Disorder effect in two-dimensional topological insulators

International Nuclear Information System (INIS)

Zhang Xianglin; Feng Shiping; Guo Huaiming

2012-01-01

We conduct a systematic study on the disorder effect in two-dimensional (2D) topological insulators by calculating the Z 2 topological invariant. Starting from the trivial and nontrivial topological phases of the model describing HgTe/CdTe quantum wells (QWs), we introduce three different kinds of disorder into the system, including the fluctuations in the on-site potential, the hopping amplitude and the topological mass. These kinds of disorder commonly exist in HgTe/CdTe QWs grown experimentally. By explicit numerical calculations, we show that all three kinds of disorder have the similar effect: the topological phase in the system is not only robust to them, but also can be brought about by introducing them to the trivial insulator phase. These results make a further confirmation and extendability of the study on the interplay between the disorder and the topological phase.

On Inclusion-Matrix Interfacial Stresses in Composites Containing Phase-Transforming Phases

International Nuclear Information System (INIS)

Wang, Y.-C.; Ko, C.-C.

2010-01-01

Recent development in composites containing phase-transforming particles, such as vanadium dioxide or barium titanate, reveals the overall stiffness and viscoelastic damping of the composites may be unbounded. Negative stiffness is induced from phase transformation predicted by the Landau phase transformation theory. Although this unbounded phenomenon is theoretically supported with the composite homogenization theory, detailed stress analyses of the composites are still lacking. In this work, we analyze the two-dimensional plane stress elasticity problem of a square plate containing a circular inclusion, under the assumption that the Young's modulus of the inclusion is negative. Assumption of negative stiffness is a priori in the present analysis. A static loading condition is adopted to estimate the effective modulus of the composites by the ratio of applied stress to averaged strain on the loading edges. It is found that the interfacial stresses between the circular inclusion and matrix increase dramatically when the negative stiffness is so tuned that overall stiffness is unbounded. Furthermore, it is found that stress distributions in the inclusion are not uniform, contrary to Eshelby's theorem, which states, for two-phase, infinite composites, the inclusion's stress distribution is uniform when the shape of the inclusion has higher symmetry than an ellipse. The rationale for this nonuniform stress distributions is due to nonlocal effects induced from negative stiffness.

Analytic approximations for the elastic moduli of two-phase materials

DEFF Research Database (Denmark)

Zhang, Z. J.; Zhu, Y. K.; Zhang, P.

2017-01-01

Based on the models of series and parallel connections of the two phases in a composite, analytic approximations are derived for the elastic constants (Young's modulus, shear modulus, and Poisson's ratio) of elastically isotropic two-phase composites containing second phases of various volume...

Theory for disordered phase in Heisenberg and non-Heisenberg two-dimensional S=1 ferromagnets

International Nuclear Information System (INIS)

Spirin, D.V.; Fridman, Yu.A.

2003-01-01

We apply a modification of self-consistent spin-wave theory to investigation of two-dimensional S=1 isotropic Heisenberg and non-Heisenberg ferromagnets at nonzero temperatures. We use Hubbard operators method and bosonization technique. We calculated chemical potential and found dependence of correlation length on temperature. Specific heat has Schottky-type peak and decreases at high temperatures. Disordered phase in non-Heisenberg ferromagnet is also studied. The results for such a model differ from those of Heisenberg one

Anxiety and depression: One, two or three disorders?

OpenAIRE

Novović Zdenka

2004-01-01

The study deals with theoretical psychiatric proposals about relations between anxiety and depressive disorders. Three theoretical positions developed on the basis of numerous evidence on relationship of anxiety and depressive disorders: unitaristic (anxious and depressive disorders represent one disorder with different clinical pictures or phases of the disorder), pluralistic (there are two classes of disorders with clearly recognizable boundaries) and anxious-depressive position (mixed anxi...

Mechanically induced atomic disorder and phase transformations. Doctoral thesis

Energy Technology Data Exchange (ETDEWEB)

Limei, D

1992-11-30

The study shows the possibilities of preparing alloys in various metastable configurations by the simple technique of ball milling. Firstly, chapter 2 gives the description of experimental techniques. In chapter 3, evidence of atomic anti-site disordering in A15-structure superconducting compounds Nb3Sn and Nb3Au during an early stage of milling is demonstrated. Chapter 4 represents the experimental results on the B2-structure magnetic compounds CoGa and CoAl upon mechanical impact. These compounds are well known for their particular type of atomic disorder, namely triple-defect disorder. Various examples of experimental evidence of phase transformations induced by mechanical grinding are presented in chapter 5. Section 5.2 gives an example of amorphization induced by mechanical attrition in the intermetallic compound Ni3Sn. Section 5.3 shows the milling experiment of the intermetallic compound V3 Ga. In section 5.4, for the first time, the observation of a phase transformation to a high-temperature phase with a complex structure will be demonstrated for the intermetallic compound Co3Sn2. In the last chapter, detailed studies on the intermetallic Nb-Au binary compounds for a variety of compositions are presented.

Microstructure and phase composition of sputter-deposited zirconia-yttria films

International Nuclear Information System (INIS)

Knoll, R.W.; Bradley, E.R.

1983-11-01

Thin ZrO 2 -Y 2 O 3 coatings ranging in composition from 3 to 15 mole % Y 2 O 3 were produced by rf sputter deposition. This composition range spanned the region on the equilibrium ZrO 2 -Y 2 O 3 phase diagram corresponding to partially stabilized zirconia (a mixture of tetragonal ZrO 2 and cubic solid solution). Microstructural characteristics and crystalline phase composition of as-deposited and heat treated films (1100 0 C and 1500 0 C) were determined by transmission electron microscopy (TEM) and by x-ray diffraction (XRD). Effects of substrate bias (0 approx. 250 volts), which induced ion bombardment of the film during growth, were also studied. The as-deposited ZrO 2 -Y 2 O 3 films were single phase over the composition range studied, and XRD data indicated considerable local atomic disorder in the lattice. Films produced at low bias contained intergranular voids, pronounced columnar growth, and porosity between columns. At high bias, the microstructure was denser, and films contained high compressive stress. After heat treatment, all deposits remained single phase, therefore a microstructure and precipitate distribution characteristic of toughened, partially stabilized zirconia appear to be difficult to achieve in vapor deposited zirconia coatings

Microstructure characterization of multi-phase composites and utilization of phase change materials and recycled rubbers in cementitious materials

Science.gov (United States)

Meshgin, Pania

2011-12-01

This research focuses on two important subjects: (1) Characterization of heterogeneous microstructure of multi-phase composites and the effect of microstructural features on effective properties of the material. (2) Utilizations of phase change materials and recycled rubber particles from waste tires to improve thermal properties of insulation materials used in building envelopes. Spatial pattern of multi-phase and multidimensional internal structures of most composite materials are highly random. Quantitative description of the spatial distribution should be developed based on proper statistical models, which characterize the morphological features. For a composite material with multi-phases, the volume fraction of the phases as well as the morphological parameters of the phases have very strong influences on the effective property of the composite. These morphological parameters depend on the microstructure of each phase. This study intends to include the effect of higher order morphological details of the microstructure in the composite models. The higher order statistics, called two-point correlation functions characterize various behaviors of the composite at any two points in a stochastic field. Specifically, correlation functions of mosaic patterns are used in the study for characterizing transport properties of composite materials. One of the most effective methods to improve energy efficiency of buildings is to enhance thermal properties of insulation materials. The idea of using phase change materials and recycled rubber particles such as scrap tires in insulation materials for building envelopes has been studied.

Oxygen exchange and transport in dual phase ceramic composite electrodes.

Science.gov (United States)

Druce, John; Téllez, Helena; Ishihara, Tatsumi; Kilner, John A

2015-01-01

Composites consisting of a perovskite-based electronic or mixed conductor with a fluorite-structured ionic conductor are often used as electrodes in solid oxide electrochemical energy conversion devices. After sintering the materials, there is often evidence for inter-reaction between the two phases, or inter-diffusion of cations or impurities between the two phases. We studied the (18)O exchange properties of a composite consisting of CGO and LSCF in a 50 : 50 ratio. High resolution ToF-SIMS mapping reveals that the (18)O fraction at the very outer surface of grains of the CGO phase is much higher than expected from D* and k* values for the single-phase parent material. Surface compositional analysis by ToF-SIMS and low energy ion scattering (LEIS) spectroscopy suggests that the surfaces of the CGO grains in the composite do not show the impurities which typically segregate to the surface in single-phase CGO. Thus, the "cleaning" of impurities from the CGO surface by dissolution into the perovskite phase may be one explanation for the apparent enhanced surface exchange for CGO in these composites.

The Importance of Phonons with Negative Phase Quotient in Disordered Solids.

Science.gov (United States)

Seyf, Hamid Reza; Lv, Wei; Rohskopf, Andrew; Henry, Asegun

2018-02-08

Current understanding of phonons is based on the phonon gas model (PGM), which is best rationalized for crystalline materials. However, most of the phonons/modes in disordered materials have a different character and thus may contribute to heat conduction in a fundamentally different way than is described by PGM. For the modes in crystals, which have sinusoidal character, one can separate the modes into two primary categories, namely acoustic and optical modes. However, for the modes in disordered materials, such designations may no longer rigorously apply. Nonetheless, the phase quotient (PQ) is a quantity that can be used to evaluate whether a mode more so shares a distinguishing property of acoustic vibrations manifested as a positive PQ, or a distinguishing property of an optical vibrations manifested as negative PQ. In thinking about this characteristic, there is essentially no intuition regarding the role of positive vs. negative PQ vibrational modes in disordered solids. Given this gap in understanding, herein we studied the respective contributions to thermal conductivity for several disordered solids as a function of PQ. The analysis sheds light on the importance of optical like/negative PQ modes in structurally/compositionally disordered solids, whereas in crystalline materials, the contributions of optical modes are usually small.

Stability analysis of whirling composite shells partially filled with two liquid phases

Energy Technology Data Exchange (ETDEWEB)

Sahebnasagh, Mohammad [Department of Mechanical Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Nikkhah-Bahrami, Mansour; Firouz-Abadi, Roohollah [Department of Aerospace Engineering, Sharif University, Tehran (Iran, Islamic Republic of)

2017-05-15

In this paper, the stability of whirling composite cylindrical shells partially filled with two liquid phases is studied. Using the first-order shear shell theory, the structural dynamics of the shell is modeled and based on the Navier-Stokes equations for ideal liquid, a 2D model is developed for liquid motion at each section of the cylinder. In steady state condition, liquids are supposed to locate according to mass density. In this study, the thick shells are investigated. Using boundary conditions between liquids, the model of coupled fluid-structure system is obtained. This coupled fluid-structure model is employed to determine the critical speed of the system. The effects of the main variables on the stability of the shell are studied and the results are investigated.

Compensating for non-response in a study estimating the incidence of mental disorders in long-term sickness absence by a two-phased design

DEFF Research Database (Denmark)

Søgaard, Hans Jørgen; Bech, Per

2010-01-01

at 48% by a two-phase design and weighted logistic regression. The total non-response rate was 53.6%. This motivated the present study to compensate for non-response by applying adjustment of the weights and by multiple imputation of missing data in the estimation of the frequencies of mental disorders....... METHODS: The study took place in a Danish population of 120,000 inhabitants. During one year, all 2,414 incident individuals on LSA were identified. By a two-phase design 1,121 individuals were screened in Phase 1. In Phase 2, which was a subsample of Phase 1, 337 individuals participated in a psychiatric...... diagnostic examination applying Present State Examination as gold standard. The weighted analyses were based on scores of the screening instrument SCL-8AD compiled of SCL-8, SCL-ANX4, and SCL-DEP6 from the Common Mental Disorders Screening Questionnaire. In the present study, the variables sex, age...

Phase Composition of a CrMo0.5NbTa0.5TiZr High Entropy Alloy: Comparison of Experimental and Simulated Data

OpenAIRE

Fan Zhang; Oleg N. Senkov; Jonathan D. Miller

2013-01-01

Microstructure and phase composition of a CrMo0.5NbTa0.5TiZr high entropy alloy were studied in the as-solidified and heat treated conditions. In the as-solidified condition, the alloy consisted of two disordered BCC phases and an ordered cubic Laves phase. The BCC1 phase solidified in the form of dendrites enriched with Mo, Ta and Nb, and its volume fraction was 42%. The BCC2 and Laves phases solidified by the eutectic-type reaction, and their volume fractions were 27% and 31%, respectively....

Anxiety and depression: One, two or three disorders?

Directory of Open Access Journals (Sweden)

Novović Zdenka

2004-01-01

Full Text Available The study deals with theoretical psychiatric proposals about relations between anxiety and depressive disorders. Three theoretical positions developed on the basis of numerous evidence on relationship of anxiety and depressive disorders: unitaristic (anxious and depressive disorders represent one disorder with different clinical pictures or phases of the disorder, pluralistic (there are two classes of disorders with clearly recognizable boundaries and anxious-depressive position (mixed anxious-depressive disorder represents also a single disorder. Possible reasons for antagonisms, connections (i.e. lack of connections to some proposals of psychologists are commented upon, as well as the significance of this problem for classification of mental disorders in general.

Thermal Conductivity and Erosion Durability of Composite Two-Phase Air Plasma Sprayed Thermal Barrier Coatings

Science.gov (United States)

Schmitt, Michael P.; Rai, Amarendra K.; Zhu, Dongming; Dorfman, Mitchell R.; Wolfe, Douglas E.

2015-01-01

To enhance efficiency of gas turbines, new thermal barrier coatings (TBCs) must be designed which improve upon the thermal stability limit of 7 wt% yttria stabilized zirconia (7YSZ), approximately 1200 C. This tenant has led to the development of new TBC materials and microstructures capable of improved high temperature performance. This study focused on increasing the erosion durability of cubic zirconia based TBCs, traditionally less durable than the metastable t' zirconia based TBCs. Composite TBC microstructures composed of a low thermal conductivity/high temperature stable cubic Low-k matrix phase and a durable t' Low-k secondary phase were deposited via APS. Monolithic coatings composed of cubic Low-k and t' Low-k were also deposited, in addition to a 7YSZ benchmark. The thermal conductivity and erosion durability were then measured and it was found that both of the Low-k materials have significantly reduced thermal conductivities, with monolithic t' Low-k and cubic Low-k improving upon 7YSZ by approximately 13 and approximately 25%, respectively. The 40 wt% t' Low-k composite (40 wt% t' Low-k - 60 wt% cubic Low-k) showed a approximately 22% reduction in thermal conductivity over 7YSZ, indicating even at high levels, the t' Low-k secondary phase had a minimal impact on thermal in the composite coating. It was observed that a mere 20 wt% t' Low-k phase addition can reduce the erosion of a cubic Low-k matrix phase composite coating by over 37%. Various mixing rules were then investigated to assess this non-linear composite behavior and suggestions were made to further improve erosion durability.

Disordered vortex phases in YBa2Cu3Ox

International Nuclear Information System (INIS)

Crabtree, G. W.; Kwok, W. K.; Olsson, R. J.; Karapetrov, G.; Paulius, L. M.; Petrean, A.; Tobos, V.; Moulton, W. G.

2000-01-01

The disordered vortex phases induced by line and point pinning in YBa 2 Cu 3 O x are explored. At high defect densities there is a single disordered solid separated from the liquid phase by a melting line. At low defect densities the topology of the phase diagram changes dramatically, with a vortex lattice phase adjoining disordered phases at high or low field. Critical points at the termination of first order melting separate the lattice and disordered phases. The line defect disordered phases follow the expected Bose glass behavior, while the point defect disordered phases do not exhibit the expected vortex glass behavior

Isotopic separation of nitrogen 15. Influence of the gaseous phase composition

International Nuclear Information System (INIS)

Lacoste, Germain; Routie, Rene; Mahenc, Jean

1977-01-01

A study has been made on the gas phase composition effect on the isotopic separation of nitrogen 15 for the two HNO 3 -NO and N 2 O 3 -NO systems. It was shown that the changes in composition of the gas phases could account for the increase in the overall separation; most accuracy, measurements of isotopic concentration along the separation column and of total enrichment exhibit how important are the reactions of oxydo-reduction between the two phases in such process [fr

Learning disordered topological phases by statistical recovery of symmetry

Science.gov (United States)

Yoshioka, Nobuyuki; Akagi, Yutaka; Katsura, Hosho

2018-05-01

We apply the artificial neural network in a supervised manner to map out the quantum phase diagram of disordered topological superconductors in class DIII. Given the disorder that keeps the discrete symmetries of the ensemble as a whole, translational symmetry which is broken in the quasiparticle distribution individually is recovered statistically by taking an ensemble average. By using this, we classify the phases by the artificial neural network that learned the quasiparticle distribution in the clean limit and show that the result is totally consistent with the calculation by the transfer matrix method or noncommutative geometry approach. If all three phases, namely the Z2, trivial, and thermal metal phases, appear in the clean limit, the machine can classify them with high confidence over the entire phase diagram. If only the former two phases are present, we find that the machine remains confused in a certain region, leading us to conclude the detection of the unknown phase which is eventually identified as the thermal metal phase.

Two-dimensional phase fraction charts

International Nuclear Information System (INIS)

Morral, J.E.

1984-01-01

A phase fraction chart is a graphical representation of the amount of each phase present in a system as a function of temperature, composition or other variable. Examples are phase fraction versus temperature charts used to characterize specific alloys and as a teaching tool in elementary texts, and Schaeffler diagrams used to predict the amount of ferrite in stainless steel welds. Isothermal-transformation diagrams (TTT diagrams) are examples that give phase (or microconstituent) amount versus temperature and time. The purpose of this communication is to discuss the properties of two-dimensional phase fraction charts in more general terms than have been reported before. It is shown that they can represent multi-component, multiphase equilibria in a way which is easier to read and which contains more information than the isotherms and isopleths of multi-component phase diagrams

Body composition variables and leptin levels in functional hypothalamic amenorrhea and amenorrhea related to eating disorders.

Science.gov (United States)

Bruni, Vincenzina; Dei, Metella; Morelli, Chiara; Schettino, M Teresa; Balzi, Daniela; Nuvolone, Daniela

2011-12-01

The purpose of the study was to identify diagnostic criteria that can distinguish between subjects with functional hypothalamic amenorrhea largely related to minimal energy deficiency and those in whom failure of adaptive response to stress prevails. We studied 59 young women with secondary amenorrhea related to modest eating disorders and 58 who complained of stressful events in their history. We assessed anthropometric measurements, body composition using dual energy X-ray absorptiometry (DEXA) and bioelectrical impedance analysis (BIA), and basal endocrine profile. Subjects with disordered eating had lower body mass index (BMI), fat mass (FM) measured with both techniques, lumbar mineral density and direct and indirect measures of lean mass. Leptin and free tri-iodothyronine(FT(3)) concentrations also proved lower in the group of subjects with eating disorders, although there was no significant difference in cortisol between the two groups. Leptin levels were positively associated not only with fat mass, but also with body cell mass indexed to height and phase angle, parameters studied with BIA as expression of active lean compartment. A multivariate model confirmed the utility of integrating endocrine data with the study of body composition. The use of bioelectrical impedance analysis proved to be, in clinical use, a valid diagnostic alternative to DEXA, especially considering body cell mass and phase angle. Copyright © 2011 North American Society for Pediatric and Adolescent Gynecology. Published by Elsevier Inc. All rights reserved.

Disorder-induced stiffness degradation of highly disordered porous materials

Science.gov (United States)

Laubie, Hadrien; Monfared, Siavash; Radjaï, Farhang; Pellenq, Roland; Ulm, Franz-Josef

2017-09-01

The effective mechanical behavior of multiphase solid materials is generally modeled by means of homogenization techniques that account for phase volume fractions and elastic moduli without considering the spatial distribution of the different phases. By means of extensive numerical simulations of randomly generated porous materials using the lattice element method, the role of local textural properties on the effective elastic properties of disordered porous materials is investigated and compared with different continuum micromechanics-based models. It is found that the pronounced disorder-induced stiffness degradation originates from stress concentrations around pore clusters in highly disordered porous materials. We identify a single disorder parameter, φsa, which combines a measure of the spatial disorder of pores (the clustering index, sa) with the pore volume fraction (the porosity, φ) to scale the disorder-induced stiffness degradation. Thus, we conclude that the classical continuum micromechanics models with one spherical pore phase, due to their underlying homogeneity assumption fall short of addressing the clustering effect, unless additional texture information is introduced, e.g. in form of the shift of the percolation threshold with disorder, or other functional relations between volume fractions and spatial disorder; as illustrated herein for a differential scheme model representative of a two-phase (solid-pore) composite model material.

Efficient and robust compositional two-phase reservoir simulation in fractured media

Science.gov (United States)

Zidane, A.; Firoozabadi, A.

2015-12-01

Compositional and compressible two-phase flow in fractured media has wide applications including CO2 injection. Accurate simulations are currently based on the discrete fracture approach using the cross-flow equilibrium model. In this approach the fractures and a small part of the matrix blocks are combined to form a grid cell. The major drawback is low computational efficiency. In this work we use the discrete-fracture approach to model the fractures where the fracture entities are described explicitly in the computational domain. We use the concept of cross-flow equilibrium in the fractures (FCFE). This allows using large matrix elements in the neighborhood of the fractures. We solve the fracture transport equations implicitly to overcome the Courant-Freidricks-Levy (CFL) condition in the small fracture elements. Our implicit approach is based on calculation of the derivative of the molar concentration of component i in phase (cαi ) with respect to the total molar concentration (ci ) at constant volume V and temperature T. This contributes to significant speed up of the code. The hybrid mixed finite element method (MFE) is used to solve for the velocity in both the matrix and the fractures coupled with the discontinuous Galerkin (DG) method to solve the species transport equations in the matrix, and a finite volume (FV) discretization in the fractures. In large scale problems the proposed approach is orders of magnitude faster than the existing models.

Bias voltage effect on electron tunneling across a junction with a ferroelectric–ferromagnetic two-phase composite barrier

International Nuclear Information System (INIS)

Wang Jian; Ju Sheng; Li, Z.Y.

2012-01-01

The effect of bias voltage on electron tunneling across a junction with a ferroelectric–ferromagnetic composite barrier is investigated theoretically. Because of the inversion symmetry breaking of the spontaneous ferroelectric polarization, bias voltage dependence of the electron tunneling shows significant differences between the positive bias and the negative one. The differences of spin filtering or tunnel magnetoresistance increase with the increasing absolute value of bias voltage. Such direction preferred electron tunneling is found intimately related with the unusual asymmetry of the electrical potential profile in two-phase composite barrier and provides a unique change to realize rectifying functions in spintronics. - Highlights: ► Electron tunneling across a ferroelectric–ferromagnetic composite barrier junction. ► TMR effect is different under the same value but opposite direction bias voltage. ► This directionality of the electron tunneling enhances with increasing bias voltage.

X-ray analysis of phase coexistence and electric poling processing in alkaline niobate-based compositions

International Nuclear Information System (INIS)

Fu Jian; Zuo Ruzhong; Liu Yi

2010-01-01

The characteristic and origin of two-phase coexistence and the content of each phase in typical alkaline niobate-based lead-free compositions were investigated through the refinement of X-ray diffraction peaks and the measurement of dielectric constant versus temperature curves. The diffuse nature of polymorphic phase transition has resulted in the coexistence of two ferroelectric phases within a wide composition and temperature range. As a result, the optimum piezoelectric properties appear in the composition rich in tetragonal phases and there is a remarkable poling temperature effect. Discussions on the difference between morphotropic phase boundary and polymorphic phase boundary were made in combination with the variation of electrical properties.

Comparison of orthorhombic and alpha-two titanium aluminides as matrices for continuous SiC-reinforced composites

International Nuclear Information System (INIS)

Smith, P.R.; Graves, J.A.; Rhodes, C.G.

1994-01-01

The attributes of an orthorhombic Ti aluminide alloy, Ti-21Al-22Nb (at. pct), and an alpha-two Ti aluminide alloy, Ti-24Al-11Nb (at. pct), for use as a matrix with continuous SiC (SCS-6) fiber reinforcement have been compared. Foil-fiber-foil processing was used to produce both unreinforced (''neat'') and unidirectional ''SCS-6'' reinforced panels. Microstructure of the Ti-24Al-11Nb matrix consisted of ordered Ti 3 Al (α 2 ) + disordered beta (β), while the Ti-21Al-22Nb matrix contained three phases: α 2 , ordered beta (β 0 ), and ordered orthorhombic (O). Fiber/matrix interface reaction zone growth kinetics at 982 C were examined for each composite system. Although both systems exhibited similar interface reaction products (i.e., mixed Ti carbides, silicides, and Ti-Al carbides), growth kinetics in the α 2 + β matrix composite were much more rapid than in the O + β 0 + α 2 matrix composite. Additionally, interfacial reaction in the α 2 + β composite resulted in a relatively large brittle matrix zone, depleted of beta phase, which was not present in the O + β 0 + α 2 matrix composite. Mechanical property measurements included room and elevated temperature tensile, thermal stability, thermal fatigue, thermomechanical fatigue (TMF), and creep. The three-phase orthorhombic-based alloy outperformed the α 2 + β alloy in all of these mechanical behavioral areas, on both an absolute and a specific (i.e., density corrected) basis

Disorder-Induced Order in Two-Component Bose-Einstein Condensates

International Nuclear Information System (INIS)

Niederberger, A.; Schulte, T.; Wehr, J.; Lewenstein, M.; Sanchez-Palencia, L.; Sacha, K.

2008-01-01

We propose and analyze a general mechanism of disorder-induced order in two-component Bose-Einstein condensates, analogous to corresponding effects established for XY spin models. We show that a random Raman coupling induces a relative phase of π/2 between the two BECs and that the effect is robust. We demonstrate it in one, two, and three dimensions at T=0 and present evidence that it persists at small T>0. Applications to phase control in ultracold spinor condensates are discussed

Body composition, disordered eating and menstrual regularity in a ...

African Journals Online (AJOL)

Body composition, disordered eating and menstrual regularity in a group of South African ... e between body composition and disordered eating in irregular vs normal menstruating athletes. ... measured by air displacement plethysmography.

Role of oxygen disorder in the ferroelectric phase transitions for various materials

International Nuclear Information System (INIS)

Pasciak, Marek; Goossens, Darren J.; Welberry, Richard T.

2009-01-01

Full text: The nature of ferroelectric phase transitions in many materials have been questioned for many years. Whereas some methods provide definitive evidence of mode softening, other methods, such as local structure probes, indicate the existence of disorder in the paraelectric phase [1]. It is now widely accepted, that the ferroelectric phase transition usually has two components - soft-mode displacive and order-disorder. The latter leads inevitably to some form of pretransitional clusters in the paraelectric phase [2]. In relaxor ferroelectrics, in which disorder drives the transformation, such polar clusters can exist over a wide range of temperatures. Diffuse scattering is a powerful tool for studying such disorder and also for studying short-range order correlations in atomic displacements [3]. In this work we concentrate on the role of oxygens in various materials. By different means of molecular simulations we build models in which the oxygens constitute a framework for short range order correlations. This leads to a discussion of the differences between x-ray and neutron diffuse scattering patterns that may arise due to the disorder of oxygens.

Effect of alloying by lanthanum and high rhenium superalloys on the basis of Ni-Al-Cr on the structure and phase composition

Energy Technology Data Exchange (ETDEWEB)

Kozlov, Eduard, E-mail: kozlov@tsuab.ru; Tsedrik, Elena, E-mail: tsedrik@sibmail.ru; Koneva, Nina, E-mail: koneva@tsuab.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); Popova, Natalya, E-mail: natalya-popova-44@mail.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); Institute of Strength Physics and Materials Science, SB RAS, 2/4, Academicheskii Av., 634055, Tomsk (Russian Federation); Nikonenko, Elena, E-mail: vilatomsk@mail.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); National Research Tomsk Polytechnic University, 30, Lenin Av., 634050, Tomsk (Russian Federation); Fedoricheva, Marina, E-mail: fed-mv@mail.ru [Institute of Strength Physics and Materials Science, SB RAS, 2/4, Academicheskii Av., 634055, Tomsk (Russian Federation); National Research Tomsk Polytechnic University, 30, Lenin Av., 634050, Tomsk (Russian Federation)

2016-01-15

This paper presents transmission and scanning electronic microscope investigations of Ni-Al-Cr superalloy alloyed with additional Re and La elements. This superalloy is obtained by the directional solidification method and subsequently is subjected to two-stage high-temperature annealing: 1) at T = 1150°C, the test time is 1 hour; 2) at T = 1100°C, the testing time is 1430 hours. It was found that the γ- and γ′-phases are the main phases in the two states on the basis of fcc lattice. Where γ is the disordered fcc solid solution and γ′-phase is the main phase with an ordered arrangement of atoms having the L1{sub 2} superstructure. It is shown that such additional elements as Re and La result in the formation of new phases in Ni-Al-Cr accompanied by considerable modifications of quasi-cuboid structure in its γ′-phase. The phase composition and morphology of the phases are studied.

Composite Repair System, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — GTL has developed an innovative composite repair methodology known as the Composite Repair System (CRS). In this phase I effort, CRS is being developed for the...

Two-phase regime in the magnetic field-temperature phase diagram of a type-II superconductor

International Nuclear Information System (INIS)

Adams, L.L.A.; Halterman, Klaus; Valls, Oriol T.; Goldman, A.M.

2004-01-01

The magnetic field and temperature dependencies of the magnetic moments of superconducting crystals of V 3 Si have been studied. In a constant magnetic field and at temperatures somewhat below the superconducting transition temperature, the moments are hysteretic in temperature. However, the magnetic moment-magnetic field isotherms are reversible and exhibit features that formally resemble the pressure-volume isotherms of the liquid-gas transition. This suggests the existence of a first-order phase transition, a two-phase regime, and a critical point in the superconducting phase diagram. The two phases are disordered vortex configurations with the same magnetization, but with different vortex densities. The entropy change, determined from the data using the Clausius-Clapeyron equation, is consistent with estimates based on the difference in the vortex densities of the two phases

Two-phase regime in the magnetic field-temperature phase diagram of a type-II superconductor

Energy Technology Data Exchange (ETDEWEB)

Adams, L.L.A.; Halterman, Klaus; Valls, Oriol T.; Goldman, A.M

2004-01-01

The magnetic field and temperature dependencies of the magnetic moments of superconducting crystals of V{sub 3}Si have been studied. In a constant magnetic field and at temperatures somewhat below the superconducting transition temperature, the moments are hysteretic in temperature. However, the magnetic moment-magnetic field isotherms are reversible and exhibit features that formally resemble the pressure-volume isotherms of the liquid-gas transition. This suggests the existence of a first-order phase transition, a two-phase regime, and a critical point in the superconducting phase diagram. The two phases are disordered vortex configurations with the same magnetization, but with different vortex densities. The entropy change, determined from the data using the Clausius-Clapeyron equation, is consistent with estimates based on the difference in the vortex densities of the two phases.

Continuous solid-state phase transitions in energy storage materials with orientational disorder – Computational and experimental approach

International Nuclear Information System (INIS)

Singh, Harpreet; Talekar, Anjali; Chien, Wen-Ming; Shi, Renhai; Chandra, Dhanesh; Mishra, Amrita; Tirumala, Muralidhar; Nelson, Daryl J.

2015-01-01

We report on TES (thermal energy storage) in new CT (continuous phase transitions) in multicomponent tetrahederally configured (orientationally disordered) crystals of NPG-neopentylglycol-C 5 H 12 O 2 , PG-pentaglycerine-C 5 H 12 O 3 , and PE-pentaerythritol-C 5 H 12 O 4 . This discovery is applicable in thermal energy storage in many systems which do not require conventional isothermal first-order phase transition energy storage. The above compounds exhibit polymorphs of orientationally disordered phases in which O–H…O bond rotation around the C–C bond stores significant amount of energy; for example, in PE 41.26 kJ/mol are absorbed isothermally during solid–solid transitions. In this paper we show, anisothermal continuous phase transitions (CT), due to compositional changes with changes in temperature, associated with a measurable amount of energy, not reported earlier. The correlation of phase stability regions in pseudo-binaries, calculated from ternary NPG–PG–PE phase diagrams, is validated by experimental ternary DSC (differential scanning calorimetry) and in-situ x-ray diffraction data. We established equations for determining the CT in a temperature range, and their respective enthalpies of transitions for any composition of the ternaries. Thermodynamic calculations of the Gibbs energies of the solution phases are modeled as substitutional solid solutions, in which the excess Gibbs energies are expressed by the Redlich–Kister–Muggianu polynomial. There is excellent agreement between the experimental and CALPHAD calculated data. - Highlights: • Continuous phase transition (CT) thermal energy storage in organic ternary system. • Anisothermal temperature ramping leads to CT transitions as per lever rule. • Orientationally disordered phases store energy in O–H…O bond rotation/oscillation. • Validated calculated data with measured thermodynamic properties in ternary system. • Used CALPHAD methodology to calculate Gibbs energies of

Same-strand overlapping genes in bacteria: compositional determinants of phase bias

Directory of Open Access Journals (Sweden)

Landan Giddy

2008-08-01

Full Text Available Abstract Background Same-strand overlapping genes may occur in frameshifts of one (phase 1 or two nucleotides (phase 2. In previous studies of bacterial genomes, long phase-1 overlaps were found to be more numerous than long phase-2 overlaps. This bias was explained by either genomic location or an unspecified selection advantage. Models that focused on the ability of the two genes to evolve independently did not predict this phase bias. Here, we propose that a purely compositional model explains the phase bias in a more parsimonious manner. Same-strand overlapping genes may arise through either a mutation at the termination codon of the upstream gene or a mutation at the initiation codon of the downstream gene. We hypothesized that given these two scenarios, the frequencies of initiation and termination codons in the two phases may determine the number for overlapping genes. Results We examined the frequencies of initiation- and termination-codons in the two phases, and found that termination codons do not significantly differ between the two phases, whereas initiation codons are more abundant in phase 1. We found that the primary factors explaining the phase inequality are the frequencies of amino acids whose codons may combine to form start codons in the two phases. We show that the frequencies of start codons in each of the two phases, and, hence, the potential for the creation of overlapping genes, are determined by a universal amino-acid frequency and species-specific codon usage, leading to a correlation between long phase-1 overlaps and genomic GC content. Conclusion Our model explains the phase bias in same-strand overlapping genes by compositional factors without invoking selection. Therefore, it can be used as a null model of neutral evolution to test selection hypotheses concerning the evolution of overlapping genes. Reviewers This article was reviewed by Bill Martin, Itai Yanai, and Mikhail Gelfand.

Atomic disorder, phase transformation, and phase restoration in Co3Sn2

Science.gov (United States)

di, L. M.; Zhou, G. F.; Bakker, H.

1993-03-01

The behavior of the intermetallic compound Co3Sn2 upon ball milling was studied by x-ray diffraction, high-field-magnetization measurements, and subsequently by differential scanning calorimetry. It turns out that starting from the stoichiometric-ordered compound, mechanical attrition of Co3Sn2 generates atomic disorder in the early stage of milling. The nonequilibrium phase transformation from the low-temperature phase with orthorhombic structure to the high-temperature phase with a hexagonal structure was observed in the intermediate stage of milling. It was accompanied by the creation of increasing atomic disorder. After long milling periods, the phase transformation was completed and the atomic disordering became saturated. All the physical parameters measured in the present work remained constant during this period. The above outcome was confirmed by comparison with the high-temperature phase thermally induced by quenching. The good agreement of the results obtained by different techniques proves that the ball milling generates well-defined metastable states in Co3Sn2.

Two-phase flow in volatile oil reservoir using two-phase pseudo-pressure well test method

Energy Technology Data Exchange (ETDEWEB)

Sharifi, M.; Ahmadi, M. [Calgary Univ., AB (Canada)

2009-09-15

A study was conducted to better understand the behaviour of volatile oil reservoirs. Retrograde condensation occurs in gas-condensate reservoirs when the flowing bottomhole pressure (BHP) lowers below the dewpoint pressure, thus creating 4 regions in the reservoir with different liquid saturations. Similarly, when the BHP of volatile oil reservoirs falls below the bubblepoint pressure, two phases are created in the region around the wellbore, and a single phase (oil) appears in regions away from the well. In turn, higher gas saturation causes the oil relative permeability to decrease towards the near-wellbore region. Reservoir compositional simulations were used in this study to predict the fluid behaviour below the bubblepoint. The flowing bottomhole pressure was then exported to a well test package to diagnose the occurrence of different mobility regions. The study also investigated the use of a two-phase pseudo-pressure method on volatile and highly volatile oil reservoirs. It was concluded that this method can successfully predict the true permeability and mechanical skin. It can also distinguish between mechanical skin and condensate bank skin. As such, the two-phase pseudo-pressure method is particularly useful for developing after-drilling well treatment and enhanced oil recovery process designs. However, accurate relative permeability and PVT data must be available for reliable interpretation of the well test in volatile oil reservoirs. 18 refs., 3 tabs., 9 figs.

Phase diagram of the disordered Bose-Hubbard model

International Nuclear Information System (INIS)

Gurarie, V.; Pollet, L.; Prokof'ev, N. V.; Svistunov, B. V.; Troyer, M.

2009-01-01

We establish the phase diagram of the disordered three-dimensional Bose-Hubbard model at unity filling which has been controversial for many years. The theorem of inclusions, proven by Pollet et al. [Phys. Rev. Lett. 103, 140402 (2009)] states that the Bose-glass phase always intervenes between the Mott insulating and superfluid phases. Here, we note that assumptions on which the theorem is based exclude phase transitions between gapped (Mott insulator) and gapless phases (Bose glass). The apparent paradox is resolved through a unique mechanism: such transitions have to be of the Griffiths type when the vanishing of the gap at the critical point is due to a zero concentration of rare regions where extreme fluctuations of disorder mimic a regular gapless system. An exactly solvable random transverse field Ising model in one dimension is used to illustrate the point. A highly nontrivial overall shape of the phase diagram is revealed with the worm algorithm. The phase diagram features a long superfluid finger at strong disorder and on-site interaction. Moreover, bosonic superfluidity is extremely robust against disorder in a broad range of interaction parameters; it persists in random potentials nearly 50 (!) times larger than the particle half-bandwidth. Finally, we comment on the feasibility of obtaining this phase diagram in cold-atom experiments, which work with trapped systems at finite temperature.

Spheroidization behavior of dendritic b.c.c. phase in Zr-based モ-phase composite

Directory of Open Access Journals (Sweden)

Sun Guoyuan

2013-03-01

Full Text Available The spheroidization behavior of the dendritic b.c.c. phase dispersed in a bulk metallic glass (BMG matrix was investigated through applying semi-solid isothermal processing and a subsequent rapid quenching procedure to a Zr-based モ-phase composite. The Zr-based composite with the composition of Zr56.2Ti13.8Nb5.0Cu6.9Ni5.6Be12.5 was prefabricated by a water-cooled copper mold-casting method and characterized by X-ray diffraction (XRD and scanning electron microscope (SEM. The results show that the composite consists of a glassy matrix and uniformly distributed fine dendrites of the モ-Zr solid solution with the body-centered-cubic (b.c.c. structure. Based on the differential scanning calorimeter (DSC examination results, and in view of the b.c.c. モ-Zr to h.c.p. メ-Zr phase transition temperature, a semi-solid holding temperature of 900 ìC was determined. After reheating the prefabricated composite to the semi-solid temperature, followed by an isothermal holding process at this temperature for 5 min, and then quenching the semi-solid mixture into iced-water; the two-phase microstructure composed of a BMG matrix and uniformly dispersed spherical b.c.c. モ-Zr particles with a high degree of sphericity was achieved. The present spheroidization transition is a thermodynamically autonomic behavior, and essentially a diffusion process controlled by kinetic factors; and the formation of the BMG matrix should be attributed to the rapid quenching of the semi-solid mixture as well as the large glass-forming ability of the remaining melt in the semi-solid mixture.

Construction of the Al-Ni-Si phase diagram over the whole composition and temperature ranges: thermodynamic modeling supported by key experiments and first-principles calculations

Energy Technology Data Exchange (ETDEWEB)

Xiong Wei; Du Yong; Wang Jiong; Zhang Wei-Wei [State Key Lab. of Powder Metallurgy, Central South Univ., Changsha (China); Hu Rong-Xiang; Nash, P. [Thermal Processing Technology Center, Illinois Inst. of Tech., Chicago (United States); Lu Xiao-Gang [Thermo-Calc AB, Stockholm Technology Park, Stockholm (Sweden)

2008-06-15

An extensive thermodynamic investigation of the Al-Ni-Si system is carried out via an integrated approach of calculation of phase diagrams, first-principles calculations, and key experiments. Eighteen decisive alloys are prepared in order to verify the existence of the previously reported ternary compounds and to provide new phase equilibrium data. Phase compositions, microstructure, and phase transition temperatures are determined using the combined techniques of X-ray diffraction, scanning electron microscopy, energy dispersion X-ray analysis, and differential thermal analysis. The order/disorder transition between disordered bccA2 and ordered bccB2 phases as well as that between disordered fccA1 and ordered L1{sub 2} phase are described using a two-sublattice model. A self-consistent parameter set is finally obtained by considering the huge amount of experimental data including 13 vertical sections and 5 isothermal sections from both the literature and the present experiments. Almost all of the reliable phase diagram data can be well described by the present modeling. The reliability of the calculated thermodynamic properties for ternary phases is verified through enthalpy measurement employing drop calorimetry and first-principles calculations. The thermodynamic parameters obtained can also successfully predict most of the thermodynamic properties and describe the solidification path for the selected as-cast alloy Al{sub 6}Ni{sub 55}Si{sub 39}. (orig.)

Order-disorder phase transitions in Au-Cu nanocubes: from nano-thermodynamics to synthesis.

Science.gov (United States)

Mendoza-Cruz, R; Bazán-Diaz, L; Velázquez-Salazar, J J; Samaniego-Benitez, J E; Ascencio-Aguirre, F M; Herrera-Becerra, R; José-Yacamán, M; Guisbiers, G

2017-07-13

Catalysts have been widely used in industries and can be optimized by tuning the composition and chemical ordering of the elements involved in the nano-alloy. Among bi-metallic alloys, the Au-Cu system is of particular interest because it exhibits ordered phases at low temperatures. Nevertheless, the temperature at which these ordered structures are formed is totally unknown at the nanoscale. Consequently, to speed up the development of these catalysts, this paper theoretically predicts the structural phase transitions between ordered and disordered phases for the Au-Cu system by using nano-thermodynamics. Following the predictions, the suggested annealing temperatures have been carefully chosen and consequently, Au-Cu ordered nanocubes have been successfully synthesized through a solventless protocol. The results are fully supported by electron microscopy observations.

Two-boson composites

DEFF Research Database (Denmark)

Tichy, Malte C.; Bouvrier, P. Alexander; Mølmer, Klaus

2013-01-01

Composite bosons made of two bosonic constituents exhibit deviations from ideal bosonic behavior due to their substructure. This deviation is reflected by the normalization ratio of the quantum state of N composites. We find a set of saturable, efficiently evaluable bounds for this indicator, which...... quantifies the bosonic behavior of composites via the entanglement of their constituents. We predict an abrupt transition between ordinary and exaggerated bosonic behavior in a condensate of two-boson composites....

Comparison of Two Methods for Speeding Up Flash Calculations in Compositional Simulations

DEFF Research Database (Denmark)

Belkadi, Abdelkrim; Yan, Wei; Michelsen, Michael Locht

2011-01-01

Flash calculation is the most time consuming part in compositional reservoir simulations and several approaches have been proposed to speed it up. Two recent approaches proposed in the literature are the shadow region method and the Compositional Space Adaptive Tabulation (CSAT) method. The shadow...... region method reduces the computation time mainly by skipping stability analysis for a large portion of compositions in the single phase region. In the two-phase region, a highly efficient Newton-Raphson algorithm can be employed with initial estimates from the previous step. The CSAT method saves...... and the tolerance set for accepting the feed composition are the key parameters in this method since they will influence the simulation speed and the accuracy of simulation results. Inspired by CSAT, we proposed a Tieline Distance Based Approximation (TDBA) method to get approximate flash results in the twophase...

Order-disorder phase transition in ZrV2Dsub(3.6)

International Nuclear Information System (INIS)

Didisheim, J.-J.; Yvon, K.; Tissot, P.

1981-01-01

The deuterated C15-type Laves phase ZrV 2 Dsub(3.6) undergoes a structural phase transition near room temperature (T of the order of 325 K). In the cubic high-temperature phase the deuterium atoms are disordered over two types of tetrahedral interstices, the centres of which are 1.3 A apart. In the tetragonal low-temperature phase the D atoms are ordered and occupy only the energetically more favourable interstices. The tetragonal structure is isotypic with the low-temperature phase of HfV 2 D 4 . The shortest D-D distance is 2.1 A. (author)

Nuclear prehistory influence on irradiated metallic iron phase composition

International Nuclear Information System (INIS)

Alekseev, I.E.

2007-01-01

With application of different Moessbauer spectroscopy applications the phase composition of metallic iron after irradiation by both neutrons and charged particles were studied. Irradiation conditions, method of targets examination and phase composition of samples after irradiation were presented in tabular form. It is shown, that phase composition of irradiated metal is defined by nuclear prehistory. So, in a number of cases abnormals (stabilization of high- and low-temperature structural phases of iron at room temperature after irradiation end) were revealed

Scaling behavior of Anderson transition in system with two types of disorder

International Nuclear Information System (INIS)

Xiong Shijie; Xing, D.Y.; Evangelou, S.N.; Sheng, D.N.

2003-01-01

We present numerical results for a specific phase diagram of the Anderson transition in a model with two types of disorder: the diagonal disorder W 1 , and the off-diagonal disorder W 2 originated from double-exchange interactions. The critical line separating localization and delocalization regions in the W 1 -W 2 phase diagram exhibits zigzag oscillations. This results in multiple critical values of W 2 if W 1 is fixed, although a single critical value of W 1 usually appears when W 2 is fixed. By applying magnetic field the period of oscillations is shortened. Near the critical line the system shows universal scaling behavior with critical exponent dependent only on the field

Optical Phase Measurements of Disorder Strength Link Microstructure to Cell Stiffness.

Science.gov (United States)

Eldridge, Will J; Steelman, Zachary A; Loomis, Brianna; Wax, Adam

2017-02-28

There have been sustained efforts on the part of cell biologists to understand the mechanisms by which cells respond to mechanical stimuli. To this end, many rheological tools have been developed to characterize cellular stiffness. However, measurement of cellular viscoelastic properties has been limited in scope by the nature of most microrheological methods, which require direct mechanical contact, applied at the single-cell level. In this article, we describe, to our knowledge, a new analysis approach for quantitative phase imaging that relates refractive index variance to disorder strength, a parameter that is linked to cell stiffness. Significantly, both disorder strength and cell stiffness are measured with the same phase imaging system, presenting a unique alternative for label-free, noncontact, single-shot imaging of cellular rheologic properties. To demonstrate the potential applicability of the technique, we measure phase disorder strength and shear stiffness across five cellular populations with varying mechanical properties and demonstrate an inverse relationship between these two parameters. The existence of this relationship suggests that predictions of cell mechanical properties can be obtained from examining the disorder strength of cell structure using this, to our knowledge, novel, noncontact technique. Copyright © 2017 Biophysical Society. Published by Elsevier Inc. All rights reserved.

Quantum phase transitions of a disordered antiferromagnetic topological insulator

Science.gov (United States)

Baireuther, P.; Edge, J. M.; Fulga, I. C.; Beenakker, C. W. J.; Tworzydło, J.

2014-01-01

We study the effect of electrostatic disorder on the conductivity of a three-dimensional antiferromagnetic insulator (a stack of quantum anomalous Hall layers with staggered magnetization). The phase diagram contains regions where the increase of disorder first causes the appearance of surface conduction (via a topological phase transition), followed by the appearance of bulk conduction (via a metal-insulator transition). The conducting surface states are stabilized by an effective time-reversal symmetry that is broken locally by the disorder but restored on long length scales. A simple self-consistent Born approximation reliably locates the boundaries of this so-called "statistical" topological phase.

Disorder-induced localization in crystalline phase-change materials.

Science.gov (United States)

Siegrist, T; Jost, P; Volker, H; Woda, M; Merkelbach, P; Schlockermann, C; Wuttig, M

2011-03-01

Localization of charge carriers in crystalline solids has been the subject of numerous investigations over more than half a century. Materials that show a metal-insulator transition without a structural change are therefore of interest. Mechanisms leading to metal-insulator transition include electron correlation (Mott transition) or disorder (Anderson localization), but a clear distinction is difficult. Here we report on a metal-insulator transition on increasing annealing temperature for a group of crystalline phase-change materials, where the metal-insulator transition is due to strong disorder usually associated only with amorphous solids. With pronounced disorder but weak electron correlation, these phase-change materials form an unparalleled quantum state of matter. Their universal electronic behaviour seems to be at the origin of the remarkable reproducibility of the resistance switching that is crucial to their applications in non-volatile-memory devices. Controlling the degree of disorder in crystalline phase-change materials might enable multilevel resistance states in upcoming storage devices.

Colossal magnetoresistance of bulk Ag-doped Nd{sub 0.7}Sr{sub 0.3}MnO{sub 3} two-phase composites

Energy Technology Data Exchange (ETDEWEB)

Cui Xugao [National Laboratory of Solid State Microstructures, Department of Physics, Nanjing University, Nanjing 210093 (China); Hu Xiukun [National Laboratory of Solid State Microstructures, Department of Physics, Nanjing University, Nanjing 210093 (China); Xia Hongxu [National Laboratory of Solid State Microstructures, Department of Physics, Nanjing University, Nanjing 210093 (China); Yu Jiangying [National Laboratory of Solid State Microstructures, Department of Physics, Nanjing University, Nanjing 210093 (China); Zhang Shiyuan [National Laboratory of Solid State Microstructures, Department of Physics, Nanjing University, Nanjing 210093 (China)]. E-mail: zsy@netra.nju.edu.cn

2005-05-17

We have prepared a series of bulk polycrystalline manganites with the nominal compositions, Nd{sub 0.7}Sr{sub 0.3}MnO{sub 3}-Ag {sub x} (x is the molar fraction) with x = 0.1, 0.2, 0.3, 0.4, 0.5 by conventional solid-state reaction. The X-ray diffraction patterns show that the sample Nd{sub 0.7}Sr{sub 0.3}MnO{sub 3} (x = 0) is a single-phase compound with the pseudocubic perovskite structure, while the Ag-doped samples are two-phase composites consisting of a ferromagnetic perovskite phase and a nonmagnetic Ag metal phase. For all the samples, the Curie temperature, T {sub C}, remains nearly the same (228 {+-} 2 K), but the maximum magnetoresistance in a magnetic field of 1 T at 222 K is enhanced strongly due to the addition of Ag, namely, from 45% for the Nd{sub 0.7}Sr{sub 0.3}MnO{sub 3} sample to 188, 277, 142, 158 and 151% for the Nd{sub 0.7}Sr{sub 0.3}MnO{sub 3}-Ag {sub x} samples with x = 0.1, 0.2, 0.3, 0.4, and 0.5, respectively. This magnetoresistance-enhancement phenomenon can be attributed to the spin-dependent scattering of the spin-polarized electrons at the interfaces between the perovskite grains and the Ag granules.

