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Sample records for two-dimensional infrared 2d

  1. Chemical profiling and adulteration screening of Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy.

    Science.gov (United States)

    Qu, Lei; Chen, Jian-Bo; Zhang, Gui-Jun; Sun, Su-Qin; Zheng, Jing

    2017-03-05

    As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p=0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR.

  2. Chemical profiling and adulteration screening of Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy

    Science.gov (United States)

    Qu, Lei; Chen, Jian-bo; Zhang, Gui-Jun; Sun, Su-qin; Zheng, Jing

    2017-03-01

    As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p = 0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR.

  3. Near-infrared (NIR) monitoring of Nylon 6 during quenching studied by projection two-dimensional (2D) correlation spectroscopy

    Science.gov (United States)

    Shinzawa, Hideyuki; Mizukado, Junji

    2016-11-01

    Evolutionary change in supermolecular structure of Nylon 6 during its melt-quenched process was studied by Near-infrared (NIR) spectroscopy. Time-resolved NIR spectra was measured by taking the advantage of high-speed NIR monitoring based on an acousto-optic tunable filter (AOTF). Fine spectral features associated with the variation of crystalline and amorphous structure occurring in relatively short time scale were readily captured. For example, synchronous and asynchronous 2D correlation spectra reveal the initial decrease in the contribution of the NIR band at 1485 nm due to the amorphous structure, predominantly existing in the melt Nylon 6. This is then followed by the emerging contribution of the band intensity at 1535 nm associated with the crystalline structure. Consequently, the results clearly demonstrate a definite advantage of the high-speed NIR monitoring for analyzing fleeting phenomena.

  4. Two-dimensional (2D) infrared correlation study of the structural characterization of a surface immobilized polypeptide film stimulated by pH

    Science.gov (United States)

    Chae, Boknam; Son, Seok Ho; Kwak, Young Jun; Jung, Young Mee; Lee, Seung Woo

    2016-11-01

    The pH-induced structural changes to surface immobilized poly (L-glutamic acid) (PLGA) films were examined by Fourier transform infrared (FTIR) spectroscopy and two-dimensional (2D) correlation analysis. Significant spectral changes were observed in the FTIR spectra of the surface immobilized PLGA film between pH 6 and 7. The 2D correlation spectra constructed from the pH-dependent FTIR spectra of the surface immobilized PLGA films revealed the spectral changes induced by the alternations of the protonation state of the carboxylic acid group in the PLGA side chain. When the pH was increased from 6 to 8, weak spectral changes in the secondary structure of the PLGA main chain were induced by deprotonation of the carboxylic acid side group.

  5. Two-dimensional correlation spectroscopy (2D-COS) variable selection for near-infrared microscopy discrimination of meat and bone meal in compound feed.

    Science.gov (United States)

    Lü, Chengxu; Chen, Longjian; Yang, Zengling; Liu, Xian; Han, Lujia

    2014-01-01

    This article presents a novel method for combining auto-peak and cross-peak information for sensitive variable selection in synchronous two-dimensional correlation spectroscopy (2D-COS). This variable selection method is then applied to the case of near-infrared (NIR) microscopy discrimination of meat and bone meal (MBM). This is of important practical value because MBM is currently banned in ruminate animal compound feed. For the 2D-COS analysis, a set of NIR spectroscopy data of compound feed samples (adulterated with varying concentrations of MBM) was pretreated using standard normal variate and detrending (SNVD) and then mapped to the 2D-COS synchronous matrix. For the auto-peak analysis, 12 main sensitive variables were identified at 6852, 6388, 6320, 5788, 5600, 5244, 4900, 4768, 4572, 4336, 4256, and 4192 cm(-1). All these variables were assigned their specific spectral structure and chemical component. For the cross-peak analysis, these variables were divided into two groups, each group containing the six sensitive variables. This grouping resulted in a correlation between the spectral variables that was in accordance with the chemical-component content of the MBM and compound feed. These sensitive variables were then used to build a NIR microscopy discrimination model, which yielded a 97% correct classification. Moreover, this method detected the presence of MBM when its concentration was less than 1% in an adulterated compound feed sample. The concentration-dependent 2D-COS-based variable selection method developed in this study has the unique advantages of (1) introducing an interpretive aspect into variable selection, (2) substantially reducing the complexity of the computations, (3) enabling the transferability of the results to discriminant analysis, and (4) enabling the efficient compression of spectral data.

  6. Near-infrared (NIR) imaging analysis of polylactic acid (PLA) nanocomposite by multiple-perturbation two-dimensional (2D) correlation spectroscopy

    Science.gov (United States)

    Shinzawa, Hideyuki; Murakami, Takurou N.; Nishida, Masakazu; Kanematsu, Wataru; Noda, Isao

    2014-07-01

    Multiple-perturbation two-dimensional (2D) correlation spectroscopy was applied to sets of near-infrared (NIR) imaging data of polylactic acid (PLA) nanocomposite samples undergoing UV degradation. Incorporation of clay nanoparticles substantially lowers the surface free energy barrier for the nucleation of PLA and eventually increases the frequency of the spontaneous nucleation of PLA crystals. Thus, when exposed to external stimuli such as UV light, PLA nanocomposite may show different structure alternation depending on the clay dispersion. Multiple-perturbation 2D correlation analysis of the PLA nanocomposite samples revealed different spatial variation between crystalline and amorphous structure of PLA, and the phenomenon especially becomes acute in the region where the clay particles are coagulated. The incorporation of the clay leads to the cleavage-induced crystallization of PLA when the sample is subjected to the UV light. The additional development of the ordered crystalline structure then works favorably to restrict the initial degradation of the polymer, providing the delay in the weight loss of the PLA.

  7. Two-Dimensional Gel Electrophoresis and 2D-DIGE.

    Science.gov (United States)

    Meleady, Paula

    2018-01-01

    Two-dimensional polyacrylamide gel electrophoresis (2D-PAGE) continues to be one of the most versatile and widely used techniques to study the proteome of a biological system. In particular, a modified version of 2D-PAGE, two-dimensional difference gel electrophoresis (2D-DIGE), which uses differential labeling of protein samples with up to three fluorescent tags, offers greater sensitivity and reproducibility over conventional 2D-PAGE gels for differential quantitative analysis of protein expression between experimental groups. Both these methods have distinct advantages in the separation and identification of thousands of individual proteins species including protein isoforms and post-translational modifications. This review will discuss the principles of 2D-PAGE and 2D-DIGE including limitations to the methods. 2D-PAGE and 2D-DIGE continue to be popular methods in bioprocessing-related research (particularly on recombinant Chinese hamster ovary cells), which will also be discussed in the review chapter.

  8. Ultrafast two dimensional infrared chemical exchange spectroscopy

    Science.gov (United States)

    Fayer, Michael

    2011-03-01

    The method of ultrafast two dimensional infrared (2D IR) vibrational echo spectroscopy is described. Three ultrashort IR pulses tuned to the frequencies of the vibrational transitions of interest are directed into the sample. The interaction of these pulses with the molecular vibrational oscillators produces a polarization that gives rise to a fourth pulse, the vibrational echo. The vibrational echo pulse is combined with another pulse, the local oscillator, for heterodyne detection of the signal. For fixed time between the second and third pulses, the waiting time, the first pulse is scanned. Two Fourier transforms of the data yield a 2D IR spectrum. The waiting time is increased, and another spectrum is obtained. The change in the 2D IR spectra with increased waiting time provides information on the time evolution of the structure of the molecular system under observation. In a 2D IR chemical exchange experiment, two species A and B, are undergoing chemical exchange. A's are turning into B's, and B's are turning into A's, but the overall concentrations of the species are not changing. The kinetics of the chemical exchange on the ground electronic state under thermal equilibrium conditions can be obtained 2D IR spectroscopy. A vibration that has a different frequency for the two species is monitored. At very short time, there will be two peaks on the diagonal of the 2D IR spectrum, one for A and one for B. As the waiting time is increased, chemical exchange causes off-diagonal peaks to grow in. The time dependence of the growth of these off-diagonal peaks gives the chemical exchange rate. The method is applied to organic solute-solvent complex formation, orientational isomerization about a carbon-carbon single bond, migration of a hydrogen bond from one position on a molecule to another, protein structural substate interconversion, and water hydrogen bond switching between ions and water molecules. This work was supported by the Air Force Office of Scientific

  9. Two-Dimensional (2D) Polygonal Electromagnetic Cloaks

    Institute of Scientific and Technical Information of China (English)

    LI Chao; YAO Kan; LI Fang

    2009-01-01

    Transformation optics offers remarkable control over electromagnetic fields and opens an exciting gateway to design 'invisible cloak devices' recently.We present an important class of two-dimensional (2D) cloaks with polygon geometries.Explicit expressions of transformed medium parameters are derived with their unique properties investigated.It is found that the elements of diagonalized permittivity tensors are always positive within an irregular polygon cloak besides one element diverges to plus infinity and the other two become zero at the inner boundary.At most positions,the principle axes of permittivity tensors do not align with position vectors.An irregular polygon cloak is designed and its invisibility to external electromagnetic waves is numerically verified.Since polygon cloaks can be tailored to resemble any objects,the transformation is finally generalized to the realization of 2D cloaks with arbitrary geometries.

  10. A spectroelectrochemical cell for ultrafast two-dimensional infrared spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    El Khoury, Youssef; Van Wilderen, Luuk J. G. W.; Vogt, Tim; Winter, Ernst; Bredenbeck, Jens, E-mail: bredenbeck@biophysik.uni-frankfurt.org, E-mail: bredenbeck@biophysik.uni-frankfurt.de [Institut für Biophysik, Johann Wolfgang Goethe-Universität, Max-von-Laue-Strasse 1, 60438 Frankfurt (Germany)

    2015-08-15

    A spectroelectrochemical cell has been designed to combine electrochemistry and ultrafast two-dimensional infrared (2D-IR) spectroscopy, which is a powerful tool to extract structure and dynamics information on the femtosecond to picosecond time scale. Our design is based on a gold mirror with the dual role of performing electrochemistry and reflecting IR light. To provide the high optical surface quality required for laser spectroscopy, the gold surface is made by electron beam evaporation on a glass substrate. Electrochemical cycling facilitates in situ collection of ultrafast dynamics of redox-active molecules by means of 2D-IR. The IR beams are operated in reflection mode so that they travel twice through the sample, i.e., the signal size is doubled. This methodology is optimal for small sample volumes and successfully tested with the ferricyanide/ferrocyanide redox system of which the corresponding electrochemically induced 2D-IR difference spectrum is reported.

  11. A spectroelectrochemical cell for ultrafast two-dimensional infrared spectroscopy

    Science.gov (United States)

    El Khoury, Youssef; Van Wilderen, Luuk J. G. W.; Vogt, Tim; Winter, Ernst; Bredenbeck, Jens

    2015-08-01

    A spectroelectrochemical cell has been designed to combine electrochemistry and ultrafast two-dimensional infrared (2D-IR) spectroscopy, which is a powerful tool to extract structure and dynamics information on the femtosecond to picosecond time scale. Our design is based on a gold mirror with the dual role of performing electrochemistry and reflecting IR light. To provide the high optical surface quality required for laser spectroscopy, the gold surface is made by electron beam evaporation on a glass substrate. Electrochemical cycling facilitates in situ collection of ultrafast dynamics of redox-active molecules by means of 2D-IR. The IR beams are operated in reflection mode so that they travel twice through the sample, i.e., the signal size is doubled. This methodology is optimal for small sample volumes and successfully tested with the ferricyanide/ferrocyanide redox system of which the corresponding electrochemically induced 2D-IR difference spectrum is reported.

  12. Waiting Time Dynamics in Two-Dimensional Infrared Spectroscopy

    NARCIS (Netherlands)

    Jansen, Thomas L. C.; Knoester, Jasper

    We review recent work on the waiting time dynamics of coherent two-dimensional infrared (2DIR) spectroscopy. This dynamics can reveal chemical and physical processes that take place on the femto- and picosecond time scale, which is faster than the time scale that may be probed by, for example,

  13. Synchronous two-dimensional MIR correlation spectroscopy (2D-COS) as a novel method for screening smoke tainted wine.

    Science.gov (United States)

    Fudge, Anthea L; Wilkinson, Kerry L; Ristic, Renata; Cozzolino, Daniel

    2013-08-15

    In this study, two-dimensional correlation spectroscopy (2D-COS) combined with mid-infrared (MIR) spectroscopy was evaluated as a novel technique for the identification of spectral regions associated with smoke-affected wine, for the purpose of screening taint arising from grapevine exposure to smoke. Smoke-affected wines obtained from experimental and industry sources were analysed using MIR spectroscopy and chemometrics, and calibration models developed. 2D-COS analysis was used to generate synchronous data maps for red and white cask wines spiked with guaiacol, a marker of smoke taint. Correlations were observed at wavelengths that could be attributable to aromatic C-C stretching, i.e., between 1400 and 1500 cm(-1), indicative of volatile phenols. These results demonstrate the potential of 2D-COS as a rapid, high-throughput technique for the preliminary screening of smoke tainted wine.

  14. Status for the two-dimensional Navier-Stokes solver EllipSys2D

    DEFF Research Database (Denmark)

    Bertagnolio, F.; Sørensen, Niels N.; Johansen, J.

    2001-01-01

    This report sets up an evaluation of the two-dimensional Navier-Stokes solver EllipSys2D in its present state. This code is used for blade aerodynamics simulations in the Aeroelastic Design group at Risø. Two airfoils are investigated by computing theflow at several angles of attack ranging from...... the linear to the stalled region. The computational data are compared to experimental data and numerical results from other computational codes. Several numerical aspects are studied, as mesh dependency,convective scheme, steady state versus unsteady computations, transition modelling. Some general...... conclusions intended to help in using this code for numerical simulations are given....

  15. Bill2d -- a software package for classical two-dimensional Hamiltonian systems

    CERN Document Server

    Solanpää, Janne; Räsänen, Esa

    2016-01-01

    We present Bill2d, a modern and efficient C++ package for classical simulations of two-dimensional Hamiltonian systems. Bill2d can be used for various billiard and diffusion problems with one or more charged particles with interactions, different external potentials, an external magnetic field, periodic and open boundaries, etc. The software package can also calculate many key quantities in complex systems such as Poincar\\'e sections, survival probabilities, and diffusion coefficients. While aiming at a large class of applicable systems, the code also strives for ease-of-use, efficiency, and modularity for the implementation of additional features. The package comes along with a user guide, a developer's manual, and a documentation of the application program interface (API).

  16. BILL2D - A software package for classical two-dimensional Hamiltonian systems

    Science.gov (United States)

    Solanpää, J.; Luukko, P. J. J.; Räsänen, E.

    2016-02-01

    We present BILL2D, a modern and efficient C++ package for classical simulations of two-dimensional Hamiltonian systems. BILL2D can be used for various billiard and diffusion problems with one or more charged particles with interactions, different external potentials, an external magnetic field, periodic and open boundaries, etc. The software package can also calculate many key quantities in complex systems such as Poincaré sections, survival probabilities, and diffusion coefficients. While aiming at a large class of applicable systems, the code also strives for ease-of-use, efficiency, and modularity for the implementation of additional features. The package comes along with a user guide, a developer's manual, and a documentation of the application program interface (API).

  17. Hysteretic Spin Crossover in Two-Dimensional (2D) Hofmann-Type Coordination Polymers.

    Science.gov (United States)

    Liu, Wei; Wang, Lu; Su, Yu-Jun; Chen, Yan-Cong; Tucek, Jiri; Zboril, Radek; Ni, Zhao-Ping; Tong, Ming-Liang

    2015-09-08

    Three new two-dimensional (2D) Hofmann-type coordination polymers with general formula [Fe(3-NH2py)2M(CN)4] (3-NH2py = 3-aminopyridine, M = Ni (1), Pd (2), Pt (3)) have been synthesized. Magnetic susceptibility measurements show that they exhibited cooperative spin crossover (SCO) with remarkable hysteretic behaviors. Their hysteresis widths are 25, 37, and 30 K for 1-3, respectively. The single-crystal structure of 1 suggest that the pseudo-octahedral Fe sites are equatorially bridged by [M(CN)4](2-) to form 2D grids and axially coordinated by 3-NH2py ligands. The intermolecular interactions between layers (the offset face-to-face π···π interactions, hydrogen bonds, and weak N(amino)···Ni(II) contacts) together with the covalent bonds bridged by [M(CN)4](2-) units are responsible to the significant cooperativity.

  18. Removal of interfering substances in samples prepared for two-dimensional (2-D) electrophoresis.

    Science.gov (United States)

    Berkelman, Tom

    2008-01-01

    Biological samples may contain contaminants that interfere with analysis by two-dimensional (2-D) electrophoresis. Lysates or biological fluids are complex mixtures that contain a wide variety of nonprotein substances in addition to the proteins to be analyzed. These substances often interfere with the resolution of the electrophoretic separation or the visualization of the result. Macromolecules (e.g., polysaccharides and DNA) can interfere with electrophoretic separation by clogging gel pores. Small ionic molecules can impair isoelectric focusing (IEF) separation by rendering the sample too conductive. Other substances (e.g., phenolics and lipids) can bind to proteins, influencing their electrophoretic properties or solubility. In many cases, measures to remove interfering substances can result in significantly clearer 2-D patterns with more visible spots and better resolution. It should be borne in mind, however, that analysis of samples by 2-D electrophoresis is usually most successful and informative when performed with minimally processed samples, so it is important that any steps taken to remove interfering substance be appropriate to the sample and only performed when necessary. Procedures for the removal of interfering substances therefore represent a compromise between removing nonprotein contaminants, and minimizing interference with the integrity and relative abundances of the sample proteins. This chapter presents a number of illustrative examples of optimized sample preparation methods in which specific interfering substances are removed by a variety of different strategies.

  19. PRONTO 2D: A two-dimensional transient solid dynamics program

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, L.M.; Flanagan, D.P.

    1987-03-01

    PRONTO 2D is a two-dimensional transient solid dynamics code for analyzing large deformations of highly nonlinear materials subjected to extremely high strain rates. This Lagrangian finite element program uses an explicit time integration operator to integrate the equations of motion. Four node uniform strain quadrilateral elements are used in the finite element formulation. A number of new numerical algorithms which have been developed for the code are described in this report. An adaptive time step control algorithm is described which greatly improves stability as well as performance in plasticity problems. A robust hourglass control scheme which eliminates hourglass distortions without disturbing the finite element solution is included. All constitutive models in PRONTO are cast in an unrotated configuration defined using the rotation determined from the polar decomposition of the deformation gradient. An accurate incremental algorithm was developed to determine this rotation and is described in detail. A robust contact algorithm was developed which allows for the impact and interaction of deforming contact surfaces of quite general geometry. A number of numerical examples are presented to demonstrate the utility of these algorithms. 41 refs., 51 figs., 5 tabs.

  20. Two-dimensional Fourier transform ESR in the slow-motional and rigid limits: 2D-ELDOR

    Science.gov (United States)

    Patyal, Baldev R.; Crepeau, Richard H.; Gamliel, Dan; Freed, Jack H.

    1990-12-01

    The two-dimensional Fourier transform ESP techniques of stimulated SECSY and 2D-ELDOR are shown to be powerful methods for the study of slow motions for nitroxides. Stimulated SECSY provides magnetization transfer rates, whereas 2D-ELDOR displays how the rotational motions spread the spins out from their initial spectral positions to new spectral positions, as a function of mixing time. The role of nuclear modulation in studies of structure and dynamics is also considered.

  1. Waiting time dynamics in two-dimensional infrared spectroscopy.

    Science.gov (United States)

    Jansen, Thomas L C; Knoester, Jasper

    2009-09-15

    We review recent work on the waiting time dynamics of coherent two-dimensional infrared (2DIR) spectroscopy. This dynamics can reveal chemical and physical processes that take place on the femto- and picosecond time scale, which is faster than the time scale that may be probed by, for example, nuclear magnetic resonance spectroscopy. A large number of chemically relevant processes take place on this time scale. Such processes range from forming and breaking hydrogen bonds and proton transfer to solvent exchange and vibrational population transfer. In typical 2DIR spectra, multiple processes contribute to the waiting time dynamics and the spectra are often congested. This makes the spectra challenging to interpret, and the aid of theoretical models and simulations is often needed. To be useful, such models need to account for all dynamical processes in the sample simultaneously. The numerical integration of the Schrodinger equation (NISE) method has proven to allow for a very general treatment of the dynamical processes. It accounts for both the motional narrowing resulting from solvent-induced frequency fluctuations and population transfer between coupled vibrations. At the same time, frequency shifts arising from chemical-exchange reactions and changes of the transition dipoles because of either non-Condon effects or molecular reorientation are included in the treatment. This method therefore allows for the disentanglement of all of these processes. The NISE method has thus far been successfully applied to study chemical-exchange processes. It was demonstrated that 2DIR is not only sensitive to reaction kinetics but also to the more detailed reaction dynamics. NISE has also been applied to the study of population transfer within the amide I band (CO stretch) and between the amide I and amide II bands (CN stretch and NH bend) in polypeptides. From the amide I studies, it was found that the population transfer can be used to enhance cross-peaks that act as

  2. Two-dimensional hetero-spectral mid-infrared and near-infrared correlation spectroscopy for discrimination adulterated milk.

    Science.gov (United States)

    Yang, Renjie; Liu, Rong; Dong, Guimei; Xu, Kexin; Yang, Yanrong; Zhang, Weiyu

    2016-03-15

    A new approach for discriminant analysis of adulterated milk is proposed based on two-dimensional (2D) hetero-spectral near-infrared (NIR) and mid-infrared (IR) correlation spectroscopy along with multi-way partial least squares discriminant analysis (NPLS-DA). NIR transmittance spectra and IR attenuated total reflection spectra of pure milk and adulterated milk with level of melamine varying from 0.03 to 3 g·L(-1) were collected at room temperature. The synchronous 2D hetero-spectral IR/NIR correlation spectra of all samples were calculated to build a discriminant model to classify adulterated milk and pure milk. Also, the NPLS-DA models were built based on synchronous 2D homo-spectral NIR/NIR and IR/IR correlation spectra, respectively. Comparison results showed that the NPLS-DA model could provide better results using 2D hetero-spectral IR/NIR correlation spectra than using 2D homo-spectral NIR/NIR and 2D IR/IR correlation spectra.

  3. Two-dimensional hetero-spectral mid-infrared and near-infrared correlation spectroscopy for discrimination adulterated milk

    Science.gov (United States)

    Yang, Renjie; Liu, Rong; Dong, Guimei; Xu, Kexin; Yang, Yanrong; Zhang, Weiyu

    2016-03-01

    A new approach for discriminant analysis of adulterated milk is proposed based on two-dimensional (2D) hetero-spectral near-infrared (NIR) and mid-infrared (IR) correlation spectroscopy along with multi-way partial least squares discriminant analysis (NPLS-DA). NIR transmittance spectra and IR attenuated total reflection spectra of pure milk and adulterated milk with level of melamine varying from 0.03 to 3 g·L- 1 were collected at room temperature. The synchronous 2D hetero-spectral IR/NIR correlation spectra of all samples were calculated to build a discriminant model to classify adulterated milk and pure milk. Also, the NPLS-DA models were built based on synchronous 2D homo-spectral NIR/NIR and IR/IR correlation spectra, respectively. Comparison results showed that the NPLS-DA model could provide better results using 2D hetero-spectral IR/NIR correlation spectra than using 2D homo-spectral NIR/NIR and 2D IR/IR correlation spectra.

  4. MULTI2D - a computer code for two-dimensional radiation hydrodynamics

    Science.gov (United States)

    Ramis, R.; Meyer-ter-Vehn, J.; Ramírez, J.

    2009-06-01

    Simulation of radiation hydrodynamics in two spatial dimensions is developed, having in mind, in particular, target design for indirectly driven inertial confinement energy (IFE) and the interpretation of related experiments. Intense radiation pulses by laser or particle beams heat high-Z target configurations of different geometries and lead to a regime which is optically thick in some regions and optically thin in others. A diffusion description is inadequate in this situation. A new numerical code has been developed which describes hydrodynamics in two spatial dimensions (cylindrical R-Z geometry) and radiation transport along rays in three dimensions with the 4 π solid angle discretized in direction. Matter moves on a non-structured mesh composed of trilateral and quadrilateral elements. Radiation flux of a given direction enters on two (one) sides of a triangle and leaves on the opposite side(s) in proportion to the viewing angles depending on the geometry. This scheme allows to propagate sharply edged beams without ray tracing, though at the price of some lateral diffusion. The algorithm treats correctly both the optically thin and optically thick regimes. A symmetric semi-implicit (SSI) method is used to guarantee numerical stability. Program summaryProgram title: MULTI2D Catalogue identifier: AECV_v1_0 Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AECV_v1_0.html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.html No. of lines in distributed program, including test data, etc.: 151 098 No. of bytes in distributed program, including test data, etc.: 889 622 Distribution format: tar.gz Programming language: C Computer: PC (32 bits architecture) Operating system: Linux/Unix RAM: 2 Mbytes Word size: 32 bits Classification: 19.7 External routines: X-window standard library (libX11.so) and corresponding heading files (X11/*.h) are

  5. A new model for two-dimensional numerical simulation of pseudo-2D gas-solids fluidized beds

    Energy Technology Data Exchange (ETDEWEB)

    Li, Tingwen; Zhang, Yongmin

    2013-10-11

    Pseudo-two dimensional (pseudo-2D) fluidized beds, for which the thickness of the system is much smaller than the other two dimensions, is widely used to perform fundamental studies on bubble behavior, solids mixing, or clustering phenomenon in different gas-solids fluidization systems. The abundant data from such experimental systems are very useful for numerical model development and validation. However, it has been reported that two-dimensional (2D) computational fluid dynamic (CFD) simulations of pseudo-2D gas-solids fluidized beds usually predict poor quantitative agreement with the experimental data, especially for the solids velocity field. In this paper, a new model is proposed to improve the 2D numerical simulations of pseudo-2D gas-solids fluidized beds by properly accounting for the frictional effect of the front and back walls. Two previously reported pseudo-2D experimental systems were simulated with this model. Compared to the traditional 2D simulations, significant improvements in the numerical predictions have been observed and the predicted results are in better agreement with the available experimental data.

  6. [Two-Dimensional Hetero-Spectral Near-Infrared and Mid-Infrared Correlation Spectroscopy for Discrimination Adulterated Milk].

    Science.gov (United States)

    Yu, Ge; Yang, Ren-jie; Lü, Ai-jun; Tan, En-zhong

    2015-08-01

    New approach for discriminant analysis of adulterated milk is proposed based on combining hetero-spectral two-dimensional (2D) near-infrared (NIR) and mid-infrared (IR) correlation spectroscopy along with multi-way partial least squares discriminant analysis (NPLS-DA). Firstly, 36 pure milk samples were collected and 36 adulterated milk with starch samples (0.01 to 1 g · L(-1)) were prepared by adding appropriate mass of starch into pure milk. Then, one-dimensional NIR transmittance spectra and IR attenuated total reflection spectra of pure milk and adulterated milk with starch were measured at room temperature. And the synchronous 2D NIR-IR (4200~4800 vs. 900~1700 cm(-1)) correlation spectra of all samples were calculated. Due to the trace of adulterants, the synchronous 2D IR-NIR correlation spectral differences between adulterated milk with starch and pure milk are very subtle. Consequently, it was impossible to directly distinguish whether the sample was pure milk or adulterated milk. Finally, 2D IR-NIR correlation spectra were to build a discriminant model to classify adulterated milk and pure milk. The classification accuracy rates of samples in calibration set and in prediction set were 95.8% and 100% respectively. Also, the NPLS-DA models were built based on 2D NIR and 2D IR correlation spectra, respectively. The classification accuracy rates of samples in prediction set were 95.8%. Comparison results showed that the NPLS-DA model could provide better results using 2D NIR-IR correlation spectra than using 2D NIR, and 2D IR correlation spectra. The proposed method can not only effectively extract the feature information of adulterants in milk, but also explores a new perspective method for detection of adulterated food.

  7. Structure analysis of aromatic medicines containing nitrogen using near-infrared spectroscopy and generalized two-dimensional correlation spectroscopy

    Science.gov (United States)

    Liu, Hao; Gao, Hongbin; Qu, Lingbo; Huang, Yanping; Xiang, Bingren

    2008-12-01

    Four aromatic medicines (acetaminophen; niacinamide; p-aminophenol; nicotinic acid) containing nitrogen were investigated by FT-NIR (Fourier transform near-infrared) spectroscopy and generalized two-dimensional (2D) correlation spectroscopy. The FT-NIR spectra were measured over a temperature range of 30-130 °C. By combining near-infrared spectroscopy, generalized 2D correlation spectroscopy and references, the molecular structures (especially the hydrogen bond related with nitrogen) were analyzed and the NIR band assignments were performed. The results will be helpful to the understanding of aromatic medicines containing nitrogen and the utility of these substances.

  8. Optical properties of two-dimensional (2D) CdSe nanostructures

    Science.gov (United States)

    Cherevkov, S. A.; Baranov, A. V.; Fedorov, A. V.; Litvin, A. P.; Artemyev, M. V.; Prudnikau, A. V.

    2013-09-01

    The resonant and off-resonant Raman spectra of optical phonons in two-dimensional CdSe nanocrystals of 5, 6, and 7 monolayers are analysed. The spectra are dominated by SO and LO phonon bands of CdSe, whose frequencies are thickness-independent in the off-resonant Raman scattering but demonstrate an evident thickness dependence in the case of the resonant Raman scattering.

  9. Infrared absorber based on sandwiched two-dimensional black phosphorus metamaterials.

    Science.gov (United States)

    Wang, Jiao; Jiang, Yannan

    2017-03-06

    As a direct band gap two-dimensional (2D) semiconductor material, black phosphorus (BP) bridges the characteristics of graphene, with a zero or near-zero band gap, and transition metal dichalcogenides, with a wide band gap. In the infrared (IR) regime, 2D BP materials can harvest electromagnetic energy due to losses derived from its surface conductivity. In this paper, we propose an IR absorber design comprising 2D BP metamaterials sandwiched between dielectric layers. The multilayered sandwich-like absorber structure is mounted on a full reflective gold mirror, which forms a Fabry-Perot resonator to strengthen light-matter interactions. Harvested surface plasmons are excited around the 2D BP metamaterial edges, and the incident IR light can be efficiently dissipated by increasing the number of layers of the sandwich-like structure (NLSS). The physical absorption mechanism can be attributed to the destructive interference from the metamaterials, which can be enhanced with increasing NLSS. Here, a phase difference of about 180° is obtained between the directly reflected wave from the first interface and the emergent wave derived from the superposition of the multiple reflections among the resonator, and the amplitude of the emergent wave is steadily reduced to a value close to that of the directly reflected wave with increasing NLSS for incident transverse-magnetic polarized IR illumination.

  10. MARG2D code. 1. Eigenvalue problem for two dimensional Newcomb equation

    Energy Technology Data Exchange (ETDEWEB)

    Tokuda, Shinji [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan). Naka Fusion Research Establishment; Watanabe, Tomoko

    1997-10-01

    A new method and a code MARG2D have been developed to solve the 2-dimensional Newcomb equation which plays an important role in the magnetohydrodynamic (MHD) stability analysis in an axisymmetric toroidal plasma such as a tokamak. In the present formulation, an eigenvalue problem is posed for the 2-D Newcomb equation, where the weight function (the kinetic energy integral) and the boundary conditions at rational surfaces are chosen so that an eigenfunction correctly behaves as the linear combination of the small solution and the analytical solutions around each of the rational surfaces. Thus, the difficulty on solving the 2-D Newcomb equation has been resolved. By using the MARG2D code, the ideal MHD marginally stable state can be identified for a 2-D toroidal plasma. The code is indispensable on computing the outer-region matching data necessary for the resistive MHD stability analysis. Benchmark with ERATOJ, an ideal MHD stability code, has been carried out and the MARG2D code demonstrates that it indeed identifies both stable and marginally stable states against ideal MHD motion. (author)

  11. Stochastic Simulation of Chemical Exchange in Two Dimensional Infrared Spectroscopy

    CERN Document Server

    Sanda, F; Sanda, Frantisek; Mukamel, Shaul

    2006-01-01

    The stochastic Liouville equations are employed to investigate the combined signatures of chemical exchange (two-state-jump) and spectral diffusion (coupling to an overdamped Brownian oscillator) in the coherent response of an anharmonic vibration to three femtosecond infrared pulses. Simulations reproduce the main features recently observed in the OD stretch of phenol in benzene.

  12. Optical theorem for two-dimensional (2D) scalar monochromatic acoustical beams in cylindrical coordinates.

    Science.gov (United States)

    Mitri, F G

    2015-09-01

    The optical theorem for plane waves is recognized as one of the fundamental theorems in optical, acoustical and quantum wave scattering theory as it relates the extinction cross-section to the forward scattering complex amplitude function. Here, the optical theorem is extended and generalized in a cylindrical coordinates system for the case of 2D beams of arbitrary character as opposed to plane waves of infinite extent. The case of scalar monochromatic acoustical wavefronts is considered, and generalized analytical expressions for the extinction, absorption and scattering cross-sections are derived and extended in the framework of the scalar resonance scattering theory. The analysis reveals the presence of an interference scattering cross-section term describing the interaction between the diffracted Franz waves with the resonance elastic waves. The extended optical theorem in cylindrical coordinates is applicable to any object of arbitrary geometry in 2D located arbitrarily in the beam's path. Related investigations in optics, acoustics and quantum mechanics will benefit from this analysis in the context of wave scattering theory and other phenomena closely connected to it, such as the multiple scattering by a cloud of particles, as well as the resulting radiation force and torque.

  13. Retrieval of spectral and dynamic properties from two-dimensional infrared pump-probe experiments.

    Science.gov (United States)

    Chelli, Riccardo; Volkov, Victor V; Righini, Roberto

    2008-07-15

    We have developed a fitting algorithm able to extract spectral and dynamic properties of a three level oscillator from a two-dimensional infrared spectrum (2D-IR) detected in time resolved nonlinear experiments. Such properties go from the frequencies of the ground-to-first and first-to-second vibrational transitions (and hence anharmonicity) to the frequency-fluctuation correlation function. This last is represented through a general expression that allows one to approach the various strategies of modeling proposed in the literature. The model is based on the Kubo picture of stochastic fluctuations of the transition frequency as a result of perturbations by a fluctuating surrounding. To account for the line-shape broadening due to pump pulse spectral width in double-resonance measurements, we supply the fitting algorithm with the option to perform the convolution of the spectral signal with a Lorentzian function in the pump-frequency dimension. The algorithm is tested here on 2D-IR pump-probe spectra of a Gly-Ala dipeptide recorded at various pump-probe delay times. Speedup benchmarks have been performed on a small Beowulf cluster. The program is written in FORTRAN language for both serial and parallel architectures and is available free of charge to the interested reader.

  14. Generalized two-dimensional correlation near-infrared spectroscopy and principal component analysis of the structures of methanol and ethanol

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Liquid state methanol and ethanol under different temperatures have been investigated by FT-NIR(Fourier transform nearinfrared) spectroscopy,generalized two-dimensional(2D) correlation spectroscopy,and PCA(principal component analysis) . First,the FT-NIR spectra were measured over a temperature range of 30-64(or 30-71) °C,and then the 2D correlation spectra were computed.Combining near-infrared spectroscopy,generalized 2D correlation spectroscopy,and references,we analyzed the molecular structures(especially the hydrogen bond) of methanol and ethanol,and performed the NIR band assignments. The PCA method was employed to verify the results of the 2D analysis.This study will be helpful to the understanding of these reagents.

  15. Adulteration detection in milk using infrared spectroscopy combined with two-dimensional correlation analysis

    Science.gov (United States)

    He, Bin; Liu, Rong; Yang, Renjie; Xu, Kexin

    2010-02-01

    Adulteration of milk and dairy products has brought serious threats to human health as well as enormous economic losses to the food industry. Considering the diversity of adulterants possibly mixed in milk, such as melamine, urea, tetracycline, sugar/salt and so forth, a rapid, widely available, high-throughput, cost-effective method is needed for detecting each of the components in milk at once. In this paper, a method using Fourier Transform Infrared spectroscopy (FTIR) combined with two-dimensional (2D) correlation spectroscopy is established for the discriminative analysis of adulteration in milk. Firstly, the characteristic peaks of the raw milk are found in the 4000-400 cm-1 region by its original spectra. Secondly, the adulterant samples are respectively detected with the same method to establish a spectral database for subsequent comparison. Then, 2D correlation spectra of the samples are obtained which have high time resolution and can provide information about concentration-dependent intensity changes not readily accessible from one-dimensional spectra. And the characteristic peaks in the synchronous 2D correlation spectra of the suspected samples are compared with those of raw milk. The differences among their synchronous spectra imply that the suspected milk sample must contain some kinds of adulterants. Melamine, urea, tetracycline and glucose adulterants in milk are identified respectively. This nondestructive method can be used for a correct discrimination on whether the milk and dairy products are adulterated with deleterious substances and it provides a new simple and cost-effective alternative to test the components of milk.

  16. Two-dimensional crystal melting and D4-D2-D0 on toric Calabi-Yau singularities

    CERN Document Server

    Nishinaka, Takahiro; Yoshida, Yutaka

    2013-01-01

    We construct a two-dimensional crystal melting model which reproduces the BPS index of D2-D0 states bound to a non-compact D4-brane on an arbitrary toric Calabi-Yau singularity. The crystalline structure depends on the toric divisor wrapped by the D4-brane. The molten crystals are in one-to-one correspondence with the torus fixed points of the moduli space of the quiver gauge theory on D-branes. The F- and D-term constraints of the gauge theory are regarded as a generalization of the ADHM constraints on instantons. We also show in several examples that our model is consistent with the wall-crossing formula for the BPS index.

  17. Two-dimensional near-infrared photonic crystal fabrication by generation of void channels in solid resin

    Institute of Scientific and Technical Information of China (English)

    Guangyong Zhou; Michael James Ventura; Min Gu

    2003-01-01

    Two-dimensional (2D) triangular void channel photonic crystals with different lattice constants stacked in two different directions were fabricated by using femtosecond laser micro-explosion in solid polymer material. Fundamental and higher-order stop gaps were observed both in the infrared transmission and reflection spectra. There is an approximately linear relationship between the gap position and the lattice constant. The suppression of the fundamental gap is as high as 70% for 24-layer structures stacked in the Г-M direction.

  18. Bandwidth control of wavelength-selective uncooled infrared sensors using two-dimensional plasmonic absorbers

    Science.gov (United States)

    Ogawa, Shinpei; Fujisawa, Daisuke; Kimata, Masafumi

    2016-05-01

    Although standard uncooled infrared (IR) sensors can be used to record information such as the shape, position, and average radiant intensity of objects, these devices cannot capture color (that is, wavelength) data. Achieving wavelength selectivity would pave the way for the development of advanced uncooled IR sensors capable of providing color information as well as multi-color image sensors that would have significant advantages in applications such as fire detection, gas analysis, hazardous material recognition, and biological analysis. We have previously demonstrated an uncooled IR sensor incorporating a two-dimensional plasmonic absorber (2D PLA) that exhibits wavelength selectivity over a wide range in the mid- and long-IR regions. This PLA has a 2D Au-based periodic array of dimples, in which surface plasmon modes are induced and wavelength-selective absorption occurs. However, the dependence of the absorption bandwidth on certain structural parameters has yet to be clarified. The bandwidth of such devices is a vital factor when considering the practical application of these sensors to tasks such as gas detection. In the present study, control of the bandwidth was theoretically investigated using a rigorous coupled wave analysis approach. It is demonstrated that the dimple sidewall structure has a significant impact on the bandwidth and can be used to control both narrow- and broadband absorption. Increasing the sidewall slope was found to decrease the bandwidth due to suppression of cavity-mode resonance in the depth direction of the dimples. These results will contribute to the development of high-resolution, wavelength-selective uncooled IR sensors.

  19. Anharmonic exciton dynamics and energy dissipation in liquid water from two-dimensional infrared spectroscopy

    Science.gov (United States)

    De Marco, Luigi; Fournier, Joseph A.; Thämer, Martin; Carpenter, William; Tokmakoff, Andrei

    2016-09-01

    Water's extended hydrogen-bond network results in rich and complex dynamics on the sub-picosecond time scale. In this paper, we present a comprehensive analysis of the two-dimensional infrared (2D IR) spectrum of O-H stretching vibrations in liquid H2O and their interactions with bending and intermolecular vibrations. By exploring the dependence of the spectrum on waiting time, temperature, and laser polarization, we refine our molecular picture of water's complex ultrafast dynamics. The spectral evolution following excitation of the O-H stretching resonance reveals vibrational dynamics on the 50-300 fs time scale that are dominated by intermolecular delocalization. These O-H stretch excitons are a result of the anharmonicity of the nuclear potential energy surface that arises from the hydrogen-bonding interaction. The extent of O-H stretching excitons is characterized through 2D depolarization measurements that show spectrally dependent delocalization in agreement with theoretical predictions. Furthermore, we show that these dynamics are insensitive to temperature, indicating that the exciton dynamics alone set the important time scales in the system. Finally, we study the evolution of the O-H stretching mode, which shows highly non-adiabatic dynamics suggestive of vibrational conical intersections. We argue that the so-called heating, commonly observed within ˜1 ps in nonlinear IR spectroscopy of water, is a nonequilibrium state better described by a kinetic temperature rather than a Boltzmann distribution. Our conclusions imply that the collective nature of water vibrations should be considered in describing aqueous solvation.

  20. FireStem2D--a two-dimensional heat transfer model for simulating tree stem injury in fires.

    Directory of Open Access Journals (Sweden)

    Efthalia K Chatziefstratiou

    Full Text Available FireStem2D, a software tool for predicting tree stem heating and injury in forest fires, is a physically-based, two-dimensional model of stem thermodynamics that results from heating at the bark surface. It builds on an earlier one-dimensional model (FireStem and provides improved capabilities for predicting fire-induced mortality and injury before a fire occurs by resolving stem moisture loss, temperatures through the stem, degree of bark charring, and necrotic depth around the stem. We present the results of numerical parameterization and model evaluation experiments for FireStem2D that simulate laboratory stem-heating experiments of 52 tree sections from 25 trees. We also conducted a set of virtual sensitivity analysis experiments to test the effects of unevenness of heating around the stem and with aboveground height using data from two studies: a low-intensity surface fire and a more intense crown fire. The model allows for improved understanding and prediction of the effects of wildland fire on injury and mortality of trees of different species and sizes.

  1. Proton transport in a membrane protein channel: two-dimensional infrared spectrum modeling.

    NARCIS (Netherlands)

    Liang, C.; Knoester, J.; Jansen, T.L.Th.A.

    2012-01-01

    We model the two-dimensional infrared (2DIR) spectrum of a proton channel to investigate its applicability as a spectroscopy tool to study the proton transport process in biological systems. Proton transport processes in proton channels are involved in numerous fundamental biochemical reactions. How

  2. Two-dimensional infrared spectroscopy of neat ice I-h

    NARCIS (Netherlands)

    Shi, Liang; Skinner, J. L.; Jansen, Thomas L. C.

    2016-01-01

    The assignment of the distinct peaks observed in the OH stretch lineshape of ice I-h is controversial. Recent two-dimensional infrared spectroscopic measurements provided new data. The spectra are, however, challenging to interpret and here we provide simulations that help overcome experimental issu

  3. Calculation of two-dimensional infrared spectra of ultrafast chemical exchange with numerical Langevin simulations

    NARCIS (Netherlands)

    Jansen, Thomas la Cour; Knoester, Jasper

    2007-01-01

    We combine numerical Langevin simulations with numerical integration of the Schrodinger equation to calculate two-dimensional infrared spectra of ultrafast chemical exchange. This provides a tool to model and interpret such spectra of molecules undergoing chemical processes, such as isomerization an

  4. An Efficient N-3-Scaling Propagation Scheme for Simulating Two-Dimensional Infrared and Visible Spectra

    NARCIS (Netherlands)

    Liang, Chungwen; Jansen, Thomas L. C.

    2012-01-01

    In this paper, we develop and test a new approximate propagation scheme for calculating two-dimensional infrared and visible spectra. The new scheme scales one order more efficiently with the system size than the existing schemes. A Trotter type of approximation is used for the matrix exponent that

  5. Signatures of beta-sheet secondary structures in linear and two-dimensional infrared spectroscopy

    NARCIS (Netherlands)

    Cheatum, CM; Tokmakoff, A; Knoester, J

    2004-01-01

    Using idealized models for parallel and antiparallel beta sheets, we calculate the linear and two-dimensional infrared spectra of the amide I vibration as a function of size and secondary structure. The model assumes transition-dipole coupling between the amide I oscillators in the sheet and account

  6. [Discrimination of adulterated milk based on Euclidian distances between two-dimensional infrared correlation spectra].

    Science.gov (United States)

    Yang, Ren-jie; Yang, Yan-rong; Dong, Gui-mei; Du, Yan-hong; Shan, Hui-yong; Zhang, Wei-yu

    2014-08-01

    Based on Euclidian distances between synchronous two-dimensional infrared correlation spectra, in terms of the average Euclidian distances between unknown samples and "extreme samples", and average intra- and inter-Euclidian distances of samples in the calibration set, a new method for the discrimination of adulterated milk was proposed. Sixteen pure milk samples were collected and 16 adulterated milk samples with urea (0.01-0.3 g x L(-1)), and 16 adulterated milk samples with melamine (0.01-0.3 g x L(-1)) samples were prepared, respectively. The IR absorption spectra of all samples were measured at room temperature. The synchronous two-dimensional correlation spectra were generated from concentration-dependent spectral variation of adulterant in milk. The Euclidian distances were calculated between synchronous two-dimensional infrared correlation spectra of all samples. Then, the classification models were built respectively for adulterated milk with urea, and adiulterated milk with melamine. The "extreme samples", average intra- and inter-Euclidian distances were determined. Finally, the unknown samples in prediction set were predicted using constructed models in terms of classification rules of adulterated milk. The classification accuracy rates for pure milk and adulterated milk were 100%. The effectiveness of the proposed method was verified. The results obtained in this study revealed that synchronous two-dimensional infrared correlation spectra in combination with Euclidian distance has a feasible potential to discriminate adulterated milk and pure milk.

  7. Study on the crystalline structure transition of syndiotactic polystyrene film during heat treatment by two-dimensional infrared correlation spectroscopy.

    Science.gov (United States)

    Li, Weizhen; Wu, Peiyi

    2009-08-01

    The crystal structure transition of syndiotactic polystyrene film from the helical conformation to the more stable planar zigzag conformation during a heating process was studied using Fourier transform infrared (FT-IR) spectroscopy in combination with two-dimensional (2D) correlation analysis and perturbation-correlation moving-window 2D analysis. The sequence of different conformations during the transition was investigated by analyzing two-dimensional FT-IR correlation spectra in the spectral ranges of 800-700 cm(-1) and 600-500 cm(-1). It was observed that the conformation of delta helical changes prior to gamma helical, and the gamma helical phase is faster than the alpha' planar zigzag phase. By utilizing the 2D asynchronous correlation spectra, the 744 cm(-1) band, which is usually incorporated in the broad 750 cm(-1) band, can now be uniquely attributed as the alpha' zigzag configuration for the first time. Furthermore, by employing thermal perturbation, the shorter helical segments consisting of m = 7-12 and m = 12-20 monomeric units were disturbed in a shorter time than the longer helical segments m = 20-30 during the heating process.

  8. WSJointInv2D-MT-DCR: An efficient joint two-dimensional magnetotelluric and direct current resistivity inversion

    Science.gov (United States)

    Amatyakul, Puwis; Vachiratienchai, Chatchai; Siripunvaraporn, Weerachai

    2017-05-01

    An efficient joint two-dimensional direct current resistivity (DCR) and magnetotelluric (MT) inversion, referred to as WSJointInv2D-MT-DCR, was developed with FORTRAN 95 based on the data space Occam's inversion algorithm. Our joint inversion software can be used to invert just the MT data or the DCR data, or invert both data sets simultaneously to get the electrical resistivity structures. Since both MT and DCR surveys yield the same resistivity structures, the two data types enhance each other leading to a better interpretation. Two synthetic and a real field survey are used here to demonstrate that the joint DCR and MT surveys can help constrain each other to reduce the ambiguities occurring when inverting the DCR or MT alone. The DCR data increases the lateral resolution of the near surface structures while the MT data reveals the deeper structures. When the MT apparent resistivity suffers from the static shift, the DCR apparent resistivity can serve as a replacement for the estimation of the static shift factor using the joint inversion. In addition, we also used these examples to show the efficiency of our joint inversion code. With the availability of our new joint inversion software, we expect the number of joint DCR and MT surveys to increase in the future.

  9. Effects on the Thermo-Mechanical and Crystallinity Properties of Nylon 6,6 Electrospun Fibres Reinforced with One Dimensional (1D and Two Dimensional (2D Carbon

    Directory of Open Access Journals (Sweden)

    Francisco Medellín-Rodríguez

    2013-08-01

    Full Text Available Electrospun one dimensional (1D and two dimensional (2D carbon based polymer nanocomposites are studied in order to determine the effect provided by the two differently structured nanofillers on crystallinity and thermo-mechanical properties of the nanofibres. The nanomaterials studied are pristine carbon nanotubes, oxidised carbon nanotubes, reduced graphene oxide and graphene oxide. Functional groups associated with the order structure of the polymers are analysed by infrared and Raman spectroscopies; the morphology is studied by scanning electron microscopy and the crystallinity properties are investigated by differential scanning calorimetry and X-ray diffraction. Differences in crystallisation behaviour between 1D and 2D carbon based nanofibres are shown by their crystallinity degree and their crystal sizes. The nanocomposite crystal sizes perpendicular to the plane (100 decrease with nanofiller content in all cases. The crystallinity trend and crystal sizes are in accordance with storage modulus response. The results also suggest that functionalisation favours interfacial bonding and dispersion of the nanomaterials within the polymer matrix. As a consequence the number of nucleating sites increases which in turn decreases the crystal size in the nanocomposites. These features explain the improved thermo-mechanical properties in the nanocomposites.

  10. Coherent two-dimensional infrared spectroscopy: quantitative analysis of protein secondary structure in solution.

    Science.gov (United States)

    Baiz, Carlos R; Peng, Chunte Sam; Reppert, Mike E; Jones, Kevin C; Tokmakoff, Andrei

    2012-04-21

    We present a method to quantitatively determine the secondary structure composition of globular proteins using coherent two-dimensional infrared (2DIR) spectroscopy of backbone amide I vibrations (1550-1720 cm(-1)). Sixteen proteins with known crystal structures were used to construct a library of 2DIR spectra, and the fraction of residues in α-helix, β-sheet, and unassigned conformations was determined by singular value decomposition (SVD) of the measured two-dimensional spectra. The method was benchmarked by removing each individual protein from the set and comparing the composition extracted from 2DIR against the composition determined from the crystal structures. To highlight the increased structural content extracted from 2DIR spectra a similar analysis was also carried out using conventional infrared absorption of the proteins in the library.

  11. Description of cross peaks induced by intermolecular vibrational energy transfer in two-dimensional infrared spectroscopy

    CERN Document Server

    Villaeys, Albert A

    2013-01-01

    In the present work, the analytical description of an intermolecular vibrational energy transfer, analyzed by two dimensional infrared spectroscopy, is established. The energy transfer process takes place between the dark combination states of low frequency modes pertaining to different molecules. The appearance of the cross peaks results from coherent transfer between these combination states and an optically active state of the acceptor molecule. Such a process has recently been observed experimentally between the nitrile groups of acetonitrile-d3 and benzonitrile molecules. This molecular system will be used as a model for the simulations of their two-dimensional infrared spectra. The dependence of the cross-peak growth, which is a signature of the intermolecular energy transfer, will be discussed in detail as a function of the molecular dynamical constants.

  12. User's Guide for ECAP2D: an Euler Unsteady Aerodynamic and Aeroelastic Analysis Program for Two Dimensional Oscillating Cascades, Version 1.0

    Science.gov (United States)

    Reddy, T. S. R.

    1995-01-01

    This guide describes the input data required for using ECAP2D (Euler Cascade Aeroelastic Program-Two Dimensional). ECAP2D can be used for steady or unsteady aerodynamic and aeroelastic analysis of two dimensional cascades. Euler equations are used to obtain aerodynamic forces. The structural dynamic equations are written for a rigid typical section undergoing pitching (torsion) and plunging (bending) motion. The solution methods include harmonic oscillation method, influence coefficient method, pulse response method, and time integration method. For harmonic oscillation method, example inputs and outputs are provided for pitching motion and plunging motion. For the rest of the methods, input and output for pitching motion only are given.

  13. Photon-Phonon-Enhanced Infrared Rectification in a Two-Dimensional Nanoantenna-Coupled Tunnel Diode

    Science.gov (United States)

    Kadlec, Emil A.; Jarecki, Robert L.; Starbuck, Andrew; Peters, David W.; Davids, Paul S.

    2016-12-01

    The interplay of strong infrared photon-phonon coupling with electromagnetic confinement in nanoscale devices is demonstrated to have a large impact on ultrafast photon-assisted tunneling in metal-oxide-semiconductor (MOS) structures. Infrared active optical phonon modes in polar oxides lead to strong dispersion and enhanced electric fields at material interfaces. We find that the infrared dispersion of SiO2 near a longitudinal optical phonon mode can effectively impedance match a photonic surface mode into a nanoscale tunnel gap that results in large transverse-field confinement. An integrated 2D nanoantenna structure on a distributed large-area MOS tunnel-diode rectifier is designed and built to resonantly excite infrared surface modes and is shown to efficiently channel infrared radiation into nanometer-scale gaps in these MOS devices. This enhanced-gap transverse-electric field is converted to a rectified tunneling displacement current resulting in a dc photocurrent. We examine the angular and polarization-dependent spectral photocurrent response of these 2D nanoantenna-coupled tunnel diodes in the photon-enhanced tunneling spectral region. Our 2D nanoantenna-coupled infrared tunnel-diode rectifier promises to impact large-area thermal energy harvesting and infrared direct detectors.

  14. Noise reduction methods applied to two-dimensional correlation spectroscopy (2D-COS) reveal complementary benefits of pre- and post-treatment.

    Science.gov (United States)

    Foist, Rod B; Schulze, H Georg; Ivanov, Andre; Turner, Robin F B

    2011-05-01

    Two-dimensional correlation spectroscopy (2D-COS) is a powerful spectral analysis technique widely used in many fields of spectroscopy because it can reveal spectral information in complex systems that is not readily evident in the original spectral data alone. However, noise may severely distort the information and thus limit the technique's usefulness. Consequently, noise reduction is often performed before implementing 2D-COS. In general, this is implemented using one-dimensional (1D) methods applied to the individual input spectra, but, because 2D-COS is based on sets of successive spectra and produces 2D outputs, there is also scope for the utilization of 2D noise-reduction methods. Furthermore, 2D noise reduction can be applied either to the original set of spectra before performing 2D-COS ("pretreatment") or on the 2D-COS output ("post-treatment"). Very little work has been done on post-treatment; hence, the relative advantages of these two approaches are unclear. In this work we compare the noise-reduction performance on 2D-COS of pretreatment and post-treatment using 1D (wavelets) and 2D algorithms (wavelets, matrix maximum entropy). The 2D methods generally outperformed the 1D method in pretreatment noise reduction. 2D post-treatment in some cases was superior to pretreatment and, unexpectedly, also provided correlation coefficient maps that were similar to 2D correlation spectroscopy maps but with apparent better contrast.

  15. Further investigation on potassium-induced conformation transition of Nephila spidroin film with two-dimensional infrared correlation spectroscopy.

    Science.gov (United States)

    Peng, Xianneng; Shao, Zhengzhong; Chen, Xin; Knight, David P; Wu, Peiyi; Vollrath, Fritz

    2005-01-01

    We used two-dimensional (2D) correlation infrared spectroscopy to study further the potassium-induced conformation transition in Nephila spidroin films. It provided increased resolution and important new information on the sequence of events in the conformation transition process, showing that beta-sheet formed from the helical component before they formed from random coil. It also showed more evidence that formation of the 1691 cm(-1) (turn/bend) peak did not proceed with the same kinetics as the 1620 cm(-1) (antiparallel beta-sheet component) one, so we attribute the 1691 cm(-1) peak to turns which formed with different kinetics as the antiparallel beta-sheets. We present a single coherent and detailed hypothesis for the assembly and secondary structural transition of silk proteins in vivo and in vitro based on our findings and on evidence from other laboratories.

  16. Fano resonance in asymmetric-period two-dimensional plasmonic absorbers for dual-band uncooled infrared sensors

    Science.gov (United States)

    Ogawa, Shinpei; Takagawa, Yousuke; Kimata, Masafumi

    2016-11-01

    The spectral discrimination function of uncooled infrared (IR) sensors has significant advantages for applications such as fire detection, gas analysis, and biological analysis. We have previously demonstrated wavelength-selective uncooled IR sensors using two-dimensional plasmonic absorbers (2-D PLAs) over a wide range spanning the middle- and long-wavelength IR regions. 2-D PLAs are highly promising in terms of practical application due to the ease of fabrication and robustness for structural fluctuations. However, dual-band operation based on this concept has not yet been investigated, even though the ability to absorb in two different wavelength bands is extremely important for object recognition. Thus, a dual-band uncooled IR sensor was developed that employs Fano resonance in the plasmonic structures. To achieve dual-band detection, asymmetric periods in the orthogonal x- and y-directions were introduced into 2-D PLAs. Theoretical investigations predicted an asymmetric absorbance line shape dependent on the polarization attributed to Fano resonance. The spectral responsivity of the developed sensor demonstrated that selective detection occurred in two different wavelength bands due to polarization-dependent Fano resonance. The results obtained in this study will be applicable to the development of advanced sensors capable of multiband detection in the IR region.

  17. Analysis of crystallized lactose in milk powder by Fourier-transform infrared spectroscopy combined with two-dimensional correlation infrared spectroscopy

    Science.gov (United States)

    Lei, Yu; Zhou, Qun; Zhang, Yan-ling; Chen, Jian-bo; Sun, Su-qin; Noda, Isao

    2010-06-01

    Infrared (IR) spectroscopy is used in combination with two-dimensional (2D) correlation IR spectroscopy to conduct rapid non-destructive quantitative research in milk powder without additional separation steps. The experiments conducted in both FT-IR and 2D FT-IR spectra suggest that characteristic spectroscopic features of milk powder containing different carbohydrate can be detected, and then determine the type of carbohydrate. To predict the approximate content of lactose while the carbohydrate is lactose, different amount of crystallized lactose has been added to the reference milk powder. The correlation coefficient could be used to determine the content of crystallized lactose in milk powder. The method provides a rapid and convenient means for assessing the quality of milk powder.

  18. Discrimination of different genuine Danshen and their extracts by Fourier transform infrared spectroscopy combined with two-dimensional correlation infrared spectroscopy

    Science.gov (United States)

    Liu, Xin-hu; Xu, Chang-hua; Sun, Su-qin; Huang, Jian; Zhang, Ke; Li, Guo-yu; Zhu, Yun; Zhou, Qun; Zhang, Zhi-cheng; Wang, Jin-hui

    2012-11-01

    In this study, six varieties of Danshen from different populations and genuine ("Daodi" in Chinese transliteration) regions were discriminated and identified by a three-step infrared spectroscopy method (Fourier transform-infrared spectroscopy (FT-IR) coupled with second derivative infrared spectroscopy (SD-IR) and two dimensional correlation infrared spectroscopy (2D-IR)). Though only small differences were found among the FT-IR spectra of the six Danshen samples, the positions and intensities of peaks at 3393, 3371, 1613, 1050, and 1036 cm-1 could be considered as the key factors to discriminate them. More significant differences were exhibited in their SD-IR, particularly for the peaks around 1080, 1144, 695, 665, 800, 1610, 1510, 1450, 1117 and 1077 cm-1. The visual 2D-IR spectra provided dynamic chemical structure information of the six Danshen samples with presenting different particular auto-peak clusters, respectively. Moreover, the contents of salvianolic acid B in all samples were measured quantitatively by a validated ultra performance liquid chromatography (UPLC), which was consistent with the FT-IR findings. This study provides a promising method for characteristics and quality control of the complicated and extremely similar herbal medicine like Danshen, which is more cost effective and time saving.

  19. Two-dimensional correlation infrared spectroscopy applied to analyzing and identifying the extracts of Baeckea frutescens medicinal materials.

    Science.gov (United States)

    Adib, Adiana Mohamed; Jamaludin, Fadzureena; Kiong, Ling Sui; Hashim, Nuziah; Abdullah, Zunoliza

    2014-08-05

    Baeckea frutescens or locally known as Cucur atap is used as antibacterial, antidysentery, antipyretic and diuretic agent. In Malaysia and Indonesia, they are used as an ingredient of the traditional medicine given to mothers during confinement. A three-steps infra-red (IR) macro-fingerprinting method combining conventional IR spectra, and the secondary derivative spectra with two dimensional infrared correlation spectroscopy (2D-IR) have been proved to be effective methods to examine a complicated mixture such as herbal medicines. This study investigated the feasibility of employing multi-steps IR spectroscopy in order to study the main constituents of B. frutescens and its different extracts (extracted by chloroform, ethyl acetate, methanol and aqueous in turn). The findings indicated that FT-IR and 2D-IR can provide many holistic variation rules of chemical constituents. The structural information of the samples indicated that B. frutescens and its extracts contain a large amount of flavonoids, since some characteristic absorption peaks of flavonoids, such as ∼1600cm(-1), ∼1500cm(-1), ∼1450cm(-1), and ∼1270cm(-1) can be observed. The macroscopical fingerprint characters of FT-IR and 2D-IR spectra can not only provide the information of main chemical constituents in medicinal materials and their different extracts, but also compare the components differences among the similar samples. In conclusion, the multi-steps IR macro-fingerprint method is rapid, effective, visual and accurate for pharmaceutical research. Copyright © 2014 Elsevier B.V. All rights reserved.

  20. Distinction of three wood species by Fourier transform infrared spectroscopy and two-dimensional correlation IR spectroscopy

    Science.gov (United States)

    Huang, Anmin; Zhou, Qun; Liu, Junliang; Fei, Benhua; Sun, Suqin

    2008-07-01

    Dalbergia odorifera T. Chen, Pterocarpus santalinus L.F. and Pterocarpus soyauxii are three kinds of the most valuable wood species, which are hard to distinguish. In this paper, differentiation of D. odorifera, P. santalinus and P. soyauxii was carried out by using Fourier transform infrared spectroscopy (FT-IR), second derivative IR spectra and two-dimensional correlation infrared (2D-IR) spectroscopy. The three woods have their characteristic peaks in conventional IR spectra. For example, D. odorifera has obvious absorption peaks at 1640 and 1612 cm -1; P. santalinus has only one peak at 1614 cm -1; and P. soyauxii has one peak at 1619 cm -1 and one shoulder peak at 1597 cm -1. To enhance spectrum resolution and amplify the differences between the IR spectra of different woods, the second derivative technology was adopted to examine the three wood samples. More differences could be observed in the region of 800-1700 cm -1. Then, the thermal perturbation is applied to distinguish different wood samples in an easier way, because of the spectral resolution being enhanced by the 2D correlation spectroscopy. In the region of 1300-1800 cm -1, D. odorifera has five auto-peaks at 1518, 1575, 1594, 1620 and 1667 cm -1; P. santalinus has four auto-peaks at 1469, 1518, 1627 and 1639 cm -1 and P. soyauxii has only two auto-peaks at 1627 and 1639 cm -1. It is proved that the 2D correlation IR spectroscopy can be a new method to distinguish D. odorifera, P. santalinus and P. soyauxii.

