WorldWideScience

Sample records for ultracold atomic samples

  1. Ultracold atoms on atom chips

    DEFF Research Database (Denmark)

    Krüger, Peter; Hofferberth, S.; Haller, E.

    2005-01-01

    Miniaturized potentials near the surface of atom chips can be used as flexible and versatile tools for the manipulation of ultracold atoms on a microscale. The full scope of possibilities is only accessible if atom-surface distances can be reduced to microns. We discuss experiments in this regime...

  2. Superconducting microtraps for ultracold atoms

    International Nuclear Information System (INIS)

    Hufnagel, C.

    2011-01-01

    Atom chips are integrated devices in which atoms and atomic clouds are stored and manipulated in miniaturized magnetic traps. State of the art fabrication technologies allow for a flexible design of the trapping potentials and consequently provide extraordinary control over atomic samples, which leads to a promising role of atom chips in the engineering and investigation of quantum mechanical systems. Naturally, for quantum mechanical applications, the atomic coherence has to be preserved. Using room temperature circuits, the coherence time of atoms close to the surface was found to be drastically limited by thermal current fluctuations in the conductors. Superconductors offer an elegant way to circumvent thermal noise and therefore present a promising option for the coherent manipulation of atomic quantum states. In this thesis trapping and manipulation of ultracold Rubidium atoms in superconducting microtraps is demonstrated. In this connection the unique properties of superconductors are used to build traps based on persistent currents, the Meissner effect and remanent magnetization. In experiment it is shown, that in superconducting atom chips, thermal magnetic field noise is significantly reduced. Furthermore it is demonstrated, that atomic samples can be employed to probe the properties of superconducting materials. (author) [de

  3. Pseudogap phenomena in ultracold atomic Fermi gases

    OpenAIRE

    Chen, Qijin; Wang, Jibiao

    2014-01-01

    The pairing and superfluid phenomena in a two-component ultracold atomic Fermi gas is an analogue of Cooper pairing and superconductivity in an electron system, in particular, the high $T_c$ superconductors. Owing to the various tunable parameters that have been made accessible experimentally in recent years, atomic Fermi gases can be explored as a prototype or quantum simulator of superconductors. It is hoped that, utilizing such an analogy, the study of atomic Fermi gases may shed light to ...

  4. Illustration of Babinet's principle with ultracold atoms

    OpenAIRE

    Reinhard, Aaron; Riou, Jean-Félix; Zundel, Laura A.; Weiss, David S.

    2013-01-01

    We demonstrate Babinet's principle by the absorption of high intensity light from dense clouds of ultracold atoms. Images of the diffracted light are directly related to the spatial distribution of atoms. The advantages of employing Babinet's principle as an imaging technique are that it is easy to implement and the detected signal is large. We discuss the regimes of applicability of this technique as well as its limitations.

  5. Towards quantum magnetism with ultracold atoms

    International Nuclear Information System (INIS)

    Weld, David M; Ketterle, Wolfgang

    2011-01-01

    At ICAP we presented the efforts and progress at MIT towards using ultracold atoms for the realization of various forms of quantum magnetism. These efforts include a study of fermions with strong repulsive interactions in which we obtained evidence for a phase transition to itinerant ferromagnetism, the characterization of cold atom systems by noise measurements, and a new adiabatic gradient demagnetization cooling scheme which has enabled us to realize temperatures of less than 350 picokelvin and spin temperatures of less than 50 picokelvin in optical lattices. These are the lowest temperatures ever measured in any physical system.

  6. Absorption imaging of ultracold atoms on atom chips

    DEFF Research Database (Denmark)

    Smith, David A.; Aigner, Simon; Hofferberth, Sebastian

    2011-01-01

    Imaging ultracold atomic gases close to surfaces is an important tool for the detailed analysis of experiments carried out using atom chips. We describe the critical factors that need be considered, especially when the imaging beam is purposely reflected from the surface. In particular we present...... methods to measure the atom-surface distance, which is a prerequisite for magnetic field imaging and studies of atom surface-interactions....

  7. Ultracold atoms and the Functional Renormalization Group

    International Nuclear Information System (INIS)

    Boettcher, Igor; Pawlowski, Jan M.; Diehl, Sebastian

    2012-01-01

    We give a self-contained introduction to the physics of ultracold atoms using functional integral techniques. Based on a consideration of the relevant length scales, we derive the universal effective low energy Hamiltonian describing ultracold alkali atoms. We then introduce the concept of the effective action, which generalizes the classical action principle to full quantum status and provides an intuitive and versatile tool for practical calculations. This framework is applied to weakly interacting degenerate bosons and fermions in the spatial continuum. In particular, we discuss the related BEC and BCS quantum condensation mechanisms. We then turn to the BCS-BEC crossover, which interpolates between both phenomena, and which is realized experimentally in the vicinity of a Feshbach resonance. For its description, we introduce the Functional Renormalization Group approach. After a general discussion of the method in the cold atoms context, we present a detailed and pedagogical application to the crossover problem. This not only provides the physical mechanism underlying this phenomenon. More generally, it also reveals how the renormalization group can be used as a tool to capture physics at all scales, from few-body scattering on microscopic scales, through the finite temperature phase diagram governed by many-body length scales, up to critical phenomena dictating long distance physics at the phase transition. The presentation aims to equip students at the beginning PhD level with knowledge on key physical phenomena and flexible tools for their description, and should enable to embark upon practical calculations in this field.

  8. Spatially resolved photoionization of ultracold atoms on an atom chip

    International Nuclear Information System (INIS)

    Kraft, S.; Guenther, A.; Fortagh, J.; Zimmermann, C.

    2007-01-01

    We report on photoionization of ultracold magnetically trapped Rb atoms on an atom chip. The atoms are trapped at 5 μK in a strongly anisotropic trap. Through a hole in the chip with a diameter of 150 μm, two laser beams are focused onto a fraction of the atomic cloud. A first laser beam with a wavelength of 778 nm excites the atoms via a two-photon transition to the 5D level. With a fiber laser at 1080 nm the excited atoms are photoionized. Ionization leads to depletion of the atomic density distribution observed by absorption imaging. The resonant ionization spectrum is reported. The setup used in this experiment is suitable not only to investigate mixtures of Bose-Einstein condensates and ions but also for single-atom detection on an atom chip

  9. High-Flux Ultracold-Atom Chip Interferometers, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — ColdQuanta's ultimate objective is to produce a compact, turnkey, ultracold-atom system specifically designed for performing interferometry with Bose-Einstein...

  10. Preparation of Ultracold Atom Clouds at the Shot Noise Level

    DEFF Research Database (Denmark)

    Gajdacz, M.; Hilliard, A. J.; Kristensen, Mick

    2016-01-01

    We prepare number stabilized ultracold atom clouds through the real-time analysis of nondestructive images and the application of feedback. In our experiments, the atom number N∼10^6 is determined by high precision Faraday imaging with uncertainty ΔN below the shot noise level, i.e., ΔN... on this measurement, feedback is applied to reduce the atom number to a user-defined target, whereupon a second imaging series probes the number stabilized cloud. By this method, we show that the atom number in ultracold clouds can be prepared below the shot noise level....

  11. Non-destructive Faraday imaging of dynamically controlled ultracold atoms

    Science.gov (United States)

    Gajdacz, Miroslav; Pedersen, Poul; Mørch, Troels; Hilliard, Andrew; Arlt, Jan; Sherson, Jacob

    2013-05-01

    We investigate non-destructive measurements of ultra-cold atomic clouds based on dark field imaging of spatially resolved Faraday rotation. In particular, we pursue applications to dynamically controlled ultracold atoms. The dependence of the Faraday signal on laser detuning, atomic density and temperature is characterized in a detailed comparison with theory. In particular the destructivity per measurement is extremely low and we illustrate this by imaging the same cloud up to 2000 times. The technique is applied to avoid the effect of shot-to-shot fluctuations in atom number calibration. Adding dynamic changes to system parameters, we demonstrate single-run vector magnetic field imaging and single-run spatial imaging of the system's dynamic behavior. The method can be implemented particularly easily in standard imaging systems by the insertion of an extra polarizing beam splitter. These results are steps towards quantum state engineering using feedback control of ultracold atoms.

  12. Thermometry of ultracold atoms by electromagnetically induced transparency

    Science.gov (United States)

    Peters, Thorsten; Wittrock, Benjamin; Blatt, Frank; Halfmann, Thomas; Yatsenko, Leonid P.

    2012-06-01

    We report on systematic numerical and experimental investigations of electromagnetically induced transparency (EIT) to determine temperatures in an ultracold atomic gas. The technique relies on the strong dependence of EIT on atomic motion (i.e., Doppler shifts), when the relevant atomic transitions are driven with counterpropagating probe and control laser beams. Electromagnetically induced transparency permits thermometry with satisfactory precision over a large temperature range, which can be addressed by the appropriate choice of Rabi frequency in the control beam. In contrast to time-of-flight techniques, thermometry by EIT is fast and nondestructive, i.e., essentially it does not affect the ultracold medium. In an experimental demonstration we apply both EIT and time-of-flight measurements to determine temperatures along different symmetry axes of an anisotropic ultracold gas. As an interesting feature we find that the temperatures in the anisotropic atom cloud vary in different directions.

  13. Mixtures of ultracold atoms and the quest for ultracold molecules

    International Nuclear Information System (INIS)

    Weidemueller, M.

    2000-08-01

    A cold atomic gas formed by two different species represents an intriguing system for a deeper understanding of atom-atom interactions at ultralow temperatures. We present experiments on a mixture of atomic lithium and cesium which are of particular interest regarding the formation of heteronuclear molecules on the one hand, and the prospects for sympathetic cooling of atomic gases through mutual thermalization on the other hand. A first series of experiments on interaction in presence of a near-resonant light field is performed in a two-species magneto-optical trap. The collisional properties of the lithium-cesium mixture are investigated through detailed analysis of trap-loss processes induced by the trap light. Photoassociation in an additional near-resonant laser field yields high-resolution spectra of the excited Cs 2 dimers, but shows no unambiguous indication of LiCs molecule formation. A second series of experiments on pure ground-state collisional properties utilizes an optical dipole trap formed by light that is detuned extremely far below atomic resonance (quasi-electrostatic trap). Storage times of many minutes are achieved in a particularly simple and versatile setup for both atomic species. Cooling of cesium through evaporation and thermalization by elastic collisions is observed. The evolution of temperature and particle number is compared with model simulations of evaporative cooling. Direct laser cooling of trapped cesium in the absolute energetic ground state is demonstrated. Homonuclear spin-changing collisions of ground-state cesium and lithium atoms are analyzed, and first evidence for pure ground-state collisions between atoms of different species is found. Based on the current achievements, prospects for future experiments are discussed. (orig.)

  14. Emulating Molecular Orbitals and Electronic Dynamics with Ultracold Atoms

    Directory of Open Access Journals (Sweden)

    Dirk-Sören Lühmann

    2015-08-01

    Full Text Available In recent years, ultracold atoms in optical lattices have proven their great value as quantum simulators for studying strongly correlated phases and complex phenomena in solid-state systems. Here, we reveal their potential as quantum simulators for molecular physics and propose a technique to image the three-dimensional molecular orbitals with high resolution. The outstanding tunability of ultracold atoms in terms of potential and interaction offer fully adjustable model systems for gaining deep insight into the electronic structure of molecules. We study the orbitals of an artificial benzene molecule and discuss the effect of tunable interactions in its conjugated π electron system with special regard to localization and spin order. The dynamical time scales of ultracold atom simulators are on the order of milliseconds, which allows for the time-resolved monitoring of a broad range of dynamical processes. As an example, we compute the hole dynamics in the conjugated π system of the artificial benzene molecule.

  15. Quantum chaos in ultracold collisions of gas-phase erbium atoms.

    Science.gov (United States)

    Frisch, Albert; Mark, Michael; Aikawa, Kiyotaka; Ferlaino, Francesca; Bohn, John L; Makrides, Constantinos; Petrov, Alexander; Kotochigova, Svetlana

    2014-03-27

    Atomic and molecular samples reduced to temperatures below one microkelvin, yet still in the gas phase, afford unprecedented energy resolution in probing and manipulating the interactions between their constituent particles. As a result of this resolution, atoms can be made to scatter resonantly on demand, through the precise control of a magnetic field. For simple atoms, such as alkalis, scattering resonances are extremely well characterized. However, ultracold physics is now poised to enter a new regime, where much more complex species can be cooled and studied, including magnetic lanthanide atoms and even molecules. For molecules, it has been speculated that a dense set of resonances in ultracold collision cross-sections will probably exhibit essentially random fluctuations, much as the observed energy spectra of nuclear scattering do. According to the Bohigas-Giannoni-Schmit conjecture, such fluctuations would imply chaotic dynamics of the underlying classical motion driving the collision. This would necessitate new ways of looking at the fundamental interactions in ultracold atomic and molecular systems, as well as perhaps new chaos-driven states of ultracold matter. Here we describe the experimental demonstration that random spectra are indeed found at ultralow temperatures. In the experiment, an ultracold gas of erbium atoms is shown to exhibit many Fano-Feshbach resonances, of the order of three per gauss for bosons. Analysis of their statistics verifies that their distribution of nearest-neighbour spacings is what one would expect from random matrix theory. The density and statistics of these resonances are explained by fully quantum mechanical scattering calculations that locate their origin in the anisotropy of the atoms' potential energy surface. Our results therefore reveal chaotic behaviour in the native interaction between ultracold atoms.

  16. Optical ferris wheel for ultracold atoms

    Science.gov (United States)

    Franke-Arnold, S.; Leach, J.; Padgett, M. J.; Lembessis, V. E.; Ellinas, D.; Wright, A. J.; Girkin, J. M.; Ohberg, P.; Arnold, A. S.

    2007-07-01

    We propose a versatile optical ring lattice suitable for trapping cold and quantum degenerate atomic samples. We demonstrate the realisation of intensity patterns from pairs of Laguerre-Gauss (exp(iℓө) modes with different ℓ indices. These patterns can be rotated by introducing a frequency shift between the modes. We can generate bright ring lattices for trapping atoms in red-detuned light, and dark ring lattices suitable for trapping atoms with minimal heating in the optical vortices of blue-detuned light. The lattice sites can be joined to form a uniform ring trap, making it ideal for studying persistent currents and the Mott insulator transition in a ring geometry.

  17. From few to many. Ultracold atoms in reduced dimensions

    International Nuclear Information System (INIS)

    Wenz, Andre Niklas

    2013-01-01

    This thesis reports on experimental studies exploring few and many-body physics of ultracold Bose and Fermi gases with reduced dimensionality. These experiments illustrate the versatility and great amount of control over the particle number, the interaction and other degrees of freedom, like the spin, that these generic quantum systems offer. In the first part of this thesis, we use quasi one-dimensional few-particle systems of one to ten fermionic atoms to investigate the crossover from few to many-body physics. This is achieved by measuring the interaction energy between a single impurity atom in a state vertical stroke ↓ right angle which repulsively interacts with an increasing number of majority atoms in a state vertical stroke ↑ right angle. We find that the system quickly approaches the results from the many-body theory, which describes the behavior of a single impurity immersed in a Fermi sea of an infinite number of majority particles. The second part of this thesis presents studies of the time evolution of a bosonic F=1 spinor BEC of 87 Rb atoms. In this system, we investigate the emergence and coarsening of ferromagnetic spin textures from initially unmagnetized samples. While the ferromagnetic domains grow, we observe the development of a spin space anisotropy which is in agreement with the predicted phase-diagram. The last part of this thesis presents our first steps towards the investigation of phase coherence of quasi two-dimensional quantum gases in the crossover from bosonic molecules to fermionic atoms.

  18. Coupling ultracold atoms to a superconducting coplanar waveguide resonator

    OpenAIRE

    Hattermann, H.; Bothner, D.; Ley, L. Y.; Ferdinand, B.; Wiedmaier, D.; Sárkány, L.; Kleiner, R.; Koelle, D.; Fortágh, J.

    2017-01-01

    We demonstrate coupling of magnetically trapped ultracold $^87$Rb ground state atoms to a coherently driven superconducting coplanar resonator on an integrated atom chip. We measure the microwave field strength in the cavity through observation of the AC shift of the hyperfine transition frequency when the cavity is driven off-resonance from the atomic transition. The measured shifts are used to reconstruct the field in the resonator, in close agreement with transmission measurements of the c...

  19. Strategic Applications of Ultra-Cold Atoms

    Science.gov (United States)

    2008-03-07

    Peer-Reviewed Conference Proceeding publications (other than abstracts): “Laser cooling in anisotropic traps”, M. Vengalattore, R.S. Conroy, M. Prentiss...IEEE Cat. No. 04CH37598. Piscataway, NJ, IEEE, 2004, 1 pp. “Guiding of light in an ultracold, anisotropic medium”, M. Vengalattore and M. Prentiss, in...molecules the rotational dynamics imposes significantly larger Rabi frequencies than would otherwise be expected, but within this limitation, a full

  20. Quantum information entropies of ultracold atomic gases in a ...

    Indian Academy of Sciences (India)

    bosonic systems and a ≃ 1.982 and b = 1 for ideal fermionic systems. These results obey the entropic uncertainty relation given by Beckner, Bialynicki-Birula and Myceilski. Keywords. Ultracold atomic gases; information entropy; foundations of quantum mechanics. PACS Nos 67.85.−d; 89.70.Cf; 03.65.Ta. 1. Introduction.

  1. Manipulating collective quantum states of ultracold atoms by probing

    DEFF Research Database (Denmark)

    Wade, Andrew Christopher James

    2015-01-01

    The field of cold gases has grown dramatically over the past few decades. The exquisite experimental control of their environment and properties has lead to landmark achievements, and has motivated the pursuit of quantum technologies with ultracold atoms. At the same time, the theory of measureme......The field of cold gases has grown dramatically over the past few decades. The exquisite experimental control of their environment and properties has lead to landmark achievements, and has motivated the pursuit of quantum technologies with ultracold atoms. At the same time, the theory...... of measurements on quantum systems has grown into a well established field. Experimental demonstrations of nondestructive continuous measurements on individual quantum systems now occur in many laboratories. Such experiments with ultracold atoms have shown great progress, but the exploitation of the quantum...... nature of the measurement interaction and backaction is yet to be realised. This dissertation is concerned with ultracold atoms and their control via fully quantum mechanical probes. Nonclassical, squeezed and entangled states of matter and single photon sources are important for fundamental studies...

  2. Dressed molecules in resonantly interacting ultracold atomic Fermi gases

    NARCIS (Netherlands)

    Falco, G.M.; Stoof, H.T.C.

    2007-01-01

    We present a detailed analysis of the two-channel atom-molecule effective Hamiltonian for an ultracold two-component homogeneous Fermi gas interacting near a Feshbach resonance. We particularly focus on the two-body and many-body properties of the dressed molecules in such a gas. An exact result

  3. Non-destructive Faraday imaging of dynamically controlled ultracold atoms

    DEFF Research Database (Denmark)

    Gajdacz, Miroslav; Pedersen, Poul Lindholm; Mørch, Troels

    2013-01-01

    We describe an easily implementable method for non-destructive measurements of ultracold atomic clouds based on dark field imaging of spatially resolved Faraday rotation. The signal-to-noise ratio is analyzed theoretically and, in the absence of experimental imperfections, the sensitivity limit...

  4. Ultracold atoms for precision measurement of fundamental physical quantities

    CERN Multimedia

    CERN. Geneva

    2003-01-01

    Cooling and trapping of neutral atoms has been one of the most active fields of research in physics in recent years. Several methods were demonstrated to reach temperatures as low as a few nanokelvin allowing, for example, the investigation of quantum degenerate gases. The ability to control the quantum degrees of freedom of atoms opens the way to applications for precision measurement of fundamental physical quantities. Experiments in progress, planned or being considered using new quantum devices based on ultracold atoms, namely atom interferometers and atomic clocks, will be discussed.

  5. From few to many. Ultracold atoms in reduced dimensions

    Energy Technology Data Exchange (ETDEWEB)

    Wenz, Andre Niklas

    2013-12-19

    This thesis reports on experimental studies exploring few and many-body physics of ultracold Bose and Fermi gases with reduced dimensionality. These experiments illustrate the versatility and great amount of control over the particle number, the interaction and other degrees of freedom, like the spin, that these generic quantum systems offer. In the first part of this thesis, we use quasi one-dimensional few-particle systems of one to ten fermionic atoms to investigate the crossover from few to many-body physics. This is achieved by measuring the interaction energy between a single impurity atom in a state vertical stroke ↓ right angle which repulsively interacts with an increasing number of majority atoms in a state vertical stroke ↑ right angle. We find that the system quickly approaches the results from the many-body theory, which describes the behavior of a single impurity immersed in a Fermi sea of an infinite number of majority particles. The second part of this thesis presents studies of the time evolution of a bosonic F=1 spinor BEC of {sup 87}Rb atoms. In this system, we investigate the emergence and coarsening of ferromagnetic spin textures from initially unmagnetized samples. While the ferromagnetic domains grow, we observe the development of a spin space anisotropy which is in agreement with the predicted phase-diagram. The last part of this thesis presents our first steps towards the investigation of phase coherence of quasi two-dimensional quantum gases in the crossover from bosonic molecules to fermionic atoms.

  6. Extended Hubbard models for ultracold atoms in optical lattices

    Energy Technology Data Exchange (ETDEWEB)

    Juergensen, Ole

    2015-06-05

    In this thesis, the phase diagrams and dynamics of various extended Hubbard models for ultracold atoms in optical lattices are studied. Hubbard models are the primary description for many interacting particles in periodic potentials with the paramount example of the electrons in solids. The very same models describe the behavior of ultracold quantum gases trapped in the periodic potentials generated by interfering beams of laser light. These optical lattices provide an unprecedented access to the fundamentals of the many-particle physics that govern the properties of solid-state materials. They can be used to simulate solid-state systems and validate the approximations and simplifications made in theoretical models. This thesis revisits the numerous approximations underlying the standard Hubbard models with special regard to optical lattice experiments. The incorporation of the interaction between particles on adjacent lattice sites leads to extended Hubbard models. Offsite interactions have a strong influence on the phase boundaries and can give rise to novel correlated quantum phases. The extended models are studied with the numerical methods of exact diagonalization and time evolution, a cluster Gutzwiller approximation, as well as with the strong-coupling expansion approach. In total, this thesis demonstrates the high relevance of beyond-Hubbard processes for ultracold atoms in optical lattices. Extended Hubbard models can be employed to tackle unexplained problems of solid-state physics as well as enter previously inaccessible regimes.

  7. Extended Hubbard models for ultracold atoms in optical lattices

    International Nuclear Information System (INIS)

    Juergensen, Ole

    2015-01-01

    In this thesis, the phase diagrams and dynamics of various extended Hubbard models for ultracold atoms in optical lattices are studied. Hubbard models are the primary description for many interacting particles in periodic potentials with the paramount example of the electrons in solids. The very same models describe the behavior of ultracold quantum gases trapped in the periodic potentials generated by interfering beams of laser light. These optical lattices provide an unprecedented access to the fundamentals of the many-particle physics that govern the properties of solid-state materials. They can be used to simulate solid-state systems and validate the approximations and simplifications made in theoretical models. This thesis revisits the numerous approximations underlying the standard Hubbard models with special regard to optical lattice experiments. The incorporation of the interaction between particles on adjacent lattice sites leads to extended Hubbard models. Offsite interactions have a strong influence on the phase boundaries and can give rise to novel correlated quantum phases. The extended models are studied with the numerical methods of exact diagonalization and time evolution, a cluster Gutzwiller approximation, as well as with the strong-coupling expansion approach. In total, this thesis demonstrates the high relevance of beyond-Hubbard processes for ultracold atoms in optical lattices. Extended Hubbard models can be employed to tackle unexplained problems of solid-state physics as well as enter previously inaccessible regimes.

  8. Measurement of Spectral Functions of Ultracold Atoms in Disordered Potentials

    Science.gov (United States)

    Volchkov, Valentin V.; Pasek, Michael; Denechaud, Vincent; Mukhtar, Musawwadah; Aspect, Alain; Delande, Dominique; Josse, Vincent

    2018-02-01

    We report on the measurement of the spectral functions of noninteracting ultracold atoms in a three-dimensional disordered potential resulting from an optical speckle field. Varying the disorder strength by 2 orders of magnitude, we observe the crossover from the "quantum" perturbative regime of low disorder to the "classical" regime at higher disorder strength, and find an excellent agreement with numerical simulations. The method relies on the use of state-dependent disorder and the controlled transfer of atoms to create well-defined energy states. This opens new avenues for experimental investigations of three-dimensional Anderson localization.

  9. Atomic physics precise measurements and ultracold matter

    CERN Document Server

    Inguscio, Massimo

    2013-01-01

    Atomic Physics provides an expert guide to two spectacular new landscapes in physics: precision measurements, which have been revolutionized by the advent of the optical frequency comb, and atomic physics, which has been revolutionized by laser cooling. These advances are not incremental but transformative: they have generated a consilience between atomic and many-body physics, precipitated an explosion of scientific and technological applications, opened new areas of research, and attracted a brilliant generation of younger scientists. The research is advancing so rapidly, the barrage of applications is so dazzling, that students can be bewildered. For both students and experienced scientists, this book provides an invaluable description of basic principles, experimental methods, and scientific applications.

  10. Individual Tracer Atoms in an Ultracold Dilute Gas

    Science.gov (United States)

    Hohmann, Michael; Kindermann, Farina; Lausch, Tobias; Mayer, Daniel; Schmidt, Felix; Lutz, Eric; Widera, Artur

    2017-06-01

    We report on the experimental investigation of individual Cs atoms impinging on a dilute cloud of ultracold Rb atoms with variable density. We study the relaxation of the initial nonthermal state and detect the effect of single collisions which has so far eluded observation. We show that, after few collisions, the measured spatial distribution of the tracer atoms is correctly described by a Langevin equation with a velocity-dependent friction coefficient, over a large range of Knudsen numbers. Our results extend the simple and effective Langevin treatment to the realm of light particles in dilute gases. The experimental technique developed opens up the microscopic exploration of a novel regime of diffusion at the level of individual collisions.

  11. Permanent magnetic lattices for ultracold atoms and quantum degenerate gases

    International Nuclear Information System (INIS)

    Ghanbari, Saeed; Kieu, Tien D; Sidorov, Andrei; Hannaford, Peter

    2006-01-01

    We propose the use of periodic arrays of permanent magnetic films for producing magnetic lattices of microtraps for confining, manipulating and controlling small clouds of ultracold atoms and quantum degenerate gases. Using analytical expressions and numerical calculations we show that periodic arrays of magnetic films can produce one-dimensional (1D) and two-dimensional (2D) magnetic lattices with non-zero potential minima, allowing ultracold atoms to be trapped without losses due to spin flips. In particular, we show that two crossed layers of periodic arrays of parallel rectangular magnets plus bias fields, or a single layer of periodic arrays of square-shaped magnets with three different thicknesses plus bias fields, can produce 2D magnetic lattices of microtraps having non-zero potential minima and controllable trap depth. For arrays with micron-scale periodicity, the magnetic microtraps can have very large trap depths (∼0.5 mK for the realistic parameters chosen for the 2D lattice) and very tight confinement

  12. Interfacing ultracold atoms and cryogenic micromechanical oscillator

    Energy Technology Data Exchange (ETDEWEB)

    Bick, Andreas

    2015-02-06

    fiber. This previously unknown effect was identified as crucial in asymmetric fiber-based cavities and is studied in this thesis using an analytical model, which is verified using numerical calculations and experimental data. The curved structures necessary for a stable cavity mode in the MiM system are processed onto the fiber tips using CO{sub 2} laser pulses. The light is absorbed, resulting in the evaporation of material. Afterwards, the fiber is analyzed using a Linnik interference microscope to determine the radius of curvature of the processed feature. With this knowledge, an asymmetric fiber-based MiM system at room temperature was set up and in first measurements the mechanical quality factor and the optomechanical coupling strength were studied. Furthermore, a setup to create BECs was planned and realized. Here, in first measurements, Bose-Einstein condensation was observed. The system is based on a 2D/3D MOT design in combination with a Hybrid-Dee magnetic trap. Using radio-frequency evaporation, BECs with N ∼ 8 x 10{sup 4} atoms can be produced at a cycle time of 30 s.

  13. Few-particle quantum magnetism with ultracold atoms

    Energy Technology Data Exchange (ETDEWEB)

    Murmann, Simon

    2015-11-25

    This thesis reports on the deterministic preparation of magnetically ordered states in systems of few fermionic atoms. We follow the concept of quantum simulation and use {sup 6}Li atoms in two different hyperfine states to mimic the behavior of electrons in a solidstate system. In a first experiment, we simulate the two-site Hubbard model by using two atoms in an isolated double-well potential. We prepare the two-particle ground state of this model with a fidelity exceeding 90%. By introducing strong repulsive interactions, we are able to realize a pure spin model and describe the energy spectrum with a two-site Heisenberg Hamiltonian. In a second experiment, we realize Heisenberg spin chains of up to four atoms in a single strongly-elongated trapping potential. Here, the atoms self-align along the potential axis due to strong repulsive interactions. We introduce two novel measurement techniques to identify the state of the spin chains and thereby confirm that we can deterministically prepare antiferromagnetic ground-state systems. This constitutes the first observation of quantum magnetism with fermionic atoms that exceeds nearest-neighbor correlations. Both the double-well system and the spin chains can be seen as building blocks of larger ground-state spin systems. Their deterministic preparation therefore opens up a new bottom-up approach to the experimental realization of quantum many-body systems with ultracold atoms.

  14. Scattering resonances of ultracold atoms in confined geometries

    Energy Technology Data Exchange (ETDEWEB)

    Saeidian, Shahpoor

    2008-06-18

    Subject of this thesis is the investigation of the quantum dynamics of ultracold atoms in confined geometries. We discuss the behavior of ground state atoms inside a 3D magnetic quadrupole field. Such atoms in enough weak magnetic fields can be approximately treated as neutral point-like particles. Complementary to the well-known positive energy resonances, we point out the existence of short-lived negative energy resonances. The latter originate from a fundamental symmetry of the underlying Hamiltonian. We drive a mapping of the two branches of the spectrum. Moreover, we analyze atomic hyperfine resonances in a magnetic quadrupole field. This corresponds to the case for which both the hyperfine and Zeeman interaction, are comparable, and should be taken into account. Finally, we develop a general grid method for multichannel scattering of two atoms in a two-dimensional harmonic confinement. With our approach we analyze transverse excitations/deexcitations in the course of the collisional process (distinguishable or identical atoms) including all important partial waves and their couplings due to the broken spherical symmetry. Special attention is paid to suggest a non-trivial extension of the CIRs theory developed so far only for the single-mode regime and zero-energy limit. (orig.)

  15. Scattering resonances of ultracold atoms in confined geometries

    International Nuclear Information System (INIS)

    Saeidian, Shahpoor

    2008-01-01

    Subject of this thesis is the investigation of the quantum dynamics of ultracold atoms in confined geometries. We discuss the behavior of ground state atoms inside a 3D magnetic quadrupole field. Such atoms in enough weak magnetic fields can be approximately treated as neutral point-like particles. Complementary to the well-known positive energy resonances, we point out the existence of short-lived negative energy resonances. The latter originate from a fundamental symmetry of the underlying Hamiltonian. We drive a mapping of the two branches of the spectrum. Moreover, we analyze atomic hyperfine resonances in a magnetic quadrupole field. This corresponds to the case for which both the hyperfine and Zeeman interaction, are comparable, and should be taken into account. Finally, we develop a general grid method for multichannel scattering of two atoms in a two-dimensional harmonic confinement. With our approach we analyze transverse excitations/deexcitations in the course of the collisional process (distinguishable or identical atoms) including all important partial waves and their couplings due to the broken spherical symmetry. Special attention is paid to suggest a non-trivial extension of the CIRs theory developed so far only for the single-mode regime and zero-energy limit. (orig.)

  16. D-state Rydberg electrons interacting with ultracold atoms

    Energy Technology Data Exchange (ETDEWEB)

    Krupp, Alexander Thorsten

    2014-10-02

    This thesis was established in the field of ultracold atoms where the interaction of highly excited D-state electrons with rubidium atoms was examined. This work is divided into two main parts: In the first part we study D-state Rydberg molecules resulting from the binding of a D-state Rydberg electron to a ground state rubidium atom. We show that we can address specific rovibrational molecular states by changing our laser detuning and thus create perfectly aligned axial or antialigned toroidal molecules, in good agreement with our theoretical calculations. Furthermore the influence of the electric field on the Rydberg molecules was investigated, creating novel states which show a different angular dependence and alignment. In the second part of this thesis we excite single D-state Rydberg electrons in a Bose-Einstein condensate. We study the lifetime of these Rydberg electrons, the change of the shape of our condensate and the atom losses in the condensate due to this process. Moreover, we observe quadrupolar shape oscillations of the whole condensate created by the consecutive excitation of Rydberg atoms and compare all results to previous S-state measurements. In the outlook we propose a wide range of further experiments including the proposal of imaging a single electron wavefunction by the imprint of its orbit into the Bose-Einstein condensate.

  17. Light-induced gauge fields for ultracold atoms

    Science.gov (United States)

    Goldman, N.; Juzeliūnas, G.; Öhberg, P.; Spielman, I. B.

    2014-12-01

    Gauge fields are central in our modern understanding of physics at all scales. At the highest energy scales known, the microscopic universe is governed by particles interacting with each other through the exchange of gauge bosons. At the largest length scales, our Universe is ruled by gravity, whose gauge structure suggests the existence of a particle—the graviton—that mediates the gravitational force. At the mesoscopic scale, solid-state systems are subjected to gauge fields of different nature: materials can be immersed in external electromagnetic fields, but they can also feature emerging gauge fields in their low-energy description. In this review, we focus on another kind of gauge field: those engineered in systems of ultracold neutral atoms. In these setups, atoms are suitably coupled to laser fields that generate effective gauge potentials in their description. Neutral atoms ‘feeling’ laser-induced gauge potentials can potentially mimic the behavior of an electron gas subjected to a magnetic field, but also, the interaction of elementary particles with non-Abelian gauge fields. Here, we review different realized and proposed techniques for creating gauge potentials—both Abelian and non-Abelian—in atomic systems and discuss their implication in the context of quantum simulation. While most of these setups concern the realization of background and classical gauge potentials, we conclude with more exotic proposals where these synthetic fields might be made dynamical, in view of simulating interacting gauge theories with cold atoms.

  18. Light-induced gauge fields for ultracold atoms

    International Nuclear Information System (INIS)

    Goldman, N; Juzeliūnas, G; Öhberg, P; Spielman, I B

    2014-01-01

    Gauge fields are central in our modern understanding of physics at all scales. At the highest energy scales known, the microscopic universe is governed by particles interacting with each other through the exchange of gauge bosons. At the largest length scales, our Universe is ruled by gravity, whose gauge structure suggests the existence of a particle—the graviton—that mediates the gravitational force. At the mesoscopic scale, solid-state systems are subjected to gauge fields of different nature: materials can be immersed in external electromagnetic fields, but they can also feature emerging gauge fields in their low-energy description. In this review, we focus on another kind of gauge field: those engineered in systems of ultracold neutral atoms. In these setups, atoms are suitably coupled to laser fields that generate effective gauge potentials in their description. Neutral atoms ‘feeling’ laser-induced gauge potentials can potentially mimic the behavior of an electron gas subjected to a magnetic field, but also, the interaction of elementary particles with non-Abelian gauge fields. Here, we review different realized and proposed techniques for creating gauge potentials—both Abelian and non-Abelian—in atomic systems and discuss their implication in the context of quantum simulation. While most of these setups concern the realization of background and classical gauge potentials, we conclude with more exotic proposals where these synthetic fields might be made dynamical, in view of simulating interacting gauge theories with cold atoms. (review article)

  19. Rydberg-atom formation in strongly correlated ultracold plasmas

    International Nuclear Information System (INIS)

    Bannasch, G.; Pohl, T.

    2011-01-01

    In plasmas at very low temperatures, the formation of neutral atoms is dominated by collisional three-body recombination, owing to the strong ∼T -9/2 scaling of the corresponding recombination rate with the electron temperature T. While this law is well established at high temperatures, the unphysical divergence as T→0 clearly suggests a breakdown in the low-temperature regime. Here, we present a combined molecular dynamics Monte Carlo study of electron-ion recombination over a wide range of temperatures and densities. Our results reproduce the known behavior of the recombination rate at high temperatures, but reveal significant deviations with decreasing temperature. We discuss the fate of the kinetic bottleneck and resolve the divergence problem as the plasma enters the ultracold, strongly coupled domain.

  20. Velocity selection for ultra-cold atoms using bimodal mazer cavity

    International Nuclear Information System (INIS)

    Irshad, A.; Qamar, S.

    2009-04-01

    In this paper, we discuss the velocity selection of ultra-cold three-level atoms in Λ configuration using a micromazer. Our model is the same as discussed by Arun et al., for mazer action in a bimodal cavity. We have shown that significantly narrowed velocity distribution of ultra-cold atoms can be obtained in this system due to the presence of dark states. (author)

  1. Classical and quantum analysis of one-dimensional velocity selection for ultracold atoms

    International Nuclear Information System (INIS)

    Fox, J K; Kim, H A; Mishra, S R; Myrskog, S H; Jofre, A M; Segal, L R; Kim, J B; Steinberg, A M

    2005-01-01

    We discuss a velocity selection technique for obtaining cold atoms, in which all atoms below a certain energy are spatially selected from the surrounding atom cloud. Velocity selection can in some cases be more efficient than other cooling techniques for the preparation of ultracold atom clouds in one dimension. With quantum mechanical and classical simulations and theory we present a scheme using a dipole force barrier to select the coldest atoms from a magnetically trapped atom cloud. The dipole and magnetic potentials create a local minimum which traps the coldest atoms. A unique advantage of this technique is the sharp cut-off in the velocity distribution of the sample of selected atoms. Such a non-thermal distribution should prove useful for a variety of experiments, including proposed studies of atomic tunnelling and scattering from quantum potentials. We show that when the rms size of the atom cloud is smaller than the local minimum in which the selected atoms are trapped, the velocity selection technique can be more efficient in one dimension than some common techniques such as evaporative cooling. For example, one simulation shows nearly 6% of the atoms retained at a temperature 100 times lower than the starting condition

  2. Microscopic description and simulation of ultracold atoms in optical resonators

    International Nuclear Information System (INIS)

    Niedenzu, W.

    2012-01-01

    Ultracold atoms in optical resonators are an ideal system to investigate the full quantum regime of light-matter interaction. Microscopic insight into the underlying processes can nowadays easily be obtained from numerical calculations, e.g. with Monte Carlo wave function simulations. In the first part we discuss cold atoms in ring resonators, where the modified boundary conditions significantly alter the dynamics as compared to the standing-wave case. Quantum jumps induce momentum correlations and entanglement between the particles. We observe strong non-classical motional correlations, cooling and entanglement heralded by single photon measurements. For deeply trapped particles the complex system Hamiltonian can be mapped onto a generic optomechanical model, allowing for analytical microscopic insight into the dynamics. The rates of cavity-mediated correlated heating and cooling processes are obtained by adiabatically eliminating the cavity field from the dynamics and can be directly related to the steady-state momentum correlation coefficient. The second part is devoted to cooling and self-organisation of a cold gas in a transversally pumped standing-wave resonator, in which the atoms are directly illuminated by a laser beam. Above a certain critical laser intensity the atoms order in a specific pattern, maximising light scattering into the cavity. The particles thus create and sustain their own trap. We derive a nonlinear Fokker-Planck equation for the one-particle distribution function describing the gas dynamics below and above threshold. This kinetic theory predicts dissipation-induced self-organisation and q-Gaussian velocity distributions in steady state. (author)

  3. Tunneling and traversal of ultracold three-level atoms through vacuum-induced potentials

    Energy Technology Data Exchange (ETDEWEB)

    Badshah, Fazal; Irfan, Muhammad; Qamar, Shahid [Department of Physics and Applied Mathematics, Pakistan Institute of Engineering and Applied Sciences, Nilore, Islamabad 45650 (Pakistan); Qamar, Sajid [Department of Physics, COMSATS Institute of Information Technology, Islamabad (Pakistan)

    2011-09-15

    The passage of ultracold three-level atoms through the potential induced by the vacuum cavity mode is discussed using cascade atomic configuration. We study the tunneling or traversal time of the ultracold atoms via a bimodal high-Q cavity. It is found that the phase time, which may be considered as a measure for the time required to traverse the cavity, exhibits superclassical and subclassical behaviors. Further, the dark states and interference effects in cascade atomic configuration may influence the passage time of the atom through the cavity.

  4. Tunneling and traversal of ultracold three-level atoms through vacuum-induced potentials

    International Nuclear Information System (INIS)

    Badshah, Fazal; Irfan, Muhammad; Qamar, Shahid; Qamar, Sajid

    2011-01-01

    The passage of ultracold three-level atoms through the potential induced by the vacuum cavity mode is discussed using cascade atomic configuration. We study the tunneling or traversal time of the ultracold atoms via a bimodal high-Q cavity. It is found that the phase time, which may be considered as a measure for the time required to traverse the cavity, exhibits superclassical and subclassical behaviors. Further, the dark states and interference effects in cascade atomic configuration may influence the passage time of the atom through the cavity.

  5. Manipulating beams of ultra-cold atoms with a static magnetic field

    International Nuclear Information System (INIS)

    Rowlands, W.J.; Lau, D.C.; Opat, G.I.; Sidorov, A.I.; McLean, R.J.; Hannaford, P.

    1996-01-01

    The preliminary results on the deflection of a beam of ultra-cold atoms by a static magnetic field are presented. Caesium atoms trapped in a magneto-optical trap (MOT) are cooled using optical molasses, and then fall freely under gravity to form a beam of ultra-cold atoms. The atoms pass through a static inhomogeneous magnetic field produced by a single current-carrying wire, and are deflected by a force dependent on the magnetic substate of the atom. A schematical diagram of the experimental layout for laser trapping and cooling of cesium atom is given. The population of atoms in various magnetic substates can be altered by using resonant laser radiation to optically pump the atoms. The single-wire deflection experiment described can be considered as atomic reflexion from a cylindrical magnetic mirror; the underlying principles and techniques being relevant to the production of atomic mirrors and diffraction gratings. 16 refs., 10 figs

  6. Dipole-dipole interactions in a hot atomic vapor and in an ultracold gas of Rydberg atoms

    Science.gov (United States)

    Sautenkov, V. A.; Saakyan, S. A.; Bronin, S. Ya; Klyarfeld, A. B.; Zelener, B. B.; Zelener, B. V.

    2018-01-01

    In our paper ideal and non-ideal gas media of neutral atoms are analyzed. The first we discuss a dipole broadening of atomic transitions in excited dilute and dense metal vapors. Then the theoretical studies of the dipole-dipole interactions in dense ultracold gas of Rydberg atoms are considered. Possible future experiments on a base of our experimental arrangement are suggested.

  7. Predicting scattering properties of ultracold atoms : Adiabatic accumulated phase method and mass scaling

    NARCIS (Netherlands)

    Verhaar, B.J.; Kempen, van E.G.M.; Kokkelmans, S.J.J.M.F.

    2009-01-01

    Ultracold atoms are increasingly used for high-precision experiments that can be utilized to extract accurate scattering properties. This results in a stronger need to improve on the accuracy of interatomic potentials, and in particular the usually rather inaccurate inner-range potentials. A

  8. Observation of electric quadrupole transitions to Rydberg nd states of ultracold rubidium atoms

    NARCIS (Netherlands)

    Tong, D.; Farooqi, S.M.; Kempen, van E.G.M.; Pavlovic, Z.; Stanojevic, J.; Coté, R.; Eyler, E.E.; Gould, P.L.

    2009-01-01

    We report the observation of dipole-forbidden, but quadrupole-allowed, one-photon transitions to high-Rydberg states in Rb. Using pulsed uv excitation of ultracold atoms in a magneto-optical trap, we excite 5s¿nd transitions over a range of principal quantum numbers n=27–59. Compared to

  9. Quantum simulation of conductivity plateaux and fractional quantum Hall effect using ultracold atoms

    International Nuclear Information System (INIS)

    Barberán, Nuria; García-March, Miguel Angel; Taron, Josep; Dagnino, Daniel; Trombettoni, Andrea; Lewenstein, Maciej

    2015-01-01

    We analyze the role of impurities in the fractional quantum Hall effect using a highly controllable system of ultracold atoms. We investigate the mechanism responsible for the formation of plateaux in the resistivity/conductivity as a function of the applied magnetic field in the lowest Landau level regime. To this aim, we consider an impurity immersed in a small cloud of an ultracold quantum Bose gas subjected to an artificial magnetic field. We consider scenarios corresponding to experimentally realistic systems with gauge fields induced by rotation of the trapping parabolic potential. Systems of this kind are adequate to simulate quantum Hall effects in ultracold atom setups. We use exact diagonalization for few atoms and to emulate transport equations, we analyze the time evolution of the system under a periodic perturbation. We provide a theoretical proposal to detect the up-to-now elusive presence of strongly correlated states related to fractional filling factors in the context of ultracold atoms. We analyze the conditions under which these strongly correlated states are associated with the presence of the resistivity/conductivity plateaux. Our main result is the presence of a plateau in a region, where the transfer between localized and non-localized particles takes place, as a necessary condition to maintain a constant value of the resistivity/conductivity as the magnetic field increases. (paper)

  10. Strongly-correlated ultracold atoms in optical lattices

    International Nuclear Information System (INIS)

    Dao, Tung-Lam

    2008-01-01

    This thesis is concerned with the theoretical study of strongly correlated quantum states of ultra-cold fermionic atoms trapped in optical lattices. This field has grown considerably in recent years, following the experimental progress made in cooling and controlling atomic gases, which has led to the observation of the first Bose-Einstein condensation (in 1995). The trapping of these gases in optical lattices has opened a new field of research at the interface between atomic physics and condensed matter physics. The observation of the transition from a superfluid to a Mott insulator for bosonic atoms paved the way for the study of strongly correlated phases and quantum phase transitions in these systems. Very recently, the investigation of the Mott insulator state of fermionic atoms provides additional motivation to conduct such theoretical studies. This thesis can be divided broadly into two types of work: - On the one hand, we have proposed a new type of spectroscopy to measure single-particle correlators and associated physical observables in these strongly correlated states. - On the other hand, we have studied the ground state of the fermionic Hubbard model under different conditions (mass imbalance, population imbalance) by using analytical techniques and numerical simulations. In a collaboration with J. Dalibard and C. Salomon (LKB at the ENS Paris) and I. Carusotto (Trento, Italy), we have proposed and studied a novel spectroscopic method for the measurement and characterization of single particle excitations (in particular, the low energy excitations, namely the quasiparticles) in systems of cold fermionic atoms, with energy and momentum resolution. This type of spectroscopy is an analogue of angular-resolved photoemission in solid state physics (ARPES). We have shown, via simple models, that this method of measurement can characterize quasiparticles not only in the 'conventional' phases such as the weakly interacting gas in the lattice or in Fermi

  11. Rydberg Molecules for Ion-Atom Scattering in the Ultracold Regime.

    Science.gov (United States)

    Schmid, T; Veit, C; Zuber, N; Löw, R; Pfau, T; Tarana, M; Tomza, M

    2018-04-13

    We propose a novel experimental method to extend the investigation of ion-atom collisions from the so far studied cold, essentially classical regime to the ultracold, quantum regime. The key aspect of this method is the use of Rydberg molecules to initialize the ultracold ion-atom scattering event. We exemplify the proposed method with the lithium ion-atom system, for which we present simulations of how the initial Rydberg molecule wave function, freed by photoionization, evolves in the presence of the ion-atom scattering potential. We predict bounds for the ion-atom scattering length from ab initio calculations of the interaction potential. We demonstrate that, in the predicted bounds, the scattering length can be experimentally determined from the velocity of the scattered wave packet in the case of ^{6}Li^{+}-^{6}Li and from the molecular ion fraction in the case of ^{7}Li^{+}-^{7}Li. The proposed method to utilize Rydberg molecules for ultracold ion-atom scattering, here particularized for the lithium ion-atom system, is readily applicable to other ion-atom systems as well.

  12. Effects of mode profile on tunneling and traversal of ultracold atoms through vacuum-induced potentials

    Science.gov (United States)

    Badshah, Fazal; Irfan, Muhammad; Qamar, Sajid; Qamar, Shahid

    2016-04-01

    We consider the resonant interaction of an ultracold two-level atom with an electromagnetic field inside a high-Q micromaser cavity. In particular, we study the tunneling and traversal of ultracold atoms through vacuum-induced potentials for secant hyperbolic square and sinusoidal cavity mode functions. The phase time which may be considered as an appropriate measure of the time required for the atoms to cross the cavity, significantly modifies with the change of cavity mode profile. For example, switching between the sub and superclassical behaviors in phase time can occur due to the mode function. Similarly, negative phase time appears for the transmission of the two-level atoms in both excited and ground states for secant hyperbolic square mode function which is in contrast to the mesa mode case.

  13. Quantifying, characterizing, and controlling information flow in ultracold atomic gases

    International Nuclear Information System (INIS)

    Haikka, P.; McEndoo, S.; Maniscalco, S.; De Chiara, G.; Palma, G. M.

    2011-01-01

    We study quantum information flow in a model comprised of a trapped impurity qubit immersed in a Bose-Einstein-condensed reservoir. We demonstrate how information flux between the qubit and the condensate can be manipulated by engineering the ultracold reservoir within experimentally realistic limits. We show that this system undergoes a transition from Markovian to non-Markovian dynamics, which can be controlled by changing key parameters such as the condensate scattering length. In this way, one can realize a quantum simulator of both Markovian and non-Markovian open quantum systems, the latter ones being characterized by a reverse flow of information from the background gas (reservoir) to the impurity (system).

  14. Floquet Engineering of Correlated Tunneling in the Bose-Hubbard Model with Ultracold Atoms.

    Science.gov (United States)

    Meinert, F; Mark, M J; Lauber, K; Daley, A J; Nägerl, H-C

    2016-05-20

    We report on the experimental implementation of tunable occupation-dependent tunneling in a Bose-Hubbard system of ultracold atoms via time-periodic modulation of the on-site interaction energy. The tunneling rate is inferred from a time-resolved measurement of the lattice site occupation after a quantum quench. We demonstrate coherent control of the tunneling dynamics in the correlated many-body system, including full suppression of tunneling as predicted within the framework of Floquet theory. We find that the tunneling rate explicitly depends on the atom number difference in neighboring lattice sites. Our results may open up ways to realize artificial gauge fields that feature density dependence with ultracold atoms.

  15. Superexchange-mediated magnetization dynamics with ultracold alkaline-earth atoms in an optical lattice

    International Nuclear Information System (INIS)

    Zhu Shaobing; Qian Jun; Wang Yuzhu

    2017-01-01

    Superexchange and inter-orbital spin-exchange interactions are key ingredients for understanding (orbital) quantum magnetism in strongly correlated systems and have been realized in ultracold atomic gases. Here we study the spin dynamics of ultracold alkaline-earth atoms in an optical lattice when the two exchange interactions coexist. In the superexchange interaction dominating regime, we find that the time-resolved spin imbalance shows a remarkable modulated oscillation, which can be attributed to the interplay between local and nonlocal quantum mechanical exchange mechanisms. Moreover, the filling of the long-lived excited atoms affects the collapse and revival of the magnetization dynamics. These observations can be realized in state-dependent optical lattices combined with the state-of-the-art advances in optical lattice clock spectroscopy. (paper)

  16. A hybrid system of a membrane oscillator coupled to ultracold atoms

    Science.gov (United States)

    Kampschulte, Tobias

    2015-05-01

    The control over micro- and nanomechanical oscillators has recently made impressive progress. First experiments demonstrated ground-state cooling and single-phonon control of high-frequency oscillators using cryogenic cooling and techniques of cavity optomechanics. Coupling engineered mechanical structures to microscopic quantum system with good coherence properties offers new possibilities for quantum control of mechanical vibrations, precision sensing and quantum-level signal transduction. Ultracold atoms are an attractive choice for such hybrid systems: Mechanical can either be coupled to the motional state of trapped atoms, which can routinely be ground-state cooled, or to the internal states, for which a toolbox of coherent manipulation and detection exists. Furthermore, atomic collective states with non-classical properties can be exploited to infer the mechanical motion with reduced quantum noise. Here we use trapped ultracold atoms to sympathetically cool the fundamental vibrational mode of a Si3N4 membrane. The coupling of membrane and atomic motion is mediated by laser light over a macroscopic distance and enhanced by an optical cavity around the membrane. The observed cooling of the membrane from room temperature to 650 +/- 230 mK shows that our hybrid mechanical-atomic system operates at a large cooperativity. Our scheme could provide ground-state cooling and quantum control of low-frequency oscillators such as levitated nanoparticles, in a regime where purely optomechanical techniques cannot reach the ground state. Furthermore, we will present a scheme where an optomechanical system is coupled to internal states of ultracold atoms. The mechanical motion is translated into a polarization rotation which drives Raman transitions between atomic ground states. Compared to the motional-state coupling, the new scheme enables to couple atoms to high-frequency structures such as optomechanical crystals.

  17. Measuring the One-Particle Excitations of Ultracold Fermionic Atoms by Stimulated Raman Spectroscopy

    International Nuclear Information System (INIS)

    Dao, T.-L.; Georges, Antoine; Dalibard, Jean; Salomon, Christophe; Carusotto, Iacopo

    2007-01-01

    We propose a Raman spectroscopy technique which is able to probe the one-particle Green function, the Fermi surface, and the quasiparticles of a gas of strongly interacting ultracold atoms. We give quantitative examples of experimentally accessible spectra. The efficiency of the method is validated by means of simulated images for the case of a usual Fermi liquid as well as for more exotic states: specific signatures of, e.g., a d-wave pseudogap are clearly visible

  18. Tunable superconducting resonators with integrated trap structures for coupling with ultracold atomic gases

    Energy Technology Data Exchange (ETDEWEB)

    Ferdinand, Benedikt; Wiedmaier, Dominik; Koelle, Dieter; Kleiner, Reinhold [Physikalisches Institut and Center for Quantum Science in LISA+, Universitaet Tuebingen (Germany); Bothner, Daniel [Physikalisches Institut and Center for Quantum Science in LISA+, Universitaet Tuebingen (Germany); Kavli Institute of Nanoscience, Delft University of Technology, Delft (Netherlands)

    2016-07-01

    We intend to investigate a hybrid quantum system where ultracold atomic gases play the role of a long-living quantum memory, coupled to a superconducting qubit via a coplanar waveguide transmission line resonator. As a first step we developed a resonator chip containing a Z-shaped trapping wire for the atom trap. In order to suppress parasitic resonances due to stray capacitances, and to achieve good ground connection we use hybrid superconductor - normal conductor chips. As an additional degree of freedom we add a ferroelectric capacitor making the resonators voltage-tunable. We furthermore show theoretical results on the expected coupling strength between resonator and atomic cloud.

  19. Disordered ultracold atomic gases in optical lattices: A case study of Fermi-Bose mixtures

    International Nuclear Information System (INIS)

    Ahufinger, V.; Sanchez-Palencia, L.; Kantian, A.; Sanpera, A.; Lewenstein, M.

    2005-01-01

    We present a review of properties of ultracold atomic Fermi-Bose mixtures in inhomogeneous and random optical lattices. In the strong interacting limit and at very low temperatures, fermions form, together with bosons or bosonic holes, composite fermions. Composite fermions behave as a spinless interacting Fermi gas, and in the presence of local disorder they interact via random couplings and feel effective random local potential. This opens a wide variety of possibilities of realizing various kinds of ultracold quantum disordered systems. In this paper we review these possibilities, discuss the accessible quantum disordered phases, and methods for their detection. The discussed quantum phases include Fermi glasses, quantum spin glasses, 'dirty' superfluids, disordered metallic phases, and phases involving quantum percolation

  20. Quantum information entropies of ultracold atomic gases in a ...

    Indian Academy of Sciences (India)

    The position and momentum space information entropies of weakly interacting trapped atomic Bose–Einstein condensates and spin-polarized trapped atomic Fermi gases at absolute zero temperature are evaluated. We find that sum of the position and momentum space information entropies of these quantum systems ...

  1. De Haas-van Alphen effect of a two-dimensional ultracold atomic gas

    Science.gov (United States)

    Farias, B.; Furtado, C.

    2016-01-01

    In this paper, we show how the ultracold atom analogue of the two-dimensional de Haas-van Alphen effect in electronic condensed matter systems can be induced by optical fields in a neutral atomic system. The interaction between the suitable spatially varying laser fields and tripod-type trapped atoms generates a synthetic magnetic field which leads the particles to organize themselves in Landau levels. Initially, with the atomic gas in a regime of lowest Landau level, we display the oscillatory behaviour of the atomic energy and its derivative with respect to the effective magnetic field (B) as a function of 1/B. Furthermore, we estimate the area of the Fermi circle of the two-dimensional atomic gas.

  2. Ultracold atoms in optical lattices simulating quantum many-body systems

    CERN Document Server

    Lewenstein, Maciej; Ahufinger, Verònica

    2012-01-01

    Quantum computers, though not yet available on the market, will revolutionize the future of information processing. Quantum computers for special purposes like quantum simulators are already within reach. The physics of ultracold atoms, ions and molecules offer unprecedented possibilities of control of quantum many body systems and novel possibilities of applications to quantum information processing and quantum metrology. Particularly fascinating is the possibility of usingultracold atoms in lattices to simulate condensed matter or even high energy physics.This book provides a complete and co

  3. Generating a picokelvin ultracold atomic ensemble in microgravity

    International Nuclear Information System (INIS)

    Wang, Lu; Ma, Zhao-Yuan; Zhang, Peng; Chen, Xu-Zong

    2013-01-01

    Applying the direct Monte Carlo simulation (DSMC) method developed for a cold atom system, we study the evaporative cooling process in tilted optical dipole traps with a magnetic field gradient-induced over-levitation or merely a gravitational force. We propose a two-stage decomposed evaporative cooling process in a microgravity environment, and suggest that quantum degeneracy can be obtained at a few picokelvins with several thousand atoms. (paper)

  4. Holographic method for site-resolved detection of a 2D array of ultracold atoms

    Science.gov (United States)

    Hoffmann, Daniel Kai; Deissler, Benjamin; Limmer, Wolfgang; Hecker Denschlag, Johannes

    2016-08-01

    We propose a novel approach to site-resolved detection of a 2D gas of ultracold atoms in an optical lattice. A near-resonant laser beam is coherently scattered by the atomic array, and after passing a lens its interference pattern is holographically recorded by superimposing it with a reference laser beam on a CCD chip. Fourier transformation of the recorded intensity pattern reconstructs the atomic distribution in the lattice with single-site resolution. The holographic detection method requires only about two hundred scattered photons per atom in order to achieve a high reconstruction fidelity of 99.9 %. Therefore, additional cooling during detection might not be necessary even for light atomic elements such as lithium. Furthermore, first investigations suggest that small aberrations of the lens can be post-corrected in imaging processing.

  5. A quantum trampoline for ultra-cold atoms

    Science.gov (United States)

    Robert-de-Saint-Vincent, M.; Brantut, J.-P.; Bordé, Ch. J.; Aspect, A.; Bourdel, T.; Bouyer, P.

    2010-01-01

    We have observed the interferometric suspension of a free-falling Bose-Einstein condensate periodically submitted to multiple-order diffraction by a vertical 1D standing wave. This scheme permits simultaneously the compensation of gravity and coherent splitting/recombination of the matter waves. It results in high-contrast interference in the number of atoms detected at constant height. For long suspension times, multiple-wave interference is revealed through a sharpening of the fringes. We characterize our atom interferometer and use it to measure the acceleration of gravity.

  6. Scattering amplitude of ultracold atoms near the p-wave magnetic Feshbach resonance

    International Nuclear Information System (INIS)

    Zhang Peng; Naidon, Pascal; Ueda, Masahito

    2010-01-01

    Most of the current theories on the p-wave superfluid in cold atomic gases are based on the effective-range theory for the two-body scattering, where the low-energy p-wave scattering amplitude f 1 (k) is given by f 1 (k)=-1/[ik+1/(Vk 2 )+1/R]. Here k is the incident momentum, V and R are the k-independent scattering volume and effective range, respectively. However, due to the long-range nature of the van der Waals interaction between two colliding ultracold atoms, the p-wave scattering amplitude of the two atoms is not described by the effective-range theory [J. Math. Phys. 4, 54 (1963); Phys. Rev. A 58, 4222 (1998)]. In this paper we provide an explicit calculation for the p-wave scattering of two ultracold atoms near the p-wave magnetic Feshbach resonance. We show that in this case the low-energy p-wave scattering amplitude f 1 (k)=-1/[ik+1/(V eff k 2 )+1/(S eff k)+1/R eff ] where V eff , S eff , and R eff are k-dependent parameters. Based on this result, we identify sufficient conditions for the effective-range theory to be a good approximation of the exact scattering amplitude. Using these conditions we show that the effective-range theory is a good approximation for the p-wave scattering in the ultracold gases of 6 Li and 40 K when the scattering volume is enhanced by the resonance.

  7. Reactive Collisions and Interactions of Ultracold Dipolar Atoms

    Science.gov (United States)

    2014-10-29

    Kotochigova Department of Physics, Temple University, Philadelphia, PA 19122-6082 I. COLLISIONAL INTERACTIONS OF RARE- EARTH MAGNETIC ATOMS The breakthroughs...technologies, it was not previously implemented, possibly owing to the misconception that molecular ions predominantly undergo charge-exchange reactions leading

  8. Quantum phases of low-dimensional ultra-cold atom systems

    Science.gov (United States)

    Mathey, Ludwig G.

    2007-06-01

    In this thesis we derive and explore the quantum phases of various types of ultracold atom systems, as well as their experimental signature. The technology of cooling, trapping and manipulating ultracold atoms has advanced in an amazing fashion during the last decade, which has led to the study of many-body effects of atomic ensembles. We first consider atomic mixtures in one dimension, which show a rich structure of phases, using a Luttinger liquid description. We then go on to consider how noise correlations in time-of-flight images of one-dimensional systems can be used to draw conclusions about the many-body state that they're in. Thirdly, we consider the quantum phases of Bose-Fermi mixtures in optical lattices, either square lattices or triangular lattices, using the powerful method of functional renormalization group analysis. Lastly, we study the phases of two-coupled quasi-superfluids in two dimensions, which shows unusual phases, and which could be used to realize the Kibble-Zurek mechanism, i.e. the generation of topological defects by ramping across a phase transition, first proposed in the context of an early universe scenario.

  9. Atom Interferometry with Ultracold Quantum Gases in a Microgravity Environment

    Science.gov (United States)

    Williams, Jason; D'Incao, Jose; Chiow, Sheng-Wey; Yu, Nan

    2015-05-01

    Precision atom interferometers (AI) in space promise exciting technical capabilities for fundamental physics research, with proposals including unprecedented tests of the weak equivalence principle, precision measurements of the fine structure and gravitational constants, and detection of gravity waves and dark energy. Consequently, multiple AI-based missions have been proposed to NASA, including a dual-atomic-species interferometer that is to be integrated into the Cold Atom Laboratory (CAL) onboard the International Space Station. In this talk, I will discuss our plans and preparation at JPL for the proposed flight experiments to use the CAL facility to study the leading-order systematics expected to corrupt future high-precision measurements of fundamental physics with AIs in microgravity. The project centers on the physics of pairwise interactions and molecular dynamics in these quantum systems as a means to overcome uncontrolled shifts associated with the gravity gradient and few-particle collisions. We will further utilize the CAL AI for proof-of-principle tests of systematic mitigation and phase-readout techniques for use in the next-generation of precision metrology experiments based on AIs in microgravity. This research was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration.

  10. Realizing analogues of color superconductivity with ultracold alkali atoms

    International Nuclear Information System (INIS)

    O'Hara, K M

    2011-01-01

    A degenerate three-component Fermi gas of atoms with identical attractive interactions is expected to exhibit superfluidity and magnetic order at low temperature and, for sufficiently strong pairwise interactions, become a Fermi liquid of weakly interacting trimers. The phase diagram of this system is analogous to that of quark matter at low temperature, motivating strong interest in its investigation. We describe how a three-component gas below the superfluid critical temperature can be prepared in an optical lattice. To realize an SU(3)-symmetric system, we show how pairwise interactions in the three-component atomic system can be made equal by applying radiofrequency and microwave radiation. Finally, motivated by the aim to make more accurate models of quark matter, which have color, flavor and spin degrees of freedom, we discuss how an atomic system with SU(2)xSU(3) symmetry can be achieved by confining a three-component Fermi gas in the p-orbital band of an optical lattice potential.

  11. Realization of the manipulation of ultracold atoms with a reconfigurable nanomagnetic system of domain walls.

    Science.gov (United States)

    West, Adam D; Weatherill, Kevin J; Hayward, Thomas J; Fry, Paul W; Schrefl, Thomas; Gibbs, Mike R J; Adams, Charles S; Allwood, Dan A; Hughes, Ifan G

    2012-08-08

    Planar magnetic nanowires have been vital to the development of spintronic technology. They provide an unparalleled combination of magnetic reconfigurability, controllability, and scalability, which has helped to realize such applications as racetrack memory and novel logic gates. Microfabricated atom optics benefit from all of these properties, and we present the first demonstration of the amalgamation of spintronic technology with ultracold atoms. A magnetic interaction is exhibited through the reflection of a cloud of (87)Rb atoms at a temperature of 10 μK, from a 2 mm × 2 mm array of nanomagnetic domain walls. In turn, the incident atoms approach the array at heights of the order of 100 nm and are thus used to probe magnetic fields at this distance.

  12. Numerical methods for atomic quantum gases with applications to Bose-Einstein condensates and to ultracold fermions

    NARCIS (Netherlands)

    Minguzzi, A.; Succi, S.; Toschi, F.; Tosi, M.P.; Vignolo, P.

    2004-01-01

    The achievement of Bose–Einstein condensation in ultra-cold vapours of alkali atoms has given enormous impulse to the study of dilute atomic gases in condensed quantum states inside magnetic traps and optical lattices. High-purity and easy optical access make them ideal candidates to investigate

  13. First-principles many-body theory for ultra-cold atoms

    International Nuclear Information System (INIS)

    Drummond, Peter D.; Hu Hui; Liu Xiaji

    2010-01-01

    Recent breakthroughs in the creation of ultra-cold atoms in the laboratory have ushered in unprecedented changes in physical science. These enormous changes in the coldest temperatures available in the laboratory mean that many novel experiments are possible. There is unprecedented control and simplicity in these novel systems, meaning that quantum many-body theory is now facing severe challenges in quantitatively understanding these new results. We discuss some of the new experiments and recently developed theoretical techniques required to predict the results obtained.

  14. Conjugate gradient minimisation approach to generating holographic traps for ultracold atoms.

    Science.gov (United States)

    Harte, Tiffany; Bruce, Graham D; Keeling, Jonathan; Cassettari, Donatella

    2014-11-03

    Direct minimisation of a cost function can in principle provide a versatile and highly controllable route to computational hologram generation. Here we show that the careful design of cost functions, combined with numerically efficient conjugate gradient minimisation, establishes a practical method for the generation of holograms for a wide range of target light distributions. This results in a guided optimisation process, with a crucial advantage illustrated by the ability to circumvent optical vortex formation during hologram calculation. We demonstrate the implementation of the conjugate gradient method for both discrete and continuous intensity distributions and discuss its applicability to optical trapping of ultracold atoms.

  15. Symmetry breaking in small rotating clouds of trapped ultracold Bose atoms

    International Nuclear Information System (INIS)

    Dagnino, D.; Barberan, N.; Riera, A.; Osterloh, K.; Lewenstein, M.

