foundations consisted of bored piles 800 MM in diameter joined by slab with base widening diameter of 1500 MM. Experiment results of static and dynamic load testing (ELDY method) are considered. Geotechnical monitoring data of adjacent building and utility systems settlement caused by construction of presented high-rise building were compared to numerical modelling results, predicted and permissible values.

  12. Underground storage tanks

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    Environmental contamination from leaking underground storage tanks poses a significant threat to human health and the environment. An estimated five to six million underground storage tanks containing hazardous substances or petroleum products are in use in the US. Originally placed underground as a fire prevention measure, these tanks have substantially reduced the damages from stored flammable liquids. However, an estimated 400,000 underground tanks are thought to be leaking now, and many more will begin to leak in the near future. Products released from these leaking tanks can threaten groundwater supplies, damage sewer lines and buried cables, poison crops, and lead to fires and explosions. As required by the Hazardous and Solid Waste Amendments (HSWA), the EPA has been developing a comprehensive regulatory program for underground storage tanks. The EPA proposed three sets of regulations pertaining to underground tanks. The first addressed technical requirements for petroleum and hazardous substance tanks, including new tank performance standards, release detection, release reporting and investigation, corrective action, and tank closure. The second proposed regulation addresses financial responsibility requirements for underground petroleum tanks. The third addressed standards for approval of state tank programs

  13. Underground pipeline corrosion

    CERN Document Server

    Orazem, Mark

    2014-01-01

    Underground pipelines transporting liquid petroleum products and natural gas are critical components of civil infrastructure, making corrosion prevention an essential part of asset-protection strategy. Underground Pipeline Corrosion provides a basic understanding of the problems associated with corrosion detection and mitigation, and of the state of the art in corrosion prevention. The topics covered in part one include: basic principles for corrosion in underground pipelines, AC-induced corrosion of underground pipelines, significance of corrosion in onshore oil and gas pipelines, n

  14. The Effect of the Concentration of Oxidant, Cr(VI), on the Iron Oxidation in Saline Water

    Science.gov (United States)

    Ahn, H.; Jo, H. Y.; Ryu, J. H.; Koh, Y. K.

    2014-12-01

    Deep geological disposal is currently considered as the most appropriate method to isolate high level radioactive wastes (HLRWs) from the ecosystem. If groundwater seeps into underground disposal facilities, water molecules can be dissociated to radicals or peroxides, which can oxidize metal canisters and HLRWs. The oxidized radionuclides with a high solubility can be dissolved in the groundwater. Some dissolved radionuclides can act as oxidants. The continuous radiolysis of water molecules, which results from continuous seepage of groundwater, can enable the continuous production of the radioactive oxidants, resulting in an increase in concentration of oxidants. In this study, the effect of oxidant concentration on iron oxidation in the presence of salt was evaluated. Zero valent iron (ZVI) particles were reacted with Cr(VI) solutions with initial Cr(VI) concentrations ranged from 50 to 300 mg/L in reactors. The initial pH and NaCl concentration were fixed at 3 and 0.5 M, respectively. An increase in the initial Cr(VI) concentration caused an increase in the rate and extend of H2 gas production. The decrement of Cr(VI) was increased as the initial Cr(VI) concentration was increased. The penetration of H+ ions in the presence Cl- ions through the passive film on the ZVI particles caused the reaction between H+ ions and ZVI particles, producing H2 gas and Fe2+ ions. The passive film was damaged during the reaction due to the eruption of H2 gas or peptization by Cl- ions. The Fe2+ ions were reacted with Cr(VI) ions in the solution, producing Fe(III)-Cr(III) (oxy)hydroxides on the passive film of ZVI particles or in the solution as colloidal particles. The Fe(III)-Cr(III) (oxy)hydroxides tends to be precipitated as colloidal particles at a high Cr(VI) concentration and precipitated on the passive film at a low Cr(VI) concentration. The passive film was repaired or thickened by additional formation of Fe(III)-Cr(III) (oxy)hydroxides at a lower Cr(VI) concentration.

  15. Analysis on one underground nuclear waste repository rock mass in USA

    International Nuclear Information System (INIS)

    Ha Qiuling; Zhang Tiantian

    2012-01-01

    When analyzing the rock mass of a underground nuclear waste repository, the current studies are all based on the loading mechanical condition, and the unloading damage of rock mass is unconsidered. According to the different mechanical condition of actual engineering rock mass of loading and unloading, this paper implements a comprehensive analysis on the rock mass deformation of underground nuclear waste repository through the combination of present loading and unloading rock mass mechanics. It is found that the results of comprehensive analysis and actual measured data on the rock mass deformation of underground nuclear waste repository are basically the same, which provide supporting data for the underground nuclear waste repository. (authors)

  16. The Canfranc Underground Laboratory

    International Nuclear Information System (INIS)

    Amare, J.; Beltran, B.; Carmona, J.M.; Cebrian, S.; Garcia, E.; Irastorza, I.G.; Gomez, H.; Luzon, G.; Martinez, M.; Morales, J.; Ortiz de Solorzano, A.; Pobes, C.; Puimedon, J.; Rodriguez, A.; Ruz, J.; Sarsa, M.L.; Torres, L.; Villar, J.A.

    2005-01-01

    This paper describes the forthcoming enlargement of the Canfranc Underground Laboratory (LSC) which will allow to host new international Astroparticle Physics experiments and therefore to broaden the European underground research area. The new Canfranc Underground Laboratory will operate in coordination (through the ILIAS Project) with the Gran Sasso (Italy), Modane (France) and Boulby (UK) underground laboratories

  17. In situ monitoring of primary roofbolts at underground coal mines in the USA

    OpenAIRE

    Spearing, A.J.S.; Hyett, A.

    2014-01-01

    Primary roof support represents the first line of defence against rock-related falls of ground in underground mines, and improper utilization or misunderstanding of the applicability and behaviour of primary support can be costly from a safety standpoint. This is a major concern for underground mines, as roof support is the single most costly expense from a mining operational perspective. This is further backed by the evidence that, in the USA, hundreds of injuries and fatalities still occur ...

  18. Management of mining-related damages in abandoned underground coal mine areas using GIS

    International Nuclear Information System (INIS)

    Lee, U.J.; Kim, J.A.; Kim, S.S.; Kim, W.K.; Yoon, S.H.; Choi, J.K.

    2005-01-01

    The mining-related damages such as ground subsidence, acid mine drainage (AMD), and deforestation in the abandoned underground coal mine areas become an object of public concern. Therefore, the system to manage the mining-related damages is needed for the effective drive of rehabilitation activities. The management system for Abandoned Underground Coal Mine using GIS includes the database about mining record and information associated with the mining-related damages and application programs to support mine damage prevention business. Also, this system would support decision-making policy for rehabilitation and provide basic geological data for regional construction works in abandoned underground coal mine areas. (authors)

  19. Underground laboratories for rock mechanics before radioactive waste

    International Nuclear Information System (INIS)

    Duffaut, P.

    1985-01-01

    Many rock mechanics tests are performed in situ, most of them underground since 1936 at the Beni Bahdel dam. The chief tests for understanding the rock mass behaviour are deformability tests (plate test and pressure cavern test, including creep experiments) and strength tests (compression of a mine pillar, shear test on rock mass or joint). Influence of moisture, heat, cold and freeze are other fields of investigation which deserve underground laboratories. Behaviour of test galleries, either unsupported or with various kinds of support, often is studied along time, and along the work progression, tunnel face advance, enlargement or deepening of the cross section. The examples given here help to clarify the concept of underground laboratory in spite of its many different objectives. 38 refs.; 1 figure; 1 table

  20. Biological detoxification of Cr(VI) using wood-husk immobilized Acinetobacter haemolyticus

    International Nuclear Information System (INIS)

    Zakaria, Zainul Akmar; Zakaria, Zainoha; Surif, Salmijah; Ahmad, Wan Azlina

    2007-01-01

    Acinetobacter haemolyticus, a Gram-negative aerobic locally isolated bacterium, immobilized on wood-husk showed the ability to detoxify Cr(VI) to Cr(III). Wood-husk, a natural cellulose-based support material, packed in an upward-flow column was used as support material for bacterial attachment. Around 97% of the Cr(VI) in wastewater containing 15 mg L -1 of Cr(VI) was reduced at a flow rate of 8.0 mL min -1 . The wastewater containing Cr(VI) was added with liquid pineapple wastewater as nutrient source for the bacteria. Electron microscopic examinations of the wood-husk after 42 days of column operation showed gradual colonization of the wood-husk by bacterial biofilm. The use of 0.1% (v/v) formaldehyde as a disinfecting agent inhibited growth of bacteria present in the final wastewater discharge. This finding is important in view of the ethical code regarding possible introduction of exogenous bacterial species into the environment

  1. Biological detoxification of Cr(VI) using wood-husk immobilized Acinetobacter haemolyticus

    Energy Technology Data Exchange (ETDEWEB)

    Zakaria, Zainul Akmar; Zakaria, Zainoha [Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 Skudai, Johor (Malaysia); Surif, Salmijah [Department of Environmental Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Ahmad, Wan Azlina [Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 Skudai, Johor (Malaysia)], E-mail: azlina@kimia.fs.utm.my

    2007-09-05

    Acinetobacter haemolyticus, a Gram-negative aerobic locally isolated bacterium, immobilized on wood-husk showed the ability to detoxify Cr(VI) to Cr(III). Wood-husk, a natural cellulose-based support material, packed in an upward-flow column was used as support material for bacterial attachment. Around 97% of the Cr(VI) in wastewater containing 15 mg L{sup -1} of Cr(VI) was reduced at a flow rate of 8.0 mL min{sup -1}. The wastewater containing Cr(VI) was added with liquid pineapple wastewater as nutrient source for the bacteria. Electron microscopic examinations of the wood-husk after 42 days of column operation showed gradual colonization of the wood-husk by bacterial biofilm. The use of 0.1% (v/v) formaldehyde as a disinfecting agent inhibited growth of bacteria present in the final wastewater discharge. This finding is important in view of the ethical code regarding possible introduction of exogenous bacterial species into the environment.

  2. A Corrosion Risk Assessment Model for Underground Piping

    Science.gov (United States)

    Datta, Koushik; Fraser, Douglas R.

    2009-01-01

    The Pressure Systems Manager at NASA Ames Research Center (ARC) has embarked on a project to collect data and develop risk assessment models to support risk-informed decision making regarding future inspections of underground pipes at ARC. This paper shows progress in one area of this project - a corrosion risk assessment model for the underground high-pressure air distribution piping system at ARC. It consists of a Corrosion Model of pipe-segments, a Pipe Wrap Protection Model; and a Pipe Stress Model for a pipe segment. A Monte Carlo simulation of the combined models provides a distribution of the failure probabilities. Sensitivity study results show that the model uncertainty, or lack of knowledge, is the dominant contributor to the calculated unreliability of the underground piping system. As a result, the Pressure Systems Manager may consider investing resources specifically focused on reducing these uncertainties. Future work includes completing the data collection effort for the existing ground based pressure systems and applying the risk models to risk-based inspection strategies of the underground pipes at ARC.

  3. Inhibition of bacterial U(VI) reduction by calcium

    International Nuclear Information System (INIS)

    Brooks, Scott C.; Fredrickson, Jim K.; Carroll, S. L.; Kennedy, David W.; Zachara, John M.; Plymale, Andrew E.; Kelly, S. D.; Kemner, K. M.; Fendorf, S.

    2003-01-01

    The rapid kinetics of bacterial U(VI) reduction and low solubility of uraninite (UO2,cr) make this process an attractive option for removing uranium from groundwater. Nevertheless, conditions that may promote or inhibit U(VI) reduction are not well-defined. Recent descriptions of Ca-UO2-CO3 complexes indicate that these species may dominate the aqueous speciation of U(VI) in many environments. We monitored the bacterial reduction of U(VI) in bicarbonate-buffered solution in the presence and absence of Ca. XAFS measurements confirmed the presence of a Ca-U(VI)-CO3 complex in the initial solutions containing calcium. Calcium, at millimolar concentrations (0.45-5 mM), caused a significant decrease in the rate and extent of bacterial U(VI) reduction. Both facultative (Shewanella putrefaciens strain CN32) and obligate (Desulfovibrio desulfuricans, Geobacter sulfurreducens) anaerobic bacteria were affected by the presence of calcium. Reduction of U(VI) ceased when the calculated system Eh re ached -0.046+/- 0.001 V, based on the Ca2UO2(CO3)(3) -- > UO2,cr couple. The results are consistent with the hypothesis that U is a less energetically favorable electron acceptor when the Ca-UO2-CO3 complexes are present. The results do not support Ca inhibition caused by direct interactions with the cells or with the electron donor as the reduction of fumarate or Tc(VII)O-4(-) under identical conditions was unaffected by the presence of Ca

  4. An electrochemical study of U(VI) and Cr(VI) in molten borates

    International Nuclear Information System (INIS)

    Brigaudeau, M.; Gregori de Pinochet, I. de

    1977-01-01

    The electrochemical reduction of U(VI) and Cr(VI), in molten Na 2 B 4 O 7 at 800 deg C was studied by means of linear sweep voltammetry, and chronopotentiometry. The reduction of U(VI) to U(V) proceeded reversibly at a platinum electrode. The diffusion coefficient for the U(VI) species at 800 deg C was 4.10 -7 cm 2 .s -1 . The activation energy of diffusion was (34,8 +- 0,8) kcal. mole -1 . Electrochemical studies of Cr(VI) at 800 0 C reveal a two-step reduction process at a platinum electrode. Only the voltammogram for the first step charge transfer process was studied. Analysis indicated that Cr(VI) is reversibly reduced to Cr(III) at a platinum electrode. The diffusion coefficient for Cr(VI) at 800 0 C is 1,9.10 -7 cm 2 .s -1 [fr

  5. Environment Of Underground Water And Pollution

    Energy Technology Data Exchange (ETDEWEB)

    Han, Jeong Sang

    1998-02-15

    This book deals with environment of underground water and pollution, which introduces the role of underground water in hydrology, definition of related study of under water, the history of hydro-geology, basic conception of underground water such as origin of water, and hydrogeologic characteristic of aquifers, movement of underground water, hydrography of underground water and aquifer test analysis, change of an underground water level, and water balance analysis and development of underground water.

  6. Glimos Instructions for CMS Underground Guiding - in english

    CERN Multimedia

    CERN. Geneva; Dupont, Niels; Esposito, William

    2016-01-01

    In this presentation in english, the basic safety rules for CMS underground visits are explained. The trainees are taught how to plan/organize a CMS underground visit along important safety aspects of the CMS underground (Point 5). Content owners and presenters (CMS safety team) : Niels Dupont (in french), Michael Brodski (in german), William Esposito (in english) A pdf document on the subject is available as material from the indico event page. (TO BE DONE from https://twiki.cern.ch/Edutech/CMSGlimosInstructions!)   Tell us what you think via e-learning.support at cern.ch More tutorials in the e-learning collection of the CERN Document Server (CDS) http://cds.cern.ch/collection/E-learning%20modules?ln=en All info about the CERN rapid e-learning project is linked from http://twiki.cern.ch/ELearning  

  7. Glimos Instructions for CMS Underground Guiding - in french

    CERN Multimedia

    CERN. Geneva; Dupont, Niels; Brodski, Michael

    2016-01-01

    In this presentation in french, the basic safety rules for CMS underground visits are explained. The trainees are taught how to plan/organize a CMS underground visit along important safety aspects of the CMS underground (Point 5). Content owners and presenters (CMS safety team) : Niels Dupont (in french), Michael Brodski (in german), William Esposito (in english) A pdf document on the subject is available as material from the indico event page. (TO BE DONE from https://twiki.cern.ch/Edutech/CMSGlimosInstructions!)   Tell us what you think via e-learning.support at cern.ch More tutorials in the e-learning collection of the CERN Document Server (CDS) http://cds.cern.ch/collection/E-learning%20modules?ln=en All info about the CERN rapid e-learning project is linked from http://twiki.cern.ch/ELearning  

  8. Solvent impregnated resin for isolation of U(VI) from industrial wastes

    International Nuclear Information System (INIS)

    Karve, M.; Rajgor, R.V.

    2008-01-01

    A solid-phase extraction method based upon impregnation of Cyanex 302 (bis(2,4,4- trimethylpentyl)mono-thio-phosphinic acid) on Amberlite XAD-2 resin is proposed for isolation of U(VI) from uranmicrolite ore tailing samples and industrial effluent samples. U(VI) was sorbed from nitric acid media on the solvent-impregnated resin (SIR) and was recovered completely with 1.0 M HCl. Based upon sorption behavior of U(VI) with Cyanex 302, it was quantitatively sorbed on the SIR in a dynamic method, while the other metal ions were not sorbed by the modified resin. The preparation of impregnated resin is simple, based upon physical interaction of the extractant and solid support, has good sorption capacity for U(VI), and is also reliable for detection of traces of U(VI). (authors)

  9. The Use of Underground Research Laboratories to Support Repository Development Programs. A Roadmap for the Underground Research Facilities Network.

    Energy Technology Data Exchange (ETDEWEB)

    MacKinnon, Robert J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-10-26

    Under the auspices of the International Atomic Energy Agency (IAEA), nationally developed underground research laboratories (URLs) and associated research institutions are being offered for use by other nations. These facilities form an Underground Research Facilities (URF) Network for training in and demonstration of waste disposal technologies and the sharing of knowledge and experience related to geologic repository development, research, and engineering. In order to achieve its objectives, the URF Network regularly sponsors workshops and training events related to the knowledge base that is transferable between existing URL programs and to nations with an interest in developing a new URL. This report describes the role of URLs in the context of a general timeline for repository development. This description includes identification of key phases and activities that contribute to repository development as a repository program evolves from an early research and development phase to later phases such as construction, operations, and closure. This information is cast in the form of a matrix with the entries in this matrix forming the basis of the URF Network roadmap that will be used to identify and plan future workshops and training events.

  10. Status and prospects of a deep underground laboratory in China

    International Nuclear Information System (INIS)

    Kang, K J; Cheng, J P; Li, Y J; Yue, Q; Chen, Y H; Shen, M B; Wu, S Y

    2010-01-01

    An excellent candidate location for a deep underground laboratory with more than 2500 m of rock overburden has been identified at Sichuan Province in China. It can be accessed through a road tunnel of length 17.5 km, and is supported by services and amenities near the entrance provided by the local Ertan Hydropower Plant. The particle physics community in China is actively pursuing the construction of an underground laboratory at this location, under the leadership of Tsinghua University. Memorandum has been signed with Ertan Hydropower Plant which permits access to and construction of the underground laboratory - China JinPing Deep Underground Laboratory (CJPL). The basic features of this underground site, as well as the status and schedules of the construction of the first laboratory cavern are presented. The immediate goal is to have the first experiment operational in 2010, deploying an Ultra-Low-Energy Germanium detector for WIMP dark matter searches, with emphasis on the mass range of 1-10 GeV. The conceptual design of the experiment, as well as the future plans and prospects of the laboratory, will be surveyed.

  11. Construction experiences from underground works at Oskarshamn. Compilation report

    International Nuclear Information System (INIS)

    Carlsson, Anders; Christiansson, Rolf

    2007-12-01

    The main objective with this report is to compile experiences from the underground works carried out at Oskarshamn, primarily construction experiences from the tunnelling of the cooling water tunnels of the Oskarshamn nuclear power units 1,2 and 3, from the underground excavations of Clab 1 and 2 (Central Interim Storage Facility for Spent Nuclear Fuel), and Aespoe Hard Rock Laboratory. In addition, an account is given of the operational experience of Clab 1 and 2 and of the Aespoe HRL on primarily scaling and rock support solutions. This report, as being a compilation report, is in its substance based on earlier published material as presented in the list of references. Approximately 8,000 m of tunnels including three major rock caverns with a total volume of about 550,000 m 3 have been excavated. The excavation works of the various tunnels and rock caverns were carried out during the period of 1966-2000. In addition, minor excavation works were carried out at the Aespoe HRL in 2003. The depth location of the underground structures varies from near surface down to 450 m. As an overall conclusion it may be said that the rock mass conditions in the area are well suited for underground construction. This conclusion is supported by the experiences from the rock excavation works in the Simpevarp and Aespoe area. These works have shown that no major problems occurred during the excavation works; nor have any stability or other rock engineering problems of significance been identified after the commissioning of the Oskarshamn nuclear power units O1, O2 and O3, BFA, Clab 1 and 2, and Aespoe Hard Rock Laboratory. The underground structures of these facilities were built according to plan, and since than been operated as planned. Thus, the quality of the rock mass within the construction area is such that it lends itself to excavation of large rock caverns with a minimum of rock support

  12. Construction experiences from underground works at Oskarshamn. Compilation report

    Energy Technology Data Exchange (ETDEWEB)

    Carlsson, Anders (Vattenfall Power Consultant AB, Stockholm (SE)); Christiansson, Rolf (Swedish Nuclear Fuel and Waste Management Co., Stockholm (SE))

    2007-12-15

    The main objective with this report is to compile experiences from the underground works carried out at Oskarshamn, primarily construction experiences from the tunnelling of the cooling water tunnels of the Oskarshamn nuclear power units 1,2 and 3, from the underground excavations of Clab 1 and 2 (Central Interim Storage Facility for Spent Nuclear Fuel), and Aespoe Hard Rock Laboratory. In addition, an account is given of the operational experience of Clab 1 and 2 and of the Aespoe HRL on primarily scaling and rock support solutions. This report, as being a compilation report, is in its substance based on earlier published material as presented in the list of references. Approximately 8,000 m of tunnels including three major rock caverns with a total volume of about 550,000 m3 have been excavated. The excavation works of the various tunnels and rock caverns were carried out during the period of 1966-2000. In addition, minor excavation works were carried out at the Aespoe HRL in 2003. The depth location of the underground structures varies from near surface down to 450 m. As an overall conclusion it may be said that the rock mass conditions in the area are well suited for underground construction. This conclusion is supported by the experiences from the rock excavation works in the Simpevarp and Aespoe area. These works have shown that no major problems occurred during the excavation works; nor have any stability or other rock engineering problems of significance been identified after the commissioning of the Oskarshamn nuclear power units O1, O2 and O3, BFA, Clab 1 and 2, and Aespoe Hard Rock Laboratory. The underground structures of these facilities were built according to plan, and since than been operated as planned. Thus, the quality of the rock mass within the construction area is such that it lends itself to excavation of large rock caverns with a minimum of rock support

  13. Removal of Cr(VI from Water Using a New Reactive Material: Magnesium Oxide Supported Nanoscale Zero-Valent Iron

    Directory of Open Access Journals (Sweden)

    Alessio Siciliano

    2016-08-01

    Full Text Available The chromium pollution of water is an important environmental and health issue. Cr(VI removal by means of metallic iron is an attractive method. Specifically, nanoscopic zero valent iron (NZVI shows great reactivity, however, its applicability needs to be further investigated. In the present paper, NZVI was supported on MgO grains to facilitate the treatments for remediation of chromium-contaminated waters. The performances and mechanisms of the developed composite, in the removal of hexavalent chromium, were investigated by means of batch and continuous tests. Kinetic studies, under different operating conditions, showed that reduction of Cr(VI could be expressed by a pseudo second-order reaction kinetic. The reaction rate increased with the square of Fe(0 amount, while it was inversely proportional to the initial chromium concentration. The process performance was satisfactory also under uncontrolled pH, and a limited influence of temperature was observed. The reactive material was efficiently reusable for many cycles without any regeneration treatment. The performances in continuous tests were close to 97% for about 80 pore volume of reactive material.

  14. Synthesis and characterization of a homogeneous and silica supported homoleptic cationic tungsten(vi) methyl complex: application in olefin metathesis

    KAUST Repository

    Dey, Raju

    2016-08-19

    A method for the synthesis of a homogeneous cationic tungsten(VI)penta-methyl complex [(WMe5)(+)(C6F5)(3)BMe-] from neutral tungstenhexamethyl (WMe6) and a silica supported cationic tungstentetramethyl complex [( Si-O-)WMe4+ (C6F5)(3)BMe-] from a neutral silica supported tungstenpentamethyl complex [( Si-O-)WMe5] is described. In both cases a direct demethylation using the B(C6F5)(3) reagent was used. The aforesaid complexes were characterized by liquid or solid state NMR spectroscopy. Interestingly, the homogeneous cationic complex [(WMe5)(+)(C6F5)(3)BMe-] shows moderate activity whereas the supported cationic complex [( Si-O-)WMe4+(C6F5)(3)BMe-] exhibits good activity in olefin metathesis reactions.

  15. Synthesis and characterization of a homogeneous and silica supported homoleptic cationic tungsten(vi) methyl complex: application in olefin metathesis

    KAUST Repository

    Dey, Raju; Samantaray, Manoja; Poater, Albert; Hamieh, Ali Imad Ali; Kavitake, Santosh Giridhar; Abou-Hamad, Edy; Callens, Emmanuel; Emwas, Abdul-Hamid M.; Cavallo, Luigi; Basset, Jean-Marie

    2016-01-01

    A method for the synthesis of a homogeneous cationic tungsten(VI)penta-methyl complex [(WMe5)(+)(C6F5)(3)BMe-] from neutral tungstenhexamethyl (WMe6) and a silica supported cationic tungstentetramethyl complex [( Si-O-)WMe4+ (C6F5)(3)BMe-] from a neutral silica supported tungstenpentamethyl complex [( Si-O-)WMe5] is described. In both cases a direct demethylation using the B(C6F5)(3) reagent was used. The aforesaid complexes were characterized by liquid or solid state NMR spectroscopy. Interestingly, the homogeneous cationic complex [(WMe5)(+)(C6F5)(3)BMe-] shows moderate activity whereas the supported cationic complex [( Si-O-)WMe4+(C6F5)(3)BMe-] exhibits good activity in olefin metathesis reactions.

  16. Underground laboratories in Asia

    International Nuclear Information System (INIS)

    Lin, Shin Ted; Yue, Qian

    2015-01-01

    Deep underground laboratories in Asia have been making huge progress recently because underground sites provide unique opportunities to explore the rare-event phenomena for the study of dark matter searches, neutrino physics and nuclear astrophysics as well as the multi-disciplinary researches based on the low radioactive environments. The status and perspectives of Kamioda underground observatories in Japan, the existing Y2L and the planned CUP in Korea, India-based Neutrino Observatory (INO) in India and China JinPing Underground Laboratory (CJPL) in China will be surveyed

  17. Underground laboratories in Asia

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Shin Ted, E-mail: linst@mails.phys.sinica.edu.tw [College of Physical Science and Technology, Sichuan University, Chengdu 610064 China (China); Yue, Qian, E-mail: yueq@mail.tsinghua.edu.cn [Key Laboratory of Particle and Radiation Imaging (Ministry of Education) and Department of Engineering Physics, Tsinghua University, Beijing 100084 China (China)

    2015-08-17

    Deep underground laboratories in Asia have been making huge progress recently because underground sites provide unique opportunities to explore the rare-event phenomena for the study of dark matter searches, neutrino physics and nuclear astrophysics as well as the multi-disciplinary researches based on the low radioactive environments. The status and perspectives of Kamioda underground observatories in Japan, the existing Y2L and the planned CUP in Korea, India-based Neutrino Observatory (INO) in India and China JinPing Underground Laboratory (CJPL) in China will be surveyed.

  18. The use of halloysite functionalized with isothiouronium salts as an organic/inorganic hybrid adsorbent for uranium(VI) ions removal.

    Science.gov (United States)

    Gładysz-Płaska, A; Majdan, M; Tarasiuk, B; Sternik, D; Grabias, E

    2018-07-15

    Elimination of U(VI) from nuclear wastes and from the underground water near the uranium mines is the serious problem. Therefore search for new sorbents for U(VI) is still a big challenge for the scientists. This paper investigates of U(VI) ions sorption on halloysite modified with the isothiouronium salts: S-dodecaneisothiouronium bromide (ligand 1), S,S'-dodecane-1,12-diylbis(isothiouronium bromide) (ligand 2), S-hexadecaneisothiouronium chloride (ligand 3), S,S'-naphthalene-1,4-diylbis(methylisothiouronium) dichloride (ligand 4), and S,S'-2,5-dimethylbenzene-1,4-diylbis(methylisothiouronium) dichloride (ligand 5). It was established that halloysite modified by the ligands with four nitrogen atoms in their structure (ligand-5, 2 and 4) was characterized by higher sorption capacity compared with that modified by the ligands with two donor nitrogens (ligand-1 and 3). The maximum sorption capacity of halloysite-5 toward U(VI) was 157 mg U/g and this places the modified mineral among the most effective sorbents for U(VI) removal from wastes. As follows from ATR, XPS and thermal degradation spectra of the sorption products [R-S-C(NH)(NH 2 )] n = 1-2 (UO 2 2+ ) complexes are formed on the external surface of the halloysite whereas oligomeric hydroxy complexes (UO 2 ) 3 (OH) 5 + and (UO 2 ) 4 (OH) 7 + are present in the interior of halloysite structure and interact predominantly with aluminols. Copyright © 2018 Elsevier B.V. All rights reserved.

  19. Vi, de civiliserede

    DEFF Research Database (Denmark)

    Nyemann, Dorthe

    2016-01-01

    Vi har i årtier troet på, at mennesker under de rette omstændigheder kan lykkes med at leve i fred og fordragelighed med hinanden. Skal vi til at erkende, at også vores samfundsstrukturer kun er en tynd fernis ovenpå et utæmmeligt voldspotentiale og egoisme?......Vi har i årtier troet på, at mennesker under de rette omstændigheder kan lykkes med at leve i fred og fordragelighed med hinanden. Skal vi til at erkende, at også vores samfundsstrukturer kun er en tynd fernis ovenpå et utæmmeligt voldspotentiale og egoisme?...

  20. Orpheus in the Underground

    Directory of Open Access Journals (Sweden)

    Puskás Dániel

    2015-12-01

    Full Text Available In my study I deal with descents to the underworld and hell in literature in the 20th century and in contemporary literature. I will focus on modem literary reinterpretations of the myth of Orpheus, starting with Rilke’s Orpheus. Eurydice. Hermes. In Seamus Heaney’s The Underground. in the Hungarian Istvan Baka’s Descending to the Underground of Moscow and in Czesław Miłosz’s Orpheus and Eurydice underworld appears as underground, similarly to the contemporary Hungarian János Térey’s play entitled Jeramiah. where underground will also be a metaphorical underworld which is populated with the ghosts of the famous deceased people of Debrecen, and finally, in Péter Kárpáti’s Everywoman the grave of the final scene of the medieval Everyman will be replaced with a contemporary underground station. I analyse how an underground station could be parallel with the underworld and I deal with the role of musicality and sounds in the literary works based on the myth of Orpheus.

  1. 40 CFR 280.220 - Ownership of an underground storage tank or underground storage tank system or facility or...

    Science.gov (United States)

    2010-07-01

    ... tank or underground storage tank system or facility or property on which an underground storage tank or underground storage tank system is located. 280.220 Section 280.220 Protection of Environment ENVIRONMENTAL... underground storage tank or underground storage tank system or facility or property on which an underground...

  2. Syntheses of polystyrene supported chelating resin containing the Schiff base derived from salicylaldehyde and triethylene tetramine and its copper(II), nickel(II), cobalt(II), iron(III), zinc(II), cadmium(II), molybdenum(VI), zirconium(IV) and uranium(VI) complexes

    International Nuclear Information System (INIS)

    Syamal, A.; Singh, M.M.

    1998-01-01

    A new polymer-anchored chelating ligand has been synthesized by the reaction of chloromethylated polystyrene (containing 0.94 mmol of Cl per gram of resin and 1% cross-linked with divinylbenzene) and the Schiff base derived from salicylaldehyde and triethylenetetramine. A new series of polystyrene supported, Cu(II), Ni(II), Co(II), Fe(III), Zn(II), Cd(II), Zr(IV), dioxomolybdenum (VI) and dioxouranium (VI) complexes of the formulae PS-LCu, PS-LNi, PS-LCo, PS-LFeCl.DMF, PS-LZn, PS-LCd, PS-LZr(OH) 2 . DMF, PS L MoO 2 and PS-LUO 2 (where PS-LH 2 = polymer-anchored Schiff base and DMF dimethyl-formamide) have been synthesized and characterised by elemental analysis, infrared, electronic spectra and magnetic susceptibility measurements. The complexes PS-LCu, PS-LNi and PS-LCo have square planar structure, PS-LFeCl.DMF, PS-LMoO 2 and PS-LUO 2 have octahedral structure, PS L Zn and PS-LCd are tetrahedral and PS-LZr(OH) 2 .DMF is pentagonal bipyramidal. The polymer-anchored Cu(II), Co(II) and Fe(III) complexes are paramagnetic while Ni(II), Zn(II), Cd(II), Zr(IV), dioxomolybdenum(VI) and dioxouranium(VI) complexes are diamagnetic. The negative shift of the v (C=N) (azomethine) and the positive shift of v (C--O)(phenolic) are indicative of ONNO donor behaviour of the polymer-anchored Schiff base. (author)

  3. Plutonium(VI) accumulation and reduction by lichen biomass: correlation with U(VI)

    International Nuclear Information System (INIS)

    Ohnuki, Toshihiko; Aoyagi, Hisao; Kitatsuji, Yoshihiro; Samadfam, Mohammad; Kimura, Yasuhiko; William Purvis, O.

    2004-01-01

    The uptake of plutonium(VI) and uranium(VI) by lichen biomass was studied in the foliose lichen Parmotrema tinctorum to elucidate the migration behavior of Pu and U in the terrestrial environment. Pu and U uptake by P. tinctorum averaged 0.040±0.010 and 0.055±0.015 g g dry -1 , respectively, after 96 h incubation with 4.0x10 -4 mol l -1 Pu solutions of pH 3, 4 and 5. SEM observations showed that the accumulated Pu is evenly distributed on the upper and lower surfaces of P. tinctorum, in contrast to U(VI), which accumulated in both cortical and medullary layers. UV/VIS absorption spectroscopy demonstrates that a fraction of Pu(VI) in the solution is reduced to Pu(V) by the organic substances released from P. tinctorum, and the accumulated Pu on the surface is reduced to Pu(IV), while U(VI) keeps the oxidation state of VI. Since the solubility of Pu(IV) hydroxides is very low, reduced Pu(VI) does not penetrate to the medullary layers, but is probably precipitated as Pu(IV) hydroxides on the cortical lichen surface. It is concluded that the uptake and reduction of Pu(VI) by lichens is important to determine the mobilization and oxidation states of Pu in the terrestrial environment

  4. Anaerobic bio-removal of uranium (VI) and chromium (VI): Comparison of microbial community structure

    International Nuclear Information System (INIS)

    Martins, Monica; Faleiro, Maria Leonor; Chaves, Sandra; Tenreiro, Rogerio; Santos, Erika; Costa, Maria Clara

    2010-01-01

    Several microbial communities, obtained from uranium contaminated and non-contaminated samples, were investigated for their ability to remove uranium (VI) and the cultures capable for this removal were further assessed on their efficiency for chromium (VI) removal. The highest efficiency for removal of both metals was observed on a consortium from a non-contaminated soil collected in Monchique thermal place, which was capable to remove 91% of 22 mg L -1 U(VI) and 99% of 13 mg L -1 Cr(VI). This study revealed that uranium (VI) removing communities have also ability to remove chromium (VI), but when uranium (VI) was replaced by chromium (VI) several differences in the structure of all bacterial communities were observed. TGGE and phylogenetic analysis of 16S rRNA gene showed that the uranium (VI) removing bacterial consortia are mainly composed by members of Rhodocyclaceae family and Clostridium genus. On the other hand, bacteria from Enterobacteriaceae family were detected in the community with ability for chromium (VI) removal. The existence of members of Enterobacteriaceae and Rhodocyclaceae families never reported as chromium or uranium removing bacteria, respectively, is also a relevant finding, encouraging the exploitation of microorganisms with new abilities that can be useful for bioremediation.

  5. Anaerobic bio-removal of uranium (VI) and chromium (VI): Comparison of microbial community structure

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Monica [Centro de Ciencias do Mar, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Faleiro, Maria Leonor [IBB - Centro de Biomedicina Molecular e Estrutural, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Chaves, Sandra; Tenreiro, Rogerio [Universidade de Lisboa, Faculdade de Ciencias, Centro de Biodiversidade, Genomica Integrativa e Funcional (BioFIG), Campus de FCUL, Campo Grande 1749-016 Lisboa (Portugal); Santos, Erika [Centro de Ciencias do Mar, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Costa, Maria Clara, E-mail: mcorada@ualg.pt [Centro de Ciencias do Mar, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal)

    2010-04-15

    Several microbial communities, obtained from uranium contaminated and non-contaminated samples, were investigated for their ability to remove uranium (VI) and the cultures capable for this removal were further assessed on their efficiency for chromium (VI) removal. The highest efficiency for removal of both metals was observed on a consortium from a non-contaminated soil collected in Monchique thermal place, which was capable to remove 91% of 22 mg L{sup -1} U(VI) and 99% of 13 mg L{sup -1} Cr(VI). This study revealed that uranium (VI) removing communities have also ability to remove chromium (VI), but when uranium (VI) was replaced by chromium (VI) several differences in the structure of all bacterial communities were observed. TGGE and phylogenetic analysis of 16S rRNA gene showed that the uranium (VI) removing bacterial consortia are mainly composed by members of Rhodocyclaceae family and Clostridium genus. On the other hand, bacteria from Enterobacteriaceae family were detected in the community with ability for chromium (VI) removal. The existence of members of Enterobacteriaceae and Rhodocyclaceae families never reported as chromium or uranium removing bacteria, respectively, is also a relevant finding, encouraging the exploitation of microorganisms with new abilities that can be useful for bioremediation.

  6. Underground laboratories in Europe

    International Nuclear Information System (INIS)

    Coccia, E

    2006-01-01

    The only clear evidence today for physics beyond the standard model comes from underground experiments and the future activity of underground laboratories appears challenging and rich. I review here the existing underground research facilities in Europe. I present briefly the main characteristics, scientific activity and perspectives of these Laboratories and discuss the present coordination actions in the framework of the European Union

  7. A Careful Blasting Technique During Construction of underground Openings for Nuclear Waste Repository

    International Nuclear Information System (INIS)

    Ester, Z.; Vrkljan, D.

    1998-01-01

    Underground nuclear waste repositories are constructed in natural rock formations, with heterogenous compound and structure, and should be accommodated in design and construction according to rock conditions. The quality insurance of underground repository, during and after construction, is most demanding in view of contour and category of excavation. the technology of drilling and blasting, regarding the mechanical excavation, is accommodated in sense of response to cross section magnitude of underground openings, the rock conditions and category, the support performance and other design demands. The high level rock damage around underground openings, that is in opposition with reaching quality insurance. Conventional construction technology can be successful by implementation of controlled blasting technique avoiding extensive rock weakness. (author)

  8. Support for caverns, especially in tunneling and underground mining, e. g. for roadways. Ausbau fuer unterirdische Raeume, insbesondere im Tunnel- und Untertagebergbau, z. B. zum Streckenausbau

    Energy Technology Data Exchange (ETDEWEB)

    Wustinger, H

    1981-10-01

    A water proofed triplex layered permanent support for tunneling and underground mining is described. An adhesive layer is cemented or nailed to the rock. It is a web made from plastic fibres and has a profiled surface. Between this first layer and the permanent concrete support, a plastic foil serves as water seal. This foil is fastened to the first layer by spot welding. (OGR).

  9. Underground space planning in Helsinki

    Directory of Open Access Journals (Sweden)

    Ilkka Vähäaho

    2014-10-01

    Full Text Available This paper gives insight into the use of underground space in Helsinki, Finland. The city has an underground master plan (UMP for its whole municipal area, not only for certain parts of the city. Further, the decision-making history of the UMP is described step-by-step. Some examples of underground space use in other cities are also given. The focus of this paper is on the sustainability issues related to urban underground space use, including its contribution to an environmentally sustainable and aesthetically acceptable landscape, anticipated structural longevity and maintaining the opportunity for urban development by future generations. Underground planning enhances overall safety and economy efficiency. The need for underground space use in city areas has grown rapidly since the 21st century; at the same time, the necessity to control construction work has also increased. The UMP of Helsinki reserves designated space for public and private utilities in various underground areas of bedrock over the long term. The plan also provides the framework for managing and controlling the city's underground construction work and allows suitable locations to be allocated for underground facilities. Tampere, the third most populated city in Finland and the biggest inland city in the Nordic countries, is also a good example of a city that is taking steps to utilise underground resources. Oulu, the capital city of northern Finland, has also started to ‘go underground’. An example of the possibility to combine two cities by an 80-km subsea tunnel is also discussed. A new fixed link would generate huge potential for the capital areas of Finland and Estonia to become a real Helsinki-Tallinn twin city.

  10. Assessment of the mechanical stability of underground excavations

    International Nuclear Information System (INIS)

    Kuroki, Shigemori; Taniguchi, Wataru

    1999-01-01

    Each tunnel in the underground high level radioactive waste repository must be mechanically stable to maintain safety throughout the construction, emplacement operations and closure phase. The mechanical stability of underground excavations were assessed using a theoretical analysis and a finite element method taking a wide range of geological environment in Japan into consideration to establish confidence in the construction of disposal facilities. The results show that it is possible to maintain the mechanical stability with adequate tunnel spacing and disposal pit pitch and proper mechanical support. The procedure used for the analysis of the mechanical stability in the H12 report and the results are described in this report. (author)

  11. Occupational exposure to radon for underground tourist routes in Poland: Doses to lung and the risk of developing lung cancer

    Directory of Open Access Journals (Sweden)

    Katarzyna Walczak

    2017-10-01

    Full Text Available Objectives: Radon concentrations for 31 Polish underground tourist routes were analyzed. The equivalent dose to the lung, the effective dose and the relative risk were calculated for employees of the analyzed routes on the grounds of information on radon concentrations, work time, etc. Material and Methods: The relative risk for lung cancers was calculated using the Biological Effects of Ionizing Radiation (BEIR VI Committee model. Equivalent doses to the lungs of workers were determined using the coefficients calculated by the Kendall and Smith. The conversion coefficient proposed by the International Atomic Energy Agency (IAEA in the report No. 33 was used for estimating the effective doses. Results: In 13 routes, the effective dose was found to be above 1 mSv/year, and in 3 routes, it exceeded 6 mSv/year. For 5 routes, the equivalent dose to lungs was higher than 100 mSv/year, and in 1 case it was as high as 490 mSv/year. In 22.6% of underground workplaces the risk of developing lung cancer among employees was about 2 times higher than that for the general population, and for 1 tourist route it was about 5 times higher. The geometric mean of the relative risk of lung cancer for all workers of underground tourist routes was 1.73 (95% confidence interval (CI: 1.6–1.87. Routes were divided into: caves, mines, post-military underground constructions and urban underground constructions. Conclusions: The difference between levels of the relative risk of developing lung cancer for all types of underground tourist routes was not found to be significant. If we include the professional group of the employees of underground tourist routes into the group of occupational exposure, the number of persons who are included in the Category A due to occupational exposure may increase by about 3/4. The professional group of the employees of underground tourist routes should be monitored for their exposure to radon. Int J Occup Med Environ Health 2017;30(5:687

  12. II-VI semiconductor compounds

    CERN Document Server

    1993-01-01

    For condensed matter physicists and electronic engineers, this volume deals with aspects of II-VI semiconductor compounds. Areas covered include devices and applications of II-VI compounds; Co-based II-IV semi-magnetic semiconductors; and electronic structure of strained II-VI superlattices.

  13. Underground openings production line 2012. Design, production and initial state of the underground openings

    International Nuclear Information System (INIS)

    2013-08-01

    The Underground Openings Line Production Line report describes the design requirements, the design principles, the methods of construction and the target properties for the underground rooms required for the final repository. It is one of five Production Line reports, namely the: Underground Openings Line report, Canister report, Buffer report, Backfill report, Closure report. Together, these reports cover the lifespan of the underground phases of the final repository from the start of construction of the underground rooms to their closure. Posiva has developed reference methods for constructing the underground rooms. Tunnels will be constructed using the drill and blast technique, shafts will be constructed using raise boring and the deposition holes will be constructed by reverse down reaming. Underground openings will be made safe by reinforcement by using rock bolts, net or shotcrete, depending on which type of opening is being considered, and groundwater inflows will be limited by grouting. Posiva's requirements management system (VAHA) sets out the specifications for the enactment of the disposal concept at Olkiluoto under five Levels - 1 to 5, from the most generic to the most specific. In this report, the focus is on Level 4 and 5 requirements, which provide practical guidance for the construction of the underground openings. The design requirements are presented in Level 4 and the design specification in Level 5 In addition to the long-term safety-related requirements included in VAHA, there are additional requirements regarding the operation of underground openings, e.g. space requirements due to the equipment used and its maintenance, operational and fire safety. The current reference design for the disposal facility is presented based on the design requirements and design specifications. During the lifespan of the repository the reference design will be revised and updated according to the design principles as new information is available. Reference

  14. An approach to underground characterization of a disposal vault in granite

    International Nuclear Information System (INIS)

    Everitt, R.A.; Martin, C.D.; Thompson, P.M.

    1994-12-01

    The concept of disposing of nuclear fuel waste by sealing it in a disposal vault in the Canadian Shield is being investigated as part of the Canadian Nuclear Fuel Waste Management Program. Engineered and natural barriers would isolate the waste from the biosphere. Underground characterization and testing have been under way since 1983 at the Underground Research Laboratory in support of this program. This report draws on experience gained at the URL to recommend an approach to underground characterization to obtain information to optimize the design of the excavation and the engineered barriers, and to provide a baseline against which to monitor the performance of the facility during and following its operation. (author). 35 refs., 12 tabs., 49 figs

  15. Cinética e equilíbrio de adsorção dos oxiânions Cr (VI, Mo (VI e Se (VI pelo sal de amônio quaternário de quitosana Kinetics and equilibrium of adsorption of oxyanions Cr (VI, Mo (VI and Se (VI by quaternary ammonium chitosan salt

    Directory of Open Access Journals (Sweden)

    Viviane A. Spinelli

    2005-07-01

    Full Text Available O sal quaternário de quitosana foi sintetizado com cloreto de glicidil trimetil amônio. A modificação química foi caracterizada por espectrometria no IV, RMN de 13C e ¹H, e mmol/g de grupos quaternários presentes na matriz polimérica por condutimetria. A remoção de Cr (VI, Mo (VI e Se (VI, em meio aquoso, foi investigada em processo de batelada. A adsorção mostrou ser dependente do pH para o Cr (VI e Se (VI, com um pH ótimo de adsorção, entre 4,0 a 6,0. Para o Mo (VI a adsorção manteve-se quase constante no intervalo de pH entre 4,0 e 11,5. O modelo de isoterma de Langmuir descreveu melhor os dados de equilíbrio na faixa de concentração investigada. No presente estudo, um grama do sal quaternário de quitosana reticulado com glutaraldeído adsorveu 68,3 mg de Cr, 63,4 mg de Mo e 90,0 mg de Se. A velocidade de adsorção, no processo, segue a equação cinética de pseudo segunda-ordem, sendo que o equilíbrio para os três íons foi alcançado próximo aos 200 minutos. A análise dispersiva de raios-X para o Cr (VI mostrou que o principal mecanismo de adsorção é a troca iônica entre os íons Cl- da superfície do polímero pelos oxiânions. O trocador aniônico apresentou a seguinte ordem de seletividade: Cr (VI > Mo (VI > Se (VI.Quaternary chitosan salt was synthesized in the presence of glycidyl trimetyl ammonium chloride. The polymer was characterized by spectroscopic techniques: infrared, 13C and ¹H NMR, while the amount of quaternary ammonium groups was obtained by condutimetry. The removal of Cr (VI, Mo (VI and Se (VI from aqueous solutions was carried out in batch adsorption processes. The process seemed to be pH dependent for Cr (VI and Se (VI with an optimum pH ranging from 4.0 to 6.0; while for Mo (VI the adsorption remained almost constant within the range between 4.0 and 11.5. The Langmuir isotherm model provided the best fit of the equilibrium data over the whole concentration investigated. In the experiment

  16. U(VI) sorption on kaolinite. Effects of pH, U(VI) concentration and oxyanions

    International Nuclear Information System (INIS)

    Liang Gao; Ziqian Yang; Keliang Shi; Xuefeng Wang; Zhijun Guo; Wangsuo Wu

    2010-01-01

    U(VI) sorption on kaolinite was studied as functions of contact time, pH, U(VI) concentration, solid-to-liquid ratio (m/V) by using a batch experimental method. The effects of sulfate and phosphate on U(VI) sorption were also investigated. It was found that the sorption kinetics of U(VI) can be described by a pseudo-second-order model. Potentiometric titrations at variable ionic strengths indicated that the titration curves of kaolinite were not sensitive to ionic strength, and that the pH of the zero net proton charge (pH PZNPC ) was at 6.9. The sorption of U(VI) on kaolinite increased with pH up to 6.5 and reached a plateau at pH >6.5. The presence of phosphate strongly increased U(VI) sorption especially at pH <5.5, which may be due to formation of ternary surface complexes involving phosphate. In contrast, the presence of sulfate did not cause any apparent effect on U(VI) sorption. A double layer model was used to interpret both results of potentiometric titrations and U(VI) sorption on kaolinite. (author)

  17. An Underground Storage Tank Integrated Demonstration report

    International Nuclear Information System (INIS)

    Quadrel, M.J.; Hunter, V.L.; Young, J.K.; Lini, D.C.; Goldberg, C.

    1993-04-01

    The Waste Characterization Data and Technology Development Needs Assessment provides direct support to the Underground Storage Tank Integrated Demonstration (UST-ID). Key users of the study's products may also include individuals and programs within the US Department of Energy (DOE) Office of Technology Development (EM-50), the Office of Waste Operations (EM-30), and the Office of Environmental Restoration (EM-40). The goal of this work is to provide the UST-ID with a procedure for allocating funds across competing characterization technologies in a timely and defensible manner. It resulted in three primary products: 1. It organizes and summarizes information on underground storage tank characterization data needs. 2. It describes current technology development activity related to each need and flags areas where technology development may be beneficial. 3. It presents a decision process, with supporting software, for evaluating, prioritizing, and integrating possible technology development funding packages. The data presented in this document can be readily updated as the needs of the Waste Operations and Environmental Restoration programs mature and as new and promising technology development options emerge

  18. Mucopolysaccharidosis VI

    Directory of Open Access Journals (Sweden)

    Harmatz Paul

    2010-04-01

    Full Text Available Abstract Mucopolysaccharidosis VI (MPS VI is a lysosomal storage disease with progressive multisystem involvement, associated with a deficiency of arylsulfatase B leading to the accumulation of dermatan sulfate. Birth prevalence is between 1 in 43,261 and 1 in 1,505,160 live births. The disorder shows a wide spectrum of symptoms from slowly to rapidly progressing forms. The characteristic skeletal dysplasia includes short stature, dysostosis multiplex and degenerative joint disease. Rapidly progressing forms may have onset from birth, elevated urinary glycosaminoglycans (generally >100 μg/mg creatinine, severe dysostosis multiplex, short stature, and death before the 2nd or 3rd decades. A more slowly progressing form has been described as having later onset, mildly elevated glycosaminoglycans (generally ARSB gene, located in chromosome 5 (5q13-5q14. Over 130 ARSB mutations have been reported, causing absent or reduced arylsulfatase B (N-acetylgalactosamine 4-sulfatase activity and interrupted dermatan sulfate and chondroitin sulfate degradation. Diagnosis generally requires evidence of clinical phenotype, arylsulfatase B enzyme activity ®, clinical management was limited to supportive care and hematopoietic stem cell transplantation. Galsulfase is now widely available and is a specific therapy providing improved endurance with an acceptable safety profile. Prognosis is variable depending on the age of onset, rate of disease progression, age at initiation of ERT and on the quality of the medical care provided.

  19. KENO-VI Primer: A Primer for Criticality Calculations with SCALE/KENO-VI Using GeeWiz

    International Nuclear Information System (INIS)

    Bowman, Stephen M.

    2008-01-01

    The SCALE (Standardized Computer Analyses for Licensing Evaluation) computer software system developed at Oak Ridge National Laboratory is widely used and accepted around the world for criticality safety analyses. The well-known KENO-VI three-dimensional Monte Carlo criticality computer code is one of the primary criticality safety analysis tools in SCALE. The KENO-VI primer is designed to help a new user understand and use the SCALE/KENO-VI Monte Carlo code for nuclear criticality safety analyses. It assumes that the user has a college education in a technical field. There is no assumption of familiarity with Monte Carlo codes in general or with SCALE/KENO-VI in particular. The primer is designed to teach by example, with each example illustrating two or three features of SCALE/KENO-VI that are useful in criticality analyses. The primer is based on SCALE 6, which includes the Graphically Enhanced Editing Wizard (GeeWiz) Windows user interface. Each example uses GeeWiz to provide the framework for preparing input data and viewing output results. Starting with a Quickstart section, the primer gives an overview of the basic requirements for SCALE/KENO-VI input and allows the user to quickly run a simple criticality problem with SCALE/KENO-VI. The sections that follow Quickstart include a list of basic objectives at the beginning that identifies the goal of the section and the individual SCALE/KENO-VI features that are covered in detail in the sample problems in that section. Upon completion of the primer, a new user should be comfortable using GeeWiz to set up criticality problems in SCALE/KENO-VI. The primer provides a starting point for the criticality safety analyst who uses SCALE/KENO-VI. Complete descriptions are provided in the SCALE/KENO-VI manual. Although the primer is self-contained, it is intended as a companion volume to the SCALE/KENO-VI documentation. (The SCALE manual is provided on the SCALE installation DVD.) The primer provides specific examples of

  20. The planning of future research program of underground laboratories in overseas

    International Nuclear Information System (INIS)

    Honma, Nobuyuki; Tanai, Kenji; Hasegawa, Hiroshi

    2002-02-01

    The objectives of this study is to identify the research issues, which are to be conducted in the future underground research laboratory, about operation and logistics systems for the planning of future research and development program. The research programs and experiments, etc. were investigated for the geological disposal projects in overseas sedimentary rocks and coastal geological environments aiming to reflect in the future underground research facility plan in Japan. In the investigation, information on the engineered-barrier performance, design and construction of underground facilities, tunnel support, transportation and emplacement, and backfilling technology, etc. were collected. Based on these informations, the purpose, the content, and the result of each investigations and tests were arranged. The strategy and the aim in the entire underground research facility, and the flow of investigations and tests, etc. were also arranged from the purpose, the relations and the sequence of each investigation and experiment, and the usage of results, etc. (author)

  1. Experience and prospects of using the pneumatic designs in underground mining

    Energy Technology Data Exchange (ETDEWEB)

    Rakhutin, V.S. [National Mining University of Ukraine, Dnipropetrovsk (Ukraine)

    1999-07-01

    The article reviews the experience of application of pneumatic designs ('flexible shells') in coal mines (pneumatic cogs and supports), ore mines (pneumatic cofferdams and partitions in filling), and in the construction of mines and underground constructions (pneumatic casings, temporary (pilot) supports). 2 refs.

  2. Cranial mononeuropathy VI

    Science.gov (United States)

    ... Abducens palsy; Lateral rectus palsy; VIth nerve palsy; Cranial nerve VI palsy; Sixth nerve palsy; Neuropathy - sixth nerve ... Cranial mononeuropathy VI is damage to the sixth cranial nerve. This nerve is also called the abducens nerve. ...

  3. Global Pursuits: The Underground Railroad

    Science.gov (United States)

    School Arts: The Art Education Magazine for Teachers, 2004

    2004-01-01

    This brief article describes Charles T. Webber's oil on canvas painting, "The Underground Railroad, 1893." The subject of this painting is the Underground Railroad, which today has become an American legend. The Underground Railroad was not a systematic means of transportation, but rather a secretive process that allowed fugitive slaves…

  4. Evaluation of groundwater flow and transport at the Shoal underground nuclear test: An interim report

    International Nuclear Information System (INIS)

    Pohll, G.; Chapman, J.; Hassan, A.; Papelis, C.; Andricevic, R.; Shirley, C.

    1998-07-01

    Since 1962, all United States nuclear tests have been conducted underground. A consequence of this testing has been the deposition of large amounts of radioactive materials in the subsurface, sometimes in direct contact with groundwater. The majority of this testing occurred on the Nevada Test Site, but a limited number of experiments were conducted in other locations. One of these is the subject of this report, the Project Shoal Area (PSA), located about 50 km southeast of Fallon, Nevada. The Shoal test consisted of a 12-kiloton-yield nuclear detonation which occurred on October 26, 1963. Project Shoal was part of studies to enhance seismic detection of underground nuclear tests, in particular, in active earthquake areas. Characterization of groundwater contamination at the Project Shoal Area is being conducted by the US Department of Energy (DOE) under the Federal Facility Agreement and Consent Order (FFACO) with the State of Nevada Department of Environmental Protection and the US Department of Defense (DOD). This order prescribes a Corrective Action Strategy (Appendix VI), which, as applied to underground nuclear tests, involves preparing a Corrective Action Investigation Plan (CAIP), Corrective Action Decision Document (CADD), Corrective Action Plan, and Closure Report. The scope of the CAIP is flow and transport modeling to establish contaminant boundaries that are protective of human health and the environment. This interim report describes the current status of the flow and transport modeling for the PSA

  5. Evaluation of groundwater flow and transport at the Shoal underground nuclear test: An interim report

    Energy Technology Data Exchange (ETDEWEB)

    Pohll, G.; Chapman, J.; Hassan, A.; Papelis, C.; Andricevic, R.; Shirley, C.

    1998-07-01

    Since 1962, all United States nuclear tests have been conducted underground. A consequence of this testing has been the deposition of large amounts of radioactive materials in the subsurface, sometimes in direct contact with groundwater. The majority of this testing occurred on the Nevada Test Site, but a limited number of experiments were conducted in other locations. One of these is the subject of this report, the Project Shoal Area (PSA), located about 50 km southeast of Fallon, Nevada. The Shoal test consisted of a 12-kiloton-yield nuclear detonation which occurred on October 26, 1963. Project Shoal was part of studies to enhance seismic detection of underground nuclear tests, in particular, in active earthquake areas. Characterization of groundwater contamination at the Project Shoal Area is being conducted by the US Department of Energy (DOE) under the Federal Facility Agreement and Consent Order (FFACO) with the State of Nevada Department of Environmental Protection and the US Department of Defense (DOD). This order prescribes a Corrective Action Strategy (Appendix VI), which, as applied to underground nuclear tests, involves preparing a Corrective Action Investigation Plan (CAIP), Corrective Action Decision Document (CADD), Corrective Action Plan, and Closure Report. The scope of the CAIP is flow and transport modeling to establish contaminant boundaries that are protective of human health and the environment. This interim report describes the current status of the flow and transport modeling for the PSA.

  6. GeoViQua: quality-aware geospatial data discovery and evaluation

    Science.gov (United States)

    Bigagli, L.; Papeschi, F.; Mazzetti, P.; Nativi, S.

    2012-04-01

    /tracking information such as provenance of data and metadata), and user-generated metadata (informal user comments, usage information, rating, etc.). Moreover, metadata should include sufficiently complete access information, to allow rich data visualization and propagation. The following main enabling components are currently identified within WP4: - Quality-aware access services, e.g. a quality-aware extension of the OGC Sensor Observation Service (SOS-Q) specification, to support quality constraints for sensor data publishing and access; - Quality-aware discovery services, namely a quality-aware extension of the OGC Catalog Service for the Web (CSW-Q), to cope with quality constrained search; - Quality-augmentation broker (GeoViQua Broker), to support the linking and combination of the existing GCI metadata with GeoViQua- and user-generated metadata required to support the users in selecting the "best" data for their intended use. We are currently developing prototypes of the above quality-enabled geo-search components, that will be assessed in a sensor-based pilot case study in the next months. In particular, the GeoViQua Broker will be integrated with the EuroGEOSS Broker, to implement CSW-Q and federate (either via distribution or harvesting schemes) quality-aware data sources, GeoViQua will constitute a valuable test-bed for advancing the current best practices and standards in geospatial quality representation and exploitation. The research leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/2007-2013) under Grant Agreement n° 265178.

  7. Rokibaar Underground = Rock bar Underground

    Index Scriptorium Estoniae

    2008-01-01

    Rokibaari Underground (Küütri 7, Tartu) sisekujundus, mis pälvis Eesti Sisearhitektide Liidu 2007. a. eripreemia. Sisearhitekt: Margus Mänd (Tammat OÜ). Margus Männist, tema tähtsamad tööd. Plaan, 5 värv. vaadet, foto M. Männist

  8. The underground economy in Romania

    Directory of Open Access Journals (Sweden)

    Adriana Veronica LITRA

    2016-07-01

    Full Text Available The paper aims at covering issues related to the underground economy, activities that compound this phenomenon, its magnitude in Romania and reported to the European average. Underground economy in Romania consists of undeclared work (2/3 from the total and unreported income; it decreased from 33.6% of GDP in 2003 to 28% in 2014, but remained over EU-28 average with about 10 p.p. Among EU-28 countries, only Bulgaria exceeds the size of the underground economy of Romania. The underground economy is a challenge for the leadership of the state which must act simultaneously to stop illegal activities, and to discourage non-declaration of the legal activities. Corruption favours maintaining the underground economy, delays economic development, obstructs democratic processes and affects justice and the law state.

