WorldWideScience

Sample records for two-part underwater epoxy

  1. A simple protocol using underwater epoxy to install annual temperature monitoring sites in rivers and streams

    Science.gov (United States)

    Daniel J. Isaak; Dona L. Horan; Sherry P. Wollrab

    2013-01-01

    Thermal regimes in rivers and streams are fundamental determinants of biological processes and are often monitored for regulatory compliance. Here, we describe a simple technique for establishing annual monitoring sites that uses underwater epoxy to attach miniature sensors to large rocks and cement bridge supports, which then serve as protective anchors. More than 500...

  2. Advanced Nanocomposite Coatings of Fusion Bonded Epoxy Reinforced with Amino-Functionalized Nanoparticles for Applications in Underwater Oil Pipelines

    Directory of Open Access Journals (Sweden)

    Patricia A. Saliba

    2016-01-01

    Full Text Available The performance of fusion-bonded epoxy coatings can be improved through advanced composite coatings reinforced with nanomaterials. Hence, in this study a novel organic-inorganic nanocomposite finish was designed, synthesized, and characterized, achieved by adding γ-aminopropyltriethoxysilane modified silica nanoparticles produced via sol-gel process in epoxy-based powder. After the curing process of the coating reinforced with nanoparticles, the formation of a homogenous novel nanocomposite with the development of interfacial reactions between organic-inorganic and inorganic-inorganic components was observed. These hybrid nanostructures produced better integration between nanoparticles and epoxy matrix and improved mechanical properties that are expected to enhance the overall performance of the system against underwater corrosion.

  3. Underwater acoustic performance simulation of polyurethane/epoxy resin elastomer%聚氨酯/环氧树脂弹性体声学性能仿真∗

    Institute of Scientific and Technical Information of China (English)

    孙卫红; 刘波; 晏欣; 高孔军

    2015-01-01

    An underwater acoustic model of polyurethane/epoxy resin (PU/EP)elastomer was established based on the acoustic boundary conditions,the influences of the PU/EP elastomer’s elastic modulus,loss factor and Poisson’s ratio to its acoustic performance;the underwater acoustic property of PU/EP(70/30)elastomer was tested on underwater acoustic pulsetube system.The simulation results showed that larger modulus,suitably damping factor and higher Poisson ratio were the key to obtain low reflection and high acoustic absorption per-formance.The underwater acoustic test results showe that the average acoustic absorption coefficient of PU/EP (70/30)elastomers was 0.39,the maximum absorption coefficient was 0.42,and the reflection coefficient over the entire frequency range of less than 0.4,it can be used as acoustic absorbing material matrix.And the numer-ical examples show the experimental results of PU/EP elastomer were basically consistent with the acoustic model simulation results.%基于声学边界条件,建立了聚氨酯/环氧树脂(PU/EP)弹性体的水声模型,探讨了弹性体弹性模量、损耗因子及泊松比对其声学性能的影响;在水声脉冲声管中测试了PU/EP 的水声性能并进行了算例验证.仿真结果表明,较大的模量、合适的阻尼因子和较高的泊松比是 PU/EP 弹性体获得低反射、高吸声性能的关键.水声测试结果表明,PU/EP(70/30)弹性体的平均吸声系数为0.39,最大吸声系数为0.42,且反射系数在整个频段范围内小于0.4,可作为水声吸声材料的基材.算例验证表明,计算结果与实验测量结果吻合的较好.

  4. 环氧树脂基轻质芯材夹层复合吸声结构的水声性能%Underwater Acoustic Properties of Sound Absorption Structure of Sandwich Composites Based on Light Epoxy Resin Core Material

    Institute of Scientific and Technical Information of China (English)

    李浩; 梅志远; 朱锡

    2011-01-01

    Sound absorption structure of light sandwich composite based on epoxy resin (EPS) was synthesized from glass fiber, vinyl ester resins, epoxy resin, hollow glass microsphere. The underwater acoustical properties of EPS specimen were measured in the sound pulse tube and anechoic tank. The experiment results indicate that underwater acoustic properties of EPS are affected by the technological parameters of core material such as proportion of matrix, content of polyether amine curing agent and proportion of upper and lower layer. The underwater sound absorption coefficient of EPS is not less than 0.5 at 5 kHz ~ 30 kHz with the relative density 0.8 + 0.05 and thickness 25 mm of core material by regulating the technological parameters. EPS has a low density and excellent underwater sound stealth properties. The application range of sound absorption structure of sandwich composite will be enlarged. Then, sound absorption mechanism of EPS was analyzed.%用玻璃纤维、乙烯基树脂、环氧树脂和空心玻璃微珠等为原料合成了环氧树脂基轻质夹层复合吸声结构(EPS),在脉冲声管和消声水池中测试了EPS试件的反射系数和吸声系数,测试结果表明,EPS的水声性能受到芯材基体比例、聚醚胺固化剂含量及分层比例等工艺参数的影响,通过合理控制这些参数,可以使芯材相对密度0.8±0.05、厚度25 mm的EPS在5kHz~30kHz频段内平均吸声系数不低于0.5,具有质轻和良好的水下声隐身能力,扩大了夹层复合吸声结构的使用范围.最后对EPS的吸声机理进行了分析.

  5. EPU/EP 弹性体的力学及水声吸声性能%Mechanical properties and underwater acoustic absorption properties of epoxyurethane/epoxy elastomers

    Institute of Scientific and Technical Information of China (English)

    孙卫红; 刘波; 晏欣

    2014-01-01

    Epoxyurethane (EPU)was prepared using dibutyltin dilaurate (DBTDL)as a catalyst and glycidol as a capping agent.EPU and EPU /EP blend elastomers were prepared using butyl acrylate-diethylenetriamine (BA-DETA)as a curing agent with the casting method,the tensile properties,dynamic mechanical properties and underwater acoustic properties of these blend elastomers were characterized.The results showed that the tensile strength of EPU /EP blend elastomers increases with increase in amount of epoxy resin;the tensile strength of TDI-type epoxyurethanes are higher than that of IPDI-type epoxyurethane;with increase in content of EP,the middle and high temperature transition peaks and Young's modulus of TDI-type epoxyurethane /E-51 blends become larger,and the compatibility of the two components becomes worse;EPU1 /E-51 series blends have a good underwater acoustic absorption ability;the underwater acoustic absorption ability of EPU1 /E-51 (70 /30)elastomers is the best,its average acoustic absorption coefficient is 0.75,and its maximum acoustic absorption coefficient is 0.94.%以二丁基二月桂酸锡(DBTDL)作催化剂、环氧丙醇作封端剂制备了环氧氨酯(EPU);以自制的丙烯酸丁酯-二乙烯三胺(BA -DETA)为固化剂用浇铸法制备了 EPU 及环氧氨酯/环氧树脂(EPU /EP)共混物弹性体,并对该系列共混物弹性体的力学性能、动态力学性能和水声声学性能进行了表征,研究结果表明:随着 EP 用量的增加,EPU /EP 共混物的拉伸强度逐渐增大,TDI 型环氧氨酯的抗拉强度高于 IPDI 型环氧氨酯;随着 EP 含量的增加,TDI 型环氧氨酯/环氧-E51(EPU1/E -51)共混物中、高温转变峰增强,杨氏模量变大,两组分相容性变差;EPU1/E -51系列共混物具有良好的水声吸声性能。EPU1/E -51(70/30)弹性体的水声性能最优,其平均吸声系数为0.75,最大吸声系数为0.94。

  6. Two-part set systems

    CERN Document Server

    Gerbner, Dániel; Lemons, Nathan; Mubayi, Dhruv; Palmer, Cory; Patkós, Balázs

    2011-01-01

    The two part Sperner theorem of Katona and Kleitman states that if $X$ is an $n$-element set with partition $X_1 \\cup X_2$, and $\\cF$ is a family of subsets of $X$ such that no two sets $A, B \\in \\cF$ satisfy $A \\subset B$ (or $B \\subset A$) and $A \\cap X_i=B \\cap X_i$ for some $i$, then $|\\cF| \\le {n \\choose \\lfloor n/2 \\rfloor}$. We consider variations of this problem by replacing the Sperner property with the intersection property and considering families that satisfiy various combinations of these properties on one or both parts $X_1$, $X_2$. Along the way, we prove the following new result which may be of independent interest: let $\\cF, \\cG$ be families of subsets of an $n$-element set such that $\\cF$ and $\\cG$ are both intersecting and cross-Sperner, meaning that if $A \\in \\cF$ and $B \\in \\cG$, then $A \

  7. Underwater robots

    CERN Document Server

    Antonelli, Gianluca

    2014-01-01

    This book, now at the third edition, addresses the main control aspects in underwater manipulation tasks. The mathematical model with significant impact on the control strategy is discussed. The problem of controlling a 6-degrees-of-freedoms autonomous underwater vehicle is deeply investigated and a survey of fault detection/tolerant strategies for unmanned underwater vehicles is provided. Inverse kinematics, dynamic and interaction control for underwater vehicle-manipulator systems are then discussed. The code used to generate most of the numerical simulations is made available and briefly discussed.       

  8. Google™ underwater

    Science.gov (United States)

    Showstack, Randy

    2012-10-01

    The first underwater panoramic images were added to Google Maps™, the company announced on 25 September. This first “underwater Street View collection,” launched in partnership with the Caitlin Seaview Survey, provides people with the opportunity to “become the next virtual Jacques Cousteau.” For more information, see: maps.google.com/ocean.

  9. Epoxy resins.

    Science.gov (United States)

    Bray, P G

    1999-01-01

    Epoxy resins have an extraordinarily broad range of commercial applications, especially as protective surface coatings and adhesives. Epoxy resin systems include combinations of epoxy monomers, hardeners, reactive diluents, and/or a vast array of other additives. As a result, an epoxy resin system may have a number of chemical ingredients with the potential for attendant health hazards. Most, but not all, of these health hazards arise in the occupational setting. The most frequent adverse effects are irritation or allergic mechanisms involving the dermal and respiratory systems. Sensitization usually is caused by low molecular weight or short-chain compounds. This review discusses the diagnosis, treatment, and prevention of epoxy resin-related adverse health effects.

  10. Epoxy sheathing

    National Research Council Canada - National Science Library

    1992-01-01

    ... their vessels using polyester resins. In May 1990, several fishermen applied to the Vessel Upgrading Program for assistance to fiberglass their vessels using epoxy resin for the purpose of extending fishing vessel life...

  11. Epoxy resin

    Science.gov (United States)

    Wilson, Glenn R.; Salyer, Ival O.; Ball, III, George L.

    1976-07-13

    By mixing one part of a prepolymer containing a polyamine partially polymerized with an organic epoxide and subsequently reacted with a fatty acid containing from 8 to 32 carbon atoms, and then reacting this prepolymer mixture with 3 parts of an organic epoxide, a composition was obtained which made a gas frothable, shear-stable, room temperature curing, low density foam. A particularly advantageous prepolymer was prepared using a polyamine selected from the group consisting of diethylenetriamine, triethylenetetramine, and tetraethylenepentamine, partially polymerized with an organic epoxide having an average molecular weight of about 350 and having an epoxide equivalent of 185 to 192, and reacted with 2-10 weight percent linoleic acid. When one part of this prepolymer was reacted with about three parts of epoxy, and frothed by whipping in air or nitrogen an epoxy foam was produced which could be troweled onto surfaces and into corners or crevices, and subsequently cured, at near ambient temperature, to a strong dimensionally stable foam product.

  12. Underwater manipulator

    Science.gov (United States)

    Schrum, P.B.; Cohen, G.H.

    1993-04-20

    Self-contained, waterproof, water-submersible, remote-controlled apparatus is described for manipulating a device, such as an ultrasonic transducer for measuring crack propagation on an underwater specimen undergoing shock testing. The subject manipulator includes metal bellows for transmittal of angular motions without the use of rotating shaft seals or O-rings. Inside the manipulator, a first stepper motor controls angular movement. In the preferred embodiment, the bellows permit the first stepper motor to move an ultrasonic transducer [plus minus]45 degrees in a first plane and a second bellows permit a second stepper motor to move the transducer [plus minus]10 degrees in a second plane orthogonal to the first. In addition, an XY motor-driven table provides XY motion.

  13. Underwater Sound Reference Division

    Data.gov (United States)

    Federal Laboratory Consortium — The Underwater Sound Reference Division (USRD) serves as the U.S. standardizing activity in the area of underwater acoustic measurements, as the National Institute...

  14. Underwater Sound Reference Division

    Data.gov (United States)

    Federal Laboratory Consortium — The Underwater Sound Reference Division (USRD) serves as the U.S. standardizing activity in the area of underwater acoustic measurements, as the National Institute...

  15. Radiation curing of epoxies

    Science.gov (United States)

    Dickson, Lawrence W.; Singh, Ajit

    The literature on radiation polymerization of epoxy compounds has been reviewed to assess the potential use of radiation for curing these industrially important monomers. Chemical curing of epoxies may proceed by either cationic or anionic mechanisms depending on the nature of the curing agent, but most epoxies polymerize by cationic mechanisms under the influence of high-energy radiation. Radiation-induced cationic polymerization of epoxy compounds is inhibited by trace quantities of water because of proton transfer from the chain-propagating epoxy cation to water. Several different methods with potential for obtaining high molecular weight polymers by curing epoxies with high-energy radiation have been studied. Polymeric products with epoxy-like properties have been produced by radiation curing of epoxy oligomers with terminal acrylate groups and mixtures of epoxies with vinyl monomers. Both of these types of resin have good potential for industrial-scale curing by radiation treatment.

  16. Performance of Underwater Weldments

    Science.gov (United States)

    1990-09-05

    Underwater Wet Welds," Underwater Welding Soudage Sous L’Eau, Proceedings of the International Conference held at Trondheim, Norway, 27-28 June 1983 under...Wet Welds", Underwater Welding Soudage Sous L’Eau, Proceedings of the International Conference held at Trondheim, Norway, 27-28 June 1983 under the

  17. Blind equalization for underwater communications

    NARCIS (Netherlands)

    Blom, Koen Cornelis Hubertus

    2014-01-01

    Underwater wireless (sensor) networks would vastly improve man's ability to explore and exploit remote aquatic environments. Despite underwater sensor and vehicle technology being relatively mature, underwater communications is still a major challenge. The most challenging characteristics of the und

  18. Underwater Coatings Testing for INEEL Fuel Basin Applications

    Energy Technology Data Exchange (ETDEWEB)

    Julia L. Tripp

    2004-01-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) is deactivating several fuel storage basins. Airborne contamination is a concern when the sides of the basins are exposed and allowed to dry during water removal. One way of controlling this airborne contamination is to fix the contamination in place while the pool walls are still submerged. There are many underwater coatings available on the market that are used in marine, naval and other applications. A series of tests were run to determine whether the candidate underwater fixatives are easily applied and adhere well to the substrates (pool wall materials) found in INEEL fuel pools. The four pools considered included (1) Test Area North (TAN-607) with epoxy painted concrete walls; (2) Idaho Nuclear Technology and Engineering Center (INTEC) (CPP-603) with bare concrete walls; (3) Materials Test Reactor (MTR) Canal with stainless steel lined concrete walls; and (4) Power Burst Facility (PBF-620) with stainless steel lined concrete walls on the bottom and epoxy painted carbon steel lined walls on the upper portions. Therefore, the four materials chosen for testing included bare concrete, epoxy painted concrete, epoxy painted carbon steel, and stainless steel. The typical water temperature of the pools varies from 55 F to 80 F dependent on the pool and the season. These tests were done at room temperature.

  19. Flame Retardant Epoxy Resins

    Science.gov (United States)

    Thompson, C. M.; Smith, J. G., Jr.; Connell, J. W.; Hergenrother, P. M.; Lyon, R. E.

    2004-01-01

    As part of a program to develop fire resistant exterior composite structures for future subsonic commercial aircraft, flame retardant epoxy resins are under investigation. Epoxies and their curing agents (aromatic diamines) containing phosphorus were synthesized and used to prepare epoxy formulations. Phosphorus was incorporated within the backbone of the epoxy resin and not used as an additive. The resulting cured epoxies were characterized by thermogravimetric analysis, propane torch test, elemental analysis and microscale combustion calorimetry. Several formulations showed excellent flame retardation with phosphorous contents as low as 1.5% by weight. The fracture toughness of plaques of several cured formulations was determined on single-edge notched bend specimens. The chemistry and properties of these new epoxy formulations are discussed.

  20. Underwater Scene Composition

    Science.gov (United States)

    Kim, Nanyoung

    2009-01-01

    In this article, the author describes an underwater scene composition for elementary-education majors. This project deals with watercolor with crayon or oil-pastel resist (medium); the beauty of nature represented by fish in the underwater scene (theme); texture and pattern (design elements); drawing simple forms (drawing skill); and composition…

  1. Underwater Acoustic Networking Techniques

    CERN Document Server

    Otnes, Roald; Casari, Paolo; Goetz, Michael; Husøy, Thor; Nissen, Ivor; Rimstad, Knut; van Walree, Paul; Zorzi, Michele

    2012-01-01

    This literature study presents an overview of underwater acoustic networking. It provides a background and describes the state of the art of all networking facets that are relevant for underwater applications. This report serves both as an introduction to the subject and as a summary of existing protocols, providing support and inspiration for the development of network architectures.

  2. Design and characterization of cellulose nanocrystal-enhanced epoxy hardeners

    Science.gov (United States)

    Shane X. Peng; Robert J. Moon; Jeffrey P. Youngblood

    2014-01-01

    Cellulose nanocrystals (CNCs) are renewable, sustainable, and abundant nanomaterial widely used as reinforcing fillers in the field of polymer nanocomposites. In this study, two-part epoxy systems with CNC-enhanced hardeners were fabricated. Three types of hardeners, Jeffamine D400 (JD400), diethylenetriamine (DETA), and (±)-trans-1,2- diaminocyclohexane (DACH), were...

  3. Approximation of the two-part MDL code

    NARCIS (Netherlands)

    Adriaans, P.; Vitányi, P.M.B.

    2009-01-01

    Approximation of the optimal two-part minimum description length (MDL) code for given data, through successive monotonically length-decreasing two-part MDL codes, has the following properties: (i) computation of each step may take arbitrarily long; (ii) we may not know when we reach the optimum, or

  4. Approximation of the two-part MDL code

    NARCIS (Netherlands)

    P. Adriaans; P.M.B. Vitányi (Paul)

    2009-01-01

    htmlabstractApproximation of the optimal two-part minimum description length (MDL) code for given data, through successive monotonically length-decreasing two-part MDL codes, has the following properties: (i) computation of each step may take arbitrarily long; (ii) we may not know when we reach the

  5. Epoxy + liquid crystalline epoxy coreacted network

    Science.gov (United States)

    Punchaipetch, Prakaipetch

    2000-10-01

    Molecular reinforcement through in-situ polymerization of liquid crystalline epoxies (LCEs) and a non-liquid crystalline epoxy has been investigated. Three LCEs: diglycidyl ether of 4,4'-dihydroxybiphenol (DGE-DHBP) and digylcidyl ether of 4-hydroxyphenyl-4″-hydroxybiphenyl-4 '-carboxylate (DGE-HHC), were synthesized and blended with diglycidyl ether of bisphenol F (DGEBP-F) and subsequently cured with anhydride and amine curing agents. Curing kinetics were determined using differential scanning calorimetry (DSC). Parameters for autocatalytic curing kinetics of both pure monomers and blended systems were determined. The extent of cure for both monomers was monitored by using Fourier transform infrared spectroscopy (FT-IR). The glass transitions were evaluated as a function of composition using DSC and dynamic mechanical analysis (DMA). The results show that the LC constituent affects the curing kinetics of the epoxy resin and that the systems are highly miscible. The effects of molecular reinforcement of DGEBP-F by DGE-DHBP and DGE-HHC were investigated. The concentration of the liquid crystalline moiety affects mechanical properties. Tensile, impact and fracture toughness tests results are evaluated. Scanning electron microscopy of the fracture surfaces shows changes in failure mechanisms compared to the pure components. Results indicate that mechanical properties of the blended samples are improved already at low concentration by weight of the LCE added into epoxy resin. The improvement in mechanical properties was found to occur irrespective of the absence of liquid crystallinity in the blended networks. The mechanism of crack study indicates that crack deflection and crack bridging are the mechanisms in case of LC epoxy. In case of LC modified epoxy, the crack deflection is the main mechanism. Moreover, the effect of coreacting an epoxy with a reactive monomer liquid crystalline epoxy as a matrix for glass fiber composites was investigated. Mechanical

  6. Underwater wireless communication system

    Energy Technology Data Exchange (ETDEWEB)

    Goh, J H; Shaw, A; Al-Shamma' a, A I, E-mail: j.h.goh@2006.ljmu.ac.u [Liverpool John Moores University, General Engineering Research Institute (GERI), RF and Microwave Group, Byrom Street, Liverpool, L3 3AF (United Kingdom)

    2009-07-01

    Underwater communication has a range of applications including remotely operated vehicle (ROV) and autonomous underwater vehicle (AUV) communication and docking in the offshore industry. Current underwater transmission techniques is primarily utilise sound waves for large distance at lower frequencies and the velocity of sound in water is approximately 1500m/s the resultant communications have problems with multi-path propagation and low bandwidth problems. The use of electromagnetic (EM) techniques underwater has largely been overlooked because of the attenuation due to the conductivity of seawater. However, for short range applications, the higher frequencies and much higher velocity can prove advantageous. This paper will outline a project which will utilise recent investigations that demonstrate EM wave propagation up to the MHz frequency range is possible in seawater.

  7. Trends in underwater warfare : From an underwater acoustics perspective

    NARCIS (Netherlands)

    Ort, C.M.; Driessen, F.P.G.

    2002-01-01

    Technological developments concerning underwater systems for Anti Submarine Warfare (ASW) and Mine Counter Measures (MCM) are directed at optimally countering the underwater threat in the near future. Countering the existing underwater threat is already extremely difficult, but there are several tre

  8. Resources for Underwater Robotics Education

    Science.gov (United States)

    Wallace, Michael L.; Freitas, William M.

    2016-01-01

    4-H clubs can build and program underwater robots from raw materials. An annotated resource list for engaging youth in building underwater remotely operated vehicles (ROVs) is provided. This article is a companion piece to the Research in Brief article "Building Teen Futures with Underwater Robotics" in this issue of the "Journal of…

  9. Securing underwater wireless communication networks

    OpenAIRE

    Domingo Aladrén, Mari Carmen

    2011-01-01

    Underwater wireless communication networks are particularly vulnerable to malicious attacks due to the high bit error rates, large and variable propagation delays, and low bandwidth of acoustic channels. The unique characteristics of the underwater acoustic communication channel, and the differences between underwater sensor networks and their ground-based counterparts require the development of efficient and reliable security mechanisms. In this article, a compl...

  10. Multiwall carbon nanotubes reinforced epoxy nanocomposites

    Science.gov (United States)

    Chen, Wei

    The emergence of carbon nanotubes (CNTs) has led to myriad possibilities for structural polymer composites with superior specific modulus, strength, and toughness. While the research activities in carbon nanotube reinforced polymer composites (NRPs) have made enormous progress towards fabricating next-generation advanced structural materials with added thermal, optical, and electrical advantages, questions concerning the filler dispersion, interface, and CNT alignment in these composites remain partially addressed. In this dissertation, the key technical challenges related to the synthesis, processing, and reinforcing mechanics governing the effective mechanical properties of NRPs were introduced and reviewed in the first two chapters. Subsequently, issues on the dispersion, interface control, hierarchical structure, and multi-functionality of NRPs were addressed based on functionalized multi-walled carbon nanotube reinforced DGEBA epoxy systems (NREs). In chapter 3, NREs with enhanced flexural properties were discussed in the context of improved dispersion and in-situ formation of covalent bonds at the interface. In chapter 4, NREs with controlled interface and tailored thermomechanical properties were demonstrated through the judicious choice of surface functionality and resin chemistry. In chapter 5, processing-condition-induced CNT organization in hierarchical epoxy nanocomposites was analyzed. In Chapter 6, possibilities were explored for multi-functional NREs for underwater acoustic structural applications. Finally, the findings of this dissertation were concluded and future research was proposed for ordered carbon nanotube array reinforced nanocomposites in the last chapter. Four journal publications resulted from this work are listed in Appendix.

  11. RESEARCH ON IMPROVED EPOXY RESINS.

    Science.gov (United States)

    another ’million-modulus’ epoxy resin. Cast resin properties from a series of epoxy resins hardened with several aromatic diamines are reported, but these data are sufficient to advance only speculative conclusions. (Author)

  12. Underwater Navigation using Pseudolite

    Directory of Open Access Journals (Sweden)

    Krishneshwar Tiwary

    2011-07-01

    Full Text Available Using pseudolite or pseudo satellite, a proven technology for ground and space applications for the augmentation of GPS, is proposed for underwater navigation. Global positioning systems (GPS like positioning for underwater system, needs minimum of four pseudolite-ranging signals for pseudo-range and accumulated delta range measurements. Using four such measurements and using the models of underwater attenuation and delays, the navigation solution can be found. However, for application where the one-way ranging does not give good accuracy, alternative algorithms based upon the bi-directional and self-difference ranging is proposed using selfcalibrated pseudolite array algorithm. The hardware configuration is proposed for pseudolite transceiver for making the self-calibrated array. The pseudolite array, fixed or moored under the sea, can give position fixing similar to GPS for underwater applications.Defence Science Journal, 2011, 61(4, pp.331-336, DOI:http://dx.doi.org/10.14429/dsj.61.1087

  13. A two-part model for censored medical cost data.

    Science.gov (United States)

    Tian, Lu; Huang, Jie

    2007-10-15

    The two-part model is often used to analyse medical cost data which contain a large proportion of zero cost and are highly skewed with some large costs. The total medical costs over a period of time are often censored due to incomplete follow-up, making the analysis difficult as the censoring can be informative. We propose to apply the inverse probability weighting method on a two-part model to analyse right-censored cumulative medical costs with informative censoring. We also introduce a set of simple functionals based on the intermediate cost history to be applied with the efficiency augmentation technique. In addition, we propose a practical model-checking technique based on the cumulative residuals. Simulation studies are conducted to evaluate the finite sample performance of the proposed method. We use a data set on the cardiovascular disease (CVD)-related Medicare costs to illustrate our proposed method.

  14. Cobalt ion-containing epoxies

    Science.gov (United States)

    Stoakley, D. M.; St.clair, A. K.

    1983-01-01

    Varying concentrations of an organometallic cobalt complex were added to an epoxy system currently used by the aerospace industry as a composite matrix resin. Methods for combining cobalt (III) acetylacetonate with a tetraglycidyl 4,4 prime - diaminodiphenylmethane-based epoxy were investigated. The effects of increasing cobalt ion concentration on the epoxy cure were demonstrated by epoxy gel times and differential scanning calorimetry cure exotherms. Analysis on cured cobalt-containing epoxy castings included determination of glass transition temperatures by thermomechanical analysis, thermooxidative stabilities by thermogravimetric analysis, and densities in a density gradient column. Flexural strength and stiffness were also measured on the neat resin castings.

  15. Explosive welding underwater

    Energy Technology Data Exchange (ETDEWEB)

    Sim, T.; Allen, K.; Lowes, J.M.

    1980-06-11

    Explosive welding underwater is described. First and second underwater tubular members are assembled together so that the outer surface of the first tubular member and the inner surface of the second tubular member are spaced apart to form an annular cavity. The cavity is closed by seals accommodated in portions of the second tubular member, and is then cleaned and dried and filled with a gas at a pressure greater than the surrounding water pressure. The pressure in the cavity is reduced prior to detonating an explosive charge within the first tubular member to weld the members together. The second tubular member may include portions for receiving further seals so as to subdivide the cavity into a number of zones. The pressures in the zones then can be separately adjusted so as to be able to control the pressure difference a cross each seal. 9 claims.

  16. Mechanics of underwater noise

    CERN Document Server

    Ross, Donald

    1976-01-01

    Mechanics of Underwater Noise elucidates the basic mechanisms by which noise is generated, transmitted by structures and radiated into the sea. Organized into 10 chapters, this book begins with a description of noise, decibels and levels, significance of spectra, and passive sonar equation. Subsequent chapters discuss sound waves in liquids; acoustic radiation fundamentals; wind-generated ocean ambient noise; vibration isolation and structural damping; and radiation by plate flexural vibrations. Other chapters address cavitation, propeller cavitation noise, radiation by fluctuating-force (dipo

  17. Underwater Gliders: A Review

    Directory of Open Access Journals (Sweden)

    Javaid Muhammad Yasar

    2014-07-01

    Full Text Available Underwater gliders are a type of underwater vehicle that transverse the oceans by shifting its buoyancy, during which its wings develop a component of the downward motion in the horizontal plane, thus producing a forward force. They are primarily used in oceanography sensing and data collection and play an important role in ocean research and development. Although there have been considerable developments in these gliders since the development of the first glider concept in 1989, to date, no review of these gliders have been done. This paper reviews existing underwater gliders, with emphasis on their respective working principles, range and payload capacity. All information on gliders available in the public domain or published in literature from the year 2000-2013 was reviewed. The majority of these gliders have an operational depth of 1000 m and a payload of less than 25 kg. The exception is a blend-body shape glider, which has a payload of approximately 800 kg and an operational depth around about 300 m. However, the commercialization of these gliders has been limited with only three know examples that have been successfully commercialized.

  18. Contact allergy to epoxy hardeners.

    Science.gov (United States)

    Aalto-Korte, Kristiina; Suuronen, Katri; Kuuliala, Outi; Henriks-Eckerman, Maj-Len; Jolanki, Riitta

    2014-09-01

    Diglycidylether of bisphenol A resin is the most important sensitizer in epoxy systems, but a minority of patients develop concomitant or solitary contact allergy to epoxy hardeners. At the Finnish Institute of Occupational Health, several in-house test substances of epoxy hardeners have been tested in a special epoxy compound patch test series. To analyse the frequency and clinical relevance of allergic reactions to different epoxy hardeners. Test files (January 1991 to March 2013) were screened for contact allergy to different epoxy hardeners, and the clinical records of patients with allergic reactions were analysed for occupation, concomitant allergic reactions, and exposure. The most commonly positive epoxy hardeners were m-xylylenediamine (n = 24), 2,4,6-tris-(dimethylaminomethyl)phenol (tris-DMP; n = 14), isophorone-diamine (n = 12), and diethylenetriamine (n = 9). Trimethylhexamethylenediamine (n = 7), tetraethylenepentamine (n = 4), and triethylenetetramine (n = 2) elicited some reactions, although most patients were found to have no specific exposure. Allergic reactions to hexamethylenetetramine, dimethylaminopropylamine and ethylenediamine dihydrochloride were not related to epoxy products. Tris-DMP is an important sensitizer in epoxy hardeners, and should be included in the patch test series of epoxy chemicals. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  19. Process for epoxy foam production

    Science.gov (United States)

    Celina, Mathias C [Albuquerque, NM

    2011-08-23

    An epoxy resin mixture with at least one epoxy resin of between approximately 60 wt % and 90 wt %, a maleic anhydride of between approximately 1 wt % and approximately 30 wt %, and an imidazole catalyst of less than approximately 2 wt % where the resin mixture is formed from at least one epoxy resin with a 1-30 wt % maleic anhydride compound and an imidazole catalyst at a temperature sufficient to keep the maleic anhydride compound molten, the resin mixture reacting to form a foaming resin which can then be cured at a temperature greater than 50.degree. C. to form an epoxy foam.

  20. Underwater Hearing in Turtles.

    Science.gov (United States)

    Willis, Katie L

    2016-01-01

    The hearing of turtles is poorly understood compared with the other reptiles. Although the mechanism of transduction of sound into a neural signal via hair cells has been described in detail, the rest of the auditory system is largely a black box. What is known is that turtles have higher hearing thresholds than other reptiles, with best frequencies around 500 Hz. They also have lower underwater hearing thresholds than those in air, owing to resonance of the middle ear cavity. Further studies demonstrated that all families of turtles and tortoises share a common middle ear cavity morphology, with scaling best suited to underwater hearing. This supports an aquatic origin of the group. Because turtles hear best under water, it is important to examine their vulnerability to anthropogenic noise. However, the lack of basic data makes such experiments difficult because only a few species of turtles have published audiograms. There are also almost no behavioral data available (understandable due to training difficulties). Finally, few studies show what kinds of sounds are behaviorally relevant. One notable paper revealed that the Australian snake-necked turtle (Chelodina oblonga) has a vocal repertoire in air, at the interface, and under water. Findings like these suggest that there is more to the turtle aquatic auditory scene than previously thought.

  1. Occupational exposure to epoxy resins

    NARCIS (Netherlands)

    Terwoert, J.; Kersting, K.

    2014-01-01

    Products based on epoxy resins as a binder have become popular in various settings, among which the construction industry and in windmill blade production, as a result of their excellent technical properties. However, due to the same properties epoxy products are a notorious cause of allergic skin d

  2. Occupational exposure to epoxy resins

    NARCIS (Netherlands)

    Terwoert, J.; Kersting, K.

    2014-01-01

    Products based on epoxy resins as a binder have become popular in various settings, among which the construction industry and in windmill blade production, as a result of their excellent technical properties. However, due to the same properties epoxy products are a notorious cause of allergic skin

  3. EPOXY RESIN TOUGHENED BY THERMOPLASTICS

    Institute of Scientific and Technical Information of China (English)

    FU Zengli; SUN Yishi

    1989-01-01

    Two kinds of tough ductile heatresisting thermoplastic, namely bisphenol A polysulfone (PSF) and polyethersulfone (PES) were used to toughen thermoset epoxy resin. A systematic study on the relationship between the molecular weight and the terminal group of the thermoplastic modifier and the fracture toughness of the modified resin was carried out. The morphology of PSF modified epoxy resin was surveyed. With the same kind of PSF the structure of the epoxy resin and the toughening effect of PSF was also investigated. The fractography of PSF, particle modified epoxy was examined in detail with SEM. The contribution of every possible energy absorption process has been discussed. Crack pinning mechanism seems to be the most important toughening mechanism for tough ductile thermoplastic PSF particle modified epoxy system.

  4. Curing Behavior of Epoxy Asphalt

    Institute of Scientific and Technical Information of China (English)

    YU Jianying; CONG Peiliang; WU Shaopeng; CHENG Songbo

    2009-01-01

    The curing process of epoxy asphalt was analyzed by Fourier transform infrared (FT-IR)spectroscopy.Effect of curing temperature on viscosity of epoxy asphalt,and changes of mechanical properties with curing time were investigated.The evolution of concentration of epoxy band was followed as a function of the applied curing process.The experimental results indicate that the curing reaction rate of epoxy asphalt is invariable before 70 min at 120℃,and it decreases when curing time exceeds 70 min.The viscosity of epoxy asphalt increases slowly with curing time at initial curing stage.But it increases quickly after initial curing stage and the initial curing time decreases as the curing temperature increases.The tensile strength increases slowly at incipient curing stage and increases rapidly when curing time is form 20 min to 70 min.The elongation at break shows a decrease with curing time,but it exceeds 200%after cured.

  5. Interaction of water with epoxy.

    Energy Technology Data Exchange (ETDEWEB)

    Powers, Dana Auburn

    2009-07-01

    The chemistries of reactants, plasticizers, solvents and additives in an epoxy paint are discussed. Polyamide additives may play an important role in the absorption of molecular iodine by epoxy paints. It is recommended that the unsaturation of the polyamide additive in the epoxy cure be determined. Experimental studies of water absorption by epoxy resins are discussed. These studies show that absorption can disrupt hydrogen bonds among segments of the polymers and cause swelling of the polymer. The water absorption increases the diffusion coefficient of water within the polymer. Permanent damage to the polymer can result if water causes hydrolysis of ether linkages. Water desorption studies are recommended to ascertain how water absorption affects epoxy paint.

  6. OFDM for underwater acoustic communications

    CERN Document Server

    Zhou, Shengli

    2014-01-01

    A blend of introductory material and advanced signal processing and communication techniques, of critical importance to underwater system and network development This book, which is the first to describe the processing techniques central to underwater OFDM, is arranged into four distinct sections: First, it describes the characteristics of underwater acoustic channels, and stresses the difference from wireless radio channels. Then it goes over the basics of OFDM and channel coding. The second part starts with an overview of the OFDM receiver, and develops various modules for the receiver des

  7. Underwater boom box

    Science.gov (United States)

    White, M. Catherine

    So far, there is no evidence that humpback whales are negatively affected by noise emitted from underwater speakers that may one day be used to measure warming in the oceans. A group of independent biologists from Cornell University monitored the behavior of the whales before, during, and after a scaled-down version of the controversial Acoustic Thermometry of Ocean Climate (ATOC) experiment off the coast of Hawaii. In 84 trials from February through March, they “saw no overt response from the whales.” Previous observations of similar sound transmissions at California's Pioneer Seamount, the other site planned for the experiment, also found no sign of disturbance among marine mammals, including elephant seals and several whale species. More observations are needed, however, before the experiment can be deemed safe, the Cornell biologists advised.

  8. Underwater optical wireless communication network

    Science.gov (United States)

    Arnon, Shlomi

    2010-01-01

    The growing need for underwater observation and subsea monitoring systems has stimulated considerable interest in advancing the enabling technologies of underwater wireless communication and underwater sensor networks. This communication technology is expected to play an important role in investigating climate change, in monitoring biological, biogeochemical, evolutionary, and ecological changes in the sea, ocean, and lake environments, and in helping to control and maintain oil production facilities and harbors using unmanned underwater vehicles (UUVs), submarines, ships, buoys, and divers. However, the present technology of underwater acoustic communication cannot provide the high data rate required to investigate and monitor these environments and facilities. Optical wireless communication has been proposed as the best alternative to meet this challenge. Models are presented for three kinds of optical wireless communication links: (a) a line-of-sight link, (b) a modulating retroreflector link, and (c) a reflective link, all of which can provide the required data rate. We analyze the link performance based on these models. From the analysis, it is clear that as the water absorption increases, the communication performance decreases dramatically for the three link types. However, by using the scattered light it was possible to mitigate this decrease in some cases. It is concluded from the analysis that a high-data-rate underwater optical wireless network is a feasible solution for emerging applications such as UUV-to-UUV links and networks of sensors, and extended ranges in these applications could be achieved by applying a multi-hop concept.

  9. Contact allergy to epoxy resin

    DEFF Research Database (Denmark)

    Bangsgaard, Nannie; Thyssen, Jacob Pontoppidan; Menné, Torkil

    2012-01-01

    . Objectives. To evaluate the prevalence of contact allergy to epoxy resin monomer (diglycidyl ether of bisphenol A; MW 340) among patients with suspected contact dermatitis and relate this to occupation and work-related consequences. Patients/methods. The dataset comprised 20 808 consecutive dermatitis...... in an educational programme. Conclusion. The 1% prevalence of epoxy resin contact allergy is equivalent to reports from other countries. The high occurrence of epoxy resin exposure at work, and the limited use of protective measures, indicate that reinforcement of the law is required....

  10. Epoxy hydantoins as matrix resins

    Science.gov (United States)

    Weiss, J.

    1983-01-01

    Tensile strength and fracture toughness of castings of the hydantoin resins cured with methylenedianiline are significantly higher than MY 720 control castings. Water absorption of an ethyl, amyl hydantoin formulation is 2.1 percent at equilibrium and Tg's are about 160 C, approximately 15 deg below the final cure temperature. Two series of urethane and ester-extended hydantoin epoxy resins were synthesized to determine the effect of crosslink density and functional groups on properties. Castings cured with methylenedianiline or with hexahydrophthalic anhydride were made from these compounds and evaluated. The glass transition temperatures, tensile strengths and moduli, and fracture toughness values were all much lower than that of the simple hydantoin epoxy resins. Using a methylene bishydantoin epoxy with a more rigid structure gave brittle, low-energy fractures, while a more flexible, ethoxy-extended hydantoin epoxy resin gave a very low Tg.

  11. Covert underwater acoustic communications.

    Science.gov (United States)

    Ling, Jun; He, Hao; Li, Jian; Roberts, William; Stoica, Petre

    2010-11-01

    Low probability of detection (LPD) communications are conducted at a low received signal-to-noise ratio (SNR) to deter eavesdroppers to sense the presence of the transmitted signal. Successful detection at intended receiver heavily relies on the processing gain achieved by employing the direct-sequence spread-spectrum (DSSS) technique. For scenarios that lack a sufficiently low SNR to maintain LPD, another metric, referred to as low probability of interception (LPI), is of interest to protect the privacy of the transmitted information. If covert communications take place in underwater acoustic (UWA) environments, then additional challenges are present. The time-varying nature of the UWA channel prevents the employment of a long spreading waveform. Furthermore, UWA environments are frequency-selective channels with long memory, which imposes challenges to the design of the spreading waveform. In this paper, a covert UWA communication system that adopts the DSSS technique and a coherent RAKE receiver is investigated. Emphasis is placed on the design of a spreading waveform that not only accounts for the transceiver structure and frequency-selective nature of the UWA channel, but also possesses a superior LPI. The proposed techniques are evaluated using both simulated and SPACE'08 in-water experimental data.

  12. Underwater Sensor Nodes and Networks

    Directory of Open Access Journals (Sweden)

    Jaime Lloret

    2013-09-01

    Full Text Available Sensor technology has matured enough to be used in any type of environment. The appearance of new physical sensors has increased the range of environmental parameters for gathering data. Because of the huge amount of unexploited resources in the ocean environment, there is a need of new research in the field of sensors and sensor networks. This special issue is focused on collecting recent advances on underwater sensors and underwater sensor networks in order to measure, monitor, surveillance of and control of underwater environments. On the one hand, from the sensor node perspective, we will see works related with the deployment of physical sensors, development of sensor nodes and transceivers for sensor nodes, sensor measurement analysis and several issues such as layer 1 and 2 protocols for underwater communication and sensor localization and positioning systems. On the other hand, from the sensor network perspective, we will see several architectures and protocols for underwater environments and analysis concerning sensor network measurements. Both sides will provide us a complete view of last scientific advances in this research field.

  13. Energy source possibilities in underwater technics

    Science.gov (United States)

    Farin, Juho

    1991-04-01

    Underwater energy source possibilities are treated. The power demand of underwater vehicles is restricted to approximately 0.5 MW. Besides well known primary and secondary batteries as well as conventional diesel engines and closed cycle diesels, fuel cells, radio nuclear isotopes and small nuclear reactors have already been installed or tested in conditions representative of underwater.

  14. Synthesis of polyoxometalate-loaded epoxy composites

    Science.gov (United States)

    Anderson, Benjamin J

    2014-10-07

    The synthesis of a polyoxometalate-loaded epoxy uses a one-step cure by applying an external stimulus to release the acid from the polyoxometalate and thereby catalyze the cure reaction of the epoxy resin. Such polyoxometalate-loaded epoxy composites afford the cured epoxy unique properties imparted by the intrinsic properties of the polyoxometalate. For example, polyoxometalate-loaded epoxy composites can be used as corrosion resistant epoxy coatings, for encapsulation of electronics with improved dielectric properties, and for structural applications with improved mechanical properties.

  15. Design of Autonomous Underwater Vehicle

    Directory of Open Access Journals (Sweden)

    Tadahiro Hyakudome

    2011-03-01

    Full Text Available There are concerns about the impact that global warming will have on our environment, and which will inevitably result in expanding deserts and rising water levels. While a lot of underwater vehicles are utilized, AUVs (Autonomous Underwater Vehicle were considered and chosen, as the most suitable tool for conduction survey concerning these global environmental problems. AUVs can comprehensive survey because the vehicle does not have to be connected to the support vessel by tether cable. When such underwater vehicles are made, it is necessary to consider about the following things. 1 Seawater and Water Pressure Environment, 2 Sink, 3 There are no Gas or Battery Charge Stations, 4 Global Positioning System cannot use, 5 Radio waves cannot use. In the paper, outline of above and how deal about it are explained.

  16. Paramagnetic epoxy resin

    Directory of Open Access Journals (Sweden)

    E. C. Vazquez Barreiro

    2017-01-01

    Full Text Available This work illustrates that macrocycles can be used as crosslinking agents for curing epoxy resins, provided that they have appropriate organic functionalities. As macrocycles can complex metal ions in their structure, this curing reaction allows for the introduction of that metal ion into the resin network. As a result, some characteristic physical properties of the metallomacrocycle could be transferred to the new material. The bisphenol A diglycidyl ether (BADGE, n = 0 and hemin (a protoporphyrin IX containing the Fe(III ion, and an additional chloride ligand have been chosen. The new material has been characterized by differential scanning calorimetry (DSC, thermogravimetric analysis (TGA, Fourier Transform Infrared (FT-IR, Nuclear Magnetic Resonance (NMR, Transmission Electron Microscopy (TEM, and magnetic susceptibility measurements. Fe(III remains in the high-spin state during the curing process and, consequently, the final material exhibits the magnetic characteristics of hemin. The loss of the chlorine atom ligand during the cure of the resin allows that Fe(III can act as Lewis acid, catalyzing the crosslinking reactions. At high BADGE n = 0/hemin ratios, the formation of ether and ester bonds occurs simultaneously during the process.

  17. Underwater laser imaging system (UWLIS)

    Energy Technology Data Exchange (ETDEWEB)

    DeLong, M. [Lawrence Livermore National Lab., CA (United States)

    1994-11-15

    Practical limitations with underwater imaging systems area reached when the noise in the back scattered radiation generated in the water between the imaging system and the target obscures the spatial contrast and resolution necessary for target discovery and identification. The advent of high power lasers operating in the blue-green portion of the visible spectrum (oceanic transmission window) has led to improved experimental illumination systems for underwater imaging. Range-gated and synchronously scanned devices take advantage of the unique temporal and spatial coherence properties of laser radiation, respectively, to overcome the deleterious effects of common volume back scatter.

  18. Underwater noise due to precipitation

    DEFF Research Database (Denmark)

    Crum, Lawrence A.; Pumphrey, Hugh C.; Prosperetti, Andrea;

    1989-01-01

    surface, both for individual and for multiple events such as those produced by artificial and natural rainfall, has been examined. The studies indicate that the major contribution to the underwater noise produced by both rain and snow is that associated with the oscillations of gas bubbles introduced...

  19. Underwater Applications of Acoustical Holography

    Directory of Open Access Journals (Sweden)

    P. C. Mehta

    1984-01-01

    Full Text Available The paper describes the basic technique of acoustical holography. Requirements for recording the acoustical hologram are discussed with its ability for underwater imaging in view. Some practical systems for short-range and medium-range imaging are described. The advantages of acoustical holography over optical imaging, acoustical imaging and sonars are outlined.

  20. Calibration of Underwater Sound Transducers

    Directory of Open Access Journals (Sweden)

    H.R.S. Sastry

    1983-07-01

    Full Text Available The techniques of calibration of underwater sound transducers for farfield, near-field and closed environment conditions are reviewed in this paper .The design of acoustic calibration tank is mentioned. The facilities available at Naval Physical & Oceanographic Laboratory, Cochin for calibration of transducers are also listed.

  1. Underwater Robots Surface in Utah

    Science.gov (United States)

    Hurd, Randy C.; Hacking, Kip S.; Damarjian, Jennifer L.; Wright, Geoffrey A.; Truscott, Tadd

    2015-01-01

    Underwater robots (or ROVs: Remotely Operated Vehicles as they are typically called in industry) have recently become a very popular instructional STEM activity. Nationally, ROVs have been used in science and technology classrooms for several years in cities such as Seattle, San Diego, Virginia Beach, and other coastal areas. In the past two…

  2. Damping Properties of Flexible Epoxy Resin

    Institute of Scientific and Technical Information of China (English)

    WANG Xiang; LIU Hanxing; OUYANG Shixi

    2008-01-01

    Amino-terminated polyethers and amino-terminated polyurethane were used as curing agent to cure the epoxy resin together and get a series of cured products. The damping properties of the composites were studied by DMA test at different measurement frequencies. Damping mechanical tests show that the flexible epoxy resin has higher loss factor than common epoxy. The highest loss factor reaches 1.57. Also the height and position of loss factor peak of the flexible epoxy resin varies by changing the content of amino-terminated polyethers. Results shows that the flexible epoxy resin can be used as damping polymer materials at room temperature or in common frequency range.

  3. [Epoxy resin systems and contact dermatitis].

    Science.gov (United States)

    Pietranek, Jolanta Eliza

    2007-01-01

    Contact dermatitis is the major chronic skin disease that represents a global health problem. Its prevalence has been significant increasing in the latest decades. Contact dermatitis substantially alters the social life of patients and affects their work productivity. Epoxy resin systems are a frequent cause of occupational allergic contact dermatitis. Epoxy resins have an extremely wide range of commercial applications. Epoxy resin systems include combinations of epoxy monomers, hardeners, reactive diluents, and/or a vast array of other additives. In occupational settings, sensitization occurs not only to resins, but also to hardeners and reactive diluents. In this article adverse effects of epoxy resin systems are discussed.

  4. Tailoring of epoxy material properties

    NARCIS (Netherlands)

    Nakka, J.S.

    2010-01-01

    This research work is aimed to understand the effect of resin chemistry on the physical properties (e.g. moduli, viscoelasticity, moisture uptake, coefficient of thermal expansion) of cured aromatic epoxy-amine thermoset resins. This understanding will result into a good first approximation of the f

  5. Research on biomimetic underwater vehicles for underwater ISR

    Science.gov (United States)

    Szymak, Piotr; Praczyk, Tomasz; Naus, Krzysztof; Szturomski, Bogdan; Malec, Marcin; Morawski, Marcin

    2016-05-01

    Autonomous Biomimetic Underwater Vehicles BUVs driven by an undulating propulsion are a new branch in an area of an underwater robotics. They imitate both the construction and kinematics of a motion of underwater living organisms, e.g. fishes. Such vehicles have several features crucial from the point of view of military applications, e.g. larger secrecy and potential range of operation. The paper presents results of the research on BUVs carried out within two (Polish and EDA) projects both led by Polish Naval Academy. At the beginning, the initial efforts in building Polish BUV called CyberFish are included. Then, selected results of the tests of subsystems, e.g. navigational and 3D model of BUV built within national project are described. Next, the initial research achieved in the international project are showed. At the end, the schedule of the research planned to carry out within both projects is inserted. The paper is mainly focused on the hardware development of the BUVs.

  6. Lap shear strength and healing capability of self-healing adhesive containing epoxy/mercaptan microcapsules

    Energy Technology Data Exchange (ETDEWEB)

    Ghazali, Habibah; Ye, Lin [Centre for Advanced Materials Technology (CAMT), School of Aerospace, Mechanical and Mechatronic Engineering, The University of Sydney, NSW 2006 (Australia); Zhang, Ming-Qiu [Key Laboratory of Polymeric Composite and Functional Materials of Ministry of Education, Zhongshan University, Guangzhou 510275 (China)

    2016-03-09

    The aim of this work is to develop a self-healing polymeric adhesive formulation with epoxy/mercaptan microcapsules. Epoxy/mercaptan microcapsules were dispersed into a commercialize two-part epoxy adhesive for developing self-healing epoxy adhesive. The influence of different content of microcapsules on the shear strength and healing capability of epoxy adhesive were investigated using single-lap-joints with average thickness of adhesive layer of about 180 µm. This self-healing adhesive was used in bonding of 5000 series aluminum alloys adherents after mechanical and alkaline cleaning surface treatment. The adhesion strength was measured and presented as function of microcapsules loading. The results indicated that the virgin lap shear strength was increased by about 26% with addition of 3 wt% of self-healing microcapsules. 12% to 28% recovery of the shear strength is achieved after self-healing depending on the microcapsules content. Scanning electron microscopy was used to study fracture surface of the joints. The self-healing adhesives exhibit recovery of both cohesion and adhesion properties with room temperature healing.

  7. Lap shear strength and healing capability of self-healing adhesive containing epoxy/mercaptan microcapsules

    Science.gov (United States)

    Ghazali, Habibah; Ye, Lin; Zhang, Ming-Qiu

    2016-03-01

    The aim of this work is to develop a self-healing polymeric adhesive formulation with epoxy/mercaptan microcapsules. Epoxy/mercaptan microcapsules were dispersed into a commercialize two-part epoxy adhesive for developing self-healing epoxy adhesive. The influence of different content of microcapsules on the shear strength and healing capability of epoxy adhesive were investigated using single-lap-joints with average thickness of adhesive layer of about 180 µm. This self-healing adhesive was used in bonding of 5000 series aluminum alloys adherents after mechanical and alkaline cleaning surface treatment. The adhesion strength was measured and presented as function of microcapsules loading. The results indicated that the virgin lap shear strength was increased by about 26% with addition of 3 wt% of self-healing microcapsules. 12% to 28% recovery of the shear strength is achieved after self-healing depending on the microcapsules content. Scanning electron microscopy was used to study fracture surface of the joints. The self-healing adhesives exhibit recovery of both cohesion and adhesion properties with room temperature healing.

  8. Sensor Network Architectures for Monitoring Underwater Pipelines

    OpenAIRE

    Imad Jawhar; Jameela Al-Jaroodi; Nader Mohamed; Liren Zhang

    2011-01-01

    This paper develops and compares different sensor network architecture designs that can be used for monitoring underwater pipeline infrastructures. These architectures are underwater wired sensor networks, underwater acoustic wireless sensor networks, RF (Radio Frequency) wireless sensor networks, integrated wired/acoustic wireless sensor networks, and integrated wired/RF wireless sensor networks. The paper also discusses the reliability challenges and enhancement approaches for these network...