    2007-01-01

    We study the signatures of rotational and phase symmetry breaking in small rotating clouds of trapped ultracold Bose atoms by looking at rigorously defined condensate wave function. Rotational symmetry breaking occurs in narrow frequency windows, where energy degeneracy between the lowest energy states of different total angular momentum takes place. This leads to a complex condensate wave function that exhibits vortices clearly seen as holes in the density, as well as characteristic local phase patterns, reflecting the appearance of vorticities. Phase symmetry (or gauge symmetry) breaking, on the other hand, is clearly manifested in the interference of two independent rotating clouds

  16. Photo-associative ionization in ultracold sodium atoms

    International Nuclear Information System (INIS)

    Bagnato, V.; Marcassa, L.; Tsao, C.; Wang, Y.; Weiner, J.

    1993-01-01

    We study photo-associative ionization (PAI) for sodium atoms held in a magneto-optical trap (T < 1 mK). The process is investigated using one and two laser frequencies. For a single color PAI, we measure the rate constant as a function of light intensity and the result is compared with calculation based on semiclassical Bloch equation theory. The measured rate constant appears to saturate sooner than theory. In the two-color PAI (TCPAI) we investigate individual steps of the process. Different combinations of laser frequencies prepare different populations in each of the hyperfine ground state and the contribution of each one in this collisional process is investigated. The comparison with theory allows a fairly clear understanding of PAI and TCPAI

  17. Robust mesoscopic superposition of strongly correlated ultracold atoms

    International Nuclear Information System (INIS)

    Hallwood, David W.; Ernst, Thomas; Brand, Joachim

    2010-01-01

    We propose a scheme to create coherent superpositions of annular flow of strongly interacting bosonic atoms in a one-dimensional ring trap. The nonrotating ground state is coupled to a vortex state with mesoscopic angular momentum by means of a narrow potential barrier and an applied phase that originates from either rotation or a synthetic magnetic field. We show that superposition states in the Tonks-Girardeau regime are robust against single-particle loss due to the effects of strong correlations. The coupling between the mesoscopically distinct states scales much more favorably with particle number than in schemes relying on weak interactions, thus making particle numbers of hundreds or thousands feasible. Coherent oscillations induced by time variation of parameters may serve as a 'smoking gun' signature for detecting superposition states.

  18. Dark states and interferences in cascade transitions of ultracold atoms in a cavity

    International Nuclear Information System (INIS)

    Arun, R.; Agarwal, G.S.

    2002-01-01

    We examine the competition among one- and two-photon processes in an ultracold, three-level atom undergoing cascade transitions as a result of its interaction with a bimodal cavity. We show parameter domains where two-photon transitions are dominant, and we also study the effect of two-photon emission on the mazer action in the cavity. The two-photon emission leads to the loss of detailed balance and therefore we obtain the photon statistics of the cavity field by the numerical integration of the master equation. The photon distribution in each cavity mode exhibits sub- and super-Poissonian behaviors depending on the strength of atom-field coupling. The photon distribution becomes identical to a Poisson distribution when the atom-field coupling strengths of the modes are equal

  19. Towards experimental quantum-field tomography with ultracold atoms.

    Science.gov (United States)

    Steffens, A; Friesdorf, M; Langen, T; Rauer, B; Schweigler, T; Hübener, R; Schmiedmayer, J; Riofrío, C A; Eisert, J

    2015-07-03

    The experimental realization of large-scale many-body systems in atomic-optical architectures has seen immense progress in recent years, rendering full tomography tools for state identification inefficient, especially for continuous systems. To work with these emerging physical platforms, new technologies for state identification are required. Here we present first steps towards efficient experimental quantum-field tomography. Our procedure is based on the continuous analogues of matrix-product states, ubiquitous in condensed-matter theory. These states naturally incorporate the locality present in realistic physical settings and are thus prime candidates for describing the physics of locally interacting quantum fields. To experimentally demonstrate the power of our procedure, we quench a one-dimensional Bose gas by a transversal split and use our method for a partial quantum-field reconstruction of the far-from-equilibrium states of this system. We expect our technique to play an important role in future studies of continuous quantum many-body systems.

  20. Probe Knots and Hopf Insulators with Ultracold Atoms

    Science.gov (United States)

    Deng, Dong-Ling; Wang, Sheng-Tao; Sun, Kai; Duan, L.-M.

    2018-01-01

    Knots and links are fascinating and intricate topological objects. Their influence spans from DNA and molecular chemistry to vortices in superfluid helium, defects in liquid crystals and cosmic strings in the early universe. Here we find that knotted structures also exist in a peculiar class of three-dimensional topological insulators—the Hopf insulators. In particular, we demonstrate that the momentum-space spin textures of Hopf insulators are twisted in a nontrivial way, which implies the presence of various knot and link structures. We further illustrate that the knots and nontrivial spin textures can be probed via standard time-of-flight images in cold atoms as preimage contours of spin orientations in stereographic coordinates. The extracted Hopf invariants, knots, and links are validated to be robust to typical experimental imperfections. Our work establishes the existence of knotted structures in Hopf insulators, which may have potential applications in spintronics and quantum information processing. D.L.D., S.T.W. and L.M.D. are supported by the ARL, the IARPA LogiQ program, and the AFOSR MURI program, and supported by Tsinghua University for their visits. K.S. acknowledges the support from NSF under Grant No. PHY1402971. D.L.D. is also supported by JQI-NSF-PFC and LPS-MPO-CMTC at the final stage of this paper.

  1. Ultracold atoms in a cavity-mediated double-well system

    International Nuclear Information System (INIS)

    Larson, Jonas; Martikainen, Jani-Petri

    2010-01-01

    We study ground-state properties and dynamics of a dilute ultracold atomic gas in a double-well potential. The Gaussian barrier separating the two wells derives from the interaction between the atoms and a quantized field of a driven Fabry-Perot cavity. Due to intrinsic atom-field nonlinearity, several interesting phenomena arise which are the focus of this work. For the ground state, there is a critical pumping amplitude in which the atoms self-organize and the intra-cavity-field amplitude drastically increases. In the dynamical analysis, we show that the Josephson oscillations depend strongly on the atomic density and may be greatly suppressed within certain regimes, reminiscent of self-trapping of Bose-Einstein condensates in double-well setups. This pseudo-self-trapping effect is studied within a mean-field treatment valid for large atom numbers. For small numbers of atoms, we consider the analogous many-body problem and demonstrate a collapse-revival structure in the Josephson oscillations.

  2. Sympathetic cooling in a rubidium cesium mixture: Production of ultracold cesium atoms

    International Nuclear Information System (INIS)

    Haas, M.

    2007-01-01

    This thesis presents experiments for the production of ultracold rubidium cesium mixture in a magnetic trap. The long-termed aim of the experiment is the study of the interaction of few cesium atoms with a Bose-Einstein condensate of rubidium atoms. Especially by controlled variation of the cesium atom number the transition in the description of the interaction by concepts of the one-particle physics to the description by concepts of the many-particle physics shall be studied. The rubidium atoms are trapped in a magneto-optical trap (MOT) and from there reloaded into a magnetic trap. In this the rubidium atoms are stored in the state vertical stroke f=2,m f =2 right angle of the electronic ground state and evaporatively cooled by means of microwave-induced transitions into the state vertical stroke f=1,m f =1] (microwave cooling). The cesium atoms are also trppaed in a MOT and into the same magnetic trap reloaded, in which they are stored in the state vertical stroke f=4,m f =4 right angle of the electronic ground state together with rubidium. Because of the different hyperfine splitting only rubidium is evaporatively cooled, while cesium is cooled jointly sympathetically - i.e. by theramal contact via elastic collisions with rubidium atoms. The first two chapters contain a description of interatomic interactions in ultracold gases as well as a short summary of theoretical concepts in the description of Bose-Einstein condensates. The chapters 3 and 4 contain a short presentation of the methods applied in the experiment for the production of ultracold gases as well as the experimental arrangement; especially in the framework of this thesis a new coil system has been designed, which offers in view of future experiments additionally optical access for an optical trap. Additionally the fourth chapter contains an extensive description of the experimental cycle, which is applied in order to store rubidium and cesium atoms together into the magnetic trap. The last chapter

  3. Experimental apparatus for overlapping a ground-state cooled ion with ultracold atoms

    Science.gov (United States)

    Meir, Ziv; Sikorsky, Tomas; Ben-shlomi, Ruti; Akerman, Nitzan; Pinkas, Meirav; Dallal, Yehonatan; Ozeri, Roee

    2018-03-01

    Experimental realizations of charged ions and neutral atoms in overlapping traps are gaining increasing interest due to their wide research application ranging from chemistry at the quantum level to quantum simulations of solid state systems. In this paper, we describe our experimental system in which we overlap a single ground-state cooled ion trapped in a linear Paul trap with a cloud of ultracold atoms such that both constituents are in the ?K regime. Excess micromotion (EMM) currently limits atom-ion interaction energy to the mK energy scale and above. We demonstrate spectroscopy methods and compensation techniques which characterize and reduce the ion's parasitic EMM energy to the ?K regime even for ion crystals of several ions. We further give a substantial review on the non-equilibrium dynamics which governs atom-ion systems. The non-equilibrium dynamics is manifested by a power law distribution of the ion's energy. We also give an overview on the coherent and non-coherent thermometry tools which can be used to characterize the ion's energy distribution after single to many atom-ion collisions.

  4. Observation of Spin Polarons in a Tunable Fermi Liquid of Ultracold Atoms

    Science.gov (United States)

    Zwierlein, Martin

    2009-05-01

    We have observed spin polarons, dressed spin down impurities in a spin up Fermi sea of ultracold atoms via tomographic RF spectroscopy. Feshbach resonances allow to freely tune the interactions between the two spin states involved. A single spin down atom immersed in a Fermi sea of spin up atoms can do one of two things: For strong attraction, it can form a molecule with exactly one spin up partner, but for weaker interaction it will spread its attraction and surround itself with a collection of majority atoms. This spin down atom dressed with a spin up cloud constitutes the spin- or Fermi polaron. We have observed a striking spectroscopic signature of this quasi-particle for various interaction strengths, a narrow peak in the spin down spectrum that emerges above a broad background. The spectra allow us to directly measure the polaron energy and the quasi-particle residue Z. The polarons are found to be only weakly interacting with each other, and can thus be identified with the quasi-particles of Landau's Fermi liquid theory. At a critical interaction strength, we observe a transition from spin one-half polarons to spin zero molecules. At this point the Fermi liquid undergoes a phase transition into a superfluid Bose liquid.

  5. Tunable spin-orbit coupling for ultracold atoms in two-dimensional optical lattices

    Science.gov (United States)

    Grusdt, Fabian; Li, Tracy; Bloch, Immanuel; Demler, Eugene

    2017-06-01

    Spin-orbit coupling (SOC) is at the heart of many exotic band structures and can give rise to many-body states with topological order. Here we present a general scheme based on a combination of microwave driving and lattice shaking for the realization of two-dimensional SOC with ultracold atoms in systems with inversion symmetry. We show that the strengths of Rashba and Dresselhaus SOC can be independently tuned in a spin-dependent square lattice. More generally, our method can be used to open gaps between different spin states without breaking time-reversal symmetry. We demonstrate that this allows for the realization of topological insulators with nontrivial spin textures closely related to the Kane-Mele model.

  6. Lattice-Assisted Spectroscopy: A Generalized Scanning Tunneling Microscope for Ultracold Atoms.

    Science.gov (United States)

    Kantian, A; Schollwöck, U; Giamarchi, T

    2015-10-16

    We propose a scheme to measure the frequency-resolved local particle and hole spectra of any optical lattice-confined system of correlated ultracold atoms that offers single-site addressing and imaging, which is now an experimental reality. Combining perturbation theory and time-dependent density matrix renormalization group simulations, we quantitatively test and validate this approach of lattice-assisted spectroscopy on several one-dimensional example systems, such as the superfluid and Mott insulator, with and without a parabolic trap, and finally on edge states of the bosonic Su-Schrieffer-Heeger model. We highlight extensions of our basic scheme to obtain an even wider variety of interesting and important frequency resolved spectra.

  7. Ultracold atoms in one-dimensional optical lattices approaching the Tonks-Girardeau regime

    International Nuclear Information System (INIS)

    Pollet, L.; Rombouts, S.M.A.; Denteneer, P.J. H.

    2004-01-01

    Recent experiments on ultracold atomic alkali gases in a one-dimensional optical lattice have demonstrated the transition from a gas of soft-core bosons to a Tonks-Girardeau gas in the hard-core limit, where one-dimensional bosons behave like fermions in many respects. We have studied the underlying many-body physics through numerical simulations which accommodate both the soft-core and hard-core limits in one single framework. We find that the Tonks-Girardeau gas is reached only at the strongest optical lattice potentials. Results for slightly higher densities, where the gas develops a Mott-like phase already at weaker optical lattice potentials, show that these Mott-like short-range correlations do not enhance the convergence to the hard-core limit

  8. Fast, High-Precision Optical Polarization Synthesizer for Ultracold-Atom Experiments

    Science.gov (United States)

    Robens, Carsten; Brakhane, Stefan; Alt, Wolfgang; Meschede, Dieter; Zopes, Jonathan; Alberti, Andrea

    2018-03-01

    We present a technique for the precision synthesis of arbitrary polarization states of light with a high modulation bandwidth. Our approach consists of superimposing two laser light fields with the same wavelength, but with opposite circular polarizations, where the phase and the amplitude of each light field are individually controlled. We find that the polarization-synthesized beam reaches a degree of polarization of 99.99%, which is mainly limited by static spatial variations of the polarization state over the beam profile. We also find that the depolarization caused by temporal fluctuations of the polarization state is about 2 orders of magnitude smaller. In a recent work, Robens et al. [Low-Entropy States of Neutral Atoms in Polarization-Synthesized Optical Lattices, Phys. Rev. Lett. 118, 065302 (2017), 10.1103/PhysRevLett.118.065302] demonstrated an application of the polarization synthesizer to create two independently controllable optical lattices which trap atoms depending on their internal spin state. We use ultracold atoms in polarization-synthesized optical lattices to give an independent, in situ demonstration of the performance of the polarization synthesizer.

  9. Superfluidity and BCS-BEC crossover of ultracold atomic Fermi gases in mixed dimensions

    Science.gov (United States)

    Zhang, Leifeng; Chen, Qijin

    Atomic Fermi gases have been under active investigation in the past decade. Here we study the superfluid and pairing phenomena of a two-component ultracold atomic Fermi gas in the presence of mixed dimensionality, in which one component is confined on a 1D optical lattice whereas the other is free in the 3D continuum. We assume a short-range pairing interaction and determine the superfluid transition temperature Tc and the phase diagram for the entire BCS-BEC crossover, using a pairing fluctuation theory which includes self-consistently the contributions of finite momentum pairs. We find that, as the lattice depth increases and the lattice spacing decreases, the behavior of Tc becomes very similar to that of a population imbalance Fermi gas in a simple 3D continuum. There is no superfluidity even at T = 0 below certain threshold of pairing strength in the BCS regime. Nonmonotonic Tc behavior and intermediate temperature superfluidity emerge, and for deep enough lattice, the Tc curve will split into two parts. Implications for experiment will be discussed. References: 1. Q.J. Chen, Ioan Kosztin, B. Janko, and K. Levin, Phys. Rev. B 59, 7083 (1999). 2. Chih-Chun Chien, Qijin Chen, Yan He, and K. Levin, Phys. Rev. Lett. 97, 090402(2006). Work supported by NSF of China and the National Basic Research Program of China.

  10. Evolution from Rydberg gas to ultracold plasma in a supersonic atomic beam of Xe

    International Nuclear Information System (INIS)

    Hung, J; Sadeghi, H; Schulz-Weiling, M; Grant, E R

    2014-01-01

    A Rydberg gas of xenon, entrained in a supersonic atomic beam, evolves slowly to form an ultracold plasma. In the early stages of this evolution, when the free-electron density is low, Rydberg atoms undergo long-range ℓ-mixing collisions, yielding states of high orbital angular momentum. The development of high-ℓ states promotes dipole–dipole interactions that help to drive Penning ionization. The electron density increases until it reaches the threshold for avalanche. Ninety μs after the production of a Rydberg gas with the initial state, n 0 ℓ 0 =42d, a 432 V cm −1 electrostatic pulse fails to separate charge in the excited volume, an effect which is ascribed to screening by free electrons. Photoexcitation cross sections, observed rates of ℓ-mixing, and a coupled-rate-equation model simulating the onset of the electron-impact avalanche point consistently to an initial Rydberg gas density of 5×10 8 cm −3 . (paper)

  11. Evolution from Rydberg gas to ultracold plasma in a supersonic atomic beam of Xe

    Science.gov (United States)

    Hung, J.; Sadeghi, H.; Schulz-Weiling, M.; Grant, E. R.

    2014-08-01

    A Rydberg gas of xenon, entrained in a supersonic atomic beam, evolves slowly to form an ultracold plasma. In the early stages of this evolution, when the free-electron density is low, Rydberg atoms undergo long-range \\ell -mixing collisions, yielding states of high orbital angular momentum. The development of high-\\ell states promotes dipole-dipole interactions that help to drive Penning ionization. The electron density increases until it reaches the threshold for avalanche. Ninety μs after the production of a Rydberg gas with the initial state, {{n}_{0}}{{\\ell }_{0}}=42d, a 432 V cm-1 electrostatic pulse fails to separate charge in the excited volume, an effect which is ascribed to screening by free electrons. Photoexcitation cross sections, observed rates of \\ell -mixing, and a coupled-rate-equation model simulating the onset of the electron-impact avalanche point consistently to an initial Rydberg gas density of 5\\times {{10}^{8}}\\;c{{m}^{-3}}.

  12. Generalized quantum mean-field systems and their application to ultracold atoms

    International Nuclear Information System (INIS)

    Trimborn-Witthaut, Friederike Annemarie

    2011-01-01

    Strongly interacting many-body systems consisting of a large number of indistinguishable particles play an important role in many areas of physics. Though such systems are hard to deal with theoretically since the dimension of the respective Hilbert space increases exponentially both in the particle number and in the number of system modes. Therefore, approximations are of considerable interest. The mean-field approximation describes the behaviour in the macroscopic limit N→∞, which leads to an effective nonlinear single-particle problem. Although this approximation is widely used, rigorous results on the applicability and especially on finite size corrections are extremely rare. One prominent example of strongly interacting many-body systems are ultracold atoms in optical lattices, which are a major subject of this thesis. Typically these systems consist of a large but well-defined number of particles, such that corrections to the mean-field limit can be systematically studied. This thesis is divided into two parts: In the first part we study generalized quantum mean-field systems in a C * -algebraic framework. These systems are characterized by their intrinsic permutation symmetry. In the limit of infinite system size, N→∞, the intensive observables converge to the commutative algebra of weak * -continuous functions on the single particle state space. To quantify the deviations from the meanfield prediction for large but finite N, we establish a differential calculus for state space functions and provide a generalized Taylor expansion around the mean-field limit. Furthermore, we introduce the algebra of macroscopic fluctuations around the mean-field limit and prove a quantum version of the central limit theorem. On the basis of these results, we give a detailed study of the finite size corrections to the ground state energy and establish bounds, for both the quantum and the classical case. Finally, we restrict ourselves to the subspace of Bose

  13. Quantum many-body dynamics of ultracold atoms in optical lattices

    Energy Technology Data Exchange (ETDEWEB)

    Kessler, Stefan

    2014-04-15

    Ultracold atoms can be trapped in periodic intensity patterns of light created by counterpropagating laser beams, so-called optical lattices. In contrast to its natural counterpart, electrons in a solid state crystal, this man-made setup is very clean and highly isolated from environmental degrees of freedom. Moreover, to a large extent, the experimenter has dynamical control over the relevant system parameters: the interaction between atoms, the tunneling amplitude between lattice sites, and even the dimensionality of the lattice. These advantages render this system a unique platform for the simulation of quantum many-body dynamics for various lattice Hamiltonians as has been demonstrated in several experiments by now. The most significant step in recent times has arguably been the introduction of single-site detection of individual atoms in optical lattices. This technique, based on fluorescence microscopy, opens a new doorway for the study of quantum many-body states: the detection of the microscopic atom configuration. In this thesis, we theoretically explore the dynamics of ultracold atoms in optical lattices for various setups realized in present-day experiments. Our main focus lies on aspects that become experimentally accessible by (realistic extensions of) the novel single-site measurement technique. The first part deals with the expansion of initially confined atoms in a homogeneous lattice, which is one way to create atomic motion in experiments. We analyze the buildup of spatial correlations during the expansion of a finitely extended band insulating state in one dimension. The numerical simulation reveals the creation of remote spin-entangled fermions in the strongly interacting regime. We discuss the experimental observation of such spin-entangled pairs by means of a single-site measurement. Furthermore, we suggest studying the impact of observations on the expansion dynamics for the extreme case of a projective measurement in the spatial occupation

  14. Quantum many-body dynamics of ultracold atoms in optical lattices

    International Nuclear Information System (INIS)

    Kessler, Stefan

    2014-01-01

    Ultracold atoms can be trapped in periodic intensity patterns of light created by counterpropagating laser beams, so-called optical lattices. In contrast to its natural counterpart, electrons in a solid state crystal, this man-made setup is very clean and highly isolated from environmental degrees of freedom. Moreover, to a large extent, the experimenter has dynamical control over the relevant system parameters: the interaction between atoms, the tunneling amplitude between lattice sites, and even the dimensionality of the lattice. These advantages render this system a unique platform for the simulation of quantum many-body dynamics for various lattice Hamiltonians as has been demonstrated in several experiments by now. The most significant step in recent times has arguably been the introduction of single-site detection of individual atoms in optical lattices. This technique, based on fluorescence microscopy, opens a new doorway for the study of quantum many-body states: the detection of the microscopic atom configuration. In this thesis, we theoretically explore the dynamics of ultracold atoms in optical lattices for various setups realized in present-day experiments. Our main focus lies on aspects that become experimentally accessible by (realistic extensions of) the novel single-site measurement technique. The first part deals with the expansion of initially confined atoms in a homogeneous lattice, which is one way to create atomic motion in experiments. We analyze the buildup of spatial correlations during the expansion of a finitely extended band insulating state in one dimension. The numerical simulation reveals the creation of remote spin-entangled fermions in the strongly interacting regime. We discuss the experimental observation of such spin-entangled pairs by means of a single-site measurement. Furthermore, we suggest studying the impact of observations on the expansion dynamics for the extreme case of a projective measurement in the spatial occupation

  15. Soliton Trains Induced by Adaptive Shaping with Periodic Traps in Four-Level Ultracold Atom Systems

    International Nuclear Information System (INIS)

    Djouom Tchenkoue, M. L.; Welakuh Mbangheku, D.; Dikandé, Alain M.

    2017-01-01

    It is well known that an optical trap can be imprinted by a light field in an ultracold-atom system embedded in an optical cavity, and driven by three different coherent fields. Of the three fields coexisting in the optical cavity there is an intense control field that induces a giant Kerr nonlinearity via electromagnetically-induced transparency, and another field that creates a periodic optical grating of strength proportional to the square of the associated Rabi frequency. In this work elliptic-soliton solutions to the nonlinear equation governing the propagation of the probe field are considered, with emphasis on the possible generation of optical soliton trains forming a discrete spectrum with well defined quantum numbers. The problem is treated assuming two distinct types of periodic optical gratings and taking into account the negative and positive signs of detunings (detuning above or below resonance). Results predict that the competition between the self-phase and cross-phase modulation nonlinearities gives rise to a rich family of temporal soliton train modes characterized by distinct quantum numbers. (paper)

  16. Soliton Trains Induced by Adaptive Shaping with Periodic Traps in Four-Level Ultracold Atom Systems

    Science.gov (United States)

    Djouom Tchenkoue, M. L.; Welakuh Mbangheku, D.; Dikandé, Alain M.

    2017-06-01

    It is well known that an optical trap can be imprinted by a light field in an ultracold-atom system embedded in an optical cavity, and driven by three different coherent fields. Of the three fields coexisting in the optical cavity there is an intense control field that induces a giant Kerr nonlinearity via electromagnetically-induced transparency, and another field that creates a periodic optical grating of strength proportional to the square of the associated Rabi frequency. In this work elliptic-soliton solutions to the nonlinear equation governing the propagation of the probe field are considered, with emphasis on the possible generation of optical soliton trains forming a discrete spectrum with well defined quantum numbers. The problem is treated assuming two distinct types of periodic optical gratings and taking into account the negative and positive signs of detunings (detuning above or below resonance). Results predict that the competition between the self-phase and cross-phase modulation nonlinearities gives rise to a rich family of temporal soliton train modes characterized by distinct quantum numbers.

  17. Ground States of Ultracold Spin-1 Atoms in a Deep Double-Well Optical Superlattice in a Weak Magnetic Field

    International Nuclear Information System (INIS)

    Zheng Gong-Ping; Qin Shuai-Feng; Wang Shou-Yang; Jian Wen-Tian

    2013-01-01

    The ground states of the ultracold spin-1 atoms trapped in a deep one-dimensional double-well optical superlattice in a weak magnetic field are obtained. It is shown that the ground-state diagrams of the reduced double-well model are remarkably different for the antiferromagnetic and ferromagnetic condensates. The transition between the singlet state and nematic state is observed for the antiferromagnetic interaction atoms, which can be realized by modulating the tunneling parameter or the quadratic Zeeman energy. An experiment to distinguish the different spin states is suggested. (general)

  18. Formation of Ultracold Molecules

    Energy Technology Data Exchange (ETDEWEB)

    Cote, Robin [Univ. of Connecticut, Storrs, CT (United States)

    2016-01-28

    Advances in our ability to slow down and cool atoms and molecules to ultracold temperatures have paved the way to a revolution in basic research on molecules. Ultracold molecules are sensitive of very weak interactions, even when separated by large distances, which allow studies of the effect of those interactions on the behavior of molecules. In this program, we have explored ways to form ultracold molecules starting from pairs of atoms that have already reached the ultracold regime. We devised methods that enhance the efficiency of ultracold molecule production, for example by tuning external magnetic fields and using appropriate laser excitations. We also investigates the properties of those ultracold molecules, especially their de-excitation into stable molecules. We studied the possibility of creating new classes of ultra-long range molecules, named macrodimers, thousand times more extended than regular molecules. Again, such objects are possible because ultra low temperatures prevent their breakup by collision. Finally, we carried out calculations on how chemical reactions are affected and modified at ultracold temperatures. Normally, reactions become less effective as the temperature decreases, but at ultracold temperatures, they can become very effective. We studied this counter-intuitive behavior for benchmark chemical reactions involving molecular hydrogen.

  19. Competition between Final-State and Pairing-Gap Effects in the Radio-Frequency Spectra of Ultracold Fermi Atoms

    International Nuclear Information System (INIS)

    Perali, A.; Pieri, P.; Strinati, G. C.

    2008-01-01

    The radio-frequency spectra of ultracold Fermi atoms are calculated by including final-state interactions affecting the excited level of the transition and compared with the experimental data. A competition is revealed between pairing-gap effects which tend to push the oscillator strength toward high frequencies away from threshold and final-state effects which tend instead to pull the oscillator strength toward threshold. As a result of this competition, the position of the peak of the spectra cannot be simply related to the value of the pairing gap, whose extraction thus requires support from theoretical calculations

  20. The Pauli potential in relation to the differential virial theorem with application to experiments on ultracold atomic gases of fermions

    International Nuclear Information System (INIS)

    March, N.H.

    2008-08-01

    In early work by the writer introducing the Pauli potential VP (r) into density functional theory, the relation of VP (r) to the, as yet unknown, single-particle kinetic energy density functional was emphasized. Here, because of ongoing experiments on ultracold atomic gases of fermions, an explicit expression for the first derivative of VP (r) for an arbitrary number of closed shells generated by harmonic confinement is derived in terms of the spherically symmetric particle density n(r) and the confining potential. (author)

  1. An ultracold, optically trapped mixture of 87Rb and metastable 4He atoms

    NARCIS (Netherlands)

    Flores, A.S.; Mishra, H.P.; Vassen, Wim; Knoop, S.

    2017-01-01

    We report on the realization of an ultracold (<25 μK) mixture of rubidium (87Rb) and metastable triplet helium (4He) in an optical dipole trap. Our scheme involves laser cooling in a dual-species magneto-optical trap, simultaneous MW- and RF-induced forced evaporative cooling in a quadrupole

  2. Pump-probe study of the formation of rubidium molecules by ultrafast photoassociation of ultracold atoms

    Science.gov (United States)

    McCabe, David J.; England, Duncan G.; Martay, Hugo E. L.; Friedman, Melissa E.; Petrovic, Jovana; Dimova, Emiliya; Chatel, Béatrice; Walmsley, Ian A.

    2009-09-01

    An experimental pump-probe study of the photoassociative creation of translationally ultracold rubidium molecules is presented together with numerical simulations of the process. The formation of loosely bound excited-state dimers is observed as a first step toward a fully coherent pump-dump approach to the stabilization of Rb2 into its lowest ground vibrational states. The population that contributes to the pump-probe process is characterized and found to be distinct from a background population of preassociated molecules.

  3. A hydrogen leak-tight, transparent cryogenic sample container for ultracold-neutron transmission measurements

    Science.gov (United States)

    Döge, Stefan; Hingerl, Jürgen

    2018-03-01

    The improvement of the number of extractable ultracold neutrons (UCNs) from converters based on solid deuterium (sD2) crystals requires a good understanding of the UCN transport and how the crystal's morphology influences its transparency to the UCNs. Measurements of the UCN transmission through cryogenic liquids and solids of interest, such as hydrogen (H2) and deuterium (D2), require sample containers with thin, highly polished and optically transparent windows and a well defined sample thickness. One of the most difficult sealing problems is that of light gases like hydrogen and helium at low temperatures against high vacuum. Here we report on the design of a sample container with two 1 mm thin amorphous silica windows cold-welded to aluminum clamps using indium wire gaskets, in order to form a simple, reusable, and hydrogen-tight cryogenic seal. The container meets the above-mentioned requirements and withstands up to 2 bar hydrogen gas pressure against isolation vacuum in the range of 10-5 to 10-7 mbar at temperatures down to 4.5 K. Additionally, photographs of the crystallization process are shown and discussed.

  4. A hydrogen leak-tight, transparent cryogenic sample container for ultracold-neutron transmission measurements.

    Science.gov (United States)

    Döge, Stefan; Hingerl, Jürgen

    2018-03-01

    The improvement of the number of extractable ultracold neutrons (UCNs) from converters based on solid deuterium (sD 2 ) crystals requires a good understanding of the UCN transport and how the crystal's morphology influences its transparency to the UCNs. Measurements of the UCN transmission through cryogenic liquids and solids of interest, such as hydrogen (H 2 ) and deuterium (D 2 ), require sample containers with thin, highly polished and optically transparent windows and a well defined sample thickness. One of the most difficult sealing problems is that of light gases like hydrogen and helium at low temperatures against high vacuum. Here we report on the design of a sample container with two 1 mm thin amorphous silica windows cold-welded to aluminum clamps using indium wire gaskets, in order to form a simple, reusable, and hydrogen-tight cryogenic seal. The container meets the above-mentioned requirements and withstands up to 2 bar hydrogen gas pressure against isolation vacuum in the range of 10 -5 to 10 -7 mbar at temperatures down to 4.5 K. Additionally, photographs of the crystallization process are shown and discussed.

  5. Sample Preprocessing For Atomic Spectrometry

    International Nuclear Information System (INIS)

    Kim, Sun Tae

    2004-08-01

    This book gives descriptions of atomic spectrometry, which deals with atomic absorption spectrometry such as Maxwell-Boltzmann equation and Beer-Lambert law, atomic absorption spectrometry for solvent extraction, HGAAS, ETASS, and CVAAS and inductively coupled plasma emission spectrometer, such as basic principle, generative principle of plasma and device and equipment, and interferences, and inductively coupled plasma mass spectrometry like device, pros and cons of ICP/MS, sample analysis, reagent, water, acid, flux, materials of experiments, sample and sampling and disassembling of sample and pollution and loss in open system and closed system.

  6. Ultracold Atoms in a Square Lattice with Spin-Orbit Coupling: Charge Order, Superfluidity, and Topological Signatures

    Science.gov (United States)

    Rosenberg, Peter; Shi, Hao; Zhang, Shiwei

    2017-12-01

    We present an ab initio, numerically exact study of attractive fermions in square lattices with Rashba spin-orbit coupling. The ground state of this system is a supersolid, with coexisting charge and superfluid order. The superfluid is composed of both singlet and triplet pairs induced by spin-orbit coupling. We perform large-scale calculations using the auxiliary-field quantum Monte Carlo method to provide the first full, quantitative description of the charge, spin, and pairing properties of the system. In addition to characterizing the exotic physics, our results will serve as essential high-accuracy benchmarks for the intense theoretical and especially experimental efforts in ultracold atoms to realize and understand an expanding variety of quantum Hall and topological superconductor systems.

  7. Limit Cycles and Chaos via Quasi-periodicity in Two Coupled Ensembles of Ultra-cold Atoms.

    Science.gov (United States)

    Patra, Aniket; Yuzbashyan, Emil; Altshuler, Boris

    We study the dynamics of two mesoscopic ensembles of ultra-cold two level atoms, which are collectively coupled to an optical cavity and are being pumped incoherently to the excited state. Whereas the time independent steady states are well understood, little is known about the time dependent ones. We explore and categorize various time dependent steady states, e.g. limit cycles and chaotic behavior. We draw a non-equilibrium phase diagram indicating different steady-state behaviors in different parts of the parameter space. We discuss the synchronization of the two ensembles in the time dependent steady states. We also show the onset of chaos via quasi-periodicity. The rich time dependent steady-state behavior, especially the existence of chaos, opens up possibilities for several engineering applications. Supported in part by the University and Louis Bevier Graduate Fellowship.

  8. Ultracold neutrons

    International Nuclear Information System (INIS)

    Steenstrup, S.

    Briefly surveys recent developments in research work with ultracold neutrons (neutrons of very low velocity, up to 10 m/s at up to 10 -7 eV and 10 -3 K). Slow neutrons can be detected in an ionisation chamber filled with B 10 F 3 . Very slow neutrons can be used for investigations into the dipole moment of neutrons. Neutrons of large wave length have properties similar to those of light. The limit angle for total reflection is governed by the wave length and by the material. Total reflection can be used to filter ultracold neutrons out of the moderator material of a reactor. Total reflection can also be used to store ultracold neutrons but certain problems with storage have not yet been clarified. Slow neutrons can be made to lose speed in a neutron turbine, and come out as ultracold neutrons. A beam of ultracold neutrons could be used in a neutron microscope. (J.S.)

  9. Magnetic transport apparatus for the production of ultracold atomic gases in the vicinity of a dielectric surface

    International Nuclear Information System (INIS)

    Haendel, S.; Marchant, A. L.; Wiles, T. P.; Hopkins, S. A.; Cornish, S. L.

    2012-01-01

    We present an apparatus designed for studies of atom-surface interactions using quantum degenerate gases of 85 Rb and 87 Rb in the vicinity of a room temperature dielectric surface. The surface to be investigated is a super-polished face of a glass Dove prism mounted in a glass cell under ultra-high vacuum. To maintain excellent optical access to the region surrounding the surface, magnetic transport is used to deliver ultracold atoms from a separate vacuum chamber housing the magneto-optical trap (MOT). We present a detailed description of the vacuum apparatus highlighting the novel design features; a low profile MOT chamber and the inclusion of an obstacle in the transport path. We report the characterization and optimization of the magnetic transport around the obstacle, achieving transport efficiencies of 70% with negligible heating. Finally, we demonstrate the loading of a hybrid optical-magnetic trap with 87 Rb and the creation of Bose-Einstein condensates via forced evaporative cooling close to the dielectric surface.

  10. Numerical methods for atomic quantum gases with applications to Bose-Einstein condensates and to ultracold fermions

    International Nuclear Information System (INIS)

    Minguzzi, A.; Succi, S.; Toschi, F.; Tosi, M.P.; Vignolo, P.

    2004-01-01

    The achievement of Bose-Einstein condensation in ultra-cold vapours of alkali atoms has given enormous impulse to the study of dilute atomic gases in condensed quantum states inside magnetic traps and optical lattices. High-purity and easy optical access make them ideal candidates to investigate fundamental issues on interacting quantum systems. This review presents some theoretical issues which have been addressed in this area and the numerical techniques which have been developed and used to describe them, from mean-field models to classical and quantum simulations for equilibrium and dynamical properties. After an introductory overview on dilute quantum gases, both in the homogeneus state and under harmonic or periodic confinement, the article is organized in three main sections. The first concerns Bose-condensed gases at zero temperature, with main regard to the properties of the ground state in different confinements and to collective excitations and transport in the condensate. Bose-Einstein-condensed gases at finite temperature are addressed in the next section, the main emphasis being on equilibrium properties and phase transitions and on dynamical and transport properties associated with the presence of the thermal cloud. Finally, the last section is focused on theoretical and computational issues that have emerged from the efforts to drive gases of fermionic atoms and boson-fermion mixtures deep into the quantum degeneracy regime, with the aim of realizing novel superfluids from fermion pairing. The attention given in this article to methods beyond standard mean-field approaches should make it a useful reference point for future advances in these areas

  11. Production and manipulation of wave packets from ultracold atoms in an optical lattice

    DEFF Research Database (Denmark)

    Pedersen, Poul Lindholm; Gajdacz, Miroslav; Winter, Nils

    2013-01-01

    of the system. The modulation technique also allows for a controllable transfer (deexcitation) of atoms from such wave packets to a state bound by the lattice. Thus, it acts as a beam splitter for matter waves that can selectively address different bands, enabling the preparation of atoms in localized states...

  12. Forward and backward scattering experiments in ultra-cold Rubidium atoms

    DEFF Research Database (Denmark)

    Kampel, Nir Shlomo

    project, we have studied coherent forward scattering in the form of a memory experiment. In such an experiment we convert the input light pulse to an atomic excitation, and at a later time convert back the atomic excitation into the retrieved light pulse. In the first project, we investigate the source...

  13. Bloch oscillations of ultracold atoms and measurement of the fine structure constant

    International Nuclear Information System (INIS)

    Clade, P.

    2005-10-01

    From a measurement of the recoil velocity of an atom absorbing a photon, it is possible to deduce a determination of the ratio h/m between the Planck constant and the mass of the atoms and then to deduce a value of the fine structure constant alpha. To do this measurement, we use the technique of Bloch oscillations, which allows us to transfer a large number of recoils to atoms. A velocity sensor, based on velocity selective Raman transition, enables us to measure the momentum transferred to the atoms. A measurement with a statistical uncertainty of 4.4 10 -9 , in conjunction with a careful study of systematic effects (5 10 -9 ), has led us to a determination of alpha with an uncertainty of 6.7 10 -9 : α -1 (Rb) = 137.03599878 (91). This uncertainty is similar to the uncertainty of the best determinations of alpha based on atom interferometry. (author)

  14. Exciton induced directed motion of unconstrained atoms in an ultracold gas

    Science.gov (United States)

    Leonhardt, K.; Wüster, S.; Rost, J. M.

    2017-03-01

    We demonstrate that through localised Rydberg excitation in a three-dimensional cold atom cloud atomic motion can be rendered directed and nearly confined to a plane, without spatial constraints for the motion of individual atoms. This enables creation and observation of non-adiabatic electronic Rydberg dynamics in atoms accelerated by dipole-dipole interactions under natural conditions. Using the full l = 0, 1 m=0,+/- 1 angular momentum state space, our simulations show that conical intersection crossings are clearly evident, both in atomic position information and excited state spectra of the Rydberg system. Hence, flexible Rydberg aggregates suggest themselves for probing quantum chemical effects in experiments on length scales much inflated as compared to a standard molecular situation.

  15. Detecting Friedel oscillations in ultracold Fermi gases

    Science.gov (United States)

    Riechers, Keno; Hueck, Klaus; Luick, Niclas; Lompe, Thomas; Moritz, Henning

    2017-09-01

    Investigating Friedel oscillations in ultracold gases would complement the studies performed on solid state samples with scanning-tunneling microscopes. In atomic quantum gases interactions and external potentials can be tuned freely and the inherently slower dynamics allow to access non-equilibrium dynamics following a potential or interaction quench. Here, we examine how Friedel oscillations can be observed in current ultracold gas experiments under realistic conditions. To this aim we numerically calculate the amplitude of the Friedel oscillations which are induced by a potential barrier in a 1D Fermi gas and compare it to the expected atomic and photonic shot noise in a density measurement. We find that to detect Friedel oscillations the signal from several thousand one-dimensional systems has to be averaged. However, as up to 100 parallel one-dimensional systems can be prepared in a single run with present experiments, averaging over about 100 images is sufficient.

  16. Photon-Induced Spin-Orbit Coupling in Ultracold Atoms inside Optical Cavity

    Directory of Open Access Journals (Sweden)

    Lin Dong

    2015-05-01

    Full Text Available We consider an atom inside a ring cavity, where a plane-wave cavity field together with an external coherent laser beam induces a two-photon Raman transition between two hyperfine ground states of the atom. This cavity-assisted Raman transition induces effective coupling between atom’s internal degrees of freedom and its center-of-mass motion. In the meantime, atomic dynamics exerts a back-action to cavity photons. We investigate the properties of this system by adopting a mean-field and a full quantum approach, and show that the interplay between the atomic dynamics and the cavity field gives rise to intriguing nonlinear phenomena.

  17. Fundamental Interactions for Atom Interferometry with Ultracold Quantum Gases in a Microgravity Environment

    Science.gov (United States)

    D'Incao, Jose P.; Willians, Jason R.

    2015-05-01

    Precision atom interferometers (AI) in space are a key element for several applications of interest to NASA. Our proposal for participating in the Cold Atom Laboratory (CAL) onboard the International Space Station is dedicated to mitigating the leading-order systematics expected to corrupt future high-precision AI-based measurements of fundamental physics in microgravity. One important focus of our proposal is to enhance initial state preparation for dual-species AIs. Our proposed filtering scheme uses Feshbach molecular states to create highly correlated mixtures of heteronuclear atomic gases in both their position and momentum distributions. We will detail our filtering scheme along with the main factors that determine its efficiency. We also show that the atomic and molecular heating and loss rates can be mitigated at the unique temperature and density regimes accessible on CAL. This research is supported by the National Aeronautics and Space Administration.

  18. Manipulation of ultracold atoms in dressed adiabatic radio-frequency potentials

    DEFF Research Database (Denmark)

    Lesanovsky, Igor; Hofferberth, S.; Schmiedmayer, Jörg

    2006-01-01

    We explore properties of atoms whose magnetic hyperfine sublevels are coupled by an external magnetic radio frequency (rf) field. We perform a thorough theoretical analysis of this driven system and present a number of systematic approximations which eventually give rise to dressed adiabatic radio...... frequency potentials. The predictions of this analytical investigation are compared to numerically exact results obtained by a wave packet propagation. We outline the versatility and flexibility of this class of potentials and demonstrate their potential use to build atom optical elements such as double...... wells, interferometers, and ringtraps. Moreover, we perform simulations of interference experiments carried out in rf induced double-well potentials. We discuss how the nature of the atom-field coupling mechanism gives rise to a decrease of the interference contrast....

  19. Understanding Molecular-Ion Neutral Atom Collisions for the Production of Ultracold Molecular Ions

    Science.gov (United States)

    2014-02-03

    SECURITY CLASSIFICATION OF: This project was superseded and replaced by another ARO-funded project of the same name, which is still continuing. The goal...cooled atoms," IOTA -COST Workshop on molecular ions, Arosa, Switzerland. 5. E.R. Hudson, "Sympathetic cooling of molecules with laser cooled

  20. Spin-orbit coupling in ultracold Fermi gases of 173Yb atoms

    Science.gov (United States)

    Song, Bo; He, Chengdong; Hajiyev, Elnur; Ren, Zejian; Seo, Bojeong; Cai, Geyue; Amanov, Dovran; Zhang, Shanchao; Jo, Gyu-Boong

    2017-04-01

    Synthetic spin-orbit coupling (SOC) in cold atoms opens an intriguing new way to probe nontrivial topological orders beyond natural conditions. Here, we report the realization of the SOC physics both in a bulk system and in an optical lattice. First, we demonstrate two hallmarks induced from SOC in a bulk system, spin dephasing in the Rabi oscillation and asymmetric atomic distribution in the momentum space respectively. Then we describe the observation of non-trivial spin textures and the determination of the topological phase transition in a spin-dependent optical lattice dressed by the periodic Raman field. Furthermore, we discuss the quench dynamics between topological and trivial states by suddenly changing the band topology. Our work paves a new way to study non-equilibrium topological states in a controlled manner. Funded by Croucher Foundation and Research Grants Council (RGC) of Hong Kong (Project ECS26300014, GRF16300215, GRF16311516, and Croucher Innovation Grants).

  1. Intertwined and vestigial order with ultracold atoms in multiple cavity modes

    Science.gov (United States)

    Gopalakrishnan, Sarang; Shchadilova, Yulia E.; Demler, Eugene

    2017-12-01

    Atoms in transversely pumped optical cavities "self-organize" by forming a density wave and emitting superradiantly into the cavity mode(s). For a single-mode cavity, the properties of this self-organization transition are well characterized both theoretically and experimentally. Here, we explore the self-organization of a Bose-Einstein condensate in the presence of two cavity modes—a system that recently was realized experimentally [Léonard et al., Nature (London) 543, 87 (2017), 10.1038/nature21067]. We argue that this system can exhibit a "vestigially ordered" phase in which neither cavity mode exhibits superradiance but the cavity modes are mutually phase locked by the atoms. We argue that this vestigially ordered phase should generically be present in multimode cavity geometries.

  2. On the tunneling time of ultracold atoms through a system of two mazer cavities.

    Science.gov (United States)

    Badshah, Fazal; Ge, Guo-Qin; Irfan, Muhammad; Qamar, Sajid; Qamar, Shahid

    2018-01-30

    We study the resonant tunneling of ultraslow atoms through a system of high quality microwave cavities. We find that the phase tunneling time across the two coupled cavities exhibits more frequent resonances as compared to the single cavity interaction. The increased resonances are instrumental in the display of an alternate sub and superclassical character of the tunneling time along the momentum axis with increasing energies of the incident slow atoms. Here, the intercavity separation appears as an additional controlling parameter of the system that provides an efficient control of the superclassical behavior of the phase tunneling time. Further, we find that the phase time characteristics through two cavity system has the combined features of the tunneling through a double barrier and a double well arrangements.

  3. Understanding Molecular Ion-Neutral Atom Collisions for the Production of Ultracold Molecular Ions

    Science.gov (United States)

    2016-06-06

    2012): 0. doi: 10.1103/PhysRevLett.109.223002 Kuang Chen, Scott T. Sullivan, Wade G. Rellergert, Eric R. Hudson. Measurement of the Coulomb Logarithm...or fellowships for further studies in science, mathematics, engineering or technology fields: Student Metrics This section only applies to graduating...clouds of Ba+ ions and Ca atoms. Due to the strong Coulomb interaction, the Ba+ ions quickly cool the molecular ion translation motion, while the

  4. Ultra-cold molecules in an atomic Bose-Einstein condensate

    Science.gov (United States)

    Wynar, Roahn Helden

    2000-08-01

    This thesis is about photoassociation of Bose-condensed 87Rb. Most importantly we report that state selected 87Rb2 molecules were created at rest in a condensate of 87Rb using two-photon photoassociation. Additionally, we have identified three weakly bound states of the 87Rb2 S+u3 , potential for the |1, -1> + |1, - 1> collisional channel. The binding energies of these states are 529.4 +/- .07, 636.0094 +/- .0012, and 24.24 +/- .01 MHz respectively. We have also carried out a detailed study of the density dependence of the shift and width of the two-photon lineshape. This shift and width is modeled using the theory of Bohn and Julienne [34] and in addition to the precise measurement of binding energy we also report the first measurement of an atom molecule scattering length, aam, which we conclude is -180 +/- 150 a0, and the inelastic collision rate, Kinel dependent coherent coupling between atoms and molecules. This theory yields two coupled equations, one for the evolution of atomic condensate amplitude and one for the evolution of molecular condensate amplitude. The nature of the atomic-molecular condensate evolution is shown to depend on six, model parameters including the coherent coupling, given by cn . The other five parameters can be interpreted as light-shifts and incoherent loss rates. We present a calculation intended to estimate the values of these six parameters for the 87Rb - 87Rb 2 system. Based on the results of this calculation we identify two locations in the 87Rb2 spectrum where coherent transfer of population from atomic condensate to molecular condensate is plausible. Finally, we examine the credibility of the theoretical model used to estimate the six parameters used by the mean field theory. By comparing the measured Stark shifts of two-color resonances with predictions based on our theoretical model we conclude that the model is satisfactory for the v = 37 level of the S+u3 potential. This work also describes the experimental details of

  5. Ultra-cold molecule production

    International Nuclear Information System (INIS)

    Ramirez-Serrano, Jamie; Chandler, David W.; Strecker, Kevin; Rahn, Larry A.

    2005-01-01

    The production of Ultra-cold molecules is a goal of many laboratories through out the world. Here we are pursuing a unique technique that utilizes the kinematics of atomic and molecular collisions to achieve the goal of producing substantial numbers of sub Kelvin molecules confined in a trap. Here a trap is defined as an apparatus that spatially localizes, in a known location in the laboratory, a sample of molecules whose temperature is below one degree absolute Kelvin. Further, the storage time for the molecules must be sufficient to measure and possibly further cool the molecules. We utilize a technique unique to Sandia to form cold molecules from near mass degenerate collisions between atoms and molecules. This report describes the progress we have made using this novel technique and the further progress towards trapping molecules we have cooled

  6. Surface modes of ultra-cold atomic clouds with very large number of vortices

    Energy Technology Data Exchange (ETDEWEB)

    Cazalilla, M A [Donostia International Physics Center, Donostia (Spain); [Abdus Salam International Centre for Theoretical Physics, Trieste (Italy)

    2003-04-01

    We study the surface modes of some of the vortex liquids recently found by means of exact diagonalizations in systems of rapidly rotating bosons. In contrast to the surface modes of Bose condensates, we find that the surface waves have a frequency linear in the excitation angular momentum, h-bar l > 0. Furthermore, in analogy with the edge waves of electronic quantum Hall states, these excitations are chiral, that is, they can be excited only for values of l that increase the total angular momentum of the vortex liquid. However, differently from the quantum Hall phenomena for electrons, we also find other excitations that are approximately degenerate in the laboratory frame with the surface modes, and which decrease the total angular momentum by l quanta. The surface modes of the Laughlin, as well as other scalar and vector boson states are analyzed, and their observable properties characterized. We argue that measurement of the response of a vortex liquid to a weak time-dependent potential that imparts angular momentum to the system should provide valuable information to characterize the vortex liquid. In particular, the intensity of the signal of the surface waves in the dynamic structure factor has been studied and found to depend on the type of vortex liquid. We point out that the existence of surface modes has observable consequences on the density profile of the Laughlin state. These features are due to the strongly correlated behavior of atoms in the vortex liquids. We point out that these correlations should be responsible for a remarkable stability of some vortex liquids with respect to three-body losses. (author)

  7. Trapping ultracold gases near cryogenic materials with rapid reconfigurability

    Energy Technology Data Exchange (ETDEWEB)

    Naides, Matthew A.; Turner, Richard W.; Lai, Ruby A.; DiSciacca, Jack M.; Lev, Benjamin L. [Departments of Applied Physics and Physics and Ginzton Laboratory, Stanford University, Stanford, California 94305 (United States)

    2013-12-16

    We demonstrate an atom chip trapping system that allows the placement and high-resolution imaging of ultracold atoms within microns from any ≲100 μm-thin, UHV-compatible material, while also allowing sample exchange with minimal experimental downtime. The sample is not connected to the atom chip, allowing rapid exchange without perturbing the atom chip or laser cooling apparatus. Exchange of the sample and retrapping of atoms has been performed within a week turnaround, limited only by chamber baking. Moreover, the decoupling of sample and atom chip provides the ability to independently tune the sample temperature and its position with respect to the trapped ultracold gas, which itself may remain in the focus of a high-resolution imaging system. As a first demonstration of this system, we have confined a 700-nK cloud of 8 × 10{sup 4} {sup 87}Rb atoms within 100 μm of a gold-mirrored 100-μm-thick silicon substrate. The substrate was cooled to 35 K without use of a heat shield, while the atom chip, 120 μm away, remained at room temperature. Atoms may be imaged and retrapped every 16 s, allowing rapid data collection.

  8. Sympathetic cooling in a rubidium cesium mixture: Production of ultracold cesium atoms; Sympathetisches Kuehlen in einer Rubidium-Caesium-Mischung: Erzeugung ultrakalter Caesiumatome

    Energy Technology Data Exchange (ETDEWEB)

    Haas, M.

    2007-07-01

    This thesis presents experiments for the production of ultracold rubidium cesium mixture in a magnetic trap. The long-termed aim of the experiment is the study of the interaction of few cesium atoms with a Bose-Einstein condensate of rubidium atoms. Especially by controlled variation of the cesium atom number the transition in the description of the interaction by concepts of the one-particle physics to the description by concepts of the many-particle physics shall be studied. The rubidium atoms are trapped in a magneto-optical trap (MOT) and from there reloaded into a magnetic trap. In this the rubidium atoms are stored in the state vertical stroke f=2,m{sub f}=2 right angle of the electronic ground state and evaporatively cooled by means of microwave-induced transitions into the state vertical stroke f=1,m{sub f}=1] (microwave cooling). The cesium atoms are also trppaed in a MOT and into the same magnetic trap reloaded, in which they are stored in the state vertical stroke f=4,m{sub f}=4 right angle of the electronic ground state together with rubidium. Because of the different hyperfine splitting only rubidium is evaporatively cooled, while cesium is cooled jointly sympathetically - i.e. by theramal contact via elastic collisions with rubidium atoms. The first two chapters contain a description of interatomic interactions in ultracold gases as well as a short summary of theoretical concepts in the description of Bose-Einstein condensates. The chapters 3 and 4 contain a short presentation of the methods applied in the experiment for the production of ultracold gases as well as the experimental arrangement; especially in the framework of this thesis a new coil system has been designed, which offers in view of future experiments additionally optical access for an optical trap. Additionally the fourth chapter contains an extensive description of the experimental cycle, which is applied in order to store rubidium and cesium atoms together into the magnetic trap. The

  9. Expansion of an ultracold Rydberg plasma

    Science.gov (United States)

    Forest, Gabriel T.; Li, Yin; Ward, Edwin D.; Goodsell, Anne L.; Tate, Duncan A.

    2018-04-01

    We report a systematic experimental and numerical study of the expansion of ultracold Rydberg plasmas. Specifically, we have measured the asymptotic expansion velocities, v0, of ultracold neutral plasmas (UNPs) which evolve from cold, dense samples of Rydberg rubidium atoms using ion time-of-flight spectroscopy. From this, we have obtained values for the effective initial plasma electron temperature, Te ,0=mionv02/kB (where mion is the Rb+ ion mass), as a function of the original Rydberg atom density and binding energy, Eb ,i. We have also simulated numerically the interaction of UNPs with a large reservoir of Rydberg atoms to obtain data to compare with our experimental results. We find that for Rydberg atom densities in the range 107-109 cm-3, for states with principal quantum number n >40 , Te ,0 is insensitive to the initial ionization mechanism which seeds the plasma. In addition, the quantity kBTe ,0 is strongly correlated with the fraction of atoms which ionize, and is in the range 0.6 ×| Eb ,i|≲ kBTe ,0≲2.5 ×|Eb ,i| . On the other hand, plasmas from Rydberg samples with n ≲40 evolve with no significant additional ionization of the remaining atoms once a threshold number of ions has been established. The dominant interaction between the plasma electrons and the Rydberg atoms is one in which the atoms are deexcited, a heating process for electrons that competes with adiabatic cooling to establish an equilibrium where Te ,0 is determined by their Coulomb coupling parameter, Γe˜0.01 .

  10. Formation of ultracold NaRb Feshbach molecules

    International Nuclear Information System (INIS)

    Wang, Fudong; He, Xiaodong; Li, Xiaoke; Zhu, Bing; Chen, Jun; Wang, Dajun

    2015-01-01

    We report the creation of ultracold bosonic 23 Na 87 Rb Feshbach molecules via magneto-association. By ramping the magnetic field across an interspecies Feshbach resonance (FR), at least 4000 molecules can be produced out of the near degenerate ultracold mixture. Fast loss due to inelastic atom–molecule collisions is observed, which limits the pure molecule number, after residual atoms removal, to 1700. The pure molecule sample can live for 21.8(8) ms in the optical trap, long enough for future molecular spectroscopy studies toward coherently transferring to the singlet ro-vibrational ground state, where these molecules are stable against chemical reaction and have a permanent electric dipole moment of 3.3 Debye. We have also measured the Feshbach molecule’s binding energy near the FR by the oscillating magnetic field method and found these molecules have a large closed-channel fraction. (paper)

  11. Interatomic interaction effects on second-order momentum correlations and Hong-Ou-Mandel interference of double-well-trapped ultracold fermionic atoms

    Science.gov (United States)

    Brandt, Benedikt B.; Yannouleas, Constantine; Landman, Uzi

    2018-05-01

    Identification and understanding of the evolution of interference patterns in two-particle momentum correlations as a function of the strength of interatomic interactions are important in explorations of the nature of quantum states of trapped particles. Together with the analysis of two-particle spatial correlations, they offer the prospect of uncovering fundamental symmetries and structure of correlated many-body states, as well as opening vistas into potential control and utilization of correlated quantum states as quantum-information resources. With the use of the second-order density matrix constructed via exact diagonalization of the microscopic Hamiltonian, and an analytic Hubbard-type model, we explore here the systematic evolution of characteristic interference patterns in the two-body momentum and spatial correlation maps of two entangled ultracold fermionic atoms in a double well, for the entire attractive- and repulsive-interaction range. We uncover quantum-statistics-governed bunching and antibunching, as well as interaction-dependent interference patterns, in the ground and excited states, and interpret our results in light of the Hong-Ou-Mandel interference physics, widely exploited in photon indistinguishability testing and quantum-information science.

  12. Universal Three-Body Physics in Ultracold KRb Mixtures

    DEFF Research Database (Denmark)

    Wacker, L. J.; Jørgensen, N. B.; Birkmose, Danny Matthiesen

    2016-01-01

    Ultracold atomic gases have recently become a driving force in few-body physics due to the observation of the Efimov effect. While initially observed in equal mass systems, one expects even richer few-body physics in the mass-imbalanced case. In previous experiments with ultracold mixtures of pot...

  13. Continuous-measurement-enhanced self-trapping of degenerate ultracold atoms in a double well: Nonlinear quantum Zeno effect

    International Nuclear Information System (INIS)

    Li Weidong; Liu Jie

    2006-01-01

    In the present paper we investigate the influence of measurements on the quantum dynamics of degenerate Bose atoms gases in a symmetric double well. We show that continuous measurements enhance asymmetry on the density distribution of the atoms and broaden the parameter regime for self-trapping. We term this phenomenon as nonlinear quantum Zeno effect in analog to the celebrated Zeno effect in a linear quantum system. Under discontinuous measurements, the self-trapping due to the atomic interaction in the degenerate bosons is shown to be destroyed completely. Underlying physics is revealed and possible experimental realization is discussed

  14. Quantum control of ultra-cold atoms: uncovering a novel connection between two paradigms of quantum nonlinear dynamics

    DEFF Research Database (Denmark)

    Wang, Jiao; Mouritzen, Anders Sørrig; Gong, Jiangbin

    2009-01-01

    Controlling the translational motion of cold atoms using optical lattice potentials is of both theoretical and experimental interest. By designing two on-resonance time sequences of kicking optical lattice potentials, a novel connection between two paradigms of nonlinear mapping systems, i.e. the...... sequences of control fields. Extensions of this study are also discussed. The results are intended to open up a new generation of cold-atom experiments of quantum nonlinear dynamics.......Controlling the translational motion of cold atoms using optical lattice potentials is of both theoretical and experimental interest. By designing two on-resonance time sequences of kicking optical lattice potentials, a novel connection between two paradigms of nonlinear mapping systems, i...

  15. Magnetic-Field Dependence of Raman Coupling Strength in Ultracold "4"0K Atomic Fermi Gas

    International Nuclear Information System (INIS)

    Huang Liang-Hui; Wang Peng-Jun; Meng Zeng-Ming; Peng Peng; Chen Liang-Chao; Li Dong-Hao; Zhang Jing

    2016-01-01

    We experimentally demonstrate the relation of Raman coupling strength with the external bias magnetic field in degenerate Fermi gas of "4"0K atoms. Two Raman lasers couple two Zeeman energy levels, whose energy splitting depends on the external bias magnetic field. The Raman coupling strength is determined by measuring the Rabi oscillation frequency. The characteristics of the Rabi oscillation is to be damped after several periods due to Fermi atoms in different momentum states oscillating with different Rabi frequencies. The experimental results show that the Raman coupling strength will decrease as the external bias magnetic field increases, which is in good agreement with the theoretical prediction. (paper)

  16. Inhomogeneous spectral moment sum rules for the retarded Green function and self-energy of strongly correlated electrons or ultracold fermionic atoms in optical lattices

    International Nuclear Information System (INIS)

    Freericks, J. K.; Turkowski, V.

    2009-01-01

    Spectral moment sum rules are presented for the inhomogeneous many-body problem described by the fermionic Falicov-Kimball or Hubbard models. These local sum rules allow for arbitrary hoppings, site energies, and interactions. They can be employed to quantify the accuracy of numerical solutions to the inhomogeneous many-body problem such as strongly correlated multilayered devices, ultracold atoms in an optical lattice with a trap potential, strongly correlated systems that are disordered, or systems with nontrivial spatial ordering such as a charge-density wave or a spin-density wave. We also show how the spectral moment sum rules determine the asymptotic behavior of the Green function, self-energy, and dynamical mean field when applied to the dynamical mean-field theory solution of the many-body problem. In particular, we illustrate in detail how one can dramatically reduce the number of Matsubara frequencies needed to solve the Falicov-Kimball model while still retaining high precision, and we sketch how one can incorporate these results into Hirsch-Fye quantum Monte Carlo solvers for the Hubbard (or more complicated) models. Since the solution of inhomogeneous problems is significantly more time consuming than periodic systems, efficient use of these sum rules can provide a dramatic speed up in the computational time required to solve the many-body problem. We also discuss how these sum rules behave in nonequilibrium situations as well, where the Hamiltonian has explicit time dependence due to a driving field or due to the time-dependent change in a parameter such as the interaction strength or the origin of the trap potential.

  17. Time-dependent analysis of tunneling effect in the formation of ultracold molecules via photo-association of laser-cooled atoms

    International Nuclear Information System (INIS)

    Vatasescu, M.; Masnou-Seeuws, F.

    2002-01-01

    The paper contains a time-dependent investigation of the tunneling effect observed in the photo-association spectrum of Cs 2 and attributed to the 0 g - (6s,6p 3/2 ) double well. When by photo-association of two cold cesium atoms a vibrational level of the outer well is populated, tunneling is an efficient mechanism for transferring the population to the inner well (R 0 ), where spontaneous emission may lead to formation of cold molecules in low vibrational levels of the a 3 Σ u + (6s,6s) electronic state. This tunneling effect is analyzed by wave packets propagation, first considering the double well potential alone, and following a packet made by a superposition of states initially located at large distances. Characteristic times for the vibration dynamics, corresponding to a beating phenomenon between the two wells, to partial 'revival' at large distances, and to maxima in the population localized in the inner well are reported and discussed. Second, we simulate the two-channels a 3 Σ u + (6s,6s) → 0 g - (6s,6p 3/2 ) photo-association at detuning around 2.9 cm -1 : the inner well can be populated either by the excitation of a vibrational level of the external well (resonant excitation), or by tuning the photo-association laser at the energy of the inner well level which displays tunneling (''off-resonance excitation''). In the first case the photo-association is efficient, while the tunneling probability is small; in the second, the tunneling probability is large, so that despite the poor efficiency of the photo-association process, more population can be transferred to the inner well. This second choice is shown to be very sensitive to the laser intensity, which could be used to control the population of the inner well and hence the formation of ultracold molecules in low vibrational levels. (authors)

  18. Ultracold lithium-6 atoms in the BEC-BCS crossover: experiments and the construction of a new apparatus

    International Nuclear Information System (INIS)

    Teichmann, M.

    2007-09-01

    We use a fermionic gas of Lithium-6 as a model system to study superfluidity. The limiting cases of superfluidity are Bose-Einstein condensation (BEC) and superconductivity, described by the theory by Bardeen, Cooper and Schrieffer (BCS). In Lithium-6 gases, we can explore the whole range between the two cases, known as the BEC-BCS crossover, using a Feshbach resonance. We study the change of the momentum distribution of the gas in this cross-over and compare to theoretical models. We also investigate the hydrodynamic expansion, characteristic for a superfluid gas. We observe a sudden change of the ellipticity of the gas close to the transition to the superfluid phase. Moreover, we localized heteronuclear Feshbach resonances between 6 Li and 7 Li. We are currently constructing a second generation of the experimental setup. An new laser system, based on high power laser diodes, was developed. Changes in the vacuum chamber, including a complete reconstruction of the Zeeman slower, have increased the atomic flux, allowing us to increase the repetition rate of our experiment. Modifications of the geometry of the magnetic traps lead to a higher number of trapped atoms. (author)

  19. Bloch oscillations of ultracold atoms and measurement of the fine structure constant; Oscillations de Bloch d'atomes ultrafroids et mesure de la constante de structure fine

    Energy Technology Data Exchange (ETDEWEB)

    Clade, P

    2005-10-15

    From a measurement of the recoil velocity of an atom absorbing a photon, it is possible to deduce a determination of the ratio h/m between the Planck constant and the mass of the atoms and then to deduce a value of the fine structure constant alpha. To do this measurement, we use the technique of Bloch oscillations, which allows us to transfer a large number of recoils to atoms. A velocity sensor, based on velocity selective Raman transition, enables us to measure the momentum transferred to the atoms. A measurement with a statistical uncertainty of 4.4 10{sup -9}, in conjunction with a careful study of systematic effects (5 10{sup -9}), has led us to a determination of alpha with an uncertainty of 6.7 10{sup -9}: {alpha}{sup -1}(Rb) = 137.03599878 (91). This uncertainty is similar to the uncertainty of the best determinations of alpha based on atom interferometry. (author)

  20. Ultrafast electron diffraction using an ultracold source

    Directory of Open Access Journals (Sweden)

    M. W. van Mourik

    2014-05-01

    Full Text Available The study of structural dynamics of complex macromolecular crystals using electrons requires bunches of sufficient coherence and charge. We present diffraction patterns from graphite, obtained with bunches from an ultracold electron source, based on femtosecond near-threshold photoionization of a laser-cooled atomic gas. By varying the photoionization wavelength, we change the effective source temperature from 300 K to 10 K, resulting in a concomitant change in the width of the diffraction peaks, which is consistent with independently measured source parameters. This constitutes a direct measurement of the beam coherence of this ultracold source and confirms its suitability for protein crystal diffraction.

  1. Ultracold fermions with repulsive interactions

    Directory of Open Access Journals (Sweden)

    Ketterle W.

    2013-08-01

    Full Text Available An ultracold Fermi gas with repulsive interaction has been studied. For weak interactions, the atomic gas is metastable, and the interactions were characterized by obtaining the isothermal compressibility from atomic density profiles. For stronger interactions (kFa ≈ 1, rapid conversion into Feshbach molecules is observed. When the conversion rate becomes comparable to the Fermi energy divided by η, the atomic gas cannot reach equilibrium without forming pairs. This precludes the predicted transition to a ferromagnetic state (Stoner transition. The absence of spin fluctuations proves that the gas stays paramagnetic. In free space, a Fermi gas with strong short-range repulsion does not exist because of the rapid coupling to molecular states.

  2. Dissociation and decay of ultracold sodium molecules

    International Nuclear Information System (INIS)

    Mukaiyama, T.; Abo-Shaeer, J.R.; Xu, K.; Chin, J.K.; Ketterle, W.

