Calculation of the spatial resolution in two-photon absorption spectroscopy applied to plasma diagnosis

International Nuclear Information System (INIS)

Garcia-Lechuga, M.; Fuentes, L. M.; Grützmacher, K.; Pérez, C.; Rosa, M. I. de la

2014-01-01

We report a detailed characterization of the spatial resolution provided by two-photon absorption spectroscopy suited for plasma diagnosis via the 1S-2S transition of atomic hydrogen for optogalvanic detection and laser induced fluorescence (LIF). A precise knowledge of the spatial resolution is crucial for a correct interpretation of measurements, if the plasma parameters to be analysed undergo strong spatial variations. The present study is based on a novel approach which provides a reliable and realistic determination of the spatial resolution. Measured irradiance distribution of laser beam waists in the overlap volume, provided by a high resolution UV camera, are employed to resolve coupled rate equations accounting for two-photon excitation, fluorescence decay and ionization. The resulting three-dimensional yield distributions reveal in detail the spatial resolution for optogalvanic and LIF detection and related saturation due to depletion. Two-photon absorption profiles broader than the Fourier transform-limited laser bandwidth are also incorporated in the calculations. The approach allows an accurate analysis of the spatial resolution present in recent and future measurements.

Two-Photon-Absorption Scheme for Optical Beam Tracking

Science.gov (United States)

Ortiz, Gerardo G.; Farr, William H.

2011-01-01

A new optical beam tracking approach for free-space optical communication links using two-photon absorption (TPA) in a high-bandgap detector material was demonstrated. This tracking scheme is part of the canonical architecture described in the preceding article. TPA is used to track a long-wavelength transmit laser while direct absorption on the same sensor simultaneously tracks a shorter-wavelength beacon. The TPA responsivity was measured for silicon using a PIN photodiode at a laser beacon wavelength of 1,550 nm. As expected, the responsivity shows a linear dependence with incident power level. The responsivity slope is 4.5 x 10(exp -7) A/W2. Also, optical beam spots from the 1,550-nm laser beacon were characterized on commercial charge coupled device (CCD) and complementary metal-oxide semiconductor (CMOS) imagers with as little as 13.7 microWatts of optical power (see figure). This new tracker technology offers an innovative solution to reduce system complexity, improve transmit/receive isolation, improve optical efficiency, improve signal-to-noise ratio (SNR), and reduce cost for free-space optical communications transceivers.

Inhibition of two-photon absorption in a three-level system with a pair of bichromatic fields

International Nuclear Information System (INIS)

Zou Jinhua; Hu Xiangming; Cheng Guangling; Li Xing; Du Dan

2005-01-01

We study two-photon absorption in a three-level ladder atomic system driven by a pair of bichromatic fields of equal frequency differences. The high-frequency component of one bichromatic field and the low-frequency component of the other are on two-photon resonance. The transition probability is calculated by employing the method of harmonic expansion and matrix inversion. Unexpectedly, when the sums of the phases of the different pairs of field components on the two-photon resonance are equal to each other, two-photon absorption is dramatically suppressed and the atomic system becomes transparent against two-photon absorption. Physically, due to dynamical Stark splitting, the two-photon transitions induced by the different pairs of field components experience different dressed states with phase difference of π. As a result, destructive interference occurs between the two pathways and leads to the inhibition of two-photon absorption

Inhibition of two-photon absorption due to dipole-dipole interaction in nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Singh, Mahi R. [Department of Physics and Astronomy, University of Western Ontario, London, N6A 3K7 (Canada)], E-mail: msingh@uwo.ca

2008-07-21

We have investigated the inhibition of two-photon absorption in photonic crystals doped with an ensemble of four-level nanoparticles. The particles are interacting with one another by the dipole-dipole interaction. Dipoles in nanoparticles are induced by a selected transition. Numerical simulations have been performed for an isotropic photonic crystal. Interesting phenomena have been predicted such as the inhibition of the two-photon absorption due to the dipole-dipole interaction. It has also been found that the inhibition effect can be switched on and off by tuning a decay resonance energy within the energy band of the crystal. A theory of dressed states has been used to explain the results.

Optical Kerr effect and two-photon absorption in monolayer black phosphorus

Science.gov (United States)

Margulis, Vl A.; Muryumin, E. E.; Gaiduk, E. A.

2018-05-01

A theoretical treatment of nonlinear refraction and two-photon absorption is presented for a novel two-dimensional material, monolayer black phosphorus (or phosphorene), irradiated by a normally incident and linearly polarized coherent laser beam of frequency ω. It is found that both the nonlinear refractive index n 2(ω) and the two-photon absorption coefficient α 2(ω) of phosphorene depend upon the polarization of the radiation field relative to phosphorene’s crystallographic axes. For the two principal polarization directions considered—viz, the armchair ({ \\mathcal A }{ \\mathcal C }) and zigzag ({ \\mathcal Z }{ \\mathcal Z }), the calculated values of n 2 and α 2 are distinguished by the order of their magnitude, with the n 2 and α 2 values being greater for the { \\mathcal A }{ \\mathcal C } direction. Furthermore, for almost all the incident photon energies below the fundamental absorption edge, except its neighborhood, the signs of n 2 as well as α 2 for the { \\mathcal A }{ \\mathcal C } and { \\mathcal Z }{ \\mathcal Z } polarization directions are opposed to each other. Also, for both the directions, the change of sign of n 2 is predicted to occur in the way between the two-photon absorption edge and the fundamental absorption edge, as well as in the near vicinity of the latter, where the Kerr nonlinearity has a pronounced resonant character and the magnitude of n 2 for the { \\mathcal A }{ \\mathcal C } and { \\mathcal Z }{ \\mathcal Z } polarization directions reaches its largest positive values of the order of 10‑9 and 10‑10 cm2 W‑1, respectively. The implications of the findings for practical all-optical switching applications are discussed.

Highly sensitive measurement in two-photon absorption cross section and investigation of the mechanism of two-photon-induced polymerization

Energy Technology Data Exchange (ETDEWEB)

Lu Youmei E-mail: luym19@cc.tuat.ac.jp; Hasegawa, Fuyuki; Goto, Takamichi; Ohkuma, Satoshi; Fukuhara, Setsuko; Kawazu, Yukie; Totani, Kenro; Yamashita, Takashi; Watanabe, Toshiyuki E-mail: toshi@cc.tuat.ac.jp

2004-10-01

A novel two-photon initiator, 4,4'-bis[4-(di-n-butylamino)styryl]-benzene with the side-group methyl (Me) (abbreviated as Chromophore 1), was synthesized in comparison with the chromophore with the side group methoxy (MeO) (abbreviated as Chromophore 2). Femtosecond laser-induced fluorescence intensity was used to evaluate two-photon absorption (TPA) cross section, {delta}, by means of a charge-coupled device, USB-2000 (abbreviated as CCD). Results showed that changing the side group from Me to MeO led to a significant red-shift of the two-photon absorption ({sup 2}{lambda}{sub max}). However, the microstructures obtained by two-photon-induced polymerization (TPIP) demonstrated that the sensitivities of Chromophore 1 increased despite a two-fold decrease in the two-photon cross section {delta}{sub max,} relative to Chromophore 2. Correlated with the appearance that the long-lived charge transfer emission of the chromophore in the monomer bulk, we suggest that the intramolecular charge transfer (intra-CT) takes place within the excited dye. Then intermolecular charge transfer was successive as a result of the formation of an exciplex between the dye and the monomer. The Me group was favorable for the intra-CT, relative to MeO, which contributed to the enhancement of the sensitivity of TPIP.

Pressure broadening of atomic oxygen two-photon absorption laser induced fluorescence

NARCIS (Netherlands)

Marinov, D.; Drag, C.; Blondel, C.; Guaitella, O.; Golda, J.; Klarenaar, B.L.M.; Engeln, R.A.H.; Schulz-von der Gathen, V.; Booth, J.-P.

2016-01-01

Atomic oxygen, considered to be a determining reactant in plasma applications at ambient pressure, is routinely detected by two-photon absorption laser induced fluorescence (TALIF). Here, pressure broadening of the (2p 4 3 P 2  →  3p 3 P J=0,1,2) two-photon transition in oxygen atoms was

Characterization of Photon-Counting Detector Responsivity for Non-Linear Two-Photon Absorption Process

Science.gov (United States)

Sburlan, S. E.; Farr, W. H.

2011-01-01

Sub-band absorption at 1550 nm has been demonstrated and characterized on silicon Geiger mode detectors which normally would be expected to have no response at this wavelength. We compare responsivity measurements to singlephoton absorption for wavelengths slightly above the bandgap wavelength of silicon (approx. 1100 microns). One application for this low efficiency sub-band absorption is in deep space optical communication systems where it is desirable to track a 1030 nm uplink beacon on the same flight terminal detector array that monitors a 1550 nm downlink signal for pointingcontrol. The currently observed absorption at 1550 nm provides 60-70 dB of isolation compared to the response at 1064 nm, which is desirable to avoid saturation of the detector by scattered light from the downlink laser.

Two-photon absorption and two-photon circular dichroism of hexahelicene derivatives: a study of the effect of the nature of intramolecular charge transfer

Czech Academy of Sciences Publication Activity Database

Díaz, C.; Vesga, Y.; Echevarria, L.; Stará, Irena G.; Starý, Ivo; Anger, E.; Shen, C.; Moussa, M. E. S.; Vanthuyne, N.; Crassous, J.; Rizzo, A.; Hernández, F. E.

2015-01-01

Roč. 5, č. 23 (2015), s. 17429-17437 ISSN 2046-2069 Institutional support: RVO:61388963 Keywords : [6]helicene * two photon absorption * two photon CD Subject RIV: CC - Organic Chemistry Impact factor: 3.289, year: 2015

A series of fluorene-based two-photon absorbing molecules: synthesis, linear and nonlinear characterization, and bioimaging

Science.gov (United States)

Andrade, Carolina D.; Yanez, Ciceron O.; Rodriguez, Luis; Belfield, Kevin D.

2010-01-01

The synthesis, structural, and photophysical characterization of a series of new fluorescent donor–acceptor and acceptor-acceptor molecules, based on the fluorenyl ring system, with two-photon absorbing properties is described. These new compounds exhibited large Stokes shifts, high fluorescent quantum yields, and, significantly, high two-photon absorption cross sections, making them well suited for two-photon fluorescence microscopy (2PFM) imaging. Confocal and two-photon fluorescence microscopy imaging of COS-7 and HCT 116 cells incubated with probe I showed endosomal selectivity, demonstrating the potential of this class of fluorescent probes in multiphoton fluorescence microscopy. PMID:20481596

Study the multi-photon absorption process in two types of molecules

International Nuclear Information System (INIS)

Al-azawi, H.R.

1986-01-01

The aim of the present work was to study the multi-photon absorption process in two types of molecules; spherical top such as SF 6 molecules and assymetric top such as CHOOH and C 2 H 4 molecules. This work also aimed to study the effect of buffer gas pressure (Ar), which is transparent to the infrared (IR) laser on the multiphoton absorption of both types of molecules. A pulsed (TEA) CO 2 laser was used as a source which generates multi-lines in the IR-region of the spectrum and an optoacoustic detector was used to detect the energy absorbed by the molecules. In this study, the relaxation process was found to be faster in the heavy molecules than that in the light ones. A limit in the Ar pressure was observed. Below this limit, the gas acted as an active buffer gas and above it, the multi-photon absorption process was quenched. This work also aimed to study the multi-photon absorption spectrum for the CHOOH molecules in the range (1067-1090 cm -1 ). This spectrum was found to be consistent with the linear absorption spectrum obtained for the same range. The density of the vibrational states as a function of the vibrational energy was studied for the molecules SF 6 , CHOOH and C 2 H 4 . The results were used to interpret (i) the difference in the energy absorbed by difference molecules at the same energy density and (ii) the non-linearity in the multi-photon absorption for CHOOH molecules. 1 tab.; 40 figs.; 70 refs

Vibrational excitation of hydrogen molecules by two-photon absorption and third-harmonic generation

Science.gov (United States)

Miyamoto, Yuki; Hara, Hideaki; Hiraki, Takahiro; Masuda, Takahiko; Sasao, Noboru; Uetake, Satoshi; Yoshimi, Akihiro; Yoshimura, Koji; Yoshimura, Motohiko

2018-01-01

We report the coherent excitation of the vibrational state of hydrogen molecules by two-photon absorption and the resultant third-harmonic generation (THG). Parahydrogen molecules cooled by liquid nitrogen are irradiated by mid-infrared nanosecond pulses at 4.8 μm with a nearly Fourier-transform-limited linewidth. The first excited vibrational state of parahydrogen is populated by two-photon absorption of the mid-infrared photons. Because of the narrow linewidth of the mid-infrared pulses, coherence between the ground and excited states is sufficient to induce higher-order processes. Near-infrared photons from the THG are observed at 1.6 μm. The dependence of the intensity of the near-infrared radiation on mid-infrared pulse energy, target pressure, and cell length is determined. We used a simple formula for THG with consideration of realistic experimental conditions to explain the observed results.

Polarization control of intermediate state absorption in resonance-mediated multi-photon absorption process

International Nuclear Information System (INIS)

Xu, Shuwu; Yao, Yunhua; Jia, Tianqing; Ding, Jingxin; Zhang, Shian; Sun, Zhenrong; Huang, Yunxia

2015-01-01

We theoretically and experimentally demonstrate the control of the intermediate state absorption in an (n + m) resonance-mediated multi-photon absorption process by the polarization-modulated femtosecond laser pulse. An analytical solution of the intermediate state absorption in a resonance-mediated multi-photon absorption process is obtained based on the time-dependent perturbation theory. Our theoretical results show that the control efficiency of the intermediate state absorption by the polarization modulation is independent of the laser intensity when the transition from the intermediate state to the final state is coupled by the single-photon absorption, but will be affected by the laser intensity when this transition is coupled by the non-resonant multi-photon absorption. These theoretical results are experimentally confirmed via a two-photon fluorescence control in (2 + 1) resonance-mediated three-photon absorption of Coumarin 480 dye and a single-photon fluorescence control in (1 + 2) resonance-mediated three-photon absorption of IR 125 dye. (paper)

Influence of two-photon absorption on soliton self-frequency shift

DEFF Research Database (Denmark)

Steffensen, Henrik; Agger, Christian; Bang, Ole

2012-01-01

In this paper we develop an analytical model for the soliton self-frequency shift, which includes second- and thirdorder dispersion, self-steepening, the full Raman term, and, for the first time to our best knowledge, the effect of two-photon absorption (TPA). We show that TPA can have a signific...

Broadband two-photon absorption cross sections of benzothiazole derivatives and benzobisthiazolium salts

Science.gov (United States)

Noskovičova, Eva; Lorenc, Dušan; Magdolen, Peter; Sigmundová, Ivica; Zahradník, Pavol; Velič, Dušan

2018-05-01

Two-photon absorption (TPA) cross sections of conjugated donor-π-acceptor dipolar structures containing benzothiazole or benzobisthiazolium moieties are determined in a broad spectral range from 700 nm to 1000 nm using two-photon induced fluorescence technique. The TPA cross section values range from 150 GM to 4600 GM. The largest values are observed in near-infrared region. The dipolar derivative of benzothiazole has the largest TPA cross section of 4600 GM at wavelength of 890 nm. A combination of the large TPA in the near-infrared region and the high emission quantum yield makes these compounds excellent candidates for two-photon fluorescence microscopy.

Temperature dependence of the two photon absorption in indium arsenide

International Nuclear Information System (INIS)

Berryman, K.W.; Rella, C.W.

1995-01-01

Nonlinear optical processes in semiconductors have long been a source of interesting physics. Two photon absorption (TPA) is one such process, in which two photons provide the energy for the creation of an electron-hole pair. Researchers at other FEL centers have studied room temperature TPA in InSb, InAs, and HgCdTe. Working at the Stanford Picosecond FEL Center, we have extended and refined this work by measuring the temperature dependence of the TPA coefficient in InAs over the range from 80 to 350 K at four wavelengths: 4.5, 5.06, 6.01, and 6.3 microns. The measurements validate the functional dependence of recent band structure calculations with enough precision to discriminate parabolic from non-parabolic models, and to begin to observe smaller effects, such as contributions due to the split-off band. These experiments therefore serve as a strong independent test of the Kane band theory, as well as providing a starting point for detailed observations of other nonlinear absorption mechanisms

Exciton absorption of entangled photons in semiconductor quantum wells

Science.gov (United States)

Rodriguez, Ferney; Guzman, David; Salazar, Luis; Quiroga, Luis; Condensed Matter Physics Group Team

2013-03-01

The dependence of the excitonic two-photon absorption on the quantum correlations (entanglement) of exciting biphotons by a semiconductor quantum well is studied. We show that entangled photon absorption can display very unusual features depending on space-time-polarization biphoton parameters and absorber density of states for both bound exciton states as well as for unbound electron-hole pairs. We report on the connection between biphoton entanglement, as quantified by the Schmidt number, and absorption by a semiconductor quantum well. Comparison between frequency-anti-correlated, unentangled and frequency-correlated biphoton absorption is addressed. We found that exciton oscillator strengths are highly increased when photons arrive almost simultaneously in an entangled state. Two-photon-absorption becomes a highly sensitive probe of photon quantum correlations when narrow semiconductor quantum wells are used as two-photon absorbers. Research funds from Facultad de Ciencias, Universidad de los Andes

On-demand single-photon state generation via nonlinear absorption

International Nuclear Information System (INIS)

Hong Tao; Jack, Michael W.; Yamashita, Makoto

2004-01-01

We propose a method for producing on-demand single-photon states based on collision-induced exchanges of photons and unbalanced linear absorption between two single-mode light fields. These two effects result in an effective nonlinear absorption of photons in one of the modes, which can lead to single-photon states. A quantum nonlinear attenuator based on such a mechanism can absorb photons in a normal input light pulse and terminate the absorption at a single-photon state. Because the output light pulses containing single photons preserve the properties of the input pulses, we expect this method to be a means for building a highly controllable single-photon source

Two and four photon absorption and nonlinear refraction in undoped, chromium doped and copper doped ZnS quantum dots

Science.gov (United States)

Sharma, Dimple; Malik, B. P.; Gaur, Arun

2015-12-01

The ZnS quantum dots (QDs) with Cr and Cu doping were synthesized by chemical co-precipitation method. The nanostructures of the prepared undoped and doped ZnS QDs were characterized by UV-vis spectroscopy, Transmission electron microscopy (TEM) and X-ray diffraction (XRD). The sizes of QDs were found to be within 3-5 nm range. The nonlinear parameters viz. Two photon absorption coefficient (β2), nonlinear refractive index (n2), third order nonlinear susceptibility (χ3) at wavelength 532 nm and Four photon absorption coefficient (β4) at wavelength 1064 nm have been calculated by Z-scan technique using nanosecond Nd:YAG laser in undoped, Cr doped and Cu doped ZnS QDs. Higher values of nonlinear parameters for doped ZnS infer that they are potential material for the development of photonics devices and sensor protection applications.

Multi-photon absorption limits to heralded single photon sources

Science.gov (United States)

Husko, Chad A.; Clark, Alex S.; Collins, Matthew J.; De Rossi, Alfredo; Combrié, Sylvain; Lehoucq, Gaëlle; Rey, Isabella H.; Krauss, Thomas F.; Xiong, Chunle; Eggleton, Benjamin J.

2013-01-01

Single photons are of paramount importance to future quantum technologies, including quantum communication and computation. Nonlinear photonic devices using parametric processes offer a straightforward route to generating photons, however additional nonlinear processes may come into play and interfere with these sources. Here we analyse spontaneous four-wave mixing (SFWM) sources in the presence of multi-photon processes. We conduct experiments in silicon and gallium indium phosphide photonic crystal waveguides which display inherently different nonlinear absorption processes, namely two-photon (TPA) and three-photon absorption (ThPA), respectively. We develop a novel model capturing these diverse effects which is in excellent quantitative agreement with measurements of brightness, coincidence-to-accidental ratio (CAR) and second-order correlation function g(2)(0), showing that TPA imposes an intrinsic limit on heralded single photon sources. We build on these observations to devise a new metric, the quantum utility (QMU), enabling further optimisation of single photon sources. PMID:24186400

Total photon absorption

International Nuclear Information System (INIS)

Carlos, P.

1985-06-01

The present discussion is limited to a presentation of the most recent total photonuclear absorption experiments performed with real photons at intermediate energy, and more precisely in the region of nucleon resonances. The main sources of real photons are briefly reviewed and the experimental procedures used for total photonuclear absorption cross section measurements. The main results obtained below 140 MeV photon energy as well as above 2 GeV are recalled. The experimental study of total photonuclear absorption in the nuclear resonance region (140 MeV< E<2 GeV) is still at its beginning and some results are presented

Polarization control of multi-photon absorption under intermediate femtosecond laser field

International Nuclear Information System (INIS)

Cheng Wenjing; Liang Guo; Wu Ping; Liu Pei; Jia Tianqing; Sun Zhenrong; Zhang Shian

2017-01-01

It has been shown that the femtosecond laser polarization modulation is a very simple and well-established method to control the multi-photon absorption process by the light–matter interaction. Previous studies mainly focused on the multi-photon absorption control in the weak field. In this paper, we further explore the polarization control behavior of multi-photon absorption process in the intermediate femtosecond laser field. In the weak femtosecond laser field, the second-order perturbation theory can well describe the non-resonant two-photon absorption process. However, the higher order nonlinear effect (e.g., four-photon absorption) can occur in the intermediate femtosecond laser field, and thus it is necessary to establish new theoretical model to describe the multi-photon absorption process, which includes the two-photon and four-photon transitions. Here, we construct a fourth-order perturbation theory to study the polarization control behavior of this multi-photon absorption under the intermediate femtosecond laser field excitation, and our theoretical results show that the two-photon and four-photon excitation pathways can induce a coherent interference, while the coherent interference is constructive or destructive that depends on the femtosecond laser center frequency. Moreover, the two-photon and four-photon transitions have the different polarization control efficiency, and the four-photon absorption can obtain the higher polarization control efficiency. Thus, the polarization control efficiency of the whole excitation process can be increased or decreased by properly designing the femtosecond laser field intensity and laser center frequency. These studies can provide a clear physical picture for understanding and controlling the multi-photon absorption process in the intermediate femtosecond laser field, and also can provide a theoretical guidance for the future experimental realization. (paper)

N-Annulated perylene-substituted and fused porphyrin dimers with intense near-infrared one-photon and two-photon absorption

KAUST Repository

Luo, Jie; Lee, Sangsu; Son, Minjung; Zheng, Bin; Huang, Kuo-Wei; Qi, Qingbiao; Zeng, Wangdong; Li, Gongqiang; Kim, Dongho; Wu, Jishan

2015-01-01

. These new chromophores also exhibited good nonlinear optical susceptibility with large two-photon absorption cross-sections in the NIR region due to extended π-conjugation. Time-dependent density functional theory calculations have been performed to aid our

Control of one- and two-photon absorption in a four-level atomic system by changing the amplitude and phase of a driving microwave field

International Nuclear Information System (INIS)

Hou, B P; Wang, S J; Yu, W L; Sun, W L

2005-01-01

We consider the one- and two-photon absorption spectra of a four-level Y-type atom with the two highest lying levels driven by a microwave field. We found that in the one-photon absorption case, the microwave field can lead to the probe gain, and the absorption and gain spectral structures depend strongly on the microwave field amplitude. For the two-photon absorption case, the strong microwave field can enhance the absorption. When the microwave field amplitude is reduced to a certain value, the single absorption peak in the two-photon spectrum changes into a structure of two-peak structure with different magnitudes. Moreover, the one- and two-photon absorption spectra can be modulated by the phase of the microwave field which produces a closed-loop configuration. Finally, we use the analytic solutions in terms of dressed-state basis to explain the results from our numerical calculation

Low temperature characterization of the photocurrent produced by two-photon transitions in a quantum dot intermediate band solar cell

International Nuclear Information System (INIS)

Antolin, E.; Marti, A.; Stanley, C.R.; Farmer, C.D.; Canovas, E.; Lopez, N.; Linares, P.G.; Luque, A.

2008-01-01

Conceived to exceed the conversion efficiency of conventional photovoltaic devices, the intermediate band solar cell bases its operation on exploiting, besides the usual band-to-band optical transitions, the absorption of two sub-bandgap photons. For the present, the only technology used to implement an intermediate band in real devices has been the growth of an InAs/GaAs quantum dot superlattice. In practice, the obtained material shows two limitations: the narrow energy gap between conduction and intermediate band and the appearance of growth defects due to the lattice stress. The consequences are the presence of non-radiative recombination mechanisms and the thermal escape of electrons from the intermediate to the conduction band, hindering the splitting of the quasi-Fermi levels associated with the intermediate and conduction bands and the observation of photocurrent associated with the two-photon absorption. By reducing the temperature at which the devices are characterised we have suppressed the parasitic thermal mechanisms and have succeeded in measuring the photocurrent caused by the absorption of two below bandgap photons. In this work, the characterization of this photocurrent at low temperature is presented and discussed

Enantiopure distorted ribbon-shaped nanographene combining two-photon absorption-based upconversion and circularly polarized luminescence.

Science.gov (United States)

Cruz, Carlos M; Márquez, Irene R; Mariz, Inês F A; Blanco, Victor; Sánchez-Sánchez, Carlos; Sobrado, Jesús M; Martín-Gago, José A; Cuerva, Juan M; Maçôas, Ermelinda; Campaña, Araceli G

2018-04-28

Herein we describe a distorted ribbon-shaped nanographene exhibiting unprecedented combination of optical properties in graphene-related materials, namely upconversion based on two-photon absorption (TPA-UC) together with circularly polarized luminescence (CPL). The compound is a graphene molecule of ca. 2 nm length and 1 nm width with edge defects that promote the distortion of the otherwise planar lattice. The edge defects are an aromatic saddle-shaped ketone unit and a [5]carbohelicene moiety. This system is shown to combine two-photon absorption and circularly polarized luminescence and a remarkably long emission lifetime of 21.5 ns. The [5]helicene is responsible for the chiroptical activity while the push-pull geometry and the extended network of sp 2 carbons are factors favoring the nonlinear absorption. Electronic structure theoretical calculations support the interpretation of the results.

Size- and Wavelength-Dependent Two-Photon Absorption Cross-Section of CsPbBr3 Perovskite Quantum Dots

NARCIS (Netherlands)

Chen, Junsheng; Zidek, Karel; Chabera, Pavel; Liu, Dongzhou; Cheng, Pengfei; Nuuttila, Lauri; Al-Marri, Mohammed J.; Lehtivuori, Heli; Messing, Maria E.; Han, Keli; Zheng, Kaibo; Pullerits, Tonu

2017-01-01

All-inorganic colloidal perovskite quantum dots (QDs) based on cesium, lead, and halide have recently emerged as promising light emitting materials. CsPbBr3 QDs have also been demonstrated as stable two-photon-pumped lasing medium. However, the reported two photon absorption (TPA) cross sections for

Transient absorption study of two-photon excitation mechanism in the LH2 complex from purple bacterium Rhodobacter sphaeroides.

Science.gov (United States)

Stepanenko, Ilya; Kompanetz, Viktor; Makhneva, Zoya; Chekalin, Sergey; Moskalenko, Andrei; Razjivin, Andrei

2012-03-08

The mechanism of two-photon excitation of a peripheral light-harvesting complex LH2 (B800-850) from purple bacterium Rhodobacter sphaeroides was explained on the basis of femtosecond transient absorption data. Fast bleaching of the B850 absorption band was measured under two-photon excitation by 1350 nm femtosecond pulses, showing fast subpicosecond arrival of excitation energy to B850 circular aggregates. Any spectral changes connected with the B800 absorption band of B800-BChl molecules were absent. A similar picture was observed under one-photon excitation of the LH2 complex by 675 nm femtosecond pulses. We believe these effects may be attributed to direct excitation of high-energy excitonic states of a B850 circular aggregate or its vibrational manifold in accordance with the model of Abe [Chem. Phys. 2001, 264, 355-363].

Synthesis, singlet-oxygen photogeneration, two-photon absorption, photo-induced DNA cleavage and cytotoxic properties of an amphiphilic β-Schiff-base linked Ru(II) polypyridyl–porphyrin conjugate

International Nuclear Information System (INIS)

Ke, Hanzhong; Ma, Wanpeng; Wang, Hongda; Cheng, Guoe; Yuan, Han; Wong, Wai-Kwok; Kwong, Daniel W.J.; Tam, Hoi-Lam; Cheah, Kok-Wai; Chan, Chi-Fai; Wong, Ka-Leung

2014-01-01

A novel porphyrin–polypyridyl ruthenium(II) conjugate (TPP–Ru), in which the ruthenium(II) polypyridyl moiety is linked to the β-position of the tetraphenylporphyrin via a Schiff base linkage, has been synthesized and characterized by 1 H NMR, HRMS and UV–visible spectroscopy. The relative singlet oxygen quantum yield and two-photon absorption cross-section of this conjugate, together with its photo-induced DNA cleavage and cytotoxic activities were measured. The results show that the amphiphilic ruthenium(II) polypyridyl–porphyrin conjugate is an effective DNA photocleavage agent, with potential application in one- and two-photon absorption anti-cancer photodynamic therapy. - Highlights: • New porphyrin–ruthenium(II) polypyridyl complexes (TTP–Ru) have been synthesized. • The TTP–Ru shows substantial two-photon absorption cross-section (σ 2 =391 GM). • The TTP–Ru exhibits a substantial 1 O 2 quantum yield (0.64±0.13). • The TTP–Ru exhibits a strong DNA cleavage activity upon photo-excitation. • The TTP–Ru is available for in vitro imaging and as a photodynamic therapy agent

Synthesis, singlet-oxygen photogeneration, two-photon absorption, photo-induced DNA cleavage and cytotoxic properties of an amphiphilic β-Schiff-base linked Ru(II) polypyridyl–porphyrin conjugate

Energy Technology Data Exchange (ETDEWEB)

Ke, Hanzhong, E-mail: kehanz@163.com [Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan, Hubei 430074 (China); Ma, Wanpeng; Wang, Hongda; Cheng, Guoe [Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan, Hubei 430074 (China); Yuan, Han [Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR (China); Wong, Wai-Kwok, E-mail: wkwong@hkbu.edu.hk [Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR (China); Institute of Advanced Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR (China); Kwong, Daniel W.J. [Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR (China); Tam, Hoi-Lam; Cheah, Kok-Wai [Department of Physics, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR (China); Institute of Advanced Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR (China); Chan, Chi-Fai; Wong, Ka-Leung [Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR (China)

2014-10-15

A novel porphyrin–polypyridyl ruthenium(II) conjugate (TPP–Ru), in which the ruthenium(II) polypyridyl moiety is linked to the β-position of the tetraphenylporphyrin via a Schiff base linkage, has been synthesized and characterized by {sup 1}H NMR, HRMS and UV–visible spectroscopy. The relative singlet oxygen quantum yield and two-photon absorption cross-section of this conjugate, together with its photo-induced DNA cleavage and cytotoxic activities were measured. The results show that the amphiphilic ruthenium(II) polypyridyl–porphyrin conjugate is an effective DNA photocleavage agent, with potential application in one- and two-photon absorption anti-cancer photodynamic therapy. - Highlights: • New porphyrin–ruthenium(II) polypyridyl complexes (TTP–Ru) have been synthesized. • The TTP–Ru shows substantial two-photon absorption cross-section (σ{sub 2}=391 GM). • The TTP–Ru exhibits a substantial {sup 1}O{sub 2} quantum yield (0.64±0.13). • The TTP–Ru exhibits a strong DNA cleavage activity upon photo-excitation. • The TTP–Ru is available for in vitro imaging and as a photodynamic therapy agent.

The study of nonlinear two-photon phenomenon in photonic crystals doped with nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Singh, Mahi R [Department of Physics and Astronomy, University of Western Ontario, London, N6A 3K7 (Canada)

2007-02-28

A theory of the nonlinear two-photon absorption has been developed in a photonic crystal doped with an ensemble of four-level nanoparticles. We have considered that the nanoparticles are interacting with the photonic crystal. An expression of two-photon absorption has been obtained by using the density matrix method. The effect of the dipole-dipole interaction has also been included in the formulation. Interesting new phenomena have been predicted. For example, it is found that the inhibition of two-photon absorption can be turned on and off when the decay resonance energies of the four-level nanoparticles are moved within the energy band.

Bio-Inspired Photon Absorption and Energy Transfer for Next Generation Photovoltaic Devices

Science.gov (United States)

Magsi, Komal

Nature's solar energy harvesting system, photosynthesis, serves as a model for photon absorption, spectra broadening, and energy transfer. Photosynthesis harvests light far differently than photovoltaic cells. These differences offer both engineering opportunity and scientific challenges since not all of the natural photon absorption mechanisms have been understood. In return, solar cells can be a very sensitive probe for the absorption characteristics of molecules capable of transferring charge to a conductive interface. The objective of this scientific work is the advancement of next generation photovoltaics through the development and application of natural photo-energy transfer processes. Two scientific methods were used in the development and application of enhancing photon absorption and transfer. First, a detailed analysis of photovoltaic front surface fluorescent spectral modification and light scattering by hetero-structure was conducted. Phosphor based spectral down-conversion is a well-known laser technology. The theoretical calculations presented here indicate that parasitic losses and light scattering within the spectral range are large enough to offset any expected gains. The second approach for enhancing photon absorption is based on bio-inspired mechanisms. Key to the utilization of these natural processes is the development of a detailed scientific understanding and the application of these processes to cost effective systems and devices. In this work both aspects are investigated. Dye type solar cells were prepared and tested as a function of Chlorophyll (or Sodium-Copper Chlorophyllin) and accessory dyes. Forster has shown that the fluorescence ratio of Chlorophyll is modified and broadened by separate photon absorption (sensitized absorption) through interaction with nearby accessory pigments. This work used the dye type solar cell as a diagnostic tool by which to investigate photon absorption and photon energy transfer. These experiments shed

N-Annulated perylene-substituted and fused porphyrin dimers with intense near-infrared one-photon and two-photon absorption

KAUST Repository

Luo, Jie

2015-01-21

Fusion of two N-annulated perylene (NP) units with a fused porphyrin dimer along the S0-S1 electronic transition moment axis has resulted in new near-infrared (NIR) dyes 1a/1b with very intense absorption (ε>1.3×105M-1cm-1) beyond 1250nm. Both compounds displayed moderate NIR fluorescence with fluorescence quantum yields of 4.4×10-6 and 6.0×10-6 for 1a and 1b, respectively. The NP-substituted porphyrin dimers 2a/2b have also been obtained by controlled oxidative coupling and cyclodehydrogenation, and they showed superimposed absorptions of the fused porphyrin dimer and the NP chromophore. The excited-state dynamics of all of these compounds have been studied by femtosecond transient absorption measurements, which revealed porphyrin dimer-like behaviour. These new chromophores also exhibited good nonlinear optical susceptibility with large two-photon absorption cross-sections in the NIR region due to extended π-conjugation. Time-dependent density functional theory calculations have been performed to aid our understanding of their electronic structures and absorption spectra.

Size- and Wavelength-Dependent Two-Photon Absorption Cross-Section of CsPbBr3 Perovskite Quantum Dots.

Science.gov (United States)

Chen, Junsheng; Žídek, Karel; Chábera, Pavel; Liu, Dongzhou; Cheng, Pengfei; Nuuttila, Lauri; Al-Marri, Mohammed J; Lehtivuori, Heli; Messing, Maria E; Han, Keli; Zheng, Kaibo; Pullerits, Tõnu

2017-05-18

All-inorganic colloidal perovskite quantum dots (QDs) based on cesium, lead, and halide have recently emerged as promising light emitting materials. CsPbBr 3 QDs have also been demonstrated as stable two-photon-pumped lasing medium. However, the reported two photon absorption (TPA) cross sections for these QDs differ by an order of magnitude. Here we present an in-depth study of the TPA properties of CsPbBr 3 QDs with mean size ranging from 4.6 to 11.4 nm. By using femtosecond transient absorption (TA) spectroscopy we found that TPA cross section is proportional to the linear one photon absorption. The TPA cross section follows a power law dependence on QDs size with exponent 3.3 ± 0.2. The empirically obtained power-law dependence suggests that the TPA process through a virtual state populates exciton band states. The revealed power-law dependence and the understanding of TPA process are important for developing high performance nonlinear optical devices based on CsPbBr 3 nanocrystals.

Two-photon Absorption In Quantum Dots,quantum Dashes And Related Materials

Energy Technology Data Exchange (ETDEWEB)

Jain, Ravinder

2009-08-31

We have proposed the use of USQDs for various deep-tissue biological imaging applications, notably wavelength-multiplexed multicolor imaging and intra-nuclear studies such as those involving cell apoptosis, and have studied the issue of maximizing two-photon absorption-induced fluorescence (TPAF) signals from CdSe/ZnS USQDs to be used for this application. In particular, using 2 nm USQDs, we have shown that the TPAF signal at 780 nm is ~ 8 times that at 850 nm and 68 times that at 900 nm, two wavelengths that have been used in previous studies using CdSe/ZnS SQDs for deep-tissue imaging of biological studies via TPAF .

Ultrafast two-photon absorption optical thresholding of spectrally coded pulses

Science.gov (United States)

Zheng, Z.; Shen, S.; Sardesai, H.; Chang, C.-C.; Marsh, J. H.; Karkhanehchi, M. M.; Weiner, A. M.

1999-08-01

We report studies on two-photon absorption (TPA) GaAs p-i-n waveguide photodetectors as optical thresholders for proposed ultrashort pulse optical code-division multiple-access (CDMA) systems. For either chirped optical pulses or spectrally phase coded pseudonoise bursts, the TPA photocurrent response reveals a strong pulseshape dependence and shows good agreement with theoretical predictions and results from conventional SHG measurements. The performance limits of the TPA optical thresholders set by the encoded bandwidth in the spectral encoding-decoding process are also discussed based on numerical simulations. Our results show the feasibility of applying such devices as nonlinear intensity discriminators in ultrahigh-speed optical network applications.

pH-Induced Modulation of One- and Two-Photon Absorption Properties in a Naphthalene-Based Molecular Probe.

Science.gov (United States)

Murugan, N Arul; Kongsted, Jacob; Ågren, Hans

2013-08-13

Presently, there is a great demand for small probe molecules that can be used for two-photon excitation microscopy (TPM)-based monitoring of intracellular and intraorganelle activity and pH. The candidate molecules should ideally possess a large two-photon absorption cross section with optical properties sensitive to pH changes. In the present work, we investigate the potential of a methoxy napthalene (MONAP) derivative for its suitability to serve as a pH sensor using TPM. Using an integrated approach rooted in hybrid quantum mechanics/molecular mechanics, the structures, dynamics, and the one- and two-photon properties of the probe in dimethylformamide solvent are studied. It is found that the protonated form is responsible for the optical property of MONAP at moderately low pH, for which the calculated pH-induced red shift is in good agreement with experiments. A 2-fold increase in the two-photon absorption cross section in the IR region of the spectrum is predicted for the moderately low pH form of the probe, suggesting that this can be a potential probe for pH monitoring of living cells. We also propose some design principles aimed at obtaining control of the absorption spectral range of the probe by structural tuning. Our work indicates that the integrated approach employed is capable of capturing the pH-induced changes in structure and optical properties of organic molecular probes and that such in silico tools can be used to draw structure-property relationships to design novel molecular probes suitable for a specific application.

Broadband Two-Photon Absorption Characteristics of Highly Photostable Fluorenyl-Dicyanoethylenylated [60]Fullerene Dyads

Directory of Open Access Journals (Sweden)

Seaho Jeon

2016-05-01

Full Text Available We synthesized four C60-(light-harvesting antenna dyads C60 (>CPAF-Cn (n = 4, 9, 12, or 18 1-Cn for the investigation of their broadband nonlinear absorption effect. Since we have previously demonstrated their high function as two-photon absorption (2PA materials at 1000 nm, a different 2PA wavelength of 780 nm was applied in the study. The combined data taken at two different wavelength ranges substantiated the broadband characteristics of 1-Cn. We proposed that the observed broadband absorptions may be attributed by a partial π-conjugation between the C60 > cage and CPAF-Cn moieties, via endinitrile tautomeric resonance, giving a resonance state with enhanced molecular conjugation. This transient state could increase its 2PA and excited-state absorption at 800 nm. In addition, a trend of concentration-dependent 2PA cross-section (σ2 and excited-state absorption magnitude was detected showing a higher σ value at a lower concentration that was correlated to increasing molecular separation with less aggregation for dyads C60(>CPAF-C18 and C60(>CPAF-C9, as better 2PA and excited-state absorbers.

Novel xenon calibration scheme for two-photon absorption laser induced fluorescence of hydrogen

Energy Technology Data Exchange (ETDEWEB)

Elliott, Drew; Scime, Earl; Short, Zachary, E-mail: zdshort@mix.wvu.edu [Department of Physics and Astronomy, West Virginia University, Morgantown, West Virginia 26056 (United States)

2016-11-15

Two photon absorption laser induced fluorescence (TALIF) measurements of neutral hydrogen and its isotopes are typically calibrated by performing TALIF measurements on krypton with the same diagnostic system and using the known ratio of the absorption cross sections [K. Niemi et al., J. Phys. D 34, 2330 (2001)]. Here we present the measurements of a new calibration method based on a ground state xenon scheme for which the fluorescent emission wavelength is nearly identical to that of hydrogen, thereby eliminating chromatic effects in the collection optics and simplifying detector calibration. We determine that the ratio of the TALIF cross sections of xenon and hydrogen is 0.024 ± 0.001.

Optical beam induced current measurements based on two-photon absorption process in 4H-SiC bipolar diodes

Energy Technology Data Exchange (ETDEWEB)

Hamad, H.; Raynaud, C.; Bevilacqua, P.; Tournier, D.; Planson, D. [Ampère Laboratory - UMR 5005, 21, Avenue Jean Capelle, 69621 Villeurbanne Cedex (France); Vergne, B. [Franco-Allemand Institute of Saint-Louis ISL, 5, Rue du Général Cassagnou, 68300 Saint-Louis (France)

2014-02-24

Using a pulsed green laser with a wavelength of 532 nm, a duration pulse of ∼1 ns, and a mean power varying between 1 and 100 mW, induced photocurrents have been measured in 4H-SiC bipolar diodes. Considering the photon energy (2.33 eV) and the bandgap of 4H-SiC (3.2 eV), the generation of electron-hole pair by the conventional single photon absorption process should be negligible. The intensity of the measured photocurrents depends quadratically on the power beam intensity. This clearly shows that they are generated using two-photon absorption process. As in conventional OBIC (Optical Beam Induced Current), the measurements give an image of the electric field distribution in the structure under test, and the minority carrier lifetime can be extracted from the decrease of the photocurrent at the edge of the structure. The extracted minority carrier lifetime of 210 ns is consistent with results obtained in case of single photon absorption.

Optical beam induced current measurements based on two-photon absorption process in 4H-SiC bipolar diodes

International Nuclear Information System (INIS)

Hamad, H.; Raynaud, C.; Bevilacqua, P.; Tournier, D.; Planson, D.; Vergne, B.

2014-01-01

Using a pulsed green laser with a wavelength of 532 nm, a duration pulse of ∼1 ns, and a mean power varying between 1 and 100 mW, induced photocurrents have been measured in 4H-SiC bipolar diodes. Considering the photon energy (2.33 eV) and the bandgap of 4H-SiC (3.2 eV), the generation of electron-hole pair by the conventional single photon absorption process should be negligible. The intensity of the measured photocurrents depends quadratically on the power beam intensity. This clearly shows that they are generated using two-photon absorption process. As in conventional OBIC (Optical Beam Induced Current), the measurements give an image of the electric field distribution in the structure under test, and the minority carrier lifetime can be extracted from the decrease of the photocurrent at the edge of the structure. The extracted minority carrier lifetime of 210 ns is consistent with results obtained in case of single photon absorption

Antimony orthophosphate glasses with large nonlinear refractive indices, low two-photon absorption coefficients, and ultrafast response

International Nuclear Information System (INIS)

Falcao-Filho, E.L.; Araujo, Cid B. de; Bosco, C.A.C.; Maciel, G.S.; Acioli, L.H.; Nalin, M.; Messaddeq, Y.

2005-01-01

Antimony glasses based on the composition Sb 2 O 3 -SbPO 4 were prepared and characterized. The samples present high refractive index, good transmission from 380 to 2000 nm, and high thermal stability. The nonlinear refractive index, n 2 , of the samples was studied using the optical Kerr shutter technique at 800 nm. The third-order correlation signals between pump and probe pulses indicate ultrafast response ( 2 was observed by adding lead oxide to the Sb 2 O 3 -SbPO 4 composition. Large values of n 2 ≅10 -14 cm 2 /W and negligible two-photon absorption coefficients (smaller than 0.01 cm/GW) were determined for all samples. The glass compositions studied present appropriate figure-of-merit for all-optical switching applications

Two-Photon Absorbing Molecules as Potential Materials for 3D Optical Memory

Directory of Open Access Journals (Sweden)

Kazuya Ogawa

2014-01-01

Full Text Available In this review, recent advances in two-photon absorbing photochromic molecules, as potential materials for 3D optical memory, are presented. The investigations introduced in this review indicate that 3D data storage processing at the molecular level is possible. As 3D memory using two-photon absorption allows advantages over existing systems, the use of two-photon absorbing photochromic molecules is preferable. Although there are some photochromic molecules with good properties for memory, in most cases, the two-photon absorption efficiency is not high. Photochromic molecules with high two-photon absorption efficiency are desired. Recently, molecules having much larger two-photon absorption cross sections over 10,000 GM (GM= 10−50 cm4 s molecule−1 photon−1 have been discovered and are expected to open the way to realize two-photon absorption 3D data storage.

Quantum-correlated two-photon transitions to excitons in semiconductor quantum wells.

Science.gov (United States)

Salazar, L J; Guzmán, D A; Rodríguez, F J; Quiroga, L

2012-02-13

The dependence of the excitonic two-photon absorption on the quantum correlations (entanglement) of exciting biphotons by a semiconductor quantum well is studied. We show that entangled photon absorption can display very unusual features depending on space-time-polarization biphoton parameters and absorber density of states for both bound exciton states as well as for unbound electron-hole pairs. We report on the connection between biphoton entanglement, as quantified by the Schmidt number, and absorption by a semiconductor quantum well. Comparison between frequency-anti-correlated, unentangled and frequency-correlated biphoton absorption is addressed. We found that exciton oscillator strengths are highly increased when photons arrive almost simultaneously in an entangled state. Two-photon-absorption becomes a highly sensitive probe of photon quantum correlations when narrow semiconductor quantum wells are used as two-photon absorbers.

Theory of two-photon absorption by exciton states in cubic semiconductors with degenerate valence bands

International Nuclear Information System (INIS)

Nguyen Ai Viet; Nguyen Toan Thang.

1987-06-01

The coefficient of the absorption of two polarized photons is calculated for direct band gap semiconductors with degenerate valence bands. Wannier-Mott exciton states are included in both the intermediate and final states. Numerical calculations are performed for ZnSe and are compared with Sondergeld's experimental and theoretical results. (author). 11 refs, 2 tabs

Total photon absorption

International Nuclear Information System (INIS)

Carlos, P.

1985-01-01

Experimental methods using real photon beams for measurements of total photonuclear absorption cross section σ(Tot : E/sub γ/) are recalled. Most recent σ(Tot : E/sub γ/)results for complex nuclei and in the nucleon resonance region are presented

Two-photon excitation of argon

International Nuclear Information System (INIS)

Pindzola, P.S.; Payne, M.C.

1982-01-01

The authors calculate two photon excitation parameters for various excited states of argon assuming the absorption of near resonance broad-bandwidth laser radiation. Results are given for the case of two photons absorbed for the same laser beam as well as the case of absorbing photons of different frequency from each of two laser beams. The authors use multiconfiguration Hartree-Fock wave functions to evaluate the second-order sums over matrix elements. Various experimental laser schemes are suggested for the efficient excitation and subsequent ionization of argon

Absorption in one-dimensional metallic-dielectric photonic crystals

International Nuclear Information System (INIS)

Yu Junfei; Shen Yifeng; Liu Xiaohan; Fu Rongtang; Zi Jian; Zhu Zhiqiang

2004-01-01

We show theoretically that the absorption of one-dimensional metallic-dielectric photonic crystals can be enhanced considerably over the corresponding constituent metal. By properly choosing the structural and material parameters, the absorption of one-dimensional metallic-dielectric photonic crystals can be enhanced by one order of magnitude in the visible and in the near infrared regions. It is found that the absorptance of such photonic crystals increases with increasing number of periods. Rules on how to obtain a absorption enhancement in a certain frequency range are discussed. (letter to the editor)

High-resolution three-dimensional imaging of a depleted CMOS sensor using an edge Transient Current Technique based on the Two Photon Absorption process (TPA-eTCT)

CERN Document Server

García, Marcos Fernández; Echeverría, Richard Jaramillo; Moll, Michael; Santos, Raúl Montero; Moya, David; Pinto, Rogelio Palomo; Vila, Iván

2016-01-01

For the first time, the deep n-well (DNW) depletion space of a High Voltage CMOS sensor has been characterized using a Transient Current Technique based on the simultaneous absorption of two photons. This novel approach has allowed to resolve the DNW implant boundaries and therefore to accurately determine the real depleted volume and the effective doping concentration of the substrate. The unprecedented spatial resolution of this new method comes from the fact that measurable free carrier generation in two photon mode only occurs in a micrometric scale voxel around the focus of the beam. Real three-dimensional spatial resolution is achieved by scanning the beam focus within the sample.

High-resolution three-dimensional imaging of a depleted CMOS sensor using an edge Transient Current Technique based on the Two Photon Absorption process (TPA-eTCT)

Energy Technology Data Exchange (ETDEWEB)

García, Marcos Fernández; Sánchez, Javier González; Echeverría, Richard Jaramillo [Instituto de Física de Cantabria (CSIC-UC), Avda. los Castros s/n, E-39005 Santander (Spain); Moll, Michael [CERN, Organisation europénne pour la recherche nucléaire, CH-1211 Genéve 23 (Switzerland); Santos, Raúl Montero [SGIker Laser Facility, UPV/EHU, Sarriena, s/n - 48940 Leioa-Bizkaia (Spain); Moya, David [Instituto de Física de Cantabria (CSIC-UC), Avda. los Castros s/n, E-39005 Santander (Spain); Pinto, Rogelio Palomo [Departamento de Ingeniería Electrónica, Escuela Superior de Ingenieros Universidad de Sevilla (Spain); Vila, Iván [Instituto de Física de Cantabria (CSIC-UC), Avda. los Castros s/n, E-39005 Santander (Spain)

2017-02-11

For the first time, the deep n-well (DNW) depletion space of a High Voltage CMOS sensor has been characterized using a Transient Current Technique based on the simultaneous absorption of two photons. This novel approach has allowed to resolve the DNW implant boundaries and therefore to accurately determine the real depleted volume and the effective doping concentration of the substrate. The unprecedented spatial resolution of this new method comes from the fact that measurable free carrier generation in two photon mode only occurs in a micrometric scale voxel around the focus of the beam. Real three-dimensional spatial resolution is achieved by scanning the beam focus within the sample.

Absorption and emission properties of photonic crystals and metamaterials

International Nuclear Information System (INIS)

Peng, Lili

2007-01-01

We study the emission and absorption properties of photonic crystals and metamaterials using Comsol Multiphysics and Ansoft HFSS as simulation tools. We calculate the emission properties of metallic designs using drude model and the results illustrate that an appropriate termination of the surface of the metallic structure can significantly increase the absorption and therefore the thermal emissivity. We investigate the spontaneous emission rate modifications that occur for emitters inside two-dimensional photonic crystals and find the isotropic and directional emissions with respect to different frequencies as we have expected.