  1. Introducing 2D Materials—a new multidisciplinary journal devoted to all aspects of graphene and related two-dimensional materials

    Science.gov (United States)

    Fal'ko, Vladimir I.

    2014-06-01

    On behalf of the Editorial Board and IOP Publishing, I am pleased to announce the opening of 2D Materials. Research on two-dimensional materials, such as graphene, now involves thousands of researchers worldwide cutting across physics, chemistry, engineering and biology, and extending from fundamental science to novel applications. It is this situation which defines the scope and mission of 2D Materials, a new journal that will serve all sides of this multidisciplinary field by publishing urgent research of the highest quality and impact.

  2. Dynamics of a multimode system coupled to multiple heat baths probed by two-dimensional infrared spectroscopy.

    Science.gov (United States)

    Ishizaki, Akihito; Tanimura, Yoshitaka

    2007-09-27

    Reduced equation of motion for a multimode system coupled to multiple heat baths is constructed by extending the quantum Fokker-Planck equation with low-temperature correction terms (J. Phys. Soc. Jpn. 2005, 74, 3131). Unlike such common approaches used to describe intramolecular multimode vibration as a Bloch-Redfield theory and a stochastic theory, the present formalism is defined by the molecular coordinates. To explore the correlation among different modes through baths, we consider two cases of system-bath couplings. One is a correlated case in which two modes are coupled to a single bath, and the other is an uncorrelated case in which each mode is coupled to a different bath. We further classify the correlated case into two cases, the plus- and minus-correlated cases, according to distinct correlation manners. For these, one-dimensional and two-dimensional infrared (2D-IR) spectra are calculated numerically by solving the equation of motion. It is demonstrated that 2D-IR spectroscopy has the ability to analyze the correlation of fluctuation-dissipation processes among different modes.

  3. Dynamics and Structure of Disordered Peptides from Two-Dimensional Infrared Spectroscopy

    Science.gov (United States)

    Reppert, Mike; Lessing, Joshua; Peng, Chunte; Jones, Kevin; Baiz, Carlos; Tokmakoff, Andrei

    2012-02-01

    Two-dimensional infrared (IR) spectroscopy is a powerful tool for investigating the ultra-fast dynamics and association of complex biological macromolecules such as proteins and DNA. In addition to the improved spectral discrimination afforded by a two-dimensional spectrum, the ultra-fast time-resolution inherent to the technique provides unique insight (unobtainable by standard linear IR measurements) into the time-scales of macromolecular conformational fluctuations, particularly for intrinsically disordered systems. Here we discuss the use of accurate line shape modeling of peptide amide I vibrations as an advanced method for extracting structural and dynamic information from experimental spectra. The mixed quantum-classical model makes use of standard MD trajectories and a parametrized site energy and coupling map as inputs for excitonic calculations of the delocalized amide I vibrations. We present examples of the application of this method to extract site-specific structural information (such as hydrogen bond number and turn conformation) as well as insight into conformation dynamics and time-scales from experimental data for disordered peptides.

  4. Investigating protein structure and folding with coherent two-dimensional infrared spectroscopy

    Science.gov (United States)

    Baiz, Carlos; Peng, Chunte; Reppert, Michael; Jones, Kevin; Tokmakoff, Andrei

    2012-02-01

    We present a new technique to quantitatively determine the secondary structure composition of proteins in solution based on ultrafast two-dimensional infrared (2DIR) spectroscopy. The percentage of residues in alpha-helix, beta-sheet, and unstructured conformations is extracted from a principal component analysis of the measured amide-I 2DIR spectra. We benchmark the method against a library of commercially-available proteins by comparing the predicted structure compositions with the x-ray crystal structures. The new technique offers sub-picosecond time resolution, and can be used to study systems that are difficult to study with conventional methods such as gels, intrinsically disordered peptides, fibers, and aggregates. We use the technique to investigate the structural changes and timescales associated with folding and denaturing of small proteins via equilibrium and transient temperature-jump 2DIR spectroscopy.

  5. Two-Dimensional Infrared (2DIR) Spectroscopy of the Peptide Beta3s Folding

    Science.gov (United States)

    Lai, Zaizhi; Preketes, Nicholas K; Jiang, Jun; Mukamel, Shaul; Wang, Jin

    2013-01-01

    Probing underlying free energy landscape, pathways, and mechanism is the key for understanding protein folding in theory and experiment. Recently time-resolved two-dimensional infrared (2DIR) with femtosecond laser pulses, has emerged as a promising tool for investigating the protein folding dynamics on faster timescales than possible by NMR. We have employed molecular dynamics simulations to compute 2DIR spectra of the folding process of a peptide, Beta3s. Simulated non-chiral and chiral 2DIR signals illustrate the variation of the spectra as the peptide conformation evolves along the free energy landscape. Chiral spectra show stronger changes than the non-chiral signals because cross peaks caused by the formation of the β-sheet are clearly resolved. Chirality-induced 2DIR may be used to detect the folding of β-sheet proteins with high spectral and temporal resolution. PMID:23956818

  6. Monitoring the Folding of Trp-cage Peptide by Two-dimensional Infrared (2DIR) Spectroscopy

    Science.gov (United States)

    Lai, Zaizhi; Preketes, Nicholas K.; Mukamel, Shaul; Wang, Jin

    2013-01-01

    Protein folding is one of the most fundamental problems in modern molecular biology. Uncovering the detailed folding mechanism requires methods that can monitor the structures at high temporal and spatial resolution. Two-dimensional infrared (2DIR) spectroscopy is a new tool for studying protein structures and dynamics with high time resolution. Using atomistic molecular dynamics simulations, we illustrate the folding process of Trp-cage along the dominant pathway on free energy landscape by analyzing nonchiral and chiral coherent 2DIR spectra along the pathway. Isotope-labeling is used to reveal residue-specific information. We show that the high resolution structural sensitivity of 2DIR can differentiate the ensemble evolution of protein, and thus provides a microscopic picture of the folding process. PMID:23448437

  7. Two-dimensional infrared spectroscopic study on the thermally induced structural changes of glutaraldehyde-crosslinked collagen.

    Science.gov (United States)

    Tian, Zhenhua; Wu, Kun; Liu, Wentao; Shen, Lirui; Li, Guoying

    2015-04-05

    The thermal stability of collagen solution (5 mg/mL) crosslinked by glutaraldehyde (GTA) [GTA/collagen (w/w)=0.5] was measured by differential scanning calorimetry and Fourier transform infrared spectroscopy (FTIR), and the thermally induced structural changes were analyzed using two-dimensional (2D) correlation spectra. The denaturation temperature (Td) and enthalpy change (ΔH) of crosslinked collagen were respectively about 27°C and 88 J/g higher than those of native collagen, illuminating the thermal stability increased. With the increase of temperature, the red-shift of absorption bands and the decreased AIII/A1455 value obtained from FTIR spectra indicated that hydrogen bonds were weakened and the unwinding of triple helix occurred for both native and crosslinked collagens; whereas the less changes in red-shifting and AIII/A1455 values for crosslinked collagen also confirmed the increase in thermal stability. Additionally, the 2D correlation analysis provided information about the thermally induced structural changes. In the 2D synchronous spectra, the intensities of auto-peaks at 1655 and 1555 cm(-1), respectively assigned to amide I band (CO stretching vibration) and amide II band (combination of NH bending and CN stretching vibrations) in helical conformation were weaker for crosslinked collagen than those for native collagen, indicating that the helical structure of crosslinked collagen was less sensitive to temperature. Moreover, the sequence of the band intensity variations showed that the band at 1555 cm(-1) moved backwards owing to the addition of GTA, demonstrating that the response of helical structure of crosslinked collagen to the increased temperature lagged. It was speculated that the stabilization of collagen by GTA was due to the reinforcement of triple helical structure.

  8. Surface plasmon hurdles leading to a strongly localized giant field enhancement on two-dimensional (2D) metallic diffraction gratings.

    Science.gov (United States)

    Brûlé, Yoann; Demésy, Guillaume; Gralak, Boris; Popov, Evgeny

    2015-04-01

    An extensive numerical study of diffraction of a plane monochromatic wave by a single gold cone on a plane gold substrate and by a periodical array of such cones shows formation of curls in the map of the Poynting vector. They result from the interference between the incident wave, the wave reflected by the substrate, and the field scattered by the cone(s). In case of a single cone, when going away from its base along the surface, the main contribution in the scattered field is given by the plasmon surface wave (PSW) excited on the surface. As expected, it has a predominant direction of propagation, determined by the incident wave polarization. Two particular cones with height approximately 1/6 and 1/3 of the wavelength are studied in detail, as they present the strongest absorption and field enhancement when arranged in a periodic array. While the PSW excited by the smaller single cone shows an energy flux globally directed along the substrate surface, we show that curls of the Poynting vector generated with the larger cone touch the diopter surface. At this point, their direction is opposite to the energy flow of the PSW, which is then forced to jump over the vortex regions. Arranging the cones in a two-dimensional subwavelength periodic array (diffraction grating), supporting a specular reflected order only, resonantly strengthens the field intensity at the tip of cones and leads to a field intensity enhancement of the order of 10 000 with respect to the incident wave intensity. The enhanced field is strongly localized on the rounded top of the cones. It is accompanied by a total absorption of the incident light exhibiting large angular tolerances. This strongly localized giant field enhancement can be of much interest in many applications, including fluorescence spectroscopy, label-free biosensing, surface-enhanced Raman scattering (SERS), nonlinear optical effects and photovoltaics.

  9. An algorithm for circular test and improved optical configuration by two-dimensional (2D) laser heterodyne interferometer

    Science.gov (United States)

    Tang, Shanzhi; Yu, Shengrui; Han, Qingfu; Li, Ming; Wang, Zhao

    2016-09-01

    Circular test is an important tactic to assess motion accuracy in many fields especially machine tool and coordinate measuring machine. There are setup errors due to using directly centring of the measuring instrument for both of contact double ball bar and existed non-contact methods. To solve this problem, an algorithm for circular test using function construction based on matrix operation is proposed, which is not only used for the solution of radial deviation (F) but also should be applied to obtain two other evaluation parameters especially circular hysteresis (H). Furthermore, an improved optical configuration with a single laser is presented based on a 2D laser heterodyne interferometer. Compared with the existed non-contact method, it has a more pure homogeneity of the laser sources of 2D displacement sensing for advanced metrology. The algorithm and modeling are both illustrated. And error budget is also achieved. At last, to validate them, test experiments for motion paths are implemented based on a gantry machining center. Contrast test results support the proposal.

  10. Coherent Two-Dimensional Infrared Spectroscopy of Vibrational Excitons in Hydrogen-Bonded Liquids

    Science.gov (United States)

    Paarmann, Alexander

    The structure and structural dynamics of hydrogen bonded liquids were studied experimentally and theoretically with coherent two-dimensional infrared (2DIR) spectroscopy. The resonant intermolecular interactions within the fully resonant hydrogen bond networks give access to spatial correlations in the dynamics of the liquid structures. New experimental and theoretical tools were developed that significantly reduced the technical challenges of these studies. A nanofluidic flow device was designed and manufactured providing sub-micron thin, actively stabilized liquid sample layers between similarly thin windows. A simulation protocol for nonlinear vibrational response calculations of disordered fluctuating vibrational excitons was developed that allowed for the first treatment of resonant intermolecular interactions in the 2DIR response of liquid water. The 2DIR spectrum of the O-H stretching vibration of pure liquid water was studied experimentally at different temperatures. At ambient conditions the loss of frequency correlations is extremely fast, and is attributed to very efficient modulations of the two-dimensional O-H stretching vibrational potential through librational motions in the hydrogen bond network. At temperatures near freezing, the librational motions are significantly reduced leading to a pronounced slowing down of spectral diffusion dynamics. Comparison with energy transfer time scales revealed the first direct proof of delocalization of the vibrational excitations. This work establishes a fundamentally new view of vibrations in liquid water by providing a spatial length scale of correlated hydrogen-bond motions. The linear and 2DIR response of the amide I mode in neat liquid formamide was found to be dominated by excitonic effects due to largely delocalized vibrational excitations. The spectral response and dynamics are very sensitive to the excitonic mode structure and infrared activity distributions, leading to a pronounced asymmetry of linear

  11. Two Dimensional Electrostrictive Field Effect Transistor (2D-EFET): A sub-60mV/decade Steep Slope Device with High ON current

    Science.gov (United States)

    Das, Saptarshi

    2016-01-01

    This article proposes a disruptive device concept which meets both low power and high performance criterion for post-CMOS computing and at the same time enables aggressive channel length scaling. This device, hereafter refer to as two-dimensional electrostrictive field effect transistor or 2D-EFET, allows sub-60 mV/decade subthreshold swing and considerably higher ON current compared to any state of the art FETs. Additionally, by the virtue of its ultra-thin body nature and electrostatic integrity, the 2D-EFET enjoys scaling beyond 10 nm technology node. The 2D-EFET works on the principle of voltage induced strain transduction. It uses an electrostrictive material as gate oxide which expands in response to an applied gate bias and thereby transduces an out-of-plane stress on the 2D channel material. This stress reduces the inter-layer distance between the consecutive layers of the semiconducting 2D material and dynamically reduces its bandgap to zero i.e. converts it into a semi-metal. Thus the device operates with a large bandgap in the OFF state and a small or zero bandgap in the ON state. As a consequence of this transduction mechanism, internal voltage amplification takes place which results in sub-60 mV/decade subthreshold swing (SS). PMID:27721489

  12. Two Dimensional Electrostrictive Field Effect Transistor (2D-EFET): A sub-60mV/decade Steep Slope Device with High ON current

    Science.gov (United States)

    Das, Saptarshi

    2016-10-01

    This article proposes a disruptive device concept which meets both low power and high performance criterion for post-CMOS computing and at the same time enables aggressive channel length scaling. This device, hereafter refer to as two-dimensional electrostrictive field effect transistor or 2D-EFET, allows sub-60 mV/decade subthreshold swing and considerably higher ON current compared to any state of the art FETs. Additionally, by the virtue of its ultra-thin body nature and electrostatic integrity, the 2D-EFET enjoys scaling beyond 10 nm technology node. The 2D-EFET works on the principle of voltage induced strain transduction. It uses an electrostrictive material as gate oxide which expands in response to an applied gate bias and thereby transduces an out-of-plane stress on the 2D channel material. This stress reduces the inter-layer distance between the consecutive layers of the semiconducting 2D material and dynamically reduces its bandgap to zero i.e. converts it into a semi-metal. Thus the device operates with a large bandgap in the OFF state and a small or zero bandgap in the ON state. As a consequence of this transduction mechanism, internal voltage amplification takes place which results in sub-60 mV/decade subthreshold swing (SS).

  13. [Specific interaction study in collagen/hyaluronic acid blends by two-dimensional infrared correlation spectroscopy].

    Science.gov (United States)

    Tan, Qing-Tian; Tian, Zhen-Hua; Li, Guo-Ying

    2011-04-01

    Conformational changes and specific interactions in the collagen/hyaluronic acid blends were studied by two-dimensional infrared correlation spectroscopy with the interruption of the component of hyaluronic acid in collagen/ hyaluronic acid blends. It was found that the synchronous cross-peaks, derived from stretching vibrations of C=O at 1 694 cm(-1), wagging of N-H at 1 524 cm(-1) and in-plane deformation of N-H at 1 241 cm(-1) of collagen, were indicative of local conformational changes of collagen. The synchronous negative cross-peak between stretching vibrations of C-OH of hyaluronic acid at 1 045 cm(-1) and streching vibrations of C=O of collagen at 1 694 cm(-1) suggested that the interaction of hydrogen bonding existing between O-H of HA and C=O of collagen with the content of HA varied from 0% to 50%. With the content of HA more than 50%, the cross-peak at 1 045 cm(-1) disappeared in synchronous correlation spectra while the intensity of cross-peak at (1 694, 1 524), (1 694, 1 241), (1 524, 1 241) increased, which indicated that no interaction was found between O-H of HA and collagen, however, the interactions of hydrogen bonding existed between C=O of HA and N-H of collagen, resulting in the conformational changes of collagen.

  14. Linear Absorption and Two-Dimensional Infrared Spectra of N-Methylacetamide in Chloroform Revisited : Polarizability and Multipole Effects

    NARCIS (Netherlands)

    Jansen, Thomas L. C.

    2014-01-01

    The effect of solvent polarizability and multipole effects on the amide I vibrational spectra of a peptide unit is investigated. Four molecular dynamics force fields of increasing complexity for the solvent are used to model both the linear absorption and two-dimensional infrared spectra. It is obse

  15. Application of two-dimensional infrared spectroscopy to benchmark models for the amide I band of proteins

    NARCIS (Netherlands)

    Bondarenko, Anna S.; Jansen, Thomas L. C.

    2015-01-01

    In this paper, we present a novel benchmarking method for validating the modelling of vibrational spectra for the amide I region of proteins. We use the linear absorption spectra and two-dimensional infrared spectra of four experimentally well-studied proteins as a reference and test nine combinatio

  16. Generalized two-dimensional (2D) linear system analysis metrics (GMTF, GDQE) for digital radiography systems including the effect of focal spot, magnification, scatter, and detector characteristics

    Science.gov (United States)

    Kuhls-Gilcrist, Andrew T.; Gupta, Sandesh K.; Bednarek, Daniel R.; Rudin, Stephen

    2010-01-01

    The MTF, NNPS, and DQE are standard linear system metrics used to characterize intrinsic detector performance. To evaluate total system performance for actual clinical conditions, generalized linear system metrics (GMTF, GNNPS and GDQE) that include the effect of the focal spot distribution, scattered radiation, and geometric unsharpness are more meaningful and appropriate. In this study, a two-dimensional (2D) generalized linear system analysis was carried out for a standard flat panel detector (FPD) (194-micron pixel pitch and 600-micron thick CsI) and a newly-developed, high-resolution, micro-angiographic fluoroscope (MAF) (35-micron pixel pitch and 300-micron thick CsI). Realistic clinical parameters and x-ray spectra were used. The 2D detector MTFs were calculated using the new Noise Response method and slanted edge method and 2D focal spot distribution measurements were done using a pin-hole assembly. The scatter fraction, generated for a uniform head equivalent phantom, was measured and the scatter MTF was simulated with a theoretical model. Different magnifications and scatter fractions were used to estimate the 2D GMTF, GNNPS and GDQE for both detectors. Results show spatial non-isotropy for the 2D generalized metrics which provide a quantitative description of the performance of the complete imaging system for both detectors. This generalized analysis demonstrated that the MAF and FPD have similar capabilities at lower spatial frequencies, but that the MAF has superior performance over the FPD at higher frequencies even when considering focal spot blurring and scatter. This 2D generalized performance analysis is a valuable tool to evaluate total system capabilities and to enable optimized design for specific imaging tasks. PMID:21243038

  17. Insight into the Local Solvent Environment of Biologically Relevant Iron-nitroysl Systems through Two-Dimensional Infrared Spectroscopy

    Science.gov (United States)

    Brookes, Jennifer Faith

    Iron-nitrosyl systems, particularly in the form of heme proteins, with their iron metal active sites play an important role in biological systems. Heme proteins act as storage, transporters, and receptors for nitric oxide (NO), a signaling molecule that is important in immune, nervous, and cardiovascular systems of mammals. By better understanding the local environment of the active site of NO binding heme proteins we can gain insight into disease in which the NO pathways have been implicated. This is an important step to being able to develop pharmaceuticals targeting NO pathways in humans. Sodium nitroprusside ((SNP, Na2[Fe(CN)5is NO]·2H 2O) investigated as a model system for the active site of nitric oxide binding heme proteins. Using two-dimensional infrared spectroscopy (2D IR) to obtain dephasing dynamics of the nitrosyl stretch (nuNO) in a series of solvents we are able to better understand the local environment of the more complicated metalloproteins. Rigorous line shape analysis is performed by using nonlinear response theory to simulate 2D IR spectra which are then fit to experimental data in an iterative process to extract frequency-frequency correlation functions (FFCFs). The time scales obtained are then correlated to empirical solvent polarity parameters. The analysis of the 2D IR lineshapes reveal that the spectral diffusion timescale of the nuNO in SNP varies from 0.8 -- 4 ps and is negatively correlated with the empirical solvent polarity scales. We continue to investigate NO binding of metalloproteins through 2D IR experiments on nitrophorin 4 (NP4). NP4 is a pH-sensitive NO transporter protein present in the salivary gland of the blood sucking insect Rhodius prolixus which undergoes a pH sensitive structural change between a closed and open conformation allowing for the storage and delivery of NO. The two structures are observed spectroscopically as two distinct pH-dependent nu NO frequencies at ~1904 and ~1917 cm-1. We obtain FFCFs by globally

  18. Visual recognition of fishmeal and meat and bone meal using temperature-dependent two-dimensional correlation near-infrared spectroscopy.

    Science.gov (United States)

    Lü, Chengxu; Chen, Longjian; Yang, Zengling; Liu, Xian; Han, Lujia

    2013-12-01

    The purpose of this study is to investigate the efficiency of two-dimensional correlation spectroscopy (2D-COS) in recognizing the authenticity and purity of fishmeal (FM) and meat and bone meal (MBM), which are both complex mixtures with high similarity. Twenty FM samples and 20 MBM samples were obtained and examined. Temperature-dependent near-infrared (NIR) spectra were obtained using a Spectrum 400 spectrometer from 20 °C to 60 °C with an interval of 10 °C. Wavelet transform (Daubechies 5 wavelet with five levels) and baseline correction were applied to the temperature-dependent spectra in the wave range of 6000-5400 cm(-1). A 2D-COS synchronous map was calculated and scaled to the range between -1 and 1. A correlation coefficient was employed to quantitatively evaluate the visual differences of synchronous maps. The results show minor differences in NIR spectral absorbency of FM and MBM, and such differences are caused by appropriate temperature perturbation and enlarged by the 2D-COS method. The sensitive wave range is found in the area of 5800-5400 cm(-1). FM and MBM have observable pattern differences in the synchronous maps. Further quantitative evaluation of synchronous maps confirms correct recognizing results. Temperature-dependent 2D-COS is capable of recognizing the authenticity and purity of highly similar FM and MBM samples.

  19. Haptic-2D: A new haptic test battery assessing the tactual abilities of sighted and visually impaired children and adolescents with two-dimensional raised materials.

    Science.gov (United States)

    Mazella, Anaïs; Albaret, Jean-Michel; Picard, Delphine

    2016-01-01

    To fill an important gap in the psychometric assessment of children and adolescents with impaired vision, we designed a new battery of haptic tests, called Haptic-2D, for visually impaired and sighted individuals aged five to 18 years. Unlike existing batteries, ours uses only two-dimensional raised materials that participants explore using active touch. It is composed of 11 haptic tests, measuring scanning skills, tactile discrimination skills, spatial comprehension skills, short-term tactile memory, and comprehension of tactile pictures. We administered this battery to 138 participants, half of whom were sighted (n=69), and half visually impaired (blind, n=16; low vision, n=53). Results indicated a significant main effect of age on haptic scores, but no main effect of vision or Age × Vision interaction effect. Reliability of test items was satisfactory (Cronbach's alpha, α=0.51-0.84). Convergent validity was good, as shown by a significant correlation (age partialled out) between total haptic scores and scores on the B101 test (rp=0.51, n=47). Discriminant validity was also satisfactory, as attested by a lower but still significant partial correlation between total haptic scores and the raw score on the verbal WISC (rp=0.43, n=62). Finally, test-retest reliability was good (rs=0.93, n=12; interval of one to two months). This new psychometric tool should prove useful to practitioners working with young people with impaired vision.

  20. Two-dimensional correlation infrared spectroscopic study on the crystallization and gelation of poly(vinylidene fluoride) in cyclohexanone.

    Science.gov (United States)

    Peng, Yun; Sun, Bingjie; Wu, Peiyi

    2008-03-01

    Poly(vinylidene fluoride) (PVDF) converts easily into a thermo-reversible gel through crystallization by standing at room temperature in cyclohexanone. In this study, the Fourier transform infrared (FT-IR) spectra were measured continuously at room temperature during the conversion of the solution into a gel. The IR difference spectra derived from these spectra by absorbance subtraction clearly indicate the presence of PVDF alpha-crystallites in the gel due to the presence of absorption bands corresponding to the TG+TG- conformation of the alpha-phase. In the time interval from 25 to 45 min after the beginning of the experiment, the IR bands of PVDF increased dramatically, indicating the conversion of polymer chains from random statistical coils to the ordered TG+TG- conformation (alpha-form). In the time interval from 45 to 90 min, the IR bands of PVDF increased slowly, reflecting no further crystallization. Using two-dimensional (2D) IR analysis, it could be shown that the nu(C=O) absorption band of cyclohexanone changed during the gelation process. During the conformational ordering process (25-45 min), the nu(C=O) absorption band of the cyclohexanone dimer (1707 cm(-1)) decreased while the corresponding band of the monomer at 1718 cm(-1) increased. Furthermore, a new band at 1695 cm(-1) increased, which could be assigned to C=O groups of the solvent interacting with the CF2 groups in the polymer chain. The bands of the crystalline PVDF share positive cross-peaks with the bands of cyclohexanone, which indicates that the chain of PVDF changed prior to the cyclohexanone molecules during the conformational ordering process. However, these positive cross-peaks disappeared during the crystallization process, which means that the chain of PVDF changed synchronously with the solvent molecules. As for the bands of PVDF chains, the band at 762 cm(-1) varied prior to the bands at 873 cm(-1) and 796 cm(-1) during the conformational ordering process. The 762 cm(-1

  1. Depth profiling of SBS/PET layered materials using step-scan phase modulation Fourier transform infrared photoacoustic spectroscopy and two-dimensional correlation analysis

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    This paper demonstrates the application of step-scan phase modulation Fourier transform infrared photoacoustic spectroscopy(FTIR-PAS) in non-destructively depth profiling of styrene-butadiene-styrene block copolymer/polyethylene terephthalate(SBS/PET) layered materials.The surface thicknesses of three layered samples were determined to be 1.2,4.3 and 9.4μm by using phase difference analysis,overcoming the spatial detection limits of FTIR.Combined with generalized two-dimensional(G2D) FTIR correlation analysis,the spatial origins of peaks in the SBS/PET spectrum are identified with those having overlapping peaks between different layers are resolved.

  2. [Study of the effect of temperature on the conformation of ovotransferrin by two-dimensional infrared correlation spectroscopy].

    Science.gov (United States)

    Ren, Guo-Dong; Guo, Ai-Ling; Geng, Fang; Ma, Mei-Hu; Huang, Qun; Wu, Xiao-Fen

    2012-07-01

    The conformation changes of Apo-Ovotransferrin and Holo-Ovotransferrin were studied with the heat treatment 25-95 degrees C by using Fourier transform infrared spectroscopy (FTIR) and two-dimensional correlation spectroscopy analyzer. The results of one-dimensional infrared spectroscopy showed that with the increase in temperature, the peak at 3 300 cm(-1) of Apo-Ovo-transferrin shifted more than that of Holo-Ovotransferrin. The peak at 3 300 cm(-1) derived from stretching vibrations of N-H and O-H indicates that iron-binding enhanced the role of hydrogen bonds and resistance to heat. The changing order of the secondary structure of ovotransferrin was determined by analyzing two-dimensional infrared spectra,witch is beta-sheet>amide II >-CH2 - bending vibration. In addition, it was found that the cross-peaks at 1 652 and 1 688 cm(-1) are different in synchronous and asynchronous counter maps by comparing Apo-Ovotransferrin with Holo-Ovotransferrin. It was suggested that the temperature made less impact on the alpha-helix in Holo-Ovotransferrin than on that in Apo-Ovotransferrin, however, the beta-turn in Holo-Ovotransferrin was more sensitive to temperature.

  3. One- and two-dimensional infrared spectroscopic studies of solution-phase homogeneous catalysis and spin-forbidden reactions

    Energy Technology Data Exchange (ETDEWEB)

    Sawyer, Karma Rae [Univ. of California, Berkeley, CA (United States)

    2008-12-01

    Understanding chemical reactions requires the knowledge of the elementary steps of breaking and making bonds, and often a variety of experimental techniques are needed to achieve this goal. The initial steps occur on the femto- through picosecond time-scales, requiring the use of ultrafast spectroscopic methods, while the rate-limiting steps often occur more slowly, requiring alternative techniques. Ultrafast one and two-dimensional infrared and step-scan FTIR spectroscopies are used to investigate the photochemical reactions of four organometallic complexes. The analysis leads to a detailed understanding of mechanisms that are general in nature and may be applicable to a variety of reactions.

  4. Controlling the self-collimation characteristics of a near-infrared two-dimensional metallic photonic crystal

    Institute of Scientific and Technical Information of China (English)

    Feng Shuai; Ren Cheng; Wang Wen-Zhong; Wang Yi-Quan

    2012-01-01

    Self-collimation characteristics of the two-dimensional square-lattice photonic crystal (PC) consisting of metal rods immersed in silicon are studied by the finite-difference time-domain method.The Drude dispersion model is adopted to describe the metal rod,and the self-collimation behaviours of the near-infrared light through the PC are studied.The frequency region and the tolerance of incident angle for the self-collimation behaviour can be controlled by changing the shape of the metal rods.

  5. Derivatization technique to increase the spectral selectivity of two-dimensional Fourier transform infrared focal plane array imaging: analysis of binder composition in aged oil and tempera paint.

    Science.gov (United States)

    Zumbühl, Stefan; Scherrer, Nadim C; Eggenberger, Urs

    2014-01-01

    The interpretation of standard Fourier transform infrared spectra (FT-IR) on oil-based paint samples often suffers from interfering bands of the different compounds, namely, binder, oxidative aging products, carboxylates formed during aging, and several pigments and fillers. The distinction of the aging products such as ketone and carboxylic acid functional groups pose the next problem, as these interfere with the triglyceride esters of the oil. A sample preparation and derivatization technique using gaseous sulfur tetrafluoride (SF4), was thus developed with the aim to discriminate overlapping signals and achieve a signal enhancement on superposed compounds. Of particular interest in this context is the signal elimination of the broad carboxylate bands of the typical reaction products developing during the aging processes in oil-based paints, as well as signal interference originating from several typical pigments in this spectral range. Furthermore, it is possible to distinguish the different carbonyl-containing functional groups upon selective alteration. The derivatization treatment can be applied to both microsamples and polished cross sections. It increases the selectivity of the infrared spectroscopy technique in a fundamental manner and permits the identification and two-dimensional (2D) localization of binder components in aged paint samples at the micrometer scale. The combination of SF4 derivatization with high-resolution 2D FT-IR focal plane array (FPA) imaging delivers considerable advances to the study of micro-morphological processes involving organic compounds.

  6. [Study on the identification of radix scutellariae and extract using Fourier transform infrared spectroscopy and two-dimensional IR correlation spectroscopy].

    Science.gov (United States)

    Zhang, Chun-hui; Zhang, Gui-jun; Sun, Su-qin; Tu, Ya

    2010-07-01

    2D-IR correlation spectroscopy was used to do the research on crude and prepared drug of radix scutellariae and the extracts of them. The results show that the holistic shape of peaks among them are similar in the FTIR spectra. In second derivative spectra, the two absorption peaks: 1,745 and 1,411 cm(-1) of processed products move to the bigger wavenumber direction, while 1,357 cm(-1) of processed products moves to the smaller wavenumber direction; There are conspicuous differences in Two-dimensional infrared correlation spectroscopy among them: Four characteristic peaks are shown between 1,300 and 1,800 cm(-1). The intensity of peak at 1,575 cm(-1) is the strongest. There are three main districts about the autopeaks of sliced scutellariae. Wine-fried scutellariae has two auto-peak districts, in which all the auto-peaks are positively correlated. The FTIR spectra of total glycoside extract of different samples present characteristic peaks at 1,615, 1,585, 1,450 cm(-1) (vibration of phenyl framework) and 1,658 cm(-1) (=C-O ) respectively, therefore, the authors speculated that their mutual component is the compound of phenolic glycoside. The two-dimensional infrared correlation spectra present five automatic peaks (vibration of phenyl framework) in 800-1,800 cm(-1) (1,366, 1,420, 1,508, 1,585, 1,669 cm(-1)). So the authors can conclude that a lot of information can be provided by macro-fingerprint technology of infrared spectroscopy which can evaluate overall quality of radix scutellariae accurately and be used to study the characteristics of relevance of crude and prepared scutellariae.

  7. Two-dimensional Infrared Spectroscopy of vibrational polaritons of molecules in an optical cavity

    CERN Document Server

    Saurabh, Prasoon

    2016-01-01

    Strong coupling of molecular vibrations to an infrared cavity mode affects their nature by creating dressed polariton states. We show how the single and double vibrational polariton manifolds may be controlled by varying the cavity coupling strength, and probed by a time domain 2DIR technique, Double Quantum Coherence (DQC). Applications are made to the amide-I ($CO$) and amide-II ($CN$) bond vibrations of $N-methylacetamide$ (NMA).

  8. Identification of authentic and adulterated Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation analysis

    Science.gov (United States)

    Qu, Lei; Chen, Jian-bo; Zhou, Qun; Zhang, Gui-jun; Sun, Su-qin; Guo, Yi-zhen

    2016-11-01

    As a kind of expensive perfume and valuable herb, the commercial Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy and two-dimensional (2D) correlation analysis are employed to establish a simple and quick identification method for the authentic and adulterated ALR. In the conventional infrared spectra, the standard ALR has a strong peak at 1658 cm-1 referring to the conjugated carbonyl of resin, while this peak is absent in the adulterated samples. The position, intensity, and shape of the auto-peaks and cross-peaks of the authentic and adulterated ALR are much different in the synchronous 2D correlation spectra with thermal perturbation. In the range of 1700-1500 cm-1, the standard ALR has four obvious auto-peaks, while the strongest one is at 1659 cm-1. The adulterated sample w-1 has three obvious auto-peaks and the strongest one is at 1647 cm-1. The adulterated sample w-2 has three obvious auto-peaks and the strongest one is at 1519 cm-1. The adulterated sample w-3 has four obvious auto-peaks and the strongest one is at 1690 cm-1. The above auto-peaks confirm that the standard ALR contains a certain content of resin compounds, while the three counterfeits contain little or different resins. The results show the potential of FT-IR spectroscopy and 2D correlation analysis in the simple and quick identification of authentic and adulterated ALR.

  9. Two-dimensional ring-type photonic crystals in the near-infrared region

    Institute of Scientific and Technical Information of China (English)

    Xu Xing-Sheng; Wang Yi-Quan; Han Shou-Zhen; Cheng Bing-Ying; Zhang Dao-Zhong

    2004-01-01

    We propose a ring photonic crystal working in the near infrared region, where the air holes in the background material GaAs are arranged to form a series of rings. We find that the band gaps do not depend on the incident direction,and only a small number of rows are needed to create a frequency gap in the transmission spectrum. The transmission spectra of both P and S polarizations show that there is a complete bandgap in the hexagonal ring photonic crystals and the ratio of gap width to mid-gap frequency is as high as 11%.

  10. Anomalous infrared transmission of indium tin oxide thin films on two-dimensional nanosphere arrays.

    Science.gov (United States)

    Jiang, Hang; Zhou, Yuqin; Zhou, Yurong

    2016-04-15

    The excitation of surface plasmons was studied by nano-structural indium tin oxide (ITO) films in the infrared range using nano-imprint lithography (NIL). We investigated the effect of the diameter of silica spheres, thickness of ITO film, and ordering degree of the mask plate on the transmission spectra of structural ITO films by experiments and simulations. Increasing the diameter of silica spheres makes the transmission valley blueshift, while increasing the thickness of ITO film leads the transmission valley redshift. The transmission valley corresponds to the absorption band which results from the excitation of surface plasmons. The ordering degree and the surface coverage ratios of mask plate affect the transmission feature directly. An excitation of local surface plasmons may exist on the undulated ITO surface.

  11. Multiple-perturbation two-dimensional near-infrared correlation study of time-dependent water absorption behavior of cellulose affected by pressure.

    Science.gov (United States)

    Shinzawa, Hideyuki; Awa, Kimie; Noda, Isao; Ozaki, Yukihiro

    2013-02-01

    Transient water absorption by cellulosic samples manufactured under varying pressure was monitored by near-infrared spectroscopy to explore the absorption behavior affected by the pressure. A substantial level of variation of the spectral features was induced by the water absorption and changes in the pressure. The detail of the spectral changes was analyzed with a multiple-perturbation, two-dimensional (2D) correlation method to determine the underlying mechanism. The 2D correlation spectra indicated that the compression of the cellulose increased the packing density of the samples, preventing the penetration of water. In addition, the compression substantially disintegrated its crystalline structure and eventually resulted in the development of inter- and intrachain hydrogen-bonded structures arising from an interaction between the water and cellulose. Consequently, the cellulose samples essentially underwent an evolutionary change in the polymer structure as well as in the packing density during the compression. This structural change, in turn, led to the seemingly complicated absorption trends, depending on the pressure.

  12. Structural analysis of lime wood biodegraded by white rot fungi through infrared and two dimensional correlation spectroscopy techniques

    Science.gov (United States)

    Popescu, Carmen-Mihaela; Gradinariu, Petronela; Popescu, Maria-Cristina

    2016-11-01

    The action of the white rot fungi Phanerochaete crisosporium on the structure of lime wood (Tilia cordata) has been studied. The degree of decay was determined by weight loss, which was of 37% after 110 days. The samples were further analyzed by infrared and two dimensional correlation spectroscopy. The recorded spectra for different intervals of decay indicate variations in the intensities and width or wavenumber shifts of the bands assigned, both, for lignin and carbohydrates. An increase in the intensities of the bands from the carbonyl region due to formation of new structures, accompanied by the reduction of the methoxyl and methyl/methylene groups in lignin was evidenced. Further, the differences between reference and decayed wood spectra were examined in detail using 2DCOS spectroscopy and the second derivative analysis and the sequential order of modifications were established.

  13. Mid-Infrared Pulse Shaping and Two-Dimensional Spectroscopy of Open Quantum Systems in Liquid Solution

    Science.gov (United States)

    Ross, Matthew R.

    The primary focus of this work is the development of a mid-infrared pulse shaping system. The primary motivation for this system is for two-dimensional infrared (2DIR) spectroscopy, however, the mid-infrared pulse shaper also allows for more sophisticated spectroscopic experiments not previously attempted in the mid-infrared. Moreover, many can be implemented without changes or realignment of the optical setup. Example spectra are presented along with a discussion of capabilities and diagnostics. A second major project presented is 2DIR spectroscopy of iron pentacarbonyl, Fe(CO)5, a small metal carbonyl. This molecule undergoes Berry pseudorotation, a form of fluxtionality. This fast exchange of ligands mixes axial and equatorial modes and occurs on a timescale of picoseconds, too fast for NMR and other methods of measuring chemical structure and isomerization. Ultrafast chemical exchange spectroscopy, a measurement within 2DIR spectroscopy, is capable of resolving the time scales of this motion. We found that this process is affected by the solvent environment, specifically the solvent viscosity in alkanes and hydrogen bonding environments in alcohols. Lastly, a study is presented in which a series of synthetic metalloenzymes with a metal active site are studied by 2DIR spectroscopy. In this case a carbonyl is ligated to a copper-I atom in the active site, which then serves as our spectroscopic probe. We find, unexpectedly, that the shape of the carbonyl vibrational potential, as measured by the anharmonicity, is time-dependent. We attribute this to a geometrical rearrangement and are able to suggest that this effect is dependent on local site structure and dynamics and not significantly affected by electric potential near the peptide.

  14. Adulteration screening of botanical materials by a sensitive and model-free approach using infrared spectroscopic imaging and two-dimensional correlation infrared spectroscopy

    Science.gov (United States)

    Chen, Jian-bo; Zhou, Qun; Sun, Su-qin

    2016-11-01

    Infrared (IR) spectroscopy is often used as a simple, fast, and green method for the adulteration screening of botanical materials for foods and herbs. However, the overlapping of absorption signals of various substances significantly decrease the sensitivity and specificity of IR spectroscopy in the detection of adulterated samples. In this research, a model-free approach is proposed for the sensitive and non-targeted screening of botanical materials adulterated by adding other plant materials. First, the spectra of the entities in the test sample are collected by near-infrared spectroscopic imaging and clustered by unsupervised pattern recognition methods. The sample may be adulterated if there are two or more clusters of the entities. Next, the entities of different clusters are characterized by mid-infrared spectroscopy to interpret the chemical compositions to determine the clustering is caused whether by adulteration or other reasons. Second derivative spectroscopy and two-dimensional correlation spectroscopy are often needed to resolve the overlapped bands mathematically or experimentally to find the characteristic signals to identify the authentic and adulterant entities. The feasibility of this approach was proved by the simulated adulterated sample of saffron. In conclusion, botanical materials adulterated by adding other plant materials can be detected by a simple, fast, sensitive, and green screening approach using IR spectroscopic imaging, two-dimensional correlation spectroscopy, and necessary chemometrics techniques.

  15. Water dynamics in small reverse micelles in two solvents: Two-dimensional infrared vibrational echoes with two-dimensional background subtraction

    Science.gov (United States)

    Fenn, Emily E.; Wong, Daryl B.; Fayer, M. D.

    2011-02-01

    Water dynamics as reflected by the spectral diffusion of the water hydroxyl stretch were measured in w0 = 2 (1.7 nm diameter) Aerosol-OT (AOT)/water reverse micelles in carbon tetrachloride and in isooctane solvents using ultrafast 2D IR vibrational echo spectroscopy. Orientational relaxation and population relaxation are observed for w0 = 2, 4, and 7.5 in both solvents using IR pump-probe measurements. It is found that the pump-probe observables are sensitive to w0, but not to the solvent. However, initial analysis of the vibrational echo data from the water nanopool in the reverse micelles in the isooctane solvent seems to yield different dynamics than the CCl4 system in spite of the fact that the spectra, vibrational lifetimes, and orientational relaxation are the same in the two systems. It is found that there are beat patterns in the interferograms with isooctane as the solvent. The beats are observed from a signal generated by the AOT/isooctane system even when there is no water in the system. A beat subtraction data processing procedure does a reasonable job of removing the distortions in the isooctane data, showing that the reverse micelle dynamics are the same within experimental error regardless of whether isooctane or carbon tetrachloride is used as the organic phase. Two time scales are observed in the vibrational echo data, ~1 and ~10 ps. The slower component contains a significant amount of the total inhomogeneous broadening. Physical arguments indicate that there is a much slower component of spectral diffusion that is too slow to observe within the experimental window, which is limited by the OD stretch vibrational lifetime.

  16. Facile synthesis of CuSe nanoparticles and high-quality single-crystal two-dimensional hexagonal nanoplatelets with tunable near-infrared optical absorption

    Science.gov (United States)

    Wu, Yimin; Korolkov, Ilia; Qiao, Xvsheng; Zhang, Xianghua; Wan, Jun; Fan, Xianping

    2016-06-01

    A rapid injection approach is used to synthesize the copper selenide nanoparticles and two-dimensional single crystal nanoplates. This technique excludes the use of toxic or expensive materials, increasing the availability of two-dimensional binary chalcogenide semiconductors. The structure of the nanocrystals has been studied and the possible formation mechanism of the nanoplates has been proposed. The optical absorption showed that the nanoplates demonstrated wide and tuneable absorption band in the visible and near infrared region. These nanoplates could be interesting for converting solar energy and for nanophotonic devices operating in the near infrared.

  17. Two-dimensional HRCT for monitoring postoperative results of the anterior cruciate ligament reconstruction. Zweidimensionale (2-D) CT-Arthrotomographie zur postoperativen Kontrolle einer neuen vorderen Kreuzbandplastik

    Energy Technology Data Exchange (ETDEWEB)

    Tosch, U.; Witt, H. (Freie Univ. Berlin (Germany, F.R.). Roentgendiagnostisches Zentralinstitut); Hertel, P.; Lais, E. (Freie Univ. Berlin (Germany, F.R.). Unfallchirurgische Klinik)

    1989-11-01

    Fifty-eight patients underwent intraarticular reconstruction of the anterior cruciate ligament. This was performed by using an autogenous transplant from the mid portion of the patellar ligament with a proximal and distal bone block, as described by Hertel. For comparison with the conventional X-ray examination, HRCT was performed to study the early postoperative results. In four patients (7%) dislocation of the bone block in the femoral condyle was seen. Two-dimensional reconstruction proved to be a satisfactory method for demonstration of the exact position of the autogenous transplant in both coronary and sagittal planes. (orig.).

  18. Two-dimensional heterospectral correlation analysis of the redox-induced conformational transition in cytochrome c using surface-enhanced Raman and infrared absorption spectroscopies on a two-layer gold surface.

    Science.gov (United States)

    Zou, Changji; Larisika, Melanie; Nagy, Gabor; Srajer, Johannes; Oostenbrink, Chris; Chen, Xiaodong; Knoll, Wolfgang; Liedberg, Bo; Nowak, Christoph

    2013-08-22

    The heme protein cytochrome c adsorbed to a two-layer gold surface modified with a self-assembled monolayer of 2-mercaptoethanol was analyzed using a two-dimensional (2D) heterospectral correlation analysis that combined surface-enhanced infrared absorption spectroscopy (SEIRAS) and surface-enhanced Raman spectroscopy (SERS). Stepwise increasing electric potentials were applied to alter the redox state of the protein and to induce conformational changes within the protein backbone. We demonstrate herein that 2D heterospectral correlation analysis is a particularly suitable and useful technique for the study of heme-containing proteins as the two spectroscopies address different portions of the protein. Thus, by correlating SERS and SEIRAS data in a 2D plot, we can obtain a deeper understanding of the conformational changes occurring at the redox center and in the supporting protein backbone during the electron transfer process. The correlation analyses are complemented by molecular dynamics calculations to explore the intramolecular interactions.

  19. Identification and relative quantification of tyrosine nitration in a model peptide using two-dimensional infrared spectroscopy.

    Science.gov (United States)

    Rezende Valim, Lays; Davies, Julia A; Tveen Jensen, Karina; Guo, Rui; Willison, Keith R; Spickett, Corinne M; Pitt, Andrew R; Klug, David R

    2014-11-13

    Nitration of tyrosine in proteins and peptides is a post-translational modification that occurs under conditions of oxidative stress. It is implicated in a variety of medical conditions, including neurodegenerative and cardiovascular diseases. However, monitoring tyrosine nitration and understanding its role in modifying biological function remains a major challenge. In this work, we investigate the use of electron-vibration-vibration (EVV) two-dimensional infrared (2DIR) spectroscopy for the study of tyrosine nitration in model peptides. We demonstrate the ability of EVV 2DIR spectroscopy to differentiate between the neutral and deprotonated states of 3-nitrotyrosine, and we characterize their spectral signatures using information obtained from quantum chemistry calculations and simulated EVV 2DIR spectra. To test the sensitivity of the technique, we use mixed-peptide samples containing various levels of tyrosine nitration, and we use mass spectrometry to independently verify the level of nitration. We conclude that EVV 2DIR spectroscopy is able to provide detailed spectroscopic information on peptide side-chain modifications and to detect nitration levels down to 1%. We further propose that lower nitration levels could be detected by introducing a resonant Raman probe step to increase the detection sensitivity of EVV 2DIR spectroscopy.

  20. Analysis of branched DNA replication and recombination intermediates from prokaryotic cells by two-dimensional (2D) native-native agarose gel electrophoresis.

    Science.gov (United States)

    Robinson, Nicholas P

    2013-01-01

    Branched DNA molecules are generated by the essential processes of replication and recombination. Owing to their distinctive extended shapes, these intermediates migrate differently from linear double-stranded DNA under certain electrophoretic conditions. However, these branched species exist in the cell at much low abundance than the bulk linear DNA. Consequently, branched molecules cannot be visualized by conventional electrophoresis and ethidium bromide staining. Two-dimensional native-native agarose electrophoresis has therefore been developed as a method to facilitate the separation and visualization of branched replication and recombination intermediates. A wide variety of studies have employed this technique to examine branched molecules in eukaryotic, archaeal, and bacterial cells, providing valuable insights into how DNA is duplicated and repaired in all three domains of life.

  1. Effect of the observation length on the two-dimensional shadowing function of the sea surface: application on infrared 3-13-microm emissivity.

    Science.gov (United States)

    Bourlier, C; Saillard, J; Berginc, G

    2000-07-10

    An analytical approach of the two-dimensional emissivity of a rough sea surface in the infrared band is presented. The emissivity characterizes the intrinsic radiation of the sea surface. Because the temperature measured by the infrared camera depends on the emissivity, the emissivity is a relevant parameter for retrieving the sea-surface temperature from remotely sensed radiometric measurements, such as from satellites. This theory is developed from the first-order geometrical-optics approximation and is based on recent research. The typical approach assumes that the slope in the upwind direction is greater than the slope in the crosswind direction, involving the use of a one-dimensional shadowing function with the observed surface assumed to be infinite. We introduce the two-dimensional shadowing function and the surface observation length parameters that are included in the modeling of the two-dimensional emissivity.

  2. Comparative Variable Temperature Studies of Polyamide II with a Benchtop Fourier Transform and a Miniature Handheld Near-Infrared Spectrometer Using 2D-COS and PCMW-2D Analysis.

    Science.gov (United States)

    Unger, Miriam; Pfeifer, Frank; Siesler, Heinz W

    2016-07-01

    The main objective of this communication is to compare the performance of a miniaturized handheld near-infrared (NIR) spectrometer with a benchtop Fourier transform near-infrared (FT-NIR) spectrometer. Generally, NIR spectroscopy is an extremely powerful analytical tool to study hydrogen-bonding changes of amide functionalities in solid and liquid materials and therefore variable temperature NIR measurements of polyamide II (PAII) have been selected as a case study. The information content of the measurement data has been further enhanced by exploiting the potential of two-dimensional correlation spectroscopy (2D-COS) and the perturbation correlation moving window two-dimensional (PCMW2D) evaluation technique. The data provide valuable insights not only into the changes of the hydrogen-bonding structure and the recrystallization of the hydrocarbon segments of the investigated PAII but also in their sequential order. Furthermore, it has been demonstrated that the 2D-COS and PCMW2D results derived from the spectra measured with the miniaturized NIR instrument are equivalent to the information extracted from the data obtained with the high-performance FT-NIR instrument.

  3. Analysis of Chuanxiong Rhizoma and its active components by Fourier transform infrared spectroscopy combined with two-dimensional correlation infrared spectroscopy

    Science.gov (United States)

    Guo, Yizhen; Lv, Beiran; Wang, Jingjuan; Liu, Yang; Sun, Suqin; Xiao, Yao; Lu, Lina; Xiang, Li; Yang, Yanfang; Qu, Lei; Meng, Qinghong

    2016-01-01

    As complicated mixture systems, active components of Chuanxiong Rhizoma are very difficult to identify and discriminate. In this paper, the macroscopic IR fingerprint method including Fourier transform infrared spectroscopy (FT-IR), the second derivative infrared spectroscopy (SD-IR) and two-dimensional correlation infrared spectroscopy (2DCOS-IR), was applied to study and identify Chuanxiong raw materials and its different segmented production of HPD-100 macroporous resin. Chuanxiong Rhizoma is rich in sucrose. In the FT-IR spectra, water eluate is more similar to sucrose than the powder and the decoction. Their second derivative spectra amplified the differences and revealed the potentially characteristic IR absorption bands and combined with the correlation coefficient, concluding that 50% ethanol eluate had more ligustilide than other eluates. Finally, it can be found from 2DCOS-IR spectra that proteins were extracted by ethanol from Chuanxiong decoction by HPD-100 macroporous resin. It was demonstrated that the above three-step infrared spectroscopy could be applicable for quick, non-destructive and effective analysis and identification of very complicated and similar mixture systems of traditional Chinese medicines.

  4. Comprehensive two-dimensional liquid chromatography with on-line Fourier-transform-infrared-spectroscopy detection for the characterization of copolymers

    NARCIS (Netherlands)

    Kok, S.J.; Hankemeier, T.; Schoenmakers, P.J.

    2005-01-01

    The on-line coupling of comprehensive two-dimensional liquid chromatography (liquid chromatography × size-exclusion chromatography, LC × SEC) and infrared (IR) spectroscopy has been realized by means of an IR flow cell. The system has been assessed by the functional-group analysis of a series of

  5. Comprehensive two-dimensional liquid chromatography with on-line Fourier-transform-infrared-spectroscopy detection for the characterization of copolymers

    NARCIS (Netherlands)

    Kok, S.J.; Hankemeier, T.; Schoenmakers, P.J.

    2005-01-01

    The on-line coupling of comprehensive two-dimensional liquid chromatography (liquid chromatography × size-exclusion chromatography, LC × SEC) and infrared (IR) spectroscopy has been realized by means of an IR flow cell. The system has been assessed by the functional-group analysis of a series of sty

  6. Application of highly sensitive fluorescent dyes (CyDye DIGE Fluor saturation dyes) to laser microdissection and two-dimensional difference gel electrophoresis (2D-DIGE) for cancer proteomics.

    Science.gov (United States)

    Kondo, Tadashi; Hirohashi, Setsuo

    2006-01-01

    Proteome data combined with histopathological information provides important, novel clues for understanding cancer biology and reveals candidates for tumor markers and therapeutic targets. We have established an application of a highly sensitive fluorescent dye (CyDye DIGE Fluor saturation dye), developed for two-dimensional difference gel electrophoresis (2D-DIGE), to the labeling of proteins extracted from laser microdissected tissues. The use of the dye dramatically decreases the protein amount and, in turn, the number of cells required for 2D-DIGE; the cells obtained from a 1 mm2 area of an 8-12 microm thick tissue section generate up to 5,000 protein spots in a large-format 2D gel. This protocol allows the execution of large-scale proteomics in a more efficient, accurate and reproducible way. The protocol can be used to examine a single sample in 5 d or to examine hundreds of samples in large-scale proteomics.

  7. JAC2D: A two-dimensional finite element computer program for the nonlinear quasi-static response of solids with the conjugate gradient method; Yucca Mountain Site Characterization Project

    Energy Technology Data Exchange (ETDEWEB)

    Biffle, J.H.; Blanford, M.L.

    1994-05-01

    JAC2D is a two-dimensional finite element program designed to solve quasi-static nonlinear mechanics problems. A set of continuum equations describes the nonlinear mechanics involving large rotation and strain. A nonlinear conjugate gradient method is used to solve the equations. The method is implemented in a two-dimensional setting with various methods for accelerating convergence. Sliding interface logic is also implemented. A four-node Lagrangian uniform strain element is used with hourglass stiffness to control the zero-energy modes. This report documents the elastic and isothermal elastic/plastic material model. Other material models, documented elsewhere, are also available. The program is vectorized for efficient performance on Cray computers. Sample problems described are the bending of a thin beam, the rotation of a unit cube, and the pressurization and thermal loading of a hollow sphere.

  8. In situ orientation studies of a poly(3-hydroxybutyrate)/poly(epsilon-caprolactone) blend by rheo-optical fourier transform infrared spectroscopy and two-dimensional correlation spectroscopic analysis.

    Science.gov (United States)

    Unger, Miriam; Siesler, Heinz W

    2009-12-01

    In the present study, the orientation of a poly(3-hydroxybutyrate) (PHB)/poly(epsilon-caprolactone) (PCL) blend was monitored during uniaxial elongation by rheo-optical Fourier transform infrared (FT-IR) spectroscopy and analyzed by generalized two-dimensional correlation spectroscopy (2D-COS). The dichroism of the delta(CH(2)) absorption bands of PHB and PCL was employed to determine the polymer chain orientation in the PHB/PCL blend during the elongation up to 267% strain. From the PHB and PCL specific orientation functions it was derived that the PCL chains orient into the drawing direction while the PHB chains orient predominantly perpendicular to the applied strain. To extract more detailed information about the polymer orientation during uniaxial elongation, 2D-COS analysis was employed for the dichroic difference of the polarization spectra recorded during the drawing process. In the corresponding synchronous and asynchronous 2D correlation plots, absorption bands characteristic of the crystalline and amorphous regions of PHB and PCL were separated. Furthermore, the 2D-COS analysis revealed that during the mechanical treatment the PCL domains orient before the PHB domains.

  9. Comparison of vibrational dynamics between non-ionic and ionic vibrational probes in water: Experimental study with two-dimensional infrared and infrared pump-probe spectroscopies

    Science.gov (United States)

    Okuda, Masaki; Ohta, Kaoru; Tominaga, Keisuke

    2016-09-01

    Dynamics of the hydration structure around small vibrational probes have been extensively studied over the past few decades. However, we need to gain insight into how vibrational dynamics is affected by the molecular nature of the probe molecules in water. In this study, 2-nitro-5-thiocyanate benzoic acid (NTBA), which has an SCN group attached to an aromatic ring, and thiocyanate ion (SCN-) were used to investigate the vibrational dynamics of two vibrational probes, including vibrational frequency fluctuations and rotational relaxation. By performing two-dimensional infrared spectroscopic measurements, the vibrational frequency fluctuations of the SCN anti-stretching modes of these solutes were compared. The frequency-frequency time correlation function (FFTCF) of these solutes can be modeled by a delta function plus an exponential function and a constant. The FFTCF of NTBA was characterized by a time constant of 1.1 ps, which is similar to that of SCN-. Moreover, no component was longer than this constant. Consequently, the loss of the correlation in frequency fluctuations of the SCN anti-stretching mode of NTBA may be controlled by a mechanism similar to that of the ionic probe, which involves the hydrogen bonding dynamics of water. Polarization-controlled IR pump-probe measurements were performed for these vibrational probes in water to study the vibrational energy relaxation (VER) and reorientational relaxation processes. The VER rate of NTBA is much smaller than that of SCN-, which indicates that the intramolecular relaxation process is significant for VER of NTBA. Based on the rotational relaxation time of NTBA being shorter than that of SCN-, the internal rotational motion of the SCN group around the Cphenyl-S bond axis, where Cphenyl denotes a carbon atom of the aromatic ring to which the SCN group is attached, may play an important role in the anisotropic decay of NTBA in H2O.

  10. [Apply fourier transform infrared spectra coupled with two-dimensional correlation analysis to study the evolution of humic acids during composting].

    Science.gov (United States)

    Bu, Gui-jun; Yu, Jing; Di, Hui-hui; Luo, Shi-jia; Zhou, Da-zhai; Xiao, Qiang

    2015-02-01

    The composition and structure of humic acids formed during composting play an important influence on the quality and mature of compost. In order to explore the composition and evolution mechanism, municipal solid wastes were collected to compost and humic and fulvic acids were obtained from these composted municipal solid wastes. Furthermore, fourier transform infrared spectra and two-dimensional correlation analysis were applied to study the composition and transformation of humic and fulvic acids during composting. The results from fourier transform infrared spectra showed that, the composition of humic acids was complex, and several absorbance peaks were observed at 2917-2924, 2844-2852, 2549, 1662, 1622, 1566, 1454, 1398, 1351, 990-1063, 839 and 711 cm(-1). Compared to humic acids, the composition of fulvci acids was simple, and only three peaks were detected at 1725, 1637 and 990 cm(-1). The appearance of these peaks showed that both humic and fulvic acids comprised the benzene originated from lignin and the polysaccharide. In addition, humic acids comprised a large number of aliphatic and protein which were hardly detected in fulvic acids. Aliphatic, polysaccharide, protein and lignin all were degraded during composting, however, the order of degradation was different between humic and fulvci acids. The result from two-dimensional correlation analysis showed that, organic compounds in humic acids were degraded in the following sequence: aliphatic> protein> polysaccharide and lignin, while that in fulvic acids was as following: protein> polysaccharide and aliphatic. A large number of carboxyl, alcohols and ethers were formed during the degradation process, and the carboxyl was transformed into carbonates. It can be concluded that, fourier transform infrared spectra coupled with two-dimensional correlation analysis not only can analyze the function group composition of humic substances, but also can characterize effectively the degradation sequence of these

  11. Two-dimensional monthly average ozone balance from limb infrared monitor of the stratosphere and stratospheric and mesospheric sounder data

    Science.gov (United States)

    Jackman, C. H.; Stolarski, R. S.; Kaye, J. A.

    1986-01-01

    For many years, atmospheric scientists have been concerned with the balance of ozone production and loss terms in the upper stratosphere. Crutzen and Schmailzl (1983) found that the ozone loss was higher than the ozone production in the upper stratosphere. In the present investigation, previous studies are used as a basis in the conduction of a two-dimensional calculation of the production and loss of ozone. The monthly and zonally averaged loss and production rates for ozone are computed using recent Nimbus 7 satellite measurements of stratospheric constituents and accepted reaction and photodissociation rates. It is found that ozone has a loss rate which is about 40-60 percent higher than the production in the photochemical region.

  12. Framework for 2D-3D image fusion of infrared thermography with preoperative MRI.

    Science.gov (United States)

    Hoffmann, Nico; Weidner, Florian; Urban, Peter; Meyer, Tobias; Schnabel, Christian; Radev, Yordan; Schackert, Gabriele; Petersohn, Uwe; Koch, Edmund; Gumhold, Stefan; Steiner, Gerald; Kirsch, Matthias

    2017-01-23

    Multimodal medical image fusion combines information of one or more images in order to improve the diagnostic value. While previous applications mainly focus on merging images from computed tomography, magnetic resonance imaging (MRI), ultrasonic and single-photon emission computed tomography, we propose a novel approach for the registration and fusion of preoperative 3D MRI with intraoperative 2D infrared thermography. Image-guided neurosurgeries are based on neuronavigation systems, which further allow us track the position and orientation of arbitrary cameras. Hereby, we are able to relate the 2D coordinate system of the infrared camera with the 3D MRI coordinate system. The registered image data are now combined by calibration-based image fusion in order to map our intraoperative 2D thermographic images onto the respective brain surface recovered from preoperative MRI. In extensive accuracy measurements, we found that the proposed framework achieves a mean accuracy of 2.46 mm.

  13. Ultrafast Structural Fluctuations of Myoglobin-Bound Thiocyanate and Selenocyanate Ions Measured with Two-Dimensional Infrared Photon Echo Spectroscopy.