The d-band of disordered Cu3Au as determined by constant initial state photoemission spectroscopy: a search for the origins of the disorder/order phase transition

International Nuclear Information System (INIS)

Stampfl, A.P.J.; Riley, J.D.; Leckey, R.C.G.

1998-01-01

Full text: Binary alloys must either order or phase separate as the temperature is lowered. Substitutionally disordered Cu 3 Au is known to order below a transition temperature of T c =390 deg C. The driving force (of ordering) is believed to be the lowering of free energy as a result of changes to the electronic and compositional structure. Details of the role that particular electronic levels play and the amount of coupling between the electronic and phonon structures, is as yet not fully understood. Gyorffy and Stocks have indeed suggested that instabilities in the electronic structure of the Fermi surface of Cu-Pd alloys may be the driving force for the disorder/order phase transition. It is expected, however, that the Fermi surfaces of ordered and disordered Cu 3 Au to be nearly similar. Our work on the Fermi surface of disordered Cu 3 Au supports this view. Large differences, however, are observed in the d-band region between the ordered and disordered phases and it has been suggested that these states may exhibit a type of electronic instability upon approaching T c . We present our initial study of the d-band region of disordered Cu 3 Au using a constant initial state spectroscopy technique which we previously developed to map the Fermi surface of Cu. Our technique allows the accurate k-space mapping of very flat bands such as d-levels. The k-space shape of the d-bands are compared to calculation and a discussion is given as to their likely role in the phase transition

Interplay between topology and disorder in a two-dimensional semi-Dirac material

Science.gov (United States)

Sriluckshmy, P. V.; Saha, Kush; Moessner, Roderich

2018-01-01

We investigate the role of disorder in a two-dimensional semi-Dirac material characterized by a linear dispersion in one direction and a parabolic dispersion in the orthogonal direction. Using the self-consistent Born approximation, we show that disorder can drive a topological Lifshitz transition from an insulator to a semimetal, as it generates a momentum-independent off-diagonal contribution to the self-energy. Breaking time-reversal symmetry enriches the topological phase diagram with three distinct regimes—single-node trivial, two-node trivial, and two-node Chern. We find that disorder can drive topological transitions from both the single- and two-node trivial to the two-node Chern regime. We further analyze these transitions in an appropriate tight-binding Hamiltonian of an anisotropic hexagonal lattice by calculating the real-space Chern number. Additionally, we compute the disorder-averaged entanglement entropy which signals both the topological Lifshitz and Chern transition as a function of the anisotropy of the hexagonal lattice. Finally, we discuss experimental aspects of our results.

Pulsed cathodoluminescence of nanoscale aluminum oxide with different phase compositions

International Nuclear Information System (INIS)

Kortov, V.S.; Zvonarev, S.V.; Medvedev, A.I.

2011-01-01

The methods of pulsed cathodoluminescence have been used to study compacted powders and ceramics containing different phases of aluminum oxide. An intensive luminescence of the samples under study in the visible, NIR, and UV regions of the spectrum has been found. The luminescence bands are very broad and include a few components. The number of the bands depends on the phase composition of the samples. The oxygen vacancies, which capture one or two electrons, produce luminescence centers in the near UV region. The most probable in the visible region is the luminescence of aggregate defects, impurities, and surface centers. - Highlights: → We investigate pulsed cathodoluminescence spectra of nanoscale alumina. → We found the intensive luminescence in the visible, NIR, and UV regions. → The transformation of R-line structure depends on phase composition of alumina. → We substantiate the relation of luminescence bands with concrete centers.

Mean-field description of ultracold bosons on disordered two-dimensional optical lattices

International Nuclear Information System (INIS)

Buonsante, Pierfrancesco; Massel, Francesco; Penna, Vittorio; Vezzani, Alessandro

2007-01-01

In the present communication, we describe the properties induced by disorder on an ultracold gas of bosonic atoms loaded into a two-dimensional optical lattice with global confinement ensured by a parabolic potential. Our analysis is centred on the spatial distribution of the various phases, focusing particularly on the superfluid properties of the system as a function of external parameters and disorder amplitude. In particular, it is shown how disorder can suppress superfluidity, while partially preserving the system coherence. (fast track communication)

Thermal conductivity of an organic phase change material/expanded graphite composite across the phase change temperature range and a novel thermal conductivity model

International Nuclear Information System (INIS)

Ling, Ziye; Chen, Jiajie; Xu, Tao; Fang, Xiaoming; Gao, Xuenong; Zhang, Zhengguo

2015-01-01

Highlights: • Expanded graphite can improve thermal conductivity of RT44HC by 20–60 times. • Thermal conductivity of PCM/EG composites keeps constant before/after melting. • Thermal conductivity of PCMs nearly doubled during phase changing. • Thermal conductivity of composite PCM increases with density and percentage of EG. • The simple model predicts thermal conductivity of EG-based composites accurately. - Abstract: This work studies factors that affect the thermal conductivity of an organic phase change material (PCM), RT44HC/expanded graphite (EG) composite, which include: EG mass fraction, composite PCM density and temperature. The increase of EG mass fraction and bulk density will both enhance thermal conductivity of composite PCMs, by up to 60 times. Thermal conductivity of RT44HC/EG composites remains independent on temperature outside the phase change range (40–45 °C), but nearly doubles during the phase change. The narrow temperature change during the phase change allows the maximum heat flux or minimum temperature for heat source if attaching PCMs to a first (constant temperature) or second (constant heat flux) thermal boundary. At last, a simple thermal conductivity model for EG-based composites is put forward, based on only two parameters: mass fraction of EG and bulk density of the composite. This model is validated with experiment data presented in this paper and in literature, showing this model has general applicability to any composite of EG and poor thermal conductive materials

Transient two-phase flow

International Nuclear Information System (INIS)

Hsu, Y.Y.

1974-01-01

The following papers related to two-phase flow are summarized: current assumptions made in two-phase flow modeling; two-phase unsteady blowdown from pipes, flow pattern in Laval nozzle and two-phase flow dynamics; dependence of radial heat and momentum diffusion; transient behavior of the liquid film around the expanding gas slug in a vertical tube; flooding phenomena in BWR fuel bundles; and transient effects in bubble two-phase flow. (U.S.)

Two-phase flow models in unbounded two-phase critical flows

International Nuclear Information System (INIS)

Celata, G.P.; Cumo, M.; Farello, G.E.

1985-01-01

With reference to a Loss-of-Coolant Accident in Light Water Reactors, an analysis of the unbounded two-phase critical flow (i.e. the issuing two-phase jet) has been accomplished. Considering jets external shape, obtained by means of photographic pictures; pressure profiles inside the jet, obtained by means of a movable ''Pitot;'' and jet phases distribution information, obtained by means of X-rays pictures; a characterization of the flow pattern in the unbounded region of a two-phase critical flow is given. Jets X-ray pictures show the existence of a central high density ''core'' gradually evaporating all around, which gives place to a characteristic ''dartflow'' the length of which depends on stagnation thermodynamic conditions

On the stability of the disordered molecular alloy phase of ammonia hemihydrate

International Nuclear Information System (INIS)

Wilson, C. W.; Bull, C. L.; Stinton, G. W.; Amos, D. M.; Donnelly, M.-E.; Loveday, J. S.

2015-01-01

The disordered-molecular-alloy phase (DMA) of ammonia hydrates [J. S. Loveday and R. J. Nelmes, Phys. Rev. Lett. 83, 4329 (1999)] is unique in that it has substitutional disorder of ammonia and water over the molecular sites of a body centred cubic lattice. Whilst this structure has been observed in ammonia di- and mono-hydrate compositions, it has not been conclusively observed in the ammonia hemihydrate system. This work presents investigations of the structural behaviour of ammonia hemihydrate as a function of P and T. The indications of earlier studies [Ma et al. RSC Adv. 2, 4290 (2012)] that the DMA structure could be produced by compression of ammonia hemihydrate above 20 GPa at ambient temperature are confirmed. In addition, the DMA structure was found to form reversibly both from the melt, and on warming of ammonia hemihydrate phase-II, in the pressure range between 4 and 8 GPa. The route used to make the DMA structure from ammonia mono- and di-hydrates—compression at 170 K to 6 GPa followed by warming to ambient temperature—was found not to produce the DMA structure for ammonia hemihydrate. These results provide the first strong evidence that DMA is a thermodynamically stable form. A high-pressure phase diagram for ammonia hemihydrate is proposed which has importance for planetary modelling

Quantum phases of dipolar rotors on two-dimensional lattices.

Science.gov (United States)

Abolins, B P; Zillich, R E; Whaley, K B

2018-03-14

The quantum phase transitions of dipoles confined to the vertices of two-dimensional lattices of square and triangular geometry is studied using path integral ground state quantum Monte Carlo. We analyze the phase diagram as a function of the strength of both the dipolar interaction and a transverse electric field. The study reveals the existence of a class of orientational phases of quantum dipolar rotors whose properties are determined by the ratios between the strength of the anisotropic dipole-dipole interaction, the strength of the applied transverse field, and the rotational constant. For the triangular lattice, the generic orientationally disordered phase found at zero and weak values of both dipolar interaction strength and applied field is found to show a transition to a phase characterized by net polarization in the lattice plane as the strength of the dipole-dipole interaction is increased, independent of the strength of the applied transverse field, in addition to the expected transition to a transverse polarized phase as the electric field strength increases. The square lattice is also found to exhibit a transition from a disordered phase to an ordered phase as the dipole-dipole interaction strength is increased, as well as the expected transition to a transverse polarized phase as the electric field strength increases. In contrast to the situation with a triangular lattice, on square lattices, the ordered phase at high dipole-dipole interaction strength possesses a striped ordering. The properties of these quantum dipolar rotor phases are dominated by the anisotropy of the interaction and provide useful models for developing quantum phases beyond the well-known paradigms of spin Hamiltonian models, implementing in particular a novel physical realization of a quantum rotor-like Hamiltonian that possesses an anisotropic long range interaction.

Quantum phases of dipolar rotors on two-dimensional lattices

Science.gov (United States)

Abolins, B. P.; Zillich, R. E.; Whaley, K. B.

2018-03-01

The quantum phase transitions of dipoles confined to the vertices of two-dimensional lattices of square and triangular geometry is studied using path integral ground state quantum Monte Carlo. We analyze the phase diagram as a function of the strength of both the dipolar interaction and a transverse electric field. The study reveals the existence of a class of orientational phases of quantum dipolar rotors whose properties are determined by the ratios between the strength of the anisotropic dipole-dipole interaction, the strength of the applied transverse field, and the rotational constant. For the triangular lattice, the generic orientationally disordered phase found at zero and weak values of both dipolar interaction strength and applied field is found to show a transition to a phase characterized by net polarization in the lattice plane as the strength of the dipole-dipole interaction is increased, independent of the strength of the applied transverse field, in addition to the expected transition to a transverse polarized phase as the electric field strength increases. The square lattice is also found to exhibit a transition from a disordered phase to an ordered phase as the dipole-dipole interaction strength is increased, as well as the expected transition to a transverse polarized phase as the electric field strength increases. In contrast to the situation with a triangular lattice, on square lattices, the ordered phase at high dipole-dipole interaction strength possesses a striped ordering. The properties of these quantum dipolar rotor phases are dominated by the anisotropy of the interaction and provide useful models for developing quantum phases beyond the well-known paradigms of spin Hamiltonian models, implementing in particular a novel physical realization of a quantum rotor-like Hamiltonian that possesses an anisotropic long range interaction.

Two-phase flow models

International Nuclear Information System (INIS)

Delaje, Dzh.

1984-01-01

General hypothesis used to simplify the equations, describing two-phase flows, are considered. Two-component and one-component models of two-phase flow, as well as Zuber and Findlay model for actual volumetric steam content, and Wallis model, describing the given phase rates, are presented. The conclusion is made, that the two-component model, in which values averaged in time are included, is applicable for the solving of three-dimensional tasks for unsteady two-phase flow. At the same time, using the two-component model, including values, averaged in space only one-dimensional tasks for unsteady two-phase flow can be solved

Searching for Next Single-Phase High-Entropy Alloy Compositions

Directory of Open Access Journals (Sweden)

David E. Alman

2013-10-01

Full Text Available There has been considerable technological interest in high-entropy alloys (HEAs since the initial publications on the topic appeared in 2004. However, only several of the alloys investigated are truly single-phase solid solution compositions. These include the FCC alloys CoCrFeNi and CoCrFeMnNi based on 3d transition metals elements and BCC alloys NbMoTaW, NbMoTaVW, and HfNbTaTiZr based on refractory metals. The search for new single-phase HEAs compositions has been hindered by a lack of an effective scientific strategy for alloy design. This report shows that the chemical interactions and atomic diffusivities predicted from ab initio molecular dynamics simulations which are closely related to primary crystallization during solidification can be used to assist in identifying single phase high-entropy solid solution compositions. Further, combining these simulations with phase diagram calculations via the CALPHAD method and inspection of existing phase diagrams is an effective strategy to accelerate the discovery of new single-phase HEAs. This methodology was used to predict new single-phase HEA compositions. These are FCC alloys comprised of CoFeMnNi, CuNiPdPt and CuNiPdPtRh, and HCP alloys of CoOsReRu.

Anderson localization in metamaterials with compositional disorder

Science.gov (United States)

Torres-Herrera, E. J.; Izrailev, F. M.; Makarov, N. M.

2011-11-01

We consider one-dimensional periodic-on-average bi-layered models with random perturbations in dielectric constants of both basic slabs composing the structure unit-cell. We show that when the thicknesses da and db of basic layers are essentially nonequal, da ≠ db, the localization length Lloc is described by the universal expression for two cases: (a) both layers are made from right-handed materials (the RH-RH model), (b) the a layers are of a right-handed material while the b layers are of a left-handed material (the RH-LH model). For these models the derived expression for Lloc includes all possible correlations between two disorders. However, when da = db the RH-LH model exhibits a highly nontrivial properties originated from inhomogeneous distribution of the phase of propagating wave, even in the case of white-noise disorder. We analytically show that in this case the localization length diverges in the conventional second order in perturbation parameters. Therefore, recently numerically discovered anomalies in Lloc are due to the next order of approximation. On the other hand, for the RH-RH model the general expression for Lloc remains valid for da = db as well.

Two-phase magnetoconvection flow of magnetite (Fe3O4) nanoparticles in a horizontal composite porous annulus

Science.gov (United States)

Abbas, Zaheer; Hasnain, Jafar

A numerical study is performed to examine the two-phase magnetoconvection and heat transfer phenomena of Fe3O4 -kerosene nanofluid flow in a horizontal composite porous annulus with an external magnetic field. The annulus is filled with immiscible fluids flowing between two concentric cylinders. The governing equations of the flow problem are obtained using Darcy-Brinkman model. Heat transfer is analyzed in the presence of viscous and Darcian dissipation terms. The shooting method is used as a tool to solve the obtained non-linear ordinary differential equations for the velocity and temperature profiles. The velocity and temperature distributions are analyzed and discussed under the influence of involved flow parameters with the aid of graphs. It is found that both velocity and temperature of fluid are decreased with ferroparticle volume fraction. In addition to that, it is also presented that the existence of magnetic field decreases the benefit of ferrofluids in heat transfer progression.

Effect of disorders on topological phases in one-dimensional optical superlattices

International Nuclear Information System (INIS)

Wang Zhizhou; Wu Yidong; Du Huijing; Jing Xili

2016-01-01

In a recent paper, Lang et al. proposed that edge states and topological phases can be observed in one-dimensional optical superlattices. They showed that the topological phases can be revealed by observing the density profile of a trapped fermion system, which displays plateaus with their positions. However, disorders are not considered in their model. To study the effect of disorders on the topological phases, we introduce random potentials to the model for optical superlattcies. Our calculations show that edge states are robust against the disorders. We find the edge states are very sensitive to the number of the sites in the optical superlattice and we propose a simple rule to describe the relationship between the edge states and the number of sites. The density plateaus are also robust against weak disorders provided that the average density is calculated over a long interval. The widths of the plateaus are proportional to the widths of the bulk energy gaps when there are disorders. The disorders can diminish the bulk energy gaps. So the widths of the plateaus decrease with the increase of disorders and the density plateaus disappear when disorders are too strong. The results in our paper can be used to guide the experimental detection of topological phases in one-dimensional systems. (paper)

Progress in Dual (Piezoelectric-Magnetostrictive Phase Magnetoelectric Sintered Composites

Directory of Open Access Journals (Sweden)

Rashed Adnan Islam

2012-01-01

Full Text Available The primary aims of this review article are (a to develop the fundamental understanding of ME behavior in perovskite piezoelectric-spinel magnetostrictive composite systems, (b to identify the role of composition, microstructural variables, phase transformations, composite geometry, and postsintering heat treatment on ME coefficient, and (c to synthesize, characterize, and utilize the high ME coefficient composite. The desired range of ME coefficient in the sintered composite is 0.5–1 V/cm⋅Oe. The studies showed that the soft piezoelectric phase quantified by smaller elastic modulus, large grain size of piezoelectric phase (~1 μm, and layered structures yields higher magnitude of ME coefficient. It is also found that postsintering thermal treatment such as annealing and aging alters the magnitude of magnetization providing an increase in the magnitude of ME coefficient. A trilayer composite was synthesized using pressure-assisted sintering with soft phase [0.9 PZT–0.1 PZN] having grain size larger than 1 μm and soft ferromagnetic phase of composition Ni0.8Cu0.2Zn0.2Fe2O4 [NCZF]. The composite showed a high ME coefficient of 412 and 494 mV/cm⋅Oe after sintering and annealing, respectively. Optimized ferrite to PZT thickness ratio was found to be 5.33, providing ME coefficient of 525 mV/cm⋅Oe. The ME coefficient exhibited orientation dependence with respect to applied magnetic field. Multilayering the PZT layer increased the magnitude of ME coefficient to 782 mV/cm⋅Oe. Piezoelectric grain texturing and nanoparticulate assembly techniques were incorporated with the layered geometry. It was found that with moderate texturing, d33 and ME coefficient reached up to 325 pC/N and 878 mV/cm⋅Oe, respectively. Nanoparticulate core shell assembly shows the promise for achieving large ME coefficient in the sintered composites. A systematic relationship between composition, microstructure, geometry, and properties is

Analysis of Two-Phase Flow in Damper Seals for Cryogenic Turbopumps

Science.gov (United States)

Arauz, Grigory L.; SanAndres, Luis

1996-01-01

Cryogenic damper seals operating close to the liquid-vapor region (near the critical point or slightly su-cooled) are likely to present two-phase flow conditions. Under single phase flow conditions the mechanical energy conveyed to the fluid increases its temperature and causes a phase change when the fluid temperature reaches the saturation value. A bulk-flow analysis for the prediction of the dynamic force response of damper seals operating under two-phase conditions is presented as: all-liquid, liquid-vapor, and all-vapor, i.e. a 'continuous vaporization' model. The two phase region is considered as a homogeneous saturated mixture in thermodynamic equilibrium. Th flow in each region is described by continuity, momentum and energy transport equations. The interdependency of fluid temperatures and pressure in the two-phase region (saturated mixture) does not allow the use of an energy equation in terms of fluid temperature. Instead, the energy transport is expressed in terms of fluid enthalpy. Temperature in the single phase regions, or mixture composition in the two phase region are determined based on the fluid enthalpy. The flow is also regarded as adiabatic since the large axial velocities typical of the seal application determine small levels of heat conduction to the walls as compared to the heat carried by fluid advection. Static and dynamic force characteristics for the seal are obtained from a perturbation analysis of the governing equations. The solution expressed in terms of zeroth and first order fields provide the static (leakage, torque, velocity, pressure, temperature, and mixture composition fields) and dynamic (rotordynamic force coefficients) seal parameters. Theoretical predictions show good agreement with experimental leakage pressure profiles, available from a Nitrogen at cryogenic temperatures. Force coefficient predictions for two phase flow conditions show significant fluid compressibility effects, particularly for mixtures with low mass

Interplay between topology and disorder in a two-dimensional semi-Dirac material

OpenAIRE

Sriluckshmy, P. V.; Saha, Kush; Moessner, Roderich

2017-01-01

We investigate the role of disorder in a two-dimensional semi-Dirac material characterized by a linear dispersion in one, and a parabolic dispersion in the orthogonal, direction. Using the self-consistent Born approximation, we show that disorder can drive a topological Lifshitz transition from an insulator to a semi-metal, as it generates a momentum independent off-diagonal contribution to the self-energy. Breaking time-reversal symmetry enriches the topological phase diagram with three dist...

Computational study of heat transport in compositionally disordered binary crystals

International Nuclear Information System (INIS)

Lyver, John W.; Blaisten-Barojas, Estela

2006-01-01

The thermal conductivity of compositionally disordered binary crystals with atoms interacting through Lennard-Jones potentials has been studied as a function of temperature. The two species in the crystal differ in mass, hard-core atomic diameter, well depth and relative concentration. The isobaric Monte Carlo was used to equilibrate the samples at near-zero pressure. The isoenergy molecular dynamics combined with the Green-Kubo approach was taken to calculate the heat current time-dependent autocorrelation function and determine the lattice thermal conductivity of the sample. The inverse temperature dependence of the lattice thermal conductivity was shown to fail at low temperatures when the atomic diameters of the two species differ. Instead, the thermal conductivity was nearly a constant across temperatures for species with different atomic diameters. Overall, it is shown that there is a dramatic decrease of the lattice thermal conductivity with increasing atomic radii ratio between species and a moderate decrease due to mass disorder

Anderson localization in metamaterials with compositional disorder

International Nuclear Information System (INIS)

Torres-Herrera, E.J.; Izrailev, F.M.; Makarov, N.M.

2011-01-01

We consider one-dimensional periodic-on-average bi-layered models with random perturbations in dielectric constants of both basic slabs composing the structure unit-cell. We show that when the thicknesses da and db of basic layers are essentially nonequal, da not = db, the localization length L-l-o-c is described by the universal expression for two cases: (a) both layers are made from right-handed materials (the RH-RH model), (b) the a layers are of a right-handed material while the b layers are of a left-handed material (the RH-LH model). For these models the derived expression for L-l-o-c includes all possible correlations between two disorders. However, when da = db the RH-LH model exhibits a highly nontrivial properties originated from inhomogeneous distribution of the phase of propagating wave, even in the case of white-noise disorder. We analytically show that in this case the localization length diverges in the conventional second order in perturbation parameters. Therefore, recently numerically discovered anomalies in L-l-o-c are due to the next order of approximation. On the other hand, for the RH-RH model the general expression for Lloc remains valid for da = db as well.

Two phase sampling

CERN Document Server

Ahmad, Zahoor; Hanif, Muhammad

2013-01-01

The development of estimators of population parameters based on two-phase sampling schemes has seen a dramatic increase in the past decade. Various authors have developed estimators of population using either one or two auxiliary variables. The present volume is a comprehensive collection of estimators available in single and two phase sampling. The book covers estimators which utilize information on single, two and multiple auxiliary variables of both quantitative and qualitative nature. Th...

Phase composition of Al-Ti-Nb-Mo γ alloys in the heat-treatment temperature range: Calculation and experiment

Science.gov (United States)

Belov, N. A.; Dashkevich, N. I.; Bel'tyukova, S. O.

2015-07-01

The phase composition of TNM-type Al-Ti-Nb-Mo γ alloys at heat-treatment temperatures is quantitatively studied using the Thermo-Calc program package and experimental methods. Isothermal cross sections are calculated and the joint influence of two alloying elements on the phase composition of the alloy is determined at the mean concentration of a third component. Based on the calculations of vertical cross sections, the boundaries of the four-phase eutectoid reaction α → α2 + β + γ are found. The temperature is shown to significantly influence the phase compositions of the γ alloys, among them the mass fractions of various phases (α, β, γ,α2) and the element concentration in them.

Composition-induced structural phase transitions in the (Ba1-xLax)2In2O5+x (0=

International Nuclear Information System (INIS)

Tenailleau, C.; Pring, A.; Moussa, S.M.; Liu, Y.; Withers, R.L.; Tarantino, S.; Zhang, M.; Carpenter, M.A.

2005-01-01

Composition-induced structural phase changes across the high temperature, fast oxide ion conducting (Ba 1-x La x ) 2 In 2 O 5+x , 0= orthorhombic transition, while the cubic->tetragonal transition could be continuous. Differences between the variation with composition of spectral parameters and of macroscopic strain parameters are consistent with a substantial order/disorder component for the transitions. There is also evidence for precursor effects within the cubic structure before symmetry is broken

Rounding by disorder of first-order quantum phase transitions: emergence of quantum critical points.

Science.gov (United States)

Goswami, Pallab; Schwab, David; Chakravarty, Sudip

2008-01-11

We give a heuristic argument for disorder rounding of a first-order quantum phase transition into a continuous phase transition. From both weak and strong disorder analysis of the N-color quantum Ashkin-Teller model in one spatial dimension, we find that, for N > or =3, the first-order transition is rounded to a continuous transition and the physical picture is the same as the random transverse field Ising model for a limited parameter regime. The results are strikingly different from the corresponding classical problem in two dimensions where the fate of the renormalization group flows is a fixed point corresponding to N-decoupled pure Ising models.

Equilibrium phases of dipolar lattice bosons in the presence of random diagonal disorder

Science.gov (United States)

Zhang, C.; Safavi-Naini, A.; Capogrosso-Sansone, B.

2018-01-01

Ultracold gases offer an unprecedented opportunity to engineer disorder and interactions in a controlled manner. In an effort to understand the interplay between disorder, dipolar interactions, and quantum degeneracy, we study two-dimensional hard-core dipolar lattice bosons in the presence of on-site bound disorder. Our results are based on large-scale path-integral quantum Monte Carlo simulations by the worm algorithm. We study the ground-state phase diagram at a fixed half-integer filling factor for which the clean system is either a superfluid at a lower dipolar interaction strength or a checkerboard solid at a larger dipolar interaction strength. We find that, even for weak dipolar interactions, superfluidity is destroyed in favor of a Bose glass at a relatively low disorder strength. Interestingly, in the presence of disorder, superfluidity persists for values of the dipolar interaction strength for which the clean system is a checkerboard solid. At a fixed disorder strength, as the dipolar interaction is increased, superfluidity is destroyed in favor of a Bose glass. As the interaction is further increased, the system eventually develops extended checkerboard patterns in the density distribution. Due to the presence of disorder, though, grain boundaries and defects, responsible for a finite residual compressibility, are present in the density distribution. Finally, we study the robustness of the superfluid phase against thermal fluctuations.

Preejaculatory illness syndrome: Two cases of a rare psychosomatic disorder

Directory of Open Access Journals (Sweden)

Adel Mohsen

2016-01-01

Full Text Available Human ejaculation happens in the orgasmic phase of the human sexual response cycle. Among psychosomatic ejaculatory disorders that may happen before ejaculation, we present two cases of preejaculatory illness syndrome. The two cases shared common symptoms of sympathetic over activity, the sensation of impending death, and muscle atonia with subsequent failure to ejaculate. Depression, anxiety disorders, and family histories of psychiatric problems were noticed as risk factors. Medical conditions that may lead to panic attack type symptoms were eliminated before the final diagnosis. After the failure of empirical medications, symptoms became controlled with fluoxetine. Patients reported a recurrence of the symptoms on trying to stop the prescribed medication. On the last follow-up, they still take fluoxetine on a regular base with satisfactory sexual life.

Nonergodic dynamics of the two-dimensional random-phase sine-Gordon model: Applications to vortex-glass arrays and disordered-substrate surfaces

International Nuclear Information System (INIS)

Cule, D.; Shapir, Y.

1995-01-01

The dynamics of the random-phase sine-Gordon model, which describes two-dimensional vortex-glass arrays and crystalline surfaces on disordered substrates, is investigated using the self-consistent Hartree approximation. The fluctuation-dissipation theorem is violated below the critical temperature T c for large time t>t * where t * diverges in the thermodynamic limit. While above T c the averaged autocorrelation function diverges as Tln(t), for T c it approaches a finite value q * ∼1/(T c -T) as q(t)=q * -c(t/t * ) -ν (for t→t * ) where ν is a temperature-dependent exponent. On larger time scales t>t * the dynamics becomes nonergodic. The static correlations behave as ∼Tln|rvec x| for T>T c and for T c when x * with ξ * ∼exp{A/(T c -T)}. For scales x>ξ * , they behave as ∼m -1 Tln|rvec x| where m∼T/T c near T c , in general agreement with the variational replica-symmetry breaking approach and with recent simulations of the disordered-substrate surface. For strong coupling the transition becomes first order

Tethered Nanoparticle–Polymer Composites: Phase Stability and Curvature

KAUST Repository

Srivastava, Samanvaya; Agarwal, Praveen; Archer, Lynden A.

2012-01-01

different small-angle X-ray scattering signatures in comparison to phase-separated composites comprised of bare or sparsely grafted nanoparticles. A general diagram for the dispersion state and phase stability of polymer tethered nanoparticle-polymer

Ductile-phase toughening in V-V3Si in situ composites

International Nuclear Information System (INIS)

Henshall, G.; Strum, M.J.; Bewlay, B.P.; Sutliff, J.A.

1997-01-01

This article describes the room-temperature fracture behavior of ductile-phase-toughened V-V 3 Si in situ composites that were produced by arc melting (AM), cold-crucible induction melting (IM), and cold-crucible directional solidification (DS). Composites were produced containing a wide range of microstructures, interstitial impurity contents, and volume fractions of the ductile V-Si solid solution phase, denoted (V). The fracture toughness of these composites generally increases as the volume fraction of (V) increases, but is strongly influenced by the microstructure, the mechanical properties of the component phases, and the crystallographic orientation of the (V) phase with respect to the maximum principal stress direction. For eutectic composites that have a (V) volume fraction of about 50 pct, the fracture toughness increases with decreasing ''''effective'''' interstitial impurity concentration, [I] = [N] + 1.33 [O] + 9 [H]. As [I] decreases from 1,400 ppm (AM) to 400 ppm (IM), the fracture toughness of the eutectic composites increases from 10 to 20 MPa √m. Further, the fracture toughness of the DS eutectic composites is greater when the crack propagation direction is perpendicular, rather than parallel, to the composite growth direction. These results are discussed in light of conventional ductile-phase bridging theories, which alone cannot fully explain the fracture toughness of V-Si in situ composites

Composition-microstructure-property relationships in dual phase bulk magnetoelectric composite

Science.gov (United States)

Islam, Rashed Adnan

The coexistence of coupled electrical and magnetic properties in the "magnetoelectric" material has led to the possibility of developing smarter and smaller electronic components. In order to make this possibility a reality, significant efforts are required to understand the science of magnetoelectric (ME) behavior and apply this understanding to develop higher sensitivity material. The primary aims of this thesis are to identify the role of composition, microstructural variables, composite geometry, texturing, post sintering heat treatment, and nanoscale assembly on ME coefficient. The overall objective is to synthesize, characterize and utilize a high ME coefficient composite. The desired range of ME coefficient in the sintered composite is more than 1.5 V/cm.Oe. At first, a piezoelectric composition in the system of Pb(Zr,Ti)O 3 - Pb[(Zn,Ni)1/3Nb2/3]O3 was designed and synthesized which has high energy density (d.g) parameter of 18456.2 x 10-15m2/N and high g constant of 83.1 V-m/N in order to use it as the matrix in piezoelectric---magnetostrictive composite. Secondly it was found that soft piezoelectric phase shows much better magnetoelectric response. The magnetoelectric coefficient for Pb(Zr 0.52Ti0.48)O3 - 15% Pb(Zn1/3Nb 2/3)O3 [PZT - 15 PZN] - 20% Ni0.8Zn 0.2Fe2O4 was found to be around 186 mV/cm.Oe. Thridly, soft magnetic phase with lower coercivity and higher magnetization was found to be suitable for high ME coefficient. Zinc doped Ni-ferrite has higher resistivity, permeability, magnetization and it was found that with increasing Zn concentration the ME coefficient increases exhibiting maxima near 30 at% Zn (138 mV/cm.Oe). Fourthly, if the connectivity was changed from (0-3) to (2-2) which is a bilayer geometry, improved piezoelectric (d33 ˜ 80 pC/N), ferroelectric (polarization = 60 muC/cm2), magnetization (25 emu/gm) and lower coercive field (2.8 Oe) were measured. The bilayer shows an enhancement of 67% increase in ME coefficient compared to bulk

The exploration of stability of two-dimensional nanocrystalline metallic composites depending on temperature

International Nuclear Information System (INIS)

Poletayev, G.M.; Starostenkov, M.D.; Popova, G.V.; Skakov, M.K.

2004-01-01

Full text: In nanocrystalline compositional materials the borders of phase separation play special role. The detection of stability of the borders of phase separation depending on external conditions, such pressure, temperature of alloying is the important task in the case of nanocrystalline materials. In the current paper the stability of two-dimensional nanocrystal, composite on the basis of Ni-Al system, depending on the structure of compositional material and vacancy availability is studied. Atomic packing in two-dimensional crystal corresponds to the plane (111) of fee crystal structure, or the plane (111) of superstructure L1 2 of intermetallide system Ni-Al. The interaction between atoms is set by pair potential functions of Morse, that consider interatomic bonding in the first six coordinate spheres. The calculated block was expressed in atomic packing in the cell 40x40. Beyond the bounds of the calculated block crystal is repeated with the help of periodical border conditions. Computer modeling is performed according to the method of molecular dynamics, when speeds of atom dislocations depending on temperature are set in accidental way, according to Boltzmann allocation. Two-dimensional material was represented by different packs of phases, clean Ni, Al and intermetallic superstructure NiAl in accordance with concentrations, structures and forms. It was understood that when the concentration in composite of phase of clean Al increases, or when the number of Al atoms in intermetallide rises, the initial temperature of thermo activated diffusing destruction of interphase borders turns out to be very low. On the other hand, when the part of clean nickel increases or when the concentration of clean Ni atoms in the structure (L1 2 ) rises, diffusion stability of interphase borders is observes right up to high temperatures. According to the results, basic diffusion processes take place right on interphase borders

Theory of the disordered ν =5/2 quantum thermal Hall state: Emergent symmetry and phase diagram

Science.gov (United States)

Lian, Biao; Wang, Juven

2018-04-01

Fractional quantum Hall (FQH) system at Landau level filling fraction ν =5 /2 has long been suggested to be non-Abelian, either Pfaffian (Pf) or antiPfaffian (APf) states by numerical studies, both with quantized Hall conductance σx y=5 e2/2 h . Thermal Hall conductances of the Pf and APf states are quantized at κx y=7 /2 and κx y=3 /2 , respectively, in a proper unit. However, a recent experiment shows the thermal Hall conductance of ν =5 /2 FQH state is κx y=5 /2 . It has been speculated that the system contains random Pf and APf domains driven by disorders, and the neutral chiral Majorana modes on the domain walls may undergo a percolation transition to a κx y=5 /2 phase. In this paper, we do perturbative and nonperturbative analyses on the domain walls between Pf and APf. We show the domain wall theory possesses an emergent SO(4) symmetry at energy scales below a threshold Λ1, which is lowered to an emergent U (1 )×U (1) symmetry at energy scales between Λ1 and a higher value Λ2, and is finally lowered to the composite fermion parity symmetry Z2F above Λ2. Based on the emergent symmetries, we propose a phase diagram of the disordered ν =5 /2 FQH system and show that a κx y=5 /2 phase arises at disorder energy scales Λ >Λ1 . Furthermore, we show the gapped double-semion sector of ND compact domain walls contributes nonlocal topological degeneracy 2ND-1, causing a low-temperature peak in the heat capacity. We implement a nonperturbative method to bootstrap generic topological 1 +1 D domain walls (two-surface defects) applicable to any 2 +1 D non-Abelian topological order. We also identify potentially relevant spin topological quantum field theories (TQFTs) for various ν =5 /2 FQH states in terms of fermionic version of U (1) ±8 Chern-Simons theory ×Z8 -class TQFTs.

Literature survey on phase composition of hardened cement paste containing fly ash

International Nuclear Information System (INIS)

Otsuka, Taku; Yamamoto, Takeshi

2015-01-01

The purpose of this literature survey is to collect the knowledge on the effect of fly ash in hardened cement paste and the information about evaluation of physicochemical performance based on phase composition of hardened cement paste. The performance of hardened cement paste containing fly ash is affected by the property of fly ash, hydration of cement and pozzolanic reaction of fly ash. Some properties of fly ash such as density and chemical composition are reflected in phase composition, showing the progress of cement hydration and pozzolanic reaction. Therefore clarification of the relationship of phase composition and performance will lead to appropriate evaluation of the property of fly ash. The amount of pore, chemical shrinkage, pore solution, compressive strength, Young modulus and alkali silica reaction have relations to the phase composition of hardened cement paste. It is considered as future subject to clarify the relationship of phase composition and performance for various properties of fly ash. (author)

The Relationship of Disordered Eating Attitudes With Body Composition and Anthropometric Indices in Physical Education Students.

Science.gov (United States)

Rouzitalab, Tohid; Pourghassem Gargari, Bahram; Amirsasan, Ramin; Asghari Jafarabadi, Mohammad; Farsad Naeimi, Alireza; Sanoobar, Meisam

2015-11-01

Abnormal eating behavior, unhealthy weight control methods, and eating disordered symptoms have risen among college students. The aim of this study was to examine disordered eating attitudes and their relationship with anthropometric and body composition indices in physical education students in Tabriz, the capital of East Azerbaijan province, Iran. This cross-sectional study was conducted on 210 physical education students, 105 males and 105 females aged 18 to 25, who were selected by systematic random sampling from physical education faculty of Tabriz University in Tabriz, Iran, in 2013. Eating attitude test (EAT-26) was used for the assessment of disordered eating attitudes. In addition, anthropometric and body composition indices were assessed. About 10% of the studied subject had disturbed eating attitudes; significantly more males (15.4%) reported an EAT-26 ≥ 20 (disordered eating attitudes) than females (4.8%) (P EAT-26 score was positively correlated with weist perimeter (WP) (r = 0.21, P EAT-26 score was positively correlated with weight (r = 0.19, P eating attitude and healthy subjects, while in males there was no significant difference between the two groups regarding the anthropometric and body composition indices. Abnormal eating attitude was notable among physical education students in Tabriz, Iran. It seems that some anthropometric indices such as BMI and central obesity indices were related to the increase of disordered eating attitude.

Disordered ultracold atomic gases in optical lattices: A case study of Fermi-Bose mixtures

International Nuclear Information System (INIS)

Ahufinger, V.; Sanchez-Palencia, L.; Kantian, A.; Sanpera, A.; Lewenstein, M.

2005-01-01

We present a review of properties of ultracold atomic Fermi-Bose mixtures in inhomogeneous and random optical lattices. In the strong interacting limit and at very low temperatures, fermions form, together with bosons or bosonic holes, composite fermions. Composite fermions behave as a spinless interacting Fermi gas, and in the presence of local disorder they interact via random couplings and feel effective random local potential. This opens a wide variety of possibilities of realizing various kinds of ultracold quantum disordered systems. In this paper we review these possibilities, discuss the accessible quantum disordered phases, and methods for their detection. The discussed quantum phases include Fermi glasses, quantum spin glasses, 'dirty' superfluids, disordered metallic phases, and phases involving quantum percolation

The impact of handwriting difficulties on compositional quality in children with developmental coordination disorder

Science.gov (United States)

Barnett, Anna L; Wilmut, Kate; Plumb, Mandy S

2016-01-01

Introduction There is substantial evidence to support the relationship between transcription skills (handwriting and spelling) and compositional quality. For children with developmental coordination disorder, handwriting can be particularly challenging. While recent research has aimed to investigate their handwriting difficulties in more detail, the impact of transcription on their compositional quality has not previously been examined. The aim of this exploratory study was to examine compositional quality in children with developmental coordination disorder and to ascertain whether their transcription skills influence writing quality. Method Twenty-eight children with developmental coordination disorder participated in the study, with 28 typically developing age and gender matched controls. The children completed the ‘free-writing’ task from the detailed assessment of speed of handwriting tool, which was evaluated for compositional quality using the Wechsler objective language dimensions. Results The children with developmental coordination disorder performed significantly below their typically developing peers on five of the six Wechsler objective language dimensions items. They also had a higher percentage of misspelled words. Regression analyses indicated that the number of words produced per minute and the percentage of misspelled words explained 55% of the variance for compositional quality. Conclusion The handwriting difficulties so commonly reported in children with developmental coordination disorder have wider repercussions for the quality of written composition. PMID:27807392

Stochastic modelling of two-phase flows including phase change

International Nuclear Information System (INIS)

Hurisse, O.; Minier, J.P.

2011-01-01

Stochastic modelling has already been developed and applied for single-phase flows and incompressible two-phase flows. In this article, we propose an extension of this modelling approach to two-phase flows including phase change (e.g. for steam-water flows). Two aspects are emphasised: a stochastic model accounting for phase transition and a modelling constraint which arises from volume conservation. To illustrate the whole approach, some remarks are eventually proposed for two-fluid models. (authors)

Dual role of an ac driving force and the underlying two distinct order–disorder transitions in the vortex phase diagram of Ca3Ir4Sn13

International Nuclear Information System (INIS)

Kumar, Santosh; Singh, Ravi P.; Thamizhavel, A.; Tomy, C.V.; Grover, A.K.

2014-01-01

Highlights: • This work pertains to new findings related to a broad SMP anomaly. • Broad SMP prima facie encompasses two phase transformations in vortex matter. • We demarcated two phase boundaries pertaining to order–disorder transitions which have quasi first-order nature. - Abstract: We present distinct demarcation of the Bragg glass (BG) to multi-domain vortex glass (VG) transition line and the eventual amorphization of the VG phase in a weakly pinned single crystal of the superconducting compound Ca 3 Ir 4 Sn 13 on the basis of comprehension of the different yields about the second magnetization peak (SMP) anomaly in the dc magnetization and the corresponding anomalous feature in the ac susceptibility measurements. The shaking by a small ac magnetic field, inevitably present in the ac susceptibility measurements, is seen to result in contrasting responses in two different portions of the field-temperature (H, T) phase space of the multi-domain VG. In one of the portions, embracing the BG to VG transition across the onset of the SMP anomaly, the ac drive is surprisingly seen to assist the transformation of the well ordered BG phase to a lesser ordered VG phase. The BG phase exists as a superheated state over a small portion of the VG space and this attests to the first order nature of the BG to VG transition

Microstructural effects of ductile phase toughening of Nb-Nb silicide composites

International Nuclear Information System (INIS)

Lewandowski, J.J.; Dimiduk, D.; Kerr, W.; Menddiratta, M.G.

1988-01-01

In the Nb-Si system, the terminal Nb phase and Nb 5 Si 3 phase are virtually immiscible up to approximately 2033k. This system offers the potential of producing composites consisting of a ductile refractory metal phase and a strong intermetallic phase. In-situ composites containing different volume fractions of the ductile Nb phase were produced via vacuum arc-casting. Microhardness testing as well as smooth bend bar testing was conducted at temperatures ranging from 298k to 1673k in an attempt to determine microstructural effects on the yield strength and smooth bar fracture strength. Notched bend specimens were similarly tested to determine the effects of the ductile phase (i.e. Nb) on enhancing the notched bend toughness. It is shown that Nb phase often behaves in a ductile manner during testing, thereby toughening the in-situ composite. The mechanism of toughening appears to be due to crack bridging

Synthesis and characterization of nanostructured powders of hydroxyapatite and of three-calcium {beta} phosphate: elaboration of two phase compositions for application in the orthopedics and traumatology; Sintese e caracterizacao de pos nanoestruturados de hidroxiapatita e de fosfato tricalcico {beta}: elaboracao de composicoes bifasicas para aplicacoes na ortopedia e traumatologia

Energy Technology Data Exchange (ETDEWEB)

Dalmonico, G.M.L.; Pinheiro, D.M.; Camargo, N.H.A.; Orzechowki, L.G.; Goncalves, A.F.; Melnik, V.; Jesus, J.; Gemelli, E. [Universidade do Estado de Santa Catarina (UDESC), Joinville, SC (Brazil). Centro de Ciencias Tecnologicas], e-mail: gidalmonico@gmail.com

2010-07-01

This paper synthesized nano structured hydroxyapatite and three calcium {beta} phosphate, for elaboration of two phase compositions of HA/TCP in the concentration in volume of 80% HA/20% TCP-{beta}, 60% HA/40% TCP-{beta} and 50% HA/50% TCP-{beta}. For phase mixing realization, the method of mechanical fragmentation by attritor mill were used. The material recovered from the process of mechanical fragmentation was dried in rotate evaporator, supplying the two phase compositions. The preliminary studies shown the obtention of nano metric powders and a good phase dispersions inside the two phase compositions. (author)

Creep of Two-Phase Microstructures for Microelectronic Applications

Energy Technology Data Exchange (ETDEWEB)

Reynolds, Heidi Linch [Univ. of California, Berkeley, CA (United States)

1998-12-01

The mechanical properties of low-melting temperature alloys are highly influenced by their creep behavior. This study investigates the dominant mechanisms that control creep behavior of two-phase, low-melting temperature alloys as a function of microstructure. The alloy systems selected for study were In-Ag and Sn-Bi because their eutectic compositions represent distinctly different microstructure.” The In-Ag eutectic contains a discontinuous phase while the Sn-Bi eutectic consists of two continuous phases. In addition, this work generates useful engineering data on Pb-free alloys with a joint specimen geometry that simulates microstructure found in microelectronic applications. The use of joint test specimens allows for observations regarding the practical attainability of superplastic microstructure in real solder joints by varying the cooling rate. Steady-state creep properties of In-Ag eutectic, Sn-Bi eutectic, Sn-xBi solid-solution and pure Bi joints have been measured using constant load tests at temperatures ranging from O°C to 90°C. Constitutive equations are derived to describe the steady-state creep behavior for In-Ageutectic solder joints and Sn-xBi solid-solution joints. The data are well represented by an equation of the form proposed by Dom: a power-law equation applies to each independent creep mechanism. Rate-controlling creep mechanisms, as a function of applied shear stress, test temperature, and joint microstructure, are discussed. Literature data on the steady-state creep properties of Sn-Bi eutectic are reviewed and compared with the Sn-xBi solid-solution and pure Bi joint data measured in the current study. The role of constituent phases in controlling eutectic creep behavior is discussed for both alloy systems. In general, for continuous, two-phase microstructure, where each phase exhibits significantly different creep behavior, the harder or more creep resistant phase will dominate the creep behavior in a lamellar microstructure. If a

Tethered Nanoparticle–Polymer Composites: Phase Stability and Curvature

KAUST Repository

Srivastava, Samanvaya

2012-04-17

Phase behavior of poly(ethylene glycol) (PEG) tethered silica nanoparticles dispersed in PEG hosts is investigated using small-angle X-ray scattering. Phase separation in dispersions of densely grafted nanoparticles is found to display strikingly different small-angle X-ray scattering signatures in comparison to phase-separated composites comprised of bare or sparsely grafted nanoparticles. A general diagram for the dispersion state and phase stability of polymer tethered nanoparticle-polymer composites incorporating results from this as well as various other contemporary studies is presented. We show that in the range of moderate to high grafting densities the dispersion state of nanoparticles in composites is largely insensitive to the grafting density of the tethered chains and chemistry of the polymer host. Instead, the ratio of the particle diameter to the size of the tethered chain and the ratio of the molecular weights of the host and tethered polymer chains (P/N) are shown to play a dominant role. Additionally, we find that well-functionalized nanoparticles form stable dispersions in their polymer host beyond the P/N limit that demarcates the wetting/dewetting transition in polymer brushes on flat substrates interacting with polymer melts. A general strategy for achieving uniform nanoparticle dispersion in polymers is proposed. © 2012 American Chemical Society.

Strongly correlated Fermi-Bose mixtures in disordered optical lattices

International Nuclear Information System (INIS)

Sanchez-Palencia, L; Ahufinger, V; Kantian, A; Zakrzewski, J; Sanpera, A; Lewenstein, M

2006-01-01

We investigate theoretically the low-temperature physics of a two-component ultracold mixture of bosons and fermions in disordered optical lattices. We focus on the strongly correlated regime. We show that, under specific conditions, composite fermions, made of one fermion plus one bosonic hole, form. The composite picture is used to derive an effective Hamiltonian whose parameters can be controlled via the boson-boson and the boson-fermion interactions, the tunnelling terms and the inhomogeneities. We finally investigate the quantum phase diagram of the composite fermions and show that it corresponds to the formation of Fermi glasses, spin glasses and quantum percolation regimes

Strongly correlated Fermi-Bose mixtures in disordered optical lattices

Energy Technology Data Exchange (ETDEWEB)

Sanchez-Palencia, L [Laboratoire Charles Fabry de l' Institut d' Optique, CNRS and Universite Paris-Sud XI, Bat 503, Centre scientifique, F-91403 Orsay Cedex (France); Ahufinger, V [ICREA and Grup d' optica, Departament de FIsica, Universitat Autonoma de Barcelona, E-08193 Belaterra (Barcelona) (Spain); Kantian, A [Institut fuer Theoretische Physik, Universitaet Innsbruck, A-6020 Innsbruck (Austria); Zakrzewski, J [Instytut Fizyki imienia Mariana Smoluchowskiego i Centrum Badan Ukladow Zlozonych imienia Marka Kaca, Uniwersytet Jagiellonski, ulica Reymonta 4, PL-30-059 Krakow (Poland); Sanpera, A [ICREA and Grup de FIsica Teorica, Departament de FIsica, Universitat Autonoma de Barcelona, E-08193 Belaterra (Barcelona) (Spain); Lewenstein, M [ICREA and ICFO-Institut de Ciencies Fotoniques, Parc Mediterrani de la TecnologIa, E-08860 Castelldefels (Barcelona) (Spain); Institut fuer Theoretische Physik, Universitaet Hannover, D-30167 Hannover (Germany)

2006-05-28

We investigate theoretically the low-temperature physics of a two-component ultracold mixture of bosons and fermions in disordered optical lattices. We focus on the strongly correlated regime. We show that, under specific conditions, composite fermions, made of one fermion plus one bosonic hole, form. The composite picture is used to derive an effective Hamiltonian whose parameters can be controlled via the boson-boson and the boson-fermion interactions, the tunnelling terms and the inhomogeneities. We finally investigate the quantum phase diagram of the composite fermions and show that it corresponds to the formation of Fermi glasses, spin glasses and quantum percolation regimes.