Occurrence of two-photon absorption saturation in Ag nanocolloids, prepared by chemical reduction method

Energy Technology Data Exchange (ETDEWEB)

Rahulan, K. Mani, E-mail: krahul.au@gmail.com [Department of Physics, Anna University, Chennai (India); Ganesan, S. [Department of Physics, Anna University, Chennai (India); Aruna, P., E-mail: aruna@annauniv.edu [Department of Physics, Anna University, Chennai (India)

2012-09-01

Highlights: Black-Right-Pointing-Pointer Ag nanocolloids were synthesized via chemical reduction method. Black-Right-Pointing-Pointer The molecules of PVP play an important role in growth and agglomeration of silver nanocolloids. Black-Right-Pointing-Pointer Saturation behaviour followed by two photon absorption was responsible for good optical limiting characteristics in these nanocolloids. Black-Right-Pointing-Pointer The nonlinear optical parameters calculated from the data showed that these materials could be used as efficient optical limiters. - Abstract: Silver nanocolloids stabilized with polyvinyl pyrrolidone (PVP) have been prepared from (AgNO{sub 3}) by a chemical reduction method, involving the intermediate preparation of (Ag{sub 2}O) colloidal dispersions in the presence of sodium dodecycle sulfate as a surfactant and formaldehyde as reducing agent. The molecules of PVP play an important role in growth and agglomeration of silver nanocolloids. The formation of Ag nanocolloids was studied from the UV-vis absorption characteristics. An energy dispersive X-ray (EDX) spectrum and X-ray diffraction peak of the nanoparticles showed the highly crystalline nature of silver structure. The particle size was found to be 40 nm as analyzed from Field emission scanning electron microscopy (FESEM). The nonlinear optical and optical limiting properties of these nanoparticle dispersions were studied by using the Z-scan technique at 532 nm. Experimental results show that the Ag nanocolloids possess strong optical limiting effect, originated from absorption saturation followed by two-photon mechanism. The data show that Ag nanocolloids have great potential for nonlinear optical devices.

Novel triphenylamine-cored two-photon absorbing dyes for labeling of biomolecules

International Nuclear Information System (INIS)

Xiao Haibo; Mei Chong; Wang Yaochuan; Li, Hui; Qian Shixiong; Yin Hongyao; Xu Zhisong

2011-01-01

Highlights: → Two novel triphenylamine-cored chromophores were synthesized. → These two dyes have sizable two-photon absorption cross-section at 800 nm. → They possess reasonable water solubility and are suitable as labels in aqueous biological environments. → These dyes have strong chelating ability. → They display a large set of reactivity for coupling to biomolecules. - Abstract: Two novel, V-shaped and Y-shaped dipicolinate derivatives branched from triphenylamine, {4-[(E)-2-(2,6-dimethoxycarbonylpyridin-4-yl)vinyl]}-N-phenyl-N-{4- [(E)-2-(2,6-dimethoxycarbonylpyridin-4-yl)vinylphenyl]}aniline (1) and {4-[(E)-2-(2,6-dimethoxycarbonylpyridin-4-yl) vinyl]}-N,N-bis {4-[(E)-2-(2,6-dimethoxycarbonyl pyridin-4-yl)vinylphenyl]}aniline (2) were synthesized. These compounds were designed for large two-photon absorption and in particular for labeling of biomolecules. Their linear absorption, fluorescence properties and their two-photon absorption properties as well as two-photon fluorescence cell imaging were examined. When excited at 800 nm, the two-photon absorption cross-section values of chromophores 1 and 2 in THF were 208 GM, 376 GM, respectively. These two-photon absorbing dyes possess reasonable water solubility, strong chelating ability and display a large set of reactivity for coupling to biomolecules, which are apparently due to the two methoxycarbonyl groups in pyridine ring. This work suggests that chromophores 1 and 2 are promising labels potentially applicable for the tracking of biomolecules using two-photon scanning microscopy.

Two-photon patterning of a polymer containing Y-shaped azochromophores

International Nuclear Information System (INIS)

Ambrosio, A.; Orabona, E.; Maddalena, P.; Camposeo, A.; Polo, M.; Neves, A. A. R.; Pisignano, D.; Carella, A.; Borbone, F.; Roviello, A.

2009-01-01

We report on the patterning of the free surface of azo-based polymer films by means of mass migration driven by one- or two-photon absorption. A symmetric donor-acceptor-donor structured Y-shaped azochromophore is specifically synthesized to enhance two-photon absorption in the polymer. The exposure of the polymer film to a focused laser beam results in light-driven mass migration for both one- and two-photon absorptions. Features with subdiffraction resolution (250 nm) are realized and the patterning dynamics is investigated as a function of the light dose. Furthermore, functional photonic structures, such as diffraction gratings with periods ranging between 0.5 and 2.0 μm, have been realized

Two-photon emission and multiphoton absorption by atoms

International Nuclear Information System (INIS)

Mu, X.

1988-01-01

This thesis consists of investigations of two problems concerning photon-atom interactions. The first topic deals with two-photon transitions in atomic inner shells. An independent-particle model has been used to describe the two-photon transitions between different inner-shell electron states. The first relativistic self-consistent-field calculation of these transition rates in Ag, Mo, and Xe has been carried out. The theoretical results are compared with recent measurements. Good agreement with measured rates is found except in some cases where more reliable experiments still need to be done. The second topic is multiphoton multiionization of atoms. The maximum entropy principle has been employed in this theoretical investigation. A detailed statistical analysis of measured ionic charge distributions produced in strong laser pulses has been carried out. The results of this analysis indicates that the charge-state distribution is a Poissonian, rather than the binomial which prevails under infrared radiation, and hence that ionization occurs stepwise during the pulse. This result is shown to be consistent with experimental data

Resonant two-photon absorption and electromagnetically induced transparency in open ladder-type atomic system.

Science.gov (United States)

Moon, Han Seb; Noh, Heung-Ryoul

2013-03-25

We have experimentally and theoretically studied resonant two-photon absorption (TPA) and electromagnetically induced transparency (EIT) in the open ladder-type atomic system of the 5S(1/2) (F = 1)-5P(3/2) (F' = 0, 1, 2)-5D(5/2) (F″ = 1, 2, 3) transitions in (87)Rb atoms. As the coupling laser intensity was increased, the resonant TPA was transformed to EIT for the 5S(1/2) (F = 1)-5P(3/2) (F' = 2)-5D(5/2) (F″ = 3) transition. The transformation of resonant TPA into EIT was numerically calculated for various coupling laser intensities, considering all the degenerate magnetic sublevels of the 5S(1/2)-5P(3/2)-5D(5/2) transition. From the numerical results, the crossover from TPA to EIT could be understood by the decomposition of the spectrum into an EIT component owing to the pure two-photon coherence and a TPA component caused by the mixed term.

A two photon absorption laser induced fluorescence diagnostic for fusion plasmas

Energy Technology Data Exchange (ETDEWEB)

Magee, R. M.; Galante, M. E.; McCarren, D.; Scime, E. E. [Physics Department, West Virginia University, Morgantown, West Virginia 26506 (United States); Boivin, R. L.; Brooks, N. H.; Groebner, R. J.; Hill, D. N. [General Atomics, San Diego, California 92121 (United States); Porter, G. D. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

2012-10-15

The quality of plasma produced in a magnetic confinement fusion device is influenced to a large extent by the neutral gas surrounding the plasma. The plasma is fueled by the ionization of neutrals, and charge exchange interactions between edge neutrals and plasma ions are a sink of energy and momentum. Here we describe a diagnostic capable of measuring the spatial distribution of neutral gas in a magnetically confined fusion plasma. A high intensity (5 MW/cm{sup 2}), narrow bandwidth (0.1 cm{sup -1}) laser is injected into a hydrogen plasma to excite the Lyman {beta} transition via the simultaneous absorption of two 205 nm photons. The absorption rate, determined by measurement of subsequent Balmer {alpha} emission, is proportional to the number of particles with a given velocity. Calibration is performed in situ by filling the chamber to a known pressure of neutral krypton and exciting a transition close in wavelength to that used in hydrogen. We present details of the calibration procedure, including a technique for identifying saturation broadening, measurements of the neutral density profile in a hydrogen helicon plasma, and discuss the application of the diagnostic to plasmas in the DIII-D tokamak.

A two photon absorption laser induced fluorescence diagnostic for fusion plasmas.

Science.gov (United States)

Magee, R M; Galante, M E; McCarren, D; Scime, E E; Boivin, R L; Brooks, N H; Groebner, R J; Hill, D N; Porter, G D

2012-10-01

The quality of plasma produced in a magnetic confinement fusion device is influenced to a large extent by the neutral gas surrounding the plasma. The plasma is fueled by the ionization of neutrals, and charge exchange interactions between edge neutrals and plasma ions are a sink of energy and momentum. Here we describe a diagnostic capable of measuring the spatial distribution of neutral gas in a magnetically confined fusion plasma. A high intensity (5 MW/cm(2)), narrow bandwidth (0.1 cm(-1)) laser is injected into a hydrogen plasma to excite the Lyman β transition via the simultaneous absorption of two 205 nm photons. The absorption rate, determined by measurement of subsequent Balmer α emission, is proportional to the number of particles with a given velocity. Calibration is performed in situ by filling the chamber to a known pressure of neutral krypton and exciting a transition close in wavelength to that used in hydrogen. We present details of the calibration procedure, including a technique for identifying saturation broadening, measurements of the neutral density profile in a hydrogen helicon plasma, and discuss the application of the diagnostic to plasmas in the DIII-D tokamak.

Chemical control of channel interference in two-photon absorption processes.

Science.gov (United States)

Alam, Md Mehboob; Chattopadhyaya, Mausumi; Chakrabarti, Swapan; Ruud, Kenneth

2014-05-20

The two-photon absorption (TPA) process is the simplest and hence the most studied nonlinear optical phenomenon, and various aspects of this process have been explored in the past few decades, experimentally as well as theoretically. Previous investigations have shown that the two-photon (TP) activity of a molecular system can be tuned, and at present, performance-tailored TP active materials are easy to develop by monitoring factors such as length of conjugation, dimensionality of charge-transfer network, strength of donor-acceptor groups, polarity of solvents, self-aggregation, H-bonding, and micellar encapsulation to mention but a few. One of the most intriguing phenomena affecting the TP activity of a molecule is channel interference. The phrase "channel interference" implies that if the TP transition from one electronic state to another involves more than one optical pathway or channel, characterized by the corresponding transition dipole moment (TDM) vectors, the channels may interfere with each other depending upon the angles between the TDM vectors and hence can either increase (constructive interference) or decrease (destructive interference) the overall TP activity of a system to a significant extent. This phenomenon was first pointed out by Cronstrand, Luo, and Ågren [Chem. Phys. Lett. 2002, 352, 262-269] in two-dimensional systems (i.e., only involving two components of the transition moment vectors). For three-dimensional molecules, an extended version of this idea was required. In order to fill this gap, we developed a generalized model for describing and exploring channel interference, valid for systems of any dimensionality. We have in particular applied it to through-bond (TB) and through-space (TS) charge-transfer systems both in gas phase and in solvents with different polarities. In this Account, we will, in addition to briefly describing the concept of channel interference, discuss two key findings of our recent work: (1) how to control the

Polarized two-photon photoselection in EGFP: Theory and experiment.

Science.gov (United States)

Masters, T A; Marsh, R J; Blacker, T S; Armoogum, D A; Larijani, B; Bain, A J

2018-04-07

In this work, we present a complete theoretical description of the excited state order created by two-photon photoselection from an isotropic ground state; this encompasses both the conventionally measured quadrupolar (K = 2) and the "hidden" degree of hexadecapolar (K = 4) transition dipole alignment, their dependence on the two-photon transition tensor and emission transition dipole moment orientation. Linearly and circularly polarized two-photon absorption (TPA) and time-resolved single- and two-photon fluorescence anisotropy measurements are used to determine the structure of the transition tensor in the deprotonated form of enhanced green fluorescent protein. For excitation wavelengths between 800 nm and 900 nm, TPA is best described by a single element, almost completely diagonal, two-dimensional (planar) transition tensor whose principal axis is collinear to that of the single-photon S 0 → S 1 transition moment. These observations are in accordance with assignments of the near-infrared two-photon absorption band in fluorescent proteins to a vibronically enhanced S 0 → S 1 transition.

Polarized two-photon photoselection in EGFP: Theory and experiment

Science.gov (United States)

Masters, T. A.; Marsh, R. J.; Blacker, T. S.; Armoogum, D. A.; Larijani, B.; Bain, A. J.

2018-04-01

In this work, we present a complete theoretical description of the excited state order created by two-photon photoselection from an isotropic ground state; this encompasses both the conventionally measured quadrupolar (K = 2) and the "hidden" degree of hexadecapolar (K = 4) transition dipole alignment, their dependence on the two-photon transition tensor and emission transition dipole moment orientation. Linearly and circularly polarized two-photon absorption (TPA) and time-resolved single- and two-photon fluorescence anisotropy measurements are used to determine the structure of the transition tensor in the deprotonated form of enhanced green fluorescent protein. For excitation wavelengths between 800 nm and 900 nm, TPA is best described by a single element, almost completely diagonal, two-dimensional (planar) transition tensor whose principal axis is collinear to that of the single-photon S0 → S1 transition moment. These observations are in accordance with assignments of the near-infrared two-photon absorption band in fluorescent proteins to a vibronically enhanced S0 → S1 transition.

Optical components based on two-photon absorption process in functionalized polymers

International Nuclear Information System (INIS)

Klein, S.; Barsella, A.; Taupier, G.; Stortz, V.; Fort, A.; Dorkenoo, K.D.

2006-01-01

We report on the fabrication of basic elements needed in optical circuits in a photopolymerizable resin, using a two-photon absorption (TPA) process to perform a selective polymerization. By taking advantage of the high spatial selectivity of the TPA approach, we can control the value of the local index of refraction in the material and realize permanent optical pathways in the bulk of photopolymerizable matrices. The computer-controlled design of such pathways allows creating optical circuits. As an example of application, optical fibers separated by millimetric distances and placed in arbitrary positions have been connected with moderate losses. Moreover, active components, such as electro-optical Mach-Zehnder interferometers, can be fabricated using photopolymers functionalized with non-linear optical chromophores, in order to be integrated in micro-optical circuits

Synthesis, structure and two-photon absorption properties of a new multi-branched compound, 1,2,4,5-tetrakis(4-pyridylvinyl)benzene

International Nuclear Information System (INIS)

Wang Lei; Tao Xutang; Yang Jiaxiang; Yu Wentao; Ren Yan; Xin Qian; Liu Zhi; Jiang Minhua

2004-01-01

A conjugated and symmetric multi-branched compound, 1,2,4,5-tetrakis(4-pyridylvinyl)benzene (TKPVB), has been synthesized and the crystal structures of TKPVB and its intermediate, 1,2,4,5-tetrakis(dimethoxyphosphorylmethyl)benzene, were determined by diffraction method. TKPVB with four units of 4-vinylpyridine moieties attached to the central benzene core presents an A-π-A general framework, where A is a π-deficient pyridine ring. The single-photon and two-photon absorption and fluorescence properties in different solvents of varying polarity have been investigated. It is also found that the one- and two-photon-induced fluorescence spectra are quite similar, which indicate that the one- and two-photon allowed-excited states are the same

The development of efficient two-photon singlet oxygen sensitizers

DEFF Research Database (Denmark)

Nielsen, Christian Benedikt

The development of efficient two-photon singlet oxygen sensitizers is addressed focusing on organic synthesis. Photophysical measurements were carried out on new lipophilic molecules, where two-photon absorption cross sections and singlet oxygen quantumyields were measured. Design principles...... for making efficient two-photon singlet oxygen sensitizers were then constructed from these results. Charge-transfer in the excited state of the prepared molecules was shown to play a pivotal role in the generationof singlet oxygen. This was established through studies of substituent effects on both...... the singlet oxygen yield and the two-photon absorption cross section, where it was revealed that a careful balancing of the amount of charge transfer present in theexcited state of the sensitizer is necessary to obtain both a high singlet oxygen quantum yield and a high two-photon cross section. An increasing...

Probing the SEB Sensitive Depth of a Power MOSFET Using a Two-Photon Absorption Laser Method

Science.gov (United States)

Lauenstein, Jean-Marie; Liu, Sandra; Titus, Jeffrey L.; McMorrow, Dale; Casey, Megan C.; Buchner, Stephen P.; Warner, Jeffrey; Phan, Anthony M.; Topper, Alyson D.; Kim, Hak S.;

Multi-mode interference revealed by two photon absorption in silicon rich SiO2 waveguides

International Nuclear Information System (INIS)

Manna, S.; Ramiro-Manzano, F.; Mancinelli, M.; Turri, F.; Pavesi, L.; Ghulinyan, M.; Pucker, G.

2015-01-01

Photoluminescence (PL) from Si nanocrystals (NCs) excited by two-photon absorption (TPA) has been observed in Si nanocrystal-based waveguides fabricated by plasma enhanced chemical vapor deposition. The TPA excited photoluminescence emission resembles the one-photon excited photoluminescence arising from inter-band transitions in the quantum confined Si nanocrystals. By measuring the non-linear transmission of waveguides, a large TPA coefficient of β up to 10 −8  cm/W has been measured at 1550 nm. These values of β depend on the Si NCs size and are two orders of magnitude larger than the bulk silicon value. Here, we propose to use the TPA excited visible PL emission as a tool to map the spatial intensity profile of the 1550 nm propagating optical modes in multimode waveguides. In this way, multimode interference has been revealed experimentally and confirmed through a finite element simulation

Polarization dependence of two-photon absorption coefficient and nonlinear susceptibility tensor in InP

International Nuclear Information System (INIS)

Matsusue, Toshio; Bando, Hiroyuki; Fujita, Shoichi; Takayama, Yusuke

2011-01-01

Two-photon absorption (TPA) effect in (001) InP is investigated using fs laser. Its dependences on wavelength and polarization are clarified by single and double beam methods with linearly polarized lights. Characteristic features are revealed and discussed with scaling law, crystal bonding and mutual relation of polarizations for double beams. The results are successfully analyzed on the basis of the third-order susceptibility tensor for comprehensive understanding of TPA effect at any polarization geometry. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Two-Photon Fluorescence Microscope for Microgravity Research

Science.gov (United States)

Fischer, David G.; Zimmerli, Gregory A.; Asipauskas, Marius

2005-01-01

A two-photon fluorescence microscope has been developed for the study of biophysical phenomena. Two-photon microscopy is a novel form of laser-based scanning microscopy that enables three-dimensional imaging without many of the problems inherent in confocal microscopy. Unlike one-photon optical microscopy, two-photon microscopy utilizes the simultaneous nonlinear absorption of two near-infrared photons. However, the efficiency of two-photon absorption is much lower than that of one-photon absorption, so an ultra-fast pulsed laser source is typically employed. On the other hand, the critical energy threshold for two-photon absorption leads to fluorophore excitation that is intrinsically localized to the focal volume. Consequently, two-photon microscopy enables optical sectioning and confocal performance without the need for a signal-limiting pinhole. In addition, there is a reduction (relative to one-photon optical microscopy) in photon-induced damage because of the longer excitation wavelength. This reduction is especially advantageous for in vivo studies. Relative to confocal microscopy, there is also a reduction in background fluorescence, and, because of a reduction in Rayleigh scattering, there is a 4 increase of penetration depth. The prohibitive cost of a commercial two-photon fluorescence-microscope system, as well as a need for modularity, has led to the construction of a custom-built system (see Figure 1). This system includes a coherent mode-locked titanium: sapphire laser emitting 120-fs-duration pulses at a repetition rate of 80 MHz. The pulsed laser has an average output power of 800 mW and a wavelength tuning range of 700 to 980 nm, enabling the excitation of a variety of targeted fluorophores. The output from the laser is attenuated, spatially filtered, and then directed into a confocal scanning head that has been modified to provide for side entry of the laser beam. The laser output coupler has been replaced with a dichroic filter that reflects the

Quantum efficiency and two-photon absorption cross-section of conjugated polyelectrolytes used for protein conformation measurements with applications on amyloid structures

Energy Technology Data Exchange (ETDEWEB)

Stabo-Eeg, Frantz [Norwegian University of Science and Technology, N-7491 Trondheim (Norway)], E-mail: Frantz.Stabo-Eeg@phys.ntnu.no; Lindgren, Mikael [Norwegian University of Science and Technology, N-7491 Trondheim (Norway); Nilsson, K. Peter R.; Inganaes, Olle; Hammarstroem, Per [IFM Department of Physics, Chemistry and Biology Linkoeping University, S-581 83 Linkoeping (Sweden)

2007-07-27

Amyloid diseases such as Alzheimer's and spongiform encephalopathies evolve from aggregation of proteins due to misfolding of the protein structure. Early disease handling require sophisticated but yet simple techniques to follow the complex properties of the aggregation process. Conjugated polyelectrolytes (CPEs) have shown promising capabilities acting as optical biological sensors, since they can specifically bind to polypeptides both in solution and in solid phase. The structural changes in biomolecules can be monitored by changes of the optical spectra of the CPEs, both in absorption and emission modes. Notably, the studied CPEs possess multi-photon excitation capability, making them potential for in vivo imaging using laser scanning microscopy. Aggregation of proteins depends on concentration, temperature and pH. The optical effect on the molecular probe in various environments must also be investigated if applied in these environments. Here we present the results of quantum efficiency and two-photon absorption cross-section of three CPEs: POMT, POWT and PTAA in three different pH buffer systems. The extinction coefficient and quantum efficiency were measured. POMT was found to have the highest quantum efficiency being approximately 0.10 at pH 2.0. The two-photon absorption cross-section was measured for POMT and POWT and was found to be more than 18-25 times and 7-11 times that of Fluorescein, respectively. We also show how POMT fluorescence can be used to distinguish conformational differences between amyloid fibrils formed from reduced and non-reduced insulin in spectrally resolved images recorded with a laser scanning microscope using both one- and two-photon excitation.

Polarizable Embedded RI-CC2 Method for Two-Photon Absorption Calculations

DEFF Research Database (Denmark)

Hršak, Dalibor; Khah, Alireza Marefat; Christiansen, Ove

2015-01-01

We present a novel polarizable embedded resolution-of-identity coupled cluster singles and approximate doubles (PERI-CC2) method for calculation of two-photon absorption (TPA) spectra of large molecular systems. The method was benchmarked for three types of systems: a water-solvated molecule...... of formamide, a uracil molecule in aqueous solution, and a set of mutants of the channelrhodopsin (ChR) protein. The first test case shows that the PERI-CC2 method is in excellent agreement with the PE-CC2 method and in good agreement with the PE-CCSD method. The uracil test case indicates that the effects...... of hydrogen bonding on the TPA of a chromophore with the nearest environment is well-described with the PERI-CC2 method. Finally, the ChR calculation shows that the PERI-CC2 method is well-suited and efficient for calculations on proteins with medium-sized chromophores....

Photon absorption of calcium phosphate-based dental biomaterials

International Nuclear Information System (INIS)

Singh, V. P.; Badiger, N. M.; Tekin, H. O.; Kara, U.; Vega C, H. R.; Fernandes Z, M. A.

2017-10-01

Effective atomic number and mass energy absorption buildup factors for four calcium phosphate-based biomaterials used in dental treatments were calculated for 0.015 to 15 MeV photons. The mass energy absorption coefficients were calculated for 0.5 to 40 mean free paths of photons. In the energy region important for dental radiology the Zeff for all studied biomaterials are larger in comparison to larger energies. In x-rays for dental radiology and the energy absorption buildup factors are low, however CbMDI bio material shows a resonance at 80 keV. (Author)

Molecular photosensitisers for two-photon photodynamic therapy.

Science.gov (United States)

Bolze, F; Jenni, S; Sour, A; Heitz, V

2017-11-30

Two-photon excitation has attracted the attention of biologists, especially after the development of two-photon excited microscopy in the nineties. Since then, new applications have rapidly emerged such as the release of biologically active molecules and photodynamic therapy (PDT) using two-photon excitation. PDT, which requires a light-activated drug (photosensitiser), is a clinically approved and minimally invasive treatment for cancer and for non-malignant diseases. This feature article focuses on the engineering of molecular two-photon photosensitisers for PDT, which should bring important benefits to the treatment, increase the treatment penetration depth with near-infrared light excitation, improve the spatial selectivity and reduce the photodamage to healthy tissues. After an overview of the two-photon absorption phenomenon and the methods to evaluate two-photon induced phototoxicity on cell cultures, the different classes of photosensitisers described in the literature are discussed. The two-photon PDT performed with historical one-photon sensitisers are briefly presented, followed by specifically engineered cyclic tetrapyrrole photosensitisers, purely organic photosensitisers and transition metal complexes. Finally, targeted two-photon photosensitisers and theranostic agents that should enhance the selectivity and efficiency of the treatment are discussed.

Two-Color Single-Photon Photoinitiation and Photoinhibition for Subdiffraction Photolithography

Science.gov (United States)

Scott, Timothy F.; Kowalski, Benjamin A.; Sullivan, Amy C.; Bowman, Christopher N.; McLeod, Robert R.

2009-05-01

Controlling and reducing the developed region initiated by photoexposure is one of the fundamental goals of optical lithography. Here, we demonstrate a two-color irradiation scheme whereby initiating species are generated by single-photon absorption at one wavelength while inhibiting species are generated by single-photon absorption at a second, independent wavelength. Co-irradiation at the second wavelength thus reduces the polymerization rate, delaying gelation of the material and facilitating enhanced spatial control over the polymerization. Appropriate overlapping of the two beams produces structures with both feature sizes and monomer conversions otherwise unobtainable with use of single- or two-photon absorption photopolymerization. Additionally, the generated inhibiting species rapidly recombine when irradiation with the second wavelength ceases, allowing for fast sequential exposures not limited by memory effects in the material and thus enabling fabrication of complex two- or three-dimensional structures.

Arduino Due based tool to facilitate in vivo two-photon excitation microscopy.

Science.gov (United States)

Artoni, Pietro; Landi, Silvia; Sato, Sebastian Sulis; Luin, Stefano; Ratto, Gian Michele

2016-04-01

Two-photon excitation spectroscopy is a powerful technique for the characterization of the optical properties of genetically encoded and synthetic fluorescent molecules. Excitation spectroscopy requires tuning the wavelength of the Ti:sapphire laser while carefully monitoring the delivered power. To assist laser tuning and the control of delivered power, we developed an Arduino Due based tool for the automatic acquisition of high quality spectra. This tool is portable, fast, affordable and precise. It allowed studying the impact of scattering and of blood absorption on two-photon excitation light. In this way, we determined the wavelength-dependent deformation of excitation spectra occurring in deep tissues in vivo.

and Three-Photon Absorption Properties of PRODAN based chemo ...

Indian Academy of Sciences (India)

Mehboob

Solvent dependent One-, Two- and Three-Photon Absorption. Properties of PRODAN based chemo-sensors. Md. Mehboob Alam, Mausumi Chattopadhyaya. Department of Chemistry, University of Calcutta, 92 A.P.C. Road, Kolkata - 700009,. India. CONTENTS. 1) Optimized coordinates of all the systems in Gas phase and ...

Coherent single-photon absorption by single emitters coupled to 1D nanophotonic waveguides

DEFF Research Database (Denmark)

Chen, Yuntian; Wubs, Martijn; Mørk, Jesper

2012-01-01

We have derived an efficient model that allows calculating the dynamical single-photon absorption of an emitter coupled to a waveguide. We suggest a novel and simple structure that leads to strong single-photon absorption.......We have derived an efficient model that allows calculating the dynamical single-photon absorption of an emitter coupled to a waveguide. We suggest a novel and simple structure that leads to strong single-photon absorption....

Preparation, one- and two-photon properties of carbazole derivatives containing nitrogen heterocyclic ring

Science.gov (United States)

Zhang, Yichi; Wang, Ping; Li, Liang; Chen, Zhimin; He, Chunying; Wu, Yiqun

Preparation of recording materials with high two-photon absorption activities is one of the important issues to superhigh- density two-photon absorption (TPA) three-dimensional (3D) optical data storage. In this paper, three new carbazole derivatives containing nitrogen heterocyclic ring with symmetric and asymmetric structures are prepared using ethylene as the π bridge between the carbazole unit and nitrogen heterocyclic ring, namely, 9-butyl-3-(2-(1,8- naphthyridin)vinyl)-carbazole (material 1), 9-butyl-3,6-bis(2-(1,8-naphthyl)vinyl)-carbazole (material 2) and 9-butyl-3,6- bis(2-(quinolin)vinyl)-carbazole (material 3). Their one photon properties including linear absorption spectra, fluorescence emission spectra, and fluorescence quantum yields are studied. The fluorescence excited by 120 fs pulse at 800 nm Ti: sapphire laser operating at 1 kHz repetition rate with different incident powers of 9-butyl-3-(2-(quinolin) vinyl)-carbazole (material 3) was investigated, and two-photon absorption cross-sections has been obtained. It is shown that material 3 containing quinoline rings as electron acceptor with symmetric structure exhibit high two-photon absorption activity. The result implies that material 3 (9-butyl-3-(2-(quinolin) vinyl)-carbazole) is a good candidate as a promising recording material for super-high-density two-photon absorption (TPA) three-dimensional (3D) optical data storage. The influence of chemical structure of the materials on the optical properties is discussed.

Selective Two-Photon Absorptive Resonance Femtosecond-Laser Electronic-Excitation Tagging (STARFLEET) Velocimetry in Flow and Combustion Diagnostics

Science.gov (United States)

Jiang, Naibo; Halls, Benjamin R.; Stauffer, Hans U.; Roy, Sukesh; Danehy, Paul M.; Gord, James R.

2016-01-01

Selective Two-Photon Absorptive Resonance Femtosecond-Laser Electronic-Excitation Tagging (STARFLEET), a non-seeded ultrafast-laser-based velocimetry technique, is demonstrated in reactive and non-reactive flows. STARFLEET is pumped via a two-photon resonance in N2 using 202.25-nm 100-fs light. STARFLEET greatly reduces the per-pulse energy required (30 µJ/pulse) to generate the signature FLEET emission compared to the conventional FLEET technique (1.1 mJ/pulse). This reduction in laser energy results in less energy deposited in the flow, which allows for reduced flow perturbations (reactive and non-reactive), increased thermometric accuracy, and less severe damage to materials. Velocity measurements conducted in a free jet of N2 and in a premixed flame show good agreement with theoretical velocities and further demonstrate the significantly less-intrusive nature of STARFLEET.

Ionization of a cesium atom by an absorption process involving two photons from a laser beam; Ionisation d'un atome de cesium par un processus d'absorption a deux photons issus d'un faisceau laser

Energy Technology Data Exchange (ETDEWEB)

Gontier, Y; Trahin, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1967-01-01

The expression giving the ionisation cross-section of an atom, by an absorption process involving two photons produced from a laser beam, is derived. The non-relativistic case is considered and the dipolar approximation used. The summation over the intermediate states is carried out rigorously by means of a special technique which is described in detail. A method is presented which makes it possible to obtain the numerical solution. (authors) [French] La formule donnant la section efficace d'ionisation d'un atome, par un processus d'absorption mettant en jeu deux photons issus d'un faiseau Laser, est etablie. On se place dans le cas non relativiste et Pon utilise l'approximation dipolaire. La sommation sur les etats intermediaires est effectuee rigoureusement au moyen d'une technique particuliere qui est decrite en detail. On expose une methode permettant d'obtenir la solution numerique. (auteurs)

Photon absorption mechanism in the 4He(γ, npp)n reaction

International Nuclear Information System (INIS)

Emura, T.; Endo, I.; Endo, S.

1990-09-01

We measured the 4 He(γ, npp)n reaction in a kinematically complete way for the first time using the large-acceptance TAGX spectrometer and tagged photons at E γ = 135-455 MeV. The momentum and angular distributions of the nucleons are explained by assuming that photons are absorbed either on the two-nucleon systems (np and pp) or on the three nucleon system (npp). The data can not be reproduced well by the photon absorption on the np system only. (author)

Two Photon Absorption Laser Induced Fluorescence for Neutral Hydrogen Profile Measurements

Energy Technology Data Exchange (ETDEWEB)

Scime, Earl E. [West Virginia Univ., Morgantown, WV (United States)

2016-09-23

The magnitude and spatial dependence of neutral density in magnetic confinement fusion experiments is a key physical parameter, particularly in the plasma edge. Modeling codes require precise measurements of the neutral density to calculate charge-exchange power losses and drag forces on rotating plasmas. However, direct measurements of the neutral density are problematic. In this work, we proposed to construct a laser-based diagnostic capable of providing spatially resolved measurements of the neutral density in the edge of plasma in the DIII-D tokamak. The diagnostic concept is based on two-photon absorption laser induced fluorescence (TALIF). By injecting two beams of 205 nm light (co or counter propagating), ground state hydrogen (or deuterium or tritium) can be excited from the n = 1 level to the n = 3 level at the location where the two beams intersect. Individually, the beams experience no absorption, and therefore have no difficulty penetrating even dense plasmas. After excitation, a fraction of the hydrogen atoms decay from the n = 3 level to the n = 2 level and emit photons at 656 nm (the H_α line). Calculations based on the results of previous TALIF experiments in magnetic fusion devices indicated that a laser pulse energy of approximately 3 mJ delivered in 5 ns would provide sufficient signal-to-noise for detection of the fluorescence. In collaboration with the DIII-D engineering staff and experts in plasma edge diagnostics for DIII-D from Oak Ridge National Laboratory (ORNL), WVU researchers designed a TALIF system capable of providing spatially resolved measurements of neutral deuterium densities in the DIII-D edge plasma. The laser systems were specified, purchased, and assembled at WVU. The TALIF system was tested on a low-power hydrogen discharge at WVU and the plan was to move the instrument to DIII-D for installation in collaboration with ORNL researchers. After budget cuts at DIII-D, the DIII-D facility declined to support

Two Photon Absorption Laser Induced Fluorescence for Neutral Hydrogen Profile Measurements

International Nuclear Information System (INIS)

Scime, Earl E.

2016-01-01

The magnitude and spatial dependence of neutral density in magnetic confinement fusion experiments is a key physical parameter, particularly in the plasma edge. Modeling codes require precise measurements of the neutral density to calculate charge-exchange power losses and drag forces on rotating plasmas. However, direct measurements of the neutral density are problematic. In this work, we proposed to construct a laser-based diagnostic capable of providing spatially resolved measurements of the neutral density in the edge of plasma in the DIII-D tokamak. The diagnostic concept is based on two-photon absorption laser induced fluorescence (TALIF). By injecting two beams of 205 nm light (co or counter propagating), ground state hydrogen (or deuterium or tritium) can be excited from the n = 1 level to the n = 3 level at the location where the two beams intersect. Individually, the beams experience no absorption, and therefore have no difficulty penetrating even dense plasmas. After excitation, a fraction of the hydrogen atoms decay from the n = 3 level to the n = 2 level and emit photons at 656 nm (the H α line). Calculations based on the results of previous TALIF experiments in magnetic fusion devices indicated that a laser pulse energy of approximately 3 mJ delivered in 5 ns would provide sufficient signal-to-noise for detection of the fluorescence. In collaboration with the DIII-D engineering staff and experts in plasma edge diagnostics for DIII-D from Oak Ridge National Laboratory (ORNL), WVU researchers designed a TALIF system capable of providing spatially resolved measurements of neutral deuterium densities in the DIII-D edge plasma. The laser systems were specified, purchased, and assembled at WVU. The TALIF system was tested on a low-power hydrogen discharge at WVU and the plan was to move the instrument to DIII-D for installation in collaboration with ORNL researchers. After budget cuts at DIII-D, the DIII-D facility declined to support installation on their

Two-Photon Activation of p-Hydroxyphenacyl Phototriggers: Toward Spatially Controlled Release of Diethyl Phosphate and ATP.

Science.gov (United States)

Houk, Amanda L; Givens, Richard S; Elles, Christopher G

2016-03-31

Two-photon activation of the p-hydroxyphenacyl (pHP) photoactivated protecting group is demonstrated for the first time using visible light at 550 nm from a pulsed laser. Broadband two-photon absorption measurements reveal a strong two-photon transition (>10 GM) near 4.5 eV that closely resembles the lowest-energy band at the same total excitation energy in the one-photon absorption spectrum of the pHP chromophore. The polarization dependence of the two-photon absorption band is consistent with excitation to the same S3 ((1)ππ*) excited state for both one- and two-photon activation. Monitoring the progress of the uncaging reaction under nonresonant excitation at 550 nm confirms a quadratic intensity dependence and that two-photon activation of the uncaging reaction is possible using visible light in the range 500-620 nm. Deprotonation of the pHP chromophore under mildly basic conditions shifts the absorption band to lower energy (3.8 eV) in both the one- and two-photon absorption spectra, suggesting that two-photon activation of the pHP chromophore may be possible using light in the range 550-720 nm. The results of these measurements open the possibility of spatially and temporally selective release of biologically active compounds from the pHP protecting group using visible light from a pulsed laser.

Two-photon-excited fluorescence spectroscopy of atomic fluorine at 170 nm

Science.gov (United States)

Herring, G. C.; Dyer, Mark J.; Jusinski, Leonard E.; Bischel, William K.

1988-01-01

Two-photon-excited fluorescence spectroscopy of atomic fluorine is reported. A doubled dye laser at 286-nm is Raman shifted in H2 to 170 nm (sixth anti-Stokes order) to excite ground-state 2P(0)J fluorine atoms to the 2D(0)J level. The fluorine atoms are detected by one of two methods: observing the fluorescence decay to the 2PJ level or observing F(+) production through the absorption of an additional photon by the excited atoms. Relative two-photon absorption cross sections to and the radiative lifetimes of the 2D(0)J states are measured.

Two-photon or higher-order absorbing optical materials and methods of use

Science.gov (United States)

Marder, Seth (Inventor); Perry, Joseph (Inventor)

2012-01-01

Compositions capable of simultaneous two-photon absorption and higher order absorptivities are provided. Compounds having a donor-pi-donor or acceptor-pi-acceptor structure are of particular interest, where the donor is an electron donating group, acceptor is an electron accepting group, and pi is a pi bridge linking the donor and/or acceptor groups. The pi bridge may additionally be substituted with electron donating or withdrawing groups to alter the absorptive wavelength of the structure. Also disclosed are methods of generating an excited state of such compounds through optical stimulation with light using simultaneous absorption of photons of energies individually insufficient to achieve an excited state of the compound, but capable of doing so upon simultaneous absorption of two or more such photons. Applications employing such methods are also provided, including controlled polymerization achieved through focusing of the light source(s) used.

Electromagnetically induced two-photon transparency in rubidium atoms

International Nuclear Information System (INIS)

Wang, D.; Gao, J.Y.; Xu, J.H.; Bassani, F.; La Rocca, G.C.; Salerno Univ.

2001-01-01

We present an experimental demonstration of electromagnetically induced two-photon transparency (EITT) in room temperature rubidium vapor. The 8S 1/2 to 5P 1/2 fluorescence is used to monitor the 5S 1/2 (F = 3) to 8S 1/2 (F = 3) two-photon absorption near resonance with the intermediate state 5P 3/2 . A controlling pump laser beam is employed to coherently couple the 5P 3/2 and 5D 5/2 states, thus producing two dressed intermediate states which give rise to destructive interference in the two-photon transition. An induced two-photon transparency of about 80% has been obtained at resonance; our experimental findings are in good agreement with the general theory of Agarwal et al. (1996), when the appropriate spectroscopic parameters are used. (orig.)

Coherent single-photon absorption by single emitters coupled to one-dimensional nanophotonic waveguides

Energy Technology Data Exchange (ETDEWEB)

Chen Yuntian; Wubs, Martijn; Moerk, Jesper [DTU Fotonik, Department of Photonics Engineering, Oersteds Plads, DK-2800 Kgs Lyngby (Denmark); Koenderink, A Femius, E-mail: yche@fotonik.dtu.dk [Center for Nanophotonics, FOM Institute for Atomic and Molecular Physics (AMOLF), Science Park 104, 1098 XG Amsterdam (Netherlands)

2011-10-15

We study the dynamics of single-photon absorption by a single emitter coupled to a one-dimensional waveguide that simultaneously provides channels for spontaneous emission (SE) decay and a channel for the input photon. We have developed a time-dependent theory that allows us to specify any input single-photon wavepacket guided by the waveguide as the initial condition, and calculate the excitation probability of the emitter, as well as the time evolution of the transmitted and reflected fields. For single-photon wavepackets with a Gaussian spectrum and temporal shape, we obtain analytical solutions for the dynamics of absorption, with maximum atomic excitation {approx}40%. We furthermore propose a terminated waveguide to aid the single-photon absorption. We found that for an emitter placed at an optimal distance from the termination, the maximum atomic excitation due to an incident single-photon wavepacket can exceed 70%. This high value is a direct consequence of the high SE {beta}-factor for emission into the waveguide. Finally, we have also explored whether waveguide dispersion could aid single-photon absorption by pulse shaping. For a Gaussian input wavepacket, we found that the absorption efficiency can be improved by a further 4% by engineering the dispersion. Efficient single-photon absorption by a single emitter has potential applications in quantum communication and quantum computation. (paper)

Quantum interference between multi photon absorption pathways in organic solid

International Nuclear Information System (INIS)

Rebane, A.; Christensson, N.; Drobizhev, M.; Stepanenko, Y.; Spangler, C.W.

2007-01-01

We demonstrate spatial interference fringe pattern by simultaneous one- and three-photon absorption of UV and near-IR femtosecond pulses in thin film organic solid at room temperature. We use organic dendrimers that are specially designed to have strong fluorescence and very large three-photon absorption cross-section. High fringe visibility allows the quantum interference to be observed by eye

Induced absorption and stimulated emission in a driven two-level atom

International Nuclear Information System (INIS)

Mavroyannis, C.

1992-01-01

We have considered the induced processes that occur in a driven two-level atom, where a laser photon is absorbed and emitted by the ground and by the excited states of the atom, respectively. In the low-intensity limit of the laser field, the induced spectra arising when a laser photon is absorbed by the ground state of the atom consist of two peaks describing induced absorption and stimulated-emission processes, respectively, where the former prevails over the latter. Asymmetry of the spectral lines occurs at off-resonance and its extent depends on the detuning of the laser field. The physical. process where a laser photon is emitted by the excited state is the reverse of that arising from the absorption of a laser photon by the ground state of the atom. The former differs from the latter in that the emission of a laser photon by the excited state occurs in the low frequency regime and that the stimulated-emission process prevails over that of the induced absorption. In this case, amplification of ultrashort pulses is likely to occur without the need of population inversion between the optical transitions. The computed spectra are graphically presented and discussed. (author)

Two-Photon Fluorescence Microscopy Developed for Microgravity Fluid Physics

Science.gov (United States)

Fischer, David G.; Zimmerli, Gregory A.; Asipauskas, Marius

2004-01-01

Recent research efforts within the Microgravity Fluid Physics Branch of the NASA Glenn Research Center have necessitated the development of a microscope capable of high-resolution, three-dimensional imaging of intracellular structure and tissue morphology. Standard optical microscopy works well for thin samples, but it does not allow the imaging of thick samples because of severe degradation caused by out-of-focus object structure. Confocal microscopy, which is a laser-based scanning microscopy, provides improved three-dimensional imaging and true optical sectioning by excluding the out-of-focus light. However, in confocal microscopy, out-of-focus object structure is still illuminated by the incoming beam, which can lead to substantial photo-bleaching. In addition, confocal microscopy is plagued by limited penetration depth, signal loss due to the presence of a confocal pinhole, and the possibility of live-cell damage. Two-photon microscopy is a novel form of laser-based scanning microscopy that allows three-dimensional imaging without many of the problems inherent in confocal microscopy. Unlike one-photon microscopy, it utilizes the nonlinear absorption of two near-infrared photons. However, the efficiency of two-photon absorption is much lower than that of one-photon absorption because of the nonlinear (i.e., quadratic) electric field dependence, so an ultrafast pulsed laser source must typically be employed. On the other hand, this stringent energy density requirement effectively localizes fluorophore excitation to the focal volume. Consequently, two-photon microscopy provides optical sectioning and confocal performance without the need for a signal-limiting pinhole. In addition, there is a reduction in photo-damage because of the longer excitation wavelength, a reduction in background fluorescence, and a 4 increase in penetration depth over confocal methods because of the reduction in Rayleigh scattering.

Collision, scattering and absorption differential cross-sections in double-photon Compton scattering

International Nuclear Information System (INIS)

Dewan, R.; Saddi, M.B.; Sandhu, B.S.; Singh, B.; Ghumman, B.S.

2005-01-01

The collision, scattering and absorption differential cross-sections of double-photon Compton scattering are measured experimentally for 0.662 MeV incident gamma photons. Two simultaneously emitted gamma quanta are investigated using a slow-fast coincidence technique having 25 ns resolving time. The coincidence spectra for different energy windows of one of the two final photons are recorded using HPGe detector. The experimental data do not suffer from inherent energy resolution of gamma detector and provide more faithful reproduction of the distribution under the full energy peak of recorded coincidence spectra. The present results are in agreement with the currently acceptable theory of this higher order process

Doppler-free two-photon excitation of 238U

International Nuclear Information System (INIS)

Hodgkinson, D.P.; Wort, D.J.H.

1981-04-01

A theory of resonantly enhanced two-photon absorption is presented and tested in a number of experiments in which 238 U vapour is excited by two continuous wave dye lasers. Good quantitative agreement between theory and experiment is found. In particular the central prediction of the theory, that antiparallel laser beams of modest intensity can pump an appreciable fraction of the Maxwell velocity distribution, has been checked directly by measuring the spectral width of the fluorescence from the two-photon excited level. (author)

Distribution of photon absorption rates across the rat retina.

Science.gov (United States)

Williams, T P; Webbers, J P; Giordano, L; Henderson, R P

1998-04-15

1. An investigation into the distribution of light intensity across the rat retina was carried out on excised, intact rat eyes exposed to Ganzfeld illumination from a helium-neon laser (543 nm). 2. Some of the light entering the eyes exits through the sclera where its intensity can be monitored with an optical 'pick-up' that samples the intensity coming from a small region of external sclera and underlying retina. The spatial resolution of the pick-up is such that it samples light that has passed through ca 2 % of the rods in the rat eye. 3. Some of the laser light is absorbed by the rod pigment, rhodopsin, which gradually bleaches. Bleaching in the retina, in turn, causes an exponential increase in intensity emanating from the sclera. By monitoring this intensity increase, we are able to measure two important parameters in a single bleaching run: the local rhodopsin concentration and the local intensity falling on the rods. 4. With an ocular transmission photometer, we have measured both the local intensity and the local rhodopsin concentration across wide regions of rat retina. Both pigmented and albino rats were studied. 5. The distributions of rhodopsin and intensity were both nearly uniform; consequently, the product, (rhodopsin concentration) x (intensity), was similarly nearly equal across the retina. This means that the initial rate of photon absorption is about the same at all retinal locations. 6. Interpreted in terms of photostasis (the regulation of daily photon catch), this means that the rate of photon absorption is about the same in each rod, viz. 14 400 photons absorbed per rod per second. Since this rate of absorption is sufficient to saturate the rod, one possible purpose of photostasis is to maintain the rod system in a saturated state during daylight hours.

Ionization of a cesium atom by an absorption process involving two photons from a laser beam; Ionisation d'un atome de cesium par un processus d'absorption a deux photons issus d'un faisceau laser

Energy Technology Data Exchange (ETDEWEB)

Gontier, Y.; Trahin, M. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1967-01-01

The expression giving the ionisation cross-section of an atom, by an absorption process involving two photons produced from a laser beam, is derived. The non-relativistic case is considered and the dipolar approximation used. The summation over the intermediate states is carried out rigorously by means of a special technique which is described in detail. A method is presented which makes it possible to obtain the numerical solution. (authors) [French] La formule donnant la section efficace d'ionisation d'un atome, par un processus d'absorption mettant en jeu deux photons issus d'un faiseau Laser, est etablie. On se place dans le cas non relativiste et Pon utilise l'approximation dipolaire. La sommation sur les etats intermediaires est effectuee rigoureusement au moyen d'une technique particuliere qui est decrite en detail. On expose une methode permettant d'obtenir la solution numerique. (auteurs)

Photonic devices based on patterning by two photon induced polymerization techniques

Science.gov (United States)

Fortunati, I.; Dainese, T.; Signorini, R.; Bozio, R.; Tagliazucca, V.; Dirè, S.; Lemercier, G.; Mulatier, J.-C.; Andraud, C.; Schiavuta, P.; Rinaldi, A.; Licoccia, S.; Bottazzo, J.; Franco Perez, A.; Guglielmi, M.; Brusatin, G.

2008-04-01

Two and three dimensional structures with micron and submicron resolution have been achieved in commercial resists, polymeric materials and sol-gel materials by several lithographic techniques. In this context, silicon-based sol-gel materials are particularly interesting because of their versatility, chemical and thermal stability, amount of embeddable active compounds. Compared with other micro- and nano-fabrication schemes, the Two Photon Induced Polymerization is unique in its 3D processing capability. The photopolymerization is performed with laser beam in the near-IR region, where samples show less absorption and less scattering, giving rise to a deeper penetration of the light. The use of ultrashort laser pulses allows the starting of nonlinear processes like multiphoton absorption at relatively low average power without thermally damaging the samples. In this work we report results on the photopolymerization process in hybrid organic-inorganic films based photopolymerizable methacrylate-containing Si-nanobuilding blocks. Films, obtained through sol-gel synthesis, are doped with a photo-initiator allowing a radical polymerization of methacrylic groups. The photo-initiator is activated by femtosecond laser source, at different input energies. The development of the unexposed regions is performed with a suitable solvent and the photopolymerized structures are characterized by microscopy techniques.

Enhancement of broadband optical absorption in photovoltaic devices by band-edge effect of photonic crystals.

Science.gov (United States)

Tanaka, Yoshinori; Kawamoto, Yosuke; Fujita, Masayuki; Noda, Susumu

2013-08-26

We numerically investigate broadband optical absorption enhancement in thin, 400-nm thick microcrystalline silicon (µc-Si) photovoltaic devices by photonic crystals (PCs). We realize absorption enhancement by coupling the light from the free space to the large area resonant modes at the photonic band-edge induced by the photonic crystals. We show that multiple photonic band-edge modes can be produced by higher order modes in the vertical direction of the Si photovoltaic layer, which can enhance the absorption on multiple wavelengths. Moreover, we reveal that the photonic superlattice structure can produce more photonic band-edge modes that lead to further optical absorption. The absorption average in wavelengths of 500-1000 nm weighted to the solar spectrum (AM 1.5) increases almost twice: from 33% without photonic crystal to 58% with a 4 × 4 period superlattice photonic crystal; our result outperforms the Lambertian textured structure.

Two-photon transitions to exciton polaritons

International Nuclear Information System (INIS)

Hassan, A.R.

1979-08-01

A semiclassical theory for the creation of excitonic polariton states by two-photon absorption, via an intermediate exciton state, is given. A band model has been introduced which gives the dominant contribution to this process. A numerical calculation is found to be in good agreement with a recent observation in CuCl. (author)

Theory of two-photon interactions with broadband down-converted light and entangled photons

International Nuclear Information System (INIS)

Dayan, Barak

2007-01-01

When two-photon interactions are induced by down-converted light with a bandwidth that exceeds the pump bandwidth, they can obtain a behavior that is pulselike temporally, yet spectrally narrow. At low photon fluxes this behavior reflects the time and energy entanglement between the down-converted photons. However, two-photon interactions such as two-photon absorption (TPA) and sum-frequency generation (SFG) can exhibit such a behavior even at high power levels, as long as the final state (i.e., the atomic level in TPA, or the generated light in SFG) is narrow-band enough. This behavior does not depend on the squeezing properties of the light, is insensitive to linear losses, and has potential applications. In this paper we describe analytically this behavior for traveling-wave down conversion with continuous or pulsed pumping, both for high- and low-power regimes. For this we derive a quantum-mechanical expression for the down-converted amplitude generated by an arbitrary pump, and formulate operators that represent various two-photon interactions induced by broadband light. This model is in excellent agreement with experimental results of TPA and SFG with high-power down-converted light and with entangled photons [Dayan et al., Phys. Rev. Lett. 93, 023005 (2004); 94, 043602 (2005); Pe'er et al., ibid. 94, 073601 (2005)

Two photon absorption energy transfer in the light-harvesting complex of photosystem II (LHC-II) modified with organic boron dye

Science.gov (United States)

Chen, Li; Liu, Cheng; Hu, Rui; Feng, Jiao; Wang, Shuangqing; Li, Shayu; Yang, Chunhong; Yang, Guoqiang

2014-07-01

The plant light-harvesting complexes of photosystem II (LHC-II) play important roles in collecting solar energy and transferring the energy to the reaction centers of photosystems I and II. A two photon absorption compound, 4-(bromomethyl)-N-(4-(dimesitylboryl)phenyl)-N-phenylaniline (DMDP-CH2Br), was synthesized and covalently linked to the LHC-II in formation of a LHC-II-dye complex, which still maintained the biological activity of LHC-II system. Under irradiation with femtosecond laser pulses at 754 nm, the LHC-II-dye complex can absorb two photons of the laser light effectively compared with the wild type LHC-II. The absorbed excitation energy is then transferred to chlorophyll a with an obvious fluorescence enhancement. The results may be interesting and give potentials for developing hybrid photosystems.