  9. Locating underground uranium deposits

    International Nuclear Information System (INIS)

    Felice, P.E.

    1979-01-01

    Underground uranium deposits are located by placing wires of dosimeters each about 5 to 18 mg/cm 2 thick underground in a grid pattern. Each dosimeter contains a phosphor which is capable of storing the energy of alpha particles. In each pair one dosimeter is shielded from alpha particles with more than 18 mg/cm 2 thick opaque material but not gamma and beta rays and the other dosimeter is shielded with less than 1 mg/cm 2 thick opaque material to exclude dust. After a period underground the dosimeters are heated which releases the stored energy as light. The amount of light produced from the heavily shielded dosimeter is subtracted from the amount of light produced from the thinly shielded dosimeter to give an indication of the location and quantity of uranium underground

  10. Sorption of Cs, Eu and U(VI) onto rock samples from Nizhnekansky massive

    Energy Technology Data Exchange (ETDEWEB)

    Petrov, V.; Vlasova, I.; Kalmykov, S. [Lomonosov Moscow State University (Russian Federation); Kuzmenkova, N. [Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Science (Russian Federation); Petrov, V.; Poluektov, V. [Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences - IGEM RAS (Russian Federation)

    2014-07-01

    The accepted in Russia concept for high level wastes (HLW) and spent nuclear fuel (SNF) disposal is based on their isolation into the deep underground crystalline rock formations. The 'Eniseysky' area (Nizhnekansky massive) is supposed as the most perspective location for the future HLW and SNF repository. Core materials from different areas of Nizhnekasnsky massive have been studied in terms of petrographic and mineralogical characterization; definition of filtration, elastic, petro-physical and strength properties; estimation of hydrothermal-metasomatic transformation of rocks. We used both undisturbed sliced cores and crushed material for the sorption experiments. Preliminary results of uranium sorption show some significant differences between used rock samples from different depth in sorption rate and pH-dependence. In all cases maximum sorption (more than 90%) is reached in 2-3 weeks. The pH-dependence of sorbed uranium fraction has typical hump-shape: increase of sorption percentage with increasing pH values to 6, plateau (90-98 % of uranium sorbed), decrease of sorption percentage with increasing pH values from 8 due to U(VI) hydrolysis. In the case of cesium the sorption maximum is reached within 10-12 days and in the case of europium - about 5 days. All radionuclides sorbed preferentially onto dark minerals. Local distribution and preferential sorption of cesium, europium and uranium (VI) onto different minerals within the sample were studied by radiography, SEM-EDX, etc. These data accompanying with rock sample composition will allow the development of quantitative model for Cs, Eu and U(VI) sorption onto investigated rocks. Document available in abstract form only. (authors)

  11. Enzymatic reduction of U(VI) in groundwaters; Reduction enzymatique de U(VI) dans des eaux souterraines

    Energy Technology Data Exchange (ETDEWEB)

    Addelouas, A.; Gong, W. [Center for Radioactive Waste Management, Advanced Materials Laboratory, 1001 University, Albuquerque (United States); Lutze, W.; Nuttall, E. [New Mexico Univ., Albuquerque, NM (United States). Dept. of Chemical and Nuclear Engineering; Fritz, B.; Crovisier, J.L. [Centre National de la Recherche Scientifique (CNRS), 67 - Strasbourg (France). Centre de Sedimentologie et Geochimie de la Surface

    1999-03-01

    The use of enzymatic reduction of U(VI) in remediation of groundwater contaminated with U(VI) is receiving considerable attention. Certain strains of bacteria can combine the oxidation of an organic compound to the reduction of U(VI) to U(IV), which precipitates as uraninite. In the present study, we tested the reduction of U(VI) in groundwaters with various origins and compositions. In all groundwaters u(VI) was reduced by sulfate reducing bacteria that had been activated by ethanol and tri-metaphosphate. The reduction rate of U(VI) depends on sulfate concentration in water and the abundance of bacteria in the system. This work shows that bacteria capable of U(VI) reduction are ubiquitous in nature, and suggests the possibility of a large application of the enzymatic reduction of U(VI) for in situ clean up of groundwaters contaminated with uranium. (authors) 12 refs.

  12. Concept of underground nuclear power plant

    International Nuclear Information System (INIS)

    Onishi, Sotoaki

    1976-01-01

    The concept of constructing nuclear power plants on the sea or underground as the future sitting is based on moving the present power plants on the ground with actual results to the sea or underground without changing the design. The underground nuclear power plants have many similar points to underground hydro-electric power stations with many achievements in the construction viewpoint, though they have their proper difficult problems. Of course, it requires to excavate larger underground caves than the case of underground hydro-electric power plants. The maximum dimensions of the caves have been determined through experience in practice. Therefore the developments of design theory and construction technique are desirable in this field. In discussing underground construction, two evaluating methods are considered for the shielding effect of base rocks. The minimum vertical distance up to ground surface from the center of the cave differs depending upon the in-cave pressure, and the conditions of base rock, soil and underground water in case of the accident assumed in the design, and is approximately 60m, if the cave is assumed to be an indefinite cylindrical shape, by the safer side calculation in the above two evaluations. (Wakatsuki, Y.)

  13. Third symposium on underground mining

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-01-01

    The Third Symposium on Underground Mining was held at the Kentucky Fair and Exposition Center, Louisville, KY, October 18--20, 1977. Thirty-one papers have been entered individually into EDB and ERA. The topics covered include mining system (longwall, shortwall, room and pillar, etc.), mining equipment (continuous miners, longwall equipment, supports, roof bolters, shaft excavation equipment, monitoring and control systems. Maintenance and rebuilding facilities, lighting systems, etc.), ventilation, noise abatement, economics, accidents (cost), dust control and on-line computer systems. (LTN)

  14. Examination of earthquake Ground Motion in the deep underground environment of Japan

    International Nuclear Information System (INIS)

    Goto, J.; Tsuchi, H.; Mashimo, M.

    2009-01-01

    Among the possible impacts of earthquakes on the geological disposal system, ground motion is not included in the criteria for selecting a candidate repository site because, in general, ground motion deep underground is considered to be smaller than at the surface. Also, after backfilling/closure, the repository moves together with the surrounding rock. We have carried out a detailed examination of earthquake ground motion deep underground using extensive data from recent observation networks to support the above assumption. As a result, it has been reconfirmed that earthquake ground motion deep underground is relatively smaller than at the surface. Through detailed analysis of data, we have identified the following important parameters for evaluating earthquake ground motion deep underground: depth and velocity distribution of the rock formations of interest, the intensity of the short period component of earthquakes and incident angle of seismic waves to the rock formations. (authors)

  15. Underground water stress release models

    Science.gov (United States)

    Li, Yong; Dang, Shenjun; Lü, Shaochuan

    2011-08-01

    The accumulation of tectonic stress may cause earthquakes at some epochs. However, in most cases, it leads to crustal deformations. Underground water level is a sensitive indication of the crustal deformations. We incorporate the information of the underground water level into the stress release models (SRM), and obtain the underground water stress release model (USRM). We apply USRM to the earthquakes occurred at Tangshan region. The analysis shows that the underground water stress release model outperforms both Poisson model and stress release model. Monte Carlo simulation shows that the simulated seismicity by USRM is very close to the real seismicity.

  16. Kinetic evaluation of propyne surface diffusivity on silica-alumina-supported chromium(VI) using positron annihilation surface detection

    International Nuclear Information System (INIS)

    Ferrieri, R.A.; Wolf, A.P.

    1984-01-01

    A study has been performed on the rate of the translational surface diffusivity of propyne on a silica-alumina-supported Cr(VI) catalyst. This rate was measured via nonchemical acetylene-propyne sorbate interactions coupled with positron annihilation surface detection (PASD). The surface displacement rate of [ 11 C]acetylene by propyne was measured in a transient experiment as a function of the adjacent Cr-site distance and correlated to propyne surface diffusivity, D/sub s/. Results indicated that D/sub s/ increased linearly when the adjacent site distance was decreased for catalysts loaded with between 0.08 and 0.8 wt % of chromium. However, D/sub s/ fell off drastically to nearly zero when greater Cr-site dispersion was achieved at support loadings below 0.08 wt % of chromium. Catalytic selectivity for p-xylene production was also measured as a function of D/sub s/ and was shown to have a strong dependence of its rate. 25 references, 4 figures

  17. The Deep Underground Science and Engineering Laboratory at Homestake

    Energy Technology Data Exchange (ETDEWEB)

    Lesko, Kevin T [Department of Physics, University of California Berkeley and the Institute for Nuclear and Particle Astrophysics, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, MS50R5239, Berkeley, CA 94720-8146 (United States)], E-mail: KTLesko@lbl.gov

    2008-11-01

    The National Science Foundation and the international underground science community are well into establishing a world-class, multidisciplinary Deep Underground Science and Engineering Laboratory (DUSEL) at the former Homestake mine in Lead South Dakota. The NSF's review committee, following the first two NSF solicitations, selected the Homestake Proposal and site as the prime location to be developed into an international research facility. Homestake DUSEL will provide much needed underground research space to help relieve the worldwide shortage, particularly at great depth, and will develop research campuses at several different depths to satisfy the research requirements for the coming decades. The State of South Dakota has demonstrated remarkable support for the project and has secured the site with the transfer from the Homestake Mining Corp. The State, through its Science and Technology Authority with state funds and those of a philanthropic donor has initiated rehabilitation of the surface and underground infrastructure including the Ross and Yates hoists accessing the 4850 Level (feet below ground, 4100 to 4200 mwe). The scientific case for DUSEL and the progress in establishing the preliminary design of the facility and the associated suite of experiments to be funded along with the facility by the NSF are presented.

  18. A Fiber Bragg Grating-Based Monitoring System for Roof Safety Control in Underground Coal Mining

    Directory of Open Access Journals (Sweden)

    Yiming Zhao

    2016-10-01

    Full Text Available Monitoring of roof activity is a primary measure adopted in the prevention of roof collapse accidents and functions to optimize and support the design of roadways in underground coalmines. However, traditional monitoring measures, such as using mechanical extensometers or electronic gauges, either require arduous underground labor or cannot function properly in the harsh underground environment. Therefore, in this paper, in order to break through this technological barrier, a novel monitoring system for roof safety control in underground coal mining, using fiber Bragg grating (FBG material as a perceived element and transmission medium, has been developed. Compared with traditional monitoring equipment, the developed, novel monitoring system has the advantages of providing accurate, reliable, and continuous online monitoring of roof activities in underground coal mining. This is expected to further enable the prevention of catastrophic roof collapse accidents. The system has been successfully implemented at a deep hazardous roadway in Zhuji Coal Mine, China. Monitoring results from the study site have demonstrated the advantages of FBG-based sensors over traditional monitoring approaches. The dynamic impacts of progressive face advance on roof displacement and stress have been accurately captured by the novel roadway roof activity and safety monitoring system, which provided essential references for roadway support and design of the mine.

  19. Occupational exposure to radon for underground tourist routes in Poland: Doses to lung and the risk of developing lung cancer.

    Science.gov (United States)

    Walczak, Katarzyna; Olszewski, Jerzy; Politański, Piotr; Zmyślony, Marek

    2017-07-14

    Radon concentrations for 31 Polish underground tourist routes were analyzed. The equivalent dose to the lung, the effective dose and the relative risk were calculated for employees of the analyzed routes on the grounds of information on radon concentrations, work time, etc. The relative risk for lung cancers was calculated using the Biological Effects of Ionizing Radiation (BEIR) VI Committee model. Equivalent doses to the lungs of workers were determined using the coefficients calculated by the Kendall and Smith. The conversion coefficient proposed by the International Atomic Energy Agency (IAEA) in the report No. 33 was used for estimating the effective doses. In 13 routes, the effective dose was found to be above 1 mSv/year, and in 3 routes, it exceeded 6 mSv/year. For 5 routes, the equivalent dose to lungs was higher than 100 mSv/year, and in 1 case it was as high as 490 mSv/year. In 22.6% of underground workplaces the risk of developing lung cancer among employees was about 2 times higher than that for the general population, and for 1 tourist route it was about 5 times higher. The geometric mean of the relative risk of lung cancer for all workers of underground tourist routes was 1.73 (95% confidence interval (CI): 1.6-1.87). Routes were divided into: caves, mines, post-military underground constructions and urban underground constructions. The difference between levels of the relative risk of developing lung cancer for all types of underground tourist routes was not found to be significant. If we include the professional group of the employees of underground tourist routes into the group of occupational exposure, the number of persons who are included in the Category A due to occupational exposure may increase by about 3/4. The professional group of the employees of underground tourist routes should be monitored for their exposure to radon. Int J Occup Med Environ Health 2017;30(5):687-694. This work is available in Open Access model and licensed under a CC

  20. The hazardous nature of small scale underground mining in Ghana

    Directory of Open Access Journals (Sweden)

    K.J. Bansah

    2016-01-01

    Full Text Available Small scale mining continues to contribute significantly to the growth of Ghana's economy. However, the sector poses serious dangers to human health and the environment. Ground failures resulting from poorly supported stopes have led to injuries and fatalities in recent times. Dust and fumes from drilling and blasting of ore present health threats due to poor ventilation. Four prominent small scale underground mines were studied to identify the safety issues associated with small scale underground mining in Ghana. It is recognized that small scale underground mining in Ghana is inundated with unsafe acts and conditions including stope collapse, improper choice of working tools, absence of personal protective equipment and land degradation. Inadequate monitoring of the operations and lack of regulatory enforcement by the Minerals Commission of Ghana are major contributing factors to the environmental, safety and national security issues of the operations.

  1. Safety risk management of underground engineering in China: Progress, challenges and strategies

    Directory of Open Access Journals (Sweden)

    Qihu Qian

    2016-08-01

    Full Text Available Underground construction in China is featured by large scale, high speed, long construction period, complex operation and frustrating situations regarding project safety. Various accidents have been reported from time to time, resulting in serious social impact and huge economic loss. This paper presents the main progress in the safety risk management of underground engineering in China over the last decade, i.e. (1 establishment of laws and regulations for safety risk management of underground engineering, (2 implementation of the safety risk management plan, (3 establishment of decision support system for risk management and early-warning based on information technology, and (4 strengthening the study on safety risk management, prediction and prevention. Based on the analysis of the typical accidents in China in the last decade, the new challenges in the safety risk management for underground engineering are identified as follows: (1 control of unsafe human behaviors; (2 technological innovation in safety risk management; and (3 design of safety risk management regulations. Finally, the strategies for safety risk management of underground engineering in China are proposed in six aspects, i.e. the safety risk management system and policy, law, administration, economy, education and technology.

  2. Modification of Poly- and Oligosaccharides with Os(VI) pyridine. Voltammetry of the Os(VI) Adducts Obtained by Ligand Exchange

    Czech Academy of Sciences Publication Activity Database

    Trefulka, Mojmír; Paleček, Emil

    2013-01-01

    Roč. 25, č. 8 (2013), s. 1813-1817 ISSN 1040-0397 R&D Projects: GA ČR(CZ) GAP301/11/2055 Institutional research plan: CEZ:AV0Z50040702 Institutional support: RVO:68081707 Keywords : OS(VI)-MODIFIED POLYSACCHARIDES * STRIPPING VOLTAMMETRY * TRANS-ESTERIFICATION Subject RIV: BO - Biophysics Impact factor: 2.502, year: 2013

  3. Simultaneous Treatment of Agro-Industrial and Industrial Wastewaters: Case Studies of Cr(VI/Second Cheese Whey and Cr(VI/Winery Effluents

    Directory of Open Access Journals (Sweden)

    Triantafyllos I. Tatoulis

    2018-03-01

    Full Text Available Hexavalent chromium (Cr(VI was co-treated either with second cheese whey (SCW or winery effluents (WE using pilot-scale biological trickling filters in series under different operating conditions. Two pilot-scale filters in series using plastic support media were used in each case. The first filter (i.e., Cr-SCW-filter or Cr-WE-filter aimed at Cr(VI reduction and the partial removal of dissolved chemical oxygen demand (d-COD from SCW or WE and was inoculated with indigenous microorganisms originating from industrial sludge. The second filter in series (i.e., SCW-filter or WE-filter aimed at further d-COD removal and was inoculated with indigenous microorganisms that were isolated from SCW or WE. Various Cr(VI (5–100 mg L−1 and SCW or WE (d-COD, 1000–25,000 mg L−1 feed concentrations were tested. Based on the experimental results, the sequencing batch reactor operating mode with recirculation of 0.5 L min−1 proved very efficient since it led to complete Cr(VI reduction in the first filter in series and achieved high Cr(VI reduction rates (up to 36 and 43 mg L−1 d−1, for SCW and WW, respectively. Percentage d-COD removal for SCW and WE in the first filter was rather low, ranging from 14 to 42.5% and from 4 to 29% in the Cr-SCW-filter and Cr-WE-filter, respectively. However, the addition of the second filter in series enhanced total d-COD removal to above 97% and 90.5% for SCW and WE, respectively. The above results indicate that agro-industrial wastewater could be used as a carbon source for Cr(VI reduction, while the use of two trickling filters in series could effectively treat both industrial and agro-industrial wastewaters with very low installation and operational costs.

  4. The Sanford Underground Research Facility at Homestake

    International Nuclear Information System (INIS)

    Heise, J.

    2015-01-01

    The former Homestake gold mine in Lead, South Dakota, has been transformed into a dedicated facility to pursue underground research in rare-process physics, as well as offering research opportunities in other disciplines such as biology, geology and engineering. A key component of the Sanford Underground Research Facility (SURF) is the Davis Campus, which is in operation at the 4850-foot level (4300 m.w.e.) and currently hosts two main physics projects: the LUX dark matter experiment and the MAJORANA DEMONSTRATOR neutrinoless double-beta decay experiment. In addition, two low-background counters currently operate at the Davis Campus in support of current and future experiments. Expansion of the underground laboratory space is underway at the 4850L Ross Campus in order to maintain and enhance low-background assay capabilities as well as to host a unique nuclear astrophysics accelerator facility. Plans to accommodate other future experiments at SURF are also underway and include the next generation of direct-search dark matter experiments and the Fermilab-led international long-baseline neutrino program. Planning to understand the infrastructure developments necessary to accommodate these future projects is well advanced and in some cases have already started. SURF is a dedicated research facility with significant expansion capability

  5. The Sanford Underground Research Facility at Homestake

    International Nuclear Information System (INIS)

    Heise, J

    2015-01-01

    The former Homestakegold mine in Lead, South Dakota has been transformed into a dedicated facility to pursue underground research in rare-process physics, as well as offering research opportunities in other disciplines such as biology, geology and engineering. A key component of the Sanford Underground Research Facility (SURF) is the Davis Campus, which is in operation at the 4850-foot level (4300 m.w.e.) and currently hosts two main physics projects: the LUX dark matter experiment and the MAJORANA DEMONSTRATOR neutrinolessdouble-beta decay experiment. In addition, two low-background counters currently operate at the Davis Campus in support of current and future experiments. Expansion of the underground laboratory space is underway at the 4850L Ross Campus in order to maintain and enhance low- background assay capabilities as well as to host a unique nuclear astrophysics accelerator facility. Plans to accommodate other future experiments at SURF are also underway and include the next generation of direct-search dark matter experiments and the Fermilab-led international long- baseline neutrino program. Planning to understand the infrastructure developments necessary to accommodate these future projects is well advanced and in some cases have already started. SURF is a dedicated research facility with significant expansion capability. (paper)

  6. 30 CFR 75.804 - Underground high-voltage cables.

    Science.gov (United States)

    2010-07-01

    ... AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Underground High-Voltage Distribution § 75.804 Underground high-voltage cables. (a) Underground high-voltage cables used in resistance... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Underground high-voltage cables. 75.804 Section...

  7. Importance of c-Type cytochromes for U(VI reduction by Geobacter sulfurreducens

    Directory of Open Access Journals (Sweden)

    Leang Ching

    2007-03-01

    Full Text Available Abstract Background In order to study the mechanism of U(VI reduction, the effect of deleting c-type cytochrome genes on the capacity of Geobacter sulfurreducens to reduce U(VI with acetate serving as the electron donor was investigated. Results The ability of several c-type cytochrome deficient mutants to reduce U(VI was lower than that of the wild type strain. Elimination of two confirmed outer membrane cytochromes and two putative outer membrane cytochromes significantly decreased (ca. 50–60% the ability of G. sulfurreducens to reduce U(VI. Involvement in U(VI reduction did not appear to be a general property of outer membrane cytochromes, as elimination of two other confirmed outer membrane cytochromes, OmcB and OmcC, had very little impact on U(VI reduction. Among the periplasmic cytochromes, only MacA, proposed to transfer electrons from the inner membrane to the periplasm, appeared to play a significant role in U(VI reduction. A subpopulation of both wild type and U(VI reduction-impaired cells, 24–30%, accumulated amorphous uranium in the periplasm. Comparison of uranium-accumulating cells demonstrated a similar amount of periplasmic uranium accumulation in U(VI reduction-impaired and wild type G. sulfurreducens. Assessment of the ability of the various suspensions to reduce Fe(III revealed no correlation between the impact of cytochrome deletion on U(VI reduction and reduction of Fe(III hydroxide and chelated Fe(III. Conclusion This study indicates that c-type cytochromes are involved in U(VI reduction by Geobacter sulfurreducens. The data provide new evidence for extracellular uranium reduction by G. sulfurreducens but do not rule out the possibility of periplasmic uranium reduction. Occurrence of U(VI reduction at the cell surface is supported by the significant impact of elimination of outer membrane cytochromes on U(VI reduction and the lack of correlation between periplasmic uranium accumulation and the capacity for uranium

  8. Uranium(VI) speciation by spectroscopy

    International Nuclear Information System (INIS)

    Meinrath, G.

    1997-01-01

    The application of UV-Vis and time-resolved laser-induced fluorescence (TRLF) spectroscopies to direct of uranium(VI) in environmental samples offers various prospects that have, however, serious limitations. While UV-Vis spectroscopy is probably not sensitive enough to detect uranium(VI) species in the majority of environmental samples, TRLFS is principially able to speciate uranium(VI) at very low concentration levels in the nanomol range. Speciation by TRLFS can be based on three parameters: excitation spectrum, emission spectrum and lifetime of the fluorescence emission process. Due to quenching effects, the lifetime may not be expected to be as characteristics as, e.g., the emission spectrum. Quenching of U(VI) fluorescence by reaction with organic substances, inorganic ions and formation of carbonate radicals is one important limiting factor in the application of U(VI) fluorescence spectroscopy. Fundamental photophysical criteria are illustrated using UV-Vis and fluorescence spectra of U(VI) hydrolysis and carbonato species as examples. (author)

  9. Sediment studies of the biological factors controlling the reduction of U(VI)

    International Nuclear Information System (INIS)

    Lovley, Derek R.

    2004-01-01

    Studies were conducted primarily with sediments, both in laboratory incubations and in a field experiment, with supporting studies with pure cultures. To our knowledge the sediment studies were the first on microbial U(VI) reduction in actual uranium-contaminated subsurface sediments, under conditions that mimic those found in situ. Important findings included: (1) U(VI) reduction is a biotic process in subsurface sediments. (2) U(VI) reduction can be stimulated most effectively with the addition of acetate. Although it had been speculated that microbial U(VI) reduction might be capable of this type of environmental remediation ever since the discovery of microbial U(VI) reduction, this had not been previously demonstrated under environmentally relevant conditions. (3) U(VI) is reduced concurrently with Fe(III) and prior to sulfate reduction. U(VI) and Fe(III) reduction proceeded concurrently, accompanied by a dramatic enrichment in organisms in the Geobacteraceae. Sulfate-reducing microorganisms do not appear to be important components of the microbial community reducing U(VI) in these subsurface sediments. (4) Nitrate has important influences on U(VI) reduction. Nitrate inhibits the reduction of metals until nitrate is depleted. Fe(III)-reducing microorganisms such as Geobacter metallireducens and Desulfitobacterium species can oxidize Fe(II) with the reduction of nitrate which is an important consideration because our previous studies have demonstrated that freshly precipitated Fe(III) oxides can reoxidize U(IV) to U(VI). The discovery that G. metallireducens can ''run backwards'' and oxidize U(IV) when nitrate is present reveals another mechanism preventing precipitation of U(IV) in the presence of nitrate as well as potential novel strategy for removing uranium from the subsurface after a site has been remediated. (5) Importance of understanding Fe(III) forms available for microbial reduction. Fe(III) is orders of magnitude more abundant than U(VI) as an

  10. Enlarging the underground hydroelectric plant at Villarino, Spain

    Energy Technology Data Exchange (ETDEWEB)

    Oriard, L.L.

    1997-05-01

    Near the village of Villarino de los Aires, in the province of Salamanca, Spain, was an existing underground hydroelectric power plant. A major enlargement was undertaken to increase the electrical generating capacity, under a contract awarded to a joint venture of Dragados y Construcciones, S. A. (Spain), Entrecanales y Tavora, S. A. (Spain), and S.A. Conrad Zschokke (Switzerland). The enlargement required the excavation of a large and complex underground system of tunnels, shafts and chambers adjacent to existing facilities and interconnected with these facilities. The existing machine hall and transformer chamber were both extended, requiring the blasting of the existing end walls. The drilling, blasting and excavating of the underground system had to be done without damage to existing underground chambers and tunnels, or any of the existing structures, equipment or instrumentation facilities, often within just a few feet of the blasting. This required careful control of vibrations, airblast overpressures and dust. Because the only available non-electric detonating systems were found to be unreliable and unsafe, electric systems would be preferred if they could be used in a safe manner at this site. High electrical potentials existed at the site, and the facilities could not be shut down. Electrical fields were studied carefully, both in the underground environment and above the ground surface. Based on these results, it was concluded that electric detonators could be used if special blasting procedures were developed and followed. In accord with contracting practices of this Spanish agency, the contract was not awarded to the lowest bidder, but to the bidder who demonstrated the best understanding of the project and who presented the best technical proposal for conducting the work to a conclusion that would be satisfactory to the owner. The development of the technical proposal was a two-month effort for a technical group and support staff, prepared in Madrid.

  11. Underground storage of nuclear waste

    International Nuclear Information System (INIS)

    Russell, J.E.

    1977-06-01

    The objective of the National Waste Terminal Storage (NWTS) Program is to provide facilities in various deep geologic formations at multiple locations in the United States which will safely dispose of commerical radioactive waste. The NWTS Program is being administered for the Energy Research and Development Administration (ERDA) by the Office of Waste Isolation (OWI), Union Carbide Corporation, Nuclear Division. OWI manages projects that will lead to the location, construction, and operation of repositories, including all surface and underground engineering and facility design projects and technical support projects. 7 refs., 5 figs

  12. Underground storage of nuclear waste

    Energy Technology Data Exchange (ETDEWEB)

    Russell, J E

    1977-12-01

    The objective of the National Waste Terminal Storage (NWTS) Program is to provide facilities in various deep geologic formations at multiple locations in the United States which will safely dispose of commercial radioactive waste. The NWTS Program is being administered for the Energy Research and Development Administration (ERDA) by the Office of Waste Isolation (OWI), Union Carbide Corporation, Nuclear Division. OWI manages projects that will lead to the location, construction, and operation of repositories, including all surface and underground engineering and facility design projects and technical support projects.

  13. Underground coal mining - methods, equipment developments and trends

    Energy Technology Data Exchange (ETDEWEB)

    Singhal, R

    1988-12-01

    Underground mines are truly beginning to accept the so-called 'high tech' technology evident in other industries. Automation, remote control and robotics have taken an added significance. Wireless communication, mine-wide equipment health and performance monitoring, and transmission of data from deeper levels to surface is moving towards becoming the norm. There is emphasis on developing and applying continuous mining systems, as well as on modifying cyclical discontinuous methods to continuous systems. Multi-purpose equipment is also being developed. Technology transfer is playing its role - equipment and systems from surface coal mining are being applied to underground mining and vice-versa. At the American Mining Congress Exhibition held in Chicago in April 1988, a variety of equipment for underground mining was displayed including coal face equipment such as shearer loaders, conveyors and powered supports, and equipment for room-and-pillar coal mining. The trend continues to be towards high power machines equipped with a variety of electronics and sensors, safety devices, and alarm systems. Ancillary equipment on display covered a variety of cutting drums, cutting tools, conveying equipment and so on. In room-and-pillar mining, the overall emphasis was on moving away from the cyclical nature of the work. Transportation by shuttle cars must be replaced by continuous transport systems such as conveyors. Experience from Australia has shown that the application of continuous haulage and breaker line supports has permitted a doubling of production from room-and-pillar systems. Production levels of 3,000tpd have already been achieved, and 4,000tpd is considered achievable.

  14. Differential Killing of Salmonella enterica Serovar Typhi by Antibodies Targeting Vi and Lipopolysaccharide O:9 Antigen.

    Directory of Open Access Journals (Sweden)

    Peter J Hart

    Full Text Available Salmonella enterica serovar Typhi expresses a capsule of Vi polysaccharide, while most Salmonella serovars, including S. Enteritidis and S. Typhimurium, do not. Both S. Typhi and S. Enteritidis express the lipopolysaccharide O:9 antigen, yet there is little evidence of cross-protection from anti-O:9 antibodies. Vaccines based on Vi polysaccharide have efficacy against typhoid fever, indicating that antibodies against Vi confer protection. Here we investigate the role of Vi capsule and antibodies against Vi and O:9 in antibody-dependent complement- and phagocyte-mediated killing of Salmonella. Using isogenic Vi-expressing and non-Vi-expressing derivatives of S. Typhi and S. Typhimurium, we show that S. Typhi is inherently more sensitive to serum and blood than S. Typhimurium. Vi expression confers increased resistance to both complement- and phagocyte-mediated modalities of antibody-dependent killing in human blood. The Vi capsule is associated with reduced C3 and C5b-9 deposition, and decreased overall antibody binding to S. Typhi. However, purified human anti-Vi antibodies in the presence of complement are able to kill Vi-expressing Salmonella, while killing by anti-O:9 antibodies is inversely related to Vi expression. Human serum depleted of antibodies to antigens other than Vi retains the ability to kill Vi-expressing bacteria. Our findings support a protective role for Vi capsule in preventing complement and phagocyte killing of Salmonella that can be overcome by specific anti-Vi antibodies, but only to a limited extent by anti-O:9 antibodies.

  15. Differential Killing of Salmonella enterica Serovar Typhi by Antibodies Targeting Vi and Lipopolysaccharide O:9 Antigen.

    Science.gov (United States)

    Hart, Peter J; O'Shaughnessy, Colette M; Siggins, Matthew K; Bobat, Saeeda; Kingsley, Robert A; Goulding, David A; Crump, John A; Reyburn, Hugh; Micoli, Francesca; Dougan, Gordon; Cunningham, Adam F; MacLennan, Calman A

    2016-01-01

    Salmonella enterica serovar Typhi expresses a capsule of Vi polysaccharide, while most Salmonella serovars, including S. Enteritidis and S. Typhimurium, do not. Both S. Typhi and S. Enteritidis express the lipopolysaccharide O:9 antigen, yet there is little evidence of cross-protection from anti-O:9 antibodies. Vaccines based on Vi polysaccharide have efficacy against typhoid fever, indicating that antibodies against Vi confer protection. Here we investigate the role of Vi capsule and antibodies against Vi and O:9 in antibody-dependent complement- and phagocyte-mediated killing of Salmonella. Using isogenic Vi-expressing and non-Vi-expressing derivatives of S. Typhi and S. Typhimurium, we show that S. Typhi is inherently more sensitive to serum and blood than S. Typhimurium. Vi expression confers increased resistance to both complement- and phagocyte-mediated modalities of antibody-dependent killing in human blood. The Vi capsule is associated with reduced C3 and C5b-9 deposition, and decreased overall antibody binding to S. Typhi. However, purified human anti-Vi antibodies in the presence of complement are able to kill Vi-expressing Salmonella, while killing by anti-O:9 antibodies is inversely related to Vi expression. Human serum depleted of antibodies to antigens other than Vi retains the ability to kill Vi-expressing bacteria. Our findings support a protective role for Vi capsule in preventing complement and phagocyte killing of Salmonella that can be overcome by specific anti-Vi antibodies, but only to a limited extent by anti-O:9 antibodies.

  16. The deep underground science and engineering laboratory at Homestake

    Energy Technology Data Exchange (ETDEWEB)

    Lesko, Kevin T, E-mail: ktlesko@lbl.go [Department of Physics, University of California Berkeley and Institute for Nuclear and Particle Astrophysics, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, MS 50R5239, Berkeley, CA 94720-8156 (United States)

    2009-06-01

    The US National Science Foundation and the US underground science community are well into the campaign to establish a world-class, multi-disciplinary deep underground science and engineering laboratory - DUSEL. The NSF's review committee, following the first two NSF solicitations, selected Homestake as the prime site to be developed into an international, multidisciplinary, world-class research facility. Homestake DUSEL will provide much needed underground research space to help relieve the worldwide shortage, particularly at great depth, and will develop research campuses at different depths to satisfy the research requirements for the coming decades. The State of South Dakota has demonstrated remarkable support for the project and has secured the site with the transfer of the former Homestake Gold Mine and has initiated re-entry and rehabilitation of the facility to host a modest interim science program with state funds and those from a substantial philanthropic donor. I review the scientific case for DUSEL and the progress in developing the preliminary design of DUSEL in Homestake and the initial suite of experiments to be funded along with the facility.

  17. Underground Nuclear Testing Program, Nevada Test Site

    International Nuclear Information System (INIS)

    1975-09-01

    The Energy Research and Development Administration (ERDA) continues to conduct an underground nuclear testing program which includes tests for nuclear weapons development and other tests for development of nuclear explosives and methods for their application for peaceful uses. ERDA also continues to provide nuclear explosive and test site support for nuclear effects tests sponsored by the Department of Defense. This Supplement extends the Environmental Statement (WASH-1526) to cover all underground nuclear tests and preparations for tests of one megaton (1 MT) or less at the Nevada Test Site (NTS) during Fiscal Year 1976. The test activities covered include numerous continuing programs, both nuclear and non-nuclear, which can best be conducted in a remote area. However, if nuclear excavation tests or tests of yields above 1 MT or tests away from NTS should be planned, these will be covered by separate environmental statements

  18. Effect of Salicylic and Picolinic Acids on the Adsorption of U(VI) onto Oxides

    International Nuclear Information System (INIS)

    Park, Kyoung Kyun; Jung, Euo Chang; Cho, Hye Ryun; Song, Kyu Seok

    2009-01-01

    The effect of organic acids on the adsorption of U(VI) onto oxide surfaces (TiO 2 (anatase), SiO 2 (amorphous) and Al 2 O-3(amorphous)) has been investigated. Two different organic acids, salicylic and picolinic acids, were used. Changes of adsorption ratio of U(VI), which depend on the existence of organic acids in a sample, were measured as a function of pH. Quantities of adsorbed organic acids, which depend on the existence of U(VI) in a sample, were also measured as a function of pH. It is confirmed that the soluble complex formation of U(VI) with organic acids can deteriorate the adsorption of U(VI) onto TiO 2 surface. It is noteworthy that salicylic acid does not affect the adsorption of U(VI) onto SiO 2 surface, however, picolinic acid enhances the adsorption of U(VI) onto SiO 2 surface. The latter effect can be understood by considering the formation of a ternary surface complex on SiO 2 surface, which was confirmed by the co-adsorption of picolinic acid with U(VI) and the change in a fluorescence spectra of U(VI) on surface, In the case of Al 2 O-3, organic acids themselves were largely adsorbed onto a surface without deteriorating the adsorption of U(VI). This would support the possibility of a ternary surface complex formation on the Al 2 O-3 surface, and an additional spectroscopic study is required.

  19. Diverse anaerobic Cr(VI) tolerant bacteria from Cr(VI)-contaminated 100H site at Hanford

    Science.gov (United States)

    Chakraborty, R.; Phan, R.; Lam, S.; Leung, C.; Brodie, E. L.; Hazen, T. C.

    2007-12-01

    Hexavalent Chromium [Cr(VI)] is a widespread contaminant found in soil, sediment, and ground water. Cr(VI) is more soluble, toxic, carcinogenic, and mutagenic compared to its reduced form Cr(III). In order to stimulate microbially mediated reduction of Cr(VI), a poly-lactate compound HRC was injected into the chromium contaminated aquifers at site 100H at Hanford. Based on the results of the bacterial community composition using high-density DNA microarray analysis of 16S rRNA gene products, we recently investigated the diversity of the dominant anaerobic culturable microbial population present at this site and their role in Cr(VI) reduction. Positive enrichments set up at 30°C using specific defined anaerobic media resulted in the isolation of an iron reducing isolate strain HAF, a sulfate reducing isolate strain HBLS and a nitrate reducing isolate, strain HLN among several others. Preliminary 16S rDNA sequence analysis identifies strain HAF as Geobacter metallireducens, strain HLN as Pseudomonas stutzeri and strain HBLS as a member of Desulfovibrio species. Strain HAF isolated with acetate as the electron donor utilized propionate, glycerol and pyruvate as alternative carbon sources, and reduced metals like Mn(IV) and Cr(VI). Growth was optimal at 37°C, pH of 6.5 and 0% salinity. Strain HLN isolated with lactate as electron donor utilized acetate, glycerol and pyruvate as alternative carbon sources, and reduced metals like Mn(IV) and Cr(VI). Optimal growth was observed at 37°C, at a pH of 7.5 and 0.3% salinity. Anaerobic active washed cell suspension of strain HLN reduced almost 95 micromolar Cr(VI) within 4 hours relative to controls. Further, with 100 micromolar Cr(VI) as the sole electron acceptor, cells of strain HLN grew to cell numbers of 4.05X 107/ml over a period of 24hrs after an initial lag, demonstrating direct enzymatic Cr(VI) reduction by this species. 10mM lactate served as the sole electron donor. These results demonstrate that Cr(VI

  20. A Psychosocial Approach to Understanding Underground Spaces

    Directory of Open Access Journals (Sweden)

    Eun H. Lee

    2017-03-01

    Full Text Available With a growing need for usable land in urban areas, subterranean development has been gaining attention. While construction of large underground complexes is not a new concept, our understanding of various socio-cultural aspects of staying underground is still at a premature stage. With projected emergence of underground built environments, future populations may spend much more of their working, transit, and recreational time in underground spaces. Therefore, it is essential to understand the challenges and advantages that such environments have to improve the future welfare of users of underground spaces. The current paper discusses various psycho-social aspects of underground spaces, the impact they can have on the culture shared among the occupants, and possible solutions to overcome some of these challenges.

  1. Molecular Interactions of Plutonium(VI) with Synthetic Manganese-Substituted Goethite

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Yung-Jin; Schwaiger, Luna Kestrel; Booth, Corwin H.; Kukkadapu, Ravi K.; Cristiano, Elena; Kaplan, Daniel; Nitsche, Heino

    2010-03-09

    Plutonium(VI) sorption on the surface of well-characterized synthetic manganese-substituted goethite minerals (Fe1-xMnxOOH) was studied using X-ray absorption spectroscopy. We chose to study the influence of manganese as a minor component in goethite, because goethite rarely exists as a pure phase in nature. Manganese X-ray absorption near-edge structure measurements indicated that essentially all the Mn in the goethite existed as Mn(III), even though Mn was added during mineral synthesis as Mn(II). Importantly, energy dispersive X-ray analysis demonstrated that Mn did not exist as discrete phases and that it was homogeneously mixed into the goethite to within the limit of detection of the method. Furthermore, Mössbauer spectra demonstrated that all Fe existed as Fe(III), with no Fe(II) present. Plutonium(VI) sorption experiments were conducted open to air and no attempt was made to exclude carbonate. The use of X-ray absorption spectroscopy allows us to directly and unambiguously measure the oxidation state of plutonium in situ at the mineral surface. Plutonium X-ray absorption near-edge structure measurements carried out on these samples showed that Pu(VI) was reduced to Pu(IV) upon contact with the mineral. This reduction appears to be strongly correlated with mineral solution pH, coinciding with pH transitions across the point of zero charge of the mineral. Furthermore, extended X-ray absorption fine structure measurements show evidence of direct plutonium binding to the metal surface as an inner-sphere complex. This combination of extensive mineral characterization and advanced spectroscopy suggests that sorption of the plutonium onto the surface of the mineral was followed by reduction of the plutonium at the surface of the mineral to form an inner-sphere complex. Because manganese is often found in the environment as a minor component associated with major mineral components, such as goethite, understanding the molecular-level interactions of plutonium with

  2. A kinetic study of biological Cr(VI) reduction in trickling filters with different filter media types

    International Nuclear Information System (INIS)

    Dermou, E.; Vayenas, D.V.

    2007-01-01

    Two pilot-scale trickling filters were used in order to estimate Cr(VI) reduction through biological mechanisms in biofilm reactors operated in SBR mode with recirculation using different filter media types, i.e. plastic media and calcitic gravel. The feed concentrations of Cr(VI) examined were about 5, 10, 20, 30, 50 and 100 mg/l, while the concentration of the organic carbon was constant at 400 mg/l, in order to avoid carbon limitations in the bulk liquid. Maximum reduction rates of 4.8 and 4.7 g Cr(VI)/d were observed for feed Cr(VI) concentration of about 5 mg Cr(VI)/l, for the filters with the plastic support material and the gravel media, respectively. The reduction rates were significantly affected by the feed Cr(VI) concentration in both bioreactors. A dual-enzyme kinetic model was used in order to describe Cr(VI) reduction by aerobically grown mixed cultures. Model predictions were found to correspond very closely to experimental quantitative observations of Cr(VI) reduction at both pilot-scale trickling filters used

  3. Underground nuclear power plant

    International Nuclear Information System (INIS)

    Takahashi, Hideo.

    1997-01-01

    In an underground-type nuclear power plant, groups of containing cavities comprising a plurality of containing cavities connected in series laterally by way of partition walls are disposed in parallel underground. Controlled communication tunnels for communicating the containing cavities belonging to a control region to each other, and non-controlled communication tunnels for communicating containing cavities belonging to a non-controlled area to each other are disposed underground. A controlled corridor tunnel and a non-controlled corridor tunnel extended so as to surround the containing cavity groups are disposed underground, and the containing cavities belonging to the controlled area are connected to the controlled corridor tunnel respectively, and the containing cavities belonging to the non-controlled area are connected to the non-controlled corridor tunnel respectively. The excavating amount of earth and sand upon construction can be reduced by disposing the containing cavity groups comprising a plurality of containing cavities connected in series laterally. The time and the cost for the construction can be reduced, and various excellent effects can be provided. (N.H.)

  4. UNDERGROUND ECONOMY, GDP AND STOCK MARKET

    Directory of Open Access Journals (Sweden)

    Caus Vasile Aurel

    2012-07-01

    Full Text Available Economic growth is affected by the size and dynamics of underground economy. Determining this size is a subject of research for many authors. In this paper we present the relationship between underground economy dynamics and the dynamics of stock markets. The observations are based on regression used by Tanzi (1983 and the relationship between GDP and stock market presented in Tudor (2008. The conclusion of this paper is that the dynamics of underground economy is influenced by dynamic of financial markets. Thus, using specific stock market mathematical tools analysis, one can analyze the dynamic of underground economy

  5. Capital Subsidies and the Underground Economy

    DEFF Research Database (Denmark)

    Busato, Francesco; Chiarini, Bruno; Angelis, Pasquale de

    In this paper we investigate the effects of different fiscal policies on the firm choice to produce underground. We consider a tax evading firm operating simultaneously both in the regular and in the underground economy. We suggest that such a kind of firm, referred to as moonlighting firm, is able...... allocation in the underground production. In fact, a strong and inverse relationship is found, and tax reduction is the best policy to reduce the convenience to produce underground. Wealso confirm the depressing effect on investment of taxation (see, for instance, Summers,1981), so that tax reduction has...

  6. Biased Brownian motion mechanism for processivity and directionality of single-headed myosin-VI.

    Science.gov (United States)

    Iwaki, Mitsuhiro; Iwane, Atsuko Hikikoshi; Ikebe, Mitsuo; Yanagida, Toshio

    2008-01-01

    Conventional form to function as a vesicle transporter is not a 'single molecule' but a coordinated 'two molecules'. The coordinated two molecules make it complicated to reveal its mechanism. To overcome the difficulty, we adopted a single-headed myosin-VI as a model protein. Myosin-VI is an intracellular vesicle and organelle transporter that moves along actin filaments in a direction opposite to most other known myosin classes. The myosin-VI was expected to form a dimer to move processively along actin filaments with a hand-over-hand mechanism like other myosin organelle transporters. However, wild-type myosin-VI was demonstrated to be monomer and single-headed, casting doubt on its processivity. Using single molecule techniques, we show that green fluorescent protein (GFP)-fused single-headed myosin-VI does not move processively. However, when coupled to a 200 nm polystyrene bead (comparable to an intracellular vesicle in size) at a ratio of one head per bead, single-headed myosin-VI moves processively with large (40 nm) steps. Furthermore, we found that a single-headed myosin-VI-bead complex moved more processively in a high-viscous solution (40-fold higher than water) similar to cellular environment. Because diffusion of the bead is 60-fold slower than myosin-VI heads alone in water, we propose a model in which the bead acts as a diffusional anchor for the myosin-VI, enhancing the head's rebinding following detachment and supporting processive movement of the bead-monomer complex. This investigation will help us understand how molecular motors utilize Brownian motion in cells.

  7. MB-OFDM-UWB Based Wireless Multimedia Sensor Networks for Underground Coalmine: A Survey

    Science.gov (United States)

    Han, Ruisong; Yang, Wei; You, Kaiming

    2016-01-01

    Safety production of coalmines is a task of top priority which plays an important role in guaranteeing, supporting and promoting the continuous development of the coal industry. Since traditional wireless sensor networks (WSNs) cannot fully meet the requirements of comprehensive environment monitoring of underground coalmines, wireless multimedia sensor networks (WMSNs), enabling the retrieval of multimedia information, are introduced to realize fine-grained and precise environment surveillance. In this paper, a framework for designing underground coalmine WMSNs based on Multi-Band Orthogonal Frequency-Division Multiplexing Ultra-wide Band (MB-OFDM-UWB) is presented. The selection of MB-OFDM-UWB wireless transmission solution is based on the characteristics of underground coalmines. Network structure and design challenges are analyzed first, which is the foundation for further discussion. Then, key supporting technologies and open research areas in different layers are surveyed, and we provide a detailed literature review of the state of the art strategies, algorithms and general solutions in these issues. Finally, other research issues like localization, information processing, and network management are discussed. PMID:27999258

  8. MB-OFDM-UWB Based Wireless Multimedia Sensor Networks for Underground Coalmine: A Survey.

    Science.gov (United States)

    Han, Ruisong; Yang, Wei; You, Kaiming

    2016-12-16

    Safety production of coalmines is a task of top priority which plays an important role in guaranteeing, supporting and promoting the continuous development of the coal industry. Since traditional wireless sensor networks (WSNs) cannot fully meet the requirements of comprehensive environment monitoring of underground coalmines, wireless multimedia sensor networks (WMSNs), enabling the retrieval of multimedia information, are introduced to realize fine-grained and precise environment surveillance. In this paper, a framework for designing underground coalmine WMSNs based on Multi-Band Orthogonal Frequency-Division Multiplexing Ultra-wide Band (MB-OFDM-UWB) is presented. The selection of MB-OFDM-UWB wireless transmission solution is based on the characteristics of underground coalmines. Network structure and design challenges are analyzed first, which is the foundation for further discussion. Then, key supporting technologies and open research areas in different layers are surveyed, and we provide a detailed literature review of the state of the art strategies, algorithms and general solutions in these issues. Finally, other research issues like localization, information processing, and network management are discussed.

  9. Measurement of age of underground water, using tritium

    International Nuclear Information System (INIS)

    Chatani, Kunio; Kagami, Tadaaki; Tomita, Ban-ichi; Onuma, Akiko; Shoka, Yasushi

    1978-01-01

    Age of four kinds of underground water in Aichi prefecture was estimated by measuring a concentration of tritium. The tritium concentration was measured by the usual method. The first water-bearing zone of the shallow part, about 50m in depth, of Nobi plain is a new underground water cultivated within 20 years, whereas second water-bearing zone is an old underground water of 20 years old or more. No relationship of water flow between the first and the second water-bearing zone was observed. A very deep underground about 100m or more in depth, of the Nobi plain is confirmed to be infinite years old fossil water by measuring of tritium. The underground water in Atsumi peninsula is mostly a new underground water within 20 years. Only one out of eight showed the existence of old underground water before 20 years or more. The underground water of the granite area at Mikawa district is confirmed to be old underground water before 20 years or more. Alkaline underground water in the granite zone is considered to be very old in view of composition of water. The origin of underground water can be learned by tritium concentration, which shows whether the water is new water in the neighborhood of earth's surface or very old cultivated water. (Iwakiri, K.)

  10. Enzymatic reduction of U(VI) in groundwaters

    International Nuclear Information System (INIS)

    Addelouas, A.; Gong, W.; Lutze, W.; Nuttall, E.; Fritz, B.; Crovisier, J.L.

    1999-01-01

    The use of enzymatic reduction of U(VI) in remediation of groundwater contaminated with U(VI) is receiving considerable attention. Certain strains of bacteria can combine the oxidation of an organic compound to the reduction of U(VI) to U(IV), which precipitates as uraninite. In the present study, we tested the reduction of U(VI) in groundwaters with various origins and compositions. In all groundwaters u(VI) was reduced by sulfate reducing bacteria that had been activated by ethanol and tri-metaphosphate. The reduction rate of U(VI) depends on sulfate concentration in water and the abundance of bacteria in the system. This work shows that bacteria capable of U(VI) reduction are ubiquitous in nature, and suggests the possibility of a large application of the enzymatic reduction of U(VI) for in situ clean up of groundwaters contaminated with uranium. (authors)

  11. Modeling to Support Groundwater Contaminant Boundaries for the Shoal Underground Nuclear Test

    Energy Technology Data Exchange (ETDEWEB)

    K. Pohlmann; G. Pohll; J. Chapman; A. Hassan; R. Carroll; C. Shirley

    2004-03-01

    Groundwater flow and radionuclide transport at the Shoal underground nuclear test are characterized using three-dimensional numerical models, based on site-specific hydrologic data. The objective of this modeling is to provide the flow and transport models needed to develop a contaminant boundary defining the extent of radionuclide-contaminated groundwater at the site throughout 1,000 years at a prescribed level of confidence. This boundary will then be used to manage the Project Shoal Area for the protection of the public and the environment.

  12. Monitoring underground movements

    CERN Multimedia

    Antonella Del Rosso

    2015-01-01

    On 16 September 2015 at 22:54:33 (UTC), an 8.3-magnitude earthquake struck off the coast of Chile. 11,650 km away, at CERN, a new-generation instrument – the Precision Laser Inclinometer (PLI) – recorded the extreme event. The PLI is being tested by a JINR/CERN/ATLAS team to measure the movements of underground structures and detectors.   The Precision Laser Inclinometer during assembly. The instrument has proven very accurate when taking measurements of the movements of underground structures at CERN.    The Precision Laser Inclinometer is an extremely sensitive device capable of monitoring ground angular oscillations in a frequency range of 0.001-1 Hz with a precision of 10-10 rad/Hz1/2. The instrument is currently installed in one of the old ISR transfer tunnels (TT1) built in 1970. However, its final destination could be the ATLAS cavern, where it would measure and monitor the fine movements of the underground structures, which can affect the precise posi...

  13. Chromium VI and stomach cancer: a meta-analysis of the current epidemiological evidence.

    Science.gov (United States)

    Welling, Roberta; Beaumont, James J; Petersen, Scott J; Alexeeff, George V; Steinmaus, Craig

    2015-02-01

    Chromium VI (hexavalent chromium, Cr(VI)) is an established cause of lung cancer, but its association with gastrointestinal cancer is less clear. The goal of this study was to examine whether the current human epidemiological research on occupationally inhaled Cr(VI) supports the hypothesis that Cr(VI) is associated with human stomach cancer. Following a thorough literature search and review of individual studies, we used meta-analysis to summarise the current epidemiological literature on inhaled Cr(VI) and stomach cancer, explore major sources of heterogeneity, and assess other elements of causal inference. We identified 56 cohort and case-control studies and 74 individual relative risk (RR) estimates on stomach cancer and Cr(VI) exposure or work in an occupation associated with high Cr(VI) exposure including chromium production, chrome plating, leather work and work with Portland cement. The summary RR for all studies combined was 1.27 (95% CI 1.18 to 1.38). In analyses limited to only those studies identifying increased risks of lung cancer, the summary RR for stomach cancer was higher (RR=1.41, 95% CI 1.18 to 1.69). Overall, these results suggest that Cr(VI) is a stomach carcinogen in humans, which is consistent with the tumour results reported in rodent studies. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

  14. A review of international underground laboratory developments

    International Nuclear Information System (INIS)

    Cheng Jianping; Yue Qian; Wu Shiyong; Shen Manbin

    2011-01-01

    Underground laboratories are essential for various important physics areas such as the search for dark matter, double beta decay, neutrino oscillation, and proton decay. At the same time, they are also a very important location for studying rock mechanics, earth structure evolution,and ecology. It is essential for a nation's basic research capability to construct and develop underground laboratories. In the past, China had no high-quality underground laboratory,in particular no deep underground laboratory,so her scientists could not work independently in major fields such as the search for dark matter,but had to collaborate with foreign scientists and share the space of foreign underground laboratories. In 2009, Tsinghua university collaborated with the Ertan Hydropower Development Company to construct an extremely deep underground laboratory, the first in China and currently the deepest in the world, in the Jinping traffic tunnel which was built to develop hydropower from the Yalong River in Sichuan province. This laboratory is named the China Jinping Underground Laboratory (CJPL) and formally opened on December 12, 2010. It is now a major independent platform in China and can host various leading basic research projects. We present a brief review of the development of various international underground laboratories,and especially describe CJPL in detail. (authors)

  15. Polarographic behaviour of uranium (VI) in tributyl phosphate organic solutions

    International Nuclear Information System (INIS)

    Degueldre, C.A.; Meklati, M.

    1984-01-01

    U(VI) determination by D.C. and differential pulse polarography was studied in the organic solutions derived from tributyl phosphate - diluent extracts (after separation from nitric acid media) along with a selected aprotic solvent (i.e.: propylene carbonate and N,N-dimethylacetamide). Miscibility of the TBP-diluent (e.g. cyclohexane, n-hexane, kerosene, n-dodecane) phase with nitric acid as supporting electrolyte, either by addition or already present in the extract was larger in DMA than in PC. In the DMA organic mixture, U(VI) exhibited a DPP peak due to a one electron step, with Esub(p)=-0.4 V (position connected with H 2 O and HNO 3 concentrations). This peak which was proportionnel to the U(VI) concentration from 5x10 -6 to 10 -3 M can be used to determinate directly hexavalent uranium in the industrial organic extraction phases TBP-diluent. (orig.)

  16. Enzymatic U(VI) reduction by Desulfosporosinus species

    International Nuclear Information System (INIS)

    Suzuki, Y.; Kelly, S.D.; Kemner, K.M.; Banfield, J.F.

    2004-01-01

    Here we tested U(VI) reduction by a Desulfosporosinus species (sp.) isolate and type strain (DSM 765) in cell suspensions (pH 7) containing 1 mM U(VI) and lactate, under an atmosphere containing N 2 -CO 2 -H 2 (90: 5: 5). Although neither Desulfosporosinus species (spp.) reduced U(VI) in cell suspensions with 0.25% Na-bicarbonate or 0.85% NaCl, U(VI) was reduced in these solutions by a control strain, desulfovibrio desulfuricans (ATCC 642). However, both Desulfosporosinus strains reduced U(VI) in cell suspensions depleted in bicarbonate and NaCl. No U(VI) reduction was observed without lactate and H 2 electron donors or with heat-killed cells, indicating enzymatic U(VI) reduction. Uranium(VI) reduction by both strains was inhibited when 1 mM CuCl 2 was added to the cell suspensions. Because the Desulfosporosinus DSM 765 does not contain cytochrome c 3 used by Desulfovibrio spp. to reduce U(VI), Desulfosporosinus species reduce uranium via a different enzymatic pathway. (orig.)

  17. Kiintoainehäviöselvitys

    OpenAIRE

    Ylimys, Jussi

    2014-01-01

    Teoriaosassa käydään läpi yleisesti pyörrepuhdistuslaitoksen toimintaa sekä kiintoainehäviöitä paperi- ja kartonkitehtailla. Tämän opinnäytetyön tarkoituksena oli tutkia Metsä Boardin Kyröskosken tehtaan kiintoainehäviötä. Työssä selvitettiin, minkälaista kiintoainetta jätevesilaitokselle päätyy ja miksi. Selvityksen kohteena oli myös, missä kohteissa kiintoainehäviöt tarkalleen syntyvät ja kuinka paljon häviötä tapahtuu. Kahden edellä mainitun tiedon perusteella selvitettiin, kuinka palj...

  18. Underground Coal Gasification: Rates of Post Processing Gas Transport

    Czech Academy of Sciences Publication Activity Database

    Soukup, Karel; Hejtmánek, Vladimír; Stanczyk, K.; Šolcová, Olga

    2014-01-01

    Roč. 68, č. 12 (2014), s. 1707-1715 ISSN 0366-6352 R&D Projects: GA MŠk 7C12017 Grant - others:RFCS(XE) RFCR-CT-2011-00002 Institutional support: RVO:67985858 Keywords : underground coal gas ification * gas transport * textural properties Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.468, year: 2014

  19. Henderson Deep Underground Science and Engineering Lab: Unearthing the secrets of the Universe, underground

    International Nuclear Information System (INIS)

    Jung, C.K.

    2011-01-01

    The Henderson Mine near Empire, Colorado is proposed to be the site to host a Deep Underground Science and Engineering Laboratory (DUSEL), which will have a rich program for forefront research in physics, biology, geosciences, and mining engineering. The mine is owned by the Climax Molybdenum Company (CMC). It is located about 50 miles west of Denver and is easily accessible via major highways. The mine is modern and has extensive infrastructure with reserve capacity well-suited to the demands of DUSEL. CMC owns all land required for DUSEL, including the tailings site. It also has all environmental and mining permits required for DUSEL excavation, core drilling, and rock disposal. The mine owners are enthusiastic supporters of this initiative. In support of the Henderson DUSEL project, the State of Colorado has pledged substantial funding for surface construction.

  20. Peroxo complexes of molybdenum(VI), tungsten(VI), uranium(VI), zirconium(IV) and thorium(IV) ions containing tridentate Schiff bases derived from salicylaldehyde and amino acids

    International Nuclear Information System (INIS)

    Tarafder, M.T.H.; Khan, A.R.

    1997-01-01

    The synthesis of peroxo complexes of molybdenum(VI), tungsten(VI), uranium(VI), zirconium(IV), thorium(IV) and their possible oxygen transfer reactions is presented. An attempt has also been made to study the size of the metal ions and the electronic effect derived from the tridentate Schiff bases on the v 1 (O-O) mode of the complexes in their IR spectra

  1. Concept Design and Development Model of Underground Villas

    Directory of Open Access Journals (Sweden)

    Xinrong Liu

    2015-08-01

    Full Text Available With the rapid development of society, modern buildings have been consuming excessive amount of energy and resources. Eco-friendly building is going to be the leading style of architecture in the future. Underground villa, as a type of energy efficient architecture, has widely drawn humans’ attention. However, Chinese are still at an exploratory stage in terms of the development of underground construction. This paper describes several typical underground villas in western developed countries; briefly states the advantages and shortcomings of underground villas; discusses the design of style-planning, inner-space design, lighting and ventilation, and waterproof and fireproof of underground villas; also puts forward how to improve the living environment of underground villas. Besides, the paper suggests an innovative concept of underground living that best suits China’s market based on the merits of underground villas and the analysis upon China’s traditional cave-house. In addition, it roughly analyzes the prospect of this innovate style of dwelling in China.

  2. Cathode protection for underground steel tanks

    International Nuclear Information System (INIS)

    Angelovski, Zoran

    1998-01-01

    Cathodic protection of underground petroleum storage tanks and piping systems is acceptable for both economic and ecological reasons. With out the cathodic protection of underground steel reservoirs, short time after the exploitation, there was a bore as a result of underground corrosion. The bore causes ecological consequences and at the same time its repair needs big investments. Furthermore, there are great number of tanks placed near cities, so in the future this problem needs a special attention in order to preserve ecological surrounding. The topic of this paper is underground corrosion as well as cathodic protection of steel tanks for oil derivatives storage. (author)

  3. Proposed underground gasification. [United Kingdom

    Energy Technology Data Exchange (ETDEWEB)

    1986-05-01

    An underground coal gasification experiment which could provide the key to recovering the energy in millions of tonnes of otherwise inaccessible undersea coal reserves is proposed by the NCB. The Board's Headquarters Technical Department hope to carry out a field trial in a six foot thick coal seam about 2000 feet beneath a former wartime airfield near the hamlet of Ossington near Newark, Notts, UK. This paper describes briefly the proposed project, which could cost up to 15 million pounds over five years. It has the backing and financial support of the European Economic Community.