Swift heavy ion irradiation induced phase transformation in undoped and niobium doped titanium dioxide composite thin films

Energy Technology Data Exchange (ETDEWEB)

Gautam, Subodh K., E-mail: subodhkgtm@gmail.com [Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110 067 (India); Chettah, Abdelhak [LGMM Laboratory, Université 20 Août 1955-Skikda, BP 26, 21000 Skikda (Algeria); Singh, R.G. [Department of Physics, Bhagini Nivedita College, Delhi University, Delhi 110043 (India); Ojha, Sunil; Singh, Fouran [Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110 067 (India)

2016-07-15

Study reports the effect of swift heavy ion (SHI) irradiation induced phase transformation in undoped and Niobium doped anatase TiO{sub 2} composite thin films. Investigations were carried out at different densities of electronic excitations (EEs) using 120 MeV Ag and 130 MeV Ni ions irradiations. Films were initially annealed at 900 °C and results revealed that undoped films were highly stable in anatase phase, while the Nb doped films showed the composite nature with the weak presence of Niobium penta-oxide (Nb{sub 2}O{sub 5}) phase. The effect at low density of EEs in undoped film show partial anatase to rutile phase transformation; however doped film shows only further growth of Nb{sub 2}O{sub 5} phase beside the anatase to rutile phase transformation. At higher density of EEs induced by Ag ions, registered continuous ion track of ∼3 nm in lattice which leads to nano-crystallization followed by decomposition/amorphization of rutile TiO{sub 2} and Nb{sub 2}O{sub 5} phases in undoped and doped films, respectively. However, Ni ions are only induced discontinuous sequence of ion tracks with creation of damage and disorder and do not show amorphization in the lattice. The in-elastic thermal spike calculations were carried out for anatase TiO{sub 2} phase to understand the effect of EEs on anatase to rutile phase transformation followed by amorphization in NTO films in terms of continuous and discontinuous track formation by SHI irradiation.

Parkinsonian syndromes presenting with circadian rhythm sleep disorder- advanced sleep-phase type.

Science.gov (United States)

Shukla, Garima; Kaul, Bhavna; Gupta, Anupama; Goyal, Vinay; Behari, Madhuri

2015-01-01

Circadian rhythm sleep disorder-advanced sleep-phase type is a relatively uncommon disorder, mostly seen among the elderly population. Impaired circadian rhythms have been reported in neurodegenerative conditions; however, there are no reports of any circadian rhythm sleep disorder among patients with Parkinsonian syndromes. We report two patients who presented with this circadian rhythm disorder, and were then diagnosed with a Parkinsonian syndrome. The cases. A 65-year-old retired man presented with history of abrupt change in sleep schedules, sleeping around 6.30-7 p.m. and waking up around 3-4 a.m. for the last 2 months. On detailed examination, the patient was observed to have symmetrical bradykinesia and cogwheel rigidity of limbs. A diagnosis of multiple system atrophy was made, supported by MRI findings and evidence of autonomic dysfunction. Symptoms of change in sleep-wake cycles resolved over the next 1 year, while the patient was treated with dopaminergic therapy. A 47-year-old man, who was being evaluated for presurgical investigation for refractory temporal lobe epilepsy, presented with complaints suggestive of dysarthria, bradykinesia of limbs and frequent falls for 5 months. Simultaneously, he began to sleep around 7 p.m. and wake up at about 2-3 a.m. Examination revealed severe axial rigidity, restricted vertical gaze and bradykinesia of limbs. A diagnosis of progressive supranuclear palsy was made. This is the first report of Parkinson's plus syndromes presenting with a circadian rhythm sleep disorder-advanced sleep-phase type. More prospective assessment for circadian sleep disorders may introduce useful insights into similar associations. Copyright 2015, NMJI.

Investigation of Power Losses of Two-Stage Two-Phase Converter with Two-Phase Motor

Directory of Open Access Journals (Sweden)

Michal Prazenica

2011-01-01

Full Text Available The paper deals with determination of losses of two-stage power electronic system with two-phase variable orthogonal output. The simulation is focused on the investigation of losses in the converter during one period in steady-state operation. Modeling and simulation of two matrix converters with R-L load is shown in the paper. The simulation results confirm a very good time-waveform of the phase current and the system seems to be suitable for low-cost application in automotive/aerospace industries and in application with high frequency voltage sources.

Microencapsulated Phase Change Composite Materials for Energy Efficient Buildings

Science.gov (United States)

Thiele, Alexander

This study aims to elucidate how phase change material (PCM)-composite materials can be leveraged to reduce the energy consumption of buildings and to provide cost savings to ratepayers. Phase change materials (PCMs) can store thermal energy in the form of latent heat when subjected to temperatures exceeding their melting point by undergoing a phase transition from solid to liquid state. Reversibly, PCMs can release this thermal energy when the system temperature falls below their solidification point. The goal in implementing composite PCM walls is to significantly reduce and time-shift the maximum thermal load on the building in order to reduce and smooth out the electricity demand for heating and cooling. This Ph.D. thesis aims to develop a set of thermal design methods and tools for exploring the use of PCM-composite building envelopes and for providing design rules for their practical implementation. First, detailed numerical simulations were used to show that the effective thermal conductivity of core-shell-matrix composites depended only on the volume fraction and thermal conductivity of the constituent materials. The effective medium approximation reported by Felske (2004) was in very good agreement with numerical predictions of the effective thermal conductivity. Second, a carefully validated transient thermal model was used to simulate microencapsulated PCM-composite walls subjected to diurnal or annual outdoor temperature and solar radiation flux. It was established that adding microencapsulated PCM to concrete walls both substantially reduced and delayed the thermal load on the building. Several design rules were established, most notably, (i) increasing the volume fraction of microencapsulated PCM within the wall increases the energy savings but at the potential expense of mechanical properties [1], (ii) the phase change temperature leading to the maximum energy and cost savings should equal the desired indoor temperature regardless of the climate

Thermophysical properties estimation of paraffin/graphite composite phase change material using an inverse method

International Nuclear Information System (INIS)

Lachheb, Mohamed; Karkri, Mustapha; Albouchi, Fethi; Mzali, Foued; Nasrallah, Sassi Ben

2014-01-01

Highlights: • Preparation of paraffin/graphite composites by uni-axial compression technique. • Measurement of thermophysical properties of paraffin/graphite using the periodic method. • Measurement of the experimental densities of paraffin/graphite composites. • Prediction of the effective thermal conductivity using analytical models. - Abstract: In this paper, two types of graphite were combined with paraffin in an attempt to improve thermal conductivity of paraffin phase change material (PCM): Synthetic graphite (Timrex SFG75) and graphite waste obtained from damaged Tubular graphite Heat Exchangers. These paraffin/graphite phase change material (PCM) composites are prepared by the cold uniaxial compression technique and the thermophysical properties were estimated using a periodic temperature method and an inverse technique. Results showed that the thermal conductivity and thermal diffusivity are greatly influenced by the graphite addition

Design and Preparation of Carbon Based Composite Phase Change Material for Energy Piles.

Science.gov (United States)

Yang, Haibin; Memon, Shazim Ali; Bao, Xiaohua; Cui, Hongzhi; Li, Dongxu

2017-04-07

Energy piles-A fairly new renewable energy concept-Use a ground heat exchanger (GHE) in the foundation piles to supply heating and cooling loads to the supported building. Applying phase change materials (PCMs) to piles can help in maintaining a stable temperature within the piles and can then influence the axial load acting on the piles. In this study, two kinds of carbon-based composite PCMs (expanded graphite-based PCM and graphite nanoplatelet-based PCM) were prepared by vacuum impregnation for potential application in energy piles. Thereafter, a systematic study was performed and different characterization tests were carried out on two composite PCMs. The composite PCMs retained up to 93.1% of paraffin and were chemically compatible, thermally stable and reliable. The latent heat of the composite PCM was up to 152.8 J/g while the compressive strength of cement paste containing 10 wt % GNP-PCM was found to be 37 MPa. Hence, the developed composite PCM has potential for thermal energy storage applications.

Design and Preparation of Carbon Based Composite Phase Change Material for Energy Piles

Science.gov (United States)

Yang, Haibin; Memon, Shazim Ali; Bao, Xiaohua; Cui, Hongzhi; Li, Dongxu

2017-01-01

Energy piles—A fairly new renewable energy concept—Use a ground heat exchanger (GHE) in the foundation piles to supply heating and cooling loads to the supported building. Applying phase change materials (PCMs) to piles can help in maintaining a stable temperature within the piles and can then influence the axial load acting on the piles. In this study, two kinds of carbon-based composite PCMs (expanded graphite-based PCM and graphite nanoplatelet-based PCM) were prepared by vacuum impregnation for potential application in energy piles. Thereafter, a systematic study was performed and different characterization tests were carried out on two composite PCMs. The composite PCMs retained up to 93.1% of paraffin and were chemically compatible, thermally stable and reliable. The latent heat of the composite PCM was up to 152.8 J/g while the compressive strength of cement paste containing 10 wt % GNP-PCM was found to be 37 MPa. Hence, the developed composite PCM has potential for thermal energy storage applications. PMID:28772752

Identification of sigma and OMEGA phases in AA2009/SiC composites

Energy Technology Data Exchange (ETDEWEB)

Rodrigo, P., E-mail: pilar.rodrigo@urjc.e [Departamento de Ciencia e Ingenieria de Materiales, Escuela Superior de Ciencias Experimentales y Tecnologia, Universidad Rey Juan Carlos, c/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Poza, P.; Utrilla, M.V.; Urena, A. [Departamento de Ciencia e Ingenieria de Materiales, Escuela Superior de Ciencias Experimentales y Tecnologia, Universidad Rey Juan Carlos, c/Tulipan s/n, 28933 Mostoles, Madrid (Spain)

2009-08-12

The microstructure evolution during ageing treatment at 170 and 190 deg. C of AA2009/SiC composites, reinforced with 15 vol.% particulates and whiskers, was studied by transmission electron microscopy. Besides theta' and S' phases, the typical hardening precipitates on Al-Cu-Mg alloys, it was found the presence of OMEGA and sigma (Al{sub 5}Cu{sub 6}Mg{sub 2}) phases in the matrix. sigma phase was only found in the matrix of particulate composite, while OMEGA phase appeared in both. This phase has not been previously observed in Al matrix composites based on conventional Al-Cu-Mg alloys.

Study on paraffin/expanded graphite composite phase change thermal energy storage material

International Nuclear Information System (INIS)

Zhang Zhengguo; Fang Xiaoming

2006-01-01

A paraffin/expanded graphite composite phase change thermal energy storage material was prepared by absorbing the paraffin into an expanded graphite that has an excellent absorbability. In such a composite, the paraffin serves as a latent heat storage material and the expanded graphite acts as the supporting material, which prevents leakage of the melted paraffin from its porous structure due to the capillary and surface tension forces. The inherent structure of the expanded graphite did not change in the composite material. The solid-liquid phase change temperature of the composite PCM was the same as that of the paraffin, and the latent heat of the paraffin/expanded graphite composite material was equivalent to the calculated value based on the mass ratio of the paraffin in the composite. The heat transfer rate of the paraffin/expanded graphite composite was obviously higher than that of the paraffin due to the combination with the expanded graphite that had a high thermal conductivity. The prepared paraffin/expanded graphite composite phase change material had a large thermal storage capacity and improved thermal conductivity and did not experience liquid leakage during its solid-liquid phase change

Thermal conductivity of solid cyclohexane in orientationally ordered and disordered phases

International Nuclear Information System (INIS)

Konstantinov, V. A.; Revyakin, V. P.; Sagan, V. V.; Pursky, O. I.; Sysoev, V. M.

2011-01-01

Thermal conductivity Λ P of solid cyclohexane is measured at a pressure P = 0.1 MPa in the temperature range from 80 K to the melting point, which covers the ranges of low-temperature orientationally ordered phase II and high-temperature orientationally disordered phase I. Thermal conductivity Λ V is measured at a constant volume in orientationally disordered phase I. The thermal conductivity measured at atmospheric pressure decreases with increasing temperature as Λ P ∝ T −1.15 in phase II, whereas Λ P ∝ T −0.3 in phase I. As temperature increases, isochoric thermal conductivity Λ V in phase I increases gradually. The experimental data are described in terms of a modified Debye model of thermal conductivity with allowance for heat transfer by both phonons and “diffuse” modes.

Disorder trapping by rapidly moving phase interface in an undercooled liquid

Science.gov (United States)

Galenko, Peter; Danilov, Denis; Nizovtseva, Irina; Reuther, Klemens; Rettenmayr, Markus

2017-08-01

Non-equilibrium phenomena such as the disappearance of solute drag, the origin of solute trapping and evolution of disorder trapping occur during fast transformations with originating metastable phases [D.M. Herlach, P.K. Galenko, D. Holland-Moritz, Metastable solids from undrercooled melts (Elsevier, Amsterdam, 2007)]. In the present work, a theoretical investigation of disorder trapping by a rapidly moving phase interface is presented. Using a model of fast phase transformations, a system of governing equations for the diffusion of atoms, and the evolution of both long-range order parameter and phase field variable is formulated. First numerical solutions are carried out for a congruently melting binary alloy system.

Cognitive impairment in the euthymic phase of affective disorder

DEFF Research Database (Denmark)

Kessing, L V

1998-01-01

BACKGROUND: A review of studies of cognition in the euthymic phase of unipolar and bipolar affective disorder reveals diverging results. METHODS: The study was designed as a controlled cohort study, with the Danish psychiatric case register of admissions used to identify patients and the Danish...... civil register to identify controls. Patients who were hospitalized between 19 and 25 years ago with an affective diagnosis and who at interviews fulfilled criteria for a primary affective unipolar or bipolar disorder, according to ICD-10, were compared with age- and gender-matched controls. Interviews...... and assessment of the cognitive function were made in the euthymic phase of the disorder. In all, 118 unipolar patients, 28 bipolar patients and 58 controls were included. Analyses were adjusted for differences in the level of education and for subclinical depressive and anxiety symptoms. RESULTS: Patients...

Home dim light melatonin onsets with measures of compliance in delayed sleep phase disorder.

Science.gov (United States)

Burgess, Helen J; Park, Margaret; Wyatt, James K; Fogg, Louis F

2016-06-01

The dim light melatonin onset (DLMO) assists with the diagnosis and treatment of circadian rhythm sleep disorders. Home DLMOs are attractive for cost savings and convenience, but can be confounded by home lighting and sample timing errors. We developed a home saliva collection kit with objective measures of light exposure and sample timing. We report on our first test of the kit in a clinical population. Thirty-two participants with delayed sleep phase disorder (DSPD; 17 women, aged 18-52 years) participated in two back-to-back home and laboratory phase assessments. Most participants (66%) received at least one 30-s epoch of light >50 lux during the home phase assessments, but for only 1.5% of the time. Most participants (56%) collected every saliva sample within 5 min of the scheduled time. Eighty-three per cent of home DLMOs were not affected by light or sampling errors. The home DLMOs occurred, on average, 10.2 min before the laboratory DLMOs, and were correlated highly with the laboratory DLMOs (r = 0.93, P light exposure and sample timing, can assist in identifying accurate home DLMOs. © 2016 European Sleep Research Society.

Vapor Compressor Driven Hybrid Two-Phase Loop, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — This Small Business Innovation Research Phase I project will demonstrate a vapor compressor driven hybrid two-phase loop technology. The hybrid two-phase loop...

High-velocity two-phase flow two-dimensional modeling

International Nuclear Information System (INIS)

Mathes, R.; Alemany, A.; Thilbault, J.P.

1995-01-01

The two-phase flow in the nozzle of a LMMHD (liquid metal magnetohydrodynamic) converter has been studied numerically and experimentally. A two-dimensional model for two-phase flow has been developed including the viscous terms (dragging and turbulence) and the interfacial mass, momentum and energy transfer between the phases. The numerical results were obtained by a finite volume method based on the SIMPLE algorithm. They have been verified by an experimental facility using air-water as a simulation pair and a phase Doppler particle analyzer for velocity and droplet size measurement. The numerical simulation of a lithium-cesium high-temperature pair showed that a nearly homogeneous and isothermal expansion of the two phases is possible with small pressure losses and high kinetic efficiencies. In the throat region a careful profiling is necessary to reduce the inertial effects on the liquid velocity field

Phase-Separated Polyaniline/Graphene Composite Electrodes for High-Rate Electrochemical Supercapacitors.

Science.gov (United States)

Wu, Jifeng; Zhang, Qin'e; Zhou, An'an; Huang, Zhifeng; Bai, Hua; Li, Lei

2016-12-01

Polyaniline/graphene hydrogel composites with a macroscopically phase-separated structure are prepared. The composites show high specific capacitance and excellent rate performance. Further investigation demonstrates that polyaniline inside the graphene hydrogel has low rate performance, thus a phase-separated structure, in which polyaniline is mainly outside the graphene hydrogel matrix, can enhance the rate performance of the composites. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Phase composition of yttrium-doped zirconia ceramics

Energy Technology Data Exchange (ETDEWEB)

Hennig, Christoph; Scheinost, Andreas C. [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Molecular Structures; Weiss, Stephan [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Surface Processes; Ikeda-Ohno, Atsushi [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Chemistry of the F-Elements; Gumeniuk, R. [Technische Univ. Bergakademie Freiberg (Germany). Inst. fuer Experimentelle Physik

2017-06-01

Ceramic material might be an alternative to borosilicate glass for the immobilization of nuclear waste. The crystallinity of ceramic material increases the corrosion resistance over several magnitudes in relation to amorphous glasses. The stability of such ceramics depend on several parameters, among them the crystal phase composition. A reliable quantitative phase analysis is necessary to correlate the macroscopic material properties with structure parameters. We performed a feasibility study based on yttrium-doped zirconia ceramics as analogue for trivalent actinides to ascertain that the nanosized crystal phases in zirconia ceramics can be reliably determined.

The structural phases and vibrational properties of Mo1-xWxTe2 alloys

Science.gov (United States)

Oliver, Sean M.; Beams, Ryan; Krylyuk, Sergiy; Kalish, Irina; Singh, Arunima K.; Bruma, Alina; Tavazza, Francesca; Joshi, Jaydeep; Stone, Iris R.; Stranick, Stephan J.; Davydov, Albert V.; Vora, Patrick M.

2017-12-01

The structural polymorphism in transition metal dichalcogenides (TMDs) provides exciting opportunities for developing advanced electronics. For example, MoTe2 crystallizes in the 2H semiconducting phase at ambient temperature and pressure, but transitions into the 1T‧ semimetallic phase at high temperatures. Alloying MoTe2 with WTe2 reduces the energy barrier between these two phases, while also allowing access to the T d Weyl semimetal phase. The \\text{M}{{\\text{o}}1-\\text{x}} WxTe2 alloy system is therefore promising for developing phase change memory technology. However, achieving this goal necessitates a detailed understanding of the phase composition in the MoTe2-WTe2 system. We combine polarization-resolved Raman spectroscopy with x-ray diffraction (XRD) and scanning transmission electron microscopy (STEM) to study bulk \\text{M}{{\\text{o}}1-\\text{x}} WxTe2 alloys over the full compositional range x from 0 to 1. We identify Raman and XRD signatures characteristic of the 2H, 1T‧, and T d structural phases that agree with density-functional theory (DFT) calculations, and use them to identify phase fields in the MoTe2-WTe2 system, including single-phase 2H, 1T‧, and T d regions, as well as a two-phase 1T‧  +  T d region. Disorder arising from compositional fluctuations in \\text{M}{{\\text{o}}1-\\text{x}} WxTe2 alloys breaks inversion and translational symmetry, leading to the activation of an infrared 1T‧-MoTe2 mode and the enhancement of a double-resonance Raman process in \\text{2H-M}{{\\text{o}}1-\\text{x}} WxTe2 alloys. Compositional fluctuations limit the phonon correlation length, which we estimate by fitting the observed asymmetric Raman lineshapes with a phonon confinement model. These observations reveal the important role of disorder in \\text{M}{{\\text{o}}1-\\text{x}} WxTe2 alloys, clarify the structural phase boundaries, and provide a foundation for future explorations of phase transitions and electronic phenomena in this

Pressure-induced decoupling of the order-disorder and displacive contributions to the phase transition in diguanidinium tetrachlorostannate

DEFF Research Database (Denmark)

Szafranski, M.; Ståhl, Kenny

2000-01-01

The crystals of diguanidinium tetrachlorostannate [C(NH2)(3)](2)(+).SnCl4-2, were studied by single-crystal x-ray diffraction at various temperatures and by calorimetric and dielectric measurements at ambient and high hydrostatic pressures. At room temperature the crystal structure is orthorhombic......) cations. At ambient pressure the crystals undergo two first-order phase transitions at 354.8 and 395.4 K. The former, between two orthorhombic phases (Pbca --> Cmca), is characterized by antiphase displacement of the double sheets along the b direction of the low-temperature unit cell which is coupled...... to dynamical disordering of G(2) and transformation of its hydrogen bonding scheme. At elevated pressures the coupling between the displacive and order-disorder contributions is modified and its breaking near a triple point at 180 MPa and 270 K results in a pressure-induced phase observed between Pbca and Cmca...

Coupling two-phase fluid flow with two-phase darcy flow in anisotropic porous media

KAUST Repository

Chen, J.

2014-06-03

This paper reports a numerical study of coupling two-phase fluid flow in a free fluid region with two-phase Darcy flow in a homogeneous and anisotropic porous medium region. The model consists of coupled Cahn-Hilliard and Navier-Stokes equations in the free fluid region and the two-phase Darcy law in the anisotropic porous medium region. A Robin-Robin domain decomposition method is used for the coupled Navier-Stokes and Darcy system with the generalized Beavers-Joseph-Saffman condition on the interface between the free flow and the porous media regions. Obtained results have shown the anisotropic properties effect on the velocity and pressure of the two-phase flow. 2014 Jie Chen et al.

Coupling Two-Phase Fluid Flow with Two-Phase Darcy Flow in Anisotropic Porous Media

Directory of Open Access Journals (Sweden)

Jie Chen

2014-06-01

Full Text Available This paper reports a numerical study of coupling two-phase fluid flow in a free fluid region with two-phase Darcy flow in a homogeneous and anisotropic porous medium region. The model consists of coupled Cahn-Hilliard and Navier-Stokes equations in the free fluid region and the two-phase Darcy law in the anisotropic porous medium region. A Robin-Robin domain decomposition method is used for the coupled Navier-Stokes and Darcy system with the generalized Beavers-Joseph-Saffman condition on the interface between the free flow and the porous media regions. Obtained results have shown the anisotropic properties effect on the velocity and pressure of the two-phase flow.

Rational design of stealthy hyperuniform two-phase media with tunable order

Science.gov (United States)

DiStasio, Robert A.; Zhang, Ge; Stillinger, Frank H.; Torquato, Salvatore

2018-02-01

Disordered stealthy hyperuniform materials are exotic amorphous states of matter that have attracted recent attention because of their novel structural characteristics (hidden order at large length scales) and physical properties, including desirable photonic and transport properties. It is therefore useful to devise algorithms that enable one to design a wide class of such amorphous configurations at will. In this paper, we present several algorithms enabling the systematic identification and generation of discrete (digitized) stealthy hyperuniform patterns with a tunable degree of order, paving the way towards the rational design of disordered materials endowed with novel thermodynamic and physical properties. To quantify the degree of order or disorder of the stealthy systems, we utilize the discrete version of the τ order metric, which accounts for the underlying spatial correlations that exist across all relevant length scales in a given digitized two-phase (or, equivalently, a two-spin state) system of interest. Our results impinge on a myriad of fields, ranging from physics, materials science and engineering, visual perception, and information theory to modern data science.

Novel Formulations of Phase Change Materials—Epoxy Composites for Thermal Energy Storage

Directory of Open Access Journals (Sweden)

Maria Elena Arce

2018-01-01

Full Text Available This research aimed to evaluate the thermal properties of new formulations of phase change materials (PCMs-epoxy composites, containing a thickening agent and a thermally conductive phase. The composite specimens produced consisted of composites fabricated using (a inorganic PCMs (hydrated salts, epoxy resins and aluminum particulates or (b organic PCM (paraffin, epoxy resins, and copper particles. Differential Scanning Calorimetry (DSC was used to analyze the thermal behavior of the samples, while hardness measurements were used to determine changes in mechanical properties at diverse PCM and conductive phase loading values. The results indicate that the epoxy matrix can act as a container for the PCM phase without hindering the heat-absorbing behavior of the PCMs employed. Organic PCMs presented reversible phase transformations over multiple cycles, an advantage that was lacking in their inorganic counterparts. The enthalpy of the organic PCM-epoxy specimens increased linearly with the PCM content in the matrix. The use of thickening agents prevented phase segregation issues and allowed the fabrication of specimens containing up to 40% PCM, a loading significantly higher than others reported. The conductive phase seemed to improve the heat transfer and the mechanical properties of the composites when present in low percentages (<10 wt %; however, given its mass, the enthalpy detected in the composites was reduced as their loading further increased. The conductive phase combination (PCM + epoxy resin + hardener + thickening agent presents great potential as a heat-absorbing material at the temperatures employed.

Preparation and thermal energy storage properties of paraffin/calcined diatomite composites as form-stable phase change materials

International Nuclear Information System (INIS)

Sun, Zhiming; Zhang, Yuzhong; Zheng, Shuilin; Park, Yuri; Frost, Ray L.

2013-01-01

Highlights: ► Composite phase change material (PCM) was prepared by blending composite paraffin and calcined diatomite. ► The optimum mixed proportion was obtained through differential scanning calorimetry. ► Thermal energy storage properties of the composite PCMs were determined by DSC. ► Thermal cycling test showed that the prepared PCMs are thermally reliable and chemically stable. - Abstract: A composite paraffin-based phase change material (PCM) was prepared by blending composite paraffin and calcined diatomite through the fusion adsorption method. In this study, raw diatomite was purified by thermal treatment in order to improve the adsorption capacity of diatomite, which acted as a carrier material to prepare shape-stabilized PCMs. Two forms of paraffin (paraffin waxes and liquid paraffin) with different melting points were blended together by the fusion method, and the optimum mixed proportion with a suitable phase-transition temperature was obtained through differential scanning calorimetry (DSC) analysis. Then the prepared composite paraffin was adsorbed in calcined diatomite. The prepared paraffin/calcined diatomite composites were characterized by the scanning electron microscope (SEM) and Fourier transformation infrared (FT-IR) analysis techniques. Thermal energy storage properties of the composite PCMs were determined by DSC method. DSC results showed that there was an optimum adsorption ratio between composite paraffin and calcined diatomite and the phase-transition temperature and the latent heat of the composite PCMs were 33.04 °C and 89.54 J/g, respectively. Thermal cycling test of composite PCMs showed that the prepared material is thermally reliable and chemically stable. The obtained paraffin/calcined diatomite composites have proper latent heat and melting temperatures, and show practical significance and good potential application value

Preparation and thermal energy storage properties of paraffin/calcined diatomite composites as form-stable phase change materials

Energy Technology Data Exchange (ETDEWEB)

Sun, Zhiming [School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083 (China); Chemistry Discipline, Faculty of Science and Technology, Queensland University of Technology, 2 George Street, GPO Box 2434, Brisbane, Queensland 4001 (Australia); Zhang, Yuzhong [School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083 (China); Zheng, Shuilin, E-mail: shuilinzh@yahoo.com.cn [School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083 (China); Park, Yuri [Chemistry Discipline, Faculty of Science and Technology, Queensland University of Technology, 2 George Street, GPO Box 2434, Brisbane, Queensland 4001 (Australia); Frost, Ray L., E-mail: r.frost@qut.edu.au [Chemistry Discipline, Faculty of Science and Technology, Queensland University of Technology, 2 George Street, GPO Box 2434, Brisbane, Queensland 4001 (Australia)

2013-04-20

Highlights: ► Composite phase change material (PCM) was prepared by blending composite paraffin and calcined diatomite. ► The optimum mixed proportion was obtained through differential scanning calorimetry. ► Thermal energy storage properties of the composite PCMs were determined by DSC. ► Thermal cycling test showed that the prepared PCMs are thermally reliable and chemically stable. - Abstract: A composite paraffin-based phase change material (PCM) was prepared by blending composite paraffin and calcined diatomite through the fusion adsorption method. In this study, raw diatomite was purified by thermal treatment in order to improve the adsorption capacity of diatomite, which acted as a carrier material to prepare shape-stabilized PCMs. Two forms of paraffin (paraffin waxes and liquid paraffin) with different melting points were blended together by the fusion method, and the optimum mixed proportion with a suitable phase-transition temperature was obtained through differential scanning calorimetry (DSC) analysis. Then the prepared composite paraffin was adsorbed in calcined diatomite. The prepared paraffin/calcined diatomite composites were characterized by the scanning electron microscope (SEM) and Fourier transformation infrared (FT-IR) analysis techniques. Thermal energy storage properties of the composite PCMs were determined by DSC method. DSC results showed that there was an optimum adsorption ratio between composite paraffin and calcined diatomite and the phase-transition temperature and the latent heat of the composite PCMs were 33.04 °C and 89.54 J/g, respectively. Thermal cycling test of composite PCMs showed that the prepared material is thermally reliable and chemically stable. The obtained paraffin/calcined diatomite composites have proper latent heat and melting temperatures, and show practical significance and good potential application value.

Two-step nucleation of the g-phase in a Ti-45Al-18Nb alloy

Energy Technology Data Exchange (ETDEWEB)

Goyel, Sonalika [University of Florida, Gainesville; Rios, Orlando [ORNL; Kesler, Michael [University of Florida, Gainesville; Ebrahimi, Fereshteh [University of Florida, Gainesville

2010-01-01

Phase transformations in a high Nb TieAleNb alloy (Ti-45Al-18Nb at%) upon cooling were studied. This alloy solidifies as single b-phase, which upon cooling under equilibrium conditions, is expected to follow the b / b g / b g s / g s transformation path. The DTA analysis confirmed two transformation events as manifested by two peaks upon cooling. However, compositional and structural characterization of samples with different heat treatment schedules, including slow cooling (9 C/min), revealed that the s-phase did not form upon cooling. The two DTA peaks observed in the cooling cycle of the alloy are proven to be associated with the two-stage formation of the g-phase. Detailed microstructural evaluations showed that the g-phase nucleated in two discrete stages and exhibited two different morphologies. The absence of the s-phase is believed to be due to the lack of enough driving force at high temperatures. The aging of a fast cooled sample, yielding an equilibrated microstructure, substantiated the presence of the s-phase.

History independence of steady state in simultaneous two-phase flow through two-dimensional porous media.

Science.gov (United States)

Erpelding, Marion; Sinha, Santanu; Tallakstad, Ken Tore; Hansen, Alex; Flekkøy, Eirik Grude; Måløy, Knut Jørgen

2013-11-01

It is well known that the transient behavior during drainage or imbibition in multiphase flow in porous media strongly depends on the history and initial condition of the system. However, when the steady-state regime is reached and both drainage and imbibition take place at the pore level, the influence of the evolution history and initial preparation is an open question. Here, we present an extensive experimental and numerical work investigating the history dependence of simultaneous steady-state two-phase flow through porous media. Our experimental system consists of a Hele-Shaw cell filled with glass beads which we model numerically by a network of disordered pores transporting two immiscible fluids. From measurements of global pressure evolution, histograms of saturation, and cluster-size distributions, we find that when both phases are flowing through the porous medium, the steady state does not depend on the initial preparation of the system or on the way it has been reached.

Relaxation processes in a lower disorder order transition diblock copolymer

International Nuclear Information System (INIS)

Sanz, Alejandro; Ezquerra, Tiberio A.; Nogales, Aurora; Hernández, Rebeca; Sprung, Michael

2015-01-01

The dynamics of lower disorder-order temperature diblock copolymer leading to phase separation has been observed by X ray photon correlation spectroscopy. Two different modes have been characterized. A non-diffusive mode appears at temperatures below the disorder to order transition, which can be associated to compositional fluctuations, that becomes slower as the interaction parameter increases, in a similar way to the one observed for diblock copolymers exhibiting phase separation upon cooling. At temperatures above the disorder to order transition T ODT , the dynamics becomes diffusive, indicating that after phase separation in Lower Disorder-Order Transition (LDOT) diblock copolymers, the diffusion of chain segments across the interface is the governing dynamics. As the segregation is stronger, the diffusive process becomes slower. Both observed modes have been predicted by the theory describing upper order-disorder transition systems, assuming incompressibility. However, the present results indicate that the existence of these two modes is more universal as they are present also in compressible diblock copolymers exhibiting a lower disorder-order transition. No such a theory describing the dynamics in LDOT block copolymers is available, and these experimental results may offer some hints to understanding the dynamics in these systems. The dynamics has also been studied in the ordered state, and for the present system, the non-diffusive mode disappears and only a diffusive mode is observed. This mode is related to the transport of segment in the interphase, due to the weak segregation on this system

Design and Preparation of Carbon Based Composite Phase Change Material for Energy Piles

Directory of Open Access Journals (Sweden)

Haibin Yang

2017-04-01

Full Text Available Energy piles—A fairly new renewable energy concept—Use a ground heat exchanger (GHE in the foundation piles to supply heating and cooling loads to the supported building. Applying phase change materials (PCMs to piles can help in maintaining a stable temperature within the piles and can then influence the axial load acting on the piles. In this study, two kinds of carbon-based composite PCMs (expanded graphite-based PCM and graphite nanoplatelet-based PCM were prepared by vacuum impregnation for potential application in energy piles. Thereafter, a systematic study was performed and different characterization tests were carried out on two composite PCMs. The composite PCMs retained up to 93.1% of paraffin and were chemically compatible, thermally stable and reliable. The latent heat of the composite PCM was up to 152.8 J/g while the compressive strength of cement paste containing 10 wt % GNP-PCM was found to be 37 MPa. Hence, the developed composite PCM has potential for thermal energy storage applications.

Stratified steady and unsteady two-phase flows between two parallel plates

International Nuclear Information System (INIS)

Sim, Woo Gun

2006-01-01

To understand fluid dynamic forces acting on a structure subjected to two-phase flow, it is essential to get detailed information about the characteristics of two-phase flow. Stratified steady and unsteady two-phase flows between two parallel plates have been studied to investigate the general characteristics of the flow related to flow-induced vibration. Based on the spectral collocation method, a numerical approach has been developed for the unsteady two-phase flow. The method is validated by comparing numerical result to analytical one given for a simple harmonic two-phase flow. The flow parameters for the steady two-phase flow, such as void fraction and two-phase frictional multiplier, are evaluated. The dynamic characteristics of the unsteady two-phase flow, including the void fraction effect on the complex unsteady pressure, are illustrated

Phase spectral composition of wind generated ocean surface waves

Digital Repository Service at National Institute of Oceanography (India)

Varkey, M.J.

A study of the composition of the phase spectra of wind generated ocean surface waves is carried out using wave records collected employing a ship borne wave recorder. It is found that the raw phase spectral estimates could be fitted by the Uniform...

Two-phase mixed media dielectric with macro dielectric beads for enhancing resistivity and breakdown strength

Science.gov (United States)

Falabella, Steven; Meyer, Glenn A; Tang, Vincent; Guethlein, Gary

2014-06-10

A two-phase mixed media insulator having a dielectric fluid filling the interstices between macro-sized dielectric beads packed into a confined volume, so that the packed dielectric beads inhibit electro-hydrodynamically driven current flows of the dielectric liquid and thereby increase the resistivity and breakdown strength of the two-phase insulator over the dielectric liquid alone. In addition, an electrical apparatus incorporates the two-phase mixed media insulator to insulate between electrical components of different electrical potentials. And a method of electrically insulating between electrical components of different electrical potentials fills a confined volume between the electrical components with the two-phase dielectric composite, so that the macro dielectric beads are packed in the confined volume and interstices formed between the macro dielectric beads are filled with the dielectric liquid.

Giant Andreev Backscattering through a Quantum Point Contact Coupled via a Disordered Two-Dimensional Electron Gas to Superconductors

International Nuclear Information System (INIS)

den Hartog, S.G.; van Wees, B.J.; Klapwijk, T.M.; Nazarov, Y.V.; Borghs, G.

1997-01-01

We have investigated the superconducting-phase-modulated reduction in the resistance of a ballistic quantum point contact (QPC) connected via a disordered two-dimensional electron gas (2DEG) to superconductors. We show that this reduction is caused by coherent Andreev backscattering of holes through the QPC, which increases monotonically by reducing the bias voltage to zero. In contrast, the magnitude of the phase-dependent resistance of the disordered 2DEG displays a nonmonotonic reentrant behavior versus bias voltage. copyright 1997 The American Physical Society

Novel Formulations of Phase Change Materials-Epoxy Composites for Thermal Energy Storage.

Science.gov (United States)

Arce, Maria Elena; Alvarez Feijoo, Miguel Angel; Suarez Garcia, Andres; Luhrs, Claudia C

2018-01-26

This research aimed to evaluate the thermal properties of new formulations of phase change materials (PCMs)-epoxy composites, containing a thickening agent and a thermally conductive phase. The composite specimens produced consisted of composites fabricated using (a) inorganic PCMs (hydrated salts), epoxy resins and aluminum particulates or (b) organic PCM (paraffin), epoxy resins, and copper particles. Differential Scanning Calorimetry (DSC) was used to analyze the thermal behavior of the samples, while hardness measurements were used to determine changes in mechanical properties at diverse PCM and conductive phase loading values. The results indicate that the epoxy matrix can act as a container for the PCM phase without hindering the heat-absorbing behavior of the PCMs employed. Organic PCMs presented reversible phase transformations over multiple cycles, an advantage that was lacking in their inorganic counterparts. The enthalpy of the organic PCM-epoxy specimens increased linearly with the PCM content in the matrix. The use of thickening agents prevented phase segregation issues and allowed the fabrication of specimens containing up to 40% PCM, a loading significantly higher than others reported. The conductive phase seemed to improve the heat transfer and the mechanical properties of the composites when present in low percentages (material at the temperatures employed.

Microfluidic Manufacturing of Polymeric Nanoparticles: Comparing Flow Control of Multiscale Structure in Single-Phase Staggered Herringbone and Two-Phase Reactors.

Science.gov (United States)

Xu, Zheqi; Lu, Changhai; Riordon, Jason; Sinton, David; Moffitt, Matthew G

2016-12-06

We compare the microfluidic manufacturing of polycaprolactone-block-poly(ethylene oxide) (PCL-b-PEO) nanoparticles (NPs) in a single-phase staggered herringbone (SHB) mixer and in a two-phase gas-liquid segmented mixer. NPs generated from two different copolymer compositions in both reactors and at three different flow rates, along with NPs generated using a conventional bulk method, are compared with respect to morphologies, dimensions, and internal crystallinities. Our work, the first direct comparison between alternate microfluidic NP synthesis methods, shows three key findings: (i) NP morphologies and dimensions produced in the bulk are different from those produced in a microfluidic mixer, whereas NP crystallinities produced in the bulk and in the SHB mixer are similar; (ii) NP morphologies, dimensions, and crystallinities produced in the single-phase SHB and two-phase mixers at the lowest flow rate are similar; and (iii) NP morphologies, dimensions, and crystallinities change with flow rate in the two-phase mixer but not in the single-phase SHB mixer. These findings provide new insights into the relative roles of mixing and shear in the formation and flow-directed processing of polymeric NPs in microfluidics, informing future reactor designs for manufacturing NPs of low polydispersity and controlled multiscale structure and function.

Structure, phases, and mechanical response of Ti-alloy bioactive glass composite coatings

Energy Technology Data Exchange (ETDEWEB)

Nelson, G.M.; Nychka, J.A. [Department of Chemical and Materials Engineering, University of Alberta, 7th Floor, Electrical and Computer Engineering Research Facility, Edmonton, Alberta T6G 2V4 (Canada); McDonald, A.G., E-mail: andre2@ualberta.ca [Department of Mechanical Engineering, University of Alberta, 4-9 Mechanical Engineering Building, Edmonton, Alberta T6G 2G8 (Canada)

2014-03-01

Porous titanium alloy-bioactive glass composite coatings were manufactured via the flame spray deposition process. The porous coatings, targeted for orthodontic and bone-fixation applications, were made from bioactive glass (45S5) powder blended with either commercially pure titanium (Cp-Ti) or Ti-6Al-4V alloy powder. Two sets of spray conditions, two metallic particle size distributions, and two glass particle size distributions were used for this study. Negative control coatings consisting of pure Ti-6Al-4V alloy or Cp-Ti were sprayed under both conditions. The as-sprayed coatings were characterized through quantitative optical cross-sectional metallography, X-ray diffraction (XRD), and ASTM Standard C633 tensile adhesion testing. Determination of the porosity and glassy phase distribution was achieved by using image analysis in accordance with ASTM Standard E2109. Theoretical thermodynamic and heat transfer modeling was conducted to explain experimental observations. Thermodynamic modeling was performed to estimate the flame temperature and chemical environment for each spray condition and a lumped capacitance heat transfer model was developed to estimate the temperatures attained by each particle. These models were used to establish trends among the choice of alloy, spray condition, and particle size distribution. The deposition parameters, alloy composition, and alteration of the feedstock powder size distribution had a significant effect on the coating microstructure, porosity, phases present, mechanical response, and theoretical particle temperatures that were attained. The most promising coatings were the Ti-6Al-4V-based composite coatings, which had bond strength of 20 ± 2 MPa (n = 5) and received reinforcement and strengthening from the inclusion of a glassy phase. It was shown that the use of the Ti-6Al-4V-bioactive glass composite coatings may be a superior choice due to the possible osteoproductivity from the bioactive glass, the potential ability to

Novel Formulations of Phase Change Materials—Epoxy Composites for Thermal Energy Storage

Science.gov (United States)

Alvarez Feijoo, Miguel Angel

2018-01-01

This research aimed to evaluate the thermal properties of new formulations of phase change materials (PCMs)-epoxy composites, containing a thickening agent and a thermally conductive phase. The composite specimens produced consisted of composites fabricated using (a) inorganic PCMs (hydrated salts), epoxy resins and aluminum particulates or (b) organic PCM (paraffin), epoxy resins, and copper particles. Differential Scanning Calorimetry (DSC) was used to analyze the thermal behavior of the samples, while hardness measurements were used to determine changes in mechanical properties at diverse PCM and conductive phase loading values. The results indicate that the epoxy matrix can act as a container for the PCM phase without hindering the heat-absorbing behavior of the PCMs employed. Organic PCMs presented reversible phase transformations over multiple cycles, an advantage that was lacking in their inorganic counterparts. The enthalpy of the organic PCM-epoxy specimens increased linearly with the PCM content in the matrix. The use of thickening agents prevented phase segregation issues and allowed the fabrication of specimens containing up to 40% PCM, a loading significantly higher than others reported. The conductive phase seemed to improve the heat transfer and the mechanical properties of the composites when present in low percentages (phase combination (PCM + epoxy resin + hardener + thickening agent) presents great potential as a heat-absorbing material at the temperatures employed. PMID:29373538

Nature of the interfaces between the constituent phases in the high entropy alloy CoCrCuFeNiAl

Energy Technology Data Exchange (ETDEWEB)

Welk, Brian A.; Williams, Robert E.A.; Viswanathan, Gopal B. [Center for the Accelerated Maturation of Materials, Department of Materials Science and Engineering, The Ohio State University, 1305 Kinnear Road, Columbus, OH 43212 (United States); Gibson, Mark A. [CSIRO, Private Bag 33, Clayton, Victoria 3169 (Australia); Liaw, Peter K. [Department of Materials Science and Engineering, The University of Tennessee, 414 Ferris Hall, 1508 Middle Drive, Knoxville, TN 37996 (United States); Fraser, Hamish L., E-mail: fraser.3@osu.edu [Center for the Accelerated Maturation of Materials, Department of Materials Science and Engineering, The Ohio State University, 1305 Kinnear Road, Columbus, OH 43212 (United States)

2013-11-15

The interfaces between the phase separated regions in the dendritic grains of laser-deposited samples of the high entropy alloy CoCrCuFeNiAl have been studied using aberration-corrected analytical (scanning) transmission electron microscopy ((S)TEM). The compositional variations have been determined using energy dispersive x-ray spectroscopy (EDS) in (S)TEM. It was found that between B2, consisting mainly of Al, Ni, Co, and Fe, and disordered bcc phase, consisting mainly of Cr and Fe, there is a transition region, approximately 1.5 nm in width, over which the chemical composition changes from the B2 to that of the bcc phase. The crystal structure of this interfacial region is also B2, but with very different sublattice occupancy than that of the adjacent B2 compound. The structural aspects of the interface between the ordered B2 phase and the disordered bcc phase have been characterized using high angle annular dark-field (HAADF) imaging in STEM. It has been determined that the interfaces are essentially coherent, with the lattice parameters of the two B2 regions and the disordered bcc phase being more or less the same, the uncertainty arising from possible relaxations from the proximity of the surfaces of the thin foils used in imaging of the microstructures. Direct observations show that there is a planar continuity between all three constituent phases. - Highlights: • In the dendritic grains, there are two dominant phases, one with the ordered B2 structure, and the other disordered bcc. • From the intensity ratios in HAADF, the B2 phase appears to have a stoichiometry of the form Al(Ni, Co, and Fe). • Energy dispersive x-ray spectroscopy reveals the presence of an ordered interface transition region between the two phases. • Nanodiffraction in the Titan shows that the interface region is also ordered with the B2 crystal structure based on C.

Quantum disordered phase in a doped antiferromagnet

International Nuclear Information System (INIS)

Kuebert, C.; Muramatsu, A.

1995-01-01

A quantitative description of the transition to a quantum disordered phase in a doped antiferromagnet is obtained for the long-wavelength limit of the spin-fermion model, which is given by the O(3) non-linear σ model, a free fermionic part and current-current interactions. By choosing local spin quantization axes for the fermionic spinor we show that the low-energy limit of the model is equivalent to a U(1) gauge theory, where both the bosonic and fermionic degrees of freedom are minimally coupled to a vector gauge field. Within a large-N expansion, the strength of the gauge fields is found to be determined by the gap in the spin-wave spectrum, which is dynamically generated. The explicit doping dependence of the spin-gap is determined as a function of the parameters of the original model. As a consequence of the above, the gauge-fields mediate a long-range interaction among dopant holes and S-1/2 magnetic excitations only in the quantum disordered phase. The possible bound-states in this regime correspond to charge-spin separation and pairing

Composition-Driven Phase Boundary and Piezoelectricity in Potassium-Sodium Niobate-Based Ceramics.

Science.gov (United States)

Zheng, Ting; Wu, Jiagang; Xiao, Dingquan; Zhu, Jianguo; Wang, Xiangjian; Lou, Xiaojie

2015-09-16

The piezoelectricity of (K,Na)NbO3 ceramics strongly depends on the phase boundary types as well as the doped compositions. Here, we systematically studied the relationships between the compositions and phase boundary types in (K,Na) (Nb,Sb)O3-Bi0.5Na0.5AO3 (KNNS-BNA, A=Hf, Zr, Ti, Sn) ceramics; then their piezoelectricity can be readily modified. Their phase boundary types are determined by the doped elements. A rhombohedral-tetragonal (R-T) phase boundary can be driven in the compositions range of 0.035≤BNH≤0.040 and 0.035≤BNZ≤0.045; an orthorhombic-tetragonal (O-T) phase boundary is formed in the composition range of 0.005≤BNT≤0.02; and a pure O phase can be only observed regardless of BNS content (≤0.01). In addition, the phase boundary types strongly affect their corresponding piezoelectricities. A larger d33 (∼440-450 pC/N) and a higher d33* (∼742-834 pm/V) can be attained in KNNS-BNA (A=Zr and Hf) ceramics due to the involvement of R-T phase boundary, and unfortunately KNNS-BNA (A=Sn and Ti) ceramics possess a relatively poor piezoelectricity (d33≤200 and d33*piezoelectricity and phase boundary types were also discussed. We believe that comprehensive research can design more excellent ceramic systems concerning potassium-sodium niobate.

Novel Formulations of Phase Change Materials—Epoxy Composites for Thermal Energy Storage

OpenAIRE

Maria Elena Arce; Miguel Angel Alvarez Feijoo; Andres Suarez Garcia; Claudia C. Luhrs

2018-01-01

This research aimed to evaluate the thermal properties of new formulations of phase change materials (PCMs)-epoxy composites, containing a thickening agent and a thermally conductive phase. The composite specimens produced consisted of composites fabricated using (a) inorganic PCMs (hydrated salts), epoxy resins and aluminum particulates or (b) organic PCM (paraffin), epoxy resins, and copper particles. Differential Scanning Calorimetry (DSC) was used to analyze the thermal behavior of the sa...