Dynamical Evolution of Properties for Atom and Field in the Process of Two-Photon Absorption and Emission Between Atomic Levels

Science.gov (United States)

Wang, Jian-ming; Xu, Xue-xiang

2018-04-01

Using dressed state method, we cleverly solve the dynamics of atom-field interaction in the process of two-photon absorption and emission between atomic levels. Here we suppose that the atom is initially in the ground state and the optical field is initially in Fock state, coherent state or thermal state, respectively. The properties of the atom, including the population in excited state and ground state, the atom inversion, and the properties for optical field, including the photon number distribution, the mean photon number, the second-order correlation function and the Wigner function, are discussed in detail. We derive their analytical expressions and then make numerical analysis for them. In contrast with Jaynes-Cummings model, some similar results, such as quantum Rabi oscillation, revival and collapse, are also exhibit in our considered model. Besides, some novel nonclassical states are generated.

Evaluation of mitochondrial activity by two-photon absorption with near-field multioptical fiber probes

Science.gov (United States)

Kanazashi, Yasuaki; Takara, Naoshi; Iwami, Kentaro; Ohta, Yoshihiro; Umeda, Norihiro

2018-04-01

pH measurements enable the direct monitoring and evaluation of mitochondrial activity. We constructed a scanning near-field optical microscopy system with multioptical fiber probes using the two-photon absorption of a pH-sensitive fluorescent dye, SNARF-4F, to measure the activity difference of mitochondrial aggregates. pH can be monitored through the fluorescence intensity ratio (FIR) of SNARF-4F. We derived a calibration curve of the FIR as a function of pH. The FIR dynamic responses were measured by adding hydrochloric acid to the buffer solution. Using the developed system, we simultaneously measured the pH changes at two different locations in the SNARF-4F solution. Mitochondrial samples were prepared using optical tweezers to control the number and position of mitochondria. Mitochondrial pH changes (ΔpH) between 0.05 and 0.57 were observed after adding a nutritional supplement (malate and glutamate). In addition, in the comparative experiment on the activities of two mitochondrial populations, the obtained result suggested that the activity differs depending on the difference in the number of mitochondria.

Uniform silica nanoparticles encapsulating two-photon absorbing fluorescent dye

International Nuclear Information System (INIS)

Wu Weibing; Liu Chang; Wang Mingliang; Huang Wei; Zhou Shengrui; Jiang Wei; Sun Yueming; Cui Yiping; Xu Chunxinag

2009-01-01

We have prepared uniform silica nanoparticles (NPs) doped with a two-photon absorbing zwitterionic hemicyanine dye by reverse microemulsion method. Obvious solvatochromism on the absorption spectra of dye-doped NPs indicates that solvents can partly penetrate into the silica matrix and then affect the ground and excited state of dye molecules. For dye-doped NP suspensions, both one-photon and two-photon excited fluorescence are much stronger and recorded at shorter wavelength compared to those of free dye solutions with comparative overall dye concentration. This behavior is possibly attributed to the restricted twisted intramolecular charge transfer (TICT), which reduces fluorescence quenching when dye molecules are trapped in the silica matrix. Images from two-photon laser scanning fluorescence microscopy demonstrate that the dye-doped silica NPs can be actively uptaken by Hela cells with low cytotoxicity. - Graphical abstract: Water-soluble silica NPs doped with a two-photon absorbing zwitterionic hemicyanine dye were prepared. They were found of enhanced one-photon and two-photon excited fluorescence compared to free dye solutions. Images from two-photon laser scanning fluorescence microscopy demonstrate that the dye-doped silica NPs can be actively uptaken by Hela cells.

Measurement of electron beam polarization from unstrained GaAs via two-photon photoemission

Energy Technology Data Exchange (ETDEWEB)

McCarter, J.L., E-mail: jlm2ar@virginia.edu [Department of Physics, University of Virginia, Charlottesville, VA 22901 (United States); Afanasev, A. [Department of Physics, The George Washington University, Washington, DC 20052 (United States); Gay, T.J. [Jorgensen Hall, University of Nebraska, Lincoln, NE 68588 (United States); Hansknecht, J. [Thomas Jefferson National Accelerator Facility, 12050 Jefferson Avenue, Suite 500, Newport News, VA 23606 (United States); Kechiantz, A. [Department of Physics, The George Washington University, Washington, DC 20052 (United States); Poelker, M. [Thomas Jefferson National Accelerator Facility, 12050 Jefferson Avenue, Suite 500, Newport News, VA 23606 (United States)

2014-02-21

Two-photon absorption of 1560 nm light was used to generate polarized electron beams from unstrained GaAs photocathodes of varying thickness: 625 μm, 0.32 μm, and 0.18 μm. For each photocathode, the degree of spin polarization of the photoemitted beam was less than 50%, contradicting earlier predictions based on simple quantum mechanical selection rules for spherically-symmetric systems but consistent with the more sophisticated model of Bhat et al. (Phys. Rev. B 71 (2005) 035209). Polarization via two-photon absorption was the highest from the thinnest photocathode sample and comparable to that obtained via one-photon absorption (using 778 nm light), with values 40.3±1.0% and 42.6±1.0%, respectively.

Enhanced Size Selection in Two-Photon Excitation for CsPbBr3 Perovskite Nanocrystals.

Science.gov (United States)

Chen, Junsheng; Chábera, Pavel; Pascher, Torbjörn; Messing, Maria E; Schaller, Richard; Canton, Sophie; Zheng, Kaibo; Pullerits, Tõnu

2017-10-19

Cesium lead bromide (CsPbBr 3 ) perovskite nanocrystals (NCs), with large two-photon absorption (TPA) cross-section and bright photoluminescence (PL), have been demonstrated as stable two-photon-pumped lasing medium. With two-photon excitation, red-shifted PL spectrum and increased PL lifetime is observed compared with one-photon excitation. We have investigated the origin of such difference using time-resolved laser spectroscopies. We ascribe the difference to the enhanced size selection of NCs by two-photon excitation. Because of inherent nonlinearity, the size dependence of absorption cross-section under TPA is stronger. Consequently, larger size NCs are preferably excited, leading to longer excited-state lifetime and red-shifted PL emission. In a broad view, the enhanced size selection in two-photon excitation of CsPbBr 3 NCs is likely a general feature of the perovskite NCs and can be tuned via NC size distribution to influence their performance within NC-based nonlinear optical materials and devices.

Performance Analysis of Spectral-Phase-Encoded Optical CDMA System Using Two-Photon-Absorption Receiver Structure for Asynchronous and Slot-Level Synchronous Transmitters

Science.gov (United States)

Jamshidi, Kambiz; Salehi, Jawad A.

2007-06-01

In this paper, we analyze the performance of a nonlinear two-photon-absorption (TPA) receiver and compare its performance with that of a single-photon-absorption (SPA) receiver in the context of spectral-phase-encoded optical code-division multiple access (CDMA) technique. The performances for the above systems are evaluated for two different transmission scenarios, namely, asynchronous and slot-level synchronous transmitters. Performance evaluation includes different sources of degradation such as multiple-access interference, noise due to optical amplification, shot noise, and thermal noise. In obtaining the performance, the mean and variance of the received signal in each of the above techniques are derived, and bit error rate is obtained using Gaussian approximation. In general, it is shown that TPA receivers are superior in performance with respect to SPA receivers when the receiver employs a much slower photodetector in comparison with the laser's transmitted pulse duration. This, indeed, is the reason behind the choice of nonlinear receivers, such as TPA, in most spectral-phase-encoded optical CDMA systems.

Two-photon spin generation and detection

International Nuclear Information System (INIS)

Miah, M Idrish

2009-01-01

A time- and polarization-resolved two-photon pump-probe investigation is performed in lightly doped GaAs. We generate spin-polarized electrons in bulk GaAs at various temperatures using right-circularly polarized two-photon excitation and detect them by probing the spin-dependent transmission of the sample. The spin polarization (P) of conduction band electrons, as measured using probe pulses with the same (right) and opposite (left) circular polarization, is measured in dependences of pump-probe delay (Δt), lattice temperature (T L ), doping density (n) as well as of the excess photon energy ΔE 2ω = ℎ2ω - E g , where E g is the band gap energy. P is found to be decayed with Δt and enhanced with the decrease in T L or the increase in n. It is also found that P decreases with the increase in ΔE 2ω and depolarizes rapidly for ΔE 2ω > ΔE SO , where ΔE SO is the spin-orbit splitting energy. The results demonstrate that due to a much longer absorption depth highly polarized spins can be generated optically by two-photon pumping of bulk semiconductors.

Effective photons in weakly absorptive dielectric media and the Beer–Lambert–Bouguer law

International Nuclear Information System (INIS)

Judge, A C; Brownless, J S; Martijn de Sterke, C; Bhat, N A R; Sipe, J E; Steel, M J

2014-01-01

We derive effective photon modes that facilitate an intuitive and convenient picture of photon dynamics in a structured Kramers–Kronig dielectric in the limit of weak absorption. Each mode is associated with a mode field distribution that includes the effects of both material and structural dispersion, and an effective line-width that determines the temporal decay rate of the photon. These results are then applied to obtain an expression for the Beer–Lambert–Bouguer law absorption coefficient for unidirectional propagation in structured media consisting of dispersive, weakly absorptive dielectric materials

Mitochondria-targeted cationic porphyrin-triphenylamine hybrids for enhanced two-photon photodynamic therapy.

Science.gov (United States)

Hammerer, Fabien; Poyer, Florent; Fourmois, Laura; Chen, Su; Garcia, Guillaume; Teulade-Fichou, Marie-Paule; Maillard, Philippe; Mahuteau-Betzer, Florence

2018-01-01

The proof of concept for two-photon activated photodynamic therapy has already been achieved for cancer treatment but the efficiency of this approach still heavily relies on the availability of photosensitizers combining high two-photon absorption and biocompatibility. In this line we recently reported on a series of porphyrin-triphenylamine hybrids which exhibit high singlet oxygen production quantum yield as well as high two-photon absorption cross-sections but with a very poor cellular internalization. We present herein new photosensitizers of the same porphyrin-triphenylamine hybrid series but bearing cationic charges which led to strongly enhanced water solubility and thus cellular penetration. In addition the new compounds have been found localized in mitochondria that are preferential target organelles for photodynamic therapy. Altogether the strongly improved properties of the new series combined with their specific mitochondrial localization lead to a significantly enhanced two-photon activated photodynamic therapy efficiency. Copyright © 2017 Elsevier Ltd. All rights reserved.

Two-photon polarization Fourier spectroscopy of metastable atomic hydrogen

International Nuclear Information System (INIS)

Duncan, A.J.; Beyer, H.-J.; Kleinpoppen, H.; Sheikh, Z.A,; B-Z Univ., Multan

1997-01-01

A novel Fourier-transform spectroscopic method using two-photon polarization to determine the spectral distribution of the two photons emitted in the spontaneous decay of metastable atomic hydrogen is described. The method uses birefringent retardation plates and takes advantage of the subtle interplay between the spectral properties and the entangled polarization properties of the radiation emitted in the decay. Assuming the validity of the theoretical spectral distribution, it is shown that the experimental results agree well with theory. On the other hand, success in solving the inverse problem of determining the spectral distribution from the experimental results is limited by the small number of experimental points. However, making reasonable assumptions it is deduced that the observed spectrum is characterized by a broadband signal of width (0.43 ± 0.06) x 10 16 rad s -1 and centre angular frequency (0.77 ± 0.03) x 10 16 rad s -1 in good agreement with the predictions of 0.489 x 10 16 rad s -1 and 0.775 x 10 16 rad s -1 , respectively, obtained from the theoretical spectral distribution modified to take account of the absorption of the two-photon radiation in air. The values of 1.5 fs for the coherence time and 440 nm for the coherence length for single photons of the two-photon pair which are obtained from the measured bandwidth imply that, in the ideal case, these values are determined by the essentially zero lifetime of the virtual intermediate state of the decay process rather than the long lifetime of the metastable state which, it is suggested, determines the coherence time and coherence length appropriate to certain types of fourth-order interference experiments. (Author)

Data reading with the aid of one-photon and two-photon luminescence in three-dimensional optical memory devices based on photochromic materials

International Nuclear Information System (INIS)

Akimov, Denis A; Zheltikov, Aleksei M; Koroteev, Nikolai I; Naumov, A N; Fedotov, Andrei B; Magnitskiy, Sergey A; Sidorov-Biryukov, D A; Sokolyuk, N T

1998-01-01

The problem of nondestructive reading of the data stored in the interior of a photochromic sample was analysed. A comparison was made of the feasibility of reading based on one-photon and two-photon luminescence. A model was proposed for the processes of reading the data stored in photochromic molecules with the aid of one-photon and two-photon luminescence. In addition to photochromic transitions, account was taken of the transfer of populations between optically coupled transitions in molecules under the action of the exciting radiation. This model provided a satisfactory description of the kinetics of decay of the coloured form of bulk samples of spiropyran and made it possible to determine experimentally the quantum yield of the reverse photoreaction as well as the two-photon absorption cross section of the coloured form. Measurements were made of the characteristic erasure times of the data stored in a photochromic medium under one-photon and two-photon luminescence reading conditions. It was found that the use of two-photon luminescence made it possible to enhance considerably the contrast and localisation of the optical data reading scheme in three-dimensional optical memory devices. The experimental results were used to estimate the two-photon absorption cross section of the coloured form of a sample of indoline spiropyran in a polymethyl methacrylate matrix. (laser applications and other topics in quantum electronics)

Photo-induced changes of silicate glasses optical parameters at multi-photon laser radiation absorption

International Nuclear Information System (INIS)

Efimov, O.M.; Glebov, L.B.; Mekryukov, A.M.

1995-01-01

In this paper the results of investigations of the mechanisms of photo-induced changes of alkali-silicate (crown) and lead-silicate (flint) glasses optical parameters upon the exposure to the intense laser radiation, and the basic regularities of these processes are reported. These investigations were performed in Research Center open-quotes S. I. Vavilov State Optical Instituteclose quotes during last 15 years. The kinetics of stable and unstable CC formation and decay, the effect of widely spread impurity ions on these processes, the characteristics of fundamental and impure luminescence, the kinetics of refractive index change under conditions of multi-photon glass matrix excitation, and other properties are considered. On the basis of analysis of received regularities it was shown that the nonlinear coloration of alkali-silicate glasses (the fundamental absorption edge is nearly 6 eV) takes place only as a result of two-photon absorption. Important efforts were aimed at the detection of three- or more photon matrix ionization of these glasses, but they were failed. However it was established that in the lead silicate glasses the long-wave carriers mobility boundary (> 5.6 eV) is placed considerably higher the fundamental absorption edge (∼ 3.5 eV) of material matrix. This results in that the linear color centers formation in the lead silicate glasses is not observed. The coloration of these glasses arises only from the two- or three-photon matrix ionization, and the excitation occurs through virtual states that are placed in the fundamental absorption region. In the report the available mechanisms of photo-induced changes of glasses optical parameters, and some applied aspects of this problem are discussed

Two-photon absorption laser-induced fluorescence of atomic oxygen in the afterglow of pulsed positive corona discharge

Science.gov (United States)

Ono, Ryo; Takezawa, Kei; Oda, Tetsuji

2009-08-01

Atomic oxygen is measured in the afterglow of pulsed positive corona discharge using time-resolved two-photon absorption laser-induced fluorescence. The discharge occurs in a 14 mm point-to-plane gap in dry air. After the discharge pulse, the atomic oxygen density decreases at a rate of 5×104 s-1. Simultaneously, ozone density increases at almost the same rate, where the ozone density is measured using laser absorption method. This agreement between the increasing rate of atomic oxygen and decreasing rate of ozone proves that ozone is mainly produced by the well-known three-body reaction, O+O2+M→O3+M. No other process for ozone production such as O2(v)+O2→O3+O is observed. The spatial distribution of atomic oxygen density is in agreement with that of the secondary streamer luminous intensity. This agreement indicates that atomic oxygen is mainly produced in the secondary streamer channels, not in the primary streamer channels.

Self-assembly of Terbium(III)-based metal-organic complexes with two-photon absorbing active

Science.gov (United States)

Li, Dandan; Shao, Nanqi; Sun, Xianshun; Zhang, Guocui; Li, Shengli; Zhou, Hongping; Wu, Jieying; Tian, Yupeng

2014-12-01

Hybrid complexes based on D-π-A type dyes p-aminostyryl-pyridinum and Terbium(III) complex anion (1, 2) have been synthesized by ionic exchange reaction. Meanwhile two different alkyl-substituted amino groups were used as electron donors in organic dyes cations. The synthesized complexes were characterized by element analysis. In addition, the structural features of them were systematic studied by single crystal X-ray diffraction analysis. Their linear properties have been systematically investigated by absorption spectra and fluorescence, the results show that the energy transfer takes place from the trans-4-[4‧-(N,N-diethylamino)styryl]-N-methyl pyridinium (2‧) cation to Tb(III). In addition, complex 2 exhibit a large two-photon absorption coefficient β: 0.044 cm/GW at 710 nm.

Analytical Absorption Cross-Section for Photon by a Hydrogen 2s Atom

International Nuclear Information System (INIS)

Ndinya, Boniface Otieno; Okeyo, Stephen Onyango

2011-01-01

We calculate the absorption cross-section for photon by a hydrogen 2s atom using the quantum-classical approximation for the total photo cross-section of many electron atoms. With the application of the first-order term of the Baker-Hausdorf expansion, the absorption cross-section for the hydrogen 2s atom decreases to a minimum, the Cooper pair minimum, at low photon energy. Such a minimum is absent in the exact absorption cross-section for photon by a hydrogen 2s atom. We have extended the calculation for the absorption cross-section of the hydrogen 2s atom using the quantum-classical approximation for the total photo cross-section of many electron to include the second-order term of the Baker-Hausdorf expansion and observed a great reduction in the dip associated with the Cooper pair minimum at the zero crossing. (atomic and molecular physics)

Two-photon spin generation and detection

Energy Technology Data Exchange (ETDEWEB)

Miah, M Idrish, E-mail: m.miah@griffith.edu.a [Nanoscale Science and Technology Centre, Griffith University, Nathan, Brisbane, QLD 4111 (Australia)

2009-02-21

A time- and polarization-resolved two-photon pump-probe investigation is performed in lightly doped GaAs. We generate spin-polarized electrons in bulk GaAs at various temperatures using right-circularly polarized two-photon excitation and detect them by probing the spin-dependent transmission of the sample. The spin polarization (P) of conduction band electrons, as measured using probe pulses with the same (right) and opposite (left) circular polarization, is measured in dependences of pump-probe delay ({Delta}t), lattice temperature (T{sub L}), doping density (n) as well as of the excess photon energy {Delta}E{sub 2{omega}}= {h_bar}2{omega} - E{sub g}, where E{sub g} is the band gap energy. P is found to be decayed with {Delta}t and enhanced with the decrease in T{sub L} or the increase in n. It is also found that P decreases with the increase in {Delta}E{sub 2{omega}}and depolarizes rapidly for {Delta}E{sub 2{omega}}> {Delta}E{sub SO}, where {Delta}E{sub SO} is the spin-orbit splitting energy. The results demonstrate that due to a much longer absorption depth highly polarized spins can be generated optically by two-photon pumping of bulk semiconductors.

One Photon Can Simultaneously Excite Two or More Atoms.

Science.gov (United States)

Garziano, Luigi; Macrì, Vincenzo; Stassi, Roberto; Di Stefano, Omar; Nori, Franco; Savasta, Salvatore

2016-07-22

We consider two separate atoms interacting with a single-mode optical or microwave resonator. When the frequency of the resonator field is twice the atomic transition frequency, we show that there exists a resonant coupling between one photon and two atoms, via intermediate virtual states connected by counterrotating processes. If the resonator is prepared in its one-photon state, the photon can be jointly absorbed by the two atoms in their ground state which will both reach their excited state with a probability close to one. Like ordinary quantum Rabi oscillations, this process is coherent and reversible, so that two atoms in their excited state will undergo a downward transition jointly emitting a single cavity photon. This joint absorption and emission process can also occur with three atoms. The parameters used to investigate this process correspond to experimentally demonstrated values in circuit quantum electrodynamics systems.

Coherent single-photon absorption by single emitters coupled to one-dimensional nanophotonic waveguides

DEFF Research Database (Denmark)

Chen, Yuntian; Wubs, Martijn; Mørk, Jesper

2011-01-01

-photon wavepacket can exceed 70%. This high value is a direct consequence of the high SE β-factor for emission into the waveguide. Finally, we have also explored whether waveguide dispersion could aid single-photon absorption by pulse shaping. For a Gaussian input wavepacket, we found that the absorption efficiency...

Tuning Ag29 nanocluster light emission from red to blue with one and two-photon excitation.

Science.gov (United States)

Russier-Antoine, Isabelle; Bertorelle, Franck; Hamouda, Ramzi; Rayane, Driss; Dugourd, Philippe; Sanader, Željka; Bonačić-Koutecký, Vlasta; Brevet, Pierre-François; Antoine, Rodolphe

2016-02-07

We demonstrate that the tuning of the light emission from red to blue in dihydrolipoic acid (DHLA) capped Ag29 nanoclusters can be trigged with one and two photon excitations. The cluster stoichiometry was determined with mass spectrometry and found to be Ag29(DHLA)12. In a detailed optical investigation, we show that these silver nanoclusters exhibit a strong red photoluminescence visible to the naked eye and characterized by a quantum yield of nearly ∼2% upon one-photon excitation. In the nonlinear optical (NLO) study of the properties of the clusters, the two-photon excited fluorescence spectra were recorded and their first hyperpolarizability obtained. The two-photon absorption cross-section at ∼800 nm for Ag29(DHLA)12 is higher than 10(4) GM and the hyperpolarizability is 106 × 10(-30) esu at the same excitation wavelength. The two-photon excited fluorescence spectrum appears strongly blue-shifted as compared to the one-photon excited spectrum, displaying a broad band between 400 and 700 nm. The density functional theory (DFT) provides insight into the structural and electronic properties of Ag29(DHLA)12 as well as into interplay between metallic subunit or core and ligands which is responsible for unique optical properties.

Determining photon energy absorption parameters for different soil samples

International Nuclear Information System (INIS)

Kucuk, Nil; Cakir, Merve; Tumsavas, Zeynal

2013-01-01

The mass attenuation coefficients (μ s ) for five different soil samples were measured at 661.6, 1173.2 and 1332.5 keV photon energies. The soil samples were separately irradiated with 137 Cs and 60 Co (370 kBq) radioactive point gamma sources. The measurements were made by performing transmission experiments with a 2″ x 2″ NaI(Tl) scintillation detector, which had an energy resolution of 7% at 0.662 MeV for the gamma-rays from the decay of 137 Cs. The effective atomic numbers (Z eff ) and the effective electron densities (N eff ) were determined experimentally and theoretically using the obtained μ s values for the soil samples. Furthermore, the Z eff and N eff values of the soil samples were computed for the total photon interaction cross-sections using theoretical data over a wide energy region ranging from 1 keV to 15 MeV. The experimental values of the soils were found to be in good agreement with the theoretical values. Sandy loam and sandy clay loam soils demonstrated poor photon energy absorption characteristics. However, clay loam and clay soils had good photon energy absorption characteristics. (author)

Femtosecond Two-Photon Absorption Spectroscopy of Poly(fluorene Derivatives Containing Benzoselenadiazole and Benzothiadiazole

Directory of Open Access Journals (Sweden)

Marcelo Gonçalves Vivas

2017-05-01

Full Text Available We have investigated the molecular structure and two-photon absorption (2PA properties relationship of two push–pull poly(fluorene derivatives containing benzoselenadiazole and benzothiadiazole units. For that, we have used the femtosecond wavelength-tunable Z-scan technique with a low repetition rate (1 kHz and an energy per pulse on the order of nJ. Our results show that both 2PA spectra present a strong 2PA (around 600 GM (1 GM = 1 × 10−50 cm4·s·photon−1 band at around 720 nm (transition energy 3.45 eV ascribed to the strongly 2PA-allowed 1Ag-like → mAg-like transition, characteristic of poly(fluorene derivatives. Another 2PA band related to the intramolecular charge transfer was also observed at around 900 nm (transition energy 2.75 eV. In both 2PA bands, we found higher 2PA cross-section values for the poly(fluorene containing benzothiadiazole unit. This outcome was explained through the higher charge redistribution at the excited state caused by the benzothiadiazole group as compared to the benzoselenadiazole and confirmed by means of solvatochromic Stokes shift measurements. To shed more light on these results, we employed the sum-over-states approach within the two-energy level model to estimate the maximum permanent dipole moment change related to the intramolecular charge transfer transition.

Characterizing multi-photon quantum interference with practical light sources and threshold single-photon detectors

Science.gov (United States)

Navarrete, Álvaro; Wang, Wenyuan; Xu, Feihu; Curty, Marcos

2018-04-01

The experimental characterization of multi-photon quantum interference effects in optical networks is essential in many applications of photonic quantum technologies, which include quantum computing and quantum communication as two prominent examples. However, such characterization often requires technologies which are beyond our current experimental capabilities, and today's methods suffer from errors due to the use of imperfect sources and photodetectors. In this paper, we introduce a simple experimental technique to characterize multi-photon quantum interference by means of practical laser sources and threshold single-photon detectors. Our technique is based on well-known methods in quantum cryptography which use decoy settings to tightly estimate the statistics provided by perfect devices. As an illustration of its practicality, we use this technique to obtain a tight estimation of both the generalized Hong‑Ou‑Mandel dip in a beamsplitter with six input photons and the three-photon coincidence probability at the output of a tritter.

Two-Photon or Higher-Order Absorbing Optical Materials for Generation of Reactive Species

Science.gov (United States)

Cumpston, Brian (Inventor); Lipson, Matthew (Inventor); Marder, Seth R. (Inventor); Perry, Joseph W. (Inventor)

2013-01-01

Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.

On the theory of the two-photon linear photovoltaic effect in n-GaP

Energy Technology Data Exchange (ETDEWEB)

Rasulov, V. R.; Rasulov, R. Ya., E-mail: r-rasulov51@mail.ru [Fergana State University (Uzbekistan)

2016-02-15

A quantitative theory of the diagonal (ballistic) and nondiagonal (shift) band index contributions to the two-photon current of the linear photovoltaic effect in a semiconductor with a complex band due to the asymmetry of events of electron scattering at phonons and photons is developed. It is shown that processes caused by the simultaneous absorption of two photons do not contribute to the ballistic photocurrent in n-GaP. This is due to the fact that, in this case, there is no asymmetric distribution of the momentum of electrons excited with photons; this distribution arises upon the sequential absorption of two photons with the involvement of LO phonons. It is demonstrated that the temperature dependence of the shift contribution to the two-photon photocurrent in n-GaP is determined by the temperature dependence of the light-absorption coefficient caused by direct optical transitions of electrons between subbands X{sub 1} and X{sub 3}. It is shown that the spectral dependence of the photocurrent has a feature in the light frequency range ω → Δ/2ℏ, which is related to the hump-like shape of subband X{sub 1} in n-GaP{sup 1} and the root-type singularity of the state density determined as k{sub ω}{sup -1}= (2ℏω–Δ){sup –1/2}, where Δ is the energy gap between subbands X{sub 1} and X{sub 3}. The spectral and temperature dependences of the coefficient of absorption of linearly polarized light in n-GaP are obtained with regard to the cone-shaped lower subband of the conduction band.

Perfect absorption in nanotextured thin films via Anderson-localized photon modes

Science.gov (United States)

Aeschlimann, Martin; Brixner, Tobias; Differt, Dominik; Heinzmann, Ulrich; Hensen, Matthias; Kramer, Christian; Lükermann, Florian; Melchior, Pascal; Pfeiffer, Walter; Piecuch, Martin; Schneider, Christian; Stiebig, Helmut; Strüber, Christian; Thielen, Philip

2015-10-01

The enhancement of light absorption in absorber layers is crucial in a number of applications, including photovoltaics and thermoelectrics. The efficient use of natural resources and physical constraints such as limited charge extraction in photovoltaic devices require thin but efficient absorbers. Among the many different strategies used, light diffraction and light localization at randomly nanotextured interfaces have been proposed to improve absorption. Although already exploited in commercial devices, the enhancement mechanism for devices with nanotextured interfaces is still subject to debate. Using coherent two-dimensional nanoscopy and coherent light scattering, we demonstrate the existence of localized photonic states in nanotextured amorphous silicon layers as used in commercial thin-film solar cells. Resonant absorption in these states accounts for the enhanced absorption in the long-wavelength cutoff region. Our observations establish that Anderson localization—that is, strong localization—is a highly efficient resonant absorption enhancement mechanism offering interesting opportunities for the design of efficient future absorber layers.

Determination of absorption changes from moments of distributions of times of flight of photons: optimization of measurement conditions for a two-layered tissue model.

Science.gov (United States)

Liebert, Adam; Wabnitz, Heidrun; Elster, Clemens

2012-05-01

Time-resolved near-infrared spectroscopy allows for depth-selective determination of absorption changes in the adult human head that facilitates separation between cerebral and extra-cerebral responses to brain activation. The aim of the present work is to analyze which combinations of moments of measured distributions of times of flight (DTOF) of photons and source-detector separations are optimal for the reconstruction of absorption changes in a two-layered tissue model corresponding to extra- and intra-cerebral compartments. To this end we calculated the standard deviations of the derived absorption changes in both layers by considering photon noise and a linear relation between the absorption changes and the DTOF moments. The results show that the standard deviation of the absorption change in the deeper (superficial) layer increases (decreases) with the thickness of the superficial layer. It is confirmed that for the deeper layer the use of higher moments, in particular the variance of the DTOF, leads to an improvement. For example, when measurements at four different source-detector separations between 8 and 35 mm are available and a realistic thickness of the upper layer of 12 mm is assumed, the inclusion of the change in mean time of flight, in addition to the change in attenuation, leads to a reduction of the standard deviation of the absorption change in the deeper tissue layer by a factor of 2.5. A reduction by another 4% can be achieved by additionally including the change in variance.

Integrated three-dimensional photonic nanostructures for achieving near-unity solar absorption and superhydrophobicity

Energy Technology Data Exchange (ETDEWEB)

Kuang, Ping; Lin, Shawn-Yu, E-mail: sylin@rpi.edu [The Future Chips Constellation and the Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, 110 8th Street, Troy, New York 12180 (United States); Hsieh, Mei-Li [Department of Photonics, National Chia-Tung University, Hsinchu, Taiwan (China)

2015-06-07

In this paper, we proposed and realized 3D photonic nanostructures consisting of ultra-thin graded index antireflective coatings (ARCs) and woodpile photonic crystals. The use of the integrated ARC and photonic crystal structure can achieve broadband, broad-angle near unity solar absorption. The amorphous silicon based photonic nanostructure experimentally shows an average absorption of ∼95% for λ = 400–620 nm over a wide angular acceptance of θ = 0°–60°. Theoretical studies show that a Gallium Arsenide (GaAs) based structure can achieve an average absorption of >95% for λ = 400–870 nm. Furthermore, the use of the slanted SiO{sub 2} nanorod ARC surface layer by glancing angle deposition exhibits Cassie-Baxter state wetting, and superhydrophobic surface is obtained with highest water contact angle θ{sub CB} ∼ 153°. These properties are fundamentally important for achieving maximum solar absorption and surface self-cleaning in thin film solar cell applications.

Boundary Layer of Photon Absorption Applied to Heterogeneous Photocatalytic Solar Flat Plate Reactor Design

Directory of Open Access Journals (Sweden)

Héctor L. Otálvaro-Marín

2014-01-01

Full Text Available This study provides information to design heterogeneous photocatalytic solar reactors with flat plate geometry used in treatment of effluents and conversion of biomass to hydrogen. The concept of boundary layer of photon absorption taking into account the efficient absorption of radiant energy was introduced; this concept can be understood as the reactor thickness measured from the irradiated surface where 99% of total energy is absorbed. Its thickness and the volumetric rate of photons absorption (VRPA were used as design parameters to determine (i reactor thickness, (ii maximum absorbed radiant energy, and (iii the optimal catalyst concentration. Six different commercial brands of titanium dioxide were studied: Evonik-Degussa P-25, Aldrich, Merck, Hombikat, Fluka, and Fisher. The local volumetric rate of photon absorption (LVRPA inside the reactor was described using six-flux absorption-scattering model (SFM applied to solar radiation. The radiation field and the boundary layer thickness of photon absorption were simulated with absorption and dispersion effects of catalysts in water at different catalyst loadings. The relationship between catalyst loading and reactor thickness that maximizes the absorption of radiant energy was obtained for each catalyst by apparent optical thickness. The optimum concentration of photocatalyst Degussa P-25 was 0.2 g/l in 0.86 cm of thickness, and for photocatalyst Aldrich it was 0.3 g/l in 0.80 cm of thickness.

Suppression of two-photon resonantly enhanced nonlinear processes in extended media

International Nuclear Information System (INIS)

Garrett, W.R.; Moore, M.A.; Payne, M.G.; Wunderlich, R.K.

1988-11-01

On the basis of combined experimental and theoretical studies of nonlinear processes associated with two-photon excitations near 3d and 4d states in Na, we show how resonantly enhanced stimulated hyper-Raman emission, parametric four-wave mixing processes and total resonant two-photon absorption can become severely suppressed through the actions of internally generated fields on the total atomic response in extended media. 7 refs., 3 figs

Non-scanning fiber-optic near-infrared beam led to two-photon optogenetic stimulation in-vivo.

Directory of Open Access Journals (Sweden)

Kamal R Dhakal

Full Text Available Stimulation of specific neurons expressing opsins in a targeted region to manipulate brain function has proved to be a powerful tool in neuroscience. However, the use of visible light for optogenetic stimulation is invasive due to low penetration depth and tissue damage owing to larger absorption and scattering. Here, we report, for the first time, in-depth non-scanning fiber-optic two-photon optogenetic stimulation (FO-TPOS of neurons in-vivo in transgenic mouse models. In order to optimize the deep-brain stimulation strategy, we characterized two-photon activation efficacy at different near-infrared laser parameters. The significantly-enhanced in-depth stimulation efficiency of FO-TPOS as compared to conventional single-photon beam was demonstrated both by experiments and Monte Carlo simulation. The non-scanning FO-TPOS technology will lead to better understanding of the in-vivo neural circuitry because this technology permits more precise and less invasive anatomical delivery of stimulation.

One, two or three-nucleon photo- absorption in 3He

International Nuclear Information System (INIS)

Tamas, G.

1986-08-01

Pion production and photodisintegration of 3 He are studied in the δ resonance region to try to separate the various photon absorption mechanism by one, two or three nucleons. The results are compared to the existing models

Time evolution of absorption process in nonlinear metallic photonic crystals

Energy Technology Data Exchange (ETDEWEB)

Singh, Mahi R.; Hatef, Ali [Department of Physics and Astronomy, University of Western Ontario, London (Canada)

2009-05-15

The time evolution of the absorption coefficient in metallic photonic crystals has been studied numerically. These crystals are made from metallic spheres which are arranged periodically in air. The refractive index of the metallic spheres depends on the plasma frequency. Probe and pump fields are applied to monitor the absorption process. Ensembles of three-level particles are embedded in the crystal. Nanoparticles are interacting with the metallic crystals via the electron-photon interaction. It is found that when the resonance states lie away from the band edges system goes to transparent state. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Two- and three-photon excitation of Gd3+ in CaAl12O19

International Nuclear Information System (INIS)

Heerdt, M.L.H. ter; Basun, S.A.; Imbusch, G.F.; Yen, W.M.

2002-01-01

We have employed two-photon excitation to study the higher energy levels of Gd 3+ ions in CaAl 12 O 19 and we compare the results with those obtained using conventional UV excitation techniques. Under two-photon excitation, the luminescence intensity exhibits an unusual temporal behavior, a very long build-up followed by a decrease by orders of magnitude, ascribed to a recombination-assisted luminescence excitation mechanism assuming photo-ionization of Gd 3+ ions and trapping of free electrons on deep traps. We also find that the two-photon excitation spectra contain an additional broadening contribution which can be attributed to homogeneous broadening of excitation levels caused by excited state absorption into the conduction band. We believe that this may be a general phenomenon whenever participating photons produce ionization of impurity ions from metastable excited states. The phenomenon can manifest itself also in two-photon ionization spectral hole burning and in up-conversion processes (in the latter case, the homogeneous broadening can be caused by an intra-ion excited-state absorption)

Measurement of polarization dependence of two-photon absorption coefficient in InP using extended Z-scan technique for thick materials

Science.gov (United States)

Oishi, Masaki; Shinozaki, Tomohisa; Hara, Hikaru; Yamamoto, Kazunuki; Matsusue, Toshio; Bando, Hiroyuki

2018-03-01

The two-photon absorption coefficient β in InP has been measured in the wavelength range of 1640 to 1800 nm by the Z-scan technique in relatively thick materials. The values of β have been evaluated from the fit to the equation including the spatial and temporal profiles of the focused Gaussian beam. The polarization dependence of β has also been measured. The dependence has been expressed very well by the expression of β with the imaginary part of the third-order nonlinear susceptibility tensor χ(3).

Effects of two-photon absorption on all optical logic operation based on quantum-dot semiconductor optical amplifiers

Science.gov (United States)

Zhang, Xiang; Dutta, Niloy K.

2018-01-01

We investigate all-optical logic operation in quantum-dot semiconductor optical amplifier (QD-SOA) based Mach-Zehnder interferometer considering the effects of two-photon absorption (TPA). TPA occurs during the propagation of sub-picosecond pulses in QD-SOA, which leads to a change in carrier recovery dynamics in quantum-dots. We utilize a rate equation model to take into account carrier refill through TPA and nonlinear dynamics including carrier heating and spectral hole burning in the QD-SOA. The simulation results show the TPA-induced pumping in the QD-SOA can reduce the pattern effect and increase the output quality of the all-optical logic operation. With TPA, this scheme is suitable for high-speed Boolean logic operation at 320 Gb/s.

Characterization of scintillating CaWO{sub 4} crystals for the CRESST experiment using two-photon excitation

Energy Technology Data Exchange (ETDEWEB)

Hampf, Raphael; Dandl, Thomas; Muenster, Andrea; Oberauer, Lothar; Roth, Sabine; Schoenert, Stefan; Ulrich, Andreas [Physik-Department and Excellence Cluster Universe, Technische Universitaet Muenchen, D-85747 Garching (Germany)

2016-07-01

In the CRESST experiment for direct dark matter search, phonon and photon signals from cryogenic CaWO{sub 4} crystals are used to search for WIMP-induced nuclear recoil events. We present a novel table-top setup in which the scintillation of CaWO{sub 4} is induced by 0.7 ns laser pulses of 355 nm wavelength. The excitation occurs via two-photon absorption in the bulk material. The scintillation light is observed by time resolved optical spectroscopy. By varying the focusing of the laser-beam the excitation density can be made high enough to study quenching effects due to exciton-exciton annihilation. This allows to perform experiments to test models for the quenching factors of different ionizing projectiles in CaWO{sub 4} which are used to identify these projectiles on an event by event basis.

A new approach to dual-color two-photon microscopy with fluorescent proteins

Directory of Open Access Journals (Sweden)

Rebane Aleks

2010-02-01

Full Text Available Abstract Background Two-photon dual-color imaging of tissues and cells labeled with fluorescent proteins (FPs is challenging because most two-photon microscopes only provide one laser excitation wavelength at a time. At present, methods for two-photon dual-color imaging are limited due to the requirement of large differences in Stokes shifts between the FPs used and their low two-photon absorption (2PA efficiency. Results Here we present a new method of dual-color two-photon microscopy that uses the simultaneous excitation of the lowest-energy electronic transition of a blue fluorescent protein and a higher-energy electronic transition of a red fluorescent protein. Conclusion Our method does not require large differences in Stokes shifts and can be extended to a variety of FP pairs with larger 2PA efficiency and more optimal imaging properties.

A Successful Attempt to Obtain the Linear Dependence Between One-Photon and Two-Photon Spectral Properties and Hammett Parameters of Various Aromatic Substituents in New π-Extended Asymmetric Organic Chromophores.

Science.gov (United States)

Hu, Nvdan; Gong, Yulong; Wang, Xinchao; Lu, Yao; Peng, Guangyue; Yang, Long; Zhang, Shengtao; Luo, Ziping; Li, Hongru; Gao, Fang

2015-11-01

A series of new asymmetric chromophores containing aromatic substituents and possessing the excellent π-extension in space were prepared through multi-steps routes. One-photon and two-photon spectral properties of these new chromophores could be tuned by these substituents finely and simultaneously. The linear correlation of the wave numbers of the one-photon absorption and emission maxima to Hammett parameters of these substituents was presented. Near infrared two-photon absorption emission integrated areas of the target chromophores were correlated linearly to Hammett constants of these substituted groups.

Two-Photon Pumped Synchronously Mode-Locked Bulk GaAs Laser

Science.gov (United States)

Cao, W. L.; Vaucher, A. M.; Ling, J. D.; Lee, C. H.

1982-04-01

Pulses 7 picoseconds or less in duration have been generated from a bulk GaAs crystal by a synchronous mode-locking technique. The GaAs crystal was optically pumped by two-photon absorption of the emission from a mode-locked Nd:glass laser. Two-photon absorption as the means of excitation increases the volume of the gain medium by increasing the pene-tration depth of the pump intensity, enabling generation of intra-cavity pulses with peak power in the megawatt range. Tuning of the wavelength of the GaAs emission is achieved by varying the temperature. A tuning range covering 840 nm to 885 nm has been observed over a temperature range from 97°K to 260°K. The intensity of the GaAs emission has also been observed to decrease as the temperature of the crystal is increased.

Backscattering of 59.54 keV photons for characterization of metallic elements

International Nuclear Information System (INIS)

Elyaseery, I.S.; Chong Chon Sing; Ahmad Shukri Mustapa Kamal; Abdul Aziz Tajuddin

2000-01-01

Scattering measurements of x-rays and gamma rays have been developed for the characterization of internal features of materials such as density or composition. Previous studies were generally carried at small scattering angles. In this paper, a system is described for preliminary studies of back scattering of photons for characterization of materials. The apparatus consist of an annular 100 mCi 241 Am source and a high purity thin intensities for the 59.54 keV photons are presented for different metallic elements such as Al, Cu, Zn, Zr, Nb, Mo, Ag, Cd, In, Sn, Ta and W. The measurements were carried out at back scattering angles of 145 0 , 154 0 , 165 0 . Coherent peak measurements offer greater sensitivity than Compton peak measurements. In particular, the 59.54 keV coherent peak intensity shows a proportional increase with increasing Z number elements except for the elements Ta and W whose absorption edges are in the vicinity of this photon energy. The experimental results demonstrate the feasibility of the backscattering method for the characterization of metallic elements. (Author)

Frequency up-shift in the stimulated thermal scattering under two-photon absorption in liquids and colloids of metal nanoparticles

Science.gov (United States)

Smetanin, I. V.; Erokhin, A. I.; Baranov, A. N.

2018-07-01

We report the results of the experimental and theoretical study of stimulated temperature scattering in toluene and hexane solutions of Ag-nanoparticles, as well as in pure toluene in the two-photon absorption regime. A four-wave mixing scheme with two counter-propagating pump waves of the same frequency is utilised to demonstrate the lasing effect and the amplification of the backscattered anti-Stokes signal. For the first time, we have measured anti-Stokes spectral shifts which turn out to appreciably exceed the Rayleigh line widths in those liquids. It is shown that the amplification effect is provided predominantly by thermally induced coherent polarisation oscillations, while the dynamic interference temperature grating causes the formation of a self-induced optical cavity inside the interaction region.

Dynamical modeling of pulsed two-photon interference

International Nuclear Information System (INIS)

Fischer, Kevin A; Lagoudakis, Konstantinos G; Vučković, Jelena; Müller, Kai

2016-01-01

Single-photon sources are at the heart of quantum-optical networks, with their uniquely quantum emission and phenomenon of two-photon interference allowing for the generation and transfer of nonclassical states. Although a few analytical methods have been briefly investigated for describing pulsed single-photon sources, these methods apply only to either perfectly ideal or at least extremely idealized sources. Here, we present the first complete picture of pulsed single-photon sources by elaborating how to numerically and fully characterize non-ideal single-photon sources operating in a pulsed regime. In order to achieve this result, we make the connection between quantum Monte-Carlo simulations, experimental characterizations, and an extended form of the quantum regression theorem. We elaborate on how an ideal pulsed single-photon source is connected to its photocount distribution and its measured degree of second- and first-order optical coherence. By doing so, we provide a description of the relationship between instantaneous source correlations and the typical experimental interferometers (Hanbury-Brown and Twiss, Hong–Ou–Mandel, and Mach–Zehnder) used to characterize such sources. Then, we use these techniques to explore several prototypical quantum systems and their non-ideal behaviors. As an example numerical result, we show that for the most popular single-photon source—a resonantly excited two-level system—its error probability is directly related to its excitation pulse length. We believe that the intuition gained from these representative systems and characters can be used to interpret future results with more complicated source Hamiltonians and behaviors. Finally, we have thoroughly documented our simulation methods with contributions to the Quantum Optics Toolbox in Python in order to make our work easily accessible to other scientists and engineers. (paper)

Fano resonance in the absorption of two photons in crystal defects. Ressonancia de Fano na absorcao de dois fotons em defeitos cristalinos

Energy Technology Data Exchange (ETDEWEB)

Souza, G P

1984-01-01

The absorption of two photons in the electronic transition within the 4f/sup 7/ configuration which is superposed to the vibronic structure of the 4f/sup 7/ - 4f/sup 6/5d transition, is studied. The line shape with the Fano's formalism is described. The study was carried out on Eu/sup +2/ doped CaF/sub 2/. The experimental apparatus was built and the results obtained are in good agreement with the theoretical predictions.

Effects of conjugation length and resonance enhancement on two-photon absorption in phenylene–vinylene oligomers

DEFF Research Database (Denmark)

Johnsen, Mette; Paterson, M.J.; Arnbjerg, J.

2008-01-01

. This phenomenon of the so-called resonance enhancement allows for greater control in obtaining an optimal response when using existing two-photon chromophores, and provides a much-needed guide for the systematic development and efficient use of two-photon singlet oxygen sensitizers....

Pulse-bandwidth dependence of coherent phase control of resonance-mediated (2+1) three-photon absorption

International Nuclear Information System (INIS)

Gandman, Andrey; Chuntonov, Lev; Rybak, Leonid; Amitay, Zohar

2007-01-01

We study in detail coherent phase control of femtosecond resonance-mediated (2+1) three-photon absorption and its dependence on the spectral bandwidth of the excitation pulse. The regime is the weak-field regime of third perturbative order. The corresponding interference mechanism involves a group of three-photon excitation pathways that are on resonance with the intermediate state and a group of three-photon excitation pathways that are near resonant with it. The model system of the study is atomic sodium (Na), for which experimental and numerical-theoretical results are obtained. Prominent among the results is our finding that with simple proper pulse shaping an increase in the excitation bandwidth leads to a corresponding increase in the enhancement of the three-photon absorption over the absorption induced by the (unshaped) transform-limited pulse. For example, here, a 40 nm bandwidth leads to an order-of-magnitude enhancement over the transform-limited absorption

Phonon-assisted two-photon exciton transitions in semiconductors

International Nuclear Information System (INIS)

Hassan, A.R.

1987-08-01

The theory of phonon-assisted two-photon transitions to excitonic states in semiconductors has been theoretically investigated. The effects of both the nonparabolicity of the band and the degeneracy of the valence band have been taken into account. Expressions for the absorption coefficient through different band models are calculated. The numerical applications to CdI 2 and GaP show that the 4-band model gives the dominant contribution which leads to a final s-exciton state. An exciton peak appears at an energy which is close to that recently observed in CdI 2 . The non-parabolic effect enhances the absorption coefficient by a two-order of magnitude. (author). 6 refs, 1 fig., 1 tab

Effect of loss on slow-light enhanced absorption in liquid-infiltrated photonic crystals

DEFF Research Database (Denmark)

Pedersen, Jesper Goor; Xiao, Sanshui; Mortensen, Asger

2008-01-01

We study slow-light enhancement of absorption measurements in photonic crystals composed of lossy dielectrics. We find that the material loss has an unexpected limited drawback and may even increase the bandwidth for low-index contrast systems.......We study slow-light enhancement of absorption measurements in photonic crystals composed of lossy dielectrics. We find that the material loss has an unexpected limited drawback and may even increase the bandwidth for low-index contrast systems....

A bistriphenylamine-substituted spirobifluorene derivative exhibiting excellent nonlinearity/transparency/thermal stability trade-off and strong two-photon induced blue fluorescence

International Nuclear Information System (INIS)

Yin, Hongyao; Xiao, Haibo; Ding, Lei; Zhang, Chun; Ren, Aiming; Li, Bo

2015-01-01

A spirobifluorene-bridged donor/donor chromophore, 2,7-bis-(4-(N,N-diphenylamino)phen-1-yl)-9,9′-spirobifluorene (SPF-TP), was found to combine excellent transparency in the near UV–visible region (λ cut-off  ≤ 420 nm), large two-photon absorption cross-section (4.5 × 10 3 GM) and high thermal stability (T d  = 501 °C). In comparison to the reported two-photon absorption molecules, SPF-TP represents the best thermal stability so far described in the literature. The main electronic factors explaining the high two-photon absorption activities of SPF-TP were analyzed by theoretical calculations. Cyclic voltammograms were employed to explore the causes of the excellent transparency of SPF-TP. It was found that the spiroconjugation effect is responsible for the excellent nonlinearity/transparency/thermal stability trade-off in SPF-TP. In addition, SPF-TP is also a good two-photon induced blue fluorescent material with high fluorescence quantum yield (Φ = 0.90, in THF). - Highlights: • We report a molecule exhibiting excellent transparency. • The two-photon absorption cross-section is as large as 4.5 × 10 3 GM. • The molecule exhibits excellent thermal stability. • The molecule is a good two-photon induced blue fluorescent material. • The spiroconjugation effect explains the excellent properties

A bistriphenylamine-substituted spirobifluorene derivative exhibiting excellent nonlinearity/transparency/thermal stability trade-off and strong two-photon induced blue fluorescence

Energy Technology Data Exchange (ETDEWEB)

Yin, Hongyao [Department of Chemistry, Shanghai Normal University, Shanghai 200234 (China); Xiao, Haibo, E-mail: xiaohb@shnu.edu.cn [Department of Chemistry, Shanghai Normal University, Shanghai 200234 (China); Ding, Lei [Department of Chemistry, Shanghai Normal University, Shanghai 200234 (China); Zhang, Chun; Ren, Aiming [State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130023 (China); Li, Bo [Key Laboratory of Polar Materials and Devices, Ministry of Education, East China Normal University, Shanghai 200241 (China)

2015-02-01

A spirobifluorene-bridged donor/donor chromophore, 2,7-bis-(4-(N,N-diphenylamino)phen-1-yl)-9,9′-spirobifluorene (SPF-TP), was found to combine excellent transparency in the near UV–visible region (λ{sub cut-off} ≤ 420 nm), large two-photon absorption cross-section (4.5 × 10{sup 3}GM) and high thermal stability (T{sub d} = 501 °C). In comparison to the reported two-photon absorption molecules, SPF-TP represents the best thermal stability so far described in the literature. The main electronic factors explaining the high two-photon absorption activities of SPF-TP were analyzed by theoretical calculations. Cyclic voltammograms were employed to explore the causes of the excellent transparency of SPF-TP. It was found that the spiroconjugation effect is responsible for the excellent nonlinearity/transparency/thermal stability trade-off in SPF-TP. In addition, SPF-TP is also a good two-photon induced blue fluorescent material with high fluorescence quantum yield (Φ = 0.90, in THF). - Highlights: • We report a molecule exhibiting excellent transparency. • The two-photon absorption cross-section is as large as 4.5 × 10{sup 3}GM. • The molecule exhibits excellent thermal stability. • The molecule is a good two-photon induced blue fluorescent material. • The spiroconjugation effect explains the excellent properties.

Engineering Photon-Photon Interactions within Rubidium-Filled Waveguides

Science.gov (United States)

Perrella, C.; Light, P. S.; Vahid, S. Afshar; Benabid, F.; Luiten, A. N.

2018-04-01

Strong photon-photon interactions are a required ingredient for deterministic two-photon optical quantum logic gates. Multiphoton transitions in dense atomic vapors have been shown to be a promising avenue for producing such interactions. The strength of a multiphoton interaction can be enhanced by conducting the interaction in highly confined geometries such as small-cross-section optical waveguides. We demonstrate, both experimentally and theoretically, that the strength of such interactions scale only with the optical mode diameter, d , not d2 as might be initially expected. This weakening of the interaction arises from atomic motion inside the waveguides. We create an interaction between two optical signals, at 780 and 776 nm, using the 5 S1 /2→5 D5 /2 two-photon transition in rubidium vapor within a range of hollow-core fibers with different core sizes. The interaction strength is characterized by observing the absorption and phase shift induced on the 780-nm beam, which is in close agreement with theoretical modeling that accounts for the atomic motion inside the fibers. These observations demonstrate that transit-time effects upon multiphoton transitions are of key importance when engineering photon-photon interactions within small-cross-section waveguides that might otherwise be thought to lead to enhanced optical nonlinearity through increased intensities.

