Two-dimensional fourier transform spectrometer
DeFlores, Lauren; Tokmakoff, Andrei
2013-09-03
The present invention relates to a system and methods for acquiring two-dimensional Fourier transform (2D FT) spectra. Overlap of a collinear pulse pair and probe induce a molecular response which is collected by spectral dispersion of the signal modulated probe beam. Simultaneous collection of the molecular response, pulse timing and characteristics permit real time phasing and rapid acquisition of spectra. Full spectra are acquired as a function of pulse pair timings and numerically transformed to achieve the full frequency-frequency spectrum. This method demonstrates the ability to acquire information on molecular dynamics, couplings and structure in a simple apparatus. Multi-dimensional methods can be used for diagnostic and analytical measurements in the biological, biomedical, and chemical fields.
Sui, Liansheng; Liu, Benqing; Wang, Qiang; Li, Ye; Liang, Junli
2015-12-01
A color image encryption scheme is proposed based on Yang-Gu mixture amplitude-phase retrieval algorithm and two-coupled logistic map in gyrator transform domain. First, the color plaintext image is decomposed into red, green and blue components, which are scrambled individually by three random sequences generated by using the two-dimensional Sine logistic modulation map. Second, each scrambled component is encrypted into a real-valued function with stationary white noise distribution in the iterative amplitude-phase retrieval process in the gyrator transform domain, and then three obtained functions are considered as red, green and blue channels to form the color ciphertext image. Obviously, the ciphertext image is real-valued function and more convenient for storing and transmitting. In the encryption and decryption processes, the chaotic random phase mask generated based on logistic map is employed as the phase key, which means that only the initial values are used as private key and the cryptosystem has high convenience on key management. Meanwhile, the security of the cryptosystem is enhanced greatly because of high sensitivity of the private keys. Simulation results are presented to prove the security and robustness of the proposed scheme.
Analysis of two dimensional signals via curvelet transform
Lech, W.; Wójcik, W.; Kotyra, A.; Popiel, P.; Duk, M.
2007-04-01
This paper describes an application of curvelet transform analysis problem of interferometric images. Comparing to two-dimensional wavelet transform, curvelet transform has higher time-frequency resolution. This article includes numerical experiments, which were executed on random interferometric image. In the result of nonlinear approximations, curvelet transform obtains matrix with smaller number of coefficients than is guaranteed by wavelet transform. Additionally, denoising simulations show that curvelet could be a very good tool to remove noise from images.
Paul, Jagannath
Advent of ultrashort lasers made it possible to probe various scattering phenomena in materials that occur in a time scale on the order of few femtoseconds to several tens of picoseconds. Nonlinear optical spectroscopy techniques, such as pump-probe, transient four wave mixing (TFWM), etc., are very common to study the carrier dynamics in various material systems. In time domain, the transient FWM uses several ultrashort pulses separated by time delays to obtain the information of dephasing and population relaxation times, which are very important parameters that govern the carrier dynamics of materials. A recently developed multidimensional nonlinear optical spectroscopy is an enhanced version of TFWM which keeps track of two time delays simultaneously and correlate them in the frequency domain with the aid of Fourier transform in a two dimensional map. Using this technique, the nonlinear complex signal field is characterized both in amplitude and phase. Furthermore, this technique allows us to identify the coupling between resonances which are rather difficult to interpret from time domain measurements. This work focuses on the study of the coherent response of a two dimensional electron gas formed in a modulation doped GaAs/AlGaAs quantum well both at zero and at high magnetic fields. In modulation doped quantum wells, the excitons are formed as a result of the inter- actions of the charged holes with the electrons at the Fermi edge in the conduction band, leading to the formation of Mahan excitons, which is also referred to as Fermi edge singularity (FES). Polarization and temperature dependent rephasing 2DFT spectra in combination with TI-FWM measurements, provides insight into the dephasing mechanism of the heavy hole (HH) Mahan exciton. In addition to that strong quantum coherence between the HH and LH Mahan excitons is observed, which is rather surprising at this high doping concentration. The binding energy of Mahan excitons is expected to be greatly
Two-Dimensional Fourier Transform Analysis of Helicopter Flyover Noise
SantaMaria, Odilyn L.; Farassat, F.; Morris, Philip J.
1999-01-01
A method to separate main rotor and tail rotor noise from a helicopter in flight is explored. Being the sum of two periodic signals of disproportionate, or incommensurate frequencies, helicopter noise is neither periodic nor stationary. The single Fourier transform divides signal energy into frequency bins of equal size. Incommensurate frequencies are therefore not adequately represented by any one chosen data block size. A two-dimensional Fourier analysis method is used to separate main rotor and tail rotor noise. The two-dimensional spectral analysis method is first applied to simulated signals. This initial analysis gives an idea of the characteristics of the two-dimensional autocorrelations and spectra. Data from a helicopter flight test is analyzed in two dimensions. The test aircraft are a Boeing MD902 Explorer (no tail rotor) and a Sikorsky S-76 (4-bladed tail rotor). The results show that the main rotor and tail rotor signals can indeed be separated in the two-dimensional Fourier transform spectrum. The separation occurs along the diagonals associated with the frequencies of interest. These diagonals are individual spectra containing only information related to one particular frequency.
Optical Two Dimensional Fourier Transform Spectroscopy of Layered Metal Dichalcogenides
Dey, P.; Paul, J.; Stevens, C. E.; Kovalyuk, Z. D.; Kudrynskyi, Z. R.; Romero, A. H.; Cantarero, A.; Hilton, D. J.; Shan, J.; Karaiskaj, D.; Z. D. Kovalyuk; Z. R. Kudrynskyi Collaboration; A. H. Romero Collaboration; A. Cantarero Collaboration; D. J. Hilton Collaboration; J. Shan Collaboration
2015-03-01
Nonlinear two-dimensional Fourier transform (2DFT) measurements were used to study the mechanism of excitonic dephasing and probe the electronic structure of the excitonic ground state in layered metal dichalcogenides. Temperature-dependent 2DFT measurements were performed to probe exciton-phonon interactions. Excitation density dependent 2DFT measurements reveal exciton-exciton and exciton-carrier scattering, and the lower limit for the homogeneous linewidth of excitons on positively and negatively doped samples. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award DE-SC0012635.
Phase conjugated Andreev backscattering in two-dimensional ballistic cavities
Morpurgo, A.F.; Holl, S.; Wees, B.J.van; Klapwijk, T.M; Borghs, G.
1997-01-01
We have experimentally investigated transport in two-dimensional ballistic cavities connected to a point contact and to two superconducting electrodes with a tunable macroscopic phase difference. The point contact resistance oscillates as a function of the phase difference in a way which reflects
Optimal Padding for the Two-Dimensional Fast Fourier Transform
Dean, Bruce H.; Aronstein, David L.; Smith, Jeffrey S.
2011-01-01
One-dimensional Fast Fourier Transform (FFT) operations work fastest on grids whose size is divisible by a power of two. Because of this, padding grids (that are not already sized to a power of two) so that their size is the next highest power of two can speed up operations. While this works well for one-dimensional grids, it does not work well for two-dimensional grids. For a two-dimensional grid, there are certain pad sizes that work better than others. Therefore, the need exists to generalize a strategy for determining optimal pad sizes. There are three steps in the FFT algorithm. The first is to perform a one-dimensional transform on each row in the grid. The second step is to transpose the resulting matrix. The third step is to perform a one-dimensional transform on each row in the resulting grid. Steps one and three both benefit from padding the row to the next highest power of two, but the second step needs a novel approach. An algorithm was developed that struck a balance between optimizing the grid pad size with prime factors that are small (which are optimal for one-dimensional operations), and with prime factors that are large (which are optimal for two-dimensional operations). This algorithm optimizes based on average run times, and is not fine-tuned for any specific application. It increases the amount of times that processor-requested data is found in the set-associative processor cache. Cache retrievals are 4-10 times faster than conventional memory retrievals. The tested implementation of the algorithm resulted in faster execution times on all platforms tested, but with varying sized grids. This is because various computer architectures process commands differently. The test grid was 512 512. Using a 540 540 grid on a Pentium V processor, the code ran 30 percent faster. On a PowerPC, a 256x256 grid worked best. A Core2Duo computer preferred either a 1040x1040 (15 percent faster) or a 1008x1008 (30 percent faster) grid. There are many industries that
Quantum phases of dipolar rotors on two-dimensional lattices.
Abolins, B P; Zillich, R E; Whaley, K B
2018-03-14
The quantum phase transitions of dipoles confined to the vertices of two-dimensional lattices of square and triangular geometry is studied using path integral ground state quantum Monte Carlo. We analyze the phase diagram as a function of the strength of both the dipolar interaction and a transverse electric field. The study reveals the existence of a class of orientational phases of quantum dipolar rotors whose properties are determined by the ratios between the strength of the anisotropic dipole-dipole interaction, the strength of the applied transverse field, and the rotational constant. For the triangular lattice, the generic orientationally disordered phase found at zero and weak values of both dipolar interaction strength and applied field is found to show a transition to a phase characterized by net polarization in the lattice plane as the strength of the dipole-dipole interaction is increased, independent of the strength of the applied transverse field, in addition to the expected transition to a transverse polarized phase as the electric field strength increases. The square lattice is also found to exhibit a transition from a disordered phase to an ordered phase as the dipole-dipole interaction strength is increased, as well as the expected transition to a transverse polarized phase as the electric field strength increases. In contrast to the situation with a triangular lattice, on square lattices, the ordered phase at high dipole-dipole interaction strength possesses a striped ordering. The properties of these quantum dipolar rotor phases are dominated by the anisotropy of the interaction and provide useful models for developing quantum phases beyond the well-known paradigms of spin Hamiltonian models, implementing in particular a novel physical realization of a quantum rotor-like Hamiltonian that possesses an anisotropic long range interaction.
Quantum phases of dipolar rotors on two-dimensional lattices
Abolins, B. P.; Zillich, R. E.; Whaley, K. B.
2018-03-01
The quantum phase transitions of dipoles confined to the vertices of two-dimensional lattices of square and triangular geometry is studied using path integral ground state quantum Monte Carlo. We analyze the phase diagram as a function of the strength of both the dipolar interaction and a transverse electric field. The study reveals the existence of a class of orientational phases of quantum dipolar rotors whose properties are determined by the ratios between the strength of the anisotropic dipole-dipole interaction, the strength of the applied transverse field, and the rotational constant. For the triangular lattice, the generic orientationally disordered phase found at zero and weak values of both dipolar interaction strength and applied field is found to show a transition to a phase characterized by net polarization in the lattice plane as the strength of the dipole-dipole interaction is increased, independent of the strength of the applied transverse field, in addition to the expected transition to a transverse polarized phase as the electric field strength increases. The square lattice is also found to exhibit a transition from a disordered phase to an ordered phase as the dipole-dipole interaction strength is increased, as well as the expected transition to a transverse polarized phase as the electric field strength increases. In contrast to the situation with a triangular lattice, on square lattices, the ordered phase at high dipole-dipole interaction strength possesses a striped ordering. The properties of these quantum dipolar rotor phases are dominated by the anisotropy of the interaction and provide useful models for developing quantum phases beyond the well-known paradigms of spin Hamiltonian models, implementing in particular a novel physical realization of a quantum rotor-like Hamiltonian that possesses an anisotropic long range interaction.
Guo, Chuan Fei; Cao, Sihai; Zhang, Jianming; Tang, Haoying; Guo, Shengming; Tian, Ye; Liu, Qian
2011-06-01
Design and synthesis of super-nanostructures is one of the key and prominent topics in nanotechnology. Here we propose a novel methodology for synthesizing complex hierarchical superstructures using sacrificial templates composed of ordered two-dimensional (2D) nanostructures through lattice-directed topotactic transformations. The fabricated superstructures are nested 2D orthogonal Bi(2)S(3) networks composed of nanorods. Further investigation indicates that the lattice matching between the product and sacrificial template is the dominant mechanism for the formation of the superstructures, which agrees well with the simulation results based on an anisotropic nucleation and growth analysis. Our approach may provide a promising way toward a lattice-directed nonlithographic nanofabrication technique for making functional porous nanoarchitectures and electronic devices. © 2011 American Chemical Society
Cinematic camera emulation using two-dimensional color transforms
McElvain, Jon S.; Gish, Walter
2015-02-01
For cinematic and episodic productions, on-set look management is an important component of the creative process, and involves iterative adjustments of the set, actors, lighting and camera configuration. Instead of using the professional motion capture device to establish a particular look, the use of a smaller form factor DSLR is considered for this purpose due to its increased agility. Because the spectral response characteristics will be different between the two camera systems, a camera emulation transform is needed to approximate the behavior of the destination camera. Recently, twodimensional transforms have been shown to provide high-accuracy conversion of raw camera signals to a defined colorimetric state. In this study, the same formalism is used for camera emulation, whereby a Canon 5D Mark III DSLR is used to approximate the behavior a Red Epic cinematic camera. The spectral response characteristics for both cameras were measured and used to build 2D as well as 3x3 matrix emulation transforms. When tested on multispectral image databases, the 2D emulation transforms outperform their matrix counterparts, particularly for images containing highly chromatic content.
Quantum phase transitions in highly crystalline two-dimensional superconductors.
Saito, Yu; Nojima, Tsutomu; Iwasa, Yoshihiro
2018-02-22
Superconductor-insulator transition is one of the remarkable phenomena driven by quantum fluctuation in two-dimensional (2D) systems. Such a quantum phase transition (QPT) was investigated predominantly on highly disordered thin films with amorphous or granular structures using scaling law with constant exponents. Here, we provide a totally different view of QPT in highly crystalline 2D superconductors. According to the magneto-transport measurements in 2D superconducting ZrNCl and MoS 2 , we found that the quantum metallic state commonly observed at low magnetic fields is converted via the quantum Griffiths state to the weakly localized metal at high magnetic fields. The scaling behavior, characterized by the diverging dynamical critical exponent (Griffiths singularity), indicates that the quantum fluctuation manifests itself as superconducting puddles, in marked contrast to the thermal fluctuation. We suggest that an evolution from the quantum metallic to the quantum Griffiths state is generic nature in highly crystalline 2D superconductors with weak pinning potentials.
Phase-sensitive two-dimensional neutron shearing interferometer and Hartmann sensor
Baker, Kevin
2015-12-08
A neutron imaging system detects both the phase shift and absorption of neutrons passing through an object. The neutron imaging system is based on either of two different neutron wavefront sensor techniques: 2-D shearing interferometry and Hartmann wavefront sensing. Both approaches measure an entire two-dimensional neutron complex field, including its amplitude and phase. Each measures the full-field, two-dimensional phase gradients and, concomitantly, the two-dimensional amplitude mapping, requiring only a single measurement.
International Nuclear Information System (INIS)
Leich, A.; Polyntsev, A.D.
1982-01-01
The structure and software of the arithmetical module for the multi-microprocessor intelligent graphics terminal designed for realization of the world coordinate two-dimensional transformation are described. The module performs the operations like coordinate system displacement, scaling and rotation as well as transformations for window/viewport separation
High-pressure phase in tetragonal two-dimensional polymeric C60
International Nuclear Information System (INIS)
Meletov, K.P.; Rossijskaya Akademiya Nauk, Chernogolovka; Arvanitidis, J.; Ves, S.; Kourouklis, G.A.
2001-01-01
The pressure behavior of the phonon modes of tetragonal two-dimensional polymeric C 60 has been studied at pressure up to 27.5 GPa and room temperature by means of Raman spectroscopy. Gradual transformation of the material to a new phase was observed in the pressure region 18.0-22.0 GPa. The Raman spectrum characteristics of the high-pressure phase provide a strong indication that the fullerene molecular cage is retained and the material may be related to a three-dimensionally polymerized C 60 . The new phase remains stable upon pressure decrease down to 9 GPa. Further release of pressure leads to its transformation to a highly disordered structure whose broad features in the Raman spectrum resemble those of amorphous carbon. (orig.)
Single-shot X-ray phase-contrast imaging using two-dimensional gratings
Energy Technology Data Exchange (ETDEWEB)
Sato, Genta; Itoh, Hidenosuke; Nagai, Kentaro; Nakamura, Takashi; Yamaguchi, Kimiaki; Kondoh, Takeshi; Handa, Soichiro; Ouchi, Chidane; Teshima, Takayuki; Setomoto, Yutaka; Den, Toru [Frontier Research Center, Corporate R and D Headquarters, Canon Inc., 3-30-2 Shimomaruko, Ohta-ku, Tokyo 146-8501 (Japan); Optics Technology Development Center, Corporate R and D Headquarters, Canon Inc., 23-10, Kiyohara-Kogyodanchi, Utsunomiya Tochigi 321-3231 (Japan); Nanotechnology R and D Center, Corporate R and D Headquarters, Canon Inc., 3-30-2 Shimomaruko, Ohta-ku, Tokyo 146-8501 (Japan)
2012-07-31
We developed a two-dimensional gratings-based X-ray interferometer that requires only a single exposure for clinical radiography. The interferometer consisted of a checkerboard phase grating for {pi} phase modulation and a latticed amplitude grating. Using a synchrotron radiation source, the phase grating modulates the X-rays and generates a self-image, transformed to a moire fringe by the amplitude grating. To allow use of a conventional X-ray tube, the latticed source grating was installed downstream from the X-ray tube. Differential phase-contrast and scattering images in two orthogonal directions were obtained by Fourier analysis of the single moire fringe image and an absorption image. Results show that characteristic features of soft tissue in two orthogonal directions were clearly shown in the differential phase-contrast images.
DEFF Research Database (Denmark)
Kretschmer, Silvan; Komsa, Hannu-Pekka; Bøggild, Peter
2017-01-01
The polymorphism of two-dimensional (w2D) transition-metal dichalcogenides (TMDs) and different electronic properties of the polymorphs make TMDs particularly promising materials in the context of applications in electronics. Recently, local transformations from the semiconducting trigonal...... prismatic H phase to the metallic octahedral T phase in 2D MoS2 have been induced by electron irradiation [Nat. Nanotech. 2014, 9, 391], but the mechanism of the transformations remains elusive. Using density functional theory calculations, we study the energetics of the stable and metastable phases of 2D...
Nonequilibrium topological phase transitions in two-dimensional optical lattices
Nakagawa, Masaya; Kawakami, Norio
2014-01-01
Recently, concepts of topological phases of matter are extended to nonequilibrium systems, especially periodically driven systems. In this paper, we construct an example which shows nonequilibrium topological phase transitions using ultracold fermions in optical lattices. We show that the Rabi oscillation has the possibility to induce nonequilibrium topological phases which are classified into time-reversal-invariant topological insulators for a two-orbital model of alkaline-earth-metal atoms. Furthermore, we study the nonequilibrium topological phases using time-dependent Schrieffer-Wolff-type perturbation theory, and we obtain an analytical expression to describe the topological phase transitions from a high-frequency limit of external driving fields.
Curvature effects in two-dimensional optical devices inspired by transformation optics
Yuan, Shuhao
2016-11-14
Light transport in curved quasi two-dimensional waveguides is considered theoretically. Within transformation optics and tensor theory, a concise description of curvature effects on transverse electric and magnetic waves is derived. We show that the curvature can induce light focusing and photonic crystal properties, which are confirmed by finite element simulations. Our results indicate that the curvature is an effective parameter for designing quasi two-dimensional optical devices in the fields of micro and nano photonics. Â© 2016 Author(s).
van Agthoven, Maria A; Barrow, Mark P; Chiron, Lionel; Coutouly, Marie-Aude; Kilgour, David; Wootton, Christopher A; Wei, Juan; Soulby, Andrew; Delsuc, Marc-André; Rolando, Christian; O'Connor, Peter B
2015-12-01
Two-dimensional Fourier transform ion cyclotron resonance mass spectrometry is a data-independent analytical method that records the fragmentation patterns of all the compounds in a sample. This study shows the implementation of atmospheric pressure photoionization with two-dimensional (2D) Fourier transform ion cyclotron resonance mass spectrometry. In the resulting 2D mass spectrum, the fragmentation patterns of the radical and protonated species from cholesterol are differentiated. This study shows the use of fragment ion lines, precursor ion lines, and neutral loss lines in the 2D mass spectrum to determine fragmentation mechanisms of known compounds and to gain information on unknown ion species in the spectrum. In concert with high resolution mass spectrometry, 2D Fourier transform ion cyclotron resonance mass spectrometry can be a useful tool for the structural analysis of small molecules. Graphical Abstract ᅟ.
Chen, Cao; Chu, Xinzhao
2017-09-01
Waves in the atmosphere and ocean are inherently intermittent, with amplitudes, frequencies, or wavelengths varying in time and space. Most waves exhibit wave packet-like properties, propagate at oblique angles, and are often observed in two-dimensional (2-D) datasets. These features make the wavelet transforms, especially the 2-D wavelet approach, more appealing than the traditional windowed Fourier analysis, because the former allows adaptive time-frequency window width (i.e., automatically narrowing window size at high frequencies and widening at low frequencies), while the latter uses a fixed envelope function. This study establishes the mathematical formalism of modified 1-D and 2-D Morlet wavelet transforms, ensuring that the power of the wavelet transform in the frequency/wavenumber domain is equivalent to the mean power of its counterpart in the time/space domain. Consequently, the modified wavelet transforms eliminate the bias against high-frequency/small-scale waves in the conventional wavelet methods and many existing codes. Based on the modified 2-D Morlet wavelet transform, we put forward a wave recognition methodology that automatically identifies and extracts 2-D quasi-monochromatic wave packets and then derives their wave properties including wave periods, wavelengths, phase speeds, and time/space spans. A step-by-step demonstration of this methodology is given on analyzing the lidar data taken during 28-30 June 2014 at McMurdo, Antarctica. The newly developed wave recognition methodology is then applied to two more lidar observations in May and July 2014, to analyze the recently discovered persistent gravity waves in Antarctica. The decomposed inertia-gravity wave characteristics are consistent with the conclusion in Chen et al. (2016a) that the 3-10 h waves are persistent and dominant, and exhibit lifetimes of multiple days. They have vertical wavelengths of 20-30 km, vertical phase speeds of 0.5-2 m/s, and horizontal wavelengths up to several
Separation of complex fringe patterns using two-dimensional continuous wavelet transform.
Pokorski, Krzysztof; Patorski, Krzysztof
2012-12-10
A method for processing fringe patterns containing additively superimposed multiple fringe sets is presented. It enables to analyze different fringe families present in a single image separately. The proposed method is based on a two-dimensional continuous wavelet transform. A robust ridge extraction algorithm for a single fringe set extraction is presented. The method is fully automatic and requires no user interference. Spectral separation of fringe families is not required. Simulations are presented to verify performance and advantage of the proposed method over the Fourier transform based technique. Method validity has been confirmed using experimental images.
Ma, Q.; Boulet, C.; Tipping, R. H.
2014-01-01
The refinement of the Robert-Bonamy (RB) formalism by considering the line coupling for isotropic Raman Q lines of linear molecules developed in our previous study [Q. Ma, C. Boulet, and R. H. Tipping, J. Chem. Phys. 139, 034305 (2013)] has been extended to infrared P and R lines. In these calculations, the main task is to derive diagonal and off-diagonal matrix elements of the Liouville operator iS1 - S2 introduced in the formalism. When one considers the line coupling for isotropic Raman Q lines where their initial and final rotational quantum numbers are identical, the derivations of off-diagonal elements do not require extra correlation functions of the ^S operator and their Fourier transforms except for those used in deriving diagonal elements. In contrast, the derivations for infrared P and R lines become more difficult because they require a lot of new correlation functions and their Fourier transforms. By introducing two dimensional correlation functions labeled by two tensor ranks and making variable changes to become even functions, the derivations only require the latters' two dimensional Fourier transforms evaluated at two modulation frequencies characterizing the averaged energy gap and the frequency detuning between the two coupled transitions. With the coordinate representation, it is easy to accurately derive these two dimensional correlation functions. Meanwhile, by using the sampling theory one is able to effectively evaluate their two dimensional Fourier transforms. Thus, the obstacles in considering the line coupling for P and R lines have been overcome. Numerical calculations have been carried out for the half-widths of both the isotropic Raman Q lines and the infrared P and R lines of C2H2 broadened by N2. In comparison with values derived from the RB formalism, new calculated values are significantly reduced and become closer to measurements.
Two-dimensional Potts antiferromagnets with a phase transition at arbitrarily large q
Czech Academy of Sciences Publication Activity Database
Huang, Y.; Chen, K.; Deng, Y.; Jacobsen, J. L.; Kotecký, R.; Salas, J.; Sokal, Alan D.; Swart, Jan M.
2013-01-01
Roč. 87, Č. 1 (2013), 12136-1-12136-5 ISSN 1539-3755 R&D Projects: GA ČR GAP201/12/2613 Institutional support: RVO:67985556 Keywords : Monte Carlo simulation * two-dimensional lattices * q-state Potts Subject RIV: BE - Theoretical Physics Impact factor: 2.326, year: 2013 http://library.utia.cas.cz/separaty/2013/SI/swart-two-dimensional potts antiferromagnets with a phase transition at arbitrarily large q.pdf
Improved implementation algorithms of the two-dimensional nonseparable linear canonical transform.
Ding, Jian-Jiun; Pei, Soo-Chang; Liu, Chun-Lin
2012-08-01
The two-dimensional nonseparable linear canonical transform (2D NSLCT), which is a generalization of the fractional Fourier transform and the linear canonical transform, is useful for analyzing optical systems. However, since the 2D NSLCT has 16 parameters and is very complicated, it is a great challenge to implement it in an efficient way. In this paper, we improved the previous work and propose an efficient way to implement the 2D NSLCT. The proposed algorithm can minimize the numerical error arising from interpolation operations and requires fewer chirp multiplications. The simulation results show that, compared with the existing algorithm, the proposed algorithms can implement the 2D NSLCT more accurately and the required computation time is also less.
Energy Technology Data Exchange (ETDEWEB)
Kudryavtsev, A.G., E-mail: kudryavtsev_a_g@mail.ru
2013-11-15
The Fokker–Planck equation associated with the two-dimensional stationary Schrödinger equation has the conservation law form that yields a pair of potential equations. The special form of Darboux transformation of the potential equations system is considered. As the potential variable is a nonlocal variable for the Schrödinger equation that provides the nonlocal Darboux transformation for the Schrödinger equation. This nonlocal transformation is applied for obtaining of the exactly solvable two-dimensional stationary Schrödinger equations. The examples of exactly solvable two-dimensional stationary Schrödinger operators with smooth potentials decaying at infinity are obtained.
High-speed fan-beam reconstruction using direct two-dimensional Fourier transform method
International Nuclear Information System (INIS)
Niki, Noboru; Mizutani, Toshio; Takahashi, Yoshizo; Inouye, Tamon.
1984-01-01
Since the first development of X-ray computer tomography (CT), various efforts have been made to obtain high quality of high-speed image. However, the development of high resolution CT and the ultra-high speed CT to be applied to hearts is still desired. The X-ray beam scanning method was already changed from the parallel beam system to the fan-beam system in order to greatly shorten the scanning time. Also, the filtered back projection (DFBP) method has been employed to directly processing fan-beam projection data as reconstruction method. Although the two-dimensional Fourier transform (TFT) method significantly faster than FBP method was proposed, it has not been sufficiently examined for fan-beam projection data. Thus, the ITFT method was investigated, which first executes rebinning algorithm to convert the fan-beam projection data to the parallel beam projection data, thereafter, uses two-dimensional Fourier transform. By this method, although high speed is expected, the reconstructed images might be degraded due to the adoption of rebinning algorithm. Therefore, the effect of the interpolation error of rebinning algorithm on the reconstructed images has been analyzed theoretically, and finally, the result of the employment of spline interpolation which allows the acquisition of high quality images with less errors has been shown by the numerical and visual evaluation based on simulation and actual data. Computation time was reduced to 1/15 for the image matrix of 512 and to 1/30 for doubled matrix. (Wakatsuki, Y.)
Two-dimensional wavelet transform feature extraction for porous silicon chemical sensors.
Murguía, José S; Vergara, Alexander; Vargas-Olmos, Cecilia; Wong, Travis J; Fonollosa, Jordi; Huerta, Ramón
2013-06-27
Designing reliable, fast responding, highly sensitive, and low-power consuming chemo-sensory systems has long been a major goal in chemo-sensing. This goal, however, presents a difficult challenge because having a set of chemo-sensory detectors exhibiting all these aforementioned ideal conditions are still largely un-realizable to-date. This paper presents a unique perspective on capturing more in-depth insights into the physicochemical interactions of two distinct, selectively chemically modified porous silicon (pSi) film-based optical gas sensors by implementing an innovative, based on signal processing methodology, namely the two-dimensional discrete wavelet transform. Specifically, the method consists of using the two-dimensional discrete wavelet transform as a feature extraction method to capture the non-stationary behavior from the bi-dimensional pSi rugate sensor response. Utilizing a comprehensive set of measurements collected from each of the aforementioned optically based chemical sensors, we evaluate the significance of our approach on a complex, six-dimensional chemical analyte discrimination/quantification task problem. Due to the bi-dimensional aspects naturally governing the optical sensor response to chemical analytes, our findings provide evidence that the proposed feature extractor strategy may be a valuable tool to deepen our understanding of the performance of optically based chemical sensors as well as an important step toward attaining their implementation in more realistic chemo-sensing applications. Copyright © 2013 Elsevier B.V. All rights reserved.
Finite element analysis of electromagnetic waves in two-dimensional transformed bianisotropic media.
Liu, Yan; Gralak, Boris; Guenneau, Sebastien
2016-11-14
We analyze the wave propagation in two-dimensional bianisotropic media with the Finite Element Method (FEM). Starting from the Maxwell-Tellegen's equations in bianisotropic media, we derive some system of coupled Partial Differential Equations (PDEs) for longitudinal electric and magnetic field components. These PDEs are implemented in FEM using a solid mechanics formulation. Perfectly Matched Layers (PMLs) are also discussed to model unbounded bianisotropic media. The PDEs and PMLs are then implemented in a finite element software, and transformation optics is further introduced to design some bianisotropic media with interesting functionalities, such as cloaks, concentrators and rotators. In addition, we propose a design of metamaterial with concentric layers made of homogeneous media with isotropic permittivity, permeability and magnetoelectric parameters that mimic the required effective anisotropic tensors of a bianisotropic cloak in the long wavelength limit (homogenization approach). Our numerical results show that transformation based electromagnetic metamaterials can be extended to bianisotropic media.
On the structure of the topological phase of two-dimensional gravity
International Nuclear Information System (INIS)
Witten, E.
1990-01-01
The topological phase of two-dimensional gravity is re-examined. The correlation functions of the naturally occurring operators in the minimal topological model are computed, using topological methods, in genus zero and genus one. The genus-zero results agree with recent results obtained in exact solutions of 'matrix models', suggesting that the two approaches to two-dimensional gravity are equivalent. The coupling of two-dimensional topological gravity to topological sigma models is investigated. The CP 1 model appears to be almost as simple as the pure topological gravity theory. General, model-independent properties of the correlation functions are obtained which hold in coupling to arbitrary topological field theories and can serve as a qualitative definition of the topological phase of two-dimensional gravity. A number of facts that are familiar in the usual phase of string theory, such as the relation between vanishing of the canonical line bundle of a Kaehler manifold and scale invariance of the corresponding field theory, have simpler echoes in the topological phase. (orig.)
International Nuclear Information System (INIS)
Miranda, M; Dorrio, B V; Blanco, J; Diz-Bugarin, J; Ribas, F
2011-01-01
Two-stage phase shifting algorithms make possible to directly recover the sum or the difference of the encoded optical phase of two different fringe patterns. These algorithms can be constructed, for example, by combining known phase shifting algorithms in a non-linear way. In this work two-stage phase shifting algorithms are linked to a two-dimensional characteristic polynomial to qualitatively analyse their behaviour against the main systematic error sources in an analysis protocol like that used for phase shifting algorithms. This tool enables us to understand the propagation of properties from precursor phase shifting algorithms to new evaluation algorithms that can be built from them.
Watanabe, A.; Furukawa, H.
2018-04-01
The resolution of multichannel Fourier transform (McFT) spectroscopy is insufficient for many applications despite its extreme advantage of high throughput. We propose an improved configuration to realise both performance using a two-dimensional area sensor. For the spectral resolution, we obtained the interferogram of a larger optical path difference by shifting the area sensor without altering any optical components. The non-linear phase error of the interferometer was successfully corrected using a phase-compensation calculation. Warping compensation was also applied to realise a higher throughput to accumulate the signal between vertical pixels. Our approach significantly improved the resolution and signal-to-noise ratio by factors of 1.7 and 34, respectively. This high-resolution and high-sensitivity McFT spectrometer will be useful for detecting weak light signals such as those in non-invasive diagnosis.
Melting in Two-Dimensional Lennard-Jones Systems: Observation of a Metastable Hexatic Phase
International Nuclear Information System (INIS)
Chen, K.; Kaplan, T.; Mostoller, M.
1995-01-01
Large scale molecular dynamics simulations of two-dimensional melting have been carried out using a recently revised Parrinello-Rahman scheme on massively parallel supercomputers. A metastable state is observed between the solid and liquid phases in Lennard-Jones systems of 36 864 and 102 400 atoms. This intermediate state shows the characteristics of the hexatic phase predicted by the theory of Kosterlitz, Thouless, Halperin, Nelson, and Young
The Two-Dimensional Wavelet Transform De-noising and Combining with Side Scan Sonar Image
Directory of Open Access Journals (Sweden)
Muhammad Zainuddin Lubis
2017-05-01
Full Text Available This paper puts forward an image de-noising method based on 2D wavelet transform with the application of the method in seabed identification data collection system. Two-dimensional haar wavelets in image processing presents a unified framework for wavelet image compression and combining with side scan sonar image. Seabed identification target have 7 target detection in side scan sonar imagery result. The vibration signals were analyzed to perform fault diagnosis. The obtained signal was time-domain signal. The experiment result shows that the application of 2D wavelet transform image de-noising algorithm can achieve good subjective and objective image quality and help to collect high quality data and analyze the images for the data center with optimum effects, the features from time-domain signal were extracted. 3 vectors were formed which are v1, v2, v3. In Haar wavelet retained energy is 93.8 %, so from the results, it has been concluded that Haar wavelet transform shows the best results in terms of Energy from De-noised Image processing with side scan sonar imagery.
The Two-Dimensional Wavelet Transform De-noising and Combining with Side Scan Sonar Image
Directory of Open Access Journals (Sweden)
Muhammad Zainuddin Lubis
2017-04-01
Full Text Available This paper puts forward an image de-noising method based on 2D wavelet transform with the application of the method in seabed identification data collection system. Two-dimensional haar wavelets in image processing presents a unified framework for wavelet image compression and combining with side scan sonar image. Seabed identification target have 7 target detection in side scan sonar imagery result. The vibration signals were analyzed to perform fault diagnosis. The obtained signal was time-domain signal. The experiment result shows that the application of 2D wavelet transform image de-noising algorithm can achieve good subjective and objective image quality and help to collect high quality data and analyze the images for the data center with optimum effects, the features from time-domain signal were extracted. 3 vectors were formed which are v1, v2, v3. In Haar wavelet retained energy is 93.8 %, so from the results, it has been concluded that Haar wavelet transform shows the best results in terms of Energy from De-noised Image processing with side scan sonar imagery.
Wang, Yun-Peng; Li, Xiang-Guo; Liu, Shuang-Long; Fry, James N.; Cheng, Hai-Ping
2018-03-01
We investigate theoretically magnetism and magnetic phase transitions induced by electrostatic gating of two-dimensional square metal-organic framework compounds. We find that electrostatic gating can induce phase transitions between homogeneous ferromagnetic and various spin-textured antiferromagnetic states. Electronic structure and Wannier function analysis can reveal hybridizations between transition-metal d orbitals and conjugated π orbitals in the organic framework. Mn-containing compounds exhibit a strong d -π hybridization that leads to partially occupied spin-minority bands, in contrast to compounds containing transition-metal ions other than Mn, for which electronic structure around the Fermi energy is only slightly spin split due to weak d -π hybridization and the magnetic interaction is of the Ruderman-Kittel-Kasuya-Yosida type. We use a ferromagnetic Kondo lattice model to understand the phase transition in Mn-containing compounds in terms of carrier density and illuminate the complexity and the potential to control two-dimensional magnetization.
Dissipation-driven phase transition in two-dimensional Josephson arrays
International Nuclear Information System (INIS)
Capriotti, Luca; Cuccoli, Alessandro; Fubini, Andrea; Tognetti, Valerio; Vaia, Ruggero
2005-01-01
We analyze the interplay of dissipative and quantum effects in the proximity of a quantum phase transition. The prototypical system is a resistively shunted two-dimensional Josephson junction array, studied by means of an advanced Fourier path-integral Monte Carlo algorithm. The reentrant superconducting-to-normal phase transition driven by quantum fluctuations, recently discovered in the limit of infinite shunt resistance, persists for moderate dissipation strength but disappears in the limit of small resistance. For large quantum coupling our numerical results show that, beyond a critical dissipation strength, the superconducting phase is always stabilized at sufficiently low temperature. Our phase diagram explains recent experimental findings
Micro-phase separation in two dimensional suspensions of self-propelled spheres and dumbbells.
Tung, Clarion; Harder, Joseph; Valeriani, C; Cacciuto, A
2016-01-14
We use numerical simulations to study the phase behavior of self-propelled spherical and dumbbellar particles interacting via micro-phase separation inducing potentials. Our results indicate that under the appropriate conditions, it is possible to drive the formation of two new active states; a spinning cluster crystal, i.e. an ordered mesoscopic phase having finite size spinning crystallites as lattice sites, and a fluid of living clusters, i.e. a two dimensional fluid where each "particle" is a finite size living cluster. We discuss the dynamics of these phases and suggest ways of extending their stability under a wide range of active forces.
International Nuclear Information System (INIS)
Dakaloyannis, C.
2006-01-01
Full text: (author)The two dimensional quantum superintegrable systems with quadratic integrals of motion on a manifold are classified by using the quadratic associative algebra of the integrals of motion. There are six general fundamental classes of quantum superintegrable systems corresponding to the classical ones. Analytic formulas for the involved integrals are calculated in all the cases. All the known quantum superintegrable systems with quadratic integrals are classified as special cases of these six general classes. The coefficients of the quadratic associative algebra of integrals are calculated and they are compared to the coefficients of the corresponding coefficients of the Poisson quadratic algebra of the classical systems. The quantum coefficients are similar as the classical ones multiplied by a quantum coefficient -n 2 plus a quantum deformation of order n 4 and n 6 . The systems inside the classes are transformed using Stackel transforms in the quantum case as in the classical case and general form is discussed. The idea of the Jacobi Hamiltonian corresponding to the Jacobi metric in the classical case is discussed
The Utilization of Triton X-100 for Enhanced Two-Dimensional Liquid-Phase Proteomics
Kim, Mina; Lee, Sang-Hee; Min, Jiho; Kobayashi, Fumihisa; Um, Hyun-Ju; Kim, Yang-Hoon
2011-01-01
One of the main challenges in proteomics lies in obtaining a high level of reproducible fractionation of the protein samples. Automated two-dimensional liquid phase fractionation (PF2D) system manufactured by Beckman Coulter provides a process well suited for proteome studies. However, the protein recovery efficiency of such system is low when a protocol recommended by the manufacturer is used for metaproteome profiling of environmental sample. In search of an alternative method that can over...
Phase Coexistence in Two-Dimensional Passive and Active Dumbbell Systems
Cugliandolo, Leticia F.; Digregorio, Pasquale; Gonnella, Giuseppe; Suma, Antonio
2017-12-01
We demonstrate that there is a macroscopic coexistence between regions with hexatic order and regions in the liquid or gas phase over a finite interval of packing fractions in active dumbbell systems with repulsive power-law interactions in two dimensions. In the passive limit, this interval remains finite, similar to what has been found in two-dimensional systems of hard and soft disks. We did not find discontinuous behavior upon increasing activity from the passive limit.
Lv, Zeqian; Xu, Xiaohai; Yan, Tianhao; Cai, Yulong; Su, Yong; Zhang, Qingchuan
2018-01-01
In the measurement of plate specimens, traditional two-dimensional (2D) digital image correlation (DIC) is challenged by two aspects: (1) the slant optical axis (misalignment of the optical camera axis and the object surface) and (2) out-of-plane motions (including translations and rotations) of the specimens. There are measurement errors in the results measured by 2D DIC, especially when the out-of-plane motions are big enough. To solve this problem, a novel compensation method has been proposed to correct the unsatisfactory results. The proposed compensation method consists of three main parts: 1) a pre-calibration step is used to determine the intrinsic parameters and lens distortions; 2) a compensation panel (a rigid panel with several markers located at known positions) is mounted to the specimen to track the specimen's motion so that the relative coordinate transformation between the compensation panel and the 2D DIC setup can be calculated using the coordinate transform algorithm; 3) three-dimensional world coordinates of measuring points on the specimen can be reconstructed via the coordinate transform algorithm and used to calculate deformations. Simulations have been carried out to validate the proposed compensation method. Results come out that when the extensometer length is 400 pixels, the strain accuracy reaches 10 με no matter out-of-plane translations (less than 1/200 of the object distance) nor out-of-plane rotations (rotation angle less than 5°) occur. The proposed compensation method leads to good results even when the out-of-plane translation reaches several percents of the object distance or the out-of-plane rotation angle reaches tens of degrees. The proposed compensation method has been applied in tensile experiments to obtain high-accuracy results as well.
Wetting controlled phase transitions in two-dimensional systems of colloids
DEFF Research Database (Denmark)
Gil, Tamir; Ipsen, John Hjorth; Tejero, T.F.
1998-01-01
The phase behavior of disk colloids, embedded in a two-dimensional fluid matrix that undergoes a first-order phase transition, is studied in the complete wetting regime where the thermodynamically metastable fluid phase is stabilized at the surface of the disks. In dilute collections of disks......, the tendency to minimize the extent of the fluid-fluid interface and the extent of the unfavorable wetting phase in the system gives rise to aggregation phenomena and to separation of large domains of disks that have the characteristics of bulk colloidal phases. The conditions for phase transitions among...... cluster gas, liquid, and solid phases of the disk colloids are determined from the corresponding values of the disk chemical potential within an analytic representation of the grand partition function for the excess energy associated with a gas of disk clusters in the low-disk-density limit. The wetting...
High-velocity two-phase flow two-dimensional modeling
International Nuclear Information System (INIS)
Mathes, R.; Alemany, A.; Thilbault, J.P.
1995-01-01
The two-phase flow in the nozzle of a LMMHD (liquid metal magnetohydrodynamic) converter has been studied numerically and experimentally. A two-dimensional model for two-phase flow has been developed including the viscous terms (dragging and turbulence) and the interfacial mass, momentum and energy transfer between the phases. The numerical results were obtained by a finite volume method based on the SIMPLE algorithm. They have been verified by an experimental facility using air-water as a simulation pair and a phase Doppler particle analyzer for velocity and droplet size measurement. The numerical simulation of a lithium-cesium high-temperature pair showed that a nearly homogeneous and isothermal expansion of the two phases is possible with small pressure losses and high kinetic efficiencies. In the throat region a careful profiling is necessary to reduce the inertial effects on the liquid velocity field
Spin supercurrent and effect of quantum phase transition in the two-dimensional XY model
Lima, L. S.
2018-04-01
We have verified the influence of quantum phase transition on spin transport in the spin-1 two-dimensional XY model on the square lattice, with easy plane, single ion and exchange anisotropy. We analyze the effect of the phase transition from the Néel phase to the paramagnetic phase on the AC spin conductivity. Our results show a bit influence of the quantum phase transition on the conductivity. We also obtain a conventional spin transport for ω > 0 and an ideal spin transport in the limit of DC conductivity and therefore, a superfluid spin transport for the DC current in this limit. We have made the diagrammatic expansion for the Green-function with objective to include the effect exciton-exciton scattering on the results.
Steady state bifurcations for phase field crystal equations with underlying two dimensional kernel
Directory of Open Access Journals (Sweden)
Appolinaire Abourou Ella
2015-10-01
Full Text Available This paper is concerned with the study of some properties of stationary solutions to phase field crystal equations bifurcating from a trivial solution. It is assumed that at this trivial solution, the kernel of the underlying linearized operator has dimension two. By means of the multiparameter method, we give a second order approximation of these bifurcating solutions and analyse their stability properties. The main result states that the stability of these solutions can be described by the variation of a certain angle in a two dimensional parameter space. The behaviour of the parameter curve is also investigated.
Heat transfer of phase-change materials in two-dimensional cylindrical coordinates
Labdon, M. B.; Guceri, S. I.
1981-01-01
Two-dimensional phase-change problem is numerically solved in cylindrical coordinates (r and z) by utilizing two Taylor series expansions for the temperature distributions in the neighborhood of the interface location. These two expansions form two polynomials in r and z directions. For the regions sufficiently away from the interface the temperature field equations are numerically solved in the usual way and the results are coupled with the polynomials. The main advantages of this efficient approach include ability to accept arbitrarily time dependent boundary conditions of all types and arbitrarily specified initial temperature distributions. A modified approach using a single Taylor series expansion in two variables is also suggested.
Phase transitions in two-dimensional uniformly frustrated XY models. II. General scheme
International Nuclear Information System (INIS)
Korshunov, S.E.
1986-01-01
For two-dimensional uniformly frustrated XY models the group of symmetry spontaneously broken in the ground state is a cross product of the group of two-dimensional rotations by some discrete group of finite order. Different possibilities of phase transitions in such systems are investigated. The transition to the Coulomb gas with noninteger charges is widely used when analyzing the properties of relevant topological excitations. The number of these excitations includes not only domain walls and traditional (integer) vortices, but also vortices with a fractional number of circulation quanta which are to be localized at bends and intersections of domain walls. The types of possible phase transitions prove to be dependent on their relative sequence: in the case the vanishing of domain wall free energy occurs earlier (at increasing temperature) than the dissociation of pairs of ordinary vortices, the second phase transition is to be associated with dissociation of pairs of fractional vortices. The general statements are illustrated with a number of examples
Applications of neural networks to the studies of phase transitions of two-dimensional Potts models
Li, C.-D.; Tan, D.-R.; Jiang, F.-J.
2018-04-01
We study the phase transitions of two-dimensional (2D) Q-states Potts models on the square lattice, using the first principles Monte Carlo (MC) simulations as well as the techniques of neural networks (NN). We demonstrate that the ideas from NN can be adopted to study these considered phase transitions efficiently. In particular, even with a simple NN constructed in this investigation, we are able to obtain the relevant information of the nature of these phase transitions, namely whether they are first order or second order. Our results strengthen the potential applicability of machine learning in studying various states of matters. Subtlety of applying NN techniques to investigate many-body systems is briefly discussed as well.
Basic studies on two-dimensional heat transfer characteristics of He II with phase changes
Energy Technology Data Exchange (ETDEWEB)
Noda, Takafumi [Energy Conversion Engineering, Interdisciplinary Graduate School of Engineering Science, Kyushu Univ., Kasuga, Fukuoka (Japan); Rao, Y.F.; Fujimoto, Noboru; Morita, Koji; Fukuda, Kenji
2000-01-01
Multi-dimensional analytical model to simulate the heat transfer characteristics of He II with phase changes is proposed. To simulate the heat transfer characteristics which are different according to the phases, parameters such as the thermo-mechanical force in the He II region, and others to deal with the boiling/condensation in the two-phase He I region are added to the Navier-Stockes equation. In order to verify the validity of the model, a two-dimensional transient numerical simulation is performed. The results of transient temperature distributions from the simulation are compared with the experimental ones by Hamaguchi et al. It is found that the present model yields the results in qualitatively good agreement with the experiments and that the model is able to explain the mechanism of the unique temperature characteristics observed in the experiments. (author)
Wang, Chun-Hsiung; Chiu, Shih-Yung; Hsu, Yu-Hsiang; Lee, Shu-Sheng; Lee, Chih-Kung
2017-06-01
A non-contact arterial-induced skin vibration inspection system is implemented. This optical metrology system is constructed with shadow Moiré configuration and the fringe analysis algorithm. Developed with the Region of Interested (ROI) capturing technique and the Two-dimensional Wavelet Transform (2D-CWT) method, this algorithm is able to retrieve the height-correlated phase information from the shadow Moiré fringe patterns. Using a commercial video camera or a CMOS image sensor, this system could monitor the skin-vibration induced by the cyclic deformation of inner layered artery. The cross-sectional variation and the rhythm of heart cycle could be continuously measured for health monitoring purposes. The average vibration amplitude of the artery at the wrist ranges between 20 μm and 50 μm, which is quite subtle comparing with the skin surface structure. Having the non-stationary motion of human body, the traditional phase shifting (PS) technique can be very unstable due to the requirement of several frames of images, especially for case that artery is continuously pumping. To bypass this fundamental issue, the shadow Moiré technique is introduced to enhance the surface deformation characteristic. And the phase information is retrieved by the means of spectrum filtering instead of PS technique, which the phase is calculated from intensity maps of multiple images. The instantaneous surface can therefore be reconstructed individually from each frame, enabling the subtle arterial-induced skin vibration measurement. The comparative results of phase reconstruction between different fringe analysis algorithms will be demonstrated numerically and experimentally. And the electrocardiography (ECG) results will used as the reference for the validity of health monitoring potential of the non-contact arterial-induced skin vibration inspection system.
Existence of several surface-reconstructed phases in a two-dimensional lattice model
Huckaby, Dale A.; Rys, Franz S.
1992-03-01
The zero-temperature phase diagram is rigorously obtained for a two-dimensional lattice model with four energy parameters. It is shown that the parameter space can be divided into regions, together with their boundaries, such that in each region the ground-state configurations are of one of seven different types. These types include one which is nondegenerate, four which are doubly degenerate, one which is infinitely degenerate but with no residual entropy, and one which is infinitely degenerate and has a nonzero residual entropy. The Pirogov-Sinai extension of the Peierls argument is used to establish the existence at low temperatures of four different types of ordered surface-reconstructed phases.
Dynamics of the two-dimensional directed Ising model in the paramagnetic phase
Godrèche, C.; Pleimling, M.
2014-05-01
We consider the nonconserved dynamics of the Ising model on the two-dimensional square lattice, where each spin is influenced preferentially by its east and north neighbours. The single-spin flip rates are such that the stationary state is Gibbsian with respect to the usual ferromagnetic Ising Hamiltonian. We show the existence, in the paramagnetic phase, of a dynamical transition between two regimes of violation of the fluctuation-dissipation theorem in the nonequilibrium stationary state: a regime of weak violation where the stationary fluctuation-dissipation ratio is finite, when the asymmetry parameter is less than a threshold value, and a regime of strong violation where this ratio vanishes asymptotically above the threshold. This study suggests that this novel kind of dynamical transition in nonequilibrium stationary states, already found for the directed Ising chain and the spherical model with asymmetric dynamics, might be quite general. In contrast with the latter models, the equal-time correlation function for the two-dimensional directed Ising model depends on the asymmetry.
Chia, Tze Shyang; Quah, Ching Kheng
2017-10-01
Hexamethylenetetramine-benzoic acid (1/2) (HBA) and hexamethylenetetramine-4-methylbenzoic acid (1/2) (HMBA) co-crystals undergo order-disorder structural phase transition from a low-temperature monoclinic crystal structure to a high-temperature orthorhombic crystal structure at the transition temperatures of 257.5 (5) K (Pn ↔ Fmm2) and 265.5 (5) K (P2 1 /n ↔ Cmcm), respectively, using variable-temperature single-crystal X-ray diffraction analysis. The observed phase transitions were confirmed to be reversible first-order transitions as indicated by the sharp endothermic and exothermic peaks in the differential scanning calorimetry measurement. The three-molecule aggregate of HBA and HMBA consists of a hexamethylenetetramine molecule and two benzoic acid or two 4-methylbenzoic acid molecules, respectively. The acid molecules are ordered at the low-temperature phase and are equally disordered over two positions, which are related by a mirror symmetry, at the high-temperature phase. The two-dimensional supramolecular constructs common to both co-crystals are formed by three-molecule aggregates via weak intermolecular C-H...O and C-H...π interactions into molecular trilayers parallel to the ac plane with small XPac dissimilarity indices and parameters. The PIXEL interaction energies of all corresponding molecular contacts were calculated and the results are comparable between HBA and HMBA co-crystals, resulting in similar lattice energies and transition temperatures despite their two-dimensional isostructural relationship. The observed phase transitions of these two energetically similar co-crystals are triggered by similar mechanisms, i.e. the molecular rotator ordering and structural order-disorder transformation, which induced non-merohedral twinning with similar twin matrices in the low-temperature crystal form of both co-crystals.
Prediction of Two-Dimensional Phase of Boron with Anisotropic Electric Conductivity.
Cui, Zhi-Hao; Jimenez-Izal, Elisa; Alexandrova, Anastassia N
2017-03-16
Two-dimensional (2D) phases of boron are rare and unique. Here we report a new 2D all-boron phase (named the π phase) that can be grown on a W(110) surface. The π phase, composed of four-membered rings and six-membered rings filled with an additional B atom, is predicted to be the most stable on this support. It is characterized by an outstanding stability upon exfoliation off of the W surface, and unusual electronic properties. The chemical bonding analysis reveals the metallic nature of this material, which can be attributed to the multicentered π-bonds. Importantly, the calculated conductivity tensor is anisotropic, showing larger conductivity in the direction of the sheet that is in-line with the conjugated π-bonds, and diminished in the direction where the π-subsystems are connected by single σ-bonds. The π-phase can be viewed as an ultrastable web of aligned conducting boron wires, possibly of interest to applications in electronic devices.
Ahn, Junyeong; Yang, Bohm-Jung
2017-04-01
We study a topological phase transition between a normal insulator and a quantum spin Hall insulator in two-dimensional (2D) systems with time-reversal and twofold rotation symmetries. Contrary to the case of ordinary time-reversal invariant systems, where a direct transition between two insulators is generally predicted, we find that the topological phase transition in systems with an additional twofold rotation symmetry is mediated by an emergent stable 2D Weyl semimetal phase between two insulators. Here the central role is played by the so-called space-time inversion symmetry, the combination of time-reversal and twofold rotation symmetries, which guarantees the quantization of the Berry phase around a 2D Weyl point even in the presence of strong spin-orbit coupling. Pair creation and pair annihilation of Weyl points accompanying partner exchange between different pairs induces a jump of a 2D Z2 topological invariant leading to a topological phase transition. According to our theory, the topological phase transition in HgTe /CdTe quantum well structure is mediated by a stable 2D Weyl semimetal phase because the quantum well, lacking inversion symmetry intrinsically, has twofold rotation about the growth direction. Namely, the HgTe /CdTe quantum well can show 2D Weyl semimetallic behavior within a small but finite interval in the thickness of HgTe layers between a normal insulator and a quantum spin Hall insulator. We also propose that few-layer black phosphorus under perpendicular electric field is another candidate system to observe the unconventional topological phase transition mechanism accompanied by the emerging 2D Weyl semimetal phase protected by space-time inversion symmetry.
Ahn, Junyeong; Yang, Bohm-Jung
2017-04-14
We study a topological phase transition between a normal insulator and a quantum spin Hall insulator in two-dimensional (2D) systems with time-reversal and twofold rotation symmetries. Contrary to the case of ordinary time-reversal invariant systems, where a direct transition between two insulators is generally predicted, we find that the topological phase transition in systems with an additional twofold rotation symmetry is mediated by an emergent stable 2D Weyl semimetal phase between two insulators. Here the central role is played by the so-called space-time inversion symmetry, the combination of time-reversal and twofold rotation symmetries, which guarantees the quantization of the Berry phase around a 2D Weyl point even in the presence of strong spin-orbit coupling. Pair creation and pair annihilation of Weyl points accompanying partner exchange between different pairs induces a jump of a 2D Z_{2} topological invariant leading to a topological phase transition. According to our theory, the topological phase transition in HgTe/CdTe quantum well structure is mediated by a stable 2D Weyl semimetal phase because the quantum well, lacking inversion symmetry intrinsically, has twofold rotation about the growth direction. Namely, the HgTe/CdTe quantum well can show 2D Weyl semimetallic behavior within a small but finite interval in the thickness of HgTe layers between a normal insulator and a quantum spin Hall insulator. We also propose that few-layer black phosphorus under perpendicular electric field is another candidate system to observe the unconventional topological phase transition mechanism accompanied by the emerging 2D Weyl semimetal phase protected by space-time inversion symmetry.
Inada, Yuki; Kamiya, Tomoki; Matsuoka, Shigeyasu; Kumada, Akiko; Ikeda, Hisatoshi; Hidaka, Kunihiko
2018-01-01
Two-dimensional electron density imaging over free burning SF6 arcs and SF6 gas-blast arcs was conducted at current zero using highly sensitive Shack-Hartmann type laser wavefront sensors in order to experimentally characterise electron density distributions for the success and failure of arc interruption in the thermal reignition phase. The experimental results under an interruption probability of 50% showed that free burning SF6 arcs with axially asymmetric electron density profiles were interrupted with a success rate of 88%. On the other hand, the current interruption of SF6 gas-blast arcs was reproducibly achieved under locally reduced electron densities and the interruption success rate was 100%.
Wideband radar cross section reduction using two-dimensional phase gradient metasurfaces
Li, Yongfeng; Zhang, Jieqiu; Qu, Shaobo; Wang, Jiafu; Chen, Hongya; Xu, Zhuo; Zhang, Anxue
2014-06-01
Phase gradient metasurface (PGMs) are artificial surfaces that can provide pre-defined in-plane wave-vectors to manipulate the directions of refracted/reflected waves. In this Letter, we propose to achieve wideband radar cross section (RCS) reduction using two-dimensional (2D) PGMs. A 2D PGM was designed using a square combination of 49 split-ring sub-unit cells. The PGM can provide additional wave-vectors along the two in-plane directions simultaneously, leading to either surface wave conversion, deflected reflection, or diffuse reflection. Both the simulation and experiment results verified the wide-band, polarization-independent, high-efficiency RCS reduction induced by the 2D PGM.