Enhancement of polar crystalline phase formation in transparent PVDF-CaF{sub 2} composite films

Energy Technology Data Exchange (ETDEWEB)

Lee, Sang Goo; Ha, Jong-Wook, E-mail: jongwook@krict.re.kr; Sohn, Eun-Ho; Park, In Jun; Lee, Soo-Bok

2016-12-30

Highlights: • The crystalline phase in transparent PVDF-CaF{sub 2} composite films was investigated. • CaF{sub 2} promoted the formation of polar crystalline phases in PVDF matrix. • Ordered γ-phase was obtained by thermal treatment of as-cast films at the vicinity of its melting temperature. - Abstract: We consider the influence of calcium fluoride (CaF{sub 2}) nanoparticles on the crystalline phase formation of poly(vinylidene fluoride) (PVDF) for the first time. The transparent PVDF-CaF{sub 2} composite films were prepared by casting on PET substrates using N,N-dimethylacetamide (DMAc) as a solvent. It was found that CaF{sub 2} promoted the formation of polar crystalline phase of PVDF in composites, whereas nonpolar α-phase was dominant in the neat PVDF film prepared at the same condition. The portion of polar crystalline phase increased in proportional to the weight fraction of CaF{sub 2} in the composite films up to 10 wt%. Further addition of CaF{sub 2} suppressed completely the α-phase formation. Polar crystalline phase observed in as-cast composite films was a mixture of β- and γ-polymorph structures. It was also shown that much ordered γ-phase could be obtained through thermal treatment of as-cast PVDF-CaF{sub 2} composite film at the temperatures above the melting temperature of the composite films, but below that of γ-phase.

On an Algebraic Property of the Disordered Phase of the Ising Model with Competing Interactions on a Cayley Tree

Energy Technology Data Exchange (ETDEWEB)

Mukhamedov, Farrukh, E-mail: far75m@yandex.ru, E-mail: farrukh.m@uaeu.ac.ae [International Islamic University Malaysia, Department of Computational and Theoretical Sciences, Faculty of Science (Malaysia); Barhoumi, Abdessatar, E-mail: abdessatar.barhoumi@ipein.rnu.tn [Carthage University, Department of Mathematics, Nabeul Preparatory Engineering Institute (Tunisia); Souissi, Abdessatar, E-mail: s.abdessatar@hotmail.fr [Carthage University, Department of Mathematics, Marsa Preparatory Institute for Scientific and Technical Studies (Tunisia)

2016-12-15

It is known that the disordered phase of the classical Ising model on the Caley tree is extreme in some region of the temperature. If one considers the Ising model with competing interactions on the same tree, then about the extremity of the disordered phase there is no any information. In the present paper, we first aiming to analyze the correspondence between Gibbs measures and QMC’s on trees. Namely, we establish that states associated with translation invariant Gibbs measures of the model can be seen as diagonal quantum Markov chains on some quasi local algebra. Then as an application of the established correspondence, we study some algebraic property of the disordered phase of the Ising model with competing interactions on the Cayley tree of order two. More exactly, we prove that a state corresponding to the disordered phase is not quasi-equivalent to other states associated with translation invariant Gibbs measures. This result shows how the translation invariant states relate to each other, which is even a new phenomena in the classical setting. To establish the main result we basically employ methods of quantum Markov chains.

Phase Composition of a CrMo0.5NbTa0.5TiZr High Entropy Alloy: Comparison of Experimental and Simulated Data

Directory of Open Access Journals (Sweden)

Fan Zhang

2013-09-01

Full Text Available Microstructure and phase composition of a CrMo0.5NbTa0.5TiZr high entropy alloy were studied in the as-solidified and heat treated conditions. In the as-solidified condition, the alloy consisted of two disordered BCC phases and an ordered cubic Laves phase. The BCC1 phase solidified in the form of dendrites enriched with Mo, Ta and Nb, and its volume fraction was 42%. The BCC2 and Laves phases solidified by the eutectic-type reaction, and their volume fractions were 27% and 31%, respectively. The BCC2 phase was enriched with Ti and Zr and the Laves phase was heavily enriched with Cr. After hot isostatic pressing at 1450 °C for 3 h, the BCC1 dendrites coagulated into round-shaped particles and their volume fraction increased to 67%. The volume fractions of the BCC2 and Laves phases decreased to 16% and 17%, respectively. After subsequent annealing at 1000 °C for 100 h, submicron-sized Laves particles precipitated inside the BCC1 phase, and the alloy consisted of 52% BCC1, 16% BCC2 and 32% Laves phases. Solidification and phase equilibrium simulations were conducted for the CrMo0.5NbTa0.5TiZr alloy using a thermodynamic database developed by CompuTherm LLC. Some discrepancies were found between the calculated and experimental results and the reasons for these discrepancies were discussed.

Dual role of an ac driving force and the underlying two distinct order–disorder transitions in the vortex phase diagram of Ca{sub 3}Ir{sub 4}Sn{sub 13}

Energy Technology Data Exchange (ETDEWEB)

Kumar, Santosh, E-mail: santoshkumar@phy.iitb.ac.in [Department of Physics, Indian Institute of Technology Bombay, Mumbai 400076 (India); Singh, Ravi P.; Thamizhavel, A. [Department of Condensed Matter Physics and Materials Science, Tata Institute of Fundamental Research, Mumbai 400005 (India); Tomy, C.V., E-mail: tomy@phy.iitb.ac.in [Department of Physics, Indian Institute of Technology Bombay, Mumbai 400076 (India); Grover, A.K. [Department of Condensed Matter Physics and Materials Science, Tata Institute of Fundamental Research, Mumbai 400005 (India); Department of Physics, Panjab University, Chandigarh 160014 (India)

2014-11-15

Highlights: • This work pertains to new findings related to a broad SMP anomaly. • Broad SMP prima facie encompasses two phase transformations in vortex matter. • We demarcated two phase boundaries pertaining to order–disorder transitions which have quasi first-order nature. - Abstract: We present distinct demarcation of the Bragg glass (BG) to multi-domain vortex glass (VG) transition line and the eventual amorphization of the VG phase in a weakly pinned single crystal of the superconducting compound Ca{sub 3}Ir{sub 4}Sn{sub 13} on the basis of comprehension of the different yields about the second magnetization peak (SMP) anomaly in the dc magnetization and the corresponding anomalous feature in the ac susceptibility measurements. The shaking by a small ac magnetic field, inevitably present in the ac susceptibility measurements, is seen to result in contrasting responses in two different portions of the field-temperature (H, T) phase space of the multi-domain VG. In one of the portions, embracing the BG to VG transition across the onset of the SMP anomaly, the ac drive is surprisingly seen to assist the transformation of the well ordered BG phase to a lesser ordered VG phase. The BG phase exists as a superheated state over a small portion of the VG space and this attests to the first order nature of the BG to VG transition.

State of the art of durability-performance evaluation of hardened cement based on phase compositions

International Nuclear Information System (INIS)

Kurashige, Isao; Imoto, Harutake; Yamamoto, Takeshi; Hironaga, Michihiko

2006-01-01

Upgrading durability-performance evaluation technique for concrete is urgently demanded in connection to its application to radio-active waste repository which needs ultra long-term durability. Common concrete structures also require an advanced method for minimizing the life-cycle cost. The purpose of this research is to investigate current problems and future tasks on durability-performance evaluation of hardened cement from the view point of phase composition. Although the phase composition of hardened cement has not fully been reflected to durability-performance evaluation, it influences concrete durability as well as its pore structure. This report reviews state of the art of the factors affecting phase composition, analytical and experimental evaluation techniques for phase composition, and durability-performance evaluation methods of hardened cement based on phase composition. (author)

Two-phase flow characteristics in BWRs

International Nuclear Information System (INIS)

Katono, Kenichi; Aoyama, Goro; Nagayoshi, Takuji; Yasuda, Kenichi; Nishida, Koji

2014-01-01

Reliable prediction of two-phase flow characteristics is important for safety and economy improvements of BWR plants. We have been developing two-phase flow measurement tools and techniques for BWR thermal hydraulic conditions, such as a 3D time-averaged X-ray CT system, an ultrasonic liquid film sensor and a wire-mesh sensor. We applied the developed items in experiments using the multi-purpose steam-water test facility known as HUSTLE, which can simulate two-phase thermal-hydraulic conditions in a BWR reactor pressure vessel, and we constructed a detailed instrumentation database. We validated a 3D two-phase flow simulator using the database and developed the reactor internal two-phase flow analysis system. (author)

No-Oven, No-Autoclave, Composite Processing, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Cornerstone Research Group Inc. (CRG) proposes to continue the efforts from the 2010 NASA SBIR Phase I topic X5.03, "No-Oven, No-Autoclave (NONA) Composite...

System identification on two-phase flow stability

International Nuclear Information System (INIS)

Wu Shaorong; Zhang Youjie; Wang Dazhong; Bo Jinghai; Wang Fei

1996-01-01

The theoretical principle, experimental method and results of interrelation analysis identification for the instability of two-phase flow are described. A completely new concept of test technology and method on two-phase flow stability was developed by using he theory of information science on system stability and system identification for two-phase flow stability in thermo-physics field. Application of this method would make it possible to identify instability boundary of two-phase flow under stable operation conditions of two-phase flow system. The experiment was carried out on the thermohydraulic test system HRTL-5. Using reverse repeated pseudo-random sequences of heating power as input signal sources and flow rate as response function in the test, the two-phase flow stability and stability margin of the natural circulation system are investigated. The effectiveness and feasibility of identifying two-phase flow stability by using this system identification method were experimentally demonstrated. Basic data required for mathematics modeling of two-phase flow and analysis of two-phase flow stability were obtained, which are useful for analyzing, monitoring of the system operation condition, and forecasting of two-phase flow stability in engineering system

Competing magnetic interactions and low temperature magnetic phase transitions in composite multiferroics

International Nuclear Information System (INIS)

Borkar, Hitesh; Singh, V N; Kumar, Ashok; Choudhary, R J; Tomar, M; Gupta, Vinay

2015-01-01

Novel magnetic properties and magnetic interactions in composite multiferroic oxides Pb[(Zr 0.52 Ti 0.48 ) 0.60 (Fe 0.67 W 0.33 ) .40 ]O 3 ] 0.80 –[CoFe 2 O 4 ] 0.20 (PZTFW–CFO) have been studied from 50 to 1000 Oe field cooled (FC) and zero field cooled (ZFC) probing conditions, and over a wide range of temperatures (4–350 K). Crystal structure analysis, surface morphology, and high resolution transmission electron microscopy images revealed the presence of two distinct phases, where micro- and nano-size spinel CFO were embedded in tetragonal PZTFW matrix and applied a significant built-in compressive strain (∼0.4–0.8%). Three distinct magnetic phase transitions were observed with the subtle effect of CFO magnetic phase on PZTFW magnetic phase transitions below the blocking temperature (T B ). Temperature dependence magnetic property m(T) shows a clear evidence of spin freezing in magnetic order with lowering in thermal vibration. Chemical inhomogeneity and confinement of nanoscale ferrimagnetic phase in paramagnetic/antiferromagnetic matrix restrict the long range interaction of spin which in turn develop a giant spin frustration. A large divergence in the FC and ZFC data and broad hump in ZFC data near 200 (±10) K were observed which suggests that large magnetic anisotropy and short range order magnetic dipoles lead to the development of superparamagnetic states in composite. (paper)

Numerical modeling of two-phase binary fluid mixing using mixed finite elements

KAUST Repository

Sun, Shuyu

2012-07-27

Diffusion coefficients of dense gases in liquids can be measured by considering two-phase binary nonequilibrium fluid mixing in a closed cell with a fixed volume. This process is based on convection and diffusion in each phase. Numerical simulation of the mixing often requires accurate algorithms. In this paper, we design two efficient numerical methods for simulating the mixing of two-phase binary fluids in one-dimensional, highly permeable media. Mathematical model for isothermal compositional two-phase flow in porous media is established based on Darcy\\'s law, material balance, local thermodynamic equilibrium for the phases, and diffusion across the phases. The time-lag and operator-splitting techniques are used to decompose each convection-diffusion equation into two steps: diffusion step and convection step. The Mixed finite element (MFE) method is used for diffusion equation because it can achieve a high-order and stable approximation of both the scalar variable and the diffusive fluxes across grid-cell interfaces. We employ the characteristic finite element method with moving mesh to track the liquid-gas interface. Based on the above schemes, we propose two methods: single-domain and two-domain methods. The main difference between two methods is that the two-domain method utilizes the assumption of sharp interface between two fluid phases, while the single-domain method allows fractional saturation level. Two-domain method treats the gas domain and the liquid domain separately. Because liquid-gas interface moves with time, the two-domain method needs work with a moving mesh. On the other hand, the single-domain method allows the use of a fixed mesh. We derive the formulas to compute the diffusive flux for MFE in both methods. The single-domain method is extended to multiple dimensions. Numerical results indicate that both methods can accurately describe the evolution of the pressure and liquid level. © 2012 Springer Science+Business Media B.V.

The manic phase of Bipolar disorder significantly impairs theory of mind decoding.

Science.gov (United States)

Hawken, Emily R; Harkness, Kate L; Lazowski, Lauren K; Summers, David; Khoja, Nida; Gregory, James Gardner; Milev, Roumen

2016-05-30

Bipolar disorder is associated with significant deficits in the decoding of others' mental states in comparison to healthy participants. However, differences in theory of mind decoding ability among patients in manic, depressed, and euthymic phases of bipolar disorder is currently unknown. Fifty-nine patients with bipolar I or II disorder (13 manic, 25 depressed, 20 euthymic) completed the "Reading the Mind in the Eyes" Task (Eyes task) and the Animals Task developed to control for non-mentalistic response demands of the Eyes Task. Patients also completed self-report and clinician-rated measures of depression, mania, and anxiety symptoms. Patients in the manic phase were significantly less accurate than those in the depressed and euthymic phases at decoding mental states in the Eyes task, and this effect was strongest for eyes of a positive or neutral valence. Further Eyes task performance was negatively correlated with the symptoms of language/thought disorder, pressured speech, and disorganized thoughts and appearance. These effects held when controlling for accuracy on the Animals task, response times, and relevant demographic and clinical covariates. Results suggest that the state of mania, and particularly psychotic symptoms that may overlap with the schizophrenia spectrum, are most strongly related to social cognitive deficits in bipolar disorder. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Numerical study of compositional compressible degenerate two-phase flow in saturated–unsaturated heterogeneous porous media

KAUST Repository

Saad, Ali S.; Saad, Bilal Mohammed; Saad, Mazen

2016-01-01

We study the convergence of a combined finite volume-nonconforming finite element scheme on general meshes for a partially miscible two-phase flow model in anisotropic porous media. This model includes capillary effects and exchange between the phases. The diffusion term, which can be anisotropic and heterogeneous, is discretized by piecewise linear nonconforming triangular finite elements. The other terms are discretized by means of a cell-centered finite volume scheme on a dual mesh. The relative permeability of each phase is decentered according to the sign of the velocity at the dual interface. The convergence of the scheme is proved thanks to an estimate on the two pressures which allows to show estimates on the discrete time and compactness results in the case of degenerate relative permeabilities. A key point in the scheme is to use particular averaging formula for the dissolution function arising in the diffusion term. We show also a simulation of hydrogen production in nuclear waste management. Numerical results are obtained by in-house numerical code. © 2015 Elsevier Ltd.

Numerical study of compositional compressible degenerate two-phase flow in saturated–unsaturated heterogeneous porous media

KAUST Repository

Saad, Ali S.

2016-01-02

We study the convergence of a combined finite volume-nonconforming finite element scheme on general meshes for a partially miscible two-phase flow model in anisotropic porous media. This model includes capillary effects and exchange between the phases. The diffusion term, which can be anisotropic and heterogeneous, is discretized by piecewise linear nonconforming triangular finite elements. The other terms are discretized by means of a cell-centered finite volume scheme on a dual mesh. The relative permeability of each phase is decentered according to the sign of the velocity at the dual interface. The convergence of the scheme is proved thanks to an estimate on the two pressures which allows to show estimates on the discrete time and compactness results in the case of degenerate relative permeabilities. A key point in the scheme is to use particular averaging formula for the dissolution function arising in the diffusion term. We show also a simulation of hydrogen production in nuclear waste management. Numerical results are obtained by in-house numerical code. © 2015 Elsevier Ltd.

Vibration measurement on composite material with embedded optical fiber based on phase-OTDR

Science.gov (United States)

Franciscangelis, C.; Margulis, W.; Floridia, C.; Rosolem, J. B.; Salgado, F. C.; Nyman, T.; Petersson, M.; Hallander, P.; Hällstrom, S.; Söderquist, I.; Fruett, F.

2017-04-01

Distributed sensors based on phase-optical time-domain reflectometry (phase-OTDR) are suitable for aircraft health monitoring due to electromagnetic interference immunity, small dimensions, low weight and flexibility. These features allow the fiber embedment into aircraft structures in a nearly non-intrusive way to measure vibrations along its length. The capability of measuring vibrations on avionics structures is of interest for what concerns the study of material fatigue or the occurrence of undesirable phenomena like flutter. In this work, we employed the phase-OTDR technique to measure vibrations ranging from some dozens of Hz to kHz in two layers of composite material board with embedded polyimide coating 0.24 numerical aperture single-mode optical fiber.

Study of the formation of secondary phases in the composite LSM/YSZ

International Nuclear Information System (INIS)

Rodrigues, Ranieri Andrade

2007-01-01

The composite of strontium-doped lanthanum manganite (La 1-x SrxMnO 3 - LSM) and Yttria-stabilized zirconia (ZrO 2 /Y 2 O 3 - YSZ), is indicated as cathode of the Solid Oxide Fuel Cells (SOFC). It presents better acting as cathode due to the Triple Phase Boundary (TPB) formed in the interface area between the cathode and the electrolyte. For the temperatures up to 1100 deg C, LSM and YSZ can react producing lanthanum zirconate (La 2 Zr 2 O 7 - LZO) and strontium zirconate (SrZrO 3 - SZO). In this sense, the present work intends to contribute in the study of the formation of phases LZO and SZO, studying different massic proportions between LSM and YSZ with sintering temperatures varying between 1000 deg C and 1400 deg C. For the obtention of the precursory powders the co-precipitation routes were adopted to obtain YSZ and conventional powder mixture for the preparation of LSM. The composite LSM/YSZ, studied in this work, is prepared with two concentrations of Sr for LSM (30 mol por cent - LSM7 and 40 mol por cent - LSM6) and one concentration of Yttria for YSZ (10 mol por cent). The results obtained by X-ray fluorescence showed that the routes adopted for synthesis of powders were effective in the obtention of the compositions LSM6, LSM7 and YSZ, with close values to the stoichiometric. The studied massic proportions were: 50 por cent of LSM and 50 por cent of YSZ (1:1), 25 por cent of LSM and 75 por cent of YSZ (1:3), and 75 por cent of LSM and 25 por cent of YSZ (3:1). Such proportions of mixtures were conformed and submitted at different conditions of temperatures and times of sintering: 1000 deg C, 1200 deg C, 1300 deg C, 1350 deg C and 1400 deg C for 4 and 8 hours. The values of medium size of the particles and the specific surface area values for the mixture of LSM6/YSZ and LSM7/YSZ, are of the same order of largeness after the mixture in a attrition mill and in different massic proportions. Secondary phases like LZO and SZO were not found in the analysis for

Research on one-dimensional two-phase flow

International Nuclear Information System (INIS)

Adachi, Hiromichi

1988-10-01

In Part I the fundamental form of the hydrodynamic basic equations for a one-dimensional two-phase flow (two-fluid model) is described. Discussions are concentrated on the treatment of phase change inertial force terms in the equations of motion and the author's equations of motion which have a remarkable uniqueness on the following three points. (1) To express force balance of unit mass two-phase fluid instead of that of unit volume two-phase fluid. (2) To pick up the unit existing mass and the unit flowing mass as the unit mass of two-phase fluid. (3) To apply the kinetic energy principle instead of the momentum low in the evaluation of steady inertial force term. In these three, the item (1) is for excluding a part of momentum change or kinetic energy change due to mass change of the examined part of fluid, which is independent of force. The item (2) is not to introduce a phenomenological physical model into the evaluation of phase change inertial force term. And the item (3) is for correctly applying the momentum law taking into account the difference of representative velocities between the main flow fluid (vapor phase or liquid phase) and the phase change part of fluid. In Part II, characteristics of various kinds of high speed two-phase flow are clarified theoretically by the basic equations derived. It is demonstrated that the steam-water two-phase critical flow with violent flashing and the airwater two-phase critical flow without phase change can be described with fundamentally the same basic equations. Furthermore, by comparing the experimental data from the two-phase critical discharge test and the theoretical prediction, the two-phase discharge coefficient, C D , for large sharp-edged orifice is determined as the value which is not affected by the experimental facility characteristics, etc. (author)

Laterally structured ripple and square phases with one and two dimensional thickness modulations in a model bilayer system.

Science.gov (United States)

Debnath, Ananya; Thakkar, Foram M; Maiti, Prabal K; Kumaran, V; Ayappa, K G

2014-10-14

Molecular dynamics simulations of bilayers in a surfactant/co-surfactant/water system with explicit solvent molecules show formation of topologically distinct gel phases depending upon the bilayer composition. At low temperatures, the bilayers transform from the tilted gel phase, Lβ', to the one dimensional (1D) rippled, Pβ' phase as the surfactant concentration is increased. More interestingly, we observe a two dimensional (2D) square phase at higher surfactant concentration which, upon heating, transforms to the gel Lβ' phase. The thickness modulations in the 1D rippled and square phases are asymmetric in two surfactant leaflets and the bilayer thickness varies by a factor of ∼2 between maximum and minimum. The 1D ripple consists of a thinner interdigitated region of smaller extent alternating with a thicker non-interdigitated region. The 2D ripple phase is made up of two superimposed square lattices of maximum and minimum thicknesses with molecules of high tilt forming a square lattice translated from the lattice formed with the thickness minima. Using Voronoi diagrams we analyze the intricate interplay between the area-per-head-group, height modulations and chain tilt for the different ripple symmetries. Our simulations indicate that composition plays an important role in controlling the formation of low temperature gel phase symmetries and rippling accommodates the increased area-per-head-group of the surfactant molecules.

Speeding up compositional reservoir simulation through an efficient implementation of phase equilibrium calculation

DEFF Research Database (Denmark)

Belkadi, Abdelkrim; Yan, Wei; Moggia, Elsa

2013-01-01

Compositional reservoir simulations are widely used to simulate reservoir processes with strong compositional effects, such as gas injection. The equations of state (EoS) based phase equilibrium calculation is a time consuming part in this type of simulations. The phase equilibrium problem can....... Application of the shadow region method to skip stability analysis can further cut the phase equilibrium calculation time. Copyright 2013, Society of Petroleum Engineers....

The design of a two-phase radiolabelled meal for gastric emptying studies

International Nuclear Information System (INIS)

Mather, S.J.; Ellison, D.; Nightingale, J.; Kamm, M.; Britton, K.E.

1991-01-01

A meal intended for use in gastric emptying studies must be highly reproducible, must provide a normal physiological stimulus in terms of bulk, calorie content and composition and must employ stable radiotracers which accurately reflect in their biodistribution, the fate of the two-phases. This is particularly important in a field, such as gastric emptying, where so many variables may influence the results. A conventional pancake and orange juice were chosen as suitable vehicles for the solid and liquid phases. 111 In-labelled resin beads were used as the solid-phase marker and a variety of 99 Tc m -labelled radiopharmaceuticals including pertechnetate, DTPA and colloid forms were investigated as liquid-phase markers. Prior to administration to patients, the stability of the phases and their interactions in vitro were investigated. The use of 99 Tc m -DTPA resulted in a loss of 111 In from solid to liquid phase. All non-colloidal markers exhibited a tendency for adsorption onto solid phase. Colloidal markers including rhenium and antimony sulphide colloids showed the truest delineation of the liquid phase. (author)

Thermal performance study of form-stable composite phase change material with polyacrylic

Science.gov (United States)

Kee, Shin Yiing; Munusamy, Yamuna; Ong, Kok Seng; Chee, Swee Yong; Sanmuggam, Shimalaa

2017-04-01

Phase change material (PCM) is one of the most popular and widely used as thermal energy storage material because it is able to absorb and release a large amount of latent heat during a phase change process over a narrow temperature range. In this work, the form-stable composite PCM was prepared by blending of PMMA and myristic acid in different weight percentage. PMMA was used as a supporting material while myristic acid was used as PCM. Theoretically, PCM can be encapsulated in the support material after blending. However, a small amount of liquid PCMs can leak out from supporting material due to the volume change in phase change process. Therefore, a form-stable composite PCM with polyacrylic coating was studied. Leakage test was carried out to determine the leakage percentage of the form-stable composite PCM. Fourier transform infrared spectroscopy (FTIR) was used to characterize the chemical compatibility of the form-stable PCM composite while differential scanning calorimetry (DSC) was used to study the melting, freezing point and the latent heat of melting and freezing for the form-stable composite PCM.

Molecular dynamics simulation of the rotational order-disorder phase transition in calcite

International Nuclear Information System (INIS)

Kawano, Jun; Miyake, Akira; Shimobayashi, Norimasa; Kitamura, Masao

2009-01-01

Molecular dynamics (MD) simulation of calcite was carried out with the interatomic potential model based on ab initio calculations to elucidate the phase relations for calcite polymorphs and the mechanism of the rotational order-disorder transition of calcite at high temperature at the atomic scale. From runs of MD calculations with increasing temperature within a pressure range of 1 atm and 2 GPa, the transition of calcite with R3-barc symmetry into a high-temperature phase with R3-barm symmetry was reproduced. In the high-temperature R3-barm phase, CO 3 groups vibrate with large amplitudes either around the original positions in the R3-barc structure or around other positions rotated ± 60 deg., and their positions change continuously with time. Moreover, contrary to the suggestion of previous investigators, the motion of CO 3 groups is not two-dimensional. At 1 atm, the transition between R3-barc and R3-barm is first order in character. Upon increasing temperature at high pressure, however, first a first-order isosymmetric phase transition between the R3-barc phases occurs, which corresponds to the start of ± 120 deg. flipping of CO 3 groups. Then, at higher temperatures, the transition of R3-barc to R3-barm phases happens, which can be considered second order. This set of two types of transitions at elevated pressure can be characterized by the appearance of an 'intermediate' R3-barc phase between the stable region of calcite and the high-temperature R3-barm phase, which may correspond to the CaCO 3 -IV phase.

Clinical Practice Guideline for the Treatment of Intrinsic Circadian Rhythm Sleep-Wake Disorders: Advanced Sleep-Wake Phase Disorder (ASWPD), Delayed Sleep-Wake Phase Disorder (DSWPD), Non-24-Hour Sleep-Wake Rhythm Disorder (N24SWD), and Irregular Sleep-Wake Rhythm Disorder (ISWRD). An Update for 2015

Science.gov (United States)

Auger, R. Robert; Burgess, Helen J.; Emens, Jonathan S.; Deriy, Ludmila V.; Thomas, Sherene M.; Sharkey, Katherine M.

2015-01-01

A systematic literature review and meta-analyses (where appropriate) were performed and the GRADE approach was used to update the previous American Academy of Sleep Medicine Practice Parameters on the treatment of intrinsic circadian rhythm sleep-wake disorders. Available data allowed for positive endorsement (at a second-tier degree of confidence) of strategically timed melatonin (for the treatment of DSWPD, blind adults with N24SWD, and children/ adolescents with ISWRD and comorbid neurological disorders), and light therapy with or without accompanying behavioral interventions (adults with ASWPD, children/adolescents with DSWPD, and elderly with dementia). Recommendations against the use of melatonin and discrete sleep-promoting medications are provided for demented elderly patients, at a second- and first-tier degree of confidence, respectively. No recommendations were provided for remaining treatments/ populations, due to either insufficient or absent data. Areas where further research is needed are discussed. Citation: Auger RR, Burgess HJ, Emens JS, Deriy LV, Thomas SM, Sharkey KM. Clinical practice guideline for the treatment of intrinsic circadian rhythm sleep-wake disorders: advanced sleep-wake phase disorder (ASWPD), delayed sleep-wake phase disorder (DSWPD), non-24-hour sleep-wake rhythm disorder (N24SWD), and irregular sleep-wake rhythm disorder (ISWRD). An update for 2015. J Clin Sleep Med 2015;11(10):1199–1236. PMID:26414986

DETERMINATION OF PHASE COMPOSITION OF SEALING COATING BASED ON APC (ALUMINOPHOSPHATE COMPOUNDS

Directory of Open Access Journals (Sweden)

BOLSHAKOV V. I.

2017-02-01

Full Text Available Summary. Goal. To investigate the phase composition of the obtained sealing coatings based on aluminophosphate compound (APC and the impact of temperature rise on it. Methods. Qualitative X-ray phase analysis (XRPA and differential thermal analysis (DTA are used as the methods of research. Roentgenograms for structural analysis were obtained on a DRON-4-07 using filtered copper radiation in the secondary beam. Registration and initial processing of diffraction patterns was performed using the software package PDOS with the output of the diffraction patterns on the screen. Using the "loupe" option allowed to identify weak interference lines, which increased the accuracy of the method of qualitative XRPA. The thermograms for DTA received on the device type Termoskan-2. The results. It is revealed that base of coating is X-ray amorphous phase. There are following crystalline phases: Al, AlPO4, Al (PO3 3, BN found in the coating. It is revealed that annealing doesn’t make a significant influence on the phase composition of the crystalline phases and the coating doesn’t lose properties after annealing during repeated thermal stress. Scientific novelty. The phase composition of the proposed sealing coatings based on APC and produced by plasma spraying, and the effect of annealing on the phase composition of the coating are investigated. The reaction of synthesis of primary material forming on the basis of APC for coating is offered. Practical significance. The results can be used in aviation technology in the development of gas turbine engines (GTE and the design of the compressors. The sealing coating may be used to improve the reliability of the compressor and to increase the efficiency ratio of turbine engine. During the operation the compressor’s blades touch the sealing coating of compressor’s stator and grooves it without causing locking and destruction of the rotor. Therefore, the development of new sealing coating compositions that

Performance evaluation on solar still integrated with nano-composite phase change materials

International Nuclear Information System (INIS)

Rajasekhar, G.; Eswaramoorthy, M.

2015-01-01

This paper communicates the performance evaluation of single slope solar still integrated with nano-composite phase change materials and compare with the experimental results of with and without phase change materials. A solar still with 1 m"2 surface area is developed with non-selective coating of absorber sheet with the provision of thermal energy storage materials. The solar still is tested on typical days with and without thermal energy storage materials. It is found that from the experimental studies that nano-materials (Al_2O_3) dispersed in paraffin wax is giving better cumulative yield of distillate than paraffin wax alone and without paraffin wax thermal storage. The daily efficiency of the solar still is computed for solar still with nano-composite phase change materials is 45% and solar still paraffin wax alone thermal storage is 40% and solar still without any thermal storage is 38%. It is concluded from the experimental studies; solar still integrated with nano-composite phase change materials gives better performance than with and without phase change material alone. (authors)

Phase Change Insulation for Energy Efficiency Based on Wax-Halloysite Composites

International Nuclear Information System (INIS)

Zhao, Yafei; Thapa, Suvhashis; Weiss, Leland; Lvov, Yuri

2014-01-01

Phase change materials (PCMs) have gained extensive attention in thermal energy storage. Wax can be used as a PCM in solar storage but it has low thermal conductivity. Introducing 10% halloysite admixed into wax yields a novel composite (wax-halloysite) which has a thermal conductivity of 0.5 W/mK. To increase the base conductivity, graphite and carbon nanotubes were added into the PCM composite improving its thermal energy storage. Thermal conductivity of wax-halloysite-graphite (45/45/10%) composite showed increased conductivity of 1.4 W/mK (3 times higher than the base wax-halloysite composite). Wax- halloysite-graphite-carbon nanotubes (45/45/5/5%) composite showed conductivity of 0.85 W/mK while maintaining the original shape perfectly until 91 °C (above the original wax melting point). Thermal conductivity can be further increased with higher doping of carbon nanotubes. This new composites are promising heat storage material due to good thermal stability, high thermal/electricity conductivity and ability to preserve its shape during phase transitions

Diagnosis of obsessive-compulsive disorder in the course of bipolar disorder

Directory of Open Access Journals (Sweden)

Maciej Żerdziński

2016-06-01

Full Text Available Aim: The aim of this study was to evaluate the coexistence of obsessive-compulsive symptoms with bipolar disorder (during the manic phase, depressive phase and remission. Method: The subjects were 70 patients previously diagnosed with and treated for bipolar disorder. For the purposes of this study, three subgroups were created: patients in the manic phase, depressive phase and in remission. The Hamilton Depression Rating Scale, Young Mania Rating Scale and Yale-Brown Obsessive Compulsive Scale were diagnostic tools used for the evaluation of patients’ mental health. Results: The data indicate high likelihood of co-occurrence of obsessive-compulsive disorder (28.6% and obsessive-compulsive syndromes (32.8% with bipolar disorder. Obsessions and compulsions were observed irrespectively of the type of bipolar disorder (type 1 and 2 and phase of the illness (depression, mania, remission. The results in the three subgroups were similar. The severity of anankastic symptoms depended both on the severity of depression and mania. The subjects confirmed the presence of obsessive-compulsive symptoms in the interview, although they were usually undiagnosed and untreated. Conclusions: Obsessive-compulsive disorder symptoms often coexist with bipolar disorder, both in its two phases and in remission. The severity of obsessive-compulsive symptoms in the course of bipolar condition varies, ranging from mild to extremely severe forms. The obsessive-compulsive disorder presentation in the course of bipolar disorder increases with the severity of depressive and manic symptoms. Obsessive-compulsive disorder can be primary to bipolar disorder. Obsessive-compulsive disorder coexisting with bipolar disorder is not diagnosed or treated properly.

Disorder Induced Dynamic Equilibrium Localization and Random Phase Steps of Bose—Einstein Condensates

International Nuclear Information System (INIS)

Duan Ya-Fan; Xu Zhen; Qian Jun; Sun Jian-Fang; Jiang Bo-Nan; Hong Tao

2011-01-01

We numerically analyze the dynamic behavior of Bose—Einstein condensate (BEC) in a one-dimensional disordered potential before it completely loses spatial quantum coherence. We find that both the disorder statistics and the atom interactions produce remarkable effects on localization. We also find that the single phase of the initial condensate is broken into many small pieces while the system approaches localization, showing a counter-intuitive step-wise phase but not a thoroughly randomized phase. Although the condensates as a whole show less flow and expansion, the currents between adjacent phase steps retain strong time dependence. Thus we show explicitly that the localization of a finite size Bose—Einstein condensate is a dynamic equilibrium state. (general)

A phase-field model for non-equilibrium solidification of intermetallics

International Nuclear Information System (INIS)

Assadi, H.

2007-01-01

Intermetallics may exhibit unique solidification behaviour-including slow growth kinetics, anomalous partitioning and formation of unusual growth morphologies-because of departure from local equilibrium. A phase-field model is developed and used to illustrate these non-equilibrium effects in solidification of a prototype B2 intermetallic phase. The model takes sublattice compositions as primary field variables, from which chemical long-range order is derived. The diffusive reactions between the two sublattices, and those between each sublattice and the liquid phase are taken as 'internal' kinetic processes, which take place within control volumes of the system. The model can thus capture solute and disorder trapping effects, which are consistent-over a wide range of the solid/liquid interface thickness-with the predictions of the sharp-interface theory of solute and disorder trapping. The present model can also take account of solid-state ordering and thus illustrate the effects of chemical ordering on microstructure formation and crystal growth kinetics

Analysis of phase dynamics in two-phase flow using latticegas automata

International Nuclear Information System (INIS)

Ohashi, H.; Hashimoto, Y.; Tsumaya, A.; Chen, Y.; Akiyama, M.

1998-01-01

In this paper, we describe lattice gas automaton models appropriate for two-phase flow simulation and their applications to study various phase dynamics of two-fluid mixtures. Several algorithms are added to the original immiscible Lattice Gas model to adjust surface tension and to introduce density difference between two fluids. Surface tension is controlled by the collision rules an difference in density is due to nonlocal forces between automaton particles. We simulate the relative motion of the dispersed phase in another continuous fluid. Deformation and disintegration of rising drops are reproduced. The interaction between multiple drops is also observed in calculations. Furutre, we obtain the transition of the two-phase flow pattern from bubbly, slug to annular flow. Density difference of two phase is one of the key ingredients to generate the annular flow pattern

Cermet anode compositions with high content alloy phase

Science.gov (United States)

Marschman, Steven C.; Davis, Norman C.

1989-01-01

Cermet electrode compositions comprising NiO-NiFe.sub.2 O.sub.4 -Cu-Ni, and methods for making, are disclosed. Addition of nickel metal prior to formation and densification of a base mixture into the cermet allows for an increase in the total amount of copper and nickel that can be contained in the NiO-NiFe.sub.2 O.sub.4 oxide system. Nickel is present in a base mixture weight concentration of from 0.1% to 10%. Copper is present in the alloy phase in a weight concentration of from 10% to 30% of the densified composition. Such cermet electrodes can be formed to have electrical conductivities well in excess of 100 ohm.sup.-1 cm.sup.-1. Other alloy and oxide system cermets having high content metal phases are also expected to be manufacturable in accordance with the invention.

Carbon nanotube/paraffin/montmorillonite composite phase change material for thermal energy storage.

Science.gov (United States)

Li, Min; Guo, Qiangang; Nutt, Steven

2017-04-01

A composite phase change material (PCM) comprised of organic montmorillonite (OMMT)/paraffin/grafted multi-walled nanotube (MWNT) is synthesized via ultrasonic dispersion and liquid intercalation. The microstructure of the composite PCM has been characterized to determine the phase distribution, and thermal properties (latent heat and thermal conductivity) have been measured by differential scanning calorimetry (DSC) and a thermal constant analyzer. The results show that paraffin molecules are intercalated in the montmorillonite layers and the grafted MWNTs are dispersed in the montmorillonite layers. The latent heat is 47.1 J/g, and the thermal conductivity of the OMMT/paraffin/grafted MWNT composites is 34% higher than that of the OMMT/paraffin composites and 65% higher than that of paraffin.

Lβ' → Lc' phase transition in phosphatidylcholine lipid bilayers: a disorder-order transition in two dimensions

International Nuclear Information System (INIS)

Raghunathan, V.A.; Katsaras, J.

1996-01-01

The structure of the L c' phase exhibited by hydrated dipalmitoylphosphatidylcholine (DPPC) was recently determined by Raghunathan and Katsaras [Phys. Rev. Lett. 74, 4456 (1995)] from x-ray diffraction studies on oriented multibilayers. Here, we reanalyze the powder diffraction data reported in the literature on a number of hydrated lipids possessing the phosphatidylcholine headgroup. As in DPPC, the L c' phase in all of these systems is found to be characterized by two-dimensional ordering of the lipid molecules on a superlattice of the hydrocarbon chain lattice. We also discuss the influence of headgroup interactions on the structure of this phase. (author)

Multi-scale diffuse interface modeling of multi-component two-phase flow with partial miscibility

Science.gov (United States)

Kou, Jisheng; Sun, Shuyu

2016-08-01

In this paper, we introduce a diffuse interface model to simulate multi-component two-phase flow with partial miscibility based on a realistic equation of state (e.g. Peng-Robinson equation of state). Because of partial miscibility, thermodynamic relations are used to model not only interfacial properties but also bulk properties, including density, composition, pressure, and realistic viscosity. As far as we know, this effort is the first time to use diffuse interface modeling based on equation of state for modeling of multi-component two-phase flow with partial miscibility. In numerical simulation, the key issue is to resolve the high contrast of scales from the microscopic interface composition to macroscale bulk fluid motion since the interface has a nanoscale thickness only. To efficiently solve this challenging problem, we develop a multi-scale simulation method. At the microscopic scale, we deduce a reduced interfacial equation under reasonable assumptions, and then we propose a formulation of capillary pressure, which is consistent with macroscale flow equations. Moreover, we show that Young-Laplace equation is an approximation of this capillarity formulation, and this formulation is also consistent with the concept of Tolman length, which is a correction of Young-Laplace equation. At the macroscopical scale, the interfaces are treated as discontinuous surfaces separating two phases of fluids. Our approach differs from conventional sharp-interface two-phase flow model in that we use the capillary pressure directly instead of a combination of surface tension and Young-Laplace equation because capillarity can be calculated from our proposed capillarity formulation. A compatible condition is also derived for the pressure in flow equations. Furthermore, based on the proposed capillarity formulation, we design an efficient numerical method for directly computing the capillary pressure between two fluids composed of multiple components. Finally, numerical tests

Multi-scale diffuse interface modeling of multi-component two-phase flow with partial miscibility

KAUST Repository

Kou, Jisheng

2016-05-10

In this paper, we introduce a diffuse interface model to simulate multi-component two-phase flow with partial miscibility based on a realistic equation of state (e.g. Peng-Robinson equation of state). Because of partial miscibility, thermodynamic relations are used to model not only interfacial properties but also bulk properties, including density, composition, pressure, and realistic viscosity. As far as we know, this effort is the first time to use diffuse interface modeling based on equation of state for modeling of multi-component two-phase flow with partial miscibility. In numerical simulation, the key issue is to resolve the high contrast of scales from the microscopic interface composition to macroscale bulk fluid motion since the interface has a nanoscale thickness only. To efficiently solve this challenging problem, we develop a multi-scale simulation method. At the microscopic scale, we deduce a reduced interfacial equation under reasonable assumptions, and then we propose a formulation of capillary pressure, which is consistent with macroscale flow equations. Moreover, we show that Young-Laplace equation is an approximation of this capillarity formulation, and this formulation is also consistent with the concept of Tolman length, which is a correction of Young-Laplace equation. At the macroscopical scale, the interfaces are treated as discontinuous surfaces separating two phases of fluids. Our approach differs from conventional sharp-interface two-phase flow model in that we use the capillary pressure directly instead of a combination of surface tension and Young-Laplace equation because capillarity can be calculated from our proposed capillarity formulation. A compatible condition is also derived for the pressure in flow equations. Furthermore, based on the proposed capillarity formulation, we design an efficient numerical method for directly computing the capillary pressure between two fluids composed of multiple components. Finally, numerical tests

Phase composition and catalytic properties of oxide multicomponent molybdenum-containing catalysts for partial oxidation of propylene

International Nuclear Information System (INIS)

Malakhov, V.V.; Vlasov, A.A.; Boldyreva, N.N.; Dovlitova, L.S.; Plyasova, L.M.; Andrushkevich, T.V.; Kuznetsova, T.G.

1996-01-01

The catalytic properties and phase composition of multicomponent molybdenum-containing catalyst treated under various redox conditions have been studied. The phase composition has been considered by the methods of X-ray phase analysis and noncalibrated methods of differentiating dissolution (DD). Using the DD method the data on element composition, stoichiometry and quantitative content of phases of complex molybdates have been obtained for the first time. Data on modification of basic phases of the catalyst-cobalt and iron molybdates - by other cations from its composition suggest that the mechanism of action of the multicomponent catalyst is defined by the properties of one or several formed modified phases combining all the functions of an effective catalyst. 18 refs., 7 figs., 2 tabs

Nucleation of the lamellar phase from the disordered phase of the renormalized Landau-Brazovskii model

Science.gov (United States)

Carilli, Michael F.; Delaney, Kris T.; Fredrickson, Glenn H.

2018-02-01

Using the zero-temperature string method, we investigate nucleation of a stable lamellar phase from a metastable disordered phase of the renormalized Landau-Brazovskii model at parameters explicitly connected to those of an experimentally accessible diblock copolymer melt. We find anisotropic critical nuclei in qualitative agreement with previous experimental and analytic predictions; we also find good quantitative agreement with the predictions of a single-mode analysis. We conduct a thorough search for critical nuclei containing various predicted and experimentally observed defect structures. The predictions of the renormalized model are assessed by simulating the bare Landau-Brazovskii model with fluctuations. We find that the renormalized model makes reasonable predictions for several important quantities, including the order-disorder transition (ODT). However, the critical nucleus size depends sharply on proximity to the ODT, so even small errors in the ODT predicted by the renormalized model lead to large errors in the predicted critical nucleus size. We conclude that the renormalized model is a poor tool to study nucleation in the fluctuating Landau-Brazovskii model, and recommend that future studies work with the fluctuating bare model directly, using well-chosen collective variables to investigate kinetic pathways in the disorder → lamellar transition.

Phase formation, dielectric and magnetic properties of bismuth ferrite–lead magnesium niobate multiferroic composites

Energy Technology Data Exchange (ETDEWEB)

Wongmaneerung, R., E-mail: re_nok@yahoo.com [Faculty of Science, Maejo University, Chiang Mai 50290 (Thailand); Padchasri, J.; Tipakontitikul, R. [Department of Physics, Ubonratchathani University, Ubonratchathani 31490 (Thailand); Loan, T.H. [International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology, No. 1, Dai Co Viet, Hanoi (Viet Nam); Jantaratana, P. [Department of Physics, Kasetsart University, Bangkok 10900 (Thailand); Yimnirun, R. [School of Physics, Institute of Science, and NANOTEC-SUT Center of Excellence of Advanced Functional Nanomaterials, Suranaree University of Technology, Nakhon Ratchasima 30000 (Thailand); Ananta, S. [Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand)

2014-09-01

Highlights: • A bimodal particle size concept was designed in the production of BF–PMN composites. • A very abnormal diffuse dielectric pattern is observed during the heating process. • BF–PMN composites show highly saturated magnetization. - Abstract: Binary multiferroic composites (1−x)BiFeO{sub 3}–xPb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3} (BF–PMN; x = 0.0–50 wt%) were fabricated through a traditional ceramic process. The effect of the PMN contents on the phase assemblage, microstructure, dielectric and magnetic properties of the samples were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), LCR meter and vibrating sample magnetometer (VSM), respectively. The results indicate that all composites show that perovskite structure and PMN phase is compatible with the BF phase. The microstructure displays the mix phases between BF, PMN, Bi-rich BF and Fe-rich BF phases. Dielectric anomalies of these composites are totally different from BiFeO{sub 3} single phase. Moreover, the dielectric constant is found to increase as the content of PMN decreases. Magnetic transition temperatures are in the range of 270–440 °C. Interestingly, the M–H hysteresis loop measurements indicated that all composites exhibited weak ferromagnetism behavior at room temperature. The maximum remanent magnetization M{sub r} is observed for x = 30 wt% and then decreases when the PMN content is more than 40 wt%.

Preparation and Properties of Paraffin/TiO2/Active-carbon Composite Phase Change Materials

Directory of Open Access Journals (Sweden)

HAO Yong-gan

2016-11-01

Full Text Available A novel composite phase change materials (PCMs of paraffin/TiO2/active-carbon was prepared by a microemulsion method, where paraffin acted as a PCM and titanium dioxide (TiO2 as matrix material, and a small amount of active carbon was added to improve the thermal conductivity. The compositions, morphology and thermal properties of the paraffin/TiO2/active-carbon composite PCMs were characterized by XRD, SEM, TGA and DSC respectively. The shape stability during phase change process of this composite was also tested. The results show that paraffin is well encapsulated by TiO2 matrix, and thus exhibiting excellent shape-stabilized phase change feature. Besides, this composite PCM also presents superhydrophobic property. Therefore, these multifunctional features will endow PCMs with important application potential in energy efficient buildings.

Teaching Advanced Operation of an iPod-Based Speech-Generating Device to Two Students with Autism Spectrum Disorders

Science.gov (United States)

Achmadi, Donna; Kagohara, Debora M.; van der Meer, Larah; O'Reilly, Mark F.; Lancioni, Giulio E.; Sutherland, Dean; Lang, Russell; Marschik, Peter B.; Green, Vanessa A.; Sigafoos, Jeff

2012-01-01

We evaluated a program for teaching two adolescents with autism spectrum disorders (ASD) to perform more advanced operations on an iPod-based speech-generating device (SGD). The effects of the teaching program were evaluated in a multiprobe multiple baseline across participants design that included two intervention phases. The first intervention…

Written Composition Performance of Students with Attention-Deficit/Hyperactivity Disorder

Science.gov (United States)

Casas, Ana Miranda; Ferrer, Manuel Soriano; Fortea, Inmaculada Baixauli

2013-01-01

Attention-deficit/hyperactivity disorder (ADHD) is frequently associated with learning disabilities. The present study examined the written composition of children with ADHD, which depends to a large degree on continuous self-regulation and attentional control skills for organizing information and maintaining the level of effort. Fifty children…

Gauge-field topology in two dimensions: θ-vacuum, topological phases and composite fields

International Nuclear Information System (INIS)

Ilieva, N.; Pervushin, V.N.

1990-06-01

In the framework of the minimal quantization method, the residual 'longitudinal' vacuum dynamics of the Abelian gauge field, that is described by a new pair of canonical variables, is revealed. This dynamics is shown to give origin to the θ-vacuum, thus providing a field analogy of the Josephson effect. The destructive interference of the topological phases - that the fermion fields are shown to acquire - is considered as a reason for the charge screening in the two-dimensional massless QED. (author). 11 refs

Synthesis and characterization of interpenetrating phase ceramic metal composites

International Nuclear Information System (INIS)

Kanwal, T.

