Two-Compartment Pharmacokinetic Models for Chemical Engineers
Kanneganti, Kumud; Simon, Laurent
2011-01-01
The transport of potassium permanganate between two continuous-stirred vessels was investigated to help chemical and biomedical engineering students understand two-compartment pharmacokinetic models. Concepts of modeling, mass balance, parameter estimation and Laplace transform were applied to the two-unit process. A good agreement was achieved…
Two-Compartment Pharmacokinetic Models for Chemical Engineers
Kanneganti, Kumud; Simon, Laurent
2011-01-01
The transport of potassium permanganate between two continuous-stirred vessels was investigated to help chemical and biomedical engineering students understand two-compartment pharmacokinetic models. Concepts of modeling, mass balance, parameter estimation and Laplace transform were applied to the two-unit process. A good agreement was achieved…
Gherase, Mihai R
2012-01-01
Diffusive spin exchange is one of the most important relaxation mechanisms in the Nuclear Magnetic Resonance (NMR) applications to medicine and biology. Two models based on the Bloch-McConnell (B-M) and the Bloch-Torrey (B-T) equations are commonly used for modelling the physical processes which determine the NMR lineshapes. Qualitative arguments for each of the two methods can be found in various studies in the literature. However, there is a lack of systematic quantitative investigations of the diffusive exchange spectra calculated with the two methods for the same physical system or model. In this work exact frequency-domain transverse magnetization solutions of the B-M and the B-T equations with boundary conditions for a two-compartment radial diffusive exchange model are presented. Theoretical spectra and the two corresponding metrics were computed by varying three different parameters: diffusive permeability of the separating membrane between the two compartments (P), the radius of the inner spherical c...
Two-compartment model of radioimmunotherapy delivered through cerebrospinal fluid
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He, Ping [Johns Hopkins University, Department of Biomedical Engineering, Baltimore, MD (United States); Kramer, Kim; Cheung, Nai-Kong V. [Memorial Sloan-Kettering Cancer Center, Department of Pediatrics, New York, NY (United States); Smith-Jones, Peter; Larson, Steven M. [Memorial Sloan-Kettering Cancer Center, Department of Radiology, New York, NY (United States); Zanzonico, Pat; Humm, John [Memorial Sloan-Kettering Cancer Center, Department of Medical Physics, New York, NY (United States)
2011-02-15
Radioimmunotherapy (RIT) using {sup 131}I-3F8 injected into cerebrospinal fluid (CSF) was a safe modality for the treatment of leptomeningeal metastases (JCO, 25:5465, 2007). A single-compartment pharmacokinetic model described previously (JNM 50:1324, 2009) showed good fitting to the CSF radioactivity data obtained from patients. We now describe a two-compartment model to account for the ventricular reservoir of {sup 131}I-3F8 and to identify limiting factors that may impact therapeutic ratio. Each parameter was examined for its effects on (1) the area under the radioactivity concentration curve of the bound antibody (AUC[C{sub IAR}]), (2) that of the unbound antibody AUC[C{sub IA}], and (3) their therapeutic ratio (AUC[C{sub IAR}]/AUC[C{sub IA}]). Data fitting showed that CSF kBq/ml data fitted well using the two-compartment model (R = 0.95 {+-} 0.03). Correlations were substantially better when compared to the one-compartment model (R = 0.92 {+-} 0.11 versus 0.77 {+-} 0.21, p = 0.005). In addition, we made the following new predictions: (1) Increasing immunoreactivity of {sup 131}I-3F8 from 10% to 90% increased both (AUC[C{sub IAR}]) and therapeutic ratio (AUC[C{sub IAR}]/AUC[C{sub IA}]) by 7.4 fold, (2) When extrapolated to the clinical setting, the model predicted that if {sup 131}I-3F8 could be split into 4 doses of 1.4 mg each and given at {>=}24 hours apart, an antibody affinity of K{sub D} of 4 x 10{sup -9} at 50% immunoreactivity were adequate in order to deliver {>=}100 Gy to tumor cells while keeping normal CSF exposure to <10 Gy. This model predicted that immunoreactivity, affinity and optimal scheduling of antibody injections were crucial in improving therapeutic index. (orig.)
Two-compartment model for competitive hybridization on molecular biochips
Chechetkin, V. R.
2007-01-01
During competitive hybridization the specific and non-specific fractions of tested biomolecules in solution bind jointly with the specific probes immobilized in a separate cell of a microchip. The application of two-compartment model to the two-component hybridization allows analytically investigating the underlying kinetics. It is shown that the behaviour with the non-monotonous growth of complexes formed by the non-specific fraction on a probe cell is a typical feature of competitive hybridization for both diffusion-limited and reaction-limited kinetics. The physical reason behind such an evolution consists in the fact that the characteristic hybridization time for the perfect complexes turns out longer with respect to that for the mismatch complexes. This behaviour should be taken into account for the choice of optimum hybridization and washing conditions for the analysis of specific fraction.
Two-compartment model for competitive hybridization on molecular biochips
Energy Technology Data Exchange (ETDEWEB)
Chechetkin, V.R. [Theoretical Department of Division for Perspective Investigations, Troitsk Institute of Innovation and Thermonuclear Investigations (TRINITI), Troitsk, 142190 Moscow Region (Russian Federation)]. E-mail: chechet@biochip.ru
2007-01-08
During competitive hybridization the specific and non-specific fractions of tested biomolecules in solution bind jointly with the specific probes immobilized in a separate cell of a microchip. The application of two-compartment model to the two-component hybridization allows analytically investigating the underlying kinetics. It is shown that the behaviour with the non-monotonous growth of complexes formed by the non-specific fraction on a probe cell is a typical feature of competitive hybridization for both diffusion-limited and reaction-limited kinetics. The physical reason behind such an evolution consists in the fact that the characteristic hybridization time for the perfect complexes turns out longer with respect to that for the mismatch complexes. This behaviour should be taken into account for the choice of optimum hybridization and washing conditions for the analysis of specific fraction.
Characterizing exposure to chemicals from soil vapor intrusion using a two-compartment model
Olson, David A.; Corsi, Richard L.
Though several different models have been developed for sub-surface migration, little attention has been given to the effect of subsurface transport on the indoor environment. Existing methods generally assume that a house is one well-mixed compartment. A two-compartment model was developed to better characterize this exposure pathway; the model treats the house as two well-mixed compartments, one for the basement and one for the remainder of the house. A field study was completed to quantify parameters associated with the two-compartment model, such as soil gas intrusion rates and basement to ground floor air exchange rates. Two residential test houses in Paulsboro, New Jersey were selected for this study. All experiments were completed using sulfur hexafluoride (SF 6) as a tracer gas. Soil gas intrusion rates were found to be highly dependent on the soil gas to basement pressure difference, varying from 0.001 m 3 m -2 h -1 for a pressure drop of -0.2 Pa to 0.011 m 3 m -2 h -1 for a pressure drop of -6.0 Pa. Basement ventilation rates ranged from 0.17 to 0.75 air changes per hour (ACH) for basement to ambient pressure differences ranging from -1.1 to -7.6 Pa (relative to ambient). Application of experimental results in conjunction with the two-compartment model indicate that exposures are highly dependent on gas intrusion rates, basement ventilation rate, and fraction of time spent in the basement. These results can also be significantly different when compared with the simple well-mixed house assumption.
Tamrin, N. S. Ahmad; Ibrahim, N.
2014-11-01
The reduction of the urea concentration in blood can be numerically projected by using one-compartment model and two-compartment model with no variation in body fluid. This study aims to compare the simulated values of post-dialysis urea concentration for both models with the clinical data obtained from the hospital. The clinical assessment of adequacy of a treatment is based on the value of Kt/V. Further, direct calculation using clinical data and one-compartment model are presented in the form of ratio. It is found that the ratios of postdialysis urea concentration simulated using two-compartment model are higher compared to the ratios of post-dialysis urea concentration using one-compartment model. In addition, most values of post-dialysis urea concentration simulated using two-compartment model are much closer to the clinical data compared to values simulated using one-compartment model. Kt/V values calculated directly using clinical data are found to be higher than Kt/V values derived from one-compartment model.
DEFF Research Database (Denmark)
Fedosov, Sergey
1994-01-01
In order to characterize ADP-ATP and creatine-creatine phosphate (Cr-CrP) shuttles a minimal mathematical model with two compartments and cyclic turnover of matter was designed. The 'mitochondrial' compartment contained 'ATP-synthase' and 'mitochondrial ereatine kinase' (mitCK). The 'cytoplasmic......' compartment consisted of 'ATPase', 'cytoplasmic creatine kinase' (cytCK) and an 'ADP-binding structure'. The exchange of metabolites between these compartments was limited. Different levels of cytCK and mitCK expression as welt as different exchange rate constants between the compartments were assigned...
Role of delay in plant growth dynamics: A two compartment mathematical model
Kalra, Preety; Kumar, Pankaj
2017-07-01
A mathematical model consisting of two compartments-shoot and root is used in this paper for the study of growth of an individual plant. The dynamics of plant growth is studied by division of plant in these two compartments where the associated state variables are structural dry weight and concentration of nutrients. The assumption is that the nutrient is taken up from the root compartment and the exogenic activities hinder the up taking of nutrients that are essential for the plants and adversely affect the nutrient use efficiency (utilization coefficients) resulting into root structural damage. This effect is studied by introducing the delay (time-lag) in utilization parameter. The inclusion of delay disturbed the Stability of the system and Hopf bifurcation occurred. Analytic results have been supported by numerical simulation using MATLAB.
The dynamical analysis of modified two-compartment neuron model and FPGA implementation
Lin, Qianjin; Wang, Jiang; Yang, Shuangming; Yi, Guosheng; Deng, Bin; Wei, Xile; Yu, Haitao
2017-10-01
The complexity of neural models is increasing with the investigation of larger biological neural network, more various ionic channels and more detailed morphologies, and the implementation of biological neural network is a task with huge computational complexity and power consumption. This paper presents an efficient digital design using piecewise linearization on field programmable gate array (FPGA), to succinctly implement the reduced two-compartment model which retains essential features of more complicated models. The design proposes an approximate neuron model which is composed of a set of piecewise linear equations, and it can reproduce different dynamical behaviors to depict the mechanisms of a single neuron model. The consistency of hardware implementation is verified in terms of dynamical behaviors and bifurcation analysis, and the simulation results including varied ion channel characteristics coincide with the biological neuron model with a high accuracy. Hardware synthesis on FPGA demonstrates that the proposed model has reliable performance and lower hardware resource compared with the original two-compartment model. These investigations are conducive to scalability of biological neural network in reconfigurable large-scale neuromorphic system.
Two-compartment model as a teaching tool for cholesterol homeostasis.
Wrona, Artur; Balbus, Joanna; Hrydziuszko, Olga; Kubica, Krystian
2015-12-01
Cholesterol is a vital structural and functional molecule in the human body that is only slightly soluble in water and therefore does not easily travels by itself in the bloodstream. To enable cholesterol's targeted delivery to cells and tissues, it is encapsulated by different fractions of lipoproteins, complex particles containing both proteins and lipids. Maintaining cholesterol homeostasis is a highly regulated process with multiple factors acting at both molecular and tissue levels. Furthermore, to regulate the circulatory transport of cholesterol in lipoproteins, the amount of cholesterol present depends on and is controlled by cholesterol dietary intake, de novo synthesis, usage, and excretion; abnormal and/or unbalanced cholesterol levels have been shown to lead to severe outcomes, e.g., cardiovascular diseases. To investigate cholesterol transport in the circulatory system, we have previously developed a two-compartment mathematical model. Here, we show how this model can be used as a teaching tool for cholesterol homeostasis. Using the model and a hands-on approach, students can familiarize themselves with the basic components and mechanisms behind balanced cholesterol circulatory transport as well as investigate the consequences of and countermeasures to abnormal cholesterol levels. Among others, various treatments of high blood cholesterol levels can be simulated, e.g., with commonly prescribed de novo cholesterol synthesis inhibitors.
Water renewal in Montevideo's bay: a two compartments model for tritium kinetics
Energy Technology Data Exchange (ETDEWEB)
Suarez-Antola, Roberto, E-mail: rsuarez@ucu.edu.uy [Universidad Catolica del Uruguay (UCU), Montevideo (Uruguay)
2013-07-01
During field work about dynamics and renewal of water in Montevideo's Bay, 100 Ci of tritiated water were evenly distributed in the north-east region of the bay, by a continuous injection of a solution, during 5 hours, from a 200 litres tank, using a peristaltic pump. The whole bay was divided in 20 concentration cells, taking into account available bathymetric charts and corrections from field data obtained in situ. Tritium concentrations (activities per unit volume) and other relevant parameters (temperature, electrical conductivity, etc.) were measured in vertical profiles during three weeks, in the mid-point of each cell, first twice a day and the on a daily basis. Remnant total tritium activity was estimated from cells volumes and midpoint cells activity concentrations. Consistency checks were done. A one compartment model was used to estimate a global renewal time of circa 29 hours. However, the details of the measured tritium kinetics, a careful consideration of bathymetric data, water movements in a tidal environment (measured with drogues, fluorescent tracers and current meters), as well as the results of computer fluid dynamics modelling (in depth averaged) suggests that the bay can be meaningfully divided in two main compartments: a North-East and a South-West compartment. The purpose of this paper is threefold: (1) to describe the construction of a two compartments model for water renewal in Montevideo's Bay, (2) to apply experimental data of tritium kinetics to estimate the parameters of the model, and (3) to discuss the validity of the model and its practical applicability. The meaning of the renewal time of each compartment and its relation with the measured tritium kinetics in each cell is discussed. The perturbations in water circulation and renewal produced by civil works already done or the perturbations that could be expected due to civil works to be done, in relation with Montevideo's harbour, is discussed. The tracer model
Jinga, V V; Bogdan, I; Fruchter, J
1986-01-01
A two-compartment system was set up for the measurement of macromolecules, particles and water transfer through the monolayers of cultured endothelial cells. Experimental parameters like differential hydrostatic and osmotic pressures (delta P and delta pi, respectively) concentration gradients, temperature could be controlled. The experiments were carried out, on a cellular line of bovine aortic endothelium produced in our laboratory. Morphological and immunological investigations attested the differentiation of these cells grown on a porous support membrane separating the two compartments. The system allowed morphologic check up on the continuity of endothelial monolayer and ultrastructural studies. Hydraulic conductivity determined for endothelial monolayers was 6.86 +/- 0.85 cm. sec-1 X cm H2O-1 X 10(-7) at delta P = 10 mm Hg and 8.23 +/- 0.80 cm. sec-1 X cm H2O-1 X 10(-7) at delta P = 30 mm Hg, which proves an adequate functional integrity. Investigations using successive radioactive pulses on the same culture were possible without notable residual radioactivity between pulses.
Directory of Open Access Journals (Sweden)
Cogo Paola E
2007-02-01
Full Text Available Abstract Background In patients with acute respiratory distress syndrome (ARDS, it is well known that only part of the lungs is aerated and surfactant function is impaired, but the extent of lung damage and changes in surfactant turnover remain unclear. The objective of the study was to evaluate surfactant disaturated-phosphatidylcholine turnover in patients with ARDS using stable isotopes. Methods We studied 12 patients with ARDS and 7 subjects with normal lungs. After the tracheal instillation of a trace dose of 13C-dipalmitoyl-phosphatidylcholine, we measured the 13C enrichment over time of palmitate residues of disaturated-phosphatidylcholine isolated from tracheal aspirates. Data were interpreted using a model with two compartments, alveoli and lung tissue, and kinetic parameters were derived assuming that, in controls, alveolar macrophages may degrade between 5 and 50% of disaturated-phosphatidylcholine, the rest being lost from tissue. In ARDS we assumed that 5–100% of disaturated-phosphatidylcholine is degraded in the alveolar space, due to release of hydrolytic enzymes. Some of the kinetic parameters were uniquely determined, while others were identified as lower and upper bounds. Results In ARDS, the alveolar pool of disaturated-phosphatidylcholine was significantly lower than in controls (0.16 ± 0.04 vs. 1.31 ± 0.40 mg/kg, p de novo synthesis of disaturated-phosphatidylcholine were also significantly lower, while mean resident time in lung tissue was significantly higher in ARDS than in controls. Recycling was 16.2 ± 3.5 in ARDS and 31.9 ± 7.3 in controls (p = 0.08. Conclusion In ARDS the alveolar pool of surfactant is reduced and disaturated-phosphatidylcholine turnover is altered.
Energy Technology Data Exchange (ETDEWEB)
Tachibana, Yasuhiko [National Institute of Radiological Sciences, Research Center for Charged Particle Therapy, Chiba (Japan); Yokohama City University Graduate School of Medicine, Department of Radiology, Yokohama (Japan); Juntendo University School of Medicine, Department of Radiology, Tokyo (Japan); Obata, Takayuki [National Institute of Radiological Sciences, Research Center for Charged Particle Therapy, Chiba (Japan); Yoshida, Mariko; Hori, Masaaki; Kamagata, Koji; Suzuki, Michimasa; Fukunaga, Issei; Kamiya, Kouhei; Aoki, Shigeki [Juntendo University School of Medicine, Department of Radiology, Tokyo (Japan); Yokoyama, Kazumasa; Hattori, Nobutaka [Juntendo University School of Medicine, Department of Neurology, Tokyo (Japan); Inoue, Tomio [Yokohama City University Graduate School of Medicine, Department of Radiology, Yokohama (Japan)
2015-06-01
To compare the significance of the two-compartment model, considering diffusional anisotropy with conventional diffusion analyzing methods regarding the detection of occult changes in normal-appearing white matter (NAWM) of multiple sclerosis (MS). Diffusion-weighted images (nine b-values with six directions) were acquired from 12 healthy female volunteers (22-52 years old, median 33 years) and 13 female MS patients (24-48 years old, median 37 years). Diffusion parameters based on the two-compartment model of water diffusion considering diffusional anisotropy was calculated by a proposed method. Other parameters including diffusion tensor imaging and conventional apparent diffusion coefficient (ADC) were also obtained. They were compared statistically between the control and MS groups. Diffusion of the slow diffusion compartment in the radial direction of neuron fibers was elevated in MS patients (0.121 x 10{sup -3} mm{sup 2}/s) in comparison to control (0.100 x 10{sup -3} mm{sup 2}/s), the difference being significant (P = 0.001). The difference between the groups was not significant in other comparisons, including conventional ADC and fractional anisotropy (FA) of diffusion tensor imaging. The proposed method was applicable to clinically acceptable small data. The parameters obtained by this method improved the detectability of occult changes in NAWM compared to the conventional methods. (orig.)
Directory of Open Access Journals (Sweden)
Hedia Fgaier
2015-01-01
Full Text Available The effect of β-amyloid aggregates on activity of choline acetyltransferase (ChAT which is responsible for synthesizing acetylcholine (ACh in human brain is investigated through the two-enzyme/two-compartment (2E2C model where the presynaptic neuron is considered as compartment 1 while both the synaptic cleft and the postsynaptic neuron are considered as compartment 2 through suggesting three different kinetic mechanisms for the inhibition effect. It is found that the incorporation of ChAT inhibition by β-amyloid aggregates into the 2E2C model is able to yield dynamic solutions for concentrations of generated β-amyloid, ACh, choline, acetate, and pH in addition to the rates of ACh synthesis and ACh hydrolysis in compartments 1 and 2. It is observed that ChAT activity needs a high concentration of β-amyloid aggregates production rate. It is found that ChAT activity is reduced significantly when neurons are exposed to high levels of β-amyloid aggregates leading to reduction in levels of ACh which is one of the most significant physiological symptoms of AD. Furthermore, the system of ACh neurocycle is dominated by the oscillatory behavior when ChAT enzyme is completely inhibited by β-amyloid. It is observed that the direct inactivation of ChAT by β-amyloid aggregates may be a probable mechanism contributing to the development of AD.
Murphy, Kelly E.
2011-03-01
The repair of dermal tissue is a complex process of interconnected phenomena, where cellular, chemical and mechanical aspects all play a role, both in an autocrine and in a paracrine fashion. Recent experimental results have shown that transforming growth factor -β (TGF β) and tissue mechanics play roles in regulating cell proliferation, differentiation and the production of extracellular materials. We have developed a 1D mathematical model that considers the interaction between the cellular, chemical and mechanical phenomena, allowing the combination of TGF β and tissue stress to inform the activation of fibroblasts to myofibroblasts. Additionally, our model incorporates the observed feature of residual stress by considering the changing zero-stress state in the formulation for effective strain. Using this model, we predict that the continued presence of TGF β in dermal wounds will produce contractures due to the persistence of myofibroblasts; in contrast, early elimination of TGF β significantly reduces the myofibroblast numbers resulting in an increase in wound size. Similar results were obtained by varying the rate at which fibroblasts differentiate to myofibroblasts and by changing the myofibroblast apoptotic rate. Taken together, the implication is that elevated levels of myofibroblasts is the key factor behind wounds healing with excessive contraction, suggesting that clinical strategies which aim to reduce the myofibroblast density may reduce the appearance of contractures. © 2010 Elsevier Ltd.
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Krylov, S.N.; Huang, X.D.; Zeiler, L.F.; Dixon, D.G.; Greenberg, B.M. [Univ. of Waterloo, Ontario (Canada). Dept. of Biology
1997-11-01
A quantitative structure-activity relationship model for the photoinduced toxicity of 16 polycyclic aromatic hydrocarbons (PAHs) to duckweed (Lemna gibba) in simulated solar radiation (SSR) was developed. Lemna gibba was chosen for this study because toxicity could be considered in two compartments: water column and leaf tissue. Modeling of photoinduced toxicity was described by photochemical reactions between PAHs and a hypothetical group of endogenous biomolecules (G) required for normal growth, with damage to G by PAHs and/or photomodified PAHs in SSR resulting in impaired growth. The reaction scheme includes photomodification of PAHs, uptake of PAHs into leaves, triplet-state formation of intact PAHs, photosensitization reactions that damage G, and reactions between photomodified PAHs and G. The assumptions used were: the PAH photomodification rate is slower than uptake of chemicals into leaves, the PAH concentration in aqueous solution is nearly constant during a toxicity test, the fluence rate of actinic radiation is lower within leaves than in the aqueous phase, and the toxicity of intact PAHs in the dark is negligible. A series of differential equations describing the reaction kinetics of intact and photomodifed PAHs with G was derived. The resulting equation for PAH toxicity was a function of treatment period, initial PAH concentration, relative absorbance of SSR by each PAH, quantum yield for formation of triplet-state PAH, and rate of PAH photomodification. Data for growth in the presence of intact and photomodified PAHs were used to empirically solve for a photosensitization constant (PSC) and a photomodification constant (PMC) for each of the 16 PAHs tested. For 9 PAHs the PMC dominates and for 7 PAHs the PSC dominates.
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Zoellner, Frank G.; Zimmer, Fabian; Schad, Lothar R. [Heidelberg Univ., Mannheim (Germany). Computer Assisted Clinical Medicine; Klotz, Sarah; Hoeger, Simone [Heidelberg Univ., Mannheim (Germany). Dept. of Medicine V
2015-05-01
To investigate how MR-based parameters reflect functional changes in kidneys with acute kidney injury (AKI) using dynamic contrast enhanced MRI and a two-compartment renal filtration model. MRI data of eight male Lewis rats were analyzed retrospectively. Five animals were subjected to AKI, three native rats served as control. All animals underwent perfusion imaging by dynamic contrast-enhanced MRI. Renal blood volume, glomerular filtration rate (GFR) as well as plasma and tubular mean transit times were estimated from regions-of-interest drawn in the renal cortex. Differences between healthy kidneys and kidneys subjected to AKI were analyzed using a paired t-test. Significant differences between ischemic and healthy kidneys could only be detected for the glomerular filtration rate. For all other calculated parameters, differences were present, however not significant. In rats with AKI, average single kidney GFR was 0.66 ± 0.37 ml/min for contralateral and 0.26 ± 0.12 ml/ min for diseased kidneys (P = 0.0254). For the healthy control group, the average GFR was 0.39 ± 0.06 ml/min and 0.41 ± 0.11 ml/min, respectively. Differences between diseased kidneys of AKI rats and ipsilateral kidneys of the healthy control group were significant (P=0.0381). Significant differences of functional parameters reflecting damage of the renal tissue of kidneys with AKI compared to the contralateral, healthy kidneys could only be detected by GFR. GFR might be a useful parameter that allows for a spatially resolved detection of abnormal changes of renal tissue by AKI.
Tipirneni-Sajja, Aaryani; Loeffler, Ralf B; Oesingmann, Niels; Bissler, John; Song, Ruitian; McCarville, Beth; Jones, Deborah P; Hudson, Melissa; Spunt, Sheri L; Hillenbrand, Claudia M
2016-04-01
Measuring glomerular filtration rate (GFR) by dynamic contrast-enhanced (DCE) magnetic resonance imaging (MRI) as part of standard of care clinicalMRIexams (e.g., in pediatric solid tumor patients) has the potential to reduce diagnostic burden. However, enthusiasm for this relatively newGFRtest may be curbed by the limited amount of cross-calibration studies with referenceGFRtechniques and the vast variety ofMRtracer model algorithms causing confusion on the choice of model. To advanceMRI-basedGFRquantification via improvedGFRmodeling and comparison with associated(99m)Tc-DTPA-GFR, 29 long-term Wilms' tumor survivors (19.0-43.3 years, [median 32.0 ± 6.0 years]) treated with nephrectomy, nonnephrotoxic chemotherapy ± radiotherapy underwentMRIwith Gd-DTPAadministration and a(99m)Tc-DTPA GFRtest. ForDCE-MRI-basedGFRestimation, a subject-specific two-compartment (SS-2C) model was developed that uses individual hematocrit values, automatically defines subject-specific uptake intervals, and fits tracer-uptake curves by incorporating these measures. The association between reference(99m)Tc-DTPA GFRandMR-GFRs obtained bySS-2C, three published 2C uptake, and inflow-outflow models was investigated via linear regression analysis. Uptake intervals varied from 64 sec to 141 sec [96 sec ± 21 sec] and hematocrit values ranged from 30% to 49% [41% ± 4%]; these parameters can therefore not be assumed as constants in 2C modeling. OurMR-GFRestimates using theSS-2C model showed accordingly the highest correlation with(99m)Tc-DTPA-GFRs (R(2) = 0.76,P < 0.001) compared with other models (R(2)-range: 0.36-0.66). In conclusion,SS-2C modeling ofDCE-MRIdata improved the association betweenGFRobtained by(99m)Tc-DTPAand Gd-DTPA DCE-MRIto such a degree that this approach could turn into a viable, diagnosticGFRassay without radiation exposure to the patient.
Institute of Scientific and Technical Information of China (English)
张应云; 张榆锋; 王勇; 李敬敬; 施心陵
2014-01-01
A approach according to the Maximum Likelihood method was presented in this paper to identify the parameters of the Two-compartment Model.To verify the performance of this method, the estimation parameters of the Two-compartment Model ob-tained from it and their absolute errors were compared with those obtained from the methods based on recursive augmented least -squares algorithm.It could be seen that the accuracy and feasibility of the identification-parameters of the nonlinear two-compart-ment model received by Maximum Likelihood method were obviously better than those from the recursive augmented least-squares method.So those parameters with smaller deviations can be used in correlative clinical trial to improve the practicability of the nonlinear two-compartment model.%提出一种基于极大似然法的二房室模型参数辨识方法。为验证本方法的有效性，我们比较了基于极大似然法和递推增广最小二乘法估计得到的常用二房室模型的参数值及其绝对误差。结果表明，基于极大似然法的非线性二房室模型参数辨识准确性和可行性明显优于递推增广最小二乘法。通过极大似然法获得的较小误差的非线性二房室模型参数估计值可用于相关临床试验，有助于提高建立非线性二房室模型的实用性。
Brunner, Matthias; Braun, Philipp; Doppler, Philipp; Posch, Christoph; Behrens, Dirk; Herwig, Christoph; Fricke, Jens
2017-01-12
Due to high mixing times and base addition from top of the vessel, pH inhomogeneities are most likely to occur during large-scale mammalian processes. The goal of this study was to set-up a scale-down model of a 10-12 m(3) stirred tank bioreactor and to investigate the effect of pH perturbations on CHO cell physiology and process performance. Short-term changes in extracellular pH are hypothesized to affect intracellular pH and thus cell physiology. Therefore, batch fermentations, including pH shifts to 9.0 and 7.8, in regular one-compartment systems are conducted. The short-term adaption of the cells intracellular pH are showed an immediate increase due to elevated extracellular pH. With this basis of fundamental knowledge, a two-compartment system is established which is capable of simulating defined pH inhomogeneities. In contrast to state-of-the-art literature, the scale-down model is included parameters (e.g. volume of the inhomogeneous zone) as they might occur during large-scale processes. pH inhomogeneity studies in the two-compartment system are performed with simulation of temporary pH zones of pH 9.0. The specific growth rate especially during the exponential growth phase is strongly affected resulting in a decreased maximum viable cell density and final product titer. The gathered results indicate that even short-term exposure of cells to elevated pH values during large-scale processes can affect cell physiology and overall process performance. In particular, it could be shown for the first time that pH perturbations, which might occur during the early process phase, have to be considered in scale-down models of mammalian processes.
Steinbach, Sarah M L; Sturgess, Christopher P; Dunning, Mark D; Neiger, Reto
2015-06-01
Assessment of renal function by means of plasma clearance of a suitable marker has become standard procedure for estimation of glomerular filtration rate (GFR). Sinistrin, a polyfructan solely cleared by the kidney, is often used for this purpose. Pharmacokinetic modeling using adequate software is necessary to calculate disappearance rate and half-life of sinistrin. The purpose of this study was to describe the use of a Microsoft excel based add-in program to calculate plasma sinistrin clearance, as well as additional pharmacokinetic parameters such as transfer rates (k), half-life (t1/2) and volume of distribution (Vss) for sinistrin in dogs with varying degrees of renal function.
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Tofts, Paul S. [Brighton and Sussex Medical School, Falmer, Sussex (United Kingdom); UCL Institute of Neurology, London (United Kingdom); Cutajar, Marica [Brighton and Sussex Medical School, Falmer, Sussex (United Kingdom); UCL Institute of Child Health, London (United Kingdom); Mendichovszky, Iosif A. [University of Manchester, Imaging Science and Biomedical Engineering, Manchester (United Kingdom); Peters, A.M. [Brighton and Sussex Medical School, Falmer, Sussex (United Kingdom); Gordon, Isky [UCL Institute of Child Health, London (United Kingdom)
2012-06-15
To model the uptake phase of T{sub 1}-weighted DCE-MRI data in normal kidneys and to demonstrate that the fitted physiological parameters correlate with published normal values. The model incorporates delay and broadening of the arterial vascular peak as it appears in the capillary bed, two distinct compartments for renal intravascular and extravascular Gd tracer, and uses a small-vessel haematocrit value of 24%. Four physiological parameters can be estimated: regional filtration K{sup trans} (ml min {sup -1} [ml tissue ]{sup -1}), perfusion F (ml min {sup -1} [100 ml tissue ]{sup -1}), blood volume v{sub b} (%) and mean residence time MRT (s). From these are found the filtration fraction (FF; %) and total GFR (ml min {sup -1}). Fifteen healthy volunteers were imaged twice using oblique coronal slices every 2.5 s to determine the reproducibility. Using parenchymal ROIs, group mean values for renal biomarkers all agreed with published values: K{sup trans}: 0.25; F: 219; v{sub b}: 34; MRT: 5.5; FF: 15; GFR: 115. Nominally cortical ROIs consistently underestimated total filtration (by {proportional_to} 50%). Reproducibility was 7-18%. Sensitivity analysis showed that these fitted parameters are most vulnerable to errors in the fixed parameters kidney T{sub 1}, flip angle, haematocrit and relaxivity. These renal biomarkers can potentially measure renal physiology in diagnosis and treatment. circle Dynamic contrast-enhanced magnetic resonance imaging can measure renal function. circle Filtration and perfusion values in healthy volunteers agree with published normal values. circle Precision measured in healthy volunteers is between 7 and 15%. (orig.)
Energy Technology Data Exchange (ETDEWEB)
Akahira, Hideaki; Takekawa, Shoichi; Nigawara, Kazuo; Funyu, Tomihisa [Oyokyo Kidney Research Inst., Hirosaki, Aomori (Japan). Hirosaki Hospital
1996-12-01
To estimate renal blood flow and glomerular function in transplanted kidneys, we applied the 2 compartment model and the graphic analysis method to {sup 99m}Tc-DTPA dynamic SPECT and calculated some parameters, i.e. K1 (renal influx rate constant), K3 (glomerular filtration rate constant), Vdl (function phase distribution volume), and others. Twenty-three renal transplant recipients were examined and divided into following 3 groups according to their serum creatinine levels (SCr); Group I; less than 1.3 mg/dl (1.1{+-}0.3, n=7), Group II: 1.4-2.5 mg/dl (1.8{+-}0.3, n=7), and Group III more than 2.6 mg/dl (4.8{+-}2.9, n=5). The K3 value became lower in the order of Group I>II>III, and well correlated with blood urea nitrogen (BUN, r=<0.91, P<0.001) and creatinine clearance (Ccr, r=0.87, P<0.001). The K1 value reduced markedly in Group III despite or no difference between Group I and II. Glomerular filtration rate (GFR) derived from K1 and K3 showed a correlation with those by Tauxe`s method. From these results and clinical conditions including histopathological findings, it is suggested that K1, K3 and Vdl are useful paraments of renal central arterial blood flow, renal peripheral arteriolar blood flow and renal {sup 99m}Tc-DTPA uptake function, respectively. (author)
Imperfect pitchfork bifurcation in asymmetric two-compartment granular gas
Institute of Scientific and Technical Information of China (English)
Zhang Yin; Li Yin-Chang; Liu Rui; Cui Fei-Fei; Pierre Evesque; Hou Mei-Ying
2013-01-01
The clustering behavior of a mono-disperse granular gas is experimentally studied in an asymmetric two-compartment setup.Unlike the random clustering in either compartment in the case of symmetric configuration when lowering the shaking strength to below a critical value,the directed clustering is observed,which corresponds to an imperfect pitchfork bifurcation.Numerical solutions of the flux equation using a modified simple flux function show qualitative agreements with the experimental results.The potential application of this asymmetric structure is discussed.
de Jesus, E B; de Andrade Lima, L R P
2016-08-01
Souring of oil fields during secondary oil recovery by water injection occurs mainly due to the action of sulfate-reducing bacteria (SRB) adhered to the rock surface in the vicinity of injection wells. Upflow packed-bed bioreactors have been used in petroleum microbiology because of its similarity to the oil field near the injection wells or production. However, these reactors do not realistically describe the regions near the injection wells, which are characterized by the presence of a saturated zone and a void region close to the well. In this study, the hydrodynamics of the two-compartment packing-free/packed-bed pilot bioreactor that mimics an oil reservoir was studied. The packed-free compartment was modeled using a continuous stirred tank model with mass exchange between active and stagnant zones, whereas the packed-bed compartment was modeled using a piston-dispersion-exchange model. The proposed model adequately represents the hydrodynamic of the packed-free/packed-bed bioreactor while the simulations provide important information about the characteristics of the residence time distribution (RTD) curves for different sets of model parameters. Simulations were performed to represent the control of the sulfate-reducing bacteria activity in the bioreactor with the use of molybdate in different scenarios. The simulations show that increased amounts of molybdate cause an effective inhibition of the souring sulfate-reducing bacteria activity.