Two-dimensional phase contrast MR angiography of the venous system of lower extremities
International Nuclear Information System (INIS)
Hashimoto, Hiromi; Nakatsuka, Haruki; Tsubakimoto, Mitsuo
1994-01-01
Two-dimensional phase contrast MR angiography (MRA) was performed in 10 healthy volunteers and 14 patients in whom deep venous occlusion was clinically suspected. In all volunteers, MRA demonstrated bilateral great saphenous veins, superficial femoral veins and popliteal veins. Deep veins in the calves were visualized in only 3 of 20 legs (15%) examined, but after applying tourniquets above the knee, they were visualized in 6 of 8 legs (75%). In 5 of 8 patients whose lower extremities were swollen, deep vein occlusions were diagnosed by MRA and in 4 patients deep vein thrombosis was confirmed by computed tomography or conventional venography. In the other 3 patients whose lower extremities were swollen and in 6 patients whose lower extremities were not swollen but who had varicose veins, MRA demonstrated patency of the deep veins. It is concluded that MRA is a non-invasive useful diagnostic technique for evaluating patency of the deep venous system of the lower extremities. (author)
Two-dimensional phase contrast MR angiography of the venous system of lower extremities
Energy Technology Data Exchange (ETDEWEB)
Hashimoto, Hiromi; Nakatsuka, Haruki; Tsubakimoto, Mitsuo (Itami City Hospital, Hyogo (Japan)) (and others)
1994-01-01
Two-dimensional phase contrast MR angiography (MRA) was performed in 10 healthy volunteers and 14 patients in whom deep venous occlusion was clinically suspected. In all volunteers, MRA demonstrated bilateral great saphenous veins, superficial femoral veins and popliteal veins. Deep veins in the calves were visualized in only 3 of 20 legs (15%) examined, but after applying tourniquets above the knee, they were visualized in 6 of 8 legs (75%). In 5 of 8 patients whose lower extremities were swollen, deep vein occlusions were diagnosed by MRA and in 4 patients deep vein thrombosis was confirmed by computed tomography or conventional venography. In the other 3 patients whose lower extremities were swollen and in 6 patients whose lower extremities were not swollen but who had varicose veins, MRA demonstrated patency of the deep veins. It is concluded that MRA is a non-invasive useful diagnostic technique for evaluating patency of the deep venous system of the lower extremities. (author).
Gray, Michael; Dennis, Gary R; Wormell, Paul; Shalliker, R Andrew; Slonecker, Patrick
2002-11-01
Informational theory and a geometric approach to factor analysis were employed to evaluate the degree of orthogonality of a two-dimensional reversed-phase-reversed-phase chromatographic system. The system incorporated a C18 column as one dimension and a carbon clad zirconia column as the second dimension. In order to study the resolving power of this system, the separation of a sample matrix containing an artificial mix of 32 isomers (structural and diastereoisomers) was evaluated. Using this system, between 25 and 28 of the 32 isomers could be separated, depending on the mobile phase combinations--with resolution that could not possibly be achieved in a single one dimensional separation. The results from this study indicate that in order to fully evaluate the resolving power of a 2D system multiple methods of analysis are most appropriate. This becomes increasingly important when the sample contains components that are very closely related and the retention of solutes is clustered in one quadrant of the 2D space. Ultimately, the usefulness of the 2D separation is determined by the goals of analyst.
Winchester, Andrew; Ghosh, Sujoy; Feng, Simin; Elias, Ana Laura; Mallouk, Tom; Terrones, Mauricio; Talapatra, Saikat
2014-02-12
We report on the electrochemical charge storage behavior of few-layered flakes of molybdenum disulfide (MoS2) obtained by liquid phase exfoliation of bulk MoS2 powder in 1-dodecyl-2-pyrrolidinone. The specific capacitances of the exfoliated flakes obtained using a 6 M KOH aqueous solution as an electrolyte were found to be an order of magnitude higher than those of bulk MoS2 (∼0.5 and ∼2 mF cm(-2) for bulk and exfoliated MoS2 electrodes, respectively). The exfoliated MoS2 flakes also showed significant charge storage in different electrolytes, such as organic solvents [1 M tetraethylammonium tetrafluoroborate in propylene carbonate (Et4NBF4 in PC)] and ionic liquids [1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF6)]. The values of specific capacitances obtained using Et4NBF4 in PC and BMIM-PF6 were ∼2.25 and ∼2.4 mF cm(-2), respectively. An analysis of electrochemical impedance spectroscopy using an equivalent circuit modeling was performed to understand the charge storage mechanism of these exfoliated MoS2 flakes using different electrolytes. Our findings indicate that liquid phase exfoliation methods can be used to produce large quantities of electrochemically active, two-dimensional layers of MoS2 and can act as an ideal material in several applications related to electrochemistry.
Complete two-dimensional gel electrophoresis pattern of de novo synthesized acute phase reactants.
Pluschke, G; Jenni, L; van Alphen, L; Lefkovits, I
1986-01-01
The early stages of inflammatory responses are characterized by the rapid synthesis of a heterogenous group of plasma proteins known as acute phase reactants. We show that the complex changes in the serum protein composition of mice in response to infections can easily be analysed by two-dimensional (2D) gel electrophoresis, which allows simultaneous analysis of numerous proteins from small volume samples. While changes in the protein composition can be visualized by silver staining, radiofluorography of gels loaded with serum samples from mice that had been labelled in vivo with 35S-methionine allows an analysis of the changes in the pattern of protein synthesis. Thus, these techniques should allow the evaluation of the relative contributions of alterations of protein synthesis and catabolism to the changes in the overall concentration of individual acute phase reactants. Identification of proteins in the 2 D gel pattern can be easily accomplished by co-electrophoresing small serum samples together with immunoprecipitates obtained from in-vivo labelled serum. Using this approach we were able to identify some of the major acute phase reactants of mice. Some of these proteins, like haptoglobin and haemopexin, show concentration increases that are characteristic for type III reactants like C-reactive protein (CRP) or serum amyloid A component (SAA) in man. Results obtained with serum from healthy and infected human newborns indicate that 2D gel electrophoresis could be used to analyse changes in human plasma protein profiles, which would make it a valuable tool for diagnosis and management in certain clinical situations. Images Fig. 1 Fig. 2 Fig. 3 Fig. 4 PMID:2434273
Long, Zhen; Zhang, Yanhai; Gamache, Paul; Guo, Zhimou; Steiner, Frank; Du, Nana; Liu, Xiaoda; Jin, Yan; Liu, Xingguo; Liu, Lvye
2018-01-01
Current Chinese Pharmacopoeia (ChP) standards apply liquid extraction combined with one dimensional liquid chromatography (1DLC) method for determining alkaloids in herbal medicines. The complex pretreatments lead to a low analytical efficiency and possible component loss. In this study, a heart cutting reversed phase - strong cation exchange two dimensional liquid chromatography (RP - SCX 2DLC) approach was optimized for simultaneously quantifying tropane alkaloids (anisodine, scopolamine and hyoscyamine) in herbal medicines and herbal medicine tablets without further treatment of the filtered extract. The chromatographic conditions were systematically optimized in terms of column type, mobile phase composition and flow rate. To improve peak capacity and obtain symmetric peak shape of alkaloids, a polar group embedded C18 column combined with chaotropic salts was used in the first dimension. To remove the disturbance of non-alkaloids, achieve unique selectivity and acquire symmetric peak shape of alkaloids, an SCX column combined with phosphate buffer was used in the second dimension. Method validation was performed in terms of linearity, precision (0.54-0.82%), recovery (94.1-105.2%), limit of detection (LOD) and limit of quantification (LOQ) of the three analytes varied between 0.067-0.115mgL -1 and 0.195-0.268mgL -1 , respectively. The method demonstrated superiority over 1DLC method in respect of resolution (less alkaloid co-eluted), sample preparation (no pretreatment procedure) and transfer rate (minimum component loss). The optimized RP - SCX 2DLC approach was subsequently applied to quantify target alkaloids in five herbal medicines and herbal medicine tablets from three different manufactures. The results demonstrated that the developed heart cutting RP - SCX 2DLC approach represented a new, strategically significant methodology for the quality evaluation of tropane alkaloid in related herbal medicines that involve complex chemical matrix. Copyright
Refined fourier-transform method of analysis of full two-dimensional digitized interferograms.
Lovrić, Davorin; Vucić, Zlatko; Gladić, Jadranko; Demoli, Nazif; Mitrović, Slobodan; Milas, Mirko
2003-03-10
A refined Fourier-transform method of analysis of interference patterns is presented. The refinements include a method of automatic background subtraction and a way of treating the problem of heterodyning. The method proves particularly useful for analysis of long sequences of interferograms.
Mueed, M. A.
In this Thesis, we present low-temperature magnetotransport studies of two-dimensional (2D) electron and hole systems confined to GaAs quantum wells and subjected to a one-dimensional, periodic density modulation. The modulation is achieved through the piezo-electric effect in GaAs as we fabricate a periodic, strain-inducing superlattice on the sample surface. Under varying perpendicular magnetic field, whenever the carriers' cyclotron orbit becomes commensurate with the modulation period, the magnetoresistance exhibits a minimum value. The resulting oscillations, known as the commensurability oscillations, directly measure the carriers' Fermi wave vector. Imposing a density modulation thus allows us to study the Fermi contour properties of 2D electrons and holes near zero field, and composite fermions (CFs) near the half filling of the lowest Landau level, i.e., filling factor nu=1/2. The application of a parallel magnetic field (B||) also features extensively in the Thesis. First, we use commensurability oscillations to capture the B||-induced deformation and the eventual splitting of the Fermi contour of 2D electrons. We also deduce the scattering time anisotropy of hole-flux CFs whose Fermi contour is rendered anisotropic by B||. Moreover, we study the anisotropic (warped) Fermi contour of 2D holes and hole-flux CFs in wide quantum well samples at B||=0. The results provide evidence that CFs inherit Fermi contour properties from their zero-field counterparts. We further investigate the fate of CFs near the bilayer quantum Hall states at nu=1 and 1/2 induced by a large B||. We observe that the commensurability features of CFs near nu=1 are consistent with half the total carrier density, implying that CFs prefer to stay in separate layers and show a two-component behavior. In contrast, close to nu=1/2, CFs appear single-layer-like (single-component) as their commensurability features correspond to the total density. This finding sheds light on the different
Fraction transfer process in on-line comprehensive two-dimensional liquid phase separations
Czech Academy of Sciences Publication Activity Database
Česla, P.; Křenková, Jana
2017-01-01
Roč. 40, č. 1 (2017), s. 109-123 ISSN 1615-9306 R&D Projects: GA ČR(CZ) GA14-06319S Institutional support: RVO:68081715 Keywords : capillary electrophoresis * comprehensive liquid chromatography * fraction transfer * two-dimensional separations * liquid chromatography Subject RIV: CB - Analytical Chemistry, Separation OBOR OECD: Analytical chemistry Impact factor: 2.557, year: 2016
Shchesnovich, Valery S; Desyatnikov, Anton S; Kivshar, Yuri S
2008-09-01
We study, analytically and numerically, the dynamics of interband transitions in two-dimensional hexagonal periodic photonic lattices. We develop an analytical approach employing the Bragg resonances of different types and derive the effective multi-level models of the Landau-Zener-Majorana type. For two-dimensional periodic potentials without a tilt, we demonstrate the possibility of the Rabi oscillations between the resonant Fourier amplitudes. In a biased lattice, i.e., for a two-dimensional periodic potential with an additional linear tilt, we identify three basic types of the interband transitions or Zener tunnelling. First, this is a quasi-one-dimensional tunnelling that involves only two Bloch bands and occurs when the Bloch index crosses the Bragg planes away from one of the high-symmetry points. In contrast, at the high-symmetry points (i.e., at the M and Gamma points), the Zener tunnelling is essentially two-dimensional, and it involves either three or six Bloch bands being described by the corresponding multi-level Landau-Zener-Majorana systems. We verify our analytical results by numerical simulations and observe an excellent agreement. Finally, we show that phase dislocations, or optical vortices, can tunnel between the spectral bands preserving their topological charge. Our theory describes the propagation of light beams in fabricated or optically-induced two-dimensional photonic lattices, but it can also be applied to the physics of cold atoms and Bose-Einstein condensates tunnelling in tilted two-dimensional optical potentials and other types of resonant wave propagation in periodic media.
Fraction transfer process in on-line comprehensive two-dimensional liquid phase separations
Czech Academy of Sciences Publication Activity Database
Česla, P.; Křenková, Jana
2017-01-01
Roč. 40, č. 1 (2017), s. 109-123 ISSN 1615-9306 R&D Projects: GA ČR(CZ) GA14-06319S Institutional support: RVO:68081715 Keywords : capillary electrophoresis * comprehensive liquid chromatography * fraction transfer * two-dimensional separation s * liquid chromatography Subject RIV: CB - Analytical Chemistry, Separation OBOR OECD: Analytical chemistry Impact factor: 2.557, year: 2016
Diffusionless phase transformations
International Nuclear Information System (INIS)
Vejman, K.M.
1987-01-01
Diffusionless phase transformations in metals and alloys in the process of which atomic displacements occur at the distances lower than interatomic ones and relative correspondence of neighbour atoms is preserved, are considered. Special attention is paid to the mechanism of martensitic transformations. Phenomenologic crystallographical theory of martensitic transformations are presented. Two types of martensitic transformations different from the energy viewpoint are pointed out - thermoelastic and non-thermoelastic ones - which are characterized by transformation hysteresis and ways of martensite - initial phase reverse transformation realization. Mechanical effect in the martensitic transformations have been analyzed. The problem of diffusionless formation of ω-phases and the effect of impurities and vacancies on the process are briefly discussed. The role of charge density waves in phase transformations of the second type (transition of initial phase into noncommensurate one) and of the first type (transition of noncommensurate phase into commensurate one) is considered
International Nuclear Information System (INIS)
Taneichi, T.; Kobayashi, T.
2007-01-01
Discussion on wavelength dependent 'anharmonic' effects in a pump-probe signal for a system of wavepacket on one- and two-dimensional harmonic potentials was given. The Fourier power spectrum of the signal, calculated for a model composed of a three-state electronic system coupled to a set of displaced harmonic oscillators, depends on the pulse duration. Condition under which the wavepacket motion in the harmonic potential substantially deviates from that of the classical point mass is derived. The Fourier power spectrum has enhanced components with frequencies of harmonics even in a system composed of ideally harmonic potentials. Utility of the Fourier analysis of the spectrum for clarification of the squeezed molecular vibrational state is discussed. Calculated oscillatory behavior in phase of a pump-probe signal, as a function of probe frequency, was discussed in terms of a two-dimensional effect on a pump-probe signal
A two-dimensional numerical model of two-phase heat transfer and fluid flow in a kettle reboiler
International Nuclear Information System (INIS)
Edwards, D.P.; Jensen, M.K.
1991-01-01
This paper reports on a numerical model that has been developed to predict the two-dimensional, two-phase flow in a kettle reboiler using a finite difference computer code. The effects of bundle-averaged heat flux, heat transfer mode, weir height, and reboiler size were examined. The recirculation flow rate in the kettle reboiler was found to be strongly dependent upon the bundle-averaged heat flux; the recirculating flow increased with increasing heat flux, reached a plateau, and then decreased with further increases in the heat flux. Differences between the constant wall heat flux and constant wall temperature modes of heat transfer were minimal. The model is an improvement over previous one- and two-dimensional models because; the location of the recirculation center could be predicted, the model included the horizontal flow components within the tube bundle, and the model employed a two-fluid rather than a homogeneous fluid model
A new method for information retrieval in two-dimensional grating-based X-ray phase contrast imaging
International Nuclear Information System (INIS)
Wang Zhi-Li; Gao Kun; Chen Jian; Ge Xin; Tian Yang-Chao; Wu Zi-Yu; Zhu Pei-Ping
2012-01-01
Grating-based X-ray phase contrast imaging has been demonstrated to be an extremely powerful phase-sensitive imaging technique. By using two-dimensional (2D) gratings, the observable contrast is extended to two refraction directions. Recently, we have developed a novel reverse-projection (RP) method, which is capable of retrieving the object information efficiently with one-dimensional (1D) grating-based phase contrast imaging. In this contribution, we present its extension to the 2D grating-based X-ray phase contrast imaging, named the two-dimensional reverse-projection (2D-RP) method, for information retrieval. The method takes into account the nonlinear contributions of two refraction directions and allows the retrieval of the absorption, the horizontal and the vertical refraction images. The obtained information can be used for the reconstruction of the three-dimensional phase gradient field, and for an improved phase map retrieval and reconstruction. Numerical experiments are carried out, and the results confirm the validity of the 2D-RP method
Liu, Hong-xia; Sun, Su-qin; Lv, Guang-hua; Chan, Kelvin K. C.
2006-05-01
In order to develop a rapid and effective analysis method for studying integrally the main constituents in the medicinal materials and their extracts, discriminating the extracts from different extraction process, comparing the categories of chemical constituents in the different extracts and monitoring the qualities of medicinal materials, we applied Fourier transform infrared spectroscopy (FT-IR) associated with second derivative infrared spectroscopy and two-dimensional correlation infrared spectroscopy (2D-IR) to study the main constituents in traditional Chinese medicine Angelica and its different extracts (extracted by petroleum ether, ethanol and water in turn). The findings indicated that FT-IR spectrum can provide many holistic variation rules of chemical constituents. Use of the macroscopical fingerprint characters of FT-IR and 2D-IR spectrum can not only identify the main chemical constituents in medicinal materials and their different extracts, but also compare the components differences among the similar samples. This analytical method is highly rapid, effective, visual and accurate for pharmaceutical research.
Adiana, M. A.; Mazura, M. P.
2011-04-01
Senna alata L. commonly known as candle bush belongs to the family of Fabaceae and the plant has been reported to possess anti-inflammatory, analgesic, laxative and antiplatelet-aggregating activity. In order to develop a rapid and effective analysis method for studying integrally the main constituents in the medicinal materials and their extracts, discriminating the extracts from different extraction process, comparing the categories of chemical constituents in the different extracts and monitoring the qualities of medicinal materials, we applied Fourier transform infrared spectroscopy (FT-IR) associated with second derivative infrared spectroscopy and two-dimensional infrared correlation spectroscopy (2D-IR) to study the main constituents of S. alata and its different extracts (extracted by hexane, dichloromethane, ethyl acetate and methanol in turn). The findings indicated that FT-IR and 2D-IR can provide many holistic variation rules of chemical constituents. Use of the macroscopical fingerprint characters of FT-IR and 2D-IR spectrum can identify the main chemical constituents in medicinal materials and their extracts, but also compare the components differences among similar samples. In a conclusion, FT-IR spectroscopy combined with 2D correlation analysis provides a powerful method for the quality control of traditional medicines.
Zhang, Yan-ling; Chen, Jian-bo; Lei, Yu; Zhou, Qun; Sun, Su-qin; Noda, Isao
2010-06-01
Fourier-transform infrared spectroscopy (FT-IR) and two-dimensional infrared (2D IR) correlation spectroscopy were applied to analyze main components of liquid red wine with different sugar contents and volatilization residues of dry red wine from different manufactures. The infrared spectra, second derivative spectra of dry red wine show the typical peaks of alcohol, while the spectra of sweet wine are composed of the peaks of both alcohol and sugar, and the contribution of sugar enhanced as the increase of sugar content. Using principal component analysis (PCA) method, dry and sweet wine can be readily classified. Analysis of the infrared spectra of the volatilization residues of dry red wine samples from five different manufactures indicates that dry red wine may be composed of glycerol, carboxylic acids or esters and carboxyl ate, at the same time, different dry red wine show different characteristic peaks in the second derivative spectra and 2D IR correlation spectra, which can be used to discriminate the different manufactures and evaluate the quality of wine samples. The results suggested that infrared spectroscopy is a direct and effective method for the analysis of principle components of different red wines and discrimination of different red wines.
Evidence of hexatic phase formation in two-dimensional Lennard-Jones binary arrays
International Nuclear Information System (INIS)
Li, M.; Johnson, W.L.; Goddard, W.A. III
1996-01-01
We report evidence of the hexatic phase formation in Lennard-Jones binary substitutional random arrays from isothermal-isobaric molecular-dynamics simulations. The hexatic phase is analogous to those predicted in Kosterlitz-Thouless theory of melting that is characterized by short-range translational order and quasi-long-range orientational order. At the crystal to hexatic phase transition, dislocation pairs are observed to unbind into isolated dislocations. Further disordering of the hexatic phase, however, does not lead to dissociation of dislocations into disclinations. Instead, the dislocations become clustered and form dislocation networks which results in formation of amorphous phases. copyright 1996 The American Physical Society
Tile-Based Two-Dimensional Phase Unwrapping for Digital Holography Using a Modular Framework.
Directory of Open Access Journals (Sweden)
Georgios C Antonopoulos
Full Text Available A variety of physical and biomedical imaging techniques, such as digital holography, interferometric synthetic aperture radar (InSAR, or magnetic resonance imaging (MRI enable measurement of the phase of a physical quantity additionally to its amplitude. However, the phase can commonly only be measured modulo 2π, as a so called wrapped phase map. Phase unwrapping is the process of obtaining the underlying physical phase map from the wrapped phase. Tile-based phase unwrapping algorithms operate by first tessellating the phase map, then unwrapping individual tiles, and finally merging them to a continuous phase map. They can be implemented computationally efficiently and are robust to noise. However, they are prone to failure in the presence of phase residues or erroneous unwraps of single tiles. We tried to overcome these shortcomings by creating novel tile unwrapping and merging algorithms as well as creating a framework that allows to combine them in modular fashion. To increase the robustness of the tile unwrapping step, we implemented a model-based algorithm that makes efficient use of linear algebra to unwrap individual tiles. Furthermore, we adapted an established pixel-based unwrapping algorithm to create a quality guided tile merger. These original algorithms as well as previously existing ones were implemented in a modular phase unwrapping C++ framework. By examining different combinations of unwrapping and merging algorithms we compared our method to existing approaches. We could show that the appropriate choice of unwrapping and merging algorithms can significantly improve the unwrapped result in the presence of phase residues and noise. Beyond that, our modular framework allows for efficient design and test of new tile-based phase unwrapping algorithms. The software developed in this study is freely available.
Tile-Based Two-Dimensional Phase Unwrapping for Digital Holography Using a Modular Framework
Antonopoulos, Georgios C.; Steltner, Benjamin; Heisterkamp, Alexander; Ripken, Tammo; Meyer, Heiko
2015-01-01
A variety of physical and biomedical imaging techniques, such as digital holography, interferometric synthetic aperture radar (InSAR), or magnetic resonance imaging (MRI) enable measurement of the phase of a physical quantity additionally to its amplitude. However, the phase can commonly only be measured modulo 2π, as a so called wrapped phase map. Phase unwrapping is the process of obtaining the underlying physical phase map from the wrapped phase. Tile-based phase unwrapping algorithms operate by first tessellating the phase map, then unwrapping individual tiles, and finally merging them to a continuous phase map. They can be implemented computationally efficiently and are robust to noise. However, they are prone to failure in the presence of phase residues or erroneous unwraps of single tiles. We tried to overcome these shortcomings by creating novel tile unwrapping and merging algorithms as well as creating a framework that allows to combine them in modular fashion. To increase the robustness of the tile unwrapping step, we implemented a model-based algorithm that makes efficient use of linear algebra to unwrap individual tiles. Furthermore, we adapted an established pixel-based unwrapping algorithm to create a quality guided tile merger. These original algorithms as well as previously existing ones were implemented in a modular phase unwrapping C++ framework. By examining different combinations of unwrapping and merging algorithms we compared our method to existing approaches. We could show that the appropriate choice of unwrapping and merging algorithms can significantly improve the unwrapped result in the presence of phase residues and noise. Beyond that, our modular framework allows for efficient design and test of new tile-based phase unwrapping algorithms. The software developed in this study is freely available. PMID:26599984
Tile-Based Two-Dimensional Phase Unwrapping for Digital Holography Using a Modular Framework.
Antonopoulos, Georgios C; Steltner, Benjamin; Heisterkamp, Alexander; Ripken, Tammo; Meyer, Heiko
2015-01-01
A variety of physical and biomedical imaging techniques, such as digital holography, interferometric synthetic aperture radar (InSAR), or magnetic resonance imaging (MRI) enable measurement of the phase of a physical quantity additionally to its amplitude. However, the phase can commonly only be measured modulo 2π, as a so called wrapped phase map. Phase unwrapping is the process of obtaining the underlying physical phase map from the wrapped phase. Tile-based phase unwrapping algorithms operate by first tessellating the phase map, then unwrapping individual tiles, and finally merging them to a continuous phase map. They can be implemented computationally efficiently and are robust to noise. However, they are prone to failure in the presence of phase residues or erroneous unwraps of single tiles. We tried to overcome these shortcomings by creating novel tile unwrapping and merging algorithms as well as creating a framework that allows to combine them in modular fashion. To increase the robustness of the tile unwrapping step, we implemented a model-based algorithm that makes efficient use of linear algebra to unwrap individual tiles. Furthermore, we adapted an established pixel-based unwrapping algorithm to create a quality guided tile merger. These original algorithms as well as previously existing ones were implemented in a modular phase unwrapping C++ framework. By examining different combinations of unwrapping and merging algorithms we compared our method to existing approaches. We could show that the appropriate choice of unwrapping and merging algorithms can significantly improve the unwrapped result in the presence of phase residues and noise. Beyond that, our modular framework allows for efficient design and test of new tile-based phase unwrapping algorithms. The software developed in this study is freely available.
Fan, Yunpeng; Fu, Yanhui; Fu, Qing; Cai, Jianfeng; Xin, Huaxia; Dai, Mei; Jin, Yu
2016-07-01
An orthogonal (71.9%) off-line preparative two-dimensional normal-phase liquid chromatography/reversed-phase liquid chromatography method coupled with effective sample pretreatment was developed for separation and purification of flavonoids from licorice. Most of the nonflavonoids were firstly removed using a self-made Click TE-Cys (60 μm) solid-phase extraction. In the first dimension, an industrial grade preparative chromatography was employed to purify the crude flavonoids. Click TE-Cys (10 μm) was selected as the stationary phase that provided an excellent separation with high reproducibility. Ethyl acetate/ethanol was selected as the mobile phase owing to their excellent solubility for flavonoids. Flavonoids co-eluted in the first dimension were selected for further purification using reversed-phase liquid chromatography. Multiple compounds could be isolated from one normal-phase fraction and some compounds with bad resolution in one-dimensional liquid chromatography could be prepared in this two-dimensional system owing to the orthogonal separation. Moreover, this two-dimensional liquid chromatography method was beneficial for the preparation of relatively trace flavonoid compounds, which were enriched in the first dimension and further purified in the second dimension. Totally, 24 flavonoid compounds with high purity were obtained. The results demonstrated that the off-line two-dimensional liquid chromatography method was effective for the preparative separation and purification of flavonoids from licorice. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Two-dimensional unwrapped phase inversion with damping and a Gaussian filter
Choi, Yun Seok
2014-01-01
Phase wrapping is one of main causes of the local minima problem in waveform inversion. However, the unwrapping process for 2D phase maps that includes singular points (residues) is complicated and does not guarantee unique solutions. We employ an exponential damping to eliminate the residues in the 2D phase maps, which makes the 2D phase unwrapping process easy and produce a unique solution. A recursive inversion process using the damped unwrapped phase provides an opportunity to invert for smooth background updates first, and higher resolution updates later as we reduce the damping. We also apply a Gaussian filter to the gradient to mitigate the edge artifacts resulting from the narrow shape of the sensitivity kernels at high damping. Numerical examples demonstrate that our unwrapped phase inversion with damping and a Gaussian filter produces good convergent results even for a 3Hz single frequency of Marmousi dataset and with a starting model far from the true model.
Phase transformation and diffusion
Kale, G B; Dey, G K
2008-01-01
Given that the basic purpose of all research in materials science and technology is to tailor the properties of materials to suit specific applications, phase transformations are the natural key to the fine-tuning of the structural, mechanical and corrosion properties. A basic understanding of the kinetics and mechanisms of phase transformation is therefore of vital importance. Apart from a few cases involving crystallographic martensitic transformations, all phase transformations are mediated by diffusion. Thus, proper control and understanding of the process of diffusion during nucleation, g
Zhang, Yan-ling; Chen, Jian-bo; Lei, Yu; Zhou, Qun; Sun, Su-qin; Noda, Isao
2010-06-01
Ginseng is one of the most widely used herbal medicines which have many kinds of pharmaceutical values. The discrimination of grades of ginseng includes the cultivation types and the growth years herein. To evaluate the different grades of ginseng, the fibrous roots and rhizome roots of ginseng were analyzed by Fourier-transform infrared and two-dimensional infrared correlation spectroscopy in this paper. The fibrous root and rhizome root of ginseng have different content of starch, calcium oxalate and other components. For the fibrous roots of ginseng, mountain cultivation ginseng (MCG), garden cultivation ginseng (GCG) and transplanted cultivation ginseng (TCG) have clear difference in the infrared spectra and second derivative spectra in the range of 1800-400 cm -1, and clearer difference was observed in the range of 1045-1160 and 1410-1730 cm -1 in 2D synchronous correlation spectra. Three kinds of ginseng can be clustered very well by using SIMCA analysis on the basis of PCA as well. For the rhizome roots, the content of calcium oxalate and starch change with growth years in the IR spectra, and some useful procedure can be obtained by the analysis of 2D IR synchronous spectra in the range of 1050-1415 cm -1. Also, ginsengs cultivated in different growth years were clustered perfectly by using SIMCA analysis. The results suggested that different grades of ginseng can be well recognized using the mid-infrared spectroscopy assisted by 2D IR correlation spectroscopy, which provide the macro-fingerprint characteristics of ginseng in different parts and supplied a rapid, effective approach for the evaluation of the quality of ginseng.
International Nuclear Information System (INIS)
Korshunov, S.E.; Uimin, G.V.
1986-01-01
A most popular model in the family of two-dimensional uniformly-frustrated XY models is the antiferromagnetic model on a triangular lattice (AF XY(t) model). Its ground state is both continuously and twofold discretely degenerated. Different phase transitions possible in such systems are investigated. Relevant topological excitations are analyzed and a new class of such (vortices with a fractional number of circulation quanta) is discovered. Their role in determining the properties of the system proves itself essential. The characteristics of phase transitions related to breaking of discrete and continuous symmetries change. The phase diagram of the ''generalized'' AF XY(t) model is constructed. The results obtained are rederived in the representation of the Coulomb gas with half-interger charges, equivalent to the AF XY(t) model with the Berezinskii-Villain interaction
Phase-matching-free parametric oscillators based on two dimensional semiconductors
Ciattoni, A.; Marini, A.; Rizza, C.; Conti, C.
2017-01-01
Optical parametric oscillators are widely-used pulsed and continuous-wave tunable sources for innumerable applications, as in quantum technologies, imaging and biophysics. A key drawback is material dispersion imposing the phase-matching condition that generally entails a complex setup design, thus hindering tunability and miniaturization. Here we show that the burden of phase-matching is surprisingly absent in parametric micro-resonators adopting monolayer transition-metal dichalcogenides as...
Miao, Zheng; He, Ya-Ling; Li, Xiang-Lin; Zou, Jin-Qiang
A two-dimensional two-phase mass transport model for liquid-feed direct methanol fuel cells (DMFCs) is presented in this paper. The fluid flow and mass transport across the membrane electrode assembly (MEA) is formulated based on the classical multiphase flow theory in the porous media. The modeling of mass transport in the catalyst layers (CLs) and membrane is given more attentions. The effect of the two-dimensional migration of protons in the electrolyte phase on the liquid flow behavior is considered. Water and methanol crossovers through the membrane are implicitly calculated in the governing equations of momentum and methanol concentration. A modified agglomerate model is developed to characterize the microstructure of the CLs. A self-written computer code is used to solve the inherently coupled differential governing equations. Then this model is applied to investigate the mechanisms of species transport and the distributions of the species concentrations, overpotential and the electrochemical reaction rates in CLs. The effects of radius and overlapping angle of agglomerates on cell performance are also explored in this work.
Czech Academy of Sciences Publication Activity Database
Archer, J.A.; Malijevský, Alexandr
2011-01-01
Roč. 109, 7-10 SI (2011), s. 1087-1099 ISSN 0026-8976 R&D Projects: GA AV ČR IAA400720710 Institutional research plan: CEZ:AV0Z40720504 Keywords : colloids * sedimentation * phase transitions Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.819, year: 2011
Zak phase induced multiband waveguide by two-dimensional photonic crystals.
Yang, Yuting; Xu, Tao; Xu, Yun Fei; Hang, Zhi Hong
2017-08-15
Interface states in photonic crystals provide efficient approaches to control the flow of light. Photonic Zak phase determines the bulk band properties of photonic crystals, and, by assembling two photonic crystals with different bulk band properties together, deterministic interface states can be realized. By translating each unit cell of a photonic crystal by half the lattice constant, another photonic crystal with identical common gaps but a different Zak phase at each photonic band can be created. By assembling these two photonic crystals together, multiband waveguide can thus be easily created and then experimentally characterized. Our experimental results have good agreement with numerical simulations, and the propagation properties of these measured interface states indicate that this new type of interface state will be a good candidate for future applications of optical communications.
Two-dimensional distributed-phase-reference protocol for quantum key distribution
DEFF Research Database (Denmark)
Bacco, Davide; Christensen, Jesper Bjerge; Usuga Castaneda, Mario A.
2016-01-01
Quantum key distribution (QKD) and quantum communication enable the secure exchange of information between remote parties. Currently, the distributed-phase-reference (DPR) protocols, which are based on weak coherent pulses, are among the most practical solutions for long-range QKD. During the las...... coherent pulses. The ability of extracting two bits of information per detection event, enables a higher secret key rate in specific realistic network scenarios. Moreover, despite the use of more dimensions, the proposed protocol remains simple, practical, and fully integrable.......Quantum key distribution (QKD) and quantum communication enable the secure exchange of information between remote parties. Currently, the distributed-phase-reference (DPR) protocols, which are based on weak coherent pulses, are among the most practical solutions for long-range QKD. During the last...
Bragança, Helena; Sakai, Shiro; Aguiar, M. C. O.; Civelli, Marcello
2018-02-01
We study the relationship between the pseudogap and Fermi-surface topology in the two-dimensional Hubbard model by means of the cellular dynamical mean-field theory. We find two possible mean-field metallic solutions on a broad range of interactions, doping, and frustration: a conventional renormalized metal and an unconventional pseudogap metal. At half filling, the conventional metal is more stable and displays an interaction-driven Mott metal-insulator transition. However, for large interactions and small doping, a region that is relevant for cuprates, the pseudogap phase becomes the ground state. By increasing doping, we show that a first-order transition from the pseudogap to the conventional metal is tied to a change of the Fermi surface from hole- to electronlike, unveiling a correlation-driven mechanism for a Lifshitz transition. This explains the puzzling link between the pseudogap phase and Fermi surface topology that has been pointed out in recent experiments.
Choi, Tae-Hoon; Huh, Jae-Won; Woo, Jae-Hyeon; Kim, Jin-Hun; Jo, Young-Seo; Yoon, Tae-Hoon
2017-05-15
We report an electrically-switchable two-dimensional liquid crystal (LC) phase grating device for window display applications. The device consists of the top and bottom substrates with crossed interdigitated electrodes and vertically-aligned LCs sandwiched between the two substrates. The device, switchable between the transparent and translucent states by applying an electric field, can provide high haze by the strong diffraction effect thanks to a large spatial phase difference with little dependence on the azimuth angle. We found that the device has outstanding features, such as a low operating voltage, high transparency, and wide viewing angle characteristics in the transparent state and high haze in the translucent state. Moreover, we achieved submillisecond switching between transparent and translucent states by employing the overdrive scheme and a vertical trigger pulse.
Gascooke, Jason R.; Lawrance, Warren D.
2017-11-01
Two dimensional laser induced fluorescence (2D-LIF) extends the usual laser induced fluorescence technique by adding a second dimension, the wavelength at which excited states emit, thereby significantly enhancing the information that can be extracted. It allows overlapping absorption features, whether they arise from within the same molecule or from different molecules in a mixture, to be associated with their appropriate "parent" state and/or molecule. While the first gas phase version of the technique was published a decade ago, the technique is in its infancy, having been exploited by only a few groups to date. However, its potential in gas phase spectroscopy and dynamics is significant. In this article we provide an overview of the technique and illustrate its potential with examples, with a focus on those utilising high resolution in the dispersed fluorescence dimension.
Probing the liquid and solid phases in closely spaced two-dimensional systems
International Nuclear Information System (INIS)
Zhang, Ding
2014-01-01
Gas, liquid and solid phases are the most common states of matter in our daily encountered 3-dimensional space. The school example is the H 2 O molecule with its phases vapor, water and ice. Interestingly, electrons - with their point-like nature and negative charges - can also organize themselves under certain conditions to bear properties of these three common phases. At relatively high temperature, where Boltzmann statistics prevails, the ensemble of electrons without interactions can be treated as a gas of free particles. Cooling down the system, this electron gas condenses into a Fermi liquid. Finally, as a result of the repulsive Coulomb forces, electrons try to avoid each other by maximizing their distances. When the Coulomb interaction becomes sufficiently strong, a regular lattice emerges - an electron solid. The story however does not end here. Nature has much more in store for us. Electronic systems in fact exhibit a large variety of phases induced by spatial confinement, an external magnetic field, Coulomb interactions, or interactions involving degrees of freedom other than charge such as spin and valley. Here in this thesis, we restrict ourselves to the study of electrons in a 2-dimenisonal (2D) plane. Already in such a 2D electron system (2DES), several distinct states of matter appear: integer and fractional quantum Hall liquids, the 2D Wigner solid, stripe and bubble phases etc. In 2DES it is sufficient to sweep the perpendicular magnetic field to pass from one of these phases into another. Experimentally, many of these phases can be revealed by simply measuring the resistance. For a quantum Hall state, the longitudinal resistance vanishes, while the Hall resistance exhibits a plateau. The quantum Hall plateau is a manifestation of localization induced by the inevitable sample disorder. Coulomb interaction can also play an important role to localize charges. Even in the disorder-free case, electrons - more precisely quasi-particles in the partially
DEFF Research Database (Denmark)
Vandekerckhove, J; Bauw, G; Vancompernolle, K
1990-01-01
downregulated markers typical of the transformed state. Using the information stored in the comprehensive human cellular protein database, we found this protein strongly expressed in several fetal tissues and one of them, epidermis, served as a source for preparative two-dimensional gel electrophoresis. Partial......A systematic comparison of the protein synthesis patterns of cultured normal and transformed human fibroblasts and epithelial cells, using two-dimensional gel protein analysis combined with computerized imaging and data acquisition, identified a 90-kD protein (SSP 5714) as one of the most striking...... and by coelectrophoresis with purified human gelsolin. These results suggest that an important regulatory protein of the microfilament system may play a role in defining the phenotype of transformed human fibroblast and epithelial cells in culture. Udgivelsesdato: 1990-Jul...
Xu, Lin; Wang, Hai-Xiao; Xu, Ya-Dong; Chen, Huan-Yang; Jiang, Jian-Hua
2016-08-08
A simple core-shell two-dimensional photonic crystal is studied where the triangular lattice symmetry and the C6 point group symmetry give rich physics in accidental touching points of photonic bands. We systematically evaluate different types of accidental nodal points at the Brillouin zone center for transverse-magnetic harmonic modes when the geometry and permittivity of the core-shell material are continuously tuned. The accidental nodal points can have different dispersions and topological properties (i.e., Berry phases). These accidental nodal points can be the critical states lying between a topological phase and a normal phase of the photonic crystal. They are thus very important for the study of topological photonic states. We show that, without breaking time-reversal symmetry, by tuning the geometry of the core-shell material, a phase transition into the photonic quantum spin Hall insulator can be achieved. Here the "spin" is defined as the orbital angular momentum of a photon. We study the topological phase transition as well as the properties of the edge and bulk states and their application potentials in optics.
Gwarda, Radosław Łukasz; Dzido, Tadeusz Henryk
2013-10-18
Among many advantages of planar techniques, two-dimensional (2D) separation seems to be the most important for analysis of complex samples. Here we present quick, simple and efficient two-dimensional high-performance thin-layer chromatography (2D HPTLC) of bovine albumin digest using commercial HPTLC RP-18W plates (silica based stationary phase with chemically bonded octadecyl ligands of coverage density 0.5μmol/m(2) from Merck, Darmstadt). We show, that at low or high concentration of water in the mobile phase comprised methanol and some additives the chromatographic systems with the plates mentioned demonstrate normal- or reversed-phase liquid chromatography properties, respectively, for separation of peptides obtained. These two systems show quite different separation selectivity and their combination into 2D HPTLC process provides excellent separation of peptides of the bovine albumin digest. Copyright © 2013 Elsevier B.V. All rights reserved.
International Nuclear Information System (INIS)
Chen Lijen; Lefebvre, Bertrand; Torbert, Roy B.; Daughton, William S.
2011-01-01
Based on two-dimensional fully kinetic simulations that resolve the electron diffusion layer in undriven collisionless magnetic reconnection with zero guide field, this paper reports the existence and evolution of an inversion layer of bipolar electric fields, its corresponding phase-space structure (an electron-hole layer), and the implication to collisionless dissipation. The inversion electric field layer is embedded in the layer of bipolar Hall electric field and extends throughout the entire length of the electron diffusion layer. The electron phase-space hole structure spontaneously arises during the explosive growth phase when there exist significant inflows into the reconnection layer, and electrons perform meandering orbits across the layer while being cyclotron-turned toward the outflow directions. The cyclotron turning of meandering electrons by the magnetic field normal to the reconnection layer is shown to be a primary factor limiting the current density in the region where the reconnection electric field is balanced by the gradient (along the current sheet normal) of the off-diagonal electron pressure-tensor.
Qu, Yuanju; Pan, Hui; Kwok, Chi Tat
2016-01-01
Two-dimensional (2D) transition metal dichalcogenides (TMDs) have been widely used from nanodevices to energy harvesting/storage because of their tunable physical and chemical properties. In this work, we systematically investigate the effects of hydrogenation on the structural, electronic, magnetic, and catalytic properties of 33 TMDs based on first-principles calculations. We find that the stable phases of TMD monolayers can transit from 1T to 2H phase or vice versa upon the hydrogenation. We show that the hydrogenation can switch their magnetic and electronic states accompanying with the phase transition. The hydrogenation can tune the magnetic states of TMDs among non-, ferro, para-, and antiferro-magnetism and their electronic states among semiconductor, metal, and half-metal. We further show that, out of 33 TMD monolayers, 2H-TiS2 has impressive catalytic ability comparable to Pt in hydrogen evolution reaction in a wide range of hydrogen coverages. Our findings would shed the light on the multi-functional applications of TMDs. PMID:27686869
Shinzawa, Hideyuki; Mizukado, Junji; Kazarian, Sergei G
2017-06-01
A novel technique called disrelation spectroscopic imaging describes the process of identifying an area where a coordinated or out-of-phase change in pattern of spectral absorbance occurs. Disrelation mapping can be viewed as a spatial filter based on the well-established two-dimensional (2D) correlation function to highlight specific areas where disrelated variation occurs between ν 1 and ν 2 . Disrelation intensity develops only if the spectral absorbance measured at ν 1 and ν 2 vary out of phase with each other within a specific spatial area. The disrelation mapping locates regions where absorbance varies in a dissimilar manner because of the contribution from species of different physical or chemical origins. Consequently, it becomes possible to probe onset of molecular interactions or presence of intermediate forms between components, which is not fully detected by the conventional visualizations based on a single wavenumber. Data analysis using disrelation mapping applied to Fourier transform infrared (FT-IR) spectroscopic images is presented in this study. Data sets of FT-IR spectroscopic images of blends of poly(methyl methacrylate) (PMMA) and polyethylene glycol (PEG) were subjected to the disrelation mapping. It was found that the disrelation intensity between 1730 and 1714 cm -1 becomes especially acute around the spatial boundary between PMMA and PEG domains within the studied blend sample. Thus the band at 1730 cm -1 most likely represents the C=O stretching mode of the C=O···H-O species due to the intermolecular hydrogen bonding between PMMA and PEG. The appearance of such disrelation is more noticeable in the PEG-rich region, for the PEG with low molecular weight. Consequently, it suggests that the blends of PMMA and PEG are partially miscible at the molecular level and these intermolecular interactions are affected by the quantity of the terminal -OH groups of the PEG.
Bu, Gui-jun; Yu, Jing; Di, Hui-hui; Luo, Shi-jia; Zhou, Da-zhai; Xiao, Qiang
2015-02-01
The composition and structure of humic acids formed during composting play an important influence on the quality and mature of compost. In order to explore the composition and evolution mechanism, municipal solid wastes were collected to compost and humic and fulvic acids were obtained from these composted municipal solid wastes. Furthermore, fourier transform infrared spectra and two-dimensional correlation analysis were applied to study the composition and transformation of humic and fulvic acids during composting. The results from fourier transform infrared spectra showed that, the composition of humic acids was complex, and several absorbance peaks were observed at 2917-2924, 2844-2852, 2549, 1662, 1622, 1566, 1454, 1398, 1351, 990-1063, 839 and 711 cm(-1). Compared to humic acids, the composition of fulvci acids was simple, and only three peaks were detected at 1725, 1637 and 990 cm(-1). The appearance of these peaks showed that both humic and fulvic acids comprised the benzene originated from lignin and the polysaccharide. In addition, humic acids comprised a large number of aliphatic and protein which were hardly detected in fulvic acids. Aliphatic, polysaccharide, protein and lignin all were degraded during composting, however, the order of degradation was different between humic and fulvci acids. The result from two-dimensional correlation analysis showed that, organic compounds in humic acids were degraded in the following sequence: aliphatic> protein> polysaccharide and lignin, while that in fulvic acids was as following: protein> polysaccharide and aliphatic. A large number of carboxyl, alcohols and ethers were formed during the degradation process, and the carboxyl was transformed into carbonates. It can be concluded that, fourier transform infrared spectra coupled with two-dimensional correlation analysis not only can analyze the function group composition of humic substances, but also can characterize effectively the degradation sequence of these
Osserman, Robert
2011-01-01
The basic component of several-variable calculus, two-dimensional calculus is vital to mastery of the broader field. This extensive treatment of the subject offers the advantage of a thorough integration of linear algebra and materials, which aids readers in the development of geometric intuition. An introductory chapter presents background information on vectors in the plane, plane curves, and functions of two variables. Subsequent chapters address differentiation, transformations, and integration. Each chapter concludes with problem sets, and answers to selected exercises appear at the end o
Energy Technology Data Exchange (ETDEWEB)
Minardi, A.; Bishop, P.J. (Univ. of Central Florida, Orlando (USA))
1988-11-01
Metal-laser interactions have become increasingly important due to advances in laser-machining processes, laser weaponry, and rocket propulsion using laser beams. An interesting physical phenomenon that is not well understood is the interaction of the metal plasma above a surface with a laser beam. Although most models neglect the natural convection, other papers, such as by Sparrow et al., have considered this effect and found it to be of importance at low energy fluxes. This study assumes that the laser beam has a spatial variation, and thus a two-dimensional model for the temperature distribution within the substrate is required. Further, it was assumed at first that the thermophysical properties are constant, but modifications were made to allow for different thermal conductivities of the liquid and solid phases. The model was developed to describe the physical processes until the vapor just forms, so that movement of the vapor away from the surface will not be considered. Natural convection will be neglected in the liquid pool, and radiation losses from the surface wil be neglected since these are very small in comparison to the energy absorbed from the high intensity laser beam.
Directory of Open Access Journals (Sweden)
Margarita Zakharova
2018-03-01
Full Text Available Single-shot grating-based phase-contrast imaging techniques offer additional contrast modalities based on the refraction and scattering of X-rays in a robust and versatile configuration. The utilization of a single optical element is possible in such methods, allowing the shortening of the acquisition time and increasing flux efficiency. One of the ways to upgrade single-shot imaging techniques is to utilize customized optical components, such as two-dimensional (2D X-ray gratings. In this contribution, we present the achievements in the development of 2D gratings with UV lithography and gold electroplating. Absorption gratings represented by periodic free-standing gold pillars with lateral structure sizes from 5 µm to 25 µm and heights from 5 µm to 28 µm have shown a high degree of periodicity and defect-free patterns. Grating performance was tested in a radiographic setup using a self-developed quality assessment algorithm based on the intensity distribution histograms. The algorithm allows the final user to estimate the suitability of a specific grating to be used in a particular setup.
Non-Linear Non Stationary Analysis of Two-Dimensional Time-Series Applied to GRACE Data, Phase II
National Aeronautics and Space Administration — The proposed innovative two-dimensional (2D) empirical mode decomposition (EMD) analysis was applied to NASA's Gravity Recovery and Climate Experiment (GRACE)...
Two-dimensional ferroelectrics
Energy Technology Data Exchange (ETDEWEB)
Blinov, L M; Fridkin, Vladimir M; Palto, Sergei P [A.V. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Moscow, Russian Federaion (Russian Federation); Bune, A V; Dowben, P A; Ducharme, Stephen [Department of Physics and Astronomy, Behlen Laboratory of Physics, Center for Materials Research and Analysis, University of Nebraska-Linkoln, Linkoln, NE (United States)
2000-03-31
The investigation of the finite-size effect in ferroelectric crystals and films has been limited by the experimental conditions. The smallest demonstrated ferroelectric crystals had a diameter of {approx}200 A and the thinnest ferroelectric films were {approx}200 A thick, macroscopic sizes on an atomic scale. Langmuir-Blodgett deposition of films one monolayer at a time has produced high quality ferroelectric films as thin as 10 A, made from polyvinylidene fluoride and its copolymers. These ultrathin films permitted the ultimate investigation of finite-size effects on the atomic thickness scale. Langmuir-Blodgett films also revealed the fundamental two-dimensional character of ferroelectricity in these materials by demonstrating that there is no so-called critical thickness; films as thin as two monolayers (1 nm) are ferroelectric, with a transition temperature near that of the bulk material. The films exhibit all the main properties of ferroelectricity with a first-order ferroelectric-paraelectric phase transition: polarization hysteresis (switching); the jump in spontaneous polarization at the phase transition temperature; thermal hysteresis in the polarization; the increase in the transition temperature with applied field; double hysteresis above the phase transition temperature; and the existence of the ferroelectric critical point. The films also exhibit a new phase transition associated with the two-dimensional layers. (reviews of topical problems)
Čermák, J
2008-01-01
This special-topic book, devoted to ""Solid Phase Transformations"" , covers a broad range of phenomena which are of importance in a number of technological processes. Most commercial alloys undergo thermal treatment after casting, with the aim of imparting desired compositions and/or optimal morphologies to the component phases. In spite of the fact that the topic has lain at the center of physical metallurgy for a long time, there are numerous aspects which are wide open to potential investigative breakthroughs. Materials with new structures also stimulate research in the field, as well as n
Su, Gehong; Zhou, Tao; Liu, Xifei; Zhang, Yulin
2017-10-18
In this study, temperature-dependent FTIR spectroscopy in combination with the perturbation-correlation moving-window (PCMW2D) technique and generalized two-dimensional (2D) correlation analysis was applied to investigate the phase transition mechanism of poly(N-vinylcaprolactam) (PVCL) hydrogel upon heating. In the conventional 1D FTIR spectra, the gradual dehydration of C-H groups, as well as the gradual dissociation of hydrogen bonds between C[double bond, length as m-dash]O groups and water molecules, was observed during phase transition. Moreover, we found that the rate at which water molecules were expelled out of the gel network during phase transition was changed to a sigmoid mode, rather than increasing linearly with increasing temperature. PCMW2D FTIR spectra revealed that the phase transition of PVCL hydrogel can be divided into two steps (named as I and II) upon heating, and we further determined the temperature regions of steps I and II to be 29.0-35.7 °C and 35.7-47.5 °C, respectively. Step I is the formation of hydrophobic domains in the gel, and step II is the chain collapse of the gel. Finally, with the help of generalized 2D correlation analysis, it was confirmed that the transformation of hydrogen bonds was the driving force of the hydrophobic domain formation process, while the hydrophobic interaction of C-H groups was the driving force for the chain collapse process. Combined with the obtained sequential orders of step I and step II, an integrated two-step phase transition mechanism of PVCL hydrogel upon heating was proposed.
Brudin, S.S.; Shellie, R.A.; Haddad, P.R.; Schoenmakers, P.J.
2010-01-01
In the work presented here a novel approach to comprehensive two-dimensional liquid chromatography is evaluated. Ion chromatography is chosen for the first-dimension separation and reversed-phase liquid chromatography is chosen for the second-dimension separation mode. The coupling of these modes is
Kagesawa, Koichi; Nishimura, Yuki; Yoshida, Hiroki; Breedlove, Brian K; Yamashita, Masahiro; Miyasaka, Hitoshi
2017-03-07
Two-dimensional layered compounds with different counteranions, [{Mn(salen)} 4 C6](BF 4 ) 2 ·2(CH 3 OH) (1) and [{Mn(salen)} 4 C6](PF 6 ) 2 ·2(CH 3 OH) (2) (salen 2- = N,N'-bis(salicylideneiminato), C6 2- = C 6 H 12 (COO) 2 2- ), were synthesized by assembling [Mn(salen)(H 2 O)]X (X - = BF 4 - and PF 6 - ) and C 6 H 12 (CO 2 - ) 2 (C6 2- ) in a methanol/2-propanol medium. The compounds have similar structures, which are composed of Mn(salen) out-of-plane dimers bridged by μ 4 -type C6 2- ions, forming a brick-wall-type network of [-{Mn 2 }-OCO-] chains alternately connected via C 6 H 12 linkers of C6 2- moieties. The counteranions for 1 and 2, i.e., BF 4 - and PF 6 - , respectively, are located between layers. Since the size of BF 4 - is smaller than that of PF 6 - , intra-layer inter-chain and inter-plane nearest-neighbor MnMn distances are shorter in 1 than in 2. The zigzag chain moiety of [-{Mn 2 }-OCO-] leads to a canted S = 2 spin arrangement with ferromagnetic coupling in the Mn III out-of-plane dimer moiety and antiferromagnetic coupling through -OCO- bridges. Due to strong uniaxial anisotropy of the Mn III ion, the [-{Mn 2 }-OCO-] chains could behave as a single-chain magnet (SCM), which exhibits slow relaxation of magnetization at low temperatures. Nevertheless, these compounds fall into an antiferromagnetic ground state at higher temperatures of T N = 4.6 and 3.8 K for 1 and 2, respectively, than active temperatures for SCM behavior. The spin flip field at 1.8 K is 2.7 and 1.8 kOe for 1 and 2, respectively, which is attributed to the inter-chain interactions tuned by the size of the counteranions. The relaxation times of magnetization become longer at the boundary between the antiferromagnetic phase and the paramagnetic phase.
Lin, Zhaoyang; Yin, Anxiang; Mao, Jun; Xia, Yi; Kempf, Nicholas; He, Qiyuan; Wang, Yiliu; Chen, Chih-Yen; Zhang, Yanliang; Ozolins, Vidvuds; Ren, Zhifeng; Huang, Yu; Duan, Xiangfeng
2016-10-01
Epitaxial heterostructures with precisely controlled composition and electronic modulation are of central importance for electronics, optoelectronics, thermoelectrics, and catalysis. In general, epitaxial material growth requires identical or nearly identical crystal structures with small misfit in lattice symmetry and parameters and is typically achieved by vapor-phase depositions in vacuum. We report a scalable solution-phase growth of symmetry-mismatched PbSe/Bi 2 Se 3 epitaxial heterostructures by using two-dimensional (2D) Bi 2 Se 3 nanoplates as soft templates. The dangling bond-free surface of 2D Bi 2 Se 3 nanoplates guides the growth of PbSe crystal without requiring a one-to-one match in the atomic structure, which exerts minimal restriction on the epitaxial layer. With a layered structure and weak van der Waals interlayer interaction, the interface layer in the 2D Bi 2 Se 3 nanoplates can deform to accommodate incoming layer, thus functioning as a soft template for symmetry-mismatched epitaxial growth of cubic PbSe crystal on rhombohedral Bi 2 Se 3 nanoplates. We show that a solution chemistry approach can be readily used for the synthesis of gram-scale PbSe/Bi 2 Se 3 epitaxial heterostructures, in which the square PbSe (001) layer forms on the trigonal/hexagonal (0001) plane of Bi 2 Se 3 nanoplates. We further show that the resulted PbSe/Bi 2 Se 3 heterostructures can be readily processed into bulk pellet with considerably suppressed thermal conductivity (0.30 W/m·K at room temperature) while retaining respectable electrical conductivity, together delivering a thermoelectric figure of merit ZT three times higher than that of the pristine Bi 2 Se 3 nanoplates at 575 K. Our study demonstrates a unique epitaxy mode enabled by the 2D nanocrystal soft template via an affordable and scalable solution chemistry approach. It opens up new opportunities for the creation of diverse epitaxial heterostructures with highly disparate structures and functions.
Energy Technology Data Exchange (ETDEWEB)
Davis, A.B.
1998-12-01
The authors compare several ways of uncovering multifractal properties of data in 1D and 2D using wavelet transforms. The WTMM or (Continuous) Wavelet Transform Maximum Modulus method has been extensively documented and widely applied by Dr. Alain Arneodo`s (Bordeaux) group, to the point where their successes have overshadowed simpler techniques that use the Discrete WT. What the latter lack in robustness is gained in efficiency, thus enabling virtually real-time multifractal analysis of data as it is collected. Another advantage of DWT-based approaches is that tensor products of dyadic and triadic branching schemes enable a straightforward attack on strong anisotropy in natural and artificial 2D random fields.
International Nuclear Information System (INIS)
Perez Guerrero, Jesus Salvador
1995-01-01
Laminar developing flow in channels of arbitrary geometry was studied by solving the Navier-Stokes equations in the stream function-only formulation through the Generalized Integral Transform Technique (GITT). The stream function is expanded in an infinite system based on eigenfunctions obtained by considering solely the diffusive terms of the original formulation. The Navier-Stokes equations are transformed into an infinite system of ordinary differential equations, by using the transformation and inversion formulae. For computational purposes, the infinite series is truncated, according to an automatic error control procedure. The ordinary differential is solved through well-established scientific subroutines from widely available mathematical libraries. The classical problem of developing flow between parallel-plates is analysed first, as for both uniform and irrotational inlet conditions. The effect of truncating the duct length in the accuracy of the obtained solution is studied. A convergence analysis of the results obtained by the GITT is performed and compared with results obtained by finite difference and finite element methods, for different values of Reynolds number. The problem of flow over a backward-facing step then follows. Comparisons with experimental results in the literature indicate an excellent agreement. The numerical co-validation was established for a test case, and perfect agreement is reached against results considered as benchmarks in the recent literature. The results were shown to be physically more reasonable than others obtained by purely numerical methods, in particular for situations where three-dimensional effects are identified. Finally, a test problem for an irregular by shoped duct was studied and compared against results found in the literature, with good agreement and excellent convergence rates for the stream function field along the whole channel, for different values of Reynolds number. (author)
Yang, Feng; Shen, Yufeng; Camp, David G.; Smith, Richard D.