    Science.gov (United States)

    Maj, Michał; Kwak, Kyungwon; Cho, Minhaeng

    2015-11-16

    Structural dynamics within the distal cavity of myoglobin protein is investigated using 2D-IR and IR pump-probe spectroscopy of the N≡C stretch modes of heme-bound thiocyanate and selenocyanate ions. Although myoglobin-bound thiocyanate group shows a doublet in its IR absorption spectrum, no cross peaks originating from chemical exchange between the two components are observed in the time-resolved 2D IR spectra within the experimental time window. Frequency-frequency correlation functions of the two studied anionic ligands are obtained by means of a few different analysis approaches; these functions were then used to elucidate the differences in structural fluctuation around ligand, ligand-protein interactions, and the degree of structural heterogeneity within the hydrophobic pocket of these myoglobin complexes.

  14. Simulations of the infrared, Raman, and 2D-IR photon echo spectra of water in nanoscale silica pores.

    Science.gov (United States)

    Burris, Paul C; Laage, Damien; Thompson, Ward H

    2016-05-21

    Vibrational spectroscopy is frequently used to characterize nanoconfined liquids and probe the effect of the confining framework on the liquid structure and dynamics relative to the corresponding bulk fluid. However, it is still unclear what molecular-level information can be obtained from such measurements. In this paper, we address this question by using molecular dynamics (MD) simulations to reproduce the linear infrared (IR), Raman, and two-dimensional IR (2D-IR) photon echo spectra for water confined within hydrophilic (hydroxyl-terminated) silica mesopores. To simplify the spectra the OH stretching region of isotopically dilute HOD in D2O is considered. An empirical mapping approach is used to obtain the OH vibrational frequencies, transition dipoles, and transition polarizabilities from the MD simulations. The simulated linear IR and Raman spectra are in good general agreement with measured spectra of water in mesoporous silica reported in the literature. The key effect of confinement on the water spectrum is a vibrational blueshift for OH groups that are closest to the pore interface. The blueshift can be attributed to the weaker hydrogen bonds (H-bonds) formed between the OH groups and silica oxygen acceptors. Non-Condon effects greatly diminish the contribution of these OH moieties to the linear IR spectrum, but these weaker H-bonds are readily apparent in the Raman spectrum. The 2D-IR spectra have not yet been measured and thus the present results represent a prediction. The simulated spectra indicates that it should be possible to probe the slower spectral diffusion of confined water compared to the bulk liquid by analysis of the 2D-IR spectra.

  15. Facile synthesis of CuSe nanoparticles and high-quality single-crystal two-dimensional hexagonal nanoplatelets with tunable near-infrared optical absorption

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Yimin [State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Korolkov, Ilia [Laboratory of Glasses and Ceramics, Institute of Chemistry, CNRS-Université de Rennes I, Campus de Beaulieu, 35042 Rennes Cedex (France); Qiao, Xvsheng [State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Zhang, Xianghua [Laboratory of Glasses and Ceramics, Institute of Chemistry, CNRS-Université de Rennes I, Campus de Beaulieu, 35042 Rennes Cedex (France); Wan, Jun; Fan, Xianping [State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China)

    2016-06-15

    A rapid injection approach is used to synthesize the copper selenide nanoparticles and two-dimensional single crystal nanoplates. This technique excludes the use of toxic or expensive materials, increasing the availability of two-dimensional binary chalcogenide semiconductors. The structure of the nanocrystals has been studied and the possible formation mechanism of the nanoplates has been proposed. The optical absorption showed that the nanoplates demonstrated wide and tuneable absorption band in the visible and near infrared region. These nanoplates could be interesting for converting solar energy and for nanophotonic devices operating in the near infrared. - Graphical abstract: TEM images of the copper selenides nanoparticles and nanoplates synthesized at 180 °C for 0 min, 10 min, 60 min. And the growth mechanism of the copper selenide nanoplates via the “oriented attachment”. Display Omitted - Highlights: • CuSe nanoparticles and nanoplates are synthesized by a rapid injection approach. • CuSe band gap can be widely tuned simply by modifying the synthesized time. • Al{sup 3+} ions have a significant impact on the growth rate of the nanoplates. • Growth mechanism of the CuSe nanoplates is based on the “oriented attachment”.

  16. Topological defects in two-dimensional crystals

    OpenAIRE

    Chen, Yong; Qi, Wei-Kai

    2008-01-01

    By using topological current theory, we study the inner topological structure of the topological defects in two-dimensional (2D) crystal. We find that there are two elementary point defects topological current in two-dimensional crystal, one for dislocations and the other for disclinations. The topological quantization and evolution of topological defects in two-dimensional crystals are discussed. Finally, We compare our theory with Brownian-dynamics simulations in 2D Yukawa systems.

  17. Infrared ion spectroscopy inside a mass-selective cryogenic 2D linear ion trap.

    Science.gov (United States)

    Cismesia, Adam P; Tesler, Larry F; Bell, Matthew R; Bailey, Laura S; Polfer, Nicolas C

    2017-07-27

    We demonstrate operation of the first cryogenic 2D linear ion trap (LIT) with mass-selective capabilities. This trap presents a number of advantages for infrared ion "action" spectroscopy studies, particularly those employing the "tagging/messenger" spectroscopy approach. The high trapping efficiencies, trapping capacities, and low detection limits make 2D LITs a highly suitable choice for low-concentration analytes from scarce biological samples. In our trap, ions can be cooled down to cryogenic temperatures to achieve higher-resolution infrared spectra, and individual ions can be mass selected prior to irradiation for a background-free photodissociation scheme. Conveniently, multiple tagged analyte ions can be mass isolated and efficiently irradiated in the same experiment, allowing their infrared spectra to be recorded in parallel. This multiplexed approach is critical in terms of increasing the duty cycle of infrared ion spectroscopy, which is currently a key weakness of the technique. The compact design of this instrument, coupled with powerful mass selection capabilities, set the stage for making cryogenic infrared ion spectroscopy viable as a bioanalytical tool in small molecule identification. This article is protected by copyright. All rights reserved.

  18. Infrared pulsed fiber lasers employing 2D nanomaterials as saturable absorbers

    Science.gov (United States)

    Liu, Yong; Li, Heping; Li, Jianfeng

    2016-11-01

    We demonstrate that two kinds of 2D nanomaterials are employed as saturable absorbers to realize infrared pulsed fiber lasers at 1.5 μm and 3 μm, respectively. Mode-locked optical pulses are achieved at 1.5 μm erbium-doped fiber lasers by using multilayer molybdenum disulfide (MoS2). In addition, Q-switched fiber lasers are realized at 3 μm region by using topological insulator: Bi2Te3. Experimental proofs are provided. Our work reveals that 2D nanomaterials like MoS2 and TI: Bi2Te3 are absolutely a class of promising and reliable saturable absorbers for optical pulse generation at infrared waveband.

  19. Understanding the two-dimensional ionization structure in luminous infrared galaxies. A near-IR integral field spectroscopy perspective

    CERN Document Server

    Colina, Luis; Arribas, Santiago; Riffel, Rogerio; Riffel, Rogemar A; Rodriguez-Ardila, Alberto; Pastoriza, Miriani; Storchi-Bergmann, Thaisa; Alonso-Herrero, Almudena; Sales, Dinalva

    2015-01-01

    We investigate the 2D excitation structure of the ISM in a sample of LIRGs and Seyferts using near-IR IFS. This study extends to the near-IR the well-known optical and mid-IR emission line diagnostics used to classify activity in galaxies. Based on the spatially resolved spectroscopy of prototypes, we identify in the [FeII]1.64/Br$\\gamma$ - H_2 1-0S(1)/Br$\\gamma$ plane regions dominated by the different heating sources, i.e. AGNs, young MS massive stars, and evolved stars i.e. supernovae. The ISM in LIRGs occupy a wide region in the near-IR diagnostic plane from -0.6 to +1.5 and from -1.2 to +0.8 (in log units) for the [FeII]/Br$\\gamma$ and H_2/Br$\\gamma$ line ratios, respectively. The corresponding median(mode) ratios are +0.18(0.16) and +0.02(-0.04). Seyferts show on average larger values by factors ~2.5 and ~1.4 for the [FeII]/Br$\\gamma$ and H_2/Br$\\gamma$ ratios, respectively. New areas and relations in the near-IR diagnostic plane are defined for the compact, high surface brightness regions dominated by ...

  20. Verification of Ganoderma (lingzhi) commercial products by Fourier Transform infrared spectroscopy and two-dimensional IR correlation spectroscopy

    Science.gov (United States)

    Choong, Yew-Keong; Sun, Su-Qin; Zhou, Qun; Lan, Jin; Lee, Han-Lim; Chen, Xiang-Dong

    2014-07-01

    Ganoderma commercial products are typically based on two sources, raw material (powder form and/or spores) and extract (water and/or solvent). This study compared three types of Ganoderma commercial products using 1 Dimensional Fourier Transform infrared and second derivative spectroscopy. The analyzed spectra of Ganoderma raw material products were compared with spectra of cultivated Ganoderma raw material powder from different mushroom farms in Malaysia. The Ganoderma extract product was also compared with three types of cultivated Ganoderma extracts. Other medicinal Ganoderma contents in commercial extract product that included glucan and triterpenoid were analyzed by using FTIR and 2DIR. The results showed that water extract of cultivated Ganoderma possessed comparable spectra with that of Ganoderma product water extract. By comparing the content of Ganoderma commercial products using FTIR and 2DIR, product content profiles could be detected. In addition, the geographical origin of the Ganoderma products could be verified by comparing their spectra with Ganoderma products from known areas. This study demonstrated the possibility of developing verification tool to validate the purity of commercial medicinal herbal and mushroom products.

  1. Identification of Edible Vegetable Oil by Two Dimensional Correlation Near- infrared Spectroscopy%二维相关近红外光谱快速鉴别食用植物油种类

    Institute of Scientific and Technical Information of China (English)

    周志琴; 陈斌; 颜辉

    2011-01-01

    Various fatty acids of edible vegetable oil are basically the same or similar, but their concentration distributions are different. The absorption peaks, absorption figures and absorption intensity of one - dimensional near infrared spectra of edible vegetable oils were similar to each other. Several kinds of edible vegetable oils, peanut oil, bean oil, rapeseed oil, sesame oil, oil - tea camellia seed oil and olive oil, were analyzed by two-dimensional correlation near - infrared spectroscopy (2D - NIR). The NIR spectra were measured over a temperature range of 50 ~ 160 ℃, with the rise of temperature, the difference was evident in the map of 2D near - infrared correlation spectroscopy in region 5 500 ~ 6 000 cm-1 . Thus, different kinds of edible vegetable oils could be distinguished directly by autopeaks and crosspeaks. The results proved that the combination of 2D correlation analysis and near - infrared spectroscopy allowed a fast and accurate approach for distinguishing edible vegetable oils.%由于食用植物油中各种脂肪酸的组成基本相同或相近,仅存在含量分布的差异,因此食用植物油的一维近红外光谱图的峰位、峰形、峰强没有明显区别.利用傅里叶变换近红外光谱( FT - NIR)结合二维相关分析技术,分析鉴别了几种不同种类的食用植物油.对花生油、大豆油、菜籽油、芝麻油、油茶籽油和橄榄油,在温度挠动(50~160℃)状态下的动态光谱进行二维相关分析,试验证明6种食用植物油随着温度升高,在5 500 ~6 000 cm-1波段范围内建立的二维相关近红外谱图差异比较明显,凭借二维相关谱图上的自动峰和交叉峰可直观地鉴别不同种类的食用植物油,从而证明了利用二维相关近红外光谱分析技术可快速准确鉴别食用植物油的种类.

  2. Variable-temperature Fourier-transform infrared studies of poly(L-lactic acid) in different states of order: A 2DCOS and PCMW2D analysis

    Science.gov (United States)

    Zhang, Pudun; Unger, Miriam; Pfeifer, Frank; Siesler, Heinz W.

    2016-11-01

    Variable-temperature Fourier-transform infrared (FT-IR) spectra of a predominantly amorphous and a semi-crystalline poly(L-lactic acid) (PLLA) film were measured between 30 °C and 170 °C in order to investigate their temperature-dependent structural changes as a function of the initial state of order. For an in-depth analysis of the spectral variations in the carbonyl stretching band region (1803-1722 cm-1) two-dimensional correlation spectroscopy (2DCOS) and perturbation-correlation moving-window two-dimensional (PCMW2D) analyses were applied. Significant spectral changes were observed during heating of the amorphous PLLA sample whereas the semi-crystalline specimen showed only slight band shifts as a function of the external perturbation. The PCMW2D results suggested that for efficient 2DCOS analyses the heating process should be split up in two temperature intervals. These analyses then provided information on the recrystallization of the amorphous regions, the presence of an intermediate state of order and a sequence scenario for the observed spectral changes.

  3. Tracking the curing process of automotive paint by moving-window two-dimensional infrared correlation spectroscopy and principal component analysis

    Science.gov (United States)

    Chen, Jian-bo; Sun, Su-qin; Yu, Jing; Zhou, Qun

    2014-07-01

    Moving-window two-dimensional correlation spectroscopy (MW2DCOS) and principal component analysis (PCA) were combined to interpret the time serial infrared spectra. The curing process of an automotive paint sample was tracked by attenuated total reflection Fourier transform infrared spectroscopy. Score plots of the first and second principal components showed that the curing process contained three stages. Meanwhile, the loading spectra indicated that the solvent was a mixture of aromatic compounds. Absorption peaks which changed significantly in each stage were revealed by auto-peak MW2DCOS. Furthermore, point-line and point-point MW2DCOS demonstrated the time-resolved relationship between absorption peaks from toluene, xylene and resin. In summary, the evaporation of toluene was the first stage of the curing process of this automotive paint sample. Next, the mixture of o-xylene, m-xylene and p-xylene began to evaporate in the second stage. After the evaporation of the solvent, the solid paint membrane was formed. For the interpretation of the time serial spectra, PCA is useful to estimate the number of significant chemical components and to find out the important turning points of the process, while MW2DCOS can show the changes of the spectral peaks and the relationship between them step by step. The combination of PCA and MW2DCOS is very interesting to extract and display the time-resolved information in the time serial spectra.

  4. Further investigation of the intermolecular interactions and component distributions in a [Bmim][BF4]-based polystyrene composite membranes using two-dimensional correlation infrared spectroscopy.

    Science.gov (United States)

    Shi, Jingya; Wu, Peiyi; Yan, Feng

    2010-07-06

    The intermolecular interaction and distribution of components in [Bmim][BF(4)]-based polystyrene composite membrane which is composed of 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim][BF(4)]), poly(1-(2-methyl acryloyloxyundecyl)-3-methylimidazolium bromide) (poly(MAUM-Br)) and polystyrene is investigated by in situ Fourier transform infrared spectroscopy (FTIR) and two-dimensional correlation infrared spectroscopy (2DIR) in this study. A proposed model about the structure of this composite material is presented, and a sketch map about the local distributions of components is provided. In this model, alkyl chains in [Bmim][BF(4)], poly(MAUM-Br), and polystyrene in this system were supposed to form a polymeric network through aggregation or copolymerization. Cations of ionic liquids separate into the polymer network, while anions are kept mainly through the Coulomb force and partially by the hydrogen bonding between cations and anions. To support this model, FTIR has provided some hints on the pi-pi interaction existing in this complex material between the imidazole ring of ionic liquids and the benzene ring of polystyrene, based on the discovery of the shifts of IR absorption bands assigned to the C-C stretching vibrational mode. The sequential order of the responses from different chemical groups toward the variation of temperature is calculated by 2DIR, and the results suggest how different components distributed in this [Bmim][BF(4)]-based polystyrene composite membrane.

  5. The retrieval of two-dimensional distribution of the earth's surface aerodynamic roughness using SAR image and TM thermal infrared image

    Institute of Scientific and Technical Information of China (English)

    ZHANG; Renhua; WANG; Jinfeng; ZHU; Caiying; SUN; Xiaomin

    2004-01-01

    After having analyzed the requirement on the aerodynamic earth's surface roughness in two-dimensional distribution in the research field of interaction between land surface and atmosphere, this paper presents a new way to calculate the aerodynamic roughness using the earth's surface geometric roughness retrieved from SAR (Synthetic Aperture Radar) and TM thermal infrared image data. On the one hand, the SPM (Small Perturbation Model) was used as a theoretical SAR backscattering model to describe the relationship between the SAR backscattering coefficient and the earth's surface geometric roughness and its dielectric constant retrieved from the physical model between the soil thermal inertia and the soil surface moisture with the simultaneous TM thermal infrared image data and the ground microclimate data. On the basis of the SAR image matching with the TM image, the non-volume scattering surface geometric information was obtained from the SPM model at the TM image pixel scale, and the ground pixel surface's equivalent geometric roughness-height standard RMS (Root Mean Square) was achieved from the geometric information by the transformation of the typical topographic factors. The vegetation (wheat, tree) height retrieved from spectrum model was also transferred into its equivalent geometric roughness. A completely two-dimensional distribution map of the equivalent geometric roughness over the experimental area was produced by the data mosaic technique. On the other hand, according to the atmospheric eddy currents theory, the aerodynamic surface roughness was iterated out with the atmosphere stability correction method using the wind and the temperature profiles data measured at several typical fields such as bare soil field and vegetation field. After having analyzed the effect of surface equivalent geometric roughness together with dynamic and thermodynamic factors on the aerodynamic surface roughness within the working area, this paper first establishes a scale

  6. Two-Dimensional Planetary Surface Lander

    Science.gov (United States)

    Hemmati, H.; Sengupta, A.; Castillo, J.; McElrath, T.; Roberts, T.; Willis, P.

    2014-06-01

    A systems engineering study was conducted to leverage a new two-dimensional (2D) lander concept with a low per unit cost to enable scientific study at multiple locations with a single entry system as the delivery vehicle.

  7. [Study on the effect of temperature on the conformation of cross-linked collagen by two-dimensional infrared correlation spectroscopy].

    Science.gov (United States)

    Chen, Yi-Hui; Tian, Hui-Lin; Li, Ji-Heng; Li, Guo-Ying

    2012-06-01

    The Fourier transform infrared spectroscopy and two dimensional correlation analysis method were applied to study a denaturing process of uncross-linked collagen and cross-linked collagen during varying temperature. It was found that the intensity of typically characteristic absorptions of collagen decreased and its peak shifted to low frequency, The amide II central absorbance peak moved to a lower frequency by about 10 cm(-1), which indicated that the inter-chain hydrogen bonds which stabilized the triple helix conformation of collagen were disrupted during thermal denaturation, resulting in a conformational change. The intensity of auto-peak at 1 515 cm(-1) was maximum, which suggested that the temperature had a big impact on amide II. In comparison with uncross-linked collagen, the intensity of cross-peaks of cross-linked collagen was weaker, which demonstrated that the effect of temperature on the structure of cross-linked collagen was smaller, and the thermal stability properties of collagen solution could be improved by cross-linking. While the order of second structure changes of cross-linked collagen was different. These fundamental data should provide available information for understanding the relationship between the structure and function of cross-linked collagen.

  8. Si-B-C陶瓷涂敷2D C/SiC复合材料的抗氧化性能%Oxidation resistance of two dimensional C/SiC composite coated with Si-B-C ceramic

    Institute of Scientific and Technical Information of China (English)

    左新章; 张立同; 刘永胜; 成来飞; 龚慧灵

    2013-01-01

    Two dimensional C/SiC composite coated with Si-B-C ceramic was prepared via chemical vapor deposition (CVD).Properties and structure evolution and self-healing mechanisms of the C/SiC composite were studied after oxidation for 10 h during 700-1200 ℃.At the same time,the evolution of morphologies,composition and phase for Si-B-C ceramic were also investigated.The experimental results show that the oxidation of Si-B-C ceramic accelerates with the temperature increasing,however,the oxidation scale is shallow and no more than 7 μm.With the temperature increasing,viscosity of borosilicate glass oxidized from Si-B-C ceramic reduces but volatilization accelerates.When the temperature increases to 1200 ℃,SiO2 crystallizes from borosilicate glass.C/SiC composite coated with Si-B-C ceramic shows an excellent oxidation resistance.Mass loss increases with temperature increasing,which is only 0.47% after oxidation for 10 h at 1200 ℃.Furthermore,the strength retention ratio is 91.6% at 1000 ℃,higher than that at other temperatures.The main mechanisms for excellent oxidation resistance of C/SiC composite is that borosilicatc glass oxidized from Si-B-C ceramic can seal cracks in composite effectively.%利用化学气相沉积(CVD)法制备了Si-B-C陶瓷涂敷改性的2D C/SiC复合材料,研究了其在700~1200℃氧化10 h性能和结构的演变规律以及自愈合机制,同时获得了Si-B-C涂层在不同温度氧化后的形貌、组分和物相转变规律.结果表明:涂敷在复合材料表面的Si-B-C陶瓷随温度的升高氧化加快,但氧化程度较低,不深于7μm;随温度的升高,氧化形成的硅硼玻璃黏度降低,挥发增强;当温度达到1200℃时,硅硼玻璃析出SiO2晶体;Si-B-C陶瓷涂敷改性的C/SiC具有优良的抗氧化性能,随氧化温度的升高,复合材料失重率增加,但在1200℃氧化10h后失重率仅为0.47%;此外材料在1000℃氧化后的强度保持率最高,达到91.6%,Si-B-C陶瓷氧化形

  9. The infrared spectrum of the He–C{sub 2}D{sub 2} complex

    Energy Technology Data Exchange (ETDEWEB)

    Moazzen-Ahmadi, N. [Department of Physics and Astronomy, University of Calgary, 2500 University Drive North West, Calgary, Alberta T2N 1N4 (Canada); McKellar, A. R. W. [National Research Council of Canada, Ottawa, Ontario K1A 0R6 (Canada); Fernández, Berta [Department of Physical Chemistry, and Center for Research in Biological Chemistry and Molecular Materials (CIQUS), University of Santiago de Compostela, E-15782 Santiago de Compostela (Spain); Farrelly, David [Department of Chemistry and Biochemistry, Utah State University, Logan, Utah 84322-0300 (United States)

    2015-02-28

    Spectra of the helium-acetylene complex are elusive because this weakly bound system lies close to the free rotor limit. Previously, limited assignments of He–C{sub 2}D{sub 2} transitions in the R(0) region of the ν{sub 3} fundamental band (≈2440 cm{sup −1}) were published. Here, new He–C{sub 2}D{sub 2} infrared spectra of this band are obtained using a tunable optical parametric oscillator laser source to probe a pulsed supersonic slit jet expansion from a cooled nozzle, and the analysis is extended to the weaker and more difficult P(1) and R(1) regions. A term value approach is used to obtain a consistent set of “experimental” energy levels. These are compared directly with calculations using two recently reported ab initio intermolecular potential energy surfaces, which exhibit small but significant differences. Rovibrational energies for the He–C{sub 2}H{sub 2} complex are also calculated using both surfaces. A Coriolis model, useful for predicting spectral intensities, is used to interpret the energy level patterns, and a comparison with the isoelectronic complex He–CO is made.

  10. Two-dimensional cubic convolution.

    Science.gov (United States)

    Reichenbach, Stephen E; Geng, Frank

    2003-01-01

    The paper develops two-dimensional (2D), nonseparable, piecewise cubic convolution (PCC) for image interpolation. Traditionally, PCC has been implemented based on a one-dimensional (1D) derivation with a separable generalization to two dimensions. However, typical scenes and imaging systems are not separable, so the traditional approach is suboptimal. We develop a closed-form derivation for a two-parameter, 2D PCC kernel with support [-2,2] x [-2,2] that is constrained for continuity, smoothness, symmetry, and flat-field response. Our analyses, using several image models, including Markov random fields, demonstrate that the 2D PCC yields small improvements in interpolation fidelity over the traditional, separable approach. The constraints on the derivation can be relaxed to provide greater flexibility and performance.

  11. Two-dimensional subwavelength plasmonic lattice solitons

    CERN Document Server

    Ye, F; Hu, B; Panoiu, N C

    2010-01-01

    We present a theoretical study of plasmonic lattice solitons (PLSs) formed in two-dimensional (2D) arrays of metallic nanowires embedded into a nonlinear medium with Kerr nonlinearity. We analyze two classes of 2D PLSs families, namely, fundamental and vortical PLSs in both focusing and defocusing media. Their existence, stability, and subwavelength spatial confinement are studied in detai

  12. Identification of Adulterated Milk Using Two-dimensional Infrared Correlation Spectroscopy and PARAFACᅳMLR%二维相关红外谱结合PARAFACᅳMLR判别掺杂牛奶

    Institute of Scientific and Technical Information of China (English)

    崔彩路; 杨仁杰; 朱文碧; 杨延荣; 董桂梅; 张伟玉

    2015-01-01

    The discriminant models of adulterated milk and pure milk were constructed using two-dimensional (2D) infrared correlation spectroscopy by PARAFAC and multivariable linear regression (MLR). First, a total of 96 samples including 48 pure milk samples and three types of adulterated milk (16 melamine-tainted milk, 16 urea-tainted milk, and 16 tetracycline-tainted milk) were prepared. The concentration ranges of all adulterants were 0.01~0.30 g⋅L-1. The mid-infrared spectra of all samples were measured in the regions of 900~1 700 cm-1. Then, the synchronous 2D correlation spectra of all samples were calculated in the region between 900~1 200 cm-1 and 1 200~1 700 cm-1. The 2D correlation spectra of all samples were analyzed based on trilinear decomposition using PARAFAC. Finally, the discriminant models for melamine-tainted milk, urea-tainted milk and tetracycline-tainted milk were constructed combined score matrix extracted from 2D correlation spectra using PARAFAC with MLR. The unknown samples were predicted using the constructed models in prediction set. The results show that using a combination of 2D IR correlation spectra and PARAFAC-MLR is an effective analytical method for the classification of adulterated milk and pure milk.%将二维相关红外谱与平行因子、多元线性回归方法相结合,建立了掺杂牛奶与纯牛奶的判别模型。采集48个合格牛奶样品,配置浓度范围均为0.01~0.30 g/L的掺杂三聚氰胺牛奶、掺杂尿素牛奶和掺杂四环素牛奶各16个,并在900~1700 cm-1采集各样品的常规一维谱。对各样品在900~1200 cm-1与1200~1700 cm-1进行同步二维相关计算,构建了纯牛奶与掺杂牛奶的二维红外相关谱。采用平行因子算法对所有样品二维相关谱构成的三维矩阵进行三线性分解,得到其得分矩阵。在此基础上,将其得分矩阵与多元线性回归方法相结合,分别建立了掺杂三聚氰胺牛奶、掺杂尿素牛奶、掺

  13. Local doping of two-dimensional materials

    Science.gov (United States)

    Wong, Dillon; Velasco, Jr, Jairo; Ju, Long; Kahn, Salman; Lee, Juwon; Germany, Chad E.; Zettl, Alexander K.; Wang, Feng; Crommie, Michael F.

    2016-09-20

    This disclosure provides systems, methods, and apparatus related to locally doping two-dimensional (2D) materials. In one aspect, an assembly including a substrate, a first insulator disposed on the substrate, a second insulator disposed on the first insulator, and a 2D material disposed on the second insulator is formed. A first voltage is applied between the 2D material and the substrate. With the first voltage applied between the 2D material and the substrate, a second voltage is applied between the 2D material and a probe positioned proximate the 2D material. The second voltage between the 2D material and the probe is removed. The first voltage between the 2D material and the substrate is removed. A portion of the 2D material proximate the probe when the second voltage was applied has a different electron density compared to a remainder of the 2D material.

  14. VLT/VIMOS integral field spectroscopy of luminous and ultraluminous infrared galaxies: 2D kinematic properties

    CERN Document Server

    Bellocchi, Enrica; Colina, Luis; Miralles-Caballero, Daniel

    2013-01-01

    We present and discuss the 2D kinematic properties of the ionized gas (Halpha) in a sample of 38 local (ultra) luminous infrared galaxies [(U)LIRGs] (31 LIRGs and 7 ULIRGs) observed with VIMOS at the VLT using integral field spectroscopy. This sample covers well the less studied LIRG luminosity range and includes isolated disks, interacting systems, and mergers. The majority of the galaxies have two main kinematically distinct components. One component (i.e., narrow or systemic) extends over the whole line-emitting region and is characterized by small to intermediate velocity dispersions (i.e., sigma from 30 to 160 km s^-1). It traces the overall velocity field. The second component (broad) has in general a larger velocity dispersion (up to 320 km s^-1), mainly found in the inner regions and generally blueshifted with respect to the systemic component. Most of the objects (76%) are dominated by rotation, more relevant in LIRGs than in ULIRGs. Isolated disks, interacting galaxies, and merging systems define a ...

  15. Binding energy of two-dimensional biexcitons

    DEFF Research Database (Denmark)

    Singh, Jai; Birkedal, Dan; Vadim, Lyssenko;

    1996-01-01

    Using a model structure for a two-dimensional (2D) biexciton confined in a quantum well, it is shown that the form of the Hamiltonian of the 2D biexciton reduces into that of an exciton. The binding energies and Bohr radii of a 2D biexciton in its various internal energy states are derived...... analytically using the fractional dimension approach. The ratio of the binding energy of a 2D biexciton to that of a 2D exciton is found to be 0.228, which agrees very well with the recent experimental value. The results of our approach are compared with those of earlier theories....

  16. Study on Identification of Melamine in Milk Based on Two-dimensional Correlation Infrared Spectroscopy%掺杂三聚氰胺牛奶二维相关红外光谱法的鉴别研究

    Institute of Scientific and Technical Information of China (English)

    杨仁杰; 杨延荣; 杜艳红; 常若葵; 张志勇

    2011-01-01

    将红外光谱与二维相关谱技术结合起来对牛奶中掺杂的目标物三聚氰胺进行了检测。配置浓度为3g/L三聚氰胺牛奶溶液,并采集样品在不同温度下的红外光谱图。以温度为外扰,分别构建纯牛奶与掺杂三聚氰胺牛奶的二维相关谱,研究了各自的二维相关特性,并进行对比、分析。结果表明:在14001800cm-1区间内,掺杂三聚氰胺牛奶在同步图上出现3个自相关峰,分别在1448cm-1,1552cm-1和1640cm-1,这三个峰是牛奶中掺杂三聚氰胺的特征吸收。该方法可实现对纯牛奶与掺杂牛奶的正确识别,对提高乳制品的质量和保护消费者的利益具有重要的意义。%In this paper, Fourier transform infrared spectroscopy combined with two-dimensional (2D) correlation spectroscopy was used to investigate the melamine of milk. The sample adulterated with concentration of melamine (3 g/L ) was prepared and the infrared spectra were measured at different temperature. Then the 2D correlation spectroscopy was calculated under the perturbation of temperature. In the range between 1 400 and 1 800 cm-1, three autopeaks were aroused at 1 448 cm-1, 1 552 cm-2 and 1 640 cm-2 in synchronous spectrum, which are the absorbance features of melamine in milk. The method can be used for a correct discrimination on whether the milk is adulterated. The study is important to improve the quality of dairy products and to protect the benefits of consumers.

  17. Two-dimensional photonic crystal surfactant detection.

    Science.gov (United States)

    Zhang, Jian-Tao; Smith, Natasha; Asher, Sanford A

    2012-08-07

    We developed a novel two-dimensional (2-D) crystalline colloidal array photonic crystal sensing material for the visual detection of amphiphilic molecules in water. A close-packed polystyrene 2-D array monolayer was embedded in a poly(N-isopropylacrylamide) (PNIPAAm)-based hydrogel film. These 2-D photonic crystals placed on a mirror show intense diffraction that enables them to be used for visual determination of analytes. Binding of surfactant molecules attaches ions to the sensor that swells the PNIPAAm-based hydrogel. The resulting increase in particle spacing red shifts the 2-D diffracted light. Incorporation of more hydrophobic monomers increases the sensitivity to surfactants.

  18. Conformational analysis of Gly-Ala-NHMe in D2O and DMSO solutions: A two-dimensional infrared spectroscopy study

    DEFF Research Database (Denmark)

    Candelaresi, Marco; Ragnoni, Elena; Cappelli, Chiara

    2013-01-01

    Amide I modes is evaluated from both linear and 2D spectra. The interconversion between the different conformations occurs on time scales longer than the vibrational lifetime, and the spectral diffusion observed in 2D spectra is attributed to the solvent dynamics. Quantum mechanical calculations...

  19. Two-dimensional Kagome photonic bandgap waveguide

    DEFF Research Database (Denmark)

    Nielsen, Jens Bo; Søndergaard, Thomas; Libori, Stig E. Barkou;

    2000-01-01

    The transverse-magnetic photonic-bandgap-guidance properties are investigated for a planar two-dimensional (2-D) Kagome waveguide configuration using a full-vectorial plane-wave-expansion method. Single-moded well-localized low-index guided modes are found. The localization of the optical modes...... is investigated with respect to the width of the 2-D Kagome waveguide, and the number of modes existing for specific frequencies and waveguide widths is mapped out....

  20. Piezoelectricity in Two-Dimensional Materials

    KAUST Repository

    Wu, Tao

    2015-02-25

    Powering up 2D materials: Recent experimental studies confirmed the existence of piezoelectricity - the conversion of mechanical stress into electricity - in two-dimensional single-layer MoS2 nanosheets. The results represent a milestone towards embedding low-dimensional materials into future disruptive technologies. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA.

  1. A two-dimensional Dirac fermion microscope

    DEFF Research Database (Denmark)

    Bøggild, Peter; Caridad, Jose; Stampfer, Christoph

    2017-01-01

    in the solid state. Here we provide a perspective view on how a two-dimensional (2D) Dirac fermion-based microscope can be realistically implemented and operated, using graphene as a vacuum chamber for ballistic electrons. We use semiclassical simulations to propose concrete architectures and design rules of 2...

  2. Two-dimensional calculus

    CERN Document Server

    Osserman, Robert

    2011-01-01

    The basic component of several-variable calculus, two-dimensional calculus is vital to mastery of the broader field. This extensive treatment of the subject offers the advantage of a thorough integration of linear algebra and materials, which aids readers in the development of geometric intuition. An introductory chapter presents background information on vectors in the plane, plane curves, and functions of two variables. Subsequent chapters address differentiation, transformations, and integration. Each chapter concludes with problem sets, and answers to selected exercises appear at the end o

  3. Two dimensional vernier

    Science.gov (United States)

    Juday, Richard D. (Inventor)

    1992-01-01

    A two-dimensional vernier scale is disclosed utilizing a cartesian grid on one plate member with a polar grid on an overlying transparent plate member. The polar grid has multiple concentric circles at a fractional spacing of the spacing of the cartesian grid lines. By locating the center of the polar grid on a location on the cartesian grid, interpolation can be made of both the X and Y fractional relationship to the cartesian grid by noting which circles coincide with a cartesian grid line for the X and Y direction.

  4. Two-dimensional heterostructures for energy storage

    Science.gov (United States)

    Pomerantseva, Ekaterina; Gogotsi, Yury

    2017-07-01

    Two-dimensional (2D) materials provide slit-shaped ion diffusion channels that enable fast movement of lithium and other ions. However, electronic conductivity, the number of intercalation sites, and stability during extended cycling are also crucial for building high-performance energy storage devices. While individual 2D materials, such as graphene, show some of the required properties, none of them can offer all properties needed to maximize energy density, power density, and cycle life. Here we argue that stacking different 2D materials into heterostructured architectures opens an opportunity to construct electrodes that would combine the advantages of the individual building blocks while eliminating the associated shortcomings. We discuss characteristics of common 2D materials and provide examples of 2D heterostructured electrodes that showed new phenomena leading to superior electrochemical performance. We also consider electrode fabrication approaches and finally outline future steps to create 2D heterostructured electrodes that could greatly expand current energy storage technologies.

  5. The roles of carbohydrates, proteins and lipids in the process of aggregation of natural marine organic matter investigated by means of 2D correlation spectroscopy applied to infrared spectra

    Science.gov (United States)

    Mecozzi, Mauro; Pietrantonio, Eva; Pietroletti, Marco

    2009-01-01

    In this paper the marine organic matter soluble in an alkaline medium called extractable humic substance (EHS), was extracted from three sediment samples of Tyrrhenian Sea and separated by precipitation at pH 2 in the two fractions of fulvic acids (FAs) and humic acids (HAs). FAs were further fractionated in seven sub-samples of different molecular weight (mw) by means of seven different ultrafiltration membranes operating in the range between mw 100 kDa. Then the qualitative composition of each sample of fractionated FAs and HAs was studied by means of one-dimensional Fourier transform infrared spectroscopy in reflectance mode (FTIR-DRIFT) and by two-dimensional (2D) correlation spectroscopy both in wavelength-wavelength (WW) and in sample-sample (SS) mode. The application of 2D correlation WW spectroscopy allows to elucidate the different roles played by carbohydrates and proteins with respect to some lipid compounds such as fatty acids and ester fatty acids during the process of aggregate formations from mw ˜1 kDa to higher size aggregates. In addition, 2D correlation WW spectroscopy allows to observe some peculiar interactions between carbohydrates and proteins in the formation of EHS aggregates, interactions which vary from a sample to another sample. The results of 2D correlation SS spectroscopy confirm the general evidences obtained by 2D WW spectroscopy and moreover, they also describe the formation of EHS aggregates as a complex process where evolutionary links and connectivity between aggregates of neighbour molecular size ranges are not evident. Two-dimensional correlation spectroscopy applied to FTIR spectroscopy shows to be a powerful tool for the investigation of the mechanisms involved in EHS aggregation because it supports the acquisition of structural information which sometimes can be hardly obtained by one-dimensional FTIR spectroscopy.

  6. Design and fabrication of rod-type two-dimensional photonic crystal slabs with large high-order bandgaps in near-infrared wavelengths.

    Science.gov (United States)

    Jiang, Liyong; Jia, Wei; Zheng, Gaige; Li, Xiangyin

    2012-05-01

    We proposed a novel two-dimensional photonic crystal slab comprised of a number of silicon rods with different radii and locations in the square-lattice unit cell pattern. Such rod-type photonic crystal slabs were automatically optimized by the genetic algorithm and fabricated on the silicon-on-insulator wafer. In particular, the measured transmission spectra of the five-rods sample have shown a large accepted high-order bandgap between 1498 and 1648 nm (gap size is 9.54%). Based on the theories of multiple Bragg and Mie scattering effects, we have given a reasonable explanation to the large high-order bandgaps found in the present study.

  7. Evidence for Intramolecular Antiparallel Beta-Sheet Structure in Alpha-Synuclein Fibrils from a Combination of Two-Dimensional Infrared Spectroscopy and Atomic Force Microscopy

    NARCIS (Netherlands)

    Roeters, Steven J.; Iyer, Aditya; Pletikapic, Galja; Kogan, Vladimir; Subramaniam, Vinod; Woutersen, Sander

    2017-01-01

    The aggregation of the intrinsically disordered protein alpha-synuclein (αS) into amyloid fibrils is thought to play a central role in the pathology of Parkinson’s disease. Using a combination of techniques (AFM, UV-CD, XRD, and amide-I 1D- and 2D-IR spectroscopy) we show that the structure of αS fi

  8. Two-dimensional x-ray diffraction

    CERN Document Server

    He, Bob B

    2009-01-01

    Written by one of the pioneers of 2D X-Ray Diffraction, this useful guide covers the fundamentals, experimental methods and applications of two-dimensional x-ray diffraction, including geometry convention, x-ray source and optics, two-dimensional detectors, diffraction data interpretation, and configurations for various applications, such as phase identification, texture, stress, microstructure analysis, crystallinity, thin film analysis and combinatorial screening. Experimental examples in materials research, pharmaceuticals, and forensics are also given. This presents a key resource to resea

  9. Two-dimensional optical spectroscopy

    CERN Document Server

    Cho, Minhaeng

    2009-01-01

    Discusses the principles and applications of two-dimensional vibrational and optical spectroscopy techniques. This book provides an account of basic theory required for an understanding of two-dimensional vibrational and electronic spectroscopy.

  10. Two-Dimensional Electrons.

    Science.gov (United States)

    2014-09-26

    Isihara and Y. Nalane, Elementary Excitations and Energy Dispersion in TTF-TCNQ;Proc. Internat. Conf. on Phys. and Chem. of Low-Dimen. Syn. Conductors ...Abano Terme, Molec. Crys. Liq. Crys. 120, 85 (1984). One-dimensiona4 conductors such as TTF-TCNQ are attracting considerable attention for their...A. Isihara and Y. Nakane; Magnetoconductivity of 2D Conductors ; Proc. Internat. Conf. on Phys. and Chem. of Low-Dimen. Syn. Conductors , Abano Terme

  11. The methyl C-H blueshift in N,N-dimethylformamide-water mixtures probed by two-dimensional Fourier-transform infrared spectroscopy.

    Science.gov (United States)

    Xu, Zheng; Li, Haoran; Wang, Congmin; Pan, Haihua; Han, Shijun

    2006-06-28

    Two-dimensional correlation spectroscopy was used to study the composition-dependent spectral variations of the CH-stretching bands of N,N-dimethylformamide (DMF)-water mixtures with X(DMF) ranging from 0.98 to 0.60. By a detailed correlation analysis of the spectral changes of the CH- and OH-stretching bands, it is found that the intensities of the CH and OH bands change in different ways when the water content is increased. It is also found that two different regions of the water content can be distinguished, in which the intensity changes have different signatures. A tentative explanation for how these phenomena might be related to structural changes in the mixture is proposed. The structural change of DMF induced by the water hydrogen bonded on the carbonyl group is supposed to be the possible origin of the methyl C-H blueshift instead of the direct C-H...O interactions before the hydrophobic hydration takes place.

  12. Analysis of directional dependence of the two-dimensional array of detectors 2D array seven 29 implications in the planning system; Analisis de la dependencia direcccional de la matriz bidimensional de detectores 2D array seven29. Implicaciones en el sistema de planificacion

    Energy Technology Data Exchange (ETDEWEB)

    Mora Melendez, R.; Seguro Fernandez, A.; Iborra Oquendo, M.; Urena Llinares, A.

    2013-07-01

    The main objective of our study is to find correction factors dependent on the 2D array incidence angles, and to give account of the phenomenon, allowing the Planner to faithfully reproduce data and curves measured experimentally. (Author)

  13. Comparative analysis between two-dimensional (2D) and three-dimensional (3D) MRI acquisitions - clinical applications for the evaluation of the knees in juvenile rheumatoid arthritis (JRA); Analise comparativa entre aquisicao tri (3D) e bidimensional (2D) em ressonancia magnetica - aplicabilidade clinica em joelhos em artrite reumatoide juvenil (ARJ)

    Energy Technology Data Exchange (ETDEWEB)

    Doria, Andre S. [Hospital das Clinicas, Sao Paulo, SP (Brazil). Inst. de Radiologia; Rebelo, Marina de Sa [Hospital das Clinicas, Sao Paulo, SP (Brazil). Instituto do Coracao. Servico de Informatica; Castro, Claudio Campi de [Hospital das Clinicas, Sao Paulo, SP (Brazil). Instituto do Coracao. Servico de Ressonancia Magnetica] [and others

    2000-06-01

    In this cross-sectional study in patients with juvenile rheumatoid arthritis the authors compare two-dimensional evaluation of the maximum synovial diameter on post-contrast axial T1-weighted SE (spin-echo) sequences with volumetric (three-dimensional assessment) on post-contrast axial T1-weighted SPIR (spectral presaturation with inversion recovery) SE sequences. With the aim of determining their cost-effectiveness these two methods of assessment were compared to clinical and laboratorial parameters, as well as the presence of synovial enhancement seen on magnetic resonance imaging. (author)

  14. Two-dimensional effects in nonlinear Kronig-Penney models

    DEFF Research Database (Denmark)

    Gaididei, Yuri Borisovich; Christiansen, Peter Leth; Rasmussen, Kim

    1997-01-01

    An analysis of two-dimensional (2D) effects in the nonlinear Kronig-Penney model is presented. We establish an effective one-dimensional description of the 2D effects, resulting in a set of pseudodifferential equations. The stationary states of the 2D system and their stability is studied...

  15. Energy Transfer Between Coherently Delocalized States in Thin Films of the Explosive Pentaerythritol Tetranitrate (PETN) Revealed by Two-Dimensional Infrared Spectroscopy.

    Science.gov (United States)

    Ostrander, Joshua S; Knepper, Robert; Tappan, Alexander S; Kay, Jeffrey J; Zanni, Martin T; Farrow, Darcie A

    2017-02-16

    Pentaerythritol tetranitrate (PETN) is a common secondary explosive and has been used extensively to study shock initiation and energy propagation in energetic materials. We report 2D IR measurements of PETN thin films that resolve vibrational energy transfer and relaxation mechanisms. Ultrafast anisotropy measurements reveal a sub-500 fs reorientation of transition dipoles in thin films of vapor-deposited PETN that is absent in solution measurements, consistent with intermolecular energy transfer. The anisotropy is frequency dependent, suggesting spectrally heterogeneous vibrational relaxation. Cross peaks are observed in 2D IR spectra that resolve a specific energy transfer pathway with a 2 ps time scale. Transition dipole coupling calculations of the nitrate ester groups in the crystal lattice predict that the intermolecular couplings are as large or larger than the intramolecular couplings. The calculations match well with the experimental frequencies and the anisotropy, leading us to conclude that the observed cross peak is measuring energy transfer between two eigenstates that are extended over multiple PETN molecules. Measurements of the transition dipole strength indicate that these vibrational modes are coherently delocalized over at least 15-30 molecules. We discuss the implications of vibrational relaxation between coherently delocalized eigenstates for mechanisms relevant to explosives.

  16. A two-dimensional Dirac fermion microscope

    Science.gov (United States)

    Bøggild, Peter; Caridad, José M.; Stampfer, Christoph; Calogero, Gaetano; Papior, Nick Rübner; Brandbyge, Mads

    2017-06-01

    The electron microscope has been a powerful, highly versatile workhorse in the fields of material and surface science, micro and nanotechnology, biology and geology, for nearly 80 years. The advent of two-dimensional materials opens new possibilities for realizing an analogy to electron microscopy in the solid state. Here we provide a perspective view on how a two-dimensional (2D) Dirac fermion-based microscope can be realistically implemented and operated, using graphene as a vacuum chamber for ballistic electrons. We use semiclassical simulations to propose concrete architectures and design rules of 2D electron guns, deflectors, tunable lenses and various detectors. The simulations show how simple objects can be imaged with well-controlled and collimated in-plane beams consisting of relativistic charge carriers. Finally, we discuss the potential of such microscopes for investigating edges, terminations and defects, as well as interfaces, including external nanoscale structures such as adsorbed molecules, nanoparticles or quantum dots.

  17. A two-dimensional Dirac fermion microscope.

    Science.gov (United States)

    Bøggild, Peter; Caridad, José M; Stampfer, Christoph; Calogero, Gaetano; Papior, Nick Rübner; Brandbyge, Mads

    2017-06-09

    The electron microscope has been a powerful, highly versatile workhorse in the fields of material and surface science, micro and nanotechnology, biology and geology, for nearly 80 years. The advent of two-dimensional materials opens new possibilities for realizing an analogy to electron microscopy in the solid state. Here we provide a perspective view on how a two-dimensional (2D) Dirac fermion-based microscope can be realistically implemented and operated, using graphene as a vacuum chamber for ballistic electrons. We use semiclassical simulations to propose concrete architectures and design rules of 2D electron guns, deflectors, tunable lenses and various detectors. The simulations show how simple objects can be imaged with well-controlled and collimated in-plane beams consisting of relativistic charge carriers. Finally, we discuss the potential of such microscopes for investigating edges, terminations and defects, as well as interfaces, including external nanoscale structures such as adsorbed molecules, nanoparticles or quantum dots.

  18. Mobility anisotropy of two-dimensional semiconductors

    CERN Document Server

    Lang, Haifeng; Liu, Zhirong

    2016-01-01

    The carrier mobility of anisotropic two-dimensional (2D) semiconductors under longitudinal acoustic (LA) phonon scattering was theoretically studied with the deformation potential theory. Based on Boltzmann equation with relaxation time approximation, an analytic formula of intrinsic anisotropic mobility was deduced, which shows that the influence of effective mass to the mobility anisotropy is larger than that of deformation potential constant and elastic modulus. Parameters were collected for various anisotropic 2D materials (black phosphorus, Hittorf's phosphorus, BC$_2$N, MXene, TiS$_3$, GeCH$_3$) to calculate their mobility anisotropy. It was revealed that the anisotropic ratio was overestimated in the past.

  19. Quality Analysis of Powdered Milk by Two Dimensional Correlation Infrared Spectroscopy%二维相关红外光谱与奶粉的品质分析

    Institute of Scientific and Technical Information of China (English)

    秦竹; 许长华; 周群; 王晶; 方向; 孙素琴

    2004-01-01

    采用红外光谱法(FT-IR)并结合二阶导数谱对几种奶粉产品进行了无损快速鉴别.结果表明:不同脂肪含量的奶粉其最主要的差别直观地表现在1747 cm-1对应的脂肪CO吸收峰强度的不同;同理,不同糖含量的奶粉红外谱图上的主要差别就体现在糖的特征峰带(1150~900 cm-1)的强度上.最后,采用二维相关红外光谱法(2D-IR)对全脂奶粉和全脂甜奶粉进行了热扰动过程研究,发现由于糖类物质的加入,奶粉蛋白成分在常温下变得相对稳定.该法为研究奶粉的稳定性提供了一条新的途径.

  20. Elucidation of Chemical Reactions by Two-Dimensional Resonance Raman Spectroscopy

    Science.gov (United States)

    Moran, Andrew

    Two-dimensional (2D) Raman spectroscopies were proposed by Mukamel and Loring in1985 as a method for resolving line broadening mechanisms of vibrational motions in liquids. Significant technical issues challenged the development of both five- and seven-pulse 2D Raman spectroscopies. For this reason, 2D Raman experiments were largely abandoned in 2002 following the first demonstrations of 2D infrared spectroscopies (i.e., an alternate approach for obtaining similar information). We have recently shown that 2D Raman experiments conducted under electronically resonant conditions are much less susceptible to the problems encountered in the earlier 2D Raman work, which was carried out off-resonance. In effect, Franck-Condon activity obviates the problematic selection rules encountered under electronically off-resonant conditions. In this presentation, I will discuss applications of 2D resonance Raman spectroscopies to photodissocation reactions of triiodide and myoglobin. It will be shown that vibrational resonances of the reactants and products can be displayed in separate dimensions of a 2D resonance Raman spectrum when the photo-dissociation reaction is fast compared to the vibrational period. Such 2D spectra expose correlations between the nonequilibrium geometry of the reactant and the distribution of vibrational quanta in the product, thereby yielding insight in the photo-dissociation mechanism. Our results suggest that the ability of 2D resonance Raman spectroscopy to detect correlations between reactants and products will generalize to other ultrafast processes such as electron transfer and energy transfer.

  1. Evidence for Intramolecular Antiparallel Beta-Sheet Structure in Alpha-Synuclein Fibrils from a Combination of Two-Dimensional Infrared Spectroscopy and Atomic Force Microscopy

    Science.gov (United States)

    Roeters, Steven J.; Iyer, Aditya; Pletikapić, Galja; Kogan, Vladimir; Subramaniam, Vinod; Woutersen, Sander

    2017-01-01

    The aggregation of the intrinsically disordered protein alpha-synuclein (αS) into amyloid fibrils is thought to play a central role in the pathology of Parkinson’s disease. Using a combination of techniques (AFM, UV-CD, XRD, and amide-I 1D- and 2D-IR spectroscopy) we show that the structure of αS fibrils varies as a function of ionic strength: fibrils aggregated in low ionic-strength buffers ([NaCl] ≤ 25 mM) have a significantly different structure than fibrils grown in higher ionic-strength buffers. The observations for fibrils aggregated in low-salt buffers are consistent with an extended conformation of αS molecules, forming hydrogen-bonded intermolecular β-sheets that are loosely packed in a parallel fashion. For fibrils aggregated in high-salt buffers (including those prepared in buffers with a physiological salt concentration) the measurements are consistent with αS molecules in a more tightly-packed, antiparallel intramolecular conformation, and suggest a structure characterized by two twisting stacks of approximately five hydrogen-bonded intermolecular β-sheets each. We find evidence that the high-frequency peak in the amide-I spectrum of αS fibrils involves a normal mode that differs fundamentally from the canonical high-frequency antiparallel β-sheet mode. The high sensitivity of the fibril structure to the ionic strength might form the basis of differences in αS-related pathologies.

  2. Nonlocal bottleneck effect in two-dimensional turbulence

    CERN Document Server

    Biskamp, D; Schwarz, E

    1998-01-01

    The bottleneck pileup in the energy spectrum is investigated for several two-dimensional (2D) turbulence systems by numerical simulation using high-order diffusion terms to amplify the effect, which is weak for normal diffusion. For 2D magnetohydrodynamic (MHD) turbulence, 2D electron MHD (EMHD) turbulence and 2D thermal convection, which all exhibit direct energy cascades, a nonlocal behavior is found resulting in a logarithmic enhancement of the spectrum.

  3. Detection of Melamine in Milk by Two-dimensional Near-infrared Correlation Spectroscopy%二维相关近红外光谱检测牛奶中的三聚氰胺

    Institute of Scientific and Technical Information of China (English)

    刘蓉; 杨仁杰; 徐可欣

    2013-01-01

    20 pure milk samples and 20 adulterated milk samples with different mass concentration of melamine(0. 01~3 g/L) were prepared and their near infrared spectra were collected. The two-dimensional correlation spectra were calculated under the perturbation of adulteration concentration. The characteristics of two-dimensional correlation spectra of adulterated milk were studied. Partial least squares discriminate analysis (PLS-DA) was applied to differentiate the pure milk samples and the adulterated milk samples. The classification accuracy was 100%. At the same time, the model for quantitative analysis of melamine concentration in the adulterated milk samples was constructed by partial least square (PLS) combined with two-dimensional near infrared correction spectra. Results showed that the root mean square error of prediction (RMSEP) was 0. 18 g/L. The correlation coefficient between reference values and predicted values was 0. 98. The method does not rely on sample separation, and provides alternative way to detect the adulterant of milk.%配置合格的纯牛奶样本及含有三聚氰胺质量浓度范围为0.01 g/L~3 g/L的掺杂牛奶样本各20个,并采集其近红外光谱.以牛奶中掺杂三聚氰胺浓度为外扰,构建二维相关同步谱,研究其相关谱特性.在此基础上,结合偏最小二乘判别分析法(PLS-DA)建立定性模型,可以实现纯牛奶与掺伪牛奶的定性鉴别,正确识别率达100%.同时,将二维相关近红外同步谱矩阵与偏最小二乘法(PLS)结合起来,建立定量分析牛奶中掺杂三聚氰胺的数学模型.对未知样品的预测相关系数R达到0.98,预测均方根误差(RM-SEP)为0.18 g/L,说明基于同步相关谱矩阵建立定量分析的数学模型是可行的.该方法无需样品处理,成本低,为快速检测掺伪牛奶提供了一种新的途径.

  4. Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films.

    Science.gov (United States)

    Halim, Joseph; Lukatskaya, Maria R; Cook, Kevin M; Lu, Jun; Smith, Cole R; Näslund, Lars-Åke; May, Steven J; Hultman, Lars; Gogotsi, Yury; Eklund, Per; Barsoum, Michel W

    2014-04-08

    Since the discovery of graphene, the quest for two-dimensional (2D) materials has intensified greatly. Recently, a new family of 2D transition metal carbides and carbonitrides (MXenes) was discovered that is both conducting and hydrophilic, an uncommon combination. To date MXenes have been produced as powders, flakes, and colloidal solutions. Herein, we report on the fabrication of ∼1 × 1 cm(2) Ti3C2 films by selective etching of Al, from sputter-deposited epitaxial Ti3AlC2 films, in aqueous HF or NH4HF2. Films that were about 19 nm thick, etched with NH4HF2, transmit ∼90% of the light in the visible-to-infrared range and exhibit metallic conductivity down to ∼100 K. Below 100 K, the films' resistivity increases with decreasing temperature and they exhibit negative magnetoresistance-both observations consistent with a weak localization phenomenon characteristic of many 2D defective solids. This advance opens the door for the use of MXenes in electronic, photonic, and sensing applications.

  5. Synthesis, structure and near-infrared luminescence of a new 2D praseodymium(Ⅲ) coordination polymer

    Institute of Scientific and Technical Information of China (English)

    LIU Guangxiang; ZHOU Hong; REN Xiaoming

    2011-01-01

    A novel coordination polymer,[Pr2(BIPA)3(H2O)2]·2H2O (1) (H2BIPA=5-bromoisophthalic acid),was prepared by hydrothermal synthesis and characterized by IR spectroscopy,elemental analysis and single-crystal X-ray diffraction.The crystal was of monoclinic system,space group C2/c,with a=1.98037(14),b=1.44189(14),c=2.15281(18) nm,β=95.220(2)°,V=6.1218(9) nm3,C24H17Br3O16Pr2,Mr=1082.93,De=2.350 g/cm3,F(000)=4096,μ=7.136 mm-1 and Z=8.The final R 1=0.0608 and wR2=0.1371 for 5624 observed reflections ((I)>2σ((I))).Complex 1 featured an interesting 2D layer containing {Pr2(CO2)3}n right-handed and left-handed helical chains.Furthermore,hydrogen bonds linked the adjacent 2D layers to form a 3D supramolecular framework.Moreover,the near-infrared luminescent properties of 1 were also investigated in the solid state.

  6. Rationally synthesized two-dimensional polymers.

    Science.gov (United States)

    Colson, John W; Dichtel, William R

    2013-06-01

    Synthetic polymers exhibit diverse and useful properties and influence most aspects of modern life. Many polymerization methods provide linear or branched macromolecules, frequently with outstanding functional-group tolerance and molecular weight control. In contrast, extending polymerization strategies to two-dimensional periodic structures is in its infancy, and successful examples have emerged only recently through molecular framework, surface science and crystal engineering approaches. In this Review, we describe successful 2D polymerization strategies, as well as seminal research that inspired their development. These methods include the synthesis of 2D covalent organic frameworks as layered crystals and thin films, surface-mediated polymerization of polyfunctional monomers, and solid-state topochemical polymerizations. Early application targets of 2D polymers include gas separation and storage, optoelectronic devices and membranes, each of which might benefit from predictable long-range molecular organization inherent to this macromolecular architecture.

  7. Two-Dimensional Plasmonics in Massive and Massless Electron Gases

    Science.gov (United States)

    Yoon, Hosang

    Plasmonic waves in solid-state are caused by collective oscillation of mobile charges inside or at the surface of conductors. In particular, surface plasmonic waves propagating at the skin of metals have recently attracted interest, as they reduce the wavelength of electromagnetic waves coupled to them by up to ˜10 times, allowing one to create miniaturized wave devices at optical frequencies. In contrast, plasmonic waves on two-dimensional (2D) conductors appear at much lower infrared and THz-GHz frequencies, near or in the electronics regime, and can achieve far stronger wavelength reduction factor reaching well above 100. In this thesis, we study the unique machinery of 2D plasmonic waves behind this ultra-subwavelength confinement and explore how it can be used to create various interesting devices. To this end, we first develop a physically intuitive theoretical formulation of 2D plasmonic waves, whose two main components---the Coulomb restoration force and inertia of the collectively oscillating charges---are combined into a transmission-line-like model. We then use this formulation to create various ultra-subwavelength 2D plasmonic devices. For the 2D conductor, we first choose GaAs/AlGaAs heterostructure---a 2D electron gas consisting of massive (m* > 0) electrons---demonstrating plasmonic bandgap crystals, interferometers, and negatively refracting metamaterials. We then examine a 2D plasmonic device based on graphene, a 2D electron gas consisting of effectively massless (m* = 0) electrons. We theoretically show and experimentally demonstrate that the massless electrons in graphene can surprisingly exhibit a collective mass when subjected to a collective excitation, providing the inertia that is essential for the propagation of 2D plasmonic waves. Lastly, we theoretically investigate the thermal current fluctuation behaviors in massive and massless electron gases. While seemingly unrelated on first sight, we show that the thermal current fluctuation is

  8. Two-Dimensional Mesoscale-Ordered Conducting Polymers

    NARCIS (Netherlands)

    Liu, Shaohua; Zhang, Jian; Dong, Renhao; Gordiichuk, Pavlo; Zhang, Tao; Zhuang, Xiaodong; Mai, Yiyong; Liu, Feng; Herrmann, Andreas; Feng, Xinliang

    2016-01-01

    Despite the availability of numerous two-dimensional (2D) materials with structural ordering at the atomic or molecular level, direct construction of mesoscale-ordered superstructures within a 2D monolayer remains an enormous challenge. Here, we report the synergic manipulation of two types of assem

  9. Two-Dimensional Mesoscale-Ordered Conducting Polymers

    NARCIS (Netherlands)

    Liu, Shaohua; Zhang, Jian; Dong, Renhao; Gordiichuk, Pavlo; Zhang, Tao; Zhuang, Xiaodong; Mai, Yiyong; Liu, Feng; Herrmann, Andreas; Feng, Xinliang

    2016-01-01

    Despite the availability of numerous two-dimensional (2D) materials with structural ordering at the atomic or molecular level, direct construction of mesoscale-ordered superstructures within a 2D monolayer remains an enormous challenge. Here, we report the synergic manipulation of two types of

  10. Forensic potential of comprehensive two-dimensional gas chromatography

    NARCIS (Netherlands)

    Sampat, A.; Lopatka, M.; Sjerps, M.; Vivo-Truyols, G.; Schoenmakers, P.; van Asten, A.

    2016-01-01

    In this study, the application of comprehensive two-dimensional (2D) gas chromatography (GC × GC) in forensic science is reviewed. The peer-reviewed publications on the forensic use of GC × GC and 2D gas chromatography with mass spectrometric detection (GC × GC-MS) have been studied in detail, not o

  11. Forensic potential of comprehensive two-dimensional gas chromatography

    NARCIS (Netherlands)

    Sampat, A.; Lopatka, M.; Sjerps, M.; Vivo-Truyols, G.; Schoenmakers, P.; van Asten, A.