The benefit of dividing an indirect thermal storage into two compartments: Discharge experiments
Energy Technology Data Exchange (ETDEWEB)
Ragoonanan, Vishard; Davidson, Jane H.; Mantell, Susan C. [Department of Mechanical Engineering, 111 Church Street, S.E. Minneapolis, MN 55455 (United States); Homan, Kelly O. [Department of Mechanical and Aerospace Engineering, University of Missouri-Rolla, 1870 Miner Circle, Rolla, MO 65409 (United States)
2006-01-15
Experiments are presented to demonstrate the benefits of dividing an indirect thermal storage into two compartments. The transient discharge experiments were conducted in an undivided and equally divided 126l rectangular storage vessel, which has a height to depth aspect ratio of 9.3:1 and is inclined at 30{sup o} to the horizontal. A 240-tube copper heat exchanger with a total surface area of 2.38m{sup 2} was immersed in the storage fluid. For the divided storage, the heat exchanger flow path was in series through the two compartments. Water flow rate through the heat exchanger was varied from 0.05 to 0.15kg/s to demonstrate the effect of varying the number of transfer units (NTU) from 2.2 to 7 on the relative performance of undivided and divided storage vessels. Reported measurements include transient storage temperature distribution, heat exchanger outlet temperature, delivered energy, and exergy of the divided and undivided storage. The divided storage provides higher energy delivery rates and higher heat exchanger outlet temperatures during most of the discharge. The magnitude of these benefits depends on NTU and the extent of discharge. For a flow rate of 0.05kg/s, corresponding to a nominal NTU of 7, the divided storage delivers a maximum of 11% more energy than the undivided storage when 100l of hot water or 55% of the stored energy has been delivered. For a flow rate of 0.15kg/s, corresponding to a nominal NTU of 2.5, the divided storage delivers a maximum of 5% more energy at the same level of discharge. Data agree with first and second law analyses of a storage system comprised of two tanks in series. (author)
46 CFR 171.017 - One and two compartment standards of flooding.
2010-10-01
... 46 Shipping 7 2010-10-01 2010-10-01 false One and two compartment standards of flooding. 171.017... STABILITY SPECIAL RULES PERTAINING TO VESSELS CARRYING PASSENGERS General § 171.017 One and two compartment... standard of flooding if the margin line is not submerged when the total buoyancy between each set of two...
Two-Compartment Photoelectrochemical Reactors Tested under various solar Light Concentration ratios
Energy Technology Data Exchange (ETDEWEB)
Fernandez-Ibanez, P.; Malato, S. [Plataforma Solar de Almeria. CIEMAT (Spain)
1999-07-01
A new type of photo reactor, made of a cylindrical photo anode placed around an inner comportment, has been adapted to the compound parabolic (CPC's) and to the parabolic trough (PTC, Helioman) solar collectors. The photoelectrochemical performances of such two-compartment photo reactors are noticeably improved with respect to those previously obtained with photo reactors having flat photoanodes and a single compartment. The abatement of model pollutants shows up to threefold higher organic oxidation rates compared to Ti O{sub 2} slurries tested in the same experimental conditions. Clearly, charge separation is much better when an external electrochemical bias is applied to Ti/Ti O{sub 2} photoanodes under irradiation. (Author) 8 refs.
Development of a patient-specific two-compartment anthropomorphic breast phantom
Prionas, Nicolas D.; Burkett, George W.; McKenney, Sarah E.; Chen, Lin; Stern, Robin L.; Boone, John M.
2012-07-01
The purpose of this paper is to develop a technique for the construction of a two-compartment anthropomorphic breast phantom specific to an individual patient's pendant breast anatomy. Three-dimensional breast images were acquired on a prototype dedicated breast computed tomography (bCT) scanner as part of an ongoing IRB-approved clinical trial of bCT. The images from the breast of a patient were segmented into adipose and glandular tissue regions and divided into 1.59 mm thick breast sections to correspond to the thickness of polyethylene stock. A computer-controlled water-jet cutting machine was used to cut the outer breast edge and the internal regions corresponding to glandular tissue from the polyethylene. The stack of polyethylene breast segments was encased in a thermoplastic ‘skin’ and filled with water. Water-filled spaces modeled glandular tissue structures and the surrounding polyethylene modeled the adipose tissue compartment. Utility of the phantom was demonstrated by inserting 200 µm microcalcifications as well as by measuring point dose deposition during bCT scanning. Affine registration of the original patient images with bCT images of the phantom showed similar tissue distribution. Linear profiles through the registered images demonstrated a mean coefficient of determination (r2) between grayscale profiles of 0.881. The exponent of the power law describing the anatomical noise power spectrum was identical in the coronal images of the patient's breast and the phantom. Microcalcifications were visualized in the phantom at bCT scanning. The real-time air kerma rate was measured during bCT scanning and fluctuated with breast anatomy. On average, point dose deposition was 7.1% greater than the mean glandular dose. A technique to generate a two-compartment anthropomorphic breast phantom from bCT images has been demonstrated. The phantom is the first, to our knowledge, to accurately model the uncompressed pendant breast and the glandular tissue
Collagen/chitosan based two-compartment and bi-functional dermal scaffolds for skin regeneration
Energy Technology Data Exchange (ETDEWEB)
Wang, Feng [Department of Plastic Surgery and Burns, Shenzhen Second People' s Hospital, Shenzhen 518035 (China); Wang, Mingbo [Key Laboratory of Biomedical Materials and Implants, Research Institute of Tsinghua University in Shenzhen, Shenzhen 518057 (China); She, Zhending [Key Laboratory of Biomedical Materials and Implants, Research Institute of Tsinghua University in Shenzhen, Shenzhen 518057 (China); Shenzhen Lando Biomaterials Co., Ltd., Shenzhen 518057 (China); Fan, Kunwu; Xu, Cheng [Department of Plastic Surgery and Burns, Shenzhen Second People' s Hospital, Shenzhen 518035 (China); Chu, Bin; Chen, Changsheng [Key Laboratory of Biomedical Materials and Implants, Research Institute of Tsinghua University in Shenzhen, Shenzhen 518057 (China); Shi, Shengjun, E-mail: shengjunshi@yahoo.com [The Burns Department of Zhujiang Hospital, Southern Medical University, Guangzhou 510280 (China); Tan, Rongwei, E-mail: tanrw@landobiom.com [Key Laboratory of Biomedical Materials and Implants, Research Institute of Tsinghua University in Shenzhen, Shenzhen 518057 (China); Shenzhen Lando Biomaterials Co., Ltd., Shenzhen 518057 (China)
2015-07-01
Inspired from the sophisticated bilayer structures of natural dermis, here, we reported collagen/chitosan based two-compartment and bi-functional dermal scaffolds. Two functions refer to mediating rapid angiogenesis based on recombinant human vascular endothelial growth factor (rhVEGF) and antibacterial from gentamicin, which were encapsulated in PLGA microspheres. The gentamicin and rhVEGF encapsulated PLGA microspheres were further combined with collagen/chitosan mixtures in low (lower layer) and high (upper layer) concentrations, and molded to generate the two-compartment and bi-functional scaffolds. Based on morphology and pore structure analyses, it was found that the scaffold has a distinct double layered porous and connective structure with PLGA microspheres encapsulated. Statistical analysis indicated that the pores in the upper layer and in the lower layer have great variations in diameter, indicative of a two-compartment structure. The release profiles of gentamicin and rhVEGF exceeded 28 and 49 days, respectively. In vitro culture of mouse fibroblasts showed that the scaffold can facilitate cell adhesion and proliferation. Moreover, the scaffold can obviously inhibit proliferation of Staphylococcus aureus and Serratia marcescens, exhibiting its unique antibacterial effect. The two-compartment and bi-functional dermal scaffolds can be a promising candidate for skin regeneration. - Highlights: • The dermal scaffold is inspired from the bilayer structures of natural dermis. • The dermal scaffold has two-compartment structures. • The dermal scaffold containing VEGF and gentamicin encapsulated PLGA microspheres • The dermal scaffold can facilitate cell adhesion and proliferation.
Minimum energy control for a two-compartment neuron to extracellular electric fields
Yi, Guo-Sheng; Wang, Jiang; Li, Hui-Yan; Wei, Xi-Le; Deng, Bin
2016-11-01
The energy optimization of extracellular electric field (EF) stimulus for a neuron is considered in this paper. We employ the optimal control theory to design a low energy EF input for a reduced two-compartment model. It works by driving the neuron to closely track a prescriptive spike train. A cost function is introduced to balance the contradictory objectives, i.e., tracking errors and EF stimulus energy. By using the calculus of variations, we transform the minimization of cost function to a six-dimensional two-point boundary value problem (BVP). Through solving the obtained BVP in the cases of three fundamental bifurcations, it is shown that the control method is able to provide an optimal EF stimulus of reduced energy for the neuron to effectively track a prescriptive spike train. Further, the feasibility of the adopted method is interpreted from the point of view of the biophysical basis of spike initiation. These investigations are conducive to designing stimulating dose for extracellular neural stimulation, which are also helpful to interpret the effects of extracellular field on neural activity.
Anisotropic exchange-interaction model: From the Potts model to the exchange-interaction model
King, T. C.; Chen, H. H.
1995-04-01
A spin model called the anisotropic exchange-interaction model is proposed. The Potts model, the exchange-interaction model, and the spin-1/2 anisotropic Heisenberg model are special cases of the proposed model. Thermodynamic properties of the model on the bcc and the fcc lattices are determined by the constant-coupling approximation.
A simple nonlocal model for exchange.
Janesko, Benjamin G
2009-12-21
This work presents a new nonlocal model for the exchange energy density. The model is obtained from the product of the Kohn-Sham one-particle density matrix used to construct exact [Hartree-Fock-like (HF)] exchange, and an approximate density matrix used to construct local spin-density approximation (LSDA) exchange. The proposed exchange energy density has useful formal properties, including correct spin and coordinate scaling and the correct uniform limit. It can readily be evaluated in finite basis sets, with a computational scaling intermediate between HF exchange and semilocal quantities such as the noninteracting kinetic energy density. Applications to representative systems indicate that its properties are typically intermediate between HF and LSDA exchange, and often similar to global hybrids of HF and LSDA exchange. The model is proposed as a novel "Rung 3.5" ingredient for constructing approximate exchange-correlation functionals.
Wealth Distributions in Asset Exchange Models
Krapivsky, P L
2010-01-01
How do individuals accumulate wealth as they interact economically? We outline the consequences of a simple microscopic model in which repeated pairwise exchanges of assets between individuals build the wealth distribution of a population. This distribution is determined for generic exchange rules --- transactions that involve a fixed amount or a fixed fraction of individual wealth, as well as random or greedy exchanges. In greedy multiplicative exchange, a continuously evolving power law wealth distribution arises, a feature that qualitatively mimics empirical observations.
Vidal Melo, M. F.; Loeppky, J. A.; Caprihan, A.; Luft, U. C.
1993-01-01
This study describes a two-compartment model of pulmonary gas exchange in which alveolar ventilation to perfusion (VA/Q) heterogeneity and impairment of pulmonary diffusing capacity (D) are simultaneously taken into account. The mathematical model uses as input data measurements usually obtained in the lung function laboratory. It consists of two compartments and an anatomical shunt. Each compartment receives fractions of alveolar ventilation and blood flow. Mass balance equations and integration of Fick's law of diffusion are used to compute alveolar and blood O2 and CO2 values compatible with input O2 uptake and CO2 elimination. Two applications are presented. The first is a method to partition O2 and CO2 alveolar-arterial gradients into VA/Q and D components. The technique is evaluated in data of patients with chronic obstructive pulmonary disease (COPD). The second is a theoretical analysis of the effects of blood flow variation in alveolar and blood O2 partial pressures. The results show the importance of simultaneous consideration of D to estimate VA/Q heterogeneity in patients with diffusion impairment. This factor plays an increasing role in gas alveolar-arterial gradients as severity of COPD increases. Association of VA/Q heterogeneity and D may produce an increase of O2 arterial pressure with decreasing QT which would not be observed if only D were considered. We conclude that the presented computer model is a useful tool for description and interpretation of data from COPD patients and for performing theoretical analysis of variables involved in the gas exchange process.
Edge exchangeable models for network data
Crane, Harry
2016-01-01
Exchangeable models for vertex labeled graphs cannot replicate the large sample behaviors of sparsity and power law degree distributions observed in many network datasets. Out of this mathematical impossibility emerges the question of how network data can be modeled in a way that reflects known empirical behaviors and respects basic statistical principles. We address this question by observing that edges, not vertices, act as the statistical units in most network datasets, making a theory of edge labeled networks more natural for most applications. Within this context we introduce the new invariance principle of {\\em edge exchangeability}, which unlike its vertex exchangeable counterpart can produce networks with sparse and/or power law structure. We characterize the class of all edge exchangeable network models and identify a particular two parameter family of models with suitable theoretical properties for statistical inference. We discuss issues of estimation from edge exchangeable models and compare our a...
A two-compartment phantom for VOI profile measurements in small-bore 31P MR spectroscopy
DEFF Research Database (Denmark)
Vikhoff, Babro; Stubgaard, Max; Stensgaard, Anders
1998-01-01
A two-compartment gel phantom for VOI profile measurements in volume-selective 31P spectroscopy in small-bore units is presented. The phantom is cylindrical with two compartments divided by a very thin (30 microm) polyethene film. This thin film permits measurements with a minimum of susceptibility...... from the two compartments was measured for each position and the data were evaluated following differentiation. We have found this phantom suitable for VOI profile measurements of ISIS in small-bore systems. The phantom forms a useful complement to recommended phantoms for small bore-spectroscopy...
Energy Technology Data Exchange (ETDEWEB)
Salmon, E.; Brooks, D.J.; Leenders, K.L.; Turton, D.R.; Hume, S.P.; Cremer, J.E.; Jones, T.; Frackowiak, R.S. (Hammersmith Hospital, London (England))
1990-05-01
S-(11C)Nomifensine (S-(11C)NMF) is a positron-emitting tracer suitable for positron emission tomography, which binds to both dopaminergic and noradrenergic reuptake sites in the striatum and the thalamus. Modelling of the cerebral distribution of this drug has been hampered by the rapid appearance of glucuronide metabolites in the plasma, which do not cross the blood--brain barrier. To date, (11C)NMF uptake has simply been expressed as regional versus nonspecific cerebellar activity ratios. We have calculated a free NMF input curve from red cell activity curves, using the fact that the free drug rapidly equilibrates between red cells and plasma, while glucuronides do not enter red cells. With this free (11C)NMF input function, all regional cerebral uptake curves could be fitted to a conventional two-compartment model, defining tracer distribution in terms of (11C)NMF regional volume of distribution. Assuming that the cerebellar volume of distribution of (11C)NMF represents the nonspecific volume of distribution of the tracer in striatum and thalamus, we have calculated an equilibrium partition coefficient for (11C)NMF between freely exchanging specific and nonspecific compartments in these regions, representing its binding potential to dopaminergic or noradrenergic uptake sites (or complexes). This partition coefficient was lower in the striatum when the racemate rather than the active S-enantiomer of (11C)NMF was administered. In the striatum of patients suffering from Parkinson's disease and multiple-system atrophy, the specific compartmentation of S-(11C)NMF was significantly decreased compared with that of age-matched volunteers.
A formal model of fair exchange protocols
Institute of Scientific and Technical Information of China (English)
QING Sihan; LI Gaicheng
2005-01-01
Based on the study of existing fair exchange protocols, this paper sets up an accurate formal model by stepwise refinement. In the process of refinement an unreliable channel is employed to simulate an attack behavior. The model provides a novel formal definition of exchanged items, and presents the formal goals for fairness, accountability,etc., reflecting the inherent requirements for fair exchange protocols across-the-board. In order to check, prove, and design fair exchange protocols effectively and efficiently, the model puts forward a novel property of abuse-freeness which applies to all fair exchange protocols, gives a formal definition for trust strand of the third party, and presents general criteria of designing a secure and effective fair exchange protocol. Taking a typical fair exchange protocol as an example, this paper presents the analysis steps of fair exchange protocols appealing to our model. An unknown attack is uncovered. The analysis reveals the process of a complete attack, discovering deeper reasons for causing an attack.Finally, we modify the flawed protocol and the revised protocol ensures the desirable properties.
Fragmentary model of exchange interactions
Kotov, V M
2000-01-01
This article makes attempt to refusal from using neutrino for explanation continuous distribution of beta particle energy by conversion to characteristic exchange interaction particles in nucleolus. It is taking formulation for nuclear position with many different fragments. It is computing half-value period of spontaneous fission of heavy nucleolus. (author)
Kinetic exchange models for social opinion formation
Lallouache, Mehdi; Chakrabarti, Bikas K
2010-01-01
We propose a minimal model for the collective dynamics of opinion formation in the society, by modifying kinetic exchange dynamics studied in the context of income, money or wealth distributions in a society.
SPEEDUP{trademark} ion exchange column model
Energy Technology Data Exchange (ETDEWEB)
Hang, T.
2000-03-06
A transient model to describe the process of loading a solute onto the granular fixed bed in an ion exchange (IX) column has been developed using the SpeedUp{trademark} software package. SpeedUp offers the advantage of smooth integration into other existing SpeedUp flowsheet models. The mathematical algorithm of a porous particle diffusion model was adopted to account for convection, axial dispersion, film mass transfer, and pore diffusion. The method of orthogonal collocation on finite elements was employed to solve the governing transport equations. The model allows the use of a non-linear Langmuir isotherm based on an effective binary ionic exchange process. The SpeedUp column model was tested by comparing to the analytical solutions of three transport problems from the ion exchange literature. In addition, a sample calculation of a train of three crystalline silicotitanate (CST) IX columns in series was made using both the SpeedUp model and Purdue University's VERSE-LC code. All test cases showed excellent agreement between the SpeedUp model results and the test data. The model can be readily used for SuperLig{trademark} ion exchange resins, once the experimental data are complete.
DEFF Research Database (Denmark)
Nakayama, Ryo-ichi; Imai, Masanao; Woodley, John
2017-01-01
a an original two-compartment reactor. The reactor was composed of a mechanically stirred compartment (ST) and ultrasound irradiation compartment (US). The reaction solution was recirculated between the ST and the US. The enzyme was only exposed by ultrasonication in the US. The reactor system has the option...
Modeling foreign exchange risk premium in Armenia
Poghosyan, Tigran; Kocenda, Evnen; Zemcik, Petr
2008-01-01
This paper applies stochastic discount factor methodology to modeling the foreign exchange risk premium in Armenia. We use weekly data on foreign and domestic currency deposits, which coexist in the Armenian banking system. This coexistence implies elimination of the cross-country risks and transact
Two-Compartment Model as a Teaching Tool for Cholesterol Homeostasis
Wrona, Artur; Balbus, Joanna; Hrydziuszko, Olga; Kubica, Krystian
2015-01-01
Cholesterol is a vital structural and functional molecule in the human body that is only slightly soluble in water and therefore does not easily travels by itself in the bloodstream. To enable cholesterol's targeted delivery to cells and tissues, it is encapsulated by different fractions of lipoproteins, complex particles containing both proteins…
ECONOMETRIC MODELS FOR DETERMING THE EXCHANGE RATE
Directory of Open Access Journals (Sweden)
Mihaela BRATU
2012-05-01
Full Text Available The simple econometric models for the exchange rate, according to recent researches, generates the forecasts with the highest degree of accuracy. This type of models (Simultaneous Equations Model, MA(1 Procedure, Model with lagged variables is used to describe the evolution of the average exchange rate in Romanian in January 1991-March 2012 and to predict it on short run. The best forecasts, in terms of accuracy, on the forecasting horizon April-May 2012 were those based on a Simultaneous Equations Model that takes into account the Granger causality. An almost high degree of accuracy was gotten by combining the predictions based on MA(1 model with those based on the simultaneous equations model, when INV weighting scheme was applied (the forecasts are inversely weighted to their relative mean squared forecast error. The lagged variables Model provided the highest prediction errors. The importance of knowing the best exchange rate forecasts is related to the improvement of decision-making and the building of the monetary policy.
Mathematical Modeling of Spiral Heat Exchanger
Directory of Open Access Journals (Sweden)
Probal Guha , Vaishnavi Unde
2014-04-01
Full Text Available Compact Heat Exchangers (CHEs are increasingly being used on small and medium scale industries. Due to their compact size and efficient design, they facilitate more efficient heat transfer. Better heat transfer would imply lesser fuel consumption for the operations of the plant, giving improvement to overall efficiency. This reduction in consumption of fuel is a step towards sustainable development. This report exclusively deals with the study the spiral heat exchanger.The design considerations for spiral heat exchanger is that the flow within the spiral has been assumed as flow through a duct and by using Shah London empirical equation for Nusselt number design parameters are further optimized.This is accompanied by a detailed energy balance to generate a concise mathematical model
Community structure at two compartments of a disturbed mangrove forests at Pulau Langkawi
Norilani, W. I. Wan; Juliana, W. A. Wan; Salam, Muhamad Razali; Latiff, A.
2014-09-01
A study on floristic composition and estimation of above ground biomass of trees was carried out in two areas of disturbed mangroves at Kisap Forest Reserve, Pulau Langkawi. Two compartments that were selected was based on the different types of disturbances, i.e. compartment 5 (C5) was disrupted by human harvesting activities of mangrove trees for charcoal production, while compartment 7 (C7) was naturally disturbed from lightning strikes. In C5, a total of 1,217 trees measuring 1 cm DBH and above were enumerated in the plots of 0.25 ha which included 7 species and 5 genera in 3 families, i.e. Rhizophoraceae, Meliaceae and Avicenniaceae. In C7, a total of 390 individual trees of 8 species, 5 genera and 3 families were recorded. The three families recorded in C7 were also common in C5. Rhizophoraceae was recorded as the family with highest density in both compartments. Ceriops tagal had the highest density in C5, while Rhizophora apiculata was the most prominent species in the C7. Total basal area that represents tree coverage showed C5 had a value of 7.767 m2/ha with C. tagal as the major contributor at 5.022m2/ha. Total coverage in C7 was 18.184 m2/ha that was mostly contributed by R. apiculata at 11.135 m2/ha. Ceriops tagal (22.41 t/ha) and R. apiculata (111.75 t/ha), were the main contributors to the total biomass in C5 (37.34 t/ha) and C7 (162.29 t/ha), respectively. The distribution of individuals of six tree size classes in C7 was homogenous compared to that of C5, which had more saplings. In this study, the total biomass indicated that anthropogenic activities resulted in lower productivity of forest compared to natural disturbance. Therefore, conservation efforts of mangrove forest should be enhance in the management of mangrove forest in Pulau Langkawi.
Salem, Ahmed F; Whitaker-Menezes, Diana; Lin, Zhao; Martinez-Outschoorn, Ubaldo E; Tanowitz, Herbert B; Al-Zoubi, Mazhar Salim; Howell, Anthony; Pestell, Richard G; Sotgia, Federica; Lisanti, Michael P
2012-07-01
Previously, we proposed a new paradigm to explain the compartment-specific role of autophagy in tumor metabolism. In this model, autophagy and mitochondrial dysfunction in the tumor stroma promotes cellular catabolism, which results in the production of recycled nutrients. These chemical building blocks and high-energy "fuels" would then drive the anabolic growth of tumors, via autophagy resistance and oxidative mitochondrial metabolism in cancer cells. We have termed this new form of stromal-epithelial metabolic coupling: "two-compartment tumor metabolism." Here, we stringently tested this energy-transfer hypothesis, by genetically creating (1) constitutively autophagic fibroblasts, with mitochondrial dysfunction or (2) autophagy-resistant cancer cells, with increased mitochondrial function. Autophagic fibroblasts were generated by stably overexpressing key target genes that lead to AMP-kinase activation, such as DRAM and LKB1. Autophagy-resistant cancer cells were derived by overexpressing GOLPH3, which functionally promotes mitochondrial biogenesis. As predicted, DRAM and LKB1 overexpressing fibroblasts were constitutively autophagic and effectively promoted tumor growth. We validated that autophagic fibroblasts showed mitochondrial dysfunction, with increased production of mitochondrial fuels (L-lactate and ketone body accumulation). Conversely, GOLPH3 overexpressing breast cancer cells were autophagy-resistant, and showed signs of increased mitochondrial biogenesis and function, which resulted in increased tumor growth. Thus, autophagy in the tumor stroma and oxidative mitochondrial metabolism (OXPHOS) in cancer cells can both dramatically promote tumor growth, independently of tumor angiogenesis. For the first time, our current studies also link the DNA damage response in the tumor microenvironment with "Warburg-like" cancer metabolism, as DRAM is a DNA damage/repair target gene.
Ion exchange model for α phase proton exchange waveguide in LiNbO3
DEFF Research Database (Denmark)
Veng, Torben Erik; Skettrup, Torben
1998-01-01
An H+/Li+ exchange model is found to be applicable to describe the diffusion of protons when optical waveguides are formed in LiNbO3 by proton exchange methods where the proton doped crystal structure stays in the pure α phase. The H + and Li+ self-diffusion coefficients in the ion exchange model...
Qi, Xu; Shao, Ming; Peng, Haisheng; Bi, Zhenggang; Su, Zhiqiang; Li, Hulun
2010-07-01
This study was performed to establish a bone marrow stromal cell (BMSC)/neuron two-compartment co-culture model in which differentiation of BMSCs into neurons could occur without direct contact between the two cell types, and to investigate protein expression changes during differentiation of this entirely BMSC-derived population. Cultured BMSCs isolated from Wistar rats were divided into three groups: BMSC culture, BMSC/neuron co-culture and BMSC/neuron two-compartment co-culture. Cells were examined for neuron-specific enolase (NSE) and glial fibrillary acidic protein (GFAP) expression. The electrophysiological behavior of the BMSCs was examined using patch clamping. Proteins that had significantly different expression levels in BMSCs cultured alone and co-cultured with neurons were studied using a protein chip-mass spectroscopy technique. Expression of NSE and GFAP were significantly higher in co-culture cells than in two-compartment co-culture cells, and significantly higher in both co-culture groups than in BMSCs cultured alone. Five proteins showed significant changes in expression during differentiation: TIP39_RAT and CALC_RAT underwent increases, and INSL6_RAT, PNOC_RAT and PCSK1_RAT underwent decreases in expression. We conclude that BMSCs can differentiate into neurons during both contact co-culture with neurons and two-compartment co-culture with neurons. The rate at which BMSCs differentiated into neurons was higher in contact co-culture than in non-contact co-culture.
Modelling Heat Exchangers for Domestic Boilers
Directory of Open Access Journals (Sweden)
S. F. C. F. Teixeira
2000-01-01
Full Text Available In the present paper the thermal behaviour of fin-tube heat exchangers is modeled. Particular attention has been given to the plate fins. The heat fluxes in the fins are described using a finite volume technique to discretize the energy equation. The thermal interactions with the water in the tubes and the surrounding air are treated as external boundaries, using appropriate relationships for forced convection in pipes and flat plates. The numerical results are presented in terms of dimensionless numbers (Fourier, Biot and geometric ratios which are found to be representative for this particular geometry. Furthermore, the effect of thermal gradients along the fin surface upon the fin efficiency is investigated. Based on a differential model for the heat balances, design charts have been developed for the thermal analysis of heat exchangers.
Forecasting Exchange Rates with Mixed Models
Directory of Open Access Journals (Sweden)
Laura Maria Badea
2013-06-01
Full Text Available Gaining accuracy in exchange rate forecasting applications provides true benefits for financial activities. Supported today by the advancements in computing power, machine learning techniques provide good alternatives to traditional time series estimation methods. Very approached in time series forecasting are Artificial Neural Networks (ANNs which offer robust results and allow a flexible data manipulation. When integrating both, the “white-box” feature of conventional methods and the complexity of machine learning techniques, forecasting models perform even better in terms of generated errors. In this study, input variables (independent variables are selected using an ARIMA technique and are further employed in differently configured multilayered feed-forward neural networks using Broyden-Fletcher-Goldfarb-Shanno (BFGS optimization algorithm to perform predictions on EUR/RON and CHF/RON exchange rates. Results in terms of mean squared error highlight good results when using mixed models.
Multidimensional numerical modeling of heat exchangers
Sha, W. T.; Yang, C. I.; Kao, T. T.; Cho, S. M.
A comprehensive, multidimensional, thermal-hydraulic model is developed for the analysis of shell-and-tube heat exchangers for liquid-metal services. For the shellside fluid, the conservation equations of mass, momentum, and energy for continuum fluids are modified using the concept of porosity, surface permeability and distributed resistance to account for the blockage effects due to the presence of heat-transfer tubes, flow baffles/shrouds, the support plates, etc. On the tubeside, the heat-transfer tubes are connected in parallel between the inlet and outlet plenums, and tubeside flow distribution is calculated based on the plenum-to-plenum pressure difference being equal for all tubes. It is assumed that the fluid remains single-phase on the shell side and may undergo phase-change on the tube side, thereby simulating the conditions of Liquid Metal Fast Breeder Reactor (LMFBR) intermediate heat exchangers (IHX) and steam generators (SG).
Forecasting the Euro exchange rate using vector error correction models
Aarle, B. van; Bos, M.; Hlouskova, J.
2000-01-01
Forecasting the Euro Exchange Rate Using Vector Error Correction Models. — This paper presents an exchange rate model for the Euro exchange rates of four major currencies, namely the US dollar, the British pound, the Japanese yen and the Swiss franc. The model is based on the monetary approach of ex
Jiang, N; Shelley, J D; Smith, Robin
2014-01-01
The retrofit of heat exchanger networks requires detailed models of the heat exchangers for the detailed assessment of network performance. Network retrofit options include heat transfer enhancement. There is thus a requirement for detailed models of heat exchanger performance, including heat transfer enhancement, suitable for inclusion in network retrofit optimization algorithms. Such models must be robust, computationally efficient and accurate enough to reflect the heat transfer and pressu...
Modeling the Volatility of Exchange Rates: GARCH Models
Directory of Open Access Journals (Sweden)
Fahima Charef
2017-03-01
Full Text Available The modeling of the dynamics of the exchange rate at a long time remains a financial and economic research center. In our research we tried to study the relationship between the evolution of exchange rates and macroeconomic fundamentals. Our empirical study is based on a series of exchange rates for the Tunisian dinar against three currencies of major trading partners (dollar, euro, yen and fundamentals (the terms of trade, the inflation rate, the interest rate differential, of monthly data, from jan 2000 to dec-2014, for the case of the Tunisia. We have adopted models of conditional heteroscedasticity (ARCH, GARCH, EGARCH, TGARCH. The results indicate that there is a partial relationship between the evolution of the Tunisian dinar exchange rates and macroeconomic variables.
Asset pricing model selection: Indonesian Stock Exchange
Pasaribu, Rowland Bismark Fernando
2010-01-01
The Capital Asset Pricing Model (CAPM) has dominated finance theory for over thirty years; it suggests that the market beta alone is sufficient to explain stock returns. However evidence shows that the cross-section of stock returns cannot be described solely by the one-factor CAPM. Therefore, the idea is to add other factors in order to complete the beta in explaining the price movements in the stock exchange. The Arbitrage Pricing Theory (APT) has been proposed as the first multifactor succ...
STEP - Product Model Data Sharing and Exchange
DEFF Research Database (Denmark)
Kroszynski, Uri
1998-01-01
- Product Data Representation and Exchange", featuring at present some 30 released parts, and growing continuously. Many of the parts are Application Protocols (AP). This article presents an overview of STEP, based upon years of involvement in three ESPRIT projects, which contributed to the development......During the last fifteen years, a very large effort to standardize the product models employed in product design, manufacturing and other life-cycle phases has been undertaken. This effort has the acronym STEP, and resulted in the International Standard ISO-10303 "Industrial Automation Systems...
A Model for Trading the Foreign Exchange Market | Nwokorie | West ...
African Journals Online (AJOL)
A Model for Trading the Foreign Exchange Market. ... interest rates, inflation rates, etc. have significant impacts on the exchange rate fluctuation. Existing ... The predictions from the networks are integrated to get the direction of price movement.
DEFF Research Database (Denmark)
Ottosen, Lisbeth M.; Jensen, Pernille Erland; Kirkelund, Gunvor Marie
2016-01-01
was suspended in water in the anolyte, which was separated from the catholyte by a cation exchange membrane. Electrolysis at the anode acidified the SSA suspension, and hereby P, Cu, Pb, Cd and Zn were extracted. The heavy metal ions electromigrated into the catholyte and were thus separated from the filtrate...... with P. More than 95% P was extracted from both SSAs. The charge transfer to obtain this varied when treating the two SSAs, and for one ash it was about 30% higher than for the other as a result of a higher buffering capacity against acidification. The repeatability of EDS results between experiments...... with the same SSA and the same experimental conditions was good, which shows that the process is easy to control at the studied laboratory conditions. About 80% P and 10% of the heavy metals remained in the filtrate from the anolyte after treatment of both SSAs. The heavy metal content relative to P...