2012-01-01
Orthogonal high-resolution separations are critical for attaining improved analytical dynamic range and protein coverage in proteomic measurements. High pH reversed-phase liquid chromatography (RPLC) followed by fraction concatenation affords better peptide analysis than conventional strong-cation exchange (SCX) chromatography applied for the two-dimensional proteomic analysis. For example, concatenated high pH reversed-phase liquid chromatography increased identification for peptides (1.8-fo...
Choong, Yew-Keong; Sun, Su-Qin; Zhou, Qun; Lan, Jin; Lee, Han-Lim; Chen, Xiang-Dong
2014-07-01
Ganoderma commercial products are typically based on two sources, raw material (powder form and/or spores) and extract (water and/or solvent). This study compared three types of Ganoderma commercial products using 1 Dimensional Fourier Transform infrared and second derivative spectroscopy. The analyzed spectra of Ganoderma raw material products were compared with spectra of cultivated Ganoderma raw material powder from different mushroom farms in Malaysia. The Ganoderma extract product was also compared with three types of cultivated Ganoderma extracts. Other medicinal Ganoderma contents in commercial extract product that included glucan and triterpenoid were analyzed by using FTIR and 2DIR. The results showed that water extract of cultivated Ganoderma possessed comparable spectra with that of Ganoderma product water extract. By comparing the content of Ganoderma commercial products using FTIR and 2DIR, product content profiles could be detected. In addition, the geographical origin of the Ganoderma products could be verified by comparing their spectra with Ganoderma products from known areas. This study demonstrated the possibility of developing verification tool to validate the purity of commercial medicinal herbal and mushroom products.
Energy Technology Data Exchange (ETDEWEB)
Sawyer, Karma Rae [Univ. of California, Berkeley, CA (United States)
2008-12-01
Understanding chemical reactions requires the knowledge of the elementary steps of breaking and making bonds, and often a variety of experimental techniques are needed to achieve this goal. The initial steps occur on the femto- through picosecond time-scales, requiring the use of ultrafast spectroscopic methods, while the rate-limiting steps often occur more slowly, requiring alternative techniques. Ultrafast one and two-dimensional infrared and step-scan FTIR spectroscopies are used to investigate the photochemical reactions of four organometallic complexes. The analysis leads to a detailed understanding of mechanisms that are general in nature and may be applicable to a variety of reactions.
High pressure phase transformations revisited
Levitas, Valery I.
2018-04-01
High pressure phase transformations play an important role in the search for new materials and material synthesis, as well as in geophysics. However, they are poorly characterized, and phase transformation pressure and pressure hysteresis vary drastically in experiments of different researchers, with different pressure transmitting media, and with different material suppliers. Here we review the current state, challenges in studying phase transformations under high pressure, and the possible ways in overcoming the challenges. This field is critically compared with fields of phase transformations under normal pressure in steels and shape memory alloys, as well as plastic deformation of materials. The main reason for the above mentioned discrepancy is the lack of understanding that there is a fundamental difference between pressure-induced transformations under hydrostatic conditions, stress-induced transformations under nonhydrostatic conditions below yield, and strain-induced transformations during plastic flow. Each of these types of transformations has different mechanisms and requires a completely different thermodynamic and kinetic description and experimental characterization. In comparison with other fields the following challenges are indicated for high pressure phase transformation: (a) initial and evolving microstructure is not included in characterization of transformations; (b) continuum theory is poorly developed; (c) heterogeneous stress and strain fields in experiments are not determined, which leads to confusing material transformational properties with a system behavior. Some ways to advance the field of high pressure phase transformations are suggested. The key points are: (a) to take into account plastic deformations and microstructure evolution during transformations; (b) to formulate phase transformation criteria and kinetic equations in terms of stress and plastic strain tensors (instead of pressure alone); (c) to develop multiscale continuum
International Nuclear Information System (INIS)
Anon.
1991-01-01
This chapter addresses the extension of previous work in one-dimensional (linear) error theory to two-dimensional error analysis. The topics of the chapter include the definition of two-dimensional error, the probability ellipse, the probability circle, elliptical (circular) error evaluation, the application to position accuracy, and the use of control systems (points) in measurements
Xun, Xiaodong; Erwin, James K.; Bletscher, Warren; Choi, Jinhan; Kallenbach, Senta; Mansuripur, Masud
2001-12-01
We present the results of crystallization studies in thin-film samples of amorphous and crystalline GexSbyTez. The experiments, conducted at moderately elevated temperatures, are based on measurements of the first-order diffraction efficiency from a two-dimensional periodic array of recorded marks. When the samples are slowly heated above room temperature, changes in the efficiencies of various diffracted orders give information about the on-going crystallization process within the sample. Two different compositions of the GeSbTe alloy are used in these experiments. Measurements on Ge2Sb2,3Te5 films show crystallization dominated by nucleation. For the Sb-rich eutectic composition Ge-(SbTe), crystallization is found to be dominated by growth from crystalline boundaries. We also show that crystalline marks written by relatively high-power laser pulses are different in their optical properties from the regions crystallized by slow heating of the sample to moderate temperatures.
Yan, Zhiwei; Li, Qian; Zhang, Pudun
2017-11-01
It is a trend to substitute bioplastics for petroleum-based plastics in food packaging. Glycerol-plasticized soy protein isolate (SPI) is promising as a replacement for traditional petroleum-based plastics. Hydrogen bonding (H-bonding) plays a key role in plasticization of SPI film. However, few publications are concerned with the interactions of SPI and glycerol at the molecular level. In this paper, attenuated total reflection Fourier transform infrared (ATR FT-IR) spectroscopy was applied to investigate the effect of H-bonding on the secondary structures of glycerol-plasticized SPI films and thus on the plasticization. An "S" profile of the H-bonding between SPI and glycerol with an abrupt jump in the glycerol range of 10-30% was achieved. For more in-depth investigation of the H-bonding, two-dimensional correlation spectroscopy (2D-COS) and perturbation-correlation moving-window two-dimensional (PCMW2D) analyses were applied to the amide I and II bands of SPI films spectra series. The conformation change sequences under the effect of H-bonding were revealed. When glycerol was involved, it entered into the β-sheet and the H-bonds of the SPI peptide backbone (C = O···H-N-) were replaced by the new H-bonds between SPI and glycerol (C = O···H-O-). The transformations of parallel β-sheet to β-turn in the range of 0-20% and anti-parallel β-sheet to β-turn in the range of 20-35% were obtained. In the 35-60% concentration range, the β-sheet was first changed to a transition state conformation, then together with the β-turn, to the random coil. The 2D-COS results clearly suggest that the conformations of SPI gradually change from the ordered to the less ordered and disordered, which significantly improve the plasticity of SPI film.
Gauchotte-Lindsay, Caroline; McGregor, Laura; Richards, Phil; Kerr, Stephanie; Glenn, Aliyssa; Thomas, Russell; Kalin, Robert
2013-04-01
Comprehensive two-dimensional gas chromatography (GCxGC) is a recently developed analytical technique in which two capillary columns with different stationary phases are placed in series enabling planar resolution of the analytes. The resolution power of GCxGC is one order of magnitude higher than that of one dimension gas chromatography. Because of its high resolution capacity, the use of GCxGC for complex environmental samples such as crude oils, petroleum derivatives and polychlorinated biphenyls mixtures has rapidly grown in recent years. We developed a one-step method for the forensic analysis of coal tar dense non-aqueous phase liquids (DNAPLs) from former manufactured gas plant (FMGP) sites. Coal tar is the by-product of the gasification of coal for heating and lighting and it is composed of thousands of organic and inorganic compounds. Before the boom of natural gases and oils, most towns and cities had one or several manufactured gas plants that have, in many cases, left a devastating environmental print due to coal tar contamination. The fate of coal tar DNAPLs, which can persist in the environment for more than a hundred years, is therefore of crucial interest. The presented analytical method consists of a unique clean-up/ extraction stage by pressurized liquid extraction and a single analysis of its organic chemical composition using GCxGC coupled with time of flight mass spectrometry (TOFMS). The chemical fingerprinting is further improved by derivatisation by N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA) of the tar compounds containing -OH functions such as alcohols and carboxylic acids. We present here how, using the logical order of elution in GCxGC-TOFMS system, 1) the identification of never before observed -OH containing compounds is possible and 2) the isomeric selectivity of an oxidation reaction on a DNAPL sample can be revealed. Using samples collected at various FMGP sites, we demonstrate how this GCxGC method enables the simultaneous
Two-dimensional critical phenomena
International Nuclear Information System (INIS)
Saleur, H.
1987-09-01
Two dimensional critical systems are studied using transformation to free fields and conformal invariance methods. The relations between the two approaches are also studied. The analytical results obtained generally depend on universality hypotheses or on renormalization group trajectories which are not established rigorously, so numerical verifications, mainly using the transfer matrix approach, are presented. The exact determination of critical exponents; the partition functions of critical models on toruses; and results as the critical point is approached are discussed [fr
Guo, Yizhen; Lv, Beiran; Wang, Jingjuan; Liu, Yang; Sun, Suqin; Xiao, Yao; Lu, Lina; Xiang, Li; Yang, Yanfang; Qu, Lei; Meng, Qinghong
2016-01-15
As complicated mixture systems, active components of Chuanxiong Rhizoma are very difficult to identify and discriminate. In this paper, the macroscopic IR fingerprint method including Fourier transform infrared spectroscopy (FT-IR), the second derivative infrared spectroscopy (SD-IR) and two-dimensional correlation infrared spectroscopy (2DCOS-IR), was applied to study and identify Chuanxiong raw materials and its different segmented production of HPD-100 macroporous resin. Chuanxiong Rhizoma is rich in sucrose. In the FT-IR spectra, water eluate is more similar to sucrose than the powder and the decoction. Their second derivative spectra amplified the differences and revealed the potentially characteristic IR absorption bands and combined with the correlation coefficient, concluding that 50% ethanol eluate had more ligustilide than other eluates. Finally, it can be found from 2DCOS-IR spectra that proteins were extracted by ethanol from Chuanxiong decoction by HPD-100 macroporous resin. It was demonstrated that the above three-step infrared spectroscopy could be applicable for quick, non-destructive and effective analysis and identification of very complicated and similar mixture systems of traditional Chinese medicines. Copyright © 2015 Elsevier B.V. All rights reserved.
Qu, Lei; Chen, Jian-bo; Zhang, Gui-Jun; Sun, Su-qin; Zheng, Jing
2017-03-01
As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p = 0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR.
Yan, Rui; Chen, Jian-bo; Sun, Su-qin; Guo, Bao-lin
2016-11-01
Lonicerae japonicae Flos (LJF) and Lonicerae Flos (LF) are widely-used herbs derived from several plants of the genus Lonicera with similar appearances. LF are usually misused or counterfeited as LJF for economically motivated adulteration. However, the saponins in LF may cause serious side-effects. In this research, the infrared spectroscopic tri-step identification approach is used to develop a simple and rapid method to discriminate LJF and LF to ensure the safety and efficacy of these herbal drugs. In the primary identification by Fourier transform infrared spectra, LJF and LF show different peaks near 1534, 1404, and 781 cm-1. In the secondary identification by the second derivative infrared spectra, LJF and LF show more different peaks near 1078, 1050, 988, 923, 855, 815, and 781 cm-1. In the tertiary identification by the two-dimensional correlation infrared spectra, the differences between LJF and LF are shown more remarkably and convincingly. The results show the potential of the infrared spectroscopic tri-step identification approach in the rapid identification of LJF and LF when the samples are too few to build a statistical recognition rule. This should be very helpful to ensure the quality, safety, and efficacy of LJF and LF for clinical applications.
Muller, Hendrik; Adam, Frederick M; Panda, Saroj K; Al-Jawad, Hanadi H; Al-Hajji, Adnan A
2012-05-01
Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) has been applied for the quantitative speciation of sulfur containing compounds in gas oil (GO). For this purpose, ionization and mass spectrometric parameters have been studied and optimized with a set of standard compounds and GO samples. Comprehensive two-dimensional gas chromatography (GCxGC) was used as the reference method. To allow a quantitative comparison between FT-ICR MS and GCxGC results for GO samples, FT-ICR MS parameters were optimized and data obtained by both techniques were standardized. Response factors were established for two ionization modes: atmospheric pressure photo ionization (APPI) and electrospray after selective derivatization of sulfur compounds (MeESI). To test the validity of the developed MS methods, a third GO was analyzed and response factors were applied. Comparison with GCxGC results showed good agreement for sulfur families (deviation within 5% and 15% for MeESI and APPI data, respectively). Abundances of individual isomer groups match within 40% in most cases. These results principally demonstrate the suitability of FT-ICR MS for a quantitative analysis of sulfur compounds (by DBE and carbon number distribution pattern) in petroleum middle distillates. This approach has the potential to be extended to higher- and non-boiling petroleum fractions where quantitative speciation is presently not available.
Zumbühl, Stefan; Scherrer, Nadim C; Eggenberger, Urs
2014-01-01
The interpretation of standard Fourier transform infrared spectra (FT-IR) on oil-based paint samples often suffers from interfering bands of the different compounds, namely, binder, oxidative aging products, carboxylates formed during aging, and several pigments and fillers. The distinction of the aging products such as ketone and carboxylic acid functional groups pose the next problem, as these interfere with the triglyceride esters of the oil. A sample preparation and derivatization technique using gaseous sulfur tetrafluoride (SF4), was thus developed with the aim to discriminate overlapping signals and achieve a signal enhancement on superposed compounds. Of particular interest in this context is the signal elimination of the broad carboxylate bands of the typical reaction products developing during the aging processes in oil-based paints, as well as signal interference originating from several typical pigments in this spectral range. Furthermore, it is possible to distinguish the different carbonyl-containing functional groups upon selective alteration. The derivatization treatment can be applied to both microsamples and polished cross sections. It increases the selectivity of the infrared spectroscopy technique in a fundamental manner and permits the identification and two-dimensional (2D) localization of binder components in aged paint samples at the micrometer scale. The combination of SF4 derivatization with high-resolution 2D FT-IR focal plane array (FPA) imaging delivers considerable advances to the study of micro-morphological processes involving organic compounds.
International Nuclear Information System (INIS)
Mudry, Christopher; Wen Xiaogang
1999-01-01
Effective theories for random critical points are usually non-unitary, and thus may contain relevant operators with negative scaling dimensions. To study the consequences of the existence of negative-dimensional operators, we consider the random-bond XY model. It has been argued that the XY model on a square lattice, when weakly perturbed by random phases, has a quasi-long-range ordered phase (the random spin wave phase) at sufficiently low temperatures. We show that infinitely many relevant perturbations to the proposed critical action for the random spin wave phase were omitted in all previous treatments. The physical origin of these perturbations is intimately related to the existence of broadly distributed correlation functions. We find that those relevant perturbations do enter the Renormalization Group equations, and affect critical behavior. This raises the possibility that the random XY model has no quasi-long-range ordered phase and no Kosterlitz-Thouless (KT) phase transition
Seeley, John V; Bates, Carly T; McCurry, James D; Seeley, Stacy K
2012-02-24
The GC×GC solvation parameter model has been used to identify effective stationary phases for the separation of fatty acid methyl esters (FAMEs) from petroleum hydrocarbons. This simple mathematical model was used to screen the 1225 different combinations of 50 stationary phases. The most promising pairs combined a poly(methyltrifluoropropylsiloxane) stationary phase with a poly(dimethyldiphenylsiloxane) stationary phase. The theoretical results were experimentally tested by equipping a GC×GC instrument with a DB-210 primary stationary phase and an HP-50+ secondary stationary phase. This instrument was used to analyze trace levels of FAMEs in kerosene. The FAMEs were fully separated from the petroleum hydrocarbons on the secondary dimension of the 2-D chromatogram. The resulting GC×GC method was shown to be capable of accurately quantifying FAME levels as low as 2 ppm (w/w). These results demonstrate the utility of the solvation parameter model for identifying optimal stationary phases for high resolution GC×GC separations. Furthermore, this work presents an effective method for determining the level of biodiesel contamination in aviation fuel and other petroleum-based fuels. Copyright © 2011 Elsevier B.V. All rights reserved.
DEFF Research Database (Denmark)
Nielsen, Morten; Miao, Ling; Ipsen, John Hjorth
1996-01-01
In this work we concentrate on phase equilibria in two-dimensional condensed systems of particles where both translational and internal degrees of freedom are present and coupled through microscopic interactions, with a focus on the manner of the macroscopic coupling between the two types...... spin-spin interactions that may have spatial dependence. The fluctuating number of nearest neighbors and the possible spatial dependence of the spin-spin interactions couple microscopically the spin degrees of freedom to the translational degrees of freedom. The first model (I) is a random......-disorder singularity can be of first order throughout the phase diagram. It is found that this first-order singularity can be either coupled to or decoupled from the lattice-melting singularity, depending on the strength of the microscopic coupling. The calculated phase diagram and the associated thermodynamic...
On a phase structure of a two-dimensional (Φ-vector2)2 field theory
International Nuclear Information System (INIS)
Efimov, G.V.
1989-01-01
Two models of scalar fields with the interaction Lagrangians gΦ 4 and g(Σ Φ 1 2 ) 2 are considered in R 2 . There are phase transitions in these models for a certain g=g c . It is shown that the spontaneous symmetry breaking takes place for g>g c . The descritpion of two phases for g c and g>g c is given. The effective coupling constants in perturbation series are less than unity for both the phases so that these models describe the systems with weak coupling. In the second model the Goldstone particles have nonzero masses in the phase g>g c . 7 refs.; 5 figs
International Nuclear Information System (INIS)
Park, Chan Wook; Lee, Sung Su
2008-01-01
Two-phase compressible flow fields of air-water are investigated numerically in the fixed Eulerian grid framework. The phase interface is captured via volume fractions of ech phase. A way to model two phase compressible flows as a single phase one is found based on an equivalent equation of states of Tait's type for a multiphase cell. The equivalent single phase field is discretized using the Roe's approximate Riemann solver. Two approaches are tried to suppress the pressure oscillation phenomena at the phase interface, a passive advection of volume fraction and a direct pressure relaxation with the compressible form of volume fraction equation. The direct pressure equalizing method suppresses pressure oscillation successfully and generates sharp discontinuities, transmitting and reflecting acoustic waves naturally at the phase interface. In discretizing the compressible form of volume fraction equation, phase interfaces are geometrically reconstructed to minimize the numerical diffusion of volume fraction and relevant variables. The motion of a projectile in a water-filled tube which is fired by the release of highly pressurized air is simulated presuming the flow field as a two dimensional one, and several design factors affecting the projectile movement are investigated
Qu, Lei; Chen, Jian-Bo; Zhang, Gui-Jun; Sun, Su-Qin; Zheng, Jing
2017-03-05
As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p=0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR. Copyright © 2016 Elsevier B.V. All rights reserved.
Lu, Guang-hua; Zhou, Qun; Sun, Su-qin; Leung, Kelvin Sze-yin; Zhang, Hao; Zhao, Zhong-zhen
2008-07-01
The herbal materials of Asian ginseng (the root of Panax ginseng), American ginseng (the root of Panax quinquefolius) and Notoginseng (the root of Panax notoginseng) were differentiated by conventional Fourier transform infrared spectroscopy (1D-FTIR) and two-dimensional (2D) correlation FTIR applying a thermal perturbation. Altogether 30 samples were collected and analyzed. Their entire 1D-FTIR spectra in the range of 4000-400 cm -1 and 2D-FTIR spectra in the region of 850-1530 cm -1 were generally similar based on the peaks position and intensities. This indicated the chemical constituents in these species of herbs were not distinctively different. However, variation in peak intensity were observed at about 1640 cm -1, 1416 cm -1, 1372 cm -1 and 1048 cm -1 in the 1D-FTIR spectra among these species for their ease differentiation. Clustering analysis of 1D-FTIR showed that these species located in different clusters. Much difference in their second derivative FTIR pattern among the three species also provided information for easy differentiation. These species of herbs were further identified based on the positions and intensities of relatively strong auto-peaks, positive or negative cross-peaks in their 2D-FTIR spectra. The findings provide a rapid and new operational procedure for the differentiation of these notable herbs. The visual and colorful 2D-FTIR spectra can provide dynamic structural information of chemical components in analyte and demonstrated as a powerful and useful approach for herbs identification.
Erpelding, Marion; Sinha, Santanu; Tallakstad, Ken Tore; Hansen, Alex; Flekkøy, Eirik Grude; Måløy, Knut Jørgen
2013-11-01
It is well known that the transient behavior during drainage or imbibition in multiphase flow in porous media strongly depends on the history and initial condition of the system. However, when the steady-state regime is reached and both drainage and imbibition take place at the pore level, the influence of the evolution history and initial preparation is an open question. Here, we present an extensive experimental and numerical work investigating the history dependence of simultaneous steady-state two-phase flow through porous media. Our experimental system consists of a Hele-Shaw cell filled with glass beads which we model numerically by a network of disordered pores transporting two immiscible fluids. From measurements of global pressure evolution, histograms of saturation, and cluster-size distributions, we find that when both phases are flowing through the porous medium, the steady state does not depend on the initial preparation of the system or on the way it has been reached.
Integrable two dimensional supersystems
International Nuclear Information System (INIS)
Tripathy, K.C.; Tripathy, L.K.
1988-08-01
The integrability of two dimensional time-dependent classical systems is examined in N=2 superspace using Dirac's second class constraints. The invariants involving quadratic powers in velocities for super harmonic oscillator and super Kepler potentials have been derived. (author). 5 refs
Phase diagram of a two-dimensional liquid in GaAs/AlxGa1-xAs biased double quantum wells
DEFF Research Database (Denmark)
Timofeev, V. B.; Larionov, A. V.; Alessi, M. G.
2000-01-01
densities, P, and temperatures, T. For increasing P or decreasing T, a sharp transition from two gases of photoexcited electrons and holes, spatially separated and confined in the two wells, to two two-dimensional (2D) liquids has been observed. The gas-to-2D-liquid transition is evidenced by a strong...... screening of applied biases and by major changes in the optical spectra. The phase diagram in the (P,T) plane of the e-h system has been determined. Time-resolved FL, cw FL, and PLE in the presence of a magnetic field normal to the quantum wells support the presence of e- and h-liquid phases in the two...... wells with a critical density equal to 8.8 x 10(10) cm(-2) and a binding energy of 2.5 meV....
Directory of Open Access Journals (Sweden)
Lulu Deng
2011-07-01
Full Text Available The phase and texture of a newly developed solution-processed copper phthalocyanine (CuPc thin film have been investigated by two-dimensional grazing incidence X-ray diffraction. The results show that it has β phase crystalline structure, with crystallinity greater than 80%. The average size of the crystallites is found to be about 24 nm. There are two different arrangements of crystallites, with one dominating the diffraction pattern. Both of them have preferred orientation along the thin film normal. Based on the similarities to the vacuum deposited CuPc thin films, the new solution processing method is verified to offer a good alternative to vacuum process, for the fabrication of low cost small molecule based organic photovoltaics.
Zhang, Yuantao; Dong, Xin; Li, Guoxing; Li, Wancheng; Zhang, Baolin; Du, Guotong
2013-03-01
We report the growth of atomically smooth N-polar GaN on c-plane sapphire by metalorganic vapor phase epitaxy. A two-step growth technique was adopted; low-temperature growth of GaN buffer before high-temperature GaN growth. The complete two-dimensional N-polar GaN growth process was recorded by in situ reflectance. The phase composition of the low-temperature GaN was examined by X-ray diffraction pole figure measurements. The thickness of the low-temperature GaN buffer dramatically affected the crystalline and electronic properties of the N-polar GaN. A very small full width at half maximum for the (0 0 0 2) X-ray rocking curve, 51 arcs, was obtained for 700-nm-thick N-polarity GaN by optimizing the buffer thickness.
Brennan; Biddison; Frauendorf; Schwarcz; Keen; Ecker; Davis; Tinder; Swayze
1998-01-01
An automated, 96-well parallel array synthesizer for solid-phase organic synthesis has been designed and constructed. The instrument employs a unique reagent array delivery format, in which each reagent utilized has a dedicated plumbing system. An inert atmosphere is maintained during all phases of a synthesis, and temperature can be controlled via a thermal transfer plate which holds the injection molded reaction block. The reaction plate assembly slides in the X-axis direction, while eight nozzle blocks holding the reagent lines slide in the Y-axis direction, allowing for the extremely rapid delivery of any of 64 reagents to 96 wells. In addition, there are six banks of fixed nozzle blocks, which deliver the same reagent or solvent to eight wells at once, for a total of 72 possible reagents. The instrument is controlled by software which allows the straightforward programming of the synthesis of a larger number of compounds. This is accomplished by supplying a general synthetic procedure in the form of a command file, which calls upon certain reagents to be added to specific wells via lookup in a sequence file. The bottle position, flow rate, and concentration of each reagent is stored in a separate reagent table file. To demonstrate the utility of the parallel array synthesizer, a small combinatorial library of hydroxamic acids was prepared in high throughput mode for biological screening. Approximately 1300 compounds were prepared on a 10 μmole scale (3-5 mg) in a few weeks. The resulting crude compounds were generally >80% pure, and were utilized directly for high throughput screening in antibacterial assays. Several active wells were found, and the activity was verified by solution-phase synthesis of analytically pure material, indicating that the system described herein is an efficient means for the parallel synthesis of compounds for lead discovery. Copyright 1998 John Wiley & Sons, Inc.
Two-dimensional analysis of two-phase reacting flow in a firing direct-injection diesel engine
Nguyen, H. Lee
1989-01-01
The flow field, spray penetration, and combustion in two-stroke diesel engines are described. Fuel injection begins at 345 degrees after top dead center (ATDC) and n-dodecane is used as the liquid fuel. Arrhenius kinetics is used to calculate the reaction rate term in the quasi-global combustion model. When the temperature, fuel, and oxygen mass fraction are within suitable flammability limits, combustion begins spontaneously. No spark is necessary to ignite a localized high temperature region. Compression is sufficient to increase the gaseous phase temperature to a point where spontaneous chemical reactions occur. Results are described for a swirl angle of 22.5 degrees.
Phase transformations in engineering materials
International Nuclear Information System (INIS)
Bourke, M.A.M.; Lawson, A.C.; Dunand, D.C.
1996-01-01
Phase transformations in engineering materials are inevitably related to mechanical behavior and are often precursors to residual stress and distortion. Neutron scattering in general is a valuable tool for studying their effects, and pulsed neutrons are of special value, because of the inherently comprehensive crystallographic coverage they provide in each measurement. At the Manuel Lujan neutron scattering center several different research programs have addressed the relationships between phase transformation/mechanical behavior and residual strains. Three disparate examples are presented; (1) stress induced transformation in a NiTi shape memory alloy, (2) cryogenically induced transformation in a quenched 5180 steel, and (3) time resolved evolution of strain induced martensite in 304 stainless steel. In each case a brief description of the principle result will be discussed in the context of using neutrons for the measurement
Lima Gomes, Paulo C F; Barnes, Brian B; Santos-Neto, Álvaro J; Lancas, Fernando M; Snow, Nicholas H
2013-07-19
Analysis of several emerging contaminants (steroids, caffeine and methylparaben) in water using automated solid-phase microextraction with comprehensive two dimensional gas chromatography coupled to time of flight mass spectrometry (SPME-GCxGC-ToF/MS) is presented. Experimental design was used to determine the best SPME extraction conditions and the steroids were not derivatized prior to injection. SPME-GCxGC-ToF/MS provided linear ranges from 0.6 to 1200μgL(-1) and limits of detection and quantitation from 0.02 to 100μgL(-1). A series of river water samples obtained locally were subjected to analysis. SPME-GCxGC-ToF/MS is readily automated, straightforward and competitive with other methods for low level analysis of emerging contaminants. Copyright © 2013 Elsevier B.V. All rights reserved.
Xiao, Fan; Williams, Rob; Lancaster, Tom; Landee, Christopher; Turnbull, Mark
A family of randomized two-dimensional quantum Heisenberg antiferromagnets (2DQHAF) (QuinH)2CuCl4xBr4 (1 - x) . 2 H2O (QuinH=quinolinium) have been synthesized and characterized. In such systems, the original interaction in the square lattice parent compound (x = 0) is partially replaced by a different exchange strength. Zero-field muon spin relaxation (ZF μ+SR) experiments have revealed that the magnetic long range ordering can be strongly suppressed by the introduction of the second interaction and the ordering temperature TN drops sharply as x increases. No 3D long range ordered state was observed in the compounds with x > 0 . 25 and the system stays disordered down to the lowest accessible temperature. The structure, magnetic properties and the TN - x phase diagram of the family will be presented.
DiFilippo, Erica L; Brusseau, Mark L
2011-11-01
A simple, noninvasive imaging technique was used to obtain in situ measurements of organic-liquid saturation in a two-phase system under dynamic conditions. Efficacy of the light reflection visualization (LRV) imaging method was tested through comparison of measured and known volumes of organic liquid for experiments conducted with a two-dimensional flow cell. Two sets of experiments were conducted, with source-zone configurations representing two archetypical residual-and-pool architectures. LRV measurements were collected during the injection of organic liquid and during a dissolution phase induced by water flushing. There was a strong correlation between measured and known organic-liquid volumes, with the LRV-measured values generally somewhat lower than the known volumes. Errors were greater for the system wherein organic liquid was present in multiple zones comprised of porous media of different permeabilities, and for conditions of multiphase flow. This method proved effective at determining organic-liquid distribution in a two-phase system using minimal specialized equipment.
Energy Technology Data Exchange (ETDEWEB)
Tselev, Alexander [ORNL; Strelcov, Evgheni [Southern Illinois University; Luk' yanchuk, Prof. Igor A. [University of Picardie Jules Verne, Amiens, France; Ivanov, Ilia N [ORNL; Budai, John D [ORNL; Tischler, Jonathan Zachary [ORNL; Jones, Keith M [ORNL; Proksch, Roger [Asylum Research, Santa Barbara, CA; Kalinin, Sergei V [ORNL; Kolmakov, Andrei [ORNL
2010-01-01
Formation of ferroelastic twin domains in VO_2 nanosystems can strongly affect local strain distributions, and hence couple to the strain-controlled metal-insulator transition. Here we report polarized-light optical and scanning microwave microscopy studies of interrelated ferroelastic and metal-insulator transitions in single-crystalline vanadium dioxide (VO_2) quasi-two-dimensional (quasi-2D) nanoplatelets (NPls). In contrast to quasi-1D single-crystalline nanobeams, the geometric frustration results in emergence of several possible families of ferroelastic domains in NPls, thus allowing systematic studies of strain-controlled transitions in the presence of geometrical frustration. We demonstrate possibility of controlling the ferroelastic domain population by the strength of the NPl-substrate interaction, mechanical stress, and by the NPl lateral size. Ferroelastic domain species and domain walls are identified based on standard group-theoretical considerations. Using variable temperature microscopy, we imaged the development of domains of metallic and semiconducting phases during the metal-insulator phase transition and non-trivial strain-driven reentrant domain formation. A long-range reconstruction of ferroelastic structures accommodating metal-insulator domain formation has been observed. These studies illustrate that complete picture of the phase transitions in single-crystalline and disordered VO_2 structures can be drawn only if both ferroelastic and metal-insulator strain effects are taken into consideration and understood.
Directory of Open Access Journals (Sweden)
Dongjia Cao
2017-12-01
Full Text Available Phase-field simulation serves as an effective tool for quantitative characterization of microstructure evolution in single-crystal Ni-based superalloys during solidification nowadays. The classic unit cell is either limited to γ dendrites along crystal orientation or too ideal to cover complex morphologies for γ dendrites. An attempt to design the unit cell for two-dimensional (2-D phase-field simulations of microstructure evolution in single-crystal Ni-based superalloys during solidification was thus performed by using the MICRESS (MICRostructure Evolution Simulation Software in the framework of the multi-phase-field (MPF model, and demonstrated in a commercial TMS-113 superalloy. The coupling to CALPHAD (CALculation of PHAse Diagram thermodynamic database was realized via the TQ interface and the experimental diffusion coefficients were utilized in the simulation. Firstly, the classic unit cell with a single γ dendrite along crystal orientation was employed for the phase-field simulation in order to reproduce the microstructure features. Then, such simple unit cell was extended into the cases with two other different crystal orientations, i.e., and . Thirdly, for crystal orientations, the effect of γ dendritic orientations and unit cell sizes on microstructure and microsegregation was comprehensively studied, from which a new unit cell with multiple γ dendrites was proposed. The phase-field simulation with the newly proposed unit cell was further performed in the TMS-113 superalloy, and the microstructure features including the competitive growth of γ dendrites, microsegregation of different solutes and distribution of γ′ grains, can be nicely reproduced.
Gan, Liyong
2014-10-21
A combination of density functional theory, an empirical model, and Monte Carlo simulations is used to shed light on the evolution of the atomic distribution in the two-dimensional semiconducting transition metal dichalcogenide alloys Mo1−xWxX2 (X = S, Se, and Te) as a function of the W concentration and temperature. Both random and ordered phases are discovered and the origin of the phase transitions is clarified. While the empirical model predicts at x = 1/3 and 2/3 ordered alloys, Monte Carlo simulations suggest that they only exist at low temperature due to a small energetic preference of Mo-X-W over Mo-X-Mo and W-X-W interactions, explaining the experimental observation of random alloy Mo1−xWxS2. Negative formation energies point to a high miscibility. Tunability of the band edges and band gaps by alteration of the W concentration gives rise to a broad range of applications.
Phase field modeling of tetragonal to monoclinic phase transformation in zirconia
Mamivand, Mahmood
Zirconia based ceramics are strong, hard, inert, and smooth, with low thermal conductivity and good biocompatibility. Such properties made zirconia ceramics an ideal material for different applications form thermal barrier coatings (TBCs) to biomedicine applications like femoral implants and dental bridges. However, this unusual versatility of excellent properties would be mediated by the metastable tetragonal (or cubic) transformation to the stable monoclinic phase after a certain exposure at service temperatures. This transformation from tetragonal to monoclinic, known as LTD (low temperature degradation) in biomedical application, proceeds by propagation of martensite, which corresponds to transformation twinning. As such, tetragonal to monoclinic transformation is highly sensitive to mechanical and chemomechanical stresses. It is known in fact that this transformation is the source of the fracture toughening in stabilized zirconia as it occurs at the stress concentration regions ahead of the crack tip. This dissertation is an attempt to provide a kinetic-based model for tetragonal to monoclinic transformation in zirconia. We used the phase field technique to capture the temporal and spatial evolution of monoclinic phase. In addition to morphological patterns, we were able to calculate the developed internal stresses during tetragonal to monoclinic transformation. The model was started form the two dimensional single crystal then was expanded to the two dimensional polycrystalline and finally to the three dimensional single crystal. The model is able to predict the most physical properties associated with tetragonal to monoclinic transformation in zirconia including: morphological patterns, transformation toughening, shape memory effect, pseudoelasticity, surface uplift, and variants impingement. The model was benched marked with several experimental works. The good agreements between simulation results and experimental data, make the model a reliable tool for
Huang, Shaoya; Sun, Yunjun; Yang, Qi; Xiao, Xiuqing; Cao, Zhenping
2012-01-01
The proteome of a new Bacillus thuringiensis subsp. kurstaki strain, 4.0718, from the middle vegetative (T1), early sporulation (T2), and late sporulation (T3) phases was analyzed using an integrated liquid chromatography (LC)-based protein identification system. The system comprised two-dimensional (2D) LC coupled with nanoscale electrospray ionization (ESI) tandem mass spectrometry (MS/MS) on a high-resolution hybrid mass spectrometer with an automated data analysis system. After deletion of redundant proteins from the different batches and B. thuringiensis subspecies, 918, 703, and 778 proteins were identified in the respective three phases. Their molecular masses ranged from 4.6 Da to 477.4 Da, and their isoelectric points ranged from 4.01 to 11.84. Function clustering revealed that most of the proteins in the three phases were functional metabolic proteins, followed by proteins participating in cell processes. Small molecular and macromolecular metabolic proteins were further classified according to the Kyoto Encyclopedia of Genes and Genome and BioCyc metabolic pathway database. Three protoxins (Cry2Aa, Cry1Aa, and Cry1Ac) as well as a series of potential intracellular active factors were detected. Many significant proteins related to spore and crystal formation, including sporulation proteins, help proteins, chaperones, and so on, were identified. The expression patterns of two identified proteins, CotJc and glutamine synthetase, were validated by Western blot analysis, which further confirmed the MS results. This study is the first to use shotgun technology to research the proteome of B. thuringiensis. Valuable experimental data are provided regarding the methodology of analyzing the B. thuringiensis proteome (which can be used to produce insecticidal crystal proteins) and have been added to the related protein database. PMID:22636013
International Nuclear Information System (INIS)
Moesinger, H.
1979-08-01
The computer program DRIX-2D has been developed from SOLA-DF. The essential elements of the program structure are described. In order to verify DRIX-2D an Edwards-Blowdown-Experiment is calculated and other numerical results are compared with steady state experiments and models. Numerical experiments on transient two-phase flow, occurring in the broken pipe of a PWR in the case of a hypothetic LOCA, are performed. The essential results of the two-dimensional calculations are: 1. The appearance of a radial profile of void-fraction, velocity, sound speed and mass flow-rate inside the blowdown nozzle. The reason for this is the flow contraction at the nozzle inlet leading to more vapour production in the vicinity of the pipe wall. 2. A comparison between modelling in axisymmetric and Cartesian coordinates and calculations with and without the core barrel show the following: a) The three-dimensional flow pattern at the nozzle inlet is poorly described using Cartesian coordinates. In consequence a considerable difference in pressure history results. b) The core barrel alters the reflection behaviour of the pressure waves oscillating in the blowdown-nozzle. Therefore, the core barrel should be modelled as a wall normal to the nozzle axis. (orig./HP) [de
Directory of Open Access Journals (Sweden)
Dong Zhang
2017-10-01
Full Text Available In this paper, we focus on the problem of two-dimensional direction of arrival (2D-DOA estimation for monostatic MIMO Radar with electromagnetic vector received sensors (MIMO-EMVSs under the condition of gain and phase uncertainties (GPU and mutual coupling (MC. GPU would spoil the invariance property of the EMVSs in MIMO-EMVSs, thus the effective ESPRIT algorithm unable to be used directly. Then we put forward a C-SPD ESPRIT-like algorithm. It estimates the 2D-DOA and polarization station angle (PSA based on the instrumental sensors method (ISM. The C-SPD ESPRIT-like algorithm can obtain good angle estimation accuracy without knowing the GPU. Furthermore, it can be applied to arbitrary array configuration and has low complexity for avoiding the angle searching procedure. When MC and GPU exist together between the elements of EMVSs, in order to make our algorithm feasible, we derive a class of separated electromagnetic vector receiver and give the S-SPD ESPRIT-like algorithm. It can solve the problem of GPU and MC efficiently. And the array configuration can be arbitrary. The effectiveness of our proposed algorithms is verified by the simulation result.
Zhang, Dong; Zhang, Yongshun; Zheng, Guimei; Feng, Cunqian; Tang, Jun
2017-10-26
In this paper, we focus on the problem of two-dimensional direction of arrival (2D-DOA) estimation for monostatic MIMO Radar with electromagnetic vector received sensors (MIMO-EMVSs) under the condition of gain and phase uncertainties (GPU) and mutual coupling (MC). GPU would spoil the invariance property of the EMVSs in MIMO-EMVSs, thus the effective ESPRIT algorithm unable to be used directly. Then we put forward a C-SPD ESPRIT-like algorithm. It estimates the 2D-DOA and polarization station angle (PSA) based on the instrumental sensors method (ISM). The C-SPD ESPRIT-like algorithm can obtain good angle estimation accuracy without knowing the GPU. Furthermore, it can be applied to arbitrary array configuration and has low complexity for avoiding the angle searching procedure. When MC and GPU exist together between the elements of EMVSs, in order to make our algorithm feasible, we derive a class of separated electromagnetic vector receiver and give the S-SPD ESPRIT-like algorithm. It can solve the problem of GPU and MC efficiently. And the array configuration can be arbitrary. The effectiveness of our proposed algorithms is verified by the simulation result.
Figueiredo, T. P.; Rocha, J. C. S.; Costa, B. V.
2017-12-01
Although the topological Berezinskii-Kosterlitz-Thouless transition was for the first time described by 40 years ago, it is still a matter of discussion. It has been used to explain several experiments in the most diverse physical systems. In contrast with the ordinary continuous phase transitions the BKT-transition does not break any symmetry. However, in some contexts it can easily be confused with other continuous transitions, in general due to an insufficient data analysis. The two-dimensional XY (or sometimes called planar rotator) spin model is the fruit fly model describing the BKT transition. As demonstrated by Bramwell and Holdsworth (1993) the finite-size effects are more important in two-dimensions than in others due to the logarithmic system size dependence of the properties of the system. Closely related is the anisotropic two dimensional Heisenberg model (AH). Although they have the same Hamiltonian the spin variable in the former has only two degrees of freedom while the AH has three. Many works treat the AH model as undergoing a transition in the same universality class as the XY model. However, its characterization as being in the BKT class of universality deserve some investigation. This paper has two goals. First, we describe an analytical evidence showing that the AH model is in the BKT class of universality. Second, we make an extensive simulation, using the numerical Replica Exchange Wang-Landau method that corroborate our analytical calculations. From our simulation we obtain the BKT transition temperature as TBKT = 0 . 6980(10) by monitoring the susceptibility, the two point correlation function and the helicity modulus. We discuss the misuse of the fourth order Binder's cumulant to locate the transition temperature. The specific heat is shown to have a non-critical behavior as expected in the BKT transition. An analysis of the two point correlation function at low temperature, C(r) ∝r - η(T), shows that the exponent, η, is consistent
Phase transformations in metallic glasses
DEFF Research Database (Denmark)
Jiang, Jianzhong
2003-01-01
Recent development of grain-size effect on phase transformations induced by pressure is reported. A thermodynamic theory is presented and three components: the ratio of volume collapses, the surface energy differences, and the internal energy differences, governing the change of transition pressure...... in nanocrystals were uncovered. They can be used to explain the results reported in the literature and to identify the main factor to the change of the transition pressure in nanocrystals. We demonstrated that the grain-size effect on the structural stability in nanocrystals with respect to transition pressure...
Energy Technology Data Exchange (ETDEWEB)
Torre-Fernández, Laura; Khainakova, Olena A. [Departamentos de Química Física y Analítica y Química Orgánica e Inorgánica, Universidad de Oviedo-CINN, 33006 Oviedo (Spain); Espina, Aránzazu [Servicios Científico Técnicos, Universidad de Oviedo, 33006 Oviedo (Spain); Amghouz, Zakariae, E-mail: amghouz.uo@uniovi.es [Servicios Científico Técnicos, Universidad de Oviedo, 33006 Oviedo (Spain); Khainakov, Sergei A. [Servicios Científico Técnicos, Universidad de Oviedo, 33006 Oviedo (Spain); Alfonso, Belén F.; Blanco, Jesús A. [Departamento de Física, Universidad de Oviedo, 33007 Oviedo (Spain); García, José R.; García-Granda, Santiago [Departamentos de Química Física y Analítica y Química Orgánica e Inorgánica, Universidad de Oviedo-CINN, 33006 Oviedo (Spain)
2015-05-15
A two-dimensional piperazinium cobalt–zinc phosphate, formulated as (C{sub 4}N{sub 2}H{sub 12}){sub 1.5}(Co{sub 0.6}Zn{sub 0.4}){sub 2}(HPO{sub 4}){sub 2}(PO{sub 4})·H{sub 2}O (2D), was synthesized under hydrothermal conditions. The crystal structure was determined using single-crystal X-ray diffraction data (monoclinic P2{sub 1}/c, a=8.1165(3) Å, b=26.2301(10) Å, c=8.3595(4) Å, and β=110.930(5)°) and the hydrogen atom positions were optimized by DFT calculations. A single-crystal corresponding to one-dimensional metastable phase, (C{sub 4}N{sub 2}H{sub 12})Co{sub 0.3}Zn{sub 0.7}(HPO{sub 4}){sub 2}·H{sub 2}O (1D), was also isolated and the crystal structure was determined (monoclinic P2{sub 1}/c, a=8.9120(6) Å, b=14.0290(1) Å, c=12.2494(5) Å, and β=130.884(6)°). The bulk was characterized by chemical (C–H–N) analysis, powder X-ray diffraction (PXRD), powder X-ray thermodiffractometry (HT-XRD), transmission electron microscopy (STEM(DF)-EDX and EFTEM), and thermal analysis (TG/SDTA-MS), including activation energy data of its thermal decomposition. The magnetic susceptibility and magnetization measurements show no magnetic ordering down to 4 K. - Graphical abstract: Hydrothermal synthesis and structural characterization of a two-dimensional piperazinium cobalt–zinc phosphate, (C{sub 4}N{sub 2}H{sub 12}){sub 1.5}(Co{sub 0.6}Zn{sub 0.4}){sub 2}(HPO{sub 4}){sub 2}(PO{sub 4})·H{sub 2}O (2D), have been reported. The crystal structure of a one-dimensional piperazinium cobalt–zinc phosphate, (C{sub 4}N{sub 2}H{sub 12})Co{sub 0.3}Zn{sub 0.7}(HPO{sub 4}){sub 2}·H{sub 2}O (1D) a metastable phase during the hydrothermal synthesis, was also determined. The thermal behavior of 2D compound is strongly dependent on the selected heating rate and the magnetic susceptibility and magnetization measurements show no magnetic ordering down to 4 K. - Highlights: • A 2D piperazinium cobalt–zinc phosphate has been synthesized and characterized. • Crystal
Mamin, R. F.; Shaposhnikova, T. S.; Kabanov, V. V.
2018-03-01
We have considered the model of the phase transition of the second order for the Coulomb frustrated 2D charged system. The coupling of the order parameter with the charge was considered as the local temperature. We have found that in such a system, an appearance of the phase-separated state is possible. By numerical simulation, we have obtained different types ("stripes," "rings," "snakes") of phase-separated states and determined the parameter ranges for these states. Thus the system undergoes a series of phase transitions when the temperature decreases. First, the system moves from the homogeneous state with a zero order parameter to the phase-separated state with two phases in one of which the order parameter is zero and, in the other, it is nonzero (τ >0 ). Then a first-order transition occurs to another phase-separated state, in which both phases have different and nonzero values of the order parameter (for τ <0 ). Only a further decrease of temperature leads to a transition to a homogeneous ordered state.
Neutron scattering at structural phase transformations
International Nuclear Information System (INIS)
Plakida, N.M.
1982-01-01
The specific fractures of neutron scattering cross sections on crystal lattices at structural phase transformations are considered in the lecture. The analysis of the elastic and inelastic scattering is carried out at different transformations (ordering type, displacement type incommensurable transformations). The experimental study on some transitions are given as an example, namely, transformation at the Brillouin zone edge in cubic perovskite. RbCaF 3 transformation in a quasiunidimensional ferroelectrics CsH 2 PO 4 and CsD 2 PO 4 , phase transformation into an incommensurable phase in diphenyl
Savareear, Benjamin; Brokl, Michał; Wright, Chris; Focant, Jean-Francois
2017-11-24
A thermal desorption comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (TD-GC×GC-TOFMS) method has been developed for the analysis of mainstream tobacco smoke (MTS) vapour phase (VP). The selection process of the sample introduction approach involved comparing the results obtained from three different approaches: a) use of gas sampling bag followed by SPME (Tedlar ® -SPME), b) gas sampling bag followed by TD (Tedlar ® -TD), and c) sampling directly on TD sorbents (Direct-TD). Six different SPME fibers and six different TD sorbent beds were evaluated for the extraction capacities in terms of total number of peaks and related intensities or peak areas. The best results were obtained for the Direct-TD approach using Tenax TA/Carbograph1TD/Carboxen1003 sorbent tubes. The optimisation of TD tube desorption parameters was carried out using a face-centered central composite experimental design and resulted in the use of the Tenax TA/Carbograph 1TD/Carboxen 1003 sorbent with a 7.5min desorption time, a 60mL/min tube desorption flow, and a 250°C tube desorption temperature. The optimised method was applied to the separation of MTS-VP constituents, with 665 analytes detected. The method precision ranged from 1% to 15% for over 99% of identified peak areas and from 0% to 3% and 0% to 1% for both first ( 1 t R ) and second ( 2 t R ) dimension retention times, respectively. The method was applied to the analyses of two cigarette types differing in their filter construction. Principal component analysis (PCA) allowed a clear differentiation of the studied cigarette types (PC1 describing 94% of the explained variance). Supervised Fisher ratio analysis permitted the identification of compounds responsible for the chemical differences between the two sample types. A set of 91 most relevant compounds was selected by applying a Fisher ratio cut-off approach and most of them were selectively removed by one of the cigarette filter types
DEFF Research Database (Denmark)
Celis, J E; Dejgaard, K; Madsen, Peder
1990-01-01
A new version of the MRC-5 two-dimensional gel cellular protein database (Celis et al., Electrophoresis 1989, 10, 76-115) is presented. Gels were scanned with a Molecular Dynamics laser scanner and processed by the PDQUEST II software. A total of 1895 [35S]methionine-labeled cellular polypeptides...... (1323 with isoelectric focusing and 572 with nonequilibrium pH gradient electrophoresis) are recorded in this database, containing quantitative and qualitative data on the relative abundance of cellular proteins synthesized by quiescent, proliferating and SV40 transformed MRC-5 fibroblasts. Of the 592...... proteins quantitated so far, the levels of 138 were up- or down-regulated (51 and 87, respectively) by two times or more in the transformed cells as compared to their normal proliferating counterparts, while only 14 behaved similarly in quiescent cells. Seven MRC-5 SV40 proteins, including plastin and two...
Sheng, Qianying; Yang, Kaiya; Ke, Yanxiong; Liang, Xinmiao; Lan, Minbo
2016-09-01
Maltose covalently bonded to silica was prepared by using carbonyl diimidazole as a cross-linker and employed as a stationary phase for hydrophilic interaction liquid chromatography. The column efficiency and the effect of water content, buffer concentration, and pH value influenced on retention were investigated. The separation or enrichment selectivity was also studied with nucleosides, saccharides, amino acids, peptides, and glycopeptides. The results indicated that the stationary phase processed good separation efficiency and separation selectivity in hydrophilic interaction liquid chromatography mode. Moreover, a two-dimensional hydrophilic interaction liquid chromatography× reversed-phase liquid chromatography method with high orthogonality was developed to analyze the Ginkgo Biloba extract fractions. The development of this two-dimensional chromatographic system would be an effective tool for the separation of complex samples of different polarities and contents. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Two-dimensional x-ray diffraction
He, Bob B
2009-01-01
Written by one of the pioneers of 2D X-Ray Diffraction, this useful guide covers the fundamentals, experimental methods and applications of two-dimensional x-ray diffraction, including geometry convention, x-ray source and optics, two-dimensional detectors, diffraction data interpretation, and configurations for various applications, such as phase identification, texture, stress, microstructure analysis, crystallinity, thin film analysis and combinatorial screening. Experimental examples in materials research, pharmaceuticals, and forensics are also given. This presents a key resource to resea
DEFF Research Database (Denmark)
Celis, J E; Gesser, B; Rasmussen, H H
1990-01-01
A total of 3430 polypeptides (2592 cellular; 838 secreted) from transformed human amnion cells (AMA) labeled with [35S]methionine were separated and recorded using computer-aided two-dimensional (2-D) gel electrophoresis. A master 2-D gel database of cellular protein information that includes both...... qualitative and quantitative annotations has been established. The protein numbers in this database differ from those reported in an earlier version (Celis et al. Leukemia 1988, 2,561-602) as a result of changes in the scanning hardware. The reported information includes: percentage of total radioactivity...... recovered from the gels (based on quantitations of polypeptides labeled with a mixture of 16 14C-amino acids), protein name (including credit to investigators that aided identification), antibody against protein, cellular localization, (nuclear, 40S hnRNP, 20S snRNP U5, proteasomes, endoplasmic reticulum...
Seetharam, H. C.; Wentz, W. H., Jr.
1975-01-01
Results were given on experimental studies of flow separation and stalling on a two-dimensional GA(W)-1 17 percent thick airfoil with an extended Fowler flap. Experimental velocity profiles obtained from a five tube probe survey with optimum flap gap and overlap setting (flap at 40 deg) are shown at various stations above, below, and behind the airfoil/flap combination for various angles of attack. The typical zones of steady flow, intermittent turbulence, and large scale turbulence were obtained from a hot wire anemometer survey and are depicted graphically for an angle of attack of 12.5 deg. Local skin friction distributions were obtained and are given for various angles of attack. Computer plots of the boundary layer profiles are shown for the case of the flap at 40 deg. Static pressure contours are also given. A GA(W)-2 section model was fabricated with 30 percent Fowler flaps and with pressure tabs.
Quasi-two-dimensional holography
International Nuclear Information System (INIS)
Kutzner, J.; Erhard, A.; Wuestenberg, H.; Zimpfer, J.
1980-01-01
The acoustical holography with numerical reconstruction by area scanning is memory- and time-intensive. With the experiences by the linear holography we tried to derive a scanning for the evaluating of the two-dimensional flaw-sizes. In most practical cases it is sufficient to determine the exact depth extension of a flaw, whereas the accuracy of the length extension is less critical. For this reason the applicability of the so-called quasi-two-dimensional holography is appropriate. The used sound field given by special probes is divergent in the inclined plane and light focussed in the perpendicular plane using cylindrical lenses. (orig.) [de
Grain nucleation and growth during phase transformations
DEFF Research Database (Denmark)
Offerman, S.E.; Dijk, N.H. van; Sietsma, J.
2002-01-01
The mechanical properties of polycrystalline materials are largely determined by the kinetics of the phase transformations during the production process. Progress in x-ray diffraction instrumentation at synchrotron sources has created an opportunity to study the transformation kinetics at the level...
Two dimensional plasma simulation code
International Nuclear Information System (INIS)
Hazak, G.; Boneh, Y.; Goshen, Sh.; Oreg, J.
1977-03-01
An electrostatic two-dimensional particle code for plasma simulation is described. Boundary conditions which take into account the finiteness of the system are presented. An analytic solution for the case of crossed fields plasma acceleration is derived. This solution serves as a check on a computer test run
Pirok, Bob W J; Knip, Jitske; van Bommel, Maarten R; Schoenmakers, Peter J
2016-03-04
In the late 19th century, newly invented synthetic dyes rapidly replaced the natural dyes on the market. The characterization of mixtures of these so-called early synthetic dyes is complicated through the occurrence of many impurities and degradation products. Conventional one-dimensional liquid chromatography does not suffice to obtain fingerprints with sufficient resolution and baseline integrity. Comprehensive two-dimensional liquid chromatography (LC×LC) is employed in this study, with ion-exchange chromatography in the first dimension and fast ion-pair liquid chromatography in the second. Retention in the first dimension is largely determined by the number of charges, while the selection of a small ion-pair reagent (tetramethylammonium hydroxide) in the second dimension causes retention to be largely determined by the molecular structure of the dye. As a result, there is a high degree of orthogonality of the two dimensions, similar to the values typically encountered in GC×GC. The proposed LC×LC method shows a theroretical peak capacity of about 2000 in an analysis time of about three hours. Clear, informative fingerprints are obtained that open a way to a more efficient characterization of dyes used in objects of cultural heritage. Copyright © 2016 Elsevier B.V. All rights reserved.
Soliton bubbles and phase transformations
International Nuclear Information System (INIS)
Masperi, L.
1989-01-01
It is shown that no topological classical solutions in form of bubbles of a real scalar field theory with Lagrangian of quartet and sextet self interactions in 1+1 dimensions are responsible to discontinue transitions in the quantum problem between phases with degenerated and disordered excited level. (M.C.K.)
Path Dependency of High Pressure Phase Transformations
Cerreta, Ellen
2017-06-01
At high pressures titanium and zirconium are known to undergo a phase transformation from the hexagonal close packed (HCP), alpha-phase to the simple-hexagonal, omega-phase. Under conditions of shock loading, the high-pressure omega-phase can be retained upon release. It has been shown that temperature, peak shock stress, and texture can influence the transformation. Moreover, under these same loading conditions, plastic processes of slip and twinning are also affected by similar differences in the loading path. To understand this path dependency, in-situ velocimetry measurements along with post-mortem metallographic and neutron diffraction characterization of soft recovered specimens have been utilized to qualitatively understand the kinetics of transformation, quantify volume fraction of retained omega-phase and characterize the shocked alpha and omega-phases. Together the work described here can be utilized to map the non-equilibrium phase diagram for these metals and lend insight into the partitioning of plastic processes between phases during high pressure transformation. In collaboration with: Frank Addesssio, Curt Bronkhorst, Donald Brown, David Jones, Turab Lookman, Benjamin Morrow, Carl Trujillo, Los Alamos National Lab.; Juan Pablo Escobedo-Diaz, University of New South Wales; Paulo Rigg, Washington State University.
Effect of Phase Transformations on Seismic Velocities
Weidner, D. J.; Li, L.; Whitaker, M.; Triplett, R.
2017-12-01
The radial velocity structure of the Earth consists of smooth variations of velocities with depth punctuated by abrupt changes of velocity, which are typically due to multivariant phase transformations, where high - low pressure phases can coexist. In this mixed phase region, both the effective shear and bulk moduli will be significantly reduced by the dynamic interaction of the propagating wave and the phase transition if the period of the wave is long enough relative to the kinetic time so that some of the transition can take place. In this presentation, we will give examples from both laboratory studies of phases transitions of Earth minerals and the calculated velocity profile based on our models. We focus on understanding the time limiting factor of the phase transformation in order to extrapolate laboratory results to Earth observations. Both the olivine to ringwoodite transition and KLB-1 partial melting are explored. We find that when the transformation requires diffusion, the kinetics are often slowed down considerably and as a result the diffusivity of atoms become the limiting factor of characteristic time. Specifically Fe-Mg exchange rate in the olivine-ringwoodite phase transition becomes the limiting factor that seismic waves are likely to sample. On the other hand, partial melting is an extremely fast phase transformation at seismic wave periods. We present evidence that ultrasonic waves, with a period of a few tens of nanoseconds, are slowed by the reduction of the effective elastic moduli in this case.