  9. International Conference on Underwater Environment

    CERN Document Server

    Jaulin, Luc; Creuze, Vincent; Debese, Nathalie; Quidu, Isabelle; Clement, Benoît; Billon-Coat, Annick

    2016-01-01

    This volume constitutes the results of the International Conference on Underwater Environment, MOQESM’14, held at “Le Quartz” Conference Center in Brest, France, on October 14-15, 2014, within the framework of the 9th Sea Tech Week, International Marine Science and Technology Event. The objective of MOQESM'14 was to bring together researchers from both academia and industry, interested in marine robotics and hydrography with application to the coastal environment mapping and underwater infrastructures surveys. The common thread of the conference is the combination of technical control, perception, and localization, typically used in robotics, with the methods of mapping and bathymetry. The papers presented in this book focus on two main topics. Firstly, coastal and infrastructure mapping is addressed, focusing not only on hydrographic systems, but also on positioning systems, bathymetry, and remote sensing. The proposed methods rely on acoustic sensors such as side scan sonars, multibeam echo sounders, ...

  10. Cooperative OFDM underwater acoustic communications

    CERN Document Server

    Cheng, Xilin; Cheng, Xiang

    2016-01-01

    Following underwater acoustic channel modeling, this book investigates the relationship between coherence time and transmission distances. It considers the power allocation issues of two typical transmission scenarios, namely short-range transmission and medium-long range transmission. For the former scenario, an adaptive system is developed based on instantaneous channel state information. The primary focus is on cooperative dual-hop orthogonal frequency division multiplexing (OFDM). This book includes the decomposed fountain codes designed to enable reliable communications with higher energy efficiency. It covers the Doppler Effect, which improves packet transmission reliability for effective low-complexity mirror-mapping-based intercarrier interference cancellation schemes capable of suppressing the intercarrier interference power level. Designed for professionals and researchers in the field of underwater acoustic communications, this book is also suitable for advanced-level students in electrical enginee...

  11. Taiwan's underwater cultural heritage documentation management

    Science.gov (United States)

    Tung, Y.-Y.

    2015-09-01

    Taiwan is an important trading and maritime channels for many countries since ancient time. Numerous relics lie underwater due to weather, wars, and other factors. In the year of 2006, Bureau of Cultural Heritage (BOCH) entrusted the Underwater Archaeological Team of Academia Sinica to execute the underwater archaeological investigation projects. Currently, we verified 78 underwater targets, with 78 site of those had been recognized as shipwrecks sites. Up to date, there is a collection of 638 underwater objects from different underwater archaeological sites. Those artefacts are distributed to different institutions and museums. As very diverse management methods/systems are applied for every individual institution, underwater cultural heritage data such as survey, excavation report, research, etc. are poorly organized and disseminated for use. For better communication regarding to Taiwan's underwater cultural heritage in every level, a universal format of documentation should be established. By comparing the existing checklist used in Taiwan with guidelines that are followed in other countries, a more intact and appropriate underwater cultural heritage condition documentation system can be established and adapted in Taiwan.

  12. Action-Specific Effects Underwater

    OpenAIRE

    Witt, Jessica; Schuck, Donald M; Taylor, J. Eric T.

    2011-01-01

    Action-specific effects on perception are apparent in terrestrial environments. For example, targets that require more effort to walk, jump, or throw to look farther away than when the targets require less effort. Here, we examined whether action-specific effects would generalize to an underwater environment. Instead, perception might be geometrically precise, rather than action-specific, in an environment that is novel from an evolutionary perspective. We manipulated ease to swim by giving p...

  13. Underwater Acoustic Beacon Location System

    Science.gov (United States)

    2016-12-23

    transpose operator is a standard operator in linear or matrix algebra . The transpose operator converts the row vector   T aaaa z,y,x=P to a column...February 2017 The below identified patent application is available for licensing. Requests for information should be addressed to...300087 1 of 31 UNDERWATER ACOUSTIC BEACON LOCATION SYSTEM [0001] The present application claims the benefit of United States Provisional

  14. Effect of epoxy resin properties on the mechanical properties of carbon fiber/epoxy resin composites

    Energy Technology Data Exchange (ETDEWEB)

    He, Hong-Wei; Gao, Feng [Taiyuan Univ. of Technology (China). College of Materials Science and Engineering; Taiyuan Univ. of Technology (China). Key Laboratory of Interface Science and Engineering in Advanced Materials; Li, Kai-Xi [Chinese Academy of Sciences, Taiyuan, Shanxi (China). Key Laboratory of Carbon Materials

    2013-09-15

    Three kinds of epoxy resins, i.e. tetraglycidyl diaminodiphenyl methane (AG80), difunctional diglycidyl ether of bisphenol-A (E51) and novolac type epoxy resin (F46) were selected as matrices for carbon fiber/epoxy composites. The objective of this work is to study the mechanical properties of fiber/epoxy composites by using these three kinds of epoxy resins with different physical and chemical performance. The results show that the composites fabricated with AG80 present the best stiffness and the composites prepared with E5 1have the best toughness. The stiffness and toughness of the composites prepared with F46 are middle values located between those for AG80/epoxy and E51/epoxy composites. Thus, the mixed epoxy resin is a promising approach for industrial production. (orig.)

  15. Flammability of Epoxy Resins Containing Phosphorus

    Science.gov (United States)

    Hergenrother, P. M.; Thompson, C. M.; Smith, J. G.; Connell, J. W.; Hinkley, J. A.

    2005-01-01

    As part of a program to develop fire-resistant exterior composite structures for future subsonic commercial and general aviation aircraft, flame-retardant epoxy resins are under investigation. Epoxies and their curing agents (aromatic diamines) containing phosphorus were synthesized and used to prepare epoxy formulations. Phosphorus was incorporated within the backbone of the epoxy resin and not used as an additive. The resulting cured neat epoxy formulations were characterized by thermogravimetric analysis, propane torch test, elemental analysis, microscale combustion calorimetry, and fire calorimetry. Several formulations showed excellent flame retardation with phosphorous contents as low as 1.5% by weight. The fracture toughness and compressive strength of several cured formulations showed no detrimental effect due to phosphorus content. The chemistry and properties of these new epoxy formulations are discussed.

  16. Epoxy resins in the construction industry.

    Science.gov (United States)

    Spee, Ton; Van Duivenbooden, Cor; Terwoert, Jeroen

    2006-09-01

    Epoxy resins are used as coatings, adhesives, and in wood and concrete repair. However, epoxy resins can be highly irritating to the skin and are strong sensitizers. Some hardeners are carcinogenic. Based on the results of earlier Dutch studies, an international project on "best practices,"--Epoxy Code--with epoxy products was started. Partners were from Denmark, Germany, the Netherlands, and the UK. The "Code" deals with substitution, safe working procedures, safer tools, and skin protection. The feasibility of an internationally agreed "ranking system" for the health risks of epoxy products was studied. Such a ranking system should inform the user of the harmfulness of different epoxies and stimulate research on less harmful products by product developers.

  17. Shelf Stable Epoxy Repair Adhesive

    Science.gov (United States)

    2015-02-01

    manufacturing operations are more efficient , discarding less expired film. Commercial and military aircraft repair operations at Boeing experience very similar...successfully encapsulated at concentrations greater than 50 wt% within four N N = CC Infoscitex Corporation Shelf Stable Epoxy Resin Adhesive WP-1763 8...affects the composition of the encapsulant , which in turn affects the ability of the encapsulant to wet the core phase, the barrier properties of the

  18. Graphite/Epoxy Deicing Heater

    Science.gov (United States)

    Hung, Ching-Cheh; Dillehay, Michael E.; Stahl, Mark

    1988-01-01

    Heat applied close to surface protected. One ply of highly electrically- and thermally-conductive brominated-graphite fiber composite laminated between two plies of electrically-insulating composite material, with michel foil making contact with end portions of graphite fibers. Part of foil exposed beyond composite to serve as electrical contact. Graphite/Epoxy composite heater developed to prevent and reverse formation of ice on advanced composite surfaces of aircraft.

  19. Mechanical Properties of Heavy Duty Epoxy Coatings

    OpenAIRE

    Reinoso Rodríguez, Rosa

    2013-01-01

    In a first stage, the composition of epoxy coatings is discussed with special focus on the mechanism of curing and the chemistry of curing agents and their advantages and downturns in prospect to their use in the manufacture of epoxy resins. Then literature on the causes of increased brittleness, cracking and degradation of epoxy resins was studied, especially in relation to evolution of the resins in the glassy state, hydrothermal aging and also in relation to chemical aging. ...

  20. Functionalization of nanodiamond with epoxy monomer

    Institute of Scientific and Technical Information of China (English)

    Huan Huan Zhang; Ya Ting Liu; Rong Wang; Xiao Yan Yu; Xiong Wei Qu; Qing Xin Zhang

    2011-01-01

    A novel nanodiamond-epoxy derivative (ND-EP) was synthesized by grafting epoxy monomers onto the surface of nanodiamond (ND), and characterized by FTIR and TGA. The ratio of grafted epoxy groups was determined to be 32.5 wt% by TGA. The developed methodology provides an efficient method for the functionalization of nanodiamond material, which enables a variety of advanced engineering and biomedical applications of ND.

  1. Epoxy Resins Modified with Vegetable Oils

    Institute of Scientific and Technical Information of China (English)

    P.Czub

    2007-01-01

    1 Results The application of modified natural oils, nontoxic, biodegradable and renewable materials, for the modification and the synthesis of epoxy resins were presented. Firstly, the application of epoxidized vegetable oils (soybean, rapeseed, linseed and sunflower):as reactive diluents for epoxy resins was proposed and studied[1-2]. Viscosity reducing ability of epoxidized oils was tested in the compositions with Bisphenol A based low-molecular-weight epoxy resins. The rheological behaviour of the mi...

  2. Acoustic signal analysis of underwater elastic cylinder

    Institute of Scientific and Technical Information of China (English)

    LI Xiukun; YANG Shi'e

    2001-01-01

    The echoes of underwater elastic cylinder comprise two types of acoustic components: Geometrical scattering waves and elastic scattering waves. The transfer function is appropriate to characterize the echo of targets. And the discrete wavelet transform of amplitude spectrum is presented and used to identify the resonant components of underwater targets.PACS numbers: 43.30, 43.60

  3. Seeking Teachers for Underwater Robotics PD Program

    Science.gov (United States)

    McGrath, Beth; Sayres, Jason

    2012-01-01

    With funding from the National Science Foundation (NSF), ITEEA members will contribute to the development of a hybrid professional development program designed to facilitate the scale-up of an innovative underwater robotics curriculum. WaterBotics[TM] is an underwater robotics curriculum that targets students in middle and high school classrooms…

  4. Coefficient of variation of underwater irradiance fluctuations

    Science.gov (United States)

    Weber, V. L.

    2010-06-01

    We consider underwater sunlight fluctuations in the case of a one-dimensional irregular sea surface. Several rigorous and approximate models are proposed, which make it possible to analytically treat and physically explain the dependence of the coefficient of variation of the underwater irradiance on the depth, the wind velocity, and optical parameters of the sea water.

  5. 29 CFR 1926.912 - Underwater blasting.

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 8 2010-07-01 2010-07-01 false Underwater blasting. 1926.912 Section 1926.912 Labor... (CONTINUED) SAFETY AND HEALTH REGULATIONS FOR CONSTRUCTION Blasting and the Use of Explosives § 1926.912 Underwater blasting. (a) A blaster shall conduct all blasting operations, and no shot shall be fired...

  6. Evaluation of Underwater Adhesives and Friction Coatings for In Situ Attachment of Fiber Optic Sensor System for Subsea Applications

    Science.gov (United States)

    Tang, Henry H.; Le, Suy Q.; Orndoff, Evelyne S.; Smith, Frederick D.; Tapia, Alma S.; Brower, David V.

    2012-01-01

    Integrity and performance monitoring of subsea pipelines and structures provides critical information for managing offshore oil and gas production operation and preventing environmentally damaging and costly catastrophic failure. Currently pipeline monitoring devices require ground assembly and installation prior to the underwater deployment of the pipeline. A monitoring device that could be installed in situ on the operating underwater structures could enhance the productivity and improve the safety of current offshore operation. Through a Space Act Agreement (SAA) between the National Aeronautics and Space Administration (NASA) Johnson Space Center (JSC) and Astro Technology, Inc. (ATI), JSC provides technical expertise and testing facilities to support the development of fiber optic sensor technologies by ATI. This paper details the first collaboration effort between NASA JSC and ATI in evaluating underwater applicable adhesives and friction coatings for attaching fiber optic sensor system to subsea pipeline. A market survey was conducted to examine different commercial ]off ]the ]shelf (COTS) underwater adhesive systems and to select adhesive candidates for testing and evaluation. Four COTS epoxy based underwater adhesives were selected and evaluated. The adhesives were applied and cured in simulated seawater conditions and then evaluated for application characteristics and adhesive strength. The adhesive that demonstrated the best underwater application characteristics and highest adhesive strength were identified for further evaluation in developing an attachment system that could be deployed in the harsh subsea environment. Various friction coatings were also tested in this study to measure their shear strengths for a mechanical clamping design concept for attaching fiber optic sensor system. A COTS carbide alloy coating was found to increase the shear strength of metal to metal clamping interface by up to 46 percent. This study provides valuable data for

  7. Thermally activated, single component epoxy systems

    KAUST Repository

    Unruh, David A.

    2011-08-23

    A single component epoxy system in which the resin and hardener components found in many two-component epoxies are combined onto the same molecule is described. The single molecule precursor to the epoxy resin contains both multiple epoxide moieties and a diamine held latent by thermally degradable carbamate linkages. These bis-carbamate "single molecule epoxies" have an essentially infinite shelf life and access a significant range in curing temperatures related to the structure of the carbamate linkages used. © 2011 American Chemical Society.

  8. ROV Based Underwater Blurred Image Restoration

    Institute of Scientific and Technical Information of China (English)

    LIU Zhishen; DING Tianfu; WANG Gang

    2003-01-01

    In this paper, we present a method of ROV based image processing to restore underwater blurry images from the theory of light and image transmission in the sea. Computer is used to simulate the maximum detection range of the ROV under different water body conditions. The receiving irradiance of the video camera at different detection ranges is also calculated. The ROV's detection performance under different water body conditions is given by simulation. We restore the underwater blurry images using the Wiener filter based on the simulation. The Wiener filter is shown to be a simple useful method for underwater image restoration in the ROV underwater experiments. We also present examples of restored images of an underwater standard target taken by the video camera in these experiments.

  9. Quantum imaging for underwater arctic navigation

    Science.gov (United States)

    Lanzagorta, Marco

    2017-05-01

    The precise navigation of underwater vehicles is a difficult task due to the challenges imposed by the variable oceanic environment. It is particularly difficult if the underwater vehicle is trying to navigate under the Arctic ice shelf. Indeed, in this scenario traditional navigation devices such as GPS, compasses and gyrocompasses are unavailable or unreliable. In addition, the shape and thickness of the ice shelf is variable throughout the year. Current Arctic underwater navigation systems include sonar arrays to detect the proximity to the ice. However, these systems are undesirable in a wartime environment, as the sound gives away the position of the underwater vehicle. In this paper we briefly describe the theoretical design of a quantum imaging system that could allow the safe and stealthy navigation of underwater Arctic vehicles.

  10. Synthesis, characterization and cure kinetics of polyaniline modified MMT clay/epoxy nanocomposites

    Science.gov (United States)

    Aykanat, Aydin

    This research work focuses on the synthesis characterization and processing of conducting polymer coated both carbon fiber and montmorillonite clay based nanoparticles to improve the mechanical, thermal, and adhesive properties of epoxy based micro and nano composites. The entire research work mainly consists of two parts. In the first part, homogeneous and uniform coatings of polyaniline were successfully deposited onto carbon fibers by aqueous electrodeposition technique using p-toluene sulfonic acid as the electrolyte. Electrochemical deposition of aniline was carried out by cyclic voltammetry in the potential range of -0.2 V to 1.0 V vs. SCE. The electrochemical deposition parameters such as the number of cycles, scan rate (SR), initial monomer ([M]) and electrolyte concentration ([E]) were systematically varied. The amount of composite coatings on carbon fibers was dependant on the electrochemical deposition parameters. From the weight gain analysis, rate of the reactions (Rp) were calculated. As the aniline concentration was increased up to 0.35 M and electrolyte concentration up to 0.5 M, the deposition rate also increased, whereas an increase in scan rate decreased the deposition rate. The kinetic analysis showed that the rate equation for the p-toluene sulfonic acid system is R p ∝ SR-1.25 [M]0.73 [E]0.95 . IR spectra also show an increase in the deposition of polyaniline coatings on carbon fibers with a decrease in the scan rate and an increase in both monomer and electrolyte concentration. The ratio of two oxidation states of polyaniline namely emeraldine and pernigraniline obtained during electrodeposition can be varied by changing the electrochemical deposition parameters. SEM results show that carbon fiber surface was uniformly coated with polyaniline resulting a dense, rough and reactive surface that increases the compatibility and wettability of carbon fibers. The effect of PANi coated carbon fibers on the curing behavior of diglycidyl ether of

  11. Underwater camera with depth measurement

    Science.gov (United States)

    Wang, Wei-Chih; Lin, Keng-Ren; Tsui, Chi L.; Schipf, David; Leang, Jonathan

    2016-04-01

    The objective of this study is to develop an RGB-D (video + depth) camera that provides three-dimensional image data for use in the haptic feedback of a robotic underwater ordnance recovery system. Two camera systems were developed and studied. The first depth camera relies on structured light (as used by the Microsoft Kinect), where the displacement of an object is determined by variations of the geometry of a projected pattern. The other camera system is based on a Time of Flight (ToF) depth camera. The results of the structural light camera system shows that the camera system requires a stronger light source with a similar operating wavelength and bandwidth to achieve a desirable working distance in water. This approach might not be robust enough for our proposed underwater RGB-D camera system, as it will require a complete re-design of the light source component. The ToF camera system instead, allows an arbitrary placement of light source and camera. The intensity output of the broadband LED light source in the ToF camera system can be increased by putting them into an array configuration and the LEDs can be modulated comfortably with any waveform and frequencies required by the ToF camera. In this paper, both camera were evaluated and experiments were conducted to demonstrate the versatility of the ToF camera.

  12. Thermoset epoxy polymers from renewable resources

    Science.gov (United States)

    East, Anthony; Jaffe, Michael; Zhang, Yi; Catalani, Luiz H

    2009-11-17

    Novel thermoset epoxy polymers using the bisglycidyl ethers of anhydrosugars, such as isosorbide, isomannide, and isoidide, are disclosed. The bisglycidyl ethers are useful as substitutes for bisphenol A in the manufacture of thermoset epoxy ethers. The anhydrosugars are derived from renewable sources and the bisglycidyl ethers are not xenoestrogenic and the thermoset curing agents are likewise derived form renewable resources.

  13. [Delayed asthma bronchiale due to epoxy resin].

    Science.gov (United States)

    Authried, Georg; Al-Asadi, Haifaa; Møller, Ulla; Sherson, David Lee

    2013-10-28

    Epoxy resin is a low molecular weight agent, which can cause both acute and delayed allergic reactions. However, it is known causing skin reactions with direct or airborne contact. Rarely it can cause airway reactions like asthma bronchiale. We describe a case of a windmill worker who developed delayed asthma bronchiale due to airborne contact with epoxy resin.

  14. Astmatisk senreaktion efter kontakt med epoxy

    DEFF Research Database (Denmark)

    Authried, Georg; Al-Asadi, Haifaa; Møller, Ulla;

    2013-01-01

    Epoxy resin is a low molecular weight agent, which can cause both acute and delayed allergic reactions. However, it is known causing skin reactions with direct or airborne contact. Rarely it can cause airway reactions like asthma bronchiale. We describe a case of a windmill worker who developed...... delayed asthma bronchiale due to airborne contact with epoxy resin....

  15. Astmatisk senreaktion efter kontakt med epoxy

    DEFF Research Database (Denmark)

    Authried, Georg; Al-Asadi, Haifaa; Møller, Ulla

    2013-01-01

    Epoxy resin is a low molecular weight agent, which can cause both acute and delayed allergic reactions. However, it is known causing skin reactions with direct or airborne contact. Rarely it can cause airway reactions like asthma bronchiale. We describe a case of a windmill worker who developed...... delayed asthma bronchiale due to airborne contact with epoxy resin....

  16. Comparative properties of optically clear epoxy encapsulants

    Science.gov (United States)

    Edwards, Maury; Zhou, Yan

    2001-12-01

    Three epoxy systems were evaluated for physical dn optical properties. The three systems chosen for the study were selected on the basis of their optical clarity, color and chemistry. Three distinctly different chemistries were chosen, aromatic epoxy-amine cured. Aromatic epoxy- anhydride cured and cycloaliphatic epoxy-anhydride cured. All three systems remained optically clear and water-white after full cure. The three selected systems were tested for physical properties, adhesion and light transmission properties. Light transmission was measured after thermal and humidity exposure. Adhesion was measured after humidity exposure only. Both of the epoxy-anhydride systems performed well in optical properties but poorer in adhesion as compared to the epoxy-amine system. The aromatic epoxy- amine system discolored badly during thermal exposure at 100 C. Data generated from this work will be used in selecting clear encapsulating materials for photonics applications. No single system offers optimal performance in all areas. The best compromise material is the aromatic epoxy-anhydride system.

  17. Curing Reaction Model of Epoxy Asphalt Binder

    Institute of Scientific and Technical Information of China (English)

    QIAN Zhendong; CHEN Leilei; WANG Yaqi; SHEN Jialin

    2012-01-01

    In order to understand the strength developing law of the epoxy asphalt mixture,a curing reaction model of the epoxy asphalt binder was proposed based upon the thermokinetic analysis.Given some assumptions,the model was developed by applying the Kissinger law as well as Arrhenius equation,and the differential scanning calorimetry was performed for estimating the model parameters.To monitor the strength development of the epoxy asphalt mixture,a strength test program was employed and then results were compared to those produced from the proposed model.The comparative evaluation shows that a good consistency exists between the outputs from test program and the proposed model,indicating that the proposed model can be used effectively for simulating the curing reaction process for the epoxy asphalt binder and predicting the strength development for the epoxy asphalt mixture.

  18. Waterborne Epoxy Resin Modified by AMPS

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    A stable epoxy emulsion was prepared with epoxy resin (EP) as raw material, 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) as modifier and benzoyl peroxide as initiator. By criterion of yield of the copolymer AMPS-EP, water-solubility, change of the acid value and intrinsic viscosity [η] along with reaction time, the copolymerization course was deduced. It is found that during the process, AMPS takes part in both the grafting copolymerization with epoxy principal chain and the ring-opening polyaddition with epoxy group. It is also discovered that the yield of AMPS-EP and water dispersing varies with reaction time. When it reaches 1.5 h,AMPS-EP can obtain good water-solubility; but the water-solubility will go bad gradually ifit exceeds 3.5 h.( )R spectrum analysis indicates that partial epoxy group partially remains and the others create sulfonic ester.

  19. 4th Pacific Rim Underwater Acoustics Conference

    CERN Document Server

    Xu, Wen; Cheng, Qianliu; Zhao, Hangfang

    2016-01-01

    These proceedings are a collection of 16 selected scientific papers and reviews by distinguished international experts that were presented at the 4th Pacific Rim Underwater Acoustics Conference (PRUAC), held in Hangzhou, China in October 2013. The topics discussed at the conference include internal wave observation and prediction; environmental uncertainty and coupling to sound propagation; environmental noise and ocean dynamics; dynamic modeling in acoustic fields; acoustic tomography and ocean parameter estimation; time reversal and matched field processing; underwater acoustic localization and communication as well as measurement instrumentations and platforms. These proceedings provide insights into the latest developments in underwater acoustics, promoting the exchange of ideas for the benefit of future research.

  20. AURP: An AUV-Aided Underwater Routing Protocol for Underwater Acoustic Sensor Networks

    Directory of Open Access Journals (Sweden)

    Sunghwan Kim

    2012-02-01

    Full Text Available Deploying a multi-hop underwater acoustic sensor network (UASN in a large area brings about new challenges in reliable data transmissions and survivability of network due to the limited underwater communication range/bandwidth and the limited energy of underwater sensor nodes. In order to address those challenges and achieve the objectives of maximization of data delivery ratio and minimization of energy consumption of underwater sensor nodes, this paper proposes a new underwater routing scheme, namely AURP (AUV-aided underwater routing protocol, which uses not only heterogeneous acoustic communication channels but also controlled mobility of multiple autonomous underwater vehicles (AUVs. In AURP, the total data transmissions are minimized by using AUVs as relay nodes, which collect sensed data from gateway nodes and then forward to the sink. Moreover, controlled mobility of AUVs makes it possible to apply a short-range high data rate underwater channel for transmissions of a large amount of data. To the best to our knowledge, this work is the first attempt to employ multiple AUVs as relay nodes in a multi-hop UASN to improve the network performance in terms of data delivery ratio and energy consumption. Simulations, which are incorporated with a realistic underwater acoustic communication channel model, are carried out to evaluate the performance of the proposed scheme, and the results indicate that a high delivery ratio and low energy consumption can be achieved.

  1. AURP: an AUV-aided underwater routing protocol for underwater acoustic sensor networks.

    Science.gov (United States)

    Yoon, Seokhoon; Azad, Abul K; Oh, Hoon; Kim, Sunghwan

    2012-01-01

    Deploying a multi-hop underwater acoustic sensor network (UASN) in a large area brings about new challenges in reliable data transmissions and survivability of network due to the limited underwater communication range/bandwidth and the limited energy of underwater sensor nodes. In order to address those challenges and achieve the objectives of maximization of data delivery ratio and minimization of energy consumption of underwater sensor nodes, this paper proposes a new underwater routing scheme, namely AURP (AUV-aided underwater routing protocol), which uses not only heterogeneous acoustic communication channels but also controlled mobility of multiple autonomous underwater vehicles (AUVs). In AURP, the total data transmissions are minimized by using AUVs as relay nodes, which collect sensed data from gateway nodes and then forward to the sink. Moreover, controlled mobility of AUVs makes it possible to apply a short-range high data rate underwater channel for transmissions of a large amount of data. To the best to our knowledge, this work is the first attempt to employ multiple AUVs as relay nodes in a multi-hop UASN to improve the network performance in terms of data delivery ratio and energy consumption. Simulations, which are incorporated with a realistic underwater acoustic communication channel model, are carried out to evaluate the performance of the proposed scheme, and the results indicate that a high delivery ratio and low energy consumption can be achieved.

  2. Imide modified epoxy matrix resins

    Science.gov (United States)

    Scola, D. A.

    1984-01-01

    The results of a program designed to develop tough imide modified epoxy resins cured by bisimide amine (BIA) hardeners are described. State-of-the-art epoxides MY720 and DER383 were used, and four bismide amines were evaluated. These were the BIA's derived from the 6F anhydride (4,4'-(hexafluoroisopropylidene) bis(phthalic anhydride) and the diamines 3,3'-diaminodiphynyl sulfone, 4,4'-oxygianiline, 4,4'-methylene dianiline, and 1,12-dodecane diamine. A key intermediate, designated 6F anhydride, is required for the synthesis of the bisimide amines. Reaction parameters to synthesize a precursor to the 6F anhydride (6FHC) in high yields were investigated. The catalyst trifluoromethane sulfonic acid was studied. Although small scale runs yielded the 6FHC in 50 percent yield, efforts to ranslate these results to a larger scale synthesis gave the 6FHC in only 9 percent yield. Results show that the concept of using bisimide amine as curing agents to improve the toughness properties of epoxies is valid.

  3. Sample selection versus two-part models revisited: the case of female smoking and drinking.

    Science.gov (United States)

    Madden, David

    2008-03-01

    There is a well-established debate between Heckman sample selection and two-part models in health econometrics, particularly when no obvious exclusion restrictions are available. Most of this debate has focussed on the application of these models to health care expenditure. This paper revisits the debate in the context of female smoking and drinking, and evaluates the two approaches on three grounds: theoretical, practical and statistical. The two-part model is generally favoured but it is stressed that this comparison should be carried out on a case-by-case basis.

  4. A Study on Digital Analysis of Bach’s “Two-Part Inventions”

    Directory of Open Access Journals (Sweden)

    Xiao-Yi Song

    2015-01-01

    Full Text Available In the field of music composition, creating polyphony is relatively one of the most difficult parts. Among them, the basis of multivoice polyphonic composition is two-part counterpoint. The main purpose of this paper is, through the computer technology, conducting a series of studies on “Two-Part Inventions” of Bach, a Baroque polyphony master. Based on digitalization, visualization and mathematical methods, data mining algorithm has been applied to identify bipartite characteristics and rules of counterpoint polyphony. We hope that the conclusions drawn from the article could be applied to the digital creation of polyphony.

  5. Mechanical and Thermoviscoelastic Behavior of Clay/Epoxy Nanocomposites

    Science.gov (United States)

    2003-01-01

    bisphenol A ( DGEBA ) epoxy of subambient glass transition temperature (Tg) with 5% weight of montmorillonite. The authors showed that no big improvements...reinforced polymers for structural applications. The epoxy system considered here is an anhydride-cured epoxy consisting of a DGEBA epoxy resin cross-linked

  6. Evolution: Fossil Ears and Underwater Sonar.

    Science.gov (United States)

    Lambert, Olivier

    2016-08-22

    A key innovation in the history of whales was the evolution of a sonar system together with high-frequency hearing. Fossils of an archaic toothed whale's inner ear bones provide clues for a stepwise emergence of underwater echolocation ability.

  7. Active-imaging-based underwater navigation

    Science.gov (United States)

    Monnin, David; Schmitt, Gwenaël.; Fischer, Colin; Laurenzis, Martin; Christnacher, Frank

    2015-10-01

    Global navigation satellite systems (GNSS) are widely used for the localization and the navigation of unmanned and remotely operated vehicles (ROV). In contrast to ground or aerial vehicles, GNSS cannot be employed for autonomous underwater vehicles (AUV) without the use of a communication link to the water surface, since satellite signals cannot be received underwater. However, underwater autonomous navigation is still possible using self-localization methods which determines the relative location of an AUV with respect to a reference location using inertial measurement units (IMU), depth sensors and even sometimes radar or sonar imaging. As an alternative or a complementary solution to common underwater reckoning techniques, we present the first results of a feasibility study of an active-imaging-based localization method which uses a range-gated active-imaging system and can yield radiometric and odometric information even in turbid water.

  8. Navigation System Fault Diagnosis for Underwater Vehicle

    DEFF Research Database (Denmark)

    Falkenberg, Thomas; Gregersen, Rene Tavs; Blanke, Mogens

    2014-01-01

    This paper demonstrates fault diagnosis on unmanned underwater vehicles (UUV) based on analysis of structure of the nonlinear dynamics. Residuals are generated using dierent approaches in structural analysis followed by statistical change detection. Hypothesis testing thresholds are made signal b...

  9. Sensor network architectures for monitoring underwater pipelines.

    Science.gov (United States)

    Mohamed, Nader; Jawhar, Imad; Al-Jaroodi, Jameela; Zhang, Liren

    2011-01-01

    This paper develops and compares different sensor network architecture designs that can be used for monitoring underwater pipeline infrastructures. These architectures are underwater wired sensor networks, underwater acoustic wireless sensor networks, RF (radio frequency) wireless sensor networks, integrated wired/acoustic wireless sensor networks, and integrated wired/RF wireless sensor networks. The paper also discusses the reliability challenges and enhancement approaches for these network architectures. The reliability evaluation, characteristics, advantages, and disadvantages among these architectures are discussed and compared. Three reliability factors are used for the discussion and comparison: the network connectivity, the continuity of power supply for the network, and the physical network security. In addition, the paper also develops and evaluates a hierarchical sensor network framework for underwater pipeline monitoring.

  10. Sensor Network Architectures for Monitoring Underwater Pipelines

    Directory of Open Access Journals (Sweden)

    Imad Jawhar

    2011-11-01

    Full Text Available This paper develops and compares different sensor network architecture designs that can be used for monitoring underwater pipeline infrastructures. These architectures are underwater wired sensor networks, underwater acoustic wireless sensor networks, RF (Radio Frequency wireless sensor networks, integrated wired/acoustic wireless sensor networks, and integrated wired/RF wireless sensor networks. The paper also discusses the reliability challenges and enhancement approaches for these network architectures. The reliability evaluation, characteristics, advantages, and disadvantages among these architectures are discussed and compared. Three reliability factors are used for the discussion and comparison: the network connectivity, the continuity of power supply for the network, and the physical network security. In addition, the paper also develops and evaluates a hierarchical sensor network framework for underwater pipeline monitoring.

  11. Time Synchronization for Mobile Underwater Sensor Networks

    Directory of Open Access Journals (Sweden)

    Ying Guo

    2013-01-01

    Full Text Available Time synchronization is very crucial for the implementation of energy constricted underwater wireless sensor networks (UWSN. The purpose of this paper is to present a time synchronization algorithm which is suitable to UWSN. Although several time synchronization protocols have been developed, most of them tend to break down when implemented on mobile underwater sensor networks. In this paper, we analyze the effect of node mobility, and propose a Mobile Counteracted Time Synchronization approach, called “Mc-Sync”, which is a novel time synchronization scheme for mobile underwater acoustic sensor networks. It makes use of two mobile reference nodes to counteract the effect of node mobility. We also analyze and design the optimized trajectories of the two mobile reference nodes in underwater environment. We show through analysis and simulation that Mc-Sync provides much better performance than existing schemes.

  12. Underwater Acoustic Sensing with Optical Fibres

    Directory of Open Access Journals (Sweden)

    V. V. Rampal

    1982-01-01

    Full Text Available The use of optical fibres for the detection of acoustic pressure underwater has been discussed with particular reference to the recent literature on the development of fibre optic hydrophones.

  13. Autonomous underwater riser inspection tool

    Energy Technology Data Exchange (ETDEWEB)

    Camerini, Claudio; Marnet, Robson [Petrobras SA, (Brazil); Freitas, Miguel; Von der Weid, Jean Pierre [CPTI/PUC-Rio, Rio de Janeiro, (Brazil); Artigas Lander, Ricardo [EngeMOVI, Curitiba, (Brazil)

    2010-07-01

    The detection of damage on the riser is a serious concern for pipeline companies. Visual examinations by remotely operated vehicle (ROV) are presently carried out to detect the defects but this process has limitations and is expensive. This paper presents the development of a new tool to ensure autonomous underwater riser inspection (AURI) that uses the riser itself for guidance. The AURI, which is autonomous in terms of control and power supply, is equipped with several cameras that perform a complete visual inspection of the riser with 100 % coverage of the external surface of the riser. The paper presents the detailed characteristics of the first AURI prototype, describes its launching procedure and provides the preliminary test results from pool testing. The results showed that the AURI is a viable system for autonomous riser inspection. Offshore tests on riser pipelines are scheduled to be performed shortly.

  14. Experimental and theoretical investigation of mechanical disturbances in epoxy-impregnated superconducting coils. 2. Shear-stress-induced epoxy fracture as the principal source of premature quenches and training theoretical analysis

    Science.gov (United States)

    Bobrov, E. S.; Williams, J. E. C.; Iwasa, Y.

    An epoxy-impregnated superconducting winding may be considered structurally as a unidirectional composite consisting of superconducting wires embedded in a matrix of epoxy resin. The epoxy, because of its low strength and brittleness at low temperatures, is susceptible to brittle fracture which occurs under stresses induced initially during the cooldown (by differential thermal contractions of epoxy and metal) and subsequently during the magnet charge-up (by the Lorentz forces). Various modes of matrix failure are discussed and analysed. For the composite winding represented by four principal characteristics - geometry; constituent material properties; winding boundary conditions; and microcracks which become stress concentration sites for the initiation of further cracking. It is demonstrated that the transverse shear stresses induced by Lorentz forces in windings with cylindrical symmetry are principally responsible for premature magnet quenches. It is further demonstrated that to minimize shear stresses and thus prevent epoxy fracture in the winding, the whole winding body must not be restrained by the coil form and must be free to take its natural shape as the magnet is energized. This unrestrained winding support design is called the floating coil concept. The conclusions of the analysis agree both qualitatively and quantitatively with experimental results reported in the next two parts of this work.

  15. Autonomous Underwater Vehicle Planning for Information Exploitation

    Science.gov (United States)

    2012-03-01

    Remotely Operated Vehicles (ROV’s) and Autonomous Underwater Vehicles (AUVs) are being used extensively in fields of underwater cartography , exploration...controls required to follow each candidate trajectory. What we are essentially doing is computing the time- histories of the states and controls along...numerically differentiate (3.24) in order to check a given constraint on Ψ such as |Ψ̇(t)| ≤ Ψ̇max. The net result is a time- history of the states and

  16. Ocean Variability Effects on Underwater Acoustic Communications

    Science.gov (United States)

    2007-09-30

    B is about 6 dB higher than that during enviromental case A. Due to the large aperture and deployment range of the MPL array, the channel impulse...coherence. IMPACT /APPLICATIONS The developed receiver is a robust structure for high data rate underwater digital communications at high frequencies...H.-C. Song, W. S. Hodgkiss, M. B. Porter, and the KauaiEx group, “ Impact of Ocean Variability on Coherent Underwater Acoustic Communications

  17. Underwater Robotic Propulsors Inspired by Jetting Jellyfish

    OpenAIRE

    Marut, Kenneth Joseph

    2014-01-01

    Underwater surveillance missions both for defense and civilian applications are continually demanding the need for unmanned underwater vehicles or UUVs. Unmanned vehicles are needed to meet the logistical requirements for operation over long distances, greater depths, long duration, and harsh conditions. In order to design UUVs that not only satisfy these needs but are also adaptive and efficient, there has been increasing interest in taking inspiration from nature. These biomimetic/bio-insp...

  18. Recognition of epoxy with phage displayed peptides.

    Science.gov (United States)

    Swaminathan, Swathi; Cui, Yue

    2013-07-01

    The development of a general approach for non-destructive chemical and biological functionalization of epoxy could expand opportunities for both fundamental studies and creating various device platforms. Epoxy shows unique electrical, mechanical, chemical and biological compatibility and has been widely used for fabricating a variety of devices. Phage display has emerged as a powerful method for selecting peptides that possess enhanced selectivity and binding affinity toward a variety of targets. In this letter, we demonstrate for the first time a powerful yet benign approach for identifying binding motifs to epoxy via comprehensively screened phage displayed peptides. Our results show that the epoxy can be selectively recognized with peptide-displaying phages. Further, along with the development of epoxy-based microstructures; recognition of the epoxy with phage displayed peptides can be specifically localized in these microstructures. We anticipate that these results could open up exciting opportunities in the use of peptide-recognized epoxy in fundamental biochemical recognition studies, as well as in applications ranging from analytical devices, hybrid materials, surface and interface, to cell biology. Copyright © 2013 Elsevier B.V. All rights reserved.

  19. An evaluation of underwater epoxies to permanently install temperature sensors in mountain streams

    Science.gov (United States)

    Daniel J. Isaak; Dona L. Horan

    2011-01-01

    Stream temperature regimes are of fundamental importance in understanding the patterns and processes in aquatic ecosystems, and inexpensive digital sensors provide accurate and repeated measurements of temperature. Most temperature measurements in mountain streams are made only during summer months because of logistical constraints associated with stream access and...

  20. Development of ICPF Actuated Underwater Microrobots

    Institute of Scientific and Technical Information of China (English)

    Xiuo-Fen Ye; Bao-Feng Gao; Shu-Xiang Guo; Li-Quan Wang

    2006-01-01

    It is our target to develop underwater microrobots for medical and industrial applications. This kind of underwater microrobots should have the characteristics of flexibility, good response and safety. Its structure should be simple and it can be driven by low voltage and produces no pollution or noise. The low actuating voltage and quick bending responses of Ionic Conducting Polymer Film (ICPF) are considered very useful and attractive for constructing various types of actuators and sensors. In this paper, we will first study the characteristics of the ICPF actuator used in underwater microrobot to realize swimming and walking. Then, we propose a new prototype model of underwater swimming microrobot utilizing only one piece of ICPF as the servo actuator. Through theoretic analysis, the motion mechanism of the microrobot is illustrated. It can swim forward and vertically. The relationships between moving speed and signal voltage amplitude and signal frequency is obtained after experimental study. Lastly, we present a novel underwater crab-like walking microrobot named crabliker-1. It has eight legs, and each leg is made up of two pieces of ICPF. Three sample processes of the octopod gait are proposed with a new analyzing method. The experimental results indicate that the crab-like underwater microrobot can perform transverse and rotation movement when the legs of the crab collaborate.

  1. Affordable underwater wireless optical communication using LEDs

    Science.gov (United States)

    Pilipenko, Vladimir; Arnon, Shlomi

    2013-09-01

    In recent years the need for high data rate underwater wireless communication (WC) has increased. Nowadays, the conventional technology for underwater communication is acoustic. However, the maximum data rate that acoustic technology can provide is a few kilobits per second. On the other hand, emerging applications such as underwater imaging, networks of sensors and swarms of underwater vehicles require much faster data rates. As a result, underwater optical WC, which can provide much higher data rates, has been proposed as an alternative means of communication. In addition to high data rates, affordable communication systems become an important feature in the development requirements. The outcome of these requirements is a new system design based on off-the-shelf components such as blue and green light emitting diodes (LEDs). This is due to the fact that LEDs offer solutions characterized by low cost, high efficiency, reliability and compactness. However, there are some challenges to be met when incorporating LEDs as part of the optical transmitter, such as low modulation rates and non linearity. In this paper, we review the main challenges facing the incorporation of LEDs as an integral part of underwater WC systems and propose some techniques to mitigate the LED limitations in order to achieve high data rate communication

  2. Mechanical behaviors of hyberbranched epoxy toughened bisphenol F epoxy resin for cryogenic applications

    Science.gov (United States)

    Li, Jingwen; Wu, Zhixiong; Huang, Chuanjun; Huang, Rongjin; Li, Laifeng

    2014-01-01

    Epoxy resins have been widely employed in cryogenic engineering fields. In this work, bisphenol F epoxy resin was modified by an aromatic polyester hyperbranched epoxy resin (HTDE-2). Mechanical behaviors of the modified epoxy resins in terms of tensile properties and impact property were studied at both room and cryogenic temperatures. Moreover, the toughening mechanism was discussed by fracture surface morphology analysis. The results demonstrated that, the mechanical properties of composites initially increased until reaches the maximum value with increasing the mass content of the HTDE-2, and then decreased at both room temperature (RT) and 77K. Especially, the impact strength at 77 K was improved 40.7% compared with the pure epoxy matrix when 10 wt% HTDE-2 was introduced. The findings suggest that the HTDE-2 will be an effective toughener for the brittle bisphenol F epoxy resin for cryogenic applications.

  3. A Cost-Effective Two-Part Experiment for Teaching Introductory Organic Chemistry Techniques

    Science.gov (United States)

    Sadek, Christopher M.; Brown, Brenna A.; Wan, Hayley

    2011-01-01

    This two-part laboratory experiment is designed to be a cost-effective method for teaching basic organic laboratory techniques (recrystallization, thin-layer chromatography, column chromatography, vacuum filtration, and melting point determination) to large classes of introductory organic chemistry students. Students are exposed to different…

  4. Synthesis and characterization of novel multifunctional epoxy resin

    Institute of Scientific and Technical Information of China (English)

    Jue Cheng; Jing Chen; Wan Tai Yang

    2007-01-01

    A novel multifunctional epoxy resin was synthesized by polyphenol and epichlorohydrin. The structure and molecular weight of the multifunctional epoxy were characterized by FTIR and ESI-MS. DSC and DMTA were used to investigate the thermal property of multifunctional epoxy cured by DDS. The thermal resistance of the synthesized multifunctional epoxy was much better than a standard diglycidyl ether of bisphenol-A epoxy.

  5. Advanced resin systems for graphite epoxy composites

    Science.gov (United States)

    Gilwee, W. J.; Jayarajan, A.

    1980-01-01

    The value of resin/carbon fiber composites as lightweight structures for aircraft and other vehicle applications is dependent on many properties: environmental stability, strength, toughness, resistance to burning, smoke produced when burning, raw material costs, and complexity of processing. A number of woven carbon fiber and epoxy resin composites were made. The epoxy resin was commercially available tetraglycidylmethylene dianiline. In addition, composites were made using epoxy resin modified with amine and carboxyl terminated butadiene acrylonitrile copolymer. Strength and toughness in flexure as well as oxygen index flammability and NBS smoke chamber tests of the composites are reported.

  6. Epoxy Foam Encapsulants: Processing and Dielectric Characterization

    Energy Technology Data Exchange (ETDEWEB)

    Linda Domeier; Marion Hunter

    1999-01-01

    The dielectric performance of epoxy foams was investigated to determine if such materials might provide advantages over more standard polyurethane foams in the encapsulation of electronic assemblies. Comparisons of the dielectric characteristics of epoxy and urethane encapsulant foams found no significant differences between the two resin types and no significant difference between as-molded and machined foams. This study specifically evaluated the formulation and processing of epoxy foams using simple methylhydrosiloxanes as the flowing agent and compared the dielectric performance of those to urethane foams of similar density.

  7. Structural/Radiation-Shielding Epoxies

    Science.gov (United States)

    Connell, John W.; Smith, Joseph G.; Hinkley, Jeffrey; Blattnig, Steve; Delozier, Donavon M.; Watson, Kent A.; Ghose, Sayata

    2009-01-01

    A development effort was directed toward formulating epoxy resins that are useful both as structural materials and as shielding against heavy-ion radiation. Hydrogen is recognized as the best element for absorbing heavy-ion radiation, and high-hydrogen-content polymers are now in use as shielding materials. However, high-hydrogen-content polymers (e.g. polyethylene) are typically not good structural materials. In contrast, aromatic polymers, which contain smaller amounts of hydrogen, often have the strength necessary for structural materials. Accordingly, the present development effort is based on the concept that an ideal structural/ heavy-ion-radiation-shielding material would be a polymer that contains sufficient hydrogen (e.g., in the form of aliphatic molecular groups) for radiation shielding and has sufficient aromatic content for structural integrity.

  8. Ionic Liquid Epoxy Composite Cryotanks Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The objective of this work is to determine the optimal process for manufacturing lightweight linerless cryogenic storage tanks using ionic liquid epoxy composite...

  9. [Allergic contact eczema from epoxy resin].

    Science.gov (United States)

    Calzado, Leticia; Ortiz-de Frutos, Francisco J; del Prado Sánchez-Caminero, María; Galera, Carmen María; Valverde, Ricardo; Vanaclocha, Francisco

    2005-11-01

    Epoxy resins are plastics that are widely used as electrical insulation, in coatings, and as adhesives and paints. They have strong sensitizing power and are one of the main causes of allergic contact eczema, both in the workplace and elsewhere. We present the case of a worker at a plastics/chemical plant, who handled aeronautical components in the process of manufacturing fuselage parts. He consulted his physician because of eczematous lesions on his fingers, hands and forearms which had developed over a two-year period and were clearly related to his work. The standard battery of skin tests was performed, along with the plastics and adhesives series and tests using the products from his workplace. Positivity was shown to epoxy resins (standard battery) and to the products from his workplace, which included different fiberglass and carbon fiber sheets impregnated with epoxy resins and epoxy adhesives.

  10. Structure Property Relationships of Biobased Epoxy Resins

    Science.gov (United States)

    Maiorana, Anthony Surraht

    The thesis is about the synthesis, characterization, development, and application of epoxy resins derived from sustainable feedstocks such as lingo-cellulose, plant oils, and other non-food feedstocks. The thesis can be divided into two main topics 1) the synthesis and structure property relationship investigation of new biobased epoxy resin families and 2) mixing epoxy resins with reactive diluents, nanoparticles, toughening agents, and understanding co-curing reactions, filler/matrix interactions, and cured epoxy resin thermomechanical, viscoelastic, and dielectric properties. The thesis seeks to bridge the gap between new epoxy resin development, application for composites and advanced materials, processing and manufacturing, and end of life of thermoset polymers. The structures of uncured epoxy resins are characterized through traditional small molecule techniques such as nuclear magnetic resonance, high resolution mass spectrometry, and infrared spectroscopy. The structure of epoxy resin monomers are further understood through the process of curing the resins and cured resins' properties through rheology, chemorheology, dynamic mechanical analysis, tensile testing, fracture toughness, differential scanning calorimetry, scanning electron microscopy, thermogravimetric analysis, and notched izod impact testing. It was found that diphenolate esters are viable alternatives to bisphenol A and that the structure of the ester side chain can have signifi-cant effects on monomer viscosity. The structure of the cured diphenolate based epoxy resins also influence glass transition temperature and dielectric properties. Incorporation of reactive diluents and flexible resins can lower viscosity, extend gel time, and enable processing of high filler content composites and increase fracture toughness. Incorpora-tion of high elastic modulus nanoparticles such as graphene can provide increases in physical properties such as elastic modulus and fracture toughness. The synthesis

  11. Advanced Concepts for Underwater Acoustic Channel Modeling

    Science.gov (United States)

    Etter, P. C.; Haas, C. H.; Ramani, D. V.

    2014-12-01

    This paper examines nearshore underwater-acoustic channel modeling concepts and compares channel-state information requirements against existing modeling capabilities. This process defines a subset of candidate acoustic models suitable for simulating signal propagation in underwater communications. Underwater-acoustic communications find many practical applications in coastal oceanography, and networking is the enabling technology for these applications. Such networks can be formed by establishing two-way acoustic links between autonomous underwater vehicles and moored oceanographic sensors. These networks can be connected to a surface unit for further data transfer to ships, satellites, or shore stations via a radio-frequency link. This configuration establishes an interactive environment in which researchers can extract real-time data from multiple, but distant, underwater instruments. After evaluating the obtained data, control messages can be sent back to individual instruments to adapt the networks to changing situations. Underwater networks can also be used to increase the operating ranges of autonomous underwater vehicles by hopping the control and data messages through networks that cover large areas. A model of the ocean medium between acoustic sources and receivers is called a channel model. In an oceanic channel, characteristics of the acoustic signals change as they travel from transmitters to receivers. These characteristics depend upon the acoustic frequency, the distances between sources and receivers, the paths followed by the signals, and the prevailing ocean environment in the vicinity of the paths. Properties of the received signals can be derived from those of the transmitted signals using these channel models. This study concludes that ray-theory models are best suited to the simulation of acoustic signal propagation in oceanic channels and identifies 33 such models that are eligible candidates.

  12. Geometric documentation of underwater archaeological sites

    Directory of Open Access Journals (Sweden)

    Eleni Diamanti

    2013-12-01

    Full Text Available Photogrammetry has often been the most preferable method for the geometric documentation of monuments, especially in cases of highly complex objects, of high accuracy and quality requirements and, of course, budget, time or accessibility limitations. Such limitations, requirements and complexities are undoubtedly features of the highly challenging task of surveying an underwater archaeological site. This paper is focused on the case of a Hellenistic shipwreck found in Greece at the Southern Euboean gulf, 40-47 meters below the sea surface. Underwater photogrammetry was chosen as the ideal solution for the detailed and accurate mapping of a shipwreck located in an environment with limited accessibility. There are time limitations when diving at these depths so it is essential that the data collection time is kept as short as possible. This makes custom surveying techniques rather impossible to apply. However, with the growing use of consumer cameras and photogrammetric software, this application is becoming easier, thus benefiting a wide variety of underwater sites. Utilizing cameras for underwater photogrammetry though, poses some crucial modeling problems, due to the refraction effect and further additional parameters which have to be co-estimated [1]. The applied method involved an underwater calibration of the camera as well as conventional field survey measurements in order to establish a reference frame. The application of a three-dimensional trilateration using common tape measures was chosen for this reason. Among the software that was used for surveying and photogrammetry processing, were Site Recorder SE, Eos Systems Photomodeler, ZI’s SSK and Rhinoceros. The underwater archaeological research at the Southern Euboean gulf is a continuing project carried out by the Hellenic Institute for Marine Archaeology (H.I.M.A. in collaboration with the Greek Ephorate of Underwater Antiquities, under the direction of the archaeologist G

  13. Development of the two-part pattern during regeneration of the head in hydra

    DEFF Research Database (Denmark)

    Bode, Matthias; Awad, T A; Koizumi, O;

    1988-01-01

    The head of a hydra is composed of two parts, a domed hypostome with a mouth at the top and a ring of tentacles below. When animals are decapitated a new head regenerates. During the process of regeneration the apical tip passes through a transient stage in which it exhibits tentacle...... began evaginating in a ring, both the TS-19 antigen and RLI+ ganglion cells gradually disappeared from the presumptive hypostome area and RLI+ sensory cells appeared at the apex. By tracking tissue movements during morphogenesis it became clear that the apical cap, in which these changes took place, did...... not undergo tissue turnover. The implications of this tentacle-like stage for patterning the two-part head are discussed....

  14. Vacuum impregnation with epoxy of large superconducting magnet structures

    Energy Technology Data Exchange (ETDEWEB)

    Green, M.A.; Coyle, D.E.; Miller, P.B.; Wenzel, W.F.