  4. Characterization of Cr(VI) removal from aqueous solutions by a surplus agricultural waste-Rice straw

    International Nuclear Information System (INIS)

    Gao Hui; Liu Yunguo; Zeng Guangming; Xu Weihua; Li Ting; Xia Wenbin

    2008-01-01

    The removal of Cr(VI) from aqueous solution by rice straw, a surplus agricultural byproduct was investigated. The optimal pH was 2.0 and Cr(VI) removal rate increased with decreased Cr(VI) concentration and with increased temperature. Decrease in straw particle size led to an increase in Cr(VI) removal. Equilibrium was achieved in about 48 h under standard conditions, and Cr(III), which appeared in the solution and remained stable thereafter, indicating that both reduction and adsorption played a part in the Cr(VI) removal. The increase of the solution pH suggested that protons were needed for the Cr(VI) removal. A relatively high level of NO 3 - notably restrained the reduction of Cr(VI) to Cr(III), while high level of SO 4 2- supported it. The promotion of the tartaric acid modified rice straw (TARS) and the slight inhibition of the esterified rice straw (ERS) on Cr(VI) removal indicated that carboxyl groups present on the biomass played an important role in chromium remediation even though were not fully responsible for it. Isotherm tests showed that equilibrium sorption data were better represented by Langmuir model and the sorption capacity of rice straw was found to be 3.15 mg/g

  5. 30 CFR 57.8519 - Underground main fan controls.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Underground main fan controls. 57.8519 Section... Ventilation Surface and Underground § 57.8519 Underground main fan controls. All underground main fans shall have controls placed at a suitable protected location remote from the fan and preferably on the surface...

  6. ENDF-201, ENDF/B-VI summary documentation supplement 1, ENDF/HE-VI summary documentation

    International Nuclear Information System (INIS)

    McLane, V.

    1996-12-01

    The National Nuclear Data Center (NNDC) provides coordination for and serves as the secretariat to the Cross Section Evaluation Working Group (CSWEG). CSEWG is responsible for the oversight of the ENDF/B Evaluated Nuclear Data File. All data are checked and reviewed by CSEWG, and the file is maintained at the NNDC. For a description of the ENDF/B-VI file, see the ENDF-102 Data Formats and Procedures for the Evaluated Nuclear Data File ENDF-6. The purpose of this addendum to the ENDF/B-VI Summary Documentation is to provide documentation of Releases 1, 2, 3, and 4 for the ENDF/B-VI and ENDF/HE-VI evaluated nuclear data libraries. These releases contain many new and revised evaluations for the neutron, photo-atomic interaction, radioactive decay data, spontaneous fission product yield, neutron-induced fission product yield, thermal neutron scattering, proton, deuteron, and triton sublibraries. The summaries have been extracted mainly from the ENDF/B-VI File 1 comments (MT = 451), which have been checked, edited, and may also include supplementary information. Some summaries have been provided by the evaluators in electronic format, while others are extracted from reports on the evaluations. All references have been checked and corrected, or updated where appropriate. A list of the laboratories which have contributed evaluations used in ENDF/B-VI is given

  7. ENDF-201, ENDF/B-VI summary documentation supplement 1, ENDF/HE-VI summary documentation

    Energy Technology Data Exchange (ETDEWEB)

    McLane, V.

    1996-12-01

    The National Nuclear Data Center (NNDC) provides coordination for and serves as the secretariat to the Cross Section Evaluation Working Group (CSWEG). CSEWG is responsible for the oversight of the ENDF/B Evaluated Nuclear Data File. All data are checked and reviewed by CSEWG, and the file is maintained at the NNDC. For a description of the ENDF/B-VI file, see the ENDF-102 Data Formats and Procedures for the Evaluated Nuclear Data File ENDF-6. The purpose of this addendum to the ENDF/B-VI Summary Documentation is to provide documentation of Releases 1, 2, 3, and 4 for the ENDF/B-VI and ENDF/HE-VI evaluated nuclear data libraries. These releases contain many new and revised evaluations for the neutron, photo-atomic interaction, radioactive decay data, spontaneous fission product yield, neutron-induced fission product yield, thermal neutron scattering, proton, deuteron, and triton sublibraries. The summaries have been extracted mainly from the ENDF/B-VI File 1 comments (MT = 451), which have been checked, edited, and may also include supplementary information. Some summaries have been provided by the evaluators in electronic format, while others are extracted from reports on the evaluations. All references have been checked and corrected, or updated where appropriate. A list of the laboratories which have contributed evaluations used in ENDF/B-VI is given.

  8. 24 CFR 971.11 - HOPE VI developments.

    Science.gov (United States)

    2010-04-01

    ... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false HOPE VI developments. 971.11... § 971.11 HOPE VI developments. Developments with HOPE VI implementation grants that have approved HOPE... with reasonable revitalization plans. Future HUD actions to approve or deny proposed HOPE VI...

  9. 40 CFR 280.230 - Operating an underground storage tank or underground storage tank system.

    Science.gov (United States)

    2010-07-01

    ... underground storage tank or underground storage tank system. (a) Operating an UST or UST system prior to...) Operating an UST or UST system after foreclosure. The following provisions apply to a holder who, through..., the purchaser must decide whether to operate or close the UST or UST system in accordance with...

  10. Development of support system for large-scale underground structures using WEB 3D technology and RDBMS

    International Nuclear Information System (INIS)

    Xu, Zhaofeng; Itakura, Ken-ichi; Yamachi, Hiroshi; Sato, Toshinori; Matsui, Hiroya

    2015-01-01

    In the process of underground space development, enormous information is collected in each developing stage, such as investigation, plan, design and construction. It is important to properly feed back these information to design and construction in order to realize rational design and construction of an underground space. And more, these information also become basic data in a plane of structure management. However, it is almost impossible that it is controlled in the individual ability, since collected information quantity is too enormous. For the purpose of intuitively controlling and processing these enormous information, we devised the system for the data management by freely moving in virtual reality space. In this paper, the basic structure of the system constructed by adopting WEB 3D and RDBMS, is described, and the practicability is verified. (author)

  11. Underground disposal of radioactive wastes

    International Nuclear Information System (INIS)

    1981-01-01

    This report is an overview document for the series of IAEA reports dealing with underground waste disposal to be prepared in the next few years. It provides an introduction to the general considerations involved in implementing underground disposal of radioactive wastes. It suggests factors to be taken into account for developing and assessing waste disposal concepts, including the conditioned waste form, the geological containment and possible additional engineered barriers. These guidelines are general so as to cover a broad range of conditions. They are generally applicable to all types of underground disposal, but the emphasis is on disposal in deep geological formations. Some information presented here may require slight modifications when applied to shallow ground disposal or other types of underground disposal. Modifications may also be needed to reflect local conditions. In some specific cases it may be that not all the considerations dealt with in this book are necessary; on the other hand, while most major considerations are believed to be included, they are not meant to be all-inclusive. The book primarily concerns only underground disposal of the wastes from nuclear fuel cycle operations and those which arise from the use of isotopes for medical and research activities

  12. Technology-derived storage solutions for stabilizing insulin in extreme weather conditions I: the ViViCap-1 device.

    Science.gov (United States)

    Pfützner, Andreas; Pesach, Gidi; Nagar, Ron

    2017-06-01

    Injectable life-saving drugs should not be exposed to temperatures 30°C/86°F. Frequently, weather conditions exceed these temperature thresholds in many countries. Insulin is to be kept at 4-8°C/~ 39-47°F until use and once opened, is supposed to be stable for up to 31 days at room temperature (exception: 42 days for insulin levemir). Extremely hot or cold external temperature can lead to insulin degradation in a very short time with loss of its glucose-lowering efficacy. Combined chemical and engineering solutions for heat protection are employed in ViViCap-1 for disposable insulin pens. The device works based on vacuum insulation and heat consumption by phase-change material. Laboratory studies with exposure of ViViCap-1 to hot outside conditions were performed to evaluate the device performance. ViViCap-1 keeps insulin at an internal temperature phase-change process and 'recharges' the device for further use. ViViCap-1 performed within its specifications. The small and convenient device maintains the efficacy and safety of using insulin even when carried under hot weather conditions.

  13. Reduction of ferrate(VI) and oxidation of cyanate in a Fe(VI)-TiO2-UV-NCO- system.

    Science.gov (United States)

    Winkelmann, Kurt; Sharma, Virender K; Lin, Yekaterina; Shreve, Katherine A; Winkelmann, Catherine; Hoisington, Laura J; Yngard, Ria A

    2008-08-01

    The aqueous photocatalytic degradation of cyanate (NCO(-)), which is a long-lived neurotoxin formed during the remediation of cyanide in industrial waste streams, was studied in the ferrate(VI)-UV-TiO2-NCO(-) system. Kinetics measurements of the photocatalytic reduction of ferrate(VI) were carried out as a function of [NCO(-)], [ferrate(VI)], [O(2)], light intensity (I(o)), and amount of TiO2 in suspensions at pH 9.0. The photocatalytic reduction rate of ferrate(VI) in the studied system can be expressed as -d[Fe(VI)]/dt=kI(o)(0.5) [NCO(-)] [TiO2]. The rate of photocatalytic oxidation of cyanate with ferrate(VI) was greater than the rate in the analogous system without ferrate(VI). The possibility of involvement of reactive ferrate(V) species for this enhancement was determined by studying the reactivity of ferrate(V) with NCO(-) in a homogeneous solution using a premix pulse radiolysis technique. The rate constant for the reaction of ferrate(V) and NCO(-) in alkaline medium was estimated to be (9.60+/-0.07) x 10(2) M(-1) s(-1), which is much slower than the ferrate(VI) self-decomposition reaction (k approximately 10(7) M(-1) s(-1)). An analysis of the kinetic data in the Fe(VI)-UV-TiO2-NCO(-) system suggests that ferrate(V) is not directly participating in the oxidation of cyanate. Possible reactions in the system are presented to explain results of ferrate(VI) reduction and oxidation of cyanate.

  14. Regulating and Combating Underground Banking

    NARCIS (Netherlands)

    Borgers, M.J.

    2009-01-01

    In combating and regulating underground banking, a choice can be made of roughly two models, the risk model and the assimilation model. The risk model comes down to a complete prohibition of underground banking combined with an active investigation and prosecution policy. In the assimilation model,

  15. Vi har intet lært - hvornår lærer vi det?

    DEFF Research Database (Denmark)

    Sodemann, Morten

    2016-01-01

    WHO anså fra i går ikke længere ebola for at være en trussel mod global folkesundhed, så fra i dag er kameraerne slukket i Vestafrika og vi er tilbage hvor vi startede. SDG målene skal have et dansk udtryk, men hvad er de danske kompetencer på globalt plan når sundhed ikke længere er en kerneakti......WHO anså fra i går ikke længere ebola for at være en trussel mod global folkesundhed, så fra i dag er kameraerne slukket i Vestafrika og vi er tilbage hvor vi startede. SDG målene skal have et dansk udtryk, men hvad er de danske kompetencer på globalt plan når sundhed ikke længere er en...

  16. Thermodynamics of U(VI) and Eu(III) complexation by unsaturated carboxylates

    Energy Technology Data Exchange (ETDEWEB)

    Rawat, Neetika; Bhattacharyya, A. [Radiochemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Tomar, B.S., E-mail: bstomar@barc.gov.in [Radiochemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Ghanty, T.K. [Theoretical Chemistry Section, Bhabha Atomic Research Centre, Mumbai 400085 (India); Manchanda, V.K. [Radiochemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India)

    2011-05-10

    Highlights: {yields} {Delta}H and log K determined for U(VI) and Eu(III) complexes with maleate and fumarate. {yields} log K and coordination environment of Eu(III) complexes has been studied by TRFS. {yields} Higher log K of U(VI) complexes than Eu(III) complexes is due to higher entropy. {yields} Plot of log K vs log K{sub P} suggest charge polarization in fumarate complexes. {yields} Ab initio calculations support charge polarization in fumarate complexes. - Abstract: The thermodynamic parameters ({Delta}G, {Delta}H and {Delta}S) of complexation of U(VI) and Eu(III) by unsaturated dicarboxylic acids, namely, maleic and fumaric acid, has been determined by potentiometric and microcalorimetric titrations at fixed ionic strength (I = 1.0 M) and temperature (298 K). The results show formation of 1:1 complexes by both the ligands with Eu(III). In the case of U(VI), maleate forms both 1:1 and 1:2 complexes, while only 1:1 complex was formed with fumarate. The fluorescence emission spectra of Eu(III)-dicarboxylate solutions at varying ligand to metal ratio were also used to obtain their stability constants. In addition, the fluorescence lifetimes reveal higher dehydration of Eu(III)-maleate compared to Eu(III)-fumarate which corroborates the {Delta}S values. The thermodynamic quantities suggest charge polarization effects in the case of U(VI) and Eu(III) complexes of fumarate, which is further corroborated by theoretical calculations. For the same ligand, U(VI) complexes were found to be more stable which was mainly due to higher entropy term.

  17. Geological-Technical and Geo-engineering Aspects of Dimensional Stone Underground Quarrying

    Science.gov (United States)

    Fornaro, Mauro; Lovera, Enrico

    Underground exploitation of dimensional stones is not a novelty, being long since practised, as proved by a number of historical documents and by a certain number of ancient quarrying voids throughout the world. Anyway, so far, open cast quarrying has been the most adopted practice for the excavation of dimensional stones. One primary reason that led to this situation is of course connected to the lower production costs of an open cast exploitation compared to an underground one. This cheapness has been supported by geological and technical motives: on the one hand, the relative availability of surface deposits and, on the other, the development of technologies, which often can be used only outdoor. But, nowadays, general costs of quarrying activities should be re-evaluated because new, and often proper, restrictions have been strongly rising during recent years. As a consequence of both environmental and technical restrictions, pressure will more and more arise to reduce open cast quarrying and to promote underground exploitations. The trend is already well marked for weak rocks - for instance in the extractive basin of Carrara, where about one hundred quarries are active, 30 per cent is working underground, but also in Spain, Portugal and Greece the number of underground marble quarries is increasing - but not yet for hard rock quarrying, where only few quarries are working underground all around the world. One reason has to be found in cutting technologies traditionally used. In weak rocks, diamond wire saw and chain cutter are usable, with few adaptations, in underground spaces, while drilling and blasting, the traditional exploitation method for hard stone, is not easily usable in a confined space, where often only one free face is available. Many technicians and researchers agree that two technologies will probably open the door to underground quarrying in hard rocks: diamond wire and water jet. The first one is already available; the second should still be

  18. Underground Politics

    DEFF Research Database (Denmark)

    Galis, Vasilis; Summerton, Jane

    Public spaces are often contested sites involving the political use of sociomaterial arrangements to check, control and filter the flow of people (see Virilio 1977, 1996). Such arrangements can include configurations of state-of-the-art policing technologies for delineating and demarcating borders...... status updates on identity checks at the metro stations in Stockholm and reports on locations and time of ticket controls for warning travelers. Thus the attempts by authorities to exert control over the (spatial) arena of the underground is circumvented by the effective developing of an alternative...... infrastructural "underground" consisting of assemblages of technologies, activists, immigrants without papers, texts and emails, homes, smart phones and computers. Investigating the embedded politics of contested spatial arrangements as characteristic of specific societies one can discover not only the uses...

  19. Groundwater and underground coal gasification in Alberta

    International Nuclear Information System (INIS)

    Haluszka, A.; MacMillan, G.; Maev, S.

    2010-01-01

    Underground coal gasification has potential in Alberta. This presentation provided background information on underground coal gasification and discussed groundwater and the Laurus Energy demonstration project. A multi-disciplined approach to project assessment was described with particular reference to geologic and hydrogeologic setting; geologic mapping; and a hydrogeologic numerical model. Underground coal gasification involves the conversion of coal into synthesis gas or syngas. It can be applied to mined coal at the surface or applied to non-mined coal seams using injection and production wells. Underground coal gasification can effect groundwater as the rate of water influx into the coal seams influences the quality and composition of the syngas. Byproducts created include heat as well as water with dissolved concentrations of ammonia, phenols, salts, polyaromatic hydrocarbons, and liquid organic products from the pyrolysis of coal. A process overview of underground coal gasification was also illustrated. It was concluded that underground coal gasification has the potential in Alberta and risks to groundwater could be minimized by a properly designed project. refs., figs.

  20. Modeling of Cr(VI) Bioreduction Under Fermentative and Denitrifying Conditions

    Science.gov (United States)

    Molins, S.; Steefel, C.; Yang, L.; Beller, H. R.

    2011-12-01

    The mechanisms of bioreductive immobilization of Cr(VI) were investigated by reactive transport modeling of a set of flow-through column experiments performed using natural Hanford 100H aquifer sediment. The columns were continuously eluted with 5 μM Cr(VI), 5 mM lactate as the electron donor, and selected electron acceptors (tested individually). Here we focus on the two separate experimental conditions that showed the most removal of Cr(VI) from solution: fermentation and denitrification. In each case, a network of enzymatic and abiotic reaction pathways was considered to interpret the rate of chromate reduction. The model included biomass growth and decay, and thermodynamic limitations on reaction rates, and was constrained by effluent concentrations measured by IC and ICP-MS and additional information from bacterial isolates from column effluent. Under denitrifying conditions, Cr(VI) reduction was modeled as co-metabolic with nitrate reduction based on experimental observations and previous studies on a denitrifying bacterium derived from the Hanford 100H aquifer. The reactive transport model results supported this interpretation of the reaction mechanism and were used to quantify the efficiency of the process. The models results also suggest that biomass growth likely relied on a nitrogen source other than ammonium (e.g. nitrate). Under fermentative conditions and based on cell suspension studies performed on a bacterial isolate from the columns, the model assumes that Cr(VI) reduction is carried out directly by fermentative bacteria that convert lactate into acetate and propionate. The evolution to complete lactate fermentation and Cr(VI) reduction took place over a week's time and simulations were used to determine an estimate for a lower limit of the rate of chromate reduction by calibration with the flow-through column experimental results. In spite of sulfate being added to these columns, sulfate reduction proceeded at a slow rate and was not well

  1. Underground storage tank program

    International Nuclear Information System (INIS)

    Lewis, M.W.

    1994-01-01

    Underground storage tanks, UST'S, have become a major component of the Louisville District's Environmental Support Program. The District's Geotechnical and Environmental Engineering Branch has spear-headed an innovative effort to streamline the time, effort and expense for removal, replacement, upgrade and associated cleanup of USTs at military and civil work installations. This program, called Yank-A-Tank, creates generic state-wide contracts for removal, remediation, installation and upgrade of storage tanks for which individual delivery orders are written under the basic contract. The idea is to create a ''JOC type'' contract containing all the components of work necessary to remove, reinstall or upgrade an underground or above ground tank. The contract documents contain a set of generic specifications and unit price books in addition to the standard ''boiler plate'' information. Each contract requires conformance to the specific regulations for the state in which it is issued. The contractor's bid consists of a bid factor which in the multiplier used with the prices in the unit price book. The solicitation is issued as a Request for Proposal (RPP) which allows the government to select a contractor based on technical qualification an well as bid factor. Once the basic contract is awarded individual delivery orders addressing specific areas of work are scoped, negotiated and awarded an modifications to the original contract. The delivery orders utilize the prepriced components and the contractor's factor to determine the value of the work

  2. Effect of uranium (VI) on the growth of yeast and influence of metabolism of yeast on adsorption of U (VI)

    International Nuclear Information System (INIS)

    Sakamoto, Fuminori; Ohnuki, Toshihiko; Kozai, Naofumi; Wakai, Eiichi; Francis, A.J.

    2005-01-01

    We have carried out the growth experiments of 3 strains of yeast in a medium containing uranium (VI) to elucidate the effect of U (VI) on the growth of microorganisms. Hansenula fabianii J640 grew in the liquid medium containing 0.1 mM U (VI) at lower rate than the control, but Saccharomyces cerevisiae did not grow under this condition. The H. fabianii J640 pre-cultured for 21 h in the liquid medium without U (VI) grew even after the exposure to 1 mM U (VI), but did not grow without pre-cultivation. For the pre-cultured H. fabianii J640, radioactivity of U in the medium was the same as the initial one for 110 h, and then gradually decreased. TEM-EDS analysis of H. fabianii J640 exposed to 1 mM U (VI) for 165 h showed accumulation of U (VI) on the cells. When H. fabianii J640 was not pre-cultured, radioactivity of U in the medium was lower than the initial one. These results indicated that U (VI) inhibits the growth of yeast, and that the adsorption of U (VI) by the cells depends on the metabolism of yeast. (author)

  3. Preparation and properties of N-Phenylbutyrohydroxamic acid and N-p-Chlorophenylbutyrohydroxamic acid and their uses as extracting agents for Chromium (VI), Molybdenum (VI), Titanium (IV) and Uranium (VI)

    Energy Technology Data Exchange (ETDEWEB)

    Abu Elnour, Sawsan Hassan [Department of Chemistry, Faculty of Science, University of Khartoum, Khartoum (Sudan)

    1993-05-01

    Two lignads, N-phenylbutyrohydroxamic acid (1), N-p-chlorophenylbutyryl chloride with {beta} phenyl-hydroylamine and N-p-chlorophenylhydroxylamine, respectively. The acids prepared were identified and characterised through their reactions with Vanadiun (V) and iron (III), their melting points, infra-red spectra and nitrogen content. The extractive properties of these acids towards the metals Cr (VI), Mo (VI), Ti (IV) and U (VI) were examined at different PH values. The percentage of maximum extraction with the two acids was found to be as follows : for Cr (VI) at PH 1, (100%) for both acids, Mo (VI) at PH 2 (33.34%) with acid (I) and (16.67%) with acid (II) and U (VI) at PH 6 (72%) with acid (I) and (76%) with acid (II). The metal: Ligand complexes ratios were determined by using the continuous variation method, the ratio of the two ligands with four metals was found to be 1:2. Finally the suitability of the two acids for spectrophotometric determination of four metals was examined.(Author) 90 refs. , 24 tabs. , 24 figs

  4. Preparation and properties of N-Phenylbutyrohydroxamic acid and N-p-Chlorophenylbutyrohydroxamic acid and their uses as extracting agents for Chromium (VI), Molybdenum (VI), Titanium (IV) and Uranium (VI)

    International Nuclear Information System (INIS)

    Abu Elnour, Sawsan Hassan

    1993-05-01

    Two lignads, N-phenylbutyrohydroxamic acid (1), N-p-chlorophenylbutyryl chloride with β phenyl-hydroylamine and N-p-chlorophenylhydroxylamine, respectively. The acids prepared were identified and characterised through their reactions with Vanadiun (V) and iron (III), their melting points, infra-red spectra and nitrogen content. The extractive properties of these acids towards the metals Cr (VI), Mo (VI), Ti (IV) and U (VI) were examined at different PH values. The percentage of maximum extraction with the two acids was found to be as follows : for Cr (VI) at PH 1, (100%) for both acids, Mo (VI) at PH 2 (33.34%) with acid (I) and (16.67%) with acid (II) and U (VI) at PH 6 (72%) with acid (I) and (76%) with acid (II). The metal: Ligand complexes ratios were determined by using the continuous variation method, the ratio of the two ligands with four metals was found to be 1:2. Finally the suitability of the two acids for spectrophotometric determination of four metals was examined.(Author)

  5. Ground engineering principles and practices for underground coal mining

    CERN Document Server

    Galvin, J M

    2016-01-01

    This book teaches readers ground engineering principles and related mining and risk management practices associated with underground coal mining. It establishes the basic elements of risk management and the fundamental principles of ground behaviour and then applies these to the essential building blocks of any underground coal mining system, comprising excavations, pillars, and interactions between workings. Readers will also learn about types of ground support and reinforcement systems and their operating mechanisms. These elements provide the platform whereby the principles can be applied to mining practice and risk management, directed primarily to bord and pillar mining, pillar extraction, longwall mining, sub-surface and surface subsidence, and operational hazards. The text concludes by presenting the framework of risk-based ground control management systems for achieving safe workplaces and efficient mining operations. In addition, a comprehensive reference list provides additional sources of informati...

  6. Wavelengths and energy levels of Xe V and Xe VI obtained by collision-based spectroscopy

    International Nuclear Information System (INIS)

    Larsson, M.O.; Gonzalez, A.M.; Hallin, R.; Heijkenskjoeld, F.; Nystroem, B.; O'Sullivan, G.; Weber, C.; Waennstroem, A.

    1996-01-01

    We have utilized collision-based spectroscopy to investigate the spectra of Xe V and Xe VI. The radiation emitted following electron capture by 50 keV Xe 5+ and 60 keV Xe 6+ ions impinging on a He (Ar) gas target has been recorded in the 350-6000 (1200-2500) A wavelength region. A number of new energy levels of Xe V and Xe VI have been established from lines identified by us. In particular, we have observed and identified transitions from the 5s 2 5p4f (5s 2 4f) configuration of Xe V (Xe VI). The analysis was supported by Hartree-Fock calculations. (orig.)

  7. Estimating RMR Values for Underground Excavations in a Rock Mass

    Directory of Open Access Journals (Sweden)

    Vítor Santos

    2018-02-01

    Full Text Available During underground excavations for civil or mining engineering purposes, the variations in rock mass quality are important, especially for the design of the most suitable support to be applied to ensure stability. The aim of this investigation is to model the expected behavior of the ground, and thus to predict the scenarios indicating potential variations in the quality of the rock mass during underground excavation. When considering the rock mass rating (RMR values observed at the excavation face in six study cases, which together total more than 27 km in length of underground excavation by drilling and blasting (D&B, and based on the observed RMR values at the face, the most probable value (1–100 is estimate for the RMR index at the five subsequent front advances. It is concluded that, up to about 20 m ahead of the current face, the quality of the rock mass for the next advances is close to the quality observed at the present face, and that, with increasing distance, there is a greater deviation of RMR values with respect to the quality observed at the current face.

  8. Underground reactor containments: An option for the future?

    International Nuclear Information System (INIS)

    Forsberg, C.W.; Kress, T.

    1997-01-01

    Changing world conditions and changing technologies suggest that serious consideration should be given to siting of nuclear power plants underground. Underground siting is not a new concept. Multiple research reactors, several weapons production reactors, and one power reactor have been built underground. What is new are the technologies and incentives that may now make underground siting a preferred option. The conditions and technologies, along with their implications, are discussed herein. Underground containments can be constructed in mined cavities or pits that are then backfilled with thick layers of rock and soil. Conventional above-ground containments resist assaults and accidents because of the strength of their construction materials and the effectiveness of their safety features that are engineered to reduce loads. However, underground containments can provide even more resistance to assaults and accidents because of the inertia of the mass of materials over the reactor. High-technology weapons or some internal accidents can cause existing strong-material containments to fail, but only very-high energy releases can move large inertial masses associated with underground containments. New methods of isolation may provide a higher confidence in isolation that is independent of operator action

  9. Bedrock instability of underground storage systems in the Czech Republic, Central Europe

    Czech Academy of Sciences Publication Activity Database

    Nováková, Lucie; Brož, Milan; Záruba, J.; Sosna, K.; Najser, J.; Rukavičková, L.; Franěk, J.; Rudajev, V.

    2016-01-01

    Roč. 13, č. 2 (2016), s. 315-325 ISSN 1672-7975 R&D Projects: GA MPO(CZ) FR-TI1/367 Institutional support: RVO:67985891 ; RVO:67985530 Keywords : underground storage * instability * seismicity * Bohemian Massif Subject RIV: DD - Geochemistry Impact factor: 0.796, year: 2016

  10. Underground infrastructure damage for a Chicago scenario

    Energy Technology Data Exchange (ETDEWEB)

    Dey, Thomas N [Los Alamos National Laboratory; Bos, Rabdall J [Los Alamos National Laboratory

    2011-01-25

    Estimating effects due to an urban IND (improvised nuclear device) on underground structures and underground utilities is a challenging task. Nuclear effects tests performed at the Nevada Test Site (NTS) during the era of nuclear weapons testing provides much information on how underground military structures respond. Transferring this knowledge to answer questions about the urban civilian environment is needed to help plan responses to IND scenarios. Explosions just above the ground surface can only couple a small fraction of the blast energy into an underground shock. The various forms of nuclear radiation have limited penetration into the ground. While the shock transmitted into the ground carries only a small fraction of the blast energy, peak stresses are generally higher and peak ground displacement is lower than in the air blast. While underground military structures are often designed to resist stresses substantially higher than due to the overlying rocks and soils (overburden), civilian structures such as subways and tunnels would generally only need to resist overburden conditions with a suitable safety factor. Just as we expect the buildings themselves to channel and shield air blast above ground, basements and other underground openings as well as changes of geology will channel and shield the underground shock wave. While a weaker shock is expected in an urban environment, small displacements on very close-by faults, and more likely, soils being displaced past building foundations where utility lines enter could readily damaged or disable these services. Immediately near an explosion, the blast can 'liquefy' a saturated soil creating a quicksand-like condition for a period of time. We extrapolate the nuclear effects experience to a Chicago-based scenario. We consider the TARP (Tunnel and Reservoir Project) and subway system and the underground lifeline (electric, gas, water, etc) system and provide guidance for planning this scenario.

  11. Ecology and economic estimate of using of the underground excavation space

    International Nuclear Information System (INIS)

    Umnov, V.A.; Tarasov, V.F.; Tret'yakov, I.O.; Sheloumov, A.A.

    1995-01-01

    Stages of ecological and economic estimates of utilizing underground space, including evaluation of underground space resources, selection of its utilization trends and substantiation of optimal parameters for selected trends, are considered. Certain directions of possible repeated utilization of mining excavations are shown, including underground hydropower stations, underground energy storages, underground nuclear stations. Underground waste disposal is one of the most available directions in utilization of the underground space presently. Evaluation of the underground space utilization at all stages envisages complete account of all economical, social and ecological results

  12. Legal considerations for urban underground space development in Malaysia

    Directory of Open Access Journals (Sweden)

    F. Zaini

    2017-12-01

    Full Text Available In 2008, the Malaysia land code, named the National Land Code 1965 (NLC 1965, was amended to add Part Five (A to deal with the disposal of underground space. In addition, the Circular of the Director General of Lands and Mines No. 1/2008 was issued to assist the application of Part Five (A of the NLC 1965. However, the legislation is still questionable and has instigated many arguments among numerous actors. Therefore, this research was undertaken to examine legal considerations for the development of underground space. The focus is on four legal considerations, namely underground space ownership, the bundle of rights, depth, and underground space utilization. Rooted in qualitative methods, interviews were conducted with respondents involved in the development of underground space in Malaysia. The obtained data were then analyzed descriptively. The findings differentiated the rights of landowners for surface land and underground space, and their liability for damages and the depth. It was indicated that the current legislation in Malaysia, namely Part Five (A of the NLC 1965 and the Circular of the Director General of Lands and Mines No. 1/2008, is adequate to facilitate the development of underground space in terms of legal considerations. However, to further facilitate the development of underground land in the future, based on the research, four enhancements are recommended for legal considerations pertaining to the development of underground space in Malaysia. Keywords: Underground space, Legal consideration, Land right, Urban development

  13. Earthquake damage to underground facilities

    International Nuclear Information System (INIS)

    Pratt, H.R.; Stephenson, D.E.; Zandt, G.; Bouchon, M.; Hustrulid, W.A.

    1980-01-01

    In order to assess the seismic risk for an underground facility, a data base was established and analyzed to evaluate the potential for seismic disturbance. Substantial damage to underground facilities is usually the result of displacements primarily along pre-existing faults and fractures, or at the surface entrance to these facilities. Evidence of this comes from both earthquakes and large explosions. Therefore, the displacement due to earthquakes as a function of depth is important in the evaluation of the hazard to underground facilities. To evaluate potential displacements due to seismic effects of block motions along pre-existing or induced fractures, the displacement fields surrounding two types of faults were investigated. Analytical models were used to determine relative displacements of shafts and near-surface displacement of large rock masses. Numerical methods were used to determine the displacement fields associated with pure strike-slip and vertical normal faults. Results are presented as displacements for various fault lengths as a function of depth and distance. This provides input to determine potential displacements in terms of depth and distance for underground facilities, important for assessing potential sites and design parameters

  14. 30 CFR 57.4461 - Gasoline use restrictions underground.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Gasoline use restrictions underground. 57.4461... Prevention and Control Flammable and Combustible Liquids and Gases § 57.4461 Gasoline use restrictions underground. If gasoline is used underground to power internal combustion engines— (a) The mine shall be...

  15. Different roles of ROS and Nrf2 in Cr(VI)-induced inflammatory responses in normal and Cr(VI)-transformed cells

    Energy Technology Data Exchange (ETDEWEB)

    Roy, Ram Vinod; Pratheeshkumar, Poyil; Son, Yong-Ok; Wang, Lei [Center for Research on Environmental Disease, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Department of Toxicology and Cancer Biology, College of Medicine, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Hitron, John Andrew [Center for Research on Environmental Disease, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Divya, Sasidharan Padmaja; Zhang, Zhuo [Department of Toxicology and Cancer Biology, College of Medicine, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Shi, Xianglin, E-mail: xshi5@email.uky.edu [Center for Research on Environmental Disease, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States)

    2016-09-15

    Hexavalent chromium (Cr(VI)) is classified as a human carcinogen. Cr(VI) has been associated with adenocarcinomas and squamous cell carcinoma of the lung. The present study shows that acute Cr(VI) treatment in human bronchial epithelial cells (BEAS-2B) increased inflammatory responses (TNF-α, COX-2, and NF-кB/p65) and expression of Nrf2. Cr(VI)-induced generation of reactive oxygen species (ROS) are responsible for increased inflammation. Despite the fact that Nrf2 is a master regulator of response to oxidative stress, silencing of Nrf2 in the acute Cr(VI) treatment had no effect on Cr(VI)-induced inflammation. In contrast, in Cr(VI)-transformed (CrT) cells, Nrf2 is constitutively activated. Knock-down of this protein resulted in decreased inflammation, while silencing of SOD2 and CAT had no effect in the expression of these inflammatory proteins. Results obtained from the knock-down of Nrf2 in CrT cells are very different from the results obtained in the acute Cr(VI) treatment. In BEAS-2B cells, knock-down of Nrf2 had no effect in the inflammation levels, while in CrT cells a decrease in the expression of inflammation markers was observed. These results indicate that before transformation, ROS plays a critical role while Nrf2 not in Cr(VI)-induced inflammation, whereas after transformation (CrT cells), Nrf2 is constitutively activated and this protein maintains inflammation while ROS not. Constitutively high levels of Nrf2 in CrT binds to the promoter regions of COX-2 and TNF-α, leading to increased inflammation. Collectively, our results demonstrate that before cell transformation ROS are important in Cr(VI)-induced inflammation and after transformation a constitutively high level of Nrf2 is important. - Highlights: • Cr(VI)-induced ROS increased inflammation, while Nrf2 had no effect. • In the CrT cells knock-down of Nrf2 resulted in decreased inflammation. • Mechanistic differences in regulating Cr(VI)-induced inflammation.

  16. Radon study in underground buildings in Chongqing, China

    International Nuclear Information System (INIS)

    Deng Wen; Jiang Rende; Liu Yigang

    1993-01-01

    Radon concentration measurements using a scintillation detector were conducted in 51 large underground buildings, which have been used as hotels, entertainment halls, restaurants, shops and factories, etc, in Chongqing, China. The results showed that the radon concentrations in these underground buildings ranged from 3.2 to 616.2 Bqm -3 . The arithmetic mean was 57.6 Bqm -3 , which was about 4 times as much as the mean radon concentration in ground buildings in Chongqing. The underground buildings with the highest radon concentrations were correlated with the high content of radium-226 in building materials, mechanical ventilation through interior circulatory ducts, underground depth of the building, and particularly, fissures in the walls. Measures of radon mitigation in underground buildings were recommended. (orig.). (3 refs., 5 tabs.)

  17. Construction and maintenance of underground mine roads

    Energy Technology Data Exchange (ETDEWEB)

    Logan, A.S.; Seedsman, R.W. [Coffey Partners International Pty. Ltd. (Australia)

    1995-12-31

    Good roads are essential in moving men and materials to and from the underground workplace. An underground coal industry funded project was recently completed on underground mine road construction and maintenance. This paper discusses practical approaches to construction and maintenance of underground mine roads using transferable civil technologies and innovative techniques. Mine pavements are generally low-cost (relative to civil roads), constructed to varying standards using locally available materials to best meet the mobility needs of the mine. Performance of pavements is thus largely dependent on the environmental conditions, quality of the available road making materials, maintenance policies and available resources. This paper explains the causes of bad roads in various underground environments. It details available management strategies, construction and water control techniques, road maintenance and vehicle considerations. It concludes that the trend to larger rubber tires mining equipment needs to be matched with construction and maintenance of high quality road surfaces. For large operations, the total cost due to poor roads may equate to in excess of $A1 million per annum. The strategies outlined in this paper provide the basis for construction and maintenance of underground mine roads to help achieve desired production targets. (author). 2 tabs., 4 figs., 7 refs.

  18. Underground ventilation remote monitoring and control system

    International Nuclear Information System (INIS)

    Strever, M.T.; Wallace, K.G. Jr.; McDaniel, K.H.

    1995-01-01

    This paper presents the design and installation of an underground ventilation remote monitoring and control system at the Waste Isolation Pilot Plant. This facility is designed to demonstrate safe underground disposal of U.S. defense generated transuranic nuclear waste. To improve the operability of the ventilation system, an underground remote monitoring and control system was designed and installed. The system consists of 15 air velocity sensors and 8 differential pressure sensors strategically located throughout the underground facility providing real-time data regarding the status of the ventilation system. In addition, a control system was installed on the main underground air regulators. The regulator control system gives indication of the regulator position and can be controlled either locally or remotely. The sensor output is displayed locally and at a central surface location through the site-wide Central Monitoring System (CMS). The CMS operator can review all sensor data and can remotely operate the main underground regulators. Furthermore, the Virtual Address Extension (VAX) network allows the ventilation engineer to retrieve real-time ventilation data on his personal computer located in his workstation. This paper describes the types of sensors selected, the installation of the instrumentation, and the initial operation of the remote monitoring system

  19. [The Research Advancement and Conception of the Deep-underground Medicine].

    Science.gov (United States)

    Xie, He-Ping; Liu, Ji-Feng; Gao, Ming-Zhong; Wan, Xue-Hong; Liu, Shi-Xi; Zou, Jian; Wu, Jiang; Ma, Teng-Fei; Liu, Yi-Lin; Bu, Hong; Li, Wei-Min

    2018-03-01

    The 21th century is the century of exploring and utilizing the underground space. In the future, more and more people will spend more and more time living or/and working in the underground space. However,we know little about the effect on the health of human caused by the underground environment. Herein,we systematically put forward the strategic conception of the deep-underground medicine,in order to reveal relative effects and mechanism of the potential factors in the deep underground space on human's physiological and psychological healthy,and to work out the corresponding countermeasures. The original deep-underground medicine includes the following items. ①To model different depth of underground environment according to various parameters (such as temperature,radiation,air pressure, rock,microorganism), and to explore their quantitative character and effects on human health and mechanism. ② To study the psychological change, maintenance of homeostasis and biothythm of organism in the deep underground space. ③ To learn the association between psychological healthy of human and the depth, structure, physical environment and working time of underground space. ④ To investigate the effect of different terrane and lithology on healthy of human and to deliberate their contribution on organism growth. ⑤ To research the character and their mechanism of growth,metabolism,exchange of energy,response of growth, aging and adaptation of cells living in deep underground space. ⑥ To explore the physiological feature,growth of microbiome and it's interaction with host in the deep underground space. ⑦ To develop deep-underground simulation space, the biologically medical technology and equipments. As a research basis,a deep-underground medical lab under a rock thickness of about 1 470 m has been built,which aims to operate the research of the effect on living organism caused by different depth of underground environment. Copyright© by Editorial Board of Journal

  20. Review of underground siting of nuclear power plants

    International Nuclear Information System (INIS)

    1974-01-01

    A review of the potential for the underground siting of nuclear power generating plants has been undertaken. The review comprised a survey and assessment of relevant published documents currently available, together with discussions with Government sponsored agencies and other bodies, to evaluate the current status of technology related to the design and construction of underground nuclear power plants. It includes a review of previous work related to the underground siting of power plants and other facilities; a preliminary evaluation of the relative merits of the various concepts of undergrounding which have been proposed or constructed; a review of current technology as it relates to the requirements for the design, construction and operation of underground nuclear power plants; an examination of the safety and environmental aspects; and the identification of areas of further study which will be required if the underground is to be established as a fully viable alternative to surface siting. No attempt has been made to draw final conclusions at this stage. Nothing has been found to suggest that the underground siting concept could not provide a viable alternative to the surface concept. It is also apparent that no major technological developments are required. It is not clear, however, whether the improvements in safety and containment postulated for the underground can be realized at an economic cost; or even whether any additional cost is in fact involved. The problem is essentially site dependent and requires further study for which recommendations are made. (auth)

  1. Kinetic investigations of quinoline oxidation by ferrate(VI).

    Science.gov (United States)

    Luo, Zhiyong; Li, Xueming; Zhai, Jun

    2016-01-01

    Quinoline is considered as one of the most toxic and carcinogenic compounds and is commonly found in industrial wastewaters, which require treatment before being discharged. Removal of quinoline by the use of an environmentally friendly oxidant, potassium ferrate(VI) (K2FeO4), was assessed by studying the kinetics of the oxidation of quinoline by ferrate(VI) (Fe(VI)) as a function of pH (8.53-10.53) and temperature (21-36°C) in this work. The reaction of quinoline with Fe(VI) was found to be first order in Fe(VI), half order in quinoline, and 1.5 order overall. The observed rate constant at 28°C decreased non-linearly from 0.5334 to 0.2365 M(-0.5) min(-1) with an increase in pH from 8.53 to 10.03. Considering the equilibria of Fe(VI) and quinoline, the reaction between quinoline and Fe(VI) contained two parallel reactions under the given pH conditions. The individual rate constants of these two reactions were determined. The results indicate that the protonated species of Fe(VI) reacts more quickly with quinoline than the deprotonated form of Fe(VI). The reaction activation energy Ea was obtained to be 51.44 kJ·mol(-1), and it was slightly lower than that of conventional chemical reaction. It reveals that the oxidation of quinoline by Fe(VI) is feasible in the routine water treatment.

  2. Immunization with the conjugate vaccine Vi-CRM₁₉₇ against Salmonella typhi induces Vi-specific mucosal and systemic immune responses in mice.

    Science.gov (United States)

    Fiorino, Fabio; Ciabattini, Annalisa; Rondini, Simona; Pozzi, Gianni; Martin, Laura B; Medaglini, Donata

    2012-09-21

    Typhoid fever is a public health problem, especially among young children in developing countries. To address this need, a glycoconjugate vaccine Vi-CRM₁₉₇, composed of the polysaccharide antigen Vi covalently conjugated to the non-toxic mutant of diphtheria toxin CRM₁₉₇, is under development. Here, we assessed the antibody and cellular responses, both local and systemic, following subcutaneous injection of Vi-CRM₁₉₇. The glycoconjugate elicited Vi-specific serum IgG titers significantly higher than unconjugated Vi, with prevalence of IgG1 that persisted for at least 60 days after immunization. Vi-specific IgG, but not IgA, were present in intestinal washes. Lymphocytes proliferation after restimulation with Vi-CRM₁₉₇ was observed in spleen and mesenteric lymph nodes. These data confirm the immunogenicity of Vi-CRM₁₉₇ and demonstrate that the vaccine-specific antibody and cellular immune responses are present also in the intestinal tract, thus strengthening the suitability of Vi-CRM₁₉₇ as a promising candidate vaccine against Salmonella Typhi. Copyright © 2012 Elsevier Ltd. All rights reserved.

  3. 30 CFR 57.4761 - Underground shops.

    Science.gov (United States)

    2010-07-01

    ... Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and... toxic gases from a fire originating in an underground shop where maintenance work is routinely done on...

  4. Mechanism of the reduction of hexavalent chromium by organo-montmorillonite supported iron nanoparticles

    International Nuclear Information System (INIS)

    Wu, Pingxiao; Li, Shuzhen; Ju, Liting; Zhu, Nengwu; Wu, Jinhua; Li, Ping; Dang, Zhi

    2012-01-01

    Highlights: ► Organo-montmorillonite supported iron nanoparticles were found to be more efficient in the removal of Cr(VI) than unsupported iron nanoparticles. ► The iron nanoparticles were accommodated by the sectional structure of the clay minerals which were helpful to protect the nanoparticles from aggregating. ► XPS and XANES provided some direct information about the reduction mechanisms. ► The structure of the supported iron nanoparticles was stable in the reaction with Cr(VI). - Abstract: Iron nanoparticles exhibit greater reactivity than micro-sized Fe 0 , and they impart advantages for groundwater remediation. In this paper, supported iron nanoparticles were synthesized to further enhance the speed and efficiency of remediation. Natural montmorillonite and organo-montmorillonite were chosen as supporting materials. The capacity of supported iron nanoparticles was evaluated, compared to unsupported iron nanoparticles, for the reduction of aqueous Cr(VI). The reduction of Cr(VI) was much greater with organo-montmorillonite supported iron nanoparticles and fitted the pseudo-second order equation better. With a dose at 0.47 g/L, a total removal capacity of 106 mg Cr/g Fe 0 was obtained. Other factors that affect the efficiency of Cr(VI) removal, such as pH values, the initial Cr(VI) concentration and storage time of nanoparticles were investigated. X-ray photoelectron spectrometry (XPS) and X-ray absorption near edge structure (XANES) were used to figure out the mechanism of the removal of Cr(VI). XPS indicated that the Cr(VI) bound to the particle surface was completely reduced to Cr(III) under a range of conditions. XANES confirmed that the Cr(VI) reacted with iron nanoparticles was completely reduced to Cr(III).

  5. Simulation of Underground Muon Flux with Application to Muon Tomography

    Science.gov (United States)

    Yamaoka, J. A. K.; Bonneville, A.; Flygare, J.; Lintereur, A.; Kouzes, R.

    2015-12-01

    Muon tomography uses highly energetic muons, produced by cosmic rays interacting within the upper atmosphere, to image dense materials. Like x-rays, an image can be constructed from the negative of the absorbed (or scattered) muons. Unlike x-rays, these muons can penetrate thousands of meters of earth. Muon tomography has been shown to be useful across a wide range of applications (such as imaging of the interior of volcanoes and cargo containers). This work estimates the sensitivity of muon tomography for various underground applications. We use simulations to estimate the change in flux as well as the spatial resolution when imaging static objects, such as mine shafts, and dynamic objects, such as a CO2 reservoir filling over time. We present a framework where we import ground density data from other sources, such as wells, gravity and seismic data, to generate an expected muon flux distribution at specified underground locations. This information can further be fed into a detector simulation to estimate a final experimental sensitivity. There are many applications of this method. We explore its use to image underground nuclear test sites, both the deformation from the explosion as well as the supporting infrastructure (access tunnels and shafts). We also made estimates for imaging a CO2 sequestration site similar to Futuregen 2.0 in Illinois and for imaging magma chambers beneath the Cascade Range volcanoes. This work may also be useful to basic science, such as underground dark matter experiments, where increasing experimental sensitivity requires, amongst other factors, a precise knowledge of the muon background.

  6. Deeper underground

    Energy Technology Data Exchange (ETDEWEB)

    Brearley, D. [Pantek Ltd. (United Kingdom)

    2005-12-01

    The paper describes how efficient data gathering has led to production and uptime improvements in UK Coal's Daw Mill colliery in Warwickshire. Software called FactorySuite A{sup 2} from Wonderware is being used to control and monitor all underground production and conveying. 3 photos.

  7. Electrochemical alkaline Fe(VI) water purification and remediation.

    Science.gov (United States)

    Licht, Stuart; Yu, Xingwen

    2005-10-15

    Fe(VI) is an unusual and strongly oxidizing form of iron, which provides a potentially less hazardous water-purifying agent than chlorine. A novel on-line electrochemical Fe(VI) water purification methodology is introduced. Fe(VI) addition had been a barrier to its effective use in water remediation, because solid Fe(VI) salts require complex (costly) syntheses steps and solutions of Fe(VI) decompose. Online electrochemical Fe(VI) water purification avoids these limitations, in which Fe(VI) is directly prepared in solution from an iron anode as the FeO42- ion, and is added to the contaminant stream. Added FeO42- decomposes, by oxidizing a wide range of water contaminants including sulfides (demonstrated in this study) and other sulfur-containing compounds, cyanides (demonstrated in this study), arsenic (demonstrated in this study), ammonia and other nitrogen-containing compounds (previously demonstrated), a wide range of organics (phenol demonstrated in this study), algae, and viruses (each previously demonstrated).

  8. Electronic structure, fluorescence and photochemistry of the uranyl ion, and comparison with octahedral uranium (VI), ruthenyl (VI), rhenium (V) and osmium (VI) complexes

    Energy Technology Data Exchange (ETDEWEB)

    Joergensen, C K [Geneva Univ. (Switzerland)

    1977-01-01

    The highly anisotropic uranyl complexes (with very short U-O distances and very long distances to the ligating atoms in the equatorial plane) are compared with trans-dioxo complexes of 4d/sup 2/Ru(VI) and 5d/sup 2/Re(V) and Os(VI). A major difference is the low-lying empty 5f orbitals, and the first excited state is highly oxidizing, and sufficiently long-lived to abstract hydrogen atoms from most organic molecules. It is argued that even the low concentrations of uranyl carbonate present in sea water is excited by solar radiation roughly every 10 minutes. Octahedral U(VI)O/sub 6/ in perovskites and UF/sub 6/ are also discussed, as well as trans-lawrencium chemistry.

  9. Waste Isolation Pilot Plant supplementary roof support system underground storage area, Panel 1, Room 1

    International Nuclear Information System (INIS)

    1991-10-01

    WIPP is designed to provide a full-scale facility to demonstrate the technical and operational principles for permanent isolation of defense-generated transuranic waste. It is also designed to provide a facility in which studies and experiments can be conducted. Bin Scale Tests are being planned as part of the WIPP Test Phase Performance Assessment Program described in the WIPP Test Phase Plan: Performance Assessment (DOE 1990 b). These Tests are anticipated to be conducted over a period of up to seven years. Room 1 of Panel 1 of the Underground Storage Area is to be used as the location of the Bin-Scale Tests to investigate the generation of gas from the waste that is proposed to be stored at the WIPP in the near future. The original design for the waste storage rooms in Panel 1 provided for a limited period of time during which to mine the openings and to emplace waste. Room 1 was initially mined to rough dimensions in 1986. Information obtained from the Site and Preliminary Design Validation (SPDV) program showed that the rooms would remain stable without ground support and that creep closure would not adversely affect equipment clearances during at least five years following excavation

  10. Design of underground layout and their maintenance

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Bok Youn; Kang, Chang Hee; Jo, Young Do; Lim, Sang Taek [Korea Institute of Geology Mining and Materials, Taejon (Korea, Republic of)

    1997-12-01

    Layout of underground structure has to be designed based on rock mechanical analysis and the concept of active support has to be adopted considering the large openings are requested to accommodate heavy duty diesel equipment in underground. Rock bolt and shotcrete will be the most applicable method to support such a large dimensional tunnels. 1) Direction: The main haulage way of the mines where diesel equipment are operating is ramp way system. For optimizing safety measures, and minimizing maintenance cost of the tunnels, it is strongly recommended that all the tunnels including ramp way, rooms and sublevels should be designed in parallel to the direction of principal stress and perpendicular to the direction of major discontinuity. 2) Inclination: Basically, the inclination of the ramp way depends on the specification of the equipment, but 10-15% is usual. The steep inclination needs less initial investment but there will be an adverse effects such as higher operating and maintenance costs. 3) Profile (Cross section): The maximum dimension of the equipment operating in local mines appeared 12.8m long, 3.705m wide and 3.68m high. Considering the dimension, the requested profile simply can be calculated to 4m x 4m, but it should be decided according to the regulated minimum clearances from the walls and roof. The minimum inner curvature radius of the tunnels should be more than 5.2m, and in this case, the tunnel width of the curved zone should be more than 5.5m. 4) Sight distance and braking distance: For the safe operation of the equipment, the sight distance must be longer than braking distance, so that the driver can hold up the equipment safely after finding the obstacles in front of him. The maximum braking distance without heating of brake shoe is 60m. 5) Support and maintenance: Due to the large dimensional tunnels where diesel equipment are operating, the conventional supporting system is not applicable. Therefore, the active support concept should be

  11. Underground science initiatives at Los Alamos

    International Nuclear Information System (INIS)

    Simmons, L.M. Jr.

    1985-01-01

    Recently, the Los Alamos National Laboratory has proposed two major new initiatives in underground science. Following the dissolution of the original gallium solar neutrino collaboration, Los Alamos has formed a new North American collaboration. We briefly review the rationale for solar neutrino research, outline the proposal and new Monte Carlo simulations, and describe the candidate locations for the experiment. Because there is no dedicated deep underground site in North America suitable for a wide range of experiments, Los Alamos has conducted a survey of possible sites and developed a proposal to create a new National Underground Science Facility. This paper also reviews that proposal

  12. Biosorption of Cr(VI) by coconut coir: Spectroscopic investigation on the reaction mechanism of Cr(VI) with lignocellulosic material

    International Nuclear Information System (INIS)

    Shen, Ying-Shuian; Wang, Shan-Li; Huang, Shiuh-Tsuen; Tzou, Yu-Min; Huang, Jang-Hung

    2010-01-01

    In this study, the removal mechanism of Cr(VI) from water by coconut coir (CC) was investigated using X-ray photoelectron spectroscopy (XPS), Cr K-edge X-ray absorption near edge structure (XANES) and FTIR spectroscopy. The results showed that, upon reaction with CC at pH 3, Cr(VI) was reduced to Cr(III), which was either bound to CC or released back into solution. As revealed by the FTIR spectra of CC before and after reacting with Cr(VI), the phenolic methoxyl and hydroxyl groups of lignin in CC are the dominant drivers of Cr(VI) reduction, giving rise to carbonyl and carboxyl groups on CC. These functional groups can subsequently provide binding sites for Cr(III) resulting from Cr(VI) reduction. In conjunction with forming complexes with carbonyl and carboxyl groups, the formation of Cr(III) hydroxide precipitate could also readily occur as revealed by the linear combination fitting of the Cr K-edge XANES spectrum using a set of reference compounds. The phenolic groups in lignin are responsible for initiating Cr(VI) reduction, so lignocellulosic materials containing a higher amount of phenolic groups are expected to be more effective scavengers for removal of Cr(VI) from the environment.

  13. Biosorption of Cr(VI) by coconut coir: Spectroscopic investigation on the reaction mechanism of Cr(VI) with lignocellulosic material

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Ying-Shuian [Department of Soil and Environmental Sciences, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 40227, Taiwan (China); Wang, Shan-Li, E-mail: slwang@nchu.edu.tw [Department of Soil and Environmental Sciences, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 40227, Taiwan (China); Huang, Shiuh-Tsuen [Department of Soil and Environmental Sciences, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 40227, Taiwan (China); Department of Science Application and Dissemination, National Taichung University, Taichung, Taiwan (China); Tzou, Yu-Min; Huang, Jang-Hung [Department of Soil and Environmental Sciences, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 40227, Taiwan (China)

    2010-07-15

    In this study, the removal mechanism of Cr(VI) from water by coconut coir (CC) was investigated using X-ray photoelectron spectroscopy (XPS), Cr K-edge X-ray absorption near edge structure (XANES) and FTIR spectroscopy. The results showed that, upon reaction with CC at pH 3, Cr(VI) was reduced to Cr(III), which was either bound to CC or released back into solution. As revealed by the FTIR spectra of CC before and after reacting with Cr(VI), the phenolic methoxyl and hydroxyl groups of lignin in CC are the dominant drivers of Cr(VI) reduction, giving rise to carbonyl and carboxyl groups on CC. These functional groups can subsequently provide binding sites for Cr(III) resulting from Cr(VI) reduction. In conjunction with forming complexes with carbonyl and carboxyl groups, the formation of Cr(III) hydroxide precipitate could also readily occur as revealed by the linear combination fitting of the Cr K-edge XANES spectrum using a set of reference compounds. The phenolic groups in lignin are responsible for initiating Cr(VI) reduction, so lignocellulosic materials containing a higher amount of phenolic groups are expected to be more effective scavengers for removal of Cr(VI) from the environment.

  14. Biosorption of Cr(VI) by coconut coir: spectroscopic investigation on the reaction mechanism of Cr(VI) with lignocellulosic material.

    Science.gov (United States)

    Shen, Ying-Shuian; Wang, Shan-Li; Huang, Shiuh-Tsuen; Tzou, Yu-Min; Huang, Jang-Hung

    2010-07-15

    In this study, the removal mechanism of Cr(VI) from water by coconut coir (CC) was investigated using X-ray photoelectron spectroscopy (XPS), Cr K-edge X-ray absorption near edge structure (XANES) and FTIR spectroscopy. The results showed that, upon reaction with CC at pH 3, Cr(VI) was reduced to Cr(III), which was either bound to CC or released back into solution. As revealed by the FTIR spectra of CC before and after reacting with Cr(VI), the phenolic methoxyl and hydroxyl groups of lignin in CC are the dominant drivers of Cr(VI) reduction, giving rise to carbonyl and carboxyl groups on CC. These functional groups can subsequently provide binding sites for Cr(III) resulting from Cr(VI) reduction. In conjunction with forming complexes with carbonyl and carboxyl groups, the formation of Cr(III) hydroxide precipitate could also readily occur as revealed by the linear combination fitting of the Cr K-edge XANES spectrum using a set of reference compounds. The phenolic groups in lignin are responsible for initiating Cr(VI) reduction, so lignocellulosic materials containing a higher amount of phenolic groups are expected to be more effective scavengers for removal of Cr(VI) from the environment. 2010 Elsevier B.V. All rights reserved.

  15. Underground design Laxemar, Layout D2

    Energy Technology Data Exchange (ETDEWEB)

    2009-11-15

    Laxemar candidate area is located in the province of Smaaland, some 320 km south of Stockholm. The area is located close to the shoreline of the Baltic Sea and is within the municipality of Oskarshamn, and immediately west of the Oskarshamn nuclear power plant and the Central interim storage facility for spent fuel (Clab). The easternmost part (Simpevarp subarea) includes the Simpevarp peninsula, which hosts the power plants and the Clab facility. The island of Aespoe, containing the Aespoe Hard Rock Laboratory is located some three kilometres northeast of the central parts of Laxemar. The Laxemar subarea covers some 12.5 km2, compared with the Simepvarp subarea, which is approximately 6.6 km2. The Laxemar candidate area has been investigated in stages, referred to as the initial site investigations (ISI) and the complete site investigations (CSI). These investigations commenced in 2002 and were completed in 2008. During the site investigations, several studies and design steps (D0, D1 and D2) were carried out to ensure that sufficient space was available for the 6,000-canister layout within the target volume at a depth of approximately 500 m. The findings from design Step D2 for the underground facilities including the access ramp, shafts, rock caverns in a Central Area, transport tunnels, and deposition tunnels and deposition holes are contained in this report. The layout for these underground excavations at the deposition horizon requires an area of 5.7 km2, and the total rock volume to be excavated is 3,008 x 103 m3 using a total tunnel length of approximately 115 km. The behaviour of the underground openings associated with this layout is expected to be similar to the behaviour of other underground openings in the Scandinavian shield at similar depths. The dominant mode of instability is expected to be structurally controlled wedge failure. Stability of the openings will be achieved with traditional underground rock support and by orienting the openings

  16. Isolation of a star-shaped uranium(V/VI) cluster from the anaerobic photochemical reduction of uranyl(VI)

    International Nuclear Information System (INIS)

    Chatelain, Lucile; White, Sarah; Scopelliti, Rosario; Mazzanti, Marinella

    2016-01-01

    Actinide oxo clusters are an important class of compounds due to their impact on actinide migration in the environment. The photolytic reduction of uranyl(VI) has potential application in catalysis and spent nuclear fuel reprocessing, but the intermediate species involved in this reduction have not yet been elucidated. Here we show that the photolysis of partially hydrated uranyl(VI) in anaerobic conditions leads to the reduction of uranyl(VI), and to the incorporation of the resulting U V species into the stable mixed-valent star-shaped U VI /U V oxo cluster [U(UO 2 ) 5 (μ 3 -O) 5 (PhCOO) 5 (Py) 7 ]. This cluster is only the second example of a U VI /U V cluster and the first one associating uranyl groups to a non-uranyl(V) center. The U V center in 1 is stable, while the reaction of uranyl(V) iodide with potassium benzoate leads to immediate disproportionation and formation of the U 12 IV U 4 V O 24 cluster {[K(Py) 2 ] 2 [K(Py)] 2 [U 16 O 24 (PhCOO) 24 (Py) 2 ]}.