    2004-01-01

    The dissociation of ultracold molecules was studied by ramping an external magnetic field through a Feshbach resonance. The observed dissociation energies directly yielded the strength of the atom-molecule coupling. They showed nonlinear dependence on the ramp speed. This was explained by a Wigner threshold law which predicts that the decay rate of the molecules above threshold increases with the density of states. In addition, inelastic molecule-molecule and molecule-atom collisions were characterized

  3. Single-atom detection on a chip: from realization to application

    Energy Technology Data Exchange (ETDEWEB)

    Stibor, A; Bender, H; Kuehnhold, S; Fortagh, J; Zimmermann, C; Guenther, A, E-mail: aguenth@pit.physik.uni-tuebingen.d [CQ Center for Collective Quantum Phenomena and their Applications, Eberhard-Karls-Universitaet Tuebingen, Auf der Morgenstelle 14, D-72076 Tuebingen (Germany)

    2010-06-15

    In this paper, we describe the preparation and detection of ultracold atoms on a microchip with single-atom sensitivity. The detection scheme is based on multi-photon ionization of atoms and the subsequent guiding of the generated ions by ion optics to a channel electron multiplier. We resolve single atoms with a detection efficiency above 60%. The detector is suitable for real-time observations of static and dynamic processes in ultracold quantum gases. Although the ionization is destructive, sampling a small subset of the atomic distribution is sufficient for the determination of the desired information. We take full high-resolution spectra of ultracold atoms by ionizing only 5% of the atoms. Using an additional microwave near 6.8 GHz, the detection scheme becomes energy, position and state selective. This can be used for in situ determination of the energy distribution and temperature of atom clouds inside the trap and applied for future correlation measurements.

  4. Multielement methods of atomic fluorescence analysis of enviromental samples

    International Nuclear Information System (INIS)

    Rigin, V.I.

    1985-01-01

    A multielement method of atomic fluorescence analysis of environmental samples based on sample decomposition by autoclave fluorination and gas-phase atomization of volatile compounds in inductive araon plasma using a nondispersive polychromator is suggested. Detection limits of some elements (Be, Sr, Cd, V, Mo, Te, Ru etc.) for different sample forms introduced in to an analyzer are given

  5. Functional renormalization and ultracold quantum gases

    International Nuclear Information System (INIS)

    Floerchinger, Stefan

    2010-01-01

    Modern techniques from quantum field theory are applied in this work to the description of ultracold quantum gases. This leads to a unified description of many phenomena including superfluidity for bosons and fermions, classical and quantum phase transitions, different dimensions, thermodynamic properties and few-body phenomena as bound state formation or the Efimov effect. The non-perturbative treatment with renormalization group flow equations can account for all known limiting cases by solving one single equation. It improves previous results quantitatively and brings qualitatively new insights. As an example, new quantum phase transitions are found for fermions with three spin states. Ultracold atomic gases can be seen as an interesting model for features of high energy physics and for condensed matter theory. The research reported in this thesis helps to solve the difficult complexity problem in modern theoretical physics. (orig.)

  6. Detecting high-density ultracold molecules using atom–molecule collision

    International Nuclear Information System (INIS)

    Chen, Jun-Ren; Kao, Cheng-Yang; Chen, Hung-Bin; Liu, Yi-Wei

    2013-01-01

    Utilizing single-photon photoassociation, we have achieved ultracold rubidium molecules with a high number density that provides a new efficient approach toward molecular quantum degeneracy. A new detection mechanism for ultracold molecules utilizing inelastic atom–molecule collision is demonstrated. The resonant coupling effect on the formation of the X 1 Σ + g ground state 85 Rb 2 allows for a sufficient number of more deeply bound ultracold molecules, which induced an additional trap loss and heating of the co-existing atoms owing to the inelastic atom–molecule collision. Therefore, after the photoassociation process, the ultracold molecules can be investigated using the absorption image of the ultracold rubidium atoms mixed with the molecules in a crossed optical dipole trap. The existence of the ultracold molecules was then verified, and the amount of accumulated molecules was measured. This method detects the final produced ultracold molecules, and hence is distinct from the conventional trap loss experiment, which is used to study the association resonance. It is composed of measurements of the time evolution of an atomic cloud and a decay model, by which the number density of the ultracold 85 Rb 2 molecules in the optical trap was estimated to be >5.2 × 10 11 cm −3 . (paper)

  7. The formation and interactions of cold and ultracold molecules: new challenges for interdisciplinary physics

    Energy Technology Data Exchange (ETDEWEB)

    Dulieu, O [Laboratoire Aime Cotton, CNRS, Bat. 505, Univ Paris-Sud 11, F-91405 Orsay Cedex (France); Gabbanini, C [Istituto per i processi chimico-fisici del C.N.R., Via Moruzzi 1, 56124 Pisa (Italy)], E-mail: olivier.dulieu@lac.u-psud.fr, E-mail: carlo@ipcf.cnr.it

    2009-08-15

    Progress on research in the field of molecules at cold and ultracold temperatures is reported in this review. It covers extensively the experimental methods to produce, detect and characterize cold and ultracold molecules including association of ultracold atoms, deceleration by external fields and kinematic cooling. Confinement of molecules in different kinds of traps is also discussed. The basic theoretical issues related to the knowledge of the molecular structure, the atom-molecule and molecule-molecule mutual interactions, and to their possible manipulation and control with external fields, are reviewed. A short discussion on the broad area of applications completes the review.

  8. Dynamics of entanglement between two atomic samples with spontaneous scattering

    International Nuclear Information System (INIS)

    Di Lisi, Antonio; De Siena, Silvio; Illuminati, Fabrizio

    2004-01-01

    We investigate the effects of spontaneous scattering on the evolution of entanglement of two atomic samples, probed by phase-shift measurements on optical beams interacting with both samples. We develop a formalism of conditional quantum evolutions and present a wave function analysis implemented in numerical simulations of the state vector dynamics. This method allows us to track the evolution of entanglement and to compare it with the predictions obtained when spontaneous scattering is neglected. We provide numerical evidence that the interferometric scheme to entangle atomic samples is only marginally affected by the presence of spontaneous scattering and should thus be robust even in more realistic situations

  9. Ultracold Dipolar Gases in Optical Lattices

    OpenAIRE

    Trefzger, C.; Menotti, C.; Capogrosso-Sansone, B.; Lewenstein, M.

    2011-01-01

    This tutorial is a theoretical work, in which we study the physics of ultra-cold dipolar bosonic gases in optical lattices. Such gases consist of bosonic atoms or molecules that interact via dipolar forces, and that are cooled below the quantum degeneracy temperature, typically in the nK range. When such a degenerate quantum gas is loaded into an optical lattice produced by standing waves of laser light, new kinds of physical phenomena occur. These systems realize then extended Hubbard-type m...

  10. New approaches to nanoparticle sample fabrication for atom probe tomography

    International Nuclear Information System (INIS)

    Felfer, P.; Li, T.; Eder, K.; Galinski, H.; Magyar, A.P.; Bell, D.C.; Smith, G.D.W.; Kruse, N.; Ringer, S.P.; Cairney, J.M.

    2015-01-01

    Due to their unique properties, nano-sized materials such as nanoparticles and nanowires are receiving considerable attention. However, little data is available about their chemical makeup at the atomic scale, especially in three dimensions (3D). Atom probe tomography is able to answer many important questions about these materials if the challenge of producing a suitable sample can be overcome. In order to achieve this, the nanomaterial needs to be positioned within the end of a tip and fixed there so the sample possesses sufficient structural integrity for analysis. Here we provide a detailed description of various techniques that have been used to position nanoparticles on substrates for atom probe analysis. In some of the approaches, this is combined with deposition techniques to incorporate the particles into a solid matrix, and focused ion beam processing is then used to fabricate atom probe samples from this composite. Using these approaches, data has been achieved from 10–20 nm core–shell nanoparticles that were extracted directly from suspension (i.e. with no chemical modification) with a resolution of better than ±1 nm. - Highlights: • Samples for APT of nanoparticles were fabricated from particle powders and dispersions. • Electrophoresis was suitable for producing samples from dispersions. • Powder lift-out was successfully producing samples from particle agglomerates. • Dispersion application/coating delivered the highest quality results.

  11. New approaches to nanoparticle sample fabrication for atom probe tomography

    Energy Technology Data Exchange (ETDEWEB)

    Felfer, P., E-mail: peter.felfer@sydney.edu.au [School for Aerospace, Mechanical and Mechatronic Engineering/Australian Centre for Microscopy and Microanalysis, The University of Sydney, NSW 2006 (Australia); Li, T. [School for Aerospace, Mechanical and Mechatronic Engineering/Australian Centre for Microscopy and Microanalysis, The University of Sydney, NSW 2006 (Australia); Materials Department, The University of Oxford, Oxford (United Kingdom); Eder, K. [School for Aerospace, Mechanical and Mechatronic Engineering/Australian Centre for Microscopy and Microanalysis, The University of Sydney, NSW 2006 (Australia); Galinski, H. [School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138 (United States); Magyar, A.P.; Bell, D.C. [School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138 (United States); Center for Nanoscale Systems, Harvard University, Cambridge, MA 02138 (United States); Smith, G.D.W. [Materials Department, The University of Oxford, Oxford (United Kingdom); Kruse, N. [Chemical Physics of Materials (Catalysis-Tribology), Université Libre de Bruxelles, Campus Plaine, CP 243, 1050 Brussels (Belgium); Ringer, S.P.; Cairney, J.M. [School for Aerospace, Mechanical and Mechatronic Engineering/Australian Centre for Microscopy and Microanalysis, The University of Sydney, NSW 2006 (Australia)

    2015-12-15

    Due to their unique properties, nano-sized materials such as nanoparticles and nanowires are receiving considerable attention. However, little data is available about their chemical makeup at the atomic scale, especially in three dimensions (3D). Atom probe tomography is able to answer many important questions about these materials if the challenge of producing a suitable sample can be overcome. In order to achieve this, the nanomaterial needs to be positioned within the end of a tip and fixed there so the sample possesses sufficient structural integrity for analysis. Here we provide a detailed description of various techniques that have been used to position nanoparticles on substrates for atom probe analysis. In some of the approaches, this is combined with deposition techniques to incorporate the particles into a solid matrix, and focused ion beam processing is then used to fabricate atom probe samples from this composite. Using these approaches, data has been achieved from 10–20 nm core–shell nanoparticles that were extracted directly from suspension (i.e. with no chemical modification) with a resolution of better than ±1 nm. - Highlights: • Samples for APT of nanoparticles were fabricated from particle powders and dispersions. • Electrophoresis was suitable for producing samples from dispersions. • Powder lift-out was successfully producing samples from particle agglomerates. • Dispersion application/coating delivered the highest quality results.

  12. Use of ultracold neutrons for condensed-matter studies

    Energy Technology Data Exchange (ETDEWEB)

    Michaudon, A.

    1997-05-01

    Ultracold neutrons have such low velocities that they are reflected by most materials at all incident angles and can be stored in material bottles for long periods of time during which their intrinsic properties can be studied in great detail. These features have been mainly used for fundamental-physics studies including the detection of a possible neutron electric dipole moment and the precise determination of neutron-decay properties. Ultracold neutrons can also play a role in condensed-matter studies with the help of high-resolution spectrometers that use gravity as a strongly dispersive medium for low-velocity neutrons. Such studies have so far been limited by the low intensity of existing ultracold-neutron sources but could be reconsidered with more intense sources, which are now envisaged. This report provides a broad survey of the properties of ultracold neutrons (including their reflectivity by different types of samples), of ultracold-neutron spectrometers that are compared with other high-resolution instruments, of results obtained in the field of condensed matter with these instruments, and of neutron microscopes. All these subjects are illustrated by numerous examples.

  13. Use of ultracold neutrons for condensed-matter studies

    International Nuclear Information System (INIS)

    Michaudon, A.

    1997-05-01

    Ultracold neutrons have such low velocities that they are reflected by most materials at all incident angles and can be stored in material bottles for long periods of time during which their intrinsic properties can be studied in great detail. These features have been mainly used for fundamental-physics studies including the detection of a possible neutron electric dipole moment and the precise determination of neutron-decay properties. Ultracold neutrons can also play a role in condensed-matter studies with the help of high-resolution spectrometers that use gravity as a strongly dispersive medium for low-velocity neutrons. Such studies have so far been limited by the low intensity of existing ultracold-neutron sources but could be reconsidered with more intense sources, which are now envisaged. This report provides a broad survey of the properties of ultracold neutrons (including their reflectivity by different types of samples), of ultracold-neutron spectrometers that are compared with other high-resolution instruments, of results obtained in the field of condensed matter with these instruments, and of neutron microscopes. All these subjects are illustrated by numerous examples

  14. EDITORIAL: Focus on Cold and Ultracold Molecules FOCUS ON COLD AND ULTRACOLD MOLECULES

    Science.gov (United States)

    Carr, Lincoln D.; Ye, Jun

    2009-05-01

    Cold and ultracold molecules are the next wave of ultracold physics, giving rise to an exciting array of scientific opportunities, including many body physics for novel quantum phase transitions, new states of matter, and quantum information processing. Precision tests of fundamental physical laws benefit from the existence of molecular internal structure with exquisite control. The study of novel collision and reaction dynamics will open a new chapter of quantum chemistry. Cold molecules bring together researchers from a variety of fields, including atomic, molecular, and optical physics, chemistry and chemical physics, quantum information science and quantum simulations, condensed matter physics, nuclear physics, and astrophysics, a truly remarkable synergy of scientific explorations. For the past decade there have been steady advances in direct cooling techniques, from buffer-gas cooling to cold molecular beams to electro- and magneto-molecular decelerators. These techniques have allowed a large variety of molecules to be cooled for pioneering studies. Recent amazing advances in experimental techniques combining the ultracold and the ultraprecise have furthermore brought molecules to the point of quantum degeneracy. These latter indirect cooling techniques magnetically associate atoms from a Bose-Einstein condensate and/or a quantum degenerate Fermi gas, transferring at 90% efficiency highly excited Fano-Feshbach molecules, which are on the order of 10 000 Bohr radii in size, to absolute ground state molecules just a few Bohr across. It was this latter advance, together with significant breakthroughs in internal state manipulations, which inspired us to coordinate this focus issue now, and is the reason why we say the next wave of ultracold physics has now arrived. Whether directly or indirectly cooled, heteronuclear polar molecules offer distinct new features in comparison to cold atoms, while sharing all of their advantages (purity, high coherence

  15. Photodissociation of ultracold diatomic strontium molecules with quantum state control.

    Science.gov (United States)

    McDonald, M; McGuyer, B H; Apfelbeck, F; Lee, C-H; Majewska, I; Moszynski, R; Zelevinsky, T

    2016-07-07

    Chemical reactions at ultracold temperatures are expected to be dominated by quantum mechanical effects. Although progress towards ultracold chemistry has been made through atomic photoassociation, Feshbach resonances and bimolecular collisions, these approaches have been limited by imperfect quantum state selectivity. In particular, attaining complete control of the ground or excited continuum quantum states has remained a challenge. Here we achieve this control using photodissociation, an approach that encodes a wealth of information in the angular distribution of outgoing fragments. By photodissociating ultracold (88)Sr2 molecules with full control of the low-energy continuum, we access the quantum regime of ultracold chemistry, observing resonant and nonresonant barrier tunnelling, matter-wave interference of reaction products and forbidden reaction pathways. Our results illustrate the failure of the traditional quasiclassical model of photodissociation and instead are accurately described by a quantum mechanical model. The experimental ability to produce well-defined quantum continuum states at low energies will enable high-precision studies of long-range molecular potentials for which accurate quantum chemistry models are unavailable, and may serve as a source of entangled states and coherent matter waves for a wide range of experiments in quantum optics.

  16. Diatomic molecules in ultracold Fermi gases - Novel composite bosons

    OpenAIRE

    Petrov, D. S.; Salomon, C.; Shlyapnikov, G. V.

    2005-01-01

    We give a brief overview of recent studies of weakly bound homonuclear molecules in ultracold two-component Fermi gases. It is emphasized that they represent novel composite bosons, which exhibit features of Fermi statistics at short intermolecular distances. In particular, Pauli exclusion principle for identical fermionic atoms provides a strong suppression of collisional relaxation of such molecules into deep bound states. We then analyze heteronuclear molecules which are expected to be for...

  17. Quantum Fluctuations of Vortex Lattices in Ultracold Gases

    OpenAIRE

    Kwasigroch, M. P.; Cooper, N. R.

    2012-01-01

    We discuss the effects of quantum fluctuations on the properties of vortex lattices in rapidly rotating ultracold atomic gases. We develop a variational method that goes beyond the Bogoliubov theory by including the effects of interactions between the quasiparticle excitations. These interactions are found to have significant quantitative effects on physical properties even at relatively large filling factors. We use our theory to predict the expected experimental signatures of quantum fluctu...

  18. Ultracold gas shows 'lopsided' properties

    CERN Multimedia

    2002-01-01

    "Duke University researchers have created an ultracold gas that has the startling property of bursting outward in a preferred direction when released. According to the researchers, studying the properties of the "lopsided" gas will yield fundamental insights into how matter holds itself together at the subatomic level" (1 page).

  19. Advances in ultracold collisions: Experimentation and theory

    International Nuclear Information System (INIS)

    Weiner, J.

    1995-01-01

    Collisions between optically cooled and trapped atoms have been the subject of intensive investigation since early proposals discussed their novel features and key importance to the achievement of a gaseous ensemble in a single quantum state. Progress in both experimentation and theory has accelerated rapidly over the last three years, and two reviews, one emphasizing theory and the other, experiments, recount the state of the art published up to about the midpoint of 1993. The purpose of this chapter is to update continuing lines of research set forth in these and earlier works and to relate new results, establishing novel directions for investigation that have appeared in the literature. Two principal questions motivate research into the nature of ultracold collisions: (1) what new phenomena arise when collisionally interacting particles also exchange photons with modes of the radiation field and (2) what are the important two-body collisional heating mechanisms and how can they be overcome in order to achieve the temperature and density conditions appropriate for Bose-Einstein condensation (BEC)? In fact these two questions are not mutually exclusive, and one of the most notable developments in the past year, relevant to both, has been the demonstration of optical control of two-body ultracold collisional processes. Other important issues touching, on one or both of these questions are the magnitude and sign of the scattering length in s-wave collisions between species in various well-defined quantum states, progress in high-resolution trap loss and photoassociation spectroscopy, and application of optical cooling and compression to atomic beams. 58 refs., 21 figs

  20. Rare earth analysis in human biological samples by atomic absorption using electrothermal atomization

    International Nuclear Information System (INIS)

    Citron, I.M.; Holtzman, R.B.; Leiman, J.

    1982-01-01

    The determination of Sc and seven rare earth elements, Nd, Sm, Dy, Ho, Eu, Tm, and Yb, in biological samplesby atomic absorption spectrophotometric analysis (AAS) using electrothermal atomization in a pyrolytic graphite tube is shown to be rapid, precise and accurate. The technique utilizes the method of standard additions and linear regression analysis to determine results from peak area data. Inter-elemental interferences are negligible. The elements found sensitive enough for this type of analysis are, in order of decreasing sensitivity, Yb, Eu, Tm, Dy, Sc, Ho, Sm and Nd. The determination in these types of materials of Gd and elements less sensitive to AAS detection than Gd does not appear to be feasible. Results are presented on the concentrations of these elements in 41 samples from human subjects, cows and vegetables with normal environmental exposure to the rare earth elements. The composite percent mean deviation in peak-area readings for all samples and all elements examined was 4%. The mean standard error in the results among samples was about 6.5%

  1. Optical trapping and Feshbach spectroscopy of an ultracold Rb-Cs mixture

    International Nuclear Information System (INIS)

    Pilch, K.

    2009-01-01

    We investigate quantum-mechanical interactions between ultracold rubidium and cesium in an optical trap at temperatures of a few micro kelvin. Our results provide, on the one hand, an experimental key to understand the collisional properties and, on the other hand, a tool to control the interspecies interactions. By performing loss measurements we locate several Feshbach resonances, which provide insight into the energy structure of weakly bound RbCs molecules near the dissociation threshold and allow for the production of such heteronuclear Feshbach molecules. In the future we will transfer these loosely-bound molecules into the absolute internal ground state. The availability of ultracold heteronuclear ground state molecules will open the door to investigate phenomena associated with ultracold polar quantum gases. In our new experimental set-up we are able to trap and cool rubidium and cesium atoms in their lowest internal states. First we load both species into a two-color magneto-optical trap, having full control over the single-species atom number. We extend the technique of degenerate Raman-sideband cooling to a two-color version, which is able to simultaneously cool and polarize both rubidium and cesium. Thereafter we load the atoms into a levitated crossed optical dipole trap. Because of the presence of the gradient magnetic field the trap is highly state selective and consequently provides perfect spin-polarization of the sample. Furthermore, a coincidence of the magnetic-moment-to-mass ratios of the two species allows for simultaneous levitation of both, which assures an almost perfect spatial overlap between the species. We perform Feshbach spectroscopy in two dierent spin channels of the mixture within a magnetic field ranging from 20 to 300 Gauss. In the lowest spin combination of the species we locate 23 interspecies Feshbach resonances, while in a higher spin mixture we find 2 resonances. The high number of resonances found within this range of

  2. Light crystals for ultracold quantum degenerate bosonic gases

    International Nuclear Information System (INIS)

    Arimondo, E.

    2009-01-01

    Full text follows. The experimental realization of quantum degenerate states in ultracold atomic gases has opened the possibility to realize few body systems isolated from external perturbations and at temperatures close to absolute zero. Under these conditions counterintuitive phenomena characteristic of the quantum mechanical evolution may be assessed experimentally. Matter quantum-mechanical waves inside periodic potentials investigated in solid-state physics, where electrons propagate within a crystal lattice. Interfering laser beams create a light-induced spatial periodic potential for ultracold atoms called an 'optical lattice'. Atoms hopping between the lattice periodic potential minima emulate the motion of electrons in a crystal. The creation of one-, two-, and three-dimensional periodic structures in which atoms can be trapped and accelerated, with the possibility of switching or modulating the lattice at will, gives a great flexibility. In addition atomic physicists can tune the lattice's geometry, the rate of hopping, and the push and pull between atoms within the light crystals. So they hope to map the various behaviors of solid-state models. On the basis of the research work performed at Pisa, several processes of quantum mechanics evolution within a spatial periodic potential and associated to the solid-state physics will be presented

  3. Directional emission of single photons from small atomic samples

    DEFF Research Database (Denmark)

    Miroshnychenko, Yevhen; V. Poulsen, Uffe; Mølmer, Klaus

    2013-01-01

    We provide a formalism to describe deterministic emission of single photons with tailored spatial and temporal profiles from a regular array of multi-level atoms. We assume that a single collective excitation is initially shared by all the atoms in a metastable atomic state, and that this state i...... is coupled by a classical laser field to an optically excited state which rapidly decays to the ground atomic state. Our model accounts for the different field polarization components via re-absorption and emission of light by the Zeeman manifold of optically excited states.......We provide a formalism to describe deterministic emission of single photons with tailored spatial and temporal profiles from a regular array of multi-level atoms. We assume that a single collective excitation is initially shared by all the atoms in a metastable atomic state, and that this state...

  4. From ultracold Fermi Gases to Neutron Stars

    Science.gov (United States)

    Salomon, Christophe

    2012-02-01

    Ultracold dilute atomic gases can be considered as model systems to address some pending problem in Many-Body physics that occur in condensed matter systems, nuclear physics, and astrophysics. We have developed a general method to probe with high precision the thermodynamics of locally homogeneous ultracold Bose and Fermi gases [1,2,3]. This method allows stringent tests of recent many-body theories. For attractive spin 1/2 fermions with tunable interaction (^6Li), we will show that the gas thermodynamic properties can continuously change from those of weakly interacting Cooper pairs described by Bardeen-Cooper-Schrieffer theory to those of strongly bound molecules undergoing Bose-Einstein condensation. First, we focus on the finite-temperature Equation of State (EoS) of the unpolarized unitary gas. Surprisingly, the low-temperature properties of the strongly interacting normal phase are well described by Fermi liquid theory [3] and we localize the superfluid phase transition. A detailed comparison with theories including recent Monte-Carlo calculations will be presented. Moving away from the unitary gas, the Lee-Huang-Yang and Lee-Yang beyond-mean-field corrections for low density bosonic and fermionic superfluids are quantitatively measured for the first time. Despite orders of magnitude difference in density and temperature, our equation of state can be used to describe low density neutron matter such as the outer shell of neutron stars. [4pt] [1] S. Nascimbène, N. Navon, K. Jiang, F. Chevy, and C. Salomon, Nature 463, 1057 (2010) [0pt] [2] N. Navon, S. Nascimbène, F. Chevy, and C. Salomon, Science 328, 729 (2010) [0pt] [3] S. Nascimbène, N. Navon, S. Pilati, F. Chevy, S. Giorgini, A. Georges, and C. Salomon, Phys. Rev. Lett. 106, 215303 (2011)

  5. Ultracold chromium: a dipolar quantum gas

    International Nuclear Information System (INIS)

    Pfau, T.; Stuhler, J.; Griesmaier, A.; Fattori, M.; Koch, T.

    2005-01-01

    We report on our recent achievement of a Bose-Einstein condensate in a gas of chromium atoms. Peculiar electronic and magnetic properties of chromium require the implementation of novel cooling strategies. We observe up to ∼ 10 5 condensed 52 Cr atoms after forced evaporation within a crossed optical dipole trap. Due to its large magnetic moment (6μ B ), the dipole-dipole interaction strength in chromium is comparable with the one of the van der Waals interaction. We prove the anisotropic nature of the dipolar interaction by releasing the condensate from a cigar shaped trap and observe, in time of flight measurements, the change of the aspect-ratio for different in-trap orientations of the atomic dipoles. We also report on the recent observation of 14 Feshbach resonances in elastic collisions between polarized ultra-cold 52 Cr atoms. This is the first Ballistic expansion of a dipolar quantum gas: The anisotropic interaction leads to a different expansion dynamics for the case of the magnetic dipoles aligned with the symmetry axis of the cigar shaped trap as compared with the dipoles oriented perpendicular to the axis of the cigar. The straight lines correspond to the theoretical expectation according to mean field theory without free parameters. observation of collisional Feshbach resonances in an atomic species with more than one valence electron. Moreover, such resonances constitute an important tool towards the realization of a purely dipolar interacting gas because they can be used to change strength and sign of the van der Waals interaction. (author)

  6. Ultracold lithium-6 atoms in the BEC-BCS crossover: experiments and the construction of a new apparatus; Atomes de lithium-6 ultra froids dans la transition BEC-BCS: experiences et construction d'un montage experimental

    Energy Technology Data Exchange (ETDEWEB)

    Teichmann, M

    2007-09-15

    We use a fermionic gas of Lithium-6 as a model system to study superfluidity. The limiting cases of superfluidity are Bose-Einstein condensation (BEC) and superconductivity, described by the theory by Bardeen, Cooper and Schrieffer (BCS). In Lithium-6 gases, we can explore the whole range between the two cases, known as the BEC-BCS crossover, using a Feshbach resonance. We study the change of the momentum distribution of the gas in this cross-over and compare to theoretical models. We also investigate the hydrodynamic expansion, characteristic for a superfluid gas. We observe a sudden change of the ellipticity of the gas close to the transition to the superfluid phase. Moreover, we localized heteronuclear Feshbach resonances between {sup 6}Li and {sup 7}Li. We are currently constructing a second generation of the experimental setup. An new laser system, based on high power laser diodes, was developed. Changes in the vacuum chamber, including a complete reconstruction of the Zeeman slower, have increased the atomic flux, allowing us to increase the repetition rate of our experiment. Modifications of the geometry of the magnetic traps lead to a higher number of trapped atoms. (author)

  7. Ultracold lithium-6 atoms in the BEC-BCS crossover: experiments and the construction of a new apparatus; Atomes de lithium-6 ultra froids dans la transition BEC-BCS: experiences et construction d'un montage experimental

    Energy Technology Data Exchange (ETDEWEB)

    Teichmann, M

    2007-09-15

    We use a fermionic gas of Lithium-6 as a model system to study superfluidity. The limiting cases of superfluidity are Bose-Einstein condensation (BEC) and superconductivity, described by the theory by Bardeen, Cooper and Schrieffer (BCS). In Lithium-6 gases, we can explore the whole range between the two cases, known as the BEC-BCS crossover, using a Feshbach resonance. We study the change of the momentum distribution of the gas in this cross-over and compare to theoretical models. We also investigate the hydrodynamic expansion, characteristic for a superfluid gas. We observe a sudden change of the ellipticity of the gas close to the transition to the superfluid phase. Moreover, we localized heteronuclear Feshbach resonances between {sup 6}Li and {sup 7}Li. We are currently constructing a second generation of the experimental setup. An new laser system, based on high power laser diodes, was developed. Changes in the vacuum chamber, including a complete reconstruction of the Zeeman slower, have increased the atomic flux, allowing us to increase the repetition rate of our experiment. Modifications of the geometry of the magnetic traps lead to a higher number of trapped atoms. (author)

  8. The production and storage of ultracold neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Yoshiki, Hajime [Kure University, Hiroshima (Japan); Shimizu, Hirohiko; Sakai, Kenji [and others

    1998-01-01

    The electric dipole measurement done on the ultracold neutron till now shows that its quantity is minute, not more than 10{sup -25}e.cm. It is purpose of this particular research program to produce such very slow neutrons, or so-cold ultracold neutrons in great quantity. Then, it was investigated what was the ultracold neutron important for, how is the ultracold neutron made, and how is very pure superfluid liquid helium made. As a result of these investigations, it was found that the validity of ultracold neutron production by superfluid liquid helium was established, that its efficiency is high enough to improve the neutron electric dipole moment detection sensitivity by at least one order of magnitude, and so forth. (G.K.)

  9. Magnetic-field gradiometer based on ultracold collisions

    Science.gov (United States)

    Wasak, Tomasz; Jachymski, Krzysztof; Calarco, Tommaso; Negretti, Antonio

    2018-05-01

    We present a detailed analysis of the usefulness of ultracold atomic collisions for sensing the strength of an external magnetic field as well as its spatial gradient. The core idea of the sensor, which we recently proposed in Jachymski et al. [Phys. Rev. Lett. 120, 013401 (2018), 10.1103/PhysRevLett.120.013401], is to probe the transmission of the atoms through a set of quasi-one-dimensional waveguides that contain an impurity. Magnetic-field-dependent interactions between the incoming atoms and the impurity naturally lead to narrow resonances that can act as sensitive field probes since they strongly affect the transmission. We illustrate our findings with concrete examples of experimental relevance, demonstrating that for large atom fluences N a sensitivity of the order of 1 nT/√{N } for the field strength and 100 nT/(mm √{N }) for the gradient can be reached with our scheme.

  10. On the theory of ultracold neutrons scattering by Davydov solitons

    International Nuclear Information System (INIS)

    Brizhik, L.S.

    1984-01-01

    Elastic coherent scattering of ultracold neutrons by Davydov solitons in one-dimensional periodic molecular chains without account of thermal oscillations of chain atoms is studied. It is shown that the expression for the differential cross section of the elastic neutron scattering by Davydov soliton breaks down into two components. One of them corresponds to scattering by a resting soliton, the other is proportional to the soliton velocity and has a sharp maximum in the direction of mirror reflection of neutrons from the chain

  11. Determination of copper in powdered chocolate samples by slurry-sampling flame atomic-absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Walter N.L. dos; Silva, Erik G.P. da; Fernandes, Marcelo S.; Araujo, Rennan G.O.; Costa, Anto' ' enio C.S.; Ferreira, Sergio L.C. [Nucleo de Excelencia em Quimica Analitica da Bahia, Universidade Federal da Bahia, Instituto de Quimica, Salvador, Bahia (Brazil); Vale, M.G.R. [Instituto de Quimica, Universidade Federal da Bahia do Rio Grande do Sul, Porto Alegre, Rio Grande do Sul (Brazil)

    2005-06-01

    Chocolate is a complex sample with a high content of organic compounds and its analysis generally involves digestion procedures that might include the risk of losses and/or contamination. The determination of copper in chocolate is important because copper compounds are extensively used as fungicides in the farming of cocoa. In this paper, a slurry-sampling flame atomic-absorption spectrometric method is proposed for determination of copper in powdered chocolate samples. Optimization was carried out using univariate methodology involving the variables nature and concentration of the acid solution for slurry preparation, sonication time, and sample mass. The recommended conditions include a sample mass of 0.2 g, 2.0 mol L{sup -1} hydrochloric acid solution, and a sonication time of 15 min. The calibration curve was prepared using aqueous copper standards in 2.0 mol L{sup -1} hydrochloric acid. This method allowed determination of copper in chocolate with a detection limit of 0.4 {mu}g g{sup -1} and precision, expressed as relative standard deviation (RSD), of 2.5% (n=10) for a copper content of approximately 30 {mu}g g{sup -1}, using a chocolate mass of 0.2 g. The accuracy was confirmed by analyzing the certified reference materials NIST SRM 1568a rice flour and NIES CRM 10-b rice flour. The proposed method was used for determination of copper in three powdered chocolate samples, the copper content of which varied between 26.6 and 31.5 {mu}g g{sup -1}. The results showed no significant differences with those obtained after complete digestion, using a t-test for comparison. (orig.)

  12. SO(3) "Nuclear Physics" with ultracold Gases

    Science.gov (United States)

    Rico, E.; Dalmonte, M.; Zoller, P.; Banerjee, D.; Bögli, M.; Stebler, P.; Wiese, U.-J.

    2018-06-01

    An ab initio calculation of nuclear physics from Quantum Chromodynamics (QCD), the fundamental SU(3) gauge theory of the strong interaction, remains an outstanding challenge. Here, we discuss the emergence of key elements of nuclear physics using an SO(3) lattice gauge theory as a toy model for QCD. We show that this model is accessible to state-of-the-art quantum simulation experiments with ultracold atoms in an optical lattice. First, we demonstrate that our model shares characteristic many-body features with QCD, such as the spontaneous breakdown of chiral symmetry, its restoration at finite baryon density, as well as the existence of few-body bound states. Then we show that in the one-dimensional case, the dynamics in the gauge invariant sector can be encoded as a spin S = 3/2 Heisenberg model, i.e., as quantum magnetism, which has a natural realization with bosonic mixtures in optical lattices, and thus sheds light on the connection between non-Abelian gauge theories and quantum magnetism.

  13. Device to investigate samples by means of flameless atomic absorption measurement

    International Nuclear Information System (INIS)

    Sperling, K.R.

    1977-01-01

    An improvement on a device to investigate samples by means of flameless atomic absorption measurement is suggested in which one aims to produce a most complete possible atomic clond from the sample to be investigated within the sample space defined by the beam bundle, through which the measuring beam bundle is passed. According to the invention, the tubular sample space should be closed by an optically penetrable window on one side. (RW) [de

  14. Ultracold molecules: vehicles to scalable quantum information processing

    International Nuclear Information System (INIS)

    Brickman Soderberg, Kathy-Anne; Gemelke, Nathan; Chin Cheng

    2009-01-01

    In this paper, we describe a novel scheme to implement scalable quantum information processing using Li-Cs molecular states to entangle 6 Li and 133 Cs ultracold atoms held in independent optical lattices. The 6 Li atoms will act as quantum bits to store information and 133 Cs atoms will serve as messenger bits that aid in quantum gate operations and mediate entanglement between distant qubit atoms. Each atomic species is held in a separate optical lattice and the atoms can be overlapped by translating the lattices with respect to each other. When the messenger and qubit atoms are overlapped, targeted single-spin operations and entangling operations can be performed by coupling the atomic states to a molecular state with radio-frequency pulses. By controlling the frequency and duration of the radio-frequency pulses, entanglement can be either created or swapped between a qubit messenger pair. We estimate operation fidelities for entangling two distant qubits and discuss scalability of this scheme and constraints on the optical lattice lasers. Finally we demonstrate experimental control of the optical potentials sufficient to translate atoms in the lattice.

  15. Strongly correlated quantum fluids: ultracold quantum gases, quantum chromodynamic plasmas and holographic duality

    OpenAIRE

    Adams, Allan; Carr, Lincoln D.; Schafer, Thomas; Steinberg, Peter; Thomas, John E.

    2012-01-01

    Strongly correlated quantum fluids are phases of matter that are intrinsically quantum mechanical, and that do not have a simple description in terms of weakly interacting quasi-particles. Two systems that have recently attracted a great deal of interest are the quark-gluon plasma, a plasma of strongly interacting quarks and gluons produced in relativistic heavy ion collisions, and ultracold atomic Fermi gases, very dilute clouds of atomic gases confined in optical or magnetic traps. These sy...

  16. Thermodynamics of ultracold Fermi gases

    International Nuclear Information System (INIS)

    Nascimbene, Sylvain

    2010-01-01

    Complex Hamiltonians from condensed matter, such as the Fermi-Hubbard model, can be experimentally studied using ultracold gases. This thesis describes a new method for determining the equation of state of an ultracold gas, making the comparison with many-body theories straightforward. It is based on the measurement of the local pressure inside a trapped gas from the analysis of its in situ image. We first apply this method to the study of a Fermi gas with resonant interactions, a weakly-interacting 7 Li gas acting as a thermometer. Surprisingly, none of the existing many-body theories of the unitary gas accounts for the equation of state deduced from our study over its full range. The virial expansion extracted from the high-temperature data agrees with the resolution of the three-body problem. At low temperature, we observe, contrary to some previous studies, that the normal phase behaves as a Fermi liquid. Finally we obtain the critical temperature for superfluidity from a clear signature on the equation of state. We also measure the pressure of the ground state as a function of spin imbalance and interaction strength - measure directly relevant to describe the crust of neutron stars. Our data validate Monte-Carlo simulations and quantify the Lee-Huang-Yang corrections to mean-field interactions in low-density fermionic or bosonic superfluids. We show that, in most cases, the partially polarized normal phase can be described as a Fermi liquid of polarons. The polaron effective mass extracted from the equation of state is in agreement with a study of collective modes. (author)

  17. Precision spectroscopy with ultracold 87Rb2 triplet molecules

    International Nuclear Information System (INIS)

    Strauss, Christoph

    2011-01-01

    In this thesis I report precision spectroscopy with ultracold 87 Rb 2 triplet molecules where we use lasers to couple the states in different molecular potentials. We study in detail states of the a 3 sum + u and (1) 3 sum + g potentials. These states are of great importance for transferring weakly bound molecules to the ro-vibrational triplet ground state via states of the excited potential. As most experiments start from molecules in their X 1 sum + g ground state, the triplet states were hard to access via dipole transitions and remained largely unexplored. The measurements presented in this thesis are the first detailed study of diatomic 87 Rb 2 molecules in these states. Our experiments start with an ultracold cloud of 87 Rb atoms. We then load this cloud into an optical lattice where we use a magnetic Feshbach resonance at 1007.4 G to perform a Feshbach association. After we have removed all unbound atoms, we end up with a pure sample of weakly bound Feshbach molecules inside the optical lattice. The optical lattice prevents these molecules from colliding with each other which results in molecular lifetimes on the order of a few hundred milliseconds. In the first set of experiments, we use a laser coupling the Feshbach state to the excited (1) 3 sum + g triplet state to map out its low-lying vibrational (v = 0.. 15), rotational, hyperfine, and Zeeman structure. The experimental results are in good agreement with calculations done by Marius Lysebo and Prof. Leif Veseth. We then map out in detail the vibrational, rotational, hyperfine, and Zeeman structure of the a 3 sum + u triplet ground state using dark state spectroscopy with levels in the (1) 3 sum + g potential as an intermediate state. In this scheme we are able to access molecules in triplet states because our Feshbach state has strong triplet character. Interestingly, it happens that some deeply bound states which belong to the X 1 sum + g potential are close to levels in the a 3 sum + u potential. In

  18. Observation of symmetry-protected topological band with ultracold fermions

    Science.gov (United States)

    Song, Bo; Zhang, Long; He, Chengdong; Poon, Ting Fung Jeffrey; Hajiyev, Elnur; Zhang, Shanchao; Liu, Xiong-Jun; Jo, Gyu-Boong

    2018-01-01

    Symmetry plays a fundamental role in understanding complex quantum matter, particularly in classifying topological quantum phases, which have attracted great interests in the recent decade. An outstanding example is the time-reversal invariant topological insulator, a symmetry-protected topological (SPT) phase in the symplectic class of the Altland-Zirnbauer classification. We report the observation for ultracold atoms of a noninteracting SPT band in a one-dimensional optical lattice and study quench dynamics between topologically distinct regimes. The observed SPT band can be protected by a magnetic group and a nonlocal chiral symmetry, with the band topology being measured via Bloch states at symmetric momenta. The topology also resides in far-from-equilibrium spin dynamics, which are predicted and observed in experiment to exhibit qualitatively distinct behaviors in quenching to trivial and nontrivial regimes, revealing two fundamental types of spin-relaxation dynamics related to bulk topology. This work opens the way to expanding the scope of SPT physics with ultracold atoms and studying nonequilibrium quantum dynamics in these exotic systems. PMID:29492457

  19. A novel apparatus for the investigation of material properties for the storage of ultracold neutrons

    International Nuclear Information System (INIS)

    Brys, T.; Daum, M.; Fierlinger, P.; Geltenbort, P.; George, D.; Gupta, M.; Henneck, R.; Heule, S.; Horvat, M.; Kasprzak, M.; Kirch, K.; Kohlik, K.; Negrazus, M.; Pichlmaier, A.; Straumann, U.; Vrankovic, V.; Wermelinger, C.

    2005-01-01

    We have built a novel apparatus for the investigation of materials for the storage of ultracold neutrons. Neutrons are filled into a storage volume, confined at the bottom by a magnetic field, at the top by gravity and at the sides by the slit-less sample surface under investigation. For different beryllium and diamond-like carbon samples, storage times up to 200s were obtained at room temperature. The corresponding loss parameters η for ultracold neutrons varied between 4.2 and 6.8x10 -4 per wall collision

  20. Diamondlike carbon can replace beryllium in physics with ultracold neutrons

    International Nuclear Information System (INIS)

    Atchison, F.; Blau, B.; Daum, M.; Fierlinger, P.; Foelske, A.; Geltenbort, P.; Gupta, M.; Henneck, R.; Heule, S.; Kasprzak, M.; Kuzniak, M.; Kirch, K.; Meier, M.; Pichlmaier, A.; Plonka, Ch.; Reiser, R.; Theiler, B.; Zimmer, O.; Zsigmond, G.

    2006-01-01

    To complete our study of ultracold neutron (UCN) storage-vessel coatings, we have measured the Fermi potential for neutrons on diamondlike carbon coatings produced by laser induced vacuum arc deposition. A sample with an sp 3 content of 0.45, measured using, for the first time, neutron transmission had a Fermi potential of (249+/-14)neV. A second sample with an sp 3 fraction of 0.67, measured using cold neutron reflectometry, gave (271+/-13)neV. These values complete the demonstration that there is a viable alternative to Be in UCN physics

  1. Evidence of Antiblockade in an Ultracold Rydberg Gas

    Science.gov (United States)

    Amthor, Thomas; Giese, Christian; Hofmann, Christoph S.; Weidemüller, Matthias

    2010-01-01

    We present the experimental observation of the antiblockade in an ultracold Rydberg gas recently proposed by Ates et al. [Phys. Rev. Lett. 98, 023002 (2007)PRLTAO0031-900710.1103/PhysRevLett.98.023002]. Our approach allows the control of the pair distribution in the gas and is based on a strong coupling of one transition in an atomic three-level system, while introducing specific detunings of the other transition. When the coupling energy matches the interaction energy of the Rydberg long-range interactions, the otherwise blocked excitation of close pairs becomes possible. A time-resolved spectroscopic measurement of the Penning ionization signal is used to identify slight variations in the Rydberg pair distribution of a random arrangement of atoms. A model based on a pair interaction Hamiltonian is presented which well reproduces our experimental observations and allows one to deduce the distribution of nearest-neighbor distances.

  2. Quantum optics with ultracold quantum gases: towards the full quantum regime of the light-matter interaction

    International Nuclear Information System (INIS)

    Mekhov, Igor B; Ritsch, Helmut

    2012-01-01

    Although the study of ultracold quantum gases trapped by light is a prominent direction of modern research, the quantum properties of light were widely neglected in this field. Quantum optics with quantum gases closes this gap and addresses phenomena where the quantum statistical natures of both light and ultracold matter play equally important roles. First, light can serve as a quantum nondemolition probe of the quantum dynamics of various ultracold particles from ultracold atomic and molecular gases to nanoparticles and nanomechanical systems. Second, due to the dynamic light-matter entanglement, projective measurement-based preparation of the many-body states is possible, where the class of emerging atomic states can be designed via optical geometry. Light scattering constitutes such a quantum measurement with controllable measurement back-action. As in cavity-based spin squeezing, the atom number squeezed and Schrödinger cat states can be prepared. Third, trapping atoms inside an optical cavity, one creates optical potentials and forces, which are not prescribed but quantized and dynamical variables themselves. Ultimately, cavity quantum electrodynamics with quantum gases requires a self-consistent solution for light and particles, which enriches the picture of quantum many-body states of atoms trapped in quantum potentials. This will allow quantum simulations of phenomena related to the physics of phonons, polarons, polaritons and other quantum quasiparticles. (topical review)

  3. High-resolution internal state control of ultracold 23Na87Rb molecules

    Science.gov (United States)

    Guo, Mingyang; Ye, Xin; He, Junyu; Quéméner, Goulven; Wang, Dajun

    2018-02-01

    We report the full internal state control of ultracold 23Na87Rb molecules, including vibrational, rotational, and hyperfine degrees of freedom. Starting from a sample of weakly bound Feshbach molecules, we realize the creation of molecules in single hyperfine levels of both the rovibrational ground and excited states with a high-efficiency and high-resolution stimulated Raman adiabatic passage. This capability brings broad possibilities for investigating ultracold polar molecules with different chemical reactivities and interactions with a single molecular species. Moreover, starting from the rovibrational and hyperfine ground state, we achieve rotational and hyperfine control with one- and two-photon microwave spectroscopy to reach levels not accessible by the stimulated Raman transfer. The combination of these two techniques results in complete control over the internal state of ultracold polar molecules, which paves the way to study state-dependent molecular collisions and state-controlled chemical reactions.

  4. Observation of Resonant Effects in Ultracold Collisions between Heteronuclear Feshbach Molecules

    Science.gov (United States)

    Ye, Xin; Wang, Fudong; Zhu, Bing; Guo, Mingyang; Lu, Bo; Wang, Dajun

    2016-05-01

    Magnetic field dependent dimer-dimer collisional losses are studied with ultracold 23 Na87 Rb Feshbach molecules. By ramping the magnetic field across the 347.8 G inter-species Feshbach resonance and removing residual atoms with a magnetic field gradient, ~ 8000 pure NaRb Feshbach molecules with a temperature below 1 μK are produced. By holding the pure molecule sample in a crossed optical dipole trap and measuring the time-dependent loss curves under different magnetic fields near the Feshbach resonance, the dimer-dimer loss rates with respect to the atomic scattering length a are mapped out. We observe a resonant feature at around a = 600a0 and a rising tail at above a = 1600a0 . This behavior resembles previous theoretical works on homonuclear Feshbach molecule, where resonant effects between dimer-dimer collisions tied to tetramer bound states were predicted. Our work shows the possibility of exploring four-body physics within a heteronuclear system. We are supported by Hong Kong RGC General Research Fund no. CUHK403813.

  5. Making ultracold molecules in a two color pump-dump photoassociation scheme using chirped pulses

    OpenAIRE

    Koch, Christiane P.; Luc-Koenig, Eliane; Masnou-Seeuws, Françoise

    2005-01-01

    This theoretical paper investigates the formation of ground state molecules from ultracold cesium atoms in a two-color scheme. Following previous work on photoassociation with chirped picosecond pulses [Luc-Koenig et al., Phys. Rev. A {\\bf 70}, 033414 (2004)], we investigate stabilization by a second (dump) pulse. By appropriately choosing the dump pulse parameters and time delay with respect to the photoassociation pulse, we show that a large number of deeply bound molecules are created in t...

  6. Mean-field description of ultracold bosons on disordered two-dimensional optical lattices

    International Nuclear Information System (INIS)

    Buonsante, Pierfrancesco; Massel, Francesco; Penna, Vittorio; Vezzani, Alessandro

    2007-01-01

    In the present communication, we describe the properties induced by disorder on an ultracold gas of bosonic atoms loaded into a two-dimensional optical lattice with global confinement ensured by a parabolic potential. Our analysis is centred on the spatial distribution of the various phases, focusing particularly on the superfluid properties of the system as a function of external parameters and disorder amplitude. In particular, it is shown how disorder can suppress superfluidity, while partially preserving the system coherence. (fast track communication)

  7. Hofstadter's butterfly energy spectrum of ultracold fermions on the two-dimensional triangular optical lattice

    International Nuclear Information System (INIS)

    Hou Jingmin; Lu Qingqing

    2009-01-01

    We study the energy spectrum of ultracold fermionic atoms on the two-dimensional triangular optical lattice subjected to a perpendicular effective magnetic field, which can be realized with laser beams. We derive the generalized Harper's equations and numerically solve them, then we obtain the Hofstadter's butterfly-like energy spectrum, which has a novel fractal structure. The observability of the Hofstadter's butterfly spectrum is also discussed

  8. Automated Sampling and Extraction of Krypton from Small Air Samples for Kr-85 Measurement Using Atom Trap Trace Analysis

    International Nuclear Information System (INIS)

    Hebel, S.; Hands, J.; Goering, F.; Kirchner, G.; Purtschert, R.

    2015-01-01

    Atom-Trap-Trace-Analysis (ATTA) provides the capability of measuring the Krypton-85 concentration in microlitre amounts of krypton extracted from air samples of about 1 litre. This sample size is sufficiently small to allow for a range of applications, including on-site spot sampling and continuous sampling over periods of several hours. All samples can be easily handled and transported to an off-site laboratory for ATTA measurement, or stored and analyzed on demand. Bayesian sampling methodologies can be applied by blending samples for bulk measurement and performing in-depth analysis as required. Prerequisite for measurement is the extraction of a pure krypton fraction from the sample. This paper introduces an extraction unit able to isolate the krypton in small ambient air samples with high speed, high efficiency and in a fully automated manner using a combination of cryogenic distillation and gas chromatography. Air samples are collected using an automated smart sampler developed in-house to achieve a constant sampling rate over adjustable time periods ranging from 5 minutes to 3 hours per sample. The smart sampler can be deployed in the field and operate on battery for one week to take up to 60 air samples. This high flexibility of sampling and the fast, robust sample preparation are a valuable tool for research and the application of Kr-85 measurements to novel Safeguards procedures. (author)

  9. Atoms

    International Nuclear Information System (INIS)

    Fuchs, Alain; Villani, Cedric; Guthleben, Denis; Leduc, Michele; Brenner, Anastasios; Pouthas, Joel; Perrin, Jean

    2014-01-01

    Completed by recent contributions on various topics (atoms and the Brownian motion, the career of Jean Perrin, the evolution of atomic physics since Jean Perrin, relationship between scientific atomism and philosophical atomism), this book is a reprint of a book published at the beginning of the twentieth century in which the author addressed the relationship between atomic theory and chemistry (molecules, atoms, the Avogadro hypothesis, molecule structures, solutes, upper limits of molecular quantities), molecular agitation (molecule velocity, molecule rotation or vibration, molecular free range), the Brownian motion and emulsions (history and general features, statistical equilibrium of emulsions), the laws of the Brownian motion (Einstein's theory, experimental control), fluctuations (the theory of Smoluchowski), light and quanta (black body, extension of quantum theory), the electricity atom, the atom genesis and destruction (transmutations, atom counting)

  10. Quantum versus classical statistical dynamics of an ultracold Bose gas

    International Nuclear Information System (INIS)

    Berges, Juergen; Gasenzer, Thomas

    2007-01-01

    We investigate the conditions under which quantum fluctuations are relevant for the quantitative interpretation of experiments with ultracold Bose gases. This requires to go beyond the description in terms of the Gross-Pitaevskii and Hartree-Fock-Bogoliubov mean-field theories, which can be obtained as classical (statistical) field-theory approximations of the quantum many-body problem. We employ functional-integral techniques based on the two-particle irreducible (2PI) effective action. The role of quantum fluctuations is studied within the nonperturbative 2PI 1/N expansion to next-to-leading order. At this accuracy level memory integrals enter the dynamic equations, which differ for quantum and classical statistical descriptions. This can be used to obtain a classicality condition for the many-body dynamics. We exemplify this condition by studying the nonequilibrium evolution of a one-dimensional Bose gas of sodium atoms, and discuss some distinctive properties of quantum versus classical statistical dynamics

  11. A Michelson interferometer for ultracold neutrons

    International Nuclear Information System (INIS)

    Steyerl, A.; Malik, S.S.; Steinhauser, K.A.; Berger, L.

    1979-01-01

    We propose a neutron Michelson Interferometer installed within a focussing 'gravity diffractometer' for ultracold neutrons. In this arrangement the expected interference pattern depends only on the well-defined vertical component of neutron wavevector. Possible applications of such an interferometer are discussed. (orig.)

  12. Continuous all-optical deceleration of molecular beams and demonstration with Rb atoms

    Science.gov (United States)

    Long, Xueping; Jayich, Andrew; Campbell, Wesley

    2017-04-01

    Ultracold samples of molecules are desirable for a variety of applications, such as many-body physics, precision measurement and quantum information science. However, the pursuit of ultracold molecules has achieved limited success: spontaneous emission into many different dark states makes it hard to optically decelerate molecules to trappable speed. We propose to address this problem with a general optical deceleration technique that exploits a pump-dump pulse pair from a mode-locked laser. A molecular beam is first excited by a counter-propagating ``pump'' pulse. The molecular beam is then driven back to the initial ground state by a co-propagating ``dump'' pulse via stimulated emission. The delay between the pump and dump pulse is set to be shorter than the excited state lifetimes in order to limit decays to dark states. We report progress benchmarking this stimulated force by accelerating a cold sample of neutral Rb atoms.

  13. Determination of trace elements in paints by direct sampling graphite furnace atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Bentlin, Fabrina R.S. [Instituto de Quimica, Universidade Federal do Rio Grande do Sul, UFRGS, 91501-970 Porto Alegre, RS (Brazil); Pozebon, Dirce [Instituto de Quimica, Universidade Federal do Rio Grande do Sul, UFRGS, 91501-970 Porto Alegre, RS (Brazil)], E-mail: dircepoz@iq.ufrgs.br; Mello, Paola A.; Flores, Erico M.M. [Departamento de Quimica, Universidade Federal de Santa Maria, UFSM, 97105-900 Santa Maria, RS (Brazil)

    2007-10-17

    A direct sampling graphite furnace atomic absorption spectrometric (DS-GFAAS) method for the determination of Cd, Pb, Cr, Ni, Co and Cu in paints has been developed. Serigraphy, acrylic and tattoo paints were analysed. Approaches like pyrolysis and atomization temperatures, modifiers and sample mass introduced in the atomizer were studied. Quantification was performed using calibration curves measured with aqueous standard solutions pipetted onto the platform. The sample mass introduced in the graphite tube ranged from 0.02 to 8.0 mg. Palladium was used as modifier for Cd, Pb and Cu, while Mg(NO{sub 3}){sub 2} was used for Co. For Ni determination, the graphite platform was covered with carbon powder. The characteristic masses of Cd, Pb, Cr, Ni, Co and Cu were 1.4, 22.5, 7.9, 11.0, 9.6 and 12.5 pg, while the limits of detection were 0.0004, 0.001, 0.03, 0.22, 0.11 and 0.05 {mu}g g{sup -1} of Cd, Pb, Cr, Ni, Co and Cu, respectively. The accuracy was determined by comparison of the results with those obtained by inductively coupled plasma mass spectrometry (ICP-MS) and graphite furnace atomic absorption spectrometry (GFAAS), using liquid sampling of digests. For matrix characterization, major and minor elements (Al, Mg, Ba, Ca, Cr, Cu, Pb, Sr, Ti and Mg) were determined by inductively coupled plasma optical emission spectrometry (ICP OES)

  14. Determination of trace impurities in titanium dioxide by direct solid sampling electrothermal atomic absorption spectrometry

    Czech Academy of Sciences Publication Activity Database

    Vojtková, Blanka; Dočekal, Bohumil

    2005-01-01

    Roč. 99, S (2005), s489-s491 ISSN 0009-2770. [Meeting on Chemistry and Life /3./. Brno, 20.09.2005-22.09.2005] Institutional research plan: CEZ:AV0Z40310501 Keywords : solid sampling * electrothermal atomic absorption spectrometry * trace analysis Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 0.445, year: 2005

  15. Determination of trace elements in paints by direct sampling graphite furnace atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Bentlin, Fabrina R.S.; Pozebon, Dirce; Mello, Paola A.; Flores, Erico M.M.

    2007-01-01

    A direct sampling graphite furnace atomic absorption spectrometric (DS-GFAAS) method for the determination of Cd, Pb, Cr, Ni, Co and Cu in paints has been developed. Serigraphy, acrylic and tattoo paints were analysed. Approaches like pyrolysis and atomization temperatures, modifiers and sample mass introduced in the atomizer were studied. Quantification was performed using calibration curves measured with aqueous standard solutions pipetted onto the platform. The sample mass introduced in the graphite tube ranged from 0.02 to 8.0 mg. Palladium was used as modifier for Cd, Pb and Cu, while Mg(NO 3 ) 2 was used for Co. For Ni determination, the graphite platform was covered with carbon powder. The characteristic masses of Cd, Pb, Cr, Ni, Co and Cu were 1.4, 22.5, 7.9, 11.0, 9.6 and 12.5 pg, while the limits of detection were 0.0004, 0.001, 0.03, 0.22, 0.11 and 0.05 μg g -1 of Cd, Pb, Cr, Ni, Co and Cu, respectively. The accuracy was determined by comparison of the results with those obtained by inductively coupled plasma mass spectrometry (ICP-MS) and graphite furnace atomic absorption spectrometry (GFAAS), using liquid sampling of digests. For matrix characterization, major and minor elements (Al, Mg, Ba, Ca, Cr, Cu, Pb, Sr, Ti and Mg) were determined by inductively coupled plasma optical emission spectrometry (ICP OES)

  16. Influence of atomic force microscope tip-sample interaction on the study of scaling behavior

    NARCIS (Netherlands)

    Aue, J.; de Hosson, J.T.M.

    1997-01-01

    Images acquired with atomic force microscopy are based on tip-sample interaction. It is shown that using scanning probe techniques for determining scaling parameters of a surface leads to an underestimate of the actual scaling dimension, due to the dilation of tip and surface. How much we

  17. Electric-field-modified Feshbach resonances in ultracold atom–molecule collision

    International Nuclear Information System (INIS)

    Cheng Dong; Li Ya; Feng Eryin; Huang Wuying

    2017-01-01

    We present a detailed analysis of near zero-energy Feshbach resonances in ultracold collisions of atom and molecule, taking the He–PH system as an example, subject to superimposed electric and magnetic static fields. We find that the electric field can induce Feshbach resonance which cannot occur when only a magnetic field is applied, through couplings of the adjacent rotational states of different parities. We show that the electric field can shift the position of the magnetic Feshbach resonance, and change the amplitude of resonance significantly. Finally, we demonstrate that, for narrow magnetic Feshbach resonance as in most cases of ultracold atom–molecule collision, the electric field may be used to modulate the resonance, because the width of resonance in electric field scale is relatively larger than that in magnetic field scale. (paper)

  18. Interactions of Ultracold Impurity Particles with Bose-Einstein Condensates

    Science.gov (United States)

    2015-06-23

    AFRL-OSR-VA-TR-2015-0141 INTERACTIONS OF ULTRACOLD IMPURITY PARTICLES WITH BOSE- EINSTEIN CONDENSATES Georg Raithel UNIVERSITY OF MICHIGAN Final...SUBTITLE Interactions of ultracold impurity particles with Bose- Einstein Condensates 5a. CONTRACT NUMBER FA9550-10-1-0453 5b. GRANT NUMBER 5c...Interactions of ultracold impurity particles with Bose- Einstein Condensates Contract/Grant #: FA9550-10-1-0453 Reporting Period: 8/15/2010 to 2/14

  19. Nonlinear Dynamics of Cantilever-Sample Interactions in Atomic Force Microscopy

    Science.gov (United States)

    Cantrell, John H.; Cantrell, Sean A.

    2010-01-01

    The interaction of the cantilever tip of an atomic force microscope (AFM) with the sample surface is obtained by treating the cantilever and sample as independent systems coupled by a nonlinear force acting between the cantilever tip and a volume element of the sample surface. The volume element is subjected to a restoring force from the remainder of the sample that provides dynamical equilibrium for the combined systems. The model accounts for the positions on the cantilever of the cantilever tip, laser probe, and excitation force (if any) via a basis set of set of orthogonal functions that may be generalized to account for arbitrary cantilever shapes. The basis set is extended to include nonlinear cantilever modes. The model leads to a pair of coupled nonlinear differential equations that are solved analytically using a matrix iteration procedure. The effects of oscillatory excitation forces applied either to the cantilever or to the sample surface (or to both) are obtained from the solution set and applied to the to the assessment of phase and amplitude signals generated by various acoustic-atomic force microscope (A-AFM) modalities. The influence of bistable cantilever modes of on AFM signal generation is discussed. The effects on the cantilever-sample surface dynamics of subsurface features embedded in the sample that are perturbed by surface-generated oscillatory excitation forces and carried to the cantilever via wave propagation are accounted by the Bolef-Miller propagating wave model. Expressions pertaining to signal generation and image contrast in A-AFM are obtained and applied to amplitude modulation (intermittent contact) atomic force microscopy and resonant difference-frequency atomic force ultrasonic microscopy (RDF-AFUM). The influence of phase accumulation in A-AFM on image contrast is discussed, as is the effect of hard contact and maximum nonlinearity regimes of A-AFM operation.

  20. Determination of the neutral oxygen atom density in a plasma reactor loaded with metal samples

    Science.gov (United States)

    Mozetic, Miran; Cvelbar, Uros

    2009-08-01

    The density of neutral oxygen atoms was determined during processing of metal samples in a plasma reactor. The reactor was a Pyrex tube with an inner diameter of 11 cm and a length of 30 cm. Plasma was created by an inductively coupled radiofrequency generator operating at a frequency of 27.12 MHz and output power up to 500 W. The O density was measured at the edge of the glass tube with a copper fiber optics catalytic probe. The O atom density in the empty tube depended on pressure and was between 4 and 7 × 1021 m-3. The maximum O density was at a pressure of about 150 Pa, while the dissociation fraction of O2 molecules was maximal at the lowest pressure and decreased with increasing pressure. At about 300 Pa it dropped below 10%. The measurements were repeated in the chamber loaded with different metallic samples. In these cases, the density of oxygen atoms was lower than that in the empty chamber. The results were explained by a drain of O atoms caused by heterogeneous recombination on the samples.

  1. The charge imbalance in ultracold plasmas

    International Nuclear Information System (INIS)

    Chen, Tianxing; Lu, Ronghua; Guo, Li; Han, Shensheng

    2016-01-01

    Ultracold plasmas are regarded as quasineutral but not strictly neutral. The results of charge imbalance in the expansion of ultracold plasmas are reported. The calculations are performed by a full molecular-dynamics simulation. The details of the electron velocity distributions are calculated without the assumption of electron global thermal equilibrium and Boltzmann distribution. Spontaneous evolutions of the charge imbalance from the initial states with perfect neutrality are given in the simulations. The expansion of outer plasma slows down with the charge imbalance. The influences of plasma size and parameters on the charge imbalance are discussed. The radial profiles of electron temperature are given for the first time, and the self-similar expansion can still occur even if there is no global thermal equilibrium. The electron disorder induced heating is also found in the simulation.

  2. The charge imbalance in ultracold plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Tianxing; Lu, Ronghua, E-mail: lurh@siom.ac.cn; Guo, Li; Han, Shensheng [Key Laboratory for Quantum Optics and Center for Cold Atom Physics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 (China)

    2016-09-15

    Ultracold plasmas are regarded as quasineutral but not strictly neutral. The results of charge imbalance in the expansion of ultracold plasmas are reported. The calculations are performed by a full molecular-dynamics simulation. The details of the electron velocity distributions are calculated without the assumption of electron global thermal equilibrium and Boltzmann distribution. Spontaneous evolutions of the charge imbalance from the initial states with perfect neutrality are given in the simulations. The expansion of outer plasma slows down with the charge imbalance. The influences of plasma size and parameters on the charge imbalance are discussed. The radial profiles of electron temperature are given for the first time, and the self-similar expansion can still occur even if there is no global thermal equilibrium. The electron disorder induced heating is also found in the simulation.

  3. Atom

    International Nuclear Information System (INIS)

    Auffray, J.P.

    1997-01-01

    The atom through centuries, has been imagined, described, explored, then accelerated, combined...But what happens truly inside the atom? And what are mechanisms who allow its stability? Physicist and historian of sciences, Jean-Paul Auffray explains that these questions are to the heart of the modern physics and it brings them a new lighting. (N.C.)

  4. Atomic absorption determination of ultratrace tellurium in rocks utilizing high sensitivity sampling systems

    International Nuclear Information System (INIS)

    Beaty, R.D.

    1973-01-01

    The sampling boat and the graphite furnace were shown to possess the required sensitivity to detect tellurium at ultratrace levels, in a variety of sample types, by atomic absorption. In the sampling boat approach, tellurium in sample solutions is chemically separated and concentrated by extraction into methyl isobutyl ketone before measurement. For samples exhibiting extraction interferences or excessively high background absorption, a preliminary separation of tellurium by coprecipitation with selenium is described. Using this technique, tellurium can be quantitatively detected down to 5 nanograms and linear response is observed to 100 nanograms. Relative standard deviations of better than 7 percent are achieved for 50 nanograms of tellurium. For samples that have a tellurium content below the detection limits of the sampling boat, the graphite furnace is used for atomization. By this method, as little as 0.07 nanograms of tellurium can be detected, and a precision of 1 percent relative standard deviation is achievable at the 5 nanogram level. A routinely applicable procedure was developed for determining tellurium in rocks, using the graphite furnace, after a hydrofluoric acid decomposition of the sample. Using this procedure, tellurium data were obtained on 20 different rocks, and the significance of this new information is discussed. (Diss. Abstr. Int., B)

  5. On-line determination of manganese in solid seafood samples by flame atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Yebra, M.C.; Moreno-Cid, A.

    2003-01-01

    Manganese is extracted on-line from solid seafood samples by a simple continuous ultrasound-assisted extraction system (CUES). This system is connected to an on-line manifold, which permits the flow-injection flame atomic absorption spectrometric determination of manganese. Optimisation of the continuous leaching procedure is performed by an experimental design. The proposed method allows the determination of manganese with a relative standard deviation of 0.9% for a sample containing 23.4 μg g -1 manganese (dry mass). The detection limit is 0.4 μg g -1 (dry mass) for 30 mg of sample and the sample throughput is ca. 60 samples per hour. Accurate results are obtained by measuring TORT-1 certified reference material. The procedure is finally applied to mussel, tuna, sardine and clams samples

  6. Collisional Cooling of Light Ions by Cotrapped Heavy Atoms.

    Science.gov (United States)

    Dutta, Sourav; Sawant, Rahul; Rangwala, S A

    2017-03-17

    We experimentally demonstrate cooling of trapped ions by collisions with cotrapped, higher-mass neutral atoms. It is shown that the lighter ^{39}K^{+} ions, created by ionizing ^{39}K atoms in a magneto-optical trap (MOT), when trapped in an ion trap and subsequently allowed to cool by collisions with ultracold, heavier ^{85}Rb atoms in a MOT, exhibit a longer trap lifetime than without the localized ^{85}Rb MOT atoms. A similar cooling of trapped ^{85}Rb^{+} ions by ultracold ^{133}Cs atoms in a MOT is also demonstrated in a different experimental configuration to validate this mechanism of ion cooling by localized and centered ultracold neutral atoms. Our results suggest that the cooling of ions by localized cold atoms holds for any mass ratio, thereby enabling studies on a wider class of atom-ion systems irrespective of their masses.