    1978-06-01

    The Lawrence Berkeley Laboratory (LBL) has been developing a new generation of superconducting magnets which have the helium cooling system as an integral part of the magnet structure. The LBL technique calls for large sections of the magnet structure to be vacuum impregnated with epoxy. The epoxy was chosen for its impregnation properties. Epoxies which have good impregnation characteristics are often subject to cracking when they are cooled to cryogenic temperatures. The cracking of such an epoxy can be controlled by: (1) minimizing the amount of epoxy in the structure; (2) reducing the size of unfilled epoxy spaces; and (3) keeping the epoxy in compression. The technique for using the epoxy is often more important than the formulation of the epoxy. The LBL vacuum impregnation and curing technique is described. Experimental measurements on small samples of coil sections are presented. Practical experience with large vacuum impregnation superconducting coils (up to two meters in dia) is also discussed.

  15. Orthophoto imaging and GIS for seabed visualization and underwater archaeology

    OpenAIRE

    Seinturier, Julien; Drap, Pierre; Durand, Anne; Vincent, N.; Cibecchi, F.; Papani, O.; Grussenmeyer, Pierre

    2004-01-01

    We present here the first step of an interdisciplinary work dealing with underwater photogrammetry and archaeological data management. In the framework of a phd project we develop a set of tools from underwater data capture to 3D underwater GIS for archaeological excavation. The phd project, managed by Julien Seinturier, is monitored by Odile Papini for the data fusion aspect and Pierre Drap for the underwater photogrammetrical aspect. The project is financed together by the French Region PAC...

  16. On Modeling Eavesdropping Attacks in Underwater Acoustic Sensor Networks †

    OpenAIRE

    Qiu Wang; Hong-Ning Dai; Xuran Li; Hao Wang; Hong Xiao

    2016-01-01

    The security and privacy of underwater acoustic sensor networks has received extensive attention recently due to the proliferation of underwater activities. This paper proposes an analytical model to investigate the eavesdropping attacks in underwater acoustic sensor networks. Our analytical framework considers the impacts of various underwater acoustic channel conditions (such as the acoustic signal frequency, spreading factor and wind speed) and different hydrophones (isotropic hydrophones ...

  17. Omnidirectional Underwater Camera Design and Calibration

    Directory of Open Access Journals (Sweden)

    Josep Bosch

    2015-03-01

    Full Text Available This paper presents the development of an underwater omnidirectional multi-camera system (OMS based on a commercially available six-camera system, originally designed for land applications. A full calibration method is presented for the estimation of both the intrinsic and extrinsic parameters, which is able to cope with wide-angle lenses and non-overlapping cameras simultaneously. This method is valid for any OMS in both land or water applications. For underwater use, a customized housing is required, which often leads to strong image distortion due to refraction among the different media. This phenomena makes the basic pinhole camera model invalid for underwater cameras, especially when using wide-angle lenses, and requires the explicit modeling of the individual optical rays. To address this problem, a ray tracing approach has been adopted to create a field-of-view (FOV simulator for underwater cameras. The simulator allows for the testing of different housing geometries and optics for the cameras to ensure a complete hemisphere coverage in underwater operation. This paper describes the design and testing of a compact custom housing for a commercial off-the-shelf OMS camera (Ladybug 3 and presents the first results of its use. A proposed three-stage calibration process allows for the estimation of all of the relevant camera parameters. Experimental results are presented, which illustrate the performance of the calibration method and validate the approach.

  18. Underwater Calibration of Dome Port Pressure Housings

    Science.gov (United States)

    Nocerino, E.; Menna, F.; Fassi, F.; Remondino, F.

    2016-03-01

    Underwater photogrammetry using consumer grade photographic equipment can be feasible for different applications, e.g. archaeology, biology, industrial inspections, etc. The use of a camera underwater can be very different from its terrestrial use due to the optical phenomena involved. The presence of the water and camera pressure housing in front of the camera act as additional optical elements. Spherical dome ports are difficult to manufacture and consequently expensive but at the same time they are the most useful for underwater photogrammetry as they keep the main geometric characteristics of the lens unchanged. Nevertheless, the manufacturing and alignment of dome port pressure housing components can be the source of unexpected changes of radial and decentring distortion, source of systematic errors that can influence the final 3D measurements. The paper provides a brief introduction of underwater optical phenomena involved in underwater photography, then presents the main differences between flat and dome ports to finally discuss the effect of manufacturing on 3D measurements in two case studies.

  19. Omnidirectional underwater camera design and calibration.

    Science.gov (United States)

    Bosch, Josep; Gracias, Nuno; Ridao, Pere; Ribas, David

    2015-03-12

    This paper presents the development of an underwater omnidirectional multi-camera system (OMS) based on a commercially available six-camera system, originally designed for land applications. A full calibration method is presented for the estimation of both the intrinsic and extrinsic parameters, which is able to cope with wide-angle lenses and non-overlapping cameras simultaneously. This method is valid for any OMS in both land or water applications. For underwater use, a customized housing is required, which often leads to strong image distortion due to refraction among the different media. This phenomena makes the basic pinhole camera model invalid for underwater cameras, especially when using wide-angle lenses, and requires the explicit modeling of the individual optical rays. To address this problem, a ray tracing approach has been adopted to create a field-of-view (FOV) simulator for underwater cameras. The simulator allows for the testing of different housing geometries and optics for the cameras to ensure a complete hemisphere coverage in underwater operation. This paper describes the design and testing of a compact custom housing for a commercial off-the-shelf OMS camera (Ladybug 3) and presents the first results of its use. A proposed three-stage calibration process allows for the estimation of all of the relevant camera parameters. Experimental results are presented, which illustrate the performance of the calibration method and validate the approach.

  20. Effect of cure cycle on enthalpy relaxation and post shrinkage in neat epoxy and epoxy composites

    DEFF Research Database (Denmark)

    Jensen, Martin; Jakobsen, Johnny

    2016-01-01

    The effect of cure cycle on enthalpy relaxation and warpage is studied for both neat epoxy and glass/epoxy composites. An approach for determining the enthalpy relaxation in the matrix of composite materials combining modulated differential scanning calorimetry and thermogravimetry is presented...

  1. Modeling and Model Identification of Autonomous Underwater Vehicles

    Science.gov (United States)

    2015-06-01

    IDENTIFICATION OF AUTONOMOUS UNDERWATER VEHICLES by Jose Alberti June 2015 Thesis Advisor: Noel du Toit Second Reader: Douglas...Master’s Thesis 4. TITLE AND SUBTITLE MODELING AND MODEL IDENTIFICATION OF AUTONOMOUS UNDERWATER VEHICLES 5. FUNDING NUMBERS 6. AUTHOR(S...unlimited 12b. DISTRIBUTION CODE 13. ABSTRACT (maximum 200 words) As autonomous underwater vehicles (AUVs) are deployed in more complex

  2. Underwater robots to safeguard Olympic Games in 2008

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ A small-sized autonomous underwater vehicle(AUV) independently developed and built by CAS researchers has been designated as an underwater guard for the forthcoming Olympic Game in 2008 in Beijing. It has recently been approved by the Olympic Sub-committee of Sailing to be a component of the "underwater safety alert system" of the competition.

  3. Wave run up in Zones of Underwater Canyons

    Directory of Open Access Journals (Sweden)

    Katline Koblev A. Julio

    2013-01-01

    Full Text Available The wave run up on coast and shore protection constructions in zones of underwater canyons is considered. The mathematical model of wave run up on the coast, considering distinctions in biases of underwater and surface parts of the coastal slope, allowing to receive setup parameters in zones of the underwater canyons, corresponding to data of supervision is offered.

  4. 46 CFR 167.05-40 - Underwater survey.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Underwater survey. 167.05-40 Section 167.05-40 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) NAUTICAL SCHOOLS PUBLIC NAUTICAL SCHOOL SHIPS Definitions § 167.05-40 Underwater survey. Underwater survey means the examination of the vessel's...

  5. Molecular design of an epoxy for cryogenic temperatures

    Science.gov (United States)

    Sawa, Fumio; Nishijima, Shigehiro; Okada, Toichi

    The mechanical and thermal properties of several epoxy resins were measured to obtain guidelines for the molecular design of an epoxy resin for cryogenic temperatures. Two types of epoxy resin with different numbers of epoxy groups were mixed (with different mixing ratios) and cured. Fracture toughness, flexural strength and thermal contraction of the hybrid epoxy resins were measured down to cryogenic temperatures. The results suggest that epoxies with larger molecular weights between crosslinkings relaxed stress at the crack tip, even at cryogenic temperatures. Intermolecular forces and stress relaxation at the crack tip were found to be important for high fracture toughness.

  6. Application of time reversal in underwater communication

    Institute of Scientific and Technical Information of China (English)

    LU Minghui; ZHANG Bixing; WANG Chenghao

    2004-01-01

    Time reversal is applied to the underwater spreading spectrum coding communication. On the base of analyzing the focusing characteristics of the time reversal in underwater waveguide, the time reversal is studied to overcome the wave distortion of the encoded signal caused by the multi-path effect. The experiment research for underwater coding communication is carried out in a lab water tank and the corresponding theoretical analysis is also conducted by Binary Phase Shift Keying (BPSK) encoding and Barker code with 7 chips for the spreading spectrum signal. The results show that the time reversal can improve the focusing gain and increase the ratio of the principal to the second lobe of the coding signal, and can decrease the bit error rate and increase the communication distance.

  7. Survivability design for a hybrid underwater vehicle

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Biao; Wu, Chao; Li, Xiang; Zhao, Qingkai; Ge, Tong [State Key Lab of Ocean Engineering, School of Naval Architecture, Ocean and Civil Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China)

    2015-03-10

    A novel hybrid underwater robotic vehicle (HROV) capable of working to the full ocean depth has been developed. The battery powered vehicle operates in two modes: operate as an untethered autonomous vehicle in autonomous underwater vehicle (AUV) mode and operate under remote control connected to the surface vessel by a lightweight, fiber optic tether in remotely operated vehicle (ROV) mode. Considering the hazardous underwater environment at the limiting depth and the hybrid operating modes, survivability has been placed on an equal level with the other design attributes of the HROV since the beginning of the project. This paper reports the survivability design elements for the HROV including basic vehicle design of integrated navigation and integrated communication, emergency recovery strategy, distributed architecture, redundant bus, dual battery package, emergency jettison system and self-repairing control system.

  8. Autonomous underwater pipeline monitoring navigation system

    Science.gov (United States)

    Mitchell, Byrel; Mahmoudian, Nina; Meadows, Guy

    2014-06-01

    This paper details the development of an autonomous motion-control and navigation algorithm for an underwater autonomous vehicle, the Ocean Server IVER3, to track long linear features such as underwater pipelines. As part of this work, the Nonlinear and Autonomous Systems Laboratory (NAS Lab) developed an algorithm that utilizes inputs from the vehicles state of the art sensor package, which includes digital imaging, digital 3-D Sidescan Sonar, and Acoustic Doppler Current Profilers. The resulting algorithms should tolerate real-world waterway with episodic strong currents, low visibility, high sediment content, and a variety of small and large vessel traffic.

  9. Efficient Modelling Methodology for Reconfigurable Underwater Robots

    DEFF Research Database (Denmark)

    Nielsen, Mikkel Cornelius; Blanke, Mogens; Schjølberg, Ingrid

    2016-01-01

    This paper considers the challenge of applying reconfigurable robots in an underwater environment. The main result presented is the development of a model for a system comprised of N, possibly heterogeneous, robots dynamically connected to each other and moving with 6 Degrees of Freedom (DOF......). This paper presents an application of the Udwadia-Kalaba Equation for modelling the Reconfigurable Underwater Robots. The constraints developed to enforce the rigid connection between robots in the system is derived through restrictions on relative distances and orientations. To avoid singularities...

  10. Stabilization of coordinated motion for underwater vehicles

    Institute of Scientific and Technical Information of China (English)

    Fan Wu; Zhi-Yong Geng

    2011-01-01

    This paper presents a coordinating and stabilizing control law for a group of underwater vehicles with unstable dynamics. The coordinating law is derived from a potential that only depends on the relative configuration of the underwater vehicles. Being coordinated, the group behaves like one mechanical system with symmetry, and we focus on stabilizing a family of coordinated motions, called relative equilibria. The stabilizing law is derived using energy shaping to stabilize the relative equilibria which involve each vehicle translating along its longest (unstable) axis without spinning,while maintaining a relative configuration within the group.The proposed control law is physically motivated and avoids the linearization or cancellation of nonlinearities.

  11. DESIGN OPTIMISATION OF AN UNMANNED UNDERWATER VEHICLE

    Directory of Open Access Journals (Sweden)

    FIRDAUS ABDULLAH

    2007-08-01

    Full Text Available The results of fluid flow simulation around an unmanned underwater vehicle (UUV are presented in this paper. The UUV represents a small submarine for underwater search and rescue operation, which suits the local river conditions. The flow simulation was performed with a commercially available computational fluid dynamics package, Star-CD. The effects of the UUV geometry on the velocity and pressure distributions on the UUV surface were discussed for Re=500,000 and 3,000,000. The discussion led to an improved design of the UUV with a smoother velocity profile around the UUV body.

  12. Efficient Modelling Methodology for Reconfigurable Underwater Robots

    DEFF Research Database (Denmark)

    Nielsen, Mikkel Cornelius; Blanke, Mogens; Schjølberg, Ingrid

    2016-01-01

    This paper considers the challenge of applying reconfigurable robots in an underwater environment. The main result presented is the development of a model for a system comprised of N, possibly heterogeneous, robots dynamically connected to each other and moving with 6 Degrees of Freedom (DOF......). This paper presents an application of the Udwadia-Kalaba Equation for modelling the Reconfigurable Underwater Robots. The constraints developed to enforce the rigid connection between robots in the system is derived through restrictions on relative distances and orientations. To avoid singularities...... in the orientation and, thereby, allow the robots to undertake any relative configuration the attitude is represented in Euler parameters....

  13. Chronic Dermal Toxicity of Epoxy Resins I. Skin Carcinogenic Potency and General Toxicity

    Energy Technology Data Exchange (ETDEWEB)

    Holland, J.M.

    2001-01-16

    Epoxy resins are a diverse class of chemicals that differ in structure, physical properties, and, presumably, biological activity. The purpose of these experiments was to compare the chronic dermal toxicity and carcinogenicity of selected commercial epoxy resins and to determine the potential for positive synergistic carcinogenic interactions between different resins. This work is an extension and continuation of a Department of Energy sponsored program to evaluate epoxy resins for potential occupational health risks. The materials examined were chosen on the basis of their interest to the U.S. government. They are representative of the manufacturer's production at the time, and therefore the data are completely valid only for the specific production period. Results of the experimental exposures will be reported in two parts. This report describes the test materials, their chemical and physical characteristics and the experimental design. General (systemic) toxicity will be evaluated and the skin carcinogenicity of the materials compared. A subsequent report will provide morphological descriptions of skin and significant internal pathology induced by the various treatments.

  14. Much ado about two: reconsidering retransformation and the two-part model in health econometrics.

    Science.gov (United States)

    Mullahy, J

    1998-06-01

    In health economics applications involving outcomes (y) and covariates (x), it is often the case that the central inferential problems of interest involve E[y/x] and its associated partial effects or elasticities. Many such outcomes have two fundamental statistical properties: y > or = 0; and the outcome y = 0 is observed with sufficient frequency that the zeros cannot be ignored econometrically. This paper (1) describes circumstances where the standard two-part model with homoskedastic retransformation will fail to provide consistent inferences about important policy parameters; and (2) demonstrates some alternative approaches that are likely to prove helpful in applications.

  15. Physical activity versus cardiorespiratory fitness: two (partly) distinct components of cardiovascular health?

    Science.gov (United States)

    DeFina, Laura F; Haskell, William L; Willis, Benjamin L; Barlow, Carolyn E; Finley, Carrie E; Levine, Benjamin D; Cooper, Kenneth H

    2015-01-01

    Physical activity (PA) and cardiorespiratory fitness (CRF) both have inverse relationships to cardiovascular (CV) morbidity and mortality. Recent position papers and guidelines have identified the important role of both of these factors in CV health. The benefits of PA and CRF in the prevention of CV disease and risk factors are reviewed. In addition, assessment methodology and utilization in the research and clinical arenas are discussed. Finally, the benefits, methodology, and utilization are compared and contrasted to better understand the two (partly) distinct components and their impact on CV health.

  16. Fluorinated Alkyl Ether Epoxy Resin Compositions and Applications Thereof

    Science.gov (United States)

    Wohl, Christopher J. (Inventor); Connell, John W. (Inventor); Smith, Joseph G. (Inventor); Siochi, Emilie J. (Inventor); Gardner, John M. (Inventor); Palmieri, Frank M. (Inventor)

    2017-01-01

    Epoxy resin compositions prepared using amino terminated fluoro alkyl ethers. The epoxy resin compositions exhibit low surface adhesion properties making them useful as coatings, paints, moldings, adhesives, and fiber reinforced composites.

  17. Testing Tensile and Shear Epoxy Strength at Cryogenic Temperatures

    Science.gov (United States)

    Alberts, S. J.; Doehne, C. J.; Johnson, W. L.

    2017-01-01

    This paper covers cryogenic, tensile testing and research completed on a number of epoxies used in cryogenic applications. Epoxies are used in many different applications; however, this research focused on the use of epoxy used to bond MLI standoffs to cryogenic storage tanks and the loads imparted to the tank through the MLI. To conduct testing, samples were made from bare stainless steel, aluminum and primed aluminum. Testing involved slowly cooling test samples with liquid nitrogen then applying gradually increasing tensile loads to the epoxy. The testing evaluated the strength and durability of epoxies at cryogenic temperatures and serves as a base for future testing. The results of the tests showed that some epoxies withstood the harsh conditions while others failed. The two epoxies yielding the best results were Masterbond EP29LPSP and Scotch Weld 2216. For all metal surfaces tested, both epoxies had zero failures for up to 11.81 kg of mass.

  18. Need and Role of Underwater Acoustic Sensor Networks

    Directory of Open Access Journals (Sweden)

    Tajinder Singh

    2013-07-01

    Full Text Available The field of underwater acoustic sensor networking is growing rapidly thanks to the key role it plays in many military and commercial applications. Among these are disaster prevention, tactical surveillance, offshore exploration, pollution monitoring and oceanographic data collection. Moreover, unmanned or autonomous underwater vehicles (UUVs, AUVs, equipped with sensors, will enable the exploration of natural undersea resources and gathering of scientific data in collaborative monitoring missions. Underwater acoustic networking is the enabling technology for these applications. The objective of this paper is to understand several fundamental key aspects of underwater acoustic communications. Different architectures for two-dimensional and three-dimensional underwater sensor networks are discussed, and the characteristics of the underwater channel are detailed. The main challenges for the development of efficient networking solutions posed by the underwater environment are detailed. This paper also presents a detailed explanation of the sensor networks used in tsunami detection. We then present an overview of the recent advances

  19. IVO develops a new repair technique for underwater sites. Viscous doughlike substance underwater cracks

    Energy Technology Data Exchange (ETDEWEB)

    Klingstedt, G.; Leisio, C. [ed.

    1998-07-01

    A viscous sealant is revolutionizing repair of the stone and concrete masonry of underwater dams, bridges and canals. There is now no need for expensive and time-consuming cofferdams, since a diver can extrude quick-setting mortar into underwater structures needing repair. This technique has worked well in recent years in various parts of Finland even in strongly flowing water. IVO experts are now starting to look more beyond the borders of Finland

  20. Two-part silicone mold. A new tool for flexible ureteroscopy surgical training

    Directory of Open Access Journals (Sweden)

    Bruno Marroig

    Full Text Available ABSTRACT Introduction and objectives: Flexible ureteroscopy is a common procedure nowadays. Most of the training programs use virtual reality simulators. The aim of this study was to standardize the building of a three-dimensional silicone mold (cavity of the collecting system, on the basis of polyester resin endocasts, which can be used in surgical training programs. Materials and Methods: A yellow polyester resin was injected into the ureter to fill the collecting system of 24 cadaveric fresh human kidneys. After setting off the resin, the kidneys were immersed in hydrochloric acid until total corrosion of the organic matter was achieved and the collecting system endocasts obtained. The endocasts were used to prepare white color two-part silicone molds, which after endocasts withdrawn, enabled a ureteroscope insertion into the collecting system molds (cavities. Also, the minor calices were painted with different colors in order to map the access to the different caliceal groups. The cost of the materials used in the molds is $30.00 and two days are needed to build them. Results: Flexible ureteroscope could be inserted into all molds and the entire collecting system could be examined. Since some anatomical features, as infundular length, acute angle, and perpendicular minor calices may difficult the access to some minor calices, especially in the lower caliceal group, surgical training in models leads to better surgical results. Conclusions: The two-part silicone mold is feasible, cheap and allows its use for flexible ureteroscopy surgical training.

  1. Chromium Ions Improve Moisure Resistance of Epoxy Resins

    Science.gov (United States)

    St. Clair, A. K.; St. Clair, T. L.; Stoakley, D. M.; Singh, J. J.; Sprinkle, D. R.

    1986-01-01

    Broad spectrum of thermosetting epoxy resins used on commercial and military aircraft, primarily as composite matrices and adhesives. In new technique, chromium-ion containing epoxy with improved resistance to moisture produced where chromium ions believed to prevent absorption of water molecules by coordinating themselves to hydroxyl groups on epoxy chain. Anticipated that improved epoxy formulation useful as composite matrix resin, adhesive, or casting resin for applications on commercial and advanced aircraft. Improvement made without sacrifice in mechanical properties of polymer.

  2. Thermal properties of epoxy composites filled with boric acid

    Science.gov (United States)

    Visakh, P. M.; Nazarenko, O. B.; Amelkovich, Yu A.; Melnikova, T. V.

    2015-04-01

    The thermal properties of epoxy composites filled with boric acid fine powder at different percentage were studied. Epoxy composites were prepared using epoxy resin ED-20, boric acid as flame-retardant filler, hexamethylenediamine as a curing agent. The prepared samples and starting materials were examined using methods of thermal analysis, scanning electron microscopy and infrared spectroscopy. It was found that the incorporation of boric acid fine powder enhances the thermal stability of epoxy composites.

  3. RADIATION EFFECTS ON EPOXY CARBON FIBER COMPOSITE

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, E

    2008-05-30

    Carbon fiber-reinforced bisphenol-A epoxy matrix composite was evaluated for gamma radiation resistance. The composite was exposed to total gamma doses of 50, 100, and 200 Mrad. Irradiated and baseline samples were tested for tensile strength, hardness and evaluated using FTIR (Fourier transform infrared) spectroscopy and DSC (differential scanning calorimetry) for structural changes. Scanning electron microscopy was used to evaluate microstructural behavior. Mechanical testing of the composite bars revealed no apparent change in modulus, strain to failure, or fracture strength after exposures. However, testing of only the epoxy matrix revealed changes in hardness, thermal properties, and FTIR results with increasing gamma irradiation. The results suggest the epoxy within the composite can be affected by exposure to gamma irradiation.

  4. Thermal Conductivity of Carbon Nanoreinforced Epoxy Composites

    Directory of Open Access Journals (Sweden)

    C. Kostagiannakopoulou

    2016-01-01

    Full Text Available The present study attempts to investigate the influence of multiwalled carbon nanotubes (MWCNTs and graphite nanoplatelets (GNPs on thermal conductivity (TC of nanoreinforced polymers and nanomodified carbon fiber epoxy composites (CFRPs. Loading levels from 1 to 3% wt. of MWCNTs and from 1 to 15% wt. of GNPs were used. The results indicate that TC of nanofilled epoxy composites increased with the increase of GNP content. Quantitatively, 176% and 48% increase of TC were achieved in nanoreinforced polymers and nanomodified CFRPs, respectively, with the addition of 15% wt. GNPs into the epoxy matrix. Finally, micromechanical models were applied in order to predict analytically the TC of polymers and CFRPs. Lewis-Nielsen model with optimized parameters provides results very close to the experimental ones in the case of polymers. As far as the composites are concerned, the Hashin and Clayton models proved to be sufficiently accurate for the prediction at lower filler contents.

  5. Unanticipated Effects of Epoxy Impregnating Transformers

    Energy Technology Data Exchange (ETDEWEB)

    SANCHEZ,ROBERT O.; ARCHER,WENDEL E.

    2000-08-23

    Many Sandia components for military applications are designed for a 20-year life. In order to determine if magnetic components meet that requirement, the parts are subjected to selected destructive tests. This paper reviews the re-design of a power transformer and the tests required to prove-in the re-design. The re-design included replacing the Epon 828/Mica/methylenedianiline (curing agent Z) epoxy encapsulant with a recent Sandia National Laboratory (SNL) developed epoxy encapsulant. The new encapsulant reduces the Environmental Safety and Health (ES and H) hazards. Life testing of this re-designed transformer generated failures; an open secondary winding. An experimental program to determine the cause of the broken wires and an improved design to eliminate the problem was executed. This design weakness was corrected by reverting to the hazardous epoxy system.

  6. Atomistic modeling of thermomechanical properties of SWNT/Epoxy nanocomposites

    Science.gov (United States)

    Fasanella, Nicholas; Sundararaghavan, Veera

    2015-09-01

    Molecular dynamics simulations are performed to compute thermomechanical properties of cured epoxy resins reinforced with pristine and covalently functionalized carbon nanotubes. A DGEBA-DDS epoxy network was built using the ‘dendrimer’ growth approach where 75% of available epoxy sites were cross-linked. The epoxy model is verified through comparisons to experiments, and simulations are performed on nanotube reinforced cross-linked epoxy matrix using the CVFF force field in LAMMPS. Full stiffness matrices and linear coefficient of thermal expansion vectors are obtained for the nanocomposite. Large increases in stiffness and large decreases in thermal expansion were seen along the direction of the nanotube for both nanocomposite systems when compared to neat epoxy. The direction transverse to nanotube saw a 40% increase in stiffness due to covalent functionalization over neat epoxy at 1 K whereas the pristine nanotube system only saw a 7% increase due to van der Waals effects. The functionalized SWNT/epoxy nanocomposite showed an additional 42% decrease in thermal expansion along the nanotube direction when compared to the pristine SWNT/epoxy nanocomposite. The stiffness matrices are rotated over every possible orientation to simulate the effects of an isotropic system of randomly oriented nanotubes in the epoxy. The randomly oriented covalently functionalized SWNT/Epoxy nanocomposites showed substantial improvements over the plain epoxy in terms of higher stiffness (200% increase) and lower thermal expansion (32% reduction). Through MD simulations, we develop means to build simulation cells, perform annealing to reach correct densities, compute thermomechanical properties and compare with experiments.

  7. 40 CFR 721.3140 - Vinyl epoxy ester.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Vinyl epoxy ester. 721.3140 Section... Substances § 721.3140 Vinyl epoxy ester. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance vinyl epoxy ester (PMN P-85-527) is subject to reporting under...

  8. Effect of Viscoelasticity on Adhesion of Bioinspired Micropatterned Epoxy Surfaces

    NARCIS (Netherlands)

    Castellanos, G.; Arzt, E.; Kamperman, M.M.G.

    2011-01-01

    The effect of viscoelasticity on adhesion was investigated for micropatterned epoxy surfaces and compared to nonpatterned surfaces. A two-component epoxy system was used to produce epoxy compositions with different viscoelastic properties. Pillar arrays with flat punch tip geometries were fabricated

  9. 40 CFR 721.3135 - Phosphorous modified epoxy resin (generic).

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Phosphorous modified epoxy resin... Specific Chemical Substances § 721.3135 Phosphorous modified epoxy resin (generic). (a) Chemical substance... phosphorous modified epoxy resin (PMNs P-00-992 and P-01-471) is subject to reporting under this section...

  10. 40 CFR 721.2752 - Epoxy resin containing phosphorus (generic).

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Epoxy resin containing phosphorus... Specific Chemical Substances § 721.2752 Epoxy resin containing phosphorus (generic). (a) Chemical substance... epoxy resin containing phosphorus (PMN P-00-912) is subject to reporting under this section for...

  11. Aluminum Rich Epoxy Primer for Ground and Air Vehicles

    Science.gov (United States)

    2017-03-01

    UNCLASSIFIED DOCUMENT Aluminum Rich Epoxy Primer for Ground and Air Vehicles Monthly Technical Report for the Period: January 20, 2017...Objective: To further develop the Aluminum Rich Epoxy Primer systems for Air and Ground Vehicles while addressing the objective requirements... Epoxy Primers in order to afford a lower initial viscosity allowing for better application properties; lower VOC; and the incorporation of various

  12. 40 CFR 721.10113 - Thioether epoxy (generic).

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Thioether epoxy (generic). 721.10113... Substances § 721.10113 Thioether epoxy (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as thioether epoxy (PMN P-04-547) is subject to...

  13. Adaptive turbo equalization for underwater acoustic communication

    NARCIS (Netherlands)

    Cannelli, L; Leus, G.; Dol, H.S.; Walree, P.A. van

    2013-01-01

    In this paper a multiband transceiver designed for underwater channels is presented. Multi-branch filtering at the receiver is used to leverage the diversity offered by a multi-scale multi-lag scenario. The multi-branch bank of filters is constructed by estimating scale and delay coefficients throug

  14. Human Injury Criteria for Underwater Blasts

    Science.gov (United States)

    2014-09-08

    marine mammals, USDI/MMA/OCS study 90-0093, (Bryan, Texas, LGL Ecological Research Assoc, 1991). 17.  Richmond, D., Underwater shock facility and...Martin, P., The Lancet, 242(1943), pp. 336. 50.  Moore, T., British medical journal, 2(1944), pp. 626. 51.  Palma , J., and Uldall, U.S. Naval Medical

  15. Simplified scheduling for underwater acoustic networks

    NARCIS (Netherlands)

    Kleunen, van Wouter; Meratnia, Nirvana; Havinga, Paul J.M.

    2013-01-01

    The acoustic propagation speed under water poses significant challenges to the design of underwater sensor networks and their medium access control protocols. Similar to the air, scheduling transmissions under water has significant impact on throughput, energy consumption, and reliability. In this p

  16. Underwater Simultaneous EMl and Magnetometer System (USEMS)

    Science.gov (United States)

    2011-02-01

    simply maneuver the sensor(s) over them. However, this is not the case with an underwater test strip. Tall bicycle flags used to mark objects risk...USEMS requires the equipment to be strapped to the deck of the boat, and the boat, on its trailer , to be towed to a survey site. The equipment is

  17. Simplified scheduling for underwater acoustic networks

    NARCIS (Netherlands)

    van Kleunen, W.A.P.; Meratnia, Nirvana; Havinga, Paul J.M.

    The acoustic propagation speed under water poses significant challenges to the design of underwater sensor networks and their medium access control protocols. Similar to the air, scheduling transmissions under water has significant impact on throughput, energy consumption, and reliability. In this

  18. Underwater Adhesives Retrofit Pipelines with Advanced Sensors

    Science.gov (United States)

    2015-01-01

    Houston-based Astro Technology Inc. used a partnership with Johnson Space Center to pioneer an advanced fiber-optic monitoring system for offshore oil pipelines. The company's underwater adhesives allow it to retrofit older deepwater systems in order to measure pressure, temperature, strain, and flow properties, giving energy companies crucial data in real time and significantly decreasing the risk of a catastrophe.

  19. Efficient Modelling Methodology for Reconfigurable Underwater Robots

    DEFF Research Database (Denmark)

    Nielsen, Mikkel Cornelius; Blanke, Mogens; Schjølberg, Ingrid

    2016-01-01

    This paper considers the challenge of applying reconfigurable robots in an underwater environment. The main result presented is the development of a model for a system comprised of N, possibly heterogeneous, robots dynamically connected to each other and moving with 6 Degrees of Freedom (DOF...

  20. KE Basin underwater visual fuel survey

    Energy Technology Data Exchange (ETDEWEB)

    Pitner, A.L.

    1995-02-01

    Results of an underwater video fuel survey in KE Basin using a high resolution camera system are presented. Quantitative and qualitative information on fuel degradation are given, and estimates of the total fraction of ruptured fuel elements are provided. Representative photographic illustrations showing the range of fuel conditions observed in the survey are included.

  1. Underwater noise generated by offshore pile driving

    NARCIS (Netherlands)

    Tsouvalas, A.

    2015-01-01

    Anthropogenic noise emission in the marine environment has always been an environmental issue of serious concern. In particular, the noise generated during the installation of foundation piles is considered to be one of the most significant sources of underwater noise pollution. This is mainly attri

  2. Communication and cooperation in underwater acoustic networks

    Science.gov (United States)

    Yerramalli, Srinivas

    In this thesis, we present a study of several problems related to underwater point to point communications and network formation. We explore techniques to improve the achievable data rate on a point to point link using better physical layer techniques and then study sensor cooperation which improves the throughput and reliability in an underwater network. Robust point-to-point communications in underwater networks has become increasingly critical in several military and civilian applications related to underwater communications. We present several physical layer signaling and detection techniques tailored to the underwater channel model to improve the reliability of data detection. First, a simplified underwater channel model in which the time scale distortion on each path is assumed to be the same (single scale channel model in contrast to a more general multi scale model). A novel technique, which exploits the nature of OFDM signaling and the time scale distortion, called Partial FFT Demodulation is derived. It is observed that this new technique has some unique interference suppression properties and performs better than traditional equalizers in several scenarios of interest. Next, we consider the multi scale model for the underwater channel and assume that single scale processing is performed at the receiver. We then derive optimized front end pre-processing techniques to reduce the interference caused during single scale processing of signals transmitted on a multi-scale channel. We then propose an improvised channel estimation technique using dictionary optimization methods for compressive sensing and show that significant performance gains can be obtained using this technique. In the next part of this thesis, we consider the problem of sensor node cooperation among rational nodes whose objective is to improve their individual data rates. We first consider the problem of transmitter cooperation in a multiple access channel and investigate the stability of

  3. Control of pore size in epoxy systems.

    Energy Technology Data Exchange (ETDEWEB)

    Sawyer, Patricia Sue; Lenhart, Joseph Ludlow (North Dakota State University, Fargo, ND); Lee, Elizabeth (North Dakota State University, Fargo, ND); Kallam, Alekhya (North Dakota State University, Fargo, ND); Majumdar, Partha (North Dakota State University, Fargo, ND); Dirk, Shawn M.; Gubbins, Nathan; Chisholm, Bret J. (North Dakota State University, Fargo, ND); Celina, Mathias Christopher; Bahr, James (North Dakota State University, Fargo, ND); Klein, Robert J.

    2009-01-01

    Both conventional and combinatorial approaches were used to study the pore formation process in epoxy based polymer systems. Sandia National Laboratories conducted the initial work and collaborated with North Dakota State University (NDSU) using a combinatorial research approach to produce a library of novel monomers and crosslinkers capable of forming porous polymers. The library was screened to determine the physical factors that control porosity, such as porogen loading, polymer-porogen interactions, and polymer crosslink density. We have identified the physical and chemical factors that control the average porosity, pore size, and pore size distribution within epoxy based systems.

  4. Epoxy-based carbon nanotubes reinforced composites

    CSIR Research Space (South Africa)

    Kesavan Pillai, Sreejarani

    2011-04-01

    Full Text Available ). After curing the composite film system, the substrate was etched from the backside by deep reactive ion etching (DRIE) which left a circular thin film on the rigid substrate with a hole 8 mm in diameter. Extensive examination of the CNT... treatment or plasma oxidation to improve interfacial bonding and dispersion of nanotubes in the epoxy matrix. CVD-grown MWCNTs with average diameter of 13 nm and length of 10 ?m, epoxy resin (YD 128) and hardener (TH 432) were used in the study. The CNTs...

  5. High Temperature Epoxy Nanocomposites for Aerospace Applications

    Science.gov (United States)

    2009-06-10

    epoxy-clay nanocomposites were prepared by dispersing imidazolium- modified clays in diglycidyl ether of bisphenol A ( DGEBA ) mixture by performing...functionalized anionic clay was vigorously mixed for 2h with difunctional epoxy resin ( DGEBA ) that contained small fraction of reactive diluent 1,4...the neat DGEBA resin to increase from ~300°C to ~330°C in the 2 wt% NLDH nanocomposite at 10°C/min heating rate, while it increases from ~305°C in

  6. Kevlar 49/Epoxy COPV Aging Evaluation

    Science.gov (United States)

    Sutter, James K.; Salem, Jonathan L.; Thesken, John C.; Russell, Richard W.; Littell, Justin; Ruggeri, Charles; Leifeste, Mark R.

    2008-01-01

    NASA initiated an effort to determine if the aging of Kevlar 49/Epoxy composite overwrapped pressure vessels (COPV) affected their performance. This study briefly reviews the history and certification of composite pressure vessels employed on NASA Orbiters. Tests to evaluate overwrap tensile strength changes compared 30 year old samples from Orbiter vessels to new Kevlar/Epoxy pressure vessel materials. Other tests include transverse compression and thermal analyses (glass transition and moduli). Results from these tests do not indicate a noticeable effect due to aging of the overwrap materials.

  7. Luminous Efficient Compositions Based on Epoxy Resin

    Directory of Open Access Journals (Sweden)

    R.S. Palaiah

    2006-07-01

    Full Text Available Magnesium/sodium nitrate illuminating compositions with epoxy resin - E 605 have beenstudied for luminosity and luminous efficiency by varying fuel oxidizer ratio and binder content.The compositions have been evaluated for impact and friction sensitivities, burn rate, thermalcharacteristics, and mechanical properties. Flame temperature and combustion products areevaluated theoretically by using REAL program. Experimental results show that, luminosity,burn rate, and calorimetric value are higher for polyester resin-based compositions. The highluminous efficiency composition is achieved with magnesium/sodium nitrate ratio of 70/30 with4 per cent epoxy resin.

  8. Interphase tailoring in graphite-epoxy composites

    Science.gov (United States)

    Subramanian, R. V.; Sanadi, A. R.; Crasto, A. S.

    1988-01-01

    The fiber-matrix interphase in graphite fiber-epoxy matrix composites is presently modified through the electrodeposition of a coating of the polymer poly(styrene-comaleic anhydride), or 'SMA' on the graphite fibers; optimum conditions have been established for the achievement of the requisite thin, uniform coatings, as verified by SEM. A single-fiber composite test has shown the SMA coating to result in an interfacial shear strength to improve by 50 percent over commercially treated fibers without sacrifice in impact strength. It is suggested that the epoxy resin's superior penetration into the SMA interphase results in a tougher fiber/matrix interface which possesses intrinsic energy-absorbing mechanisms.

  9. Long-term creep-rupture failure envelope of epoxy

    Science.gov (United States)

    Melo, José Daniel D.; de Medeiros, Antonio M.

    2014-02-01

    An accelerated testing methodology based on the time-temperature superposition principle has been proposed in the literature for the long-term creep strength of polymer matrices and polymer composites. Also, it has been suggested that a standard master curve may be a feasible assumption to describe the creep behavior in both tension and compression modes. In the present research, strength master curves for an aerospace epoxy (8552) were generated for tension and compression, by shifting strength data measured at various temperatures. The shift function is obtained from superposition of creep-compliance curves obtained at different temperatures. A standard master curve was presented to describe the creep-rupture of the polymer under tension and compression. Moreover, long-term creep-rupture failure envelopes of the polymer were presented based on a two-part failure criterion for homogeneous and isotropic materials. Ultimately, the approach presented allows the prediction of creep-rupture failure envelopes for a time-dependent material based on tensile strengths measured at various temperatures, considering that the ratio between tensile and compressive strengths is known.

  10. New Classification Methods for Hiding Information into Two Parts: Multimedia Files and Non Multimedia Files

    CERN Document Server

    Alanazi, Hamdan O; Zaidan, B B; Jalab, Hamid A; AL-Ani, Zaidoon Kh

    2010-01-01

    With the rapid development of various multimedia technologies, more and more multimedia data are generated and transmitted in the medical, commercial, and military fields, which may include some sensitive information which should not be accessed by or can only be partially exposed to the general users. Therefore, security and privacy has become an important, Another problem with digital document and video is that undetectable modifications can be made with very simple and widely available equipment, which put the digital material for evidential purposes under question .With the large flood of information and the development of the digital format Information hiding considers one of the techniques which used to protect the important information. The main goals for this paper, provides a general overview of the New Classification Methods for Hiding Information into Two Parts: Multimedia Files and Non Multimedia Files.

  11. Characterization of Epoxy Functionalized Graphite Nanoparticles and the Physical Properties of Epoxy Matrix Nanocomposites

    Science.gov (United States)

    Miller, Sandi G.; Bauer, Jonathan L.; Maryanski, Michael J.; Heimann, Paula J.; Barlow, Jeremy P.; Gosau, Jan-Michael; Allred, Ronald E.

    2010-01-01

    This work presents a novel approach to the functionalization of graphite nanoparticles. The technique provides a mechanism for covalent bonding between the filler and matrix, with minimal disruption to the sp2 hybridization of the pristine graphene sheet. Functionalization proceeded by covalently bonding an epoxy monomer to the surface of expanded graphite, via a coupling agent, such that the epoxy concentration was measured as approximately 4 wt.%. The impact of dispersing this material into an epoxy resin was evaluated with respect to the mechanical properties and electrical conductivity of the graphite-epoxy nanocomposite. At a loading as low as 0.5 wt.%, the electrical conductivity was increased by five orders of magnitude relative to the base resin. The material yield strength was increased by 30% and Young s modulus by 50%. These results were realized without compromise to the resin toughness.

  12. Dynamic Response of Composite Structures Underwater

    Science.gov (United States)

    2013-09-01

    The material properties included: Density = 2000 kg/m3, Young’s modulus = 20x109 Pa , and Poisson’s ratio = 0.3. Once the beam was modeled, water...Hardener toughened laminating epoxy. [Online]. Available: http://www.prosetepoxy.com/PDF/Custom/M1002- 237.pdf. 46 THIS PAGE INTENTIONALLY LEFT

  13. Effect of Liquid-Crystalline Epoxy Backbone Structure on Thermal Conductivity of Epoxy-Alumina Composites

    Science.gov (United States)

    Giang, Thanhkieu; Kim, Jinhwan

    2017-01-01

    In a series of papers published recently, we clearly demonstrated that the most important factor governing the thermal conductivity of epoxy-Al2O3 composites is the backbone structure of the epoxy. In this study, three more epoxies based on diglycidyl ester-terminated liquid-crystalline epoxy (LCE) have been synthesized to draw conclusions regarding the effect of the epoxy backbone structure on the thermal conductivity of epoxy-alumina composites. The synthesized structures were characterized by proton nuclear magnetic resonance (1H-NMR) and Fourier-transform infrared (FT-IR) spectroscopy. Differential scanning calorimetry, thermogravimetric analysis, and optical microscopy were also employed to examine the thermal and optical properties of the synthesized LCEs and the cured composites. All three LCE resins exhibited typical liquid-crystalline behaviors: clear solid crystalline state below the melting temperature ( T m), sharp crystalline melting at T m, and transition to nematic phase above T m with consequent isotropic phase above the isotropic temperature ( T i). The LCE resins displayed distinct nematic liquid-crystalline phase over a wide temperature range and retained liquid-crystalline phase after curing, with high thermal conductivity of the resulting composite. The thermal conductivity values ranged from 3.09 W/m-K to 3.89 W/m-K for LCE-Al2O3 composites with 50 vol.% filler loading. The steric effect played a governing role in the difference. The neat epoxy resin thermal conductivity was obtained as 0.35 W/m-K to 0.49 W/m-K based on analysis using the Agari-Uno model. The results clearly support the objective of this study in that the thermal conductivity of the LCE-containing networks strongly depended on the epoxy backbone structure and the degree of ordering in the cured network.

  14. Underwater holography: past and future

    Science.gov (United States)

    Watson, John

    2006-05-01

    100 m and over 300 holograms recorded. However, the HoloMar camera is physically large and heavy and difficult to deploy. It is also based on the use of photographic emulsions to record the holograms. To overcome some of these difficulties we are now developing a new holographic camera (eHoloCam) based on digital holography. In digital or "eHolography", a hologram is directly electronically recorded onto a CCD or CMOS sensor and then numerically reconstructed by simulation of the optical hologram reconstruction. The immediate advantages of this new camera are compactness, ease-of-use and speed of response, but at the expense of restricted off-axis recording angles and reduced recording volume. In this paper we describe both approaches, the use of holography for analysis of marine organisms and the results obtained in the field. We also describe recent work, using both photo and digital holography, to study the behaviour of sediments in river estuaries and outline future applications of underwater holography.

  15. Adhesion between coating layers based on epoxy and silicone

    DEFF Research Database (Denmark)

    Svendsen, Jacob R.; Kontogeorgis, Georgios; Kiil, Søren

    2007-01-01

    The adhesion between a silicon tie-coat and epoxy primers, used in marine coating systems, has been studied in this work. Six epoxy coatings (with varying chain lengths of the epoxy resins), some of which have shown problems with adhesion to the tie-coat during service life, have been considered....... The experimental investigation includes measurements of the surface tension of the tie-coat and the critical surface tensions of the epoxies, topographic investigation of the surfaces of cured epoxy coatings via atomic force microscopy (AFM), and pull-off tests for investigating the strength of adhesion...... to the silicon/epoxy systems. Calculations for determining the roughness factor of the six epoxy coatings (based on the AFM topographies) and the theoretical work of adhesion have been carried out. The coating surfaces are also characterized based on the van Oss-Good theory. Previous studies on the modulus...

  16. Thermal expansion and swelling of cured epoxy resin used in graphite/epoxy composite materials

    Science.gov (United States)

    Adamson, M. J.

    1980-01-01

    The paper presents results of experiments in which the thermal expansion and swelling behavior of an epoxy resin system and two graphite/epoxy composite systems exposed to water were measured. It was found that the cured epoxy resin swells by an amount slightly less than the volume of the absorbed water and that the swelling efficiency of the water varies with the moisture content of the polymer. Additionally, the thermal expansion of cured epoxy resin that is saturated with water is observed to be more than twice that of dry resin. Results also indicate that cured resin that is saturated with 7.1% water at 95 C will rapidly increase in moisture content to 8.5% when placed in 1 C water. The mechanism for this phenomenon, termed reverse thermal effect, is described in terms of a slightly modified free-volume theory in conjunction with the theory of polar molecule interaction. Nearly identical behavior was observed in two graphite/epoxy composite systems, thus establishing that this behavior may be common to all cured epoxy resins.

  17. Development and characterization of epoxy syntactic foam filled with epoxy hollow spheres

    Directory of Open Access Journals (Sweden)

    2011-07-01

    Full Text Available The present study focuses on the development and characterization of epoxy syntactic foam filled with epoxy hollow spheres (ESF/EHoS. The epoxy syntactic foam (ESF was produced by embedding epoxy hollow spheres (EHoS into a mixture of epoxy-hardener and 3% KOH solution. An innovative approach and simple procedure was implemented in the preparation of the EHoS where expanded polystyrene (EPS beads were used as initiation material. The EPS beads were coated with the epoxy resin and these coated EPS beads were later cured and post-cured at high temperature which will also shrink the EPS beads thus producing a hollow structure. The physical and compressive properties of the developed ESF were characterized. The progressive collapse of the syntactic foam was monitored in real-time with respect to percentage of strain during a compression test. Results also indicated that the (ESF/EHoS showed similar deformation pattern with other types of syntactic foams which exhibited the common three regions of deformations.

  18. Synthesis and application of epoxy starch derivatives

    NARCIS (Netherlands)

    Huijbrechts, A.M.L.; Haar, ter R.; Schols, H.A.; Franssen, M.C.R.; Boeriu, C.G.; Sudhölter, E.J.R.

    2010-01-01

    Epoxy starch derivatives were synthesized by epoxidation of allylated starch. The reaction was performed with low substituted 1-allyloxy-2-hydroxypropyl-waxy maize starch (AHP-WMS; degree of substitution (DS) of 0.23) using hydrogen peroxide and acetonitrile Via a two step spectrophotometric assay,

  19. Synthesis and application of epoxy starch derivatives

    NARCIS (Netherlands)

    Huijbrechts, A.M.L.; Haar, ter R.; Schols, H.A.; Franssen, M.C.R.; Boeriu, C.G.; Sudhölter, E.J.R.

    2010-01-01

    Epoxy starch derivatives were synthesized by epoxidation of allylated starch. The reaction was performed with low substituted 1-allyloxy-2-hydroxypropyl-waxy maize starch (AHP-WMS; degree of substitution (DS) of 0.23) using hydrogen peroxide and acetonitrile Via a two step spectrophotometric assay,

  20. Epoxy adhesive plays crucial role at CERN

    CERN Multimedia

    2006-01-01

    "Epoxy adhesives are set to play a vital role in Europe's biggest-ever scientific experiment at the European Centre for Nuclear Research (CERN) in Geneva, Switzerland, thereby helping scientists gain a better understanding of the origins of the universe." (1 page)

  1. Epoxy adhesive plays crucial role at CERN

    CERN Multimedia

    2007-01-01

    "Epoxy adhesives are set to play a vital role in Europe's biggest-ever scientific experiment at the European Centrefor Nuclear Research (CERN) in Geneva, Switzerland, thereby helping scientists gain a better understanding of the origins of the universe." (1/2 page)

  2. Trajectory Simulation for Underwater Vehicle with Power-Lunched

    Institute of Scientific and Technical Information of China (English)

    Chaoqian Chen; Wei Cao; Cong Wang∗and Yingjie Wei

    2016-01-01

    The motion of combustion gas bubble produced by underwater ignition was developed based on Rayleigh⁃Plesset equation. Combining the bubble motion equation with the underwater launched vehicle motion equation in the longitudinal plane, a trajectory simulation model with power⁃launched was established. The hydrodynamic characteristics of underwater ignition at different depths and the trajectory analysis of the underwater vehicle with power⁃launched were given by simulation. The simulation results have a good agreement with experimental results, and show that the thrust peak caused by underwater ignition and the stable thrust both decrease slightly with the increase of the water depth, and the thrust peak will decline obviously by enlarging the initial radius of gas bubble; the thrust peak generated at the instant of ignition and the low⁃frequency oscillation of the stable thrust have no significant influence on the trajectory of underwater vehicle.

  3. Survey on Routing Protocols for Underwater Sensor Networks

    Directory of Open Access Journals (Sweden)

    Aman Sharma

    2012-02-01

    Full Text Available Different routing protocol perform different role in the underwater sensor network. All routing perform each and specific task into underwater sensor network which responsible for networking problems issue that is why this is the latest way of research. Routing term derived from “route” that means a path a way that perform different terms in underwater sensor network problem related issue. The best part is today many routing protocol are present in the underwater wireless sensor network. Some different attributes comes underwater wireless sensor network like likes high bit error rates, limited band-width, 3D deployment and high propagation delay. This paper is referring to as helpful for giving brief overview about each and every protocol and responsible for entire underwater wireless sensor network

  4. HYDRODYNAMIC BEHAVIOR OF AN UNDERWATER MOVING BODY AFTER WATER ENTRY

    Institute of Scientific and Technical Information of China (English)

    施红辉; 高见卓也

    2001-01-01

    An experimental study was conducted to investigate the vater entry phenomenon. A facility was designed to carry out the tests with the entry velocities of around 352 m/s. Visualization, pressure measurement, velocity measurement and underwater impact test were performed to investigate the hydroballistic behavior of the underwater moving body, the underwater flow field, the supercavitation,etc.. This study shows that the motion of a high-speed underwater body is strongly three-dimensional and chaotic. Furthermore, it is found that the distribution of the trajectory deflection of the underwater projectile depends on the depth of water. It is also found by measuring the deformation on a witness plate submerged in water,that the impact energy of an underwater projectile is reduced as it penetrates deeper into vater.

  5. Delay Tolerance in Underwater Wireless Communications: A Routing Perspective

    Directory of Open Access Journals (Sweden)

    Safdar Hussain Bouk

    2016-01-01

    Full Text Available Similar to terrestrial networks, underwater wireless networks (UWNs also aid several critical tasks including coastal surveillance, underwater pollution detection, and other maritime applications. Currently, once underwater sensor nodes are deployed at different levels of the sea, it is nearly impossible or very expensive to reconfigure the hardware, for example, battery. Taking this issue into account, considerable amount of research has been carried out to ensure minimum energy costs and reliable communication between underwater nodes and base stations. As a result, several different network protocols were proposed for UWN, including MAC, PHY, transport, and routing. Recently, a new paradigm was introduced claiming that the intermittent nature of acoustic channel and signal resulted in designing delay tolerant routing schemes for the UWN, known as an underwater delay tolerant network. In this paper, we provide a comprehensive survey of underwater routing protocols with emphasis on the limitations, challenges, and future open issues in the context of delay tolerant network routing.

  6. Efficient Motion Planning and Control for Underwater Gliders

    OpenAIRE

    Mahmoudian, Nina

    2009-01-01

    Underwater gliders are highly efficient, winged autonomous underwater vehicles that propel themselves by modifying their buoyancy and their center of mass. The center of mass is controlled by a set of servo-actuators which move one or more internal masses relative to the vehicle's frame. Underwater gliders are so efficient because they spend most of their time in stable, steady motion, expending control energy only when changing their equilibrium state. Motion control thus reduces to varyin...