  17. Comparison of U(VI) adsorption onto nanoscale zero-valent iron and red soil in the presence of U(VI)–CO_3/Ca–U(VI)–CO_3 complexes

    International Nuclear Information System (INIS)

    Zhang, Zhibin; Liu, Jun; Cao, Xiaohong; Luo, Xuanping; Hua, Rong; Liu, Yan; Yu, Xiaofeng; He, Likai

    2015-01-01

    Highlights: • NZVI can be used for adsorbing U(VI)–CO_3 complexes. • Use of NZVI is feasible for remediation of uranium-contaminated soils. • The mechanism of U(VI)–CO_3 complexes adsorbing onto NZVI has been explained. - Abstract: The influence of U(VI)–CO_3 and Ca–U(VI)–CO_3 complexes on U(VI) adsorption onto red soil and nanoscale zero-valent iron (NZVI) was investigated using batch adsorption and fixed-bed column experiments to simulate the feasibility of NZVI as the reactive medium in permeable- reactive barriers (PRB) for in situ remediation of uranium-contaminated red soils. The adsorption capacity (q_e) and distribution constant (K_d) of NZVI and red soil decreased with increasing pH, dissolved carbonate and calcium concentrations, but the q_e and K_d values of NZVI were 5–10 times higher than those of red soil. The breakthrough pore volume (PV) values increased with the decrease of pH, dissolved carbonate and calcium concentration; however, the breakthrough PV values of the PRB column filled with 5% NZVI were 2.0–3.5 times higher than the 100% red soil column. The U(VI)–CO_3 complexes adsorbed onto the surface of red soil/NZVI (≡SOH) to form SO–UO_2CO_3"− or SO–UO_2 (CO_3)_2"3"−. XPS and XRD analysis further confirmed the reduction of U(VI) to U(IV) and the formation of FeOOH on NZVI surfaces. The findings of this study are significant to the remediation of uranium-contaminated red soils and the consideration of practical U(VI) species in the natural environment.

  18. Transmission line undergrounding : rate impact investigation and analysis

    International Nuclear Information System (INIS)

    2004-01-01

    In response to concerns expressed by the residents of Markham, Ontario regarding the possible environmental and health impacts of a proposed 230 kV overhead transmission line, Hydro One Networks Inc. (HONI) has proposed to place the line underground as an alternative. This analysis was prepared to evaluate the potential impacts on transmission rates and consumer prices related to changes in the level of underground construction of transmission lines by HONI, as opposed to overhead construction. The report presents the approach to data collection; cost estimates and projections; the modeling and projecting of HONI's regulated rate base and revenue requirement on a basis that reflects the manner in which its future transmission rates are expected to be established; estimates of the incremental cost of undergrounding reflecting a range of reasonable assumptions; and a comparison of the resulting transmission costs and total customer bill. To address the issue of potential demand in other municipalities for additional undergrounding, the study also examined the cumulative effects of ten years' incremental undergrounding costs (i.e. effects on 2014 rates). It was concluded that if HONI were to implement an undergrounding program beginning in 2005, resulting in the installation of 80 km of underground lines by 2014, and shared costs by all users of HONI's system through the network transmission charges, the 2014 transmission rates would be higher. 5 tabs

  19. UNDERGROUND ECONOMY, INFLUENCES ON NATIONAL ECONOMIES

    Directory of Open Access Journals (Sweden)

    CEAUȘESCU IONUT

    2015-04-01

    Full Text Available The purpose of research is to improve the understanding of nature underground economy by rational justification of the right to be enshrined a reality that, at least statistically, can no longer be neglected. So, we propose to find the answer to the question: has underground economy to stand-alone?

  20. Dynamic Underground Stripping Project

    International Nuclear Information System (INIS)

    Aines, R.; Newmark, R.; McConachie, W.; Udell, K.; Rice, D.; Ramirez, A.; Siegel, W.; Buettner, M.; Daily, W.; Krauter, P.; Folsom, E.; Boegel, A.J.; Bishop, D.; Udell, K.

    1992-01-01

    LLNL is collaborating with the UC Berkeley College of Engineering to develop and demonstrate a system of thermal remediation and underground imaging techniques for use in rapid cleanup of localized underground spills. Called ''Dynamic Stripping'' to reflect the rapid and controllable nature of the process, it will combine steam injection, direct electrical heating, and tomographic geophysical imaging in a cleanup of the LLNL gasoline spill. In the first 8 months of the project, a Clean Site engineering test was conducted to prove the field application of the techniques before moving the contaminated site in FY 92

  1. Numerical modeling of underground storage system for natural gas

    Science.gov (United States)

    Ding, J.; Wang, S.

    2017-12-01

    Natural gas is an important type of base-load energy, and its supply needs to be adjusted according to different demands in different seasons. For example, since natural gas is increasingly used to replace coal for winter heating, the demand for natural gas in winter is much higher than that in other seasons. As storage systems are the essential tools for balancing seasonal supply and demand, the design and simulation of natural gas storage systems form an important research direction. In this study, a large-scale underground storage system for natural gas is simulated based on theoretical analysis and finite element modeling.It is proven that the problem of axi-symmetric Darcy porous flow of ideal gas is governed by the Boussinesq equation. In terms of the exact solution to the Boussinesq equation, the basic operating characteristics of the underground storage system is analyzed, and it is demonstrated that the propagation distance of the pore pressure is proportional to the 1/4 power of the mass flow rate and to the 1/2 power of the propagation time. This quantitative relationship can be used to guide the overall design of natural gas underground storage systems.In order to fully capture the two-way coupling between pore pressure and elastic matrix deformation, a poro-elastic finite element model for natural gas storage is developed. Based on the numerical model, the dynamic processes of gas injection, storage and extraction are simulated, and the corresponding time-dependent surface deformations are obtained. The modeling results not only provide a theoretical basis for real-time monitoring for the operating status of the underground storage system through surface deformation measurements, but also demonstrate that a year-round balance can be achieved through periodic gas injection and extraction.This work is supported by the CAS "100 talents" Program and the National Natural Science Foundation of China (41371090).

  2. The underground macroeconomics

    Directory of Open Access Journals (Sweden)

    Marin Dinu

    2013-01-01

    Full Text Available Like Physics, which cannot yet explain 96% of the substance in the Universe, so is Economics, unprepared to understand and to offer a rational explicative model to the underground economy.

  3. Mechanism of the reduction of hexavalent chromium by organo-montmorillonite supported iron nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Pingxiao, E-mail: pppxwu@scut.edu.cn [College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006 (China); Li, Shuzhen [School of Chemical and Environmental Engineering, Wuyi University, Jiangmen, Guangdong Province 529020 (China); Ju, Liting [College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006 (China); Zhu, Nengwu [College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006 (China); The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006 (China); The Key Laboratory of Environmental Protection and Eco-Remediation of Guangdong Regular Higher Education Institutions (China); Wu, Jinhua; Li, Ping [College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006 (China); Dang, Zhi [College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006 (China); The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006 (China); The Key Laboratory of Environmental Protection and Eco-Remediation of Guangdong Regular Higher Education Institutions (China)

    2012-06-15

    Highlights: Black-Right-Pointing-Pointer Organo-montmorillonite supported iron nanoparticles were found to be more efficient in the removal of Cr(VI) than unsupported iron nanoparticles. Black-Right-Pointing-Pointer The iron nanoparticles were accommodated by the sectional structure of the clay minerals which were helpful to protect the nanoparticles from aggregating. Black-Right-Pointing-Pointer XPS and XANES provided some direct information about the reduction mechanisms. Black-Right-Pointing-Pointer The structure of the supported iron nanoparticles was stable in the reaction with Cr(VI). - Abstract: Iron nanoparticles exhibit greater reactivity than micro-sized Fe{sup 0}, and they impart advantages for groundwater remediation. In this paper, supported iron nanoparticles were synthesized to further enhance the speed and efficiency of remediation. Natural montmorillonite and organo-montmorillonite were chosen as supporting materials. The capacity of supported iron nanoparticles was evaluated, compared to unsupported iron nanoparticles, for the reduction of aqueous Cr(VI). The reduction of Cr(VI) was much greater with organo-montmorillonite supported iron nanoparticles and fitted the pseudo-second order equation better. With a dose at 0.47 g/L, a total removal capacity of 106 mg Cr/g Fe{sup 0} was obtained. Other factors that affect the efficiency of Cr(VI) removal, such as pH values, the initial Cr(VI) concentration and storage time of nanoparticles were investigated. X-ray photoelectron spectrometry (XPS) and X-ray absorption near edge structure (XANES) were used to figure out the mechanism of the removal of Cr(VI). XPS indicated that the Cr(VI) bound to the particle surface was completely reduced to Cr(III) under a range of conditions. XANES confirmed that the Cr(VI) reacted with iron nanoparticles was completely reduced to Cr(III).

  4. Reactivity of nitrido complexes of ruthenium(VI), osmium(VI), and manganese(V) bearing Schiff base and simple anionic ligands.

    Science.gov (United States)

    Man, Wai-Lun; Lam, William W Y; Lau, Tai-Chu

    2014-02-18

    Nitrido complexes (M≡N) may be key intermediates in chemical and biological nitrogen fixation and serve as useful reagents for nitrogenation of organic compounds. Osmium(VI) nitrido complexes bearing 2,2':6',2″-terpyridine (terpy), 2,2'-bipyridine (bpy), or hydrotris(1-pyrazolyl)borate anion (Tp) ligands are highly electrophilic: they can react with a variety of nucleophiles to generate novel osmium(IV)/(V) complexes. This Account describes our recent results studying the reactivity of nitridocomplexes of ruthenium(VI), osmium(VI), and manganese(V) that bear Schiff bases and other simple anionic ligands. We demonstrate that these nitrido complexes exhibit rich chemical reactivity. They react with various nucleophiles, activate C-H bonds, undergo N···N coupling, catalyze the oxidation of organic compounds, and show anticancer activities. Ruthenium(VI) nitrido complexes bearing Schiff base ligands, such as [Ru(VI)(N)(salchda)(CH3OH)](+) (salchda = N,N'-bis(salicylidene)o-cyclohexyldiamine dianion), are highly electrophilic. This complex reacts readily at ambient conditions with a variety of nucleophiles at rates that are much faster than similar reactions using Os(VI)≡N. This complex also carries out unique reactions, including the direct aziridination of alkenes, C-H bond activation of alkanes and C-N bond cleavage of anilines. The addition of ligands such as pyridine can enhance the reactivity of [Ru(VI)(N)(salchda)(CH3OH)](+). Therefore researchers can tune the reactivity of Ru≡N by adding a ligand L trans to nitride: L-Ru≡N. Moreover, the addition of various nucleophiles (Nu) to Ru(VI)≡N initially generate the ruthenium(IV) imido species Ru(IV)-N(Nu), a new class of hydrogen-atom transfer (HAT) reagents. Nucleophiles also readily add to coordinated Schiff base ligands in Os(VI)≡N and Ru(VI)≡N complexes. These additions are often stereospecific, suggesting that the nitrido ligand has a directing effect on the incoming nucleophile. M≡N is also

  5. 78 FR 73471 - Refuge Alternatives for Underground Coal Mines

    Science.gov (United States)

    2013-12-06

    ... Refuge Alternatives for Underground Coal Mines AGENCY: Mine Safety and Health Administration, Labor... Agency's Request for Information (RFI) on Refuge Alternatives for Underground Coal Mines. This extension...), MSHA published a Request for Information on Refuge Alternatives for Underground Coal Mines. The RFI...

  6. Are underground coal miners satisfied with their work boots?

    Science.gov (United States)

    Dobson, Jessica A; Riddiford-Harland, Diane L; Bell, Alison F; Steele, Julie R

    2018-01-01

    Dissatisfaction with work boot design is common in the mining industry. Many underground coal miners believe their work boots contribute to the high incidence of lower limb injuries they experience. Despite this, the most recent research to examine underground coal mining work boot satisfaction was conducted over a decade ago. This present study aimed to address this gap in the literature by assessing current mining work boot satisfaction in relation to the work-related requirements for underground coal mining. 358 underground coal miners (355 men; mean age = 39.1 ± 10.7 years) completed a 54-question survey regarding their job details, work footwear habits, foot problems, lower limb and lower back pain history, and work footwear fit and comfort. Results revealed that underground coal miners were not satisfied with their current mining work boots. This was evident in the high incidence of reported foot problems (55.3%), lower back pain (44.5%), knee pain (21.5%), ankle pain (24.9%) and foot pain (42.3%). Over half of the underground coal miners surveyed believed their work boots contributed to their lower limb pain and reported their work boots were uncomfortable. Different working roles and environments resulted in differences in the incidence of foot problems, lower limb pain and comfort scores, confirming that one boot design cannot meet all the work-related requirements of underground coal mining. Further research examining the interaction of a variety of boot designs across the different underground surfaces and the different tasks miners perform is paramount to identify key boot design features that affect the way underground coal miners perform. Enhanced work boot design could improve worker comfort and productivity by reducing the high rates of reported foot problems and pain amongst underground coal miners. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Closures for underground nuclear power plants

    International Nuclear Information System (INIS)

    1981-10-01

    This study demonstrates that, with the appropriate selection of an access concept on the underground nuclear power plant, it is possible to design a gate complying with the increased requirements of the construction of an underground nuclear power plant. The investigations revealed that a comparison leakage of 42 mm in diameter for the failure of seals is too conservative. When selecting suitable seals a leakage being more extensive than the above mentioned one can be prevented even in case of disturbance lasting several months. The closure structures of the personnel and material accesses do not represent any weak point within the concept of the construction method for underground nuclear power plants. (orig./HP)

  8. A case of undeclared debt? Claude Lévi-Strauss' ambiguities and paradoxes toward analytical psychology.

    Science.gov (United States)

    Serina, Florent

    2018-06-09

    If his relationship to Sigmund Freud's psychoanalysis has been widely acknowledged, Claude Lévi-Strauss' rapport with C.G. Jung's analytical psychology remains quite obscure. While secondary commentary has been abundant, its approach has above all been intertextual, to the detriment of a rigorously historical reading. Even if certain arguments put forward by supporters of so-called "influence" deserve to be taken into account, especially because they highlight Lévi-Strauss ambiguities and paradoxes toward Jung, this paper provides proof that a precise reading of the texts, with the help of recent studies on the intellectual genesis of Lévi-Strauss, lead to reject the thesis of an unstated debt owed by the French anthropologist to the Zurich psychologist. © 2018 Wiley Periodicals, Inc.

  9. Low energy neutron background in deep underground laboratories

    Energy Technology Data Exchange (ETDEWEB)

    Best, Andreas, E-mail: andreas.best@lngs.infn.it [INFN, Laboratori Nazionali del Gran Sasso (LNGS), 67100 Assergi (Italy); Department of Physics and The Joint Institute for Nuclear Astrophysics, University of Notre Dame, Notre Dame, IN 46556 (United States); Görres, Joachim [Department of Physics and The Joint Institute for Nuclear Astrophysics, University of Notre Dame, Notre Dame, IN 46556 (United States); Junker, Matthias [INFN, Laboratori Nazionali del Gran Sasso (LNGS), 67100 Assergi (Italy); Kratz, Karl-Ludwig [Department for Biogeochemistry, Max-Planck-Institute for Chemistry, 55020 Mainz (Germany); Laubenstein, Matthias [INFN, Laboratori Nazionali del Gran Sasso (LNGS), 67100 Assergi (Italy); Long, Alexander [Department of Physics and The Joint Institute for Nuclear Astrophysics, University of Notre Dame, Notre Dame, IN 46556 (United States); Nisi, Stefano [INFN, Laboratori Nazionali del Gran Sasso (LNGS), 67100 Assergi (Italy); Smith, Karl; Wiescher, Michael [Department of Physics and The Joint Institute for Nuclear Astrophysics, University of Notre Dame, Notre Dame, IN 46556 (United States)

    2016-03-11

    The natural neutron background influences the maximum achievable sensitivity in most deep underground nuclear, astroparticle and double-beta decay physics experiments. Reliable neutron flux numbers are an important ingredient in the design of the shielding of new large-scale experiments as well as in the analysis of experimental data. Using a portable setup of {sup 3}He counters we measured the thermal neutron flux at the Kimballton Underground Research Facility, the Soudan Underground Laboratory, on the 4100 ft and the 4850 ft levels of the Sanford Underground Research Facility, at the Waste Isolation Pilot Plant and at the Gran Sasso National Laboratory. Absolute neutron fluxes at these laboratories are presented.

  10. Mechanisms of chromium (VI)-induced apoptosis in anterior pituitary cells.

    Science.gov (United States)

    Quinteros, Fernanda A; Machiavelli, Leticia I; Miler, Eliana A; Cabilla, Jimena P; Duvilanski, Beatriz H

    2008-07-30

    Hexavalent chromium (Cr (VI)) is a highly toxic metal. Exposure to Cr (VI) compounds may affect reproductive functions. Due to the importance of anterior pituitary hormones on reproductive physiology we have studied the effects of Cr (VI) on anterior pituitary. We previously demonstrated that, after in vivo Cr (VI) administration, Cr accumulates in the pituitary gland and affects prolactin secretion. In vitro, Cr (VI) causes apoptosis in anterior pituitary cells due to oxidative stress generation. To better understand the mechanisms involved in Cr (VI)-induced apoptosis we studied: (a) whether Cr (VI) affects the intracellular antioxidant response and (b) which of the apoptotic factors participates in Cr (VI) effect. Our results show that Cr (VI) treatment induces a decrease in catalase and glutathione peroxidase (GPx) activity but does not modify glutathione reductase (GR) activity. Cr (VI) exposure causes an increase of GSH levels. p53 and Bax mRNA are also upregulated by the metal. Pifithrin alpha, a p53 transcriptional inhibitor, increases Cr (VI) cytotoxicity, suggesting a role of p53 as a survival molecule. The antioxidant N-acetyl-cysteine (NAC) could prevent Bax mRNA increase and caspase 3 activation, confirming that Cr (VI)-induced apoptosis involves oxidative stress generation.

  11. Underground treatment of combustible minerals

    Energy Technology Data Exchange (ETDEWEB)

    Sarapuu, E

    1954-10-14

    A process is described for treating oil underground, consisting in introducing several electrodes spaced one from the other in a bed of combustibles underground so that they come in electric contact with this bed of combustibles remaining insulated from the ground, and applying to the electrodes a voltage sufficient to produce an electric current across the bed of combustibles, so as to heat it and create an electric connection between the electrodes on traversing the bed of combustibles.

  12. 30 CFR 75.811 - High-voltage underground equipment; grounding.

    Science.gov (United States)

    2010-07-01

    ...-voltage equipment supplying power to such equipment receiving power from resistance grounded systems shall... 30 Mineral Resources 1 2010-07-01 2010-07-01 false High-voltage underground equipment; grounding... COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Underground High-Voltage...

  13. 78 FR 58264 - Refuge Alternatives for Underground Coal Mines

    Science.gov (United States)

    2013-09-23

    ... Refuge Alternatives for Underground Coal Mines AGENCY: Mine Safety and Health Administration, Labor... Agency's Request for Information (RFI) on Refuge Alternatives for Underground Coal Mines. This extension... Alternatives for Underground Coal Mines. The RFI comment period had been scheduled to close on October 7, 2013...

  14. A Global Survey and Interactive Map Suite of Deep Underground Facilities; Examples of Geotechnical and Engineering Capabilities, Achievements, Challenges: (Mines, Shafts, Tunnels, Boreholes, Sites and Underground Facilities for Nuclear Waste and Physics R&D)

    Science.gov (United States)

    Tynan, M. C.; Russell, G. P.; Perry, F.; Kelley, R.; Champenois, S. T.

    2017-12-01

    This global survey presents a synthesis of some notable geotechnical and engineering information reflected in four interactive layer maps for selected: 1) deep mines and shafts; 2) existing, considered or planned radioactive waste management deep underground studies, sites, or disposal facilities; 3) deep large diameter boreholes, and 4) physics underground laboratories and facilities from around the world. These data are intended to facilitate user access to basic information and references regarding deep underground "facilities", history, activities, and plans. In general, the interactive maps and database [http://gis.inl.gov/globalsites/] provide each facility's approximate site location, geology, and engineered features (e.g.: access, geometry, depth, diameter, year of operations, groundwater, lithology, host unit name and age, basin; operator, management organization, geographic data, nearby cultural features, other). Although the survey is not all encompassing, it is a comprehensive review of many of the significant existing and historical underground facilities discussed in the literature addressing radioactive waste management and deep mined geologic disposal safety systems. The global survey is intended to support and to inform: 1) interested parties and decision makers; 2) radioactive waste disposal and siting option evaluations, and 3) safety case development as a communication tool applicable to any mined geologic disposal facility as a demonstration of historical and current engineering and geotechnical capabilities available for use in deep underground facility siting, planning, construction, operations and monitoring.

  15. Surface modification to improve the sorption property of U(VI) on mesoporous silica

    International Nuclear Information System (INIS)

    Lijuan Song; Yulong Wang; Lu Zhu; Bolong Guo; Suwen Chen; Wangsuo Wu

    2014-01-01

    Polyoxometalates K 7 [α-PW 11 O 39 ]·14H 2 O (PW11) modified mesoporous silica (MCM-48) with cubic structure, was prepared by impregnation and calcination methods. The modified mesoporous silica sorbent (PW11/MCM-48) was studied as a potential adsorbent for U(VI) from aqueous solutions. MCM-48 and PW11/MCM-48 were confirmed by X-ray diffraction and nitrogen physisorption techniques. The results indicate the original keggin structure of PW11 and mesoporous structure of MCM-48 are maintained after supporting PW11 on mesoporous silica MCM-48. The effects of contact time, solid-to-liquid ratio (m/V), solution pH and ionic strength on U(VI) sorption behaviors of the pure and modified mesoporous silicas were also studied. Typical sorption isotherms such as Langmuir and Freundlich isotherms were determined for sorption process. The results suggest that the sorption of U(VI) on MCM-48 or PW11/MCM-48 are strongly dependent on pH values but independent of ionic strength. The sorption capacity of PW11/MCM-48 for U(VI) is about ten times more than that of MCM-48. (author)

  16. Emissions of chromium (VI) from arc welding.

    Science.gov (United States)

    Heung, William; Yun, Myoung-Jin; Chang, Daniel P Y; Green, Peter G; Halm, Chris

    2007-02-01

    The presence of Cr in the +6 oxidation state (Cr[VI]) is still observed in ambient air samples in California despite steps taken to reduce emissions from plating operations. One known source of emission of Cr(VI) is welding, especially with high Cr-content materials, such as stainless steels. An experimental effort was undertaken to expand and update Cr(VI) emission factors by conducting tests on four types of arc-welding operations: gas-metal arc welding (GMAW), shielded metal arc welding (SMAW), fluxcore arc welding, and pulsed GMAW. Standard American Welding Society hood results were compared with a total enclosure method that permitted isokinetic sampling for particle size-cut measurement, as well as total collection of the aerosol. The fraction of Cr(VI) emitted per unit mass of Cr electrode consumed was determined. Consistent with AP-42 data, initial results indicate that a significant fraction of the total Cr in the aerosol is in the +6 oxidation state. The fraction of Cr(VI) and total aerosol mass produced by the different arc welding methods varies with the type of welding process used. Self-shielded electrodes that do not use a shield gas, for example, SMAW, produce greater amounts of Cr(VI) per unit mass of electrode consumed. The formation of Cr(VI) from standard electrode wires used for welding mild steel was below the method detection limit after eliminating an artifact in the analytical method used.

  17. High Temperature Superconducting Underground Cable

    International Nuclear Information System (INIS)

    Farrell, Roger A.

    2010-01-01

    The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the worlds first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

  18. An integrated environment monitoring system for underground coal mines--Wireless Sensor Network subsystem with multi-parameter monitoring.

    Science.gov (United States)

    Zhang, Yu; Yang, Wei; Han, Dongsheng; Kim, Young-Il

    2014-07-21

    Environment monitoring is important for the safety of underground coal mine production, and it is also an important application of Wireless Sensor Networks (WSNs). We put forward an integrated environment monitoring system for underground coal mine, which uses the existing Cable Monitoring System (CMS) as the main body and the WSN with multi-parameter monitoring as the supplementary technique. As CMS techniques are mature, this paper mainly focuses on the WSN and the interconnection between the WSN and the CMS. In order to implement the WSN for underground coal mines, two work modes are designed: periodic inspection and interrupt service; the relevant supporting technologies, such as routing mechanism, collision avoidance, data aggregation, interconnection with the CMS, etc., are proposed and analyzed. As WSN nodes are limited in energy supply, calculation and processing power, an integrated network management scheme is designed in four aspects, i.e., topology management, location management, energy management and fault management. Experiments were carried out both in a laboratory and in a real underground coal mine. The test results indicate that the proposed integrated environment monitoring system for underground coal mines is feasible and all designs performed well as expected.

  19. An Integrated Environment Monitoring System for Underground Coal Mines—Wireless Sensor Network Subsystem with Multi-Parameter Monitoring

    Science.gov (United States)

    Zhang, Yu; Yang, Wei; Han, Dongsheng; Kim, Young-Il

    2014-01-01

    Environment monitoring is important for the safety of underground coal mine production, and it is also an important application of Wireless Sensor Networks (WSNs). We put forward an integrated environment monitoring system for underground coal mine, which uses the existing Cable Monitoring System (CMS) as the main body and the WSN with multi-parameter monitoring as the supplementary technique. As CMS techniques are mature, this paper mainly focuses on the WSN and the interconnection between the WSN and the CMS. In order to implement the WSN for underground coal mines, two work modes are designed: periodic inspection and interrupt service; the relevant supporting technologies, such as routing mechanism, collision avoidance, data aggregation, interconnection with the CMS, etc., are proposed and analyzed. As WSN nodes are limited in energy supply, calculation and processing power, an integrated network management scheme is designed in four aspects, i.e., topology management, location management, energy management and fault management. Experiments were carried out both in a laboratory and in a real underground coal mine. The test results indicate that the proposed integrated environment monitoring system for underground coal mines is feasible and all designs performed well as expected. PMID:25051037

  20. An Integrated Environment Monitoring System for Underground Coal Mines—Wireless Sensor Network Subsystem with Multi-Parameter Monitoring

    Directory of Open Access Journals (Sweden)

    Yu Zhang

    2014-07-01

    Full Text Available Environment monitoring is important for the safety of underground coal mine production, and it is also an important application of Wireless Sensor Networks (WSNs. We put forward an integrated environment monitoring system for underground coal mine, which uses the existing Cable Monitoring System (CMS as the main body and the WSN with multi-parameter monitoring as the supplementary technique. As CMS techniques are mature, this paper mainly focuses on the WSN and the interconnection between the WSN and the CMS. In order to implement the WSN for underground coal mines, two work modes are designed: periodic inspection and interrupt service; the relevant supporting technologies, such as routing mechanism, collision avoidance, data aggregation, interconnection with the CMS, etc., are proposed and analyzed. As WSN nodes are limited in energy supply, calculation and processing power, an integrated network management scheme is designed in four aspects, i.e., topology management, location management, energy management and fault management. Experiments were carried out both in a laboratory and in a real underground coal mine. The test results indicate that the proposed integrated environment monitoring system for underground coal mines is feasible and all designs performed well as expected.

  1. Horonobe Underground Research Laboratory project. Investigation program for the 2008 fiscal year

    International Nuclear Information System (INIS)

    Nakayama, Masashi; Sanada, Hiroyuki; Yamaguchi, Takehiro; Sugita, Yutaka

    2008-09-01

    As part of the research and development program on geological disposal of high-level radioactive waste (HLW), the Horonobe Underground Research Center, a division of the Japan Atomic Energy Agency (JAEA), is implementing the Horonobe Underground Research Laboratory Project (Horonobe URL Project) with the aim at investigating sedimentary rock formations. According to the research plan described in the Midterm Plan of JAEA, geological investigations are to be carried out during the drilling of a shaft down to intermediate depth, while research and development in the areas of engineering technology and safety assessment are to be promoted by collaboration with other research organizations. The results of the R and D activities will be systematized as a 'knowledge base' that supports a wide range of arguments related to the safety of geological disposal. The Horonobe URL Project is planned to extend over a period of 20 years. The investigations will be conducted in three phases, namely 'Phase 1: Surface-based investigations', 'Phase 2: Construction phase' (investigations during construction of the underground facilities) and 'Phase 3: Operation phase' (research in the underground facilities). This report summarizes the investigation program for the 2008 fiscal year (2008/2009), the 4th year of the Phase 2 investigations. In the 2008 fiscal year, investigations in geoscientific research', including 'development of techniques for investigating the geological environment', 'development of techniques for long-term monitoring of the geological environment', 'development of engineering techniques for use in the deep underground environment' and studies on the long-term stability of the geological environment', are continuously carried out. Investigations in 'research and development on geological disposal technology', including 'improving the reliability of disposal technologies' and 'enhancement of safety assessment methodologies', are also continuously carried out

  2. 30 CFR 57.4263 - Underground belt conveyors.

    Science.gov (United States)

    2010-07-01

    ....4263 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and Control Firefighting Equipment § 57.4263 Underground belt conveyors. Fire protection shall be...

  3. Polarographic behaviour and determination of uranium(VI) in alcoholic solutions from organic extraction phases

    International Nuclear Information System (INIS)

    Degueldre, C.; Taibi, K.

    1996-01-01

    The determination of U(VI) in organic extraction phases: hydrocarbon-diethyl-2-hexyl phosphoric acid-trioctylphosphine oxide and hydrocarbon-tri-n-octylamine, diluted by an alcohol has been studied by direct current polarography, as well as by differential pulse polarography (DPP). In order to optimise the analytical procedure, miscibility and conductivity studies of the mixtures hydrocarbon-alcohol (ethanol, n- and isopropanol and n- and isobutanol) were made after addition of sulphuric acid as a supporting electrolyte. In the solutions of sulphuric acid in the alcohol-extractant-hydrocarbon phases, U(VI) gives rise to well defined polarograms. Its electroreduction involves a single electron step in all cases. The DPP peak height is proportional to the U(VI) concentration between 2x10 -6 and 2x10 -3 M, and the 3σ detection limit is ca. 10 -6 M

  4. 78 FR 48591 - Refuge Alternatives for Underground Coal Mines

    Science.gov (United States)

    2013-08-08

    ... Administration 30 CFR Parts 7 and 75 Refuge Alternatives for Underground Coal Mines; Proposed Rules #0;#0;Federal... Underground Coal Mines AGENCY: Mine Safety and Health Administration, Labor. ACTION: Limited reopening of the... for miners to deploy and use refuge alternatives in underground coal mines. The U.S. Court of Appeals...

  5. The stress and underground environment

    Science.gov (United States)

    Chama, A.

    2009-04-01

    Currently,the program of prevention in occupational health needs mainly to identify occupational hazards and strategy of their prevention.Among these risks,the stress represents an important psycho-social hazard in mental health,which unfortunately does not spare no occupation.My Paper attempts to highlight and to develop this hazard in its different aspects even its regulatory side in underground environment as occupational environment.In the interest of better prevention ,we consider "the information" about the impact of stress as the second prevention efficient and no expensive to speleologists,hygienists and workers in the underground areas. In this occasion of this event in Vienna,we also highlight the scientific works on the stress of the famous viennese physician and endocrinologist Doctor Hans Selye (1907-1982),nicknamed "the father of stress" and note on relation between biological rhythms in this underground area and psychological troubles (temporal isolation) (Jurgen Aschoff’s works and experiences out-of time).

  6. Vi-da: vitiligo diagnostic assistance mobile application

    Science.gov (United States)

    Nugraha, G. A.; Nurhudatiana, A.; Bahana, R.

    2018-03-01

    Vitiligo is a skin disorder in which white patches of depigmentation appear on different parts of the body. Usually, patients come to hospitals or clinics to have their vitiligo conditions assessed. This can be very tiring to the patients, as vitiligo treatments usually take a relatively long period of time, which can range from months to years. To address this challenge, we present in this paper a prototype of an Android-based mobile application called Vi-DA, which stands for Vitiligo Diagnostic Assistance. Vi-DA consists of three subsystems, which are user sign-up subsystem, camera and image analysis subsystem, and progress report subsystem. The mobile application was developed in Java programming language and uses MySQL as the database system. Vi-DA adopts a vitiligo segmentation algorithm to segment input image into normal skin area, vitiligo skin area, and non-skin area. Results showed that Vi-DA gave comparable results to the previous system implemented in Matlab. User acceptance testing results also showed that all respondents agreed on the usefulness of the system and agreed to use Vi-DA again in the future. Vi-DA benefits both dermatologists and patients as not only a computer-aided diagnosis (CAD) tool but also as a smart application that can be used for self-assessment at home.

  7. Occurrence of radon in the Polish underground tourist routes

    Directory of Open Access Journals (Sweden)

    Jerzy Olszewski

    2015-08-01

    Full Text Available Background: There are about 200 underground tourist routes in Poland. There are caves, mines or underground structures. This paper presents the results of the research intended to identify the extent of the occurrence of radon concentrations in underground areas of tourist routes. Material and Methods: We conducted the measurement of periodic concentrations of radon (1–2 months in the summer using type Tastrak trace detectors. We determined the average concentrations of radon in air in 66 underground tourist routes in Poland. Results: The research results comprise 259 determinations of average radon concentrations in 66 routes. The arithmetic average of the results was 1610 Bqm–3, and the maximum measured concentration was over 20 000 Bqm–3. The minimum concentration was 100 Bqm–3 (threshold method considering the arithmetic average of the measurements. It was found that in 67% of the routes, the average concentration of radon has exceeded 300 Bqm–3 and in 22 underground routes it exceeded 1000 Bqm–3. Conclusions: Radon which occurs in many Polish underground tourist routes may be an organizational, legal and health problem. It is necessary to develop a program of measures to reduce radon concentrations in underground routes, especially routes located in the former mines. Med Pr 2015;66(4:557–563

  8. The arrangement of the seismic design method of the underground facility

    International Nuclear Information System (INIS)

    Tanai, Kenji; Horita, Masakuni; Dewa, Katsuyuki; Gouke, Mitsuo

    2002-03-01

    Earthquake resistance for the underground structure is higher than the ground structure. Therefore, the case of examining the earthquake resistance of underground structure was little. However, it carries out the research on the aseismic designing method of underground structure, since the tunnel was struck by Hyogo-ken Nanbu Earthquake, and it has obtained a much knowledge. However, an object of the most study was behavior at earthquake of the comparatively shallow underground structure in the alluvial plain board, and it not carry out the examination on behavior at earthquake of underground structure in the deep rock mass. In the meantime, underground disposal facility of the high level radioactive waste constructs in the deep underground, and it carries out the operation in these tunnels. In addition, it has made almost the general process of including from the construction start to the backfilling to be about 60 years (Japan Nuclear Fuel Cycle Development Institute, 1999). During these periods, it is necessary to also consider the earthquake resistance as underground structure from the viewpoint of the safety of facilities. Then, it extracted future problem as one of the improvement of the basis information for the decision of the safety standard and guideline of the country on earthquake-resistant design of the underground disposal facility, while it carried out investigation and arrangement of earthquake-resistant design cases, guidelines and analysis method on existing underground structure, etc. And, the research items for the earthquake resistance assessment of underground structure as case study of the underground research laboratory. (author)

  9. Comparative study of uranyl(VI) and -(V) carbonato complexes in an aqueous solution.

    Science.gov (United States)

    Ikeda, Atsushi; Hennig, Christoph; Tsushima, Satoru; Takao, Koichiro; Ikeda, Yasuhisa; Scheinost, Andreas C; Bernhard, Gert

    2007-05-14

    Electrochemical, complexation, and electronic properties of uranyl(VI) and -(V) carbonato complexes in an aqueous Na2CO3 solution have been investigated to define the appropriate conditions for preparing pure uranyl(V) samples and to understand the difference in coordination character between UO22+ and UO2+. Cyclic voltammetry using three different working electrodes of platinum, gold, and glassy carbon has suggested that the electrochemical reaction of uranyl(VI) carbonate species proceeds quasi-reversibly. Electrolysis of UO22+ has been performed in Na2CO3 solutions of more than 0.8 M with a limited pH range of 11.7 < pH < 12.0 using a platinum mesh electrode. It produces a high purity of the uranyl(V) carbonate solution, which has been confirmed to be stable for at least 2 weeks in a sealed glass cuvette. Extended X-ray absorption fine structure (EXAFS) measurements revealed the structural arrangement of uranyl(VI) and -(V) tricarbonato complexes, [UO2(CO3)3]n- [n = 4 for uranyl(VI), 5 for uranyl(V)]. The bond distances of U-Oax, U-Oeq, U-C, and U-Odist are determined to be 1.81, 2.44, 2.92, and 4.17 A for the uranyl(VI) complex and 1.91, 2.50, 2.93, and 4.23 A for the uranyl(V) complex, respectively. The validity of the structural parameters obtained from EXAFS has been supported by quantum chemical calculations for the uranyl(VI) complex. The uranium LI- and LIII-edge X-ray absorption near-edge structure spectra have been interpreted in terms of electron transitions and multiple-scattering features.

  10. Underground siting of nuclear power plants

    International Nuclear Information System (INIS)

    Bender, F.

    1982-01-01

    The symposium gave the opportunity for an international exchange of views on the concepts of underground nuclear power plants, which are presently world wide under consideration. The results of investigations into the advantages and disadvantages with regard to the technical safety aspects of the underground plants in comparison to plants on the surface led to open and sometimes controversal discussions. As a result of the symposium (32 contributions) a general agreement can be stated on the judgement concerning the advantages and the disadvantages of underground nuclear power plants (nnp). The advantages are: increased protection against external events; delayed release of fission products in accident situations, if the closures operate properly. The disadvantages are: increased costs of the construction of underground and restrictions to such sites where either large caverns or deep pits can be constructed, which also requires that certain technical problems must be solved beforehand. Also, additional safety certificates related to the site will be required within the licensing procedures. The importance of these advantages and disadvantages was in some cases assessed very differently. The discussions also showed, that there are a number of topics where some questions have not been finally answered yet. (orig./HP) [de

  11. Comparison of U(VI) adsorption onto nanoscale zero-valent iron and red soil in the presence of U(VI)–CO{sub 3}/Ca–U(VI)–CO{sub 3} complexes

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Zhibin [Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Nanchang 330013 (China); State Key Laboratory Breeding Base of Nuclear Resources and Environment (East China Institute of Technology), Ministry of Education, Nanchang 330013 (China); Chemistry, Biological and Materials Sciences Department, East China Institute of Technology, Nanchang 330013 (China); Liu, Jun [State Key Laboratory Breeding Base of Nuclear Resources and Environment (East China Institute of Technology), Ministry of Education, Nanchang 330013 (China); Cao, Xiaohong, E-mail: xhcao@ecit.cn [Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Nanchang 330013 (China); State Key Laboratory Breeding Base of Nuclear Resources and Environment (East China Institute of Technology), Ministry of Education, Nanchang 330013 (China); Chemistry, Biological and Materials Sciences Department, East China Institute of Technology, Nanchang 330013 (China); Luo, Xuanping [Chemistry, Biological and Materials Sciences Department, East China Institute of Technology, Nanchang 330013 (China); Hua, Rong; Liu, Yan [Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Nanchang 330013 (China); State Key Laboratory Breeding Base of Nuclear Resources and Environment (East China Institute of Technology), Ministry of Education, Nanchang 330013 (China); Chemistry, Biological and Materials Sciences Department, East China Institute of Technology, Nanchang 330013 (China); Yu, Xiaofeng; He, Likai [Chemistry, Biological and Materials Sciences Department, East China Institute of Technology, Nanchang 330013 (China); and others

    2015-12-30

    Highlights: • NZVI can be used for adsorbing U(VI)–CO{sub 3} complexes. • Use of NZVI is feasible for remediation of uranium-contaminated soils. • The mechanism of U(VI)–CO{sub 3} complexes adsorbing onto NZVI has been explained. - Abstract: The influence of U(VI)–CO{sub 3} and Ca–U(VI)–CO{sub 3} complexes on U(VI) adsorption onto red soil and nanoscale zero-valent iron (NZVI) was investigated using batch adsorption and fixed-bed column experiments to simulate the feasibility of NZVI as the reactive medium in permeable- reactive barriers (PRB) for in situ remediation of uranium-contaminated red soils. The adsorption capacity (q{sub e}) and distribution constant (K{sub d}) of NZVI and red soil decreased with increasing pH, dissolved carbonate and calcium concentrations, but the q{sub e} and K{sub d} values of NZVI were 5–10 times higher than those of red soil. The breakthrough pore volume (PV) values increased with the decrease of pH, dissolved carbonate and calcium concentration; however, the breakthrough PV values of the PRB column filled with 5% NZVI were 2.0–3.5 times higher than the 100% red soil column. The U(VI)–CO{sub 3} complexes adsorbed onto the surface of red soil/NZVI (≡SOH) to form SO–UO{sub 2}CO{sub 3}{sup −} or SO–UO{sub 2} (CO{sub 3}){sub 2}{sup 3−}. XPS and XRD analysis further confirmed the reduction of U(VI) to U(IV) and the formation of FeOOH on NZVI surfaces. The findings of this study are significant to the remediation of uranium-contaminated red soils and the consideration of practical U(VI) species in the natural environment.

  12. Study of new U(VI) and Pu(VI) coprecipitation methods for the preparation of (U,Pu)O2

    International Nuclear Information System (INIS)

    Sanoit, J. de.

    1990-01-01

    Two U(VI) and Pu(VI) coprecipitation methods have been studied, for the definition of new processes to prepare (U,Pu)O 2 mixed oxides suitable for making MoX fuels or fast breeder reactor fuels. The first system is based on the coprecipitation of a new U(VI), Pu(VI) compound; ammonium uranoplutonate, where as a second system is related to the precipitation of uranyl plutonyl monocarbonate. Experimental conditions to optimize the precipitation and the filtration steps of these two systems have been determined. After calcination under reducing conditions, the mixed oxides obtained are characterized according to different techniques: granulometry, thermogravimetry, solubility in boiling HNO 3 solutions. The properties of such oxides are excellent. The possible processes for preparing (U, Pu)O 2 using these new routes are compared with those actually exploited [fr

  13. Cr(VI) removal from aqueous solution by dried activated sludge biomass

    International Nuclear Information System (INIS)

    Wu Jun; Zhang Hua; He Pinjing; Yao Qian; Shao Liming

    2010-01-01

    Batch experiments were conducted to remove Cr(VI) from aqueous solution using activated sludge biomass. The effects of acid pretreatment of the biomass, initial pH, biomass and Cr(VI) concentrations on Cr(VI) removal efficiency were investigated. Proton consumption during the removal process and the reducing capacity of sludge biomass were studied. The results show that acid pretreatment could significantly improve Cr(VI) removal efficiency and increase Cr(VI) reducing capacity by 20.4%. Cr(VI) removal was remarkably pH-dependent; lower pH (pH = 1, 2) facilitated Cr(VI) reduction while higher pH (pH = 3, 4) favored sorption of the converted Cr(III). Lower Cr(VI) concentration as well as higher biomass concentration could accelerate Cr(VI) removal. Cr(VI) reduction was not the only reason for proton consumption in the removal process. Pseudo-second-order adsorption kinetic model could successfully simulate Cr(VI) removal except under higher pH conditions (pH = 3, 4).

  14. Separation of valence forms of chromium(III) and chromium(VI) by coprecipitation with iron(III) hydroxide

    International Nuclear Information System (INIS)

    Nazirmadov, B.; Khamidov, B.O.; Egorova, L.A.

    1989-01-01

    The sorption of 9.62·10 -5 M of Cr (III) and Cr (VI) with iron hydroxide in 1 M potassium nitrate and potassium chloride was investigated in relation to the pH of the medium. Experimental data on the sorption of chromium(III) and chromium(VI) with iron(III) hydroxide made it possible to determine the region of practically complete concentration of Cr (III) and Cr (VI) (pH = 3-6.5). The results from spectrophotometric investigations, calculated data on the distribution of the hydroxocationic forms of chromium(III) and the anions of chromium(IV), and their sorption by iron-(III) hydroxide made it possible to characterize the sorbability of the cationic and anionic forms of chromium in various degrees of oxidation. On this basis a method was developed for the separation of chromium(III) and chromium(VI) by coprecipitation on iron(III) hydroxide and their separation from the iron(III) hydroxide support

  15. Behaviour of chromium(VI) in stormwater soil infiltration systems

    DEFF Research Database (Denmark)

    Cederkvist, Karin; Ingvertsen, Simon T.; Jensen, Marina B.

    2013-01-01

    mm in 2 h) and extreme (100 mm in 3 h) rain events. The objectives were to understand the behaviour of the anionic and toxic Cr(VI) in soil at neutral pH and to asses treatment efficiency towards Cr(VI). During normal rain events Cr(VI) was largely retained (more than 50, even though pH was neutral......The ability of stormwater infiltration systems to retain Cr(VI) was tested by applying a synthetic stormwater runoff solution with a neutral pH and high Cr(VI) concentrations to four intact soil columns excavated from two roadside infiltration swales in Germany. Inlet flow rates mimicked normal (10......, while under extreme rain events approximately 20% of Cr(VI) was retained. In both cases effluent concentrations of Cr(VI) would exceed the threshold value of 3.4 mu g/L if the infiltrated water were introduced to freshwater environments. More knowledge on the composition of the stormwater runoff...

  16. Industrial Internet of Things: (IIoT) applications in underground coal mines.

    Science.gov (United States)

    Zhou, C; Damiano, N; Whisner, B; Reyes, M

    2017-12-01

    The Industrial Internet of Things (IIoT), a concept that combines sensor networks and control systems, has been employed in several industries to improve productivity and safety. U.S. National Institute for Occupational Safety and Health (NIOSH) researchers are investigating IIoT applications to identify the challenges of and potential solutions for transferring IIoT from other industries to the mining industry. Specifically, NIOSH has reviewed existing sensors and communications network systems used in U.S. underground coal mines to determine whether they are capable of supporting IIoT systems. The results show that about 40 percent of the installed post-accident communication systems as of 2014 require minimal or no modification to support IIoT applications. NIOSH researchers also developed an IIoT monitoring and control prototype system using low-cost microcontroller Wi-Fi boards to detect a door opening on a refuge alternative, activate fans located inside the Pittsburgh Experimental Mine and actuate an alarm beacon on the surface. The results of this feasibility study can be used to explore IIoT applications in underground coal mines based on existing communication and tracking infrastructure.

  17. Underground muons from Cygnus X-3

    International Nuclear Information System (INIS)

    Price, L.E.

    1985-01-01

    Underground detectors, intended for searches for nucleon decay and other rare processes, have recently begun searching for evidence of astrophysical sources, particularly Cygnus X-3, in the cosmic ray muons they record. Some evidence for signals from Cygnus X-3 has been reported. The underground observations are reported here in the context of previous (surface) observations of the source at high energies. 25 refs., 8 figs

  18. Design, construction and initial state of the underground openings

    International Nuclear Information System (INIS)

    2010-12-01

    The report is included in a set of Production reports, presenting how the KBS-3 repository is designed, produced and inspected. The set of reports is included in the safety report for the KBS-3 repository and repository facility. The report provides input on the initial state of the underground openings for the assessment of the long-term safety, SR-Site. The initial state refers to the properties of the underground openings at final disposal, backfilling or closure. In addition, the report provides input to the operational safety report, SR-Operation, on how the underground openings shall be constructed and inspected. The report presents the design premises and the methodology applied to design the underground openings and adapt them the to the site conditions so that they conform to the design premises. It presents the reference design at Forsmark and its conformity to the design premises. It also describes the reference methods to be applied to construct and inspect the different kinds of underground openings. Finally, the initial state of the underground openings and its conformity to the design premises is presented

  19. Design, construction and initial state of the underground openings

    Energy Technology Data Exchange (ETDEWEB)

    2010-12-15

    The report is included in a set of Production reports, presenting how the KBS-3 repository is designed, produced and inspected. The set of reports is included in the safety report for the KBS-3 repository and repository facility. The report provides input on the initial state of the underground openings for the assessment of the long-term safety, SR-Site. The initial state refers to the properties of the underground openings at final disposal, backfilling or closure. In addition, the report provides input to the operational safety report, SR-Operation, on how the underground openings shall be constructed and inspected. The report presents the design premises and the methodology applied to design the underground openings and adapt them the to the site conditions so that they conform to the design premises. It presents the reference design at Forsmark and its conformity to the design premises. It also describes the reference methods to be applied to construct and inspect the different kinds of underground openings. Finally, the initial state of the underground openings and its conformity to the design premises is presented

  20. Isolation of a star-shaped uranium(V/VI) cluster from the anaerobic photochemical reduction of uranyl(VI)

    Energy Technology Data Exchange (ETDEWEB)

    Chatelain, Lucile; White, Sarah; Scopelliti, Rosario; Mazzanti, Marinella [Ecole Polytechnique Federale de Lausanne (EPFL) (Switzerland). Inst. de Sciences et Ingenierie Chimiques

    2016-11-07

    Actinide oxo clusters are an important class of compounds due to their impact on actinide migration in the environment. The photolytic reduction of uranyl(VI) has potential application in catalysis and spent nuclear fuel reprocessing, but the intermediate species involved in this reduction have not yet been elucidated. Here we show that the photolysis of partially hydrated uranyl(VI) in anaerobic conditions leads to the reduction of uranyl(VI), and to the incorporation of the resulting U{sup V} species into the stable mixed-valent star-shaped U{sup VI}/U{sup V} oxo cluster [U(UO{sub 2}){sub 5}(μ{sub 3}-O){sub 5}(PhCOO){sub 5}(Py){sub 7}]. This cluster is only the second example of a U{sup VI}/U{sup V} cluster and the first one associating uranyl groups to a non-uranyl(V) center. The U{sup V} center in 1 is stable, while the reaction of uranyl(V) iodide with potassium benzoate leads to immediate disproportionation and formation of the U{sub 12}{sup IV}U{sub 4}{sup V}O{sub 24} cluster {[K(Py)_2]_2[K(Py)]_2[U_1_6O_2_4(PhCOO)_2_4(Py)_2]}.

  1. Establishing sustainable strategies in urban underground engineering.

    Science.gov (United States)

    Curiel-Esparza, Jorge; Canto-Perello, Julian; Calvo, Maria A

    2004-07-01

    Growth of urban areas, the corresponding increased demand for utility services and the possibility of new types of utility systems are overcrowding near surface underground space with urban utilities. Available subsurface space will continue to diminish to the point where utilidors (utility tunnels) may become inevitable. Establishing future sustainable strategies in urban underground engineering consists of the ability to lessen the use of traditional trenching. There is an increasing interest in utility tunnels for urban areas as a sustainable technique to avoid congestion of the subsurface. One of the principal advantages of utility tunnels is the substantially lower environmental impact compared with common trenches. Implementing these underground facilities is retarded most by the initial cost and management procedures. The habitual procedure is to meet problems as they arise in current practice. The moral imperative of sustainable strategies fails to confront the economic and political conflicts of interest. Municipal engineers should act as a key enabler in urban underground sustainable development.

  2. Nitrate Enhanced Microbial Cr(VI) Reduction-Final Report

    Energy Technology Data Exchange (ETDEWEB)

    John F. Stolz

    2011-06-15

    A major challenge for the bioremediation of radionuclides (i.e., uranium, technetium) and metals (i.e., Cr(VI), Hg) is the co-occurrence of nitrate as it can inhibit metal transformation. Denitrification (nitrate reduction to dinitrogen gas) is considered the most important ecological process. For many metal and metalloid reducing bacteria, however, ammonia is the end product through respiratory nitrate reduction (RNRA). The focus of this work was to determine how RNRA impacts Cr(VI) transformation. The goal was to elucidate the specific mechanism(s) that limits Cr(VI) reduction in the presence of nitrate and to use this information to develop strategies that enhance Cr(VI) reduction (and thus detoxification). Our central hypothesis is that nitrate impacts the biotransformation of metals and metalloids in three ways 1) as a competitive alternative electron acceptor (inhibiting transformation), 2) as a co-metabolite (i.e., concomitant reduction, stimulating transformation), and 3) as an inducer of specific proteins and pathways involved in oxidation/reduction reactions (stimulating transformation). We have identified three model organisms, Geobacter metallireducens (mechanism 1), Sulfurospirillum barnesii, (mechasism 2), and Desulfovibrio desulfuricans (mechanisms 3). Our specific aims were to 1) investigate the role of Cr(VI) concentration on the kinetics of both growth and reduction of nitrate, nitrite, and Cr(VI) in these three organisms; 2) develop a profile of bacterial enzymes involved in nitrate transformation (e.g., oxidoreductases) using a proteomic approach; 3) investigate the function of periplasmic nitrite reductase (Nrf) as a chromate reductase; and 4) develop a strategy to maximize microbial chromium reduction in the presence of nitrate. We found that growth on nitrate by G. metallireducens was inhibited by Cr(VI). Over 240 proteins were identified by LC/MS-MS. Redox active proteins, outer membrane heavy metal efflux proteins, and chemotaxis sensory

  3. Master plan of Mizunami underground research laboratory

    International Nuclear Information System (INIS)

    1999-04-01

    In June 1994, the Atomic Energy Commission of Japan reformulated the Long-Term Programme for Research, Development and Utilisation of Nuclear Energy (LTP). The LTP (item 7, chapter 3) sets out the guidelines which apply to promoting scientific studies of the deep geological environment, with a view to providing a sound basis for research and development programmes for geological disposal projects. The Japan Nuclear Cycle Development Institute (JNC) has been conducting scientific studies of the deep geological environment as part of its Geoscientific Research Programme. The LTP also emphasised the importance of deep underground research facilities in the following terms: Deep underground research facilities play an important role in research relating to geological disposal. They allow the characteristics and features of the geological environment, which require to be considered in performance assessment of disposal systems, to be investigated in situ and the reliability of the models used for evaluating system performance to be developed and refined. They also provide opportunities for carrying out comprehensive research that will contribute to an improved overall understanding of Japan's deep geological environment. It is recommended that more than one facility should be constructed, considering the range of characteristics and features of Japan's geology and other relevant factors. It is important to plan underground research facilities on the basis of results obtained from research and development work already carried out, particularly the results of scientific studies of the deep geological environment. Such a plan for underground research facilities should be clearly separated from the development of an actual repository. JNC's Mizunami underground research laboratory (MIU) Project will be a deep underground research facility as foreseen by the above provisions of the LTP. (author)

  4. Underground neutrino astronomy

    International Nuclear Information System (INIS)

    Schramm, D.N.

    1983-02-01

    A review is made of possible astronomical neutrino sources detectable with underground facilities. Comments are made about solar neutrinos and gravitational-collapse neutrinos, and particular emphasis is placed on ultra-high-energy astronomical neutrino sources. An appendix mentions the exotic possibility of monopolonium

  5. Learning the vi and Vim Editor

    CERN Document Server

    Robbins, Arnold; Hannah, Elbert

    2008-01-01

    There's nothing that hard-core Unix and Linux users are more fanatical about than their text editor. Editors are the subject of adoration and worship, or of scorn and ridicule, depending upon whether the topic of discussion is your editor or someone else's. vi has been the standard editor for close to 30 years. Popular on Unix and Linux, it has a growing following on Windows systems, too. Most experienced system administrators cite vi as their tool of choice. And since 1986, this book has been the guide for vi. However, Unix systems are not what they were 30 years ago, and neither is this

  6. Behaviors of radionuclides in wet underground soil

    International Nuclear Information System (INIS)

    Inoue, Y.; Morisawa, S.

    Experimental studies were made of the variations of the distribution coefficient of 65 Zn, 60 Co, and /sup 110 m/Ag with Ca ion contents in sand--water and resin--water systems. It is concluded that: (1) The distribution coefficient of a radionuclide is not constant but varies greatly especially with calcium ion concentration in underground water. (2) The Saturation Index I=pH-pHs can be used as a parameter to indicate such variations. (3) Some radionuclides, existing as radiocolloids like (sup 110m/Ag and 59 Fe, are inactive toward ion exchange reactions as with hydroxide. In such cases, the nuclides migrate underground as fast as underground water

  7. Chromium(VI) bioremediation by probiotics.

    Science.gov (United States)

    Younan, Soraia; Sakita, Gabriel Z; Albuquerque, Talita R; Keller, Rogéria; Bremer-Neto, Hermann

    2016-09-01

    Chromium is a common mineral in the earth's crust and can be released into the environment from anthropogenic sources. Intake of hexavalent chromium (Cr(VI)) through drinking water and food causes toxic effects, leading to serious diseases, and is a commonly reported environmental problem. Microorganisms can mitigate or prevent the toxic effects caused by heavy metals in addition to having effective resistance mechanisms to prevent cell damage and bind to these metals, sequestering them from the cell surface and removing them from the body. Species of Lactobacillus, Streptococcus, Bacillus and Bifidobacterium present in the human mouth and gut and in fermented foods have the ability to bind and detoxify some of these substances. This review address the primary topics related to Cr(VI) poisoning in animals and humans and the use of probiotics as a way to mitigate or prevent the toxic effects caused by Cr(VI). Further advances in the genetic knowledge of such microorganisms may lead to discoveries which will clarify the most active microorganisms that act as bioprotectants in bodies exposed to Cr(VI) and are an affordable option for people and animals intoxicated by the oral route. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

  8. The Horonobe Underground Research Laboratory (Tentative name) Project. A program on survey and research performed from earth surface

    International Nuclear Information System (INIS)

    2001-03-01

    The Horonobe Underground Research Laboratory (Tentative name) Project under planning at Horonobe-machi by the Japan Nuclear Cycle Development Institute (JNC) is a research facility on deep underground shown in the Long-term program on research, development and application of nuclear energy (June, 1994)' (LPNE), where some researches on the deep underground targeted at sedimentary rocks are carried out. The plan on The Horonobe Underground Research Laboratory performed at Horonobe-machi' is an about 20 years plan ranging from beginning to finishing of its survey and research, which is carried out by three steps such as 'Survey and research performed from earth surface', 'Survey and research performed under excavation of road', and Survey and research performed by using the road'. The Horonobe Underground Research Laboratory is one of research facilities on deep underground shown its importance in LPNE, and carries out some researches on the deep underground at a target of the sedimentary rocks. And also The Horonobe Underground Research Laboratory confirms some technical reliability and support on stratum disposal shown in the 'Technical reliability on stratum disposal of the high level radioactive wastes. The Second Progress Report of R and D on geological disposal' summarized on November, 1999 by JNC through actual tests and researches at the deep stratum. The obtained results are intended to reflect to disposal business of The Horonobe Underground Research Laboratory and safety regulation and so on performed by the government, together with results of stratum science research, at the Tono Geoscience Center, of geological disposal R and D at the Tokai Works, or of international collaborations. For R and D at the The Horonobe Underground Research Laboratory after 2000, following subjects are shown: 1) Survey technique on long-term stability of geological environment, 2) Survey technique on geological environment, 3) Engineering technique on engineered barrier and

  9. A study of feasibility, design and cost of excavations for underground siting of nuclear power plants

    International Nuclear Information System (INIS)

    1976-02-01

    A study conducted for the State Power Board on underground siting of nuclear power plants is presented. The report is divided into two chapters, both concerning the technical aspects of large underground openings. The first chapter gives a brief general survey of the problems involved, and the second outlines the technical aspects of a PWR project at a specific site. Details are given in 8 appendices and arrangement drawings. The project differs from conventional hydroelectric excavation schemes mainly in the fact that the spherical reactor containment requires a vault of 60m free span, and the turbine hall a cylindrical vault of 45m span, both of which exceed any span hitherto built for similar purposes. This requires a comparatively wide extrapolation of tested and available experience in underground excavations for permanent civil use. To what extent and under what circumstances such extrapolation is tenable must be tested in practice, preferably in a specially controlled prototype test. However the study indicates that conventional nuclear power plants can be sited underground when the topography and rock conditions are suitable. A 1000-2000 MW conventional plant adapted for underground siting will require large span caverns, tunnels and shafts, totalling about 1.0 mill. cubic metres of underground excavation. In addition access and cooling water tunnels, depending on the location, will require 0.2-0.5 mill. cubic metres of tunnel excavations. The excavations and support work can be completed within a construction time of about 2 1/2 years at an estimated total cost of 215 mill. Norwegian kroner (1975 value). (JIW)

  10. Simulation of Daylighting Conditions in a Virtual Underground City

    Directory of Open Access Journals (Sweden)

    Cristiano Merli Alcini

    2015-06-01

    Full Text Available From the Piranesi fantastic architectures to the animation movies and video games of the last thirty years, a new design approach has been introduced and developed: the design of the virtual space. Designing the "virtual" means experiencing a multidisciplinary approach where architecture, engineering, and urban planning meet the new horizons of information and communication technology. This study is focused on virtual space, which is an underground city. Mankind have always made and used underground environments: the possibilities of unlimited spaces to potential development, the reduced needs for raw materials for the construction and the protection from outdoor weather are some of the reasons that prompted humans to the realization of underground spaces in the past. These reasons and the availability of innovative technologies could encourage a breakthrough in the realization of new underground environments. A recent example is represented by the Underground City of Montreal (RÉSO. We present the architectural design of a virtual underground city, which is called Arch[ane], and its evaluation. The underground city is modular and the studied module is composed of eight floors with a total depth of 400 m and dimensions of 800 m × 800 m. The study comprises the evaluation of the effect of sunlight on each eight floors of the city. Daylighting simulations were performed considering different cities at different latitudes, days, and hours. The results have shown that the particular design of the underground city with skylights gives significant values of illuminance at a certain depth. Furthermore, the simulation results show how huge can be the potentialities of software to simulate extremely big environments.

  11. Radon exposure in selected underground touring routes in Poland

    International Nuclear Information System (INIS)

    Olszewski, J.; Chruscielewski, W.; Jankowski, J.