Ponsin, Violaine; Buscheck, Timothy E; Hunkeler, Daniel
2017-04-07
Compound-specific isotope analysis (CSIA) is increasingly used to evaluate the origin and fate of petroleum hydrocarbons in the environment. However, as samples often contain a complex mixture of compounds and the method requires a full chromatographic separation, it can be challenging to obtain accurate and precise isotope values. In this study, in order to develop a method to analyze carbon isotopes in benzene, toluene, ethylbenzene, and xylenes (BTEX) in complex environmental samples, a two-dimensional heart-cutting gas chromatograph (GC) was hyphenated to an isotope ratio mass spectrometer (IRMS). The focus was placed on benzene and toluene, which are the main compounds of concern in contaminated sites. A full separation for BTEX was successfully achieved using a 60m polar column in the first dimension and a 30m non-polar column in the second dimension. Accuracy and precision of carbon isotope measurements of standards were not impacted by the new setup compared to classic one-dimensional (1D) GC-C-IRMS. For benzene and toluene, precision remained very good (≤0.2‰) for concentrations comprised between 5 and 20μg/L. A high matrix load did not influence the precision and accuracy of isotope measurements. The method was tested on several samples from two different field sites. For all samples tested, full chromatographic baseline resolution was achieved for benzene and toluene. Spatial variability of isotopes values linked to biodegradation was evidenced for one field site. This new 2D-GC-C-IRMS method will broaden the spectrum of samples suitable for isotope analysis and will be therefore able to give new insights into attenuation processes of BTEX in contaminated sites or source fingerprinting. Copyright © 2017 Elsevier B.V. All rights reserved.
Sakhratov, Yu. A.; Kweon, J. J.; Choi, E. S.; Zhou, H. D.; Svistov, L. E.; Reyes, A. P.
2018-03-01
The magnetic phase diagram of CuCrO2 was studied with an alternative method of simultaneous Cu NMR and electric polarization techniques with the primary goal of demonstrating that, regardless of cooling history of the sample, the magnetic phase with specific helmet-shaped NMR spectra associated with interplanar disorder possesses electric polarization. Our result unequivocally confirms the assumption of Sakhratov et al. [Phys. Rev. B 94, 094410 (2016), 10.1103/PhysRevB.94.094410] that the high-field low-temperature phase is in fact a three-dimensional (3D) polar phase characterized by a 3D magnetic order with tensor order parameter. In comparison with the results obtained in pulsed fields, a modified phase diagram is introduced defining the upper boundary of the first-order transition from the 3D spiral to the 3D polar phase.
Two dimensional image correlation processor
Yao, Shi-Kai
1992-06-01
Two dimensional images are converted into a very long 1-dimensional data stream by means of raster scan. It is shown that the 1-dimensional correlation function of such long data streams is equivalent to the raster scan converted data of 2-dimensional correlation function of images. Real time correlation of high resolution two-dimensional images has been demonstrated using commercially available components. The advantages of this approach includes programmable electronics reference images, easy interface to objects of interest using conventional image collection optics, real time operation with high resolution images using off-the shelf components, and usefulness in the form of either black and white or full colored images. Such system would be versatile enough for robotics vision, optical inspection, and other pattern recognition and identification applications.
Two-dimensional topological photonics
Khanikaev, Alexander B.; Shvets, Gennady
2017-12-01
Originating from the studies of two-dimensional condensed-matter states, the concept of topological order has recently been expanded to other fields of physics and engineering, particularly optics and photonics. Topological photonic structures have already overturned some of the traditional views on wave propagation and manipulation. The application of topological concepts to guided wave propagation has enabled novel photonic devices, such as reflection-free sharply bent waveguides, robust delay lines, spin-polarized switches and non-reciprocal devices. Discrete degrees of freedom, widely used in condensed-matter physics, such as spin and valley, are now entering the realm of photonics. In this Review, we summarize the latest advances in this highly dynamic field, with special emphasis on the experimental work on two-dimensional photonic topological structures.
Two dimensional generalizations of the Newcomb equation
International Nuclear Information System (INIS)
Dewar, R.L.; Pletzer, A.
1989-11-01
The Bineau reduction to scalar form of the equation governing ideal, zero frequency linearized displacements from a hydromagnetic equilibrium possessing a continuous symmetry is performed in 'universal coordinates', applicable to both the toroidal and helical cases. The resulting generalized Newcomb equation (GNE) has in general a more complicated form than the corresponding one dimensional equation obtained by Newcomb in the case of circular cylindrical symmetry, but in this cylindrical case , the equation can be transformed to that of Newcomb. In the two dimensional case there is a transformation which leaves the form of the GNE invariant and simplifies the Frobenius expansion about a rational surface, especially in the limit of zero pressure gradient. The Frobenius expansions about a mode rational surface is developed and the connection with Hamiltonian transformation theory is shown. 17 refs
Cui, Yulei; Shen, Na; Dang, Jun; Mei, Lijuan; Tao, Yanduo; Liu, Zenggen
2017-07-01
Bioactive equivalent combinatorial components play a critical role in herbal medicines. However, how to discover and enrich them efficiently is a question for herbal pharmaceuticals researchers. In our work, a novel two-dimensional reversed-phase/hydrophilic interaction high-performance liquid chromatography method was established to perform real-time components trapping and combining for preparation and isolation of coeluting components. Arenaria kansuensis was taken as an example, and solid-phase extraction coupled with liquid-liquid extraction as a simple and efficient method for enriching trace components, reversed phase column coupled with hydrophilic interaction liquid chromatography XAmide column as two-dimensional chromatography technology for isolation and preparation of coeluting constituents, enzyme-linked immune-sorbent assay as bio-guided assay, and anti-inflammatory bioactivity evaluation for bioactive constituents. A combination of 12 β-carboline alkaloids was identified as anti-inflammatory bioactive equivalent combinatorial components from A. kansuensis, which accounts for 1.9% w/w of original A. kansuensis. This work answers the key question of which are real anti-inflammatory components from A. kansuensis and provides a fast and efficient approach for discovering and enriching trace β-carboline alkaloids from herbal medicines for the first time. More importantly, the discovery of bioactive equivalent combinatorial components could improve the quality control of herbal products and inspire a herbal medicine based on combinatorial therapeutics. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Equivalency of two-dimensional algebras
International Nuclear Information System (INIS)
Santos, Gildemar Carneiro dos; Pomponet Filho, Balbino Jose S.
2011-01-01
Full text: Let us consider a vector z = xi + yj over the field of real numbers, whose basis (i,j) satisfy a given algebra. Any property of this algebra will be reflected in any function of z, so we can state that the knowledge of the properties of an algebra leads to more general conclusions than the knowledge of the properties of a function. However structural properties of an algebra do not change when this algebra suffers a linear transformation, though the structural constants defining this algebra do change. We say that two algebras are equivalent to each other whenever they are related by a linear transformation. In this case, we have found that some relations between the structural constants are sufficient to recognize whether or not an algebra is equivalent to another. In spite that the basis transform linearly, the structural constants change like a third order tensor, but some combinations of these tensors result in a linear transformation, allowing to write the entries of the transformation matrix as function of the structural constants. Eventually, a systematic way to find the transformation matrix between these equivalent algebras is obtained. In this sense, we have performed the thorough classification of associative commutative two-dimensional algebras, and find that even non-division algebra may be helpful in solving non-linear dynamic systems. The Mandelbrot set was used to have a pictorial view of each algebra, since equivalent algebras result in the same pattern. Presently we have succeeded in classifying some non-associative two-dimensional algebras, a task more difficult than for associative one. (author)
Baglai, Anna; Gargano, Andrea F G; Jordens, Jan; Mengerink, Ynze; Honing, Maarten; van der Wal, Sjoerd; Schoenmakers, Peter J
2017-12-29
Recent advancements in separation science have resulted in the commercialization of multidimensional separation systems that provide higher peak capacities and, hence, enable a more-detailed characterization of complex mixtures. In particular, two powerful analytical tools are increasingly used by analytical scientists, namely online comprehensive two-dimensional liquid chromatography (LC×LC, having a second-dimension separation in the liquid phase) and liquid chromatography-ion mobility-spectrometry (LC-IMS, second dimension separation in the gas phase). The goal of the current study was a general assessment of the liquid-chromatography-trapped-ion-mobility-mass spectrometry (LC-TIMS-MS) and comprehensive two-dimensional liquid chromatography-mass spectrometry (LC×LC-MS) platforms for untargeted lipid mapping in human plasma. For the first time trapped-ion-mobility spectrometry (TIMS) was employed for the separation of the major lipid classes and ion-mobility-derived collision-cross-section values were determined for a number of lipid standards. The general effects of a number of influencing parameters have been inspected and possible directions for improvements are discussed. We aimed to provide a general indication and practical guidelines for the analyst to choose an efficient multidimensional separation platform according to the particular requirements of the application. Analysis time, orthogonality, peak capacity, and an indicative measure for the resolving power are discussed as main characteristics for multidimensional separation systems. Copyright © 2017 Elsevier B.V. All rights reserved.
Yi, Xin; Gao, Huajian
2014-06-01
A fundamental understanding of cell-nanomaterial interaction is essential for biomedical diagnostics, therapeutics, and nanotoxicity. Here, we perform a theoretical analysis to investigate the phase diagram and morphological evolution of an elastic rod-shaped nanoparticle wrapped by a lipid membrane in two dimensions. We show that there exist five possible wrapping phases based on the stability of full wrapping, partial wrapping, and no wrapping states. The wrapping phases depend on the shape and size of the particle, adhesion energy, membrane tension, and bending rigidity ratio between the particle and membrane. While symmetric morphologies are observed in the early and late stages of wrapping, in between a soft rod-shaped nanoparticle undergoes a dramatic symmetry breaking morphological change while stiff and rigid nanoparticles experience a sharp reorientation. These results are of interest to the study of a range of phenomena including viral budding, exocytosis, as well as endocytosis or phagocytosis of elastic particles into cells.
Magnetic phase transitions in two-dimensional frustrated Cu3R(SeO3)2O2Cl. Spectroscopic study
Klimin, S. A.; Budkin, I. V.
2017-01-01
Using optical study of electronic spectra of rare-earth (RE) ions, magnetic phase transitions in the low-dimensional frustrated RE magnets Cu3R(SeO3)2O2Cl (R = Sm, Yb, Er, Nd, Pr, Eu) were investigated. Phase transitions were registered either by splittings of crystal-field (CF) doublets or by repulsion of CF levels of f-ions in a staggered magnetic field. Different scenarios of magnetic order in isostructural compounds of the francisite family are discussed.
Energy Technology Data Exchange (ETDEWEB)
Tikhonov, A. M. [Russian Academy of Sciences (RAS), Moscow (Russian Federation). Kapitza Inst. for Physical Problems
2016-09-01
According to experimental data on X-ray scattering and reflectometry with synchrotron radiation, a twodimensional crystallization phase transition in a monolayer of melissic acid at the n-hexane–water interface with a decrease in the temperature occurs after a wetting transition.
Tikhonov, A. M.
2017-11-01
The molecular structure of neutral n-triacontanol mesophases at the n-hexane-water interface has been studied by diffuse X-ray scattering using synchrotron radiation. According to the experimental data, a transition to the multilayer adsorption of alkanol occurs at a temperature below the transition from a gas phase to a liquid Gibbs monolayer.
Two dimensional compass model with Heisenberg interactions
Pires, A. S. T.
2018-04-01
We consider a two dimensional compass model with a next and a next near Heisenberg term. The interactions are of two types: frustrated near neighbor compass interactions of amplitudes Jx and Jy, and next and next near neighbor Heisenberg interactions with exchanges J1 and J2 respectively. The Heisenberg interactions are isotropic in spin space, but the compass interactions depend on the bond direction. The ground state of the pure compass model is degenerated with a complex phase diagram. This degeneracy is removed by the Heisenberg terms leading to the arising of a magnetically ordered phase with a preferred direction. We calculate the phase diagrams at zero temperature for the case where, for J2 = 0, we have an antiferromagnetic ground state. We show that varying the value of J2, a magnetically disordered phase can be reached for small values of the compass interactions. We also calculate the critical temperature for a specified value of parameters.
Phase Transformations During Cooling of Automotive Steels
Padgett, Matthew C.
This thesis explores the effect of cooling rate on the microstructure and phases in advanced high strength steels (AHSS). In the manufacturing of automobiles, the primary joining mechanism for steel is resistance spot welding (RSW), a process that produces a high heat input and rapid cooling in the welded metal. The effect of RSW on the microstructure of these material systems is critical to understanding their mechanical properties. A dual phase steel, DP-600, and a transformation induced plasticity bainitic-ferritic steel, TBF-1180, were studied to assess the changes to their microstructure that take place in controlled cooling environments and in uncontrolled cooling environments, i.e. resistance spot welding. Continuous cooling transformation (CCT) diagrams were developed using strip specimens of DP-600 and TBF-1180 to determine the phase transformations that occur as a function of cooling rate. The resulting phases were determined using a thermal-mechanical simulator and dilatometry, combined with light optical microscopy and hardness measurements. The resulting phases were compared with RSW specimens where cooling rate was controlled by varying the welding time for two-plate welds. Comparisons were drawn between experimental welds of DP-600 and simulations performed using a commercial welding software. The type and quantity of phases present after RSW were examined using a variety of techniques, including light optical microscopy using several etchants, hardness measurements, and x-ray diffraction (XRD).
Gate-tunable polarized phase of two-dimensional electrons at the LaAlO3/SrTiO3 interface.
Joshua, Arjun; Ruhman, Jonathan; Pecker, Sharon; Altman, Ehud; Ilani, Shahal
2013-06-11
Controlling the coupling between localized spins and itinerant electrons can lead to exotic magnetic states. A novel system featuring local magnetic moments and extended 2D electrons is the interface between LaAlO3 and SrTiO3. The magnetism of the interface, however, was observed to be insensitive to the presence of these electrons and is believed to arise solely from extrinsic sources like oxygen vacancies and strain. Here we show the existence of unconventional electronic phases in the LaAlO3/SrTiO3 system pointing to an underlying tunable coupling between itinerant electrons and localized moments. Using anisotropic magnetoresistance and anomalous Hall effect measurements in a unique in-plane configuration, we identify two distinct phases in the space of carrier density and magnetic field. At high densities and fields, the electronic system is strongly polarized and shows a response, which is highly anisotropic along the crystalline directions. Surprisingly, below a density-dependent critical field, the polarization and anisotropy vanish whereas the resistivity sharply rises. The unprecedented vanishing of the easy axes below a critical field is in sharp contrast with other coupled magnetic systems and indicates strong coupling with the moments that depends on the symmetry of the itinerant electrons. The observed interplay between the two phases indicates the nature of magnetism at the LaAlO3/SrTiO3 interface as both having an intrinsic origin and being tunable.
Two-dimensional capillary origami
International Nuclear Information System (INIS)
Brubaker, N.D.; Lega, J.
2016-01-01
We describe a global approach to the problem of capillary origami that captures all unfolded equilibrium configurations in the two-dimensional setting where the drop is not required to fully wet the flexible plate. We provide bifurcation diagrams showing the level of encapsulation of each equilibrium configuration as a function of the volume of liquid that it contains, as well as plots representing the energy of each equilibrium branch. These diagrams indicate at what volume level the liquid drop ceases to be attached to the endpoints of the plate, which depends on the value of the contact angle. As in the case of pinned contact points, three different parameter regimes are identified, one of which predicts instantaneous encapsulation for small initial volumes of liquid. - Highlights: • Full solution set of the two-dimensional capillary origami problem. • Fluid does not necessarily wet the entire plate. • Global energy approach provides exact differential equations satisfied by minimizers. • Bifurcation diagrams highlight three different regimes. • Conditions for spontaneous encapsulation are identified.
Two-dimensional capillary origami
Energy Technology Data Exchange (ETDEWEB)
Brubaker, N.D., E-mail: nbrubaker@math.arizona.edu; Lega, J., E-mail: lega@math.arizona.edu
2016-01-08
We describe a global approach to the problem of capillary origami that captures all unfolded equilibrium configurations in the two-dimensional setting where the drop is not required to fully wet the flexible plate. We provide bifurcation diagrams showing the level of encapsulation of each equilibrium configuration as a function of the volume of liquid that it contains, as well as plots representing the energy of each equilibrium branch. These diagrams indicate at what volume level the liquid drop ceases to be attached to the endpoints of the plate, which depends on the value of the contact angle. As in the case of pinned contact points, three different parameter regimes are identified, one of which predicts instantaneous encapsulation for small initial volumes of liquid. - Highlights: • Full solution set of the two-dimensional capillary origami problem. • Fluid does not necessarily wet the entire plate. • Global energy approach provides exact differential equations satisfied by minimizers. • Bifurcation diagrams highlight three different regimes. • Conditions for spontaneous encapsulation are identified.
Modelling of phase transformations in substitutional alloys
Czech Academy of Sciences Publication Activity Database
Svoboda, Jiří; Vala, J.; Gamsjäger, E.; Fischer, F. D.
237-240, - (2005), s. 647-652 ISSN 1012-0386. [DIMAT 2004 /6./. Krakow, 18.07.2004-23.07.2004] R&D Projects: GA AV ČR(CZ) 1QS200410502 Institutional research plan: CEZ:AV0Z20410507 Keywords : phase transformations Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.483, year: 2005
Orbital momentum and topological phase transformation
Czech Academy of Sciences Publication Activity Database
Středa, Pavel; Kučera, Jan
2015-01-01
Roč. 92, č. 23 (2015), "235152-1"-"235152-6" ISSN 1098-0121 R&D Projects: GA ČR GA15-13436S Institutional support: RVO:68378271 Keywords : orbital momentum * anomalous Hall effect * topological phase transformation Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.736, year: 2014
Phase transformations, stability, and materials interactions
International Nuclear Information System (INIS)
Morris, J.W. Jr.; Brewer, L.; Cost, J.R.; Shewmon, P.
1977-07-01
The proceedings of the Materials Sciences Workshop on Phase Transformations, Stability, and Materials Interactions are divided into sections according to the following topics: (I) workshop scope and priorities; (II) study group reports--ERDA mission needs; (III) study group reports--technical area research priorities
Czech Academy of Sciences Publication Activity Database
Dobrev, Petre; Havlíček, Libor; Vágner, Martin; Malbeck, Jiří; Kamínek, Miroslav
2005-01-01
Roč. 1075, 1-2 (2005), s. 159-166 ISSN 0021-9673 R&D Projects: GA ČR GP522/02/D058; GA ČR GA206/02/0967; GA MŠk LN00A081; GA ČR GA522/04/0549; GA MZe QF4176 Institutional research plan: CEZ:AV0Z50380511 Keywords : Auxin * Abscisic acid * Solid phase extraction Subject RIV: EB - Genetics ; Molecular Biology Impact factor: 3.096, year: 2005
Two-dimensional static deformation of an anisotropic medium
Indian Academy of Sciences (India)
The problem of two-dimensional static deformation of a monoclinic elastic medium has been studied using the eigenvalue method, following a Fourier transform. We have obtained expressions for displacements and stresses for the medium in the transformed domain. As an application of the above theory, the particular ...
Li, Yi; Gu, Christine; Gruenhagen, Jason; Zhang, Kelly; Yehl, Peter; Chetwyn, Nik P; Medley, Colin D
2015-05-08
Antibody drug conjugates (ADCs) are complex therapeutic agents combining the specific targeting properties of antibodies and highly potent cytotoxic small molecule drugs to selectively eliminate tumor cells while limiting the toxicity to normal healthy tissues. One unique critical quality attribute of ADCs is the content of unconjugated small molecule drug present from either incomplete conjugation or degradation of the ADC. In this work, size exclusion chromatography (SEC) was coupled with reversed-phase (RP) HPLC in an online 2-dimensional chromatography format for identification and quantitation of unconjugated small molecule drugs and related small molecule impurities in ADC samples directly without sample preparation. The SEC method in the 1st dimension not only separated the small molecule impurities from the intact ADC, but also provided information about the size variants (monomer, dimer, aggregates, etc.) of the ADC. The small molecule peak from the SEC was trapped and sent to a RP-HPLC in the 2nd dimension to further separate and quantify the different small molecule impurities present in the ADC sample. This SEC-RP 2D-LC method demonstrated excellent precision (%RSDmolecule degradation products and aggregation of the conjugate were observed in the stability samples and the degradation pathways of the ADC were investigated. This 2D-LC method offers a powerful tool for ADC characterization and provides valuable information for conjugation and formulation development. Copyright © 2015 Elsevier B.V. All rights reserved.
On Two-Dimensional Quaternion Wigner-Ville Distribution
Directory of Open Access Journals (Sweden)
Mawardi Bahri
2014-01-01
Full Text Available We present the two-dimensional quaternion Wigner-Ville distribution (QWVD. The transform is constructed by substituting the Fourier transform kernel with the quaternion Fourier transform (QFT kernel in the classical Wigner-Ville distribution definition. Based on the properties of quaternions and the QFT kernel we obtain three types of the QWVD. We discuss some useful properties of various definitions for the QWVD, which are extensions of the classical Wigner-Ville distribution properties.
Two-dimensional Quantum Gravity
Rolf, Juri
1998-10-01
This Ph.D. thesis pursues two goals: The study of the geometrical structure of two-dimensional quantum gravity and in particular its fractal nature. To address these questions we review the continuum formalism of quantum gravity with special focus on the scaling properties of the theory. We discuss several concepts of fractal dimensions which characterize the extrinsic and intrinsic geometry of quantum gravity. This work is partly based on work done in collaboration with Jan Ambjørn, Dimitrij Boulatov, Jakob L. Nielsen and Yoshiyuki Watabiki (1997). The other goal is the discussion of the discretization of quantum gravity and to address the so called quantum failure of Regge calculus. We review dynamical triangulations and show that it agrees with the continuum theory in two dimensions. Then we discuss Regge calculus and prove that a continuum limit cannot be taken in a sensible way and that it does not reproduce continuum results. This work is partly based on work done in collaboration with Jan Ambjørn, Jakob L. Nielsen and George Savvidy (1997).
Phase Transformations in Cast Duplex Stainless Steels
Energy Technology Data Exchange (ETDEWEB)
Kim, Yoon-Jun [Iowa State Univ., Ames, IA (United States)
2004-01-01
Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as σ and χ can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase (σ + χ) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, σ was stabilized with increasing Cr addition and χ by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in DSS can be affected by
Phase transformations in cast duplex stainless steels
Kim, Yoon-Jun
Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as sigma (sigma) and chi (chi) can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase (sigma + chi) formation were analyzed using the Johnson-Mehl-Avrami (JMA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities, a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, a was stabilized with increasing Cr addition and chi by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in
Elementary excitations and phase transformations in solids
International Nuclear Information System (INIS)
Cowley, R.A.
1985-01-01
Neutron scattering is and will continue to be a uniquely powerful tool for the study of elementary excitations and phase transformations in solids. The paper examines a few recent experiments on molecular crystals, superionic materials, paramagnetic scattering and phase transitions to see what experimental features made these experiments possible, and hence to make suggestions about future needs. It is concluded that new instruments will extend the scope of neutron scattering studies to new excitations, that there is a need for higher resolution, particularly for phase transition studies, and that it will be important to use intensity information, discrimination against unwanted inelastic processes and polarization analysis to reliably measure the excitations in new materials. (author)
Phase transformations in Mo-doped FINEMETs
Energy Technology Data Exchange (ETDEWEB)
Silveyra, Josefina M., E-mail: jsilveyra@fi.uba.a [Lab. de Solidos Amorfos, INTECIN, FIUBA-CONICET, Paseo Colon 850, (C1063ACV) Buenos Aires (Argentina); Illekova, Emilia; Svec, Peter; Janickovic, Dusan [Institute of Physics SAS, Dubravska cesta 9, 845 11 Bratislava (Slovakia); Rosales-Rivera, Andres [Laboratorio de Magnetismo y Materiales Avanzados, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Colombia, Manizales (Colombia); Cremaschi, Victoria J. [Lab. de Solidos Amorfos, INTECIN, FIUBA-CONICET, Paseo Colon 850, (C1063ACV) Buenos Aires (Argentina)
2010-06-15
In this paper, the phase transformations occurring during the crystallization process of FINEMETs in which Nb has been gradually replaced by Mo have been studied by a variety of techniques including DSC, DTA, TGA, XRD and TEM. The thermal stability of the alloy was deteriorated as a consequence of Mo's smaller atomic size. The gradual replacement of Nb by Mo reduced the onset temperature of Fe-Si and of the borides. The Curie temperature of the amorphous phase slightly decreased from 594 K for x=0 to 587 K for x=3. The borides compounds Fe{sub 2}B and Fe{sub 23}B{sub 6} as well as the (Nb,Mo){sub 5}Si{sub 3} phase were found to precipitate in the second and third crystallization.
International Nuclear Information System (INIS)
Angerand, Francois
1987-01-01
Two-dimensional phase transitions within films physi-sorbed upon the basal face of graphite have been investigated using two experimental methods: volumetric measurements of adsorption isotherms and neutron diffraction. Our main objective was to study the role played by orientational order in these films, its influence on their thermodynamic and structural properties, and its significance in wetting and roughening phenomena, which are indirectly accessible from adsorption studies. A comparative study of the adsorption isotherms of two molecules having comparable dipole moments, NH 3 and C 2 H 3 F, discloses very dissimilar behaviours, due to the fact that hydrogen bonding is involved in the interaction between NH 3 , but not C 2 H 3 F, molecules. The impossibility of such a bond for the interaction of the adsorbate with the substrate results in a poor cohesion energy of the NH 3 ad-film in comparison with those of its bulk condensed phases. The situation is opposite for the film of C 2 H 3 F which behaves almost as a rare gas film. From multilayer adsorption isotherms of CO it is shown that graphite (0001) is perfectly wet by the plastic (orientationally disordered) crystal phase, β-CO, whereas it is incompletely wet by the low-temperature crystal phase α-CO, in which the molecules are orientationally ordered. The critical temperatures of two-dimensional condensation have been measured for the successive ad-layers, up to the fifth. They seem to converge towards a value of 65 K, which we consider as representing the temperature of the roughening transition of the (0001) face of β-CO. A neutron diffraction study of the monolayers of N 2 O and C(CD 3 ) 4 adsorbed on graphite has been carried out. For N 2 O our results suggest a structure more involved than conjectured. For C(CD 3 ) 4 we have evidence for a triple point at 178 K. The crystal monolayer has a compact hexagonal structure. (author) [fr
Lee, M.; Hwang, J.; Choi, E. S.; Ma, J.; Dela Cruz, C. R.; Zhu, M.; Ke, X.; Dun, Z. L.; Zhou, H. D.
2014-03-01
We have measured magnetic, dielectric and thermodynamic properties of quasi-two-dimensional triangular lattice antiferromagnet (TLAF), Ba3CoNb2O9 (S = 1/2) and Ba3MnNb2O9 (S = 3/2). At zero magnetic field, Ba3CoNb2O9 undergoes a two-step transition at 1.36 K and 1.10 K and enters a 120 degree ordered state. By applying magnetic fields, a series of magnetic phases with fractional saturation magnetization (1/3, 1/2, 2/3 (or √{ 3}/3Ms) are observed. The collinear spin phase with 1/3 Ms becomes more robust at lower temperatures due to quantum fluctuations. For Ba3MnNb2O9, the 120 degree ordered state is stabilized below 3.10 K at zero field. Under the magnetic field, successive magnetic phase transitions are observed with fractional magnetization 1/3 and 1/2 Ms. The 1/3 Ms phase becomes more stable at higher temperatures due to thermal fluctuations. The ferroelectricity emerges in all spin states in both compounds regardless of the spin chirality. Therefore, Ba3CoNb2O9andBa3MnNb2O9 are unique TLAFs exhibiting not only a series of magnetic phase transitions but also multiferroicity. NHMFL is supported by NSF, the State of Florida and US DOE. ORNL HFIR was sponsored by U.S. DOE.
Matamoros, Víctor; Jover, Eric; Bayona, Josep M
2010-01-15
An analytical procedure based on comprehensive two-dimensional gas chromatography (GC x GC) coupled with time-of-flight mass spectrometry (TOF-MS) for the simultaneous determination of 97 organic contaminants at trace concentration in river water is presented. The target analytes included 13 pharmaceuticals, 18 plasticizers, 8 personal care products, 9 acid herbicides, 8 triazines, 10 organophosphorous compounds, 5 phenylureas, 12 organochlorine biocides, 9 polycyclic aromatic hydrocarbons (PAHs), and 5 benzothiazoles and benzotriazoles. The best resolution of the target analytes in the contour plots was obtained when a nonpolar stationary phase was used in the first dimension and polar one in the second. However, in the opposite configuration, polar-nonpolar, the retention time in the second dimension exhibited a strong correlation with the log Kow (p identification criteria. The developed methodology is based on a polymeric solid-phase extraction followed by in GC-port methylation and GC x GC/TOF-MS determination. Moreover, limits of detection (LODs) and quantification (LOQs) ranged from 0.5 to 100 ng/L and from 2 to 185 ng/L, respectively. Repeatability was always lower than 20%. Finally, the developed method has been successfully applied to the determination of incurred target analytes in four river waters subjected to a different anthropogenic pressure.
Two-dimensional generalized harmonic oscillators and their Darboux partners
International Nuclear Information System (INIS)
Schulze-Halberg, Axel
2011-01-01
We construct two-dimensional Darboux partners of the shifted harmonic oscillator potential and of an isotonic oscillator potential belonging to the Smorodinsky–Winternitz class of superintegrable systems. The transformed solutions, their potentials and the corresponding discrete energy spectra are computed in explicit form. (paper)
Two-dimensional topological photonic systems
Sun, Xiao-Chen; He, Cheng; Liu, Xiao-Ping; Lu, Ming-Hui; Zhu, Shi-Ning; Chen, Yan-Feng
2017-09-01
The topological phase of matter, originally proposed and first demonstrated in fermionic electronic systems, has drawn considerable research attention in the past decades due to its robust transport of edge states and its potential with respect to future quantum information, communication, and computation. Recently, searching for such a unique material phase in bosonic systems has become a hot research topic worldwide. So far, many bosonic topological models and methods for realizing them have been discovered in photonic systems, acoustic systems, mechanical systems, etc. These discoveries have certainly yielded vast opportunities in designing material phases and related properties in the topological domain. In this review, we first focus on some of the representative photonic topological models and employ the underlying Dirac model to analyze the edge states and geometric phase. On the basis of these models, three common types of two-dimensional topological photonic systems are discussed: 1) photonic quantum Hall effect with broken time-reversal symmetry; 2) photonic topological insulator and the associated pseudo-time-reversal symmetry-protected mechanism; 3) time/space periodically modulated photonic Floquet topological insulator. Finally, we provide a summary and extension of this emerging field, including a brief introduction to the Weyl point in three-dimensional systems.
Pressure Induced Phase Transformations in Ceramics
Energy Technology Data Exchange (ETDEWEB)
Reimanis, Ivar [Colorado School of Mines, Golden, CO (United States); Cioabanu, Cristian [Colorado School of Mines, Golden, CO (United States)
2017-10-15
The study of materials with unusual properties offers new insight into structure-property relations as well as promise for the design of novel composites. In this spirit, the PIs seek to (1) understand fundamental mechanical phenomena in ceramics that exhibit pressure-induced phase transitions, negative coefficient of thermal expansion (CTE), and negative compressibility, and (2) explore the effect of these phenomena on the mechanical behavior of composites designed with such ceramics. The broad and long-term goal is to learn how to utilize these unusual behaviors to obtain desired mechanical responses. While the results are expected to be widely applicable to many ceramics, most of the present focus is on silicates, as they exhibit remarkable diversity in structure and properties. Eucryptite, a lithium aluminum silicate (LiAlSiO_{4}), is specifically targeted because it exhibits a pressure-induced phase transition at a sufficiently low pressure to be accessible during conventional materials processing. Thus, composites with eucryptite may be designed to exhibit a novel type of transformation toughening. The PIs have performed a combination of activities that encompass synthesis and processing to control structures, atomistic modeling to predict and understand structures, and characterization to study mechanical behavior. Several materials behavior discoveries were made. It was discovered that small amounts of Zn (as small as 0.1 percent by mol) reverse the sign of the coefficient of thermal expansion of beta-eucryptite from negative to slightly positive. The presence of Zn also significantly mitigates microcracking that occurs during thermal cycling of eucryptite. It is hypothesized that Zn disrupts the Li ordering in beta-eucryptite, thereby altering the thermal expansion behavior. A nanoindentation technique developed to characterize incipient plasticity was applied to examine the initial stages of the pressure induced phase transformation from beta to
Critical Behaviour of a Two-Dimensional Random Antiferromagnet
DEFF Research Database (Denmark)
Als-Nielsen, Jens Aage; Birgeneau, R. J.; Guggenheim, H. J.
1976-01-01
A neutron scattering study of the order parameter, correlation length and staggered susceptibility of the two-dimensional random antiferromagnet Rb2Mn0.5Ni0.5F4 is reported. The system is found to exhibit a well-defined phase transition with critical exponents identical to those of the isomorphous...... pure materials K2NiF4 and K2MnF4. Thus, in these systems, which have the asymptotic critical behaviour of the two-dimensional Ising model, randomness has no measurable effect on the phase-transition behaviour....
Chiral anomaly, fermionic determinant and two dimensional models
International Nuclear Information System (INIS)
Rego Monteiro, M.A. do.
1985-01-01
The chiral anomaly in random pair dimension is analysed. This anomaly is perturbatively calculated by dimensional regularization method. A new method for non-perturbative Jacobian calculation of a general chiral transformation, 1.e., finite and non-Abelian, is developed. This method is used for non-perturbative chiral anomaly calculation, as an alternative to bosonization of two-dimensional theories for massless fermions and to study the phenomenum of fermion number fractionalization. The fermionic determinant from two-dimensional quantum chromodynamics is also studied, and calculated, exactly, as in decoupling gauge as with out reference to a particular gauge. (M.C.K.) [pt
International Nuclear Information System (INIS)
Terlain, Anne
1984-01-01
The 2D (two-dimensional) phase transitions and orientational order in N 2 O, CO 2 , C 2 N 2 and C 2 D 2 films physi-sorbed on the (0001) face of graphite or lamellar halides, were studied experimentally by adsorption isotherm measurements and neutron diffraction. The thermodynamic functions derived from sets of isotherms suggest that crystal monolayers of N 2 O, CO 2 , and C 2 N 2 adsorbed on graphite are orientationally ordered and that the quadrupolar interaction stabilizes the 2D crystal with respect to the 2D liquid. This stabilization leads to an increase in the 2D triple point temperature, T 2t as compared with the 2D critical temperature T 2c . For C 2 N 2 this stabilization is so pronounced that T 2t becomes virtually higher than T 2c , and the phase diagram qualitatively different, having no gas-liquid coexistence domain. From a neutron diffraction experiment we have determined the crystal structure of the C 2 N 2 monolayer. It supports our interpretation of the monolayer phase diagram. In N 2 O, CO 2 , C 2 N 2 films adsorbed on graphite the molecules lie flat on the surface and their orientational order hence differs from that in the bulk crystals resulting in a loss of adsorbate-adsorbate interaction energy. Beyond a given film thickness this loss will not be compensated by the adsorbate-substrate interaction and the film will stop growing. For most of the films studied a partial wetting transition is observed at which the film thickness increases discontinuously with temperature. Although C 2 N 2 and C 2 D 2 monolayers on graphite have comparable adsorption energies, only C 2 D 2 is adsorbed on lamellar halides. This adsorption is possible only because the monolayer has a large entropy due to orientational disorder. For C 2 N 2 , which has a higher moment of inertia, such an orientational disorder cannot exist. (author) [fr
Taha, Doaa; Mkhonta, S. K.; Elder, K. R.; Huang, Zhi-Feng
2017-06-01
Understanding and controlling the properties and dynamics of topological defects is a lasting challenge in the study of two-dimensional materials, and is crucial to achieve high-quality films required for technological applications. Here grain boundary structures, energies, and dynamics of binary two-dimensional materials are investigated through the development of a phase field crystal model that is parametrized to match the ordering, symmetry, energy, and length scales of hexagonal boron nitride. Our studies reveal some new dislocation core structures for various symmetrically and asymmetrically tilted grain boundaries, in addition to those obtained in previous experiments and first-principles calculations. We also identify a defect-mediated growth dynamics for inversion domains governed by the collective atomic migration and defect core transformation at grain boundaries and junctions, a process that is related to inversion symmetry breaking in binary lattice.
Perestrelo, Rosa; Petronilho, Sílvia; Câmara, José S; Rocha, Sílvia M
2010-05-14
An analytical methodology based on headspace solid phase microextraction (HS-SPME) combined with comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry (GC x GC-ToFMS) was developed for the identification and quantification of the toxic contaminant ethyl carbamate (EC) directly in fortified wines. The method performance was assessed for dry/medium dry and sweet/medium sweet model wines, and for quantification purposes, calibration plots were performed for both matrices using the ion extraction chromatography (IEC) mode (m/z 62). Good linearity was obtained with a regression coefficient (r(2)) higher than 0.981. A good precision was attained (R.S.D. wines. The quantification limits (LOQ) and recovery for dry wines were 14.38 microg/L and 88.6%, whereas for sweet wines were 9.16 microg/L and 99.4%, respectively. The higher performance was attained with sweet model wine, as increasing of glucose content improves the volatile compound in headspace, and a better linearity, recovery and precision were achieved. The analytical methodology was applied to analyse 20 fortified Madeira wines including different types of wine (dry, medium dry, sweet, and medium sweet) obtained from several harvests in Madeira Island (Portugal). The EC levels ranged from 54.1 microg/L (medium dry) to 162.5 microg/L (medium sweet). 2010 Elsevier B.V. All rights reserved.
García-Gómez, Diego; Rodríguez-Gonzalo, Encarnación; Carabias-Martínez, Rita
2015-08-01
In the present work we describe a two-dimensional liquid chromatographic system (2D-LC) with detection by mass spectrometry (MS) for the simultaneous separation of endogenous metabolites of clinical interest and excreted xenobiotics deriving from exposure to toxic compounds. The 2D-LC system involves two orthogonal chromatographic modes, hydrophilic interaction liquid chromatography (HILIC) to separate polar endogenous metabolites and reversed-phase (RP) chromatography to separate excreted xenobiotics of low and intermediate polarity. Additionally, the present proposal has the novelty of incorporating an on-line sample treatment based on the use of restricted access materials (RAMs), which permits the direct injection of urine samples into the system. The work is focused on the instrumental coupling, studying all possible options and attempting to circumvent the problems of solvent incompatibility between the RAM device and the two chromatographic columns, HILIC and RP. The instrumental configuration developed, RAM-HILIC-RPLC-MS/MS, allows the simultaneous assessment of urinary metabolites of clinical interest and excreted compounds derived from exposure to toxic agents with minimal sample manipulation. Thus, it may be of interest in areas such as occupational and environmental toxicology in order to explore the possible relationship between the two types of compounds. Copyright © 2015 John Wiley & Sons, Ltd.
Montero, Lidia; Ibáñez, Elena; Russo, Mariateresa; Rastrelli, Luca; Cifuentes, Alejandro; Herrero, Miguel
2017-09-08
Comprehensive two-dimensional liquid chromatography (LC × LC) is ever gaining interest in food analysis, as often, food-related samples are too complex to be analyzed through one-dimensional approaches. The use of hydrophilic interaction chromatography (HILIC) combined with reversed phase (RP) separations has already been demonstrated as a very orthogonal combination, which allows attaining increased resolving power. However, this coupling encompasses different analytical challenges, mainly related to the important solvent strength mismatch between the two dimensions, besides those common to every LC × LC method. In the present contribution, different strategies are proposed and compared to further increase HILIC × RP method performance for the analysis of complex food samples, using licorice as a model sample. The influence of different parameters in non-focusing modulation methods based on sampling loops, as well as under focusing modulation, through the use of trapping columns in the interface and through active modulation procedures are studied in order to produce resolving power and sensitivity gains. Although the use of a dilution strategy using sampling loops as well as the highest possible first dimension sampling rate allowed significant improvements on resolution, focusing modulation produced significant gains also in peak capacity and sensitivity. Overall, the obtained results demonstrate the great applicability and potential that active modulation may have for the analysis of complex food samples, such as licorice, by HILIC × RP. Copyright © 2017 Elsevier B.V. All rights reserved.
Design and Implementation of GSM Based Transformer Phase ...
African Journals Online (AJOL)
In this work, the design and implementation of a transformer phase monitoring system, which continuously check for blown fuses on each phases of the distribution transformer was carried out. The system promptly reports any transformer with blown J&P fuse via a preprogrammed SMS which will state the location of the ...
Topology optimization of two-dimensional waveguides
DEFF Research Database (Denmark)
Jensen, Jakob Søndergaard; Sigmund, Ole
2003-01-01
In this work we use the method of topology optimization to design two-dimensional waveguides with low transmission loss.......In this work we use the method of topology optimization to design two-dimensional waveguides with low transmission loss....
Phase transformations in neutron-irradiated Zircaloys
International Nuclear Information System (INIS)
Chung, H.M.
1986-04-01
Microstructural evolution in Zircaloy-2 and -4 spent-fuel cladding specimens after ∼3 years of irradiation in commercial power reactors has been investigated by TEM and HVEM. Two kinds of precipitates induced by the fast-neutron irradiation in the reactors have been identified, i.e., Zr 3 O and cubic-ZrO 2 particles approximately 2 to 10 nm in size. By means of a weak-beam dark-field ''2-1/2D-microscopy'' technique, the bulk nature of the precipitates and the surficial nature of artifact oxide and hydride phases could be discerned. The Zr(Fe/sub x/,Cr/sub 1-x/) 2 and Zr 2 (Fe/sub x/,Ni/sub 1-x/) intermetallic precipitates normally present in the as-fabricated material virtually dissolved in the spent-fuel cladding specimens after a fast-neutron fluence of ∼4 x 10 21 ncm -2 in the power reactors. The observed radiation-induced phase transformations are compared with predictions based on the currently available understanding of the alloy characteristics. 29 refs
Longitudinal and transverse modes dispersion in two-dimensional ...
African Journals Online (AJOL)
The dynamical properties of two-dimensional Yukawa fluids in the domain of weak and intermediate coupling parameters were analyzed through molecular dynamics (MD) simulation. The dispersion relation for both the longitudinal and transverse modes were obtained and compared with random phase approximation ...
Conformal QED in two-dimensional topological insulators
Menezes Silva Da Costa, Natália; Palumbo, Giandomenico; de Morais Smith, Cristiane
2017-01-01
It has been shown recently that local four-fermion interactions on the edges of two-dimensional time-reversal-invariant topological insulators give rise to a new non-Fermi-liquid phase, called helical Luttinger liquid (HLL). In this work, we provide a first-principle derivation of this
Complex dynamical invariants for two-dimensional complex potentials
Indian Academy of Sciences (India)
Abstract. Complex dynamical invariants are searched out for two-dimensional complex poten- tials using rationalization method within the framework of an extended complex phase space characterized by x = x1 + ip3, y = x2 + ip4, px = p1 + ix3, py = p2 + ix4. It is found that the cubic oscillator and shifted harmonic oscillator ...
Research on coordinate transformation of the three-phase circuit
Tian Ming Xing; yan hong; Yuan Dong Sheng
2013-01-01
The different three-phase circuit coordinate transformation matrixes are given in relevant literatures , which may cause some difficulties to understand and apply the coordinate transformation. The paper presents a general expression of the coordinate transformation matrixes in three-phase circuit and points out that the coordinate transformation matrixes having different specific expressions are due to existing the parameters which can be selected in the general expression. On this basis, th...
Quantum melting of a two-dimensional Wigner crystal
Dolgopolov, V. T.
2017-10-01
The paper reviews theoretical predictions about the behavior of two-dimensional low-density electron systems at nearly absolute zero temperatures, including the formation of an electron (Wigner) crystal, crystal melting at a critical electron density, and transitions between crystal modifications in more complex (for example, two-layer) systems. The paper presents experimental results obtained from real two-dimensional systems in which the nonconducting (solid) state of the electronic system with indications of collective localization is actually realized. Experimental methods for detecting a quantum liquid–solid phase interface are discussed.
An optical Fourier transform coprocessor with direct phase determination.
Macfaden, Alexander J; Gordon, George S D; Wilkinson, Timothy D
2017-10-20
The Fourier transform is a ubiquitous mathematical operation which arises naturally in optics. We propose and demonstrate a practical method to optically evaluate a complex-to-complex discrete Fourier transform. By implementing the Fourier transform optically we can overcome the limiting O(nlogn) complexity of fast Fourier transform algorithms. Efficiently extracting the phase from the well-known optical Fourier transform is challenging. By appropriately decomposing the input and exploiting symmetries of the Fourier transform we are able to determine the phase directly from straightforward intensity measurements, creating an optical Fourier transform with O(n) apparent complexity. Performing larger optical Fourier transforms requires higher resolution spatial light modulators, but the execution time remains unchanged. This method could unlock the potential of the optical Fourier transform to permit 2D complex-to-complex discrete Fourier transforms with a performance that is currently untenable, with applications across information processing and computational physics.
Two dimensional convolute integers for machine vision and image recognition
Edwards, Thomas R.
1988-01-01
Machine vision and image recognition require sophisticated image processing prior to the application of Artificial Intelligence. Two Dimensional Convolute Integer Technology is an innovative mathematical approach for addressing machine vision and image recognition. This new technology generates a family of digital operators for addressing optical images and related two dimensional data sets. The operators are regression generated, integer valued, zero phase shifting, convoluting, frequency sensitive, two dimensional low pass, high pass and band pass filters that are mathematically equivalent to surface fitted partial derivatives. These operators are applied non-recursively either as classical convolutions (replacement point values), interstitial point generators (bandwidth broadening or resolution enhancement), or as missing value calculators (compensation for dead array element values). These operators show frequency sensitive feature selection scale invariant properties. Such tasks as boundary/edge enhancement and noise or small size pixel disturbance removal can readily be accomplished. For feature selection tight band pass operators are essential. Results from test cases are given.
Low-temperature phase transformation in rubidium and cesium superoxides
International Nuclear Information System (INIS)
Alikhanov, R.A.; Toshich, B.S.; Smirnov, L.S.
1980-01-01
Crystal structures of rubidium and cesium superoxides which are two interpenetrating lattices of metal ions and oxygen molecule ions reveal a number of phase transformations with temperature decrease. Crystal-phase transformations in CsO 2 are 1-2, 2-3 and low temperature one 3-4 at 378, 190 and 10 K. Low temperature transition is considered as the instability of lattice quadrupoles of oxygen molecule ions to phase transformation of the order-disorder type. Calculated temperatures of low temperature phase transformations in PbO 2 and CsO 2 agree with experimental calculations satisfactory [ru
Energy Technology Data Exchange (ETDEWEB)
Yoon, Jeong Hee; Lee, Jeong Min; Han, Joon Koo [Dept. of Radiology, Seoul National University Hospital, Seoul (Korea, Republic of); Yu, Mi Hye [Dept. of Radiology, Konkuk University Medical Center, Seoul (Korea, Republic of); Kim, Eun Ju [Philips Healthcare Korea, Seoul (Korea, Republic of)
2016-07-15
To determine whether triple arterial phase acquisition via a combination of Contrast Enhanced Time Robust Angiography, keyhole, temporal viewsharing and parallel imaging can improve arterial phase acquisition with higher spatial resolution than single arterial phase gadoxetic-acid enhanced magnetic resonance imaging (MRI). Informed consent was waived for this retrospective study by our Institutional Review Board. In 752 consecutive patients who underwent gadoxetic acid-enhanced liver MRI, either single (n = 587) or triple (n = 165) arterial phases was obtained in a single breath-hold under MR fluoroscopy guidance. Arterial phase timing was assessed, and the degree of motion was rated on a four-point scale. The percentage of patients achieving the late arterial phase without significant motion was compared between the two methods using the χ2 test. The late arterial phase was captured at least once in 96.4% (159/165) of the triple arterial phase group and in 84.2% (494/587) of the single arterial phase group (p < 0.001). Significant motion artifacts (score ≤ 2) were observed in 13.3% (22/165), 1.2% (2/165), 4.8% (8/165) on 1st, 2nd, and 3rd scans of triple arterial phase acquisitions and 6.0% (35/587) of single phase acquisitions. Thus, the late arterial phase without significant motion artifacts was captured in 96.4% (159/165) of the triple arterial phase group and in 79.9% (469/587) of the single arterial phase group (p < 0.001). Triple arterial phase imaging may reliably provide adequate arterial phase imaging for gadoxetic acid-enhanced liver MRI.
Energy Technology Data Exchange (ETDEWEB)
Yoon, Jeong Hee [Department of Radiology, Seoul National University Hospital, Seoul 03080 (Korea, Republic of); Department of Radiology, Seoul National University College of Medicine, Seoul 03087 (Korea, Republic of); Lee, Jeong Min [Department of Radiology, Seoul National University Hospital, Seoul 03080 (Korea, Republic of); Department of Radiology, Seoul National University College of Medicine, Seoul 03087 (Korea, Republic of); Institute of Radiation Medicine, Seoul National University Medical Research Center, Seoul 03087 (Korea, Republic of); Yu, Mi Hye [Department of Radiology, Konkuk University Medical Center, Seoul 05030 (Korea, Republic of); Kim, Eun Ju [Philips Healthcare Korea, Seoul 04342 (Korea, Republic of); Han, Joon Koo [Department of Radiology, Seoul National University Hospital, Seoul 03080 (Korea, Republic of); Department of Radiology, Seoul National University College of Medicine, Seoul 03087 (Korea, Republic of); Institute of Radiation Medicine, Seoul National University Medical Research Center, Seoul 03087 (Korea, Republic of)
2016-11-01
To determine whether triple arterial phase acquisition via a combination of Contrast Enhanced Time Robust Angiography, keyhole, temporal viewsharing and parallel imaging can improve arterial phase acquisition with higher spatial resolution than single arterial phase gadoxetic-acid enhanced magnetic resonance imaging (MRI). Informed consent was waived for this retrospective study by our Institutional Review Board. In 752 consecutive patients who underwent gadoxetic acid-enhanced liver MRI, either single (n = 587) or triple (n = 165) arterial phases was obtained in a single breath-hold under MR fluoroscopy guidance. Arterial phase timing was assessed, and the degree of motion was rated on a four-point scale. The percentage of patients achieving the late arterial phase without significant motion was compared between the two methods using the χ{sup 2} test. The late arterial phase was captured at least once in 96.4% (159/165) of the triple arterial phase group and in 84.2% (494/587) of the single arterial phase group (p < 0.001). Significant motion artifacts (score ≤ 2) were observed in 13.3% (22/165), 1.2% (2/165), 4.8% (8/165) on 1st, 2nd, and 3rd scans of triple arterial phase acquisitions and 6.0% (35/587) of single phase acquisitions. Thus, the late arterial phase without significant motion artifacts was captured in 96.4% (159/165) of the triple arterial phase group and in 79.9% (469/587) of the single arterial phase group (p < 0.001). Triple arterial phase imaging may reliably provide adequate arterial phase imaging for gadoxetic acid-enhanced liver MRI.
Development of Two-Dimensional NMR
Indian Academy of Sciences (India)
Home; Journals; Resonance – Journal of Science Education; Volume 20; Issue 11. Development of Two-Dimensional NMR: Strucure Determination of Biomolecules in Solution. Anil Kumar. General Article Volume 20 Issue 11 November 2015 pp 995-1002 ...
Conoscopic holography: two-dimensional numerical reconstructions.
Mugnier, L M; Sirat, G Y; Charlot, D
1993-01-01
Conoscopic holography is an incoherent light holographic technique based on the properties of crystal optics. We present experimental results of the numerical reconstruction of a two-dimensional object from its conoscopic hologram.
Error compensation of IQ modulator using two-dimensional DFT
Ohshima, Takashi; Maesaka, Hirokazu; Matsubara, Shinichi; Otake, Yuji
2016-06-01
It is important to precisely set and keep the phase and amplitude of an rf signal in the accelerating cavity of modern accelerators, such as an X-ray Free Electron Laser (XFEL) linac. In these accelerators an acceleration rf signal is generated or detected by an In-phase and Quadrature (IQ) modulator, or a demodulator. If there are any deviations of the phase and the amplitude from the ideal values, crosstalk between the phase and the amplitude of the output signal of the IQ modulator or the demodulator arises. This causes instability of the feedback controls that simultaneously stabilize both the rf phase and the amplitude. To compensate for such deviations, we developed a novel compensation method using a two-dimensional Discrete Fourier Transform (DFT). Because the observed deviations of the phase and amplitude of an IQ modulator involve sinusoidal and polynomial behaviors on the phase angle and the amplitude of the rf vector, respectively, the DFT calculation with these basis functions makes a good approximation with a small number of compensation coefficients. Also, we can suppress high-frequency noise components arising when we measure the deviation data. These characteristics have advantages compared to a Look Up Table (LUT) compensation method. The LUT method usually demands many compensation elements, such as about 300, that are not easy to treat. We applied the DFT compensation method to the output rf signal of a C-band IQ modulator at SACLA, which is an XFEL facility in Japan. The amplitude deviation of the IQ modulator after the DFT compensation was reduced from 15.0% at the peak to less than 0.2% at the peak for an amplitude control range of from 0.1 V to 0.9 V (1.0 V full scale) and for a phase control range from 0 degree to 360 degrees. The number of compensation coefficients is 60, which is smaller than that of the LUT method, and is easy to treat and maintain.
Pseudospectral reduction of incompressible two-dimensional turbulence
Bowman, John C.; Roberts, Malcolm
2012-05-01
Spectral reduction was originally formulated entirely in the wavenumber domain as a coarse-grained wavenumber convolution in which bins of modes interact with enhanced coupling coefficients. A Liouville theorem leads to inviscid equipartition solutions when each bin contains the same number of modes. A pseudospectral implementation of spectral reduction which enjoys the efficiency of the fast Fourier transform is described. The model compares well with full pseudospectral simulations of the two-dimensional forced-dissipative energy and enstrophy cascades.
Weldegergis, B.T.; Crouch, A.M.; Górecki, T.; Villiers, de A.
2011-01-01
Comprehensive two-dimensional gas chromatography in combination with time-of-flight mass spectrometry (GC × GC–TOFMS) has been applied for the analysis of volatile compounds in three young South African red wines. In spite of the significant benefits offered by GC × GC–TOFMS for the separation and
Application of CRAFT in two-dimensional NMR data processing.
Krishnamurthy, Krish; Sefler, Andrea M; Russell, David J
2017-03-01
Two-dimensional (2D) data are typically truncated in both dimensions, but invariably and severely so in the indirect dimension. These truncated FIDs and/or interferograms are extensively zero filled, and Fourier transformation of such zero-filled data is always preceded by a rapidly decaying apodization function. Hence, the frequency line width in the spectrum (at least parallel to the evolution dimension) is almost always dominated by the apodization function. Such apodization-driven line broadening in the indirect (t 1 ) dimension leads to the lack of clear resolution of cross peaks in the 2D spectrum. Time-domain analysis (i.e. extraction of frequency, amplitudes, line width, and phase parameters directly from the FID, in this case via Bayesian modeling into a tabular format) of NMR data is another approach for spectral resonance characterization and quantification. The recently published complete reduction to amplitude frequency table (CRAFT) technique converts the raw FID data (i.e. time-domain data) into a table of frequencies, amplitudes, decay rate constants, and phases. CRAFT analyses of time-domain data require minimal or no apodization prior to extraction of the four parameters. We used the CRAFT processing approach for the decimation of the interferograms and compared the results from a variety of 2D spectra against conventional processing with and without linear prediction. The results show that use of the CRAFT technique to decimate the t 1 interferograms yields much narrower spectral line width of the resonances, circumventing the loss of resolution due to apodization. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.
Phase and structural transformations in magnetorheological suspensions
Iskakova, L. Yu.; Romanchuk, A. P.; Zubarev, A. Yu.
2006-07-01
Particle condensation in magnetorheological suspensions (MRS) under external magnetic field is studied theoretically. It is shown that the bulk condensation of particles into dense phases is preceded by the formation of fairly long chain aggregates. Phase transition occurs as a condensation of such chains due to their magnetic interaction. In thin layers of MRS, placed into the normal magnetic field, scenario of the phase transition differs essentially from that in infinite volumes of these systems. Equilibrium state of the system after the phase transition corresponds to the formation of ensemble of discrete domains of the dense phase rather than to separation into two massive phases as it takes place in infinite media.
TWO-DIMENSIONAL TOPOLOGY OF COSMOLOGICAL REIONIZATION
International Nuclear Information System (INIS)
Wang, Yougang; Xu, Yidong; Chen, Xuelei; Park, Changbom; Kim, Juhan
2015-01-01
We study the two-dimensional topology of the 21-cm differential brightness temperature for two hydrodynamic radiative transfer simulations and two semi-numerical models. In each model, we calculate the two-dimensional genus curve for the early, middle, and late epochs of reionization. It is found that the genus curve depends strongly on the ionized fraction of hydrogen in each model. The genus curves are significantly different for different reionization scenarios even when the ionized faction is the same. We find that the two-dimensional topology analysis method is a useful tool to constrain the reionization models. Our method can be applied to the future observations such as those of the Square Kilometre Array
Dirac cones in two-dimensional borane
Martinez-Canales, Miguel; Galeev, Timur R.; Boldyrev, Alexander I.; Pickard, Chris J.
2017-11-01
We introduce two-dimensional borane, a single-layered material of BH stoichiometry, with promising electronic properties. We show that, according to density functional theory calculations, two-dimensional borane is semimetallic, with two symmetry-related Dirac cones meeting right at the Fermi energy Ef. The curvature of the cones is lower than in graphene, thus closer to the ideal linear dispersion. Its structure, formed by a puckered trigonal boron network with hydrogen atoms connected to each boron atom, can be understood as distorted, hydrogenated borophene [Mannix et al., Science 350, 1513 (2015), 10.1126/science.aad1080]. Chemical bonding analysis reveals the boron layer in the network being bound by delocalized four-center two-electron σ bonds. Finally, we suggest high pressure could be a feasible route to synthesize two-dimensional borane.