  7. Note: A scanning electron microscope sample holder for bidirectional characterization of atomic force microscope probe tips

    Energy Technology Data Exchange (ETDEWEB)

    Eisenstein, Alon; Goh, M. Cynthia [Department of Chemistry and Institute for Optical Sciences, University of Toronto, 80 St. George Street, Toronto M5S 3H6 (Canada)

    2012-03-15

    A novel sample holder that enables atomic force microscopy (AFM) tips to be mounted inside a scanning electron microscopy (SEM) for the purpose of characterizing the AFM tips is described. The holder provides quick and easy handling of tips by using a spring clip to hold them in place. The holder can accommodate two tips simultaneously in two perpendicular orientations, allowing both top and side view imaging of the tips by the SEM.

  8. Introduction of Flame Atomic Absorption Spectrometry (FAAS) For River Water Samples Analysis

    International Nuclear Information System (INIS)

    Shakirah Abd Shukor; Mohd Suhaimi Hamzah; Shamsiah Abdul Rahman

    2015-01-01

    Metal contamination in water is a major component in the determination of water quality monitoring. In spite of the viability of several other metal ion analysis techniques for river water, atomic absorption spectroscopy (AAS) method is most commonly used due to the reproducibility results, short analysis time, cost effective, lower level detection and robust. Therefore, this article gives an overview on the principles, instrumentation techniques, sample preparations, instrument calibration and data analysis in a simple manner for beginner. (author)

  9. Minimizing tip-sample forces in jumping mode atomic force microscopy in liquid

    Energy Technology Data Exchange (ETDEWEB)

    Ortega-Esteban, A. [Departamento de Fisica de la Materia Condensada, C-3, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid (Spain); Horcas, I. [Nanotec Electronica S.L., Centro Empresarial Euronova 3, Ronda de Poniente 12, 28760 Tres Cantos, Madrid (Spain); Hernando-Perez, M. [Departamento de Fisica de la Materia Condensada, C-3, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid (Spain); Ares, P. [Nanotec Electronica S.L., Centro Empresarial Euronova 3, Ronda de Poniente 12, 28760 Tres Cantos, Madrid (Spain); Perez-Berna, A.J.; San Martin, C.; Carrascosa, J.L. [Centro Nacional de Biotecnologia (CNB-CSIC), Darwin 3, 28049 Madrid (Spain); Pablo, P.J. de [Departamento de Fisica de la Materia Condensada, C-3, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid (Spain); Gomez-Herrero, J., E-mail: julio.gomez@uam.es [Departamento de Fisica de la Materia Condensada, C-3, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid (Spain)

    2012-03-15

    Control and minimization of tip-sample interaction forces are imperative tasks to maximize the performance of atomic force microscopy. In particular, when imaging soft biological matter in liquids, the cantilever dragging force prevents identification of the tip-sample mechanical contact, resulting in deleterious interaction with the specimen. In this work we present an improved jumping mode procedure that allows detecting the tip-sample contact with high accuracy, thus minimizing the scanning forces ({approx}100 pN) during the approach cycles. To illustrate this method we report images of human adenovirus and T7 bacteriophage particles which are prone to uncontrolled modifications when using conventional jumping mode. -- Highlights: Black-Right-Pointing-Pointer Improvement in atomic force microscopy in buffer solution. Black-Right-Pointing-Pointer Peak force detection. Black-Right-Pointing-Pointer Subtracting the cantilever dragging force. Black-Right-Pointing-Pointer Forces in the 100 pN range. Black-Right-Pointing-Pointer Imaging of delicate viruses with atomic force microscopy.

  10. Ultracold fermion race is on

    International Nuclear Information System (INIS)

    Hulet, R.

    1999-01-01

    At the quantum level, particles behave very differently depending on whether their spin angular momentum is an integer or a half-integer. Half-integer spin particles are known as fermions, and include all the constituents of atoms: electrons, protons and neutrons. Bosons, on the other hand, are particles with integer spin, such as photons. Atoms are fermions if they are composed of an odd number of particles, like helium-3 or lithium-6. If they have an even number of constituents, like hydrogen, helium-4 or lithium-7, they are known as bosons. Fermions and bosons behave in profoundly different ways under certain conditions, especially at low temperatures. Four years ago, physicists created a Bose condensate, a quantum degenerate gas of bosons. Now the race is on to do the same with fermions. Deborah Jin's group at the US National Institute of Standards and Technology (NIST) and the University of Colorado has cooled a fermion gas to the lowest temperature yet (B DeMarco 1999 Phys. Rev. Lett. 82 4208). And John Thomas and co-workers at Duke University have set a new record for the length of time that fermions can be trapped using lasers (K O'Hara 1999 Phys. Rev. Lett. 82 4204). In this article the author describes the latest advances in the race to create a quantum degenerate gas of fermions. (UK)

  11. Matrix modifiers application during microimpurities determination in complex samples by electrothermal atomic-absorption spectrometry

    International Nuclear Information System (INIS)

    Bejzel', N.F.; Daaman, F.I.; Fuks-Pol', G.R.; Yudelevich, I.G.

    1993-01-01

    The review covers publications of primarily last 5 years and is devoted to the use of matrix modifiers (MM) for the determinations of trace impurities in complex samples by electrothermal atomic-absorption analysis. The role of MM in analytical process has been discussed as well as MM influence on all the elements of analytical system; factors, determining the effectiveness of MM action, the basis types of MM have been described. A great body of information is tabulated on the use of different MM for the determination of particular analysis in geological, medicobiological, technological, ecological samples and in pure materials and chemicals

  12. Matrix modification for determination of microimpurities in complex samples by electrothermal atomic-absorption spectrometry

    International Nuclear Information System (INIS)

    Bejzel', N.F.; Daaman, F.I.; Fuks-Pol', G.R.; Yudelevich, I.G.

    1993-01-01

    The review covers publications of primarily last 5 years and is devoted to the use of matrix modifiers (MM) for the determinations of trace impurities in complex samples by electrothermal atomic-absorption analysis. The role of MM in analytical process has been discussed as well as MM influence on all the elements of analytical system; factors, determining the effectiveness of MM action, the basis types of MM have been described. A great body of information is tabulated on the use of different MM for the determination of particular analysis in geological, medicobiological, technological, ecological samples and in pure materials and chemicals

  13. Small sample analysis using sputter atomization/resonance ionization mass spectrometry

    International Nuclear Information System (INIS)

    Christie, W.H.; Goeringer, D.E.

    1986-01-01

    We have used secondary ion mass spectrometry (SIMS) to investigate the emission of ions via argon sputtering from U metal, UO 2 , and U 3 O 8 samples. We have also used laser resonance ionization techniques to study argon-sputtered neutral atoms and molecules emitted from these same samples. For the case of U metal, a significant enhancement in detection sensitivity for U is obtained via SA/RIMS. For U in the fully oxidized form (U 3 O 8 ), SA/RIMS offers no improvement in U detection sensitivity over conventional SIMS when sputtering with argon. 9 refs., 1 fig., 2 tabs

  14. Mercury speciation in environmental solid samples using thermal release technique with atomic absorption detection

    Energy Technology Data Exchange (ETDEWEB)

    Shuvaeva, Olga V. [Institute of Inorganic Chemistry, Academician Lavrent' ev Prospect 3, 630090 Novosbirsk (Russian Federation)], E-mail: olga@che.nsk.su; Gustaytis, Maria A.; Anoshin, Gennadii N. [Institute of Geology and Mineralogy, Siberian Branch of Russian Academy of Sciences, Koptyug Prospect 3, 630090 Novosibirsk (Russian Federation)

    2008-07-28

    A sensitive and very simple method for determination of mercury species in solid samples has been developed involving thermal release analysis in combination with atomic absorption (AAS) detection. The method allows determination of mercury(II) chloride, methylmercury and mercury sulfide at the level of 0.70, 0.35 and 0.20 ng with a reproducibility of the results of 14, 25 and 18%, respectively. The accuracy of the developed assay has been estimated using certified reference materials and by comparison of the results with those of an independent method. The method has been applied for Hg species determination in original samples of lake sediments and plankton.

  15. The King model for electrons in a finite-size ultracold plasma

    Energy Technology Data Exchange (ETDEWEB)

    Vrinceanu, D; Collins, L A [Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Balaraman, G S [School of Physics, Georgia Institute of Technology, Atlanta, GA 30332 (United States)

    2008-10-24

    A self-consistent model for a finite-size non-neutral ultracold plasma is obtained by extending a conventional model of globular star clusters. This model describes the dynamics of electrons at quasi-equilibrium trapped within the potential created by a cloud of stationary ions. A random sample of electron positions and velocities can be generated with the statistical properties defined by this model.

  16. New high temperature plasmas and sample introduction systems for analytical atomic emission and mass spectrometry

    International Nuclear Information System (INIS)

    Montaser, A.

    1993-01-01

    In this research, new high-temperature plasmas and new sample introduction systems are explored for rapid elemental and isotopic analysis of gases, solutions, and solids using mass spectrometry and atomic emission spectrometry. During the period January 1993--December 1993, emphasis was placed on (a) analytical investigations of atmospheric-pressure helium inductively coupled plasma (He ICP) that are suitable for atomization, excitation, and ionization of elements possessing high excitation and ionization energies; (b) simulation and computer modeling of plasma sources to predict their structure and fundamental and analytical properties without incurring the enormous cost of experimental studies; (c) spectrosopic imaging and diagnostic studies of high-temperature plasmas; (d) fundamental studies of He ICP discharges and argon-nitrogen plasma by high-resolution Fourier transform spectrometry; and (e) fundamental and analytical investigation of new, low-cost devices as sample introduction systems for atomic spectrometry and examination of new diagnostic techniques for probing aerosols. Only the most important achievements are included in this report to illustrate progress and obstacles. Detailed descriptions of the authors' investigations are outlined in the reprints and preprints that accompany this report. The technical progress expected next year is briefly described at the end of this report

  17. Quasi-energy of ultracold neutrons

    International Nuclear Information System (INIS)

    Frank, A.I.; Nosov, V.G.

    1992-01-01

    A solution is found to the problem of the propagation of a neutron beam transmitted through a periodically acting high-speed chopper. It is a generalization of the Moshinsky's problem of the evolution of a plane wave in the right half-space after an ideal absorber at the origin of coordinates has been instantaneously removed. The energy spectrum of transmitted neutrons is found to be discrete and corresponding to their quasi-energy. Interference of the states corresponding to different satellite lines leads to a complex spatial pattern with typical beats. A number of experiments with ultracold neutrons are suggested and discussed. 12 refs.; 1 fig

  18. Transfer coefficients in ultracold strongly coupled plasma

    Science.gov (United States)

    Bobrov, A. A.; Vorob'ev, V. S.; Zelener, B. V.

    2018-03-01

    We use both analytical and molecular dynamic methods for electron transfer coefficients in an ultracold plasma when its temperature is small and the coupling parameter characterizing the interaction of electrons and ions exceeds unity. For these conditions, we use the approach of nearest neighbor to determine the average electron (ion) diffusion coefficient and to calculate other electron transfer coefficients (viscosity and electrical and thermal conductivities). Molecular dynamics simulations produce electronic and ionic diffusion coefficients, confirming the reliability of these results. The results compare favorably with experimental and numerical data from earlier studies.

  19. Research using ultracold neutrons at the ILL

    International Nuclear Information System (INIS)

    Steyerl, A.

    1990-01-01

    In this talk I will make no effort to give an exhaustive, detailed description of the well-published results of recent work with ultracold neutrons (UCN) at the ILL. Instead, there will be a biased selection of some topics in which author happens to be most interested, though in some cases as a spectator from a considerable distance than as an actor. The selection includes the recent lifetime experiment using a Fomblin-coated bottle, the continuing search for an electric dipole moment of the neutron and some ideas on high precision neutron optics experiments

  20. Sampling and analysis plan for the former Atomic Energy Commission bus lot property

    International Nuclear Information System (INIS)

    Nielson, R.R.

    1998-07-01

    This sampling and analysis plan (SAP) presents the rationale and strategy for the sampling and analysis activities proposed in support of an initial investigation of the former Atomic Energy Commission (AEC) bus lot property currently owned by Battelle Memorial Institute. The purpose of the proposed sampling and analysis activity is to investigate the potential for contamination above established action levels. The SAP will provide defensible data of sufficient quality and quantity to support recommendations of whether any further action within the study area is warranted. To assist in preparing sampling plans and reports, the Washington State Department of Ecology (Ecology) has published Guidance on Sampling and Data Analysis Methods. To specifically address sampling plans for petroleum-contaminated sites, Ecology has also published Guidance for Remediation of Petroleum Contaminated Sites. Both documents were used as guidance in preparing this plan. In 1992, a soil sample was taken within the current study area as part of a project to remove two underground storage tanks (USTs) at Battelle's Sixth Street Warehouse Petroleum Dispensing Station (Section 1.3). The results showed that the sample contained elevated levels of total petroleum hydrocarbons (TPH) in the heavy distillate range. This current study was initiated in part as a result of that discovery. The following topics are considered: the historical background of the site, current site conditions, previous investigations performed at the site, an evaluation based on the available data, and the contaminants of potential concern (COPC)

  1. Sampling and analysis plan for the former Atomic Energy Commission bus lot property

    Energy Technology Data Exchange (ETDEWEB)

    Nielson, R.R.

    1998-07-01

    This sampling and analysis plan (SAP) presents the rationale and strategy for the sampling and analysis activities proposed in support of an initial investigation of the former Atomic Energy Commission (AEC) bus lot property currently owned by Battelle Memorial Institute. The purpose of the proposed sampling and analysis activity is to investigate the potential for contamination above established action levels. The SAP will provide defensible data of sufficient quality and quantity to support recommendations of whether any further action within the study area is warranted. To assist in preparing sampling plans and reports, the Washington State Department of Ecology (Ecology) has published Guidance on Sampling and Data Analysis Methods. To specifically address sampling plans for petroleum-contaminated sites, Ecology has also published Guidance for Remediation of Petroleum Contaminated Sites. Both documents were used as guidance in preparing this plan. In 1992, a soil sample was taken within the current study area as part of a project to remove two underground storage tanks (USTs) at Battelle`s Sixth Street Warehouse Petroleum Dispensing Station (Section 1.3). The results showed that the sample contained elevated levels of total petroleum hydrocarbons (TPH) in the heavy distillate range. This current study was initiated in part as a result of that discovery. The following topics are considered: the historical background of the site, current site conditions, previous investigations performed at the site, an evaluation based on the available data, and the contaminants of potential concern (COPC).

  2. The use of slurry sampling for the determination of manganese and copper in various samples by electrothermal atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Tokman, Nilgun

    2007-01-01

    Manganese and copper in multivitamin-mineral supplements and standard reference materials were determined by slurry sampling electrothermal atomic absorption spectrometry. Slurries were prepared in an aqueous solution containing Triton X-100. The effects of different parameters such as ratio of solid to liquid phase volume, total slurry volume and addition of Triton X-100 as a dispersant on the analytical results were investigated. The graphite furnace programs were optimized for slurry sampling depending on the analytes and their concentrations in the samples. The linear calibration method with aqueous standard solutions was used for the quantification. At optimum experimental conditions, R.S.D. values were below 5%. The analytes were determined in the limits of 95% confidence level with respect to certified values in coal and soil standard reference materials and to those found by wet-digestion in multivitamin-mineral supplements. Detection limits (3δ) for Mn and Cu were 0.10 μg L -1 and 1.82 μg L -1 for 10 μL coal standard reference material slurry, respectively

  3. THE STUDY OF HEAVY METAL FROM ENVIRONMENTAL SAMPLES BY ATOMIC TECHNIQUES

    Directory of Open Access Journals (Sweden)

    Ion V. POPESCU

    2011-05-01

    Full Text Available Using the Atomic Absorption Spectrometry (AAS and Energy Dispersive X-ray spectrometry (EDXRF techniques we analyzed the contents of heavy metals ( Cd, Cr, Ni, Pb, Ti, Sr, Co, Bi from eight wild mushrooms and soil substrate samples (48 samples of eight fungal species and 32 underlying soil samples, collected from ten forest sites of Dambovița County Romania. It was determined that the elements, especially heavy metals, in soil were characteristic of the acidic soils of the Romanian forest lands and are influenced by industrial pollution. Analytical possibilities of AAS and EDXRF analytical techniques have been compared and the heavy metal transfer from substrate to mushrooms has been studied. The coefficient of accumulation of essential and heavy metals has been calculated as well. Heavy metal contents of all analyzed mushrooms were generally higher than previously reported in literature.

  4. Energy landscape of all-atom protein-protein interactions revealed by multiscale enhanced sampling.

    Directory of Open Access Journals (Sweden)

    Kei Moritsugu

    2014-10-01

    Full Text Available Protein-protein interactions are regulated by a subtle balance of complicated atomic interactions and solvation at the interface. To understand such an elusive phenomenon, it is necessary to thoroughly survey the large configurational space from the stable complex structure to the dissociated states using the all-atom model in explicit solvent and to delineate the energy landscape of protein-protein interactions. In this study, we carried out a multiscale enhanced sampling (MSES simulation of the formation of a barnase-barstar complex, which is a protein complex characterized by an extraordinary tight and fast binding, to determine the energy landscape of atomistic protein-protein interactions. The MSES adopts a multicopy and multiscale scheme to enable for the enhanced sampling of the all-atom model of large proteins including explicit solvent. During the 100-ns MSES simulation of the barnase-barstar system, we observed the association-dissociation processes of the atomistic protein complex in solution several times, which contained not only the native complex structure but also fully non-native configurations. The sampled distributions suggest that a large variety of non-native states went downhill to the stable complex structure, like a fast folding on a funnel-like potential. This funnel landscape is attributed to dominant configurations in the early stage of the association process characterized by near-native orientations, which will accelerate the native inter-molecular interactions. These configurations are guided mostly by the shape complementarity between barnase and barstar, and lead to the fast formation of the final complex structure along the downhill energy landscape.

  5. Label-free quantification of Tacrolimus in biological samples by atomic force microscopy

    International Nuclear Information System (INIS)

    Menotta, Michele; Biagiotti, Sara; Streppa, Laura; Rossi, Luigia; Magnani, Mauro

    2015-01-01

    Highlights: • Tacrolimus is a potent immunosuppressant drug that has to be continually monitored. • We present an atomic force microscope approach for quantification of Tacrolimus in blood samples. • Detection and quantification have been successfully achieved. - Abstract: In the present paper we describe an atomic force microscopy (AFM)-based method for the quantitative analysis of FK506 (Tacrolimus) in whole blood (WB) samples. Current reference methods used to quantify this immunosuppressive drug are based on mass spectrometry. In addition, an immunoenzymatic assay (ELISA) has been developed and is widely used in clinic, even though it shows a small but consistent overestimation of the actual drug concentration when compared with the mass spectrometry method. The AFM biosensor presented herein utilises the endogen drug receptor, FKBP12, to quantify Tacrolimus levels. The biosensor was first assayed to detect the free drug in solution, and subsequently used for the detection of Tacrolimus in blood samples. The sensor was suitable to generate a dose–response curve in the full range of clinical drug monitoring. A comparison with the clinically tested ELISA assay is also reported

  6. Label-free quantification of Tacrolimus in biological samples by atomic force microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Menotta, Michele, E-mail: michele.menotta@uniurb.it [Department of Biomolecular Sciences, University of Urbino “Carlo Bo” via Saffi 2, Urbino (Italy); Biagiotti, Sara [Department of Biomolecular Sciences, University of Urbino “Carlo Bo” via Saffi 2, Urbino (Italy); Streppa, Laura [Physics Laboratory, CNRS-ENS, UMR 5672, Lyon (France); Cell and Molecular Biology Laboratory, CNRS-ENS Lyon, UMR 5239, IFR128, Lyon (France); Rossi, Luigia; Magnani, Mauro [Department of Biomolecular Sciences, University of Urbino “Carlo Bo” via Saffi 2, Urbino (Italy)

    2015-07-16

    Highlights: • Tacrolimus is a potent immunosuppressant drug that has to be continually monitored. • We present an atomic force microscope approach for quantification of Tacrolimus in blood samples. • Detection and quantification have been successfully achieved. - Abstract: In the present paper we describe an atomic force microscopy (AFM)-based method for the quantitative analysis of FK506 (Tacrolimus) in whole blood (WB) samples. Current reference methods used to quantify this immunosuppressive drug are based on mass spectrometry. In addition, an immunoenzymatic assay (ELISA) has been developed and is widely used in clinic, even though it shows a small but consistent overestimation of the actual drug concentration when compared with the mass spectrometry method. The AFM biosensor presented herein utilises the endogen drug receptor, FKBP12, to quantify Tacrolimus levels. The biosensor was first assayed to detect the free drug in solution, and subsequently used for the detection of Tacrolimus in blood samples. The sensor was suitable to generate a dose–response curve in the full range of clinical drug monitoring. A comparison with the clinically tested ELISA assay is also reported.

  7. High-precision multiband spectroscopy of ultracold fermions in a nonseparable optical lattice

    Science.gov (United States)

    Fläschner, Nick; Tarnowski, Matthias; Rem, Benno S.; Vogel, Dominik; Sengstock, Klaus; Weitenberg, Christof

    2018-05-01

    Spectroscopic tools are fundamental for the understanding of complex quantum systems. Here, we demonstrate high-precision multiband spectroscopy in a graphenelike lattice using ultracold fermionic atoms. From the measured band structure, we characterize the underlying lattice potential with a relative error of 1.2 ×10-3 . Such a precise characterization of complex lattice potentials is an important step towards precision measurements of quantum many-body systems. Furthermore, we explain the excitation strengths into different bands with a model and experimentally study their dependency on the symmetry of the perturbation operator. This insight suggests the excitation strengths as a suitable observable for interaction effects on the eigenstates.

  8. Using Three-Body Recombination to Extract Electron Temperatures of Ultracold Plasmas

    International Nuclear Information System (INIS)

    Fletcher, R. S.; Zhang, X. L.; Rolston, S. L.

    2007-01-01

    Three-body recombination, an important collisional process in plasmas, increases dramatically at low electron temperatures, with an accepted scaling of T e -9/2 . We measure three-body recombination in an ultracold neutral xenon plasma by detecting recombination-created Rydberg atoms using a microwave-ionization technique. With the accepted theory (expected to be applicable for weakly coupled plasmas) and our measured rates, we extract the plasma temperatures, which are in reasonable agreement with previous measurements early in the plasma lifetime. The resulting electron temperatures indicate that the plasma continues to cool to temperatures below 1 K

  9. Atomic absorption determination of metals in soils using ultrasonic sample preparation

    International Nuclear Information System (INIS)

    Chmilenko, F.A.; Smityuk, N.M.; Baklanov, A.N.

    2002-01-01

    It was shown that ultrasonic treatment accelerates sample preparation of soil extracts from chernozem into different solvents by a factor of 6 to 60. These extracts are used for the atomic absorption determination of soluble species of Cd, Co, Cr, Cu, Ni, Pb, and Zn. The optimum ultrasound parameters (frequency, intensity, and treatment time) were found for preparing soil extracts containing analytes in concentrations required in agrochemical procedures. Different extractants used to extract soluble heavy metals from soils of an ordinary chernozem type in agrochemical procedures using ultrasonic treatment were classified in accordance with the element nature [ru

  10. Determination of heavy metals in solid emission and immission samples using atomic absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fara, M.; Novak, F. [EGU Prague, PLC, Bichovice, Prague (Czechoslovakia)

    1995-12-01

    Both flame and electrothermal methods of atomic absorption spectroscopy (AAS) have been applied to the determination of Al, As, Be, Ca, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, TI, Se, V and Zn in emission and emission (deposition) samples decomposed in open PTFE test-tubes by individual fuming-off hydrofluoric, perchloroic and nitric acid. An alternative hydride technique was also used for As and Se determination and Hg was determined using a self-contained AAS analyzer. A graphite platform proved good to overcome non-spectral interferences in AAS-ETA. Methods developed were verified by reference materials (inc. NBS 1633a).

  11. Production and spectroscopy of ultracold YbRb{sup *} molecules

    Energy Technology Data Exchange (ETDEWEB)

    Nemitz, Nils

    2008-11-15

    This thesis describes the formation of electronically excited but translationally cold molecules formed from rubidium atoms and two isotopes of ytterbium ({sup 176}Yb and {sup 174}Yb) by means of photoassociation. The experiments were performed in a combined MOT with 10{sup 9} rubidium atoms and 2.10{sup 6} ytterbium atoms at temperatures of less than 1 mK. Photoassociation lines were found by trap loss spectroscopy throughout a wavelength range of 2 nm near the 795 nm D1 transition in rubidium. The majority of lines belong to two vibrational series in the excited YbRb{sup *} molecule, converging on a system of a ground state ytterbium atom and an excited rubidium atom. The strong variation of line strength between different vibrational lines is explained through the Franck-Condon principle. An improved version of the Leroy-Bernstein equation was used to extract the leading dispersion coefficient of the potential from the vibrational progression. Most of the observed lines show a resolved rotational structure as expected from a basic quantum mechanical model. The series terminates with the third or forth rotational component due to the ground state centrifugal barrier.The measured rotational constants agree very well with calculations based on the C{sub 6} coefficient. The discovery of a splitting of the rotational components into subcomponents indicates an uncommon angular momentum coupling described by Hund's case. Variations in the depth of the subcomponents indicates a similar splitting in the ground state, with the energies of the substates based on the alignment of the rubidium atom's magnetic dipole moment relative to the angular momentum carried by an approaching ytterbium atom. This creates an additional ground state barrier, partially suppressing some of the subcomponents. Using a rate equation model developed for this purpose, a maximum formation rate of 2.5.10{sup 6} molecules per second was calculated over the volume of the entire trap. The

  12. Production and spectroscopy of ultracold YbRb* molecules

    International Nuclear Information System (INIS)

    Nemitz, Nils

    2008-11-01

    This thesis describes the formation of electronically excited but translationally cold molecules formed from rubidium atoms and two isotopes of ytterbium ( 176 Yb and 174 Yb) by means of photoassociation. The experiments were performed in a combined MOT with 10 9 rubidium atoms and 2.10 6 ytterbium atoms at temperatures of less than 1 mK. Photoassociation lines were found by trap loss spectroscopy throughout a wavelength range of 2 nm near the 795 nm D1 transition in rubidium. The majority of lines belong to two vibrational series in the excited YbRb * molecule, converging on a system of a ground state ytterbium atom and an excited rubidium atom. The strong variation of line strength between different vibrational lines is explained through the Franck-Condon principle. An improved version of the Leroy-Bernstein equation was used to extract the leading dispersion coefficient of the potential from the vibrational progression. Most of the observed lines show a resolved rotational structure as expected from a basic quantum mechanical model. The series terminates with the third or forth rotational component due to the ground state centrifugal barrier.The measured rotational constants agree very well with calculations based on the C 6 coefficient. The discovery of a splitting of the rotational components into subcomponents indicates an uncommon angular momentum coupling described by Hund's case. Variations in the depth of the subcomponents indicates a similar splitting in the ground state, with the energies of the substates based on the alignment of the rubidium atom's magnetic dipole moment relative to the angular momentum carried by an approaching ytterbium atom. This creates an additional ground state barrier, partially suppressing some of the subcomponents. Using a rate equation model developed for this purpose, a maximum formation rate of 2.5.10 6 molecules per second was calculated over the volume of the entire trap. The work presented here is an important step on

  13. Physics with Ultracold and Thermal Neutron Beams

    International Nuclear Information System (INIS)

    None

    2004-01-01

    The final report is broken into 5 segments, reflecting research conclusions reached during specific time periods: 1991-1997, 1997-1999, 1999-2000, 2000-2001, and 2001-2002. The first part of the work reported was carried out at the 2 Mw research reactor of the Rhode Island Nuclaer Science Center (RJNSC). Chosen for study was the slow phase separation in mixtures of oil and water in the presence of a surfactant, and the structural features of an oil layer during the slow build-up from the gas phase. The results of these measurements, as well as studies of the capillary wave properties of oil/surfactant/water interfaces are described. The second part of the work was performed at the neutron reflection facilities of the Intennse Pulsed Neutron Source at Argonne and of the NBSR reactor at NIST. At Argonne, the uniaxial magnetic order of an Fe/CR superlattice was investigated, while the experiments at NIST studied the swelling behavior of ordered thin films of diblock copolymers when they were exposed to solvent vapors. The third part of the work was concerned with the storage properties of ultracold neturons in a trap. New experiments on spectral evolution during storage, using the UCN source of the Institut Laue-Langevin were able to be run. Subsequent periods focussed on the ultracold neutrons work, spin valve multilayer systems, and pseudo-partial wetting

  14. Geometric phase effects in ultracold chemistry

    Science.gov (United States)

    Hazra, Jisha; Naduvalath, Balakrishnan; Kendrick, Brian K.

    2016-05-01

    In molecules, the geometric phase, also known as Berry's phase, originates from the adiabatic transport of the electronic wavefunction when the nuclei follow a closed path encircling a conical intersection between two electronic potential energy surfaces. It is demonstrated that the inclusion of the geometric phase has an important effect on ultracold chemical reaction rates. The effect appears in rotationally and vibrationally resolved integral cross sections as well as cross sections summed over all product quantum states. It arises from interference between scattering amplitudes of two reaction pathways: a direct path and a looping path that encircle the conical intersection between the two lowest adiabatic electronic potential energy surfaces. Illustrative results are presented for the O+ OH --> H+ O2 reaction and for hydrogen exchange in H+ H2 and D+HD reactions. It is also qualitatively demonstrated that the geometric phase effect can be modulated by applying an external electric field allowing the possibility of quantum control of chemical reactions in the ultracold regime. This work was supported in part by NSF Grant PHY-1505557 (N.B.) and ARO MURI Grant No. W911NF-12-1-0476 (N.B.).

  15. Thermalization and Prethermalization in an ultracold Bose Gas

    International Nuclear Information System (INIS)

    Kuhnert, M.

    2013-01-01

    Atom chips consist of microscopic current carrying structures that generate magnetic trapping potentials for ultracold neutral atoms. These atom chips provide a high design flexibility of possible trap geometries, making the creation of highly anisotropic trapping potentials feasible. The resulting magnetic traps are characterized by a high isolation from the environment and are used to create degenerate, one-dimensional (1d) Bose gases. On typical experimental time scales, these 1d Bose gases can be described as practically closed quantum many-body systems. By applying a rapid quantum quench, the many-body system is brought out of thermal equilibrium and the resulting dynamics are studied via the statistical properties of matter-wave interference measurements. These measured quantum statistical distributions reveal that thermalization of this effectively integrable 1d Bose gas happens in a two-step process. First, the system rapidly dephases to a prethermalized state, characterized by thermal-like correlation properties, which are still distinctly different from the true thermal equilibrium state. Second, on a much longer time scale, the measured distribution functions indicate a further decay to the true thermal equilibrium state. Furthermore, by studying a highly non-equilibrium system via matter-wave interferometry, the underlying multimode dynamics, characterizing one-dimensional quantum systems, are revealed. This thesis shows that these dynamics are essential in establishing the prethermalized state and that its properties are defined by the quantum shot noise of the splitting process. In conclusion, this work aims at improving the understanding of quantum thermalization processes in integrable and nearly-integrable systems in the 1d and 1d/3d crossover regimes. Apparently, the general paths to thermal equilibrium in nearly-integrable systems are indirect and complex. This work provides an in depth experimental study of the relaxation dynamics of a highly

  16. Building one molecule from a reservoir of two atoms.

    Science.gov (United States)

    Liu, L R; Hood, J D; Yu, Y; Zhang, J T; Hutzler, N R; Rosenband, T; Ni, K-K

    2018-05-25

    Chemical reactions typically proceed via stochastic encounters between reactants. Going beyond this paradigm, we combined exactly two atoms in a single, controlled reaction. The experimental apparatus traps two individual laser-cooled atoms [one sodium (Na) and one cesium (Cs)] in separate optical tweezers and then merges them into one optical dipole trap. Subsequently, photoassociation forms an excited-state NaCs molecule. The discovery of previously unseen resonances near the molecular dissociation threshold and measurement of collision rates are enabled by the tightly trapped ultracold sample of atoms. As laser-cooling and trapping capabilities are extended to more elements, the technique will enable the study of more diverse, and eventually more complex, molecules in an isolated environment, as well as synthesis of designer molecules for qubits. Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

  17. A compound parabolic concentrator as an ultracold neutron spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Hickerson, K.P., E-mail: hickerson@gmail.com; Filippone, B.W., E-mail: bradf@caltech.edu

    2013-09-01

    The design principles of nonimaging optics are applied to ultracold neutrons (UCN). In particular a vertical compound parabolic concentrator (CPC) that efficiently redirects UCN vertically into a bounded spatial volume where they have a maximum energy mga that depends only on the initial phase space cross sectional area πa{sup 2} creates a spectrometer which can be applied to neutron lifetime and gravitational quantum state experiments. -- Highlights: • Nonimaging optics is applied to ultracold neutrons. • A novel ultracold neutron spectrometer is discussed. • New uses may include a neutron lifetime experiment.

  18. A compound parabolic concentrator as an ultracold neutron spectrometer

    International Nuclear Information System (INIS)

    Hickerson, K.P.; Filippone, B.W.

    2013-01-01

    The design principles of nonimaging optics are applied to ultracold neutrons (UCN). In particular a vertical compound parabolic concentrator (CPC) that efficiently redirects UCN vertically into a bounded spatial volume where they have a maximum energy mga that depends only on the initial phase space cross sectional area πa 2 creates a spectrometer which can be applied to neutron lifetime and gravitational quantum state experiments. -- Highlights: • Nonimaging optics is applied to ultracold neutrons. • A novel ultracold neutron spectrometer is discussed. • New uses may include a neutron lifetime experiment

  19. From Nanoscale Systems to Ultracold Atoms and Molecules, and Back

    Science.gov (United States)

    2016-08-05

    Francesco Bariani 0.18 Swati Singh 0.71 Steven Steinke 0.37 1.26 3 PERCENT_SUPPORTEDNAME FTE Equivalent: Total Number: National Academy Member...doi: 10.1103/PhysRevLett.108.210403 H. Seok, L. Buchmann, S. Singh , S. Steinke, P. Meystre. Generation of mechanical squeezing via magnetic dipoles...10.1126/science.1208322 S. Singh , S. Steinke, M. Tasgin, P. Meystre, K. Schwab, M. Vengalattore. Quantum-measurement backaction from a Bose-Einstein

  20. [Detecting Thallium in Water Samples using Dispersive Liquid Phase Microextraction-Graphite Furnace Atomic Absorption Spectroscopy].

    Science.gov (United States)

    Zhu, Jing; Li, Yan; Zheng, Bo; Tang, Wei; Chen, Xiao; Zou, Xiao-li

    2015-11-01

    To develope a method of solvent demulsification dispersive liquid phase microextraction (SD-DLPME) based on ion association reaction coupled with graphite furnace atomic absorption spectroscopy (GFAAS) for detecting thallium in water samples. Methods Thallium ion in water samples was oxidized to Tl(III) with bromine water, which reacted with Cl- to form TlCl4-. The ionic associated compound with trioctylamine was obtained and extracted. DLPME was completed with ethanol as dispersive solvent. The separation of aqueous and organic phase was achieved by injecting into demulsification solvent without centrifugation. The extractant was collected and injected into GFAAS for analysis. With palladium colloid as matrix modifier, a two step drying and ashing temperature programming process was applied for high precision and sensitivity. The linear range was 0.05-2.0 microg/L, with a detection limit of 0.011 microg/L. The relative standard derivation (RSD) for detecting Tl in spiked water sample was 9.9%. The spiked recoveries of water samples ranged from 94.0% to 103.0%. The method is simple, sensitive and suitable for batch analysis of Tl in water samples.

  1. Cold and ultracold molecules: science, technology and applications

    International Nuclear Information System (INIS)

    Carr, Lincoln D; DeMille, David; Krems, Roman V; Ye Jun

    2009-01-01

    This paper presents a review of the current state of the art in the research field of cold and ultracold molecules. It serves as an introduction to the focus issue of New Journal of Physics on Cold and Ultracold Molecules and describes new prospects for fundamental research and technological development. Cold and ultracold molecules may revolutionize physical chemistry and few-body physics, provide techniques for probing new states of quantum matter, allow for precision measurements of both fundamental and applied interest, and enable quantum simulations of condensed-matter phenomena. Ultracold molecules offer promising applications such as new platforms for quantum computing, precise control of molecular dynamics, nanolithography and Bose-enhanced chemistry. The discussion is based on recent experimental and theoretical work and concludes with a summary of anticipated future directions and open questions in this rapidly expanding research field.

  2. Rapid prototyping of versatile atom chips for atom interferometry applications.

    Science.gov (United States)

    Kasch, Brian; Squires, Matthew; Olson, Spencer; Kroese, Bethany; Imhof, Eric; Kohn, Rudolph; Stuhl, Benjamin; Schramm, Stacy; Stickney, James

    2016-05-01

    We present recent advances in the manipulation of ultracold atoms with ex-vacuo atom chips (i.e. atom chips that are not inside to the UHV chamber). Details will be presented of an experimental system that allows direct bonded copper (DBC) atom chips to be removed and replaced in minutes, requiring minimal re-optimization of parameters. This system has been used to create Bose-Einstein condensates, as well as magnetic waveguides with precisely tunable axial parameters, allowing double wells, pure harmonic confinement, and modified harmonic traps. We investigate the effects of higher order magnetic field contributions to the waveguide, and the implications for confined atom interferometry.

  3. Determination of cobalt in biological samples by line-source and high-resolution continuum source graphite furnace atomic absorption spectrometry using solid sampling or alkaline treatment

    International Nuclear Information System (INIS)

    Ribeiro, Anderson Schwingel; Vieira, Mariana Antunes; Furtado da Silva, Alessandra; Borges, Daniel L. Gallindo; Welz, Bernhard; Heitmann, Uwe; Curtius, Adilson Jose

    2005-01-01

    Two procedures for the determination of Co in biological samples by graphite furnace atomic absorption spectrometry (GF AAS) were compared: solid sampling (SS) and alkaline treatment with tetramethylammonium hydroxide (TMAH) using two different instruments for the investigation: a conventional line-source (LS) atomic absorption spectrometer and a prototype high-resolution continuum source atomic absorption spectrometer. For the direct introduction of the solid samples, certified reference materials (CRM) were ground to a particle size ≤50 μm. Alkaline treatment was carried out by placing about 250 mg of the sample in polypropylene flasks, adding 2 mL of 25% m/v tetramethylammonium hydroxide and de-ionized water. Due to its unique capacity of providing a 3-D spectral plot, a high-resolution continuum source (HR-CS) graphite furnace atomic absorption spectrometry was used as a tool to evaluate potential spectral interferences, including background absorption for both sample introduction procedures, revealing that a continuous background preceded the atomic signal for pyrolysis temperatures lower than 700 deg. C. Molecular absorption bands with pronounced rotational fine structure appeared for atomization temperatures >1800 deg. C probably as a consequence of the formation of PO. After optimization had been carried out using high resolution continuum source atomic absorption spectrometry, the optimized conditions were adopted also for line-source atomic absorption spectrometry. Six biological certified reference materials were analyzed, with calibration against aqueous standards, resulting in agreement with the certified values (according to the t-test for a 95% confidence level) and in detection limits as low as 5 ng g -1

  4. Study on the application of electrothermal atomization atomic absorption spectrometry for the determination of metallic Cu, Pb, Zn, Cd traces in sea water samples

    International Nuclear Information System (INIS)

    Nguyen Thi Kim Dung; Doan Thanh Son; Tran Thi Ngoc Diep

    2004-01-01

    The trace amount of some heavy metallic elements (Cu, Zn, Pb, Cd) in sea water samples were determined directly (without separation) and quantitatively by using Electro-Thermal Atomization Atomic Absorption Spectrometry (ETA-AAS). The effect of mainly major constituents such as Na, Mg, Ca, K, and the mutual effect of the trace elements, which were present in the matrix on the absorption intensity of each analyzed element was studied. The adding of a certain chemical modification for each trace element was also investigated in order to eliminate the overall effect of the background during the pyrolysis and atomization. The sea water sample after fitrating through a membrane with 0.45 μm-hole size was injected in to the graphite tube via an autosampler (MPE50). The absorption intensity of each element was then measured on the VARIO-6 under the optimum parameters for spectrometer such as: maximum wavelength, current of hollow cathode lamp, and that for graphite furnace such as dry temperature, pyrolysis temperature, atomization temperature, ect. The analytical procedures were set-up and applied for the determination of these above mentioned elements in the synthesized sea water sample and in the real sea water samples with high precision and accuracy. (author)

  5. An endoscopic detector for ultracold neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Goeltl, L.; Fertl, M.; Kirch, K. [Paul Scherrer Institute, Laboratory for Particle Physics, Villigen-PSI (Switzerland); Institute for Particle Physics, Zuerich (Switzerland); Chowdhuri, Z.; Henneck, R.; Lauss, B.; Mtchedlishvili, A.; Schmidt-Wellenburg, P.; Zsigmond, G. [Paul Scherrer Institute, Laboratory for Particle Physics, Villigen-PSI (Switzerland); Gray, F. [Regis University, Denver, CO (United States); Lefort, T. [Universite de Caen, CNRS/IN2P3, Laboratoire de Physique Corpusculaire, Caen (France)

    2013-01-15

    A new versatile detector for ultracold neutrons (UCN) has been built and operated which combines multi-pixel photon counters and GS10 lithium-doped scintillators. Such detectors can be very small and can be used to monitor UCN inside storage vessels or guides with negligible influence (of order 10{sup -6}) on the UCN intensity itself. We have shown that such detectors can be used in a very harsh radiation environment of up to 200Gy/h via the addition of a 4m long quartz light guide in order to place the radiation-sensitive photon counters outside the hot zone. Additionally we have measured the UCN storage times in situ in this harsh environment. (orig.)

  6. A multilayer surface detector for ultracold neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhehui, E-mail: zwang@lanl.gov [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Hoffbauer, M.A.; Morris, C.L. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Callahan, N.B.; Adamek, E.R. [Indiana University, Bloomington, IN 47405 (United States); Bacon, J.D. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Blatnik, M. [Cleveland State University, Cleveland, OH 44115 (United States); Brandt, A.E. [North Carolina State University, Raleigh, NC 27695 (United States); Broussard, L.J.; Clayton, S.M. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Cude-Woods, C. [North Carolina State University, Raleigh, NC 27695 (United States); Currie, S. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Dees, E.B. [North Carolina State University, Raleigh, NC 27695 (United States); Ding, X. [Virginia Polytechnic Institute and State University, Blacksburg, VA 24061 (United States); Gao, J. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Gray, F.E. [Regis University, Denver, CO 80221 (United States); Hickerson, K.P. [University of California Los Angeles, Los Angeles, CA 90095 (United States); Holley, A.T. [Tennessee Technological University, Cookeville, TN 38505 (United States); Ito, T.M. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Liu, C.-Y. [Indiana University, Bloomington, IN 47405 (United States); and others

    2015-10-21

    A multilayer surface detector for ultracold neutrons (UCNs) is described. The top {sup 10}B layer is exposed to vacuum and directly captures UCNs. The ZnS:Ag layer beneath the {sup 10}B layer is a few microns thick, which is sufficient to detect the charged particles from the {sup 10}B(n,α){sup 7}Li neutron-capture reaction, while thin enough that ample light due to α and {sup 7}Li escapes for detection by photomultiplier tubes. A 100-nm thick {sup 10}B layer gives high UCN detection efficiency, as determined by the mean UCN kinetic energy, detector materials, and other parameters. Low background, including negligible sensitivity to ambient neutrons, has also been verified through pulse-shape analysis and comparison with other existing {sup 3}He and {sup 10}B detectors. This type of detector has been configured in different ways for UCN flux monitoring, development of UCN guides and neutron lifetime research.

  7. Cold atoms close to surfaces

    DEFF Research Database (Denmark)

    Krüger, Peter; Wildermuth, Stephan; Hofferberth, Sebastian

    2005-01-01

    Microscopic atom optical devices integrated on atom chips allow to precisely control and manipulate ultra-cold (T atoms and Bose-Einstein condensates (BECs) close to surfaces. The relevant energy scale of a BEC is extremely small (down to ... be utilized as a sensor for variations of the potential energy of the atoms close to the surface. Here we describe how to use trapped atoms as a measurement device and analyze the performance and flexibility of the field sensor. We demonstrate microscopic magnetic imaging with simultaneous high spatial...

  8. Precision spectroscopy with ultracold {sup 87}Rb{sub 2} triplet molecules

    Energy Technology Data Exchange (ETDEWEB)

    Strauss, Christoph

    2011-10-19

    In this thesis I report precision spectroscopy with ultracold {sup 87}Rb{sub 2} triplet molecules where we use lasers to couple the states in different molecular potentials. We study in detail states of the a {sup 3} sum {sup +}{sub u} and (1) {sup 3} sum {sup +}{sub g} potentials. These states are of great importance for transferring weakly bound molecules to the ro-vibrational triplet ground state via states of the excited potential. As most experiments start from molecules in their X {sup 1} sum {sup +}{sub g} ground state, the triplet states were hard to access via dipole transitions and remained largely unexplored. The measurements presented in this thesis are the first detailed study of diatomic {sup 87}Rb{sub 2} molecules in these states. Our experiments start with an ultracold cloud of {sup 87}Rb atoms. We then load this cloud into an optical lattice where we use a magnetic Feshbach resonance at 1007.4 G to perform a Feshbach association. After we have removed all unbound atoms, we end up with a pure sample of weakly bound Feshbach molecules inside the optical lattice. The optical lattice prevents these molecules from colliding with each other which results in molecular lifetimes on the order of a few hundred milliseconds. In the first set of experiments, we use a laser coupling the Feshbach state to the excited (1) {sup 3} sum {sup +}{sub g} triplet state to map out its low-lying vibrational (v = 0.. 15), rotational, hyperfine, and Zeeman structure. The experimental results are in good agreement with calculations done by Marius Lysebo and Prof. Leif Veseth. We then map out in detail the vibrational, rotational, hyperfine, and Zeeman structure of the a {sup 3} sum {sup +}{sub u} triplet ground state using dark state spectroscopy with levels in the (1) {sup 3} sum {sup +}{sub g} potential as an intermediate state. In this scheme we are able to access molecules in triplet states because our Feshbach state has strong triplet character. Interestingly, it

  9. Precision spectroscopy with ultracold {sup 87}Rb{sub 2} triplet molecules

    Energy Technology Data Exchange (ETDEWEB)

    Strauss, Christoph

    2011-10-19

    In this thesis I report precision spectroscopy with ultracold {sup 87}Rb{sub 2} triplet molecules where we use lasers to couple the states in different molecular potentials. We study in detail states of the a {sup 3} sum {sup +}{sub u} and (1) {sup 3} sum {sup +}{sub g} potentials. These states are of great importance for transferring weakly bound molecules to the ro-vibrational triplet ground state via states of the excited potential. As most experiments start from molecules in their X {sup 1} sum {sup +}{sub g} ground state, the triplet states were hard to access via dipole transitions and remained largely unexplored. The measurements presented in this thesis are the first detailed study of diatomic {sup 87}Rb{sub 2} molecules in these states. Our experiments start with an ultracold cloud of {sup 87}Rb atoms. We then load this cloud into an optical lattice where we use a magnetic Feshbach resonance at 1007.4 G to perform a Feshbach association. After we have removed all unbound atoms, we end up with a pure sample of weakly bound Feshbach molecules inside the optical lattice. The optical lattice prevents these molecules from colliding with each other which results in molecular lifetimes on the order of a few hundred milliseconds. In the first set of experiments, we use a laser coupling the Feshbach state to the excited (1) {sup 3} sum {sup +}{sub g} triplet state to map out its low-lying vibrational (v = 0.. 15), rotational, hyperfine, and Zeeman structure. The experimental results are in good agreement with calculations done by Marius Lysebo and Prof. Leif Veseth. We then map out in detail the vibrational, rotational, hyperfine, and Zeeman structure of the a {sup 3} sum {sup +}{sub u} triplet ground state using dark state spectroscopy with levels in the (1) {sup 3} sum {sup +}{sub g} potential as an intermediate state. In this scheme we are able to access molecules in triplet states because our Feshbach state has strong triplet character. Interestingly, it

  10. Role of Feshbach resonances in enhancing the production of deeply bound ultracold LiRb molecules with laser pulses

    Science.gov (United States)

    Gacesa, Marko; Ghosal, Subhas; Côté, Robin

    2010-03-01

    We investigate the possibility of forming deeply bound LiRb molecules in a two-color photoassociation experiment. Ultracold ^6Li and ^87Rb atoms colliding in the vicinity of a magnetic Feshbach resonance are photoassociated into an excited electronic state. A wavepacket is then formed by exciting a few vibrational levels of the excited state and allowed to propagate. We calculate the time-dependent overlaps between the wave packet and the lowest vibrational levels of the ground state. After the optimal overlap is obtained we use the second laser pulse to dump the wave packet and efficiently populate the deeply bound ro-vibrational levels of ^6Li^87Rb in the ground state. The resulting combination of Feshbach-optimized photoassociation (FOPA) with the time-dependent pump-dump approach will produce a large number of stable ultracold molecules in the ground state. This technique is general and applicable to other systems.

  11. Sensitivity and accuracy of atomic absorption spectrophotometry for trace elements in marine biological samples

    International Nuclear Information System (INIS)

    Fukai, R.; Oregioni, B.

    1976-01-01

    During the course of 1974-75 atomic absorption spectrophotometry (AAS) has been used extensively in our laboratory for measuring various trace elements in marine biological materials in order to conduct homogeneity tests on the intercalibration samples for trace metal analysis as well as to obtain baseline data for trace elements in various kinds of marine organisms collected from different locations in the Mediterranean Sea. Several series of test experiments have been conducted on the current methodology in use in our laboratory to ensure satisfactory analytical performance in measuring a number of trace elements for which analytical problems have not completely been solved. Sensitivities of the techniques used were repeatedly checked for various elements and the accuracy of the analyses were always critically evaluated by analyzing standard reference materials. The results of these test experiments have uncovered critical points relevant to the application of the AAS to routine analysis

  12. Column preconcentration and electrothermal atomic absorption spectrometric determination of rhodium in some food and standard samples.

    Science.gov (United States)

    Taher, Mohammad Ali; Pourmohammad, Fatemeh; Fazelirad, Hamid

    2015-12-01

    In the present work, an electrothermal atomic absorption spectrometric method has been developed for the determination of ultra-trace amounts of rhodium after adsorption of its 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol/tetraphenylborate ion associated complex at the surface of alumina. Several factors affecting the extraction efficiency such as the pH, type of eluent, sample and eluent flow rates, sorption capacity of alumina and sample volume were investigated and optimized. The relative standard deviation for eight measurements of 0.1 ng/mL of rhodium was ±6.3%. In this method, the detection limit was 0.003 ng/mL in the original solution. The sorption capacity of alumina and the linear range for Rh(III) were evaluated as 0.8 mg/g and 0.015-0.45 ng/mL in the original solution, respectively. The proposed method was successfully applied for the extraction and determination of rhodium content in some food and standard samples with high recovery values. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Liquid sample introduction in inductively coupled plasma atomic emission and mass spectrometry — Critical review

    Energy Technology Data Exchange (ETDEWEB)

    Bings, N.H., E-mail: bings@uni-mainz.de; Orlandini von Niessen, J.O.; Schaper, J.N.

    2014-10-01

    Inductively coupled plasma optical emission spectroscopy (ICP-OES) and mass spectrometry (ICP-MS) can be considered as the most important tools in inorganic analytical chemistry. Huge progress has been made since the first analytical applications of the ICP. More stable RF generators, improved spectrometers and detection systems were designed along with the achievements gained from advanced microelectronics, leading to overall greatly improved analytical performance of such instruments. In contrast, for the vast majority of cases liquid sample introduction is still based on the pneumatic principle as described in the late 19th century. High flow pneumatic nebulizers typically demand the use of spray chambers as “aerosol filters” in order to match the prerequisites of an ICP. By this, only a small fraction of the nebulized sample actually contributes to the measured signal. Hence, the development of micronebulizers was brought forward. Those systems produce fine aerosols at low sample uptake rates, but they are even more prone for blocking or clogging than conventional systems in the case of solutions containing a significant amount of total dissolved solids (TDS). Despite the high number of publications devoted to liquid sample introduction, it is still considered the Achilles' heel of atomic spectrometry and it is well accepted, that the technology used for liquid sample introduction is still far from ideal, even when applying state-of-the-art systems. Therefore, this review is devoted to offer an update on developments in the field liquid sample introduction that had been reported until the year 2013. The most recent and noteworthy contributions to this field are discussed, trends are highlighted and future directions are outlined. The first part of this review provides a brief overview on theoretical considerations regarding conventional pneumatic nebulization, the fundamentals on aerosol generation and discusses characteristics of aerosols ideally

  14. Liquid sample introduction in inductively coupled plasma atomic emission and mass spectrometry — Critical review

    International Nuclear Information System (INIS)

    Bings, N.H.; Orlandini von Niessen, J.O.; Schaper, J.N.

    2014-01-01

    Inductively coupled plasma optical emission spectroscopy (ICP-OES) and mass spectrometry (ICP-MS) can be considered as the most important tools in inorganic analytical chemistry. Huge progress has been made since the first analytical applications of the ICP. More stable RF generators, improved spectrometers and detection systems were designed along with the achievements gained from advanced microelectronics, leading to overall greatly improved analytical performance of such instruments. In contrast, for the vast majority of cases liquid sample introduction is still based on the pneumatic principle as described in the late 19th century. High flow pneumatic nebulizers typically demand the use of spray chambers as “aerosol filters” in order to match the prerequisites of an ICP. By this, only a small fraction of the nebulized sample actually contributes to the measured signal. Hence, the development of micronebulizers was brought forward. Those systems produce fine aerosols at low sample uptake rates, but they are even more prone for blocking or clogging than conventional systems in the case of solutions containing a significant amount of total dissolved solids (TDS). Despite the high number of publications devoted to liquid sample introduction, it is still considered the Achilles' heel of atomic spectrometry and it is well accepted, that the technology used for liquid sample introduction is still far from ideal, even when applying state-of-the-art systems. Therefore, this review is devoted to offer an update on developments in the field liquid sample introduction that had been reported until the year 2013. The most recent and noteworthy contributions to this field are discussed, trends are highlighted and future directions are outlined. The first part of this review provides a brief overview on theoretical considerations regarding conventional pneumatic nebulization, the fundamentals on aerosol generation and discusses characteristics of aerosols ideally

  15. Speciation of mercury in fish samples by flow injection catalytic cold vapour atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Yanlin [NanoScience and Sensor Technology Research Group, School of Applied Sciences and Engineering, Monash University, Churchill, Victoria 3842 (Australia); Adeloju, Samuel B., E-mail: Sam.Adeloju@monash.edu [NanoScience and Sensor Technology Research Group, School of Applied Sciences and Engineering, Monash University, Churchill, Victoria 3842 (Australia)

    2012-04-06

    Highlights: Black-Right-Pointing-Pointer Successful speciation of inorganic and organic Hg with Fe{sup 3+}, Cu{sup 2+} and thiourea as catalysts. Black-Right-Pointing-Pointer Best sensitivity enhancement and similar sensitivity for MeHg and Hg{sup 2+} with Fe{sup 3+}. Black-Right-Pointing-Pointer Successful use of Hg{sup 2+} as the primary standard for quantification of inorganic and total-Hg. Black-Right-Pointing-Pointer Quantitative extraction of Hg and MeHg with 2 M HCl which contained thiourea. Black-Right-Pointing-Pointer Integration with FIA for rapid analysis with a sample throughput of 180 h{sup -1}. - Abstract: A rapid flow injection catalytic cold vapour atomic absorption spectrometric (FI-CCV-AAS) method is described for speciation and determination of mercury in biological samples. Varying concentrations of NaBH{sub 4} were employed for mercury vapour generation from inorganic and mixture of inorganic and organic (total) Hg. The presence of Fe{sup 3+}, Cu{sup 2+} and thiourea had catalytic effect on mercury vapour generation from methylmercury (MeHg) and, when together, Cu{sup 2+} and thiourea had synergistic catalytic effect on the vapour generation. Of the two metal ions, Fe{sup 3+} gave the best sensitivity enhancement, achieving the same sensitivity for MeHg and inorganic Hg{sup 2+}. Due to similarity of resulting sensitivity, Hg{sup 2+} was used successfully as a primary standard for quantification of inorganic and total Hg. The catalysis was homogeneous in nature, and it was assumed that the breaking of the C-Hg bond was facilitated by the delocalization of the 5d electron pairs in Hg atom. The extraction of MeHg and inorganic mercury (In-Hg) in fish samples were achieved quantitatively with hydrochloric acid in the presence of thiourea and determined by FI-CCV-AAS. The application of the method to the quantification of mercury species in a fish liver reference material DOLT-4 gave 91.5% and 102.3% recoveries for total and methyl mercury

  16. Speciation of mercury in fish samples by flow injection catalytic cold vapour atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Zhang Yanlin; Adeloju, Samuel B.

    2012-01-01

    Highlights: ► Successful speciation of inorganic and organic Hg with Fe 3+ , Cu 2+ and thiourea as catalysts. ► Best sensitivity enhancement and similar sensitivity for MeHg and Hg 2+ with Fe 3+ . ► Successful use of Hg 2+ as the primary standard for quantification of inorganic and total-Hg. ► Quantitative extraction of Hg and MeHg with 2 M HCl which contained thiourea. ► Integration with FIA for rapid analysis with a sample throughput of 180 h −1 . - Abstract: A rapid flow injection catalytic cold vapour atomic absorption spectrometric (FI-CCV-AAS) method is described for speciation and determination of mercury in biological samples. Varying concentrations of NaBH 4 were employed for mercury vapour generation from inorganic and mixture of inorganic and organic (total) Hg. The presence of Fe 3+ , Cu 2+ and thiourea had catalytic effect on mercury vapour generation from methylmercury (MeHg) and, when together, Cu 2+ and thiourea had synergistic catalytic effect on the vapour generation. Of the two metal ions, Fe 3+ gave the best sensitivity enhancement, achieving the same sensitivity for MeHg and inorganic Hg 2+ . Due to similarity of resulting sensitivity, Hg 2+ was used successfully as a primary standard for quantification of inorganic and total Hg. The catalysis was homogeneous in nature, and it was assumed that the breaking of the C-Hg bond was facilitated by the delocalization of the 5d electron pairs in Hg atom. The extraction of MeHg and inorganic mercury (In-Hg) in fish samples were achieved quantitatively with hydrochloric acid in the presence of thiourea and determined by FI-CCV-AAS. The application of the method to the quantification of mercury species in a fish liver reference material DOLT-4 gave 91.5% and 102.3% recoveries for total and methyl mercury, respectively. The use of flow injection enabled rapid analysis with a sample throughput of 180 h −1 .

  17. Preparation of water and ice samples for 39Ar dating by atom trap trace analysis (ATTA)

    Science.gov (United States)

    Schwefel, R.; Reichel, T.; Aeschbach-Hertig, W.; Wagenbach, D.

    2012-04-01

    Atom trap trace analysis (ATTA) is a new and promising method to measure very rare noble gas radioisotopes in the environment. The applicability of this method for the dating of very old groundwater with 81Kr has already been demonstrated [1]. Recent developments now show its feasibility also for the analysis of 39Ar [2,3], which is an ideal dating tracer for the age range between 50 and 1000 years. This range is of interest in the fields of hydro(geo)logy, oceanography, and glaciology. We present preparation (gas extraction and Ar separation) methods for groundwater and ice samples for later analysis by the ATTA technique. For groundwater, the sample size is less of a limitation than for applications in oceanography or glaciology. Large samples are furthermore needed to enable a comparison with the classical method of 39Ar detection by low-level counting. Therefore, a system was built that enables gas extraction from several thousand liters of water using membrane contactors. This system provides degassing efficiencies greater than 80 % and has successfully been tested in the field. Gas samples are further processed to separate a pure Ar fraction by a gas-chromatographic method based on Li-LSX zeolite as selective adsorber material at very low temperatures. The gas separation achieved by this system is controlled by a quadrupole mass spectrometer. It has successfully been tested and used on real samples. The separation efficiency was found to be strongly temperature dependent in the range of -118 to -130 °C. Since ATTA should enable the analysis of 39Ar on samples of less than 1 ccSTP of Ar (corresponding to about 100 ml of air, 2.5 l of water or 1 kg of ice), a method to separate Ar from small amounts of gas was developed. Titanium sponge was found to absorb 60 ccSTP of reactive gases per g of the getter material with reasonably high absorption rates at high operating temperatures (~ 800 ° C). Good separation (higher than 92 % Ar content in residual gas) was

  18. Overcoming Matrix Effects in a Complex Sample: Analysis of Multiple Elements in Multivitamins by Atomic Absorption Spectroscopy

    Science.gov (United States)

    Arnold, Randy J.; Arndt, Brett; Blaser, Emilia; Blosser, Chris; Caulton, Dana; Chung, Won Sog; Fiorenza, Garrett; Heath, Wyatt; Jacobs, Alex; Kahng, Eunice; Koh, Eun; Le, Thao; Mandla, Kyle; McCory, Chelsey; Newman, Laura; Pithadia, Amit; Reckelhoff, Anna; Rheinhardt, Joseph; Skljarevski, Sonja; Stuart, Jordyn; Taylor, Cassie; Thomas, Scott; Tse, Kyle; Wall, Rachel; Warkentien, Chad

    2011-01-01

    A multivitamin tablet and liquid are analyzed for the elements calcium, magnesium, iron, zinc, copper, and manganese using atomic absorption spectrometry. Linear calibration and standard addition are used for all elements except calcium, allowing for an estimate of the matrix effects encountered for this complex sample. Sample preparation using…

  19. Environmental samples analysis by Atomic Absorption Spectrophotometry and Inductively Coupled Plasma-Optical Emission Spectroscopy

    International Nuclear Information System (INIS)

    Popescu, I.V.; Iordan, M.; Stihi, C.; Bancuta, A.; Busuioc, G.; Dima, G.; Ciupina, V.; Belc, M.; Vlaicu, Gh.; Marian, R.

    2002-01-01

    Biological samples are interesting from many aspects of environmental monitoring. By analyzing tree leaves conclusions can be drown regarding the metal loading in the growth medium. So that, starting from assumption that the pollution factors from environmental medium can modify the normal concentration of elements, we decided to control the presence of toxic elements and the deviation from normal state of elements in leaves of different trees from areas situated at different distances of pollution source. The aim of this work is to determine the elemental composition of tree leaves using Atomic Absorption Spectrophotometry (AAS) method and Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES) method. Using AAS spectrophotometer SHIMADZU we identified and determined the concentration of: Cd, Co, Cu, Zn, Mn, Cr, Fe, Se, Pb with an instrumental error less than 1% for most of the elements analyzed. The same samples were analyzed by ICP-OES spectrometer, BAIRD ICP2070-Sequential Plasma spectrometer. We identified and determined in leaves of different trees the concentration of Mg, Ca, and Sr with a precision less than 6%. (authors)

  20. Wet sample digestion for quantification of vanadium(V) in serum by electrothermal atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Heinemann, G.; Vogt, W.; Jacob, K.

    1999-01-01

    Three types of pressure digestion systems used prior to the determination of the ultratrace element vanadium by electrothermal atomic absorption spectrometry were evaluated: The high-pressure ashing (HPA) system, the DAB III pressure digestion system and the pressurized microwave digestion (PMD) system. Complete sample digestion and no loss of graphite tube sensitivity as well as reliable vanadium values could only be achieved with HPA digests of freeze-dried serum. The mean recovery rate was 98% and no loss of tube sensitivity could be observed. Using non-lyophilized serum the mean recovery rate was 70%. The DAB III digestion system, vicarious for closed pressure digestion in steel bombs with an allowable temperature up to about 200C, cannot be recommended to mineralize human biological material for vanadium determinations, because the remaining not completely decomposed organic compounds extracted together with the vanadium-cupferron complex caused a marked carbon-buildup and formation of carbides in the graphite tube were found to change the shape of the absorption signals distinctly, and to decline the tube sensitivity strongly (about 25%) so that reliable results cannot be achieved. The recovery rate was too low in general (about 50%). In addition, a subsequent treatment of the DAB III digests with perchloric acid was unsuccessful. The PMD system proved to be not suited, because the samples became highly contaminated by vanadium possibly from the titan seal. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  1. A method for ion distribution function evaluation using escaping neutral atom kinetic energy samples

    International Nuclear Information System (INIS)

    Goncharov, P.R.; Ozaki, T.; Veshchev, E.A.; Sudo, S.

    2008-01-01

    A reliable method to evaluate the probability density function for escaping atom kinetic energies is required for the analysis of neutral particle diagnostic data used to study the fast ion distribution function in fusion plasmas. Digital processing of solid state detector signals is proposed in this paper as an improvement of the simple histogram approach. Probability density function for kinetic energies of neutral particles escaping from the plasma has been derived in a general form taking into account the plasma ion energy distribution, electron capture and loss rates, superposition along the diagnostic sight line and the magnetic surface geometry. A pseudorandom number generator has been realized that enables a sample of escaping neutral particle energies to be simulated for given plasma parameters and experimental conditions. Empirical probability density estimation code has been developed and tested to reconstruct the probability density function from simulated samples assuming. Maxwellian and classical slowing down plasma ion energy distribution shapes for different temperatures and different slowing down times. The application of the developed probability density estimation code to the analysis of experimental data obtained by the novel Angular-Resolved Multi-Sightline Neutral Particle Analyzer has been studied to obtain the suprathermal particle distributions. The optimum bandwidth parameter selection algorithm has also been realized. (author)

  2. Determination of some metal ions in various meat and baby food samples by atomic spectrometry.

    Science.gov (United States)

    Daşbaşı, Teslima; Saçmacı, Şerife; Ülgen, Ahmet; Kartal, Şenol

    2016-04-15

    In this paper, we report a simple and rapid solid phase extraction system for the separation/preconcentration and determination of Cd(II), Co(II), Cu(II), Fe(III), Cr(III), Pb(II), and Zn(II) ions by flame atomic absorption spectrometry (FAAS). This method is based upon the retention of metal ions on a column packed with poly[N-(3-methyl-1H-indole-1-yl)]-2-methacrylamide-co-2-acrylamido-2-methyl-1-propane sulphonic acid-co divinylbenzene] (MMAD) resin as a solid-phase extraction (SPE) sorbent at pH 8. At the optimized conditions, the limits of detection (3 s/b) between 0.12 and 1.6 μg L(-1), preconcentration factor of 100, and the relative standard deviation of ⩽1.8% were achieved (n=10). The accuracy of the method was verified by analyzing certified reference materials (CRMs) and performing recovery experiments. The developed method was successfully applied to the various natural water, meat products and baby food samples. The recoveries of analyte ions were found in added real samples and CRMs from 95% to 102%. Copyright © 2015 Elsevier Ltd. All rights reserved.

  3. Design and construction of a heat stage for investigations of samples by atomic force microscopy above ambient temperatures

    DEFF Research Database (Denmark)

    Bækmark, Thomas Rosleff; Bjørnholm, Thomas; Mouritsen, Ole G.

    1997-01-01

    The construction from simple and cheap commercially available parts of a miniature heat stage for the direct heating of samples studied with a commercially available optical-lever-detection atomic force microscope is reported. We demonstrate that by using this heat stage, atomic resolution can...... be obtained on highly oriented pyrolytic graphite at 52 °C. The heat stage is of potential use for the investigation of biological material at physiological temperatures. ©1997 American Institute of Physics....

  4. Spatial noise correlations of a chain of ultracold fermions: A numerical study

    International Nuclear Information System (INIS)

    Luescher, Andreas; Laeuchli, Andreas M.; Noack, Reinhard M.

    2007-01-01

    We present a numerical study of noise correlations, i.e., density-density correlations in momentum space, in the extended fermionic Hubbard model in one dimension. In experiments with ultracold atoms, these noise correlations can be extracted from time-of-flight images of the expanding cloud. Using the density-matrix renormalization group method to investigate the Hubbard model at various fillings and interactions, we confirm that the noise correlations contain full information on the most important fluctuations present in the system. We point out the importance of the sum rules fulfilled by the noise correlations and show that they yield nonsingular structures beyond the predictions of bosonization approaches. Noise correlations can thus serve as a universal probe of order and can be used to characterize the many-body states of cold atoms in optical lattices

  5. Optical Studies of Strong Coupling and Recombination in Ultracold Neutral Plasmas

    International Nuclear Information System (INIS)

    Killian, Thomas C.