Studies of photoionization in liquids using a laser two-photon ionization conductivity technique

International Nuclear Information System (INIS)

Siomos, K.; Christophorou, L.G.

1981-01-01

One-photon ionization studies of solute molecules in a liquid medium are limited by the absorption of the host medium. A laser two-photon ionization (TPI) technique using a frequency tunable dye laser has been developed, whereby the photoionization threshold of a solute molecule was determined from the induced conductivity in the liquid medium under study due to electron-ion pair formation via two-photon ionization of the solute. The two-photon induced electron-ion current is measured as a function of the laser wavelength, lambda/sub laser/. In this paper, results are reported and discussed on the photoionization of N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD), pyrene and fluoranthene in liquid n-pentane

Can Two-Photon Interference be Considered the Interference of Two Photons?

International Nuclear Information System (INIS)

Pittman, T.B.; Strekalov, D.V.; Migdall, A.; Rubin, M.H.; Sergienko, A.V.; Shih, Y.H.

1996-01-01

We report on a open-quote open-quote postponed compensation close-quote close-quote experiment in which the observed two-photon entangled state interference cannot be pictured in terms of the overlap of the two individual photon wave packets of a parametric down-conversion pair on a beam splitter. In the sense of a quantum eraser, the distinguishability of the different two-photon Feynman amplitudes leading to a coincidence detection is removed by delaying the compensation until after the output of an unbalanced two-photon interferometer. copyright 1996 The American Physical Society

NIR-emitting molecular-based nanoparticles as new two-photon absorbing nanotools for single particle tracking

Science.gov (United States)

Daniel, J.; Godin, A. G.; Clermont, G.; Lounis, B.; Cognet, L.; Blanchard-Desce, M.

2015-07-01

In order to provide a green alternative to QDs for bioimaging purposes and aiming at designing bright nanoparticles combining both large one- and two-photon brightness, a bottom-up route based on the molecular engineering of dedicated red to NIR emitting dyes that spontaneously form fluorescent organic nanoparticles (FONs) has been implemented. These fully organic nanoparticles built from original quadrupolar dyes are prepared using a simple, expeditious and green protocol that yield very small molecular-based nanoparticles (radius ~ 7 nm) suspension in water showing a nice NIR emission (λem=710 nm). These FONs typically have absorption coefficient more than two orders larger than popular NIR-emitting dyes (such as Alexa Fluor 700, Cy5.5 ….) and much larger Stokes shift values (i.e. up to over 5500 cm-1). They also show very large two-photon absorption response in the 800-1050 nm region (up to about 106 GM) of major promise for two-photon excited fluorescence microscopy. Thanks to their brightness and enhanced photostability, these FONs could be imaged as isolated nanoparticles and tracked using wide-field imaging. As such, thanks to their size and composition (absence of heavy metals), they represent highly promising alternatives to NIR-emitting QDs for use in bioimaging and single particle tracking applications. Moreover, efficient FONs coating was achieved by using a polymeric additive built from a long hydrophobic (PPO) and a short hydrophilic (PEO) segment and having a cationic head group able to interact with the highly negative surface of FONs. This electrostatically-driven interaction promotes both photoluminescence and two-photon absorption enhancement leading to an increase of two-photon brightness of about one order of magnitude. This opens the way to wide-field single particle tracking under two-photon excitation

Resonant metallic nanostructure for enhanced two-photon absorption in a thin GaAs p-i-n diode

Energy Technology Data Exchange (ETDEWEB)

Portier, Benjamin; Pardo, Fabrice; Péré-Laperne, Nicolas; Steveler, Emilie; Dupuis, Christophe; Bardou, Nathalie; Lemaître, Aristide; Pelouard, Jean-Luc, E-mail: jean-luc.pelouard@lpn.cnrs.fr [Laboratoire de Photonique et de Nanostructures (LPN-CNRS), Route de Nozay, 91460 Marcoussis (France); Vest, Benjamin; Jaeck, Julien; Rosencher, Emmanuel [ONERA The French Aerospace Lab, Chemin de la Hunière, F-91760 Palaiseau (France); Haïdar, Riad [ONERA The French Aerospace Lab, Chemin de la Hunière, F-91760 Palaiseau (France); École Polytechnique, Département de Physique, F-91128 Palaiseau (France)

2014-07-07

Degenerate two-photon absorption (TPA) is investigated in a 186 nm thick gallium arsenide (GaAs) p-i-n diode embedded in a resonant metallic nanostructure. The full device consists in the GaAs layer, a gold subwavelength grating on the illuminated side, and a gold mirror on the opposite side. For TM-polarized light, the structure exhibits a resonance close to 1.47 μm, with a confined electric field in the intrinsic region, far from the metallic interfaces. A 109 times increase in photocurrent compared to a non-resonant device is obtained experimentally, while numerical simulations suggest that both gain in TPA-photocurrent and angular dependence can be further improved. For optimized grating parameters, a maximum gain of 241 is demonstrated numerically and over incidence angle range of (−30°; +30°).

Resonant metallic nanostructure for enhanced two-photon absorption in a thin GaAs p-i-n diode

International Nuclear Information System (INIS)

Portier, Benjamin; Pardo, Fabrice; Péré-Laperne, Nicolas; Steveler, Emilie; Dupuis, Christophe; Bardou, Nathalie; Lemaître, Aristide; Pelouard, Jean-Luc; Vest, Benjamin; Jaeck, Julien; Rosencher, Emmanuel; Haïdar, Riad

2014-01-01

Degenerate two-photon absorption (TPA) is investigated in a 186 nm thick gallium arsenide (GaAs) p-i-n diode embedded in a resonant metallic nanostructure. The full device consists in the GaAs layer, a gold subwavelength grating on the illuminated side, and a gold mirror on the opposite side. For TM-polarized light, the structure exhibits a resonance close to 1.47 μm, with a confined electric field in the intrinsic region, far from the metallic interfaces. A 109 times increase in photocurrent compared to a non-resonant device is obtained experimentally, while numerical simulations suggest that both gain in TPA-photocurrent and angular dependence can be further improved. For optimized grating parameters, a maximum gain of 241 is demonstrated numerically and over incidence angle range of (−30°; +30°).

Enhancement of two photon absorption with Ni doping in the dilute magnetic semiconductor ZnO crystalline nanorods

Energy Technology Data Exchange (ETDEWEB)

Rana, Amit Kumar; Kumar, Yogendra; Arjunan, M.S.; Sen, Somaditya; Shirage, Parasharam M., E-mail: pmshirage@iiti.ac.in, E-mail: paras.shirage@gmail.com [Department of Physics, Indian Institute of Technology Indore, Simrol Campus, Khandwa Road, Indore 452020 (India); Centre of Materials Science and Engineering, Indian Institute of Technology Indore, Simrol Campus, Khandwa Road, Indore 452020 (India); J, Aneesh; Adarsh, K. V. [Department of Physics, Indian Institute of Science Education and Research, Bhopal 462023 (India)

2015-12-07

In this letter, we have investigated the third-order optical nonlinearities of high-quality Ni doped ZnO nanorods crystallized in wurtzite lattice, prepared by the wet chemical method. In our experiments, we found that the two photon absorption coefficient (β) increases by as much as 14 times, i.e., 7.6 ± 0.4 to 112 ± 6 cm/GW, when the Ni doping is increased from 0% to 10%. The substantial enhancement in β is discussed in terms of the bandgap scaling and Ni doping. Furthermore, we also show that the optical bandgap measured by UV-Vis and photoluminescence spectroscopies, continuously redshift with increasing Ni doping concentration. We envision that the strong nonlinear optical properties together with their dilute magnetic effects, they form an important class of materials for potential applications in magneto-optical and integrated optical chips.

Enhancement of two photon absorption with Ni doping in the dilute magnetic semiconductor ZnO crystalline nanorods

International Nuclear Information System (INIS)

Rana, Amit Kumar; Kumar, Yogendra; Arjunan, M.S.; Sen, Somaditya; Shirage, Parasharam M.; J, Aneesh; Adarsh, K. V.

2015-01-01

In this letter, we have investigated the third-order optical nonlinearities of high-quality Ni doped ZnO nanorods crystallized in wurtzite lattice, prepared by the wet chemical method. In our experiments, we found that the two photon absorption coefficient (β) increases by as much as 14 times, i.e., 7.6 ± 0.4 to 112 ± 6 cm/GW, when the Ni doping is increased from 0% to 10%. The substantial enhancement in β is discussed in terms of the bandgap scaling and Ni doping. Furthermore, we also show that the optical bandgap measured by UV-Vis and photoluminescence spectroscopies, continuously redshift with increasing Ni doping concentration. We envision that the strong nonlinear optical properties together with their dilute magnetic effects, they form an important class of materials for potential applications in magneto-optical and integrated optical chips

Radiobiological Characterization of Two Photon-Beam Energies 6 and 15 MV used in Radiotherapy From Linear Accelerator

International Nuclear Information System (INIS)

Eltayeb, A.E.H.

2009-02-01

The main objective of this study is to perform radiobiological characterization of two different photon beam energies, 6 MV and 15 MV, from linear accelerator used in radiotherapy, with special regard to late effects of radiation. Two end-points, namely cell survival and micronucleus induction were used for the characterization. Chinese hamster V 79 lung fibroblast cell line to prepare cell culture and to perform the innervate experiments. chromosomes number was counted and found to be 22 chromosomes per cell, this result is in complete agreement with expected 11 pairs of chromosomes representing the genome of this species. Cells were kept in confluent growth for two days and then exposed to two photon beam energies, 6 and 15 MV respectively. Different dose rates were used for the two beam energies, 0.25, 0.5, 1.0, 2.0, 4.0, 7.0 Gy. Cells were counted immediately after irradiation and re seeded, the seeded number of cells was calculated to the dose rate used. Another set of unirradiated cells treated the same as the experimental set was used as a control group. The plating efficiency (PE) was calculated for the control group, then cells were incubated at 37 o C for 6 days to construct the survival curve, five samples were counted per dose and the mean was calculated. The two survival curves are similar for photon beam energies (6 and 15 MV) and the surviving fraction was decreased with dose rate. The two curves showed similar values of α and β parameters, this result is expected for the same radiation type (X-ray). For the micronuclei assay three samples for each dose were seeded and incubated at 37 o C for 24 hours then Cytochalasin-B was added to block cells in cytokinesis phase of the mitosis. The micronuclei number was counted and plotted with dose. A significant positive correlation was found between dose and micronuclei frequency (P=0.00), moreover, the micronuclei frequency is relatively higher with 15 MV compared with 6 MV energy. This indicates the

Electron Correlations and Two-Photon States in Polycyclic Aromatic Hydrocarbon Molecules: A Peculiar Role of Geometry

OpenAIRE

Aryanpour, K.; Shukla, A.; Mazumdar, S.

2013-01-01

We present numerical studies of one- and two-photon excited states ordering in a number of polycyclic aromatic hydrocarbon molecules: coronene, hexa-peri-hexabenzocoronene and circumcoronene, all possessing $D_{6h}$ point group symmetry versus ovalene with $D_{2h}$ symmetry, within the Pariser-Parr-Pople model of interacting $\\pi$-electrons. The calculated energies of the two-photon states as well as their relative two-photon absorption cross-sections within the interacting model are qualitat...

Two-photon physics

International Nuclear Information System (INIS)

Bardeen, W.A.

1981-10-01

A new experimental frontier has recently been opened to the study of two photon processes. The first results of many aspects of these reactions are being presented at this conference. In contrast, the theoretical development of research ito two photon processes has a much longer history. This talk reviews the many different theoretical ideas which provide a detailed framework for our understanding of two photon processes

Optical nonlinearities of colloidal InP@ZnS core-shell quantum dots probed by Z-scan and two-photon excited emission

International Nuclear Information System (INIS)

Wawrzynczyk, Dominika; Szeremeta, Janusz; Samoc, Marek; Nyk, Marcin

2015-01-01

Spectrally resolved nonlinear optical properties of colloidal InP@ZnS core-shell quantum dots of various sizes were investigated with the Z-scan technique and two-photon fluorescence excitation method using a femtosecond laser system tunable in the range from 750 nm to 1600 nm. In principle, both techniques should provide comparable results and can be interchangeably used for determination of the nonlinear optical absorption parameters, finding maximal values of the cross sections and optimizing them. We have observed slight differences between the two-photon absorption cross sections measured by the two techniques and attributed them to the presence of non-radiative paths of absorption or relaxation. The most significant value of two-photon absorption cross section σ 2 for 4.3 nm size InP@ZnS quantum dot was equal to 2200 GM, while the two-photon excitation action cross section σ 2 Φ was found to be 682 GM at 880 nm. The properties of these cadmium-free colloidal quantum dots can be potentially useful for nonlinear bioimaging

Printed organic smart devices characterized by nonlinear optical

DEFF Research Database (Denmark)

Pastorelli, Francesco; Accanto, Nicolo; Jørgensen, Mikkel

2017-01-01

In this study, we demonstrate that nonlinear optical microscopy is a promising technique to characterize organic printed electronics. Using ultrashort laser pulses we stimulate two-photon absorption in a roll coated polymer semiconductor and map the resulting two-photon induced photoluminescence...

Fluorenyl benzothiadiazole and benzoselenadiazole near-IR fluorescent probes for two-photon fluorescence imaging (Conference Presentation)

Science.gov (United States)

Belfield, Kevin D.; Yao, Sheng; Kim, Bosung; Yue, Xiling

2016-03-01

Imaging biological samples with two-photon fluorescence (2PF) microscopy has the unique advantage of resulting high contrast 3D resolution subcellular image that can reach up to several millimeters depth. 2PF probes that absorb and emit at near IR region need to be developed. Two-photon excitation (2PE) wavelengths are less concerned as 2PE uses wavelengths doubles the absorption wavelength of the probe, which means 2PE wavelengths for probes even with absorption at visible wavelength will fall into NIR region. Therefore, probes that fluoresce at near IR region with high quantum yields are needed. A series of dyes based on 5-thienyl-2, 1, 3-benzothiadiazole and 5-thienyl-2, 1, 3-benzoselenadiazole core were synthesized as near infrared two-photon fluorophores. Fluorescence maxima wavelengths as long as 714 nm and fluorescence quantum yields as high as 0.67 were achieved. The fluorescence quantum yields of the dyes were nearly constant, regardless of solvents polarity. These diazoles exhibited large Stokes shift (GM), and high two-photon fluorescence figure of merit (FM , 1.04×10-2 GM). Cells incubated on a 3D scaffold with one of the new probes (encapsulated in Pluronic micelles) exhibited bright fluorescence, enabling 3D two-photon fluorescence imaging to a depth of 100 µm.

Two-Photon Absorption Properties of Gold Fluorescent Protein: A Combined Molecular Dynamics and Quantum Chemistry Study.

Science.gov (United States)

Simsek, Yusuf; Brown, Alex

2018-05-09

Molecular dynamic (MD) simulations were carried out to obtain the conformational changes of the chromophore in the gold fluorescent protein (PDB ID: 1OXF). To obtain two-photon absorption (TPA) cross-sections, time dependent density functional theory (TD-DFT) computations were performed for chromophore geometries sampled along the trajectory. The TD-DFT computations used the CAM-B3LYP functional and 6-31+G(d) basis set with the conductor-like polarizable continuum model (PCM) with parameters for water. Results showed that two dihedral angles change remarkably over the simulation time. TPA cross-sections were found to average 20 GM for the excitation to S1 between 430 and 460 nm; however, the maximal and minimal values were 35GM and 5GM, respectively. Besides the effects of the dihedrals on the spectroscopic properties, some bond lengths affected the excitation energies and the TPA cross-sections significantly (up to ±25-30%) while the effects of bond angles were smaller (±5%). Overall the present results provide insight in the effects of conformational exibility on TPA (with gold fluorescent protein as a specific example) and suggest that further experimental measurements of TPA for gold fluorescent protein should be undertaken.

Active Photonic crystal fibers for high power applications

DEFF Research Database (Denmark)

Olausson, Christina Bjarnal Thulin

The photonic crystal ber technology provides means to realize bers optimized for high power operation, due to the large single-mode cores and the unique design exibility of the microstructure. The work presented in this thesis focuses on improving the properties of active photonic crystal bers...... contributed to the compounding of new and improved material compositions. The second part is an investigation of pump absorption in photonic crystal bers, demonstrating that the microstructure in photonic crystal bers improves the pump absorption by up to a factor of two compared to step-index bers....... This plays an important role in high power lasers and ampliers with respect to efficiency, packaging, and thermal handling. The third part of the work has involved developing tools for characterizing the mode quality and stability of large core bers. Stable, single-mode bers with larger cores are essential...

Zak phase induced multiband waveguide by two-dimensional photonic crystals.

Science.gov (United States)

Yang, Yuting; Xu, Tao; Xu, Yun Fei; Hang, Zhi Hong

2017-08-15

Interface states in photonic crystals provide efficient approaches to control the flow of light. Photonic Zak phase determines the bulk band properties of photonic crystals, and, by assembling two photonic crystals with different bulk band properties together, deterministic interface states can be realized. By translating each unit cell of a photonic crystal by half the lattice constant, another photonic crystal with identical common gaps but a different Zak phase at each photonic band can be created. By assembling these two photonic crystals together, multiband waveguide can thus be easily created and then experimentally characterized. Our experimental results have good agreement with numerical simulations, and the propagation properties of these measured interface states indicate that this new type of interface state will be a good candidate for future applications of optical communications.

Two-photon Microscopy and Polarimetry for Assessment of Myocardial Tissue Organization

Science.gov (United States)

Archambault-Wallenburg, Marika

Optical methods can provide useful tissue characterization tools. For this project, two-photon microscopy and polarized light examinations (polarimetry) were used to assess the organizational state of myocardium in healthy, infarcted, and stem-cell regenerated states. Two-photon microscopy visualizes collagen through second-harmonic generation and myocytes through two-photon excitation autofluorescence, providing information on the composition and structure/organization of the tissue. Polarimetry measurements yield a value of linear retardance that can serve as an indicator of tissue anisotropy, and with a dual-projection method, information about the anisotropy axis orientation can also be extracted. Two-photon microscopy results reveal that stem-cell treated tissue retains more myocytes and structure than infarcted myocardium, while polarimetry findings suggest that the injury caused by temporary ligation of a coronary artery is less severe and more diffuse that than caused by a permanent ligation. Both these methods show potential for tissue characterization.

Phosphorescent probes for two-photon microscopy of oxygen (Conference Presentation)

Science.gov (United States)

Vinogradov, Sergei A.; Esipova, Tatiana V.

2016-03-01

The ability to quantify oxygen in vivo in 3D with high spatial and temporal resolution is much needed in many areas of biological research. Our laboratory has been developing the phosphorescence quenching technique for biological oximetry - an optical method that possesses intrinsic microscopic capability. In the past we have developed dendritically protected oxygen probes for quantitative imaging of oxygen in tissue. More recently we expanded our design on special two-photon enhanced phosphorescent probes. These molecules brought about first demonstrations of the two-photon phosphorescence lifetime microscopy (2PLM) of oxygen in vivo, providing new information for neouroscience and stem cell biology. However, current two-photon oxygen probes suffer from a number of limitations, such as sub-optimal brightness and high cost of synthesis, which dramatically reduce imaging performance and limit usability of the method. In this paper we discuss principles of 2PLM and address the interplay between the probe chemistry, photophysics and spatial and temporal imaging resolution. We then present a new approach to brightly phosphorescent chromophores with internally enhanced two-photon absorption cross-sections, which pave a way to a new generation of 2PLM probes.

Near-IR Two-Photon Fluorescent Sensor for K(+) Imaging in Live Cells.

Science.gov (United States)

Sui, Binglin; Yue, Xiling; Kim, Bosung; Belfield, Kevin D

2015-08-19

A new two-photon excited fluorescent K(+) sensor is reported. The sensor comprises three moieties, a highly selective K(+) chelator as the K(+) recognition unit, a boron-dipyrromethene (BODIPY) derivative modified with phenylethynyl groups as the fluorophore, and two polyethylene glycol chains to afford water solubility. The sensor displays very high selectivity (>52-fold) in detecting K(+) over other physiological metal cations. Upon binding K(+), the sensor switches from nonfluorescent to highly fluorescent, emitting red to near-IR (NIR) fluorescence. The sensor exhibited a good two-photon absorption cross section, 500 GM at 940 nm. Moreover, it is not sensitive to pH in the physiological pH range. Time-dependent cell imaging studies via both one- and two-photon fluorescence microscopy demonstrate that the sensor is suitable for dynamic K(+) sensing in living cells.

The Density Matrix for Single-mode Light after k-Photon Absorption

Science.gov (United States)

Voigt, H.; Bandilla, A.

In order to continue and generalize the studies of the density matrix of a light field undergoing k-photon absorption, in this paper we put the emphasis on the off-diagonal elements. The solution obtained earlier for the diagonal elements describing the photon statistics can be found as a special case but will not be discussed again. The general solution calculated by recursion shows an asymptotic behaviour if the initial photon number is sufficiently high. Only the initial phase information survives. Illustrating the solution we start with coherent light and a generalized coherent state.Translated AbstractDie Dichtematrix eines Lichtstrahls nach k-Photonen-Absorption aus einer ModeWir führen die Betrachtungen über das Verhalten der Dichtematrix eines Lichtfeldes nach k-Photonen-Absorption aus einer Mode verallgemeinernd weiter und konzentrieren uns auf die Nichtdiagonalelemente. Die im folgenden angegebene allgemeine Lösung, die durch Rekursion gefunden wurde, enthält die schon früher erhaltene, jedoch hier nicht weiter diskutierte Lösung für die Diagonalelemente als Spezialfall. Sie zeigt ferner, daß es einen asymptotischen Zustand gibt, der eine von der Ausgangsintensität unabhängige Information über die Ausgangsphase enthält. Zur Diskussion der Lösung werden verschiedene Anfangsbedingungen betrachtet, so z. B. kohärentes Licht und kohärentes Licht, das ein Medium mit nichtlinearem Brechungsindex durchlaufen hat (Kerr-Effekt).

Silole-Based Red Fluorescent Organic Dots for Bright Two-Photon Fluorescence In vitro Cell and In vivo Blood Vessel Imaging.

Science.gov (United States)

Chen, Bin; Feng, Guangxue; He, Bairong; Goh, Chiching; Xu, Shidang; Ramos-Ortiz, Gabriel; Aparicio-Ixta, Laura; Zhou, Jian; Ng, Laiguan; Zhao, Zujin; Liu, Bin; Tang, Ben Zhong

2016-02-10

Robust luminescent dyes with efficient two-photon fluorescence are highly desirable for biological imaging applications, but those suitable for organic dots fabrication are still rare because of aggregation-caused quenching. In this work, a red fluorescent silole, 2,5-bis[5-(dimesitylboranyl)thiophen-2-yl]-1-methyl-1,3,4-triphenylsilole ((MesB)2 DTTPS), is synthesized and characterized. (MesB)2 DTTPS exhibits enhanced fluorescence efficiency in nanoaggregates, indicative of aggregation-enhanced emission (AEE). The organic dots fabricated by encapsulating (MesB)2 DTTPS within lipid-PEG show red fluorescence peaking at 598 nm and a high fluorescence quantum yield of 32%. Upon excitation at 820 nm, the dots show a large two-photon absorption cross section of 3.43 × 10(5) GM, which yields a two-photon action cross section of 1.09 × 10(5) GM. These (MesB)2 DTTPS dots show good biocompatibility and are successfully applied to one-photon and two-photon fluorescence imaging of MCF-7 cells and two-photon in vivo visualization of the blood vascular of mouse muscle in a high-contrast and noninvasive manner. Moreover, the 3D blood vasculature located at the mouse ear skin with a depth of over 100 μm can also be visualized clearly, providing the spatiotemporal information about the whole blood vascular network. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Wideband absorption in one dimensional photonic crystal with graphene-based hyperbolic metamaterials

Science.gov (United States)

Kang, Yongqiang; Liu, Hongmei

2018-02-01

A broadband absorber which was proposed by one dimensional photonic crystal (1DPC) containing graphene-based hyperbolic metamaterials (GHMM) is theoretically investigated. For TM mode, it was demonstrated to absorb roughly 90% of all available electromagnetic waves at a 14 THz absorption bandwidth at normal incidence. The absorption bandwidth was affected by Fermi energy and thickness of dielectric layer. When the incident angle was increased, the absorption value decreased, and the absorption band had a gradual blue shift. These findings have potential applications for designing broadband optoelectronic devices at mid-infrared and THz frequency range.

Printed organic smart devices characterized by ultra-short laser pulses

DEFF Research Database (Denmark)

Pastorelli, Francesco

Resume: In this study, we demonstrate that nonlinear optical microscopy is a promising technique to characterize organic printed electronics. Using ultrashort laser pulses we stimulate two-photon absorption in a roll coated polymer semiconductor and map the resulting two-photon induced...

In vivo two-photon imaging of retina in rabbits and rats.

Science.gov (United States)

Jayabalan, Gopal Swamy; Wu, Yi-Kai; Bille, Josef F; Kim, Samuel; Mao, Xiao Wen; Gimbel, Howard V; Rauser, Michael E; Fan, Joseph T

2018-01-01

The purpose of this study was to evaluate the retina using near-infrared (NIR) two-photon scanning laser ophthalmoscopy. New Zealand white rabbits, albino rats, and brown Norway rats were used in this study. An autofluorescence image of the retina, including the retinal cells and its associated vasculatures was obtained by a real-time scan using the ophthalmoscope. Furthermore, the retinal vessels, nerve fiber layers and the non-pigmented retina were recorded with two-photon fluorescein angiography (FA); and the choroidal vasculatures were recorded using two-photon indocyanine green angiography (ICGA). Two-photon ICGA was achieved by exciting a second singlet state at ∼398 nm. Simultaneous two-photon FA and two-photon ICGA were performed to characterize the retinal and choroidal vessels with a single injection. The minimum laser power threshold required to elicit two-photon fluorescence was determined. The two-photon ophthalmoscope could serve as a promising tool to detect and monitor the disease progression in animal models. Moreover, these high-resolution images of retinal and choroidal vessels can be acquired in a real-time scan with a single light source, requiring no additional filters for FA or ICGA. The combination of FA and ICGA using the two-photon ophthalmoscope will help researchers to characterize the retinal diseases in animal models, and also to classify the types (classic, occult or mixed) of choroidal neovascularization (CNV) in macular degeneration. Furthermore, the prototype can be adapted to image the retina of rodents and rabbits. Copyright © 2017 Elsevier Ltd. All rights reserved.

A microprocessor controlled system for pulsed laser experiments nad its applications in two photon absorption spectroscopy of CaF2: Eu+2

International Nuclear Information System (INIS)

Nunes, L.A.O.; Matinaga, F.M.; Castro, J.C. de

1986-01-01

A very low cost data station for pulsed dye laser aplications is developed. The system employs a low cost single board microcomputer and low cost componenets. Details on the hardware configuration and sofware are presented. In order to demonstrate the power of this system we employed it to obtain a two photon absorption spectrum of some f→f transitions in europium ions present as impurity in CaF 2 . Flexibility of hardware and software allow other aplications, such as transient recording in the 10nsec per channel range and other real time data processing. (Author) [pt

New all-optical method for measuring molecular permanent dipole moment difference using two-photon absorption spectroscopy

International Nuclear Information System (INIS)

Rebane, A.; Drobizhev, M.; Makarov, N.S.; Beuerman, E.; Tillo, S.; Hughes, T.

2010-01-01

Stark effect, in combination with spectral hole burning and single-molecule spectroscopy, has been a fruitful technique to study permanent electric dipole moment of molecules in condensed phase. However, because measuring Stark shifts relies on external fields and narrow line- or hole-widths, the applicability of this method at ambient conditions required by most biological systems has remained limited. Here we demonstrate a new all-optical method for measuring the molecular dipole moment difference between ground and excited states using two-photon absorption (2PA) spectroscopy. We show that the value and orientation of the static dipole moment difference can be determined from the corresponding absolute 2PA cross-section. We use this new method to determine for the first time the strength of local electric field E loc =0.1-1.0x10 8 V/cm inside beta-barrel of Fruit series of red fluorescent proteins. Because our method does not rely on external field and is applicable in liquid solutions, it is well suited for the study of biological systems.

Controllable Absorption and Dispersion Properties of an RF-driven Five-Level Atom in a Double-Band Photonic-Band-Gap Material

International Nuclear Information System (INIS)

Ding Chunling; Li Jiahua; Yang Xiaoxue

2011-01-01

The probe absorption-dispersion spectra of a radio-frequency (RF)-driven five-level atom embedded in a photonic crystal are investigated by considering the isotropic double-band photonic-band-gap (PBG) reservoir. In the model used, the two transitions are, respectively, coupled by the upper and lower bands in such a PBG material, thus leading to some curious phenomena. Numerical simulations are performed for the optical spectra. It is found that when one transition frequency is inside the band gap and the other is outside the gap, there emerge three peaks in the absorption spectra. However, for the case that two transition frequencies lie inside or outside the band gap, the spectra display four absorption profiles. Especially, there appear two sharp peaks in the spectra when both transition frequencies exist inside the band gap. The influences of the intensity and frequency of the RF-driven field on the absorptive and dispersive response are analyzed under different band-edge positions. It is found that a transparency window appears in the absorption spectra and is accompanied by a very steep variation of the dispersion profile by adjusting system parameters. These results show that the absorption-dispersion properties of the system depend strongly on the RF-induced quantum interference and the density of states (DOS) of the PBG reservoir. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

Angular distributions of low kinetic energy photoelectrons in one- and two-photon ionisation of rare gas atoms

International Nuclear Information System (INIS)

O'Keeffe, P; Bolognesi, P; Avaldi, L; Richter, R; Moise, A; Cleva, P De; Mihelic, A

2012-01-01

The angular distributions of electrons emitted in the photoionisation of rare gas atoms using one and two photons are presented. The one-photon results show that these differential measurements can provide complementary information on the photoionisation event with respect to the measurement of the total absorption cross section while the two photon ionization allows additional parameters to be extracted from the experiments thus permitting a more complete description of the photoionisation dynamics.

Two-photon fluorescence and fluorescence imaging of two styryl heterocyclic dyes combined with DNA.

Science.gov (United States)

Gao, Chao; Liu, Shu-yao; Zhang, Xian; Liu, Ying-kai; Qiao, Cong-de; Liu, Zhao-e

2016-03-05

Two new styryl heterocyclic two-photon (TP) materials, 4-[4-(N-methyl)styrene]-imidazo [4,5-f][1,10] phenanthroline-benzene iodated salt (probe-1) and 4,4-[4-(N-methyl)styrene]-benzene iodated salt (probe-2) were successfully synthesized and studied as potential fluorescent probes of DNA detection. The linear and nonlinear photophysical properties of two compounds in different solvents were investigated. The absorption, one- and two-photon fluorescent spectra of the free dye and dye-DNA complex were also examined to evaluate their photophysical properties. The binding constants of dye-DNA were obtained according to Scatchard equation with good values. The results showed that two probes could be used as fluorescent DNA probes by two-photon excitation, and TP fluorescent properties of probe-1 are superior to that of probe-2. The fluorescent method date indicated that the mechanisms of dye-DNA complex interaction may be groove binding for probe-1 and electrostatic interaction for probe-2, respectively. The MTT assay experiments showed two probes are low toxicity. Moreover, the TP fluorescence imaging of DNA detection in living cells at 800 nm indicated that the ability to locate in cell nuclei of probe-1 is better than that of probe-2. Copyright © 2015 Elsevier B.V. All rights reserved.

Characterization of a remote optical element with bi-photons

Science.gov (United States)

Puhlmann, D.; Henkel, C.; Heuer, A.; Pieplow, G.; Menzel, R.

2016-02-01

We present a simple setup that exploits the interference of entangled photon pairs. ‘Signal’ photons are sent through a Mach-Zehnder-like interferometer, while ‘idlers’ are detected in a variable polarization state. Two-photon interference (in coincidence detection) is observed with very high contrast and for significant time delays between signal and idler detection events. This is explained by quantum erasure of the polarization tag and a delayed choice protocol involving a non-local virtual polarizer. The phase of the two-photon fringes is scanned by varying the path length in the signal beam or by rotating a birefringent crystal in the idler beam. We exploit this to characterize one beam splitter of the signal photon interferometer (reflection and transmission amplitudes including losses), using only information about coincidences and control parameters in the idler path. This is possible because our bi-photon state saturates the Greenberger-Yelin-Englert inequality between contrast and predictability.

Characterization of a remote optical element with bi-photons

International Nuclear Information System (INIS)

Puhlmann, D; Henkel, C; Heuer, A; Pieplow, G; Menzel, R

2016-01-01

We present a simple setup that exploits the interference of entangled photon pairs. ‘Signal’ photons are sent through a Mach–Zehnder-like interferometer, while ‘idlers’ are detected in a variable polarization state. Two-photon interference (in coincidence detection) is observed with very high contrast and for significant time delays between signal and idler detection events. This is explained by quantum erasure of the polarization tag and a delayed choice protocol involving a non-local virtual polarizer. The phase of the two-photon fringes is scanned by varying the path length in the signal beam or by rotating a birefringent crystal in the idler beam. We exploit this to characterize one beam splitter of the signal photon interferometer (reflection and transmission amplitudes including losses), using only information about coincidences and control parameters in the idler path. This is possible because our bi-photon state saturates the Greenberger–Yelin–Englert inequality between contrast and predictability. (invited comment)

The role of molecular conformation and polarizable embedding for one- and two-photon absorption of disperse orange 3 in solution.

Science.gov (United States)

Silva, Daniel L; Murugan, N Arul; Kongsted, Jacob; Rinkevicius, Zilvinas; Canuto, Sylvio; Ågren, Hans

2012-07-19

Solvent effects on the one- and two-photon absorption (1PA and 2PA) of disperse orange 3 (DO3) in dimethyl sulfoxide (DMSO) are studied using a discrete polarizable embedding (PE) response theory. The scheme comprises a quantum region containing the chromophore and an atomically granulated classical region for the solvent accounting for full interactions within and between the two regions. Either classical molecular dynamics (MD) or hybrid Car-Parrinello (CP) quantum/classical (QM/MM) molecular dynamics simulations are employed to describe the solvation of DO3 in DMSO, allowing for an analysis of the effect of the intermolecular short-range repulsion, long-range attraction, and electrostatic interactions on the conformational changes of the chromophore and also the effect of the solute-solvent polarization. PE linear response calculations are performed to verify the character, solvatochromic shift, and overlap of the two lowest energy transitions responsible for the linear absorption spectrum of DO3 in DMSO in the visible spectral region. Results of the PE linear and quadratic response calculations, performed using uncorrelated solute-solvent configurations sampled from either the classical or hybrid CP QM/MM MD simulations, are used to estimate the width of the line shape function of the two electronic lowest energy excited states, which allow a prediction of the 2PA cross-sections without the use of empirical parameters. Appropriate exchange-correlation functionals have been employed in order to describe the charge-transfer process following the electronic transitions of the chromophore in solution.

Tale of two photons

International Nuclear Information System (INIS)

Anon.

1994-01-01

A very profitable spinoff from electron- positron collisions is two-photon physics. Rather than the electron and positron interacting directly via an exchanged photon, two virtual (transient) photons, one from each particle, get tangled up. With new electron-positron colliders appearing on the scene, a topical meeting on two-photon physics - 'From DAPHNE to LEP 200 and beyond' - held from 2-4 February in Paris, in the premises of the Ministry of Higher Education and Research, was particularly timely. Some 60 physicists, both experimentalists and theorists, participated, with some thirty speakers

Two-photon interference of polarization-entangled photons in a Franson interferometer.

Science.gov (United States)

Kim, Heonoh; Lee, Sang Min; Kwon, Osung; Moon, Han Seb

2017-07-18

We present two-photon interference experiments with polarization-entangled photon pairs in a polarization-based Franson-type interferometer. Although the two photons do not meet at a common beamsplitter, a phase-insensitive Hong-Ou-Mandel type two-photon interference peak and dip fringes are observed, resulting from the two-photon interference effect between two indistinguishable two-photon probability amplitudes leading to a coincidence detection. A spatial quantum beating fringe is also measured for nondegenerate photon pairs in the same interferometer, although the two-photon states have no frequency entanglement. When unentangled polarization-correlated photons are used as an input state, the polarization entanglement is successfully recovered through the interferometer via delayed compensation.

Simultaneous control of emission localization and two-photon absorption efficiency in dissymmetrical chromophores

International Nuclear Information System (INIS)

Tretiak, Sergei

2009-01-01

The aim of the present work is to demonstrate that combined spectral tuning of fluorescence and two-photon absorption (TPA) properties of multipolar chromophores can be achieved by introduction of slight electronic chemical dissymmetry. In that perspective, two novel series of structurally related chromophores have been designed and studied: a first series based on rod-like quadrupolar chromophores bearing different electron-donating (D) end groups and a second series based on three-branched octupolar chromophores built from a trigonal donating moiety and bearing various acceptor (A) peripheral groups. The influence of the electronic dissymmetry is investigated by combined experimental and theoretical studies of the linear and nonlinear optical properties of dissymmetric chromophores compared to their symmetrical counterparts. In both types of systems (i.e. quadrupoles and octupoles) experiments and theory reveal that excitation is essentially delocalized and that excitation involves synchronized charge redistribution between the different D and A moieties within the multipolar structure (i.e. concerted intramolecular charge transfer). In contrast, the emission stems only from a particular dipolar subunit bearing the strongest D or A moieties due to fast excitation localization after excitation prior to emission. Hence control of emission characteristics (polarization and emission spectrum) in addition to localization can be achieved by controlled introduction of electronic dissymmetry (i.e. replacement of one of the D or A end-groups by a slightly stronger D(prime) or A(prime) units). Interestingly dissymmetrical functionalization of both quadrupolar and octupolar compounds does not lead to significant loss in TPA responses and can even be beneficial due to the spectral broadening and peak position tuning that it allows. This study thus reveals an original molecular engineering route strategy allowing major TPA enhancement in multipolar structures due to concerted

Direct and indirect two-photon processes in semiconductors

International Nuclear Information System (INIS)

Hassan, A.R.

1986-07-01

The expressions describing direct and indirect two-photon absorption in crystals are given. They are valid both near and far from the energy gap. A perturbative approach through two different band models is adopted. The effects of the non-parabolicity and the degeneracy of the energy bands are considered. The numerical results are compared with the other theories and with a recent experimental data in Zn and AgCl. It is shown that the dominant transition mechanisms are of the allowed-allowed type near and far from the gap for both direct and indirect processes. (author)

A spirobifluorene-based two-photon fluorescence probe for mercury ions and its applications in living cells

Energy Technology Data Exchange (ETDEWEB)

Xiao, Haibo, E-mail: xiaohb@shnu.edu.cn; Zhang, Yanzhen; Zhang, Wu; Li, Shaozhi; Tan, Jingjing; Han, Zhongying

2017-05-01

A novel spirobifluorene derivative SPF-TMS, which containing dithioacetal groups and triphenylamine units, was synthesized. The probing behaviors toward various metal ions were investigated via UV/Vis absorption spectra as well as one-photon fluorescence changes. The results indicated that SPF-TMS exhibits high sensitivity and selectivity for mercury ions. The detection limit was at least 8.6 × 10{sup −8}M, which is excellent comparing with other optical sensors for Hg{sup 2+}. When measured by two-photon excited fluorescence technique in THF at 800 nm, the two-photon cross-section of SPF-TMS is 272 GM. Especially, upon reaction with mercury species, SPF-TMS yielded another two-photon dye SPF-DA. Both SPF-TMS and SPF-DA emit strong two-photon induced fluorescence and can be applied in cell imaging by two-photon microscopy. - Highlights: • We report a spirobifluorene-based molecule as two-photon fluorescent probe with large two-photon cross-section. • The molecule has exclusive selectivity and sensitivity for mercury species. • The molecule has large two-photon emission changes before and after addition of Hg{sup 2+}. • Both the probe and the mercury ion-promoted reaction product can be applied in cell imaging by two-photon microscopy.

A bioaccumulative cyclometalated platinum(II) complex with two-photon-induced emission for live cell imaging.

Science.gov (United States)

Koo, Chi-Kin; Wong, Ka-Leung; Man, Cornelia Wing-Yin; Lam, Yun-Wah; So, Leo King-Yan; Tam, Hoi-Lam; Tsao, Sai-Wah; Cheah, Kok-Wai; Lau, Kai-Chung; Yang, Yang-Yi; Chen, Jin-Can; Lam, Michael Hon-Wah

2009-02-02

The cyclometalated platinum(II) complex [Pt(L)Cl], where HL is a new cyclometalating ligand 2-phenyl-6-(1H-pyrazol-3-yl)pyridine containing C(phenyl), N(pyridyl), and N(pyrazolyl) donor moieties, was found to possess two-photon-induced luminescent properties. The two-photon-absorption cross section of the complex in N,N-dimethylformamide at room temperature was measured to be 20.8 GM. Upon two-photon excitation at 730 nm from a Ti:sapphire laser, bright-green emission was observed. Besides its two-photon-induced luminescent properties, [Pt(L)Cl] was able to be rapidly accumulated in live HeLa and NIH3T3 cells. The two-photon-induced luminescence of the complex was retained after live cell internalization and can be observed by two-photon confocal microscopy. Its bioaccumulation properties enabled time-lapse imaging of the internalization process of the dye into living cells. Cytotoxicity of [Pt(L)Cl] to both tested cell lines was low, according to MTT assays, even at loadings as high as 20 times the dose concentration for imaging for 6 h.

Two Photon Induced Lasing in 1550 nm Quantum Dash Optical Gain Media

DEFF Research Database (Denmark)

Capua, Amir; Saal, Abigael; Reithmaier, Johann Peter

2011-01-01

We report on a unique lasing mechanism observed in quantum dash Gain media. While the gain media is electrically pumped below lasing threshold, a strong optical pulse excites carriers by two photon absorption into high energy states of the quantum dashes and wetting layer. Fast inter band carrier...

Coherent enhancement of resonance-mediated multiphoton absorption

International Nuclear Information System (INIS)

Zhang, Shian; Zhang, Hui; Jia, Tianqing; Wang, Zugeng; Sun, Zhenrong

2010-01-01

In this paper, we theoretically investigate the coherent enhancement of resonance-mediated (2+2) four-photon absorption. It is found that by shaping the spectral phase with a π phase step, the resonance-mediated (2+2) four-photon transition probability can be enhanced. Furthermore, the coherent enhancement dependences on the detuning between the two two-photon absorptions, laser spectral bandwidth and laser centre frequency are explicitly discussed and analysed. We believe these theoretical results may play an important role in enhancing more complex resonance-mediated multiphoton absorption processes.

Two-photon double ionization of the helium atom by ultrashort pulses

International Nuclear Information System (INIS)

Palacios, Alicia; Horner, Daniel A.; Rescigno, Thomas N.; McCurdy, C. William

2010-01-01

Two-photon double ionization of the helium atom was the subject of early experiments at FLASH and will be the subject of future benchmark measurements of the associated electron angular and energy distributions. As the photon energy of a single femtosecond pulse is raised from the threshold for two-photon double ionization at 39.5 eV to beyond the sequential ionization threshold at 54.4 eV, the electron ejection dynamics change from the highly correlated motion associated with nonsequential absorption to the much less correlated sequential ionization process. The signatures of both processes have been predicted in accurate ab initio calculations of the joint angular and energy distributions of the electrons, and those predictions contain some surprises. The dominant terms that contribute to sequential ionization make their presence apparent several eV below that threshold. In two-color pump probe experiments with short pulses whose central frequencies require that the sequential ionization process necessarily dominates, a two-electron interference pattern emerges that depends on the pulse delay and the spin state of the atom.

Two photon processes in surface photovoltage spectroscopy

International Nuclear Information System (INIS)

Craig, R.P.; Thurgate, S.M.

1996-01-01

Full text: A significant mid-gap effect has been found in Surface Photovoltage Spectroscopy measurements of cleaved GaAs, InP and Si wafer which is normally interpreted as arising from transitions between surface states and band edges. This large mid-gap effect common to various materials is puzzling as such a high proportion of mid-gap states seems unlikely. Most theories of surface states predict states that tail from the band edges into the gap or states that have a well defined energy in the gap. None propose a large state exactly at E G /2. We recently investigated the variation in SPS spectra with flux density. We find a non-linear correlation in the magnitude of Band-Bending arising from mid-gap and band-gap photon energies. We suggest that the mid-gap feature is due to a two photon absorption process leading to carrier pair generation mediated by mid-gap states in the continuum of band-gap surface states

Multiphoton absorption coefficients in solids: an universal curve

International Nuclear Information System (INIS)

Brandi, H.S.; Araujo, C.B. de

1983-04-01

An universal curve for the frequency dependence of the multiphoton absorption coefficient is proposed based on a 'non-perturbative' approach. Specific applications have been made to obtain two, three, four and five photons absorption coefficient in different materials. Properly scaling of the two photon absorption coefficient and the use of the universal curve yields results for the higher order absorption coefficients in good agreement with the experimental data. (Author) [pt

Time-resolved measurement of the quantum states of photons using two-photon interference with short-time reference pulses

International Nuclear Information System (INIS)

Ren Changliang; Hofmann, Holger F.

2011-01-01

To fully utilize the energy-time degree of freedom of photons for optical quantum-information processes, it is necessary to control and characterize the temporal quantum states of the photons at extremely short time scales. For measurements of the temporal coherence of the quantum states beyond the time resolution of available detectors, two-photon interference with a photon in a short-time reference pulse may be a viable alternative. In this paper, we derive the temporal measurement operators for the bunching statistics of a single-photon input state with a photon from a weak coherent reference pulse. It is shown that the effects of the pulse shape of the reference pulse can be expressed in terms of a spectral filter selecting the bandwidth within which the measurement can be treated as an ideal projection on eigenstates of time. For full quantum tomography, temporal coherence can be determined by using superpositions of reference pulses at two different times. Moreover, energy-time entanglement can be evaluated based on the two-by-two entanglement observed in the coherences between pairs of detection times.

Polarised two-photon excitation of quantum well excitons for manipulation of optically pumped terahertz lasers

Energy Technology Data Exchange (ETDEWEB)

Slavcheva, G., E-mail: gsk23@bath.ac.uk [Blackett Laboratory, Imperial College London, Prince Consort Road, London SW7 2AZ (United Kingdom); Kavokin, A.V., E-mail: A.Kavokin@soton.ac.uk [School of Physics and Astronomy, University of Southampton, Highfield, Southampton SO17 1BJ (United Kingdom); Spin Optics Laboratory, St. Petersburg State University, 1, Ulyanovskaya 198504 (Russian Federation)

2014-11-15

Optical pumping of excited exciton states in a semiconductor quantum well embedded in a microcavity is a tool for realisation of ultra-compact terahertz (THz) lasers based on stimulated optical transition between excited (2p) and ground (1s) exciton state. We show that the probability of two-photon absorption by a 2p-exciton is strongly dependent on the polarisation of both pumping photons. Five-fold variation of the threshold power for terahertz lasing by switching from circular to co-linear pumping is predicted. We identify photon polarisation configurations for achieving maximum THz photon generation quantum efficiency.

Selective two-photon collagen crosslinking in situ measured by Brillouin microscopy (Conference Presentation)

Science.gov (United States)

Kwok, Sheldon J. J.; Kuznetsov, Ivan A.; Kim, Moonseok; Choi, Myunghwan; Scarcelli, Giuliano; Yun, Seok-Hyun

2017-02-01

Two-photon polymerization and crosslinking are commonly used methods for microfabrication of three-dimensional structures with applications spanning from photonic microdevices, drug delivery systems, to cellular scaffolds. However, the use of two-photon processes for precise, internal modification of biological tissues has not yet been reported. One of the major challenges has been a lack of appropriate tools to monitor and characterize crosslinked regions nondestructively. Here, we demonstrate spatially selective two-photon collagen crosslinking (2P-CXL) in intact tissue for the first time. Using riboflavin photosensitizer and femtosecond laser irradiation, we crosslinked a small volume of tissue within animal corneas. Collagen fiber orientations and photobleaching were characterized by second harmonic generation and two-photon fluorescence imaging, respectively. Using confocal Brillouin microscopy, we measured local changes in longitudinal mechanical moduli and visualized the cross-linked pattern without perturbing surrounding non-irradiated regions. 2P-CXL-induced tissue stiffening was comparable to that achieved with conventional one-photon CXL. Our results demonstrate the ability to selectively stiffen biological tissue in situ at high spatial resolution, with broad implications in ophthalmology, laser surgery, and tissue engineering.

Diagnostics of MCF plasmas using Lyman-α fluorescence excited by one or two photons

International Nuclear Information System (INIS)

Voslamber, D.

1998-11-01

Laser-induced Lyman-α fluorescence of the hydrogen isotopes is investigated with regard to diagnostic applications in magnetically confined fusion plasmas. A formal analysis is presented for two excitation schemes: one-photon and Doppler-free two-photon excitation. The analysis includes estimates of the expected experimental errors arising from the photon noise and from the sensitivity of the observed fluorescence signals to variations of the plasma and laser parameters. Both excitation schemes are suitable primarily for application in the plasma edge, but even in the plasma bulk of large machines they can still be applied in combination with a diagnostic neutral beam. The two-photon excitation scheme is particularly attractive because it involves absorption spectra that are resolved within the Doppler width. This implies a large diagnostic potential and in particular offers a way to measure the deuterium-tritium fuel mix in fusion reactors. (author)

Production mechanism of atomic nitrogen in atmospheric pressure pulsed corona discharge measured using two-photon absorption laser-induced fluorescence

International Nuclear Information System (INIS)

Teramoto, Yoshiyuki; Ono, Ryo; Oda, Tetsuji

2012-01-01

To study the production mechanism of atomic nitrogen, the temporal profile and spatial distribution of atomic nitrogen are measured in atmospheric pressure pulsed positive corona discharge using two-photon absorption laser-induced fluorescence. The absolute atomic nitrogen density in the streamer filaments is estimated from decay rate of atomic nitrogen in N 2 discharge. The results indicate that the absolute atomic nitrogen density is approximately constant against discharge energy. When the discharge voltage is 21.5 kV, production yield of atomic nitrogen produced by an N 2 discharge pulse is estimated to be 2.9 - 9.8 × 10 13 atoms and the energy efficiency of atomic nitrogen production is estimated to be about 1.8 - 6.1 × 10 16 atoms/J. The energy efficiency of atomic nitrogen production in N 2 discharge is constant against the discharge energy, while that in N 2 /O 2 discharge increases with discharge energy. In the N 2 /O 2 discharge, two-step process of N 2 dissociation plays significant role for atomic nitrogen production.

Two-dimensional topological photonics

Science.gov (United States)

Khanikaev, Alexander B.; Shvets, Gennady

2017-12-01

Originating from the studies of two-dimensional condensed-matter states, the concept of topological order has recently been expanded to other fields of physics and engineering, particularly optics and photonics. Topological photonic structures have already overturned some of the traditional views on wave propagation and manipulation. The application of topological concepts to guided wave propagation has enabled novel photonic devices, such as reflection-free sharply bent waveguides, robust delay lines, spin-polarized switches and non-reciprocal devices. Discrete degrees of freedom, widely used in condensed-matter physics, such as spin and valley, are now entering the realm of photonics. In this Review, we summarize the latest advances in this highly dynamic field, with special emphasis on the experimental work on two-dimensional photonic topological structures.

Tutorial on X-ray photon counting detector characterization.

Science.gov (United States)

Ren, Liqiang; Zheng, Bin; Liu, Hong

2018-01-01

Recent advances in photon counting detection technology have led to significant research interest in X-ray imaging. As a tutorial level review, this paper covers a wide range of aspects related to X-ray photon counting detector characterization. The tutorial begins with a detailed description of the working principle and operating modes of a pixelated X-ray photon counting detector with basic architecture and detection mechanism. Currently available methods and techniques for charactering major aspects including energy response, noise floor, energy resolution, count rate performance (detector efficiency), and charge sharing effect of photon counting detectors are comprehensively reviewed. Other characterization aspects such as point spread function (PSF), line spread function (LSF), contrast transfer function (CTF), modulation transfer function (MTF), noise power spectrum (NPS), detective quantum efficiency (DQE), bias voltage, radiation damage, and polarization effect are also remarked. A cadmium telluride (CdTe) pixelated photon counting detector is employed for part of the characterization demonstration and the results are presented. This review can serve as a tutorial for X-ray imaging researchers and investigators to understand, operate, characterize, and optimize photon counting detectors for a variety of applications.