    2016-01-01

    In this study, the application of comprehensive two-dimensional (2D) gas chromatography (GC × GC) in forensic science is reviewed. The peer-reviewed publications on the forensic use of GC × GC and 2D gas chromatography with mass spectrometric detection (GC × GC-MS) have been studied in detail, not o

  12. Impact of geometry parameters on the thrust and infrared radiation characteristics of two-dimensional ejector nozzle%二元引射喷管几何特征参数对推力及红外特性的影响

    Institute of Scientific and Technical Information of China (English)

    刘福城; 吉洪湖; 林兰之; 黄伟; 刘常春; 斯仁

    2011-01-01

    采用数值模拟的方法研究了二元引射喷管间距比变化和面积比变化对推力特性和3~5μm波段红外辐射特性的影响.排气系统的流场采用了商用软件计算,红外辐射特征采用了自主开发的软件(NU-AA-IR)进行计算.结果表明:间距比变化和面积比变化对二元引射喷管的推力系数和引射流量比有不同程度的影响.在小方向角范围内,间距比和面积比的变化对宽边探测平面上的积分辐射强度影响较大,最大降幅为30%左右,而对窄边探测平面上的积分辐射强度影响较小;二元引射喷管相对于二元喷管的红外辐射特性最大降幅为50%左右.%The thrust and infrared radiation (IR) characteristics in the waveband of 3 ~ 5 μm of two-dimensional (2-D) ejector nozzle were studied numerically. The flow field of the exhaust jet was calculated with commercial software. The infrared radiation characteristics were calculated with an IR analysis software (NUAA-IR) developed by our research group. The results show that spacing ratio and area ratio have different impacts on the thrust ratio and mass-flow ratio of the 2-D ejector nozzle. Spacing ratio and area ratio have greater impact on wide detected plane within a small azimuth angles. In relation to a 2-D nozzle, the integral IR intensity of a 2-D ejector nozzle can be reduced about 50%.

  13. TreePM Method for Two-Dimensional Cosmological Simulations

    Indian Academy of Sciences (India)

    Suryadeep Ray

    2004-09-01

    We describe the two-dimensional TreePM method in this paper. The 2d TreePM code is an accurate and efficient technique to carry out large two-dimensional N-body simulations in cosmology. This hybrid code combines the 2d Barnes and Hut Tree method and the 2d Particle–Mesh method. We describe the splitting of force between the PM and the Tree parts. We also estimate error in force for a realistic configuration. Finally, we discuss some tests of the code.

  14. Theory of two-dimensional transformations

    OpenAIRE

    Kanayama, Yutaka J.; Krahn, Gary W.

    1998-01-01

    The article of record may be found at http://dx.doi.org/10.1109/70.720359 Robotics and Automation, IEEE Transactions on This paper proposes a new "heterogeneous" two-dimensional (2D) transformation group ___ to solve motion analysis/planning problems in robotics. In this theory, we use a 3×1 matrix to represent a transformation as opposed to a 3×3 matrix in the homogeneous formulation. First, this theory is as capable as the homogeneous theory, Because of the minimal size, its implement...

  15. [Progress in Application of Two-Dimensional Correlation Spectroscopy for Detection of Food Quality].

    Science.gov (United States)

    Yang, Ren-jie; Yang, Yan-rong; Liu, Hai-xue; Dong, Gui-mei; Du, Yan-hong; Shan, Hui-yong; Zhang, Wei-yu

    2015-08-01

    In recent years, the food safety and quality has always been a serious issue. Therefore, it is urgent to develop a rapid and widely available method to determine the quality of food. Due to high spectral resolution, good spectral selectivity and good ability of spectrogram analysis, the technology of two-dimensional (2D) correlation spectroscopy is an effective method for solving three major problems encountered by the conventional one-dimensional (1D) spectrum: low selectivity of the spectra, difficulty in extracting the information of the spectral feature and difficulty in spectrogram analysis. Therefore, 2D correlation spectroscopy, which is suited to distinguish similar samples hardly distinguished by the conventional 1D spectroscopy, has been successfully applied in many complex biological systems. The developmental process, the experimental way to obtain spectrum, the fundamental mathematical principle and the properties of 2D correlation spectroscopy were introduced in this paper. At the same time, it is pointed out that the origin of weak characteristic bands of substance can be verified in terms of the positive or negative corss peaks in synchronous 2D correlation spectrum combined with the existence or inexistence of corss peaks in asynchronous 2D correlation spectrum. The application of 2D near-infrared, mid-infrared, fluorescence, and raman correlation spectroscopy in the detection of food quality and adulteration, concentrated specifically on diary product, wine, oil, meat, honey, and rice were reviewed. Finally, the limitations and future development prospects were pointed out.

  16. Long-Wavelength Infrared Surface Plasmons on Ga-Doped ZnO Films Excited via 2D Hole Arrays for Extraordinary Optical Transmission (Preprint)

    Science.gov (United States)

    2013-10-01

    AFRL-RY-WP-TP-2013-0180 LONG-WAVELENGTH INFRARED SURFACE PLASMONS ON Ga- DOPED ZnO FILMS EXCITED VIA 2D HOLE ARRAYS FOR EXTRAORDINARY OPTICAL...TITLE AND SUBTITLE LONG-WAVELENGTH INFRARED SURFACE PLASMONS ON Ga- DOPED ZnO FILMS EXCITED VIA 2D HOLE ARRAYS FOR EXTRAORDINARY OPTICAL TRANSMISSION...structure size such as period. Pulse laser deposited Ga- doped ZnO has been shown to have fluctuations in optical and electrical parameters based on

  17. Symmetric two dimensional photonic crystal coupled waveguide with point defect for optical switch application

    CERN Document Server

    Hardhienata, Hendradi

    2012-01-01

    Two dimensional (2D) photonic crystals are well known for its ability to manipulate the propagation of electromagnetic wave inside the crystal. 1D and 2D photonic crystals are relatively easier to fabricate than 3D because the former work in the microwave and far infrared regions whereas the later work in the visible region and requires smaller lattice constants. In this paper, simulation for a modified 2D PC with two symmetric waveguide channels where a defect is located inside one of the channel is performed. The simulation results show that optical switching is possible by modifying the refractive index of the defect. If more than one structure is applied this feature can potentially be applied to produce a cascade optical switch.

  18. Predicting Two-Dimensional Silicon Carbide Monolayers.

    Science.gov (United States)

    Shi, Zhiming; Zhang, Zhuhua; Kutana, Alex; Yakobson, Boris I

    2015-10-27

    Intrinsic semimetallicity of graphene and silicene largely limits their applications in functional devices. Mixing carbon and silicon atoms to form two-dimensional (2D) silicon carbide (SixC1-x) sheets is promising to overcome this issue. Using first-principles calculations combined with the cluster expansion method, we perform a comprehensive study on the thermodynamic stability and electronic properties of 2D SixC1-x monolayers with 0 ≤ x ≤ 1. Upon varying the silicon concentration, the 2D SixC1-x presents two distinct structural phases, a homogeneous phase with well dispersed Si (or C) atoms and an in-plane hybrid phase rich in SiC domains. While the in-plane hybrid structure shows uniform semiconducting properties with widely tunable band gap from 0 to 2.87 eV due to quantum confinement effect imposed by the SiC domains, the homogeneous structures can be semiconducting or remain semimetallic depending on a superlattice vector which dictates whether the sublattice symmetry is topologically broken. Moreover, we reveal a universal rule for describing the electronic properties of the homogeneous SixC1-x structures. These findings suggest that the 2D SixC1-x monolayers may present a new "family" of 2D materials, with a rich variety of properties for applications in electronics and optoelectronics.

  19. FACE RECOGNITION USING TWO DIMENSIONAL LAPLACIAN EIGENMAP

    Institute of Scientific and Technical Information of China (English)

    Chen Jiangfeng; Yuan Baozong; Pei Bingnan

    2008-01-01

    Recently,some research efforts have shown that face images possibly reside on a nonlinear sub-manifold. Though Laplacianfaces method considered the manifold structures of the face images,it has limits to solve face recognition problem. This paper proposes a new feature extraction method,Two Dimensional Laplacian EigenMap (2DLEM),which especially considers the manifold structures of the face images,and extracts the proper features from face image matrix directly by using a linear transformation. As opposed to Laplacianfaces,2DLEM extracts features directly from 2D images without a vectorization preprocessing. To test 2DLEM and evaluate its performance,a series of ex-periments are performed on the ORL database and the Yale database. Moreover,several experiments are performed to compare the performance of three 2D methods. The experiments show that 2DLEM achieves the best performance.

  20. The Rare Two-Dimensional Materials with Dirac Cones

    OpenAIRE

    Wang, Jinying; Deng, Shibin; Liu, Zhongfan; Liu, Zhirong

    2014-01-01

    Inspired by the great development of graphene, more and more works have been conducted to seek new two-dimensional (2D) materials with Dirac cones. Although 2D Dirac materials possess many novel properties and physics, they are rare compared with the numerous 2D materials. To provide explanation for the rarity of 2D Dirac materials as well as clues in searching for new Dirac systems, here we review the recent theoretical aspects of various 2D Dirac materials, including graphene, silicene, ger...

  1. Two-dimensional signal analysis

    CERN Document Server

    Garello, René

    2010-01-01

    This title sets out to show that 2-D signal analysis has its own role to play alongside signal processing and image processing.Concentrating its coverage on those 2-D signals coming from physical sensors (such as radars and sonars), the discussion explores a 2-D spectral approach but develops the modeling of 2-D signals and proposes several data-oriented analysis techniques for dealing with them. Coverage is also given to potential future developments in this area.

  2. 基于二维红外相关谱欧氏距离判别掺杂牛奶%Discrimination of Adulterated Milk Based on Euclidian Distances between Two-Dimensional Infrared Correlation Spectra

    Institute of Scientific and Technical Information of China (English)

    杨仁杰; 杨延荣; 董桂梅; 杜艳红; 单慧勇; 张伟玉

    2014-01-01

    Based on Euclidian distances between synchronous two-dimensional infrared correlation spectra,in terms of the aver-age Euclidian distances between unknown samples and “extreme samples”,and average intra- and inter- Euclidian distances of samples in the calibration set,a new method for the discrimination of adulterated milk was proposed.Sixteen pure milk samples were collected and 16 adulterated milk samples with urea (0. 01~0. 3 g·L-1 ),and 16 adulterated milk samples with melamine (0. 01~0. 3 g·L-1 )samples were prepared,respectively.The IR absorption spectra of all samples were measured at room tem-perature.The synchronous two-dimensional correlation spectra were generated from concentration-dependent spectral variation of adulterant in milk.The Euclidian distances were calculated between synchronous two-dimensional infrared correlation spectra of all samples.Then,the classification models were built respectively for adulterated milk with urea,and adulterated milk with melamine.The “extreme samples”,average intra- and inter- Euclidian distances were determined.Finally,the unknown samples in prediction set were predicted using constructed models in terms of classification rules of adulterated milk.The classification accuracy rates for pure milk and adulterated milk were 100%.The effectiveness of the proposed method was verified.The re-sults obtained in this study revealed that synchronous two-dimensional infrared correlation spectra in combination with Euclidian distance has a feasible potential to discriminate adulterated milk and pure milk.%基于纯牛奶、掺杂牛奶样品间二维红外相关谱欧氏距离,依据未知样品与校正集中“极值样品”欧氏距离平均值、组内、组间样品欧氏距离平均值,提出了一种掺杂牛奶判别的新方法。分别配置掺杂尿素牛奶(0.01~0.3 g·L-1)和掺杂三聚氰胺牛奶(0.01~0.3 g·L-1)样品各16个,采集纯牛奶及掺杂牛奶样品的红外

  3. High resolution infrared synchrotron study of CH2D81Br: ground state constants and analysis of the ν5, ν6 and ν9 fundamentals

    DEFF Research Database (Denmark)

    Baldacci, A.; Stoppa, P.; Visinoni, R.

    2012-01-01

    The high resolution infrared absorption spectrum of CH2D81Br has been recorded by Fourier transform spectroscopy in the range 550–1075 cm1, with an unapodized resolution of 0.0025 cm-1, employing a synchrotron radiation source. This spectral region is characterized by the ν6 (593.872 cm-1), ν5 (768...

  4. Two-dimensional liquid chromatography

    DEFF Research Database (Denmark)

    Græsbøll, Rune

    of this thesis is on online comprehensive two-dimensional liquid chromatography (online LC×LC) with reverse phase in both dimensions (online RP×RP). Since online RP×RP has not been attempted before within this research group, a significant part of this thesis consists of knowledge and experience gained...

  5. Graphene and Two-Dimensional Materials for Optoelectronic Applications

    Directory of Open Access Journals (Sweden)

    Andreas Bablich

    2016-03-01

    Full Text Available This article reviews optoelectronic devices based on graphene and related two-dimensional (2D materials. The review includes basic considerations of process technology, including demonstrations of 2D heterostructure growth, and comments on the scalability and manufacturability of the growth methods. We then assess the potential of graphene-based transparent conducting electrodes. A major part of the review describes photodetectors based on lateral graphene p-n junctions and Schottky diodes. Finally, the progress in vertical devices made from 2D/3D heterojunctions, as well as all-2D heterostructures is discussed.

  6. Two dimensional unstable scar statistics.

    Energy Technology Data Exchange (ETDEWEB)

    Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Kotulski, Joseph Daniel; Lee, Kelvin S. H. (ITT Industries/AES Los Angeles, CA)

    2006-12-01

    This report examines the localization of time harmonic high frequency modal fields in two dimensional cavities along periodic paths between opposing sides of the cavity. The cases where these orbits lead to unstable localized modes are known as scars. This paper examines the enhancements for these unstable orbits when the opposing mirrors are both convex and concave. In the latter case the construction includes the treatment of interior foci.

  7. Two-Dimensional Vernier Scale

    Science.gov (United States)

    Juday, Richard D.

    1992-01-01

    Modified vernier scale gives accurate two-dimensional coordinates from maps, drawings, or cathode-ray-tube displays. Movable circular overlay rests on fixed rectangular-grid overlay. Pitch of circles nine-tenths that of grid and, for greatest accuracy, radii of circles large compared with pitch of grid. Scale enables user to interpolate between finest divisions of regularly spaced rule simply by observing which mark on auxiliary vernier rule aligns with mark on primary rule.

  8. Photodetectors based on two dimensional materials

    Science.gov (United States)

    Zheng, Lou; Zhongzhu, Liang; Guozhen, Shen

    2016-09-01

    Two-dimensional (2D) materials with unique properties have received a great deal of attention in recent years. This family of materials has rapidly established themselves as intriguing building blocks for versatile nanoelectronic devices that offer promising potential for use in next generation optoelectronics, such as photodetectors. Furthermore, their optoelectronic performance can be adjusted by varying the number of layers. They have demonstrated excellent light absorption, enabling ultrafast and ultrasensitive detection of light in photodetectors, especially in their single-layer structure. Moreover, due to their atomic thickness, outstanding mechanical flexibility, and large breaking strength, these materials have been of great interest for use in flexible devices and strain engineering. Toward that end, several kinds of photodetectors based on 2D materials have been reported. Here, we present a review of the state-of-the-art in photodetectors based on graphene and other 2D materials, such as the graphene, transition metal dichalcogenides, and so on. Project supported by the National Natural Science Foundation of China (Nos. 61377033, 61574132, 61504136) and the State Key Laboratory of Applied Optics, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences.

  9. Molecular assembly on two-dimensional materials

    Science.gov (United States)

    Kumar, Avijit; Banerjee, Kaustuv; Liljeroth, Peter

    2017-02-01

    Molecular self-assembly is a well-known technique to create highly functional nanostructures on surfaces. Self-assembly on two-dimensional (2D) materials is a developing field driven by the interest in functionalization of 2D materials in order to tune their electronic properties. This has resulted in the discovery of several rich and interesting phenomena. Here, we review this progress with an emphasis on the electronic properties of the adsorbates and the substrate in well-defined systems, as unveiled by scanning tunneling microscopy. The review covers three aspects of the self-assembly. The first one focuses on non-covalent self-assembly dealing with site-selectivity due to inherent moiré pattern present on 2D materials grown on substrates. We also see that modification of intermolecular interactions and molecule–substrate interactions influences the assembly drastically and that 2D materials can also be used as a platform to carry out covalent and metal-coordinated assembly. The second part deals with the electronic properties of molecules adsorbed on 2D materials. By virtue of being inert and possessing low density of states near the Fermi level, 2D materials decouple molecules electronically from the underlying metal substrate and allow high-resolution spectroscopy and imaging of molecular orbitals. The moiré pattern on the 2D materials causes site-selective gating and charging of molecules in some cases. The last section covers the effects of self-assembled, acceptor and donor type, organic molecules on the electronic properties of graphene as revealed by spectroscopy and electrical transport measurements. Non-covalent functionalization of 2D materials has already been applied for their application as catalysts and sensors. With the current surge of activity on building van der Waals heterostructures from atomically thin crystals, molecular self-assembly has the potential to add an extra level of flexibility and functionality for applications ranging

  10. Two-dimensional fourier transform spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    DeFlores, Lauren; Tokmakoff, Andrei

    2016-10-25

    The present invention relates to a system and methods for acquiring two-dimensional Fourier transform (2D FT) spectra. Overlap of a collinear pulse pair and probe induce a molecular response which is collected by spectral dispersion of the signal modulated probe beam. Simultaneous collection of the molecular response, pulse timing and characteristics permit real time phasing and rapid acquisition of spectra. Full spectra are acquired as a function of pulse pair timings and numerically transformed to achieve the full frequency-frequency spectrum. This method demonstrates the ability to acquire information on molecular dynamics, couplings and structure in a simple apparatus. Multi-dimensional methods can be used for diagnostic and analytical measurements in the biological, biomedical, and chemical fields.

  11. Two-dimensional fourier transform spectrometer

    Science.gov (United States)

    DeFlores, Lauren; Tokmakoff, Andrei

    2013-09-03

    The present invention relates to a system and methods for acquiring two-dimensional Fourier transform (2D FT) spectra. Overlap of a collinear pulse pair and probe induce a molecular response which is collected by spectral dispersion of the signal modulated probe beam. Simultaneous collection of the molecular response, pulse timing and characteristics permit real time phasing and rapid acquisition of spectra. Full spectra are acquired as a function of pulse pair timings and numerically transformed to achieve the full frequency-frequency spectrum. This method demonstrates the ability to acquire information on molecular dynamics, couplings and structure in a simple apparatus. Multi-dimensional methods can be used for diagnostic and analytical measurements in the biological, biomedical, and chemical fields.

  12. Divorticity and dihelicity in two-dimensional hydrodynamics

    DEFF Research Database (Denmark)

    Shivamoggi, B.K.; van Heijst, G.J.F.; Juul Rasmussen, Jens

    2010-01-01

    A framework is developed based on the concepts of divorticity B (≡×ω, ω being the vorticity) and dihelicity g (≡vB) for discussing the theoretical structure underlying two-dimensional (2D) hydrodynamics. This formulation leads to the global and Lagrange invariants that could impose significant...

  13. Zero sound in a two-dimensional dipolar Fermi gas

    NARCIS (Netherlands)

    Lu, Z.K.; Matveenko, S.I.; Shlyapnikov, G.V.

    2013-01-01

    We study zero sound in a weakly interacting two-dimensional (2D) gas of single-component fermionic dipoles (polar molecules or atoms with a large magnetic moment) tilted with respect to the plane of their translational motion. It is shown that the propagation of zero sound is provided by both mean-f

  14. On the continua in two-dimensional nonadiabatic magnetohydrodynamic spectra

    NARCIS (Netherlands)

    De Ploey, A.; Van der Linden, R. A. M.; Belien, A. J. C.

    2000-01-01

    The equations for the continuous subspectra of the linear magnetohydrodynamic (MHD) normal modes spectrum of two-dimensional (2D) plasmas are derived in general curvilinear coordinates, taking nonadiabatic effects in the energy equation into account. Previously published derivations of continuous sp

  15. Bounds on the capacity of constrained two-dimensional codes

    DEFF Research Database (Denmark)

    Forchhammer, Søren; Justesen, Jørn

    2000-01-01

    Bounds on the capacity of constrained two-dimensional (2-D) codes are presented. The bounds of Calkin and Wilf apply to first-order symmetric constraints. The bounds are generalized in a weaker form to higher order and nonsymmetric constraints. Results are given for constraints specified by run...

  16. Linkage analysis by two-dimensional DNA typing

    NARCIS (Netherlands)

    te Meerman, G J; Mullaart, E; van der Meulen, M A; den Daas, J H; Morolli, B; Uitterlinden, A G; Vijg, J

    1993-01-01

    In two-dimensional (2-D) DNA typing, genomic DNA fragments are separated, first according to size by electrophoresis in a neutral polyacrylamide gel and second according to sequence by denaturing gradient gel electrophoresis, followed by hybridization analysis using micro- and minisatellite core pro

  17. Two-dimensional liquid chromatography

    DEFF Research Database (Denmark)

    Græsbøll, Rune

    Two-dimensional liquid chromatography has received increasing interest due to the rise in demand for analysis of complex chemical mixtures. Separation of complex mixtures is hard to achieve as a simple consequence of the sheer number of analytes, as these samples might contain hundreds or even...... dimensions. As a consequence of the conclusions made within this thesis, the research group has, for the time being, decided against further development of online LC×LC systems, since it was not deemed ideal for the intended application, the analysis of the polar fraction of oil. Trap-and...

  18. Optical Spectroscopy of Two Dimensional Graphene and Boron Nitride

    Science.gov (United States)

    Ju, Long

    a charge transfer process between graphene and BN when the exposure of visible light is introduced. We show this photo-induced doping in graphene resembles the modulation doping technique in traditional semiconductor heterojunctions, where a charge doping is introduced while the high mobility is maintained. This work reveals importance of interactions between stacked 2D materials on the overall properties and demonstrate a repeatable and convenient way of fabricating high quality graphene devices with active control of doping patterning. Along this direction, we did further STM experiment to visualize and manipulate charged defects in boron nitride with the help of graphene. The last theme is about the interesting properties of bilayer graphene, which is to some extent more interesting than monolayer graphene due to its electric-field dependent band structures. Firstly, we visualized the stacking boundary within exfoliated bilayer graphene by near field infrared microscopy. In dual-gated field-effect-transistor devices fabricated on the boundaries, we demonstrated the existence of topologically protected one dimensional conducting channels at the boundary through electric transport measurement. The 1D boundary states also demonstrated the first graphene-based valleytronic device. The topics we are going to talk about in this thesis are quite diversified. Just like the versatile nature of optical spectroscopy, we never limit ourself to a specific technique and do incremental things. Most of the experiments are driven by the important and interesting problems in the two dimensional materials field and we chose the right tool and conceive the right experiment to answer that question. Both pure optical methods and combinations with electric transport and STM measurements were used. I believe the flexibility of optical spectroscopy and its compatibility with other experimental techniques provide a powerful toolbox to explore many possibilities beyond the reach of a

  19. Two-dimensional capillary origami

    Energy Technology Data Exchange (ETDEWEB)

    Brubaker, N.D., E-mail: nbrubaker@math.arizona.edu; Lega, J., E-mail: lega@math.arizona.edu

    2016-01-08

    We describe a global approach to the problem of capillary origami that captures all unfolded equilibrium configurations in the two-dimensional setting where the drop is not required to fully wet the flexible plate. We provide bifurcation diagrams showing the level of encapsulation of each equilibrium configuration as a function of the volume of liquid that it contains, as well as plots representing the energy of each equilibrium branch. These diagrams indicate at what volume level the liquid drop ceases to be attached to the endpoints of the plate, which depends on the value of the contact angle. As in the case of pinned contact points, three different parameter regimes are identified, one of which predicts instantaneous encapsulation for small initial volumes of liquid. - Highlights: • Full solution set of the two-dimensional capillary origami problem. • Fluid does not necessarily wet the entire plate. • Global energy approach provides exact differential equations satisfied by minimizers. • Bifurcation diagrams highlight three different regimes. • Conditions for spontaneous encapsulation are identified.

  20. Perspective: Two-dimensional resonance Raman spectroscopy

    Science.gov (United States)

    Molesky, Brian P.; Guo, Zhenkun; Cheshire, Thomas P.; Moran, Andrew M.

    2016-11-01

    Two-dimensional resonance Raman (2DRR) spectroscopy has been developed for studies of photochemical reaction mechanisms and structural heterogeneity in complex systems. The 2DRR method can leverage electronic resonance enhancement to selectively probe chromophores embedded in complex environments (e.g., a cofactor in a protein). In addition, correlations between the two dimensions of the 2DRR spectrum reveal information that is not available in traditional Raman techniques. For example, distributions of reactant and product geometries can be correlated in systems that undergo chemical reactions on the femtosecond time scale. Structural heterogeneity in an ensemble may also be reflected in the 2D spectroscopic line shapes of both reactive and non-reactive systems. In this perspective article, these capabilities of 2DRR spectroscopy are discussed in the context of recent applications to the photodissociation reactions of triiodide and myoglobin. We also address key differences between the signal generation mechanisms for 2DRR and off-resonant 2D Raman spectroscopies. Most notably, it has been shown that these two techniques are subject to a tradeoff between sensitivity to anharmonicity and susceptibility to artifacts. Overall, recent experimental developments and applications of the 2DRR method suggest great potential for the future of the technique.

  1. Elastic models of defects in two-dimensional crystals

    Science.gov (United States)

    Kolesnikova, A. L.; Orlova, T. S.; Hussainova, I.; Romanov, A. E.

    2014-12-01

    Elastic models of defects in two-dimensional (2D) crystals are presented in terms of continuum mechanics. The models are based on the classification of defects, which is founded on the dimensionality of the specification region of their self-distortions, i.e., lattice distortions associated with the formation of defects. The elastic field of an infinitesimal dislocation loop in a film is calculated for the first time. The fields of the center of dilatation, dislocation, disclination, and circular inclusion in planar 2D elastic media, namely, nanofilms and graphenes, are considered. Elastic fields of defects in 2D and 3D crystals are compared.

  2. Fast Assembly of Gold Nanoparticles in Large-Area 2D Nanogrids Using a One-Step, Near-Infrared Radiation-Assisted Evaporation Process.

    Science.gov (United States)

    Utgenannt, André; Maspero, Ross; Fortini, Andrea; Turner, Rebecca; Florescu, Marian; Jeynes, Christopher; Kanaras, Antonios G; Muskens, Otto L; Sear, Richard P; Keddie, Joseph L

    2016-02-23

    When fabricating photonic crystals from suspensions in volatile liquids using the horizontal deposition method, the conventional approach is to evaporate slowly to increase the time for particles to settle in an ordered, periodic close-packed structure. Here, we show that the greatest ordering of 10 nm aqueous gold nanoparticles (AuNPs) in a template of larger spherical polymer particles (mean diameter of 338 nm) is achieved with very fast water evaporation rates obtained with near-infrared radiative heating. Fabrication of arrays over areas of a few cm(2) takes only 7 min. The assembly process requires that the evaporation rate is fast relative to the particles' Brownian diffusion. Then a two-dimensional colloidal crystal forms at the falling surface, which acts as a sieve through which the AuNPs pass, according to our Langevin dynamics computer simulations. With sufficiently fast evaporation rates, we create a hybrid structure consisting of a two-dimensional AuNP nanoarray (or "nanogrid") on top of a three-dimensional polymer opal. The process is simple, fast, and one-step. The interplay between the optical response of the plasmonic Au nanoarray and the microstructuring of the photonic opal results in unusual optical spectra with two extinction peaks, which are analyzed via finite-difference time-domain method simulations. Comparison between experimental and modeling results reveals a strong interplay of plasmonic modes and collective photonic effects, including the formation of a high-order stopband and slow-light-enhanced plasmonic absorption. The structures, and hence their optical signatures, are tuned by adjusting the evaporation rate via the infrared power density.

  3. Two-dimensional quantum repeaters

    Science.gov (United States)

    Wallnöfer, J.; Zwerger, M.; Muschik, C.; Sangouard, N.; Dür, W.

    2016-11-01

    The endeavor to develop quantum networks gave rise to a rapidly developing field with far-reaching applications such as secure communication and the realization of distributed computing tasks. This ultimately calls for the creation of flexible multiuser structures that allow for quantum communication between arbitrary pairs of parties in the network and facilitate also multiuser applications. To address this challenge, we propose a two-dimensional quantum repeater architecture to establish long-distance entanglement shared between multiple communication partners in the presence of channel noise and imperfect local control operations. The scheme is based on the creation of self-similar multiqubit entanglement structures at growing scale, where variants of entanglement swapping and multiparty entanglement purification are combined to create high-fidelity entangled states. We show how such networks can be implemented using trapped ions in cavities.

  4. Two-dimensional capillary origami

    Science.gov (United States)

    Brubaker, N. D.; Lega, J.

    2016-01-01

    We describe a global approach to the problem of capillary origami that captures all unfolded equilibrium configurations in the two-dimensional setting where the drop is not required to fully wet the flexible plate. We provide bifurcation diagrams showing the level of encapsulation of each equilibrium configuration as a function of the volume of liquid that it contains, as well as plots representing the energy of each equilibrium branch. These diagrams indicate at what volume level the liquid drop ceases to be attached to the endpoints of the plate, which depends on the value of the contact angle. As in the case of pinned contact points, three different parameter regimes are identified, one of which predicts instantaneous encapsulation for small initial volumes of liquid.

  5. A theoretical study on the electronic property of a new two-dimensional material molybdenum dinitride

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Haiping, E-mail: mrhpwu@njust.edu.cn [Department of Applied Physics, Nanjing University of Science and Technology, Nanjing 210094 (China); State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012 (China); Qian, Yan, E-mail: qianyan@njust.edu.cn [Department of Applied Physics, Nanjing University of Science and Technology, Nanjing 210094 (China); Lu, Ruifeng; Tan, Weishi [Department of Applied Physics, Nanjing University of Science and Technology, Nanjing 210094 (China)

    2016-02-15

    Motivated by the recent synthesis of bulk MoN{sub 2} which exhibits the layered structure just like the bulk MoS{sub 2}, the monolayered MoN{sub 2} exfoliated from the bulk counterpart is investigated systematically by using density-functional calculations in this work. The result shows that the ground-state two-dimensional monolayered MoN{sub 2} behaves as an indirect band gap semiconductor with the energy gap of ∼0.12 eV. Subsequently, the external strain from −6% to 6% is employed to engineer the band structure, and the energy gap can be efficiently tuned from 0 to 0.70 eV. Notably, when the strain is beyond 5% or −3%, the two-dimensional monolayered MoN{sub 2} would transfer from an indirect band gap to a direct band gap semiconductor. This work introduces a new member of two-dimensional transition-metal family, which is important for industry applications, especially for the utilization in the long-wavelength infrared field. - Highlights: • The 2D MoN{sub 2} behaves as an indirect band gap semiconductor with the energy gap of ∼0.12 eV. • The energy gap can be efficiently tuned from 0 to 0.70 eV by small strain. • The band gap would transfer from an indirect to a direct one when the strain is beyond 5% or −3%.

  6. Effects of light on quantum phases and topological properties of two-dimensional Metal-organic frameworks

    Science.gov (United States)

    Wang, Yunhua; Liu, Yulan; Wang, Biao

    2017-01-01

    Periodically driven nontrivial quantum states open another door to engineer topological phases in solid systems by light. Here we show, based on the Floquet-Bloch theory, that the on-resonant linearly and circularly polarized infrared light brings in the exotic Floquet quantum spin Hall state and half-metal in two-dimensional Metal-organic frameworks (2D MOFs) because of the unbroken and broken time-reversal symmetry, respectively. We also observe that the off-resonant light triggers topological quantum phase transitions and induces semimetals with pseudospin-1 Dirac-Weyl fermions via the photon-dressed topological band structures of 2D MOFs. This work paves a way to design light-controlled spintronics and optoelectronics based on 2D MOFs. PMID:28134315

  7. Effects of light on quantum phases and topological properties of two-dimensional Metal-organic frameworks

    Science.gov (United States)

    Wang, Yunhua; Liu, Yulan; Wang, Biao

    2017-01-01

    Periodically driven nontrivial quantum states open another door to engineer topological phases in solid systems by light. Here we show, based on the Floquet-Bloch theory, that the on-resonant linearly and circularly polarized infrared light brings in the exotic Floquet quantum spin Hall state and half-metal in two-dimensional Metal-organic frameworks (2D MOFs) because of the unbroken and broken time-reversal symmetry, respectively. We also observe that the off-resonant light triggers topological quantum phase transitions and induces semimetals with pseudospin-1 Dirac-Weyl fermions via the photon-dressed topological band structures of 2D MOFs. This work paves a way to design light-controlled spintronics and optoelectronics based on 2D MOFs.

  8. Two-dimensional correlation spectroscopy in protein science, a summary for past 20years.

    Science.gov (United States)

    Wu, Yuqing; Zhang, Liping; Jung, Young Mee; Ozaki, Yukihiro

    2018-01-15

    Two-dimensional correlation spectroscopy (2DCOS) has been widely used to Infrared, Raman, Near IR, Optical Activity (ROA), Vibrational Circular Dichroism (VCD) and Fluorescence spectroscopy. In addition, several new developments, such as 2D hetero-correlation analysis, moving-window two-dimensional (MW2D) correlation, model based correlation (βν and kν correlation analyses) have also well incorporated into protein research. They have been used to investigate secondary structure, denaturation, folding and unfolding changes of protein, and have contributed greatly to the field of protein science. This review provides an overview of the applications of 2DCOS in the field of protein science for the past 20 year, especially to memory our old friend, Dr. Boguslawa Czarnik-Matusewicz, for her great contribution in this research field. The powerful utility of 2DCOS combined with various analytical techniques in protein studies is summarized. The noteworthy developments and perspective of 2DCOS in this field are highlighted finally. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Vibrational Properties of a Two-Dimensional Silica Kagome Lattice.

    Science.gov (United States)

    Björkman, Torbjörn; Skakalova, Viera; Kurasch, Simon; Kaiser, Ute; Meyer, Jannik C; Smet, Jurgen H; Krasheninnikov, Arkady V

    2016-12-27

    Kagome lattices are structures possessing fascinating magnetic and vibrational properties, but in spite of a large body of theoretical work, experimental realizations and investigations of their dynamics are scarce. Using a combination of Raman spectroscopy and density functional theory calculations, we study the vibrational properties of two-dimensional silica (2D-SiO2), which has a kagome lattice structure. We identify the signatures of crystalline and amorphous 2D-SiO2 structures in Raman spectra and show that, at finite temperatures, the stability of 2D-SiO2 lattice is strongly influenced by phonon-phonon interaction. Our results not only provide insights into the vibrational properties of 2D-SiO2 and kagome lattices in general but also suggest a quick nondestructive method to detect 2D-SiO2.

  10. Emergent elemental two-dimensional materials beyond graphene

    Science.gov (United States)

    Zhang, Yuanbo; Rubio, Angel; Le Lay, Guy

    2017-02-01

    Two-dimensional (2D) materials may offer the ultimate scaling beyond the 5 nm gate length. The difficulty of reliably opening a band gap in graphene has led to the search for alternative, semiconducting 2D materials. Emerging classes of elemental 2D materials stand out for their compatibility with existing technologies and/or for their diverse, tunable electronic structures. Among this group, black phosphorene has recently shown superior semiconductor performances. Silicene and germanene feature Dirac-type band dispersions, much like graphene. Calculations show that most group IV and group V elements have one or more stable 2D allotropes, with properties potentially suitable for electronic and optoelectronic applications. Here, we review the advances in these fascinating elemental 2D materials and discuss progress and challenges in their applications in future opto- and nano-electronic devices.

  11. Computationally Driven Two-Dimensional Materials Design: What Is Next?

    Energy Technology Data Exchange (ETDEWEB)

    Pan, Jie [Materials Science; Lany, Stephan [Materials Science; Qi, Yue [Department of Chemical Engineering and Materials Science, Michigan State University, East Lansing, Michigan 48824, United States

    2017-07-17

    Two-dimensional (2D) materials offer many key advantages to innovative applications, such as spintronics and quantum information processing. Theoretical computations have accelerated 2D materials design. In this issue of ACS Nano, Kumar et al. report that ferromagnetism can be achieved in functionalized nitride MXene based on first-principles calculations. Their computational results shed light on a potentially vast group of materials for the realization of 2D magnets. In this Perspective, we briefly summarize the promising properties of 2D materials and the role theory has played in predicting these properties. In addition, we discuss challenges and opportunities to boost the power of computation for the prediction of the 'structure-property-process (synthesizability)' relationship of 2D materials.

  12. Classifying Two-dimensional Hyporeductive Triple Algebras

    CERN Document Server

    Issa, A Nourou

    2010-01-01

    Two-dimensional real hyporeductive triple algebras (h.t.a.) are investigated. A classification of such algebras is presented. As a consequence, a classification of two-dimensional real Lie triple algebras (i.e. generalized Lie triple systems) and two-dimensional real Bol algebras is given.

  13. Two-Dimensional Electronic Spectroscopy Using Incoherent Light: Theoretical Analysis

    CERN Document Server

    Turner, Daniel B; Sutor, Erika J; Hendrickson, Rebecca A; Gealy, M W; Ulness, Darin J

    2012-01-01

    Electronic energy transfer in photosynthesis occurs over a range of time scales and under a variety of intermolecular coupling conditions. Recent work has shown that electronic coupling between chromophores can lead to coherent oscillations in two-dimensional electronic spectroscopy measurements of pigment-protein complexes measured with femtosecond laser pulses. A persistent issue in the field is to reconcile the results of measurements performed using femtosecond laser pulses with physiological illumination conditions. Noisy-light spectroscopy can begin to address this question. In this work we present the theoretical analysis of incoherent two-dimensional electronic spectroscopy, I(4) 2D ES. Simulations reveal diagonal peaks, cross peaks, and coherent oscillations similar to those observed in femtosecond two-dimensional electronic spectroscopy experiments. The results also expose fundamental differences between the femtosecond-pulse and noisy-light techniques; the differences lead to new challenges and opp...

  14. Moment-based method for computing the two-dimensional discrete Hartley transform

    Science.gov (United States)

    Dong, Zhifang; Wu, Jiasong; Shu, Huazhong

    2009-10-01

    In this paper, we present a fast algorithm for computing the two-dimensional (2-D) discrete Hartley transform (DHT). By using kernel transform and Taylor expansion, the 2-D DHT is approximated by a linear sum of 2-D geometric moments. This enables us to use the fast algorithms developed for computing the 2-D moments to efficiently calculate the 2-D DHT. The proposed method achieves a simple computational structure and is suitable to deal with any sequence lengths.

  15. Two-dimensional function photonic crystals

    CERN Document Server

    Wu, Xiang-Yao; Liu, Xiao-Jing; Liang, Yu

    2016-01-01

    In this paper, we have firstly proposed two-dimensional function photonic crystals, which the dielectric constants of medium columns are the functions of space coordinates $\\vec{r}$, it is different from the two-dimensional conventional photonic crystals constituting by the medium columns of dielectric constants are constants. We find the band gaps of two-dimensional function photonic crystals are different from the two-dimensional conventional photonic crystals, and when the functions form of dielectric constants are different, the band gaps structure should be changed, which can be designed into the appropriate band gaps structures by the two-dimensional function photonic crystals.

  16. A new structure of two-dimensional allotropes of group V elements

    Science.gov (United States)

    Li, Ping; Luo, Weidong

    2016-05-01

    The elemental two-dimensional (2D) materials such as graphene, silicene, germanene, and black phosphorus have attracted considerable attention due to their fascinating physical properties. Structurally they possess the honeycomb or distorted honeycomb lattices, which are composed of six-atom rings. Here we find a new structure of 2D allotropes of group V elements composed of eight-atom rings, which we name as the octagonal tiling (OT) structure. First-principles calculations indicate that these allotropes are dynamically stable and are also thermally stable at temperatures up to 600 K. These allotropes are semiconductors with band gaps ranging from 0.3 to 2.0 eV, thus they are potentially useful in near- and mid-infrared optoelectronic devices. OT-Bi is also a 2D topological insulator (TI) with a band gap of 0.33 eV, which is the largest among the reported elemental 2D TIs, and this gap can be increased further by applying compressive strains.

  17. Phase-sensitive two-dimensional neutron shearing interferometer and Hartmann sensor

    Energy Technology Data Exchange (ETDEWEB)

    Baker, Kevin

    2015-12-08

    A neutron imaging system detects both the phase shift and absorption of neutrons passing through an object. The neutron imaging system is based on either of two different neutron wavefront sensor techniques: 2-D shearing interferometry and Hartmann wavefront sensing. Both approaches measure an entire two-dimensional neutron complex field, including its amplitude and phase. Each measures the full-field, two-dimensional phase gradients and, concomitantly, the two-dimensional amplitude mapping, requiring only a single measurement.

  18. Comparative Two-Dimensional Fluorescence Gel Electrophoresis.

    Science.gov (United States)

    Ackermann, Doreen; König, Simone

    2018-01-01

    Two-dimensional comparative fluorescence gel electrophoresis (CoFGE) uses an internal standard to increase the reproducibility of coordinate assignment for protein spots visualized on 2D polyacrylamide gels. This is particularly important for samples, which need to be compared without the availability of replicates and thus cannot be studied using differential gel electrophoresis (DIGE). CoFGE corrects for gel-to-gel variability by co-running with the sample proteome a standardized marker grid of 80-100 nodes, which is formed by a set of purified proteins. Differentiation of reference and analyte is possible by the use of two fluorescent dyes. Variations in the y-dimension (molecular weight) are corrected by the marker grid. For the optional control of the x-dimension (pI), azo dyes can be used. Experiments are possible in both vertical and horizontal (h) electrophoresis devices, but hCoFGE is much easier to perform. For data analysis, commercial software capable of warping can be adapted.

  19. Development of Novel Two-dimensional Layers, Alloys and Heterostructures

    Science.gov (United States)

    Liu, Zheng

    2015-03-01

    The one-atom-think graphene has fantastic properties and attracted tremendous interests in these years, which opens a window towards various two-dimensional (2D) atomic layers. However, making large-size and high-quality 2D layers is still a great challenge. Using chemical vapor deposition (CVD) method, we have successfully synthesized a wide varieties of highly crystalline and large scale 2D atomic layers, including h-BN, metal dichalcogenides e.g. MoS2, WS2, CdS, GaSe and MoSe2 which belong to the family of binary 2D materials. Ternary 2D alloys including BCN and MoS2xSe2 (1 - x) are also prepared and characterized. In addition, synthesis of 2D heterostructures such as vertical and lateral graphene/h-BN, vertical and lateral TMDs are also demonstrated. Complementary to CVD grown 2D layers, 2D single-crystal (bulk) such as Phosphorene (P), WTe2, SnSe2, PtS2, PtSe2, PdSe2, WSe2xTe2 (1 - x), Ta2NiS5andTa2NiSe5 are also prepared by solid reactions. There work provide a better understanding of the atomic layered materials in terms of the synthesis, atomic structure, alloying and their physical properties. Potential applications of these 2D layers e.g. optoelectronic devices, energy device and smart coating have been explored.

  20. 基于二维相关近红外谱参数化及BP神经网络的掺杂牛奶鉴别%Identification of Adulterated Milk Based on Two-Dimensional Correlation Near-Infrared Spectra Parameterization and BP Neural Network

    Institute of Scientific and Technical Information of China (English)

    苗静; 曹玉珍; 杨仁杰; 刘蓉; 孙惠丽; 徐可欣

    2013-01-01

    Discriminant models of adulterated milk and pure milk were established using BP neural network combined with two-dimensional (2D) correlation near-infrared spectra parameterization .Forty pure milk samples ,40 adulterated milk samples with urea (1~20 g · L -1 ) and 40 adulterated milk samples with melamine (0.01~3 g · L -1 ) were prepared respectively .Based on the characteristics of 2D correlation near-infrared spectra of pure milk and adulterated milk ,5 apparent statistic parameters were calculated based on the parameterization theory .Using 5 characteristic parameters ,discriminant models of urea adulterated milk , melamine adulterated milk and two types of adulterated milk were built by BP neural network .The prediction rate of unknown samples were 95% ,100% and 96.7% ,respectively .The results show that this method can extract effectively feature informa-tion of adulterant ,reduce the input dimensions of BP neural network ,and better realize qualitative analysis of adulterant in milk .%将二维相关近红外谱参数化方法与BP神经网络结合,建立掺杂牛奶与纯牛奶的判别模型。分别配制含有尿素牛奶(1~20g·L -1)和三聚氰胺牛奶(0.01~3g·L -1)样品各40个。研究了纯牛奶、掺杂牛奶的二维相关近红外谱特性,在此基础上,分别提取了各样品二维相关同步谱的5个特征参数。将这5个特征参数作为BP神经网络的输入,分别建立掺杂尿素、掺杂三聚氰胺、两种掺杂牛奶与纯牛奶的判别模型,采用这些模型对未知样品进行预测,其预测正确率分别为95%,100%和96.7%。研究结果表明:该方法有效地提取了牛奶中掺杂目标物的特征光谱信息,同时又减少了BP神经网络输入变量的维数,实现了掺杂牛奶与纯牛奶的鉴别。

  1. А heuristic algorithm for two-dimensional strip packing problem

    OpenAIRE

    Dayong, Cao; Kotov, V.M.

    2011-01-01

    In this paper, we construct an improved best-fit heuristic algorithm for two-dimensional rectangular strip packing problem (2D-RSPP), and compare it with some heuristic and metaheuristic algorithms from literatures. The experimental results show that BFBCC could produce satisfied packing layouts than these methods, especially for the large problem of 50 items or more, BFBCC could get better results in shorter time.

  2. Colloidal interactions in two-dimensional nematic emulsions

    Indian Academy of Sciences (India)

    N M Silvestre; P Patrício; M M Telo Da Gama

    2005-06-01

    We review theoretical and experimental work on colloidal interactions in two-dimensional (2D) nematic emulsions. We pay particular attention to the effects of (i) the nematic elastic constants, (ii) the size of the colloids, and (iii) the boundary conditions at the particles and the container. We consider the interactions between colloids and fluid (deformable) interfaces and the shape of fluid colloids in smectic-C films.

  3. Analysis of the Effect of Moisture on Soil Spectra Detection by Using Two-Dimensional Correlation Near Infrared Spectroscopy%水分对土壤近红外光谱检测影响的二维相关光谱解析

    Institute of Scientific and Technical Information of China (English)

    宋海燕; 程旭

    2014-01-01

    为了能进一步分析水分对土壤近红外光谱检测的影响,分别从三个地方(桃园堡、牧场和农大示范田)采集了三种土壤,经过筛、烘干后分别配制了含水率为20%,15%和10%的土壤,然后采用ASD公司的FieldSpec3光谱仪在保证其他检测条件不变的情况下,对不同含水率下不同采集地的土壤进行了检测,获得了其不同含水率下的动态光谱图。最后视水分为外部干扰,应用二维相关光谱的理论对其进行了分析。结果表明,在350~2500 nm波段范围内,三个不同采集地土壤的同步二维相关光谱图比较类似,都在2210和1929 nm附近处出现较强的自动峰,在1415 nm附近处有较弱的自动峰;从三处自相关峰的密集程度来看,1929 nm处对应的官能团对水分最敏感,2210 nm处次之,1415 nm处最不敏感。该研究明确找出了水分对土壤近红外光谱检测影响的敏感波段和敏感程度,为今后消除水分影响建立抗水分干扰模型提供了依据。%In order to analyze the effects of moisture on soil spectra detection ,soil samples from three different places (Taoyuan-bao ,Muchang ,and Shanxi agricultural university) were collected .All soil samples were sieved ,dried and prepared with differ-ent water content (20% ,15% and 10% ) .The spectra of soil samples with different water content were collected by ASD Field-Spec3 .Finally ,moisture was looked as the the external disturbance ,and two-dimensional correlation near-infrared spectroscopy (2D-NIR) technique was applied to analyze the effect of moisture on soil spectra detection .2D-NIR analysis was realized by using shige software (2Dshige shigeaki Morita ,Kwansei-Gakuin University ) .The results showed that ,the sensitive bands of moisture in 2D-NIR spectra were more obvious than one-dimensional spectra .In the region 350~2 500 nm ,the synchronous spectra of soil samples from different places were similar .Two

  4. A comparative study of two-dimensional multifractal detrended fluctuation analysis and two-dimensional multifractal detrended moving average algorithm to estimate the multifractal spectrum

    Science.gov (United States)

    Xi, Caiping; Zhang, Shunning; Xiong, Gang; Zhao, Huichang

    2016-07-01

    Multifractal detrended fluctuation analysis (MFDFA) and multifractal detrended moving average (MFDMA) algorithm have been established as two important methods to estimate the multifractal spectrum of the one-dimensional random fractal signal. They have been generalized to deal with two-dimensional and higher-dimensional fractal signals. This paper gives a brief introduction of the two-dimensional multifractal detrended fluctuation analysis (2D-MFDFA) and two-dimensional multifractal detrended moving average (2D-MFDMA) algorithm, and a detailed description of the application of the two-dimensional fractal signal processing by using the two methods. By applying the 2D-MFDFA and 2D-MFDMA to the series generated from the two-dimensional multiplicative cascading process, we systematically do the comparative analysis to get the advantages, disadvantages and the applicabilities of the two algorithms for the first time from six aspects such as the similarities and differences of the algorithm models, the statistical accuracy, the sensitivities of the sample size, the selection of scaling range, the choice of the q-orders and the calculation amount. The results provide a valuable reference on how to choose the algorithm from 2D-MFDFA and 2D-MFDMA, and how to make the schemes of the parameter settings of the two algorithms when dealing with specific signals in practical applications.

  5. Two-dimensional numerical assessment of the hydrodynamics of the Nile swamps in southern Sudan

    National Research Council Canada - National Science Library

    Petersen, G; Fohrer, N

    2010-01-01

    A two-dimensional (2D) hydrodynamic assessment of the Nile swamps in southern Sudan has been carried out using DHI MIKE 21 software based on a ground referenced and corrected Shuttle Radar Topography Mission (SRTM...

  6. Logarithmic divergent thermal conductivity in two-dimensional nonlinear lattices.

    Science.gov (United States)

    Wang, Lei; Hu, Bambi; Li, Baowen

    2012-10-01

    Heat conduction in three two-dimensional (2D) momentum-conserving nonlinear lattices are numerically calculated via both nonequilibrium heat-bath and equilibrium Green-Kubo algorithms. It is expected by mainstream theories that heat conduction in such 2D lattices is divergent and the thermal conductivity κ increases with lattice length N logarithmically. Our simulations for the purely quartic lattice firmly confirm it. However, very robust finite-size effects are observed in the calculations for the other two lattices, which well explain some existing studies and imply the extreme difficulties in observing their true asymptotic behaviors with affordable computation resources.

  7. Absolute band gaps in two-dimensional graphite photonic crystal

    Institute of Scientific and Technical Information of China (English)

    Gaoxin Qiu(仇高新); Fanglei Lin(林芳蕾); Hua Wang(王华); Yongping Li(李永平)

    2003-01-01

    The off-plane propagation of electromagnetic (EM) waves in a two-dimensional (2D) graphite photoniccrystal structure was studied using transfer matrix method. Transmission spectra calculations indicatethat such a 2D structure has a common band gap from 0.202 to 0.2035 c/a for both H and E polarizationsand for all off-plane angles form 0° up to 90°. The presence of such an absolute band gap implies that 2Dgraphite photonic crystal, which is much easier and more feasible to fabricate, can exhibit some propertiesof a three-dimensional (3D) photonic crystal.

  8. Two-dimensional carbon fundamental properties, synthesis, characterization, and applications

    CERN Document Server

    Yihong, Wu; Ting, Yu

    2013-01-01

    After a brief introduction to the fundamental properties of graphene, this book focuses on synthesis, characterization and application of various types of two-dimensional (2D) nanocarbons ranging from single/few layer graphene to carbon nanowalls and graphene oxides. Three major synthesis techniques are covered: epitaxial growth of graphene on SiC, chemical synthesis of graphene on metal, and chemical vapor deposition of vertically aligned carbon nanosheets or nanowalls. One chapter is dedicated to characterization of 2D nanocarbon using Raman spectroscopy. It provides extensive coverage for a

  9. Band alignment of two-dimensional lateral heterostructures

    CERN Document Server

    Zhang, Junfeng; Xie, Weiyu; Zhang, S B

    2016-01-01

    Band alignment in two-dimensional (2D) lateral heterostructures is fundamentally different from three-dimensional (3D), as Schottky barrier height is at the Schottky-Mott limit and band offset is at the Anderson limit, regardless interfacial conditions. This robustness arises because, in the asymptotic limit, effect of interfacial dipole vanishes. First-principles calculations of graphene/h-BN and MoS2/WS2 show that 2D junction width W is typically an order of magnitude longer than 3D. Therefore, heterostructures with dimension less than W can also be made, leading to tunable band alignment.

  10. A Direct Two-Dimensional Pressure Formulation in Molecular Dynamics

    CERN Document Server

    YD, Sumith

    2016-01-01

    Two-dimensional (2D) pressure field estimation in molecular dynamics (MD) simulations has been done using three-dimensional (3D) pressure field calculations followed by averaging, which is computationally expensive due to 3D convolutions. In this work, we develop a direct 2D pressure field estimation method which is much faster than 3D methods without losing accuracy. The method is validated with MD simulations on two systems: a liquid film and a cylindrical drop of argon suspended in surrounding vapor.

  11. A Two-dimensional Magnetohydrodynamics Scheme for General Unstructured Grids

    Science.gov (United States)

    Livne, Eli; Dessart, Luc; Burrows, Adam; Meakin, Casey A.

    2007-05-01

    We report a new finite-difference scheme for two-dimensional magnetohydrodynamics (MHD) simulations, with and without rotation, in unstructured grids with quadrilateral cells. The new scheme is implemented within the code VULCAN/2D, which already includes radiation hydrodynamics in various approximations and can be used with arbitrarily moving meshes (ALEs). The MHD scheme, which consists of cell-centered magnetic field variables, preserves the nodal finite difference representation of divB by construction, and therefore any initially divergence-free field remains divergence-free through the simulation. In this paper, we describe the new scheme in detail and present comparisons of VULCAN/2D results with those of the code ZEUS/2D for several one-dimensional and two-dimensional test problems. The code now enables two-dimensional simulations of the collapse and explosion of the rotating, magnetic cores of massive stars. Moreover, it can be used to simulate the very wide variety of astrophysical problems for which multidimensional radiation magnetohydrodynamics (RMHD) is relevant.

  12. OH-asterisk (7-5) Meinel band dayglow and nightglow measured by the SME limb scanning near infrared spectrometer - Comparison of the observed seasonal variability with two-dimensional model simulations

    Science.gov (United States)

    Le Texier, H.; Solomon, S.; Thomas, R. J.; Garcia, R. R.

    1989-01-01

    Seasonal variations of the OH-asterisk (7-5) mesospheric hydroxyl emission at 1.89 microns observed by the SME near-IR spectrometer are compared with the theoretical predictions of a two-dimensional dynamical/chemical model. The good agreement found at low latitudes for both dayglow and nightglow provides support for the model assumption that breaking gravity waves induce seasonal and latitudinal variations in diffusion. The seasonal behavior of atomic hydrogen in the upper mesosphere (related to vertical transport) and/or uncertainties in the OH Meinel band parameters are proposed as possible explanations for the discrepancy noted between model and observational data for the middle latitudes.

  13. Two-dimensional artificial light-harvesting antennae with predesigned high-order structure and robust photosensitising activity

    Science.gov (United States)

    Feng, Xiao; Ding, Xuesong; Chen, Long; Wu, Yang; Liu, Lili; Addicoat, Matthew; Irle, Stephan; Dong, Yuping; Jiang, Donglin

    2016-09-01

    Highly ordered discrete assemblies of chlorophylls that are found in natural light-harvesting antennae are key to photosynthesis, which converts light energy to chemical energy and is the principal producer of organic matter on Earth. Porphyrins and phthalocyanines, which are analogues of chlorophylls, exhibit a strong absorbance of visible and near-infrared light, respectively. A highly ordered porphyrin-co-phthalocyanine antennae would harvest photons over the entire solar spectrum for chemical transformation. However, such a robust antennae has not yet been synthesised. Herein, we report a strategy that merges covalent bonds and noncovalent forces to produce highly ordered two-dimensional porphyrin-co-phthalocyanine antennae. This methodology enables control over the stoichiometry and order of the porphyrin and phthalocyanine units; more importantly, this approach is compatible with various metalloporphyrin and metallophthalocyanine derivatives and thus may lead to the generation of a broad structural diversity of two-dimensional artificial antennae. These ordered porphyrin-co-phthalocyanine two-dimensional antennae exhibit unique optical properties and catalytic functions that are not available with single-component or non-structured materials. These 2D artificial antennae exhibit exceptional light-harvesting capacity over the entire solar spectrum as a result of a synergistic light-absorption effect. In addition, they exhibit outstanding photosensitising activities in using both visible and near-infrared photons for producing singlet oxygen.

  14. Separation of colloidal two dimensional materials by density gradient ultracentrifugation

    Energy Technology Data Exchange (ETDEWEB)

    Kuang, Yun; Song, Sha [State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029 (China); Huang, Jinyang, E-mail: huangjy@mail.buct.edu.cn [Department of Mathematics, College of Science, Beijing University of Chemical Technology, Beijing 100029 (China); Sun, Xiaoming, E-mail: sunxm@mail.buct.edu.cn [State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029 (China)

    2015-04-15

    Two-dimensional (2D) materials have been made through various approaches but obtaining monodispersed simply by synthesis optimization gained little success, which highlighted the need for introducing nanoseparation methods. Density gradient ultracentrifugation method has emerged as a versatile and scalable method for sorting colloidal 2D nanomaterials. Isopycnic separation was applied on thickness-dependent separation of graphene nanosheets. And rate-zonal separation, as a more versatile separation method, demonstrated its capability in sorting nanosheets of chemically modified single layered graphene, layered double hydroxide, and even metallic Ag. Establishing such density gradient ultracentrifugation method not only achieves monodispersed nanosheets and provides new opportunities for investigation on size dependent properties of 2D materials, but also makes the surface modification possible by introducing “reaction zones” during sedimentation of the colloids. - Graphical abstract: Two-dimensional (2D) materials have been made through various approaches but obtaining monodispersed simply by synthesis optimization gained little success, which highlighted the need for introducing nanoseparation methods. Density gradient ultracentrifugation method has emerged as a versatile and scalable method for sorting colloidal 2D nanomaterials according to their size of thickness difference. Establishing such density gradient ultracentrifugation method not only achieves monodispersed nanosheets and provides new opportunities for investigation on size dependent properties of 2D materials, but also makes the surface modification possible by introducing “reaction zones” during sedimentation of the colloids. - Highlights: • Density gradient ultracentrifugation was applied on size separation of 2D material. • Isopycnic separation was applied on separation of low density materials. • Rate-zonal separation was applied on separation of large density materials. • Size

  15. Hadamard States and Two-dimensional Gravity

    CERN Document Server

    Salehi, H

    2001-01-01

    We have used a two-dimensional analog of the Hadamard state-condition to study the local constraints on the two-point function of a linear quantum field conformally coupled to a two-dimensional gravitational background. We develop a dynamical model in which the determination of the state of the quantum field is essentially related to the determination of a conformal frame. A particular conformal frame is then introduced in which a two-dimensional gravitational equation is established.

  16. Radiation effects on two-dimensional materials

    Energy Technology Data Exchange (ETDEWEB)

    Walker, R.C. II; Robinson, J.A. [Department of Materials Science, Penn State, University Park, PA (United States); Center for Two-Dimensional Layered Materials, Penn State, University Park, PA (United States); Shi, T. [Department of Mechanical and Nuclear Engineering, Penn State, University Park, PA (United States); Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, MI (United States); Silva, E.C. [GlobalFoundries, Malta, NY (United States); Jovanovic, I. [Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, MI (United States)

    2016-12-15

    The effects of electromagnetic and particle irradiation on two-dimensional materials (2DMs) are discussed in this review. Radiation creates defects that impact the structure and electronic performance of materials. Determining the impact of these defects is important for developing 2DM-based devices for use in high-radiation environments, such as space or nuclear reactors. As such, most experimental studies have been focused on determining total ionizing dose damage to 2DMs and devices. Total dose experiments using X-rays, gamma rays, electrons, protons, and heavy ions are summarized in this review. We briefly discuss the possibility of investigating single event effects in 2DMs based on initial ion beam irradiation experiments and the development of 2DM-based integrated circuits. Additionally, beneficial uses of irradiation such as ion implantation to dope materials or electron-beam and helium-beam etching to shape materials have begun to be used on 2DMs and are reviewed as well. For non-ionizing radiation, such as low-energy photons, we review the literature on 2DM-based photo-detection from terahertz to UV. The majority of photo-detecting devices operate in the visible and UV range, and for this reason they are the focus of this review. However, we review the progress in developing 2DMs for detecting infrared and terahertz radiation. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  17. Tunable states of interlayer cations in two-dimensional materials

    Energy Technology Data Exchange (ETDEWEB)

    Sato, K.; Numata, K. [Department of Environmental Sciences, Tokyo Gakugei University, Koganei, Tokyo 184-8501 (Japan); Dai, W. [Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071 (China); Hunger, M. [Institute of Chemical Technology, University of Stuttgart, 70550 Stuttgart (Germany)

    2014-03-31

    The local state of cations inside the Ångstrom-scale interlayer spaces is one of the controlling factors for designing sophisticated two-dimensional (2D) materials consisting of 2D nanosheets. In the present work, the molecular mechanism on how the interlayer cation states are induced by the local structures of the 2D nanosheets is highlighted. For this purpose, the local states of Na cations in inorganic 2D materials, in which the compositional fluctuations of a few percent are introduced in the tetrahedral and octahedral units of the 2D nanosheets, were systematically studied by means of {sup 23}Na magic-angle-spinning (MAS) nuclear magnetic resonance (NMR) and {sup 23}Na multiple-quantum MAS (MQMAS) NMR spectroscopy. In contrast with an uniform distribution of Na cations expected so far, various well-defined cation states sensitive to the local structures of the 2D nanosheets were identified. The tunability of the interlayer cation states along with the local structure of the 2D nanosheets, as the smallest structural unit of the 2D material, is discussed.

  18. Two-dimensional gallium nitride realized via graphene encapsulation

    Science.gov (United States)

    Al Balushi, Zakaria Y.; Wang, Ke; Ghosh, Ram Krishna; Vilá, Rafael A.; Eichfeld, Sarah M.; Caldwell, Joshua D.; Qin, Xiaoye; Lin, Yu-Chuan; Desario, Paul A.; Stone, Greg; Subramanian, Shruti; Paul, Dennis F.; Wallace, Robert M.; Datta, Suman; Redwing, Joan M.; Robinson, Joshua A.

    2016-11-01

    The spectrum of two-dimensional (2D) and layered materials `beyond graphene’ offers a remarkable platform to study new phenomena in condensed matter physics. Among these materials, layered hexagonal boron nitride (hBN), with its wide bandgap energy (~5.0-6.0 eV), has clearly established that 2D nitrides are key to advancing 2D devices. A gap, however, remains between the theoretical prediction of 2D nitrides `beyond hBN’ and experimental realization of such structures. Here we demonstrate the synthesis of 2D gallium nitride (GaN) via a migration-enhanced encapsulated growth (MEEG) technique utilizing epitaxial graphene. We theoretically predict and experimentally validate that the atomic structure of 2D GaN grown via MEEG is notably different from reported theory. Moreover, we establish that graphene plays a critical role in stabilizing the direct-bandgap (nearly 5.0 eV), 2D buckled structure. Our results provide a foundation for discovery and stabilization of 2D nitrides that are difficult to prepare via traditional synthesis.