    2004-01-01

    The ultracold atoms and plasmas research group at Rice University uses a combination of atomic and plasma physics techniques to create neutral plasmas that are orders of magnitude colder than have ever been studied before. Through this work, we probe the basic plasma physics of this exotic regime. During the past year, the major components of a new experiment were completed. We demonstrated a powerful new diagnostic, optical imaging of the plasma, which led to a paper that was published in Physical Review Letters. (Figure A, Phys. Rev. Lett. 92, 143001 (2004)) This was the central feature of my DOE Junior Faculty Award proposal. DOE funding has been used to support one postdoctoral researcher, multiple graduate students, the principle investigator, apparatus construction, and normal laboratory expenses

  6. Band structure engineering for ultracold quantum gases in optical lattices

    International Nuclear Information System (INIS)

    Weinberg, Malte

    2014-01-01

    the same system maps onto a quantum spin-1/2 XY model. Owing to the quantum nature of the pseudospins, geometrical frustration leads to a highly degenerate ground state which can result in exotic valence bond spin-liquid phases. First signatures of an order-by-disorder effect emerge in this regime. A complementary approach to the manipulation of the band structure is investigated in a honeycomb potential. By rotating the quantization field of the system, the statedependent energy offset between the twofold atomic basis of the hexagonal Bravais lattice can be adjusted. This purposeful breaking of inversion symmetry enables the continuous opening of an energy gap at the Dirac points of the honeycomb band structure. In addition, a striking influence of the band gap onto the lifetimes for atoms in the first excited energy band is observed. In the last part of the thesis, both experimental manipulation techniques are discussed with respect to future applications for ultracold quantum gases in non-cubic optical lattices.

  7. Ordered structures in rotating ultracold Bose gases

    International Nuclear Information System (INIS)

    Barberan, N.; Dagnino, D.; Lewenstein, M.; Osterloh, K.

    2006-01-01

    Two-dimentional systems of trapped samples of few cold bosonic atoms submitted to strong rotation around the perpendicular axis may be realized in optical lattices and microtraps. We investigate theoretically the evolution of ground state structures of such systems as the rotational frequency Ω increases. Various kinds of ordered structures are observed. In some cases, hidden interference patterns exhibit themselves only in the pair correlation function; in some other cases explicit broken-symmetry structures appear that modulate the density. For N<10 atoms, the standard scenario, valid for large sytems is absent, and is only gradually recovered as N increases. On the one hand, the Laughlin state in the strong rotational regime contains ordered structures much more similar to a Wigner molecule than to a fermionic quantum liquid. On the other hand, in the weak rotational regime, the possibility to obtain equilibrium states, whose density reveals an array of vortices, is restricted to the vicinity of some critical values of the rotational frequency Ω

  8. Hybrid quantum systems of ions and atoms

    OpenAIRE

    Sias, Carlo; Köhl, Michael

    2014-01-01

    In this chapter we review the progress in experiments with hybrid systems of trapped ions and ultracold neutral atoms. We give a theoretical overview over the atom-ion interactions in the cold regime and give a summary of the most important experimental results. We conclude with an overview of remaining open challenges and possible applications in hybrid quantum systems of ions and neutral atoms.

  9. Determination of cadmium in real water samples by flame atomic absorption spectrometry after cloud point extraction

    International Nuclear Information System (INIS)

    Naeemullah, A.; Kazi, T.G.

    2011-01-01

    Water pollution is a global threat and it is the leading world wide cause of death and diseases. The awareness of the potential danger posed by heavy metals to the ecosystems and in particular to human health has grown tremendously in the past decades. Separation and preconcentration procedures are considered of great importance in analytical and environmental chemistry. Cloud point is one of the most reliable and sophisticated separation methods for determination of traces quantities of heavy metals. Cloud point methodology was successfully employed for preconcentration of trace quantities of cadmium prior to their determination by flame atomic absorption spectrometry (FAAS). The metals react with 8-hydroxquinoline in a surfactant Triton X-114 medium. The following parameters such as pH, concentration of the reagent and Triton X-114, equilibrating temperature and centrifuging time were evaluated and optimized to enhance the sensitivity and extraction efficiency of the proposed method. Dilution of the surfactant-rich phase with acidified ethanol was performed after phase separation and the cadmium content was measured by FAAS. The validation of the procedure was carried out by spiking addition methods. The method was applied for determination of Cd in water samples of different ecosystems (lake and river). (author)

  10. High performance liquid chromatography--atomic fluorescence spectrometric determination of arsenic species in beer samples

    International Nuclear Information System (INIS)

    Melo Coelho, N.M.; Parrilla, Carmen; Cervera, M.L.; Pastor, A.; Guardia, M. de la

    2003-01-01

    A method has been developed for the direct determination of As(III), dimethylarsinic acid (DMA), monomethylarsonic acid (MMA) and As(V) in beers by hydride generation--atomic fluorescence spectrometry after separation of arsenic species by high performance liquid chromatography. Compounds were separated by anion-exchange chromatography with isocratic elution using KH 2 PO 4 /K 2 HPO 4 as mobile phase with elution times of 1.67, 2.08, 6.52 and 10.72 min for As(III), DMA, MMA and As(V), respectively. Parameters affecting the hydride generation of all arsenic species were studied and the best conditions were established as a reaction coil of 150 cm, for a sample injected volume of 100 μl, a 4.0% (m/v) solution of sodium tetrahydroborate and 2.0 mol l -1 hydrochloric acid with flow rates of 2.7 and 1.7 ml min -1 , respectively and a flow rate of 500 ml min -1 for the argon carrier gas. Under the best experimental conditions, the detection limit was found to be 0.12, 0.20, 0.27 and 0.39 μg l -1 for As(III), DMA, MMA and As(V), respectively. The relative standard deviation for eight independent determinations varied from 3.9 till 8.9% for species considered at a concentration level of 10.0 μg l -1 . Recovery and comparative studies evidenced that the method is suitable for the accurate determination of arsenic species in water and beer samples

  11. High performance liquid chromatography--atomic fluorescence spectrometric determination of arsenic species in beer samples

    Energy Technology Data Exchange (ETDEWEB)

    Melo Coelho, N.M.; Parrilla, Carmen; Cervera, M.L.; Pastor, A.; Guardia, M. de la

    2003-04-10

    A method has been developed for the direct determination of As(III), dimethylarsinic acid (DMA), monomethylarsonic acid (MMA) and As(V) in beers by hydride generation--atomic fluorescence spectrometry after separation of arsenic species by high performance liquid chromatography. Compounds were separated by anion-exchange chromatography with isocratic elution using KH{sub 2}PO{sub 4}/K{sub 2}HPO{sub 4} as mobile phase with elution times of 1.67, 2.08, 6.52 and 10.72 min for As(III), DMA, MMA and As(V), respectively. Parameters affecting the hydride generation of all arsenic species were studied and the best conditions were established as a reaction coil of 150 cm, for a sample injected volume of 100 {mu}l, a 4.0% (m/v) solution of sodium tetrahydroborate and 2.0 mol l{sup -1} hydrochloric acid with flow rates of 2.7 and 1.7 ml min{sup -1}, respectively and a flow rate of 500 ml min{sup -1} for the argon carrier gas. Under the best experimental conditions, the detection limit was found to be 0.12, 0.20, 0.27 and 0.39 {mu}g l{sup -1} for As(III), DMA, MMA and As(V), respectively. The relative standard deviation for eight independent determinations varied from 3.9 till 8.9% for species considered at a concentration level of 10.0 {mu}g l{sup -1}. Recovery and comparative studies evidenced that the method is suitable for the accurate determination of arsenic species in water and beer samples.

  12. Visualization and automatic detection of defect distribution in GaN atomic structure from sampling Moiré phase.

    Science.gov (United States)

    Wang, Qinghua; Ri, Shien; Tsuda, Hiroshi; Kodera, Masako; Suguro, Kyoichi; Miyashita, Naoto

    2017-09-19

    Quantitative detection of defects in atomic structures is of great significance to evaluating product quality and exploring quality improvement process. In this study, a Fourier transform filtered sampling Moire technique was proposed to visualize and detect defects in atomic arrays in a large field of view. Defect distributions, defect numbers and defect densities could be visually and quantitatively determined from a single atomic structure image at low cost. The effectiveness of the proposed technique was verified from numerical simulations. As an application, the dislocation distributions in a GaN/AlGaN atomic structure in two directions were magnified and displayed in Moire phase maps, and defect locations and densities were detected automatically. The proposed technique is able to provide valuable references to material scientists and engineers by checking the effect of various treatments for defect reduction. © 2017 IOP Publishing Ltd.

  13. Spin squeezing and Schrödinger cat generation in atomic samples with Rydberg blockade

    DEFF Research Database (Denmark)

    Opatrný, Tomáš; Mølmer, Klaus

    2012-01-01

    A scheme is proposed to prepare squeezed states and Schrödinger-cat-like states of the collective spin degrees of freedom associated with a pair of ground states in an atomic ensemble. The scheme uses an effective Jaynes-Cummings interaction which can be provided by excitation of the atoms...

  14. Trapping and interactions of an ultracold gas of Cs2 molecules

    International Nuclear Information System (INIS)

    Mark, M.; Kraemer, T.; Herbig, J.; Waldburger, P.; Naegerl, H.C.; Chin, C.; Grimm, R.

    2005-01-01

    Full text: We investigate dynamics and interactions of Cs 2 dimers in a CO2-laser dipole trap. Starting with a Bose-Einstein condensate (BEC) of 2.2 x 10 5 Cs atoms, we create ultracold molecules in a single, weakly bound quantum state by sweeping the magnetic field across a narrow Feshbach resonance. When the molecules are created in free space, the conversion efficiency exceeds 30 %, yielding up to 50000 molecules. In our trapping experiments, about 6000 ultracold Cs 2 dimers are prepared in the optical trap at a temperature of 200 nK. We transfer the trapped molecules from the initial molecular state to other molecular states by following avoided crossings. We find two magnetically tunable resonances in collisions between the molecules for one of the molecular states. We interpret these Feshbach-liKEX resonances as being induced by Cs 4 bound states near the molecular scattering continuum. Further, we have discovered a new molecular state with very large orbital angular momentum of l = 8. This state is very weakly coupled to one of the initial molecular states. We use the associated avoided crossing as a molecular beam splitter to realize a molecular Ramsey-type interferometer. Refs. 2 (author)

  15. Long-Lived Ultracold Molecules with Electric and Magnetic Dipole Moments

    Science.gov (United States)

    Rvachov, Timur M.; Son, Hyungmok; Sommer, Ariel T.; Ebadi, Sepehr; Park, Juliana J.; Zwierlein, Martin W.; Ketterle, Wolfgang; Jamison, Alan O.

    2017-10-01

    We create fermionic dipolar 23Na 6Li molecules in their triplet ground state from an ultracold mixture of 23Na and 6Li. Using magnetoassociation across a narrow Feshbach resonance followed by a two-photon stimulated Raman adiabatic passage to the triplet ground state, we produce 3 ×1 04 ground state molecules in a spin-polarized state. We observe a lifetime of 4.6 s in an isolated molecular sample, approaching the p -wave universal rate limit. Electron spin resonance spectroscopy of the triplet state was used to determine the hyperfine structure of this previously unobserved molecular state.

  16. Trapped atoms along nanophotonic resonators

    Science.gov (United States)

    Fields, Brian; Kim, May; Chang, Tzu-Han; Hung, Chen-Lung

    2017-04-01

    Many-body systems subject to long-range interactions have remained a very challenging topic experimentally. Ultracold atoms trapped in extreme proximity to the surface of nanophotonic structures provides a dynamic system combining the strong atom-atom interactions mediated by guided mode photons with the exquisite control implemented with trapped atom systems. The hybrid system promises pair-wise tunability of long-range interactions between atomic pseudo spins, allowing studies of quantum magnetism extending far beyond nearest neighbor interactions. In this talk, we will discuss our current status developing high quality nanophotonic ring resonators, engineered on CMOS compatible optical chips with integrated nanostructures that, in combination with a side illuminating beam, can realize stable atom traps approximately 100nm above the surface. We will report on our progress towards loading arrays of cold atoms near the surface of these structures and studying atom-atom interaction mediated by photons with high cooperativity.

  17. Moeller polarimetry with atomic hydrogen targets

    International Nuclear Information System (INIS)

    Chudakov, E.; Luppov, V.

    2005-01-01

    A novel proposal of using polarized atomic hydrogen gas, stored in an ultra-cold magnetic trap, as the target for electron beam polarimetry based on Moeller scattering is discussed. Such a target of practically 100% polarized electrons could provide a superb systematic accuracy of about 0.5% for beam polarization measurements. Feasibility studies for the CEBAF electron beam have been performed. (orig.)

  18. Atomic rubidium, the workhorse of theoretical collision physics

    NARCIS (Netherlands)

    Verhaar, B.; van Kempen, E.; Kokkelmans, S.J.J.M.F.

    2008-01-01

    Since the first realizations of Bose-Einstein condensates in ultracold atomic gases in 1995, the 85Rb and 87Rb atomic species have acted as the workhorses of experimental developments in this field. Parallel to and partly preceding this work the same isotopes figured also as workhorses for

  19. Ultracold molecules for the masses: Evaporative cooling and magneto-optical trapping

    Science.gov (United States)

    Stuhl, B. K.

    While cold molecule experiments are rapidly moving towards their promised benefits of precision spectroscopy, controllable chemistry, and novel condensed phases, heretofore the field has been greatly limited by a lack of methods to cool and compress chemically diverse species to temperatures below ten millikelvin. While in atomic physics these needs are fulfilled by laser cooling, magneto-optical trapping, and evaporative cooling, until now none of these techniques have been applicable to molecules. In this thesis, two major breakthroughs are reported. The first is the observation of evaporative cooling in magnetically trapped hydroxyl (OH) radicals, which potentially opens a path all the way to Bose-Einstein condensation of dipolar radicals, as well as allowing cold- and ultracold-chemistry studies of fundamental reaction mechanisms. Through the combination of an extremely high gradient magnetic quadrupole trap and the use of the OH Λ-doublet transition to enable highly selective forced evaporation, cooling by an order of magnitude in temperature was achieved and yielded a final temperature no higher than 5mK. The second breakthrough is the successful application of laser cooling and magneto-optical trapping to molecules. Motivated by a proposal in this thesis, laser cooling of molecules is now known to be technically feasible in a select but substantial pool of diatomic molecules. The demonstration of not only Doppler cooling but also two-dimensional magneto-optical trapping in yttrium (II) oxide, YO, is expected to enable rapid growth in the availability of ultracold molecules—just as the invention of the atomic magneto-optical trap stimulated atomic physics twenty-five years ago.

  20. A device for simultaneous spin analysis of ultracold neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Afach, S. [Institute for Particle Physics, ETH Zuerich, Zuerich (Switzerland); Paul Scherrer Institute, Villigen-PSI (Switzerland); Jena University Hospital, Hans Berger Department of Neurology, Jena (Germany); Ban, G.; Lefort, T.; Lemiere, Y.; Naviliat-Cuncic, O.; Quemener, G. [Universite de Caen, CNRS/IN2P3, LPC Caen ENSICAEN, Caen (France); Bison, G.; Chowdhuri, Z.; Daum, M.; Henneck, R.; Lauss, B.; Mtchedlishvili, A.; Schmidt-Wellenburg, P.; Zsigmond, G. [Paul Scherrer Institute, Villigen-PSI (Switzerland); Bodek, K.; Rawlik, M.; Rozpedzik, D.; Zejma, J. [Jagiellonian University, Marian Smoluchowski Institute of Physics, Cracow (Poland); Fertl, M.; Franke, B.; Kirch, K.; Komposch, S. [Institute for Particle Physics, ETH Zuerich, Zuerich (Switzerland); Paul Scherrer Institute, Villigen-PSI (Switzerland); Geltenbort, P. [Institut Laue-Langevin, Grenoble (France); Grujic, Z.D.; Kasprzak, M.; Weis, A. [University of Fribourg, Physics Department, Fribourg (Switzerland); Hayen, L.; Severijns, N.; Wursten, E. [Katholieke Universiteit Leuven, Instituut voor Kernen Stralingsfysica, Leuven (Belgium); Helaine, V. [Paul Scherrer Institute, Villigen-PSI (Switzerland); Universite de Caen, CNRS/IN2P3, LPC Caen ENSICAEN, Caen (France); Kermaidic, Y.; Pignol, G.; Rebreyend, D. [Universite Grenoble Alpes, CNRS/IN2P3, LPSC, Grenoble (France); Kozela, A. [Henryk Niedwodniczanski Institute for Nuclear Physics, Cracow (Poland); Krempel, J.; Piegsa, F.M. [Institute for Particle Physics, ETH Zuerich, Zuerich (Switzerland); Prashanth, P.N. [Paul Scherrer Institute, Villigen-PSI (Switzerland); Katholieke Universiteit Leuven, Instituut voor Kernen Stralingsfysica, Leuven (Belgium); Ries, D. [Paul Scherrer Institute, Villigen-PSI (Switzerland); Jena University Hospital, Hans Berger Department of Neurology, Jena (Germany); Roccia, S. [Universite Paris Sud, CNRS/IN2P3, CSNSM, Orsay campus (France); Wyszynski, G. [Institute for Particle Physics, ETH Zuerich, Zuerich (Switzerland); Jagiellonian University, Marian Smoluchowski Institute of Physics, Cracow (Poland)

    2015-11-15

    We report on the design and first tests of a device allowing for measurement of ultracold neutrons polarisation by means of the simultaneous analysis of the two spin components. The device was developed in the framework of the neutron electric dipole moment experiment at the Paul Scherrer Institute. Individual parts and the entire newly built system have been characterised with ultracold neutrons. The gain in statistical sensitivity obtained with the simultaneous spin analyser is (18.2 ± 6.1) % relative to the former sequential analyser under nominal running conditions. (orig.)

  1. Ultracold and very cold neutron facility in KUR

    International Nuclear Information System (INIS)

    Kawabata, Yuji; Utsuro, Masahiko

    1992-01-01

    The present status of the ultracold and very cold neutron facility installed in the Kyoto University Reactor (KUR) is described in this presentation. It consists of a VCN (very cold neutrons) guide tube, a VCN bender and a supermirror neutron turbine. The guide tube extracts VCN from a liquid deuterium cold neutron source in a graphite thermal column and the neutron turbine converts VCN to UCN (ultracold neutrons). As for the utilization of the present facility, VCN radiography and an UCN gravity spectrometer are shown for the practical examples of the research with VCN and UCN. (author)

  2. Sample preparation for arsenic speciation analysis in baby food by generation of substituted arsines with atomic absorption spectrometry detection

    Czech Academy of Sciences Publication Activity Database

    Huber, C. S.; Vale, M. G. R.; Dessuy, M. B.; Svoboda, Milan; Musil, Stanislav; Dědina, Jiří

    2017-01-01

    Roč. 175, DEC (2017), s. 406 -412 ISSN 0039-9140 R&D Projects: GA MŠk(CZ) LH15174 Institutional support: RVO:68081715 Keywords : slurry sampling * methyl-substituted arsenic species * hydride generation-cryotrapping-atomic absorption spectrometry Subject RIV: CB - Analytical Chemistry, Separation OBOR OECD: Analytical chemistry Impact factor: 4.162, year: 2016

  3. Sample preparation for arsenic speciation analysis in baby food by generation of substituted arsines with atomic absorption spectrometry detection

    Czech Academy of Sciences Publication Activity Database

    Huber, C. S.; Vale, M. G. R.; Dessuy, M. B.; Svoboda, Milan; Musil, Stanislav; Dědina, Jiří

    2017-01-01

    Roč. 175, DEC (2017), s. 406-412 ISSN 0039-9140 R&D Projects: GA MŠk(CZ) LH15174 Institutional support: RVO:68081715 Keywords : slurry sampling * methyl-substituted arsenic species * hydride generation-cryotrapping-atomic absorption spectrometry Subject RIV: CB - Analytical Chemistry, Separation OBOR OECD: Analytical chemistry Impact factor: 4.162, year: 2016

  4. Buffer choice and effects of sample composition examined by experiment planning methods for determination of molybdenum by atomic absorption with a flame atomizer

    International Nuclear Information System (INIS)

    Zav'yalkov, P.I.; Danishehvskii, A.L.; Rakita, R.A.; Yakshinskii, A.I.

    1986-01-01

    The authors use orthogonal experiment planning to define the optimum form of buffer and to establish the effects of sample composition since there are high levels of cation and anion interference in the atomic-absorption determination of molybdenum. A spectroscopic buffer has been identified (HCLO 4 + NH 4 Cl mixture), which eliminates the interference from the elements tested and improves the analytical characteristics in determining molybdenum. A model has been formulated enabling one to estimate the buffer performance and the effects of the components on the determination of molybdenum. The model enables one to forecast the expected order of the effect without performing additional experiments

  5. Analytical Model of the Nonlinear Dynamics of Cantilever Tip-Sample Surface Interactions for Various Acoustic-Atomic Force Microscopies

    Science.gov (United States)

    Cantrell, John H., Jr.; Cantrell, Sean A.

    2008-01-01

    A comprehensive analytical model of the interaction of the cantilever tip of the atomic force microscope (AFM) with the sample surface is developed that accounts for the nonlinearity of the tip-surface interaction force. The interaction is modeled as a nonlinear spring coupled at opposite ends to linear springs representing cantilever and sample surface oscillators. The model leads to a pair of coupled nonlinear differential equations that are solved analytically using a standard iteration procedure. Solutions are obtained for the phase and amplitude signals generated by various acoustic-atomic force microscope (A-AFM) techniques including force modulation microscopy, atomic force acoustic microscopy, ultrasonic force microscopy, heterodyne force microscopy, resonant difference-frequency atomic force ultrasonic microscopy (RDF-AFUM), and the commonly used intermittent contact mode (TappingMode) generally available on AFMs. The solutions are used to obtain a quantitative measure of image contrast resulting from variations in the Young modulus of the sample for the amplitude and phase images generated by the A-AFM techniques. Application of the model to RDF-AFUM and intermittent soft contact phase images of LaRC-cp2 polyimide polymer is discussed. The model predicts variations in the Young modulus of the material of 24 percent from the RDF-AFUM image and 18 percent from the intermittent soft contact image. Both predictions are in good agreement with the literature value of 21 percent obtained from independent, macroscopic measurements of sheet polymer material.

  6. Determination of As, Cd, Cu, Hg and Pb in biological samples by modern electrothermal atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Sardans, Jordi; Montes, Fernando; Penuelas, Josep

    2010-01-01

    Pollution from heavy metals has increased in recent decades and has become an important concern for environmental agencies. Arsenic, cadmium, copper, mercury and lead are among the trace elements that have the greatest impact and carry the highest risk to human health. Electrothermal atomic absorption spectrometry (ETAAS) has long been used for trace element analyses and over the past few years, the main constraints of atomic absorption spectrometry (AAS) methods, namely matrix interferences that provoked high background absorption and interferences, have been reduced. The use of new, more efficient modifiers and in situ trapping methods for stabilization and pre-concentration of these analytes, progress in control of atomization temperatures, new designs of atomizers and advances in methods to correct background spectral interferences have permitted an improvement in sensitivity, an increase in detection power, reduction in sample manipulation, and increase in the reproducibility of the results. These advances have enhanced the utility of Electrothermal atomic absorption spectrometry (ETAAS) for trace element determination at μg L -1 levels, especially in difficult matrices, giving rise to greater reproducibility, lower economic cost and ease of sample pre-treatment compared to other methods. Moreover, the recent introduction of high resolution continuum source Electrothermal atomic absorption spectrometry (HR-CS-ETAAS) has facilitated direct solid sampling, reducing background noise and opening the possibility of achieving even more rapid quantitation of some elements. The incorporation of flow injection analysis (FIA) systems for automation of sample pre-treatment, as well as chemical vapor generation renders (ETAAS) into a feasible option for detection of As and Hg in environmental and food control studies wherein large numbers of samples can be rapidly analyzed. A relatively inexpensive approach with low sample consumption provide additional advantages of

  7. Determination of As, Cd, Cu, Hg and Pb in biological samples by modern electrothermal atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Sardans, Jordi, E-mail: j.sardans@creaf.uab.ca [Ecophysiological and Global Change Unit CSIC-CREAF, Edifici C, Universitat Autonoma de Barcelona, Bellaterra 08193, Barcelona (Spain); Montes, Fernando [Departamento de Ciencias Analiticas, Facultad de Ciencias, Universidad Nacional de Educacion a Distancia (UNED), C/ Senda del Rey 9. 28040 Madrid (Spain); Penuelas, Josep [Ecophysiological and Global Change Unit CSIC-CREAF, Edifici C, Universitat Autonoma de Barcelona, Bellaterra 08193, Barcelona (Spain)

    2010-02-15

    Pollution from heavy metals has increased in recent decades and has become an important concern for environmental agencies. Arsenic, cadmium, copper, mercury and lead are among the trace elements that have the greatest impact and carry the highest risk to human health. Electrothermal atomic absorption spectrometry (ETAAS) has long been used for trace element analyses and over the past few years, the main constraints of atomic absorption spectrometry (AAS) methods, namely matrix interferences that provoked high background absorption and interferences, have been reduced. The use of new, more efficient modifiers and in situ trapping methods for stabilization and pre-concentration of these analytes, progress in control of atomization temperatures, new designs of atomizers and advances in methods to correct background spectral interferences have permitted an improvement in sensitivity, an increase in detection power, reduction in sample manipulation, and increase in the reproducibility of the results. These advances have enhanced the utility of Electrothermal atomic absorption spectrometry (ETAAS) for trace element determination at mug L{sup -1} levels, especially in difficult matrices, giving rise to greater reproducibility, lower economic cost and ease of sample pre-treatment compared to other methods. Moreover, the recent introduction of high resolution continuum source Electrothermal atomic absorption spectrometry (HR-CS-ETAAS) has facilitated direct solid sampling, reducing background noise and opening the possibility of achieving even more rapid quantitation of some elements. The incorporation of flow injection analysis (FIA) systems for automation of sample pre-treatment, as well as chemical vapor generation renders (ETAAS) into a feasible option for detection of As and Hg in environmental and food control studies wherein large numbers of samples can be rapidly analyzed. A relatively inexpensive approach with low sample consumption provide additional advantages

  8. Stability of a fully magnetized ferromagnetic state in repulsively interacting ultracold Fermi gases

    International Nuclear Information System (INIS)

    Cui Xiaoling; Zhai Hui

    2010-01-01

    We construct a variational wave function to study whether a fully polarized Fermi sea of ultracold atoms is energetically stable against a single spin flip. Our variational wave function contains short-range correlations at least to the same level as Gutzwiller's projected wave function. For the Hubbard lattice model and the continuum model with pure repulsive interaction, we show that a fully polarized Fermi sea is generally unstable even for infinite repulsive strength. By contrast, for a resonance model, the ferromagnetic state is possible if the s-wave scattering length is positive and sufficiently large and the system is prepared to be orthogonal to the molecular bound state. However, we cannot rule out the possibility that more exotic correlations can destabilize the ferromagnetic state.

  9. Response Functions for the Two-Dimensional Ultracold Fermi Gas: Dynamical BCS Theory and Beyond

    Science.gov (United States)

    Vitali, Ettore; Shi, Hao; Qin, Mingpu; Zhang, Shiwei

    2017-12-01

    Response functions are central objects in physics. They provide crucial information about the behavior of physical systems, and they can be directly compared with scattering experiments involving particles such as neutrons or photons. Calculations of such functions starting from the many-body Hamiltonian of a physical system are challenging and extremely valuable. In this paper, we focus on the two-dimensional (2D) ultracold Fermi atomic gas which has been realized experimentally. We present an application of the dynamical BCS theory to obtain response functions for different regimes of interaction strengths in the 2D gas with zero-range attractive interaction. We also discuss auxiliary-field quantum Monte Carlo (AFQMC) methods for the calculation of imaginary time correlations in these dilute Fermi gas systems. Illustrative results are given and comparisons are made between AFQMC and dynamical BCS theory results to assess the accuracy of the latter.

  10. Making ultracold molecules in a two-color pump-dump photoassociation scheme using chirped pulses

    International Nuclear Information System (INIS)

    Koch, Christiane P.; Luc-Koenig, Eliane; Masnou-Seeuws, Francoise

    2006-01-01

    This theoretical paper investigates the formation of ground state molecules from ultracold cesium atoms in a two-color scheme. Following previous work on photoassociation with chirped picosecond pulses [Luc-Koenig et al., Phys. Rev. A, 70, 033414 (2004)], we investigate stabilization by a second (dump) pulse. By appropriately choosing the dump pulse parameters and time delay with respect to the photoassociation pulse, we show that a large number of deeply bound molecules are created in the ground triplet state. We discuss (i) broad-bandwidth dump pulses which maximize the probability to form molecules while creating a broad vibrational distribution as well as (ii) narrow-bandwidth pulses populating a single vibrational ground state level, bound by 113 cm -1 . The use of chirped pulses makes the two-color scheme robust, simple, and efficient

  11. Experimental testing of the dispersion law of ultracold neutrons

    International Nuclear Information System (INIS)

    Bondarenko, I.V.; Krasnoperov, A.V.; Frank, A.I.; Geltenbort, P.; Hoghoj, P.; Klein, A.G.; Cimmino, A.; Masalovich, S.V.; Nosov, V.G.

    1998-01-01

    Experiment on testing the generally accepted laws on ultracold neutron dispersion is described. The experiment is based on search of displacement lines of a neutron interference filter resonance by variation of neutrons rapidity component, parallel to the filter surface. The first results testify to the presence of statistically meaningful effect

  12. Depolarization of ultracold neutrons during their storage in material bottles

    International Nuclear Information System (INIS)

    Serebrov, A.P.; Lasakov, M.S.; Vassiljev, A.V.; Krasnoschekova, I.A.; Rudnev, Yu.P.; Fomin, A.K.; Varlamov, V.E.; Geltenbort, P.; Butterworth, J.; Young, A.R.; Pesavento, U.

    2003-01-01

    The depolarization of ultracold neutrons (UCN) during their storage in traps has been investigated. The neutron spin-flip probability for the materials studied amounts to ∼(1-2)x10 -5 per collision and does not depend on the temperature. The possible connection between the phenomenon of UCN depolarization and that of anomalous losses is discussed

  13. Depolarization of ultracold neutrons during their storage in material bottles

    Energy Technology Data Exchange (ETDEWEB)

    Serebrov, A.P.; Lasakov, M.S.; Vassiljev, A.V.; Krasnoschekova, I.A.; Rudnev, Yu.P.; Fomin, A.K.; Varlamov, V.E.; Geltenbort, P.; Butterworth, J.; Young, A.R.; Pesavento, U

    2003-07-14

    The depolarization of ultracold neutrons (UCN) during their storage in traps has been investigated. The neutron spin-flip probability for the materials studied amounts to {approx}(1-2)x10{sup -5} per collision and does not depend on the temperature. The possible connection between the phenomenon of UCN depolarization and that of anomalous losses is discussed.

  14. On a magnet configuration for confining ultracold neutrons

    International Nuclear Information System (INIS)

    Abov, Yu.G.; Vasil'ev, V.V.; Vladimirskij, V.V.; Krupchitskij, P.A.; Rissukhin, V.K.

    1977-01-01

    A magnetic system for experiments on the ultracold neutron confinement is described. The magnetic field calculation results are given. They make it possible to select the geometric places of points in which the neutron depolarization may appear and to suggest the way for diminishing the depolarization

  15. Exploring strategies for the production of ultracold RbYb molecules in conservative traps

    Energy Technology Data Exchange (ETDEWEB)

    Bruni, Cristian

    2015-07-14

    Within the scope of this thesis, the production of ultracold molecules at a temperature of a few μK with various isotopes of rubidium (Rb) and ytterbium (Yb) was examined by means of photoassociation spectroscopy and magnetic Feshbach resonances in combined conservative traps. The long-term goal of this experiment is the production of ultracold RbYb molecules in the rovibronic ground state. It was possible to produce electronically excited {sup 87}Rb {sup 176}Yb molecules in a novel hybrid trap (HT) at a combined temperature of 1.7 μK by means of 1-photon photoassociation close to the Rb D1 line at 795 nm. This HT takes advantage of the different magnetic properties of Rb and Yb and allows for independent trapping and manipulation of the atomic species. It combines an Ioffe-Pritchard type magnetic trap for Rb and a near-resonant optical dipole trap for Yb. The excited molecular {sup 2}Π{sub 1/2} state could be characterized further extending previous works in a combined MOT and vibrational levels reaching binding energies up to E{sub b}=-h x 2.2 THz could be assigned by trap-loss spectroscopy. Almost every detected vibrational state consists of two resonances that could be assigned to the molecular analogue of the hyperfine structure of {sup 87}Rb. An important experimental observation is a decrease in hyperfine splitting with increasing binding energy of a vibrational level. For the deepest found vibrational state the hyperfine splitting amounts only 70 % of the atomic value (817 MHz) which emphasizes a gradual passage from weakly to tightly bound molecules. Furthermore, detailed attempts were undertaken to induce magnetic Feshbach resonances in {sup 85}Rb and different Yb isotopes, especially {sup 171}Yb in a crossed optical dipole trap at 1064 nm at temperatures of 10 μK. For this purpose, a homogeneous magnetic field was applied and scanned in small steps over the range of 495 G ∼ 640 G. Unfortunately, our efforts were without success. Additionally, well

  16. Magni: A Python Package for Compressive Sampling and Reconstruction of Atomic Force Microscopy Images

    DEFF Research Database (Denmark)

    Oxvig, Christian Schou; Pedersen, Patrick Steffen; Arildsen, Thomas

    2014-01-01

    Magni is an open source Python package that embraces compressed sensing and Atomic Force Microscopy (AFM) imaging techniques. It provides AFM-specific functionality for undersampling and reconstructing images from AFM equipment and thereby accelerating the acquisition of AFM images. Magni also pr...... as a convenient platform for researchers in compressed sensing aiming at obtaining a high degree of reproducibility of their research....

  17. Atom interferometry with trapped Bose-Einstein condensates: impact of atom-atom interactions

    International Nuclear Information System (INIS)

    Grond, Julian; Hohenester, Ulrich; Mazets, Igor; Schmiedmayer, Joerg

    2010-01-01

    Interferometry with ultracold atoms promises the possibility of ultraprecise and ultrasensitive measurements in many fields of physics, and is the basis of our most precise atomic clocks. Key to a high sensitivity is the possibility to achieve long measurement times and precise readout. Ultracold atoms can be precisely manipulated at the quantum level and can be held for very long times in traps; they would therefore be an ideal setting for interferometry. In this paper, we discuss how the nonlinearities from atom-atom interactions, on the one hand, allow us to efficiently produce squeezed states for enhanced readout and, on the other hand, result in phase diffusion that limits the phase accumulation time. We find that low-dimensional geometries are favorable, with two-dimensional (2D) settings giving the smallest contribution of phase diffusion caused by atom-atom interactions. Even for time sequences generated by optimal control, the achievable minimal detectable interaction energy ΔE min is of the order of 10 -4 μ, where μ is the chemical potential of the Bose-Einstein condensate (BEC) in the trap. From these we have to conclude that for more precise measurements with atom interferometers, more sophisticated strategies, or turning off the interaction-induced dephasing during the phase accumulation stage, will be necessary.

  18. Storage ring to investigate cold unidimensional atomic collisions

    International Nuclear Information System (INIS)

    Marcassa, L. G.; Caires, A. R. L.; Nascimento, V. A.; Dulieu, O.; Weiner, J.; Bagnato, V. S.

    2005-01-01

    In this paper we employ a circulating ring of trapped atoms, that we have named the atomotron, to study cold collisions. The atomotron is obtained from a conventional magneto-optical trap when the two pairs of normally retroreflecting Gaussian laser beams in the x-y plane are slightly offset. Circulating stable atomic orbits then form a racetrack geometry in this plane. The circulating atom flux behaves similarly to an atomic beam with an average tangential velocity much greater than the transverse components, and is therefore suitable for one-dimensional atomic collision studies. Using the atomotron, we have investigated the polarization dependence of ultracold photoassociation collisions between Rb atoms circulating in the racetrack. The ability to investigate collisions in ultracold circulating atomic rings reveals alignment and orientation properties that are averaged away in ordinary three-dimensional magneto-optical trap collision processes

  19. Imaging contrast and tip-sample interaction of non-contact amplitude modulation atomic force microscopy with Q -control

    International Nuclear Information System (INIS)

    Shi, Shuai; Guo, Dan; Luo, Jianbin

    2017-01-01

    Active quality factor ( Q ) exhibits many promising properties in dynamic atomic force microscopy. Energy dissipation and image contrasts are investigated in the non-contact amplitude modulation atomic force microscopy (AM-AFM) with an active Q -control circuit in the ambient air environment. Dissipated power and virial were calculated to compare the highly nonlinear interaction of tip-sample and image contrasts with different Q gain values. Greater free amplitudes and lower effective Q values show better contrasts for the same setpoint ratio. Active quality factor also can be employed to change tip-sample interaction force in non-contact regime. It is meaningful that non-destructive and better contrast images can be realized in non-contact AM-AFM by applying an active Q -control to the dynamic system. (paper)

  20. Direct determination of lead in human urine and serum samples by electrothermal atomic absorption spectrometry and permanent modifiers

    International Nuclear Information System (INIS)

    Andrada, Daniel; Pinto, Frederico G.; Magalhaes, Cristina Goncalves; Nunes, Berta R.; Silva, Jose Bento Borba da; Franco, Milton B.

    2006-01-01

    The object of the present study was the development of alternative methods for the direct determination of lead in undigested samples of human urine and serum by electrothermal atomic absorption spectrometry (ETAAS). Thus, some substances have been investigated to act as chemical modifiers. Volumes of 20 μL of diluted samples, 1 + 1, v/v for urine and 1 + 4, v/v for serum, with HNO 3 1% v/v and 0.02% v/v of cetyl trimethyl ammonium chloride (CTAC) were prepared directly in the autosampler cups and placed into the graphite furnace. For modifiers in solutions 10 μL were used. Pyrolysis and atomization temperature curves were used in all optimizations in the matrixes diluted as exposed. For urine with permanent iridium (500 μg), the best pyrolysis and atomization temperatures were 900 and 1600 deg C, respectively, with a characteristic mass of 12 pg (recommended of 10 pg), with symmetrical absorption pulses and corrected background. Spiked urine samples presented recoveries between 86 and 112% for Ir permanent. The analysis results of certified urine samples are in agreement with certified values (95% of confidence) for two levels of the metal. For serum, good results were obtained with the mixture of Zr+Rh or Ir+Rh as permanent modifiers, with characteristic masses of 9.8 and 8.1 pg, respectively. Recoveries from spiked serum samples varied between 98.6 and 100.1% (Ir+Rh) and between 93.9 and 105.2% (Zr+Rh). In both recovery studies, the relative standard deviation (n=3) was lower than 7%. Calibration for both samples were made with aqueous calibration curves and presented r 2 higher than 0.99. The limits of detection were 0.7 μg L -1 for serum samples, with Zr+Rh permanent, and 1.0 μg L -1 for urine with iridium permanent. (author)

  1. Direct determination of lead in human urine and serum samples by electrothermal atomic absorption spectrometry and permanent modifiers

    Directory of Open Access Journals (Sweden)

    Andrada Daniel

    2006-01-01

    Full Text Available The object of the present study was the development of alternative methods for the direct determination of lead in undigested samples of human urine and serum by electrothermal atomic absorption spectrometry (ET AAS. Thus, some substances have been investigated to act as chemical modifiers. Volumes of 20 µL of diluted samples, 1 + 1, v/v for urine and 1 + 4, v/v for serum, with HNO3 1% v/v and 0.02% v/v of cetil trimethyl ammonium chloride (CTAC were prepared directly in the autosampler cups and placed into the graphite furnace. For modifiers in solutions 10 µL were used. Pyrolysis and atomization temperature curves were used in all optimizations in the matrixes diluted as exposed. For urine with permanent iridium (500 µg, the best pyrolysis and atomization temperatures were 900 and 1600 ºC, respectively, with a characteristic mass of 12 pg (recommended of 10 pg, with symmetrical absorption pulses and corrected background. Spiked urine samples presented recoveries between 86 and 112% for Ir permanent. The analysis results of certified urine samples are in agreement with certified values (95% of confidence for two levels of the metal. For serum, good results were obtained with the mixture of Zr+Rh or Ir+Rh as permanent modifiers, with characteristic masses of 9.8 and 8.1 pg, respectively. Recoveries from spiked serum samples varied between 98.6 and 100.1% (Ir+Rh and between 93.9 and 105.2% (Zr+Rh. In both recovery studies, the relative standard deviation (n=3 was lower than 7%. Calibration for both samples were made with aqueous calibration curves and presented r² higher than 0.99. The limits of detection were 0.7 µg L-1 for serum samples, with Zr+Rh permanent, and 1.0 µg L-1 for urine with iridium permanent.

  2. Bovine liver sample preparation and micro-homogeneity study for Cu and Zn determination by solid sampling electrothermal atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Nomura, Cassiana S.; Silva, Cintia S.; Nogueira, Ana R.A.; Oliveira, Pedro V.

    2005-01-01

    This work describes a systematic study for the bovine liver sample preparation for Cu and Zn determination by solid sampling electrothermal atomic absorption spectrometry. The main parameters investigated were sample drying, grinding process, particle size, sample size, microsample homogeneity, and their relationship with the precision and accuracy of the method. A bovine liver sample was prepared using different drying procedures: (1) freeze drying, and (2) drying in a household microwave oven followed by drying in a stove at 60 deg. C until constant mass. Ball and cryogenic mills were used for grinding. Less sensitive wavelengths for Cu (216.5 nm) and Zn (307.6 nm), and Zeeman-based three-field background correction for Cu were used to diminish the sensitivities. The pyrolysis and atomization temperatures adopted were 1000 deg. C and 2300 deg. C for Cu, and 700 deg. C and 1700 deg. C for Zn, respectively. For both elements, it was possible to calibrate the spectrometer with aqueous solutions. The use of 250 μg of W + 200 μg of Rh as permanent chemical modifier was imperative for Zn. Under these conditions, the characteristic mass and detection limit were 1.4 ng and 1.6 ng for Cu, and 2.8 ng and 1.3 ng for Zn, respectively. The results showed good agreement (95% confidence level) for homogeneity of the entire material (> 200 mg) when the sample was dried in microwave/stove and ground in a cryogenic mill. The microsample homogeneity study showed that Zn is more dependent on the sample pretreatment than Cu. The bovine liver sample prepared in microwave/stove and ground in a cryogenic mill presented results with the lowest relative standard deviation for Cu than Zn. Good accuracy and precision were observed for bovine liver masses higher than 40 μg for Cu and 30 μg for Zn. The concentrations of Cu and Zn in the prepared bovine liver sample were 223 mg kg - 1 and 128 mg kg - 1 , respectively. The relative standard deviations were lower than 6% (n = 5). The

  3. Multimode quantum model of a cw atom laser

    International Nuclear Information System (INIS)

    Hope, J.J.; Haine, S.A.; Savage, C.M.

    2002-01-01

    Full text: Laser cooling allows dilute atomic gases to be cooled to within K of absolute zero. Ultracold gases were first achieved twenty years ago and have since found applications in areas such as spectroscopy, time standards, frequency standards, quantum information processing and atom optics. The atomic analogue of the lasing mode in optical lasers is Bose-Einstein Condensation (BEC), in which a cooled sample of atoms condense into the lowest energy quantum state. This new state of matter was recently achieved in dilute Bose gases in 1995. Atoms coupled out of a BEC exhibit long-range spatial coherence, and provide the coldest atomic source currently available. These atomic sources are called 'atom lasers' because the BEC is analogous to the lasing mode of an optical laser. The high spectral flux from optical lasers is caused by a process called gain-narrowing, which requires continuous wave (cw) operation. Coupling a BEC quickly into an untrapped state forms a coherent atomic beam but it has a spread in momentum as large as the trapped BEC. Coupling the atoms out more slowly reduces the output linewidth at the expense of reducing the overall flux. These atom lasers are equivalent to Q-switched optical lasers. A cw atom laser with gain-narrowing would produce an increasingly monoenergetic output as the flux increased, dramatically improving the spectral flux. A cw atom laser is therefore a major goal of the atom optics community, but there are several theoretical and practical obstacles to understanding the complexities of such a system. The main obstacle to the production of a cw atom laser is the technical difficulties involved in continuously pumping the lasing mode. No complete theory exists which describes a cw atom laser. Complete cw atom laser models require a quantum field description due to their non-Markovian dynamics, significant spatial effects and the dependence of the output on the quantum statistics of the lasing mode. The extreme dimensionality

  4. Speciation and detection of arsenic in aqueous samples: A review of recent progress in non-atomic spectrometric methods

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Jian [State Key Laboratory of Marine Environmental Science, College of the Environment and Ecology, Xiamen University, Xiamen 361102 (China); Department of Chemistry and Biochemistry, University of Texas, 700 Planetarium Place, Arlington, TX 76019 (United States); Sengupta, Mrinal K. [Department of Chemistry and Biochemistry, University of Texas, 700 Planetarium Place, Arlington, TX 76019 (United States); Thermo Fisher Scientific, Dionex Products, 445 Lakeside Drive, Sunnyvale, CA, 94085 (United States); Yuan, Dongxing [State Key Laboratory of Marine Environmental Science, College of the Environment and Ecology, Xiamen University, Xiamen 361102 (China); Dasgupta, Purnendu K., E-mail: Dasgupta@uta.edu [Department of Chemistry and Biochemistry, University of Texas, 700 Planetarium Place, Arlington, TX 76019 (United States)

    2014-06-01

    Highlights: • Compilation of principal official documents and major review articles, including the toxicology and chemistry of As. • Review of non-atomic spectrometric methods for speciation and detection of arsenic in aqueous samples (2005–2013) of the performance of field-usable methods. - Abstract: Inorganic arsenic (As) displays extreme toxicity and is a class A human carcinogen. It is of interest to both analytical chemists and environmental scientists. Facile and sensitive determination of As and knowledge of the speciation of forms of As in aqueous samples are vitally important. Nearly every nation has relevant official regulations on permissible limits of drinking water As content. The size of the literature on As is therefore formidable. The heart of this review consists of two tables: one is a compilation of principal official documents and major review articles, including the toxicology and chemistry of As. This includes comprehensive official compendia on As speciation, sample treatment, recommended procedures for the determination of As in specific sample matrices with specific analytical instrument(s), procedures for multi-element (including As) speciation and analysis, and prior comprehensive reviews on arsenic analysis. The second table focuses on the recent literature (2005–2013, the coverage for 2013 is incomplete) on As measurement in aqueous matrices. Recent As speciation and analysis methods based on spectrometric and electrochemical methods, inductively coupled plasma-mass spectrometry, neutron activation analysis and biosensors are summarized. We have deliberately excluded atomic optical spectrometric techniques (atomic absorption, atomic fluorescence, inductively coupled plasma-optical emission spectrometry) not because they are not important (in fact the majority of arsenic determinations are possibly carried out by one of these techniques) but because these methods are sufficiently mature and little meaningful innovation has been

  5. A preconcentration system for determination of copper and nickel in water and food samples employing flame atomic absorption spectrometry

    OpenAIRE

    Tuzen, Mustafa; Soylak, Mustafa; Citak, Demirhan; Ferreira, Hadla S.; Korn, Maria das Graças Andrade; Bezerra, Marcos de Almeida

    2009-01-01

    Texto completo: acesso restrito. p. 1041-1045 A separation/preconcentration procedure using solid phase extraction has been proposed for the flame atomic absorption spectrometric determination of copper and nickel at trace level in food samples. The solid phase is Dowex Optipore SD-2 resin contained on a minicolumn, where analyte ions are sorbed as 5-methyl-4-(2-thiazolylazo) resorcinol chelates. After elution using 1 mol L−1 nitric acid solution, the analytes are determinate employing fla...

  6. Speciation and detection of arsenic in aqueous samples: A review of recent progress in non-atomic spectrometric methods

    International Nuclear Information System (INIS)

    Ma, Jian; Sengupta, Mrinal K.; Yuan, Dongxing; Dasgupta, Purnendu K.

    2014-01-01

    Highlights: • Compilation of principal official documents and major review articles, including the toxicology and chemistry of As. • Review of non-atomic spectrometric methods for speciation and detection of arsenic in aqueous samples (2005–2013) of the performance of field-usable methods. - Abstract: Inorganic arsenic (As) displays extreme toxicity and is a class A human carcinogen. It is of interest to both analytical chemists and environmental scientists. Facile and sensitive determination of As and knowledge of the speciation of forms of As in aqueous samples are vitally important. Nearly every nation has relevant official regulations on permissible limits of drinking water As content. The size of the literature on As is therefore formidable. The heart of this review consists of two tables: one is a compilation of principal official documents and major review articles, including the toxicology and chemistry of As. This includes comprehensive official compendia on As speciation, sample treatment, recommended procedures for the determination of As in specific sample matrices with specific analytical instrument(s), procedures for multi-element (including As) speciation and analysis, and prior comprehensive reviews on arsenic analysis. The second table focuses on the recent literature (2005–2013, the coverage for 2013 is incomplete) on As measurement in aqueous matrices. Recent As speciation and analysis methods based on spectrometric and electrochemical methods, inductively coupled plasma-mass spectrometry, neutron activation analysis and biosensors are summarized. We have deliberately excluded atomic optical spectrometric techniques (atomic absorption, atomic fluorescence, inductively coupled plasma-optical emission spectrometry) not because they are not important (in fact the majority of arsenic determinations are possibly carried out by one of these techniques) but because these methods are sufficiently mature and little meaningful innovation has been

  7. Direct determination of cadmium in Orujo spirit samples by electrothermal atomic absorption spectrometry: Comparative study of different chemical modifiers

    Energy Technology Data Exchange (ETDEWEB)

    Vilar Farinas, M. [Departamento de Quimica Analitica, Nutricion y Bromatologia, Facultad de Ciencias, Universidad de Santiago de Compostela, Campus de Lugo, 27002 Lugo (Spain); Barciela Garcia, J. [Departamento de Quimica Analitica, Nutricion y Bromatologia, Facultad de Ciencias, Universidad de Santiago de Compostela, Campus de Lugo, 27002 Lugo (Spain); Garcia Martin, S. [Departamento de Quimica Analitica, Nutricion y Bromatologia, Facultad de Ciencias, Universidad de Santiago de Compostela, Campus de Lugo, 27002 Lugo (Spain); Pena Crecente, R. [Departamento de Quimica Analitica, Nutricion y Bromatologia, Facultad de Ciencias, Universidad de Santiago de Compostela, Campus de Lugo, 27002 Lugo (Spain); Herrero Latorre, C. [Departamento de Quimica Analitica, Nutricion y Bromatologia, Facultad de Ciencias, Universidad de Santiago de Compostela, Campus de Lugo, 27002 Lugo (Spain)]. E-mail: cherrero@lugo.usc.es

    2007-05-22

    In this work, several analytical methods are proposed for cadmium determination in Orujo spirit samples using electrothermal atomic absorption spectrometry (ETAAS). Permanent chemical modifiers thermally coated on the platforms inserted in pyrolytic graphite tubes (such as W, Ir, Ru, W-Ir and W-Ru) were comparatively studied in relation to common chemical modifier mixtures [Pd-Mg(NO{sub 3}){sub 2} and (NH{sub 4})H{sub 2}PO{sub 4}-Mg(NO{sub 3}){sub 2}] for cadmium stabilization. Different ETAAS Cd determination methods based on the indicated modifiers have been developed. In each case, pyrolysis and atomization temperatures, atomization shapes, characteristic masses and detection limits as well as other analytical characteristics have been determined. All the assayed modifiers (permanent and conventional) were capable of achieving the appropriate stabilization of the analyte, with the exception of Ru and W-Ru. Moreover, for all developed methods, recoveries (99-102%) and precision (R.S.D. lower than 10%) were acceptable. Taking into account the analytical performance (best detection limit LOD = 0.01 {mu}g L{sup -1}), the ETAAS method based on the use of W as a permanent modifier was selected for further direct Cd determinations in Orujo samples from Galicia (NW Spain). The chosen method was applied in the determination of the Cd content in 38 representative Galician samples. The cadmium concentrations ranged

  8. Neutron-induced {sup 63}Ni activity and microscopic observation of copper samples exposed to the Hiroshima atomic bomb

    Energy Technology Data Exchange (ETDEWEB)

    Shizuma, Kiyoshi, E-mail: shizuma@hiroshima-u.ac.jp [Quantum Energy Applications, Department of Mechanical Science and Engineering, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527 (Japan); Endo, Satoru [Quantum Energy Applications, Department of Mechanical Science and Engineering, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527 (Japan); Shinozaki, Kenji [Materials Joining Science and Engineering, Department of Mechanical Science and Engineering, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527 (Japan); Fukushima, Hiroshi [Materials Physics, Department of Mechanical Science and Engineering, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527 (Japan)

    2013-05-01

    Fast neutron activation data for {sup 63}Ni in copper samples exposed to the Hiroshima atomic bomb are important in evaluating neutron doses to the survivors. Up to until now, accelerator mass spectrometry and liquid scintillation counting methods have been applied in {sup 63}Ni measurements and data were accumulated within 1500 m from the hypocenter. The slope of the activation curve versus distance shows reasonable agreement with the calculation result, however, data near the hypocenter are scarce. In the present work, two copper samples obtained from the Atomic bomb dome (155 m from the hypocenter) and the Bank of Japan building (392 m) were utilized in {sup 63}Ni beta-ray measurement with a Si surface barrier detector. Additionally, microscopic observation of the metal surfaces was performed for the first time. Only upper limit of {sup 63}Ni production was obtained for copper sample of the Atomic bomb dome. The result of the {sup 63}Ni measurement for Bank of Japan building show reasonable agreement with the AMS measurement and to fast neutron activation calculations based on the Dosimetry System 2002 (DS02) neutrons.

  9. Direct determination of cadmium in Orujo spirit samples by electrothermal atomic absorption spectrometry: Comparative study of different chemical modifiers

    International Nuclear Information System (INIS)

    Vilar Farinas, M.; Barciela Garcia, J.; Garcia Martin, S.; Pena Crecente, R.; Herrero Latorre, C.

    2007-01-01

    In this work, several analytical methods are proposed for cadmium determination in Orujo spirit samples using electrothermal atomic absorption spectrometry (ETAAS). Permanent chemical modifiers thermally coated on the platforms inserted in pyrolytic graphite tubes (such as W, Ir, Ru, W-Ir and W-Ru) were comparatively studied in relation to common chemical modifier mixtures [Pd-Mg(NO 3 ) 2 and (NH 4 )H 2 PO 4 -Mg(NO 3 ) 2 ] for cadmium stabilization. Different ETAAS Cd determination methods based on the indicated modifiers have been developed. In each case, pyrolysis and atomization temperatures, atomization shapes, characteristic masses and detection limits as well as other analytical characteristics have been determined. All the assayed modifiers (permanent and conventional) were capable of achieving the appropriate stabilization of the analyte, with the exception of Ru and W-Ru. Moreover, for all developed methods, recoveries (99-102%) and precision (R.S.D. lower than 10%) were acceptable. Taking into account the analytical performance (best detection limit LOD = 0.01 μg L -1 ), the ETAAS method based on the use of W as a permanent modifier was selected for further direct Cd determinations in Orujo samples from Galicia (NW Spain). The chosen method was applied in the determination of the Cd content in 38 representative Galician samples. The cadmium concentrations ranged -1

  10. Mercury in Environmental and Biological Samples Using Online Combustion with Sequential Atomic Absorption and Fluorescence Measurements: A Direct Comparison of Two Fundamental Techniques in Spectrometry

    Science.gov (United States)

    Cizdziel, James V.

    2011-01-01

    In this laboratory experiment, students quantitatively determine the concentration of an element (mercury) in an environmental or biological sample while comparing and contrasting the fundamental techniques of atomic absorption spectrometry (AAS) and atomic fluorescence spectrometry (AFS). A mercury analyzer based on sample combustion,…

  11. Lead preconcentration in synthetic samples with triton x-114 in the cloud point extraction and analysis by atomic absorption (EAAF)

    International Nuclear Information System (INIS)

    Zegarra Pisconti, Marixa; Cjuno Huanca, Jesus

    2015-01-01

    A methodology was developed about lead preconcentration in water samples that were added dithizone as complexing agent, previously dissolved in the nonionic surfactant Triton X-114, until the formation of the critical micelle concentration and the cloud point temperature. The centrifuged system gave a precipitate with high concentrations of Pb (II) that was measured by atomic absorption spectroscopy with flame (EAAF). The method has proved feasible to be implemented as a method of preconcentration and analysis of Pb in aqueous samples with concentrations less than 1 ppm. Several parameters were evaluated to obtain a percentage recovery of 89.8%. (author)

  12. Direct determination of Pb in raw milk by graphite furnace atomic absorption spectrometry (GF AAS) with electrothermal atomization sampling from slurries.

    Science.gov (United States)

    de Oliveira, Tatiane Milão; Augusto Peres, Jayme; Lurdes Felsner, Maria; Cristiane Justi, Karin

    2017-08-15

    Milk is an important food in the human diet due to its physico-chemical composition; therefore, it is necessary to monitor contamination by toxic metals such as Pb. Milk sample slurries were prepared using Triton X-100 and nitric acid for direct analysis of Pb using graphite furnace atomic absorption spectrometry - GF AAS. After dilution of the slurries, 10.00µl were directly introduced into the pyrolytic graphite tube without use of a chemical modifier, which acts as an advantage considering this type of matrix. The limits of detection and quantification were 0.64 and 2.14µgl -1 , respectively. The figures of merit studied showed that the proposed methodology without pretreatment of the raw milk sample and using external standard calibration is suitable. The methodology was applied in milk samples from the Guarapuava region, in Paraná State (Brazil) and Pb concentrations ranged from 2.12 to 37.36µgl -1 . Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Determination of cadmium and lead in urine samples after dispersive solid–liquid extraction on multiwalled carbon nanotubes by slurry sampling electrothermal atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Álvarez Méndez, J.; Barciela García, J.; García Martín, S.; Peña Crecente, R.M.; Herrero Latorre, C., E-mail: carlos.herrero@usc.es

    2015-04-01

    A new method for the determination of Cd and Pb in urine samples has been developed. The method involves dispersive solid-phase extraction (DSPE), slurry sampling (SS), and subsequent electrothermal atomic absorption spectrometry (ETAAS). Oxidized multiwalled carbon nanotubes (MWCNTs) were used as the sorbent material. The isolated MWCNT/analyte aggregates were treated with nitric acid to form a slurry and both metals were determined directly by injecting the slurry into the ETAAS-atomizer. The parameters that influence the adsorption of the metals on MWCNTs in the DSPE process, the formation and extraction of the slurry, and the ETAAS conditions were studied by different factorial design strategies. The detection and quantification limits obtained for Cd under optimized conditions were 9.7 and 32.3 ng L{sup −1}, respectively, and for Pb these limits were 0.13 and 0.43 μg L{sup −1}. The preconcentration factors achieved were 3.9 and 5.4. The RSD values (n = 10) were less than 4.1% and 5.9% for Cd and Pb, respectively. The accuracy of the method was assessed in recovery studies, with values in the range 96–102% obtained for Cd and 97–101% for Pb. In addition, the analysis of certified reference materials gave consistent results. The DSPE–SS–ETAAS method is a novel and useful strategy for the determination of Pb and Cd at low levels in human urine samples. The method is sensitive, fast, and free of matrix interferences, and it avoids the tedious and time-consuming on-column adsorption and elution steps associated with commonly used SPE procedures. The proposed method was used to determine Cd and Pb in urine samples of unexposed healthy people and satisfactory results were obtained. - Highlights: • Cd and Pb determination based on the combination of DSP, SS and ETAAS • Urine matrix was eliminated using DSPE based on multiwalled carbon nanotubes. • Slurry sampling technique permitted the direct injection of sample into the ETAAS atomizer.

  14. Magni: A Python Package for Compressive Sampling and Reconstruction of Atomic Force Microscopy Images

    Directory of Open Access Journals (Sweden)

    Christian Schou Oxvig

    2014-10-01

    Full Text Available Magni is an open source Python package that embraces compressed sensing and Atomic Force Microscopy (AFM imaging techniques. It provides AFM-specific functionality for undersampling and reconstructing images from AFM equipment and thereby accelerating the acquisition of AFM images. Magni also provides researchers in compressed sensing with a selection of algorithms for reconstructing undersampled general images, and offers a consistent and rigorous way to efficiently evaluate the researchers own developed reconstruction algorithms in terms of phase transitions. The package also serves as a convenient platform for researchers in compressed sensing aiming at obtaining a high degree of reproducibility of their research.

  15. Accuracy and Precision in Elemental Analysis of Environmental Samples using Inductively Coupled Plasma-Atomic Emission Spectrometry

    International Nuclear Information System (INIS)

    Quraishi, Shamsad Begum; Chung, Yong-Sam; Choi, Kwang Soon

    2005-01-01

    Inductively Coupled Plasma-Atomic Emission Spectrometry followed by micro-wave digestion have been performed on different environmental Certified Reference Materials (CRMs). Analytical results show that accuracy and precision in ICP-AES analysis were acceptable and satisfactory in case of soil and hair CRM samples. The relative error of most of the elements in these two CRMs is within 10% with few exceptions and coefficient of variation is also less than 10%. Z-score as an analytical performance was also within the acceptable range (±2). ICP-AES was found as an inadequate method for Air Filter CRM due to incomplete dissolution, low concentration of elements and very low mass of the sample. However, real air filter sample could have been analyzed with high accuracy and precision by increasing sample mass during collection. (author)

  16. Separation and enrichment of gold(III) from environmental samples prior to its flame atomic absorption spectrometric determination

    International Nuclear Information System (INIS)

    Senturk, Hasan Basri; Gundogdu, Ali; Bulut, Volkan Numan; Duran, Celal; Soylak, Mustafa; Elci, Latif; Tufekci, Mehmet

    2007-01-01

    A simple and accurate method was developed for separation and enrichment of trace levels of gold in environmental samples. The method is based on the adsorption of Au(III)-diethyldithiocarbamate complex on Amberlite XAD-2000 resin prior to the analysis of gold by flame atomic absorption spectrometry after elution with 1 mol L -1 HNO 3 in acetone. Some parameters including nitric acid concentration, eluent type, matrix ions, sample volume, sample flow rate and adsorption capacity were investigated on the recovery of gold(III). The recovery values for gold(III) and detection limit of gold were greater than 95% and 16.6 μg L -1 , respectively. The preconcentration factor was 200. The relative standard deviation of the method was -1 . The validation of the presented procedure was checked by the analysis of CRM-SA-C Sandy Soil certified reference material. The presented procedure was applied to the determination of gold in some environmental samples

  17. High precision optical spectroscopy and quantum state selected photodissociation of ultracold 88Sr2 molecules in an optical lattice

    Science.gov (United States)

    McDonald, Mickey

    2017-04-01

    Over the past several decades, rapid progress has been made toward the accurate characterization and control of atoms, epitomized by the ever-increasing accuracy and precision of optical atomic lattice clocks. Extending this progress to molecules will have exciting implications for chemistry, condensed matter physics, and precision tests of physics beyond the Standard Model. My thesis describes work performed over the past six years to establish the state of the art in manipulation and quantum control of ultracold molecules. We describe a thorough set of measurements characterizing the rovibrational structure of weakly bound 88Sr2 molecules from several different perspectives, including determinations of binding energies; linear, quadratic, and higher order Zeeman shifts; transition strengths between bound states; and lifetimes of narrow subradiant states. Finally, we discuss measurements of photofragment angular distributions produced by photodissociation of molecules in single quantum states, leading to an exploration of quantum-state-resolved ultracold chemistry. The images of exploding photofragments produced in these studies exhibit dramatic interference effects and strongly violate semiclassical predictions, instead requiring a fully quantum mechanical description.

  18. Simultaneous determination of Cr, Ga, In and V in soil and water samples by tungsten coil atomic emission spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Donati, George L.; Kron, Benjamin E. [Department of Chemistry, Wake Forest University, Winston-Salem, NC 27109 (United States); Jones, Bradley T. [Department of Chemistry, Wake Forest University, Winston-Salem, NC 27109 (United States)], E-mail: jonesbt@wfu.edu

    2009-06-15

    Tungsten coil atomic emission spectrometry is employed for the simultaneous determination of Cr, Ga, In, and V. Both V and In are detected by this technique for the first time. The atomizer is a simple, inexpensive tungsten filament extracted from a mass-produced, commercially-available 150 W, 15 V microscope bulb. A 25 {mu}l sample aliquot is placed directly on the coil and a small constant-current power source is used to carefully dry, ash and atomize the sample. Analytical signals are detected with a Czerny-Turner spectrograph and a charge coupled device detector. Multiple emission lines from all 4 elements are monitored simultaneously in a 54 nm spectral window. Concentration limits of detection are in the {mu}g l{sup - 1} range for all elements, and the absolute limits of detection are 0.2, 2, 0.5, and 10 ng for Cr, Ga, In, and V, respectively. Even lower values may be obtained by combining the signals for the multiple emission lines of a single element. The method precision is typically better than 5.0% relative standard deviation, and sometimes as good as 0.95% (Ga). Standard reference materials of soil and water are used to check the method accuracy. After a simple acid extraction, the values determined by the method presented no significant difference from the reported values at the 95% confidence level.

  19. Reinforced dynamics for enhanced sampling in large atomic and molecular systems

    Science.gov (United States)

    Zhang, Linfeng; Wang, Han; E, Weinan

    2018-03-01

    A new approach for efficiently exploring the configuration space and computing the free energy of large atomic and molecular systems is proposed, motivated by an analogy with reinforcement learning. There are two major components in this new approach. Like metadynamics, it allows for an efficient exploration of the configuration space by adding an adaptively computed biasing potential to the original dynamics. Like deep reinforcement learning, this biasing potential is trained on the fly using deep neural networks, with data collected judiciously from the exploration and an uncertainty indicator from the neural network model playing the role of the reward function. Parameterization using neural networks makes it feasible to handle cases with a large set of collective variables. This has the potential advantage that selecting precisely the right set of collective variables has now become less critical for capturing the structural transformations of the system. The method is illustrated by studying the full-atom explicit solvent models of alanine dipeptide and tripeptide, as well as the system of a polyalanine-10 molecule with 20 collective variables.

  20. On-line preconcentration and determination of mercury in biological and environmental samples by cold vapor-atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Ferrua, N.; Cerutti, S.; Salonia, J.A.; Olsina, R.A.; Martinez, L.D.

    2007-01-01

    An on-line procedure for the determination of traces of total mercury in environmental and biological samples is described. The present methodology combines cold vapor generation associated to atomic absorption spectrometry (CV-AAS) with preconcentration of the analyte on a minicolumn packed with activated carbon. The retained analyte was quantitatively eluted from the minicolumn with nitric acid. After that, volatile specie of mercury was generated by merging the acidified sample and sodium tetrahydroborate(III) in a continuous flow system. The gaseous analyte was subsequently introduced via a stream of Ar carrier into the atomizer device. Optimizations of both, preconcentration and mercury volatile specie generation variables were carried out using two level full factorial design (2 3 ) with 3 replicates of the central point. Considering a sample consumption of 25 mL, an enrichment factor of 13-fold was obtained. The detection limit (3σ) was 10 ng L -1 and the precision (relative standard deviation) was 3.1% (n = 10) at the 5 μg L -1 level. The calibration curve using the preconcentration system for mercury was linear with a correlation coefficient of 0.9995 at levels near the detection limit up to at least 1000 μg L -1 . Satisfactory results were obtained for the analysis of mercury in tap water and hair samples

  1. High-speed imaging upgrade for a standard sample scanning atomic force microscope using small cantilevers

    Energy Technology Data Exchange (ETDEWEB)

    Adams, Jonathan D.; Nievergelt, Adrian; Erickson, Blake W.; Yang, Chen; Dukic, Maja; Fantner, Georg E., E-mail: georg.fantner@epfl.ch [Ecole Polytechnique Fédérale de Lausanne, Lausanne (Switzerland)

    2014-09-15

    We present an atomic force microscope (AFM) head for optical beam deflection on small cantilevers. Our AFM head is designed to be small in size, easily integrated into a commercial AFM system, and has a modular architecture facilitating exchange of the optical and electronic assemblies. We present two different designs for both the optical beam deflection and the electronic readout systems, and evaluate their performance. Using small cantilevers with our AFM head on an otherwise unmodified commercial AFM system, we are able to take tapping mode images approximately 5–10 times faster compared to the same AFM system using large cantilevers. By using additional scanner turnaround resonance compensation and a controller designed for high-speed AFM imaging, we show tapping mode imaging of lipid bilayers at line scan rates of 100–500 Hz for scan areas of several micrometers in size.