  7. Optimal Sensor Layouts in Underwater Locomotory Systems

    Science.gov (United States)

    Colvert, Brendan; Kanso, Eva

    2015-11-01

    Retrieving and understanding global flow characteristics from local sensory measurements is a challenging but extremely relevant problem in fields such as defense, robotics, and biomimetics. It is an inverse problem in that the goal is to translate local information into global flow properties. In this talk we present techniques for optimization of sensory layouts within the context of an idealized underwater locomotory system. Using techniques from fluid mechanics and control theory, we show that, under certain conditions, local measurements can inform the submerged body about its orientation relative to the ambient flow, and allow it to recognize local properties of shear flows. We conclude by commenting on the relevance of these findings to underwater navigation in engineered systems and live organisms.

  8. Ocean Research Enabled by Underwater Gliders

    Science.gov (United States)

    Rudnick, Daniel L.

    2016-01-01

    Underwater gliders are autonomous underwater vehicles that profile vertically by changing their buoyancy and use wings to move horizontally. Gliders are useful for sustained observation at relatively fine horizontal scales, especially to connect the coastal and open ocean. In this review, research topics are grouped by time and length scales. Large-scale topics addressed include the eastern and western boundary currents and the regional effects of climate variability. The accessibility of horizontal length scales of order 1 km allows investigation of mesoscale and submesoscale features such as fronts and eddies. Because the submesoscales dominate vertical fluxes in the ocean, gliders have found application in studies of biogeochemical processes. At the finest scales, gliders have been used to measure internal waves and turbulent dissipation. The review summarizes gliders' achievements to date and assesses their future in ocean observation.

  9. Detecting underwater improvised explosive threats (DUIET)

    Science.gov (United States)

    Feeley, Terry

    2010-04-01

    Improvised Explosive Devices (IEDs) have presented a major threat in the wars in Afghanistan and Iraq. These devices are powerful homemade land mines that can be small and easily hidden near roadsides. They are then remotely detonated when Coalition Forces pass by either singly or in convoys. Their rapid detection, classification and destruction is key to the safety of troops in the area. These land based bombs will have an analogue in the underwater theater especially in ports, lakes, rivers and streams. These devices may be used against Americans on American soil as an element of the global war on terrorism (GWOT) Rapid detection and classification of underwater improvised explosive devices (UIED) is critical to protecting innocent lives and maintaining the day to day flow of commerce. This paper will discuss a strategy and tool set to deal with this potential threat.

  10. Signal processing for high speed underwater acoustic transmission of image

    Institute of Scientific and Technical Information of China (English)

    ZHU Weiqing; ZHU Min; WANG Junwei; HUANG Haiyun; YANG Bo; XU Lijun; ZHAO Liang

    2009-01-01

    A signal processing method for high-speed underwater acoustic transmission of image is presented. It has two parts. Part 1 introduces signal processing for underwater acoustic coherent communication. Part 1 includes 3 technical points. (1) Doppler shift compensation.Chirp signals are inserted between data packages. A correlation process between two copy correlation functions gives more accurate estimation of the mean Doppler shift. Then it could be compensated by resampling the data. In adaptive decision feedback equalizer (DFE) an adaptive phase compensator with fast self-optimized least mean square (FOLMS) adaptation algorithm is utilized resulting in better motion tolerance than compensators with 2nd order Phase-Lock Loop algorithm. The performance of the combination of mean Doppler shift compensation and adaptive phase compensator is quite good. (2) A diversity combiner (DC) used in advance of equalizer. Both combiner and adaptive DFE are based on FOLMS adaptation algorithm. This results in reduced computation complexity and better performance. (3) Cascaded equalizer and Turbo-Trellis Coded Modulation (TCM) decoder and the iteration algorithm. A new bitsymbol converter based on Soft Output Viterbi Algorithm (SOVA) is studied. Comparing with the traditional decision, coding and mapping algorithm, the new converter can reduce Bit Error Rate(BER) by nearly 2 orders. Part 2 is mainly around a robust image compression algorithm. Based on Discrete wavelet transform and fixed length coding, a robust compression algorithm for acoustic image is studied. The algorithm includes 4 technical points. (1) Utilizes CDF9/7 wavelet bases to transform the images. (2) Analyses the energy distribution of subband coefficients. Suitable transformation layer number is 3. (3) Applies different quantization steps to different subbands in accordance with their energy distribution. (4) Uses fixed length coding to prevent error propagation. The results show the algorithm achieves a balance

  11. 76 FR 52734 - Underwater Locating Devices (Acoustic) (Self-Powered)

    Science.gov (United States)

    2011-08-23

    ... Brazilian authorities but the flight data recorder and cockpit voice recorder were not recovered until April... for underwater locator beacons installed on flight recorders on airplanes performing public...

  12. Calibration Techniques for Accurate Measurements by Underwater Camera Systems

    Directory of Open Access Journals (Sweden)

    Mark Shortis

    2015-12-01

    Full Text Available Calibration of a camera system is essential to ensure that image measurements result in accurate estimates of locations and dimensions within the object space. In the underwater environment, the calibration must implicitly or explicitly model and compensate for the refractive effects of waterproof housings and the water medium. This paper reviews the different approaches to the calibration of underwater camera systems in theoretical and practical terms. The accuracy, reliability, validation and stability of underwater camera system calibration are also discussed. Samples of results from published reports are provided to demonstrate the range of possible accuracies for the measurements produced by underwater camera systems.

  13. Calibration Techniques for Accurate Measurements by Underwater Camera Systems.

    Science.gov (United States)

    Shortis, Mark

    2015-12-07

    Calibration of a camera system is essential to ensure that image measurements result in accurate estimates of locations and dimensions within the object space. In the underwater environment, the calibration must implicitly or explicitly model and compensate for the refractive effects of waterproof housings and the water medium. This paper reviews the different approaches to the calibration of underwater camera systems in theoretical and practical terms. The accuracy, reliability, validation and stability of underwater camera system calibration are also discussed. Samples of results from published reports are provided to demonstrate the range of possible accuracies for the measurements produced by underwater camera systems.

  14. Tethered Antennas for Unmanned Underwater Vehicles

    Science.gov (United States)

    2009-04-27

    Concepts The first design (Figure 1) was based on the concept of an airfoil kite. The shape of the tow body was built around a NACA5515 hydrofoil to...Underwater Vehicles Brooke Ocean Technology (USA) Inc. 6 Figure 1: Hydrofoil Design The second design was based on that of a boat hull...communications. A sharp bow was utilized to cut through the water to reduce drag when on the surface. Like the hydrofoil design the top profile was

  15. Underwater bipedal locomotion by octopuses in disguise.

    Science.gov (United States)

    Huffard, Christine L; Boneka, Farnis; Full, Robert J

    2005-03-25

    Here we report bipedal movement with a hydrostatic skeleton. Two species of octopus walk on two alternating arms using a rolling gait and appear to use the remaining six arms for camouflage. Octopus marginatus resembles a coconut, and Octopus (Abdopus) aculeatus, a clump of floating algae. Using underwater video, we analyzed the kinematics of their strides. Each arm was on the sand for more than half of the stride, qualifying this behavior as a form of walking.

  16. Optical Magnetometry for Detecting Underwater Objects

    Science.gov (United States)

    2015-09-21

    the underwater object itself (Faraday effect). An analytical expression is obtained for the polarization-rotated field when the incident plane wave...itself (Faraday effect). An analytical expression is obtained for the polarization-rotated field when the incident plane wave is at arbitrary angle...polarization-rotated field on the incident wave vector’s orientation for a specific geometry ( 0 , 0B B yE    ). We find that no choice of

  17. Navigation of an underwater industrial autonomous vehicle

    Energy Technology Data Exchange (ETDEWEB)

    Korotchentsev, V.I.; Rozenbaum, A.N.; Deshner, A.I. [Rossijskaya Akademiya Nauk, Vladivostok (Russian Federation). Inst. Avtomatiki i Protsessov Upravleniya

    2000-07-01

    This paper suggests a new approach to solving the problem of navigation of an underwater vehicle using arbitrary seafloor relief data. The known methods of building seafloor acoustic maps are not effective for correction of coordinates in areas of smooth relief and in shallow water. The suggested algorithm allows making maps using acoustic sectional view of the seafloor layers. The sectional view is of various forms in different areas of the smooth relief. (orig.)

  18. Underwater sensor networks: applications, advances and challenges.

    Science.gov (United States)

    Heidemann, John; Stojanovic, Milica; Zorzi, Michele

    2012-01-13

    This paper examines the main approaches and challenges in the design and implementation of underwater wireless sensor networks. We summarize key applications and the main phenomena related to acoustic propagation, and discuss how they affect the design and operation of communication systems and networking protocols at various layers. We also provide an overview of communications hardware, testbeds and simulation tools available to the research community.

  19. Underwater Imaging with a Moving Acoustic Lens

    Science.gov (United States)

    1998-01-01

    10.00  1998 IEEE Authorized licensed use limited to: NRL. Downloaded on December 1, 2009 at 15:29 from IEEE Xplore . Restrictions apply. Report...licensed use limited to: NRL. Downloaded on December 1, 2009 at 15:29 from IEEE Xplore . Restrictions apply. KAMGAR-PARSI et al.: UNDERWATER IMAGING 93...use limited to: NRL. Downloaded on December 1, 2009 at 15:29 from IEEE Xplore . Restrictions apply. 94 IEEE TRANSACTIONS ON IMAGE PROCESSING, VOL. 7

  20. Experiments with Underwater Robot Localization and Tracking

    OpenAIRE

    Corke, Peter; Detwiler, Carrick; Dunbabin, Matthew; Hamilton, Michael; Rus, Daniela; Vasilescu, Iuliu

    2007-01-01

    This paper describes a novel experiment in which two very different methods of underwater robot localization are compared. The first method is based on a geometric approach in which a mobile node moves within a field of static nodes, and all nodes are capable of estimating the range to their neighbours acoustically. The second method uses visual odometry, from stereo cameras, by integrating scaled optical flow. The fundamental algorithmic principles of each localization technique is described...

  1. Inspecting the inside of underwater hull

    Science.gov (United States)

    Valkovic, Vladivoj; Sudac, Davorin

    2009-05-01

    In order to demonstrate the possibility of identifying the material within ship's underwater hull, sunken ships and other objects on the sea floor tests with the 14 MeV sealed tube neutron generator incorporated inside a small submarine submerged in the test basin filled with sea water have been performed. Results obtained for inspection of diesel fuel and explosive presence behind single and double hull constructions are presented.

  2. Optimal design of stiffened composite underwater hulls

    OpenAIRE

    Messager, Tanguy; Chauchot, Pierre; Bigourdan, Benoit

    2006-01-01

    This numerical study deals with the stiffened composite underwater vessel design. The structures under investigation are laminated cylinders with rigid end-closures and inter-nal circumferential and longitudinal unidirectional composite stiffeners. Structural buckling induced by the high external hydrostatic pressure is considered as the major failure risk. An optimization design tool has been developed to obtain the reinforcement definition which maximizes the limit of stability: an analytic...

  3. Modeling and Control of Underwater Robotic Systems

    Energy Technology Data Exchange (ETDEWEB)

    Schjoelberg, I:

    1996-12-31

    This doctoral thesis describes modeling and control of underwater vehicle-manipulator systems. The thesis also presents a model and a control scheme for a system consisting of a surface vessel connected to an underwater robotic system by means of a slender marine structure. The equations of motion of the underwater vehicle and manipulator are described and the system kinematics and properties presented. Feedback linearization technique is applied to the system and evaluated through a simulation study. Passivity-based controllers for vehicle and manipulator control are presented. Stability of the closed loop system is proved and simulation results are given. The equation of motion for lateral motion of a cable/riser system connected to a surface vessel at the top end and to a thruster at the bottom end is described and stability analysis and simulations are presented. The equations of motion in 3 degrees of freedom of the cable/riser, surface vessel and robotic system are given. Stability analysis of the total system with PD-controllers is presented. 47 refs., 32 figs., 7 tabs.

  4. Underwater Noise Modelling of Wave Energy Devices

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    Future large-scale implementation of wave energy converts (WECs) will introduce an anthropogenic activity in the ocean which may contribute to underwater noise. The Ocean houses several marine species with acoustic sensibility; consequently the potential impact of the underwater noise needs to be addressed. At present, there are no acoustic impact studies based on acquired data. The WEAM project (Wave Energy Acoustic Monitoring) aims at developing an underwater noise monitoring plan for WECs. The development of an acoustic monitoring plan must consider the sound propagation in the ocean, identify noise sources, understand the operational characteristics and select adequate instrumentation. Any monitoring strategy must involve in-situ measurements. However, the vast distances which sound travels within the ocean, can make in-situ measurements covering the entire area of interest, impracticable. This difficulty can be partially overcome through acoustic numerical modelling. This paper presents a synthetic study, on the application of acoustic forward modelling and the evaluation of the impact of noise produced by wave energy devices on marine mammals using criteria based on audiograms of dolphins, or other species. The idea is to illustrate the application of that methodology, and to show to what extent it allows for estimating distances of impacts due to acoustic noise.

  5. Lifetime Prolonging Algorithms for Underwater Sensor Networks

    Institute of Scientific and Technical Information of China (English)

    GUO Zhong-wen; LI Zhi-wei; YU Lei

    2006-01-01

    Underwater acoustic modem technology has attained a level of maturity to support underwater acoustic sensor networks (UASNs) which are generally formed by acoustically connected sensor nodes and a surface station providing a link to an on-shore control center. While many applications require long-term monitoring of the deployment area, the battery-powered network nodes limit the lifetime of UASNs. Therefore, designing a UASN that minimizes the power consumption while maximizing lifetime becomes a very difficult task. In this paper, a method is proposed to determine the optimum number of clusters through combining an application-specific protocol architecture and underwater acoustic communication model so as to reduce the energy dissipation of UASNs. Deploying more sensor nodes which work alternately is another way to prolong the lifetime of UASNs. An algorithm is presented for selecting sensor nodes and putting them into operation in each round, ensuring the monitoring to the whole given area. The present results show that the algorithm can help prolong system lifetime remarkably when it is applied to other conventional approaches for sensor networks under the condition that the sensor node density is high.

  6. Modification of (DGEBA epoxy resin with maleated depolymerised natural rubber

    Directory of Open Access Journals (Sweden)

    2008-04-01

    Full Text Available In this work, diglycidyl ether of bisphenol A (DEGBA type epoxy resin has been modified with maleated depolymerised natural rubber (MDPR. MDPR was prepared by grafting maleic anhydride onto depolymerised natural rubber. MDPR has been characterized by Fourier transform infrared (FT-IR spectroscopy and nuclear magnetic resonance spectroscopy. MDPR was blended with epoxy resin at three different ratios (97/3, 98/2 and 99/1, by keeping the epoxy resin component as the major phase and maleated depolymerised natural rubber component as the minor phase. The reaction between the two blend components took place between the acid/anhydride group in the MDPR and the epoxide group of the epoxy resin. The proposed reaction schemes were supported by the FT-IR spectrum of the uncured Epoxy/MDPR blends. The neat epoxy resin and Epoxy/MDPR blends were cured by methylene dianiline (DDM at 100°C for three hours. Thermal, morphological and mechanical properties of the neat epoxy and the blends were investigated. Free volume studies of the cured, neat epoxy and Epoxy/MDPR blends were correlated with the morphological and mechanical properties of the same systems using Positron Annihilation Lifetime Studies.

  7. Contact allergy to epoxy resin: risk occupations and consequences.

    Science.gov (United States)

    Bangsgaard, Nannie; Thyssen, Jacob Pontoppidan; Menné, Torkil; Andersen, Klaus Ejner; Mortz, Charlotte G; Paulsen, Evy; Sommerlund, Mette; Veien, Niels Kren; Laurberg, Grete; Kaaber, Knud; Thormann, Jens; Andersen, Bo Lasthein; Danielsen, Anne; Avnstorp, Christian; Kristensen, Berit; Kristensen, Ove; Vissing, Susanne; Nielsen, Niels Henrik; Johansen, Jeanne Duus

    2012-08-01

    Epoxy resin monomers are strong skin sensitizers that are widely used in industrial sectors. In Denmark, the law stipulates that workers must undergo a course on safe handling of epoxy resins prior to occupational exposure, but the effectiveness of this initiative is largely unknown. To evaluate the prevalence of contact allergy to epoxy resin monomer (diglycidyl ether of bisphenol A; MW 340) among patients with suspected contact dermatitis and relate this to occupation and work-related consequences. The dataset comprised 20 808 consecutive dermatitis patients patch tested during 2005-2009. All patients with an epoxy resin-positive patch test were sent a questionnaire. A positive patch test reaction to epoxy resin was found in 275 patients (1.3%), with a higher proportion in men (1.9%) than in women (1.0%). The prevalence of sensitization to epoxy resin remained stable over the study period. Of the patients with an epoxy resin-positive patch test, 71% returned a questionnaire; 95 patients had worked with epoxy resin in the occupational setting, and, of these, one-third did not use protective gloves and only 50.5% (48) had participated in an educational programme. The 1% prevalence of epoxy resin contact allergy is equivalent to reports from other countries. The high occurrence of epoxy resin exposure at work, and the limited use of protective measures, indicate that reinforcement of the law is required. © 2012 John Wiley & Sons A/S.

  8. On the Effects of Frequency Scaling Over Capacity Scaling in Underwater Networks—Part I

    DEFF Research Database (Denmark)

    Shin, Won-Yong; Roetter, Daniel Enrique Lucani; Médard, Muriel

    2013-01-01

    In this two-part paper, information-theoretic capacity scaling laws are analyzed in an underwater acoustic network with n regularly located nodes on a square, in which both bandwidth and received signal power can be limited significantly. Parts I and II deal with an extended network of unit node...... parameter that depends on the frequency scaling as well as the transmission distance. Upper and lower bounds on the capacity scaling are then derived. In Part I, we show that the upper bound on capacity for extended networks is inversely proportional to the attenuation parameter, thus resulting in a highly...... power-limited network. Interestingly, it is shown that the upper bound is intrinsically related to the attenuation parameter but not the spreading factor. Furthermore, we propose an achievable communication scheme based on the nearest-neighbor MH transmission, which is suitable due to the low...

  9. On the Effects of Frequency Scaling over Capacity Scaling in Underwater Networks

    DEFF Research Database (Denmark)

    Shin, Won-Yong; Roetter, Daniel Enrique Lucani; Médard, Muriel

    2013-01-01

    This is the second in a two-part series of papers on information-theoretic capacity scaling laws for an underwater acoustic network. Part II focuses on a dense network scenario, where nodes are deployed in a unit area. By deriving a cut-set upper bound on the capacity scaling, we first show......) transmission is presented for dense networks. MH is shown to guarantee the order optimality under certain operating regimes. More specifically, it turns out that scaling the carrier frequency faster than or as is instrumental towards achieving the order optimality of the MH protocol....... that there exists either a bandwidth or power limitation, or both, according to the operating regimes (i.e., path-loss attenuation regimes), thus yielding the upper bound that follows three fundamentally different information transfer arguments. In addition, an achievability result based on the multi-hop (MH...

  10. EPOXY RESINS TOUGHENED WITH CARBOXYL TERMINATED POLYETHERS

    Institute of Scientific and Technical Information of China (English)

    YU Yunchao; LI Yiming

    1983-01-01

    Carboxyl terminated polyethers, the adducts of hydroxyl terminated polytetrahydrofuran and maleic anhydride, were used as toughener for epoxy resins. The morphology of the toughened resins was investigated by means of turbidity measurement, dynamic mechanical testing and scanning electron microscope observation. It turned out that the molecular weight and the carboxyl content of the polyether and the cure conditions are important factors, which affect the particle size of the polyether-rich domains and, in turn, the mechanical properties of the cured resin. Carboxyl terminated polytetrahydrofurans have a low glass transition temperature, and in appropriate amount they do not affect the thermal resistance of the resin. These advantages make them preferable as toughener for epoxy resins.

  11. Cycloaliphatic epoxy resin coating for capillary electrophoresis.

    Science.gov (United States)

    Shah, Roopa S; Wang, Qinggang; Lee, Milton L

    2002-04-05

    Coating the interior surface of a fused-silica capillary with a polymeric material has long been used in capillary electrophoresis (CE) to reduce or eliminate electroosmotic flow and suppress adsorption. A cycloaliphatic epoxide-based resin was bonded to silane treated capillaries and crosslinked with a curing agent. The epoxy resin coating significantly reduced electroosmotic flow over a pH range of 3-10. This coating was sufficiently hydrophilic to suppress protein adsorption. The epoxy resin coated capillary was used to separate several acidic and basic proteins and peptides. Separation efficiencies greater than 400,000 theoretical plates were achieved. The relative standard deviations in migration times for proteins were methods.

  12. Investigations of toughening mechanisms of epoxy resins

    Science.gov (United States)

    Koenig, T.

    1986-01-01

    Composite material technology was applied to the solid rocket booster by the development of a carbon filament-epoxy resin case which yields a net increase of 4000 lbs. in payload in the shuttle. The question of reusability of the new composite tanks has not yet been answered and will depend on the toughness of the matrix resin. The present study was aimed at providing conditions whereby test specimens of the epoxy resin (EPON/85) and curing agents of systematically varied structures could be produced in a controlled manner. Three sets of conditions were found that might allow the isolation of the structural effects on toughness from the cure effects. The kinetic methods leading to the determination of these conditions are described.

  13. Permeability measurement and control for epoxy composites

    Science.gov (United States)

    Chang, Tsun-Hsu; Tsai, Cheng-Hung; Wong, Wei-Syuan; Chen, Yen-Ren; Chao, Hsien-Wen

    2017-08-01

    The coupling of the electric and magnetic fields leads to a strong interplay in materials' permittivity and permeability. Here, we proposed a specially designed cavity, called the mu cavity. The mu cavity, consisting of a mushroom structure inside a cylindrical resonator, is exclusively sensitive to permeability, but not to permittivity. It decouples materials' electromagnetic properties and allows an accurate measurement of the permeability. With the help of an epsilon cavity, these two cavities jointly determine the complex permeability and permittivity of the materials at microwave frequencies. Homemade epoxy-based composite materials were prepared and tested. Measurement and manipulation of the permeability and permittivity of the epoxy composites will be shown. The results will be compared with the effective medium theories.

  14. Epoxy thermoset networks derived from vegetable oils and their blends

    Science.gov (United States)

    Ryu, Chang; Ravalli, Matthew

    2015-03-01

    Epoxidized vegetable oils (EVOs), such as epoxidized soybean oil and linseed oils were prepared by the partial oxidation of the unsaturated double bonds in vegetable oils and used as monomers for preparing epoxy thermoset materials based on the cationic polymerization. These EVOs have been used to prepare epoxy thermosets of different network densities by cationic polymerization using onium salt catalyst. The crosslinked epoxy thermosets provide an ideal platform to study the structure-property-relationships of networked polymers. In particular, rheological studies on the epoxidized vegetable oil thermosets have been performed to measure the molecular weights between crosslinks (Mx) in the epoxy thermosets and to ultimately elucidate the role of functionality of epoxy groups in EVO on the mechanical and thermophysical properties of the epoxy thermoset materials. NSF DMR POLYMERS 1308617.

  15. Biobased Epoxy Nanocomposites Derived from Lignin-Based Monomers.

    Science.gov (United States)

    Zhao, Shou; Abu-Omar, Mahdi M

    2015-07-13

    Biobased epoxy nanocomposites were synthesized based on 2-methoxy-4-propylphenol (dihydroeugenol, DHE), a molecule that has been obtained from the lignin component of biomass. To increase the content of hydroxyl groups, DHE was o-demethylated using aqueous HBr to yield propylcatechol (DHEO), which was subsequently glycidylated to epoxy monomer. Optimal conditions in terms of yield and epoxy equivalent weight were found to be 60 °C with equal NaOH/phenolic hydroxyl molar ratio. The structural evolution from DHE to cured epoxy was followed by (1)H NMR and Fourier transform infrared spectroscopy. The nano-montmorillonite modified DHEO epoxy exhibited improved storage modulus and thermal stability as determined from dynamic mechanical analysis and thermogravimetric analysis. This study widens the synthesis routes of biobased epoxy thermosets from lignin-based molecules.

  16. Rubber-Modified Epoxies: Transitions and Morphology.

    Science.gov (United States)

    1980-09-01

    temperatures used for cure (i.e. Tso > Tcure). A low molecular weight liquid diglycidyl ether of bisphenol A ( DGEBA ) epoxy resin, Epon 828, Shell Chemical Co...the rubber damping peak always occurs at or below the Tg of unreacted CTBN even though CTBN is capped with DGEBA (see Ref. 5 which also shows that the...depression of RTg decreases with increasing amounts of rubber modifier in the formulations). DGEBA and CTBN must be incorporated in the domains since

  17. Epoxy-based carbon nanotubes reinforced composites

    CSIR Research Space (South Africa)

    Kesavan Pillai, Sreejarani

    2011-04-01

    Full Text Available blocks for 24 h at 60?C. Low and high magnification transmission electron microscopy (TEM) images of the thin slices cut from the composite showed that the thinner and longer nanotubes were preferentially oriented along the cutting direction, though... in Epon 828 epoxy resin matrix. The composites were cured with triethylene tetraamine hardener by gelling overnight at room temperature (RT) and curing at 100?C for 2 h. The micro-structural analysis of the composite using scanning electron microscopy...

  18. Safe epoxy encapsulant for high voltage magnetics

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez, R.O.; Archer, W.E.

    1998-01-01

    This paper describes the use of Formula 456, an aliphatic amine cured epoxy for impregnating coils and high voltage transformers. Sandia has evaluated a number of MDA-free epoxy encapsulants which relied on either anhydride or other aromatic amine curing agents. The use of aliphatic amine curing agents was more recently evaluated and has resulted in the definition of Formula 456 resin. Methylene dianiline (MDA) has been used for more than 20 years as the curing agent for various epoxy formulations throughout the Department of Energy and much of industry. Sandia National Laboratories began the process of replacing MDA with other formulations because of regulations imposed by OSHA on the use of MDA. OSHA has regulated MDA because it is a suspect carcinogen. Typically the elimination of OSHA-regulated materials provides a rare opportunity to qualify new formulations in a range of demanding applications. It was important to take full advantage of that opportunity, although the associated materials qualification effort was costly. Small high voltage transformers are one of those demanding applications. The successful implementation of the new formulation for high reliability transformers will be described. The test results that demonstrate the parts are qualified for use in DOE weapon systems will be presented.

  19. Prediction of brittle fracture of epoxy-aluminum flanging

    Directory of Open Access Journals (Sweden)

    Korbel J.

    2010-07-01

    Full Text Available This paper presents a fracture mechanical approach for estimation of critical bending load of different types of aluminum-epoxy flanging and comparison with experimental measurements. For this purpose, several designs of the flanges were investigated. The flanges were glued to the epoxy bars and adhesive-epoxy interface was considered as a bi-material notch. Prediction of the failure is based on generalized stress intensity factor and generalized fracture toughness.

  20. Thermal properties of epoxy composites filled with boric acid

    OpenAIRE

    Visakh, P. M.; Nazarenko, Olga Bronislavovna; Amelkovich, Yuliya Alexandrovna; Melnikova, T. V.

    2015-01-01

    The thermal properties of epoxy composites filled with boric acid fine powder at different percentage were studied. Epoxy composites were prepared using epoxy resin ED-20, boric acid as flame-retardant filler, hexamethylenediamine as a curing agent. The prepared samples and starting materials were examined using methods of thermal analysis, scanning electron microscopy and infrared spectroscopy. It was found that the incorporation of boric acid fine powder enhances the thermal stability of ep...

  1. Multiscale Modeling of Graphite/CNT/Epoxy Hybrid Composites

    Science.gov (United States)

    2016-03-09

    AFRL-AFOSR-VA-TR-2016-0154 Multiscale Modeling of Graphite/CNT/Epoxy Hybrid Composites Gregory Odegard MICHIGAN TECHNOLOGICAL UNIVERSITY Final Report...SUBTITLE Multiscale Modeling of Graphite/CNT/Epoxy Hybrid Composites 5a. CONTRACT NUMBER 5b. GRANT NUMBER FA9550-13-1-0030 5c. PROGRAM ELEMENT NUMBER...DISTRIBUTION A: Distribution approved for public release. Final Report Multiscale Modeling of Graphite/CNT/Epoxy Hybrid Composites Grant FA9550-13-1-0030 PI

  2. Adding Effects of Reactive Oligomers for Epoxy Resin

    OpenAIRE

    山田, 英介; 稲垣, 慎二; 岡本, 弘

    1991-01-01

    Reactive oligomers with both functional end groups were prepared by the radical telomerization and the effect of oligomers added to bisphenol-A-glycidylehter type epoxy resin was investigated by measuring mechanical properties, adhesive properties and dynamic viscoelasticities. These oligomers were high viscous liquid except the one prepared from methyl methacrylate, therefore the blend of oligomers with epoxy resin is easy. Adding oligomers, the cured epoxy resins showed the lower glass-tran...

  3. Evaluation of epoxy for use on NuSTAR optics

    DEFF Research Database (Denmark)

    An, H.; Christensen, Finn Erland; Doll, M.

    2009-01-01

    The Nuclear Spectroscopic Telescope Array (NuSTAR) is a NASA Small Explorer (SMEX) mission which employs two focusing optics. The optics are composed of stacks of thin mirror shells and spacers. Epoxy is used to bond the mirror shells to the spacers and is a crucial component in determining...... the structural and optical performance of the telescopes. We describe the epoxy selection for NuSTAR optics, emphasizing those epoxy characteristics essential to obtaining good optical performance....

  4. Selective Clay Placement Within a Silicate-Clay Epoxy Blend Nanocomposite

    Science.gov (United States)

    Miller, Sandi G (Inventor)

    2013-01-01

    A clay-epoxy nanocomposite may be prepared by dispersing a layered clay in an alkoxy epoxy, such as a polypropylene oxide based epoxide before combining the mixture with an aromatic epoxy to improve the nanocomposite's thermal and mechanical properties.

  5. Rate dependent response and failure of a ductile epoxy and carbon fiber reinforced epoxy composite

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Eric N [Los Alamos National Laboratory; Rae, Philip J [Los Alamos National Laboratory; Dattelbaum, Dana M [Los Alamos National Laboratory; Stahl, David B [Los Alamos National Laboratory

    2010-01-01

    An extensive characterization suite has been performed on the response and failure of a ductile epoxy 55A and uniaxial carbon fiber reinforced epoxy composite of IM7 fibers in 55A resin from the quasistatic to shock regime. The quasistatic and intermediate strain rate response, including elastic modulus, yield and failure have are characterized by quasistatic, SHPB, and DMA measurements as a function of fiber orientation and temperature. The high strain rate shock effect of fiber orientation in the composite and response of the pure resin are presented for plate impact experiments. It has previously been shown that at lower impact velocities the shock velocity is strongly dependent on fiber orientation but at higher impact velocity the in-plane and through thickness Hugoniots converge. The current results are compared with previous studies of the shock response of carbon fiber composites with more conventional brittle epoxy matrices. The spall response of the composite is measured and compared with quasistatic fracture toughness measurements.

  6. Underwater shock response analysis of a floating vessel

    NARCIS (Netherlands)

    Aanhold, J.E. van; Meijer, G.J.; Lemmen, P.P.M.

    1998-01-01

    The response of a surface vessel to underwater shock has been calculated using an explicit finite element analysis. The analysis model is two-dimensional and contains the floating steel structure, a large surrounding water volume and the free surface. The underwater shock is applied in the form ot a

  7. Underwater communication. FOA-STU project 4: Maritime technology

    Science.gov (United States)

    Goetherstroem, L.; Kleman, B.; Lindquist, R.; Pentelius, T.

    1980-04-01

    Technological forecasts for underwater communication by acoustical, optical, or radio techniques are summarized. Results on transmission by the various means were evaluated under different hypotheses for the aqueous milieu. Technological possibilities, the need for underwater communications in assorted applications, and a practical assessment of the potential for realization are considered. Conclusions lead to a proposal for a series of development projects.

  8. Mexican Underwater Archaeology and Some of its Challenges and Solutions

    Directory of Open Access Journals (Sweden)

    Pilar Luna Erreguerena

    2013-10-01

    Full Text Available In response to Carver’s lead article, I’d like to highlight an easily overlooked aspect of archaeology: underwater archaeology. I will offer some examples and experiences from Mexico, which will perhaps resonate in other cities and nations around the world with a rich underwater cultural heritage.

  9. Underwater Acoustic Image Transmission System Based on DSP

    Institute of Scientific and Technical Information of China (English)

    Cheng En; Xu Ru

    2002-01-01

    The underwater acoustic image transmission system based on the high-speed DSP device TMS320C549 has been studied. We use Goertzel algorithm for source decoding and MFSK for modulation. Turbo code is used for channel coding and decoding. The purpose is to implement underwater video image data transmission.

  10. Preliminary OFDM based acoustic communication for underwater sensor networks synchronization

    OpenAIRE

    Pallarés Valls, Oriol; Sarriá Gandul, David; Viñolo Monzoncillo, Carlos; Río Fernandez, Joaquín del; Manuel Lázaro, Antonio

    2013-01-01

    This work presents a first approach to wireless underwater sensor networks UWSN time synchronization, using OFDM (Orthogonal Frequency Division Multiplexing) acoustic communication and time reference served by a synchronization protocol. This synchronization and type of modulation allows getting a low drift clock on each sensor, on a high efficiency underwater communication network. Peer Reviewed

  11. Remarks on the observability of single beacon underwater navigation

    DEFF Research Database (Denmark)

    Jouffroy, Jerome; Ross, Andrew

    This paper contributes a simple and intuitive result in the analysis of underwater navigation using a single ranging beacon. This analysis should help with the design of small and lightweight underwater vehicles by reducing the amount of instrumentation required for accurate navigation. The concept...

  12. The WODA guidance paper on underwater sound from dredging (abstract)

    NARCIS (Netherlands)

    Thomsen, F.; Borsani, F.; Clarke, D.; Jong, C.A.F. de; Witt, P. de; Holtkamp, M.; Goethals, F.; San Martin, E.; Spadaro, P.; Raalte, G. van; Jensen, A.

    2013-01-01

    The World Organisation of Dredging Associations (WODA) has identified underwater sound as an environmental issue that needs further consideration. A WODA Expert Group on Underwater Sound (WEGUS) was established to provide a guidance paper on dredging sound, impact on aquatic biota and advice on unde

  13. Characterization of ships as sources of underwater noise

    NARCIS (Netherlands)

    Jong, C.A.F.

    2009-01-01

    There is a growing interest in the possible impact of anthropogenic underwater noise on marine life [1]. One of the concerns is the increasing contribution of shipping noise, with the growing number and size of commercial ships. Traditionally, underwater radiated noise control was only of interest f

  14. Remarks on the observability of single beacon underwater navigation

    DEFF Research Database (Denmark)

    Jouffroy, Jerome; Ross, Andrew

    This paper contributes a simple and intuitive result in the analysis of underwater navigation using a single ranging beacon. This analysis should help with the design of small and lightweight underwater vehicles by reducing the amount of instrumentation required for accurate navigation. The concept...

  15. Underwater shock response analysis of a floating vessel

    NARCIS (Netherlands)

    Aanhold, J.E. van; Lemmen, P.P.M.

    1996-01-01

    The response of a surface vessel to underwater shock has been calculated using an explicit finite element analysis. The analysis model is two-dimensional and contains the floating steel structure, a large surrounding water volume and the free surface. The underwater shock is applied in the form of a

  16. Underwater reflectance transformation imaging: a technology for in situ underwater cultural heritage object-level recording

    Science.gov (United States)

    Selmo, David; Sturt, Fraser; Miles, James; Basford, Philip; Malzbender, Tom; Martinez, Kirk; Thompson, Charlie; Earl, Graeme; Bevan, George

    2017-01-01

    There is an increasing demand for high-resolution recording of in situ underwater cultural heritage. Reflectance transformation imaging (RTI) has a proven track record in terrestrial contexts for acquiring high-resolution diagnostic data at small scales. The research presented here documents the first adaptation of RTI protocols to the subaquatic environment, with a scuba-deployable method designed around affordable off-the-shelf technologies. Underwater RTI (URTI) was used to capture detail from historic shipwrecks in both the Solent and the western Mediterranean. Results show that URTI can capture submillimeter levels of qualitative diagnostic detail from in situ archaeological material. In addition, this paper presents the results of experiments to explore the impact of turbidity on URTI. For this purpose, a prototype fixed-lighting semisubmersible RTI photography dome was constructed to allow collection of data under controlled conditions. The signal-to-noise data generated reveals that the RGB channels of underwater digital images captured in progressive turbidity degraded faster than URTI object geometry calculated from them. URTI is shown to be capable of providing analytically useful object-level detail in conditions that would render ordinary underwater photography of limited use.

  17. Cobalt Ions Improve the Strength of Epoxy Resins

    Science.gov (United States)

    Stoakley, D. M.; St. Clair, A. K.

    1986-01-01

    Technique developed for improving mechanical strength of epoxy resins by adding cobalt ions in form of tris(acetylacetonato)cobalt (III) complex. Solid cast disks prepared from cobalt ion-containing epoxy resins tested for flexural strength and stiffness. Incorporation of cobalt ions into epoxies increased flexural strength of resins by 10 to 95 percent. Suitable resins for this technique include any liquid or solid TGMDA resins. Improved epoxy formulation proves useful as composite matrix resin, adhesive, or casting resin for applications on commercial and advanced aircraft.

  18. THE POLYMERIZATION OF ROOM TEMPERATURE CURING EPOXY RESINS

    Science.gov (United States)

    EPOXY RESINS , *PLASTICS, *POLYMERIZATION, AGING (PHYSIOLOGY), CHEMICAL BONDS, ELECTRICAL PROPERTIES, EMBEDDING SUBSTANCES, MONITORS, POLYMERS, RESISTANCE (ELECTRICAL), STORAGE, STRUCTURES, TEMPERATURE, TEST METHODS, VOLUME

  19. Persistent photosensitivity after allergic contact dermatitis to epoxy resin.

    Science.gov (United States)

    Kwok, Tiffany; Rosen, Cheryl F; Storrs, Frances J; Lobel, Edmund; DeKoven, Joel G

    2013-01-01

    Persistent photosensitivity after allergic contact dermatitis (ACD) to epoxy resin has rarely been described. The aim of this study was to create awareness that ACD to epoxy may be a trigger for persistent photosensitivity. We present a series of 5 patients who developed ACD to epoxy resin and later a photodistributed eczematous eruption when exposed to sunlight, with a documented decrease in minimal erythema dose to UVA and UVB. The age of patients ranged from 34 to 71 years, and there were 3 men and 2 women. Each patient had occupational exposure to epoxy. Symptoms of epoxy ACD preceded photosensitivity by 5 months to 12 years in 3 cases and occurred simultaneously in 2 cases. Patch testing to epoxy resin was positive in all patients. Phototesting revealed a decreased minimal erythema dose to UVA and UVB in each of the 3 patients who were phototested. Photopatch testing was positive for epoxy resin in 1 of the 2 patients tested. All patients remained photosensitive for at least 2 years after diagnosis, with only 1 case of photosensitivity resolving with extended avoidance of epoxy. There is an association between ACD to epoxy resin and development of persistent photosensitivity. Possible mechanisms to explain the relationship between the 2 phenomena are discussed.

  20. Effect of the hardener to epoxy monomer ratio on the water absorption behavior of the DGEBA/TETA epoxy system

    Directory of Open Access Journals (Sweden)

    Ayrton Alef Castanheira Pereira

    2016-02-01

    Full Text Available Abstract The water absorption behavior of the DGEBA/TETA epoxy system was evaluated as a function of the epoxy monomer to amine hardener ratio. Weight gain versus immersion time curves were obtained and the experimental points were fitted using Fickian and Non-Fickian diffusion models. The results obtained showed that for all epoxy monomer to hardener ratios analyzed water diffusion followed non-Fickian behavior. It was possible to correlate the water absorption behavior to the macromolecular structure developed when the epoxy/ hardener ratio was varied. All epoxy/hardener ratios present a two-phase macromolecular structure, composed of regions with high crosslink density and regions with lower crosslinking. Epoxy rich systems have a more open macromolecular structure with a lower fraction of the dense phase than the amine rich systems, which present a more compact two-phase structure.

  1. Underwater plasma discharge and its water treatment applications

    Science.gov (United States)

    Ma, Sukhwal; Huh, Jin Young; Kim, Kangil; Hong, Yong Cheol; National Fusion Research Institute Team; Chonbuk National University Team; Kwangwoon University Team; NPAC Team

    2016-09-01

    In recent, the quality of water has been exacerbated by the influx of wastewater and water pollutants. There have been frequent occurrences of water blooms due to the eutrophication of river. Therefore, the needs for water treatment are increased through effective and environment-friendly method. In this work, we propose the plasma system to overcome the problems mentioned above using underwater discharge plasma. The underwater discharges are generated by capillary electrode, and have the advantages of low cost, high efficiency and eco-friendly processing. The proposed technologies can be suitable for eliminating cyanobacteria, decreasing the concentration of oil dissolved in water, and purifying wastewater. Cyanobacteria is killed directly by the underwater discharge and water-dissolved oil and heavy-metal wastewater are purified by coagulation effect, which may result from the chemical reactions of underwater plasma. Consequently, these technologies using underwater discharge can be alternative methods to replace the existing technologies.

  2. On Modeling Eavesdropping Attacks in Underwater Acoustic Sensor Networks †

    Science.gov (United States)

    Wang, Qiu; Dai, Hong-Ning; Li, Xuran; Wang, Hao; Xiao, Hong

    2016-01-01

    The security and privacy of underwater acoustic sensor networks has received extensive attention recently due to the proliferation of underwater activities. This paper proposes an analytical model to investigate the eavesdropping attacks in underwater acoustic sensor networks. Our analytical framework considers the impacts of various underwater acoustic channel conditions (such as the acoustic signal frequency, spreading factor and wind speed) and different hydrophones (isotropic hydrophones and array hydrophones) in terms of network nodes and eavesdroppers. We also conduct extensive simulations to evaluate the effectiveness and the accuracy of our proposed model. Empirical results show that our proposed model is quite accurate. In addition, our results also imply that the eavesdropping probability heavily depends on both the underwater acoustic channel conditions and the features of hydrophones. PMID:27213379

  3. On Modeling Eavesdropping Attacks in Underwater Acoustic Sensor Networks.

    Science.gov (United States)

    Wang, Qiu; Dai, Hong-Ning; Li, Xuran; Wang, Hao; Xiao, Hong

    2016-01-01

    The security and privacy of underwater acoustic sensor networks has received extensive attention recently due to the proliferation of underwater activities. This paper proposes an analytical model to investigate the eavesdropping attacks in underwater acoustic sensor networks. Our analytical framework considers the impacts of various underwater acoustic channel conditions (such as the acoustic signal frequency, spreading factor and wind speed) and different hydrophones (isotropic hydrophones and array hydrophones) in terms of network nodes and eavesdroppers. We also conduct extensive simulations to evaluate the effectiveness and the accuracy of our proposed model. Empirical results show that our proposed model is quite accurate. In addition, our results also imply that the eavesdropping probability heavily depends on both the underwater acoustic channel conditions and the features of hydrophones.

  4. On Modeling Eavesdropping Attacks in Underwater Acoustic Sensor Networks

    Directory of Open Access Journals (Sweden)

    Qiu Wang

    2016-05-01

    Full Text Available The security and privacy of underwater acoustic sensor networks has received extensive attention recently due to the proliferation of underwater activities. This paper proposes an analytical model to investigate the eavesdropping attacks in underwater acoustic sensor networks. Our analytical framework considers the impacts of various underwater acoustic channel conditions (such as the acoustic signal frequency, spreading factor and wind speed and different hydrophones (isotropic hydrophones and array hydrophones in terms of network nodes and eavesdroppers. We also conduct extensive simulations to evaluate the effectiveness and the accuracy of our proposed model. Empirical results show that our proposed model is quite accurate. In addition, our results also imply that the eavesdropping probability heavily depends on both the underwater acoustic channel conditions and the features of hydrophones.

  5. An underwater acoustic data compression method based on compressed sensing

    Institute of Scientific and Technical Information of China (English)

    郭晓乐; 杨坤德; 史阳; 段睿

    2016-01-01

    The use of underwater acoustic data has rapidly expanded with the application of multichannel, large-aperture underwater detection arrays. This study presents an underwater acoustic data compression method that is based on compressed sensing. Underwater acoustic signals are transformed into the sparse domain for data storage at a receiving terminal, and the improved orthogonal matching pursuit (IOMP) algorithm is used to reconstruct the original underwater acoustic signals at a data processing terminal. When an increase in sidelobe level occasionally causes a direction of arrival estimation error, the proposed compression method can achieve a 10 times stronger compression for narrowband signals and a 5 times stronger compression for wideband signals than the orthogonal matching pursuit (OMP) algorithm. The IOMP algorithm also reduces the computing time by about 20% more than the original OMP algorithm. The simulation and experimental results are discussed.

  6. Design and implementation of an underwater sound recording device

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, Jayson J.; Myers, Joshua R.; Carlson, Thomas J.; Deng, Zhiqun; Rohrer, John S.; Caviggia, Kurt A.

    2011-09-19

    The purpose of this study was to design and build two versions of an underwater sound recording device. The device designed is referred to as the Underwater Sound Recorder (USR), which can be connected to one or two hydrophones or other underwater sound sensors. The URS contains a 26 dB preamplifier and a user selectable gain that permits additional amplification of input to the system from 26 dB to 46 dB. Signals within the frequency range up to 15 kHz may be recorded using the USR. Examples of USR applications are monitoring underwater processes that have the potential to create large pressure waves that could potentially harm fish or other aquatic life, such as underwater explosions or pile driving. Additional applications are recording sound generated by vessels or the vocalizations of some marine mammals, such as the calls from many species of whales.

  7. The design of underwater hull-cleaning robot

    Institute of Scientific and Technical Information of China (English)

    YUAN Fu-cai; GUO Li-bin; MENG Qing-xin; LIU Fu-qiang

    2004-01-01

    The research on underwater ship-hull cleaning robot was conducted on the purpose of realizing the automation of cleaning underwater ship hull so that service life of ship will be prolonged and ship speed will raised. Moreover, fuel consumption and the work intensity of divers will be reduced. In this paper, the current situation and the latest technology in China and abroad were analyzed;meanwhile, the typical characteristics of the underwater cleaning robot were introduced. According to the work principle of the underwater cleaning robot, the emphasis was put on the analysis and study of permanent-magnetic absorption, magnetic wheel, airproof and anticorrosion, underwater cleaning equipment and control system. The robot is easy in rotation and simple in control.

  8. Strong, reversible underwater adhesion via gecko-inspired hydrophobic fibers.

    Science.gov (United States)

    Soltannia, Babak; Sameoto, Dan

    2014-12-24

    Strong, reversible underwater adhesion using gecko-inspired surfaces is achievable through the use of a hydrophobic structural material and does not require surface modification or suction cup effects for this adhesion to be effective. Increased surface energy can aid in dry adhesion in an air environment but strongly degrades wet adhesion via reduction of interfacial energy underwater. A direct comparison of structurally identical but chemically different mushroom shaped fibers shows that strong, reversible adhesion, even in a fully wetted, stable state, is feasible underwater if the structural material of the fibers is hydrophobic and the mating surface is not strongly hydrophilic. The exact adhesion strength will be a function of the underwater interfacial energy between surfaces and the specific failure modes of individual fibers. This underwater adhesion has been calculated to be potentially greater than the dry adhesion for specific combinations of hydrophobic surfaces.

  9. Improving fundamental factors among correlation matching algorithms in underwater TANS

    Science.gov (United States)

    Lin, Yi; Yan, Lei; Tong, Qingxi

    2007-06-01

    TERCOM, ICP and TIEM algorithms, which mathematically all apply correlation matching mode, have been developed for positioning in underwater Terrain-aided Navigation System (TANS), but how to virtually improve their performance is still research puzzle now. Analyzing the characters of terrain reference data's distribution and vehicles prowling underwater, we find that grid spacing and accumulation sequence are two decisional elements of underwater TANS. Then the modified Maximum a Posteriori (MAP) estimation algorithm (M-MAP) from super-resolution images reconstruction is creatively explored for implementing interpolation to enhance the accuracy of non-surveyed points' deep-determination, and basic error mechanism model (EMM) based on Mean Absolute Difference (MAD) algorithm is deduced which can reflect the relationship of underwater TANS's inner factors. Simulation experiments indicate that adopting appropriate fundamental factors can effectively boost up underwater TANS's navigation competence based on the algorithms listed above.

  10. Shock initiated instabilities in underwater cylindrical structures

    Science.gov (United States)

    Gupta, Sachin; Matos, Helio; LeBlanc, James M.; Shukla, Arun

    2016-10-01

    An experimental investigation to understand the mechanisms of dynamic buckling instability in cylindrical structures due to underwater explosive loadings is conducted. In particular, the effects of initial hydrostatic pressure coupled with a dynamic pressure pulse on the stability of metallic cylindrical shells are evaluated. The experiments are conducted at varying initial hydrostatic pressures, below the critical buckling pressure, to estimate the threshold after which dynamic buckling will initiate. The transient underwater full-field deformations of the structures during shock wave loading are captured using high-speed stereo photography coupled with modified 3-D Digital Image Correlation (DIC) technique. Experimental results show that increasing initial hydrostatic pressure decreases the natural vibration frequency of the structure indicating loss in structural stiffness. DIC measurements reveal that the initial structural excitations primarily consist of axisymmetric vibrations due to symmetrical shock wave loading in the experiments. Following their decay after a few longitudinal reverberations, the primary mode of vibration evolves which continues throughout later in time. At the initial hydrostatic pressures below the threshold value, these vibrations are stable in nature. The analytical solutions for the vibration frequency and the transient response of cylindrical shell are discussed in the article by accounting for both (1) the added mass effect of the surrounding water and (2) the effect of initial stress on the shell imposed by the hydrostatic pressure. The analytical solutions match reasonably well with the experimental vibration frequencies. Later, the transient response of a cylindrical shell subjected to a general underwater pressure wave loading is derived which leads to the analytical prediction of dynamic stability.

  11. Occupational allergic contact dermatitis from epoxy resin in a golf club repairman.

    Science.gov (United States)

    Isaksson, Marléne; Möller, Halvor; Pontén, Ann

    2008-01-01

    A golfer presented with facial and hand eczema. He had exacerbations of his hand eczema prior to golf tournaments. Being an authorized golf club repairman, he had been working with a two-part glue containing an epoxy resin (ER) based on diglycidyl ether of bisphenol A (DGEBA) and the hardener diethylenetriamine (DETA) for approximately 4 years before he developed any skin problems. He was patch-tested with the standard, which contains an ER based on DGEBA (DGEBA-R), epoxy (containing DETA), and rubber glove series and had positive reactions to DGEBA-R only. Other work materials (a latex glove, a golf glove made of leather, and part of the handle of his own golf club "as is" and in a methyl tert-butyl ether extract) were tested, with negative results. Allergic contact dermatitis from ER affects the skin by direct contact; the dermatitis is usually localized to the hands and forearms. If the face and eyelids are involved, the dermatitis may be due to exposure to airborne hardeners or reactive diluents, exposure to airborne dust from residual monomers, or ectopic allergic reactions. Our repairman had sandpapered an old glued surface, which may have led to possible airborne dust formation, thus explaining the facial eczema. Therefore, a worker with contact allergy to ER may continue working provided the skin is protected from contamination.

  12. Underwater vehicle sonar self-noise prediction based on genetic algorithms and neural network

    Institute of Scientific and Technical Information of China (English)

    WU Xiao-guang; SHI Zhong-kun

    2006-01-01

    The factors that influence underwater vehicle sonar self-noise are analyzed, and genetic algorithms and a back propagation (BP) neural network are combined to predict underwater vehicle sonar self-noise. The experimental results demonstrate that underwater vehicle sonar self-noise can be predicted accurately by a GA-BP neural network that is based on actual underwater vehicle sonar data.

  13. Some experiments with underwater acoustic returns from cylinders relative to object identification for AUV operation/

    OpenAIRE

    Farren, Maureen A.

    1988-01-01

    Approved for public release; distribution is unlimited Underwater Vehicles, Sonar Sound Analyzers, Underwater Navigation, Acoustics, Anechoic Chambers, Cylindrical Bodies, Data Storage Systems, Delay, Electroacoustic Transducers, Estimates, Experimental Data, Geometric Forms, Identification, Images, Position Location, Propagation, Sonar, Surface Properties, Target Strength, Theses, Time Intervals, Underwater, Underwater Equipment http://archive.org/details/someexperimentsw00farr Lieu...

  14. Fault Diagnosis of Autonomous Underwater Vehicles

    Directory of Open Access Journals (Sweden)

    Xiao Liang

    2013-04-01

    Full Text Available In this study, we propose the least disturbance algorithm adding scale factor and shift factor. The dynamic learning ratio can be calculated to minimize the scale factor and shift factor of wavelet function and the variation of net weights and the algorithm improve the stability and the convergence of wavelet neural network. It was applied to build the dynamical model of autonomous underwater vehicles and the residuals are generated by comparing the outputs of the dynamical model with the real state values in the condition of thruster fault. Fault detection rules are distilled by residual analysis to execute thruster fault diagnosis. The results of simulation prove the effectiveness.