  19. van der Waals epitaxy and photoresponse of two-dimensional CdSe plates

    Science.gov (United States)

    Zhu, Dan-Dan; Xia, Jing; Wang, Lei; Li, Xuan-Ze; Tian, Li-Feng; Meng, Xiang-Min

    2016-06-01

    Here we demonstrate the first growth of two-dimensional (2D) single-crystalline CdSe plates on mica substrates via van der Waals epitaxy. The as-synthesized 2D plates exhibit hexagonal, truncated triangular and triangular shapes with the lateral size around several microns. Photodetectors based on 2D CdSe plates present a fast response time of 24 ms, revealing that 2D CdSe is a promising building block for ultrathin optoelectronic devices.

  20. Surface topography to reflectivity mapping in two-dimensional photonic crystals designed in germanium

    Energy Technology Data Exchange (ETDEWEB)

    Husanu, M.A.; Ganea, C.P. [National Institute of Materials Physics, Atomistilor 105b, 077125 Magurele, Ilfov (Romania); Anghel, I. [National Institute for Laser, Plasma & Radiation Physics, Atomistilor 409, 077125 Magurele (Romania); University of Bucharest, Faculty of Physics, Atomistilor 405, 077125 Magurele (Romania); Florica, C.; Rasoga, O. [National Institute of Materials Physics, Atomistilor 105b, 077125 Magurele, Ilfov (Romania); Popescu, D.G., E-mail: dana.popescu@infim.ro [National Institute of Materials Physics, Atomistilor 105b, 077125 Magurele, Ilfov (Romania)

    2015-11-15

    Highlights: • Laser ablation is used for drilling a periodic 2D photonic structure. • Confinement of radiation is revealed by infra-red spectromicroscopy correlated with numerical calculations. • Telecommunication range is accessible upon tuning conveniently the processing parameters. - Abstract: Light confinement in a two dimensional photonic crystal (2D PhC) with hexagonal symmetry is studied using infra-red reflectance spectromicroscopy and numerical calculations. The structure has been realized by laser ablation, using a pulsed laser (λ = 775 nm), perforating an In-doped Ge wafer and creating a lattice of holes with well-defined symmetry. Correlating the spectral signature of the photonic gaps recorded experimentally with the results obtained in the finite difference time domain and finite difference frequency domain calculations, we established the relationship between the geometric parameters of the structure (lattice constants, shape of the hole) and its efficiency in trapping and guiding the radiation in a well-defined frequency range. Besides the gap in the low energy range of transversal electric modes, a second one is identified in the telecommunication range, originating in the localization of the leaky modes within the radiation continuum. The emerging picture is of a device with promising characteristics as an alternative to Si-based technology in photonic device fabrication with special emphasize in energy storage and conversion.

  1. Two-Dimensional DOA Estimation for Uniform Rectangular Array Using Reduced-Dimension Propagator Method

    Directory of Open Access Journals (Sweden)

    Ming Zhou

    2015-01-01

    Full Text Available A novel algorithm is proposed for two-dimensional direction of arrival (2D-DOA estimation with uniform rectangular array using reduced-dimension propagator method (RD-PM. The proposed algorithm requires no eigenvalue decomposition of the covariance matrix of the receive data and simplifies two-dimensional global searching in two-dimensional PM (2D-PM to one-dimensional local searching. The complexity of the proposed algorithm is much lower than that of 2D-PM. The angle estimation performance of the proposed algorithm is better than that of estimation of signal parameters via rotational invariance techniques (ESPRIT algorithm and conventional PM algorithms, also very close to 2D-PM. The angle estimation error and Cramér-Rao bound (CRB are derived in this paper. Furthermore, the proposed algorithm can achieve automatically paired 2D-DOA estimation. The simulation results verify the effectiveness of the algorithm.

  2. Strongly interacting two-dimensional Dirac fermions

    NARCIS (Netherlands)

    Lim, L.K.; Lazarides, A.; Hemmerich, Andreas; de Morais Smith, C.

    2009-01-01

    We show how strongly interacting two-dimensional Dirac fermions can be realized with ultracold atoms in a two-dimensional optical square lattice with an experimentally realistic, inherent gauge field, which breaks time reversal and inversion symmetries. We find remarkable phenomena in a temperature

  3. Topology optimization of two-dimensional waveguides

    DEFF Research Database (Denmark)

    Jensen, Jakob Søndergaard; Sigmund, Ole

    2003-01-01

    In this work we use the method of topology optimization to design two-dimensional waveguides with low transmission loss.......In this work we use the method of topology optimization to design two-dimensional waveguides with low transmission loss....

  4. Transient two-dimensional IR spectrometer for probing nanosecond temperature-jump kinetics.

    Science.gov (United States)

    Chung, Hoi Sung; Khalil, Munira; Smith, Adam W; Tokmakoff, Andrei

    2007-06-01

    We have developed a Fourier transform two-dimensional infrared (2D IR) spectrometer to probe chemical reactions and biophysical processes triggered by a nanosecond temperature jump (T jump). The technical challenges for such a spectrometer involve (1) synchronization of a nanosecond T-jump laser and femtosecond laser system, (2) overcoming the decreased signal-to-noise ratio from low repetition rate data acquisition, and (3) performing an interferometric measurement through a sample with a density and index of refraction that varies with time delay after the T jump. The first challenge was overcome by synchronizing the two lasers to a clock derived from the Ti:sapphire oscillator, leading to timing accuracy of 2 ns for delays up to 50 ms. The data collection time is reduced by using undersampling with the improved signal-to-noise ratio obtained from a balanced detection scheme with a dual stripe array detector. Transient dispersed vibrational echo and 2D IR spectroscopy are applied to N-methylacetamide and ubiquitin, as examples, and the spectral responses by a temperature elevation and by structural changes of the protein are compared. The synchronization of 2D IR spectroscopy with a nanosecond temperature jump without losing its sensitivity at a low repetition rate opens a new applicability of the nonlinear spectroscopy to probe a variety of molecular structure changes induced by a nanosecond perturbation.

  5. Interaction of two-dimensional magnetoexcitons

    Science.gov (United States)

    Dumanov, E. V.; Podlesny, I. V.; Moskalenko, S. A.; Liberman, M. A.

    2017-04-01

    We study interaction of the two-dimensional magnetoexcitons with in-plane wave vector k→∥ = 0 , taking into account the influence of the excited Landau levels (ELLs) and of the external electric field perpendicular to the surface of the quantum well and parallel to the external magnetic field. It is shown that the account of the ELLs gives rise to the repulsion between the spinless magnetoexcitons with k→∥ = 0 in the Fock approximation, with the interaction constant g decreasing inverse proportional to the magnetic field strength B (g (0) ∼ 1 / B) . In the presence of the perpendicular electric field the Rashba spin-orbit coupling (RSOC), Zeeman splitting (ZS) and nonparabolicity of the heavy-hole dispersion law affect the Landau quantization of the electrons and holes. They move along the new cyclotron orbits, change their Coulomb interactions and cause the interaction between 2D magnetoexcitons with k→∥ = 0 . The changes of the Coulomb interactions caused by the electrons and by the holes moving with new cyclotron orbits are characterized by some coefficients, which in the absence of the electric field turn to be unity. The differences between these coefficients of the electron-hole pairs forming the magnetoexcitons determine their affinities to the interactions. The interactions between the homogeneous, semihomogeneous and heterogeneous magnetoexcitons forming the symmetric states with the same signs of their affinities are attractive whereas in the case of different sign affinities are repulsive. In the heterogeneous asymmetric states the interactions have opposite signs in comparison with the symmetric states. In all these cases the interaction constant g have the dependence g (0) 1 /√{ B} .

  6. Hyper-Kähler singularities in superstring compactification and two-dimensional N = 4 conformal field theory

    Science.gov (United States)

    Belhaj, A.; Saidi, E. H.

    2001-01-01

    Using a geometric realization of the SU(2)R symmetry and a factorization of the gauge and SU(2)R charges, we study the small instanton singularities of the Higgs branch of supersymmetric U(1)r gauge theories with eight supercharges. We derive new solutions for the moduli space of vacua preserving manifestly the eight supercharges. In particular, we obtain an extension of the ordinary ADE singularities for hyper-Kähler manifolds and show that the classical moduli space of vacua is, in general, given by cotangent bundles of compact weighted projective spaces describing new models which flow in the infrared to two-dimensional (2D) N = (4,4) scale-invariant models. We also study the N = 4 conformal Liouville description near an An singularity of the metric of the 2D N = 4 Higgs branch using a field-theoretical approach.

  7. 2-D Animation's Not Just for Mickey Mouse.

    Science.gov (United States)

    Weinman, Lynda

    1995-01-01

    Discusses characteristics of two-dimensional (2-D) animation; highlights include character animation, painting issues, and motion graphics. Sidebars present Silicon Graphics animations tools and 2-D animation programs for the desktop computer. (DGM)

  8. Characterization by Fourier transform infrared spectroscopy (FT-IR) and 2D IR correlation spectroscopy of a carbosilane dendrimer with peripheral ammonium groups

    Energy Technology Data Exchange (ETDEWEB)

    Popescu, Maria-Cristina, E-mail: cpopescu@icmpp.ro [' Petru Poni' Institute of Macromolecular Chemistry (Romania); Gomez, Rafael; Mata, Fco Javier de la; Rasines, Beatriz [Universidad de Alcala, Departamento de Quimica Inorganica (Spain); Simionescu, Bogdan C. [' Petru Poni' Institute of Macromolecular Chemistry (Romania)

    2013-06-15

    Fourier transform infrared spectroscopy and 2D correlation spectroscopy were used to study the microstructural changes occurring on heating of a new carbosilane dendrimer with peripheral ammonium groups. Temperature-dependent spectral variations in the 3,010-2,710, 1,530-1,170, and 1,170-625 cm{sup -1} regions were monitored during the heating process. The dependence, on temperature, of integral absorptions and position of spectral bands was established and the spectral modifications associated with molecular conformation rearrangements, allowing molecular shape changes, were found. Before 180 Degree-Sign C, the studied carbosilane dendrimer proved to be stable, while at higher temperatures it oxidizes and Si-O groups appear. 2D IR correlation spectroscopy gives new information about the effect of temperature on the structure and dynamics of the system. Synchronous and asynchronous spectra indicate that, at low temperature, conformational changes of CH{sub 3} and CH{sub 3}-N{sup +} groups take place first. With increasing temperature, the intensity variation of the CH{sub 2}, C-N, Si-C and C-C groups from the dendritic core is faster than that of the terminal units. This indicates that, with increasing temperature, the segments of the dendritic core obtain enough energy to change their conformation more easily as compared to the terminal units, due to their internal flexibility.

  9. Drying process of sodium alginate films studied by two-dimensional correlation ATR-FTIR spectroscopy.

    Science.gov (United States)

    Xiao, Qian; Gu, Xiaohong; Tan, Suo

    2014-12-01

    Drying process of aqueous sodium alginate solutions at 50°C was investigated by ATR-FTIR spectroscopy and two-dimensional correlation infrared spectroscopy. Two-dimensional asynchronous spectrum at 1,800-1,350 cm(-1) wavenumber could be resolved into five separate bands, which were assigned to O-H bending vibrations in water (around 1,645 cm(-1)), antisymmetric and symmetric stretching vibrations of free and hydrogen-bonded COO(-) groups of alginate (around 1,595, 1,412, 1,572 and 1,390 cm(-1), respectively). As the drying process progressed, absorbance bands at around 1,127 and 1,035 cm(-1) significantly shifted to lower wavenumbers (1120 and 1027cm(-1), respectively). Suggesting that oxygen atoms at the 2th and 3th position in the pyranose ring might have hydrogen bonded with water or alginate chains. Further analysis using 2D asynchronous correlation spectroscopy between 1800-1500 and 1200-960 cm(-1) wavenumber regions revealed the sequence of spectral changes during the drying process. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. Superfluid phase transition in two-dimensional excitonic systems

    Energy Technology Data Exchange (ETDEWEB)

    Apinyan, V.; Kopeć, T.K., E-mail: kopec@int.pan.wroc.pl

    2014-03-01

    We study the superfluid phase transition in the two-dimensional (2D) excitonic system. Employing the extended Falicov–Kimball model (EFKM) and considering the local quantum correlations in the system composed of conduction band electrons and valence band holes we demonstrate the existence of the excitonic insulator (EI) state in the system. We show that at very low temperatures, the particle phase stiffness in the pure-2D excitonic system, governed by the non-local cross correlations, is responsible for the vortex–antivortex binding phase-field state, known as the Berezinskii–Kosterlitz–Thouless (BKT) superfluid state. We demonstrate that the existence of excitonic insulator phase is a necessary prerequisite, leading to quasi-long-range order in the 2D excitonic system.

  11. Two-dimensional electronic spectroscopy with birefringent wedges

    Energy Technology Data Exchange (ETDEWEB)

    Réhault, Julien; Maiuri, Margherita; Oriana, Aurelio; Cerullo, Giulio [IFN-CNR, Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano (Italy)

    2014-12-15

    We present a simple experimental setup for performing two-dimensional (2D) electronic spectroscopy in the partially collinear pump-probe geometry. The setup uses a sequence of birefringent wedges to create and delay a pair of phase-locked, collinear pump pulses, with extremely high phase stability and reproducibility. Continuous delay scanning is possible without any active stabilization or position tracking, and allows to record rapidly and easily 2D spectra. The setup works over a broad spectral range from the ultraviolet to the near-IR, it is compatible with few-optical-cycle pulses and can be easily reconfigured to two-colour operation. A simple method for scattering suppression is also introduced. As a proof of principle, we present degenerate and two-color 2D spectra of the light-harvesting complex 1 of purple bacteria.

  12. Nonlinear optical response of a two-dimensional atomic crystal.

    Science.gov (United States)

    Merano, Michele

    2016-01-01

    The theory of Bloembergen and Pershan for the light waves at the boundary of nonlinear media is extended to a nonlinear two-dimensional (2D) atomic crystal, i.e., a single planar atomic lattice, placed between linear bulk media. The crystal is treated as a zero-thickness interface, a real 2D system. Harmonic waves emanate from it. Generalization of the laws of reflection and refraction give the direction and the intensity of the harmonic waves. As a particular case that contains all the essential physical features, second-order harmonic generation is considered. The theory, due to its simplicity that stems from the special character of a single planar atomic lattice, is able to elucidate and explain the rich experimental details of harmonic generation from a 2D atomic crystal.

  13. Synthesis of borophenes: Anisotropic, two-dimensional boron polymorphs

    Science.gov (United States)

    Mannix, Andrew J.; Zhou, Xiang-Feng; Kiraly, Brian; Wood, Joshua D.; Alducin, Diego; Myers, Benjamin D.; Liu, Xiaolong; Fisher, Brandon L.; Santiago, Ulises; Guest, Jeffrey R.; Yacaman, Miguel Jose; Ponce, Arturo; Oganov, Artem R.; Hersam, Mark C.; Guisinger, Nathan P.

    2016-01-01

    At the atomic-cluster scale, pure boron is markedly similar to carbon, forming simple planar molecules and cage-like fullerenes.Theoretical studies predict that two-dimensional (2D) boron sheets will adopt an atomic configuration similar to that of boron atomic clusters. We synthesized atomically thin, crystalline 2D boron sheets (i.e., borophene) on silver surfaces under ultrahigh-vacuum conditions. Atomic-scale characterization, supported by theoretical calculations, revealed structures reminiscent of fused boron clusters with multiple scales of anisotropic, out-of-plane buckling. Unlike bulk boron allotropes, borophene shows metallic characteristics that are consistent with predictions of a highly anisotropic, 2D metal. PMID:26680195

  14. Proximity Induced Superconducting Properties in One and Two Dimensional Semiconductors

    DEFF Research Database (Denmark)

    Kjærgaard, Morten

    a voltage is passed through the Josephson junction, we observe multiple Andreev reflections and preliminary results point to a highly transmissive interface between the 2D electron gas and the superconductor. In the theoretical section we demonstrate analytically and numerically, that in a 1D nanowire......This report is concerned with the properties of one and two dimensional semiconducting materials when brought into contact with a superconductor. Experimentally we study the 2D electron gas in an InGaAs/InAs heterostructure with aluminum grown in situ on the surface, and theoretically we show...... that a superconducting 1D nanowire can harbor Majorana bound states in the absence of spin–orbit coupling. We fabricate and measure micrometer–sized mesoscopic devices demonstrating the inheritance of superconducting properties in the 2D electron gas. By placing a quantum point contact proximal to the interface between...

  15. A renormalization group analysis of two-dimensional magnetohydrodynamic turbulence

    Science.gov (United States)

    Liang, Wenli Z.; Diamond, P. H.

    1993-01-01

    The renormalization group (RNG) method is used to study the physics of two-dimensional (2D) magnetohydrodynamic (MHD) turbulence. It is shown that, for a turbulent magnetofluid in two dimensions, no RNG transformation fixed point exists on account of the coexistence of energy transfer to small scales and mean-square magnetic flux transfer to large scales. The absence of a fixed point renders the RNG method incapable of describing the 2D MHD system. A similar conclusion is reached for 2D hydrodynamics, where enstrophy flows to small scales and energy to large scales. These analyses suggest that the applicability of the RNG method to turbulent systems is intrinsically limited, especially in the case of systems with dual-direction transfer.

  16. Quasi-Two-Dimensional Magnetism in Co-Based Shandites

    Science.gov (United States)

    Kassem, Mohamed A.; Tabata, Yoshikazu; Waki, Takeshi; Nakamura, Hiroyuki

    2016-06-01

    We report quasi-two-dimensional (Q2D) itinerant electron magnetism in the layered Co-based shandites. Comprehensive magnetization measurements were performed using single crystals of Co3Sn2-xInxS2 (0 ≤ x ≤ 2) and Co3-yFeySn2S2 (0 ≤ y ≤ 0.5). The magnetic parameters of both systems; the Curie temperature TC, effective moment peff and spontaneous moment ps; exhibit almost identical variations against the In- and Fe-concentrations, indicating significance of the electron count on the magnetism in the Co-based shandite. The ferromagnetic-nonmagnetic quantum phase transition is found around xc ˜ 0.8. Analysis based on the extended Q2D spin fluctuation theory clearly reveals the highly Q2D itinerant electron character of the ferromagnetism in the Co-based shandites.

  17. Two-dimensional Imaging Velocity Interferometry: Technique and Data Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Erskine, D J; Smith, R F; Bolme, C; Celliers, P; Collins, G

    2011-03-23

    We describe the data analysis procedures for an emerging interferometric technique for measuring motion across a two-dimensional image at a moment in time, i.e. a snapshot 2d-VISAR. Velocity interferometers (VISAR) measuring target motion to high precision have been an important diagnostic in shockwave physics for many years Until recently, this diagnostic has been limited to measuring motion at points or lines across a target. We introduce an emerging interferometric technique for measuring motion across a two-dimensional image, which could be called a snapshot 2d-VISAR. If a sufficiently fast movie camera technology existed, it could be placed behind a traditional VISAR optical system and record a 2d image vs time. But since that technology is not yet available, we use a CCD detector to record a single 2d image, with the pulsed nature of the illumination providing the time resolution. Consequently, since we are using pulsed illumination having a coherence length shorter than the VISAR interferometer delay ({approx}0.1 ns), we must use the white light velocimetry configuration to produce fringes with significant visibility. In this scheme, two interferometers (illuminating, detecting) having nearly identical delays are used in series, with one before the target and one after. This produces fringes with at most 50% visibility, but otherwise has the same fringe shift per target motion of a traditional VISAR. The 2d-VISAR observes a new world of information about shock behavior not readily accessible by traditional point or 1d-VISARS, simultaneously providing both a velocity map and an 'ordinary' snapshot photograph of the target. The 2d-VISAR has been used to observe nonuniformities in NIF related targets (polycrystalline diamond, Be), and in Si and Al.

  18. Analysis of the IEA 2D test. 2D, 3D, steady or unsteady airflow?

    DEFF Research Database (Denmark)

    Cortes, Ines Olmedo; Nielsen, Peter V.

    The “IEA Annex 20 two-dimensional test case” was defined by proffesor Peter V. Nielsen (1990) and was originally considered two-dimensional and steady flow. However, some recent works considering the case as three dimensional have shown different solutions from the 2D case as well as different so...

  19. Extension of modified power method to two-dimensional problems

    Science.gov (United States)

    Zhang, Peng; Lee, Hyunsuk; Lee, Deokjung

    2016-09-01

    In this study, the generalized modified power method was extended to two-dimensional problems. A direct application of the method to two-dimensional problems was shown to be unstable when the number of requested eigenmodes is larger than a certain problem dependent number. The root cause of this instability has been identified as the degeneracy of the transfer matrix. In order to resolve this instability, the number of sub-regions for the transfer matrix was increased to be larger than the number of requested eigenmodes; and a new transfer matrix was introduced accordingly which can be calculated by the least square method. The stability of the new method has been successfully demonstrated with a neutron diffusion eigenvalue problem and the 2D C5G7 benchmark problem.

  20. Parallel β-sheet vibrational couplings revealed by 2D IR spectroscopy of an isotopically labeled macrocycle: quantitative benchmark for the interpretation of amyloid and protein infrared spectra.

    Science.gov (United States)

    Woys, Ann Marie; Almeida, Aaron M; Wang, Lu; Chiu, Chi-Cheng; McGovern, Michael; de Pablo, Juan J; Skinner, James L; Gellman, Samuel H; Zanni, Martin T

    2012-11-21

    Infrared spectroscopy is playing an important role in the elucidation of amyloid fiber formation, but the coupling models that link spectra to structure are not well tested for parallel β-sheets. Using a synthetic macrocycle that enforces a two stranded parallel β-sheet conformation, we measured the lifetimes and frequency for six combinations of doubly (13)C═(18)O labeled amide I modes using 2D IR spectroscopy. The average vibrational lifetime of the isotope labeled residues was 550 fs. The frequencies of the labels ranged from 1585 to 1595 cm(-1), with the largest frequency shift occurring for in-register amino acids. The 2D IR spectra of the coupled isotope labels were calculated from molecular dynamics simulations of a series of macrocycle structures generated from replica exchange dynamics to fully sample the conformational distribution. The models used to simulate the spectra include through-space coupling, through-bond coupling, and local frequency shifts caused by environment electrostatics and hydrogen bonding. The calculated spectra predict the line widths and frequencies nearly quantitatively. Historically, the characteristic features of β-sheet infrared spectra have been attributed to through-space couplings such as transition dipole coupling. We find that frequency shifts of the local carbonyl groups due to nearest neighbor couplings and environmental factors are more important, while the through-space couplings dictate the spectral intensities. As a result, the characteristic absorption spectra empirically used for decades to assign parallel β-sheet secondary structure arises because of a redistribution of oscillator strength, but the through-space couplings do not themselves dramatically alter the frequency distribution of eigenstates much more than already exists in random coil structures. Moreover, solvent exposed residues have amide I bands with >20 cm(-1) line width. Narrower line widths indicate that the amide I backbone is solvent

  1. Two dimensional density and its fluctuation measurements by using phase imaging method in GAMMA 10

    Energy Technology Data Exchange (ETDEWEB)

    Yoshikawa, M.; Negishi, S.; Shima, Y.; Hojo, H.; Imai, T. [Plasma Research Center, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577 (Japan); Mase, A. [Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka 816-8580 (Japan); Kogi, Y. [Fukuoka Institute of Technology, 3-30-1 Wajiro-higashi, Higashiku, Fukuoka 811-0295 (Japan)

    2010-10-15

    Two dimensional (2D) plasma image analysis is useful to study the improvement of plasma confinement in magnetically confined fusion plasmas. We have constructed a 2D interferometer system with phase imaging method for studying 2D plasma density distribution and its fluctuation measurement in the tandem mirror GAMMA 10. 2D profiles of electron density and its fluctuation have been successfully obtained by using this 2D phase imaging system. We show that 2D plasma density and fluctuation profiles clearly depends on the axial confining potential formation with application of plug electron cyclotron heating in GAMMA 10.

  2. Two-dimensional coupled electron-hole layers in high magnetic fields

    NARCIS (Netherlands)

    Parlangeli, Andrea

    2000-01-01

    In solids, it is nowadays possible to create structures in which electrons are confined into a two-dimensional (2D) plane. The physics of a 2D electron gas (2DEG) has proved to be very rich, in particular in the presence of a transverse magnetic field. The Quantum Hall Effect, i.e. the quantization

  3. Dipeptide Structural Analysis Using Two-Dimensional NMR for the Undergraduate Advanced Laboratory

    Science.gov (United States)

    Gonzalez, Elizabeth; Dolino, Drew; Schwartzenburg, Danielle; Steiger, Michelle A.

    2015-01-01

    A laboratory experiment was developed to introduce students in either an organic chemistry or biochemistry lab course to two-dimensional nuclear magnetic resonance (2D NMR) spectroscopy using simple biomolecules. The goal of this experiment is for students to understand and interpret the information provided by a 2D NMR spectrum. Students are…

  4. Dipeptide Structural Analysis Using Two-Dimensional NMR for the Undergraduate Advanced Laboratory

    Science.gov (United States)

    Gonzalez, Elizabeth; Dolino, Drew; Schwartzenburg, Danielle; Steiger, Michelle A.

    2015-01-01

    A laboratory experiment was developed to introduce students in either an organic chemistry or biochemistry lab course to two-dimensional nuclear magnetic resonance (2D NMR) spectroscopy using simple biomolecules. The goal of this experiment is for students to understand and interpret the information provided by a 2D NMR spectrum. Students are…

  5. Two-Dimensional Hydrous Silica : Nanosheets and Nanotubes Predicted from First-Principles Simulations

    NARCIS (Netherlands)

    Fang, Changming; Van Blaaderen, Alfons; Van Huis, Marijn A.

    2015-01-01

    Two-dimensional (2D) hydrous silica sheets (HSSs) and hydrous silica nanotubes (HSNTs) have many unique properties and potential applications. Although preparation of 2D HSSs was patented already about half a century ago, very little is known about their structure and physical properties. He we pred

  6. Two-dimensional multiferroics in monolayer group IV monochalcogenides

    Science.gov (United States)

    Wang, Hua; Qian, Xiaofeng

    2017-03-01

    Low-dimensional multiferroic materials hold great promises in miniaturized device applications such as nanoscale transducers, actuators, sensors, photovoltaics, and nonvolatile memories. Here, using first-principles theory we predict that two-dimensional (2D) monolayer group IV monochalcogenides including GeS, GeSe, SnS, and SnSe are a class of 2D semiconducting multiferroics with giant strongly-coupled in-plane spontaneous ferroelectric polarization and spontaneous ferroelastic lattice strain that are thermodynamically stable at room temperature and beyond, and can be effectively modulated by elastic strain engineering. Their optical absorption spectra exhibit strong in-plane anisotropy with visible-spectrum excitonic gaps and sizable exciton binding energies, rendering the unique characteristics of low-dimensional semiconductors. More importantly, the predicted low domain wall energy and small migration barrier together with the coupled multiferroic order and anisotropic electronic structures suggest their great potentials for tunable multiferroic functional devices by manipulating external electrical, mechanical, and optical field to control the internal responses, and enable the development of four device concepts including 2D ferroelectric memory, 2D ferroelastic memory, and 2D ferroelastoelectric nonvolatile photonic memory as well as 2D ferroelectric excitonic photovoltaics.

  7. On the critical behaviour of two-dimensional liquid crystals

    Directory of Open Access Journals (Sweden)

    A.l. Fariñas-Sánchez

    2010-01-01

    Full Text Available The Lebwohl-Lasher (LL model is the traditional model used to describe the nematic-isotropic transition of real liquid crystals. In this paper, we develop a numerical study of the temperature behaviour and of finite-size scaling of the two-dimensional (2D LL-model. We discuss two possible scenarios. In the first one, the 2D LL-model presents a phase transition similar to the topological transition appearing in the 2D XY-model. In the second one, the 2D LL-model does not exhibit any critical transition, but its low temperature behaviour is rather characterized by a crossover from a disordered phase to an ordered phase at zero temperature. We realize and discuss various comparisons with the 2D XY-model and the 2D Heisenberg model. Having added finite-size scaling behaviour of the order parameter and conformal mapping of order parameter profile to previous studies, we analyze the critical scaling of the probability distribution function, hyperscaling relations and stiffness order parameter and conclude that the second scenario (no critical transition is the most plausible.

  8. Ab Initio Prediction of Piezoelectricity in Two-Dimensional Materials.

    Science.gov (United States)

    Blonsky, Michael N; Zhuang, Houlong L; Singh, Arunima K; Hennig, Richard G

    2015-10-27

    Two-dimensional (2D) materials present many unique materials concepts, including material properties that sometimes differ dramatically from those of their bulk counterparts. One of these properties, piezoelectricity, is important for micro- and nanoelectromechanical systems applications. Using symmetry analysis, we determine the independent piezoelectric coefficients for four groups of predicted and synthesized 2D materials. We calculate with density-functional perturbation theory the stiffness and piezoelectric tensors of these materials. We determine the in-plane piezoelectric coefficient d11 for 37 materials within the families of 2D metal dichalcogenides, metal oxides, and III-V semiconductor materials. A majority of the structures, including CrSe2, CrTe2, CaO, CdO, ZnO, and InN, have d11 coefficients greater than 5 pm/V, a typical value for bulk piezoelectric materials. Our symmetry analysis shows that buckled 2D materials exhibit an out-of-plane coefficient d31. We find that d31 for 8 III-V semiconductors ranges from 0.02 to 0.6 pm/V. From statistical analysis, we identify correlations between the piezoelectric coefficients and the electronic and structural properties of the 2D materials that elucidate the origin of the piezoelectricity. Among the 37 2D materials, CdO, ZnO, and CrTe2 stand out for their combination of large piezoelectric coefficient and low formation energy and are recommended for experimental exploration.

  9. Soluble, Exfoliated Two-Dimensional Nanosheets as Excellent Aqueous Lubricants.

    Science.gov (United States)

    Zhang, Wenling; Cao, Yanlin; Tian, Pengyi; Guo, Fei; Tian, Yu; Zheng, Wen; Ji, Xuqiang; Liu, Jingquan

    2016-11-30

    Dispersion in water of two-dimensional (2D) nanosheets is conducive to their practical applications in fundamental science communities due to their abundance, low cost, and ecofriendliness. However, it is difficult to achieve stable aqueous 2D material suspensions because of the intrinsic hydrophobic properties of the layered materials. Here, we report an effective and economic way of producing various 2D nanosheets (h-BN, MoS2, MoSe2, WS2, and graphene) as aqueous dispersions using carbon quantum dots (CQDs) as exfoliation agents and stabilizers. The dispersion was prepared through a liquid phase exfoliation. The as-synthesized stable 2D nanosheets based dispersions were characterized by UV-vis, HRTEM, AFM, Raman, XPS, and XRD. The solutions based on CQD decorated 2D nanosheets were utilized as aqueous lubricants, which realized a friction coefficient as low as 0.02 and even achieved a superlubricity under certain working conditions. The excellent lubricating properties were attributed to the synergetic effects of the 2D nanosheets and CQDs, such as good dispersion stability and easy-sliding interlayer structure. This work thus proposes a novel strategy for the design and preparation of high-performance water based green lubricants.

  10. Study onβ-carotene under Thermal Treatment by Two-Dimensional Correlation Fourier Transform Infrared Spectroscopy%温度对β-胡萝卜素二维相关红外光谱的影响

    Institute of Scientific and Technical Information of China (English)

    卢明倩; 黄桂媛; 王巧贞; 许超; 黄庶识

    2016-01-01

    Abtract:[Objective]The aim of this study is to analyze the interaction between the different groups ofβ-carotene in the heating process.[Methods]Two-dimensional correlation spectrosco-py was applied to study the dynamic spectral changes ofβ-carotene from 30℃ to 100℃.[Re-sults]The changes of absorption characteristic peaks ofβ-carotene were inconspicuous in the conventional FTIR spectra and second derivative FTIR spectra during 30℃ to 100℃,which in-dicated that they had no oxidation reation.Two-dimensional correlation analysis showed that the changes of absorption peaks at 968 cm-1 ,1 442 cm-1 ,2 9 6 6 cm-1 and 3 0 1 2 cm-1 were more sen-sitive to temperature.Meanwhile,the order of different groups changes induced by temperature were as follows:the spectral changes of methyl-ene were faster than methyl,the spectral changes of methyl C-H symmetric stretching vibration in low wavenumber were faster than methyl anti-symmetric stretching vibration in high wavenumber,and olefin hydrocarbon symmetric stretching vibration were prior to olefin hydrocarbon anti-symmetric stretching vibration.[Con-clusion]This provides experimental basis for the mechanism of the conformational change ofβ-carotene in heating process.%【目的】了解在升温过程中β-胡萝卜素分子内不同基团之间的相互影响。【方法】采用二维相关红外光谱分析技术,研究β-胡萝卜素在30~100℃变温微扰过程中的动态光谱变化。【结果】β-胡萝卜素分子的吸收特征峰在一维红外光谱和二阶导数谱上变化不明显,表明其没有发生氧化反应。二维相关分析表明,反式共轭烯烃C—H 面外弯曲振动的968 cm-1,烯烃C—H 基团反对称弯曲振动的1442cm-1,甲基C—H 反对称伸缩振动的2966 cm-1和烯烃C—H 的对称伸缩振动的3012 cm-1,这些吸收峰的光谱变化对温度比较敏感。同时在微扰过程中,不同基团变化的先后顺序:亚甲基热运动引起的光谱变化快于

  11. Wavelength selective uncooled infrared sensor by plasmonics

    Science.gov (United States)

    Ogawa, Shinpei; Okada, Kazuya; Fukushima, Naoki; Kimata, Masafumi

    2012-01-01

    A wavelength selective uncooled infrared (IR) sensor using two-dimensional plasmonic crystals (2D PLCs) has been developed. The numerical investigation of 2D PLCs demonstrates that the wavelength of absorption can be mainly controlled by the period of the surface structure. A microelectromechanical systems-based uncooled IR sensor with 2D PLCs as the IR absorber was fabricated through a complementary metal oxide semiconductor and a micromachining technique. The selective enhancement of responsivity was observed at the wavelength that coincided with the period of the 2D-PLC absorber.

  12. Two Dimensional Plasmonic Cavities on Moire Surfaces

    Science.gov (United States)

    Balci, Sinan; Kocabas, Askin; Karabiyik, Mustafa; Kocabas, Coskun; Aydinli, Atilla

    2010-03-01

    We investigate surface plasmon polariton (SPP) cavitiy modes on two dimensional Moire surfaces in the visible spectrum. Two dimensional hexagonal Moire surface can be recorded on a photoresist layer using Interference lithography (IL). Two sequential exposures at slightly different angles in IL generate one dimensional Moire surfaces. Further sequential exposure for the same sample at slightly different angles after turning the sample 60 degrees around its own axis generates two dimensional hexagonal Moire cavity. Spectroscopic reflection measurements have shown plasmonic band gaps and cavity states at all the azimuthal angles (omnidirectional cavity and band gap formation) investigated. The plasmonic band gap edge and the cavity states energies show six fold symmetry on the two dimensional Moire surface as measured in reflection measurements.

  13. Two-dimensional function photonic crystals

    Science.gov (United States)

    Liu, Xiao-Jing; Liang, Yu; Ma, Ji; Zhang, Si-Qi; Li, Hong; Wu, Xiang-Yao; Wu, Yi-Heng

    2017-01-01

    In this paper, we have studied two-dimensional function photonic crystals, in which the dielectric constants of medium columns are the functions of space coordinates , that can become true easily by electro-optical effect and optical kerr effect. We calculated the band gap structures of TE and TM waves, and found the TE (TM) wave band gaps of function photonic crystals are wider (narrower) than the conventional photonic crystals. For the two-dimensional function photonic crystals, when the dielectric constant functions change, the band gaps numbers, width and position should be changed, and the band gap structures of two-dimensional function photonic crystals can be adjusted flexibly, the needed band gap structures can be designed by the two-dimensional function photonic crystals, and it can be of help to design optical devices.

  14. Three-dimensional versus two-dimensional vision in laparoscopy

    DEFF Research Database (Denmark)

    Sørensen, Stine Maya Dreier; Savran, Mona M; Konge, Lars;

    2016-01-01

    BACKGROUND: Laparoscopic surgery is widely used, and results in accelerated patient recovery time and hospital stay were compared with laparotomy. However, laparoscopic surgery is more challenging compared with open surgery, in part because surgeons must operate in a three-dimensional (3D) space...... through a two-dimensional (2D) projection on a monitor, which results in loss of depth perception. To counter this problem, 3D imaging for laparoscopy was developed. A systematic review of the literature was performed to assess the effect of 3D laparoscopy. METHODS: A systematic search of the literature...

  15. Complex Saddles in Two-dimensional Gauge Theory

    CERN Document Server

    Buividovich, P V; Valgushev, S N

    2015-01-01

    We study numerically the saddle point structure of two-dimensional (2D) lattice gauge theory, represented by the Gross-Witten-Wadia unitary matrix model. The saddle points are in general complex-valued, even though the original integration variables and action are real. We confirm the trans-series/instanton gas structure in the weak-coupling phase, and identify a new complex-saddle interpretation of non-perturbative effects in the strong-coupling phase. In both phases, eigenvalue tunneling refers to eigenvalues moving off the real interval, into the complex plane, and the weak-to-strong coupling phase transition is driven by saddle condensation.

  16. Two Dimensional Spatial Independent Component Analysis and Its Application in fMRI Data Process

    Institute of Scientific and Technical Information of China (English)

    CHEN Hua-fu; YAO De-zhong

    2005-01-01

    One important application of independent component analysis (ICA) is in image processing. A two dimensional (2-D) composite ICA algorithm framework for 2-D image independent component analysis (2-D ICA) is proposed. The 2-D nature of the algorithm provides it an advantage of circumventing the roundabout transforming procedures between two dimensional (2-D) image data and one-dimensional (1-D) signal. Moreover the combination of the Newton (fixed-point algorithm) and natural gradient algorithms in this composite algorithm increases its efficiency and robustness. The convincing results of a successful example in functional magnetic resonance imaging (fMRI) show the potential application of composite 2-D ICA in the brain activity detection.

  17. Electron Cryomicroscopy of Membrane Proteins: Specimen Preparation for Two-Dimensional Crystals and Single Particles

    OpenAIRE

    Schmidt-Krey, Ingeborg; Rubinstein, John L.

    2010-01-01

    Membrane protein structure and function can be studied by two powerful and highly complementary electron cryomicroscopy (cryo-EM) methods: electron crystallography of two-dimensional (2D) crystals and single particle analysis of detergent-solubilized protein complexes. To obtain the highest-possible resolution data from membrane proteins, whether prepared as 2D crystals or single particles, cryo-EM samples must be vitrified with great care. Grid preparation for cryo-EM of 2D crystals is possi...

  18. 25th anniversary article: hybrid nanostructures based on two-dimensional nanomaterials.

    Science.gov (United States)

    Huang, Xiao; Tan, Chaoliang; Yin, Zongyou; Zhang, Hua

    2014-04-09

    Two-dimensional (2D) nanomaterials, such as graphene and transition metal dichalcogenides (TMDs), receive a lot of attention, because of their intriguing properties and wide applications in catalysis, energy-storage devices, electronics, optoelectronics, and so on. To further enhance the performance of their application, these 2D nanomaterials are hybridized with other functional nanostructures. In this review, the latest studies of 2D nanomaterial-based hybrid nanostructures are discussed, focusing on their preparation methods, properties, and applications.

  19. Perspectives for spintronics in 2D materials

    Directory of Open Access Journals (Sweden)

    Wei Han

    2016-03-01

    Full Text Available The past decade has been especially creative for spintronics since the (rediscovery of various two dimensional (2D materials. Due to the unusual physical characteristics, 2D materials have provided new platforms to probe the spin interaction with other degrees of freedom for electrons, as well as to be used for novel spintronics applications. This review briefly presents the most important recent and ongoing research for spintronics in 2D materials.

  20. Two Dimensional Organometal Halide Perovskite Nanorods with Tunable Optical Properties.

    Science.gov (United States)

    Aharon, Sigalit; Etgar, Lioz

    2016-05-11

    Organo-metal halide perovskite is an efficient light harvester in photovoltaic solar cells. Organometal halide perovskite is used mainly in its "bulk" form in the solar cell. Confined perovskite nanostructures could be a promising candidate for efficient optoelectronic devices, taking advantage of the superior bulk properties of organo-metal halide perovskite, as well as the nanoscale properties. In this paper, we present facile low-temperature synthesis of two-dimensional (2D) lead halide perovskite nanorods (NRs). These NRs show a shift to higher energies in the absorbance and in the photoluminescence compared to the bulk material, which supports their 2D structure. X-ray diffraction (XRD) analysis of the NRs demonstrates their 2D nature combined with the tetragonal 3D perovskite structure. In addition, by alternating the halide composition, we were able to tune the optical properties of the NRs. Fast Fourier transform, and electron diffraction show the tetragonal structure of these NRs. By varying the ligands ratio (e.g., octylammonium to oleic acid) in the synthesis, we were able to provide the formation mechanism of these novel 2D perovskite NRs. The 2D perovskite NRs are promising candidates for a variety of optoelectronic applications, such as light-emitting diodes, lasing, solar cells, and sensors.

  1. Generalized non-separable two-dimensional Dammann encoding method

    Science.gov (United States)

    Yu, Junjie; Zhou, Changhe; Zhu, Linwei; Lu, Yancong; Wu, Jun; Jia, Wei

    2017-01-01

    We generalize for the first time, to the best of our knowledge, the Dammann encoding method into non-separable two-dimensional (2D) structures for designing various pure-phase Dammann encoding gratings (DEGs). For examples, three types of non-separable 2D DEGs, including non-separable binary Dammann vortex gratings, non-separable binary distorted Dammann gratings, and non-separable continuous-phase cubic gratings, are designed theoretically and demonstrated experimentally. Correspondingly, it is shown that 2D square arrays of optical vortices with topological charges proportional to the diffraction orders, focus spots shifting along both transversal and axial directions with equal spacings, and Airy-like beams with controllable orientation for each beam, are generated in symmetry or asymmetry by these three DEGs, respectively. Also, it is shown that a more complex-shaped array of modulated beams could be achieved by this non-separable 2D Dammann encoding method, which will be a big challenge for those conventional separable 2D Dammann encoding gratings. Furthermore, the diffractive efficiency of the gratings can be improved around ∼10% when the non-separable structure is applied, compared with their conventional separable counterparts. Such improvement in the efficiency should be of high significance for some specific applications.

  2. Gate-induced superconductivity in two-dimensional atomic crystals

    Science.gov (United States)

    Saito, Yu; Nojima, Tsutomu; Iwasa, Yoshihiro

    2016-09-01

    Two-dimensional (2D) crystals are attracting growing interest in condensed matter physics, since these systems exhibit not only rich electronic and photonic properties but also exotic electronic phase transitions including superconductivity and charge density wave. Moreover, owing to the recent development of transfer methods after exfoliation and electric-double-layer transistors, superconducting 2D atomic crystals, the thicknesses of which are below 1-2 nm, have been successfully obtained. Here, we present a topical review on the recent discoveries of 2D crystalline superconductors by ionic-liquid gating and a series of their novel properties. In particular, we highlight two topics; quantum metallic states (or possible metallic ground states) and superconductivity robust against in-plane magnetic fields. These phenomena can be discussed with the effects of weakened disorder and/or broken spacial inversion symmetry leading to valley-dependent spin-momentum locking (spin-valley locking). These examples suggest the superconducting 2D crystals are new platforms for investigating the intrinsic quantum phases as well as exotic nature in 2D superconductors.

  3. Band alignment of two-dimensional lateral heterostructures

    Science.gov (United States)

    Zhang, Junfeng; Xie, Weiyu; Zhao, Jijun; Zhang, Shengbai

    2017-03-01

    Recent experimental synthesis of two-dimensional (2D) heterostructures opens a door to new opportunities in tailoring the electronic properties for novel 2D devices. Here, we show that a wide range of lateral 2D heterostructures could have a prominent advantage over the traditional three-dimensional (3D) heterostructures, because their band alignments are insensitive to the interfacial conditions. They should be at the Schottky-Mott limits for semiconductor-metal junctions and at the Anderson limits for semiconductor junctions, respectively. This fundamental difference from the 3D heterostructures is rooted in the fact that, in the asymptotic limit of large distance, the effect of the interfacial dipole vanishes for 2D systems. Due to the slow decay of the dipole field and the dependence on the vacuum thickness, however, studies based on first-principles calculations often failed to reach such a conclusion. Taking graphene/hexagonal-BN and MoS2/WS2 lateral heterostructures as the respective prototypes, we show that the converged junction width can be order of magnitude longer than that for 3D junctions. The present results provide vital guidance to high-quality transport devices wherever a lateral 2D heterostructure is involved.

  4. Two-Dimensional Tail-Biting Convolutional Codes

    CERN Document Server

    Alfandary, Liam

    2011-01-01

    The multidimensional convolutional codes are an extension of the notion of convolutional codes (CCs) to several dimensions of time. This paper explores the class of two-dimensional convolutional codes (2D CCs) and 2D tail-biting convolutional codes (2D TBCCs), in particular, from several aspects. First, we derive several basic algebraic properties of these codes, applying algebraic methods in order to find bijective encoders, create parity check matrices and to inverse encoders. Next, we discuss the minimum distance and weight distribution properties of these codes. Extending an existing tree-search algorithm to two dimensions, we apply it to find codes with high minimum distance. Word-error probability asymptotes for sample codes are given and compared with other codes. The results of this approach suggest that 2D TBCCs can perform better than comparable 1D TBCCs or other codes. We then present several novel iterative suboptimal algorithms for soft decoding 2D CCs, which are based on belief propagation. Two ...

  5. Assessment of the Left Ventricular Systolic Function in Dilated Cardiomyopathy Patients by Two -dimensional Speckle Tracking Imaging( 2D - STI)%二维斑点追踪成像技术评价扩张型心肌病患者左心室心肌纵向收缩功能

    Institute of Scientific and Technical Information of China (English)

    黄俊; 胡元平; 宋樟伟; 杨炜宇; 徐瑞; 倪显达

    2012-01-01

    Objective To assess the left ventricular systolic function in patients with dilated cardiomyopathy ( DCM ) . Methods 35 healthy subjects and 39 dilated cardiomyopathy patients underwent conventional echocardiography examination. Left atrial ( LA) diameter were measured by M - mode echocardiography, left ventricular( LV) end - systolic volume, end - diastolic volume and left ventricular ejection fraction (LVEF) were calculated by bi -plane Simpson's method. The peak velocity during early diastole(Ve) and late diastole (Va) of anterior mitral valve were measured by pulse -waved doppler, and the ratio Ve/Va was calculated. We acquired the apical four - chamber, two - chamber and the long - axis views of the left ventricular images in these patients with GE - Vivid7 - dimension. Then the peak longitudinal velocity, strain and strain rate in systolic period were measured and recorded. Results The values of LAD, LVESV and LVEDV in DCM patients were significantly higher than those of healthy subjects (P 0. 05 ) . The peak velocity in systolic period of the base and middle LV segments in DCM patients were lower than those of the healthy subjects (P < 0. 05). The peak longitudinal strain and strain rate were significantly lower than healthy subjects (P < 0. 01). The peak velocity of the healthy subjects and the DCM patients were descent from the base to the apex. Conclusion The peak velocity, stain and strain rate of regional myocardial function in long - axis of left ventricular can be analyzed by 2D - STI, and it is a feasible technique for the assessment of cardiac longitudinal systolic function in DCM patients, and it can be widely used in the cardiac examination.%目的 评价二维斑点追踪成像技术(2D - STI)在扩张型心肌病(dilated cardiomyopathy,DCM)患者的左心室心肌纵向收缩功能应用价值.方法 对39例DCM患者和35例正常对照组行常规超声心动图检查得到左心房内径(LAD)、左心室射血分数(LVEF)、过二尖瓣口

  6. Interpolation by two-dimensional cubic convolution

    Science.gov (United States)

    Shi, Jiazheng; Reichenbach, Stephen E.

    2003-08-01

    This paper presents results of image interpolation with an improved method for two-dimensional cubic convolution. Convolution with a piecewise cubic is one of the most popular methods for image reconstruction, but the traditional approach uses a separable two-dimensional convolution kernel that is based on a one-dimensional derivation. The traditional, separable method is sub-optimal for the usual case of non-separable images. The improved method in this paper implements the most general non-separable, two-dimensional, piecewise-cubic interpolator with constraints for symmetry, continuity, and smoothness. The improved method of two-dimensional cubic convolution has three parameters that can be tuned to yield maximal fidelity for specific scene ensembles characterized by autocorrelation or power-spectrum. This paper illustrates examples for several scene models (a circular disk of parametric size, a square pulse with parametric rotation, and a Markov random field with parametric spatial detail) and actual images -- presenting the optimal parameters and the resulting fidelity for each model. In these examples, improved two-dimensional cubic convolution is superior to several other popular small-kernel interpolation methods.

  7. Structure and Two-dimensional Correlation Infrared Spectroscopy Study of a New One-dimensional Chain Compound:(4,4'-Hbpy)3[NaMo8O26] (4,4'-bpy)2(H2O)4 (bpy = Bipydine)

    Institute of Scientific and Technical Information of China (English)

    CHEN Yi-Ping; ZHANG Han-Hui; KE Da-Mei; SHEN Xiao-Min; HUANG Chang-Cang; SUN Rui-Qing

    2005-01-01

    A novel compound, (4,4'-Hbpy)3[NaMo8O26](4,4'-bpy)2(H2O)4 1 (bpy = bipydine),was synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that compound 1 belongs to the monoclinic system, space group C2/m with a = 19.1921(5), b = 18.6931(6), c = 9.3821 (3) (A), β = 104.8020(11)°, V = 3254.22(17) (A)3, C50H51Mo8N10NaO30, Mr = 2062.52, Z = 2,F(000) = 2016,μ = 1.591 mm- 1 and Dc = 2.105 g/cm3. The final R = 0.0283 and wR = 0.0912 for 3118 observed reflections (I > 2σ(Ⅰ)). Compound 1 contains the β-[Mo8O26]4- anion, sodium ion, 4,4'-bpy and lattice crystalline water molecules. The β-[Mo8O26] units link the sodium ion to form a chain structure. The infinitechains of [Na(Mo8O26)]3- blocks are surrounded by protonized 4,4'-bpy cations,4,4'-bpy and lattice crystalline water molecules. The 2D-IR correlation spectroscopy study indicates that the stretching vibrations of Mo=O occur more preferentially due to the thermal effect. The TGA analysis shows that compound 1 has high thermal stability.

  8. High resolution infrared synchrotron study of CH2D81Br: ground state constants and analysis of the ν5, ν6 and ν9 fundamentals

    Science.gov (United States)

    Baldacci, A.; Stoppa, P.; Visinoni, R.; Wugt Larsen, R.

    2012-09-01

    The high resolution infrared absorption spectrum of CH2D81Br has been recorded by Fourier transform spectroscopy in the range 550-1075 cm-1, with an unapodized resolution of 0.0025 cm-1, employing a synchrotron radiation source. This spectral region is characterized by the ν6 (593.872 cm-1), ν5 (768.710 cm-1) and ν9 (930.295 cm-1) fundamental bands. The ground state constants up to sextic centrifugal distortion terms have been obtained for the first time by ground-state combination differences from the three bands and subsequently employed for the evaluation of the excited state parameters. Watson's A-reduced Hamiltonian in the Ir representation has been used in the calculations. The ν 6 = 1 level is essentially free from perturbation whereas the ν 5 = 1 and ν 9 = 1 states are mutually interacting through a-type Coriolis coupling. Accurate spectroscopic parameters of the three excited vibrational states and a high-order coupling constant which takes into account the interaction between ν5 and ν9 have been determined.

  9. Epi-two-dimensional flow and generalized enstrophy

    CERN Document Server

    Yoshida, Zensho

    2016-01-01

    The conservation of the enstrophy ($L^2$ norm of the vorticity $\\omega$) plays an essential role in the physics and mathematics of two-dimensional (2D) Euler fluids. Generalizing to compressible ideal (inviscid and barotropic) fluids, the generalized enstrophy $\\int_{\\Sigma(t)} f(\\omega/\\rho)\\rho\\, d^2 x$, ($f$ an arbitrary smooth function, $\\rho$ the density, and $\\Sigma(t)$ an arbitrary 2D domain co-moving with the fluid) is a constant of motion, and plays the same role. On the other hand, for the three-dimensional (3D) ideal fluid, the helicity $\\int_{M} {V}\\cdot\\omega\\,d^3x$, ($V$ the flow velocity, $\\omega=\

  10. Two-dimensional atom localization induced by a squeezed vacuum

    Science.gov (United States)

    Wang, Fei; Xu, Jun

    2016-10-01

    A scheme of two-dimensional (2D) atom localization induced by a squeezed vacuum is proposed, in which the three-level V-type atoms interact with two classical standing-wave fields. It is found that when the environment is changed from an ordinary vacuum to a squeezed vacuum, the 2D atom localization is realized by detecting the position-dependent resonance fluorescence spectrum. For comparison, we demonstrate that the atom localization originating from the quantum interference effect is distinct from that induced by a squeezed vacuum. Furthermore, the combined effects of the squeezed vacuum and quantum interference are also discussed under appropriate conditions. The internal physical mechanism is analyzed in terms of dressed-state representation. Project supported by the National Natural Science Foundation of China (Grant Nos. 11574179 and 11204099) and the Natural Science Foundation of Hubei Province, China (Grant No. 2014CFC1148).

  11. Oriented Two-Dimensional Porous Organic Cage Crystals.

    Science.gov (United States)

    Jiang, Shan; Song, Qilei; Massey, Alan; Chong, Samantha Y; Chen, Linjiang; Sun, Shijing; Hasell, Tom; Raval, Rasmita; Sivaniah, Easan; Cheetham, Anthony K; Cooper, Andrew I

    2017-08-01

    The formation of two-dimensional (2D) oriented porous organic cage crystals (consisting of imine-based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution-processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth was obtained by experimental and computational techniques. For the first time, structural defects in porous molecular materials were observed directly and the defect concentration could be correlated with crystal growth rate. These oriented crystals suggest potential for future applications, such as solution-processable molecular crystalline 2D membranes for molecular separations. © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

  12. Thermal conductivity of disordered two-dimensional binary alloys.

    Science.gov (United States)

    Zhou, Yang; Guo, Zhi-Xin; Cao, Hai-Yuan; Chen, Shi-You; Xiang, Hong-Jun; Gong, Xin-Gao

    2016-10-20

    Using non-equilibrium molecular dynamics simulations, we have studied the effect of disorder on the thermal conductivity of two-dimensional (2D) C1-xNx alloys. We find that the thermal conductivity not only depends on the substitution concentration of nitrogen, but also strongly depends on the disorder distribution. A general linear relationship is revealed between the thermal conductivity and the participation ratio of phonons in 2D alloys. Localization mode analysis further indicates that the thermal conductivity variation in the ordered alloys can be attributed to the number of inequivalent atoms. As for the disordered alloys, we find that the thermal conductivity variation can be described by a simple linear formula with the disorder degree and the substitution concentration. The present study suggests some general guidance for phonon manipulation and thermal engineering in low dimensional alloys.

  13. Two-dimensional random arrays for real time volumetric imaging

    DEFF Research Database (Denmark)

    Davidsen, Richard E.; Jensen, Jørgen Arendt; Smith, Stephen W.

    1994-01-01

    Two-dimensional arrays are necessary for a variety of ultrasonic imaging techniques, including elevation focusing, 2-D phase aberration correction, and real time volumetric imaging. In order to reduce system cost and complexity, sparse 2-D arrays have been considered with element geometries...... real time volumetric imaging system, which employs a wide transmit beam and receive mode parallel processing to increase image frame rate. Depth-of-field comparisons were made from simulated on-axis and off-axis beamplots at ranges from 30 to 160 mm for both coaxial and offset transmit and receive...... selected ad hoc, by algorithm, or by random process. Two random sparse array geometries and a sparse array with a Mills cross receive pattern were simulated and compared to a fully sampled aperture with the same overall dimensions. The sparse arrays were designed to the constraints of the Duke University...

  14. Soliton nanoantennas in two-dimensional arrays of quantum dots

    CERN Document Server

    Gligorić, G; Hadžievski, Lj; Slepyan, G Ya; Malomed, B A

    2015-01-01

    We consider two-dimensional (2D) arrays of self-organized semiconductor quantum dots (QDs) strongly interacting with electromagnetic field in the regime of Rabi oscillations. The QD array built of two-level states is modelled by two coupled systems of discrete nonlinear Schr\\"{o}dinger equations. Localized modes in the form of single-peaked fundamental and vortical stationary Rabi solitons and self-trapped breathers have been found. The results for the stability, mobility and radiative properties of the Rabi modes suggest a concept of a self-assembled 2D \\textit{% soliton-based nano-antenna}, which should be stable against imperfections In particular, we discuss the implementation of such a nano-antenna in the form of surface plasmon solitons in graphene, and illustrate possibilities to control their operation by means of optical tools.

  15. Design of two-dimensional digital filters using neural networks

    Institute of Scientific and Technical Information of China (English)

    Wang Xiaohua; He Yigang

    2005-01-01

    A new approach for the design of two-dimensional (2-D) linear phase FIR digital filters based on a new neural networks algorithm (NNA) is provided. A compact expression for the transfer function of a 2-D linear phase FIR filter is derived based on its frequency response characteristic, and the NNA, based on minimizing the square-error in the frequency-domain, is established according to the compact expression. To illustrate the stability of the NNA, the convergence theorem is presented and proved. Design examples are also given, and the results show that the ripple is considerably small in passband and stopband, and the NNA-based method is of powerful stability and requires quite little amount of computations.

  16. Two-dimensional spatial patterning in developmental systems.

    Science.gov (United States)

    Torii, Keiko U

    2012-08-01

    Multicellular organisms produce complex tissues with specialized cell types. During animal development, numerous cell-cell interactions shape tissue patterning through mechanisms involving contact-dependent cell migration and ligand-receptor-mediated lateral inhibition. Owing to the presence of cell walls, plant cells neither migrate nor undergo apoptosis as a means to correct for mis-specified cells. How can plants generate functional tissue patterns? This review aims to deduce fundamental principles of pattern formation through examining two-dimensional (2-D) spatial tissue patterning in plants and animals. Turing's mathematical framework will be introduced and applied to classic examples of de novo 2-D patterning in both animal and plant systems. By comparing their regulatory circuits, new insights into the similarities and differences of the basic principles governing tissue patterning will be discussed. Copyright © 2012 Elsevier Ltd. All rights reserved.

  17. Ultrabroadband two-quantum two-dimensional electronic spectroscopy

    Science.gov (United States)

    Gellen, Tobias A.; Bizimana, Laurie A.; Carbery, William P.; Breen, Ilana; Turner, Daniel B.

    2016-08-01

    A recent theoretical study proposed that two-quantum (2Q) two-dimensional (2D) electronic spectroscopy should be a background-free probe of post-Hartree-Fock electronic correlations. Testing this theoretical prediction requires an instrument capable of not only detecting multiple transitions among molecular excited states but also distinguishing molecular 2Q signals from nonresonant response. Herein we describe a 2Q 2D spectrometer with a spectral range of 300 nm that is passively phase stable and uses only beamsplitters and mirrors. We developed and implemented a dual-chopping balanced-detection method to resolve the weak molecular 2Q signals. Experiments performed on cresyl violet perchlorate and rhodamine 6G revealed distinct 2Q signals convolved with nonresonant response. Density functional theory computations helped reveal the molecular origin of these signals. The experimental and computational results demonstrate that 2Q electronic spectra can provide a singular probe of highly excited electronic states.

  18. Two-Dimensional Hexagonal Transition-Metal Oxide for Spintronics.

    Science.gov (United States)

    Kan, Erjun; Li, Ming; Hu, Shuanglin; Xiao, Chuanyun; Xiang, Hongjun; Deng, Kaiming

    2013-04-04

    Two-dimensional materials have been the hot subject of studies due to their great potential in applications. However, their applications in spintronics have been blocked by the difficulty in producing ordered spin structures in 2D structures. Here we demonstrated that the ultrathin films of recently experimentally realized wurtzite MnO can automatically transform into a stable graphitic structure with ordered spin arrangement via density functional calculation, and the stability of graphitic structure can be enhanced by external strain. Moreover, the antiferromagnetic ordering of graphitic MnO single layer can be switched into half-metallic ferromagnetism by small hole-doping, and the estimated Curie temperature is higher than 300 K. Thus, our results highlight a promising way toward 2D magnetic materials.

  19. Review—Two-Dimensional Layered Materials for Energy Storage Applications

    KAUST Repository

    Kumar, Pushpendra

    2016-07-02

    Rechargeable batteries are most important energy storage devices in modern society with the rapid development and increasing demand for handy electronic devices and electric vehicles. The higher surface-to-volume ratio two-dimensional (2D) materials, especially transition metal dichalcogenides (TMDCs) and transition metal carbide/nitrite generally referred as MXene, have attracted intensive research activities due to their fascinating physical/chemical properties with extensive applications. One of the growing applications is to use these 2D materials as potential electrodes for rechargeable batteries and electrochemical capacitors. This review is an attempt to summarize the research and development of TMDCs, MXenes and their hybrid structures in energy storage systems. (C) The Author(s) 2016. Published by ECS. All rights reserved.

  20. TWO-DIMENSIONAL TOPOLOGY OF COSMOLOGICAL REIONIZATION

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yougang; Xu, Yidong; Chen, Xuelei [Key Laboratory of Computational Astrophysics, National Astronomical Observatories, Chinese Academy of Sciences, Beijing, 100012 China (China); Park, Changbom [School of Physics, Korea Institute for Advanced Study, 85 Hoegiro, Dongdaemun-gu, Seoul 130-722 (Korea, Republic of); Kim, Juhan, E-mail: wangyg@bao.ac.cn, E-mail: cbp@kias.re.kr [Center for Advanced Computation, Korea Institute for Advanced Study, 85 Hoegiro, Dongdaemun-gu, Seoul 130-722 (Korea, Republic of)

    2015-11-20

    We study the two-dimensional topology of the 21-cm differential brightness temperature for two hydrodynamic radiative transfer simulations and two semi-numerical models. In each model, we calculate the two-dimensional genus curve for the early, middle, and late epochs of reionization. It is found that the genus curve depends strongly on the ionized fraction of hydrogen in each model. The genus curves are significantly different for different reionization scenarios even when the ionized faction is the same. We find that the two-dimensional topology analysis method is a useful tool to constrain the reionization models. Our method can be applied to the future observations such as those of the Square Kilometre Array.