Electromagnetically induced two-dimensional grating assisted by incoherent pump
Energy Technology Data Exchange (ETDEWEB)
Chen, Yu-Yuan; Liu, Zhuan-Zhuan; Wan, Ren-Gang, E-mail: wrg@snnu.edu.cn
2017-04-25
We propose a scheme for realizing electromagnetically induced two-dimensional grating in a double-Λ system driven simultaneously by a coherent field and an incoherent pump field. In such an atomic configuration, the absorption is suppressed owing to the incoherent pumping process and the probe can be even amplified, while the refractivity is mainly attributed to the dynamically induced coherence. With the help of a standing-wave pattern coherent field, we obtain periodically modulated refractive index without or with gain, and therefore phase grating or gain-phase grating which diffracts a probe light into high-order direction efficiently can be formed in the medium via appropriate manipulation of the system parameters. The diffraction efficiency attainable by the present gratings can be controlled by tuning the coherent field intensity or the interaction length. Hence, the two-dimensional grating can be utilized as all-optical splitter or router in optical networking and communication. - Highlights: • Two-dimensional grating is coherently induced in four-level atoms. • Phase and gain-phase gratings are obtained assisted by incoherent pump. • The diffraction power is improved due to the enhanced refraction modulation. • The gratings can be utilized as multi-channel all-optical splitter and router.
Shear-driven phase transformation in silicon nanowires
Vincent, L.; Djomani, D.; Fakfakh, M.; Renard, C.; Belier, B.; Bouchier, D.; Patriarche, G.
2018-03-01
We report on an unprecedented formation of allotrope heterostructured Si nanowires by plastic deformation based on applied radial compressive stresses inside a surrounding matrix. Si nanowires with a standard diamond structure (3C) undergo a phase transformation toward the hexagonal 2H-allotrope. The transformation is thermally activated above 500 °C and is clearly driven by a shear–stress relief occurring in parallel shear bands lying on {115} planes. We have studied the influence of temperature and axial orientation of nanowires. The observations are consistent with a martensitic phase transformation, but the finding leads to clear evidence of a different mechanism of deformation-induced phase transformation in Si nanowires with respect to their bulk counterpart. Our process provides a route to study shear-driven phase transformation at the nanoscale in Si.
Two-dimensional vibrational-electronic spectroscopy
Courtney, Trevor L.; Fox, Zachary W.; Slenkamp, Karla M.; Khalil, Munira
2015-10-01
Two-dimensional vibrational-electronic (2D VE) spectroscopy is a femtosecond Fourier transform (FT) third-order nonlinear technique that creates a link between existing 2D FT spectroscopies in the vibrational and electronic regions of the spectrum. 2D VE spectroscopy enables a direct measurement of infrared (IR) and electronic dipole moment cross terms by utilizing mid-IR pump and optical probe fields that are resonant with vibrational and electronic transitions, respectively, in a sample of interest. We detail this newly developed 2D VE spectroscopy experiment and outline the information contained in a 2D VE spectrum. We then use this technique and its single-pump counterpart (1D VE) to probe the vibrational-electronic couplings between high frequency cyanide stretching vibrations (νCN) and either a ligand-to-metal charge transfer transition ([FeIII(CN)6]3- dissolved in formamide) or a metal-to-metal charge transfer (MMCT) transition ([(CN)5FeIICNRuIII(NH3)5]- dissolved in formamide). The 2D VE spectra of both molecules reveal peaks resulting from coupled high- and low-frequency vibrational modes to the charge transfer transition. The time-evolving amplitudes and positions of the peaks in the 2D VE spectra report on coherent and incoherent vibrational energy transfer dynamics among the coupled vibrational modes and the charge transfer transition. The selectivity of 2D VE spectroscopy to vibronic processes is evidenced from the selective coupling of specific νCN modes to the MMCT transition in the mixed valence complex. The lineshapes in 2D VE spectra report on the correlation of the frequency fluctuations between the coupled vibrational and electronic frequencies in the mixed valence complex which has a time scale of 1 ps. The details and results of this study confirm the versatility of 2D VE spectroscopy and its applicability to probe how vibrations modulate charge and energy transfer in a wide range of complex molecular, material, and biological systems.
Explorative data analysis of two-dimensional electrophoresis gels
DEFF Research Database (Denmark)
Schultz, J.; Gottlieb, D.M.; Petersen, Marianne Kjerstine
2004-01-01
Methods for classification of two-dimensional (2-DE) electrophoresis gels based on multivariate data analysis are demonstrated. Two-dimensional gels of ten wheat varieties are analyzed and it is demonstrated how to classify the wheat varieties in two qualities and a method for initial screening...... of gels is presented. First, an approach is demonstrated in which no prior knowledge of the separated proteins is used. Alignment of the gels followed by a simple transformation of data makes it possible to analyze the gels in an automated explorative manner by principal component analysis, to determine...... if the gels should be further analyzed. A more detailed approach is done by analyzing spot volume lists by principal components analysis and partial least square regression. The use of spot volume data offers a mean to investigate the spot pattern and link the classified protein patterns to distinct spots...
Spontaneous spiral formation in two-dimensional oscillatory media
Kettunen, Petteri; Amemiya, Takashi; Ohmori, Takao; Yamaguchi, Tomohiko
1999-08-01
Computational studies of pattern formation in a modified Oregonator model of the Belousov-Zhabotinsky reaction is described. Initially inactive two-dimensional reaction media with an immobilized catalyst is connected to a reservoir of fresh reactants through a set of discrete points distributed randomly over the interphase surface. It is shown that the diffusion of reactants combined with oscillatory reaction kinetics can give rise to spontaneous spiral formation and phase waves.
Mechanisms of diffusional phase transformations in metals and alloys
Aaronson, Hubert I; Lee, Jong K
2010-01-01
Developed by the late metallurgy professor and master experimentalist Hubert I. Aaronson, this collection of lecture notes details the fundamental principles of phase transformations in metals and alloys upon which steel and other metals industries are based. Mechanisms of Diffusional Phase Transformations in Metals and Alloys is devoted to solid-solid phase transformations in which elementary atomic processes are diffusional jumps, and these processes occur in a series of so-called nucleation and growth through interface migration. Instead of relying strictly on a pedagogical approach, it doc
Reflectance changes during shock-induced phase transformations in metals.
Stevens, G D; Turley, W D; Veeser, L R; Jensen, B J; Rigg, P A
2010-06-01
In performing shock wave experiments to study the characteristics of metals at high pressures, wave profiles (i.e., velocity measurements of the surface of the sample) are an established and useful way to study phase transformations. For example, a sudden change in the velocity or its slope can occur when the phase transformation induces a large volume change leading to a change in particle velocity. Allowing the shock to release into a transparent window that is in contact with the sample surface allows the study of conditions away from the shock Hugoniot. However, in cases where the wave profile is not definitive, an additional phase-transformation diagnostic is often useful. Changes in the electronic structure of the atoms in the crystal offer opportunities to develop new phase-change diagnostics. We have studied optical reflectance changes for several shock-induced phase transformations to see whether reflectance changes might be a generally applicable phase-transformation diagnostic. Shocks were produced by direct contact with explosives or with impacts from guns. Optical wavelengths for the reflectance measurements ranged from 355 to 700 nm. We studied samples of tin, iron, gallium, and cerium as each passed through a phase transformation during shock loading and, if observable, a reversion upon unloading. In addition to metals with complicated phase diagrams, we also measured dynamic, pressure-induced changes in the reflectivity of aluminum. For rapid solid-solid phase changes in tin and iron, we saw small changes in the surface scattering characteristics, perhaps from voids or rough areas frozen into the surface of the sample as it transformed to a new crystal structure. For melt in gallium and cerium, we saw changes in the wavelength dependence of the reflectance, and we surmise that these changes may result from changes in the crystal electronic structure. It appears that reflectance measurements can be a significant part of a larger suite of diagnostics
International Nuclear Information System (INIS)
Chudnovsky, D.V.; Columbia Univ., New York; Chudnovsky, G.V.; Columbia Univ., New York
1980-01-01
General algebraic and analytic formalism for derivation and solution of general two dimensional field theory equations of Zakharov-Shabat-Mikhailov type is presented. The examples presented show that this class of equations covers most of the known two-dimensional completely integrable equations. Possible generalizations for four dimensional systems require detailed analysis of Baecklund transformation of these equations. Baecklund transformation is presented in the form of Riemann problem and one special case of dual symmetry is worked out. (orig.)
Liquid-solid surface phase transformation of fluorinated fullerene on monolayer tungsten diselenide
Song, Zhibo
2018-04-04
Hybrid van der Waals heterostructures constructed by the integration of organic molecules and two-dimensional (2D) transition metal dichalcogenide (TMD) materials have useful tunable properties for flexible electronic devices. Due to the chemically inert and atomically smooth nature of the TMD surface, well-defined crystalline organic films form atomically sharp interfaces facilitating optimal device performance. Here, the surface phase transformation of the supramolecular packing structure of fluorinated fullerene (C60F48) on single-layer tungsten diselenide (WSe2) is revealed by low-temperature scanning tunneling microscopy, from thermally stable liquid to solid phases as the coverage increases. Statistical analysis of the intermolecular interaction potential reveals that the repulsive dipole-dipole interaction induced by interfacial charge transfer and substrate-mediated interactions play important roles in stabilizing the liquid C60F48 phases. Theoretical calculations further suggest that the dipole moment per C60F48 molecule varies with the surface molecule density, and the liquid-solid transformation could be understood from the perspective of the thermodynamic free energy for open systems. This study offers insights into the growth behavior at 2D organic/TMD hybrid heterointerfaces.
Liquid-solid surface phase transformation of fluorinated fullerene on monolayer tungsten diselenide
Song, Zhibo; Wang, Qixing; Li, Ming-Yang; Li, Lain-Jong; Zheng, Yu Jie; Wang, Zhuo; Lin, Tingting; Chi, Dongzhi; Ding, Zijing; Huang, Yu Li; Thye Shen Wee, Andrew
2018-04-01
Hybrid van der Waals heterostructures constructed by the integration of organic molecules and two-dimensional (2D) transition metal dichalcogenide (TMD) materials have useful tunable properties for flexible electronic devices. Due to the chemically inert and atomically smooth nature of the TMD surface, well-defined crystalline organic films form atomically sharp interfaces facilitating optimal device performance. Here, the surface phase transformation of the supramolecular packing structure of fluorinated fullerene (C60F48 ) on single-layer tungsten diselenide (WSe2) is revealed by low-temperature scanning tunneling microscopy, from thermally stable liquid to solid phases as the coverage increases. Statistical analysis of the intermolecular interaction potential reveals that the repulsive dipole-dipole interaction induced by interfacial charge transfer and substrate-mediated interactions play important roles in stabilizing the liquid C60F48 phases. Theoretical calculations further suggest that the dipole moment per C60F48 molecule varies with the surface molecule density, and the liquid-solid transformation could be understood from the perspective of the thermodynamic free energy for open systems. This study offers insights into the growth behavior at 2D organic/TMD hybrid heterointerfaces.
Dipolar vortices in two-dimensional flows
DEFF Research Database (Denmark)
Juul Rasmussen, J.; Hesthaven, J.S.; Lynov, Jens-Peter
1996-01-01
The dynamics of dipolar vortex solutions to the two-dimensional Euler equations is studied. A new type of nonlinear dipole is found and its dynamics in a slightly viscous system is compared with the dynamics of the Lamb dipole. The evolution of dipolar structures from an initial turbulent patch...
Analytical simulation of two dimensional advection dispersion ...
African Journals Online (AJOL)
The study was designed to investigate the analytical simulation of two dimensional advection dispersion equation of contaminant transport. The steady state flow condition of the contaminant transport where inorganic contaminants in aqueous waste solutions are disposed of at the land surface where it would migrate ...
Analytical Simulation of Two Dimensional Advection Dispersion ...
African Journals Online (AJOL)
ADOWIE PERE
ABSTRACT: The study was designed to investigate the analytical simulation of two dimensional advection dispersion equation of contaminant transport. The steady state flow condition of the contaminant transport where inorganic contaminants in aqueous waste solutions are disposed of at the land surface where it would ...
Two-dimensional position sensitive neutron detector
Indian Academy of Sciences (India)
A two-dimensional position sensitive neutron detector has been developed. The detector is a 3He + Kr filled multiwire proportional counter with charge division position readout and has a sensitive area of 345 mm × 345 mm, pixel size 5 mm × 5 mm, active depth 25 mm and is designed for efficiency of 70% for 4 Å neutrons.
Stability of two-dimensional vorticity filaments
International Nuclear Information System (INIS)
Elhmaidi, D.; Provenzale, A.; Lili, T.; Babiano, A.
2004-01-01
We discuss the results of a numerical study on the stability of two-dimensional vorticity filaments around a circular vortex. We illustrate how the stability of the filaments depends on the balance between the strain associated with the far field of the vortex and the local vorticity of the filament, and we discuss an empirical criterion for filament stability
Two-dimensional membranes in motion
Davidovikj, D.
2018-01-01
This thesis revolves around nanomechanical membranes made of suspended two - dimensional materials. Chapters 1-3 give an introduction to the field of 2D-based nanomechanical devices together with an overview of the underlying physics and the measurementtools used in subsequent chapters. The research
Piezoelectricity in Two-Dimensional Materials
Wu, Tao
2015-02-25
Powering up 2D materials: Recent experimental studies confirmed the existence of piezoelectricity - the conversion of mechanical stress into electricity - in two-dimensional single-layer MoS2 nanosheets. The results represent a milestone towards embedding low-dimensional materials into future disruptive technologies. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA.
Sums of two-dimensional spectral triples
DEFF Research Database (Denmark)
Christensen, Erik; Ivan, Cristina
2007-01-01
We study countable sums of two dimensional modules for the continuous complex functions on a compact metric space and show that it is possible to construct a spectral triple which gives the original metric back. This spectral triple will be finitely summable for any positive parameter. We also co...
A novel two dimensional particle velocity sensor
Pjetri, O.; Wiegerink, Remco J.; Lammerink, Theodorus S.J.; Krijnen, Gijsbertus J.M.
2013-01-01
In this paper we present a two wire, two-dimensional particle velocity sensor. The miniature sensor of size 1.0x2.5x0.525 mm, consisting of only two crossed wires, shows excellent directional sensitivity in both directions, thus requiring no directivity calibration, and is relatively easy to
Two-dimensional microstrip detector for neutrons
Energy Technology Data Exchange (ETDEWEB)
Oed, A. [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)
1997-04-01
Because of their robust design, gas microstrip detectors, which were developed at ILL, can be assembled relatively quickly, provided the prefabricated components are available. At the beginning of 1996, orders were received for the construction of three two-dimensional neutron detectors. These detectors have been completed. The detectors are outlined below. (author). 2 refs.
Acoustic emission during low temperature phase transformations in plutonium
International Nuclear Information System (INIS)
Khejpl, K.; Karpenter, S.
1988-01-01
To study the nature of phase transformations in plutonium and plutonium-gallium alloys (0.3 and 0.57% Ga) the measurement of acoustic emission is conducted. The presence of acoustic emission testifies to martensitic character of transformation, related to sharp local changes in the volume, which cause elastic waves. It is detected that during α reversible β transformations in non-alloyed plutonium acoustic emission is absent, and that testifies to nonmartensitic nature of the transformations. σ reversible α transformation in plutonium-gallium alloys is accompanied by the appearance of acoustic emission, i.e. it is of martensitic origin
International Nuclear Information System (INIS)
Yang Bo; Li Xiao-Teng; Chen Xiao-Song; Chen Wei; Liu Jian
2016-01-01
Self-questioning mechanism which is similar to single spin-flip of Ising model in statistical physics is introduced into spatial evolutionary game model. We propose a game model with altruistic to spiteful preferences via weighted sums of own and opponent's payoffs. This game model can be transformed into Ising model with an external field. Both interaction between spins and the external field are determined by the elements of payoff matrix and the preference parameter. In the case of perfect rationality at zero social temperature, this game model has three different phases which are entirely cooperative phase, entirely non-cooperative phase and mixed phase. In the investigations of the game model with Monte Carlo simulation, two paths of payoff and preference parameters are taken. In one path, the system undergoes a discontinuous transition from cooperative phase to non-cooperative phase with the change of preference parameter. In another path, two continuous transitions appear one after another when system changes from cooperative phase to non-cooperative phase with the prefenrence parameter. The critical exponents v, β, and γ of two continuous phase transitions are estimated by the finite-size scaling analysis. Both continuous phase transitions have the same critical exponents and they belong to the same universality class as the two-dimensional Ising model. (paper)
Size dependent phase and morphological transformation of alumina nanoparticles
Dommisa, D. B.; Dash, R. K.
2018-03-01
The size effect of the alumina nanoparticles on the phase and morphological transition by thermal treatment at various temperatures is investigated by choosing two different sizes alumina nanoparticles. Our experimental results revealed that phase and morphological transformation behavior is significantly different for smaller size alumina nanoparticles than that of larger size. The more stable alpha phase transformation occurs at a higher temperature for smaller size alumina nanoparticles in comparison to that of the larger size alumina nanoparticles. Moreover, the experimental facts also elucidated that the nucleation and growth process at the nanoscale for the phase transition is also size dependent. Our experimental result from the FESEM and TEM analysis also revealed that there is a direct correlation between phase and morphological transition of alumina nanoparticles size which is consistent with the XRD results. Therefore, we believe that our experimental findings can be extended to other complex nanomaterials for understanding the size-dependent phase and morphological transformation at the nanoscale.
Diffusion phase transformation and deformation in steels
Czech Academy of Sciences Publication Activity Database
Gamsjaeger, E.; Antretter, T.; Schmaranzer, C.; Preis, W.; Chimani, C.; Simha, N. K.; Svoboda, Jiří; Fischer, F. D.
2002-01-01
Roč. 25, č. 1 (2002), s. 92-99 ISSN 0927-0256 R&D Projects: GA AV ČR KSK1010104 Institutional research plan: CEZ:AV0Z2041904 Keywords : Transformation kinetics * Fe-C system * steel Subject RIV: BJ - Thermodynamics Impact factor: 0.856, year: 2002
Energy Technology Data Exchange (ETDEWEB)
Perez Guerrero, Jesus Salvador
1995-12-31
Laminar developing flow in channels of arbitrary geometry was studied by solving the Navier-Stokes equations in the stream function-only formulation through the Generalized Integral Transform Technique (GITT). The stream function is expanded in an infinite system based on eigenfunctions obtained by considering solely the diffusive terms of the original formulation. The Navier-Stokes equations are transformed into an infinite system of ordinary differential equations, by using the transformation and inversion formulae. For computational purposes, the infinite series is truncated, according to an automatic error control procedure. The ordinary differential is solved through well-established scientific subroutines from widely available mathematical libraries. The classical problem of developing flow between parallel-plates is analysed first, as for both uniform and irrotational inlet conditions. The effect of truncating the duct length in the accuracy of the obtained solution is studied. A convergence analysis of the results obtained by the GITT is performed and compared with results obtained by finite difference and finite element methods, for different values of Reynolds number. The problem of flow over a backward-facing step then follows. Comparisons with experimental results in the literature indicate an excellent agreement. The numerical co-validation was established for a test case, and perfect agreement is reached against results considered as benchmarks in the recent literature. The results were shown to be physically more reasonable than others obtained by purely numerical methods, in particular for situations where three-dimensional effects are identified. Finally, a test problem for an irregular by shoped duct was studied and compared against results found in the literature, with good agreement and excellent convergence rates for the stream function field along the whole channel, for different values of Reynolds number. (author) 78 refs., 24 figs., 14 tabs.
Estimating Transformation Length in Linear- to Minimum-Phase Transformation Using Cepstrums
DEFF Research Database (Denmark)
Bysted, Tommy Kristensen
1997-01-01
response of the minimum-phase FIR-filter. The transformation length estimation is made using the absolute value of the dominating zero in the linear-phase FIR-filter and the maximum allowed amplitude and phase deviation of the disturbing function. Two examples are given. The first one verifies...
Study of effect of chromium on titanium dioxide phase transformation ...
Indian Academy of Sciences (India)
Administrator
Electronic Supplementary Material. Study of effect of chromium on titanium dioxide phase transformation by A Bellifa (pp 669–677). Figure S1. Structural schemes of anatase to rutile transition. Figure S2. Analysis ATG-ATD for different samples.
Phase transformations in the Cu.6 Pd.4 alloy
International Nuclear Information System (INIS)
Imakuma, K.
1977-01-01
Order-disorder and structural transformations in the Cu-Pd 60-40% (Cu. 6 Pd. 4 ) alloy by means of a temperature and time dependent treatment are studied. The structural transformations by x-rays diffraction are also studied, where the bcc, fcc and tetragonal phases were observed. A qualitative analyze of the resistivity kinetics are made [pt
Kinetics of solid state phase transformations: Measurement and ...
Indian Academy of Sciences (India)
Home; Journals; Journal of Chemical Sciences; Volume 122; Issue 1. Kinetics of solid state phase transformations: Measurement and modelling of some basic issues. S Raju E ... are enumerated. A simple and general modelling methodology for understanding the kinetics of non-isothermal transformations is outlined.
A Novel Three Phase to Seven Phase Conversion Technique Using Transformer Winding Connections
Directory of Open Access Journals (Sweden)
M. Tabrez
2017-10-01
Full Text Available This paper proposes a novel multiphase transformer connection scheme which converts three phase balanced AC input to seven phase balanced AC output. Generalized theory to convert a three phase utility supply into any number of phases is presented. Based on the proposed generalized principle, a three phase to seven phase power converting transformer design is presented with connection scheme, analysis and simulation and experimental results of the proposed three phase to seven phase conversion transformer. The proposed transformer in this paper is analyzed and compared with the connection scheme for seven phase available in the literature. The connection scheme is found to have higher power density, lower core area and lower core requirement as compared to the available connection scheme of the same rating. Impedance mismatching between different phases of the transformer is observed in the three phase to seven phase transformer available in the literature. As this mismatching introduces error in study of per phase equivalent circuit diagrams as well as imbalance in voltage and currents. The present design also addresses the impedance mismatching issue and reduces mismatching in the proposed transformer design. A prototype of the proposed system is developed and waveforms are presented. The proposed design is verified using simulation and validated using experimental approach.
SIMULATION OF CHARACTERISTICS OF DUAL-CORE PHASE SHIFTING TRANSFORMER
Directory of Open Access Journals (Sweden)
Kalinin L.P.
2014-04-01
Full Text Available The role and importance of phase shifting transformers are increased as a result of the further development of integrated power systems. This gives the rise to new technical solutions which entails the necessity of comparison of new developments with existing. The article consider the technical characteristics of dual-core phase shifting transformer which later will be used as a basis for comparison with other competing options and assess of their technical efficiency.
Two-dimensional quantum electrodynamics as a model in the constructive quantum field theory
International Nuclear Information System (INIS)
Ito, K.R.
1976-01-01
We investigate two-dimensional quantum electrodynamics((QED) 2 ) type models on the basis of the Hamiltonian formalism of a vector field. The transformation into a sine-Gordon equation is clarified as a generalized mass-shift transformation through canonical linear transformations. (auth.)
Phase Transformations during the Reaction Heat Treatment
Scheuerlein, C; Thilly, L; Buta, F; Peng, X; Gregory, E; Parrell, J A; Pong, I; Bordini, B; Cantoni, M
2009-01-01
The evolution of Nb containing phases during the diffusion heat treatment of three different high critical current Nb3Sn strand types is compared, based on synchrotron X-ray diffraction results that have been obtained at the ID15 beam line of the European Synchrotron Radiation Facility (ESRF). In all strands studied, Nb3Sn formation is preceded by the formation of a Cu-Nb-Sn ternary phase, NbSn2 and Nb6Sn5. As compared to the PIT and Tube Type strand, the amount of these phases formed in the RRP strand is relatively small. In the RRP strand subelements with a fine filament structure Nb3Sn grows more quickly, thereby preventing to a large extent the formation of the other higher tin phases.
Energy Technology Data Exchange (ETDEWEB)
Ishino, Y.; Kojima, T.; Oiwa, N.; Yamaguchi, S. (Nagoya Institute of Technology, Nagoya (Japan))
1993-11-25
The acoustic excitation of a plane diffusion flame enhances the periodicity of organized eddy controlled combustion. In this study, to clarify an effectiveness of application of active combustion control, phase characteristics of the excited eddy flames with high periodicity have been examined. A computer-aided phase-locked averaging method was employed to obtain graphical two-dimensional contour maps of the instantaneous profiles of temperature and CH emission. Both maps consisting of eight consecutive phases indicated clearly not only the periodic behavior of the organized eddy flame, but also the gas dynamic properties peculiar to those flames with coherent structure. In addition, the profiles of local contribution of the sound field to the combustion process were examined by calculating the two-dimensional distribution of the local Rayleigh index. Calculation results of the two-dimensional distribution of the local Rayleigh index indicated that the organized eddy flames have high sensitivity to sound, and play an important role in an interaction of sound and flame. 6 refs., 9 figs.
Two-dimensional sensitivity calculation code: SENSETWO
International Nuclear Information System (INIS)
Yamauchi, Michinori; Nakayama, Mitsuo; Minami, Kazuyoshi; Seki, Yasushi; Iida, Hiromasa.
1979-05-01
A SENSETWO code for the calculation of cross section sensitivities with a two-dimensional model has been developed, on the basis of first order perturbation theory. It uses forward neutron and/or gamma-ray fluxes and adjoint fluxes obtained by two-dimensional discrete ordinates code TWOTRAN-II. The data and informations of cross sections, geometry, nuclide density, response functions, etc. are transmitted to SENSETWO by the dump magnetic tape made in TWOTRAN calculations. The required input for SENSETWO calculations is thus very simple. The SENSETWO yields as printed output the cross section sensitivities for each coarse mesh zone and for each energy group, as well as the plotted output of sensitivity profiles specified by the input. A special feature of the code is that it also calculates the reaction rate with the response function used as the adjoint source in TWOTRAN adjoint calculation and the calculated forward flux from the TWOTRAN forward calculation. (author)
Two-dimensional ranking of Wikipedia articles
Zhirov, A. O.; Zhirov, O. V.; Shepelyansky, D. L.
2010-10-01
The Library of Babel, described by Jorge Luis Borges, stores an enormous amount of information. The Library exists ab aeterno. Wikipedia, a free online encyclopaedia, becomes a modern analogue of such a Library. Information retrieval and ranking of Wikipedia articles become the challenge of modern society. While PageRank highlights very well known nodes with many ingoing links, CheiRank highlights very communicative nodes with many outgoing links. In this way the ranking becomes two-dimensional. Using CheiRank and PageRank we analyze the properties of two-dimensional ranking of all Wikipedia English articles and show that it gives their reliable classification with rich and nontrivial features. Detailed studies are done for countries, universities, personalities, physicists, chess players, Dow-Jones companies and other categories.
Two-dimensional confinement of heavy fermions
International Nuclear Information System (INIS)
Shishido, Hiroaki; Shibauchi, Takasada; Matsuda, Yuji; Terashima, Takahito
2010-01-01
Metallic systems with the strongest electron correlations are realized in certain rare-earth and actinide compounds whose physics are dominated by f-electrons. These materials are known as heavy fermions, so called because the effective mass of the conduction electrons is enhanced via correlation effects up to as much as several hundreds times the free electron mass. To date the electronic structure of all heavy-fermion compounds is essentially three-dimensional. Here we report on the first realization of a two-dimensional heavy-fermion system, where the dimensionality is adjusted in a controllable fashion by fabricating heterostructures using molecular beam epitaxy. The two-dimensional heavy fermion system displays striking deviations from the standard Fermi liquid low-temperature electronic properties. (author)
Toward two-dimensional search engines
International Nuclear Information System (INIS)
Ermann, L; Shepelyansky, D L; Chepelianskii, A D
2012-01-01
We study the statistical properties of various directed networks using ranking of their nodes based on the dominant vectors of the Google matrix known as PageRank and CheiRank. On average PageRank orders nodes proportionally to a number of ingoing links, while CheiRank orders nodes proportionally to a number of outgoing links. In this way, the ranking of nodes becomes two dimensional which paves the way for the development of two-dimensional search engines of a new type. Statistical properties of information flow on the PageRank–CheiRank plane are analyzed for networks of British, French and Italian universities, Wikipedia, Linux Kernel, gene regulation and other networks. A special emphasis is done for British universities networks using the large database publicly available in the UK. Methods of spam links control are also analyzed. (paper)
Plasmonics with two-dimensional conductors
Yoon, Hosang; Yeung, Kitty Y. M.; Kim, Philip; Ham, Donhee
2014-01-01
A wealth of effort in photonics has been dedicated to the study and engineering of surface plasmonic waves in the skin of three-dimensional bulk metals, owing largely to their trait of subwavelength confinement. Plasmonic waves in two-dimensional conductors, such as semiconductor heterojunction and graphene, contrast the surface plasmonic waves on bulk metals, as the former emerge at gigahertz to terahertz and infrared frequencies well below the photonics regime and can exhibit far stronger subwavelength confinement. This review elucidates the machinery behind the unique behaviours of the two-dimensional plasmonic waves and discusses how they can be engineered to create ultra-subwavelength plasmonic circuits and metamaterials for infrared and gigahertz to terahertz integrated electronics. PMID:24567472
Two-dimensional Kagome photonic bandgap waveguide
DEFF Research Database (Denmark)
Nielsen, Jens Bo; Søndergaard, Thomas; Libori, Stig E. Barkou
2000-01-01
The transverse-magnetic photonic-bandgap-guidance properties are investigated for a planar two-dimensional (2-D) Kagome waveguide configuration using a full-vectorial plane-wave-expansion method. Single-moded well-localized low-index guided modes are found. The localization of the optical modes...... is investigated with respect to the width of the 2-D Kagome waveguide, and the number of modes existing for specific frequencies and waveguide widths is mapped out....
Superintegrability on the two dimensional hyperboloid
International Nuclear Information System (INIS)
Akopyan, E.; Pogosyan, G.S.; Kalnins, E.G.; Miller, W. Jr
1998-01-01
This work is devoted to the investigation of the quantum mechanical systems on the two dimensional hyperboloid which admit separation of variables in at least two coordinate systems. Here we consider two potentials introduced in a paper of C.P.Boyer, E.G.Kalnins and P.Winternitz, which haven't been studied yet. An example of an interbasis expansion is given and the structure of the quadratic algebra generated by the integrals of motion is carried out
Quantum skyrmions in two-dimensional chiral magnets
Takashima, Rina; Ishizuka, Hiroaki; Balents, Leon
2016-10-01
We study the quantum mechanics of magnetic skyrmions in the vicinity of the skyrmion-crystal to ferromagnet phase boundary in two-dimensional magnets. We show that the skyrmion excitation has an energy dispersion that splits into multiple bands due to the combination of magnus force and the underlying lattice. Condensation of the skyrmions can give rise to an intermediate phase between the skyrmion crystal and ferromagnet: a quantum liquid, in which skyrmions are not spatially localized. We show that the critical behavior depends on the spin size S and the topological number of the skyrmion. Experimental signatures of quantum skyrmions in inelastic neutron-scattering measurements are also discussed.
Stable corrugated state of the two-dimensional electron gas
International Nuclear Information System (INIS)
Mendez-Moreno, R.M.; Moreno, M.; Ortiz, M.A.
1991-01-01
A corrugated and stable ground state is found for the two-dimensional electron gas in both the normal paramagnetic and the fully polarized phases. The self-consistent Hartree-Fock method is used with a modulated set of trial wave functions within the deformable jellium model. The results for high metallic densities reproduce the usual noncorrugated ferromagnetic electron-gas behavior. A transition to a paramagnetic corrugated state for values of r s ∼6.5 is predicted. At lower densities r s ∼30, a second transition to a corrugated ferromagnetic phase is suggested
Magnetism and pairing of two-dimensional trapped fermions.
Chiesa, Simone; Varney, Christopher N; Rigol, Marcos; Scalettar, Richard T
2011-01-21
The emergence of local phases in a trapped two-component Fermi gas in an optical lattice is studied using quantum Monte Carlo simulations. We treat temperatures that are comparable to or lower than those presently achievable in experiments and large enough systems that both magnetic and paired phases can be detected by inspection of the behavior of suitable short-range correlations. We use the latter to suggest the interaction strength and temperature range at which experimental observation of incipient magnetism and d-wave pairing are more likely and evaluate the relation between entropy and temperature in two-dimensional confined fermionic systems.
Thermal neutron diffraction on two-dimensional lattices
International Nuclear Information System (INIS)
Stern, T.
1974-06-01
This thesis deals with the problem of neutron diffraction from a two-dimensional lattice. The neutron spin is not taken into account. Firstly the scalar wave field is treated by means of differential equations (Helmholtz) and secondly by the equivalent integral equation formulation (Kirchoff-Weber). Finally, using the methods of the Green function, the reflected and transmitted wave fields are represented as integral transformations of a certain source function. In respect to the calculation of the amplitudes of the diffraction waves the third method seems to be the best one for the purpose of the physical interpretation and the applicability of numerical methods. (C.R.)
Phase Transformation of Hydrothermally Synthesized Nanoparticle ...
African Journals Online (AJOL)
NJD
Mild hydrothermal hydrolysis of TiCl4 produces nanorods of the rutile phase of titanium dioxide in high yield, while in the presence of organic ..... Reading, MA, 1969. 39 H.P. Klug and L.E. Alexander, X-ray Diffraction Procedures for. Polycrystalline and Amorphous Materials, 2nd edn. John Wiley & Sons,. New York, 1974.
Phase Transformation of Hydrothermally Synthesized Nanoparticle ...
African Journals Online (AJOL)
Mild hydrothermal hydrolysis of TiCl4 produces nanorods of the rutile phase of titanium dioxide in high yield, while in the presence of organic acids (citric, acetic, D-tartaric and benzoic acids) anatase is the only product. The effect of these organic acids on the products of the hydrolysis reaction as well as the reaction kinetics ...
Complexion-mediated martensitic phase transformation in Titanium
Zhang, J.; Tasan, C. C.; Lai, M. J.; Dippel, A.-C.; Raabe, D.
2017-02-01
The most efficient way to tune microstructures and mechanical properties of metallic alloys lies in designing and using athermal phase transformations. Examples are shape memory alloys and high strength steels, which together stand for 1,500 million tons annual production. In these materials, martensite formation and mechanical twinning are tuned via composition adjustment for realizing complex microstructures and beneficial mechanical properties. Here we report a new phase transformation that has the potential to widen the application window of Ti alloys, the most important structural material in aerospace design, by nanostructuring them via complexion-mediated transformation. This is a reversible martensitic transformation mechanism that leads to a final nanolaminate structure of α'' (orthorhombic) martensite bounded with planar complexions of athermal ω (a-ω, hexagonal). Both phases are crystallographically related to the parent β (BCC) matrix. As expected from a planar complexion, the a-ω is stable only at the hetero-interface.
Chemically Induced Phase Transformation in Austenite by Focused Ion Beam
Basa, Adina; Thaulow, Christian; Barnoush, Afrooz
2014-03-01
A highly stable austenite phase in a super duplex stainless steel was subjected to a combination of different gallium ion doses at different acceleration voltages. It was shown that contrary to what is expected, an austenite to ferrite phase transformation occurred within the focused ion beam (FIB) milled regions. Chemical analysis of the FIB milled region proved that the gallium implantation preceded the FIB milling. High resolution electron backscatter diffraction analysis also showed that the phase transformation was not followed by the typical shear and plastic deformation expected from the martensitic transformation. On the basis of these observations, it was concluded that the change in the chemical composition of the austenite and the local increase in gallium, which is a ferrite stabilizer, results in the local selective transformation of austenite to ferrite.
Study of 18-Pulse Rectifier Utilizing Hexagon Connected 3-Phase to 9-Phase Transformer
Directory of Open Access Journals (Sweden)
Ahmad Saudi Samosir
2008-04-01
Full Text Available The 18-pulse converter, using Y or -connected differential autotransformer, is very interesting since it allows natural high power factor correction. The lowest input current harmonic components are the 17th and 19th. The Transformer is designed to feed three six-pulse bridge rectifiers displaced in phase by 200. This paper present a high power factor three-phase rectifier bases on 3-phase to 9-phase transformer and 18-pulse rectifier. The 9-phase polygon-connected transformer followed by 18-pulse diode rectifiers ensures the fundamental concept of natural power factor correction. Simulation results to verify the proposed concept are shown in this paper.
Kinetics of solid state phase transformations: Measurement and ...
Indian Academy of Sciences (India)
Administrator
in the realm of metals and alloys. While thermody- namics classifies phase changes in terms of the nature of .... structural change in uranium. 9. It is interesting to note that the temperature interval of the two phase ... diagram for the α → β transformation in uranium is shown. The dotted lines represent various heating rates,.
Continuum mechanics methods in the theory of phase transformations
Grinfel'D, Mikhail A.
A theory for phase transformations in solids is developed on the basis of the variational principles of thermodynamics. The discussion focuses on the fundamental concepts of the theory, detailed classification of phase transformations at the phenomenological level, and statement of essentially new boundary value problems for continuum mechanics equations. General solutions are illustrated by the equilibrium and stability analysis of specific two-phase systems and solution of problems of practical importance. The methods and results discussed here are relevant to various problems in rigid body mechanics, hydrodynamics, materials science, geomechanics, and other fields.
Modelling of phase transformations occurring in low activation martensitic steels
International Nuclear Information System (INIS)
Brachet, J.-C.; Gavard, L.; Boussidan, C.; Lepoittevin, C.; Servant, C.
1998-01-01
The main objective of this paper is to summarize modelling of on-heating and on-cooling phase transformations occurring in low activation martensitic (LAM) steels. Calculations of thermodynamic equilibrium phase fractions and kinetic aspects of phase transformations have been performed by using different approaches from experimental data (CCT and TTT diagrams obtained by dilatometry). All the calculated data have been compared to an important and systematic set of experimental data obtained on different LAM steels of the 7.5-11% CrWVT a type. (orig.)
Modelling of phase transformations occurring in low activation martensitic steels
Brachet, J.-C.; Gavard, L.; Boussidan, C.; Lepoittevin, C.; Denis, S.; Servant, C.
1998-10-01
The main objective of this paper is to summarize modelling of on-heating and on-cooling phase transformations occurring in Low Activation Martensitic (LAM) steels. Calculations of thermodynamic equilibrium phase fractions and kinetic aspects of phase transformations have been performed by using different approaches from experimental data (CCT and TTT diagrams obtained by dilatometry). All the calculated data have been compared to an important and systematic set of experimental data obtained on different LAM steels of the 7.5-11% CrWVT a type.
Frame transforms, star products and quantum mechanics on phase space
International Nuclear Information System (INIS)
Aniello, P; Marmo, G; Man'ko, V I
2008-01-01
Using the notions of frame transform and of square integrable projective representation of a locally compact group G, we introduce a class of isometries (tight frame transforms) from the space of Hilbert-Schmidt operators in the carrier Hilbert space of the representation into the space of square integrable functions on the direct product group G x G. These transforms have remarkable properties. In particular, their ranges are reproducing kernel Hilbert spaces endowed with a suitable 'star product' which mimics, at the level of functions, the original product of operators. A 'phase space formulation' of quantum mechanics relying on the frame transforms introduced in the present paper, and the link of these maps with both the Wigner transform and the wavelet transform are discussed
Liu, Hui; Chen, Jun; Huang, Houbing; Fan, Longlong; Ren, Yang; Pan, Zhao; Deng, Jinxia; Chen, Long-Qing; Xing, Xianran
2018-01-01
A functional material with coexisting energetically equivalent phases often exhibits extraordinary properties such as piezoelectricity, ferromagnetism, and ferroelasticity, which is simultaneously accompanied by field-driven reversible phase transformation. The study on the interplay between such phase transformation and the performance is of great importance. Here, we have experimentally revealed the important role of field-driven reversible phase transformation in achieving enhanced electromechanical properties using in situ high-energy synchrotron x-ray diffraction combined with 2D geometry scattering technology, which can establish a comprehensive picture of piezoelectric-related microstructural evolution. High-throughput experiments on various Pb /Bi -based perovskite piezoelectric systems suggest that reversible phase transformation can be triggered by an electric field at the morphotropic phase boundary and the piezoelectric performance is highly related to the tendency of electric-field-driven phase transformation. A strong tendency of phase transformation driven by an electric field generates peak piezoelectric response. Further, phase-field modeling reveals that the polarization alignment and the piezoelectric response can be much enhanced by the electric-field-driven phase transformation. The proposed mechanism will be helpful to design and optimize the new piezoelectrics, ferromagnetics, or other related functional materials.
Kuppan, Saravanan; Xu, Yahong; Liu, Yijin; Chen, Guoying
2017-02-01
Understanding the reaction pathway and kinetics of solid-state phase transformation is critical in designing advanced electrode materials with better performance and stability. Despite the first-order phase transition with a large lattice mismatch between the involved phases, spinel LiMn1.5Ni0.5O4 is capable of fast rate even at large particle size, presenting an enigma yet to be understood. The present study uses advanced two-dimensional and three-dimensional nano-tomography on a series of well-formed LixMn1.5Ni0.5O4 (0growth process instead of a shrinking-core or a particle-by-particle process. Superior kinetics of (100) facets at the vertices of truncated octahedral particles promote preferential delithiation, whereas the observation of strain-induced cracking suggests mechanical degradation in the material.
Analysis and simulation of phase transformation kinetics of zeolite A from amorphous phases
Energy Technology Data Exchange (ETDEWEB)
Marui, Yukiko; Matsuoka, Masakuni; Uchida, Hirohisa; Takiyama, Hiroshi [Tokyo Univ. of Agriculture and Technology, Koganei, Tokyo (Japan)
2003-05-01
Experiments on transformation rates of zeolite A from amorphous phases at different feed rates to alter the particle size of the amorphous phases were carried out to analyze the kinetics of the transformation, and were analyzed by performing simulation of the transformation. A clear dependence of the induction time for nucleation of zeolite A crystals on the surface area of the amorphous phase was recognized, indicating that the nucleation of zeolite A was heterogeneous and the nucleation rate was almost proportional to the size of the amorphous particles. From the simulation, the mechanism of the transformation was found to be heterogeneous nucleation of zeolite A crystals on the surface of amorphous particles followed by solution mediated phase transformation, and the transformation kinetics were well reproduced at different feed rates. (author)
Analysis and simulation of phase transformation kinetics of zeolite A from amorphous phases
Marui, Y; Uchida, H; Takiyama, H
2003-01-01
Experiments on transformation rates of zeolite A from amorphous phases at different feed rates to alter the particle size of the amorphous phases were carried out to analyze the kinetics of the transformation, and were analyzed by performing simulation of the transformation. A clear dependence of the induction time for nucleation of zeolite A crystals on the surface area of the amorphous phase was recognized, indicating that the nucleation of zeolite A was heterogeneous and the nucleation rate was almost proportional to the size of the amorphous particles. From the simulation, the mechanism of the transformation was found to be heterogeneous nucleation of zeolite A crystals on the surface of amorphous particles followed by solution mediated phase transformation, and the transformation kinetics were well reproduced at different feed rates. (author)
Domain Wall Evolution in Phase Transforming Oxides
2015-01-14
Domain wall motion and electric?field?induced strains in NBT ?xBT solid solutions from in situ neutron diffraction,” T.-M. Usher,* J. S. Forrester, E...Morphotropic Phase Boundary of NBT ?BT,” L. M. Denis,* J. Glaum, M. Hoffman, J. Forrester, and J. L. Jones, Electronic Materials and Applications 2013...titanate (PZT) and lead-free compositions Na0.5K0.5NbO3 (NKN) and Na0.5Bi0.5TiO3 ( NBT ). This past year, we reported results on piezoelectric compositions
Degenerate ground states and multiple bifurcations in a two-dimensional q-state quantum Potts model.
Dai, Yan-Wei; Cho, Sam Young; Batchelor, Murray T; Zhou, Huan-Qiang
2014-06-01
We numerically investigate the two-dimensional q-state quantum Potts model on the infinite square lattice by using the infinite projected entangled-pair state (iPEPS) algorithm. We show that the quantum fidelity, defined as an overlap measurement between an arbitrary reference state and the iPEPS ground state of the system, can detect q-fold degenerate ground states for the Z_{q} broken-symmetry phase. Accordingly, a multiple bifurcation of the quantum ground-state fidelity is shown to occur as the transverse magnetic field varies from the symmetry phase to the broken-symmetry phase, which means that a multiple-bifurcation point corresponds to a critical point. A (dis)continuous behavior of quantum fidelity at phase transition points characterizes a (dis)continuous phase transition. Similar to the characteristic behavior of the quantum fidelity, the magnetizations, as order parameters, obtained from the degenerate ground states exhibit multiple bifurcation at critical points. Each order parameter is also explicitly demonstrated to transform under the Z_{q} subgroup of the symmetry group of the Hamiltonian. We find that the q-state quantum Potts model on the square lattice undergoes a discontinuous (first-order) phase transition for q=3 and q=4 and a continuous phase transition for q=2 (the two-dimensional quantum transverse Ising model).
Effect of phase transformations on microstructures in deep mantle materials
Merkel, Sébastien; Langrand, Christopher; Rosa, Angelika; Hilairet, Nadège
2017-04-01
Phase transformations induce microstructural changes in deep Earth materials, including changes in grain size and orientation distribution. The effect of phase transformations on mineral microstructures is usually studied using electron microscopy on quench products from high P/T experiments. The method allows for a precise evaluation of the microscopic mechanisms involved. It is limited, however, to samples that can be quenched to ambient conditions and allows for investigations at a single P/T point for each experiment. In recent years, we extended the use of multigrain crystallography to samples inside diamond anvil cells under mantle P/T conditions. The method allows for monitoring the orientations of hundreds of grains and grain size variations during various physical processes, such as plastic deformation and successions of phase transformations (Rosa et al 2015, Langrand et al 2017). Here, we will show results concerning hydrous Mg2SiO4 during the series of α-β-γ phase transformations up to 40 GPa and 850 °C. Such results are important to understand the descending behaviour of subducted slabs, observations of seismic anisotropy, and polarity changes for seismic waves reflected of deep Earth interfaces. The data is used to asses the effect of the transformation on grain orientation and grain sizes. In particular, we do not observe orientation relationships between the parent α-phase and the daughter β-phase phase, suggesting an incoherent growth. We also observe significant grain size reductions and only little grain growth within the newly formed phases (Rosa et al 2016). These new results are important for understanding the mechanical behavior of subducting slabs, seismic anisotropy in the Earth's mantle, and phase transformation mechanisms in olivine. Now that it is validated, the method can also be applied to other phases that can not be studied using electron microscopy, such as perovskite and post-perovskite. Langrand, Hilairet, Nisr, Roskosz, Rib
Gyroscope with two-dimensional optomechanical mirror
Davuluri, Sankar; Li, Kai; Li, Yong
2017-11-01
We propose an application of two-dimensional optomechanical oscillator as a gyroscope by detecting the Coriolis force which is modulated at the natural frequency of the optomechanical oscillator. Dependence of gyroscope's sensitivity on shot noise, back-action noise, thermal noise, and input laser power is studied. At optimal input laser power, the gyroscope's sensitivity can be improved by increasing the mass or by decreasing the temperature and decay rate of the mechanical oscillator. When the mechanical oscillator's thermal occupation number, n th, is zero, sensitivity improves with decrease in frequency of the mechanical oscillator. For {n}{{th}}\\gg 1, the sensitivity is independent of the mechanical oscillator's frequency.
Versatile two-dimensional transition metal dichalcogenides
DEFF Research Database (Denmark)
Canulescu, Stela; Affannoukoué, Kévin; Döbeli, Max
Two-dimensional transition metal dichalcogenides (2D-TMDCs), such as MoS2, have emerged as a new class of semiconducting materials with distinct optical and electrical properties. The availability of 2D-TMDCs with distinct band gaps allows for unlimited combinations of TMDC monolayers (MLs...... vacancies. We have found that the absorption spectra of the MoS2 films exhibit distinct excitonic peaks at ~1.8 and ~2 eV when grown in the presence of a sulfur evaporation beam as compared to those deposited in vacuum. The structure of the PLD-grown MoS2 films will be further discussed based Raman...
Binding energy of two-dimensional biexcitons
DEFF Research Database (Denmark)
Singh, Jai; Birkedal, Dan; Vadim, Lyssenko
1996-01-01
Using a model structure for a two-dimensional (2D) biexciton confined in a quantum well, it is shown that the form of the Hamiltonian of the 2D biexciton reduces into that of an exciton. The binding energies and Bohr radii of a 2D biexciton in its various internal energy states are derived...... analytically using the fractional dimension approach. The ratio of the binding energy of a 2D biexciton to that of a 2D exciton is found to be 0.228, which agrees very well with the recent experimental value. The results of our approach are compared with those of earlier theories....
Formation, transformation and dissolution of phases formed on surfaces
International Nuclear Information System (INIS)
Shoesmith, D.W.
1983-03-01
The basic mechanisms of film growth, transformation, and dissolution of phases formed on surfaces are discussed. Film growth can occur via solid-state processes or via substrate (usally metal or alloy) dissolution, followed by local supersaturation and precipitation of an insoluble phase. The phase(s) formed may be metastable and transform to a more stable phase, via either solid-state or dissolution-reprecipitation processes. Film dissolution reactions can also occur via a variety of mechanisms, including: (i) direct chemical dissolution when no oxidation state change occurs; (ii) redox dissolution when the film dissolves via a redox reaction involving a reducing or oxidizing agent in solution; and (iii) autoreduction, where film dissolution is coupled to metal dissolution. Such film-growth and dissolution processes, which often produce complex multilayer films, are common in the nuclear industry. A number of examples are discussed
Statistical thermodynamics of a two-dimensional relativistic gas.
Montakhab, Afshin; Ghodrat, Malihe; Barati, Mahmood
2009-03-01
In this paper we study a fully relativistic model of a two-dimensional hard-disk gas. This model avoids the general problems associated with relativistic particle collisions and is therefore an ideal system to study relativistic effects in statistical thermodynamics. We study this model using molecular-dynamics simulation, concentrating on the velocity distribution functions. We obtain results for x and y components of velocity in the rest frame (Gamma) as well as the moving frame (Gamma;{'}) . Our results confirm that Jüttner distribution is the correct generalization of Maxwell-Boltzmann distribution. We obtain the same "temperature" parameter beta for both frames consistent with a recent study of a limited one-dimensional model. We also address the controversial topic of temperature transformation. We show that while local thermal equilibrium holds in the moving frame, relying on statistical methods such as distribution functions or equipartition theorem are ultimately inconclusive in deciding on a correct temperature transformation law (if any).
Transmission Network Expansion Planning Considering Phase-Shifter Transformers
Miasaki, Celso T.; Franco, Edgar M. C.; Romero, Ruben A.
2012-01-01
This paper presents a novel mathematical model for the transmission network expansion planning problem. Main idea is to consider phase-shifter (PS) transformers as a new element of the transmission system expansion together with other traditional components such as transmission lines and conventional transformers. In this way, PS are added in order to redistribute active power flows in the system and, consequently, to diminish the total investment costs due to new transmission lines. Proposed...
Parallel comprehensive two-dimensional gas chromatography.
Yan, DanDan; Tedone, Laura; Koutoulis, Anthony; Whittock, Simon P; Shellie, Robert A
2017-11-17
We introduce an information rich analytical approach called parallel comprehensive two-dimensional gas chromatography (2GC×2GC). This parallel chromatography approach splits injected samples into two independent two-dimensional column ensembles and provides two GC×GC separations by using contra-directional thermal modulation. The first-dimension ( 1 D) and second-dimension ( 2 D) columns are connected using planar three-port microchannel devices, which are supplied with supplementary flow via two pressure controller modules. Precise carrier gas flow control at the junction of the 1 D and 2 D columns permits independent control of flow conditions in each separation column. The 2GC×2GC approach provides two entirely independent GC×GC separations for each injection. Analysis of hop (Humulus lupulus L.) essential oils is used to demonstrate the capability of the approach. The analytical performance of each GC×GC separation in the 2GC×2GC experiment is comparable to individual GC×GC separation with matching column configurations. The peak capacity of 2GC×2GC is about 2 times than that of single GC×GC system. The dual 2D chromatograms produced by this single detector system provide complementary separations and additional identification information by harnessing different selectivity provided by the four separation columns. Copyright © 2017 Elsevier B.V. All rights reserved.
Flow transitions in two-dimensional foams.
Gilbreth, Christopher; Sullivan, Scott; Dennin, Michael
2006-11-01
For sufficiently slow rates of strain, flowing foam can exhibit inhomogeneous flows. The nature of these flows is an area of active study in both two-dimensional model foams and three dimensional foam. Recent work in three-dimensional foam has identified three distinct regimes of flow [S. Rodts, J. C. Baudez, and P. Coussot, Europhys. Lett. 69, 636 (2005)]. Two of these regimes are identified with continuum behavior (full flow and shear banding), and the third regime is identified as a discrete regime exhibiting extreme localization. In this paper, the discrete regime is studied in more detail using a model two-dimensional foam: a bubble raft. We characterize the behavior of the bubble raft subjected to a constant rate of strain as a function of time, system size, and applied rate of strain. We observe localized flow that is consistent with the coexistence of a power-law fluid with rigid-body rotation. As a function of applied rate of strain, there is a transition from a continuum description of the flow to discrete flow when the thickness of the flow region is approximately ten bubbles. This occurs at an applied rotation rate of approximately 0.07 s-1.
The lattice correspondence and diffusional-displacive phase transformations
International Nuclear Information System (INIS)
Nie, J.F.; Muddle, B.C.
1999-01-01
When a coherent interface is maintained between parent and product phases in a solid state phase transformation, then it is always possible to define a lattice correspondence across this interface and describe the structural change by a homogeneous lattice deformation, S T . For certain transformations, this strain is an invariant plane strain, with the invariant plane defining the planar, coherent interface between parent and product. This group includes the familiar martensitic face-centred cubic to close-packed hexagonal transformation in, for example, cobalt-based alloys, but it is demonstrated here that it also contains transformations giving rise to a broad range of plate-shaped, diffusional precipitation products. For many such transformation products, the transformation strain has a significant shear component and the accommodation of shear strain energy is potentially an important, and often overlooked, factor in both the nucleation and growth of such products. More commonly S T is not an invariant plane strain and, if a planar interface is to be preserved between parent and product, it is necessary to combine S T with a lattice invariant strain to allow a partially-coherent interface that is macroscopically invariant. It is demonstrated that there are diffusional transformation products which also have the geometric and crystallographic features of both of the common forms of partially-coherent martensitic products
New analytical treatment for a kind of two dimensional integrals in ion-atom collisions
International Nuclear Information System (INIS)
Yang Qifeng; Kuang Yurang
1994-01-01
A kind of two-dimensional integrals, separated from two-center matrix elements in ion-atom collisions, is analytically integrated by introducing the Laplace transform into the integrals and expressed by the modified Bessel functions. The traditional Feynman transform is very complicated for this kind of more general integrals related to the excited state capture
Phase transformations in intermetallic phases in zirconium alloys
Energy Technology Data Exchange (ETDEWEB)
Filippov, V. P., E-mail: vpfilippov@mephi.ru [National Research Nuclear University MEPhI (Moscow Engineering Physics Institute) (Russian Federation); Kirichenko, V. G. [Kharkiv National Karazin University (Ukraine); Salomasov, V. A. [National Research Nuclear University MEPhI (Moscow Engineering Physics Institute) (Russian Federation); Khasanov, A. M. [University of North Carolina – Asheville, Chemistry Department (United States)
2017-11-15
Phase change was analyzed in intermetallic compounds of zirconium alloys (Zr – 1.03 at.% Fe; Zr – 0.51 at.% Fe; Zr – 0.51 at.% Fe – M(M = Nb, Sn). Mössbauer spectroscopy on {sup 57}Fe nuclei in backscattering geometry with the registration of the internal conversion electrons and XRD were used. Four types of iron bearing intermetallic compounds with Nb were detected. A relationship was found between the growth process of intermetallic inclusions and segregation of these phases. The growth kinetics of inclusions possibly is not controlled by bulk diffusion, and a lower value of the iron atom’s activation energy of migration can be attributed to the existence of enhanced diffusion paths and interface boundaries.
AC system stabilization via phase shift transformer with thyristor commutation
Energy Technology Data Exchange (ETDEWEB)
Oliveira, Jose Carlos de; Guimaraes, Geraldo Caixeta; Moraes, Adelio Jose [Uberlandia Univ., MG (Brazil); Abreu, Jose Policarpo G. de [Escola Federal de Engenharia de Itajuba, MG (Brazil); Oliveira, Edimar Jose de [Juiz de Fora Univ., MG (Brazil)
1994-12-31
This article aims to present initially the constructive and operative forms of a phase-shift autotransformer which provides both magnitude and phase angle change through thyristor commutation, including a technic to reduce the number of thyristors. Following, it is proposed a control system to make such equipment an efficient AC system stabilizing tool. It is presented some simulation results to show the operation of this transformer in an electrical system. (author) 3 refs., 11 figs., 3 tabs.
Two dimensional NMR studies of polysaccharides
International Nuclear Information System (INIS)
Byrd, R.A.; Egan, W.; Summers, M.F.