  2. Optimal sample preparation for nanoparticle metrology (statistical size measurements) using atomic force microscopy

    International Nuclear Information System (INIS)

    Hoo, Christopher M.; Doan, Trang; Starostin, Natasha; West, Paul E.; Mecartney, Martha L.

    2010-01-01

    Optimal deposition procedures are determined for nanoparticle size characterization by atomic force microscopy (AFM). Accurate nanoparticle size distribution analysis with AFM requires non-agglomerated nanoparticles on a flat substrate. The deposition of polystyrene (100 nm), silica (300 and 100 nm), gold (100 nm), and CdSe quantum dot (2-5 nm) nanoparticles by spin coating was optimized for size distribution measurements by AFM. Factors influencing deposition include spin speed, concentration, solvent, and pH. A comparison using spin coating, static evaporation, and a new fluid cell deposition method for depositing nanoparticles is also made. The fluid cell allows for a more uniform and higher density deposition of nanoparticles on a substrate at laminar flow rates, making nanoparticle size analysis via AFM more efficient and also offers the potential for nanoparticle analysis in liquid environments.

  3. Nonlinear dynamics of ultracold gases in double-well lattices

    International Nuclear Information System (INIS)

    Yukalov, V I; Yukalova, E P

    2009-01-01

    An ultracold gas is considered, loaded into a lattice, each site of which is formed by a double-well potential. Initial conditions, after the loading, correspond to a nonequilibrium state. The nonlinear dynamics of the system, starting with a nonequilibrium state, is analysed in the local-field approximation. The importance of taking into account attenuation, caused by particle collisions, is emphasized. The presence of this attenuation dramatically influences the system dynamics

  4. An ultracold neutron storage bottle for UCN density measurements

    Energy Technology Data Exchange (ETDEWEB)

    Bison, G.; Burri, F.; Daum, M. [Paul Scherrer Institute (PSI), CH-5232 Villigen PSI (Switzerland); Kirch, K. [Paul Scherrer Institute (PSI), CH-5232 Villigen PSI (Switzerland); Institute for Particle Physics, Eidgenössische Technische Hochschule (ETH), Zürich (Switzerland); Krempel, J. [Institute for Particle Physics, Eidgenössische Technische Hochschule (ETH), Zürich (Switzerland); Lauss, B., E-mail: bernhard.lauss@psi.ch [Paul Scherrer Institute (PSI), CH-5232 Villigen PSI (Switzerland); Meier, M. [Paul Scherrer Institute (PSI), CH-5232 Villigen PSI (Switzerland); Ries, D., E-mail: dieter.ries@psi.ch [Paul Scherrer Institute (PSI), CH-5232 Villigen PSI (Switzerland); Institute for Particle Physics, Eidgenössische Technische Hochschule (ETH), Zürich (Switzerland); Schmidt-Wellenburg, P.; Zsigmond, G. [Paul Scherrer Institute (PSI), CH-5232 Villigen PSI (Switzerland)

    2016-09-11

    We have developed a storage bottle for ultracold neutrons (UCNs) in order to measure the UCN density at the beamports of the Paul Scherrer Institute's (PSI) UCN source. This paper describes the design, construction and commissioning of the robust and mobile storage bottle with a volume comparable to typical storage experiments (32 L) e.g. searching for an electric dipole moment of the neutron.

  5. Trapping and Evolution Dynamics of Ultracold Two-Component Plasmas

    International Nuclear Information System (INIS)

    Choi, J.-H.; Knuffman, B.; Zhang, X. H.; Povilus, A. P.; Raithel, G.

    2008-01-01

    We demonstrate the trapping of a strongly magnetized, quasineutral ultracold plasma in a nested Penning trap with a background field of 2.9 T. Electrons remain trapped in this system for several milliseconds. Early in the evolution, the dynamics are driven by a breathing-mode oscillation in the ionic charge distribution, which modulates the electron trap depth. Over longer times scales, the electronic component undergoes cooling. Trap loss resulting from ExB drift is characterized

  6. Theoretical model for ultracold molecule formation via adaptive feedback control

    OpenAIRE

    Poschinger, Ulrich; Salzmann, Wenzel; Wester, Roland; Weidemueller, Matthias; Koch, Christiane P.; Kosloff, Ronnie

    2006-01-01

    We investigate pump-dump photoassociation of ultracold molecules with amplitude- and phase-modulated femtosecond laser pulses. For this purpose a perturbative model for the light-matter interaction is developed and combined with a genetic algorithm for adaptive feedback control of the laser pulse shapes. The model is applied to the formation of 85Rb2 molecules in a magneto-optical trap. We find for optimized pulse shapes an improvement for the formation of ground state molecules by more than ...

  7. An analysis of lead (Pb) from human hair samples (20-40 years of age) by atomic absorption spectrophotometry

    Energy Technology Data Exchange (ETDEWEB)

    Gelsano, Flordeliza K; Timing, Laurie D

    2003-02-17

    This analysis of lead from human hair samples in five different groups namely scavengers from Payatas Quezon City, tricycle drivers, car shop workers, paint factory workers, and students from Polytechnic University of the Philippines. The people from Nagcarlan, Laguna represented as a ''base-line value'' or as a control group. The method applied was acid digestion using HNO{sub 3} and HClO{sub 4} then the samples were subjected to atomic absorption spectrophotometer. In terms of lead found from hair, the scavengers from Payatas Q.C. obtained high exposure of lead among the samples that were tested. The result of the analysis of concentration of lead was expressed in mg/L. (Authors)

  8. An analysis of lead (Pb) from human hair samples (20-40 years of age) by atomic absorption spectrophotometry

    International Nuclear Information System (INIS)

    Gelsano, Flordeliza K.; Timing, Laurie D.

    2003-01-01

    This analysis of lead from human hair samples in five different groups namely scavengers from Payatas Quezon City, tricycle drivers, car shop workers, paint factory workers, and students from Polytechnic University of the Philippines. The people from Nagcarlan, Laguna represented as a ''base-line value'' or as a control group. The method applied was acid digestion using HNO 3 and HClO 4 then the samples were subjected to atomic absorption spectrophotometer. In terms of lead found from hair, the scavengers from Payatas Q.C. obtained high exposure of lead among the samples that were tested. The result of the analysis of concentration of lead was expressed in mg/L. (Authors)

  9. Proton Induced X-Rays Emission (PIXE) and Atomic Absorption Spectrometry (AAS) applied in the environmental sample analysis

    International Nuclear Information System (INIS)

    Popescu, Ion V.; Iordan, M.; Stihi, C.; Bancuta, A.; Dima, G.; Busuioc, G.; Ciupina, V.; Belc, M.; Badica, T.

    2003-01-01

    The aim of this work is to determine the elemental composition of tree leaves using Proton-Induced X-Rays Emission (PIXE) and Atomic Absorption Spectrophotometry (AAS) methods. By PIXE Spectrometry we identified and determined the concentration of S, Cl, K, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu Zn, As, Br, Sr and by AAS method the concentration of elements: Cr, Mn, Fe, Co, Cu, Zn, Se, Cd. Pb was identified in only 2 samples from 29. For tree leave samples collected at a large distance to the polluting source the Sr concentration decreased and the Mg, Ca, Se, Zn and Fe concentrations increased. Also, we can observe a small affinity of these leaves for the environmental Pb which was detected for two samples at a small distance to polluting source. (authors)

  10. Assessment of crystalline disorder in cryo-milled samples of indomethacin using atomic pair-wise distribution functions

    DEFF Research Database (Denmark)

    Bøtker, Johan P; Karmwar, Pranav; Strachan, Clare J

    2011-01-01

    to analyse the cryo-milled samples. The high similarity between the ¿-indomethacin cryogenic ball milled samples and the crude ¿-indomethacin indicated that milled samples retained residual order of the ¿-form. The PDF analysis encompassed the capability of achieving a correlation with the physical......The aim of this study was to investigate the usefulness of the atomic pair-wise distribution function (PDF) to detect the extension of disorder/amorphousness induced into a crystalline drug using a cryo-milling technique, and to determine the optimal milling times to achieve amorphisation. The PDF...... properties determined from DSC, ss-NMR and stability experiments. Multivariate data analysis (MVDA) was used to visualize the differences in the PDF and XRPD data. The MVDA approach revealed that PDF is more efficient in assessing the introduced degree of disorder in ¿-indomethacin after cryo-milling than...

  11. Cloud point extraction and flame atomic absorption spectrometric determination of cadmium and nickel in drinking and wastewater samples.

    Science.gov (United States)

    Naeemullah; Kazi, Tasneem G; Shah, Faheem; Afridi, Hassan I; Baig, Jameel Ahmed; Soomro, Abdul Sattar

    2013-01-01

    A simple method for the preconcentration of cadmium (Cd) and nickel (Ni) in drinking and wastewater samples was developed. Cloud point extraction has been used for the preconcentration of both metals, after formation of complexes with 8-hydroxyquinoline (8-HQ) and extraction with the surfactant octylphenoxypolyethoxyethanol (Triton X-114). Dilution of the surfactant-rich phase with acidified ethanol was performed after phase separation, and the Cd and Ni contents were measured by flame atomic absorption spectrometry. The experimental variables, such as pH, amounts of reagents (8-HQ and Triton X-114), temperature, incubation time, and sample volume, were optimized. After optimization of the complexation and extraction conditions, enhancement factors of 80 and 61, with LOD values of 0.22 and 0.52 microg/L, were obtained for Cd and Ni, respectively. The proposed method was applied satisfactorily for the determination of both elements in drinking and wastewater samples.

  12. Strong dependence of ultracold chemical rates on electric dipole moments

    International Nuclear Information System (INIS)

    Quemener, Goulven; Bohn, John L.

    2010-01-01

    We use the quantum threshold laws combined with a classical capture model to provide an analytical estimate of the chemical quenching cross sections and rate coefficients of two colliding particles at ultralow temperatures. We apply this quantum threshold model (QT model) to indistinguishable fermionic polar molecules in an electric field. At ultracold temperatures and in weak electric fields, the cross sections and rate coefficients depend only weakly on the electric dipole moment d induced by the electric field. In stronger electric fields, the quenching processes scale as d 4(L+(1/2)) where L>0 is the orbital angular-momentum quantum number between the two colliding particles. For p-wave collisions (L=1) of indistinguishable fermionic polar molecules at ultracold temperatures, the quenching rate thus scales as d 6 . We also apply this model to pure two-dimensional collisions and find that chemical rates vanish as d -4 for ultracold indistinguishable fermions. This model provides a quick and intuitive way to estimate chemical rate coefficients of reactions occuring with high probability.

  13. Diffusion of Magnetized Binary Ionic Mixtures at Ultracold Plasma Conditions

    Science.gov (United States)

    Vidal, Keith R.; Baalrud, Scott D.

    2017-10-01

    Ultracold plasma experiments offer an accessible means to test transport theories for strongly coupled systems. Application of an external magnetic field might further increase their utility by inhibiting heating mechanisms of ions and electrons and increasing the temperature at which strong coupling effects are observed. We present results focused on developing and validating a transport theory to describe binary ionic mixtures across a wide range of coupling and magnetization strengths relevant to ultracold plasma experiments. The transport theory is an extension of the Effective Potential Theory (EPT), which has been shown to accurately model correlation effects at these conditions, to include magnetization. We focus on diffusion as it can be measured in ultracold plasma experiments. Using EPT within the framework of the Chapman-Enskog expansion, the parallel and perpendicular self and interdiffusion coefficients for binary ionic mixtures with varying mass ratios are calculated and are compared to molecular dynamics simulations. The theory is found to accurately extend Braginskii-like transport to stronger coupling, but to break down when the magnetization strength becomes large enough that the typical gyroradius is smaller than the interaction scale length. This material is based upon work supported by the Air Force Office of Scientific Research under Award Number FA9550-16-1-0221.

  14. Influence of electron evaporative cooling on ultracold plasma expansion

    International Nuclear Information System (INIS)

    Wilson, Truman; Chen, Wei-Ting; Roberts, Jacob

    2013-01-01

    The expansion of ultracold neutral plasmas (UCP) is driven primarily by the thermal pressure of the electron component and is therefore sensitive to the electron temperature. For typical UCP spatial extents, evaporative cooling has a significant influence on the UCP expansion rate at lower densities (less than 10 8 /cm 3 ). We studied the effect of electron evaporation in this density range. Owing to the low density, the effects of three-body recombination were negligible. We modeled the expansion by taking into account the change in electron temperature owing to evaporation as well as adiabatic expansion and found good agreement with our data. We also developed a simple model for initial evaporation over a range of ultracold plasma densities, sizes, and electron temperatures to determine over what parameter range electron evaporation is expected to have a significant effect. We also report on a signal calibration technique, which relates the signal at our detector to the total number of ions and electrons in the ultracold plasma

  15. Magnetic field modification of ultracold molecule-molecule collisions

    International Nuclear Information System (INIS)

    Tscherbul, T V; Suleimanov, Yu V; Aquilanti, V; Krems, R V

    2009-01-01

    We present an accurate quantum mechanical study of molecule-molecule collisions in the presence of a magnetic field. The work focuses on the analysis of elastic scattering and spin relaxation in collisions of O 2 ( 3 Σ g - ) molecules at cold (∼0.1 K) and ultracold (∼10 -6 K) temperatures. Our calculations show that magnetic spin relaxation in molecule-molecule collisions is extremely efficient except at magnetic fields below 1 mT. The rate constant for spin relaxation at T=0.1 K and a magnetic field of 0.1 T is found to be as large as 6.1x10 -11 cm -3 s -1 . The magnetic field dependence of elastic and inelastic scattering cross sections at ultracold temperatures is dominated by a manifold of Feshbach resonances with the density of ∼100 resonances per Tesla for collisions of molecules in the absolute ground state. This suggests that the scattering length of ultracold molecules in the absolute ground state can be effectively tuned in a very wide range of magnetic fields. Our calculations demonstrate that the number and properties of the magnetic Feshbach resonances are dramatically different for molecules in the absolute ground and excited spin states. The density of Feshbach resonances for molecule-molecule scattering in the low-field-seeking Zeeman state is reduced by a factor of 10.

  16. Characterizing fallout material using Cs and Pu atom ratios in environmental samples from the FDNPP fallout zone

    Science.gov (United States)

    Richards, David; Dunne, James; Martin, Peter; Scott, Tom; Yamashiki, Yosuke; Coath, Chris; Chen, Hart

    2017-04-01

    Here we report the use of combined of Cs and Pu isotope measurements to investigate the extensive plumes of radioactive fallout from the disaster at Fukishima Daiichi nuclear power plant (FNDPP) in March 2011. Among the aims of our study are improved assessment of the physico-chemical nature and changing distribution of land-based fallout. 135Cs/137Cs and 134Cs/137Cs atom ratios are indicative of conditions that relate to the nuclear fission reactions responsible for producing the respective radiocaesium isotopes, and offer much more in terms of forensic and chronological analysis than monitoring 137Cs alone. We briefly present methods to quantify the atom ratios of Cs and Pu isotopes in soil, lichen and moss samples from FDNPP catchment using mass spectrometry (ThermoTRITON for Cs and ThermoNEPTUNE for Pu). High precision data from Fukushima are presented (e.g decay corrected 135Cs/137Cs atom ratio = 0.384 ± 0.001 (n = 5) for roadside dust from Iitate region), and these are in agreement with prelimary estimates by others. We also confirm results for IAEA-330, a spinach sample collected from Polesskoe, Ukraine and subject to contamination from the Chernobyl accident. In addition to Cs isotopes, we adopt Pu isotopes to add a further dimension to the forensic analysis. We discuss the corrections required for background levels prior to the disaster, possibility for multiple components of fallout and complicating factors associated with remobilisation during the clean-up operation. In parallel with this work on digests and leaches from bulk environmental samples, we are refining methods for particle identification, isolation and characterisation using a complementary sequence of cutting-edge materials and manipulation techniques, including combined electron microscopy, focused ion beam techniques (Dualbeam), nano/micro manipulators and nano-scale imaging x-ray photoelectron spectroscopy (NanoESCA) and microCT.

  17. Detection of silver nanoparticles in parsley by solid sampling high-resolution-continuum source atomic absorption spectrometry.

    Science.gov (United States)

    Feichtmeier, Nadine S; Leopold, Kerstin

    2014-06-01

    In this work, we present a fast and simple approach for detection of silver nanoparticles (AgNPs) in biological material (parsley) by solid sampling high-resolution-continuum source atomic absorption spectrometry (HR-CS AAS). A novel evaluation strategy was developed in order to distinguish AgNPs from ionic silver and for sizing of AgNPs. For this purpose, atomisation delay was introduced as significant indication of AgNPs, whereas atomisation rates allow distinction of 20-, 60-, and 80-nm AgNPs. Atomisation delays were found to be higher for samples containing silver ions than for samples containing silver nanoparticles. A maximum difference in atomisation delay normalised by the sample weight of 6.27 ± 0.96 s mg(-1) was obtained after optimisation of the furnace program of the AAS. For this purpose, a multivariate experimental design was used varying atomisation temperature, atomisation heating rate and pyrolysis temperature. Atomisation rates were calculated as the slope of the first inflection point of the absorbance signals and correlated with the size of the AgNPs in the biological sample. Hence, solid sampling HR-CS AAS was proved to be a promising tool for identifying and distinguishing silver nanoparticles from ionic silver directly in solid biological samples.

  18. All-atom simulation study of protein PTH(1-34) by using the Wang-Landau sampling method

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Seung-Yeon [Korea National University of Transportation, Chungju (Korea, Republic of); Kwak, Woo-Seop [Chosun University, Gwangju (Korea, Republic of)

    2014-12-15

    We perform simulations of the N-terminal 34-residue protein fragment PTH(1-34), consisting of 581 atoms, of the 84-residue human parathyroid hormone by using the all-atom ECEPP/3 force field and the Wang-Landau sampling method. Through a massive high-performance computation, the density of states and the partition function Z(T), as a continuous function of T, are obtained for PTH(1-34). From the continuous partition function Z(T), the partition function zeros of PTH(1-34) are evaluated for the first time. From both the specific heat and the partition function zeros, two characteristic transition temperatures are obtained for the all-atom protein PTH(1-34). The higher transition temperature T{sub 1} and the lower transition temperature T{sub 2} of PTH(1-34) can be interpreted as the collapse temperature T{sub θ} and the folding temperature T{sub f} , respectively.

  19. Application of atomic absorption spectrophotometry to determine Cd, Cu, Pb, Zn,...in vegetable samples in Dalat

    Energy Technology Data Exchange (ETDEWEB)

    Giang, Nguyen; Tam, Nguyen Thanh; Ngoc Trinh, Le Thi; Mai, Truong Phuong; Minh, Nguyen Van [Nuclear Research Institute, Dalat (Viet Nam)

    2004-08-01

    Nowadays atomic absorption spectrometry has become valuable method for trace element analysis because high specificity; low detection litmus, easy to use; easy sample preparation, low investment and running costs... atomic absorption spectrometry is generally accepted as one the most suitable method for single - element analysis of trace elements in various kinds of materiel. In 2003, we applied flame - atomic absorption spectrometry for analyzing Ca, Cd, Cu, Pb, Zn...in vegetables and their extracted juices were collected form 11 locations of Dalat, including two kinds of vegetables (goods and safety) in both the summer and winter. Average concentration of Ca = 240 mg/kg wet, Cd = 0.035 mg/kg wet, Cu = 0.67 mg/kg wet, Mg = 131 mg/kg wet, Fe = 8.1/kg wet, Mn = 3.1/kg wet, Na = 3266 mg/kg wet, Pb = 0.345 mg/kg wet and Zn = 3.3 mg wet. In their extracted juices: Ca = 89 mg/kg wet, Cd = 0.008 mg/kg wet, Cu = 0.19 mg/kg wet, Mg = 43 mg/kg wet, Fe = 2.3 mg/kg wet, Mn = 0.61 mg/kg wet, Na = 971 mg/kg wet, Pb = 0.107 mg/kg wet and Zn = 0.65 mg/kg wet. (author)

  20. Application of atomic absorption spectrophotometry to determine Cd, Cu, Pb, Zn,...in vegetable samples in Dalat

    International Nuclear Information System (INIS)

    Nguyen Giang; Nguyen Thanh Tam; Le Thi Ngoc Trinh; Truong Phuong Mai; Nguyen Van Minh

    2004-01-01

    Nowadays atomic absorption spectrometry has become valuable method for trace element analysis because high specificity; low detection litmus, easy to use; easy sample preparation, low investment and running costs... atomic absorption spectrometry is generally accepted as one the most suitable method for single - element analysis of trace elements in various kinds of materiel. In 2003, we applied flame - atomic absorption spectrometry for analyzing Ca, Cd, Cu, Pb, Zn...in vegetables and their extracted juices were collected form 11 locations of Dalat, including two kinds of vegetables (goods and safety) in both the summer and winter. Average concentration of Ca = 240 mg/kg wet, Cd = 0.035 mg/kg wet, Cu = 0.67 mg/kg wet, Mg = 131 mg/kg wet, Fe = 8.1/kg wet, Mn = 3.1/kg wet, Na = 3266 mg/kg wet, Pb = 0.345 mg/kg wet and Zn = 3.3 mg wet. In their extracted juices: Ca = 89 mg/kg wet, Cd = 0.008 mg/kg wet, Cu = 0.19 mg/kg wet, Mg = 43 mg/kg wet, Fe = 2.3 mg/kg wet, Mn = 0.61 mg/kg wet, Na = 971 mg/kg wet, Pb = 0.107 mg/kg wet and Zn = 0.65 mg/kg wet. (author)

  1. Determination of total mercury for marine environmental monitoring studies by solid sampling continuum source high resolution atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Mandjukov, Petko; Orani, Anna Maria; Han, Eunmi; Vassileva, Emilia, E-mail: e.vasileva-veleva@iaea.org

    2015-01-01

    The most critical step in almost all commonly used analytical procedures for Hg determination is the sample preparation due to its extreme volatility. One of the possible solutions of this problem is the application of methods for direct analysis of solid samples. The possibilities for solid sampling high resolution continuum source atomic absorption spectrometry (HR CS AAS) determination of total mercury in various marine environmental samples e.g. sediments and biota are object of the present study. The instrumental parameters were optimized in order to obtain reproducible and interference free analytical signal. A calibration technique based on the use of solid standard certified reference materials similar to the nature of the analyzed sample was developed and applied to various CRMs and real samples. This technique allows simple and reliable evaluation of the uncertainty of the result and the metrological characteristics of the method. A validation approach in line with the requirements of ISO 17025 standard and Eurachem guidelines was followed. With this in mind, selectivity, working range (0.06 to 25 ng for biota and 0.025 to 4 ng for sediment samples, expressed as total Hg) linearity (confirmed by Student's t-test), bias (1.6–4.3%), repeatability (4–9%), reproducibility (9–11%), and absolute limit of detection (0.025 ng for sediment, 0.096 ng for marine biota) were systematically assessed using solid CRMs. The relative expanded uncertainty was estimated at 15% for sediment sample and 8.5% for marine biota sample (k = 2). Demonstration of traceability of measurement results is also presented. The potential of the proposed analytical procedure, based on solid sampling HR CS AAS technique was demonstrated by direct analysis of sea sediments form the Caribbean region and various CRMs. Overall, the use of solid sampling HR CS AAS permits obtaining significant advantages for the determination of this complex analyte in marine samples, such as

  2. Sub-microanalysis of solid samples with near-field enhanced atomic emission spectroscopy

    Science.gov (United States)

    Wang, Xiaohua; Liang, Zhisen; Meng, Yifan; Wang, Tongtong; Hang, Wei; Huang, Benli

    2018-03-01

    A novel approach, which we have chosen to name it as near-field enhanced atomic emission spectroscopy (NFE-AES), was proposed by introducing a scanning tunnelling microscope (STM) system into a laser-induced breakdown spectrometry (LIBS). The near-field enhancement of a laser-illuminated tip was utilized to improve the lateral resolution tremendously. Using the hybrid arrangement, pure metal tablets were analyzed to verify the performance of NFE-AES both in atmosphere and in vacuum. Due to localized surface plasmon resonance (LSPR), the incident electromagnetic field is enhanced and confined at the apex of tip, resulting in sub-micron scale ablation and elemental emission signal. We discovered that the signal-to-noise ratio (SNR) and the spectral resolution obtained in vacuum condition are better than those acquired in atmospheric condition. The quantitative capability of NFE-AES was demonstrated by analyzing Al and Pb in Cu matrix, respectively. Submicron-sized ablation craters were achieved by performing NFE-AES on a Si wafer with an Al film, and the spectroscopic information from a crater of 650 nm diameter was successfully obtained. Due to its advantage of high lateral resolution, NFE-AES imaging of micro-patterned Al lines on an integrated circuit of a SIM card was demonstrated with a sub-micron lateral resolution. These results reveal the potential of the NFE-AES technique in sub-microanalysis of solids, opening an opportunity to map chemical composition at sub-micron scale.

  3. Dating of ice and ocean samples with Atom Trap Trace Analysis of 39Ar

    OpenAIRE

    Ebser, Sven Conrad

    2018-01-01

    The noble gas radioisotope 39Ar with a half-life of 269 years is an almost ideal tracer for dating ice and water samples in the time range of 50 to 1000 years ago, for which no other reliable methods exist. Due to its very low relative abundance of 39Ar/Ar = 8.1(3)*10^-16, 39Ar has only been routinely measured by Low-Level Counting so far. However, since Low-Level Counting requires samples in the order of 1000 L, the application of 39Ar, besides some proof-of-principle experiments, has been l...

  4. Direct analysis of Antarctic krill by slurry sampling: determination of copper, iron, manganese and zinc by flame atomic absorption spectrometry

    Directory of Open Access Journals (Sweden)

    Alves Flávia L.

    2000-01-01

    Full Text Available Slurry sampling in combination with flame atomic absorption spectrometry was employed for the direct determination of four essential trace elements, namely Cu, Fe, Mn and Zn in Antarctic krill. The effect of instrumental operating conditions and slurry sampling preparation on the analytical signal was investigated. For the determination of Cu, Fe and Zn, samples were suspended in a solution containing 2 mol L-1 HNO3. In the case of Mn, 4 mol L-1 HNO3 was necessary for the preparation of the slurry. The precision between sample replicates was better than 5%. The method was applied to the direct determination of Cu, Fe, Mn and Zn in Antarctic krill samples using aqueous reference solutions to prepare the calibration curves. The results obtained were in good agreement with those achieved by FAAS and ICP-AES after microwave-assisted wet digestion of the krill samples. The detection limits were 4.5, 1.0, 4.9 and 8.4 mug L-1 for Cu, Zn, Mn and Fe, respectively.

  5. Application of Atomic Dielectric Resonance Spectroscopy for the screening of blood samples from patients with clinical variant and sporadic CJD

    Directory of Open Access Journals (Sweden)

    Ironside James W

    2007-08-01

    Full Text Available Abstract Background Sub-clinical variant Creutzfeldt-Jakob disease (vCJD infection and reports of vCJD transmission through blood transfusion emphasise the need for blood screening assays to ensure the safety of blood and transplanted tissues. Most assays aim to detect abnormal prion protein (PrPSc, although achieving required sensitivity is a challenge. Methods We have used innovative Atomic Dielectric Resonance Spectroscopy (ADRS, which determines dielectric properties of materials which are established by reflectivity and penetration of radio/micro waves, to analyse blood samples from patients and controls to identify characteristic ADR signatures unique to blood from vCJD and to sCJD patients. Initial sets of blood samples from vCJD, sCJD, non-CJD neurological diseases and normal healthy adults (blood donors were screened as training samples to determine group-specific ADR characteristics, and provided a basis for classification of blinded sets of samples. Results Blood sample groups from vCJD, sCJD, non-CJD neurological diseases and normal healthy adults (blood donors screened by ADRS were classified with 100% specificity and sensitivity, discriminating these by a co-variance expert analysis system. Conclusion ADRS appears capable of recognising and discriminating serum samples from vCJD, sCJD, non-CJD neurological diseases, and normal healthy adults, and might be developed to provide a system for primary screening or confirmatory assay complementary to other screening systems.

  6. Application of Atomic Dielectric Resonance Spectroscopy for the screening of blood samples from patients with clinical variant and sporadic CJD

    Science.gov (United States)

    Fagge, Timothy J; Barclay, G Robin; Stove, G Colin; Stove, Gordon; Robinson, Michael J; Head, Mark W; Ironside, James W; Turner, Marc L

    2007-01-01

    Background Sub-clinical variant Creutzfeldt-Jakob disease (vCJD) infection and reports of vCJD transmission through blood transfusion emphasise the need for blood screening assays to ensure the safety of blood and transplanted tissues. Most assays aim to detect abnormal prion protein (PrPSc), although achieving required sensitivity is a challenge. Methods We have used innovative Atomic Dielectric Resonance Spectroscopy (ADRS), which determines dielectric properties of materials which are established by reflectivity and penetration of radio/micro waves, to analyse blood samples from patients and controls to identify characteristic ADR signatures unique to blood from vCJD and to sCJD patients. Initial sets of blood samples from vCJD, sCJD, non-CJD neurological diseases and normal healthy adults (blood donors) were screened as training samples to determine group-specific ADR characteristics, and provided a basis for classification of blinded sets of samples. Results Blood sample groups from vCJD, sCJD, non-CJD neurological diseases and normal healthy adults (blood donors) screened by ADRS were classified with 100% specificity and sensitivity, discriminating these by a co-variance expert analysis system. Conclusion ADRS appears capable of recognising and discriminating serum samples from vCJD, sCJD, non-CJD neurological diseases, and normal healthy adults, and might be developed to provide a system for primary screening or confirmatory assay complementary to other screening systems. PMID:17760958

  7. Solid sample atomic absorption spectroscopy in a chemical contaminant monitoring pilot project

    Energy Technology Data Exchange (ETDEWEB)

    Klein, J.; Schmidt, H.; Dirscherl, C.; Muntau, H.

    1987-09-01

    The Institute for Technology and Hygiene of Food of Animal Origin is developing a practible system of monitoring the distribution of toxic substances in the environment, using the dairy cows as bioindicators. A pilot project has been established to solve basic problems as sampling strategy, sample preparation, analysis and data handling. In the preliminary stage of this study the new technique of SS-AAS turned out to be a useful tool. In order to test overall analytical reliability of the data obtained all analytical procedures applied for the different matrices are controlled by the use of reference material of similar matrix compositions. Results of studies on the distribution of admium and lead are reported; the representativity of small sample amounts of cortical tissue (50-60 mg and 1-2 mg dry mass) has additionally been investigated. Direct analysis of wet tissue aliquots (5-10 mg) was not feasible. A possible method of sample preparation of wet tissue is presented which yields reliable results within 10 min of operation time.

  8. A preconcentration system for determination of copper and nickel in water and food samples employing flame atomic absorption spectrometry.

    Science.gov (United States)

    Tuzen, Mustafa; Soylak, Mustafa; Citak, Demirhan; Ferreira, Hadla S; Korn, Maria G A; Bezerra, Marcos A

    2009-03-15

    A separation/preconcentration procedure using solid phase extraction has been proposed for the flame atomic absorption spectrometric determination of copper and nickel at trace level in food samples. The solid phase is Dowex Optipore SD-2 resin contained on a minicolumn, where analyte ions are sorbed as 5-methyl-4-(2-thiazolylazo) resorcinol chelates. After elution using 1 mol L(-1) nitric acid solution, the analytes are determinate employing flame atomic absorption spectrometry. The optimization step was performed using a full two-level factorial design and the variables studied were: pH, reagent concentration (RC) and amount of resin on the column (AR). Under the experimental conditions established in the optimization step, the procedure allows the determination of copper and nickel with limit of detection of 1.03 and 1.90 microg L(-1), respectively and precision of 7 and 8%, for concentrations of copper and nickel of 200 microg L(-1). The effect of matrix ions was also evaluated. The accuracy was confirmed by analyzing of the followings certified reference materials: NIST SRM 1515 Apple leaves and GBW 07603 Aquatic and Terrestrial Biological Products. The developed method was successfully applied for the determination of copper and nickel in real samples including human hair, chicken meat, black tea and canned fish.

  9. A preconcentration system for determination of copper and nickel in water and food samples employing flame atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Tuzen, Mustafa; Soylak, Mustafa; Citak, Demirhan; Ferreira, Hadla S.; Korn, Maria G.A.; Bezerra, Marcos A.

    2009-01-01

    A separation/preconcentration procedure using solid phase extraction has been proposed for the flame atomic absorption spectrometric determination of copper and nickel at trace level in food samples. The solid phase is Dowex Optipore SD-2 resin contained on a minicolumn, where analyte ions are sorbed as 5-methyl-4-(2-thiazolylazo) resorcinol chelates. After elution using 1 mol L -1 nitric acid solution, the analytes are determinate employing flame atomic absorption spectrometry. The optimization step was performed using a full two-level factorial design and the variables studied were: pH, reagent concentration (RC) and amount of resin on the column (AR). Under the experimental conditions established in the optimization step, the procedure allows the determination of copper and nickel with limit of detection of 1.03 and 1.90 μg L -1 , respectively and precision of 7 and 8%, for concentrations of copper and nickel of 200 μg L -1 . The effect of matrix ions was also evaluated. The accuracy was confirmed by analyzing of the followings certified reference materials: NIST SRM 1515 Apple leaves and GBW 07603 Aquatic and Terrestrial Biological Products. The developed method was successfully applied for the determination of copper and nickel in real samples including human hair, chicken meat, black tea and canned fish

  10. A preconcentration system for determination of copper and nickel in water and food samples employing flame atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Tuzen, Mustafa [Department of Chemistry, Gaziosmanpasa University, 60250 Tokat (Turkey); Soylak, Mustafa [Department of Chemistry, Erciyes University, 38039 Kayseri (Turkey)], E-mail: soylak@erciyes.edu.tr; Citak, Demirhan [Department of Chemistry, Gaziosmanpasa University, 60250 Tokat (Turkey); Ferreira, Hadla S.; Korn, Maria G.A. [Universidade Federal da Bahia, Instituto de Quimica, 40170-290 Salvador (Brazil); Bezerra, Marcos A. [Universidade Estadual do Sudoeste da Bahia, 45200-190 Jequie (Brazil)

    2009-03-15

    A separation/preconcentration procedure using solid phase extraction has been proposed for the flame atomic absorption spectrometric determination of copper and nickel at trace level in food samples. The solid phase is Dowex Optipore SD-2 resin contained on a minicolumn, where analyte ions are sorbed as 5-methyl-4-(2-thiazolylazo) resorcinol chelates. After elution using 1 mol L{sup -1} nitric acid solution, the analytes are determinate employing flame atomic absorption spectrometry. The optimization step was performed using a full two-level factorial design and the variables studied were: pH, reagent concentration (RC) and amount of resin on the column (AR). Under the experimental conditions established in the optimization step, the procedure allows the determination of copper and nickel with limit of detection of 1.03 and 1.90 {mu}g L{sup -1}, respectively and precision of 7 and 8%, for concentrations of copper and nickel of 200 {mu}g L{sup -1}. The effect of matrix ions was also evaluated. The accuracy was confirmed by analyzing of the followings certified reference materials: NIST SRM 1515 Apple leaves and GBW 07603 Aquatic and Terrestrial Biological Products. The developed method was successfully applied for the determination of copper and nickel in real samples including human hair, chicken meat, black tea and canned fish.

  11. Determination of daily intake of elements from Philippine total diet samples using inductively coupled plasma-atomic emission spectrometry

    International Nuclear Information System (INIS)

    Leon, G.C. de; Shiraishi, K.; Kawamura, H.; Igaraishi, Y.; Palattao, M.V.; Azanon, E.M.

    1990-10-01

    Total diet samples were analyzed for major elements (Na, K, Ca, Mg, P) and some minor trace elements (Fe, Zn, Mn, Al, Sr, Cu, Ba, Yt) using inductively coupled plasma-atomic emission spectrometry (ICP-AES). Samples analyzed were classified into sex and age groups. Results for some elements (Na, K, Mg, Zn, Cu, Mn) were compared with values from Bataan dietary survey calculated using the Philippine composition table. Exceot for Na, analytical results were similar to calculated values. Analytical results for Ca and Fe were also compared with the values from Food and Nutrition Research Institute. In general, values obtained in the study were lower than the FNRI values. Comparison of the analytical and calculated results with the Japanese and ICRP data showed that Philippine values were lower than foreign values. (Auth.). 22 refs., 9 tabs

  12. Study of the relationship between peaks scattering Rayleigh to Compton ratio and effective atomic number in biological samples

    International Nuclear Information System (INIS)

    Pereira, Marcelo O.; Conti, Claudio de Carvalho; Anjos, Marcelino J.; Lopes, Ricardo T.

    2011-01-01

    The aim of this work was to develop a new method to correct the absorbed radiation (the mass attenuation coefficient curve) in low energy (E B O 3 , Na 2 CO 3 , CaCO 3 , Al 2 O 3 , K 2 SO 4 and MgO) of radiation produced by a gamma-ray source of Am-241(59.54 keV) also applied to certified biological samples of milk powder, hay powder and bovine liver (NIST 155 7B). In addition, six methods of effective atomic number determination were used as described in literature to determinate the Rayleigh to Compton scattering ratio (R/C) , in order to calculate the mass attenuation coefficient. The results obtained by the proposed method were compared with those obtained using the transmission method. The experimental results were in good agreement with transmission values suggesting that the method to correct radiation absorption presented in this paper is adequate for biological samples. (author)

  13. Interaction of antihydrogen with ordinary atoms and solid surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Froelich, Piotr, E-mail: piotr.froelich@kvac.uu.se; Voronin, Alexei [P.N. Lebedev Physical Institute (Russian Federation)

    2012-12-15

    The characteristic features of cold atom-antiatom collisions and antiatom-surface interactions are discussed and illustrated by the results for hydrogen-antihydrogen scattering and for quantum reflection of ultracold antihydrogen from a metallic surface. We discuss in some detail the case of spin-exchange in ultracold H-bar - H collisions, exposing the interplay of Coulombic, strong and dispersive forces, and demonstrating the sensitivity of the spin-exchange cross sections to hypothetical violations of Charge-Parity-Time (CPT) symmetry.

  14. Determination of total mercury for marine environmental monitoring studies by solid sampling continuum source high resolution atomic absorption spectrometry

    Science.gov (United States)

    Mandjukov, Petko; Orani, Anna Maria; Han, Eunmi; Vassileva, Emilia

    2015-01-01

    The most critical step in almost all commonly used analytical procedures for Hg determination is the sample preparation due to its extreme volatility. One of the possible solutions of this problem is the application of methods for direct analysis of solid samples. The possibilities for solid sampling high resolution continuum source atomic absorption spectrometry (HR CS AAS) determination of total mercury in various marine environmental samples e.g. sediments and biota are object of the present study. The instrumental parameters were optimized in order to obtain reproducible and interference free analytical signal. A calibration technique based on the use of solid standard certified reference materials similar to the nature of the analyzed sample was developed and applied to various CRMs and real samples. This technique allows simple and reliable evaluation of the uncertainty of the result and the metrological characteristics of the method. A validation approach in line with the requirements of ISO 17025 standard and Eurachem guidelines was followed. With this in mind, selectivity, working range (0.06 to 25 ng for biota and 0.025 to 4 ng for sediment samples, expressed as total Hg) linearity (confirmed by Student's t-test), bias (1.6-4.3%), repeatability (4-9%), reproducibility (9-11%), and absolute limit of detection (0.025 ng for sediment, 0.096 ng for marine biota) were systematically assessed using solid CRMs. The relative expanded uncertainty was estimated at 15% for sediment sample and 8.5% for marine biota sample (k = 2). Demonstration of traceability of measurement results is also presented. The potential of the proposed analytical procedure, based on solid sampling HR CS AAS technique was demonstrated by direct analysis of sea sediments form the Caribbean region and various CRMs. Overall, the use of solid sampling HR CS AAS permits obtaining significant advantages for the determination of this complex analyte in marine samples, such as straightforward

  15. Low-energy-spread ion bunches from a trapped atomic gas

    NARCIS (Netherlands)

    Reijnders, M.P.; Kruisbergen, van P.A.; Taban, G.; Geer, van der S.B.; Mutsaers, P.H.A.; Vredenbregt, E.J.D.; Luiten, O.J.

    2009-01-01

    We present time-of-flight measurements of the longitudinal energy spread of pulsed ultracold ion beams, produced by near-threshold ionization of rubidium atoms captured in a magneto-optical atom trap. Well-defined pulsed beams have been produced with energies of only 1 eV and a root-mean-square

  16. Measurement of integrated coefficients of ultracold neutron reflection from solid surfaces

    International Nuclear Information System (INIS)

    Golikov, V.V.; Kulagin, E.N.; Nikitenko, Yu.V.

    1985-01-01

    The method of measurement of the integrated coefficients of ultracold neutrons (UCN) reflection from solid surfaces is reported. A simple formula is suggested which expresses the integrated coefficients of UCN reflection from a given sample through the measured counting rate of the detector with and without strong absorber (polyethelene). The parameters are determined describing anisotropic and inhomogeneity properties of UCN reflection from Al, Mg, Pb, Zn, Mo, stainless steel, T and V are measured. The thickness of oxide layers is determined within the 5-10A accuracy limits from the experimental coefficients of UCN reflection from metals having on their surfaces the oxides with boundary velocity larger than that for the metal. It has been determined that the density of 5000 A layer of heavy ice freezed on aluminium is 0.83 +- 0.05 from the crystal ice density

  17. Characterization and development of diamond-like carbon coatings for storing ultracold neutrons

    CERN Document Server

    Grinten, M G D; Shiers, D; Baker, C A; Green, K; Harris, P G; Iaydjiev, P S; Ivanov, S N; Geltenbort, P

    1999-01-01

    In order to determine the suitability of diamond-like carbon (DLC) as a material for storing ultracold neutrons to use in neutron electric-dipole moment (EDM) experiments, a number of tests on DLC coatings have been performed. Thin DLC layers deposited on quartz and aluminium substrates by chemical vapour deposition have been characterised by neutron transmission, neutron reflectometry, electron microscopy and neutron and mercury storage and depolarisation lifetime measurements. Two types of DLC have been compared; DLC made by chemical vapour deposition from natural methane and DLC made by chemical vapour deposition from deuterated methane. With these samples we determined the density, hydrogen concentration and Fermi potential of the coatings. DLC coatings made from deuterated methane are now successfully being used in an experiment to measure the EDM of the neutron.

  18. Characterization and development of diamond-like carbon coatings for storing ultracold neutrons

    International Nuclear Information System (INIS)

    Grinten, M.G.D. van der; Pendlebury, J.M.; Shiers, D.; Baker, C.A.; Green, K.; Harris, P.G.; Iaydjiev, P.S.; Ivanov, S.N.; Geltenbort, P.

    1999-01-01

    In order to determine the suitability of diamond-like carbon (DLC) as a material for storing ultracold neutrons to use in neutron electric-dipole moment (EDM) experiments, a number of tests on DLC coatings have been performed. Thin DLC layers deposited on quartz and aluminium substrates by chemical vapour deposition have been characterised by neutron transmission, neutron reflectometry, electron microscopy and neutron and mercury storage and depolarisation lifetime measurements. Two types of DLC have been compared; DLC made by chemical vapour deposition from natural methane and DLC made by chemical vapour deposition from deuterated methane. With these samples we determined the density, hydrogen concentration and Fermi potential of the coatings. DLC coatings made from deuterated methane are now successfully being used in an experiment to measure the EDM of the neutron

  19. Determination of mercury in ash and soil samples by oxygen flask combustion method-Cold vapor atomic fluorescence spectrometry (CVAFS)

    International Nuclear Information System (INIS)

    Geng Wenhua; Nakajima, Tsunenori; Takanashi, Hirokazu; Ohki, Akira

    2008-01-01

    A simple method was developed for the determination of mercury (Hg) in coal fly ash (CFA), waste incineration ash (WIA), and soil by use of oxygen flask combustion (OFC) followed by cold vapor atomic fluorescence spectrometry (CVAFS). A KMnO 4 solution was used as an absorbent in the OFC method, and the sample containing a combustion agent and an ash or soil sample was combusted by the OFC method. By use of Hg-free graphite as the combustion agent, the determination of Hg in ash and soil was successfully carried out; the Hg-free graphite was prepared by use of a mild pyrolysis procedure at 500 deg. C. For six certified reference materials (three CFA samples and three soil samples), the values of Hg obtained by this method were in good agreement with the certified or reference values. In addition, real samples including nine CFAs collected from some coal-fired power plants, five WIAs collected from waste incineration plants, and two soils were analyzed by the present method, and the data were compared to those from microwave-acid digestion (MW-AD) method

  20. A non-destructive technique for assigning effective atomic number to scientific samples by scattering of 59.54 keV gamma photons

    International Nuclear Information System (INIS)

    Singh, M.P.; Sharma, Amandeep; Singh, Bhajan; Sandhu, B.S.

    2010-01-01

    The objective of present experiment, employing a scattering of 59.54 keV gamma photons, is to assign effective atomic number (Z eff ) to scientific samples (rare earths) of known composition. An HPGe semiconductor detector, placed at 90 o to the incident beam, detects gamma photons scattered from the sample under investigation. The experiment is performed on various elements with atomic number satisfying, 6≤Z≤82, for 59.54 keV incident photons. The intensity ratio of Rayleigh to Compton scattered peaks, corrected for photo-peak efficiency of gamma detector and absorption of photons in the sample and air, is plotted as a function of atomic number and constituted a best fit-curve. From this fit-curve, the respective effective atomic numbers to samples of rare earths are determined. The agreement of measured values of Z eff with theoretical calculations is quite satisfactory.

  1. Electric field gradient calculation at atomic site of In implanted ZnO samples

    International Nuclear Information System (INIS)

    Abreu, Y.; Cruz, C. M.; Leyva, A.; Pinnera; Van Espen, P.; Perez, C.

    2011-01-01

    The electric field gradient (EFG) calculated for 111 In→ 111 Cd implanted ZnO samples is reported. The study was made for ideal hexagonal ZnO structures and super-cells considering the In implantation environment at the cation site using the 'WIEN2k' code within the GGA(+U) approximation. The obtained EFG values are in good agreement with the experimental reports for ideal ZnO and 111 In→ 111 Cd implanted structures; measured by perturbed angular correlation (PAC) and Moessbauer spectroscopy. The attribution of substitutional incorporation of 111 In at the ZnO cation site after annealing was confirmed. (Author)

  2. High-resolution imaging of ultracold fermions in microscopically tailored optical potentials

    International Nuclear Information System (INIS)

    Zimmermann, B; Mueller, T; Meineke, J; Esslinger, T; Moritz, H

    2011-01-01

    We report on the local probing and preparation of an ultracold Fermi gas on the length scale of one micrometer, i.e. of the order of the Fermi wavelength. The essential tool of our experimental setup is a pair of identical, high-resolution microscope objectives. One of the microscope objectives allows local imaging of the trapped Fermi gas of 6 Li atoms with a maximum resolution of 660 nm, while the other enables the generation of arbitrary optical dipole potentials on the same length scale. Employing a two-dimensional (2D) acousto-optical deflector, we demonstrate the formation of several trapping geometries, including a tightly focused single optical dipole trap, a 4x4 site 2D optical lattice and an 8 site ring lattice configuration. Furthermore, we show the ability to load and detect a small number of atoms in these trapping potentials. A site separation down to one micrometer in combination with the low mass of 6 Li results in tunneling rates that are sufficiently large for the implementation of Hubbard models with the designed geometries.

  3. Damping of electron center-of-mass oscillation in ultracold plasmas

    International Nuclear Information System (INIS)

    Chen, Wei-Ting; Witte, Craig; Roberts, Jacob L.

    2016-01-01

    Applying a short electric field pulse to an ultracold plasma induces an electron plasma oscillation. This manifests itself as an oscillation of the electron center of mass around the ion center of mass in the ultracold plasma. In general, the oscillation can damp due to either collisionless or collisional mechanisms, or a combination of the both. To investigate the nature of oscillation damping in ultracold plasmas, we developed a molecular dynamics model of the ultracold plasma electrons. Through this model, we found that depending on the neutrality of the ultracold plasma and the size of an applied DC electric field, there are some parameter ranges where the damping is primarily collisional and some primarily collisionless. We conducted experiments to compare the measured damping rate with theory predictions and found them to be in good agreement. Extension of our measurements to different parameter ranges should enable studies for strong-coupling influence on electron-ion collision rates.

  4. Time-Dependent Wave Packet Dynamics Calculations of Cross Sections for Ultracold Scattering of Molecules

    Science.gov (United States)

    Huang, Jiayu; Liu, Shu; Zhang, Dong H.; Krems, Roman V.

    2018-04-01

    Because the de Broglie wavelength of ultracold molecules is very large, the cross sections for collisions of molecules at ultracold temperatures are always computed by the time-independent quantum scattering approach. Here, we report the first accurate time-dependent wave packet dynamics calculation for reactive scattering of ultracold molecules. Wave packet dynamics calculations can be applied to molecular systems with more dimensions and provide real-time information on the process of bond rearrangement and/or energy exchange in molecular collisions. Our work thus makes possible the extension of rigorous quantum calculations of ultracold reaction properties to polyatomic molecules and adds a new powerful tool for the study of ultracold chemistry.

  5. Method validation for control determination of mercury in fresh fish and shrimp samples by solid sampling thermal decomposition/amalgamation atomic absorption spectrometry.

    Science.gov (United States)

    Torres, Daiane Placido; Martins-Teixeira, Maristela Braga; Cadore, Solange; Queiroz, Helena Müller

    2015-01-01

    A method for the determination of total mercury in fresh fish and shrimp samples by solid sampling thermal decomposition/amalgamation atomic absorption spectrometry (TDA AAS) has been validated following international foodstuff protocols in order to fulfill the Brazilian National Residue Control Plan. The experimental parameters have been previously studied and optimized according to specific legislation on validation and inorganic contaminants in foodstuff. Linearity, sensitivity, specificity, detection and quantification limits, precision (repeatability and within-laboratory reproducibility), robustness as well as accuracy of the method have been evaluated. Linearity of response was satisfactory for the two range concentrations available on the TDA AAS equipment, between approximately 25.0 and 200.0 μg kg(-1) (square regression) and 250.0 and 2000.0 μg kg(-1) (linear regression) of mercury. The residues for both ranges were homoscedastic and independent, with normal distribution. Correlation coefficients obtained for these ranges were higher than 0.995. Limits of quantification (LOQ) and of detection of the method (LDM), based on signal standard deviation (SD) for a low-in-mercury sample, were 3.0 and 1.0 μg kg(-1), respectively. Repeatability of the method was better than 4%. Within-laboratory reproducibility achieved a relative SD better than 6%. Robustness of the current method was evaluated and pointed sample mass as a significant factor. Accuracy (assessed as the analyte recovery) was calculated on basis of the repeatability, and ranged from 89% to 99%. The obtained results showed the suitability of the present method for direct mercury measurement in fresh fish and shrimp samples and the importance of monitoring the analysis conditions for food control purposes. Additionally, the competence of this method was recognized by accreditation under the standard ISO/IEC 17025.

  6. Arsenic speciation in environmental samples by hydride generation and electrothermal atomic absorption spectrometry.

    Science.gov (United States)

    Anawar, Hossain Md

    2012-01-15

    For the past few years many studies have been performed to determine arsenic (As) speciation in drinking water, food chain and other environmental samples due to its well-recognized carcinogenic and toxic effects relating to its chemical forms and oxidation states. This review provides an overview of analytical methods, preconcentration and separation techniques, developed up to now, using HGAAS and ETAAS for the determination of inorganic As and organoarsenic species in environmental samples. Specific advantages, disadvantages, selectivity, sensitivity, efficiency, rapidity, detection limit (DL), and some aspects of recent improvements and modifications for different analytical and separation techniques, that can define their application for a particular sample analysis, are highlighted. HG-AAS has high sensitivity, selectivity and low DL using suitable separation techniques; and it is a more suitable, affordable and much less expensive technique than other detectors. The concentrations of HCl and NaBH(4) have a critical effect on the HG response of As species. Use of l-cysteine as pre-reductant is advantageous over KI to obtain the same signal response for different As species under the same, optimum and mild acid concentration, and to reduce the interference of transition metals on the arsine generation. Use of different pretreatment, digestion, separation techniques and surfactants can determine As species with DL from ngL(-1) to μgL(-1). Out of all the chromatographic techniques coupled with HGAAS/ETAAS, ion-pair reversed-phase chromatography (IP-RP) is the most popular due to its higher separation efficiency, resolution selectivity, simplicity, and ability to separate up to seven As species for both non-ionic and ionic compounds in a signal run using the same column and short time. However, a combination of anion- and cation-exchange chromatography seems the most promising for complete resolution up to eight As species. The ETAAS method using different

  7. Solid sampling-graphite furnace atomic absorption spectrometry for the direct determination of boron in plant tissues

    International Nuclear Information System (INIS)

    Resano, M.; Briceno, J.; Aramendia, M.; Belarra, M.A.

    2007-01-01

    In this work, the potential of graphite furnace atomic absorption spectrometry for the direct determination of B in plant tissues has been investigated. Three certified reference materials (NIST SRM 1570a spinach leaves, NIST SRM 1573a tomato leaves and BCR CRM 679 white cabbage) were selected for this study, the goal always being to develop a fast procedure that could be robust enough to provide a satisfactory performance for all of them, without any modifications in the conditions applied. The use of a suitable chemical modifier was found to be essential for obtaining a reproducible and sufficiently sensitive signal for boron solutions. In this regard, the performance of the combination of citric acid plus W (added as a permanent modifier) was noteworthy, resulting in well-defined signal profiles, a remarkable analyte stabilization during the pyrolysis step (up to 2100 deg. C) and minimal memory effects. This mixture of modifiers provided a good performance for the direct analysis of solid samples as well, but only if a suitable temperature program, favoring the interaction between the analyte and the modifiers, was used. Thus, such a temperature program, with two pyrolysis steps and the addition of NH 4 NO 3 in order to carry out the in situ sample microdigestion, was optimized. Under these conditions, the peak areas obtained for both solid samples and aqueous standards were comparable. Finally, the analysis of the samples was carried out. In all cases, a good agreement with the certified values was obtained, while R.S.D. values ranged between 6 and 10%. It can be concluded that the method proposed shows significant advantages for the determination of this complicated element in solid samples such as the use of aqueous standards for calibration, a high sample throughput (20 min per sample), a suitable limit of detection (0.3 μg g -1 ) and reduced risk of analyte losses and contamination

  8. Flame Atomic Absorption Determination of Gold Ion in Aqueous Samples after Preconcentration Using 9-Acridinylamine Functionalized γ-Alumina Nanoparticles

    Directory of Open Access Journals (Sweden)

    Mohammad Karimi

    2013-01-01

    Full Text Available A simple and sensitive solid phase extraction utilizing 9-acridinylamine functionalized alumina nanoparticles was developed, and their potential use for preconcentration and subsequent determination of gold by flame atomic absorption spectrometry (FAAS was investigated. A number of parameters, namely, type, concentration, and volume of eluent, pH of the sample solution, flow rate of extraction, and volume of the sample, were evaluated. The effect of a variety of ions on preconcentration and recovery was also investigated. Gold ions were found to be recovered quantitatively at pH 3.0, with 0.1 mol L−1 thiourea in 2 mol L−1 H2SO4 as eluent. The limit of detection (LOD, defined as five times the standard deviation of the blank, was determined to be lower than 13.0 ppb. Under optimum conditions, the accuracy and precision (RSD% of the method were >98.0 and <1.5%, respectively. To gauge its ability in terms of application to real samples, the proposed method was successfully applied for determination of gold concentration in waste water samples and one soil standard material, and satisfactory results were obtained.

  9. In-situ suspended aggregate microextraction of gold nanoparticles from water samples and determination by electrothermal atomic absorption spectrometry.

    Science.gov (United States)

    Choleva, Tatiana G; Kappi, Foteini A; Tsogas, George Z; Vlessidis, Athanasios G; Giokas, Dimosthenis L

    2016-05-01

    This work describes a new method for the extraction and determination of gold nanoparticles in environmental samples by means of in-situ suspended aggregate microextraction and electrothermal atomic absorption spectrometry. The method relies on the in-situ formation of a supramolecular aggregate phase through ion-association between a cationic surfactant and a benzene sulfonic acid derivative. Gold nanoparticles are physically entrapped into the aggregate phase which is separated from the bulk aqueous solution by vacuum filtration on the surface of a cellulose filter in the form of a thin film. The film is removed from the filter surface and is dissociated into an acidified methanolic solution which is used for analysis. Under the optimized experimental conditions, gold nanoparticles can be efficiently extracted from water samples with recovery rates between 81.0-93.3%, precision 5.4-12.0% and detection limits as low as 75femtomolL(-1) using only 20mL of sample volume. The satisfactory analytical features of the method along with the simplicity indicate the efficiency of this new approach to adequately collect and extract gold nanoparticle species from water samples. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. Separation and enrichment of gold(III) from environmental samples prior to its flame atomic absorption spectrometric determination

    Energy Technology Data Exchange (ETDEWEB)

    Senturk, Hasan Basri; Gundogdu, Ali [Department of Chemistry, Faculty of Arts and Sciences, Karadeniz Technical University, 61080 Trabzon (Turkey); Bulut, Volkan Numan [Department of Chemistry, Faculty of Arts and Sciences, Karadeniz Technical University, 28049 Giresun (Turkey); Duran, Celal [Department of Chemistry, Faculty of Arts and Sciences, Karadeniz Technical University, 61080 Trabzon (Turkey); Soylak, Mustafa [Department of Chemistry, Faculty of Arts and Sciences, Erciyes University, 38039 Kayseri (Turkey)], E-mail: soylak@erciyes.edu.tr; Elci, Latif [Department of Chemistry, Faculty of Arts and Sciences, Pamukkale University, 20020 Denizli (Turkey); Tufekci, Mehmet [Department of Chemistry, Faculty of Arts and Sciences, Karadeniz Technical University, 61080 Trabzon (Turkey)

    2007-10-22

    A simple and accurate method was developed for separation and enrichment of trace levels of gold in environmental samples. The method is based on the adsorption of Au(III)-diethyldithiocarbamate complex on Amberlite XAD-2000 resin prior to the analysis of gold by flame atomic absorption spectrometry after elution with 1 mol L{sup -1} HNO{sub 3} in acetone. Some parameters including nitric acid concentration, eluent type, matrix ions, sample volume, sample flow rate and adsorption capacity were investigated on the recovery of gold(III). The recovery values for gold(III) and detection limit of gold were greater than 95% and 16.6 {mu}g L{sup -1}, respectively. The preconcentration factor was 200. The relative standard deviation of the method was <6%. The adsorption capacity of the resin was 12.3 mg g{sup -1}. The validation of the presented procedure was checked by the analysis of CRM-SA-C Sandy Soil certified reference material. The presented procedure was applied to the determination of gold in some environmental samples.

  11. Moller Polarimetry with Atomic Hydrogen Targets

    International Nuclear Information System (INIS)

    Chudakov, Eugene; Luppov, V.

    2012-01-01

    A proposal to use polarized atomic hydrogen gas as the target for electron beam polarimetry based on the Moller scattering is described. Such a gas, stored in an ultra-cold magnetic trap, would provide a target of practically 100% polarized electrons. It is conceivable to reach a ∼0.3% systematic accuracy of the beam polarimetry with such a target. Feasibility studies for the CEBAF electron beam have been performed

  12. Determination of ultra trace arsenic species in water samples by hydride generation atomic absorption spectrometry after cloud point extraction

    Energy Technology Data Exchange (ETDEWEB)

    Ulusoy, Halil Ibrahim, E-mail: hiulusoy@yahoo.com [University of Cumhuriyet, Faculty of Science, Department of Chemistry, TR-58140, Sivas (Turkey); Akcay, Mehmet; Ulusoy, Songuel; Guerkan, Ramazan [University of Cumhuriyet, Faculty of Science, Department of Chemistry, TR-58140, Sivas (Turkey)

    2011-10-10

    Graphical abstract: The possible complex formation mechanism for ultra-trace As determination. Highlights: {yields} CPE/HGAAS system for arsenic determination and speciation in real samples has been applied first time until now. {yields} The proposed method has the lowest detection limit when compared with those of similar CPE studies present in literature. {yields} The linear range of the method is highly wide and suitable for its application to real samples. - Abstract: Cloud point extraction (CPE) methodology has successfully been employed for the preconcentration of ultra-trace arsenic species in aqueous samples prior to hydride generation atomic absorption spectrometry (HGAAS). As(III) has formed an ion-pairing complex with Pyronine B in presence of sodium dodecyl sulfate (SDS) at pH 10.0 and extracted into the non-ionic surfactant, polyethylene glycol tert-octylphenyl ether (Triton X-114). After phase separation, the surfactant-rich phase was diluted with 2 mL of 1 M HCl and 0.5 mL of 3.0% (w/v) Antifoam A. Under the optimized conditions, a preconcentration factor of 60 and a detection limit of 0.008 {mu}g L{sup -1} with a correlation coefficient of 0.9918 was obtained with a calibration curve in the range of 0.03-4.00 {mu}g L{sup -1}. The proposed preconcentration procedure was successfully applied to the determination of As(III) ions in certified standard water samples (TMDA-53.3 and NIST 1643e, a low level fortified standard for trace elements) and some real samples including natural drinking water and tap water samples.

  13. Determination of Zinc Ions in Environmental Samples by Dispersive Liquid- Liquid Micro Extraction and Atomic Absorption Spectroscopy

    Directory of Open Access Journals (Sweden)

    F. Arabi

    2012-11-01

    Full Text Available In this work preconcentration of the Zn ions was investigated in water sample by Dispersive liquid- liquid micro extraction (DLLME using chloroform as an extraction solvent, methanol as a disperser solvent and 8-Hydroxyquinoline as a chelating agent. The determination of extracted ions was done by graphite furnace atomic absorption spectrometry. The influence of various analytical parameters including pH, extraction and disperser solvent type and volume and concentration of the chelating agent on the extraction efficiency of analyses was investigated. After extraction, the enrichment factor was 26 and the detection limit of the method was 0.0033 µg l-1 and the relative standard deviations (R.S.D for five determinations of 1 ng/ml Zn were 7.41%. 

  14. An ultra-cold neutron source at the MLNSC

    International Nuclear Information System (INIS)

    Bowles, T.J.; Brun, T.; Hill, R.; Morris, C.; Seestrom, S.J.; Crow, L.; Serebrov, A.

    1998-01-01

    This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The authors have carried out the research and development of an Ultra-Cold Neutron (UCN) source at the Manuel Lujan Neutron Scattering Center (MLNSC). A first generation source was constructed to test the feasibility of a rotor source. The source performed well with an UCN production rate reasonably consistent with that expected. This source can now provide the basis for further development work directed at using UCN in fundamental physics research as well as possible applications in materials science

  15. Spectroscopy with cold and ultra-cold neutrons

    Directory of Open Access Journals (Sweden)

    Abele Hartmut

    2015-01-01

    Full Text Available We present two new types of spectroscopy methods for cold and ultra-cold neutrons. The first method, which uses the R×B drift effect to disperse charged particles in a uniformly curved magnetic field, allows to study neutron β-decay. We aim for a precision on the 10−4 level. The second method that we refer to as gravity resonance spectroscopy (GRS allows to test Newton’s gravity law at short distances. At the level of precision we are able to provide constraints on any possible gravity-like interaction. In particular, limits on dark energy chameleon fields are improved by several orders of magnitude.

  16. Diamond-like carbon coated ultracold neutron guides

    International Nuclear Information System (INIS)

    Heule, S.; Atchison, F.; Daum, M.; Foelske, A.; Henneck, R.; Kasprzak, M.; Kirch, K.; Knecht, A.; Kuzniak, M.; Lippert, T.; Meier, M.; Pichlmaier, A.; Straumann, U.

    2007-01-01

    It has been shown recently that diamond-like carbon (DLC) with a sp 3 fraction above 60% is a better wall coating material for ultracold neutron applications than beryllium. We report on results of Raman spectroscopic and XPS measurements obtained for diamond-like carbon coated neutron guides produced in a new facility, which is based on pulsed laser deposition at 193 nm. For diamond-like carbon coatings on small stainless steel substrates we find sp 3 fractions in the range from 60 to 70% and showing slightly increasing values with laser pulse energy and pulse repetition rate

  17. Progress towards magnetic trapping of ultra-cold neutrons

    CERN Document Server

    Huffman, P R; Butterworth, J S; Coakley, K J; Dewey, M S; Dzhosyuk, S N; Gilliam, D M; Golub, R; Greene, G L; Habicht, K; Lamoreaux, S K; Mattoni, C E H; McKinsey, D N; Wietfeldt, F E; Doyle, J M

    2000-01-01

    We report progress towards magnetic trapping of ultra-cold neutrons (UCN) in preparation for a neutron lifetime measurement. UCN will be produced by inelastic scattering of cold (0.89 nm) neutrons in a reservoir of superfluid sup 4 He and confined in a three-dimensional magnetic trap. As the trapped neutrons decay, recoil electrons will generate scintillations in the liquid He, which should be detectable with nearly 100% efficiency. This direct measure of the number of UCN decays vs. time can be used to determine the neutron beta-decay lifetime.

  18. Quantum levitation of nanoparticles seen with ultracold neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Nesvizhevsky, V. V., E-mail: nesvizhevsky@ill.eu [Institut Laue-Langevin (France); Voronin, A. Yu. [Lebedev Institute (Russian Federation); Lambrecht, A.; Reynaud, S. [Laboratoire Kastler-Brossel, CNRS, ENS, UPMC (France); Lychagin, E. V.; Muzychka, A. Yu.; Strelkov, A. V. [Joint Institute for Nuclear Research (Russian Federation)

    2013-09-15

    Analyzing new experiments with ultracold neutrons (UCNs) we show that physical adsorption of nanoparticles/nanodroplets, levitating in high-excited states in a deep and broad potential well formed by van der Waals/Casimir-Polder (vdW/CP) forces results in new effects on a cross-road of the fields of fundamental interactions, neutron, surface and nanoparticle physics. Accounting for the interaction of UCNs with nanoparticles explains a recently discovered intriguing so-called 'small heating' of UCNs in traps. It might be relevant to the striking conflict of the neutron lifetime experiments with smallest reported uncertainties by adding false effects there.

  19. Quantum levitation of nanoparticles seen with ultracold neutrons

    International Nuclear Information System (INIS)

    Nesvizhevsky, V. V.; Voronin, A. Yu.; Lambrecht, A.; Reynaud, S.; Lychagin, E. V.; Muzychka, A. Yu.; Strelkov, A. V.