Fs-transient absorption and fluorescence upconversion after two- photon excitation of carotenoids in solution and in LHC II

CERN Document Server

Wall, P J; Fleming, G R

2000-01-01

With time resolved two-photon techniques we determined the lifetime and two-photon spectrum of the forbidden S/sub 1/ state of beta - carotene (9+or-0.2 ps), lutein (15+or-0.5 ps) and the energy transferring carotenoids in LHC II (250+or-50 fs). (7 refs).

Two-Photon Polymerization Metrology: Characterization Methods of Mechanisms and Microstructures

Directory of Open Access Journals (Sweden)

Christopher N. LaFratta

2017-03-01

Full Text Available The ability to create complex three-dimensional microstructures has reached an unprecedented level of sophistication in the last 15 years. For the most part, this is the result of a steady development of the additive manufacturing technique named two-photon polymerization (TPP. In a short amount of time, TPP has gone from being a microfabrication novelty employed largely by laser specialists to a useful tool in the hands of scientists and engineers working in a wide range of research fields including microfluidics. When used in combination with traditional microfabrication processes, TPP can be employed to add unique three-dimensional components to planar platforms, thus enabling the realization of lab-on-a-chip solutions otherwise impossible to create. To take full advantage of TPP, an in-depth understanding is required of the materials photochemistry and the fabricated microstructures’ mechanical and chemical properties. Thus, we review methods developed so far to investigate the underling mechanism involved during TPP and analytical methods employed to characterize TPP microstructures. Furthermore, we will discuss potential opportunities for using optofluidics and lab-on-a-chip systems for TPP metrology.

Applications of two-photon fluorescence microscopy in deep-tissue imaging

Science.gov (United States)

Dong, Chen-Yuan; Yu, Betty; Hsu, Lily L.; Kaplan, Peter D.; Blankschstein, D.; Langer, Robert; So, Peter T. C.

2000-07-01

Based on the non-linear excitation of fluorescence molecules, two-photon fluorescence microscopy has become a significant new tool for biological imaging. The point-like excitation characteristic of this technique enhances image quality by the virtual elimination of off-focal fluorescence. Furthermore, sample photodamage is greatly reduced because fluorescence excitation is limited to the focal region. For deep tissue imaging, two-photon microscopy has the additional benefit in the greatly improved imaging depth penetration. Since the near- infrared laser sources used in two-photon microscopy scatter less than their UV/glue-green counterparts, in-depth imaging of highly scattering specimen can be greatly improved. In this work, we will present data characterizing both the imaging characteristics (point-spread-functions) and tissue samples (skin) images using this novel technology. In particular, we will demonstrate how blind deconvolution can be used further improve two-photon image quality and how this technique can be used to study mechanisms of chemically-enhanced, transdermal drug delivery.

Photon management in two-dimensional disordered media.

Science.gov (United States)

Vynck, Kevin; Burresi, Matteo; Riboli, Francesco; Wiersma, Diederik S

2012-12-01

Elaborating reliable and versatile strategies for efficient light coupling between free space and thin films is of crucial importance for new technologies in energy efficiency. Nanostructured materials have opened unprecedented opportunities for light management, notably in thin-film solar cells. Efficient coherent light trapping has been accomplished through the careful design of plasmonic nanoparticles and gratings, resonant dielectric particles and photonic crystals. Alternative approaches have used randomly textured surfaces as strong light diffusers to benefit from their broadband and wide-angle properties. Here, we propose a new strategy for photon management in thin films that combines both advantages of an efficient trapping due to coherent optical effects and broadband/wide-angle properties due to disorder. Our approach consists of the excitation of electromagnetic modes formed by multiple light scattering and wave interference in two-dimensional random media. We show, by numerical calculations, that the spectral and angular responses of thin films containing disordered photonic patterns are intimately related to the in-plane light transport process and can be tuned through structural correlations. Our findings, which are applicable to all waves, are particularly suited for improving the absorption efficiency of thin-film solar cells and can provide a new approach for high-extraction-efficiency light-emitting diodes.

Selective two-photon excitation of a vibronic state by correlated photons.

Science.gov (United States)

Oka, Hisaki

2011-03-28

We theoretically investigate the two-photon excitation of a molecular vibronic state by correlated photons with energy anticorrelation. A Morse oscillator having three sets of vibronic states is used, as an example, to evaluate the selectivity and efficiency of two-photon excitation. We show that a vibrational mode can be selectively excited with high efficiency by the correlated photons, without phase manipulation or pulse-shaping techniques. This can be achieved by controlling the quantum correlation so that the photon pair concurrently has two pulse widths, namely, a temporally narrow width and a spectrally narrow width. Though this concurrence is seemingly contradictory, we can create such a photon pair by tailoring the quantum correlation between two photons.

Broadband and high absorption in Fibonacci photonic crystal including MoS2 monolayer in the visible range

Science.gov (United States)

Ansari, Narges; Mohebbi, Ensiyeh

2018-03-01

2D molybdenum disulfide MoS2, has represented potential applications in optoelectronic devices based on their promising optical absorption responses. However, for practical applications, absorption should increase furthermore in a wide wavelength window. In this paper, we design Fibonacci photonic crystals (PCs) based on Si, SiO2 and MoS2 monolayer and we calculate their absorption responses based on the transfer matrix method. The optical refractive index of the MoS2 monolayer was determined based on the Lorentz-Drude-Gauss model. Effects of Fibonacci order, periodicity, incident light angle and polarization are included in our calculations. Finally, an absorption as large as 90% in a wide optical wavelength range is achieved for both polarizations and incident angle down to 60°. Our results are useful for designing photonic devices with high absorption efficiency.

Two-dimensional 'photon fluid': effective photon-photon interaction and physical realizations

International Nuclear Information System (INIS)

Chiao, R Y; Hansson, T H; Leinaas, J M; Viefers, S

2004-01-01

We describe a recently developed effective theory for atom-mediated photon-photon interactions in a two-dimensional 'photon fluid' confined to a Fabry-Perot resonator. The photons in the lowest longitudinal cavity mode will appear as massive bosons interacting via a renormalized delta-function potential with a strength determined by physical parameters such as the density of atoms and the detuning of the photons relative to the resonance frequency of the atoms. We discuss novel quantum phenomena for photons, such as Bose-Einstein condensation and bound state formation, as well as possible experimental scenarios based on Rydberg atoms in a microwave cavity, or alkali atoms in an optical cavity

Enhancement of Solar Cell Efficiency for Space Applications Using Two-Dimensional Photonic Crystals

Directory of Open Access Journals (Sweden)

Postigo P.A.

2017-01-01

Full Text Available The effects of having a nanopatterned photonic crystal (PC structure in the surface of a solar cell can be usefully employed to increase the energy conversion efficiency, which may be critical for space applications. In this work, we have measured the reflectance (R and transmittance (T of thin InP layers (270 nm thick bonded to a glass substrate and nanopatterned with holes down to the glass in a triangular symmetry lattice separated by a lattice parameter a=450nm and maintaining a value of r/a=0.32. The optical spectra were measured with angular resolution in the range from 0.55 to 2.0 eV. There are noticeable changes in the spectra of the PC sample, with minima and maxima of the R and T clearly shifted with respect to the unpatterned sample, and new features that alter significantly the overall lineshape of each spectrum. Those features correspond in a first approximation to the well-known Fano-like resonances of the discrete photonic modes of the PC lattice and they have been used before to determine experimentally the position of the PC bands. The observed features can be translated to the optical absorption (A defined as A=1-R-T provided there are low or negligible scattering effects. The generated absorption spectra show enhancements above and below the electronic band edge of the InP that can be correlated with the photonic band structure. Even using a thicker semiconductor layer, the abovementioned effects can justify to use a photonic crystal front surface with sub-wavelength motifs. In this way, we have fabricated and characterized a complete Ge/InGaP solar cell with a 2D-PC on its front surface. An increase in the photocurrent up to a 8% was achieved on a solar cell with a 40% of its surface covered with a PC pattern. Enhancements of the external quantum efficiency (EQE of 22% for a wide range of wavelengths and up to a 46% for specific wavelengths have been measured, without use of any anti-reflection coating (ARC. A correlation

Charge Transport in Two-Photon Semiconducting Structures for Solar Fuels.

Science.gov (United States)

Liu, Guohua; Du, Kang; Haussener, Sophia; Wang, Kaiying

2016-10-20

Semiconducting heterostructures are emerging as promising light absorbers and offer effective electron-hole separation to drive solar chemistry. This technology relies on semiconductor composites or photoelectrodes that work in the presence of a redox mediator and that create cascade junctions to promote surface catalytic reactions. Rational tuning of their structures and compositions is crucial to fully exploit their functionality. In this review, we describe the possibilities of applying the two-photon concept to the field of solar fuels. A wide range of strategies including the indirect combination of two semiconductors by a redox couple, direct coupling of two semiconductors, multicomponent structures with a conductive mediator, related photoelectrodes, as well as two-photon cells are discussed for light energy harvesting and charge transport. Examples of charge extraction models from the literature are summarized to understand the mechanism of interfacial carrier dynamics and to rationalize experimental observations. We focus on a working principle of the constituent components and linking the photosynthetic activity with the proposed models. This work gives a new perspective on artificial photosynthesis by taking simultaneous advantages of photon absorption and charge transfer, outlining an encouraging roadmap towards solar fuels. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Magnetic absorption of VHE photons in the magnetosphere of the Crab pulsar

Science.gov (United States)

Bogovalov, S. V.; Contopoulos, I.; Prosekin, A.; Tronin, I.; Aharonian, F. A.

2018-05-01

The detection of the pulsed ˜1 TeV gamma-ray emission from the Crab pulsar reported by MAGIC and VERITAS collaborations demands a substantial revision of existing models of particle acceleration in the pulsar magnetosphere. In this regard model independent restrictions on the possible production site of the very high energy (VHE) photons become an important issue. In this paper, we consider limitations imposed by the process of conversion of VHE gamma-rays into e± pairs in the magnetic field of the pulsar magnetosphere. Photons with energies exceeding 1 TeV are effectively absorbed even at large distances from the surface of the neutron star. Our calculations of magnetic absorption in the force-free magnetosphere show that the twisting of the magnetic field due to the pulsar rotation makes the magnetosphere more transparent compared to the dipole magnetosphere. The gamma-ray absorption appears stronger for photons emitted in the direction of rotation than in the opposite direction. There is a small angular cone inside which the magnetosphere is relatively transparent and photons with energy 1.5 TeV can escape from distances beyond 0.1 light cylinder radius (Rlc). The emission surface from where photons can be emitted in the observer's direction further restricts the sites of VHE gamma-ray production. For the observation angle 57° relative to the Crab pulsar axis of rotation and the orthogonal rotation, the emission surface in the open field line region is located as close as 0.4 Rlc from the stellar surface for a dipole magnetic field, and 0.1 Rlc for a force-free magnetic field.

Broadband transient absorption spectroscopy with 1- and 2-photon excitations: Relaxation paths and cross sections of a triphenylamine dye in solution

Energy Technology Data Exchange (ETDEWEB)

Moreno, J.; Dobryakov, A. L.; Hecht, S., E-mail: sh@chemie.hu-berlin.de, E-mail: skovale@chemie.hu-berlin.de; Kovalenko, S. A., E-mail: sh@chemie.hu-berlin.de, E-mail: skovale@chemie.hu-berlin.de [Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-St. 2, 12489 Berlin (Germany); Ioffe, I. N. [Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow (Russian Federation); Granovsky, A. A. [Firefly Project, 117593 Moscow (Russian Federation)

2015-07-14

1-photon (382 nm) and 2-photon (752 nm) excitations to the S{sub 1} state are applied to record and compare transient absorption spectra of a push-pull triphenylamine (TrP) dye in solution. After 1-photon excitation, ultrafast vibrational and structural molecular relaxations are detected on a 0.1 ps time scale in nonpolar hexane, while in polar acetonitrile, the spectral evolution is dominated by dipolar solvation. Upon 2-photon excitation, transient spectra in hexane reveal an unexpected growth of stimulated emission (SE) and excited-state absorption (ESA) bands. The behavior is explained by strong population transfer S{sub 1} → S{sub n} due to resonant absorption of a third pump photon. Subsequent S{sub n} → S{sub 1} internal conversion (with τ{sub 1} = 1 ps) prepares a very hot S{sub 1} state which cools down with τ{sub 2} = 13 ps. The pump pulse energy dependence proves the 2-photon origin of the bleach signal. At the same time, SE and ESA are strongly affected by higher-order pump absorptions that should be taken into account in nonlinear fluorescence applications. The 2-photon excitation cross sections σ{sup (2)} = 32 ⋅ 10{sup −50} cm{sup 4} s at 752 nm are evaluated from the bleach signal.

Two-photon high-resolution measurement of partial pressure of oxygen in cerebral vasculature and tissue.

Science.gov (United States)

Sakadzić, Sava; Roussakis, Emmanuel; Yaseen, Mohammad A; Mandeville, Emiri T; Srinivasan, Vivek J; Arai, Ken; Ruvinskaya, Svetlana; Devor, Anna; Lo, Eng H; Vinogradov, Sergei A; Boas, David A

2010-09-01

Measurements of oxygen partial pressure (pO(2)) with high temporal and spatial resolution in three dimensions is crucial for understanding oxygen delivery and consumption in normal and diseased brain. Among existing pO(2) measurement methods, phosphorescence quenching is optimally suited for the task. However, previous attempts to couple phosphorescence with two-photon laser scanning microscopy have faced substantial difficulties because of extremely low two-photon absorption cross-sections of conventional phosphorescent probes. Here we report to our knowledge the first practical in vivo two-photon high-resolution pO(2) measurements in small rodents' cortical microvasculature and tissue, made possible by combining an optimized imaging system with a two-photon-enhanced phosphorescent nanoprobe. The method features a measurement depth of up to 250 microm, sub-second temporal resolution and requires low probe concentration. The properties of the probe allowed for direct high-resolution measurement of cortical extravascular (tissue) pO(2), opening many possibilities for functional metabolic brain studies.

Two-photon high-resolution measurement of partial pressure of oxygen in cerebral vasculature and tissue

Science.gov (United States)

Sakadžić, Sava; Roussakis, Emmanuel; Yaseen, Mohammad A.; Mandeville, Emiri T.; Srinivasan, Vivek J.; Arai, Ken; Ruvinskaya, Svetlana; Devor, Anna; Lo, Eng H.; Vinogradov, Sergei A.; Boas, David A.

2010-01-01

The ability to measure oxygen partial pressure (pO2) with high temporal and spatial resolution in three dimensions is crucial for understanding oxygen delivery and consumption in normal and diseased brain. Among existing pO2 measurement methods, phosphorescence quenching is optimally suited for the task. However, previous attempts to couple phosphorescence with two-photon laser scanning microscopy have faced substantial difficulties because of extremely low two-photon absorption cross-sections of conventional phosphorescent probes. Here, we report the first practical in vivo two-photon high-resolution pO2 measurements in small rodents’ cortical microvasculature and tissue, made possible by combining an optimized imaging system with a two-photon-enhanced phosphorescent nanoprobe. The method features a measurement depth of up to 250 µm, sub-second temporal resolution and requires low probe concentration. Most importantly, the properties of the probe allowed for the first direct high-resolution measurement of cortical extravascular (tissue) pO2, opening numerous possibilities for functional metabolic brain studies. PMID:20693997

Non-Invasive In Vivo Characterization of Breast Tumors Using Photon Migration Spectroscopy

Directory of Open Access Journals (Sweden)

Bruce J. Tromberg

2000-01-01

Full Text Available Frequency-domain photon migration (FDPM is a noninvasive optical technique that utilizes intensity-modulated, near-infrared (NIR light to quantitatively measure optical properties in thick tissues. Optical properties (absorption, μa, and scattering, μs′, parameters derived from FDPM measurements can be used to construct low-resolution (0.5 to 1 cm functional images of tissue hemoglobin (total, oxy-, and deoxyforms, oxygen saturation, blood volume fraction, water content, fat content and cellular structure. Unlike conventional NIR transillumination, FDPM enables quantitative analysis of tissue absorption and scattering parameters in a single non-invasive measurement. The unique functional information provided by FDPM makes it well-suited to characterizing tumors in thick tissues. In order to test the sensitivity of FDPM for cancer diagnosis, we have initiated clinical studies to quantitatively determine normal and malignant breast tissue optical and physiological properties in human subjects. Measurements are performed using a non-invasive, multi-wavelength, diode-laser FDPM device optimized for clinical studies. Results show that ductal carcinomas (invasive and in situ and benign fibroadenomas exhibit 1.25 to 3-fold higher absorption than normal breast tissue. Within this group, absorption is greatest for measurements obtained from sites of invasive cancer. Optical scattering is approximately 20% greater in pre-menopausal versus post-menopausal subjects due to differences in gland/cell proliferation and collagen/fat content. Spatial variations in tissue scattering reveal the loss of differentiation associated with breast disease progression. Overall, the metabolic demands of hormonal stimulation and tumor growth are detectable using photon migration techniques. Measurements provide quantitative optical property values that reflect changes in tissue perfusion, oxygen consumption, and cell/matrix development.

Direct Characterization of Ultrafast Energy-Time Entangled Photon Pairs.

Science.gov (United States)

MacLean, Jean-Philippe W; Donohue, John M; Resch, Kevin J

2018-02-02

Energy-time entangled photons are critical in many quantum optical phenomena and have emerged as important elements in quantum information protocols. Entanglement in this degree of freedom often manifests itself on ultrafast time scales, making it very difficult to detect, whether one employs direct or interferometric techniques, as photon-counting detectors have insufficient time resolution. Here, we implement ultrafast photon counters based on nonlinear interactions and strong femtosecond laser pulses to probe energy-time entanglement in this important regime. Using this technique and single-photon spectrometers, we characterize all the spectral and temporal correlations of two entangled photons with femtosecond resolution. This enables the witnessing of energy-time entanglement using uncertainty relations and the direct observation of nonlocal dispersion cancellation on ultrafast time scales. These techniques are essential to understand and control the energy-time degree of freedom of light for ultrafast quantum optics.

Monte Carlo simulation of photon scattering in x-ray absorption imaging of high-intensity discharge lamps

Energy Technology Data Exchange (ETDEWEB)

Curry, J J, E-mail: jjcurry@nist.go [National Institute of Standards and Technology, Gaithersburg, MD 20899-8422 (United States)

2010-06-16

Coherent and incoherent scattering of x-rays during x-ray absorption imaging of high-intensity discharge lamps have been studied with Monte Carlo simulations developed specifically for this purpose. The Monte Carlo code is described and some initial results are discussed. Coherent scattering, because of its angular concentration in the forward direction, is found to be the most significant scattering mechanism. Incoherent scattering, although comparably strong, is not as significant because it results primarily in photons being scattered in the rearward direction and therefore out of the detector. Coherent scattering interferes with the detected absorption signal because the path of a scattered photon through the object to be imaged is unknown. Although scattering is usually a small effect, it can be significant in regions of high contrast. At the discharge/wall interface, as many as 50% of the detected photons are scattered photons. The effect of scattering on analysis of Hg distributions has not yet been quantified.

Two-photon anisotropy: Analytical description and molecular modeling for symmetrical and asymmetrical organic dyes

International Nuclear Information System (INIS)

Fu Jie; Przhonska, Olga V.; Padilha, Lazaro A.; Hagan, David J.; Van Stryland, Eric W.; Belfield, Kevin D.; Bondar, Mikhail V.; Slominsky, Yuriy L.; Kachkovski, Alexei D.

2006-01-01

One- and two-photon anisotropy spectra of a series of symmetrical and asymmetrical polymethine (PD) and fluorene molecules were measured experimentally and discussed theoretically within the framework of three-state and four-state models. For all the molecules discussed in this paper, the experimental two-photon anisotropy values, r 2PA , lie in the relatively narrow range from 0.47 to 0.57 and remain almost independent of wavelength over at least two electronic transitions. This is in contrast with their one-photon anisotropy, which shows strong wavelength dependence, typically varying from ∼0 to 0.38 over the same transitions. A detailed analysis of the two-photon absorption (2PA) processes allows us to conclude that a three-state model can explain the 2PA anisotropy spectra of most asymmetrical PDs and fluorenes. However, this model is inadequate for all the symmetrical molecules. Experimental values of r 2PA for symmetrical polymethines and fluorenes can be explained by symmetry breaking leading to the deviation of the orientation of the participating transition dipole moments from their 'classical' orientations

Multi-Photon Absorption Spectra: A Comparison Between Transmittance Change and Fluorescence Methods

Science.gov (United States)

2015-05-21

AFRL-OSR-VA-TR-2015-0134 multi-photon absorption spectra Cleber Mendonca INSTITUTO DE FISICA DE SAO CARLOS Final Report 05/21/2015 DISTRIBUTION A...5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) Instituto de Fisica de Sao Carlos - Universidade de Sao Paulo Av

Ultrabright narrow-band telecom two-photon source for long-distance quantum communication

Science.gov (United States)

Niizeki, Kazuya; Ikeda, Kohei; Zheng, Mingyang; Xie, Xiuping; Okamura, Kotaro; Takei, Nobuyuki; Namekata, Naoto; Inoue, Shuichiro; Kosaka, Hideo; Horikiri, Tomoyuki

2018-04-01

We demonstrate an ultrabright narrow-band two-photon source at the 1.5 µm telecom wavelength for long-distance quantum communication. By utilizing a bow-tie cavity, we obtain a cavity enhancement factor of 4.06 × 104. Our measurement of the second-order correlation function G (2)(τ) reveals that the linewidth of 2.4 MHz has been hitherto unachieved in the 1.5 µm telecom band. This two-photon source is useful for obtaining a high absorption probability close to unity by quantum memories set inside quantum repeater nodes. Furthermore, to the best of our knowledge, the observed spectral brightness of 3.94 × 105 pairs/(s·MHz·mW) is also the highest reported over all wavelengths.

Identification of CW two-photon transitions in Na2 and NaK

International Nuclear Information System (INIS)

Morgan, G.P.

1983-01-01

This thesis reports on the two-photon visible excitation spectra of sodium and potassium vapors. In the past, similar work has been performed on sodium and many atomic two-photon transitions have been characterized. However, many extra signals exist which do not possess the ground, 3S, state hyperfine splitting. These extra transitions are due to the sodium dimer Na 2 . 79 such transitions, from 5800A - 6500A, which lie within the resolution of the apparatus have been studied. The molecules are excited with a lowpower narrow band counterpropagating cw dye laser beam and two-photon fluorescence. The fluorescence intensities of many of these transitions are greater than the 3S to 5S and 3S to 4D atomic signals, where the 3P enhancing state lies 300 cm -1 from resonance. By comparing the number density of the atomic with any molecular ground state and also the two-photon transition rates to excited states, the intermediate enhancing state for a two-photon transition in Na 2 can be predicted to be less than 1 cm -1 from resonance with the two-photon transition. This observation, along with published Dunham coefficients, is used to identify the states involved in the two-photon transitions

Electron correlations and two-photon states in polycyclic aromatic hydrocarbon molecules: A peculiar role of geometry

Energy Technology Data Exchange (ETDEWEB)

Aryanpour, Karan [Department of Physics, University of Arizona, Tucson, Arizona 85721 (United States); Shukla, Alok [Department of Physics, Indian Institute of Technology, Powai, Mumbai 400076 (India); Mazumdar, Sumit [Department of Physics, University of Arizona, Tucson, Arizona 85721 (United States); College of Optical Sciences, University of Arizona, Tucson, Arizona 85721 (United States)

2014-03-14

We present numerical studies of one- and two-photon excited states ordering in a number of polycyclic aromatic hydrocarbon molecules: coronene, hexa-peri-hexabenzocoronene, and circumcoronene, all possessing D{sub 6h} point group symmetry versus ovalene with D{sub 2h} symmetry, within the Pariser-Parr-Pople model of interacting π-electrons. The calculated energies of the two-photon states as well as their relative two-photon absorption cross-sections within the interacting model are qualitatively different from single-particle descriptions. More remarkably, a peculiar role of molecular geometry is found. The consequence of electron correlations is far stronger for ovalene, where the lowest spin-singlet two-photon state is a quantum superposition of pairs of lowest spin triplet states, as in the linear polyenes. The same is not true for D{sub 6h} group hydrocarbons. Our work indicates significant covalent character, in valence bond language, of the ground state, the lowest spin triplet state and a few of the lowest two-photon states in D{sub 2h} ovalene but not in those with D{sub 6h} symmetry.

Electron correlations and two-photon states in polycyclic aromatic hydrocarbon molecules: A peculiar role of geometry

International Nuclear Information System (INIS)

Aryanpour, Karan; Shukla, Alok; Mazumdar, Sumit

2014-01-01

We present numerical studies of one- and two-photon excited states ordering in a number of polycyclic aromatic hydrocarbon molecules: coronene, hexa-peri-hexabenzocoronene, and circumcoronene, all possessing D 6h point group symmetry versus ovalene with D 2h symmetry, within the Pariser-Parr-Pople model of interacting π-electrons. The calculated energies of the two-photon states as well as their relative two-photon absorption cross-sections within the interacting model are qualitatively different from single-particle descriptions. More remarkably, a peculiar role of molecular geometry is found. The consequence of electron correlations is far stronger for ovalene, where the lowest spin-singlet two-photon state is a quantum superposition of pairs of lowest spin triplet states, as in the linear polyenes. The same is not true for D 6h group hydrocarbons. Our work indicates significant covalent character, in valence bond language, of the ground state, the lowest spin triplet state and a few of the lowest two-photon states in D 2h ovalene but not in those with D 6h symmetry

Electron correlations and two-photon states in polycyclic aromatic hydrocarbon molecules: a peculiar role of geometry.

Science.gov (United States)

Aryanpour, Karan; Shukla, Alok; Mazumdar, Sumit

2014-03-14

We present numerical studies of one- and two-photon excited states ordering in a number of polycyclic aromatic hydrocarbon molecules: coronene, hexa-peri-hexabenzocoronene, and circumcoronene, all possessing D(6h) point group symmetry versus ovalene with D(2h) symmetry, within the Pariser-Parr-Pople model of interacting π-electrons. The calculated energies of the two-photon states as well as their relative two-photon absorption cross-sections within the interacting model are qualitatively different from single-particle descriptions. More remarkably, a peculiar role of molecular geometry is found. The consequence of electron correlations is far stronger for ovalene, where the lowest spin-singlet two-photon state is a quantum superposition of pairs of lowest spin triplet states, as in the linear polyenes. The same is not true for D(6h) group hydrocarbons. Our work indicates significant covalent character, in valence bond language, of the ground state, the lowest spin triplet state and a few of the lowest two-photon states in D(2h) ovalene but not in those with D(6h) symmetry.

Far-Field Focus and Dispersionless Anticrossing Bands in Two-Dimensional Photonic Crystals

Directory of Open Access Journals (Sweden)

Xiaoshuang Chen

2007-01-01

Full Text Available We review the simulation work for the far-field focus and dispersionless anticrossing bands in two-dimensional (2D photonic crystals. In a two-dimensional photonic-crystal-based concave lens, the far-field focus of a plane wave is given by the distance between the focusing point and the lens. Strong and good-quality far-field focusing of a transmitted wave, explicitly following the well-known wave-beam negative refraction law, can be achieved. The spatial frequency information of the Bloch mode in multiple Brillouin zones (BZs is investigated in order to indicate the wave propagation in two different regions. When considering the photonic transmission in a 2D photonic crystal composed of a negative phase-velocity medium (NPVM, it is shown that the dispersionless anticrossing bands are generated by the couplings among the localized surface polaritons of the NPVM rods. The photonic band structures of the NPVM photonic crystals are characterized by a topographical continuous dispersion relationship accompanied by many anticrossing bands.

Thermally activated delayed fluorescence organic dots for two-photon fluorescence lifetime imaging

Science.gov (United States)

He, Tingchao; Ren, Can; Li, Zhuohua; Xiao, Shuyu; Li, Junzi; Lin, Xiaodong; Ye, Chuanxiang; Zhang, Junmin; Guo, Lihong; Hu, Wenbo; Chen, Rui

2018-05-01

Autofluorescence is a major challenge in complex tissue imaging when molecules present in the biological tissue compete with the fluorophore. This issue may be resolved by designing organic molecules with long fluorescence lifetimes. The present work reports the two-photon absorption (TPA) properties of a thermally activated delayed fluorescence (TADF) molecule with carbazole as the electron donor and dicyanobenzene as the electron acceptor (i.e., 4CzIPN). The results indicate that 4CzIPN exhibits a moderate TPA cross-section (˜9 × 10-50 cm4 s photon-1), high fluorescence quantum yield, and a long fluorescence lifetime (˜1.47 μs). 4CzIPN was compactly encapsulated into an amphiphilic copolymer via nanoprecipitation to achieve water-soluble organic dots. Interestingly, 4CzIPN organic dots have been utilized in applications involving two-photon fluorescence lifetime imaging (FLIM). Our work aptly demonstrates that TADF molecules are promising candidates of nonlinear optical probes for developing next-generation multiphoton FLIM applications.

Two-photon interference : spatial aspects of two-photon entanglement, diffraction, and scattering

NARCIS (Netherlands)

Peeters, Wouter Herman

2010-01-01

This dissertation contains scientific research within the realm of quantum optics, which is a branch of physics. An experimental and theoretical study is made of two-photon interference phenomena in various optical systems. Spatially entangled photon pairs are produced via the nonlinear optical

Concentration of atomic hydrogen in a dielectric barrier discharge measured by two-photon absorption fluorescence

Science.gov (United States)

Dvořák, P.; Talába, M.; Obrusník, A.; Kratzer, J.; Dědina, J.

2017-08-01

Two-photon absorption laser-induced fluorescence (TALIF) was utilized for measuring the concentration of atomic hydrogen in a volume dielectric barrier discharge (DBD) ignited in mixtures of Ar, H2 and O2 at atmospheric pressure. The method was calibrated by TALIF of krypton diluted in argon at atmospheric pressure, proving that three-body collisions had a negligible effect on quenching of excited krypton atoms. The diagnostic study was complemented with a 3D numerical model of the gas flow and a zero-dimensional model of the chemistry in order to better understand the reaction kinetics and identify the key pathways leading to the production and destruction of atomic hydrogen. It was determined that the density of atomic hydrogen in Ar-H2 mixtures was in the order of 1021 m-3 and decreased when oxygen was added into the gas mixture. Spatially resolved measurements and simulations revealed a sharply bordered region with low atomic hydrogen concentration when oxygen was added to the gas mixture. At substoichiometric oxygen/hydrogen ratios, this H-poor region is confined to an area close to the gas inlet and it is shown that the size of this region is not only influenced by the chemistry but also by the gas flow patterns. Experimentally, it was observed that a decrease in H2 concentration in the feeding Ar-H2 mixture led to an increase in H production in the DBD.

Distribution of quantum information between an atom and two photons

International Nuclear Information System (INIS)

Weber, Bernhard

2008-01-01

The construction of networks consisting of optically interconnected processing units is a promising way to scale up quantum information processing systems. To store quantum information, single trapped atoms are among the most proven candidates. By placing them in high finesse optical resonators, a bidirectional information exchange between the atoms and photons becomes possible with, in principle, unit efficiency. Such an interface between stationary and ying qubits constitutes a possible node of a future quantum network. The results presented in this thesis demonstrate the prospects of a quantum interface consisting of a single atom trapped within the mode of a high-finesse optical cavity. In a two-step process, we distribute entanglement between the stored atom and two subsequently emitted single photons. The long atom trapping times achieved in the system together with the high photon collection efficiency of the cavity make the applied protocol in principle deterministic, allowing for the creation of an entangled state at the push of a button. Running the protocol on this quasi-stationary quantum interface, the internal state of the atom is entangled with the polarization state of a single emitted photon. The entanglement is generated by driving a vacuum-stimulated Raman adiabatic passage between states of the coupled atom-cavity system. In a second process, the atomic part of the entangled state is mapped onto a second emitted photon using a similar technique and resulting in a polarization-entangled two-photon state. To verify and characterize the photon-photon entanglement, we measured a violation of a Bell inequality and performed a full quantum state tomography. The results prove the prior atom-photon entanglement and demonstrate a quantum information transfer between the atom and the two emitted photons. This reflects the advantages of a high-finesse cavity as a quantum interface in future quantum networks. (orig.)

Distribution of quantum information between an atom and two photons

Energy Technology Data Exchange (ETDEWEB)

Weber, Bernhard

2008-11-03

The construction of networks consisting of optically interconnected processing units is a promising way to scale up quantum information processing systems. To store quantum information, single trapped atoms are among the most proven candidates. By placing them in high finesse optical resonators, a bidirectional information exchange between the atoms and photons becomes possible with, in principle, unit efficiency. Such an interface between stationary and ying qubits constitutes a possible node of a future quantum network. The results presented in this thesis demonstrate the prospects of a quantum interface consisting of a single atom trapped within the mode of a high-finesse optical cavity. In a two-step process, we distribute entanglement between the stored atom and two subsequently emitted single photons. The long atom trapping times achieved in the system together with the high photon collection efficiency of the cavity make the applied protocol in principle deterministic, allowing for the creation of an entangled state at the push of a button. Running the protocol on this quasi-stationary quantum interface, the internal state of the atom is entangled with the polarization state of a single emitted photon. The entanglement is generated by driving a vacuum-stimulated Raman adiabatic passage between states of the coupled atom-cavity system. In a second process, the atomic part of the entangled state is mapped onto a second emitted photon using a similar technique and resulting in a polarization-entangled two-photon state. To verify and characterize the photon-photon entanglement, we measured a violation of a Bell inequality and performed a full quantum state tomography. The results prove the prior atom-photon entanglement and demonstrate a quantum information transfer between the atom and the two emitted photons. This reflects the advantages of a high-finesse cavity as a quantum interface in future quantum networks. (orig.)

One- and two-photon spectra of Nd3+ clusters in CaF2 and SrF2 crystals

International Nuclear Information System (INIS)

Basiev, Tasoltan T; Voronov, Valerii V; Glotova, M Yu; Papashvili, A G; Karasik, Aleksandr Ya

2003-01-01

The polarised two-photon (IR) and one-photon (visible) luminescence excitation spectra of Nd 3+ nanoclusters in CaF 2 and SrF 2 crystals are measured at 10 K using a F - 2 :LiF colour centre laser tunable in spectral ranges 1090 - 1230 nm and 545 - 615 nm with an emission linewidth of ∼0.02 - 0.03 cm -1 , an average output power of ∼55 mW, and a pulse repetition rate of 10 Hz. The two-photon excitation spectra at the 4 I 9/2 → 4 G 5/2 transition reveal the structure, which is absent upon one-photon excitation, which can be explained by different selection rules for some Stark - Stark transitions upon one- and two-photon absorption. (special issue devoted to the memory of academician a m prokhorov)

Characterization of photonic structures using visible and infrared polarimetry

Directory of Open Access Journals (Sweden)

Kral Z.

2010-06-01

Full Text Available Photonic Crystals are materials with a spatial periodic variation of the refractive index on the wavelength scale. This confers these materials interesting photonic properties such as the existence of photonic bands and forbidden photon frequency ranges, the photonic band gaps. Among their applications it is worth mentioning the achievement of low-threshold lasers and high-Q resonant cavities. A particular case of the Photonic Crystals is well-known and widely studied since a long time: the periodic thin film coatings. The characterization of thin film coatings is a classical field of study with a very well established knowledge. However, characterization of 2D and 3D photonic crystals needs to be studied in detail as it poses new problems that have to be solved. In this sense, Polarimetry is a specially suited tool given their inherent anisotropy: photonic bands depend strongly on the propagation direction and on polarization. In this work we show how photonic crystal structures can be characterized using polarimetry equipment. We compare the numerical modeling of the interaction of the light polarization with the photonic crystal with the polarimetry measurements. With the S-Matrix formalism, the Mueller matrix of a Photonic Crystal for a given wavelength, angle of incidence and propagation direction can be obtained. We will show that useful information from polarimetry (and also from spectrometry can be obtained when multivariate spectra are considered. We will also compare the simulation results with Polarimetry measurements on different kinds of samples: macroporous silicon photonic crystals in the near-IR range and Laser-Interference-Lithography nanostructured photoresist.

Resonant absorption in semiconductor nanowires and nanowire arrays: Relating leaky waveguide modes to Bloch photonic crystal modes

Energy Technology Data Exchange (ETDEWEB)

Fountaine, Katherine T., E-mail: kfountai@caltech.edu [Department of Chemistry and Chemical Engineering, California Institute of Technology, 1200 E. California Blvd., Pasadena, California 91125 (United States); Joint Center for Artificial Photosynthesis, California Institute of Technology, 1200 E. California Blvd., Pasadena, California 91125 (United States); Whitney, William S. [Joint Center for Artificial Photosynthesis, California Institute of Technology, 1200 E. California Blvd., Pasadena, California 91125 (United States); Department of Physics, California Institute of Technology, 1200 E. California Blvd., Pasadena, California 91125 (United States); Atwater, Harry A. [Joint Center for Artificial Photosynthesis, California Institute of Technology, 1200 E. California Blvd., Pasadena, California 91125 (United States); Department of Applied Physics and Materials Science, California Institute of Technology, 1200 E. California Blvd., Pasadena, California 91125 (United States)

2014-10-21

We present a unified framework for resonant absorption in periodic arrays of high index semiconductor nanowires that combines a leaky waveguide theory perspective and that of photonic crystals supporting Bloch modes, as array density transitions from sparse to dense. Full dispersion relations are calculated for each mode at varying illumination angles using the eigenvalue equation for leaky waveguide modes of an infinite dielectric cylinder. The dispersion relations along with symmetry arguments explain the selectivity of mode excitation and spectral red-shifting of absorption for illumination parallel to the nanowire axis in comparison to perpendicular illumination. Analysis of photonic crystal band dispersion for varying array density illustrates that the modes responsible for resonant nanowire absorption emerge from the leaky waveguide modes.

Random Photon Absorption Model Elucidates How Early Gain Control in Fly Photoreceptors Arises from Quantal Sampling

Science.gov (United States)

Song, Zhuoyi; Zhou, Yu; Juusola, Mikko

2016-01-01

Many diurnal photoreceptors encode vast real-world light changes effectively, but how this performance originates from photon sampling is unclear. A 4-module biophysically-realistic fly photoreceptor model, in which information capture is limited by the number of its sampling units (microvilli) and their photon-hit recovery time (refractoriness), can accurately simulate real recordings and their information content. However, sublinear summation in quantum bump production (quantum-gain-nonlinearity) may also cause adaptation by reducing the bump/photon gain when multiple photons hit the same microvillus simultaneously. Here, we use a Random Photon Absorption Model (RandPAM), which is the 1st module of the 4-module fly photoreceptor model, to quantify the contribution of quantum-gain-nonlinearity in light adaptation. We show how quantum-gain-nonlinearity already results from photon sampling alone. In the extreme case, when two or more simultaneous photon-hits reduce to a single sublinear value, quantum-gain-nonlinearity is preset before the phototransduction reactions adapt the quantum bump waveform. However, the contribution of quantum-gain-nonlinearity in light adaptation depends upon the likelihood of multi-photon-hits, which is strictly determined by the number of microvilli and light intensity. Specifically, its contribution to light-adaptation is marginal (≤ 1%) in fly photoreceptors with many thousands of microvilli, because the probability of simultaneous multi-photon-hits on any one microvillus is low even during daylight conditions. However, in cells with fewer sampling units, the impact of quantum-gain-nonlinearity increases with brightening light. PMID:27445779

Secured Optical Communications Using Quantum Entangled Two-Photon Transparency Modulation

Science.gov (United States)

Kojima, Jun (Inventor); Nguyen, Quang-Viet (Inventor); Lekki, John (Inventor)

2015-01-01

A system and method is disclosed wherein optical signals are coded in a transmitter by tuning or modulating the interbeam delay time (which modulates the fourth-order coherence) between pairs of entangled photons. The photon pairs are either absorbed or not absorbed (transparent) by an atomic or molecular fluorescer in a receiver, depending on the inter-beam delay that is introduced in the entangled photon pairs. Upon the absorption, corresponding fluorescent optical emissions follow at a certain wavelength, which are then detected by a photon detector. The advantage of the disclosed system is that it eliminates a need of a coincidence counter to realize the entanglement-based secure optical communications because the absorber acts as a coincidence counter for entangled photon pairs.

Direct and quantitative photothermal absorption spectroscopy of individual particulates

International Nuclear Information System (INIS)

Tong, Jonathan K.; Hsu, Wei-Chun; Eon Han, Sang; Burg, Brian R.; Chen, Gang; Zheng, Ruiting; Shen, Sheng

2013-01-01

Photonic structures can exhibit significant absorption enhancement when an object's length scale is comparable to or smaller than the wavelength of light. This property has enabled photonic structures to be an integral component in many applications such as solar cells, light emitting diodes, and photothermal therapy. To characterize this enhancement at the single particulate level, conventional methods have consisted of indirect or qualitative approaches which are often limited to certain sample types. To overcome these limitations, we used a bilayer cantilever to directly and quantitatively measure the spectral absorption efficiency of a single silicon microwire in the visible wavelength range. We demonstrate an absorption enhancement on a per unit volume basis compared to a thin film, which shows good agreement with Mie theory calculations. This approach offers a quantitative approach for broadband absorption measurements on a wide range of photonic structures of different geometric and material compositions

Holographic Two-Photon Induced Photopolymerization

Data.gov (United States)

Federal Laboratory Consortium — Holographic two-photon-induced photopolymerization (HTPIP) offers distinct advantages over conventional one-photon-induced photopolymerization and current techniques...

Deep and tapered silicon photonic crystals for achieving anti-reflection and enhanced absorption.

Science.gov (United States)

Hung, Yung-Jr; Lee, San-Liang; Coldren, Larry A

2010-03-29

Tapered silicon photonic crystals (PhCs) with smooth sidewalls are realized using a novel single-step deep reactive ion etching. The PhCs can significantly reduce the surface reflection over the wavelength range between the ultra-violet and near-infrared regions. From the measurements using a spectrophotometer and an angle-variable spectroscopic ellipsometer, the sub-wavelength periodic structure can provide a broad and angular-independent antireflective window in the visible region for the TE-polarized light. The PhCs with tapered rods can further reduce the reflection due to a gradually changed effective index. On the other hand, strong optical resonances for TM-mode can be found in this structure, which is mainly due to the existence of full photonic bandgaps inside the material. Such resonance can enhance the optical absorption inside the silicon PhCs due to its increased optical paths. With the help of both antireflective and absorption-enhanced characteristics in this structure, the PhCs can be used for various applications.

Mass attenuation and mass energy absorption coefficients for 10 keV to 10 MeV photons; Coefficients d'attenuation massique et d'absorption massique en energie pour les photons de 10 keV a 10 MeV

Energy Technology Data Exchange (ETDEWEB)

Joffre, H; Pages, L [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1968-07-01

In this report are given the elements allowing the definition of the values of mass attenuation coefficients and mass energy absorption coefficients for some elements and mixtures, necessary for the study of tissue equivalent materials, for photons in the energy range 10 keV to 10 MeV. After a short reminding of the definitions of the two coefficients, follows, in table form, a compilation of these coefficients, as a function of energy, for simple elements, for certain mineral compounds, organic compounds, gases and particularly of soft tissues. (author) [French] Dans ce rapport, sont donnes les elements permettant de determiner les valeurs des coefficients d'attenuation massique et d'absorption massique en energie pour certains elements et melanges necessaires a l'etude des materiaux equivalents aux tissus pour les photons dans le domaine d'energie allant de 10 keV a 10 MeV. Apres un bref rappel des definitions des deux coefficients, suit, sous forme de tableaux, un recueil de ces coefficients, en fonction de l'energie, pour les elements simples, certains composes mineraux, composes organiques, gaz, et, particulierement, pour les tissus mous. (auteur)

Extreme nonlinearities in InAs/InP nanowire gain media: the two-photon induced laser

DEFF Research Database (Denmark)

Capua, Amir; Kami, Ouri; Eisenstein, Gadi

2012-01-01

We demonstrate a novel laser oscillation scheme in an InAs / InP wire-like quantum dash gain medium. A short optical pulse excites carriers by two photon absorption which relax to the energy levels providing gain thereby enabling laser oscillations. The nonlinear dynamic interaction is analyzed a...

A review of two photon physics

International Nuclear Information System (INIS)

Cooper, S.

1982-08-01

This talk is intended as an introduction for those not yet expert in two-photon physics, especially those e + e - one-photon physicists who still think of two-photon events as background. I concentrate on the physics questions involved, especially emphasizing the areas where I feel progress can be made in the near future, and of necessity leaving most experimental details to be found in the references. After a quick survey of the field and a few words about kinematics, I discuss in detail two major fields: the photon structure function and resonance production. (orig.)

Quantum entanglement and phase transition in a two-dimensional photon-photon pair model

International Nuclear Information System (INIS)

Zhang Jianjun; Yuan Jianhui; Zhang Junpei; Cheng Ze

2013-01-01

We propose a two-dimensional model consisting of photons and photon pairs. In the model, the mixed gas of photons and photon pairs is formally equivalent to a two-dimensional system of massive bosons with non-vanishing chemical potential, which implies the existence of two possible condensate phases. Using the variational method, we discuss the quantum phase transition of the mixed gas and obtain the critical coupling line analytically. Moreover, we also find that the phase transition of the photon gas can be interpreted as enhanced second harmonic generation. We then discuss the entanglement between photons and photon pairs. Additionally, we also illustrate how the entanglement between photons and photon pairs can be associated with the phase transition of the system.

Two-photon superradiance in extended medium

International Nuclear Information System (INIS)

Branzan, V.; Enache, N.

1993-01-01

The possibility of collectivization of an ensemble of atoms of an extended system (the distance between atoms is larger or equal to the wave-length of a spontaneous emitted radiation) during two-photon spontaneous decay is theoretically investigated. It is demonstrated that such systems of inverted atoms should emit phase-correlated pairs of photons. The time-space correlation among atoms is realized due to the two-photon exchanging through the electromagnetic field's vacuum. An increase of the spontaneous decay rate of the two-atom inverted ensemble is demonstrated. The dependence of two-photon superradiance on the sample geometry is investigated. A non-equilibrium method of the elimination of the atoms level Fermi-operators is proposed. (Author)

Two Photon Distribution Amplitudes

International Nuclear Information System (INIS)

El Beiyad, M.; Pire, B.; Szymanowski, L.; Wallon, S.

2008-01-01

The factorization of the amplitude of the process γ*γ→γγ in the low energy and high photon virtuality region is demonstrated at the Born order and in the leading logarithmic approximation. The leading order two photon (generalized) distribution amplitudes exhibit a characteristic ln Q 2 behaviour and obey new inhomogeneous evolution equations

Enhanced two-photon emission from a dressed biexciton

International Nuclear Information System (INIS)

Sánchez Muñoz, Carlos; Laussy, Fabrice P; Tejedor, Carlos; Valle, Elena del

2015-01-01

Radiative two-photon cascades from biexcitons in semiconductor quantum dots under resonant two-photon excitation are promising candidates for the generation of photon pairs. In this work, we propose a scheme to obtain two-photon emission that allows us to operate under very intense driving fields. This approach relies on the Purcell enhancement of two-photon virtual transitions between states of the biexciton dressed by the laser. The richness provided by the biexcitonic level structure allows to reach a variety of regimes, from antibunched and bunched photon pairs with polarization orthogonal to the driving field, to polarization entangled two-photon emission. This provides evidence that the general paradigm of two-photon emission from a ladder of dressed states can find interesting, particular implementations in a variety of systems. (paper)

Design and synthesis of hyperstructured molecules based on cyclophosphazene core for multiphoton absorption

International Nuclear Information System (INIS)

Naik, K. Praveen Kumar; Sreeramulu, V.; Ramya, E.; Muralidharan, K.; Rao, D. Narayana

2016-01-01

Cyclophosphazene based hyperstructured molecules were synthesized through simple nucleophilic substitution reactions. All these molecules were characterized by multinuclear NMR, MALDI and HRMS spectral data. Third order nonlinear optical properties of the hyperstructured molecules were measured using Z-scan technique with 532 nm, picosecond (ps) laser and 800 nm, femtosecond (fs) laser pulses. The molecules showed reverse saturable absorption on excitation at both 532 nm and 800 nm, which could be attributed to the two-photon absorption (2 PA) and three-photon absorption (3 PA), respectively. The 2 PA and 3 PA cross section values exhibited by the molecules based on cyclophosphazene are as high as 527 GM and 1.86 × 10"−"7"6 cm"−"6 s"2 photon"−"1, respectively. The 2PA, 3PA coefficients and optical limiting properties make them suitable candidates for nonlinear optical devices in the visible and near IR range. - Graphical abstract: The hyperstructured molecules based on cyclophosphazene core were synthesized and used for multiphoton absorption. Open aperture Z-scan curves of hyper structured molecules at the excitation of (a) picosecond laser and (b) femtosecond laser representing multiphoton absorption properties are reported. - Highlights: • Two hyperstructured molecules based on cyclophosphazene core are designed for multiphoton absorption. • NLO properties are measured using Z-scan technique at 532 nm and 800 nm wavelengths. • The molecules were tested for the optical limiting applications at 532 nm and 800 nm laser pulses.

Design and synthesis of hyperstructured molecules based on cyclophosphazene core for multiphoton absorption

Energy Technology Data Exchange (ETDEWEB)

Naik, K. Praveen Kumar [School of Chemistry, University of Hyderabad, Hyderabad 500046 India (India); Sreeramulu, V. [School of Physics, University of Hyderabad, Hyderabad 500046 India (India); CNR-IFN CSMFO Laboratory, Via alla Cascata, 56/C Povo, Trento (Italy); Ramya, E. [School of Physics, University of Hyderabad, Hyderabad 500046 India (India); Muralidharan, K., E-mail: murali@uohyd.ac.in [School of Chemistry, University of Hyderabad, Hyderabad 500046 India (India); Rao, D. Narayana [School of Physics, University of Hyderabad, Hyderabad 500046 India (India)

2016-09-01

Cyclophosphazene based hyperstructured molecules were synthesized through simple nucleophilic substitution reactions. All these molecules were characterized by multinuclear NMR, MALDI and HRMS spectral data. Third order nonlinear optical properties of the hyperstructured molecules were measured using Z-scan technique with 532 nm, picosecond (ps) laser and 800 nm, femtosecond (fs) laser pulses. The molecules showed reverse saturable absorption on excitation at both 532 nm and 800 nm, which could be attributed to the two-photon absorption (2 PA) and three-photon absorption (3 PA), respectively. The 2 PA and 3 PA cross section values exhibited by the molecules based on cyclophosphazene are as high as 527 GM and 1.86 × 10{sup −76} cm{sup −6} s{sup 2} photon{sup −1}, respectively. The 2PA, 3PA coefficients and optical limiting properties make them suitable candidates for nonlinear optical devices in the visible and near IR range. - Graphical abstract: The hyperstructured molecules based on cyclophosphazene core were synthesized and used for multiphoton absorption. Open aperture Z-scan curves of hyper structured molecules at the excitation of (a) picosecond laser and (b) femtosecond laser representing multiphoton absorption properties are reported. - Highlights: • Two hyperstructured molecules based on cyclophosphazene core are designed for multiphoton absorption. • NLO properties are measured using Z-scan technique at 532 nm and 800 nm wavelengths. • The molecules were tested for the optical limiting applications at 532 nm and 800 nm laser pulses.

Effective atomic numbers for photon energy absorption of essential amino acids in the energy range 1 keV to 20 MeV

International Nuclear Information System (INIS)

Manohara, S.R.; Hanagodimath, S.M.