1987-01-01
Polysaccharides are very important components in the immune response system. Capsular polysaccharides and lipopolysaccharides occupy cell surface sites of bacteria, play key roles in recognition and some have been used to develop vaccines. Consequently, the ability to determine chemical structures of these systems is vital to an understanding of their immunogenic action. The authors have been utilizing recently developed two-dimensional homonuclear and heteronuclear correlation spectroscopy for unambiguous assignment and structure determination of a number of polysaccharides. In particular, the 1 H-detected heteronuclear correlation experiments are essential to the rapid and sensitive determination of these structures. Linkage sites are determined by independent polarization transfer experiments and multiple quantum correlation experiments. These methods permit the complete structure determination on very small amounts of the polysaccharides. They present the results of a number of structural determinations and discuss the limits of these experiments in terms of their applications to polysaccharides
Two-dimensional materials for ultrafast lasers
International Nuclear Information System (INIS)
Wang Fengqiu
2017-01-01
As the fundamental optical properties and novel photophysics of graphene and related two-dimensional (2D) crystals are being extensively investigated and revealed, a range of potential applications in optical and optoelectronic devices have been proposed and demonstrated. Of the many possibilities, the use of 2D materials as broadband, cost-effective and versatile ultrafast optical switches (or saturable absorbers) for short-pulsed lasers constitutes a rapidly developing field with not only a good number of publications, but also a promising prospect for commercial exploitation. This review primarily focuses on the recent development of pulsed lasers based on several representative 2D materials. The comparative advantages of these materials are discussed, and challenges to practical exploitation, which represent good future directions of research, are laid out. (paper)
Ward identities in two-dimensional gravity
International Nuclear Information System (INIS)
Polchinski, J.
1991-01-01
We study the decoupling of null states in two-dimensional gravity, using methods of critical string theory. We identify a family of null states which fail to decouple due to curvature and boundary terms. This gives relations involving amplitudes at different genus. At genus zero, these determine certain operator product coefficients. At genus one, they determine the partition function. At higher genus, we obtain a relation similar in form to the Painleve equation, but due to an incomplete understanding of a certain ghost/curvature term we do not have a closed relation for the partition function. Our results appear to correspond to the L 0 and L 1 equations in the topological and matrix model approaches. (orig.)
Strategies for Interpreting Two Dimensional Microwave Spectra
Martin-Drumel, Marie-Aline; Crabtree, Kyle N.; Buchanan, Zachary
2017-06-01
Microwave spectroscopy can uniquely identify molecules because their rotational energy levels are sensitive to the three principal moments of inertia. However, a priori predictions of a molecule's structure have traditionally been required to enable efficient assignment of the rotational spectrum. Recently, automated microwave double resonance spectroscopy (AMDOR) has been employed to rapidly generate two dimensional spectra based on transitions that share a common rotational level, which may enable automated extraction of rotational constants without any prior estimates of molecular structure. Algorithms used to date for AMDOR have relied on making several initial assumptions about the nature of a subset of the linked transitions, followed by testing possible assignments by "brute force." In this talk, we will discuss new strategies for interpreting AMDOR spectra, using eugenol as a test case, as well as prospects for library-free, automated identification of the molecules in a volatile mixture.
Modified black holes in two dimensional gravity
International Nuclear Information System (INIS)
Mohammedi, N.
1991-11-01
The SL(2,R)/U(1) gauged WZWN model is modified by a topological term and the accompanying change in the geometry of the two dimensional target space is determined. The possibility of this additional term arises from a symmetry in the general formalism of gauging an isometry subgroup of a non-linear sigma model with an antisymmetric tensor. It is shown, in particular, that the space-time exhibits some general singularities for which the recently found black hole is just a special case. From a conformal field theory point of view and for special values of the unitary representation of SL(2,R), this topological term can be interpreted as a small perturbation by a (1,1) conformal operator of the gauged WZWN action. (author). 26 refs
Thermal properties of two-dimensional materials
International Nuclear Information System (INIS)
Zhang Gang; Zhang Yong-Wei
2017-01-01
Two-dimensional (2D) materials, such as graphene, phosphorene, and transition metal dichalcogenides (e.g., MoS 2 and WS 2 ), have attracted a great deal of attention recently due to their extraordinary structural, mechanical, and physical properties. In particular, 2D materials have shown great potential for thermal management and thermoelectric energy generation. In this article, we review the recent advances in the study of thermal properties of 2D materials. We first review some important aspects in thermal conductivity of graphene and discuss the possibility to enhance the ultra-high thermal conductivity of graphene. Next, we discuss thermal conductivity of MoS 2 and the new strategy for thermal management of MoS 2 device. Subsequently, we discuss the anisotropic thermal properties of phosphorene. Finally, we review the application of 2D materials in thermal devices, including thermal rectifier and thermal modulator. (topical reviews)
Two-dimensional heterostructures for energy storage
Energy Technology Data Exchange (ETDEWEB)
Gogotsi, Yury G. [Drexel Univ., Philadelphia, PA (United States); Pomerantseva, Ekaterina [Drexel Univ., Philadelphia, PA (United States)
2017-06-12
Two-dimensional (2D) materials provide slit-shaped ion diffusion channels that enable fast movement of lithium and other ions. However, electronic conductivity, the number of intercalation sites, and stability during extended cycling are also crucial for building high-performance energy storage devices. While individual 2D materials, such as graphene, show some of the required properties, none of them can offer all properties needed to maximize energy density, power density, and cycle life. Here we argue that stacking different 2D materials into heterostructured architectures opens an opportunity to construct electrodes that would combine the advantages of the individual building blocks while eliminating the associated shortcomings. We discuss characteristics of common 2D materials and provide examples of 2D heterostructured electrodes that showed new phenomena leading to superior electrochemical performance. As a result, we also consider electrode fabrication approaches and finally outline future steps to create 2D heterostructured electrodes that could greatly expand current energy storage technologies.
Two-dimensional electroacoustic waves in silicene
Zhukov, Alexander V.; Bouffanais, Roland; Konobeeva, Natalia N.; Belonenko, Mikhail B.
2018-01-01
In this letter, we investigate the propagation of two-dimensional electromagnetic waves in a piezoelectric medium built upon silicene. Ultrashort optical pulses of Gaussian form are considered to probe this medium. On the basis of Maxwell's equations supplemented with the wave equation for the medium's displacement vector, we obtain the effective governing equation for the vector potential associated with the electromagnetic field, as well as the component of the displacement vector. The dependence of the pulse shape on the bandgap in silicene and the piezoelectric coefficient of the medium was analyzed, thereby revealing a nontrivial triadic interplay between the characteristics of the pulse dynamics, the electronic properties of silicene, and the electrically induced mechanical vibrations of the medium. In particular, we uncovered the possibility for an amplification of the pulse amplitude through the tuning of the piezoelectric coefficient. This property could potentially offer promising prospects for the development of amplification devices for the optoelectronics industry.
Z-transform Zeros in Mixed Phase Deconvolution of Speech
DEFF Research Database (Denmark)
Pedersen, Christian Fischer
2013-01-01
The present thesis addresses mixed phase deconvolution of speech by z-transform zeros. This includes investigations into stability, accuracy, and time complexity of a numerical bijection between time domain and the domain of z-transform zeros. Z-transform factorization is by no means esoteric, bu...... vectors prior to polynomial expansion achieve persistent estimation accuracies near machine epsilon. The associated time complexity cost is effectively countered by proposing a refined Leja ordering obtained via `1 maximization....... phases of the glottal flow derivative is investigated analytically with regard to model parameters and sequence lengths. It is shown that time domain concatenation and convolution of the phases are tightly related. Therefore, immiscibility remains regardless of considering entire glottal flow derivative...... sequences or individual opening and closing sequences. To counter the computational burden associated with z-transform factorization, an adaptive ZZT estimation method is proposed for time-varying z-transforms. The method bounds estimation drifting as accuracy is the cost of lowered time complexity...
Phase-transformation-induced lubrication of earthquake sliding
Green, Harry W.
2017-08-01
Frictional failure is not possible at depth in Earth, hence earthquakes deeper than 30-50 km cannot initiate by overcoming dry friction. Moreover, the frequency distribution of earthquakes with depth is bimodal, suggesting another change of mechanism at about 350 km. Here I suggest that the change at 30-50 km is from overcoming dry friction to reduction of effective stress by dehydration embrittlement and that the change at 350 km is due to desiccation of slabs and initiation by phase-transformation-induced faulting. High-speed friction experiments at low pressure indicate that exceeding dry friction provokes shear heating that leads to endothermic reactions and pronounced weakening. Higher-pressure studies show nanocrystalline gouge accompanying dehydration and the highest pressure experiments initiate by exothermic polymorphic phase transformation. Here I discuss the characteristic nanostructures of experiments on high-speed friction and high-pressure faulting and show that all simulated earthquake systems yield very weak transformation-induced lubrication, most commonly nanometric gouge or melt. I also show that phase-transformation-induced faulting of olivine to spinel can propagate into material previously transformed to spinel, apparently by triggering melting analogous to high-speed friction studies at low pressure. These experiments taken as a whole suggest that earthquakes at all depths slide at low frictional resistance by a self-healing pulse mechanism with rapid strength recovery. This article is part of the themed issue 'Faulting, friction and weakening: from slow to fast motion'.
International Nuclear Information System (INIS)
Henggeler, W.; Boehm, M.
2003-11-01
Both reports - part I by Wolfgang Henggeler and part II by Martin Boehm - serve as a comprehensive basis for the realisation of a PST (phase-space transformation) instrument coupled either to cold or ultra-cold neutrons, respectively. This publication accidentally coincides with the 200 th birthday of the Austrian physicist C.A. Doppler who discovered the principle (i.e., the effect denoted later by his name) giving rise to the phase-space transformation described in the present work. (author)
Phase transformation order-disorder in nonstoichiometric titanium carbide
International Nuclear Information System (INIS)
Vlasov, V.A.; Karmo, Yu.S.; Kustova, L.V.
1986-01-01
Titanium carbide delta-phase is studied using the methods of electric conductivity and differential thermal analysis (DTA). It is shown on the Ti-C system phase diagram that two regions of TiCsub(0.46-0.60) and TiCsub(0.65-1.00) compositions, different in their properties, correspond to delta-phase. Both ordered and disordered phases exist within the TiCsub(0.046-0.60) concentration range, and in equilibrium heating or cooling one phase converts to another at 590 deg C (the first order phase transformation). Samples of the TiCsub(0.65-1.00) composition are characterized by low electric conductivity stability, that is explained by strong titanium carbide electric conductivity sensitivity to defects and impurities
Anomalous compression behavior of germanium during phase transformation
Energy Technology Data Exchange (ETDEWEB)
Yan, Xiaozhi [Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065 (China); Center for High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai 201203 (China); Tan, Dayong [Center for High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai 201203 (China); Guangzhou Institute of Geochemistry, Chinese Academic of Sciences, Guangzhou 510640 (China); Ren, Xiangting [Center for High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai 201203 (China); Yang, Wenge, E-mail: yangwg@hpstar.ac.cn, E-mail: duanweihe@scu.edu.cn [Center for High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai 201203 (China); High Pressure Synergetic Consortium (HPSynC), Geophysical Laboratory, Carnegie Institution of Washington, Argonne, Illinois 60439 (United States); He, Duanwei, E-mail: yangwg@hpstar.ac.cn, E-mail: duanweihe@scu.edu.cn [Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065 (China); Institute of Fluid Physics and National Key Laboratory of Shockwave and Detonation Physic, China Academy of Engineering Physics, Mianyang 621900 (China); Mao, Ho-Kwang [Center for High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai 201203 (China); High Pressure Synergetic Consortium (HPSynC), Geophysical Laboratory, Carnegie Institution of Washington, Argonne, Illinois 60439 (United States); Geophysical Laboratory, Carnegie Institution of Washington, Washington, DC 20015 (United States)
2015-04-27
In this article, we present the abnormal compression and plastic behavior of germanium during the pressure-induced cubic diamond to β-tin structure transition. Between 8.6 GPa and 13.8 GPa, in which pressure range both phases are co-existing, first softening and followed by hardening for both phases were observed via synchrotron x-ray diffraction and Raman spectroscopy. These unusual behaviors can be interpreted as the volume misfit between different phases. Following Eshelby, the strain energy density reaches the maximum in the middle of the transition zone, where the switch happens from softening to hardening. Insight into these mechanical properties during phase transformation is relevant for the understanding of plasticity and compressibility of crystal materials when different phases coexist during a phase transition.
Effect of isochronal annealing on phase transformation studies of ...
Indian Academy of Sciences (India)
Abstract. The effect of isochronal annealing on the phase transformation in iron oxide nanoparticles is reported in this work. Iron oxide nanoparticles were successfully synthesized using an ash supported technique followed by annealing for 2 h at various temperatures between 300 and 700◦C. It was observed using X-ray ...
Effect of isochronal annealing on phase transformation studies of ...
Indian Academy of Sciences (India)
The effect of isochronal annealing on the phase transformation in iron oxide nanoparticles is reported in this work. Iron oxide nanoparticles were successfully synthesized using an ash supported technique followed by annealing for 2 h at various temperatures between 300 and 700° C. It was observed using X-ray diffraction ...
In-situ High Temperature Phase Transformations in Ceramics
2009-07-28
dissertations from U.S. & Canadian institutions. 1861-present in ProQuest 29 SciELO : Scientific Electronic Library Online Identifies scientific...literature published in Spain and coverage dates that vary with resource in SciELO 19 High Temperature Phase Transformations in Oxide Ceramics
The Phase Transformations in Hypoeutectoid Steels Mn-Cr-Ni
Directory of Open Access Journals (Sweden)
RoŻniata E.
2015-04-01
Full Text Available The results of a microstructure and hardness investigations of the hypoeutectoid steels Mn-Cr-Ni, imitating by its chemical composition toughening steels, are presented in the paper. The analysis of the kinetics of phase transformations of undercooled austenite of steels containing different amounts of alloying elements in their chemical composition, constitutes the aim of investigations.
Unsteady detonations driven by first-order phase transformations
Energy Technology Data Exchange (ETDEWEB)
Rabie, R.L.; Fickett, W.
1978-01-01
Reactive waves supported by the energy released during a phase transformation are examined as elementary detonations. It is found that a class of eigenvalue detonations exist containing the well known Chapman-Jouguet solution as a particular case. In general the set of eigenvalue detonations are unsteady in any single inertial reference frame.
Morphological variations in cadmium sulfide nanocrystals without phase transformation.
Dhage, Sanjay R; Colorado, Henry A; Hahn, Thomas
2011-06-14
A very novel phenomenon of morphological variations of cadmium sulfide (CdS) nanorods under the transmission electron microscopy (TEM) beam was observed without structural phase transformation. Environmentally stable and highly crystalline CdS nanorods have been obtained via a chemical bath method. The energy of the TEM beam is believed to have a significant influence on CdS nanorods and may melt and transform them into smaller nanowires. Morphological variations without structural phase transformation are confirmed by recording selected area electron diffraction at various stages. The prepared CdS nanorods have been characterized by X-ray powder diffraction, TEM, UV-Vis spectroscopy, and photoluminescence spectroscopy. The importance of this phenomenon is vital for the potential application for CdS such as smart materials.
Morphological variations in cadmium sulfide nanocrystals without phase transformation
Directory of Open Access Journals (Sweden)
Colorado Henry
2011-01-01
Full Text Available Abstract A very novel phenomenon of morphological variations of cadmium sulfide (CdS nanorods under the transmission electron microscopy (TEM beam was observed without structural phase transformation. Environmentally stable and highly crystalline CdS nanorods have been obtained via a chemical bath method. The energy of the TEM beam is believed to have a significant influence on CdS nanorods and may melt and transform them into smaller nanowires. Morphological variations without structural phase transformation are confirmed by recording selected area electron diffraction at various stages. The prepared CdS nanorods have been characterized by X-ray powder diffraction, TEM, UV-Vis spectroscopy, and photoluminescence spectroscopy. The importance of this phenomenon is vital for the potential application for CdS such as smart materials.
Grain Boundary Phase Transformations in Nanostructured Conducting Oxides
Straumal, B. B.; Myatiev, A. A.; Straumal, P. B.; Mazilkin, A. A.
Nanostructured conducting oxides are very promising for various applications like varistors (doped zinc oxide), electrolytes for the solid oxide fuel cells (SOFC) (ceria, zirconia, yttria), semipermeable membranes, and sensors (perovskite-type oxides). Grain boundary (GB) phases crucially determine the properties of nanograined oxides. GB phase transformations (wetting, prewetting, pseudopartial wetting) proceed in the conducting oxides. Novel GB lines appear in the conventional bulk phase diagrams. They can be used for the tailoring of properties of nanograined conducting oxides, particularly by using the novel synthesis method of liquid ceramics.
Laser sheet dropsizing based on two-dimensional Raman and Mie scattering.
Malarski, Anna; Schürer, Benedikt; Schmitz, Ingo; Zigan, Lars; Flügel, Alexandre; Leipertz, Alfred
2009-04-01
The imaging and quantification of droplet sizes in sprays is a challenging task for optical scientists and engineers. Laser sheet dropsizing (LSDS) combines the two-dimensional information of two different optical processes, one that is proportional to the droplet volume and one that depends on the droplet surface, e.g., Mie scattering. Besides Mie scattering, here we use two-dimensional Raman scattering as the volume-dependent measurement technique. Two different calibration strategies are presented and discussed. Two-dimensional droplet size distributions in a spray have been validated in comparison with the results of point-resolved phase Doppler anemometry (PDA) measurements.
Iterative-Transform Phase Retrieval Using Adaptive Diversity
Dean, Bruce H.
2007-01-01
A phase-diverse iterative-transform phase-retrieval algorithm enables high spatial-frequency, high-dynamic-range, image-based wavefront sensing. [The terms phase-diverse, phase retrieval, image-based, and wavefront sensing are defined in the first of the two immediately preceding articles, Broadband Phase Retrieval for Image-Based Wavefront Sensing (GSC-14899-1).] As described below, no prior phase-retrieval algorithm has offered both high dynamic range and the capability to recover high spatial-frequency components. Each of the previously developed image-based phase-retrieval techniques can be classified into one of two categories: iterative transform or parametric. Among the modifications of the original iterative-transform approach has been the introduction of a defocus diversity function (also defined in the cited companion article). Modifications of the original parametric approach have included minimizing alternative objective functions as well as implementing a variety of nonlinear optimization methods. The iterative-transform approach offers the advantage of ability to recover low, middle, and high spatial frequencies, but has disadvantage of having a limited dynamic range to one wavelength or less. In contrast, parametric phase retrieval offers the advantage of high dynamic range, but is poorly suited for recovering higher spatial frequency aberrations. The present phase-diverse iterative transform phase-retrieval algorithm offers both the high-spatial-frequency capability of the iterative-transform approach and the high dynamic range of parametric phase-recovery techniques. In implementation, this is a focus-diverse iterative-transform phaseretrieval algorithm that incorporates an adaptive diversity function, which makes it possible to avoid phase unwrapping while preserving high-spatial-frequency recovery. The algorithm includes an inner and an outer loop (see figure). An initial estimate of phase is used to start the algorithm on the inner loop, wherein
Isomorphic phase transformation in shocked cerium using molecular dynamics
Energy Technology Data Exchange (ETDEWEB)
Dupont, Virginie [Los Alamos National Laboratory; Germann, Timothy C [Los Alamos National Laboratory; Chen, Shao - Ping [Los Alamos National Laboratory
2010-08-12
Cerium (Ce) undergoes a significant ({approx}16%) volume collapse associated with an isomorphic fcc-fcc phase transformation when subject to compressive loading. We present here a new Embedded Atom Method (EAM) potential for Cerium that models two minima for the two fcc phases. We show results from its use in Molecular Dynamics (MD) simulations of Ce samples subjected to shocks with pressures ranging from 0.5 to 25 GPa. A split wave structure is observed, with an elastic precursor followed by a plastic wave. The plastic wave causes the expected fcc-fcc phase transformation. Comparisons to experiments and MD simulations on Cesium (Cs) indicate that three waves could be observed. The construction of the EAM potential may be the source of the difference.
Nanoindentation-induced phase transformations in silicon at elevated temperatures
International Nuclear Information System (INIS)
Ruffell, S; Bradby, J E; Williams, J S; Munoz-Paniagua, D; Tadayyon, S; Coatsworth, L L; Norton, P R
2009-01-01
The nanoindentation-induced phase transformation behavior of silicon at elevated temperatures (25-150 deg. C) has been studied. Nucleation of Si-III/Si-XII on unloading is enhanced with increasing temperature and at the highest temperatures in an amorphous Si matrix, occurs in a continuous fashion without a pop-out event. Interestingly, for slow unloading at the highest temperatures, formation of Si-III/Si-XII in a crystalline Si matrix was not observed. Elevated temperatures enhance the nucleation of Si-III and Si-XII during unloading but the final composition of the phase transformed zone is also dependent on the thermal stability of the phases in their respective matrices.
Berezinskii–Kosterlitz–Thouless transition and two-dimensional melting
Ryzhov, V. N.; Tareyeva, E. E.; Fomin, Yu D.; Tsiok, E. N.
2017-12-01
The main aspects of the theory of phase transitions in two-dimensional degenerate systems (Berezinskii–Kosterlitz–Thouless, or BKT, transitions) are reviewed in detail, including the transition mechanism, the renormalization group as a tool for describing the transition, and how the transition scenario can possibly depend on the core energy of topological defects (in particular, in thin superconducting films). Various melting scenarios in two-dimensional systems are analyzed, and the current status of actual experiments and computer simulations in the field is examined. Whereas in three dimensions melting always occurs as a single first-order transition, in two dimensions, as shown by Halperin, Nelson, and Young, melting via two continuous BKT transitions with an intermediate hexatic phase characterized by quasi-long-range orientational order is possible. But there is also a possibility for a first-order phase transition to occur. Recently, one further melting scenario, different from that occurring in the Berezinskii–Kosterlitz–Thouless–Halperin–Nelson–Young theory, has been proposed, according to which a solid can melt in two stages: a continuous BKT-type solid–hexatic transition and then a first-order hexatic-phase–isotropic-liquid phase transition. Particular attention is given to the melting scenario as a function of the potential shape and to the random pinning effect on two-dimensional melting. In particular, it is shown that random pinning can alter the melting scenario fundamentally in the case of a first-order transition. Also considered is the melting of systems with potentials having a negative curvature in the repulsion region–potentials that are successfully used in describing the anomalous properties of water in two dimensions. This review is an extended version of the report “Old and new in the physics of phase transitions” presented at the scientific session of the Physical Sciences Division of the Russian Academy of
International Nuclear Information System (INIS)
Yamada, Yoshifumi; Liu, Na; Ito, Satoshi
2006-01-01
The signal in the Fresnel transform technique corresponds to a blurred one of the spin density image. Because the amplitudes of adjacent sampled signals have a high interrelation, the signal amplitude at a point between sampled points can be estimated with a high degree of accuracy even if the sampling is so coarse as to generate aliasing in the reconstructed images. In this report, we describe a new aliasless image reconstruction technique in the phase scrambling Fourier transform (PSFT) imaging technique in which the PSFT signals are converted to Fresnel transform signals by multiplying them by a quadratic phase term and are then interpolated using polynomial expressions to generate fully encoded signals. Numerical simulation using MR images showed that almost completely aliasless images are reconstructed by this technique. Experiments using ultra-low-field PSFT MRI were conducted, and aliasless images were reconstructed from coarsely sampled PSFT signals. (author)
Dynamical heterogeneities and defects in two-dimensional soft colloidal crystals
Meer, Van Der B.; Qi, W.; Sprakel, J.; Filion, L.; Dijkstra, M.
2015-01-01
In this paper we study a two-dimensional system of charged colloidal particles using Brownian dynamics simulations. We determine the phase diagram and investigate the dynamics of this system in the density regime where hexatic and solid phases are stable. We find that the dynamics in these phases
Two-dimensional void reconstruction by neutron transmission
International Nuclear Information System (INIS)
Zakaib, G.D.; Harms, A.A.; Vlachopoulos, J.
1978-01-01
Contemporary algebraic reconstruction methods are utilized in investigating the two-dimensional void distribution in a water analog from neutron transmission measurements. It is sought to ultimately apply these techniques to the determination of time-averaged void distribution in two-phase flow systems as well as for potential usage in neutron radiography. Initially, projection data were obtained from a digitized model of a hypothetical two-phase representation and later from neutron beam traverses across a voided methacrylate plastic model. From 10 to 15 views were incorporated, and decoupling of overlapped measurements was utilized to afford greater resolution. In general, the additive Algebraic Reconstruction Technique yielded the best reconstructions, with others showing promise for noisy data. Results indicate the need for some further development of the method in interpreting real data
Two-dimensional electronic spectroscopy with birefringent wedges
Energy Technology Data Exchange (ETDEWEB)
Réhault, Julien; Maiuri, Margherita; Oriana, Aurelio; Cerullo, Giulio [IFN-CNR, Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano (Italy)
2014-12-15
We present a simple experimental setup for performing two-dimensional (2D) electronic spectroscopy in the partially collinear pump-probe geometry. The setup uses a sequence of birefringent wedges to create and delay a pair of phase-locked, collinear pump pulses, with extremely high phase stability and reproducibility. Continuous delay scanning is possible without any active stabilization or position tracking, and allows to record rapidly and easily 2D spectra. The setup works over a broad spectral range from the ultraviolet to the near-IR, it is compatible with few-optical-cycle pulses and can be easily reconfigured to two-colour operation. A simple method for scattering suppression is also introduced. As a proof of principle, we present degenerate and two-color 2D spectra of the light-harvesting complex 1 of purple bacteria.
Charge ordering in two-dimensional ionic liquids
Perera, Aurélien; Urbic, Tomaz
2018-04-01
The structural properties of model two-dimensional (2D) ionic liquids are examined, with a particular focus on the charge ordering process, with the use of computer simulation and integral equation theories. The influence of the logarithmic form of the Coulomb interaction, versus that of a 3D screened interaction form, is analysed. Charge order is found to hold and to be analogous for both interaction models, despite their very different form. The influence of charge ordering in the low density regime is discussed in relation to well known properties of 2D Coulomb fluids, such as the Kosterlitz-Thouless transition and criticality. The present study suggests the existence of a stable thermodynamic labile cluster phase, implying the existence of a liquid-liquid "transition" above the liquid-gas binodal. The liquid-gas and Kosterlitz-Thouless transitions would then take place inside the predicted cluster phase.
Two-dimensional electronic spectroscopy with birefringent wedges
Réhault, Julien; Maiuri, Margherita; Oriana, Aurelio; Cerullo, Giulio
2014-12-01
We present a simple experimental setup for performing two-dimensional (2D) electronic spectroscopy in the partially collinear pump-probe geometry. The setup uses a sequence of birefringent wedges to create and delay a pair of phase-locked, collinear pump pulses, with extremely high phase stability and reproducibility. Continuous delay scanning is possible without any active stabilization or position tracking, and allows to record rapidly and easily 2D spectra. The setup works over a broad spectral range from the ultraviolet to the near-IR, it is compatible with few-optical-cycle pulses and can be easily reconfigured to two-colour operation. A simple method for scattering suppression is also introduced. As a proof of principle, we present degenerate and two-color 2D spectra of the light-harvesting complex 1 of purple bacteria.
Coulomb interaction and phonons in doped semiconducting and metallic two-dimensional materials
Schönhoff, Gunnar
2017-01-01
Two-dimensional (2D) materials present a rapidly developing field of research with sometimes highly unusual and uniquely two-dimensional physics. Starting with graphene, many recent studies have investigated 2D materials, with results for properties encompassing such different topics as Dirac electrons, charge ordering, and superconductivity. To get closer to a predictive theory of the phases of 2D materials, this thesis systematically tackles the previously unclear problem of the Coulomb int...
On the connection between quantum mechanics and the geometry of two-dimensional strings
Ellis, Jonathan Richard; Nanopoulos, Dimitri V
1991-01-01
On the basis of an area-preserving symmetry in the phase space of a one-dimensional matrix model - believed to describe two-dimensional string theory in a black-hole background which also allows for space-time foam - we give a geometric interpretation of the fact that two-dimensional stringy black holes are consistent with conventional quantum mechanics due to the infinite gauged `W-hair' property that characterises them.
Structural-phase transformations in bentonite after acid treatment
Directory of Open Access Journals (Sweden)
Vlasova M.
2003-01-01
Full Text Available The methods of X-ray diffraction, Fourier transform infra-red spectroscopy (FTIR, X-ray microanalysis, electron microscopy, BET and cation exchange capacity (CEC were used for investigation of the structural-phase transformations in bentonite under the influence of hydrochloric acid and temperature treatment (100-800ºC. It is established that in HCl medium during temperature treatment, dehydration and dehydroxilation of montmorillonite occur. The presence of gypsum and barium chloride results in an intercalation of interlayer space of montmorillonite by Ca and Ba ions Temperature treatment of intercalated montmorillonite leads to the formation of pores.
Directory of Open Access Journals (Sweden)
A. Gribovsky
2012-06-01
Full Text Available The diffraction problem of a three-dimensional elliptic p- polarized Gaussian beam on an aperture array of rectangular holes is solved. The new algorithm for the solution of three-dimensional scattering problems of linearly polarized wave beams on two-dimensional periodic structures is offered. The given algorithm allows exploring of wave beams with any allocation of a field on cross section. The case of oblique incidence of linearly polarized elliptic Gaussian wave beam on two-dimensional periodic structure is viewed. As structure the rectangular waveguides phased antenna array is chosen. The elliptic shape of a beam cross section gives the chance to proportion energy of an incident field in a plane of an antenna array in the chosen direction. The frequency dependence of the reflection coefficient intensity for the Gaussian beam is calculated. For the analysis of patterns of the reflected and transmitted beams in a far zone the frequencies on which the strongest interaction between next waveguides channels is observed have been chosen. Dynamics of patterns transformation of the reflected and transmitted beams depending on the form of cross-section and a polarization direction of an incident beam on different frequencies is investigated. It is determined that shape of the pattern of reflected and transmitted beams (symmetry, asymmetry, bifurcation, amplitude, width depends on chosen spatial orientation of the ellipse axes of the cross section in the incident beam. Frequency ranges, in which the form of the reflected and transmitted beams is not Gaussian, are defined. The nature of transformation of the patterns of scattered beams was examined. Narrowing effect of the pattern of transmitted beam and deformation of the pattern of reflected beam is detected. A physical explanation of these effects is given. The results are presented in the form of two- and three-dimensional patterns of the scattered field of beams in the far field.
Two dimensional estimates from ocean SAR images
Directory of Open Access Journals (Sweden)
J. M. Le Caillec
1996-01-01
Full Text Available Synthetic Aperture Radar (SAR images of the ocean yield a lot of information on the sea-state surface providing that the mapping process between the surface and the image is clearly defined. However it is well known that SAR images exhibit non-gaussian statistics and that the motion of the scatterers on the surface, while the image is being formed, may yield to nonlinearities. The detection and quantification of these nonlinearities are made possible by using Higher Order Spectra (HOS methods and more specifically, bispectrum estimation. The development of the latter method allowed us to find phase relations between different parts of the image and to recognise their level of coupling, i.e. if and how waves of different wavelengths interacted nonlinearly. This information is quite important as the usual models assume strong nonlinearities when the waves are propagating in the azimuthal direction (i.e. along the satellite track and almost no nonlinearities when propagating in the range direction. In this paper, the mapping of the ocean surface to the SAR image is reinterpreted and a specific model (i.e. a Second Order Volterra Model is introduced. The nonlinearities are thus explained as either produced by a nonlinear system or due to waves propagating into selected directions (azimuth or range and interacting during image formation. It is shown that quadratic nonlinearities occur for waves propagating near the range direction while for those travelling in the azimuthal direction the nonlinearities, when present, are mostly due to wave interactions but are almost completely removed by the filtering effect coming from the surface motion itself (azimuth cut-off. An inherent quadratic interaction filtering (azimuth high pass filter is also present. But some other effects, apparently nonlinear, are not detected with the methods described here, meaning that either the usual relation developed for the Ocean-to-SAR transform is somewhat incomplete
The use of Fourier reverse transforms in crystallographic phase refinement
Energy Technology Data Exchange (ETDEWEB)
Ringrose, Sharon [Iowa State Univ., Ames, IA (United States)
1997-10-08
Often a crystallographer obtains an electron density map which shows only part of the structure. In such cases, the phasing of the trial model is poor enough that the electron density map may show peaks in some of the atomic positions, but other atomic positions are not visible. There may also be extraneous peaks present which are not due to atomic positions. A method for determination of crystal structures that have resisted solution through normal crystallographic methods has been developed. PHASER is a series of FORTRAN programs which aids in the structure solution of poorly phased electron density maps by refining the crystallographic phases. It facilitates the refinement of such poorly phased electron density maps for difficult structures which might otherwise not be solvable. The trial model, which serves as the starting point for the phase refinement, may be acquired by several routes such as direct methods or Patterson methods. Modifications are made to the reverse transform process based on several assumptions. First, the starting electron density map is modified based on the fact that physically the electron density map must be non-negative at all points. In practice a small positive cutoff is used. A reverse Fourier transform is computed based on the modified electron density map. Secondly, the authors assume that a better electron density map will result by using the observed magnitudes of the structure factors combined with the phases calculated in the reverse transform. After convergence has been reached, more atomic positions and less extraneous peaks are observed in the refined electron density map. The starting model need not be very large to achieve success with PHASER; successful phase refinement has been achieved with a starting model that consists of only 5% of the total scattering power of the full molecule. The second part of the thesis discusses three crystal structure determinations.
Radiation effects on two-dimensional materials
Energy Technology Data Exchange (ETDEWEB)
Walker, R.C. II; Robinson, J.A. [Department of Materials Science, Penn State, University Park, PA (United States); Center for Two-Dimensional Layered Materials, Penn State, University Park, PA (United States); Shi, T. [Department of Mechanical and Nuclear Engineering, Penn State, University Park, PA (United States); Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, MI (United States); Silva, E.C. [GlobalFoundries, Malta, NY (United States); Jovanovic, I. [Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, MI (United States)
2016-12-15
The effects of electromagnetic and particle irradiation on two-dimensional materials (2DMs) are discussed in this review. Radiation creates defects that impact the structure and electronic performance of materials. Determining the impact of these defects is important for developing 2DM-based devices for use in high-radiation environments, such as space or nuclear reactors. As such, most experimental studies have been focused on determining total ionizing dose damage to 2DMs and devices. Total dose experiments using X-rays, gamma rays, electrons, protons, and heavy ions are summarized in this review. We briefly discuss the possibility of investigating single event effects in 2DMs based on initial ion beam irradiation experiments and the development of 2DM-based integrated circuits. Additionally, beneficial uses of irradiation such as ion implantation to dope materials or electron-beam and helium-beam etching to shape materials have begun to be used on 2DMs and are reviewed as well. For non-ionizing radiation, such as low-energy photons, we review the literature on 2DM-based photo-detection from terahertz to UV. The majority of photo-detecting devices operate in the visible and UV range, and for this reason they are the focus of this review. However, we review the progress in developing 2DMs for detecting infrared and terahertz radiation. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Photodetectors based on two dimensional materials
Zheng, Lou; Zhongzhu, Liang; Guozhen, Shen
2016-09-01
Two-dimensional (2D) materials with unique properties have received a great deal of attention in recent years. This family of materials has rapidly established themselves as intriguing building blocks for versatile nanoelectronic devices that offer promising potential for use in next generation optoelectronics, such as photodetectors. Furthermore, their optoelectronic performance can be adjusted by varying the number of layers. They have demonstrated excellent light absorption, enabling ultrafast and ultrasensitive detection of light in photodetectors, especially in their single-layer structure. Moreover, due to their atomic thickness, outstanding mechanical flexibility, and large breaking strength, these materials have been of great interest for use in flexible devices and strain engineering. Toward that end, several kinds of photodetectors based on 2D materials have been reported. Here, we present a review of the state-of-the-art in photodetectors based on graphene and other 2D materials, such as the graphene, transition metal dichalcogenides, and so on. Project supported by the National Natural Science Foundation of China (Nos. 61377033, 61574132, 61504136) and the State Key Laboratory of Applied Optics, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences.
Two-dimensional atomic crystals beyond graphene
Kaul, Anupama B.
2014-06-01
Carbon-based nanostructures have been the center of intense research and development for more than two decades now. Of these materials, graphene, a two-dimensional (2D) layered material system, has had a significant impact on science and technology over the past decade after monolayers of this material were experimentally isolated in 2004. The recent emergence of other classes of 2D graphene-like layered materials has added yet more exciting dimensions for research in exploring the diverse properties and applications arising from these 2D material systems. For example, hexagonal-BN, a layered material closest in structure to graphene, is an insulator, while NbSe2, a transition metal di-chalcogenide, is metallic and monolayers of other transition metal di-chalcogenides such as MoS2 are direct band-gap semiconductors. The rich spectrum of properties that 2D layered material systems offer can potentially be engineered ondemand, and creates exciting prospects for using such materials in applications ranging from electronics, sensing, photonics, energy harvesting and flexible electronics over the coming years.
Seismic isolation of two dimensional periodic foundations
Energy Technology Data Exchange (ETDEWEB)
Yan, Y.; Mo, Y. L., E-mail: yilungmo@central.uh.edu [University of Houston, Houston, Texas 77004 (United States); Laskar, A. [Indian Institute of Technology Bombay, Powai, Mumbai (India); Cheng, Z.; Shi, Z. [Beijing Jiaotong University, Beijing (China); Menq, F. [University of Texas, Austin, Texas 78712 (United States); Tang, Y. [Argonne National Laboratory, Argonne, Illinois 60439 (United States)
2014-07-28
Phononic crystal is now used to control acoustic waves. When the crystal goes to a larger scale, it is called periodic structure. The band gaps of the periodic structure can be reduced to range from 0.5 Hz to 50 Hz. Therefore, the periodic structure has potential applications in seismic wave reflection. In civil engineering, the periodic structure can be served as the foundation of upper structure. This type of foundation consisting of periodic structure is called periodic foundation. When the frequency of seismic waves falls into the band gaps of the periodic foundation, the seismic wave can be blocked. Field experiments of a scaled two dimensional (2D) periodic foundation with an upper structure were conducted to verify the band gap effects. Test results showed the 2D periodic foundation can effectively reduce the response of the upper structure for excitations with frequencies within the frequency band gaps. When the experimental and the finite element analysis results are compared, they agree well with each other, indicating that 2D periodic foundation is a feasible way of reducing seismic vibrations.
Comparative Two-Dimensional Fluorescence Gel Electrophoresis.
Ackermann, Doreen; König, Simone
2018-01-01
Two-dimensional comparative fluorescence gel electrophoresis (CoFGE) uses an internal standard to increase the reproducibility of coordinate assignment for protein spots visualized on 2D polyacrylamide gels. This is particularly important for samples, which need to be compared without the availability of replicates and thus cannot be studied using differential gel electrophoresis (DIGE). CoFGE corrects for gel-to-gel variability by co-running with the sample proteome a standardized marker grid of 80-100 nodes, which is formed by a set of purified proteins. Differentiation of reference and analyte is possible by the use of two fluorescent dyes. Variations in the y-dimension (molecular weight) are corrected by the marker grid. For the optional control of the x-dimension (pI), azo dyes can be used. Experiments are possible in both vertical and horizontal (h) electrophoresis devices, but hCoFGE is much easier to perform. For data analysis, commercial software capable of warping can be adapted.
Stress distribution in two-dimensional silos
Blanco-Rodríguez, Rodolfo; Pérez-Ángel, Gabriel
2018-01-01
Simulations of a polydispersed two-dimensional silo were performed using molecular dynamics, with different numbers of grains reaching up to 64 000, verifying numerically the model derived by Janssen and also the main assumption that the walls carry part of the weight due to the static friction between grains with themselves and those with the silo's walls. We vary the friction coefficient, the radii dispersity, the silo width, and the size of grains. We find that the Janssen's model becomes less relevant as the the silo width increases since the behavior of the stresses becomes more hydrostatic. Likewise, we get the normal and tangential stress distribution on the walls evidencing the existence of points of maximum stress. We also obtained the stress matrix with which we observe zones of concentration of load, located always at a height around two thirds of the granular columns. Finally, we observe that the size of the grains affects the distribution of stresses, increasing the weight on the bottom and reducing the normal stress on the walls, as the grains are made smaller (for the same total mass of the granulate), giving again a more hydrostatic and therefore less Janssen-type behavior for the weight of the column.
Asymptotics for Two-dimensional Atoms
DEFF Research Database (Denmark)
Nam, Phan Thanh; Portmann, Fabian; Solovej, Jan Philip
2012-01-01
We prove that the ground state energy of an atom confined to two dimensions with an infinitely heavy nucleus of charge $Z>0$ and $N$ quantum electrons of charge -1 is $E(N,Z)=-{1/2}Z^2\\ln Z+(E^{\\TF}(\\lambda)+{1/2}c^{\\rm H})Z^2+o(Z^2)$ when $Z\\to \\infty$ and $N/Z\\to \\lambda$, where $E^{\\TF}(\\lambd......We prove that the ground state energy of an atom confined to two dimensions with an infinitely heavy nucleus of charge $Z>0$ and $N$ quantum electrons of charge -1 is $E(N,Z)=-{1/2}Z^2\\ln Z+(E^{\\TF}(\\lambda)+{1/2}c^{\\rm H})Z^2+o(Z^2)$ when $Z\\to \\infty$ and $N/Z\\to \\lambda$, where $E......^{\\TF}(\\lambda)$ is given by a Thomas-Fermi type variational problem and $c^{\\rm H}\\approx -2.2339$ is an explicit constant. We also show that the radius of a two-dimensional neutral atom is unbounded when $Z\\to \\infty$, which is contrary to the expected behavior of three-dimensional atoms....
Two-dimensional bipolar junction transistors
Gharekhanlou, Behnaz; Khorasani, Sina; Sarvari, Reza
2014-03-01
Recent development in fabrication technology of planar two-dimensional (2D) materials has introduced the possibility of numerous novel applications. Our recent analysis has revealed that by definition of p-n junctions through appropriate patterned doping of 2D semiconductors, ideal exponential I-V characteristics may be expected. However, the theory of 2D junctions turns out to be very different to that of standard bulk junctions. Based on this theory of 2D diodes, we construct for the first time a model to describe 2D bipolar junction transistors (2D-BJTs). We derive the small-signal equivalent model, and estimate the performance of a 2D-BJT device based on graphone as the example material. A current gain of about 138 and maximum threshold frequency of 77 GHz, together with a power-delay product of only 4 fJ per 1 μm lateral width is expected at an operating voltage of 5 V. In addition, we derive the necessary formulae and a new approximate solution for the continuity equation in the 2D configuration, which have been verified against numerical solutions.
Two-dimensional steady unsaturated flow through embedded elliptical layers
Bakker, Mark; Nieber, John L.
2004-12-01
New analytic element solutions are presented for unsaturated, two-dimensional steady flow in vertical planes that include nonoverlapping impermeable elliptical layers and elliptical inhomogeneities. The hydraulic conductivity, which is represented by an exponential function of the pressure head, differs between the inside and outside of an elliptical inhomogeneity; both the saturated hydraulic conductivity and water retention parameters are allowed to differ between the inside and outside. The Richards equation is transformed, through the Kirchhoff transformation and a second standard transformation, into the modified Helmholtz equation. Analytic element solutions are obtained through separation of variables in elliptical coordinates. The resulting equations for the Kirchhoff potential consist of infinite sums of products of exponentials and modified Mathieu functions. In practical applications the series are truncated but still fulfill the differential equation exactly; boundary conditions are met approximately but up to machine accuracy, provided that enough terms are used. The pressure head, saturation, and flow may be computed analytically at any point in the vadose zone. Examples are given of the shadowing effect of an impermeable elliptical layer in a uniform flow field and funnel-type flow between two elliptical inhomogeneities. The presented solutions may be applied to study transport processes in vadose zones containing many impermeable elliptical layers or elliptical inhomogeneities.
Lectures notes on phase transformations in nuclear matter
López, Jorge A
2000-01-01
The atomic nucleus, despite of being one of the smallest objects found in nature, appears to be large enough to experience phase transitions. The book deals with the liquid and gaseous phases of nuclear matter, as well as with the experimental routes to achieve transformation between them.Theoretical models are introduced from the ground up and with increasing complexity to describe nuclear matter from a statistical and thermodynamical point of view. Modern critical phenomena, heavy ion collisions and computational techniques are presented while establishing a linkage to experimental data.The
Plasticity induced by phase transformation in steel: experiment vs modeling
International Nuclear Information System (INIS)
Tahimi, Abdeladhim
2011-01-01
The objectives of this work are: (i) understand the mechanisms and phenomena involved in the plasticity of steels in the presence of a diffusive or martensitic phase transformation. (ii) develop tools for predicting TRIP, which are able to correctly reproduce the macroscopic deformation for cases of complex loading and could also provide information about local elasto-visco-plastic interactions between product and parent phases. To this purpose, new experimental tests are conducted on 35NCD16 steel for austenite to martensite transformation and on 100C6 steel for austenite to pearlite transformation. The elasto viscoplastic properties of austenite and pearlite of the 100C6 steel are characterized through tension compression and relaxation tests. The parameters of macro-homogeneous and crystal-based constitutive laws could then be identified such as to analyse different models with respect to the experimental TRIP: the analytical models of Leblond (1989) and Taleb and Sidoroff (2003) but also, above all, different numerical models which can be distinguished by the prevailing assumptions concerning the local kinetics and the constitutive laws. An extension of the single-grain model dedicated to martensitic transformations developed during the thesis of S. Meftah (2007) is proposed. It consists in introducing the polycrystalline character of the austenite through a process of homogenization based on a self-consistent scheme by calculating the properties of an Equivalent Homogeneous Medium environment (EHM). (author)
Microstructures and phase transformations in interstitial alloys of tantalum
International Nuclear Information System (INIS)
Dahmen, U.
1979-01-01
The analysis of microstructures, phases, and possible ordering of interstitial solute atoms is fundamental to an understanding of the properties of metal-interstitial alloys in general. As evidenced by the controversies on phase transformations in the particular system tantalum--carbon, our understanding of this class of alloys is inferior to our knowledge of substitutional metal alloys. An experimental clarification of these controversies in tantalum was made. Using advanced techniques of electron microscopy and ultrahigh vacuum techology, an understanding of the microstructures and phase transformations in dilute interstitial tantalum--carbon alloys is developed. Through a number of control experiments, the role and sources of interstitial contamination in the alloy preparation (and under operating conditions) are revealed. It is demonstrated that all previously published work on the dilute interstitially ordered phase Ta 64 C can be explained consistently in terms of ordering of the interstitial contaminants oxygen and hydrogen, leading to the formation of the phases Ta 12 O and Ta 2 H
Phase transformation of NiTi alloys during vacuum sintering
Wang, Jun; Hu, Kuang
2017-05-01
The aim of this study is to ascertain the Phase transformation of NiTi alloys during vacuum sintering. NiTi shape memory alloys (SMA) of atomic ratio 1:1 were prepared through press forming and vacuum sintering with the mixture of Ni and Ti powders. Different samples were prepared by changing the sintering time and the sintering temperature. Phase and porosity of the samples were investigated by X-ray diffraction (XRD) and scanning electron microscope (SEM). The results show that in the process of sintering NiTi2 and Ni3Ti phases are formed firstly and then transform into NiTi phase. The quantity of NiTi2 and Ni3Ti phases gradually decreased but not eliminate completely with increase of sintering time. The porosity of specimen sintering at 900°C decreases slightly with increase of sintering time. With increase of sintering time the porosity of specimen sintering at 1050°C decreased firstly and then increased because of generation rich titanium liquid in the process of sintering.
Phase Transformation of Hot Dipped Aluminium during High Temperature Oxidation
International Nuclear Information System (INIS)
Zaifol Samsu; Muhammad Daud; Hishamuddin Husain; Mohd Saari Ripin; Rusni Rejab; Zaiton Selamat; Mohd Shariff Sattar
2014-01-01
Low alloy carbon steel was coated by hot-dipping into a molten aluminum bath. Isothermal oxidations were carried out at 750 degree Celsius in static air to study the oxidation behaviour of the hot-dipped aluminide steel. The phase transformation in the aluminide layer during diffusion at 750 degree Celsius in static air was analyzed by SEM-EDX and XRD. After hot-dip treatment, the coating layers consisted of three phases, where Al, thinner layer of FeAl 3 , and thicker layer of Fe 2 Al 5 were detected from external topcoat to the aluminide/ steel substrate. After oxidation, the Fe 2 Al 5 formed during the immersion process completely transformed to Fe 2 Al 5 , FeAl 2 , FeAl and Al-Fe(Al) phases because of the composition gradient and the chemical diffusion by oxidation. After oxidation, there are some voids were found at the coating/ substrate interface due to the rapid inter-diffusion of iron and aluminium during oxidation. The FeAl phase kept growing with increasing exposure time at 750 degree Celsius, while the Fe 2 Al 5 was consumed during oxidation. After 168 hrs oxidation, the Fe 2 Al 5 phase was going disappeared as the aluminum layer was consumed. (author)
Interaction of two-dimensional magnetoexcitons
Dumanov, E. V.; Podlesny, I. V.; Moskalenko, S. A.; Liberman, M. A.
2017-04-01
We study interaction of the two-dimensional magnetoexcitons with in-plane wave vector k→∥ = 0 , taking into account the influence of the excited Landau levels (ELLs) and of the external electric field perpendicular to the surface of the quantum well and parallel to the external magnetic field. It is shown that the account of the ELLs gives rise to the repulsion between the spinless magnetoexcitons with k→∥ = 0 in the Fock approximation, with the interaction constant g decreasing inverse proportional to the magnetic field strength B (g (0) ∼ 1 / B) . In the presence of the perpendicular electric field the Rashba spin-orbit coupling (RSOC), Zeeman splitting (ZS) and nonparabolicity of the heavy-hole dispersion law affect the Landau quantization of the electrons and holes. They move along the new cyclotron orbits, change their Coulomb interactions and cause the interaction between 2D magnetoexcitons with k→∥ = 0 . The changes of the Coulomb interactions caused by the electrons and by the holes moving with new cyclotron orbits are characterized by some coefficients, which in the absence of the electric field turn to be unity. The differences between these coefficients of the electron-hole pairs forming the magnetoexcitons determine their affinities to the interactions. The interactions between the homogeneous, semihomogeneous and heterogeneous magnetoexcitons forming the symmetric states with the same signs of their affinities are attractive whereas in the case of different sign affinities are repulsive. In the heterogeneous asymmetric states the interactions have opposite signs in comparison with the symmetric states. In all these cases the interaction constant g have the dependence g (0) 1 /√{ B} .
Dynamics of two-dimensional bubbles
Piedra, Saúl; Ramos, Eduardo; Herrera, J. Ramón
2015-06-01
The dynamics of two-dimensional bubbles ascending under the influence of buoyant forces is numerically studied with a one-fluid model coupled with the front-tracking technique. The bubble dynamics are described by recording the position, shape, and orientation of the bubbles as functions of time. The qualitative properties of the bubbles and their terminal velocities are described in terms of the Eötvos (ratio of buoyancy to surface tension) and Archimedes numbers (ratio of buoyancy to viscous forces). The terminal Reynolds number result from the balance of buoyancy and drag forces and, consequently, is not an externally fixed parameter. In the cases that yield small Reynolds numbers, the bubbles follow straight paths and the wake is steady. A more interesting behavior is found at high Reynolds numbers where the bubbles follow an approximately periodic zigzag trajectory and an unstable wake with properties similar to the Von Karman vortex street is formed. The dynamical features of the motion of single bubbles are compared to experimental observations of air bubbles ascending in a water-filled Hele-Shaw cell. Although the comparison is not strictly valid in the sense that the effect of the lateral walls is not incorporated in the model, most of the dynamical properties observed are in good qualitative agreement with the numerical calculations. Hele-Shaw cells with different gaps have been used to determine the degree of approximation of the numerical calculation. It is found that for the relation between the terminal Reynolds number and the Archimedes number, the numerical calculations are closer to the observations of bubble dynamics in Hele-Shaw cells of larger gaps.
Application of phase coherent transform to cloud clutter suppression
Energy Technology Data Exchange (ETDEWEB)
Ng, L.C. [Lawrence Livermore National Lab., CA (United States)
1994-11-15
This paper describes a tracking algorithm using frame-to-frame correlation with frequency domain clutter suppression. Clutter suppression was mechanized via a `Phase Coherent Transform` (PCT) approach. This approach was applied to explore the feasibility of tracking a post-boost rocket from a low earth orbit satellite with real cloud background data. Simulation results show that the PCT/correlation tracking algorithm can perform satisfactorily at signal-to-clutter ratio (SCR) as low as 5 or 7 dB.
Stacking faults and phase transformations in silicon nitride
Milhet, X.; Demenet, J.-L.; Rabier, J.
1998-11-01
From observations of extended dislocation nodes in β silicon nitride, possible stacking fault structures in the basal plane of this compound have been investigated. It has been found that stacking fault structure is locally analogous to α silicon nitride. A phase transformation α to β or β to α can also be achieved by cooperative shear of partial dislocations with 1/3<~ngle1bar{1}00rangle Burgers vectors.
A TECHNIQUE OF IDENTIFICATION OF THE PHASE-DISPLACEMENT GROUP OF THREE-PHASE TRANSFORMER
International Nuclear Information System (INIS)
Aburjania, A.; Begiashvili, V.; Rezan Turan
2007-01-01
It is demonstrated that the arbitrary choice of arbitrarily pisitive direction of induced currents and voltages contradicts the energy conservation law and leads to equilibrium equations and standards making no sense from the physical standpoint. Of 12 recognized standard phase-displacement groups of three-phase transformer, only three have real physical bases. The rest are based on a wrong assumption about mutual biasing of primary and secondary currents. They does not rule out the occurrence of emergency situations and, thus, must be eliminated from use. A new method of identification of the phase-displacement of three-phase transformer is proposed. The method is based on well-known physical laws with consideration for the dual character of the inertia of mutual inductance and exhausts for all possible versions of connection of transformer windings. (author)
Effects of sharp vorticity gradients in two-dimensional hydrodynamic turbulence
DEFF Research Database (Denmark)
Kuznetsov, E.A.; Naulin, Volker; Nielsen, Anders Henry
2007-01-01
The appearance of sharp vorticity gradients in two-dimensional hydrodynamic turbulence and their influence on the turbulent spectra are considered. We have developed the analog of the vortex line representation as a transformation to the curvilinear system of coordinates moving together with the ......The appearance of sharp vorticity gradients in two-dimensional hydrodynamic turbulence and their influence on the turbulent spectra are considered. We have developed the analog of the vortex line representation as a transformation to the curvilinear system of coordinates moving together...... with the divorticity lines. Compressibility of this mapping can be considered as the main reason for the formation of the sharp vorticity gradients at high Reynolds numbers. For two-dimensional turbulence in the case of strong anisotropy the sharp vorticity gradients can generate spectra which fall off as k−3 at large...
Thermally induced phase transformation in multi-phase iron oxide nanoparticles on vacuum annealing
Anupama, A. V.; Keune, W.; Sahoo, B.
2017-10-01
The evolution of magnetic phases in multi-phase iron oxide nanoparticles, synthesized via the transferred arc plasma induced gas phase condensation method, was investigated by X-ray diffraction, vibrating sample magnetometry and 57Fe Mössbauer spectroscopy. The particles are proposed to be consisting of three different iron oxide phases: α-Fe2O3, γ-Fe2O3 and Fe3O4. These nanoparticles were exposed to high temperature (∼935 K) under vacuum (10-3 mbar He pressure), and the thermally induced phase transformations were investigated. The Rietveld refinement of the X-ray diffraction data corroborates the least-squares fitting of the transmission Mössbauer spectra in confirming the presence of Fe3O4, γ-Fe2O3 and α-Fe2O3 phases before the thermal treatment, while only Fe3O4 and α-Fe2O3 phases exist after thermal treatment. On thermal annealing in vacuum, conversion from γ-Fe2O3 to Fe3O4 and α-Fe2O3 was observed. Interestingly, we have observed a phase transformation occurring in the temperature range ∼498 K-538 K, which is strikingly lower than the phase transformation temperature of γ-Fe2O3 to α-Fe2O3 (573-623 K) in air. Combining the results of Rietveld refinement of X-ray diffraction patterns and Mössbauer spectroscopy, we have attributed this phase transformation to the phase conversion of a metastable "defected and strained" d-Fe3O4 phase, present in the as-prepared sample, to the α-Fe2O3 phase. Stabilization of the phases by controlling the phase transformations during the use of different iron-oxide nanoparticles is the key factor to select them for a particular application. Our investigation provides insight into the effect of temperature and chemical nature of the environment, which are the primary factors governing the phase stability, suitability and longevity of the iron oxide nanomaterials prepared by the gas-phase condensation method for various applications.
Development of Two-Dimensional NMR
Indian Academy of Sciences (India)
IAS Admin
The development of Fourier transform NMR in the mid. 1960's, did parallel processing of the collection of NMR data, increased the signal/noise ratio by two orders of magnitude and made it possible to record the proton NMR spectra of small proteins which contain hundreds of resonances. The assignment of these ...
Intruder Motion in Two-Dimensional Shaken Granular Beds
International Nuclear Information System (INIS)
Ma Huan-Ping; Lv Yong-Jun; Zheng Ning; Shi Qing-Fan; Li Liang-Sheng
2014-01-01
The dynamical behavior of an intruder immersed in a two-dimensional shaken granular bed is experimentally investigated. With two types of background particles, f−Γ phase diagrams depicting the intruder's motion are measured and compared. It is found that even with the same size and density ratio of the intruder to the background particles, the intruder exhibits a distinct behavior at given vibrational conditions: rising behavior in one granular bed; sinking behavior in another granular bed. We slightly tune the size and density ratio to confirm the reliability of the experimental results. In addition, we examine the influences of interstitial air, convection and the initial position on the intruder's motion, speculating that the opposite motion could be traced to the material properties of the background particles
Two-dimensional random arrays for real time volumetric imaging
DEFF Research Database (Denmark)
Davidsen, Richard E.; Jensen, Jørgen Arendt; Smith, Stephen W.
1994-01-01
real time volumetric imaging system, which employs a wide transmit beam and receive mode parallel processing to increase image frame rate. Depth-of-field comparisons were made from simulated on-axis and off-axis beamplots at ranges from 30 to 160 mm for both coaxial and offset transmit and receive......Two-dimensional arrays are necessary for a variety of ultrasonic imaging techniques, including elevation focusing, 2-D phase aberration correction, and real time volumetric imaging. In order to reduce system cost and complexity, sparse 2-D arrays have been considered with element geometries...... selected ad hoc, by algorithm, or by random process. Two random sparse array geometries and a sparse array with a Mills cross receive pattern were simulated and compared to a fully sampled aperture with the same overall dimensions. The sparse arrays were designed to the constraints of the Duke University...