  15. Silent Localization of Underwater Sensors Using Magnetometers

    Science.gov (United States)

    Callmer, Jonas; Skoglund, Martin; Gustafsson (Eurasipmember), Fredrik

    2010-12-01

    Sensor localization is a central problem for sensor networks. If the sensor positions are uncertain, the target tracking ability of the sensor network is reduced. Sensor localization in underwater environments is traditionally addressed using acoustic range measurements involving known anchor or surface nodes. We explore the usage of triaxial magnetometers and a friendly vessel with known magnetic dipole to silently localize the sensors. The ferromagnetic field created by the dipole is measured by the magnetometers and is used to localize the sensors. The trajectory of the vessel and the sensor positions are estimated simultaneously using an Extended Kalman Filter (EKF). Simulations show that the sensors can be accurately positioned using magnetometers.

  16. SIMULATIONS OF FLOWFIELDS AROUND UNDERWATER APPENDED BODIES

    Institute of Scientific and Technical Information of China (English)

    Huang Zhen-yu; Cheng Hong-rong; Zhou Lian-di; Miao Guo-ping

    2003-01-01

    The numerical method which is based on flux difference splitting, LU decomposition, and implicit high-resolution third-order Essentially Non-Oscillatory (ENO) scheme was constructed for the efficient computation of steady state solution to three-dimensional incompressible Navier-Stokes equations in general coordinates. The flowfields over underwater axisymmetric bodies, full-appended axisymmetric bodies and axisymetric bodies with a ring-wing duct were simulated. The method is proved to be capable of predicting the circumferential-mean velocity distribution at model scale to the accuracy of around 3% of measured values, and of predicting some details of flow features, for example, the wake harmonics.

  17. Hemispherical Optical Dome for Underwater Communication

    Science.gov (United States)

    Shiri, Ron S.; Lunde, Emily L.; Coronado, Patrick L.; Quijada, Manuel A.

    2017-01-01

    For many years, acoustic systems have been used as the primary method for underwater communication; however, the data transfer rate of such systems is low because sound propagates slowly through the water. A higher throughput can be achieved using visible light to transmit data underwater. The first issue with using this approach is that there is generally a large loss of the light signal due to scattering and absorption in water even though there is an optimal wavelength for transmission in the blue or green wavelengths of the visible spectrum. The second issue is that a simple system consisting only of a highly directional source transmitter and small optical detector receiver has a very narrow field of view. The goal of this project is to improve an optical, underwater communication system by increasing the effective field of view of the receiving optics. To this end, we make two changes to the simple system: (1) An optical dome was added near the receiver. An array of lenses is placed radially on the surface of the dome, reminiscent of the compound eye of an insect. The lenses make the source and detector planes conjugate, and each lens adds a new region of the source plane to the instrument's total field of view. (2) The receiver was expanded to include multiple photodiodes. With these two changes, the receiver has much more tolerance to misalignments (in position and angle) of the transmitter.Two versions of the optical dome (with 6 and 8 diameters) were designed using the CREO CAD software and modeled using the CODE V optical design software. A series of these transparent hemispherical domes, with both design diameters, were manufactured using a 5-axis mill. The prototype was then retrofitted with lenses and compared with the computer-generated model to demonstrate the effectiveness of this solution. This work shows the dome design improves the optical field of view of the underwater communication system considerably. Furthermore, with the experimental test

  18. Autonomous Underwater Vehicle „ABYSS“

    Directory of Open Access Journals (Sweden)

    Peter Linke

    2016-06-01

    Full Text Available The Autonomous Underwater Vehicle (AUV „ABYSS“ is a modular AUV designed to survey the ocean combining geophysical studies of the seafloor with oceanographic investigations of the overlying water column. The basic mission of ABYSS is deep-sea exploration, specifically in volcanically and tectonically active parts, such as mid-ocean ridges. With a maximum mission depth of 6000 meters, the AUV uses several technologies to map the seafloor accurately and determine its geological structure with applications from geology to biology to mineral exploration.

  19. Underwater Explosion Damage of Ship Hull Panels

    OpenAIRE

    K. Rarnajeyathilagam; Vendhan, C.P.

    2003-01-01

    Underwater explosion is a major threat to ships and submarines in a war environment. The prediction of the mode and the extent of the failure is an essential step in designing for shock loading. The localised failure in a hull panel is severe compared to the global response of the ship. In this study, an attempt has been made to predict the response and failure modes of three types of hull panels (flat, concave, and convex). The shock loading on the hull panel has been estimated based on the ...

  20. Covert underwater acoustic communication using dolphin sounds.

    Science.gov (United States)

    Liu, Songzuo; Qiao, Gang; Ismail, Asim

    2013-04-01

    In November 2012, an experiment demonstrating biological mimicry method for covert underwater acoustic communication (UAC) was conducted at Lianhua Lake in Heilongjiang China. Dolphin whistles were used for synchronization while dolphin clicks were used as information carrier. The time interval between dolphin clicks conveys the information bits. Channel estimates were obtained with matching pursuit (MP) algorithm, which is useful for sparse channel estimation. Adaptive RAKE Equalization was employed at the receiver. Bit error rates were less than 10(-4) with 37 bits per second data rate in the lake trial.

  1. Water waves generated by underwater explosion

    CERN Document Server

    Mehaute, Bernard Le

    1996-01-01

    This is the first book on explosion-generated water waves. It presents the theoretical foundations and experimental results of the generation and propagation of impulsively generated waves resulting from underwater explosions. Many of the theories and concepts presented herein are applicable to other types of water waves, in particular, tsunamis and waves generated by the fall of a meteorite. Linear and nonlinear theories, as well as experimental calibrations, are presented for cases of deep and shallow water explosions. Propagation of transient waves on dissipative, nonuniform bathymetries to

  2. Underwater Chaotic Lidar using Blue Laser Diodes

    Science.gov (United States)

    Rumbaugh, Luke K.

    The thesis proposes and explores an underwater lidar system architecture based on chaotic modulation of recently introduced, commercially available, low cost blue laser diodes. This approach is experimentally shown to allow accurate underwater impulse response measurements while eliminating the need for several major components typically found in high-performance underwater lidar systems. The proposed approach is to: 1. Generate wideband, noise-like intensity modulation signals using optical chaotic modulation of blue-green laser diodes, and then 2. Use this signal source to develop an underwater chaotic lidar system that uses no electrical signal generator, no electro-optic modulator, no optical frequency doubler, and no large-aperture photodetector. The outcome of this thesis is the demonstration of a new underwater lidar system architecture that could allow high resolution ranging, imaging, and water profiling measurements in turbid water, at a reduced size, weight, power and cost relative to state-of-the-art high-performance underwater lidar sensors. This work also makes contributions to the state of the art in optics, nonlinear dynamics, and underwater sensing by demonstrating for the first time: 1. Wideband noise-like intensity modulation of a blue laser diode using no electrical signal generator or electro-optic modulator. Optical chaotic modulation of a 462 nm blue InGaN laser diode by self-feedback is explored for the first time. The usefulness of the signal to chaotic lidar is evaluated in terms of bandwidth, modulation depth, and autocorrelation peak-to-sidelobe-ratio (PSLR) using both computer and laboratory experiments. In laboratory experiments, the optical feedback technique is shown to be effective in generating wideband, noise-like chaotic signals with strong modulation depth when the diode is operated in an external-cavity dominated state. The modulation signal strength is shown to be limited by the onset of lasing within the diode's internal

  3. Atomistic Modeling of Thermal Conductivity of Epoxy Nanotube Composites

    Science.gov (United States)

    Fasanella, Nicholas A.; Sundararaghavan, Veera

    2016-05-01

    The Green-Kubo method was used to investigate the thermal conductivity as a function of temperature for epoxy/single wall carbon nanotube (SWNT) nanocomposites. An epoxy network of DGEBA-DDS was built using the `dendrimer' growth approach, and conductivity was computed by taking into account long-range Coulombic forces via a k-space approach. Thermal conductivity was calculated in the direction perpendicular to, and along the SWNT axis for functionalized and pristine SWNT/epoxy nanocomposites. Inefficient phonon transport at the ends of nanotubes is an important factor in the thermal conductivity of the nanocomposites, and for this reason discontinuous nanotubes were modeled in addition to long nanotubes. The thermal conductivity of the long, pristine SWNT/epoxy system is equivalent to that of an isolated SWNT along its axis, but there was a 27% reduction perpendicular to the nanotube axis. The functionalized, long SWNT/epoxy system had a very large increase in thermal conductivity along the nanotube axis (~700%), as well as the directions perpendicular to the nanotube (64%). The discontinuous nanotubes displayed an increased thermal conductivity along the SWNT axis compared to neat epoxy (103-115% for the pristine SWNT/epoxy, and 91-103% for functionalized SWNT/epoxy system). The functionalized system also showed a 42% improvement perpendicular to the nanotube, while the pristine SWNT/epoxy system had no improvement over epoxy. The thermal conductivity tensor is averaged over all possible orientations to see the effects of randomly orientated nanotubes, and allow for experimental comparison. Excellent agreement is seen for the discontinuous, pristine SWNT/epoxy nanocomposite. These simulations demonstrate there exists a threshold of the SWNT length where the best improvement for a composite system with randomly oriented nanotubes would transition from pristine SWNTs to functionalized SWNTs.

  4. Thermal Expansion and Swelling of Cured Epoxy Resin Used in Graphite/Epoxy Composite

    Science.gov (United States)

    Adamson, M. J.

    1979-01-01

    The thermal expansion and swelling of resin material as influenced by variations in temperature during moisture absorption is discussed. Comparison measurements using composites constructed of graphite fibers and each of two epoxy resin matrices are included. Polymer theory relative to these findings is discussed and modifications are proposed.

  5. Epoxy-resin adhesive and method for bonding using such an epoxy resin adhesive

    NARCIS (Netherlands)

    Bhowmik, S.; Poulis, J.A.; Benedictus, R.

    2008-01-01

    The invention relates to an epoxy resin adhesive comprising a dotation of nano-substances, wherein the nano- substances are selected from the group comprising carbon-fibre nanotubes, carbon nano-fibres, silicate nano powders, and wherein the nano-substances are dispersed in the adhesive with a weigh

  6. Epoxy-resin adhesive and method for bonding using such an epoxy resin adhesive

    NARCIS (Netherlands)

    Bhowmik, S.; Poulis, J.A.; Benedictus, R.

    2008-01-01

    The invention relates to an epoxy resin adhesive comprising a dotation of nano-substances, wherein the nano- substances are selected from the group comprising carbon-fibre nanotubes, carbon nano-fibres, silicate nano powders, and wherein the nano-substances are dispersed in the adhesive with a

  7. Software architecture of biomimetic underwater vehicle

    Science.gov (United States)

    Praczyk, Tomasz; Szymak, Piotr

    2016-05-01

    Autonomous underwater vehicles are vehicles that are entirely or partly independent of human decisions. In order to obtain operational independence, the vehicles have to be equipped with a specialized software. The main task of the software is to move the vehicle along a trajectory with collision avoidance. Moreover, the software has also to manage different devices installed on the vehicle board, e.g. to start and stop cameras, sonars etc. In addition to the software embedded on the vehicle board, the software responsible for managing the vehicle by the operator is also necessary. Its task is to define mission of the vehicle, to start, to stop the mission, to send emergency commands, to monitor vehicle parameters, and to control the vehicle in remotely operated mode. An important objective of the software is also to support development and tests of other software components. To this end, a simulation environment is necessary, i.e. simulation model of the vehicle and all its key devices, the model of the sea environment, and the software to visualize behavior of the vehicle. The paper presents architecture of the software designed for biomimetic autonomous underwater vehicle (BAUV) that is being constructed within the framework of the scientific project financed by Polish National Center of Research and Development.

  8. Underwater noise from a wave energy converter

    DEFF Research Database (Denmark)

    Tougaard, Jakob

    A recent addition to the anthropogenic sources of underwater noise is offshore wave energy converters. Underwater noise was recorded from the Wavestar wave energy converter located at Hastholm, Denmark (57°7.73´N, 8°37.23´E). The Wavestar is a full-scale test and demonstration converter...... in full operation and start and stop of the converter. Median broad band (10 Hz – 20 kHz) sound pressure level (Leq) was 123 dB re. 1 Pa, irrespective of status of the wave energy converter (stopped, running or starting/stopping). The most pronounced peak in the third-octave spectrum was in the 160 Hz...... significant noise above ambient could be detected above the 250 Hz band. The absolute increase in noise above ambient was very small. L50 third-octave levels in the four bands with the converter running were thus only 1-2 dB above ambient L50 levels. The noise recorded 25 m from the wave energy converter...

  9. Underwater noise levels in UK waters

    Science.gov (United States)

    Merchant, Nathan D.; Brookes, Kate L.; Faulkner, Rebecca C.; Bicknell, Anthony W. J.; Godley, Brendan J.; Witt, Matthew J.

    2016-11-01

    Underwater noise from human activities appears to be rising, with ramifications for acoustically sensitive marine organisms and the functioning of marine ecosystems. Policymakers are beginning to address the risk of ecological impact, but are constrained by a lack of data on current and historic noise levels. Here, we present the first nationally coordinated effort to quantify underwater noise levels, in support of UK policy objectives under the EU Marine Strategy Framework Directive (MSFD). Field measurements were made during 2013-2014 at twelve sites around the UK. Median noise levels ranged from 81.5-95.5 dB re 1 μPa for one-third octave bands from 63-500 Hz. Noise exposure varied considerably, with little anthropogenic influence at the Celtic Sea site, to several North Sea sites with persistent vessel noise. Comparison of acoustic metrics found that the RMS level (conventionally used to represent the mean) was highly skewed by outliers, exceeding the 97th percentile at some frequencies. We conclude that environmental indicators of anthropogenic noise should instead use percentiles, to ensure statistical robustness. Power analysis indicated that at least three decades of continuous monitoring would be required to detect trends of similar magnitude to historic rises in noise levels observed in the Northeast Pacific.

  10. Pulmonary overinflation syndrome in an underwater logger.

    Science.gov (United States)

    Rozali, A; Sulaiman, A; Zin, B Mohd; Khairuddin, H; Abd-Halim, M; Sherina, M S

    2006-10-01

    Pulmonary overinflation syndrome (POIS) is a group of barotrauma-related diseases caused by the expansion of gas trapped in the lung, or over-pressurization of the lung with subsequent over-expansion and rupture of the alveolar air sacs. This group of disorders includes arterial gas embolism, tension pneumothorax, mediastinal emphysema, subcutaneous emphysema and rarely pneumopericardium. In the case of diving activities, POIS is rarely reported and is frequently related to unsafe diving techniques. We report a classical case of POIS in an underwater logger while cutting trees for logs in Tasik Kenyir, Terengganu. The patient, a 24-year-old worker, made a rapid free ascent to the surface after his breathing equipment malfunctioned while he was working underwater. He suffered from bilateral tension pneumothoraces, arterial gas embolism giving rise to multiple cerebral and cerebellar infarcts, mediastinal and subcutaneous emphysema as well as pneumopericardium. He was treated in a recompression chamber with hyperbaric oxygen therapy and discharged with residual weakness in his right leg.

  11. Simplified Scheduling for Underwater Acoustic Networks

    Directory of Open Access Journals (Sweden)

    Wouter van Kleunen

    2013-01-01

    Full Text Available The acoustic propagation speed under water poses significant challenges to the design of underwater sensor networks and their medium access control protocols. Similar to the air, scheduling transmissions under water has significant impact on throughput, energy consumption, and reliability. In this paper we present an extended set of simplified scheduling constraints which allows easy scheduling of underwater acoustic communication. We also present two algorithms for scheduling communications, i.e. a centralized scheduling approach and a distributed scheduling approach. The centralized approach achieves the highest throughput while the distributed approach aims to minimize the computation and communication overhead. We further show how the centralized scheduling approach can be extended with transmission dependencies to reduce the end-to-end delay of packets. We evaluate the performance of the centralized and distributed scheduling approaches using simulation. The centralized approach outperforms the distributed approach in terms of throughput, however we also show the distributed approach has significant benefits in terms of communication and computational overhead required to setup the schedule. We propose a novel way of estimating the performance of scheduling approaches using the ratio of modulation time and propagation delay. We show the performance is largely dictated by this ratio, although the number of links to be scheduled also has a minor impact on the performance.

  12. Dynamic formation control for autonomous underwater vehicles

    Institute of Scientific and Technical Information of China (English)

    燕雪峰; 古锋; 宋琛; 胡晓琳; 潘毅

    2014-01-01

    Path planning and formation structure forming are two of the most important problems for autonomous underwater vehicles (AUVs) to collaborate with each other. In this work, a dynamic formation model was proposed, in which several algorithms were developed for the complex underwater environment. Dimension changeable particle swarm algorithm was used to find an optimized path by dynamically adjusting the number and the distribution of the path nodes. Position relationship based obstacle avoidance algorithm was designed to detour along the edges of obstacles. Virtual potential point based formation-keeping algorithm was employed by incorporating dynamic strategies which were decided by the current states of the formation. The virtual potential point was used to keep the formation structure when the AUV or the formation was deviated. Simulation results show that an optimal path can be dynamically planned with fewer path nodes and smaller fitness, even with a concave obstacle. It has been also proven that different formation-keeping strategies can be adaptively selected and the formation can change its structure in a narrow area and restore back after passing the obstacle.

  13. Hydrogel microphones for stealthy underwater listening

    Science.gov (United States)

    Gao, Yang; Song, Jingfeng; Li, Shumin; Elowsky, Christian; Zhou, You; Ducharme, Stephen; Chen, Yong Mei; Zhou, Qin; Tan, Li

    2016-08-01

    Exploring the abundant resources in the ocean requires underwater acoustic detectors with a high-sensitivity reception of low-frequency sound from greater distances and zero reflections. Here we address both challenges by integrating an easily deformable network of metal nanoparticles in a hydrogel matrix for use as a cavity-free microphone. Since metal nanoparticles can be densely implanted as inclusions, and can even be arranged in coherent arrays, this microphone can detect static loads and air breezes from different angles, as well as underwater acoustic signals from 20 Hz to 3 kHz at amplitudes as low as 4 Pa. Unlike dielectric capacitors or cavity-based microphones that respond to stimuli by deforming the device in thickness directions, this hydrogel device responds with a transient modulation of electric double layers, resulting in an extraordinary sensitivity (217 nF kPa-1 or 24 μC N-1 at a bias of 1.0 V) without using any signal amplification tools.

  14. Modelling cavitating flow around underwater missiles

    Directory of Open Access Journals (Sweden)

    Fabien Petitpas

    2011-12-01

    Full Text Available The diffuse interface model of Saurel et al. (2008 is used for the computation of compressible cavitating flows around underwater missiles. Such systems use gas injection and natural cavitation to reduce drag effects. Consequently material interfaces appear separating liquid and gas. These interfaces may have a really complex dynamics such that only a few formulations are able to predict their evolution. Contrarily to front tracking or interface reconstruction method the interfaces are computed as diffused numerical zones, that are captured in a routinely manner, as is done usually with gas dynamics solvers for shocks and contact discontinuity. With the present approach, a single set of partial differential equations is solved everywhere, with a single numerical scheme. This leads to very efficient solvers. The algorithm derived in Saurel et al. (2009 is used to compute cavitation pockets around solid bodies. It is first validated against experiments done in cavitation tunnel at CNU. Then it is used to compute flows around high speed underwater systems (Shkval-like missile. Performance data are then computed showing method ability to predict forces acting on the system.

  15. An explanatory model of underwater adaptation

    Directory of Open Access Journals (Sweden)

    Joaquín Colodro

    Full Text Available The underwater environment is an extreme environment that requires a process of human adaptation with specific psychophysiological demands to ensure survival and productive activity. From the standpoint of existing models of intelligence, personality and performance, in this explanatory study we have analyzed the contribution of individual differences in explaining the adaptation of military personnel in a stressful environment. Structural equation analysis was employed to verify a model representing the direct effects of psychological variables on individual adaptation to an adverse environment, and we have been able to confirm, during basic military diving courses, the structural relationships among these variables and their ability to predict a third of the variance of a criterion that has been studied very little to date. In this way, we have confirmed in a sample of professionals (N = 575 the direct relationship of emotional adjustment, conscientiousness and general mental ability with underwater adaptation, as well as the inverse relationship of emotional reactivity. These constructs are the psychological basis for working under water, contributing to an improved adaptation to this environment and promoting risk prevention and safety in diving activities.

  16. Suspended microstructures of epoxy based photoresists fabricated with UV photolithography

    DEFF Research Database (Denmark)

    Hemanth, Suhith; Anhøj, Thomas Aarøe; Caviglia, Claudia

    2017-01-01

    In this work we present an easy, fast, reliable and low cost microfabrication technique for fabricating suspended microstructures of epoxy based photoresistswith UV photolithography. Two different fabrication processes with epoxy based resins (SU-8 and mr-DWL) using UV exposures at wavelengths of...

  17. Microstructural Design & Optimization of Highly Filled Epoxy Based Composites

    Science.gov (United States)

    2009-11-01

    particle concentration and decreasing the particle size were found to increase the stress at 4% strain [5]. A study of aluminum filled epoxy ( DGEBA ...to increase the strength corresponding to 4% plastic strain [5]. A study of aluminum filled epoxy ( DGEBA /MTHPA) composites has found that a small

  18. The training in epoxy-impregnated superconducting coils

    Energy Technology Data Exchange (ETDEWEB)

    Fujita, H.; Bobrov, E.S.; Iwasa, Y.; Takaghi, T.; Tsukamoto, O.

    1985-03-01

    The authors have investigated the training of epoxy-impregnated superconducting coils. It has been observed that the boundary conditions at the coil ends have a crucial effect on shear-stress-induced epoxy cracks in the winding and consequently on the coil training. The results were quantified using acoustic emission data.

  19. Positron Annihilation in a Rubber Modified Epoxy Resin

    DEFF Research Database (Denmark)

    Mogensen, O. E.; Jacobsen, F. M.; Pethrick, R. A.

    1979-01-01

    Positron annihilation data is reported on a rubber-modified epoxy resin. Studies of the temperature dependence of the o-positronium lifetime indicated the existence of three distinct regions; the associated transition temperatures by comparison with dilatometric data can be ascribed respectively...... to be glass transition of the epoxy phase and to that of a mixed acrylonitrile—epoxy—butadiene interfacial region....

  20. Intelligent Navigation for a Solar Powered Unmanned Underwater Vehicle

    Directory of Open Access Journals (Sweden)

    Francisco García-Córdova

    2013-04-01

    Full Text Available In this paper, an intelligent navigation system for an unmanned underwater vehicle powered by renewable energy and designed for shadow water inspection in missions of a long duration is proposed. The system is composed of an underwater vehicle, which tows a surface vehicle. The surface vehicle is a small boat with photovoltaic panels, a methanol fuel cell and communication equipment, which provides energy and communication to the underwater vehicle. The underwater vehicle has sensors to monitor the underwater environment such as sidescan sonar and a video camera in a flexible configuration and sensors to measure the physical and chemical parameters of water quality on predefined paths for long distances. The underwater vehicle implements a biologically inspired neural architecture for autonomous intelligent navigation. Navigation is carried out by integrating a kinematic adaptive neuro‐controller for trajectory tracking and an obstacle avoidance adaptive neuro‐controller. The autonomous underwater vehicle is capable of operating during long periods of observation and monitoring. This autonomous vehicle is a good tool for observing large areas of sea, since it operates for long periods of time due to the contribution of renewable energy. It correlates all sensor data for time and geodetic position. This vehicle has been used for monitoring the Mar Menor lagoon.

  1. Measurements of optical underwater turbulence under controlled conditions

    Science.gov (United States)

    Kanaev, A. V.; Gladysz, S.; Almeida de Sá Barros, R.; Matt, S.; Nootz, G. A.; Josset, D. B.; Hou, W.

    2016-05-01

    Laser beam propagation underwater is becoming an important research topic because of high demand for its potential applications. Namely, ability to image underwater at long distances is highly desired for scientific and military purposes, including submarine awareness, diver visibility, and mine detection. Optical communication in the ocean can provide covert data transmission with much higher rates than that available with acoustic techniques, and it is now desired for certain military and scientific applications that involve sending large quantities of data. Unfortunately underwater environment presents serious challenges for propagation of laser beams. Even in clean ocean water, the extinction due to absorption and scattering theoretically limit the useful range to few attenuation lengths. However, extending the laser light propagation range to the theoretical limit leads to significant beam distortions due to optical underwater turbulence. Experiments show that the magnitude of the distortions that are caused by water temperature and salinity fluctuations can significantly exceed the magnitude of the beam distortions due to atmospheric turbulence even for relatively short propagation distances. We are presenting direct measurements of optical underwater turbulence in controlled conditions of laboratory water tank using two separate techniques involving wavefront sensor and LED array. These independent approaches will enable development of underwater turbulence power spectrum model based directly on the spatial domain measurements and will lead to accurate predictions of underwater beam propagation.

  2. The influence of underwater turbulence on optical phase measurements

    Science.gov (United States)

    Redding, Brandon; Davis, Allen; Kirkendall, Clay; Dandridge, Anthony

    2016-05-01

    Emerging underwater optical imaging and sensing applications rely on phase-sensitive detection to provide added functionality and improved sensitivity. However, underwater turbulence introduces spatio-temporal variations in the refractive index of water which can degrade the performance of these systems. Although the influence of turbulence on traditional, non-interferometric imaging has been investigated, its influence on the optical phase remains poorly understood. Nonetheless, a thorough understanding of the spatio-temporal dynamics of the optical phase of light passing through underwater turbulence are crucial to the design of phase-sensitive imaging and sensing systems. To address this concern, we combined underwater imaging with high speed holography to provide a calibrated characterization of the effects of turbulence on the optical phase. By measuring the modulation transfer function of an underwater imaging system, we were able to calibrate varying levels of optical turbulence intensity using the Simple Underwater Imaging Model (SUIM). We then used high speed holography to measure the temporal dynamics of the optical phase of light passing through varying levels of turbulence. Using this method, we measured the variance in the amplitude and phase of the beam, the temporal correlation of the optical phase, and recorded the turbulence induced phase noise as a function of frequency. By bench marking the effects of varying levels of turbulence on the optical phase, this work provides a basis to evaluate the real-world potential of emerging underwater interferometric sensing modalities.

  3. Underwater Acoustic Source Localisation Among Blind and Sighted Scuba Divers

    Science.gov (United States)

    Cambi, Jacopo; Livi, Ludovica; Livi, Walter

    2017-01-01

    Objectives Many blind individuals demonstrate enhanced auditory spatial discrimination or localisation of sound sources in comparison to sighted subjects. However, this hypothesis has not yet been confirmed with regards to underwater spatial localisation. This study therefore aimed to investigate underwater acoustic source localisation among blind and sighted scuba divers. Methods This study took place between February and June 2015 in Elba, Italy, and involved two experimental groups of divers with either acquired (n = 20) or congenital (n = 10) blindness and a control group of 30 sighted divers. Each subject took part in five attempts at an under-water acoustic source localisation task, in which the divers were requested to swim to the source of a sound originating from one of 24 potential locations. The control group had their sight obscured during the task. Results The congenitally blind divers demonstrated significantly better underwater sound localisation compared to the control group or those with acquired blindness (P = 0.0007). In addition, there was a significant correlation between years of blindness and underwater sound localisation (P sound in an underwater environment. As the correct localisation of sounds underwater may help individuals to avoid imminent danger, divers should perform sound localisation tests during training sessions. PMID:28690888

  4. The Durability of Epoxy Resin Coating

    Institute of Scientific and Technical Information of China (English)

    ZHAO Fujun; BA Hengjing; GAO Xiaojian

    2008-01-01

    The durability of epoxy resin coating was studied under environments with relative humidity(RH) of 98%-100%, at 55 ℃ for 900 h, at 65℃ for 700 h and at 75 ℃ for 400 h, respectively. Peel strength test, dynamical mechanical thermal analysis (DMTA), infrared spectroscopy (IR) and energy dispersive X-ray spectroscopy (EDX) were employed for measurements. Peel strength indicated the development of adhesive property of the coating, DMTA indicated the development of physical property, IR revealed the development of chemical structure, and EDX showed surface element change of the coating. All these results show a good time-temperature equivalence characteristic between humidity aging time and temperature.

  5. Nonlinear time dependent behaviour of epoxy resins

    Science.gov (United States)

    Marotzke, C.; Feldmann, T.

    2016-07-01

    The nonlinear behaviour of epoxy resins is studied on standard tensile tests. A strain field measurement system is applied (Aramis) in order to monitor local strains. The residual strain is measured by recovering the specimens for up to 68 hours after unloading. The time span the specimen is exposed to load has a large influence on the creeping process and the residual strain after recovering. This is studied by comparison of instantaneous unloading with keeping the specimen under permanent load for thirty minutes. It is shown that moderate differences in the initial strain can lead to large differences in the creep behaviour as well as in the residual strain.

  6. RHEOLOGICAL BEHAVIOR OF EPOXY RESIN WATERBORNE DISPERSIONS

    Institute of Scientific and Technical Information of China (English)

    Zhen-zhong Yang; Yuan-ze Xu; De-lu Zhao

    2001-01-01

    The waterborne dispersions of epoxy resin were prepared by the phase inversion emulsification technique.Rheological behavior and its relationship with the structural change of the systems were studied. It was shown that the concentrated dispersions were highly viscoelastic and pseudoplastic, which was attributed to the formation of a physical network among the waterborne particles via hydrogen bond. The dilute dispersions were Newtonian fluids. The discrete clusters composed of small waterborne particles were found in diluted dispersions. With increasing solid content, there existed a structural transition via percolation through a cluster-cluster aggregation mode to form the physical network, which was qualitatively evidenced by the TEM morphologies.``

  7. Dielectric properties of nanosilica filled epoxy nanocomposites

    Indian Academy of Sciences (India)

    M G VEENA; N M RENUKAPPA; KUNIGAL N SHIVAKUMAR; S SEETHARAMU

    2016-04-01

    This paper presents the development of epoxy-silica nanocomposites and characterized for dielectric properties. The effect of nanosilica loading (0–20 wt%), frequency, temperature and sea water aging on these properties was studied. Transmission electron microscopy (TEM) analysis of the samples showed an excellent dispersion. However, at higher silica loading TEM showed inter-contactity of the particles. The dielectric constant (υ') increased with silica loading and reached an optimum at about 10 wt%. The υ' of the nanocomposites showed linear decrease with frequency whereas AC conductivity (σac) increases. The σac and υ' increased marginally with temperature and sea water aging.

  8. Epoxy Pipelining Composition and Method of Manufacture.

    Science.gov (United States)

    1994-12-14

    resin such as DGEBA (the diglycidyl ether of bisphenol A; see infra page 38) 16 and/or DGEBF (the diglycidyl ether of bisphenol F; see infra page 38...acid and 1,2 DCH, 20 about 22.4 mole % of the benzyl alcohol (i.e. the exemplary reactive diluent), and about 21 6.26 mole % of the DGEBA wherein x = 0...of the part A epoxy resin 5 ( DGEBA : Epon° 828, and/or Araldite XU Bis F GY° 281) containing optional 6 pigments such as Titanium Oxide (TiO 2 R-960

  9. Thermomechanical stability of graphite/epoxy composites.

    Science.gov (United States)

    Goggin, W R

    1974-02-01

    Results are reported on an investigation to evaluate the usefulness of selected graphite/epoxy composite structures for applications requiring precision tolerancing and dimensional stability. Thornel 75S/ELRB 4617 and Modmor 1/ELRB 4617 laminate composites in a six-ply design were tested, as well as a honeycomb design having two Thornel/ELRB faceplates bonded to an aluminum honeycomb core. Measurements were made of thermal expansion coefficient and its directional variations, microyielding and microcreep behavior, thermal and temporal stabilities. Data, discussion of results, and recommendations for applicable areas are given for the specific material and design types tested.

  10. Toughening of epoxy resins by epoxidized soybean oil

    Energy Technology Data Exchange (ETDEWEB)

    Frischinger, I.; Dirlikov, S. [Eastern Michigan Univ., Ypsilanti, MI (United States)

    1993-12-31

    Homogeneous mixtures of a liquid rubber based on prepolymers of epoxidized soybean oil with amines, diglycidyl ether of bisphenol A epoxy resins, and commercial diamines form, under certain conditions, two-phase thermosetting materials that consist of a rigid epoxy matrix and randomly distributed small rubbery soybean particles (0.1-5 {mu}m). These two-phase thermosets have improved toughness, similar to that of other rubber-modified epoxies, low water absorption, and low sodium content. In comparison to the unmodified thermosets, the two-phase thermosets exhibit slightly lower glass-transition temperatures and Young`s moduli, but their dielectric properties do not change. The epoxidized soybean oil is available at a price below that of commercial epoxy resins and appears very attractive for epoxy toughening on an industrial scale. 15 refs., 17 figs., 6 tabs.

  11. Physical aging of linear and network epoxy resins

    Science.gov (United States)

    Kong, E. S.-W.; Wilkes, G. L.; Mcgrath, J. E.; Banthia, A. K.; Mohajer, Y.; Tant, M. R.

    1981-01-01

    Network and linear epoxy resins principally based on the diglycidyl ether of bisphenol-A and its oligomers are prepared and studied using diamine and anhydride crosslinking agents. Rubber modified epoxies and a carbon fiber reinforced composite are also investigated. All materials display time-dependent changes when stored at temperatures below the glass transition temperature after quenching (sub-T/g/ annealing). Solvent sorption experiments initiated after different sub-T(g) annealing times demonstrate that the rate of solvent uptake can be indirectly related to the free volume of the epoxy resins. Residual thermal stresses and water are found to have little effect on the physical aging process, which affects the sub-T(g) properties of uniaxial carbon fiber reinforced epoxy material. Finally, the importance of the recovery phenomenon which affects the durability of epoxy glasses is considered.

  12. Insights into Epoxy Network Nanostructural Heterogeneity Using AFM-IR.

    Science.gov (United States)

    Morsch, Suzanne; Liu, Yanwen; Lyon, Stuart B; Gibbon, Simon R

    2016-01-13

    The first direct observation of a chemically heterogeneous nanostructure within an epoxy resin is reported. Epoxy resins comprise the matrix component of many high performance composites, coatings and adhesives, yet the molecular network structure that underpins the performance of these industrially essential materials is not well understood. Internal nodular morphologies have repeatedly been reported for epoxy resins analyzed using SEM or AFM, yet the origin of these features remains a contentious subject, and epoxies are still commonly assumed to be chemically homogeneous. Uniquely, in this contribution we use the recently developed AFM-IR technique to eliminate previous differences in interpretation, and establish that nodule features correspond to heterogeneous network connectivity within an epoxy phenolic formulation.

  13. Biobased Epoxy Resins from Deconstructed Native Softwood Lignin.

    Science.gov (United States)

    van de Pas, Daniel J; Torr, Kirk M

    2017-08-14

    The synthesis of novel epoxy resins from lignin hydrogenolysis products is reported. Native lignin in pine wood was depolymerized by mild hydrogenolysis to give an oil product that was reacted with epichlorohydrin to give epoxy prepolymers. These were blended with bisphenol A diglycidyl ether or glycerol diglycidyl ether and cured with diethylenetriamine or isophorone diamine. The key novelty of this work lies in using the inherent properties of the native lignin in preparing new biobased epoxy resins. The lignin-derived epoxy prepolymers could be used to replace 25-75% of the bisphenol A diglycidyl ether equivalent, leading to increases of up to 52% in the flexural modulus and up to 38% in the flexural strength. Improvements in the flexural strength were attributed to the oligomeric products present in the lignin hydrogenolysis oil. These results indicate lignin hydrogenolysis products have potential as sustainable biobased polyols in the synthesis of high performance epoxy resins.

  14. Method for epoxy foam production using a liquid anhydride

    Science.gov (United States)

    Celina, Mathias [Albuquerque, NM

    2012-06-05

    An epoxy resin mixture with at least one epoxy resin of between approximately 50 wt % and 100 wt %, an anhydride cure agent of between approximately 0 wt % and approximately 50 wt %, a tert-butoxycarbonyl anhydride foaming agent of between proximately 0.1-20 wt %, a surfactant and an imidazole or similar catalyst of less than approximately 2 wt %, where the resin mixture is formed from at least one epoxy resin with a 1-10 wt % tert-butoxycarbonyl anhydride compound and an imidazole catalyst at a temperature sufficient to keep the resin in a suitable viscosity range, the resin mixture reacting to form a foaming resin which in the presence of an epoxy curative can then be cured at a temperature greater than 50.degree. C. to form an epoxy foam.

  15. Impact Resistance of Short Fibre/Particle Reinforced Epoxy

    Science.gov (United States)

    Chang, L.; Zhang, Z.; Breidt, C.

    2004-01-01

    The influence of temperature on the fracture behaviour of epoxy-based composites was studied using an instrumented Charpy impact approach. A series of epoxy reinforced with short carbon fibres (SCF) and additionally filled with various amounts of PTFE and graphite particles was considered in this study. Unnotched specimens were tested at -196°C, 20°C, and 70°C, respectively. It was found that, for specimens with the same matrix content, a proper hybridisation of composites was possible to achieve a better impact performance compared to single-filler/epoxy. For example, 10 vol.%PTFE+10 vol.%SCF/epoxy exhibited a higher impact resistance than that of 20 vol.%SCF/epoxy at all measured temperatures. Failure mechanisms at different temperatures were discussed with SEM fractography.

  16. Designing of epoxy resin systems for cryogenic use

    Science.gov (United States)

    Ueki, T.; Nishijima, S.; Izumi, Y.

    2005-02-01

    The mechanical and thermal properties of several types of epoxy systems were designed based on the chemical structure, network structure and morphology aiming at cryogenic application. In this research di-epoxies or multifunctional epoxies were cured by several kinds of hardeners such as anhydride, amine or phenol and were blended with polycarbonate, carboxyl-terminated butadiene acrylonitrile copolymer or phenoxy. The mechanical properties and thermal properties of these cured epoxies were measured at room and liquid nitrogen temperature. It was found that the two-dimensional network structured linear polymer shows high performance even at cryogenic temperature. It was concluded that the controls of the structures are very important to optimize epoxy systems for cryogenic application.

  17. Algorithms and analysis for underwater vehicle plume tracing.

    Energy Technology Data Exchange (ETDEWEB)

    Byrne, Raymond Harry; Savage, Elizabeth L. (Texas A& M University, College Station, TX); Hurtado, John Edward (Texas A& M University, College Station, TX); Eskridge, Steven E.

    2003-07-01

    The goal of this research was to develop and demonstrate cooperative 3-D plume tracing algorithms for miniature autonomous underwater vehicles. Applications for this technology include Lost Asset and Survivor Location Systems (L-SALS) and Ship-in-Port Patrol and Protection (SP3). This research was a joint effort that included Nekton Research, LLC, Sandia National Laboratories, and Texas A&M University. Nekton Research developed the miniature autonomous underwater vehicles while Sandia and Texas A&M developed the 3-D plume tracing algorithms. This report describes the plume tracing algorithm and presents test results from successful underwater testing with pseudo-plume sources.

  18. Exploring underwater target detection by imaging polarimetry and correlation techniques.

    Science.gov (United States)

    Dubreuil, M; Delrot, P; Leonard, I; Alfalou, A; Brosseau, C; Dogariu, A

    2013-02-10

    Underwater target detection is investigated by combining active polarization imaging and optical correlation-based approaches. Experiments were conducted in a glass tank filled with tap water with diluted milk or seawater and containing targets of arbitrary polarimetric responses. We found that target estimation obtained by imaging with two orthogonal polarization states always improves detection performances when correlation is used as detection criterion. This experimental study illustrates the potential of polarization imaging for underwater target detection and opens interesting perspectives for the development of underwater imaging systems.

  19. A secure communication suite for underwater acoustic sensor networks.

    Science.gov (United States)

    Dini, Gianluca; Lo Duca, Angelica

    2012-01-01

    In this paper we describe a security suite for Underwater Acoustic Sensor Networks comprising both fixed and mobile nodes. The security suite is composed of a secure routing protocol and a set of cryptographic primitives aimed at protecting the confidentiality and the integrity of underwater communication while taking into account the unique characteristics and constraints of the acoustic channel. By means of experiments and simulations based on real data, we show that the suite is suitable for an underwater networking environment as it introduces limited, and sometimes negligible, communication and power consumption overhead.

  20. Energy Efficiency in Underwater Sensor Networks: a Research Review

    Directory of Open Access Journals (Sweden)

    V. Kanakaris

    2010-01-01

    Full Text Available In an energy-constrained underwater system environment it is very important to find ways to improve the life expectancy ofthe sensors. Compared to the sensors of a terrestrial Ad Hoc Wireless Sensor Network (WSN, underwater sensors cannotuse solar energy to recharge the batteries, and it is difficult to replace the batteries in the sensors. This paper reviews theresearch progress made to date in the area of energy consumption in underwater sensor networks (UWSN and suggestsfurther research that needs to be carried out in order to increase the energy efficiency of the UWSN system.

  1. The cormorant ear – an adaptation to underwater hearing?

    DEFF Research Database (Denmark)

    Larsen, Ole Næsbye; Wahlberg, Magnus; Christensen-Dalsgaard, Jakob

    not know how sensitive their underwater hearing is or even if they respond to underwater sound. Consequently, we do not know if anthropogenic sound affects their hearing during dives. To help filling this gap we measured the audiograms of cormorants (Phalacrocorax carbo sinensis) and studied the ear...... rather poor in-air hearing compared to similar-sized birds. Their underwater hearing sensitivity, however, is higher than what would have been expected for purely air-adapted ears. A possible reason for the poor in-air sensitivity is the special ear anatomy with the central eardrum shaped as a rigid...... piston, which is reminiscent of the turtle ear....

  2. Centralised versus Decentralised Control Reconfiguration for Collaborating Underwater Robots

    DEFF Research Database (Denmark)

    Furno, Lidia; Nielsen, Mikkel Cornelius; Blanke, Mogens

    2015-01-01

    The present paper introduces an approach to fault-tolerant reconfiguration for collaborating underwater robots. Fault-tolerant reconfiguration is obtained using the virtual actuator approach, Steen (2005). The paper investigates properties of a centralised versus a decentralised implementation...... an underwater drill needs to be transported and positioned by three collaborating robots as part of an underwater autonomous operation....... and assesses the capabilities under communication constraints between the individual robots. In the centralised case, each robot sends information related to its own status to a unique virtual actuator that computes the necessary reconfiguration. In the decentralised case, each robot is equipped with its own...

  3. A Secure Communication Suite for Underwater Acoustic Sensor Networks

    Directory of Open Access Journals (Sweden)

    Angelica Lo Duca

    2012-11-01

    Full Text Available In this paper we describe a security suite for Underwater Acoustic Sensor Networks comprising both fixed and mobile nodes. The security suite is composed of a secure routing protocol and a set of cryptographic primitives aimed at protecting the confidentiality and the integrity of underwater communication while taking into account the unique characteristics and constraints of the acoustic channel. By means of experiments and simulations based on real data, we show that the suite is suitable for an underwater networking environment as it introduces limited, and sometimes negligible, communication and power consumption overhead.

  4. Comparison of structural health assessment capabilities in epoxy – carbon black and epoxy – carbon nanotube nanocomposites

    Directory of Open Access Journals (Sweden)

    F. Inam

    2014-01-01

    Full Text Available A novel method for comparing structural health of different types of brittle epoxy nanocomposites filled with carbon nanostructured fillers is presented. Epoxy – 0.2 vol% carbon black (CB and epoxy – 0.2 vol% carbon nanotube (CNT nanocomposite bars were prepared by calendering and thermal curing. Nanocomposite bars were subjected to Vickers diamond indentation to produce sub-surface damage. Electrical conductivities were analysed by 4-point method to estimate the structural damage caused by indentation. For comprehensive comparison, fracture toughness and percolation threshold were analysed as well. Because of the systematically induced indentation damage, a sharp decrease of 89% was observed in the electrical conductivity of epoxy – CNT nanocomposite as compared to 25% in the electrical conductivity of epoxy – CB nanocomposite. CNTs impart superior damage sensing capability in brittle nanocomposite structures, in comparison to CB, due to their high aspect ratio (fibrous nature and high electrical conductivity.

  5. Task Allocation and Path Planning for Collaborative Autonomous Underwater Vehicles Operating through an Underwater Acoustic Network

    Directory of Open Access Journals (Sweden)

    Yueyue Deng

    2013-01-01

    Full Text Available Dynamic and unstructured multiple cooperative autonomous underwater vehicle (AUV missions are highly complex operations, and task allocation and path planning are made significantly more challenging under realistic underwater acoustic communication constraints. This paper presents a solution for the task allocation and path planning for multiple AUVs under marginal acoustic communication conditions: a location-aided task allocation framework (LAAF algorithm for multitarget task assignment and the grid-based multiobjective optimal programming (GMOOP mathematical model for finding an optimal vehicle command decision given a set of objectives and constraints. Both the LAAF and GMOOP algorithms are well suited in poor acoustic network condition and dynamic environment. Our research is based on an existing mobile ad hoc network underwater acoustic simulator and blind flooding routing protocol. Simulation results demonstrate that the location-aided auction strategy performs significantly better than the well-accepted auction algorithm developed by Bertsekas in terms of task-allocation time and network bandwidth consumption. We also demonstrate that the GMOOP path-planning technique provides an efficient method for executing multiobjective tasks by cooperative agents with limited communication capabilities. This is in contrast to existing multiobjective action selection methods that are limited to networks where constant, reliable communication is assumed to be available.

  6. Ultrasonic Transducers for Air and Underwater Communication.

    Science.gov (United States)

    Koosha, Abdolrahim

    Available from UMI in association with The British Library. The performance of a novel radiator capable of producing ultrasonic waves in air and liquids has been investigated. For commercial transducers when operating in air or liquids, impedance matching is the necessary condition for maximum transfer of energy to the medium (thus no standing waves are involved). However, for this radiator the formation of the mechanical standing waves on it is the key condition for directional radiation of energy into the surrounding environment. Under this condition the radiator exhibits a practical conversion of electrical energy into ultrasound. To further improve the performance of the radiator the wavelength coincidence condition must be satisfied. This condition implies that the wavelength of the bending vibration developed on the blade to be the same as that in the medium to which it is coupled. Consequently, an end-fire radiation pattern is obtained. The theory of this when applied to water and also for a double blade configuration are presented. The main component of the radiator consists of a cantilever blade on which a pair of piezoelectric (PZT) ceramic bars are fixed. These the so called excitation gauges, are fixed on both sides of a thin rectangular metal blade near the clamped end. When wavelength coincidence condition is fulfilled, the radiator transmits ultrasonic wave in a highly directional pattern. The direction of propagation of ultrasound is solely steered by frequency of the applied signal. System imperfections such as inter modal coupling when used underwater are considered. An analytical approach is developed to investigate the performance of the radiator for transmission of digital signals in air as well as in water. This method is used to evaluate the efficiency of the device as a suitable means for communication between divers or a diver and an underwater stationary station. Amplitude modulation of speech signals demonstrated the capabilities of a new

  7. Epoxy Sol-Gel Hybrid Thermosets

    Directory of Open Access Journals (Sweden)

    Angels Serra

    2016-02-01

    Full Text Available Sol-gel methodologies are advantageous in the preparation of hybrid materials in front of the conventional addition of nanoparticles, because of the fine dispersion of the inorganic phase that can be reached in epoxy matrices. In addition, the use of organoalkoxysilanes as coupling agents allows covalent linkage between organic and inorganic phases, which is the key point in the improvement of mechanical properties. The sol-gel process involves hydrolysis and condensation reactions under mild conditions, starting from hydrolysable metal alkoxides, generally alkoxy silanes. Using the sol-gel procedure, the viscosity of the formulation is maintained, which is an important issue in coating applications, whereas the transparency of the polymer matrix is also maintained. However, only the proper combination of the chemistries and functionalities of both organic and inorganic structures leads to thermosets with the desired characteristics. The adequate preparation of hybrid epoxy thermosets enables their improvement in characteristics such as mechanical properties (modulus, hardness, scratch resistance, thermal and flame resistance, corrosion and antimicrobial protection, and even optical performance among others.

  8. Digital sonar design in underwater acoustics principles and applications

    CERN Document Server

    Li, Qihu

    2012-01-01

    "Digital Sonar Design in Underwater Acoustics Principles and Applications" provides comprehensive and up-to-date coverage of research on sonar design, including the basic theory and techniques of digital signal processing, basic concept of information theory, ocean acoustics, underwater acoustic signal propagation theory, and underwater signal processing theory. This book discusses the general design procedure and approaches to implementation, the design method, system simulation theory and techniques, sonar tests in the laboratory, lake and sea, and practical validation criteria and methods for digital sonar design. It is intended for researchers in the fields of underwater signal processing and sonar design, and also for navy officers and ocean explorers. Qihu Li is a professor at the Institute of Acoustics, Chinese Academy of Sciences, and an academician of the Chinese Academy of Sciences.

  9. Euclidean reconstruction of natural underwater scenes using optic imagery sequence

    Science.gov (United States)

    Hu, Han

    The development of maritime applications require monitoring, studying and preserving of detailed and close observation on the underwater seafloor and objects. Stereo vision offers advanced technologies to build 3D models from 2D still overlapping optic images in a relatively inexpensive way. However, while image stereo matching is a necessary step in 3D reconstruction procedure, even the most robust dense matching techniques are not guaranteed to work for underwater images due to the challenging aquatic environment. In this thesis, in addition to a detailed introduction and research on the key components of building 3D models from optic images, a robust modified quasi-dense matching algorithm based on correspondence propagation and adaptive least square matching for underwater images is proposed and applied to some typical underwater image datasets. The experiments demonstrate the robustness and good performance of the proposed matching approach.

  10. Underwater color image segmentation method via RGB channel fusion

    Science.gov (United States)

    Xuan, Li; Mingjun, Zhang

    2017-02-01

    Aiming at the problem of low segmentation accuracy and high computation time by applying existing segmentation methods for underwater color images, this paper has proposed an underwater color image segmentation method via RGB color channel fusion. Based on thresholding segmentation methods to conduct fast segmentation, the proposed method relies on dynamic estimation of the optimal weights for RGB channel fusion to obtain the grayscale image with high foreground-background contrast and reaches high segmentation accuracy. To verify the segmentation accuracy of the proposed method, the authors have conducted various underwater comparative experiments. The experimental results demonstrate that the proposed method is robust to illumination, and it is superior to existing methods in terms of both segmentation accuracy and computation time. Moreover, a segmentation technique is proposed for image sequences for real-time autonomous underwater vehicle operations.

  11. Underwater Sensor Networks: A New Energy Efficient and Robust Architecture

    Directory of Open Access Journals (Sweden)

    Juan José Serrano

    2012-01-01

    Full Text Available The specific characteristics of underwater environments introduce new challenges for networking protocols. In this paper, a specialized architecture for underwater sensor networks (UWSNs is proposed and evaluated. Experiments are conducted in order to analyze the suitability of this protocol for the subaquatic transmission medium. Moreover, different scheduling techniques are applied to the architecture in order to study their performance. In addition, given the harsh conditions of the underwater medium, different retransmission methods are combined with the scheduling techniques. Finally, simulation results illustrate the performance achievements of the proposed protocol in end-to-end delay, packet delivery ratio and energy consumption, showing that this protocol can be very suitable for the underwater medium.

  12. Studies on coaxial circular array for underwater transducer applications

    Digital Repository Service at National Institute of Oceanography (India)

    Chakraborty, B.

    This thesis presents analytical methods to study important aspects of a coaxial circular array for wideband underwater transducer application. It begins with detailed theoretical study of a coaxial circular array of three turns and an analysis...

  13. Acoustic Model of the Remnant Bubble Cloud from Underwater Explosion

    Science.gov (United States)

    2012-11-01

    oceanography, Sydney, Academic Press. Underwater Explosion Research 1950, Office of Naval Re- search, Washington, D.C., Vol. 2. Wilcox, DC 1994, Turbulence Modeling for CFD, DCW Industries, Inc., La Canada CA.

  14. Time domain dispersion of underwater optical wireless communication

    Institute of Scientific and Technical Information of China (English)

    Wei Wei; Xiaohui Zhang; Jionghui Rao; Wenbo Wang

    2011-01-01

    @@ A new method to count the expected value and variance of time dispersion is presented for time dispersion of underwater optical wireless communication.Instead of the typically used Gamma distribution, inverse-Gaussian distribution is suggested for underwater optical impulse response time waveform function.The expectation of this method is in good agreement with experimental data.Future works may include water absorption to the model.%A new method to count the expected value and variance of time dispersion is presented for time dispersion of underwater optical wireless communication.Instead of the typically used Gamma distribution, inverseGaussian distribution is suggested for underwater optical impulse response time waveform function.The expectation of this method is in good agreement with experimental data.Future works may include water absorption to the model.

  15. Virtual Diving in the Underwater Archaeological Site of Cala Minnola

    Science.gov (United States)

    Bruno, F.; Lagudi, A.; Barbieri, L.; Muzzupappa, M.; Mangeruga, M.; Pupo, F.; Cozza, M.; Cozza, A.; Ritacco, G.; Peluso, R.; Tusa, S.