    2006-01-01

    The radioactive elements abounding in the natural environment cause that the whole human population is exposed to radiation. In Poland, mean gamma radiation dose power is 45.4 n Gy h -1 , while atmospheric radon concentration is 4.4 Bq m -3 [1]. In closed rooms, where radon tends to accumulate, the concentrations may be many times higher.Underground touring routes located in caves, mines, ancient cellars, vaults may accumulate radon at concentrations several thousand times exceeding its atmospheric levels. Studies on natural radioactivity in underground touring routes, with particular reference to caves, have continued worldwide since the 80's. Current register of underground touring routes in Poland comprises over 30 items, which include caves (e.g. Niedzwiedzia), mines (Wieliczka), cellars and underground stores (Opatow City vaults) and military objects (underground factories of Walim). The Nofer Institute of Occupational Medicine has for several years already continued determinations of periodical mean radon concentrations in four underground touring routes (starting date in parentheses): Niedzwiedzia Cave (1995); Kowary Drifts closed uranium mine (2001); closed uranium mine in Kletno (2004); Zloty Stok closed gold mine (2004); Osowka underground city in Gluszyca (2004).The results of our determinations of radon concentrations at five selected touring routes lead to the following conclusions. 1. The exposure in the Kowary Drifts touring route is at the level of 5% of the recommended maximum annual admissible limit of 20 mSv. 2. It is assessed that workers of the touring routes where exposures are estimated from the measured concentrations and the time spent underground may receive doses ranging from 0.01 to 5 mSv. (N.C.)

  12. Radon exposure in selected underground touring routes in Poland

    Energy Technology Data Exchange (ETDEWEB)

    Olszewski, J.; Chruscielewski, W.; Jankowski, J. [Nofer Institute of Occupational Medicine, Dept. of Radiation Protection, Lodz (Poland)

    2006-07-01

    The radioactive elements abounding in the natural environment cause that the whole human population is exposed to radiation. In Poland, mean gamma radiation dose power is 45.4 n Gy h{sup -1}, while atmospheric radon concentration is 4.4 Bq m{sup -3} [1]. In closed rooms, where radon tends to accumulate, the concentrations may be many times higher.Underground touring routes located in caves, mines, ancient cellars, vaults may accumulate radon at concentrations several thousand times exceeding its atmospheric levels. Studies on natural radioactivity in underground touring routes, with particular reference to caves, have continued worldwide since the 80's. Current register of underground touring routes in Poland comprises over 30 items, which include caves (e.g. Niedzwiedzia), mines (Wieliczka), cellars and underground stores (Opatow City vaults) and military objects (underground factories of Walim). The Nofer Institute of Occupational Medicine has for several years already continued determinations of periodical mean radon concentrations in four underground touring routes (starting date in parentheses): Niedzwiedzia Cave (1995); Kowary Drifts closed uranium mine (2001); closed uranium mine in Kletno (2004); Zloty Stok closed gold mine (2004); Osowka underground city in Gluszyca (2004).The results of our determinations of radon concentrations at five selected touring routes lead to the following conclusions. 1. The exposure in the Kowary Drifts touring route is at the level of 5% of the recommended maximum annual admissible limit of 20 mSv. 2. It is assessed that workers of the touring routes where exposures are estimated from the measured concentrations and the time spent underground may receive doses ranging from 0.01 to 5 mSv. (N.C.)

  13. Underground siting of nuclear power plants: potential benefits and penalties

    International Nuclear Information System (INIS)

    Allensworth, J.A.; Finger, J.T.; Milloy, J.A.; Murfin, W.B.; Rodeman, R.; Vandevender, S.G.

    1977-08-01

    The potential for improving nuclear power safety is analyzed by siting plants underground in mined cavities or by covering plants with fill earth after construction in an excavated cut. Potential benefits and penalties of underground plants are referenced to analogous plants located on the surface. Three representative regional sites having requisite underground geology were used to evaluate underground siting. The major factors which were evaluated for all three sites were: (1) containment of radioactive materials, (2) transport of groundwater contamination, and (3) seismic vulnerability. External protection, plant security, feasibility, operational considerations, and cost were evaluated on a generic basis. Additionally, the national availability of sites having the requisite geology for both underground siting concepts was determined

  14. The Stranger Within: Dostoevsky's Underground

    Science.gov (United States)

    Roberts, Peter

    2013-01-01

    In Fyodor Dostoevsky's influential novel "Notes from underground", we find one of the most memorable characters in nineteenth century literature. The Underground Man, around whom everything else in this book revolves, is in some respects utterly repugnant: he is self-centred, obsessive and cruel. Yet he is also highly intelligent,…

  15. Underground laboratories in Japan and North America

    International Nuclear Information System (INIS)

    Sobel, Henry W

    2006-01-01

    There is a blossoming demand for deep underground laboratory space to satisfy the expanding interest in experiments that require significant cosmic-ray shielding. I'll briefly describe the existing deep facilities and their plans for expansion. I will also discuss the planning for a new major underground facility in the U.S

  16. First ATLAS Events Recorded Underground

    CERN Multimedia

    Teuscher, R

    As reported in the CERN Bulletin, Issue No.30-31, 25 July 2005 The ATLAS barrel Tile calorimeter has recorded its first events underground using a cosmic ray trigger, as part of the detector commissioning programme. This is not a simulation! A cosmic ray muon recorded by the barrel Tile calorimeter of ATLAS on 21 June 2005 at 18:30. The calorimeter has three layers and a pointing geometry. The light trapezoids represent the energy deposited in the tiles of the calorimeter depicted as a thick disk. On the evening of June 21, the ATLAS detector, now being installed in the underground experimental hall UX15, reached an important psychological milestone: the barrel Tile calorimeter recorded the first cosmic ray events in the underground cavern. An estimated million cosmic muons enter the ATLAS cavern every 3 minutes, and the ATLAS team decided to make good use of some of them for the commissioning of the detector. Although only 8 of the 128 calorimeter slices ('superdrawers') were included in the trigg...

  17. Research on prognostics and health management of underground pipeline

    Science.gov (United States)

    Zhang, Guangdi; Yang, Meng; Yang, Fan; Ni, Na

    2018-04-01

    With the development of the city, the construction of the underground pipeline is more and more complex, which has relation to the safety and normal operation of the city, known as "the lifeline of the city". First of all, this paper introduces the principle of PHM (Prognostics and Health Management) technology, then proposed for fault diagnosis, prognostics and health management in view of underground pipeline, make a diagnosis and prognostics for the faults appearing in the operation of the underground pipeline, and then make a health assessment of the whole underground pipe network in order to ensure the operation of the pipeline safely. Finally, summarize and prospect the future research direction.

  18. Titanium dioxide-based DGT for measuring dissolved As(V), V(V), Sb(V), Mo(VI) and W(VI) in water

    DEFF Research Database (Denmark)

    Panther, Jared G.; Stewart, Ryan R.; Teasdale, Peter R.

    2013-01-01

    A titanium dioxide-based DGT method (Metsorb-DGT) was evaluated for the measurement of As(V), V(V), Sb(V), Mo(VI), W(VI) and dissolved reactive phosphorus (DRP) in synthetic waters. Mass vs. time DGT deployments at pH 6.06 (0.01 mol L-1 NaNO3) demonstrated linear uptake of all analytes (R2...... for deployment times >4 h (CDGT=0.27-0.72). For ferrihydrite-DGT, CDGT/CSol values in the range 0.92-1.16 were obtained for As(V), V(V) and DRP, however, Mo(VI), Sb(V) and W(VI) could not be measured to within 15% of the solution concentration (C DGT/CSol 0.02-0.83)....

  19. Physics at the proposed National Underground Science Facility

    International Nuclear Information System (INIS)

    Nieto, M.M.

    1983-01-01

    The scientific, technical, and financial reasons for building a National Underground Science Facility are discussed. After reviewing examples of other underground facilities, we focus on the Los Alamos proposal and the national for its choice of site

  20. Optimizing the application of magnetic nanoparticles in Cr(VI) removal

    Science.gov (United States)

    Simeonidis, Konstantinos; Kaprara, Efthymia; Mitrakas, Manassis; Tziomaki, Magdalini; Angelakeris, Mavroidis; Vourlias, Georgios; Andritsos, Nikolaos

    2013-04-01

    nanoparticles to reduce Cr(VI) concentration below the regulation limit. The removal capacity is maximized for Fe3O4 nanoparticles due to the high reducing potential of the Fe2+ cations. Furthermore, their applicability was tested in a pilot-scale magnetic separator for the continuous flow removal of nanoparticles after water treatment that takes advantage of the magnetic properties. Acknowledgment This work was implemented within the framework of the Action «Supporting Postdoctoral Researchers» of the Operational Program "Education and Lifelong Learning" (Action's Beneficiary: General Secretariat for Research and Technology), and is co-financed by the European Social Fund (ESF) and the Greek State.

  1. Underground spaces/cybernetic spaces

    Directory of Open Access Journals (Sweden)

    Tomaž Novljan

    2000-01-01

    Full Text Available A modern city space is a space where in the vertical and horizontal direction dynamic, non-linear processes exist, similar as in nature. Alongside the “common” city surface, cities have underground spaces as well that are increasingly affecting the functioning of the former. It is the space of material and cybernetic communication/transport. The psychophysical specifics of using underground places have an important role in their conceptualisation. The most evident facts being their limited volume and often limited connections to the surface and increased level of potential dangers of all kinds. An efficient mode for alleviating the effects of these specific features are artistic interventions, such as: shape, colour, lighting, all applications of the basic principles of fractal theory.

  2. Case study of siting technology for underground nuclear power plant

    International Nuclear Information System (INIS)

    Hibino, Satoshi; Komada, Hiroya; Honsho, Shizumitsu; Fujiwara, Yoshikazu; Motojima, Mutsumi; Nakagawa, Kameichiro; Nosaki, Takashi

    1991-01-01

    Underground siting method is one of new feasible siting methods for nuclear power plants. This report presents the results on case studies on underground siting. Two sites of a steeply inclined and plateau like configurations were selected. 'Tunnel type cavern; all underground siting' method was applied for the steeply inclined configuration, and 'shaft type semi-cavern; partial underground siting' method was applied for the plateau like configuration. The following designs were carried out for these two sites as case studies; (1) conceptual designs, (2) geological surveys and rock mechanics tests, (3) stability analysis during cavern excavations, (4) seismic stability analysis of caverns during earthquake, (5) reinforcement designs for caverns, (6) drainage designs. The case studies showed that these two cases were fully feasible, and comparison between two cases revealed that the 'shaft type semi-cavern; partial underground siting' method was more suitable for Japanese islands. As a first step of underground siting, therefore, the authors recommend to construct a nuclear power plant by this method. (author)

  3. Dynamic response of underground openings in discontinuous rock

    International Nuclear Information System (INIS)

    Asmis, H.W.

    1984-02-01

    This report examines the behaviour of underground openings in discontinuous rock in response to seismic waves associated with either earthquakes or rock bursts. A literature search revealed that well-constructed underground structures, such as would be expected for nuclear fuel waste disposal vaults, underground pumped-storage or nuclear plants, have an extremely high resistance to damage from seismic motion. To complement these qualitative results, it was necessary to examine the basic mechanisms of the entire progression of seismic motion, from wave generation and propagation, to wave interaction with the underground opening. From these investigations, it was found that unless a seismic event occurs very close to the installation, the stresses generated will be low with respect to the excavation stresses, because high stress waves are rapidly attenuated in travelling through rock. As well, an earthquake may generate extremely high accelerations, but is limited in the maximum amount of stress that it can create. The question, however, of the actual specific nature of underground seismic motions still remains essentially unanswered, although it is expected that there is a reduction in peak motions with depth due to the effect of the free surface of the earth

  4. THE JOSEF REGIONAL UNDERGROUND RESEARCH CENTRE (JOSEF URC

    Directory of Open Access Journals (Sweden)

    Dana Pacovská

    2012-07-01

    Full Text Available The Josef Gallery, located in the central Bohemia region of the Czech Republic was first excavated in 1981 as an exploration complex for the potential mining of gold. In 2007, the gallery was substantially reconstructed to house the Josef Underground Educational Facility (Josef UEF, which subsequently became an autonomous workplace under the direction of the Czech Technical University in Prague. At the beginning of 2010, the UEF was renamed the Josef Regional Underground Research Centre (Josef URC which, along with the extensive underground complex, features modern above-ground facilities. One of the most important roles of this research center is to provide practical in-situ instruction in the fields of geotechnical engineering, geology, geochemistry, radiochemistry and radioecology. The training of future experts in this authentic underground setting involves the participation of several other Czech universities and numerous experienced specialists from outside the academic sphere. The IAEA (International Atomic Energy Agency has added the Josef URC to its prestigious list of international training canters involved in the “Training in and Demonstration of Waste Disposal Technologies in Underground Research Facilities – A Network of Centers of Excellence” project.

  5. The Mimetic Principle in the Underground Economy

    Directory of Open Access Journals (Sweden)

    Cristina Voicu

    2009-08-01

    Full Text Available There has been in the recent years an increased preoccupation at international level for the research of the mechanism of development of the underground economy. The numerous vain attempts to measure the dimension of the underground economy persuaded us to embark on a qualitative research of this economic phenomenon. In our investigation on the roots of the underground economy we drew very close to the psychological and sociological aspects of the phenomenon itself. The process of humanizing that has at its origin components of the mimetic principle, like acquisitive mimesis, prompt us to ponder over J.M. Keynes’ words: „The avoidance of taxes is the only intellectual ambition that one feels rewarded for.”

  6. RP delves underground

    CERN Document Server

    Anaïs Schaeffer

    2011-01-01

    The LHC’s winter technical stop is rapidly approaching. As in past years, technical staff in their thousands will be flocking to the underground areas of the LHC and the Linac2, Booster, PS and SPS injectors. To make sure they are protected from ionising radiation, members of the Radiation Protection Group will perform an assessment of the levels of radioactivity in the tunnels as soon as the beams have stopped.   Members of the Radiation Protection Group with their precision instruments that measure radioactivity. At 7-00 a.m. on 8 December the LHC and all of the upstream accelerators will begin their technical stop. At 7-30 a.m., members of the Radiation Protection Group will enter the tunnel to perform a radiation mapping, necessary so that the numerous teams can do their work in complete safety. “Before we proceed underground, we always check first to make sure that the readings from the induced radioactivity monitors installed in the tunnels are all normal,&rdqu...

  7. Når vi taler om 68

    DEFF Research Database (Denmark)

    Jensen, Henrik; Metz, Georg

    Når vi taler om 68 er en intellektuel samtale mellem to ligeværdige gentlemen og skallesmækkere. En essayistisk dyst om porno, RAF, Pittelkow og livsfilosofi......Når vi taler om 68 er en intellektuel samtale mellem to ligeværdige gentlemen og skallesmækkere. En essayistisk dyst om porno, RAF, Pittelkow og livsfilosofi...

  8. Research progress in the electrochemical synthesis of ferrate(VI)

    International Nuclear Information System (INIS)

    Macova, Zuzana; Bouzek, Karel; Hives, Jan; Sharma, Virender K.; Terryn, Raymond J.; Baum, J. Clayton

    2009-01-01

    There is renewed interest in the +6 oxidation state of iron, ferrate (VI) (Fe VI O 4 2- ), because of its potential as a benign oxidant for organic synthesis, as a chemical in developing cleaner ('greener') technology for remediation processes, and as an alternative for environment-friendly battery cathodes. This interest has led many researchers to focus their attention on the synthesis of ferrate(VI). Of the three synthesis methods, electrochemical, wet chemical and thermal, electrochemical synthesis has received the most attention due to its ease and the high purity of the product. Moreover, electrochemical processes use an electron as a so-called clean chemical, thus avoiding the use of any harmful chemicals to oxidize iron to the +6 oxidation state. This paper reviews the development of electrochemical methods to synthesize ferrate(VI). The approaches chosen by different laboratories to overcome some of the difficulties associated with the electrochemical synthesis of ferrate(VI) are summarized. Special attention is paid to parameters such as temperature, anolyte, and anode material composition. Spectroscopic work to understand the mechanism of ferrate(VI) synthesis is included. Recent advances in two new approaches, the use of an inert electrode and molten hydroxide salts, in the synthesis of ferrate(VI) are also reviewed. Progress made in the commercialization of ferrate(VI) continuous production is briefly discussed as well

  9. Underground nuclear energy complexes - technical and economic advantages

    Energy Technology Data Exchange (ETDEWEB)

    Myers, Carl W [Los Alamos National Laboratory; Kunze, Jay F [IDAHO STATE UNIV; Giraud, Kellen M [BABECOCK AND WILCOX; Mahar, James M [IDAHO STATE UNIV

    2010-01-01

    Underground nuclear power plant parks have been projected to be economically feasible compared to above ground instalIations. This paper includes a thorough cost analysis of the savings, compared to above ground facilities, resulting from in-place entombment (decommissioning) of facilities at the end of their life. reduced costs of security for the lifetime of the various facilities in the underground park. reduced transportation costs. and reduced costs in the operation of the waste storage complex (also underground). compared to the fair share of the costs of operating a national waste repository.

  10. Dynamic Underground Stripping Demonstration Project

    International Nuclear Information System (INIS)

    Aines, R.; Newmark, R.; McConachie, W.; Rice, D.; Ramirez, A.; Siegel, W.; Buettner, M.; Daily, W.; Krauter, P.; Folsom, E.; Boegel, A.J.; Bishop, D.; udel, K.

    1992-03-01

    LLNL is collaborating with the UC Berkeley College of Engineering to develop and demonstrate a system of thermal remediation and underground imaging techniques for use in rapid cleanup of localized underground spills. Called ''Dynamic Stripping'' to reflect the rapid and controllable nature of the process, it will combine steam injection, direct electrical heating, and tomographic geophysical imaging in a cleanup of the LLNL gasoline spill. In the first 8 months of the project, a Clean Site engineering test was conducted to prove the field application of the techniques before moving to the contaminated site in FY 92

  11. Synthesis, characterization and oxidative behaviour of dioxoruthenium(VI) complexes

    International Nuclear Information System (INIS)

    Agarwal, D.D.; Rastogi, Rachana

    1995-01-01

    Dioxoruthenium(VI) complexes are found to give low yield of epoxide but good yield of cyclohexanone. The complexes are electro active giving metal centered Ru VI /Ru V couple. Cis-stilbene gives trans epoxide and benzaldehyde. Norbornene gives exo epoxy norbornene. The selectivity for allylic oxidation is high. In the present note the synthesis of dioxoruthenium(VI) complexes and their oxidation behaviour is reported. The dioxoruthenium(VI) complexes have been stoichiometrically found to be good oxidants. (author). 21 refs., 1 tab

  12. Fructan dynamics in the underground organs of Chresta exsucca (Asteraceae, a dry season flowering species

    Directory of Open Access Journals (Sweden)

    Camila Silva dos Santos

    2017-11-01

    Full Text Available ABSTRACT Climatic seasonality has an influence on the phenology of native Cerrado plants. Herbs and subshrubs tend to flower in the rainy season, although some species of these habits flower in the dry season. Reserve carbohydrates, stored in the underground organs, are used to support phases of high energy-demand, but also may protect plants from damage during periods of environmental limitation. In this study we evaluated variation in fructan levels in the underground organs of field-grown plants of Chresta exsucca among different phenological phases. Chresta exsucca flowers in the dry season and possesses a diffuse underground system, which stores inulin-type fructans. Resprouting was continual during the sampling period. Oligosaccharide content was always higher than polysaccharide content, except during senescence, the only phase with an oligosaccharide: polysaccharide ratio < 1. Fructan accumulation occurred during vegetative growth until flowering. Fructan mobilization was prominent during resprouting until the beginning of vegetative growth. Fructans stored in the underground organs of C. exsucca serve to fulfill the energetic demands of development and maintenance of this complex structure. In this way, fructans are essential to the persistence of this species in the environment of the Cerrado by ensuring reproduction in harsh conditions, such as drought.

  13. Modeling of Contaminant Migration through Porous Media after Underground Coal Gasification in Shallow Coal Seam

    Czech Academy of Sciences Publication Activity Database

    Soukup, Karel; Hejtmánek, Vladimír; Čapek, P.; Stanczyk, K.; Šolcová, Olga

    2015-01-01

    Roč. 140, DEC (2015), s. 188-197 ISSN 0378-3820 Grant - others:RFCS(XE) RFCR-CT-2011-00002 Institutional support: RVO:67985858 Keywords : underground coal gasification * transport phenomena modeling * transport parameters Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 3.847, year: 2015

  14. Diseases of uranium miners and other underground miners exposed to radon

    International Nuclear Information System (INIS)

    Samet, J.M.

    1991-01-01

    Excess lung cancer has been demonstrated in many groups of underground miners exposed to radon, including uranium miners and those mining other substances in radon-contaminated mines. In the United States, most underground uranium mines had shut down by the late 1980s, but occupational exposure to radon progeny remains a concern for many other types of underground miners and other underground workers. Worldwide, uranium mining continues, with documented production in Canada, South Africa and other African countries, and Australia. Thus, radon in underground mines remains a significant occupational hazard as the end of the twentieth century approaches.39 references

  15. Underground laboratories

    Energy Technology Data Exchange (ETDEWEB)

    Bettini, A., E-mail: Bettini@pd.infn.i [Padua University and INFN Section, Dipartimento di Fisca G. Galilei, Via Marzolo 8, 35131 Padova (Italy); Laboratorio Subterraneo de Canfranc, Plaza Ayuntamiento n1 2piso, Canfranc (Huesca) (Spain)

    2011-01-21

    Underground laboratories provide the low radioactive background environment necessary to frontier experiments in particle and nuclear astrophysics and other disciplines, geology and biology, that can profit of their unique characteristics. The cosmic silence allows to explore the highest energy scales that cannot be reached with accelerators by searching for extremely rare phenomena. I will briefly review the facilities that are operational or in an advanced status of approval around the world.

  16. Underground gasification and combustion brown with the use of groundwater

    Directory of Open Access Journals (Sweden)

    Zholudyev S.V.

    2011-11-01

    Full Text Available The problems of coal excavation and environement protection are priority for Ukraine. Underground coal gasification (UCG and underground coal incineration (UCI are combining excavation with simultaneous underground processing in entire technological process, capable to solve this problem. Using an intermediate heat carrier - ground water may optimisating of these processes.

  17. New generation ion-imprinted nanocarrier for removal of Cr(VI) from wastewater

    International Nuclear Information System (INIS)

    Uygun, Murat; Feyzioğlu, Esra; Özçalışkan, Emir; Caka, Müşerref; Ergen, Aygen; Akgöl, Sinan; Denizli, Adil

    2013-01-01

    The purpose of this study was to prepare a novel ion-imprinted nanoparticle to remove Cr(VI) ions from waste water. For this, Cr(VI) ions were complexed with 2-methacryloylamido histidine (MAH) and then Cr(VI)-imprinted poly(HEMAH) nanoparticles were synthesized by surfactant-free emulsion polymerization technique. The templates, Cr(VI) ions, were removed from the nanoparticles using 0.1 M of HNO 3 solution. The specific surface area of the Cr(VI)-imprinted poly(HEMAH) nanoparticles was found to be 1,397.85 m 2 /g, and the particle size was calculated as 155.3 nm. These Cr(VI)-imprinted nanoparticles were used for the adsorption/desorption of Cr(VI) ions from its aqueous solutions. The effects of initial Cr(VI) concentration and medium pH on the Cr(VI) adsorption capacity were also studied. The maximum adsorbed amount of Cr(VI) on the imprinted nanoparticles was found to be 3,830.58 mg/g nanoparticle in pH 4.0. In order to investigate the selectivity of the imprinted nanoparticle, adsorption studies were repeated using Cr(III) ions. The selectivity results demonstrated that Cr(VI)-imprinted poly(HEMAH) nanoparticles showed high affinity for the Cr(VI) ions than Cr(III). The Cr(VI)-imprinted nanoparticles were used several times without decreasing their Cr(VI) adsorption capacities

  18. New generation ion-imprinted nanocarrier for removal of Cr(VI) from wastewater

    Science.gov (United States)

    Uygun, Murat; Feyzioğlu, Esra; Özçalışkan, Emir; Caka, Müşerref; Ergen, Aygen; Akgöl, Sinan; Denizli, Adil

    2013-08-01

    The purpose of this study was to prepare a novel ion-imprinted nanoparticle to remove Cr(VI) ions from waste water. For this, Cr(VI) ions were complexed with 2-methacryloylamido histidine (MAH) and then Cr(VI)-imprinted poly(HEMAH) nanoparticles were synthesized by surfactant-free emulsion polymerization technique. The templates, Cr(VI) ions, were removed from the nanoparticles using 0.1 M of HNO3 solution. The specific surface area of the Cr(VI)-imprinted poly(HEMAH) nanoparticles was found to be 1,397.85 m2/g, and the particle size was calculated as 155.3 nm. These Cr(VI)-imprinted nanoparticles were used for the adsorption/desorption of Cr(VI) ions from its aqueous solutions. The effects of initial Cr(VI) concentration and medium pH on the Cr(VI) adsorption capacity were also studied. The maximum adsorbed amount of Cr(VI) on the imprinted nanoparticles was found to be 3,830.58 mg/g nanoparticle in pH 4.0. In order to investigate the selectivity of the imprinted nanoparticle, adsorption studies were repeated using Cr(III) ions. The selectivity results demonstrated that Cr(VI)-imprinted poly(HEMAH) nanoparticles showed high affinity for the Cr(VI) ions than Cr(III). The Cr(VI)-imprinted nanoparticles were used several times without decreasing their Cr(VI) adsorption capacities.

  19. New generation ion-imprinted nanocarrier for removal of Cr(VI) from wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Uygun, Murat, E-mail: muygun@adu.edu.tr [Adnan Menderes University, Kocarl Latin-Small-Letter-Dotless-I Vocational and Training School (Turkey); Feyzioglu, Esra; Oezcal Latin-Small-Letter-Dotless-I skan, Emir; Caka, Mueserref; Ergen, Aygen; Akgoel, Sinan [Ege University, Department of Biochemistry, Faculty of Science (Turkey); Denizli, Adil [Hacettepe University, Department of Chemistry, Faculty of Science (Turkey)

    2013-08-15

    The purpose of this study was to prepare a novel ion-imprinted nanoparticle to remove Cr(VI) ions from waste water. For this, Cr(VI) ions were complexed with 2-methacryloylamido histidine (MAH) and then Cr(VI)-imprinted poly(HEMAH) nanoparticles were synthesized by surfactant-free emulsion polymerization technique. The templates, Cr(VI) ions, were removed from the nanoparticles using 0.1 M of HNO{sub 3} solution. The specific surface area of the Cr(VI)-imprinted poly(HEMAH) nanoparticles was found to be 1,397.85 m{sup 2}/g, and the particle size was calculated as 155.3 nm. These Cr(VI)-imprinted nanoparticles were used for the adsorption/desorption of Cr(VI) ions from its aqueous solutions. The effects of initial Cr(VI) concentration and medium pH on the Cr(VI) adsorption capacity were also studied. The maximum adsorbed amount of Cr(VI) on the imprinted nanoparticles was found to be 3,830.58 mg/g nanoparticle in pH 4.0. In order to investigate the selectivity of the imprinted nanoparticle, adsorption studies were repeated using Cr(III) ions. The selectivity results demonstrated that Cr(VI)-imprinted poly(HEMAH) nanoparticles showed high affinity for the Cr(VI) ions than Cr(III). The Cr(VI)-imprinted nanoparticles were used several times without decreasing their Cr(VI) adsorption capacities.

  20. ALTERATION OF U(VI)-PHASES UNDER OXIDIZING CONDITIONS

    Energy Technology Data Exchange (ETDEWEB)

    A.P. Deditius; S. Utsunomiya; R.C. Ewing

    2006-02-21

    Uranium-(VI) phases are the primary alteration products of the UO{sub 2} in spent nuclear fuel and the UO{sub 2+x}, in natural uranium deposits. The U(VI)-phases generally form sheet structures of edge-sharing UO{sub 2}{sup 2+} polyhedra. The complexity of these structures offers numerous possibilities for coupled-substitutions of trace metals and radionuclides. The incorporation of radionuclides into U(VI)-structures provides a potential barrier to their release and transport in a geologic repository that experiences oxidizing conditions. In this study, we have used natural samples of UO{sub 2+x}, to study the U(VI)-phases that form during alteration and to determine the fate of the associated trace elements.

  1. ALTERATION OF U(VI)-PHASES UNDER OXIDIZING CONDITIONS

    International Nuclear Information System (INIS)

    A.P. Deditius; S. Utsunomiya; R.C. Ewing

    2006-01-01

    Uranium-(VI) phases are the primary alteration products of the UO 2 in spent nuclear fuel and the UO 2+x , in natural uranium deposits. The U(VI)-phases generally form sheet structures of edge-sharing UO 2 2+ polyhedra. The complexity of these structures offers numerous possibilities for coupled-substitutions of trace metals and radionuclides. The incorporation of radionuclides into U(VI)-structures provides a potential barrier to their release and transport in a geologic repository that experiences oxidizing conditions. In this study, we have used natural samples of UO 2+x , to study the U(VI)-phases that form during alteration and to determine the fate of the associated trace elements

  2. Structural design and dynamic analysis of underground nuclear reactor containments

    International Nuclear Information System (INIS)

    Kierans, T.W.; Reddy, D.V.; Heale, D.G.

    1975-01-01

    Present actual experience in the structural design of undeground containments is limited to only four rather small reactors all located in Europe. Thus proposals for future underground reactors depend on the transposition of applicable design specifications, constraints and criteria from existing surface nuclear power plants to underground, and the use of many years of experience in the structural design of large underground cavities and cavity complexes for other purposes such as mining, hydropower stations etc. An application of such considerations in a recent input for the Underground Containment sub-section of the Seismic Task Group Report to the ASCE Committee for Nuclear Structures and Materials is presented as follows: underground concept considerations, siting criteria and structural selection, structural types, analytical and semi-analytical approaches, design and other miscellaneous considerations

  3. About working of the research program on development of underground space of Russia

    International Nuclear Information System (INIS)

    Kartoziya, B.A.

    1995-01-01

    Basic proposition relative to the developed federal program on scientific research in the area of assimilating underground space in Russia are presented. The underground objects are divided by their purpose into four groups: 1) underground objects of house-hold purpose (energy and mining complex, industrial enterprises, storages, garages, etc); 2) underground objects of social purpose (libraries, shops, restaurants, etc); 3) underground objects of ecological purpose (storages, disposal sites for radioactive wastes and hazardous substances, dangerous productions, etc); 4) underground objects of defense purpose. Trends in the scientific-research program formation, relative to underground space assimilation are enumerated. 7 refs

  4. Background intercomparison with escape-suppressed germanium detectors in underground mines

    Energy Technology Data Exchange (ETDEWEB)

    Szuecs, Tamas; Bemmerer, Daniel [Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany)

    2014-07-01

    A key requirement for underground nuclear astrophysics experiments is the very low background level in germanium detectors underground. The reference for these purposes is the world's so far only underground accelerator laboratory for nuclear astrophysics, LUNA. LUNA is located deep underground in the Gran Sasso laboratory in Italy, shielded from cosmic rays by 1400 m of rock. The background at LUNA was studied in detail using an escape-suppressed Clover-type HPGe detector. Exactly the same detector was subsequently transported to the Felsenkeller underground laboratory in Dresden, shielded by 45 m of rock, and the background was shown to be only a factor of three higher than at LUNA when comparing the escape-suppressed spectra, with interesting consequences for underground nuclear astrophysics. As the next step of a systematic study of the effects of a combination of active and passive shielding on the cosmic ray induced background, this detector is now being brought to the ''Reiche Zeche'' mine in Freiberg/Sachsen, shielded by 150 m of rock. The data from the Freiberg measurement are shown and discussed.

  5. Oxidation of trimethoprim by ferrate(VI): kinetics, products, and antibacterial activity.

    Science.gov (United States)

    Anquandah, George A K; Sharma, Virender K; Knight, D Andrew; Batchu, Sudha Rani; Gardinali, Piero R

    2011-12-15

    Kinetics, stoichiometry, and products of the oxidation of trimethoprim (TMP), one of the most commonly detected antibacterial agents in surface waters and municipal wastewaters, by ferrate(VI) (Fe(VI)) were determined. The pH dependent second-order rate constants of the reactions of Fe(VI) with TMP were examined using acid-base properties of Fe(VI) and TMP. The kinetics of reactions of diaminopyrimidine (DAP) and trimethoxytoluene (TMT) with Fe(VI) were also determined to understand the reactivity of Fe(VI) with TMP. Oxidation products of the reactions of Fe(VI) with TMP and DAP were identified by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Reaction pathways of oxidation of TMP by Fe(VI) are proposed to demonstrate the cleavage of the TMP molecule to ultimately result in 3,4,5,-trimethoxybenzaldehyde and 2,4-dinitropyrimidine as among the final identified products. The oxidized products mixture exhibited no antibacterial activity against E. coli after complete consumption of TMP. Removal of TMP in the secondary effluent by Fe(VI) was achieved.

  6. Solvent extraction of uranium(VI), plutonium(VI) and americium(III) with HTTA/HPMBP using mono- and bi-functional neutral donors. Synergism and thermodynamics

    International Nuclear Information System (INIS)

    Pai, S.A.; Lohithakshan, K.V.; Mithapara, P.D.; Aggarwal, S.K.

    2000-01-01

    Synergistic extraction of hexavalent uranium and plutonium as well as trivalent americium was studied in HNO 3 with thenoyl, trifluoro-acetone (HTTA)/1-phenyl, 3-methyl, 4-benzoyl pyrazolone-5 (HPMBP) in combination with neutral donors viz. DPSO, TBP, TOPO (mono-functional) and DBDECMP, DHDECMP, CMPO (bi-functional) with wide basicity range using benzene as diluent. A linear correlation was observed when the equilibrium constant log Ks for the organic phase synergistic reaction of both U(VI) and Pu(VI) with either of the chelating agents HTTA or HPMBP was plotted vs. the basicity (log Kh) of the donor (both mono- and bi-functional) indicating bi-functional donors also behave as mono-functional. This was supported by the thermodynamic data (ΔG 0 , ΔH 0 , ΔS 0 ) obtained for these systems. The organic phase adduct formation reactions were identified for the above systems from the thermodynamic data. In the Am(III) HTTA system log K s values of bi-functional donors were found to be very high and deviate from the linear plot (log K s vs. log K h ) obtained for mono-functional donors, indicating that they function as bi-functional for the Am(III)/HTTA) system studied. This was supported by high +ve ΔS 0 values obtained for this system. (author)

  7. Site selection under the underground geologic store plan. Procedures of selecting underground geologic stores as disputed by society, science, and politics. Site selection rules

    International Nuclear Information System (INIS)

    Aebersold, M.

    2008-01-01

    The new Nuclear Power Act and the Nuclear Power Ordinance of 2005 are used in Switzerland to select a site of an underground geologic store for radioactive waste in a substantive planning procedure. The ''Underground Geologic Store Substantive Plan'' is to ensure the possibility to build underground geologic stores in an independent, transparent and fair procedure. The Federal Office for Energy (BFE) is the agency responsible for this procedure. The ''Underground Geologic Store'' Substantive Plan comprises these principles: - The long term protection of people and the environment enjoys priority. Aspects of regional planning, economics and society are of secondary importance. - Site selection is based on the waste volumes arising from the five nuclear power plants currently existing in Switzerland. The Substantive Plan is no precedent for or against future nuclear power plants. - A transparent and fair procedure is an indispensable prerequisite for achieving the objectives of a Substantive Plan, i.e., finding accepted sites for underground geologic stores. The Underground Geologic Stores Substantive Plan is arranged in two parts, a conceptual part defining the rules of the selection process, and an implementation part documenting the selection process step by step and, in the end, naming specific sites of underground geologic stores in Switzerland. The objective is to be able to commission underground geologic stores in 25 or 35 years' time. In principle, 2 sites are envisaged, one for low and intermediate level waste, and one for high level waste. The Swiss Federal Council approved the conceptual part on April 2, 2008. This marks the beginning of the implementation phase and the site selection process proper. (orig.)

  8. Social Set Visualizer (SoSeVi) II

    DEFF Research Database (Denmark)

    Flesch, Benjamin; Vatrapu, Ravi

    2016-01-01

    This paper reports the second iteration of the Social Set Visualizer (SoSeVi), a set theoretical visual analytics dashboard of big social data. In order to further demonstrate its usefulness in large-scale visual analytics tasks of individual and collective behavior of actors in social networks......, the current iteration of the Social Set Visualizer (SoSeVi) in version II builds on recent advancements in visualizing set intersections. The development of the SoSeVi dashboard involved cutting-edge open source visual analytics libraries (D3.js) and creation of new visualizations such as of actor mobility...

  9. Fremtidens lavenergibyggeri - kan vi gøre som vi plejer?

    DEFF Research Database (Denmark)

    Larsen, Tine Steen

    2011-01-01

    Stramninger af kravene til energiforbruget i vores boliger medfører stor fokus på energiberegningen, men erfaringer fra lavenergiboliger opført i dag viser, at vi, for at sikre succes for fremtidens boliger, også skal inddrage dokumentation af indeklimaet og forbedre samarbejdet mellem arkitekter...

  10. Approaches to surface complexation modeling of Uranium(VI) adsorption on aquifer sediments

    Science.gov (United States)

    Davis, J.A.; Meece, D.E.; Kohler, M.; Curtis, G.P.

    2004-01-01

    Uranium(VI) adsorption onto aquifer sediments was studied in batch experiments as a function of pH and U(VI) and dissolved carbonate concentrations in artificial groundwater solutions. The sediments were collected from an alluvial aquifer at a location upgradient of contamination from a former uranium mill operation at Naturita, Colorado (USA). The ranges of aqueous chemical conditions used in the U(VI) adsorption experiments (pH 6.9 to 7.9; U(VI) concentration 2.5 ?? 10-8 to 1 ?? 10-5 M; partial pressure of carbon dioxide gas 0.05 to 6.8%) were based on the spatial variation in chemical conditions observed in 1999-2000 in the Naturita alluvial aquifer. The major minerals in the sediments were quartz, feldspars, and calcite, with minor amounts of magnetite and clay minerals. Quartz grains commonly exhibited coatings that were greater than 10 nm in thickness and composed of an illite-smectite clay with occluded ferrihydrite and goethite nanoparticles. Chemical extractions of quartz grains removed from the sediments were used to estimate the masses of iron and aluminum present in the coatings. Various surface complexation modeling approaches were compared in terms of the ability to describe the U(VI) experimental data and the data requirements for model application to the sediments. Published models for U(VI) adsorption on reference minerals were applied to predict U(VI) adsorption based on assumptions about the sediment surface composition and physical properties (e.g., surface area and electrical double layer). Predictions from these models were highly variable, with results overpredicting or underpredicting the experimental data, depending on the assumptions used to apply the model. Although the models for reference minerals are supported by detailed experimental studies (and in ideal cases, surface spectroscopy), the results suggest that errors are caused in applying the models directly to the sediments by uncertain knowledge of: 1) the proportion and types of

  11. Connected Cities : Guide to good practice underground space

    NARCIS (Netherlands)

    Van der Hoeven, F.D.; Hobma, W.

    2007-01-01

    This guide to good practice underground space is developed within the framework of the EU-funded INTERREG IIIC project ‘Connected Cities’. It focuses on how a strategic use of underground space can facilitate sustainable modes of transportation and mobility in urban and rural areas. Twelve strategic

  12. 77 FR 56717 - Specifications for Medical Examinations of Underground Coal Miners

    Science.gov (United States)

    2012-09-13

    ... CFR Part 37 Specifications for Medical Examinations of Underground Coal Miners; Final Rule #0;#0... 0920-AA21 Specifications for Medical Examinations of Underground Coal Miners AGENCY: Centers for... medical examinations of underground coal miners. Existing regulations established specifications for...

  13. Evaluation method of radon preventing effect in underground construction

    International Nuclear Information System (INIS)

    Luo Shaodong; Deng Yuequan; Dong Faqin; Qu Ruixue; Xie Zhonglei

    2014-01-01

    Background: It's difficult to evaluate the radon prevention effect because of the short operating time of measuring instrument under the circumstances of high humidity in underground construction. Purpose: A new rapid method to evaluate the radon prevention efficiency of underground construction was introduced. Methods: The radon concentrations before and after shielding operation were determined, and according to the regularity of radon decay, the shielding rate can be calculated. Results: The results showed that radon shielding rate in underground construction remains generally stable with variation of time, and the actual relatively standard deviation was 3.95%. So the rapid determination and evaluation of radon preventing effect under special conditions in underground construction can be realized by taking shielding rate in a short time for the final shielding rate. Compared with those by the local static method in ground lab, the results were similar. Conclusion: This paper provided a prompt, accurate and practicable way for the evaluation of radon prevention in underground construction, having a certain reference value. (authors)

  14. 30 CFR 75.206 - Conventional roof support.

    Science.gov (United States)

    2010-07-01

    ... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Roof Support § 75.206 Conventional roof support. (a) Except in anthracite mines using non-mechanized mining systems, when conventional roof support... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Conventional roof support. 75.206 Section 75...

  15. Chromium(VI) generation in vadose zone soils and alluvial sediments of the southwestern Sacramento Valley, California: A potential source of geogenic Cr(VI) to groundwater

    International Nuclear Information System (INIS)

    Mills, Christopher T.; Morrison, Jean M.; Goldhaber, Martin B.; Ellefsen, Karl J.

    2011-01-01

    Highlights: → Southern Sacramento Valley soil and sediment has abundant naturally-occurring Cr(III). → Cr(III) resides mainly in chromite but some is associated with clays and Fe oxides. → Cr(VI) is mostly absent in surface soil but ubiquitous in deeper soil and sediment. → Cr(VI) increased linearly with time during lab soil incubations with no additions. → Cation exchange processes resulted in greater Cr(VI) generation rates. - Abstract: Concentrations of geogenic Cr(VI) in groundwater that exceed the World Health Organization's maximum contaminant level for drinking water (50 μg L -1 ) occur in several locations globally. The major mechanism for mobilization of this Cr(VI) at these sites is the weathering of Cr(III) from ultramafic rocks and its subsequent oxidation on Mn oxides. This process may be occurring in the southern Sacramento Valley of California where Cr(VI) concentrations in groundwater can approach or exceed 50 μg L -1 . To characterize Cr geochemistry in the area, samples from several soil auger cores (approximately 4 m deep) and drill cores (approximately 25 m deep) were analyzed for total concentrations of 44 major, minor and trace elements, Cr associated with labile Mn and Fe oxides, and Cr(VI). Total concentrations of Cr in these samples ranged from 140 to 2220 mg per kg soil. Between 9 and 70 mg per kg soil was released by selective extractions that target Fe oxides, but essentially no Cr was associated with the abundant reactive Mn oxides (up to ∼1000 mg hydroxylamine-reducible Mn per kg soil was present). Both borehole magnetic susceptibility surveys performed at some of the drill core sites and relative differences between Cr released in a 4-acid digestion versus total Cr (lithium metaborate fusion digestion) suggest that the majority of total Cr in the samples is present in refractory chromite minerals transported from ultramafic exposures in the Coast Range Mountains. Chromium(VI) in the samples studied ranged from 0 to 42

  16. Chromium(VI) generation in vadose zone soils and alluvial sediments of the southwestern Sacramento Valley, California: A potential source of geogenic Cr(VI) to groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Mills, Christopher T., E-mail: cmills@usgs.gov [United States Geological Survey, Crustal Geophysics and Geochemistry Science Center, Denver Federal Center, MS 964D, Denver, CO 80225 (United States); Morrison, Jean M.; Goldhaber, Martin B.; Ellefsen, Karl J. [United States Geological Survey, Crustal Geophysics and Geochemistry Science Center, Denver Federal Center, MS 964D, Denver, CO 80225 (United States)

    2011-08-15

    Highlights: > Southern Sacramento Valley soil and sediment has abundant naturally-occurring Cr(III). > Cr(III) resides mainly in chromite but some is associated with clays and Fe oxides. > Cr(VI) is mostly absent in surface soil but ubiquitous in deeper soil and sediment. > Cr(VI) increased linearly with time during lab soil incubations with no additions. > Cation exchange processes resulted in greater Cr(VI) generation rates. - Abstract: Concentrations of geogenic Cr(VI) in groundwater that exceed the World Health Organization's maximum contaminant level for drinking water (50 {mu}g L{sup -1}) occur in several locations globally. The major mechanism for mobilization of this Cr(VI) at these sites is the weathering of Cr(III) from ultramafic rocks and its subsequent oxidation on Mn oxides. This process may be occurring in the southern Sacramento Valley of California where Cr(VI) concentrations in groundwater can approach or exceed 50 {mu}g L{sup -1}. To characterize Cr geochemistry in the area, samples from several soil auger cores (approximately 4 m deep) and drill cores (approximately 25 m deep) were analyzed for total concentrations of 44 major, minor and trace elements, Cr associated with labile Mn and Fe oxides, and Cr(VI). Total concentrations of Cr in these samples ranged from 140 to 2220 mg per kg soil. Between 9 and 70 mg per kg soil was released by selective extractions that target Fe oxides, but essentially no Cr was associated with the abundant reactive Mn oxides (up to {approx}1000 mg hydroxylamine-reducible Mn per kg soil was present). Both borehole magnetic susceptibility surveys performed at some of the drill core sites and relative differences between Cr released in a 4-acid digestion versus total Cr (lithium metaborate fusion digestion) suggest that the majority of total Cr in the samples is present in refractory chromite minerals transported from ultramafic exposures in the Coast Range Mountains. Chromium(VI) in the samples studied ranged

  17. 30 CFR 784.30 - Support facilities.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Support facilities. 784.30 Section 784.30... Support facilities. Each applicant for an underground coal mining and reclamation permit shall submit a description, plans, and drawings for each support facility to be constructed, used, or maintained within the...

  18. Monitoring and information management system at the Underground Research Laboratory

    International Nuclear Information System (INIS)

    Strobel, G.S.; Chernis, P.J.; Bushman, A.T.; Spinney, M.H.; Backer, R.J.

    1996-01-01

    Atomic Energy of Canada Limited (AECL) has developed a customer oriented monitoring and information management system at the Underground Research Laboratory (URL) near Lac du Bonnet, Manitoba. The system is used to monitor instruments and manage, process, and distribute data. It consists of signal conditioners and remote loggers, central schedule and control systems, computer aided design and drafting work centres, and the communications linking them. The monitoring and communications elements are designed to meet the harsh demands of underground conditions while providing accurate monitoring of sensitive instruments to rigorous quality assured specifications. These instruments are used for testing of the concept for the deep geological disposal of nuclear fuel waste as part of the Canadian Nuclear Fuel Waste Management Program. Many of the tests are done in situ and at full-scale. The monitoring and information management system services engineering, research, and support staff working to design, develop, and demonstrate and present the concept. Experience gained during development of the monitoring and information management system at the URL, can be directly applied at the final disposal site. (author)

  19. Monitoring and information management system at the Underground Research Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Strobel, G.S.; Chernis, P.J.; Bushman, A.T.; Spinney, M.H.; Backer, R.J. [Atomic Energy of Canada Limited, Pinawa, Manitoba (Canada)

    1996-07-01

    Atomic Energy of Canada Limited (AECL) has developed a customer oriented monitoring and information management system at the Underground Research Laboratory (URL) near Lac du Bonnet, Manitoba. The system is used to monitor instruments and manage, process, and distribute data. It consists of signal conditioners and remote loggers, central schedule and control systems, computer aided design and drafting work centres, and the communications linking them. The monitoring and communications elements are designed to meet the harsh demands of underground conditions while providing accurate monitoring of sensitive instruments to rigorous quality assured specifications. These instruments are used for testing of the concept for the deep geological disposal of nuclear fuel waste as part of the Canadian Nuclear Fuel Waste Management Program. Many of the tests are done in situ and at full-scale. The monitoring and information management system services engineering, research, and support staff working to design, develop, and demonstrate and present the concept. Experience gained during development of the monitoring and information management system at the URL, can be directly applied at the final disposal site. (author)

  20. Prediction of underground argon content for dark matter experiments

    International Nuclear Information System (INIS)

    Mei, D.-M.; Spaans, J.; Keller, C.; Yin, Z.-B.; Koppang, M.; Hime, A.; Gehman, V. M.

    2010-01-01

    In this paper, we demonstrate the use of physical models to evaluate the production of 39 Ar and 40 Ar underground. Considering both cosmogenic 39 Ar production and radiogenic 40 Ar production in situ and from external sources, we can derive the ratio of 39 Ar to 40 Ar in underground sources. We show for the first time that the 39 Ar production underground is dominated by stopping negative muon capture on 39 K and (α,n) induced subsequent 39 K(n,p) 39 Ar reactions. The production of 39 Ar is shown as a function of depth. We demonstrate that argon depleted in 39 Ar can be obtained only if the depth of the underground resources is greater than 500 m.w.e. below the surface. Stopping negative muon capture on 39 K dominates over radiogenic production at depths of less than 2000 m.w.e., and that production by muon-induced neutrons is subdominant at any depth. The depletion factor depends strongly on both radioactivity level and potassium content in the rock. We measure the radioactivity concentration and potassium concentration in the rock for a potential site of an underground argon source in South Dakota. Depending on the probability of 39 Ar and 40 Ar produced underground being dissolved in the water, the upper limit of the concentration of 39 Ar in the underground water at this site is estimated to be in a range of a factor of 1.6 to 155 less than the 39 Ar concentration in the atmosphere. The calculation tools presented in this paper are also critical to the dating method with 39 Ar.

  1. Underground Gas Storage in the World 2013 (fifth edition)

    International Nuclear Information System (INIS)

    Cornot-Gandolphe, Sylvie

    2013-06-01

    Since its first publication in 1990, 'Underground Gas Storage in the World' has been the industry's reference on underground gas storage (UGS). The updated 2013 edition includes in-depth CEDIGAZ's analyses of the latest developments and trends in the storage industry all over the world as well as extensive country analyses with complete datasets including current, under construction and planned Underground Gas Storage facilities in 48 countries. It describes the 688 existing storage facilities in the world and the 236 projects under construction and planned. Future storage demand and its main drivers are presented at global and regional levels. The study builds on the CEDIGAZ Underground Gas Storage Database, the only worldwide Underground Gas Storage database to be updated every year. This document summarizes the key findings of the Survey which includes four main parts: The first part gives an overview of underground gas storage in the world at the beginning of 2013 and analyzes future storage needs by 2030, at regional and international levels. The second part focuses on new trends and issues emerging or developing in key storage markets. It analyzes the emerging storage market in China, reviews the storage business climate in Europe, examines Gazprom's storage strategy in Europe, and reviews recent trends in storage development in the United States. The third part gives some fundamental background on technical, economic and regulatory aspects of gas storage. The fourth part gives a countrywide analysis of the 48 countries in the world holding underground gas storage facilities or planning storage projects. 48 countries are surveyed with 688 existing UGS facilities, 256 projects under construction or planned

  2. "We do as well as we can". The experiences of staff assisting disabled people in community residential homes "Við gerum bara eins og við getum" - Þjónusta við fólk með fjölþættar skerðingar

    Directory of Open Access Journals (Sweden)

    Guðný Jónsdóttir

    2013-06-01

    Full Text Available Staff supporting young people and adults with complex and severe neurological impairments are the key to their communication, quality of life and participation. This study reports the knowledge and experiences of staff members supporting disabled people living in community residential homes, as well as their perceived needs for information and support. Furthermore, the study aimed to reveal staff´s views on their possibilities to support service users´ wellbeing, participation and quality of life. Participants were twelve experienced staff members. Qualitative methods were used and data were collected through semi-structured interviews. The results of the study reveal that services provided in community residential homes for people with complex and severe impairments are not in line with human rights treaties, including the right to health. Further, it does not mirror the social approach to disability which today is the focus of policy frameworks. The staff were positive toward service users, tried to do their best but lacked resources. Their knowledge of service user´s health-related needs was scarce and little was done to prevent further impairments or increasing health problems. Staff reported lack of human resources, high staff turnover and lack of information, training and support. Recent governmental changes, provide possibilities for revised emphasis in the service provided, on cooperation between different sectors as well as for the development of transdisciplinary services.Aðstoðarfólk á heimilum fólks með fjölþættar skerðingar er mikilvægur hlekkur í lífi þess og lykill að samskiptum, lífsgæðum og þátttöku. Rannsóknin varpar ljósi á sýn þessa starfsfólks á megináherslur í þjónustu við fólk með flóknar stuðningsþarfir og þörf fyrir fræðslu og stuðning í starfi. Ennfremur var leitað eftir skilningi á heilsutengdum þörfum þjónustunotenda og möguleikum til að styðja við velferð

  3. 30 CFR 57.4161 - Use of fire underground.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Use of fire underground. 57.4161 Section 57.4161 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention...

  4. Modelling biological Cr(VI) reduction in aquifer microcosm column systems.

    Science.gov (United States)

    Molokwane, Pulane E; Chirwa, Evans M N

    2013-01-01

    Several chrome processing facilities in South Africa release hexavalent chromium (Cr(VI)) into groundwater resources. Pump-and-treat remediation processes have been implemented at some of the sites but have not been successful in reducing contamination levels. The current study is aimed at developing an environmentally friendly, cost-effective and self-sustained biological method to curb the spread of chromium at the contaminated sites. An indigenous Cr(VI)-reducing mixed culture of bacteria was demonstrated to reduce high levels of Cr(VI) in laboratory samples. The effect of Cr(VI) on the removal rate was evaluated at concentrations up to 400 mg/L. Following the detailed evaluation of fundamental processes for biological Cr(VI) reduction, a predictive model for Cr(VI) breakthrough through aquifer microcosm reactors was developed. The reaction rate in batch followed non-competitive rate kinetics with a Cr(VI) inhibition threshold concentration of approximately 99 mg/L. This study evaluates the application of the kinetic parameters determined in the batch reactors to the continuous flow process. The model developed from advection-reaction rate kinetics in a porous media fitted best the effluent Cr(VI) concentration. The model was also used to elucidate the logistic nature of biomass growth in the reactor systems.

  5. Polysubstance Use Patterns in Underground Rave Attenders: A Cluster Analysis

    Science.gov (United States)

    Fernandez-Calderon, Fermin; Lozano, Oscar M.; Vidal, Claudio; Ortega, Josefa Gutierrez; Vergara, Esperanza; Gonzalez-Saiz, Francisco; Bilbao, Izaskun; Caluente, Marta; Cano, Tomas; Cid, Francisco; Dominguez, Celia; Izquierdo, Emcarni; Perez, Maria I.

    2011-01-01

    Drug use in mainstream rave parties has been widely documented in a large number of studies. However, not much is known about drug use in underground raves. The purpose of this study is to find out the polysubstance use patterns at underground raves. Two hundred and fifty-two young people between the ages of 18 and 30 who went to underground raves…

  6. Diverse functions of myosin VI elucidated by an isoform-specific α-helix domain.

    Science.gov (United States)

    Wollscheid, Hans-Peter; Biancospino, Matteo; He, Fahu; Magistrati, Elisa; Molteni, Erika; Lupia, Michela; Soffientini, Paolo; Rottner, Klemens; Cavallaro, Ugo; Pozzoli, Uberto; Mapelli, Marina; Walters, Kylie J; Polo, Simona

    2016-04-01

    Myosin VI functions in endocytosis and cell motility. Alternative splicing of myosin VI mRNA generates two distinct isoform types, myosin VI(short) and myosin VI(long), which differ in the C-terminal region. Their physiological and pathological roles remain unknown. Here we identified an isoform-specific regulatory helix, named the α2-linker, that defines specific conformations and hence determines the target selectivity of human myosin VI. The presence of the α2-linker structurally defines a new clathrin-binding domain that is unique to myosin VI(long) and masks the known RRL interaction motif. This finding is relevant to ovarian cancer, in which alternative myosin VI splicing is aberrantly regulated, and exon skipping dictates cell addiction to myosin VI(short) in tumor-cell migration. The RRL interactor optineurin contributes to this process by selectively binding myosin VI(short). Thus, the α2-linker acts like a molecular switch that assigns myosin VI to distinct endocytic (myosin VI(long)) or migratory (myosin VI(short)) functional roles.

  7. Parameters of Solidifying Mixtures Transporting at Underground Ore Mining

    Directory of Open Access Journals (Sweden)

    Golik Vladimir

    2017-01-01

    Full Text Available The article is devoted to the problem of providing mining enterprises with solidifying filling mixtures at underground mining. The results of analytical studies using the data of foreign and domestic practice of solidifying mixtures delivery to stopes are given. On the basis of experimental practice the parameters of transportation of solidifying filling mixtures are given with an increase in their quality due to the effect of vibration in the pipeline. The mechanism of the delivery process and the procedure for determining the parameters of the forced oscillations of the pipeline, the characteristics of the transporting processes, the rigidity of the elastic elements of pipeline section supports and the magnitude of vibrator’ driving force are detailed. It is determined that the quality of solidifying filling mixtures can be increased due to the rational use of technical resources during the transportation of mixtures, and as a result the mixtures are characterized by a more even distribution of the aggregate. The algorithm for calculating the parameters of the pipe vibro-transport of solidifying filling mixtures can be in demand in the design of mineral deposits underground mining technology.

  8. Parameters of Solidifying Mixtures Transporting at Underground Ore Mining

    Science.gov (United States)

    Golik, Vladimir; Dmitrak, Yury

    2017-11-01

    The article is devoted to the problem of providing mining enterprises with solidifying filling mixtures at underground mining. The results of analytical studies using the data of foreign and domestic practice of solidifying mixtures delivery to stopes are given. On the basis of experimental practice the parameters of transportation of solidifying filling mixtures are given with an increase in their quality due to the effect of vibration in the pipeline. The mechanism of the delivery process and the procedure for determining the parameters of the forced oscillations of the pipeline, the characteristics of the transporting processes, the rigidity of the elastic elements of pipeline section supports and the magnitude of vibrator' driving force are detailed. It is determined that the quality of solidifying filling mixtures can be increased due to the rational use of technical resources during the transportation of mixtures, and as a result the mixtures are characterized by a more even distribution of the aggregate. The algorithm for calculating the parameters of the pipe vibro-transport of solidifying filling mixtures can be in demand in the design of mineral deposits underground mining technology.

  9. Underground gas storage in the World - 2013 (fifth Edition)

    International Nuclear Information System (INIS)

    Cornot-Gandolphe, Sylvie

    2013-07-01

    Since its first publication in 1990, 'Underground Gas Storage in the World' has been the industry's reference on underground gas storage (UGS). The updated 2013 edition includes in-depth CEDIGAZ's analyses of the latest developments and trends in the storage industry all over the world as well as extensive country analyses with complete datasets including current, under construction and planned Underground Gas Storage facilities in 48 countries. It describes the 688 existing storage facilities in the world and the 236 projects under construction and planned. Future storage demand and its main drivers are presented at global and regional levels. 'Underground Gas Storage in the World 2013' builds on the CEDIGAZ Underground Gas Storage Database, the only worldwide Underground Gas Storage database to be updated every year. The Survey includes four main parts: The first part gives an overview of underground gas storage in the world at the beginning of 2013 and analyzes future storage needs by 2030, at regional and international levels. The second part focuses on new trends and issues emerging or developing in key storage markets. It analyzes the emerging storage market in China, reviews the storage business climate in Europe, examines Gazprom's storage strategy in Europe, and reviews recent trends in storage development in the United States. The third part gives some fundamental background on technical, economic and regulatory aspects of gas storage. The fourth part gives a countrywide analysis of the 48 countries in the world holding underground gas storage facilities or planning storage projects. 48 countries surveyed, 688 existing UGS facilities, 256 projects under construction or planned. The document includes 70 tables, 72 charts and figures, 44 country maps. The countries surveyed are: Europe : Albania, Austria, Belgium, Bosnia, Bulgaria, Croatia, Czech Republic, Denmark, France, Germany, Greece, Hungary, Ireland, Italy, Latvia, Lithuania, Netherlands, Poland

  10. Location of leaks in pressurized underground pipelines

    International Nuclear Information System (INIS)

    Eckert, E.G.; Maresca, J.W. Jr.

    1993-01-01

    Millions of underground storage tanks (UST) are used to store petroleum and other chemicals. The pressurized underground pipelines associated with USTs containing petroleum motor fuels are typically 2 in. in diameter and 50 to 200 ft in length. These pipelines typically operate at pressures of 20 to 30 psi. Longer lines, with diameters up to 4 in., are found in some high-volume facilities. There are many systems that can be used to detect leaks in pressurized underground pipelines. When a leak is detected, the first step in the remediation process is to find its location. Passive-acoustic measurements, combined with advanced signal-processing techniques, provide a nondestructive method of leak location that is accurate and relatively simple, and that can be applied to a wide variety of pipelines and pipeline products

  11. The reduction of Np(VI) and Pu(VI) by organic chelating agents

    International Nuclear Information System (INIS)

    Reed, D.T.; Aase, S.B.; Banaszak, J.E.