2007-01-01

Effective atomic numbers for photon energy-absorption (Z PEAeff ) of essential amino acids histidine, leucine, lysine, methionine, phenylalanine, threonine, tryptophan and valine have been calculated by a direct method in the energy region of 1 keV to 20 MeV. The Z PEAeff values have been found to change with energy and composition of the amino acids. The variations of mass energy-absorption coefficient, effective atomic number for photon interaction (Z PIeff ) and Z PEAeff with energy are shown graphically. Significant differences exist between Z PIeff and the Z PEAeff in the energy region of 8-100 keV for histidine and threonine; 6-100 keV for leucine, lysine, tryptophan, phenylalanine and valine; 15-400 keV for methionine. The effect of absorption edge on effective atomic numbers and the possibility of defining two set values of these parameters at the K-absorption edge of high-Z element present in the amino acids are discussed. The reasons for using Z PEAeff rather than the commonly used Z PIeff in medical radiation dosimetry for the calculation of absorbed dose in radiation therapy are also discussed

Thrust distribution of two-jet like events at a photon-photon collider

International Nuclear Information System (INIS)

Kanakubo, Fumiko

1995-01-01

One of the advantages of using a photon-photon collision with the same helicity is that the continuum qq-bar production is suppressed at the lowest order (α s 0 ). However, the helicity suppression does not take place for the gluon radiation process, and qq-barg can be two-jet like. We evaluate the cross sections of the two-jet like events in a photon-photon collision, and present the thrust distributions. We take into account the QCD effect to all orders in α s in the leading-double-log approximation, and show the suppression due to this effect. The evaluation with the energy and the polarization distributions of the photon suggests that the contaminating photons with the opposite helicity contribute dominantly to the two-jet like process. (author)

Photon statistical properties of photon-added two-mode squeezed coherent states

International Nuclear Information System (INIS)

Xu Xue-Fen; Wang Shuai; Tang Bin

2014-01-01

We investigate photon statistical properties of the multiple-photon-added two-mode squeezed coherent states (PA-TMSCS). We find that the photon statistical properties are sensitive to the compound phase involved in the TMSCS. Our numerical analyses show that the photon addition can enhance the cross-correlation and anti-bunching effects of the PA-TMSCS. Compared with that of the TMSCS, the photon number distribution of the PA-TMSCS is modulated by a factor that is a monotonically increasing function of the numbers of adding photons to each mode; further, that the photon addition essentially shifts the photon number distribution. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

Absorption imaging of a quasi-two-dimensional gas: a multiple scattering analysis

International Nuclear Information System (INIS)

Chomaz, L; Corman, L; Yefsah, T; Desbuquois, R; Dalibard, J

2012-01-01

Absorption imaging with quasi-resonant laser light is a commonly used technique for probing ultra-cold atomic gases in various geometries. In this paper, we investigate some non-trivial aspects of this method when applying the method to in situ diagnosis of a quasi-two-dimensional (2D) gas. Using Monte Carlo simulations we study the modification of the absorption cross-section of a photon when it undergoes multiple scattering in the gas. We determine the variations of the optical density with various parameters, such as the detuning of the light from the atomic resonance and the thickness of the gas. We compare our results to the known 3D result (the Beer-Lambert law) and outline the specific features of the 2D case. (paper)

Quantitative mineral salt evaluation in the calcaneous bone using computed tomography, 125I-photon absorption and chemical analysis to compare the value of the individual methods

International Nuclear Information System (INIS)

Hitzler, H.J.

1983-01-01

It was the aim of the study described here to verify the accuracy of two different methods for the quantitative evaluation of mineral salts, which were the 125I-photon absorption technique on the one hand and wholebody CT on the other hand. For this purpose, post-mortem examinations of 31 calcaneous bones were carried out to evaluate their individual mineral salt contents in vitro using either of the above-mentioned methods. The results obtained were subsequently contrasted with calcium concentrations determined by chemical analysis. A comparison of the individual mineral salt evaluations with the results from calcium analyses pointed to a highly significant correlation (p=0.001) for both methods under investigation. The same held for the correlation of findings from CT and the 125I-hydroxylapatite technique, where the level of significance was also p=0.001. The above statements must, however, be modified in as much as the mineral salt values measured by CT were consistently lower than those obtained on the basis of 125I-photon absorption. These deviations are chiefly attributable to the fact that the values provided by CT are more susceptible to influences from the fat contained in the bones. In 125I-photon absorption a special formula may be derived to allow for the bias occurring here, provided that the composition of the bone is known. To summarise, the relative advantages and drawbacks of CT and 125I-photon absorption are carefully balanced. Mineral salt evaluations by CT permit incipient losses to be ascertained even in the trunk. The 125I-photon absorption technique would appear to be the obvious method for any kind of follow-up examination in the peripheral skeleton, as it is easily reproducible and radiation exposure can be kept to minimum. (TRV) [de

Two-photon processes in highly charged ions

International Nuclear Information System (INIS)

Jahrsetz, Thorsten

2015-01-01

Two-photon processes are atomic processes in which an atom interacts simultaneously with two photons. Such processes describe a wide range of phenomena, such as two-photon decay and elastic or inelastic scattering of photons. In recent years two-photon processes involving highly charged heavy ions have become an active area of research. Such studies do not only consider the total transition or scattering rates but also their angular and polarization dependence. To support such examinations in this thesis I present a theoretical framework to describe these properties in all two-photon processes with bound initial and final states and involving heavy H-like or He-like ions. I demonstrate how this framework can be used in some detailed studies of different two-photon processes. Specifically a detailed analysis of two-photon decay of H-like and He-like ions in strong external electromagnetic fields shows the importance of considering the effect of such fields for the physics of such systems. Furthermore I studied the elastic Rayleigh as well as inelastic Raman scattering by heavy H-like ions. I found a number of previously unobserved phenomena in the angular and polarization dependence of the scattering cross-sections that do not only allow to study interesting details of the electronic structure of the ion but might also be useful for the measurement of weak physical effects in such systems.

Two-photon processes in highly charged ions

Energy Technology Data Exchange (ETDEWEB)

Jahrsetz, Thorsten

2015-03-05

Two-photon processes are atomic processes in which an atom interacts simultaneously with two photons. Such processes describe a wide range of phenomena, such as two-photon decay and elastic or inelastic scattering of photons. In recent years two-photon processes involving highly charged heavy ions have become an active area of research. Such studies do not only consider the total transition or scattering rates but also their angular and polarization dependence. To support such examinations in this thesis I present a theoretical framework to describe these properties in all two-photon processes with bound initial and final states and involving heavy H-like or He-like ions. I demonstrate how this framework can be used in some detailed studies of different two-photon processes. Specifically a detailed analysis of two-photon decay of H-like and He-like ions in strong external electromagnetic fields shows the importance of considering the effect of such fields for the physics of such systems. Furthermore I studied the elastic Rayleigh as well as inelastic Raman scattering by heavy H-like ions. I found a number of previously unobserved phenomena in the angular and polarization dependence of the scattering cross-sections that do not only allow to study interesting details of the electronic structure of the ion but might also be useful for the measurement of weak physical effects in such systems.

Variation of energy absorption buildup factors with incident photon energy and penetration depth for some commonly used solvents

International Nuclear Information System (INIS)

Singh, Parjit S.; Singh, Tejbir; Kaur, Paramjeet

2008-01-01

G.P. fitting method has been used to compute energy absorption buildup factor of some commonly used solvents such as acetonitrile (C 4 H 3 N), butanol (C 4 H 9 OH), chlorobenzene (C 6 H 5 Cl), diethyl ether (C 4 H 10 O), ethanol (C 2 H 5 OH), methanol (CH 3 OH), propanol (C 3 H 7 OH) and water (H 2 O) for the wide energy range (0.015-15.0 MeV) up to the penetration depth of 10 mean free path. The variation of energy absorption buildup factor with chemical composition as well as incident photon energy for the selected solvents has been studied. It has been observed that the maximum value of energy absorption buildup factors shifts to the slightly higher incident photon energy with the increase in equivalent atomic number of the solvent and the solvent with least equivalent atomic number possesses the maximum value of energy absorption buildup factor

Electromagnetic Wave Propagation in Two-Dimensional Photonic Crystals

Energy Technology Data Exchange (ETDEWEB)

Foteinopoulou, Stavroula [Iowa State Univ., Ames, IA (United States)

2003-01-01

In this dissertation, they have undertaken the challenge to understand the unusual propagation properties of the photonic crystal (PC). The photonic crystal is a medium where the dielectric function is periodically modulated. These types of structures are characterized by bands and gaps. In other words, they are characterized by frequency regions where propagation is prohibited (gaps) and regions where propagation is allowed (bands). In this study they focus on two-dimensional photonic crystals, i.e., structures with periodic dielectric patterns on a plane and translational symmetry in the perpendicular direction. They start by studying a two-dimensional photonic crystal system for frequencies inside the band gap. The inclusion of a line defect introduces allowed states in the otherwise prohibited frequency spectrum. The dependence of the defect resonance state on different parameters such as size of the structure, profile of incoming source, etc., is investigated in detail. For this study, they used two popular computational methods in photonic crystal research, the Finite Difference Time Domain method (FDTD) and the Transfer Matrix Method (TMM). The results for the one-dimensional defect system are analyzed, and the two methods, FDTD and TMM, are compared. Then, they shift their attention only to periodic two-dimensional crystals, concentrate on their band properties, and study their unusual refractive behavior. Anomalous refractive phenomena in photonic crystals included cases where the beam refracts on the ''wrong'' side of the surface normal. The latter phenomenon, is known as negative refraction and was previously observed in materials where the wave vector, the electric field, and the magnetic field form a left-handed set of vectors. These materials are generally called left-handed materials (LHM) or negative index materials (NIM). They investigated the possibility that the photonic crystal behaves as a LHM, and how this behavior relates

Sublinear absorption in OCS gas

International Nuclear Information System (INIS)

Bogani, F.; Querzoli, R.; Ernst, K.

1988-01-01

Sublinear absorption in OCS gas has been experimentally studied in detail by means of an optoacustic technique and transmission measurements. The best fit of the results is obtained by a phenomenological model, that considers the process as the sum of one-and two-photon absorptions

Two-photon stimulated emission and pulse amplification

International Nuclear Information System (INIS)

Yuen, H.P.

1975-01-01

Threshold conditions are given for the sustained operation of standing-wave and long-pulse traveling-wave two-photon lasers. Pulse shortening in long-pulse two-photon amplification, a behavior absent in the one-photon case, is also demonstrated analytically. (U.S.)

The mechanism and properties of bio-photon emission and absorption in protein molecules in living systems

Science.gov (United States)

Pang, Xiao-feng

2012-05-01

The mechanism and properties of bio-photon emission and absorption in bio-tissues were studied using Pang's theory of bio-energy transport, in which the energy spectra of protein molecules are obtained from the discrete dynamic equation. From the energy spectra, it was determined that the protein molecules could both radiate and absorb bio-photons with wavelengths of energy level transitions of the excitons. These results were consistent with the experimental data; this consisted of infrared absorption data from collagen, bovine serum albumin, the protein-like molecule acetanilide, plasma, and a person's finger, and the laser-Raman spectra of acidity I-type collagen in the lungs of a mouse, and metabolically active Escherichia coli. We further elucidated the mechanism responsible for the non-thermal biological effects produced by the infrared light absorbed by the bio-tissues, using the above results. No temperature rise was observed; instead, the absorbed infrared light promoted the vibrations of amides as well the transport of the bio-energy from one place to other in the protein molecules, which changed their conformations. These experimental results, therefore, not only confirmed the validity of the mechanism of bio-photon emission, and the newly developed theory of bio-energy transport mentioned above, but also explained the mechanism and properties of the non-thermal biological effects produced by the absorption of infrared light by the living systems.

New experiments call for a continuous absorption alternative to the photon model

Science.gov (United States)

Reiter, Eric S.

2015-09-01

A famous beam-split coincidence test of the photon model is described herein using gamma-rays instead of the usual visible light. A similar a new test was performed using alpha-rays. In both tests, coincidence rates greatly exceed chance, leading to an unquantum effect. In contradiction to quantum theory and the photon model, these new results are strong evidence of the long abandoned accumulation hypothesis, also known as the loading theory. Attention is drawn to assumptions applied to past key-experiments that led to quantum mechanics. The history of the loading theory is outlined, and a few equations for famous experiments are derived, now free of wave-particle duality. Quantum theory usually works because there is a subtle difference between quantized and thresholded absorption.

Review of Two-Photon Interactions

International Nuclear Information System (INIS)

Urner, David

2004-01-01

Presented are recent results of two-photon interactions. Topics include photon structure functions, inclusive hadron production, differential cross sections derived from tagged γγ fusion events and results in exclusive hadron production, particularly the observations of the η'c

Sensitive measurement of nonlinear absorption and optical limiting in undoped and Fe-doped ZnO quantum dots using pulsed laser

Science.gov (United States)

Sharma, D.; Malik, B. P.; Gaur, A.

2016-11-01

Zinc oxide quantum dots (QDs) with Fe-doping at different concentrations were prepared by chemical co-precipitation method. The prepared QDs were characterized by UV-Vis spectroscopy, X-ray diffraction and Z-scan technique. The sizes of QDs were found to be within 4.6-6.6 nm range. The nonlinear parameters viz. two-photon absorption coefficient (βTPA) and two-photon absorption cross-section (σTPA) were extracted with the help of open aperture Z-scan technique using nanosecond Nd:YAG laser operating at wavelength 532 nm. Higher values of βTPA and σTPA for Fe doped ZnO implied that they were potential materials for development of photonics devices and sensor protection applications. Fe doped sample (3 % by wt) was found to be the best optical limiter with limiting threshold intensity of 0.64 TW/cm2.

A method for characterizing photon radiation fields

International Nuclear Information System (INIS)

Whicker, J.J.; Hsu, H.H.; Hsieh, F.H.; Borak, T.B.

1999-01-01

Uncertainty in dosimetric and exposure rate measurements can increase in areas where multi-directional and low-energy photons (< 100 keV) exist because of variations in energy and angular measurement response. Also, accurate measurement of external exposures in spatially non-uniform fields may require multiple dosimetry. Therefore, knowledge of the photon fields in the workplace is required for full understanding of the accuracy of dosimeters and instruments, and for determining the need for multiple dosimeters. This project was designed to develop methods to characterize photon radiation fields in the workplace, and to test the methods in a plutonium facility. The photon field at selected work locations was characterized using TLDs and a collimated NaI(Tl) detector from which spatial variations in photon energy distributions were calculated from measured spectra. Laboratory results showed the accuracy and utility of the method. Field measurement results combined with observed work patterns suggested the following: (1) workers are exposed from all directions, but not isotropically, (2) photon energy distributions were directionally dependent, (3) stuffing nearby gloves into the glovebox reduced exposure rates significantly, (4) dosimeter placement on the front of the chest provided for a reasonable estimate of the average dose equivalent to workers' torsos, (5) justifiable conclusions regarding the need for multiple dosimetry can be made using this quantitative method, and (6) measurements of the exposure rates with ionization chambers pointed with open beta windows toward the glovebox provided the highest measured rates, although absolute accuracy of the field measurements still needs to be assessed

Electrically Induced Two-Photon Transparency in Semiconductor Quantum Wells

International Nuclear Information System (INIS)

Hayat, Alex; Nevet, Amir; Orenstein, Meir

2009-01-01

We demonstrate experimentally two-photon transparency, achieved by current injection into a semiconductor quantum-well structure which exhibits two-photon emission. The two-photon induced luminescence is progressively reduced by the injected current, reaching the point of two-photon transparency - a necessary condition for semiconductor two-photon gain and lasing. These results agree with our calculations.

Gamma absorption meter

International Nuclear Information System (INIS)

Dincklage, R.D. von.

1984-01-01

The absorption meter consists of a radiation source, a trough for the absorbing liquid and a detector. It is characterized by the fact that there is a foil between the detector and the trough, made of a material whose binding energy of the K electrons is a little greater than the energy of the photons emitted by the radiation source. The source of radiation and foil are replaceable. (orig./HP) [de

Direct measurements of neutral density depletion by two-photon absorption laser-induced fluorescence spectroscopy

International Nuclear Information System (INIS)

Aanesland, A.; Liard, L.; Leray, G.; Jolly, J.; Chabert, P.

2007-01-01

The ground state density of xenon atoms has been measured by spatially resolved laser-induced fluorescence spectroscopy with two-photon excitation in the diffusion chamber of a magnetized Helicon plasma. This technique allows the authors to directly measure the relative variations of the xenon atom density without any assumptions. A significant neutral gas density depletion was measured in the core of the magnetized plasma, in agreement with previous theoretical and experimental works. It was also found that the neutral gas density was depleted near the radial walls

Negative refraction angular characterization in one-dimensional photonic crystals.

Directory of Open Access Journals (Sweden)

Jesus Eduardo Lugo

2011-04-01

Full Text Available Photonic crystals are artificial structures that have periodic dielectric components with different refractive indices. Under certain conditions, they abnormally refract the light, a phenomenon called negative refraction. Here we experimentally characterize negative refraction in a one dimensional photonic crystal structure; near the low frequency edge of the fourth photonic bandgap. We compare the experimental results with current theory and a theory based on the group velocity developed here. We also analytically derived the negative refraction correctness condition that gives the angular region where negative refraction occurs.By using standard photonic techniques we experimentally determined the relationship between incidence and negative refraction angles and found the negative refraction range by applying the correctness condition. In order to compare both theories with experimental results an output refraction correction was utilized. The correction uses Snell's law and an effective refractive index based on two effective dielectric constants. We found good agreement between experiment and both theories in the negative refraction zone.Since both theories and the experimental observations agreed well in the negative refraction region, we can use both negative refraction theories plus the output correction to predict negative refraction angles. This can be very useful from a practical point of view for space filtering applications such as a photonic demultiplexer or for sensing applications.

Negative refraction angular characterization in one-dimensional photonic crystals.

Science.gov (United States)

Lugo, Jesus Eduardo; Doti, Rafael; Faubert, Jocelyn

2011-04-06

Photonic crystals are artificial structures that have periodic dielectric components with different refractive indices. Under certain conditions, they abnormally refract the light, a phenomenon called negative refraction. Here we experimentally characterize negative refraction in a one dimensional photonic crystal structure; near the low frequency edge of the fourth photonic bandgap. We compare the experimental results with current theory and a theory based on the group velocity developed here. We also analytically derived the negative refraction correctness condition that gives the angular region where negative refraction occurs. By using standard photonic techniques we experimentally determined the relationship between incidence and negative refraction angles and found the negative refraction range by applying the correctness condition. In order to compare both theories with experimental results an output refraction correction was utilized. The correction uses Snell's law and an effective refractive index based on two effective dielectric constants. We found good agreement between experiment and both theories in the negative refraction zone. Since both theories and the experimental observations agreed well in the negative refraction region, we can use both negative refraction theories plus the output correction to predict negative refraction angles. This can be very useful from a practical point of view for space filtering applications such as a photonic demultiplexer or for sensing applications.

Absorption spectrum of a two-level atom in a bad cavity with injected squeezed vacuum

Science.gov (United States)

Zhou, Peng; Swain, S.

1996-02-01

We study the absorption spectrum of a coherently driven two-level atom interacting with a resonant cavity mode which is coupled to a broadband squeezed vacuum through its input-output mirror in the bad cavity limit. We study the modification of the two-photon correlation strength of the injected squeezed vacuum inside the cavity, and show that the equations describing probe absorption in the cavity environment are formally identical to these in free space, but with modified parameters describing the squeezed vacuum. The two photon correlations induced by the squeezed vacuum are always weaker than in free space. We pay particular attention to the spectral behaviour at line centre in the region of intermediate trength driving intensities, where anomalous spectral features such as hole-burning and dispersive profiles are displayed. These unusual spectral features are very sensitive to the squeezing phase and the Rabi frequency of the driving field. We also derive the threshold value of the Rabi frequency which gives rise to the transparency of the probe beam at the driving frequency. When the Rabi frequency is less than the threshold value, the probe beam is absorbed, whilst the probe beam is amplified (without population inversion under certain conditions) when the Rabi frequency is larger than this threshold. The anomalous spectral features all take place in the vicinity of the critical point dividing the different dynamical regimes, probe absorption and amplification, of the atomic radiation. The physical origin of the strong amplification without population inversion, and the feasibility of observing it, are discussed.

Variation of energy absorption buildup factors with incident photon energy and penetration depth for some commonly used solvents

Energy Technology Data Exchange (ETDEWEB)

Singh, Parjit S. [Department of Physics, Punjabi University, Patiala 147 002 (India)], E-mail: dr_parjit@hotmail.com; Singh, Tejbir [Department of Physics, Lovely Professional University, Phagwara 144 402 (India); Kaur, Paramjeet [IAS and Allied Services Training Centre, Punjabi University, Patiala 147 002 (India)

2008-06-15

G.P. fitting method has been used to compute energy absorption buildup factor of some commonly used solvents such as acetonitrile (C{sub 4}H{sub 3}N), butanol (C{sub 4}H{sub 9}OH), chlorobenzene (C{sub 6}H{sub 5}Cl), diethyl ether (C{sub 4}H{sub 10}O), ethanol (C{sub 2}H{sub 5}OH), methanol (CH{sub 3}OH), propanol (C{sub 3}H{sub 7}OH) and water (H{sub 2}O) for the wide energy range (0.015-15.0 MeV) up to the penetration depth of 10 mean free path. The variation of energy absorption buildup factor with chemical composition as well as incident photon energy for the selected solvents has been studied. It has been observed that the maximum value of energy absorption buildup factors shifts to the slightly higher incident photon energy with the increase in equivalent atomic number of the solvent and the solvent with least equivalent atomic number possesses the maximum value of energy absorption buildup factor.

Low momentum transfer theorem for two photon exchange in lepton hardron scattering

International Nuclear Information System (INIS)

Penarrocha, J.A.; Bernabeu, J.

1981-01-01

The two photon contribution to lepton-hardon scattering is considered. Under the assumptions of Lorentz covarience, gauge invarience, unitarity, and analyticity, we prove a low momentum transfer theorem for the relevant amplitudes. Fixed energy dispersion relations tell us that their nonanalytic part, in the neighbourhood of t = 0, is given by the contribution of the two photon cut in the t-channel. The t-channel absorptive parts are obtained from unitarity. Their calculation has as input the two amplitudes corresponding to Compton scattering on the hadron with a pole contribution, and the continuum controlled at low t by the electromagnetic polarizabilities. By means of the dispersion integral, one proves the expansion k 1 (s)+k 2 (s)√-t+k 3 (s)tlog(-t)+O(t) for the continuum contribution, where k 1 (s) is the only unknown. Explicit expressions are obtained for the pole contribution as M→infinity, where M is the hadron mass, and for the continuum when (-t) 2 , where m is the muon mass and Λ is a characteristic parameter of the hadron structure

Mapping of the atomic hydrogen density in combustion processes at atmospheric pressure by two-photon polarization spectroscopy

International Nuclear Information System (INIS)

Steiger, A.; Gruetzmacher, K.; Steiger, M.; Gonzalo, A.B.; Rosa, M.I. de la

2001-01-01

With laser spectroscopic techniques used so far, quantitative measurements of atomic number densities in flames and other combustion processes at atmospheric pressure yield no satisfying results because high quenching rates remarkably reduce the signal size and the results suffer from large uncertainties. Whereas, two-photon polarization spectroscopy is not limited by quenching, as the polarization signal is a direct measure of the two-photon absorption. This sensitive laser technique with high spatial and temporal resolution has been applied to determine absolute number densities and the kinetic temperatures of atomic hydrogen in flames for the first time. The great potential of this method of measurement comes into its own only in conjunction with laser radiation of highest possible spectral quality, i.e. single-frequency ns-pulses with peak irradiance of up to 1 GW/cm 2 tunable around 243 nm for 1S-2S two-photon transition of atomic hydrogen

Possibility of producing the event-ready two-photon polarization entangled state with normal photon detectors

International Nuclear Information System (INIS)

Wang Xiangbin

2003-01-01

We propose a scheme to produce the maximally two-photon polarization entangled state with single-photon sources and the passive linear optics devices. In particular, our scheme only requires the normal photon detectors which distinguish the vacuum and non-vacuum Fock number states. A sophisticated photon detector distinguishing between one-photon state and two-photon state is unnecessary in the scheme

Coherent effects on two-photon correlation and directional emission of two two-level atoms

International Nuclear Information System (INIS)

Ooi, C. H. Raymond; Kim, Byung-Gyu; Lee, Hai-Woong

2007-01-01

Sub- and superradiant dynamics of spontaneously decaying atoms are manifestations of collective many-body systems. We study the internal dynamics and the radiation properties of two atoms in free space. Interesting results are obtained when the atoms are separated by less than half a wavelength of the atomic transition, where the dipole-dipole interaction gives rise to new coherent effects, such as (a) coherence between two intermediate collective states, (b) oscillations in the two-photon correlation G (2) , (c) emission of two photons by one atom, and (d) the loss of directional correlation. We compare the population dynamics during the two-photon emission process with the dynamics of single-photon emission in the cases of a Λ and a V scheme. We compute the temporal correlation and angular correlation of two successively emitted photons using the G (2) for different values of atomic separation. We find antibunching when the atomic separation is a quarter wavelength λ/4. Oscillations in the temporal correlation provide a useful feature for measuring subwavelength atomic separation. Strong directional correlation between two emitted photons is found for atomic separation larger than a wavelength. We also compare the directionality of a photon spontaneously emitted by the two atoms prepared in phased-symmetric and phased-antisymmetric entangled states vertical bar ±> k 0 =e ik 0 ·r 1 vertical bar a 1 ,b 2 >±e ik 0 ·r 2 vertical bar b 1 ,a 2 > by a laser pulse with wave vector k 0 . Photon emission is directionally suppressed along k 0 for the phased-antisymmetric state. The directionality ceases for interatomic distances less than λ/2

Two-Dimentional Photonic Crystal Waveguides

DEFF Research Database (Denmark)

Søndergaard, Thomas; Dridi, Kim

1999-01-01

possible a novel class of optical microcavities, whereas line defects make possible a novel class of waveguides. In this paper we will analyze two-dimensional photonic crystal waveguides based on photonic crystals with rods arranged on a triangular and a square lattice using a plane-wave expansion method......In the recent years a new class of periodic high-index contrast dielectric structures, known as photonic bandgap structures, has been discovered. In these structures frequency intervals, known as photonic bandgaps, where propagation of electromagnetic waves is not allowed, exist due to the periodic...... dielectric function. This is analogous to semiconductors, where electronic bandgaps exist due to the periodic arrangement of atoms. As is also the case for semiconductor structures, photonic bandgap structures may become of even greater value when defects are introduced. In particular, point defects make...

Quarkonium two-photon decays in QCD

International Nuclear Information System (INIS)

Dulyan, L.S.; Khodjamirian, A.Yu.; Magakian, A.D.

1989-01-01

The two-photon decay of tensor charmonium χ c2 → 2 γ is calculated with account of gluon condensate effects. The result is in good agreement with experiment. The two-photon width of pseudoscalar b-quarkonium η b → 2 γ is estimated. 19 refs.; 1 fig.; 1 tab

Characterization of InP and InGaN quantum dots for single photon sources and AlGaInAs quantum dots in intermediate band solar cells

International Nuclear Information System (INIS)

Kremling, Stefan

2014-01-01

This thesis describes the characterization of semiconductor quantum dots (QDs) in different material systems with potential applications as single photon emitters or intermediate band solar cells. All investigations were carried out by means of optical spectroscopy methods. First, the theoretical background regarding the physics of QDs with respect to their electronic structure and their associated statistical properties are presented. Especially peculiarities of photon statistics of light are explained. Moreover, a closer look at the physics of solar cells and the respective carrier transport is given. Then experimental methods, which were used to characterize the QD-samples, are briefly explained. First, the components and techniques of optical spectroscopy for the study of individual, isolated QDs are described. Second, different experimental technologies for the characterization of solar cells are discussed. The method for measuring the two-photon-absorption process is explained in detail. The section of experimental results begins with studies of individual and spectrally isolated InP QD. Due to the low surface density of one QD per μm 2 , it is possible to study the physical properties of individual QDs optically without additional lateral sample structuring. Based on power and polarization dependent measurements, various luminescence peaks of a single QD were associated with different exciton states. In addition, the QDs were tested subject to an external magnetic field in a Faraday configuration. Finally, the temporal photon statistics of a single QD was tested using autocorrelation measurement. Afterwards, InP QDs manufactured by cyclic material deposition with growth interruptions were investigated by means of PL spectroscopy. Based on excitation power and time-resolved measurements on the QD ensemble, a bimodal QD distribution of type-I and type-II band alignment was observed. In addition, different exciton states were identified on spectrally isolated

One-, two- and three-photon spectroscopy of π-conjugated dendrimers: cooperative enhancement and coherent domains

International Nuclear Information System (INIS)

Drobizhev, M.; Rebane, A.; Suo, Z.; Spangler, C.W.

2005-01-01

We use wavelength tunable femtosecond pulses to measure intrinsic (simultaneous) two-photon absorption (2PA) and three-photon absorption (3PA) molecular cross section in two series of π-conjugated dendrimers built of identical 4,4'-bis(diphenylamino) stilbene (BDPAS) and 4,4'-bis(diphenylamino) distyrylbenzene (BDPADSB) repeat units. Record large 2PA cross sections, σ 2 =10 -46 cm 4 s are obtained for the largest second-generation BDPAS-based dendrimer, as well as zeroth-generation 4-arm BDPADSB-based dendrimer. In both series, maximum 2PA cross section increases nonlinearly with the number of π-electrons, whereas for higher generations this dependence turns to linear one. 3PA cross section also increases nonlinearly with the size of the system in the series of BDPAS-based molecules, amounting a record large value, σ 3 =10 -79 cm 6 s 2 , for the largest, second-generation dendrimer. We interpret these results in terms of direct inter-branch conjugation, which facilitates cooperative enhancement of the nonlinear-optical response. We propose a simple model which allows us to determine the effective size of coherent domains (extent of conjugation), which, in turn, determines the optimum dendrimer size for most efficient nonlinear response

Analysis of the intermediate-band absorption properties of type-II GaSb/GaAs quantum-dot photovoltaics

Science.gov (United States)

Ramiro, I.; Villa, J.; Tablero, C.; Antolín, E.; Luque, A.; Martí, A.; Hwang, J.; Phillips, J.; Martin, A. J.; Millunchick, J.

2017-09-01

Quantum-dot (QD) intermediate-band (IB) materials are regarded as promising candidates for high-efficiency photovoltaics. The sequential two-step two-photon absorption processes that take place in these materials have been proposed to develop high-efficiency solar cells and infrared (IR) photodetectors. In this work, we experimentally and theoretically study the interrelation of the absorptivity with transitions of carriers to and from the IB in type-II GaSb/GaAs QD devices. Our devices exhibit three optical band gaps with: EL=0.49 eV ,EH=1.02 eV , and EG=1.52 eV , with the IB located 0.49 eV above the valence band. These values are well supported by semiempirical calculations of the QDs electronic structure. Through intensity-dependent two-photon photocurrent experiments, we are able to vary the filling state of the IB, thus modifying the absorptivity of the transitions to and from this band. By filling the IB with holes via E =1.32 eV or E =1.93 eV monochromatic illumination, we demonstrate an increase in the EL-related absorptivity of more than two orders of magnitude and a decrease in the EH-related absorptivity of one order of magnitude. The antisymmetrical evolution of those absorptivities is quantitatively explained by a photoinduced shift of the quasi-Fermi level of the IB. Furthermore, we report the observation of a two-photon photovoltage, i.e., the contribution of subband gap two-photon absorption to increase the open-circuit voltage of solar cells. We find that the generation of the two-photon photovoltage is related, in general, to the production of a two-photon photocurrent. However, while photons with energy close to EL participate in the production of the two-photon photocurrent, they are not effective in the production of a two-photon photovoltage. We also report the responsivity of GaSb/GaAs QD devices performing as optically triggered photodetectors. These devices exhibit an amplification factor of almost 400 in the IR spectral region. This high

Synthesis of novel fluorene-based two-photon absorbing molecules and their applications in optical data storage, microfabrication, and stimulated emission depletion

Science.gov (United States)

Yanez, Ciceron

2009-12-01

Two-photon absorption (2PA) has been used for a number of scientific and technological applications, exploiting the fact that the 2PA probability is directly proportional to the square of the incident light intensity (while one-photon absorption bears a linear relation to the incident light intensity). This intrinsic property of 2PA leads to 3D spatial localization, important in fields such as optical data storage, fluorescence microscopy, and 3D microfabrication. The spatial confinement that 2PA enables has been used to induce photochemical and photophysical events in increasingly smaller volumes and allowed nonlinear, 2PA-based, technologies to reach sub-diffraction limit resolutions. The primary focus of this dissertation is the development of novel, efficient 2PA, fluorene-based molecules to be used either as photoacid generators (PAGs) or fluorophores. A second aim is to develop more effective methods of synthesizing these compounds. As a third and final objective, the new molecules were used to develop a write-once-read many (WORM) optical data storage system, and stimulated emission depletion probes for bioimaging. In Chapter I, the microwave-assisted synthesis of triarylsulfonium salt photoacid generators (PAGs) from their diphenyliodonium counterparts is reported. The microwave-assisted synthesis of these novel sulfonium salts afforded reaction times 90 to 420 times faster than conventional thermal conditions, with photoacid quantum yields of new sulfonium PAGs ranging from 0.01 to 0.4. These PAGs were used to develop a fluorescence readout-based, nonlinear three-dimensional (3D) optical data storage system (Chapter II). In this system, writing was achieved by acid generation upon two-photon absorption (2PA) of a PAG (at 710 or 730 nm). Readout was then performed by interrogating two-photon absorbing dyes, after protonation, at 860 nm. Two-photon recording and readout of voxels was demonstrated in five and eight consecutive, crosstalk-free layers within a

Two-photon decay in heavy atoms and ions

International Nuclear Information System (INIS)

Mokler, P.H.; Dunford, R.W

2003-08-01

We review the status of and comment on current developments in the field of two-photon decay in atomic physics research. Recent work has focused on two-photon decays in highly-charged ions and two-photon decay of inner-shell vacancies in heavy neutral atoms. We emphasize the importance of measuring the shape of the continuum emission in two-photon decay as a probe of relativistic effects in the strong central fields found in heavy atomic systems. New experimental approaches and their consequences will be discussed. (orig.)

Suitable photo-resists for two-photon polymerization using femtosecond fiber lasers

KAUST Repository

Rajamanickam, V.P.

2014-06-01

We present suitable materials with good optical and mechanical properties, simple processing, efficient and optimized for two-photon polymerization (TPP) with femtosecond fiber lasers. We selected readily available acrylic monomer Bisphenol A ethoxylate diacrylate (BPA-EDA) with three different photo-initiators (PIs), isopropyl thioxanthone (ITX), 7-diethylamino-3-thenoylcoumarin (DETC), and 4,4′ bis(diethylamino) benzophenone (BDEB), since their absorption spectra match well with the laser wavelength at 780 nm. These PIs grant efficient radical generation, reactivity and high solubility in acrylic monomers. Finally, good optical and mechanical properties are demonstrated by the fabrication of different micro-structures.

Negative Refraction Angular Characterization in One-Dimensional Photonic Crystals

OpenAIRE

Lugo, Jesus Eduardo; Doti, Rafael; Faubert, Jocelyn

2011-01-01

Background Photonic crystals are artificial structures that have periodic dielectric components with different refractive indices. Under certain conditions, they abnormally refract the light, a phenomenon called negative refraction. Here we experimentally characterize negative refraction in a one dimensional photonic crystal structure; near the low frequency edge of the fourth photonic bandgap. We compare the experimental results with current theory and a theory based on the group velocity de...

Two-photon quantum interference in a Michelson interferometer

International Nuclear Information System (INIS)

Odate, Satoru; Wang Haibo; Kobayashi, Takayoshi

2005-01-01

We have observed two-photon quantum interference in a Michelson interferometer. For the first time, we experimentally demonstrated two-photon quantum interference patterns, which show the transition from nonsubwavelength interference fringes to the general subwavelength interference. At the same time, a photon bunching effect was also shown by a postselection. The |1, 1> state with a single photon in a mode corresponding to each arm of the interferometer was exclusively postselected by using path difference between two arms

Coherence revivals in two-photon frequency combs

International Nuclear Information System (INIS)

Torres-Company, Victor; Lancis, Jesus; Lajunen, Hanna; Friberg, Ari T.

2011-01-01

We describe and theoretically analyze the self-imaging Talbot effect of entangled photon pairs in the time domain. Rich phenomena are observed in coherence propagation along dispersive media of mode-locked two-photon states with frequency entanglement exhibiting a comblike correlation function. Our results can be used to remotely transfer frequency standards through optical fiber networks with two-photon light, avoiding the requirement of dispersion compensation.

Targeted two-photon photodynamic therapy for the treatment of subcutaneous tumors

Science.gov (United States)

Spangler, Charles W.; Starkey, Jean R.; Meng, Fanqing; Gong, Aijun; Drobizhev, Mikhail; Rebane, Aleksander; Moss, B.

2005-04-01

Photodynamic therapy (PDT) has developed into a mature technology over the past several years, and is currently being exploited for the treatment of a variety of cancerous tumors, and more recently for age-related wet macular degeneration of the eye. However, there are still some unresolved problems with PDT that are retarding a more general acceptance in clinical settings, and thus, for the most part, the treatment of most cancerous rumors still involves some combination of invasive surgery, chemotherapy and radiation treatment, particularly subcutaneous tumors. Currently approved PDT agents are activated in the Visible portion of the spectrum below 700 nm, Laser light in this spectral region cannot penetrate the skin more than a few millimeters, and it would be more desirable if PDT could be initiated deep in the Near-infrared (NIR) in the tissue transparency window (700-1000 nm). MPA Technologies, Inc. and Rasiris, Inc. have been co-developing new porphyrin PDT designed to have greatly enhanced intrinsic two-photon cross-sections (>800 GM units) whose two-photon absorption maxima lie deep in the tissue transparency window (ca. 780-850 nm), and have solubility characteristics that would allow for direct IV injection into animal models. Classical PDT also suffers from the lengthy time necessary for accumulation at the tumor site, a relative lack of discrimination between healthy and diseased tissue, particularly at the tumor margins, and difficulty in clearing from the system in a reasonable amount of time post-PDT. We have recently discovered a new design paradigm for the delivery of our two-photon activated PDT agents by incorporating the porphyrins into a triad ensemble that includes a small molecule targeting agent that directs the triad to over-expressed tumor receptor sites, and a NIR one-photon imaging agent that allows the tracking of the triad in terms of accumulation and clearance rates. We are currently using these new two-photon PDT triads in efficacy

Dynamic characterization of hydrophobic and hydrophilic solutes in oleic-acid enhanced transdermal delivery using two-photon fluorescence microscopy

Energy Technology Data Exchange (ETDEWEB)

Tseng, Te-Yu; Yang, Chiu-Sheng; Chen, Yang-Fang [Department of Physics, National Taiwan University, Taipei, Taiwan (China); Tsai, Tsung-Hua [Department of Dermatology, Far Eastern Memorial Hospital, New Taipei City, Taiwan (China); Dong, Chen-Yuan, E-mail: cydong@phys.ntu.edu.tw [Department of Physics, National Taiwan University, Taipei, Taiwan (China); Center for Quantum Science and Engineering, National Taiwan University, Taipei, Taiwan (China); Center for Optoelectronic Biomedicine, National Taiwan University, Taipei, Taiwan (China)

2014-10-20

In this letter, we propose an efficient methodology of investigating dynamic properties of sulforhodamine B and rhodamine B hexyl ester molecules transporting across ex-vivo human stratum corneum with and without oleic acid enhancement. Three-dimensional, time-lapse fluorescence images of the stratum corneum can be obtained using two-photon fluorescence microscopy. Furthermore, temporal quantifications of transport enhancements in diffusion parameters can be achieved with the use of Fick's second law. Dynamic characterization of solutes transporting across the stratum corneum is an effective method for understanding transient phenomena in transdermal delivery of probe molecules, leading to improved delivery strategies of molecular species for therapeutic purposes.

Energy dependence of effective atomic numbers for photon energy absorption and photon interaction: Studies of some biological molecules in the energy range 1 keV-20 MeV

DEFF Research Database (Denmark)

Manohara, S.R.; Hanagodimath, S.M.; Gerward, Leif

2008-01-01

Effective atomic numbers for photon energy absorption, Z(PEA,eff), and for photon interaction, Z(PI,eff), have been calculated by a direct method in the photon-energy region from 1 keV to 20 MeV for biological molecules, such as fatty acids (lauric, myristic, palmitic, stearic, oleic, linoleic......, linolenic, arachidonic, and arachidic acids), nucleotide bases (adenine, guanine, cytosine, uracil, and thymine), and carbohydrates (glucose, sucrose, raffinose, and starch). The Z(PEA, eff) and Z(PI, eff) values have been found to change with energy and composition of the biological molecules. The energy...

Time-resolved statistics of photon pairs in two-cavity Josephson photonics

Energy Technology Data Exchange (ETDEWEB)

Dambach, Simon; Kubala, Bjoern; Ankerhold, Joachim [Institute for Complex Quantum Systems and IQST, Ulm University (Germany)

2017-06-15

We analyze the creation and emission of pairs of highly nonclassical microwave photons in a setup where a voltage-biased Josephson junction is connected in series to two electromagnetic oscillators. Tuning the external voltage such that the Josephson frequency equals the sum of the two mode frequencies, each tunneling Cooper pair creates one additional photon in both of the two oscillators. The time-resolved statistics of photon emission events from the two oscillators is investigated by means of single- and cross-oscillator variants of the second-order correlation function g{sup (2)}(τ) and the waiting-time distribution w(τ). They provide insight into the strongly correlated quantum dynamics of the two oscillator subsystems and reveal a rich variety of quantum features of light including strong antibunching and the presence of negative values in the Wigner function. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Total absorption by degenerate critical coupling

Energy Technology Data Exchange (ETDEWEB)

Piper, Jessica R., E-mail: jrylan@stanford.edu; Liu, Victor; Fan, Shanhui, E-mail: shanhui@stanford.edu [Ginzton Laboratory, Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States)

2014-06-23

We consider a mirror-symmetric resonator with two ports. We show that, when excited from a single port, complete absorption can be achieved through critical coupling to degenerate resonances with opposite symmetry. Moreover, any time two resonances with opposite symmetry are degenerate in frequency and absorption is always significantly enhanced. In contrast, when two resonances with the same symmetry are nearly degenerate, there is no absorption enhancement. We numerically demonstrate these effects using a graphene monolayer on top of a photonic crystal slab, illuminated from a single side in the near-infrared.

Tuning optical and three photon absorption properties in graphene oxide-polyvinyl alcohol free standing films

Energy Technology Data Exchange (ETDEWEB)

Karthikeyan, B., E-mail: bkarthik@nitt.edu; Hariharan, S. [Department of Physics, National Institute of Technology, Tiruchirappalli 620 015 (India); Udayabhaskar, R. [Department of Physics, National Institute of Technology, Tiruchirappalli 620 015 (India); Advanced Ceramics and Nanotechnology Laboratory, Department of Materials Engineering, University of Concepcion, Concepcion 4070386 (Chile)

2016-07-11

We report the optical and nonlinear optical properties of graphene oxide (GO)-polyvinyl alcohol (PVA) free standing films. The composite polymer films were prepared in ex-situ method. The variation in optical absorption spectra and optical constants with the amount of GO loading was noteworthy from the optical absorption spectroscopic studies. Nonlinear optical studies done at 532 nm using 5 ns laser pulses show three photon absorption like behaviour. Both steady state and time resolved fluorescence studies reveal that the GO was functioning as a pathway for the decay of fluorescence from PVA. This is attributed to the energy level modifications of GO through hydroxyl groups with PVA. Raman spectroscopy also supports the interaction between GO and PVA ions through OH radicals.

Tuning optical and three photon absorption properties in graphene oxide-polyvinyl alcohol free standing films

International Nuclear Information System (INIS)

Karthikeyan, B.; Hariharan, S.; Udayabhaskar, R.

2016-01-01

We report the optical and nonlinear optical properties of graphene oxide (GO)-polyvinyl alcohol (PVA) free standing films. The composite polymer films were prepared in ex-situ method. The variation in optical absorption spectra and optical constants with the amount of GO loading was noteworthy from the optical absorption spectroscopic studies. Nonlinear optical studies done at 532 nm using 5 ns laser pulses show three photon absorption like behaviour. Both steady state and time resolved fluorescence studies reveal that the GO was functioning as a pathway for the decay of fluorescence from PVA. This is attributed to the energy level modifications of GO through hydroxyl groups with PVA. Raman spectroscopy also supports the interaction between GO and PVA ions through OH radicals.

High-throughput gated photon counter with two detection windows programmable down to 70 ps width

Energy Technology Data Exchange (ETDEWEB)

Boso, Gianluca; Tosi, Alberto, E-mail: alberto.tosi@polimi.it; Zappa, Franco [Dipartimento di Elettronica, Informazione e Bioingegneria, Politecnico di Milano, Piazza Leonardo Da Vinci 32, 20133 Milano (Italy); Mora, Alberto Dalla [Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo Da Vinci 32, 20133 Milano (Italy)

2014-01-15

We present the design and characterization of a high-throughput gated photon counter able to count electrical pulses occurring within two well-defined and programmable detection windows. We extensively characterized and validated this instrument up to 100 Mcounts/s and with detection window width down to 70 ps. This instrument is suitable for many applications and proves to be a cost-effective and compact alternative to time-correlated single-photon counting equipment, thanks to its easy configurability, user-friendly interface, and fully adjustable settings via a Universal Serial Bus (USB) link to a remote computer.

High-throughput gated photon counter with two detection windows programmable down to 70 ps width

International Nuclear Information System (INIS)

Boso, Gianluca; Tosi, Alberto; Zappa, Franco; Mora, Alberto Dalla

2014-01-01

We present the design and characterization of a high-throughput gated photon counter able to count electrical pulses occurring within two well-defined and programmable detection windows. We extensively characterized and validated this instrument up to 100 Mcounts/s and with detection window width down to 70 ps. This instrument is suitable for many applications and proves to be a cost-effective and compact alternative to time-correlated single-photon counting equipment, thanks to its easy configurability, user-friendly interface, and fully adjustable settings via a Universal Serial Bus (USB) link to a remote computer

Targeted two-photon PDT photo-sensitizers for the treatment of subcutaneous tumors

Science.gov (United States)

Spangler, C. W.; Rebane, A.; Starkey, J.; Drobizhev, M.

2009-06-01

New porphyrin-based photo-sensitizers have been designed, synthesized and characterized that exhibit greatly enhanced intrinsic two-photon absorption. These new photo-sensitizers have been incorporated into triad formulations that also incorporate Near-infrared (NIR) imaging agents, and small-molecule targeting agents that direct the triads to cancerous tumors' over-expressed receptor sites. PDT can be initiated deep into the tissue transparency window at 780-800 nm utilizing a regeneratively amplified Ti:sapphire laser using 100-150 fs pulses of 600-800 mW. Human tumor xenografts of human breast cancer (MDA-MB-231) and both small SCLC (NCI-H69) and NSCLC (A-459) have been successfully treated using octreotate targeting of over-expressed SST2 receptors. In particular, the lung cancer xenografts can be successfully treated by irradiating from the side of the mouse opposite the implanted tumor, thereby passing through ca. 2 cm of mouse skin, tissue and organs with no discernible damage to healthy tissue while causing regression in the tumors. These results suggest a new PDT paradigm for the noninvasive treatment of subcutaneous tumors, including the possibility that the targeting moiety could be matched to individual patient genetic profiles (patient-specific therapeutics).

Photon echo with a few photons in two-level atoms

International Nuclear Information System (INIS)

Bonarota, M; Dajczgewand, J; Louchet-Chauvet, A; Le Gouët, J-L; Chanelière, T

2014-01-01

To store and retrieve signals at the single photon level, various photon echo schemes have resorted to complex preparation steps involving ancillary shelving states in multi-level atoms. For the first time, we experimentally demonstrate photon echo operation at such a low signal intensity without any preparation step, which allows us to work with mere two-level atoms. This simplified approach relies on the so-coined ‘revival of silenced echo’ (ROSE) scheme. Low noise conditions are obtained by returning the atoms to the ground state before the echo emission. In the present paper we manage ROSE in photon counting conditions, showing that very strong control fields can be compatible with extremely weak signals, making ROSE consistent with quantum memory requirements. (paper)

A polarizable embedding DFT study of one-photon absorption in fluorescent proteins

DEFF Research Database (Denmark)

Beerepoot, Maarten; Steindal, Arnfinn H.; Kongsted, Jacob

2013-01-01

mutants (BFP, eGFP, YFP and eCFP). The observed trends in excitation energies among the FPs are reproduced by our approach when performing calculations directly on the crystal structures or when using structures extracted from a molecular dynamics simulations. However, in the former case, QM/MM geometry......A theoretical study of the one-photon absorption of five fluorescent proteins (FPs) is presented. The absorption properties are calculated using a polarizable embedding approach combined with density functional theory (PE-DFT) on the wild-type green fluorescent protein (wtGFP) and several of its...... optimization of the chromophores within a frozen protein environment is needed in order to reproduce the experimental trends. Explicit account of polarization in the force field is not needed to yield the correct trend between the different FPs, but is necessary for reproducing the experimentally observed red...

Multiphoton Absorption Order of CsPbBr3 As Determined by Wavelength-Dependent Nonlinear Optical Spectroscopy.

Science.gov (United States)

Saouma, Felix O; Stoumpos, Constantinos C; Kanatzidis, Mercouri G; Kim, Yong Soo; Jang, Joon I

2017-10-05

CsPbBr 3 is a direct-gap semiconductor where optical absorption takes place across the fundamental bandgap, but this all-inorganic halide perovskite typically exhibits above-bandgap emission when excited over an energy level, lying above the conduction-band minimum. We probe this bandgap anomaly using wavelength-dependent multiphoton absorption spectroscopy and find that the fundamental gap is strictly two-photon forbidden, rendering it three-photon absorption (3PA) active. Instead, two-photon absorption (2PA) commences when the two-photon energy is resonant with the optical gap, associated with the level causing the anomaly. We determine absolute nonlinear optical dispersion over this 3PA-2PA region, which can be explained by two-band models in terms of the optical gap. The polarization dependence of 3PA and 2PA is also measured and explained by the relevant selection rules. CsPbBr 3 is highly luminescent under multiphoton absorption at room temperature with marked polarization and wavelength dependence at the 3PA-2PA crossover and therefore has potential for nonlinear optical applications.

Quantum theory of two-photon wavepacket interference in a beamsplitter

International Nuclear Information System (INIS)

Wang, Kaige

2006-01-01

A general theory is derived for the interference of a two-photon wavepacket in a beamsplitter. The theory is presented in the Schroedinger picture so that the quantum nature of the two-photon interference is explicitly revealed. We find that the topological symmetry of the probability-amplitude spectrum of the two-photon wavepacket dominates the nature of the two-photon interference, which may be distinguished by the increase or decrease of the coincidence probability in the absence of interference. However, two-photon entanglement can be identified by the nature of the interference. We demonstrate the necessary and sufficient conditions for perfect two-photon interference. It is shown that a two-photon entangled state with an anti-symmetric spectrum passes through a 50/50 beamsplitter with perfect transparency. The theory provides us with a unified understanding of the various two-photon interference effects. (topical review)

Microsphere imaging with confocal microscopy and two photon microscopy

International Nuclear Information System (INIS)

Chun, Hyung Su; An, Kyung Won; Lee, Jai Hyung

2002-01-01

We have acquired images of polystyrene and fused-silica microsphere by using conventional optical microscopy, confocal microscopy and two-photon microscopy, and performed comparative analysis of these images. Different from conventional optical microscopy, confocal and two-photon microscopy had good optical sectioning capability. In addition, confocal microscopy and two-photon microscopy had better lateral resolution than conventional optical microscopy. These results are attributed to confocality and nonlinearity of confocal microscopy and two photon microscopy, respectively.

On the kinematics of the two-photon Cherenkov effect

International Nuclear Information System (INIS)

Afanas'ev, G.N.; Stepanovskij, Yu.P.

2003-01-01

We study the kinematics of the two-photon Cherenkov effect. In the general case, the emission angles of two photons satisfy certain inequalities and the corresponding radiation intensities are rather diffused. In special cases, when the above inequalities reduce to equalities, the emission angles of two photons are fixed and the corresponding radiation intensities should have sharp maxima at these angles. This makes easier the experimental study of the two-photon Cherenkov effect

Limitations of two-level emitters as nonlinearities in two-photon controlled-PHASE gates

DEFF Research Database (Denmark)

Nysteen, Anders; McCutcheon, Dara P. S.; Heuck, Mikkel

2017-01-01

We investigate the origin of imperfections in the fidelity of a two-photon controlled-PHASE gate based on two-level-emitter nonlinearities. We focus on a passive system that operates without external modulations to enhance its performance. We demonstrate that the fidelity of the gate is limited...... by opposing requirements on the input pulse width for one-and two-photon-scattering events. For one-photon scattering, the spectral pulse width must be narrow compared with the emitter linewidth, while two-photon-scattering processes require the pulse width and emitter linewidth to be comparable. We find...

Two-Photon Ghost Image and Interference-Diffraction

Science.gov (United States)

Shih, Y. H.; Sergienko, A. V.; Pittman, T. B.; Strekalov, D. V.; Klyshko, D. N.