Two-dimensional silica opens new perspectives
Büchner, Christin; Heyde, Markus
2017-12-01
In recent years, silica films have emerged as a novel class of two-dimensional (2D) materials. Several groups succeeded in epitaxial growth of ultrathin SiO2 layers using different growth methods and various substrates. The structures consist of tetrahedral [SiO4] building blocks in two mirror symmetrical planes, connected via oxygen bridges. This arrangement is called a silica bilayer as it is the thinnest 2D arrangement with the stoichiometry SiO2 known today. With all bonds saturated within the nano-sheet, the interaction with the substrate is based on van der Waals forces. Complex ring networks are observed, including hexagonal honeycomb lattices, point defects and domain boundaries, as well as amorphous domains. The network structures are highly tuneable through variation of the substrate, deposition parameters, cooling procedure, introducing dopants or intercalating small species. The amorphous networks and structural defects were resolved with atomic resolution microscopy and modeled with density functional theory and molecular dynamics. Such data contribute to our understanding of the formation and characteristic motifs of glassy systems. Growth studies and doping with other chemical elements reveal ways to tune ring sizes and defects as well as chemical reactivities. The pristine films have been utilized as molecular sieves and for confining molecules in nanocatalysis. Post growth hydroxylation can be used to tweak the reactivity as well. The electronic properties of silica bilayers are favourable for using silica as insulators in 2D material stacks. Due to the fully saturated atomic structure, the bilayer interacts weakly with the substrate and can be described as quasi-freestanding. Recently, a mm-scale film transfer under structure retention has been demonstrated. The chemical and mechanical stability of silica bilayers is very promising for technological applications in 2D heterostacks. Due to the impact of this bilayer system for glass science
Two-Dimensional Planetary Surface Landers
National Aeronautics and Space Administration — We propose to develop a new landing approach that significantly reduces development time and obviates the most complicated, most expensive and highest-risk phase of...
Light-Induced Two-Dimensional FT-IR Spectroscopy of BacterioRhodopsin
Kosters, P.G.H.; de Vries, A.H.B.; Kooyman, R.P.H.
2000-01-01
Two-dimensional Fourier transform infrared (2D FT-IR) spectroscopy was applied to study the slower states of the membrane protein bacterioRhodopsin (bR) photocycle, with bR adsorbed on a ZnSe attenuated total reflectance (ATR) crystal. The M and the N states of the bR photocycle could be
Two-Dimensional Interactions in a Class of Tensor Gauge Fields from Local BRST Cohomology
Babalic, E M; Cioroianu, E M; Negru, I; Sararu, S C
2003-01-01
Lagrangian interactions in a class of two-dimensional tensor gauge field theory are derived by means of deforming the solution to the master equation with specific cohomological techniques. Both the gauge transformations and their algebra are deformed. The gauge algebra of the coupled model is open.
Use of real Dirac matrices in two-dimensional coupled linear optics
Directory of Open Access Journals (Sweden)
C. Baumgarten
2011-11-01
Full Text Available The Courant-Snyder theory for two-dimensional coupled linear optics is presented, based on the systematic use of the real representation of the Dirac matrices. Since any real 4×4 matrix can be expressed as a linear combination of these matrices, the presented ansatz allows for a comprehensive and complete treatment of two-dimensional linear coupling. A survey of symplectic transformations in two dimensions is presented. A subset of these transformations is shown to be identical to rotations and Lorentz boosts in Minkowski space-time. The transformation properties of the classical state vector are formulated and found to be analog to those of a Dirac spinor. The equations of motion for a relativistic charged particle—the Lorentz force equations—are shown to be isomorph to envelope equations of two-dimensional linear coupled optics. A universal and straightforward method to decouple two-dimensional harmonic oscillators with constant coefficients by symplectic transformations is presented, which is based on this isomorphism. The method yields the eigenvalues (i.e., tunes and eigenvectors and can be applied to a one-turn transfer matrix or directly to the coefficient matrix of the linear differential equation.
Phase transformations and thermodynamics of aluminum-based metallic glasses
Gao, Changhua (Michael)
This thesis examines the thermodynamics and associated kinetics and phase transformations of the glass forming Al-Ni-Gd and Al-Fe-Gd systems. In order to fully understand the unique glass forming ability (GFA) of Al-based metallic glasses, the ternary Al-Fe-Gd and Al-Ni-Gd systems in their Al-rich corners were examined experimentally to assist in a thermodynamic assessment. The solid-state phase equilibria are determined using XRD and TEM-EDS techniques. While this work basically confirms the solid-state equilibria in Al-Fe-Gd reported previously, the ternary phase in Al-Ni-Gd system has been identified to be Al15Ni3Gd2 rather than Al16Ni 3Gd reported in the literature. DTA analysis of 24 alloys in the Al-Fe-Gd system and 42 alloys in the Al-Ni-Gd system have yielded critical temperatures pertaining to the solid-liquid transition. Based on these data and information from the literature, a self-consistent thermodynamic database for these systems has been developed using the CALPHAD technique. Parameters describing the Gibbs free energy for various phases of the Al-Gd, Al-Fe-Gd and Al-Ni-Gd systems are manually optimized in this study. Once constructed, the database is used to calculate driving forces for nucleation of crystalline phases which can qualitatively explain the phase formation sequence during crystallization at low temperatures. It was also confirmed that alloy compositions with the lowest Gibbs free energy difference between the equilibrium state and undercooled liquid state exhibit better GFA than other chemistries. Based on 250°C isothermal devitrification phase transformations of 17 Al-Ni-Gd alloys, a phase formation sequence map is constructed. Fcc-Al nanocrystals are formed first in most of the alloys studied, but eutectic crystallization of a metastable phase and fcc-Al is also observed. Addition of Al or Ni promotes fcc-Al phase formation, while increasing Gd suppresses it. The continuous heating DSC scans revealed that crystallization in Al
Two-dimensional maximum entropy reconstruction of radio brightness
International Nuclear Information System (INIS)
Wernecke, S.J.
1977-01-01
A procedure is described for maximum entropy reconstruction of two-dimensional radio brightness maps from noisy interferometer measurements. The method defines a map that obeys the nonnegativity constraint and is, in a sense, the smoothest of all brightness distributions that agree with the visibility measurements within the errors of observation. This approach acknowledges the fact that signal-to-noise considerations have a strong influence on useful resolution; fine structure appears only to the extent justified by measurement accuracy. Iterative computing is needed to find the maximum entropy image. It is shown that the primary computational burden of maximum entropy reconstruction involves calculations that are efficiently performed by fast Fourier transform techniques. Different techniques are used depending on whether visibility data are irregularly distributed in the u,ν plane or interpolated onto a rectangular lattice prior to reconstruction. The efficiency of the fast Fourier transform provides a tremendous computational advantage with the result that maximum entropy reconstruction on a moderately large grid (64 x 64) is practicable at reasonable cost. Several comparative examples are shown, and some of the limitations of the present theory of maximum entropy imaging are identified
Energy Technology Data Exchange (ETDEWEB)
Kuepers, Michael; Konze, Philipp M.; Maintz, Stefan; Steinberg, Simon [Institute of Inorganic Chemistry, Chair of Solid-State and Quantum Chemistry, RWTH Aachen University (Germany); Mio, Antonio M.; Cojocaru-Miredin, Oana; Zhu, Min; Wuttig, Matthias [I. Physikalisches Institut, RWTH Aachen University (Germany); Mueller, Merlin; Mayer, Joachim [Gemeinschaftslabor fuer Elektronenmikroskopie, RWTH Aachen University (Germany); Luysberg, Martina [Ernst-Ruska-Center, Forschungszentrum Juelich GmbH (Germany); Dronskowski, Richard [Institute of Inorganic Chemistry, Chair of Solid-State and Quantum Chemistry, RWTH Aachen University (Germany); Juelich-Aachen Research Alliance (JARA-HPC), RWTH Aachen University (Germany)
2017-08-14
A hexagonal phase in the ternary Ge-Se-Te system with an approximate composition of GeSe{sub 0.75}Te{sub 0.25} has been known since the 1960s but its structure has remained unknown. We have succeeded in growing single crystals by chemical transport as a prerequisite to solve and refine the Ge{sub 4}Se{sub 3}Te structure. It consists of layers that are held together by van der Waals type weak chalcogenide-chalcogenide interactions but also display unexpected Ge-Ge contacts, as confirmed by electron microscopy analysis. The nature of the electronic structure of Ge{sub 4}Se{sub 3}Te was characterized by chemical bonding analysis, in particular by the newly introduced density of energy (DOE) function. The Ge-Ge bonding interactions serve to hold electrons that would otherwise go into antibonding Ge-Te contacts. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)
Experimental demonstration of conformal phased array antenna via transformation optics.
Lei, Juan; Yang, Juxing; Chen, Xi; Zhang, Zhiya; Fu, Guang; Hao, Yang
2018-02-28
Transformation Optics has been proven a versatile technique for designing novel electromagnetic devices and it has much wider applicability in many subject areas related to general wave equations. Among them, quasi-conformal transformation optics (QCTO) can be applied to minimize anisotropy of transformed media and has opened up the possibility to the design of broadband antennas with arbitrary geometries. In this work, a wide-angle scanning conformal phased array based on all-dielectric QCTO lens is designed and experimentally demonstrated. Excited by the same current distribution as such in a conventional planar array, the conformal system in presence of QCTO lens can preserve the same radiation characteristics of a planar array with wide-angle beam-scanning and low side lobe level (SLL). Laplace's equation subject to Dirichlet-Neumann boundary conditions is adopted to construct the mapping between the virtual and physical spaces. The isotropic lens with graded refractive index is realized by all-dielectric holey structure after an effective parameter approximation. The measurements of the fabricated system agree well with the simulated results, which demonstrate its excellent wide-angle beam scanning performance. Such demonstration paves the way to a robust but efficient array synthesis, as well as multi-beam and beam forming realization of conformal arrays via transformation optics.
Energy Technology Data Exchange (ETDEWEB)
Ayari, Taha; Li, Xin; Voss, Paul L.; Ougazzaden, Abdallah, E-mail: aougazza@georgiatech-metz.fr [School of Electrical and Computer Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Georgia Tech Lorraine, UMI 2958, Georgia Tech-CNRS, 57070 Metz (France); Sundaram, Suresh; El Gmili, Youssef [Georgia Tech Lorraine, UMI 2958, Georgia Tech-CNRS, 57070 Metz (France); Salvestrini, Jean Paul [Georgia Tech Lorraine, UMI 2958, Georgia Tech-CNRS, 57070 Metz (France); Université de Lorraine, LMOPS, EA 4423, 57070 Metz (France)
2016-04-25
Recent advances in epitaxial growth have led to the growth of III-nitride devices on 2D layered h-BN. This advance has the potential for wafer-scale transfer to arbitrary substrates, which could improve the thermal management and would allow III-N devices to be used more flexibly in a broader range of applications. We report wafer scale exfoliation of a metal organic vapor phase epitaxy grown InGaN/GaN Multi Quantum Well (MQW) structure from a 5 nm thick h-BN layer that was grown on a 2-inch sapphire substrate. The weak van der Waals bonds between h-BN atomic layers break easily, allowing the MQW structure to be mechanically lifted off from the sapphire substrate using a commercial adhesive tape. This results in the surface roughness of only 1.14 nm on the separated surface. Structural characterizations performed before and after the lift-off confirm the conservation of structural properties after lift-off. Cathodoluminescence at 454 nm was present before lift-off and 458 nm was present after. Electroluminescence near 450 nm from the lifted-off structure has also been observed. These results show that the high crystalline quality ultrathin h-BN serves as an effective sacrificial layer—it maintains performance, while also reducing the GaN buffer thickness and temperature ramps as compared to a conventional two-step growth method. These results support the use of h-BN as a low-tack sacrificial underlying layer for GaN-based device structures and demonstrate the feasibility of large area lift-off and transfer to any template, which is important for industrial scale production.
Transmission Network Expansion Planning Considering Phase-Shifter Transformers
Directory of Open Access Journals (Sweden)
Celso T. Miasaki
2012-01-01
Full Text Available This paper presents a novel mathematical model for the transmission network expansion planning problem. Main idea is to consider phase-shifter (PS transformers as a new element of the transmission system expansion together with other traditional components such as transmission lines and conventional transformers. In this way, PS are added in order to redistribute active power flows in the system and, consequently, to diminish the total investment costs due to new transmission lines. Proposed mathematical model presents the structure of a mixed-integer nonlinear programming (MINLP problem and is based on the standard DC model. In this paper, there is also applied a specialized genetic algorithm aimed at optimizing the allocation of candidate components in the network. Results obtained from computational simulations carried out with IEEE-24 bus system show an outstanding performance of the proposed methodology and model, indicating the technical viability of using these nonconventional devices during the planning process.
Light activated phase transformation of metastable tetragonal nanocrystalline zirconia
DEFF Research Database (Denmark)
Nielsen, Mette Skovgaard; Almdal, Kristoffer; van Lelieveld, A
2012-01-01
This study searches for small molecules, which can be generated by photoacid generators (PAGs) capable of inducing the tetragonal-to-monoclinic transformation in zirconia nanocrystals. Metastable tetragonal zirconia nanocrystals were exposed in alcohol suspension. X-ray diffraction analysis showed...... that water, HCl, HF, and NH3, all initiate phase transformation of tetragonal zirconia at room temperature, whereas NBu4Cl and NBu4OH do not. 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine) was the most efficient (monoclinic volume fraction reached 0.57) out of the four tested PAGs....... For dispersion in a dimethacrylate matrix together with zirconia crystals, a monoclinic volume fraction of 0.19 was observed after 2 min of exposure to light, increasing to 0.6 after 30 min....
Two Dimensional Super QCD on a Lattice
Energy Technology Data Exchange (ETDEWEB)
Catterall, Simon [Syracuse U.; Veernala, Aarti [Fermilab
2017-10-04
We construct a lattice theory with one exact supersymmetry which consists of fields transforming in both the adjoint and fundamental representations of a U(Nc) gauge group. In addition to gluons and gluinos, the theory contains Nf flavors of fermion in the fundamental representation along with their scalar partners and is invariant under a global U(Nf) flavor symmetry. The lattice action contains an additional Fayet-Iliopoulos term which can be used to generate a scalar potential. We perform numerical simulations that corroborate the theoretical expectation that supersymmetry is spontaneously broken for Nf
Lie algebra contractions on two-dimensional hyperboloid
International Nuclear Information System (INIS)
Pogosyan, G. S.; Yakhno, A.
2010-01-01
The Inoenue-Wigner contraction from the SO(2, 1) group to the Euclidean E(2) and E(1, 1) group is used to relate the separation of variables in Laplace-Beltrami (Helmholtz) equations for the four corresponding two-dimensional homogeneous spaces: two-dimensional hyperboloids and two-dimensional Euclidean and pseudo-Euclidean spaces. We show how the nine systems of coordinates on the two-dimensional hyperboloids contracted to the four systems of coordinates on E 2 and eight on E 1,1 . The text was submitted by the authors in English.
International Nuclear Information System (INIS)
Wen Jihong; Yu, Dianlong; Wang Gang; Zhao Honggang; Liu Yaozong; Wen Xisen
2007-01-01
The directional propagation characteristics of elastic wave during pass bands in two-dimensional thin plate phononic crystals are analyzed by using the lumped-mass method to yield the phase constant surface. The directions and regions of wave propagation in phononic crystals for certain frequencies during pass bands are predicted with the iso-frequency contour lines of the phase constant surface, which are then validated with the harmonic responses of a finite two-dimensional thin plate phononic crystals with 16x16 unit cells. These results are useful for controlling the wave propagation in the pass bands of phononic crystals
Program for three-phase power transformer design
Directory of Open Access Journals (Sweden)
Olivian Chiver
2011-12-01
Full Text Available This paper presents a program developed for designing three-phase power transformers used in power systems. The program was developed in Visual Basic because this programming language allows us to realize a friendly and suggestive interface with minimum effort. The second reason, which is the most important, is to use Visual Basic, because this language is recognized by the used finite elements analysis (FEA software, MagNet produced by Infolytica. This software package is designed for calculation of the magnetic field of electromagnetic devices and machines. The 3D components of the numerical model are carried out using CATIA program, automatically, based on the calculated main geometric data.
A Transformer-less Single Phase Inverter For photovoltaic Systems
DEFF Research Database (Denmark)
Mostaan, Ali; Alizadeh, Ebrahim; Qu, Ying
2017-01-01
A single phase transformer-less inverter is introduced in this paper. The negative polarities of the input voltage and output terminal have common ground. Therefore, the leakage current problem that is common in PV systems is eliminated naturally. In addition, the proposed inverter has fewer...... components compared with its counterparts and only one switch conducts during the active states which enhance the inverter efficiency. The proposed inverter is analyzed in details and compared with some existing topologies. The performance of the proposed inverter is validated using the simulation results....
On the critical behaviour of two-dimensional liquid crystals
Directory of Open Access Journals (Sweden)
A.l. Fariñas-Sánchez
2010-01-01
Full Text Available The Lebwohl-Lasher (LL model is the traditional model used to describe the nematic-isotropic transition of real liquid crystals. In this paper, we develop a numerical study of the temperature behaviour and of finite-size scaling of the two-dimensional (2D LL-model. We discuss two possible scenarios. In the first one, the 2D LL-model presents a phase transition similar to the topological transition appearing in the 2D XY-model. In the second one, the 2D LL-model does not exhibit any critical transition, but its low temperature behaviour is rather characterized by a crossover from a disordered phase to an ordered phase at zero temperature. We realize and discuss various comparisons with the 2D XY-model and the 2D Heisenberg model. Having added finite-size scaling behaviour of the order parameter and conformal mapping of order parameter profile to previous studies, we analyze the critical scaling of the probability distribution function, hyperscaling relations and stiffness order parameter and conclude that the second scenario (no critical transition is the most plausible.
Double Dirac cone in two-dimensional phononic crystals beyond circular cells
Dai, Hongqing; Liu, Tingting; Jiao, Junrui; Xia, Baizhan; Yu, Dejie
2017-04-01
A double Dirac cone plays a significant role in the design of zero-refractive-index metamaterials without phase variation and topological insulators with pseudospin states. We present a study on the formation of a double Dirac cone in two-dimensional phononic crystals consisting of either hexagonal or triangular columns in air. We arranged hexagonal and triangular columns separately in a honeycomb lattice to explore the influence of phononic crystal symmetry on the formation of the double Dirac cone. The results show that phononic crystals forming a honeycomb lattice with C6v or C6 symmetry induce an accidental degeneracy, but C3v and C3 cannot. We also demonstrate that by varying the filling ratio of the hexagonal columns, a topological phase transformation induced by energy band inversion with dipolar and quadrupolar states occurs near the double Dirac cone. Transmission properties for acoustic tunneling and waveform shaping are confirmed in two numerical simulation examples. A discussion is given on the formation of the double Dirac cone in different phononic crystal symmetries in a honeycomb lattice. The conclusions suggest a new route for designing topological and zero-refractive-index acoustic devices.
Phase Transformations and Phase Equilibria in the Fe-N System at Temperatures below 573 K
DEFF Research Database (Denmark)
Malinov, S.; Böttger, A.J.; Mittemeijer, E.J.
2001-01-01
The phase transformations of homogeneous Fe-N alloys of nitrogen contents from 10 to 26 at. pct were investigated by means of X-ray diffraction analysis upon aging in the temperature range from 373 to 473 K. It was found that precipitation of alpha double prime-Fe16N2 below 443 K does not only oc...
Modeling of diffusional phase transformation in multi-component systems with stoichiometric phases
Czech Academy of Sciences Publication Activity Database
Svoboda, Jiří; Fischer, F. D.; Abart, R.
2010-01-01
Roč. 58, č. 8 (2010), s. 2905-2911 ISSN 1359-6454 R&D Projects: GA MŠk(CZ) OC10029 Institutional research plan: CEZ:AV0Z20410507 Keywords : Interdiffusion * Intermetallics * Phase transformation kinetics Subject RIV: BJ - Thermodynamics Impact factor: 3.781, year: 2010
Phase Stability and Transformations in Vanadium Oxide Nanocrystals
Bergerud, Amy Jo
Vanadium oxides are both fascinating and complex, due in part to the many compounds and phases that can be stabilized as well as the phase transformations which occur between them. The metal to insulator transitions (MITs) that take place in vanadium oxides are particularly interesting for both fundamental and applied study as they can be induced by a variety of stimuli ( i.e., temperature, pressure, doping) and utilized in many applications (i.e., smart windows, sensors, phase change memory). Nanocrystals also tend to demonstrate interesting phase behavior, due in part to the enhanced influence of surface energy on material thermodynamics. Vanadium oxide nanocrystals are thus expected to demonstrate very interesting properties in regard to phase stability and phase transformations, although synthesizing vanadium oxides in nanocrystal form remains a challenge. Vanadium sesquioxide (V2O3) is an example of a material that undergoes a MIT. For decades, the low temperature monoclinic phase and high temperature corundum phase were the only known crystal structures of V2O3. However, in 2011, a new metastable polymorph of V2O3 was reported with a cubic, bixbyite crystal structure. In Chapter 2, a colloidal route to bixbyite V2O 3 nanocrystals is presented. In addition to being one of the first reported observations of the bixbyite phase in V2O3, it is also one of the first successful colloidal syntheses of any of the vanadium oxides. The nanocrystals possess a flower-like morphology, the size and shape of which are dependent on synthesis time and temperature, respectively. An aminolysis reaction mechanism is determined from Fourier transform infrared spectroscopy data and the bixbyite crystal structure is confirmed by Rietveld refinement of X-ray diffraction (XRD) data. Phase stability is assessed in both air and inert environments, confirming the metastable nature of the material. Upon heating in an inert atmosphere above 700°C, the nanocrystals irreversibly transform
One- and two-dimensional fluids properties of smectic, lamellar and columnar liquid crystals
Jakli, Antal
2006-01-01
Smectic and lamellar liquid crystals are three-dimensional layered structures in which each layer behaves as a two-dimensional fluid. Because of their reduced dimensionality they have unique physical properties and challenging theoretical descriptions, and are the subject of much current research. One- and Two-Dimensional Fluids: Properties of Smectic, Lamellar and Columnar Liquid Crystals offers a comprehensive review of these phases and their applications. The book details the basic structures and properties of one- and two-dimensional fluids and the nature of phase transitions. The later chapters consider the optical, magnetic, and electrical properties of special structures, including uniformly and non-uniformly aligned anisotropic films, lyotropic lamellar systems, helical and chiral structures, and organic anisotropic materials. Topics also include typical and defective features, magnetic susceptibility, and electrical conductivity. The book concludes with a review of current and potential applications ...
Optical image encryption in Fresnel domain using spiral phase transform
Kumar, Ravi; Bhaduri, Basanta
2017-09-01
In this study, we propose a new nonlinear optical image encryption technique using spiral phase transform (SPT). First, the primary image is phase encoded and multiplied with a random amplitude mask (RAM), and using power function, the product is then powered to m. This powered output is Fresnel propagated with distance z 1 and then modulated with a random phase mask (RPM). The modulated image is further Fresnel propagated with distance z 2. Similarly, a security image is also modulated with another RAM and then Fresnel propagated with distance z 3. Next, the two modulated images after Fresnel propagations, are interfered and further Fresnel propagated with distance z 4 to get a complex image. Finally, this complex image is SPT with particular spiral phase function (SPF), to get the final encrypted image for transmission. In the proposed technique, the security keys are Fresnel propagation distances, the security image, RPM, RAMs, power order, m, and order of SPF, q. Numerical simulation results confirm the validity and effectiveness of the proposed technique. The proposed technique is robust against noise and brutal force attacks.
Explorative data analysis of two-dimensional electrophoresis gels
DEFF Research Database (Denmark)
Schultz, J.; Gottlieb, D.M.; Petersen, Marianne Kjerstine
2004-01-01
Methods for classification of two-dimensional (2-DE) electrophoresis gels based on multivariate data analysis are demonstrated. Two-dimensional gels of ten wheat varieties are analyzed and it is demonstrated how to classify the wheat varieties in two qualities and a method for initial screening...
Optimizing separations in online comprehensive two-dimensional liquid chromatography
Pirok, Bob W.J.; Gargano, Andrea F.G.; Schoenmakers, Peter J.
2018-01-01
Online comprehensive two-dimensional liquid chromatography has become an attractive option for the analysis of complex nonvolatile samples found in various fields (e.g. environmental studies, food, life, and polymer sciences). Two-dimensional liquid chromatography complements the highly popular
Beginning Introductory Physics with Two-Dimensional Motion
Huggins, Elisha
2009-01-01
During the session on "Introductory College Physics Textbooks" at the 2007 Summer Meeting of the AAPT, there was a brief discussion about whether introductory physics should begin with one-dimensional motion or two-dimensional motion. Here we present the case that by starting with two-dimensional motion, we are able to introduce a considerable…
Two-dimensional black holes and non-commutative spaces
International Nuclear Information System (INIS)
Sadeghi, J.
2008-01-01
We study the effects of non-commutative spaces on two-dimensional black hole. The event horizon of two-dimensional black hole is obtained in non-commutative space up to second order of perturbative calculations. A lower limit for the non-commutativity parameter is also obtained. The observer in that limit in contrast to commutative case see two horizon
Monolithic and core-shell columns in comprehensive two-dimensional HPLC: a review.
Jandera, Pavel; Hájek, Tomáš; Staňková, Magda
2015-01-01
The crucial point affecting the separation time in comprehensive two-dimensional liquid chromatography is the performance of the column used in the second dimension, which should allow highly efficient fast chromatographic separations in the short time available for the analysis of fractions transferred from the first to the second dimension (often 1 min or less). This can be accomplished on short columns packed with sub-2-μm particles, at the cost of very high operation pressure. Core-shell or silica monolithic columns have better permeability, and their use in the second dimension of comprehensive two-dimensional liquid chromatography with conventional liquid chromatography instrumentation is continuously increasing. Monolithic columns based on organic polymer matrices offer a wide selection of stationary phase chemistries, including new hydrophilic interaction liquid chromatography materials, which can be used in the design of novel two-dimensional separations. Some organic polymer monolithic materials offer a dual retention mechanism (reversed-phase hydrophilic interaction liquid chromatography), so a single column can be used in alternating runs for highly orthogonal off-line two-dimensional and even three-dimensional separations. In the present work, the properties of core-shell and silica gel monolithic columns are briefly summarized and their applications in two-dimensional separations of peptides, proteins, oligomer surfactants, fats and oils, carotenoids, phenolic and flavone compounds in plant extracts, food, and beverages are reviewed.
Two-dimensional modeling of conduction-mode laser welding
International Nuclear Information System (INIS)
Russo, A.J.
1984-01-01
WELD2D is a two-dimensional finite difference computer program suitable for modeling the conduction-mode welding process when the molten weld pool motion can be neglected. The code is currently structured to treat butt-welded geometries in a plane normal to the beam motion so that dissimilar materials may be considered. The surface heat transfer models used in the code include a Gaussian beam or uniform laser source, and a free electron theory reflectance calculation. Temperature-dependent material parameters are used in the reflectance calculation. Measured cold reflection data are used to include surface roughness or oxide effects until melt occurs, after which the surface is assumed to be smooth and clean. Blackbody reradiation and a simple natural convection model are also included in the upper surface boundary condition. Either an implicit or explicit finite-difference representation of the heat conduction equation in an enthalpy form is solved at each time step. This enables phase transition energies to be easily and accurately incorporated into the formulation. Temperature-dependent 9second-order polynominal dependence) thermal conductivities are used in the conduction calculations. Constant values of specific heat are used for each material phase. At present, material properties for six metals are included in the code. These are: aluminium, nickel, steel, molybdenum, copper and silicon
Gate-induced superconductivity in two-dimensional atomic crystals
Saito, Yu; Nojima, Tsutomu; Iwasa, Yoshihiro
2016-09-01
Two-dimensional (2D) crystals are attracting growing interest in condensed matter physics, since these systems exhibit not only rich electronic and photonic properties but also exotic electronic phase transitions including superconductivity and charge density wave. Moreover, owing to the recent development of transfer methods after exfoliation and electric-double-layer transistors, superconducting 2D atomic crystals, the thicknesses of which are below 1-2 nm, have been successfully obtained. Here, we present a topical review on the recent discoveries of 2D crystalline superconductors by ionic-liquid gating and a series of their novel properties. In particular, we highlight two topics; quantum metallic states (or possible metallic ground states) and superconductivity robust against in-plane magnetic fields. These phenomena can be discussed with the effects of weakened disorder and/or broken spacial inversion symmetry leading to valley-dependent spin-momentum locking (spin-valley locking). These examples suggest the superconducting 2D crystals are new platforms for investigating the intrinsic quantum phases as well as exotic nature in 2D superconductors.
Acoustic dispersion in a two-dimensional dipole system
International Nuclear Information System (INIS)
Golden, Kenneth I.; Kalman, Gabor J.; Donko, Zoltan; Hartmann, Peter
2008-01-01
We calculate the full density response function and from it the long-wavelength acoustic dispersion for a two-dimensional system of strongly coupled point dipoles interacting through a 1/r 3 potential at arbitrary degeneracy. Such a system has no random-phase-approximation (RPA) limit and the calculation has to include correlations from the outset. We follow the quasilocalized charge (QLC) approach, accompanied by molecular-dynamics (MD) simulations. Similarly to what has been recently reported for the closely spaced classical electron-hole bilayer [G. J. Kalman et al., Phys. Rev. Lett. 98, 236801 (2007)] and in marked contrast to the RPA, we report a long-wavelength acoustic phase velocity that is wholly maintained by particle correlations and varies linearly with the dipole moment p. The oscillation frequency, calculated both in an extended QLC approximation and in the Singwi-Tosi-Land-Sjolander approximation [Phys. Rev. 176, 589 (1968)], is invariant in form over the entire classical to quantum domains all the way down to zero temperature. Based on our classical MD-generated pair distribution function data and on ground-state energy data generated by recent quantum Monte Carlo simulations on a bosonic dipole system [G. E. Astrakharchik et al., Phys. Rev. Lett. 98, 060405 (2007)], there is a good agreement between the QLC approximation kinetic sound speeds and the standard thermodynamic sound speeds in both the classical and quantum domains
Two-dimensional disruption thermal analysis code DREAM
International Nuclear Information System (INIS)
Yamazaki, Seiichiro; Kobayashi, Takeshi; Seki, Masahiro.
1988-08-01
When a plasma disruption takes place in a tokamak type fusion reactor, plasma facing components such as first wall and divertor/limiter are subjected to an intense heat load with very high heat flux and short duration. At the surface of the wall, temperature rapidly rises, and melting and evaporation occurs, it causes reduction of wall thickness and crack initiation/propagation. As lifetime of the components is significantly affected by them, the transient analysis in consideration of phase changes (melting/evaporation) and radiation heat loss is required in the design of these components. This paper describes the computer code DREAM developed to perform the two-dimensional transient thermal analysis that takes phase changes and radiation into account. The input and output of the code and a sample analysis on a disruption simulation experiment are also reported. The user's input manual is added as an appendix. The profiles and time variations of temperature, and melting and evaporated thicknesses of the material subjected to intense heat load can be obtained, using this computer code. This code also gives the temperature data for elastoplastic analysis with FEM structural analysis codes (ADINA, MARC, etc.) to evaluate the thermal stress and crack propagation behavior within the wall materials. (author)
Simulations of two-dimensional electronic correlation spectra
International Nuclear Information System (INIS)
Kim, Hack Jin; Jeon, Seung Joon
2001-01-01
Two-dimensional (2D) correlation method, which generates the synchronous and the asynchronous 2D spectrum by complex cross correlation of the Fourier transformed spectra, is an analysis method for the changes of the sample spectrum induced by various perturbations. In the present work, the 2D electronic correlation spectra have been simulated for the cases where the sample spectrum composed of two gaussian bands changes linearly. When only the band amplitudes of the sample spectrum change, the synchronous spectrum shows strong peaks at the band centers of the sample spectrum, but the asynchronous spectrum does not make peaks. When the sample spectrum shifts without changing intensity and width, the synchronous spectrum shows peaks around the initial and final positions of the band maximum and the asynchronous spectrum shows long peaks spanning the shifting range. The band width change produces the complex 2D correlation spectra. When the sample spectrum shifts with band broadening, the width change by 50 % of full width at half maximum (FWHM) does not give so large an effect on the correlation spectrum as the spectral shift by one half of FWHM of the sample spectrum
Dragging two-dimensional discrete solitons by moving linear defects.
Brazhnyi, Valeriy A; Malomed, Boris A
2011-07-01
We study the mobility of small-amplitude solitons attached to moving defects which drag the solitons across a two-dimensional (2D) discrete nonlinear Schrödinger lattice. Findings are compared to the situation when a free small-amplitude 2D discrete soliton is kicked in a uniform lattice. In agreement with previously known results, after a period of transient motion the free soliton transforms into a localized mode pinned by the Peierls-Nabarro potential, irrespective of the initial velocity. However, the soliton attached to the moving defect can be dragged over an indefinitely long distance (including routes with abrupt turns and circular trajectories) virtually without losses, provided that the dragging velocity is smaller than a certain critical value. Collisions between solitons dragged by two defects in opposite directions are studied too. If the velocity is small enough, the collision leads to a spontaneous symmetry breaking, featuring fusion of two solitons into a single one, which remains attached to either of the two defects.
Role of valence electrons in phase transformation kinetics of thallium and its dilute alloys
Ahmed, R.; Ahmed, S.
1991-01-01
The kinetics of the phase transformation of thallium and its dilute alloys were investigated using XRD and calorimetry. Pure thallium exhibits a beta(bcc) to alpha(hcp) phase transformation on cooling at 508 K. With alloying additions, the crystal structure for each phase does not change, although the size of the unit cell increases. The enthalpy and the temperature of phase transformation of each alloy have been determined. The chemical free energy change associated with the phase transformation of each alloy was calculated. The valence electrons make an outstanding contribution to the chemical free energy change required for the phase change.
Non-Linear Non Stationary Analysis of Two-Dimensional Time-Series Applied to GRACE Data Project
National Aeronautics and Space Administration — The proposed innovative two-dimensional (2D) adaptive analysis will be tested NASA's Gravity Recovery and Climate Experiment (GRACE) mission database in phase I in...
Two-dimensional simulation of reactive diffusion in binary systems
Czech Academy of Sciences Publication Activity Database
Svoboda, Jiří; Stopka, J.; Fischer, F. D.
2014-01-01
Roč. 95, DEC (2014), s. 309-315 ISSN 0927-0256 R&D Projects: GA ČR(CZ) GA14-24252S Institutional support: RVO:68081723 Keywords : Phase transformation * Diffusion-controlled interface migration * Reactive diffusion * Multiphase system * Intermetallic compounds Subject RIV: BJ - Thermodynamics Impact factor: 2.131, year: 2014
Effect of cross-type bias in a two-dimensional array of short Josephson junctions
DEFF Research Database (Denmark)
Filatrella, G.; Pedersen, Niels Falsig; Wiesenfeld, K.
1998-01-01
We investigate numerically the effect of cross-type bias on two-dimensional arrays of short Josephson junctions. We have demonstrated that, for the simplest circuit, this type of bias is able to phase lock the junctions yielding a substantial improvement over ordinary biasing schemes. (C) 1998 Am...
Metallic ground state in an ion-gated two-dimensional superconductor
Saito, Yu; Kasahara, Yuichi; Ye, Jianting; Iwasa, Yoshihiro; Nojima, Tsutomu
2015-01-01
Recently emerging two-dimensional (2D) superconductors in atomically thin layers and at heterogeneous interfaces are attracting growing interest in condensed matter physics. Here, we report that an ion-gated zirconium nitride chloride surface, exhibiting a dome-shaped phase diagram with a maximum
A two-dimensional problem of a mode-I crack in a rotating fibre ...
Indian Academy of Sciences (India)
Home; Journals; Sadhana; Volume 43; Issue 1. A two-dimensional problem of a mode-I crack in a rotating fibre-reinforced isotropic thermoelastic medium under dual-phase-lag model. AHMED E ABOUELREGAL S M ABO-DAHAB. Volume 43 Issue 1 January 2018 Article ID 13 ...
Instantaneous normal modes and cooperative dynamics in a quasi-two-dimensional system of particles
Zangi, R; Rice, SA
2004-01-01
In recent molecular dynamics simulations [Phys. Rev. E 2003, 68, 061508] we found that the deviation of the single-particle displacement distribution from Gaussian form is a characteristic that is common to all phases of a system confined to a quasi-two-dimensional geometry (liquid, hexatic, and
Purification of 3H-dihydroalprenolol by two dimensional thin layer chromatography
International Nuclear Information System (INIS)
Smisterova, J.; Soltes, L.; Kallay, Z.
1989-01-01
A two dimensional thin-layer chromatographic method was developed for the purification and analysis of (-)-[ 3 H]dihydroalprenolol by using an acidic mobile phase (butanol/water/acetic acid 25:10:4, v/v) in one direction and a basic eluent (chloroform/acetone/triethylamine 50:40:10, v/v) in another direction. (author)
Berends, A.C.|info:eu-repo/dai/nl/411263986; de Mello-Donega, C.|info:eu-repo/dai/nl/125593899
2017-01-01
Research on ultrathin nanomaterials is one of the fastest developing areas in contemporary nanoscience. The field of ultrathin one- (1D) and two-dimensional (2D) colloidal nanocrystals (NCs) is still in its infancy, but offers the prospect of production of ultrathin nanomaterials in liquid-phase at
Emergent criticality and Friedan scaling in a two-dimensional frustrated Heisenberg antiferromagnet
Orth, Peter P.; Chandra, Premala; Coleman, Piers; Schmalian, Jörg
2014-03-01
We study a two-dimensional frustrated Heisenberg antiferromagnet on the windmill lattice consisting of triangular and dual honeycomb lattice sites. In the classical ground state, the spins on different sublattices are decoupled, but quantum and thermal fluctuations drive the system into a coplanar state via an "order from disorder" mechanism. We obtain the finite temperature phase diagram using renormalization group approaches. In the coplanar regime, the relative U(1) phase between the spins on the two sublattices decouples from the remaining degrees of freedom, and is described by a six-state clock model with an emergent critical phase. At lower temperatures, the system enters a Z6 broken phase with long-range phase correlations. We derive these results by two distinct renormalization group approaches to two-dimensional magnetism: Wilson-Polyakov scaling and Friedan's geometric approach to nonlinear sigma models where the scaling of the spin stiffnesses is governed by the Ricci flow of a 4D metric tensor.
Optimizing separations in online comprehensive two-dimensional liquid chromatography.
Pirok, Bob W J; Gargano, Andrea F G; Schoenmakers, Peter J
2018-01-01
Online comprehensive two-dimensional liquid chromatography has become an attractive option for the analysis of complex nonvolatile samples found in various fields (e.g. environmental studies, food, life, and polymer sciences). Two-dimensional liquid chromatography complements the highly popular hyphenated systems that combine liquid chromatography with mass spectrometry. Two-dimensional liquid chromatography is also applied to the analysis of samples that are not compatible with mass spectrometry (e.g. high-molecular-weight polymers), providing important information on the distribution of the sample components along chemical dimensions (molecular weight, charge, lipophilicity, stereochemistry, etc.). Also, in comparison with conventional one-dimensional liquid chromatography, two-dimensional liquid chromatography provides a greater separation power (peak capacity). Because of the additional selectivity and higher peak capacity, the combination of two-dimensional liquid chromatography with mass spectrometry allows for simpler mixtures of compounds to be introduced in the ion source at any given time, improving quantitative analysis by reducing matrix effects. In this review, we summarize the rationale and principles of two-dimensional liquid chromatography experiments, describe advantages and disadvantages of combining different selectivities and discuss strategies to improve the quality of two-dimensional liquid chromatography separations. © 2017 The Authors. Journal of Separation Science published by WILEY-VCH Verlag GmbH & Co. KGaA.
Thermal analysis of high temperature phase transformations of steel
Directory of Open Access Journals (Sweden)
K. Gryc
2013-10-01
Full Text Available The series of thermal analysis measurements of high temperature phase transformations of real grain oriented electrical steel grade under conditions of two analytical devices (Netzsch STA 449 F3 Jupiter; Setaram SETSYS 18TM were carried out. Two thermo analytical methods were used (DTA and Direct thermal analysis. The different weight of samples was used (200 mg, 23 g. The stability/reproducibility of results obtained by used methodologies was verified. The liquidus and solidus temperatures for close to equilibrium conditions and during cooling (20 °C/min; 80 °C/min were determined. It has been shown that the higher cooling rate lead to lower temperatures for start and end of solidification process of studied steel grade.
Phase transformations in lithium aluminates irradiated with neutrons
International Nuclear Information System (INIS)
Carrera, L.M.; Delfin L, A.; Urena N, F.; Basurto, R.; Bosch, P.
2003-01-01
The lithium aluminate like candidate to be used in the coverings producers of tritium in the fusion nuclear reactors, presents high resistance to the corrosion to the one to be stuck to structural materials as special steels. However, the crystallographic changes that take place in the cover that is continually subjected to irradiation with neutrons, can alter its resistance to the corrosion. In this work the changes of crystalline structure are shown that they present two types of nano structures of lithium aluminates, subjected to an average total dose 7.81 x 10 8 Gy in the fixed irradiation system of capsules of the one TRIGA Mark lll nuclear reactor of the Nuclear Center of Mexico. The studied nano structures presented only phase transformations without formation of amorphous material. (Author)
Interaction of stress and phase transformations during thermochemical surface engineering
DEFF Research Database (Denmark)
Jespersen, Freja Nygaard
dissolution. The present project is devoted to understanding the mutual interaction of stresses and phase transformations during thermochemical surface engineering by combining numerical modelling with experimental materials science. The modelling was done by combining solid mechanics with thermodynamics...... by chromium atoms, and the effect of composition-induced stress on surface concentration and diffusive flux. The effect of plasticity was also included. Temperature and concentration dependencies of mechanical and diffusion material properties were studied, and the effect of incorporation in the model...... examined. The effect of pre-stressing the sample was also tested, to investigate the effects of a residual stress-state that might be present from processing of the metal specimen. Controlled thermochemical treatment of austenitic stainless steel was investigated experimentally by in-diffusion of nitrogen...
Prediction and measurement of selected phase transformation temperatures of steels
Directory of Open Access Journals (Sweden)
Martiník O.
2017-01-01
Full Text Available The study deals with precise determination of phase transformation temperatures of steel. A series of experimental measurements were carried out by Differential Thermal Analysis (DTA and Direct Thermal Analysis (TA to obtain temperatures very close to the equilibrium temperatures. There are presented results from the high temperatures region, above 1000°C, with focus on the solidus temperatures (TS, peritectic transition (TP and liquidus (TL of multicomponent steels. The data obtained were verified by statistical evaluation and compared with computational thermodynamic and empirical calculations. The calculations were performed using 15 empirical equations obtained by literature research (10 for TL and 5 for TS, as well as by software InterDendritic Solidification (IDS and Thermo-Calc (2015b, TCFE8; TC. It was verified that both thermo-analytical methods used are set correctly; the results are reproducible, comparable and close to equilibrium state.
Phase Transformation of Metastable Austenite in Steel during Nano indentation
International Nuclear Information System (INIS)
Ahn, Taehong; Lee, Sung Bo; Han, Heung Nam; Park, Kyungtae
2013-01-01
These can produce geometrical softening accompanied by a sudden displacement excursion during load-controlled nanoindentation, which referred to in the literature as a pop-in. In this study, phase transformation of metastable austenite to stress-induced ε martensite which causes pop-ins during nanoindentation of steel will be reported and discussed. This study investigated the relationship between pop-in behavior of austenite in the early stage of nanoindentation and formation of ε martensite based on microstructural analyses. The load-displacement curve obtained from nanoindentation revealed stepwise pop-ins in the early stage of plastic deformation. From analyses of high resolution TEM images, a cluster of banded structure under the indent turned out a juxtaposition of (111) planes of γ austenite and (0001) planes of ε martensite. The calculation of displacement along indentation axis for (111) slip system by formation of ε martensite showed that geometrical softening can also occur by ε martensite formation when considering that the stress-induced ε martensite transformation is the predominant deformation mode in the early stage of plastic deformation and its monopartial nature as well. These microstructural investigations strongly suggest that the pop-in behavior in the early stage of plastic deformation of austenite is closely related to the formation of ε martensite
Phase Transformation of Metastable Austenite in Steel during Nano indentation
Energy Technology Data Exchange (ETDEWEB)
Ahn, Taehong [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Lee, Sung Bo; Han, Heung Nam [Seoul National Univ., Seoul (Korea, Republic of); Park, Kyungtae [Hanbat National Univ., Daejeon (Korea, Republic of)
2013-05-15
These can produce geometrical softening accompanied by a sudden displacement excursion during load-controlled nanoindentation, which referred to in the literature as a pop-in. In this study, phase transformation of metastable austenite to stress-induced ε martensite which causes pop-ins during nanoindentation of steel will be reported and discussed. This study investigated the relationship between pop-in behavior of austenite in the early stage of nanoindentation and formation of ε martensite based on microstructural analyses. The load-displacement curve obtained from nanoindentation revealed stepwise pop-ins in the early stage of plastic deformation. From analyses of high resolution TEM images, a cluster of banded structure under the indent turned out a juxtaposition of (111) planes of γ austenite and (0001) planes of ε martensite. The calculation of displacement along indentation axis for (111) slip system by formation of ε martensite showed that geometrical softening can also occur by ε martensite formation when considering that the stress-induced ε martensite transformation is the predominant deformation mode in the early stage of plastic deformation and its monopartial nature as well. These microstructural investigations strongly suggest that the pop-in behavior in the early stage of plastic deformation of austenite is closely related to the formation of ε martensite.
Nanocrystalline Fe-Pt alloys. Phase transformations, structure and magnetism
Energy Technology Data Exchange (ETDEWEB)
Lyubina, J.V.
2006-12-21
This work has been devoted to the study of phase transformations involving chemical ordering and magnetic properties evolution in bulk Fe-Pt alloys composed of nanometersized grains. Nanocrystalline Fe{sub 100-x}Pt{sub x} (x=40-60) alloys have been prepared by mechanical ball milling of elemental Fe and Pt powders at liquid nitrogen temperature. The as-milled Fe-Pt alloys consist of {proportional_to} 100 {mu}m sized particles constituted by randomly oriented grains having an average size in the range of 10-40 nm. Depending on the milling time, three major microstructure types have been obtained: samples with a multilayer-type structure of Fe and Pt with a thickness of 20-300 nm and a very thin (several nanometers) A1 layer at their interfaces (2 h milled), an intermediate structure, consisting of finer lamellae of Fe and Pt (below approximately 100 nm) with the A1 layer thickness reaching several tens of nanometers (4 h milled) and alloys containing a homogeneous A1 phase (7 h milled). Subsequent heat treatment at elevated temperatures is required for the formation of the L1{sub 0} FePt phase. The ordering develops via so-called combined solid state reactions. It is accompanied by grain growth and thermally assisted removal of defects introduced by milling and proceeds rapidly at moderate temperatures by nucleation and growth of the ordered phases with a high degree of the long-range order. In a two-particle interaction model elaborated in the present work, the existence of hysteresis in recoil loops has been shown to arise from insufficient coupling between the low- and the high-anisotropy particles. The model reveals the main features of magnetisation reversal processes observed experimentally in exchange-coupled systems. Neutron diffraction has been used for the investigation of the magnetic structure of ordered and partially ordered nanocrystalline Fe-Pt alloys. (orig.)
Thermodynamics and phase transformations: the selected works of Mats Hillert
International Nuclear Information System (INIS)
Agren, J.; Brechet, Y.; Hutchinson, Ch.; Purdy, G.
2006-01-01
For over half a century, Mats Hillert has contributed greatly to the science of materials. He is widely known and respected as an innovator and an educator, a scientist with an enormous breadth of interest and depth of insight. In acknowledgment of his many contributions, a conference was held in Stockholm in December 2004 to mark his eightieth birthday. This volume was conceived prior to, and publicly announced during the conference. The difficult choice of twenty-four papers from a publication list of more than three hundred was carried out in consultation with Mats. He also suggested or approved the scientists who would be invited to write a brief introduction to each paper. A brief reading of the topics of the selected papers and their introductions reveals something of their range and depth. Several early selections (for example, those on 'The Role of Interfacial Energy during Solid State Phase Transformations', and 'A Solid-Solution Model for Inhomogeneous Systems') contained seminal material that established Mats as a leading figure in the study of phase transformations in solids. Others established his presence in the areas of solidification and computational thermodynamics. A review of his full publication list shows that he has consistently built upon those early foundational papers, and maintained a dominant position in those fields. Although many of his contributions have been of a theoretical nature, he has always maintained a close contact with experiment, and indeed, he has designed numerous critical experiments. This volume represents a judicious sampling of Mats Hillert's extensive body of work; it is necessarily incomplete, but it is hoped and expected that it will prove useful to students of materials science and engineering at all levels, and that it will inspire the further study and appreciation of his many contributions. (authors)
Third sound in one and two dimensional modulated structures
International Nuclear Information System (INIS)
Komuro, T.; Kawashima, H., Shirahama, K.; Kono, K.
1996-01-01
An experimental technique is developed to study acoustic transmission in one and two dimensional modulated structures by employing third sound of a superfluid helium film. In particular, the Penrose lattice, which is a two dimensional quasiperiodic structure, is studied. In two dimensions, the scattering of third sound is weaker than in one dimension. Nevertheless, the authors find that the transmission spectrum in the Penrose lattice, which is a two dimensional prototype of the quasicrystal, is observable if the helium film thickness is chosen around 5 atomic layers. The transmission spectra in the Penrose lattice are explained in terms of dynamical theory of diffraction
Stability analysis of two-dimensional digital recursive filters
Alexander, W. E.; Pruess, S. A.
1980-01-01
A new approach to the stability problem for the two-dimensional digital recursive filter is presented. The bivariate difference equation representation of the two-dimensional recursive digital filter is converted to a multiinput-multioutput (MIMO) system similar to the state-space representation of the one-dimensional digital recursive filter. In this paper, a pseudo-state representation is used and three coefficient matrices are obtained. A general theorem for stability of two-dimensional digital recursive filters is derived and a very useful theorem is presented which expresses sufficient requirements for instability in terms of the spectral radii of these matrices.
ONE-DIMENSIONAL AND TWO-DIMENSIONAL LEADERSHIP STYLES
Directory of Open Access Journals (Sweden)
Nikola Stefanović
2007-06-01
Full Text Available In order to motivate their group members to perform certain tasks, leaders use different leadership styles. These styles are based on leaders' backgrounds, knowledge, values, experiences, and expectations. The one-dimensional styles, used by many world leaders, are autocratic and democratic styles. These styles lie on the two opposite sides of the leadership spectrum. In order to precisely define the leadership styles on the spectrum between the autocratic leadership style and the democratic leadership style, leadership theory researchers use two dimensional matrices. The two-dimensional matrices define leadership styles on the basis of different parameters. By using these parameters, one can identify two-dimensional styles.
Numerical evaluation of two-dimensional harmonic polylogarithms
Gehrmann, T
2002-01-01
The two-dimensional harmonic polylogarithms $\\G(\\vec{a}(z);y)$, a generalization of the harmonic polylogarithms, themselves a generalization of Nielsen's polylogarithms, appear in analytic calculations of multi-loop radiative corrections in quantum field theory. We present an algorithm for the numerical evaluation of two-dimensional harmonic polylogarithms, with the two arguments $y,z$ varying in the triangle $0\\le y \\le 1$, $ 0\\le z \\le 1$, $\\ 0\\le (y+z) \\le 1$. This algorithm is implemented into a {\\tt FORTRAN} subroutine {\\tt tdhpl} to compute two-dimensional harmonic polylogarithms up to weight 4.
Weak three-dimensional mediators of two-dimensional triplet pairing
Kelly, Shane; Tsai, S.-W.
2018-01-01
Recent experiments demonstrate the ability to construct cold-atom mixtures with species-selective optical lattices. This allows for the possibility of a mixed-dimension system, where one fermionic atomic species is confined to a two-dimensional lattice, while another species is confined to a three-dimensional lattice that contains the two-dimensional one. We show that by tuning the density of an arbitrary number of three-dimensional atomic species, we can engineer an arbitrary, rotationally symmetric, density-density, effective interaction for the two-dimensional particles. This possibility allows for an effective interaction that favors triplet pairing for two-dimensional, SU(2 ) symmetric particles. Using a functional renormalization-group analysis for the two-dimensional particles, we derive and numerically confirm that the critical temperature for triplet pairing depends exponentially on the effective interaction strength. We then analyze how the stability of this phase is affected by the particle densities and the fine tuning of interaction parameters. We conclude by briefly discussing experimental considerations and the potential to study triplet-pairing physics, including Majorana fermions and spin textures, with cold atoms on optical lattices.
A measurement system for two-dimensional DC-biased properties of magnetic materials
International Nuclear Information System (INIS)
Enokizono, M.; Matsuo, H.
2003-01-01
So far, the DC-biased magnetic properties have been measured in one dimension (scalar). However, these scalar magnetic properties are not enough to clarify the DC-biased magnetic properties because the scalar magnetic properties cannot exactly take into account the phase difference between the magnetic flux density B vector and the magnetic filed strength H vector. Thus, the magnetic field strength H and magnetic flux density B in magnetic materials must be measured as vector quantities (two-dimensional), directly. We showed the measurement system using a single-sheet tester (SST) to clarify the two-dimensional DC-biased magnetic properties. This system excited AC in Y-direction and DC in X-direction. This paper shows the measurement system using an SST and presents the measurement results of two-dimensional DC-biased magnetic properties when changing the DC exciting voltage and the iron loss
Synthesis and Electrochemical Properties of Two-Dimensional RGO/Ti3C2Tx Nanocomposites
Directory of Open Access Journals (Sweden)
Changjie Shen
2018-01-01
Full Text Available MXene is a new type of two-dimensional layered material. Herein, a GO/Ti3C2Tx nanocomposite was prepared by a simple liquid phase method, and the obtained GO/Ti3C2Tx was transformed into RGO/Ti3C2Tx under high temperature with Ar/H2. The prepared samples were characterized using X-ray diffraction (XRD, Raman measurement, scanning electron microscopy (SEM, energy disperse spectroscopy (EDS, and X-ray photoelectron spectroscopy (XPS. As an electrode material in lithium-ion batteries, the RGO/Ti3C2Tx nanocomposite exhibited an excellent electrochemical performance and an excellent rate performance. Compared to pure Ti3C2Tx, the nanocomposite had a better reversible capacity at different current densities and had no attenuation after 200 cycles, which is one time higher than pure Ti3C2Tx. The improvement in the specific capacity was due to the excellent electrical conductivity and the unique structure of RGO, in which a charge transfer bridge was built among the Ti3C2Tx flakes. Such a bridge shortened the transmission distance of the electrons and ions and effectively controlled the restacking of the laminated materials.
Universality of modular symmetries in two-dimensional magnetotransport
Olsen, K. S.; Limseth, H. S.; Lütken, C. A.
2018-01-01
We analyze experimental quantum Hall data from a wide range of different materials, including semiconducting heterojunctions, thin films, surface layers, graphene, mercury telluride, bismuth antimonide, and black phosphorus. The fact that these materials have little in common, except that charge transport is effectively two-dimensional, shows how robust and universal the quantum Hall phenomenon is. The scaling and fixed point data we analyzed appear to show that magnetotransport in two dimensions is governed by a small number of universality classes that are classified by modular symmetries, which are infinite discrete symmetries not previously seen in nature. The Hall plateaux are (infrared) stable fixed points of the scaling-flow, and quantum critical points (where the wave function is delocalized) are unstable fixed points of scaling. Modular symmetries are so rigid that they in some cases fix the global geometry of the scaling flow, and therefore predict the exact location of quantum critical points, as well as the shape of flow lines anywhere in the phase diagram. We show that most available experimental quantum Hall scaling data are in good agreement with these predictions.
Engineering the Kondo state in two-dimensional semiconducting phosphorene
Babar, Rohit; Kabir, Mukul
2018-01-01
Correlated interaction between dilute localized impurity electrons and the itinerant host conduction electrons in metals gives rise to the conventional many-body Kondo effect below sufficiently low temperature. In sharp contrast to these conventional Kondo systems, we report an intrinsic, robust, and high-temperature Kondo state in two-dimensional semiconducting phosphorene. While absorbed at a thermodynamically stable lattice defect, Cr impurity triggers an electronic phase transition in phosphorene to provide conduction electrons, which strongly interact with the localized moment generated at the Cr site. These manifest into the intrinsic Kondo state, where the impurity moment is quenched in multiple stages and at temperatures in the 40-200 K range. Further, along with a much smaller extension of the Kondo cloud, the predicted Kondo state is shown to be robust under uniaxial strain and layer thickness, which greatly simplifies its future experimental realization. We predict the present study will open up new avenues in Kondo physics and trigger further theoretical and experimental studies.
Adaptation and timing recovery for two-dimensional optical storage
Immink, Andre H.; Riani, Jamal; van Beneden, Steven; Bergmans, Jan; Ciacci, Massimo; Nowbakht Irani, Ali; Coene, Wim; van der Lee, Alexander; Bruls, Dominique
2004-09-01
This paper discusses several issues related to adaptation and timing recovery for two-dimensional (2D) optical storage. In the TwoDOS format bits are stored on a 2D hexagonal lattice which is formed by recording multiple bit rows with a fixed phase relation in a so-called broad spiral or meta-spiral. Besides a large increase in data rate by reading out with multiple spots, also a density increase by a factor of two compared to Blu-ray Disc is targeted. To increase the storage density, 2D signal processing is proposed including 2D PRML detection in the form of a stripe-wise Viterbi detector. This detector introduces an increasing detection delay when going from the outer rows towards the center of the broad spiral. For fast control loops in a decision-directed mode, special measures are needed to avoid instability due to this delay. Another issue is the large span of the 2D inter-symbol interference at higher densities and tilt, leading to a large 2D equalizer. Furthermore, in case the broad spiral is recorded with a multiple-pass mastering technology (e.g. for ROM TwoDOS discs), write-channel imperfections such as time-varying lattice distortion require independent timing recovery on each row within the broad spiral.
Soluble, Exfoliated Two-Dimensional Nanosheets as Excellent Aqueous Lubricants.