Extended Goldstone-boson-exchange constituent quark model
Wagenbrunn, R F; Plessas, W; Varga, K
2000-01-01
We discuss an updated version of the Goldstone-boson-exchange chiral quark model extended to include in addition to pseudoscalar meson exchanges also vector and scalar meson exchanges. The latter ingredients are viewed as effective parametrizations of multiple Goldstone-boson exchanges in baryons. The extended model allows for an accurate description of all light and strange baryon spectra and at the same time produces the right properties for deducing baryon-baryon interactions.
Lorantfy, Bettina; Jazini, Mohammadhadi; Herwig, Christoph
2013-09-01
Inhomogeneities in production-scale bioreactors influence microbial growth and product quality due to insufficient mixing and mass transfer. For this reason, lots of efforts are being made to investigate the effects of gradients that impose stress in large-scale reactors in laboratory scale. We have implemented a scale-down model which allows separating a homogeneous part, a stirred tank reactor (STR), and a plug flow reactor (PFR) which mimics the inhomogeneous regimes of the large-scale fermenters. This scale-down model shows solutions to trigger oxygen limited conditions in the PFR part of the scale-down setup for physiological analysis. The goal of the study was to investigate the scale-up relevant physiological responses of Pichia pastoris strain to oxygen limited process conditions in the above mentioned two-compartment bioreactor setup. Experimental results with non-induced cultures show that the specific growth rate significantly decreased with increasing the exposure time to oxygen limitation. In parallel more by-products were produced. Examining physiological scalable key parameters, multivariate data analyses solely using on-line data revealed that different exposures to the oxygen limitation significantly affected the culture performance. This work with the small scale-downs setup reflects new approaches for a valuable process development tool for accelerating strain characterization or for verifying CFD simulations of large-scale bioreactors. As a novel methodological achievement, the combination of the two-compartment scale-down system with the proposed multivariate techniques of solely using on-line data is a valuable tool for recognition of stress effects on the culture performance for physiological bioprocess scale-up issues.
Model Uncertainty and Exchange Rate Forecasting
Kouwenberg, Roy; Markiewicz, Agnieszka; Verhoeks, Ralph; Zwinkels, Remco
2013-01-01
textabstractWe propose a theoretical framework of exchange rate behavior where investors focus on a subset of economic fundamentals. We find that any adjustment in the set of predictors used by investors leads to changes in the relation between the exchange rate and fundamentals. We test the validity of this framework via a backward elimination rule which captures the current set of fundamentals that best predicts the exchange rate. Out-of-sample forecasting tests show that the backward elimi...
Model Uncertainty and Exchange Rate Forecasting
R.R.P. Kouwenberg (Roy); A. Markiewicz (Agnieszka); R. Verhoeks (Ralph); R.C.J. Zwinkels (Remco)
2013-01-01
textabstractWe propose a theoretical framework of exchange rate behavior where investors focus on a subset of economic fundamentals. We find that any adjustment in the set of predictors used by investors leads to changes in the relation between the exchange rate and fundamentals. We test the validit
Modeling And Forecasting Exchange-Rate Shocks
Andreou, A. S.; Zombanakis, George A.; Likothanassis, S. D.; Georgakopoulos, E.
1998-01-01
This paper considers the extent to which the application of neural networks methodology can be used in order to forecast exchange-rate shocks. Four major foreign currency exchange rates against the Greek Drachma as well as the overnight interest rate in the Greek market are employed in an attempt to predict the extent to which the local currency may be suffering an attack. The forecasting is extended to the estimation of future exchange rates and interest rates. The MLP proved to be highly ...
Factor Model Forecasts of Exchange Rates
Charles Engel; Nelson C. Mark; Kenneth D. West
2012-01-01
We construct factors from a cross section of exchange rates and use the idiosyncratic deviations from the factors to forecast. In a stylized data generating process, we show that such forecasts can be effective even if there is essentially no serial correlation in the univariate exchange rate processes. We apply the technique to a panel of bilateral U.S. dollar rates against 17 OECD countries. We forecast using factors, and using factors combined with any of fundamentals suggested by Taylor r...
Modeling Philippine Stock Exchange Composite Index Using Time Series Analysis
Gayo, W. S.; Urrutia, J. D.; Temple, J. M. F.; Sandoval, J. R. D.; Sanglay, J. E. A.
2015-06-01
This study was conducted to develop a time series model of the Philippine Stock Exchange Composite Index and its volatility using the finite mixture of ARIMA model with conditional variance equations such as ARCH, GARCH, EG ARCH, TARCH and PARCH models. Also, the study aimed to find out the reason behind the behaviorof PSEi, that is, which of the economic variables - Consumer Price Index, crude oil price, foreign exchange rate, gold price, interest rate, money supply, price-earnings ratio, Producers’ Price Index and terms of trade - can be used in projecting future values of PSEi and this was examined using Granger Causality Test. The findings showed that the best time series model for Philippine Stock Exchange Composite index is ARIMA(1,1,5) - ARCH(1). Also, Consumer Price Index, crude oil price and foreign exchange rate are factors concluded to Granger cause Philippine Stock Exchange Composite Index.
Modeling of Crystalline Silicotitanate Ion Exchange Columns
Energy Technology Data Exchange (ETDEWEB)
Walker, D.D.
1999-03-09
Non-elutable ion exchange is being considered as a potential replacement for the In-Tank Precipitation process for removing cesium from Savannah River Site (SRS) radioactive waste. Crystalline silicotitanate (CST) particles are the reference ion exchange medium for the process. A major factor in the construction cost of this process is the size of the ion exchange column required to meet product specifications for decontaminated waste. To validate SRS column sizing calculations, SRS subcontracted two reknowned experts in this field to perform similar calculations: Professor R. G. Anthony, Department of Chemical Engineering, Texas A&038;M University, and Professor S. W. Wang, Department of Chemical Engineering, Purdue University. The appendices of this document contain reports from the two subcontractors. Definition of the design problem came through several meetings and conference calls between the participants and SRS personnel over the past few months. This document summarizes the problem definition and results from the two reports.
Rasch models with exchangeable rows and columns
DEFF Research Database (Denmark)
Lauritzen, Steffen Lilholt
The article studies distributions of doubly infinite binary matrices with exchangeable rows and columns which satify the further property that the probability of any $m \\times n$ submatrix is a function of the row- and column sums of that matrix. We show that any such distribution is a (unique...... of existence of measures with given marginals....
Real Exchange Rate and Commodity Prices in a Neoclassical Model
Reinhart, Carmen
1988-01-01
This paper represents a neoclassical model that explains the observed empirical relationship between government spending and world commodity supplies and the real exchange rate and real commodity prices. It is shown that fiscal expansion and increasing world commodity supplies simultaneously lead to an appreciation of the real exchange rate and a decline in relative commodity prices. The structural model is estimated and its forecasting performance is compared to a variety of models. We fin...
Giacomini, Arianna; Chiodelli, Paola; Matarazzo, Sara; Rusnati, Marco; Presta, Marco; Ronca, Roberto
2016-05-01
Fibroblast growth factors (FGFs) are a family of pleiotropic factors produced by stromal and parenchymal tumor cells. Even though FGFs have been firstly characterized as angiogenic factors, they exert autocrine and paracrine functions not only on endothelial cells but also on tumor cells and other stromal components. Thus, the FGF/FGF receptor (FGFR) pathway may represent a key player in tumor growth by regulating the complex cross-talk between stromal and tumor compartments. The ligand dependent or independent activation of the FGF/FGFR system by gene upregulation, oncogenic mutation or amplification occurs in a variety of human tumors and is implicated in various key steps of tumor growth and progression. In addition, FGF/FGFR activation has been described as a mechanism of tumor escape in response to antiangiogenic/anti-VEGF therapies. Experimental and clinical evidences provide a compelling biologic rationale for the development of anti-FGF/FGFR targeting agents in cancer therapy. However, the development of drugs specifically targeting the FGF/FGFR pathway proved to be difficult, also due to the high redundancy and pleiotropic effects of FGF and FGFR family members. On the other hand, the possibility to develop "two-compartment" targeting agents endowed with both antiangiogenic and antitumor activities remains promising. Here we will review the preclinical and clinical approaches and potential therapeutics currently available to block the FGF/FGFR system in human cancer.
Energy Technology Data Exchange (ETDEWEB)
Boltz, J.C. (ed.)
1992-09-01
EXCHANGE is published monthly by the Idaho National Engineering Laboratory (INEL), a multidisciplinary facility operated for the US Department of Energy (DOE). The purpose of EXCHANGE is to inform computer users about about recent changes and innovations in both the mainframe and personal computer environments and how these changes can affect work being performed at DOE facilities.
Mathematical Modeling of Spiral Heat Exchanger
Probal Guha , Vaishnavi Unde
2014-01-01
Compact Heat Exchangers (CHEs) are increasingly being used on small and medium scale industries. Due to their compact size and efficient design, they facilitate more efficient heat transfer. Better heat transfer would imply lesser fuel consumption for the operations of the plant, giving improvement to overall efficiency. This reduction in consumption of fuel is a step towards sustainable development. This report exclusively deals with the study the spiral heat ...
Monetary models and exchange rate determination: The Nigerian ...
African Journals Online (AJOL)
Monetary models and exchange rate determination: The Nigerian evidence. ... income levels and real interest rate differentials provide better forecasts of the naira-US dollar ... in this regard is that monetary policy should be positively predicted.
Modeling of Heat Exchange with Developed Nucleate Boiling on Tenons
Directory of Open Access Journals (Sweden)
A. V. Оvsiannik
2007-01-01
Full Text Available The paper proposes a thermal and physical model for heat exchange processes with developed nucleate boiling on the developed surfaces (tenons with various contours of heat transfer surface. Dependences for calculating convective heat exchange factor have been obtained on the basis of modeling representation. Investigations have shown that an intensity of convective heat exchange does not depend on tenon profile when boiling takes place on the tenons. The intensity is determined by operating conditions, thermal and physical properties of liquid, internal characteristics of boiling processes and geometrical characteristics of a tenon.
Modeling canopy CO2 exchange in the European Russian Arctic
DEFF Research Database (Denmark)
Kiepe, Isabell; Friborg, Thomas; Herbst, Mathias
2013-01-01
In this study, we use the coupled photosynthesis-stomatal conductance model of Collatz et al. (1991) to simulate the current canopy carbon dioxide exchange of a heterogeneous tundra ecosystem in European Russia. For the parameterization, we used data obtained from in situ leaf level measurements...... in combination with meteorological data from 2008. The modeled CO2 fluxes were compared with net ecosystem exchange (NEE), measured by the eddy covariance technique during the snow-free period in 2008. The findings from this study indicated that the main state parameters of the exchange processes were leaf area...
Ferrokinetics: a biologic model for plasma iron exchange in man.
Cook, J D; Marsaglia, G; Eschbach, J W; Funk, D D; Finch, C A
1970-02-01
A method is presented for calculating internal iron kinetics. An early reflux associated with extravascular exchange and a late reflux associated with erythropoiesis are described. A biologic model of iron exchange is proposed in which erythron iron turnover is divided into an effective portion (iron fixed in circulating red cells) and wastage iron of erythropoiesis (late reflux). Nonerythroid iron exchange also has a fixed portion (parenchymal uptake) and an early reflux (lymphatic circuit), both of which correlate in amount with the amount of plasma iron. Ferrokinetic measurements in normal subjects and in various pathologic states are presented to validate the model.
Modeling radial flow ion exchange performance for condensate polisher conditions
Energy Technology Data Exchange (ETDEWEB)
Shallcross, D. [University of Melbourne, Melbourne, VIC (Australia). Department of Chemical Engineering; Renouf, P.
2001-11-01
A theoretical model is developed which simulates ion exchange performance within an annular resin bed. Flow within the mixed ion exchange bed is diverging, with the solution flowing outwards away from the bed's axis. The model is used to simulate performance of a mixed annular bed operating under condensate polisher conditions. The simulation predictions are used to develop design envelope curves for practical radial flow beds and to estimate potential cost savings flowing from less expensive polisher vessels. (orig.)
Proton exchange membrane fuel cells modeling
Gao, Fengge; Miraoui, Abdellatif
2013-01-01
The fuel cell is a potential candidate for energy storage and conversion in our future energy mix. It is able to directly convert the chemical energy stored in fuel (e.g. hydrogen) into electricity, without undergoing different intermediary conversion steps. In the field of mobile and stationary applications, it is considered to be one of the future energy solutions.Among the different fuel cell types, the proton exchange membrane (PEM) fuel cell has shown great potential in mobile applications, due to its low operating temperature, solid-state electrolyte and compactness.This book pre
RESULTS OF INTERBANK EXCHANGE RATES FORECASTING USING STATE SPACE MODEL
Directory of Open Access Journals (Sweden)
Muhammad Kashif
2008-07-01
Full Text Available This study evaluates the performance of three alternative models for forecasting daily interbank exchange rate of U.S. dollar measured in Pak rupees. The simple ARIMA models and complex models such as GARCH-type models and a state space model are discussed and compared. Four different measures are used to evaluate the forecasting accuracy. The main result is the state space model provides the best performance among all the models.
Modeling ion exchange in clinoptilolite using the EQ3/6 geochemical modeling code
Energy Technology Data Exchange (ETDEWEB)
Viani, B.E.; Bruton, C.J.
1992-06-01
Assessing the suitability of Yucca Mtn., NV as a potential repository for high-level nuclear waste requires the means to simulate ion-exchange behavior of zeolites. Vanselow and Gapon convention cation-exchange models have been added to geochemical modeling codes EQ3NR/EQ6, allowing exchange to be modeled for up to three exchangers or a single exchanger with three independent sites. Solid-solution models that are numerically equivalent to the ion-exchange models were derived and also implemented in the code. The Gapon model is inconsistent with experimental adsorption isotherms of trace components in clinoptilolite. A one-site Vanselow model can describe adsorption of Cs or Sr on clinoptilolite, but a two-site Vanselow exchange model is necessary to describe K contents of natural clinoptilolites.
Modeling ion exchange in clinoptilolite using the EQ3/6 geochemical modeling code
Energy Technology Data Exchange (ETDEWEB)
Viani, B.E.; Bruton, C.J. [Lawrence Livermore National Lab., CA (United States)
1992-12-31
Potential disposal of high-level nuclear waste at Yucca Mtn., Nevada requires the means to simulate ion-exchange behavior of clays and zeolites. Vanselow and Gapon convention cation-exchange models have been added to geochemical modeling codes EQ3NR/EQ6, allowing exchange to be modeled for up to three exchangers or a single exchanger with three independent sites. Solid-solution models that are numerically equivalent to the ion-exchange models were derived and also implemented in the code. The Gapon model is inconsistent with experimental adsorption isotherms of trace components in clinoptilolite. A one-site Vanselow model can describe adsorption of Cs and Sr on clinoptilolite, but a two-site Vanselow exchange model is necessary to describe K contents of natural clinoptilolites. 15 refs., 5 figs., 1 tab.
Kinetic exchange models: From molecular physics to social science
Patriarca, Marco; Chakraborti, Anirban
2013-08-01
We discuss several multi-agent models that have their origin in the kinetic exchange theory of statistical mechanics and have been recently applied to a variety of problems in the social sciences. This class of models can be easily adapted for simulations in areas other than physics, such as the modeling of income and wealth distributions in economics and opinion dynamics in sociology.
Kinetic exchange models: From molecular physics to social science
Patriarca, Marco
2013-01-01
We discuss several multi-agent models that have their origin in the kinetic exchange theory of statistical mechanics and have been recently applied to a variety of problems in the social sciences. This class of models can be easily adapted for simulations in areas other than physics, such as the modeling of income and wealth distributions in economics and opinion dynamics in sociology.
Identification and Estimation of Exchange Rate Models with Unobservable Fundamentals
Chambers, M.J.; McCrorie, J.R.
2004-01-01
This paper is concerned with issues of model specification, identification, and estimation in exchange rate models with unobservable fundamentals.We show that the model estimated by Gardeazabal, Reg´ulez and V´azquez (International Economic Review, 1997) is not identified and demonstrate how to spec
Study on Isomerous CAD Model Exchange Based on Feature
Institute of Scientific and Technical Information of China (English)
SHAO Xiaodong; CHEN Feng; XU Chenguang
2006-01-01
A model-exchange method based on feature between isomerous CAD systems is put forward in this paper. In this method, CAD model information is accessed at both feature and geometry levels and converted according to standard feature operation. The feature information including feature tree, dimensions and constraints, which will be lost in traditional data conversion, as well as geometry are converted completely from source CAD system to destination one. So the transferred model can be edited through feature operation, which cannot be implemented by general model-exchange interface.
Thermal performance modeling of cross-flow heat exchangers
Cabezas-Gómez, Luben; Saíz-Jabardo, José Maria
2014-01-01
This monograph introduces a numerical computational methodology for thermal performance modeling of cross-flow heat exchangers, with applications in chemical, refrigeration and automobile industries. This methodology allows obtaining effectiveness-number of transfer units (e-NTU) data and has been used for simulating several standard and complex flow arrangements configurations of cross-flow heat exchangers. Simulated results have been validated through comparisons with results from available exact and approximate analytical solutions. Very accurate results have been obtained over wide ranges
MODELING RESULTS FROM CESIUM ION EXCHANGE PROCESSING WITH SPHERICAL RESINS
Energy Technology Data Exchange (ETDEWEB)
Nash, C.; Hang, T.; Aleman, S.
2011-01-03
Ion exchange modeling was conducted at the Savannah River National Laboratory to compare the performance of two organic resins in support of Small Column Ion Exchange (SCIX). In-tank ion exchange (IX) columns are being considered for cesium removal at Hanford and the Savannah River Site (SRS). The spherical forms of resorcinol formaldehyde ion exchange resin (sRF) as well as a hypothetical spherical SuperLig{reg_sign} 644 (SL644) are evaluated for decontamination of dissolved saltcake wastes (supernates). Both SuperLig{reg_sign} and resorcinol formaldehyde resin beds can exhibit hydraulic problems in their granular (nonspherical) forms. SRS waste is generally lower in potassium and organic components than Hanford waste. Using VERSE-LC Version 7.8 along with the cesium Freundlich/Langmuir isotherms to simulate the waste decontamination in ion exchange columns, spherical SL644 was found to reduce column cycling by 50% for high-potassium supernates, but sRF performed equally well for the lowest-potassium feeds. Reduced cycling results in reduction of nitric acid (resin elution) and sodium addition (resin regeneration), therefore, significantly reducing life-cycle operational costs. These findings motivate the development of a spherical form of SL644. This work demonstrates the versatility of the ion exchange modeling to study the effects of resin characteristics on processing cycles, rates, and cold chemical consumption. The value of a resin with increased selectivity for cesium over potassium can be assessed for further development.
Stydy on the Model of Ion Exchange Kinetics
Institute of Scientific and Technical Information of China (English)
ChenFengrong; JiangZhixin
1994-01-01
In this paper, a macrokinetics model equation describing the characteristics of the solid-liquid mass transfer has been proposed.The qualitative analysis and experimental verification have been done for this mode equation.The model equation can explain the ion exchange process considerably well.
Modeling Of Proton Exchange Membrane Fuel Cell Systems
DEFF Research Database (Denmark)
Nielsen, Mads Pagh
The objective of this doctoral thesis was to develop reliable steady-state and transient component models suitable to asses-, develop- and optimize proton exchange membrane (PEM) fuel cell systems. Several components in PEM fuel cell systems were characterized and modeled. The developed component...
Exchange Rate Forecasting Using Entropy Optimized Multivariate Wavelet Denoising Model
Directory of Open Access Journals (Sweden)
Kaijian He
2014-01-01
Full Text Available Exchange rate is one of the key variables in the international economics and international trade. Its movement constitutes one of the most important dynamic systems, characterized by nonlinear behaviors. It becomes more volatile and sensitive to increasingly diversified influencing factors with higher level of deregulation and global integration worldwide. Facing the increasingly diversified and more integrated market environment, the forecasting model in the exchange markets needs to address the individual and interdependent heterogeneity. In this paper, we propose the heterogeneous market hypothesis- (HMH- based exchange rate modeling methodology to model the micromarket structure. Then we further propose the entropy optimized wavelet-based forecasting algorithm under the proposed methodology to forecast the exchange rate movement. The multivariate wavelet denoising algorithm is used to separate and extract the underlying data components with distinct features, which are modeled with multivariate time series models of different specifications and parameters. The maximum entropy is introduced to select the best basis and model parameters to construct the most effective forecasting algorithm. Empirical studies in both Chinese and European markets have been conducted to confirm the significant performance improvement when the proposed model is tested against the benchmark models.
Cluster variation studies of the anisotropic exchange interaction model
King, T. C.; Chen, H. H.
The cluster variation method is applied to study critical properties of the Potts-like ferromagnetic anisotropic exchange interaction model. Phase transition temperatures, order parameter discontinuities and latent heats of the model on the triangular and the fcc lattices are determined by the triangle approximation; and those on the square and the sc lattices are determined by the square approximation.
Phase transitions and relaxation dynamics of Ising models exchanging particles
Goh, Segun; Fortin, Jean-Yves; Choi, M. Y.
2017-01-01
A variety of systems in nature and in society are open and subject to exchanging their constituents with other systems (e.g., environments). For instance, in biological systems, cells collect necessary energy and material by exchange of molecules or ions. Similarly, countries, cities or research institutes evolve as their constituents move in or out. To probe the corresponding particle exchange dynamics in such systems, we consider two Ising models exchanging particles and establish a master equation describing the equilibrium phases as well as the non-equilibrium dynamics of the system. It is found that an additional stable phase emerges as a consequence of the particle exchange process. Furthermore, we formulate the Ginzburg-Landau theory which allows to probe correlation effects. Accordingly, critical slowing down is manifested and the associated dynamic exponent is computed in the linear relaxation regime. In particular, this approach is relevant for investigating the grand canonical description of the system plus environment, with particle exchange and state transitions taken into account explicitly.
Exchange Rate Prediction using Neural – Genetic Model
Directory of Open Access Journals (Sweden)
MECHGOUG Raihane
2012-10-01
Full Text Available Neural network have successfully used for exchange rate forecasting. However, due to a large number of parameters to be estimated empirically, it is not a simple task to select the appropriate neural network architecture for exchange rate forecasting problem.Researchers often overlook the effect of neural network parameters on the performance of neural network forecasting. The performance of neural network is critically dependant on the learning algorithms, thenetwork architecture and the choice of the control parameters. Even when a suitable setting of parameters (weight can be found, the ability of the resulting network to generalize the data not seen during learning may be far from optimal. For these reasons it seemslogical and attractive to apply genetic algorithms. Genetic algorithms may provide a useful tool for automating the design of neural network. The empirical results on foreign exchange rate prediction indicate that the proposed hybrid model exhibits effectively improved accuracy, when is compared with some other time series forecasting models.
Multiphysics Numerical Modeling of a Fin and Tube Heat Exchanger
DEFF Research Database (Denmark)
Singh, Shobhana; Sørensen, Kim; Condra, Thomas Joseph
2015-01-01
). For the purposes here, only gas flowing over the fin side is simulated assuming constant inner tube wall temperature. The study couples conjugate heat transfer mechanism with turbulent flow in order to describe the temperature and velocity profile. In addition, performance characteristics of the heat exchanger...... design in terms of heat transfer and pressure loss are determined by parameters such as overall heat transfer coefficient, Colburn j-factor, flow resistance factor, and efficiency index. The model provides useful insights necessary for optimization of heat exchanger design....
Stochastic Model of Maturation and Vesicular Exchange in Cellular Organelles
Vagne, Quentin
2016-01-01
The dynamical organization of membrane-bound organelles along intracellular transport pathways relies on vesicular exchange between organelles and on biochemical maturation of the organelle content by specific enzymes. The relative importance of each mechanism in controlling organelle dynamics remains controversial, in particular for transport through the Golgi apparatus. Using a stochastic model, we show that full maturation of membrane-bound compartments can be seen as the stochastic escape from a steady-state in which export is dominated by vesicular exchange. We show that full maturation can contribute a significant fraction of the total out-flux for small organelles such as endosomes and Golgi cisternae.
Modeling and predicting historical volatility in exchange rate markets
Lahmiri, Salim
2017-04-01
Volatility modeling and forecasting of currency exchange rate is an important task in several business risk management tasks; including treasury risk management, derivatives pricing, and portfolio risk evaluation. The purpose of this study is to present a simple and effective approach for predicting historical volatility of currency exchange rate. The approach is based on a limited set of technical indicators as inputs to the artificial neural networks (ANN). To show the effectiveness of the proposed approach, it was applied to forecast US/Canada and US/Euro exchange rates volatilities. The forecasting results show that our simple approach outperformed the conventional GARCH and EGARCH with different distribution assumptions, and also the hybrid GARCH and EGARCH with ANN in terms of mean absolute error, mean of squared errors, and Theil's inequality coefficient. Because of the simplicity and effectiveness of the approach, it is promising for US currency volatility prediction tasks.
Modeling of karst aquifer genesis: Influence of exchange flow
Bauer, Sebastian; Liedl, Rudolf; Sauter, Martin
2003-10-01
This paper presents a numerical model study simulating the early karstification of a single conduit embedded in a fissured system. A hybrid continuum-discrete pipe flow model (CAVE) is used for the modeling. The effects of coupling of the two flow systems on type and duration of early karstification are studied for different boundary conditions. Assuming fixed head boundaries at both ends of the conduit, coupling of the two flow systems via exchange flow between the conduit and the fissured system leads to an enhanced evolution of the conduit. This effect is valid over a wide range of initial conduit diameters, and karstification is accelerated by a factor of about 100 as compared to the case of no exchange flow. Parameter studies reveal the influence of the exchange coefficient and of the hydraulic conductivity of the fissured system on the development time for the conduit. In a second scenario the upstream fixed head boundary is switched to a fixed flow boundary at a specified flow rate during the evolution, limiting the amount of water draining toward the evolving conduit. Depending on the flow rate specified, conduit evolution may be slowed down or greatly impaired if exchange flow is considered.
Agent dynamics in kinetic models of wealth exchange
Chatterjee, Arnab
2010-01-01
We study the dynamics of individual agents in some kinetic models of wealth exchange, particularly, the models with savings. For the model with uniform savings, agents perform simple random walks in the `"wealth space". On the other hand, we observe ballistic diffusion in the model with distributed savings. There is an associated skewness in the gain-loss distribution which explains the steady state behavior in such models. We find that in general an agent gains while interacting with an agent with a larger saving propensity.
New hybrid model of proton exchange membrane fuel cell
Institute of Scientific and Technical Information of China (English)
WANG Rui-min; CAO Guang-yi; ZHU Xin-jian
2007-01-01
Model and simulation are good tools for design optimization of fuel cell systems. This paper proposes a new hybrid model of proton exchange membrane fuel cell (PEMFC). The hybrid model includes physical component and black-box component. The physical component represents the well-known part of PEMFC, while artificial neural network (ANN) component estimates the poorly known part of PEMFC. The ANN model can compensate the performance of the physical model. This hybrid model is implemented on Matlab/Simulink software. The hybrid model shows better accuracy than that of the physical model and ANN model. Simulation results suggest that the hybrid model can be used as a suitable and accurate model for PEMFC.
Inequality measures in kinetic exchange models of wealth distributions
Ghosh, Asim; Chatterjee, Arnab; Inoue, Jun-ichi; Chakrabarti, Bikas K.
2016-06-01
In this paper, we study the inequality indices for some models of wealth exchange. We calculated Gini index and newly introduced k-index and compare the results with reported empirical data available for different countries. We have found lower and upper bounds for the indices and discuss the efficiencies of the models. Some exact analytical calculations are given for a few cases. We also exactly compute the quantities for Gamma and double Gamma distributions.
Inequality measures in kinetic exchange models of wealth distributions
Ghosh, Asim; Inoue, Jun-ichi; Chakrabarti, Bikas K
2015-01-01
In this paper, we study the inequality indices for some models of wealth exchange. We calculated Gini index and newly introduced k-index and compare the results with reported empirical data available for different countries. We have found lower and upper bounds for the indices and discuss the efficiencies of the models. Some exact analytical calculations are given for a few cases. We also exactly compute the quantities for Gamma and double Gamma distributions.
TESTING MONETARY EXCHANGE RATE MODELS WITH PANEL COINTEGRATION TESTS
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Szabo Andrea
2015-07-01
Full Text Available The monetary exchange rate models explain the long run behaviour of the nominal exchange rate. Their central assertion is that there is a long run equilibrium relationship between the nominal exchange rate and monetary macro-fundamentals. Although these models are essential tools of international macroeconomics, their empirical validity is ambiguous. Previously, time series testing was prevalent in the literature, but it did not bring convincing results. The power of the unit root and the cointegration tests are too low to reject the null hypothesis of no cointegration between the variables. This power can be enhanced by arranging our data in a panel data set, which allows us to analyse several time series simultaneously and enables us to increase the number of observations. We conducted a weak empirical test of the monetary exchange rate models by testing the existence of cointegration between the variables in three panels. We investigated 6, 10 and 15 OECD countries during the following periods: 1976Q1-2011Q4, 1985Q1-2011Q4 and 1996Q1-2011Q4. We tested the reduced form of the monetary exchange rate models in three specifications; we have two restricted models and an unrestricted model. Since cointegration can only be interpreted among non-stationary processes, we investigate the order of the integration of our variables with IPS, Fisher-ADF, Fisher-PP panel unit root tests and the Hadri panel stationary test. All the variables can be unit root processes; therefore we analyze the cointegration with the Pedroni and Kao panel cointegration test. The restricted models performed better than the unrestricted one and we obtained the best results with the 1985Q1-2011Q4 panel. The Kao test rejects the null hypotheses – there is no cointegration between the variables – in all the specifications and all the panels, but the Pedroni test does not show such a positive picture. Hence we found only moderate support for the monetary exchange rate models.
Categorization of exchange fluxes explains the four relational models
Favre, Maroussia
2013-01-01
The theory of Relational Models (RMs) posits four elementary models of relationships governing all human interactions, singly or in combination: Communal Sharing, Authority Ranking, Equality Matching, and Market Pricing. By considering two agents that can act in one out of three ways towards one another: give resource A, give resource B, or give nothing, we find four discrete categories of exchange fluxes that map unequivocally to the four RMs. This categorization shows that the RMs form an exhaustive set of all possible elementary exchanges. Hence, the fluxes categorization answers why there are just four RMs and explains their discreteness. By considering the costs associated with extracting resources, storing them and implementing each flux category, we are able to propose conditions under which each RM should evolve. We also logically deduce the singular nature of the Authority Ranking model. Our propositions are compatible with anthropological, ethnological and historical observations and can be tested a...
ECONOMETRIC APPROACH TO DIFFERENCE EQUATIONS MODELING OF EXCHANGE RATES CHANGES
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Josip Arnerić
2010-12-01
Full Text Available Time series models that are commonly used in econometric modeling are autoregressive stochastic linear models (AR and models of moving averages (MA. Mentioned models by their structure are actually stochastic difference equations. Therefore, the objective of this paper is to estimate difference equations containing stochastic (random component. Estimated models of time series will be used to forecast observed data in the future. Namely, solutions of difference equations are closely related to conditions of stationary time series models. Based on the fact that volatility is time varying in high frequency data and that periods of high volatility tend to cluster, the most successful and popular models in modeling time varying volatility are GARCH type models and their variants. However, GARCH models will not be analyzed because the purpose of this research is to predict the value of the exchange rate in the levels within conditional mean equation and to determine whether the observed variable has a stable or explosive time path. Based on the estimated difference equation it will be examined whether Croatia is implementing a stable policy of exchange rates.
Wealth concentration in a biased asset-exchange model
Devitt-Lee, Adrian
Economic inequality is a significant and dynamic problem throughout the world. Asset-exchange models have been used to model macroeconomic systems based on microeconomic assumptions about how agents exchange wealth in an economy. Previous studies of a certain asset-exchange model, called the Yard-Sale model, have found that trade alone promotes the condensation of wealth to a single individual in an economy [Chakraborti, 2002, Moukarzel et al., 2007, Boghosian, 2014b]. A later study found that a slight modification of the Yard-Sale model seems to allow for the coexistence of both "condensed wealth" and a normal population in an economy [Boghosian et al., 2016a]. This work formalizes the notion of wealth condensation in a macroeconomic system. This can be done by extending Schwartz's theory of distributions to allow for objects which increase at most linearly at infinity, or by considering condensed wealth to be a nonstandard phenomenon, and describing it as such. Numerical simulations indicate that this continuous description of wealth concentration is a valid approximation of wealth concentration in discrete systems with as few as 256 agents. We then study the properties of the steady-state distribution of wealth in such a system, and mention the fit of our system to the distribution of wealth in the United States in 2016.
Closed Loop Brain Model of Neocortical Information Based Exchange
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James eKozloski
2016-01-01
Full Text Available Here we describe an information based exchange' model of brain function that ascribes to neocortex, basal ganglia, and thalamus distinct network functions. The model allows us to analyze whole brain system set point measures, such as the rate and heterogeneity of transitions in striatum and neocortex, in the context of neuromodulation and other perturbations. Our closed-loop model is grounded in neuroanatomical observations, proposing a novel Grand Loop through neocortex, and invokes different forms of plasticity at specific tissue interfaces and their principle cell synapses to achieve these transitions. By implementing a system for maximum information based exchange of action potentials between modeled neocortical areas, we observe changes to these measures in simulation. We hypothesize that similar dynamic set points and modulations exist in the brain's resting state activity, and that different modifications to information based exchange may shift the risk profile of different component tissues, resulting in different neurodegenerative diseases. This model is targeted for further development using IBM's Neural Tissue Simulator, which allows scalable elaboration of networks, tissues, and their neural and synaptic components towards ever greater complexity and biological realism.