2011-01-01

Alumina powder was sintered in MW furnace under vacuum, without vacuum and conventional sintering furnace at different temperatures followed by characterization to observe the effect of sintering mode. Zirconia-Nickel and Alumina-Nickel systems were selected to study the effect of metallic phase interconnectivity on the electrical and thermal behavior in interpenetrating phase composites (IPCs). In order to obtain the homogenous mixture of Alumina and Nick powders, a detailed investigation was performed on the de-agglomeration and prop mixing of powders. Sintering parameters were optimized for the homogenization o Alumina with Nickel in planetary ball mill without sticking of powders with jar.- Homogenization of Zirconia-Nickel and Alumina-Nickel powders was perform using planetary ball mill as well as pestle mortar. Compaction of composites was performed uniaxially and sintering was carried in microwave furnace, tubular furnace with Argon environment and in vacuum sintering furnace. Electrical and thermal behavior of microwave as well as conventionally sintered ZrO/sub 2/-Ni and Al/sub 2/O/sub 3/-Ni IPCs was also observed. Electrical behavior of Composites was characterized b determining the impedance of the composites. To find the percolation limit for both Alumina-Nickel and Zirconia-Nickel composite systems the real part of impedance was used. On the basis of electrical characterization, samples were selected for SEM, BET surface area and CTE analysis. SEM of selected samples was performed t observe the connectivity of Nickel in composites. Finally, the effect of percolation limit on thermal behavior of IPCs was investigated with the help of CTE. (author)

Fabrication and characterization of nanofiber-nanoparticle-composites with phase change materials by electrospinning

International Nuclear Information System (INIS)

Babapoor, Aziz; Karimi, Gholamreza; Khorram, Mohammad

2016-01-01

Highlights: • Form-stable nanofibers with phase change material are produced by electrospinning. • PA6 and PEG are used as the supporting matrix and phase change material. • Various nanoparticles are used to enhance thermal properties of the fibers. • The nanofiber-nanoparticle composites exhibited desirable thermal stability. • Al 2 O 3 nanoparticles improved thermal conductivity of the composites considerably. - Graphical Abstract: Display Omitted - Abstract: Thermal energy storage has been recognized as one of the most important technologies for the utilization of renewable energy sources and conserving energy. In this investigation, through combination of polyethylene glycol (PEG) as a phase change material (PCM), polyamid6 (PA6) and various nanoparticles (SiO 2 , Al 2 O 3 , Fe 2 O 3 and ZnO) as supporting materials, novel form-stable PCMs-based composites were fabricated by single nozzle electrospinning. The structure, morphology and thermal properties of the prepared nanofiber-nanocomposite-enhanced phase change materials (NEPCMs) were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy and differential scanning calorimeter, respectively. Based on the results, nanocomposites-nanofibers were successfully fabricated with high thermal stability and reliability. It is observed that in all composites, the fiber diameter is decreased by increasing the nanoparticles loading. The lowest average diameter obtained was for Fe 2 O 3 composite. Al 2 O 3 composite showed the maximum thermal conductivity enhancement. This study suggests that the fabricated nanocomposite-PCMs offer proper phase transition temperature range and high heat enthalpy values and hence, have potential for thermal energy storage applications.

Phase transitions in two dimensions

International Nuclear Information System (INIS)

Henderson, D.

1980-01-01

Although a two-dimensional solid with long-range translational order cannot existin the thermodynamic limit (N → ∞, V →∞, N/V finite) macroscopic samples of two-dimensional solids can exist. In this work, stability of the phase was determined by the usuar method of equating the pressure and chemical potential of the phases. (A.C.A.S.) [pt

Disordered spinor Bose-Hubbard model

International Nuclear Information System (INIS)

LaPcki, Mateusz; Paganelli, Simone; Ahufinger, Veronica; Sanpera, Anna; Zakrzewski, Jakub

2011-01-01

We study the zero-temperature phase diagram of the disordered spin-1 Bose-Hubbard model in a two-dimensional square lattice. To this aim, we use a mean-field Gutzwiller ansatz and a probabilistic mean-field perturbation theory. The spin interaction induces two different regimes, corresponding to a ferromagnetic and antiferromagnetic order. In the ferromagnetic case, the introduction of disorder reproduces analogous features of the disordered scalar Bose-Hubbard model, consisting in the formation of a Bose glass phase between Mott insulator lobes. In the antiferromagnetic regime, the phase diagram differs more from the scalar case. Disorder in the chemical potential can lead to the disappearance of Mott insulator lobes with an odd-integer filling factor and, for sufficiently strong spin coupling, to Bose glass of singlets between even-filling Mott insulator lobes. Disorder in the spinor coupling parameter results in the appearance of a Bose glass phase only between the n and the n+1 lobes for n odd. Disorder in the scalar Hubbard interaction inhibits Mott insulator regions for occupation larger than a critical value.

Mineral and chemical composition of rock core and surface gas composition in Horonobe Underground Research Laboratory project. Phase 1

International Nuclear Information System (INIS)

Hiraga, Naoto; Ishii, Eiichi

2008-02-01

The following three kinds of analyses were conducted for the 1st phase of the Horonobe Underground Research Laboratory Project. Mineral composition analysis of core sample. Whole rock chemical composition analysis of core sample. Surface gas composition analysis. This document summarizes the results of these analyses. (author)

Dynamic of Ising model with transverse field for two coupled sublattices in disordered phase

International Nuclear Information System (INIS)

Sa Motta, C.E.H. de.

1984-02-01

The dynamics of the two coupled sublattices tridimensional Ising model in a transverse field was studied by means of a continued fraction expansion for coupled operators. The static Correlation Functions necessary for studying the dynamics were calculated with the Green's Functions Method in the Random Phase Approximation (RPA). The spectral function was calculated in the region T c → . (Author) [pt

Phases of variable composition in the system Ba3-xSrxEr(BO3)3 (0≤x≤3.0)

International Nuclear Information System (INIS)

Khamaganova, T.N.

2008-01-01

The possibility of preparing two series of solid solutions in the system Ba 3-x Sr x Er(BO 3 ) 3 (0 ≤ x ≤ 3.0), crystallizing in different structural types, was examined. Samples of the phases of variable composition were synthesized by solid-phase reactions over the temperature range 500-1000 deg C, and their X-ray diffraction characteristics were determined. It is found that the triple phases prepared form two series of substitutional solid solutions in the system studied [ru

Translation-rotation coupling, phase transitions, and elastic phenomena in orientationally disordered crystals

International Nuclear Information System (INIS)

Lynden-Bell, R.M.; Michel, K.H.

1994-01-01

Many of the properties of orientationally disordered crystals are profoundly affected by the coupling (known as translation-rotation coupling) between translation displacements and molecular orientation. The consequences of translation-rotation coupling depend on molecular and crystal symmetry, and vary throughout the Brillouin zone. One result is an indirect coupling between the orientations of different molecules, which plays an important role in the order/disorder phase transition, especially in ionic orientationally disordered crystals. Translation-rotation coupling also leads to softening of elastic constants and affects phonon spectra. This article describes the theory of the coupling from the point of view of the microscopic Hamiltonian and the resulting Landau free energy. Considerable emphasis is placed on the restrictions due to symmetry as these are universal and can be used to help one's qualitative understanding of experimental observations. The application of the theory to phase transitions is described. The softening of elastic constants is discussed and shown to be universal. However, anomalies associated with the order/disorder phase transition are shown to be restricted to cases in which the symmetry of the order parameter satisfies certain conditions. Dynamic effects on phonon spectra are described and finally the recently observed dielectric behavior of ammonium compounds is discussed. Throughout the article examples from published experiments are used to illustrate the application of the theory including well known examples such as the alkali metal cyanides and more recently discovered orientationally disordered crystals such as the fullerite, C 60

Phase composition and magnetic properties in nanocrystalline permanent magnets based on misch-metal

Science.gov (United States)

Ma, Q.; Wang, J.; Zhang, Z. Y.; Zhang, X. F.; Liu, F.; Liu, Y. L.; Jv, X. M.; Li, Y. F.; Wang, G. F.

2017-09-01

The magnetic properties and phase composition of magnets based on misch-metal (MM) with nominal composition of MM13+xFe84-xB6.5 with x = 0.5, 1, 1.5, 2 and 2.5 using melt-spinning method were investigated. For x = 1.5, it could exhibit best magnetic properties (Hcj = 753.02 kA m-1, (BH)max = 70.77 kJ m-3). X-ray diffraction and energy dispersive spectroscopy show that the multi hard magnetic phase of RE2Fe14B (RE = La, Ce, Pr, Nd) existed in the magnets. The domain wall pinning effect and the exchange coupling interaction between grains are dependent on the abnormal RE-rich phase composition. Optimizing the phase constitution is necessary to improve magnetic properties in MM-Fe-B magnets for utilizing the rare earth resource in a balanced manner.

Composite Structure Monitoring using Direct Write Sensors, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — This NASA SBIR Phase II project seeks to develop and demonstrate a suite of sensor products to monitor the health of composite structures. Sensors will be made using...

The design of a two-phase radiolabelled meal for gastric emptying studies

Energy Technology Data Exchange (ETDEWEB)

Mather, S.J.; Ellison, D.; Nightingale, J.; Kamm, M.; Britton, K.E. (Saint Bartholomew' s Hospital, London (UK) St. Marks Hospital, London (UK))

1991-05-01

A meal intended for use in gastric emptying studies must be highly reproducible, must provide a normal physiological stimulus in terms of bulk, calorie content and composition and must employ stable radiotracers which accurately reflect in their biodistribution, the fate of the two-phases. This is particularly important in a field, such as gastric emptying, where so many variables may influence the results. A conventional pancake and orange juice were chosen as suitable vehicles for the solid and liquid phases. {sup 111}In-labelled resin beads were used as the solid-phase marker and a variety of {sup 99}Tc{sup m}-labelled radiopharmaceuticals including pertechnetate, DTPA and colloid forms were investigated as liquid-phase markers. Prior to administration to patients, the stability of the phases and their interactions in vitro were investigated. The use of {sup 99}Tc{sup m}-DTPA resulted in a loss of {sup 111}In from solid to liquid phase. All non-colloidal markers exhibited a tendency for adsorption onto solid phase. Colloidal markers including rhenium and antimony sulphide colloids showed the truest delineation of the liquid phase. (author).

Features of order-disorder phase transformation in nonstoichiometric transition metals carbides

International Nuclear Information System (INIS)

Emel'yanov, A.N.

1996-01-01

Measurements of temperature and electric conductivity of nonstoichiometric transition metals carbides TiC χ and NbC χ in the area of order-disorder phase transformation are carried out. There are certain peculiarities on the temperature and electric conductivity curves of the carbides, connected with the carbon sublattice disordering. On the basis of the anomalies observed on the curves of the temperature conductivity of nonstoichiometric carbides of transition metals above the temperature of the order-disorder transition the existence of the second structural transition is supposed

Organic vapor phase composition of sidestream and environmental tobacco smoke from cigarettes

International Nuclear Information System (INIS)

Higgins, C.E.; Jenkins, R.A.; Guerin, M.R.

1987-01-01

Environmental tobacco smoke (ETS) has received considerable attention because of its contribution to indoor air pollution. While some studies have attempted to estimate the exposure of humans to ETS constituents by extrapolating from information gleaned from investigations of sidestream smoke (SS), few studies have reported a direct comparison between the composition of SS and that of ETS. In the study reported here, the authors describe the relative compositional similarities and differences between the vapor phase of SS and that of ETS. SS was generated under different conditions. Both a new laminar flow chamber, which prevents significant alteration of the near-cigarette environment, and a modified Neurath chamber were used for SS generation. ETS samples were collected from an office environment. Vapor phase samples were collected on multi-media resin sorbent traps and analyzed using thermal desorption gas/liquid chromatography employing flame ionization, nitrogen-specific, and mass selective detection. Influences on the compositional profiles by the manner in which the SS is generated are described, as well as the differences between SS and ETS composition resulting from phase transition

Thermo-fluid dynamics of two-phase flow

CERN Document Server

Ishii, Mamoru; Ishii, Mamoru; Ishii, M

2006-01-01

Provides a very systematic treatment of two phase flow problems from a theoretical perspectiveProvides an easy to follow treatment of modeling and code devlopemnt of two phase flow related phenomenaCovers new results of two phase flow research such as coverage of fuel cells technology.

Surface plasmon resonance induced reduction of high quality Ag/graphene composite at water/toluene phase for reduction of H2O2

International Nuclear Information System (INIS)

Zhang Fengjun; Zhang Kehua; Xie Fazhi; Liu Jin; Dong Hongfei; Zhao Wei; Meng Zeda

2013-01-01

Highlights: ► The Ag/graphene composites have been successfully synthesized in two-phase solvent. ► The surface plasmon resonance of Ag can reduce GO with high deoxygenation and low defect. ► The Ag particles were uniformly distributed on graphene surface. ► The Ag/graphene composites obtained show high superior electrical properties for reduction of H 2 O 2 . - Abstract: Surface plasmon resonance induced synthesis of Ag/graphene composites from Ag/graphene oxide (Ag/GO) in a two-phase (water–toluene) solvent was reported. Transmission electron microscopy (TEM) results revealed that the Ag nanoparticles with size of 5–8 nm were trimly distributed on reduced graphene oxide sheets. Raman and X-ray photoelectron spectroscopy (XPS) have demonstrated low defect density and high deoxygenation degree of graphene in Ag/graphene composite. The excellent structure and morphology of Ag/graphene composites contributed to superior electrical properties for reduction of H 2 O 2 .

Phase Composition Maps integrate mineral compositions with rock textures from the micro-meter to the thin section scale

Science.gov (United States)

Willis, Kyle V.; Srogi, LeeAnn; Lutz, Tim; Monson, Frederick C.; Pollock, Meagen

2017-12-01

Textures and compositions are critical information for interpreting rock formation. Existing methods to integrate both types of information favor high-resolution images of mineral compositions over small areas or low-resolution images of larger areas for phase identification. The method in this paper produces images of individual phases in which textural and compositional details are resolved over three orders of magnitude, from tens of micrometers to tens of millimeters. To construct these images, called Phase Composition Maps (PCMs), we make use of the resolution in backscattered electron (BSE) images and calibrate the gray scale values with mineral analyses by energy-dispersive X-ray spectrometry (EDS). The resulting images show the area of a standard thin section (roughly 40 mm × 20 mm) with spatial resolution as good as 3.5 μm/pixel, or more than 81 000 pixels/mm2, comparable to the resolution of X-ray element maps produced by wavelength-dispersive spectrometry (WDS). Procedures to create PCMs for mafic igneous rocks with multivariate linear regression models for minerals with solid solution (olivine, plagioclase feldspar, and pyroxenes) are presented and are applicable to other rock types. PCMs are processed using threshold functions based on the regression models to image specific composition ranges of minerals. PCMs are constructed using widely-available instrumentation: a scanning-electron microscope (SEM) with BSE and EDS X-ray detectors and standard image processing software such as ImageJ and Adobe Photoshop. Three brief applications illustrate the use of PCMs as petrologic tools: to reveal mineral composition patterns at multiple scales; to generate crystal size distributions for intracrystalline compositional zones and compare growth over time; and to image spatial distributions of minerals at different stages of magma crystallization by integrating textures and compositions with thermodynamic modeling.

Two-phase flow in refrigeration systems

CERN Document Server

Gu, Junjie; Gan, Zhongxue

2013-01-01

Two-Phase Flow in Refrigeration Systems presents recent developments from the authors' extensive research programs on two-phase flow in refrigeration systems. This book covers advanced mass and heat transfer and vapor compression refrigeration systems and shows how the performance of an automotive air-conditioning system is affected through results obtained experimentally and theoretically, specifically with consideration of two-phase flow and oil concentration. The book is ideal for university postgraduate students as a textbook, researchers and professors as an academic reference book, and b

Flexible composite material with phase change thermal storage

Science.gov (United States)

Buckley, Theresa M. (Inventor)

2001-01-01

A highly flexible composite material having a flexible matrix containing a phase change thermal storage material. The composite material can be made to heat or cool the body or to act as a thermal buffer to protect the wearer from changing environmental conditions. The composite may also include an external thermal insulation layer and/or an internal thermal control layer to regulate the rate of heat exchange between the composite and the skin of the wearer. Other embodiments of the PCM composite also provide 1) a path for evaporation or direct absorption of perspiration from the skin of the wearer for improved comfort and thermal control, 2) heat conductive pathways within the material for thermal equalization, 3) surface treatments for improved absorption or rejection of heat by the material, and 4) means for quickly regenerating the thermal storage capacity for reuse of the material. Applications of the composite materials are also described which take advantage of the composite's thermal characteristics. The examples described include a diver's wet suit, ski boot liners, thermal socks, ,gloves and a face mask for cold weather activities, and a metabolic heating or cooling blanket useful for treating hypothermia or fever patients in a medical setting and therapeutic heating or cooling orthopedic joint supports.

Green material composites from renewable resources: Polymorphic transitions and phase diagram of beeswax/rosin resin

Energy Technology Data Exchange (ETDEWEB)

Gaillard, Yves [Mines-ParisTech., CEMEF, UMR CNRS 7635, 1 rue Claude Daunesse 06904 Sophia Antipolis cedex (France); Mija, Alice [University of Nice-Sophia Antipolis, Thermokinetic Group, Laboratory of Chemistry of Organic and Metallic Materials C.M.O.M., 06108 Nice Cedex 2 (France); Burr, Alain; Darque-Ceretti, Evelyne; Felder, Eric [Mines-ParisTech., CEMEF, UMR CNRS 7635, 1 rue Claude Daunesse 06904 Sophia Antipolis cedex (France); Sbirrazzuoli, Nicolas, E-mail: sbirrazz@unice.fr [University of Nice-Sophia Antipolis, Thermokinetic Group, Laboratory of Chemistry of Organic and Metallic Materials C.M.O.M., 06108 Nice Cedex 2 (France)

2011-07-10

Highlights: {yields} Blends of Rosin and beeswax are studied by DSC, XRD, and optical microscopy. {yields} The first phase diagram beeswax/rosin is established. {yields} Polymorphic transitions are identified and appear to be highly related to rosin content. - Abstract: Rosin and beeswax are two complex natural materials presenting numerous applications in paints, adhesives, varnishes or inks. Melted, they are particularly interesting for their adhesion properties. This paper establishes the first phase diagram beeswax/rosin blends. A systematic approach using X-ray diffraction (XRD), differential scanning calorimetry (DSC) and polarised optical microscopy (POM) has been performed in order to describe the crystallographic structure and the thermal properties of two materials, beeswax and rosin, and their blends. Indeed, melting, softening and crystallisation temperatures, polymorphic transitions but also crystalline index has been investigated. The resulting phase diagram reveals a complex behaviour in terms of phase transformation and time-dependent phenomenon mainly representative of the complex composition of beeswax.

FORMATION REGULARITIES OF PHASE COMPOSITION, STRUCTURE AND PROPERTIES DURING MECHANICAL ALLOYING OF BINARY ALUMINUM COMPOSITES

Directory of Open Access Journals (Sweden)

F. G. Lovshenko

2015-01-01

Full Text Available The paper presents investigation results pertaining to  ascertainment of formation regularities of phase composition and structure during mechanical alloying of binary aluminium composites/substances. The invetigations have been executed while applying a wide range of methods, devices and equipment used in modern material science. The obtained data complement each other. It has been established that presence of oxide and hydro-oxide films on aluminium powder  and introduction of surface-active substance in the composite have significant effect on mechanically and thermally activated phase transformations and properties of semi-finished products.  Higher fatty acids have been used as a surface active substance.The mechanism of mechanically activated solid solution formation has been identified. Its essence is  a formation of  specific quasi-solutions at the initial stage of processing. Mechanical and chemical interaction between components during formation of other phases has taken place along with dissolution  in aluminium while processing powder composites. Granule basis is formed according to the dynamic recrystallization mechanism and possess submicrocrystal structural type with the granule dimension basis less than 100 nm and the grains are divided in block size of not more than 20 nm with oxide inclusions of 10–20 nm size.All the compounds  with the addition of  surface-active substances including aluminium powder without alloying elements obtained by processing in mechanic reactor are disperse hardened. In some cases disperse hardening is accompanied by dispersive and solid solution hardnening process. Complex hardening predetermines a high temperature of recrystallization in mechanically alloyed compounds,  its value exceeds 400 °C.

Core-shell particle composition by liquid phase infrared spectroscopy

International Nuclear Information System (INIS)

Ribeiro, Luiz F.B.; Machado, Ricardo A.F.; Goncalves, Odinei H.; Bona, Evandro

2011-01-01

Polymeric particles with core-shell morphology can offer advantages over conventional particles improving properties like mechanical and chemical resistance. However, particle composition must be known due to its influence on the final properties. In this work liquid phase infrared spectroscopy was used to determine the overall composition of core-shell particles composed by polystyrene (core) and poly(methyl methacrylate) (shell). Results were in agreement with those obtained with H 1 Nuclear Magnetic Resonance data (Goncalves et al, 2008). (author)

A Complex Solar Coronal Jet with Two Phases

Energy Technology Data Exchange (ETDEWEB)

Chen, Jie; Su, Jiangtao; Deng, Yuanyong [Key Laboratory of Solar Activity, National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China); Priest, E. R., E-mail: chenjie@bao.ac.cn [Mathematical Institute, University of St Andrews, North Haugh, St Andrews, KY16 9SS (United Kingdom)

2017-05-01

Jets often occur repeatedly from almost the same location. In this paper, a complex solar jet was observed with two phases to the west of NOAA AR 11513 on 2012 July 2. If it had been observed at only moderate resolution, the two phases and their points of origin would have been regarded as identical. However, at high resolution we find that the two phases merge into one another and the accompanying footpoint brightenings occur at different locations. The phases originate from different magnetic patches rather than being one phase originating from the same patch. Photospheric line of sight (LOS) magnetograms show that the bases of the two phases lie in two different patches of magnetic flux that decrease in size during the occurrence of the two phases. Based on these observations, we suggest that the driving mechanism of the two successive phases is magnetic cancellation of two separate magnetic fragments with an opposite-polarity fragment between them.

Experimental research on the influence of system parameters on the composition shift for zeotropic mixture (isobutane/pentane) in a system occurring phase change

International Nuclear Information System (INIS)

Bao, Junjiang; Zhao, Li

2016-01-01

Highlights: • The influence of system parameters on the composition shift for zeotropic mixture is studied. • Zeotropic mixture isobutane/pentane is selected as the working fluids. • Circulating composition and charge have the inverse proportion relationship. • The relationship between circulating composition and charge composition is linear. - Abstract: Zeotropic mixture can improve the performance of the thermodynamic cycle ascribed to the better temperature match during the heat transfer process with the characteristics of temperature glide during evaporation and condensing processes. Another characteristic of zeotropic mixture is composition shift. Composition shift means that the circulating composition and charge composition is different and is mainly caused by the two-phase hold-up and different solubility in lubricating oil. The existence of composition shift will affect the design and operation of thermodynamic system. The previous study gave little information about the influence of system parameters on the composition shift in a system occurring phase change. This paper mainly discuss the influence of system parameters on the composition shift for zeotropic mixture in a system occurring phase change as well as the validation of the linear relationship between the circulating composition and the charge composition and the inverse proportion relationship between the circulating composition and the charge mass found based on our previous theory study (Zhao and Bao, 2014). With isobutane and pentane as the research object, the impact of the key system parameters (hot water temperature, mass flow rate of hot water, feed pump frequency, cold water temperature and evaporator length) on composition shift are experimentally carried out. The results show that when the hot water temperature, mass flow rate of hot water and evaporator length increase and cold water temperature decreases, circulating composition will increase. For feed pump frequency, when

High-performance for hydrogen evolution and pollutant degradation of reduced graphene oxide/two-phase g-C3N4 heterojunction photocatalysts.

Science.gov (United States)

Song, Chengjie; Fan, Mingshan; Shi, Weidong; Wang, Wei

2018-05-01

We have successfully synthesized the composites of two-phase g-C 3 N 4 heterojunction photocatalysts by one-step method. And the reduced graphene oxide/two-phase g-C 3 N 4 heterojunction photocatalyst was fabricated via a facile hydrothermal reduction method. The characterization results indicated that the two-phase g-C 3 N 4 was integrated closely, and the common phenomenon of agglomeration for g-C 3 N 4 was significantly reduced. Moreover, the oxidized graphene was reduced successfully in the composites and the graphene was overlaid on the surface or the interlayers of g-C 3 N 4 heterojunction composite uniformly. In addition, we have carried out the photocatalytic activity experiments by H 2 evolution and rhodamine B removal, tetracycline removal under the visible light irradiation. The results revealed that the composite has improved the separation efficiency a lot than the pure photocatalyst. The photocurrent test demonstrated that the recombination of electrons and holes were efficiently inhibited as well as enhanced the photocatalytic activity. The 0.4% rGO loaded samples, 0.4% rGOCN2, own the best performance. Its rate of H 2 evolution was 15 times as high as that of the pure g-C 3 N 4 .

Qualitative behaviour of incompressible two-phase flows with phase ...

Indian Academy of Sciences (India)

Jan Prüss

2017-11-07

Nov 7, 2017 ... Qualitative behaviour of incompressible two-phase flows with phase ... Germany. 2Graduate School of Human and Environmental Studies, Kyoto University, ... Note that j is a dummy variable as it can be eliminated from the ...

Preparation and characterization of form-stable paraffin/polyurethane composites as phase change materials for thermal energy storage

International Nuclear Information System (INIS)

Chen, Keping; Yu, Xuejiang; Tian, Chunrong; Wang, Jianhua

2014-01-01

Highlights: • Paraffin/polyurethane composite as form-stable phase change material was prepared by bulk polymerization. • Paraffin/polyurethane composite possesses typical character of dual phase transition. • Total latent heat of n-eicosane/PUPCM is as high as 141.2 J/g. • Maximum encapsulation ratio for n-octadecane/PUPCM composites is 25% w/w. - Abstract: Polyurethane phase change material (PUPCM) has been demonstrated to be effective solid–solid phase change material for thermal energy storage. However, the high cost and complex process on preparation of PUPCMs with high enthalpy and broad phase transition temperature range can prohibit industrial-scale applications. In this work, a series of novel form-stable paraffin/PUPCMs composites (n-octadecane/PUPCM, n-eicosane/PUPCM and paraffin wax/PUPCM) with high enthalpy and broad phase transition temperature range (20–65 °C) were directly synthesized via bulk polymerization. The composites were prepared at different mass fractions of n-octadecane (10, 20, 25, 30% w/w). The results indicated that the maximum encapsulation ratio for n-octadecane/PUPCM10000 composites was around 25% w/w. The chemical structure and crystalline properties of these composites were characterized by Fourier transform infrared spectroscopy (FT-IR), polarizing optical microscopy (POM), wide-angle X-ray diffraction (WAXD). Thermal properties and thermal reliability of the composites were determined using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). From DSC analysis, the composites showed a typical dual phase change temperature. The enthalpy for the composite with 25% w/w n-eicosane was as high as 141.2 J/g. TGA analysis indicated that the composites degraded at considerably high temperatures. The process of preparation of PUPCMs and their composites was very simple, inexpensive, environmental friendly and easy to process into desired shapes, which could find the promising applications in solar

Phase separation and shape deformation of two-phase membranes

International Nuclear Information System (INIS)

Jiang, Y.; Lookman, T.; Saxena, A.

2000-01-01

Within a coupled-field Ginzburg-Landau model we study analytically phase separation and accompanying shape deformation on a two-phase elastic membrane in simple geometries such as cylinders, spheres, and tori. Using an exact periodic domain wall solution we solve for the shape and phase separating field, and estimate the degree of deformation of the membrane. The results are pertinent to preferential phase separation in regions of differing curvature on a variety of vesicles. (c) 2000 The American Physical Society

Determination of enthalpy–temperature–composition relations in incongruent-melting phase change materials

International Nuclear Information System (INIS)

Desgrosseilliers, Louis; Allred, Paul; Groulx, Dominic; White, Mary Anne

2013-01-01

This paper demonstrates that liquidus line (T-x) data can be obtained from calorimetric determinations of phase transition enthalpy profiles (H-T) for incongruent-melting phase change materials (PCMs) more efficiently than using traditional cooling curves. An accurate and reliable equilibrium mixture enthalpy model bridges the H-T and T-x gap to provide a full suite of high density H-T-x data to assist latent heat energy storage researchers to evaluate composition-dependent two-phase equilibrium processes. The proposed method is validated for T-history method H-T determinations of 1:1 diluted sodium acetate trihydrate in water, and can also be used with other laboratory calorimetric techniques used to determine the phase transition enthalpy profiles of incongruent-melting compounds. -- Highlights: • H-T data can also be used to obtain valuable liquidus region T-x data. • Applies to all incongruent-melting compounds with known thermodynamic properties. • Reduces the effort and cost of assessing full suite H-T-x data for PCMs. • Uses existing T-x or H-T data of incongruent-melting PCMs to determine the other

Experimental Study about Two-phase Damping Ratio on a Tube Bundle Subjected to Homogeneous Two-phase Flow

Energy Technology Data Exchange (ETDEWEB)

Sim, Woo Gun; Dagdan, Banzragch [Hannam Univ., Daejeon (Korea, Republic of)

2017-03-15

Two-phase cross flow exists in many shell-and-tube heat exchangers such as condensers, evaporators, and nuclear steam generators. The drag force acting on a tube bundle subjected to air/water flow is evaluated experimentally. The cylinders subjected to two-phase flow are arranged in a normal square array. The ratio of pitch to diameter is 1.35, and the diameter of the cylinder is 18 mm. The drag force along the flow direction on the tube bundles is measured to calculate the drag coefficient and the two-phase damping ratio. The two-phase damping ratios, given by the analytical model for a homogeneous two-phase flow, are compared with experimental results. The correlation factor between the frictional pressure drop and the hydraulic drag coefficient is determined from the experimental results. The factor is used to calculate the drag force analytically. It is found that with an increase in the mass flux, the drag force, and the drag coefficients are close to the results given by the homogeneous model. The result shows that the damping ratio can be calculated using the homogeneous model for bubbly flow of sufficiently large mass flux.

Dielectric and piezoelectric properties of percolative three-phase piezoelectric polymer composites

Science.gov (United States)

Sundar, Udhay

Three-phase piezoelectric bulk composites were fabricated using a mix and cast method. The composites were comprised of lead zirconate titanate (PZT), aluminum (Al) and an epoxy matrix. The volume fraction of the PZT and Al were varied from 0.1 to 0.3 and 0.0 to 0.17, respectively. The influences of three entities on piezoelectric and dielectric properties: inclusion of an electrically conductive filler (Al), poling process (contact and Corona) and Al surface treatment, were observed. The piezoelectric strain coefficient, d33, effective dielectric constant, epsilon r, capacitance, C, and resistivity were measured and compared according to poling process, volume fraction of constituent phases and Al surface treatment. The maximum values of d33 were 3.475 and 1.0 pC/N for Corona and contact poled samples respectively, for samples with volume fractions of 0.40 and 0.13 of PZT and Al (surface treated) respectively. Also, the maximum dielectric constant for the surface treated Al samples was 411 for volume fractions of 0.40 and 0.13 for PZT and Al respectively. The percolation threshold was observed to occur at an Al volume fraction of 0.13. The composites achieved a percolated state for Al volume fractions >0.13 for both contact and corona poled samples. In addition, a comparative time study was conducted to examine the influence of surface treatment processing time of Al particles. The effectiveness of the surface treatment, sample morphology and composition was observed with the aid of SEM and EDS images. These images were correlated with piezoelectric and dielectric properties. PZT-epoxy-aluminum thick films (200 mum) were also fabricated using a two-step spin coat deposition and annealing method. The PZT volume fraction were varied from 0.2, 0.3 and 0.4, wherein the Aluminum volume fraction was varied from 0.1 to 0.17 for each PZT volume fraction, respectively. The two-step process included spin coating the first layer at 500 RPM for 30 seconds, and the second

Multifunctional Metal/Polymer Composite Fiber for Space Applications, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — In this Small Business Innovation Research Phase I Program, Syscom Technology, Inc. (STI) will fabricate a metallized multifunctional composite fiber from a...

High dielectric permittivity and improved mechanical and thermal properties of poly(vinylidene fluoride) composites with low carbon nanotube content: effect of composite processing on phase behavior and dielectric properties.

Science.gov (United States)

Kumar, G Sudheer; Vishnupriya, D; Chary, K Suresh; Patro, T Umasankar

2016-09-23

The composite processing technique and nanofiller concentration and its functionalization significantly alter the properties of polymer nanocomposites. To realize this, multi-walled carbon nanotubes (CNT) were dispersed in a poly(vinylidene fluoride) (PVDF) matrix at carefully selected CNT concentrations by two illustrious methods, such as solution-cast and melt-mixing. Notwithstanding the processing method, CNTs induced predominantly the γ-phase in PVDF, instead of the commonly obtained β-phase upon nanofiller incorporation, and imparted significant improvements in dielectric properties. Acid-treatment of CNT improved its dispersion and interfacial adhesion significantly with PVDF, and induced a higher γ-phase content and better dielectric properties in PVDF as compared to pristine CNT. Further, the γ-phase content was found to be higher in solution-cast composites than that in melt-mixed counterparts, most likely due to solvent-induced crystallization in a controlled environment and slow solvent evaporation in the former case. However, interestingly, the melt-mixed composites showed a significantly higher dielectric constant at the onset of the CNT networked-structure as compared to the solution-cast composites. This suggests the possible role of CNT breakage during melt-mixing, which might lead to higher space-charge polarization at the polymer-CNT interface, and in turn an increased number of pseudo-microcapacitors in these composites than the solution-cast counterparts. Notably, PVDF with 0.13 vol% (volume fraction, f c  = 0.0013) of acid-treated CNTs, prepared by melt-mixing, displayed the relative permittivity of ∼217 and capacitance of ∼5430 pF, loss tangent of ∼0.4 at 1 kHz and an unprecedented figure of merit of ∼10(5). We suggest a simple hypothesis for the γ-phase formation and evolution of the high dielectric constant in these composites. Further, the high-dielectric composite film showed marked improvements in mechanical and thermal

Thermal buffering performance of composite phase change materials applied in low-temperature protective garments

Science.gov (United States)

Yang, Kai; Jiao, Mingli; Yu, Yuanyuan; Zhu, Xueying; Liu, Rangtong; Cao, Jian

2017-07-01

Phase change material (PCM) is increasingly being applied in the manufacturing of functional thermo-regulated textiles and garments. This paper investigated the thermal buffering performance of different composite PCMs which are suitable for the application in functional low-temperature protective garments. First, according to the criteria selecting PCM for functional textiles/garments, three kinds of pure PCM were selected as samples, which were n-hexadecane, n-octadecane and n-eicosane. To get the adjustable phase change temperature range and higher phase change enthalpy, three kinds of composite PCM were prepared using the above pure PCM. To evaluate the thermal buffering performance of different composite PCM samples, the simulated low-temperature experiments were performed in the climate chamber, and the skin temperature variation curves in three different low temperature conditions were obtained. Finally composite PCM samples’ thermal buffering time, thermal buffering capacity and thermal buffering efficiency were calculated. Results show that the comprehensive thermal buffering performance of n-octadecane and n-eicosane composite PCM is the best.

Evidence for phase-based psychotherapy as a treatment for dissociative identity disorder comorbid with major depressive disorder and alcohol dependence.

Science.gov (United States)

Pollock, Brianna E; Macfie, Jenny; Elledge, L Christian

2017-01-01

We report on the treatment and successful outcome of a 58-year-old Native American male with a history of complex trauma presenting with dissociative identity disorder (DID) and major depressive disorder. The treatment included a trauma-informed phase-based psychotherapy as recommended by the International Society for the Study of Trauma and Dissociation for treating DID. We assessed symptoms at baseline and at three additional time points over the course of 14 months. We utilized the Reliable Change Index to examine statistically significant change in symptoms over the course of treatment. Significant symptom improvements were realized posttreatment across all measured domains of functioning, including dissociative symptoms, alcohol abuse, depression, anxiety, and emotion regulation skills. Moreover, the client no longer met criteria for DID, major depressive disorder, or alcohol abuse. Results are discussed in terms of the effectiveness of trauma-focused, phase-based treatment for DID for cases of complex trauma with comorbid disorders.

Phase-field modeling of mixing/demixing of regular binary mixtures with a composition-dependent viscosity

Science.gov (United States)

Lamorgese, A.; Mauri, R.

2017-04-01

We simulate the mixing (demixing) process of a quiescent binary liquid mixture with a composition-dependent viscosity which is instantaneously brought from the two-phase (one-phase) to the one-phase (two-phase) region of its phase diagram. Our theoretical approach follows a standard diffuse-interface model of partially miscible regular binary mixtures wherein convection and diffusion are coupled via a nonequilibrium capillary force, expressing the tendency of the phase-separating system to minimize its free energy. Based on 2D simulation results, we discuss the influence of viscosity ratio on basic statistics of the mixing (segregation) process triggered by a rapid heating (quench), assuming that the ratio of capillary to viscous forces (a.k.a. the fluidity coefficient) is large. We show that, for a phase-separating system, at a fixed value of the fluidity coefficient (with the continuous phase viscosity taken as a reference), the separation depth and the characteristic length of single-phase microdomains decrease monotonically for increasing values of the viscosity of the dispersed phase. This variation, however, is quite small, in agreement with experimental results. On the other hand, as one might expect, at a fixed viscosity of the dispersed phase both of the above statistics increase monotonically as the viscosity of the continuous phase decreases. Finally, we show that for a mixing system the attainment of a single-phase equilibrium state by coalescence and diffusion is retarded by an increase in the viscosity ratio at a fixed fluidity for the dispersed phase. In fact, for large enough values of the viscosity ratio, a thin film of the continuous phase becomes apparent when two drops of the minority phase approach each other, which further retards coalescence.

Polyamide–thallium selenide composite materials via temperature and pH controlled adsorption–diffusion method

International Nuclear Information System (INIS)

Ivanauskas, Remigijus; Samardokas, Linas; Mikolajunas, Marius; Virzonis, Darius; Baltrusaitis, Jonas

2014-01-01

Graphical abstract: Single phase polyamide–thallium selenide hybrid functional materials were synthesized for solar energy conversion. - Highlights: • Thallium selenide–polyamide composite materials surfaces synthesized. • Mixed phase composition confirmed by XRD. • Increased temperature resulted in a denser surface packing. • Urbach energies correlated with AFM showing decreased structural disorder. • Annealing in N 2 at 100 °C yielded a single TlSe phase. - Abstract: Composite materials based on III–VI elements are promising in designing efficient photoelectronic devices, such as thin film organic–inorganic solar cells. In this work, TlSe composite materials were synthesized on a model polymer polyamide using temperature and pH controlled adsorption–diffusion method via (a) selenization followed by (b) the exposure to the group III metal (Tl) salt solution and their surface morphological, chemical and crystalline phase information was determined with particular focus on their corresponding structure–optical property relationship. XRD analysis yielded a complex crystalline phase distribution which correlated well with the optical and surface morphological properties measured. pH 11.3 and 80 °C yielded well defined, low structural disorder composite material surface. After annealing in N 2 at 100 °C, polycrystalline PA-Tl x Se y composite materials yielded a single TlSe phase due to the enhanced diffusion and reaction of thallium ions into the polymer. The method described here can be used to synthesize variety of binary III–VI compounds diffused into the polymer at relatively low temperatures and low overall cost, thus providing for a flexible synthesis route for novel composite solar energy harvesting materials

Using ultrasonic measurements and a two-phase composite model to assess radiation damage in reactor pressure vessel steels

International Nuclear Information System (INIS)

Wang, J.A.

1996-01-01

Ultrasonic methods used in the study of radiation damage and recovery in single crystals appear to also be useful for similar studies on polycrystalline alloys. Ultrasonic methods have demonstrated a sensitivity to radiation damage as affected by neutron fluence, irradiation temperature, large changes in composition, and possibly, as well, by neutron energy spectrum. On the microstructure defect evolution, only the residual defects created through the radiation event will contribute to the final macroscopic material property change. From a microstructure point, it is generally accepted that radiation hardening and embrittlement in metals are caused by clusters of vacancies, interstitial, and solute atoms that impede the motion of slip dislocations. Although vacancy-type defects are a major contributor to the material hardening, they also indicate the presence of other interstitial defects. Thus the total volume change of vacancy-type defects before and after irradiation can serve as a direct index to the final material property changes. The volume change of the vacancy-type defects can be determined by utilizing the two -phase composite model (matrix and void-type inclusion) to interpret wave velocities of baseline and irradiated specimens that are obtained from the ultrasonic wave experiment. This is a relatively economic and straightforward procedure. The correlation of the volume change of the vacancy-type defects with the existing destructive mechanical test results may play an important role in the future for the prediction of the radiation embrittlement and remaining plant lifetime, especially for the older plants on the verge of exhausting all the available mechanical test specimens loaded in the surveillance capsules. The above hypothesis was supported by the limited irradiated data analyzed and presented in his paper. The proposed ultrasonic methodology also has a potential application to assess creep damage in fossil power plants

L1{sub 0} phase formation in ternary FePdNi alloys

Energy Technology Data Exchange (ETDEWEB)

Montes-Arango, A.M. [Department of Mechanical and Industrial Engineering, Northeastern University, Boston, MA 02115 (United States); Bordeaux, N.C. [Department of Chemical Engineering, Northeastern University, Boston, MA 02115 (United States); Liu, J.; Barmak, K. [Department of Applied Physics and Applied Mathematics, Columbia University, New York, NY 10027 (United States); Lewis, L.H., E-mail: lhlewis@neu.edu [Department of Mechanical and Industrial Engineering, Northeastern University, Boston, MA 02115 (United States); Department of Chemical Engineering, Northeastern University, Boston, MA 02115 (United States)

2015-11-05

Metallurgical routes to highly metastable phases are required to access new materials with new functionalities. To this end, the stability of the tetragonal chemically ordered L1{sub 0} phase in the ternary Fe–Pd–Ni system is quantified to provide enabling information concerning synthesis of L1{sub 0}-type FeNi, a highly attractive yet highly elusive advanced permanent magnet candidate. Fe{sub 50}Pd{sub 50−x}Ni{sub x} (x = 0–7 at%) samples were arc-melted and annealed at 773 K (500 °C) for 100 h to induce formation of the chemically ordered L1{sub 0} phase. Coupled calorimetry, structural and magnetic investigations allow determination of an isothermal section of the ternary Fe–Pd–Ni phase diagram featuring a single phase L1{sub 0} region near the FePd boundary for x < 6 at%. It is demonstrated that increased Ni content in Fe{sub 50}Pd{sub 50−x}Ni{sub x} alloys systematically decreases the order-disorder transition temperature, resulting in a lower thermodynamic driving force for the ordering phase transformation. The Fe{sub 50}Pd{sub 50−x}Ni{sub x} L1{sub 0} → fcc disordering transformation is determined to occur via a two-step process, with compositionally-dependent enthalpies and transition temperatures. These results highlight the need to investigate ternary alloys with higher Ni content to determine the stability range of the L1{sub 0} phase near the FeNi boundary, thereby facilitating kinetic access to the important L1{sub 0} FeNi ferromagnetic phase. - Highlights: • Chemical ordering in FePdNi enhances intrinsic and extrinsic magnetic properties. • 773 K annealed FePdNi alloys studied show a stable L1{sub 0} phase for Ni ≤ 5.2 at%. • Chemical disordering in FePdNi occurs by a previously unreported two-step process. • Ni additions to FePd dramatically decrease the chemical order-disorder temperature. • The chemical-ordering transformation kinetics are greatly affected by Ni content.

Insight into the Effects of Reinforcement Shape on Achieving Continuous Martensite Transformation in Phase Transforming Matrix Composites

Science.gov (United States)

Zhang, Xudong; Ren, Junqiang; Wang, Xiaofei; Zong, Hongxiang; Cui, Lishan; Ding, Xiangdong

2017-12-01

A continuous martensite transformation is indispensable for achieving large linear superelasticity and low modulus in phase transforming metal-based composites. However, determining how to accurately condition the residual martensite in a shape memory alloy matrix though the reinforcement shape to achieve continuous martensite transformation has been a challenge. Here, we take the finite element method to perform a comparative study of the effects of nanoinclusion shape on the interaction and martensite phase transformation in this new composite. Two typical samples are compared: one reinforced by metallic nanowires and the other by nanoparticles. We find that the residual martensite within the shape memory alloy matrix after a pretreatment can be tailored by the reinforcement shape. In particular, our results show that the shape memory alloy matrix can retain enough residual martensite phases to achieve continuous martensite transformation in the subsequent loading when the aspect ratio of nanoreinforcement is larger than 20. In contrast, the composites reinforced with spherical or low aspect ratio reinforcement show a typical nonlinear superelasticity as a result of a low stress transfer-induced discontinuous martensite transformation within the shape memory alloy matrix.

Measurement of phase interaction in dispersed gas-particle two-phase flow by phase-doppler anemometry

Directory of Open Access Journals (Sweden)

Mergheni Ali Mohamed

2008-01-01

Full Text Available For simultaneous measurement of size and velocity distributions of continuous and dispersed phases in a two-phase flow a technique phase-Doppler anemometry was used. Spherical glass particles with a particle diameter range from 102 up to 212 µm were used. In this two-phase flow an experimental results are presented which indicate a significant influence of the solid particles on the flow characteristics. The height of influence of these effects depends on the local position in the jet. Near the nozzle exit high gas velocity gradients exist and therefore high turbulence production in the shear layer of the jet is observed. Here the turbulence intensity in the two-phase jet is decreased compared to the single-phase jet. In the developed zone the velocity gradient in the shear layer is lower and the turbulence intensity reduction is higher. .

Thermo-Fluid Dynamics of Two-Phase Flow

CERN Document Server

Ishii, Mamrou

2011-01-01

"Thermo-fluid Dynamics of Two-Phase Flow, Second Edition" is focused on the fundamental physics of two-phase flow. The authors present the detailed theoretical foundation of multi-phase flow thermo-fluid dynamics as they apply to: Nuclear reactor transient and accident analysis; Energy systems; Power generation systems; Chemical reactors and process systems; Space propulsion; Transport processes. This edition features updates on two-phase flow formulation and constitutive equations and CFD simulation codes such as FLUENT and CFX, new coverage of the lift force model, which is of part

Biogasification of solid wastes by two-phase anaerobic fermentation

International Nuclear Information System (INIS)

Ghosh, S.; Vieitez, E.R.; Liu, T.; Kato, Y.

1997-01-01

Municipal, industrial and agricultural solid wastes, and biomass deposits, cause large-scale pollution of land and water. Gaseous products of waste decomposition pollute the air and contribute to global warming. This paper describes the development of a two-phase fermentation system that alleviates methanogenic inhibition encountered with high-solids feed, accelerates methane fermentation of the solid bed, and captures methane (renewable energy) for captive use to reduce global warming. The innovative system consisted of a solid bed reactor packed with simulated solid waste at a density of 160 kg/m 3 and operated with recirculation of the percolated culture (bioleachate) through the bed. A rapid onset of solids hydrolysis, acidification, denitrification and hydrogen gas formation was observed under these operating conditions. However, these fermentative reactions stopped at a total fatty acids concentration of 13,000 mg/l (as acetic) at pH 5, with a reactor head-gas composition of 75 percent carbon dioxide, 20 percent nitrogen, 2 percent hydrogen and 3 percent methane. Fermentation inhibition was alleviated by moving the bioleachate to a separate methane-phase fermenter, and recycling methanogenic effluents at pH 7 to the solid bed. Coupled operation of the two reactors promoted methanogenic conversion of the high-solids feed. (author)

Lightweight, High Strength Nano-Composite Magnesium for Radiators, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — In this Phase I SBIR, Terves will develop processing routes to produce high thermal conductivity magnesium composites for use in heat transfer applications such as...

Body composition, symptoms, and survival in advanced cancer patients referred to a phase I service.

Science.gov (United States)

Parsons, Henrique A; Baracos, Vickie E; Dhillon, Navjot; Hong, David S; Kurzrock, Razelle

2012-01-01

Body weight and body composition are relevant to the outcomes of cancer and antineoplastic therapy. However, their role in Phase I clinical trial patients is unknown. We reviewed symptom burden, body composition, and survival in 104 patients with advanced cancer referred to a Phase I oncology service. Symptom burden was analyzed using the MD Anderson Symptom Assessment Inventory(MDASI); body composition was evaluated utilizing computerized tomography(CT) images. A body mass index (BMI)≥25 kg/m² was considered overweight. Sarcopenia, severe muscle depletion, was assessed using CT-based criteria. Most patients were overweight (n = 65, 63%); 53 patients were sarcopenic (51%), including 79% of patients with a BMIbody composition: 215 (71-358) (BMIcancer diagnosis predicted longer survival in multivariate analysis after controlling for age, gender, performance status, and fat index. Patients referred to a Phase I clinic had a high frequency of sarcopenia and a BMI≥25 kg/m², independent of symptom burden. Body composition variables were predictive of clinically relevant survival differences, which is potentially important in developing Phase I studies.

Delayed sleep phase disorder: clinical perspective with a focus on light therapy

Directory of Open Access Journals (Sweden)

Figueiro MG

2016-04-01

Full Text Available Mariana G Figueiro Lighting Research Center, Rensselaer Polytechnic Institute, Troy, NY, USAAbstract: Delayed sleep phase disorder (DSPD is common among adolescents and further increases their susceptibility to chronic sleep restriction and associated detrimental outcomes, including increased risk of depression, drug and alcohol use, behavioral problems, and poor scholastic performance. DSPD is characterized by sleep onset that occurs significantly later than desired bedtimes and societal norms. Individuals with DSPD exhibit long sleep latencies when attempting to sleep at conventional bedtimes. Circadian sleep disorders such as DSPD can occur when there is misalignment between sleep timing and societal norms. This review discusses studies using light therapy to advance the timing of sleep in adolescents and college students, in particular on those suffering from DSPD. A discussion on how to increase effectiveness of light therapy in the field will also be provided.Keywords: circadian, melatonin, light, sleep, sleep phase disorder, adolescents

REVIEWS OF TOPICAL PROBLEMS: Order-disorder transformations and phase equilibria in strongly nonstoichiometric compounds

Science.gov (United States)

Gusev, Aleksandr I.

2000-01-01

Data on order-disorder phase transformations in strongly nonstoichiometric carbides and nitrides MXy (X=C, N) of Group IV and V transition metals at temperatures below 1300-1400 K are reviewed. The order-parameter functional method as applied to atomic and vacancy ordering in strongly nonstoichiometric MXy compounds and to phase equilibrium calculations for M-X systems is discussed. Phase diagram calculations for the Ti-C, Zr-C, Hf-C, V-C, Nb-C, Ta-C, Ti-N, and Ti-B-C systems (with the inclusion of the ordering of nonstoichiometric carbides and nitrides) and those for pseudobinary carbide M(1)C-M(2)C systems are presented. Heat capacity, electrical resistivity and magnetic susceptibility changes at reversible order-disorder phase transformations in nonstoichiometric carbides are considered.