    2017-02-01

    The paper presents the application of the technologies and methods defined in the VISAS project for the case study of the underwater archaeological site of Cala Minnola located in the island of Levanzo, in the archipelago of the Aegadian Islands (Sicily, Italy). The VISAS project (http://visas-project.eu) aims to improve the responsible and sustainable exploitation of the Underwater Cultural Heritage by means the development of new methods and technologies including an innovative virtual tour of the submerged archaeological sites. In particular, the paper describes the 3D reconstruction of the underwater archaeological site of Cala Minnola and focus on the development of the virtual scene for its visualization and exploitation. The virtual dive of the underwater archaeological site allows users to live a recreational and educational experience by receiving historical, archaeological and biological information about the submerged exhibits, the flora and fauna of the place.

  16. Collision Avoidance of Moving Obstacles for Underwater Robots

    Directory of Open Access Journals (Sweden)

    KWON KYOUNG YOUB

    2006-10-01

    Full Text Available A fuzzy logic for autonomous navigation of underwater robot is proposed in this paper. The VFF(Virtual Force Field algorithm, which is widely used in the field of mobile robot, is modified for application to the autonomous navigation of underwater robot. This Modified Virtual Force Field(MVFF algorithm using the fuzzy logic can be used in either track keeping or obstacle avoidance. Fuzzy logics are devised to handle various situations which can be faced during autonomous navigation of underwater robot. A graphic simulator based on OpenGL for an autonomous navigation has been developed. The good performance of the proposed MVFF algorithm is verified through computer simulations on an underwater robot.

  17. Design, Development and Testing of Underwater Vehicles: ITB Experience

    CERN Document Server

    Muljowidodo, Said D; Budiyono, Agus; Nugroho, Sapto A

    2008-01-01

    The last decade has witnessed increasing worldwide interest in the research of underwater robotics with particular focus on the area of autonomous underwater vehicles (AUVs). The underwater robotics technology has enabled human to access the depth of the ocean to conduct environmental surveys, resources mapping as well as scientific and military missions. This capability is especially valuable for countries with major water or oceanic resources. As an archipelagic nation with more than 13,000 islands, Indonesia has one of the most abundant living and non-organic oceanic resources. The needs for the mapping, exploration, and environmental preservation of the vast marine resources are therefore imperative. The challenge of the deep water exploration has been the complex issues associated with hazardous and unstructured undersea and sea-bed environments. The paper reports the design, development and testing efforts of underwater vehicle that have been conducted at Institut Teknologi Bandung. Key technology areas...

  18. Multi-layer protective armour for underwater shock wave mitigation

    Directory of Open Access Journals (Sweden)

    Ahmed Hawass

    2015-12-01

    The strain gauge data and displacement sensors results showed that the multi-layer plates have higher level of underwater shock wave mitigation than the triple aluminum plates with strain and deflection of nearly 50%.

  19. Dispersive waves generated by an underwater landslide

    CERN Document Server

    Dutykh, Denys; Beysel, Sonya; Shokina, Nina; Khakimzyanov, Gayaz

    2011-01-01

    In this work we study the generation of water waves by an underwater sliding mass. The wave dynamics are assumed to fell into the shallow water regime. However, the characteristic wavelength of the free surface motion is generally smaller than in geophysically generated tsunamis. Thus, dispersive effects need to be taken into account. In the present study the fluid layer is modeled by the Peregrine system modified appropriately and written in conservative variables. The landslide is assumed to be a quasi-deformable body of mass whose trajectory is completely determined by its barycenter motion. A differential equation modeling the landslide motion along a curvilinear bottom is obtained by projecting all the forces acting on the submerged body onto a local moving coordinate system. One of the main novelties of our approach consists in taking into account curvature effects of the sea bed.

  20. Transducers and arrays for underwater sound

    CERN Document Server

    Butler, John L

    2016-01-01

    This improved and updated second edition covers the theory, development, and design of electro-acoustic transducers for underwater applications. This highly regarded text discusses the basics of piezoelectric and magnetostrictive transducers that are currently being used as well as promising new designs. It presents the basic acoustics as well as the specific acoustics data needed in transducer design and evaluation. A broad range of designs of projectors and hydrophones are described in detail along with methods of modeling, evaluation, and measurement. Analysis of projector and hydrophone transducer arrays, including the effects of mutual radiation impedance and numerical models for elements and arrays, are also covered. The book includes new advances in transducer design and transducer materials and has been completely reorganized to be suitable for use as a textbook, as well as a reference or handbook. The new edition contains updates to the first edition, end-of-chapter exercises, and solutions to select...

  1. Broadband solid cloak for underwater acoustics

    CERN Document Server

    Chen, Yi; Liu, Xiaoning; Bi, Yafeng; Sun, Zhaoyong; Xiang, Ping; Yang, Jun; Hu, Gengkai

    2016-01-01

    Shielding an object to be undetectable is an important issue for engineering applications. Cloaking is the ultimate shielding example, routing waves around an object without mutual interaction, demonstrated as possible in principle by transformation and metamaterial techniques. Example applications have been successfully designed and validated for electromagnetic wave, thin plate flexural wave, thermal flux, and airborne sound. However, for underwater acoustics, the commonly used scheme based on meta-fluids with anisotropic density for airborne sound is unworkable since an acoustic rigid material is required with mass density three orders of magnitude higher than water. Material with such high density is impossible using even the heaviest metal, and may suffer from a narrow working frequency band even if realized with locally resonant techniques. An alternative solution was recently suggested based on solid pentamode material, which can be impedance matched with water and has anisotropic modulus. Here, we rep...

  2. Silent Localization of Underwater Sensors Using Magnetometers

    Directory of Open Access Journals (Sweden)

    Jonas Callmer

    2010-01-01

    Full Text Available Sensor localization is a central problem for sensor networks. If the sensor positions are uncertain, the target tracking ability of the sensor network is reduced. Sensor localization in underwater environments is traditionally addressed using acoustic range measurements involving known anchor or surface nodes. We explore the usage of triaxial magnetometers and a friendly vessel with known magnetic dipole to silently localize the sensors. The ferromagnetic field created by the dipole is measured by the magnetometers and is used to localize the sensors. The trajectory of the vessel and the sensor positions are estimated simultaneously using an Extended Kalman Filter (EKF. Simulations show that the sensors can be accurately positioned using magnetometers.

  3. Advanced Applications for Underwater Acoustic Modeling

    Directory of Open Access Journals (Sweden)

    Paul C. Etter

    2012-01-01

    Full Text Available Changes in the ocean soundscape have been driven by anthropogenic activity (e.g., naval-sonar systems, seismic-exploration activity, maritime shipping and windfarm development and by natural factors (e.g., climate change and ocean acidification. New regulatory initiatives have placed additional restrictions on uses of sound in the ocean: mitigation of marine-mammal endangerment is now an integral consideration in acoustic-system design and operation. Modeling tools traditionally used in underwater acoustics have undergone a necessary transformation to respond to the rapidly changing requirements imposed by this new soundscape. Advanced modeling techniques now include forward and inverse applications, integrated-modeling approaches, nonintrusive measurements, and novel processing methods. A 32-year baseline inventory of modeling techniques has been updated to reflect these new developments including the basic mathematics and references to the key literature. Charts have been provided to guide soundscape practitioners to the most efficient modeling techniques for any given application.

  4. Transducers and Arrays for Underwater Sound

    CERN Document Server

    Sherman, Charles H

    2007-01-01

    This book is concerned with the theory, development and design of electroacoustic transducers for underwater applications, and is more comprehensive than any existing book in this field. It includes the basics of the six major types of electroacoustic transducers, with emphasis on the piezoelectric ceramic transducers that are currently most widely used. It presents the basic acoustics, as well as specific acoustic data, needed in transducer design and includes analysis of nonlinear effects in transducers. A large number of specific transducer designs, including both projectors and hydrophones, are described in detail as well as methods of modeling, evaluation and measurement. Analysis of transducer arrays, including the effects of mutual radiation impedance, as well as numerical models for transducers and arrays are also covered. The book contains an extensive Appendix of useful current information, including data on the latest transduction materials, and numerous diagrams that will facilitate its use by stu...

  5. Energy System selection for Small Underwater Vehicles

    Institute of Scientific and Technical Information of China (English)

    G.T.Reader; J.G.Hawley; 等

    1994-01-01

    The oceans cover almost three-quarters of the earth's surface and provide a highway for commerce or conquest and constitute a rich source of nutrients.materials and emergy.The exploration and exploitation of oceanic resources accelerated in the 1970s because of the merging offshore oil and gas industry.The extraction and national protection of these and other resources will increase rapidly in the next century and in support of these activities one of the most useful tools will be the small underwater vehicle.However,if these vehicles are to carry out the envisageed tasks in a cost-effective and mission-effective manner they will require high performance energy systems.A number of such systems are being developed and the problem arises as which one to select for a particular task.In this paper the development of software based techniques for the selection of energy systems is described.

  6. Underwater Explosion Damage of Ship Hull Panels

    Directory of Open Access Journals (Sweden)

    K. Rarnajeyathilagam

    2003-10-01

    Full Text Available Underwater explosion is a major threat to ships and submarines in a war environment. The prediction of the mode and the extent of the failure is an essential step in designing for shock loading. The localised failure in a hull panel is severe compared to the global response of the ship. In this study, an attempt has been made to predict the response and failure modes of three types of hull panels (flat, concave, and convex. The shock loading on the hull panel has been estimated based on the Taylor's plate theory. The numerical analysis has been carried out using the CSAIGENSA (DYNA3D code that employs nonlinear finite element model.

  7. Plasma generated during underwater pulsed laser processing

    Science.gov (United States)

    Hoffman, Jacek; Chrzanowska, Justyna; Moscicki, Tomasz; Radziejewska, Joanna; Stobinski, Leszek; Szymanski, Zygmunt

    2017-09-01

    The plasma induced during underwater pulsed laser ablation of graphite is studied both experimentally and theoretically. The results of the experiment show that the maximum plasma temperature of 25000 K is reached 20 ns from the beginning of the laser pulse and decreases to 6500 K after 1000 ns. The observed OH absorption band shows that the plasma plume is surrounded by the thin layer of dissociated water vapour at a temperature around 5500 K. The hydrodynamic model applied shows similar maximum plasma temperature at delay times between 14 ns and 30 ns. The calculations show also that already at 14th ns, the plasma electron density reaches 0.97·1027 m-3, which is the critical density for 1064 nm radiation. At the same time the plasma pressure is 2 GPa, which is consisted with earlier measurements of the peak pressure exerted on a target in similar conditions.

  8. Numerical Simulation of Underwater Explosion Loads

    Institute of Scientific and Technical Information of China (English)

    XIN Chunliang; XU Gengguang; LIU Kezhong

    2008-01-01

    Numerical simulation of TNT underwater explosion was carried out with AUTODYN software.Influences of artificial viscosity and mesh density on simulation results were discussed.Detonation waves in explosive and shock wave in water during early time of explosion are high frequency waves.Fine meshes (less than 1 mm) in explosive and water nearby,and small linear viscosity coefficients and quadratic viscosity coefficients (0.02 and 0.1 respectively,1/10 of default values) are needed in numerical simulation model.According to these rules,numerical computing pressure profiles can match well with those calculated by Zamyshlyayev empirical formula.Otherwise peak pressure would be smeared off and upstream relative errors would be cumulated downstream to make downstream peak pressure lower.

  9. Adaptive control of nonlinear underwater robotic systems

    Directory of Open Access Journals (Sweden)

    Thor I. Fossen

    1991-04-01

    Full Text Available The problem of controlling underwater mobile robots in 6 degrees of freedom (DOF is addressed. Uncertainties in the input matrix due to partly known nonlinear thruster characteristics are modeled as multiplicative input uncertainty. This paper proposes two methods to compensate for the model uncertainties: (1 an adaptive passivity-based control scheme and (2 deriving a hybrid (adaptive and sliding controller. The hybrid controller consists of a switching term which compensates for uncertainties in the input matrix and an on-line parameter estimation algorithm. Global stability is ensured by applying Barbalat's Lyapunovlike lemma. The hybrid controller is simulated for the horizontal motion of the Norwegian Experimental Remotely Operated Vehicle (NEROV.

  10. Progress toward Making Epoxy/Carbon-Nanotube Composites

    Science.gov (United States)

    Tiano, Thomas; Roylance, Margaret; Gassner, John; Kyle, William

    2008-01-01

    A modicum of progress has been made in an effort to exploit single-walled carbon nanotubes as fibers in epoxy-matrix/fiber composite materials. Two main obstacles to such use of carbon nanotubes are the following: (1) bare nanotubes are not soluble in epoxy resins and so they tend to agglomerate instead of becoming dispersed as desired; and (2) because of lack of affinity between nanotubes and epoxy matrices, there is insufficient transfer of mechanical loads between the nanotubes and the matrices. Part of the effort reported here was oriented toward (1) functionalization of single-walled carbon nanotubes with methyl methacrylate (MMA) to increase their dispersability in epoxy resins and increase transfer of mechanical loads and (2) ultrasonic dispersion of the functionalized nanotubes in tetrahydrofuran, which was used as an auxiliary solvent to aid in dispersing the functionalized nanotubes into a epoxy resin. In another part of this effort, poly(styrene sulfonic acid) was used as the dispersant and water as the auxiliary solvent. In one experiment, the strength of composite of epoxy with MMA-functionalized-nanotubes was found to be 29 percent greater than that of a similar composite of epoxy with the same proportion of untreated nanotubes.

  11. Autonomous underwater vehicles modeling, control design and simulation

    CERN Document Server

    Wadoo, Sabiha

    2010-01-01

    Underwater vehicles present some difficult and very particular control system design problems. These are often the result of nonlinear dynamics and uncertain models, as well as the presence of sometimes unforeseeable environmental disturbances that are difficult to measure or estimate. Autonomous Underwater Vehicles: Modeling, Control Design, and Simulation outlines a novel approach to help readers develop models to simulate feedback controllers for motion planning and design. The book combines useful information on both kinematic and dynamic nonlinear feedback control models, providing simula

  12. RAO-II: an AUV for underwater inspection

    OpenAIRE

    Oliver, G.; Ortiz, A.; Bonin, F.

    2008-01-01

    AIRSUB is a research project funded by the Spanish Ministry of Science and Technology whose aim is to explore the industrial applications of underwater robots. The Systems, Robotics and Vision Group (SRV) from the University of the Balearic Islands (UIB) is responsible for the subproject of cable/pipeline inspection [1]. To this purpose, an Autonomous Underwater Vehicle (AUV) is under development as a platform to test the vision algorithms, control strategies and software ar...

  13. Moving in extreme environments: inert gas narcosis and underwater activities

    OpenAIRE

    Clark, James E

    2015-01-01

    Exposure to the underwater environment for pleasure or work poses many challenges on the human body including thermal stress, barotraumas, decompression sickness as well as the acute effects of breathing gases under pressure. With the popularity of recreational self-contained underwater breathing apparatus (SCUBA) diving on the increase and deep inland dive sites becoming more accessible, it is important that we understand the effects of breathing pressurised gas at depth can have on the body...

  14. A Secure Communication Suite for Underwater Acoustic Sensor Networks

    OpenAIRE

    Angelica Lo Duca; Gianluca Dini

    2012-01-01

    In this paper we describe a security suite for Underwater Acoustic Sensor Networks comprising both fixed and mobile nodes. The security suite is composed of a secure routing protocol and a set of cryptographic primitives aimed at protecting the confidentiality and the integrity of underwater communication while taking into account the unique characteristics and constraints of the acoustic channel. By means of experiments and simulations based on real data, we show that the suite is suitable f...

  15. Reliable data delivery protocols for underwater sensor networks

    OpenAIRE

    Nowsheen, Nusrat

    2017-01-01

    Underwater Acoustic Sensor Networks (UASNs) are becoming increasingly promising to monitor aquatic environment. The network is formed by deploying a number of sensor nodes and/or Autonomous Underwater Vehicles (AUVs) to support diverse applications such as pollution monitoring, oceanographic data collection, disaster recovery and surveillance. These applications require transmission of data packets from the source to a sink or gateway in a multihop fashion and eventually to a message ferry or...

  16. Application of Mellin Transform in Wideband Underwater Acoustic Signal Processing

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    According to the features of the wideband underwater acoustic signals, an algorithm for the wideband ambiguity function is put forward based on Mellin transform. The wideband acoustic signal processing using the fast Mellin transform is also explored. The theoretical analysis and simulation results show that the algorithm has not only high computation efficiency but also good concentration in wideband ambiguity domain. It suits for the wideband underwater acoustic signal processing.

  17. Modeling, Control and Energy Efficiency of Underwater Snake Robots

    OpenAIRE

    Kelasidi, Eleni

    2015-01-01

    This thesis is mainly motivated by the attribute of the snake robots that they are able to move over land as well as underwater while the physiology of the robot remains the same. This adaptability to different motion demands depending on the environment is one of the main characteristics of the snake robots. In particular, this thesis targets several interesting aspects regarding the modeling, control and energy efficiency of the underwater snake robots. This thesis address...

  18. Strong tracking adaptive Kalman filters for underwater vehicle dead reckoning

    Institute of Scientific and Technical Information of China (English)

    XIAO Kun; FANG Shao-ji; PANG Yong-jie

    2007-01-01

    To improve underwater vehicle dead reckoning, a developed strong tracking adaptive kalman filter is proposed. The filter is improved with an additional adaptive factor and an estimator of measurement noise covariance. Since the magnitude of fading factor is changed adaptively, the tracking ability of the filter is still enhanced in low velocity condition of underwater vehicles. The results of simulation tests prove the presented filter effective.

  19. A sidelobe suppression method with experiment for underwater acoustic imaging

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    In this paper,a sidelobe suppression method using nonuniformly spaced array with aperture apodization processing is proposed for underwater acoustic imaging in near field,which is studied both in theory and experiment.The focused beamforming based on spherical wave propagation theory is used in the method.Firstly,the nonuniform array with low sidelobe is designed for suppressing the sidelobe of one-way beam pattern by spacing perturbation.Then, applying the aperture apodization technique to underwater ac...

  20. Optimal Scheduling for Underwater Communications in Multiple-User Scenarios

    Science.gov (United States)

    2015-09-30

    investigate the possibility that these underwater acoustic networks disrupt the behavior of surrounding species of marine mammals . As a consequence of...In order to investigate the possibility that underwater acoustic communications disrupt behaviors of surrounding marine mammals , we identified the...programming algorithm, which requires to define a dynamic system model, whose evolution depends on both a random process, in our case the channel quality

  1. Design of a modular autonomous underwater vehicle for archaeological investigations

    OpenAIRE

    Reggiannini, Marco; Pascali, Maria Antonietta; Moroni, Davide; Salvetti, Ovidio; Allotta,Benedetto; Bartolini, Fabio; Bellavia, Fabio; Colombo, Carlo; Conti, Roberto; Costanzi, Riccardo; Fanfani, Marco; Gelli, Jonathan; Monni, Niccol?; Natalini, Marco; Pazzaglia, Fabio

    2015-01-01

    MARTA (MARine Tool for Archaeology) is a modular AUV (Autonomous Underwater Vehicle) designed and developed by the University of Florence in the framework of the ARROWS (ARchaeological RObot systems for the World's Seas) FP7 European project. The ARROWS project challenge is to provide the underwater archaeologists with technological tools for cost affordable campaigns: i.e. ARROWS adapts and develops low cost AUV technologies to significantly reduce the cost of archaeological operations, cove...

  2. Autonomous Underwater Munitions and Explosives of Concern Detection System

    Science.gov (United States)

    2015-03-01

    MR-201002) Autonomous Underwater Munitions and Explosives of Concern Detection System March 2015 This document has been... Autonomous Underwater Munitions and Explosives of Concern Detection System 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR...Certification Program (ESTCP), 4800 Mark Center Drive , Suite 17D08,Alexandria,VA,22350-3605 8. PERFORMING ORGANIZATION REPORT NUMBER 9. SPONSORING

  3. Feasibility of underwater friction stir welding of HY-80 steel

    OpenAIRE

    Stewart, William Chad

    2011-01-01

    Approved for public release; distribution is unlimited. The purpose of this thesis is to determine the feasibility of underwater friction stir welding (FSW) of high-strength; quench and temper low carbon steels that are susceptible to hydrogen-assisted cracking (HAC). The specific benefits of underwater FSW would be weld repairs of ship and submarine control surfaces and hulls without the need for drydocking and extensive environmental control procedures. A single tool of polycrystallin...

  4. Development and Characterization of Novel Interpenetrating Network (IPN Foams from Epoxy Ester and Aliphatic Epoxy Resin

    Directory of Open Access Journals (Sweden)

    Kanuprasad Patel

    2009-01-01

    Full Text Available Diglycidyl ether of bisphenol-A (DGEBA was reacted with acrylate monomer at variable molar ratios. The reaction between glycerine and epichlorohydrine form glycidyl ether of polyol aliphatic epoxy resin. The resultant resins were characterized duly. Both the resins were mixed at different ratios with constant high shear stirring. The obtained mixture and suitable additives were heated at 150oC for one and half hour. The so called Interpenetrating Network (IPN transformed into foams. The performance of foams was evaluated by testing for compression in both parallel and perpendicular to rise direction. The tests were carried out at room temperature and at the elevated temperature. The compression properties showed a decreasing trend for increasing amounts of glycerine resin. The density and thermal properties of epoxy foams were also evaluated. The relation between the composition, density and properties of the foam was analyzed.

  5. Development of a Lobster-Inspired Underwater Microrobot

    Directory of Open Access Journals (Sweden)

    Liwei Shi

    2013-01-01

    Full Text Available Biomimetic underwater microrobots are of great interest for underwater monitoring operations, such as pollution detection and video mapping in restricted underwater environments. Generally speaking, compact structure, multi‐functionality, flexibility and precise positioning are considered incompatible characteristics for underwater microrobots. Nevertheless, we have designed several novel types of bio‐inspired locomotion, using ionic polymer metal composite (IPMC and shape memory alloy (SMA actuators. We reviewed a number of previously developed underwater microrobot prototypes that were constructed to demonstrate the feasibility of these types of biomimetic locomotion. Based on these prototypes, we summarized the implemented techniques and available results for efficient and precise underwater locomotion. In order to combine compact structure, multi‐functionality, flexibility and precise positioning, we constructed a prototype of a new lobster‐like microrobot and carried out a series of experiments to evaluate its walking, rotating, floating and grasping motions. Diving/surfacing experiments were performed by electrolyzing the water around the surfaces of the actuators. Three proximity sensors were installed on the microrobot to detect an object or avoid an obstacle while walking.

  6. Optimal Node Placement in Underwater Acoustic Sensor Network

    KAUST Repository

    Felemban, Muhamad

    2011-10-01

    Almost 70% of planet Earth is covered by water. A large percentage of underwater environment is unexplored. In the past two decades, there has been an increase in the interest of exploring and monitoring underwater life among scientists and in industry. Underwater operations are extremely difficult due to the lack of cheap and efficient means. Recently, Wireless Sensor Networks have been introduced in underwater environment applications. However, underwater communication via acoustic waves is subject to several performance limitations, which makes the relevant research issues very different from those on land. In this thesis, we investigate node placement for building an initial Underwater Wireless Sensor Network infrastructure. Firstly, we formulated the problem into a nonlinear mathematic program with objectives of minimizing the total transmission loss under a given number of sensor nodes and targeted volume. We conducted experiments to verify the proposed formulation, which is solved using Matlab optimization tool. We represented each node with a truncated octahedron to fill out the 3D space. The truncated octahedrons are tiled in the 3D space with each node in the center where locations of the nodes are given using 3D coordinates. Results are supported using ns-3 simulator. Results from simulation are consistent with the obtained results from mathematical model with less than 10% error.

  7. Underwater and in-air sounds from a small hovercraft

    Science.gov (United States)

    Blackwell, Susanna B.; Greene, Charles R.

    2005-12-01

    Underwater and in-air recordings were made from a boat anchored near Prudhoe Bay, Alaska, while a Griffon 2000TD hovercraft drove by at or near full power on four passes. At the closest point of approach (CPA, 6.5 m), underwater broadband (10-10 000 Hz) levels reached 133 and 131 dB re: 1 μPa at depths of 1 and 7 m, respectively. In-air unweighted and A-weighted broadband (10-10 000 Hz) levels reached 104 and 97 dB re: 20 μPa, respectively. The hovercraft produced sound at a wide range of frequencies. Both underwater and in air, the largest spectral peak was near 87 Hz, which corresponded to the blade rate of the thrust propeller. In addition, the spectral composition included several harmonics of this frequency. The shaft or blade rate of the lift fan was barely detectable underwater despite its proximity to the water. The hovercraft was considerably quieter underwater than similar-sized conventional vessels and may be an attractive alternative when there is concern over underwater sounds.

  8. A Biological Hierarchical Model Based Underwater Moving Object Detection

    Directory of Open Access Journals (Sweden)

    Jie Shen

    2014-01-01

    Full Text Available Underwater moving object detection is the key for many underwater computer vision tasks, such as object recognizing, locating, and tracking. Considering the super ability in visual sensing of the underwater habitats, the visual mechanism of aquatic animals is generally regarded as the cue for establishing bionic models which are more adaptive to the underwater environments. However, the low accuracy rate and the absence of the prior knowledge learning limit their adaptation in underwater applications. Aiming to solve the problems originated from the inhomogeneous lumination and the unstable background, the mechanism of the visual information sensing and processing pattern from the eye of frogs are imitated to produce a hierarchical background model for detecting underwater objects. Firstly, the image is segmented into several subblocks. The intensity information is extracted for establishing background model which could roughly identify the object and the background regions. The texture feature of each pixel in the rough object region is further analyzed to generate the object contour precisely. Experimental results demonstrate that the proposed method gives a better performance. Compared to the traditional Gaussian background model, the completeness of the object detection is 97.92% with only 0.94% of the background region that is included in the detection results.

  9. Effect of Glass Reinforced Epoxy (GRE) pipe filled with Geopolymer Materials for Piping Application: Compression Properties

    OpenAIRE

    2016-01-01

    The aim of this paper is to achieve the highest compressive strength of glass reinforced epoxy pipe with the geopolymer filler content of weight percentage that were used in glass reinforced epoxy pipe. The samples were prepared by using the filament winding method. The effect of weight percentage of geopolymer materials in epoxy hardener was studied under mechanical testing, which is using the compression test. A series of glass reinforced epoxy pipe and glass reinforced epoxy pipe filled wi...

  10. Thermomechanical Behavior of High Performance Epoxy/Organoclay Nanocomposites

    Directory of Open Access Journals (Sweden)

    Artur Soares Cavalcanti Leal

    2014-01-01

    Full Text Available Nanocomposites of epoxy resin containing bentonite clay were fabricated to evaluate the thermomechanical behavior during heating. The epoxy resin system studied was prepared using bifunctional diglycidyl ether of bisphenol A (DGEBA, crosslinking agent diaminodiphenylsulfone (DDS, and diethylenetriamine (DETA. The purified bentonite organoclay (APOC was used in all experiments. The formation of nanocomposite was confirmed by X-ray diffraction analysis. Specimens of the fabricated nanocomposites were characterized by dynamic mechanical analysis (DMA. According to the DMA results a significant increase in glass transition temperature and storage modulus was evidenced when 1 phr of clay is added to epoxy resin.

  11. Realtime 3D stress measurement in curing epoxy packaging

    DEFF Research Database (Denmark)

    Richter, Jacob; Hyldgård, A.; Birkelund, Karen;

    2007-01-01

    This paper presents a novel method to characterize stress in microsystem packaging. A circular p-type piezoresistor is implemented on a (001) silicon chip. We use the circular stress sensor to determine the packaging induced stress in a polystyrene tube filled with epoxy. The epoxy curing process...... is monitored by stress measurements. From the stress measurements we conclude that the epoxy cures in 8 hours at room temperature. We find the difference in in-plane normal stresses to be sigmaxx-sigmayy=6.7 MPa and (sigmaxx+sigmayy-0.4sigmazz)=232 MPa....

  12. Wear behaviour of epoxy resin filled with hard powders

    Science.gov (United States)

    Formisano, A.; Boccarusso, L.; Minutolo, F. Capece; Carrino, L.; Durante, M.; Langella, A.

    2016-10-01

    The development of high performance materials based on epoxy resin finds a growing number of applications in which high wear resistance is required. One major drawback in many of these applications is the relatively poor wear resistance of the epoxy resin. Therefore, in order to investigate on the possibility of increasing wear resistance of thermoset polymers filled with hard powders, sliding tests are carried out by means of a pin on disc apparatus. In particular, composite resins, constituted by an epoxy resin filled with different contents and sizes of Silicon Carbide powder, are analyzed; the wear resistance, in terms of volume loss, is measured for different abrasive counterfaces and loads.

  13. Hansen solubility parameters for a carbon fiber/epoxy composite

    DEFF Research Database (Denmark)

    Launay, Helene; Hansen, Charles M.; Almdal, Kristoffer

    2007-01-01

    In this study, the physical affinity between an epoxy matrix and oxidized, unsized carbon fibers has been evaluated using Hansen solubility (cohesion) parameters (HSP). A strong physical compatibility has been shown, since their respective HSP are close. The use of a glassy carbon substrate...... as a model for unsized carbon fiber has been demonstrated as appropriate for the study of interactions between the materials in composite carbon fiber-epoxy systems. The HSP of glassy carbon are similar to those of carbon fibers and epoxy matrix. (C) 2007 Elsevier Ltd. All rights reserved....

  14. Contactless optoelectronic technique for monitoring epoxy cure.

    Science.gov (United States)

    Cusano, A; Buonocore, V; Breglio, G; Calabrò, A; Giordano, M; Cutolo, A; Nicolais, L

    2000-03-01

    We describe a novel noninvasive optical technique to monitor the refractive-index variation in an epoxy-based resin that is due to the polymerization process. This kind of resin is widely used in polymer matrix composites. It is well known that the process of fabricating a thermoset-based composite involves mass and heat transfer coupled with irreversible chemical reactions that induce physical changes. To improve the quality and the reliability of these materials, monitoring the cure and optimization of the manufacturing process are of key importance. We discuss the basic operating principles of an optical system based on angle deflection measurements and present typical cure-monitoring results obtained from optical characterization. The method provides a flexible, high-sensitivity, material-independent, low-cost, noninvasive tool for monitoring real-time refractive-index variation.

  15. Epoxy resins used to seal brachytherapy seed

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Natalia Carolina Camargos; Ferraz, Wilmar Barbosa; Reis, Sergio Carneiro dos; Santos, Ana Maria Matildes dos, E-mail: nccf@cdtn.br, E-mail: ferrazw@cdtn.br, E-mail: reissc@cdtn.br, E-mail: amms@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, BH (Brazil)

    2013-07-01

    Prostate cancer treatment with brachytherapy is recommended for patients with cancer at an early stage. In this treatment, small radioactive seeds are implanted directly in the prostate gland. These seeds are composed at least of one radionuclide carrier and an X-ray marker enclosed within a metallic tube usually sealed by laser process. This process is expensive and, furthermore, it can provoke a partial volatilization of the radionuclide and change the isotropy in dose distribution around the seed. In this paper, we present a new sealing process using epoxy resin. Three kinds of resins were utilized and characterized by scanning electron microscopy (SEM), energy dispersive X ray (EDS) and by differential scanning calorimetry (DSC) after immersion in simulated body fluid (SBF) and in sodium iodine solution (NaI). The sealing process showed excellent potential to replace the sealing laser usually employed. (author)

  16. Organic fiber/epoxy pressure vessels

    Science.gov (United States)

    Chiao, T. T.; Hamstad, M. A.; Marcon, M. A.

    1974-01-01

    We evaluated the performance of an organic fiber in an epoxy matrix by winding 20-cm diam spherical and cylindrical pressure vessels of various designs. For the spherical vessels, we used soft aluminum liners 0.76 mm thick for a double boss design and 2 mm thick for a single boss design. For the cylindrical vessels, we used both 0.5-mm rubber liners and 0.76-mm soft aluminum liners. Vessels of both types were tested for burst pressure and cyclic fatigue at room temperature and liquid hydrogen temperature. The effects of temperature and vessel shape on the vessel performance factor were negligible. Our vessel fatigue data were marred by premature failure of the liners.

  17. Curing of Epoxy Resin Induced by Femtosecond Laser Pulse

    Institute of Scientific and Technical Information of China (English)

    LI Yubin; ZHANG Zuoguang

    2005-01-01

    The possibility of curing of epoxy resin induced by femtosecond laser beam was explored through choosing different initiators . Absorption spectroscopy, infrared spectroscopy (IR), stereomicroscopy and scanning electron microscopy (SEM) were applied to analyze the structure of epoxy resin systems after irradiation with a femtosecond laser beam. The experimental results show that the epoxy resin systems containing diaryliodonium salts can be cured by irradiation of Jemtosecond laser pulse, while the systems containing benzoin can not be cured. It is found that diaryliodonium salts decompose under the irradiation of femtosecond laser pulse through multi ( two ) -photon absorption, initiating the ring-opening polymerization of epoxy resin. And the appearance of cured area has a sheet structure consisting of many tiny lamellar structures.

  18. Dispersion and reinforcing mechanism of carbon nanotubes in epoxy nanocomposites

    Indian Academy of Sciences (India)

    Smrutisikha Bal

    2010-02-01

    Carbon nanotube based epoxy composites have been fabricated at room temperature and refrigeration process using sonication principle. Flexural moduli, electrical conductivity, glass transition temperature of epoxy resin as well as nanocomposite samples have been determined. Distribution behaviour of carbon nanotubes in the epoxy matrix was examined through scanning electron microscopy. Composite samples showed better properties than resin samples due to strengthening effect of the filled nanotubes. Refrigerated nanocomposites obtained increasing mechanical property because of better dispersion due to low temperature settlement of polymers. Improvement of electrical conductivity was due to the fact that aggregated phases form a conductive three-dimensional network throughout the whole sample. The increasing glass transition temperature was indicative of restricting movement of polymer chains that ascribe strong interaction presented between carbon nanotubes and epoxy chains that was again supplemented by Raman study and SEM.

  19. Autonomic healing of carbon fiber/epoxy interfaces.

    Science.gov (United States)

    Jones, Amanda R; Cintora, Alicia; White, Scott R; Sottos, Nancy R

    2014-05-14

    A maximum of 91% recovery of interfacial shear strength (IFSS) is achieved for carbon fiber/epoxy interfaces functionalized with capsules containing reactive epoxy resin and ethyl phenyl acetate (EPA). We find a binder is necessary to improve the retention of capsules on the carbon fiber surface. Two different methods for applying the binder to the carbon fiber surface are investigated. Healing efficiency is assessed by recovery of IFSS of a single functionalized fiber embedded in a microdroplet of epoxy. Debonding of the fiber/matrix interface ruptures the capsules, releasing resin and EPA solvent into the crack plane. The solvent swells the matrix, initiating transport of residual amine functionality from the matrix for further curing with the epoxy resin delivered to the crack plane. The two binder protocols produce comparable results, both yielding higher recovery of IFSS than samples prepared without a binder.

  20. Epoxy resin developments for large superconducting magnets impregnation

    Science.gov (United States)

    Rey, J. M.; Gallet, B.; Kircher, F.; Lottin, J. C.

    The future detectors ATLAS and CMS of the Large Hadron Collider at CERN will use two huge superconducting magnets. Both are now under design, and their electrical insulation could be realized using epoxy resin and a wet impregnation technique. Because of their large dimensions, and the indirect cooling of the superconductor, the strengths of the resin and of the resin/conductor interface are of major importance. A new generation of epoxy resins for vacuum/pressure impregnation methods has been tested, and compared with some classical and well-known epoxy resins used in impregnation techniques. In order to understand the mechanical behaviour at 4 K, the complete evolution from liquid state to low temperature service condition is considered. The paper will present some results on the mechanical properties, the density and the chemical shrinkage occurring during the polymerization and the thermal contraction between room temperature and 4 K for these different types of epoxy resins.

  1. Electrical and Mechanical Characteristics of Epoxy-Nanoclay Composite

    Science.gov (United States)

    Noh, Hyun-Ji; Nam, Sung-Pill; Lee, Sung-Gap; Ahn, Byeong-Lib; Won, Woo-Sik; Woo, Hyoung-Gwan; Park, Sang-Man

    In this study, we investigated the effects of nanoclay additives on the electrical and mechanical properties of diglycidyl ether of bisphenol A (DGEBA) epoxy resin. Epoxy-clay nanocomposites were synthesized using organically modified two montmorillonite clays (MMT) with different interlamellar spacing (31.5 Å and 18.5 Å). The electrical and mechanical properties of epoxy-clay nanocopomosites were measured with variation of the amount and type of clay. The nanocomposites were found to be homogenous materials although the nanocomposites still have clay aggregates with increasing nanoclay contents. The dielectric constant showed between 3.2 ~ 3.5 and the dielectric loss showed between 3.2 ~ 5.7% in all nanocoposites. The dielectric strength and tensile strength of the 5 wt% Cloisite 15A added epoxy-oclay nanocomposite were 23.9 kV/mm and 86.7 MPa, respectively.

  2. Waterborne Epoxy Nanocoatings Modified by Nanoemulsions and Nanoparticles

    National Research Council Canada - National Science Library

    Zhenyu Wang Enhou Han Fuchun Liu Zhouhai Qian Liwei Zhu

    2014-01-01

    .... In the present investigation electrically conductive nanocoatings were prepared by the incorporation of graphite, nano-SiO2 concentrate, acrylic nanoemulsion and fluorocarbon emulsion onto the waterborne epoxy polymer...

  3. Lipase catalyzed synthesis of epoxy-fatty acids

    Institute of Scientific and Technical Information of China (English)

    CHEN, Qian; LI, Zu-Yi

    2000-01-01

    Lipase catalyzed synthesis of epoxy-fatty acidas from unsaturated carboxylic acids was investigated.Under mild conditions unsaturated arboxylic acids were convcveed to peroxide,then the unsaturated peroxycarboxylic acids epoxidised the C=C bond of themselves

  4. Glass-ceramics and epoxy-composites for radiation imaging

    Energy Technology Data Exchange (ETDEWEB)

    Williams, G.V.M. [MacDiarmid Institute, Industrial Research, P.O. Box 31310, Lower Hutt (New Zealand)], E-mail: G.Williams@irl.cri.nz; Bittar, A. [MacDiarmid Institute, Industrial Research, P.O. Box 31310, Lower Hutt (New Zealand); Dotzler, C. [MacDiarmid Institute, Industrial Research, P.O. Box 31310, Lower Hutt (New Zealand); School of Chemical and Physical Sciences, Victoria University, P.O. Box 600, Wellington (New Zealand); Beaudin, A. [MacDiarmid Institute, Industrial Research, P.O. Box 31310, Lower Hutt (New Zealand); Varoy, C. [School of Chemical and Physical Sciences, Victoria University, P.O. Box 600, Wellington (New Zealand); Dunford, C. [MacDiarmid Institute, Industrial Research, P.O. Box 31310, Lower Hutt (New Zealand)

    2007-04-15

    We report the results of optical, photo-luminescence and spatial resolution measurements on glass-ceramic and epoxy-composite X-ray storage phosphors. We find that the optical extinction coefficient at the stimulation and emission wavelengths is dominated by scattering for all the samples studied. However, the extinction coefficient is at least an order of magnitude lower in ZBLAN:BaCl{sub 2}:Eu{sup 2+} glass-ceramics when compared with the epoxy/BaCl{sub 2}:Eu{sup 2+} composites. Significantly reduced scattering is found in a epoxy/KBr:Eu{sup 2+} composite due to the better match between the refractive indices of the epoxy and crystallite. We show that the spatial resolution using a confocal microscope readout in a ZBLAN:BaCl{sub 2}:Eu{sup 2+} glass-ceramic is below 10{mu}m and hence this glass-ceramic has potential applications in high resolution radiation imaging.

  5. Method of making superhydrophobic/superoleophilic paints, epoxies, and composites

    Energy Technology Data Exchange (ETDEWEB)

    Simpson, John T.; Hunter, Scott Robert

    2016-05-10

    Superhydrophobic paints and epoxies comprising superoleophilic particles and surfaces and methods of making the same are described. The superoleophilic particles can include porous particles having a hydrophobic coating layer deposited thereon. superoleophilic particles.

  6. Finite Element Analysis Of Epoxy-Graphite Powder, Epoxy-Ms Powder, Epoxy- Ms Lathe Scrap(Ms Flakes Filled In A Circular Hollow Aluminium Column

    Directory of Open Access Journals (Sweden)

    Dr.M.AnandaRao

    2014-09-01

    Full Text Available Main objective of this paper is to prepare composite material filled hollow Al columns and test them for their compressive strengths and compare the results with Rankine’s columnar theory and Finite Element Analysis using Ansys 2014. The idea of filling the particulate polymer composite material in an aluminium tube is taken from a research paper presented at 14th international conference on computing in civil and building engineering in Moscow, Russia (27-29 June 2012 by Feng Zhou and Ben Young, in which they filled the Al tube with concrete and conducted Finite Elemental Analysis. The composites used in the project are Epoxy-graphite, Epoxy-MS powder, Epoxy-MS flakes, all these three samples are taken in a hollow Al CHS tube. Another two specimens were prepared by using epoxy-graphite powder and epoxy-MS powder without using Al tube. These specimens were subjected to crushing force and the readings obtained were compared with the results obtained by conducting Finite elemental analysis in ANSYS. The applications include columns in buildings, columns of bridges, and as columns in earthquake zones as the outer hollow metal has the capability to withstand heavy loads and dampens the vibrations.

  7. Rubber-Modified Epoxies. II. Morphology, Transitions, and Mechanical Properties.

    Science.gov (United States)

    1984-11-01

    tetrafunctional aromatic diamine-cured diglycidyl ether of bisphenol A ( DGEBA )-type epoxy resin was selected as the neat system because of its high ETgm (1670C...was a DGEBA -type epoxy resin (DER 331, Dow Chemical Co.) cured with tri- methylene glycol di-p-aminobenzoate (ITMABO, i.e. Polacure 740M, Polaroid...Chemical "o.) with excess of DGEBA resin. The second system, denoted DTAxl6, was iodified with a commercial amino-terminated butadiene-acrylonitrile

  8. Adherend Surface Effects on Epoxy Cure by NMR

    Science.gov (United States)

    1994-05-11

    questions. 3 2. Summary of results. The structure and dynamics of the cure of the epoxy resin system based on the diglycidyl ether of bisphenol-A ( DGEBA ) is... DGEBA ), obtained from Dow Chemical Co. (der 332) was heated in the oven at temperature 160 OC until completely melted. The sample was cooled and at the...epoxy to ether conversion with the NMR analysis. (b) Results and Interpretation. The mixture of DGEBA with DDS was studied at temperature 1600C. The

  9. Exit Presentation: Infrared Thermography on Graphite/Epoxy

    Science.gov (United States)

    Comeaux, Kayla

    2010-01-01

    This slide presentation reports on the internship project that was accomplished during the summer of 2010. The objectives of the project were to: (1) Simulate Flash Thermography on Graphite/Epoxy Flat Bottom hole Specimen and thin void specimens, (2) Obtain Flash Thermography data on Graphite/Epoxy flat bottom hole specimens, (3) Compare experimental results with simulation results, Compare Flat Bottom Hole Simulation with Thin Void Simulation to create a graph to determine size of IR Thermography detected defects

  10. Properties of Graphene Oxide/Epoxy Resin Composites

    OpenAIRE

    Jijun Tang; Haijun Zhou; Yunxia Liang; Xinlan Shi; Xin Yang; Jiaoxia Zhang

    2014-01-01

    The graphene oxide (GO) was obtained by pressurized oxidation method using natural graphite as raw materials. Then the GO/epoxy resin composites were prepared by casting. The mechanical and damping properties of composites were studied. As a result, the impact intensity of GO/epoxy resin composites was prominently improved with the content of the graphene oxide increasing. The glass transition temperature decreased and the damping capacity is improved.

  11. Microstructure, elastic and electromagnetic properties of epoxy-graphite composites

    OpenAIRE

    Bellucci, S.; Micciulla, F.; V. M. Levin; Yu. S. Petronyuk; Chernozatonskii, L. A.; Kuzhir, P. P.; Paddubskaya, A. G.; Macutkevic, J.; M. A. Pletnev; Fierro, V.; A. Celzard

    2015-01-01

    A set of epoxy resin-based composites filled with 0.25 – 2.0 wt.% of commercially available exfoliated graphite (EG) and thick graphene (TG), prepared by suspending EG particles in cyclohexane, and submitting the suspension to a series of grinding and ultrasonic dispersion steps, was produced. The microstructure of such epoxy-graphite composites has been studied by the impulse acoustic microscopy technique. According to acoustic microscopy data, exfoliated graphite microparticles have been we...

  12. Properties of Graphene Oxide/Epoxy Resin Composites

    OpenAIRE

    Jijun Tang; Haijun Zhou; Yunxia Liang; Xinlan Shi; Xin Yang; Jiaoxia Zhang

    2014-01-01

    The graphene oxide (GO) was obtained by pressurized oxidation method using natural graphite as raw materials. Then the GO/epoxy resin composites were prepared by casting. The mechanical and damping properties of composites were studied. As a result, the impact intensity of GO/epoxy resin composites was prominently improved with the content of the graphene oxide increasing. The glass transition temperature decreased and the damping capacity is improved.

  13. Properties of Graphene Oxide/Epoxy Resin Composites

    Directory of Open Access Journals (Sweden)

    Jijun Tang

    2014-01-01

    Full Text Available The graphene oxide (GO was obtained by pressurized oxidation method using natural graphite as raw materials. Then the GO/epoxy resin composites were prepared by casting. The mechanical and damping properties of composites were studied. As a result, the impact intensity of GO/epoxy resin composites was prominently improved with the content of the graphene oxide increasing. The glass transition temperature decreased and the damping capacity is improved.

  14. Autonomous Underwater Vehicle Magnetic Mapping System

    Science.gov (United States)

    Steigerwalt, R.; Johnson, R. M.; Trembanis, A. C.; Schmidt, V. E.; Tait, G.

    2012-12-01

    An Autonomous Underwater Vehicle (AUV) Magnetic Mapping (MM) System has been developed and tested for military munitions detection as well as pipeline locating, wreck searches, and geologic surveys in underwater environments. The system is comprised of a high sensitivity Geometrics G-880AUV cesium vapor magnetometer integrated with a Teledyne-Gavia AUV and associated Doppler enabled inertial navigation further utilizing traditional acoustic bathymetric and side scan imaging. All onboard sensors and associated electronics are managed through customized crew members to autonomously operate through the vehicles primary control module. Total field magnetic measurements are recorded with asynchronous time-stamped data logs which include position, altitude, heading, pitch, roll, and electrical current usage. Pre-planned mission information can be uploaded to the system operators to define data collection metrics including speed, height above seafloor, and lane or transect spacing specifically designed to meet data quality objectives for the survey. As a result of the AUVs modular design, autonomous navigation and rapid deployment capabilities, the AUV MM System provides cost savings over current surface vessel surveys by reducing the mobilization/demobilization effort, thus requiring less manpower for operation and reducing or eliminating the need for a surface support vessel altogether. When the system completes its mission, data can be remotely downloaded via W-LAN and exported for use in advanced signal processing platforms. Magnetic compensation software has been concurrently developed to accept electrical current measurements directly from the AUV to address distortions from permanent and induced magnetization effects on the magnetometer. Maneuver and electrical current compensation terms can be extracted from the magnetic survey missions to perform automated post-process corrections. Considerable suppression of system noise has been observed over traditional

  15. Curved spiral antennas for underwater biological applications

    Science.gov (United States)

    Llamas, Ruben

    We developed curved spiral antennas for use in underwater (freshwater) communications. Specifically, these antennas will be integrated in so-called mussel backpacks. Backpacks are compact electronics that incorporate sensors and a small radio that operate around 300 MHz. Researchers attach these backpacks in their freshwater mussel related research. The antennas must be small, lightweight, and form-fit the mussel. Additionally, since the mussel orientation is unknown, the antennas must have broad radiation patterns. Further, the electromagnetic environment changes significantly as the mussels burrow into the river bottom. Broadband antennas, such a spiral antennas, will perform better in this instance. While spiral antennas are well established, there has been little work on their performance in freshwater. Additionally, there has been some work on curved spiral antennas, but this work focused on curving in one dimension, namely curving around a cylinder. In this thesis we develop spiral antennas that curve in two dimensions in order to conform the contour of a mussel's shell. Our research has three components, namely (a) an investigation of the relevant theoretical underpinning of spiral antennas, (b) extensive computer simulations using state-of-the art computational electromagnetics (CEM) simulation software, and (c) experimental validation. The experimental validation was performed in a large tank in a laboratory setting. We also validated some designs in a pool (~300,000 liters of water and ~410 squared-meter dive pool) with the aid of a certified diver. To use CEM software and perform successful antenna-related experiments require careful attention to many details. The mathematical description of radiation from an antenna, antenna input impedance and so on, is inherently complex. Engineers often make simplifying assumptions such as assuming no reflections, or an isotropic propagation environment, or operation in the antenna far field, and so on. This makes

  16. Advanced Systems for Monitoring Underwater Sounds

    Science.gov (United States)

    Lane, Michael; Van Meter, Steven; Gilmore, Richard Grant; Sommer, Keith

    2007-01-01

    The term "Passive Acoustic Monitoring System" (PAMS) describes a developmental sensing-and-data-acquisition system for recording underwater sounds. The sounds (more precisely, digitized and preprocessed versions from acoustic transducers) are subsequently analyzed by a combination of data processing and interpretation to identify and/or, in some cases, to locate the sources of those sounds. PAMS was originally designed to locate the sources such as fish of species that one knows or seeks to identify. The PAMS unit could also be used to locate other sources, for example, marine life, human divers, and/or vessels. The underlying principles of passive acoustic sensing and analyzing acoustic-signal data in conjunction with temperature and salinity data are not new and not unique to PAMS. Part of the uniqueness of the PAMS design is that it is the first deep-sea instrumentation design to provide a capability for studying soniferous marine animals (especially fish) over the wide depth range described below. The uniqueness of PAMS also lies partly in a synergistic combination of advanced sensing, packaging, and data-processing design features with features adapted from proven marine instrumentation systems. This combination affords a versatility that enables adaptation to a variety of undersea missions using a variety of sensors. The interpretation of acoustic data can include visual inspection of power-spectrum plots for identification of spectral signatures of known biological species or artificial sources. Alternatively or in addition, data analysis could include determination of relative times of arrival of signals at different acoustic sensors arrayed at known locations. From these times of arrival, locations of acoustic sources (and errors in those locations) can be estimated. Estimates of relative locations of sources and sensors can be refined through analysis of the attenuation of sound in the intervening water in combination with water-temperature and salinity

  17. On the Effects of Frequency Scaling over Capacity Scaling in Underwater Networks— Part II: Dense Network Model

    DEFF Research Database (Denmark)

    Shin, Won-Yong; Lucani Rötter, Daniel Enrique; Medard, Muriel

    2013-01-01

    This is the second in a two-part series of papers on information-theoretic capacity scaling laws for an underwater acoustic network. Part II focuses on a dense network scenario, where nodes are deployed in a unit area. By deriving a cut-set upper bound on the capacity scaling, we first show...... that there exists either a bandwidth or power limitation, or both, according to the operating regimes (i.e., path-loss attenuation regimes), thus yielding the upper bound that follows three fundamentally different information transfer arguments. In addition, an achievability result based on the multi-hop (MH......) transmission is presented for dense networks. MH is shown to guarantee the order optimality under certain operating regimes. More specifically, it turns out that scaling the carrier frequency faster than or as is instrumental towards achieving the order optimality of the MH protocol....

  18. Bio-Based Aromatic Epoxy Monomers for Thermoset Materials.

    Science.gov (United States)

    Ng, Feifei; Couture, Guillaume; Philippe, Coralie; Boutevin, Bernard; Caillol, Sylvain

    2017-01-18

    The synthesis of polymers from renewable resources is a burning issue that is actively investigated. Polyepoxide networks constitute a major class of thermosetting polymers and are extensively used as coatings, electronic materials, adhesives. Owing to their outstanding mechanical and electrical properties, chemical resistance, adhesion, and minimal shrinkage after curing, they are used in structural applications as well. Most of these thermosets are industrially manufactured from bisphenol A (BPA), a substance that was initially synthesized as a chemical estrogen. The awareness on BPA toxicity combined with the limited availability and volatile cost of fossil resources and the non-recyclability of thermosets implies necessary changes in the field of epoxy networks. Thus, substitution of BPA has witnessed an increasing number of studies both from the academic and industrial sides. This review proposes to give an overview of the reported aromatic multifunctional epoxide building blocks synthesized from biomass or from molecules that could be obtained from transformed biomass. After a reminder of the main glycidylation routes and mechanisms and the recent knowledge on BPA toxicity and legal issues, this review will provide a brief description of the main natural sources of aromatic molecules. The different epoxy prepolymers will then be organized from simple, mono-aromatic di-epoxy, to mono-aromatic poly-epoxy, to di-aromatic di-epoxy compounds, and finally to derivatives possessing numerous aromatic rings and epoxy groups.