Modeling Of Proton Exchange Membrane Fuel Cell Systems
DEFF Research Database (Denmark)
Nielsen, Mads Pagh
The objective of this doctoral thesis was to develop reliable steady-state and transient component models suitable to asses-, develop- and optimize proton exchange membrane (PEM) fuel cell systems. Several components in PEM fuel cell systems were characterized and modeled. The developed component...... cell systems. Consequences of indirectly fueling PEM stacks with hydrocarbons using reforming technology were investigated using a PEM stack model including CO poisoning kinetics and a transient Simulink steam reforming system model. Aspects regarding the optimization of PEM fuel cell systems...
Performance analysis of a medical record exchanges model.
Huang, Ean-Wen; Liou, Der-Ming
2007-03-01
Electronic medical record exchange among hospitals can provide more information for physician diagnosis and reduce costs from duplicate examinations. In this paper, we proposed and implemented a medical record exchange model. According to our study, exchange interface servers (EISs) are designed for hospitals to manage the information communication through the intra and interhospital networks linked with a medical records database. An index service center can be given responsibility for managing the EIS and publishing the addresses and public keys. The prototype system has been implemented to generate, parse, and transfer the health level seven query messages. Moreover, the system can encrypt and decrypt a message using the public-key encryption algorithm. The queuing theory is applied to evaluate the performance of our proposed model. We estimated the service time for each queue of the CPU, database, and network, and measured the response time and possible bottlenecks of the model. The capacity of the model is estimated to process the medical records of about 4000 patients/h in the 1-MB network backbone environments, which comprises about the 4% of the total outpatients in Taiwan.
Directory of Open Access Journals (Sweden)
Waclaw Tworzydlo
Full Text Available Three main reproductive strategies have been described among insects: most common oviparity, ovoviviparity and viviparity. In the latter strategy, the embryonic development takes place within the body of the mother which provides gas exchange and nutrients for embryos. Here we present the results of histological and EM analyses of the female reproductive system of the viviparous earwig, Arixenia esau, focusing on all the modifications related to the viviparity. We show that in the studied species the embryonic development consists of two "physiological phases" that take place in two clearly disparate compartments, i.e. the terminal ovarian follicle and the uterus. In both compartments the embryos are associated with synthetically active epithelial cells. We suggest that these cells are involved in the nourishment of the embryo. Our results indicate that viviparity in arixeniids is more complex than previously considered. We propose the new term "pseudoplacento-uterotrophic viviparity" for this unique two-phase reproductive strategy.
Tworzydlo, Waclaw; Kisiel, Elzbieta; Bilinski, Szczepan M
2013-01-01
Three main reproductive strategies have been described among insects: most common oviparity, ovoviviparity and viviparity. In the latter strategy, the embryonic development takes place within the body of the mother which provides gas exchange and nutrients for embryos. Here we present the results of histological and EM analyses of the female reproductive system of the viviparous earwig, Arixenia esau, focusing on all the modifications related to the viviparity. We show that in the studied species the embryonic development consists of two "physiological phases" that take place in two clearly disparate compartments, i.e. the terminal ovarian follicle and the uterus. In both compartments the embryos are associated with synthetically active epithelial cells. We suggest that these cells are involved in the nourishment of the embryo. Our results indicate that viviparity in arixeniids is more complex than previously considered. We propose the new term "pseudoplacento-uterotrophic viviparity" for this unique two-phase reproductive strategy.
Vector Meson Electro-production in Pomeron Exchange Model
Institute of Scientific and Technical Information of China (English)
MA Wei-Xing; LIU Bao-Rong; ZHOU Li-Juan; TAN Zhen-Qiang; HE Xiao-Rong; GU Yun-Ting
2005-01-01
Based on Pomeron exchange model, elastic production of vector meson in electro-proton interaction is investigated with both linear and non-linear Pomeron trajectory. A numerical calculation for J/ψ production is performed. The effect of the energy scale so and photon virtuality Q2 on differential cross section are also predicted. Agood agreement with experimental data is obtained. Our conclusions are that the Pomeron exchange model is a successful description of J/ψ electro-production, the dependence of the differential cross sections on Q2 is negligible, the linear trajectory is a good approximation to non-linearity of the Pomeron trajectory, and the value of the energy scale parameter so is dependent on the momentum transfer, namely its effect is moderate at low momentum transfer but it causes no difference at high momentum transfer | t |≥ 1.25 GeV2.
Generalized Bogoliubov Polariton Model: An Application to Stock Exchange Market
Thuy Anh, Chu; Anh, Truong Thi Ngoc; Lan, Nguyen Tri; Viet, Nguyen Ai
2016-06-01
A generalized Bogoliubov method for investigation non-simple and complex systems was developed. We take two branch polariton Hamiltonian model in second quantization representation and replace the energies of quasi-particles by two distribution functions of research objects. Application to stock exchange market was taken as an example, where the changing the form of return distribution functions from Boltzmann-like to Gaussian-like was studied.
Exchange bias of patterned systems: Model and numerical simulation
Energy Technology Data Exchange (ETDEWEB)
Garcia, Griselda [Facultad de Fisica, P. Universidad Catolica de Chile, Casilla 306, Santiago 7820436 (Chile); Centro para el Desarrollo de la Nanociencia y la Nanotecnologia, CEDENNA, Avda. Ecuador 3493, Santiago (Chile); Kiwi, Miguel, E-mail: mkiwi@puc.c [Facultad de Fisica, P. Universidad Catolica de Chile, Casilla 306, Santiago 7820436 (Chile); Centro para el Desarrollo de la Nanociencia y la Nanotecnologia, CEDENNA, Avda. Ecuador 3493, Santiago (Chile); Mejia-Lopez, Jose; Ramirez, Ricardo [Facultad de Fisica, P. Universidad Catolica de Chile, Casilla 306, Santiago 7820436 (Chile); Centro para el Desarrollo de la Nanociencia y la Nanotecnologia, CEDENNA, Avda. Ecuador 3493, Santiago (Chile)
2010-11-15
The magnitude of the exchange bias field of patterned systems exhibits a notable increase in relation to the usual bilayer systems, where a continuous ferromagnetic film is deposited on an antiferromagnet insulator. Here we develop a model, and implement a Monte Carlo calculation, to interpret the experimental observations which is consistent with experimental results, on the basis of assuming a small fraction of spins pinned ferromagnetically in the antiferromagnetic interface layer.
Kinetic Modeling of Incremental Ambulatory Peritoneal Dialysis Exchanges.
Guest, Steven; Leypoldt, John K; Cassin, Michelle; Schreiber, Martin
2017-01-01
♦ BACKGROUND: Incremental peritoneal dialysis (PD), the gradual introduction of dialysate exchanges at less than full-dose therapy, has been infrequently described in clinical reports. One concern with less than full-dose dialysis is whether urea clearance targets are achievable with an incremental regimen. In this report, we used a large database of PD patients, across all membrane transport types, and performed urea kinetic modeling determinations of possible incremental regimens for an individual membrane type. ♦ METHODS: Using a modified 3-pore model of peritoneal transport, various incremental manual continuous ambulatory PD (CAPD) exchanges employing glucose and/or icodextrin were evaluated. Peritoneal urea clearances from those simulations were added to residual kidney urea clearance for patients with various glomerular filtration rates (GFRs), and the total weekly urea clearance was then compared to the total weekly urea Kt/V target of 1.7. All 4 peritoneal membrane types were modeled. For each simulated prescription, net ultrafiltration and carbohydrate absorption were also calculated. ♦ RESULTS: Incremental CAPD regimens of 2 exchanges a day met adequacy targets if the GFR was 6 mL/min/1.73 m(2) in all membrane types. For regimens employing 3 exchanges a day, Kt/V targets were achieved at GFR levels of 4 to 5 mL/min/1.73 m(2) in high transporters to low transporters but higher tonicity 2.5% glucose solutions or icodextrin were required in some regimens. ♦ CONCLUSIONS: This work demonstrates that with incremental CAPD regimens, urea kinetic targets are achievable in most new starts to PD with residual kidney function. Incremental PD may be a less intrusive, better accepted initial treatment regime and a cost-effective way to initiate chronic dialysis in the incident patient. The key role of intrinsic kidney function in incremental regimens is highlighted in this analysis and would warrant conscientious monitoring. Copyright © 2017 International
Wealth distribution of simple exchange models coupled with extremal dynamics
Bagatella-Flores, N.; Rodríguez-Achach, M.; Coronel-Brizio, H. F.; Hernández-Montoya, A. R.
2015-01-01
Punctuated Equilibrium (PE) states that after long periods of evolutionary quiescence, species evolution can take place in short time intervals, where sudden differentiation makes new species emerge and some species extinct. In this paper, we introduce and study the effect of punctuated equilibrium on two different asset exchange models: the yard sale model (YS, winner gets a random fraction of a poorer player's wealth) and the theft and fraud model (TF, winner gets a random fraction of the loser's wealth). The resulting wealth distribution is characterized using the Gini index. In order to do this, we consider PE as a perturbation with probability ρ of being applied. We compare the resulting values of the Gini index at different increasing values of ρ in both models. We found that in the case of the TF model, the Gini index reduces as the perturbation ρ increases, not showing dependence with the agents number. While for YS we observe a phase transition which happens around ρc = 0.79. For perturbations ρ increases (an extreme wealth condensation state), whereas for perturbations greater than or equal to ρc the Gini index becomes different to one, avoiding the system reaches this extreme state. We show that both simple exchange models coupled with PE dynamics give more realistic results. In particular for YS, we observe a power low decay of wealth distribution.
Multilinear Model of Heat Exchanger with Hammerstein Structure
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Dragan Pršić
2016-01-01
Full Text Available The multilinear model control design approach is based on the approximation of the nonlinear model of the system by a set of linear models. The paper presents the method of creation of a bank of linear models of the two-pass shell and tube heat exchanger. The nonlinear model is assumed to have a Hammerstein structure. The set of linear models is formed by decomposition of the nonlinear steady-state characteristic by using the modified Included Angle Dividing method. Two modifications of this method are proposed. The first one refers to the addition to the algorithm for decomposition, which reduces the number of linear segments. The second one refers to determination of the threshold value. The dependence between decomposition of the nonlinear characteristic and the linear dynamics of the closed-loop system is established. The decoupling process is more formal and it can be easily implemented by using software tools. Due to its simplicity, the method is particularly suitable in complex systems, such as heat exchanger networks.
A continuum model for metabolic gas exchange in pear fruit.
Directory of Open Access Journals (Sweden)
Q Tri Ho
2008-03-01
Full Text Available Exchange of O(2 and CO(2 of plants with their environment is essential for metabolic processes such as photosynthesis and respiration. In some fruits such as pears, which are typically stored under a controlled atmosphere with reduced O(2 and increased CO(2 levels to extend their commercial storage life, anoxia may occur, eventually leading to physiological disorders. In this manuscript we have developed a mathematical model to predict the internal gas concentrations, including permeation, diffusion, and respiration and fermentation kinetics. Pear fruit has been selected as a case study. The model has been used to perform in silico experiments to evaluate the effect of, for example, fruit size or ambient gas concentration on internal O(2 and CO(2 levels. The model incorporates the actual shape of the fruit and was solved using fluid dynamics software. Environmental conditions such as temperature and gas composition have a large effect on the internal distribution of oxygen and carbon dioxide in fruit. Also, the fruit size has a considerable effect on local metabolic gas concentrations; hence, depending on the size, local anaerobic conditions may result, which eventually may lead to physiological disorders. The model developed in this manuscript is to our knowledge the most comprehensive model to date to simulate gas exchange in plant tissue. It can be used to evaluate the effect of environmental stresses on fruit via in silico experiments and may lead to commercial applications involving long-term storage of fruit under controlled atmospheres.
Modeling inflation rates and exchange rates in Ghana: application of multivariate GARCH models.
Nortey, Ezekiel Nn; Ngoh, Delali D; Doku-Amponsah, Kwabena; Ofori-Boateng, Kenneth
2015-01-01
This paper was aimed at investigating the volatility and conditional relationship among inflation rates, exchange rates and interest rates as well as to construct a model using multivariate GARCH DCC and BEKK models using Ghana data from January 1990 to December 2013. The study revealed that the cumulative depreciation of the cedi to the US dollar from 1990 to 2013 is 7,010.2% and the yearly weighted depreciation of the cedi to the US dollar for the period is 20.4%. There was evidence that, the fact that inflation rate was stable, does not mean that exchange rates and interest rates are expected to be stable. Rather, when the cedi performs well on the forex, inflation rates and interest rates react positively and become stable in the long run. The BEKK model is robust to modelling and forecasting volatility of inflation rates, exchange rates and interest rates. The DCC model is robust to model the conditional and unconditional correlation among inflation rates, exchange rates and interest rates. The BEKK model, which forecasted high exchange rate volatility for the year 2014, is very robust for modelling the exchange rates in Ghana. The mean equation of the DCC model is also robust to forecast inflation rates in Ghana.
Clinical exchange: one model to achieve culturally sensitive care.
Scholes, J; Moore, D
2000-03-01
This paper reports on a clinical exchange programme that formed part of a pre-registration European nursing degree run by three collaborating institutions in England, Holland and Spain. The course included: common and shared learning including two summer schools; and the development of a second language before the students went on a three-month clinical placement in one of the other base institutions' clinical environments. The aim of the course was to enable students to become culturally sensitive carers. This was achieved by developing a programme based on transcultural nursing principles in theory and practice. Data were gathered by interview, focus groups, and questionnaires from 79 exchange students, fostering the strategies of illuminative evaluation. The paper examines: how the aims of the course were met; the factors that inhibited the attainment of certain goals; and how the acquisition of a second language influenced the students' learning about nursing. A model is presented to illustrate the process of transformative learning from the exchange experience.
Modeling Inflation Using a Non-Equilibrium Equation of Exchange
Chamberlain, Robert G.
2013-01-01
Inflation is a change in the prices of goods that takes place without changes in the actual values of those goods. The Equation of Exchange, formulated clearly in a seminal paper by Irving Fisher in 1911, establishes an equilibrium relationship between the price index P (also known as "inflation"), the economy's aggregate output Q (also known as "the real gross domestic product"), the amount of money available for spending M (also known as "the money supply"), and the rate at which money is reused V (also known as "the velocity of circulation of money"). This paper offers first a qualitative discussion of what can cause these factors to change and how those causes might be controlled, then develops a quantitative model of inflation based on a non-equilibrium version of the Equation of Exchange. Causal relationships are different from equations in that the effects of changes in the causal variables take time to play out-often significant amounts of time. In the model described here, wages track prices, but only after a distributed lag. Prices change whenever the money supply, aggregate output, or the velocity of circulation of money change, but only after a distributed lag. Similarly, the money supply depends on the supplies of domestic and foreign money, which depend on the monetary base and a variety of foreign transactions, respectively. The spreading of delays mitigates the shocks of sudden changes to important inputs, but the most important aspect of this model is that delays, which often have dramatic consequences in dynamic systems, are explicitly incorporated.macroeconomics, inflation, equation of exchange, non-equilibrium, Athena Project
MODELLING THE WORLD EXCHANGE RATES:DYNAMICS, VOLATILITY AND FORECASTING
Nwaobi, Godwin
2008-01-01
Indeed, the specification of equilibrium in the world economy depends on the exchange rate regime and thus, the early contributions to the postwar literature on exchange rate economics are to a large extent concerened with the role of speculation in foreign exchange markets. However, the world has known several exchange rate systems beginning with the fixed-gold standard, the adjustable-peg system, adjustable-parity system and the flexible exchange rate system. Yet, in 1997, when foreign exch...
φ Electro-production in Pomeron Exchange Model
Institute of Scientific and Technical Information of China (English)
MA Wei-Xing; LIU Bao-Rong; ZHOU Li-Juan; TAN Zhen-Qiang; HE Xiao-Rong; GU Yun-Ting
2005-01-01
Based on the Pomeron exchange model, elastic production of φ meson in electron-proton interaction is investigated with both linear and non-linear Pomeron trajectories. The numerical calculations of the differential cross section for e + p → e' + p+ φ are performed. The theoretical predictions show that the dependence of the differentialcross section on virtual photon virtuality, Q2, is of moderation, the change of the energy scale parameter so causes moderate effect on the differential cross section, and the linear trajectory is a good approximation to non-linearity of the Pomeron trajectory, in particular, at small momentum transfer region | t |≤ 0.2 GeV2.
Common Data Model for Neuroscience Data and Data Model Exchange
Gardner, Daniel; Kevin H. Knuth; Abato, Michael; Erde, Steven M.; White, Thomas; DeBellis, Robert; Gardner, Esther P
2001-01-01
Objective: Generalizing the data models underlying two prototype neurophysiology databases, the authors describe and propose the Common Data Model (CDM) as a framework for federating a broad spectrum of disparate neuroscience information resources.
Modeling Multi-commodity Trade Information Exchange Methods
Traczyk, Tomasz
2012-01-01
Market mechanisms are entering into new fields of economy, in which some constraints of physical world, e.g. Kirchoffs Law in power grid, must be taken into account during trading. On such markets, some of commodities, like telecommunication bandwidth or electrical energy, appear to be non-storable, and must be exchanged in real-time. On the other hand, the markets tend to react at shortest possible time, so an idea to delegate some competency to autonomous software agents is very attractive. Multi-commodity mechanism addresses the aforementioned requirements. Modeling the relationships between the commodities allows to formulate new, more sophisticated models and mechanisms, which reflect decision situations in a better manner. Application of multi-commodity approach requires solving several issues related to data modeling, communication, semantics aspects of communication, reliability, etc. This book answers some of the questions and points out promising paths for implementation and development. Presented s...
Modelling world gold prices and USD foreign exchange relationship using multivariate GARCH model
Ping, Pung Yean; Ahmad, Maizah Hura Binti
2014-12-01
World gold price is a popular investment commodity. The series have often been modeled using univariate models. The objective of this paper is to show that there is a co-movement between gold price and USD foreign exchange rate. Using the effect of the USD foreign exchange rate on the gold price, a model that can be used to forecast future gold prices is developed. For this purpose, the current paper proposes a multivariate GARCH (Bivariate GARCH) model. Using daily prices of both series from 01.01.2000 to 05.05.2014, a causal relation between the two series understudied are found and a bivariate GARCH model is produced.
Comparison of moving boundary and finite-volume heat exchanger models in the modelica language
Adriano Desideri; Bertrand Dechesne; Jorrit Wronski; Martijn van den Broek; Sergei Gusev; Vincent Lemort; Sylvain Quoilin
2016-01-01
When modeling low capacity energy systems, such as a small size (5–150 kWel) organic Rankine cycle unit, the governing dynamics are mainly concentrated in the heat exchangers. As a consequence, the accuracy and simulation speed of the higher level system model mainly depend on the heat exchanger model formulation. In particular, the modeling of thermo-flow systems characterized by evaporation or condensation requires heat exchanger models capable of handling phase transitions. To this aim, th...
A probabilistic model of a porous heat exchanger
Agrawal, O. P.; Lin, X. A.
1995-01-01
This paper presents a probabilistic one-dimensional finite element model for heat transfer processes in porous heat exchangers. The Galerkin approach is used to develop the finite element matrices. Some of the submatrices are asymmetric due to the presence of the flow term. The Neumann expansion is used to write the temperature distribution as a series of random variables, and the expectation operator is applied to obtain the mean and deviation statistics. To demonstrate the feasibility of the formulation, a one-dimensional model of heat transfer phenomenon in superfluid flow through a porous media is considered. Results of this formulation agree well with the Monte-Carlo simulations and the analytical solutions. Although the numerical experiments are confined to parametric random variables, a formulation is presented to account for the random spatial variations.
Meson Exchange Current (MEC) Models in Neutrino Interaction Generators
Katori, Teppei
2013-01-01
Understanding of the so-called 2 particle-2 hole (2p-2h) effect is an urgent program in neutrino interaction physics for current and future oscillation experiments. Such processes are believed to be responsible for the event excesses observed by recent neutrino experiments. The 2p-2h effect is dominated by the meson exchange current (MEC), and is accompanied by a 2-nucleon emission from the primary vertex, instead of a single nucleon emission from the charged-current quasi-elastic (CCQE) interaction. Current and future high resolution experiments can potentially nail down this effect. For this reason, there are world wide efforts to model and implement this process in neutrino interaction simulations. In these proceedings, I would like to describe how this channel is modeled in neutrino interaction generators.
A Laboratory Exercise Using a Physical Model for Demonstrating Countercurrent Heat Exchange
Loudon, Catherine; Davis-Berg, Elizabeth C.; Botz, Jason T.
2012-01-01
A physical model was used in a laboratory exercise to teach students about countercurrent exchange mechanisms. Countercurrent exchange is the transport of heat or chemicals between fluids moving in opposite directions separated by a permeable barrier (such as blood within adjacent blood vessels flowing in opposite directions). Greater exchange of…
Conflict measures in cooperative exchange models of collective decision-making
van Assen, Marcel; Stokman, Frans; van Oosten, Reinier
2003-01-01
This study focuses on externalities of exchanges of voting positions in collective decision-making. Exchanges are represented by nonconstant two-person cooperative games. It is assumed that the rate of exchange is specified by the Raiffa-Kalai-Smorodinsky solution, and a model is specified to identi
A Laboratory Exercise Using a Physical Model for Demonstrating Countercurrent Heat Exchange
Loudon, Catherine; Davis-Berg, Elizabeth C.; Botz, Jason T.
2012-01-01
A physical model was used in a laboratory exercise to teach students about countercurrent exchange mechanisms. Countercurrent exchange is the transport of heat or chemicals between fluids moving in opposite directions separated by a permeable barrier (such as blood within adjacent blood vessels flowing in opposite directions). Greater exchange of…
Forecasting Stock Exchange Movements Using Artificial Neural Network Models and Hybrid Models
Güreşen, Erkam; Kayakutlu, Gülgün
Forecasting stock exchange rates is an important financial problem that is receiving increasing attention. During the last few years, a number of neural network models and hybrid models have been proposed for obtaining accurate prediction results, in an attempt to outperform the traditional linear and nonlinear approaches. This paper evaluates the effectiveness of neural network models; recurrent neural network (RNN), dynamic artificial neural network (DAN2) and the hybrid neural networks which use generalized autoregressive conditional heteroscedasticity (GARCH) and exponential generalized autoregressive conditional heteroscedasticity (EGARCH) to extract new input variables. The comparison for each model is done in two view points: MSE and MAD using real exchange daily rate values of Istanbul Stock Exchange (ISE) index XU10).
Self-Service Banking: Value Creation Models and Information Exchange
Directory of Open Access Journals (Sweden)
Ragnvald Sannes
2001-01-01
Full Text Available This paper argues that most banks have failed to exploit the potential of self-service banking because they base their service design on an incomplete business model for self-service. A framework for evaluation of self-service banking concepts is developed on the basis of Stabell and Fjeldstad's three value configurations. The value network and the value shop are consistent with self-service banking while the value chain is inappropriate. The impact of the value configurations on information exchange and self-service functionality is discussed, and a framework for design of such services proposed. Current self-service banking practices are compared to the framework, and it is concluded that current practice matches the concept of a value network and not the value shop. However, current practices are only a partial implementation of a value network-based self-service banking concept.
Enterprise Networks for Competences Exchange: A Simulation Model
Remondino, Marco; Pironti, Marco; Pisano, Paola
A business process is a set of logically related tasks performed to achieve a defined business and related to improving organizational processes. Process innovation can happen at various levels: incrementally, redesign of existing processes, new processes. The knowledge behind process innovation can be shared, acquired, changed and increased by the enterprises inside a network. An enterprise can decide to exploit innovative processes it owns, thus potentially gaining competitive advantage, but risking, in turn, that other players could reach the same technological levels. Or it could decide to share it, in exchange for other competencies or money. These activities could be the basis for a network formation and/or impact the topology of an existing network. In this work an agent based model is introduced (E3), aiming to explore how a process innovation can facilitate network formation, affect its topology, induce new players to enter the market and spread onto the network by being shared or developed by new players.
Isotope exchange kinetics in metal hydrides I : TPLUG model.
Energy Technology Data Exchange (ETDEWEB)
Larson, Rich; James, Scott Carlton; Nilson, Robert H.
2011-05-01
A one-dimensional isobaric reactor model is used to simulate hydrogen isotope exchange processes taking place during flow through a powdered palladium bed. This simple model is designed to serve primarily as a platform for the initial development of detailed chemical mechanisms that can then be refined with the aid of more complex reactor descriptions. The one-dimensional model is based on the Sandia in-house code TPLUG, which solves a transient set of governing equations including an overall mass balance for the gas phase, material balances for all of the gas-phase and surface species, and an ideal gas equation of state. An energy equation can also be solved if thermodynamic properties for all of the species involved are known. The code is coupled with the Chemkin package to facilitate the incorporation of arbitrary multistep reaction mechanisms into the simulations. This capability is used here to test and optimize a basic mechanism describing the surface chemistry at or near the interface between the gas phase and a palladium particle. The mechanism includes reversible dissociative adsorptions of the three gas-phase species on the particle surface as well as atomic migrations between the surface and the bulk. The migration steps are more general than those used previously in that they do not require simultaneous movement of two atoms in opposite directions; this makes possible the creation and destruction of bulk vacancies and thus allows the model to account for variations in the bulk stoichiometry with isotopic composition. The optimization code APPSPACK is used to adjust the mass-action rate constants so as to achieve the best possible fit to a given set of experimental data, subject to a set of rigorous thermodynamic constraints. When data for nearly isothermal and isobaric deuterium-to-hydrogen (D {yields} H) and hydrogen-to-deuterium (H {yields} D) exchanges are fitted simultaneously, results for the former are excellent, while those for the latter show
Isotope exchange kinetics in metal hydrides I : TPLUG model.
Energy Technology Data Exchange (ETDEWEB)
Larson, Rich; James, Scott Carlton; Nilson, Robert H.
2011-05-01
A one-dimensional isobaric reactor model is used to simulate hydrogen isotope exchange processes taking place during flow through a powdered palladium bed. This simple model is designed to serve primarily as a platform for the initial development of detailed chemical mechanisms that can then be refined with the aid of more complex reactor descriptions. The one-dimensional model is based on the Sandia in-house code TPLUG, which solves a transient set of governing equations including an overall mass balance for the gas phase, material balances for all of the gas-phase and surface species, and an ideal gas equation of state. An energy equation can also be solved if thermodynamic properties for all of the species involved are known. The code is coupled with the Chemkin package to facilitate the incorporation of arbitrary multistep reaction mechanisms into the simulations. This capability is used here to test and optimize a basic mechanism describing the surface chemistry at or near the interface between the gas phase and a palladium particle. The mechanism includes reversible dissociative adsorptions of the three gas-phase species on the particle surface as well as atomic migrations between the surface and the bulk. The migration steps are more general than those used previously in that they do not require simultaneous movement of two atoms in opposite directions; this makes possible the creation and destruction of bulk vacancies and thus allows the model to account for variations in the bulk stoichiometry with isotopic composition. The optimization code APPSPACK is used to adjust the mass-action rate constants so as to achieve the best possible fit to a given set of experimental data, subject to a set of rigorous thermodynamic constraints. When data for nearly isothermal and isobaric deuterium-to-hydrogen (D {yields} H) and hydrogen-to-deuterium (H {yields} D) exchanges are fitted simultaneously, results for the former are excellent, while those for the latter show
Modelling system level health information exchange: an ontological approach.
McMurray, J; Zhu, L; McKillop, I; Chen, H
2015-01-01
Investment of resources to purposively improve the movement of information between health system providers is currently made with imperfect information. No inventories of system-level digital information flows currently exist, nor do measures of inter-organizational electronic information. exchange (HIE). Using Protégé 4, an open-source OWL Web ontology language editor and knowledge-based framework we formalized a model that decomposes inter-organizational electronic health information flow into derivative concepts such as diversity, breadth, volume, structure, standardization and connectivity. Self-reported data from a regional health system is used to measure HIE; the ontology identifies providers with low and high HIE, useful for planners, and using a related database is used to monitor data quality.
Phase transition in kinetic exchange opinion models with independence
Crokidakis, Nuno
2014-01-01
In this work we study the critical behavior of a three-state ($+1$, $-1$, $0$) opinion model with independence. Each agent has a probability $q$ to act as independent, i.e., he/she can choose his/her opinion independently of the opinions of the other agents. On the other hand, with the complementary probability $1-q$ the agent interacts with a randomly chosen individual through a kinetic exchange. Our analytical and numerical results show that the independence mechanism acts as a noise that induce an order-disorder transition at critical points $q_{c}$ that depend on the individuals' flexibility. For a special value of this flexibility the system undergoes a transition to an absorbing state with all opinions $0$.
Modelling the ion-exchange equilibrium in nanoporous materials
Directory of Open Access Journals (Sweden)
M. Lukšič
2012-06-01
Full Text Available Distribution of a two component electrolyte mixture between the model adsorbent and a bulk aqueous electrolyte solution was studied using the replica Ornstein-Zernike theory and the grand canonical Monte Carlo method. The electrolyte components were modelled to mimic the HCl/NaCl and HCl/CaCl2 mixtures, respectively. The matrix, invaded by the primitive model electrolyte mixture, was formed from monovalent negatively charged spherical obstacles. The solution was treated as a continuous dielectric with the properties of pure water. Comparison of the pair distribution functions (obtained by the two methods between the various ionic species indicated a good agreement between the replica Ornstein-Zernike results and machine calculations. Among thermodynamic properties, the mean activity coefficient of the invaded electrolyte components was calculated. Simple model for the ion-exchange resin was proposed. The selectivity calculations yielded qualitative agreement with the following experimental observations: (i selectivity increases with the increasing capacity of the adsorbent (matrix concentration, (ii the adsorbent is more selective for the ion having higher charge density if its fraction in mixture is smaller.
A heat transfer model of a horizontal ground heat exchanger
Mironov, R. E.; Shtern, Yu. I.; Shtern, M. Yu.; Rogachev, M. S.
2016-04-01
Ground-source heat pumps are gaining popularity in Eastern Europe, especially those which are using the horizontal ground heat exchanger (GHX). Due to the difficulty of accessing GHX after the installation, materials and the quality of the installation must satisfy the very high requirements. An inaccurate calculation of GHX can be the reason of a scarcity of heat power in a crucial moment. So far, there isn't any appropriate mathematical description of the horizontal GHX which takes into account the mutual influence of GHX pipes on each other. To solve this problem we used the temperature wave approach. As a result, a mathematical model which describes the dependence of the heat transfer rate per unit length of the horizontal GHX pipe on the thermal properties of soil, operating time of GHX and the distance between pipes was obtained. Using this model, heat transfer rates per unit length of a horizontal GHX were plotted as functions of the distance between pipes and operating time. The modeling shows that heat transfer rates decreases rapidly with the distance between pipes lower then 2 meters. After the launch of heat pump, heat power of GHX is reduced during the first 20 - 30 days and get steady after that. The obtained results correlate with experimental data. Therefore the proposed mathematical model can be used to design a horizontal GHX with the optimal characteristics, and predict its capability during operation.
Mathematical and Computational Modeling of Polymer Exchange Membrane Fuel Cells
Ulusoy, Sehribani
results showed that the fuel performance can be improved by using flow field designs alleviating the reactant depletion along the channels and supplying more uniform reactant distribution. Stepped flow field was found to show better performance when compared to straight and tapered ones. ANSYS FLUENT model is evaluated in terms of predicting the two phase flow in the fuel cell components. It is proposed that it is not capable of predicting the entire fuel cell polarization due to the lack of agglomerate catalyst layer modeling and well-established two-phase flow modeling. Along with the comprehensive modeling efforts, also an analytical model has been computed by using MathCAD and it is found that this simpler model is able to predict the performance in a general trend according to the experimental data obtained for a new novel membrane. Therefore, it can be used for robust prediction of the cell performance at different operating conditions such as temperature and pressure, and the electrochemical properties such as the catalyst loading, the exchange current density and the diffusion coefficients of the reactants. In addition to the modeling efforts, this thesis also presents a very comprehensive literature review on the models developed in the literature so far, the modeling efforts in fuel cell sandwich including membrane, catalyst layer and gas diffusion layer and fuel cell model properties. Moreover, a summary of possible directions of research in fuel cell analysis and computational modeling has been presented.
2013-01-01
Based on the relevant data from 1985 to 2010, this thesis uses a quantile regression model to make an empirical research about the effect of GDP and exchange rate on foreign exchange reserve. The findings show that: Both GDP and exchange rate have a remarkable influence on the size of foreign exchange reserve and the effect of exchange rate on foreign exchange reserve is higher than GDP at mean place and middle and lower quantile, smaller than GDP at higher quantile. At all the examined quant...
Minimal model quantification of pulmonary gas exchange in intensive care patients
DEFF Research Database (Denmark)
Karbing, Dan Stieper; Kjærgaard, Søren; Andreassen, Hans Steen
2011-01-01
Mathematical models are required to describe pulmonary gas exchange. The challenge remains to find models which are complex enough to describe physiology and simple enough for clinical practice. This study aimed at finding the necessary 'minimal' modeling complexity to represent the gas exchange ...
Model-free measurement of exchange market pressure
F.J.G.M. Klaassen; H. Jager
2006-01-01
If there is exchange market pressure (EMP), monetary authorities can use the interest rate and official interventions to offset this depreciation tendency, or they can let the exchange rate change. We introduce a new approach to derive how these three variables should be combined to measure EMP. Thi
Low GWP Refrigerants Modelling Study for a Room Air Conditioner Having Microchannel Heat Exchangers
Energy Technology Data Exchange (ETDEWEB)
Shen, Bo [ORNL; Bhandari, Mahabir S [ORNL
2016-01-01
Microchannel heat exchangers (MHX) have found great successes in residential and commercial air conditioning applications, being compact heat exchangers, to reduce refrigerant charge and material cost. This investigation aims to extend the application of MHXs in split, room air conditioners (RAC), per fundamental heat exchanger and system modelling. For this paper, microchannel condenser and evaporator models were developed, using a segment-to-segment modelling approach. The microchannel heat exchanger models were integrated to a system design model. The system model is able to predict the performance indices, such as cooling capacity, efficiency, sensible heat ratio, etc. Using the calibrated system and heat exchanger models, we evaluated numerous low GWP (global warming potential) refrigerants. The predicted system performance indices, e.g. cooling efficiency, compressor discharge temperature, and required compressor displacement volume etc., are compared. Suitable replacements for R22 and R-410A for the room air conditioner application are recommended.