    1998-01-01

    The reduction of NpO 2+ and PuO 2 2+ by oxalate. citrate, and ethylenediaminetetraacetic acid (EDTA) was investigated in low ionic strength media and brines. This was done to help establish the stability of the An(VI) oxidation state in the presence of organic complexants. The stability of the An(VI) oxidation state depended on the pH and relative strength of the various oxidation state-specific complexes. At low ionic strength and pH 6, NpO 2 O 2+ was rapidly reduced to form NpO 2 + organic complexes. At longer times, Np(IV) organic complexes were observed in the presence of citrate. PuO 2 2+ was predominantly reduced to Pu 4+ , resulting in the formation of organic complexes or polymeric/hydrolytic precipitates. The relative rates of reduction to the An(V) complex were EDTA > citrate > oxalate. Subsequent reduction to An(IV) complexes, however, occurred in the following order: citrate > EDTA > oxalate because of the stability of the An(V)-EDTA complex. The presence of organic complexants led to the rapid reduction of NpO 2 2+ and PuO 2 P 2+ in G-seep brine at pHs 5 and 7. At pHs 8 and 10 in ERDA-6 brine, carbonate and hydrolytic complexes predominated and slowed down or prevented the reduction of An(VI) by the organics present

  12. Final report on the surface-based investigation (phase 1) at the Mizunami Underground Laboratory project

    International Nuclear Information System (INIS)

    Saegusa, Hiromitsu; Seno, Yasuhiro; Nakama, Shigeo; Tsuruta, Tadahiko; Amano, Kenji; Takeuchi, Ryuji; Matsuoka, Toshiyuki; Onoe, Hironori; Mizuno, Takashi; Ohyama, Takuya; Hama, Katsuhiro; Sato, Toshinori; Kuji, Masayoshi; Kuroda, Hidetaka; Semba, Takeshi; Uchida, Masahiro; Sugihara, Kozo; Sakamaki, Masanori; Iwatsuki, Teruki

    2007-03-01

    The Mizunami Underground Laboratory (MIU) Project is a comprehensive research project investigating the deep underground environment within crystalline rock being conducted by Japan Atomic Energy Agency at Mizunami City in Gifu Prefecture, central Japan and its role is defined in 'Framework for Nuclear Energy Policy' by Japan Atomic Energy Commission. The MIU Project has three overlapping phases: Surface-based Investigation phase (Phase I), Construction phase (Phase II), and Operation phase (Phase III), with a total duration of 20 years. The overall project goals of the MIU Project from Phase I through to Phase III are: 1) to establish techniques for investigation, analysis and assessment of the deep geological environment, and 2) to develop a range of engineering for deep underground application. During Phase I, the overall project goals were supported by Phase I goals. For the overall project goals 1), the Phase I goals were set to construct models of the geological environment from all surface-based investigation results that describe the geological environment prior to excavation and predict excavation response. For the overall project goals 2), the Phase I goals were set to formulate detailed design concepts and a construction plan for the underground facilities. This report summarizes the Phase I investigation which was completed in March 2005. The authors believe this report will make an important milestone, since this report clarifies how the Phase I goals are achieved and evaluate the future issues thereby direct the research which will be conducted during Phase II. With regard to the overall project goals 1), 'To establish techniques for investigation, analysis and assessment of the deep geological environment,' a step-wise investigation was conducted by iterating investigation, interpretation, and assessment, thereby understanding of geologic environment was progressively and effectively improved with progress of investigation. An optimal procedure from

  13. Contribution to the study of the redox couple Np(VI)/Np(V) in the presence of uranium(VI) in solutions of nitric acid and nitrous acid; Contribution a l'etude du comportement redox du couple Np(VI)/Np(V) en presence d'uranium VI dans les solutions constituees d'acide nitrique et d'acide nitreux

    Energy Technology Data Exchange (ETDEWEB)

    Arpigny, S. [CEA Marcoule, Dept. de Radiochimie et Procedes, DRP, 30 (France)

    2001-07-01

    The redox behavior of the Np(VI)/Np(V) couple was the subject of a spectrometric study of the Np(VI) reduction reaction in nitric acid solutions (4 to 5 M) containing variable concentrations (1.5 to 3.5 x 10{sup -3} M) of nitrous acid. A low nitrous acid concentration and a high nitric acid concentration were found to favor the stabilization of Np(VI). The stoichiometric coefficients of nitrous acid and nitric acid in the Np(VI) reduction reaction were determined thermodynamically, although only the reaction order with respect to HNO{sub 2} could be calculated from a kinetic analysis. Adding nitrate ions to a HNO{sub 3}/HNO{sub 2} solution enhanced the stability of neptunium at oxidation state +VI, but also increased the reduction rate. When uranium(VI) was added to the HNO{sub 3}/HNO{sub 2} solutions, the total quantity of neptunium at oxidation state +V (either free or as a Np(V)-U(VI) complex) remained practically unchanged, as did the Np(VI) reduction rate. The electrochemical behavior of the Np(VI)/Np(V) couple was investigated in a weak acidic medium by voltammetry with an ultra-micro-electrode (UME). The oxidation wave limiting current variation was a linear function of the Np(V) concentration when a gold UME was used, but not with a platinum UME; the reduction wave limiting current variation versus the Np(V) concentration was linear with either gold or platinum UMEs. The presence of the Np(V)-U(VI) complex in the neptunium solutions was characterized by a shift in the normal apparent potential of the Np(VI)/Np(V) couple toward anodic potentials consistent with the previously determined values of the complexation constants. (author)

  14. Evaluation of the effects of underground water usage and spillage in the Exploratory Studies Facility

    International Nuclear Information System (INIS)

    Dunn, E.; Sobolik, S.R.

    1993-12-01

    The Yucca Mountain Site Characterization Project is studying Yucca Mountain in southwestern Nevada as a potential site for a high-level radioactive waste repository. Analyses reported herein were performed to support the design of site characterization activities so that these activities will have a minimal impact on the ability of the site to isolate waste and a minimal impact on underground tests performed as part of the characterization process. These analyses examine the effect of water to be used in the underground construction and testing activities for the Exploratory Studies Facility on in situ conditions. Underground activities and events where water will be used include construction, expected but unplanned spills, and fire protection. The models used predict that, if the current requirements in the Exploratory Studies Facility Design Requirements are observed, water that is imbibed into the tunnel wall rock in the Topopah Springs welded tuff can be removed over the preclosure time period by routine or corrective ventilation, and also that water imbibed into the Paintbrush Tuff nonwelded tuff will not reach the potential waste storage area

  15. Physics of multiple muons in underground detectors

    International Nuclear Information System (INIS)

    Gaisser, T.K.; Stanev, T.

    1982-01-01

    We summarize results of Monte Carlo simulations of underground muons with a set of parametrizations for number and lateral distribution of muons at various detector depths. We also describe the size distributions of accompanying showers at the surface. We give some illustrations of the use of these results to study the surface-underground correlation and to interpret preliminary results of the Soudan-I detector presented at this conference

  16. Zero-valent iron particles embedded on the mesoporous silica–carbon for chromium (VI) removal from aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Xiong, Kun, E-mail: kunxiong312@gmail.com; Gao, Yuan [Chongqing Technology and Business University, Engineering Research Center for Waste Oil Recovery Technology and Equipment of Ministry of Education, Chongqing Key Laboratory of Catalysis & Environmental New Materials (China); Zhou, Lin [Chengdu Radio and TV University (China); Zhang, Xianming [Chongqing Technology and Business University, Engineering Research Center for Waste Oil Recovery Technology and Equipment of Ministry of Education, Chongqing Key Laboratory of Catalysis & Environmental New Materials (China)

    2016-09-15

    Nanoscale zero-valent iron (nZVI) particles were embedded on the walls of mesoporous silica–carbon (MSC) under the conditions of high-temperature carbonization and reduction and used to remove chromium (VI) from aqueous solution. The structure and textural properties of nZVI–MSC were characterized by the powder X-ray diffraction, transmission electron microscopy and N{sub 2} adsorption and desorption. The results show that nZVI–MSC has highly ordered mesoporous structure and large surface area, indistinguishable with that of MSC. Compared with the support MSC and iron particles supported on the activated carbon (nZVI/AC), nZVI–MSC exhibited much higher Cr(VI) removal efficiency with about 98 %. The removal process obeys a pseudo first-order model. Such excellent performance of nZVI–MSC could be ascribed to the large surface and iron particles embedded on the walls of the MSC, forming an intimate contact with the MSC. It is proposed that this feature might create certain micro-electrode on the interface of iron particles and MSC, which prevented the formation of metal oxide on the surface and provided fresh Fe surface for Cr(VI) removal.

  17. Chromium(VI) generation in vadose zone soils and alluvial sediments of the southwestern Sacramento Valley, California: a potential source of geogenic Cr(VI) to groundwater

    Science.gov (United States)

    Mills, Christopher T.; Morrison, Jean M.; Goldhaber, Martin B.; Ellefsen, Karl J.

    2011-01-01

    Concentrations of geogenic Cr(VI) in groundwater that exceed the World Health Organization’s maximum contaminant level for drinking water (50 μg L−1) occur in several locations globally. The major mechanism for mobilization of this Cr(VI) at these sites is the weathering of Cr(III) from ultramafic rocks and its subsequent oxidation on Mn oxides. This process may be occurring in the southern Sacramento Valley of California where Cr(VI) concentrations in groundwater can approach or exceed 50 μg L−1. To characterize Cr geochemistry in the area, samples from several soil auger cores (approximately 4 m deep) and drill cores (approximately 25 m deep) were analyzed for total concentrations of 44 major, minor and trace elements, Cr associated with labile Mn and Fe oxides, and Cr(VI). Total concentrations of Cr in these samples ranged from 140 to 2220 mg per kg soil. Between 9 and 70 mg per kg soil was released by selective extractions that target Fe oxides, but essentially no Cr was associated with the abundant reactive Mn oxides (up to ~1000 mg hydroxylamine-reducible Mn per kg soil was present). Both borehole magnetic susceptibility surveys performed at some of the drill core sites and relative differences between Cr released in a 4-acid digestion versus total Cr (lithium metaborate fusion digestion) suggest that the majority of total Cr in the samples is present in refractory chromite minerals transported from ultramafic exposures in the Coast Range Mountains. Chromium(VI) in the samples studied ranged from 0 to 42 μg kg−1, representing a minute fraction of total Cr. Chromium(VI) content was typically below detection in surface soils (top 10 cm) where soil organic matter was high, and increased with increasing depth in the soil auger cores as organic matter decreased. Maximum concentrations of Cr(VI) were up to 3 times greater in the deeper drill core samples than the shallow auger cores. Although Cr(VI) in these vadose zone soils and sediments was only a

  18. Vi behøver innovation

    DEFF Research Database (Denmark)

    McAloone, Tim C.

    2007-01-01

    -Produktion og Maskiner. Innovation og bæredygtighed er to områder som vi i Skandinavien giver meget stor opmærksomhed for at kunne vedligeholde vores globale konkurrencekraft og stærke velfærdssamfund. Gennem årene har mange brancher bidraget til skabelsen af vidensbaserede innovationer, og det faktum, at de......Analyse: Vi behøver innovation En ny miljøbølge ruller, og danske virksomheder bør ride med Af Tim McAloone, fredag 02. feb 2007 kl. 04:50 Tim McAloone Lektor og ph.d. ved Institut for mekanik, energi og konstruktion ved DTU. Tim McAloone skriver fremover jævnligt kommentarer i Ingeniøren...... skandinaviske lande er relativt små, har ledt til en interessant evne til at etablere og derefter samarbejde inden for tætte netværk, som strækker sig over både faglige og geografiske grænser. Samtidig har vi set miljøhensyn vinde og tabe samfundsmæssig og industriel opmærksomhed på en nærmest periodisk basis...

  19. Thermodynamic analysis of Cr(VI) extraction using TOPO impregnated membranes

    Energy Technology Data Exchange (ETDEWEB)

    Praveen, Prashant; Loh, Kai-Chee, E-mail: chelohkc@nus.edu.sg

    2016-08-15

    Highlights: • Cr(VI) extraction by extractant impregnated membranes (EIM) was investigated. • EIM exhibited high extraction efficiency, mass transfer rate and stability. • Mass transfer mechanism was proposed based on kinetics and equilibrium data. • Uptake of Cr(VI) by EIMs was endothermic and spontaneous. • Cr(VI) extraction by EIMs was dominated by physical interactions. - Abstract: Solid/liquid extraction of Cr(VI) was accomplished using trioctylphosphine oxide impregnated polypropylene hollow fiber membranes. Extraction of 100–500 mg/L Cr(VI) by the extractant impregnated membranes (EIM) was characterized by high uptake rate and capacity, and equilibrium was attained within 45 min of contact. Extraction equilibrium was pH-dependent (at an optimal pH 2), whereas stripping using 0.2 M sodium hydroxide yielded the highest recovery of 98% within 60 min. The distribution coefficient was independent of initial Cr(VI) concentration, and the linear distribution equilibrium isotherm could be modeled using Freundlich isotherm. The mass transfer kinetics of Cr(VI) was examined using pseudo-second-order and intraparticle diffusion models and a mass transfer mechanism was deduced. The distribution coefficient increased with temperature, which indicated endothermic nature of the reaction. Enthalpy and entropy change during Cr(VI) extraction were positive and varied in the range of 37–49 kJ/mol and 114–155 J/mol, respectively. The free energy change was negative, confirming the feasibility and spontaneity of the mass transfer process. Results obtained suggest that EIMs are efficient and sustainable for extraction of Cr(VI) from wastewater.

  20. Organ nic pollutants in underground water

    International Nuclear Information System (INIS)

    Hussein, H. H.

    1998-01-01

    Many organic compounds have been diagnosed in underground and surface waters, and there are many theories that explain the source of the dangerous materials on Punic health. The source of pollution could be the underground stored fuel or the polluted water in farms saturated with agricultural insecticides and chemical fertilizers, or there could be leaks in sewage water wastes. The source of pollution could also be the water surfaces in the areas of garbage disposal or industrial and home waste discharge. Due to the fact that the underground water is separated from oxygen in the air, its ability on self-purification is very low, in that the micro-organism that will do the dismantling and decomposition of the organic materials that pollute the water are in need for oxygen. In the event that underground water is subject to pollution m there are many methods for t resting the polluted water including the chemical decomposition method by injecting the polluted areas with neutralizing or oxidizing chemicals, such as Ozone, Chlorine or Hydrogen Peroxide. The mechanical methods could be used for getting rid of the volatile organic materials. As to biological decomposition, it is done with the use of bacteria in dismantling the poisonous materials into un poisonous materials. The preliminary analysis of water samples in one of the water wells in Sar ir and Tazarbo in Great Jamahirieh indicated that the concentration of total organic compounds (TOC) exceeded the internationally allowed limits. This indicates a deterioration of quality of some of underground water resources. It is well known that some of the organic pollutants have a great role in causing dangerous diseases, such as the polynuclear aromatic hydrocarbons and some halogenated compounds that cause cancer. Therefore, much research is required in this field for diagnosing the polluting organic compounds and determining the suitability of this water for drinking or for human consumption. (author). 21 refs., 6 figs

  1. Potential Advantages of Underground Nuclear Parks

    International Nuclear Information System (INIS)

    Myers, Carl W.; Elkins, Ned Z.; Kunze, Jay F.; Mahar, James M.

    2006-01-01

    In this paper we argue that an underground nuclear park (UNP) could potentially lead to lower capital and operating cost for the reactors installed in the UNP compared to the traditional approach, which would be to site the reactors at the earth's surface at distributed locations. The UNP approach could also lead to lower waste management cost. A secondary benefit would be the increased margins of safety and security that would be realized simply as a consequence of siting the reactors underground. Lowered capital and operating cost for a UNP relative to traditional reactor siting is possible through the aggregate effect of the elimination of containment structures, in-place decommissioning, reduced physical security costs, reduced weather-related costs, reduced cost of liability insurance and reduced unit-cost for the nth reactor made possible through the continuous construction of multiple reactors at the same underground location. Other cost reductions might be possible through the transfer of the capital cost for part of the underground construction from the reactor owners to the owners of the UNP. Lower waste management cost is possible by siting the UNP at a location where there are geological and hydrological conditions suitable for hosting both the reactors and the repository for the waste from those reactors. After adequate storage and cooling, and assuming direct disposal, this would enable the spent fuel from the reactors to be transported directly to the repository and remain entirely underground during the transport process. Community concerns and transportation costs would be significantly reduced relative to current situations where the reactors are separated from the repository by long distances and populated areas. The concept for a UNP in bedded salt is used to develop a rough order of magnitude cost estimate for excavation of the reactor array portion of a UNP. Excavation costs appear to be only a small fraction of the overall power plant costs

  2. The Underground Economy and Tax Evasion in Pakistan. A Fresh Assessment

    OpenAIRE

    Zafar Iqbal; Sarfraz Khan Qureshi; Riaz Mahmood

    1998-01-01

    This paper assesses the size of the underground ~conomy and tax evasion in Pakistan for the period 1973-96. Using monetary approach, the results confirm the existence of large underground economy and higher tax evasion over the period under analysis. The overall underground economy has remarkably increased from 20 percent of GDP in 1973 to 51 percent of GDP in 1996. The evidence also suggests that the rate of growth in th~ underground economy has been higher than the rate of growth of the for...

  3. Influence of Calcium on Microbial Reduction of Solid Phase Uranium (VI)

    International Nuclear Information System (INIS)

    Liu, Chongxuan; Jeon, Byong-Hun; Zachara, John M.; Wang, Zheming

    2007-01-01

    The effect of calcium on microbial reduction of a solid phase U(VI), sodium boltwoodite (NaUO2SiO3OH · 1.5H2O), was evaluated in a culture of a dissimilatory metal-reducing bacterium (DMRB), Shewanella oneidensis strain MR-1. Batch experiments were performed in a non-growth bicarbonate medium with lactate as electron donor at pH 7 buffered with PIPES. Calcium increased both the rate and extent of Na-boltwoodite dissolution by increasing its solubility through the formation of a ternary aqueous calcium-uranyl-carbonate species. The ternary species, however, decreased the rates of microbial reduction of aqueous U(VI). Laser-induced fluorescence spectroscopy (LIFS) and transmission electron microscopy (TEM) revealed that microbial reduction of solid phase U(VI) is a sequentially coupled process of Na-boltwoodite dissolution, U(VI) aqueous speciation, and microbial reduction of dissolved U(VI) to U(IV) that accumulated on bacterial surfaces/periplasm. The overall rates of microbial reduction of solid phase U(VI) can be described by the coupled rates of dissolution and microbial reduction that were both influenced by calcium. The results demonstrated that dissolved U(VI) concentration during microbial reduction was a complex function of solid phase U(VI) dissolution kinetics, aqueous U(VI) speciation, and microbial activity

  4. 30 CFR 75.213 - Roof support removal.

    Science.gov (United States)

    2010-07-01

    ... mining experience shall perform permanent roof support removal work. (b) Prior to the removal of... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Roof support removal. 75.213 Section 75.213... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Roof Support § 75.213 Roof support removal. (a)(1) All...

  5. A simple Cr(VI)–S(IV)–O{sub 2} system for rapid and simultaneous reduction of Cr(VI) and oxidative degradation of organic pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, Yanan; Yang, Shaojie [Department of Environmental Science, Hubei Key Lab of Biomass Resource Chemistry and Environmental Biotechnology, School of Resources and Environmental Science, Wuhan University, 430079 (China); Zhou, Danna, E-mail: zdncug@163.com [Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074 (China); Wu, Feng [Department of Environmental Science, Hubei Key Lab of Biomass Resource Chemistry and Environmental Biotechnology, School of Resources and Environmental Science, Wuhan University, 430079 (China)

    2016-04-15

    Highlights: • Rapid and simultaneous reduction of Cr(VI) and degradation of organic pollutants occur. • Oxysulfur radicals generated in Cr(VI)–S(IV)–O{sub 2} system oxidize the organic pollutants. • Acidic pH facilitates the reactions from both directions of reduction and oxidation. • Degradation potential of aromatic amines depends on the substituted groups. • Cr(VI)–S(IV)–O{sub 2} system is promising for “waste control by waste”. - Abstract: Hexavalent chromium (Cr(VI)), a heavy-metal contaminant, can be easily reduced to less toxic trivalent chromium (Cr(III)) by sulfite ions (S(IV)). However, S(IV) has not drawn as much attention as the ferrous ion has. We report herein a novel Cr(VI)–S(IV)–O{sub 2} system containing sulfite ions that rapidly and simultaneously reduces Cr(VI) and oxidize organic pollutants in the presence of oxygen in aqueous solutions. This Cr(VI)–S(IV)-O{sub 2} system contains the initiator Cr(VI), the reductant S(IV), and the oxidant O{sub 2}, which produce oxysulfur radicals (mainly SO{sub 4}·{sup −} and SO{sub 5}·{sup −}) and hydroxyl radicals (OH·). The Cr(VI)/S(IV) molar ratio, pH, and oxygen content play important roles in the entire reaction system. Acidic conditions (pH 3.0) facilitated degradation of organic compounds and reduction of Cr(VI) as well. In addition, experiments of rapid degradation of several kinds of organic pollutants such as azo dye (acid orange 7, AO7), aniline, phenol, bisphenol A etc were also conducted. Preliminary results show that the removal rates of the analogs of phenols or aromatic amines in this Cr(VI)–S(IV)–O{sub 2} system have a relationship with the electronic parameters (Hammett constant, σ) of the substituted groups. Thus, the Cr(VI)–S(IV)–O{sub 2} system, provides an excellent strategy of “waste control by waste” for removing multiple industrial contaminants.

  6. Underground storage of carbon dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, Shoichi [Univ. of Tokyo, Hongo, Bunkyo-ku (Japan)

    1993-12-31

    Desk studies on underground storage of CO{sub 2} were carried out from 1990 to 1991 fiscal years by two organizations under contract with New Energy and Indestrial Technology Development Organization (NEDO). One group put emphasis on application of CO{sub 2} EOR (enhanced oil recovery), and the other covered various aspects of underground storage system. CO{sub 2} EOR is a popular EOR method in U.S. and some oil countries. At present, CO{sub 2} is supplied from natural CO{sub 2} reservoirs. Possible use of CO{sub 2} derived from fixed sources of industries is a main target of the study in order to increase oil recovery and storage CO{sub 2} under ground. The feasibility study of the total system estimates capacity of storage of CO{sub 2} as around 60 Gton CO{sub 2}, if worldwide application are realized. There exist huge volumes of underground aquifers which are not utilized usually because of high salinity. The deep aquifers can contain large amount of CO{sub 2} in form of compressed state, liquefied state or solution to aquifer. A preliminary technical and economical survey on the system suggests favorable results of 320 Gton CO{sub 2} potential. Technical problems are discussed through these studies, and economical aspects are also evaluated.

  7. International activities concerning seismic effects on underground structures

    International Nuclear Information System (INIS)

    Hakala, W.W.

    1982-01-01

    At the 5th Annual Meeting of the ITA in Atlanta, Georgia, on June 15-17, 1979, the General Assembly approved the formation of the Working Group Seismic Effects on Underground Structures. The objectives of this Working Group are to: (1) collect data on earthquake damage to underground facilities throughout the world; (2) collect information on aseismic design procedures used within the various countries; and (3) synthesize the information and disseminate the results to the member nations of ITA. William W. Hakala of the US was designated the Animateur of the Working Group. The Working Group decided on the following sequential course of action to achieve the stated objectives: (1) continue to develop a bibliograhy on damages to underground structures by dynamic forces. This will be an ongoing activity of the Working Group; (2) each country is to develop a summary of case histories of earthquake damage to underground structures. These case histories will be discussed at the next meeting of the Working Group in order to identify those parameters that permit or prevent such damage; (3) the state-of-the-art paper on earthquake damage to underground opening being prepared in the US (John A. Blume and Associates, Engineers) is presently being printed and will then be distributed to the membership for comment. This report will form the basis for the activities described below; (4) the above activities should lead to a textbook - like document that provides a design philosophy for underground structures subjected to seismic forces; (5) the work tasks will suggest needed research to solve the identified problems. At each Working Group meeting the member nation delegates will provide a summary of research progress in their countries. These research needs will be documented, reviewed, revised, and disseminated on an annual basis

  8. Reducing lighting electricity use in underground metro stations

    International Nuclear Information System (INIS)

    Casals, Miquel; Gangolells, Marta; Forcada, Núria; Macarulla, Marcel

    2016-01-01

    Highlights: • Lighting systems are big energy consumers in underground metro stations. • An adaptive lighting system strategy is developed for underground stations. • Dimming controls are based on station occupancy levels and maintenance cycles. • The k-means clustering technique is used to identify stations’ occupancy patterns. • Savings were found to amount to 255.47 MW h in 2 years for a case study metro network. - Abstract: Lighting systems are usually one of the largest electrical end-uses in underground metro stations. Taking into account that budget restrictions in publicly owned companies hinder energy efficiency retrofit projects that require high initial investments, affordable energy saving strategies are needed. This paper presents a low-cost approach for reducing lighting electricity use in underground stations, without affecting passengers’ comfort or the metro operator’s service. For this purpose, an adaptive lighting strategy of dimming the illuminance levels of artificial light sources has been developed. Dimming controls are based on the occupancy of the station, and the preventive maintenance and cleaning cycles of the luminaires. The stations’ monthly occupancy patterns are defined through the k-means clustering technique. To illustrate its effectiveness, the method was applied to 115 underground stations of the Barcelona metro network. The results revealed overall electricity savings of 255.47 MW h on a biannual basis, which represents 36.22% of the stations’ baseline lighting consumption. Individual energy savings were found to range from 25 to 87.5 MW h/year in the stations of the Barcelona metro network, depending on the number and profile of station users. The research findings will undoubtedly be useful for the future energy efficiency project plans of worldwide metro operators and managers of other underground spaces.

  9. Applications of radio frequency identification systems in underground mining

    Energy Technology Data Exchange (ETDEWEB)

    Knights, P F; Kairouz, J; Daneshmend, L K; Pathak, J [McGill University, Montreal, PQ (Canada). Canadian Centre for Automation and Robotics in Mining

    1994-12-31

    The paper describes the application of Radio Frequency Identification (RFID) systems in underground hardrock mines. The operating principles and some of the applications of RDIF systems are described. The system operates by the exchange of information between transponder tags and an antenna and controller device. The suitability of RFID systems for process control, inventory control, materials handling, control of access, security, and transportation in underground coal and hardrock mines is discussed. An ore tonnage tracking system is under development that uses RDIF transponder tags to locate vehicles in an underground mine. 6 refs., 4 figs.

  10. 77 FR 64399 - Order of Succession for HUD Region VI

    Science.gov (United States)

    2012-10-19

    ... Region VI AGENCY: Office of Field Policy and Management, HUD. ACTION: Notice of Order of Succession... its Field Offices (Region VI). This Order of Succession supersedes all previous Orders of Succession for HUD Region VI. DATES: Effective Date: October 9, 2012. FOR FURTHER INFORMATION CONTACT: Lawrence D...

  11. SuperCDMS Underground Detector Fabrication Facility

    Energy Technology Data Exchange (ETDEWEB)

    Platt, M.; Mahapatra, R.; Bunker, Raymond A.; Orrell, John L.

    2018-03-01

    The SuperCDMS SNOLAB dark matter experiment processes Ge and Si crystals into fully tested phonon and ionization detectors at surface fabrication and test facilities. If not mitigated, it is anticipated that trace-level production of radioisotopes in the crystals due to exposure to cosmic rays at (or above) sea level will result in the dominant source of background events in future dark matter searches using the current SuperCDMS detector technology. Fabrication and testing of detectors in underground facilities shielded from cosmic radiation is one way to directly reduce production of trace levels of radioisotopes, thereby improving experimental sensitivity for the discovery of dark matter beyond the level of the current experiment. In this report, we investigate the cost and feasibility to establish a complete detector fabrication processing chain in an underground location to mitigate cosmogenic activation of the Ge and Si detector substrates. For a specific and concrete evaluation, we explore options for such a facility located at SNOLAB, an underground laboratory in Sudbury, Canada hosting the current and future experimental phases of SuperCDMS.

  12. Extraction behavior of uranium(VI) with polyurethane foam

    International Nuclear Information System (INIS)

    Tingchia Huang; Donghwang Chen; Muchang Shieh; Chingtsven Huang

    1992-01-01

    The extraction of uranium(VI) from aqueous solution with polyether-based polyurethane (PU) foam was studied. The effects of the kinds and concentrations of nitrate salts, uranium(VI) concentration, temperature, nitric acid concentration, pH, the content of poly(ethylene oxide) in the polyurethane foam, and the ratio of PU foam weight and solution volume on the extraction of uranium(VI) were investigated. The interferences of fluoride and carbonate ions on the extraction of uranium(VI) were also examined, and methods to overcome both interferences were suggested. It was found that no uranium was extracted in the absence of a nitrate salting-out agent, and the extraction behaviors of uranium(IV) with polyurethane foam could be explained in terms of an etherlike solvent extraction mechanism. In addition, the percentage extraction of a multiple stage was also estimated theoretically

  13. The underground storages of carbon dioxide. Juridical aspects

    International Nuclear Information System (INIS)

    Bersani, F.

    2006-04-01

    In the framework of the reduction of the carbon dioxide emissions in the air, the underground storage of the CO 2 is studied. Some experimentation are already realized in the world and envisaged in France. This document aims to study the juridical aspects of these first works in France. After a presentation of the realization conditions and some recalls on the carbon dioxide its capture and storage, the natural CO 2 underground storages and the first artificial storages are discussed. The CO 2 waste qualification, in the framework of the environmental legislation is then detailed with a special task on the Lacq region. The problem of the sea underground storages is also presented. (A.L.B.)

  14. 30 CFR 75.313 - Main mine fan stoppage with persons underground.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Main mine fan stoppage with persons underground... mine fan stoppage with persons underground. (a) If a main mine fan stops while anyone is underground and the ventilating quantity provided by the fan is not maintained by a back-up fan system— (1...

  15. Horonobe Underground Research Laboratory project. Plans of investigations during shaft and drift excavation (Construction of underground facilities: Phase II)

    International Nuclear Information System (INIS)

    2005-06-01

    Horonobe Underground Research Laboratory Project is planned for over 20 years to establish the scientific and technical basis for the underground disposal of high-level radioactive wastes in Japan. The investigations are conducted by JNC in three phases, from the surface (Phase I), during the construction of the underground facilities (Phase II), and using the facilities (Phase III). This report concerns the investigation plans for Phase II. During excavation of shafts and drifts, detailed geological and borehole investigation will be conducted and the geological model constructed in Phase I is evaluated and revised by newly acquired data of geophysical and geological environment. Detailed in-situ experiments, as well as the effects of shaft excavation, are also done to study long-term changes, rock properties, groundwater flow and chemistry to ensure the reliability of repository technology and establish safety assessment methodology. (S. Ohno)

  16. Network-level architecture and the evolutionary potential of underground metabolism.

    Science.gov (United States)

    Notebaart, Richard A; Szappanos, Balázs; Kintses, Bálint; Pál, Ferenc; Györkei, Ádám; Bogos, Balázs; Lázár, Viktória; Spohn, Réka; Csörgő, Bálint; Wagner, Allon; Ruppin, Eytan; Pál, Csaba; Papp, Balázs

    2014-08-12

    A central unresolved issue in evolutionary biology is how metabolic innovations emerge. Low-level enzymatic side activities are frequent and can potentially be recruited for new biochemical functions. However, the role of such underground reactions in adaptation toward novel environments has remained largely unknown and out of reach of computational predictions, not least because these issues demand analyses at the level of the entire metabolic network. Here, we provide a comprehensive computational model of the underground metabolism in Escherichia coli. Most underground reactions are not isolated and 45% of them can be fully wired into the existing network and form novel pathways that produce key precursors for cell growth. This observation allowed us to conduct an integrated genome-wide in silico and experimental survey to characterize the evolutionary potential of E. coli to adapt to hundreds of nutrient conditions. We revealed that underground reactions allow growth in new environments when their activity is increased. We estimate that at least ∼20% of the underground reactions that can be connected to the existing network confer a fitness advantage under specific environments. Moreover, our results demonstrate that the genetic basis of evolutionary adaptations via underground metabolism is computationally predictable. The approach used here has potential for various application areas from bioengineering to medical genetics.

  17. Vi-CRM 197 as a new conjugate vaccine against Salmonella Typhi.

    Science.gov (United States)

    Micoli, F; Rondini, S; Pisoni, I; Proietti, D; Berti, F; Costantino, P; Rappuoli, R; Szu, S; Saul, A; Martin, L B

    2011-01-17

    An efficacious, low cost vaccine against typhoid fever, especially for young children, would make a major impact on disease burden in developing countries. The virulence capsular polysaccharide of Salmonella Typhi (Vi) coupled to recombinant mutant Pseudomonas aeruginosa exoprotein A (Vi-rEPA) has been shown to be highly efficacious. We investigated the use of carrier proteins included in infant vaccines, standardized the conjugation process and developed key assays required for routine lot release at production scale. Vi from a BSL1 organism, Citrobacter freundii, strain WR7011, was used as an alternative to Vi from S. Typhi. We showed that Vi conjugated to CRM(197), a non-toxic mutant of diphtheria toxin, widely used in commercial vaccines, was produced at high yield. Vi-CRM(197) proved immunogenic in animal studies, even without adjuvant. Thus, Vi-CRM(197) appears to be a suitable candidate for the development of a commercially viable, effective typhoid vaccine for developing countries. Copyright © 2010 Elsevier Ltd. All rights reserved.

  18. The adsorption ability of Cr(VI) on sawdust–polyaniline nanocomposite

    International Nuclear Information System (INIS)

    Binh Phan, Thi; Que Do, Ngoc; Thanh Thuy Mai, Thi

    2010-01-01

    The results of this study of sawdust–polyaniline nanocomposite synthesized by a chemical method for Cr(VI) treatment in the environment are presented. Cr(VI) adsorption on a composite was determined by colorimetry. The results showed that sawdust–polyaniline composite synthesized with an aniline:sawdust ratio equal to 0.5 had an adsorption degree of 21.4 mg g −1 and adsorbed nearly 99% of the Cr(VI) after 2 h. The composite could be used for the adsorption of Cr(VI) from waste water. The Cr(VI) adsorption ability of the composite slightly depends on the pH value of the medium. The adsorption is fast during the first half hour and then the rate decreases

  19. 30 CFR 57.3360 - Ground support use.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Ground support use. 57.3360 Section 57.3360... and Support-Underground Only § 57.3360 Ground support use. Ground support shall be used where ground conditions, or mining experience in similar ground conditions in the mine, indicate that it is necessary...

  20. Testing of ENDF/B-VI data for shielding applications

    International Nuclear Information System (INIS)

    Ingersoll, D.T.

    1995-01-01

    Version VI of the U.S. Evaluated Nuclear Data File (END/B-VI) was released for open distribution in 1990 after an extensive multiyear, multilaboratory evaluation effort coordinated by the Cross Section Evaluation Working Group (CSEWG). More than 75 of the 320 evaluations contained in the library are new for Version VI, including many relatively important nuclides and many with substantial changes to the cross-section data. Also, several important changes were made to the basic data formats for Version VI to permit better representation of the data and to allow additional types of data. Although these format changes yielded improved evaluations, they hindered processing of the data for use in applications codes and delayed the timely integral testing of the data. It has been only during the past year that significant integral testing of END/B-VI data has been achieved. The results and conclusions from some of these efforts are summarized in the following paragraphs

  1. An empirical study of the underground economy in the Kingdom of Belgium

    DEFF Research Database (Denmark)

    Rezaei, Shahamak; Goli, Marco; Dana, Léo-Paul

    2013-01-01

    This article investigates the underground economy in Belgium. Although several government initiatives are attempting to combat underground economic activities, we found illegal foreign workers identifying opportunities and fulfilling market needs. Underground employment thus thrives in a variety...

  2. Photoreduction of chromium(VI) in the presence of algae, Chlorella vulgaris

    International Nuclear Information System (INIS)

    Deng Lin; Wang Hongli; Deng Nansheng

    2006-01-01

    In this thesis, the photochemical reduction of hexavalent chromium Cr(VI) in the presence of algae, Chlorella vulgaris, was investigated under the irradiation of metal halide lamps (λ=365nm, 250W). The affecting factors of photochemical reduction were studied in detail, such as exposure time, initial Cr(VI) concentration, initial algae concentration and pH. The rate of Cr(VI) photochemical reduction increased with algae concentration increasing, exposure time increasing, initial Cr(VI) concentration decreasing and the decrease of pH. When pH increased to 6, the rate of Cr(VI) photochemical reduction nearly vanished. When initial Cr(VI) concentration ranged from 0.4 to 1.0mgL -1 and initial algae concentration ranged from ABS algae (the absorbency of algae)=0.025 to ABS algae =0.180, According to the results of kinetic analyses, the kinetic equation of Cr(VI) photochemical reduction in aqueous solution with algae under 250W metal halide lamps was V 0 =kC 0 0.1718 A algae 0.5235 (C 0 was initial concentration of Cr(VI); A algae was initial concentration of algae) under the condition of pH 4

  3. Design Criteria for Wireless Mesh Communications in Underground Coal Mines

    OpenAIRE

    Griffin, Kenneth Reed

    2009-01-01

    The Mine Improvement and New Emergency Response (MINER) Act of 2006 was enacted in response to several coal mining accidents that occurred in the beginning of 2006. The MINER Act does not just require underground mines to integrate wireless communication and tracking systems, but aims to overall enhance health and safety in mining at both surface and underground operations. In 2006, the underground communication technologies available to the mining industry had inherent problems that limited ...

  4. 76 FR 51970 - Agency Information Collection Activities; Proposed Collection; Comment Request; Underground...

    Science.gov (United States)

    2011-08-19

    ... Underground Injection Control (UIC) Program under the Safe Drinking Water Act established a Federal and State... Activities; Proposed Collection; Comment Request; Underground Injection Control (UIC) Program AGENCY... Water Protection Division/Underground Injection Control Program, Mailcode: 4606M, Environmental...

  5. Magneto-Inductive Underground Communications in a District Heating System

    DEFF Research Database (Denmark)

    Meybodi, Soroush Afkhami; Nielsen, Jens Frederik Dalsgaard; Bendtsen, Jan Dimon

    2011-01-01

    Feasibility of underground data communications is investigated by employing magnetic induction as the key technology at physical layer. Realizing an underground wireless sensor network for a district heating plant motivates this research problem. The main contribution of the paper is to find the ...

  6. Earthquake damage to underground facilities and earthquake related displacement fields

    International Nuclear Information System (INIS)

    Pratt, H.R.; Stephenson, D.E.; Zandt, G.; Bouchon, M.; Hustrulid, W.A.

    1982-01-01

    The potential seismic risk for an underground facility is considered in the evaluation of its location and design. The possible damage resulting from either large-scale displacements or high accelerations should be considered in evaluating potential sites of underground facilities. Scattered through the available literature are statements to the effect that below a few hundred meters shaking and damage in mines is less than at the surface; however, data for decreased damage underground have not been completely reported or explained. In order to assess the seismic risk for an underground facility, a data base was established and analyzed to evaluate the potential for seismic disturbance. Substantial damage to underground facilities is usually the result of displacements primarily along pre-existing faults and fractures, or at the surface entrance to these facilities. Evidence of this comes from both earthquakes as a function of depth is important in the evaluation of the hazard to underground facilities. To evaluate potential displacements due to seismic effects of block motions along pre-existing or induced fractures, the displacement fields surrounding two types of faults were investigated. Analytical models were used to determine relative displacements of shafts and near-surface displacement of large rock masses. Numerical methods were used to determine the displacement fields associated with pure strike-slip and vertical normal faults. Results are presented as displacements for various fault lengths as a function of depth and distance. This provides input to determine potential displacements in terms of depth and distance for underground facilities, important for assessing potential sites and design parameters

  7. Analysis of benchmark critical experiments with ENDF/B-VI data sets

    International Nuclear Information System (INIS)

    Hardy, J. Jr.; Kahler, A.C.

    1991-01-01

    Several clean critical experiments were analyzed with ENDF/B-VI data to assess the adequacy of the data for U 235 , U 238 and oxygen. These experiments were (1) a set of homogeneous U 235 -H 2 O assemblies spanning a wide range of hydrogen/uranium ratio, and (2) TRX-1, a simple, H 2 O-moderated Bettis lattice of slightly-enriched uranium metal rods. The analyses used the Monte Carlo program RCP01, with explicit three-dimensional geometry and detailed representation of cross sections. For the homogeneous criticals, calculated k crit values for large, thermal assemblies show good agreement with experiment. This supports the evaluated thermal criticality parameters for U 235 . However, for assemblies with smaller H/U ratios, k crit values increase significantly with increasing leakage and flux-spectrum hardness. These trends suggest that leakage is underpredicted and that the resonance eta of the ENDF/B-VI U 235 is too large. For TRX-1, reasonably good agreement is found with measured lattice parameters (reaction-rate ratios). Of primary interest is rho28, the ratio of above-thermal to thermal U 238 capture. Calculated rho28 is 2.3 (± 1.7) % above measurement, suggesting that U 238 resonance capture remains slightly overpredicted with ENDF/B-VI. However, agreement is better than observed with earlier versions of ENDF/B

  8. Cr(III) reactivity and foot dermatitis in Cr(VI) positive patients

    DEFF Research Database (Denmark)

    Hansen, Malene Barré; Menné, Torkil; Johansen, Jeanne Duus

    2006-01-01

    Chromium allergy has become synonymous with Cr(VI) allergy. However, real exposure to chromium from leather products may include both Cr(III) and Cr(VI). In this study, we investigate the reactivity to both Cr(VI) and Cr(III) in consecutive patients to analyse the relation between foot eczema/leather...... to Cr(III). The increased risk was not due to a higher degree of sensitivity to Cr(VI). Leather was reported most frequently as the suspected cause of chromium dermatitis (54%). However, Cr(VI) allergics having foot eczema and positive or doubtful Cr(III) reactions often had positive reactions to other...

  9. System for remote control of underground device

    Science.gov (United States)

    Brumleve, T.D.; Hicks, M.G.; Jones, M.O.

    1975-10-21

    A system is described for remote control of an underground device, particularly a nuclear explosive. The system includes means at the surface of the ground for transmitting a seismic signal sequence through the earth having controlled and predetermined signal characteristics for initiating a selected action in the device. Additional apparatus, located with or adjacent to the underground device, produces electrical signals in response to the seismic signals received and compares these electrical signals with the predetermined signal characteristics.

  10. System for remote control of underground device

    International Nuclear Information System (INIS)

    Brumleve, T.D.; Hicks, M.G.; Jones, M.O.

    1975-01-01

    A system is described for remote control of an underground device, particularly a nuclear explosive. The system includes means at the surface of the ground for transmitting a seismic signal sequence through the earth having controlled and predetermined signal characteristics for initiating a selected action in the device. Additional apparatus, located with or adjacent to the underground device, produces electrical signals in response to the seismic signals received and compares these electrical signals with the predetermined signal characteristics

  11. Radon Progeny in Egyptian Underground Phosphate Mines

    International Nuclear Information System (INIS)

    El-Hady, M.A.; Mohammed, A.; El-Hussein, A.; Ali, A.E.; Ahmed, A.A.

    2001-01-01

    In addition to the workers in uranium mines, the staff of other underground mines, such as workers in underground phosphate mines, can be exposed to 222 Rn and its progeny. In this study the individual radon progeny concentrations were measured in three Egyptian underground phosphate mines to estimate the occupational exposure of the workers at those sites. A filter method was used to measure individual radon progeny concentrations ( 218 Po, 214 Pb and 214 Po). The reported mean values of radon progeny concentrations exceed the action levels which are recommended by ICRP 65 (1993). Based on the measured individual radon progeny concentrations ( 218 Po, 214 Pb and 214 Po) in these mines, the annual effective dose for the workers has been calculated using the lung dose model of ICRP 66 (1994). According to the obtained results, some countermeasures were recommended in this study to minimise these exposure levels. (author)

  12. Underground nuclear astrophysics at the Dresden Felsenkeller

    Energy Technology Data Exchange (ETDEWEB)

    Bemmerer, Daniel; Ilgner, Christoph; Junghans, Arnd R.; Mueller, Stefan; Rimarzig, Bernd; Schwengner, Ronald; Szuecs, Tamas; Wagner, Andreas [Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany); Cowan, Thomas E.; Gohl, Stefan; Grieger, Marcel; Reinicke, Stefan; Roeder, Marko; Schmidt, Konrad; Stoeckel, Klaus; Takacs, Marcell P.; Wagner, Louis [Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany); Technische Universitaet Dresden (Germany); Reinhardt, Tobias P.; Zuber, Kai [Technische Universitaet Dresden (Germany)

    2015-07-01

    Favored by the low background underground, accelerator-based experiments are an important tool to study nuclear astrophysics reactions involving stable charged particles. This technique has been used with great success at the 0.4 MV LUNA accelerator in the Gran Sasso laboratory in Italy. However, the nuclear reactions of helium and carbon burning and the neutron source reactions for the astrophysical s-process require higher beam energies, as well as the continuation of solar fusion studies. As a result, NuPECC strongly recommended the installation of one or more higher-energy underground accelerators. Such a project is underway in Dresden. A 5 MV Pelletron accelerator is currently being refurbished by installing an ion source on the high voltage terminal, enabling intensive helium beams. The preparation of the underground site is funded, and the civil engineering project is being updated. The science case, operational strategy and project status are reported.

  13. An experimental study on the sorption of U(VI) onto granite

    International Nuclear Information System (INIS)

    Baik, Min Hoon; Hahn, Pil Soo

    2002-01-01

    The sorption of U(VI) on a domestic granite is studied as a function of experimental conditions such as contact time, solution-solid ratio, ionic strength, and pH using a batch procedure. The distribution coefficients, K d 's, of U(VI) are about 1-100mL/g depending on the experimental conditions. The sorption of U(VI) onto granite particles is greatly dependent upon the contact time, solution-solid ratio, and pH, but very little is dependent on the ionic strength. It is noticed that an U(VI)-carbonato ternary surface complex can be formed in the neutral range of pH. In the alkaline range of pH above 7, U(VI) sorption onto granite particles is greatly decreased due to the formation of anionic U(VI)-carbonato aqueous complexes

  14. Solvent extraction of W(VI) with malachite green into nitrobenzene

    International Nuclear Information System (INIS)

    Patil, V.B.; Turel, Z.R.

    1995-01-01

    A rapid and selective method has been developed for the extraction of W(VI) with malachite green into nitrobenzene. The effect of various parameters on the extraction coefficient value such as effect of pH, time of equilibration, effect of various cations and anions have been evaluated. The stoichiometry of metal to reagent determined by the method of substoichiometric extraction was found to be 1:1. It was further supported by the slope ratio method. (author). 6 refs., 2 tabs., 2 figs

  15. Solvent extraction of W(VI) with malachite green into nitrobenzene

    Energy Technology Data Exchange (ETDEWEB)

    Patil, V B; Turel, Z R [The Institute of Science, Bombay (India). Nuclear Chemistry Division

    1995-04-01

    A rapid and selective method has been developed for the extraction of W(VI) with malachite green into nitrobenzene. The effect of various parameters on the extraction coefficient value such as effect of pH, time of equilibration, effect of various cations and anions have been evaluated. The stoichiometry of metal to reagent determined by the method of substoichiometric extraction was found to be 1:1. It was further supported by the slope ratio method. (author). 6 refs., 2 tabs., 2 figs.

  16. Simultaneous Cr(VI) bio-reduction and methane production by anaerobic granular sludge.

    Science.gov (United States)

    Hu, Qian; Sun, Jiaji; Sun, Dezhi; Tian, Lan; Ji, Yanan; Qiu, Bin

    2018-08-01

    Wastewater containing toxic hexavalent chromium (Cr(VI)) were treated with well-organized anaerobic granular sludge in this study. Results showed that the anaerobic granular sludge rapidly removed Cr(VI), and 2000 µg·L -1 Cr(VI) was completely eliminated within 6 min, which was much faster than the reported duration of removal by reported artificial materials. Sucrose added as a carbon source acted as an initial electron donor to reduce Cr(VI) to Cr(III). This process was considered as the main mechanism of Cr(VI) removal. Methane production by anaerobic granular sludge was improved by the addition of Cr(VI) at a concentration lower than 500 µg·L -1 . Anaerobic granular sludge had a well-organized structure, which presented good resistance against toxic Cr(VI). Trichoccus accelerated the degradation of organic substances to generate acetates with a low Cr(VI) concentration, thereby enhancing methane production by acetotrophic methanogens. Copyright © 2018 Elsevier Ltd. All rights reserved.

  17. Re-examination of immune response and estimation of anti-Vi IgG protective threshold against typhoid fever-based on the efficacy trial of Vi conjugate in young children.

    Science.gov (United States)

    Szu, Shousun C; Klugman, Keith P; Hunt, Steven

    2014-04-25

    The capsular polysaccharide of Salmonella enterica serovar Typhi, Vi antigen, is an essential virulence factor and a protective antigen. Similar to other polysaccharide vaccines, the protective action of Vi, both to the polysaccharide alone or when presented as a conjugate, is mediated by serum IgG Vi antibodies. The evaluation of Vi capsular polysaccharide based vaccines to prevent typhoid fever would be significantly facilitated by the identification of a "protective level" of serum antibodies to Vi antigen. The protective level of anti-Vi IgG against typhoid fever was derived from the protective efficacy and immune response of a Vi-rEPA conjugate vaccine efficacy trial. The estimation was derived by two methods: correlation of the percent efficacy and the antibody distribution profile in the vaccine group at a given period of observation, and use of the relative ratio of anti-Vi IgG levels between the vaccine and placebo groups greater or equal to the Relative Risk of typhoid fever used in the efficacy determination. Both methods predicted a similar range of a minimum protective level of anti-Vi IgG between 1.4 and 2.0μg/ml (short term threshold). When applying a protective threshold of 10μg/ml at 6 months post immunization, an IgG level in excess of 1.4μg/ml was achieved by 90% of children at 46 months post immunization, consistent with an 89% level of protection over the duration of the study. We thus suggest that the proportion of children with Vi IgG>10μg/ml (long term threshold) 6 months after immunization may reflect the proportion protected over at least a 4 year period. The current assignment of an anti-Vi IgG protective level may be of value when evaluating vaccine performance of future Vi conjugate vaccines. Published by Elsevier Ltd.

  18. Center for Theoretical Underground Physics and Related Areas - CETUP*2013 Summer Program

    Energy Technology Data Exchange (ETDEWEB)

    Szczerbinska, Barbara [Dakota State Univ., Madison, SD (United States)

    2014-06-01

    In response to an increasing interest in experiments conducted at deep underground facilities around the world, in 2010 the theory community has proposed a new initiative - a Center for Theoretical Underground Physics and Related Areas (CETUP*). The main goal of CETUP* is to bring together people with different talents and skills to address the most exciting questions in particle and nuclear physics, astrophysics, geosciences, and geomicrobiology. Scientists invited to participate in the program do not only provide theoretical support to the underground science, they also examine underlying universal questions of the 21st century including: What is dark matter?, What are the masses of neutrinos?, How have neutrinos shaped the evolution of the universe?, How were the elements from iron to uranium made?, What is the origin and thermal history of the Earth? The mission of the CETUP* is to promote an organized research in physics, astrophysics, geoscience, geomicrobiology and other fields related to the underground science via individual and collaborative research in dynamic atmosphere of intense scientific interactions. Our main goal is to bring together scientists scattered around the world, promote the deep underground science and provide a stimulating environment for creative thinking and open communication between researches of varying ages and nationalities. CETUP*2014 included 5 week long program (June 24 – July 26, 2013) covering various theoretical and experimental aspects of Dark Matter, Neutrino Physics and Astrophysics. Two week long session focused on Dark Matter (June 24-July 6) was followed by two week long program on Neutrino Physics and Astrophysics (July 15-26). The VIIth International Conference on Interconnections between Particle Physics and Cosmology (PPC) was sandwiched between these sessions (July 8-13) covering the subjects of dark matter, neutrino physics, gravitational waves, collider physics and other from both

  19. Factors affecting the adsorption of chromium (VI) on activated carbon

    Energy Technology Data Exchange (ETDEWEB)

    Yavuz, R.; Orbak, I.; Karatepe, N. [Istanbul Technical University, Istanbul (Turkey)

    2006-09-15

    The aim of this investigation was to determine the adsorption behavior of chromium (VI) on two different activated carbon samples produced from Tuncbilek lignite. The effects of the initial chromium (VI) concentration (250-1000 mg/L), temperature (297-323 K) and pH (2.0-9.5) on adsorption were investigated systematically. The effectiveness of the parameters on chromium adsorption was found to be in the order of pH, the initial Cr(VI) concentration and the temperature. Increasing the pH from 2.0 to 9.5 caused a decrease in adsorption. However, the adsorption was increased by increasing the initial Cr(VI) concentration and temperature. The multilinear mathematical model was also developed to predict the Cr(VI) adsorption on activated carbon samples within the experimental conditions.

  20. Cryptosporidium galli and novel Cryptosporidium avian genotype VI in North American red-winged blackbirds (Agelaius phoeniceus)

    Czech Academy of Sciences Publication Activity Database

    Chelladurai, J.J.; Clark, M.E.; Kváč, Martin; Holubová, Nikola; Khan, E.; Stenger, B.L.S.; Giddings, C.W.; McEvoy, J.

    2016-01-01

    Roč. 115, č. 5 (2016), s. 1901-1906 ISSN 0932-0113 Institutional support: RVO:60077344 Keywords : Cryptosporidium * Red-winged blackbird * Passerines * Cryptosporidium galli * Avian genotypeVI * Proventriculus * Intestine Subject RIV: GJ - Animal Vermins ; Diseases, Veterinary Medicine Impact factor: 2.329, year: 2016

  1. Role of an organic carbon-rich soil and Fe(III) reduction in reducing the toxicity and environmental mobility of chromium(VI) at a COPR disposal site.

    Science.gov (United States)

    Ding, Weixuan; Stewart, Douglas I; Humphreys, Paul N; Rout, Simon P; Burke, Ian T

    2016-01-15

    Cr(VI) is an important contaminant found at sites where chromium ore processing residue (COPR) is deposited. No low cost treatment exists for Cr(VI) leaching from such sites. This study investigated the mechanism of interaction of alkaline Cr(VI)-containing leachate with an Fe(II)-containing organic matter rich soil beneath the waste. The soil currently contains 0.8% Cr, shown to be present as Cr(III)(OH)3 in EXAFS analysis. Lab tests confirmed that the reaction of Cr(VI) in site leachate with Fe(II) present in the soil was stoichiometrically correct for a reductive mechanism of Cr accumulation. However, the amount of Fe(II) present in the soil was insufficient to maintain long term Cr(VI) reduction at historic infiltration rates. The soil contains a population of bacteria dominated by a Mangroviflexus-like species, that is closely related to known fermentative bacteria, and a community capable of sustaining Fe(III) reduction in alkaline culture. It is therefore likely that in situ fermentative metabolism supported by organic matter in the soil produces more labile organic substrates (lactate was detected) that support microbial Fe(III) reduction. It is therefore suggested that addition of solid phase organic matter to soils adjacent to COPR may reduce the long term spread of Cr(VI) in the environment. Copyright © 2015 The Authors. Published by Elsevier B.V. All rights reserved.

  2. Bending stresses: imposed on underground small diameter lines in city streets

    Energy Technology Data Exchange (ETDEWEB)

    Kottmann, A

    1975-05-01

    Die Technischen Werke der Stadt Stuttgart AG (TWS, Stuttgart) investigated the accuracy of available bending stress calculations to represent the actual stress exerted on underground pipelines, the effective bending intervals, and the pipe diameter required to effectively resist the expected stress. The investigation covers steel, cast iron, ductile cast iron, asbestos cement, and PVC 100. The theoretical stresses were determined by the Boussinesgne method from the effects of SLW60 vehicles on pipes buried 3.28 ft (1 m) underground. The cumulative load on the pipe was obtained as the total of the vehicle load, soil load, pipe load, and water load. Results indicate that the tensile stress from internal pipe pressure can be omitted, and that welded steel and sealed PVC pipes should account for longitudinal tensile stresses. Steel pipes are generally so oversized that they need not account for these stresses. The calculations also considered the interaction between the pipe and pipe joint as the pipe emerges from the trench for the 3 possible conditions: an overhang beam, a beam encased at one end and jointed at the other, and a beam, encased at both ends. The curves of the resisting moments varied according to the type of material and pipe diameter, with the greatest rate increase reported for asbestos cement, followed by PVC 100, cast iron, ductile cast iron, and steel. Operating data of a cast-iron underground TWS system in Stuttgart indicated that pipes with less than or equal to 4 in. ( less than or equal to 100 mm) nominal diameter were quite fragile while those with diameters >6 in. (>105 mm) sustained considerably less damage. The degree of damage was found to decrease with increasing diameters. The effect of temperature also proved important. Since it is not economically possible to reinstall the distribution lines with 8-in. (200-mm) pipes, elastic support systems such as crossing troughs are recommended to support the pipes in stress areas.

  3. Characteristic behavior of underground and semi-underground structure at earthquake

    International Nuclear Information System (INIS)

    Sawada, Yoshihiro; Komada, Hiroya

    1985-01-01

    An appropriate earthquake-resistant repository design is required to ensure the safety of the radioactive wastes (shallow or deep ground disposal of low- and high-level wastes, respectively). It is particularly important to understand the propagation characteristics of seismic waves and the behaviors of underground hollow structures at the time of an earthquake. This report deals with seismologic observations of rock beds and undergound structures. The maximum acceleration deep under the ground is found to be about 1/2 - 1/3 of that at the ground surface or along the rock bed in the horizontal direction and about 1/1 - 1/2 in the longitudinal direction. A large attenuation cannot be expected in shallow ground. The decrease in displacement amplitude is small compared to that in acceleration. The attenuation effect is larger for a small earthquake and at a short hypocentral distance. The attenuation factor reaches a maximum at a depth of several tens of meters. The seismic spectrum under the ground is flatter than that at the surface. The maximum acceleration along the side wall of a cavity is almost the same as that in the surrounding rock bed. An underground cavity shows complicated phase characteristics at the time of a small earthquake at a short hypocentral distance. (Nogami, K.)

  4. Transport of Th(IV) and U(VI) through barium silico-phosphate composite membrane using electric field

    International Nuclear Information System (INIS)

    Zaki, E.E.

    2002-01-01

    The present paper describes the preparation of a novel barium silico-phosphate filter paper supported membrane. It is based on precipitation reaction of barium silico-phosphate on the outer surface and in the interstices of a filter paper by means of electrodialysis. The main physical and electrical properties of the membrane are given and its electrodialysis behaviour is assessed for Th(IV) and U(VI). The transport of Th(IV) in presence of U(VI) was studied. The cationic fluxes of Th(IV) and U(VI) were found to be 1.2 x 10 -8 and 6.5 x 10 -9 g eq cm -2 s -1 , respectively. Transport of Th(IV) and U(VI) in presence of EDTA was investigated. The cationic flux of U(VI) is found to be 9.8 x 10 -9 g eq cm -2 s -1 at a current density of 25 mA/cm 2 . A comparative study on the electro osmotic effect was carried out using the developed membrane and commercially available Nafion membranes. In this context, different parameters like current density, electrolyte concentration, etc. were investigated. The electro-osmotic permeability coefficient, D e , of Th(IV) through barium silico-phosphate and Nafion membranes were 6.9 x 10 -2 and 1.0 x 10 -2 cm 3 /As, respectively. It can be concluded that inorganic membranes have very marked electro-osmotic properties unlike their organic counterparts. (orig.)

  5. CASPAR - Nuclear Astrophysics Underground

    Science.gov (United States)

    Senarath, Chamaka; Caspar Collaboration

    2017-09-01

    The CASPAR mainly focuses on Stellar Nucleosynthesis, its impact on the production of heavy elements and study the strength of stellar neutron sources that propels the s-process, 13C(α,n)16O and 22Ne(α,n)25Mg. Currently, implementation of a 1MV fully refurbished Van de Graaff accelerator that can provide a high intensity Î+/- beam, is being done at the Sanford Underground Research Facility (SURF). The accelerator is built among a collaboration of South Dakota School of Mines and Technology, University of Notre Dame and Colorado School of Mines. It is understood that cosmic ray neutron background radiation hampers experimental Nucleosynthesis studies, hence the need to go underground in search for a neutron free environment, to study these reactions at low energies is evident. The first beam was produced in the middle of summer 2017. The entire accelerator will be run before the end of this year. A detailed overview of goals of CASPAR will be presented. NFS Grant-1615197.

  6. Development of a 3D Underground Cadastral System with Indoor Mapping for As-Built BIM: The Case Study of Gangnam Subway Station in Korea

    Directory of Open Access Journals (Sweden)

    Sangmin Kim

    2015-12-01

    Full Text Available The cadastral system provides land ownership information by registering and representing land boundaries on a map. The current cadastral system in Korea, however, focuses mainly on the management of 2D land-surface boundaries. It is not yet possible to provide efficient or reliable land administration, as this 2D system cannot support or manage land information on 3D properties (including architectures and civil infrastructures for both above-ground and underground facilities. A geometrical model of the 3D parcel, therefore, is required for registration of 3D properties. This paper, considering the role of the cadastral system, proposes a framework for a 3D underground cadastral system that can register various types of 3D underground properties using indoor mapping for as-built Building Information Modeling (BIM. The implementation consists of four phases: (1 geometric modeling of a real underground infrastructure using terrestrial laser scanning data; (2 implementation of as-built BIM based on geometric modeling results; (3 accuracy assessment for created as-built BIM using reference points acquired by total station; and (4 creation of three types of 3D underground cadastral map to represent underground properties. The experimental results, based on indoor mapping for as-built BIM, show that the proposed framework for a 3D underground cadastral system is able to register the rights, responsibilities, and restrictions corresponding to the 3D underground properties. In this way, clearly identifying the underground physical situation enables more reliable and effective decision-making in all aspects of the national land administration system.