Design, fabrication, and properties of 2-2 connectivity cement/polymer based piezoelectric composites with varied piezoelectric phase distribution

International Nuclear Information System (INIS)

Dongyu, Xu; Xin, Cheng; Shifeng, Huang; Banerjee, Sourav

2014-01-01

The laminated 2-2 connectivity cement/polymer based piezoelectric composites with varied piezoelectric phase distribution were fabricated by employing Lead Zirconium Titanate ceramic as active phase, and mixture of cement powder, epoxy resin, and hardener as matrix phase with a mass proportion of 4:4:1. The dielectric, piezoelectric, and electromechanical coupling properties of the composites were studied. The composites with large total volume fraction of piezoelectric phase have large piezoelectric strain constant and relative permittivity, and the piezoelectric and dielectric properties of the composites are independent of the dimensional variations of the piezoelectric ceramic layer. The composites with small total volume fraction of piezoelectric phase have large piezoelectric voltage constant, but also large dielectric loss. The composite with gradually increased dimension of piezoelectric ceramic layer has the smallest dielectric loss, and that with the gradually increased dimension of matrix layer has the largest piezoelectric voltage constant. The novel piezoelectric composites show potential applications in fabricating ultrasonic transducers with varied surface vibration amplitude of the transducer

Collective Interference of Composite Two-Fermion Bosons

DEFF Research Database (Denmark)

Tichy, Malte; Bouvrie, Peter Alexander; Mølmer, Klaus

2012-01-01

The composite character of two-fermion bosons manifests itself in the interference of many composites as a deviation from the ideal bosonic behavior. A state of many composite bosons can be represented as a superposition of different numbers of perfect bosons and fermions, which allows us...... to provide the full Hong–Ou–Mandel-like counting statistics of interfering composites. Our theory quantitatively relates the deviation from the ideal bosonic interference pattern to the entanglement of the fermions within a single composite boson....

Rapid Construction of Fe-Co-Ni Composition-Phase Map by Combinatorial Materials Chip Approach.

Science.gov (United States)

Xing, Hui; Zhao, Bingbing; Wang, Yujie; Zhang, Xiaoyi; Ren, Yang; Yan, Ningning; Gao, Tieren; Li, Jindong; Zhang, Lanting; Wang, Hong

2018-03-12

One hundred nanometer thick Fe-Co-Ni material chips were prepared and isothermally annealed at 500, 600, and 700 °C, respectively. Pixel-by-pixel composition and structural mapping was performed by microbeam X-ray at synchrotron light source. Diffraction images were recorded at a rate of 1 pattern/s. The XRD patterns were automatically processed, phase-identified, and categorized by hierarchical clustering algorithm to construct the composition-phase map. The resulting maps are consistent with corresponding isothermal sections reported in the ASM Alloy Phase Diagram Database, verifying the effectiveness of the present approach in phase diagram construction.

Nonlinear dynamics of two-phase flow

International Nuclear Information System (INIS)

Rizwan-uddin

1986-01-01

Unstable flow conditions can occur in a wide variety of laboratory and industry equipment that involve two-phase flow. Instabilities in industrial equipment, which include boiling water reactor (BWR) cores, steam generators, heated channels, cryogenic fluid heaters, heat exchangers, etc., are related to their nonlinear dynamics. These instabilities can be of static (Ledinegg instability) or dynamic (density wave oscillations) type. Determination of regions in parameters space where these instabilities can occur and knowledge of system dynamics in or near these regions is essential for the safe operation of such equipment. Many two-phase flow engineering components can be modeled as heated channels. The set of partial differential equations that describes the dynamics of single- and two-phase flow, for the special case of uniform heat flux along the length of the channel, can be reduced to a set of two coupled ordinary differential equations [in inlet velocity v/sub i/(t) and two-phase residence time tau(t)] involving history integrals: a nonlinear ordinary functional differential equation and an integral equation. Hence, to solve these equations, the dependent variables must be specified for -(nu + tau) ≤ t ≤ 0, where nu is the single-phase residence time. This system of nonlinear equations has been solved analytically using asymptotic expansion series for finite but small perturbations and numerically using finite difference techniques

Two-dimensional superconductivity in ultrathin disordered thin films

International Nuclear Information System (INIS)

Beasley, M.R.

1992-01-01

The status of the understanding of two-dimensional superconductivity in ultrathin, disordered thin films is reviewed. The different consequences of microscopic versus macroscopic disorder are stressed. It is shown that microscopic disorder leads to a rapid suppression of the mean-field transition temperature. The consequences of macroscopic disorder are not well understood, but a universal behavior of the zero-bias resistance as a function of field and temperature has been observed. (orig.)

Ion irradiation induced order-to-disorder transformations in δ-phase Sc4-xZr3+xO12+x/2

International Nuclear Information System (INIS)

Zhang, J.; Wang, Y.Q.; Tang, M.; Valdez, J.A.; Sickafus, K.E.

2010-01-01

The purpose of this study is to investigate the role of stoichiometry on crystal structure transformations in derivative fluorite compounds known as delta (δ) phase. In this study, polycrystalline δ-phase ceramic pellets were prepared with stoichiometries given by Sc 4-x Zr 3+x O 12+x/2 (x = 0, 0.77 and 1.20) . The pressed and polished pellets were then irradiated under cryogenic conditions with 200 keV Ne + ions to fluences ranging from 1-5 x 10 14 Ne/cm 2 . An order-to-disorder (O-D) transformation was observed for all compositions, as determined using grazing incidence X-ray diffraction (GIXRD). However, the transformation threshold dose was found to systematically decrease with increasing ZrO 2 content: ∼0.2, ∼0.16, and ∼0.08 dpa for Sc 4-x Zr 3+x O 12+x/2 with x = 0, 0.77, and 1.20, respectively. These irradiation-induced phase transformation results are discussed in terms of the crystal structure of the δ-phase.

Effect of Iron Impurity on the Phase Composition, Structure and Properties of Magnesium Alloys Containing Manganese and Aluminum

Science.gov (United States)

Volkova, E. F.

2017-07-01

Results of a study of the interaction between iron impurity and manganese and aluminum alloying elements during formation of phase composition in alloys of the Mg - Mn, Mg - Al, Mg - Al - Mn, and Mg - Al - Zn - Mn systems are presented. It is proved that this interaction results in introduction of Fe into the intermetallic phase. The phase compositions of model magnesium alloys and commercial alloys MA2-1 and MA5 are studied. It is shown that both manganese and aluminum may bind the iron impurity into phases. Composite Fe-containing intermetallic phases of different compositions influence differently the corrosion resistance of magnesium alloys.

Phase-alternated composite π/2 pulses for solid state quadrupole echo NMR spectroscopy

International Nuclear Information System (INIS)

Ramamoorthy, A.; Narasimhan, P.T.

1991-01-01

Phase-alternated composite π/2 pulses have been constructed for spin I=1 to overcome quadrupole interaction effects in solid state nuclear magnetic resonance(NMR) spectroscopy. Magnus expansion approach is used to design these sequences in a manner similar to the NMR coherent averaging theory. It is inferred that the symmetric phase-alternated composite π/2 pulses reported here are quite successful in producing quadrupole echo free phase distortions. This effectiveness of the present composite pulses is due to the fact that most of them are of shorter durations as compared to the ones reported in literature. In this theoretical procedure, irreducible spherical tensor operator formalism is employed to simplify the complexity involved in the evaluation of Magnus expansion terms. It has been argued in this paper that composite π/2 pulse sequences for this purpose can also be derived from the broadband inversion π pulses which are designed to compensate electric field gradient(efg) inhomogeniety in spin I=1 nuclear quadrupole resonance(NQR) spectroscopy. (author). 28 refs

A review of damping of two-phase flows

International Nuclear Information System (INIS)

Hara, Fumio

1993-01-01

Damping of two-phase flows has been recognized as one of the most unknown parameters in analyzing vibrational characteristics of structures subjected to two-phase flows since it seems to be influenced by many physical parameters involved in the physics of dynamic energy dissipation of a vibrating structure, for example, liquid viscosity, surface tension, flow velocity, mass ratio, frequency, void fraction, flow regime and so forth. This paper deals with a review of scientific works done to date on the damping of two phase flows and discussions about what has been clarified and what has not been known to us, or what kinds of research are needed about two-phase flow damping. The emphasis is put on the definition of two-phase fluid damping, damping measurement techniques, damping characteristics in relation to two phase flow configurations, and damping generation mechanisms

Modelling the transition between fixed and mobile bed conditions in two-phase free-surface flows: The Composite Riemann Problem and its numerical solution

Science.gov (United States)

Rosatti, Giorgio; Zugliani, Daniel

2015-03-01

In a two-phase free-surface flow, the transition from a mobile-bed condition to a fixed-bed one (and vice versa) occurs at a sharp interface across which the relevant system of partial differential equations changes abruptly. This leads to the possibility of conceiving a new type of Riemann Problem (RP), which we have called Composite Riemann Problem (CRP), where not only the initial constant values of the variables but also the system of equations change from left to right of a discontinuity. In this paper, we present a strategy for solving a CRP by reducing it to a standard RP of a single, composite system of equations. This can be obtained by combining the two original systems by means of a suitable weighting function, namely the erodibility variable, and the introduction of an appropriate differential equation for this quantity. In this way, the CRP problem can be analyzed theoretically with standard methods, and the features of the solutions can be clearly identified. In particular, a stationary contact wave is able to correctly describe the sharp transition between mobile- and fixed-bed conditions. A finite volume scheme based on the Multiple Averages Generalized Roe approach (Rosatti and Begnudelli (2013) [22]) was used to numerically solve the fixed-mobile CRP. Several test cases demonstrate the effectiveness, exact well balanceness and high accuracy of the scheme when applied to problems that fall within the physical range of applicability of the relevant mathematical model.

Measurement of phase interaction in dispersed gas-particle two-phase flow by phase-doppler anemometry

OpenAIRE

Mergheni Ali Mohamed; Ben Ticha Hmaied; Sautet Jen-Charles; Godard Gille; Ben Nasrallah Sassi

2008-01-01

For simultaneous measurement of size and velocity distributions of continuous and dispersed phases in a two-phase flow a technique phase-Doppler anemometry was used. Spherical glass particles with a particle diameter range from 102 up to 212 µm were used. In this two-phase flow an experimental results are presented which indicate a significant influence of the solid particles on the flow characteristics. The height of influence of these effects depends on the local position in the jet. Near t...

Polymorphism of 1,2,3-trichloropropane: NQR and DTA study of the ordered and disordered phases

International Nuclear Information System (INIS)

Veglio, N; Zuriaga, M J; Monti, G A

2004-01-01

1,2,3-Trichloropropane was investigated by means of nuclear quadrupole resonance (NQR) and differential thermal analysis (DTA). One amorphous state and two crystalline monotropic phases (forms I and II) were found depending on the thermal history of the sample and only one is stable up to the melting point. The different phases were characterized by 35 Cl NQR. It was concluded that form I is an ordered crystal with only one molecular conformation present in the unit cell while form II is a disordered state with at least two molecules present in the unit cell. In the two crystalline phases, the presence of group reorientations (-CH 2 Cl) and molecule reorientations as a whole can be inferred from 35 Cl spin-lattice relaxation times (T 1 ) with activation energies of 33 and 42 kJ mol -1 , respectively, in form I. In form II, these activation energies are in the range 20-29 kJ mol -1 indicating that this polymorph is less compactly crystalline packed in comparison to form I

Polymorphism of 1,2,3-trichloropropane: NQR and DTA study of the ordered and disordered phases

Science.gov (United States)

Veglio, N.; Zuriaga, M. J.; Monti1, G. A.

2004-11-01

1,2,3-Trichloropropane was investigated by means of nuclear quadrupole resonance (NQR) and differential thermal analysis (DTA). One amorphous state and two crystalline monotropic phases (forms I and II) were found depending on the thermal history of the sample and only one is stable up to the melting point. The different phases were characterized by 35Cl NQR. It was concluded that form I is an ordered crystal with only one molecular conformation present in the unit cell while form II is a disordered state with at least two molecules present in the unit cell. In the two crystalline phases, the presence of group reorientations (-CH2Cl) and molecule reorientations as a whole can be inferred from 35Cl spin-lattice relaxation times (T1) with activation energies of 33 and 42 kJ mol-1, respectively, in form I. In form II, these activation energies are in the range 20-29 kJ mol-1 indicating that this polymorph is less compactly crystalline packed in comparison to form I.

A new approach to establish both stable and metastable phase equilibria for fcc ordered/disordered phase transition: application to the Al–Ni and Ni–Si systems

International Nuclear Information System (INIS)

Yuan Xiaoming; Zhang Lijun; Du Yong; Xiong Wei; Tang Ying; Wang Aijun; Liu Shuhong

2012-01-01

Both two-sublattice (2SL) and four-sublattice (4SL) models in the framework of the compound energy formalism can be used to describe the fcc ordered/disordered transitions. When transferring the parameters of 2SL disregarding the metastable ordered states into those of 4SL, inconsistence in either stable or metastable phase diagrams could appear, as detected in both Al–Ni and Ni–Si systems. To avoid such a kind of drawback, this behavior was analyzed and investigated in the Ni–Si and Al–Ni systems with the aid of first–principle calculations. Furthermore, a new approach considering both the stable and metastable fcc ordered phase equilibria deduced from the first–principles calculations was proposed to perform a reliable thermodynamic modeling for the fcc ordered/disordered transition. The Ni–Si system was then thermodynamically assessed using the presently proposed approach. The good agreement between the calculation and experiments demonstrates the reliability of the proposed approach. It is expected that the approach is valid for other systems showing complex ordered/disordered transitions. - Highlights: ► We discuss the drawbacks of order/disorder modeling in the Ni–Si and Al–Ni systems. ► We perform ab initio calculation of thermodynamic properties in the Ni–Si system. ► A CALPHAD–type approach is proposed to model the fcc ordered/disordered transition. ► The Ni–Si system was thermodynamically assessed using the new approach.

Phase behavior of random copolymers in quenched random media

International Nuclear Information System (INIS)

Chakraborty, A.K.; Shakhnovich, E.I.

1995-01-01

In this paper, we consider the behavior of random heteropolymers in a quenched disordered medium. We develop a field theory and obtain a mean-field solution that allows for replica symmetry breaking. The presence of an external disorder leads to the formation of compact states; a homopolymeric effect. We compute the phase diagram for two classes of problems. First, we consider the situation wherein the bare heteropolymer prefers like segments to segregate, and second, we examine cases where the bare heteropolymer prefers unlike segments to mix. For the first class of systems, we find a phase diagram characterized by a replica symmetry broken phase that exists below a particular temperature. This temperature grows with the strength of the external disorder. In the second class of situations, the phase diagram is much richer. Here we find two replica symmetry broken phases with different patterns separated by a reentrant phase. The reentrant phase and one of the two replica symmetry broken phases are induced by interactions with the external disorder. The dependence of the location of the phase boundaries on the strength of the external disorder are elucidated. We discuss our results from a physical standpoint, and note the testable experimental consequences of our findings. copyright 1995 American Institute of Physics

Two-phase systems. Fundamentals and industrial applications

International Nuclear Information System (INIS)

Woillez, Jacques

2014-01-01

Two-phase flows are omnipresent in industrial processes in different sectors with the behaviour and control of non-mixing mixtures of gas and liquids, of several liquids, of solids and fluids which are present in the production of raw materials, in the environment, in energy production, in chemistry, in pharmaceutical or food industry. The author presents the fundamentals elements which are needed to perform hardware predictive calculations and to understand typical phenomena associated with these flows. The chapters address fluids mechanics (movement equations, Bernoulli equation, load losses, turbulence, heat exchange coefficients, thermodynamics, compressible flows), two-phase systems (characteristic values, modes of appearance of two-phase flows, conduct flows, suspension mechanics, mass transfers, similarity, numerical simulation), the applications (energy production, agitation and mixing, phase separation, sprays), and peculiar phenomena (Marangoni effect, the tea cup effect, entry jets, water hammer effect, sound speed, two-phase pumping, fluidization)

Elastic wave localization in two-dimensional phononic crystals with one-dimensional random disorder and aperiodicity

International Nuclear Information System (INIS)

Yan Zhizhong; Zhang Chuanzeng; Wang Yuesheng

2011-01-01

The band structures of in-plane elastic waves propagating in two-dimensional phononic crystals with one-dimensional random disorder and aperiodicity are analyzed in this paper. The localization of wave propagation is discussed by introducing the concept of the localization factor, which is calculated by the plane-wave-based transfer-matrix method. By treating the random disorder and aperiodicity as the deviation from the periodicity in a special way, three kinds of aperiodic phononic crystals that have normally distributed random disorder, Thue-Morse and Rudin-Shapiro sequence in one direction and translational symmetry in the other direction are considered and the band structures are characterized using localization factors. Besides, as a special case, we analyze the band gap properties of a periodic planar layered composite containing a periodic array of square inclusions. The transmission coefficients based on eigen-mode matching theory are also calculated and the results show the same behaviors as the localization factor does. In the case of random disorders, the localization degree of the normally distributed random disorder is larger than that of the uniformly distributed random disorder although the eigenstates are both localized no matter what types of random disorders, whereas, for the case of Thue-Morse and Rudin-Shapiro structures, the band structures of Thue-Morse sequence exhibit similarities with the quasi-periodic (Fibonacci) sequence not present in the results of the Rudin-Shapiro sequence.

Designing dual phase sensing materials from polyaniline filled styrene–isoprene–styrene composites

International Nuclear Information System (INIS)

Sadasivuni, Kishor Kumar; Ponnamma, Deepalekshmi; Kasak, Peter; Krupa, Igor; Ali S A Al-Maadeed, Mariam

2014-01-01

The demand for developing oil detectors is ever increasing since the cleanup and recovery from oil spill usually take long time. Here we propose oil sensors made of polyaniline (PANI) filled poly(styrene–isoprene–styrene) (SIS) block copolymer composite films with good uniformity and dispersion. The changes in resistivity of the samples in presence of both oil and water media reveal the good sensing ability of SIS–PANI films towards oil in water (dual phase). The morphology and chemical composition of the developed products are characterized by scanning electron microscopy and Fourier transformation infrared spectroscopy. Swelling studies are performed to correlate the sensing response to the structural variations and based on it a mechanism is derived for the dual phase sensing. Contact angle measurements confirm the behavior further. The thermal properties and crystallinity of the composites are also addressed by the thermogravimetric and differential scanning calorimetric studies. The developed oil sensor material is able to withstand extreme temperature condition as well. - Highlights: • We model a dual phase sensor capable of detecting oil in water. • A mechanism is proposed to correlate sensing with diffusion. • In situ polymerization helps in the uniform distribution of filler. • Polymer composite sensor could be used as stickers on oil pipelines

Designing dual phase sensing materials from polyaniline filled styrene–isoprene–styrene composites

Energy Technology Data Exchange (ETDEWEB)

Sadasivuni, Kishor Kumar, E-mail: kishor_kumars@yahoo.com [Centre for Advanced Materials, Qatar University, Doha (Qatar); Ponnamma, Deepalekshmi [School of Chemical Sciences, Mahatma Gandhi University, Kottayam 686560, Kerala (India); Kasak, Peter; Krupa, Igor; Ali S A Al-Maadeed, Mariam [Centre for Advanced Materials, Qatar University, Doha (Qatar)

2014-10-15

The demand for developing oil detectors is ever increasing since the cleanup and recovery from oil spill usually take long time. Here we propose oil sensors made of polyaniline (PANI) filled poly(styrene–isoprene–styrene) (SIS) block copolymer composite films with good uniformity and dispersion. The changes in resistivity of the samples in presence of both oil and water media reveal the good sensing ability of SIS–PANI films towards oil in water (dual phase). The morphology and chemical composition of the developed products are characterized by scanning electron microscopy and Fourier transformation infrared spectroscopy. Swelling studies are performed to correlate the sensing response to the structural variations and based on it a mechanism is derived for the dual phase sensing. Contact angle measurements confirm the behavior further. The thermal properties and crystallinity of the composites are also addressed by the thermogravimetric and differential scanning calorimetric studies. The developed oil sensor material is able to withstand extreme temperature condition as well. - Highlights: • We model a dual phase sensor capable of detecting oil in water. • A mechanism is proposed to correlate sensing with diffusion. • In situ polymerization helps in the uniform distribution of filler. • Polymer composite sensor could be used as stickers on oil pipelines.

Phase Defects as a Measure of Disorder in Traveling-Wave Convection

International Nuclear Information System (INIS)

La Porta, A.; Surko, C.M.

1996-01-01

Spatiotemporal disorder is studied in traveling-wave convection in an ethanol-water mixture. A technique for calculating the complex order parameter of the pattern is described, and the identification of phase defects is demonstrated. Point defects, domain boundaries, and standing wave patterns are shown to produce unique defect structures. The transition from a disordered state to a more ordered pattern is described in terms of the dynamics of defects and their statistics. copyright 1996 The American Physical Society

Preparation and thermal properties characterization of carbonate salt/carbon nanomaterial composite phase change material

International Nuclear Information System (INIS)

Tao, Y.B.; Lin, C.H.; He, Y.L.

2015-01-01

Highlights: • Nanocomposite phase change materials were prepared and characterized. • Larger specific surface area is more efficient to enhance specific heat. • Columnar structure is more efficient to enhance thermal conductivity. • Thermal conductivity enhancement is the key. • Single walled carbon nanotube is the optimal nanomaterial additive. - Abstract: To enhance the performance of high temperature salt phase change material, four kinds of carbon nanomaterials with different microstructures were mixed into binary carbonate eutectic salts to prepare carbonate salt/nanomaterial composite phase change material. The microstructures of the nanomaterial and composite phase change material were characterized by scanning electron microscope. The thermal properties such as melting point, melting enthalpy, specific heat, thermal conductivity and total thermal energy storage capacity were characterized. The results show that the nanomaterial microstructure has great effects on composite phase change material thermal properties. The sheet structure Graphene is the best additive to enhance specific heat, which could be enhanced up to 18.57%. The single walled carbon nanotube with columnar structure is the best additive to enhance thermal conductivity, which could be enhanced up to 56.98%. Melting point increases but melting enthalpy decreases with nanomaterial specific surface area increase. Although the additives decrease the melting enthalpy of composite phase change material, they also enhance the specific heat. As a combined result, the additives have little effects on thermal energy storage capacity. So, for phase change material performance enhancement, more emphasis should be placed on thermal conductivity enhancement and single walled carbon nanotube is the optimal nanomaterial additive

Polyamide–thallium selenide composite materials via temperature and pH controlled adsorption–diffusion method

Energy Technology Data Exchange (ETDEWEB)

Ivanauskas, Remigijus; Samardokas, Linas [Department of Physical and Inorganic Chemistry, Kaunas University of Technology, Radvilenu str. 19, Kaunas LT-50254 (Lithuania); Mikolajunas, Marius; Virzonis, Darius [Department of Technology, Kaunas University of Technology, Panevezys Faculty, Daukanto 12, 35212 Panevezys (Lithuania); Baltrusaitis, Jonas, E-mail: job314@lehigh.edu [Department of Chemical and Biomolecular Engineering, Lehigh University, B336 Iacocca Hall, 111 Research Drive, Bethlehem, PA 18015 (United States)

2014-10-30

Graphical abstract: Single phase polyamide–thallium selenide hybrid functional materials were synthesized for solar energy conversion. - Highlights: • Thallium selenide–polyamide composite materials surfaces synthesized. • Mixed phase composition confirmed by XRD. • Increased temperature resulted in a denser surface packing. • Urbach energies correlated with AFM showing decreased structural disorder. • Annealing in N{sub 2} at 100 °C yielded a single TlSe phase. - Abstract: Composite materials based on III–VI elements are promising in designing efficient photoelectronic devices, such as thin film organic–inorganic solar cells. In this work, TlSe composite materials were synthesized on a model polymer polyamide using temperature and pH controlled adsorption–diffusion method via (a) selenization followed by (b) the exposure to the group III metal (Tl) salt solution and their surface morphological, chemical and crystalline phase information was determined with particular focus on their corresponding structure–optical property relationship. XRD analysis yielded a complex crystalline phase distribution which correlated well with the optical and surface morphological properties measured. pH 11.3 and 80 °C yielded well defined, low structural disorder composite material surface. After annealing in N{sub 2} at 100 °C, polycrystalline PA-Tl{sub x}Se{sub y} composite materials yielded a single TlSe phase due to the enhanced diffusion and reaction of thallium ions into the polymer. The method described here can be used to synthesize variety of binary III–VI compounds diffused into the polymer at relatively low temperatures and low overall cost, thus providing for a flexible synthesis route for novel composite solar energy harvesting materials.

Comparison of two-step versus four-step composite finishing/polishing disc systems: evaluation of a new two-step composite polishing disc system.

Science.gov (United States)

da Costa, Juliana B; Goncalves, Flavia; Ferracane, Jack L

2011-01-01

The purpose of this study was to evaluate surface finish and gloss of a two-step composite finishing/polishing (F/P) disc system compared with two multistep systems on five composites. Seventy-five disc-shaped composite specimens (D=10.0 mm, 2 mm thick, n=15 per composite) were made of microfill (Durafill-D), nanofill (Filtek Supreme-FS), nanohybrid (Premise-PR), and microhybrids (Filtek Z250-FZ, Esthet-EX). One side of each specimen was initially finished with a carbide bur. Five specimens of each resin composite were randomly assigned to receive full F/P by each of the disc systems: two-step (Enhance Flex NST-EF) and four-step (Sof-Lex-SL, Super-Snap-SS). Surface gloss was measured with a glossmeter and surface roughness was measured with a profilometer. Results were analyzed by two-way analysis of variance (ANOVA)/Tukey's (αgloss was noted among the three F/P systems when used with D and EX; no difference between SL and EF when used with any composite, except for FS; and no difference between SL and SS when used with any composite. SL and EF showed similar surface roughness when used on all composites, except for EX. EF and SS showed similar surface roughness on PR. SL and SS showed similar surface roughness values on every composite, except for FZ. EF was capable of providing similar gloss and surface roughness to SL on four composites evaluated but was not able to produce as glossy or as smooth a surface as SS for three of the five composites.

Associations between Body Composition Indices and Metabolic Disorders in Chinese Adults: A Cross-Sectional Observational Study

Directory of Open Access Journals (Sweden)

Rong Zhang

2018-01-01

Conclusions: This study identified positive associations between all evaluated body composition indices and metabolic parameters in Chinese adults. Among the body composition indices, BMI predicted four of the five evaluated metabolic disorders in both gender groups.

Two-Order-Parameter Description of Liquids: Critical Phenomena and Phase Separation of Supercooled Liquids

OpenAIRE

Tanaka, Hajime

1997-01-01

Because of the isotropic and disordered nature of liquids, the anisotropy hidden in intermolecular interactions are often neglected. Accordingly, the order parameter describing a simple liquid has so far been believed to be only density. In contrast to this common sense, we propose that two order parameters, namely, density and bond order parameters, are required to describe the phase behavior of liquids since they intrinsically tend to form local bonds. This model gives us clear physical exp...

Determination of γ′+γ / γ Phase Boundary in Ni-Al-Cr System Using DTA Thermal Analysis

Directory of Open Access Journals (Sweden)

Maciąg T.

2016-03-01

Full Text Available Mechanical properties at elevated temperature, in modern alloys based on intermetallic phase Ni3Al are connected with phase composition, especially with proportion of ordered phase γ′ (L12 and disordered phase γ (A1. In this paper, analysis of one key systems for mentioned alloys - Ni-Al-Cr, is presented. A series of alloys with chemical composition originated from Ni-rich part of Ni-Al-Cr system was prepared. DTA thermal analysis was performed on all samples. Based on shape of obtained curves, characteristic for continuous order-disorder transition, places of course of phase boundaries γ′+γ / γ were determined. Moreover, temperature of melting and freezing of alloys were obtained. Results of DTA analysis concerning phase boundary γ′+γ / γ indicated agreement with results obtained by authors using calorimetric solution method.

Programming scale-free optics in disordered ferroelectrics.

Science.gov (United States)

Parravicini, Jacopo; Conti, Claudio; Agranat, Aharon J; DelRe, Eugenio

2012-06-15

Using the history dependence of a dipolar glass hosted in a compositionally disordered lithium-enriched potassium tantalate niobate (KTN:Li) crystal, we demonstrate scale-free optical propagation at tunable temperatures. The operating equilibration temperature is determined by previous crystal spiralling in the temperature/cooling-rate phase space.

Programming scale-free optics in disordered ferroelectrics

OpenAIRE

Parravicini, Jacopo; Conti, Claudio; Agranat, Aharon J.; DelRe, Eugenio

2012-01-01

Using the history-dependence of a dipolar glass hosted in a compositionally-disordered lithium-enriched potassium-tantalate-niobate (KTN:Li) crystal, we demonstrate scale-free optical propagation at tunable temperatures. The operating equilibration temperature is determined by previous crystal spiralling in the temperature/cooling-rate phase-space.

Review of two-phase instabilities

Energy Technology Data Exchange (ETDEWEB)

Kang, Han Ok; Seo, Han Ok; Kang, Hyung Suk; Cho, Bong Hyun; Lee, Doo Jeong

1997-06-01

KAERI is carrying out a development of the design for a new type of integral reactors. The once-through helical steam generator is important design features. The study on designs and operating conditions which prevent flow instability should precede the introduction of one-through steam generator. Experiments are currently scheduled to understand two-phase instability, evaluate the effect of each design parameter on the critical point, and determine proper inlet throttling for the prevention of instability. This report covers general two-phase instability with review of existing studies on this topics. The general classification of two phase flow instability and the characteristics of each type of instability are first described. Special attention is paid to BWR core flow instability and once-through steam generator instability. The reactivity feedback and the effect of system parameters are treated mainly for BWR. With relation to once-through steam generators, the characteristics of convective heating and dryout point oscillation are first investigated and then the existing experimental studies are summarized. Finally chapter summarized the proposed correlations for instability boundary conditions. (author). 231 refs., 5 tabs., 47 figs

Analysis of water hammer in two-component two-phase flows

International Nuclear Information System (INIS)

Warde, H.; Marzouk, E.; Ibrahim, S.

1989-01-01

The water hammer phenomena caused by a sudden valve closure in air-water two-phase flows must be clarified for the safety analysis of LOCA in reactors and further for the safety of boilers, chemical plants, pipe transport of fluids such as petroleum and natural gas. In the present work water hammer phenomena caused by sudden valve closure in two-component two-phase flows are investigated theoretically and experimentally. The phenomena are more complicated than in single phase-flows due to the fact of the presence of compressible component. Basic partial differential equations based on a one-dimensional homogeneous flow model are solved by the method of characteristic. The analysis is extended to include friction in a two-phase mixture depending on the local flow pattern. The profiles of the pressure transients, the propagation velocity of pressure waves and the effect of valve closure on the transient pressure are found. Different two-phase flow pattern and frictional pressure drop correlations were used including Baker, Chesholm and Beggs and Bril correlations. The effect of the flow pattern on the characteristic of wave propagation is discussed primarily to indicate the effect of void fraction on the velocity of wave propagation and on the attenuation of pressure waves. Transient pressure in the mixture were recorded at different air void fractions, rates of uniform valve closure and liquid flow velocities with the aid of pressure transducers, transient wave form recorders interfaced with an on-line pc computer. The results are compared with computation, and good agreement was obtained within experimental accuracy

Order-disorder antiferroelectric phase transition in a hybrid inorganic-organic framework with the perovskite architecture.

Science.gov (United States)

Jain, Prashant; Dalal, Naresh S; Toby, Brian H; Kroto, Harold W; Cheetham, Anthony K

2008-08-13

[(CH3)2NH2]Zn(HCOO)3, 1, adopts a structure that is analogous to that of a traditional perovskite, ABX3, with A = [(CH3)2NH2], B = Zn, and X = HCOO. The hydrogen atoms of the dimethyl ammonium cation, which hydrogen bond to oxygen atoms of the formate framework, are disordered at room temperature. X-ray powder diffraction, dielectric constant, and specific heat data show that 1 undergoes an order-disorder phase transition on cooling below 156 K. We present evidence that this is a classical paraelectric to antiferroelectric phase transition that is driven by ordering of the hydrogen atoms. This sort of electrical ordering associated with order-disorder phase transition is unprecedented in hybrid frameworks and opens up an exciting new direction in rational synthetic strategies to create extended hybrid networks for applications in ferroic-related fields.

Phase composition of rapidly solidified Ag-Sn-Cu dental alloys

International Nuclear Information System (INIS)

Lecong Dzuong; Do Minh Nghiep; Nguyen van Dzan; Cao the Ha

1996-01-01

The phase composition of some rapidly solidified Ag-Sn-Cu dental alloys with different copper contents (6.22 wtpct) has been studied by XRD, EMPA and optical microscopy. The samples were prepared from melt-spun ribbons. The microstructure of the as-quenched ribbons was microcrystalline and consisted of the Ag sub 3 Sn, Ag sub 4 Sn, Cu sub 3 Sn and Cu sub 3 Sn sub 8 phases. Mixing with mercury (amalgamation) led to formation of the Ag sub 2 Hg sub 3, Sn sub 7 Hg and Cu sub 6 Sn sub 5 phases. The amount of copper atoms in the alloys played an important role in phase formation in the amalgams

Magnetic liquid metal two-phase flow research. Phase 1. Final report

International Nuclear Information System (INIS)

Graves, R.D.

1983-04-01

The Phase I research demonstrates the feasibility of the magnetic liquid metal (MLM) two-phase flow concept. A dispersion analysis is presented based on a complete set of two-phase-flow equations augmented to include stresses due to magnetic polarization of the fluid. The analysis shows that the stability of the MLM two-phase flow is determined by the magnetic Mach number, the slip ratio, geometry of the flow relative to the applied magnetic field, and by the voidage dependence of the interfacial forces. Results of a set of experiments concerned with magnetic effects on the dynamics of single bubble motion in an aqueous-based, viscous, conducting magnetic fluid are presented. Predictions in the theoretical literature are qualitatively verified using a bench-top experimental apparatus. In particular, applied magnetic fields are seen to lead to reduced bubble size at fixed generating orifice pressure

Composite phase change materials prepared by encapsuling paraffin in PVC macrocapsules

International Nuclear Information System (INIS)

Chen, Yingbo; Zhang, Shifeng; Zhang, Qi; Chen, Yusheng; Zhang, Yufeng

2014-01-01

Highlights: • PVC macrocapsules coated with SiO 2 were synthesized. • Paraffin was encapsuled in the capsules. • The composite PCM has high heat capacity. • The composite PCM has no surpercooling. - Abstract: A novel phase change material capsules with SiO 2 in their surface was prepared by absorbing paraffin into PVC hollow capsules and by the polycondensation reaction of TEOS in different conditions. X-ray photoelectron spectroscopy (XPS) analysis and scanning electronic microscope (SEM) were used to determine chemical composition and microstructure of the composite capsules, respectively. Enthalpy capacity and thermal stability of the composite capsules are systematically characterized by using differential scanning calorimeter (DSC), thermogravimetric analyzer (TGA) and thermocycling tests. The composite has high heat capacity with good stability and absence of supercooling phenomena

The risk of eating disorders and bone health in young adults: the mediating role of body composition and fitness.

Science.gov (United States)

Garrido-Miguel, Miriam; Torres-Costoso, Ana; Martínez-Andrés, María; Notario-Pacheco, Blanca; Díez-Fernández, Ana; Álvarez-Bueno, Celia; García-Prieto, Jorge Cañete; Martínez-Vizcaíno, Vicente

2017-11-13

To analyze the independent relationship between the risk of eating disorders and bone health and to examine whether this relationship is mediated by body composition and cardiorespiratory fitness (CRF). In this cross-sectional study, bone-related variables, lean mass, fat mass (by DXA), risk of eating disorders (SCOFF questionnaire), height, weight, waist circumference and CRF were measured in 487 university students aged 18-30 years from the University of Castilla-La Mancha, Spain. ANCOVA models were estimated to test mean differences in bone mass categorized by body composition, CRF or risk of eating disorders. Subsequently, linear regression models were fitted according to Baron and Kenny's procedures for mediation analysis. The marginal estimated mean ± SE values of total body bone mineral density for the categories "no risk of eating disorders" and "risk of eating disorders" were 1.239 ± 0.126 eating disorders and bone health in young adults. Body composition and CRF mediate the association between the risk of eating disorders and bone health. These findings highlight the importance of maintaining a healthy weight and good CRF for the prevention of the development of eating disorders and for the maintenance of good bone health in young adults. Level V, cross-sectional descriptive study.

Two-phase flow in fractured rock

International Nuclear Information System (INIS)

Davies, P.; Long, J.; Zuidema, P.

1993-11-01

This report gives the results of a three-day workshop on two-phase flow in fractured rock. The workshop focused on two-phase flow processes that are important in geologic disposal of nuclear waste as experienced in a variety of repository settings. The goals and objectives of the workshop were threefold: exchange information; describe the current state of understanding; and identify research needs. The participants were divided into four subgroups. Each group was asked to address a series of two-phase flow processes. The following groups were defined to address these processes: basic flow processes; fracture/matrix interactions; complex flow processes; and coupled processes. For each process, the groups were asked to address these four issues: (1) describe the two-phase flow processes that are important with respect to repository performance; (2) describe how this process relates to the specific driving programmatic issues given above for nuclear waste storage; (3) evaluate the state of understanding for these processes; and (4) suggest additional research to address poorly understood processes relevant to repository performance. The reports from each of the four working groups are given here

Industrial aspects of gas-liquid two-phase flow

International Nuclear Information System (INIS)

Hewitt, G.F.

1977-01-01

The lecture begins by reviewing the various types of plant in which two phase flow occurs. Specifically, boiling plant, condensing plant and pipelines are reviewed, and the various two phase flow problems occurring in them are described. Of course, many other kinds of chemical engineering plant involve two phase flow, but are somewhat outside the scope of this lecture. This would include distillation columns, vapor-liquid separators, absorption towers etc. Other areas of industrial two phase flow which have been omitted for space reasons from this lecture are those concerned with gas/solids, liquid/solid and liquid/liquid flows. There then follows a description of some of the two phase flow processes which are relevant in industrial equipment and where special problems occur. The topics chosen are as follows: (1) pressure drop; (2) horizontal tubes - separation effects non-uniformites in heat transfer coefficient, effect of bends on dryout; (3) multicomponent mixtures - effects in pool boiling, mass transfer effects in condensation and Marangoni effects; (4) flow distribution - manifold problems in single phase flow, separation effects at a single T-junction in two phase flow and distribution in manifolds in two phase flow; (5) instability - oscillatory instability, special forms of instability in cryogenic systems; (6) nucleate boiling - effect of variability of surface, unresolved problems in forced convective nucleate boiling; and (7) shell side flows - flow patterns, cross flow boiling, condensation in cross flow

Fabrication of fiber composites with a MAX phase matrix by reactive melt infiltration

International Nuclear Information System (INIS)

Lenz, F; Krenkel, W

2011-01-01

Due to the inherent brittleness of ceramics it is very desirable to increase the damage tolerance of ceramics. The ternary MAX phases are a promising group of materials with high fracture toughness. The topic of this study is the development of ceramic matrix composites (CMCs) with a matrix containing MAX phases, to achieve a damage tolerant structural composite material. For this purpose carbon fiber reinforced preforms with a carbon-titanium carbide matrix (C/C-TiC) were developed and infiltrated with silicon by a pressureless reactive melt infiltration. Finally liquid silicon caused the formation of SiC, TiSi 2 and Ti 3 SiC 2 in the matrix of the composite.

Dynamic Modeling of Phase Crossings in Two-Phase Flow

DEFF Research Database (Denmark)

Madsen, Søren; Veje, Christian; Willatzen, Morten

2012-01-01

by a high resolution finite difference scheme due to Kurganov and Tadmore. The homogeneous formulation requires a set of thermodynamic relations to cover the entire range from liquid to gas state. This leads a number of numerical challenges since these relations introduce discontinuities in the derivative...... of the variables and are usually very slow to evaluate. To overcome these challenges, we use an interpolation scheme with local refinement. The simulations show that the method handles crossing of the saturation lines for both liquid to two-phase and two-phase to gas regions. Furthermore, a novel result obtained...

The geometric phase in two-level atomic systems

International Nuclear Information System (INIS)

Tian Mingzhen; Barber, Zeb W.; Fischer, Joe A.; Randall Babbitt, Wm.

2004-01-01

We report the observation of the geometric phase in a closed two-level atomic system using stimulated photon echoes. The two-level system studied consists of the two-electronic energy levels ( 3 H 4 and 3 H 6 ) of Tm 3+ doped in YAG crystal. When a two-level atom at an arbitrary superposition state is excited by a pair of specially designed laser pulses, the excited state component gains a relative phase with respect to the ground state component. We identified the phase shift to be of pure geometric nature. The dynamic phase associated to the driving Hamiltonian is unchanged. The experiment results of the phase change agree with the theory to the extent of the measurement limit

A review of creep behavior of high temperature composites in relation to molybdenum disilicide composites

International Nuclear Information System (INIS)

Sadananda, K.; Feng, C.R.

1993-01-01

A brief review of creep behavior of composites is presented. It is shown that even for a two component system, creep of a composite depends on complex combination of several factors, including the constitutive behavior of the component phases at stress and temperature, and mechanical, chemical, diffusional and thermodynamic stability of the two-phase interfaces. The existing theoretical models based on continuum mechanics are presented. These models are evaluated using the extensive experimental data on molydisilicide--silicon carbide composites by the authors. The analysis shows that the rule of mixture based on isostrain and isostress provides two limiting bounds wherein all other predictions fall. For molydisilicide, the creep is predominantly governed by the creep of the majority phase, i.e. the matrix while fibers deform predominately elastically

Polymeric compositions incorporating polyethylene glycol as a phase change material

Science.gov (United States)

Salyer, Ival O.; Griffen, Charles W.

1989-01-01

A polymeric composition comprising a polymeric material and polyethylene glycol or end-capped polyethylene glycol as a phase change material, said polyethylene glycol and said end-capped polyethylene glycol having a molecular weight greater than about 400 and a heat of fusion greater than about 30 cal/g; the composition is useful in making molded and/or coated materials such as flooring, tiles, wall panels and the like; paints containing polyethylene glycols or end-capped polyethylene glycols are also disclosed.

A new Class of Extremal Composites

DEFF Research Database (Denmark)

Sigmund, Ole

2000-01-01

microstructure belonging to the new class of composites has maximum bulk modulus and lower shear modulus than any previously known composite. Inspiration for the new composite class comes from a numerical topology design procedure which solves the inverse homogenization problem of distributing two isotropic......The paper presents a new class of two-phase isotropic composites with extremal bulk modulus. The new class consists of micro geometrics for which exact solutions can be proven and their bulk moduli are shown to coincide with the Hashin-Shtrikman bounds. The results hold for two and three dimensions...... and for both well- and non-well-ordered isotropic constituent phases. The new class of composites constitutes an alternative to the three previously known extremal composite classes: finite rank laminates, composite sphere assemblages and Vigdergauz microstructures. An isotropic honeycomb-like hexagonal...

Phase separation and pressure drop of two-phase flow in vertical manifolds

International Nuclear Information System (INIS)

Zetzmann, K.

1982-01-01

The splitting of a two-phase mass flow in a tube manifold results in a separation between liquid and gas phase. A study is presented of the phase distribution and the related two-phase pressure drop for vertical manifolds in the technically relevant geometry and flow parameter region of an air-water-flow. At the outlet changes in the gas/fluid-radio are observed which are proportional to this ratio at the inlet. The separation characteristic strongly depends on the massflow through the junction. Empirical equations are given to calculate the separation. Measuring the pressure drop at main- and secondary tube of the manifold the additional pressure drop can be obtained. If these results are related with the dynamic pressure at the inlet, two-phase resistance coefficients can be deduced, which may be tested by empirical relations. (orig.) [de

A Phase-Controlled Optical Parametric Amplifier Pumped by Two Phase-Distorted Laser Beams

International Nuclear Information System (INIS)

Hong-Yan, Ren; Lie-Jia, Qian; Peng, Yuan; He-Yuan, Zhu; Dian-Yuan, Fan

2010-01-01

We theoretically study the phase characteristic of optical parametric amplification (OPA) or chirped pulse OPA (OPCPA) pumped by two phase-distorted laser beams. In the two-beam-pumped optical parametric amplification (TBOPA), due to spatial walk-off, both of the pump phase distortions will be partly transferred to signal in a single crystal so as to degrade the signal beam-quality, which will be more serious in high-energy OPCPA. An OPA configuration with a walkoff-compensated crystal pair is demonstrated for reducing the signal phase distortion experienced in the first stage and ensuring the signal phase independent of two pump phase distortions through the second crystal, hence maintaining the signal beam-quality. Such a TBOPA is similar to the conventional quantum laser amplifier by means of eliminating its sensitivity to the phase and number of the pump beams

Probabilistic physical characteristics of phase transitions at highway bottlenecks: incommensurability of three-phase and two-phase traffic-flow theories.

Science.gov (United States)

Kerner, Boris S; Klenov, Sergey L; Schreckenberg, Michael

2014-05-01

Physical features of induced phase transitions in a metastable free flow at an on-ramp bottleneck in three-phase and two-phase cellular automaton (CA) traffic-flow models have been revealed. It turns out that at given flow rates at the bottleneck, to induce a moving jam (F → J transition) in the metastable free flow through the application of a time-limited on-ramp inflow impulse, in both two-phase and three-phase CA models the same critical amplitude of the impulse is required. If a smaller impulse than this critical one is applied, neither F → J transition nor other phase transitions can occur in the two-phase CA model. We have found that in contrast with the two-phase CA model, in the three-phase CA model, if the same smaller impulse is applied, then a phase transition from free flow to synchronized flow (F → S transition) can be induced at the bottleneck. This explains why rather than the F → J transition, in the three-phase theory traffic breakdown at a highway bottleneck is governed by an F → S transition, as observed in real measured traffic data. None of two-phase traffic-flow theories incorporates an F → S transition in a metastable free flow at the bottleneck that is the main feature of the three-phase theory. On the one hand, this shows the incommensurability of three-phase and two-phase traffic-flow theories. On the other hand, this clarifies why none of the two-phase traffic-flow theories can explain the set of fundamental empirical features of traffic breakdown at highway bottlenecks.

Models for assessing the relative phase velocity in a two-phase flow. Status report

International Nuclear Information System (INIS)

Schaffrath, A.; Ringel, H.

2000-06-01

The knowledge of slip or drift flux in two phase flow is necessary for several technical processes (e.g. two phase pressure losses, heat and mass transfer in steam generators and condensers, dwell period in chemical reactors, moderation effectiveness of two phase coolant in BWR). In the following the most important models for two phase flow with different phase velocities (e.g. slip or drift models, analogy between pressure loss and steam quality, ε - ε models and models for the calculation of void distribution in reposing fluids) are classified, described and worked up for a further comparison with own experimental data. (orig.)

Two phase cooling for superconducting magnets

International Nuclear Information System (INIS)

Eberhard, P.H.; Gibson, G.A.; Green, M.A.; Ross, R.R.; Smits, R.G.

1986-01-01

Comments on the use of two phase helium in a closed circuit tubular cooling system and some results obtained with the TPC superconducting magnet are given. Theoretical arguments and experimental evidence are given against a previously suggested method to determine helium two phase flow regimes. Two methods to reduce pressure in the magnet cooling tubes during quenches are discussed; 1) lowering the density of helium in the magnet cooling tubes and 2) proper location of pressure relief valves. Some techniques used to protect the refrigerator from too much cold return gas are also mentioned

Structure and phase composition of titanium nitride coating on austenitic steel

International Nuclear Information System (INIS)

Dubovitskaya, N.V.; Kolenchenko, L.D.; Larikov, L.N.

1989-01-01

Structure and phase composition of titanium nitride coating deposited on 08Kh18N10T steel substrate using ''Bulat'' device are studied. Use of complex investigation methods permitted despite small coating thickness (1μm) to aquire information on hardness, porosity, to study phase composition in all coating thickness. The surface layer (∼0.1 μm) consists of ε-Ti 2 N, TiN 0.6 , TiC 0.35 , that is formed with carbon participation from oil vacuum. In more deeper layers beside ε-Ti 2 N TiC 0.14 N 0.77 is present. Effect of carbon diffusion from substrate to forming coating is stated. Gradient of element concentrations in the substrate-coating interface causes recrystallization of austenite

Double-scaled disorder in Ga(N,As,P)/GaP multiquantum wells

International Nuclear Information System (INIS)

Karcher, C.; Jandieri, K.; Kunert, B.; Fritz, R.; Volz, K.; Stolz, W.; Gebhard, F.; Baranovskii, S.D.; Heimbrodt, W.

2013-01-01

The compositional dependence of the properties of metastable Ga(N,As,P) has been characterized optically by means of temperature dependent absorptive and emissive techniques. By assuming a two-scaled disorder within the alloy caused by microscopic composition fluctuations on the one hand and a fluctuation of strain fields or the well width on the other hand, Monte Carlo simulations of the carrier dynamics are in good agreement with the experimental findings. The compositional dependence further reveals an increase of disorder with decreasing nitrogen content. - Highlights: ► Temperature dependent spectral dataset of two Ga(N,As,P)/ MQWs with varying composition. ► High resolution TEM study revealing height fluctuations within the triple QWs. ► Two distinct scales of disorder corresponding to two spatial length scales. ► Almost perfect Monte-Carlo simulations of the experimental findings. ► Theoretical explanation of the discovered reduction of disorder with increasing N.

Body composition measurement using computed tomography: Does the phase of the scan matter?

Science.gov (United States)

Rollins, Katie E; Javanmard-Emamghissi, Hannah; Awwad, Amir; Macdonald, Ian A; Fearon, Kenneth C H; Lobo, Dileep N

2017-09-01

The aim of this study was to determine, from the methodologic standpoint, the effect of the presence or absence of intravenous contrast on body composition variables obtained by analysis of computed tomography (CT) images. Triphasic abdominal (noncontrast, arterial phase, and portovenous phase contrast) CT scans from 111 patients were analyzed by two independent assessors at the third lumbar vertebral level using SliceOmatic software (version 5.0, TomoVision, Montreal, Canada). Variables included skeletal muscle index (SMI), fat and fat-free mass (FM and FFM, respectively), and mean skeletal muscle Hounsfield units (SMHU). Mean SMHU was lowest in the noncontrast phase (29.4, standard deviation [SD] 8.9 HU), followed by arterial (32.4, SD 9.3 HU) then portovenous phases (34.9, SD 9.4 HU). The mean skeletal muscle attenuation was significantly different depending on the phase of the scan in which the images were obtained. Calculated FM was significantly lower in both arterial (28.6, SD 8.8 kg, P definition of myosteatosis should include a standardized phase of CT for analysis and this should be incorporated within its definition. However, as the magnitudes of the differences were relatively small, the effect of the phase of the scan on predicting outcome needs to be determined. Copyright © 2017 Elsevier Inc. All rights reserved.