Zhang, Wenling; Cao, Yanlin; Tian, Pengyi; Guo, Fei; Tian, Yu; Zheng, Wen; Ji, Xuqiang; Liu, Jingquan
2016-11-30
Dispersion in water of two-dimensional (2D) nanosheets is conducive to their practical applications in fundamental science communities due to their abundance, low cost, and ecofriendliness. However, it is difficult to achieve stable aqueous 2D material suspensions because of the intrinsic hydrophobic properties of the layered materials. Here, we report an effective and economic way of producing various 2D nanosheets (h-BN, MoS 2 , MoSe 2 , WS 2 , and graphene) as aqueous dispersions using carbon quantum dots (CQDs) as exfoliation agents and stabilizers. The dispersion was prepared through a liquid phase exfoliation. The as-synthesized stable 2D nanosheets based dispersions were characterized by UV-vis, HRTEM, AFM, Raman, XPS, and XRD. The solutions based on CQD decorated 2D nanosheets were utilized as aqueous lubricants, which realized a friction coefficient as low as 0.02 and even achieved a superlubricity under certain working conditions. The excellent lubricating properties were attributed to the synergetic effects of the 2D nanosheets and CQDs, such as good dispersion stability and easy-sliding interlayer structure. This work thus proposes a novel strategy for the design and preparation of high-performance water based green lubricants.
Critical phenomena in quasi-two-dimensional vibrated granular systems.
Guzmán, Marcelo; Soto, Rodrigo
2018-01-01
The critical phenomena associated to the liquid-to-solid transition of quasi-two-dimensional vibrated granular systems is studied using molecular dynamics simulations of the inelastic hard sphere model. The critical properties are associated to the fourfold bond-orientational order parameter χ_{4}, which measures the level of square crystallization of the system. Previous experimental results have shown that the transition of χ_{4}, when varying the vibration amplitude, can be either discontinuous or continuous, for two different values of the height of the box. Exploring the amplitude-height phase space, a transition line is found, which can be either discontinuous or continuous, merging at a tricritical point and the continuous branch ends in an upper critical point. In the continuous transition branch, the critical properties are studied. The exponent associated to the amplitude of the order parameter is β=1/2, for various system sizes, in complete agreement with the experimental results. However, the fluctuations of χ_{4} do not show any critical behavior, probably due to crossover effects by the close presence of the tricritical point. Finally, in quasi-one-dimensional systems, the transition is only discontinuous, limited by one critical point, indicating that two is the lower dimension for having a tricritical point.
Micromachined two dimensional resistor arrays for determination of gas parameters
van Baar, J.J.J.; Verwey, Willem B.; Dijkstra, Mindert; Dijkstra, Marcel; Wiegerink, Remco J.; Lammerink, Theodorus S.J.; Krijnen, Gijsbertus J.M.; Elwenspoek, Michael Curt
A resistive sensor array is presented for two dimensional temperature distribution measurements in a micromachined flow channel. This allows simultaneous measurement of flow velocity and fluid parameters, like thermal conductivity, diffusion coefficient and viscosity. More general advantages of
Proteome research : two-dimensional gel electrophoresis and identification methods
National Research Council Canada - National Science Library
Rabilloud, Thierry, 1961
2000-01-01
"Two-dimensional electrophoresis is the central methodology in proteome research, and the state of the art is described in detail in this text, together with extensive coverage of the detection methods available...
1/f noise in two-dimensional fluids
International Nuclear Information System (INIS)
Cable, S.B.; Tajima, T.
1994-10-01
We derive an exact result on the velocity fluctuation power spectrum of an incompressible two-dimensional fluid. Employing the fluctuation-dissipation relationship and the enstrophy conversation, we obtain the frequency spectrum of a 1/f form
Partition function of the two-dimensional nearest neighbour Ising ...
Indian Academy of Sciences (India)
Abstract. The partition function for two-dimensional nearest neighbour Ising model in a non-zero magnetic field have been derived for a finite square lattice of 16, 25, 36 and 64 sites with the help of ...
Multisoliton formula for completely integrable two-dimensional systems
International Nuclear Information System (INIS)
Chudnovsky, D.V.; Chudnovsky, G.V.
1979-01-01
For general two-dimensional completely integrable systems, the exact formulae for multisoliton type solutions are given. The formulae are obtained algebrically from solutions of two linear partial differential equations
Numerical Study of Two-Dimensional Volterra Integral Equations by RDTM and Comparison with DTM
Directory of Open Access Journals (Sweden)
Reza Abazari
2013-01-01
Full Text Available The two-dimensional Volterra integral equations are solved using more recent semianalytic method, the reduced differential transform method (the so-called RDTM, and compared with the differential transform method (DTM. The concepts of DTM and RDTM are briefly explained, and their application to the two-dimensional Volterra integral equations is studied. The results obtained by DTM and RDTM together are compared with exact solution. As an important result, it is depicted that the RDTM results are more accurate in comparison with those obtained by DTM applied to the same Volterra integral equations. The numerical results reveal that the RDTM is very effective, convenient, and quite accurate compared to the other kind of nonlinear integral equations. It is predicted that the RDTM can be found widely applicable in engineering sciences.
Structures of two-dimensional three-body systems
International Nuclear Information System (INIS)
Ruan, W.Y.; Liu, Y.Y.; Bao, C.G.
1996-01-01
Features of the structure of L = 0 states of a two-dimensional three-body model system have been investigated. Three types of permutation symmetry of the spatial part, namely symmetric, antisymmetric, and mixed, have been considered. A comparison has been made between the two-dimensional system and the corresponding three-dimensional one. The effect of symmetry on microscopic structures is emphasized. (author)
The Two-Dimensional Analogue of General Relativity
Lemos, José P. S.; Sá, Paulo M.
1993-01-01
General Relativity in three or more dimensions can be obtained by taking the limit $\\omega\\rightarrow\\infty$ in the Brans-Dicke theory. In two dimensions General Relativity is an unacceptable theory. We show that the two-dimensional closest analogue of General Relativity is a theory that also arises in the limit $\\omega\\rightarrow\\infty$ of the two-dimensional Brans-Dicke theory.
Two-Dimensionally-Modulated, Magnetic Structure of Neodymium Metal
DEFF Research Database (Denmark)
Lebech, Bente; Bak, P.
1979-01-01
The incipient magnetic order of dhcp Nd is described by a two-dimensional, incommensurably modulated structure ("triple-q" structure). The ordering is accompanied by a lattice distortion that forms a similar pattern.......The incipient magnetic order of dhcp Nd is described by a two-dimensional, incommensurably modulated structure ("triple-q" structure). The ordering is accompanied by a lattice distortion that forms a similar pattern....
Phase transformation of metastable cubic γ-phase in U-Mo alloys
International Nuclear Information System (INIS)
Sinha, V.P.; Hegde, P.V.; Prasad, G.J.; Dey, G.K.; Kamath, H.S.
2010-01-01
Over the past decade considerable efforts have been put by many fuel designers to develop low enriched uranium (LEU 235 ) base U-Mo alloy as a potential fuel for core conversion of existing research and test reactors which are running on high enriched uranium (HEU > 85%U 235 ) fuel and also for the upcoming new reactors. U-Mo alloy with minimum 8 wt% molybdenum shows excellent metastability with cubic γ-phase in cast condition. However, it is important to characterize the decomposition behaviour of metastable cubic γ-uranium in its equilibrium products for in reactor fuel performance point of view. The present paper describes the phase transformation behaviour of cubic γ-uranium phase in U-Mo alloys with three different molybdenum compositions (i.e. 8 wt%, 9 wt% and 10 wt%). U-Mo alloys were prepared in an induction melting furnace and characterized by X-ray diffraction (XRD) method for phase determination. Microstructures were developed for samples in as cast condition. The alloys were hot rolled in cubic γ-phase to break the cast structure and then they were aged at 500 o C for 68 h and 240 h, so that metastable cubic γ-uranium will undergo eutectoid decomposition to form equilibrium phases of orthorhombic α-uranium and body centered tetragonal U 2 Mo intermetallic compound. U-Mo alloy samples with different ageing history were then characterized by XRD for phase and development of microstructure.
Two-dimensional multifractal cross-correlation analysis
International Nuclear Information System (INIS)
Xi, Caiping; Zhang, Shuning; Xiong, Gang; Zhao, Huichang; Yang, Yonghong
2017-01-01
Highlights: • We study the mathematical models of 2D-MFXPF, 2D-MFXDFA and 2D-MFXDMA. • Present the definition of the two-dimensional N 2 -partitioned multiplicative cascading process. • Do the comparative analysis of 2D-MC by 2D-MFXPF, 2D-MFXDFA and 2D-MFXDMA. • Provide a reference on the choice and parameter settings of these methods in practice. - Abstract: There are a number of situations in which several signals are simultaneously recorded in complex systems, which exhibit long-term power-law cross-correlations. This paper presents two-dimensional multifractal cross-correlation analysis based on the partition function (2D-MFXPF), two-dimensional multifractal cross-correlation analysis based on the detrended fluctuation analysis (2D-MFXDFA) and two-dimensional multifractal cross-correlation analysis based on the detrended moving average analysis (2D-MFXDMA). We apply these methods to pairs of two-dimensional multiplicative cascades (2D-MC) to do a comparative study. Then, we apply the two-dimensional multifractal cross-correlation analysis based on the detrended fluctuation analysis (2D-MFXDFA) to real images and unveil intriguing multifractality in the cross correlations of the material structures. At last, we give the main conclusions and provide a valuable reference on how to choose the multifractal algorithms in the potential applications in the field of SAR image classification and detection.
The theory of critical phenomena in two-dimensional systems
International Nuclear Information System (INIS)
Olvera de la C, M.
1981-01-01
An exposition of the theory of critical phenomena in two-dimensional physical systems is presented. The first six chapters deal with the mean field theory of critical phenomena, scale invariance of the thermodynamic functions, Kadanoff's spin block construction, Wilson's renormalization group treatment of critical phenomena in configuration space, and the two-dimensional Ising model on a triangular lattice. The second part of this work is made of four chapters devoted to the application of the ideas expounded in the first part to the discussion of critical phenomena in superfluid films, two-dimensional crystals and the two-dimensional XY model of magnetic systems. Chapters seven to ten are devoted to the following subjects: analysis of long range order in one, two, and three-dimensional physical systems. Topological defects in the XY model, in superfluid films and in two-dimensional crystals. The Thouless-Kosterlitz iterated mean field theory of the dipole gas. The renormalization group treatment of the XY model, superfluid films and two-dimensional crystal. (author)
Two-Dimensional Materials for Sensing: Graphene and Beyond
Directory of Open Access Journals (Sweden)
Seba Sara Varghese
2015-09-01
Full Text Available Two-dimensional materials have attracted great scientific attention due to their unusual and fascinating properties for use in electronics, spintronics, photovoltaics, medicine, composites, etc. Graphene, transition metal dichalcogenides such as MoS2, phosphorene, etc., which belong to the family of two-dimensional materials, have shown great promise for gas sensing applications due to their high surface-to-volume ratio, low noise and sensitivity of electronic properties to the changes in the surroundings. Two-dimensional nanostructured semiconducting metal oxide based gas sensors have also been recognized as successful gas detection devices. This review aims to provide the latest advancements in the field of gas sensors based on various two-dimensional materials with the main focus on sensor performance metrics such as sensitivity, specificity, detection limit, response time, and reversibility. Both experimental and theoretical studies on the gas sensing properties of graphene and other two-dimensional materials beyond graphene are also discussed. The article concludes with the current challenges and future prospects for two-dimensional materials in gas sensor applications.
Optical Two-Dimensional Spectroscopy of Disordered Semiconductor Quantum Wells and Quantum Dots
Energy Technology Data Exchange (ETDEWEB)
Cundiff, Steven T. [Univ. of Colorado, Boulder, CO (United States)
2016-05-03
This final report describes the activities undertaken under grant "Optical Two-Dimensional Spectroscopy of Disordered Semiconductor Quantum Wells and Quantum Dots". The goal of this program was to implement optical 2-dimensional Fourier transform spectroscopy and apply it to electronic excitations, including excitons, in semiconductors. Specifically of interest are quantum wells that exhibit disorder due to well width fluctuations and quantum dots. In both cases, 2-D spectroscopy will provide information regarding coupling among excitonic localization sites.
Two-dimensional neural field simulator with parameter interface and 3D visualization
Nichols, Eric; Hutt, Axel
2014-01-01
International audience; A simulator calculating two-dimensional dynamic neural fields with multiple order derivatives is presented in this work. The simulated neural fields are of the type ... where I, L and S are respectively a field's input, spatial delay kernel with axonal transmission speed c and nonlinear firing rate function S = S0 / (1 + exp(-α(V-Θ)). A Fast Fourier Transform in space is used to accelerate the integral calculation. The stochastic differential equation is useful for stu...
Temperature induced reversible polymorphic phase transformations in a bis-hydrazone compound
Jayant, Vikrant; Das, Dinabandhu
2018-03-01
Two reversible polymorphic phase transformation of 2,3-butanedione, 2,3- bis[4,4‧-bis(diethylamino)benzophenone hydrazone] (DEBH) have been identified in DSC experiment. Topotactic phase transformation of three polymorphs has been observed in variable temperature Single Crystal X-ray Diffraction experiment. The reversible phase transformation of bulk material has been confirmed by Powder X-ray diffraction study.
Fanali, Chiara; Beccaria, Marco; Salivo, Simona; Tranchida, Peter; Tripodo, Giusy; Farnetti, Sara; Dugo, Laura; Dugo, Paola; Mondello, Luigi
2015-07-08
A chemical characterization of major lipid components, namely, triacylglycerols, fatty acids and the unsaponifiable fraction, in a Quinoa seed lipids sample is reported. To tackle such a task, non-aqueous reversed-phase high-performance liquid chromatography with mass spectrometry detection was employed. The latter was interfaced with atmospheric pressure chemical ionization for the analysis of triacylglycerols. The main triacylglycerols (>10%) were represented by OLP, OOL and OLL (P = palmitoyl, O = oleoyl, L = linoleoyl); the latter was present in the oil sample at the highest percentage (18.1%). Furthermore, fatty acid methyl esters were evaluated by gas chromatography with flame ionization detection. 89% of the total fatty acids was represented by unsaturated fatty acid methyl esters with the greatest percentage represented by linoleic and oleic acids accounting for approximately 48 and 28%, respectively. An extensive characterization of the unsaponifiable fraction of Quinoa seed lipids was performed for the first time, by using comprehensive two-dimensional gas chromatography with dual mass spectrometry/flame ionization detection. Overall, 66 compounds of the unsaponifiable fraction were tentatively identified, many constituents of which (particularly sterols) were confirmed by using gas chromatography with high-resolution time-of-flight mass spectrometry. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Batan, Tufan
The extensive use of power electronic devices in the last two decades have degraded the quality of the power system by introducing voltage and current harmonics as well as DC excitations. Such phenomena cause additional losses in transformers, resulting in elevated temperatures of transformers above their rated temperatures. This added heat degrades the insulating material of the windings, decreasing the rated lifetime of transformers. For this reason, transformers feeding nonlinear loads must be derated; that is. by limiting either their output apparent or real power such that rated temperatures are not exceeded. It is of advantage to measure the derating of transformers which are already in service, for given nonlinear loads and to calculate the derating of large transformers that cannot readily be tested in laboratories. It is one of the objectives of this thesis to validate the computed derating values of transformers with corroborating measurements. A 25kVA 7200V/240V single-phase pole transformer is analyzed using two dimensional field analysis based on the diffusion equation, employing either rectangular or polycentric grid structures. Such a field analysis allows us to visualize the complex vector potential and flux density distributions inside the unsaturated transformer operating under short-circuit conditions. One can calculate the eddy currents within conducting materials, such as copper and aluminum windings, from complex vector potential values. Short-circuit tests applied to low and high voltage windings allow us to calculate the eddy currents inside each winding and consequently their eddy-current losses. The frequency dependent AC winding resistance RAC as well as the per-unit eddy-current loss coefficient PEC-R are computed. These values are used to determine the derating of transformers via either the K-factor as proposed by Underwriters Laboratory, Inc., or via the harmonic loss factor FHL, as favored by IEEE and IEC. A new digital data
Discrete elastic model for two-dimensional melting
Lansac, Yves; Glaser, Matthew A.; Clark, Noel A.
2006-04-01
We present a network model for the study of melting and liquid structure in two dimensions, the first in which the presence and energy of topological defects (dislocations and disclinations) and of geometrical defects (elemental voids) can be independently controlled. Interparticle interaction is via harmonic springs and control is achieved by Monte Carlo moves which springs can either be orientationally “flipped” between particles to generate topological defects, or can be “popped” in force-free shape, to generate geometrical defects. With the geometrical defects suppressed the transition to the liquid phase occurs via disclination unbinding, as described by the Kosterlitz-Thouless-Halperin-Nelson-Young model and found in soft potential two-dimensional (2D) systems, such as the dipole-dipole potential [H. H. von Grünberg , Phys. Rev. Lett. 93, 255703 (2004)]. By contrast, with topological defects suppressed, a disordering transition, the Glaser-Clark condensation of geometrical defects [M. A. Glaser and N. A. Clark, Adv. Chem. Phys. 83, 543 (1993); M. A. Glaser , Springer Proceedings in Physics: Dynamics and Patterns in Complex Fluids (Springer-Verlag, Berlin, 1990), Vol. 52, p. 141], produces a state that accurately characterizes the local liquid structure and first-order melting observed in hard-potential 2D systems, such as hard disk and the Weeks-Chandler-Andersen (WCA) potentials (M. A. Glaser and co-workers, see above). Thus both the geometrical and topological defect systems play a role in melting. The present work introduces a system in which the relative roles of topological and geometrical defects and their interactions can be explored. We perform Monte Carlo simulations of this model in the isobaric-isothermal ensemble, and present the phase diagram as well as various thermodynamic, statistical, and structural quantities as a function of the relative populations of geometrical and topological defects. The model exhibits a rich phase behavior
Phase transformations of (Ca, Ti)-partially stabilized zirconia
Energy Technology Data Exchange (ETDEWEB)
Hon Yungshon; Shen Pouyan (Inst. of Materials Science and Engineering, Nation Sun Yat-Sen Univ., Kaohsiung (Taiwan))
1991-01-20
The results of phase transformation and microstructural investigation of the ZrO{sub 2}-rich corner of the CaO-TiO{sub 2}-ZrO{sub 2} system are reported. Samples of Ca-PSZ powder (where PSZ is partially stabilized zirconia) containing 10.8 mol.% CaO, had added to them 0-14 mol.% TiO{sub 2} (designated specimens 0T to 14T). The samples were sintered at 1600deg C for 6 h and studied by X-ray diffraction and electron microscopy. Saturation of TiO{sub 2} in the cubic (c) zirconia was reached at a total TiO{sub 2} addition of about 4 mol.% at 1600deg C, whereas the solubility limit in tetragonal (t) zirconia was not reached in the composition range studied. The t-zirconia precipitates remained tweed in the cubic matrix for specimens 2T and 4T, but became lenticular with the (101) habit plane for specimens having a larger TiO{sub 2} content (e.g. 8T). The amount of t-zirconia increased with increasing TiO{sub 2} content at 1600deg C. The addition of TiO{sub 2} also enhanced the eutectoid decomposition of Ca-PSZ to form the PHI{sub 1}-phase (CaZr{sub 4}O{sub 9}). Calzirtite (Ca{sub 2}Zr{sub 5}Ti{sub 2}O{sub 16}) was precipitated from the shell of the zirconia grains in specimen 8T. (orig.).
Rothenstein, Bernhard
2005-01-01
We show that the transformation equations for the parameters that characterize a plane acoustic wave: period, (frequency), wave vector, wave length and phase velocity can be derived without using phase invariance and Lorentz-Einstein transformation
Optimisation of Transmission Systems by use of Phase Shifting Transformers
Energy Technology Data Exchange (ETDEWEB)
Verboomen, J.
2008-10-13
In this thesis, transmission grids with PSTs (Phase Shifting Transformers) are investigated. In particular, the following goals are put forward: (a) The analysis and quantification of the impact of a PST on a meshed grid. This includes the development of models for the device; (b) The development of methods to obtain optimal coordination of several PSTs in a meshed grid. An objective function should be formulated, and an optimisation method must be adopted to solve the problem; and (c) The investigation of different strategies to use a PST. Chapter 2 gives a short overview of active power flow controlling devices. In chapter 3, a first step towards optimal PST coordination is taken. In chapter 4, metaheuristic optimisation methods are discussed. Chapter 5 introduces DC load flow approximations, leading to analytically closed equations that describe the relation between PST settings and active power flows. In chapter 6, some applications of the methods that are developed in earlier chapters are presented. Chapter 7 contains the conclusions of this thesis, as well as recommendations for future work.
Martensitic phase transformation in shape-memory alloys
International Nuclear Information System (INIS)
Golestaneh, A.A.
1979-01-01
Isothermal studies are described of the shape-recovery phenomenon, stress-strain behavior, electrical resistivity and thermo-electric power associated with the martensite-parent phase reaction in the Ni-Ti shape-memory alloys. The energy-balance equation that links the reaction kinetics with the strain energy change during the cooling-deforming and heating cycle is analyzed. The strain range in which the Clausius-Clapeyron equation satisfactorily describes this reaction is determined. A large change in the Young's modulus of the specimen is found to be associated with the M → P reaction. A hysteresis loop in the resistivity-temperature plot is found and related to the anomaly in the athermal resistivity changes during cyclic M → P → M transformation. An explanation for the resistivity anomaly is offered. The M structure is found to be electrically negative relative to the P structure. A thermal emf of greater than or equal to 0.12 mV is found at the M-P interface
Martensitic phase transformation in shape-memory alloys
Energy Technology Data Exchange (ETDEWEB)
Golestaneh, A A
1979-01-01
Isothermal studies are described of the shape-recovery phenomenon, stress-strain behavior, electrical resistivity and thermo-electric power associated with the martensite-parent phase reaction in the Ni-Ti shape-memory alloys. The energy-balance equation that links the reaction kinetics with the strain energy change during the cooling-deforming and heating cycle is analyzed. The strain range in which the Clausius-Clapeyron equation satisfactorily describes this reaction is determined. A large change in the Young's modulus of the specimen is found to be associated with the M ..-->.. P reaction. A hysteresis loop in the resistivity-temperature plot is found and related to the anomaly in the athermal resistivity changes during cyclic M ..-->.. P ..-->.. M transformation. An explanation for the resistivity anomaly is offered. The M structure is found to be electrically negative relative to the P structure. A thermal emf of greater than or equal to 0.12 mV is found at the M-P interface.
International Nuclear Information System (INIS)
Gorthi, Sai Siva; Rastogi, Pramod
2009-01-01
A noisy wrapped phase map is the end-output of commonly employed phase estimation methods in digital holographic interferometry. Hence filtering and unwrapping are necessary to obtain continuous phase distributions. This paper introduces a new approach for phase estimation in digital holographic interferometry using the polynomial phase transform. The proposed approach directly provides an accurate estimation of the unwrapped phase distribution from a noisy reconstructed interference field, thereby bypassing cumbersome and error-prone filtering and 2D phase unwrapping procedures
Phase transformations of a talc ore under heated chlorine atmosphere
Energy Technology Data Exchange (ETDEWEB)
Orosco, P., E-mail: porosco@unsl.edu.ar [Instituto de Investigaciones en Tecnología Química (INTEQUI-CONICET), Chacabuco y Pedernera, 5700 San Luis (Argentina); Ruiz, M. del C. [Instituto de Investigaciones en Tecnología Química (INTEQUI-CONICET), Chacabuco y Pedernera, 5700 San Luis (Argentina); Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); González, J. [Instituto de Investigaciones en Tecnología Química (INTEQUI-CONICET), Chacabuco y Pedernera, 5700 San Luis (Argentina); Instituto de Ciencias Básicas, Universidad Nacional de Cuyo, Mendoza (Argentina)
2013-02-20
Highlights: ► We studied the effect of Cl{sub 2} on minerals present in a talc of ultramafic origin. ► Isothermal and non-isothermal assays were performed in N{sub 2} and Cl{sub 2}–N{sub 2} atmospheres. ► The reagents and the products were analyzed by DTA, XRD, SEM, and EPMA. ► The chlorination produced protoenstatite at 800 °C. ► Calcination of a talc ore in Cl{sub 2} produces more enstatite than thermal treatment in N{sub 2}. - Abstract: The effect of Cl{sub 2} on the phase transformations of the minerals present in a talc (Mg{sub 3}Si{sub 4}O{sub 10}(OH){sub 2}) unpurified with clinochlore (Mg{sub 5}Al{sub 2}Si{sub 3}O{sub 10}(OH){sub 8}), magnesite (MgCO{sub 3}), dolomite (MgCa(CO{sub 3}){sub 2}), hematite (Fe{sub 2}O{sub 3}) and pyrite (FeS{sub 2}) was studied with the purpose of deferricating the mineral and obtaining protoenstatite (MgSiO{sub 3}), which is the basic component of steatite ceramics. Isothermal and non-isothermal assays in N{sub 2} and Cl{sub 2}–N{sub 2} atmospheres were performed using a thermogravimetric device at temperatures between 600 and 980 °C. The reagents and the products were analyzed by differential thermal analysis (DTA), X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). Results obtained showed that the following phenomena were produced in Cl{sub 2}: (a) The transformation of vitreous silica (SiO{sub 2}), from the chlorination reaction of talc, into enstatite (MgSiO{sub 3}) started at about 700 °C, being dolomite the mineral that favored this reaction. At 800 °C, more enstatite was formed as a result of the reaction between vitreous silica not transformed, MgCl{sub 2} and O{sub 2} derived from the chlorination of dolomite and magnesite; then, polymorphic transformation of enstatite into protoenstatite was produced. (b) At about 950 °C, CaCl{sub 2} produced as a result of dolomite chlorination led to the destruction of the protoenstatite
Kinetics of phase transformation and optical property of pink coral zirconia powders
International Nuclear Information System (INIS)
Chu, Hsueh-Liang; Wang, Cheng-Li; Hwang, Weng-Sing; Lee, Kuen-Chan; Zhou, Xuedong; Wang, Moo-Chin
2014-01-01
Highlights: • The single phase of tetragonal ZrO 2 formed when calcined at 1223 K for 1 h. • The tetragonal ZrO 2 fully converted to ZrSiO 4 when calcined at 1323–1473 K for 1 h. • The activation energy of t-ZrO 2 formed is 399.9 kJ/mol when 5 mol% Fe 2 O 3 added. • The activation energy of the Fe/ZrSiO 4 formed is 257.7 kJ/mol when 5 mol% Fe 2 O 3 added. • The growth morphology parameter and crystallization index are about 2.0 and 1.0. - Abstract: The kinetics of phase transformation and optical property of pink coral zircon powders have been studied. The ZrO 2 –SiO 2 –Fe 2 O 3 precursor powders were synthesized using Zr(NO 3 ) 4 ⋅4H 2 O, Si(C 2 H 5 O) 4 and Fe(NO 3 ) 3 ⋅9H 2 O as initial materials via the hot–wet routes. The kinetics of phase transformation of the ZrO 2 –SiO 2 –Fe 2 O 3 precursor powders was characterized by thermo-gravimetric (TG)/differential scanning calorimeter (DSC), X-ray diffraction (XRD), transmission electron microscopy (TEM), nano-beam electron diffraction (NBED), and spectrophotometry. The crystallization temperatures of tetragonal zirconia (t-ZrO 2 ) and zircon (ZrSiO 4 ) of ZrO 2 –SiO 2 precursor powders with 1 mol% Fe 2 O 3 were estimated to be approximately 1204 K and 1496 K, respectively, based on a DSC analysis conducted at a heating rate of 20 K/min. The activation energies of t-ZrO 2 formulation are 428.2, 403.2, and 399.9 kJ/mol, respectively, for ZrO 2 –SiO 2 precursor powders containing 1, 3, and 5 mol% Fe 2 O 3 , respectively, whereas the activation energies of the Fe/ZrSiO 4 formulation are 271.9, 261.9, and 257.7 kJ/mol, respectively. The parameter of growth morphology (n) and index of crystallization (m) were approximated as 2.0 and 1.0, respectively, meaning that two-dimensional growth with plate-like morphology was the primary mechanism of ZrO 2 crystallization from ZrO 2 –SiO 2 –Fe 2 O 3 precursor powders. The XRD results show that when the precursor powders of ZrO 2 –SiO 2 –1 mol
Wetting of two-dimensional physically patterned surfaces
Bell, Michael Scott
features. In this work, we relax these assumptions. We begin by investigating the role of hierarchical roughness (specifically dual-scale roughness) in affecting static contact angles by making no assumptions other than that the effect of gravity is negligible, though the surface features are allowed to be similar in size to the droplet. By investigating phase diagrams of contact angles as a function of surface feature parameters, we find that the nanoscale roughness in hierarchical roughness serves mainly to amplify the intrinsic contact angle of the macroscale roughness, thereby allowing for large contact angles on relatively low aspect ratio macroscale structures. Next, we lift the assumption of the negligible effect of gravity, and consider arbitrarily-sized droplets relative to the surface features, for which the effect of gravity is non-negligible. From this, we find that the effect of gravity is primarily to shift the boundary between the Cassie and Wenzel modes in the phase diagram. Other effects of gravity on contact angles occur mainly when the drops are similar in size to the surface features. Further, by comparing predictions of a circular cap model with a deformable cap model, we find that the gravitationally-induced deformations mainly affect the contact angle, with the equilibrium wetting configurations predicted by both models being otherwise quite similar. Both of these studies reinforce the idea that pinning effects become less important when the surface features become much smaller than the drop size. We next explore this regime, in which the Cassie and Wenzel models become valid, in more detail. Specifically, we use perturbation theory to derive a correction to the Wenzel equation to properly account for the volume of liquid stored in the grooves which was not considered in the original derivation. By considering both the two- and three-dimensional cases, we find an intuitive explanation for the two-dimensional correction which unfortunately breaks down
The influence of peak shock stress on the high pressure phase transformation in Zr
International Nuclear Information System (INIS)
Cerreta, E K; Addessio, F L; Bronkhorst, C A; Brown, D W; Escobedo, J P; Fensin, S J; Gray, G T III; Lookman, T; Rigg, P A; Trujillo, C P
2014-01-01
At high pressures zirconium is known to undergo a phase transformation from the hexagonal close packed (HCP) alpha phase to the simple hexagonal omega phase. Under conditions of shock loading, a significant volume fraction of high-pressure omega phase is retained upon release. However, the hysteresis in this transformation is not well represented by equilibrium phase diagrams and the multi-phase plasticity under shock conditions is not well understood. For these reasons, the influence of peak shock stress and temperature on the retention of omega phase in Zr has been explored. VISAR and PDV measurements along with post-mortem metallographic and neutron diffraction characterization of soft recovered specimens have been utilized to quantify the volume fraction of retained omega phase and qualitatively understand the kinetics of this transformation. In turn, soft recovered specimens with varying volume fractions of retained omega phase have been utilized to understand the contribution of omega and alpha phases to strength in shock loaded Zr.
Liu, Erqiang; Xiao, Gesheng; Jia, Wufei; Shu, Xuefeng; Yang, Xuexia; Wang, Yulei
2017-11-01
To study the tetragonal-to-monoclinic (T-M) phase transformation behavior under different strain rates and indentation depths, nanoindentation tests were performed on stabilized zirconia ceramics with Continuous Stiffness Measurements. The results indicate decreased phase transformation velocities at both lower and higher strain rates, but increased velocity under medium strain rate during loading. The phase transformation process is sensitive to Ṗ/P but the final volume fractions are almost identical (45%). Furthermore, most of the phase transformation is completed during a short initial time followed by slight linear increase of the M-phase volume fraction with holding time. The phase transformation continuously slowed with increasing indentation depth when indented with a constant strain rate. Copyright © 2017 Elsevier Ltd. All rights reserved.
Two dimensional NMR of liquids and oriented molecules
Energy Technology Data Exchange (ETDEWEB)
Gochin, M.
1987-02-01
Chapter 1 discusses the quantum mechanical formalism used for describing the interaction between magnetic dipoles that dictates the appearance of a spectrum. The NMR characteristics of liquids and liquid crystals are stressed. Chapter 2 reviews the theory of multiple quantum and two dimensional NMR. Properties of typical spectra and phase cycling procedures are discussed. Chapter 3 describes a specific application of heteronuclear double quantum coherence to the removal of inhomogeneous broadening in liquids. Pulse sequences have been devised which cancel out any contribution from this inhomogeneity to the final spectrum. An interpretation of various pulse sequences for the case of /sup 13/C and /sup 1/H is given, together with methods of spectral editing by removal or retention of the homo- or heteronuclear J coupling. The technique is applied to a demonstration of high resolution in both frequency and spatial dimensions with a surface coil. In Chapter 4, multiple quantum filtered 2-D spectroscopy is demonstrated as an effective means of studying randomly deuterated molecules dissolved in a nematic liquid crystal. Magnitudes of dipole coupling constants have been determined for benzene and hexane, and their signs and assignments found from high order multiple quantum spectra. For the first time, a realistic impression of the conformation of hexane can be estimated from these results. Chapter 5 is a technical description of the MDB DCHIB-DR11W parallel interface which has been set up to transfer data between the Data General Nova 820 minicomputer, interfaced to the 360 MHz spectrometer, and the Vax 11/730. It covers operation of the boards, physical specifications and installation, and programs for testing and running the interface.
Periodic trajectories for a two-dimensional nonintegrable Hamiltonian
International Nuclear Information System (INIS)
Baranger, M.; Davies, K.T.R.
1987-01-01
A numerical study is made of the classical periodic trajectories for the two-dimensional nonintegrable Hamiltonian H = 1/2(p 2 /sub x/+p 2 /sub y/)+(y-1/2x 2 ) 2 +0.05 x 2 . In addition to x--y pictures of the trajectories, E--tau (energy--period) plots of the periodic families are presented. Efforts have been ade to include all trajectories with short periods and all simple branchings of these trajectories. The monodromy matrix has been calculated in all cases, and from it the stability properties are derived. The topology of the E--tau plot has been explored, with the following results. One family may have several stable regions. The plot is not completely connected; there are islands. The plot is not a tree; there are cycles. There are isochronous branchings, period-doublings, and period-multiplyings of higher orders, and examples of each of these are presented. There is often more than one branch issuing from a branch point. Some general empirical rules are inferred. In particular, the existence of isochronous branching is seen to be a consequence of the symmetry of the Hamiltonian. All these results agree with the general classification of possible branchings derived in Ref. [10]. (M. A. M. de Aguiar, C. P. Malta, M. Baranger, and K. T. R. Davies, in preparation). Finally, some nonperiodic trajectories are calculated to illustrate the fact that stable periodic trajectories lie in ''regular'' regions of phase space, while unstable ones lie in ''chaotic'' regions
Two dimensional NMR of liquids and oriented molecules
International Nuclear Information System (INIS)
Gochin, M.
1987-02-01
Chapter 1 discusses the quantum mechanical formalism used for describing the interaction between magnetic dipoles that dictates the appearance of a spectrum. The NMR characteristics of liquids and liquid crystals are stressed. Chapter 2 reviews the theory of multiple quantum and two dimensional NMR. Properties of typical spectra and phase cycling procedures are discussed. Chapter 3 describes a specific application of heteronuclear double quantum coherence to the removal of inhomogeneous broadening in liquids. Pulse sequences have been devised which cancel out any contribution from this inhomogeneity to the final spectrum. An interpretation of various pulse sequences for the case of 13 C and 1 H is given, together with methods of spectral editing by removal or retention of the homo- or heteronuclear J coupling. The technique is applied to a demonstration of high resolution in both frequency and spatial dimensions with a surface coil. In Chapter 4, multiple quantum filtered 2-D spectroscopy is demonstrated as an effective means of studying randomly deuterated molecules dissolved in a nematic liquid crystal. Magnitudes of dipole coupling constants have been determined for benzene and hexane, and their signs and assignments found from high order multiple quantum spectra. For the first time, a realistic impression of the conformation of hexane can be estimated from these results. Chapter 5 is a technical description of the MDB DCHIB-DR11W parallel interface which has been set up to transfer data between the Data General Nova 820 minicomputer, interfaced to the 360 MHz spectrometer, and the Vax 11/730. It covers operation of the boards, physical specifications and installation, and programs for testing and running the interface
Complex Path Integrals and Saddles in Two-Dimensional Gauge Theory.
Buividovich, P V; Dunne, Gerald V; Valgushev, S N
2016-04-01
We study numerically the saddle point structure of two-dimensional lattice gauge theory, represented by the Gross-Witten-Wadia unitary matrix model. The saddle points are, in general, complex valued, even though the original integration variables and action are real. We confirm the trans-series and instanton gas structure in the weak-coupling phase, and we identify a new complex-saddle interpretation of nonperturbative effects in the strong-coupling phase. In both phases, eigenvalue tunneling refers to eigenvalues moving off the real interval, into the complex plane, and the weak-to-strong coupling phase transition is driven by saddle condensation.
Knowledge-aided Two-dimensional Autofocus for Spotlight SAR Polar Format Imagery
Mao, Xinhua
2015-01-01
Conventional two-dimensional (2-D) autofocus algorithms blindly estimate the phase error in the sense that they do not exploit any a priori information on the structure of the 2-D phase error. As such, they often suffer from low computational efficiency and lack of data redundancy to accurately estimate the 2-D phase error. In this paper, a knowledge-aided (KA) 2-D autofocus algorithm which is based on exploiting a priori knowledge about the 2-D phase error structure, is presented. First, as ...
Traditional Semiconductors in the Two-Dimensional Limit
Lucking, Michael C.; Xie, Weiyu; Choe, Duk-Hyun; West, Damien; Lu, Toh-Ming; Zhang, S. B.
2018-02-01
Interest in two-dimensional materials has exploded in recent years. Not only are they studied due to their novel electronic properties, such as the emergent Dirac fermion in graphene, but also as a new paradigm in which stacking layers of distinct two-dimensional materials may enable different functionality or devices. Here, through first-principles theory, we reveal a large new class of two-dimensional materials which are derived from traditional III-V, II-VI, and I-VII semiconductors. It is found that in the ultrathin limit the great majority of traditional binary semiconductors studied (a series of 28 semiconductors) are not only kinetically stable in a two-dimensional double layer honeycomb structure, but more energetically stable than the truncated wurtzite or zinc-blende structures associated with three dimensional bulk. These findings both greatly increase the landscape of two-dimensional materials and also demonstrate that in the double layer honeycomb form, even ordinary semiconductors, such as GaAs, can exhibit exotic topological properties.
DEFF Research Database (Denmark)
Dahl, Jens Peder; Schleich, W. P.
2009-01-01
For a closed quantum system the state operator must be a function of the Hamiltonian. When the state is degenerate, additional constants of the motion enter the play. But although it is the Weyl transform of the state operator, the Wigner function is not necessarily a function of the Weyl...... transforms of the constants of the motion. We derive conditions for which this is actually the case. The Wigner functions of the energy eigenstates of a two-dimensional isotropic harmonic oscillator serve as an important illustration....
Fermion emission in a two-dimensional black hole space-time
International Nuclear Information System (INIS)
Wanders, G.
1994-01-01
We investigate massless fermion production by a two-dimensional dilatonic black hole. Our analysis is based on the Bogoliubov transformation relating the outgoing fermion field observed outside the black hole horizon to the incoming field present before the black hole creation. It takes full account of the fact that the transformation is neither invertible nor unitarily implementable. The particle content of the outgoing radiation is specified by means of inclusive probabilities for the detection of sets of outgoing fermions and antifermions in given states. For states localized near the horizon these probabilities characterize a thermal equilibrium state. The way the probabilities become thermal as one approaches the horizon is discussed in detail
Directory of Open Access Journals (Sweden)
I. V. Novash
2015-01-01
Full Text Available This article describes the parameters calculation for the three-phase two-winding power transformer model taken from the SimPowerSystems library, which is the part of the MatLab- Simulink environment. Presented methodology is based on the power transformer nameplate data usage. Particular attention is paid to the power transformer magnetization curve para- meters calculation. The methodology of the three-phase two-winding power transformer model parameters calculation considering the magnetization curve nonlinearity isn’t presented in Russian-and English-language sources. Power transformers demo models described in the SimPowerSystems user’s guide have already calculated parameters, but without reference to the sources of their determination. A power transformer is a nonlinear element of the power system, that’s why for its performance analysis in different modes of operation is necessary to have the magnetization curve parameters.The process analysis during no-load energizing of the power transformer is of special interest. This regime is accompanied by the inrush current on the supply side of the power transformer, which is several times larger than the transformer rated current. Sharp rising of the magnetizing current is explained by the magnetic core saturation. Therefore, magnetiza- tion characteristic accounting during transformer no-load energizing modeling is a mandatory requirement. Article authors attempt to put all calculating formulas in a more convenient form and validate the power transformer nonlinear magnetization characteristics parameters calcu- lation. Inrush current oscillograms obtained during the simulation experiment confirmed the adequacy of the calculated model parameters.
Two-Dimensional Superfluidity of Exciton Polaritons Requires Strong Anisotropy
Directory of Open Access Journals (Sweden)
Ehud Altman
2015-02-01
Full Text Available Fluids of exciton polaritons, excitations of two-dimensional quantum wells in optical cavities, show collective phenomena akin to Bose condensation. However, a fundamental difference from standard condensates stems from the finite lifetime of these excitations, which necessitates continuous driving to maintain a steady state. A basic question is whether a two-dimensional condensate with long-range algebraic correlations can exist under these nonequilibrium conditions. Here, we show that such driven two-dimensional Bose systems cannot exhibit algebraic superfluid order except in low-symmetry, strongly anisotropic systems. Our result implies, in particular, that recent apparent evidence for Bose condensation of exciton polaritons must be an intermediate-scale crossover phenomenon, while the true long-distance correlations fall off exponentially. We obtain these results through a mapping of the long-wavelength condensate dynamics onto the anisotropic Kardar-Parisi-Zhang equation.
Hamiltonian formalism of two-dimensional Vlasov kinetic equation.
Pavlov, Maxim V
2014-12-08
In this paper, the two-dimensional Benney system describing long wave propagation of a finite depth fluid motion and the multi-dimensional Russo-Smereka kinetic equation describing a bubbly flow are considered. The Hamiltonian approach established by J. Gibbons for the one-dimensional Vlasov kinetic equation is extended to a multi-dimensional case. A local Hamiltonian structure associated with the hydrodynamic lattice of moments derived by D. J. Benney is constructed. A relationship between this hydrodynamic lattice of moments and the two-dimensional Vlasov kinetic equation is found. In the two-dimensional case, a Hamiltonian hydrodynamic lattice for the Russo-Smereka kinetic model is constructed. Simple hydrodynamic reductions are presented.
A nonperturbative treatment of two-dimensional quantum gravity
International Nuclear Information System (INIS)
Gross, D.J.; Migdal, A.A.
1990-01-01
We propose a nonperturbative definition of two-dimensional quantum gravity, based on a double scaling limit of the random matrix model. We develop an operator formalism for utilizing the method of orthogonal polynomials that allows us to solve the matrix models to all orders in the genus expansion. Using this formalism we derive an exact differential equation for the partition function of two-dimensional gravity as a function of the string coupling constant that governs the genus expansion of two-dimensional surfaces, and discuss its properties and consequences. We construct and discuss the correlation functions of an infinite set of pointlike and loop operators to all orders in the genus expansion. (orig.)
Control Operator for the Two-Dimensional Energized Wave Equation
Directory of Open Access Journals (Sweden)
Sunday Augustus REJU
2006-07-01
Full Text Available This paper studies the analytical model for the construction of the two-dimensional Energized wave equation. The control operator is given in term of space and time t independent variables. The integral quadratic objective cost functional is subject to the constraint of two-dimensional Energized diffusion, Heat and a source. The operator that shall be obtained extends the Conjugate Gradient method (ECGM as developed by Hestenes et al (1952, [1]. The new operator enables the computation of the penalty cost, optimal controls and state trajectories of the two-dimensional energized wave equation when apply to the Conjugate Gradient methods in (Waziri & Reju, LEJPT & LJS, Issues 9, 2006, [2-4] to appear in this series.
On integrability of a noncommutative q-difference two-dimensional Toda lattice equation
Energy Technology Data Exchange (ETDEWEB)
Li, C.X., E-mail: trisha_li2001@163.com [School of Mathematical Sciences, Capital Normal University, Beijing 100048 (China); Department of Mathematics, College of Charleston, Charleston, SC 29401 (United States); Nimmo, J.J.C., E-mail: jonathan.nimmo@glasgow.ac.uk [School of Mathematics and Statistics, University of Glasgow, Glasgow G12 8QW (United Kingdom); Shen, Shoufeng, E-mail: mathssf@zjut.edu.cn [Department of Applied Mathematics, Zhejiang University of Technology, Hangzhou 310023 (China)
2015-12-18
In our previous work (C.X. Li and J.J.C. Nimmo, 2009 [18]), we presented a generalized type of Darboux transformations in terms of a twisted derivation in a unified form. The twisted derivation includes ordinary derivatives, forward difference operators, super derivatives and q-difference operators as its special cases. This result not only enables one to recover the known Darboux transformations and quasideterminant solutions to the noncommutative KP equation, the non-Abelian two-dimensional Toda lattice equation, the non-Abelian Hirota–Miwa equation and the super KdV equation, but also inspires us to investigate quasideterminant solutions to q-difference soliton equations. In this paper, we first construct the bilinear Bäcklund transformations for the known bilinear q-difference two-dimensional Toda lattice equation (q-2DTL) and then derive a Lax pair whose compatibility gives a formally different nonlinear q-2DTL equation and finally obtain its quasideterminant solutions by iterating its Darboux transformations. - Highlights: • Examples are given to illustrate the extensive applications of twisted derivations. • Bilinear Bäcklund transformation is constructed for the known q-2DTL equation. • Lax pair is obtained for an equivalent q-2DTL equation. • Quasideterminant solutions are found for the nc q-2DTL equation.
Nonlinear excitations in two-dimensional molecular structures with impurities
DEFF Research Database (Denmark)
Gaididei, Yuri Borisovich; Rasmussen, Kim; Christiansen, Peter Leth
1995-01-01
We study the nonlinear dynamics of electronic excitations interacting with acoustic phonons in two-dimensional molecular structures with impurities. We show that the problem is reduced to the nonlinear Schrodinger equation with a varying coefficient. The latter represents the influence of the imp......We study the nonlinear dynamics of electronic excitations interacting with acoustic phonons in two-dimensional molecular structures with impurities. We show that the problem is reduced to the nonlinear Schrodinger equation with a varying coefficient. The latter represents the influence...... excitations. Analytical results are in good agreement with numerical simulations of the nonlinear Schrodinger equation....
Two-dimensional nonlinear equations of supersymmetric gauge theories
International Nuclear Information System (INIS)
Savel'ev, M.V.
1985-01-01
Supersymmetric generalization of two-dimensional nonlinear dynamical equations of gauge theories is presented. The nontrivial dynamics of a physical system in the supersymmetry and supergravity theories for (2+2)-dimensions is described by the integrable embeddings of Vsub(2/2) superspace into the flat enveloping superspace Rsub(N/M), supplied with the structure of a Lie superalgebra. An equation is derived which describes a supersymmetric generalization of the two-dimensional Toda lattice. It contains both super-Liouville and Sinh-Gordon equations
Two-dimensional SCFTs from D3-branes
Energy Technology Data Exchange (ETDEWEB)
Benini, Francesco [Blackett Laboratory, Imperial College London,South Kensington Campus, London SW7 2AZ (United Kingdom); International School for Advanced Studies (SISSA), Via Bonomea 265, 34136 Trieste (Italy); Bobev, Nikolay [Instituut voor Theoretische Fysica, KU Leuven, Celestijnenlaan 200D, B-3001 Leuven (Belgium); Crichigno, P. Marcos [Institute for Theoretical Physics and Spinoza Institute, Utrecht University,Leuvenlaan 4, 3854 CE Utrecht (Netherlands)
2016-07-05
We find a large class of two-dimensional N=(0,2) SCFTs obtained by compactifying four-dimensional N=1 quiver gauge theories on a Riemann surface. We study these theories using anomalies and c-extremization. The gravitational duals to these fixed points are new AdS{sub 3} solutions of IIB supergravity which we exhibit explicitly. Along the way we uncover a universal relation between the conformal anomaly coefficients of four-dimensional and two-dimensional SCFTs connected by an RG flow across dimensions. We also observe an interesting novel phenomenon in which the superconformal R-symmetry mixes with baryonic symmetries along the RG flow.
Densis. Densimetric representation of two-dimensional matrices
International Nuclear Information System (INIS)
Los Arcos Merino, J.M.
1978-01-01
Densis is a Fortran V program which allows off-line control of a Calcomp digital plotter, to represent a two-dimensional matrix of numerical elements in the form of a variable shading intensity map in two colours. Each matrix element is associated to a square of a grid which is traced over by lines whose number is a function of the element value according to a selected scale. Program features, subroutine structure and running instructions, are described. Some typical results, for gamma-gamma coincidence experimental data and a sampled two-dimensional function, are indicated. (author)
Two dimensional nonlinear spectral estimation techniques for breast cancer localization
International Nuclear Information System (INIS)
Stathaki, P.T.; Constantinides, A.G.
1994-01-01
In this paper the problem of image texture analysis in the presence of noise is examined from a higher-order statistical perspective. The approach taken involves the use of two dimensional second order Volterra filters where the filter weights are derived from third order cumulants of the two dimensional signal. The specific application contained in this contribution is in mammography, an area in which it is difficult to discern the appropriate features. The paper describes the fundamental issues of the various components of the approach. The results of the entire texture modelling, classification and segmentation scheme contained in this paper are very encouraging
Spin dynamics in a two-dimensional quantum gas
DEFF Research Database (Denmark)
Pedersen, Poul Lindholm; Gajdacz, Miroslav; Deuretzbacher, Frank
2014-01-01
We have investigated spin dynamics in a two-dimensional quantum gas. Through spin-changing collisions, two clouds with opposite spin orientations are spontaneously created in a Bose-Einstein condensate. After ballistic expansion, both clouds acquire ring-shaped density distributions with superimp......We have investigated spin dynamics in a two-dimensional quantum gas. Through spin-changing collisions, two clouds with opposite spin orientations are spontaneously created in a Bose-Einstein condensate. After ballistic expansion, both clouds acquire ring-shaped density distributions...... with nonlocal Einstein-Podolsky-Rosen entanglement....
Two-dimensional spin diffusion in multiterminal lateral spin valves
Saha, D.; Basu, D.; Holub, M.; Bhattacharya, P.
2008-01-01
The effects of two-dimensional spin diffusion on spin extraction in lateral semiconductor spin valves have been investigated experimentally and theoretically. A ferromagnetic collector terminal of variable size is placed between the ferromagnetic electron spin injector and detector of a conventional lateral spin valve for spin extraction. It is observed that transverse spin diffusion beneath the collector terminal plays an important role along with the conventional longitudinal spin diffusion in describing the overall transport of spin carriers. Two-dimensional spin diffusion reduces the perturbation of the channel electrochemical potentials and improves spin extraction.
Model of two-dimensional electron gas formation at ferroelectric interfaces
Energy Technology Data Exchange (ETDEWEB)
Aguado-Puente, P.; Bristowe, N. C.; Yin, B.; Shirasawa, R.; Ghosez, Philippe; Littlewood, P. B.; Artacho, Emilio
2015-07-01
The formation of a two-dimensional electron gas at oxide interfaces as a consequence of polar discontinuities has generated an enormous amount of activity due to the variety of interesting effects it gives rise to. Here, we study under what circumstances similar processes can also take place underneath ferroelectric thin films. We use a simple Landau model to demonstrate that in the absence of extrinsic screening mechanisms, a monodomain phase can be stabilized in ferroelectric films by means of an electronic reconstruction. Unlike in the LaAlO3/SrTiO3 heterostructure, the emergence with thickness of the free charge at the interface is discontinuous. This prediction is confirmed by performing first-principles simulations of free-standing slabs of PbTiO3. The model is also used to predict the response of the system to an applied electric field, demonstrating that the two-dimensional electron gas can be switched on and off discontinuously and in a nonvolatile fashion. Furthermore, the reversal of the polarization can be used to switch between a two-dimensional electron gas and a two-dimensional hole gas, which should, in principle, have very different transport properties. We discuss the possible formation of polarization domains and how such configuration competes with the spontaneous accumulation of free charge at the interfaces.
Deformation-induced phase transformation in 4H–SiC nanopillars
International Nuclear Information System (INIS)
Chen, Bin; Wang, Jun; Zhu, Yiwei; Liao, Xiaozhou; Lu, Chunsheng; Mai, Yiu-Wing; Ringer, Simon P.; Ke, Fujiu; Shen, Yaogen
2014-01-01
The deformation behaviour of single-crystal SiC nanopillars was studied by a combination of in situ deformation transmission electron microscopy and molecular dynamics simulations. An unexpected deformation-induced phase transformation from the 4H hexagonal structure to the 3C face-centred cubic structure was observed in these nanopillars at room temperature. Atomistic simulations revealed that the 4H to 3C phase transformation follows a stick–slip process with initiation and end stresses of 12.1–14.0 and 7.9–9.0 GPa, respectively. The experimentally measured stress of 9–10 GPa for the phase transformation falls within the range of these theoretical upper and lower stresses. The reasons for the phase transformation are discussed. The finding sheds light on the understanding of phase transformation in polytypic materials at low temperature
Zhang, Xudong; Ren, Junqiang; Wang, Xiaofei; Zong, Hongxiang; Cui, Lishan; Ding, Xiangdong
2017-12-01
A continuous martensite transformation is indispensable for achieving large linear superelasticity and low modulus in phase transforming metal-based composites. However, determining how to accurately condition the residual martensite in a shape memory alloy matrix though the reinforcement shape to achieve continuous martensite transformation has been a challenge. Here, we take the finite element method to perform a comparative study of the effects of nanoinclusion shape on the interaction and martensite phase transformation in this new composite. Two typical samples are compared: one reinforced by metallic nanowires and the other by nanoparticles. We find that the residual martensite within the shape memory alloy matrix after a pretreatment can be tailored by the reinforcement shape. In particular, our results show that the shape memory alloy matrix can retain enough residual martensite phases to achieve continuous martensite transformation in the subsequent loading when the aspect ratio of nanoreinforcement is larger than 20. In contrast, the composites reinforced with spherical or low aspect ratio reinforcement show a typical nonlinear superelasticity as a result of a low stress transfer-induced discontinuous martensite transformation within the shape memory alloy matrix.
String field theory in minimal model backgrounds and non-perturbative two-dimensional gravity
International Nuclear Information System (INIS)
Imbimbo, C.; Mukhi, S.
1991-01-01
The classical phase space of free closed-string field theory in the background of (p,q) minimal models is studied. It is shown that in the limit q→∞ for fixed p, this becomes the phase space of p-1 massless chiral bosons on a two-dimensional target space, twisted by Z p . It is argued that in the interacting theory, the bosons remain free and massless in the limit, but the non-linear gauge symmetries of string field theory require the imposition of W p -algebra conditions on the Hilbert space, allowing a single physical state. The wave function for this state is the KdV τ-function associated to non-perturbative two-dimensional gravity in the matrix-model approach. (orig.)
Analysis of the Scramjet inlet flow field using two-dimensional Navier-Stokes equations
Kumar, A.; Tiwari, S. N.
1982-01-01
A computer code was developed to solve the full two dimensional Navier-Stokes equations in a scramjet inlet. The analysis uses a numerical coordinate transformation which generates a set of boundary-fitted curvilinear coordinates. The explicit finite difference algorithm of MacCormack is used to solve the governing equations. A two-layer eddy viscosity model is used for the turbulent flow. The code can analyze both inviscid and viscous flows with multiple struts in the flow field. Detailed results are presented for two model problems and two scramjet inlets with one and two struts. The application of the two dimensional analysis in the preliminary design of the actual scramjet inlet is briefly discussed.
Phase transformation kinetics and microstructure of NiTi shape ...
Indian Academy of Sciences (India)
2017-07-28
Jul 28, 2017 ... Abstract. The effect of hydrostatic pressure on the behaviour of reverse and forward transformation temperatures and physical properties of NiTi shape memory alloy has been investigated. The transformation temperatures and physical prop- erties of the alloy change with applied pressure. It has been ...
Peculiarities of phase transformation in Ni3Fe powder alloy
International Nuclear Information System (INIS)
Nuzhdin, A.A.
1990-01-01
Ordering process in sintered powder alloy Ni 3 Fe by normal and high temperatures was studied. Thermal stresses connected with porosity level of material effect on transformation peculiarities. The changes of electric conductivity, thermal expansion coefficient, bulk modulus during transformation were studied. The analysis of this changes was made
Phase transformation kinetics and microstructure of NiTi shape ...
Indian Academy of Sciences (India)
2017-07-28
Jul 28, 2017 ... stress and temperature, as the external driving forces, on the transformation. The shape memory effect is also related to the martensitic transformation that is essential, and an alloy exhibiting thermoelastic martensitic transition is deformed or bent at a temperature below the martensite finish temperature,.
DEFF Research Database (Denmark)
Guan, Pengyu; Da Ros, Francesco; Lillieholm, Mads
2016-01-01
We demonstrate simultaneous phase regeneration of 16-WDM DPSK channels using optical Fourier transformation and a single phase-sensitive amplifier. The BERs of 16-WDM×10-Gbit/s phase noise degraded DPSK signals are improved by 0.4-1.3 orders of magnitude......We demonstrate simultaneous phase regeneration of 16-WDM DPSK channels using optical Fourier transformation and a single phase-sensitive amplifier. The BERs of 16-WDM×10-Gbit/s phase noise degraded DPSK signals are improved by 0.4-1.3 orders of magnitude...
DEFF Research Database (Denmark)
Guan, Pengyu; Røge, Kasper Meldgaard; Kjøller, Niels-Kristian
2015-01-01
We propose a novel all-optical WDM regeneration scheme for DPSK signals based on optical Fourier transformation and phase sensitive amplification. Phase regeneration of a WDM signal consisting of 4x10-Gbit/s phase noise degraded DPSK channels is demonstrated for the first time.......We propose a novel all-optical WDM regeneration scheme for DPSK signals based on optical Fourier transformation and phase sensitive amplification. Phase regeneration of a WDM signal consisting of 4x10-Gbit/s phase noise degraded DPSK channels is demonstrated for the first time....