  19. Bio-Based Aromatic Epoxy Monomers for Thermoset Materials

    Directory of Open Access Journals (Sweden)

    Feifei Ng

    2017-01-01

    Full Text Available The synthesis of polymers from renewable resources is a burning issue that is actively investigated. Polyepoxide networks constitute a major class of thermosetting polymers and are extensively used as coatings, electronic materials, adhesives. Owing to their outstanding mechanical and electrical properties, chemical resistance, adhesion, and minimal shrinkage after curing, they are used in structural applications as well. Most of these thermosets are industrially manufactured from bisphenol A (BPA, a substance that was initially synthesized as a chemical estrogen. The awareness on BPA toxicity combined with the limited availability and volatile cost of fossil resources and the non-recyclability of thermosets implies necessary changes in the field of epoxy networks. Thus, substitution of BPA has witnessed an increasing number of studies both from the academic and industrial sides. This review proposes to give an overview of the reported aromatic multifunctional epoxide building blocks synthesized from biomass or from molecules that could be obtained from transformed biomass. After a reminder of the main glycidylation routes and mechanisms and the recent knowledge on BPA toxicity and legal issues, this review will provide a brief description of the main natural sources of aromatic molecules. The different epoxy prepolymers will then be organized from simple, mono-aromatic di-epoxy, to mono-aromatic poly-epoxy, to di-aromatic di-epoxy compounds, and finally to derivatives possessing numerous aromatic rings and epoxy groups.

  20. Thermo-curable epoxy systems for nanoimprint lithography

    Science.gov (United States)

    Wu, Chun-Chang; Lien-Chung Hsu, Steve

    2010-01-01

    In this work, we have used solvent-free thermo-curable epoxy systems for low-pressure and moderate-temperature nanoimprint lithography (NIL). The curing kinetic parameters and conversion of diglycidyl ether of bisphenol A (DGEBA) resin with different ambient-cure 930 and 954 hardeners were studied by the isothermal DSC technique. They are useful for the study of epoxy resins in the imprinting application. The DGEBA/930 and DGEBA/954 epoxy resists can be imprinted to obtain high-density nano- and micro-scale patterns on a flexible indium tin oxide/poly(ethylene terephthalate) (ITO/PET) substrate. The DGEBA/930 epoxy resin is not only suitable for resist material, but also for plastic mold material. Highly dense nanometer patterns can be successfully imprinted using a UV-curable resist from the DGEBA/930 epoxy mold. Using the replicated DGEBA/930 epoxy mold instead of the expensive master can prevent brittle failure of the silicon molds in the NIL.

  1. Microstructure, elastic and electromagnetic properties of epoxy-graphite composites

    Science.gov (United States)

    Bellucci, S.; Micciulla, F.; Levin, V. M.; Petronyuk, Yu. S.; Chernozatonskii, L. A.; Kuzhir, P. P.; Paddubskaya, A. G.; Macutkevic, J.; Pletnev, M. A.; Fierro, V.; Celzard, A.

    2015-06-01

    A set of epoxy resin-based composites filled with 0.25 - 2.0 wt.% of commercially available exfoliated graphite (EG) and thick graphene (TG), prepared by suspending EG particles in cyclohexane, and submitting the suspension to a series of grinding and ultrasonic dispersion steps, was produced. The microstructure of such epoxy-graphite composites has been studied by the impulse acoustic microscopy technique. According to acoustic microscopy data, exfoliated graphite microparticles have been well dispersed in the epoxy matrix. TG nanoflakes demonstrated persistent tendency to clustering and formation of agglomerates. The addition of graphite particles in small amount (0.25 - 2.0 wt.%) did not influence the bulk elastic properties of epoxy-graphite composite materials. Being extremely lightweight, 0.003 g cm-3, EG had a lower percolation threshold than TG, at the level of 1-1.5 wt.% against 2.1-3.2 wt.%, respectively. As a result, epoxy composites filled with 1.0-2.0 wt.% EG provided high electromagnetic (EM) interference shielding both at microwave and THz frequencies. In contrast, no significant influence of TG loading was observed at low weight fraction (up to 2 wt.%) on the EM performance of epoxy composites.

  2. Microstructure, elastic and electromagnetic properties of epoxy-graphite composites

    Directory of Open Access Journals (Sweden)

    S. Bellucci

    2015-06-01

    Full Text Available A set of epoxy resin-based composites filled with 0.25 – 2.0 wt.% of commercially available exfoliated graphite (EG and thick graphene (TG, prepared by suspending EG particles in cyclohexane, and submitting the suspension to a series of grinding and ultrasonic dispersion steps, was produced. The microstructure of such epoxy-graphite composites has been studied by the impulse acoustic microscopy technique. According to acoustic microscopy data, exfoliated graphite microparticles have been well dispersed in the epoxy matrix. TG nanoflakes demonstrated persistent tendency to clustering and formation of agglomerates. The addition of graphite particles in small amount (0.25 – 2.0 wt.% did not influence the bulk elastic properties of epoxy-graphite composite materials. Being extremely lightweight, 0.003 g cm−3, EG had a lower percolation threshold than TG, at the level of 1-1.5 wt.% against 2.1-3.2 wt.%, respectively. As a result, epoxy composites filled with 1.0-2.0 wt.% EG provided high electromagnetic (EM interference shielding both at microwave and THz frequencies. In contrast, no significant influence of TG loading was observed at low weight fraction (up to 2 wt.% on the EM performance of epoxy composites.

  3. Characterization of Epoxy Composites Reinforced with Wax Encapsulated Microcrystalline Cellulose

    Directory of Open Access Journals (Sweden)

    Yuanfeng Pan

    2016-11-01

    Full Text Available The effect of paraffin wax encapsulated microcrystalline cellulose (EMC particles on the mechanical and physical properties of EMC/epoxy composites were investigated. It was demonstrated that the compatibility between cellulose and epoxy resin could be maintained due to partial encapsulation resulting in an improvement in epoxy composite mechanical properties. This work was unique because it was possible to improve the physical and mechanical properties of the EMC/epoxy composites while encapsulating the microcrystalline cellulose (MCC for a more homogeneous dispersion. The addition of EMC could increase the stiffness of epoxy composites, especially when the composites were wet. The 1% EMC loading with a 1:2 ratio of wax:MCC demonstrated the best reinforcement for both dry and wet properties. The decomposition temperature of epoxy was preserved up to a 5% EMC loading and for different wax:MCC ratios. An increase in wax encapsulated cellulose loading did increase water absorption but overall this absorption was still low (<1% for all composites.

  4. Interface and properties of epoxy resin modified by elastomeric nano-particles

    Institute of Scientific and Technical Information of China (English)

    HUANG Fan; LIU Yiqun; ZHANG Xiaohong; GAO Jianming; SONG Zhihai; TANG Banghui; WEI Genshuan; QIAO Jinliang

    2005-01-01

    Study on a new composite of epoxy resin/elastomeric nano-particles (ENP) is reported in this paper, which shows that, in comparison with pure epoxy resin and epoxy toughened with CTBN, the composites of epoxy resin/carboxylic nitrile-butadiene ENP and epoxy resin/styrene butadiene vinyl-pyridine ENP possess both higher toughness and heat resistance. Both ENPs used in the study have an average size of less than 100 nm. Study on the epoxy network's morphology and interface properties suggests that due to the chemical reaction between ENP and epoxy resin and more hydrogen bonds between nitrile groups of the rubber and hydroxyl groups of the epoxy resin, stronger interaction at the larger interface may lead to the observed excellent properties of the epoxy resin toughened with ENP.

  5. Preliminary results of algorithms to determine horizontal and vertical underwater visibilities of coastal waters

    Digital Repository Service at National Institute of Oceanography (India)

    Suresh, T.; Joshi, Shreya; Talaulikar, M.; Desa, E.J.

    Algorithms developed for underwater horizontal and vertical visibilities are presented. The algorithms have been developed to derive the underwater visibilities based on the contrast theory using the in-situ and Hydrolight derived optical parameters...

  6. A comparative view of routing protocols for underwater wireless sensor networks

    NARCIS (Netherlands)

    Bayrakdar, Y.; Meratnia, Nirvana; Kantarci, Aylin

    2011-01-01

    Design of efficient routing protocols for underwater sensor networks is challenging because of the distinctive characteristics of the water medium. Currently, many routing protocols are available for terrestrial wireless sensor networks. However, specific properties of underwater medium such as

  7. Effect of carbon nanotube addition on the wear behavior of basalt/epoxy woven composites.

    Science.gov (United States)

    Kim, M T; Rhee, K Y; Lee, B H; Kim, C J

    2013-08-01

    The effect of acid-treated carbon nanotube (CNT) addition on the wear and dynamic mechanical thermal properties of basalt/epoxy woven composites was investigated in this study. Basalt/CNT/epoxy composites were fabricated by impregnating woven basalt fibers into epoxy resin mixed with 1 wt% CNTs which were acid-treated. Wear and DMA (dynamic mechanical analyzer) tests were performed on basalt/epoxy composites and basalt/CNT/epoxy composites. The results showed that the addition of the acid-treated CNTs improved the wear properties of basalt/epoxy woven composites. Specifically, the friction coefficient of the basalt/epoxy composite was stabilized in the range of 0.5-0.6 while it fell in the range of 0.3-0.4 for basalt/CNT/epoxy composites. The wear volume loss of the basalt/CNT/epoxy composites was approximately 68% lower than that of the basalt/epoxy composites. The results also showed that the glass transition temperature of basalt/CNT/epoxy composites was higher than that of basalt/epoxy composites. The improvement of wear properties of basalt/epoxy composites by the addition of acid-treated CNTs was caused by the homogeneous load transfer between basalt fibers and epoxy matrix due to the reinforcement of CNTs.

  8. Electrohydroelastic Euler-Bernoulli-Morison model for underwater resonant actuation of macro-fiber composite piezoelectric cantilevers

    Science.gov (United States)

    Shahab, S.; Erturk, A.

    2016-10-01

    Bio-inspired hydrodynamic thrust generation using smart materials has received growing attention over the past few years to enable improved maneuverability and agility, small form factor, reduced power consumption, and ease of fabrication in next-generation aquatic swimmers. In order to develop a high-fidelity model to predict the electrohydroelastic dynamics of macro-fiber composite (MFC) piezoelectric structures, in this work, mixing rules-based (i.e. rule of mixtures) electroelastic mechanics formulation is coupled with the global electroelastic dynamics based on the Euler-Bernoulli kinematics and nonlinear fluid loading based on Morison’s semi-empirical model. The focus is placed on the dynamic actuation problem for the first two bending vibration modes under geometrically and materially linear, hydrodynamically nonlinear behavior. The electroelastic and dielectric properties of a representative volume element (piezoelectric fiber and epoxy matrix) between two subsequent interdigitated electrodes are correlated to homogenized parameters of MFC bimorphs and validated for a set of MFCs that have the same overhang length but different widths. Following this process of electroelastic model development and validation, underwater actuation experiments are conducted for different length-to-width aspect ratios (L/b) in quiescent water, and the empirical drag and inertia coefficients are extracted from Morison’s equation to establish the electrohydroelastic model. The repeatability of these empirical coefficients is demonstrated for experiments conducted using aluminum cantilevers of different aspect ratios with a focus on the first two bending modes. The convergence of the nonlinear electrohydroelastic Euler-Bernoulli-Morison model to its hydrodynamically linear counterpart for increased L/b values is also reported. The proposed model, its harmonic balance analysis, and experimental results can be used not only for underwater piezoelectric actuation, but also for

  9. Experimental Study on the Measurement of Water Bottom Vibration Induced by Underwater Drilling Blasting

    OpenAIRE

    Wenbin, Gu; Jianghai, Chen; Zhenxiong, Wang; Zhihua, Wang; Jianqing, Liu; Ming, Lu

    2015-01-01

    Due to the lack of proper instrumentations and the difficulties in underwater measurements, the studies about water bottom vibration induced by underwater drilling blasting are seldom reported. In order to investigate the propagation and attenuation laws of blasting induced water bottom vibration, a water bottom vibration monitor was developed with consideration of the difficulties in underwater measurements. By means of this equipment, the actual water bottom vibration induced by underwater ...

  10. Autonomous Underwater Vehicle Thermoelectric Power Generation

    Science.gov (United States)

    Buckle, J. R.; Knox, A.; Siviter, J.; Montecucco, A.

    2013-07-01

    Autonomous underwater vehicles (AUVs) are a vital part of the oceanographer's toolbox, allowing long-term measurements across a range of ocean depths of a number of ocean properties such as salinity, fluorescence, and temperature profile. Buoyancy-based gliding, rather than direct propulsion, dramatically reduces AUV power consumption and allows long-duration missions on the order of months rather than hours or days, allowing large distances to be analyzed or many successive analyses of a certain area without the need for retrieval. Recent versions of these gliders have seen the buoyancy variation system change from electrically powered to thermally powered using phase-change materials, however a significant battery pack is still required to power communications and sensors, with power consumption in the region of 250 mW. The authors propose a novel application of a thermoelectric generation system, utilizing the depth-related variation in oceanic temperature. A thermal energy store provides a temperature differential across which a thermoelectric device can generate from repeated dives, with the primary purpose of extending mission range. The system is modeled in Simulink to analyze the effect of variation in design parameters. The system proves capable of generating all required power for a modern AUV.

  11. AUTONOMOUS UNDERWATER HYBRID VEHICLE FOR OCEAN SURVEILLANCE

    Directory of Open Access Journals (Sweden)

    KIRUBAKARAN.S,

    2011-05-01

    Full Text Available Coastal areas are among the most vulnerable of all regions to global climate change. Projected impacts from global warming include rising sea levels, intensification of tropical cyclones, larger storm surges, increasing sea-surface temperatures, and – as the oceans absorb more of the carbon dioxide human activities emit to theatmosphere – growing acidification of surface waters. With an estimated 50 per cent of the world’s population now living within 60km of the coast and 60 per cent of cities with population over 5 million located within 100 km of the coast, the Potential impacts of climate change on coastal development and infrastructure is considerable. On-going development has manifested in the form of urban centers, tourist resorts, ports and Industrial areas. The rising sea levels and larger storm surges caused by climate change Threaten to compound such risks. In order to understand the Ocean systems, continuous time series Observation is essential and development of innovative Autonomous Underwater Vehicle (AUV with suite of sensors would be very useful.

  12. Underwater hydraulic shock shovel control system

    Institute of Scientific and Technical Information of China (English)

    LIU He-ping; LUO A-ni; XIAO Hai-yan

    2008-01-01

    The control system determines the effectiveness of an underwater hydraulic shock shovel.This paper begins by analyzing the working principles of these shovels and explains the importance of their control systems.A new type of control system's mathematical model was built and analyzed according to those principles.Since the initial control system's response time could not fulfill the design requirements,a PID controller was added to the control system.System response time was still slower than required,so a neural network was added to nonlinearly regulate the proportional element,integral element and derivative element coefficients of the PID controller.After these improvements to the control system,system parameters fulfilled the design requirements.The working performance of electrically-controlled parts such as the rapidly moving high speed switch valve is largely determined by the control system. Normal control methods generally can't satisfy a shovel's requirements,so advanced and normal control methods were combined to improve the control system,bringing good results.

  13. Underwater radiated noise from modern commercial ships.

    Science.gov (United States)

    McKenna, Megan F; Ross, Donald; Wiggins, Sean M; Hildebrand, John A

    2012-01-01

    Underwater radiated noise measurements for seven types of modern commercial ships during normal operating conditions are presented. Calibrated acoustic data (autonomous seafloor-mounted acoustic recorder were combined with ship passage information from the Automatic Identification System. This approach allowed for detailed measurements (i.e., source level, sound exposure level, and transmission range) on ships of opportunity. A key result was different acoustic levels and spectral shapes observed from different ship-types. A 54 kGT container ship had the highest broadband source level at 188 dB re 1 μPa@1m; a 26 kGT chemical tanker had the lowest at 177 dB re 1 μPa@1m. Bulk carriers had higher source levels near 100 Hz, while container ship and tanker noise was predominantly below 40 Hz. Simple models to predict source levels of modern merchant ships as a group from particular ship characteristics (e.g., length, gross tonnage, and speed) were not possible given individual ship-type differences. Furthermore, ship noise was observed to radiate asymmetrically. Stern aspect noise levels are 5 to 10 dB higher than bow aspect noise levels. Collectively, these results emphasize the importance of including modern ship-types in quantifying shipping noise for predictive models of global, regional, and local marine environments.

  14. Underwater laser fabrication method and device

    Energy Technology Data Exchange (ETDEWEB)

    Okazaki, Yuki; Ito, Arata; Sano, Yuji; Mukai, Naruhiko; Aoki, Nobutada; Konagai, Chikara [Toshiba Corp., Kawasaki, Kanagawa (Japan); Kikunaga, Muneyoshi

    1996-08-13

    The present invention concerns an underwater laser fabrication method which comprises irradiating laser beams having a visible wavelength at high power and of short pulse to the surface of structural components immersed in coolants to improve residual stresses on the surface of the materials of the structural components and eliminate cracks or remove cruds. Laser beams having a visible wavelength and a pulse width of not greater than 100n sec are irradiated to the materials on the surface of inner structural components of a reactor under the conditions of a peak power of from 0.1 to 10GW/cm{sup 2} per 1 pulse, and overlapping ratio of irradiation beams of not less than 100%, to improve the residual stresses on the surface of the materials of the structural components and form them into compressed stresses. Then, the irradiation is conducted while monitoring the state to remove crackings by abrasion. Further, the stresses on the surface of the materials after removing crackings are improved. In the present invention, since the laser beams, namely, visible rays can be transmitted directly under water, the operation can be conducted directly in coolants. Therefore, it is not necessary to drain coolants in the reactor before the operation. Further, reduction in an operator`s radiation exposure can be expected. (T.M.)

  15. VSiPMT for underwater neutrino telescopes

    Energy Technology Data Exchange (ETDEWEB)

    Barbarino, Giancarlo [Università di Napoli Federico II, Dipartimento di Scienze Fisiche, via Cintia 80126 Napoli (Italy); Asmundis, Riccardo de [Istituto Nazionale di fisica Nucleare, sezione di Napoli, Complesso di Monte S. Angelo Ed. 6, via Cintia 80126 Napoli (Italy); De Rosa, Gianfranca [Università di Napoli Federico II, Dipartimento di Scienze Fisiche, via Cintia 80126 Napoli (Italy); Maximiliano Mollo, Carlos [Istituto Nazionale di fisica Nucleare, sezione di Napoli, Complesso di Monte S. Angelo Ed. 6, via Cintia 80126 Napoli (Italy); Vivolo, Daniele, E-mail: vivolo@na.infn.it [Università di Napoli Federico II, Dipartimento di Scienze Fisiche, via Cintia 80126 Napoli (Italy); Istituto Nazionale di fisica Nucleare, sezione di Napoli, Complesso di Monte S. Angelo Ed. 6, via Cintia 80126 Napoli (Italy)

    2013-10-11

    Underwater neutrino telescopes are nowadays considered among the most important aims in the field of astroparticle physics. Their structure consists of a cubic-kilometer three-dimensional array of photosensitive devices aimed at the detection of the Cherenkov light emitted by charged particles produced by high energy neutrino interactions with the Earth. To date, a crucial role in this kind of experiments has been played by PhotoMultiplier Tubes (PMTs), however they suffer from many drawbacks such as linearity-to-gain relationship and difficulty in single photon counting. The next generation of experiments will require further improvements in photon detectors performances, therefore alternatives to PMTs are currently under study. In particular the most promising development in this field is represented by the rapidly emerging CMOS p-n Geiger-mode avalanche photodiode technology (G-APD or SiPM), that will allow the detection of high-speed single photons with high gain and linearity. In order to overcome the limit of small sensitive surfaces we suggest an innovative design for a modern hybrid, high gain, silicon based Vacuum Silicon Photomultiplier Tube (VSiPMT) based on the combination of a SiPM with a hemispherical vacuum glass PMT standard envelope. In this work we describe the full SiPM characterization realized by our group and we present the results of our Geant4-based simulations of electron backscattering over the SiPM surface.

  16. VSiPMT for underwater neutrino telescopes

    Science.gov (United States)

    Barbarino, Giancarlo; de Asmundis, Riccardo; De Rosa, Gianfranca; Maximiliano Mollo, Carlos; Vivolo, Daniele

    2013-10-01

    Underwater neutrino telescopes are nowadays considered among the most important aims in the field of astroparticle physics. Their structure consists of a cubic-kilometer three-dimensional array of photosensitive devices aimed at the detection of the Cherenkov light emitted by charged particles produced by high energy neutrino interactions with the Earth. To date, a crucial role in this kind of experiments has been played by PhotoMultiplier Tubes (PMTs), however they suffer from many drawbacks such as linearity-to-gain relationship and difficulty in single photon counting. The next generation of experiments will require further improvements in photon detectors performances, therefore alternatives to PMTs are currently under study. In particular the most promising development in this field is represented by the rapidly emerging CMOS p-n Geiger-mode avalanche photodiode technology (G-APD or SiPM), that will allow the detection of high-speed single photons with high gain and linearity. In order to overcome the limit of small sensitive surfaces we suggest an innovative design for a modern hybrid, high gain, silicon based Vacuum Silicon Photomultiplier Tube (VSiPMT) based on the combination of a SiPM with a hemispherical vacuum glass PMT standard envelope. In this work we describe the full SiPM characterization realized by our group and we present the results of our Geant4-based simulations of electron backscattering over the SiPM surface.

  17. Hydrodynamics of undulatory underwater swimming: a review.

    Science.gov (United States)

    Connaboy, Chris; Coleman, Simon; Sanders, Ross H

    2009-11-01

    Undulatory underwater swimming (UUS) occurs in the starts and turns of three of the four competitive swimming strokes and plays a significant role in overall swimming performance. The majority of research examining UUS is comparative in nature, dominated by studies comparing aquatic animals' undulatory locomotion with the UUS performance of humans. More recently, research directly examining human forms of UUS have been undertaken, providing further insight into the factors which influence swimming velocity and efficiency. This paper reviews studies which have examined the hydromechanical, biomechanical, and coordination aspects of UUS performance in both animals and humans. The present work provides a comprehensive evaluation of the key factors which combine to influence UUS performance examining (1) the role of end-effector frequency and body amplitudes in the production of a propulsive waveform, (2) the effects of morphology on the wavelength of the propulsive waveform and its subsequent impact on the mode of UUS adopted, and (3) the interactions of the undulatory movements to simultaneously optimise propulsive impulse whilst minimising the active drag experienced. In conclusion, the review recommends that further research is required to fully appreciate the complexity of UUS and examine how humans can further optimise performance.

  18. Underwater connect and disconnect plug and receptacle

    Science.gov (United States)

    Dodier, Paul J.

    1989-06-01

    A plug and receptacle combination is transformer coupled. There are no exposed contacts to the environment at any time, whether the plug and receptacle combination are mated or separated from each other. By encapsulating the primary winding and secondary winding separately in a respective plug and receptacle, mating and unmating can be accomplished while submerged in water. The inventive device is useful in any underwater activity in which a diver must attach a power cable to a power driven tool, light, pump, etc., while submerged. In addition submarines could have the receptacles installed outboard of the pressure hull to be used in the event it became disabled at a depth attainable by a diver. A diver could descend with cables and plug them into the receptacles providing power and communications to the stranded crew awaiting rescue. The inventions could also be used in the home as a safety device where no voltage would be exposed. Either the plug or the receptacle shown could be built into the wall. Whichever items is built into the wall would receive the power source and have the primary winding.

  19. Seam Tracking Technology for Hyperbaric Underwater Welding

    Institute of Scientific and Technical Information of China (English)

    JIAO Xiangdong; YANG Yongyong; ZHOU Canfeng

    2009-01-01

    Automatic weld seam tracking technology to be used in hyperbaric underwater damaged pipeline repair welding is much more important, because of poor bevel preparation and severe working condition. A weld seam tracking system based on digital signal processing(DSP) passive light weld image processing technology has been established. A convenient charge coupled device(CCD) camera system was used in the high pressure environment with the help of an aperture and focus altering mechanism to guarantee overall image visibility in the scope of pressure below 0.7 MPa. The system can be used in the hyperbaric environment to pick up the real welding image of both the welding arc and the welding pool. The newly developed DSP technology was adopted to achieve the goal of system real time characteristics. An effective weld groove edge recognition technique including narrow interesting window opening, middle value wave filtering, Sobel operator weld edge detecting and edge searching in a defined narrow area was proposed to remove the guide error and system accuracy was ensured. The results of tracking simulation and real tracking application with arc striking have proved the validity and the accuracy of the mentioned system and the image processing method.

  20. Under-water superoleophobicity of fish scales

    Science.gov (United States)

    Waghmare, Prashant R.; Gunda, Naga Siva Kumar; Mitra, Sushanta K.

    2014-12-01

    Recent surge in the development of superhydrophobic/superoleophobic surfaces has been motivated by surfaces like fish scales that have hierarchical structures, which are believed to promote water or oil repellency. In this work, we show that the under-water oil repellency of fish scales is entirely due to the mucus layer formation as part of its defense mechanism, which produces unprecedented contact angle close to 180°. We have identified the distinct chemical signatures that are responsible for such large contact angle, thereby making fish scale behave highly superoleophobic inside the water medium. In absence of the mucus layer, it is found that the contact angle decreases quite dramatically to around 150°, making it less oleophobic, the degree of such oleophobicity can then be contributed to its inherent hierarchical structures. Hence, through this systematic study, for the first time we have conclusively shown the role of the fish's mucus layer to generate superoleophobicity and negate the common notion that hierarchical structure is the only reason for such intrinsic behavior of the fish scales.

  1. Underwater breathing: the mechanics of plastron respiration

    Science.gov (United States)

    Flynn, M. R.; Bush, John W. M.

    The rough, hairy surfaces of many insects and spiders serve to render them water-repellent; consequently, when submerged, many are able to survive by virtue of a thin air layer trapped along their exteriors. The diffusion of dissolved oxygen from the ambient water may allow this layer to function as a respiratory bubble or , and so enable certain species to remain underwater indefinitely. Maintenance of the plastron requires that the curvature pressure balance the pressure difference between the plastron and ambient. Moreover, viable plastrons must be of sufficient area to accommodate the interfacial exchange of O2 and CO2 necessary to meet metabolic demands. By coupling the bubble mechanics, surface and gas-phase chemistry, we enumerate criteria for plastron viability and thereby deduce the range of environmental conditions and dive depths over which plastron breathers can survive. The influence of an external flow on plastron breathing is also examined. Dynamic pressure may become significant for respiration in fast-flowing, shallow and well-aerated streams. Moreover, flow effects are generally significant because they sharpen chemical gradients and so enhance mass transfer across the plastron interface. Modelling this process provides a rationale for the ventilation movements documented in the biology literature, whereby arthropods enhance plastron respiration by flapping their limbs or antennae. Biomimetic implications of our results are discussed.

  2. Fluid-structure coupled analysis of underwater cylindrical shells

    Institute of Scientific and Technical Information of China (English)

    AI Shang-mao; SUN Li-ping

    2008-01-01

    Underwater cylindrical shell structures have been found a wide of application in many engineering fields,such as the element of marine,oil platforms,etc.The coupled vibration analysis is a hot issue for these underwater structures.The vibration characteristics of underwater structures are influenced not only by hydrodynamic pressure but also by hydrostatic pressure corresponding to different water depths.In this study,an acoustic finite element method was used to evaluate the underwater structures.Taken the hydrostatic pressure into account in terms of initial stress stiffness,an acoustical fluid-structure coupled analysis of underwater cylindrical shells has been made to study the effect of hydrodynamic pressures on natural frequency and sound radiation.By comparing with the frequencies obtained by the acoustic finite element method and by the added mass method based on the Bessel function,the validity of present analysis was checked.Finally,test samples of the sound radiation of stiffened cylindrical shells were acquired by a harmonic acoustic analysis.The results showed that hydrostatic pressure plays an important role in determining a large submerged body motion,and the characteristics of sound radiation change with water depth. Furthermore,the analysis methods and the results are of significant reference value for studies of other complicated submarine structures.

  3. Design and Evaluation Methods for Underwater Control Systems

    Energy Technology Data Exchange (ETDEWEB)

    Chi, Lin

    1996-12-31

    This thesis on underwater control systems is written with the designer in mind, assuming that the reader has some knowledge of control theory. It can be used as a text for undergraduate students and engineers. To help readers better understand the system they will be working with, the thesis is organised in a stepwise way. The reader will gain basic knowledge about underwater operations, equipment and control systems. Then the reader will be able to follow the steps to develop a required control system for an underwater equipment by first understanding the characteristics of the design problem, customer requirement, functional requirement, and possible solution, and then to present a mathematical model of the control problem. Having developed the concept, the thesis guides the reader to develop evaluation criteria and different ways to make the decision. The thesis gives an overview of how to achieve a successful design rather than giving the techniques for detailed control system design. Chapter 1 describes underwater operations and systems. Chapter 2 discusses issues of underwater control systems and control methods. Chapter 3 deals with design method and control systems theory, focusing on human-centered control. Chapter 4 discusses methods used to evaluate and rank products, and chapter 5 applies the methods to an example. 113 refs., 115 figs., 80 tabs.

  4. Modeling the utility of binaural cues for underwater sound localization.

    Science.gov (United States)

    Schneider, Jennifer N; Lloyd, David R; Banks, Patchouly N; Mercado, Eduardo

    2014-06-01

    The binaural cues used by terrestrial animals for sound localization in azimuth may not always suffice for accurate sound localization underwater. The purpose of this research was to examine the theoretical limits of interaural timing and level differences available underwater using computational and physical models. A paired-hydrophone system was used to record sounds transmitted underwater and recordings were analyzed using neural networks calibrated to reflect the auditory capabilities of terrestrial mammals. Estimates of source direction based on temporal differences were most accurate for frequencies between 0.5 and 1.75 kHz, with greater resolution toward the midline (2°), and lower resolution toward the periphery (9°). Level cues also changed systematically with source azimuth, even at lower frequencies than expected from theoretical calculations, suggesting that binaural mechanical coupling (e.g., through bone conduction) might, in principle, facilitate underwater sound localization. Overall, the relatively limited ability of the model to estimate source position using temporal and level difference cues underwater suggests that animals such as whales may use additional cues to accurately localize conspecifics and predators at long distances. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. Feasibility of in situ beta ray measurements in underwater environment.

    Science.gov (United States)

    Park, Hye Min; Park, Ki Hyun; Kang, Sung Won; Joo, Koan Sik

    2017-09-01

    We describe an attempt at the development of an in situ detector for beta ray measurements in underwater environment. The prototype of the in situ detector is based on a CaF2: Eu scintillator using crystal light guide and Si photomultiplier. Tests were conducted using various reference sources for evaluating the linearity and stability of the detector in underwater environment. The system is simple and stable for long-term monitoring, and consumes low power. We show here an effective detection distance of 7 mm and a 2.273 MeV end-point energy spectrum of (90)Sr/(90)Y when using the system underwater. The results demonstrate the feasibility of in situ beta ray measurements in underwater environment and can be applied for designing an in situ detector for radioactivity measurement in underwater environment. The in situ detector can also have other applications such as installation on the marine monitoring platform and quantitative analysis of radionuclides. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Feasibility Study of High Data Rate Underwater Optical Wireless Network

    Directory of Open Access Journals (Sweden)

    V. Reji

    2014-08-01

    Full Text Available The present technology of acoustic underwater communication is a legacy of technology that provides low data rate transmission for medium range communication. In addition the speed of acoustic waves in the ocean is approximately 1500 m/sec so that long range communication involves high latency which poses a problem for a real time response and synchronization. In addition acoustic waves could distress marine mammals such as dolphins and whales. So the acoustic technology needs high data rate communication networks in real time. The growing need for underwater observation and subsea monitoring systems has stimulated considerable interest in advancing the enabling technologies of underwater wireless communication and underwater sensor networks. This communication technology is expected to play an important role in investigating climate change, in monitoring biological, biogeochemical, evolutionary and ecological changes in the sea, ocean and lake environments and in helping to control and maintain oil production facilities and harbours using unmanned underwater vehicles UUVs, submarines, ships, buoys and divers.

  7. A Review of the Emerging Field of Underwater Mass Spectrometry

    Directory of Open Access Journals (Sweden)

    Emily Chua

    2016-11-01

    Full Text Available Mass spectrometers are versatile sensor systems, owing to their high sensitivity and ability to simultaneously measure multiple chemical species. Over the last two decades, traditional laboratory-based membrane inlet mass spectrometers have been adapted for underwater use. Underwater mass spectrometry has drastically improved our capability to monitor a broad suite of gaseous compounds (e.g., dissolved atmospheric gases, light hydrocarbons, and volatile organic compounds in the aquatic environment. Here we provide an overview of the progress made in the field of underwater mass spectrometry since its inception in the 1990s to the present. In particular, we discuss the approaches undertaken by various research groups in developing in situ mass spectrometers. We also provide examples to illustrate how underwater mass spectrometers have been used in the field. Finally, we present future trends in the field of in situ mass spectrometry. Most of these efforts are aimed at improving the quality and spatial and temporal scales of chemical measurements in the ocean. By providing up-to-date information on underwater mass spectrometry, this review offers guidance for researchers interested in adapting this technology as well as goals for future progress in the field.

  8. Design and Implementation of an Underwater Sound Recording Device

    Directory of Open Access Journals (Sweden)

    Christa M. Woodley

    2011-09-01

    Full Text Available To monitor the underwater sound and pressure waves generated by anthropogenic activities such as underwater blasting and pile driving, an autonomous system was designed to record underwater acoustic signals. The underwater sound recording device (USR allows for connections of two hydrophones or other dynamic pressure sensors, filters high frequency noise out of the collected signals, has a gain that can be independently set for each sensor, and allows for 2 h of data collection. Two versions of the USR were created: a submersible model deployable to a maximum depth of 300 m, and a watertight but not fully submersible model. Tests were performed on the USR in the laboratory using a data acquisition system to send single-frequency sinusoidal voltages directly to each component. These tests verified that the device operates as designed and performs as well as larger commercially available data acquisition systems, which are not suited for field use. On average, the designed gain values differed from the actual measured gain values by about 0.35 dB. A prototype of the device was used in a case study to measure blast pressures while investigating the effect of underwater rock blasting on juvenile Chinook salmon and rainbow trout. In the case study, maximum positive pressure from the blast was found to be significantly correlated with frequency of injury for individual fish. The case study also demonstrated that the device withstood operation in harsh environments, making it a valuable tool for collecting field measurements.

  9. Development of an underwater spin facility for combined environment testing

    Energy Technology Data Exchange (ETDEWEB)

    Roach, D.P.; Nusser, M.A.

    1991-01-01

    In response to a request from the US Government, Sandia National Laboratories has developed an instrumentation system to monitor the conditions along an underwater, rotating drive shaft. It was desired to study the structural integrity and signal acquisition capabilities of the Shaft Instrumentation System (SIS) in an environment which closely simulates the actual deployment conditions. In this manner, the SIS response to ill-defined conditions, such as flow field turbulence or temperature fluctuations, could be determined. An Underwater Spin Facility was developed in order to verify the operation of the instrumentation and telemetric data acquisition system in a combined environment of external pressure, transient axial loads and centrifugal force. The main components of the Underwater Spin Facility are a large, five foot diameter pressure vessel, a dynamically sealed shaft, a drive train assembly and a shaker table interface which is used to apply the axial loads. This paper presents a detailed description of the design of the Underwater Spin Facility. It also discusses the SIS certification test program in order to demonstrate the successful performance of the Underwater Spin Facility. 8 refs., 10 figs.

  10. Fatigue life extension of epoxy materials using ultrafast epoxy-SbF5 healing system introduced by manual infiltration

    Directory of Open Access Journals (Sweden)

    X. J. Ye

    2015-03-01

    Full Text Available The present paper is devoted to the verification of the capability of epoxy-SbF5 system as a healing chemistry for rapidly retarding and/or arresting fatigue cracks in epoxy materials at room temperature. Owing to the very fast curing speed of epoxy catalyzed by SbF5, epoxy monomer and the hardener (ethanol solution of SbF5–ethanol complex are successively infiltrated into the fracture plane under cyclic loading during the tension-tension fatigue test. As a result, the mechanisms including hydrodynamic pressure crack tip shielding, polymeric wedge and adhesive bonding of the healing agent are revealed. It is found that the healing agent forms solidified wedge at the crack tip within 20 s after start of polymerization of the epoxy monomer, so that the highest healing effect is offered at the moment. The epoxy-SbF5 system proves to be effective in rapidly obstructing fatigue crack propagation (despite that its cured version has lower fracture toughness than the matrix, and satisfies the requirement of constructing fast self-healing polymeric materials.

  11. Design and Analysis of Drive Shaft using Kevlar/Epoxy and Glass/Epoxy as a Composite Material

    Science.gov (United States)

    Karthikeyan, P.; Gobinath, R.; Kumar, L. Ajith; Jenish, D. Xavier

    2017-05-01

    In automobile industry drive shaft is one of the most important components to transmit power form the engine to rear wheel through the differential gear. Generally steel drive shaft is used in automobile industry, nowadays they are more interested to replace steel drive shaft with that of composite drive shaft. The overall objective of this paper is to analyze the composite drive shaft using to find out the best replacement for conventional steel drive shaft. The uses of advanced composite materials such as Kevlar, Graphite, Carbon and Glass with proper resins ware resulted in remarkable achievements in automobile industry because of its greater specific strength and specific modulus, improved fatigue and corrosion resistances and reduction in energy requirements due to reduction in weight as compared to steel shaft. This paper is to presents, the modeling and analysis of drive shaft using Kevlar/Epoxy and Glass/Epoxy as a composite material and to find best replacement for conventional steel drive shafts with an Kevlar/epoxy or Glass/Epoxy resin composite drive shaft. Modeling is done using CATIA software and Analysis is carried out by using ANSYS 10.0 software for easy understanding. The composite drive shaft reduces the weight by 81.67 % for Kevlar/Epoxy and 72.66% for Glass/Epoxy when compared with conventional steel drive shaft.

  12. DISPERSION OF GRAPHENE OXIDE AND ITS FLAME RETARDANCY EFFECT ON EPOXY NANOCOMPOSITES

    Institute of Scientific and Technical Information of China (English)

    Zhou Wang; Xiu-zhi Tang; Zhong-zhen Yu; Peng Guo; Huai-he Song; Xu-sheng Du

    2011-01-01

    Grraphene oxide was prepared by ultrasonication of completely oxidized graphite and used to improve the flame retardancy of epoxy. The epoxy/graphene oxide nanocomposite was studied in terms of exfoliation/dispersion, thermal stability and flame retardancy. X-ray diffraction and transmission electron microscopy confirmed the exfoliation of the graphene oxide nanosheets in epoxy matrix. Cone calorimeter measurements showed that the time to ignition of the epoxy/graphene oxide nanocomposite was longer than that of neat epoxy. The heat release rate curve of the nanocomposite was broadened compared to that of neat epoxy and the peak heat release rate decreased as well.

  13. Informal Workshop on Burial and Mobility Modeling of Munitions in the Underwater Environment

    Science.gov (United States)

    2014-12-01

    WORKSHOP REPORT Informal Workshop on Burial and Mobility Modeling of Munitions in the Underwater Environment DECEMBER 2014 SERDP and...SUBTITLE Informal Workshop on Burial and Mobility Modeling of Munitions 5a. CONTRACT NUMBER in the Underwater Environment 5b. GRANT...relevant project efforts. Quite often, underwater environments can be dynamic locations where munitions are more likely subject to mobility, burial , and

  14. Experimental design applied optimization of a state in epoxy clay dispersion; Planejamento de experimentos aplicado a otimizacao do estado de dispersao de argilas em epoxi

    Energy Technology Data Exchange (ETDEWEB)

    Paz, Juliana D' Avila; Bertholdi, Jonas; Folgueras, Marilena Valadares; Pezin, Sergio Henrique; Coelho, Luiz Antonio Ferreira, E-mail: julianadpaz@yahoo.com.b [Universidade do Estado de Santa Catarina (UDESC), Joinville, SC (Brazil). Centro de Ciencias Tecnologicas

    2010-07-01

    This paper presents some analysis showed that the exfoliation / intercalation of a montmorillonite clay in epoxy resin such as viscosity, X-ray diffraction (XRD), scanning electron microscopy (SEM) and thermogravimetry (TG). Increasing the viscosity of epoxy resin diglycidyl ether bisphenol A with the addition of clay associated with the sonification system at the time of dispersion is a good indication of exfoliation. The X-ray diffraction already cured composite shows a decrease of crystallinity of clay and EDS microanalysis of SEM, non-uniform dispersion of clay in epoxy resin. Thermal analysis TG composite clay / epoxy shows an increase in thermal stability relative to pure epoxy. (author)

  15. Adhesion of PBO Fiber in Epoxy Composites

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The high mechanical and thermal performance of poly p-phenylene- 2, 6-benzobisoxazole ( PBO ) fiber provides great potential applications as reinforcement fibers for composites. A composite of PBO fiber and epoxy resin has excellent electrical insulation properties, therefore, it is considered to be the best choice for the reinforcement in high magnetic field coils for pulsed magnetic fields up to 100 T.However, poor adhesion between PBO fiber and matrix is found because of the chemically inactive and/or relatively smooth surface of the reinforcement fiber preventing efficient chemical bonding in the interface, which is a challenging issue to improve mechanical properties. Here, we report the surface modification of PBO fibers by ultraviolet (UV)irradiation, O2 and NH3 plasma, as well as acidic treatments. The interfacial adhesion strength values of all the treatments show the similar level as determined for aramid fibers by pull-out tests, a significant impact on fibermatrix-adhesion was not achieved. The surface free energy and roughness are increased for both sized and extracted fibers after plasma treatments together with maleic anhydride grafting. The sized fiber shows marginal improvement in adhesion strength and no change in fiber tensile strength because of the barrier effect of the finish.For the extracted fiber, different surface treatments either show no apparent effect or cause reduction in adhesion strength. Atomic force microscopy (AFM) topography analysis of the fracture surfaces proved adhesive failure at the fiber surface. The fiber surface roughness is increased and more surface flaws are induced, which could result in coarse interface structures when the treated fiber surface has no adequate wetting and functional groups. The adhesion failure is further confirmed by similar adhesion strength and compression shear strength values when the fiber was embedded in various epoxy resins with different temperature behavior. The tensile strength of fiber

  16. Underwater temperature on off-shore coral reefs of the Florida Keys, U.S.A.

    Science.gov (United States)

    Kuffner, Ilsa B.

    2017-01-01

    The USGS Coral Reef Ecosystems Studies project (http://coastal.er.usgs.gov/crest/) provides science that helps resource managers tasked with the stewardship of coral reef resources. Coral reef organisms are very sensitive to high and low water-temperature extremes. It is critical to precisely know water temperatures experienced by corals and associated plants and animals that live in the dynamic, nearshore environment to document thresholds in temperature tolerance. Here we provide underwater temperature data recorded every fifteen minutes since 2009 at five off-shore coral reefs in the Florida Keys. From northeast to southwest, these sites are Fowey Rocks (Biscayne National Park), Molasses Reef (Florida Keys National Marine Sanctuary, FKNMS), Crocker Reef (FKNMS), Sombrero Reef (FKNMS), and Pulaski Shoal (Dry Tortugas National Park). Temperatures were recorded with Onset® HOBO® Water Temp Pro V2 (U22-001) data loggers in duplicate at each site. Loggers were attached to concrete blocks fixed to the reef with stainless-steel rods and epoxy at depths of 13 to 16 feet of seawater. A portion of the dataset included here was interpreted in conjunction with coral and algal calcification rates in Kuffner et al. (2013).Kuffner, I.B., Hickey, T.D., and Morrison J.M., 2013, Calcification rates of the massive coral Siderastrea siderea and crustose coralline algae along the Florida Keys (USA) outer-reef tract. Coral Reefs 32:987-997. https://doi.org/10.1007/s00338-013-1047-8Note: This data release was versioned on February 01, 2017. Please see the Suggested Citation section for details.

  17. Frequency Diversity for OFDM Mobile Communication via Underwater Acoustic Channels

    Institute of Scientific and Technical Information of China (English)

    Gang Qiao; Wei Wang; Ran Guo; Rehan Khan; Yue Wang

    2012-01-01

    The major constraint on the performance of orthogonal frequency division multiplexing (OFDM) based underwater acoustic (UWA) communication is to keep subcarriers orthogonal.In this paper,Doppler estimation and the respective compensation technique along with various diversity techniques were deliberated for OFDM-based systems best suited for underwater wireless information exchange.In practice,for mobile communication,adjustment and tuning of transducers in order to get spatial diversity is extremely difficult.Considering the relatively low coherence bandwidth in UWA,the frequency diversity design with the Doppler compensation function was elaborated here.The outfield experiments of mobile underwater acoustic communication (UWAC) based on OFDM were carried out with 0.17 bit/(s.Hz) spectral efficiency.The validity and the dependability of the scheme were also analyzed.

  18. H∞ control for path tracking of autonomous underwater vehicle motion

    Directory of Open Access Journals (Sweden)

    Lin-Lin Wang

    2015-05-01

    Full Text Available In order to simplify the design of path tracking controller and solve the problem relating to nonlinear dynamic model of autonomous underwater vehicle motion planning, feedback linearization method is first adopted to transform the nonlinear dynamic model into an equivalent pseudo-linear dynamic model in horizontal coordinates. Then considering wave disturbance effect, mixed-sensitivity method of H∞ robust control is applied to design state-feedback controller for this equivalent dynamic model. Finally, control law of pseudo-linear dynamic model is transformed into state (surge velocity and yaw angular rate tracking control law of nonlinear dynamic model through inverse coordinate transformation. Simulation indicates that autonomous underwater vehicle path tracking is successfully implemented with this proposed method, and the influence of parameter variation in autonomous underwater vehicle dynamic model on its tracking performance is reduced by H∞ controller. All the results show that the method proposed in this article is effective and feasible.

  19. Depth-Trim Mapping Control of Underwater Vehicle with Fins

    Institute of Scientific and Technical Information of China (English)

    LI Ye; PANG Yong-jie; HUANG Shu-ling; WAN Lei

    2011-01-01

    Underwater vehicle plays an important role in ocean engineering.Depth control by fin is one of the difficulties for underwater vehicle in motion control.Depth control is indirect due to the freedom coupling between trim and axial motion.It includes the method of dynamic analysis and lift-resistance-coefficient experiment and theory algorithm.By considering the current speed and depth deviation,comprehensive interpretation is used in object-planning instruction.Expected depth is transformed into expected trim.Dynamic output fluctuation can be avoided,which is caused by linear mapping of deviation.It is steady and accurate for the motion of controlled underwater vehicles.The feasibility and efficiency of the control method are testified in the pool and natural area for experiments.

  20. Optimal Node Placement in Underwater Wireless Sensor Networks

    KAUST Repository

    Felamban, M.

    2013-03-25

    Wireless Sensor Networks (WSN) are expected to play a vital role in the exploration and monitoring of underwater areas which are not easily reachable by humans. However, underwater communication via acoustic waves is subject to several performance limitations that are very different from those used for terresstrial networks. In this paper, we investigate node placement for building an initial underwater WSN infrastructure. We formulate this problem as a nonlinear mathematical program with the objective of minimizing the total transmission loss under a given number of sensor nodes and targeted coverage volume. The obtained solution is the location of each node represented via a truncated octahedron to fill out the 3D space. Experiments are conducted to verify the proposed formulation, which is solved using Matlab optimization tool. Simulation is also conducted using an ns-3 simulator, and the simulation results are consistent with the obtained results from mathematical model with less than 10% error.

  1. Device for Underwater Laboratory Simulation of Unconfined Blast Waves

    CERN Document Server

    Courtney, Elijah; Courtney, Michael

    2015-01-01

    Shock tubes simulate blast waves to study their effects in air under laboratory conditions; however, few experimental models exist for simulating underwater blast waves that are needed for facilitating experiments in underwater blast transmission, determining injury thresholds in marine animals, validating numerical models, and exploring mitigation strategies for explosive well removals. This method incorporates an oxy-acetylene driven underwater blast simulator which creates peak blast pressures of about 1860 kPa. Shot-to-shot consistency was fair, with an average standard deviation near 150 kPa. Results suggest peak blast pressures from 460 kPa to 1860 kPa are available by adjusting the distance from the source.

  2. Feasibility Studies on Underwater Laser Surface Hardening Process

    Directory of Open Access Journals (Sweden)

    Biao Jin

    2015-01-01

    Full Text Available Laser surface hardening process is a very promising hardening method for ferrous and nonferrous alloys where transformations occur during cooling after laser melting in the solid state. This study experimentally characterizes laser surface hardening of tool steel in both water and air. For the underwater operation, laser surface scanning is performed over the tool steel surface which is immersed in water. The laser surface hardening tests are performed with a maximum 200 W fiber laser with a Gaussian distribution of energy in the beam. For the surface hardening, single-track melting experiment which sequentially scans elongated path of single line has been performed. As the hardened depth depends on the thermal conductivity of the material, the surface temperature and the penetration depth may be varied by underwater laser processing. The feasibility of underwater laser surface hardening process is discussed on the basis of average hardness level and hardened bead shape.

  3. Evaluation of wake detection probability of underwater vehicle by IR

    Science.gov (United States)

    Kou, Wei; Chen, Xuan; Yang, Li; Jin, Fang-yuan

    2016-10-01

    The thermal or cold wake of the underwater vehicles will be formed at the sea surface in different region during sailing, then the underwater vehicles will be detected by airborne or space borne infrared detectors easily, which will imperil their security. A model between the detection probability and the Noise Equivalent Temperature Difference (NETD) of the detectors, and the temperature difference between the wake and the sea surface, etc., was established and the evaluation of detection probability in different discrimination levels and other parameters, such as time, location, atmosphere, sea, detector performance, wake temperature, etc., was realized, and a software named Wake Detection of Underwater Vehicle by Infrared (WDPUV-IR) was developed. The results showed that the detection probability to the wake with high detector performance or large temperature difference or short detection distance or low discrimination level was relatively high, but it was difficult to detect targets with small temperature difference and size when the atmospheric transmittance value was low.

  4. A Cost Effective Block Framing Scheme for Underwater Communication

    Directory of Open Access Journals (Sweden)

    Soo-Hyun Park

    2011-12-01

    Full Text Available In this paper, the Selective Multiple Acknowledgement (SMA method, based on Multiple Acknowledgement (MA, is proposed to efficiently reduce the amount of data transmission by redesigning the transmission frame structure and taking into consideration underwater transmission characteristics. The method is suited to integrated underwater system models, as the proposed method can handle the same amount of data in a much more compact frame structure without any appreciable loss of reliability. Herein, the performance of the proposed SMA method was analyzed and compared to those of the conventional Automatic Repeat-reQuest (ARQ, Block Acknowledgement (BA, block response, and MA methods. The efficiency of the underwater sensor network, which forms a large cluster and mostly contains uplink data, is expected to be improved by the proposed method.

  5. Development and Experiments of the Sea-Wing Underwater Glider

    Institute of Scientific and Technical Information of China (English)

    YU Jian-cheng; ZHANG Ai-qun; JIN Wen-ming; CHEN Qi; TIAN Yu; LIU Chong-jie

    2011-01-01

    Underwater gliders,which glide through water columns by use of a pair of wings,are efficient long-distance,long-duration marine environment observatory platforms.The Sea-Wing underwater glider,developed by the Shenyang Institute of Automation,CAS,is designed for the application of deep-sea environment variables observation.The system components,the mechanical design,and the control system design of the Sea-Wing underwater glider are described in this paper.The pitch and roll adjusting models are derived based on the mechanical design,and the adjusting capabilities for the pitch and roll are analyzed according to the models.Field experiments have been carried out for validating the gliding motion and the ability of measuring ocean environment variables.Experimental results of the motion performances of the glider are presented.

  6. Viscoelastic properties of graphene-based epoxy resins

    Science.gov (United States)

    Nobile, Maria Rossella; Fierro, Annalisa; Rosolia, Salvatore; Raimondo, Marialuigia; Lafdi, Khalid; Guadagno, Liberata

    2015-12-01

    In this paper the viscoelastic properties of an epoxy resin filled with graphene-based nanoparticles have been investigated in the liquid state, before curing, by means of a rotational rheometer equipped with a parallel plate geometry. Exfoliated graphite was prepared using traditional acid intercalation followed by a sudden treatment at high temperature (900°C). The percentage of exfoliated graphite was found to be 56%. The epoxy matrix was prepared by mixing a tetrafunctional precursor with a reactive diluent which produces a significant decrease in the viscosity of the epoxy precursor so that the dispersion step of nanofillers in the matrix can easily occur. The hardener agent, the 4,4-diaminodiphenyl sulfone (DDS), was added at a stoichiometric concentration with respect to all the epoxy rings. The inclusion of the partially exfoliated graphite (pEG) in the formulated epoxy mixture significantly modifies the rheological behaviour of the mixture itself. The epoxy mixture, indeed, shows a Newtonian behaviour while, at 3 wt % pEG content, the complex viscosity of the nanocomposite clearly shows a shear thinning behaviour with η* values much higher at the lower frequencies. The increase in complex viscosity with the increasing of the partially exfoliated graphite content was mostly caused by a dramatic increase in the storage modulus. All the graphene-based epoxy mixtures were cured by a two-stage curing cycles: a first isothermal stage was carried out at the lower temperature of 125°C for 1 hour while the second isothermal stage was performed at the higher temperature of 200°C for 3 hours. The mechanical properties of the cured nanocomposites show high values in the storage modulus and glass transition temperature.