    2013-01-01

    Analyzing new experiments with ultracold neutrons (UCNs) we show that physical adsorption of nanoparticles/nanodroplets, levitating in high-excited states in a deep and broad potential well formed by van der Waals/Casimir-Polder (vdW/CP) forces results in new effects on a cross-road of the fields of fundamental interactions, neutron, surface and nanoparticle physics. Accounting for the interaction of UCNs with nanoparticles explains a recently discovered intriguing so-called “small heating” of UCNs in traps. It might be relevant to the striking conflict of the neutron lifetime experiments with smallest reported uncertainties by adding false effects there

  20. An ultra-cold neutron source at the MLNSC

    Energy Technology Data Exchange (ETDEWEB)

    Bowles, T.J.; Brun, T.; Hill, R.; Morris, C.; Seestrom, S.J. [Los Alamos National Lab., NM (United States); Crow, L. [Univ. of Rhode Island, Kingston, RI (United States); Serebrov, A. [Petersburg Nuclear Physics Inst. (Russian Federation)

    1998-11-01

    This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The authors have carried out the research and development of an Ultra-Cold Neutron (UCN) source at the Manuel Lujan Neutron Scattering Center (MLNSC). A first generation source was constructed to test the feasibility of a rotor source. The source performed well with an UCN production rate reasonably consistent with that expected. This source can now provide the basis for further development work directed at using UCN in fundamental physics research as well as possible applications in materials science.

  1. Scattering Length Scaling Laws for Ultracold Three-Body Collisions

    International Nuclear Information System (INIS)

    D'Incao, J.P.; Esry, B.D.

    2005-01-01

    We present a simple and unifying picture that provides the energy and scattering length dependence for all inelastic three-body collision rates in the ultracold regime for three-body systems with short-range two-body interactions. Here, we present the scaling laws for vibrational relaxation, three-body recombination, and collision-induced dissociation for systems that support s-wave two-body collisions. These systems include three identical bosons, two identical bosons, and two identical fermions. Our approach reproduces all previous results, predicts several others, and gives the general form of the scaling laws in all cases

  2. Localization of Cold Atoms in State-Dependent Optical Lattices via a Rabi Pulse

    International Nuclear Information System (INIS)

    Horstmann, Birger; Duerr, Stephan; Roscilde, Tommaso

    2010-01-01

    We propose a novel realization of Anderson localization in nonequilibrium states of ultracold atoms in an optical lattice. A Rabi pulse transfers part of the population to a different internal state with infinite effective mass. These frozen atoms create a quantum superposition of different disorder potentials, localizing the mobile atoms. For weakly interacting mobile atoms, Anderson localization is obtained. The localization length increases with increasing disorder and decreasing interaction strength, contrary to the expectation for equilibrium localization.

  3. Radio frequency selective addressing of localized atoms in a periodic potential

    International Nuclear Information System (INIS)

    Ott, H.; De Mirandes, E.; Ferlaino, F.; Roati, G.; Tuerck, V.; Modugno, G.; Inguscio, M.

    2004-01-01

    We study the localization and addressability of ultracold atoms in a combined parabolic and periodic potential. Such a potential supports the existence of localized stationary states and we show that applying a radio frequency field allows us to selectively address atoms in these states. This method is used to measure the energy and momentum distribution of the atoms in the localized states. We also discuss possible extensions of this scheme to address and manipulate atoms in single lattice sites

  4. Ground state of the polar alkali-metal-atom-strontium molecules: Potential energy curve and permanent dipole moment

    International Nuclear Information System (INIS)

    Guerout, R.; Aymar, M.; Dulieu, O.

    2010-01-01

    In this study, we investigate the structure of the polar alkali-metal-atom-strontium diatomic molecules as possible candidates for the realization of samples of ultracold polar molecular species not yet investigated experimentally. Using a quantum chemistry approach based on effective core potentials and core polarization potentials, we model these systems as effective three-valence-electron systems, allowing for calculation of electronic properties with full configuration interaction. The potential curve and the permanent dipole moment of the 2 Σ + ground state are determined as functions of the internuclear distance for LiSr, NaSr, KSr, RbSr, and CsSr molecules. These molecules are found to exhibit a significant permanent dipole moment, though smaller than those of the alkali-metal-atom-Rb molecules.

  5. Transport in a capacitive ultracold atomtronic circuit

    Science.gov (United States)

    Edwards, Mark; Eller, Benjamin; Eckel, Steve; Clark, Charles

    A recent NIST experiment studied the transport of a gaseous Bose-Einstein condensate (BEC) confined in an atomtronic ``dumbbell'' circuit. The optically created condensate potential consisted of a tight harmonic potential in the vertical direction confining the BEC to a horizontial plane. The horizontal potential consisted of two cylindrical wells separated by a channel produced by a harmonic oscillator potential transverse to the line joining the wells. The BEC, formed in the ``source'' well, was released to flow toward the ``drain'' well. The evolution of this system was shown to be reproduced by a model electronic circuit consisting of a charged capacitor, C, in series with an inductor, L, and a parallel combination of a resistor, R, and a Josephson junction. We modeled this system with the Gross-Pitaevskii (GP) equation and found good agreement with the data provided that the confining potential is carefully reproduced. The GP simulations show behavior, not detectable in the experiment, that atoms can jump out of the dumbbell area after filling up the drain well. We also present the dependence of R and L on the channel shape. Supported by NSF Grants PHY-1413768 and ARO Atomtronics MURI.

  6. Comparing and contrasting nuclei and cold atomic gases

    DEFF Research Database (Denmark)

    Zinner, Nikolaj Thomas; Jensen, Aksel Stenholm

    2013-01-01

    The experimental revolution in ultracold atomic gas physics over the past decades has brought tremendous amounts of new insight to the world of degenerate quantum systems. Here we compare and contrast the developments of cold atomic gases with the physics of nuclei since many concepts, techniques......, and nomenclatures are common to both fields. However, nuclei are finite systems with interactions that are typically much more complicated than those of ultracold atomic gases. The similarities and differences must therefore be carefully addressed for a meaningful comparison and to facilitate fruitful......, interactions, and relevant length and energy scales of cold atoms and nuclei. Next we address some attempts in nuclear physics to transfer the concepts of condensates in nuclei that can in principle be built from bosonic alpha-particle constituents. We also consider Efimov physics, a prime example of nuclear...

  7. Restricted access carbon nanotubes for direct extraction of cadmium from human serum samples followed by atomic absorption spectrometry analysis.

    Science.gov (United States)

    Barbosa, Adriano F; Barbosa, Valéria M P; Bettini, Jefferson; Luccas, Pedro O; Figueiredo, Eduardo C

    2015-01-01

    In this paper, we propose a new sorbent that is able to extract metal ions directly from untreated biological fluids, simultaneously excluding all proteins from these samples. The sorbent was obtained through the modification of carbon nanotubes (CNTs) with an external bovine serum albumin (BSA) layer, resulting in restricted access carbon nanotubes (RACNTs). The BSA layer was fixed through the interconnection between the amine groups of the BSA using glutaraldehyde as cross-linker. When a protein sample is percolated through a cartridge containing RACNTs and the sample pH is higher than the isoelectric point of the proteins, both proteins from the sample and the BSA layer are negatively ionized. Thus, an electrostatic repulsion prevents the interaction between the proteins from the sample on the RACNTs surface. At the same time, metal ions are adsorbed in the CNTs (core) after their passage through the chains of proteins. The Cd(2+) ion was selected for a proof-of-principle case to test the suitability of the RACNTs due to its toxicological relevance. RACNTs were able to extract Cd(2+) and exclude almost 100% of the proteins from the human serum samples in an online solid-phase extraction system coupled with thermospray flame furnace atomic absorption spectrometry. The limits of detection and quantification were 0.24 and 0.80 μg L(-1), respectively. The sampling frequency was 8.6h(-1), and the intra- and inter-day precisions at the 0.80, 15.0, and 30.0 μg L(-1) Cd(2+) levels were all lower than 10.1% (RSD). The recoveries obtained for human blood serum samples fortified with Cd(2+) ranged from 85.0% to 112.0%. The method was successfully applied to analyze Cd(2+) directly from six human blood serum samples without any pretreatment, and the observed concentrations ranged from

  8. The use of atomic absorption spectroscopy to measure arsenic, selenium, molybdenum, and vanadium in water and soil samples from uranium mill tailings sites

    International Nuclear Information System (INIS)

    Hollenbach, M.H.

    1988-01-01

    The Technical Measurements Center (TMC) was established to support the environmental measurement needs of the various DOE remedial action programs. A laboratory intercomparison study conducted by the TMC, using soil and water samples from sites contaminated by uranium mill tailings, indicated large discrepancies in analytical results reported by participating laboratories for arsenic, selenium, molybdenum, and vanadium. The present study was undertaken to investigate the most commonly used analytical techniques for measuring these four elements, ascertain routine and reliable quantification, and assess problems and successes of analysts. Based on a survey of the technical literature, the analytical technique of atomic absorption spectroscopy was selected for detailed study. The application of flame atomic absorption, graphite furnace atomic absorption, and hydride generation atomic absorption to the analysis of tailings-contaminated samples is discussed. Additionally, laboratory sample preparation methods for atomic absorption spectroscopy are presented. The conclusion of this report is that atomic absorption can be used effectively for the determination of arsenic, selenium, molybdenum, and vanadium in water and soil samples if the analyst understands the measurement process and is aware of potential problems. The problem of accurate quantification of arsenic, selenium, molybdenum, and vanadium in water and soil contaminated by waste products from uranium milling operations affects all DOE remedial action programs [Surplus Facilities Management Program (SFMP), Formerly Utilized Site Remedial Action Program (FUSRAP), and Uranium Mill Tailings Remedial Action Program (UMTRAP)], since all include sites where uranium was processed. 96 refs., 9 figs

  9. Laser-Cooled Ions and Atoms in a Storage Ring

    International Nuclear Information System (INIS)

    Kleinert, J.; Hannemann, S.; Eike, B.; Eisenbarth, U.; Grieser, M.; Grimm, R.; Gwinner, G.; Karpuk, S.; Saathoff, G.; Schramm, U.; Schwalm, D.; Weidemueller, M.

    2003-01-01

    We review recent experiments at the Heidelberg Test Storage Ring which apply advanced laser cooling techniques to stored ion beams. Very high phase-space densities are achieved by three-dimensional laser cooling of a coasting 9 Be + beam at 7.3 MeV. Laser-cooled, trapped Cs atoms are used as an ultracold precision target for the study of ion-atom interactions with a 74 MeV beam of 12 C 6+ ions.

  10. Preconcentration of gold ions from water samples by modified organo-nanoclay sorbent prior to flame atomic absorption spectrometry determination

    Energy Technology Data Exchange (ETDEWEB)

    Afzali, Daryoush, E-mail: daryoush_afzali@yahoo.com [Nanochemistry Department, Research Institute of Environmental Sciences, International Center for Science, High Technology and Environmental Sciences, Kerman (Iran, Islamic Republic of); Mostafavi, Ali [Chemistry Department, Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of); Mirzaei, Mohammad [Nanochemistry Department, Research Institute of Environmental Sciences, International Center for Science, High Technology and Environmental Sciences, Kerman (Iran, Islamic Republic of); Chemistry Department, Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of)

    2010-09-15

    In this work, the applicability of modified organo nanoclay as a new and easy prepared solid sorbent for the preconcentration of trace amounts of Au(III) ion from water samples is studied. The organo nanoclay was modified with 5-(4'-dimethylamino benzyliden)-rhodanine and used as a sorbent for separation of Au(III) ions. The sorption of gold ions was quantitative in the pH range of 2.0-6.0. Quantitative desorption occurred with 6.0 mL of 1.0 mol L{sup -1} Na{sub 2}S{sub 2}O{sub 3}. The amount of eluted Au(III) was measured using flame atomic absorption spectrometry. In the initial solution the linear dynamic range was in the range of 0.45 ng mL{sup -1} to 10.0 {mu}g mL{sup -1}, the detection limit was 0.1 ng mL{sup -1} and the preconcentration factor was 105. Also, the relative standard deviation was {+-}2.3% (n = 8 and C = 2.0 {mu}g mL{sup -1}) and the maximum capacity of the sorbent was 3.9 mg of Au(III) per gram of modified organo nanoclay. The influences of the experimental parameters including sample pH, eluent volume and eluent type, sample volume, and interference of some ions on the recoveries of the gold ion were investigated. The proposed method was applied for preconcentration and determination of gold in different samples.

  11. Sample preparation for arsenic speciation analysis in baby food by generation of substituted arsines with atomic absorption spectrometry detection.

    Science.gov (United States)

    Huber, Charles S; Vale, Maria Goreti R; Dessuy, Morgana B; Svoboda, Milan; Musil, Stanislav; Dědina, Jiři

    2017-12-01

    A slurry sampling procedure for arsenic speciation analysis in baby food by arsane generation, cryogenic trapping and detection with atomic absorption spectrometry is presented. Several procedures were tested for slurry preparation, including different reagents (HNO 3 , HCl and tetramethylammonium hydroxide - TMAH) and their concentrations, water bath heating and ultrasound-assisted agitation. The best results for inorganic arsenic (iAs) and dimethylarsinate (DMA) were reached when using 3molL -1 HCl under heating and ultrasound-assisted agitation. The developed method was applied for the analysis of five porridge powder and six baby meal samples. The trueness of the method was checked with a certified reference material (CRM) of total arsenic (tAs), iAs and DMA in rice (ERM-BC211). Arsenic recoveries (mass balance) for all samples and CRM were performed by the determination of the tAs by inductively coupled plasma mass spectrometry (ICP-MS) after microwave-assisted digestion and its comparison against the sum of the results from the speciation analysis. The relative limits of detection were 0.44, 0.24 and 0.16µgkg -1 for iAs, methylarsonate and DMA, respectively. The concentrations of the most toxic arsenic species (iAs) in the analyzed baby food samples ranged between 4.2 and 99µgkg -1 which were below the limits of 300, 200 and 100µgkg -1 set by the Brazilian, Chinese and European legislation, respectively. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. Discussion of parameters associated with the determination of arsenic by electrothermal atomic absorption spectrometry in slurried environmental samples.

    Science.gov (United States)

    Vassileva, E; Baeten, H; Hoenig, M

    2001-01-02

    A slurry sampling-fast program procedure has been developed for the determination of arsenic in plants, soils and sediments by electrothermal atomic absorption spectrometry. Efficiencies of various single and mixed modifiers for thermal stabilization of arsenic and for a better removal of the matrix during pyrolysis step were compared. The influence of the slurry concentration, amounts of modifier and parameters of the pyrolysis step on the As integrated absorbance signals have been studied and a comparison between fast and conventional furnace programs was also made. The ultrasonic agitation of the slurry followed by a fast electrothermal program using an Ir/Mg modifier provides the most consistent performance in terms of precision and accuracy. The reliability of the whole procedure has been compared with results obtained after application of a wet digestion method with an HF step and validated by analyzing eleven certified reference materials. Arsenic detection and quantitation limits expressed on dry sample matter were about 30 and 100 micrograms kg-1, respectively.

  13. An atomic force microscope for the study of the effects of tip sample interactions on dimensional metrology

    Science.gov (United States)

    Yacoot, Andrew; Koenders, Ludger; Wolff, Helmut

    2007-02-01

    An atomic force microscope (AFM) has been developed for studying interactions between the AFM tip and the sample. Such interactions need to be taken into account when making quantitative measurements. The microscope reported here has both the conventional beam deflection system and a fibre optical interferometer for measuring the movement of the cantilever. Both can be simultaneously used so as to not only servo control the tip movements, but also detect residual movement of the cantilever. Additionally, a high-resolution homodyne differential optical interferometer is used to measure the vertical displacement between the cantilever holder and the sample, thereby providing traceability for vertical height measurements. The instrument is compatible with an x-ray interferometer, thereby facilitating high resolution one-dimensional scans in the X-direction whose metrology is based on the silicon d220 lattice spacing (0.192 nm). This paper concentrates on the first stage of the instrument's development and presents some preliminary results validating the instrument's performance and showing its potential.

  14. Investigation of the levels of some element in edible oil samples produced in Turkey by atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Mendil, Durali; Uluoezlue, Ozguer Dogan; Tuezen, Mustafa; Soylak, Mustafa

    2009-01-01

    The element contents (Fe, Mn, Zn, Cu, Pb, Co, Cd, Na, K, Ca and Mg) in edible oils (olive oil, hazelnut oil, sunflower oil, margarine, butter and corn oil) from Turkey were determined using atomic absorption spectrometry after microwave digestion. The concentrations of trace element in the samples were found to be 291.0-52.0, 1.64-0.04, 3.08-1.03, 0.71-0.05, 0.03-0.01, 1.30-0.50, 84.0-0.90, 50.1-1.30, 174.2-20.8 and 20.8-0.60 μg/g for iron, manganese, zinc, copper, lead, cobalt, sodium, potassium, calcium, and magnesium, respectively. Cadmium was found to be 4.57-0.09 μg/kg. The high heavy metal and minerals accumulation levels in the samples were found in olive oil for Cu, Pb, Co, margarine for Fe, K, corn oil for Zn, Mn, butter for Na, Mg, sunflower oil for Ca and hazelnut oil for Cd, respectively.

  15. 3D site specific sample preparation and analysis of 3D devices (FinFETs) by atom probe tomography.

    Science.gov (United States)

    Kambham, Ajay Kumar; Kumar, Arul; Gilbert, Matthieu; Vandervorst, Wilfried

    2013-09-01

    With the transition from planar to three-dimensional device architectures such as Fin field-effect-transistors (FinFETs), new metrology approaches are required to meet the needs of semiconductor technology. It is important to characterize the 3D-dopant distributions precisely as their extent, positioning relative to gate edges and absolute concentration determine the device performance in great detail. At present the atom probe has shown its ability to analyze dopant distributions in semiconductor and thin insulating materials with sub-nm 3D-resolution and good dopant sensitivity. However, so far most reports have dealt with planar devices or restricted the measurements to 2D test structures which represent only limited challenges in terms of localization and site specific sample preparation. In this paper we will discuss the methodology to extract the dopant distribution from real 3D-devices such as a 3D-FinFET device, requiring the sample preparation to be carried out at a site specific location with a positioning accuracy ∼50 nm. Copyright © 2013 Elsevier B.V. All rights reserved.

  16. Magnetic-film atom chip with 10 μm period lattices of microtraps for quantum information science with Rydberg atoms.

    Science.gov (United States)

    Leung, V Y F; Pijn, D R M; Schlatter, H; Torralbo-Campo, L; La Rooij, A L; Mulder, G B; Naber, J; Soudijn, M L; Tauschinsky, A; Abarbanel, C; Hadad, B; Golan, E; Folman, R; Spreeuw, R J C

    2014-05-01

    We describe the fabrication and construction of a setup for creating lattices of magnetic microtraps for ultracold atoms on an atom chip. The lattice is defined by lithographic patterning of a permanent magnetic film. Patterned magnetic-film atom chips enable a large variety of trapping geometries over a wide range of length scales. We demonstrate an atom chip with a lattice constant of 10 μm, suitable for experiments in quantum information science employing the interaction between atoms in highly excited Rydberg energy levels. The active trapping region contains lattice regions with square and hexagonal symmetry, with the two regions joined at an interface. A structure of macroscopic wires, cutout of a silver foil, was mounted under the atom chip in order to load ultracold (87)Rb atoms into the microtraps. We demonstrate loading of atoms into the square and hexagonal lattice sections simultaneously and show resolved imaging of individual lattice sites. Magnetic-film lattices on atom chips provide a versatile platform for experiments with ultracold atoms, in particular for quantum information science and quantum simulation.

  17. Magnetic-film atom chip with 10 μm period lattices of microtraps for quantum information science with Rydberg atoms

    Energy Technology Data Exchange (ETDEWEB)

    Leung, V. Y. F. [Van der Waals-Zeeman Institute, University of Amsterdam, Science Park 904, PO Box 94485, 1090 GL Amsterdam (Netherlands); Complex Photonic Systems (COPS), MESA Institute for Nanotechnology, University of Twente, PO Box 217, 7500 AE Enschede (Netherlands); Pijn, D. R. M.; Schlatter, H.; Torralbo-Campo, L.; La Rooij, A. L.; Mulder, G. B.; Naber, J.; Soudijn, M. L.; Tauschinsky, A.; Spreeuw, R. J. C., E-mail: r.j.c.spreeuw@uva.nl [Van der Waals-Zeeman Institute, University of Amsterdam, Science Park 904, PO Box 94485, 1090 GL Amsterdam (Netherlands); Abarbanel, C.; Hadad, B.; Golan, E. [Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Be' er Sheva 84105 (Israel); Folman, R. [Department of Physics and Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Be' er Sheva 84105 (Israel)

    2014-05-15

    We describe the fabrication and construction of a setup for creating lattices of magnetic microtraps for ultracold atoms on an atom chip. The lattice is defined by lithographic patterning of a permanent magnetic film. Patterned magnetic-film atom chips enable a large variety of trapping geometries over a wide range of length scales. We demonstrate an atom chip with a lattice constant of 10 μm, suitable for experiments in quantum information science employing the interaction between atoms in highly excited Rydberg energy levels. The active trapping region contains lattice regions with square and hexagonal symmetry, with the two regions joined at an interface. A structure of macroscopic wires, cutout of a silver foil, was mounted under the atom chip in order to load ultracold {sup 87}Rb atoms into the microtraps. We demonstrate loading of atoms into the square and hexagonal lattice sections simultaneously and show resolved imaging of individual lattice sites. Magnetic-film lattices on atom chips provide a versatile platform for experiments with ultracold atoms, in particular for quantum information science and quantum simulation.

  18. Focus on strongly correlated quantum fluids: from ultracold quantum gases to QCD plasmas Focus on strongly correlated quantum fluids: from ultracold quantum gases to QCD plasmas

    Science.gov (United States)

    Adams, Allan; Carr, Lincoln D.; Schaefer, Thomas; Steinberg, Peter; Thomas, John E.

    2013-04-01

    interdisciplinary appeal and include new studies of high temperature superfluidity, viscosity, spin-transport, spin-imbalanced mixtures, and three-component gases, this last having a close parallel to color superconductivity. Another system important for the field of strongly-interacting quantum fluids was revealed by analysis of data from the Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Laboratory. Despite naive expectations based on asymptotic freedom that the deconfinement of quarks and gluons at high temperatures would lead to a weakly-interacting quark gluon plasma (QGP), the system appeared to be quite strongly coupled. Subsequent estimates of the viscosity-to-entropy ratio suggest that the system is tantalizingly close to the postulated bound from AdS/CFT calculations. The field is quite dynamic at the moment; new measurements are expected from upgraded detectors at RHIC, and an entirely new energy regime is being opened up by heavy ion collisions at the Large Hadron Collider (LHC) at CERN. On the theoretical side, much work remains to be done to extract the precise values of the transport coefficients, and to characterize the nature of quasi-particle excitations in the plasma. Finally, holographic dualities such as anti-de Sitter/conformal field theory (AdS/CFT) have opened a new theoretical window on strongly correlated fluids. Holography relates strongly-interacting quantum many-body systems to weakly-coupled semi-classical gravitational systems, replacing quasiparticles with geometry and translating various difficult questions about quantum fluids into simple and calculable geometric exercises. Already, some of the earliest lessons of holography, such as the conjectural bound on the viscosity-to-entropy ratio, have had a considerable impact on the theoretical and experimental study of strongly correlated fluids, from RHIC to ultracold atoms. More recently, the study of holographic superconductors, non-Fermi liquids and unitary quantum gases has touched

  19. Mode-coupling of interaction quenched ultracold bosons in periodically driven lattices

    Science.gov (United States)

    Mistakidis, Simeon; Schmelcher, Peter

    2016-05-01

    The out-of-equilibrium dynamics of interaction quenched finite ultracold bosonic ensembles in periodically driven one-dimensional optical lattices is investigated. As a first attempt a brief analysis of the dynamics caused exclusively by the periodically driven lattice is presented and the induced low-lying modes are introduced. It is shown that the periodic driving enforces the bosons in the outer wells to exhibit out-of-phase dipole-like modes, while in the central well the cloud experiences a local-breathing mode. The dynamical behavior of the system is investigated with respect to the driving frequency, revealing a resonant-like behavior of the intra-well dynamics. Subsequently, we drive the system to a highly non-equilibrium state by performing an interaction quench upon the periodically driven lattice. This protocol gives rise to admixtures of excitations in the outer wells, an enhanced breathing in the center and an amplification of the tunneling dynamics. As a result (of the quench) the system experiences multiple resonances between the inter- and intra-well dynamics at different quench amplitudes. Finally, our study reveals that the position of the resonances can be adjusted e.g. via the driving frequency or the atom number manifesting their many-body nature. Deutsche Forschungsgemeinschaft (DFG) in the framework of the SFB 925 ``Light induced dynamics and control of correlated quantum systems''.

  20. Universal Borromean Binding in Spin-Orbit-Coupled Ultracold Fermi Gases

    Directory of Open Access Journals (Sweden)

    Xiaoling Cui

    2014-08-01

    Full Text Available Borromean rings and Borromean binding, a class of intriguing phenomena as three objects are linked (bound together while any two of them are unlinked (unbound, widely exist in nature and have been found in systems of biology, chemistry, and physics. Previous studies have suggested that the occurrence of such a binding in physical systems typically relies on the microscopic details of pairwise interaction potentials at short range and is, therefore, nonuniversal. Here, we report a new type of Borromean binding in ultracold Fermi gases with Rashba spin-orbit coupling, which is universal against short-range interaction details, with its binding energy only dependent on the s-wave scattering length and the spin-orbit-coupling strength. We show that the occurrence of this universal Borromean binding is facilitated by the symmetry of the single-particle dispersion under spin-orbit coupling and is, therefore, symmetry selective rather than interaction selective. The state is robust over a wide range of mass ratios between composing fermions, which are accessible by Li-Li, K-K, and K-Li mixtures in cold-atom experiments. Our results reveal the importance of single- particle spectral symmetry in few-body physics and shed light on the emergence of new quantum phases in a many-body system with exotic few-body correlations.

  1. Method Comparison of Neutron Activation Analysis and Atomic Absorption Spectrometry for Determination of Zinc in Food Samples

    International Nuclear Information System (INIS)

    Endah Damastuti; Syukria Kurniawati; Natalia Adventini

    2009-01-01

    Zinc as a micro nutrient, has important roles in human metabolism system. It is required by the body in appropriate amount from food intake. Due to the very low concentration of Zinc in food, high selectivity and sensitivity analysis technique is required for the determination, such as Neutron Activation Analysis (NAA) and Atomic Absorption Spectrometry (AAS). In this experiment, both methods were compared in zinc analysis of food samples. The subject of this experiment is to examine of those methods conformity and improving the technique capability in zinc analysis in food sample. Those methods were validated by analyzing zinc in SRM NIST 1548a Typical Diet and were tested its accuracy and precision. The results of Zn concentration were 25.1 ± 2.14 mg/kg by NAA and 24.1 ± 1.40 mg/kg by AAS while the certificate value was 24.6 ± 1.80 mg/kg. Percentage of relative bias, %CV, μ-test score and HORRAT(Horwitz ratio) value given by NAA were 2%, 8.5%, 0.18 and 0.9 respectively, while %relative bias, %CV, μ-test score and HORRAT value given by AAS were 2%, 5.8 %, 0.20 and 0.6 respectively. The result obtained for Zn concentration in various food samples by NAA and AAS were varied from 13.7 – 29.3 mg/kg with mean value 19.8 mg/kg and 11.2 – 26.0 mg/kg with mean value 17.3 mg/kg (author)

  2. Cloud point extraction for trace inorganic arsenic speciation analysis in water samples by hydride generation atomic fluorescence spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Li, Shan, E-mail: ls_tuzi@163.com; Wang, Mei, E-mail: wmei02@163.com; Zhong, Yizhou, E-mail: yizhz@21cn.com; Zhang, Zehua, E-mail: kazuki.0101@aliyun.com; Yang, Bingyi, E-mail: e_yby@163.com

    2015-09-01

    A new cloud point extraction technique was established and used for the determination of trace inorganic arsenic species in water samples combined with hydride generation atomic fluorescence spectrometry (HGAFS). As(III) and As(V) were complexed with ammonium pyrrolidinedithiocarbamate and molybdate, respectively. The complexes were quantitatively extracted with the non-ionic surfactant (Triton X-114) by centrifugation. After addition of antifoam, the surfactant-rich phase containing As(III) was diluted with 5% HCl for HGAFS determination. For As(V) determination, 50% HCl was added to the surfactant-rich phase, and the mixture was placed in an ultrasonic bath at 70 °C for 30 min. As(V) was reduced to As(III) with thiourea–ascorbic acid solution, followed by HGAFS. Under the optimum conditions, limits of detection of 0.009 and 0.012 μg/L were obtained for As(III) and As(V), respectively. Concentration factors of 9.3 and 7.9, respectively, were obtained for a 50 mL sample. The precisions were 2.1% for As(III) and 2.3% for As(V). The proposed method was successfully used for the determination of trace As(III) and As(V) in water samples, with satisfactory recoveries. - Highlights: • Cloud point extraction was firstly established to determine trace inorganic arsenic(As) species combining with HGAFS. • Separate As(III) and As(V) determinations improve the accuracy. • Ultrasonic release of complexed As(V) enables complete As(V) reduction to As(III). • Direct HGAFS analysis can be performed.

  3. Determination of palladium in various samples by atomic absorption spectrometry after preconcentration with dimethylglyoxime on silica gel

    International Nuclear Information System (INIS)

    Tokalioglu, Serife; Oymak, Tuelay; Kartal, Senol

    2004-01-01

    A preconcentration method based on the adsorption of palladium-dimethylglyoxime (DMG) complex on silica gel for the determination of palladium at trace levels by atomic absorption spectrometry (AAS) has been developed. The retained palladium as Pd(DMG) 2 complex was eluted with 1 mol l -1 HCl in acetone. The effect of some analytical parameters such as pH, amount of reagent and the sample volume on the recovery of palladium was examined in synthetic solutions containing street dust matrix. The influence of some matrix ions on the recovery of palladium was investigated by using the developed method when the elements were present both individually and together. The results showed that 2500 μg ml -1 Na + , K + , Mg 2+ , Al 3+ and Fe 3+ ; 5000 μg ml -1 Ca 2+ ; 500 μg ml -1 Pb 2+ ; 125 μg ml -1 Zn 2+ ; 50 μg ml -1 Cu 2+ and 25 μg ml -1 Ni 2+ did not interfere with the palladium signal. At the optimum conditions determined experimentally, the recovery for palladium was found to be 95.3±1.2% at the 95% confidence level. The relative standard deviation and limit of detection (3s/b) of the method were found to be 1.7% and 1.2 μg l -1 , respectively. In order to determine the adsorption behaviour of silica gel, the adsorption isotherm of palladium was studied and the binding equilibrium constant and adsorption capacity were calculated to be 0.38 l mg -1 and 4.06 mg g -1 , respectively. The determination of palladium in various samples was performed by using both flame AAS and graphite furnace AAS. The proposed method was successfully applied for the determination of palladium in the street dust, anode slime, rock and catalytic converter samples

  4. Determination of arsenic and cadmium in shellfish samples by graphite furnace atomic absorption spectrometry using matrix modifier

    International Nuclear Information System (INIS)

    Cortez Diaz, Mirella del Carmen

    2002-01-01

    Heavy metals are a big source of environmental contamination and are also highly toxic to humans. Since shellfish are bio-accumulators of these metals, proper techniques for quantifying them should be available. This work aims to develop an analytical method for the quantitative determination of heavy metals in biological materials (shellfish), specifically arsenic and cadmium at the trace level, using graphite furnace atomic absorption spectrometry, for which nickel and phosphate solutions were used to modify the modifiers. Prior to the analysis, the sample was diluted with nitric acid in a DAB II pressure digestion system order to destroy the organic matter. The instrument conditions were initially set (wavelength, slit, integration peaks, graphite tube, etc.), then the work range was defined for each element and the most appropriate operational parameters were studied, such as: temperature, ramp times, hold times and internal gas flow, in the different stage of the electrothermal treatment (drying, calcination, atomization) for the furnace program. Once the above mentioned conditions were set and since this was a biological sample, a matrix chemical modifier had to be used, in order to make the elements that accompany the element being studied more volatile. In this way the chemical and spectral interferences decrease together with the high background absorption of the matrix. Therefore, different matrix modifiers were studied for the definition of each analyte. The method validation was done using Certified Oyster Tissue Reference Material N o 1566a from the National Institute of Standards and Technology applying different tests in order to eliminate outliers. Repeatability, uncertainty, sensitivity, lineal range, working range, detection limit and quantification limit were evaluated for each element, and the results were compared with the values for the certified material. The Fisher and Student tests were the statistical tools used. The experimental values

  5. Experiments with cold hydrogen atoms

    International Nuclear Information System (INIS)

    Leonas, V.B.

    1981-01-01

    Numerous investigations of atomic processes in Waseous phase on the surface with participation of ''cold'' hydrogen atoms, made during the last years, are considered. The term ''cold atom'' means the range of relative collision energies E<10 MeV (respectively 'ultracold ' atoms at E< or approximately 1 MeV) which corresponds to the range of temperatures in tens (units) of K degrees. Three main ranges of investigations where extensive experimental programs are realized are considered: study of collisional processes with hydrogen atom participation, hydrogen atoms being of astrophysical interest; study of elastic atom-molecular scattering at superlow energies and studies on the problem of condensed hydrogen. Hydrogen atoms production is realized at dissociation in non-electrode high-frequency or superhigh-frequency discharge. A method of hydrogen quantum generator and of its modifications appeared to be rather an effective means to study collisional changes of spin state of hydrogen atoms. First important results on storage and stabilization of the gas of polarized hydrogen atoms are received

  6. Time-Dependent Impurity in Ultracold Fermions: Orthogonality Catastrophe and Beyond

    Directory of Open Access Journals (Sweden)

    Michael Knap

    2012-12-01

    Full Text Available The recent experimental realization of strongly imbalanced mixtures of ultracold atoms opens new possibilities for studying impurity dynamics in a controlled setting. In this paper, we discuss how the techniques of atomic physics can be used to explore new regimes and manifestations of Anderson’s orthogonality catastrophe (OC, which could not be accessed in solid-state systems. Specifically, we consider a system of impurity atoms, localized by a strong optical-lattice potential, immersed in a sea of itinerant Fermi atoms. We point out that the Ramsey-interference-type experiments with the impurity atoms allow one to study the OC in the time domain, while radio-frequency (RF spectroscopy probes the OC in the frequency domain. The OC in such systems is universal, not only in the long-time limit, but also for all times and is determined fully by the impurity-scattering length and the Fermi wave vector of the itinerant fermions. We calculate the universal Ramsey response and RF-absorption spectra. In addition to the standard power-law contributions, which correspond to the excitation of multiple particle-hole pairs near the Fermi surface, we identify a novel, important contribution to the OC that comes from exciting one extra particle from the bottom of the itinerant band. This contribution gives rise to a nonanalytic feature in the RF-absorption spectra, which shows a nontrivial dependence on the scattering length, and evolves into a true power-law singularity with the universal exponent 1/4 at the unitarity. We extend our discussion to spin-echo-type experiments, and show that they probe more complicated nonequilibirum dynamics of the Fermi gas in processes in which an impurity switches between states with different interaction strength several times; such processes play an important role in the Kondo problem, but remained out of reach in the solid-state systems. We show that, alternatively, the OC can be seen in the energy-counting statistics

  7. Determination of total and inorganic mercury in fish samples with on-line oxidation coupled to atomic fluorescence spectrometry

    International Nuclear Information System (INIS)

    Shao Lijun; Gan Wuer; Su Qingde

    2006-01-01

    An atomic fluorescence spectrometry system for determination of total and inorganic mercury with electromagnetic induction-assisted heating on-line oxidation has been developed. Potassium peroxodisulphate was used as the oxidizing agent to decompose organomercury compounds. Depending on the temperature selected, inorganic or total mercury could be determined with the same manifold. Special accent was put on the study of the parameters influencing the on-line digestion efficiency. The tolerance to the interference of coexisting ions was carefully examined in this system. Under optimal conditions, the detection limits (3σ) were evaluated to be 2.9 ng l -1 for inorganic mercury and 2.6 ng l -1 for total mercury, respectively. The relative standard deviations for 10 replicate determinations of 1.0 μg l -1 Hg were 2.4 and 3.2% for inorganic mercury and total mercury, respectively. The proposed method was successfully applied to the determination of total and inorganic mercury in fish samples

  8. Graphene for separation and preconcentration of trace amounts of cobalt in water samples prior to flame atomic absorption spectrometry

    Directory of Open Access Journals (Sweden)

    Yukun Wang

    2016-09-01

    Full Text Available A new sensitive and simple method was developed for the preconcentration of trace amounts of cobalt (Co using 1-(2-pyridylazo-2-naphthol (PAN as chelating reagent prior to its determination by flame atomic absorption spectrometry. The proposed method is based on the utilization of a column packed with graphene as sorbent. Several effective parameters on the extraction and complex formation were selected and optimized. Under optimum conditions, the calibration graph was linear in the concentration range of 5.0–240.0 μg L−1 with a detection limit of 0.36 μg L−1. The relative standard deviation for ten replicate measurements of 20.0 and 100.0 μg L−1 of Co were 3.45 and 3.18%, respectively. Comparative studies showed that graphene is superior to other adsorbents including C18 silica, graphitic carbon, and single- and multi-walled carbon nanotubes for the extraction of Co. The proposed method was successfully applied in the analysis of four real environmental water samples. Good spiked recoveries over the range of 95.8–102.6% were obtained.

  9. Simultaneous preconcentration of cadmium and lead in water samples with silica gel and determination by flame atomic absorption spectrometry.

    Science.gov (United States)

    Xu, Hongbo; Wu, Yun; Wang, Jian; Shang, Xuewei; Jiang, Xiaojun

    2013-12-01

    A new method that utilizes pretreated silica gel as an adsorbent has been developed for simultaneous preconcentration of trace Cd(II) and Pb(II) prior to the measurement by flame atomic absorption spectrometry. The effects of pH, the shaking time, the elution condition and the coexisting ions on the separation/preconcentration conditions of analytes were investigated. Under optimized conditions, the static adsorption capacity of Cd(II) and Pb(II) were 45.5 and 27.1mg/g, the relative standard deviations were 3.2% and 1.7% (for n = 11), and the limits of detection obtained were 4.25 and 0.60 ng/mL, respectively. The method was validated by analyzing the certified reference materials GBW 07304a (stream sediment) and successfully applied to the analysis of various treated wastewater samples with satisfactory results. Copyright © 2013 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

  10. A portable source of lattice-trapped and ultracold strontium (PLUS), Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to design and demonstrate a portable source of lattice-trapped, ultracold strontium (PLUS). The device uses simplified and robust techniques for loading...

  11. A Portable Source of Lattice-Trapped and Ultracold Strontium (PLUS), Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to demonstrate the portable source of lattice-trapped, ultracold strontium (PLUS) designed during Phase I. The device uses simplified and robust...

  12. Determination of arsenic and cadmium in shellfish samples by graphite furnace atomic absorption spectrometry using matrix modifier

    International Nuclear Information System (INIS)

    Villalobos Aranda, Juan; Cortez Diaz, Mirella

    2003-01-01

    Serious problems of environmental contamination due to the activity of the man exist at the present time. Where the greater impact is the produced one by heavy metals that go to the sea. Where the shellfish can collect some of them, the highly toxic ones, since these are bioaccumulation of these metals. Therefore one becomes necessary to count with the reliable analytical procedures to determine these elements. The purpose of this work is to present the determination of arsenic and cadmium in shellfish, by spectroscopy of atomic absorption with graphite furnace. For each determined element, solutions of nickel and phosphate like matrix modifiers were used respectively The validation was made using a Reference Certified Material, Oyster ' Tissue 156 (National Institute of Standards and Technology). The sample previously was digested in triplicate by two consecutive days, with nitric acid in a pressure digestion system DAB 11. For each element it was evaluated: limit of detection and quantification, sensitivity, repeatability, linear, slope rank and uncertainty. In addition, the obtained results were compared with the certified values of the certified material of reference using like statistical tools the tests of Student and Fisher. In both tests the calculated values were smaller to the shown ones in table, for degrees of freedom with 95% of confidence. Thus it was verified that it does not exist significant differences between the precision and the average values of the results obtained with respect to the values of the certified material. In addition, the obtained parameters are appropriate for the determination of these trace elements in this type of environmental sample (author)

  13. Entanglement between two spatially separated atomic modes

    Science.gov (United States)

    Lange, Karsten; Peise, Jan; Lücke, Bernd; Kruse, Ilka; Vitagliano, Giuseppe; Apellaniz, Iagoba; Kleinmann, Matthias; Tóth, Géza; Klempt, Carsten

    2018-04-01

    Modern quantum technologies in the fields of quantum computing, quantum simulation, and quantum metrology require the creation and control of large ensembles of entangled particles. In ultracold ensembles of neutral atoms, nonclassical states have been generated with mutual entanglement among thousands of particles. The entanglement generation relies on the fundamental particle-exchange symmetry in ensembles of identical particles, which lacks the standard notion of entanglement between clearly definable subsystems. Here, we present the generation of entanglement between two spatially separated clouds by splitting an ensemble of ultracold identical particles prepared in a twin Fock state. Because the clouds can be addressed individually, our experiments open a path to exploit the available entangled states of indistinguishable particles for quantum information applications.

  14. Manipulating Atoms with Light Achievements and Perspectives

    CERN Multimedia

    CERN. Geneva

    2006-01-01

    During the last few decades spectacular progress has been achieved in the control of atomic systems by light. It will be shown how it is possible to use the basic conservation laws in atom-photon interactions for polarizing atoms, for trapping them, for cooling them to extremely low temperatures, in the microkelvin, and even in the nanokelvin range. A review will be given of recent advances in this field and of new applications, including atomic clocks with very high relative stability and accuracy, atomic interferometers allowing precise measurement of rotation speeds and gravitational fields, the realization of new states of matter such as Bose-Einstein condensates, matter waves and atom lasers, ultracold molecules. New perspectives opened by these results will be also briefly discussed.

  15. Manipulating ultracold polar molecules with microwave radiation: The influence of hyperfine structure

    International Nuclear Information System (INIS)

    Aldegunde, J.; Hutson, Jeremy M.; Ran Hong

    2009-01-01

    We calculate the microwave spectra of ultracold 40 K 87 Rb alkali-metal dimers, including hyperfine interactions and in the presence of electric and magnetic fields. We show that microwave transitions may be used to transfer molecules between different hyperfine states, but only because of the presence of nuclear quadrupole interactions. Hyperfine splittings may also complicate the use of ultracold molecules for quantum computing. The spectrum of molecules oriented in electric fields may be simplified dramatically by applying a simultaneous magnetic field.

  16. Microstructural evolution and mechanical properties of differently heat-treated binder jet printed samples from gas- and water-atomized alloy 625 powders

    International Nuclear Information System (INIS)

    Mostafaei, Amir; Toman, Jakub; Stevens, Erica L.; Hughes, Eamonn T.; Krimer, Yuval L.; Chmielus, Markus

    2017-01-01

    In this study, we investigate the effect of powders resulting from different atomization methods on properties of binder jet printed and heat-treated samples. Air-melted gas atomized (GA) and water atomized (WA) nickel-based alloy 625 powders were used to binder jet print samples for a detailed comparative study on microstructural evolution and mechanical properties. GA printed samples achieved higher sintering density (99.2%) than WA samples (95.0%) due to differences in powder morphology and chemistry. Grain sizes of GA and WA samples at their highest density were 89 ± 21 μm and 88 ± 26 μm, respectively. Mechanical tests were conducted on optimally sintered samples and sintered plus aged samples; aging further improved microstructure and mechanical properties. This study shows that microstructural evolution (densification, and carbide, oxide and intermetallic phase formation) is very different for GA and WA binder jet printed and heat-treated samples. This difference in microstructural evolution results in different mechanical properties with the superior sintered and aged GA specimen reaching a hardness of 327 ± 7 HV_0_._1, yield strength of 394 ± 15 MPa, and ultimate tensile strength of 718 ± 14 MPa which are higher than cast alloy 625 values.

  17. Sheet Fluorescence and Annular Analysis of Ultracold Neutral Plasmas

    International Nuclear Information System (INIS)

    Castro, J.; Gao, H.; Killian, T. C.

    2009-01-01

    Annular analysis of fluorescence imaging measurements on Ultracold Neutral Plasmas (UNPs) is demonstrated. Spatially-resolved fluorescence imaging of the strontium ions produces a spectrum that is Doppler-broadened due to the thermal ion velocity and shifted due to the ion expansion velocity. The fluorescence excitation beam is spatially narrowed into a sheet, allowing for localized analysis of ion temperatures within a volume of the plasma with small density variation. Annular analysis of fluorescence images permits an enhanced signal-to-noise ratio compared to previous fluorescence measurements done in strontium UNPs. Using this technique and analysis, plasma ion temperatures are measured and shown to display characteristics of plasmas with strong coupling such as disorder induced heating and kinetic energy oscillations.

  18. Theoretical model for ultracold molecule formation via adaptive feedback control

    International Nuclear Information System (INIS)

    Poschinger, Ulrich; Salzmann, Wenzel; Wester, Roland; Weidemueller, Matthias; Koch, Christiane P; Kosloff, Ronnie

    2006-01-01

    We theoretically investigate pump-dump photoassociation of ultracold molecules with amplitude- and phase-modulated femtosecond laser pulses. For this purpose, a perturbative model for light-matter interaction is developed and combined with a genetic algorithm for adaptive feedback control of the laser pulse shapes. The model is applied to the formation of 85 Rb 2 molecules in a magneto-optical trap. We find that optimized pulse shapes may maximize the formation of ground state molecules in a specific vibrational state at a pump-dump delay time for which unshaped pulses lead to a minimum of the formation rate. Compared to the maximum formation rate obtained for unshaped pulses at the optimum pump-dump delay, the optimized pulses lead to a significant improvement of about 40% for the target level population. Since our model yields the spectral amplitudes and phases of the optimized pulses, the results are directly applicable in pulse shaping experiments

  19. Quantized Ultracold Neutrons in Rough Waveguides: GRANIT Experiments and Beyond

    Directory of Open Access Journals (Sweden)

    M. Escobar

    2014-01-01

    Full Text Available We apply our general theory of transport in systems with random rough boundaries to gravitationally quantized ultracold neutrons in rough waveguides as in GRANIT experiments (ILL, Grenoble. We consider waveguides with roughness in both two and one dimensions (2D and 1D. In the biased diffusion approximation the depletion times for the gravitational quantum states can be easily expressed via each other irrespective of the system parameters. The calculation of the exit neutron count reduces to evaluation of a single constant which contains a complicated integral of the correlation function of surface roughness. In the case of 1D roughness (random grating this constant is calculated analytically for common types of the correlation functions. The results obey simple scaling relations which are slightly different in 1D and 2D. We predict the exit neutron count for the new GRANIT cell.

  20. Improved Noninterferometric Test of Collapse Models Using Ultracold Cantilevers

    Science.gov (United States)

    Vinante, A.; Mezzena, R.; Falferi, P.; Carlesso, M.; Bassi, A.

    2017-09-01

    Spontaneous collapse models predict that a weak force noise acts on any mechanical system, as a consequence of the collapse of the wave function. Significant upper limits on the collapse rate have been recently inferred from precision mechanical experiments, such as ultracold cantilevers and the space mission LISA Pathfinder. Here, we report new results from an experiment based on a high-Q cantilever cooled to millikelvin temperatures, which is potentially able to improve the current bounds on the continuous spontaneous localization (CSL) model by 1 order of magnitude. High accuracy measurements of the cantilever thermal fluctuations reveal a nonthermal force noise of unknown origin. This excess noise is compatible with the CSL heating predicted by Adler. Several physical mechanisms able to explain the observed noise have been ruled out.

  1. Exploiting Universality in Atoms with Large Scattering Lengths

    International Nuclear Information System (INIS)

    Braaten, Eric

    2012-01-01

    The focus of this research project was atoms with scattering lengths that are large compared to the range of their interactions and which therefore exhibit universal behavior at sufficiently low energies. Recent dramatic advances in cooling atoms and in manipulating their scattering lengths have made this phenomenon of practical importance for controlling ultracold atoms and molecules. This research project was aimed at developing a systematically improvable method for calculating few-body observables for atoms with large scattering lengths starting from the universal results as a first approximation. Significant progress towards this goal was made during the five years of the project.

  2. Levitation of atoms by interference and Two-dimensional transport in the presence of disorder

    International Nuclear Information System (INIS)

    Robert De Saint Vincent, M.

    2010-12-01

    This thesis presents two experiments of atomic physics, realized on an ultra-cold sample of Rubidium 87. We tackle the topics of atom interferometry, and of the transport properties in disordered medium. In the first experiment, we demonstrate a technique for suspending atoms against gravity, which could help increase the interrogation time of atom interferometers. The atoms are periodically diffracted on a light standing wave, used as Bragg mirror to reflect the atoms and thus prevent their fall. However, when getting close to the thin grating limit, the matter wave-packet is split into many trajectories that periodically recombine. We show that the interference between these multiple components can be used to cancel the losses towards falling channels. This original interferometer could be an interesting alternative to suspend an inertial sensor or an atom clock in a limited volume, whilst allowing simultaneous measurement of the forces acting on the atoms. The second experiment is devoted to the study of the transport properties in a 2-dimensional (2D) disordered medium. In particular, matter wave interference can prevent the transport - a phenomenon known as Anderson Localization. The atoms are confined between two repulsive sheets of light, and the disorder is generated by a speckle pattern shined onto the cloud. We observe a diffusive expansion in these potentials, and extract diffusion coefficients in agreement with a numerical simulation. We then explore the dynamic at lower energies, where sub-diffusion, classical trapping under the percolation threshold, and Anderson Localization may be observed. Finally, the study of the interplay between disorder and the Berezinskii-Kosterlitz-Thouless transition in 2D is now within reach. (author)

  3. Socio-psycho-historical observation on the twin. Sampling methods and case study of the atomic bomb exposed twins

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, S; Satow, Y; Ueoka, Hiroshi; Munaka, M; Kurihara, M [Hiroshima Univ. (Japan). Research Inst. for Nuclear Medicine and Biology

    1980-07-01

    The so-called ''twin control study'', mainly on the monozygotic twins one of which was A-bomb exposed and the other was non-exposed were carried out. Sampling was conducted utilizing the materials as follows: 1) The survey on casualities of A-bomb exposed families in Hiroshima which was undertaken in 1946. 2) The survey of A-bomb survivors in 1965. 3) A-bomb exposed family survey conducted between 1973 to 1975. 4) Investigations of A-bomb victims exposed in the proximal areas from the hypocenter. From the above mentioned materials 470 pairs were selected, of which 220 were exposed. Among them 172 pairs were twins of the same sex. Female and male pair were also employed. In one case they were exposed, while the others were nonexposed. Two pairs were examined under the following methods: 1) Depth interview to ascertain familial casualities with reference to the family life cycle. 2) Socio-historical research. 3) Motoaki's Jinkaku Shindan Kensa (Modified Rorschach test by H. Motoaki), and T.A.T. test. Results obtained were summarized as follows: 1) Both pairs of twins were of similar appearance and personality traits, and had a strong feeling of companionship for each other. 2) In family relationships, the persons studied were very conscious of the role expectations of elder and younger siblings in the twin pairs. 3) Through depth interviews and projective tests, A-bomb exposed pairs still showed deep psychological stresses, resulting from the A-bomb disaster. 4) Both among the exposed twins and within the nonexposed control group twin siblings had a close feeling of companionship for each other. However, nonexposed twins could not understand the psychological experience of twins who had been subjected to the atomic disaster.

  4. Combination of atomic force microscopy and mass spectrometry for the detection of target protein in the serum samples of children with autism spectrum disorders

    Science.gov (United States)

    Kaysheva, A. L.; Pleshakova, T. O.; Kopylov, A. T.; Shumov, I. D.; Iourov, I. Y.; Vorsanova, S. G.; Yurov, Y. B.; Ziborov, V. S.; Archakov, A. I.; Ivanov, Y. D.

    2017-10-01

    Possibility of detection of target proteins associated with development of autistic disorders in children with use of combined atomic force microscopy and mass spectrometry (AFM/MS) method is demonstrated. The proposed method is based on the combination of affine enrichment of proteins from biological samples and visualization of these proteins by AFM and MS analysis with quantitative detection of target proteins.

  5. The use of double laser pulses for the atomic-emission spectral estimation of uranium content in biological samples

    International Nuclear Information System (INIS)

    Patapovich, M.P.; Umreiko, D.S.; Zajogin, A.P.; Buloichik, J.I.

    2012-01-01

    This paper is aimed at the development of the techniques for estimation of the uranium content in biological objects (hair) using the atomic-emission laser analysis with a sufficient accuracy and high processing rate. (authors)

  6. Application of wire electrodes in electric discharge machining of metal samples of reactor blocks of the operative atomic power station

    International Nuclear Information System (INIS)

    Gozhenko, S.V.

    2007-01-01

    Features of application of electroerosive methods are considered during the process of direct definition of properties of metal of the equipment of power units of the atomic power station. Results of development of a complex of the equipment for wire electric discharge machining of metal templet and its use are presented at the control of the basic metal of the main circulating pipelines over blocks of the atomic power station of Ukraine over long terms of operation

  7. Comparison of different sample preparation methods for platinum determination in cultured cells by graphite furnace atomic absorption spectrometry

    Directory of Open Access Journals (Sweden)

    Man Xiao

    2017-01-01

    Full Text Available Background Platinum-based agents are widely used in chemotherapy against solid tumors and insufficient intracellular drug accumulation is one of the leading causes of platinum resistance which is associated with poor survival of tumor patients. Thus, the detection of intracellular platinum is pivotal for studies aiming to overcome platinum resistance. In the present study, we aimed to establish a reliable graphite furnace atomic absorption spectrometry (GFAAS-based assay to quantify the intracellular platinum content for cultured cells. Methods Several most commonly applied cell preparation methods, including 0.2% HNO3, 0.2% Triton X-100, concentrated nitric acid, RIPA combined with concentrated nitric acid and hydroxide, followed by GFAAS for platinum detection were compared in ovarian, cervical and liver cancer cell lines to obtain the optimal one, and parameters regarding linearity, accuracy, precision and sensitivity were evaluated. Influence of other metals on platinum detection and the storage conditions of samples were also determined. Results The treatment of cells with 0.2% HNO3 was superior to other approaches with fewer platinum loss and better repeatability. The recovery rate and precision of this method were 97.3%–103.0% and 1.4%–3.8%, respectively. The average recoveries in the presence of other metals were 95.1%–103.1%. The detection limit was 13.23 ug/L. The recovery rate of platinum remained acceptable even in cell samples stored in −20 °C or −80 °C for two months. Discussion After comparison, we found that 0.2% HNO3 was optimal for intracellular platinum quantification based on GFAAS, which presented values compatible with that of inductively-coupled plasma mass-spectrometry (ICP-MS, and this is partially attributed to the simplicity of this method. Moreover, the assay was proved to be accurate, sensitive, cost-effective and suitable for the research of platinum-based antitumor therapy.

  8. Micro-sampling method based on high-resolution continuum source graphite furnace atomic absorption spectrometry for calcium determination in blood and mitochondrial suspensions.

    Science.gov (United States)

    Gómez-Nieto, Beatriz; Gismera, Mª Jesús; Sevilla, Mª Teresa; Satrústegui, Jorgina; Procopio, Jesús R

    2017-08-01

    A micro-sampling and straightforward method based on high resolution continuum source atomic absorption spectrometry (HR-CS AAS) was developed to determine extracellular and intracellular Ca in samples of interest in clinical and biomedical analysis. Solid sampling platforms were used to introduce the micro-samples into the graphite furnace atomizer. The secondary absorption line for Ca, located at 239.856nm, was selected to carry out the measurements. Experimental parameters such as pyrolysis and atomization temperatures and the amount of sample introduced for the measurements were optimized. Calibration was performed using aqueous standards and the approach to measure at the wings of the absorption lines was employed for the expansion of the linear response range. The limit of detection was of 0.02mgL -1 Ca (0.39ng Ca) and the upper limit of linear range was increased up to 8.0mgL -1 Ca (160ng Ca). The proposed method was used to determine Ca in mitochondrial suspensions and whole blood samples with successful results. Adequate recoveries (within 91-107%) were obtained in the tests performed for validation purposes. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Virtual states, halos and resonances in three-body atomic and nuclear systems

    International Nuclear Information System (INIS)

    Frederico, T.; Yamashita, M.T.; Tomio, L.

    2009-01-01

    By considering nuclear and ultracold trapped atomic systems, we review the trajectory of Efimov excited states in the complex plane by changing the two-body scattering lengths and one three-body scale. This article is based on the presentation by T. Frederico at the Fifth Workshop on Critical Stability, Erice, Sicily. (author)

  10. Quantum coherent tractor beam effect for atoms trapped near a nanowaveguide

    Science.gov (United States)

    Sadgrove, Mark; Wimberger, Sandro; Nic Chormaic, Síle

    2016-01-01

    We propose several schemes to realize a tractor beam effect for ultracold atoms in the vicinity of a few-mode nanowaveguide. Atoms trapped near the waveguide are transported in a direction opposite to the guided mode propagation direction. We analyse three specific examples for ultracold 23Na atoms trapped near a specific nanowaveguide (i.e. an optical nanofibre): (i) a conveyor belt-type tractor beam effect, (ii) an accelerator tractor beam effect, and (iii) a quantum coherent tractor beam effect, all of which can effectively pull atoms along the nanofibre toward the light source. This technique provides a new tool for controlling the motion of particles near nanowaveguides with potential applications in the study of particle transport and binding as well as atom interferometry. PMID:27440516

  11. Hyperfine structure of 2Σ molecules containing alkaline-earth-metal atoms

    Science.gov (United States)

    Aldegunde, Jesus; Hutson, Jeremy M.

    2018-04-01

    Ultracold molecules with both electron spin and an electric dipole moment offer new possibilities in quantum science. We use density-functional theory to calculate hyperfine coupling constants for a selection of molecules important in this area, including RbSr, LiYb, RbYb, CaF, and SrF. We find substantial hyperfine coupling constants for the fermionic isotopes of the alkaline-earth-metal and Yb atoms. We discuss the hyperfine level patterns and Zeeman splittings expected for these molecules. The results will be important both to experiments aimed at forming ultracold open-shell molecules and to their applications.

  12. Dependences of the van der Waals atom-wall interaction on atomic and material properties

    International Nuclear Information System (INIS)

    Caride, A.O.; Klimchitskaya, G.L.; Mostepanenko, V.M.; Zanette, S.I.

    2005-01-01

    The 1%-accurate calculations of the van der Waals interaction between an atom and a cavity wall are performed in the separation region from 3 nm to 150 nm. The cases of metastable He * and Na atoms near metal, semiconductor, and dielectric walls are considered. Different approximations to the description of wall material and atomic dynamic polarizability are carefully compared. The smooth transition to the Casimir-Polder interaction is verified. It is shown that to obtain accurate results for the atom-wall van der Waals interaction at short separations with an error less than 1% one should use the complete optical-tabulated data for the complex refractive index of the wall material and the accurate dynamic polarizability of an atom. The obtained results may be useful for the theoretical interpretation of recent experiments on quantum reflection and Bose-Einstein condensation of ultracold atoms on or near surfaces of different kinds

  13. Progress on the Magnetic Trapping of Ultra-cold Neutrons

    Science.gov (United States)

    Doyle, John M.

    1998-04-01

    Ultra-cold neutrons (UCN) have been instrumental in making improved measurements of the neutron beta-decay lifetime and in searches for a permanent electric dipole moment.(R. Golub, D. Richardson and S.K. Lamoreaux, Ultra-cold Neutrons), Adam Hilger, 1991 The most accurate experiments have taken place using in-core devices at ILL (Grenoble, France) and PNPI (St. Petersburg, Russia). Superthermal techniques offer the promise of high-density sources of UCN via scattering of cold neutrons. Cold neutron beams are available at many neutron facilities. We are currently working on the development of a superfluid helium UCN source using the Cold Neutron Research Facility at the NIST Research Reactor (Gaithersburg) . Our first experiment plans to use superthermal scattering of neutrons in superfluid helium to produce UCN within a magnetic trapping volume. A magnetic trap 30 cm long and 4 cm diameter will be filled with helium at about 100 mK. Cold neutrons (around 11 K) will be introduced into the trapping region where some of them scatter to low enough energies (around 1 mK) so that they are magnetically trapped. Once trapped the UCN travel undisturbed; they have a very small probability of upscattering. Detection will be accomplished as the UCN beta-decay. The resultant high-energy electron creates excited molecular helium dimers, a portion which decay in less than 10 ns and emit radiation in the XUV (50-100 nm). We have developed techniques to measure these scintillations. Analysis indicates that a high accuracy measurement of the neutron beta decay lifetime should be possible using our techniques. An apparatus has been constructed and initial runs are underway. An overview of the experiment, discussion of systematic errors and recent experimental progress will be presented. This work is done in collaboration with C. Brome, J. Butterworth, S. Dzhosyuk, P. Huffman, C. Mattoni, D. McKinsey, M. Cooper, G. Greene, S. Lamoreaux, R. Golub, K. Habicht, K. Coakley, S. Dewey, D

  14. Ghost imaging with atoms

    Science.gov (United States)

    Khakimov, R. I.; Henson, B. M.; Shin, D. K.; Hodgman, S. S.; Dall, R. G.; Baldwin, K. G. H.; Truscott, A. G.

    2016-12-01

    Ghost imaging is a counter-intuitive phenomenon—first realized in quantum optics—that enables the image of a two-dimensional object (mask) to be reconstructed using the spatio-temporal properties of a beam of particles with which it never interacts. Typically, two beams of correlated photons are used: one passes through the mask to a single-pixel (bucket) detector while the spatial profile of the other is measured by a high-resolution (multi-pixel) detector. The second beam never interacts with the mask. Neither detector can reconstruct the mask independently, but temporal cross-correlation between the two beams can be used to recover a ‘ghost’ image. Here we report the realization of ghost imaging using massive particles instead of photons. In our experiment, the two beams are formed by correlated pairs of ultracold, metastable helium atoms, which originate from s-wave scattering of two colliding Bose-Einstein condensates. We use higher-order Kapitza-Dirac scattering to generate a large number of correlated atom pairs, enabling the creation of a clear ghost image with submillimetre resolution. Future extensions of our technique could lead to the realization of ghost interference, and enable tests of Einstein-Podolsky-Rosen entanglement and Bell’s inequalities with atoms.

  15. Sampling

    CERN Document Server

    Thompson, Steven K

    2012-01-01

    Praise for the Second Edition "This book has never had a competitor. It is the only book that takes a broad approach to sampling . . . any good personal statistics library should include a copy of this book." —Technometrics "Well-written . . . an excellent book on an important subject. Highly recommended." —Choice "An ideal reference for scientific researchers and other professionals who use sampling." —Zentralblatt Math Features new developments in the field combined with all aspects of obtaining, interpreting, and using sample data Sampling provides an up-to-date treat

  16. Dimensional BCS-BEC crossover in ultracold Fermi gases

    Energy Technology Data Exchange (ETDEWEB)

    Boettcher, Igor

    2014-12-10

    We investigate thermodynamics and phase structure of ultracold Fermi gases, which can be realized and measured in the laboratory with modern trapping techniques. We approach the subject from a both theoretical and experimental perspective. Central to the analysis is the systematic comparison of the BCS-BEC crossover of two-component fermions in both three and two dimensions. A dimensional reduction can be achieved in experiments by means of highly anisotropic traps. The Functional Renormalization Group (FRG) allows for a description of both cases in a unified theoretical framework. In three dimensions we discuss with the FRG the influence of high momentum particles onto the density, extend previous approaches to the Unitary Fermi Gas to reach quantitative precision, and study the breakdown of superfluidity due to an asymmetry in the population of the two fermion components. In this context we also investigate the stability of the Sarma phase. For the two-dimensional system scattering theory in reduced dimension plays an important role. We present both the theoretically as well as experimentally relevant aspects thereof. After a qualitative analysis of the phase diagram and the equation of state in two dimensions with the FRG we describe the experimental determination of the phase diagram of the two-dimensional BCS-BEC crossover in collaboration with the group of S. Jochim at PI Heidelberg.

  17. The MCUCN simulation code for ultracold neutron physics

    Science.gov (United States)

    Zsigmond, G.

    2018-02-01

    Ultracold neutrons (UCN) have very low kinetic energies 0-300 neV, thereby can be stored in specific material or magnetic confinements for many hundreds of seconds. This makes them a very useful tool in probing fundamental symmetries of nature (for instance charge-parity violation by neutron electric dipole moment experiments) and contributing important parameters for the Big Bang nucleosynthesis (neutron lifetime measurements). Improved precision experiments are in construction at new and planned UCN sources around the world. MC simulations play an important role in the optimization of such systems with a large number of parameters, but also in the estimation of systematic effects, in benchmarking of analysis codes, or as part of the analysis. The MCUCN code written at PSI has been extensively used for the optimization of the UCN source optics and in the optimization and analysis of (test) experiments within the nEDM project based at PSI. In this paper we present the main features of MCUCN and interesting benchmark and application examples.

  18. Ultracold Anions for High-Precision Antihydrogen Experiments.

    Science.gov (United States)

    Cerchiari, G; Kellerbauer, A; Safronova, M S; Safronova, U I; Yzombard, P

    2018-03-30

    Experiments with antihydrogen (H[over ¯]) for a study of matter-antimatter symmetry and antimatter gravity require ultracold H[over ¯] to reach ultimate precision. A promising path towards antiatoms much colder than a few kelvin involves the precooling of antiprotons by laser-cooled anions. Because of the weak binding of the valence electron in anions-dominated by polarization and correlation effects-only few candidate systems with suitable transitions exist. We report on a combination of experimental and theoretical studies to fully determine the relevant binding energies, transition rates, and branching ratios of the most promising candidate La^{-}. Using combined transverse and collinear laser spectroscopy, we determined the resonant frequency of the laser cooling transition to be ν=96.592 713(91)  THz and its transition rate to be A=4.90(50)×10^{4}  s^{-1}. Using a novel high-precision theoretical treatment of La^{-} we calculated yet unmeasured energy levels, transition rates, branching ratios, and lifetimes to complement experimental information on the laser cooling cycle of La^{-}. The new data establish the suitability of La^{-} for laser cooling and show that the cooling transition is significantly stronger than suggested by a previous theoretical study.

  19. Determination of gold, indium, tellurium and thallium in the same sample digest of geological materials by atomic-absorption spectroscopy and two-step solvent extraction

    Science.gov (United States)

    Hubert, A.E.; Chao, T.T.

    1985-01-01

    A rock, soil, or stream-sediment sample is decomposed with hydrofluoric acid, aqua regia, and hydrobromic acid-bromine solution. Gold, thallium, indium and tellurium are separated and concentrated from the sample digest by a two-step MIBK extraction at two concentrations of hydrobromic add. Gold and thallium are first extracted from 0.1M hydrobromic acid medium, then indium and tellurium are extracted from 3M hydrobromic acid in the presence of ascorbic acid to eliminate iron interference. The elements are then determined by flame atomic-absorption spectrophotometry. The two-step solvent extraction can also be used in conjunction with electrothermal atomic-absorption methods to lower the detection limits for all four metals in geological materials. ?? 1985.

  20. Quantum measurement-induced dynamics of many-body ultracold bosonic and fermionic systems in optical lattices

    Science.gov (United States)

    Mazzucchi, Gabriel; Kozlowski, Wojciech; Caballero-Benitez, Santiago F.; Elliott, Thomas J.; Mekhov, Igor B.

    2016-02-01

    Trapping ultracold atoms in optical lattices enabled numerous breakthroughs uniting several disciplines. Coupling these systems to quantized light leads to a plethora of new phenomena and has opened up a new field of study. Here we introduce an unusual additional source of competition in a many-body strongly correlated system: We prove that quantum backaction of global measurement is able to efficiently compete with intrinsic short-range dynamics of an atomic system. The competition becomes possible due to the ability to change the spatial profile of a global measurement at a microscopic scale comparable to the lattice period without the need of single site addressing. In coherence with a general physical concept, where new competitions typically lead to new phenomena, we demonstrate nontrivial dynamical effects such as large-scale multimode oscillations, long-range entanglement, and correlated tunneling, as well as selective suppression and enhancement of dynamical processes beyond the projective limit of the quantum Zeno effect. We demonstrate both the breakup and protection of strongly interacting fermion pairs by measurement. Such a quantum optical approach introduces into many-body physics novel processes, objects, and methods of quantum engineering, including the design of many-body entangled environments for open systems.