  7. Analytical applications of N-phenyl-n-butyro hydroxamic and N-p-tolyl-n-butyro hydroxamic acids towards chromium (VI), copper (II), iron (III) and uranium (VI)

    International Nuclear Information System (INIS)

    Elkhadir, A. Y. F.

    2001-05-01

    Two aliphatic hydroxamic acids were prepared; N-phenyl-n-butyro hydroxamic acid and N-p-tolyl-n-butyro hydroxamic acid, by the reaction of β-phenylhydroxylamine and p-tolyl hydroxylamine with n-butyryl chloride. The acids were identified by: their melting points, characteristic reactions with acidic solutions of vanadium (V) and iron (III), infrared spectroscopy, nitrogen content and molecular weight determination. The extractability of these acids towards Cr (VI), Cu (II), Fe (III) and U (VI) were investigated at different pH values and molar acid concentrations. N-phenyl-n- butyro hydroxamic acid has a maximum extraction (98.80%) for Cr (VI) at 4 M H 2 SO 4 , (83.25%) for Cu (II) at pH 6, (99.17%) for Fe (III) at pH 5 and (99.76%) at 4 M HNO 3 for U (VI) respectively. N-p-tolyl-n-butyro hydroxamic acid has a maximum extraction (98.40%) for Cr (VI)at 4 M H 2 SO 4 , (81.30%) for Cu (II) at pH 6, (92.80%) for Fe (III) at pH 5 and (99.64%) for U (VI) at 4 M HNO 3 , respectively. The ratios of the metal to ligands were determined by job method (continuous variation method) and were found to be 1:2 for Cr (VI) and U (VI). (Author)

  8. Analytical applications of N-phenyl-n-butyro hydroxamic and N-p-tolyl-n-butyro hydroxamic acids towards chromium (VI), copper (II), iron (III) and uranium (VI)

    Energy Technology Data Exchange (ETDEWEB)

    Elkhadir, A Y. F. [Department of Chemistry, Faculty of Science, University of Khartoum, Khartoum (Sudan)

    2001-05-01

    Two aliphatic hydroxamic acids were prepared; N-phenyl-n-butyro hydroxamic acid and N-p-tolyl-n-butyro hydroxamic acid, by the reaction of {beta}-phenylhydroxylamine and p-tolyl hydroxylamine with n-butyryl chloride. The acids were identified by: their melting points, characteristic reactions with acidic solutions of vanadium (V) and iron (III), infrared spectroscopy, nitrogen content and molecular weight determination. The extractability of these acids towards Cr (VI), Cu (II), Fe (III) and U (VI) were investigated at different pH values and molar acid concentrations. N-phenyl-n- butyro hydroxamic acid has a maximum extraction (98.80%) for Cr (VI) at 4 M H{sub 2}SO{sub 4}, (83.25%) for Cu (II) at pH 6, (99.17%) for Fe (III) at pH 5 and (99.76%) at 4 M HNO{sub 3} for U (VI) respectively. N-p-tolyl-n-butyro hydroxamic acid has a maximum extraction (98.40%) for Cr (VI)at 4 M H{sub 2} SO{sub 4}, (81.30%) for Cu (II) at pH 6, (92.80%) for Fe (III) at pH 5 and (99.64%) for U (VI) at 4 M HNO{sub 3}, respectively. The ratios of the metal to ligands were determined by job method (continuous variation method) and were found to be 1:2 for Cr (VI) and U (VI). (Author)

  9. 78 FR 68783 - Refuge Alternatives for Underground Coal Mines

    Science.gov (United States)

    2013-11-15

    ... Alternatives for Underground Coal Mines AGENCY: Mine Safety and Health Administration, Labor. ACTION: Reopen... coal mines. The U.S. Court of Appeals for the District of Columbia Circuit remanded a training... for refuge alternatives in underground coal mines. On January 13, 2009, the United Mine Workers of...

  10. Photoreduction of chromium(VI) in the presence of algae, Chlorella vulgaris

    Energy Technology Data Exchange (ETDEWEB)

    Deng Lin [School of Resources and Environmental Science, Wuhan University, Wuhan 430072 (China); Wang Hongli [School of Resources and Environmental Science, Wuhan University, Wuhan 430072 (China); Deng Nansheng [School of Resources and Environmental Science, Wuhan University, Wuhan 430072 (China)]. E-mail: nsdengwhu@163.com

    2006-11-16

    In this thesis, the photochemical reduction of hexavalent chromium Cr(VI) in the presence of algae, Chlorella vulgaris, was investigated under the irradiation of metal halide lamps ({lambda}=365nm, 250W). The affecting factors of photochemical reduction were studied in detail, such as exposure time, initial Cr(VI) concentration, initial algae concentration and pH. The rate of Cr(VI) photochemical reduction increased with algae concentration increasing, exposure time increasing, initial Cr(VI) concentration decreasing and the decrease of pH. When pH increased to 6, the rate of Cr(VI) photochemical reduction nearly vanished. When initial Cr(VI) concentration ranged from 0.4 to 1.0mgL{sup -1} and initial algae concentration ranged from ABS{sub algae} (the absorbency of algae)=0.025 to ABS{sub algae}=0.180, According to the results of kinetic analyses, the kinetic equation of Cr(VI) photochemical reduction in aqueous solution with algae under 250W metal halide lamps was V{sub 0}=kC{sub 0}{sup 0.1718}A{sub algae}{sup 0.5235} (C{sub 0} was initial concentration of Cr(VI); A{sub algae} was initial concentration of algae) under the condition of pH 4.

  11. Underground disposal of radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1979-08-15

    Disposal of low- and intermediate-level radioactive wastes by shallow land burial, emplacement in suitable abandoned mines, or by deep well injection and hydraulic fracturing has been practised in various countries for many years. In recent years considerable efforts have been devoted in most countries that have nuclear power programmes to developing and evaluating appropriate disposal systems for high-level and transuranium-bearing waste, and to studying the potential for establishing repositories in geological formations underlaying their territories. The symposium, organized jointly by the IAEA and OECD's Nuclear Energy Agency in cooperation with the Geological Survey of Finland, provided an authoritative account of the status of underground disposal programmes throughout the world in 1979. It was evidence of the experience that has been gained and the comprehensive investigations that have been performed to study various options for the underground disposal of radioactive waste since the last IAEA/NEA symposium on this topic (Disposal of Radioactive Waste into the Ground) was held in 1967 in Vienna. The 10 sessions covered the following topics: National programme and general studies, Disposal of solid waste at shallow depth and in rock caverns, underground disposal of liquid waste by deep well injection and hydraulic fracturing, Disposal in salt formations, Disposal in crystalline rocks and argillaceous sediments, Thermal aspects of disposal in deep geological formations, Radionuclide migration studies, Safety assessment and regulatory aspects.

  12. Nuclear plant undergrounding

    International Nuclear Information System (INIS)

    Brown, R.C.; Bastidas, C.P.

    1978-01-01

    Under Section 25524.3 of the Public Resources Code, the California Energy Resources Conservation and Development Commission (CERCDC) was directed to study ''the necessity for '' and the effectiveness and economic feasibility of undergrounding and berm containment of nuclear reactors. The author discusses the basis for the study, the Sargent and Lundy (S and L) involvement in the study, and the final conclusions reached by S and L

  13. Posture estimation system for underground mine vehicles

    CSIR Research Space (South Africa)

    Hlophe, K

    2010-09-01

    Full Text Available Page 1 of 8 25th International Conference of CAD/CAM, Robotics & Factories of the Future Conference, 13-16 July 2010, Pretoria, South Africa A POSTURE ESTIMATION SYSTEM FOR UNDERGROUND MINE VEHICLES Khonzumusa Hlophe1, Gideon Ferreira2... and the transmitter. The main difference between the three systems is their implementation. This paper describes an implementation of a posture estimation system for underground mine vehicles. The paper is organized as follows. In the next section, a brief...

  14. CoQ10 Deficiency May Indicate Mitochondrial Dysfunction in Cr(VI Toxicity

    Directory of Open Access Journals (Sweden)

    Xiali Zhong

    2017-04-01

    Full Text Available To investigate the toxic mechanism of hexavalent chromium Cr(VI and search for an antidote for Cr(VI-induced cytotoxicity, a study of mitochondrial dysfunction induced by Cr(VI and cell survival by recovering mitochondrial function was performed. In the present study, we found that the gene expression of electron transfer flavoprotein dehydrogenase (ETFDH was strongly downregulated by Cr(VI exposure. The levels of coenzyme 10 (CoQ10 and mitochondrial biogenesis presented by mitochondrial mass and mitochondrial DNA copy number were also significantly reduced after Cr(VI exposure. The subsequent, Cr(VI-induced mitochondrial damage and apoptosis were characterized by reactive oxygen species (ROS accumulation, caspase-3 and caspase-9 activation, decreased superoxide dismutase (SOD and ATP production, increased methane dicarboxylic aldehyde (MDA content, mitochondrial membrane depolarization and mitochondrial permeability transition pore (MPTP opening, increased Ca2+ levels, Cyt c release, decreased Bcl-2 expression, and significantly elevated Bax expression. The Cr(VI-induced deleterious changes were attenuated by pretreatment with CoQ10 in L-02 hepatocytes. These data suggest that Cr(VI induces CoQ10 deficiency in L-02 hepatocytes, indicating that this deficiency may be a biomarker of mitochondrial dysfunction in Cr(VI poisoning and that exogenous administration of CoQ10 may restore mitochondrial function and protect the liver from Cr(VI exposure.

  15. Risk analysis of underground infrastructures in urban areas

    International Nuclear Information System (INIS)

    Cagno, Enrico; De Ambroggi, Massimiliano; Grande, Ottavio; Trucco, Paolo

    2011-01-01

    The paper presents an integrated approach for vulnerability and resilience analysis for underground infrastructures, i.e. a societal risk analysis of the failures of underground services for an urban area. The approach is based on the detailed study of (1) domino-effects for the components of a single infrastructure and for a given set of infrastructures interoperated and/or belonging to the same area; (2) risk and vulnerability analysis of a given area; (3) identification of a set of intervention guidelines, in order to improve the overall system resilience. The use of an integrated (interoperability and area) approach, breaking down the analysis area extent into sub-areas and assessing the dependencies among sub-areas both in terms of interoperability and damage propagation of critical infrastructures, demonstrates a useful advantage in terms of resilience analysis, more consistent with the 'zoned' nature of failures of the underground infrastructures. An applied case, describing the interoperability and damage propagation analysis with the evaluation of time-dependency for the infrastructures and targets and of different kinds of interventions of the underground infrastructures of a town, is presented for this purpose.

  16. As duas naturezas de Lévi-Strauss

    Directory of Open Access Journals (Sweden)

    Philippe Descola

    2011-11-01

    Full Text Available Aborda-se aqui a complexidade do status do par conceitual natureza e cultura no pensamento de Lévi-Strauss. Ao mesmo tempo ferramenta de análise, cena filosófica dos primórdios e antinomia a superar, revisita-se os diferentes usos e significados na obra de Lévi-Strauss do conceito de natureza e sua relação com o de cultura. Mostra-se como é possível reconhecer na obra de Lévi-Strauss dois conceitos de natureza: por um lado, uma natureza que se opõe à cultura num programa científico formulado em termos classicamente dualistas e, por outro, uma teoria do conhecimento decididamente monista que considera o espírito como parte e produto desse mesmo mundo. Argumenta-se que se o dualismo entre cultura e natureza fundou o pensamento estruturalista de Lévi-Strauss, é na própria obra deste que encontramos os argumentos e meios de superá-lo. A vocação do estruturalismo na antropologia de hoje, no entanto, é de ir mais longe neste caminho do que foi o próprio fundador.

  17. Energy Policy Act of 2005 and Underground Storage Tanks (USTs)

    Science.gov (United States)

    The Energy Policy Act of 2005 significantly affected federal and state underground storage tank programs, required major changes to the programs, and is aimed at reducing underground storage tank releases to our environment.

  18. Reducing rock fall injuries in underground US coal mines

    Energy Technology Data Exchange (ETDEWEB)

    Robertson, S.B.; Molinda, G.M.; Pappas, D.M. [Pittsburgh Research Laboratory, Pittsburgh, PA (United States)

    2005-07-01

    A continuing risk to underground US coal miners is rock falling from the mine roof. Almost 99% of injuries caused by rock falls are not from a major roof collapse, but from smaller rock that fall from between roof bolts. Installing roof screen provides excellent overhead roof coverage and dramatically reduces the potential for rock fall injuries, especially to roof bolted operators. The National Institute for Occupational Safety and Health (NIOSH) has explored different installation techniques and roof screening options along with machine design innovations that make roof screening easier and safer. Applying ergonomic principles to roof screening will offer insight and direction for better material handling. Other techniques for controlling rock falls and roof falls for long-term stability include the application of surface support liners and polyurethane (PUR) injection. An ongoing study at the NIOSH Lake Lynn Laboratory of various types of spray-on liner and shotcrete materials is providing a unique opportunity to evaluate the long-term behaviour of liners in an underground environment. In-mine studies of PUR have involved pre- and post-injection core drilling and video borecole logging. The results have provided insights into how PUR penetrates and reinforces weak and highly fractured rock. 11 refs., 8 figs., 1 tab.

  19. Procedure for plutonium determination using Pu(VI) spectra

    International Nuclear Information System (INIS)

    Walker, L.F.; Temer, D.J.; Jackson, D.D.

    1996-01-01

    This document describes a simple spectrophotometric method for determining total plutonium in nitric acid solutions based on the spectrum of Pu(VI). Plutonium samples in nitric acid are oxidized to Pu(VI) with Ce(IV) and the net absorbance at the 830 nm peak is measured

  20. a Webgis to Support Gpr 3d Data Acquisition: a First Step for the Integration of Underground Utility Networks in 3d City Models

    Science.gov (United States)

    Tabarro, P. G.; Pouliot, J.; Fortier, R.; Losier, L.-M.

    2017-10-01

    For the planning and sustainable development of large cities, it is critical to accurately locate and map, in 3D, existing underground utility networks (UUN) such as pipelines, cables, ducts, and channels. An emerging non-invasive instrument for collecting underground data such as UUN is the ground-penetrating radar (GPR). Although its capabilities, handling GPR and extracting relevant information from its data are not trivial tasks. For instance, both GPR and its complimentary software stack provide very few capabilities to co-visualize GPR collected data and other sources of spatial data such as orthophotography, DEM or road maps. Furthermore, the GPR interface lacks functionalities for adding annotation, editing geometric objects or querying attributes. A new approach to support GPR survey is proposed in this paper. This approach is based on the integration of multiple sources of geospatial datasets and the use of a Web-GIS system and relevant functionalities adapted to interoperable GPR data acquisition. The Web-GIS is developed as an improved module in an existing platform called GVX. The GVX-GPR module provides an interactive visualization of multiple layers of structured spatial data, including GPR profiles. This module offers new features when compared to traditional GPR surveys such as geo-annotated points of interest for identifying spatial clues in the GPR profiles, integration of city contextual data, high definition drone and satellite pictures, as-built, and more. The paper explains the engineering approach used to design and develop the Web GIS and tests for this survey approach, mapping and recording UUN as part of 3D city model.

  1. A WEBGIS TO SUPPORT GPR 3D DATA ACQUISITION: A FIRST STEP FOR THE INTEGRATION OF UNDERGROUND UTILITY NETWORKS IN 3D CITY MODELS

    Directory of Open Access Journals (Sweden)

    P. G. Tabarro

    2017-10-01

    Full Text Available For the planning and sustainable development of large cities, it is critical to accurately locate and map, in 3D, existing underground utility networks (UUN such as pipelines, cables, ducts, and channels. An emerging non-invasive instrument for collecting underground data such as UUN is the ground-penetrating radar (GPR. Although its capabilities, handling GPR and extracting relevant information from its data are not trivial tasks. For instance, both GPR and its complimentary software stack provide very few capabilities to co-visualize GPR collected data and other sources of spatial data such as orthophotography, DEM or road maps. Furthermore, the GPR interface lacks functionalities for adding annotation, editing geometric objects or querying attributes. A new approach to support GPR survey is proposed in this paper. This approach is based on the integration of multiple sources of geospatial datasets and the use of a Web-GIS system and relevant functionalities adapted to interoperable GPR data acquisition. The Web-GIS is developed as an improved module in an existing platform called GVX. The GVX-GPR module provides an interactive visualization of multiple layers of structured spatial data, including GPR profiles. This module offers new features when compared to traditional GPR surveys such as geo-annotated points of interest for identifying spatial clues in the GPR profiles, integration of city contextual data, high definition drone and satellite pictures, as-built, and more. The paper explains the engineering approach used to design and develop the Web GIS and tests for this survey approach, mapping and recording UUN as part of 3D city model.

  2. Horonobe Underground Research Laboratory project investigation program for the 2007 fiscal year (Translated document)

    International Nuclear Information System (INIS)

    Matsui, Hiroya; Nakayama, Masashi; Sanada, Hiroyuki; Yamaguchi, Takehiro

    2008-09-01

    As past of the research and development program on the geological disposal of high-level radioactive waste (HLW), the Horonobe Underground Research Center, a division of the Japan Atomic Energy Agency (JAEA), is implementing the Horonobe Underground Research Laboratory Project (Horonobe URL Project) with the aim at investigating sedimentary rock formations. According to the research plan described in the Midterm Plan of JAEA, geological investigations are to be carried out during the drilling of a shaft down to intermediate depth, while research and development in the areas of engineering technology and safety assessment are to be promoted by collaboration with other research organizations. The results of the R and D activities will be systematized as a 'knowledge base' that supports a wide range of arguments related to the safety of geological disposal. The Horonobe URL Project is planned to extend over a period of 20 years. The investigations will be conducted in three phases, namely 'Phase 1: Surface-based investigations', 'Phase 2: Construction phase' (investigations during construction of the underground facilities) and 'Phase 3: Operation phase' (research in the underground facilities). This report summarizes the investigation program for the 2007 fiscal year (2007/2008), the third year of the Phase 2 investigations. In the 2007 fiscal year, investigations in geoscientific research', including 'development of techniques for investigating the geological environment', 'development of techniques for use in the deep underground environment' and 'studies on the long-term stability of the geological environment', is continuously carried out. Investigations in 'research and development on geological disposal technology', including improving the reliability of disposal technologies' and 'enhancement of safety assessment methodologies' are also continuously carried out. Construction of the underground facilities is ongoing at the Ventilation Shaft and the East Shaft

  3. 11-year field study of Pu migration from Pu III, IV, and VI sources

    International Nuclear Information System (INIS)

    Kaplan, D.I.; Serkiz, S.M.; Demirkanli, D.I.; Gumapas, L.; Fjeld, R.A.; Molz, F.J.; Powell, B.A.

    2005-01-01

    Full text of publication follows: Understanding the processes controlling Pu mobility in the subsurface environment is important for estimating the amount of Pu waste that can be safely disposed in vadose zone burial sites. To study long-term Pu mobility, four 52-L lysimeters filled with sediment collected from the Savannah River Site near Aiken South Carolina were amended with well characterized solid Pu sources (Pu III Cl 3 , Pu IV (NO 3 ) 4 , Pu IV (C 2 O 4 ) 2 , and Pu VI O 2 (NO 3 ) 2 ) and left exposed to natural precipitation for 2 to 11 years. Pu oxidation state distribution in the Pu(III) and Pu(IV) lysimeters sediments (a red clayey sediment, pH = 6.3) were similar, consisting of 0% Pu(III), >92% Pu(IV), 1% Pu(V), 1% Pu(VI), and the remainder was a Pu polymer. These three lysimeters also had near identical sediment Pu concentration profiles, where >95% of the Pu remained within 1.25 cm of the source after 11 years; moving at an overall rate of 0.9 cm yr -1 . As expected, Pu moved more rapidly through the Pu(VI) lysimeter, at an overall rate of 12.5 cm yr -1 . Solute transport modeling of the sediment Pu concentration profile data in the Pu(VI) lysimeter indicated that some transformation of Pu into a much less mobile form, presumably Pu(IV), had occurred during the course of the two year study. This modeling also supported previous laboratory measurements showing that Pu(V) or Pu(VI) reduction was five orders of magnitude faster than corresponding Pu(III) or Pu(IV) oxidation. The slow oxidation rate (1 x 10-8 hr -1 ; t 1/2 = 8,000 yr) was not discernable from the Pu(VI) lysimeter data that reflected only two years of transport but was readily discernable from the Pu(III) and Pu(IV) lysimeter data that reflected 11 yr of transport. (authors)

  4. Recovery of oil from underground drill sites

    International Nuclear Information System (INIS)

    Streeter, W.S.; Hutchinson, T.S.; Ameri, S.; Wasson, J.A.; Aminian, K.

    1991-01-01

    This paper reports that a significant quantity of oil is left in reservoirs after conventional oil recovery techniques have been applied. In West Virginia and Pennsylvania alone, this oil has been estimated at over 4.5 billion barrels (0.72 billion m 3 ). Conventional recovery methods are already being used when applicable. But a new recovery method is needed for use in reservoirs that have been abandoned. One alternative method for recovery of the residual oil is known as oil recovery from underground drill sites. This recovery technology is a combination of proven methods and equipment from the petroleum, mining, and civil construction industries. Underground oil recovery can be an economically viable method of producing oil. This has been shown in producing fields, field tests, and feasibility, studies. Faced with decreasing domestic oil production, the petroleum industry should give serious consideration to the use of oil recovery from underground drill sites as a safe, practical, and environmentally sensitive alternative method of producing oil from many reservoirs

  5. Horonobe underground research program. Research report of 2002 FY investigation

    International Nuclear Information System (INIS)

    2003-06-01

    Main results of investigation about Horonobe deep underground research center in 2002 FY were reported. It consists of six chapters: introduction, main results, selection of research center area, underground science research, R and D of geological disposal, and the environmental survey and research center on the ground. The research center area at about 3 km north of Horonobe (B1) was selected in the four areas: A, B1, B2 and C on the basis of data, researches in the sky, aboveground and underground and other conditions. The model of geological environment was constructed by physical, geological, surface water supply researches. Development of geological environment monitoring techniques, investigation of long stabilization of geological environment and design of underground facilities are reported. The basic design of preparation of research center was investigated. (S.Y.)

  6. Synthesis of surface Cr (VI)-imprinted magnetic nanoparticles for selective dispersive solid-phase extraction and determination of Cr (VI) in water samples.

    Science.gov (United States)

    Qi, Xue; Gao, Shuang; Ding, Guosheng; Tang, An-Na

    2017-01-01

    A facile, rapid and selective magnetic dispersed solid-phase extraction (dSPE) method for the extraction and enrichment of Cr (VI) prior to flame atomic absorption spectrometry (AAS) was introduced. For highly selective and efficient extraction, magnetic Cr (VI)-imprinted nanoparticles (Fe 3 O 4 @ Cr (VI) IIPs) were prepared by hyphenating surface ion-imprinted with sol-gel techniques. In the preparation process, chromate (Cr(VI)) was used as the template ion; vinylimidazole and 3-aminopropyltriethoxysilane were selected as organic functional monomer and co-monomer respectively. Another reagent, methacryloxypropyltrimethoxysilane was adopted as coupling agent to form the stable covalent bonding between organic and inorganic phases. The effects of various parameters on the extraction efficiency, such as pH of sample solution, the amount of adsorbent, extraction time, the type and concentration of eluent were systematically investigated. Furthermore, the thermodynamic and kinetic properties of the adsorption process were studied to explore the internal adsorption mechanism. Under optimized conditions, the preconcentration factor, limit of detection and linear range of the established dSPE-AAS method for Cr (VI) were found to be 98, 0.29μgL -1 and 4-140μgL -1 , respectively. The developed method was also successfully applied to the analysis of Cr (VI) in different water samples with satisfactory results, proving its reliability and feasibility in real sample analysis. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. Approach to underground characterization of a disposal vault in granite; Methode de caracterisation souterraine d`une enceinte de stockage dans la roche granitique

    Energy Technology Data Exchange (ETDEWEB)

    Everitt, R A; Martin, C D; Thompson, P M

    1994-12-01

    The concept of disposing of nuclear fuel waste by sealing it in a disposal vault in the Canadian Shield is being investigated as part of the Canadian Nuclear Fuel Waste Management Program. Engineered and natural barriers would isolate the waste from the biosphere. Underground characterization and testing have been under way since 1983 at the Underground Research Laboratory in support of this program. This report draws on experience gained at the URL to recommend an approach to underground characterization to obtain information to optimize the design of the excavation and the engineered barriers, and to provide a baseline against which to monitor the performance of the facility during and following its operation.

  8. A Testbed of Magnetic Induction-based Communication System for Underground Applications

    OpenAIRE

    Tan, Xin; Sun, Zhi; Akyildiz, Ian F.

    2015-01-01

    Wireless underground sensor networks (WUSNs) can enable many important applications such as intelligent agriculture, pipeline fault diagnosis, mine disaster rescue, concealed border patrol, crude oil exploration, among others. The key challenge to realize WUSNs is the wireless communication in underground environments. Most existing wireless communication systems utilize the dipole antenna to transmit and receive propagating electromagnetic (EM) waves, which do not work well in underground en...

  9. Underground gasification of coal. [Newman Spinney

    Energy Technology Data Exchange (ETDEWEB)

    1950-06-16

    This article gives an account of the experimental work on underground gasification at Newman Spinney near Sheffield, England. An attempt was made to develop the percolation technique in flat coal seams but to demonstrate first that gas can be made underground. A borehole system was created on an opencast site where an exposed seam face would allow horizontal drilling to be carried out. Details of trails are given, and drilling techniques, electromagnetic device developed by the Great Britain Post Office Research Branch and radioactive location developed by the Anglo-Iranian Oil Company. An account is given of the inauguration of a series of experiments on May 22, 1950.

  10. Flower-, wire-, and sheet-like MnO2-deposited diatomites: Highly efficient absorbents for the removal of Cr(VI).

    Science.gov (United States)

    Du, Yucheng; Wang, Liping; Wang, Jinshu; Zheng, Guangwei; Wu, Junshu; Dai, Hongxing

    2015-03-01

    Flower-, wire-, and sheet-like MnO2-deposited diatomites have been prepared using a hydrothermal method with Mn(Ac)2, KMnO4 and/or MnSO4 as Mn source and diatomite as support. Physical properties of the materials were characterized by means of numerous analytical techniques, and their behaviors in the adsorption of chromium(VI) were evaluated. It is shown that the MnO2-deposited diatomite samples with different morphologies possessed high surface areas and abundant surface hydroxyl groups (especially the wire-like MnO2/diatomite sample). The wire-like MnO2/diatomite sample showed the best performance in the removal of Cr(VI), giving the maximum Cr(VI) adsorption capacity of 101 mg/g. Copyright © 2014. Published by Elsevier B.V.

  11. Proceedings of the 6th underground operators conference

    International Nuclear Information System (INIS)

    Golosinski, T.S.

    1995-01-01

    This conference presents recent development in underground mining operations. A large number of papers reported on underground mining practice in the Eastern Goldfields area of Western Australia and in the traditional mining centres of Mount Isa and Broken Hill. These are supplemented by papers reporting on other underground mining developments all throughout Australia and in several overseas countries known for advanced mining expertise. Apart from papers dealing with metalliferous mining, a number of papers related to coal mining present recent developments related to the topic. The papers are grouped into sessions relating to ground control, rock mechanics, management and human resources, mining methods, mining equipment, control and communications, mine backfill, mining operations, drilling and blasting and coal mining. Relevant papers have been individually indexed/abstracted. Tabs., figs., refs

  12. Addition to the analysis of the Sr VI and Sr VII spectra

    International Nuclear Information System (INIS)

    Wyart, J.F.

    1989-01-01

    Fifty-six lines of multicharged strontium are measured with an improved wavelength accuracy, or interpreted for the first time. They are 4p-4s, 4p-5s and 4p-4d transitions in Sr VII and 4p-5s transitions in Sr VI. The revision of the singlet-triplet connection in Sr VII is supported by theoretical survey of the ground configuration in Ge-like ions. (orig.)

  13. Cr(VI) adsorption on functionalized amorphous and mesoporous silica from aqueous and non-aqueous media

    International Nuclear Information System (INIS)

    Perez-Quintanilla, Damian; Hierro, Isabel del; Fajardo, Mariano; Sierra, Isabel

    2007-01-01

    A mesoporous silica (SBA-15) and amorphous silica (SG) have been chemically modified with 2-mercaptopyridine using the homogeneous route. This synthetic route involved the reaction of 2-mercaptopyridine with 3-chloropropyltriethoxysilane prior to immobilization on the support. The resulting material has been characterized by powder X-ray diffraction, nitrogen gas sorption, FT-IR and MAS NMR spectroscopy, thermogravimetry and elemental analysis. The solid was employed as a Cr(VI) adsorbent from aqueous and non-aqueous solutions at room temperature. The effect of several variables (stirring time, pH, metal concentration and solvent polarity) has been studied using the batch technique. The results indicate that under the optimum conditions, the maximum adsorption value for Cr(VI) was 1.83 ± 0.03 mmol/g for MP-SBA-15, whereas the adsorption capacity of the MP-SG was 0.86 ± 0.02 mmol/g. On the basis of these results, it can be concluded that it is possible to modify chemically SBA-15 and SG with 2-mercaptopyridine and to use the resulting modified silicas as effective adsorbents for Cr(VI)

  14. Spent fuel disposal: is the underground the sole solution?

    International Nuclear Information System (INIS)

    Nachmilner, L.

    1997-01-01

    The following 4 major approaches to spent fuel disposal are discussed: permanent storage in an underground repository, reprocessing, partitioning and transmutation, and accelerator driven transmutation. It is concluded that underground disposal will remain the basic option for the near future, although pursuing the other methods is certainly worth while. (P.A.)

  15. Background Models for Muons and Neutrons Underground

    International Nuclear Information System (INIS)

    Formaggio, Joseph A.

    2005-01-01

    Cosmogenic-induced activity is an issue of great concern for many sensitive experiments sited underground. A variety of different arch-type experiments - such as those geared toward the detection of dark matter, neutrinoless double beta decay and solar neutrinos - have reached levels of cleanliness and sensitivity that warrant careful consideration of secondary activity induced by cosmic rays. This paper reviews some of the main issues associated with the modeling of cosmogenic activity underground. Comparison with data, when such data is available, is also presented

  16. Solution of tasks concerning protection of underground waters and environment

    International Nuclear Information System (INIS)

    Dubinchuk, V.T.; Polyakov, V.A.

    1988-01-01

    Use of environment isotopes and indicators in solving problems concerning protection of underground waters and environment is discussed. The applied methods permit to study dynamics of underground waters and to estimate risk of their contamination; to follow the surface and underground waters interrelations using data on infiltration recharge estimation etc. Complex nuclear-geophysical and isotope studies may be applied to detect hindered water exchange zones where liquid industrial waste disposals could be placed with minimum damage to environment. 48 refs.; 74 figs.; 22 tabs

  17. Modelling Cr(VI) removal by a combined carbon-activated sludge system

    International Nuclear Information System (INIS)

    Orozco, A. Micaela Ferro; Contreras, Edgardo M.; Zaritzky, Noemi E.

    2008-01-01

    The combined carbon-activated sludge process has been proposed as an alternative to protect the biomass against toxic substances in wastewaters; however, the information about the effect of powdered-activated carbon (PAC) addition in activated sludge reactors for the treatment of wastewaters containing Cr(VI) is limited. The objectives of the present study were: (a) to evaluate the removal of hexavalent chromium by (i) activated sludge microorganisms in aerobic batch reactors, (ii) powdered-activated carbon, and (iii) the combined action of powdered-activated carbon and biomass; (b) to propose mathematical models that interpret the experimental results. Different Cr(VI) removal systems were tested: (S1) biomass (activated sludge), (S2) PAC, and (S3) the combined activated carbon-biomass system. A Monod-based mathematical model was used to describe the kinetics of Cr(VI) removal in the system S1. A first-order kinetics with respect to Cr(VI) and PAC respectively, was proposed to model the removal of Cr(VI) in the system S2. Cr(VI) removal in the combined carbon-biomass system (S3) was faster than both Cr(VI) removal using PAC or activated sludge individually. Results showed that the removal of Cr(VI) using the activated carbon-biomass system (S3) was adequately described by combining the kinetic equations proposed for the systems S1 and S2

  18. ViSA: a neurodynamic model for visuo-spatial working memory, attentional blink, and conscious access.

    Science.gov (United States)

    Simione, Luca; Raffone, Antonino; Wolters, Gezinus; Salmas, Paola; Nakatani, Chie; Belardinelli, Marta Olivetti; van Leeuwen, Cees

    2012-10-01

    Two separate lines of study have clarified the role of selectivity in conscious access to visual information. Both involve presenting multiple targets and distracters: one simultaneously in a spatially distributed fashion, the other sequentially at a single location. To understand their findings in a unified framework, we propose a neurodynamic model for Visual Selection and Awareness (ViSA). ViSA supports the view that neural representations for conscious access and visuo-spatial working memory are globally distributed and are based on recurrent interactions between perceptual and access control processors. Its flexible global workspace mechanisms enable a unitary account of a broad range of effects: It accounts for the limited storage capacity of visuo-spatial working memory, attentional cueing, and efficient selection with multi-object displays, as well as for the attentional blink and associated sparing and masking effects. In particular, the speed of consolidation for storage in visuo-spatial working memory in ViSA is not fixed but depends adaptively on the input and recurrent signaling. Slowing down of consolidation due to weak bottom-up and recurrent input as a result of brief presentation and masking leads to the attentional blink. Thus, ViSA goes beyond earlier 2-stage and neuronal global workspace accounts of conscious processing limitations. PsycINFO Database Record (c) 2012 APA, all rights reserved.

  19. A CMOS rail-to-rail linear VI-converter

    NARCIS (Netherlands)

    Vervoort, P.P.; Vervoort, P.P.; Wassenaar, R.F.

    1995-01-01

    A linear CMOS VI-converter operating in strong inversion with a common-mode input range from the negative to the positive supply rail is presented. The circuit consists of three linear VI-converters based on the difference of squares principle. Two of these perform the actual V to I conversion,

  20. Ternary uranium(VI) carbonato humate complex studied by cryo-TRLFS

    International Nuclear Information System (INIS)

    Steudtner, R.; Sachs, S.; Schmeide, K.; Brendler, V.; Bernhard, G.

    2011-01-01

    The complex formation of U(VI) with humic acid (HA) in the presence of carbonate was studied by time-resolved laser-induced fluorescence spectroscopy at low temperature (cryo-TRLFS) at pH 8.5. In the presence of HA, a decrease of the luminescence intensity of U(VI) and no shift of the emission band maxima in comparison to the luminescence spectrum of the UO 2 (CO 3 ) 3 4- complex, the dominating U(VI) species under the applied experimental conditions in the absence of HA, was observed. The formation of a ternary U(VI) carbonato humate complex of the type UO 2 (CO 3 ) 2 HA(II) 4- starting from UO 2 (CO 3 ) 3 4- was concluded from the luminescence data. For this complex a complex stability constant of log K=2.83 ± 0.17 was determined. Slope analysis resulted in a slope of 1.12 ± 0.11, which verifies the postulated complexation reaction. The results agree very well with literature data. Speciation calculations show that the formation of the ternary U(VI) carbonato humate complex can significantly influence the U(VI) speciation under environmental conditions. (orig.)

  1. Underground storage of radioactive wastes

    International Nuclear Information System (INIS)

    Dietz, D.N.

    1977-01-01

    An introductory survey of the underground disposal of radioactive wastes is given. Attention is paid to various types of radioactive wastes varying from low to highly active materials, as well as mining techniques and salt deposits

  2. Propagation Characteristics in an Underground Shopping Area for 5GHz-band Wireless Access Systems

    Science.gov (United States)

    Itokawa, Kiyohiko; Kita, Naoki; Sato, Akio; Matsue, Hideaki; Mori, Daisuke; Watanabe, Hironobu

    5-GHz band wireless access systems, such as the RLAN (Radio Local Area Network) system of IEEE802.11a, HiperLAN/2, HiSWANa and AWA, are developed and provide transmission rates over 20 Mbps for indoor use. Those 5-GHz access systems are expected to extend service areas from the office to the so-called “hot-spot" in public areas. Underground shopping malls are one of the anticipated service areas for such a nomadic wireless access service. Broadband propagation characteristics are required for radio zone design in an underground mall environment despite previous results obtained by narrow band measurements. This paper presents results of an experimental study on the propagation characteristics for broadband wireless access systems in an underground mall environment. First, broadband propagation path loss is measured and formulated considering human body shadowing. A ray trace simulation is used to clarify the basic propagation mechanism in such a closed environment. Next, a distance dependency of the delay spread during a crowded time period, rush hour, is found to be at most 65 nsec, which is under the permitted maximum value of the present 5-GHz systems. Finally, above propagation characteristics support the result of transmission test carried out by using AWA equipment.

  3. THE SURPRISINGLY CONSTANT STRENGTH OF O VI ABSORBERS OVER COSMIC TIME

    International Nuclear Information System (INIS)

    Fox, Andrew J.

    2011-01-01

    O VI absorption is observed in a wide range of astrophysical environments, including the local interstellar medium, the disk and halo of the Milky Way, high-velocity clouds, the Magellanic Clouds, starburst galaxies, the intergalactic medium (IGM), damped Lyα systems, and gamma-ray-burst host galaxies. Here, a new compilation of 775 O VI absorbers drawn from the literature is presented, all observed at high resolution (instrumental FWHM ≤ 20 km s -1 ) and covering the redshift range z = 0-3. In galactic environments [log N(H I) ∼> 20], the mean O VI column density is shown to be insensitive to metallicity, taking a value log N(O VI) ∼ 14.5 for galaxies covering the range -1.6 ∼ 4 K) clouds and hot (∼10 6 K) plasma, although many such layers would have to be intersected by a typical galaxy-halo sight line to build up the characteristic galactic N(O VI). The alternative, widely used model of single-phase photoionization for intergalactic O VI is ruled out by kinematic evidence in the majority of IGM O VI components at low and high redshift.

  4. Reduction of trace quantities of chromium(VI by strong acids

    Directory of Open Access Journals (Sweden)

    Pezzin Sérgio H

    2004-01-01

    Full Text Available The chemical behavior of Cr(VI at low concentrations (10-4 to 10-7 mol L-1 in several strong acids was studied using high specific activity 51Cr(VI as a tracer. The speciation of the products from these systems was carried out by ion exchange chromatography with stepwise elution. The results show that trace quantities of Cr(VI, monitored by means of radiochromium (51Cr, are reduced in the presence of mineral acids such as perchloric, hydrochloric, hydrofluoric, sulfuric, nitric and trifluoromethanesulfonic acids, even in the absence of conventional reducing agents, producing different measureable Cr(III species, depending on the acid anion. Detailed studies of the reduction of low concentrations of Cr(VI with nitric acid have shown that the relative rate of reduction increases as the concentration of the acid increases or as the concentration of the Cr(VI decreases.

  5. Estudio de inmunogenicidad de la vacuna antitifoídica cubana de polisacárido Vi vax-TyVi® en ratones

    Directory of Open Access Journals (Sweden)

    Juan Carlos Ramírez

    2006-08-01

    Full Text Available Salmonella enterica serovar Typhi es un microorganismo que provoca más de 16 millones de casos de fiebre tifoidea con aproximadamente 600 000 muertes al año en todo el mundo. Dentro de las vacunas antitifoídicas la de polisacárido capsular Vi ha encontrado, gracias a sus incuestionables ventajas, una gran aceptación entre productores y consumidores. El presente trabajo aborda el estudio de inmunogenicidad de la vacuna antitifoídica cubana de polisacárido Vi vax-TyViâ en ratones. El estudio estuvo conformado por un grupo control no inoculado y un segundo grupo que recibió 0,05 mL de la vacuna por vía intramuscular. Se tomaron muestras de sangre a los -3, 7, 14, 21, 28, 42, 56 y 84 días. La actividad de anticuerpos IgG antipolisacárido Vi de los sueros individuales fue determinada por ELISA. Los datos fueron analizados por grupo y por sexo y se calculó el porcentaje de seroconversión, considerándose respondedor aquel animal que al menos aumentara en cuatro veces su título inicial. La respuesta de anticuerpos inducida por la vacuna mostró un aumento notable de los títulos de IgG antipolisacárido Vi en el grupo vacunado (100% de seroconversión, mientras que el grupo control no incrementó sus niveles mínimos iniciales (0% de respondedores. Aunque más dispersa, la respuesta de anticuerpos antiVi fue significativamente mayor en las hembras que en los machos.

  6. Indiana Underground Railroad Folklore: Western Route and Daviess County.

    Science.gov (United States)

    Shelton, Lois G.

    Materials for teaching a unit about the Underground Railroad (the system set up to assist fleeing, runaway slaves heading north) in Indiana are presented. Specifically, the Western Route that passed through Daviess County in Indiana is examined. The materials provide background on the Underground Railroad and the Western Route, plans for teaching…

  7. Permanent Closure of the TAN-664 Underground Storage Tank

    Energy Technology Data Exchange (ETDEWEB)

    Bradley K. Griffith

    2011-12-01

    This closure package documents the site assessment and permanent closure of the TAN-664 gasoline underground storage tank in accordance with the regulatory requirements established in 40 CFR 280.71, 'Technical Standards and Corrective Action Requirements for Owners and Operators of Underground Storage Tanks: Out-of-Service UST Systems and Closure.'

  8. Synthesis, structure and properties of oxo- and dioxochloride complexes of molybdenum(VI) and tungsten(VI) with 8-oxyquinoline

    International Nuclear Information System (INIS)

    Abramenko, V.L.; Sergienko, V.S.; Egorova, O.A.

    2005-01-01

    Complexes of oxo- and dioxochlorides of molybdenum(VI) and tungsten(VI) with 8-oxyquinoline of molecular and intracomplex type are synthesized and studied by the method of IR spectroscopy. The complexes have octahedral structure. It is proposed that 8-oxyquinoline in molecular complexes is coordinated by central atom through nitrogen atom of heterocycle, but in intracomplex compounds - through heterocyclic nitrogen atom and oxygen atom of deprotonated OH-group. Thermal stability of the complexes is studied [ru

  9. Underground gasification in Britain

    Energy Technology Data Exchange (ETDEWEB)

    1952-08-29

    A report of the discussion held on the paper Underground Gasification in Britain, by C.A. Masterman (Iron and Coal Trades Rev., Vol. 165, Aug. 22, 1952, pp. 413-422). The water question, preheating the air, controlling the gas, using the product, choosing the site, thickness of seam and faulted areas are discussed.

  10. Quantifying Cr(VI) Production and Export from Serpentine Soil of the California Coast Range.

    Science.gov (United States)

    McClain, Cynthia N; Fendorf, Scott; Webb, Samuel M; Maher, Kate

    2017-01-03

    Hexavalent chromium (Cr(VI)) is generated in serpentine soils and exported to surface and groundwaters at levels above health-based drinking water standards. Although Cr(VI) concentrations are elevated in serpentine soil pore water, few studies have reported field evidence documenting Cr(VI) production rates and fluxes that govern Cr(VI) transport from soil to water sources. We report Cr speciation (i) in four serpentine soil depth profiles derived from the California Coast Range serpentinite belt and (ii) in local surface waters. Within soils, we detected Cr(VI) in the same horizons where Cr(III)-minerals are colocated with biogenic Mn(III/IV)-oxides, suggesting Cr(VI) generation through oxidation by Mn-oxides. Water-extractable Cr(VI) concentrations increase with depth constituting a 7.8 to 12 kg/km 2 reservoir of Cr(VI) in soil. Here, Cr(VI) is produced at a rate of 0.3 to 4.8 kg Cr(VI)/km 2 /yr and subsequently flushed from soil during water infiltration, exporting 0.01 to 3.9 kg Cr(VI)/km 2 /yr at concentrations ranging from 25 to 172 μg/L. Although soil-derived Cr(VI) is leached from soil at concentrations exceeding 10 μg/L, due to reduction and dilution during transport to streams, Cr(VI) levels measured in local surface waters largely remain below California's drinking water limit.

  11. Analysis and design of SSC underground structures

    International Nuclear Information System (INIS)

    Clark, G.T.

    1993-01-01

    This paper describes the analysis and design of underground structures for the Superconducting Super Collider (SSC) Project. A brief overview of the SSC Project and the types of underground structures are presented. Engineering properties and non-linear behavior of the geologic materials are reviewed. The three-dimensional sequential finite element rock-structure interaction analysis techniques developed by the author are presented and discussed. Several examples of how the method works, specific advantages, and constraints are presented. Finally, the structural designs that resulted from the sequential interaction analysis are presented

  12. Chromium (VI) biosorption properties of multiple resistant bacteria isolated from industrial sewerage.

    Science.gov (United States)

    Oyetibo, Ganiyu Oladunjoye; Ilori, Matthew Olusoji; Obayori, Oluwafemi Sunday; Amund, Olukayode Oladipo

    2013-08-01

    Chromium (VI) [Cr (VI)] biosorption by four resistant autochthonous bacterial strains was investigated to determine their potential for use in sustainable marine water-pollution control. Maximum exchange between Cr (VI) ions and protons on the cells surfaces were at 30-35 °C, pH 2.0 and 350-450 mg/L. The bacterial strains effectively removed 79.0-90.5 % Cr (VI) ions from solution. Furthermore, 85.3-93.0 % of Cr (VI) ions were regenerated from the biomasses, and 83.4-91.7 % of the metal was adsorbed when the biomasses was reused. Langmuir isotherm performed better than Freundlich isotherm, depicting that Cr (VI) affinity was in the sequence Rhodococcus sp. AL03Ni > Burkholderia cepacia AL96Co > Corynebacterium kutscheri FL108Hg > Pseudomonas aeruginosa CA207Ni. Biosorption isotherms confirmed that Rhodococcus sp. AL03Ni was a better biosorbent with a maximum uptake of 107.46 mg of Cr (VI) per g (dry weight) of biomass. The results highlight the high potential of the organisms for bacteria-based detoxification of Cr (VI) via biosorption.

  13. Radionuclides in an underground environment

    International Nuclear Information System (INIS)

    Thompson, J.L.

    1996-01-01

    In the 100 years since Becquerel recognized radioactivity, mankind has been very successful in producing large amounts of radioactive materials. We have been less successful in reaching a consensus on how to dispose of the billions of curies of fission products and transuranics resulting from nuclear weapons testing, electrical power generation, medical research, and a variety of other human endeavors. Many countries, including the United States, favor underground burial as a means of disposing of radioactive wastes. There are, however, serious questions about how such buried wastes may behave in the underground environment and particularly how they might eventually contaminate water, air and soil resources on which we are dependent. This paper describes research done in the United States in the state of Nevada on the behavior of radioactive materials placed underground. During the last thirty years, a series of ''experiments'' conducted for other purposes (testing of nuclear weapons) have resulted in a wide variety of fission products and actinides being injected in rock strata both above and below the water table. Variables which seem to control the movement of these radionuclides include the physical form (occlusion versus surface deposition), the chemical oxidation state, sorption by mineral phases of the host rock, and the hydrologic properties of the medium. The information gained from these studies should be relevant to planning for remediation of nuclear facilities elsewhere in the world and for long-term storage of nuclear wastes

  14. Research on communication system of underground safety management based on leaky feeder cable

    Institute of Scientific and Technical Information of China (English)

    CHEN Jian-hong; ZHANG Tao; CHENG Yun-cai; ZHANG Han

    2007-01-01

    According to the current working status of underground safety management and production scheduling, the importance and existed problem of underground mine radio communication were summarized, and the basic principle and classification of leaky feeder cable were introduced and the characteristics of cable were analyzed specifically in depth, and the application model of radio communication system for underground mine safety management was put forward. Meanwhile, the research explanation of the system component, function and evaluation was provided. The discussion result indicates that communication system of underground mine safety management which is integrated two-way relay amplifier and other equipment has many communication functions, and underground mine mobile communication can be achieved well.

  15. Integrated Cr(VI) removal using constructed wetlands and composting.

    Science.gov (United States)

    Sultana, Mar-Yam; Chowdhury, Abu Khayer Md Muktadirul Bari; Michailides, Michail K; Akratos, Christos S; Tekerlekopoulou, Athanasia G; Vayenas, Dimitrios V

    2015-01-08

    The present work was conducted to study integrated chromium removal from aqueous solutions in horizontal subsurface (HSF) constructed wetlands. Two pilot-scale HSF constructed wetlands (CWs) units were built and operated. One unit was planted with common reeds (Phragmites australis) and one was kept unplanted. Influent concentrations of Cr(VI) ranged from 0.5 to 10mg/L. The effect of temperature and hydraulic residence time (8-0.5 days) on Cr(VI) removal were studied. Temperature was proved to affect Cr(VI) removal in both units. In the planted unit maximum Cr(VI) removal efficiencies of 100% were recorded at HRT's of 1 day with Cr(VI) concentrations of 5, 2.5 and 1mg/L, while a significantly lower removal rate was recorded in the unplanted unit. Harvested reed biomass from the CWs was co-composted with olive mill wastes. The final product had excellent physicochemical characteristics (C/N: 14.1-14.7, germination index (GI): 145-157%, Cr: 8-10mg/kg dry mass), fulfills EU requirements and can be used as a fertilizer in organic farming. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. High radon exposure in a Brazilian underground coal mine

    International Nuclear Information System (INIS)

    Veiga, L H S; Melo, V; Koifman, S; Amaral, E C S

    2004-01-01

    The main source of radiation exposure in most underground mining operations is radon and radon decay products. The situation of radon exposure in underground mining in Brazil is still unknown, since there has been no national regulation regarding this exposure. A preliminary radiological survey in non-uranium mines in Brazil indicated that an underground coal mine in the south of Brazil had high radon concentration and needed to be better evaluated. This paper intends to present an assessment of radon and radon decay product exposure in the underground environment of this coal mining industry and to estimate the annual exposure to the workers. As a product of this assessment, it was found that average radon concentrations at all sampling campaign and excavation sites were above the action level range for workplaces of 500-1500 Bq m -3 recommended by the International Commission on Radiological Protection-ICRP 65. The average effective dose estimated for the workers was almost 30 times higher than the world average dose for coal miners

  17. Moura tragedy the model for this year's underground exercise

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-01

    Mines Rescue teams in the 1991 E.K. Healy cup competition handled an underground exercise based on the Moura No. 4 colliery explosion which killed 12 miners on July 16, 1986. The contest organisers and hosts went to great lengths to achieve realism. This included underground water barriers and ventilation tubes being tossed around, meat, offal and bullock's blood being strewn and using trickel dusters to produce a smoke effect restricting visibility to 20 metres. The other exercises in the contest were: a theory test; and exercise involving gas monitoring, power isolation and fire fighting; and a first aid section dealt with an electrical accident near water. The task in the underground exercise was to retrieve information. The Chairman of the Assessors reported that the theory and fire fighting were handled fairly well. Handling of the electrical incident was not too bad, with the life saving techniques being very well done. The underground exercise revealed different ways of gathering information. While leadership styles and team member interaction varied this was not detrimental to efficiency. 9 photos.

  18. Prediction accident triangle in maintenance of underground mine facilities using Poisson distribution analysis

    Science.gov (United States)

    Khuluqi, M. H.; Prapdito, R. R.; Sambodo, F. P.

    2018-04-01

    In Indonesia, mining is categorized as a hazardous industry. In recent years, a dramatic increase of mining equipment and technological complexities had resulted in higher maintenance expectations that accompanied by the changes in the working conditions, especially on safety. Ensuring safety during the process of conducting maintenance works in underground mine is important as an integral part of accident prevention programs. Accident triangle has provided a support to safety practitioner to draw a road map in preventing accidents. Poisson distribution is appropriate for the analysis of accidents at a specific site in a given time period. Based on the analysis of accident statistics in the underground mine maintenance of PT. Freeport Indonesia from 2011 through 2016, it is found that 12 minor accidents for 1 major accident and 66 equipment damages for 1 major accident as a new value of accident triangle. The result can be used for the future need for improving the accident prevention programs.

  19. Retention of U(VI) onto silica in presence of model organic molecules

    International Nuclear Information System (INIS)

    Pham, T.T.H.; Mercier-Bion, F.; Drot, R.; Lagarde, G.; Simoni, E.; Lambert, J.

    2008-01-01

    It is well-known that the organic matter influences the retention of ions onto mineral surfaces. However, the major part of concerned studies implies humic substances and complex solids. Another approach for identifying the sorption mechanisms is possible by studying simpler solids than those present in natural medium. So, silica is chosen as mineral surface because of its abundance in soils and of the presence of Si-O groups in clayey minerals. Uranium (VI) is selected as cation. Simple organic molecules like acetic (one carboxylic group) and oxalic (two carboxylic functions) acids are considered as models of the natural organic matter for understanding their role in the retention of U(VI) onto powders and slides of silica. Binary (organics/silica, U(VI)/silica) and ternary systems (organics/silica/U(VI)) are studied by complementary approaches. Sorption edges as function of pH are obtained by liquid scintillation methods and capillary electrophoresis. Different spectroscopic techniques are used to deduce the interactions between the organic matter and U(VI) sorbed onto the silica whose: Time-Resolved Laser induced Fluorescence Spectroscopy (TRLFS), X-ray Photoelectron Spectroscopy (XPS), Nuclear Microprobe Analysis (NMA). The results of the effect of these model organic molecules onto the U(VI) retention showed a good agreement between the different techniques. Concerning the acetic acid, there are not differences in the sorption percentages of uranyl (see the figure). All these results indicate that the uranyl-acetate complexes stay in the aqueous solution rather than sorbing onto the silica. On the contrary, oxalic acid influences the sorption of U(VI) onto the silica surface. The sorption percentage of U(VI) in the ternary system (oxalic acid/silica/U(VI)) is lower than the binary system (U(VI)/silica) (see the figure). So, the presence of oxalic acid decreases the sorption of U(VI) onto the silica surface. (authors)

  20. Upscaling laboratory results for water quality prediction at underground collieries in South Africa's Highveld Coalfields

    Energy Technology Data Exchange (ETDEWEB)

    Usher, B.H. [University of Orange Free State, Bloemfontein (South Africa). Institute for Groundwater Studies

    2009-01-15

    The prediction of future acidity and water quality is a key aspect of water management in mining environments. In this paper, different prediction techniques tested in an isolated underground compartment at a colliery in the Highveld Coalfield of South Africa are discussed. Considerations for upscaling these results are explained, and a methodology for upscaling is tested at this facility. Over 30 samples were collected around the compartment and through cored boreholes. These samples were tested using acid-base accounting tests, humidity cells, and mineralogy. From this, an integrated interpretation of potential water quality evolution was made, supported by detailed water quality sampling with the use of surface boreholes, stratified sampling underground, and pumped qualities over a period of two years. The results show that analytical tests play an integral role in water quality predictions at underground collieries. The results also show that, despite the vast differences between laboratory test conditions and the situation in the field, by taking site conditions into account to properly contextualise the results, improved predictions of expected water quality can be obtained.

  1. Experimental Monitoring of Cr(VI) Bio-reduction Using Electrochemical Geophysics

    International Nuclear Information System (INIS)

    Birsen Canan; Gary R. Olhoeft; William A. Smith

    2007-01-01

    Many Department of Energy (DOE) sites are contaminated with highly carcinogenic hexavalent chromium (Cr(VI)). In this research, we explore the feasibility of applying complex resistivity to the detection and monitoring of microbially-induced reduction of hexavalent chromium (Cr(VI)) to a less toxic form (Cr(III)). We hope to measure the change in ionic concentration that occurs during this reduction reaction. This form of reduction promises to be an attractive alternative to more expensive remedial treatment methods. The specific goal of this research is to define the minimum and maximum concentration of the chemical and biological compounds in contaminated samples for which the Cr(VI) - Cr(III) reduction processes could be detected via complex resistivity. There are three sets of experiments, each comprised of three sample columns. The first experiment compares three concentrations of Cr(VI) at the same bacterial cell concentration. The second experiment establishes background samples with, and without, Cr(VI) and bacterial cells. The third experiment examines the influence of three different bacterial cell counts on the same concentration of Cr(VI). A polarization relaxation mechanism was observed between 10 and 50 Hz. The polarization mechanism, unfortunately, was not unique to bio-chemically active samples. Spectral analysis of complex resistivity data, however, showed that the frequency where the phase minimum occurred was not constant for bio-chemically active samples throughout the experiment. A significant shifts in phase minima occurred between 10 to 20 Hz from the initiation to completion of Cr(VI) reduction. This phenomena was quantified using the Cole-Cole model and the Marquardt-Levenberg nonlinear least square minimization method. The data suggests that the relaxation time and the time constant of this relaxation are the Cole-Cole parameters most sensitive to changes in biologically-induced reduction of Cr(VI)

  2. Paisaje del viñedo: patrimonio y recurso

    Directory of Open Access Journals (Sweden)

    Luis Vicente Elías

    2008-01-01

    Full Text Available La propuesta de que el paisaje del viñedo sea el complemento a la visita a la bodega, siendo esta el eje del turismo del vino, es el objetivo de este trabajo. Repasando los conceptos variables de patrimonio, llegamos al paisaje del viñedo como recurso, formando parte del patrimonio natural. Pero este no se puede desvincular de los otros aspectos patrimoniales, por lo que la cultura tradicional es el soporte de la tipología de paisaje que queremos proponer y que va contrastar con los nuevos paisajes del viñedo que surgen de las recientes técnicas en los cultivos y de la actual vitivicultura, emparejada con una moderna “cultura del vino”. El análisis de las diversas normativas, que salvaguardan el paisaje y la comprobación del escaso valor legal del paisaje del viñedo, es otro puntal de este trabajo que trata de unir paisaje con cultura tradicional como recursos del Turismo del Vino, integrados en las Rutas del Vino.

  3. Delineation and Diagnostic Criteria of Oral-Facial-Digital Syndrome Type VI

    Directory of Open Access Journals (Sweden)

    Poretti Andrea

    2012-01-01

    Full Text Available Abstract Oral-Facial-Digital Syndrome type VI (OFD VI represents a rare phenotypic subtype of Joubert syndrome and related disorders (JSRD. In the original report polydactyly, oral findings, intellectual disability, and absence of the cerebellar vermis at post-mortem characterized the syndrome. Subsequently, the molar tooth sign (MTS has been found in patients with OFD VI, prompting the inclusion of OFD VI in JSRD. We studied the clinical, neurodevelopmental, neuroimaging, and genetic findings in a cohort of 16 patients with OFD VI. We derived the following inclusion criteria from the literature: 1 MTS and one oral finding and polydactyly, or 2 MTS and more than one typical oral finding. The OFD VI neuroimaging pattern was found to be more severe than in other JSRD subgroups and includes severe hypoplasia of the cerebellar vermis, hypoplastic and dysplastic cerebellar hemispheres, marked enlargement of the posterior fossa, increased retrocerebellar collection of cerebrospinal fluid, abnormal brainstem, and frequently supratentorial abnormalities that occasionally include characteristic hypothalamic hamartomas. Additionally, two new JSRD neuroimaging findings (ascending superior cerebellar peduncles and fused thalami have been identified. Tongue hamartomas, additional frenula, upper lip notch, and mesoaxial polydactyly are specific findings in OFD VI, while cleft lip/palate and other types of polydactyly of hands and feet are not specific. Involvement of other organs may include ocular findings, particularly colobomas. The majority of the patients have absent motor development and profound cognitive impairment. In OFD VI, normal cognitive functions are possible, but exceptional. Sequencing of known JSRD genes in most patients failed to detect pathogenetic mutations, therefore the genetic basis of OFD VI remains unknown. Compared with other JSRD subgroups, the neurological findings and impairment of motor development and cognitive functions in OFD

  4. Cross flow ultrafiltration of Cr (VI) using MCM-41, MCM-48 and Faujasite (FAU) zeolite-ceramic composite membranes.

    Science.gov (United States)

    Basumatary, Ashim Kumar; Kumar, R Vinoth; Ghoshal, Aloke Kumar; Pugazhenthi, G

    2016-06-01

    This work describes the removal of Cr (VI) from aqueous solution in cross flow mode using MCM-41, MCM-48 and FAU zeolite membranes prepared on circular shaped porous ceramic support. Ceramic support was manufactured using locally available clay materials via a facile uni-axial compaction method followed by sintering process. A hydrothermal technique was employed for the deposition of zeolites on the ceramic support. The porosity of ceramic support (47%) is reduced by the formation of MCM-41 (23%), MCM-48 (22%) and FAU (33%) zeolite layers. The pore size of the MCM-41, MCM-48 and FAU membrane is found to be 0.173, 0.142, and 0.153 μm, respectively, which is lower than that of the support (1.0 μm). Cross flow ultrafiltration experiments of Cr (VI) were conducted at five different applied pressures (69-345 kPa) and three cross flow rates (1.11 × 10(-7) - 2.22 × 10(-7) m(3)/s). The filtration studies inferred that the performance of the fabricated zeolite composite membranes is optimum at the maximum applied pressure (345 kPa) and the highest rejection is obtained with the lowest cross flow rate (1.11 × 10(-7) m(3)/s) for all three zeolite membrane. The permeate flux of MCM-41, MCM-48 and FAU zeolite composite membranes are almost remained constant in the entire duration of the separation process. The highest removal of 82% is shown by FAU membrane, while MCM-41 and MCM-48 display 75% and 77% of Cr (VI) removal, respectively for the initial feed concentration of 1000 ppm with natural pH of the solution at an applied pressure of 345 kPa. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Tank Waste Remediation System Inactive Miscellaneous Underground Storage Tanks Program Plan

    International Nuclear Information System (INIS)

    Gustavson, R.D.