The impacts of physical activity intervention on physical and cognitive outcomes in children with autism spectrum disorder.

Science.gov (United States)

Pan, Chien-Yu; Chu, Chia-Hua; Tsai, Chia-Liang; Sung, Ming-Chih; Huang, Chu-Yang; Ma, Wei-Ya

2017-02-01

This study examined the effects of a 12-week physical activity intervention on the motor skill proficiency and executive function of 22 boys (aged 9.08 ± 1.75 years) with autism spectrum disorder. In Phase I of the 12 weeks, 11 boys with autism spectrum disorder (Group A) received the intervention, whereas the other 11 boys with autism spectrum disorder (Group B) did not (true control, no intervention). The arrangement was reversed in Phase II, which lasted an additional 12 weeks. The Bruininks-Oseretsky Test of Motor Proficiency, Second Edition, and the Wisconsin Card Sorting Test were conducted three times for each participant (Group A, primary grouping: baseline (T1), post-assessment (T2), and follow-up assessment (T3); Group B, control grouping: T1-T2; intervention condition, T2-T3). The main findings were that both groups of children with autism spectrum disorder significantly exhibited improvements in motor skill proficiency (the total motor composite and two motor-area composites) and executive function (three indices of the Wisconsin Card Sorting Test) after 12 weeks of physical activity intervention. In addition, the effectiveness appeared to have been sustained for at least 12 weeks in Group A. The findings provide supporting evidence that physical activity interventions involving table tennis training may be a viable therapeutic option for treating children with autism spectrum disorder.

Strong composition-dependent disorder in InAs1-xNx alloys

International Nuclear Information System (INIS)

Benaissa, H.; Zaoui, A.; Ferhat, M.

2009-01-01

We investigate the main causes of disorder in the InAs 1-x N x alloys (x = 0, 0.03125, 0.0625, 0.09375, 0.125, 0.25, 0.5, 0.75, 0.875, 0.90625, 0.9375, 0.96875 and 1). The calculation is based on the density-functional theory in the local-density approximation. We use a plane wave-expansion non-norm conserving ab initio Vanderbilt pseudopotentials. To avoid the difficulty of considering the huge number of atomic configurations, we use an appropriate strategy in which we consider four configurations for a given composition where the N atoms are not randomly distributed. We mainly show that the band gap decreases (increases) rapidly with increasing (decreasing) compositions of N. As a consequence the optical band gap bowing is found to be strong and composition dependent. The obtained compounds, from these alloys, may change from semi-conducting to metal (passing to a negative bowing) and could be useful for device applications, especially at certain composition.

Evidence of hexatic phase formation in two-dimensional Lennard-Jones binary arrays

International Nuclear Information System (INIS)

Li, M.; Johnson, W.L.; Goddard, W.A. III

1996-01-01

We report evidence of the hexatic phase formation in Lennard-Jones binary substitutional random arrays from isothermal-isobaric molecular-dynamics simulations. The hexatic phase is analogous to those predicted in Kosterlitz-Thouless theory of melting that is characterized by short-range translational order and quasi-long-range orientational order. At the crystal to hexatic phase transition, dislocation pairs are observed to unbind into isolated dislocations. Further disordering of the hexatic phase, however, does not lead to dissociation of dislocations into disclinations. Instead, the dislocations become clustered and form dislocation networks which results in formation of amorphous phases. copyright 1996 The American Physical Society

Two-phase-flow models and their limitations

International Nuclear Information System (INIS)

Ishii, M.; Kocamustafaogullari, G.

1982-01-01

An accurate prediction of transient two-phase flow is essential to safety analyses of nuclear reactors under accident conditions. The fluid flow and heat transfer encountered are often extremely complex due to the reactor geometry and occurrence of transient two-phase flow. Recently considerable progresses in understanding and predicting these phenomena have been made by a combination of rigorous model development, advanced computational techniques, and a number of small and large scale supporting experiments. In view of their essential importance, the foundation of various two-phase-flow models and their limitations are discussed in this paper

Two-phase flow patterns and their relationship to two-phase heat transfer

International Nuclear Information System (INIS)

Hewitt, G.F.

1977-01-01

The objective of this lecture was to discuss the general nature of two phase flows, to define the various regimes of flow and to discuss the influence of these regimes on the heat transfer processes taking place. The methods of regime delineation are briefly described and regime descriptions introduced for both vertical and horizontal flows in tubes. ''Flow regime maps'' have been widely used as an aid to determination of the regime which occurs in a given situation. Some of the more widely used maps are described and the limitations of this approach discussed. There have been many attempts to obtain a better phenomenological description of two phase flow patterns. In this lecture, these attempts will be reviewed in the context of the bubble/plug, plug/churn and churn/annular flow transitions in vertical flow. The latter two transitions are related to the flooding/flow reversal phenomena. For horizontal flows, recent work on the onset of slugging will be reviewed. In flows with evaporation or condensation, the situation is influenced by departures from thermodynamic equilibrium and the types of departure observed are discuss briefly. Flow patterns and their relationships with heat transfer regimes are then reviewed for the case of condensation in horizontal tubes and evaporation in vertical tubes

Observation of Kosterlitz-Thouless phase transition in the composite superconductor (NbTi)-Cu

International Nuclear Information System (INIS)

Fischer, E.; Khukhareva, I.S.

1989-01-01

Results are reported of an experimental investigation of the resistive behavior of a composite superconductor carrying a current perpendicular to the superconducting filaments. The sample resistance exhibits in this case, depending on the temperature and on the measurement current, a number of peculiarities, and in particular a two-step transition to the superconducting state. On the basis of an analysis of the laws governing these peculiarities, a model is developed for topological Kosterlitz-Thouless phase transitions in bulk systems. Topological defects of a new type, current-stimulated excitations, are considered. The deduced empirical relations scale with var-epsilon = I/I c . A correlation is established between the characteristic values for two- and three-dimensional systems

Phase composition, microstructure, and mechanical properties of porous Ti-Nb-Zr alloys prepared by a two-step foaming powder metallurgy method.

Science.gov (United States)

Rao, X; Chu, C L; Zheng, Y Y

2014-06-01

Porous Ti-Nb-Zr alloys with different porosities from 6.06 to 62.8% are prepared by a two-step foaming powder metallurgy method using TiH2, Nb, and Zr powders together with 0 to 50wt% of NH4HCO3. The effects of the amounts of Nb and Zr as well as the sintering temperature (1473 to 1673K) on their phase composition, porosity, morphology, and mechanical characteristics are investigated. By controlling the porosity, Nb and Zr concentrations as well as the sintering temperature, porous Ti-Nb-Zr alloys with different mechanical properties can be obtained, for example, the hardness between 290 and 63HV, the compressive strength between 1530.5 and 73.4MPa, and the elastic modulus between 10.8 and 1.2GPa. The mechanical properties of the sintered porous Ti-Nb-Zr alloys can be tailored to match different requirements for the human bones and are thus potentially useful in the hard tissue implants. Copyright © 2014 Elsevier Ltd. All rights reserved.

Compositional modeling of three-phase flow with gravity using higher-order finite element methods

KAUST Repository

Moortgat, Joachim

2011-05-11

A wide range of applications in subsurface flow involve water, a nonaqueous phase liquid (NAPL) or oil, and a gas phase, such as air or CO2. The numerical simulation of such processes is computationally challenging and requires accurate compositional modeling of three-phase flow in porous media. In this work, we simulate for the first time three-phase compositional flow using higher-order finite element methods. Gravity poses complications in modeling multiphase processes because it drives countercurrent flow among phases. To resolve this issue, we propose a new method for the upwinding of three-phase mobilities. Numerical examples, related to enhanced oil recovery and carbon sequestration, are presented to illustrate the capabilities of the proposed algorithm. We pay special attention to challenges associated with gravitational instabilities and take into account compressibility and various phase behavior effects, including swelling, viscosity changes, and vaporization. We find that the proposed higher-order method can capture sharp solution discontinuities, yielding accurate predictions of phase boundaries arising in computational three-phase flow. This work sets the stage for a broad extension of the higher-order methods for numerical simulation of three-phase flow for complex geometries and processes.

Evolution of phase microstructure during irradiation

International Nuclear Information System (INIS)

Wiedersich, H.

1985-11-01

The phase microstructure of alloys is frequently severely altered during irradiation. Sluggish precipitation reactions including precipitation coarsening are accelerated by irradiation-enhanced diffusion. Radiation-induced segregation redistributes existing precipitate phases within the microstructure, induces precipitation of nonequilibrium phases and affects the composition of phases in multicomponent alloys. The displacement process causes disordering of ordered alloys and frequently amorphization, especially in intermetallic compounds, at low temperature. Although a good qualitative understanding of the basic process involved, i.e., displacement mixing, radiation-enhanced diffusion and radiation-induced segregation exists, methods for detailed quantitative modeling of the evolution of the microstructure of alloys remain to be developed

Evaluation of the phase composition of (NH4)2SO4 + (NH4)H2PO4 mixtures by X-ray diffractometry

International Nuclear Information System (INIS)

Ortiz, Angel L.; Cumbrera, Francisco L.; Perez, Jose; Vas, Beatriz del; Perez, Eduardo

2009-01-01

The phase composition of standard (NH 4 ) 2 SO 4 + (NH 4 )H 2 PO 4 mixtures was investigated by X-ray diffractometry (XRD) using the internal-standard, reference-intensity-ratio, and Rietveld methods. It was found that the Rietveld method yields the most accurate phase-composition measurements, with an average error of ∼2 wt.%. It was also found that the internal-standard method is only effective in determining the phase composition if the calibration curve for (NH 4 )H 2 PO 4 is used, giving an average error of ∼6.5 wt.%. On the contrary, the internal-standard method with the calibration curve of the (NH 4 ) 2 SO 4 phase and the reference-intensity-ratio method are not valid. The inappropriateness of these two methods was attributed to graininess in the (NH 4 ) 2 SO 4 phase, with the attendant deviation of its diffracted intensities from the theoretical values. Direct scanning electron microscopy observations of the morphology of the powder particles in the mixtures showed clear evidence of the large agglomerates formed because the individual powder particles are partially sintered together during milling, thus corroborating the graininess determined by the XRD analyses. Finally, the implications of the present study for the quantitative phase-composition analysis of (NH 4 ) 2 SO 4 + (NH 4 )H 2 PO 4 mixtures, which are of great technological importance for the fire prevention industry, are discussed.

Nonclassical disordered phase in the strong quantum limit of frustrated antiferromagnets

International Nuclear Information System (INIS)

Ceccatto, H.A.; Gazza, C.J.; Trumper, A.E.

1992-07-01

The Schwinger boson approach to quantum helimagnets is discussed. It is shown that in order to get quantitative agreement with exact results on finite lattices, parity-breaking pairing of bosons must be allowed. The so-called J 1 - J 2 - J 3 model is studied, particularly on the special line J 2 = 2J 3 . A quantum disordered phase is found between the Neel and spiral phases, though notably only in the strong quantum limit S = 1/2, and for the third-neighbor coupling J 3 ≥ 0.038 J 1 . For spins S≥1 the spiral phase goes continuously to an antiferromagnetic order. (author). 19 refs, 3 figs

Numerical calculation of two-phase turbulent jets

Energy Technology Data Exchange (ETDEWEB)

Saif, A.A.

1995-05-01

Two-phase turbulent round jets were numerically simulated using a multidimensional two-phase CFD code based on the two-fluid model. The turbulence phenomena were treated with the standard k-{epsilon} model. It was modified to take into account the additional dissipation of turbulent kinetic energy by the dispersed phase. Within the context of the two-fluid model it is more appropriate and physically justified to treat the diffusion by an interfacial force in the momentum equation. In this work, the diffusion force and the additional dissipation effect by the dispersed phase were modeled starting from the classical turbulent energy spectrum analysis. A cut-off frequency was proposed to decrease the dissipation effect by the dispersed phase when large size particles are introduced in the flow. The cut-off frequency combined with the bubble-induced turbulence effect allows for an increase in turbulence for large particles. Additional care was taken in choosing the right kind of experimental data from the literature so that a good separate effect test was possible for their models. The models predicted the experimental data very closely and they were general enough to predict extreme limit cases: water-bubble and air-droplet jets.

Two phase cooling for superconducting magnets

International Nuclear Information System (INIS)

Eberhard, P.H.; Gibson, G.A.; Green, M.A.; Ross, R.R.; Smits, R.G.; Taylor, J.D.; Watt, R.D.

1986-01-01

Comments on the use of two phase helium in a closed circuit tubular cooling system and some results obtained with the TPC superconducting magnet are given. Theoretical arguments and experimental evidence are given against a previously suggested method to determine helium two phase flow regimes. Two methods to reduce pressure in the magnet cooling tubes during quenches are discussed; (1) lowering the density of helium in the magnet cooling tubes and (2) proper location of pressure relief valves. Some techniques used to protect the refrigerator from too much cold return gas are also mentioned. 10 refs., 1 fig., 5 tabs

Supercooling suppression of microencapsulated phase change materials by optimizing shell composition and structure

International Nuclear Information System (INIS)

Cao, Fangyu; Yang, Bao

2014-01-01

Highlights: • A new method for supercooling suppression of microPCMs by optimizing the structure of the microcapsule shell. • Large effective latent heat (up to 213 J/g) of the microPCMs, much higher than those using additive as nucleating agents. • Change of shell composition and structure significantly affects the phase transition processes of the encapsulated PCMs. • The latent heat of the shell-induced phase transition is maximized, reaching 83.7% of the latent heat of bulk octadecane. • Hollow spheres with porous rather than solid resin shell are also formed when the SDS concentration is very high. - Abstract: A new method for supercooling suppression of microencapsulated phase change materials (PCMs) has been developed by optimizing the composition and structure of the microcapsule resin shell. The microcapsules comprising paraffin octadecane encapsulated in melamine–formaldehyde resin shell were synthesized with the use the oil-in-water emulsion technique. These PCM microcapsules are 5–15 μm in diameter. The supercooling of these octadecane microcapsules can be as large as 13.6 °C, when the homogeneous nucleation is dominant during the melt crystallization into the thermodynamically stable triclinic phase. It is discovered that the homogeneous nucleation can be mediated by shell-induced nucleation of the triclinic phase and the metastable rotator phase when the shell composition and structure are optimized, without need of any nucleating additives. The effects of synthesis parameters, such as ratio of melamine to formaldehyde, pH of pre-polymer, and pH of emulsion, on the phase transition properties of the octadecane microcapsules have been investigated systemically. The optimum synthesis conditions have been identified in terms of minimizing the supercooling while maintaining heat capacity. Potential applications of this type of phase changeable microcapsules include high heat capacity thermal fluids, thermal management in smart buildings

Application of non-equilibrium thermodynamics to two-phase flows with a change of phase

International Nuclear Information System (INIS)

Delhaye, J.M.

1969-01-01

In this report we use the methods of non-equilibrium thermodynamics in two-phase flows. This paper follows a prior one in which we have studied the conservation laws and derived the general equations of two-phase flow. In the first part the basic ideas of thermodynamics of irreversible systems are given. We follow the classical point of view. The second part is concerned with the derivation of a closed set of equations for the two phase elementary volume model. In this model we assume that the elementary volume contains two phases and that it is possible to define a volumetric local concentration. To obtain the entropy balance we can choose either the reversibility of the barycentric motion or the reversibility of each phase. We adopt the last assumption and our derivation is the same as this of I.Prigogine and P. Mazur about the hydrodynamics of liquid helium. The scope of this work is not to find a general solution to the problems of two phase flows but to obtain a new set of equations which may be used to explain some characteristic phenomena of two-phase flow such as wave propagation or critical states. (author) [fr

The influence of glass composition on crystalline phase stability in glass-ceramic wasteforms

International Nuclear Information System (INIS)

Maddrell, Ewan; Thornber, Stephanie; Hyatt, Neil C.

2015-01-01

Highlights: • Crystalline phase formation shown to depend on glass matrix composition. • Zirconolite forms as the sole crystalline phase only for most aluminous glasses. • Thermodynamics indicate that low silica activity glasses stabilise zirconolite. - Abstract: Zirconolite glass-ceramic wasteforms were prepared using a suite of Na 2 O–Al 2 O 3 –B 2 O 3 –SiO 2 glass matrices with variable Al:B ratios. Zirconolite was the dominant crystalline phase only for the most alumina rich glass compositions. As the Al:B ratio decreased zirconolite was replaced by sphene, zircon and rutile. Thermodynamic data were used to calculate a silica activity in the glass melt below which zirconolite is the favoured crystalline phase. The concept of the crystalline reference state of glass melts is then utilised to provide a physical basis for why silica activity varies with the Al:B ratio

Two-Phase Induction Motor Drives

Directory of Open Access Journals (Sweden)

Gholam Reza Arab Markadeh

2010-10-01

Full Text Available The lack of variable-speed drives for two (single induction motor is a reality. This article attempts mainly to investigate the reasons for this lack of variable – speed drives. This paper deals with literature survey of various existing converter topologies, which have been proposed for adjustable speed single phase induction motor drives. Various converter topologies have been compared in this paper. Among these converter topologies, the adjustable frequency PWM inverter is the best choice for single-phase induction motor drives. However, adjustable-frequency drives have not been widely used with single-phase Induction motors. The open-loop constant V/F control law cannot be used with the single-phase induction motor drives as it is used with three phase motors. The variation of the operating frequency at lower speed range with constant load torque causes variation in motor's slip. A constant V/F control is suitable only over the upper speed range.

Effective properties of dispersed phase reinforced composite materials with perfect and imperfect interfaces

Science.gov (United States)

Han, Ru

This thesis focuses on the analysis of dispersed phase reinforced composite materials with perfect as well as imperfect interfaces using the Boundary Element Method (BEM). Two problems of interest are considered, namely, to determine the limitations in the use of effective properties and the analysis of failure progression at the inclusion-matrix interface. The effective moduli (effective Young's modulus, effective Poisson's ratio, effective shear modulus, and effective bulk modulus) of composite materials can be determined at the mesoscopic level using three-dimensional parallel BEM simulations. By comparing the mesoscopic BEM results and the macroscopic results based on effective properties, limitations in the effective property approach can be determined. Decohesion is an important failure mode associated with fiber-reinforced composite materials. Analysis of failure progression at the fiber-matrix interface in fiber-reinforced composite materials is considered using a softening decohesion model consistent with thermodynamic concepts. In this model, the initiation of failure is given directly by a failure criterion. Damage is interpreted by the development of a discontinuity of displacement. The formulation describing the potential development of damage is governed by a discrete decohesive constitutive equation. Numerical simulations are performed using the direct boundary element method. Incremental decohesion simulations illustrate the progressive evolution of debonding zones and the propagation of cracks along the interfaces. The effect of decohesion on the macroscopic response of composite materials is also investigated.

Numerical method for two-phase flow discontinuity propagation calculation

International Nuclear Information System (INIS)

Toumi, I.; Raymond, P.

1989-01-01

In this paper, we present a class of numerical shock-capturing schemes for hyperbolic systems of conservation laws modelling two-phase flow. First, we solve the Riemann problem for a two-phase flow with unequal velocities. Then, we construct two approximate Riemann solvers: an one intermediate-state Riemann solver and a generalized Roe's approximate Riemann solver. We give some numerical results for one-dimensional shock-tube problems and for a standard two-phase flow heat addition problem involving two-phase flow instabilities

Fatty acids profile and nutritional composition of two tropical diatoms from the Costa Rican Pacific Coast

International Nuclear Information System (INIS)

Rodríguez-Núñez, K.; Toledo-Aguero, P.

2017-01-01

Microalgae represent an important nutritional source for diverse organisms, therefore, their nutritional value, and more specifically, total lipid and fatty acid contents, must be considered. This study evaluated the nutritional contents and potential growth under controlled conditions of Nitzschia sp. and Chaetoceros sp. Tropical microalgae, isolated from the Gulf of Nicoya, Costa Rica. In both strains, the nutritional composition and the fatty acid profile were evaluated in exponential and stationary phases. With regards to fatty acids, Nitzschia sp. had more Eicosapentaenoic Acid (EPA) in both the exponential (32.80%) and stationary (27.20%) phases. The results in growth rate, production and biochemical composition indicated two tropical microalgae strains suitable for cultivation under controlled conditions. The studies of the phytoplankton in this geographical area is highly relevant because of its importance in the primary production of nutrients and the importance of finding sources of fatty acids such as the EPA. [es

Reversible, on-demand generation of aqueous two-phase microdroplets

Science.gov (United States)

Collier, Charles Patrick; Retterer, Scott Thomas; Boreyko, Jonathan Barton; Mruetusatorn, Prachya

2017-08-15

The present invention provides methods of on-demand, reversible generation of aqueous two-phase microdroplets core-shell microbeads, microparticle preparations comprising the core-shell microbeads, and drug delivery formulation comprising the microparticle preparations. Because these aqueous microdroplets have volumes comparable to those of cells, they provide an approach to mimicking the dynamic microcompartmentation of biomaterial that naturally occurs within the cytoplasm of cells. Hence, the present methods generate femtoliter aqueous two-phase droplets within a microfluidic oil channel using gated pressure pulses to generate individual, stationary two-phase microdroplets with a well-defined time zero for carrying out controlled and sequential phase transformations over time. Reversible phase transitions between single-phase, two-phase, and core-shell microbead states are obtained via evaporation-induced dehydration and water rehydration.

Speeding up the flash calculations in two-phase compositional flow simulations - The application of sparse grids

KAUST Repository

Wu, Yuanqing

2015-03-01

Flash calculations have become a performance bottleneck in the simulation of compositional flow in subsurface reservoirs. We apply a sparse grid surrogate model to substitute the flash calculation and thus try to remove the bottleneck from the reservoir simulation. So instead of doing a flash calculation in each time step of the simulation, we just generate a sparse grid approximation of all possible results of the flash calculation before the reservoir simulation. Then we evaluate the constructed surrogate model to approximate the values of the flash calculation results from this surrogate during the simulations. The execution of the true flash calculation has been shifted from the online phase during the simulation to the offline phase before the simulation. Sparse grids are known to require only few unknowns in order to obtain good approximation qualities. In conjunction with local adaptivity, sparse grids ensure that the accuracy of the surrogate is acceptable while keeping the memory usage small by only storing a minimal amount of values for the surrogate. The accuracy of the sparse grid surrogate during the reservoir simulation is compared to the accuracy of using a surrogate based on regular Cartesian grids and the original flash calculation. The surrogate model improves the speed of the flash calculations and the simulation of the whole reservoir. In an experiment, it is shown that the speed of the online flash calculations is increased by about 2000 times and as a result the speed of the reservoir simulations has been enhanced by 21 times in the best conditions.

Forced two phase helium cooling of large superconducting magnets

International Nuclear Information System (INIS)

Green, M.A.; Burns, W.A.; Taylor, J.D.

1979-08-01

A major problem shared by all large superconducting magnets is the cryogenic cooling system. Most large magnets are cooled by some variation of the helium bath. Helium bath cooling becomes more and more troublesome as the size of the magnet grows and as geometric constraints come into play. An alternative approach to cooling large magnet systems is the forced flow, two phase helium system. The advantages of two phase cooling in many magnet systems are shown. The design of a two phase helium system, with its control dewar, is presented. The paper discusses pressure drop of a two phase system, stability of a two phase system and the method of cool down of a two phase system. The results of experimental measurements at LBL are discussed. Included are the results of cool down and operation of superconducting solenoids

Phase composition and microstructure of WC-Co alloys obtained by selective laser melting

Science.gov (United States)

Khmyrov, Roman S.; Shevchukov, Alexandr P.; Gusarov, Andrey V.; Tarasova, Tatyana V.

2018-03-01

Phase composition and microstructure of initial WC, BK8 (powder alloy 92 wt.% WC-8 wt.% Co), Co powders, ball-milled powders with four different compositions (1) 25 wt.% WC-75 wt.% Co, (2) 30 wt.% BK8-70 wt.% Co, (3) 50 wt.% WC-50 wt.% Co, (4) 94 wt.% WC-6 wt.% Co, and bulk alloys obtained by selective laser melting (SLM) from as-milled powders in as-melted state and after heat treatment were investigated by scanning electron microscopy and X-ray diffraction analysis. Initial and ball-milled powders consist of WC, hexagonal α-Co and face-centered cubic β-Co. The SLM leads to the formation of major new phases W3Co3C, W4Co2C and face-centered cubic β-Co-based solid solution. During the heat treatment, there occurs partial decomposition of the face-centered cubic β-Co-based solid solution with the formation of W2C and hexagonal α-Co solid solution. The microstructure of obtained bulk samples, in general, corresponds to the observed phase composition.

Prevalence and predictors of stress disorders following two earthquakes.

Science.gov (United States)

Yuan, Kang Chuan; Ruo Yao, Zhao; Zhen Yu, Shi; Xu Dong, Zhao; Jian Zhong, Yang; Edwards, Jason Glen; Edwards, Glen David

2013-09-01

Studies about stress disorders following a disaster have mainly been based on single-event trauma with little emphasis on multiple traumas. This study investigated the prevalence and predictors of stress disorders following two earthquakes in China. Subjects were randomly sampled from 11 villages in rural China. A total of 624 subjects were administered with the 12-item General Health Questionnaire (GHQ-12), Symptom Checklist -90-R (SCL-90-R), Coping Style Scale and Social Support Rating Scale. This was followed by a structural clinical interview using the Chinese translation of the Structured Clinical Interview for Diagnostic and Statistical Manual (DSM)-IV-TR axis 1 disorders (SCID-I-P) for acute stress disorder (ASD) and post-traumatic stress disorder (PTSD). The prevalence of ASD and PTSD was 15% and 29%, respectively. Regression analysis indicated that high intensity of trauma exposure, lower educational level, subjective feeling of economic status and psychological stress after the first earthquake significantly predicted the outcome of PTSD. The study suggested that the prevalence of stress disorders in two earthquakes were higher than that experienced in a single disaster. The intensity of trauma exposure, low educational level, bad subjective feeling of economic status, and psychological stress after the first earthquake could be used to identify survivors at risk of developing PTSD in two earthquakes.

Analysis of mental disorders in tinnitus patients performed with Composite International Diagnostic Interview.

Science.gov (United States)

Zirke, N; Seydel, C; Arsoy, D; Klapp, B F; Haupt, H; Szczepek, A J; Olze, H; Goebel, G; Mazurek, B

2013-10-01

Known association between tinnitus and psychological distress prompted us to examine patients with chronic tinnitus by using the Composite International Diagnostic Interview (CIDI), which is a standardized and reliable method used for the diagnosis of mental disorders. One hundred patients with chronic tinnitus admitted to the Tinnitus Center, Charité-Universitätsmedizin Berlin, were included in this study. Data were collected between February 2008 and February 2009. Besides CIDI, the Tinnitus Questionnaire according to Goebel and Hiller, the Hospital Anxiety Depression Scale, and the General Anxiety Disorder-7 were used. Using CIDI, we have identified one or more mental disorders in 46 tinnitus patients. In that group, we found persistent affective disorders (37 %), anxiety disorders (32 %), and somatoform disorders (27 %). Those patients who had affective or anxiety disorders were more distressed by tinnitus and were more anxious and more depressed than tinnitus patients without mental disorders. Psychological impairment positively correlated with tinnitus distress: Patients with decompensated tinnitus had significantly more affective and anxiety disorders than patients with compensated tinnitus. In the present study, we have detected a high rate (almost half of the cases) of psychological disorders occurring in patients with chronic tinnitus. The patients diagnosed with psychological disorders were predominantly affected by affective and anxiety disorders. Psychological disorders were associated with severity of tinnitus distress. Our findings imply a need for routine comprehensive screening of mental disorders in patients with chronic tinnitus.

Electromechanical response of (2–2) layered piezoelectric composites

International Nuclear Information System (INIS)

Kar-Gupta, Ronit; Venkatesh, T A

2013-01-01

Analytical and finite element models are developed to systematically characterize the effects of phase volume fraction and the relative orientations of the poling directions in two phases on the effective elastic, dielectric and piezoelectric properties of layered piezoelectric composites. Four classes of layered piezoelectric composites are identified based on the relative orientation of the poling directions in the two piezoelectric phases. Upon verifying that the results of the finite model compare well with that of analytical models for select layered composite systems, the finite element model is extended to characterize the electromechanical response of all four classes of piezoelectric composites. It is generally observed that the electromechanical properties of the layered composite along a direction perpendicular to the layer interface is largely influenced by the properties of the ‘softer’ phase whereas the in-plane response is modulated more by the ‘rule-of-mixtures’ theory. It is also observed that variations in the poling directions of the constituents can significantly influence the symmetry of the composite with composites that belong to Classes II and III (where the poling directions of the two phases are orthogonal to each other) exhibiting a relatively lower degree of material symmetry while the composites that belong to Classes I and IV (where the poling directions of the two phases are parallel to each other) exhibit a higher order symmetry. Furthermore, the best combination of figures of merit, i.e., enhanced coupling constant and reduced acoustic impedance, in a direction parallel to the layer interface is exhibited by Class I and Class II types of composite (where the piezoelectrically stiffer phase is poled along the layer interface). (paper)

New theoretical model for two-phase flow discharged from stratified two-phase region through small break

International Nuclear Information System (INIS)

Yonomoto, Taisuke; Tasaka, Kanji

1988-01-01

A theoretical and experimental study was conducted to understand two-phase flow discharged from a stratified two-phase region through a small break. This problem is important for an analysis of a small break loss-of-coolant accident (LOCA) in a light water reactor (LWR). The present theoretical results show that a break quality is a function of h/h b , where h is the elevation difference between a bulk water level in the upstream region and break and b the suffix for entrainment initiation. This result is consistent with existing eperimental results in literature. An air-water experiment was also conducted changing a break orientation as an experimental parameter to develop and assess the model. Comparisons between the model and the experimental results show that the present model can satisfactorily predict the flow rate and the quality at the break without using any adjusting constant when liquid entrainment occurs in a stratified two-phase region. When gas entrainment occurs, the experimental data are correlated well by using a single empirical constant. (author)

Density of phonon-fracton states of disordered solids in the vicinity of percolation phase transitions

International Nuclear Information System (INIS)

Korzhenevskii, A.L.; Luzhkov, A.A.

1991-01-01

The development of a theory of phase transitions in disordered materials is still one of the central problems in solid-state physics. The model of a percolation phase transition plays the same role among the models put forward to account for phase transitions in disordered media as does the Ising model for second-order phase transitions in ideal crystals. In addition to the clear picture of the processes occurring in the course of a percolation phase transition, a scaling theory has been developed and various techniques have been used to calculate the critical exponents describing the thermodynamics of a medium in the vicinity of the percolation threshold. The authors adopt a field-theoretic approach in a study of acoustic properties of disordered solids undergoing percolation phase transitions characterized by h ∼ 1. Among these transitions they concentrate on the case with the simplest type of striction interaction when the solution of a stochastic vector differential equation of motion describing the behavior of an elastic medium in the critical region can be reduced to a scalar equation. The results of their calculations by the field renormalization group method confirmed the existence of the scaling relationships between the critical exponents and also the conclusion on the nature of short- and long-wavelength vibrations near the percolation threshold, which follow from phenomenological considerations of the scaling theory. The values of the upper critical dimensionality and of the critical exponents of the problem are shown to differ from the values applicable to percolation phase transitions characterized by h much-lt 1

Modelling aspects of two phase flow

International Nuclear Information System (INIS)

Mayinger, F.

1977-01-01

In two phase flow scaling is much more limited to very narrowly defined physical phenomena than in single phase fluids. For complex and combined phenomena it can be achieved not by using dimensionless numbers alone but in addition a detailed mathematical description of the physical problem - usually in the form of a computer program - must be available. An important role plays the scaling of the thermodynamic data of the modelling fluid. From a literature survey and from own scaling experiments the conclusion can be drawn that Freon is a quite suitable modelling fluid for scaling steam-water mixtures. However, whithout a theoretical description of the phenomena nondimensional numbers for scaling two phase flow must be handled very carefully. (orig.) [de

Geometric analysis of the solutions of two-phase flows: two-fluid model

International Nuclear Information System (INIS)

Kestin, J.; Zeng, D.L.

1984-01-01

This report contains a lightly edited draft of a study of the two-fluid model in two-phase flow. The motivation for the study stems from the authors' conviction that the construction of a computer code for any model should be preceded by a geometrical analysis of the pattern of trajectories in the phase space appropriate for the model. Such a study greatly facilitates the understanding of the phenomenon of choking and anticipates the computational difficulties which arise from the existence of singularities. The report contains a derivation of the six conservation equations of the model which includes a consideration of the simplifications imposed on a one-dimensional treatment by the presence of boundary layers at the wall and between the phases. The model is restricted to one-dimensional adiabatic flows of a single substance present in two phases, but thermodynamic equilibrium between the phases is not assumed. The role of closure conditions is defined but no specific closure conditions, or explicit equations of state, are introduced

Two-phase flow instrumentation research at RPI

International Nuclear Information System (INIS)

Lahey, R.T. Jr.; Krycuk, G.

1979-01-01

Novel instrumentation for the measurement of void fraction and phase velocity was developed. An optical digital interferometer and a dual beam x-ray equipment were designed for detection of voids. Pitot tube measurements were made to understand two-phase flow phenomena in liquid phase velocity

Studying Suspended Sediment Mechanism with Two-Phase PIV

Science.gov (United States)

Matinpour, H.; Atkinson, J. F.; Bennett, S. J.; Guala, M.

2017-12-01

Suspended sediment transport affects soil erosion, agriculture and water resources quality. Turbulent diffusion is the most primary force to maintain sediments in suspension. Although extensive previous literature have been studying the interactions between turbulent motion and suspended sediment, mechanism of sediments in suspension is still poorly understood. In this study, we investigate suspension of sediments as two distinct phases: one phase of sediments and another phase of fluid with turbulent motions. We designed and deployed a state-of-the-art two-phase PIV measurement technique to discriminate these two phases and acquire velocities of each phase separately and simultaneously. The technique that we have developed is employing a computer-vision based method, which enables us to discriminate sediment particles from fluid tracer particles based on two thresholds, dissimilar particle sizes and different particle intensities. Results indicate that fluid turbulence decreases in the presence of suspended sediments. Obtaining only sediment phase consecutive images enable us to compute fluctuation sediment concentration. This result enlightens understanding of complex interaction between the fluctuation velocities and the fluctuation of associated mass and compares turbulent viscosity with turbulent eddy diffusivity experimentally.

Efficiency of the Needle Probe Test for Evaluation of Thermal Conductivity of Composite Materials: Two-Scale Analysis

Directory of Open Access Journals (Sweden)

Łydżba Dariusz

2014-03-01

Full Text Available The needle probe test, as a thermal conductivity measurement method, has become very popular in recent years. In the present study, the efficiency of this methodology, for the case of composite materials, is investigated based on the numerical simulations. The material under study is a two-phase composite with periodic microstructure of “matrix-inclusion” type. Two-scale analysis, incorporating micromechanics approach, is performed. First, the effective thermal conductivity of the composite considered is found by the solution of the appropriate boundary value problem stated for the single unit cell. Next, numerical simulations of the needle probe test are carried out. In this case, two different locations of the measuring sensor are considered. It is shown that the “equivalent” conductivity, derived from the probe test, is strongly affected by the location of the sensor. Moreover, comparing the results obtained for different scales, one can notice that the “equivalent” conductivity cannot be interpreted as the effective one for the composites considered. Hence, a crude approximation of the effective property is proposed based on the volume fractions of constituents and the equivalent conductivities derived from different sensor locations.

Mathematical well-posedness of a two-fluid equations for bubbly two-phase flows

International Nuclear Information System (INIS)

Okawa, Tomio; Kataoka, Isao

2000-01-01

It is widely known that two-fluid equations used in most engineering applications do not satisfy the necessary condition for being mathematical well-posed as initial-value problems. In the case of stratified two-phase flows, several researchers have revealed that differential models satisfying the necessary condition are to be derived if the pressure difference between the phases is related to the spatial gradient of the void fraction through the effects of gravity or surface tension. While, in the case of dispersed two-phase flows, no physically reasonable method to derive mathematically well-posed two-fluid model has been proposed. In the present study, particularly focusing on the effect of interfacial pressure terms, we derived the mathematically closed form of the volume-averaged two-fluid model for bubbly two-phase flows. As a result of characteristic analyses, it was shown that the proposed two-fluid equations satisfy the necessary condition of mathematical well-posedness if the void fraction is sufficiently small. (author)

An implicit numerical model for multicomponent compressible two-phase flow in porous media

Science.gov (United States)

Zidane, Ali; Firoozabadi, Abbas

2015-11-01

We introduce a new implicit approach to model multicomponent compressible two-phase flow in porous media with species transfer between the phases. In the implicit discretization of the species transport equation in our formulation we calculate for the first time the derivative of the molar concentration of component i in phase α (cα, i) with respect to the total molar concentration (ci) under the conditions of a constant volume V and temperature T. The species transport equation is discretized by the finite volume (FV) method. The fluxes are calculated based on powerful features of the mixed finite element (MFE) method which provides the pressure at grid-cell interfaces in addition to the pressure at the grid-cell center. The efficiency of the proposed model is demonstrated by comparing our results with three existing implicit compositional models. Our algorithm has low numerical dispersion despite the fact it is based on first-order space discretization. The proposed algorithm is very robust.

A new characterization method of the microstructure by utilizing the macroscopic composition gradient in alloys

International Nuclear Information System (INIS)

Miyazaki, T.; Koyama, T.; Kobayashi, S.

1996-01-01

A new experimental method to determine the phase boundary and phase equilibrium is accomplished by - means of analytical transmission electron microscopy for alloys with a macroscopic composition gradient. The various phase boundaries, i.e. the coherent binodal and spinodal lines, incoherent binodal line and order/disorder transformation line are distinctly determined for the Cu-Ti alloy and the other alloy systems. Furthermore, the equilibrium compositions at the interface of precipitate/matrix can experimentally be obtained for various particle sizes, and thus the Gibbs-Thomson's relation is verified. It is expected that the composition gradient method proposed in the present will become an important experimental method of the microstructural characterization

Deep learning the quantum phase transitions in random two-dimensional electron systems

International Nuclear Information System (INIS)

Ohtsuki, Tomoki; Ohtsuki, Tomi

2016-01-01

Random electron systems show rich phases such as Anderson insulator, diffusive metal, quantum Hall and quantum anomalous Hall insulators, Weyl semimetal, as well as strong/weak topological insulators. Eigenfunctions of each matter phase have specific features, but owing to the random nature of systems, determining the matter phase from eigenfunctions is difficult. Here, we propose the deep learning algorithm to capture the features of eigenfunctions. Localization-delocalization transition, as well as disordered Chern insulator-Anderson insulator transition, is discussed. (author)

Rhodium and Hafnium Influence on the Microstructure, Phase Composition, and Oxidation Resistance of Aluminide Coatings

OpenAIRE

Maryana Zagula-Yavorska; Małgorzata Wierzbińska; Jan Sieniawski

2017-01-01

A 0.5 μm thick layer of rhodium was deposited on the CMSX 4 superalloy by the electroplating method. The rhodium-coated superalloy was hafnized and aluminized or only aluminized using the Chemical vapour deposition method. A comparison was made of the microstructure, phase composition, and oxidation resistance of three aluminide coatings: nonmodified (a), rhodium-modified (b), and rhodium- and hafnium-modified (c). All three coatings consisted of two layers: the additive layer and the interdi...

Nanoalloying and phase transformations during thermal treatment of physical mixtures of Pd and Cu nanoparticles

Directory of Open Access Journals (Sweden)

Vineetha Mukundan

2014-03-01

Full Text Available Nanoscale alloying and phase transformations in physical mixtures of Pd and Cu ultrafine nanoparticles are investigated in real time with in situ synchrotron-based x-ray diffraction complemented by ex situ high-resolution transmission electron microscopy. The combination of metal–support interaction and reactive/non-reactive environment was found to determine the thermal evolution and ultimate structure of this binary system. At 300 °C, the nanoparticles supported on silica and carbon black intermix to form a chemically ordered CsCl-type (B2 alloy phase. The B2 phase transforms into a disordered fcc alloy at higher temperature (> 450 °C. The alloy nanoparticles supported on silica and carbon black are homogeneous in volume, but evidence was found of Pd surface enrichment. In sharp contrast, when supported on alumina, the two metals segregated at 300 °C to produce almost pure fcc Cu and Pd phases. Upon further annealing of the mixture on alumina above 600 °C, the two metals interdiffused, forming two distinct disordered alloys of compositions 30% and 90% Pd. The annealing atmosphere also plays a major role in the structural evolution of these bimetallic nanoparticles. The nanoparticles annealed in forming gas are larger than the nanoparticles annealing in helium due to reduction of the surface oxides that promotes coalescence and sintering.

Mathematical modeling of disperse two-phase flows

CERN Document Server

Morel, Christophe

2015-01-01

This book develops the theoretical foundations of disperse two-phase flows, which are characterized by the existence of bubbles, droplets or solid particles finely dispersed in a carrier fluid, which can be a liquid or a gas. Chapters clarify many difficult subjects, including modeling of the interfacial area concentration. Basic knowledge of the subjects treated in this book is essential to practitioners of Computational Fluid Dynamics for two-phase flows in a variety of industrial and environmental settings. The author provides a complete derivation of the basic equations, followed by more advanced subjects like turbulence equations for the two phases (continuous and disperse) and multi-size particulate flow modeling. As well as theoretical material, readers will discover chapters concerned with closure relations and numerical issues. Many physical models are presented, covering key subjects including heat and mass transfers between phases, interfacial forces and fluid particles coalescence and breakup, a...

Phase composition and saturated liquid properties in binary and ternary systems containing carbon dioxide, n-decane, and n-tetradecane

International Nuclear Information System (INIS)

Kariznovi, Mohammad; Nourozieh, Hossein; Abedi, Jalal

2013-01-01

Highlights: ► Binary and ternary systems of (carbon dioxide + n-decane + n-tetradecane) at 323.2 K. ► Isothermal phase properties measurements over wide range of pressure (1 to 6) MPa. ► Experimental measurements, density, viscosity, and composition, using a designed PVT apparatus. ► The experimental data were correlated using two equations of state. ► The interaction parameters and the volume shift values from the experimental data on the binary pairs. - Abstract: Experimental phase equilibrium data have been measured for the binary and ternary systems containing (carbon dioxide, n-decane, and n-tetradecane) at 323.2 K over the pressure range (1 to 6) MPa using a designed PVT apparatus. The measurements presented in this paper were undertaken to determine liquid phase composition and liquid saturated properties (density and viscosity) when a liquid hydrocarbon (n-decane, n-tetradecane, and their mixtures) was saturated with carbon dioxide. The generated data for compositions and densities were correlated with the Soave–Redlich–Kwong (SRK) and Peng–Robinson (PR) equations of state (EOS). The adjustment of binary interaction parameters and volume translation technique has been employed to correlate the experimental compositions and densities. The adjusted binary parameters from the data of binary pairs (carbon dioxide + n-decane) and (carbon dioxide + n-tetradecane) were used to correlate the generated ternary data. The calculated ternary compositions were found to be in good agreement with the experimental data using the binary parameters from the data of binary pairs for both EOSs. The results for the density of saturated liquid phase indicated that the volume translation should be applied to all components in the binary and ternary systems to describe accurately the saturated liquid densities for mixtures.

Phase stability and microstructures of high entropy alloys ion irradiated to high doses

Energy Technology Data Exchange (ETDEWEB)

Xia, Songqin [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing, 100083 (China); Gao, Michael C. [National Energy Technology Laboratory, 1450 Queen Ave SW, Albany, OR, 97321 (United States); AECOM, P.O. Box 1959, Albany, OR, 97321 (United States); Yang, Tengfei [State Key Laboratory of Nuclear Physics and Technology, Center for Applied Physics and Technology, Peking University, Beijing, 100871 (China); Liaw, Peter K. [Department of Materials Science and Engineering, The University of Tennessee, Knoxville, TN, 37996 (United States); Zhang, Yong, E-mail: drzhangy@ustb.edu.cn [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing, 100083 (China)

2016-11-15

The microstructures of Al{sub x}CoCrFeNi (x = 0.1, 0.75 and 1.5 in molar ratio) high entropy alloys (HEAs) irradiated at room temperature with 3 MeV Au ions at the highest fluence of 105, 91, and 81 displacement per atom, respectively, were studied. Transmission electron microscopy (TEM) and high-resolution TEM (HRTEM) analyses show that the initial microstructures and phase composition of all three alloys are retained after ion irradiation and no phase decomposition is observed. Furthermore, it is demonstrated that the disordered face-centered cubic (FCC) and disordered body-centered cubic (BCC) phases show much less defect cluster formation and structural damage than the NiAl-type ordered B2 phase. This effect is explained by higher entropy of mixing, higher defect formation/migration energies, substantially lower thermal conductivity, and higher atomic level stress in the disordered phases.

Two-phase LMMHD mixer-development experiments

International Nuclear Information System (INIS)

Fabris, G.; Dunn, P.F.; Chow, J.C.F.

1978-01-01

The results of a series of experiments conducted to evaluate the fluid mechanical performance of various two-phase LMMHD mixer designs are presented. The results from both flow visualization studies of the local two-phase flows downstream from various mixer-element configurations and local measurements performed to characterize these flows are presented. A conceptual LMMHD mixer design is described that insures the generation of small bubbles, prevents the formation of gas slugs and separated regions, and favors the stabilization of a homogeneous foam flow

Experimental on two sensors combination used in horizontal pipe gas-water two-phase flow

International Nuclear Information System (INIS)

Wu, Hao; Dong, Feng

2014-01-01

Gas-water two phase flow phenomenon widely exists in production and living and the measurement of it is meaningful. A new type of long-waist cone flow sensor has been designed to measure two-phase mass flow rate. Six rings structure of conductance probe is used to measure volume fraction and axial velocity. The calibration of them have been made. Two sensors have been combined in horizontal pipeline experiment to measure two-phase flow mass flow rate. Several model of gas-water two-phase flow has been discussed. The calculation errors of total mass flow rate measurement is less than 5% based on the revised homogeneous flow model

Dynamic Phase Boundary Estimation in Two-phase Flows Based on Electrical Impedance Tomography

International Nuclear Information System (INIS)

Lee, Jeong Seong; Muhammada, Nauman Malik; Kim, Kyung Youn; Kim, Sin

2008-01-01

For the dynamic visualization of the phase boundary in two-phase flows, the electrical impedance tomography (EIT) technique is introduced. In EIT, a set of predetermined electrical currents is injected through the electrodes placed on the boundary of the flow passage and the induced electrical potentials are measured on the electrodes. With the relationship between the injected currents and the induced voltages, the electrical conductivity distribution across the flow domain is estimated through the image reconstruction algorithm where the conductivity distribution corresponds to the phase distribution. In the application of EIT to two-phase flows where there are only two conductivity values, the conductivity distribution estimation problem can be transformed into the boundary estimation problem. This paper considers phase boundary estimation with EIT in annular two-phase flows. As the image reconstruction algorithm, the unscented Kalman filter (UKF) is adopted since from the control theory it is reported that the UKF shows better performance than the extended Kalman filter (EKF) that has been commonly used. For the present problem, the formulation of UKF algorithm involved its incorporation in the adopted image reconstruction algorithm. Also, phantom experiments have been conducted to evaluate the improvement reported by UKF

COMPOSITION OF MINERAL PHASES OF THE GHIDIRIM DIATOMITE

Directory of Open Access Journals (Sweden)

Vasile Rusu

2007-06-01

Full Text Available Studies of the mineralogical composition of diatomite from the Ghidirim location of RM, as well as of the extracted clay phase are presented. The mineral phase of the diatomite contains a number of clay minerals, like montmorillonite (in a mixture with insignificant quantities of slightly chloritized montmorillonite, illite and kaolinite. Diatomite contains also non-clay components as fine-dispersed quartz and amorphous material, the more probable sources of which are opal, amorphous alumosilicates, aluminum and iron hydroxides. The applied procedure for separation of clay fractions by sizing settling in liquid media proves to be very useful, enabling possibilities for more accurate identification of the clay constituents of diatomic material. Procedure allows to separate very clean clay fraction especially rich in montmorillonite, which can be utilized itself as mineral adsorbent for practical purposes.

Experimental and numerical investigation of form-stable dodecane/hydrophobic fumed silica composite phase change materials for cold energy storage

International Nuclear Information System (INIS)

Chen, Jiajie; Ling, Ziye; Fang, Xiaoming; Zhang, Zhengguo

2015-01-01

Highlights: • Form-stable dodecane/fumed silica composite for cold storage is prepared. • A suggesting hypothesis that explains infiltration mechanism is proposed. • The performance of the composite phase change material is investigated. • Numerical simulation of system is carried out and results fit well. - Abstract: A kind of form-stable composite phase change materials used for cold thermal energy storage is prepared by absorbing dodecane into the hydrophobic fumed silica. With relatively suitable pore diameter and hydrophobic groups, hydrophobic fumed silica is beneficial to the penetration and infiltration of dodecane and the leakage problem solving. Scanned by electron micrographs and Fourier transformation infrared, the composite phase change material is characterized to be just physical penetration. Besides, the differential scanning calorimeter and thermo gravimetric analysis reveals the high enthalpy, good thermal stability and cycling performance of this composite phase change material. What’s more, Hot-Disk thermal constants analyzer demonstrates that the composite phase change material has low thermal conductivity which is desired in cold storage application. In the experiment, a cold energy storage system is set up and the results from the experiment show that the system has excellent performance of cold storage by incorporating composite phase change material. Apart from that, the experimental data is found to have a great agreement with the numerical simulation which is carried out by using the commercial computational fluid dynamics software FLUENT.

Dissociative Identity Disorders in Korea: Two Recent Cases.