An exchange rate determination model for central banks＇interventions in financial markets
Institute of Scientific and Technical Information of China (English)
林浚清; 黄祖辉; 战明华
2002-01-01
We establish an exchange rate determination model for central banks' interventiorm in financial markets.The model shows that central banks can adjuct exchange rate by several policy instruments and that different instruments may have different effects on exchange rate determination.It specifies potetial policy instruments for central banks as well as their policy effects.Based on these effects,feasible matches of policy instruments in contingent intervention are put forth.
An exchange rate determination model for central banks' interventions in financial markets
Institute of Scientific and Technical Information of China (English)
林浚清; 黄祖辉; 战明华
2002-01-01
We establish an exchange rate determination model for central banks' in terventions in financial markets. The model shows that central banks can adjust exchange rate by several policy instruments and that different instruments may h ave different effects on exchange rate determination. It specifies potential pol icy instruments for central banks as well as their policy effects. Based on thes e effects, feasible matches of policy instruments in contingent intervention are put forth.
Institute of Scientific and Technical Information of China (English)
Jinglan Wu; Pengfei Jiao; Wei Zhuang; Jingwei Zhou; Hanjie Ying
2016-01-01
L-phenylalanine, one of the nine essential amino acids for the human body, is extensively used as an ingredient in food, pharmaceutical and nutrition industries. A suitable equilibrium model is required for purification of L-phenylalanine based on ion-exchange chromatography. In this work, the equilibrium uptake of L-phenylalanine on a strong acid-cation exchanger SH11 was investigated experimental y and theoretical y. A modified Donnan ion-exchange (DIX) model, which takes the activity into account, was established to predict the uptake of L-phenyl-alanine at various solution pH values. The model parameters including selectivity and mean activity coefficient in the resin phase are presented. The modified DIX model is in good agreement with the experimental data. The optimum operating pH value of 2.0, with the highest L-phenylalanine uptake on the resin, is predicted by the model. This basic information combined with the general mass transfer model wil lay the foundation for the prediction of dynamic behavior of fixed bed separation process.
Simulating Replica Exchange: Markov State Models, Proposal Schemes, and the Infinite Swapping Limit.
Zhang, Bin W; Dai, Wei; Gallicchio, Emilio; He, Peng; Xia, Junchao; Tan, Zhiqiang; Levy, Ronald M
2016-08-25
Replica exchange molecular dynamics is a multicanonical simulation technique commonly used to enhance the sampling of solvated biomolecules on rugged free energy landscapes. While replica exchange is relatively easy to implement, there are many unanswered questions about how to use this technique most efficiently, especially because it is frequently the case in practice that replica exchange simulations are not fully converged. A replica exchange cycle consists of a series of molecular dynamics steps of a set of replicas moving under different Hamiltonians or at different thermodynamic states followed by one or more replica exchange attempts to swap replicas among the different states. How the replica exchange cycle is constructed affects how rapidly the system equilibrates. We have constructed a Markov state model of replica exchange (MSMRE) using long molecular dynamics simulations of a host-guest binding system as an example, in order to study how different implementations of the replica exchange cycle can affect the sampling efficiency. We analyze how the number of replica exchange attempts per cycle, the number of MD steps per cycle, and the interaction between the two parameters affects the largest implied time scale of the MSMRE simulation. The infinite swapping limit is an important concept in replica exchange. We show how to estimate the infinite swapping limit from the diagonal elements of the exchange transition matrix constructed from MSMRE "simulations of simulations" as well as from relatively short runs of the actual replica exchange simulations.
Plate Fin Heat Exchanger Model with Axial Conduction and Variable Properties
Hansen, B J; Klebaner, A; 10.1063/1.4706971
2012-01-01
Future superconducting radio frequency (SRF) cavities, as part of Project X at Fermilab, will be cooled to superfluid helium temperatures by a cryogenic distribution system supplying cold supercritical helium. To reduce vapor fraction during the final Joule-Thomson (J-T) expansion into the superfluid helium cooling bath, counter-flow, plate-fin heat exchangers will be utilized. Due to their compact size and ease of fabrication, plate-fin heat exchangers are an effective option. However, the design of compact and high-effectiveness cryogenic heat exchangers operating at liquid helium temperatures requires consideration of axial heat conduction along the direction of flow, in addition to variable fluid properties. Here we present a numerical model that includes the effects of axial conduction and variable properties for a plate fin heat exchanger. The model is used to guide design decisions on heat exchanger material choice and geometry. In addition, the J-T expansion process is modeled with the heat exchanger ...
Bayesian analysis for exponential random graph models using the adaptive exchange sampler
Jin, Ick Hoon
2013-01-01
Exponential random graph models have been widely used in social network analysis. However, these models are extremely difficult to handle from a statistical viewpoint, because of the existence of intractable normalizing constants. In this paper, we consider a fully Bayesian analysis for exponential random graph models using the adaptive exchange sampler, which solves the issue of intractable normalizing constants encountered in Markov chain Monte Carlo (MCMC) simulations. The adaptive exchange sampler can be viewed as a MCMC extension of the exchange algorithm, and it generates auxiliary networks via an importance sampling procedure from an auxiliary Markov chain running in parallel. The convergence of this algorithm is established under mild conditions. The adaptive exchange sampler is illustrated using a few social networks, including the Florentine business network, molecule synthetic network, and dolphins network. The results indicate that the adaptive exchange algorithm can produce more accurate estimates than approximate exchange algorithms, while maintaining the same computational efficiency.
Minimal model quantification of pulmonary gas exchange in intensive care patients
DEFF Research Database (Denmark)
Karbing, Dan Stieper; Kjærgaard, Søren; Andreassen, Steen
2011-01-01
of both oxygen and carbon dioxide. Three models of varying complexity were compared for their ability to fit measured data from intensive care patients and to provide adequate description of patients' gas exchange abnormalities. Pairwise F-tests showed that a two parameter model provided superior fit......Mathematical models are required to describe pulmonary gas exchange. The challenge remains to find models which are complex enough to describe physiology and simple enough for clinical practice. This study aimed at finding the necessary 'minimal' modeling complexity to represent the gas exchange...... to patient data compared to a shunt only model (p...
Land-use change arising from rural land exchange : an agent-based simulation model
Bakker, Martha M.; Alam, Shah Jamal; van Dijk, Jerry; Rounsevell, Mark D. A.
2015-01-01
Land exchange can be a major factor driving land-use change in regions with high pressure on land, but is generally not incorporated in land-use change models. Here we present an agent-based model to simulate land-use change arising from land exchange between multiple agent types representing farmer
A Model for Trading the Foreign Exchange Market
African Journals Online (AJOL)
PROF. OLIVER OSUAGWA
2015-06-01
Jun 1, 2015 ... The electronic Foreign Exchange (FOREX) market where currencies are bought and sold has .... the signal and .... indicator computations to generating trading ..... [4] Sher, G. I., (2012), Evolving Chart Pattern Sensitive Neural ...
Dynamic modeling of heat exchanger tube-to-support interaction
Energy Technology Data Exchange (ETDEWEB)
Azizian, R.; Mureithi, N.W.; Sawadog, T.P.; Pettigrew, M.J. [Ecole Polytechnique, Dept. of Mechanical Engineering, BWC/AECL/NSERC Chair of Fluid-Structure Interaction, Montreal, Quebec (Canada)
2009-07-01
Tube arrays in steam generators and heat exchangers operating in two-phase cross-flow are subjected sometimes to strong vibration due mainly to turbulence buffeting and fluidelastic forces. This can lead to tube damage by fatigue or fretting wear. A computer implementation of a fluidelastic instability model is proposed to determine with improved accuracy the fluidelastic forces and hence the critical instability flow velocity. Usually the fluidelastic instability is 'predicted', using the Connors relation with K=3. While the value of K can be determined experimentally to get an accurate prediction of the instability, the Connors relation does not allow good estimation of the fluid forces. Consequently the RMS value of the magnitude of vibration of the tube bundle, necessary to evaluate the work rate and the tube wear is only poorly estimated. The fluidelastic instability analysis presented here is based on the quasi-steady model, originally developed for single phase flow. The fluid forces are expressed in terms of the quasi-static drag and lift force coefficients and their derivatives which are determined experimentally. The forces also depend on the tube displacement and velocity. In the computer code ABAQUS, the fluid forces are provided in the user subroutines VDLOAD or VUEL. A typical simulation of the vibration of a single flexible tube within an array in two phase cross-flow is done in ABAQUS and the results are compared with the experimental measurements for a tube with similar physical properties. For a cantilever tube, in two phase cross-flow of void fraction 60 percent, the numerical critical flow velocity was 2.0 m/s compared to 1.8 m/s obtained experimentally. The relative error was 5 percent compared to 26.6 percent for the Connors relation with K=3. The simulation of the vibration of a typical tube in a steam generator is also presented. The numerical results show good agreement with experimental measurements. (author)
A General Model for Cost Estimation in an Exchange
Directory of Open Access Journals (Sweden)
Benzion Barlev
2014-03-01
Full Text Available Current Generally Accepted Accounting Principles (GAAP state that the cost of an asset acquired for cash is the fair value (FV of the amount surrendered, and that of an asset acquired in a non-monetary exchange is the FV of the asset surrendered or, if it is more “clearly evident,” the FV of the acquired asset. The measurement method prescribed for a non-monetary exchange ignores valuable information about the “less clearly evident” asset. Thus, we suggest that the FV in any exchange be measured by the weighted average of the exchanged assets’ FV estimations, where the weights are the inverse of the variances’ estimations. This alternative valuation process accounts for the uncertainty involved in estimating the FV of each of the asset in the exchange. The proposed method suits all types of exchanges: monetary and non-monetary. In a monetary transaction, the weighted average equals the cash paid because the variance of its FV is nil.
Khan, T.; Agnan, Y.; Obrist, D.; Selin, N. E.; Urban, N. R.; Wu, S.; Perlinger, J. A.
2015-12-01
Inadequate representation of process-based mechanisms of exchange behavior of elemental mercury (Hg0) and decoupled treatment of deposition and emission are two major limitations of parameterizations of atmosphere-surface exchange flux commonly incorporated into chemical transport models (CTMs). Of nineteen CTMs for Hg0 exchange we reviewed (ten global, nine regional), eight global and seven regional models have decoupled treatment of Hg0 deposition and emission, two global models include no parameterization to account for emission, and the remaining two regional models include coupled deposition and emission parameterizations (i.e., net atmosphere-surface exchange). The performance of atmosphere-surface exchange parameterizations in CTMs depends on parameterization uncertainty (in terms of both accuracy and precision) and feasibility of implementation. We provide a comparison of the performance of three available parameterizations of net atmosphere-surface exchange. To evaluate parameterization accuracy, we compare predicted exchange fluxes to field measurements conducted over a variety of surfaces compiled in a recently developed global database of terrestrial Hg0 surface-atmosphere exchange flux measurements. To assess precision, we estimate the sensitivity of predicted fluxes to the imprecision in parameter input values, and compare this sensitivity to that derived from analysis of the global Hg0 flux database. Feasibility of implementation is evaluated according to the availability of input parameters, computational requirements, and the adequacy of uncertainty representation. Based on this assessment, we provide suggestions for improved treatment of Hg0 net exchange processes in CTMs.
Directory of Open Access Journals (Sweden)
G. M. Wolfe
2010-09-01
Full Text Available We present the Chemistry of Atmosphere-Forest Exchange (CAFE model, a vertically-resolved 1-D chemical transport model designed to probe the details of near-surface reactive gas exchange. CAFE integrates all key processes, including turbulent diffusion, emission, deposition and chemistry, throughout the forest canopy and mixed layer. It is the first model of its kind to incorporate the Master Chemical Mechanism (MCM and a suite of reactions for the oxidation of monoterpenes and sesquiterpenes, providing a more comprehensive description of the oxidative chemistry occurring within and above the forest. We use CAFE to simulate a young Ponderosa pine forest in the Sierra Nevada, CA. Utilizing meteorological constraints from the BEARPEX-2007 field campaign, we assess the sensitivity of modeled fluxes to parameterizations of diffusion, laminar sublayer resistance and radiation extinction. To characterize the general chemical environment of this forest, we also present modeled mixing ratio profiles of biogenic hydrocarbons, hydrogen oxides and reactive nitrogen. The vertical profiles of these species demonstrate a range of structures and gradients that reflect the interplay of physical and chemical processes within the forest canopy, which can influence net exchange.
Directory of Open Access Journals (Sweden)
G. M. Wolfe
2011-01-01
Full Text Available We present the Chemistry of Atmosphere-Forest Exchange (CAFE model, a vertically-resolved 1-D chemical transport model designed to probe the details of near-surface reactive gas exchange. CAFE integrates all key processes, including turbulent diffusion, emission, deposition and chemistry, throughout the forest canopy and mixed layer. CAFE utilizes the Master Chemical Mechanism (MCM and is the first model of its kind to incorporate a suite of reactions for the oxidation of monoterpenes and sesquiterpenes, providing a more comprehensive description of the oxidative chemistry occurring within and above the forest. We use CAFE to simulate a young Ponderosa pine forest in the Sierra Nevada, CA. Utilizing meteorological constraints from the BEARPEX-2007 field campaign, we assess the sensitivity of modeled fluxes to parameterizations of diffusion, laminar sublayer resistance and radiation extinction. To characterize the general chemical environment of this forest, we also present modeled mixing ratio profiles of biogenic hydrocarbons, hydrogen oxides and reactive nitrogen. The vertical profiles of these species demonstrate a range of structures and gradients that reflect the interplay of physical and chemical processes within the forest canopy, which can influence net exchange.
Multiobjective Optimization of Allocated Exchange Portfolio: Model and Solution—A Case Study in Iran
Directory of Open Access Journals (Sweden)
Mostafa Ekhtiari
2014-01-01
Full Text Available This paper presents a triobjective model for optimization of allocated exchange portfolio. The objectives of this model are minimizing risk and investment initial cost (by adopting two synchronic policies of buying and selling assets and maximizing return, to optimize allocated portfolios (APs. In an AP, an investor by considering previous investment experiences and market conditions selects the within portfolio assets. Then, considering proposed model, the assets proportion of AP is optimized for a limited time horizon. In optimizing a multiobjective problem of an AP, risk and return objectives are measured on the basis of standard deviation of assets dairy return and dairy return mean within AP assets, respectively. We present a set of interobjectives trade-offs along with an analysis of Iran Melli bank investment in an exchange AP, using Weighted Global Criterion (WGC method with assumption p=1, 2, and ∞ to optimize the proposed model. Results of WGC model (in all p=1, 2 and ∞ represent that US dollar exchange in comparison with other exchanges, was rather the fewest exchange proportion in Iran Melli bank exchange AP which this is consistent with Iran exchange investment policy of more concentration on other exchanges.
A simple and accurate numerical network flow model for bionic micro heat exchangers
Energy Technology Data Exchange (ETDEWEB)
Pieper, M.; Klein, P. [Fraunhofer Institute (ITWM), Kaiserslautern (Germany)
2011-05-15
Heat exchangers are often associated with drawbacks like a large pressure drop or a non-uniform flow distribution. Recent research shows that bionic structures can provide possible improvements. We considered a set of such structures that were designed with M. Hermann's FracTherm {sup registered} algorithm. In order to optimize and compare them with conventional heat exchangers, we developed a numerical method to determine their performance. We simulated the flow in the heat exchanger applying a network model and coupled these results with a finite volume method to determine the heat distribution in the heat exchanger. (orig.)
Forecasting RMB Exchange Rate Based on a Nonlinear Combination Model of ARFIMA, SVM, and BPNN
Directory of Open Access Journals (Sweden)
Chi Xie
2015-01-01
Full Text Available There are various models to predict financial time series like the RMB exchange rate. In this paper, considering the complex characteristics of RMB exchange rate, we build a nonlinear combination model of the autoregressive fractionally integrated moving average (ARFIMA model, the support vector machine (SVM model, and the back-propagation neural network (BPNN model to forecast the RMB exchange rate. The basic idea of the nonlinear combination model (NCM is to make the prediction more effective by combining different models’ advantages, and the weight of the combination model is determined by a nonlinear weighted mechanism. The RMB exchange rate against US dollar (RMB/USD and the RMB exchange rate against Euro (RMB/EUR are used as the empirical examples to evaluate the performance of NCM. The results show that the prediction performance of the nonlinear combination model is better than the single models and the linear combination models, and the nonlinear combination model is suitable for the prediction of the special time series, such as the RMB exchange rate.
Application of models for exchange of electronic documents in complex administrative services
Glavev, Victor
2015-11-01
The report presents application of models for exchange of electronic documents between different administrations in government and business sectors. It shows the benefits of implementing electronic exchange of documents between different local offices of one administration in government sector such as a municipality and the way it is useful for implementing complex administrative services.
Application of models for exchange of electronic documents in complex administrative services
Energy Technology Data Exchange (ETDEWEB)
Glavev, Victor
2015-11-30
The report presents application of models for exchange of electronic documents between different administrations in government and business sectors. It shows the benefits of implementing electronic exchange of documents between different local offices of one administration in government sector such as a municipality and the way it is useful for implementing complex administrative services.
Champagne, Tiffany
2013-01-01
The purpose of this dissertation research was to critically examine the development of community-based health information exchanges (HIEs) and to comparatively analyze the various models of exchanges in operation today nationally. Specifically this research sought to better understand several aspects of HIE: policy influences, organizational…
Phenomenological Behavior-Exchange Models of Marital Success.
Gottman, John; And Others
The objective of two studies was to devise an assessment procedure for the evaluation of therapy with distressed marriages. An extension of behavior exchange theory was proposed to include phenomenological ratings by the couple of the intent of messages sent and the impact of messages received. Convergent criteria were used to select 14…
Stock Prices and the Monetrary Model of Exchange Rate: An Empirical Investigation.
Broom, S.; Morley, B.
2003-01-01
This paper develops an alternative version of the monetary model of exchange rate determination, which incorporates a stock price measure. This model is then tested using data from Canada and the USA, applying the cointegration and error correction methodology. In contrast to many previous tests of the monetary model, this version produces evidence of cointegration and stock prices have a highly significant effect on the exchange rate in both the short and long run. In addition the restricted...
Directory of Open Access Journals (Sweden)
Dinh An Nguyen
2012-07-01
Full Text Available Many of the Proton Exchange Membrane Fuel Cell (PEMFC models proposed in the literature consist of mathematical equations. However, they are not adequately practical for simulating power systems. The proposed model takes into account phenomena such as activation polarization, ohmic polarization, double layer capacitance and mass transport effects present in a PEM fuel cell. Using electrical analogies and a mathematical modeling of PEMFC, the circuit model is established. To evaluate the effectiveness of the circuit model, its static and dynamic performances under load step changes are simulated and compared to the numerical results obtained by solving the mathematical model. Finally, the applicability of our model is demonstrated by simulating a practical system.
Nonlinear Inverse Problem for an Ion-Exchange Filter Model: Numerical Recovery of Parameters
Directory of Open Access Journals (Sweden)
Balgaisha Mukanova
2015-01-01
Full Text Available This paper considers the problem of identifying unknown parameters for a mathematical model of an ion-exchange filter via measurement at the outlet of the filter. The proposed mathematical model consists of a material balance equation, an equation describing the kinetics of ion-exchange for the nonequilibrium case, and an equation for the ion-exchange isotherm. The material balance equation includes a nonlinear term that depends on the kinetics of ion-exchange and several parameters. First, a numerical solution of the direct problem, the calculation of the impurities concentration at the outlet of the filter, is provided. Then, the inverse problem, finding the parameters of the ion-exchange process in nonequilibrium conditions, is formulated. A method for determining the approximate values of these parameters from the impurities concentration measured at the outlet of the filter is proposed.
Directory of Open Access Journals (Sweden)
Pisit Leeahtam
2011-10-01
Full Text Available The objectives of this study are to find the fitting model and dependence measures of both Thailand’s exchange rate and Malaysia’s exchange rate during, between, and after the World’s recent financial crises based on linear, nonlinear and empirical copula approaches.The results of the study confirm that the nonlinear model (NNTs is an appropriate model for Thailand’s exchange rate return in percentage during the periods of 2008-2011but not for Malaysia’s exchange rate return. Based on empirical copula approach, the dependence measures are very small between Thailand’s exchange and Malaysia’s exchange. This seems to suggest that when global economy is affected by World’s financial crisis, the nonlinear approach should be used to predict Thailand’s exchange rate return in percentage. In addition, it suggests that both the nonlinear and linear approaches should be used to predict the Malaysia’s exchange rate return in percentage. Moreover, the relationship between the exchange rate of Thailand and that of Malaysia is not strong.This is also true for the currencies of both countries.
MODELING THE CURRENCY EXCHANGE RATE. METHODS AND PRINCIPLES
Suslov, Mark; Tregub, Ilona
2015-01-01
Since currency market is strongly and rapidly developing then it becomes more attractive area for investments, but, also, economic conditions force almost everyone be more financially educated and ready for changes in economic conditions. Currency is the money we pay for the goods and services in our country, but some of them are importing to our country or expressed in foreign currency values. Unfortunately, nobody can predict exact exchange rate, but there is a possibility to get ready for ...
U.S. Environmental Protection Agency — This dataset provides the city-specific air exchange rate measurements, modeled, literature-based as well as housing characteristics. This dataset is associated with...
Modeling inflation rates and exchange rates in Ghana: application of multivariate GARCH models
Nortey, Ezekiel NN; Ngoh, Delali D; Doku-Amponsah, Kwabena; Ofori-Boateng, Kenneth
2015-01-01
This paper was aimed at investigating the volatility and conditional relationship among inflation rates, exchange rates and interest rates as well as to construct a model using multivariate GARCH DCC and BEKK models using Ghana data from January 1990 to December 2013. The study revealed that the cumulative depreciation of the cedi to the US dollar from 1990 to 2013 is 7,010.2% and the yearly weighted depreciation of the cedi to the US dollar for the period is 20.4%. There was evidence that, t...
Modeling inflation rates and exchange rates in Ghana: application of multivariate GARCH models
Nortey, Ezekiel NN; Ngoh, Delali D; Doku-Amponsah, Kwabena; Ofori-Boateng, Kenneth
2015-01-01
This paper was aimed at investigating the volatility and conditional relationship among inflation rates, exchange rates and interest rates as well as to construct a model using multivariate GARCH DCC and BEKK models using Ghana data from January 1990 to December 2013. The study revealed that the cumulative depreciation of the cedi to the US dollar from 1990 to 2013 is 7,010.2% and the yearly weighted depreciation of the cedi to the US dollar for the period is 20.4%. There was evidence that, t...
MODELING ROMANIAN EXCHANGE RATE EVOLUTION WITH GARCH, TGARCH, GARCH- IN MEAN MODELS
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Cociuba Mihail Ioan
2011-07-01
Full Text Available In this paper we analyze the return of exchange rate in order to test and analyze the best models which are capable of forecasting accurately there evolution. We apply the GARCH family models on the exchange rate return in order to obtain the best models for there volatility. Financial time series often exhibit abnormal characteristics, such as: serial correlation, non-stationarity, heteroskedasticity, asymmetric and are leptokurtic. Due to these characteristics autoregressive models such as autoregressive (AR, moving average (MA and autoregressive integrated moving-average (ARIMA are unable to capture the evolution of financial series, to represent the special characteristic of financial a hole new range of models where developed : generalized autoregressive conditional heteroskedasticity (GARCH, which are taking into account the heteroskedasticity of the errors term. The GARCH model allows for lags in the autoregressive term and in the variance term incorporates lags of the previous variance and also for the errors. The GARCH family has expanded in the last years in order to incorporate for asymmetry (Threshold GARCH, TGARCH and risk (GARCH -in Mean. We analyze the evolution of exchange rate for: Euro/RON, dollar/RON, yen/RON, British pound/RON, Swiss franc/RON for a period of five years from 2005 till 2011, we observe that in the analyzed period there are 2 sub-periods: 2005-2007 in which the RON appreciated constantly, and 2007-2011 in which the trend is depreciation for RON in respect to all the five currencies and the volatility was sensible higher than in the previous period. We obtain the returns on exchange rate by using the following transformation r=log(curs_t-log(curs_t-1; the five analyzed series display an leptokurtic and asymmetric behavioral. Using the GARCH, TGARCH and GARCH-in Mean models, we explicit the evolution of volatility throw this period, choosing the best model using the following : minimizing the value of the sum of
Ab initio state-specific N2 + O dissociation and exchange modeling for molecular simulations
Luo, Han; Kulakhmetov, Marat; Alexeenko, Alina
2017-02-01
Quasi-classical trajectory (QCT) calculations are used in this work to calculate state-specific N2(X1Σ ) +O(3P ) →2 N(4S ) +O(3P ) dissociation and N2(X1Σ ) +O(3P ) →NO(X2Π ) +N(4S ) exchange cross sections and rates based on the 13A″ and 13A' ab initio potential energy surface by Gamallo et al. [J. Chem. Phys. 119, 2545-2556 (2003)]. The calculations consider translational energies up to 23 eV and temperatures between 1000 K and 20 000 K. Vibrational favoring is observed for dissociation reaction at the whole range of collision energies and for exchange reaction around the dissociation limit. For the same collision energy, cross sections for v = 30 are 4 to 6 times larger than those for the ground state. The exchange reaction has an effective activation energy that is dependent on the initial rovibrational level, which is different from dissociation reaction. In addition, the exchange cross sections have a maximum when the total collision energy (TCE) approaches dissociation energy. The calculations are used to generate compact QCT-derived state-specific dissociation (QCT-SSD) and QCT-derived state-specific exchange (QCT-SSE) models, which describe over 1 × 106 cross sections with about 150 model parameters. The models can be used directly within direct simulation Monte Carlo and computational fluid dynamics simulations. Rate constants predicted by the new models are compared to the experimental measurements, direct QCT calculations and predictions by other models that include: TCE model, Bose-Candler QCT-based exchange model, Macheret-Fridman dissociation model, Macheret's exchange model, and Park's two-temperature model. The new models match QCT-calculated and experimental rates within 30% under nonequilibrium conditions while other models under predict by over an order of magnitude under vibrationally-cold conditions.
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Minakhi Rout
2014-01-01
Full Text Available To alleviate the limitations of statistical based methods of forecasting of exchange rates, soft and evolutionary computing based techniques have been introduced in the literature. To further the research in this direction this paper proposes a simple but promising hybrid prediction model by suitably combining an adaptive autoregressive moving average (ARMA architecture and differential evolution (DE based training of its feed-forward and feed-back parameters. Simple statistical features are extracted for each exchange rate using a sliding window of past data and are employed as input to the prediction model for training its internal coefficients using DE optimization strategy. The prediction efficiency is validated using past exchange rates not used for training purpose. Simulation results using real life data are presented for three different exchange rates for one–fifteen months’ ahead predictions. The results of the developed model are compared with other four competitive methods such as ARMA-particle swarm optimization (PSO, ARMA-cat swarm optimization (CSO, ARMA-bacterial foraging optimization (BFO and ARMA-forward backward least mean square (FBLMS. The derivative based ARMA-FBLMS forecasting model exhibits worst prediction performance of the exchange rates. Comparisons of different performance measures including the training time of the all three evolutionary computing based models demonstrate that the proposed ARMA-DE exchange rate prediction model possesses superior short and long range prediction potentiality compared to others.
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Lu Fang-Yuan
2013-02-01
Full Text Available Based on the relevant data from 1985 to 2010, this thesis uses a quantile regression model to make an empirical research about the effect of GDP and exchange rate on foreign exchange reserve. The findings show that: Both GDP and exchange rate have a remarkable influence on the size of foreign exchange reserve and the effect of exchange rate on foreign exchange reserve is higher than GDP at mean place and middle and lower quantile, smaller than GDP at higher quantile. At all the examined quantiles elastic coefficients of GDP and exchange rate are positive and among them, the elastic coefficients of GDP present us a reverse "V" model with the conditional distribution altering from low to high, that is, the impact of GDP on foreign exchange reserve shows an increasing trend when the latter is smaller, but begins to decrease when the latter reaches to a certain level; the elastic coefficients of exchange rate at lower quantiles are bigger than that of higher quantiles.
Bi-directional exchange of ammonia in a pine forest ecosystem - a model sensitivity analysis
Moravek, Alexander; Hrdina, Amy; Murphy, Jennifer
2016-04-01
Ammonia (NH3) is a key component in the global nitrogen cycle and of great importance for atmospheric chemistry, neutralizing atmospheric acids and leading to the formation of aerosol particles. For understanding the role of NH3 in both natural and anthropogenically influenced environments, the knowledge of processes regulating its exchange between ecosystems and the atmosphere is essential. A two-layer canopy compensation point model is used to evaluate the NH3 exchange in a pine forest in the Colorado Rocky Mountains. The net flux comprises the NH3 exchange of leaf stomata, its deposition to leaf cuticles and exchange with the forest ground. As key parameters the model uses in-canopy NH3 mixing ratios as well as leaf and soil emission potentials measured at the site in summer 2015. A sensitivity analysis is performed to evaluate the major exchange pathways as well as the model's constraints. In addition, the NH3 exchange is examined for an extended range of environmental conditions, such as droughts or varying concentrations of atmospheric pollutants, in order to investigate their influence on the overall net exchange.
Herman, Cila; Chen, Yuwen
2006-08-01
A simplified model of heat transfer was developed to investigate the thermal behavior of heat exchangers and stack plates of thermoacoustic devices. The model took advantage of previous results describing the thermal behavior of the thermoacoustic core and heat transfer in oscillating flow to study the performance of heat exchangers attached to the core. The configuration considered is a flat tube (with a working fluid flowing in the tube) of the thickness of the stack plate attached to both ends of the stack plate. Geometrical and operational parameters as well as thermophysical properties of the heat exchangers, transport fluids in the heat exchangers, stack plate and the thermoacoustic working fluid were organized into dimensionless groups that allowed accounting for their impact on the performance of the heat exchangers. Two types of thermal boundary conditions were considered: constant temperature and constant heat flux along the heat exchanger tubes. Numerical simulations were carried out with the model introduced in the paper. The temperature distributions and heat fluxes near the edge of the stack plate were found to be nonlinear. The influence of system parameters on the thermal performance of the heat exchangers was analyzed.
Swat, M J; Moodie, S; Wimalaratne, S M; Kristensen, N R; Lavielle, M; Mari, A; Magni, P; Smith, M K; Bizzotto, R; Pasotti, L; Mezzalana, E; Comets, E; Sarr, C; Terranova, N; Blaudez, E; Chan, P; Chard, J; Chatel, K; Chenel, M; Edwards, D; Franklin, C; Giorgino, T; Glont, M; Girard, P; Grenon, P; Harling, K; Hooker, A C; Kaye, R; Keizer, R; Kloft, C; Kok, J N; Kokash, N; Laibe, C; Laveille, C; Lestini, G; Mentré, F; Munafo, A; Nordgren, R; Nyberg, H B; Parra-Guillen, Z P; Plan, E; Ribba, B; Smith, G; Trocóniz, I F; Yvon, F; Milligan, P A; Harnisch, L; Karlsson, M; Hermjakob, H; Le Novère, N
2015-06-01
The lack of a common exchange format for mathematical models in pharmacometrics has been a long-standing problem. Such a format has the potential to increase productivity and analysis quality, simplify the handling of complex workflows, ensure reproducibility of research, and facilitate the reuse of existing model resources. Pharmacometrics Markup Language (PharmML), currently under development by the Drug Disease Model Resources (DDMoRe) consortium, is intended to become an exchange standard in pharmacometrics by providing means to encode models, trial designs, and modeling steps.
Stationarity test with a direct test for heteroskedasticity in exchange rate forecasting models
Khin, Aye Aye; Chau, Wong Hong; Seong, Lim Chee; Bin, Raymond Ling Leh; Teng, Kevin Low Lock
2017-05-01
Global economic has been decreasing in the recent years, manifested by the greater exchange rates volatility on international commodity market. This study attempts to analyze some prominent exchange rate forecasting models on Malaysian commodity trading: univariate ARIMA, ARCH and GARCH models in conjunction with stationarity test on residual diagnosis direct testing of heteroskedasticity. All forecasting models utilized the monthly data from 1990 to 2015. Given a total of 312 observations, the data used to forecast both short-term and long-term exchange rate. The forecasting power statistics suggested that the forecasting performance of ARIMA (1, 1, 1) model is more efficient than the ARCH (1) and GARCH (1, 1) models. For ex-post forecast, exchange rate was increased from RM 3.50 per USD in January 2015 to RM 4.47 per USD in December 2015 based on the baseline data. For short-term ex-ante forecast, the analysis results indicate a decrease in exchange rate on 2016 June (RM 4.27 per USD) as compared with 2015 December. A more appropriate forecasting method of exchange rate is vital to aid the decision-making process and planning on the sustainable commodities' production in the world economy.
Comparison of Moving Boundary and Finite-Volume Heat Exchanger Models in the Modelica Language
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Adriano Desideri
2016-05-01
Full Text Available When modeling low capacity energy systems, such as a small size (5–150 kWel organic Rankine cycle unit, the governing dynamics are mainly concentrated in the heat exchangers. As a consequence, the accuracy and simulation speed of the higher level system model mainly depend on the heat exchanger model formulation. In particular, the modeling of thermo-flow systems characterized by evaporation or condensation requires heat exchanger models capable of handling phase transitions. To this aim, the finite volume (FV and the moving boundary (MB approaches are the most widely used. The two models are developed and included in the open-source ThermoCycle Modelica library. In this contribution, a comparison between the two approaches is presented. An integrity and accuracy test is designed to evaluate the performance of the FV and MB models during transient conditions. In order to analyze how the two modeling approaches perform when integrated at a system level, two organic Rankine cycle (ORC system models are built using the FV and the MB evaporator model, and their responses are compared against experimental data collected on an 11 kWel ORC power unit. Additionally, the effect of the void fraction value in the MB evaporator model and of the number of control volumes (CVs in the FV one is investigated. The results allow drawing general guidelines for the development of heat exchanger dynamic models involving two-phase flows.