1996-01-01

One of the most surprising consequences of quantum mechanics is entanglement of two or more distance particles. The two-particle entangled state was mathematically formulated by Schrodinger. Based on this unusual quantum behavior, EPR defined their 'physical reality' and then asked the question: 'Can Quantum-Mechanical Description of Physical Reality Be Considered Complete?' One may not appreciate EPR's criterion of physical reality and insist that 'no elementary quantum phenomenon is a phenomenon until it is a recorded phenomenon'. Optical spontaneous parametric down conversion (SPDC) is the most effective mechanism to generate an EPR type entangled two-photon state. In SPDC, an optical beam, called the pump, is incident on a birefringent crystal. The pump is intense enough so that nonlinear effects lead to the conversion of pump photons into pairs of photons, historically called signal and idler. Technically, the SPDC is said to be type-1 or type-2, depending on whether the signal and idler beams have parallel or orthogonal polarization. The SPDC conversion efficiency is typically on the order of 10(exp -9) to 10(exp -11), depending on the SPDC nonlinear material. The signal and idler intensities are extremely low, only single photon detection devices can register them. The quantum entanglement nature of SPDC has been demonstrated in EPR-Bohm experiments and Bell's inequality measurements. The following two experiments were recently performed in our laboratory, which are more closely related to the original 1935 EPR gedankenezperiment. The first experiment is a two-photon optical imaging type experiment, which has been named 'ghost image' by the physics community. The signal and idler beams of SPDC are sent in different directions, so that the detection of the signal and idler photons can be performed by two distant photon counting detectors. An aperture object (mask) is placed in front of the signal photon detector and illuminated by the signal beam through a

Squeezing via two-photon transitions

Science.gov (United States)

Savage, C. M.; Walls, D. F.

1986-05-01

The squeezing spectrum for a cavity field mode interacting with an ensemble of three-level 'Lambda-configuration' atoms by an effective two-photon transition is calculated. The advantage of the three-level Lambda system as a squeezing medium, that is, optical nonlinearity without atomic saturation, has recently been pointed out by Reid, Walls, and Dalton. Perfect squeezing is predicted at the turning points for dispersive optical bistability and good squeezing for a range of other cases. Three-level ladder atoms interacting by an effective two-photon transition are also shown to give perfect squeezing in the dispersive limit.

Exclusive hadron production in two photon reactions

International Nuclear Information System (INIS)

Poppe, M.

1986-02-01

This paper summarises experimental results on exclusive hadron production in two photon collisions at electron positron storage rings and attempts some interpretation. Experimental know how is described and new suggestions are made for future analyses. New model calculations on resonance form factors and pair production amplitudes are presented. The two photon vertex is decomposed such that experiments can be parameterised with the minimal number of free parameters. Selection rules for off shell photon collisions are given in addition to Yang's theorems. (orig.)

Theory of even-parity states and two-photon spectra of conjugated polymers

Science.gov (United States)

McWilliams, P. C. M.; Hayden, G. W.; Soos, Z. G.

1991-04-01

The two-photon absorption (TPA) spectrum of interacting π electrons in conjugated polymers is shown to be qualitatively different from any single-particle description, including the Hartree-Fock limit. Alternating transfer integrals t(1+/-δ) along the backbone lead to a weak TPA below the one-photon gap Eg for arbitrarily weak correlations at δ=0, for intermediate correlations at δ=0.07 in polyenes, and for strong correlations at any δtheory to Eg in the limit of strong correlations in Hubbard models and is around 1.5Eg for Pariser-Parr-Pople (PPP) parameters. The PPP model, which accounts for one- and two-photon excitations of finite polyenes, is extended to even-parity states in polydiacetylenes (PDA's), polyacetylene (PA), and polysilanes (PS's). Previous experimental data for PDA and PS support both the strong TPA above Eg and weak TPA slightly below Eg for δ=0.15 in PDA and above Eg for δ~0.3 in PS. The strong TPA expected around 1.5Eg in isolated PA strands shifts to ~Eg due to interchain π-electron dispersion forces. TPA intensities in correlated states are shown to reflect both ionicity and mean-square charge separation. The even-parity states of conjugated polymers, like those of polyenes, show qualitatively different features associated with electron-electron correlations.

Two-dimensional topological photonic systems

Science.gov (United States)

Sun, Xiao-Chen; He, Cheng; Liu, Xiao-Ping; Lu, Ming-Hui; Zhu, Shi-Ning; Chen, Yan-Feng

2017-09-01

The topological phase of matter, originally proposed and first demonstrated in fermionic electronic systems, has drawn considerable research attention in the past decades due to its robust transport of edge states and its potential with respect to future quantum information, communication, and computation. Recently, searching for such a unique material phase in bosonic systems has become a hot research topic worldwide. So far, many bosonic topological models and methods for realizing them have been discovered in photonic systems, acoustic systems, mechanical systems, etc. These discoveries have certainly yielded vast opportunities in designing material phases and related properties in the topological domain. In this review, we first focus on some of the representative photonic topological models and employ the underlying Dirac model to analyze the edge states and geometric phase. On the basis of these models, three common types of two-dimensional topological photonic systems are discussed: 1) photonic quantum Hall effect with broken time-reversal symmetry; 2) photonic topological insulator and the associated pseudo-time-reversal symmetry-protected mechanism; 3) time/space periodically modulated photonic Floquet topological insulator. Finally, we provide a summary and extension of this emerging field, including a brief introduction to the Weyl point in three-dimensional systems.

Optical field-strength polarization of two-mode single-photon states

Energy Technology Data Exchange (ETDEWEB)

Linares, J; Nistal, M C; Barral, D; Moreno, V, E-mail: suso.linares.beiras@usc.e [Optics Area, Department of Applied Physics, Faculty of Physics and School of Optics and Optometry, University of Santiago de Compostela, Campus Universitario Sur s/n, 15782-Santiago de Compostela, Galicia (Spain)

2010-09-15

We present a quantum analysis of two-mode single-photon states based on the probability distributions of the optical field strength (or position quadrature) in order to describe their quantum polarization characteristics, where polarization is understood as a significative confinement of the optical field-strength values on determined regions of the two-mode optical field-strength plane. We will show that the mentioned probability distributions along with the values of quantum Stokes parameters allow us to characterize the polarization of a two-mode single-photon state, in an analogous way to the classical case, and to distinguish conceptually between mixture and partially polarized quantum states; in this way, we propose a simple definition of the quantum polarization degree based on the recent concept of distance measure to an unpolarized distribution, which gives rise to a depolarization degree equivalent to an overlapping between the probability distribution of the quantum state and a non-polarized two-mode Gaussian distribution. The work is particularly intended to university physics teachers and graduate students as well as to physicists and specialists concerned with the issue of optical polarization.

Optical field-strength polarization of two-mode single-photon states

International Nuclear Information System (INIS)

Linares, J; Nistal, M C; Barral, D; Moreno, V

2010-01-01

We present a quantum analysis of two-mode single-photon states based on the probability distributions of the optical field strength (or position quadrature) in order to describe their quantum polarization characteristics, where polarization is understood as a significative confinement of the optical field-strength values on determined regions of the two-mode optical field-strength plane. We will show that the mentioned probability distributions along with the values of quantum Stokes parameters allow us to characterize the polarization of a two-mode single-photon state, in an analogous way to the classical case, and to distinguish conceptually between mixture and partially polarized quantum states; in this way, we propose a simple definition of the quantum polarization degree based on the recent concept of distance measure to an unpolarized distribution, which gives rise to a depolarization degree equivalent to an overlapping between the probability distribution of the quantum state and a non-polarized two-mode Gaussian distribution. The work is particularly intended to university physics teachers and graduate students as well as to physicists and specialists concerned with the issue of optical polarization.

Femtosecond Pulse Characterization as Applied to One-Dimensional Photonic Band Edge Structures

Science.gov (United States)

Fork, Richard L.; Gamble, Lisa J.; Diffey, William M.

1999-01-01

The ability to control the group velocity and phase of an optical pulse is important to many current active areas of research. Electronically addressable one-dimensional photonic crystals are an attractive candidate to achieve this control. This report details work done toward the characterization of photonic crystals and improvement of the characterization technique. As part of the work, the spectral dependence of the group delay imparted by a GaAs/AlAs photonic crystal was characterized. Also, a first generation an electrically addressable photonic crystal was tested for the ability to electronically control the group delay. The measurement technique, using 100 femtosecond continuum pulses was improved to yield high spectral resolution (1.7 nanometers) and concurrently with high temporal resolution (tens of femtoseconds). Conclusions and recommendations based upon the work done are also presented.

Localized modes in optics of photonic liquid crystals with local anisotropy of absorption

Energy Technology Data Exchange (ETDEWEB)

Belyakov, V. A., E-mail: bel1937@mail.ru, E-mail: bel@landau.ac.ru [Russian Academy of Science, Landau Institute for Theoretical Physics (Russian Federation); Semenov, S. V. [National Research Center “Kurchatov Institute,” (Russian Federation)

2016-05-15

The localized optical modes in spiral photonic liquid crystals are theoretically studied for the certainty at the example of chiral liquid crystals (CLCs) for the case of CLC with an anisotropic local absorption. The model adopted here (absence of dielectric interfaces in the structures under investigation) makes it possible to get rid of mixing of polarizations on the surfaces of the CLC layer and of the defect structure and to reduce the corresponding equations to only the equations for light with polarization diffracting in the CLC. The dispersion equations determining connection of the edge mode (EM) and defect mode (DM) frequencies with the CLC layer parameters (anisotropy of local absorption, CLC order parameter) and other parameters of the DMS are obtained. Analytic expressions for the transmission and reflection coefficients of CLC layer and DMS for the case of CLC with an anisotropic local absorption are presented and analyzed. It is shown that the CLC layers with locally anisotropic absorption reduce the EM and DM lifetimes (and increase the lasing threshold) in the way different from the case of CLC with an isotropic local absorption. Due to the Borrmann effect revealing of which is different at the opposite stop-band edges in the case of CLC layers with an anisotropic local absorption the EM life-times for the EM frequencies at the opposite stop-bands edges may be significantly different. The options of experimental observations of the theoretically revealed phenomena are briefly discussed.

InGaAs/InAlAs single photon avalanche diode for 1550 nm photons.

Science.gov (United States)

Meng, Xiao; Xie, Shiyu; Zhou, Xinxin; Calandri, Niccolò; Sanzaro, Mirko; Tosi, Alberto; Tan, Chee Hing; Ng, Jo Shien

2016-03-01

A single photon avalanche diode (SPAD) with an InGaAs absorption region, and an InAlAs avalanche region was designed and demonstrated to detect 1550 nm wavelength photons. The characterization included leakage current, dark count rate and single photon detection efficiency as functions of temperature from 210 to 294 K. The SPAD exhibited good temperature stability, with breakdown voltage dependence of approximately 45 mV K(-1). Operating at 210 K and in a gated mode, the SPAD achieved a photon detection probability of 26% at 1550 nm with a dark count rate of 1 × 10(8) Hz. The time response of the SPAD showed decreasing timing jitter (full width at half maximum) with increasing overbias voltage, with 70 ps being the smallest timing jitter measured.

Numerical characterization of nanopillar photonic crystal waveguides and directional couplers

DEFF Research Database (Denmark)

Chigrin, Dmitry N.; Lavrinenko, Andrei; Sotomayor Torres, Clivia M.

2005-01-01

We numerically characterize a novel type of a photonic crystal waveguide, which consists of several rows of periodically arranged dielectric cylinders. In such a nanopillar photonic crystal waveguide, light confinement is due to the total internal reflection. A nanopillar waveguide is a multimode...

Evaluation of the two-photon absorption characteristics of GaSb/GaAs quantum rings

Energy Technology Data Exchange (ETDEWEB)

Wagener, M. C.; Botha, J. R. [Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth 6031 (South Africa); Carrington, P. J. [Department of Electronic and Electrical Engineering, University College London, London (United Kingdom); Krier, A. [Department of Physics, Lancaster University, Lancaster LA1 4YB (United Kingdom)

2014-07-28

The optical parameters describing the sub-bandgap response of GaSb/GaAs quantum rings solar cells have been obtained from photocurrent measurements using a modulated pseudo-monochromatic light source in combination with a second, continuous photo-filling source. By controlling the charge state of the quantum rings, the photoemission cross-sections describing the two-photon sub-bandgap transitions could be determined independently. Temperature dependent photo-response measurements also revealed that the barrier for thermal hole emission from the quantum rings is significantly below the quantum ring localisation energy. The temperature dependence of the sub-bandgap photo-response of the solar cell is also described in terms of the photo- and thermal-emission characteristics of the quantum rings.

Single-photon two-qubit entangled states: Preparation and measurement

International Nuclear Information System (INIS)

Kim, Yoon-Ho

2003-01-01

We implement experimentally a deterministic method to prepare and measure the so-called single-photon two-qubit entangled states or single-photon Bell states, in which the polarization and the spatial modes of a single photon each represent a quantum bit. All four single-photon Bell states can be easily prepared and measured deterministically using linear optical elements alone. We also discuss how this method can be used for the recently proposed single-photon two-qubit quantum cryptography scheme

Recent results on two-photon physics from Tasso and a review of measurements of the two-photon total cross section

International Nuclear Information System (INIS)

Kolanoski, H.

1983-03-01

Recent results on two-photon physics from the Tasso experiment are presented: the measurement of the two-photon production of Kanti K with the determination of the #betta##betta#-width of the f'(1515), an analysis of the angular correlations in the reaction #betta##betta#->rho 0 rho 0 ->π + π - π + π - and the observation of a narrow structure in the four pion mass spectrum around 2.1 GeV. In a separate part the experimental results on the total cross section for hadron production by two photons are reviewed. (orig.)

BioPhotonics Workstation: 3D interactive manipulation, observation and characterization

DEFF Research Database (Denmark)

Glückstad, Jesper

2011-01-01

In ppo.dk we have invented the BioPhotonics Workstation to be applied in 3D research on regulated microbial cell growth including their underlying physiological mechanisms, in vivo characterization of cell constituents and manufacturing of nanostructures and new materials.......In ppo.dk we have invented the BioPhotonics Workstation to be applied in 3D research on regulated microbial cell growth including their underlying physiological mechanisms, in vivo characterization of cell constituents and manufacturing of nanostructures and new materials....

Radiobiological characterization of different energy-photon beams used in radiotherapy from linear accelerator

International Nuclear Information System (INIS)

Elata, A.; Hassan, A. M. E.; Ali, E.; Calzolari, P.; Bettega, D.

2009-02-01

The main objective of this study was to perform a radiobiological characterization of different energy photon beams (6 MV and 15 MV) from linear accelerator used in radiotherapy, and comparison of different treatment modalities, with special regard to late effects of radiation. Using two end points, cell survival and micronucleus induction, in the biological system (Chines hamster V79 cell line). Chromosomes number was counted and found to be 22 chromosomes per cell. Cells were kept in confluent growth for two days and then exposed to two photon beams and immediately after irradiation were counted and re seeded in different numbered for each dose. For evaluation of surviving fraction samples were incubated at 37o C for 6 days, five samples were counted for each dose. At the same time three samples were seeded for the micronuclei frequency and incubated at 37o C after 24 hours cytochalasin-B was added to block cells in cytokinesis. The survival curve showed similar curves for the two beams and decreased with dose. The micronuclei frequency was positively correlated with dose and the energy of the photon. This indicates the presence of low dose of photoneutrons produced by using high energy photon beams. (Author)

Water-Soluble Triarylborane Chromophores for One- and Two-Photon Excited Fluorescence Imaging of Mitochondria in Cells.

Science.gov (United States)

Griesbeck, Stefanie; Zhang, Zuolun; Gutmann, Marcus; Lühmann, Tessa; Edkins, Robert M; Clermont, Guillaume; Lazar, Adina N; Haehnel, Martin; Edkins, Katharina; Eichhorn, Antonius; Blanchard-Desce, Mireille; Meinel, Lorenz; Marder, Todd B

2016-10-04

Three water-soluble tetracationic quadrupolar chromophores comprising two three-coordinate boron π-acceptor groups bridged by thiophene-containing moieties were synthesised for biological imaging applications. Compound 3 containing the bulkier 5-(3,5-Me2 C6 H2 )-2,2'-(C4 H2 S)2 -5'-(3,5-Me2 C6 H2 ) bridge is stable over a long period of time, exhibits a high fluorescence quantum yield and strong one- and two-photon absorption (TPA), and has a TPA cross section of 268 GM at 800 nm in water. Confocal laser scanning fluorescence microscopy studies in live cells indicated localisation of the chromophore at the mitochondria; moreover, cytotoxicity measurements proved biocompatibility. Thus, chromophore 3 has excellent potential for one- and two-photon-excited fluorescence imaging of mitochondrial function in cells. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Nonlinear Absorptions of CdSeTe Quantum Dots under Ultrafast Laser Radiation

Directory of Open Access Journals (Sweden)

Zhijun Chai

2016-01-01

Full Text Available The oil-soluble alloyed CdSeTe quantum dots (QDs are prepared by the electrostatic method. The basic properties of synthesized CdSeTe QDs are characterized by UV-Vis absorption spectroscopy, photoluminescence spectroscopy, inductively coupled plasma mass spectrometry, and transmission electron microscope. The off-resonant nonlinear optical properties of CdSeTe QDs are studied by femtosecond Z-scan at 1 kHz (low-repetition rate and 84 MHz (high-repetition rate. Nonlinear absorption coefficients are calculated under different femtosecond laser excitations. Due to the long luminescent lifetime of CdSeTe QDs, under the conditions of high-repetition rate, for open-aperture curve, heat accumulation and bleaching of ground state are responsible for the decrease of two-photon absorption (TPA coefficient.

Optical microscope using an interferometric source of two-color, two-beam entangled photons

Science.gov (United States)

Dress, William B.; Kisner, Roger A.; Richards, Roger K.

2004-07-13

Systems and methods are described for an optical microscope using an interferometric source of multi-color, multi-beam entangled photons. A method includes: downconverting a beam of coherent energy to provide a beam of multi-color entangled photons; converging two spatially resolved portions of the beam of multi-color entangled photons into a converged multi-color entangled photon beam; transforming at least a portion of the converged multi-color entangled photon beam by interaction with a sample to generate an entangled photon specimen beam; and combining the entangled photon specimen beam with an entangled photon reference beam within a single beamsplitter. An apparatus includes: a multi-refringent device providing a beam of multi-color entangled photons; a condenser device optically coupled to the multi-refringent device, the condenser device converging two spatially resolved portions of the beam of multi-color entangled photons into a converged multi-color entangled photon beam; a beam probe director and specimen assembly optically coupled to the condenser device; and a beam splitter optically coupled to the beam probe director and specimen assembly, the beam splitter combining an entangled photon specimen beam from the beam probe director and specimen assembly with an entangled photon reference beam.

Molecular engineering of two-photon fluorescent probes for bioimaging applications

Science.gov (United States)

Liu, Hong-Wen; Liu, Yongchao; Wang, Peng; Zhang, Xiao-Bing

2017-03-01

During the past two decades, two-photon microscopy (TPM), which utilizes two near-infrared photons as the excitation source, has emerged as a novel, attractive imaging tool for biological research. Compared with one-photon microscopy, TPM offers several advantages, such as lowering background fluorescence in living cells and tissues, reducing photodamage to biosamples, and a photobleaching phenomenon, offering better 3D spatial localization, and increasing penetration depth. Small-molecule-based two-photon fluorescent probes have been well developed for the detection and imaging of various analytes in biological systems. In this review, we will give a general introduction of molecular engineering of two-photon fluorescent probes based on different fluorescence response mechanisms for bioimaging applications during the past decade. Inspired by the desired advantages of small-molecule two-photon fluorescent probes in biological imaging applications, we expect that more attention will be devoted to the development of new two-photon fluorophores and applications of TPM in areas of bioanalysis and disease diagnosis.

PLGA nano/microparticles loaded with cresyl violet as a tracer for drug delivery: Characterization and in-situ hyperspectral fluorescence and 2-photon localization

Energy Technology Data Exchange (ETDEWEB)

Lunardi, Claure N., E-mail: clunardi@unb.br [Laboratory of Photochemistry and Nanobiotechnology, University of Brasília, Brasília (Brazil); Department of Biomedical Engineering and Radiology, Laboratory for Functional Optical Imaging, Columbia University, New York, NY (United States); Gomes, Anderson J. [Laboratory of Photochemistry and Nanobiotechnology, University of Brasília, Brasília (Brazil); Department of Biomedical Engineering and Radiology, Laboratory for Functional Optical Imaging, Columbia University, New York, NY (United States); Palepu, Sandeep; Galwaduge, P. Thilanka; Hillman, Elizabeth M.C. [Department of Biomedical Engineering and Radiology, Laboratory for Functional Optical Imaging, Columbia University, New York, NY (United States)

2017-01-01

Here we present the production, characterization and in-vivo assessment of cresyl violet-loaded biodegradable PLGA nano/microparticles (CV-NP and CV-MP). We demonstrate that the beneficial spectral characteristics of cresyl violet make it suitable as a tracer for particle-based drug delivery using both hyperspectral wide field and two-photon excited fluorescence microscopy. Particles were prepared using a cosolvent method, after which the physicochemical properties such as morphology, particle size, drug entrapment efficiency, drug loading and in vitro drug release behavior were measured in addition to spectroscopic properties, such as absorption, fluorescence and infrared spectra. The particles were then tested in an in vivo mouse model to assess their biodistribution characteristics. The location and integrity of particles after injection was determined using both hyperspectral fluorescence and two-photon microscopy within intact organs in situ. Our results show that cresyl violet is efficiently entrapped into PLGA particles, and that the particles are spherical in shape, ranging from 300 to 5070 nm in diameter. Particle biodistribution in the mouse was found to depend on particle size, as expected. Cresyl violet is shown to be an ideal tracer to assess the properties PLGA particle-based drug delivery in combination with our novel multi-scale optical imaging techniques for in-situ particle localization. - Highlights: • Cresyl violet entrapment into polymeric particles • Cresyl violet suitable as a tracer for particle-based drug delivery • Hyperspectral analysis of polymer nano/microparticles • Two-photon microscopy of polymeric nano/microparticles.

Evaluation of hybrid polymers for high-precision manufacturing of 3D optical interconnects by two-photon absorption lithography

Science.gov (United States)

Schleunitz, A.; Klein, J. J.; Krupp, A.; Stender, B.; Houbertz, R.; Gruetzner, G.

2017-02-01

The fabrication of optical interconnects has been widely investigated for the generation of optical circuit boards. Twophoton absorption (TPA) lithography (or high-precision 3D printing) as an innovative production method for direct manufacture of individual 3D photonic structures gains more and more attention when optical polymers are employed. In this regard, we have evaluated novel ORMOCER-based hybrid polymers tailored for the manufacture of optical waveguides by means of high-precision 3D printing. In order to facilitate future industrial implementation, the processability was evaluated and the optical performance of embedded waveguides was assessed. The results illustrate that hybrid polymers are not only viable consumables for industrial manufacture of polymeric micro-optics using generic processes such as UV molding. They also are potential candidates to fabricate optical waveguide systems down to the chip level where TPA-based emerging manufacturing techniques are engaged. Hence, it is shown that hybrid polymers continue to meet the increasing expectations of dynamically growing markets of micro-optics and optical interconnects due to the flexibility of the employed polymer material concept.

Study of nonlinear effects in photonic crystals doped with nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Singh, Mahi R [Department of Physics and Astronomy, University of Western Ontario, London, N6A 3K7 Ontario (Canada)

2008-07-14

A theory of nonlinear phenomena has been developed for a photonic crystal in the presence of a pump and a coupling laser field. The crystal is doped with an ensemble of four-level nanoparticle impurities. It is considered that the impurity particles are not only interacting with the photonic crystal but also with each other via dipole-dipole interaction. An expression for the susceptibility has been obtained using the density matrix method. The nonlinear effects due to the coupling and the pump fields have been included in the formulation. The absorption spectrum has been calculated in the presence of the strong coupling and pump fields for an isotropic photonic crystal made from dielectric spheres. The photonic crystal has a gap to midgap ratio of about 21%. It is predicted that the absorption spectrum in the photonic crystal can have zero, one, two or three absorptionless states by tuning one of the transition energies within the bands. This is an interesting phenomenon which can be used to make photonic switching devices. We have also calculated the absorption spectrum in the presence of the dipole-dipole interaction. It is found that a symmetric absorption spectrum changes to an asymmetric one due to this interaction. It is also found that there is a large enhancement in the absorption and the dispersion simultaneously for certain values of the detuning and concentration.

Study of nonlinear effects in photonic crystals doped with nanoparticles

International Nuclear Information System (INIS)

Singh, Mahi R

2008-01-01

A theory of nonlinear phenomena has been developed for a photonic crystal in the presence of a pump and a coupling laser field. The crystal is doped with an ensemble of four-level nanoparticle impurities. It is considered that the impurity particles are not only interacting with the photonic crystal but also with each other via dipole-dipole interaction. An expression for the susceptibility has been obtained using the density matrix method. The nonlinear effects due to the coupling and the pump fields have been included in the formulation. The absorption spectrum has been calculated in the presence of the strong coupling and pump fields for an isotropic photonic crystal made from dielectric spheres. The photonic crystal has a gap to midgap ratio of about 21%. It is predicted that the absorption spectrum in the photonic crystal can have zero, one, two or three absorptionless states by tuning one of the transition energies within the bands. This is an interesting phenomenon which can be used to make photonic switching devices. We have also calculated the absorption spectrum in the presence of the dipole-dipole interaction. It is found that a symmetric absorption spectrum changes to an asymmetric one due to this interaction. It is also found that there is a large enhancement in the absorption and the dispersion simultaneously for certain values of the detuning and concentration

A code for the calculation of self-absorption fractions of photons

International Nuclear Information System (INIS)

Jaegers, P.; Landsberger, S.

1988-01-01

Neutron activation analysis (NAA) is now a well-established technique used by many researchers and commercial companies. It is often wrongly assumed that these NAA methods are matrix independent over a wide variety of samples. Accuracy at the level of a few percent is often difficult to achieve, since components such as timing, pulse pile-up, high dead-time corrections, sample positioning, and chemical separations may severely compromise the results. One area that has received little attention is the calculation of the effect of self-absorption of gamma-rays (including low-energy ones) in samples, particularly those with major components of high-Z values. The analysis of trace components in lead samples is an obvious example, but other high-Z matrices such as various permutations and combinations of zinc, tin, lead, copper, silver, antimony, etc.; ore concentrates; and meteorites are also affected. The authors have developed a simple but effective personal-computer-compatible user-friendly code, however, which can calculate the amount of energy signal that is lost due to the presence of any amount of one or more Z components. The program is based on Dixon's paper of 1951 for the calculation of self-absorption corrections for linear, cylindrical, and spherical sources. To determine the self-absorption fraction of a photon in a source, the FORTRAN computer code SELFABS was written

A mitochondrial targeted two-photon iridium(III) phosphorescent probe for selective detection of hypochlorite in live cells and in vivo.

Science.gov (United States)

Li, Guanying; Lin, Qian; Sun, Lingli; Feng, Changsheng; Zhang, Pingyu; Yu, Bole; Chen, Yu; Wen, Ya; Wang, Hui; Ji, Liangnian; Chao, Hui

2015-01-01

Endogenous hypochlorite ion (ClO(-)) is a highly reactive oxygen species (ROS) that is produced from hydrogen peroxide and chloride ions catalyzed by myeloperoxidase (MPO). And mitochondrion is one of the major sources of ROS including ClO(-). In the present work, a two-photon phosphorescent probe for ClO(-) in mitochondria was developed. An iridium(III) complex bearing a diaminomaleonitrile group as ClO(-) reactive moiety specifically responded to ClO(-) over other ions and ROSs. When the probe was reacted with ClO(-) to form an oxidized carboxylate product, a significant enhancement in phosphorescence intensity was observed under one-photon (402 nm) and two-photon (750 nm) excitation, with a two-photon absorption cross-section of 78.1 GM at 750 nm. More importantly, ICP-MS results and cellular images co-stained with Mito-tracker Green demonstrated that this probe possessed high specificity for mitochondria. This probe was applied in the one- and two-photon imaging of ClO(-) in vitro and in vivo. The results suggested endotoxin lipopolysaccharide (LPS) induced ClO(-) mostly generated in the liver of zebrafish. Copyright © 2015 Elsevier Ltd. All rights reserved.

Precision two-photon spectroscopy of alkali elements

Indian Academy of Sciences (India)

effect is eliminated if the wave vector of the photons is ka = −kb, i.e., the two beams .... atomic cesium, and the metre is (indirectly) defined from the wavelength of .... plasma absorb radiation, the electrical circuit parameters may vary and this .... two-photon excitation followed by an ionization step in Ca [71], Sr [72] and Gd [73] ...

Two-photon excited whispering-gallery mode ultraviolet laser from an individual ZnO microneedle

Science.gov (United States)

Zhu, G. P.; Xu, C. X.; Zhu, J.; Lv, C. G.; Cui, Y. P.

2009-02-01

Wurtzite structural ZnO microneedles with hexagonal cross section were fabricated by vapor-phase transport method and an individual microneedle was employed as a lasing microcavity. Under excitation of a femtosecond pulse laser with 800 nm wavelength, the ultraviolet (UV) laser emission was obtained, which presented narrow linewidth and high Q value. The UV emission, resonant mechanism, and laser mode characteristics were discussed in detail. The results demonstrated that the UV laser originated from the whispering-gallery mode induced by two-photon absorption assisted by Rabi oscillation.

One-, two- and three-photon experiments

International Nuclear Information System (INIS)

Caldwell, D.O.; Cumalat, J.P.; Eisner, A.M.

1977-01-01

The results of experiments to provide further information about parton structure by getting into the deep inelastic region of π 0 electroproduction are presented. To analyse whether the interference between two- and three- photon exchange would give a difference between e + and e - scattering has been measured using the 20.5 GeV electron and 13.5 GeV positron beams and a hydrogen target. No evidence for the two-photon exchange has been observed within the experimental errors. Although the e + -e - difference in the three-photon experiment has been certainly + → γ/e - → γ= 1.09+-0.03. It yields a rough value of the parton mean cubed charge of 1.1+-0.5. The mere existence of the result provides strong support for the idea of constituent particles

Tuning the nonlinear optical absorption of reduced graphene oxide by chemical reduction.

Science.gov (United States)

Shi, Hongfei; Wang, Can; Sun, Zhipei; Zhou, Yueliang; Jin, Kuijuan; Redfern, Simon A T; Yang, Guozhen

2014-08-11

Reduced graphene oxides with varying degrees of reduction have been produced by hydrazine reduction of graphene oxide. The linear and nonlinear optical properties of both graphene oxide as well as the reduced graphene oxides have been measured by single beam Z-scan measurement in the picosecond region. The results reveal both saturable absorption and two-photon absorption, strongly dependent on the intensity of the pump pulse: saturable absorption occurs at lower pump pulse intensity (~1.5 GW/cm2 saturation intensity) whereas two-photon absorption dominates at higher intensities (≥5.7 GW/cm2). Intriguingly, we find that the two-photon absorption coefficient (from 1.5 cm/GW to 4.5cm/GW) and the saturation intensity (from 1 GW/cm2 to 2 GW/cm2) vary with chemical reduction, which is ascribed to the varying concentrations of sp2 domains and sp2 clusters in the reduced graphene oxides. Our results not only provide an insight into the evolution of the nonlinear optical coefficient in reduced graphene oxide, but also suggest that chemical engineering techniques may usefully be applied to tune the nonlinear optical properties of various nano-materials, including atomically thick graphene sheets.

Theoretical studies of one- and two-photon absorption properties for three molecules with different centers (B and N) and peripheral substituted groups [N(CH{sub 3}){sub 2} and CN

Energy Technology Data Exchange (ETDEWEB)

Han Deming [State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130023 (China); Feng Jikang, E-mail: jikangf@yahoo.co [State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130023 (China); College of Chemistry, Jilin University, Changchun 130023 (China); Ren Aimin [State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130023 (China); Shang Xiaohong [College of Chemistry, Jilin University, Changchun 130023 (China); Liu Xiaojuan [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China)

2009-08-15

Three molecules with different centers (boron and nitrogen) and peripheral substituted groups [N(CH{sub 3}){sub 2} and CN] have been theoretically studied with B3LYP/6-31G(d) associated with ZINDO and sum-over-states methods. The maximum two-photon absorption cross-section delta{sub max} of the molecule with boron (B) center and N(CH{sub 3}){sub 2} peripheral group is larger than that of the molecule with nitrogen (N) center and N(CH{sub 3}){sub 2} peripheral group. As for the two molecules with N center, the delta{sub max} is obviously increased with the change from N(CH{sub 3}){sub 2} to CN group. This indicates that the large intramolecular charge transfer is in favor of the TPA response.

Observation of soliton compression in silicon photonic crystals

Science.gov (United States)

Blanco-Redondo, A.; Husko, C.; Eades, D.; Zhang, Y.; Li, J.; Krauss, T.F.; Eggleton, B.J.

2014-01-01

Solitons are nonlinear waves present in diverse physical systems including plasmas, water surfaces and optics. In silicon, the presence of two photon absorption and accompanying free carriers strongly perturb the canonical dynamics of optical solitons. Here we report the first experimental demonstration of soliton-effect pulse compression of picosecond pulses in silicon, despite two photon absorption and free carriers. Here we achieve compression of 3.7 ps pulses to 1.6 ps with photonic crystal waveguide and an ultra-sensitive frequency-resolved electrical gating technique to detect the ultralow energies in the nanostructured device. Strong agreement with a nonlinear Schrödinger model confirms the measurements. These results further our understanding of nonlinear waves in silicon and open the way to soliton-based functionalities in complementary metal-oxide-semiconductor-compatible platforms. PMID:24423977

Fluorescent Pluronic nanodots for in vivo two-photon imaging

International Nuclear Information System (INIS)

Maurin, Mathieu; Vurth, Laeticia; Vial, Jean-Claude; Baldeck, Patrice; Stephan, Olivier; Marder, Seth R; Sanden, Boudewijn Van der

2009-01-01

We report the synthesis of new nanosized fluorescent probes based on bio-compatible polyethylene-polypropylene glycol (Pluronic) materials. In aqueous solution, mini-emulsification of Pluronic with a high fluorescent di-stryl benzene-modified derivative, exhibiting a two-photon absorption cross section as high as 2500 Goeppert-Mayer units at 800 nm, leads to nanoparticles exhibiting a hydrodynamic radius below 100 nm. We have demonstrated that these new probes with luminescence located in the spectral region of interest for bio-imaging (the yellow part of the visible spectrum) allow deep (500 μm) bio-imaging of the mice brain vasculature. The dose injected during our experiments is ten times lower when compared to the classical commercial rhodamine-B isothicyanate-Dextran system but gives similar results to homogeneous blood plasma staining. The mean fluorescent signal intensity stayed constant during more than 1 h.

Ultrafast S1 and ICT state dynamics of a marine carotenoid probed by femtosecond one- and two-photon pump-probe spectroscopy

International Nuclear Information System (INIS)

Kosumi, Daisuke; Kusumoto, Toshiyuki; Fujii, Ritsuko; Sugisaki, Mitsuru; Iinuma, Yoshiro; Oka, Naohiro; Takaesu, Yuki; Taira, Tomonori; Iha, Masahiko; Frank, Harry A.; Hashimoto, Hideki

2011-01-01

Ultrafast relaxation kinetics of fucoxanthin in polar and non-polar solvents have been studied by femtosecond pump-probe spectroscopy. Transient absorption associated with S 1 or intramolecular charge transfer (ICT) excited state has been observed following either one-photon excitation to the optically allowed S 2 state or two-photon excitation to the symmetry-forbidden S 1 state. The results suggest that the ICT state formed after excitation of fucoxanthin in a polar solvent is a distinct excited state from S 1 .

Macroscopic optical response and photonic bands

International Nuclear Information System (INIS)

Pérez-Huerta, J S; Luis Mochán, W; Ortiz, Guillermo P; Mendoza, Bernardo S

2013-01-01

We develop a formalism for the calculation of the macroscopic dielectric response of composite systems made of particles of one material embedded periodically within a matrix of another material, each of which is characterized by a well-defined dielectric function. The nature of these dielectric functions is arbitrary, and could correspond to dielectric or conducting, transparent or opaque, absorptive and dispersive materials. The geometry of the particles and the Bravais lattice of the composite are also arbitrary. Our formalism goes beyond the long-wavelength approximation as it fully incorporates retardation effects. We test our formalism through the study of the propagation of electromagnetic waves in two-dimensional photonic crystals made of periodic arrays of cylindrical holes in a dispersionless dielectric host. Our macroscopic theory yields a spatially dispersive macroscopic response which allows the calculation of the full photonic band structure of the system, as well as the characterization of its normal modes, upon substitution into the macroscopic field equations. We can also account approximately for the spatial dispersion through a local magnetic permeability and analyze the resulting dispersion relation, obtaining a region of left handedness. (paper)

Interference of two photons in parametric down conversion

International Nuclear Information System (INIS)

Ghosh, R.; Hong, C.K.; Ou, Z.Y.; Mandel, L.

1986-01-01

A theoretical treatment is given of the process in which the two photons produced simultaneously in the parametric frequency splitting of light are allowed to interfere. It is shown that, while there is no interference in the usual sense involving quantities that are of the second order in the field, fourth-order interference effects are present. These may be revealed by measuring the joint probability of detecting two photons at two points x,x' in the interference plane with photoelectric detectors as a function of the separation x-x'. The probability exhibits a cosine modulation with x-x', with visibility that can approach 100%, even though the integration time in the experiment may greatly exceed the reciprocal bandwidth of the photons. The interference effect has a nonclassical origin and implies a violation of local realism in the highly correlated two-photon state

Two-photon Photoactivation to Measure Histone Exchange Dynamics in Plant Root Cells.

Science.gov (United States)

Rosa, Stefanie; Shaw, Peter

2015-10-20

Chromatin-binding proteins play a crucial role in chromatin structure and gene expression. Direct binding of chromatin proteins both maintains and regulates transcriptional states. It is therefore important to study the binding properties of these proteins in vivo within the natural environment of the nucleus. Photobleaching, photoactivation and photoconversion (photoswitching) can provide a non-invasive experimental approach to study dynamic properties of living cells and organisms. We used photoactivation to determine exchange dynamics of histone H2B in plant stem cells of the root (Rosa et al. , 2014). The stem cells of the root are located in the middle of the tissue, which made it impossible to carry out photoactivation of sufficiently small and well-defined sub-cellular regions with conventional laser illumination in the confocal microscope, mainly because scattering and refraction effects within the root tissue dispersed the focal spot and caused photoactivation of too large a region. We therefore used 2-photon activation, which has much better inherent resolution of the illuminated region. This is because the activation depends on simultaneous absorption of two or more photons, which in turns depends on the square (or higher power) of the intensity-a much sharper peak. In this protocol we will describe the experimental procedure to perform two-photon photoactivation experiments and the corresponding image analysis. This protocol can be used for nuclear proteins tagged with photoactivable GFP (PA-GFP) expressed in root tissues.

Investigation of human teeth with respect to the photon interaction, energy absorption and buildup factor

Energy Technology Data Exchange (ETDEWEB)

Kurudirek, Murat, E-mail: mkurudirek@gmail.co [Faculty of Science, Department of Physics, Ataturk University, 25240 Erzurum (Turkey); Topcuoglu, Sinan [Faculty of Dentistry, Department of Endodontic, Ataturk University, 25240 Erzurum (Turkey)

2011-05-15

The effective atomic numbers and electron densities of human teeth have been calculated for total photon interaction (Z{sub PI{sub e{sub f{sub f}}}},Ne{sub PI{sub e{sub f{sub f}}}}) and photon energy absorption (Z{sub PEA{sub e{sub f{sub f}}}},Z{sub RW{sub e{sub f{sub f}}}}Ne{sub PEA{sub e{sub f{sub f}}}}) in the energy region 1 keV-20 MeV. Besides, the energy absorption (EABF) and exposure (EBF) buildup factors have been calculated for these samples by using the geometric progression fitting approximation in the energy region 0.015-15 MeV up to 40 mfp (mean free path). Wherever possible the results were compared with experiment. Effective atomic numbers (Z{sub PI{sub e{sub f{sub f}}}}) of human teeth were calculated using different methods. Discrepancies were noted in Z{sub PI{sub e{sub f{sub f}}}} between the direct and interpolation methods in the low and high energy regions where absorption processes dominate while good agreement was observed in intermediate energy region where Compton scattering dominates. Significant variations up to 22% were observed between Z{sub PI{sub e{sub f{sub f}}}} and Z{sub PEA{sub e{sub f{sub f}}}} in the energy region 30-150 keV which is the used energy range in dental cone beam computed tomography (CBCT) X-ray machines. The Z{sub eff} values of human teeth were found to relatively vary within 1% if different laser treatments are applied. In this variation, the Er:YAG laser treated samples were found to be less effected than Nd:YAG laser treated ones when compared with control group. Relative differences between EABF and EBF were found to be significantly high in the energy region 60 keV-1 MeV even though they have similar variations with respect to the different parameters viz. photon energy, penetration depth.

Two photon versus one photon fluorescence excitation in whispering gallery mode microresonators

International Nuclear Information System (INIS)

Pastells, Carme; Marco, M.-Pilar; Merino, David; Loza-Alvarez, Pablo; Pasquardini, Laura; Lunelli, Lorenzo; Pederzolli, Cecilia; Daldosso, Nicola; Farnesi, Daniele; Berneschi, Simone; Righini, Giancarlo C.; Quercioli, Franco; Nunzi Conti, Gualtiero; Soria, Silvia

2016-01-01

We investigate the feasibility of both one photon and two photon fluorescence excitation using whispering gallery mode microresonators. We report the linear and non linear fluorescence real-time detection of labeled IgG covalently bonded to the surface of a silica whispering gallery mode resonator (WGMR). The immunoreagents have been immobilized onto the surface of the WGMR sensor after being activated with an epoxy silane and an orienting layer. The developed immunosensor presents great potential as a robust sensing device for fast and early detection of immunoreactions. We also investigate the potential of microbubbles as nonlinear enhancement platform. The dyes used in these studies are dylight800, tetramethyl rhodamine isothiocyanate, rhodamine 6G and fluorescein. All measurements were performed in a modified confocal microscope. - Highlights: • One photon fluorescence overlaps with the semiconductor pump laser gain bandwidth. • We report on the feasibility to excite two photon fluorescence in microbubble resonators. • Our functionalization process maintains a good quality factor of the microresonator.

Two photon versus one photon fluorescence excitation in whispering gallery mode microresonators

Energy Technology Data Exchange (ETDEWEB)

Pastells, Carme; Marco, M.-Pilar [Nanobiotechnology for Diagnostics Group (Nb4Dg), IQAC-CSIC, 08034 Barcelona (Spain); CIBER de Bioingeniería, Biomateriales y Nanomedicina, 08034 Barcelona (Spain); Merino, David; Loza-Alvarez, Pablo [ICFO-Institut de Ciències Fotòniques, Castelldefels, 08860 Barcelona (Spain); Pasquardini, Laura [Fondazione Bruno Kessler, 38123 Povo, TN (Italy); Lunelli, Lorenzo [Fondazione Bruno Kessler, 38123 Povo, TN (Italy); IBF-CNR, 38123 Povo, TN (Italy); Pederzolli, Cecilia [Fondazione Bruno Kessler, 38123 Povo, TN (Italy); Daldosso, Nicola [Department of Computer Science, University of Verona, Strada le Grazie 15, 37134 Verona (Italy); Farnesi, Daniele [CNR-IFAC “Nello Carrara” Institute of Applied Physics, 50019 Sesto Fiorentino, FI (Italy); Museo Storico della Fisica e Centro Studi e Ricerche “E. Fermi”, 00184 Roma (Italy); Berneschi, Simone [CNR-IFAC “Nello Carrara” Institute of Applied Physics, 50019 Sesto Fiorentino, FI (Italy); Righini, Giancarlo C. [CNR-IFAC “Nello Carrara” Institute of Applied Physics, 50019 Sesto Fiorentino, FI (Italy); Museo Storico della Fisica e Centro Studi e Ricerche “E. Fermi”, 00184 Roma (Italy); Quercioli, Franco [CNR-INO National Institute of Optics, Sesto Fiorentino, FI (Italy); Nunzi Conti, Gualtiero [CNR-IFAC “Nello Carrara” Institute of Applied Physics, 50019 Sesto Fiorentino, FI (Italy); Soria, Silvia, E-mail: s.soria@ifac.cnr.it [CNR-IFAC “Nello Carrara” Institute of Applied Physics, 50019 Sesto Fiorentino, FI (Italy)

2016-02-15

We investigate the feasibility of both one photon and two photon fluorescence excitation using whispering gallery mode microresonators. We report the linear and non linear fluorescence real-time detection of labeled IgG covalently bonded to the surface of a silica whispering gallery mode resonator (WGMR). The immunoreagents have been immobilized onto the surface of the WGMR sensor after being activated with an epoxy silane and an orienting layer. The developed immunosensor presents great potential as a robust sensing device for fast and early detection of immunoreactions. We also investigate the potential of microbubbles as nonlinear enhancement platform. The dyes used in these studies are dylight800, tetramethyl rhodamine isothiocyanate, rhodamine 6G and fluorescein. All measurements were performed in a modified confocal microscope. - Highlights: • One photon fluorescence overlaps with the semiconductor pump laser gain bandwidth. • We report on the feasibility to excite two photon fluorescence in microbubble resonators. • Our functionalization process maintains a good quality factor of the microresonator.

Characterization of our source of polarization-entangled photons

Science.gov (United States)

Adenier, Guillaume

2012-12-01

We present our source of polarization entangled photons, which consist of orthogonally polarized and collinear parametric down converted photons sent to the same input of a nonpolarizing beam splitter. We show that a too straightforward characterization of the quantum state cannot account for all the experimental observations, in particular for the behavior of the doublecounts, which are the coincidences produced whenever both photons are dispatched by the beam splitter to the same measuring station (either Alice or Bob). We argue that in order to account for all observations, the state has to be entangled in polarization before the non-polarizing beam splitter, and we discuss the intriguing and nevertheless essential role of the time-compensation required to obtain such a polarization entanglement.

Diagnosis of basal cell carcinoma by two photon excited fluorescence combined with lifetime imaging

Science.gov (United States)

Fan, Shunping; Peng, Xiao; Liu, Lixin; Liu, Shaoxiong; Lu, Yuan; Qu, Junle

2014-02-01

Basal cell carcinoma (BCC) is the most common type of human skin cancer. The traditional diagnostic procedure of BCC is histological examination with haematoxylin and eosin staining of the tissue biopsy. In order to reduce complexity of the diagnosis procedure, a number of noninvasive optical methods have been applied in skin examination, for example, multiphoton tomography (MPT) and fluorescence lifetime imaging microscopy (FLIM). In this study, we explored two-photon optical tomography of human skin specimens using two-photon excited autofluorescence imaging and FLIM. There are a number of naturally endogenous fluorophores in skin sample, such as keratin, melanin, collagen, elastin, flavin and porphyrin. Confocal microscopy was used to obtain structures of the sample. Properties of epidermic and cancer cells were characterized by fluorescence emission spectra, as well as fluorescence lifetime imaging. Our results show that two-photon autofluorescence lifetime imaging can provide accurate optical biopsies with subcellular resolution and is potentially a quantitative optical diagnostic method in skin cancer diagnosis.

Monte Carlo simulation of two-photon processes

International Nuclear Information System (INIS)

Daverveldt, P.H.W.M.

1985-01-01

During the last two decades e + e - collider experiments provided physicists with a wealth of important discoveries concerning elementary particle physics. This thesis explains in detail how the Monte Carlo approach can be applied to establish the comparison between two-photon experiments and theory. The author describes the main motives for and objectives of two-photon research. He defines the kinematics and pays attention to some special kinematical regions. Also a popular approximation for the exact differential cross section is reviewed. Next he discusses the calculation of the complete lowest order cross section for processes with four leptons in the final state and for reactions such as e + e - →e + e - qanti q, e + e - →μ + μ - qanti q. Radiative corrections to the multiperipheral diagrams are considered. The author explains in detail the distinction between soft and hard photon corrections which turns out to be somewhat more tricky than in the case of radiative corrections to one-photon processes. Finally, he presents some results which were obtained by using the event generators. (Auth.)

Importance of the green color, absorption gradient, and spectral absorption of chloroplasts for the radiative energy balance of leaves.

Science.gov (United States)

Kume, Atsushi

2017-05-01

Terrestrial green plants absorb photosynthetically active radiation (PAR; 400-700 nm) but do not absorb photons evenly across the PAR waveband. The spectral absorbance of photosystems and chloroplasts is lowest for green light, which occurs within the highest irradiance waveband of direct solar radiation. We demonstrate a close relationship between this phenomenon and the safe and efficient utilization of direct solar radiation in simple biophysiological models. The effects of spectral absorptance on the photon and irradiance absorption processes are evaluated using the spectra of direct and diffuse solar radiation. The radiation absorption of a leaf arises as a consequence of the absorption of chloroplasts. The photon absorption of chloroplasts is strongly dependent on the distribution of pigment concentrations and their absorbance spectra. While chloroplast movements in response to light are important mechanisms controlling PAR absorption, they are not effective for green light because chloroplasts have the lowest spectral absorptance in the waveband. With the development of palisade tissue, the incident photons per total palisade cell surface area and the absorbed photons per chloroplast decrease. The spectral absorbance of carotenoids is effective in eliminating shortwave PAR (solar radiation. However, most of the near infrared radiation is unabsorbed and heat stress is greatly reduced. The incident solar radiation is too strong to be utilized for photosynthesis under the current CO 2 concentration in the terrestrial environment. Therefore, the photon absorption of a whole leaf is efficiently regulated by photosynthetic pigments with low spectral absorptance in the highest irradiance waveband and through a combination of pigment density distribution and leaf anatomical structures.

Characterization of 2PA Chromophores

Science.gov (United States)

2016-01-01

When performing perturbation theory to calculate two-photon absorption, it is the product of one-photon absorption matrix elements (proportional to...vol. 2, pp. 1776-1790, 2012. [29] T. Xia, D. J. Hagan, M. Sheik-Bahae, and E. W. Van Stryland, "Eclipsing Z-Scan Measurement of ( lambda /10^4

Stimulated emission depletion following two photon excitation

OpenAIRE

Marsh, R. J.; Armoogum, D. A.; Bain, A. J.

2002-01-01

The technique of stimulated emission depletion of fluorescence (STED) from a two photon excited molecular population is demonstrated in the S, excited state of fluorescein in ethylene glycol and methanol. Two photon excitation (pump) is achieved using the partial output of a regeneratively amplified Ti:Sapphire laser in conjunction with an optical parametric amplifier whose tuneable output provides a synchronous depletion (dump) pulse. Time resolved fluorescence intensity and anisotropy measu...

Photonic crystal fibre enables short-wavelength two-photon laser scanning fluorescence microscopy with fura-2

International Nuclear Information System (INIS)

McConnell, Gail; Riis, Erling

2004-01-01

We report on a novel and compact reliable laser source capable of short-wavelength two-photon laser scanning fluorescence microscopy based on soliton self-frequency shift effects in photonic crystal fibre. We demonstrate the function of the system by performing two-photon microscopy of smooth muscle cells and cardiac myocytes from the rat pulmonary vein and Chinese hamster ovary cells loaded with the fluorescent calcium indicator fura-2/AM

One-bit photon polarization in two-photon experiments. An information mechanics perspective

International Nuclear Information System (INIS)

Kantor, F.W.

1991-01-01

In this paper is presented a detailed treatment of amount and representation of photon polarization information in the two-photon experiments of Aspect, Grangier, and Roger, seeking to test Einstein, Podolsky, and Rosen's thought experiment. Newton's mechanics, Einstein's relativistic mechanics, and quantum mechanics do not treat as fundamental the amount and representation of information in physical systems. The line of reasoning presented here was reached via Kantor's information mechanics. The information bookkeeping presented here appears to offer a simple, physical insight into what the apparatus and the photons are doing together

Polarization dependence of two-photon transition intensities in rare-earth doped crystals

Energy Technology Data Exchange (ETDEWEB)

Le Nguyen, An-Dien [Univ. of California, Berkeley, CA (United States)

1996-05-01

A polarization dependence technique has been developed as a tool to investigate phonon scattering (PS), electronic Raman scattering (ERS), and two-photon absorption (TPA) transition intensities in vanadate and phosphate crystals. A general theory for the polarization dependence (PD) of two-photon transition intensities has been given. Expressions for the polarization dependent behavior of two-photon transition intensities have been tabulated for the 32 crystallographic point groups. When the wavefunctions for the initial and final states of a rare-earth doped in crystals are known, explicit PD expressions with no unknown parameters can be obtained. A spectroscopic method for measuring and interpreting phonon and ERS intensities has been developed to study PrVO₄, NdVO₄, ErVO₄, and TmVO₄ crystals. Relative phonon intensities with the polarization of the incident and scattered light arbitrarily varied were accurately predicted and subsequently used for alignment and calibration in ERS measurements in these systems for the first time. Since ERS and PS intensities generally follow different polarization curves as a function of polar angles, the two can be uniquely identified by comparing their respective polarization behavior. The most crucial application of the technique in ERS spectroscopy is the establishment of a stringent test for the Axe theory. For the first time, the F₁/F₂ ratio extracted from the experimental fits of the ERS intensities were compared with those predicted by theories which include both the second- and third-order contributions. Relatively good agreement between the fitted values of F₁/F₂ and the predicted values using the second-order theory has been found.