  1. Two dimensional topology of cosmological reionization

    CERN Document Server

    Wang, Yougang; Xu, Yidong; Chen, Xuelei; Kim, Juhan

    2015-01-01

    We study the two-dimensional topology of the 21-cm differential brightness temperature for two hydrodynamic radiative transfer simulations and two semi-numerical models. In each model, we calculate the two dimensional genus curve for the early, middle and late epochs of reionization. It is found that the genus curve depends strongly on the ionized fraction of hydrogen in each model. The genus curves are significantly different for different reionization scenarios even when the ionized faction is the same. We find that the two-dimensional topology analysis method is a useful tool to constrain the reionization models. Our method can be applied to the future observations such as those of the Square Kilometer Array.

  2. On final states of two-dimensional decaying turbulence

    Science.gov (United States)

    Yin, Z.

    2004-12-01

    Numerical and analytical studies of final states of two-dimensional (2D) decaying turbulence are carried out. The first part of this work is trying to give a definition for final states of 2D decaying turbulence. The functional relation of ω-ψ, which is frequently adopted as the characterization of those final states, is merely a sufficient but not necessary condition; moreover, it is not proper to use it as the definition. It is found that the method through the value of the effective area S covered by the scatter ω-ψ plot, initially suggested by Read, Rhines, and White ["Geostrophic scatter diagrams and potential vorticity dynamics," J. Atmos. Sci. 43, 3226 (1986)] is more general and suitable for the definition. Based on this concept, a definition is presented, which covers all existing results in late states of decaying 2D flows (including some previous unexplainable weird double-valued ω-ψ scatter plots). The remaining part of the paper is trying to further study 2D decaying turbulence with the assistance of this definition. Some numerical results, leading to "bar" final states and further verifying the predictive ability of statistical mechanics [Yin, Montgomery, and Clercx, "Alternative statistical-mechanical descriptions of decaying two-dimensional turbulence in terms of patches and points," Phys. Fluids 15, 1937 (2003)], are reported. It is realized that some simulations with narrow-band energy spectral initial conditions result in some final states that cannot be very well interpreted by the statistical theory (meanwhile, those final states are still in the scope of the definition).

  3. Materials synthesis: Two-dimensional gallium nitride

    Science.gov (United States)

    Koratkar, Nikhil A.

    2016-11-01

    Graphene is used as a capping sheet to synthesize 2D gallium nitride by means of migration-enhanced encapsulation growth. This technique may allow the stabilization of 2D materials that are not amenable to synthesis by traditional methods.

  4. Atom-Based Geometrical Fingerprinting of Conformal Two-Dimensional Materials

    Science.gov (United States)

    Mehboudi, Mehrshad

    The shape of two-dimensional materials plays a significant role on their chemical and physical properties. Two-dimensional materials are basic meshes that are formed by mesh points (vertices) given by atomic positions, and connecting lines (edges) between points given by chemical bonds. Therefore the study of local shape and geometry of two-dimensional materials is a fundamental prerequisite to investigate physical and chemical properties. Hereby the use of discrete geometry to discuss the shape of two-dimensional materials is initiated. The local geometry of a surface embodied in 3D space is determined using four invariant numbers from the metric and curvature tensors which indicates how much the surface is stretched and curved under a deformation as compared to a reference pre-deformed conformation. Many different disciplines advance theories on conformal two-dimensional materials by relying on continuum mechanics and fitting continuum surfaces to the shape of conformal two-dimensional materials. However two-dimensional materials are inherently discrete. The continuum models are only applicable when the size of two-dimensional materials is significantly large and the deformation is less than a few percent. In this research, the knowledge of discrete differential geometry was used to tell the local shape of conformal two-dimensional materials. Three kind of two-dimensional materials are discussed: 1) one atom thickness structures such as graphene and hexagonal boron nitride; 2) high and low buckled 2D meshes like stanene, leadene, aluminum phosphate; and, 3) multi layer 2D materials such as Bi2Se3 and WSe2. The lattice structures of these materials were created by designing a mechanical model - the mechanical model was devised in the form of a Gaussian bump and density-functional theory was used to inform the local height; and, the local geometries are also discussed.

  5. Image interpolation by two-dimensional parametric cubic convolution.

    Science.gov (United States)

    Shi, Jiazheng; Reichenbach, Stephen E

    2006-07-01

    Cubic convolution is a popular method for image interpolation. Traditionally, the piecewise-cubic kernel has been derived in one dimension with one parameter and applied to two-dimensional (2-D) images in a separable fashion. However, images typically are statistically nonseparable, which motivates this investigation of nonseparable cubic convolution. This paper derives two new nonseparable, 2-D cubic-convolution kernels. The first kernel, with three parameters (designated 2D-3PCC), is the most general 2-D, piecewise-cubic interpolator defined on [-2, 2] x [-2, 2] with constraints for biaxial symmetry, diagonal (or 90 degrees rotational) symmetry, continuity, and smoothness. The second kernel, with five parameters (designated 2D-5PCC), relaxes the constraint of diagonal symmetry, based on the observation that many images have rotationally asymmetric statistical properties. This paper also develops a closed-form solution for determining the optimal parameter values for parametric cubic-convolution kernels with respect to ensembles of scenes characterized by autocorrelation (or power spectrum). This solution establishes a practical foundation for adaptive interpolation based on local autocorrelation estimates. Quantitative fidelity analyses and visual experiments indicate that these new methods can outperform several popular interpolation methods. An analysis of the error budgets for reconstruction error associated with blurring and aliasing illustrates that the methods improve interpolation fidelity for images with aliased components. For images with little or no aliasing, the methods yield results similar to other popular methods. Both 2D-3PCC and 2D-5PCC are low-order polynomials with small spatial support and so are easy to implement and efficient to apply.

  6. Matching Two-dimensional Gel Electrophoresis' Spots

    DEFF Research Database (Denmark)

    Dos Anjos, António; AL-Tam, Faroq; Shahbazkia, Hamid Reza

    2012-01-01

    This paper describes an approach for matching Two-Dimensional Electrophoresis (2-DE) gels' spots, involving the use of image registration. The number of false positive matches produced by the proposed approach is small, when compared to academic and commercial state-of-the-art approaches. This ar......This paper describes an approach for matching Two-Dimensional Electrophoresis (2-DE) gels' spots, involving the use of image registration. The number of false positive matches produced by the proposed approach is small, when compared to academic and commercial state-of-the-art approaches...

  7. Mobility anisotropy of two-dimensional semiconductors

    Science.gov (United States)

    Lang, Haifeng; Zhang, Shuqing; Liu, Zhirong

    2016-12-01

    The carrier mobility of anisotropic two-dimensional semiconductors under longitudinal acoustic phonon scattering was theoretically studied using deformation potential theory. Based on the Boltzmann equation with the relaxation time approximation, an analytic formula of intrinsic anisotropic mobility was derived, showing that the influence of effective mass on mobility anisotropy is larger than those of deformation potential constant or elastic modulus. Parameters were collected for various anisotropic two-dimensional materials (black phosphorus, Hittorf's phosphorus, BC2N , MXene, TiS3, and GeCH3) to calculate their mobility anisotropy. It was revealed that the anisotropic ratio is overestimated by the previously described method.

  8. Towards two-dimensional search engines

    OpenAIRE

    Ermann, Leonardo; Chepelianskii, Alexei D.; Shepelyansky, Dima L.

    2011-01-01

    We study the statistical properties of various directed networks using ranking of their nodes based on the dominant vectors of the Google matrix known as PageRank and CheiRank. On average PageRank orders nodes proportionally to a number of ingoing links, while CheiRank orders nodes proportionally to a number of outgoing links. In this way the ranking of nodes becomes two-dimensional that paves the way for development of two-dimensional search engines of new type. Statistical properties of inf...

  9. The two dimensional fold test in paleomagnetism using ipython notebook

    Science.gov (United States)

    Setiabudidaya, Dedi; Piper, John D. A.

    2016-01-01

    One aspect of paleomagnetic analysis prone to controversy is the result of the fold test used to evaluate the age of a magnetisation component relative to the age of a structural event. Initially, the fold test was conducted by comparing the Fisherian precision parameter (k) to results from different limbs of a fold structure before and after tilt adjustment. To accommodate synfolding magnetisation, the tilt correction can be performed in stepwise fashion to both limbs simultaneously, here called one dimensional (1D) fold test. The two dimensional (2D) fold test described in this paper is carried out by applying stepwise tilt adjustment to each limb of the fold separately. The rationale for this is that tilts observed on contrasting limbs of deformed structure may not be synchronous or even belong to the same episode of deformation. A program for the procedure is presented here which generates two dimensional values of the k-parameter visually presented in contoured form. The use of ipython notebook enables this 2D fold test to be performed interactively and yield a more precise evaluation than the primitive 1D fold test.

  10. Comprehensive two-dimensional liquid chromatographic analysis of poloxamers.

    Science.gov (United States)

    Malik, Muhammad Imran; Lee, Sanghoon; Chang, Taihyun

    2016-04-15

    Poloxamers are low molar mass triblock copolymers of poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO), having number of applications as non-ionic surfactants. Comprehensive one and two-dimensional liquid chromatographic (LC) analysis of these materials is proposed in this study. The separation of oligomers of both types (PEO and PPO) is demonstrated for several commercial poloxamers. This is accomplished at the critical conditions for one of the block while interaction for the other block. Reversed phase LC at CAP of PEO allowed for oligomeric separation of triblock copolymers with regard to PPO block whereas normal phase LC at CAP of PPO renders oligomeric separation with respect to PEO block. The oligomeric separation with regard to PEO and PPO are coupled online (comprehensive 2D-LC) to reveal two-dimensional contour plots by unconventional 2D IC×IC (interaction chromatography) coupling. The study provides chemical composition mapping of both PEO and PPO, equivalent to combined molar mass and chemical composition mapping for several commercial poloxamers.

  11. Kronecker Product of Two-dimensional Arrays

    Institute of Scientific and Technical Information of China (English)

    Lei Hu

    2006-01-01

    Kronecker sequences constructed from short sequences are good sequences for spread spectrum communication systems. In this paper we study a similar problem for two-dimensional arrays, and we determine the linear complexity of the Kronecker product of two arrays. Our result shows that similar good property on linear complexity holds for Kronecker product of arrays.

  12. Two-Dimensional Toda-Heisenberg Lattice

    Directory of Open Access Journals (Sweden)

    Vadim E. Vekslerchik

    2013-06-01

    Full Text Available We consider a nonlinear model that is a combination of the anisotropic two-dimensional classical Heisenberg and Toda-like lattices. In the framework of the Hirota direct approach, we present the field equations of this model as a bilinear system, which is closely related to the Ablowitz-Ladik hierarchy, and derive its N-soliton solutions.

  13. A novel two dimensional particle velocity sensor

    NARCIS (Netherlands)

    Pjetri, Olti; Wiegerink, Remco J.; Lammerink, Theo S.; Krijnen, Gijs J.

    2013-01-01

    In this paper we present a two wire, two-dimensional particle velocity sensor. The miniature sensor of size 1.0x2.5x0.525 mm, consisting of only two crossed wires, shows excellent directional sensitivity in both directions, thus requiring no directivity calibration, and is relatively easy to fabrica

  14. Two-dimensional microstrip detector for neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Oed, A. [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1997-04-01

    Because of their robust design, gas microstrip detectors, which were developed at ILL, can be assembled relatively quickly, provided the prefabricated components are available. At the beginning of 1996, orders were received for the construction of three two-dimensional neutron detectors. These detectors have been completed. The detectors are outlined below. (author). 2 refs.

  15. Two-dimensional magma-repository interactions

    NARCIS (Netherlands)

    Bokhove, O.

    2001-01-01

    Two-dimensional simulations of magma-repository interactions reveal that the three phases --a shock tube, shock reflection and amplification, and shock attenuation and decay phase-- in a one-dimensional flow tube model have a precursor. This newly identified phase ``zero'' consists of the impact of

  16. Performance Estimation for Two-Dimensional Brownian Rotary Ratchet Systems

    Science.gov (United States)

    Tutu, Hiroki; Horita, Takehiko; Ouchi, Katsuya

    2015-04-01

    Within the context of the Brownian ratchet model, a molecular rotary system that can perform unidirectional rotations induced by linearly polarized ac fields and produce positive work under loads was studied. The model is based on the Langevin equation for a particle in a two-dimensional (2D) three-tooth ratchet potential of threefold symmetry. The performance of the system is characterized by the coercive torque, i.e., the strength of the load competing with the torque induced by the ac driving field, and the energy efficiency in force conversion from the driving field to the torque. We propose a master equation for coarse-grained states, which takes into account the boundary motion between states, and develop a kinetic description to estimate the mean angular momentum (MAM) and powers relevant to the energy balance equation. The framework of analysis incorporates several 2D characteristics and is applicable to a wide class of models of smooth 2D ratchet potential. We confirm that the obtained expressions for MAM, power, and efficiency of the model can enable us to predict qualitative behaviors. We also discuss the usefulness of the torque/power relationship for experimental analyses, and propose a characteristic for 2D ratchet systems.

  17. Filtering and control for classes of two-dimensional systems

    CERN Document Server

    Wu, Ligang

    2015-01-01

    This book focuses on filtering, control and model-reduction problems for two-dimensional (2-D) systems with imperfect information. The time-delayed 2-D systems covered have system parameters subject to uncertain, stochastic and parameter-varying changes. After an initial introduction of 2-D systems and the ideas of linear repetitive processes, the text is divided into two parts detailing: ·         general theory and methods of analysis and optimal synthesis for 2-D systems; and ·         application of the general theory to the particular case of differential/discrete linear repetitive processes. The methods developed provide a framework for stability and performance analysis, optimal and robust controller and filter design and model approximation for the systems considered. Solutions to the design problems are couched in terms of linear matrix inequalities. For readers interested in the state of the art in linear filtering, control and model reduction, Filtering and Control for Classes of ...

  18. Two-dimensional state in driven magnetohydrodynamic turbulence.

    Science.gov (United States)

    Bigot, Barbara; Galtier, Sébastien

    2011-02-01

    The dynamics of the two-dimensional (2D) state in driven three-dimensional (3D) incompressible magnetohydrodynamic turbulence is investigated through high-resolution direct numerical simulations and in the presence of an external magnetic field at various intensities. For such a flow the 2D state (or slow mode) and the 3D modes correspond, respectively, to spectral fluctuations in the plane k(∥)=0 and in the area k(∥)>0. It is shown that if initially the 2D state is set to zero it becomes nonnegligible in few turnover times, particularly when the external magnetic field is strong. The maintenance of a large-scale driving leads to a break for the energy spectra of 3D modes; when the driving is stopped, the previous break is removed and a decay phase emerges with Alfvénic fluctuations. For a strong external magnetic field the energy at large perpendicular scales lies mainly in the 2D state, and in all situations a pinning effect is observed at small scales.

  19. Two dimensional electron spin resonance: Structure and dynamics of biomolecules

    Science.gov (United States)

    Saxena, Sunil; Freed, Jack H.

    1998-03-01

    The potential of two dimensional (2D) electron spin resonance (ESR) for measuring the structural properties and slow dynamics of labeled biomolecules will be presented. Specifically, it will be shown how the recently developed method of double quantum (DQ) 2D ESR (S. Saxena and J. H. Freed, J. Chem. Phys. 107), 1317, (1997) can be used to measure large interelectron distances in bilabeled peptides. The need for DQ ESR spectroscopy, as well as the challenges and advantages of this method will be discussed. The elucidation of the slow reorientational dynamics of this peptide (S. Saxena and J. H. Freed, J. Phys. Chem. A, 101) 7998 (1997) in a glassy medium using COSY and 2D ELDOR ESR spectroscopy will be demonstrated. The contributions to the homogeneous relaxation time, T_2, from the overall and/or internal rotations of the nitroxide can be distinguished from the COSY spectrum. The growth of spectral diffusion cross-peaks^2 with mixing time in the 2D ELDOR spectra can be used to directly determine a correlation time from the experiment which can be related to the rotational correlation time.

  20. Low-cost two-dimensional gel densitometry.

    Science.gov (United States)

    Levenson, R M; Maytin, E V; Young, D A

    1986-11-01

    A major obstacle to full utilization of the powerful technique of two-dimensional (2-D) gel electrophoresis is the expense and complexity of quantifying the results. Using an analog-to-digital converter already present in the widely available Commodore 64 or Commodore 128 microcomputer, we have developed a 2-D gel densitometer (GELSCAN) which adds only $20.00 to the cost of the Commodore system (currently around $700.00). The system is designed to work with autoradiograms of 2-D gels. Spots of interest are identified visually and then positioned manually over a light source. A pinhole photoelectric sensor mounted in a hand-held, Plexiglas holder, or "mouse," is briefly rubbed over each spot. Maximum density of the spot is determined and its value is converted to counts per minute via an internal calibration curve which corrects for the nonlinear response of film to radiation. Local spot backgrounds can be subtracted and values can be normalized between gels to adjust for variation in amount of radioactivity applied or in exposure time. Reproducibility is excellent and the technique has some practical as well as theoretical advantages over other more complicated approaches to 2-D gel densitometry. In addition, the GELSCAN system can also be used for scanning individual bands in 1-D gels, quantitation of "dot-blot" autoradiograms and other tasks involving transmission densitometry.

  1. Two-Dimensional Halide Perovskites: Tuning Electronic Activities of Defects.

    Science.gov (United States)

    Liu, Yuanyue; Xiao, Hai; Goddard, William A

    2016-05-11

    Two-dimensional (2D) halide perovskites are emerging as promising candidates for nanoelectronics and optoelectronics. To realize their full potential, it is important to understand the role of those defects that can strongly impact material properties. In contrast to other popular 2D semiconductors (e.g., transition metal dichalcogenides MX2) for which defects typically induce harmful traps, we show that the electronic activities of defects in 2D perovskites are significantly tunable. For example, even with a fixed lattice orientation one can change the synthesis conditions to convert a line defect (edge or grain boundary) from electron acceptor to inactive site without deep gap states. We show that this difference originates from the enhanced ionic bonding in these perovskites compared with MX2. The donors tend to have high formation energies and the harmful defects are difficult to form at a low halide chemical potential. Thus, we unveil unique properties of defects in 2D perovskites and suggest practical routes to improve them.

  2. Broken Ergodicity in Two-Dimensional Homogeneous Magnetohydrodynamic Turbulence

    Science.gov (United States)

    Shebalin, John V.

    2010-01-01

    Two-dimensional (2-D) homogeneous magnetohydrodynamic (MHD) turbulence has many of the same qualitative features as three-dimensional (3-D) homogeneous MHD turbulence.The se features include several ideal invariants, along with the phenomenon of broken ergodicity. Broken ergodicity appears when certain modes act like random variables with mean values that are large compared to their standard deviations, indicating a coherent structure or dynamo.Recently, the origin of broken ergodicity in 3-D MHD turbulence that is manifest in the lowest wavenumbers was explained. Here, a detailed description of the origins of broken ergodicity in 2-D MHD turbulence is presented. It will be seen that broken ergodicity in ideal 2-D MHD turbulence can be manifest in the lowest wavenumbers of a finite numerical model for certain initial conditions or in the highest wavenumbers for another set of initial conditions.T he origins of broken ergodicity in ideal 2-D homogeneous MHD turbulence are found through an eigen analysis of the covariance matrices of the modal probability density functions.It will also be shown that when the lowest wavenumber magnetic field becomes quasi-stationary, the higher wavenumber modes can propagate as Alfven waves on these almost static large-scale magnetic structures

  3. Photonics and optoelectronics of two-dimensional materials beyond graphene

    Science.gov (United States)

    Ponraj, Joice Sophia; Xu, Zai-Quan; Chander Dhanabalan, Sathish; Mu, Haoran; Wang, Yusheng; Yuan, Jian; Li, Pengfei; Thakur, Siddharatha; Ashrafi, Mursal; Mccoubrey, Kenneth; Zhang, Yupeng; Li, Shaojuan; Zhang, Han; Bao, Qiaoliang

    2016-11-01

    Apart from conventional materials, the study of two-dimensional (2D) materials has emerged as a significant field of study for a variety of applications. Graphene-like 2D materials are important elements of potential optoelectronics applications due to their exceptional electronic and optical properties. The processing of these materials towards the realization of devices has been one of the main motivations for the recent development of photonics and optoelectronics. The recent progress in photonic devices based on graphene-like 2D materials, especially topological insulators (TIs) and transition metal dichalcogenides (TMDs) with the methodology level discussions from the viewpoint of state-of-the-art designs in device geometry and materials are detailed in this review. We have started the article with an overview of the electronic properties and continued by highlighting their linear and nonlinear optical properties. The production of TIs and TMDs by different methods is detailed. The following main applications focused towards device fabrication are elaborated: (1) photodetectors, (2) photovoltaic devices, (3) light-emitting devices, (4) flexible devices and (5) laser applications. The possibility of employing these 2D materials in different fields is also suggested based on their properties in the prospective part. This review will not only greatly complement the detailed knowledge of the device physics of these materials, but also provide contemporary perception for the researchers who wish to consider these materials for various applications by following the path of graphene.

  4. Anisotropic dielectric properties of two-dimensional matrix in pseudo-spin ferroelectric system

    Science.gov (United States)

    Kim, Se-Hun

    2016-10-01

    The anisotropic dielectric properties of a two-dimensional (2D) ferroelectric system were studied using the statistical calculation of the pseudo-spin Ising Hamiltonian model. It is necessary to delay the time for measurements of the observable and the independence of the new spin configuration under Monte Carlo sampling, in which the thermal equilibrium state depends on the temperature and size of the system. The autocorrelation time constants of the normalized relaxation function were determined by taking temperature and 2D lattice size into account. We discuss the dielectric constants of a two-dimensional ferroelectric system by using the Metropolis method in view of the Slater-Takagi defect energies.

  5. Non-Linear Non Stationary Analysis of Two-Dimensional Time-Series Applied to GRACE Data Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed innovative two-dimensional (2D) adaptive analysis will be tested NASA's Gravity Recovery and Climate Experiment (GRACE) mission database in phase I in...

  6. Non-Linear Non Stationary Analysis of Two-Dimensional Time-Series Applied to GRACE Data Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed innovative two-dimensional (2D) empirical mode decomposition (EMD) analysis was applied to NASA's Gravity Recovery and Climate Experiment (GRACE)...

  7. Two-dimensional graphene analogues for biomedical applications.

    Science.gov (United States)

    Chen, Yu; Tan, Chaoliang; Zhang, Hua; Wang, Lianzhou

    2015-05-07

    The increasing demand of clinical biomedicine and fast development of nanobiotechnology has substantially promoted the generation of a variety of organic/inorganic nanosystems for biomedical applications. Biocompatible two-dimensional (2D) graphene analogues (e.g., nanosheets of transition metal dichalcogenides, transition metal oxides, g-C3N4, Bi2Se3, BN, etc.), which are referred to as 2D-GAs, have emerged as a new unique family of nanomaterials that show unprecedented advantages and superior performances in biomedicine due to their unique compositional, structural and physicochemical features. In this review, we summarize the state-of-the-art progress of this dynamically developed material family with a particular focus on biomedical applications. After the introduction, the second section of the article summarizes a range of synthetic methods for new types of 2D-GAs as well as their surface functionalization. The subsequent section provides a snapshot on the use of these biocompatible 2D-GAs for a broad spectrum of biomedical applications, including therapeutic (photothermal/photodynamic therapy, chemotherapy and synergistic therapy), diagnostic (fluorescent/magnetic resonance/computed tomography/photoacoustic imaging) and theranostic (concurrent diagnostic imaging and therapy) applications, especially on oncology. In addition, we briefly present the biosensing applications of these 2D-GAs for the detection of biomacromolecules and their in vitro/in vivo biosafety evaluations. The last section summarizes some critical unresolved issues, possible challenges/obstacles and also proposes future perspectives related to the rational design and construction of 2D-GAs for biomedical engineering, which are believed to promote their clinical translations for benefiting the personalized medicine and human health.

  8. Two-dimensional materials for novel liquid separation membranes

    Science.gov (United States)

    Ying, Yulong; Yang, Yefeng; Ying, Wen; Peng, Xinsheng

    2016-08-01

    Demand for a perfect molecular-level separation membrane with ultrafast permeation and a robust mechanical property for any kind of species to be blocked in water purification and desalination is urgent. In recent years, due to their intrinsic characteristics, such as a unique mono-atom thick structure, outstanding mechanical strength and excellent flexibility, as well as facile and large-scale production, graphene and its large family of two-dimensional (2D) materials are regarded as ideal membrane materials for ultrafast molecular separation. A perfect separation membrane should be as thin as possible to maximize its flux, mechanically robust and without failure even if under high loading pressure, and have a narrow nanochannel size distribution to guarantee its selectivity. The latest breakthrough in 2D material-based membranes will be reviewed both in theories and experiments, including their current state-of-the-art fabrication, structure design, simulation and applications. Special attention will be focused on the designs and strategies employed to control microstructures to enhance permeation and selectivity for liquid separation. In addition, critical views on the separation mechanism within two-dimensional material-based membranes will be provided based on a discussion of the effects of intrinsic defects during growth, predefined nanopores and nanochannels during subsequent fabrication processes, the interlayer spacing of stacking 2D material flakes and the surface charge or functional groups. Furthermore, we will summarize the significant progress of these 2D material-based membranes for liquid separation in nanofiltration/ultrafiltration and pervaporation. Lastly, we will recall issues requiring attention, and discuss existing questionable conclusions in some articles and emerging challenges. This review will serve as a valuable platform to provide a compact source of relevant and timely information about the development of 2D material-based membranes as

  9. Defect Characterization Using Two-Dimensional Arrays

    Science.gov (United States)

    Velichko, A.; Wilcox, P. D.

    2011-06-01

    2D arrays are able to `view' a given defect from a range of angles leading to the possibility of obtaining richer characterization detail than possible with 1D arrays. In this paper a quantitative comparison of 2D arrays with different element layouts is performed. A technique for extracting the scattering matrix of a defect from the raw 2D array data is also presented. The method is tested on experimental data for characterization of various volumetric defects.

  10. Synthesis of two-dimensional materials by selective extraction.

    Science.gov (United States)

    Naguib, Michael; Gogotsi, Yury

    2015-01-20

    CONSPECTUS: Two-dimensional (2D) materials have attracted much attention in the past decade. They offer high specific surface area, as well as electronic structure and properties that differ from their bulk counterparts due to the low dimensionality. Graphene is the best known and the most studied 2D material, but metal oxides and hydroxides (including clays), dichalcogenides, boron nitride (BN), and other materials that are one or several atoms thick are receiving increasing attention. They may deliver a combination of properties that cannot be provided by other materials. The most common synthesis approach in general is by reacting different elements or compounds to form a new compound. However, this approach does not necessarily work well for low-dimensional structures, since it favors formation of energetically preferred 3D (bulk) solids. Many 2D materials are produced by exfoliation of van der Waals solids, such as graphite or MoS2, breaking large particles into 2D layers. However, these approaches are not universal; for example, 2D transition metal carbides cannot be produced by any of them. An alternative but less studied way of material synthesis is the selective extraction process, which is based on the difference in reactivity and stability between the different components (elements or structural units) of the original material. It can be achieved using thermal, chemical, or electrochemical processes. Many 2D materials have been synthesized using selective extraction, such as graphene from SiC, transition metal oxides (TMO) from layered 3D salts, and transition metal carbides or carbonitrides (MXenes) from MAX phases. Selective extraction synthesis is critically important when the bonds between the building blocks of the material are too strong (e.g., in carbides) to be broken mechanically in order to form nanostructures. Unlike extractive metallurgy, where the extracted metal is the goal of the process, selective extraction of one or more elements from

  11. Comparison of Free Spectral Range and Quality Factor for Two-Dimensional Square and Circular Microcavities

    Institute of Scientific and Technical Information of China (English)

    国伟华; 黄永箴; 陆巧银; 于丽娟

    2004-01-01

    Free spectral range of whispering-gallery (WG)-like modes in a two-dimensional (2D) square microcavity is found to be twice that in a 2D circular microcavity. The quality factor of the WG-like mode with the low mode number in a 2D square microcavity, calculated by the finite-difference time-domain (FDTD) technique and the Pade approximation method, is found to exceed that of the WG mode in 2D circular microcavity with the same cavity dimension and close mode wavelength.

  12. Electronics based on two-dimensional materials.

    Science.gov (United States)

    Fiori, Gianluca; Bonaccorso, Francesco; Iannaccone, Giuseppe; Palacios, Tomás; Neumaier, Daniel; Seabaugh, Alan; Banerjee, Sanjay K; Colombo, Luigi

    2014-10-01

    The compelling demand for higher performance and lower power consumption in electronic systems is the main driving force of the electronics industry's quest for devices and/or architectures based on new materials. Here, we provide a review of electronic devices based on two-dimensional materials, outlining their potential as a technological option beyond scaled complementary metal-oxide-semiconductor switches. We focus on the performance limits and advantages of these materials and associated technologies, when exploited for both digital and analog applications, focusing on the main figures of merit needed to meet industry requirements. We also discuss the use of two-dimensional materials as an enabling factor for flexible electronics and provide our perspectives on future developments.

  13. Two-dimensional ranking of Wikipedia articles

    Science.gov (United States)

    Zhirov, A. O.; Zhirov, O. V.; Shepelyansky, D. L.

    2010-10-01

    The Library of Babel, described by Jorge Luis Borges, stores an enormous amount of information. The Library exists ab aeterno. Wikipedia, a free online encyclopaedia, becomes a modern analogue of such a Library. Information retrieval and ranking of Wikipedia articles become the challenge of modern society. While PageRank highlights very well known nodes with many ingoing links, CheiRank highlights very communicative nodes with many outgoing links. In this way the ranking becomes two-dimensional. Using CheiRank and PageRank we analyze the properties of two-dimensional ranking of all Wikipedia English articles and show that it gives their reliable classification with rich and nontrivial features. Detailed studies are done for countries, universities, personalities, physicists, chess players, Dow-Jones companies and other categories.

  14. Two-Dimensional NMR Lineshape Analysis

    Science.gov (United States)

    Waudby, Christopher A.; Ramos, Andres; Cabrita, Lisa D.; Christodoulou, John

    2016-04-01

    NMR titration experiments are a rich source of structural, mechanistic, thermodynamic and kinetic information on biomolecular interactions, which can be extracted through the quantitative analysis of resonance lineshapes. However, applications of such analyses are frequently limited by peak overlap inherent to complex biomolecular systems. Moreover, systematic errors may arise due to the analysis of two-dimensional data using theoretical frameworks developed for one-dimensional experiments. Here we introduce a more accurate and convenient method for the analysis of such data, based on the direct quantum mechanical simulation and fitting of entire two-dimensional experiments, which we implement in a new software tool, TITAN (TITration ANalysis). We expect the approach, which we demonstrate for a variety of protein-protein and protein-ligand interactions, to be particularly useful in providing information on multi-step or multi-component interactions.

  15. Towards two-dimensional search engines

    CERN Document Server

    Ermann, Leonardo; Shepelyansky, Dima L

    2011-01-01

    We study the statistical properties of various directed networks using ranking of their nodes based on the dominant vectors of the Google matrix known as PageRank and CheiRank. On average PageRank orders nodes proportionally to a number of ingoing links, while CheiRank orders nodes proportionally to a number of outgoing links. In this way the ranking of nodes becomes two-dimensional that paves the way for development of two-dimensional search engines of new type. Information flow properties on PageRank-CheiRank plane are analyzed for networks of British, French and Italian Universities, Wikipedia, Linux Kernel, gene regulation and other networks. Methods of spam links control are also analyzed.

  16. Toward two-dimensional search engines

    Science.gov (United States)

    Ermann, L.; Chepelianskii, A. D.; Shepelyansky, D. L.

    2012-07-01

    We study the statistical properties of various directed networks using ranking of their nodes based on the dominant vectors of the Google matrix known as PageRank and CheiRank. On average PageRank orders nodes proportionally to a number of ingoing links, while CheiRank orders nodes proportionally to a number of outgoing links. In this way, the ranking of nodes becomes two dimensional which paves the way for the development of two-dimensional search engines of a new type. Statistical properties of information flow on the PageRank-CheiRank plane are analyzed for networks of British, French and Italian universities, Wikipedia, Linux Kernel, gene regulation and other networks. A special emphasis is done for British universities networks using the large database publicly available in the UK. Methods of spam links control are also analyzed.

  17. Two-Dimensional Scheduling: A Review

    Directory of Open Access Journals (Sweden)

    Zhuolei Xiao

    2013-07-01

    Full Text Available In this study, we present a literature review, classification schemes and analysis of methodology for scheduling problems on Batch Processing machine (BP with both processing time and job size constraints which is also regarded as Two-Dimensional (TD scheduling. Special attention is given to scheduling problems with non-identical job sizes and processing times, with details of the basic algorithms and other significant results.

  18. Two dimensional fermions in four dimensional YM

    CERN Document Server

    Narayanan, R

    2009-01-01

    Dirac fermions in the fundamental representation of SU(N) live on a two dimensional torus flatly embedded in $R^4$. They interact with a four dimensional SU(N) Yang Mills vector potential preserving a global chiral symmetry at finite $N$. As the size of the torus in units of $\\frac{1}{\\Lambda_{SU(N)}}$ is varied from small to large, the chiral symmetry gets spontaneously broken in the infinite $N$ limit.

  19. String breaking in two-dimensional QCD

    CERN Document Server

    Hornbostel, K J

    1999-01-01

    I present results of a numerical calculation of the effects of light quark-antiquark pairs on the linear heavy-quark potential in light-cone quantized two-dimensional QCD. I extract the potential from the Q-Qbar component of the ground-state wavefunction, and observe string breaking at the heavy-light meson pair threshold. I briefly comment on the states responsible for the breaking.

  20. Two-dimensional supramolecular electron spin arrays.

    Science.gov (United States)

    Wäckerlin, Christian; Nowakowski, Jan; Liu, Shi-Xia; Jaggi, Michael; Siewert, Dorota; Girovsky, Jan; Shchyrba, Aneliia; Hählen, Tatjana; Kleibert, Armin; Oppeneer, Peter M; Nolting, Frithjof; Decurtins, Silvio; Jung, Thomas A; Ballav, Nirmalya

    2013-05-07

    A bottom-up approach is introduced to fabricate two-dimensional self-assembled layers of molecular spin-systems containing Mn and Fe ions arranged in a chessboard lattice. We demonstrate that the Mn and Fe spin states can be reversibly operated by their selective response to coordination/decoordination of volatile ligands like ammonia (NH3). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Two dimensional echocardiographic detection of intraatrial masses.

    Science.gov (United States)

    DePace, N L; Soulen, R L; Kotler, M N; Mintz, G S

    1981-11-01

    With two dimensional echocardiography, a left atrial mass was detected in 19 patients. Of these, 10 patients with rheumatic mitral stenosis had a left atrial thrombus. The distinctive two dimensional echocardiographic features of left atrial thrombus included a mass of irregular nonmobile laminated echos within an enlarged atrial cavity, usually with a broad base of attachment to the posterior left atrial wall. Seven patients had a left atrial myxoma. Usually, the myxoma appeared as a mottled ovoid, sharply demarcated mobile mass attached to the interatrial septum. One patient had a right atrial angiosarcoma that appeared as a nonmobile mass extending from the inferior vena caval-right atrial junction into the right atrial cavity. One patient had a left atrial leiomyosarcoma producing a highly mobile mass attached to the lateral wall of the left atrium. M mode echocardiography detected six of the seven myxomas, one thrombus and neither of the other tumors. Thus, two dimensional echocardiography appears to be the technique of choice in the detection, localization and differentiation of intraatrial masses.

  2. Night vision image fusion for target detection with improved 2D maximum entropy segmentation

    Science.gov (United States)

    Bai, Lian-fa; Liu, Ying-bin; Yue, Jiang; Zhang, Yi

    2013-08-01

    Infrared and LLL image are used for night vision target detection. In allusion to the characteristics of night vision imaging and lack of traditional detection algorithm for segmentation and extraction of targets, we propose a method of infrared and LLL image fusion for target detection with improved 2D maximum entropy segmentation. Firstly, two-dimensional histogram was improved by gray level and maximum gray level in weighted area, weights were selected to calculate the maximum entropy for infrared and LLL image segmentation by using the histogram. Compared with the traditional maximum entropy segmentation, the algorithm had significant effect in target detection, and the functions of background suppression and target extraction. And then, the validity of multi-dimensional characteristics AND operation on the infrared and LLL image feature level fusion for target detection is verified. Experimental results show that detection algorithm has a relatively good effect and application in target detection and multiple targets detection in complex background.

  3. Differentiating Fragmentation Pathways of Cholesterol by Two-Dimensional Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

    Science.gov (United States)

    van Agthoven, Maria A.; Barrow, Mark P.; Chiron, Lionel; Coutouly, Marie-Aude; Kilgour, David; Wootton, Christopher A.; Wei, Juan; Soulby, Andrew; Delsuc, Marc-André; Rolando, Christian; O'Connor, Peter B.

    2015-12-01

    Two-dimensional Fourier transform ion cyclotron resonance mass spectrometry is a data-independent analytical method that records the fragmentation patterns of all the compounds in a sample. This study shows the implementation of atmospheric pressure photoionization with two-dimensional (2D) Fourier transform ion cyclotron resonance mass spectrometry. In the resulting 2D mass spectrum, the fragmentation patterns of the radical and protonated species from cholesterol are differentiated. This study shows the use of fragment ion lines, precursor ion lines, and neutral loss lines in the 2D mass spectrum to determine fragmentation mechanisms of known compounds and to gain information on unknown ion species in the spectrum. In concert with high resolution mass spectrometry, 2D Fourier transform ion cyclotron resonance mass spectrometry can be a useful tool for the structural analysis of small molecules.

  4. Volumetric display containing multiple two-dimensional color motion pictures

    Science.gov (United States)

    Hirayama, R.; Shiraki, A.; Nakayama, H.; Kakue, T.; Shimobaba, T.; Ito, T.

    2014-06-01

    We have developed an algorithm which can record multiple two-dimensional (2-D) gradated projection patterns in a single three-dimensional (3-D) object. Each recorded pattern has the individual projected direction and can only be seen from the direction. The proposed algorithm has two important features: the number of recorded patterns is theoretically infinite and no meaningful pattern can be seen outside of the projected directions. In this paper, we expanded the algorithm to record multiple 2-D projection patterns in color. There are two popular ways of color mixing: additive one and subtractive one. Additive color mixing used to mix light is based on RGB colors and subtractive color mixing used to mix inks is based on CMY colors. We made two coloring methods based on the additive mixing and subtractive mixing. We performed numerical simulations of the coloring methods, and confirmed their effectiveness. We also fabricated two types of volumetric display and applied the proposed algorithm to them. One is a cubic displays constructed by light-emitting diodes (LEDs) in 8×8×8 array. Lighting patterns of LEDs are controlled by a microcomputer board. The other one is made of 7×7 array of threads. Each thread is illuminated by a projector connected with PC. As a result of the implementation, we succeeded in recording multiple 2-D color motion pictures in the volumetric displays. Our algorithm can be applied to digital signage, media art and so forth.

  5. Theory of two-dimensional ESR with nuclear modulation

    Science.gov (United States)

    Gamliel, Dan; Freed, Jack H.

    A formalism for computing 2D ESR lineshapes with nuclear modulation is developed in a form which is useful for planning phase cycles for particular purposes. A simple method of processing spectra, utilizing quadrature detection, is shown to enhance the selectivity of the phase cycling techniques. Computed ESR-COSY, ESR-SECSY, and 2D ELDOR lineshapes are presented for several kinds of polycrystalline and single-crystal samples which exhibit nuclear modulation, due to one or several nuclei. The two-dimensional methods are found to give more detailed structural information than the corresponding ESEEM spectra. New phase cycles are found to eliminate completely all transverse and axial peaks in 2D ELDOR and in ESR-COSY, and at the same time eliminate all artifacts arising from incomplete image rejection. Other phase cycles are presented for selecting in those experiments only axial peaks, for measuring T1. It is also shown how selective phase cycles may help to distinguish between coherent and exchange cross peaks. In the special case of nitroxides in typical Zeeman fields, there are no significant nuclear modulation effects from the 14N nuclear spin interaction, but those from the protons (or deuterons) will, in general, be significant.

  6. Interactions between lasers and two-dimensional transition metal dichalcogenides.

    Science.gov (United States)

    Lu, Junpeng; Liu, Hongwei; Tok, Eng Soon; Sow, Chorng-Haur

    2016-05-03

    The recent increasing research interest in two-dimensional (2D) layered materials has led to an explosion of in the discovery of novel physical and chemical phenomena in these materials. Among the 2D family, group-VI transition metal dichalcogenides (TMDs), such as represented by MoS2 and WSe2, are remarkable semiconductors with sizable energy band gaps, which make the TMDs promising building blocks for new generation optoelectronics. On the other hand, the specificity and tunability of the band gaps can generate particularly strong light-matter interactions between TMD crystals and specific photons, which can trigger complex and interesting phenomena such as photo-scattering, photo-excitation, photo-destruction, photo-physical modification, photochemical reaction and photo-oxidation. Herein, we provide an overview of the phenomena explained by various interactions between lasers and the 2D TMDs. Characterizations of the optical fundamentals of the TMDs via laser spectroscopies are reviewed. Subsequently, photoelectric conversion devices enabled by laser excitation and the functionality extension and performance improvement of the TMDs materials via laser modification are comprehensively summarized. Finally, we conclude the review by discussing the prospects for further development in this research area.

  7. Two-dimensional magnetic ordering in a multilayer structure

    Indian Academy of Sciences (India)

    M K Mukhopadhyay; M K Sanyal

    2006-07-01

    The effect of confinement from one, two or from all three directions on magnetic ordering has remained an active field of research for almost 100 years. The role of dipolar interactions and anisotropy are important to obtain, the otherwise forbidden, ferromagnetic ordering at finite temperature for ions arranged in two-dimensional (2D) arrays (monolayers). We have demonstrated that conventional low-temperature magnetometry and polarized neutron scattering measurements can be performed to study short-range ferromagnetic ordering of in-plane spins in 2D systems using a multilayer stack of non-interacting monolayers of gadolinium ions formed by Langmuir–Blodgett (LB) technique. The spontaneous magnetization could not be detected in the heterogeneous magnetic phase observed here and the saturation value of the net magnetization was found to depend on the sample temperature and applied magnetic field. The net magnetization rises exponentially with lowering temperature and then reaches saturation following a ln( ) dependence. The ln( ) dependence of magnetization has been predicted from spin-wave theory of 2D in-plane spin system with ferromagnetic interaction. The experimental findings reported here could be explained by extending this theory to a temperature domain of < 1.

  8. Criticality in Two-Dimensional Quantum Systems: Tensor Network Approach

    CERN Document Server

    Ran, Shi-Ju; Li, Wei; Lewenstein, Maciej; Su, Gang

    2016-01-01

    Determination and characterization of criticality in two-dimensional (2D) quantum many-body systems belong to the most important challenges and problems of quantum physics. In this paper we propose an efficient scheme to solve this problem by utilizing the infinite projected entangled pair state (iPEPS), and tensor network (TN) representations. We show that the criticality of a 2D state is faithfully reproduced by the ground state (dubbed as boundary state) of a one-dimensional effective Hamiltonian constructed from its iPEPS representation. We demonstrate that for a critical state the correlation length and the entanglement spectrum of the boundary state are essentially different from those of a gapped iPEPS. This provides a solid indicator that allows to identify the criticality of the 2D state. Our scheme is verified on the resonating valence bond (RVB) states on kagom\\'e and square lattices, where the boundary state of the honeycomb RVB is found to be described by a $c=1$ conformal field theory. We apply ...

  9. Observation of asymmetrically imploded core plasmas with a two-dimensional sampling image x-ray streak camera.

    Science.gov (United States)

    Shiraga, Hiroyuki; Lee, Myongdok; Mahigashi, Norimitsu; Fujioka, Shinsuke; Azechi, Hiroshi

    2008-10-01

    A shell target with a cone for guiding the heating beam has been proposed for the fast ignition scheme. Implosion of such target is no longer symmetric because of the cone. A fast two-dimensional x-ray imaging technique, two-dimensional (2D) sampling image x-ray streak camera was applied for the first time to observation of the dynamics of implosion and core plasma. X-ray emission image of the plasma was sampled with two-dimensionally distributed image sampling points, streaked with the tube, and the recorded signals were reconstructed as sequential 2D frame images. Shape and movement of the core plasma were clearly observed.

  10. Heterostructures based on two-dimensional layered materials and their potential applications

    KAUST Repository

    Li, Ming-yang

    2015-12-04

    The development of two-dimensional (2D) layered materials is driven by fundamental interest and their potential applications. Atomically thin 2D materials provide a wide range of basic building blocks with unique electrical, optical, and thermal properties which do not exist in their bulk counterparts. The van der Waals interlayer interaction enables the possibility to exfoliate and reassemble different 2D materials into arbitrarily and vertically stacked heterostructures. Recently developed vapor phase growth of 2D materials further paves the way of directly synthesizing vertical and lateral heterojunctions. This review provides insights into the layered 2D heterostructures, with a concise introduction to preparative approaches for 2D materials and heterostructures. These unique 2D heterostructures have abundant implications for many potential applications.

  11. Two-dimensional photonic crystal sensors for visual detection of lectin concanavalin A.

    Science.gov (United States)

    Zhang, Jian-Tao; Cai, Zhongyu; Kwak, Daniel H; Liu, Xinyu; Asher, Sanford A

    2014-09-16

    We fabricated a two-dimensional (2-D) photonic crystal lectin sensing material that utilizes light diffraction from a 2-D colloidal array attached to the surface of a hydrogel that contains mannose carbohydrate groups. Lectin-carbohydrate interactions create hydrogel cross-links that shrink the hydrogel volume and decrease the 2-D particle spacing. This mannose containing 2-D photonic crystal sensor detects Concanavalin A (Con A) through shifts in the 2-D diffraction wavelength. Con A concentrations can be determined by measuring the diffracted wavelength or visually determined from the change in the sensor diffraction color. The concentrations are easily monitored by measuring the 2-D array Debye ring diameter. Our observed detection limit for Con A is 0.02 mg/mL (0.7 μM). The 2-D photonic crystal sensors are completely reversible and can monitor Con A solution concentration changes.

  12. Visualising the strain distribution in suspended two-dimensional materials under local deformation

    Science.gov (United States)

    Elibol, Kenan; Bayer, Bernhard C.; Hummel, Stefan; Kotakoski, Jani; Argentero, Giacomo; Meyer, Jannik C.

    2016-06-01

    We demonstrate the use of combined simultaneous atomic force microscopy (AFM) and laterally resolved Raman spectroscopy to study the strain distribution around highly localised deformations in suspended two-dimensional materials. Using the AFM tip as a nanoindentation probe, we induce localised strain in suspended few-layer graphene, which we adopt as a two-dimensional membrane model system. Concurrently, we visualise the strain distribution under and around the AFM tip in situ using hyperspectral Raman mapping via the strain-dependent frequency shifts of the few-layer graphene’s G and 2D Raman bands. Thereby we show how the contact of the nm-sized scanning probe tip results in a two-dimensional strain field with μm dimensions in the suspended membrane. Our combined AFM/Raman approach thus adds to the critically required instrumental toolbox towards nanoscale strain engineering of two-dimensional materials.

  13. Multi-Symplectic Splitting Method for Two-Dimensional Nonlinear Schriidinger Equation

    Institute of Scientific and Technical Information of China (English)

    陈亚铭; 朱华君; 宋松和

    2011-01-01

    Using the idea of splitting numerical methods and the multi-symplectic methods, we propose a multisymplectic splitting (MSS) method to solve the two-dimensional nonlinear Schrodinger equation (2D-NLSE) in this paper. It is further shown that the method constructed in this way preserve the global symplectieity exactly. Numerical experiments for the plane wave solution and singular solution of the 2D-NLSE show the accuracy and effectiveness of the proposed method.

  14. Feasibility and Limitations of Vaccine Two-Dimensional Barcoding Using Mobile Devices

    OpenAIRE

    Bell, Cameron; Guerinet, Julien; Atkinson, Katherine M.; Wilson, Kumanan

    2016-01-01

    Background Two-dimensional (2D) barcoding has the potential to enhance documentation of vaccine encounters at the point of care. However, this is currently limited to environments equipped with dedicated barcode scanners and compatible record systems. Mobile devices may present a cost-effective alternative to leverage 2D vaccine vial barcodes and improve vaccine product-specific information residing in digital health records. Objective Mobile devices have the potential to capture product-spec...

  15. Two-dimensional atom localization via probe absorption in a four-level atomic system

    Institute of Scientific and Technical Information of China (English)

    Wang Zhi-Ping; Ge Qiang; Ruan Yu-Hua; Yu Ben-Li

    2013-01-01

    We have investigated the two-dimensional (2D) atom localization via probe absorption in a coherently driven fourlevel atomic system by means of a radio-frequency field driving a hyperfine transition.It is found that the detecting probability and precision of 2D atom localization can be significantly improved via adjusting the system parameters.As a result,our scheme may be helpful in laser cooling or the atom nano-lithography via atom localization.

  16. First-principles study of two-dimensional van der Waals heterojunctions

    OpenAIRE

    Hu, Wei; Yang, Jinlong

    2015-01-01

    Research on graphene and other two-dimensional (2D) materials, such as silicene, germanene, phosphorene, hexagonal boron nitride (h-BN), graphitic carbon nitride (g-C3N4), graphitic zinc oxide (g-ZnO) and molybdenum disulphide (MoS2), has recently received considerable interest owing to their outstanding properties and wide applications. Looking beyond this field, combining the electronic structures of 2D materials in ultrathin van der Waals heterojunctions has also emerged to widely study th...

  17. Design of two-dimensional recursive filters by using neural networks.

    Science.gov (United States)

    Mladenov, V M; Mastorakis, N E

    2001-01-01

    A new design method for two-dimensional (2-D) recursive digital filters is investigated. The design of the 2-D filter is reduced to a constrained minimization problem the solution of which is achieved by the convergence of an appropriate neural network. The method is tested on a numerical example and compared with previously published methods when applied to the same example. Advantages of the proposed method over the existing ones are discussed as well.

  18. Two-Dimensional (2-D) Acoustic Fish Tracking at River Mile 85, Sacramento River, California

    Science.gov (United States)

    2013-06-01

    be recovered rather than being lost due to sediment dunes, large woody material floating downstream, and vandalism. The RM 85 site was a relatively...growth rate among PIT, PIT+acoustic tag, and sham+PIT treatments . VEMCO V7 tags ERDC/EL TR-13-7 40 in the study represented a tag burden of 2.6–5.6...W. Dawley, M. Russell, A. Whiting, and D. J. Teel. 2010. Juvenile salmonid use of reconnected tidal freshwater wetlands in Grays River, lower

  19. Two-dimensional (2-D) deformation measurements with ASAR and PHARUS

    NARCIS (Netherlands)

    Groot, J.S.; Halsema, D. van; Maarseveen, R.A. van; Blommaart, P.J.L.; Kruse, G.A.M.; Loon, D. van; Hanssen, R.F.; Samson, J.; Striegel, A.J.; Visser, J.M.P.C.M.

    2001-01-01

    Deformation measurements are important in the field of ground engineering. Deformation can have a non-natural cause (e.g., surface deformation due to tunnel construction) or a natural one (e.g., dike deformation due to a high water level). Radar interferometry can in principle provide deformations w

  20. Phase coding by grid cells in unconstrained environments: Two-dimensional (2D) phase precession

    Science.gov (United States)

    Climer, Jason R.; Newman, Ehren L.; Hasselmo, Michael E.

    2014-01-01

    Action potential timing is thought to play a critical role in neural representation. For example, theta phase precession is a robust phenomenon exhibited by spatial cells of the rat entorhinal-hippocampal circuit. In phase precession, the time a neuron fires relative to the phase of theta rhythm (6-10Hz) oscillations in the local field potential reduces uncertainty about the position of the animal. This relationship between neural firing and behavior has made precession an important constraint for hypothetical mechanisms of temporal coding. However, challenges exist in identifying what regulates the spike timing of these cells. We have developed novel analytical techniques for mapping between behavior and neural firing that provide sufficient sensitivity to examine features of grid cell phase coding in open environments. Here, we show robust, omnidirectional phase precession by entorhinal grid cells in openfield enclosures. We present evidence that full phase precession persists regardless of how close the animal comes to the center of a firing field. We found many conjunctive grid cells, previously thought to be phase locked, also exhibit phase coding. However, we were unable to detect directional or field specific phase coding predicted by some variants of models. Finally, we present data that suggests bursting of layer II grid cells contributes to the bimodality of phase precession. We discuss implications of these observations for models of temporal coding and propose the utility of these techniques in other domains where behavior is aligned to neural spiking. PMID:23718553

  1. 2D Saturable Absorbers for Fibre Lasers

    Directory of Open Access Journals (Sweden)

    Robert I. Woodward

    2015-11-01

    Full Text Available Two-dimensional (2D nanomaterials are an emergent and promising platform for future photonic and optoelectronic applications. Here, we review recent progress demonstrating the application of 2D nanomaterials as versatile, wideband saturable absorbers for Q-switching and mode-locking fibre lasers. We focus specifically on the family of few-layer transition metal dichalcogenides, including MoS2, MoSe2 and WS2.

  2. Quantum creep in a highly crystalline two-dimensional superconductor

    Science.gov (United States)

    Saito, Yu; Kasahara, Yuichi; Ye, Jianting; Iwasa, Yoshihiro; Nojima, Tsutomu

    Conventional studies on quantum phase transitions, especially on superconductor-insulator or superconductor-metal-insulator transitions have been performed in deposited metallic thin films such as Bismuth or MoGe. Although the techniques of thin films deposition have been considerably improved, unintentional disorder such as impurities and deficiencies, generating the pinning centers, seems to still exist in such systems. The mechanical exfoliated highly crystalline two-dimensional material can be a good candidate to realize a less-disordered 2D superconductor with extremely weak pinning, combined with transfer method or ionic-liquid gating. We report on the quantum metal, namely, magnetic-field-induced metallic state observed in an ion-gated two-dimensional superconductor based on an ultra-highly crystalline layered band insulator, ZrNCl. We found that the superconducting state is extremely fragile against external magnetic fields; that is, zero resistance state immediately disappears, once an external magnetic field switches on. This is because the present system is relatively clean and the pinning potential is extremely weak, which cause quantum tunneling and flux flow of vortices, resulting in metallic ground state.

  3. Acoustic resonances in two-dimensional radial sonic crystal shells

    Science.gov (United States)

    Torrent, Daniel; Sánchez-Dehesa, José

    2010-07-01

    Radial sonic crystals (RSC) are fluidlike structures infinitely periodic along the radial direction that verify the Bloch theorem and are possible only if certain specially designed acoustic metamaterials with mass density anisotropy can be engineered (see Torrent and Sánchez-Dehesa 2009 Phys. Rev. Lett. 103 064301). A comprehensive analysis of two-dimensional (2D) RSC shells is reported here. A given shell is in fact a circular slab with a central cavity. These finite crystal structures contain Fabry-Perot-like resonances and modes strongly localized at the central cavity. Semi-analytical expressions are developed to obtain the quality factors of the different resonances, their symmetry features and their excitation properties. The results reported here are completely general and can be extended to equivalent 3D spherical shells and to their photonic counterparts.

  4. Dielectric-barrier discharges in two-dimensional lattice potentials

    CERN Document Server

    Sinclair, Josiah

    2011-01-01

    We use a pin-grid electrode to introduce a corrugated electrical potential into a planar dielectric-barrier discharge (DBD) system, so that the amplitude of the applied electric field has the profile of a two-dimensional square lattice. The lattice potential provides a template for the spatial distribution of plasma filaments in the system and has pronounced effects on the patterns that can form. The positions at which filaments become localized within the lattice unit cell vary with the width of the discharge gap. The patterns that appear when filaments either overfill or under-fill the lattice are reminiscent of those observed in other physical systems involving 2d lattices. We suggest that the connection between lattice-driven DBDs and other areas of physics may benefit from the further development of models that treat plasma filaments as interacting particles.

  5. Two-dimensional NQR using ultra-broadband electronics

    Science.gov (United States)

    Mandal, S.; Song, Y.-Q.

    2014-03-01

    We have recently developed an ultra-broadband instrument that can effectively excite and detect NMR and NQR signals over a wide frequency range. Our current system operates between 100 kHz and 3.2 MHz using an un-tuned sample coil. The major benefits of this instrument compared to conventional NQR/NMR systems include increased robustness, ease of use (in particular for multi-frequency experiments), and elimination of the need for tuning adjustments in the hardware. Here we describe its use for performing two-dimensional (2D) scans, which allow improved interpretation of complex NQR spectra by detecting the connected resonances. Our method relies on population transfers between the three energy levels of spin-1 nuclei (such as 14N) by using multi-frequency excitation and a single RF coil. Experimental results on pure samples and mixtures are also presented.

  6. The random discrete action for two-dimensional spacetime

    Science.gov (United States)

    Benincasa, Dionigi M. T.; Dowker, Fay; Schmitzer, Bernhard

    2011-05-01

    A one-parameter family of random variables, called the Discrete Action, is defined for a two-dimensional Lorentzian spacetime of finite volume. The single parameter is a discreteness scale. The expectation value of this discrete action is calculated for various regions of 2D Minkowski spacetime, {M}^2. When a causally convex region of {M}^2 is divided into subregions using null lines the mean of the discrete action is equal to the alternating sum of the numbers of vertices, edges and faces of the null tiling, up to corrections that tend to 0 as the discreteness scale is taken to 0. This result is used to predict that the mean of the discrete action of the flat Lorentzian cylinder is zero up to corrections, which is verified. The 'topological' character of the discrete action breaks down for causally convex regions of the flat trousers spacetime that contain the singularity and for non-causally convex rectangles.

  7. Bounds on the Capacity of Weakly constrained two-dimensional Codes

    DEFF Research Database (Denmark)

    Forchhammer, Søren

    2002-01-01

    Upper and lower bounds are presented for the capacity of weakly constrained two-dimensional codes. The maximum entropy is calculated for two simple models of 2-D codes constraining the probability of neighboring 1s as an example. For given models of the coded data, upper and lower bounds...

  8. Metallic ground state in an ion-gated two-dimensional superconductor

    NARCIS (Netherlands)

    Saito, Yu; Kasahara, Yuichi; Ye, Jianting; Iwasa, Yoshihiro; Nojima, Tsutomu

    2015-01-01

    Recently emerging two-dimensional (2D) superconductors in atomically thin layers and at heterogeneous interfaces are attracting growing interest in condensed matter physics. Here, we report that an ion-gated zirconium nitride chloride surface, exhibiting a dome-shaped phase diagram with a maximum cr

  9. Two Dimensional Electronic Correlation Spectroscopy of the npi* and pipi* Protein Backbone Transitions: A Simulation Study.

    Science.gov (United States)

    Li, Zhenyu; Abramavicius, Darius; Zhuang, Wei; Mukamel, Shaul

    2007-11-15

    The two dimensional (2D) photon echo spectrum of the amide ultraviolet (UV) bands of proteins are simulated. Two effective exciton Hamiltonian parameter sets developed by Woody and Hirst, which predict similar CD spectra, may be distinguished by their very different 2DUV spectra. These differences are enhanced in specific configurations of pulse polarizations which provide chirality-induced signals.

  10. Collective modes of a quasi-two-dimensional Bose condensate in large gas parameter regime

    Indian Academy of Sciences (India)

    S R Mishra; S P Ram; Arup Banerjee

    2007-06-01

    We have theoretically studied the collective modes of a quasi-two-dimensional (Q2D) Bose condensate in the large gas parameter regime by using a formalism which treats the interaction energy beyond the mean-field approximation. The results show that incorporation of this higher order term leads to significant modifications in the mode frequencies.

  11. Analysis of soybean embryonic axis proteins by two-dimensional gel electrophoresis and mass spectrometry

    Science.gov (United States)

    A proteomic approach based on two-dimensional polyacrylamide gel electrophoresis (2D-PAGE) for protein separation and subsequent mass spectrometry (MS) for protein identification was applied to establish a proteomic reference map for the soybean embryonic axis. Proteins were extracted from dissecte...

  12. Mapping of 34 minisatellite loci resolved by two-dimensional DNA typing

    DEFF Research Database (Denmark)

    Børglum, Anders; Nyegaard, Mette; Kvistgaard, AB

    1997-01-01

    Two-dimensional (2-D) DNA typing is based on electrophoretic separation of genomic DNA fragments in two dimensions according to independent criteria (size and base-pair sequence), followed by hybridization analysis using multilocus probes. The technique allows simultaneous visualization of severa...

  13. Quantitative analysis of target components by comprehensive two-dimensional gas chromatography

    NARCIS (Netherlands)

    Mispelaar, V.G. van; Tas, A.C.; Smilde, A.K.; Schoenmakers, P.J.; Asten, A.C. van

    2003-01-01

    Quantitative analysis using comprehensive two-dimensional (2D) gas chromatography (GC) is still rarely reported. This is largely due to a lack of suitable software. The objective of the present study is to generate quantitative results from a large GC x GC data set, consisting of 32 chromatograms. I

  14. High-flux two-dimensional magneto-optical-trap source for cold lithium atoms

    NARCIS (Netherlands)

    Tiecke, T.G.; Gensemer, S.D.; Ludewig, A.; Walraven, J.T.M.

    2009-01-01

    We demonstrate a two-dimensional magneto-optical trap (2D MOT) as a beam source for cold Li-6 atoms. The source is side loaded from an oven operated at temperatures in the range 600 less than or similar to T less than or similar to 700 K. The performance is analyzed by loading the atoms into a

  15. Two-Dimensional Covalent Organic Frameworks for Carbon Dioxide Capture through Channel-Wall Functionalization

    NARCIS (Netherlands)

    Huang, N.; Chen, X.; Krishna, R.; Jiang, D.

    2015-01-01

    Ordered open channels found in two-dimensional covalent organic frameworks (2D COFs) could enable them to adsorb carbon dioxide. However, the frameworks' dense layer architecture results in low porosity that has thus far restricted their potential for carbon dioxide adsorption. Here we report a

  16. Volumetric and two-dimensional image interpretation show different cognitive processes in learners

    NARCIS (Netherlands)

    van der Gijp, Anouk; Ravesloot, C.J.; van der Schaaf, Marieke F; van der Schaaf, Irene C; Huige, Josephine C B M; Vincken, Koen L; Ten Cate, Olle Th J; van Schaik, JPJ

    2015-01-01

    RATIONALE AND OBJECTIVES: In current practice, radiologists interpret digital images, including a substantial amount of volumetric images. We hypothesized that interpretation of a stack of a volumetric data set demands different skills than interpretation of two-dimensional (2D) cross-sectional imag

  17. Comparison of Yeast Cell Protein Solubilization Procedures for Two-dimensional Electrophoresis

    DEFF Research Database (Denmark)

    Harder, A; Wildgruber, R; Nawrocki, A;

    1999-01-01

    Three different procedures for the solubilization of yeast (S. cerevisiae) cell proteins were compared on the basis of the obtained two-dimensional (2-D) polypeptide patterns. Major emphasis was laid on minimizing handling steps, protein modification or degradation, and quantitative loss of high ...