A computational fluid dynamics model for designing heat exchangers based on natural convection
Dirkse, M.H.; Loon, van W.K.P.; Walle, van der T.; Speetjens, S.L.; Bot, G.P.A.
2006-01-01
A computational fluid dynamics model was created for the design of a natural convection shell-and-tube heat exchanger with baffles. The flow regime proved to be turbulent and this was modelled using the k¿¿ turbulence model. The features of the complex geometry were simplified considerably resulting
Dynamic Models of Learning That Characterize Parent-Child Exchanges Predict Vocabulary Growth
Ober, David R.; Beekman, John A.
2016-01-01
Cumulative vocabulary models for infants and toddlers were developed from models of learning that predict trajectories associated with low, average, and high vocabulary growth rates (14 to 46 months). It was hypothesized that models derived from rates of learning mirror the type of exchanges provided to infants and toddlers by parents and…
MODELING AN ION EXCHANGE PROCESS FOR CESIUM REMOVAL FROM ALKALINE RADIOACTIVE WASTE SOLUTIONS
Energy Technology Data Exchange (ETDEWEB)
Smith, F; Luther Hamm, L; Sebastian Aleman, S; Johnston Michael, J
2008-08-26
The performance of spherical Resorcinol-Formaldehyde ion-exchange resin for the removal of cesium from alkaline radioactive waste solutions has been investigated through computer modeling. Cesium adsorption isotherms were obtained by fitting experimental data using a thermodynamic framework. Results show that ion-exchange is an efficient method for cesium removal from highly alkaline radioactive waste solutions. On average, two 1300 liter columns operating in series are able to treat 690,000 liters of waste with an initial cesium concentration of 0.09 mM in 11 days achieving a decontamination factor of over 50,000. The study also tested the sensitivity of ion-exchange column performance to variations in flow rate, temperature and column dimensions. Modeling results can be used to optimize design of the ion exchange system.
A Comparison of the Monetary Model and Artificial Neural Networks in Exchange Rate Forecasting
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Filiz Ozkan
2012-01-01
Full Text Available Exchange value is one of the significant tools for investors in decision making. Since exchange values are volatile and they change within short periods, investors need an effective method to minimize the risk. This study compares the prediction performances of artificial neural networks, which is recently being used as an effective tool of prediction, and the monetary model, which is one of the methods to predict structural exchange rates. In this study exchange rates of Turkish Lira against US Dollar and Euro are predicted. In models, inflation levels for domestic and foreign countries, money supply, interest rates and economic indicators are used. The time period between 1986 and 2010 is covered for the USD and the time period between 1999 and 2010 is covered for the EU. Results of this study show that ANN, which is recently being used for the prediction problems, reached a high level prediction performance.
Forecasting TRY/USD Exchange Rate with Various Artificial Neural Network Models
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Cagatay Bal
2017-02-01
Full Text Available Exchange rate forecasting is one of the most common subjects among the forecasting problem field. Researchers and academicians from many different disciplines proposed various approaches for better exchange rate forecasting. In recent years, for solving the stated forecasting problem artificial neural networks have become successful tool to obtain solutions. Many different artificial neural networks have been used, developed and still developing for even better and trustable forecasts. In this study, TRY/USD exchange rate forecasting is modeled with different learning algorithms, activations functions and performance measures. Various Artificial Neural Network (ANN models for better forecasting were investigated, compared and the obtained forecasting results interpreted respectively. The results of the application show that Variable Learning Rate Backpropagation learning algorithm with tan-sigmoid activation function has the best performance for TRY/USD exchange rate forecasting.
Long Term Validity of Monetary Exchange Rate Model: Evidence from Turkey
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Ugur Ahmet
2014-03-01
Full Text Available In this study, it was analyzed if there is a long term relationship among the nominal exchange rate and monetary fundamentals within the periods of 1998:1-2011:2 in Turkey. This relationship has been analysed by using structural VAR (SVAR model. Besides, Granger causality test and Dolado-Lütkepohl Granger causality test were used to determine if there were a causality relationship among the nominal exchange rate and monetary fundamentals. As a result of the SVAR model, the relationship among the series related to nominal exchange rate and money supply, GDP, interest rate in Turkey in long term were not determined and at the end of causality tests, causality relationship among the nominal exchange rate and monetary fundamentals were not determined.
Gaiduk, Alex P.; Staroverov, Viktor N.
2012-02-01
The common way to obtain energies from Kohn-Sham exchange potentials is by using the Levy-Perdew virial relation. For potentials that are not functional derivatives (i.e., nearly all model exchange potentials in existence), this approach leads to energy expressions that lack translational and rotational invariance. We propose a method for constructing potential-based energy functionals that are free from these artifacts. It relies on the same line-integration technique that gives rise to the Levy-Perdew relation, but uses density scaling instead of coordinate scaling. The method is applicable to any exchange or correlation potential that depends on the density explicitly, and correctly recovers the parent energy functional from a functional derivative. To illustrate our approach we develop a properly invariant generalized gradient approximation for exchange starting from the model potential of van Leeuwen and Baerends.
Theoretical models for NO decomposition in Cu-exchanged zeolites
Tsekov, R
2015-01-01
A unified description of the catalytic effect of Cu-exchanged zeolites is proposed for the decomposition of NO. A general expression for the rate constant of NO decomposition is obtained by assuming that the rate-determining step consists of the transferring of a single atom associated with breaking of the N-O bond. The analysis is performed on the base of the generalized Langevin equation and takes into account both the potential interactions in the system and the memory effects due to the zeolite vibrations. Two different mechanisms corresponding to monomolecular and bimolecular NO decomposition are discussed. The catalytic effect in the monomolecular mechanism is related to both the Cu+ ions and zeolite O-vacancies, while in the case of the bimolecular mechanism the zeolite contributes through dissipation only. The comparison of the theoretically calculated rate constants with experimental results reveals additional information about the geometric and energetic characteristics of the active centers and con...
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Naghdi Yazdan
2015-08-01
Full Text Available Given the recent fluctuation in the exchange rate and the presence of several factors such as the various economy-political sanctions (mainly embargos on oil and banking, extreme volatility in different economic fields, and consequently the devaluation of national and public procurement -A landmark that is emanating from exchange rate fluctuation - two points should be noted: First, it is essential to review the effect of exchange rate fluctuation on macro economic variables such as inflation and to provide appropriate policies. Second, the existence of this condition provides the chance to study the relation between exchange rate and inflation in a non-linear and asymmetric method. Hence, the present study seeks to use TAR model and, on the basis of monthly time series data over the period March 2002 to March 2014, to analyze the cross-asymmetric and non-linear exchange rate on consumer price index (CPI in Iran. The results also show the presence of an asymmetric long-term relationship between these variables (exchange rate and CPI. Also, in the Iranian economy, the effect of negative shocks of exchange rate on inflation is more sustainable than the one from positive shocks.
Evaluation of Foreign Exchange Risk Capital Requirement Models
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Ricardo S. Maia Clemente
2005-12-01
Full Text Available This paper examines capital requirement for financial institutions in order to cover market risk stemming from exposure to foreign currencies. The models examined belong to two groups according to the approach involved: standardized and internal models. In the first group, we study the Basel model and the model adopted by the Brazilian legislation. In the second group, we consider the models based on the concept of value at risk (VaR. We analyze the single and the double-window historical model, the exponential smoothing model (EWMA and a hybrid approach that combines features of both models. The results suggest that the Basel model is inadequate to the Brazilian market, exhibiting a large number of exceptions. The model of the Brazilian legislation has no exceptions, though generating higher capital requirements than other internal models based on VaR. In general, VaR-based models perform better and result in less capital allocation than the standardized approach model applied in Brazil.
An Experimentally Validated Numerical Modeling Technique for Perforated Plate Heat Exchangers.
White, M J; Nellis, G F; Kelin, S A; Zhu, W; Gianchandani, Y
2010-11-01
Cryogenic and high-temperature systems often require compact heat exchangers with a high resistance to axial conduction in order to control the heat transfer induced by axial temperature differences. One attractive design for such applications is a perforated plate heat exchanger that utilizes high conductivity perforated plates to provide the stream-to-stream heat transfer and low conductivity spacers to prevent axial conduction between the perforated plates. This paper presents a numerical model of a perforated plate heat exchanger that accounts for axial conduction, external parasitic heat loads, variable fluid and material properties, and conduction to and from the ends of the heat exchanger. The numerical model is validated by experimentally testing several perforated plate heat exchangers that are fabricated using microelectromechanical systems based manufacturing methods. This type of heat exchanger was investigated for potential use in a cryosurgical probe. One of these heat exchangers included perforated plates with integrated platinum resistance thermometers. These plates provided in situ measurements of the internal temperature distribution in addition to the temperature, pressure, and flow rate measured at the inlet and exit ports of the device. The platinum wires were deposited between the fluid passages on the perforated plate and are used to measure the temperature at the interface between the wall material and the flowing fluid. The experimental testing demonstrates the ability of the numerical model to accurately predict both the overall performance and the internal temperature distribution of perforated plate heat exchangers over a range of geometry and operating conditions. The parameters that were varied include the axial length, temperature range, mass flow rate, and working fluid.
A simple, closed-form, mathematical model for gas exchange in microchannel artificial lungs.
Potkay, Joseph A
2013-06-01
Microfabrication techniques are attractive for constructing artificial lungs due to the ability to create features similar in size to those in the natural lung. However, a simple and intuitive mathematical model capable of accurately predicting the gas exchange performance of microchannel artificial lungs does not currently exist. Such a model is critical to understanding and optimizing these devices. Here, we describe a simple, closed-form mathematical model for gas exchange in microchannel artificial lungs and qualify it through application to experimental data from several research groups. We utilize lumped parameters and several assumptions to obtain a closed-form set of equations that describe gas exchange. This work is intended to augment computational models by providing a more intuitive, albeit potentially less accurate, understanding of the operation and trade-offs inherent in microchannel artificial lung devices.
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Zaga-Clavellina Veronica
2012-09-01
Full Text Available Abstract Background During intrauterine infection, amniochorionic membranes represent a mechanical and immunological barrier against dissemination of infection. Human beta defensins (HBD-1, HBD-2, and HBD-3 are key elements of innate immunity that represent the first line of defense against different pathogen microorganisms associated with preterm labor. The aim of this work was to characterize the individual contribution of the amnion (AMN and choriodecidua (CHD regions to the secretion of HBD-1, HBD-2 and HBD-3, after stimulation with Candida albicans. Methods Full-thickness human amniochorionic membranes were obtained after delivery by elective cesarean section from women at 37-40 wk of gestation with no evidence of active labor. The membranes were cultured in a two-compartment experimental model in which the upper compartment is delimited by the amnion and the lower chamber by the choriodecidual membrane. One million of Candida albicans were added to either the AMN or the CHD face or to both and compartmentalized secretion profiles of HBD-1, HBD-2, and HBD-3 were quantified by ELISA. Tissue immunolocalization was performed to detect the presence of HBD-1, -2, -3 in tissue sections stimulated with Candida albicans. Results HBD-1 secretion level by the CHD compartment increased 2.6 times (27.30 [20.9-38.25] pg/micrograms protein when the stimulus with Candida albicans was applied only on this side of the membrane and 2.4 times (26.55 [19.4-42.5] pg/micrograms protein when applied to both compartments simultaneously. HBD-1 in the amniotic compartment remained without significant changes. HBD-2 secretion level increased significantly in the CHD when the stimulus was applied only to this region (2.49 [1.49-2.95] pg/micrograms protein and simultaneously to both compartments (2.14 [1.67- 2.91] pg/micrograms protein. When the stimulus was done in the amniotic compartment HBD-2 remained without significant changes in both compartments. HBD-3 remained
J/ψ and φ Electro-production in Pomeron Exchange Model
Institute of Scientific and Technical Information of China (English)
无
2007-01-01
Based on Pomeron exchange model, J/ψ and φ production in electro-proton interaction are investigated with both linear and non-linear Pomeron trajectory. The experimental differential cross sections measured as a function of the kinematic variable Q2,W and t are reproduced successfully in the model. Our conclusions are that the Pomeron exchange model is a successful description of J/ψ and φ electro-productions on the proton, and that the linear trajectory is a good approximation to non-linearity of the Pomeron trajectory.
Specification of a STEP Based Reference Model for Exchange of Robotics Models
DEFF Research Database (Denmark)
Haenisch, Jochen; Kroszynski, Uri; Ludwig, Arnold
ESPRIT Project 6457: "Interoperability of Standards for Robotics in CIME" (InterRob) belongs to the Subprogram "Computer Integrated Manufacturing and Engineering" of ESPRIT, the European Specific Programme for Research and Development in Information Technology supported by the European Commision....... InterRob aims to develop an integrated solution to precision manufacturing by combining product data and database technologies with robotic off-line programming and simulation. Benefits arise from the use of high level simulation tools and developing standards for the exchange of product model data...... combining geometric, dynamic, process and robot specific data.The growing need for accurate information about manufacturing data (models of robots and other mechanisms) in diverse industrial applications has initiated ESPRIT Project 6457: InterRob. Besides the topics associated with standards for industrial...
Plate Fin Heat Exchanger Model with Axial Conduction and Variable Properties
Energy Technology Data Exchange (ETDEWEB)
Hansen, B.J.; White, M.J.; Klebaner, A.; /Fermilab
2011-06-10
Future superconducting radio frequency (SRF) cavities, as part of Project X at Fermilab, will be cooled to superfluid helium temperatures by a cryogenic distribution system supplying cold supercritical helium. To reduce vapor fraction during the final Joule-Thomson (J-T) expansion into the superfluid helium cooling bath, counter-flow, plate-fin heat exchangers will be utilized. Due to their compact size and ease of fabrication, plate-fin heat exchangers are an effective option. However, the design of compact and high-effectiveness cryogenic heat exchangers operating at liquid helium temperatures requires consideration of axial heat conduction along the direction of flow, in addition to variable fluid properties. Here we present a numerical model that includes the effects of axial conduction and variable properties for a plate fin heat exchanger. The model is used to guide design decisions on heat exchanger material choice and geometry. In addition, the J-T expansion process is modeled with the heat exchanger to analyze the effect of heat load and cryogenic supply parameters. A numerical model that includes the effects of axial conduction and variable properties for a plate fin heat exchanger was developed and the effect of various design parameters on overall heat exchanger size was investigated. It was found that highly conductive metals should be avoided in the design of compact JT heat exchangers. For the geometry considered, the optimal conductivity is around 3.5 W/m-K and can range from 0.3-10 W/m-K without a large loss in performance. The model was implemented with an isenthalpic expansion process. Increasing the cold side inlet temperature from 2K to 2.2 K decreased the liquid fraction from 0.856 to 0.839 which corresponds to a 0.12 g/s increase in supercritical helium supply needed to maintain liquid level in the cooling bath. Lastly, it was found that the effectiveness increased when the heat load was below the design value. Therefore, the heat exchanger
Gomez-Velez, Jesus D.; Harvey, Judson W.
2014-09-01
Hyporheic exchange has been hypothesized to have basin-scale consequences; however, predictions throughout river networks are limited by available geomorphic and hydrogeologic data and by models that can analyze and aggregate hyporheic exchange flows across large spatial scales. We developed a parsimonious but physically based model of hyporheic flow for application in large river basins: Networks with EXchange and Subsurface Storage (NEXSS). We applied NEXSS across a broad range of geomorphic diversity in river reaches and synthetic river networks. NEXSS demonstrates that vertical exchange beneath submerged bed forms rather than lateral exchange through meanders dominates hyporheic fluxes and turnover rates along river corridors. Per kilometer, low-order streams have a biogeochemical potential at least 2 orders of magnitude larger than higher-order streams. However, when biogeochemical potential is examined per average length of each stream order, low- and high-order streams were often found to be comparable. As a result, the hyporheic zone's intrinsic potential for biogeochemical transformations is comparable across different stream orders, but the greater river miles and larger total streambed area of lower order streams result in the highest cumulative impact from low-order streams. Lateral exchange through meander banks may be important in some cases but generally only in large rivers.
Kaniowski, Robert; Poniewski, Mieczysław
2013-12-01
Heat exchangers of different types find application in power systems based on solid oxide fuel cells (SOFC). Compact plate fin heat exchangers are typically found to perfectly fit systems with power output under 5 kWel. Micro-combined heat and power (micro-CHP) units with solid oxide fuel cells can exhibit high electrical and overall efficiencies, exceeding 85%, respectively. These values can be achieved only when high thermal integration of a system is assured. Selection and sizing of heat exchangers play a crucial role and should be done with caution. Moreover, performance of heat exchangers under variable operating conditions can strongly influence efficiency of the complete system. For that reason, it becomes important to develop high fidelity mathematical models allowing evaluation of heat exchangers under modified operating conditions, in high temperature regimes. Prediction of pressure and temperatures drops at the exit of cold and hot sides are important for system-level studies. Paper presents dedicated mathematical model used for evaluation of a plate fin heat exchanger, operating as a part of micro-CHP unit with solid oxide fuel cells.
Feru, E.; Willems, F.P.T.; Rojer, C.; Jager, B. de; Steinbuch, M.
2013-01-01
To meet future CO2 emission targets, Waste Heat Recovery systems have recently attracted much attention for automotive applications, especially for long haul trucks. This paper focuses on the development of a dynamic counter-flow heat exchanger model for control purposes. The model captures the dyna
Modeling heat efficiency, flow and scale-up in the corotating disc scraped surface heat exchanger
DEFF Research Database (Denmark)
Friis, Alan; Szabo, Peter; Karlson, Torben
2002-01-01
A comparison of two different scale corotating disc scraped surface heat exchangers (CDHE) was performed experimentally. The findings were compared to predictions from a finite element model. We find that the model predicts well the flow pattern of the two CDHE's investigated. The heat transfer...
MODELING EXCHANGE RATE CHANGE BASED ON THE ANALYSIS OF FUNDAMENTAL INDICATORS
Directory of Open Access Journals (Sweden)
Sergey A. Timofeev
2013-01-01
Full Text Available The article deals with analysis of economic fundamental data and the issue of modeling of change in exchange rate EUR/USD. On the basis of statistical methods from the analysis was developed a model which helps to predict the range of currencies.
Sridhar, Upasana Manimegalai; Govindarajan, Anand; Rhinehart, R Russell
2016-01-01
This work reveals the applicability of a relatively new optimization technique, Leapfrogging, for both nonlinear regression modeling and a methodology for nonlinear model-predictive control. Both are relatively simple, yet effective. The application on a nonlinear, pilot-scale, shell-and-tube heat exchanger reveals practicability of the techniques.
The Interpersonal Exchange Model of Sexual Satisfaction: Implications for Sex Therapy with Couples.
Byers, E. Sandra
1999-01-01
Little has been written in empirical or clinical literature about enhancement of sexual satisfaction, and there has not been a theoretical model to guide research on factors influencing sexual satisfaction. The Interpersonal Exchange Model of Sexual Satisfaction (IEMSS) was developed to fill the gaps. Article describes IEMSS and the studies that…
A one-dimensional heat transfer model for parallel-plate thermoacoustic heat exchangers
de Jong, Anne; Wijnant, Ysbrand H.; de Boer, Andries
2014-01-01
A one-dimensional (1D) laminar oscillating flow heat transfer model is derived and applied to parallel-plate thermoacoustic heat exchangers. The model can be used to estimate the heat transfer from the solid wall to the acoustic medium, which is required for the heat input/output of thermoacoustic
Feru, E.; Willems, F.P.T.; Rojer, C.; Jager, B. de; Steinbuch, M.
2013-01-01
To meet future CO2 emission targets, Waste Heat Recovery systems have recently attracted much attention for automotive applications, especially for long haul trucks. This paper focuses on the development of a dynamic counter-flow heat exchanger model for control purposes. The model captures the dyna
Modelled and measured energy exchange at a snow surface
Halberstam, I.
1979-01-01
Results of a model developed at JPL for the energy interchange between the atmosphere and the snow are compared with measurements made over a snowfield during a warm period of March, 1978. Both model and measurements show that turbulent fluxes are considerably smaller than the radiative fluxes, especially during the day. The computation of turbulent fluxes for both model and data is apparently lacking because of problems inherent in the stable atmosphere.
Extraproximal approach to calculating equilibriums in pure exchange models
Antipin, A. S.
2006-10-01
Models of economic equilibrium are a powerful tool of mathematical modeling of various markets. However, according to many publications, there are as yet no universal techniques for finding equilibrium prices that are solutions to such models. A technique of this kind that is a natural implementation of the Walras idea of tatonnements (i.e., groping for equilibrium prices) is proposed, and its convergence is proved.
Exchangeable lead from prediction models relates to vetiver lead uptake in different soil types.
Andra, Syam S; Sarkar, Dibyendu; Saminathan, Sumathi K M; Datta, Rupali
2011-12-01
Prediction models for exchangeable soil lead, published earlier in this journal (Andra et al. 2010a), were developed using a suite of native lead (Pb) paint-contaminated residential soils from two US cities heavily populated with homes constructed prior to Pb ban in paints. In this study, we tested the feasibility and practical applications of these prediction models for developing a phytoremediation design using vetiver grass (Vetiveria zizanioides), a Pb-tolerant plant. The models were used to estimate the exchangeable fraction of Pb available for vetiver uptake in four lead-spiked soil types, both acidic and alkaline, with varying physico-chemical properties and that are different from those used to build the prediction models. Results indicate a strong correlation for predictable exchangeable Pb with the observed fraction and as well with total Pb accumulated by vetiver grass grown in these soils. The correlation coefficient for the predicted vs. observed exchangeable Pb with p vetiver grass with p < 0.001 was 0.948, 0.983, 0.929, and 0.969 for each soil type, respectively. This study suggests that the success of a phytoremediation design could be assessed upfront by predicting the exchangeable Pb fraction in a given soil type based on its properties. This helps in modifying the soil conditions to enhance phytoextraction of Pb from contaminated soils.
Bojko, Marian; Kocich, Radim
2016-06-01
Application of numerical simulations based on the CFD calculation when the mass and heat transfer between the fluid flows is essential component of thermal calculation. In this article the mathematical model of the heat exchanger is defined, which is subsequently applied to the plate heat exchanger, which is connected in series with the other heat exchanger (tubular heat exchanger). The present contribution deals with the possibility to use the waste heat of the flue gas produced by small micro turbine. Inlet boundary conditions to the mathematical model of the plate heat exchanger are obtained from the results of numerical simulation of the tubular heat exchanger. Required parameters such for example inlet temperature was evaluated from temperature field, which was subsequently imported to the inlet boundary condition to the simulation of plate heat exchanger. From the results of 3D numerical simulations are evaluated basic flow variables including the evaluation of dimensionless parameters such as Colburn j-factor and friction ft factor. Numerical simulation is realized by software ANSYS Fluent15.0.
Modeling Conflict And Exchange In Collective Decision Making
Stokman, Frans N.
1995-01-01
Two dynamic models of collecuve decision maklng are Introduced and lllustrated wlth a simple example. A more extensive presentation and appllcauon concerning the European Community can be found In Bueno de Mesqulta and Stokman (19941. The two dynamlc models reflect two alternative views of collectiv
Numerical Modeling of Fin and Tube Heat Exchanger for Waste Heat Recovery
DEFF Research Database (Denmark)
Singh, Shobhana; Sørensen, Kim; Condra, Thomas Joseph
associates conjugate heat transfer phenomenon with the turbulent flow to describe the variable temperature and velocity profile. The performance of heat exchanger design is investigated in terms of overall heat transfer coefficient, Nusselt number, Colburn j-factor, flow resistance factor, and efficiency......In the present work, multiphysics numerical modeling is carried out to predict the performance of a liquid-gas fin and tube heat exchanger design. Three-dimensional (3D) steady-state numerical model using commercial software COMSOL based on finite element method (FEM) is developed. The study...... between fin and tube. The present numerical model predicts the performance of the heat exchanger design, therefore, can be applied to existing waste heat recovery systems to improve the overall performance with optimized design and process-dependent parameters....
Institute of Scientific and Technical Information of China (English)
卢建刚
2004-01-01
The salt-gradient operation mode used in ion-exchange simulated moving bed chromatography (SMBC) can improve the efficiency of protein separations. A detailed model that takes into account any kind of adsorption/ion-exchange equilibrium, salt gradient, size exclusion, mass transfer resistance, and port periodic switching mechanism, was developed to simulate the complex dynamics. The model predictions were verified by the experimental data on upward and downward gradients for protein separations reported in the literature. All design and operating parameters (number, configuration, length and diameter of columns, particle size, switching period, flow rates of feed, raffinate, desorbent and extract, protein concentrations in feed, different salt concentrations in desorbent and feed) can be chosen correctly by numerical simulation. This model can facilitate the design, operation, optimization, control and scale-up of salt-gradient ion-exchange SMBC for protein separations.
Grüne-Yanoff, Till
2015-12-01
Today's models of temporal discounting are the result of multiple interdisciplinary exchanges between psychology and economics. Although these exchanges did not result in an integrated discipline, they had important effects on all disciplines involved. The paper describes these exchanges from the 1930s onwards, focusing on two episodes in particular: an attempted synthesis by psychiatrist George Ainslie and others in the 1970s; and the attempted application of this new discounting model by a generation of economists and psychologists in the 1980s, which ultimately ended in the diversity of measurements disappointment. I draw four main conclusions. First, multiple notions of temporal discounting must be conceptually distinguished. Second, behavioral economics is not an integration or unification of psychology and economics. Third, the analysis identifies some central disciplinary markers that distinguish modeling strategies in economics and psychology. Finally, it offers a case of interdisciplinary success that does not fit the currently dominant account of interdisciplinarity as integration.
Activity systems modeling as a theoretical lens for social exchange studies
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Ernest Jones
2016-01-01
Full Text Available The social exchange perspective seeks to acknowledge, understand and predict the dynamics of social interactions. Empirical research involving social exchange constructs have grown to be highly technical including confirmatory factor analysis to assess construct distinctiveness and structural equation modeling to assess construct causality. Each study seemingly strives to assess how underlying social exchange theoretic constructs interrelate. Yet despite this methodological depth and resultant explanatory and predictive power, a significant number of studies report findings that, once synthesized, suggest an underlying persistent threat of conceptual or construct validity brought about by a search for epistemological parsimony. Further, it is argued that a methodological approach that embraces inherent complexity such as activity systems modeling facilitates the search for simplified models while not ignoring contextual factors.
Multiphysics Model of Palladium Hydride Isotope Exchange Accounting for Higher Dimensionality
Energy Technology Data Exchange (ETDEWEB)
Gharagozloo, Patricia E.; Eliassi, Mehdi; Bon, Bradley Luis
2015-03-01
This report summarizes computational model developm ent and simulations results for a series of isotope exchange dynamics experiments i ncluding long and thin isothermal beds similar to the Foltz and Melius beds and a lar ger non-isothermal experiment on the NENG7 test bed. The multiphysics 2D axi-symmetr ic model simulates the temperature and pressure dependent exchange reactio n kinetics, pressure and isotope dependent stoichiometry, heat generation from the r eaction, reacting gas flow through porous media, and non-uniformities in the bed perme ability. The new model is now able to replicate the curved reaction front and asy mmetry of the exit gas mass fractions over time. The improved understanding of the exchange process and its dependence on the non-uniform bed properties and te mperatures in these larger systems is critical to the future design of such sy stems.
Proton Exchange Membrane Fuel Cell Modeling Based on Seeker Optimization Algorithm
Institute of Scientific and Technical Information of China (English)
LI Qi; DAI Chao-hua; Chen Wei-rong; JIA Jun-bo; HAN Ming
2008-01-01
Seeker optimization algorithm (SOA) has applications in continuous space of swarm intelligence. In the fields of proton ex-change membrane fuel cell (PEMFC) modeling, SOA was proposed to research a set of optimized parameters in PEMFC polariza-tion curve model. Experimental result showed that the mean square error of the optimization modeling strategy was only 6.9 × 10-23. Hence, the optimization model could fit the experiment data with high precision.
Exposure Modeling of Residential Air Exchange Rates for NEXUS Participants.
Due to cost and participant burden of personal measurements, air pollution health studies often estimate exposures using local ambient air monitors. Since outdoor levels do not necessarily reflect personal exposures, we developed the Exposure Model for Individuals (EMI) to improv...
A thermoelectric power generating heat exchanger: Part II – Numerical modeling and optimization
DEFF Research Database (Denmark)
Sarhadi, Ali; Bjørk, Rasmus; Lindeburg, N.
2016-01-01
of the interface surfaces as well as the air gap thermal resistance at the interface. The combined CMY and parallel plate gap model is then further developed to simulate the thermal contact resistance for the case of an interface material. The numerical results show good agreement with the experimental data...... TEG-heat exchanger, the thermal contact resistance between the TEG and the heat exchanger is modeled assuming either an ideal thermal contact or using a combined Cooper–Mikic–Yovanovich (CMY) and parallel plate gap formulation, which takes into account the contact pressure, roughness and hardness...
Goyal, Mukesh; Chakravarty, Anindya; Atrey, M. D.
2017-03-01
Experimental investigations are carried out using a specially developed three-layer plate fin heat exchanger (PFHE), with helium as the working fluid cooled to cryogenic temperatures using liquid nitrogen (LN2) as a coolant. These results are used for validation of an already proposed and reported numerical model based on finite volume analysis for multistream (MS) plate fin heat exchangers (PFHE) for cryogenic applications (Goyal et al., 2014). The results from the experiments are presented and a reasonable agreement is observed with the already reported numerical model.
A macro-physics model of depreciation rate in economic exchange
Marmont Lobo, Rui F.; de Sousa, Miguel Rocha
2014-02-01
This article aims at a new approach for a known fundamental result: barter or trade increases economic value. It successfully bridges the gap between the theory of value and the exchange process attached to the transition from endowments to the equilibrium in the core and contract curve. First, we summarise the theory of value; in Section 2, we present the Edgeworth (1881) box and an axiomatic approach and in Section 3, we apply our pure exchange model. Finally (in Section 4), using our open econo-physics pure barter (EPB) model, we derive an improvement in value, which means that pure barter leads to a decline in depreciation rate.
Contributions from Goldstone-boson-exchange to baryon spectra in the MIT Bag Model
He, D H; Li, X Q; Shen, P N; He, Da-Heng; Ding, Yi-Bing; Li, Xue-Qian; Shen, Peng-Nian
2005-01-01
We discuss contributions of chiral bosons to baryon spectra in the MIT bag model. It is believed that within hadrons, chiral bosons are degrees of freedom which are independent of gluons to provide strong interactions between quarks. In the original MIT bag model, only interaction mediated by gluon exchanges was considered, by contrast, in this work we take into account the interaction mediated by the exchanges of chiral bosons $\\sigma$ and $\\pi^{(\\pm,0)}$. Then following the standard approach, we minimize the effective hamiltonian which includes both the contributions from gluon and chiral-boson exchanges with respect to the bag radius to obtain the effective radius. By re-fitting the spectra of baryons, we find that the contributions from the boson-exchange may be 40% of that from gluon-exchanges and meanwhile the bag constant $B$, the zero-point energy $z_0$ almost do not change. It indicates that in the original version of the MIT bag model, the intermediate-distance interaction due to the chiral-boson ex...
Directory of Open Access Journals (Sweden)
Oreiro José Luis
2015-01-01
Full Text Available The aim of this paper is to show at theoretical level that maintaining a competitive real exchange rate positively affects the economic growth of developing countries by means of a Keynesian-Structuralist model that combines elements of Kaleckian growth models with the balance of payments constrained growth models pioneered developed by Thirlwall. In this setting, the level of real exchange rate is capable, due to its effect over capital accumulation, to induce a structural change in the economy, making endogenous income elasticities of exports and imports. For reasonable parameter values it is shown that in steady-state growth there is two long-run equilibrium values for real exchange rate, one that corresponds to an under-valued currency and another that corresponds to an over-valued currency. If monetary authorities run exchange rate policy in order to target a competitive level for real exchange rate, than under-valued equilibrium is stable and the economy will show a high growth rate in the long-run.
Enabling Health Reform through Regional Health Information Exchange: A Model Study from China
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Jianbo Lei
2017-01-01
Full Text Available Objective. To investigate and share the major challenges and experiences of building a regional health information exchange system in China in the context of health reform. Methods. This study used interviews, focus groups, a field study, and a literature review to collect insights and analyze data. The study examined Xinjin’s approach to developing and implementing a health information exchange project, using exchange usage data for analysis. Results. Within three years and after spending approximately $2.4 million (15 million RMB, Xinjin County was able to build a complete, unified, and shared information system and many electronic health record components to integrate and manage health resources for 198 health institutions in its jurisdiction, thus becoming a model of regional health information exchange for facilitating health reform. Discussion. Costs, benefits, experiences, and lessons were discussed, and the unique characteristics of the Xinjin case and a comparison with US cases were analyzed. Conclusion. The Xinjin regional health information exchange system is different from most of the others due to its government-led, government-financed approach. Centralized and coordinated efforts played an important role in its operation. Regional health information exchange systems have been proven critical for meeting the global challenges of health reform.
Monte Carlo study of the double and super-exchange model with lattice distortion
Energy Technology Data Exchange (ETDEWEB)
Suarez, J R; Vallejo, E; Navarro, O [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Apartado Postal 70-360, 04510 Mexico D. F. (Mexico); Avignon, M, E-mail: jrsuarez@iim.unam.m [Institut Neel, Centre National de la Recherche Scientifique (CNRS) and Universite Joseph Fourier, BP 166, 38042 Grenoble Cedex 9 (France)
2009-05-01
In this work a magneto-elastic phase transition was obtained in a linear chain due to the interplay between magnetism and lattice distortion in a double and super-exchange model. It is considered a linear chain consisting of localized classical spins interacting with itinerant electrons. Due to the double exchange interaction, localized spins tend to align ferromagnetically. This ferromagnetic tendency is expected to be frustrated by anti-ferromagnetic super-exchange interactions between neighbor localized spins. Additionally, lattice parameter is allowed to have small changes, which contributes harmonically to the energy of the system. Phase diagram is obtained as a function of the electron density and the super-exchange interaction using a Monte Carlo minimization. At low super-exchange interaction energy phase transition between electron-full ferromagnetic distorted and electron-empty anti-ferromagnetic undistorted phases occurs. In this case all electrons and lattice distortions were found within the ferromagnetic domain. For high super-exchange interaction energy, phase transition between two site distorted periodic arrangement of independent magnetic polarons ordered anti-ferromagnetically and the electron-empty anti-ferromagnetic undistorted phase was found. For this high interaction energy, Wigner crystallization, lattice distortion and charge distribution inside two-site polarons were obtained.