Science.gov (United States)

Kim, Ilbin; Kim, Daeho; Jung, Hyun-Jin

2016-03-01

Although dissociative identity disorder (DID), the most severe of the dissociative disorders, has retained its own diagnostic entity since its introduction in the DSM-III, cases of DID are rarely seen in South and East Asia, likely due to the higher prevalence of possession disorder. We report two patients with DID who were recently admitted to our inpatient psychiatric unit and demonstrated distinct transitions to several identities. Their diagnoses were confirmed through a structured interview for dissociative disorders and possible differential diagnoses were ruled out by psychological, neuroimaging, and laboratory tests. The rapid transition to a Westernized, individualized society along with an increase in child abuse, might contribute to an increase in DID, previously under-diagnosed in this region.

Extension of CFD Codes Application to Two-Phase Flow Safety Problems - Phase 3

International Nuclear Information System (INIS)

Bestion, D.; Anglart, H.; Mahaffy, J.; Lucas, D.; Song, C.H.; Scheuerer, M.; Zigh, G.; Andreani, M.; Kasahara, F.; Heitsch, M.; Komen, E.; Moretti, F.; Morii, T.; Muehlbauer, P.; Smith, B.L.; Watanabe, T.

2014-11-01

The Writing Group 3 on the extension of CFD to two-phase flow safety problems was formed following recommendations made at the 'Exploratory Meeting of Experts to Define an Action Plan on the Application of Computational Fluid Dynamics (CFD) Codes to Nuclear Reactor Safety Problems' held in Aix-en-Provence, in May 2002. Extension of CFD codes to two-phase flow is significant potentiality for the improvement of safety investigations, by giving some access to smaller scale flow processes which were not explicitly described by present tools. Using such tools as part of a safety demonstration may bring a better understanding of physical situations, more confidence in the results, and an estimation of safety margins. The increasing computer performance allows a more extensive use of 3D modelling of two-phase Thermal hydraulics with finer nodalization. However, models are not as mature as in single phase flow and a lot of work has still to be done on the physical modelling and numerical schemes in such two-phase CFD tools. The Writing Group listed and classified the NRS problems where extension of CFD to two-phase flow may bring real benefit, and classified different modelling approaches in a first report (Bestion et al., 2006). First ideas were reported about the specification and analysis of needs in terms of validation and verification. It was then suggested to focus further activity on a limited number of NRS issues with a high priority and a reasonable chance to be successful in a reasonable period of time. The WG3-step 2 was decided with the following objectives: - selection of a limited number of NRS issues having a high priority and for which two-phase CFD has a reasonable chance to be successful in a reasonable period of time; - identification of the remaining gaps in the existing approaches using two-phase CFD for each selected NRS issue; - review of the existing data base for validation of two-phase CFD application to the selected NRS problems

Aqueous preparation of polyethylene glycol/sulfonated graphene phase change composite with enhanced thermal performance

International Nuclear Information System (INIS)

Li, Hairong; Jiang, Ming; Li, Qi; Li, Denian; Chen, Zongyi; Hu, Waping; Huang, Jing; Xu, Xizhe; Dong, Lijie; Xie, Haian; Xiong, Chuanxi

2013-01-01

Highlights: • We report an aqueous preparation technique of PEG/graphene phase change composite. • Hydrophilic sulfonated graphene (SG) nanosheets were synthesized. • Large increase in thermal conductivity is attained at low SG loading. • High latent heat is retained due to the low filler loading. • Affinity between SG and PEG contributes to the enhanced thermal performance. - Abstract: A polyethylene glycol (PEG)/sulfonated graphene (SG) phase change composite with enhanced thermal performance was prepared by solution processing in aqueous medium. It is remarkable that the addition of only 4 wt.% of SG to PEG could lead to a four times higher increase in thermal conductivity and a slight decrease in the phase change enthalpy, which is attributed to the formation of efficient thermal conductive network within the PEG matrix relevant to the excellent thermal property and unique 2-dimensional morphology of graphene as well as strong interface affinity between PEG matrix and SG nanosheets. The aqueous preparation technique is expected to pioneer a new way to prepare environment friendly organic phase change materials, and the production of PEG/SG composites is potentially scalable due to the facile fabricating process

Methods of chemical and phase composition analysis of gallstones

Science.gov (United States)

Suvorova, E. I.; Pantushev, V. V.; Voloshin, A. E.

2017-11-01

This review presents the instrumental methods used for chemical and phase composition investigation of gallstones. A great body of data has been collected in the literature on the presence of elements and their concentrations, obtained by fluorescence microscopy, X-ray fluorescence spectroscopy, neutron activation analysis, proton (particle) induced X-ray emission, atomic absorption spectroscopy, high-resolution gamma-ray spectrometry, electron paramagnetic resonance. Structural methods—powder X-ray diffraction, infrared spectroscopy, Raman spectroscopy—provide information about organic and inorganic phases in gallstones. Stone morphology was studied at the macrolevel with optical microscopy. Results obtained by analytical scanning and transmission electron microscopy with X-ray energy dispersive spectrometry are discussed. The chemical composition and structure of gallstones determine the strategy of removing stone from the body and treatment of patients: surgery or dissolution in the body. Therefore one chapter of the review describes the potential of dissolution methods. Early diagnosis and appropriate treatment of the disease depend on the development of clinical methods for in vivo investigation, which gave grounds to present the main characteristics and potential of ultrasonography (ultrasound scanning), magnetic resonance imaging, and X-ray computed tomography.

Phase 2B experimental design for the INEEL glass composition variation study

International Nuclear Information System (INIS)

Peeler, D.

2000-01-01

The U.S. Department of Energy's (DOE's) Offices of Science and Technology (through the Tanks Focus Area [TFA]) and Waste Management are sponsoring a partnership among Idaho National Engineering and Environmental Laboratory (INEEL), Pacific Northwest National Laboratory (PNNL), and the Savannah River Technology Center (SRTC) for a collaborative glass composition variation study (CVS). The purpose of the CVS is to investigate property - composition relationships within a glass-composition region compatible with the expected range of Idaho Nuclear Technology and Engineering Center (INTEC) high-activity wastes (HAWs). The CVS has been conducted in phases to allow INEEL, PNNL, and SRTC researchers to adjust the glass composition region of interest as flowsheet options are refined and/or waste-stream compositions become more defined

Study of phase changing characteristics of granular composites using differential scanning calorimetry

International Nuclear Information System (INIS)

Rady, Mohamed

2009-01-01

Characterization of the phase changing behavior of granular materials is an important issue for design and optimization of latent heat thermal energy storage (LHTES) systems. In the present work, differential scanning calorimetry (DSC) has been used to study the phase changing behavior of granular composites consisting of ceramic encapsulated phase change material (EPCM) with particle diameters of 1-3 mm. The obtained DSC curves characterizing melting and solidification of the composite material are shown to be dependent upon the values of heating and cooling rates. Direct utilization of the measured DSC curves could result in an inexact representation of the sample enthalpy change. A simple procedure has been advised to obtain accurate quantitative results from the DSC measurements based on the estimation of the thermal resistance between the sample and its enclosure. Analysis of the evolution of latent heat of EPCM with temperature at different values of cooling/heating rates is presented.

GASCON and MHDGAS: FORTRAN IV computer codes for calculating gas and condensed-phase compositions in the coal-fired open-cycle MHD system

Energy Technology Data Exchange (ETDEWEB)

Blackburn, P E

1977-12-01

Fortran IV computer codes have been written to calculate the equilibrium partial pressures of the gaseous phase and the quantity and composition of the condensed phases in the open-cycle MHD system. The codes are based on temperature-dependent equilibrium constants, mass conservation, the mass action law, and assumed ideal solution of compounds in each of two condensed phases. It is assumed that the phases are an oxide-silicate phase and a sulfate-carbonate-hydroxide phase. Calculations are iterated for gas and condensate concentrations while increasing or decreasing the total moles of elements, but keeping mole ratios constant, to achieve the desired total pressure. During iteration the oxygen partial pressure is incrementally changed. The decision to increase or decrease the oxygen pressure in this process depends on comparison of the oxygen content calculated in the gas and condensate phases with the initial amount of oxygen in the ash, coal, seed, and air. This process, together with a normalization step, allows the elements to converge to their initial quantities. Two versions of the computer code have been written. GASCON calculates the equilibrium gas partial pressures and the quantity and composition of the condensed phases in steps of thirteen temperature and pressure combinations in which the condensate is removed after each step, simulating continuous slag removal from the MHD system. MHDGAS retains the condensate for each step, simulating flow of condensate (and gas) through the MHD system.

Synergy in lipofection by cationic lipid mixtures: superior activity at the gel-liquid crystalline phase transition.

Science.gov (United States)

Koynova, Rumiana; Wang, Li; MacDonald, Robert C

2007-07-12

Some mixtures of two cationic lipids including phospholipid compounds (O-ethylphosphatidylcholines) as well as common, commercially available cationic lipids, such as dimethylammonium bromides and trimethylammonium propanes, deliver therapeutic DNA considerably more efficiently than do the separate molecules. In an effort to rationalize this widespread "mixture synergism", we examined the phase behavior of the cationic lipid mixtures and constructed their binary phase diagrams. Among a group of more than 50 formulations, the compositions with maximum delivery activity resided unambiguously in the solid-liquid crystalline two-phase region at physiological temperature. Thus, the transfection efficacy of formulations exhibiting solid-liquid crystalline phase coexistence is more than 5 times higher than that of formulations in the gel (solid) phase and over twice that of liquid crystalline formulations; phase coexistence occurring at physiological temperature thus appears to contribute significantly to mixture synergism. This relationship between delivery activity and physical property can be rationalized on the basis of the known consequences of lipid-phase transitions, namely, the accumulation of defects and increased disorder at solid-liquid crystalline phase boundaries. Packing defects at the borders of coexisting solid and liquid crystalline domains, as well as large local density fluctuations, could be responsible for the enhanced fusogenicity of mixtures. This study leads to the important conclusion that manipulating the composition of the lipid carriers so that their phase transition takes place at physiological temperature can enhance their delivery efficacy.

A Novel Aqueous Two Phase System Composed of Surfactant and Xylitol for the Purification of Lipase from Pumpkin (Cucurbita moschata) Seeds and Recycling of Phase Components.

Science.gov (United States)

Amid, Mehrnoush; Manap, Mohd Yazid; Hussin, Muhaini; Mustafa, Shuhaimi

2015-06-17

Lipase is one of the more important enzymes used in various industries such as the food, detergent, pharmaceutical, textile, and pulp and paper sectors. A novel aqueous two-phase system composed of surfactant and xylitol was employed for the first time to purify lipase from Cucurbita moschata. The influence of different parameters such as type and concentration of surfactants, and the composition of the surfactant/xylitol mixtures on the partitioning behavior and recovery of lipase was investigated. Moreover, the effect of system pH and crude load on the degree of purification and yield of the purified lipase were studied. The results indicated that the lipase was partitioned into the top surfactant rich phase while the impurities partitioned into the bottom xylitol-rich phase using an aqueous two phase system composed of 24% (w/w) Triton X-100 and 20% (w/w) xylitol, at 56.2% of tie line length (TLL), (TTL is one of the important parameters in this study and it is determined from a bimodal curve in which the tie-line connects two nodes on the bimodal, that represent concentration of phase components in the top and bottom phases) and a crude load of 25% (w/w) at pH 8.0. Recovery and recycling of components was also measured in each successive step process. The enzyme was successfully recovered by the proposed method with a high purification factor of 16.4 and yield of 97.4% while over 97% of the phase components were also recovered and recycled. This study demonstrated that the proposed novel aqueous two phase system method is more efficient and economical than the traditional aqueous two phase system method for the purification and recovery of the valuable enzyme lipase.

A Novel Aqueous Two Phase System Composed of Surfactant and Xylitol for the Purification of Lipase from Pumpkin (Cucurbita moschata Seeds and Recycling of Phase Components

Directory of Open Access Journals (Sweden)

Mehrnoush Amid

2015-06-01

Full Text Available Lipase is one of the more important enzymes used in various industries such as the food, detergent, pharmaceutical, textile, and pulp and paper sectors. A novel aqueous two-phase system composed of surfactant and xylitol was employed for the first time to purify lipase from Cucurbita moschata. The influence of different parameters such as type and concentration of surfactants, and the composition of the surfactant/xylitol mixtures on the partitioning behavior and recovery of lipase was investigated. Moreover, the effect of system pH and crude load on the degree of purification and yield of the purified lipase were studied. The results indicated that the lipase was partitioned into the top surfactant rich phase while the impurities partitioned into the bottom xylitol-rich phase using an aqueous two phase system composed of 24% (w/w Triton X-100 and 20% (w/w xylitol, at 56.2% of tie line length (TLL, (TTL is one of the important parameters in this study and it is determined from a bimodal curve in which the tie-line connects two nodes on the bimodal, that represent concentration of phase components in the top and bottom phases and a crude load of 25% (w/w at pH 8.0. Recovery and recycling of components was also measured in each successive step process. The enzyme was successfully recovered by the proposed method with a high purification factor of 16.4 and yield of 97.4% while over 97% of the phase components were also recovered and recycled. This study demonstrated that the proposed novel aqueous two phase system method is more efficient and economical than the traditional aqueous two phase system method for the purification and recovery of the valuable enzyme lipase.

Fatty acid composition of the postmortem prefrontal cortex of patients with schizophrenia, bipolar disorder, and major depressive disorder.

Science.gov (United States)

Hamazaki, Kei; Maekawa, Motoko; Toyota, Tomoko; Dean, Brian; Hamazaki, Tomohito; Yoshikawa, Takeo

2015-06-30

Postmortem brain studies have shown abnormal levels of n-3 polyunsaturated fatty acids (PUFAs), especially docosahexaenoic acid, in the frontal cortex (particularly the orbitofrontal cortex) of patients with depression, schizophrenia, or bipolar disorder. However, the results from regions in the frontal cortex other than the orbitofrontal cortex are inconsistent. In this study we investigated whether patients with schizophrenia, bipolar disorder, or major depressive disorder have abnormalities in PUFA levels in the prefrontal cortex [Brodmann area (BA) 8]. In postmortem studies, fatty acids in the phospholipids of the prefrontal cortex (BA8) were evaluated by thin layer chromatography and gas chromatography. Specimens were evaluated for patients with schizophrenia (n=15), bipolar disorder (n=15), or major depressive disorder (n=15) and compared with unaffected controls (n=15). In contrast to previous studies, we found no significant differences in the levels of PUFAs or other fatty acids in the prefrontal cortex (BA8) between patients and controls. Subanalysis by sex also showed no significant differences. No significant differences were found in any individual fatty acids between suicide and non-suicide cases. These psychiatric disorders might be characterized by very specific fatty acid compositions in certain areas of the brain, and BA8 might not be involved in abnormalities of PUFA metabolism. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

Prevalence of Depressive Disorder of Outpatients Visiting Two Primary Care Settings.

Science.gov (United States)

Jo, Sun-Jin; Yim, Hyeon Woo; Jeong, Hyunsuk; Song, Hoo Rim; Ju, Sang Yhun; Kim, Jong Lyul; Jun, Tae-Youn

2015-09-01

Although the prevalence of depressive disorders in South Korea's general population is known, no reports on the prevalence of depression among patients who visit primary care facilities have been published. This preliminary study was conducted to identify the prevalence of depressive disorder in patients that visit two primary care facilities. Among 231 consecutive eligible patients who visited two primary care settings, 184 patients consented to a diagnostic interview for depression by psychiatrists following the Diagnostic and Statistical Manual of Mental Disorders-IV criteria. There were no significant differences in sociodemographic characteristics such as gender, age, or level of education between the groups that consented and declined the diagnostic examination. The prevalence of depressive disorder and the proportion of newly diagnosed patients among depressive disorder patients were calculated. The prevalence of depressive disorder of patients in the two primary care facilities was 14.1% (95% confidence interval [CI], 9.1 to 19.2), with major depressive disorder 5.4% (95% CI, 2.1 to 8.7), dysthymia 1.1% (95% CI, 0.0 to 2.6), and depressive disorder, not otherwise specified 7.6% (95% CI, 3.7 to 11.5). Among the 26 patients with depressive disorder, 19 patients were newly diagnosed. As compared to the general population, a higher prevalence of depressive disorders was observed among patients at two primary care facilities. Further study is needed with larger samples to inform the development of a primary care setting-based depression screening, management, and referral system to increase the efficiency of limited health care resources.

Prevalence of Depressive Disorder of Outpatients Visiting Two Primary Care Settings

Directory of Open Access Journals (Sweden)

Sun-Jin Jo

2015-09-01

Full Text Available Objectives: Although the prevalence of depressive disorders in South Korea’s general population is known, no reports on the prevalence of depression among patients who visit primary care facilities have been published. This preliminary study was conducted to identify the prevalence of depressive disorder in patients that visit two primary care facilities. Methods: Among 231 consecutive eligible patients who visited two primary care settings, 184 patients consented to a diagnostic interview for depression by psychiatrists following the Diagnostic and Statistical Manual of Mental Disorders-IV criteria. There were no significant differences in sociodemographic characteristics such as gender, age, or level of education between the groups that consented and declined the diagnostic examination. The prevalence of depressive disorder and the proportion of newly diagnosed patients among depressive disorder patients were calculated. Results: The prevalence of depressive disorder of patients in the two primary care facilities was 14.1% (95% confidence interval [CI], 9.1 to 19.2, with major depressive disorder 5.4% (95% CI, 2.1 to 8.7, dysthymia 1.1% (95% CI, 0.0 to 2.6, and depressive disorder, not otherwise specified 7.6% (95% CI, 3.7 to 11.5. Among the 26 patients with depressive disorder, 19 patients were newly diagnosed. Conclusions: As compared to the general population, a higher prevalence of depressive disorders was observed among patients at two primary care facilities. Further study is needed with larger samples to inform the development of a primary care setting-based depression screening, management, and referral system to increase the efficiency of limited health care resources.

Stearic-acid/carbon-nanotube composites with tailored shape-stabilized phase transitions and light–heat conversion for thermal energy storage

International Nuclear Information System (INIS)

Li, Benxia; Nie, Shibin; Hao, Yonggan; Liu, Tongxuan; Zhu, Jinbo; Yan, Shilong

2015-01-01

Highlights: • A facile preparation of shape-stabilized composite PCMs for thermal energy storage. • The composite PCMs present tunable phase change temperatures and enthalpy. • Sunlight-driven phase change for photothermal conversion and storage. - Abstract: The development of functional materials with both light–heat conversion and thermal energy storage properties is of crucial importance for efficient utilization of sunlight to meet the growing demand for sustainable energy. In this work, the shape-stabilized phase change composites were designed and prepared by integration of stearic acid (SA) and acid-treated carbon nanotubes (a-CNTs). The a-CNTs not only acted as a flexible matrix but also endowed the composites high light–heat conversion ability. The reversible phase transitions shifted from high temperatures (T m = 74 °C, T f = 57 °C) of pure SA to near room temperature (T m = ∼30 °C, T f = ∼22 °C) of SA/a-CNTs composites, probably resulting from the strong interface confinement effect. The phase change enthalpy of the SA/a-CNTs composite could also be tailored by changing the mass ratio of SA and a-CNTs. The composites containing SA of 54.2 wt.%, 67.8 wt.% and 79.5 wt.% presented the melting enthalpy of 76.3 J/g, 98.8 J/g and 111.8 J/g, respectively. Moreover, the phase transition of SA/a-CNTs composite could be driven by sunlight for the energy storage/release. Therefore, this research provides a new platform for improving solar utilization, and understanding the phase transition behaviors of organic PCMs in dimensionally confined environments as well

Phase defects and spatiotemporal disorder in traveling-wave convection patterns

International Nuclear Information System (INIS)

La Porta, A.; Surko, C.M.

1997-01-01

Spatiotemporal disorder is studied in traveling-wave convection in ethanol-water mixtures. Spectral measures of disorder, linear correlation functions, and mutual information are used to characterize the patterns, and are found to give a weak indication of the level of disorder. The calculation of the complex order parameter for experimental patterns is described. It is found that the ordering of the patterns is accompanied by a dramatic change in the topological structure of the order parameter. Specific arrangements of defects are found to be associated with the elements of traveling-wave patterns, and the net charge and total number of defects is introduced as a measure of disorder in the patterns. The coarsening of the patterns is marked by an accumulation of net charge and a dramatic decrease in the number of defects. The physical significance of the defects is discussed, and it is shown that the phase velocity of the waves is lower in the vicinity of the defects. The defect-defect correlation functions are calculated for the convection patterns. It is shown that the ordering of the patterns is closely related to the apparent defect-defect interactions. copyright 1997 The American Physical Society

Disorder and pseudogap in strongly correlated systems: Phase diagram in the DMFT + Σ approach

International Nuclear Information System (INIS)

Kuleeva, N. A.; Kuchinskii, E. Z.

2013-01-01

The influence of disorder and pseudogap fluctuations on the Mott insulator-metal transition in strongly correlated systems has been studied in the framework of the generalized dynamic mean field theory (DMFT + Σ approach). Using the results of investigations of the density of states (DOS) and optical conductivity, a phase diagram (disorder-Hubbard interaction-temperature) is constructed for the paramagnetic Anderson-Hubbard model, which allows both the effects of strong electron correlations and the influence of strong disorder to be considered. Strong correlations are described using the DMFT, while a strong disorder is described using a generalized self-consistent theory of localization. The DOS and optical conductivity of the paramagnetic Hubbard model have been studied in a pseudogap state caused by antiferromagnetic spin (or charge) short-range order fluctuations with a finite correlation length, which have been modeled by a static Gaussian random field. The effect of a pseudogap on the Mott insulator-metal transition has been studied. It is established that, in both cases, the static Gaussian random field (related to the disorder or pseudogap fluctuations) leads to suppression of the Mott transition, broadening of the coexistence region of the insulator and metal phases, and an increase in the critical temperature at which the coexistence region disappears

Two-phase flow characteristics analysis code: MINCS

International Nuclear Information System (INIS)

Watanabe, Tadashi; Hirano, Masashi; Akimoto, Masayuki; Tanabe, Fumiya; Kohsaka, Atsuo.

1992-03-01

Two-phase flow characteristics analysis code: MINCS (Modularized and INtegrated Code System) has been developed to provide a computational tool for analyzing two-phase flow phenomena in one-dimensional ducts. In MINCS, nine types of two-phase flow models-from a basic two-fluid nonequilibrium (2V2T) model to a simple homogeneous equilibrium (1V1T) model-can be used under the same numerical solution method. The numerical technique is based on the implicit finite difference method to enhance the numerical stability. The code structure is highly modularized, so that new constitutive relations and correlations can be easily implemented into the code and hence evaluated. A flow pattern can be fixed regardless of flow conditions, and state equations or steam tables can be selected. It is, therefore, easy to calculate physical or numerical benchmark problems. (author)

Coupling two-phase fluid flow with two-phase darcy flow in anisotropic porous media

KAUST Repository

Chen, J.; Sun, S.; Chen, Z.

2014-01-01

in the free fluid region and the two-phase Darcy law in the anisotropic porous medium region. A Robin-Robin domain decomposition method is used for the coupled Navier-Stokes and Darcy system with the generalized Beavers-Joseph-Saffman condition

Cold storage condensation heat recovery system with a novel composite phase change material

International Nuclear Information System (INIS)

Xia, Mingzhu; Yuan, Yanping; Zhao, Xudong; Cao, Xiaoling; Tang, Zhonghua

2016-01-01

Highlights: • Cold storage condensation heat recovery system using PCM was proposed. • CW with a phase change temperature of nearly 80 °C was selected as the potential PCM. • The optimal mass ratio between the CW and EG was 10:1. • The thermal and physical performances of the CW/EG were investigated. • The thermal reliability was demonstrated by 1000 cycles. - Abstract: Using condensation heat from cold storage refrigeration systems to provide heat for domestic hot water preparation and industrial hot water supply promotes energy conservation. However, few studies have investigated cold storage condensation heat recovery using phase change materials (PCMs). In this study, a cold storage condensation heat recovery system that uses PCMs has been designed and analysed. According to the principle of energy cascade recycling, different operation modes could be effectively switched to recycle condensation heat. Furthermore, a novel and suitable phase change composite material is developed for cold storage condensation heat recovery, which has a relatively large latent heat, high thermal conductivity, and an appropriate phase change temperature (i.e. 80 °C). With carnauba wax (CW) as the PCM and expanded graphite (EG) as the additive, a composite was developed with an optimal mass ratio of CW:EG = 10:1. The thermal and physical properties and the interior structure of the composite were then investigated using a scanning electron microscope (SEM), thermal constants analyser (Hot Disk), differential scanning calorimeter (DSC), and Fourier transform infrared spectrometer (FT-IR). Furthermore, experiments on the melting and solidification processes and accelerated thermal cycling were also conducted. It was found that at the optimal mass ratio of 10:1, the temperatures of the CW/EG composite in the melting and solidification processes were 81.98 °C and 80.43 °C, respectively, while the corresponding latent heats were 150.9 J/g and 142.6 J/g, respectively

Three-dimensional numerical modeling of turbulent single-phase and two-phase flow in curved pipes

International Nuclear Information System (INIS)

Xin, R.C.; Dong, Z.F.; Ebadian, M.A.

1996-01-01

In this study, three-dimensional single-phase and two-phase flows in curved pipes have been investigated numerically. Two different pipe configurations were computed. When the results of the single-phase flow simulation were compared with the experimental data, a fairly good agreement was achieved. A flow-developing process has been suggested in single-phase flow, in which the turbulence is stronger near the outer tube wall than near the inner tube wall. For two-phase flow, the Eulerian multiphase model was used to simulate the phase distribution of a three-dimensional gas-liquid bubble flow in curved pipe. The RNG/κ-ε turbulence model was used to determine the turbulence field. An inlet gas void fraction of 5 percent was simulated. The gas phase effects on the liquid phase flow velocity have been examined by comparing the results of single-phase flow and two-phase flow. The findings show that for the downward flow in the U bend, the gas concentrates at the inner portion of the cross section at φ = π/18 - π/6 in most cases. The results of the phase distribution simulation are compared to experimental observations qualitatively and topologically

Fatty acids profile and nutritional composition of two tropical diatoms from the Costa Rican Pacific Coast

Directory of Open Access Journals (Sweden)

K. Rodríguez-Núñez

2017-09-01

Full Text Available Microalgae represent an important nutritional source for diverse organisms, therefore, their nutritional value, and more specifically, total lipid and fatty acid contents, must be considered. This study evaluated the nutritional contents and potential growth under controlled conditions of Nitzschia sp. and Chaetoceros sp. Tropical microalgae, isolated from the Gulf of Nicoya, Costa Rica. In both strains, the nutritional composition and the fatty acid profile were evaluated in exponential and stationary phases. With regards to fatty acids, v sp. had more Eicosapentaenoic Acid (EPA in both the exponential (32.80% and stationary (27.20% phases. The results in growth rate, production and biochemical composition indicated two tropical microalgae strains suitable for cultivation under controlled conditions. The studies of the phytoplankton in this geographical area is highly relevant because of its importance in the primary production of nutrients and the importance of finding sources of fatty acids such as the EPA.

Numerical simulation for two-phase jet problem

International Nuclear Information System (INIS)

Lee, W.H.; Shah, V.L.

1981-01-01

A computer program TWOP was developed for obtaining the numerical solutions of three-dimensional, transient, two-phase flow system with nonequilibrium and nonhomogeneous conditions. TWOP employs two-fluid model and a set of the conservation equations formulated by Harlow and Amsden along with their Implicit Multi-Field (IMF) numerical technique that allows all degrees of couplings between the two fields. We have further extended the procedure of Harlow and Amsden by incorporating the implicit couplings of phase transition and interfacial heat transfer terms in the energy equations. Numerical results of two tested problems are presented to demonstrate the capabilities of the TWOP code. The first problem is the separation of vapor and liquid, showing that the code can handle the computational difficulties such as liquid packing and sharp interface phenomena. The second problem is the high pressure two-phase jet impinged on vertical plate, demonstrating the important role of the interfacial mass and momentum exchange

A functional form-stable phase change composite with high efficiency electro-to-thermal energy conversion

International Nuclear Information System (INIS)

Wu, Wenhao; Huang, Xinyu; Li, Kai; Yao, Ruimin; Chen, Renjie; Zou, Ruqiang

2017-01-01

Graphical abstract: The thermal conductivity of PU was enhanced to 43 times of the pristine value by encapsulation in a PGF, PU@PGF can be used for highly efficient electro-to-heat energy conversion and storage with the highest energy storage efficiency up to 85%. - Highlights: • The composite exhibits an in-situ solid-solid phase change behavior. • The enthalpy of polyurethane is enhanced within the matrix. • The thermal conductivity of the composite is 43 times as much as that of the polyurethane. • Supercooling of polyurethane is greatly reduced. • The composite is applied to cold protection as a wear layer. - Abstract: A novel solid-to-solid phase change composite brick was prepared by combination of polyurethane (PU) and pitch-based graphite foam (PGF). The carbonaceous support, which can be used for mass production, not only greatly improves the thermal conductivity but promote electro-to-heat conversion efficiency of organic phase change materials (PCMs). Our composite retained the enthalpy of PCM and exhibited a greatly reduced supercooling temperature. The novel composite was investigated by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and scanning electron microscope (SEM). The enthalpy of polyurethane has increased about 8.6% after infiltrating into graphite foam. The composite was very stable during thermal cycle test, and the electro-to-heat conversion efficiency achieves to 85% at lower voltages (1.5–1.8 V), which can vastly reduce energy consumption. The as-prepared composite was used in a wear layer to test its performance comparing with normal fabric.

A composite peripheral blood gene expression measure as a potential diagnostic biomarker in bipolar disorder

DEFF Research Database (Denmark)

Munkholm, Klaus; Peijs, L; Vinberg, M

2015-01-01

as a diagnostic and state biomarker in bipolar disorder. First, messenger RNA levels of 19 candidate genes were assessed in peripheral blood mononuclear cells of 37 rapid cycling bipolar disorder patients in different affective states (depression, mania and euthymia) during a 6-12-month period and in 40 age...... subjects. In patients with bipolar disorder, upregulation of NDUFV2 was observed in a depressed state compared with a euthymic state. The composite gene expression measure for discrimination between patients and healthy control subjects on the basis of 19 genes generated an area under the receiver...

MAX Phase Modified SiC Composites for Ceramic-Metal Hybrid Cladding Tubes

International Nuclear Information System (INIS)

Jung, Yang-Il; Kim, Sun-Han; Park, Dong-Jun; Park, Jeong-Hwan; Park, Jeong-Yong; Kim, Hyun-Gil; Koo, Yang-Hyun

2015-01-01

A metal-ceramic hybrid cladding consists of an inner zirconium tube, and an outer SiC fiber-matrix SiC ceramic composite with surface coating as shown in Fig. 1 (left-hand side). The inner zirconium allows the matrix to remain fully sealed even if the ceramic matrix cracks through. The outer SiC composite can increase the safety margin by taking the merits of the SiC itself. In addition, the outermost layer prevents the dissolution of SiC during normal operation. On the other hand, a ceramic-metal hybrid cladding consists of an outer zirconium tube, and an inner SiC ceramic composite as shown in Fig. 1 (right-hand side). The outer zirconium protects the fuel rod from a corrosion during reactor operation, as in the present fuel claddings. The inner SiC composite, additionally, is designed to resist the severe oxidation under a postulated accident condition of a high-temperature steam environment. Reaction-bonded SiC was fabricated by modifying the matrix as the MAX phase. The formation of Ti 3 SiC 2 was investigated depending on the compositions of the preform and melt. In most cases, TiSi 2 was the preferential phase because of its lowest melting point in the Ti-Si-C system. The evidence of Ti 3 SiC 2 was the connection with the pressurizing

Thermal Performance Study of Composite Phase Change Material with Polyacrylicand Conformal Coating.

Science.gov (United States)

Kee, Shin Yiing; Munusamy, Yamuna; Ong, Kok Seng; Cornelis Metselaar, Hendrik Simon; Chee, Swee Yong; Lai, Koon Chun

2017-07-28

The composite PCM was prepared by blending polymethyl methacrylate (PMMA) and myristic acid (MA) in different weight percentages. The MA and PMMA were selected as PCM and supporting material, respectively. As liquid MA may leak out during the phase transition, this study proposes the use of two coatings, namely a polyacrylic coating and a conformal coating to overcome the leakage problem. Both coatings were studied in terms of the leakage test, chemical compatibility, thermal stability, morphology, and reliability. No leakage was found in the PCMs with coatings compared to those without under the same proportions of MA/PMMA, thus justifying the use of coatings in the present study. The chemically compatibility was confirmed by FTIR spectra: the functional groups of PCMs were in accordance with those of coatings. DSC showed that the coatings did not significantly change the melting and freezing temperatures, however, they improved the thermal stability of composite PCMs as seen in TGA analysis. Furthermore, the composite PCMs demonstrated good thermal reliability after 1000 times thermal cycling. The latent heat of melting reduced by only 0.16% and 1.02% for the PCMs coated with conformal coating and polyacrylic coating, respectively. Therefore, the proposed coatings can be considered in preparing fatty acid/PMMA blends attributed to the good stability, compatibility and leakage prevention.

Visual Analysis of Inclusion Dynamics in Two-Phase Flow.

Science.gov (United States)

Karch, Grzegorz Karol; Beck, Fabian; Ertl, Moritz; Meister, Christian; Schulte, Kathrin; Weigand, Bernhard; Ertl, Thomas; Sadlo, Filip

2018-05-01

In single-phase flow visualization, research focuses on the analysis of vector field properties. In two-phase flow, in contrast, analysis of the phase components is typically of major interest. So far, visualization research of two-phase flow concentrated on proper interface reconstruction and the analysis thereof. In this paper, we present a novel visualization technique that enables the investigation of complex two-phase flow phenomena with respect to the physics of breakup and coalescence of inclusions. On the one hand, we adapt dimensionless quantities for a localized analysis of phase instability and breakup, and provide detailed inspection of breakup dynamics with emphasis on oscillation and its interplay with rotational motion. On the other hand, we present a parametric tightly linked space-time visualization approach for an effective interactive representation of the overall dynamics. We demonstrate the utility of our approach using several two-phase CFD datasets.

Modeling creep deformation of a two-phase TiAI/Ti3Al alloy with a lamellar microstructure

Science.gov (United States)

Bartholomeusz, Michael F.; Wert, John A.

1994-10-01

A two-phase TiAl/Ti3Al alloy with a lamellar microstructure has been previously shown to exhibit a lower minimum creep rate than the minimum creep rates of the constituent TiAl and Ti3Al single-phase alloys. Fiducial-line experiments described in the present article demonstrate that the creep rates of the constituent phases within the two-phase TiAl/Ti3Al lamellar alloy tested in compression are more than an order of magnitude lower than the creep rates of single-phase TiAl and Ti3Al alloys tested in compression at the same stress and temperature. Additionally, the fiducial-line experiments show that no interfacial sliding of the phases in the TiAl/Ti3Al lamellar alloy occurs during creep. The lower creep rate of the lamellar alloy is attributed to enhanced hardening of the constituent phases within the lamellar microstructure. A composite-strength model has been formulated to predict the creep rate of the lamellar alloy, taking into account the lower creep rates of the constituent phases within the lamellar micro-structure. Application of the model yields a very good correlation between predicted and experimentally observed minimum creep rates over moderate stress and temperature ranges.

Polygenic risk for five psychiatric disorders and cross-disorder and disorder-specific neural connectivity in two independent populations.

Science.gov (United States)

Wang, Tianqi; Zhang, Xiaolong; Li, Ang; Zhu, Meifang; Liu, Shu; Qin, Wen; Li, Jin; Yu, Chunshui; Jiang, Tianzi; Liu, Bing

2017-01-01

Major psychiatric disorders, including attention deficit hyperactivity disorder (ADHD), autism (AUT), bipolar disorder (BD), major depressive disorder (MDD), and schizophrenia (SZ), are highly heritable and polygenic. Evidence suggests that these five disorders have both shared and distinct genetic risks and neural connectivity abnormalities. To measure aggregate genetic risks, the polygenic risk score (PGRS) was computed. Two independent general populations (N = 360 and N = 323) were separately examined to investigate whether the cross-disorder PGRS and PGRS for a specific disorder were associated with individual variability in functional connectivity. Consistent altered functional connectivity was found with the bilateral insula: for the left supplementary motor area and the left superior temporal gyrus with the cross-disorder PGRS, for the left insula and right middle and superior temporal lobe associated with the PGRS for autism, for the bilateral midbrain, posterior cingulate, cuneus, and precuneus associated with the PGRS for BD, and for the left angular gyrus and the left dorsolateral prefrontal cortex associated with the PGRS for schizophrenia. No significant functional connectivity was found associated with the PGRS for ADHD and MDD. Our findings indicated that genetic effects on the cross-disorder and disorder-specific neural connectivity of common genetic risk loci are detectable in the general population. Our findings also indicated that polygenic risk contributes to the main neurobiological phenotypes of psychiatric disorders and that identifying cross-disorder and specific functional connectivity related to polygenic risks may elucidate the neural pathways for these disorders.

New phase transitions in lead zirconate-titanate

International Nuclear Information System (INIS)

Ishchuk, V.M.; Morozov, E.M.; Klimov, V.V.

1977-01-01

Processes of disordering are considered in the paraelectric phase of lead zirconate-titanate. Te investigations were carried out on poly- and single-crystal specimens of the composition PbZrsub(1-x)Tisub(x)O 3 (0< x(<=)0.5). The results are presented of measurements of the temperature dependence of the dielectric constant and the dependence of the polarization on the temperature and the electric field. Anomaly is observed of the investigated characteristics above the Curie point due to a first-type phase transition. The results are interpreted within the framework of the model proposed by Coms, Lambert, and Guiniot, according to which this transition is due to the disordering of chains of unit cells existing above the Curie point

Modeling two-phase flow in PEM fuel cell channels

Energy Technology Data Exchange (ETDEWEB)

Wang, Yun; Basu, Suman; Wang, Chao-Yang [Electrochemical Engine Center (ECEC), and Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Park, PA 16802 (United States)

2008-05-01

This paper is concerned with the simultaneous flow of liquid water and gaseous reactants in mini-channels of a proton exchange membrane (PEM) fuel cell. Envisaging the mini-channels as structured and ordered porous media, we develop a continuum model of two-phase channel flow based on two-phase Darcy's law and the M{sup 2} formalism, which allow estimate of the parameters key to fuel cell operation such as overall pressure drop and liquid saturation profiles along the axial flow direction. Analytical solutions of liquid water saturation and species concentrations along the channel are derived to explore the dependences of these physical variables vital to cell performance on operating parameters such as flow stoichiometric ratio and relative humility. The two-phase channel model is further implemented for three-dimensional numerical simulations of two-phase, multi-component transport in a single fuel-cell channel. Three issues critical to optimizing channel design and mitigating channel flooding in PEM fuel cells are fully discussed: liquid water buildup towards the fuel cell outlet, saturation spike in the vicinity of flow cross-sectional heterogeneity, and two-phase pressure drop. Both the two-phase model and analytical solutions presented in this paper may be applicable to more general two-phase flow phenomena through mini- and micro-channels. (author)

Abnormal screening in the quantum disordered phases of nonlinear σ-models

International Nuclear Information System (INIS)

Wen, X.G.; Zee, A.

1989-01-01

We study some properties of the quantum disordered phase of nonlinear σ-models, focussing on the quantum numbers of the quasi-particles and possible experimental implications. We find that the quasi-particles in the quantum disordered phase may, in many cases, carry new quantum numbers which do not appear in any finite combination of the fundamental fields. We call this phenomenon abnormal screening. Abnormal screening is shown to appear in (1+1)-dimensional systems. Using a large N mean field approach to the quantum disordered state, we show that abnormal screening may also appear in (1+2)-dimensional nonlinear σ-models. In 1+2 dimensions abnormal screening is closely related to spin-charge separation, which was proposed to occur in the spin liquid state relevant in some theories of high T c superconductivity. We compare the mean field approach with bosonization and other exact results for (1+1)-dimensional systems and find exact agreement for the quantum numbers of the quasi-particles. This suggests that mean field analysis of high T c superconductivity may yield a qualitatively reliable picture. Our result also gives an alternative way of understanding some novel properties of the antiferromagnetic spin chain. We estimate the density and temperature at which deconfinement and abnormal screening occur. Finally, we suggest some experimental signatures for this phenomenon. (orig.)

Parallel two-phase-flow-induced vibrations in fuel pin model

International Nuclear Information System (INIS)

Hara, Fumio; Yamashita, Tadashi

1978-01-01

This paper reports the experimental results of vibrations of a fuel pin model -herein meaning the essential form of a fuel pin from the standpoint of vibration- in a parallel air-and-water two-phase flow. The essential part of the experimental apparatus consisted of a flat elastic strip made of stainless steel, both ends of which were firmly supported in a circular channel conveying the two-phase fluid. Vibrational strain of the fuel pin model, pressure fluctuation of the two-phase flow and two-phase-flow void signals were measured. Statistical measures such as power spectral density, variance and correlation function were calculated. The authors obtained (1) the relation between variance of vibrational strain and two-phase-flow velocity, (2) the relation between variance of vibrational strain and two-phase-flow pressure fluctuation, (3) frequency characteristics of variance of vibrational strain against the dominant frequency of the two-phase-flow pressure fluctuation, and (4) frequency characteristics of variance of vibrational strain against the dominant frequency of two-phase-flow void signals. The authors conclude that there exist two kinds of excitation mechanisms in vibrations of a fuel pin model inserted in a parallel air-and-water two-phase flow; namely, (1) parametric excitation, which occurs when the fundamental natural frequency of the fuel pin model is related to the dominant travelling frequency of water slugs in the two-phase flow by the ratio 1/2, 1/1, 3/2 and so on; and (2) vibrational resonance, which occurs when the fundamental frequency coincides with the dominant frequency of the two-phase-flow pressure fluctuation. (auth.)

Composition and property measurements for PHA Phase 4 glasses

International Nuclear Information System (INIS)

Edwards, T.B.

2000-01-01

The results presented in this report are for nine Precipitate Hydrolysis Aqueous (PHA) Phase 4 glasses. Three of the glasses contained HM sludge at 22, 26, and 30 wt% respectively, 10 wt% PHA and 1.25 wt% monosodium titanate (MST), all on an oxide basis. The remaining six glasses were selected from the Phase 1 and Phase 2 studies (Purex sludge) but with an increased amount of MST. The high-end target for MST of 2.5 wt% oxide was missed in Phases 1 and 2 due to ∼30 wt% water content of the MST. A goal of this Phase 4 study was to determine whether this increase in titanium concentration from the MST had any impact on glass quality or processibility. Two of the glasses, pha14c and pha15c, were rebatched and melted due to apparent batching errors with pha14 and pha15. The models currently in the Defense Waste Processing Facility's (DWPF) Product Composition Control System (PCCS) were used to predict durability, homogeneity, liquidus, and viscosity for these nine glasses. All of the HM glasses and half of the Purex glasses were predicted to be phase separated, and consequently prediction of glass durability is precluded with the cument models for those glasses that failed the homogeneity constraint. If one may ignore the homogeneity constraint, the measured durabilities were within the 95% prediction limits of the model. Further efforts will be required to resolve this issue on phase separation (inhomogeneity). The liquidus model predicted unacceptable liquidus temperatures for four of the nine glasses. The approximate, bounding liquidus temperatures measured for all had upper limits of 1,000 C or less. Given the fact that liquidus temperatures were only approximated, the 30 wt% loading of Purex may be near or at the edge of acceptability for liquidus. The measured viscosities were close to the predictions of the model. For the Purex glasses, pha12c and pha15c, the measured viscosities of 28 and 23 poise, respectively, indicate that DWPF processing may be compromised

Phase-separation control of KxFe2-ySe2 superconductor through rapid-quenching process

International Nuclear Information System (INIS)

Yanagisawa, Yusuke; Tanaka, Masashi; Yamashita, Aichi; Suzuki, Kouji; Hara, Hiroshi; Takeya, Hiroyuki; Takano, Yoshihiko; ElMassalami, Mohammed

2017-01-01

K x Fe 2-y Se 2 exhibits iron-vacancy ordering at T s ∼ 270°C and separates into two phases: a minor superconducting (iron-vacancy-disordered) phase and a major non-superconducting (iron-vacancy-ordered) phase. The microstructural and superconducting properties of this intermixture can be tuned by an appropriate control of the quenching process through T s . A faster quenching rate leads to a finer microstructure and a suppression of formation of the non-superconducting phase by up to 50%. Nevertheless, such a faster cooling rate induces a monotonic reduction in the superconducting transition temperature (from 30.7 to 26.0 K) and, simultaneously, a decrease in the iron content within the superconducting phase such that the compositional ratio changed from K 0.35 Fe 1.83 Se 2 to K 0.58 Fe 1.71 Se 2 . (author)

Application of Ultrasonic Phased Array Technology to the Detection of Defect in Composite Stiffened-structures

Science.gov (United States)

Zhou, Yuan-Qi; Zhan, Li-Hua

2016-05-01

Composite stiffened-structure consists of the skin and stringer has been widely used in aircraft fuselage and wings. The main purpose of the article is to detect the composite material reinforced structure accurately and explore the relationship between defect formation and structural elements or curing process. Based on ultrasonic phased array inspection technology, the regularity of defects in the manufacture of composite materials are obtained, the correlation model between actual defects and nondestructive testing are established. The article find that the forming quality of deltoid area in T-stiffened structure is obviously improved by pre-curing, the defects of hat-stiffened structure are affected by the mandrel. The results show that the ultrasonic phased array inspection technology can be an effectively way for the detection of composite stiffened-structures, which become an important means to control the defects of composite and improve the quality of the product.

Fluid dynamics of cryogenic two-phase flows

International Nuclear Information System (INIS)

Verfondern, K.; Jahn, W.

2004-01-01

The objective of this study was to examine the flow behavior of a methane hydrate/methane-liquid hydrogen dispersed two-phase fluid through a given design of a moderator chamber for the ESS target system. The calculations under simplified conditions, e.g., taking no account of heat input from outside, have shown that the computer code used, CFX, was able to simulate the behavior of the two-phase flow through the moderator chamber, producing reasonable results up to a certain level of the solid phase fraction, that allowed a continuous flow process through the chamber. Inlet flows with larger solid phase fractions than 40 vol% were found to be a ''problem'' for the computer code. From the computer runs based on fractions between 20 and 40 vol%, it was observed that with increasing solid phase fraction at the inlet, the resulting flow pattern revealed a strong tendency for blockage within the chamber, supported by the ''heavy weight'' of the pellets compared to the carrying liquid. Locations which are prone to the development of such uneven flow behavior are the areas around the turning points in the semispheres and near the exit of the moderator. The considered moderator chamber with horizontal inlet and outlet flow for a solid-liquid two-phase fluid does not seem to be an appropriate design. (orig.)

Compositional disordering of GaAs/AlGaAs multiple quantum wells using ion bombardment at elevated temperatures

International Nuclear Information System (INIS)

Anderson, K.K.; Donnelly, J.P.; Wang, C.A.; Woodhouse, J.D.; Haus, H.A.

1988-01-01

A new method has been developed for compositional mixing of heterostructures by ion bombardment at elevated temperatures. Complete mixing of a 1-μm-thick GaAs/AlGaAs 40-period multiple quantum well layer has been achieved by bombardment with 380 keV Ne + ions for 1 h with the sample at 700 0 C. This temperature is much lower than the annealing temperatures used in other vacancy-enhanced disordering techniques, and even lower temperatures and shorter durations should be possible. Compositional disordering is verified by sputter-profile Auger electron spectroscopy and transmission electron microscopy. Complete mixing is also demonstrated by optical transmission spectra of the disordered material, which exhibit the same band edge as a uniform alloy with the average aluminum mole fraction of the multiple quantum well layer

Chemical and phase composition of powders obtained by electroerosion dispersion from alloys WC-Co

International Nuclear Information System (INIS)

Putintseva, M.N.

2004-01-01

A consideration is given to the dependence of chemical and phase compositions of dispersed powders on the conditions, the medium of electroerosion dispersing and the content of cobalt in an initial alloy. It is shown that dissociation of carbon from tungsten carbide proceeds even on dispersing in liquid hydrocarbon-containing media (kerosene and machine oil). The phase composition is determined to a large extent by a medium of dispersing and a cobalt content in the initial alloy. In all powders complex tungsten-cobalt carbides and even Co 7 W 6 intermetallic compounds are found [ru

Chemical and Phase Composition of Powders Obtained by Electroerosion Dispersion from WC - Co Alloys

Science.gov (United States)

Putintseva, M. N.

2004-03-01

The dependence of the chemical and phase composition of dispersed powders on the mode and medium of electroerosion dispersion and the content of cobalt in the initial alloy is considered. It is shown that the dissociation of carbon from tungsten carbide occurs even in dispersion in liquid hydrocarbon-bearing media (kerosene and industrial oils). The phase composition is primarily determined by the dispersion medium and the content of cobalt in the initial alloy. Compound tungsten-cobalt carbides and even a Co7W6 intermetallic are determined in all the powders.

Preparation and properties of lauric acid/silicon dioxide composites as form-stable phase change materials for thermal energy storage

International Nuclear Information System (INIS)

Fang Guiyin; Li Hui; Liu Xu

2010-01-01

Form-stable lauric acid (LA)/silicon dioxide (SiO 2 ) composite phase change materials were prepared using sol-gel methods. The LA was used as the phase change material for thermal energy storage, with the SiO 2 acting as the supporting material. The structural analysis of these form-stable LA/SiO 2 composite phase change materials was carried out using Fourier transformation infrared spectroscope (FT-IR). The microstructure of the form-stable composite phase change materials was observed by a scanning electronic microscope (SEM). The thermal properties and thermal stability were investigated by a differential scanning calorimeter (DSC) and a thermogravimetric analysis apparatus (TGA), respectively. The SEM results showed that the LA was well dispersed in the porous network of SiO 2 . The DSC results indicated that the melting latent heat of the form-stable composite phase change material is 117.21 kJ kg -1 when the mass percentage of the LA in the SiO 2 is 64.8%. The results of the TGA showed that these materials have good thermal stability. The form-stable composite phase change materials can be used for thermal energy storage in waste heat recovery and solar heating systems.

Fluid-elastic vibration in two-phase cross flow