  7. Towards restoration of missing underwater forests.

    Directory of Open Access Journals (Sweden)

    Alexandra H Campbell

    successfully restore these underwater forests.

  8. Bisphenol-A epoxy resin reinforced and toughened by hyperbranched epoxy resin

    Institute of Scientific and Technical Information of China (English)

    ZHANG Daohong; JIA Demin; HUANG Xianbo

    2007-01-01

    The study on toughening and reinforcing of bisphenol-A epoxy resin is one of important developmental direction in the field.This paper reports a one-pot synthesis of aromatic polyester hyperbranched epoxy resin HTDE-2,an effect of HTDE-2 content on the mechanical and thermal performance of the bisphenol-A (E51)/HTDE-2 hybrid resin in detail.Fourier transform infrared (FT-IR) spectrometer,scanning electronic microscopy (SEM),differential scanning calorimetry (DSC),thermogravimetric analysis (TGA),dynamic mechanical thermal analysis (DMA) and molecular simulation technology are used to study the structure of HTDE-2,performance and toughening and reinforcing mechanism of the HTDE-2/E51 hybrid resin.It has been shown that the content of HTDE-2 has an important effect on the performance of the hybrid resin,and the performance of the HTDE-2/E51 blends has maximum with the increase in HTDE-2 content.The impact strength and fracture toughness of the hybrid resin with 9 wt-% HTDE-2 are almost 3.088 and 1.749 times of E51 performance respectively,furthermore,the tensile and flexural strength can also be enhanced about 20.7% and 14.2%,respectively.The glass transition temperature and thermal degradation temperature,however,are found to decrease to some extent.

  9. Design of Automobile Driveshaft using Carbon/Epoxy and Kevlar/Epoxy Composites

    Directory of Open Access Journals (Sweden)

    R. Srinivasa Moorthy

    2013-10-01

    Full Text Available Use of advanced composites has resulted in remarkable achievements in many fields including aviation, marine and automobile engineering, medicine, prosthetics and sports, in terms of improved fatigue and corrosion resistances, high specific strength and specific modulus and reduction in energy requirements owing to reduction in weight. The aim of this work is to replace the conventional steel driveshaft of automobiles with an appropriate composite driveshaft. The conventional driveshafts are made in two pieces for reducing the bending natural frequency, whereas the composite shafts can be made as single-piece shafts, thus reducing the overall weight. Carbon/Epoxy and Kevlar/Epoxy composites were designed and analysed for their appropriateness in terms of torsional strength, bending natural frequency and torsional buckling by comparing them with the conventional steel driveshaft under the same grounds of design constraints and the best-suited composite was recommended. Light has been thrown upon the aspects like mass saving, number of plies and ply distribution.

  10. Self-Healing Photocurable Epoxy/thiol-ene Systems Using an Aromatic Epoxy Resin

    Directory of Open Access Journals (Sweden)

    Ricardo Acosta Ortiz

    2016-01-01

    Full Text Available A rapid and efficient method to obtain self-healing epoxy resins is discussed. This method is based on the use of a thiol-disulfide oligomer obtained by partial oxidation of a multifunctional thiol using a hypervalent iodine (III compound as oxidant. The oligomer was characterized by Fourier transform infrared spectroscopy (FTIR, Raman and nuclear magnetic resonance spectroscopies, and gel permeation chromatography (GPC. The oligomer was a joint component of the thiol-ene system along with a tetra-allyl-functionalized curing agent. The kinetics of the photopolymerization of diglycidylether of bisphenol A (DGEBA revealed that conversions of the epoxy groups as high as 80% were achieved in only 15 minutes by increasing the concentration of the thiol-ene system in the formulation. The disulfide bonds introduced in the copolymer using the thiol-disulfide oligomer allowed the repairing of the test specimens in as little as 10 minutes when the specimens were heated at 80°C or for 500 minutes at room temperature. The analysis of the mechanical properties using dynamic mechanical analysis (DMA showed that the specimens displayed a healing efficiency up to 111% compared with the unhealed specimens, depending on the amount of polythioethers present in the copolymer.

  11. 3D MODELING FOR UNDERWATER ARCHAEOLOGICAL DOCUMENTATION: METRIC VERIFICATIONS

    Directory of Open Access Journals (Sweden)

    S. D’Amelio

    2015-04-01

    Full Text Available The survey in underwater environment has always presented considerable difficulties both operative and technical and this has sometimes made it difficult to use the techniques of survey commonly used for the documentation of Cultural Heritage in dry environment. The work of study concerns the evaluation in terms of capability and accuracy of the Autodesk123DCatch software for the reconstruction of a three-dimensional model of an object in underwater context. The subjects of the study are models generated from sets of photographs and sets of frames extracted from video sequence. The study is based on comparative method, using a reference model, obtained with laser scanner technique.

  12. Underwater sound produced by individual drop impacts and rainfall

    DEFF Research Database (Denmark)

    Pumphrey, Hugh C.; Crum, L. A.; Jensen, Leif Bjørnø

    1989-01-01

    An experimental study of the underwater sound produced by water drop impacts on the surface is described. It is found that sound may be produced in two ways: first when the drop strikes the surface and, second, when a bubble is created in the water. The first process occurs for every drop......; the second occurs for some impacts but not others. A range of conditions is described in which a bubble is produced for every drop impact, and it is shown that these conditions are likely to be met by a significant fraction of the raindrops in a typical shower. Underwater sound produced by artificial as well...

  13. Simulation platform of navigation system for autonomous underwater vehicle

    Institute of Scientific and Technical Information of China (English)

    QIN Zheng; BIAN Xin-qian

    2006-01-01

    In view of the characteristics of underwater navigation, the simulation platform of navigation system for autonomous underwater vehicle has been developed based on Windows platform. The system architecture, net communication and the information flow are discussed. The methods of software realization and some key techniques of the Vehicle Computer and the Navigation Equipment Computer are introduced in particular. The software design of Terrain Matching Computer is introduced also. The simulation platform is verified and analyzed through simulation. The results show that the architecture of the platform is reasonable and reliable, and the mathematic models and simulation algorithms of sub-systems are also valid and practicable.

  14. Underwater gamma surveys of Mururoa and Fangataufa lagoons

    Energy Technology Data Exchange (ETDEWEB)

    Osvath, I.; Povinec, P.; Huynh-Ngoc, L.; Comanducci, J.F. [International Atomic Energy Agency, Marine Environment Laboratory, B.P. 800, MC-98012 (Monaco)

    1999-09-30

    Underwater {gamma}-ray spectrometry is an effective alternative or complement to traditional sampling and laboratory analyses for applications such as contamination assessment in emergency situations, long-term monitoring of radioactive releases or investigation of sunkenradioactive objects. This technique was recently used in a seabed contamination study undertaken at the South Pacific nuclear weapons test sites of the Mururoa and Fangataufa atolls in order to guide and focus sediment core sampling in the areas with highest {gamma}-emitting radionuclide levels. 60Co inventories estimated on the basis of the underwater {gamma}-ray spectrometry survey were in good agreement with results previously obtained by traditional sediment sampling and laboratory analysis.

  15. Performance analysis of Non Linear Filtering Algorithms for underwater images

    CERN Document Server

    Padmavathi, Dr G; Kumar, Mr M Muthu; Thakur, Suresh Kumar

    2009-01-01

    Image filtering algorithms are applied on images to remove the different types of noise that are either present in the image during capturing or injected in to the image during transmission. Underwater images when captured usually have Gaussian noise, speckle noise and salt and pepper noise. In this work, five different image filtering algorithms are compared for the three different noise types. The performances of the filters are compared using the Peak Signal to Noise Ratio (PSNR) and Mean Square Error (MSE). The modified spatial median filter gives desirable results in terms of the above two parameters for the three different noise. Forty underwater images are taken for study.

  16. Pressure vessel made by free forming using underwater explosion

    Directory of Open Access Journals (Sweden)

    H Iyama

    2016-03-01

    Full Text Available Explosive forming is one particular forming technique, in which, mostcommonly, water is used as the pressure transmission medium. In recentyears, we have done the development of the method which obtains anecessary form of the metal by the control of underwater shock wave actson the metal plate, without a metal die. On the other hand, the pressurevessel is required in various fields, but we think that the free forming usingthe underwater shock wave is advantageous in the production of pressurevessel of a simple spherical, ellipse, parabola shape. In this paper, we willintroduce an experiment and several numerical simulations that we carriedout for this technical development.

  17. An algebraic perspective to single-transponder underwater navigation

    DEFF Research Database (Denmark)

    Jouffroy, Jerome; Reger, Johann

    This paper studies the position estimation of an underwater vehicle using a single acoustic transponder. The chosen estimation approach is based on nonlinear differential algebraic methods which allow to express very simply conditions for observability. These are then used in combination with an ......This paper studies the position estimation of an underwater vehicle using a single acoustic transponder. The chosen estimation approach is based on nonlinear differential algebraic methods which allow to express very simply conditions for observability. These are then used in combination...

  18. Underwater Shock Response Analysis of a Floating Vessel

    Directory of Open Access Journals (Sweden)

    J.E. van Aanhold

    1998-01-01

    Full Text Available The response of a surface vessel to underwater shock has been calculated using an explicit finite element analysis. The analysis model is two-dimensional and contains the floating steel structure, a large surrounding water volume and the free surface. The underwater shock is applied in the form of a plane shock wave and cavitation is considered in the analysis. Advanced computer graphics, in particular video animations, provide a powerful and indispensable means for the presentation and evaluation of the analysis results.

  19. Underwater color constancy: enhancement of automatic live fish recognition

    Science.gov (United States)

    Chambah, Majed; Semani, Dahbia; Renouf, Arnaud; Courtellemont, Pierre; Rizzi, Alessandro

    2003-12-01

    We present in this paper some advances in color restoration of underwater images, especially with regard to the strong and non uniform color cast which is typical of underwater images. The proposed color correction method is based on ACE model, an unsupervised color equalization algorithm. ACE is a perceptual approach inspired by some adaptation mechanisms of the human visual system, in particular lightness constancy and color constancy. A perceptual approach presents a lot of advantages: it is unsupervised, robust and has local filtering properties, that lead to more effective results. The restored images give better results when displayed or processed (fish segmentation and feature extraction). The presented preliminary results are satisfying and promising.

  20. A UEP LT Codes Design with Feedback for Underwater Communication

    Directory of Open Access Journals (Sweden)

    Danfeng Zhao

    2016-01-01

    Full Text Available To satisfy the performance requirement of LT codes with Unequal Erasure Protection (UEP in underwater environment, the Weighted Expanding Window Fountain (WEWF code is proposed in this paper. The WEWF codes can achieve strong UEP property by nonuniformly selecting input symbols within each window. To overcome the disadvantages in terms of redundancy in the lower prioritized segments, Correlation Chain Feedback (CCFB is also introduced to help the transmitter to precisely adjust the encoding scheme. Asymptotic analysis and simulation results demonstrate that the proposed approach can achieve lower symbol error rate and less overall redundancy in the underwater acoustic sensor networks.

  1. Analyzing Parabolic Profile Path for Underwater Towed-Cable

    Institute of Scientific and Technical Information of China (English)

    Vineet KSrivastava

    2014-01-01

    This article discusses the dynamic state analysis of underwater towed-cable when tow-ship changes its speed in a direction making parabolic profile path. A three-dimensional model of underwater towed system is studied. The established governing equations for the system have been solved using the central implicit finite-difference method. The obtained difference non-linear coupled equations are solved by Newton’s method and satisfactory results were achieved. The solution of this problem has practical importance in the estimation of dynamic loading and motion, and hence it is directly applicable to the enhancement of safety and the effectiveness of the offshore activities.

  2. Image blending techniques and their application in underwater mosaicing

    CERN Document Server

    Prados, Ricard; Neumann, László

    2014-01-01

    This work proposes strategies and solutions to tackle the problem of building photo-mosaics of very large underwater optical surveys, presenting contributions to the image preprocessing, enhancing and blending steps, and resulting in an improved visual quality of the final photo-mosaic. The text opens with a comprehensive review of mosaicing and blending techniques, before proposing an approach for large scale underwater image mosaicing and blending. In the image preprocessing step, a depth dependent illumination compensation function is used to solve the non-uniform illumination appearance du

  3. Contributions of the Underwater Archeology to the Organological Heritage

    Directory of Open Access Journals (Sweden)

    Jesús Alonso Yllana

    2017-01-01

    Full Text Available The present article focuses on the study of musical instruments remains found in underwater archaeological excavations in different parts of the world which so far were in a state of almost total lack of study. Firstly, they are cataloged, providing musicologists access to these documents. These instruments have the advantage of not having undergone any changes over time, which is not the case with the instruments preserved ashore, as many of them suffered subsequent changes. This line of work establishes a channel of effective communication between the work of underwater archaeologists and musicologists.v

  4. Development of an Underwater Gravity Measurement System Using Autonomous Underwater Vehicle

    Science.gov (United States)

    Shinohara, M.; Ishihara, T.; Yamada, T.; Araya, A.; Kanazawa, T.; Fujimoto, H.; Tsukioka, S.; Omika, S.; Uehira, K.; Iizasa, K.

    2015-12-01

    Gravity survey is one of powerful methods to obtain density structure in crust, especially for exploration of underground deposits. Recent technology of autonomous underwater vehicle (AUV) enables us measure gravity in underwater environment. Measurement of both gravity and gravity gradient is useful to estimate structure. From a model calculation, resolution of 0.1 mGal for gravity and 10 Etoves (E) for gradient measurement is needed for detection of seafloor deposits. From these objectives and specification, we have developed an underwater gravity measurement system for exploration below a seafloor using an AUV. For the gravimeter system, a gravimeter is mounted on a levelling mechanism to keep vertical. Depth rating of the system is 4,200 m. We confirmed that our gravity measurement system has an accuracy of less than 0.04 mGal on a land experiment. The gradiometer has two identical gravimeter aligned vertically 44 cm apart. Difference between two gravimeters is calculated for gravity gradient and a levelling system is also used to keep vertical. We estimate accuracy of 10 E from background noise spectra. We chose AUV Urashima belonging to JAMSTEC, because stable navigation is possible. All the power is supplied from the Urashima and acoustic communication system enables real-time monitoring of the system. The first observation was carried out in September 2012 in Sagami-Bay, Japan. The Urashima made round trip along a single profile. We succeeded in obtaining gravity data and other data for compensation. Information to measure gravity gradient is also obtained. After the data processing, our gravity system is estimated to have accuracy of 0.1 mGal. In August 2014, we carried out the second gravity survey using our system in Izena caldera, the middle Okinawa Trough, where seafloor deposits had been found. The Urashima was navigated on 15 profiles in the survey area at constant speed and depth. We obtained the data from both the gravimeter and gradiometer with

  5. Drug price regulation under consumer moral hazard. Two-part tariffs, uniform price or third-degree price discrimination?

    Science.gov (United States)

    Felder, Stefan

    2004-12-01

    Drug price differences across national markets as they exist in the EU are often justified by the concept of Ramsey prices: with fixed costs for R&D, the optimal mark-ups on marginal costs are inversely related to the price elasticity in the individual markets. This well-known result prevails if consumer moral hazard is taken into account. Contrary to the situation without moral hazard, the uniform price does not necessarily dominate discriminatory pricing in welfare terms. The two-part tariff is a better alternative as it allows governments to address moral hazard. A uniform price combined with lump-payments reflecting differences in the willingness to pay and the moral hazard in member states appears to be an attractive option for a common EU drug market.

  6. Toughening Mechanisms in Silica-Filled Epoxy Nanocomposites

    Science.gov (United States)

    Patel, Binay S.

    Epoxies are widely used as underfill resins throughout the microelectronics industry to mechanically couple and protect various components of flip-chip assemblies. Generally rigid materials largely surround underfill resins. Improving the mechanical and thermal properties of epoxy resins to better match those of their rigid counterparts can help extend the service lifetime of flip-chip assemblies. Recently, researchers have demonstrated that silica nanoparticles are effective toughening agents for lightly-crosslinked epoxies. Improvements in the fracture toughness of silica-filled epoxy nanocomposites have primarily been attributed to two toughening mechanisms: particle debonding with subsequent void growth and matrix shear banding. Various attempts have been made to model the contribution of these toughening mechanisms to the overall fracture energy observed in silica-filled epoxy nanocomposites. However, disparities still exist between experimental and modeled fracture energy results. In this dissertation, the thermal, rheological and mechanical behavior of eight different types of silica-filled epoxy nanocomposites was investigated. Each nanocomposite consisted of up to 10 vol% of silica nanoparticles with particle sizes ranging from 20 nm to 200 nm, with a variety of surface treatments and particle structures. Fractographical analysis was conducted with new experimental approaches in order to accurately identify morphological evidence for each proposed toughening mechanism. Overall, three major insights into the fracture behavior of real world silica-filled epoxy nanocomposites were established. First, microcracking was observed as an essential toughening mechanism in silica-filled epoxy nanocomposites. Microcracking was observed on the surface and subsurface of fractured samples in each type of silica-filled epoxy nanocomposite. The additional toughening contribution of microcracking to overall fracture energy yielded excellent agreement between experimental

  7. Epoxy nanocomposites based on high temperature pyridinium-modified clays.

    Science.gov (United States)

    Zhang, Qingxin; Naito, Kimiyoshi; Qi, Ben; Kagawa, Yutaka

    2009-01-01

    Polymer/clay nanocomposites are generally fabricated by thermal curing or melt compounding at elevated temperatures, however the thermal stability of common alkyl ammonium treated clays is poor and decomposition occurs inevitably during high temperature processing. In this study, we modified clays with an aromatic pyridinium salt. Thermogravimetric analysis (TGA) showed that the onset degradation temperature (Td(onset)) and maximum decomposition temperature (Td(max)) of the pyridinium treatment clays was up to 310 and 457 degrees C respectively implying high thermal stability. The thermal decomposition behaviour of the pyridinium modified clays was discussed. A series of epoxy/clay nanocomposites were synthesized using a diglycidyl ether of bisphenol A (DGEBA) epoxy and diethyltoluene diamine (DETDA). The morphology of epoxy/clay nanocomposites was characterized with wide angle X-ray diffraction (WAXD) and transmission electron microscope (TEM), and intercalated structures were observed. The storage modulus of epoxy was increased but glass transition temperature was decreased with clay incorporation. The effects of clays on glass transition temperature (Tg) of epoxy were also discussed.

  8. Preparation and properties of lignin-epoxy resin composite

    Directory of Open Access Journals (Sweden)

    Quanfu Yin

    2012-11-01

    Full Text Available A cross-linked biomass-polymer composite with a lignin content of up to 60% was prepared by blending lignin with an epoxy resin and polyamine using a hot press molding process. The characteristics of the curing reaction of lignin with epoxy resin were studied using DSC and FTIR analysis. The effect of molding temperature and molding pressure on the mechanical properties and microstructure of the lignin/epoxy resin composite was also studied by SEM, DMA, and TG analyses. The results showed that the epoxy resin can be cured by lignin, and the curing temperature for the blends can be reduced by the introduction of a polyamine cure agent. The properties of the composite, such as bending strength, impact strength, glass-transition temperature, and thermal stability, were evidently influenced by the molding process. A good interfacial combination was formed between lignin and epoxy resin. Increasing the molding temperature and pressure proved beneficial to achieve a better interfacial combination for the composite, and the degree of ductile fracture was increased in the fracture surface of the composite.

  9. SYNTHESIS AND CHARACTERIZATION OF KRAFT LIGNIN-BASED EPOXY RESINS

    Directory of Open Access Journals (Sweden)

    Nour Eddine El Mansouri

    2011-05-01

    Full Text Available Epoxidization is an interesting way to develop a new application of lignin and therefore to improve its application potential. In this work, kraft lignin-based epoxy resins were obtained by the epoxidization reaction, using the kraft lignin recovered directly from pulping liquor and modified by a methylolation reaction. The methylolated lignins were obtained by the reaction of original kraft lignin with formaldehyde and glyoxal, which is a less volatile and less toxic aldehyde. 1H-NMR spectroscopy showed that methylolated kraft lignin has more hydroxymethyl groups than glyoxalated kraft lignin. For the epoxidization reaction we studied the influence of the lignin:NaOH (w/w ratio, temperature, and time of the reaction on the properties of the prepared epoxidized lignins. The structures of lignin-based epoxy resins were followed by epoxy index test and FTIR spectroscopy. Optimal conditions were obtained for lignin-based epoxy resin produced at lignin/NaOH = 1/3 at 70 ºC for 3h. Thermogravimetry analysis (TGA revealed that the epoxidization enhances the thermal stability of lignins and may allow a wider temperature range for applications with lignin epoxy-PF blends.

  10. New Thermal and Microbial Resistant Metal-Containing Epoxy Polymers

    Directory of Open Access Journals (Sweden)

    Tansir Ahamad

    2010-01-01

    Full Text Available A series of metal-containing epoxy polymers have been synthesized by the condensation of epichlorohydrin (1-chloro-2,3-epoxy propane with Schiff base metal complexes in alkaline medium. Schiff base was initially prepared by the reaction of 2,6 dihydroxy 1-napthaldehyde and o-phenylenediamine in 1  :  2 molar ratio and then with metal acetate. All the synthesized compounds were characterized by elemental, spectral, and thermal analysis. The physicochemical properties, viz., epoxy value, hydroxyl content, and chlorine content [mol/100 g] were measured by standard procedures. The antimicrobial activities of these metal-containing epoxy polymers were carried out by using minimum inhibitory concentration (MIC and minimum bactericidal concentration (MBC methods against S. aureus, B. subtilis (Gram-positive bacteria, and E. coli, P. aeruginosa (Gram-negative bacteria. It was found that the ECu(II showed higher antibacterial activity than other metal-chelated epoxy resin while EMn(II exhibited reduced antibacterial activity against all bacteria.

  11. Morphological and Thermal Properties of Cellulose Nanofibrils Reinforced Epoxy Nanocomposites

    Directory of Open Access Journals (Sweden)

    Deniz Aydemir

    2015-04-01

    Full Text Available Epoxy resins have gained attention as important adhesives because they are structurally stable, inert to most chemicals, and highly resistant to oxidation. Different particles can be added to adhesives to improve their properties. In this study, cellulose nanofibrils (CNFs, which have superior mechanical properties, were used as the reinforcing agent. Cellulose nanofi brils were added to epoxy in quantities of 1 %, 2 % and 3 % by weight to prepare nanocomposites. Morphological characterization of the composites was done with scanning electron microscopy (SEM. Thermal properties of the nanocomposites were investigated with Thermogravimetric Analyzer (TGA/DTG and Differential Scanning Calorimeter (DSC. SEM images showed that the cellulose nanofibrils were dispersed partially homogenous throughout the epoxy matrix for 1 % CNF. However, it was observed that the cellulose nanofibrils were aggregated (especially for 2 and 3 % CNFs in some parts of the SEM images, and the ratios of the aggregated parts increased as the loading rate of the cellulose nanofi brils increased. The TGA curve showed that DTG and decomposition temperature of pure epoxy was higher than that of the nanocomposites. The DSC curve showed that the glass transition temperature (Tg value of pure epoxy was found to be similar with Tg of the nanocomposites.

  12. Fiber-Reinforced Reactive Nano-Epoxy Composites

    Science.gov (United States)

    Zhong, Wei-Hong

    2011-01-01

    An ultra-high-molecular-weight polyethylene/ matrix interface based on the fabrication of a reactive nano-epoxy matrix with lower surface energy has been improved. Enhanced mechanical properties versus pure epoxy on a three-point bend test include: strength (25 percent), modulus (20 percent), and toughness (30 percent). Increased thermal properties include higher Tg (glass transition temperature) and stable CTE (coefficient of thermal expansion). Improved processability for manufacturing composites includes faster wetting rates on macro-fiber surfaces, lower viscosity, better resin infusion rates, and improved rheological properties. Improved interfacial adhesion properties with Spectra fibers by pullout tests include initial debonding force of 35 percent, a maximum pullout force of 25 percent, and energy to debond at 65 percent. Improved mechanical properties of Spectra fiber composites (tensile) aging resistance properties include hygrothermal effects. With this innovation, high-performance composites have been created, including carbon fibers/nano-epoxy, glass fibers/nano-epoxy, aramid fibers/ nano-epoxy, and ultra-high-molecularweight polyethylene fiber (UHMWPE).

  13. Liquid crystalline epoxy nanocomposite material for dental application.

    Science.gov (United States)

    Tai, Yun-Yuan; Hsu, Sheng-Hao; Chen, Rung-Shu; Su, Wei-Fang; Chen, Min-Huey

    2015-01-01

    Novel liquid crystalline epoxy nanocomposites, which exhibit reduced polymerization shrinkage and effectively bond to tooth structures, can be applied in esthetic dentistry, including core and post systems, direct and indirect restorations, and dental brackets. The purposes of this study were to investigate the properties of liquid crystalline epoxy nanocomposites including biocompatibility, microhardness, and frictional forces of bracket-like blocks with different filler contents for further clinical applications. In this study, we evaluated liquid crystalline epoxy nanocomposite materials that exhibited various filler contents, by assessing their cell activity performance using a 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay and their microhardness with or without thermocycling. We also evaluated the frictional force between bracket-like duplicates and commercially available esthetic bracket systems using Instron 5566. The liquid crystalline epoxy nanocomposite materials showed good biocompatibility. The materials having high filler content demonstrated greater microhardness compared with commercially available bracket materials, before and after the thermocycling treatment. Thus, manufacturing processes are important to reduce frictional force experienced by orthodontic brackets. The microhardness of the bracket-like blocks made by our new material is superior to the commercially available brackets, even after thermocycling. Our results indicate that the evaluated liquid crystalline epoxy nanocomposite materials are of an appropriate quality for application in dental core and post systems and in various restorations. By applying technology to refine manufacturing processes, these new materials could also be used to fabricate esthetic brackets for orthodontic treatment. Copyright © 2014. Published by Elsevier B.V.

  14. Homogeneous Liquid Phase Transfer of Graphene Oxide into Epoxy Resins.

    Science.gov (United States)

    Amirova, Lyaysan; Surnova, Albina; Balkaev, Dinar; Musin, Delus; Amirov, Rustem; Dimiev, Ayrat M

    2017-04-05

    The quality of polymer composite materials depends on the distribution of the filler in the polymer matrix. Due to the presence of the oxygen functional groups, graphene oxide (GO) has a strong affinity to epoxy resins, providing potential opportunity for the uniform distribution of GO sheets in the matrix. Another advantage of GO over its nonoxidized counterpart is its ability to exfoliate to single-atomic-layer sheets in water and in some organic solvents. However, these advantages of GO have not yet been fully realized due to the lack of the methods efficiently introducing GO into the epoxy resin. Here we develop a novel homogeneous liquid phase transfer method that affords uniform distribution, and fully exfoliated condition of GO in the polymer matrix. The most pronounced alteration of properties of the cured composites is registered at the 0.10%-0.15% GO content. Addition of as little as 0.10% GO leads to the increase of the Young's modulus by 48%. Moreover, we demonstrate successful introduction of GO into the epoxy matrix containing an active diluent-modifier; this opens new venues for fabrication of improved GO-epoxy-modifier composites with a broad range of predesigned properties. The experiments done on reproducing the two literature methods, using alternative GO introduction techniques, lead to either decrease or insignificant increase of the Young's modulus of the resulting GO-epoxy composites.

  15. ETV Program Report: Coatings for Wastewater Collection Systems - Standard Cement Materials, Epoxy Coating 4553

    Science.gov (United States)

    The Standard Cement Materials, Inc. Standard Epoxy Coating 4553™ (SEC 4553) epoxy coating used for wastewater collection system rehabilitation was evaluated by EPA’s Environmental Technology Verification Program under laboratory conditions at the Center for Innovative Grouting Ma...

  16. ETV Program Report: Coatings for Wastewater Collection Systems - Standard Cement Materials, Epoxy Coating 4553

    Science.gov (United States)

    The Standard Cement Materials, Inc. Standard Epoxy Coating 4553™ (SEC 4553) epoxy coating used for wastewater collection system rehabilitation was evaluated by EPA’s Environmental Technology Verification Program under laboratory conditions at the Center for Innovative Grouting Ma...

  17. Engineering the magnetic properties of zigzag graphene nanoribbon by epoxy chains

    Science.gov (United States)

    Pu, H. H.; Rhim, S. H.; Gajdardziksa-Josifovska, M.; Hirschmugl, C. J.; Weinert, M.; Chen, J. H.

    2017-08-01

    The magnetic properties of zigzag graphene nanoribbon (ZGNR) oxidized by either two single epoxy or one epoxy pair chains were investigated here. The results show that the epoxy pair chain essentially produces finite spin moment for both the antiferromagnetic (AFM) and the ferromagnetic (FM) coupling between the ribbon edges, while the two single epoxy chains oxidized ZGNR and pure ZGNR show the trivial moment for the AFM coupling. The total spin moment has a weak dependence on the position of single epoxy and epoxy pair chains inside the ZGNR and on the width of ZGNR. In addition, the ZGNR oxidized by one epoxy pair chain transitions from a half metal to a semiconductor via tuning the Fermi level when the chain shifts inwards from the ribbon edge. Our results suggest the potential for designing graphene-based spintronics by introducing epoxy pair chains.

  18. Mechanical properties of uniaxial natural fabric Grewia tilifolia reinforced epoxy based composites: Effects of chemical treatment

    CSIR Research Space (South Africa)

    Jayaramudu, J

    2014-07-01

    Full Text Available The effects of chemical treatment on the mechanical, morphological, and chemical resistance properties of uniaxial natural fabrics, Grewia tilifolia/epoxy composites, were studied. In order to enhance the interfacial bonding between the epoxy matrix...

  19. A new double layer epoxy coating for corrosion protection of Petroleum Equipments

    Directory of Open Access Journals (Sweden)

    Maher A. El Sockarya

    2014-11-01

    Full Text Available Homogeneous epoxy coating containing polymer nanocomposite (PNC was successfully synthesized and applied on carbon steel substrates by room temperature curing of fully mixed epoxy slurry. (PNC containing both ZNO nanoparticles and epoxy hyper branched polymer (EHBP, a new double layer thin film which comprises ZNO-epoxy as a primer coat and ZNO-EHBP-epoxy as a top coat offers better corrosion protection compared to the purely inorganic ZNO-epoxy coating and hybrid ZNO-EHBP-epoxy coating. Chemical structures of synthesized compounds were confirmed by FTIR, H1NMR spectroscopy and GPC. The surface morphology and phase structure of the produced Zno nanoparticles were characterized by scanning electron microscopy SEM, transmission electron microscopy TEM and X-ray diffraction. Chemical resistance of theses coatings to NaOH and HCL was investigated. The effect of incorporating polymer nanocomposite and new double layer coating on corrosion resistance of epoxy coated steel was investigated by salt spray test.

  20. Polarimetric imaging and retrieval of target polarization characteristics in underwater environment.

    Science.gov (United States)

    Gu, Yalong; Carrizo, Carlos; Gilerson, Alexander A; Brady, Parrish C; Cummings, Molly E; Twardowski, Michael S; Sullivan, James M; Ibrahim, Amir I; Kattawar, George W

    2016-01-20

    Polarized light fields contain more information than simple irradiance and such capabilities provide an advanced tool for underwater imaging. The concept of the beam spread function (BSF) for analysis of scalar underwater imaging was extended to a polarized BSF which considers polarization. The following studies of the polarized BSF in an underwater environment through Monte Carlo simulations and experiments led to a simplified underwater polarimetric imaging model. With the knowledge acquired in the analysis of the polarimetric imaging formation process of a manmade underwater target with known polarization properties, a method to extract the inherent optical properties of the water and to retrieve polarization characteristics of the target was explored. The proposed method for retrieval of underwater target polarization characteristics should contribute to future efforts to reveal the underlying mechanism of polarization camouflage possessed by marine animals and finally to generalize guidelines for creating engineered surfaces capable of similar polarization camouflage abilities in an underwater environment.

  1. The Improved Kriging Interpolation Algorithm for Local Underwater Terrain Based on Fractal Compensation

    Directory of Open Access Journals (Sweden)

    Pengyun Chen

    2014-01-01

    Full Text Available The interpolation-reconstruction of local underwater terrain using the underwater digital terrain map (UDTM is an important step for building an underwater terrain matching unit and directly affects the accuracy of underwater terrain matching navigation. The Kriging method is often used in terrain interpolation, but, with this method, the local terrain features are often lost. Therefore, the accuracy cannot meet the requirements of practical application. Analysis of the geographical features is performed on the basis of the randomness and self-similarity of underwater terrain. We extract the fractal features of local underwater terrain with the fractal Brownian motion model, compensating for the possible errors of the Kriging method with fractal theory. We then put forward an improved Kriging interpolation method based on this fractal compensation. Interpolation-reconstruction tests show that the method can simulate the real underwater terrain features well and that it has good usability.

  2. Underwater terrain positioning method based on least squares estimation for AUV

    Science.gov (United States)

    Chen, Peng-yun; Li, Ye; Su, Yu-min; Chen, Xiao-long; Jiang, Yan-qing

    2015-12-01

    To achieve accurate positioning of autonomous underwater vehicles, an appropriate underwater terrain database storage format for underwater terrain-matching positioning is established using multi-beam data as underwater terrainmatching data. An underwater terrain interpolation error compensation method based on fractional Brownian motion is proposed for defects of normal terrain interpolation, and an underwater terrain-matching positioning method based on least squares estimation (LSE) is proposed for correlation analysis of topographic features. The Fisher method is introduced as a secondary criterion for pseudo localization appearing in a topographic features flat area, effectively reducing the impact of pseudo positioning points on matching accuracy and improving the positioning accuracy of terrain flat areas. Simulation experiments based on electronic chart and multi-beam sea trial data show that drift errors of an inertial navigation system can be corrected effectively using the proposed method. The positioning accuracy and practicality are high, satisfying the requirement of underwater accurate positioning.

  3. STUDY ON COPOLYMER EPOXY RESIN MATRIX WITHOUT SHRINKAGE PART I VOLUME CHANGE DURING CURE PROCESSES

    Institute of Scientific and Technical Information of China (English)

    HE Pingsheng; ZHOU Zhiqiang; WANG Gengchao; PAN Caiyuan; WU Renjie

    1988-01-01

    The volume change of the copolymer epoxy resins can be controlled by copolymerizing epoxy resin E51 with 3,9-di (5-norbornene-2, 2)-1, 5, 7, 11-tetraoxaspiro [5, 5] undecane (NSOC). During curing,the volume changes of copolymer epoxy resins with various amounts of NSOC were measured with a dilatometer. Cure process does not produce volume change when epoxy resin E51: NSOC is 5.88: 1 in equivalent.

  4. STUDY ON THE EPOXY RESIN TOUGHENED BY HYDROXY-TERMINATED BUTADIENE-ACRYLONITRILE COPOLYMER

    Institute of Scientific and Technical Information of China (English)

    HAN Xiaozu; LI Shaoying; ZHANG Qingyu

    1990-01-01

    Toughened epoxy resin with excellent properties was obtained by adding organic acid anhydride curing agent and hydroxy-terminated butadiene-acrylonitrile copolymer (HTBN), which is cheaper than CTBN. The anhydride reacts with both epoxy groups on epoxy resin and hydroxyl groups on HTBN. As a result the soft long chains of HTBN and the rigid chain of epoxy resin form one network, giving the resin toughness. Two-phase structure of the toughened resin was observed by SEM and TEM.

  5. Modification of epoxy resins with thermoplastic segmented polycarbonate-based polyurethanes

    OpenAIRE

    Pavličević Jelena; Jovičić Mirjana; Simendić Vesna; Bera Oskar; Radičević Radmila; Špírková Milena

    2014-01-01

    In this work, epoxy hybrid materials were synthesized by addition of thermoplastic segmented aliphatic polyurethanes with good elastic properties. The modified epoxy samples were obtained by curing of previously homogenized mixture of prepared polyurethane melts, epoxy resin and crosslinking agent Jeffamine D-2000. The influence of different weight content of polyurethanes (5, 10 and 15 wt. % compared to pure epoxy resin) as well the influence of different ...

  6. PREPARATION, CHARACTERIZATION AND THERMAL BEHAVIOR OF ALKYL SUBSTITUTED PHENOLIC EPOXY RESIN

    OpenAIRE

    Jyoti Chaudhary*, Supriya Dadhich, Giriraj Tailor

    2017-01-01

    The present article deals with the synthesis of phenolic epoxy resin by the reaction of phenolic resin and epichlorohydrin. The synthesis of phenolic resin was carried out by using p-ethylphenol, formaldehyde and naphthol. The structures of phenolic and epoxy resins were confirmed by spectroscopic analysis. The synthesized epoxy resin showed solubility in polar solvents like DMF, dioxane, acetone, DMSO, THF, ethyl acetate, and chloroform. Thermal characterization of epoxy resin was monitored ...

  7. Curing of epoxy matrix composite in stratosphere

    Science.gov (United States)

    Kondyurin, Alexey; Kondyurina, Irina; Bilek, Marcela

    Large structures for habitats, greenhouses, space bases, space factories are needed for next stage of space exploitation. A new approach enabling large-size constructions in space relies on the use of the polymerization technology of fiber-filled composites with a curable polymer matrix applied in the free space environment. The polymerisation process is proposed for the material exposed to high vacuum, dramatic temperature changes, space plasma, sun irradiation and atomic oxygen (in low Earth orbit), micrometeorite fluence, electric charging and microgravitation. The stratospheric flight experiments are directed to an investigation of the curing polymer matrix under the stratospheric conditions on. The unique combination of low atmospheric pressure, high intensity UV radiation including short wavelength UV and diurnal temperature variations associated with solar irradiation strongly influences the chemical processes in polymeric materials. The first flight experiment with uncured composites was a part of the NASA scientific balloon flight program realised at the NASA stratospheric balloon station in Alice Springs, Australia. A flight cassette installed on payload was lifted with a “zero-pressure” stratospheric balloon filled with Helium. Columbia Scientific Balloon Facility (CSBF) provided the launch, flight telemetry and landing of the balloon and payload. A cassette of uncured composite materials with an epoxy resin matrix was exposed 3 days in the stratosphere (40 km altitude). The second flight experiment was realised in South Australia in 2012, when the cassette was exposed in 27 km altitude. An analysis of the chemical structure of the composites showed, that the space irradiations are responsible for crosslinking of the uncured polymers exposed in the stratosphere. The first prepreg in the world was cured successfully in stratosphere. The investigations were supported by Alexander von Humboldt Foundation, NASA and RFBR (12-08-00970) grants.

  8. Degradation of epoxy coatings under gamma irradiation

    Science.gov (United States)

    Djouani, F.; Zahra, Y.; Fayolle, B.; Kuntz, M.; Verdu, J.

    2013-01-01

    Epoxy networks based on Diglycidyl ether of bisphenol A (DGEBA) and cured with Jeffamine® (POPA) or polyamidoamine (PAA) were gamma irradiated at 25 °C in air. Dose rates of 50, 200 or 2000 Gy h-1 for doses up 100 kGy were used. Structural changes were monitored by IR spectrophotometry, DSC and sol-gel analysis. Both networks display some common features: for I≥200 Gy h-1, reaction products grow proportionally to time and the rate is a decreasing function of dose rate. The simplest explanation is that peroxy radicals are the main precursors of these products (in the dose rate domain under study), through a unimolecular rearrangement of which an hypothetical mechanism is proposed. DGEBA-POPA are more reactive then DGEBA-PAA networks (according to IR criteria), that can be attributed to the high reactivity of tertiary CH bands in polyoxypropylene segments. The oxidation of these sites leads to methyl ketones. A simple kinetic model in which methyl ketones result from rearrangements of tertiary peroxyls and from tertiary alkoxyls was proposed. It leads to an expression of the radiochemical yield of methyl ketones (G(MK)) of the form G(MK)=a+bI where a and b are parameters depending of elementary rate constants. Experimental G(MK) values are reasonably well fitted by this equation. In DGEBA-PAA networks, a wide variety of oxidation products, among which amides predominate, can be observed. In these networks, chain scissions predominate over crosslinking, whereas a slight predominance of crosslinking was observed, at least for the lowest dose rate, in DGEBA-POPA.

  9. Dynamic Sliding Mode Control Based on Multi-model Switching Laws for the Depth Control of an Autonomous Underwater Vehicle

    Directory of Open Access Journals (Sweden)

    Huanyin Zhou

    2015-07-01

    Full Text Available This manuscript presents an improved control algorithm, called Dynamic Sliding Mode Control based on Multiple Models Switching Laws (DSMC-MMSL, for the control of the depth of the studied Autonomous Underwater Vehicle (AUV system, the diving plane controller of which faces disturbances arising from the coupled states. The diving plane model is strongly coupled with the state variables, such as surge speeds and course angles. To achieve the desired dynamic performance, the proposed algorithm consists of two parts: the diving plane control part and the pitch control part, which is used to avoid large pitch angles. Some direct switching control laws are used for the two parts to avoid some impulse phenomena on the control executions. The error-states exponential decay is recommended to eliminate the chattering on the sliding surface. The DSMC-MMSL controller was successfully implemented and experimentally validated with the studied AUV system designed and built by Shenyang Institute of Automation. The results of some lake trials demonstrated that the depth control performances of the AUV system were as desired, and that the AUV system was robust enough for the coupled state variables under the DSMCMMSL algorithm control.

  10. Dynamic Sliding Mode Control Based on Multi-Model Switching Laws for the Depth Control of an Autonomous Underwater Vehicle

    Directory of Open Access Journals (Sweden)

    Huanyin Zhou

    2015-07-01

    Full Text Available This manuscript presents an improved control algorithm, called Dynamic Sliding Mode Control based on Multiple Models Switching Laws (DSMC-MMSL, for the control of the depth of the studied Autonomous Underwater Vehicle (AUV system, the diving plane controller of which faces disturbances arising from the coupled states. The diving plane model is strongly coupled with the state variables, such as surge speeds and course angles. To achieve the desired dynamic performance, the proposed algorithm consists of two parts: the diving plane control part and the pitch control part, which is used to avoid large pitch angles. Some direct switching control laws are used for the two parts to avoid some impulse phenomena on the control executions. The error-states exponential decay is recommended to eliminate the chattering on the sliding surface. The DSMC-MMSL controller was successfully implemented and experimentally validated with the studied AUV system designed and built by Shenyang Institute of Automation. The results of some lake trials demonstrated that the depth control performances of the AUV system were as desired, and that the AUV system was robust enough for the coupled state variables under the DSMC-MMSL algorithm control.

  11. Acrylate Copolymers as Impact Modiifer for Epoxy Resin

    Institute of Scientific and Technical Information of China (English)

    WANG Tao; WANG Jun; CHEN Wei; DUAN Huajun; YANG Shuang; CHEN Xi; ZHANG Bin

    2015-01-01

    P(BA-GMA) (PBG), having various molecular weights, was synthesized by in situ polymerization of butyl acrylate (BA) and glycidyl methacrylate (GMA), and further used as a modifier to improve the comprehensive properties of the epoxy curing system. The copolymers were characterized by gel permeation chromatography (GPC). The effects of various molecular weights of copolymers on the mechanical properties, thermal performance, and phase behavior of the curing system were carefully evaluated. The experimental results of differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) showed that glass transition temperature decreased and the tan δ peak shifted to a lower temperature with decreasing molecular weight of copolymer. Mechanical properties analysis of curing films showed that the impact strength and fracture toughness increased significantly upon the addition of PBG, indicating good toughness of the modified epoxy resins. From scanning electron microscopy (SEM) studies of the fracture surfaces of ER/PBG systems, the fracture behavior of epoxy matrix was changed from brittleness to toughness.

  12. ensile and Compressive Properties of Kaolin Rienforced Epoxy

    Directory of Open Access Journals (Sweden)

    Jabbar Hussein Mohmmed

    2015-09-01

    Full Text Available The toughening of epoxy resins with the addition of organic or inorganic compounds is of great interest nowadays, considering their large scale of applications. In the present work, composites of epoxy are synthesized with kaolin particles having different particle sizes as reinforcement. Composites of epoxy with varying concentration (0 to 40 weight % of kaolin was prepared by using hand lay method. The variation of mechanical properties such as modulus of elasticity, yield, tensile, and compressive strength with filler content was evaluated. The composite showed improved modulus of elasticity and compressive properties on addition of filler. In contrast, the tensile and yield strength of the composites decreases with rising kaolin content. It is also observed that mechanical properties increase with decrease in particle size in all cases.

  13. On sample preparation and dielectric breakdown in nanostructured epoxy resins

    Energy Technology Data Exchange (ETDEWEB)

    Reading, M; Xu, Z; Lewin, P L; Vaughan, A S, E-mail: asv@ecs.soton.ac.uk [Tony Davies High Voltage Laboratory, University of Southampton (United Kingdom)

    2011-08-12

    There are many methods available to achieve a good dispersion of fillers within a polymeric matrix. This investigation considered several methods of dispersing three chosen fillers within an epoxy resin; the same processes were also performed on unfilled materials to investigate any effects they may have on the host material. For this investigation, the epoxy system (EP) was combined with sodium montmorillonite (MMT), micrometric silicon dioxide (SD) or nanometric silicon dioxide (NSD) as fillers. The effect of the different sample preparation routes on breakdown behaviour was then evaluated. While more thorough mixing protocols were found to lead to improved breakdown behaviour in the case of the various filled systems, surprisingly, an entirely equivalent form of behaviour was also seen in the unfilled epoxy. The influence of changes in sample geometry on the breakdown strength was established.

  14. Dielectric properties of inorganic fillers filled epoxy thin film

    Energy Technology Data Exchange (ETDEWEB)

    Norshamira, A., E-mail: myra.arshad@gmail.com; Mariatti, M., E-mail: mariatti@usm.my [School of Materials and Mineral Resources Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Pulau Pinang (Malaysia)

    2015-07-22

    The demand on the small size and high performance electronics has driven changes in the electronic packaging requirements from discrete capacitor to embedded capacitor. Embedded capacitor can improve electrical performance compared with discrete capacitor. This study aimed to achieve high dielectric of epoxy thin film composite that were targeted for application as embedded capacitor. In this study, inorganic fillers such as Calcium Copper Titanate (CCTO), Iron(III) Oxide (Fe{sub 2}O{sub 3}) and Titanium Dioxide (TiO{sub 2}) were loaded in epoxy system at 5 and 20vol%. Morphology and dielectric properties were investigated to identify the effect of fillers loading and types of fillers on the properties of epoxy thin film composite. Based on the study, CCTO with 20vol% loading was found to have good dielectric properties compared to other type of fillers.

  15. Synthesis and characterization of rubbery epoxy/organoclay hectorite nanocomposites

    Directory of Open Access Journals (Sweden)

    2007-12-01

    Full Text Available The present research investigates the morphology, the mechanical, and the viscoelastic properties of rubbery epoxy/clay nanocomposites synthesized by in situ polymerisation of a prepolymer diglycidyl ether of bisphenol-A crosslinked with an aliphatic diamine based on a polyoxypropylene backbone. The inorganic phase was hectorite, exchanged with octadecylammonium ions in order to give organophilic properties to the phyllosilicate. An ultrasonicator was used to disperse the silicate clay layer into epoxy-amine matrix. The morphology of epoxy-hectorite nanocomposites examined by transmission electron microscopy (TEM showed that mixed delamination or intercalation or microdispersion could occur depending on type of organoclay. Moreover, the mechanical and viscoelastic properties were found to be improved with only the treated hectorite.

  16. DEGRADATION OF MAGNET EPOXY AT NSLS X-RAY RING.

    Energy Technology Data Exchange (ETDEWEB)

    HU,J.P.; ZHONG,Z.; HAAS,E.; HULBERT,S.; HUBBARD,R.

    2004-05-24

    Epoxy resin degradation was analyzed for NSLS X-ring magnets after two decades of 2.58-2.8 GeV continuous electron-beam operation, based on results obtained from thermoluminescent dosimeters irradiated along the NSLS ring and epoxy samples irradiated at the beamline target location. A Monte Carlo-based particle transport code, MCNP, was utilized to verify the dose from synchrotron radiation distributed along the axial- and transverse-direction in a ring model, which simulates the geometry of a ring quadrupole magnet and its central vacuum chamber downstream of the bending-magnet photon ports. The actual life expectancy of thoroughly vacuum baked-and-cured epoxy resin was estimated from radiation tests on similar polymeric materials using a radiation source developed for electrical insulation and mechanical structure studies.

  17. Reinforcement of Epoxies Using Single Walled Carbon Nanotubes

    Science.gov (United States)

    Krishnamoorti, Ramanan; Sharma, Jitendra; Chatterjee, Tirtha

    2008-03-01

    The reinforcement of bisphenol-A and bisphenol-F epoxies using single walled carbon nanotubes has been approached experimentally by understanding the nature of interactions between the matrices and nanotubes. Unassisted dispersions of single walled carbon nanotubes in epoxies were studied by a combination of radiation scattering (elastic small angle scattering and inelastic scattering), DSC based glass transition determination, melt rheology and solid-state mechanical testing in order to understand and correlate changes in local and global dynamics to the tailoring of composite mechanical properties. Significant changes in the glass transition temperature of the matrix can successfully account for changes in the viscoelastic properties of the epoxy dispersions for concentrations below the percolation threshold, while above the percolation threshold the network superstructure formed by the nanotubes controls the viscoelastic properties.

  18. Epoxy-silicate nanocomposites: Cure monitoring and characterization

    Energy Technology Data Exchange (ETDEWEB)

    Hussain, Farzana [Aerospace Manufacturing Technology Center (AMTC), Institute for Aerospace Research (IAR), National Research Council Canada - NRC, Montreal, QC (Canada)]. E-mail: farzssain@gmail.com; Chen, Jihua [Aerospace Manufacturing Technology Center (AMTC), Institute for Aerospace Research (IAR), National Research Council Canada -NRC, Montreal, QC (Canada); Hojjati, Mehdi [Aerospace Manufacturing Technology Center (AMTC), Institute for Aerospace Research (IAR), National Research Council Canada - NRC, Montreal, QC (Canada)

    2007-02-15

    Epoxy-clay nanocomposites were prepared with organically modified layered clay with varying clay contents (1-8 wt.%). Neat resin and nanocomposite were characterized using different techniques. At first, the effect of nanoclay concentration on the cure behaviour was investigated using an on-line dielectric cure monitoring technique. Differential scanning calorimetry (DSC) was used to verify the dielectric measurement results. Furthermore, mechanical and thermal properties were studied using tensile test and Dynamic Mechanical Analysis (DMA), respectively. Experimental results showed that properties of the epoxy were changed evidently because of the nanoclay loading. The tensile modulus of the nanocomposites increased by 47%, however, no improvement in tensile strength and glass transition temperature (T {sub g}) was observed. Fracture surface of the tensile samples were analyzed by Scanning Electron Microscope (SEM). The nanocomposites structures were characterized with Wide Angle X-Ray Diffraction (WAXD) and Transmission Electron Microscopy (TEM), which revealed the intercalated morphology of clay layers in the epoxy resin systems.

  19. Formation of a metal/epoxy resin interface

    Energy Technology Data Exchange (ETDEWEB)

    Kanzow, J.; Horn, P. Schulze; Kirschmann, M.; Zaporojtchenko, V.; Dolgner, K.; Faupel, F.; Wehlack, C.; Possart, W

    2005-01-15

    Interfaces between cross-linked polymers and metals play a significant role in fields like splicing and coating, metallization of plastics, microelectronics, micro system technology and nanotechnology. In this paper, we present investigations on the interface formation due to metallization (Au, Ag, Cu and Al) by evapouration of the highly cured epoxy resin system diglycidilether of bisphenol a (DGEBA)-diethylene triamine (DETA) with the focus on the structure formation at the interface. A combination of X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), atomic force microscopy (AFM) and a radiotracer technique was used to analyze the metal/epoxy interface. While a strong metal/epoxy interaction was found for Al, the noble metals Au, Ag and Cu grow in a Volmer-Weber mode due to an interplay of surface diffusion and metal cluster growth. Nevertheless, polymer bulk diffusion of these metals is negligible.

  20. Multiple welding of long fiber epoxy vitrimer composites.

    Science.gov (United States)

    Chabert, Erwan; Vial, Jérôme; Cauchois, Jean-Pierre; Mihaluta, Marius; Tournilhac, François

    2016-05-25

    Vitrimers appear as a new class of polymers that exhibit mechanical strength and are insoluble even at high temperatures, like thermosets, and yet, like thermoplastics, they are heat processable, recyclable and weldable. The question arises whether this welding property is maintained in composite materials made of more than 50 vol% of reinforcing fibers. In this paper, we quantitatively analyze the bond strength of epoxy vitrimer-based composite plates made by resin transfer molding and compare them to their non-vitrimer counterparts made of a standard thermoset epoxy. It is demonstrated that only epoxy vitrimer samples show substantial bond strength and the ability to be repeatedly welded thanks to the exchange reactions, which promote improved surface conformity and chemical bonding between the adherands at the joint interface. This opens the way towards joining composite parts without adhesives nor mechanical fasteners.