    1995-12-01

    The Program Management Plan (PMP) describes the approach that will be used to manage the Tank Waste Remediation System (TWRS) Inactive Miscellaneous Underground Storage Tank (IMUST) Program. The plan describes management, technical, and administrative control systems that will be used to plan and control the IMUSTs Program performance. The technical data to determine the IMUSTs status for inclusion in the Single Shell Tank Farm Controlled Clean and Stable (CCS) Program. The second is to identify and implement surveillance, characterization, stabilization, and modifications to support CCS prior to final closure

  6. Going Underground in Singapore

    CERN Multimedia

    John Osborne (GS/SEM)

    2010-01-01

    Singapore has plans to build a massive Underground Science City (USC) housing R&D laboratories and IT data centres. A delegation involved in the planning to build the subterranean complex visited CERN on 18 October 2010 to learn from civil engineers and safety experts about how CERN plans and constructs its underground facilities.   The delegation from Singapore. The various bodies and corporations working on the USC project are currently studying the feasibility of constructing up to 40 caverns (60 m below ground) similar in size to an LHC experiment hall, in a similar type of rock. Civil engineering and geotechnical experts are calculating the maximum size of the cavern complex that can be safely built. The complex could one day accommodate between 3000 and 5000 workers on a daily basis, so typical issues of size and number of access shafts need to be carefully studied. At first glance, you might not think the LHC has much in common with the USC project; as Rolf Heuer pointed out: &ldq...

  7. New approach in modeling Cr(VI) sorption onto biomass from metal binary mixtures solutions

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chang [College of Environmental Science and Engineering, Anhui Normal University, South Jiuhua Road, 189, 241002 Wuhu (China); Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Fiol, Núria [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Villaescusa, Isabel, E-mail: Isabel.Villaescusa@udg.edu [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Poch, Jordi [Applied Mathematics Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain)

    2016-01-15

    In the last decades Cr(VI) sorption equilibrium and kinetic studies have been carried out using several types of biomasses. However there are few researchers that consider all the simultaneous processes that take place during Cr(VI) sorption (i.e., sorption/reduction of Cr(VI) and simultaneous formation and binding of reduced Cr(III)) when formulating a model that describes the overall sorption process. On the other hand Cr(VI) scarcely exists alone in wastewaters, it is usually found in mixtures with divalent metals. Therefore, the simultaneous removal of Cr(VI) and divalent metals in binary mixtures and the interactive mechanism governing Cr(VI) elimination have gained more and more attention. In the present work, kinetics of Cr(VI) sorption onto exhausted coffee from Cr(VI)–Cu(II) binary mixtures has been studied in a stirred batch reactor. A model including Cr(VI) sorption and reduction, Cr(III) sorption and the effect of the presence of Cu(II) in these processes has been developed and validated. This study constitutes an important advance in modeling Cr(VI) sorption kinetics especially when chromium sorption is in part based on the sorbent capacity of reducing hexavalent chromium and a metal cation is present in the binary mixture. - Highlights: • A kinetic model including Cr(VI) reduction, Cr(VI) and Cr(III) sorption/desorption • Synergistic effect of Cu(II) on Cr(VI) elimination included in the model • Model validation by checking it against independent sets of data.

  8. New approach in modeling Cr(VI) sorption onto biomass from metal binary mixtures solutions

    International Nuclear Information System (INIS)

    Liu, Chang; Fiol, Núria; Villaescusa, Isabel; Poch, Jordi

    2016-01-01

    In the last decades Cr(VI) sorption equilibrium and kinetic studies have been carried out using several types of biomasses. However there are few researchers that consider all the simultaneous processes that take place during Cr(VI) sorption (i.e., sorption/reduction of Cr(VI) and simultaneous formation and binding of reduced Cr(III)) when formulating a model that describes the overall sorption process. On the other hand Cr(VI) scarcely exists alone in wastewaters, it is usually found in mixtures with divalent metals. Therefore, the simultaneous removal of Cr(VI) and divalent metals in binary mixtures and the interactive mechanism governing Cr(VI) elimination have gained more and more attention. In the present work, kinetics of Cr(VI) sorption onto exhausted coffee from Cr(VI)–Cu(II) binary mixtures has been studied in a stirred batch reactor. A model including Cr(VI) sorption and reduction, Cr(III) sorption and the effect of the presence of Cu(II) in these processes has been developed and validated. This study constitutes an important advance in modeling Cr(VI) sorption kinetics especially when chromium sorption is in part based on the sorbent capacity of reducing hexavalent chromium and a metal cation is present in the binary mixture. - Highlights: • A kinetic model including Cr(VI) reduction, Cr(VI) and Cr(III) sorption/desorption • Synergistic effect of Cu(II) on Cr(VI) elimination included in the model • Model validation by checking it against independent sets of data

  9. Euro VI technologies and costs for Heavy Duty vehicles: the expert panels summary of stakeholders responses

    NARCIS (Netherlands)

    Gense, N.L.J.; Riemersma, I.J.; Such, C.l; Ntziachristos, L.

    2006-01-01

    This report is the result of the work carried out under on the Europeans Commission’s call for tender regarding “Technical support for the Commission DG Environment on the development of Euro 5 standards for light-duty vehicles and Euro VI standards for heavy-duty vehicles” (Reference:

  10. Cr(VI) retention and transport through Fe(III)-coated natural zeolite

    Energy Technology Data Exchange (ETDEWEB)

    Du, Gaoxiang [School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China); Li, Zhaohui, E-mail: li@uwp.edu [School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China); Geosciences Department, University of Wisconsin-Parkside, Kenosha, WI 53144 (United States); Department of Earth Sciences, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan (China); Liao, Libing [School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China); Hanson, Renee; Leick, Samantha; Hoeppner, Nicole [Geosciences Department, University of Wisconsin-Parkside, Kenosha, WI 53144 (United States); Jiang, Wei-Teh [Department of Earth Sciences, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan (China)

    2012-06-30

    Graphical abstract: Breakthrough curves of Cr(VI) from columns packed with raw zeolite (a) and Fe(III)-zeolite (b). The solid line in (b) is the HYDRUS-1D fit to the observed data with adsorption term only, while the dashed line in (b) includes a reduction term in the HYDRUS-1D fit. Highlights: Black-Right-Pointing-Pointer Zeolite modified with Fe(III) could be used for adsorption and retention of Cr(VI). Black-Right-Pointing-Pointer The Fe present on zeolite was in an amorphous Fe(OH){sub 3} form. Black-Right-Pointing-Pointer A Cr(VI) adsorption capacity of 82 mg/kg was found on Fe(III)-zeolite. Black-Right-Pointing-Pointer A Cr(VI) retardation factor of 3 or 5 was determined from column and batch studies. - Abstract: Cr(VI) is a group A chemical based on the weight of evidence of carcinogenicity. Its transport and retention in soils and groundwater have been studied extensively. Zeolite is a major component in deposits originated from volcanic ash and tuff after alteration. In this study, zeolite aggregates with the particle size of 1.4-2.4 mm were preloaded with Fe(III). The influence of present Fe(III) on Cr(VI) retention by and transport through zeolite was studied under batch and column experiments. The added Fe(III) resulted in an enhanced Cr(VI) retention by the zeolite with a capacity of 82 mg/kg. The Cr(VI) adsorption on Fe(III)-zeolite followed a pseudo-second order kinetically and the Freundlich adsorption isotherm thermodynamically. Fitting the column experimental data to HYDRUS-1D resulted in a retardation factor of 3 in comparison to 5 calculated from batch tests at an initial Cr(VI) concentration of 3 mg/L. The results from this study showed that enhanced adsorption and retention of Cr(VI) may happen in soils derived from volcanic ash and tuff that contains significant amounts of zeolite with extensive Fe(III) coating.

  11. Geotechnical design of underground slate mines

    International Nuclear Information System (INIS)

    Iglesias Comesaña, C.; Taboada Castro, J.; Arzúa Touriño, J.; Giráldez Pérez, E.; Martín Suárez, J.M.

    2017-01-01

    Slate is one of the most important natural materials in Spain, with a potent extractive and processing industry concentrated in the autonomous communities of Galicia, Castile and León. Thanks to its resistance to external agents, its impermeability and its excellent cleavability, slate is used as for roofing and tiling. Almost all the active exploitations in our country where this resource is extracted are open pit mines, where the exploitation ratios have nearly reached their economic limit, making it necessary to look for alternatives that will allow the mining works to be continued. Underground mining is a solution that offers low exploitation ratios, with low spoil generation. The room-and-pillar method with barrier pillars is usually applied for the exploitation of slate deposits. There are several factors to be taken into account when designing a mine (economic, logistical, geotechnical, technical, environmental…), especially for an underground mine. This study focuses on the geotechnical design process of a room-and-pillar underground mine, based on the tributary area theory, the analysis of the tensions in the ground with numerical methods and the choice of an appropriate reinforcement in view of the expected instabilities. This explanation is completed with an example of a design that includes the estimate exploitation rates and production. [es

  12. Ternary uranium(VI) carbonato humate complex studied by cryo-TRLFS

    Energy Technology Data Exchange (ETDEWEB)

    Steudtner, R.; Sachs, S.; Schmeide, K.; Brendler, V.; Bernhard, G. [Helmholtz-Zentrum Dresden-Rossendorf, Dresden (Germany). Inst. of Radiochemistry

    2011-07-01

    The complex formation of U(VI) with humic acid (HA) in the presence of carbonate was studied by time-resolved laser-induced fluorescence spectroscopy at low temperature (cryo-TRLFS) at pH 8.5. In the presence of HA, a decrease of the luminescence intensity of U(VI) and no shift of the emission band maxima in comparison to the luminescence spectrum of the UO{sub 2}(CO{sub 3}){sub 3}{sup 4-} complex, the dominating U(VI) species under the applied experimental conditions in the absence of HA, was observed. The formation of a ternary U(VI) carbonato humate complex of the type UO{sub 2}(CO{sub 3}){sub 2}HA(II){sup 4-} starting from UO{sub 2}(CO{sub 3}){sub 3}{sup 4-} was concluded from the luminescence data. For this complex a complex stability constant of log K=2.83 {+-} 0.17 was determined. Slope analysis resulted in a slope of 1.12 {+-} 0.11, which verifies the postulated complexation reaction. The results agree very well with literature data. Speciation calculations show that the formation of the ternary U(VI) carbonato humate complex can significantly influence the U(VI) speciation under environmental conditions. (orig.)

  13. Recovery of uranium (VI) from low level aqueous radioactive waste

    International Nuclear Information System (INIS)

    Kulshrestha, Mukul

    1996-01-01

    Investigation was undertaken to evaluate the uranium (VI) removal and recovery potential of a naturally occurring, nonviable macrofungus, Ganoderma Lucidum from the simulated low level aqueous nuclear waste. These low level waste waters discharged from nuclear mine tailings and nuclear power reactors have a typical U(VI) concentration of 10-100 mg/L. It is possible to recover this uranium economically with the advent of biosorption as a viable technology. Extensive laboratory studies have revealed Ganoderma Lucidum to be a potential biosorbent with a specific uptake of 2.75 mg/g at an equilibrium U(VI) concentration of 10 mg/L at pH 4.5. To recover the sorbed U(VI), the studies indicated 0.2N Na 2 CO 3 to be an effective elutant. The kinetics of U(VI) desorption from loaded Ganoderma Lucidum with 0.2N Na 2 CO 3 as elutant, was found to be rapid with more than 75% recovery occurring in the first five minutes, the specific metal release rate being 0.102 mg/g/min. The equilibrium data fitted to a linearised Freundlich plot and exhibited a near 100% recovery of sorbed U(VI), clearly revealing a cost-effective method of recovery of precious uranium from low level wastewater. (author). 7 refs., 3 figs., 1 tab

  14. Assessment of the underground disposal of tailings

    Energy Technology Data Exchange (ETDEWEB)

    Hutt, N M [Morwijk Enterprises Ltd., (Canada); Morin, K A [Normar Enterprises, (Canada)

    1995-06-01

    The Atomic Energy Control Board (AECB) of Canada is facing the issue of long-term disposal of uranium tailings. One option that has not been examined in sufficient detail for the AECB is the retrieval of tailings from surface impoundments and subsequent placement of those tailings in underground workings of mines. This report is structured like a catalogue of facts and information, with each paragraph presenting some concept, concern, theory, or case study involving the retrieval or placement of tailings. All relevant information, findings, interpretations, conclusions, and recommendations gathered during the course of this study are included. The Table of Contents illustrates the striking number of relevant topics and acts like a flowchart or checklist to ensure that an underground-disposal submission by a mining company has addressed relevant topics. This report explains in detail the implications of disturbing surface-impounded tailings for the purpose of placing only some of the volume underground. The cumulative environmental, safety, and monetary liabilities of such a partial scheme can be discouraging in some cases. (author). 244 refs., 47 tabs., 17 figs.

  15. Assessment of the underground disposal of tailings

    International Nuclear Information System (INIS)

    Hutt, N.M.; Morin, K.A.

    1995-06-01

    The Atomic Energy Control Board (AECB) of Canada is facing the issue of long-term disposal of uranium tailings. One option that has not been examined in sufficient detail for the AECB is the retrieval of tailings from surface impoundments and subsequent placement of those tailings in underground workings of mines. This report is structured like a catalogue of facts and information, with each paragraph presenting some concept, concern, theory, or case study involving the retrieval or placement of tailings. All relevant information, findings, interpretations, conclusions, and recommendations gathered during the course of this study are included. The Table of Contents illustrates the striking number of relevant topics and acts like a flowchart or checklist to ensure that an underground-disposal submission by a mining company has addressed relevant topics. This report explains in detail the implications of disturbing surface-impounded tailings for the purpose of placing only some of the volume underground. The cumulative environmental, safety, and monetary liabilities of such a partial scheme can be discouraging in some cases. (author). 244 refs., 47 tabs., 17 figs

  16. THE ANALYSIS OF INTENSE-DEFORMED MONOLITHIC CONCRETE STRIP STATE OF UNDERGROUND STRUCTURES OF NONCIRCULAR OUTLINE

    Directory of Open Access Journals (Sweden)

    Maria Aleksandrovna Bauer

    2017-12-01

    Full Text Available The research results of intense deformed state (IDS of the crepe and soil massif of un-derground structures having a non-circular outline with a depth of laying up to 50 m in unstable al-luvial rocks with dumps from 0.3 to 0.7 m are presented. The study was carried out by means of modeling the IDS of the soil massif and the hardening concrete of the monolithic support, erected after slaughter moving. To implement the proposed technological solutions ensuring the fixing of underground structures with monolithic concrete, it is necessary to use particularly fast solidifying compounds to exclude the use of temporary crepe. Based on the studies of a number of modifiers, various changes in mechanical properties of the most effective compositions have been established, which are used to simulate the concrete crepe of structures with time-varying characteristics. Purpose: the basis for using resource-saving technology for the construction of underground structures in a non-circular outline in a soil massif. Methods and methodology of the work: the studies were carried out by means of the finite element method (FEM using the optimal design of the experiment. Results: stress distributions were obtained in the hardening concrete crepe structures, stress concentration zones were established, displacement values in the soil massif and their spread on the surface were recieved. Areas of the result application: the results of research work can be used in the design of options for the construction of underground structures.

  17. Underground storage

    Energy Technology Data Exchange (ETDEWEB)

    1965-06-10

    A procedure is described for making an underground storage cavity in a soluble formation. Two holes are drilled, and fluid is pumped into the first hole. This fluid is a non-solute for the formation material. Then pressure is applied to the fluid until the formation is fractured in the direction of the second hole. More non-solute fluid is injected to complete the fracture between the 2 holes. A solute fluid is then circulated between the 2 holes, which results in removal of that part of the formation next to the fracture and the forming of a chamber.

  18. Safety consideration and economic advantage of a new underground nuclear power plant design

    International Nuclear Information System (INIS)

    Lyczkowski, R.W.; Ching, J.T.

    1979-01-01

    A conceptual design of an underground nuclear power plant is proposed to make undergrounding of nuclear reactors not only environmentally desirable but also economically feasible. Expedient to the underground environment, this design capitalizes on the pressure-containing and radiation filtering characteristics of the new underground boundary conditions. Design emphasis is on the containment of a catastrophic accident - that of a reactor vessel rupture caused by external means. The High Capacity Rapid Energy Dissipation Underground Containment (HiC-REDUCE) system which efficiently contains loss-of-coolant accidents (LOCAs) and small break conditions is described. The end product is a radiation-release-proof plant which, in effect, divorces the public from the safety of the reactor. (Auth.)

  19. Cr (VI) remediation by indigenous bacteria in soils contaminated by chromium-containing slag

    International Nuclear Information System (INIS)

    Chai Liyuan; Huang Shunhong; Yang Zhihui; Peng Bing; Huang Yan; Chen Yuehui

    2009-01-01

    Hexavalent chromium (Cr) is a toxic element causing serious environmental threat. Recently, more and more attention is paid to the bio-remediation of Cr (VI) in the contaminated soils. Cr (VI) remediation by indigenous bacteria in soils contaminated by chromium-containing slag at a steel-alloy factory in Hunan Province, China, was investigated in the present study. The results showed that when sufficient nutrients were amended into the contaminated soils, total Cr (VI) concentration declined from the initial value of 462.8 to 10 mg kg -1 at 10 days and the removal rate was 97.8%. Water soluble Cr (VI) decreased from the initial concentration of 383.8 to 1.7 mg kg -1 . Exchangeable Cr (VI) and carbonates-bound Cr (VI) were removed by 92.6% and 82.4%, respectively. Meanwhile, four Cr (VI) resistant bacterial strains were isolated from the soil under the chromium-containing slag. Only one strain showed a high ability for Cr (VI) reduction in liquid culture. This strain was identified as Pannonibacter phragmitetus sp. by gene sequencing of 16S rRNA. X-ray photoelectron spectroscope (XPS) analysis indicated that Cr (VI) was reduced into trivalent chromium. The results suggest that indigenous bacterial strains have potential application for Cr (VI) remediation in the soils contaminated by chromium-containing slag.

  20. Impact of water quality parameters on the sorption of U(VI) onto hematite

    International Nuclear Information System (INIS)

    Zhao Donglin; Wang Xianbiao; Yang Shitong; Guo Zhiqiang; Sheng Guodong

    2012-01-01

    In this study, the sorption of U(VI) from aqueous solution on hematite was studied as a function of various water quality parameters such as contact time, pH, ionic strength, soil humic acid (HA) or fulvic acid (FA), solid content and temperature by using a batch technique. The results demonstrated that the sorption of U(VI) was strongly dependent on ionic strength at pH 6.0 and the sorption was mainly dominated by inner-sphere surface complexation. The presence of HA/FA increases U(VI) sorption at low pH, whereas decreases U(VI) sorption at high pH. The thermodynamic parameters (ΔH 0 , ΔS 0 , and ΔG 0 ) were calculated from the temperature dependent sorption isotherms, and the results suggested that U(VI) sorption was a spontaneous and endothermic process. The results might be important for the application of hematite in U(VI) pollution management. Highlights: ► The sorption of U(VI) was strongly dependent on ionic strength at pH 6.0. ► A positive effect of HA/FA on U(VI) sorption was found at low pH, whereas a negative effect was observed at high pH. ► U(VI) sorption was a spontaneous and endothermic process. ► The results are quite important for the application of hematite in U(VI) pollution management.

  1. Electrochemical processes for the environmental remediation of toxic Cr(VI): A review

    International Nuclear Information System (INIS)

    Jin, Wei; Du, Hao; Zheng, Shili; Zhang, Yi

    2016-01-01

    Highlights: • Recent advances in electrochemical technologies for practical Cr(VI) treatment applications was reviewed. • The mechanism and performance of electrocoagulation, electrochemical reduction, electrodialysis, electro-electrodialysis and electrodeionization were discussed and compared. • The remained challenges and future perspectives were commented. - Abstract: Hexavalent chromium Cr(VI) is extremely toxic and classified as one of the 17 chemicals posing the greatest threat to humans. Large amounts of Cr(VI) compounds are directly or indirectly discharged into the environment, therefore considerable efforts have been made to control the Cr(VI) concentration below the recommended level. It has been demonstrated that electrochemical technique is one of the most efficient and environmental benign approach for the Cr(VI) removal. This review aims at recent advances in electrochemical technology for practical Cr(VI) treatment applications. By using the “clean reagent” of electron, Cr(VI) can be completely eliminated or separated via different electrochemical techniques such as electrocoagulation, electrochemical reduction, electrodialysis, electro-electrodialysis and electrodeionization. Besides, the mechanism and performance of different strategies are commented and compared. The treatment process is largely dependent on variables such as pH, electrode materials, cell configuration and techniques integration. Furthermore, the remained limitation and challenges for the electrochemical Cr(VI) remediation are also discussed.

  2. Structural characterization of the rock mass of the underground mine Oro Descanso

    Directory of Open Access Journals (Sweden)

    Adeoluwa Olajesu Oluwaseyi

    2017-10-01

    Full Text Available In the rocky massif where the Oro Descanso underground mine is located, an assessment was made of the physical-mechanical properties of rocks, cracking and blocking, in order to propose safe tillage measures for underground mining excavations using appropriate empirical methods. From the evaluation made it was concluded that the massif is composed of areas of rocks of different quality: good, fair and poor. It is proposed for the area of good quality to work excavations with complete advance, of free length 1.0-1.5 m, using in the crown the support of cemented anchors of diameter 20 mm, length 3 m and spaced 2.5 m and apply concrete released 50 mm thick. For the zone of bad and regular quality, it is suggested to work in stepwise progression, of free length of 1-3 m and after each blasting, to install in the crown, cemented anchors of diameter 20 mm, length 4-5 m and spacing 1-2 m, placing on the sides metallic mesh, with concrete cast 50-150 mm thick.

  3. Bulk solubility and speciation of plutonium(VI) in phosphate-containing solutions

    International Nuclear Information System (INIS)

    Weger, H.T.; Okajima, S.; Cunnane, J.C.; Reed, D.T.

    1992-01-01

    The solubility and speciation of Pu(VI) with phosphate as a function of pH was investigated to determine the ability of phosphate to act as an actinide getter. The general properties were first investigated and are reported here with the goal of performing more quantitative experiments in the future. Solubility was approached from oversaturation at initial pH = 4, 10 and 13.4. Absorption spectra were recorded, the solution filtered and the filtrate counted. Absorption spectra were obtained at varying phosphate concentrations and at pH of 2.7 to 11.9. The effect of complexation on the 833 mn Pu(VI) band was characterized. Evidence for three phosphate complexes was obtained for pH -5 to 10 -6 M Pu(VI) was measured in the filtrate at pH ≤ 10 that were passed through a 50 mn filter. Pu(VI) complexes with phosphate over hydroxide at pH ≤ 11.6, but at pH ≥ 11.9, only hydrolyzed Pu(VI) was detected. At pH = 12, the concentration of Pu(VI) was as high as 10 -4 M

  4. Bacillus lichenformis γ-glutamyl exopolymer: Physicochemical characterization and U(VI) interaction

    International Nuclear Information System (INIS)

    He, L.M.; Neu, M.P.; Vanderberg, L.A.

    2000-01-01

    Complexation by microbially produced exopolymers may significantly impact the environmental mobility and toxicity of metals. This study focused on the conformational structure of the bacterial exopolymer, γ-D-poly(glutamic acid) and its interactions with U(VI) examined using ATR-FTIR spectroscopy. Solution pH, polymer concentration, and ionic strength affected the conformation of the exopolymer, and U(VI) binding was monitored. At low pH, low concentration, or low ionic strength, this exopolymer exists in an α-helical conformation, while at high pH, concentration, or ionic strength the exopolymer exhibits a β-sheet structure. The change in exopolymer conformation is likely to influence the number and nature of exposed surface functional groups, sites most responsible for metal complexation. The authors found the polyglutamate capsule binds U(VI) in a binuclear, bidentate fashion; in contrast the glutamate monomer forms a mononuclear, bidentate complex with U(VI). The apparent polynuclear binding of U(VI) may induce β-sheet structure formation provided the U(VI) Concentration is sufficiently high

  5. Pro and con decision criteria to underground nuclear power plants

    International Nuclear Information System (INIS)

    Buchhardt, F.

    1981-01-01

    In general, basic design criteria for underground siting define increased safety margins which are mostly step-wise augmentated. The larger those postulated additional impacts become, the more the general concept might already be previously determined. Depending on site availability in general two ways may be practised - the berm-contained concept as well as mined rock caverns. According to the present technical feasibility the cut-and-cover burial seems to be favoured more. If increased external (artificial) impacts are postulated underground facilities have considerable advantages since the earth coverage provides an excellent stopping medium. In case of internal influences the features suggested mostly are additional pressure relief systems which cannot be considered typical for undergrounding. The problem of the access-way sealing is a key-point of a 'real' supplemental underground containment. With a very high safety degree a reliable closure of the penetrations must be guaranteed in case extreme external as well as internal events occur. To come to a final conclusion wheter the benefits or penalties predominate, valuation criteria and matrices are elaborated from the view of different initial points. At this time period it still seems too early to give a definite judgement of pro or con for the underground concept. (orig./HP)

  6. Radioactivity source terms for underground engineering application

    Energy Technology Data Exchange (ETDEWEB)

    Tewes, H A [Lawrence Radiation Laboratory, Livermore, CA (United States)

    1969-07-01

    The constraints on nuclide production are usually very similar in any underground engineering application of nuclear explosives. However, in some applications the end product could be contaminated unless the proper nuclear device is used. This fact can be illustrated from two underground engineering experiments-Gasbuggy and Sloop. In the Gasbuggy experiment, appreciable tritium has been shown to be present in the gas currently being produced. However, in future gas stimulation applications (as distinct from experiments), a minimum production of tritium by the explosive is desirable since product contamination by this nuclide may place severe limitations on the use of the tritiated gas. In Sloop, where production of copper is the goal of the experiment, product contamination would not be caused by tritium but could result from other nuclides: Thus, gas stimulation could require the use of fission explosives while the lower cost per kiloton of thermonuclear explosives could make them attractive for ore-crushing applications. Because of this consideration, radionuclide production calculations must be made for both fission and for thermonuclear explosives in the underground environment. Such activation calculations materials of construction are performed in a manner similar to that described in another paper, but radionuclide production in the environment must be computed using both fission neutron and 14-MeV neutron sources in order to treat the 'source term' problem realistically. In making such computations, parameter studies including the effects of environmental temperature, neutron shielding, and rock types have been carried out. Results indicate the importance of carefully evaluating the radionuclide production for each individual underground engineering application. (author)

  7. Radioactivity source terms for underground engineering application

    International Nuclear Information System (INIS)

    Tewes, H.A.

    1969-01-01

    The constraints on nuclide production are usually very similar in any underground engineering application of nuclear explosives. However, in some applications the end product could be contaminated unless the proper nuclear device is used. This fact can be illustrated from two underground engineering experiments-Gasbuggy and Sloop. In the Gasbuggy experiment, appreciable tritium has been shown to be present in the gas currently being produced. However, in future gas stimulation applications (as distinct from experiments), a minimum production of tritium by the explosive is desirable since product contamination by this nuclide may place severe limitations on the use of the tritiated gas. In Sloop, where production of copper is the goal of the experiment, product contamination would not be caused by tritium but could result from other nuclides: Thus, gas stimulation could require the use of fission explosives while the lower cost per kiloton of thermonuclear explosives could make them attractive for ore-crushing applications. Because of this consideration, radionuclide production calculations must be made for both fission and for thermonuclear explosives in the underground environment. Such activation calculations materials of construction are performed in a manner similar to that described in another paper, but radionuclide production in the environment must be computed using both fission neutron and 14-MeV neutron sources in order to treat the 'source term' problem realistically. In making such computations, parameter studies including the effects of environmental temperature, neutron shielding, and rock types have been carried out. Results indicate the importance of carefully evaluating the radionuclide production for each individual underground engineering application. (author)

  8. Selectivity enhancement of phosphate based functional polymeric gels towards Uranium(VI) using ion imprinting

    International Nuclear Information System (INIS)

    Chappa, Sankararao; Agarwal, Chhavi; Pandey, A.K.

    2015-01-01

    The imprinting of gel containing polymer chains of ethylene glycol methacrylate phosphate (EGMP) for U(VI) ions were carried out. The U(VI) imprinting has been carried out in pure EGMP and in EGMP: poly(ethylene glycol) methacrylate (PEGMA) = 1:9 composition. Complexation of the monomer with template (U(VI)) followed by polymerization have been used to imprint the U(VI) onto the polymer chains. The comparison of uptake studies of U(VI) and Pu(IV) at 3 M HNO 3 shows increased selectivity of U(VI) relative to Pu(IV) for both the gel compositions. The less uptake of U(VI) for imprinted EGMP:PEGMA gel relative to pure imprinted EGMP gel at tracer level can be possibly due to the requirement of two EGMP units in the vicinity for U(VI) complexation. (author)

  9. Clinical evaluation of complete solo surgery with the "ViKY®" robotic laparoscope manipulator.

    Science.gov (United States)

    Takahashi, Masahiro; Takahashi, Masanori; Nishinari, Naoto; Matsuya, Hideki; Tosha, Tsutomu; Minagawa, Yukihiro; Shimooki, Osamu; Abe, Tadashi

    2017-02-01

    Advancement in both surgical technique and medical equipment has enabled solo surgery. ViKY ® Endoscope Positioning System (ViKY ® ) is a robotic system that remotely controls an endoscope and provides direct vision control to the surgeon. Here, we report our experience with ViKY ® -assisted solo surgery. We retrospectively examined 25 cases of solo surgery TAPP with ViKY ® . ViKY ® was setup by the surgeon alone, and the setup duration was determined as the time at which the side rail was positioned and that when the endoscope was installed. For assessing the control unit, the number of false movements was counted. We compared the operative results between ViKY ® -assisted solo surgery TAPP and the conventional method with an assistant. The average time to set up ViKY ® was 7.9 min. The average number of commands for ViKY ® during surgery was 98.3, and the average number of errors and no response of control unit was 7.9. The mean duration of surgery was 136 min for the ViKY ® group, including the setup time, and 117 min for the conventional method. No case required an assistant during the operation. There was also no difference between the two groups with regard to postoperative complications and the rate of recurrence. ViKY ® proved reliable in recognizing orders with very few failures, and the operations were performed safely and were comparable to the conventional operations with assistants. Solo surgery with ViKY ® was beneficial in this clinical evaluation.

  10. Conceptual study on deep-underground energy generation base

    International Nuclear Information System (INIS)

    Hayano, M.; Okawa, T.

    1992-01-01

    Mitsubishi Atomic Power Industries, Inc. (MAPI) and Taisei Corporation have started a conceptual study on a deep-underground energy generation base for future cities in the 21st century around the metropolitan area, which will be increasingly important from viewpoints of the autonomy and sharing of the energy supply to the future cities. The energy generation base consists of a gas cooled reactor with naturally safety features as the energy source, an electric generation base using the Alkali Metal Thermo-electric Converter (AMTEC), a hydrogen production plant with the Solid Polymer Electrolyte (SPE), a hydrogen storage plant with the Metal Hydride (MH), and a desalination plant. This paper describes a concept of the energy generation base and the structure in the deep-underground, in soft soil, then the basic system of each plant, and finally discusses the feasibility of the deep-underground energy generation base. (author)

  11. 75 FR 17529 - High-Voltage Continuous Mining Machine Standard for Underground Coal Mines

    Science.gov (United States)

    2010-04-06

    ... High-Voltage Continuous Mining Machine Standard for Underground Coal Mines AGENCY: Mine Safety and... of high-voltage continuous mining machines in underground coal mines. It also revises MSHA's design...-- Underground Coal Mines III. Section-by-Section Analysis A. Part 18--Electric Motor-Driven Mine Equipment and...

  12. Bioaccumulation and subcellular partitioning of Cr(III) and Cr(VI) in the freshwater green alga Chlamydomonas reinhardtii

    Energy Technology Data Exchange (ETDEWEB)

    Aharchaou, Imad [Laboratoire Interdisciplinaire des Environnements Continentaux, UMR 7360, Université de Lorraine and CNRS, 8 rue du Général Delestraint, 57070 Metz (France); Rosabal, Maikel; Liu, Fengjie [Institut National de la Recherche Scientifique, Centre Eau Terre Environnement (INRS-ETE), 490 rue de la Couronne, Québec (Québec) G1K 9A9 (Canada); Battaglia, Eric; Vignati, Davide A.L. [Laboratoire Interdisciplinaire des Environnements Continentaux, UMR 7360, Université de Lorraine and CNRS, 8 rue du Général Delestraint, 57070 Metz (France); Fortin, Claude, E-mail: claude.fortin@ete.inrs.ca [Institut National de la Recherche Scientifique, Centre Eau Terre Environnement (INRS-ETE), 490 rue de la Couronne, Québec (Québec) G1K 9A9 (Canada)

    2017-01-15

    first time, that both Cr(III) and Cr(VI) have similar fate within algal cells, supporting the tenet that a unique redox form occurs within cells.

  13. Bioaccumulation and subcellular partitioning of Cr(III) and Cr(VI) in the freshwater green alga Chlamydomonas reinhardtii

    International Nuclear Information System (INIS)

    Aharchaou, Imad; Rosabal, Maikel; Liu, Fengjie; Battaglia, Eric; Vignati, Davide A.L.; Fortin, Claude

    2017-01-01

    first time, that both Cr(III) and Cr(VI) have similar fate within algal cells, supporting the tenet that a unique redox form occurs within cells.

  14. Research on Joint Parameter Inversion for an Integrated Underground Displacement 3D Measuring Sensor

    Directory of Open Access Journals (Sweden)

    Nanying Shentu

    2015-04-01

    Full Text Available Underground displacement monitoring is a key means to monitor and evaluate geological disasters and geotechnical projects. There exist few practical instruments able to monitor subsurface horizontal and vertical displacements simultaneously due to monitoring invisibility and complexity. A novel underground displacement 3D measuring sensor had been proposed in our previous studies, and great efforts have been taken in the basic theoretical research of underground displacement sensing and measuring characteristics by virtue of modeling, simulation and experiments. This paper presents an innovative underground displacement joint inversion method by mixing a specific forward modeling approach with an approximate optimization inversion procedure. It can realize a joint inversion of underground horizontal displacement and vertical displacement for the proposed 3D sensor. Comparative studies have been conducted between the measured and inversed parameters of underground horizontal and vertical displacements under a variety of experimental and inverse conditions. The results showed that when experimentally measured horizontal displacements and vertical displacements are both varied within 0 ~ 30 mm, horizontal displacement and vertical displacement inversion discrepancies are generally less than 3 mm and 1 mm, respectively, under three kinds of simulated underground displacement monitoring circumstances. This implies that our proposed underground displacement joint inversion method is robust and efficient to predict the measuring values of underground horizontal and vertical displacements for the proposed sensor.

  15. cis-dioxomolybdenum(VI)-(ONO)

    Indian Academy of Sciences (India)

    Various ONO type Schiff base ligands L(H)2 used for the preparation of ... and derivatives.6–33 Depending on the method of prepa- ration .... HCl. Scheme 6. Synthesis of a Mo(VI) Schiff base complexe by selective inversion at C–1 carbon of a ...

  16. Unified communication and standardized data exchange for underground mines; Einheitliche, standardisierte Kommunikation zur Effizienzsteigerung von Bergwerken

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, C. [Embigence GmbH, Ladbergen (Germany)

    2006-11-07

    Communication in many forms during the past ten years has changed our daily life: Cellphone technology as well as the Internet are just two examples. In the same way, modern network based communication now starts to change the way how underground mines are run: The lack of proper communication traditionally caused downtime and production loss. In the future, mine communication will be crucial for efficiency and profitability of underground operations. This enables intelligent machines to be used like e.g. a machine server equipped drill rig at LKAB or highly advanced, networked monorail systems at DSK. Standardized communication and information exchange is a basis for using three dimensional visualization tools to support decision finding. The paper explains these visions and goals for the future and explains the feasibility by two running example applications. (orig.)

  17. Radon-222 signatures of natural ventilation regimes in an underground quarry.

    Science.gov (United States)

    Perrier, Frédéric; Richon, Patrick; Crouzeix, Catherine; Morat, Pierre; Le Mouël, Jean Louis

    2004-01-01

    Radon-222 activity concentration has been monitored since 1999 in an underground limestone quarry located in Vincennes, near Paris, France. It is homogeneous in summer, with an average value of 1700 Bq m(-3), and varies from 730 to 1450 Bq m(-3) in winter, indicating natural ventilation with a rate ranging from 0.5 to 2.4 x 10(-6) s(-1) (0.04-0.22 day(-1)). This hypothesis is supported by measurements in the vertical access pit where, in winter, a turbulent air current produces a stable radon profile, smoothly decreasing from 700 Bq m(-3) at 20 m depth to 300 Bq m(-3) at surface. In summer, a thermal stratification is maintained in the pit, but the radon-222 concentration jumps repeatedly between 100 and 2000 Bq m(-3). These jumps are due to atmospheric pressure pumping, which induces ventilation in the quarry at a rate of about 0.1 x 10(-6) s(-1) (0.009 day(-1)). Radon-222 monitoring thus provides a dynamical characterisation of ventilation regimes, which is important for the assessment of the long-term evolution of underground systems.

  18. Multi-crystalline II-VI based multijunction solar cells and modules

    Science.gov (United States)

    Hardin, Brian E.; Connor, Stephen T.; Groves, James R.; Peters, Craig H.

    2015-06-30

    Multi-crystalline group II-VI solar cells and methods for fabrication of same are disclosed herein. A multi-crystalline group II-VI solar cell includes a first photovoltaic sub-cell comprising silicon, a tunnel junction, and a multi-crystalline second photovoltaic sub-cell. A plurality of the multi-crystalline group II-VI solar cells can be interconnected to form low cost, high throughput flat panel, low light concentration, and/or medium light concentration photovoltaic modules or devices.

  19. Evaluation of the feasibility, economic impact, and effectiveness of underground nuclear power plants. Final technical report

    International Nuclear Information System (INIS)

    1978-05-01

    Information on underground nuclear power plants is presented concerning underground nuclear power plant concepts; public health impacts; technical feasibility of underground concepts; economic impacts of underground construction; and evaluation of related issues

  20. 47 CFR 32.2422 - Underground cable.

    Science.gov (United States)

    2010-10-01

    ... FOR TELECOMMUNICATIONS COMPANIES Instructions for Balance Sheet Accounts § 32.2422 Underground cable... manholes and ducts in connection with construction work and the cost of permits and privileges for the...

  1. State Certification of Underground Storage Tanks

    National Research Council Canada - National Science Library

    Granetto, Paul

    1998-01-01

    .... The audit was performed in response to a Senate Armed Services Committee inquiry about whether state environmental regulatory agencies would be able to certify that DoD underground storage tanks...

  2. The three-dimensional shapes of underground coal miners' feet do not match the internal dimensions of their work boots.

    Science.gov (United States)

    Dobson, Jessica A; Riddiford-Harland, Diane L; Bell, Alison F; Steele, Julie R

    2018-04-01

    Mining work boots provide an interface between the foot and the ground, protecting and supporting miners' feet during lengthy coal mining shifts. Although underground coal miners report the fit of their work boots as reasonable to good, they frequently rate their boots as uncomfortable, suggesting that there is a mismatch between the shape of their feet and their boots. This study aimed to identify whether dimensions derived from the three-dimensional scans of 208 underground coal miners' feet (age 38.3 ± 9.8 years) differed from the internal dimensions of their work boots. The results revealed underground coal miners wore boots that were substantially longer than their feet, possibly because boots available in their correct length were too narrow. It is recommended boot manufacturers reassess the algorithms used to create boot lasts, focusing on adjusting boot circumference at the instep and heel relative to increases in foot length. Practitioner Summary: Fit and comfort ratings suggest a mismatch between the shape of underground coal miners' feet and their boots exists. This study examined whether three-dimensional scans of 208 miners' feet differed from their boot internal dimensions. Miners wore boots substantially longer than their feet, possibly due to inadequate width.

  3. THE UNDERGROUND ECONOMY,THE CORRUPTION . A WAY OF MANIFESTING THE FISCAL EVASION

    Directory of Open Access Journals (Sweden)

    Din Alina Valentina

    2012-12-01

    Full Text Available Fiscal evasion is mainly found within the underground economy, came to the specialists’ attention within the 1960s, moment in which it took a great extent. The main cause which leads to activities within the underground economy is represented by the increase of direct taxes, which has the largest influence, followed by the intensity of the regulations and the complexity of the fiscal system. The imposed taxes determine more and more countries to act within the underground economy, as long as there is not a proper offer of public goods and infrastructure. In his study, Vito Tanzi indicated as the main cause of the underground economy the level of taxes.(Tanzi,1983:11-15 He adds the instability of the legislative framework, legislative restrictions imposed within certain states, corruption and bureaucracy. Corruption and the activities specific to the underground economy are realities all the states confront with. Gathering information about the dimensions of corruption and the connection with the underground economy proves to be a task which is impossible to achieve, because all the people involved within these mechanisms prefer not to be identified. Even if the underground economy and corruption are considered as being twins, the questions which appear are: who needs them and who fights against them? Theoretically speaking, corruption and the underground economy can be complementary or substitutable.The anticorruption efforts have to focus on a real reform of the administrative system, whereas the citizen’s perception on corruption is mainly based on his personal experiences in direct connection with the state institutions. Both the public sector as well as the private sector should become more responsible, so that the public institutions to be able to carry out their obligations under integrity conditions and without external pressure or implication. Corruption attracts the economic agents to the underground economy, which leads

  4. 30 CFR 75.1312 - Explosives and detonators in underground magazines.

    Science.gov (United States)

    2010-07-01

    ... magazines. 75.1312 Section 75.1312 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF... Blasting § 75.1312 Explosives and detonators in underground magazines. (a) The quantity of explosives kept..., explosives and detonators taken underground shall be kept in— (1) Separate, closed magazines at least 5 feet...

  5. 30 CFR 819.21 - Auger mining: Protection of underground mining.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Auger mining: Protection of underground mining. 819.21 Section 819.21 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT... STANDARDS-AUGER MINING § 819.21 Auger mining: Protection of underground mining. Auger holes shall not extend...

  6. Underground economy modelling: simple models with complicated dynamics

    OpenAIRE

    Albu, Lucian-Liviu

    2003-01-01

    The paper aims to model the underground economy using two different models: one based on the labor supply method and a generalized model for the allocation of time. The model based on the labor supply method is conceived as a simulating one in order to determine some reasonable thresholds of the underground sector extension based only on the available macroeconomic statistical data. The generalized model for the allocation of time is a model based on direct approach which estimates the underg...

  7. THE UNDERGROUND ECONOMY FROM THE PERSPECTIVE OF THE TRIAD ECONOMICS, SOCIOLOGY, PSYCHOLOGY

    Directory of Open Access Journals (Sweden)

    Corneliu\tSorin\tBAICU

    2015-06-01

    Full Text Available Underground economy, in view of researchers, economists and jurists, is a theoretical complex construct, a phenomenon with profound social and economic reverberations. This study argues multidisciplinary integrative the sociological, psychological and socio-psychological approach of underground economy. The premises of this study are given by methodological individualism and rational choice theory through building in neoclassical version of Homo economicus able to interact in a multidisciplinary and multifaceted manner with the area of social sciences. For the nonce, we submit to analysis an integrative model of Homo Oeconimicus with Homo Sociologicus, aggregated with elements of social psychology. Synergistic effects of this integrative approach consist of the ability to give an answer as relevant on symptoms and forms of deviant behavior and thus to explain the development of underground economy. The finality of this paper, starting from the stated premises, resides in the explanation and analysis of deviant behavior in the framework of the morphology and causality of underground economy. Deviant behavior in the context of our analysis reveals the coherence perspective on the following issues: anatomy and etiology of underground economy (informal and underground activities, illegal labor, tax fraud, etc.; attitude towards rules, society and the state (tax mentality, tax morality, moral conscience; tax compliance or non-compliance (willingness to pay tax liabilities. This paper is intended to constitute a pleading for an interdependent approach, multi-causal and interdisciplinary of underground economy

  8. FK506-binding protein 10 (FKBP10) regulates lung fibroblast migration via collagen VI synthesis.

    Science.gov (United States)

    Knüppel, Larissa; Heinzelmann, Katharina; Lindner, Michael; Hatz, Rudolf; Behr, Jürgen; Eickelberg, Oliver; Staab-Weijnitz, Claudia A

    2018-04-19

    In idiopathic pulmonary fibrosis (IPF), fibroblasts gain a more migratory phenotype and excessively secrete extracellular matrix (ECM), ultimately leading to alveolar scarring and progressive dyspnea. Here, we analyzed the effects of deficiency of FK506-binding protein 10 (FKBP10), a potential IPF drug target, on primary human lung fibroblast (phLF) adhesion and migration. Using siRNA, FKBP10 expression was inhibited in phLF in absence or presence of 2ng/ml transforming growth factor-β1 (TGF-β1) and 0.1mM 2-phosphoascorbate. Effects on cell adhesion and migration were monitored by an immunofluorescence (IF)-based attachment assay, a conventional scratch assay, and single cell tracking by time-lapse microscopy. Effects on expression of key players in adhesion dynamics and migration were analyzed by qPCR and Western Blot. Colocalization was evaluated by IF microscopy and by proximity ligation assays. FKBP10 knockdown significantly attenuated adhesion and migration of phLF. Expression of collagen VI was decreased, while expression of key components of the focal adhesion complex was mostly upregulated. The effects on migration were 2-phosphoascorbate-dependent, suggesting collagen synthesis as the underlying mechanism. FKBP10 colocalized with collagen VI and coating culture dishes with collagen VI, and to a lesser extent with collagen I, abolished the effect of FKBP10 deficiency on migration. These findings show, to our knowledge for the first time, that FKBP10 interacts with collagen VI and that deficiency of FKBP10 reduces phLF migration mainly by downregulation of collagen VI synthesis. The results strengthen FKBP10 as an important intracellular regulator of ECM remodeling and support the concept of FKBP10 as drug target in IPF.

  9. 24 CFR 972.115 - Relationship between required conversions and HOPE VI developments.

    Science.gov (United States)

    2010-04-01

    ... conversions and HOPE VI developments. 972.115 Section 972.115 Housing and Urban Development Regulations... Relationship between required conversions and HOPE VI developments. HUD actions to approve or deny proposed HOPE VI revitalization plans must be consistent with the requirements of this subpart. Developments...

  10. Enhanced Cr(VI) removal by polyethylenimine- and phosphorus-codoped hierarchical porous carbons.

    Science.gov (United States)

    Chen, Shixia; Wang, Jun; Wu, Zeliang; Deng, Qiang; Tu, Wenfeng; Dai, Guiping; Zeng, Zheling; Deng, Shuguang

    2018-08-01

    The amino- and phosphorus-codoped (N,P-codoped) porous carbons derived from oil-tea shells were facilely fabricated through a combination of phosphoric acid (H 3 PO 4 ) activation and amino (polyethylenimine, PEI) modification method. The as-synthesized carbon adsorbents were systematically characterized and evaluated for Cr(VI) removal in aqueous solutions. The relationship between adsorbent properties and adsorption behaviors was illustrated. Moreover, the influences of contact time, initial Cr(VI) concentration, pH, coexisting anions and temperature were also investigated. The adsorption behavior of Cr(VI) could be perfectly described by the pseudo-second-order kinetic model and Sips adsorption model. The maximum adsorption capacity of Cr(VI) on the carbon adsorbents synthesized in this work was 355.0 mg/g, and this excellent Cr(VI) capacity could be sustained with other coexisting anions. In addition to high surface area and suitable pore size distribution, the high Cr(VI) removal capacity is induced by rich heteroatoms incorporation and the Cr(VI) removal mechanism was clearly illustrated. Furthermore, the continuous column breakthrough experiment on obtained N,P-codoped carbon was conducted and well fitted by the Thomas model. This work revealed that PEI modification and P-containing groups could significantly enhance Cr(VI) adsorption capacity and make these N,P-codoped biomass-derived carbons potent adsorbents in practical water treatment applications. Copyright © 2018 Elsevier Inc. All rights reserved.

  11. Alternative utilization of underground spaces with abandoned mine openings

    Energy Technology Data Exchange (ETDEWEB)

    Chung, So Keul; Cho, Won Jai; Han, Kong Chang; Choi, Sung Oong [Korea Institute of Geology Mining and Materials, Taejon (Korea)

    1998-12-01

    Utilization of the openings of the abandoned mines could be planned by the principal parameters such as location and geotechnical impact. The local governments have not only to lead the each stage of the utilization project from the very beginning of conceptual design up to the construction stage, but also to promote the project for the development of public purpose. The possible tentative candidates for the utilization of the abandoned mine openings which are supported by the local governments could be summarized as follows. a. The Gahak mine of Kwangmyung, Kyunggi: The mine caverns which have been served as the storage of the pickled fishes, could be reexcavated by taking into consideration the geotechnical parameters for the public use such as: 1) Training center for the youth, 2) Fermentation and storehouse of marine products, 3) Sightseeing resort, 4) Sports and leisure complex, 5) Underground parking lot, 6) Underground shopping mall and chilled room storage, 7) Library, concert hall and museum. b. Hamtae mine of Taebaek, Kangwon: The Hambaek main haulage way and its shaft should be investigated in detail in order to find out a possible use as the underground challenging park of the coal mining operation. c. Mines of Boryung and Hongsung, Chungnam: Lots of mine caverns have been used as the storehouse for the pickled shrimp. However, they have to be promoted to a large scale industries. d. Imgok mine of Kwangju and Palbong mine of Jeongeup, Chunbuk: Mine caverns which have been used as the storehouse of pickles, need a detailed investigation for alternative promotion. e. Yongho mine of Pusan Dalsung mine of Taegu: Both of the mines are located near metropolitan communities. Reconstruction of the old mine caverns of the Yongho mine is highly recommended for a public use. The caverns of the Dalsung mine could be utilized as the storage facilities. Detailed geotechnical survey and sit investigation could be suggested to design the recommended facilities for both

  12. A combined wet chemistry and EXAFS study of U(VI) uptake by cementitious materials

    International Nuclear Information System (INIS)

    Wieland, E.; Harfouche, M.; Tits, J.; Kunz, D.; Daehn, R.; Fujita, T.; Tsukamoto, M.

    2006-01-01

    The sorption behaviour and speciation of U(VI) in cementitious systems was investigated by a combination of wet chemistry experiments and synchrotron-based X-ray absorption spectroscopy (XAS) measurements. Radiotracer studies using 233 U were carried out on hardened cement paste (HCP) and calcium silicate hydrates (C-S-H), which are the major constituents of HCP, to determine the uptake kinetics and sorption isotherms. C-S-H phases were synthesized using different methods for solid phase preparation, which enabled us to study the U(VI) uptake by different types of C-S-H phases and a wide range of Ca/Si compositions, and to distinguish U(VI) sorption on the surface of C-S-H from U(VI) incorporation into the structure. XAS measurements were performed using U(VI) loaded HCP and C-S-H materials (sorption and co-precipitation samples) to gain structural information on the U(VI) speciation in these systems, i.e., the type and number of neighbouring atoms, and bond distances. Examples of studies that have utilized XAS to characterize U(VI) speciation in cementitious systems are still rare, and to the best of our knowledge, detailed XAS investigations of the U(VI)/C-S-H system are lacking. The results obtained from the combined use of wet chemical and spectroscopic techniques allow mechanistic models of the immobilization process to be proposed for cementitious waste forms containing low and high U(VI) inventories. In the latter case U(VI) immobilization is controlled by a solubility-limiting process with the U(VI) mineral predominantly formed under the conditions prevailing in cementitious systems. At low U(VI) concentrations, however, U(VI) appears to be predominantly bound onto C-S-H phases. The coordination environment of U(VI) taken up by C-S-H was found to resemble that of U(VI) in uranophane. A mechanistic understanding of the U(VI) binding by cementitious materials will allow more detailed and scientifically well founded predictions of the retention of

  13. Contribution of extracellular polymeric substances from Shewanella sp. HRCR-1 biofilms to U(VI) immobilization.

    Science.gov (United States)

    Cao, Bin; Ahmed, Bulbul; Kennedy, David W; Wang, Zheming; Shi, Liang; Marshall, Matthew J; Fredrickson, Jim K; Isern, Nancy G; Majors, Paul D; Beyenal, Haluk

    2011-07-01

    The goal of this study was to quantify the contribution of extracellular polymeric substances (EPS) to U(VI) immobilization by Shewanella sp. HRCR-1. Through comparison of U(VI) immobilization using cells with bound EPS (bEPS) and cells with minimal EPS, we show that (i) bEPS from Shewanella sp. HRCR-1 biofilms contribute significantly to U(VI) immobilization, especially at low initial U(VI) concentrations, through both sorption and reduction; (ii) bEPS can be considered a functional extension of the cells for U(VI) immobilization and they likely play more important roles at lower initial U(VI) concentrations; and (iii) the U(VI) reduction efficiency is dependent upon the initial U(VI) concentration and decreases at lower concentrations. To quantify the relative contributions of sorption and reduction to U(VI) immobilization by EPS fractions, we isolated loosely associated EPS (laEPS) and bEPS from Shewanella sp. HRCR-1 biofilms grown in a hollow fiber membrane biofilm reactor and tested their reactivity with U(VI). We found that, when reduced, the isolated cell-free EPS fractions could reduce U(VI). Polysaccharides in the EPS likely contributed to U(VI) sorption and dominated the reactivity of laEPS, while redox active components (e.g., outer membrane c-type cytochromes), especially in bEPS, possibly facilitated U(VI) reduction.

  14. Sorption of chromium (VI) by Mg/Fe hydrotalcite type compunds

    Energy Technology Data Exchange (ETDEWEB)

    García-Sosa, I., E-mail: irma.garcia@inin.gob.mx; Cabral-Prieto, A., E-mail: agustin.cabral@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Departamento de Química (Mexico); Nava, N., E-mail: tnava@imp.mx; Navarrete, J. [Instituto Mexicano del Petróleo (Mexico); Olguín, M. T., E-mail: teresa.olguin@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Departamento de Química (Mexico); Escobar, Luis, E-mail: luis.escobar@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Departamento de Física (Mexico); López-Castañares, R., E-mail: rlc@anuies.mx; Olea-Cardoso, O., E-mail: olc@anuies.mx [Universidad Autónoma del Edo. de México, Facultad de Química (Mexico)

    2015-06-15

    The synthesis by co-precipitation and characterization by X-ray diffraction, Raman and Mössbauer spectroscopies of Mg-Fe-hydrotalcite compounds, and their sorption capacities for Cr(VI) in aqueous media were carried out. The average sorption capacity of Cr(VI) for the non-thermal treated samples was of 6.2 mg/g. The ferrihydrite was omnipresent in all prepared hydrotalcite samples. A brief discussion is made on the role of both the hydrotalcite and ferrihydrite for removing such amount of Cr(VI)

  15. Uranium(VI) retention on quartz and kaolinite. Experiments and modelling

    International Nuclear Information System (INIS)

    Mignot, G.

    2001-01-01

    The behaviour of uranium in the geosphere is an important issue for safety performance assessment of nuclear waste repositories, or in the context of contaminated sites due to mining activity related to nuclear field. Under aerobic conditions, the fate of uranium is mainly governed by the ability of minerals to sorb U(VI) aqueous species. Hence, a thorough understanding of U(VI) sorption processes on minerals is required to provide a valuable prediction of U(VI) migration in the environment. In this study, we performed sorption/desorption experiments of U(VI) on quartz and kaolinite, for systems favouring the formation in solution (i) of UO 2 2+ and monomeric hydrolysis products or (ii) of di-/tri-meric uranyl aqueous species, and / or U(VI)-colloids or UO 2 (OH) 2 precipitates, or (iii) of uranyl-carbonate complexes. Particular attention was paid to determine the surface characteristics of the solids and their modification due to dissolution/precipitation processes during experiments. A double layer surface complexation model was applied to our experimental data in order to derive surface complexation equilibria and intrinsic constants which allow a valuable description of U(VI) retention over a wide range of pH, ionic strength, initial concentration of uranium [0.1-10μM] and solid - solution equilibration time. U(VI) sorption on quartz was successfully modeled by using two sets of adsorption equilibria, assuming (i) the formation of the surface complexes SiOUO 2 + , SiOUO 2 OH and SiO(UO 2 ) 3 (OH) 5 , or (ii) the formation of the mono-dentate complex SiO(UO 2 ) 3 (OH) 5 and of the bidentate complex (SiO) 2 UO 2 . Assumptions on the density of each type of surface sites of kaolinite and on their acid-base properties were made from potentiometric titrations of kaolinite suspensions. We proposed on such a basis a set of surface complexation equilibria which accounts for U(VI) uptake on kaolinite over a wide range of chemical conditions, with aluminol edge sites as

  16. Shape and Reinforcement Optimization of Underground Tunnels

    Science.gov (United States)

    Ghabraie, Kazem; Xie, Yi Min; Huang, Xiaodong; Ren, Gang

    Design of support system and selecting an optimum shape for the opening are two important steps in designing excavations in rock masses. Currently selecting the shape and support design are mainly based on designer's judgment and experience. Both of these problems can be viewed as material distribution problems where one needs to find the optimum distribution of a material in a domain. Topology optimization techniques have proved to be useful in solving these kinds of problems in structural design. Recently the application of topology optimization techniques in reinforcement design around underground excavations has been studied by some researchers. In this paper a three-phase material model will be introduced changing between normal rock, reinforced rock, and void. Using such a material model both problems of shape and reinforcement design can be solved together. A well-known topology optimization technique used in structural design is bi-directional evolutionary structural optimization (BESO). In this paper the BESO technique has been extended to simultaneously optimize the shape of the opening and the distribution of reinforcements. Validity and capability of the proposed approach have been investigated through some examples.

  17. WASTAGE OF UNDERGROUND WATER - STEPS TOWARDS A TRAP?

    Directory of Open Access Journals (Sweden)

    Shibabrata Pattanayak

    2015-06-01

    Full Text Available Underground water is used indiscriminately for the purposes like agriculture, serving purposes of urban people, cold drink and mineral water manufacturing etc. As a matter of policy, the rural areas are supplied with underground water in India without considering the factors like actual requirement of water in a particular area, season of scarcity of water etc. It is very common to see the ever open taps of water supplying lines in rural India thronging water continuously and nobody is there to use it. The discharge rate of underground water is far more than the charging rate. This may lead to a very serious condition of water scarcity in near future. Various steps like holding of rain water in the water bodies, selection of crop with requirement of lesser amount of water during the dry months as well as use of Forward Osmosis (FO technology for Cold drinks or Bottled Drinking Water manufacturing from the sea water are advocated.

  18. Welcome to USA 15, the first large underground hall for the LHC

    CERN Multimedia

    2001-01-01

    The first of the four huge underground halls for LHC is ready. USA 15 will be the service hall for ATLAS. It has taken three years to finish the first underground hall for LHC. It is 62 metres long and 20 metres diameter. USA 15 could be called the 'new world' for LHC construction. Although the acronym has nothing to do with the United States. In the terminology of the underground construction for the future accelerator, USA stands for Underground Service ATLAS. This is the first of the four big underground halls for LHC to be finished. Wednesday 8 August, it was officially handed over to the ST division by the collaboration of contractors and consultants who carried out the work. These are CCC (CERN civil contractors) composed of the companies Porr-Asdag (Austria), Baresel (Germany) and Zschokke-Locher (Switzerland) and the consultant EDF-KP composed of EDF (France) and Knight and Piésold (United Kingdom). For three years these firms excavated and concreted the undergro...

  19. strong>Hvad skal vi med en hjerne?strong>

    DEFF Research Database (Denmark)

    Hermansen, Judy

    2009-01-01

    neurologen Antonio Damasio, at sikre vores overlevelse og velbefindende (i nævnte rækkefølge). Vi ved, at der findes såkaldte belønningsstrukturer i hjernen på både dyr og mennesker, som aktiverer følelser af velbehag, når vi gør "det rigtige", dvs. noget der er godt for os. Men hvordan de mere konkret...

  20. Reduction of Cr(VI) in aqueous solution with DC diaphragm glow discharge

    International Nuclear Information System (INIS)

    Wang, Xiaoyan; Jin, Xinglong; Zhou, Minghua; Chen, Zhenhai; Deng, Kai

    2013-01-01

    This paper investigated the reduction of Cr(VI) in aqueous solution with direct current diaphragm glow discharge (DGD). The glow discharge sustained around the hole on a quartz tube which divided the electrolyte cell into two parts. The reduction efficiencies of Cr(VI) under different applied voltages, initial conductivities, hole diameters, hole numbers, initial pH values and initial concentrations were systematically studied. The results showed that the reduction efficiency of Cr(VI) increased with the increase of applied voltage, initial conductivity, hole diameter and hole number. The different initial pH values showed less effects on the reduction of Cr(VI). The reduction efficiency decreased with the increasing initial concentration. In addition, the simultaneous reduction of Cr(VI) and decolorization of acid orange (AO) with DGD were also fulfilled. Furthermore, the energy efficiency for Cr(VI) reduction with DGD was calculated and compared with those in photocatalysis and other glow discharge reactor