  1. Design of a scanning probe microscope with advanced sample treatment capabilities: An atomic force microscope combined with a miniaturized inductively coupled plasma source

    International Nuclear Information System (INIS)

    Hund, Markus; Herold, Hans

    2007-01-01

    We describe the design and performance of an atomic force microscope (AFM) combined with a miniaturized inductively coupled plasma source working at a radio frequency of 27.12 MHz. State-of-the-art scanning probe microscopes (SPMs) have limited in situ sample treatment capabilities. Aggressive treatments such as plasma etching or harsh treatments such as etching in aggressive liquids typically require the removal of the sample from the microscope. Consequently, time consuming procedures are required if the same sample spot has to be imaged after successive processing steps. We have developed a first prototype of a SPM which features a quasi in situ sample treatment using a modified commercial atomic force microscope. A sample holder is positioned in a special reactor chamber; the AFM tip can be retracted by several millimeters so that the chamber can be closed for a treatment procedure. Most importantly, after the treatment, the tip is moved back to the sample with a lateral drift per process step in the 20 nm regime. The performance of the prototype is characterized by consecutive plasma etching of a nanostructured polymer film

  2. In-situ pre-concentration through repeated sampling and pyrolysis for ultrasensitive determination of thallium in drinking water by electrothermal atomic absorption spectrometry.

    Science.gov (United States)

    Liu, Liwei; Zheng, Huaili; Xu, Bincheng; Xiao, Lang; Chigan, Yong; Zhangluo, Yilan

    2018-03-01

    In this paper, a procedure for in-situ pre-concentration in graphite furnace by repeated sampling and pyrolysis is proposed for the determination of ultra-trace thallium in drinking water by graphite furnace atomic absorption spectrometry (GF-AAS). Without any other laborious enrichment processes that routinely result in analyte loss and contamination, thallium was directly concentrated in the graphite furnace automatically and subsequently subject to analysis. The effects of several key factors, such as the temperature for pyrolysis and atomization, the chemical modifier, and the repeated sampling times were investigated. Under the optimized conditions, a limit of detection of 0.01µgL -1 was obtained, which fulfilled thallium determination in drinking water by GB 5749-2006 regulated by China. Successful analysis of thallium in certified water samples and drinking water samples was demonstrated, with analytical results in good agreement with the certified values and those by inductively coupled plasma mass spectrometry (ICP-MS), respectively. Routine spike-recovery tests with randomly selected drinking water samples showed satisfactory results of 80-96%. The proposed method is simple and sensitive for screening of ultra-trace thallium in drinking water samples. Copyright © 2017. Published by Elsevier B.V.

  3. Validation of a method to quantify chromium, cadmium, manganese, nickel and lead in human whole blood, urine, saliva and hair samples by electrothermal atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Olmedo, P.; Pla, A.; Hernandez, A.F.; Lopez-Guarnido, O.; Rodrigo, L.; Gil, F.

    2010-01-01

    For biological monitoring of heavy metal exposure in occupational toxicology, usually whole blood and urine samples are the most widely used and accepted matrix to assess internal xenobiotic exposure. Hair samples and saliva are also of interest in occupational and environmental health surveys but procedures for the determination of metals in saliva and hair are very scarce and to our knowledge there is no validation of a method to quantify Cr, Cd, Mn, Ni and Pb in four different human biological materials (whole blood, urine, saliva and axilary hair) by electrothermal atomization atomic absorption spectrometry (ETAAS). In the present study, quantification methods for the determination of Cr, Cd, Mn, Ni and Pb in whole blood, urine, saliva and axilary hair were validated according to the EU common standards. Pyrolisis and atomization temperatures have been determined. The main parameters evaluated were: detection and quantification limits, linearity range, repeatability, reproducibility, recovery and uncertainty. Accuracy of the methods was tested with the whole blood, urine and hair certified reference materials and recoveries of the spiked samples were acceptable ranged from 96.3 to 107.8%.

  4. Validation of a method to quantify chromium, cadmium, manganese, nickel and lead in human whole blood, urine, saliva and hair samples by electrothermal atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Olmedo, P.; Pla, A.; Hernandez, A.F.; Lopez-Guarnido, O.; Rodrigo, L. [Department of Legal Medicine and Toxicology, University of Granada, School of Medicine (Spain); Gil, F., E-mail: fgil@ugr.es [Department of Legal Medicine and Toxicology, University of Granada, School of Medicine (Spain)

    2010-02-05

    For biological monitoring of heavy metal exposure in occupational toxicology, usually whole blood and urine samples are the most widely used and accepted matrix to assess internal xenobiotic exposure. Hair samples and saliva are also of interest in occupational and environmental health surveys but procedures for the determination of metals in saliva and hair are very scarce and to our knowledge there is no validation of a method to quantify Cr, Cd, Mn, Ni and Pb in four different human biological materials (whole blood, urine, saliva and axilary hair) by electrothermal atomization atomic absorption spectrometry (ETAAS). In the present study, quantification methods for the determination of Cr, Cd, Mn, Ni and Pb in whole blood, urine, saliva and axilary hair were validated according to the EU common standards. Pyrolisis and atomization temperatures have been determined. The main parameters evaluated were: detection and quantification limits, linearity range, repeatability, reproducibility, recovery and uncertainty. Accuracy of the methods was tested with the whole blood, urine and hair certified reference materials and recoveries of the spiked samples were acceptable ranged from 96.3 to 107.8%.

  5. Characterization of a scintillating lithium glass ultra-cold neutron detector

    Energy Technology Data Exchange (ETDEWEB)

    Jamieson, B.; Rebenitsch, L.A.; Hansen-Romu, S.; Mammei, R.; Martin, J.W. [University of Winnipeg, Department of Physics, Winnipeg (Canada); Lauss, B. [Paul Scherrer Institute, Laboratory for Particle Physics, Villigen (Switzerland); Lindner, T. [TRIUMF, Vancouver (Canada); University of Winnipeg, Department of Physics, Winnipeg (Canada); Pierre, E. [TRIUMF, Vancouver (Canada); Osaka University, Research Centre for Nuclear Physics, Osaka (Japan)

    2017-01-15

    A {sup 6}Li-glass-based scintillation detector developed for the TRIUMF neutron electric dipole moment experiment was characterized using the ultra-cold neutron source at the Paul Scherrer Institute (PSI). The data acquisition system for this detector was demonstrated to perform well at rejecting backgrounds. An estimate of the absolute efficiency of background rejection of 99.7±0.1% is made. For variable ultra-cold neutron rate (varying from < 1 kHz to approx. 100 kHz per channel) and background rate seen at the Paul Scherrer Institute, we estimate that the absolute detector efficiency is 89.7{sup +1.3}{sub -1.9}%. Finally a comparison with a commercial Cascade detector was performed for a specific setup at the West-2 beamline of the ultra-cold neutron source at PSI. (orig.)

  6. Monitoring and Method development of Hg in Istanbul Airborne Particulates by Solid Sampling Continuum Source-High Resolution Electrothermal Atomic Absorption Spectromerty

    Directory of Open Access Journals (Sweden)

    Soydemir E.

    2014-07-01

    Full Text Available In this work, a method has been developed and monitoring for the determination of mercury in PM2.5 airborne particulates by solid sampling high-resolution continuum source electrothermal atomic absorption spectrometry. The PM2.5 airborne particulates were collected on quartz filters using high volume samplers (500 L/min in Istanbul (Turkey for 96 hours every month in one year. At first, experimental conditions as well as the validation tests were optimized using collected filter. For this purpose, the effects of atomization temperature, amount of sample intoduced in to the furnace, addition of acids and/or KMnO4 on the sample, covering of graphite tube and platform or using of Ag nanoparticulates, Au nanoparticulates, and Pd solutions on the accuracy and precision were investigated. After optimization of the experimental conditions, the mercury concentrations were determined in the collected filter. The filters with PM2.5 airborne particulates were dried, divided into small fine particles and then Hg concentrations were determined directly. In order to eliminate any error due to the sensitivity difference between aqueous standards and solid samples, the quantification was performed using solid calibrants. The limit of detection, based on three times the standard deviations for ten atomizations of an unused filter, was 30 ng/g. The Hg content was dependent on the sampling site, season etc, ranging from samples, addition of AuNPs, AgNPs and Pd solution for amalgamation effects on the recoveries were investigated. The results were compared using statistical tests.

  7. Combined short scale roughness and surface dielectric function gradient effects on the determination of tip-sample force in atomic force microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Gusso, André, E-mail: gusso@metal.eeimvr.uff.br [Departamento de Ciências Exatas-EEIMVR, Universidade Federal Fluminense, Volta Redonda, RJ 27255-125 (Brazil)

    2013-11-11

    The contribution of tip roughness to the van der Waals force between an atomic force microscopy probe tip and the sample is calculated using the multilayer effective medium model, which allows us to consider the relevant case of roughness characterized by correlation length and amplitude in the nanometer scale. The effect of the surface dielectric function gradient is incorporated in the tip-sample force model. It is concluded that for rms roughness in the few nanometers range the effect of short scale tip roughness is quite significant.

  8. Use of oxidative and reducing vapor generation for reducing the detection limits of iodine in biological samples by inductively coupled plasma atomic emission spectrometry

    International Nuclear Information System (INIS)

    Vtorushina, Eh.A.; Saprykin, A.I.; Knapp, G.

    2009-01-01

    Procedures of microwave combustion in an oxygen flow and microwave acid decomposition of biological samples were optimized for the subsequent determination of iodine. A new method was proposed for the generation of molecular iodine from periodate iona using hydrogen peroxide as a reductant. Procedures were developed for determining iodine in biological samples by inductively coupled plasma atomic emission spectrometry (ICP-AES) using oxidative and reducing vapor generation; these allowed the detection limit for iodine to be lowered by 3-4 orders of magnitude. The developed procedures were used to analyze certified reference materials of milk (Skim Milk Powder BCR 150) and seaweed (Sea Lettuce BCR 279) and a Supradyn vitamin complex

  9. Coupling continuous ultrasound-assisted extraction, preconcentration and flame atomic absorption spectrometric detection for the determination of cadmium and lead in mussel samples

    International Nuclear Information System (INIS)

    Yebra-Biurrun, M.C.; Cancela-Perez, S.; Moreno-Cid-Barinaga, A.

    2005-01-01

    Continuous ultrasound-assisted extraction has been coupled with preconcentration and flame atomic absorption spectrometry for the determination of cadmium and lead in mussel samples. Experimental designs were used for the optimisation of the leaching and preconcentration steps. The use of diluted nitric acid as extractant in the continuous mode at a flow rate of 3.5 ml min -1 and room temperature was sufficient for quantitative extraction of these trace metals. A minicolumn containing a chelating resin (Chelite P, with aminomethylphosphoric acid groups) was proved as an excellent material for the quantitative preconcentration of cadmium and lead prior to their flame atomic absorption detection. A flow injection manifold was used as interface for coupling the three analytical steps, which allowed the automation of the whole analytical process. A good precision of the whole procedure (2.0 and 2.3%), high enrichment factors (20.5 and 11.8) and a detection limit of 0.011 and 0.25 μg g -1 for cadmium and lead, respectively, were obtained for 80 mg of sample. The sample throughputs were ca. 16 and 14 samples h -1 for cadmium and lead, respectively. The accuracy of the analytical procedures was verified by using a standard reference material (BCR 278-R, mussel tissue) and the results were in good agreement with the certified values. The method was successfully applied to the determination of trace amounts of cadmium and lead in mussel samples from the coast of Galicia (NW, Spain)

  10. Evaluation of solid sampling high-resolution continuum source graphite furnace atomic absorption spectrometry for direct determination of chromium in medicinal plants

    International Nuclear Information System (INIS)

    Virgilio, Alex; Nóbrega, Joaquim A.; Rêgo, Jardes F.; Neto, José A. Gomes

    2012-01-01

    A method for Cr determination in medicinal plants using direct solid sampling graphite furnace high-resolution continuum source atomic absorption spectrometry was developed. Modifiers were dispensable. Pyrolysis and atomization temperatures were 1500 °C and 2400 °C, respectively. Slopes of calibration curves (50–750 pg Cr, R 2 > 0.999) using aqueous and solid standards coincides in 96%, indicated feasibility of aqueous calibration for solid sampling of medicinal plants. Accuracy was checked by analysis of four plant certified reference materials. Results were in agreement at 95% confidence level with certified and non-certified values. Ten samples of medicinal plants were analyzed and Cr contents were in the 1.3–17.7 μg g −1 Cr range. The highest RSD (n = 5) was 15.4% for the sample Melissa officinalis containing 13.9 ± 2.1 μg g −1 Cr. The limit of detection was 3.3 ng g −1 Cr. - Highlights: ► Direct solid sampling is first time employed for Cr in plant materials. ► Calibration curves with liquids and solids are coincident. ► Microanalysis of plants for Cr is validated by reference materials. ► The proposed HR-CS GF AAS method is environmental friendly.

  11. Evaluation of solid sampling high-resolution continuum source graphite furnace atomic absorption spectrometry for direct determination of chromium in medicinal plants

    Energy Technology Data Exchange (ETDEWEB)

    Virgilio, Alex; Nobrega, Joaquim A. [Department of Chemistry, Federal University of Sao Carlos, Post Office Box 676, 13560-970, Sao Carlos-SP (Brazil); Rego, Jardes F. [Department of Analytical Chemistry, Institute of Chemistry, Sao Paulo State University-UNESP, Post Office Box 355, 14801-970, Araraquara-SP (Brazil); Neto, Jose A. Gomes, E-mail: anchieta@iq.unesp.br [Department of Analytical Chemistry, Institute of Chemistry, Sao Paulo State University-UNESP, Post Office Box 355, 14801-970, Araraquara-SP (Brazil)

    2012-12-01

    A method for Cr determination in medicinal plants using direct solid sampling graphite furnace high-resolution continuum source atomic absorption spectrometry was developed. Modifiers were dispensable. Pyrolysis and atomization temperatures were 1500 Degree-Sign C and 2400 Degree-Sign C, respectively. Slopes of calibration curves (50-750 pg Cr, R{sup 2} > 0.999) using aqueous and solid standards coincides in 96%, indicated feasibility of aqueous calibration for solid sampling of medicinal plants. Accuracy was checked by analysis of four plant certified reference materials. Results were in agreement at 95% confidence level with certified and non-certified values. Ten samples of medicinal plants were analyzed and Cr contents were in the 1.3-17.7 {mu}g g{sup -1} Cr range. The highest RSD (n = 5) was 15.4% for the sample Melissa officinalis containing 13.9 {+-} 2.1 {mu}g g{sup -1} Cr. The limit of detection was 3.3 ng g{sup -1} Cr. - Highlights: Black-Right-Pointing-Pointer Direct solid sampling is first time employed for Cr in plant materials. Black-Right-Pointing-Pointer Calibration curves with liquids and solids are coincident. Black-Right-Pointing-Pointer Microanalysis of plants for Cr is validated by reference materials. Black-Right-Pointing-Pointer The proposed HR-CS GF AAS method is environmental friendly.

  12. Optimization study of ultracold neutron sources at TRIGA reactors using MCNP

    International Nuclear Information System (INIS)

    Pokotilovskij, Yu.N.; Rogov, A.D.

    1997-01-01

    Monte Carlo simulation for the optimization of ultracold and very cold neutron sources for TRIGA reactors is performed. The calculations of thermal and cold neutron fluxes from the TRIGA reactor for different positions and configurations of a very cold solid methane moderator were performed with using the MCNP program. The production of neutrons in the ultracold and very cold energy range was calculated for the most promising final moderators (converters): very cold solid deuterium and heavy methane. The radiation energy deposition was calculated for the optimized solid methane-heavy methane cold neutron moderator

  13. Excitation of surface waves of ultracold neutrons on absorbing trap walls as anomalous loss factor

    International Nuclear Information System (INIS)

    Bokun, R.Ch.

    2006-01-01

    One analyzed probability of excitation of surface waves of ultracold neutrons in terms of a plane model consisting of three media: vacuum, a finite depth neutron absorbing substance layer and a neutron reflecting substrate. One demonstrated the absence of the mentioned surface waves in terms of the generally accepted model of two media: vacuum contiguous to the plane surface of a substance filled half-space. One pointed out the effect of the excited surface waves of ultracold neutrons on the increase of their anomalous losses in traps [ru

  14. Determination of the Axial-Vector Weak Coupling Constant with Ultracold Neutrons

    International Nuclear Information System (INIS)

    Liu, J.; Mendenhall, M. P.; Carr, R.; Filippone, B. W.; Hickerson, K. P.; Perez Galvan, A.; Russell, R.; Holley, A. T.; Hoagland, J.; VornDick, B.; Back, H. O.; Pattie, R. W. Jr.; Young, A. R.; Bowles, T. J.; Clayton, S.; Currie, S.; Hogan, G. E.; Ito, T. M.; Makela, M.; Morris, C. L.

    2010-01-01

    A precise measurement of the neutron decay β asymmetry A 0 has been carried out using polarized ultracold neutrons from the pulsed spallation ultracold neutron source at the Los Alamos Neutron Science Center. Combining data obtained in 2008 and 2009, we report A 0 =-0.119 66±0.000 89 -0.00140 +0.00123 , from which we determine the ratio of the axial-vector to vector weak coupling of the nucleon g A /g V =-1.275 90 -0.00445 +0.00409 .

  15. Submicron Positioning of Single Atoms in a Microcavity

    International Nuclear Information System (INIS)

    Nussmann, Stefan; Hijlkema, Markus; Weber, Bernhard; Rohde, Felix; Rempe, Gerhard; Kuhn, Axel

    2005-01-01

    The coupling of individual atoms to a high-finesse optical cavity is precisely controlled and adjusted using a standing-wave dipole-force trap, a challenge for strong atom-cavity coupling. Ultracold Rubidium atoms are first loaded into potential minima of the dipole trap in the center of the cavity. Then we use the trap as a conveyor belt that we set into motion perpendicular to the cavity axis. This allows us to repetitively move atoms out of and back into the cavity mode with a repositioning precision of 135 nm. This makes it possible to either selectively address one atom of a string of atoms by the cavity, or to simultaneously couple two precisely separated atoms to a higher mode of the cavity

  16. Preparation and Loading Process of Single Crystalline Samples into a Gas Environmental Cell Holder for In Situ Atomic Resolution Scanning Transmission Electron Microscopic Observation.

    Science.gov (United States)

    Straubinger, Rainer; Beyer, Andreas; Volz, Kerstin

    2016-06-01

    A reproducible way to transfer a single crystalline sample into a gas environmental cell holder for in situ transmission electron microscopic (TEM) analysis is shown in this study. As in situ holders have only single-tilt capability, it is necessary to prepare the sample precisely along a specific zone axis. This can be achieved by a very accurate focused ion beam lift-out preparation. We show a step-by-step procedure to prepare the sample and transfer it into the gas environmental cell. The sample material is a GaP/Ga(NAsP)/GaP multi-quantum well structure on Si. Scanning TEM observations prove that it is possible to achieve atomic resolution at very high temperatures in a nitrogen environment of 100,000 Pa.

  17. Universal relations of an ultracold Fermi gas with arbitrary spin-orbit coupling

    Science.gov (United States)

    Jie, Jianwen; Qi, Ran; Zhang, Peng

    2018-05-01

    We derive the universal relations for an ultracold two-component Fermi gas with a spin-orbit coupling (SOC) ∑α,β =x ,y ,zλα βσαpβ , where px ,y ,z and σx ,y ,z are the single-atom momentum and Pauli operators for pseudospin, respectively, and the SOC intensity λα β could take an arbitrary value. We consider the system with an s -wave short-range interspecies interaction, and ignore the SOC-induced modification for the value of the scattering length. Using the first-quantized approach developed by Tan [S. Tan, Phys. Rev. Lett. 107, 145302 (2011), 10.1103/PhysRevLett.107.145302], we obtain the short-range and high-momentum expansions for the one-body real-space correlation function and momentum distribution function, respectively. For our system these functions are a 2 ×2 matrix in the pseudospin basis. We find that the leading-order (1 /k4 ) behavior of the diagonal elements of the momentum distribution function, i.e., n↑↑(k ) and n↓↓(k ) , are not modified by the SOC. However, the SOC can significantly modify the large-k behaviors of the distribution difference δ n (k ) ≡n↑↑(k ) -n↓↓(k ) as well as the nondiagonal elements of the momentum distribution function, i.e., n↑↓(k ) and n↓↑(k ) . In the absence of the SOC, the leading order of δ n (k ) , n↑↓(k ) , and n↓↑(k ) is O (1 /k6) . When SOC appears, it can induce a term on the order of 1 /k5 for these elements. We further derive the adiabatic relation and the energy functional. Our results show that the SOC can induce an additional term in the energy functional, which describes the contribution from the SOC to the total energy. In addition, the form of the adiabatic relation for our system is not modified by the SOC. Our results are applicable for the systems with any type of single-atom trapping potential, which could be either diagonal or nondiagonal in the pseudospin basis.

  18. Superfluid and antiferromagnetic phases in ultracold fermionic quantum gases

    International Nuclear Information System (INIS)

    Gottwald, Tobias

    2010-01-01

    In this thesis several models are treated, which are relevant for ultracold fermionic quantum gases loaded onto optical lattices. In particular, imbalanced superfluid Fermi mixtures, which are considered as the best way to realize Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) states experimentally, and antiferromagnetic states, whose experimental realization is one of the next major goals, are examined analytically and numerically with the use of appropriate versions of the Hubbard model. The usual Bardeen-Cooper-Schrieffer (BCS) superconductor is known to break down in a magnetic field with a strength exceeding the size of the superfluid gap. A spatially inhomogeneous spin-imbalanced superconductor with a complex order parameter known as FFLO-state is predicted to occur in translationally invariant systems. Since in ultracold quantum gases the experimental setups have a limited size and a trapping potential, we analyze the realistic situation of a non-translationally invariant finite sized Hubbard model for this purpose. We first argue analytically, why the order parameter should be real in a system with continuous coordinates, and map our statements onto the Hubbard model with discrete coordinates defined on a lattice. The relevant Hubbard model is then treated numerically within mean field theory. We show that the numerical results agree with our analytically derived statements and we simulate various experimentally relevant systems in this thesis. Analogous calculations are presented for the situation at repulsive interaction strength where the N'eel state is expected to be realized experimentally in the near future. We map our analytical results obtained for the attractive model onto corresponding results for the repulsive model. We obtain a spatially invariant unit vector defining the direction of the order parameter as a consequence of the trapping potential, which is affirmed by our mean field numerical results for the repulsive case. Furthermore, we observe

  19. Superfluid and antiferromagnetic phases in ultracold fermionic quantum gases

    Energy Technology Data Exchange (ETDEWEB)

    Gottwald, Tobias

    2010-08-27

    In this thesis several models are treated, which are relevant for ultracold fermionic quantum gases loaded onto optical lattices. In particular, imbalanced superfluid Fermi mixtures, which are considered as the best way to realize Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) states experimentally, and antiferromagnetic states, whose experimental realization is one of the next major goals, are examined analytically and numerically with the use of appropriate versions of the Hubbard model. The usual Bardeen-Cooper-Schrieffer (BCS) superconductor is known to break down in a magnetic field with a strength exceeding the size of the superfluid gap. A spatially inhomogeneous spin-imbalanced superconductor with a complex order parameter known as FFLO-state is predicted to occur in translationally invariant systems. Since in ultracold quantum gases the experimental setups have a limited size and a trapping potential, we analyze the realistic situation of a non-translationally invariant finite sized Hubbard model for this purpose. We first argue analytically, why the order parameter should be real in a system with continuous coordinates, and map our statements onto the Hubbard model with discrete coordinates defined on a lattice. The relevant Hubbard model is then treated numerically within mean field theory. We show that the numerical results agree with our analytically derived statements and we simulate various experimentally relevant systems in this thesis. Analogous calculations are presented for the situation at repulsive interaction strength where the N'eel state is expected to be realized experimentally in the near future. We map our analytical results obtained for the attractive model onto corresponding results for the repulsive model. We obtain a spatially invariant unit vector defining the direction of the order parameter as a consequence of the trapping potential, which is affirmed by our mean field numerical results for the repulsive case. Furthermore, we observe

  20. Two-stage crossed beam cooling with ⁶Li and ¹³³Cs atoms in microgravity.

    Science.gov (United States)

    Luan, Tian; Yao, Hepeng; Wang, Lu; Li, Chen; Yang, Shifeng; Chen, Xuzong; Ma, Zhaoyuan

    2015-05-04

    Applying the direct simulation Monte Carlo (DSMC) method developed for ultracold Bose-Fermi mixture gases research, we study the sympathetic cooling process of 6Li and 133Cs atoms in a crossed optical dipole trap. The obstacles to producing 6Li Fermi degenerate gas via direct sympathetic cooling with 133Cs are also analyzed, by which we find that the side-effect of the gravity is one of the main obstacles. Based on the dynamic nature of 6Li and 133Cs atoms, we suggest a two-stage cooling process with two pairs of crossed beams in microgravity environment. According to our simulations, the temperature of 6Li atoms can be cooled to T = 29.5 pK and T/TF = 0.59 with several thousand atoms, which propose a novel way to get ultracold fermion atoms with quantum degeneracy near pico-Kelvin.

  1. Universal Two-Body Spectra of Ultracold Harmonically Trapped Atoms in Two and Three Dimensions

    DEFF Research Database (Denmark)

    Zinner, Nikolaj Thomas

    2012-01-01

    of the short-range interaction. The results in three dimensions are examplified for narrow s-wave Feshbach resonances and we show how effective range corrections can modify the rearrangement of the level structure. However, this requires extremely narrow resonances or very tight traps that are not currently...

  2. Searching for Supersolidity in Ultracold Atomic Bose Condensates with Rashba Spin-Orbit Coupling

    Science.gov (United States)

    Liao, Renyuan

    2018-04-01

    We developed a functional integral formulation for the stripe phase of spinor Bose-Einstein condensates with Rashba spin-orbit coupling. The excitation spectrum is found to exhibit double gapless band structures, identified to be two Goldstone modes resulting from spontaneously broken internal gauge symmetry and translational invariance symmetry. The sound velocities display anisotropic behavior with the lower branch vanishing in the direction perpendicular to the stripe in the x -y plane. At the transition point between the plane-wave phase and the stripe phase, physical quantities such as fluctuation correction to the ground-state energy and quantum depletion of the condensates exhibit discontinuity, characteristic of the first-order phase transition. Despite strong quantum fluctuations induced by Rashba spin-orbit coupling, we show that the supersolid phase is stable against quantum depletion. Finally, we extend our formulation to finite temperatures to account for interactions between excitations.

  3. Phase-space curvature in spin-orbit-coupled ultracold atomic systems

    Science.gov (United States)

    Armaitis, J.; Ruseckas, J.; Anisimovas, E.

    2017-04-01

    We consider a system with spin-orbit coupling and derive equations of motion which include the effects of Berry curvatures. We apply these equations to investigate the dynamics of particles with equal Rashba-Dresselhaus spin-orbit coupling in one dimension. In our derivation, the adiabatic transformation is performed first and leads to quantum Heisenberg equations of motion for momentum and position operators. These equations explicitly contain position-space, momentum-space, and phase-space Berry curvature terms. Subsequently, we perform the semiclassical approximation and obtain the semiclassical equations of motion. Taking the low-Berry-curvature limit results in equations that can be directly compared to previous results for the motion of wave packets. Finally, we show that in the semiclassical regime, the effective mass of the equal Rashba-Dresselhaus spin-orbit-coupled system can be viewed as a direct effect of the phase-space Berry curvature.

  4. Long-range predissociation in two-color photoassociation of ultracold Na atoms

    NARCIS (Netherlands)

    Molenaar, P.A.; Straten, P. van der; Heideman, H.G.M.

    1997-01-01

    We report two-color photo-associative ionization of sodium in a Magneto-Optical Trap. The experimental results yield information on both singly and doubly excited states. We find that the highest bound vibrational levels (v > 20) of the singly-excited 0^- g state predissociate into the 3²P3/2

  5. Quantum Entangled Dark Solitons Formed by Ultracold Atoms in Optical Lattices

    International Nuclear Information System (INIS)

    Mishmash, R. V.; Carr, L. D.

    2009-01-01

    Inspired by experiments on Bose-Einstein condensates in optical lattices, we study the quantum evolution of dark soliton initial conditions in the context of the Bose-Hubbard Hamiltonian. An extensive set of quantum measures is utilized in our analysis, including von Neumann and generalized quantum entropies, quantum depletion, and the pair correlation function. We find that quantum effects cause the soliton to fill in. Moreover, soliton-soliton collisions become inelastic, in strong contrast to the predictions of mean-field theory. These features show that the lifetime and collision properties of dark solitons in optical lattices provide clear signals of quantum effects.

  6. Long-Range Predissociation in Two-Color Photoassociation of Ultracold Na Atoms

    International Nuclear Information System (INIS)

    Molenaar, P.A.; van der Straten, P.; Heideman, H.G.

    1996-01-01

    We report two-color photoassociative ionization of sodium in a magneto-optical trap. The experimental results yield information on both singly and doubly excited states. We find that the highest bound vibrational levels (v approx-gt 20) of the singly excited 0 g - state predissociate into the 3 2 P 3/2 +3 2 S 1/2 (F g =1) dissociation continuum due to avoided crossings of the hyperfine components of this potential with other molecular symmetries. Based on symmetry and energy consideration we argue that a doubly excited 1 u state remains autoionizing even when only a few GHz above the dissociation continuum. copyright 1996 The American Physical Society

  7. Quantum Simulation of the Hubbard Model Using Ultra-Cold Atoms

    Science.gov (United States)

    2008-11-01

    Hubbard model. The SU(3) Hubbard model has been proposed as a model system for studying different phases of matter expected to occur in quantum...chromodynamics (QCD): the color superconducting phase and the formation of baryons . Our initial investigations have focused on understanding three-body...density quark matter described by quantum chromodynamics . We have been investigating the stability of the 3-state Fermi gas with respect to decay due

  8. Rydberg Molecules for Ion-Atom Scattering in the Ultracold Regime

    Czech Academy of Sciences Publication Activity Database

    Schmid, T.; Veit, C.; Zuber, N.; Löw, I.; Pfau, T.; Tarana, Michal; Tomza, M.

    Roč. 120, č. 15 ( 2018 ), č. článku 153401. ISSN 0031-9007 R&D Projects: GA ČR(CZ) GP14-15989P Institutional support: RVO:61388955 Keywords : Ab initio calculations * Experimental methods * Interaction potentials Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 8.462, year: 2016

  9. Quantum Simulations of Condensed Matter Systems Using Ultra-Cold Atomic Gases

    Science.gov (United States)

    2013-03-01

    DD-MM-YYYY) 2. REPORT TYPE 3. DATES COVERED (From - To) 4. TITLE AND SUBTITLE 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 5d...M.    Moreno-­‐ Cardoner ,    T.    Kitagawa,    T.    Best,    S.    Will,          E.  Demler

  10. Sensitivity of ultracold-atom scattering experiments to variation of the fine-structure constant

    International Nuclear Information System (INIS)

    Borschevsky, A.; Beloy, K.; Flambaum, V. V.; Schwerdtfeger, P.

    2011-01-01

    We present numerical calculations for cesium and mercury to estimate the sensitivity of the scattering length to the variation of the fine-structure constant α. The method used follows the ideas of Chin and Flambaum [Phys. Rev. Lett. 96, 230801 (2006)], where the sensitivity to the variation of the electron-to-proton mass ratio β was considered. We demonstrate that for heavy systems, the sensitivity to the variation of α is of the same order of magnitude as to the variation of β. Near narrow Feshbach resonances, the enhancement of the sensitivity may exceed nine orders of magnitude.

  11. Many-body physics using cold atoms

    Science.gov (United States)

    Sundar, Bhuvanesh

    Advances in experiments on dilute ultracold atomic gases have given us access to highly tunable quantum systems. In particular, there have been substantial improvements in achieving different kinds of interaction between atoms. As a result, utracold atomic gases oer an ideal platform to simulate many-body phenomena in condensed matter physics, and engineer other novel phenomena that are a result of the exotic interactions produced between atoms. In this dissertation, I present a series of studies that explore the physics of dilute ultracold atomic gases in different settings. In each setting, I explore a different form of the inter-particle interaction. Motivated by experiments which induce artificial spin-orbit coupling for cold fermions, I explore this system in my first project. In this project, I propose a method to perform universal quantum computation using the excitations of interacting spin-orbit coupled fermions, in which effective p-wave interactions lead to the formation of a topological superfluid. Motivated by experiments which explore the physics of exotic interactions between atoms trapped inside optical cavities, I explore this system in a second project. I calculate the phase diagram of lattice bosons trapped in an optical cavity, where the cavity modes mediates effective global range checkerboard interactions between the atoms. I compare this phase diagram with one that was recently measured experimentally. In two other projects, I explore quantum simulation of condensed matter phenomena due to spin-dependent interactions between particles. I propose a method to produce tunable spin-dependent interactions between atoms, using an optical Feshbach resonance. In one project, I use these spin-dependent interactions in an ultracold Bose-Fermi system, and propose a method to produce the Kondo model. I propose an experiment to directly observe the Kondo effect in this system. In another project, I propose using lattice bosons with a large hyperfine spin

  12. Particle transport in a He-microchip plasma atomic emission system with an ultrasonic nebulizer for aqueous sample introduction

    Energy Technology Data Exchange (ETDEWEB)

    Oh, Joosuck [Department of Chemistry, Dankook University, 126 Jukjeon-dong, Suji-gu, Yongin-si, Gyeonggi-do, 448-701 (Korea, Republic of); Lim, H.B. [Department of Chemistry, Dankook University, 126 Jukjeon-dong, Suji-gu, Yongin-si, Gyeonggi-do, 448-701 (Korea, Republic of)], E-mail: plasma@dankook.ac.kr

    2008-11-15

    The transport efficiency of dried particles generated from an ultrasonic nebulizer (USN) was studied to improve the analytical performance of a lab-made, He-microchip plasma system, in which a quartz tube ({approx} 1 mm i.d.) was positioned inside the central channel of a poly(dimethylsiloxane) (PDMS) polymer chip. The polymer microchip plasma has the advantages of low cost, small size, easy handling and design, and self-ignition with long stabilization (> 24 h). However, direct introduction of aqueous solution into the microplasma for the detection of metals remains problematic due to plasma instability. In addition, the much smaller size of the system can cause signal suppression due to low transport efficiency. Therefore, knowledge of particle transport efficiency in this microplasma system is required to enhance the sensitivity and stability. The weight of transported particles in the range of 0.02 to 10 mg m{sup -3} was measured using a piezobalance with a precision of 0.4-17.8%, depending on the operating conditions. The significant effects of the USN operating conditions and the physical properties of the tubing, namely, length, inner diameter and surface characteristics, on the number of particles transported from the nebulizer to the microplasma were studied. When selected metals, such as Na, Mg and Pb, at a concentration of 5 mg L{sup -1} were nebulized, transported particles were obtained with a mass range of 0.5-5 mg m{sup -3}, depending on atomic weights. For application of the He-rf-microplasma, the atomic emission system was optimized by changing both the radio frequency (rf) power (60-200 W) and cooling temperature of the USN (- 12-9 deg. C). The limits of detection obtained for K, Na and Cu were 0.26, 0.22, and 0.28 mg L{sup -1}, respectively. These results confirmed the suitable stability and sensitivity of the He-rf-PDMS microchip plasma for application as an atomization source.

  13. A study of energy and effective atomic number dependence of the exposure build-up factors in biological samples

    International Nuclear Information System (INIS)

    Sidhu, G.S.; Singh, P.S.; Mudahar, G.S.

    2000-01-01

    A theoretical method is presented to determine the gamma-radiation build-up factors in various biological materials. The gamma energy range is 0.015-15.0 MeV, with penetration depths up to 40 mean free paths considered. The dependence of the exposure build-up factor on incident photon energy and the effective atomic number (Z eff ) has also been assessed. In a practical analysis of dose burden to gamma-irradiated biological materials, the sophistication of Monte Carlo computer techniques would be applied, with associated detailed modelling. However, a feature of the theoretical method presented is its ability to make the consequences of the physics of the scattering process in biological materials more transparent. In addition, it can be quickly employed to give a first-pass dose estimate prior to a more detailed computer study. (author)

  14. Non-destructive depth profiling of solid samples by atomic and nuclear interactions induced by charged particles

    International Nuclear Information System (INIS)

    Demortier, Guy

    2003-01-01

    The study of complex materials (non-homogeneous matrices containing medium and/or heavy atoms as major elements) by Particle Induced X-Ray Emission (PIXE) requires the tailoring of the experimental set up to take into account the high X-ray intensity produced by these main elements present at the surface, as well as the expected low intensity from other elements 'buried' in the substrate. The determination of traces is therefore limited and the minimum detection limit is generally higher by at least two orders of magnitude in comparison with those achievable for low Z matrices (Z≤20). Additionally, those high Z matrices, having a high absorption capability, are not always homogeneous. The non-homogeneity may be, on the one hand, a layered structure (which is uneasy to profile by Rutherford Backscattering Spectroscopy (RBS) if the material contains elements of neighbouring atomic masses or if the layered structure extends on several microns). PIXE measurements at various incident energies (and with various projectiles (p, d, He 3 , He 4 )) are an alternative method to overcome those difficulties. The use of special filters to selectively decrease the intensity of the most intense X-ray lines, the accurate calculation of the characteristic X-ray intensity ratios (Kα/Kβ, Lα/Lβ) of individual elements, the computation of the secondary X-ray fluorescence induced in thick targets are amongst the most important parameters to be investigated in order to solve these analytical problems. Examples of Al, Si, Cu, Ag, Au based alloys as encountered in industrial and archaeological metallurgy are discussed. The non-destructive aspect of the ion beam techniques is proved by applying the method in vivo for the study of fluorine migration in tooth enamel. Preliminary results on the composition of the blocks of the pyramid of Cheops are presented in the scope of a complete revision of the procedure of its construction

  15. Selective reduction of arsenic species by hydride generation - atomic absorption spectrometry. Part 2 - sample storage and arsenic determination in natural waters

    Directory of Open Access Journals (Sweden)

    Quináia Sueli P.

    2001-01-01

    Full Text Available Total arsenic, arsenite, arsinate and dimethylarsinic acid (DMA were selectively determined in natural waters by hydride generation - atomic absorption spectrometry, using sodium tetrahydroborate(III as reductant but in different reduction media. River water samples from the north region of Paraná State, Brazil, were analysed and showed arsenate as the principal arsenical form. Detection limits found for As(III (citrate buffer, As(III + DMA (acetic acid and As(III + As(V (hydrochloric acid were 0.6, 1.1 and 0.5 mg As L-1, respectively. Sample storage on the proper reaction media revealed to be a useful way to preserve the water sample.

  16. Optimization of microwave assisted digestion procedure for the determination of zinc, copper and nickel in tea samples employing flame atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Soylak, Mustafa; Tuzen, Mustafa; Souza, Anderson Santos; Korn, Maria das Gracas Andrade; Ferreira, Sergio Luis Costa

    2007-01-01

    The present paper describes the development of a microwave assisted digestion procedure for the determination of zinc, copper and nickel in tea samples employing flame atomic absorption spectrometry (FAAS). The optimization step was performed using a full factorial design (2 3 ) involving the factors: composition of the acid mixture (CMA), microwave power (MP) and radiation time (RT). The experiments of this factorial were carried out using a certified reference material of tea GBW 07605 furnished by National Research Centre for Certified Reference Materials, China, being the metal recoveries considered as response. The relative standard deviations of the method were found below 8% for the three elements. The procedure proposed was used for the determination of copper, zinc and nickel in several samples of tea from Turkey. For 10 tea samples analyzed, the concentration achieved for copper, zinc and nickel varied at 6.4-13.1, 7.0-16.5 and 3.1-5.7 (μg g -1 ), respectively

  17. Determination of benzothiazole and alkylphosphates in water samples from the Great Lakes Drainage Basin by gas chromatography/atomic emission detection

    Energy Technology Data Exchange (ETDEWEB)

    Scott, B.F. [Environment Canada, Burlington, ON (Canada). Wastewater Technology Centre; Sverko, E.; Maguire, R.J. [Environment Canada, Burlington, ON (Canada). Wastewater Technology Centre

    1996-06-01

    Centrifuged water extracts from large receiving water bodies were analyzed for heteroatom-containing compounds. Extracts from aqueous environmental samples were analyzed by gas chromatography/atomic emission detection for P-, S-, and N- containing compounds. The samples exhibited complex chromatographic traces. Benzothiazole, tri-n-butylphosphate, tris(2-chloroethyl)phosphate, tris({beta}-chloroisopropyl)phosphate and two isomers of this last chemical were detected in all archived water extracts collected from permanent sampling stations at Fort Erie, Niagara-on-the-Lake and Wolfe Island. The concentrations of the trialkylphosphates reported in this study were at least four orders of magnitude lower than concentrations of some other trialkylphosphates and triarylphosphates that cause acute toxicity to rainbow trout, water fleas, midge larvae and shrimp. Further work on trialkylphosphates is under way to assess their environmental distribution, their levels in industrial and municipal effluents and their acute and chronic toxicity to aquatic organisms. 32 refs., 3 tabs., 5 figs.

  18. Influence of citric acid as chemical modifier for lead determination in dietary calcium supplement samples by graphite furnace atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Cezar Paz de Mattos, Julio; Medeiros Nunes, Adriane; Figueiredo Martins, Ayrton; Luiz Dressler, Valderi; Marlon de Moraes Flores, Erico

    2005-01-01

    Citric acid was used as a chemical modifier for Pb determination by graphite furnace atomic absorption spectrometry in dietary supplement samples (calcium carbonate, dolomite and oyster shell samples) and its efficiency was compared to the use of palladium. Pyrolysis and atomization curves were established without use of chemical modifier, with the addition of 20, 100 and 200 μg of citric acid, and with 3 μg of palladium. The citric acid modifier made possible the interference-free Pb determination in the presence of high concentrations of Ca and Mg nitrates. Acid sample digestion involving closed vessels (microwave-assisted and conventional heating) and acid attack using polypropylene vessels at room temperature were compared. All digestion procedures presented similar results for calcium carbonate and dolomite samples. However, for oyster shell samples accurate results were obtained only with the use of closed vessel systems. Analyte addition and matrix-matched standards were used for calibration. The characteristic mass for Pb using citric acid and palladium were 16 and 25 pg, respectively. The relative standard deviation (RSD) was always less than 5% when citric acid was used. The relative and absolute limits of detection were 0.02 μg g -1 and 8 pg with citric acid and 0.1 μg g -1 and 44 pg with the Pd modifier, respectively (n = 10, 3σ). The recovery of Pb in spiked calcium supplement samples (10 μg l -1 ) was between 98% and 105%. With the use of 100 μg of citric acid as chemical modifier, problems such as high background absorption and high RSD values were minimized in comparison to the addition of 3 μg of palladium

  19. Direct determination of chromium in infant formulas employing high-resolution continuum source electrothermal atomic absorption spectrometry and solid sample analysis.

    Science.gov (United States)

    Silva, Arlene S; Brandao, Geovani C; Matos, Geraldo D; Ferreira, Sergio L C

    2015-11-01

    The present work proposed an analytical method for the direct determination of chromium in infant formulas employing the high-resolution continuum source electrothermal atomic absorption spectrometry combined with the solid sample analysis (SS-HR-CS ET AAS). Sample masses up to 2.0mg were directly weighted on a solid sampling platform and introduced into the graphite tube. In order to minimize the formation of carbonaceous residues and to improve the contact of the modifier solution with the solid sample, a volume of 10 µL of a solution containing 6% (v/v) H2O2, 20% (v/v) ethanol and 1% (v/v) HNO3 was added. The pyrolysis and atomization temperatures established were 1600 and 2400 °C, respectively, using magnesium as chemical modifier. The calibration technique was evaluated by comparing the slopes of calibration curves established using aqueous and solid standards. This test revealed that chromium can be determined employing the external calibration technique using aqueous standards. Under these conditions, the method developed allows the direct determination of chromium with limit of quantification of 11.5 ng g(-1), precision expressed as relative standard deviation (RSD) in the range of 4.0-17.9% (n=3) and a characteristic mass of 1.2 pg of chromium. The accuracy was confirmed by analysis of a certified reference material of tomato leaves furnished by National Institute of Standards and Technology. The method proposed was applied for the determination of chromium in five different infant formula samples. The chromium content found varied in the range of 33.9-58.1 ng g(-1) (n=3). These samples were also analyzed employing ICP-MS. A statistical test demonstrated that there is no significant difference between the results found by two methods. The chromium concentrations achieved are lower than the maximum limit permissible for chromium in foods by Brazilian Legislation. Copyright © 2015. Published by Elsevier B.V.

  20. Ultracold neutron detectors based on {sup 10}B converters used in the qBounce experiments

    Energy Technology Data Exchange (ETDEWEB)

    Jenke, Tobias, E-mail: tjenke@ati.ac.at [Atominstitut TU Wien, Stadionallee 2, 1020 Wien (Austria); Cronenberg, Gunther; Filter, Hanno [Atominstitut TU Wien, Stadionallee 2, 1020 Wien (Austria); Geltenbort, Peter [Institut Laue-Langevin, 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France); Klein, Martin [Physikalisches Institut Universität Heidelberg, Im Neuenheimer Feld 226, 69120 Heidelberg (Germany); Lauer, Thorsten [FRM II, TU München, Lichtenbergstraße 1, 85748 Garching (Germany); Mitsch, Kevin [Atominstitut TU Wien, Stadionallee 2, 1020 Wien (Austria); Saul, Heiko [Atominstitut TU Wien, Stadionallee 2, 1020 Wien (Austria); FRM II, TU München, Lichtenbergstraße 1, 85748 Garching (Germany); Seiler, Dominik [Physik Department, TU München, James-Franck-Straße, 85748 Garching (Germany); Stadler, David [Physikalisches Institut Universität Heidelberg, Im Neuenheimer Feld 226, 69120 Heidelberg (Germany); Thalhammer, Martin [Atominstitut TU Wien, Stadionallee 2, 1020 Wien (Austria); Abele, Hartmut, E-mail: abele@ati.ac.at [Atominstitut TU Wien, Stadionallee 2, 1020 Wien (Austria); Physikalisches Institut Universität Heidelberg, Im Neuenheimer Feld 226, 69120 Heidelberg (Germany); Physik Department, TU München, James-Franck-Straße, 85748 Garching (Germany)

    2013-12-21

    Gravity experiments with very slow, so-called ultracold neutrons connect quantum mechanics with tests of Newton's inverse square law at short distances. These experiments face a low count rate and hence need highly optimized detector concepts. In the frame of this paper, we present low-background ultracold neutron counters and track detectors with micron resolution based on a {sup 10}B converter. We discuss the optimization of {sup 10}B converter layers, detector design and concepts for read-out electronics focusing on high-efficiency and low-background. We describe modifications of the counters that allow one to detect ultracold neutrons selectively on their spin-orientation. This is required for searches of hypothetical forces with spin–mass couplings. The mentioned experiments utilize a beam-monitoring concept which accounts for variations in the neutron flux that are typical for nuclear research facilities. The converter can also be used for detectors, which feature high efficiencies paired with high spatial resolution of 1–2μm. They allow one to resolve the quantum mechanical wave function of an ultracold neutron bound in the gravity potential above a neutron mirror.

  1. Radio frequency acceleration and manipulation of ultra-cold electron bunches

    NARCIS (Netherlands)

    Franssen, J.G.H.; Vredenbregt, E.J.D.; Luiten, O.J.

    2016-01-01

    We are developing an ultra-fast and ultra-cold electron source based on a grating magneto optical trap, RF acceleration and RF (de-) compression techniques. The electrons will be created by near-threshold, femtosecond photoionization of a laser-cooled and trapped gas. The electron cloud is extracted

  2. To the problem of spatial focusing of ultracold neutrons by nonuniform magnetic field. Eikonal approximation

    CERN Document Server

    Chen, T

    2002-01-01

    Motion of the ultracold neutrons in the nonuniform magnetic field with a square nonuniformity by two coordinates is considered. The Schroedinger equation is solved with application of the quasi-classical (eikonal) approach. The theoretical possibility of the neutrons spatial focusing with formation of the point focus and also the neutrons bunches is shown

  3. Analysis of the Alkali Metal Diatomic Spectra; Using molecular beams and ultracold molecules

    Science.gov (United States)

    Kim, Jin-Tae

    2014-12-01

    This ebook illustrates the complementarity of molecular beam (MB) spectra and ultracold molecule (UM) spectra in unraveling the complex electronic spectra of diatomic alkali metal molecules, using KRb as a prime example. Researchers interested in molecular spectroscopy, whether physicist, chemist, or engineer, may find this ebook helpful and may be able to apply similar ideas to their molecules of interest.

  4. Ultra-cold WIMPs relics of non-standard pre-BBN cosmologies

    CERN Document Server

    Gelmini, Graciela B

    2008-01-01

    We point out that in scenarios in which the Universe evolves in a non-standard manner during and after the kinetic decoupling of weakly interacting massive particles (WIMPs), these relics can be much colder than in standard cosmological scenarios (i.e. can be ultra-cold), possibly leading to the formation of smaller first objects in hierarchical structure formation scenarios.

  5. Measurement of the time of storage of ultracold neutrons in a magnetic trap

    International Nuclear Information System (INIS)

    Abov, Y.G.; Borovlev, S.P.; Vasil'ev, V.V.; Vladimirskii, V.V.; Mospan, E.N.

    1983-01-01

    The storage time of ultracold neutrons in an axial magnetic trap with a simple singly connected confinement region is measured. It is shown that the storage of the neutrons is due just to the magnetic field. The storage time achieved is tau = 303 +- 37 sec. In a working cycle 3.6 neutrons are accumulated

  6. Moving converter as the possible tool for producing ultra-cold neutrons on pulsed neutron sources

    International Nuclear Information System (INIS)

    Pokotilovskij, Yu.N.

    1991-01-01

    A method is proposed for producing ultra-cold neutrons (UCN) at aperiodic pulse neutron sources. It is based on the use of the fast moving cooled converter of UCN in the time of the neutron pulse and includes the trapping of generated UCN's in a moving trap. 6 refs.; 2 figs

  7. Test of the fast thin-film ferromagnetic shutters for ultracold neutrons

    International Nuclear Information System (INIS)

    Pokotilovskij, Yu.N.; Novopol'tsev, M.I.; Geltenbort, P.

    2008-01-01

    Test of thin-film ferromagnetic shutters of two types for ultracold neutrons has been performed. The first type is based on neutron reflection from the sequence of successively placed thin ferromagnetic layers with oppositely directed magnetization. The second one is based on neutron refraction in ferromagnetic foils inserted in the beam

  8. Graphite furnace atomic absorption spectrometric determination of Ni and Pb in diesel and gasoline samples stabilized as microemulsion using conventional and permanent modifiers

    International Nuclear Information System (INIS)

    Matos Reyes, Mariela N.; Campos, Reinaldo C.

    2005-01-01

    A procedure for the graphite furnace atomic absorption spectrometric determination of Ni and Pb in diesel and gasoline samples was developed. Sample stabilization was necessary because of evident analyte losses that occurred immediately after sampling. Excellent long-term sample stabilization was observed by mixing different organic solvents with propan-1-ol and 50% vol/vol HNO 3 at a 3.3:6.5:1 volume ratio. For Pb, efficient thermal stabilization was obtained using aqueous Pd-Mg modifier as well as for Ir as permanent modifier. The drying temperature and ramp rate influenced the sensitivity obtained for Ni, and had to be carefully optimized. Taking this into account, the same sensitivity was attained in all investigated organic media stabilized as microemulsion. Thus, calibration with microemulsions prepared with a single organic solvent was possible, using aqueous or organic stock solutions. Commercial gasoline and diesel samples were directly analyzed after stabilization as microemulsion and by comparative UOP procedures. n-Hexane microemulsions were used for calibration, and good agreement was obtained between the results using the proposed and comparative procedures. Typical coefficients of variation (n = 6) ranged from 1% to 4%, and from 1% to 3% for Ni and Pb, respectively. Detection limits (k = 3) in the original gasoline or diesel samples, derived from 10 blank measurements, were 4.5 and 3.6 μg l -1 for Ni and Pb, respectively, comfortably below the values found in the analyzed samples

  9. Investigating effects of sample pretreatment on protein stability using size-exclusion chromatography and high-resolution continuum source atomic absorption spectrometry.

    Science.gov (United States)

    Rakow, Tobias; El Deeb, Sami; Hahne, Thomas; El-Hady, Deia Abd; AlBishri, Hassan M; Wätzig, Hermann

    2014-09-01

    In this study, size-exclusion chromatography and high-resolution atomic absorption spectrometry methods have been developed and evaluated to test the stability of proteins during sample pretreatment. This especially includes different storage conditions but also adsorption before or even during the chromatographic process. For the development of the size exclusion method, a Biosep S3000 5 μm column was used for investigating a series of representative model proteins, namely bovine serum albumin, ovalbumin, monoclonal immunoglobulin G antibody, and myoglobin. Ambient temperature storage was found to be harmful to all model proteins, whereas short-term storage up to 14 days could be done in an ordinary refrigerator. Freezing the protein solutions was always complicated and had to be evaluated for each protein in the corresponding solvent. To keep the proteins in their native state a gentle freezing temperature should be chosen, hence liquid nitrogen should be avoided. Furthermore, a high-resolution continuum source atomic absorption spectrometry method was developed to observe the adsorption of proteins on container material and chromatographic columns. Adsorption to any container led to a sample loss and lowered the recovery rates. During the pretreatment and high-performance size-exclusion chromatography, adsorption caused sample losses of up to 33%. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. A new approach for the determination of sulphur in food samples by high-resolution continuum source flame atomic absorption spectrometer.

    Science.gov (United States)

    Ozbek, N; Baysal, A

    2015-02-01

    The new approach for the determination of sulphur in foods was developed, and the sulphur concentrations of various fresh and dried food samples determined using a high-resolution continuum source flame atomic absorption spectrometer with an air/acetylene flame. The proposed method was optimised and the validated using standard reference materials, and certified values were found to be within the 95% confidence interval. The sulphur content of foods ranged from less than the LOD to 1.5mgg(-1). The method is accurate, fast, simple and sensitive. Copyright © 2014 Elsevier Ltd. All rights reserved.

  11. Atom history, from intuitive ideas to reality

    International Nuclear Information System (INIS)

    Radvanyi, P.

    2007-01-01

    This book gathers the ground scientific texts that have stood out as milestones in the way scientists have built their understanding of the atom over centuries. From the very intuitive ideas of Greek philosophers to the most recent results on ultra-cold atoms, via the discovery of natural radioactivity or the existence of the neutron, about 55 articles written by prestigious physicists have been organized into 16 chapters. Each chapter being dedicated to a topic such as molecules, spectroscopy, electrons, X-rays, atom mass, artificial radioactivity..., begins with a commentary that draws the scientific context of that time, describes the links between the articles and highlights the importance of the discoveries. (A.C.)

  12. Controlling interactions between highly magnetic atoms with Feshbach resonances.

    Science.gov (United States)

    Kotochigova, Svetlana

    2014-09-01

    This paper reviews current experimental and theoretical progress in the study of dipolar quantum gases of ground and meta-stable atoms with a large magnetic moment. We emphasize the anisotropic nature of Feshbach resonances due to coupling to fast-rotating resonant molecular states in ultracold s-wave collisions between magnetic atoms in external magnetic fields. The dramatic differences in the distribution of resonances of magnetic (7)S3 chromium and magnetic lanthanide atoms with a submerged 4f shell and non-zero electron angular momentum is analyzed. We focus on dysprosium and erbium as important experimental advances have been recently made to cool and create quantum-degenerate gases for these atoms. Finally, we describe progress in locating resonances in collisions of meta-stable magnetic atoms in electronic P-states with ground-state atoms, where an interplay between collisional anisotropies and spin-orbit coupling exists.

  13. Cadmium and lead determination in foods by beam injection flame furnace atomic absorption spectrometry after ultrasound-assisted sample preparation

    International Nuclear Information System (INIS)

    Aleixo, Poliana Carolina; Junior, Dario Santos; Tomazelli, Andrea Cristina; Rufini, Iolanda A.; Berndt, Harald; Krug, Francisco Jose

    2004-01-01

    A simple method for cadmium and lead determination in foods by beam injection flame furnace atomic absorption spectrometry (BIFF-AAS) was proposed. Food slurries were prepared by transferring an exact amount of cryogenic-ground homogenized material (50-100 mg) to centrifuge tubes, followed by addition of 5 ml (up to 2.8 mol l -1 ) nitric acid solution and sonication in an ultrasonic bath during 5-10 min. Thereafter, slurries were diluted with water to 10 ml, centrifuged during 5 min at 5400 rpm and 400 μl aliquot of the supernatant was analyzed by BIFF-AAS. The detection limits based on peak height measurements were 0.03 μg g -1 Cd and 1.6 μg g -1 Pb for 2% (m/v) slurry (200 mg/10 ml). For method validation, the certified reference materials Pig Kidney (BCR 186) and Rice Flour (NIES 10) were used. Quantitative cadmium and lead recoveries were obtained and no statistical differences were found at 95% level by applying the t-test

  14. Lamb-Dicke spectroscopy of atoms in a hollow-core photonic crystal fibre

    Science.gov (United States)

    Okaba, Shoichi; Takano, Tetsushi; Benabid, Fetah; Bradley, Tom; Vincetti, Luca; Maizelis, Zakhar; Yampol'skii, Valery; Nori, Franco; Katori, Hidetoshi

    2014-01-01

    Unlike photons, which are conveniently handled by mirrors and optical fibres without loss of coherence, atoms lose their coherence via atom–atom and atom–wall interactions. This decoherence of atoms deteriorates the performance of atomic clocks and magnetometers, and also hinders their miniaturization. Here we report a novel platform for precision spectroscopy. Ultracold strontium atoms inside a kagome-lattice hollow-core photonic crystal fibre are transversely confined by an optical lattice to prevent atoms from interacting with the fibre wall. By confining at most one atom in each lattice site, to avoid atom–atom interactions and Doppler effect, a 7.8-kHz-wide spectrum is observed for the 1S0−3P1(m=0) transition. Atoms singly trapped in a magic lattice in hollow-core photonic crystal fibres improve the optical depth while preserving atomic coherence time. PMID:24934478

  15. Investigation of chemical modifiers for the determination of lead in fertilizers and limestone using graphite furnace atomic absorption spectrometry with Zeeman-effect background correction and slurry sampling

    Energy Technology Data Exchange (ETDEWEB)

    Borges, Aline R. [Instituto de Química, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves 9500, 91501-970 Porto Alegre, RS (Brazil); Instituto Nacional de Ciência e Tecnologia do CNPq–INCT de Energia e Ambiente, Universidade Federal da Bahia, Salvador, BA (Brazil); Becker, Emilene M.; Dessuy, Morgana B. [Instituto de Química, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves 9500, 91501-970 Porto Alegre, RS (Brazil); Vale, Maria Goreti R., E-mail: mgrvale@ufrgs.br [Instituto de Química, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves 9500, 91501-970 Porto Alegre, RS (Brazil); Instituto Nacional de Ciência e Tecnologia do CNPq–INCT de Energia e Ambiente, Universidade Federal da Bahia, Salvador, BA (Brazil); Welz, Bernhard [Instituto Nacional de Ciência e Tecnologia do CNPq–INCT de Energia e Ambiente, Universidade Federal da Bahia, Salvador, BA (Brazil); Departamento de Química, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, SC (Brazil)

    2014-02-01

    In this work, chemical modifiers in solution (Pd/Mg, NH{sub 4}H{sub 2}PO{sub 4} and NH{sub 4}NO{sub 3}/Pd) were compared with permanent modifiers (Ir and Ru) for the determination of lead in fertilizer and limestone samples using slurry sampling and graphite furnace atomic absorption spectrometry with Zeeman-effect background correction. The analytical line at 283.3 nm was used due to some spectral interference observed at 217.0 nm. The NH{sub 4}H{sub 2}PO{sub 4} was abandoned due to severe spectral interference even at the 283.3-nm line. For Pd/Mg and NH{sub 4}NO{sub 3}/Pd the optimum pyrolysis and atomization temperatures were 900 °C and 1900 °C, respectively. For Ru and Ir, the integrated absorbance signal was stable up to pyrolysis temperatures of 700 °C and 900 °C, respectively, and up to atomization temperature of 1700 °C. The limit of detection (LOD) was 17 ng g{sup −1} using Pd/Mg and 29 ng g{sup −1} using NH{sub 4}NO{sub 3}/Pd. Among the permanent modifiers investigated, the LOD was 22 ng g{sup −1} Pb for Ir and 10 ng g{sup −1} Pb for Ru. The accuracy of the method was evaluated using the certified reference material NIST SRM 695. Although Ru provided lower LOD, which can be attributed to a lower blank signal, only the modifiers in solution showed concordant values of Pb concentration for the NIST SRM 695 and the most of analyzed samples. Moreover, the Pd/Mg modifier provided the highest sensitivity and for this reason it is more suitable for the determination of Pb in fertilizers samples in slurry; besides this it presented a better signal-to-noise ratio than NH{sub 4}NO{sub 3}/Pd. - Highlights: • Lead has been determined in fertilizers using slurry sampling GF AAS. • The mixture of palladium and magnesium nitrates was found to be the ideal chemical modifier. • Calibration could be carried out against aqueous standard solutions. • The proposed method is much faster than the EPA method, which includes sample digestion.

  16. Cold atoms in a cryogenic environment

    International Nuclear Information System (INIS)

    Haslinger, S.

    2011-01-01

    The idea of quantum information processing attracts increasingly interest, where a complex collection of quantum objects and quantum bits are employed to find the ideal building blocks for quantum information systems. Hybrid quantum systems are therefore promising objects as they countervail the particular drawbacks of single quantum objects. Based on superconducting resonator technology, microwave coplanar waveguides provide a well suited interconnection for photons and solid-state quantum bits (qubits), extensively investigated in recent years. Since a quantum memory is presently missing in those electrical accessible circuit cavity quantum devices, connecting the fast processing in a solid sate device to the exceptional long coherence times in atomic ensembles, the presented work is focused to establish the technological foundations for the hybridization of such quantum systems. The microwave photons stored in a superconducting high finesse microwave resonator are therefore an ideal connection between the atom and the solid state quantum world. In the last decade, the miniaturization and integration of quantum optics and atomic physics manipulation techniques on to a single chip was successfully established. Such atom chips are capable of detailed quantum manipulation of ultra-cold atoms and provide a versatile platform to combine the manipulation techniques from atomic physics with the capability of nano-fabrication. In recent years several experiments succeeded in realization of superconducting atom chips in cryogenic environments which opens the road for integrating super-conductive microwave resonators to magnetically couple an atomic ensemble to photons stored in the coplanar high finesse cavity. This thesis presents the concept, design and experimental setup of two approaches to establish an atomic ensemble of rubidium atoms inside a cryogenic environment, based on an Electron beam driven alkali metal atom source for loading a magneto optical trap in a

  17. Determination of copper and mercury in phosphate fertilizers employing direct solid sampling analysis and high resolution continuum source graphite furnace atomic absorption spectrometry

    Science.gov (United States)

    de Oliveira Souza, Sidnei; François, Luciane Luiza; Borges, Aline Rocha; Vale, Maria Goreti Rodrigues; Araujo, Rennan Geovanny Oliveira

    2015-12-01

    The present study proposes the determination of copper and mercury in phosphate fertilizers by direct solid sampling analysis (SS) employing high resolution continuum source graphite furnace atomic absorption spectrometry (HR-CS GF AAS). For Cu determination, two analytical lines were used: 327.3960 nm and 249.2146 nm. Hg determination was carried out on the line 253.6521 nm and 100 μg KMnO4 was used as chemical modifier. The optimal pyrolysis temperature for Cu determination was 1300 °C. Atomization temperatures for Cu and Hg were 2400 and 1100 °C, respectively. External calibration with aqueous standard solutions was adopted for both elements. The limits of quantification (LoQs) and characteristic mass (m0) obtained for Cu determination were 0.4 μg g- 1 and 1.12 ng, respectively, on line 249.2146 nm, and 64 μg g- 1 and 25 pg on 327.3960 nm. For mercury, LoQ and m0 were 4.8 ng g- 1 and 39 pg, respectively. The accuracy of the proposed methods was confirmed by the analysis of standard reference material (SRM) of Trace Elements in Multi-Nutrient Fertilizer (SRM NIST 695). The precision expressed as relative standard deviation (RSD), was better than 8.2% for Hg and 7.7% for the Cu (n = 5), considered satisfactory for microanalysis in solid sample. Four fertilizer samples acquired in commercial establishments in the city of Salvador, Bahia, Brazil, were analyzed. The optimized analytical methods were simple, fast, accurate, precise and free of spectral interferences for the determination of Cu and Hg in phosphate fertilizer samples by SS-HR-CS GF AAS, avoiding the dissolution of the sample, the use of harmful reagents and the generation of residues.

  18. Preconcentration of trace amounts of lead in water samples with cetyltrimethylammonium bromide coated magnetite nanoparticles and its determination by flame atomic absorption spectrometry

    Directory of Open Access Journals (Sweden)

    Mohammad Faraji

    2016-11-01

    Full Text Available A sensitive and simple magnetic solid phase extraction procedure was presented for the preconcentration of lead ions in environmental water samples. In the present study, lead ions form complexes with 1-(2-pyridilazo-2-naphthol reagent (PAN in basic medium, and then are quantitatively extracted to the surface of cetyltrimethylammonium bromide (CTAB-coated magnetite nanoparticles (Fe3O4 NPs. After magnetic separation of adsorbent, the adsorbent was eluted with 0.5% (v/v HCl in methanol prior to its analysis by flame atomic absorption spectrometry (FAAS. The pH of sample, concentrations of PAN, amounts of CTAB and Fe3O4 NPs, sample volume and desorption conditions were optimized. Under optimum conditions, the calibration curve was linear in the range of 0.05–100 ng mL−1 with R2 = 0.9996. Detection and quantification limits of the proposed method were 0.005 and 0.05 ng mL−1, respectively. Enhancement factor of 1050 was achieved using this method to extract 1000 mL of different environmental water samples. Compared with conventional solid phase extraction methods, the advantages of this method still include easy preparation of sorbents, short times of sample pre-treatment, high extraction yield, and high breakthrough volume. It shows great analytical potential in preconcentration of lead from large volume water samples.

  19. Laser-Cooled Ions and Atoms in a Storage Ring

    Energy Technology Data Exchange (ETDEWEB)

    Kleinert, J.; Hannemann, S.; Eike, B.; Eisenbarth, U.; Grieser, M.; Grimm, R.; Gwinner, G.; Karpuk, S.; Saathoff, G.; Schramm, U.; Schwalm, D.; Weidemueller, M., E-mail: m.weidemueller@mpi-hd.mpg.de [Max-Planck-Insitut fuer Kernphysik (Germany)

    2003-03-15

    We review recent experiments at the Heidelberg Test Storage Ring which apply advanced laser cooling techniques to stored ion beams. Very high phase-space densities are achieved by three-dimensional laser cooling of a coasting {sup 9}Be{sup +} beam at 7.3 MeV. Laser-cooled, trapped Cs atoms are used as an ultracold precision target for the study of ion-atom interactions with a 74 MeV beam of {sup 12}C{sup 6+} ions.

  20. Matter-wave localization in disordered cold atom lattices.

    Science.gov (United States)

    Gavish, Uri; Castin, Yvan

    2005-07-08

    We propose to observe Anderson localization of ultracold atoms in the presence of a random potential made of atoms of another species or spin state and trapped at the nodes of an optical lattice, with a filling factor less than unity. Such systems enable a nearly perfect experimental control of the disorder, while the possibility of modeling the scattering potentials by a set of pointlike ones allows an exact theoretical analysis. This is illustrated by a detailed analysis of the one-dimensional case.