Directory of Open Access Journals (Sweden)
J. O. Bash
2013-03-01
Full Text Available Atmospheric ammonia (NH3 is the primary atmospheric base and an important precursor for inorganic particulate matter and when deposited NH3 contributes to surface water eutrophication, soil acidification and decline in species biodiversity. Flux measurements indicate that the air–surface exchange of NH3 is bidirectional. However, the effects of bidirectional exchange, soil biogeochemistry and human activity are not parameterized in air quality models. The US Environmental Protection Agency's (EPA Community Multiscale Air-Quality (CMAQ model with bidirectional NH3 exchange has been coupled with the United States Department of Agriculture's (USDA Environmental Policy Integrated Climate (EPIC agroecosystem model. The coupled CMAQ-EPIC model relies on EPIC fertilization timing, rate and composition while CMAQ models the soil ammonium (NH4+ pool by conserving the ammonium mass due to fertilization, evasion, deposition, and nitrification processes. This mechanistically coupled modeling system reduced the biases and error in NHx (NH3 + NH4+ wet deposition and in ambient aerosol concentrations in an annual 2002 Continental US (CONUS domain simulation when compared to a 2002 annual simulation of CMAQ without bidirectional exchange. Fertilizer emissions estimated in CMAQ 5.0 with bidirectional exchange exhibits markedly different seasonal dynamics than the US EPA's National Emissions Inventory (NEI, with lower emissions in the spring and fall and higher emissions in July.
Bash, J. O.; Cooter, E. J.; Dennis, R. L.; Walker, J. T.; Pleim, J. E.
2013-03-01
Atmospheric ammonia (NH3) is the primary atmospheric base and an important precursor for inorganic particulate matter and when deposited NH3 contributes to surface water eutrophication, soil acidification and decline in species biodiversity. Flux measurements indicate that the air-surface exchange of NH3 is bidirectional. However, the effects of bidirectional exchange, soil biogeochemistry and human activity are not parameterized in air quality models. The US Environmental Protection Agency's (EPA) Community Multiscale Air-Quality (CMAQ) model with bidirectional NH3 exchange has been coupled with the United States Department of Agriculture's (USDA) Environmental Policy Integrated Climate (EPIC) agroecosystem model. The coupled CMAQ-EPIC model relies on EPIC fertilization timing, rate and composition while CMAQ models the soil ammonium (NH4+) pool by conserving the ammonium mass due to fertilization, evasion, deposition, and nitrification processes. This mechanistically coupled modeling system reduced the biases and error in NHx (NH3 + NH4+) wet deposition and in ambient aerosol concentrations in an annual 2002 Continental US (CONUS) domain simulation when compared to a 2002 annual simulation of CMAQ without bidirectional exchange. Fertilizer emissions estimated in CMAQ 5.0 with bidirectional exchange exhibits markedly different seasonal dynamics than the US EPA's National Emissions Inventory (NEI), with lower emissions in the spring and fall and higher emissions in July.
A computational model of insect discontinuous gas exchange: A two-sensor, control systems approach.
Grieshaber, Beverley J; Terblanche, John S
2015-06-07
The insect gas exchange system is characterised by branching air-filled tubes (tracheae/tracheoles) and valve-like structures in their outer integument (spiracles) which allow for a periodic gas exchange pattern known as the discontinuous gas exchange cycle (DGC). The DGC facilitates the temporal decoupling of whole animal gas exchange from cellular respiration rates and may confer several physiological benefits, which are nevertheless highly controversial (primarily reduction of cellular oxidative damage and/or respiratory water saving). The intrinsic and extrinsic factors influencing DGCs are the focus of extensive ongoing research and little consensus has been reached on the evolutionary genesis or mechanistic costs and benefits of the pattern. Despite several hypotheses and much experimental and evolutionary biology research, a mechanistic physical model, which captures various key elements of the DGC pattern, is currently lacking. Here, we present a biologically realistic computational, two-sensor DGC model (pH/carbon dioxide and oxygen setpoints) for an Orthopteran gas exchange system, and show computationally for the first time that a control system of two interacting feedback loops is capable of generating a full DGC pattern with outputs which are physiologically realistic, quantitatively matching experimental results found in this taxonomic model elsewhere. A finite-element mathematical approach is employed and various trigger sets are considered. Parameter sensitivity analyses suggest that various aspects of insect DGC are adequately captured in this model. In particular, with physiologically relevant input parameters, the full DGC pattern is induced; and the phase durations, endotracheal carbon dioxide partial pressure ranges, and pH fluctuations which arise are physically realistic. The model results support the emergent property hypothesis for the existence of DGC, and indicate that asymmetric loading and off-loading (hysteresis) in one of the sensor
Multi-Agent Market Modeling of Foreign Exchange Rates
Zimmermann, Georg; Neuneier, Ralph; Grothmann, Ralph
A market mechanism is basically driven by a superposition of decisions of many agents optimizing their profit. The oeconomic price dynamic is a consequence of the cumulated excess demand/supply created on this micro level. The behavior analysis of a small number of agents is well understood through the game theory. In case of a large number of agents one may use the limiting case that an individual agent does not have an influence on the market, which allows the aggregation of agents by statistic methods. In contrast to this restriction, we can omit the assumption of an atomic market structure, if we model the market through a multi-agent approach. The contribution of the mathematical theory of neural networks to the market price formation is mostly seen on the econometric side: neural networks allow the fitting of high dimensional nonlinear dynamic models. Furthermore, in our opinion, there is a close relationship between economics and the modeling ability of neural networks because a neuron can be interpreted as a simple model of decision making. With this in mind, a neural network models the interaction of many decisions and, hence, can be interpreted as the price formation mechanism of a market.
Stochastic effects in a discretized kinetic model of economic exchange
Bertotti, M. L.; Chattopadhyay, A. K.; Modanese, G.
2017-04-01
Linear stochastic models and discretized kinetic theory are two complementary analytical techniques used for the investigation of complex systems of economic interactions. The former employ Langevin equations, with an emphasis on stock trade; the latter is based on systems of ordinary differential equations and is better suited for the description of binary interactions, taxation and welfare redistribution. We propose a new framework which establishes a connection between the two approaches by introducing random fluctuations into the kinetic model based on Langevin and Fokker-Planck formalisms. Numerical simulations of the resulting model indicate positive correlations between the Gini index and the total wealth, that suggest a growing inequality with increasing income. Further analysis shows, in the presence of a conserved total wealth, a simultaneous decrease in inequality as social mobility increases, in conformity with economic data.
Pujol, Josep M.; Flache, Andreas; Delgado, Jordi; Sangüesa, Ramon; Sanguessa, R.
2005-01-01
Small-world and power-law network structures have been prominently proposed as models of large networks. However, the assumptions of these models usually-lack sociological grounding. We present a computational model grounded in social exchange theory. Agents search attractive exchange partners in a
Comparison of stock valuation models with their intrinsic value in Tehran Stock Exchange
Directory of Open Access Journals (Sweden)
Ali Amiri
2016-06-01
Full Text Available Stock evaluation is one of the most important and most complex operational processes in the stock exchange. In financial markets, the pricing of tradable assets plays a basic role in resource allocation. After initial stock valuation of listed companies in Tehran Stock Exchange, some changes were observed in prices with the value set by the Stock Exchange. The aim of this study was to determine the model applied in the formation of stock prices in the stock market to find an appropriate market value model among value-based valuation models. To test the models of stock valuation, ordinary least square regression was used. Also, E-Views software was used for further data analysis. The sample included all the companies listed in Tehran Stock Exchange from 2008 till 2013. Based on the stratified random sampling, each industry was selected as a category and using Cochran formula, sample size of 40 participants was determined from each category. The data analysis indicated that the price-to-book ratio (P/B ratio had the highest adjustment factor and had been set as the best stock valuation model.
Radon (222Rn) in ground water of fractured rocks: A diffusion/ion exchange model
Wood, W.W.; Kraemer, T.F.; Shapiro, A.
2004-01-01
Ground waters from fractured igneous and high-grade sialic metamorphic rocks frequently have elevated activity of dissolved radon (222Rn). A chemically based model is proposed whereby radium (226Ra) from the decay of uranium (238U) diffuses through the primary porosity of the rock to the water-transmitting fracture where it is sorbed on weathering products. Sorption of 226Ra on the fracture surface maintains an activity gradient in the rock matrix, ensuring a continuous supply of 226Ra to fracture surfaces. As a result of the relatively long half-life of 226Ra (1601 years), significant activity can accumulate on fracture surfaces. The proximity of this sorbed 226Ra to the active ground water flow system allows its decay progeny 222Rn to enter directly into the water. Laboratory analyses of primary porosity and diffusion coefficients of the rock matrix, radon emanation, and ion exchange at fracture surfaces are consistent with the requirements of a diffusion/ion- exchange model. A dipole-brine injection/withdrawal experiment conducted between bedrock boreholes in the high-grade metamorphic and granite rocks at the Hubbard Brook Experimental Forest, Grafton County, New Hampshire, United States (42??56???N, 71??43???W) shows a large activity of 226Ra exchanged from fracture surfaces by a magnesium brine. The 226Ra activity removed by the exchange process is 34 times greater than that of 238U activity. These observations are consistent with the diffusion/ion-exchange model. Elutriate isotopic ratios of 223Ra/226Ra and 238U/226Ra are also consistent with the proposed chemically based diffusion/ion-exchange model.
Adaptive Multi-GPU Exchange Monte Carlo for the 3D Random Field Ising Model
Navarro, C A; Deng, Youjin
2015-01-01
The study of disordered spin systems through Monte Carlo simulations has proven to be a hard task due to the adverse energy landscape present at the low temperature regime, making it difficult for the simulation to escape from a local minimum. Replica based algorithms such as the Exchange Monte Carlo (also known as parallel tempering) are effective at overcoming this problem, reaching equilibrium on disordered spin systems such as the Spin Glass or Random Field models, by exchanging information between replicas of neighbor temperatures. In this work we present a multi-GPU Exchange Monte Carlo method designed for the simulation of the 3D Random Field Model. The implementation is based on a two-level parallelization scheme that allows the method to scale its performance in the presence of faster and GPUs as well as multiple GPUs. In addition, we modified the original algorithm by adapting the set of temperatures according to the exchange rate observed from short trial runs, leading to an increased exchange rate...
A Standard Monetary Model and the Variability of the Deutschemark-DollarExchange Rate
Kenneth D. West
1986-01-01
This paper uses a novel teat to see whether the Herse (1985) and Woo (1985) models are consistent with the variability of the deutschemark - dollar exchange rate 1974-1984. The answer, perhaps surprisingly, is yes. Both models, however, explain the month to month variability as resulting in a critical way from unobservable shocks to money demand and purchasing power parity. It would therefore be of interest in future work to model one or both of these shocks as explicit functions of economic ...
A quantitative approach to developing more mechanistic gas exchange models for field grown potato
DEFF Research Database (Denmark)
Ahmadi, Seyed Hamid; Andersen, Mathias Neumann; Poulsen, Rolf Thostrup
2009-01-01
of chemical and hydraulic signalling on stomatal conductance as exp(-β[ABA])exp(-δ|ψ|) in which [ABA] and |ψ| are xylem ABA concentration and absolute value of leaf or stem water potential. In this study we found that stem water potential could be a very reliable indicator of how plant water status affects......In this study we introduce new gas exchange models that are developed under natural conditions of field grown potato. The new models could explain about 85% of the stomatal conductance variations, which was much higher than the well-known gas exchange models such as the Ball-Berry model [Ball......, Woodrow, Berry, 1987. In: Nijhoff, M. (Eds.), Progress in Photosynthesis Research, vol. 4. Dordrecht, The Netherlands, pp. 5.221-5.224]. To overcome the limitations of previous models in simulating stomatal conductance when plants are exposed to drought stress, we proposed a down-regulating factor...
Proton exchange membrane fuel cells modeling based on artificial neural networks
Institute of Scientific and Technical Information of China (English)
Yudong Tian; Xinjian Zhu; Guangyi Cao
2005-01-01
To understand the complexity of the mathematical models of a proton exchange membrane fuel cell (PEMFC) and their shortage of practical PEMFC control, the PEMFC complex mechanism and the existing PEMFC models are analyzed, and artificial neural networks based PEMFC modeling is advanced. The structure, algorithm, training and simulation of PEMFC modeling based on improved BP networks are given out in detail. The computer simulation and conducted experiment verify that this model is fast and accurate, and can be used as a suitable operational model for PEMFC real-time control.
Equity and Foreign Exchange Hybrid Models for Pricing Long-Maturity Financial Derivatives
Grzelak, L.A.
2011-01-01
Modelling derivative products in Finance usually starts with the specification of a system of Stochastic Differential Equations (SDEs), that corresponds to state variables like stock, interest rate, Foreign Exchange (FX) rate and volatility. By correlating the SDEs for the different asset classes on
DEFF Research Database (Denmark)
Wellendorff, Jess; Lundgård, Keld Troen; Møgelhøj, Andreas
2012-01-01
A methodology for semiempirical density functional optimization, using regularization and cross-validation methods from machine learning, is developed. We demonstrate that such methods enable well-behaved exchange-correlation approximations in very flexible model spaces, thus avoiding the overfit...
Residential air exchange rates (AERs) are a key determinant in the infiltration of ambient air pollution indoors. Population-based human exposure models using probabilistic approaches to estimate personal exposure to air pollutants have relied on input distributions from AER meas...
Empirical Tests of the Assumptions Underlying Models for Foreign Exchange Rates.
1984-03-01
Martinengo (1980) extends a model by Dornbusch (1976) in which market equilibrium is formalized in terms of interest rates, level of prices, public...55-65. Dornbusch , R., "The Theory of Flexible Exchange Rate Regimes and Macroeconomic Policy", Scandinavian Journal of Economics, 78, 1976, pP. 255
CFD Modeling of Flow and Ion Exchange Kinetics in a Rotating Bed Reactor System
DEFF Research Database (Denmark)
Larsson, Hilde Kristina; Schjøtt Andersen, Patrick Alexander; Byström, Emil
2017-01-01
be achieved by making the baffles deeper. Two-phase simulations were performed, which managed to reproduce the deflection of the gas–liquid interface in an unbaffled system. A chemical reaction was implemented in the model, describing the ion-exchange phenomena in the porous material using four different...
Pricing model of credit default swap with stochastic foreign exchange rate
Directory of Open Access Journals (Sweden)
WANG Yang
2013-04-01
Full Text Available A pricing model is established by using the structure approach and the backward Kolmogrov equation under the assumption of stochastic foreign exchange rate.The explicit solution of credit default swap is obtained for the dollar market.And a correlative financial analysis is given.
Dynamic Thermal Model and Temperature Control of Proton Exchange Membrane Fuel Cell Stack
Institute of Scientific and Technical Information of China (English)
邵庆龙; 卫东; 曹广益; 朱新坚
2005-01-01
A dynamic thermal transfer model of a proton exchange membrane fuel cell (PEMFC) stack is developed based on energy conservation in order to reach better temperature control of PEMFC stack. Considering its uncertain parameters and disturbance, we propose a robust adaptive controller based on backstepping algorithm of Lyaponov function. Numerical simulations indicate the validity of the proposed controller.
Study of the heavy molecular states in the quark model with meson exchange interaction
Institute of Scientific and Technical Information of China (English)
YU Si-Hai; WANG Bao-Kai; CHEN Xiao-Lin; DENG Wei-Zhen
2012-01-01
Some charmonium-like resonances such as X(3872) can be interpreted as possible D(*)(D)(*) molecular states.Within the quark model,we study the structure of such molecular states and the similar B(*)(B)(*)molecular states by taking into account the light meson exchange (π,η,ρ,ω and σ) between two light quarks from different mesons.
Testing the Capital Asset Pricing Model (CAPM) on the Uganda Stock Exchange
David Wakyiku
2010-01-01
This paper examines the validity of the Capital Asset Pricing Model (CAPM) on the Ugandan stock market using monthly stock returns from 10 of the 11 companies listed on the Uganda Stock Exchange (USE), for the period 1st March 2007 to 10th November 2009. Due to the absence of readily available Uganda Stock Exchange(USE) data, and the placement of daily price lists in pdf only, on the USE website: http://www.use.or.ug, the article also discusses the procedures taken to mine the data needed. Th...
Energy Technology Data Exchange (ETDEWEB)
Li, W. C.; Song, X.; Feng, J. J.; Zeng, M.; Gao, X. S.; Qin, M. H., E-mail: qinmh@scnu.edu.cn [Institute for Advanced Materials and Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, South China Normal University, Guangzhou 510006 (China); Jia, X. T. [School of Physics and Chemistry, Henan Polytechnic University, Jiaozuo 454000 (China)
2015-07-07
In this work, the effects of the random exchange interaction on the phase transitions and phase diagrams of classical frustrated Heisenberg model are investigated by Monte Carlo simulation in order to simulate the chemical doping effect in real materials. It is observed that the antiferromagnetic transitions shift toward low temperature with the increasing magnitude of the random exchange interaction, which can be qualitatively understood from the competitions among local spin states. This study is related to the magnetic properties in the doped iron-based superconductors.
Numerical Simulation of Different Models of Heat Pipe Heat Exchanger Using AcuSolve
Directory of Open Access Journals (Sweden)
Zainal Nurul Amira
2017-01-01
Full Text Available In this paper, a numerical simulation of heat pipe heat exchanger (HPHE is computed by using CFD solver program i.e. AcuSolve. Two idealized model of HPHE are created with different variant of entry’s dimension set to be case 1 and case 2. The geometry of HPHE is designed in SolidWorks and imported to AcuSolve to simulate the fluid flow numerically. The design of HPHE is the key to provide a heat exchanger system to work proficient as expected. Finally, the result is used to optimize and improving heat recovery systems of the increasing demand for energy efficiency in industry.
Institute of Scientific and Technical Information of China (English)
LIZhihong
2002-01-01
A new superstructure from of heat exchanger networks(HEN) is proposed based on expert system (ES). The new superstructure from is combined with the practical engineering.The different investment cost formula for different heat exchanger is also presented based on ES.The mathematical model for the simultaneous optimization of network configuration is established and solved by a genetic algorithm.This method can deal with larger scale HEN synthesis and the optimal HEN configuration is obtained automatically.Finally,a case study is presented to demonstrate the effectiveness of the method.
Flambaum, V V
2009-01-01
Exchange interaction strongly influences the long-range behavior of localized electron orbitals and quantum tunneling amplitudes.In the Hartree-Fock approximation the exchange produces a power-law decay instead of the usual exponential decrease at large distances. To show that this effect is real (i.e. not a result of the approximation) we consider a simple model where different effects may be accurately analyzed. Applications include huge enhancement of inner electron ionization by a static electric field or laser field considered in Ref. M. Ya. Amusia, arxiv:0904.4395
Zinc--bromide secondary cell. [C anode, C or Zr cathode with ion exchange diaphragm between
Energy Technology Data Exchange (ETDEWEB)
Leddy, J.J.; Gritzner, G.
1975-12-30
A zinc-bromine secondary cell is divided into two compartments by an ion exchange diaphragm. The electrolyte system includes an essentially bromide-ion-free, aqueous solution containing a zinc ion as an anolyte and a bromide ion containing catholyte. A method of operating the cell is disclosed. 2 figures, 2 tables. (auth)
A social exchange-based model of the antecedents of workplace exclusion.
Scott, Kristin L; Restubog, Simon Lloyd D; Zagenczyk, Thomas J
2013-01-01
We conducted 2 studies of coworker dyads to test a theoretical model exploring why and under what circumstances employees are the targets of workplace exclusion. Adopting a victim precipitation perspective, we integrate belongingness and social exchange theories to propose that employees who display workplace incivility are distrusted and therefore are targets of workplace exclusion. Highlighting the importance of the context of the perpetrator-target relationship, we also find support for the postulation that this mediated relationship is strengthened when the target employee is perceived to be a weak exchange partner and is attenuated when he or she is viewed as a valuable exchange partner. Theoretical and practical implications are discussed. PsycINFO Database Record (c) 2013 APA, all rights reserved.
The Renminbi Exchange Rate Reform and the Rebalancing of China’s Growth Model
Institute of Scientific and Technical Information of China (English)
JIANBO; SONG; SEAN; MACKINNON; SONGTAO; TAN
2015-01-01
This paper posits that a proper way to estimate the Renminbi(RMB) exchange rate is to base the evaluation on the Balassa-Samuelson effect, and that the optimal way to facilitate China’s growth model transformation is gradual RMB internationalization and capital account liberalization. Regression estimates show that the gross domestic product per capita growth rate, or the productivity growth rate, has strong explanatory validity when estimating the RMB exchange rate. The findings further assert that, as the growth of gross fixed capital formation slows, and the growth of household consumption speeds up, China’s economic growth will be sustained. The RMB exchange rate regime is one in which gradual reforms must yield to interest rates levels and hence should only be revalued conditionally.
Modelling of graded index waveguide fabricated by ion exchange on Er3+ doped glass
Institute of Scientific and Technical Information of China (English)
Shao Gong-Wang; Jin Guo-Liang
2009-01-01
A general numerical tool, based on thermal diffusion equation and full-vectorial eigen-mode equation, has been presented for the systematic analysis of graded index channel waveguide fabricated by ion exchange on Er3+ doped glass. Finite difference method with full-vectorial formulation (FV-FDM) is applied to solving the full-vectorial modes of graded index channel waveguide for the first time. The coupled difference equations based on magnetic fields in FV-FDM are derived from the Taylor series expansion and accurate formulation of boundary conditions. Hybrid nature of vectorial guided modes for both pump (980 nm) and signal light (1550 nm) are demonstrated by the simulation. Results show that the fabrication parameters of ion exchange, such as channel opening width and time ratio of second step to first step in ion exchange, have large influence on the properties of waveguide. By optimizing the fabrication parameters, maintenance of monomode for signal light and improvement of the gain dynamics can be achieved in Er3+ doped waveguide amplifier (EDWA) fabricated by ion exchange technique. This theoretical model is significant for the design and fabrication of EDWA with ion exchange technique. Furthermore, a single polarization EDWA, which operates at wavelength from 1528 nm to 1541 nm for HE polarization, is numerically designed.
Process-Scale Modeling of Atmosphere-Snowpack Exchange of Nitrogen Oxides
Murray, K. A.; Doskey, P. V.; Ganzeveld, L.
2013-12-01
Snowpack over glacial ice is a reservoir for reactive nitrogen gases. Previous studies indicate nitrogen oxides (NOx) are generated in snowpack interstitial air through photolysis of nitrate (NO3-). Gradients in NOx mixing ratios between snowpack interstitial air and the overlying atmosphere regulate exchange of NOx with snowpack, which affects the Arctic ozone budget and climate. To better understand the dynamics of cryosphere-atmosphere exchange of NOx in the Arctic, we collected 2 years of meteorological and chemical data in and above the snowpack at Summit, Greenland. The comprehensive dataset indicates NOx emissions are episodic, with NOx enhancements in snowpack in early spring during high wind speed events (10-20 mph), which elevate NOx levels to ~500 pptv at depths of 2.5 m. Analysis of the observations will be based upon application of a 1-D process-scale model of atmosphere-snowpack exchange of NOx. The model will include representations of the snowpack chemistry in gas and aqueous phases, mass transfer of chemical species between phases, and physical transport by diffusion and wind pumping. The model will calculate the chemical and physical tendencies in three dimensions: depth, time, and intensity. Analysis of the tendencies will allow us to perform model sensitivity tests of pertinent snowpack physical and chemical processes. The end-goal of the project is to simplify the major tendencies into a parameterized model add-on for use in global models to determine the importance of properly representing snowpack in global model simulations.
Heat exchange modeling in a multilayered karst aquifer affected by seawater intrusion
Directory of Open Access Journals (Sweden)
Luca Vettorello
2015-11-01
Full Text Available A Feflow thermohaline model has been implemented in order to study borehole heat exchangers (BHEs activity in a coastal aquifer in the South of Italy (Province of Lecce, Puglia Region. The modeled closed-loop system consists of two double u-pipe heat exchangers, installed in 200 meters deep boreholes. The main purpose of numerical modeling was to forecast thermal plume extension in groundwater after a long period of heat exchange, calculating temperature trends in observation points during a 10 years transport simulation. The complex geological structure, including calcarenites, fractured limestones and a deep karst aquifer, has been translated into a multilayered model, with a depth-related parameter distribution, assigning different values of hydraulic, thermal and chemical properties to each layer. In particular saltwater concentration has been taken into account, considering the influence of seawater intrusion on the heat transport density-dependent model. Parameters assignment was based on experimental datasets collected during initial field investigations, including thermal characterization of soil samples and GRTs, together with historical hydrogeological and hydrochemical measures and previous groundwater surveys. After model structure configuration and aquifers parameterization, a sensitivity analysis on porosity and heat dispersivity has been conducted, to evaluate their influence on thermal transport phenomena with a multiple scenarios approach, considering in particular the uncertainty related to secondary porosity in karst systems. Feflow simulation represented the first step in environmental compatibility evaluation for the BHE plant, waiting for the necessary model calibration with groundwater temperature monitoring trends.
A phenomenological model of mass-exchange between the inside and outside of a cavitation bubble
Institute of Scientific and Technical Information of China (English)
GAO XianXian; CHEN WeiZhong; HUANG Wei; XU JunFeng; XU XingHua; LIU YaNan; LIANG Yue
2009-01-01
The mass-exchange between the inside and outside of a cavitation bubble is a complicated process with several kinds of exchange forms acting together, such as gas diffusion, gas-liquid phase transition, chemical reactions and so on. A phenomenological model of mass-exchange was proposed, in which the pressure difference is considered as the drive. Compared with the previous physical models, It has a simpler form and less computational cost. Combining it with Rayleigh-Pleseet equation, the equilib-rium radius is calculated when the mass-exchange achieves the dynamic balance. The result shows that the equilibrium radius has multiple values. The relationships between the equilibrium radius and the driving ultrasound (pressure amplitude and frequency) are evaluated. We also investigated how these relationships were affected by the model parameters. Finally, the bubble radius evolution in the sulfuric acid driven by different pressures was measured. The experimental result that the equilibrium radius changes with the pressure agrees with the numerical results well.
Volume Averaging Theory (VAT) based modeling and closure evaluation for fin-and-tube heat exchangers
Zhou, Feng; Catton, Ivan
2012-10-01
A fin-and-tube heat exchanger was modeled based on Volume Averaging Theory (VAT) in such a way that the details of the original structure was replaced by their averaged counterparts, so that the VAT based governing equations can be efficiently solved for a wide range of parameters. To complete the VAT based model, proper closure is needed, which is related to a local friction factor and a heat transfer coefficient of a Representative Elementary Volume (REV). The terms in the closure expressions are complex and sometimes relating experimental data to the closure terms is difficult. In this work we use CFD to evaluate the rigorously derived closure terms over one of the selected REVs. The objective is to show how heat exchangers can be modeled as a porous media and how CFD can be used in place of a detailed, often formidable, experimental effort to obtain closure for the model.
A Three-State Markov-Modulated Switching Model for Exchange Rates
Directory of Open Access Journals (Sweden)
Idowu Oluwasayo Ayodeji
2016-01-01
Full Text Available Several authors have examined the long swings hypothesis in exchange rates using a two-state Markov switching model. This study developed a model to investigate long swings hypothesis in currencies which may exhibit a k-state (k≥2 pattern. The proposed model was then applied to euros, British pounds, Japanese yen, and Nigerian naira. Specification measures such as AIC, BIC, and HIC favoured a three-state pattern in Nigerian naira but a two-state one in the other three currencies. For the period January 2004 to May 2016, empirical results suggested the presence of asymmetric swings in naira and yen and long swings in euros and pounds. In addition, taking 0.5 as the benchmark for smoothing probabilities, choice models provided a clear reading of the cycle in a manner that is consistent with the realities of the movements in corresponding exchange rate series.
High Energy Proton-Proton Elastic Scattering in Reggeon-Pomeron Exchange Model
Institute of Scientific and Technical Information of China (English)
ZHOU Li-Juan; HU Zhao-Hui; MA Wei-Xing
2006-01-01
We initially propose a Reggeon-Pomeron exchange model to describe proton-proton elastic scattering at high energies in this short paper. A calculation for total cross section of proton-proton elastic scattering at high energies is performed without any free parameters. Our new finding from this work is that the Reggeon-Pomeron model gives a perfect fit to experimental data of the total cross section at the whole energy region where experimental data exist.
A MODEL OF HETEROGENEOUS DISTRIBUTED SYSTEM FOR FOREIGN EXCHANGE PORTFOLIO ANALYSIS
Dragutin Kermek; Neven Vrček; Tomislav Jakupić
2006-01-01
The paper investigates the design of heterogeneous distributed system for foreign exchange portfolio analysis. The proposed model includes few separated and dislocated but connected parts through distributed mechanisms. Making system distributed brings new perspectives to performance busting where software based load balancer gets very important role. Desired system should spread over multiple, heterogeneous platforms in order to fulfil open platform goal. Building such a model incorporates d...
Stock Exchange Competition in a Simple Model of Capital Market Equilibrium
Sofia B. Ramos; Ernst-Ludwig VON THADDEN
2003-01-01
This paper uses a simple model of mean-variance asset pricing with transaction costs to analyze one of the main empirical phenomena in stock market competition in the last years, the decrease of transaction costs. We endogenize transaction costs as variables strategically influenced by stock exchanges and model stock market integration as an increase in the correlation of the underlying stock market returns. Among other things, we find that market integration leads to a decrease of transactio...
Directory of Open Access Journals (Sweden)
Rybiński Witold
2016-09-01
Full Text Available The paper presents four 1-dimensional models of thermal resistance of walls in a heat exchanger with rectangular minichannels. The first model is the simplest one, with a single wall separating two fluids. The second model of the so called equivalent wall takes into account total volume of intermediate walls between layers of minichannels and of side walls of minichannels. The next two more complicated models take separately into account thermal resistance of these walls. In these two models side walls are treated as fins. The results of models comparison are presented. It is shown that thermal resistance may be neglected for metal walls but it should be taken into account for the walls made of plastics. For the case of non-neglected wall thermal resistance the optimum wall thickness was derived. Minichannel heat exchangers made of plastic are larger than those built of metal, but are significantly cheaper. It makes possible to use of such exchangers in inexpensive microscale ORC installations.
A surface complexation and ion exchange model of Pb and Cd competitive sorption on natural soils
Serrano, Susana; O'Day, Peggy A.; Vlassopoulos, Dimitri; García-González, Maria Teresa; Garrido, Fernando
2009-02-01
The bioavailability and fate of heavy metals in the environment are often controlled by sorption reactions on the reactive surfaces of soil minerals. We have developed a non-electrostatic equilibrium model (NEM) with both surface complexation and ion exchange reactions to describe the sorption of Pb and Cd in single- and binary-metal systems over a range of pH and metal concentration. Mineralogical and exchange properties of three different acidic soils were used to constrain surface reactions in the model and to estimate surface densities for sorption sites, rather than treating them as adjustable parameters. Soil heterogeneity was modeled with >FeOH and >SOH functional groups, representing Fe- and Al-oxyhydroxide minerals and phyllosilicate clay mineral edge sites, and two ion exchange sites (X - and Y -), representing clay mineral exchange. An optimization process was carried out using the entire experimental sorption data set to determine the binding constants for Pb and Cd surface complexation and ion exchange reactions. Modeling results showed that the adsorption of Pb and Cd was distributed between ion exchange sites at low pH values and specific adsorption sites at higher pH values, mainly associated with >FeOH sites. Modeling results confirmed the greater tendency of Cd to be retained on exchange sites compared to Pb, which had a higher affinity than Cd for specific adsorption on >FeOH sites. Lead retention on >FeOH occurred at lower pH than for Cd, suggesting that Pb sorbs to surface hydroxyl groups at pH values at which Cd interacts only with exchange sites. The results from the binary system (both Pb and Cd present) showed that Cd retained in >FeOH sites decreased significantly in the presence of Pb, while the occupancy of Pb in these sites did not change in the presence of Cd. As a consequence of this competition, Cd was shifted to ion exchange sites, where it competes with Pb and possibly Ca (from the background electrolyte). Sorption on >SOH
Modeling the contribution of abiotic exchange to CO2 flux in alkaline soils of arid areas
Institute of Scientific and Technical Information of China (English)
WenFeng WANG; Xi CHEN; GePing LUO; LongHui LI
2014-01-01
Recent studies on alkaline soils of arid areas suggest a possible contribution of abiotic exchange to soil CO2 flux (Fc). However, both the overall contribution of abiotic CO2 exchange and its drivers remain unknown. Here we analyzed the environmental variables suggested as possible drivers by previous studies and constructed a function of these variables to model the contribution of abiotic exchange to Fc in alkaline soils of arid areas. An automated flux system was employed to measure Fc in the Manas River Basin of Xinjiang Uygur autonomous region, China. Soil pH, soil temperature at 0-5 cm (Ts), soil volumetric water content at 0-5 cm (θs) and air temperature at 10 cm above the soil surface (Tas) were simultaneously analyzed. Results highlight reduced sensitivity of Fc to Ts and good prediction of Fc by the model Fc=R10Q10(Tas-10)/10+r7q7(pH-7)+λTas+µθs+e which represents Fc as a sum of biotic and abiotic components. This presents an approximate method to quantify the contribution of soil abiotic CO2 exchange to Fc in alkaline soils of arid areas.