  18. A true order recursive algorithm for two-dimensional mean squared error linear prediction and filtering

    NARCIS (Netherlands)

    Glentis, George-Othon; Slump, Cornelis H.; Hermann, Otto E.

    2000-01-01

    In this paper a novel algorithm is presented for the efficient two-dimensional (2-D), mean squared error (MSE), FIR filtering and system identification. Filter masks of general boundaries are allowed. Efficient order updating recursions are developed by exploiting the spatial shift invariance

  19. Two-dimensional visualization of cluster beams by microchannel plates

    Energy Technology Data Exchange (ETDEWEB)

    Khoukaz, A., E-mail: khoukaz@uni-muenster.de; Bonaventura, D.; Grieser, S.; Hergemöller, A.-K.; Köhler, E.; Täschner, A.

    2014-01-21

    An advanced technique for a two-dimensional real time visualization of cluster beams in a vacuum as well as of the overlap volume of cluster beams with particle accelerator beams is presented. The detection system consists of an array of microchannel plates (MCPs) in combination with a phosphor screen which is read out by a CCD camera. This setup together with the ionization of a cluster beam by an electron or ion beam allows for spatial resolved investigations of the cluster beam position, size, and intensity. Moreover, since electrically uncharged clusters remain undetected, the operation in an internal beam experiment opens the way to monitor the overlap region and thus the position and size of an accelerator beam crossing an originally electrically neutral cluster jet. The observed intensity distribution of the recorded image is directly proportional to the convolution of the spatial ion beam and cluster beam intensities and is by this a direct measure of the two-dimensional luminosity distribution. This information can directly be used for the reconstruction of vertex positions as well as for an input for numerical simulations of the reaction zone. The spatial resolution of the images is dominated by the granularity of the complete MCP device and was found to be in the order of σ≈100μm. -- Highlights: • We present a MCP system for a 2D real time visualization of cluster target beams. • With this device the vertex region of storage ring experiments can be investigated. • Time resolved 2D information about the target thickness distribution is accessible. • A spatial resolution of the MCP device of 0.1 mm was achieved. • The presented MCP system also allows for measurements on cluster masses.

  20. Compact triplexer in two-dimensional hexagonal lattice photonic crystals

    Institute of Scientific and Technical Information of China (English)

    Hongliang Ren; Jianping Ma; Hao Wen; Yali Qin; Zhefu Wu; Weisheng Hu; Chun Jiang; Yaohui Jin

    2011-01-01

    We design a contpact triplexer based on two-dimensional (2D) hexagonal lattice photonic crystals (PCs). A folded directional coupler (FDC) is introduced in the triplexer beside the point-defect micro-cavities and line-defect waveguides. Because of the reflection feedback of the FDC, high channel drop efficiency can be realized and a compact size with the order of micrometers can be maintained. The proposed device is analyzed using the plane wave expansion method, and its transmission characteristics are calculated using the finites-difference time-domain method. The footprint of the triplexer is about 12× 9 μm, and its extinction ratios are less than -20 dB for 1310 nm, approximately -20 dB for 1490 nm, and under -4O dB for 1550 nm, making it a potentially essential device ii future fiber-to-the-home networks.%@@ We design a compact triplexer based on two-dimensional (2D) hexagonal lattice photonic crystals (PCs).A folded directional coupler (FDC) is introduced in the triplexer beside the point-defect micro-cavities and line-defect waveguides.Because of the reflection feedback of the FDC, high channel drop efficiency can be realized and a compact size with the order of micrometers can be maintained.The proposed device is analyzed using the plane wave expansion method, and its transmission characteristics are calculated using the finite-difference time-domain method.The footprint of the triplexer is about 12×9 μm, and its extinction ratios are less than -20 dB for 1310 nm, approximately -20 dB for 1490 nm, and under -40 dB for 1550 nm, making it a potentially essential device in future fiber-to-the-home networks.

  1. Electronic nanobiosensors based on two-dimensional materials

    Science.gov (United States)

    Ping, Jinglei

    Atomically-thick two-dimensional (2D) nanomaterials have tremendous potential to be applied as transduction elements in biosensors and bioelectronics. We developed scalable methods for synthesis and large-area transfer of two-dimensional nanomaterials, particularly graphene and metal dichalcogenides (so called ``MX2'' materials). We also developed versatile fabrication methods for large arrays of field-effect transistors (FETs) and micro-electrodes with these nanomaterials based on either conventional photolithography or innovative approaches that minimize contamination of the 2D layer. By functionalizing the FETs with a computationally redesigned water-soluble mu-opioid receptor, we created selective and sensitive biosensors suitable for detection of the drug target naltrexone and the neuropeptide enkephalin at pg/mL concentrations. We also constructed DNA-functionalized biosensors and nano-particle decorated biosensors by applying related bio-nano integration techniques. Our methodology paves the way for multiplexed nanosensor arrays with all-electronic readout suitable for inexpensive point-of-care diagnostics, drug-development and biomedical research. With graphene field-effect transistors, we investigated the graphene/solution interface and developed a quantitative model for the effect of ionic screening on the graphene carrier density based on theories of the electric double layer. Finally, we have developed a technique for measuring low-level Faradaic charge-transfer current (fA) across the graphene/solution interface via real-time charge monitoring of graphene microelectrodes in ionic solution. This technique enables the development of flexible and transparent pH sensors that are promising for in vivo applications. The author acknowledges the support from the Defense Advanced Research Projects Agency (DARPA) and the U. S. Army Research Office under Grant Number W911NF1010093.

  2. Canonical structure of 2D black holes

    CERN Document Server

    Navarro-Salas, J; Talavera, C F

    1994-01-01

    We determine the canonical structure of two-dimensional black-hole solutions arising in $2D$ dilaton gravity. By choosing the Cauchy surface appropriately we find that the canonically conjugate variable to the black hole mass is given by the difference of local (Schwarzschild) time translations at right and left spatial infinities. This can be regarded as a generalization of Birkhoff's theorem.

  3. Pseudo-two-dimensional random dimer lattices

    Energy Technology Data Exchange (ETDEWEB)

    Naether, U., E-mail: naether@unizar.es [Instituto de Ciencia de Materiales de Aragón and Departamento de Física de la Materia Condensada, CSIC – Universidad de Zaragoza, 50009 Zaragoza (Spain); Mejía-Cortés, C.; Vicencio, R.A. [Departamento de Física and MSI – Nucleus for Advanced Optics, Center for Optics and Photonics (CEFOP), Facultad de Ciencias, Universidad de Chile, Santiago (Chile)

    2015-06-05

    We study the long-time wave transport in correlated and uncorrelated disordered 2D arrays. When a separation of dimensions is applied to the model, we find that the previously predicted 1D random dimer phenomenology also appears in so-called pseudo-2D arrays. Therefore, a threshold behavior is observed in terms of the effective size for eigenmodes, as well as in long-time dynamics. A minimum system size is required to observe this threshold, which is very important when considering a possible experimental realization. For the long-time evolution, we find that for correlated lattices a super-diffusive long-range transport is observed. For completely uncorrelated disorder 2D transport becomes sub-diffusive within the localization length and for random binary pseudo-2D arrays localization is observed.

  4. Proteome analysis of human colorectal cancer tissue using 2-D ...

    African Journals Online (AJOL)

    Jane

    2010-10-11

    Oct 11, 2010 ... Laser capture microdissection and two-dimensional difference gel electrophoresis were used to establish ... As a technique with high-flux and high resolution, pro- teomics ... in which the protein sample was labeled before 2-D.

  5. Weakly disordered two-dimensional Frenkel excitons

    Science.gov (United States)

    Boukahil, A.; Zettili, Nouredine

    2004-03-01

    We report the results of studies of the optical properties of weakly disordered two- dimensional Frenkel excitons in the Coherent Potential Approximation (CPA). An approximate complex Green's function for a square lattice with nearest neighbor interactions is used in the self-consistent equation to determine the coherent potential. It is shown that the Density of States is very much affected by the logarithmic singularities in the Green's function. Our CPA results are in excellent agreement with previous investigations by Schreiber and Toyozawa using the Monte Carlo simulation.

  6. Two-dimensional ranking of Wikipedia articles

    CERN Document Server

    Zhirov, A O; Shepelyansky, D L

    2010-01-01

    The Library of Babel, described by Jorge Luis Borges, stores an enormous amount of information. The Library exists {\\it ab aeterno}. Wikipedia, a free online encyclopaedia, becomes a modern analogue of such a Library. Information retrieval and ranking of Wikipedia articles become the challenge of modern society. We analyze the properties of two-dimensional ranking of all Wikipedia English articles and show that it gives their reliable classification with rich and nontrivial features. Detailed studies are done for countries, universities, personalities, physicists, chess players, Dow-Jones companies and other categories.

  7. Sums of two-dimensional spectral triples

    DEFF Research Database (Denmark)

    Christensen, Erik; Ivan, Cristina

    2007-01-01

    construct a sum of two dimensional modules which reflects some aspects of the topological dimensions of the compact metric space, but this will only give the metric back approximately. At the end we make an explicit computation of the last module for the unit interval in. The metric is recovered exactly......, the Dixmier trace induces a multiple of the Lebesgue integral but the growth of the number of eigenvalues is different from the one found for the standard differential operator on the unit interval....

  8. Dynamics of film. [two dimensional continua theory

    Science.gov (United States)

    Zak, M.

    1979-01-01

    The general theory of films as two-dimensional continua are elaborated upon. As physical realizations of such a model this paper examines: inextensible films, elastic films, and nets. The suggested dynamic equations have enabled us to find out the characteristic speeds of wave propagation of the invariants of external and internal geometry and formulate the criteria of instability of their shape. Also included herein is a detailed account of the equation describing the film motions beyond the limits of the shape stability accompanied by the formation of wrinkles. The theory is illustrated by examples.

  9. Structure of a model salt bridge in solution investigated with 2D-IR spectroscopy

    CERN Document Server

    Huerta-Viga, Adriana; Amirjalayer, Saeed; Woutersen, Sander

    2013-01-01

    Salt bridges are known to be important for the stability of protein conformation, but up to now it has been difficult to study their geometry in solution. Here we characterize the spatial structure of a model salt bridge between guanidinium (Gdm+) and acetate (Ac-) using two-dimensional vibrational (2D-IR) spectroscopy. We find that as a result of salt bridging the infrared response of Gdm+ and Ac- change significantly, and in the 2D-IR spectrum, salt bridging of the molecules appears as cross peaks. From the 2D-IR spectrum we determine the relative orientation of the transition-dipole moments of the vibrational modes involved in the salt bridge, as well as the coupling between them. In this manner we reconstruct the geometry of the solvated salt bridge.

  10. Nonstationarity of a two-dimensional perpendicular shock: Competing mechanisms

    Science.gov (United States)

    Lembège, Bertrand; Savoini, Philippe; Hellinger, Petr; Trávníček, Pavel M.

    2009-03-01

    Two-dimensional particle-in-cell (PIC) simulations are used for analyzing in detail different nonstationary behaviors of a perpendicular supercritical shock. A recent study by Hellinger et al. (2007) has shown that the front of a supercritical shock can be dominated by the emission of large-amplitude whistler waves. These waves inhibit the self-reformation driven by the reflected ions; then, the shock front appears almost ``quasi-stationary.'' The present study stresses new complementary results. First, for a fixed β i value, the whistler waves emission (WWE) persists for high M A above a critical Mach number (i.e., M A >= M A WWE). The quasi-stationarity is only apparent and disappears when considering the full 3-D field profiles. Second, for lower M A , the self-reformation is retrieved and becomes dominant as the amplitude of the whistler waves becomes negligible. Third, there exists a transition regime in M A within which both processes compete each other. Fourth, these results are observed for a strictly perpendicular shock only as B 0 is within the simulation plane. When B 0 is out of the simulation plane, no whistler waves emission is evidenced and only self-reformation is recovered. Fifth, the occurrence and disappearance of the nonlinear whistler waves are well recovered in both 2-D PIC and 2-D hybrid simulations. The impacts on the results of the mass ratio (2-D PIC simulations), of the resistivity and spatial resolution (2-D hybrid simulations), and of the size of the simulation box along the shock front are analyzed in detail.

  11. Two-Dimensional Electron-Spin Resonance

    Science.gov (United States)

    Freed, Jack H.

    2000-03-01

    The extension of the concepts of 2D-NMR to ESR posed significant technological challenges, especially for liquids. ESR relaxation times are very short, as low as 10-15 ns. for T_2's. Spectral bandwidths are 100-250 MHz for nitroxide spin labels. Adequate coverage is obtained with 3-5 ns. π/2 (9-17 GHz) microwave pulses into a small low Q resonator. Dead-times are currently 25-30 ns. Additional requirements are rapid phase shifting for phase cycling, nsec. data acquisition, and fast repetition rates (10-100 kHz). 2D-ELDOR (electron-electron double resonance), which is a 3-pulse 2D-exchange experiment, takes about 30 minutes with just 0.5 nanomole spin-probe in solution (SNR 200). 2D-ELDOR is very useful in studies of molecular dynamics and local structure in complex fluids. For such media, the slow rotational dynamics requires a theory based upon the stochastic Liouville equation which enables quantitative interpretation of 2D-ELDOR experiments. In studies of spin-probes in a liquid crystal new insights could be obtained on the dynamic structure in different phases. One obtains, in addition to ordering and reorientation rates of the probes, details of the local dynamic cage: its orienting potential and (slow) relaxation rate. 2D-ELDOR overcomes the loss of resolution resulting from microscopically ordered but macroscopically disordered complex fluids. This is illustrated by studies of the dynamic structure of lipid membrane vesicles, and the effects of adding a peptide. The short dead times enable the observation of both the bulk lipids and the more immobilized lipids that coat (or are trapped) by the (aggregates of) peptides. Also, new developments of multi-quantum (2D) FT-ESR from nitroxide spin labels interacting by dipolar interactions show considerable promise in measuring distances of ca. 15-70A in macromolecules.

  12. Two-dimensional gauge theoretic supergravities

    Science.gov (United States)

    Cangemi, D.; Leblanc, M.

    1994-05-01

    We investigate two-dimensional supergravity theories, which can be built from a topological and gauge invariant action defined on an ordinary surface. One is the N = 1 supersymmetric extension of the Jackiw-Teitelboim model presented by Chamseddine in a superspace formalism. We complement the proof of Montano, Aoaki and Sonnenschein that this extension is topological and gauge invariant, based on the graded de Sitter algebra. Not only do the equations of motion correspond to the supergravity ones and do gauge transformations encompass local supersymmetries, but we also identify the ∫-theory with the superfield formalism action written by Chamseddine. Next, we show that the N = 1 supersymmetric extension of string-inspired two-dimensional dilaton gravity put forward by Park and Strominger cannot be written as a ∫-theory. As an alternative, we propose two topological and gauge theories that are based on a graded extension of the extended Poincaré algebra and satisfy a vanishing-curvature condition. Both models are supersymmetric extensions of the string-inspired dilaton gravity.

  13. Two-Dimensional Theory of Scientific Representation

    Directory of Open Access Journals (Sweden)

    A Yaghmaie

    2013-03-01

    Full Text Available Scientific representation is an interesting topic for philosophers of science, many of whom have recently explored it from different points of view. There are currently two competing approaches to the issue: cognitive and non-cognitive, and each of them claims its own merits over the other. This article tries to provide a hybrid theory of scientific representation, called Two-Dimensional Theory of Scientific Representation, which has the merits of the two accounts and is free of their shortcomings. To do this, we will argue that although scientific representation needs to use the notion of intentionality, such a notion is defined and realized in a simply structural form contrary to what cognitive approach says about intentionality. After a short introduction, the second part of the paper is devoted to introducing theories of scientific representation briefly. In the third part, the structural accounts of representation will be criticized. The next step is to introduce the two-dimensional theory which involves two key components: fixing and structural fitness. It will be argued that fitness is an objective and non-intentional relation, while fixing is intentional.

  14. Two-dimensional shape memory graphene oxide

    Science.gov (United States)

    Chang, Zhenyue; Deng, Junkai; Chandrakumara, Ganaka G.; Yan, Wenyi; Liu, Jefferson Zhe

    2016-06-01

    Driven by the increasing demand for micro-/nano-technologies, stimuli-responsive shape memory materials at nanoscale have recently attracted great research interests. However, by reducing the size of conventional shape memory materials down to approximately nanometre range, the shape memory effect diminishes. Here, using density functional theory calculations, we report the discovery of a shape memory effect in a two-dimensional atomically thin graphene oxide crystal with ordered epoxy groups, namely C8O. A maximum recoverable strain of 14.5% is achieved as a result of reversible phase transition between two intrinsically stable phases. Our calculations conclude co-existence of the two stable phases in a coherent crystal lattice, giving rise to the possibility of constructing multiple temporary shapes in a single material, thus, enabling highly desirable programmability. With an atomic thickness, excellent shape memory mechanical properties and electric field stimulus, the discovery of a two-dimensional shape memory graphene oxide opens a path for the development of exceptional micro-/nano-electromechanical devices.

  15. Photodetectors based on graphene, other two-dimensional materials and hybrid systems.

    Science.gov (United States)

    Koppens, F H L; Mueller, T; Avouris, Ph; Ferrari, A C; Vitiello, M S; Polini, M

    2014-10-01

    Graphene and other two-dimensional materials, such as transition metal dichalcogenides, have rapidly established themselves as intriguing building blocks for optoelectronic applications, with a strong focus on various photodetection platforms. The versatility of these material systems enables their application in areas including ultrafast and ultrasensitive detection of light in the ultraviolet, visible, infrared and terahertz frequency ranges. These detectors can be integrated with other photonic components based on the same material, as well as with silicon photonic and electronic technologies. Here, we provide an overview and evaluation of state-of-the-art photodetectors based on graphene, other two-dimensional materials, and hybrid systems based on the combination of different two-dimensional crystals or of two-dimensional crystals and other (nano)materials, such as plasmonic nanoparticles, semiconductors, quantum dots, or their integration with (silicon) waveguides.

  16. Existence and Stability of Two-Dimensional Compact-Like Discrete Breathers in Discrete Two-Dimensional Monatomic Square Lattices

    Institute of Scientific and Technical Information of China (English)

    XU Quan; TIAN Qiang

    2007-01-01

    Two-dimensional compact-like discrete breathers in discrete two-dimensional monatomic square lattices are investigated by discussing a generafized discrete two-dimensional monatomic model.It is proven that the twodimensional compact-like discrete breathers exist not only in two-dimensional soft Ф4 potentials but also in hard two-dimensional Ф4 potentials and pure two-dimensional K4 lattices.The measurements of the two-dimensional compact-like discrete breather cores in soft and hard two-dimensional Ф4 potential are determined by coupling parameter K4,while those in pure two-dimensional K4 lattices have no coupling with parameter K4.The stabilities of the two-dimensional compact-like discrete breathers correlate closely to the coupling parameter K4 and the boundary condition of lattices.

  17. A two-dimensional Stockwell transform for gravity wave analysis of AIRS measurements

    Science.gov (United States)

    Hindley, Neil P.; Smith, Nathan D.; Wright, Corwin J.; Rees, D. Andrew S.; Mitchell, Nicholas J.

    2016-06-01

    Gravity waves (GWs) play a crucial role in the dynamics of the earth's atmosphere. These waves couple lower, middle and upper atmospheric layers by transporting and depositing energy and momentum from their sources to great heights. The accurate parameterisation of GW momentum flux is of key importance to general circulation models but requires accurate measurement of GW properties, which has proved challenging. For more than a decade, the nadir-viewing Atmospheric Infrared Sounder (AIRS) aboard NASA's Aqua satellite has made global, two-dimensional (2-D) measurements of stratospheric radiances in which GWs can be detected. However, one problem with current one-dimensional methods for GW analysis of these data is that they can introduce significant unwanted biases. Here, we present a new analysis method that resolves this problem. Our method uses a 2-D Stockwell transform (2DST) to measure GW amplitudes, horizontal wavelengths and directions of propagation using both the along-track and cross-track dimensions simultaneously. We first test our new method and demonstrate that it can accurately measure GW properties in a specified wave field. We then show that by using a new elliptical spectral window in the 2DST, in place of the traditional Gaussian, we can dramatically improve the recovery of wave amplitude over the standard approach. We then use our improved method to measure GW properties and momentum fluxes in AIRS measurements over two regions known to be intense hotspots of GW activity: (i) the Drake Passage/Antarctic Peninsula and (ii) the isolated mountainous island of South Georgia. The significance of our new 2DST method is that it provides more accurate, unbiased and better localised measurements of key GW properties compared to most current methods. The added flexibility offered by the scaling parameter and our new spectral window presented here extend the usefulness of our 2DST method to other areas of geophysical data analysis and beyond.

  18. Recent advances in optoelectronic properties and applications of two-dimensional metal chalcogenides

    Science.gov (United States)

    Congxin, Xia; Jingbo, Li

    2016-05-01

    Since two-dimensional (2D) graphene was fabricated successfully, many kinds of graphene-like 2D materials have attracted extensive attention. Among them, the studies of 2D metal chalcogenides have become the focus of intense research due to their unique physical properties and promising applications. Here, we review significant recent advances in optoelectronic properties and applications of 2D metal chalcogenides. This review highlights the recent progress of synthesis, characterization and isolation of single and few layer metal chalcogenides nanosheets. Moreover, we also focus on the recent important progress of electronic, optical properties and optoelectronic devices of 2D metal chalcogenides. Additionally, the theoretical model and understanding on the band structures, optical properties and related physical mechanism are also reviewed. Finally, we give some personal perspectives on potential research problems in the optoelectronic characteristics of 2D metal chalcogenides and related device applications.

  19. Spatiotemporal vector pulse shaping of femtosecond laser pulses with a multi-pass two-dimensional spatial light modulator.

    Science.gov (United States)

    Esumi, Y; Kabir, M D; Kannari, F

    2009-10-12

    A novel non-interferometric vector pulse-shaping scheme is developed for femtosecond laser pulses using a two-dimensional spatial light modulator (2D-SLM). By utilizing spatiotemporal pulse shaping obtainable by the 2D-SLM, we demonstrate spatiotemporal vector pulse shaping for the first time.

  20. Driving performance of a two-dimensional homopolar linear DC motor

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Y.; Yamaguchi, M.; Kano, Y. [Tokyo University of Agriculture and Technology, Tokyo (Japan)

    1998-05-01

    This paper presents a novel two-dimensional homopolar linear de motor (LDM) which can realize two-dimensional (2-D) motion. For position control purposes, two kinds of position detecting methods are proposed. The position in one position is detected by means of a capacitive sensor which makes the output of the sensor partially immune to the variation of the gap between electrodes. The position in the other direction is achieved by exploiting the position dependent property of the driving coil inductance, instead of using an independent sensor. The position control is implemented on the motor and 2-D tracking performance is analyzed. Experiments show that the motor demonstrates satisfactory driving performance, 2-D tracking error being within 5.5% when the angular frequency of reference signal is 3.14 rad./s. 7 refs., 17 figs., 2 tabs.

  1. Experimental studies of spin-imbalanced Fermi gases in 2D geometries

    Science.gov (United States)

    Thomas, John

    We study the thermodynamics of a quasi-two-dimensional Fermi gas, which is not quite two-dimensional (2D), but far from three dimensional (3D). This system offers opportunities to test predictions that cross interdisciplinary boundaries, such as enhanced superfluid transition temperatures in spin-imbalanced quasi-2D superconductors, and provides important benchmarks for calculations of the phase diagrams. In the experiments, an ultra-cold Fermi gas is confined in an infrared CO2 laser standing-wave, which produces periodic pancake-shaped potential wells, separated by 5.3 μm. To study the thermodynamics, we load an ultra-cold mixture of N1 = 800 spin 1/2 -up and N2 interaction strength and spin imbalance N2/N1. The measured properties are in disagreement with 2D-BCS theory, but can be fit by a 2D-polaron gas model, where each atom is surrounded by a cloud of particle-hole pairs of the opposite spin. However, this model fails to predict a transition to a spin-balanced central region as N2/N1is increased. Supported by the physics divisions of ARO, AFOSR, and NSF and by the Division of Materials Science and Engineering, the Office of Basic Energy Sciences, DOE.

  2. Hilbert Statistics of Vorticity Scaling in Two-Dimensional Turbulence

    CERN Document Server

    Tan, H S; Meng, Jianping

    2014-01-01

    In this paper, the scaling property of the inverse energy cascade and forward enstrophy cascade of the vorticity filed $\\omega(x,y)$ in two-dimensional (2D) turbulence is analyzed. This is accomplished by applying a Hilbert-based technique, namely Hilbert-Huang Transform, to a vorticity field obtained from a $8192^2$ grid-points direct numerical simulation of the 2D turbulence with a forcing scale $k_f=100$ and an Ekman friction. The measured joint probability density function $p(C,k)$ of mode $C_i(x)$ of the vorticity $\\omega$ and instantaneous wavenumber $k(x)$ is separated by the forcing scale $k_f$ into two parts, which corresponding to the inverse energy cascade and the forward enstrophy cascade. It is found that all conditional pdf $p(C\\vert k)$ at given wavenumber $k$ has an exponential tail. In the inverse energy cascade, the shape of $p(C\\vert k)$ does collapse with each other, indicating a nonintermittent cascade. The measured scaling exponent $\\zeta_{\\omega}^I(q)$ is linear with the statistical ord...

  3. Diamagnetic phase transitions in two-dimensional conductors

    Science.gov (United States)

    Bakaleinikov, L. A.; Gordon, A.

    2014-11-01

    A theory describing the susceptibility amplitude and the magnetic induction bifurcation near the dHvA driven diamagnetic phase transitions in quasi two-dimensional (2D) organic conductors of the (ET)2X with X=Cu(NCS)2, KHg(SCN)4, I3, AuBr2, IBr2, etc. is presented. We show that there is a drastic increase in the temperature and magnetic field dependence of the susceptibility amplitude on approaching the diamagnetic phase transition point. Near the phase transition point the temperature and magnetic field dependences are fitted by the ones typical of the mean-field phase transition theory. These dependences confirm the long-range character of the magnetic interactions among the conduction electrons leading to diamagnetic phase transitions. We demonstrate that the magnetic induction splitting of nuclear magnetic resonance (NMR) and muon spin-rotation spectroscopy (μSR) lines due to two Condon domains decreases tending to zero on approaching the diamagnetic phase transition. This decrease is fitted by the temperature and magnetic field dependence of the susceptibility characteristic of the mean-field theory of phase transitions. Performing new susceptibility, NMR and μSR experiments will enable to detect diamagnetic phase transitions and Condon domains in quasi 2D metals.

  4. Two-dimensional Fourier transform ESR correlation spectroscopy

    Science.gov (United States)

    Gorcester, Jeff; Freed, Jack H.

    1988-04-01

    We describe our pulsed two-dimensional Fourier transform ESR experiment and demonstrate its applicabilty for the double resonance of motionally narrowed nitroxides. Multiple pulse irradiation of the entire nitroxide spectrum enables the correlation of two precessional periods, allowing observation of cross correlations between hyperfine lines introduced by magnetization transfer in the case of a three-pulse experiment (2D ELDOR), or coherence transfer in the case of a two-pulse experiment (COSY). Cross correlations are revealed by the presence of cross peaks which connect the autocorrelation lines appearing along the diagonal ω1=ω2. The amplitudes of these cross peaks are determined by the rates of magnetization transfer in the 2D ELDOR experiment. The density operator theory for the experiment is outlined and applied to the determination of Heisenberg exchange (HE) rates in 2,2,6,6-tetramethyl-4-piperidone-N-oxyl-d15 (PD-tempone) dissolved in toluene-d8. The quantitative accuracy of this experiment is established by comparison with the HE rate measured from the dependence of the spin echo T2 on nitroxide concentration.

  5. Subsurface imaging of two-dimensional materials at the nanoscale

    Science.gov (United States)

    Dinelli, Franco; Pingue, Pasqualantonio; Kay, Nicholas D.; Kolosov, Oleg V.

    2017-02-01

    Scanning probe microscopy (SPM) represents a powerful tool that, in the past 30 years, has allowed for the investigation of material surfaces in unprecedented ways at the nanoscale level. However, SPM has shown very little capability for depth penetration, which several nanotechnology applications require. Subsurface imaging has been achieved only in a few cases, when subsurface features influence the physical properties of the surface, such as the electronic states or the heat transfer. Ultrasonic force microscopy (UFM), an adaption of the contact mode atomic force microscopy, can dynamically measure the stiffness of the elastic contact between the probing tip and the sample surface. In particular, UFM has proven highly sensitive to the near-surface elastic field in non-homogeneous samples. In this paper, we present an investigation of two-dimensional (2D) materials, namely flakes of graphite and molybdenum disulphide placed on structured polymeric substrates. We show that UFM can non-destructively distinguish suspended and supported areas and localise defects, such as buckling or delamination of adjacent monolayers, generated by residual stress. Specifically, UFM can probe small variations in the local indentation induced by the mechanical interaction between the tip and the sample. Therefore, any change in the elastic modulus within the volume perturbed by the applied load or the flexural bending of the suspended areas can be detected and imaged. These investigation capabilities are very promising in order to study the buried interfaces of nanostructured 2D materials such as in graphene-based devices.

  6. Mathematical modeling of the neuron morphology using two dimensional images.

    Science.gov (United States)

    Rajković, Katarina; Marić, Dušica L; Milošević, Nebojša T; Jeremic, Sanja; Arsenijević, Valentina Arsić; Rajković, Nemanja

    2016-02-01

    In this study mathematical analyses such as the analysis of area and length, fractal analysis and modified Sholl analysis were applied on two dimensional (2D) images of neurons from adult human dentate nucleus (DN). Using mathematical analyses main morphological properties were obtained including the size of neuron and soma, the length of all dendrites, the density of dendritic arborization, the position of the maximum density and the irregularity of dendrites. Response surface methodology (RSM) was used for modeling the size of neurons and the length of all dendrites. However, the RSM model based on the second-order polynomial equation was only possible to apply to correlate changes in the size of the neuron with other properties of its morphology. Modeling data provided evidence that the size of DN neurons statistically depended on the size of the soma, the density of dendritic arborization and the irregularity of dendrites. The low value of mean relative percent deviation (MRPD) between the experimental data and the predicted neuron size obtained by RSM model showed that model was suitable for modeling the size of DN neurons. Therefore, RSM can be generally used for modeling neuron size from 2D images.

  7. Two-dimensional investigation of forced bubble oscillation under microgravity

    Institute of Scientific and Technical Information of China (English)

    HONG Ruoyu; Masahiro KAWAJI

    2003-01-01

    Recent referential studies of fluid interfaces subjected to small vibration under microgravity conditions are reviewed. An experimental investigation was carried out aboard the American Space Shuttle Discovery. Two-dimensional (2-D) modeling and simulation were conducted to further understand the experimental results. The oscillation of a bubble in fluid under surface tension is governed by the incompressible Navier-Stokes equations. The SIMPLEC algorithm was used to solve the partial differential equations on an Eulerian mesh in a 2-D coordinate. Free surfaces were represented with the volume of fluid (VOF) obtained by solving a kinematic equation. Surface tension was modeled via a continuous surface force (CSF) algorithm that ensures robustness and accuracy. A new surface reconstruction scheme, alternative phase integration (API) scheme, was adopted to solve the kinematic equation, and was compared with referential schemes. Numerical computations were conducted to simulate the transient behavior of an oscillating gas bubble in mineral oil under different conditions. The bubble positions and shapes under different external vibrations were obtained numerically. The computed bubble oscillation amplitudes were compared with experimental data.

  8. Halogen bonded two-dimensional supramolecul arassemblies studied by high resolution scanning tunneling microscopy

    Institute of Scientific and Technical Information of China (English)

    YANG XunYu; WANG Fang; CHEN QiuXia; WANG LiYan; WANG ZhiQiang

    2007-01-01

    We described the formation of self-organized two-dimensional (2D) assemblies of N-(2,3,5,6-tetrafluoro- 4-iodophenyl)hexadecylamine and 1-dodecyl-imidazole at the liquid/HOPG interface. The two-dimen- sional assemblies showed a fishbone-like pattern structure as revealed by high-resolution scanning tunneling microscopy. Although different interactions can drive the formation of 2D assemblies,as far as we know,this is the first report on halogen bond-driven 2D assemblies.

  9. Two-dimensional Fibonacci grating for far-field super-resolution imaging

    Science.gov (United States)

    Wu, Kedi; Wang, Guo Ping

    2016-12-01

    A two-dimensional (2D) Fibonacci grating is used to transform evanescent waves into propagating waves for far-field super-resolution imaging. By detecting far-field intensity distributions of light field through objects in front of the 2D Fibonacci grating in free space at once, we can retrieve the image of objects with beyond λ/7 spatial resolution. We also find that the coherent illumination case can give a better resolution than incoherent illumination case by such 2D grating-assisted imaging system. The analytical results are verified by numerical simulation.

  10. Two-dimensional relativistic electromagnetic dromion-like soliton in a cold transparent plasma

    Institute of Scientific and Technical Information of China (English)

    Wang Yun-Liang; Zhou Zhong-Xiang; Yuan Cheng-Xun; Jiang Xiang-Qian; Qin Ru-Hu

    2006-01-01

    By using a standard multiple scale method, a Davey-Stewartson (DS) equation has been derived and also applied to a multi-dimensional analytical investigation on the interaction of an ultra-intense laser pulse with a cold unmagnetized transparent electron-ion plasma. The regions of instability are found by considering the modulation instability of a plane wave solution of the DS equation. The DS equation is just of the Daveylution, i.e. a two-dimensional (2D) dromion soliton decaying exponentially in all spatial directions. A 2D relativistic electromagnetic dromion-like soliton (2D REDLS) is derived for a vector potential.

  11. Entropy of Bit-Stuffing-Induced Measures for Two-Dimensional Checkerboard Constraints

    DEFF Research Database (Denmark)

    Forchhammer, Søren; Vaarby, Torben Strange

    2007-01-01

    A modified bit-stuffing scheme for two-dimensional (2-D) checkerboard constraints is introduced. The entropy of the scheme is determined based on a probability measure defined by the modified bit-stuffing. Entropy results of the scheme are given for 2-D constraints on a binary alphabet....... The constraints considered are 2-D RLL (d, infinity) for d = 2, 3 and 4 as well as for the constraint with a minimum 1-norm distance of 3 between Is. For these results the entropy is within 1-2% of an upper bound on the capacity for the constraint. As a variation of the scheme, periodic merging arrays are also...

  12. Simulated annealing applied to two-dimensional low-beta reduced magnetohydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Chikasue, Y., E-mail: chikasue@ppl.k.u-tokyo.ac.jp [Graduate School of Frontier Sciences, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa-shi, Chiba 277-8561 (Japan); Furukawa, M., E-mail: furukawa@damp.tottori-u.ac.jp [Graduate School of Engineering, Tottori University, Minami 4-101, Koyama-cho, Tottori-shi, Tottori 680-8552 (Japan)

    2015-02-15

    The simulated annealing (SA) method is applied to two-dimensional (2D) low-beta reduced magnetohydrodynamics (R-MHD). We have successfully obtained stationary states of the system numerically by the SA method with Casimir invariants preserved. Since the 2D low-beta R-MHD has two fields, the relaxation process becomes complex compared to a single field system such as 2D Euler flow. The obtained stationary state can have fine structure. We have found that the fine structure appears because the relaxation processes are different between kinetic energy and magnetic energy.

  13. Temperature derivative of the chemical potential and its magnetooscillations in two-dimensional system

    OpenAIRE

    Tupikov, Y.; Kuntsevich, A. Yu.; Pudalov, V. M.; Burmistrov, I. S.

    2015-01-01

    We report first thermodynamic measurements of the temperature derivative of chemical potential (d{\\mu}/dT) in two-dimensional (2D) electron systems. In order to test the technique we have chosen Schottky gated GaAs/AlGaAs heterojunctions and detected experimentally in this 2D system quantum magnetooscillations of d{\\mu}/dT. We also present a Lifshits-Kosevitch type theory for the d{\\mu}/dT magnetooscillations in 2D systems and compare the theory with experimental data. The magnetic field depe...

  14. Fractal characteristics of far-field diffraction patterns for two-dimensional Thue-Morse quasicrystals

    Institute of Scientific and Technical Information of China (English)

    YANG Ming-yang; ZHOU Jun; L Petti; S De Nicola; P Mormile

    2011-01-01

    We report a numerical method to analyze the fractal characteristics of far-field diffraction patterns for two-dimensional Thue-Morse(2-D TM) structures.The far-field diffraction patterns of the 2-D TM structures can be obtained by the numerical method,and they have a good agreement with the experimental ones.The analysis shows that the fractal characteristics of far-field diffraction patterns for the 2-D TM structures are determined by the inflation rule,which have potential applications in the design of optical diffraction devices.

  15. The PLSI Method of Stabilizing Two-Dimensional Nonsymmetric Half-Plane Recursive Digital Filters

    OpenAIRE

    Gangatharan N; Reddy PS

    2003-01-01

    Two-dimensional (2D) recursive digital filters find applications in image processing as in medical X-ray processing. Nonsymmetric half-plane (NSHP) filters have definitely positive magnitude characteristics as opposed to quarter-plane (QP) filters. In this paper, we provide methods for stabilizing the given 2D NSHP polynomial by the planar least squares inverse (PLSI) method. We have proved in this paper that if the given 2D unstable NSHP polynomial and its PLSI are of the same degree, the P...

  16. Cavity-enhanced ultrafast two-dimensional spectroscopy using higher order modes

    Science.gov (United States)

    Allison, Thomas K.

    2017-02-01

    We describe methods using frequency combs and optical resonators for recording two-dimensional (2D) ultrafast spectroscopy signals with high sensitivity. By coupling multiple frequency combs to higher-order modes of one or more optical cavities, background-free, cavity-enhanced 2D spectroscopy signals are naturally generated via phase cycling. As in cavity-enhanced ultrafast transient absorption spectroscopy, the signal to noise is enhanced by a factor proportional to the cavity finesse squared, so even using cavities of modest finesse, a very high sensitivity is expected, enabling ultrafast 2D spectroscopy experiments in dilute molecular beams.

  17. Cavity-enhanced ultrafast two-dimensional spectroscopy using higher-order modes

    CERN Document Server

    Allison, Thomas K

    2016-01-01

    We describe methods using frequency combs and optical resonators for recording two-dimensional (2D) ultrafast spectroscopy signals with high sensitivity. By coupling multiple frequency combs to higher-order modes of one or more optical cavities, background-free, cavity-enhanced 2D spectroscopy signals are naturally generated via phase cycling. As in cavity-enhanced ultrafast transient absorption spectroscopy (CE-TAS), the signal to noise is enhanced by a factor proportional to the cavity finesse squared, so even using cavities of modest finesse, a very high sensitivity is expected, enabling ultrafast 2D spectroscopy experiments in dilute molecular beams.

  18. The two-dimensional alternative binary L-J system: liquid-gas phase diagram

    Institute of Scientific and Technical Information of China (English)

    张陟; 陈立溁

    2003-01-01

    A two-dimensional (2D) binary system without considering the Lennard-Jones (L-J) potential has been studied by using the Collins model. In this paper, we introduce the L-J potential into the 2D binary system and consider the existence of the holes that are called the "molecular fraction". The liquid-gas phase diagram of the 2D alternative binary L-J system is obtained. The results are quite analogous to the behaviour of 3D substances.

  19. Optimal excitation of two dimensional Holmboe instabilities

    CERN Document Server

    Constantinou, Navid C

    2010-01-01

    Highly stratified shear layers are rendered unstable even at high stratifications by Holmboe instabilities when the density stratification is concentrated in a small region of the shear layer. These instabilities may cause mixing in highly stratified environments. However these instabilities occur in tongues for a limited range of parameters. We perform Generalized Stability analysis of the two dimensional perturbation dynamics of an inviscid Boussinesq stratified shear layer and show that Holmboe instabilities at high Richardson numbers can be excited by their adjoints at amplitudes that are orders of magnitude larger than by introducing initially the unstable mode itself. We also determine the optimal growth that obtains for parameters for which there is no instability. We find that there is potential for large transient growth regardless of whether the background flow is exponentially stable or not and that the characteristic structure of the Holmboe instability asymptotically emerges for parameter values ...

  20. Phonon hydrodynamics in two-dimensional materials.

    Science.gov (United States)

    Cepellotti, Andrea; Fugallo, Giorgia; Paulatto, Lorenzo; Lazzeri, Michele; Mauri, Francesco; Marzari, Nicola

    2015-03-06

    The conduction of heat in two dimensions displays a wealth of fascinating phenomena of key relevance to the scientific understanding and technological applications of graphene and related materials. Here, we use density-functional perturbation theory and an exact, variational solution of the Boltzmann transport equation to study fully from first-principles phonon transport and heat conductivity in graphene, boron nitride, molybdenum disulphide and the functionalized derivatives graphane and fluorographene. In all these materials, and at variance with typical three-dimensional solids, normal processes keep dominating over Umklapp scattering well-above cryogenic conditions, extending to room temperature and more. As a result, novel regimes emerge, with Poiseuille and Ziman hydrodynamics, hitherto typically confined to ultra-low temperatures, characterizing transport at ordinary conditions. Most remarkably, several of these two-dimensional materials admit wave-like heat diffusion, with second sound present at room temperature and above in graphene, boron nitride and graphane.

  1. Probabilistic Universality in two-dimensional Dynamics

    CERN Document Server

    Lyubich, Mikhail

    2011-01-01

    In this paper we continue to explore infinitely renormalizable H\\'enon maps with small Jacobian. It was shown in [CLM] that contrary to the one-dimensional intuition, the Cantor attractor of such a map is non-rigid and the conjugacy with the one-dimensional Cantor attractor is at most 1/2-H\\"older. Another formulation of this phenomenon is that the scaling structure of the H\\'enon Cantor attractor differs from its one-dimensional counterpart. However, in this paper we prove that the weight assigned by the canonical invariant measure to these bad spots tends to zero on microscopic scales. This phenomenon is called {\\it Probabilistic Universality}. It implies, in particular, that the Hausdorff dimension of the canonical measure is universal. In this way, universality and rigidity phenomena of one-dimensional dynamics assume a probabilistic nature in the two-dimensional world.

  2. Two-dimensional position sensitive neutron detector

    Indian Academy of Sciences (India)

    A M Shaikh; S S Desai; A K Patra

    2004-08-01

    A two-dimensional position sensitive neutron detector has been developed. The detector is a 3He + Kr filled multiwire proportional counter with charge division position readout and has a sensitive area of 345 mm × 345 mm, pixel size 5 mm × 5 mm, active depth 25 mm and is designed for efficiency of 70% for 4 Å neutrons. The detector is tested with 0.5 bar 3He + 1.5 bar krypton gas mixture in active chamber and 2 bar 4He in compensating chamber. The pulse height spectrum recorded at an anode potential of 2000 V shows energy resolution of ∼ 25% for the 764 keV peak. A spatial resolution of 8 mm × 6 mm is achieved. The detector is suitable for SANS studies in the range of 0.02–0.25 Å-1.

  3. Janus Spectra in Two-Dimensional Flows

    Science.gov (United States)

    Liu, Chien-Chia; Cerbus, Rory T.; Chakraborty, Pinaki

    2016-09-01

    In large-scale atmospheric flows, soap-film flows, and other two-dimensional flows, the exponent of the turbulent energy spectra, α , may theoretically take either of two distinct values, 3 or 5 /3 , but measurements downstream of obstacles have invariably revealed α =3 . Here we report experiments on soap-film flows where downstream of obstacles there exists a sizable interval in which α transitions from 3 to 5 /3 for the streamwise fluctuations but remains equal to 3 for the transverse fluctuations, as if two mutually independent turbulent fields of disparate dynamics were concurrently active within the flow. This species of turbulent energy spectra, which we term the Janus spectra, has never been observed or predicted theoretically. Our results may open up new vistas in the study of turbulence and geophysical flows.

  4. Study of the Effect of Temperature on the Conformation of Ovotransferrin by Two-Dimensional Infrared Correlation Spectroscopy%二维红外相关光谱研究温度对卵转铁蛋白构象的影响

    Institute of Scientific and Technical Information of China (English)

    任国栋; 郭爱玲; 耿放; 马美湖; 黄群; 武小芬

    2012-01-01

    The conformation changes of Apo-Ovotransferrin and Holo-Ovotransferrin were studied with the heat treatment 25~ 95 ℃ by using Fourier transform infrared spectroscopy (FT1R) and two-dimensional correlation spectroscopy analyzer. The results of one-dimensional infrared spectroscopy showed that with the increase in temperature, the peak at 3 300 cm-1 of Apo-Ovotransferrin shifted more than that of Holo-Ovotransferrin. The peak at 3 300 cm-1 derived from stretching vibrations of N-H and O-H indicates that iron-binding enhanced the role of hydrogen bonds and resistance to heat The changing order of the secondary structure of ovotransferrin was determined by analyzing two-dimensional infrared spectra, witch is β-sheet>amide Ⅱ >-CH2- bending vibratioa In addition, it was found that the cross-peaks at 1 652 and 1 688 cm-1 are different in synchronous and asynchronous counter maps by comparing Apo-Ovotransferrin with Holo-Ovotransferrin. It was suggested that the temperature made less impact on the

  5. Equivalency of two-dimensional algebras

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Gildemar Carneiro dos; Pomponet Filho, Balbino Jose S. [Universidade Federal da Bahia (UFBA), BA (Brazil). Inst. de Fisica

    2011-07-01

    Full text: Let us consider a vector z = xi + yj over the field of real numbers, whose basis (i,j) satisfy a given algebra. Any property of this algebra will be reflected in any function of z, so we can state that the knowledge of the properties of an algebra leads to more general conclusions than the knowledge of the properties of a function. However structural properties of an algebra do not change when this algebra suffers a linear transformation, though the structural constants defining this algebra do change. We say that two algebras are equivalent to each other whenever they are related by a linear transformation. In this case, we have found that some relations between the structural constants are sufficient to recognize whether or not an algebra is equivalent to another. In spite that the basis transform linearly, the structural constants change like a third order tensor, but some combinations of these tensors result in a linear transformation, allowing to write the entries of the transformation matrix as function of the structural constants. Eventually, a systematic way to find the transformation matrix between these equivalent algebras is obtained. In this sense, we have performed the thorough classification of associative commutative two-dimensional algebras, and find that even non-division algebra may be helpful in solving non-linear dynamic systems. The Mandelbrot set was used to have a pictorial view of each algebra, since equivalent algebras result in the same pattern. Presently we have succeeded in classifying some non-associative two-dimensional algebras, a task more difficult than for associative one. (author)

  6. Imaging hemodynamic changes in preterm infant brains with two-dimensional diffuse optical tomography

    Science.gov (United States)

    Gao, Feng; Ma, Yiwen; Yang, Fang; Zhao, Huijuan; Jiang, Jingying; Kusaka, Takashi; Ueno, Masanori; Yamada, Yukio

    2008-02-01

    We present our preliminary results on two-dimensional (2-D) optical tomographic imaging of hemodynamic changes of two preterm infant brains in different ventilation settings conditions. The investigations use the established two-wavelength, 16-channel time-correlated single photon counting system for the detection, and the generalized pulse spectrum technique based algorithm for the image reconstruction. The experiments demonstrate that two-dimensional diffuse optical tomography may be a potent and relatively simple way of investigating the functions and neural development of infant brains in the perinatal period.

  7. APPLICATION OF TWO-DIMENSIONAL WAVELET TRANSFORM IN NEAR-SHORE X-BAND RADAR IMAGES

    Institute of Scientific and Technical Information of China (English)

    FENG Xiang-bo; YAN Yi-xin; ZHANG Wei

    2011-01-01

    Among existing remote sensing applications, land-based X-band radar is an effective technique to monitor the wave fields,and spatial wave information could be obtained from the radar images.Two-dimensional Fourier Transform (2-D FT) is the common algorithm to derive the spectra of radar images.However, the wave field in the nearshore area is highly non-homogeneous due to wave refraction, shoaling, and other coastal mechanisms.When applied in nearshore radar images, 2-D FT would lead to ambiguity of wave characteristics in wave number domain.In this article, we introduce two-dimensional Wavelet Transform (2-D WT) to capture the non-homogeneity of wave fields from nearshore radar images.The results show that wave number spectra by 2-D WT at six parallel space locations in the given image clearly present the shoaling of nearshore waves.Wave number of the peak wave energy is increasing along the inshore direction, and dominant direction of the spectra changes from South South West (SSW) to West South West (WSW).To verify the results of2-D WT, wave shoaling in radar images is calculated based on dispersion relation.The theoretical calculation results agree with the results of 2-D WT on the whole.The encouraging performance of 2-D WT indicates its strong capability of revealing the non-homogeneity of wave fields in nearshore X-band radar images.

  8. Diamagnetic phase transitions in two-dimensional conductors

    Energy Technology Data Exchange (ETDEWEB)

    Bakaleinikov, L.A., E-mail: bakal.ammp@mail.ioffe.ru [A.F. Ioffe Physico-Technical Institute, Russian Academy of Sciences, St. Petersburg 194021 (Russian Federation); Department of Mathematics and Physics, Faculty of Natural Sciences, University of Haifa, Campus Oranim, Tivon 36006 (Israel); Gordon, A. [Department of Mathematics and Physics, Faculty of Natural Sciences, University of Haifa, Campus Oranim, Tivon 36006 (Israel)

    2014-11-15

    A theory describing the susceptibility amplitude and the magnetic induction bifurcation near the dHvA driven diamagnetic phase transitions in quasi two-dimensional (2D) organic conductors of the (ET){sub 2}X with X=Cu(NCS){sub 2},KHg(SCN){sub 4},I{sub 3},AuBr{sub 2},IBr{sub 2}, etc. is presented. We show that there is a drastic increase in the temperature and magnetic field dependence of the susceptibility amplitude on approaching the diamagnetic phase transition point. Near the phase transition point the temperature and magnetic field dependences are fitted by the ones typical of the mean-field phase transition theory. These dependences confirm the long-range character of the magnetic interactions among the conduction electrons leading to diamagnetic phase transitions. We demonstrate that the magnetic induction splitting of nuclear magnetic resonance (NMR) and muon spin-rotation spectroscopy (μSR) lines due to two Condon domains decreases tending to zero on approaching the diamagnetic phase transition. This decrease is fitted by the temperature and magnetic field dependence of the susceptibility characteristic of the mean-field theory of phase transitions. Performing new susceptibility, NMR and μSR experiments will enable to detect diamagnetic phase transitions and Condon domains in quasi 2D metals. - Highlights: • A theory of diamagnetic phase transitions (DPTs) is presented in 2D organic conductors. • The behaviour of the susceptibility amplitude and the induction splitting is shown near the DPT. • The calculated quantities are described by the mean-field theory of phase transitions.

  9. Internetwork magnetic field as revealed by two-dimensional inversions

    Science.gov (United States)

    Danilovic, S.; van Noort, M.; Rempel, M.

    2016-09-01

    Context. Properties of magnetic field in the internetwork regions are still fairly unknown because of rather weak spectropolarimetric signals. Aims: We address the matter by using the two-dimensional (2D) inversion code, which is able to retrieve the information on smallest spatial scales up to the diffraction limit, while being less susceptible to noise than most of the previous methods used. Methods: Performance of the code and the impact of various effects on the retrieved field distribution is tested first on the realistic magneto-hydrodynamic (MHD) simulations. The best inversion scenario is then applied to the real data obtained by Spectropolarimeter (SP) on board Hinode. Results: Tests on simulations show that: (1) the best choice of node position ensures a decent retrieval of all parameters; (2) the code performs well for different configurations of magnetic field; (3) slightly different noise levels or slightly different defocus included in the spatial point spread function (PSF) produces no significant effect on the results; and (4) temporal integration shifts the field distribution to a stronger, more horizontally inclined field. Conclusions: Although the contribution of the weak field is slightly overestimated owing to noise, 2D inversions are able to recover well the overall distribution of the magnetic field strength. Application of the 2D inversion code on the Hinode SP internetwork observations reveals a monotonic field strength distribution. The mean field strength at optical depth unity is ~ 130 G. At higher layers, field strength drops as the field becomes more horizontal. Regarding the distribution of the field inclination, tests show that we cannot directly retrieve it with the observations and tools at hand, however, the obtained distributions are consistent with those expected from simulations with a quasi-isotropic field inclination after accounting for observational effects.

  10. 2D materials for nanophotonic devices

    Science.gov (United States)

    Xu, Renjing; Yang, Jiong; Zhang, Shuang; Pei, Jiajie; Lu, Yuerui

    2015-12-01

    Two-dimensional (2D) materials have become very important building blocks for electronic, photonic, and phononic devices. The 2D material family has four key members, including the metallic graphene, transition metal dichalcogenide (TMD) layered semiconductors, semiconducting black phosphorous, and the insulating h-BN. Owing to the strong quantum confinements and defect-free surfaces, these atomically thin layers have offered us perfect platforms to investigate the interactions among photons, electrons and phonons. The unique interactions in these 2D materials are very important for both scientific research and application engineering. In this talk, I would like to briefly summarize and highlight the key findings, opportunities and challenges in this field. Next, I will introduce/highlight our recent achievements. We demonstrated atomically thin micro-lens and gratings using 2D MoS2, which is the thinnest optical component around the world. These devices are based on our discovery that the elastic light-matter interactions in highindex 2D materials is very strong. Also, I would like to introduce a new two-dimensional material phosphorene. Phosphorene has strongly anisotropic optical response, which creates 1D excitons in a 2D system. The strong confinement in phosphorene also enables the ultra-high trion (charged exciton) binding energies, which have been successfully measured in our experiments. Finally, I will briefly talk about the potential applications of 2D materials in energy harvesting.

  11. Two dimensional soft material: new faces of graphene oxide.

    Science.gov (United States)

    Kim, Jaemyung; Cote, Laura J; Huang, Jiaxing

    2012-08-21

    Graphite oxide sheets, now called graphene oxide (GO), can be made from chemical exfoliation of graphite by reactions that have been known for 150 years. Because GO is a promising solution-processable precursor for the bulk production of graphene, interest in this old material has resurged. The reactions to produce GO add oxygenated functional groups to the graphene sheets on their basal plane and edges, and this derivatization breaks the π-conjugated network, resulting in electrically insulating but highly water-dispersible sheets. Apart from making graphene, GO itself has many intriguing properties. Like graphene, GO is a two-dimensional (2D) sheet with feature sizes at two abruptly different length scales. The apparent thickness of the functionalized carbon sheet is approximately 1 nm, but the lateral dimensions can range from a few nanometers to hundreds of micrometers. Therefore, researchers can think of GO as either a single molecule or a particle, depending on which length scale is of greater interest. At the same time, GO can be viewed as an unconventional soft material, such as a 2D polymer, highly anisotropic colloid, membrane, liquid crystal, or amphiphile. In this Account, we highlight the soft material characteristics of GO. GO consists of nanographitic patches surrounded by largely disordered, oxygenated domains. Such structural characteristics effectively make GO a 2D amphiphile with a hydrophilic periphery and largely hydrophobic center. This insight has led to better understanding of the solution properties of GO for making thin films and new applications of GO as a surfactant. Changes in pH and sheet size can tune the amphiphilicity of GO, leading to intriguing interfacial activities. In addition, new all-carbon composites made of only graphitic nanostructures using GO as a dispersing agent have potential applications in photovoltaics and energy storage. On the other hand, GO can function as a 2D random diblock copolymer, one block graphitic and

  12. On numerical evaluation of two-dimensional phase integrals

    DEFF Research Database (Denmark)

    Lessow, H.; Rusch, W.; Schjær-Jacobsen, Hans

    1975-01-01

    The relative advantages of several common numerical integration algorithms used in computing two-dimensional phase integrals are evaluated.......The relative advantages of several common numerical integration algorithms used in computing two-dimensional phase integrals are evaluated....

  13. Ionic solutions of two-dimensional materials

    Science.gov (United States)

    Cullen, Patrick L.; Cox, Kathleen M.; Bin Subhan, Mohammed K.; Picco, Loren; Payton, Oliver D.; Buckley, David J.; Miller, Thomas S.; Hodge, Stephen A.; Skipper, Neal T.; Tileli, Vasiliki; Howard, Christopher A.

    2016-11-01

    Strategies for forming liquid dispersions of nanomaterials typically focus on retarding reaggregation, for example via surface modification, as opposed to promoting the thermodynamically driven dissolution common for molecule-sized species. Here we demonstrate the true dissolution of a wide range of important 2D nanomaterials by forming layered material salts that spontaneously dissolve in polar solvents yielding ionic solutions. The benign dissolution advantageously maintains the morphology of the starting material, is stable against reaggregation and can achieve solutions containing exclusively individualized monolayers. Importantly, the charge on the anionic nanosheet solutes is reversible, enables targeted deposition over large areas via electroplating and can initiate novel self-assembly upon drying. Our findings thus reveal a unique solution-like behaviour for 2D materials that enables their scalable production and controlled manipulation.

  14. Electrical and optoelectronic properties of two-dimensional materials

    Science.gov (United States)

    Wang, Qiaoming

    Electrical and optoelectronic properties of bulk semiconductor materials have been extensively explored in last century. However, when reduced to one-dimensional and two-dimensional, many semiconductors start to show unique electrical and optoelectronic behaviors. In this dissertation, electrical and optoelectronic properties of one-dimensional (nanowires) and two-dimensional semiconductor materials are investigated by various techniques, including scanning photocurrent microscopy, scanning Kelvin probe microscopy, Raman spectroscopy, photoluminescence, and finite-element simulations. In our work, gate-tunable photocurrent in ZnO nanowires has been observed under optical excitation in the visible regime, which originates from the nanowire/substrate interface states. This gate tunability in the visible regime can be used to enhance the photon absorption efficiency, and suppress the undesirable visible-light photodetection in ZnO-based solar cells. The power conversion efficiency of CuInSe2/CdS core-shell nanowire solar cells has been investigated. The highest power conversion efficiency per unit area/volume is achieved with core diameter of 50 nm and the thinnest shell thickness. The existence of the optimal geometrical parameters is due to a combined effect of optical resonances and carrier transport/dynamics. Significant current crowding in two-dimensional black phosphorus field-effect transistors has been found, which has been significantly underestimated by the commonly used transmission-line model. This current crowding can lead to Joule heating close to the contacts. New van der Waals metal-semiconductor junctions have been mechanically constructed and systematically studied. The photocurrent on junction area has been demonstrated to originate from the photothermal effect rather than the photovoltaic effect. Our findings suggest that a reasonable control of interface/surface state properties can enable new and beneficial functionalities in nanostructures. We

  15. Improvement in two-dimensional barcode

    Indian Academy of Sciences (India)

    SONAM WASULE; SHILPA METKAR

    2017-07-01

    Barcode is one of the existing systems which is very fast in scanning and more accurate when compared with other coding systems. It is extensively used because speed of scanning the barcode is very high as compared with manual data entry. To increase the capacity of 2D monochrome QR code to 3 fold, 2D colour QR code is developed. The challenge in the development of colour barcode is in its decoding, since the intensity and depth of colours vary during the printing and scanning process. We need to understand the decoding process and make it insensitive to such variations. A lot of work has been already done to deal with such variations but acceptable results have not yet been achieved. The objective behind colour barcode is to increase the capacity to 3 fold as compared with 2D monochrome barcode. In this paper we proposed a novel approach that will increase the capacity of barcode beyond 3 fold and deals with decoding problem of intensity variation. In the proposed technique, quantization of grey levels is specified to handle the problem of intensity variation.

  16. Development of molecular imprinted column-on line-two dimensional liquid chromatography for selective determination of clenbuterol residues in biological samples.

    Science.gov (United States)

    Guo, Pengqi; Luo, Zhimin; Xu, Xinya; Zhou, Yulan; Zhang, Bilin; Chang, Ruimiao; Du, Wei; Chang, Chun; Fu, Qiang

    2017-02-15

    A novel method coupling molecular imprinted monolithic column with two-dimensional liquid chromatography was developed and validated for the analysis of clenbuterol in pork liver and swine urine samples. The polymers were characterized by using Fourier transform infrared spectroscopy, nitrogen adsorption desorption analyses, frontal analysis and the adsorption of selectivity. The results indicated that the imprinted columns were well prepared and possessed high selectivity adsorption capacity. Subsequently, the MIMC-2D-LC (molecular imprinted monolithic column-two dimensional liquid chromatography) method was developed for the selective analysis of clenbuterol in practical samples. The accuracy ranged from 94.3% to 99.7% and from 93.7% to 99.6% for liver and urine, respectively. The relative standard deviation (RSD) of repeatability was lower than 8.6% for both analyses. The limit of detections was 16ng·mL(-1) for liver and 25ng·mL(-1) for urine, respectively. Compared with the reported methods, the disturbance of endogenous impurity could be avoided by the 2D-LC method.

  17. Two-dimensional graphene as a matrix for MALDI imaging mass spectrometry.

    Science.gov (United States)

    Friesen, William L; Schultz, Brian J; Destino, Joel F; Alivio, Theodore E G; Steet, Joseph R; Banerjee, Sarbajit; Wood, Troy D

    2015-11-01

    Here, a matrix using two-dimensional (2D) graphene is demonstrated for the first time in the context of MALDI IMS using a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Although graphene flakes have been used previously in MALDI, it is described here how a single 2D layer of graphene is applied directly on top of rat brain sections and soybean leaves. Several classes of molecules are desorbed and ionized off of the surface of the tissues examined using 2D graphene, with minimal background interference from the matrix. Moreover, no solvents are employed in application of 2D graphene, eliminating the potential for analyte diffusion in liquid droplets during matrix application. Because 2D graphene is an elemental form of carbon, an additional advantage is its high compatibility with the long duration needed for many IMS experiments. Graphical Abstract ᅟ.

  18. Novel two-dimensional DOA estimation with L-shaped array

    Science.gov (United States)

    Xiaofei, Zhang; Jianfeng, Li; Lingyun, Xu

    2011-12-01

    Two-dimensional (2D) direction-of-arrival (DOA) estimation has played an important role in array signal processing. In this article, we address a problem of bind 2D-DOA estimation with L-shaped array. This article links the 2D-DOA estimation problem to the trilinear model. To exploit this link, we derive a trilinear decomposition-based 2D-DOA estimation algorithm in L-shaped array. Without spectral peak searching and pairing, the proposed algorithm employs well. Moreover, our algorithm has much better 2D-DOA estimation performance than the estimation of signal parameters via rotational invariance technique algorithms and propagator method. Simulation results illustrate validity of the algorithm.