In vivo reactive neural plasticity investigation by means of correlative two photon: electron microscopy

Science.gov (United States)

Allegra Mascaro, A. L.; Cesare, P.; Sacconi, L.; Grasselli, G.; Mandolesi, G.; Maco, B.; Knott, G.; Huang, L.; De Paola, V.; Strata, P.; Pavone, F. S.

2013-02-01

In the adult nervous system, different populations of neurons correspond to different regenerative behavior. Although previous works showed that olivocerebellar fibers are capable of axonal regeneration in a suitable environment as a response to injury1, we have hitherto no details about the real dynamics of fiber regeneration. We set up a model of singularly axotomized climbing fibers (CF) to investigate their reparative properties in the adult central nervous system (CNS) in vivo. Time lapse two-photon imaging has been combined to laser nanosurgery2, 3 to define a temporal pattern of the degenerative event and to follow the structural rearrangement after injury. To characterize the damage and to elucidate the possible formation of new synaptic contacts on the sprouted branches of the lesioned CF, we combined two-photon in vivo imaging with block face scanning electron microscopy (FIB-SEM). Here we describe the approach followed to characterize the reactive plasticity after injury.

Entanglement of two-qubit photon beam by magnetic field

Energy Technology Data Exchange (ETDEWEB)

Levin, A.D.; Castro, R.A. [University of Sao Paulo, Institute of Physics, CP 66318, Sao Paulo (Brazil); Gitman, D.M. [University of Sao Paulo, Institute of Physics, CP 66318, Sao Paulo (Brazil); P.N. Lebedev Physical Institute, Moscow (Russian Federation); Tomsk State University, Tomsk (Russian Federation)

2014-09-15

We study the possibility of affecting the entanglement in a two-qubit system consisting of two photons with different fixed frequencies but with two arbitrary linear polarizations, moving in the same direction, with the help of an applied external magnetic field. The interaction between the magnetic field and the photons in our model is achieved through intermediate electrons that interact both with the photons and the magnetic field. The possibility of an exact theoretical analysis of this scheme is based on well-known exact solutions that describe the interaction of an electron subjected to an external magnetic field (or a medium of electrons not interacting with each other) with a quantized field of two photons. We adapt these exact solutions to the case under consideration. Using explicit wave functions for the resulting electromagnetic field, we calculate the entanglement measures (the information and the Schmidt ones) of the photon beam as functions of the applied magnetic field and the parameters of the electron medium. (orig.)

Structure-property-correlation of 3D microstructures fabricated using two-photon-polymerization

International Nuclear Information System (INIS)

Cicha, K.

2012-01-01

In the research field of materials sciences, the determination of material properties such as Young's modulus, tensile strength, elongation at break and the like is done on a routine basis. However, when the size of the available test sample gets smaller (in the range of a few millimeters) many of the classic material testing methods are no longer applicable. Components or structures which were fabricated using two-photon polymerization (2PP) are micrometer scale - traditional testing methods are no longer applicable. It was therefore the aim of this thesis to develop routines which allow a characterization of materials or material components (monomer, photoinitiator) with respect to their suitability for the two-photon process. The three methods differ significantly in terms of the measurement result, the user friendliness and the effort for evaluation of the measurement. While the first method is based on optical assessment of manufactured structures and thus provides no quantifiable results, method 2 and method 3 give a quantifiable measure as result of the test procedure. In method 2, the double-bond conversion is measured by using FTIR spectroscopy giving direct information on the reactivity of the material formulation. Method 3 is based on the measurement of the Young's modulus of micro-cantilevers that are deflected by a standard nanoindentation device recording the load and the corresponding deflection signals. Quantifiable measurement of material properties on samples that were fabricated by two-photon polymerization represents an absolute novelty and can provide new insights into the exact mechanisms of the two-photon polymerization. (author) [de

Mass distribution for the two-photon channel

CERN Multimedia

ATLAS, collaboration

2012-01-01

Mass distribution for the two-photon channel. The strongest evidence for this new particle comes from analysis of events containing two photons. The smooth dotted line traces the measured background from known processes. The solid line traces a statistical fit to the signal plus background. The new particle appears as the excess around 126.5 GeV. The full analysis concludes that the probability of such a peak is three chances in a million.

Two-Photon-Excited Silica and Organosilica Nanoparticles for Spatiotemporal Cancer Treatment.

Science.gov (United States)

Croissant, Jonas G; Zink, Jeffrey I; Raehm, Laurence; Durand, Jean-Olivier

2018-04-01

Coherent two-photon-excited (TPE) therapy in the near-infrared (NIR) provides safer cancer treatments than current therapies lacking spatial and temporal selectivities because it is characterized by a 3D spatial resolution of 1 µm 3 and very low scattering. In this review, the principle of TPE and its significance in combination with organosilica nanoparticles (NPs) are introduced and then studies involving the design of pioneering TPE-NIR organosilica nanomaterials are discussed for bioimaging, drug delivery, and photodynamic therapy. Organosilica nanoparticles and their rich and well-established chemistry, tunable composition, porosity, size, and morphology provide ideal platforms for minimal side-effect therapies via TPE-NIR. Mesoporous silica and organosilica nanoparticles endowed with high surface areas can be functionalized to carry hydrophobic and biologically unstable two-photon absorbers for drug delivery and diagnosis. Currently, most light-actuated clinical therapeutic applications with NPs involve photodynamic therapy by singlet oxygen generation, but low photosensitizing efficiencies, tumor resistance, and lack of spatial resolution limit their applicability. On the contrary, higher photosensitizing yields, versatile therapies, and a unique spatial resolution are available with engineered two-photon-sensitive organosilica particles that selectively impact tumors while healthy tissues remain untouched. Patients suffering pathologies such as retinoblastoma, breast, and skin cancers will greatly benefit from TPE-NIR ultrasensitive diagnosis and therapy. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Cascaded two-photon nonlinearity in a one-dimensional waveguide with multiple two-level emitters

Science.gov (United States)

Roy, Dibyendu

2013-01-01

We propose and theoretically investigate a model to realize cascaded optical nonlinearity with few atoms and photons in one-dimension (1D). The optical nonlinearity in our system is mediated by resonant interactions of photons with two-level emitters, such as atoms or quantum dots in a 1D photonic waveguide. Multi-photon transmission in the waveguide is nonreciprocal when the emitters have different transition energies. Our theory provides a clear physical understanding of the origin of nonreciprocity in the presence of cascaded nonlinearity. We show how various two-photon nonlinear effects including spatial attraction and repulsion between photons, background fluorescence can be tuned by changing the number of emitters and the coupling between emitters (controlled by the separation). PMID:23948782

CERN: A tale of two photons

International Nuclear Information System (INIS)

Anon.

1993-01-01

When precision data from the several million Zs carefully collected over several years by the four big experiments - Aleph, Delphi, L3 and Opal - at CERN's LEP electron-positron collider have otherwise consistently underlined conventional physics, a hint of something unexplained quickly packs the seminar rooms. In 1991, the L3 experiment turned up two examples of Z decays producing a muon pair accompanied by a widely separated pair of high energy photons, with the photon pair in each case taking some 60 GeV of energy (actually 58.8 and 59.0 GeV). Nothing to get excited about at the time, but ongoing data analysis tuned into this channel. This year two more events turned up, one again with a muon pair accompanied by a 60 GeV photon pair, the other with an electron (electron-positron) pair and a 62 GeV photon pair. At first L3 preferred to keep this quiet, and the news was not announced at the major international meeting in Dallas last August. The first public announcement of the four unexplained events (out of a total of 1.6 million Z decays) came in a LEP Experiments Committee session at CERN in October

Resonant photoionization absorption spectra of spherical quantum dots

CERN Document Server

Bondarenko, V

2003-01-01

We study theoretically the mid-infrared photon absorption spectra due to bound-free transitions of electrons in individual spherical quantum dots. It is established that change of the dot size in one or two atomic layers or/and number of electrons by one or two can change the peak value of the absorption spectra in orders of magnitude and energy of absorbed photons by tens of millielectronvolts. The reason for this is the formation of specific free states, called resonance states. Numerical calculations are performed for quantum dots (QDs) with radius varying up to 200 A, and one to eight electrons occupying the two lowest bound states. It is supposed that realistic QD systems with resonance states would be of much advantage to design novel infrared QD photo-detectors.

Ultrafast S{sub 1} and ICT state dynamics of a marine carotenoid probed by femtosecond one- and two-photon pump-probe spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Kosumi, Daisuke, E-mail: kosumi@sci.osaka-cu.ac.j [CREST/JST and Department of Physics, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585 (Japan); Kusumoto, Toshiyuki [CREST/JST and Department of Physics, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585 (Japan); Fujii, Ritsuko; Sugisaki, Mitsuru [CREST/JST and Department of Physics, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585 (Japan); Osaka City University Advanced Research Institute for Natural Science and Technology (OCARINA), Osaka (Japan); Iinuma, Yoshiro; Oka, Naohiro; Takaesu, Yuki; Taira, Tomonori; Iha, Masahiko [South Product Co. Ltd., 12-75 Suzaki, Uruma-shi, Okinawa 904-2234 (Japan); Frank, Harry A. [Department of Chemistry, University of Connecticut, Storrs, CT 06269-3060 (United States); Hashimoto, Hideki, E-mail: hassy@sci.osaka-cu.ac.j [CREST/JST and Department of Physics, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585 (Japan); Osaka City University Advanced Research Institute for Natural Science and Technology (OCARINA), Osaka (Japan)

2011-03-15

Ultrafast relaxation kinetics of fucoxanthin in polar and non-polar solvents have been studied by femtosecond pump-probe spectroscopy. Transient absorption associated with S{sub 1} or intramolecular charge transfer (ICT) excited state has been observed following either one-photon excitation to the optically allowed S{sub 2} state or two-photon excitation to the symmetry-forbidden S{sub 1} state. The results suggest that the ICT state formed after excitation of fucoxanthin in a polar solvent is a distinct excited state from S{sub 1}.

Two-dimensional plasma photonic crystals in dielectric barrier discharge

International Nuclear Information System (INIS)

Fan Weili; Dong Lifang; Zhang Xinchun

2010-01-01

A series of two-dimensional plasma photonic crystals have been obtained by filaments' self-organization in atmospheric dielectric barrier discharge with two water electrodes, which undergo the transition from square to square superlattice and finally to the hexagon. The spatio-temporal behaviors of the plasma photonic crystals in nanosecond scale have been studied by optical method, which show that the plasma photonic crystal is actually an integration of different transient sublattices. The photonic band diagrams of the transverse electric (TE) mode and transverse magnetic mode for each sublattice of these plasma photonic crystals have been investigated theoretically. A wide complete band gap is formed in the hexagonal plasma photonic crystal with the TE mode. The changes of the band edge frequencies and the band gap widths in the evolvement of different structures are studied. A kind of tunable plasma photonic crystal which can be controlled both in space and time is suggested.

Effects of four-wave mixing on four-photon resonance excitation and ionization in the presence of a three-photon intermediate state resonance enhancement

International Nuclear Information System (INIS)

Payne, M.G.; Miller, J.C.; Hart, R.C.; Garrett, W.R.

1991-01-01

We consider effects which occur when four-wave sum frequency generation and multiphoton ionization are induced by lasers tuned near a three-photon resonance and simultaneously near or at a dipole allowed four-photon resonance. In studies with unfocused laser beams, if the phase mismatch of the generated four-wave-mixing field is large and the related two-photon resonance for the absorption of a four-wave-mixing photon and a laser photon results in strong absorption of the four-wave-mixing field, a coherent cancellation occurs between the pumping of the resonance by two- and four-photon processes. This interference effect occurs when the first laser is tuned on either side of the three-photon resonance and |Δk rL |much-gt 1, where Δk r is the mismatch and L is the length of the path of the laser beams in the gas. With focused laser beams large differences occur between ionization with unidirectional beams and with counterpropagating laser beams when |Δk rb |much-gt 1, where b is the confocal parameter of the focused laser beams. Strong absorption of the four-wave-mixing field is shown not to be necessary for strong destructive interference with focused laser beams when the phase mismatch is large. This work also suggests an explanation for earlier experiments where the presence of a four-photon resonance enabled the generation of third-harmonic light in a positively dispersive wavelength region. We argue that this process can occur when the laser used to achieve the four-photon resonance is focused on the small z (z is the coordinate in the direction of propagation) side of the focal point of the laser responsible for the third-harmonic generation

Phonon-Assisted Two-Photon Interference from Remote Quantum Emitters.

Science.gov (United States)

Reindl, Marcus; Jöns, Klaus D; Huber, Daniel; Schimpf, Christian; Huo, Yongheng; Zwiller, Val; Rastelli, Armando; Trotta, Rinaldo

2017-07-12

Photonic quantum technologies are on the verge of finding applications in everyday life with quantum cryptography and quantum simulators on the horizon. Extensive research has been carried out to identify suitable quantum emitters and single epitaxial quantum dots have emerged as near-optimal sources of bright, on-demand, highly indistinguishable single photons and entangled photon-pairs. In order to build up quantum networks, it is essential to interface remote quantum emitters. However, this is still an outstanding challenge, as the quantum states of dissimilar "artificial atoms" have to be prepared on-demand with high fidelity and the generated photons have to be made indistinguishable in all possible degrees of freedom. Here, we overcome this major obstacle and show an unprecedented two-photon interference (visibility of 51 ± 5%) from remote strain-tunable GaAs quantum dots emitting on-demand photon-pairs. We achieve this result by exploiting for the first time the full potential of a novel phonon-assisted two-photon excitation scheme, which allows for the generation of highly indistinguishable (visibility of 71 ± 9%) entangled photon-pairs (fidelity of 90 ± 2%), enables push-button biexciton state preparation (fidelity of 80 ± 2%) and outperforms conventional resonant two-photon excitation schemes in terms of robustness against environmental decoherence. Our results mark an important milestone for the practical realization of quantum repeaters and complex multiphoton entanglement experiments involving dissimilar artificial atoms.

Thermalization of a two-dimensional photonic gas in a `white wall' photon box

Science.gov (United States)

Klaers, Jan; Vewinger, Frank; Weitz, Martin

2010-07-01

Bose-Einstein condensation, the macroscopic accumulation of bosonic particles in the energetic ground state below a critical temperature, has been demonstrated in several physical systems. The perhaps best known example of a bosonic gas, blackbody radiation, however exhibits no Bose-Einstein condensation at low temperatures. Instead of collectively occupying the lowest energy mode, the photons disappear in the cavity walls when the temperature is lowered-corresponding to a vanishing chemical potential. Here we report on evidence for a thermalized two-dimensional photon gas with a freely adjustable chemical potential. Our experiment is based on a dye-filled optical microresonator, acting as a `white wall' box for photons. Thermalization is achieved in a photon-number-conserving way by photon scattering off the dye molecules, and the cavity mirrors provide both an effective photon mass and a confining potential-key prerequisites for the Bose-Einstein condensation of photons. As a striking example of the unusual system properties, we demonstrate a yet unobserved light concentration effect into the centre of the confining potential, an effect with prospects for increasing the efficiency of diffuse solar light collection.

Photonic Structure-Integrated Two-Dimensional Material Optoelectronics

Directory of Open Access Journals (Sweden)

Tianjiao Wang

2016-12-01

Full Text Available The rapid development and unique properties of two-dimensional (2D materials, such as graphene, phosphorene and transition metal dichalcogenides enable them to become intriguing candidates for future optoelectronic applications. To maximize the potential of 2D material-based optoelectronics, various photonic structures are integrated to form photonic structure/2D material hybrid systems so that the device performance can be manipulated in controllable ways. Here, we first introduce the photocurrent-generation mechanisms of 2D material-based optoelectronics and their performance. We then offer an overview and evaluation of the state-of-the-art of hybrid systems, where 2D material optoelectronics are integrated with photonic structures, especially plasmonic nanostructures, photonic waveguides and crystals. By combining with those photonic structures, the performance of 2D material optoelectronics can be further enhanced, and on the other side, a high-performance modulator can be achieved by electrostatically tuning 2D materials. Finally, 2D material-based photodetector can also become an efficient probe to learn the light-matter interactions of photonic structures. Those hybrid systems combine the advantages of 2D materials and photonic structures, providing further capacity for high-performance optoelectronics.

Emulation of two-dimensional photonic crystal defect modes in a photonic crystal with a three-dimensional photonic band gap

Energy Technology Data Exchange (ETDEWEB)

Povinelli, M. L.; Johnson, Steven G.; Fan, Shanhui; Joannopoulos, J. D.

2001-08-15

Using numerical simulations, we demonstrate the construction of two-dimensional- (2D-) like defect modes in a recently proposed 3D photonic crystal structure. These modes, which are confined in all three dimensions by a complete photonic band gap, bear a striking similarity to those in 2D photonic crystals in terms of polarization, field profile, and projected band structures. It is expected that these results will greatly facilitate the observation of widely studied 2D photonic-crystal phenomena in a realistic, 3D physical system.

Emulation of two-dimensional photonic crystal defect modes in a photonic crystal with a three-dimensional photonic band gap

International Nuclear Information System (INIS)

Povinelli, M. L.; Johnson, Steven G.; Fan, Shanhui; Joannopoulos, J. D.

2001-01-01

Using numerical simulations, we demonstrate the construction of two-dimensional- (2D-) like defect modes in a recently proposed 3D photonic crystal structure. These modes, which are confined in all three dimensions by a complete photonic band gap, bear a striking similarity to those in 2D photonic crystals in terms of polarization, field profile, and projected band structures. It is expected that these results will greatly facilitate the observation of widely studied 2D photonic-crystal phenomena in a realistic, 3D physical system

Designing of Metallic Photonic Structures and Applications

International Nuclear Information System (INIS)

Yong-Sung Kim

2006-01-01

In this thesis our main interest has been to investigate metallic photonic crystal and its applications. We explained how to solve a periodic photonic structure with transfer matrix method and when and how to use modal expansion method. Two different coating methods were introduced, modifying a photonic structure's intrinsic optical properties and rigorous calculation results are presented. Two applications of metallic photonic structures are introduced. For thermal emitter, we showed how to design and find optimal structure. For conversion efficiency increasing filter, we calculated its efficiency and the way to design it. We presented the relation between emitting light spectrum and absorption and showed the material and structural dependency of the absorption spectrum. By choosing a proper base material and structural parameters, we can design a selective emitter at a certain region we are interested in. We have developed a theoretical model to analyze a blackbody filament enclosed by a metallic mesh which can increase the efficiency of converting a blackbody radiation to visible light. With this model we found that a square lattice metallic mesh enclosing a filament might increase the efficiency of incandescent lighting sources. Filling fraction and thickness dependency were examined and presented. Combining these two parameters is essential to achieve the maximum output result

Transient behaviour of EIT and EIA in an optical-radio two-photon coupling configuration

Science.gov (United States)

Li, Xiaoli; Yang, Zicai; Shang, Yaxuan

2012-11-01

Both electromagnetically induced absorption (EIA) and transparency (EIT) can be obtained in a modified quasi-lambda four level system consisting of an optical-radio two-photon coupling field and a probing field. A physical account of EIA and EIT is given in terms of a transient state picture in this paper. It can be seen that the optical coupling field in this quasi-lambda four level system has a crucial effect on the forming of EIA and EIT. An EIA is observed under a resonant optical coupling and it evolves into an EIT when there is a detuning.

Thermal and dynamic range characterization of a photonics-based RF amplifier

Science.gov (United States)

Noque, D. F.; Borges, R. M.; Muniz, A. L. M.; Bogoni, A.; Cerqueira S., Arismar, Jr.

2018-05-01

This work reports a thermal and dynamic range characterization of an ultra-wideband photonics-based RF amplifier for microwave and mm-waves future 5G optical-wireless networks. The proposed technology applies the four-wave mixing nonlinear effect to provide RF amplification in analog and digital radio-over-fiber systems. The experimental analysis from 300 kHz to 50 GHz takes into account different figures of merit, such as RF gain, spurious-free dynamic range and RF output power stability as a function of temperature. The thermal characterization from -10 to +70 °C demonstrates a 27 dB flat photonics-assisted RF gain over the entire frequency range under real operational conditions of a base station for illustrating the feasibility of the photonics-assisted RF amplifier for 5G networks.

Effect of quantum interference on the optical properties of a three-level V-type atomic system beyond the two-photon resonance condition

Energy Technology Data Exchange (ETDEWEB)

Mousavi, S M; Safari, L; Mahmoudi, M [Physics Department, Zanjan University, PO Box 45195-313, Zanjan (Iran, Islamic Republic of); Sahrai, M, E-mail: sahrai@tabrizu.ac.i [Research Institute for Applied Physics and Astronomy, University of Tabriz, Tabriz (Iran, Islamic Republic of)

2010-08-28

The effect of quantum interference on the optical properties of a pumped-probe three-level V-type atomic system is investigated. The probe absorption, dispersion, group index and optical bistability beyond the two-photon resonance condition are discussed. It is found that the optical properties of a medium in the frequency of the probe field, in general, are phase independent. The phase dependence arises from a scattering of the coupling field into the probe field at a frequency which in general differs from the probe field frequency. It is demonstrated that beyond the two-photon resonance condition the phase sensitivity of the medium will disappear.

Optical absorption in a thin nickel wire

International Nuclear Information System (INIS)

Inagaki, T.; Goudonnet, J.P.; Arakawa, E.T.

1986-01-01

Absorption of a 633-nm photon in a cylindrical nickel wire with diameter 13 μm was measured by a photoacoustic method as a function of angle of photon incidence theta. A good photoacoustic signal was obtained with a 6-mW He-Ne laser as a light source without employing focusing optics. The absorption measured for p-polarized photons was found to be in good agreement with geometrical optics calculation. For s-polarized light, however, significant excess absorption was found for theta > 35 0

Two-photon Anderson localization in a disordered quadratic waveguide array

International Nuclear Information System (INIS)

Bai, Y F; Xu, P; Lu, L L; Zhong, M L; Zhu, S N

2016-01-01

We theoretically investigate two-photon Anderson localization in a χ (2) waveguide array with off-diagonal disorder. The nonlinear parametric down-conversion process would enhance both the single-photon and the two-photon Anderson localization. In the strong disorder regime, the two-photon position correlation exhibits a bunching distribution around the pumped waveguides, which is independent of pumping conditions and geometrical structures of waveguide arrays. Quadratic nonlinearity can be supplied as a new ingredient for Anderson localization. Also, our results pave the way for engineering quantum states through nonlinear quantum walks. (paper)

Measurement of the electronic absorption coefficient for 57Co 14.4 keV gamma photons in aluminium using the Moessbauer effect as a monochromator

International Nuclear Information System (INIS)

Rajan, N.; Nigam, A.K.

1984-01-01

The total electronic absorption coefficient for 14.4 keV gamma photons in aluminium, has been measured experimentally, for the first time, using the Moessbauer effect as a monochromator. This data is important for the determination of background in Moessbauer recoilless fraction measurements especially if the energy of X-rays of the source host lattice lie near the 14.4 keV photon energy (e.g. in Rh and Pd) in which case electronic absorption coefficients should be known precisely. The coefficient obtained by interpolation from available values at other energies differ from our experimental value by as much as 20%. It is shown that this can lead to errors, in recoilless fraction values, which are far from negligible. The above absorption coefficient for aluminium was measured to be 11+-1 cm 2 /g. (orig.)

Interim report on modeling studies of two-photon isotope separation

International Nuclear Information System (INIS)

Hwang, W.C.; Badcock, C.C.; Kamada, R.F.

1975-01-01

The two-photon or two-step dissociation method of laser induced isotope enrichment is being modeled for the HBrNO photochemical system. In the model, H 79 Br is selectively excited by resonance IR laser radiation and then dissociated by uv radiation. Selectively dissociated Br atoms are scavenged to form isotopically enriched BrNO and Br 2 . This model includes all kinetic and absorption processes found to be significant and the time-varying concentrations of any species involved in a significant process. Among these processes are vibrational energy transfer reactions (including isotopic exchange) involving HBr v = 0 - 3, rotational and translational (velocity) relaxation processes, dissociation of HBr in the v = 0 - 3 levels, and secondary chemical reactions of the dissociation products. The absorption and kinetic processes that are most important to 79 Br enrichment have been identified and the study of the effects on enrichment upon variation of external parameters (such as reactant pressure, ir or uv source intensity, and temperature) is in progress. Some preliminary results are: (1) intensity of the ir source is usually more important than the uv intensity; (2) chemical reactions are the dominant kinetic processes at lower pressures while energy transfer reactions dominate at higher pressures; (3) kinetic processes usually have greater effect on the absolute amount of enriched products; (4) isotopic abundance of 79 Br in the products can range from 0.55 to 0.80 for the conditions used in the model

Two-photon excited fluorescence emission from hemoglobin

Science.gov (United States)

Sun, Qiqi; Zeng, Yan; Zhang, Wei; Zheng, Wei; Luo, Yi; Qu, Jianan Y.

2015-03-01

Hemoglobin, one of the most important proteins in blood, is responsible for oxygen transportation in almost all vertebrates. Recently, we discovered two-photon excited hemoglobin fluorescence and achieved label-free microvascular imaging based on the hemoglobin fluorescence. However, the mechanism of its fluorescence emission still remains unknown. In this work, we studied the two-photon excited fluorescence properties of the hemoglobin subunits, heme/hemin (iron (II)/(III) protoporphyrin IX) and globin. We first studied the properties of heme and the similar spectral and temporal characteristics of heme and hemoglobin fluorescence provide strong evidence that heme is the fluorophore in hemoglobin. Then we studied the fluorescence properties of hemin, globin and methemoglobin, and found that the hemin may have the main effect on the methemoglobin fluorescence and that globin has tryptophan fluorescence like other proteins. Finally, since heme is a centrosymmetric molecule, that the Soret band fluorescence of heme and hemoglobin was not observed in the single photon process in the previous study may be due to the parity selection rule. The discovery of heme two-photon excited fluorescence may open a new window for heme biology research, since heme as a cofactor of hemoprotein has many functions, including chemical catalysis, electron transfer and diatomic gases transportation.

Broadband high-resolution two-photon spectroscopy with laser frequency combs

OpenAIRE

Hipke, Arthur; Meek, Samuel A.; Ideguchi, Takuro; Hänsch, Theodor W.; Picqué, Nathalie

2013-01-01

Two-photon excitation spectroscopy with broad spectral span is demonstrated at Doppler-limited resolution. We describe first Fourier transform two-photon spectroscopy of an atomic sample with two mode-locked laser oscillators in a dual-comb technique. Each transition is uniquely identified by the modulation imparted by the interfering comb excitations. The temporal modulation of the spontaneous two-photon fluorescence is monitored with a single photodetector, and the spectrum is revealed by a...

How a single photon can mediate entanglement between two others

Energy Technology Data Exchange (ETDEWEB)

Lima Bernardo, Bertúlio de, E-mail: bertulio.fisica@gmail.com

2016-10-15

We describe a novel quantum information protocol, which probabilistically entangles two distant photons that have never interacted. Different from the entanglement swapping protocol, which requires two pairs of maximally entangled photons as the input states, as well as a Bell-state measurement (BSM), the present scheme only requires three photons: two to be entangled and another to mediate the correlation, and no BSM, in a process that we call “entanglement mediation”. Furthermore, in analyzing the paths of the photons in our arrangement, we conclude that one of them, the mediator, exchanges information with the two others simultaneously, which seems to be a new quantum-mechanical feature.

Characterization of photon-counting multislit breast tomosynthesis.

Science.gov (United States)

Berggren, Karl; Cederström, Björn; Lundqvist, Mats; Fredenberg, Erik

2018-02-01

It has been shown that breast tomosynthesis may improve sensitivity and specificity compared to two-dimensional mammography, resulting in increased detection-rate of cancers or lowered call-back rates. The purpose of this study is to characterize a spectral photon-counting multislit breast tomosynthesis system that is able to do single-scan spectral imaging with multiple collimated x-ray beams. The system differs in many aspects compared to conventional tomosynthesis using energy-integrating flat-panel detectors. The investigated system was a prototype consisting of a dual-threshold photon-counting detector with 21 collimated line detectors scanning across the compressed breast. A review of the system is done in terms of detector, acquisition geometry, and reconstruction methods. Three reconstruction methods were used, simple back-projection, filtered back-projection and an iterative algebraic reconstruction technique. The image quality was evaluated by measuring the modulation transfer-function (MTF), normalized noise-power spectrum, detective quantum-efficiency (DQE), and artifact spread-function (ASF) on reconstructed spectral tomosynthesis images for a total-energy bin (defined by a low-energy threshold calibrated to remove electronic noise) and for a high-energy bin (with a threshold calibrated to split the spectrum in roughly equal parts). Acquisition was performed using a 29 kVp W/Al x-ray spectrum at a 0.24 mGy exposure. The difference in MTF between the two energy bins was negligible, that is, there was no energy dependence on resolution. The MTF dropped to 50% at 1.5 lp/mm to 2.3 lp/mm in the scan direction and 2.4 lp/mm to 3.3 lp/mm in the slit direction, depending on the reconstruction method. The full width at half maximum of the ASF was found to range from 13.8 mm to 18.0 mm for the different reconstruction methods. The zero-frequency DQE of the system was found to be 0.72. The fraction of counts in the high-energy bin was measured to be 59% of the

Microscopic theory of cavity-enhanced single-photon emission from optical two-photon Raman processes

Science.gov (United States)

Breddermann, Dominik; Praschan, Tom; Heinze, Dirk; Binder, Rolf; Schumacher, Stefan

2018-03-01

We consider cavity-enhanced single-photon generation from stimulated two-photon Raman processes in three-level systems. We compare four fundamental system configurations, one Λ -, one V-, and two ladder (Ξ -) configurations. These can be realized as subsystems of a single quantum dot or of quantum-dot molecules. For a new microscopic understanding of the Raman process, we analyze the Heisenberg equation of motion applying the cluster-expansion scheme. Within this formalism an exact and rigorous definition of a cavity-enhanced Raman photon via its corresponding Raman correlation is possible. This definition for example enables us to systematically investigate the on-demand potential of Raman-transition-based single-photon sources. The four system arrangements can be divided into two subclasses, Λ -type and V-type, which exhibit strongly different Raman-emission characteristics and Raman-emission probabilities. Moreover, our approach reveals whether the Raman path generates a single photon or just induces destructive quantum interference with other excitation paths. Based on our findings and as a first application, we gain a more detailed understanding of experimental data from the literature. Our analysis and results are also transferable to the case of atomic three-level-resonator systems and can be extended to more complicated multilevel schemes.

Characterization of Sphinx1 ASIC X-ray detector using photon counting and charge integration

Science.gov (United States)

Habib, A.; Arques, M.; Moro, J.-L.; Accensi, M.; Stanchina, S.; Dupont, B.; Rohr, P.; Sicard, G.; Tchagaspanian, M.; Verger, L.

2018-01-01

Sphinx1 is a novel pixel architecture adapted for X-ray imaging, it detects radiation by photon counting and charge integration. In photon counting mode, each photon is compensated by one or more counter-charges typically consisting of 100 electrons (e-) each. The number of counter-charges required gives a measure of the incoming photon energy, thus allowing spectrometric detection. Pixels can also detect radiation by integrating the charges deposited by all incoming photons during one image frame and converting this analog value into a digital response with a 100 electrons least significant bit (LSB), based on the counter-charge concept. A proof of concept test chip measuring 5 mm × 5 mm, with 200 μm × 200 μm pixels has been produced and characterized. This paper provides details on the architecture and the counter-charge design; it also describes the two modes of operation: photon counting and charge integration. The first performance measurements for this test chip are presented. Noise was found to be ~80 e-rms in photon counting mode with a power consumption of only 0.9 μW/pixel for the static analog part and 0.3 μW/pixel for the static digital part.

Two-photon imaging and analysis of neural network dynamics

International Nuclear Information System (INIS)

Luetcke, Henry; Helmchen, Fritjof

2011-01-01

The glow of a starry night sky, the smell of a freshly brewed cup of coffee or the sound of ocean waves breaking on the beach are representations of the physical world that have been created by the dynamic interactions of thousands of neurons in our brains. How the brain mediates perceptions, creates thoughts, stores memories and initiates actions remains one of the most profound puzzles in biology, if not all of science. A key to a mechanistic understanding of how the nervous system works is the ability to measure and analyze the dynamics of neuronal networks in the living organism in the context of sensory stimulation and behavior. Dynamic brain properties have been fairly well characterized on the microscopic level of individual neurons and on the macroscopic level of whole brain areas largely with the help of various electrophysiological techniques. However, our understanding of the mesoscopic level comprising local populations of hundreds to thousands of neurons (so-called 'microcircuits') remains comparably poor. Predominantly, this has been due to the technical difficulties involved in recording from large networks of neurons with single-cell spatial resolution and near-millisecond temporal resolution in the brain of living animals. In recent years, two-photon microscopy has emerged as a technique which meets many of these requirements and thus has become the method of choice for the interrogation of local neural circuits. Here, we review the state-of-research in the field of two-photon imaging of neuronal populations, covering the topics of microscope technology, suitable fluorescent indicator dyes, staining techniques, and in particular analysis techniques for extracting relevant information from the fluorescence data. We expect that functional analysis of neural networks using two-photon imaging will help to decipher fundamental operational principles of neural microcircuits.

Two-photon imaging and analysis of neural network dynamics

Science.gov (United States)

Lütcke, Henry; Helmchen, Fritjof

2011-08-01

The glow of a starry night sky, the smell of a freshly brewed cup of coffee or the sound of ocean waves breaking on the beach are representations of the physical world that have been created by the dynamic interactions of thousands of neurons in our brains. How the brain mediates perceptions, creates thoughts, stores memories and initiates actions remains one of the most profound puzzles in biology, if not all of science. A key to a mechanistic understanding of how the nervous system works is the ability to measure and analyze the dynamics of neuronal networks in the living organism in the context of sensory stimulation and behavior. Dynamic brain properties have been fairly well characterized on the microscopic level of individual neurons and on the macroscopic level of whole brain areas largely with the help of various electrophysiological techniques. However, our understanding of the mesoscopic level comprising local populations of hundreds to thousands of neurons (so-called 'microcircuits') remains comparably poor. Predominantly, this has been due to the technical difficulties involved in recording from large networks of neurons with single-cell spatial resolution and near-millisecond temporal resolution in the brain of living animals. In recent years, two-photon microscopy has emerged as a technique which meets many of these requirements and thus has become the method of choice for the interrogation of local neural circuits. Here, we review the state-of-research in the field of two-photon imaging of neuronal populations, covering the topics of microscope technology, suitable fluorescent indicator dyes, staining techniques, and in particular analysis techniques for extracting relevant information from the fluorescence data. We expect that functional analysis of neural networks using two-photon imaging will help to decipher fundamental operational principles of neural microcircuits.

Two-photon imaging and analysis of neural network dynamics

Energy Technology Data Exchange (ETDEWEB)

Luetcke, Henry; Helmchen, Fritjof [Brain Research Institute, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich (Switzerland)

2011-08-15

The glow of a starry night sky, the smell of a freshly brewed cup of coffee or the sound of ocean waves breaking on the beach are representations of the physical world that have been created by the dynamic interactions of thousands of neurons in our brains. How the brain mediates perceptions, creates thoughts, stores memories and initiates actions remains one of the most profound puzzles in biology, if not all of science. A key to a mechanistic understanding of how the nervous system works is the ability to measure and analyze the dynamics of neuronal networks in the living organism in the context of sensory stimulation and behavior. Dynamic brain properties have been fairly well characterized on the microscopic level of individual neurons and on the macroscopic level of whole brain areas largely with the help of various electrophysiological techniques. However, our understanding of the mesoscopic level comprising local populations of hundreds to thousands of neurons (so-called 'microcircuits') remains comparably poor. Predominantly, this has been due to the technical difficulties involved in recording from large networks of neurons with single-cell spatial resolution and near-millisecond temporal resolution in the brain of living animals. In recent years, two-photon microscopy has emerged as a technique which meets many of these requirements and thus has become the method of choice for the interrogation of local neural circuits. Here, we review the state-of-research in the field of two-photon imaging of neuronal populations, covering the topics of microscope technology, suitable fluorescent indicator dyes, staining techniques, and in particular analysis techniques for extracting relevant information from the fluorescence data. We expect that functional analysis of neural networks using two-photon imaging will help to decipher fundamental operational principles of neural microcircuits.

Nucleon Compton Scattering with Two Space-Like Photons

International Nuclear Information System (INIS)

Andrei Afanasev; I. Akushevich; N.P. Merenkov

2002-01-01

We calculate two-photon exchange effects for elastic electron-proton scattering at high momentum transfers. The corresponding nucleon Compton amplitude is defined by two space-like virtual photons that appear to have significant virtualities. We make predictions for (a) a single-spin beam asymmetry, and (b) a single-spin target asymmetry or recoil proton polarization caused by an unpolarized electron beam

Resonant production in two photon collisions

International Nuclear Information System (INIS)

Butler, F.

1988-12-01

Using 220 picobarn/sup /minus/1/ of data collected by the Mark II detector at PEP, we have measured the width of the /eta/' for quasi real photons. The width is separately measured in the three reactions e + e/sup /minus// → e + e/sup /minus///eta/ 0 π + π/sup /minus//; /eta/ 0 → γγ, e + e/sup /minus// → e + e/sup /minus///eta/ 0 π + π/sup /minus//; /eta/ 0 → π + π/sup /minus//(π 0 ,γ) and e + e/sup /minus// → e + e/sup /minus///rho/ 0 γ, giving a statistically weighted average two-photon width of Γ/sub /eta/'→γγ/ = 5. 21+-0.28 keV. As a by-product of the measurement of Γ/sub /eta/'→γγ/ using the decay mode /eta/' → /rho/γ, we also measured a two-photon decay width for the a 2 (1320) of Γ/sub a 2(1320)→γγ/ = 1.17+-0. 15+-0.25 keV. 47 refs., 50 figs., 8 tabs

Folate receptor targeting silica nanoparticle probe for two-photon fluorescence bioimaging

Science.gov (United States)

Wang, Xuhua; Yao, Sheng; Ahn, Hyo-Yang; Zhang, Yuanwei; Bondar, Mykhailo V.; Torres, Joseph A.; Belfield, Kevin D.

2010-01-01

Narrow dispersity organically modified silica nanoparticles (SiNPs), diameter ~30 nm, entrapping a hydrophobic two-photon absorbing fluorenyl dye, were synthesized by hydrolysis of triethoxyvinylsilane and (3-aminopropyl)triethoxysilane in the nonpolar core of Aerosol-OT micelles. The surface of the SiNPs were functionalized with folic acid, to specifically deliver the probe to folate receptor (FR) over-expressing Hela cells, making these folate two-photon dye-doped SiNPs potential candidates as probes for two-photon fluorescence microscopy (2PFM) bioimaging. In vitro studies using FR over-expressing Hela cells and low FR expressing MG63 cells demonstrated specific cellular uptake of the functionalized nanoparticles. One-photon fluorescence microscopy (1PFM) imaging, 2PFM imaging, and two-photon fluorescence lifetime microscopy (2P-FLIM) imaging of Hela cells incubated with folate-modified two-photon dye-doped SiNPs were demonstrated. PMID:21258480

Effect of the coherent cancellation of the two-photon resonance on the generation of vacuum ultraviolet light by two-photon reasonantly enhanced four-wave mixing

International Nuclear Information System (INIS)

Payne, M.G.; Garrett, W.R.; Judish, J.P.; Wunderlich, R.

1988-11-01

Many of the most impressive demonstrations of the efficient generation of vacuum ultraviolet (VUV) light have made use of two- photon resonantly enhanced four-wave mixing to generate light at ω/sub VUV/ = 2ω/sub L1/ +- ω/sub L2/. The two-photon resonance state is coupled to the ground state both by two photons from the first laser, or by a photon from the second laser and one from the generated VUV beam. We show here that these two coherent pathways destructively interfere once the second laser is made sufficiently intense, thereby leading to an important limiting effect on the achievable conversion efficiency. 4 refs

Manipulation of photons at the surface of three-dimensional photonic crystals.

Science.gov (United States)

Ishizaki, Kenji; Noda, Susumu

2009-07-16

In three-dimensional (3D) photonic crystals, refractive-index variations with a periodicity comparable to the wavelength of the light passing through the crystal give rise to so-called photonic bandgaps, which are analogous to electronic bandgaps for electrons moving in the periodic electrostatic potential of a material's crystal structure. Such 3D photonic bandgap crystals are envisioned to become fundamental building blocks for the control and manipulation of photons in optical circuits. So far, such schemes have been pursued by embedding artificial defects and light emitters inside the crystals, making use of 3D bandgap directional effects. Here we show experimentally that photons can be controlled and manipulated even at the 'surface' of 3D photonic crystals, where 3D periodicity is terminated, establishing a new and versatile route for photon manipulation. By making use of an evanescent-mode coupling technique, we demonstrate that 3D photonic crystals possess two-dimensional surface states, and we map their band structure. We show that photons can be confined and propagate through these two-dimensional surface states, and we realize their localization at arbitrary surface points by designing artificial surface-defect structures through the formation of a surface-mode gap. Surprisingly, the quality factors of the surface-defect mode are the largest reported for 3D photonic crystal nanocavities (Q up to approximately 9,000). In addition to providing a new approach for photon manipulation by photonic crystals, our findings are relevant for the generation and control of plasmon-polaritons in metals and the related surface photon physics. The absorption-free nature of the 3D photonic crystal surface may enable new sensing applications and provide routes for the realization of efficient light-matter interactions.

Two-photon couplings of quarkonia with arbitrary JPC

International Nuclear Information System (INIS)

Barnes, T.; Tennessee Univ., Knoxville, TN

1992-01-01

We present theoretical results for the two-photon widths of relativistic quarkonium states with arbitrary angular momenta. These relativistic formulas are required to obtain reasonable agreement with the absolute scale of quarkonium decay rates to two photons, and have previously only been derived for spin-singlet q bar q states. We also evaluate these formulas numerically for ell ≤3 q = u, d states in a Coulomb-plus-linear q bar q potential model. Light-quark higher-ell and radially-excited q bar q states should be observable experimentally, as their two-photon widths are typically found to be ∼1 KeV. The radially-excited 1 S 0 higher-mass quarkonium states such as c bar c and b bar b should also be observable in γγ, but orbitally-excited c bar c states with ell>1 and b bar b states with ell>0 are expected to have very small two-photon widths. The helicity structure of the higher-ell q bar q couplings is predicted to be nontrivial, with both λ=0 and λ=2γγ final states contributing significantly; these results may be useful as signatures for q bar q states

Numerical study on characteristic of two-dimensional metal/dielectric photonic crystals

International Nuclear Information System (INIS)

Zong Yi-Xin; Xia Jian-Bai; Wu Hai-Bin

2017-01-01

An improved plan-wave expansion method is adopted to theoretically study the photonic band diagrams of two-dimensional (2D) metal/dielectric photonic crystals. Based on the photonic band structures, the dependence of flat bands and photonic bandgaps on two parameters (dielectric constant and filling factor) are investigated for two types of 2D metal/dielectric (M/D) photonic crystals, hole and cylinder photonic crystals. The simulation results show that band structures are affected greatly by these two parameters. Flat bands and bandgaps can be easily obtained by tuning these parameters and the bandgap width may reach to the maximum at certain parameters. It is worth noting that the hole-type photonic crystals show more bandgaps than the corresponding cylinder ones, and the frequency ranges of bandgaps also depend strongly on these parameters. Besides, the photonic crystals containing metallic medium can obtain more modulation of photonic bands, band gaps, and large effective refractive index, etc. than the dielectric/dielectric ones. According to the numerical results, the needs of optical devices for flat bands and bandgaps can be met by selecting the suitable geometry and material parameters. (paper)

Redox Chemisty of Tantalum Clusters on Silica Characterized by X-ray Absorption Spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Nemana,S.; Gates, B.

2006-01-01

SiO{sub 2}-supported clusters of tantalum were synthesized from adsorbed Ta(CH{sub 2}Ph){sub 5} by treatment in H{sub 2} at 523 K. The surface species were characterized by X-ray absorption spectroscopy (extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray absorption near edge spectroscopy (XANES)) and ultraviolet-visible spectroscopy. The EXAFS data show that SiOO{sub 2}-supported tantalum clusters were characterized by a Ta-Ta coordination number of approximately 2, consistent with the presence of tritantalum clusters, on average. When these were reduced in H{sub 2} and reoxidized in O{sub 2}, the cluster nuclearity remained essentially unchanged, although reduction and oxidation occurred, respectively, as shown by XANES and UV-vis spectra; in the reoxidation, the tantalum oxidation state change was approximately two electronic charges per tritantalum cluster. The data demonstrate an analogy between the chemistry of group 5 metals on the SiO{sub 2} support and their chemistry in solution, as determined by the group of Cotton.

Experimental two-dimensional quantum walk on a photonic chip.

Science.gov (United States)

Tang, Hao; Lin, Xiao-Feng; Feng, Zhen; Chen, Jing-Yuan; Gao, Jun; Sun, Ke; Wang, Chao-Yue; Lai, Peng-Cheng; Xu, Xiao-Yun; Wang, Yao; Qiao, Lu-Feng; Yang, Ai-Lin; Jin, Xian-Min

2018-05-01

Quantum walks, in virtue of the coherent superposition and quantum interference, have exponential superiority over their classical counterpart in applications of quantum searching and quantum simulation. The quantum-enhanced power is highly related to the state space of quantum walks, which can be expanded by enlarging the photon number and/or the dimensions of the evolution network, but the former is considerably challenging due to probabilistic generation of single photons and multiplicative loss. We demonstrate a two-dimensional continuous-time quantum walk by using the external geometry of photonic waveguide arrays, rather than the inner degree of freedoms of photons. Using femtosecond laser direct writing, we construct a large-scale three-dimensional structure that forms a two-dimensional lattice with up to 49 × 49 nodes on a photonic chip. We demonstrate spatial two-dimensional quantum walks using heralded single photons and single photon-level imaging. We analyze the quantum transport properties via observing the ballistic evolution pattern and the variance profile, which agree well with simulation results. We further reveal the transient nature that is the unique feature for quantum walks of beyond one dimension. An architecture that allows a quantum walk to freely evolve in all directions and at a large scale, combining with defect and disorder control, may bring up powerful and versatile quantum walk machines for classically intractable problems.

Characterization of Rayleigh backscattering arising in various two-mode fibers

NARCIS (Netherlands)

Yu, Dawei; Fu, Songnian; Cao, Zizheng; Tang, Ming; Deng, Lei; Liu, Deming; Giles, I.; Koonen, T.; Okonkwo, C.

2016-01-01

We experimentally characterize the mode dependent characteristics of Rayleigh backscattering (RB) arising in various two-mode fibers (TMFs). With the help of an all-fiber photonic lantern, we are able to measure the RB power at individual modes. Consequently, mode dependent power distribution of RB

Low loss GaN waveguides at the visible spectral wavelengths for integrated photonics applications.

Science.gov (United States)

Chen, Hong; Fu, Houqiang; Huang, Xuanqi; Zhang, Xiaodong; Yang, Tsung-Han; Montes, Jossue A; Baranowski, Izak; Zhao, Yuji

2017-12-11

We perform comprehensive studies on the fundamental loss mechanisms in III-nitride waveguides in the visible spectral region. Theoretical analysis shows that free carrier loss dominates for GaN under low photon power injection. When optical power increases, the two photon absorption loss becomes important and eventually dominates when photon energy above half-bandgap of GaN. When the dimensions of the waveguides reduce, the sidewall scattering loss will start to dominate. To verify the theoretical results, a high performance GaN-on-sapphire waveguide was fabricated and characterized. Experimental results are consistent with the theoretical findings, showing that under high power injection the optical loss changed significantly for GaN waveguides. A low optical loss ~2 dB/cm was achieved on the GaN waveguide, which is the lowest value ever reported for the visible spectral range. The results and fabrication processes developed in this work pave the way for the development of III-nitride integrated photonics in the visible and potentially ultraviolet spectral range for nonlinear optics and quantum photonics applications.

Photonic characterization of capacitance-voltage characteristics in MOS capacitors and current-voltage characteristics in MOSFETs

International Nuclear Information System (INIS)

Kim, H. C.; Kim, H. T.; Cho, S. D.; Song, S. J.; Kim, Y. C.; Kim, S. K.; Chi, S. S.; Kim, D. J.; Kim, D. M.

2002-01-01

Based on the photonic high-frequency capacitance-voltage (HF-CV) response of MOS capacitors, a new characterization method is reported for the analysis of interface states in MOS systems. An optical source with a photonic energy less than the silicon band-gap energy (hv g ) is employed for the photonic HF-CV characterization of interface states distributed in the photoresponsive energy band (E C - hv t C ). If a uniform distribution of trap levels is assumed, the density of interface states (D it ) in the photoresponsive energy band of MOS capacitors, characterized by the new photonic HF-CV method, was observed to be D it = 1 ∼ 5 x 10 11 eV -1 cm -2 . Photonic current-voltage characteristics (I D - V GS , V DS ) of MOSFETs, which are under control of the photoconductive and the photovoltaic effects, are also investigated under optical illumination

Dielectric-loaded surface plasmon-polariton nanowaveguides fabricated by two-photon polymerization

Energy Technology Data Exchange (ETDEWEB)

Luo, Hao; Li, Yan; Cui, Hai-Bo; Yang, Hong; Gong, Qi-Huang [Peking University, State Key Laboratory for Mesoscopic Physics and Department of Physics, Beijing (China)

2009-11-15

The design, fabrication, and characterization of dielectric-loaded surface plasmon-polariton nanowave-guides on a gold film are presented. The nanostructures are produced by two-photon polymerization with femtosecond laser pulses, and the minimum ridge height is {proportional_to}170 nm. Leakage radiation microscopy shows that these surface plasmon-polariton waveguides are single mode with strong mode confinement at the wavelength of 830 nm. The experimental results are in good agreement with the simulation by the effective-index method. (orig.)

Scanless two-photon excitation of channelrhodopsin-2

DEFF Research Database (Denmark)

Papagiakoumou, E.; Anselmi, F.; Bègue, A.

2010-01-01

developed a method that combines generalized phase contrast with temporal focusing (TF-GPC) to shape two-photon excitation for this purpose. The illumination patterns are generated automatically from fluorescence images of neurons and shaped to cover the cell body or dendrites, or distributed groups...... of cells. The TF-GPC two-photon excitation patterns generated large photocurrents in Channelrhodopsin-2–expressing cultured cells and neurons and in mouse acute cortical slices. The amplitudes of the photocurrents can be precisely modulated by controlling the size and shape of the excitation volume and...

Compositional dependence of absorption coefficient and band-gap for Nb2O5-SiO2 mixture thin films

International Nuclear Information System (INIS)

Sancho-Parramon, Jordi; Janicki, Vesna; Zorc, Hrvoje

2008-01-01

The absorption coefficient of composite films consisting of niobia (Nb 2 O 5 ) and silica (SiO 2 ) mixtures is studied for photon energies around the band gap. The films were deposited by co-evaporation and their composition was varied by changing the ratio of deposition rates of the two materials. Both, as-deposited and thermally annealed films were characterized by different techniques: the absorption coefficient was determined by spectrophotometric measurements and the structural properties were investigated using infrared spectroscopy, transmission electron microscopy and X-ray diffraction. The correlation between the variations of absorption properties and film composition and structure is established. The absorption coefficients determined experimentally are compared with the results derived from effective medium theories in order to evaluate the suitability of these theories for the studied composites

Space-time description of the two-photon decay

International Nuclear Information System (INIS)

Hrasko, P.

1981-09-01

The time correlation of photons in a two-photon decay is shown to depend on the instantaneous nature of the wave-function collapse in an essential way so the latter hypothesis can be verified by the experimental study of these correlations. (author)

Frequency dependence of coherently amplified two-photon emission from hydrogen molecules