  19. Two-dimensional novel optical lattices with multi-well traps for cold atoms or molecules

    Institute of Scientific and Technical Information of China (English)

    Junfa Lu; Xianming Ji; Jianping Yin

    2006-01-01

    We propose some new schemes to constitute two-dimensional (2D) array of multi-well optical dipole traps for cold atoms (or molecules) by using an optical system consisting of a binary π-phase grating and a 2D array of rectangle microlens. We calculate the intensity distribution of each optical well in 2D array of multi-well traps and its geometric parameters and so on. The proposed 2D array of multi-well traps can be used to form novel 2D optical lattices with cold atoms (or molecules), and form various novel optical crystals with cold atoms (or molecules), or to perform quantum computing and quantum information processing on an atom chip, even to realize an array of all-optical multi-well atomic (or molecular) BoseEinstein condensates (BECs) on an all-optical integrated atom (or molecule) chip.

  20. Novel two-dimensional DOA estimation with L-shaped array

    Directory of Open Access Journals (Sweden)

    Xiaofei Zhang

    2011-01-01

    Full Text Available Abstract Two-dimensional (2D direction-of-arrival (DOA estimation has played an important role in array signal processing. In this article, we address a problem of bind 2D-DOA estimation with L-shaped array. This article links the 2D-DOA estimation problem to the trilinear model. To exploit this link, we derive a trilinear decomposition-based 2D-DOA estimation algorithm in L-shaped array. Without spectral peak searching and pairing, the proposed algorithm employs well. Moreover, our algorithm has much better 2D-DOA estimation performance than the estimation of signal parameters via rotational invariance technique algorithms and propagator method. Simulation results illustrate validity of the algorithm.

  1. A Ternary Solvent Method for Large-Sized Two-Dimensional Perovskites.

    Science.gov (United States)

    Chen, Junnian; Gan, Lin; Zhuge, Fuwei; Li, Huiqiao; Song, Jizhong; Zeng, Haibo; Zhai, Tianyou

    2017-02-20

    Recent reports demonstrate that a two-dimensional (2D) structural characteristic can endow perovskites with both remarkable photoelectric conversion efficiency and high stability, but the synthesis of ultrathin 2D perovskites with large sizes by facile solution methods is still a challenge. Reported herein is the controlled growth of 2D (C4 H9 NH3 )2 PbBr4 perovskites by a chlorobenzene-dimethylformide-acetonitrile ternary solvent method. The critical factors, including solvent volume ratio, crystallization temperature, and solvent polarity on the growth dynamics were systematically studied. Under optimum reaction condition, 2D (C4 H9 NH3 )2 PbBr4 perovskites, with the largest lateral dimension of up to 40 μm and smallest thickness down to a few nanometers, were fabricated. Furthermore, various iodine doped 2D (C4 H9 NH3 )2 PbBrx I4-x perovskites were accessed to tune the optical properties rationally.

  2. Two-Dimensional Transition Metal Dichalcogenides and Their Charge Carrier Mobilities in Field-Effect Transistors

    Science.gov (United States)

    Ahmed, Sohail; Yi, Jiabao

    2017-10-01

    Two-dimensional (2D) materials have attracted extensive interest due to their excellent electrical, thermal, mechanical, and optical properties. Graphene has been one of the most explored 2D materials. However, its zero band gap has limited its applications in electronic devices. Transition metal dichalcogenide (TMDC), another kind of 2D material, has a nonzero direct band gap (same charge carrier momentum in valence and conduction band) at monolayer state, promising for the efficient switching devices (e.g., field-effect transistors). This review mainly focuses on the recent advances in charge carrier mobility and the challenges to achieve high mobility in the electronic devices based on 2D-TMDC materials and also includes an introduction of 2D materials along with the synthesis techniques. Finally, this review describes the possible methodology and future prospective to enhance the charge carrier mobility for electronic devices.

  3. Phase reconstruction of digital holography with the peak of the two-dimensional Gabor wavelet transform.

    Science.gov (United States)

    Weng, Jiawen; Zhong, Jingang; Hu, Cuiying

    2009-06-20

    We describe a numerical reconstruction technique for digital holography by means of the two-dimensional Gabor wavelet transform (2D-GWT). Applying the 2D-GWT to digital holography, the object wave can be reconstructed by calculating the wavelet coefficients of the hologram at the peak of the 2D-GWT automatically. At the same time the effect of the zero-order diffraction image and the twin image are eliminated without spatial filtering. Comparing the numerical reconstruction of a holographic image by the analysis of the one-dimensional Gabor wavelet transform (1D-GWT) with the 2D-GWT, we show that the 2D-GWT method is superior to the 1D-GWT method, especially when the fringes of the hologram are not just along the y direction. The theory and the results of a simulation and experiments are shown.

  4. Two-Dimensional Graphene as a Matrix for MALDI Imaging Mass Spectrometry

    Science.gov (United States)

    Friesen, William L.; Schultz, Brian J.; Destino, Joel F.; Alivio, Theodore E. G.; Steet, Joseph R.; Banerjee, Sarbajit; Wood, Troy D.

    2015-11-01

    Here, a matrix using two-dimensional (2D) graphene is demonstrated for the first time in the context of MALDI IMS using a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Although graphene flakes have been used previously in MALDI, it is described here how a single 2D layer of graphene is applied directly on top of rat brain sections and soybean leaves. Several classes of molecules are desorbed and ionized off of the surface of the tissues examined using 2D graphene, with minimal background interference from the matrix. Moreover, no solvents are employed in application of 2D graphene, eliminating the potential for analyte diffusion in liquid droplets during matrix application. Because 2D graphene is an elemental form of carbon, an additional advantage is its high compatibility with the long duration needed for many IMS experiments.

  5. Size Effect on the Infrared Spectra of Condensed Media under Conditions of 1D, 2D, and 3D Dielectric Confinement

    KAUST Repository

    Shaganov, Igor I.

    2010-10-07

    The effect of dielectric confinement on the peak position of intramolecular and a lattice vibration in the infrared spectra of various condensed media is investigated. Liquid benzene, carbon disulfide, and chloroform, as well as amorphous SiO2 and microcrystalline MgO particles, were characterized in this study. The absorption spectra of organic liquids and aqueous solutions of a silica submicrometer powder were measured under a variety of dielectric confinement configurations using Fourier transform Infrared spectroscopy. A significant shift of the resonant absorption band of liquid mesoparticles has been observed under dielectric confinement, which is in good agreement with model predictions. A corresponding expression for the dielectric loss spectrum of an absorbing composite medium was obtained using a Maxwell-Garnett generalized equation for the cases of one, two, and three-dimensional dielectric confinement in both ordered and disordered thin layers (disks), rods (wires or needles), and spheres of an absorbing medium. The experimental data on peak positions obtained from the infrared spectra of the organic liquids investigated in this work, as well as from the infrared spectra of amorphous quartz spherical particles and rods, are in good agreement with the calculated data. It is shown using simulations of the absorption spectrum of MgO powder that the approach suggested can be applied under certain conditions to the modeling of the spectra of microcrystalline particles of nonspheroidal shape. © 2010 American Chemical Society.

  6. Janus spectra in two-dimensional flows

    CERN Document Server

    Liu, Chien-Chia; Chakraborty, Pinaki

    2016-01-01

    In theory, large-scale atmospheric flows, soap-film flows and other two-dimensional flows may host two distinct types of turbulent energy spectra---in one, $\\alpha$, the spectral exponent of velocity fluctuations, equals $3$ and the fluctuations are dissipated at the small scales, and in the other, $\\alpha=5/3$ and the fluctuations are dissipated at the large scales---but measurements downstream of obstacles have invariably revealed $\\alpha = 3$. Here we report experiments on soap-film flows where downstream of obstacles there exists a sizable interval in which $\\alpha$ has transitioned from $3$ to $5/3$ for the streamwise fluctuations but remains equal to $3$ for the transverse fluctuations, as if two mutually independent turbulent fields of disparate dynamics were concurrently active within the flow. This species of turbulent energy spectra, which we term the Janus spectra, has never been observed or predicted theoretically. Our results may open up new vistas in the study of turbulence and geophysical flows...

  7. Two-dimensional hexagonal semiconductors beyond graphene

    Science.gov (United States)

    Nguyen, Bich Ha; Hieu Nguyen, Van

    2016-12-01

    The rapid and successful development of the research on graphene and graphene-based nanostructures has been substantially enlarged to include many other two-dimensional hexagonal semiconductors (THS): phosphorene, silicene, germanene, hexagonal boron nitride (h-BN) and transition metal dichalcogenides (TMDCs) such as MoS2, MoSe2, WS2, WSe2 as well as the van der Waals heterostructures of various THSs (including graphene). The present article is a review of recent works on THSs beyond graphene and van der Waals heterostructures composed of different pairs of all THSs. One among the priorities of new THSs compared to graphene is the presence of a non-vanishing energy bandgap which opened up the ability to fabricate a large number of electronic, optoelectronic and photonic devices on the basis of these new materials and their van der Waals heterostructures. Moreover, a significant progress in the research on TMDCs was the discovery of valley degree of freedom. The results of research on valley degree of freedom and the development of a new technology based on valley degree of freedom-valleytronics are also presented. Thus the scientific contents of the basic research and practical applications os THSs are very rich and extremely promising.

  8. Two-Dimensional Phononic Crystals: Disorder Matters.

    Science.gov (United States)

    Wagner, Markus R; Graczykowski, Bartlomiej; Reparaz, Juan Sebastian; El Sachat, Alexandros; Sledzinska, Marianna; Alzina, Francesc; Sotomayor Torres, Clivia M

    2016-09-14

    The design and fabrication of phononic crystals (PnCs) hold the key to control the propagation of heat and sound at the nanoscale. However, there is a lack of experimental studies addressing the impact of order/disorder on the phononic properties of PnCs. Here, we present a comparative investigation of the influence of disorder on the hypersonic and thermal properties of two-dimensional PnCs. PnCs of ordered and disordered lattices are fabricated of circular holes with equal filling fractions in free-standing Si membranes. Ultrafast pump and probe spectroscopy (asynchronous optical sampling) and Raman thermometry based on a novel two-laser approach are used to study the phononic properties in the gigahertz (GHz) and terahertz (THz) regime, respectively. Finite element method simulations of the phonon dispersion relation and three-dimensional displacement fields furthermore enable the unique identification of the different hypersonic vibrations. The increase of surface roughness and the introduction of short-range disorder are shown to modify the phonon dispersion and phonon coherence in the hypersonic (GHz) range without affecting the room-temperature thermal conductivity. On the basis of these findings, we suggest a criteria for predicting phonon coherence as a function of roughness and disorder.

  9. Two-dimensional topological photonic systems

    Science.gov (United States)

    Sun, Xiao-Chen; He, Cheng; Liu, Xiao-Ping; Lu, Ming-Hui; Zhu, Shi-Ning; Chen, Yan-Feng

    2017-09-01

    The topological phase of matter, originally proposed and first demonstrated in fermionic electronic systems, has drawn considerable research attention in the past decades due to its robust transport of edge states and its potential with respect to future quantum information, communication, and computation. Recently, searching for such a unique material phase in bosonic systems has become a hot research topic worldwide. So far, many bosonic topological models and methods for realizing them have been discovered in photonic systems, acoustic systems, mechanical systems, etc. These discoveries have certainly yielded vast opportunities in designing material phases and related properties in the topological domain. In this review, we first focus on some of the representative photonic topological models and employ the underlying Dirac model to analyze the edge states and geometric phase. On the basis of these models, three common types of two-dimensional topological photonic systems are discussed: 1) photonic quantum Hall effect with broken time-reversal symmetry; 2) photonic topological insulator and the associated pseudo-time-reversal symmetry-protected mechanism; 3) time/space periodically modulated photonic Floquet topological insulator. Finally, we provide a summary and extension of this emerging field, including a brief introduction to the Weyl point in three-dimensional systems.

  10. Asymptotics for Two-dimensional Atoms

    DEFF Research Database (Denmark)

    Nam, Phan Thanh; Portmann, Fabian; Solovej, Jan Philip

    2012-01-01

    We prove that the ground state energy of an atom confined to two dimensions with an infinitely heavy nucleus of charge $Z>0$ and $N$ quantum electrons of charge -1 is $E(N,Z)=-{1/2}Z^2\\ln Z+(E^{\\TF}(\\lambda)+{1/2}c^{\\rm H})Z^2+o(Z^2)$ when $Z\\to \\infty$ and $N/Z\\to \\lambda$, where $E^{\\TF}(\\lambd......We prove that the ground state energy of an atom confined to two dimensions with an infinitely heavy nucleus of charge $Z>0$ and $N$ quantum electrons of charge -1 is $E(N,Z)=-{1/2}Z^2\\ln Z+(E^{\\TF}(\\lambda)+{1/2}c^{\\rm H})Z^2+o(Z^2)$ when $Z\\to \\infty$ and $N/Z\\to \\lambda$, where $E......^{\\TF}(\\lambda)$ is given by a Thomas-Fermi type variational problem and $c^{\\rm H}\\approx -2.2339$ is an explicit constant. We also show that the radius of a two-dimensional neutral atom is unbounded when $Z\\to \\infty$, which is contrary to the expected behavior of three-dimensional atoms....

  11. Surface and Interface Engineering of Organometallic and Two Dimensional Semiconductor

    Science.gov (United States)

    Park, Jun Hong

    For over half a century, inorganic Si and III-V materials have led the modern semiconductor industry, expanding to logic transistor and optoelectronic applications. However, these inorganic materials have faced two different fundamental limitations, flexibility for wearable applications and scaling limitation as logic transistors. As a result, the organic and two dimensional have been studied intentionally for various fields. In the present dissertation, three different studies will be presented with followed order; (1) the chemical response of organic semiconductor in NO2 exposure. (2) The surface and stability of WSe2 in ambient air. (3) Deposition of dielectric on two dimensional materials using organometallic seeding layer. The organic molecules rely on the van der Waals interaction during growth of thin films, contrast to covalent bond inorganic semiconductors. Therefore, the morphology and electronic property at surface of organic semiconductor in micro scale is more sensitive to change in gaseous conditions. In addition, metal phthalocyanine, which is one of organic semiconductor materials, change their electronic property as reaction with gaseous analytes, suggesting as potential chemical sensing platforms. In the present part, the growth behavior of metal phthalocyanine and surface response to gaseous condition will be elucidated using scanning tunneling microscopy (STM). In second part, the surface of layered transition metal dichalcogenides and their chemical response to exposure ambient air will be investigated, using STM. Layered transition metal dichalcogenides (TMDs) have attracted widespread attention in the scientific community for electronic device applications because improved electrostatic gate control and suppression of short channel leakage resulted from their atomic thin body. To fabricate the transistor based on TMDs, TMDs should be exposed to ambient conditions, while the effect of air exposure has not been understood fully. In this part

  12. Two-Dimensional Nanomaterials for Biomedical Applications: Emerging Trends and Future Prospects.

    Science.gov (United States)

    Chimene, David; Alge, Daniel L; Gaharwar, Akhilesh K

    2015-12-02

    Two-dimensional (2D) nanomaterials are ultrathin nanomaterials with a high degree of anisotropy and chemical functionality. Research on 2D nanomaterials is still in its infancy, with the majority of research focusing on elucidating unique material characteristics and few reports focusing on biomedical applications of 2D nanomaterials. Nevertheless, recent rapid advances in 2D nanomaterials have raised important and exciting questions about their interactions with biological moieties. 2D nanoparticles such as carbon-based 2D materials, silicate clays, transition metal dichalcogenides (TMDs), and transition metal oxides (TMOs) provide enhanced physical, chemical, and biological functionality owing to their uniform shapes, high surface-to-volume ratios, and surface charge. Here, we focus on state-of-the-art biomedical applications of 2D nanomaterials as well as recent developments that are shaping this emerging field. Specifically, we describe the unique characteristics that make 2D nanoparticles so valuable, as well as the biocompatibility framework that has been investigated so far. Finally, to both capture the growing trend of 2D nanomaterials for biomedical applications and to identify promising new research directions, we provide a critical evaluation of potential applications of recently developed 2D nanomaterials.

  13. Brewster Angle Microscope Investigations of Two Dimensional Phase Transitions

    Science.gov (United States)

    Schuman, Adam William

    The liquid-liquid interface is investigated by microscopic and thermodynamic means to image and measure interfacial properties when the system undergoes a two-dimensional (2D) phase transition of a Gibbs monolayer by varying the sample temperature. An in-house Brewster angle microscope (BAM) is constructed to visualize the interface during this transition while a quasi-elastic light scattering technique is used to determine the interfacial tension. These results complement x-ray investigations of the same systems. Evidence of interfacial micro-separated structure, microphases, comes from observations across a hexane-water interface with the inclusion of a long-chain fluorinated alcohol surfactant into the bulk hexane. Microphases take the form of spatially modulated structure to the density of the surfactant as it spans laterally across the interface. The surfactant monolayer exhibits microphase morphology over a range of a couple degrees as the temperature of the system is scanned through the 2D gas-solid phase transition. Microphase structure was observed for heating and cooling the hexane-water system and structural comparisons are given when the temperature step and quench depth of the cooling process is varied. A complete sequence of morphological structure was observed from 2D gas to cluster to labyrinthine stripe to a 2D solid mosaic pattern. Two characteristic length scales emerge giving rise to speculation of an elastic contribution to the standard repulsive and attractive competitive forces stabilizing the microphase. The benefit of BAM to laterally image very thin films across the surface of an interface on the micrometer length scale nicely complements x-ray reflectivity methods that average structural data transverse to the liquid interface on a molecular scale. To properly analyze x-ray reflectivity data, the interface is required to be laterally homogeneous. BAM can sufficiently characterize the interface for this purpose as is done for a Langmuir

  14. Two-dimensional materials and their prospects in transistor electronics.

    Science.gov (United States)

    Schwierz, F; Pezoldt, J; Granzner, R

    2015-05-14

    During the past decade, two-dimensional materials have attracted incredible interest from the electronic device community. The first two-dimensional material studied in detail was graphene and, since 2007, it has intensively been explored as a material for electronic devices, in particular, transistors. While graphene transistors are still on the agenda, researchers have extended their work to two-dimensional materials beyond graphene and the number of two-dimensional materials under examination has literally exploded recently. Meanwhile several hundreds of different two-dimensional materials are known, a substantial part of them is considered useful for transistors, and experimental transistors with channels of different two-dimensional materials have been demonstrated. In spite of the rapid progress in the field, the prospects of two-dimensional transistors still remain vague and optimistic opinions face rather reserved assessments. The intention of the present paper is to shed more light on the merits and drawbacks of two-dimensional materials for transistor electronics and to add a few more facets to the ongoing discussion on the prospects of two-dimensional transistors. To this end, we compose a wish list of properties for a good transistor channel material and examine to what extent the two-dimensional materials fulfill the criteria of the list. The state-of-the-art two-dimensional transistors are reviewed and a balanced view of both the pros and cons of these devices is provided.

  15. Structural Transformations in Two-Dimensional Transition-Metal Dichalcogenide MoS2 under an Electron Beam

    DEFF Research Database (Denmark)

    Kretschmer, Silvan; Komsa, Hannu-Pekka; Bøggild, Peter

    2017-01-01

    The polymorphism of two-dimensional (w2D) transition-metal dichalcogenides (TMDs) and different electronic properties of the polymorphs make TMDs particularly promising materials in the context of applications in electronics. Recently, local transformations from the semiconducting trigonal prisma...... development and optimization of electron-beam-mediated engineering of the atomic structure and electronic properties of 2D TMDs with subnanometer resolution.......The polymorphism of two-dimensional (w2D) transition-metal dichalcogenides (TMDs) and different electronic properties of the polymorphs make TMDs particularly promising materials in the context of applications in electronics. Recently, local transformations from the semiconducting trigonal...... prismatic H phase to the metallic octahedral T phase in 2D MoS2 have been induced by electron irradiation [Nat. Nanotech. 2014, 9, 391], but the mechanism of the transformations remains elusive. Using density functional theory calculations, we study the energetics of the stable and metastable phases of 2D...

  16. Note: Unshielded bilateral magnetoencephalography system using two-dimensional gradiometers

    Science.gov (United States)

    Seki, Yusuke; Kandori, Akihiko; Ogata, Kuniomi; Miyashita, Tsuyoshi; Kumagai, Yukio; Ohnuma, Mitsuru; Konaka, Kuni; Naritomi, Hiroaki

    2010-09-01

    Magnetoencephalography (MEG) noninvasively measures neuronal activity with high temporal resolution. The aim of this study was to develop a new type of MEG system that can measure bilateral MEG waveforms without a magnetically shielded room, which is an obstacle to reducing both the cost and size of an MEG system. An unshielded bilateral MEG system was developed using four two-dimensional (2D) gradiometers and two symmetric cryostats. The 2D gradiometer, which is based on a low-Tc superconducting quantum interference device and wire-wound pickup coil detects a magnetic-field gradient in two orthogonal directions, or ∂/∂x(∂2Bz/∂z2), and reduces environmental magnetic-field noise by more than 50 dB. The cryostats can be symmetrically positioned in three directions: vertical, horizontal, and rotational. This makes it possible to detect bilateral neuronal activity in the cerebral cortex simultaneously. Bilateral auditory-evoked fields (AEF) of 18 elderly subjects were measured in an unshielded hospital environment using the MEG system. As a result, both the ipsilateral and the contralateral AEF component N100m, which is the magnetic counterpart of electric N100 in electroencephalography and appears about 100 ms after the onset of an auditory stimulus, were successfully detected for all the subjects. Moreover, the ipsilateral P50m and the contralateral P50m were also detected for 12 (67%) and 16 (89%) subjects, respectively. Experimental results demonstrate that the unshielded bilateral MEG system can detect MEG waveforms, which are associated with brain dysfunction such as epilepsy, Alzheimer's disease, and Down syndrome.

  17. Two-dimensional in situ metrology of X-ray mirrors using the speckle scanning technique

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hongchang, E-mail: hongchang.wang@diamond.ac.uk; Kashyap, Yogesh; Laundy, David; Sawhney, Kawal [Diamond Light Source Ltd, Harwell Science and Innovation Campus, Didcot OX11 0DE (United Kingdom)

    2015-06-06

    The two-dimensional slope error of an X-ray mirror has been retrieved by employing the speckle scanning technique, which will be valuable at synchrotron radiation facilities and in astronomical telescopes. In situ metrology overcomes many of the limitations of existing metrology techniques and is capable of exceeding the performance of present-day optics. A novel technique for precisely characterizing an X-ray bimorph mirror and deducing its two-dimensional (2D) slope error map is presented. This technique has also been used to perform fast optimization of a bimorph mirror using the derived 2D piezo response functions. The measured focused beam size was significantly reduced after the optimization, and the slope error map was then verified by using geometrical optics to simulate the focused beam profile. This proposed technique is expected to be valuable for in situ metrology of X-ray mirrors at synchrotron radiation facilities and in astronomical telescopes.

  18. Two-Dimensional Heat Transfer in a Heterogeneous Fracture Network

    Science.gov (United States)

    Gisladottir, V. R.; Roubinet, D.; Tartakovsky, D. M.

    2015-12-01

    Geothermal energy harvesting requires extraction and injection of geothermal fluid. Doing so in an optimal way requires a quantitative understanding of site-specific heat transfer between geothermal fluid and the ambient rock. We develop a heat transfer particle-tracking approach to model that interaction. Fracture-network models of heat transfer in fractured rock explicitly account for the presence of individual fractures, ambient rock matrix, and fracture-matrix interfaces. Computational domains of such models span the meter scale, whereas fracture apertures are on the millimeter scale. The computations needed to model these multi-scale phenomenon can be prohibitively expensive, even for methods using nonuniform meshes. Our approach appreciably decreases the computational costs. Current particle-tracking methods usually assume both infinite matrix and one-dimensional (1D) heat transfer in the matrix blocks. They rely on 1D analytical solutions for heat transfer in a single fracture, which can lead to large predictive errors. Our two-dimensional (2D) heat transfer simulation algorithm is mesh-free and takes into account both longitudinal and transversal heat conduction in the matrix. It uses a probabilistic model to transfer particle to the appropriate neighboring fracture unless it returns to the fracture of origin or remains in the matrix. We use this approach to look at the impact of a fracture-network topology (e.g. the importance of smaller scale fractures), as well as the matrix block distribution on the heat transport in heterogeneous fractured rocks.

  19. Two-dimensional Nutation Echo Nuclear Quadrupole Resonance Spectroscopy

    Science.gov (United States)

    Harbison, Gerard S.; Slokenbergs, Andris

    1990-04-01

    We discuss two new two-dimensional nuclear quadrupole resonance experiments, both based on the principle of nutation spectroscopy, which can be used to determine the asymmetry parameter, and thus the full quadrupolar tensor, of spin-3/2 nuclei at zero applied magnetic field. The first experiment is a simple nutation pulse sequence in which the first time period (t1) is the duration of the radiofrequency exciting pulse; and the second (t2) is the normal free-precession of a quadrupolar nucleus at zero-field. After double Fourier-transformation, the result is a 2 D spectrum in which the first frequency dimension is the nutation spectrum for the quadrupolar nucleus at zero-field. For polycrystalline samples this sequence generates powder lineshapes; the position of the singularities, in these lineshapes can be used to determine the asymmetry parameters η in a very straightforward manner, η has previously only been obtainable using Zeeman perturbed NQR methods. The second sequence is the same nutation experiment with a spin-echo pulse added. The virtue of this refocussing pulse is that it allows acquisition of nutation spectra from samples with arbitrary inhomogeneous linewidth; thus, asymmetry parameters can be determined even where the quadrupolar resonance is wider than the bandwidth of the spectrometer. Experimental examples of 35Cl, 81Br and 63Cu nutation and nutation-echo spectra are presented.

  20. Two dimensional discriminant neighborhood preserving embedding in face recognition

    Science.gov (United States)

    Pang, Meng; Jiang, Jifeng; Lin, Chuang; Wang, Binghui

    2015-03-01

    One of the key issues of face recognition is to extract the features of face images. In this paper, we propose a novel method, named two-dimensional discriminant neighborhood preserving embedding (2DDNPE), for image feature extraction and face recognition. 2DDNPE benefits from four techniques, i.e., neighborhood preserving embedding (NPE), locality preserving projection (LPP), image based projection and Fisher criterion. Firstly, NPE and LPP are two popular manifold learning techniques which can optimally preserve the local geometry structures of the original samples from different angles. Secondly, image based projection enables us to directly extract the optimal projection vectors from twodimensional image matrices rather than vectors, which avoids the small sample size problem as well as reserves useful structural information embedded in the original images. Finally, the Fisher criterion applied in 2DDNPE can boost face recognition rates by minimizing the within-class distance, while maximizing the between-class distance. To evaluate the performance of 2DDNPE, several experiments are conducted on the ORL and Yale face datasets. The results corroborate that 2DDNPE outperforms the existing 1D feature extraction methods, such as NPE, LPP, LDA and PCA across all experiments with respect to recognition rate and training time. 2DDNPE also delivers consistently promising results compared with other competing 2D methods such as 2DNPP, 2DLPP, 2DLDA and 2DPCA.

  1. The random discrete action for two-dimensional spacetime

    Energy Technology Data Exchange (ETDEWEB)

    Benincasa, Dionigi M T; Dowker, Fay; Schmitzer, Bernhard, E-mail: db1808@ic.ac.uk [Theoretical Physics Group, Blackett Laboratory, Imperial College, Prince Consort Road, London SW7 2AZ (United Kingdom)

    2011-05-21

    A one-parameter family of random variables, called the Discrete Action, is defined for a two-dimensional Lorentzian spacetime of finite volume. The single parameter is a discreteness scale. The expectation value of this discrete action is calculated for various regions of 2D Minkowski spacetime, M{sup 2}. When a causally convex region of M{sup 2} is divided into subregions using null lines the mean of the discrete action is equal to the alternating sum of the numbers of vertices, edges and faces of the null tiling, up to corrections that tend to 0 as the discreteness scale is taken to 0. This result is used to predict that the mean of the discrete action of the flat Lorentzian cylinder is zero up to corrections, which is verified. The 'topological' character of the discrete action breaks down for causally convex regions of the flat trousers spacetime that contain the singularity and for non-causally convex rectangles.

  2. Two Dimensional Symmetric Correlation Functions of the S Operator and Two Dimensional Fourier Transforms: Considering the Line Coupling for P and R Lines of Linear Molecules

    Science.gov (United States)

    Ma, Q.; Boulet, C.; Tipping, R. H.

    2014-01-01

    The refinement of the Robert-Bonamy (RB) formalism by considering the line coupling for isotropic Raman Q lines of linear molecules developed in our previous study [Q. Ma, C. Boulet, and R. H. Tipping, J. Chem. Phys. 139, 034305 (2013)] has been extended to infrared P and R lines. In these calculations, the main task is to derive diagonal and off-diagonal matrix elements of the Liouville operator iS1 - S2 introduced in the formalism. When one considers the line coupling for isotropic Raman Q lines where their initial and final rotational quantum numbers are identical, the derivations of off-diagonal elements do not require extra correlation functions of the ^S operator and their Fourier transforms except for those used in deriving diagonal elements. In contrast, the derivations for infrared P and R lines become more difficult because they require a lot of new correlation functions and their Fourier transforms. By introducing two dimensional correlation functions labeled by two tensor ranks and making variable changes to become even functions, the derivations only require the latters' two dimensional Fourier transforms evaluated at two modulation frequencies characterizing the averaged energy gap and the frequency detuning between the two coupled transitions. With the coordinate representation, it is easy to accurately derive these two dimensional correlation functions. Meanwhile, by using the sampling theory one is able to effectively evaluate their two dimensional Fourier transforms. Thus, the obstacles in considering the line coupling for P and R lines have been overcome. Numerical calculations have been carried out for the half-widths of both the isotropic Raman Q lines and the infrared P and R lines of C2H2 broadened by N2. In comparison with values derived from the RB formalism, new calculated values are significantly reduced and become closer to measurements.

  3. Mapping and identification of interferon gamma-regulated HeLa cell proteins separated by immobilized pH gradient two-dimensional gel electrophoresis

    DEFF Research Database (Denmark)

    Shaw, AC; Rossel Larsen, M; Roepstorff, P

    1999-01-01

    magnitude of IFN-gamma responsive genes has been reported previously. Our goal is to identify and map IFN-gamma-regulated HeLa cell proteins to the two-dimensional polyacrylamide gel electrophoresis with the immobilized pH gradient (IPG) two-dimensional polyacrylamide gel electrophoresis (2-D PAGE) system...

  4. A Method to Formulate the Unit Cell for Density Functional Theory (DFT) Calculations of the Electronic Band Structure of Heterostructures of Two-dimensional Nanosheets

    Science.gov (United States)

    2015-04-01

    distribution is unlimited. i CONTENTS Page Introduction 1 Two-dimensional Material Geometry and Analogs with Close-packed Systems 1 Matching...distribution is unlimited. 1 INTRODUCTION Two-dimensional (2D) material heterostructures offer novel and compelling electronic and optical...methods have undoubtedly been created for matching lattice constants of dissimilar nanomaterials , very few are actually covered explicitly in literature

  5. Personalized 2D color maps

    KAUST Repository

    Waldin, Nicholas

    2016-06-24

    2D color maps are often used to visually encode complex data characteristics such as heat or height. The comprehension of color maps in visualization is affected by the display (e.g., a monitor) and the perceptual abilities of the viewer. In this paper we present a novel method to measure a user\\'s ability to distinguish colors of a two-dimensional color map on a given monitor. We show how to adapt the color map to the user and display to optimally compensate for the measured deficiencies. Furthermore, we improve user acceptance of the calibration procedure by transforming the calibration into a game. The user has to sort colors along a line in a 3D color space in a competitive fashion. The errors the user makes in sorting these lines are used to adapt the color map to his perceptual capabilities.

  6. Two-dimensional optical tomography of hemodynamic changes in a preterm infant brain

    Science.gov (United States)

    Gao, Feng; Xue, Yuan; Zhao, Huijuan; Kusaka, Takashi; Ueno, Masanori; Yamada, Yukio

    2007-08-01

    Our preliminary results on two-dimensional (2D) optical tomographic imaging of hemodynamic changes in a preterm infant brain are reported. We use the established 16-channel time-correlated single photon counting system for the detection and generalized pulse spectrum technique based algorithm for the image reconstruction. The experiments demonstrate that diffuse optical tomography may be a potent means for investigating brain functions and neural development of infant brains in the perinatal period.

  7. Self-Organized Two-Dimensional Vidro-Nanodot Array on Laser-Irradiated Si Surface

    Science.gov (United States)

    Yoshida, Yutaka; Sakaguchi, Norihito; Watanabe, Seiichi; Kato, Takahiko

    2011-05-01

    We report a periodic two-dimensional (2D) array of uniquely shaped dotlike nanoprotrusions (NPs), which simultaneously self-organize on a Si surface under pulsed laser irradiation. The shape of the dotlike NPs can be controlled by adjusting the number of laser pulses. The flask-shaped dotlike NP array is named a vidro-nanodot (VND) array. We present a detailed analysis of the internal structure of VND using high-resolution electron microscopy.

  8. Optical Two-Dimensional Spectroscopy of Disordered Semiconductor Quantum Wells and Quantum Dots

    Energy Technology Data Exchange (ETDEWEB)

    Cundiff, Steven T. [Univ. of Colorado, Boulder, CO (United States)

    2016-05-03

    This final report describes the activities undertaken under grant "Optical Two-Dimensional Spectroscopy of Disordered Semiconductor Quantum Wells and Quantum Dots". The goal of this program was to implement optical 2-dimensional Fourier transform spectroscopy and apply it to electronic excitations, including excitons, in semiconductors. Specifically of interest are quantum wells that exhibit disorder due to well width fluctuations and quantum dots. In both cases, 2-D spectroscopy will provide information regarding coupling among excitonic localization sites.

  9. The investigation on two-dimensional pilot-symbol-aided channel estimation method for OFDM system

    Institute of Scientific and Technical Information of China (English)

    Sun Juying; Zhang Yanhua

    2008-01-01

    Channel estimation for orthogonal frequency division multiplexing (OFDM) system has attracted widespread attention. In this paper, a novel efficient two-dimensional (2-D) channel estimation algorithm based on fast Fourier transform (FFT) is proposed for a time-variant, frequency-selective wideband wireless channel. Both theoretical analysis and simulation results are addressed in the paper. The simulation results prove that the proposed algorithm has simpler implementation, better performance and wider application than other traditional decision-directed algorithms.

  10. Coarse error analysis and correction of a two-dimensional triangulation range finder

    Institute of Scientific and Technical Information of China (English)

    Huaqiao Gui; Liang Lü; Wei Huang; Jun Xu; Deyong He; Huanqin Wang; Jianping Xie; Tianpeng Zhao; Hai Ming

    2006-01-01

    @@ A real-time two-dimensional (2D) triangulation range finder is presented, which is composed of two linear complementary metal oxidation semiconductor (CMOS) chips, two camera lenses, and four light emitting diodes (LEDs). The high order distortion in image aberrations is the main factor responsible for the coarse errors. The theoretical prediction is in good agreement with experiments and the correction equation is used to obtain more reliable results with the unique distortion coefficient in the whole working region.

  11. Two-dimensional optical tomography of hemodynamic changes in a preterm infant brain

    Institute of Scientific and Technical Information of China (English)

    Feng Gao; Yuan Xue; Huijuan Zhao; Takashi Kusaka; Masanori Ueno; Yukio Yamada

    2007-01-01

    Our preliminary results on two-dimensional (2D) optical tomographic imaging of hemodynamic changes in a preterm infant brain are reported. We use the established 16-channel time-correlated single photon counting system for the detection and generalized pulse spectrum technique based algorithm for the image reconstruction. The experiments demonstrate that diffuse optical tomography may be a potent means for investigating brain functions and neural development of infant brains in the perinatal period.

  12. Experimental Demonstration of the Microscopic Origin of Circular Dichroism in Two dimensional Metamaterials

    Science.gov (United States)

    2016-06-22

    dichroism in two-dimensional metamaterials A.B. Khanikaev1, N. Arju2, Z. Fan2, D. Purtseladze2, F. Lu3, J. Lee3, P. Sarriugarte4, M. Schnell4, R. Hillenbrand4...M.A. Belkin3 & G. Shvets2 Optical activity and circular dichroism are fascinating physical phenomena originating from the interaction of light with...spatial symmetry of their building blocks is broken on a nanoscale. Although originally discovered in 3D structures, circular dichroism can also emerge

  13. Solvent Exfoliation of Electronic-Grade, Two-Dimensional Black Phosphorus

    OpenAIRE

    Kang, Joohoon; Wood, Joshua D.; Wells, Spencer A.; Lee, Jae-Hyeok; Liu, Xiaolong; Chen, Kan-Sheng; Hersam, Mark C.

    2015-01-01

    Solution dispersions of two-dimensional (2D) black phosphorus (BP), often referred to as phosphorene, are achieved by solvent exfoliation. These pristine, electronic-grade BP dispersions are produced with anhydrous, organic solvents in a sealed tip ultrasonication system, which circumvents BP degradation that would otherwise occur via solvated oxygen or water. Among conventional solvents, n-methyl-pyrrolidone (NMP) is found to provide stable, highly concentrated (~0.4 mg/mL) BP dispersions. A...

  14. A Comparative Study of Stability Testing Approaches of Two-Dimensional Recursive Digital Filters

    OpenAIRE

    K. R. Santhi; M.Ponnavaikko; N. Gangatharan

    2008-01-01

    There are many problems in science and engineering whose solution is applied in the design of Multi-Dimensional (MD) digital filters. Digital filtering finds an important position in the field of digital signal and image processing. Recently there had been a great deal of interest in the design and stability analysis of Two-Dimensional (2-D) recursive digital filters. The design techniques for stable One Dimensional (1-D) digital filters are relatively well developed; but their extension to 2...

  15. Full molecular dynamics simulations of liquid water and carbon tetrachloride for two-dimensional Raman spectroscopy in the frequency domain

    CERN Document Server

    Jo, Ju-Yeon; Tanimura, Yoshitaka

    2016-01-01

    Frequency-domain two-dimensional Raman signals, which are equivalent to coherent two-dimensional Raman scattering (COTRAS) signals, for liquid water and carbon tetrachloride were calculated using an equilibrium-nonequilibrium hybrid MD simulation algorithm. We elucidate mechanisms governing the 2D signal pro?les involving anharmonic mode-mode coupling and the nonlinearities of the polarizability for the intermolecular and intramolecular vibrational modes. The predicted signal pro?les and intensities can be utilized to analyze recently developed single-beam 2D spectra, whose signals are generated from a coherently controlled pulse, allowing the single-beam measurement to be carried out more efficiently.

  16. Evaluation of Aqueductal Patency in Patients with Hydrocephalus: Three-Dimensional High-Sampling-Efficiency Technique (SPACE) versus Two-Dimensional Turbo Spin Echo at 3 Tesla

    National Research Council Canada - National Science Library

    Ucar, Murat; Guryildirim, Melike; Tokgoz, Nil; Kilic, Koray; Borcek, Alp; Oner, Yusuf; Akkan, Koray; Tali, Turgut

    2014-01-01

    ...) high-sampling-efficiency technique (sampling perfection with application optimized contrast using different flip angle evolutions [SPACE]) and T2-weighted (T2W) two-dimensional (2D) turbo spin echo (TSE...

  17. Closed-form evaluation of two-dimensional static lattice sums

    Science.gov (United States)

    Yakubovich, S.; Drygas, P.; Mityushev, V.

    2016-11-01

    Closed-form formulae for the conditionally convergent two-dimensional (2D) static lattice sums S2 (for conductivity) and T2 (for elasticity) are deduced in terms of the complete elliptic integrals of the first and second kind. The obtained formulae yield asymptotic analytical formulae for the effective tensors of 2D composites with circular inclusions up to the third order in concentration. Exact relations between S2 and T2 for different lattices are established. In particular, the value S2=π for the square and hexagonal arrays is discussed and T2=π/2 for the hexagonal is deduced.

  18. Towards complete integrability of two dimensional Poincar\\'e gauge gravity

    CERN Document Server

    Mielke, E W; Obukhov, Yu N; Tresguerres, R; Hehl, F W

    1993-01-01

    It is shown that gravity on the line can be described by the two dimensional (2D) Hilbert-Einstein Lagrangian supplemented by a kinetic term for the coframe and a translational {\\it boundary} term. The resulting model is equivalent to a Yang-Mills theory of local {\\it translations} and frozen Lorentz gauge degrees. We will show that this restricted Poincar\\'e gauge model in 2 dimensions is completely integrable. {\\it Exact} wave, charged black hole, and `dilaton' solutions are then readily found. In vacuum, the integrability of the {\\it general} 2D Poincar\\'e gauge theory is formally proved along the same line of reasoning.

  19. Spectroscopy of charge transfer complexes of four amino acids as organic two-dimensional conductors

    Energy Technology Data Exchange (ETDEWEB)

    Padhiyar, Ashvin; Patel, A J; Oza, A T [Department of Physics, Sardar Patel University, Vallabh Vidyanagar-388 120, Gujarat (India)

    2007-12-05

    It is found in this study that four amino acids, namely asparagine, arginine, histidine and glutamine form two-dimensional conducting systems which are charge transfer complexes (CTCs) with organic acceptors like TCNQ, TCNE, chloranil, DDQ, TNF and iodine. It is verified using optical absorption edges that these are 2d conductors like transition metal dichalcogenides obeying absorption functions different from 1d and 3d conductors. This 2d nature is related to the network of intermolecular H-bonding in these complexes, which leads to a global H-bonded network resulting in the absence of local deformation due to the relaxation of strain.

  20. Spectroscopy of charge transfer complexes of four amino acids as organic two-dimensional conductors

    Science.gov (United States)

    Padhiyar, Ashvin; Patel, A. J.; Oza, A. T.

    2007-12-01

    It is found in this study that four amino acids, namely asparagine, arginine, histidine and glutamine form two-dimensional conducting systems which are charge transfer complexes (CTCs) with organic acceptors like TCNQ, TCNE, chloranil, DDQ, TNF and iodine. It is verified using optical absorption edges that these are 2d conductors like transition metal dichalcogenides obeying absorption functions different from 1d and 3d conductors. This 2d nature is related to the network of intermolecular H-bonding in these complexes, which leads to a global H-bonded network resulting in the absence of local deformation due to the relaxation of strain.

  1. Two-dimensional gold nanostructures with high activity for selective oxidation of carbon–hydrogen bonds

    KAUST Repository

    Wang, Liang

    2015-04-22

    Efficient synthesis of stable two-dimensional (2D) noble metal catalysts is a challenging topic. Here we report the facile synthesis of 2D gold nanosheets via a wet chemistry method, by using layered double hydroxide as the template. Detailed characterization with electron microscopy and X-ray photoelectron spectroscopy demonstrates that the nanosheets are negatively charged and [001] oriented with thicknesses varying from single to a few atomic layers. X-ray absorption spectroscopy reveals unusually low gold–gold coordination numbers. These gold nanosheets exhibit high catalytic activity and stability in the solvent-free selective oxidation of carbon–hydrogen bonds with molecular oxygen.

  2. Exact two-body solutions and quantum defect theory of two-dimensional dipolar quantum gas

    Science.gov (United States)

    Jie, Jianwen; Qi, Ran

    2016-10-01

    In this paper, we provide the two-body exact solutions of the two-dimensional (2D) Schrödinger equation with isotropic +/- 1/{r}3 interactions. An analytic quantum defect theory is constructed based on these solutions and it is applied to investigate the scattering properties as well as two-body bound states of an ultracold polar molecules confined in a quasi-2D geometry. Interestingly, we find that for the attractive case, the scattering resonance happens simultaneously in all partial waves, which has not been observed in other systems. The effect of this feature on the scattering phase shift across such resonances is also illustrated.

  3. A compact chaotic laser device with a two-dimensional external cavity structure

    Energy Technology Data Exchange (ETDEWEB)

    Sunada, Satoshi, E-mail: sunada@se.kanazawa-u.ac.jp; Adachi, Masaaki [Faculty of Mechanical Engineering, Institute of Science and Engineering, Kanazawa University, Kakuma-machi, Kanazawa, Ishikawa 920-1192 (Japan); Fukushima, Takehiro [Department of Information and Communication Engineering, Okayama Prefectural University, 111 Kuboki, Soja, Okayama 719-1197 (Japan); Shinohara, Susumu; Arai, Kenichi [NTT Communication Science Laboratories, NTT Corporation, 2-4 Hikaridai, Seika-cho, Soraku-gun, Kyoto 619-0237 (Japan); Harayama, Takahisa [NTT Communication Science Laboratories, NTT Corporation, 2-4 Hikaridai, Seika-cho, Soraku-gun, Kyoto 619-0237 (Japan); Department of Mechanical Engineering, Toyo University, 2100 Kujirai, Kawagoe, Saitama 350-8585 (Japan)

    2014-06-16

    We propose a compact chaotic laser device, which consists of a semiconductor laser and a two-dimensional (2D) external cavity for delayed optical feedback. The overall size of the device is within 230 μm × 1 mm. A long time delay sufficient for chaos generation can be achieved with the small area by the multiple reflections at the 2D cavity boundary, and the feedback strength is controlled by the injection current to the external cavity. We experimentally demonstrate that a variety of output properties, including chaotic output, can be selectively generated by controlling the injection current to the external cavity.

  4. Structure and phase transition of a two-dimensional dusty plasma

    Institute of Scientific and Technical Information of China (English)

    刘斌; 刘艳红; 陈雁萍; 杨思泽; 王龙

    2003-01-01

    The structure and phase transition of a two-dimensional (2D) dusty plasma have been investigated in detail by molecular dynamics simulation. Pair correlation function, static structure factor, mean square displacement, and bond angle correlation function have been calculated to characterize the structural properties. The variation of internal energy, shear modulus, particle trajectories and structural properties with temperature has been monitored to study the phase transition of the 2D dusty plasma system. The simulation results are in favour of a two-step continuous transition for this kind of plasma.

  5. Mathematical description of the two-dimensional Gabor transform. Application to image encryption

    Science.gov (United States)

    Perez, Ronal; Vilardy, Juan M.; Torres, Cesar O.

    2017-01-01

    Information security with optical processing, such as the double random phase encoding and the Gabor transform (GT) has been investigated by various researchers. We present a two-dimensional (2-D) generalization of the one-dimensional GT. This 2-D GT is applied to encrypt digital images in this paper. The scaling factors of the GT can be used as new keys, providing a new encryption system with a high security characteristics. This method can encrypt and protect the information of the digital images with a high security for information processing systems.

  6. Resolution enhancement of scanning four-point-probe measurements on two-dimensional systems.

    OpenAIRE

    Hansen, Torben Mikael; Stokbro, Kurt; Hansen, Ole; Hassenkam, T.; Shiraki, I.; Hasegawa, S.; Bøggild, Peter

    2003-01-01

    A method to improve the resolution of four-point-probe measurements of two-dimensional (2D) and quasi-2D systems is presented. By mapping the conductance on a dense grid around a target area and postprocessing the data, the resolution can be improved by a factor of approximately 50 to better than 1/15 of the four-point-probe electrode spacing. The real conductance sheet is simulated by a grid of discrete resistances, which is optimized by means of a standard optimization algorithm, until the ...

  7. Modeling of pressure sensors based on two-dimensional photonic crystals

    Institute of Scientific and Technical Information of China (English)

    Xuehui XIONG; Ping LU; Deming LIU

    2009-01-01

    A pressure sensor based on the two-dimensional photonic crystal (2D PC) has been proposed. Under the condition of different pressure, the photonic band gap of the sensor has been studied by means of the plane wave expansion method (PWM). The results show that there is a good linear relation between the cutoff wavelength and the pressure. Apart from being easily implemented, the presented 2D PC pressure sensor holds many characteristics such as high-pressure sensitivity and convenience in achieving demanded pressure range.

  8. Two-dimensional gold nanostructures with high activity for selective oxidation of carbon-hydrogen bonds

    Science.gov (United States)

    Wang, Liang; Zhu, Yihan; Wang, Jian-Qiang; Liu, Fudong; Huang, Jianfeng; Meng, Xiangju; Basset, Jean-Marie; Han, Yu; Xiao, Feng-Shou

    2015-04-01

    Efficient synthesis of stable two-dimensional (2D) noble metal catalysts is a challenging topic. Here we report the facile synthesis of 2D gold nanosheets via a wet chemistry method, by using layered double hydroxide as the template. Detailed characterization with electron microscopy and X-ray photoelectron spectroscopy demonstrates that the nanosheets are negatively charged and [001] oriented with thicknesses varying from single to a few atomic layers. X-ray absorption spectroscopy reveals unusually low gold-gold coordination numbers. These gold nanosheets exhibit high catalytic activity and stability in the solvent-free selective oxidation of carbon-hydrogen bonds with molecular oxygen.

  9. A Two-Dimensional MagnetoHydrodynamics Scheme for General Unstructured Grids

    CERN Document Server

    Livne, E; Burrows, A; Meakin, C A; Livne, Eli; Dessart, Luc; Burrows, Adam; Meakin, Casey A.

    2007-01-01

    We report a new finite-difference scheme for two-dimensional magnetohydrodynamics (MHD) simulations, with and without rotation, in unstructured grids with quadrilateral cells. The new scheme is implemented within the code VULCAN/2D, which already includes radiation-hydrodynamics in various approximations and can be used with arbitrarily moving meshes (ALE). The MHD scheme, which consists of cell-centered magnetic field variables, preserves the nodal finite difference representation of $div(\\bB)$ by construction, and therefore any initially divergence-free field remains divergence-free through the simulation. In this paper, we describe the new scheme in detail and present comparisons of VULCAN/2D results with those of the code ZEUS/2D for several one-dimensional and two-dimensional test problems. The code now enables two-dimensional simulations of the collapse and explosion of the rotating, magnetic cores of massive stars. Moreover, it can be used to simulate the very wide variety of astrophysical problems for...

  10. Energy Spectra of Vortex Distributions in Two-Dimensional Quantum Turbulence

    Directory of Open Access Journals (Sweden)

    Ashton S. Bradley

    2012-10-01

    Full Text Available We theoretically explore key concepts of two-dimensional turbulence in a homogeneous compressible superfluid described by a dissipative two-dimensional Gross-Pitaeveskii equation. Such a fluid supports quantized vortices that have a size characterized by the healing length ξ. We show that, for the divergence-free portion of the superfluid velocity field, the kinetic-energy spectrum over wave number k may be decomposed into an ultraviolet regime (k≫ξ^{-1} having a universal k^{-3} scaling arising from the vortex core structure, and an infrared regime (k≪ξ^{-1} with a spectrum that arises purely from the configuration of the vortices. The Novikov power-law distribution of intervortex distances with exponent -1/3 for vortices of the same sign of circulation leads to an infrared kinetic-energy spectrum with a Kolmogorov k^{-5/3} power law, which is consistent with the existence of an inertial range. The presence of these k^{-3} and k^{-5/3} power laws, together with the constraint of continuity at the smallest configurational scale k≈ξ^{-1}, allows us to derive a new analytical expression for the Kolmogorov constant that we test against a numerical simulation of a forced homogeneous, compressible, two-dimensional superfluid. The numerical simulation corroborates our analysis of the spectral features of the kinetic-energy distribution, once we introduce the concept of a clustered fraction consisting of the fraction of vortices that have the same sign of circulation as their nearest neighboring vortices. Our analysis presents a new approach to understanding two-dimensional quantum turbulence and interpreting similarities and differences with classical two-dimensional turbulence, and suggests new methods to characterize vortex turbulence in two-dimensional quantum fluids via vortex position and circulation measurements.

  11. Two dimensional graphene nanogenerator by coulomb dragging: Moving van der Waals heterostructure

    Energy Technology Data Exchange (ETDEWEB)

    Zhong, Huikai; Li, Xiaoqiang; Wu, Zhiqian; Zhang, Shengjiao; Xu, Zhijuan [Department of Information Science and Electronic Engineering, Zhejiang University, Hangzhou 310027 (China); Chen, Hongsheng; Lin, Shisheng, E-mail: shishenglin@zju.edu.cn [Department of Information Science and Electronic Engineering, Zhejiang University, Hangzhou 310027 (China); State Key Laboratory of Modern Optical Instrumentation, Zhejiang University, Hangzhou 310027 (China)

    2015-06-15

    Harvesting energy from environment is the current focus of scientific community. Here, we demonstrate a graphene nanogenerator, which is based on moving van der Waals heterostructure formed between graphene and two dimensional (2D) graphene oxide (GO). This nanogenerator can convert mechanical energy into electricity with a voltage output of around 10 mV. Systematic experiments reveal the generated electricity originates from the coulomb interaction induced momentum transfer between 2D GO and holes in graphene. 2D boron nitride was also demonstrated to be effective in the framework of moving van der Waals heterostructure nanogenerator. This investigation of nanogenerator based on the interaction between 2D macromolecule materials will be important to understand the origin of the flow-induced potential in nanomaterials and may have great potential in practical applications.

  12. Two dimensional graphene nanogenerator by coulomb dragging: Moving van der Waals heterostructure

    Science.gov (United States)

    Zhong, Huikai; Li, Xiaoqiang; Wu, Zhiqian; Zhang, Shengjiao; Xu, Zhijuan; Chen, Hongsheng; Lin, Shisheng

    2015-06-01

    Harvesting energy from environment is the current focus of scientific community. Here, we demonstrate a graphene nanogenerator, which is based on moving van der Waals heterostructure formed between graphene and two dimensional (2D) graphene oxide (GO). This nanogenerator can convert mechanical energy into electricity with a voltage output of around 10 mV. Systematic experiments reveal the generated electricity originates from the coulomb interaction induced momentum transfer between 2D GO and holes in graphene. 2D boron nitride was also demonstrated to be effective in the framework of moving van der Waals heterostructure nanogenerator. This investigation of nanogenerator based on the interaction between 2D macromolecule materials will be important to understand the origin of the flow-induced potential in nanomaterials and may have great potential in practical applications.

  13. Mapping of 34 minisatellite loci resolved by two-dimensional DNA typing

    DEFF Research Database (Denmark)

    Børglum, Anders; Nyegaard, Mette; Kvistgaard, AB

    1997-01-01

    Two-dimensional (2-D) DNA typing is based on electrophoretic separation of genomic DNA fragments in two dimensions according to independent criteria (size and base-pair sequence), followed by hybridization analysis using multilocus probes. The technique allows simultaneous visualization of several...... could be deduced, showing no evidence of clustering. In the analysis of spot patterns, use was made of a computerized image analysis system specifically designed for 2-D DNA typing. Since experimental variations between different separation patterns were automatically corrected for with this program......, rapid and reliable scorings could be obtained. The results presented demonstrate the availability of reliable genetic information throughout the 2-D separation pattern. Adding the use of semiautomated computerized pattern analysis, this study further substantiates the applicability of 2-D DNA typing...

  14. Clustering behavior of solid particles in two-dimensional liquid-solid fluidized-beds

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    In this paper, the clustering behavior of solid particles in a two-dimensional (2D) liquid-solid fluidized-bed was studied by using the charge coupled devices (CCD) imaging measuring and processing technique and was characterized by fractal analysis. CCD images show that the distribution of solid particles in the 2D liquid-solid fluidised-bed is not uniform and self-organization behavior of solid particles was observed under the present experimental conditions. The solid particles move up in the 2D fluidized-bed in groups or clusters whose configurations are often in the form of horizontal strands. The box fractal dimension of the cluster images in the 2D liquid-solid fluidized-bed increases with the rising of solid holdup and reduces with the increment of solid particle diameter and superficial liquid velocity. At given solid holdup and solid particle size,the lighter particles show smaller fractal dimensions.

  15. Two-dimensional topological crystalline insulator phase in quantum wells of trivial insulators

    Science.gov (United States)

    Niu, Chengwang; Buhl, Patrick M.; Bihlmayer, Gustav; Wortmann, Daniel; Blügel, Stefan; Mokrousov, Yuriy

    2016-06-01

    The realization of two-dimensional (2D) topological insulators (TIs) in HgTe/CdTe quantum wells (QWs) has generated an explosion of research on TIs and novel topologically nontrivial phases. Here we predict, based on first-principles calculations, that the newly discovered 2D topological crystalline insulators (TCIs) phase exists even in the QWs of trivial insulators, e.g. (Sn/Pb)Te and Na(Cl/Br), with mirror Chern number {n}{{M}}=-2. Tunable nontrivial energy gaps ranging from 4 to 238 meV are obtained, guaranteeing further room-temperature observations and applications. The combined effect of strain and electrostatic interaction that can be engineered by the cladding layers leads to a band inversion, resulting in the phase transition from trivial insulator to 2D TCIs. Our work provides a new strategy for engineering topological states in 2D materials.

  16. Femtosecond X-ray diffraction from two-dimensional protein crystals.

    Science.gov (United States)

    Frank, Matthias; Carlson, David B; Hunter, Mark S; Williams, Garth J; Messerschmidt, Marc; Zatsepin, Nadia A; Barty, Anton; Benner, W Henry; Chu, Kaiqin; Graf, Alexander T; Hau-Riege, Stefan P; Kirian, Richard A; Padeste, Celestino; Pardini, Tommaso; Pedrini, Bill; Segelke, Brent; Seibert, M Marvin; Spence, John C H; Tsai, Ching-Ju; Lane, Stephen M; Li, Xiao-Dan; Schertler, Gebhard; Boutet, Sebastien; Coleman, Matthew; Evans, James E

    2014-03-01

    X-ray diffraction patterns from two-dimensional (2-D) protein crystals obtained using femtosecond X-ray pulses from an X-ray free-electron laser (XFEL) are presented. To date, it has not been possible to acquire transmission X-ray diffraction patterns from individual 2-D protein crystals due to radiation damage. However, the intense and ultrafast pulses generated by an XFEL permit a new method of collecting diffraction data before the sample is destroyed. Utilizing a diffract-before-destroy approach at the Linac Coherent Light Source, Bragg diffraction was acquired to better than 8.5 Å resolution for two different 2-D protein crystal samples each less than 10 nm thick and maintained at room temperature. These proof-of-principle results show promise for structural analysis of both soluble and membrane proteins arranged as 2-D crystals without requiring cryogenic conditions or the formation of three-dimensional crystals.

  17. Two-Dimensional Porous Micro/Nano Metal Oxides Templated by Graphene Oxide.

    Science.gov (United States)

    Cao, Hailiang; Zhou, Xufeng; Zheng, Chao; Liu, Zhaoping

    2015-06-10

    Novel two-dimensional (2D) porous metal oxides with micro-/nanoarchitecture have been successfully fabricated using graphene oxide (GO) as a typical sacrificial template. GO as a 2D template ensures that the growth and fusion of metal oxides nanoparticles is restricted in the 2D plane. A series of metal oxides (NiO, Fe2O3, Co3O4, Mn2O3, and NiFe2O4) with similar nanostructure were investigated using this simple method. Some of these special nanostructured materials, such as NiO, when being used as anode for lithium-ion batteries, can exhibit high specific capacity, good rate performance, and cycling stability. Importantly, this strategy of creating a 2D porous micro/nano architecture can be easily extended to controllably synthesize other binary/polynary metal oxides nanostructures for lithium-ion batteries or other applications.

  18. The PLSI Method of Stabilizing Two-Dimensional Nonsymmetric Half-Plane Recursive Digital Filters

    Directory of Open Access Journals (Sweden)

    Gangatharan N

    2003-01-01

    Full Text Available Two-dimensional (2D recursive digital filters find applications in image processing as in medical X-ray processing. Nonsymmetric half-plane (NSHP filters have definitely positive magnitude characteristics as opposed to quarter-plane (QP filters. In this paper, we provide methods for stabilizing the given 2D NSHP polynomial by the planar least squares inverse (PLSI method. We have proved in this paper that if the given 2D unstable NSHP polynomial and its PLSI are of the same degree, the PLSI polynomial is always stable, irrespective of whether the coefficients of the given polynomial have relationship among its coefficients or not. Examples are given for 2D first-order and second-order cases to prove our results. The generalization is done for the th order polynomial.

  19. High-performance photodetectors and enhanced photocatalysts of two-dimensional TiO2 nanosheets under UV light excitation

    Science.gov (United States)

    Yang, Jiao; Jiang, Yi-Lin; Li, Lin-Jie; Muhire, Elisée; Gao, Mei-Zhen

    2016-04-01

    Due to the large surface area-to-volume ratio and rapid electron transfer, two-dimensional (2D) TiO2 nanosheets with ultrathin thicknesses are synthesized by using a bottom-up strategy and these self-assembled nanosheet (NS)-based photocatalysts and photodetectors were explored for the first time. The influence of calcination temperature on microstructures and photocatalytic activity of TiO2 nanosheets were discovered and presented. The as-obtained TiO2 nanosheets were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) analysis, Fourier transform infrared (FTIR) spectroscopy, UV-vis spectrophotometry, and X-ray photoelectron spectroscopy (XPS). The following heat treatment process induced phase evolution from rutile to anatase. The TiO2 nanosheets calcined at 500 °C exhibited the best activity for photo-degradation of organic dyes under UV light irradiation. The obtained photodetector exhibits excellent performance with a high photocurrent to dark current ratio and fast response and recovery times. Additionally, we demonstrated that the device may have potential applications in the future low-power optoelectronics system.Due to the large surface area-to-volume ratio and rapid electron transfer, two-dimensional (2D) TiO2 nanosheets with ultrathin thicknesses are synthesized by using a bottom-up strategy and these self-assembled nanosheet (NS)-based photocatalysts and photodetectors were explored for the first time. The influence of calcination temperature on microstructures and photocatalytic activity of TiO2 nanosheets were discovered and presented. The as-obtained TiO2 nanosheets were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) analysis, Fourier transform infrared (FTIR) spectroscopy, UV-vis spectrophotometry, and X-ray photoelectron spectroscopy (XPS). The following

  20. Novel Symmetries in Two Dimensional Proca Theory

    CERN Document Server

    Bhanja, T; Malik, R P

    2013-01-01

    By exploiting the Stueckelberg's approach, we obtain a gauge theory for the two (1+1)-dimensional (2D) Proca theory and demonstrate that this theory is endowed with, in addition to the usual Becchi-Rouet-Stora-Tyutin (BRST) and anti-BRST symmetries, the on-shell nilpotent (anti-)co-BRST symmetries, under which, the total gauge-fixing term remains invariant. The anticommutator of the BRST and co-BRST (as well as anti-BRST and anti-co-BRST) symmetries define a unique bosonic symmetry in the theory, under which, the ghost part of the Lagrangian density remains invariant. To establish connections of the above symmetries with the Hodge theory, we invoke a pseudo-scalar field in the theory. Ultimately, we demonstrate that the full theory provides a field theoretic example for the Hodge theory where the continuous symmetry transformations provide a physical realization of the de Rham cohomological operators and discrete symmetries of the theory lead to the physical realization of the Hodge duality operation of diffe...