Modelling the Dependence Structure of MUR/USD and MUR/INR Exchange Rates using Copula
Directory of Open Access Journals (Sweden)
Vandna Jowaheer
2012-01-01
Full Text Available American Dollar (USD and Indian Rupee (INR play an important role in Mauritian economy. It is important to model the pattern of dependence in their co-movement with respect to Mauritian Rupee (MUR, as this may indicate the export-import behavior in Mauritius. However, it is known that distributions of exchange rates are usually non-normal and the use of linear correlation as a dependence measure is inappropriate. Moreover it is quite difficult to obtain the joint distribution of such random variables in order to specify the complete covariance matrix to measure their dependence structure. In this paper, we first identify the marginal distributions of the exchange rates of MUR against USD and INR and then select the best fitting copula model for the bivariate series. It is concluded that both the series are asymmetric and fat-tailed following hyperbolic distribution. Their dependence structure is appropriately modeled by t copula.
A model of dynamic rewiring and knowledge exchange in R&D networks
Tomasello, Mario Vincenzo; Schweitzer, Frank
2015-01-01
This paper investigates the process of knowledge exchange in inter-firm Research and Development (R&D) alliances by means of an agent-based model. Extant research has pointed out that firms select alliance partners considering both network-related and network-unrelated features (e.g. social capital versus complementary knowledge stocks). In our agent-based model, firms are located in a metric knowledge space. The interaction rules incorporate an exploration phase and a knowledge transfer phase, during which firms search for a new partner and then evaluate whether they can establish a profitable alliance to mutually exchange their knowledge stocks. The model parameters determining the overall system properties are the rate at which alliances form and disappear and the agents' interaction radius. Next, we define a novel indicator of performance, based on the distance traveled by the firms in the knowledge space. Remarkably, we find that - depending on the alliance formation rate and the interaction radius -...
Energy exchange analysis in droplet dynamics via the Navier–Stokes–Cahn–Hilliard model
Espath, L. F. R.
2016-05-23
We develop the energy budget equation of the coupled Navier-Stokes-Cahn-Hilliard (NSCH) system. We use the NSCH equations to model the dynamics of liquid droplets in a liquid continuum. Buoyancy effects are accounted for through the Boussinesq assumption. We physically interpret each quantity involved in the energy exchange to gain further insight into the model. Highly resolved simulations involving density-driven flows and the merging of droplets allow us to analyse these energy budgets. In particular, we focus on the energy exchanges when droplets merge, and describe flow features relevant to this phenomenon. By comparing our numerical simulations to analytical predictions and experimental results available in the literature, we conclude that modelling droplet dynamics within the framework of NSCH equations is a sensible approach worthy of further research. © 2016 Cambridge University Press.
Glavev, Victor
2016-12-01
The types of software applications used by public administrations can be divided in three main groups: document management systems, record management systems and business process systems. Each one of them generates outputs that can be used as input data to the others. This is the main reason that requires exchange of data between these three groups and well defined models that should be followed. There are also many other reasons that will be discussed in the paper. Interoperability is a key aspect when those models are implemented, especially when there are different manufactures of systems in the area of software applications used by public authorities. The report includes examples of implementation of models for exchange of data between software systems deployed in one of the biggest administration in Bulgaria.
Guélat, Bertrand; Ströhlein, Guido; Lattuada, Marco; Delegrange, Lydia; Valax, Pascal; Morbidelli, Massimo
2012-08-31
A model was developed for the design of a monoclonal antibody charge variants separation process based on ion-exchange chromatography. In order to account for a broad range of operating conditions in the simulations, an explicit pH and salt concentration dependence has been included in the Langmuir adsorption isotherm. The reliability of this model was tested using experimental chromatographic retention times as well as information about the structural characteristics of the different charge variants, e.g. C-terminal lysine groups and deamidated groups. Next, overloaded isocratic elutions at various pH and salt concentrations have been performed to determine the saturation capacity of the ion-exchanger. Furthermore, the column simulation model was applied for the prediction of monoclonal antibody variants separations with both pH and salt gradient elutions. A good prediction of the elution times and peak shapes was observed, even though none of the model parameters was adjusted to fit the experimental data. The trends in the separation performance obtained through the simulations were generally sufficient to identify the most promising operating conditions. The predictive column simulation model thus developed in this work, including a set of parameters determined through specific independent experiments, was experimentally validated and offers a useful basis for a rational optimization of monoclonal antibody variants separation processes on ion-exchange chromatography.
Energy Technology Data Exchange (ETDEWEB)
Utgikar, Vivek [Univ. of Idaho, Moscow, ID (United States); Sun, Xiaodong [The Ohio State Univ., Columbus, OH (United States); Christensen, Richard [The Ohio State Univ., Columbus, OH (United States); Sabharwall, Piyush [Idaho National Lab. (INL), Idaho Falls, ID (United States)
2016-12-29
The overall goal of the research project was to model the behavior of the advanced reactorintermediate heat exchange system and to develop advanced control techniques for off-normal conditions. The specific objectives defined for the project were: 1. To develop the steady-state thermal hydraulic design of the intermediate heat exchanger (IHX); 2. To develop mathematical models to describe the advanced nuclear reactor-IHX-chemical process/power generation coupling during normal and off-normal operations, and to simulate models using multiphysics software; 3. To develop control strategies using genetic algorithm or neural network techniques and couple these techniques with the multiphysics software; 4. To validate the models experimentally The project objectives were accomplished by defining and executing four different tasks corresponding to these specific objectives. The first task involved selection of IHX candidates and developing steady state designs for those. The second task involved modeling of the transient and offnormal operation of the reactor-IHX system. The subsequent task dealt with the development of control strategies and involved algorithm development and simulation. The last task involved experimental validation of the thermal hydraulic performances of the two prototype heat exchangers designed and fabricated for the project at steady state and transient conditions to simulate the coupling of the reactor- IHX-process plant system. The experimental work utilized the two test facilities at The Ohio State University (OSU) including one existing High-Temperature Helium Test Facility (HTHF) and the newly developed high-temperature molten salt facility.
Energy Technology Data Exchange (ETDEWEB)
Neeway, James J.; Kerisit, Sebastien N.; Liu, Jia; Zhang, Jiandong; Zhu, Zihua; Riley, Brian J.; Ryan, Joseph V.
2016-05-05
Abstract: Ion exchange is an integral mechanism influencing the corrosion of glasses. Due to the formation of alteration layers in aqueous conditions, it is difficult to conclusively deconvolute the process of ion exchange from other processes, principally dissolution of the glass matrix. Therefore, we have developed a method to isolate alkali diffusion that involves contacting glass coupons with a solution of 6LiCl dissolved in functionally inert dimethyl sulfoxide. We employ the method at temperatures ranging from 25 to 150 °C with various glass formulations. Glass compositions include simulant nuclear waste glasses, such as SON68 and the international simple glass (ISG), glasses in which the nature of the alkali element was varied, and glasses that contained more than one alkali element. An interdiffusion model based on Fick’s second law was developed and applied to all experiments to extract diffusion coefficients. The model expands established models of interdiffusion to the case where multiple types of alkali sites are present in the glass. Activation energies for alkali ion exchange were calculated and the results are in agreement with those obtained in glass strengthening experiments but are nearly five times higher than values reported for diffusion-controlled processes in nuclear waste glass corrosion experiments. A discussion of the root causes for this apparent discrepancy is provided. The interdiffusion model derived from laboratory experiments is expected to be useful for modeling glass corrosion in a geological repository when the silicon concentration is high.
Directory of Open Access Journals (Sweden)
Andreea – Cristina PETRICĂ
2017-03-01
Full Text Available The aim of this study consists in examining the changes in the volatility of daily returns of EUR/RON exchange rate using on the one hand symmetric GARCH models (ARCH and GARCH and on the other hand the asymmetric GARCH models (EGARCH, TARCH and PARCH, since the conditional variance is time-varying. The analysis takes into account daily quotations of EUR/RON exchange rate over the period of 04th January 1999 to 13th June 2016. Thus, we are modeling heteroscedasticity by applying different specifications of GARCH models followed by looking for significant parameters and low information criteria (minimum Akaike Information Criterion. All models are estimated using the maximum likelihood method under the assumption of several distributions of the innovation terms such as: Normal (Gaussian distribution, Student’s t distribution, Generalized Error distribution (GED, Student’s with fixed df. Distribution, and GED with fixed parameter distribution. The predominant models turned out to be EGARCH and PARCH models, and the empirical results point out that the best model for estimating daily returns of EUR/RON exchange rate is EGARCH(2,1 with Asymmetric order 2 under the assumption of Student’s t distributed innovation terms. This can be explained by the fact that in case of EGARCH model, the restriction regarding the positivity of the conditional variance is automatically satisfied.
A one-dimensional heat transfer model for parallel-plate thermoacoustic heat exchangers.
de Jong, J A; Wijnant, Y H; de Boer, A
2014-03-01
A one-dimensional (1D) laminar oscillating flow heat transfer model is derived and applied to parallel-plate thermoacoustic heat exchangers. The model can be used to estimate the heat transfer from the solid wall to the acoustic medium, which is required for the heat input/output of thermoacoustic systems. The model is implementable in existing (quasi-)1D thermoacoustic codes, such as DeltaEC. Examples of generated results show good agreement with literature results. The model allows for arbitrary wave phasing; however, it is shown that the wave phasing does not significantly influence the heat transfer.
An H Theorem for Boltzmann's Equation for the Yard-Sale Model of Asset Exchange
Boghosian, Bruce M.; Johnson, Merek; Marcq, Jeremy A.
2015-12-01
In recent work (Boghosian, Phys Rev E 89:042804-042825, 2014; Boghosian, Int J Mod Phys 25:1441008-1441015, 2014), Boltzmann and Fokker-Planck equations were derived for the "Yard-Sale Model" of asset exchange. For the version of the model without redistribution, it was conjectured, based on numerical evidence, that the time-asymptotic state of the model was oligarchy—complete concentration of wealth by a single individual. In this work, we prove that conjecture by demonstrating that the Gini coefficient, a measure of inequality commonly used by economists, is an H function of both the Boltzmann and Fokker-Planck equations for the model.
Zhang, Ying; Majumder, Erica L-W; Yue, Hai; Blankenship, Robert E; Gross, Michael L
2014-09-09
A lack of X-ray or nuclear magnetic resonance structures of proteins inhibits their further study and characterization, motivating the development of new ways of analyzing structural information without crystal structures. The combination of hydrogen-deuterium exchange mass spectrometry (HDX-MS) data in conjunction with homology modeling can provide improved structure and mechanistic predictions. Here a unique diheme cytochrome c (DHCC) protein from Heliobacterium modesticaldum is studied with both HDX and homology modeling to bring some definition of the structure of the protein and its role. Specifically, HDX data were used to guide the homology modeling to yield a more functionally relevant structural model of DHCC.
DEFF Research Database (Denmark)
Haertel, Jan Hendrik Klaas; Nellis, Gregory F.
2017-01-01
. The conductance of the heat exchanger is maximized for a prescribed pressure drop and prescribed air-side temperature change across the heat exchanger. Polymer with infilled thermally conducting metal filaments is considered as the heat exchanger material which allows cost effective additive manufacturing...... optimized slot channel model in order to demonstrate the superior performance of the topology optimized designs. Thus, this work demonstrates the usefulness of topology optimization to fully exploit the design freedom afforded by additive manufacturing technologies....
Directory of Open Access Journals (Sweden)
Riané de Bruyn
2013-03-01
Full Text Available Evidence in favor of the monetary model of exchange rate determination for the South African Rand is, at best, mixed. A co-integrating relationship between the nominal exchange rate and monetary fundamentals forms the basis of the monetary model. With the econometric literature suggesting that the span of the data, not the frequency, determines the power of the co-integration tests and the studies on South Africa primarily using short-span data from the post-Bretton Woods era, we decided to test the long-run monetary model of exchange rate determination for the South African Rand relative to the US Dollar using annual data from 1910 – 2010. The results provide some support for the monetary model in that long-run co-integration is found between the nominal exchange rate and the output and money supply deviations. However, the theoretical restrictions required by the monetary model are rejected. A vector error-correction model identifies both the nominal exchange rate and the monetary fundamentals as the channel for the adjustment process of deviations from the long-run equilibrium exchange rate. A subsequent comparison of nominal exchange rate forecasts based on the monetary model with those of the random walk model suggests that the forecasting performance of the monetary model is superior.
Quasi-steady-state model of a counter flow air-to-air heat exchanger with phase change
DEFF Research Database (Denmark)
Rose, Jørgen; Nielsen, Toke Rammer; Kragh, Jesper;
2008-01-01
into account the effects of condensation and frost formation. The model is developed as an Excel spreadsheet, and specific results are compared with laboratory measurements. As an example, the model is used to determine the most energy-efficient control strategy for a specific heat-exchanger under northern......Using mechanical ventilation with highly efficient heat-recovery in northern European or arctic climates is a very efficient way of reducing the energy use for heating in buildings. However, it also presents a series of problems concerning condensation and frost formation in the heat......-exchanger. Developing highly efficient heat-exchangers and strategies to avoid/remove frost formation implies the use of detailed models to predict and evaluate different heat-exchanger designs and strategies. This paper presents a quasi-steady-state model of a counter-flow air-to-air heat-exchanger that takes...
Modeling the dynamic operation of a small fin plate heat exchanger - parametric analysis
Motyliński, Konrad; Kupecki, Jakub
2015-09-01
Given its high efficiency, low emissions and multiple fuelling options, the solid oxide fuel cells (SOFC) offer a promising alternative for stationary power generators, especially while engaged in micro-combined heat and power (μ-CHP) units. Despite the fact that the fuel cells are a key component in such power systems, other auxiliaries of the system can play a critical role and therefore require a significant attention. Since SOFC uses a ceramic material as an electrolyte, the high operating temperature (typically of the order of 700-900 °C) is required to achieve sufficient performance. For that reason both the fuel and the oxidant have to be preheated before entering the SOFC stack. Hot gases exiting the fuel cell stack transport substantial amount of energy which has to be partly recovered for preheating streams entering the stack and for heating purposes. Effective thermal integration of the μ-CHP can be achieved only when proper technical measures are used. The ability of efficiently preheating the streams of oxidant and fuel relies on heat exchangers which are present in all possible configurations of power system with solid oxide fuel cells. In this work a compact, fin plate heat exchanger operating in the high temperature regime was under consideration. Dynamic model was proposed for investigation of its performance under the transitional states of the fuel cell system. Heat exchanger was simulated using commercial modeling software. The model includes key geometrical and functional parameters. The working conditions of the power unit with SOFC vary due to the several factors, such as load changes, heating and cooling procedures of the stack and others. These issues affect parameters of the incoming streams to the heat exchanger. The mathematical model of the heat exchanger is based on a set of equations which are simultaneously solved in the iterative process. It enables to define conditions in the outlets of both the hot and the cold sides
Modeling the dynamic operation of a small fin plate heat exchanger – parametric analysis
Directory of Open Access Journals (Sweden)
Motyliński Konrad
2015-09-01
Full Text Available Given its high efficiency, low emissions and multiple fuelling options, the solid oxide fuel cells (SOFC offer a promising alternative for stationary power generators, especially while engaged in micro-combined heat and power (μ-CHP units. Despite the fact that the fuel cells are a key component in such power systems, other auxiliaries of the system can play a critical role and therefore require a significant attention. Since SOFC uses a ceramic material as an electrolyte, the high operating temperature (typically of the order of 700–900 °C is required to achieve sufficient performance. For that reason both the fuel and the oxidant have to be preheated before entering the SOFC stack. Hot gases exiting the fuel cell stack transport substantial amount of energy which has to be partly recovered for preheating streams entering the stack and for heating purposes. Effective thermal integration of the μ-CHP can be achieved only when proper technical measures are used. The ability of efficiently preheating the streams of oxidant and fuel relies on heat exchangers which are present in all possible configurations of power system with solid oxide fuel cells. In this work a compact, fin plate heat exchanger operating in the high temperature regime was under consideration. Dynamic model was proposed for investigation of its performance under the transitional states of the fuel cell system. Heat exchanger was simulated using commercial modeling software. The model includes key geometrical and functional parameters. The working conditions of the power unit with SOFC vary due to the several factors, such as load changes, heating and cooling procedures of the stack and others. These issues affect parameters of the incoming streams to the heat exchanger. The mathematical model of the heat exchanger is based on a set of equations which are simultaneously solved in the iterative process. It enables to define conditions in the outlets of both the hot and the
Zhu, Wei; Lin, Che-Jen; Wang, Xun; Sommar, Jonas; Fu, Xuewu; Feng, Xinbin
2016-04-01
Reliable quantification of air-surface fluxes of elemental Hg vapor (Hg0) is crucial for understanding mercury (Hg) global biogeochemical cycles. There have been extensive measurements and modeling efforts devoted to estimating the exchange fluxes between the atmosphere and various surfaces (e.g., soil, canopies, water, snow, etc.) in the past three decades. However, large uncertainties remain due to the complexity of Hg0 bidirectional exchange, limitations of flux quantification techniques and challenges in model parameterization. In this study, we provide a critical review on the state of science in the atmosphere-surface exchange of Hg0. Specifically, the advancement of flux quantification techniques, mechanisms in driving the air-surface Hg exchange and modeling efforts are presented. Due to the semi-volatile nature of Hg0 and redox transformation of Hg in environmental media, Hg deposition and evasion are influenced by multiple environmental variables including seasonality, vegetative coverage and its life cycle, temperature, light, moisture, atmospheric turbulence and the presence of reactants (e.g., O3, radicals, etc.). However, the effects of these processes on flux have not been fundamentally and quantitatively determined, which limits the accuracy of flux modeling. We compile an up-to-date global observational flux database and discuss the implication of flux data on the global Hg budget. Mean Hg0 fluxes obtained by micrometeorological measurements do not appear to be significantly greater than the fluxes measured by dynamic flux chamber methods over unpolluted surfaces (p = 0.16, one-tailed, Mann-Whitney U test). The spatiotemporal coverage of existing Hg0 flux measurements is highly heterogeneous with large data gaps existing in multiple continents (Africa, South Asia, Middle East, South America and Australia). The magnitude of the evasion flux is strongly enhanced by human activities, particularly at contaminated sites. Hg0 flux observations in East
Quantifying knowledge exchange in R&D networks: a data-driven model
Tomasello, Mario Vincenzo; Schweitzer, Frank
2015-01-01
We develop an agent-based model to reproduce the process of link formation and to understand the effect of knowledge exchange in collaborative inter-firm networks of Research and Development (R&D) alliances. In our model, agents form links based on their previous alliance history and then exchange knowledge with their partners, thus approaching in a knowledge space. We validate our model against real data using a two-step approach. Through an inter-firm alliance dataset, we estimate the model parameters related to the alliance formation, at the same time reproducing the topology of the resulting collaboration network. Subsequently, using a dataset on firm patents, we estimate the parameters related to the process of knowledge exchange. The underlying knowledge space that we consider in our study is defined by real patent classes, allowing for a precise quantification of every firm's knowledge position. We find that real R&D alliances have a duration of around two years, and that the subsequent knowled...
Designing a compatible model of share issue privatization for Tehran stock exchange (TSE development
Directory of Open Access Journals (Sweden)
Mohammad Aram Bonyar
2012-04-01
Full Text Available In this research, we conduct a reverse study to design a compatible model of share issue privatization for Tehran stock exchange (TSE development. Privatization and stock market development are known as two representatives of economic growth. Governments use these two economic means to achieve their development goals. In this study, the impact of share issue privatization on stock market development is studied and an optimal model of share issue privatization for Tehran stock exchange (TSE development is introduced. To study the effect of share issue privatization on key market development variables panel data of privatization index(IPIX, transaction volume, turnover velocity ratio and closing price of each TSE listed company are entered in co integration and error correction models (ECM during march 2008-June 2011. The result of statistical studies shows a significant relation between privatization index (IPIX growth and the growth of each of Tehran stock exchange development proxies. Then to design a compatible model of share issue privatization for Tehran stock market development, Delphi method following Schmitt approach during 4 phases is implemented.
DEFF Research Database (Denmark)
Heins, Anna-Lena; Lencastre Fernandes, Rita; Gernaey, Krist
2015-01-01
interconnected stirred tank reactors was used in combination with mathematical modeling, to mimic large-scale continuous cultivations. One reactor represents the feeding zone with high glucose concentration and low oxygen, whereas the other one represents the remaining reactor volume. An earlier developed...... were successfully validated experimentally. Single cell properties of two fluorescent reporter strains that were applied for deeper investigation of cell robustness characteristics and ethanol growth distributions were quantified compartment-wise revealing differences in cell population distributions...... related to environmental conditions and also compared with the one-compartment, conventional chemostat. CONCLUSION: Results underline the utility for the proposed combined approach as well as the use of continuous scale-down reactors for process investigations as insights concerning single...
Franco, A. F.; Landeros, P.
2016-09-01
We present a general model for the coupled magnetic resonances of an exchange interacting multilayer system, which can be implemented without complex analytical calculations or numerical simulations. The model allows one to study the spin wave modes of a multilayer structure with any number of layers, accounting for individual uniaxial and cubic anisotropies, and (static and dynamic) demagnetizing and external fields as well, assuming that only the interlayer exchange coupling mechanism is relevant between such magnetic layers. This scheme is applied to recent measurements of a NiFe/CoFe bilayer, and to studying the influence of the strength of ferromagnetic and antiferromagnetic exchange interactions and the applied field orientation on the spin wave modes and intensities of the ferromagnetic resonance response. We find that the acoustic oscillation mode tends to stabilize in frequency if the magnetizations of the layers are parallel to each other, while the optical mode stabilizes when the magnetizations are antiparallel. Furthermore, we find that each oscillation mode is governed by either the NiFe or the CoFe. The modes swap the governing layer as the perpendicular field increases, inducing a gap between their frequencies, which appears to be proportional to the exchange coupling. Finally, we find that the field linewidth of the bilayer due to Gilbert damping has a dependence on the frequency very similar to the linear dependence of the linewidth in single layers. The theoretical scheme presented here can be further used to explore magnetization dynamics in different multilayer architectures—such as exchange springs, structures with perpendicular magnetic anisotropy, and complex compositions of layer stacks—and can be useful as a basis to study multilayers with chiral and dipolar interactions.
Optimization of an industrial retrofitted heat exchanger network, using a stage-wise model
Energy Technology Data Exchange (ETDEWEB)
Kovac Kralj, Anita [Faculty of Chemistry and Chemical Engineering, University of Maribor, Smetanova 17, Maribor 2000 (Slovenia)
2010-12-15
The heat exchanger network (HEN) can be optimized using the stage-wise model of superstructure representation, as proposed by Yee and Grossmann. This model can be easily solved regarding both trivial problems, and serious and complex new industrial design plants. In this paper, a stage-wise model for new designs is extended for retrofits by using a stage-wise model for a retrofitted HEN. This method using a stage-wise model is very general; it can be used in new designs as well as during existing process integration. The methodology of the stage-wise model for retrofitted HEN can be used to solve HENs easily and well enough, over a short time, and simultaneously. A mathematical model of stage-wise for retrofit HEN can include additional equations and limitations for retrofits. This model was tested by using a retrofitted methanol process generating an additional profit of 189,200 EUR/a. (author)
Fabrication and comprehensive modeling of ion-exchanged Bragg optical add-drop multiplexers.
Castro, Jose M; Geraghty, David F; West, Brian R; Honkanen, Seppo
2004-11-20
Optical add-drop multiplexers (OADMs) based on asymmetric Y branches and tilted gratings offer excellent-performance in wavelength-division multiplexed systems. To simplify waveguide fabrication, ion-exchange techniques appear to be an important option in photosensitive glasses. Optimum OADM performance depends on how accurately the waveguide fabrication process and tilted Bragg grating operation are understood and modeled. Results from fabrication and comprehensive modeling are compared for ion-exchange processes that use different angles of the tilted grating. The transmission and reflection spectra for the fabricated and simulated OADMs show excellent agreement. The OADM's performance is evaluated in terms of the measured characteristics of the Y branches and tilted gratings.
Directory of Open Access Journals (Sweden)
Gayo Willy
2016-01-01
Full Text Available Philippine Stock Exchange Composite Index (PSEi is the main stock index of the Philippine Stock Exchange (PSE. PSEi is computed using a weighted mean of the top 30 publicly traded companies in the Philippines, called component stocks. It provides a single value by which the performance of the Philippine stock market is measured. Unfortunately, these weights, which may vary for every trading day, are not disclosed by the PSE. In this paper, we propose a model of forecasting the PSEi by estimating the weights based on historical data and forecasting each component stock using Monte Carlo simulation based on a Geometric Brownian Motion (GBM assumption. The model performance is evaluated and its forecast compared is with the results using a direct GBM forecast of PSEi over different forecast periods. Results showed that the forecasts using WGBM will yield smaller error compared to direct GBM forecast of PSEi.
Correlation between Gini index and mobility in a stochastic kinetic model of economic exchange
Bertotti, Maria Letizia; Chattopadhyay, Amit K.; Modanese, Giovanni
Starting from a class of stochastically driven kinetic models of economic exchange, here we present results highlighting the correlation of the Gini inequality index with the social mobility rate, close to dynamical equilibrium. Except for the ;canonical-additive case;, our numerical results consistently indicate negative values of the correlation coefficient, in agreement with empirical evidence. This confirms that growing inequality is not conducive to social mobility which then requires an ;external source; to sustain its dynamics. On the other hand, the sign of the correlation between inequality and total income in the canonical ensemble depends on the way wealth enters or leaves the system. At a technical level, the approach involves a generalization of a stochastic dynamical system formulation, that further paves the way for a probabilistic formulation of perturbed economic exchange models.
A numerical model for thermoelectric generator with the parallel-plate heat exchanger
Yu, Jianlin; Zhao, Hua
This paper presents a numerical model to predict the performance of thermoelectric generator with the parallel-plate heat exchanger. The model is based on an elemental approach and exhibits its feature in analyzing the temperature change in a thermoelectric generator and concomitantly its performance under operation conditions. The numerical simulated examples are demonstrated for the thermoelectric generator of parallel flow type and counter flow type in this paper. Simulation results show that the variations in temperature of the fluids in the thermoelectric generator are linear. The numerical model developed in this paper may be also applied to further optimization study for thermoelectric generator.
Marino, Michael G
2015-01-01
Polymeric anion exchange materials in membrane form can be key components in emerging energy storage and conversions systems such as the alkaline fuel cell and the RedOx flow battery. For these applications the membrane properties need to include good ionic conductivity and sufficient chemical stability, two aspects, that are not sufficiently understood in terms of materials science. Materials fulfilling both criteria are currently not available. The transport of ions and water in a model...
Fama and French Three-Factor Model: Evidence from Istanbul Stock Exchange
Veysel Eraslan
2013-01-01
This study tests the validity of the Fama and French three-factor asset pricing model on the Istanbul Stock Exchange (ISE). Monthly excess stock returns over the period from 2003 to 2010 are used in the analysis. Realized returns show that portfolios containing large firms have higher average excess returns than portfolios containing smaller sized firms. Generally, portfolios containing low book-to-market ratio firms perform better than those containing high book-to-market ratio firms. Nine p...
Biased thermohaline exchanges with the arctic across the Iceland-Faroe Ridge in ocean climate models
Directory of Open Access Journals (Sweden)
S. M. Olsen
2015-07-01
Full Text Available The northern limb of the Atlantic thermohaline circulation and its transport of heat and salt towards the Arctic strongly modulates the climate of the Northern Hemisphere. Presence of warm surface waters prevents ice formation in parts of the Arctic Mediterranean and ocean heat is in critical regions directly available for sea-ice melt, while salt transport may be critical for the stability of the exchanges. Hereby, ocean heat and salt transports play a disproportionally strong role in the climate system and realistic simulation is a requisite for reliable climate projections. Across the Greenland-Scotland Ridge (GSR this occurs in three well defined branches where anomalies in the warm and saline Atlantic inflow across the shallow Iceland-Faroe Ridge (IFR have shown particularly difficult to simulate in global ocean models. This branch (IF-inflow carries about 40 % of the total ocean heat transport into the Arctic Mediterranean and is well constrained by observation during the last two decades but is associated with significant inter-annual fluctuations. The inconsistency between model results and observational data is here explained by the inability of coarse resolution models to simulate the overflow across the IFR (IF-overflow, which feeds back on the simulated IF-inflow. In effect, this is reduced in the model to reflect only the net exchange across the IFR. Observational evidence is presented for a substantial and persistent IF-overflow and mechanisms that qualitatively control its intensity. Through this, we explain the main discrepancies between observed and simulated exchange. Our findings rebuild confidence in modeled net exchange across the IFR, but reveal that compensation of model deficiencies here through other exchange branches is not effective. This implies that simulated ocean heat transport to the Arctic is biased low by more than 10 % and associated with a reduced level of variability while the quality of the simulated salt
Biased thermohaline exchanges with the Arctic across the Iceland-Faroe Ridge in ocean climate models
Olsen, S. M.; Hansen, B.; Østerhus, S.; Quadfasel, D.; Valdimarsson, H.
2016-04-01
The northern limb of the Atlantic thermohaline circulation and its transport of heat and salt towards the Arctic strongly modulate the climate of the Northern Hemisphere. The presence of warm surface waters prevents ice formation in parts of the Arctic Mediterranean, and ocean heat is directly available for sea-ice melt, while salt transport may be critical for the stability of the exchanges. Through these mechanisms, ocean heat and salt transports play a disproportionally strong role in the climate system, and realistic simulation is a requisite for reliable climate projections. Across the Greenland-Scotland Ridge (GSR) this occurs in three well-defined branches where anomalies in the warm and saline Atlantic inflow across the shallow Iceland-Faroe Ridge (IFR) have been shown to be particularly difficult to simulate in global ocean models. This branch (IF-inflow) carries about 40 % of the total ocean heat transport into the Arctic Mediterranean and is well constrained by observation during the last 2 decades but associated with significant inter-annual fluctuations. The inconsistency between model results and observational data is here explained by the inability of coarse-resolution models to simulate the overflow across the IFR (IF-overflow), which feeds back onto the simulated IF-inflow. In effect, this is reduced in the model to reflect only the net exchange across the IFR. Observational evidence is presented for a substantial and persistent IF-overflow and mechanisms that qualitatively control its intensity. Through this, we explain the main discrepancies between observed and simulated exchange. Our findings rebuild confidence in modelled net exchange across the IFR, but reveal that compensation of model deficiencies here through other exchange branches is not effective. This implies that simulated ocean heat transport to the Arctic is biased low by more than 10 % and associated with a reduced level of variability, while the quality of the simulated salt
Finite element modeling of 129Xe diffusive gas exchange NMR in the human alveoli
Stewart, Neil J.; Parra-Robles, Juan; Wild, Jim M.
2016-10-01
Existing models of 129Xe diffusive exchange for lung microstructural modeling with time-resolved MR spectroscopy data have considered analytical solutions to one-dimensional, homogeneous models of the lungs with specific assumptions about the alveolar geometry. In order to establish a model system for simulating the effects of physiologically-realistic changes in physical and microstructural parameters on 129Xe exchange NMR, we have developed a 3D alveolar capillary model for finite element analysis. To account for the heterogeneity of the alveolar geometry across the lungs, we have derived realistic geometries for finite element analysis based on 2D histological samples and 3D micro-CT image volumes obtained from ex vivo biopsies of lung tissue from normal subjects and patients with interstitial lung disease. The 3D alveolar capillary model permits investigation of the impact of alveolar geometrical parameters and diffusion and perfusion coefficients on the in vivo measured 129Xe CSSR signal response. The heterogeneity of alveolar microstructure that is accounted for in image-based models resulted in considerable alterations to the shape of the 129Xe diffusive uptake curve when compared to 1D models. Our findings have important implications for the future design and optimization of 129Xe MR experiments and in the interpretation of lung microstructural changes from this data.
Bose-Hubbard model on a kagome lattice with sextic ring-exchange terms
Rousseau, Valéry G.; Tam, Ka-Ming; Jarrell, Mark; Moreno, Juana
2013-02-01
High-order ring-exchange interactions are crucial for the study of quantum fluctuations on many highly frustrated systems. A versatile and efficient quantum Monte Carlo method, which can handle finite and essentially zero temperature and canonical and grand-canonical ensembles, has long been sought. In this paper, we present an exact quantum Monte Carlo study of a model of hard-core bosons with sixth-order ring-exchange interactions on a two-dimensional kagome lattice. By using the stochastic Green function algorithm with global space-time update, we show that the system becomes unstable in the limit of large ring-exchange interactions. It undergoes a phase separation at all fillings, except at (1)/(3) and (2)/(3) fillings for which the superfluid density vanishes and an unusual mixed valence bond and charge density ordered solid is formed. This explains the universal features seen in previous studies on various different models, such as the transverse-field Ising models, on a kagome lattice near the classical limit.
Modeling and forecasting foreign exchange daily closing prices with normal inverse Gaussian
Teneng, Dean
2013-09-01
We fit the normal inverse Gaussian(NIG) distribution to foreign exchange closing prices using the open software package R and select best models by Käärik and Umbleja (2011) proposed strategy. We observe that daily closing prices (12/04/2008 - 07/08/2012) of CHF/JPY, AUD/JPY, GBP/JPY, NZD/USD, QAR/CHF, QAR/EUR, SAR/CHF, SAR/EUR, TND/CHF and TND/EUR are excellent fits while EGP/EUR and EUR/GBP are good fits with a Kolmogorov-Smirnov test p-value of 0.062 and 0.08 respectively. It was impossible to estimate normal inverse Gaussian parameters (by maximum likelihood; computational problem) for JPY/CHF but CHF/JPY was an excellent fit. Thus, while the stochastic properties of an exchange rate can be completely modeled with a probability distribution in one direction, it may be impossible the other way around. We also demonstrate that foreign exchange closing prices can be forecasted with the normal inverse Gaussian (NIG) Lévy process, both in cases where the daily closing prices can and cannot be modeled by NIG distribution.
Evaluating non-linear models on point and interval forecasts: an application with exchange rates
Directory of Open Access Journals (Sweden)
Emanuela Marrocu
2005-01-01
Full Text Available The aim of this paper is to compare the forecasting performance of SETAR and GARCH models against a linear benchmark using historical data for the returns of the Japanese yen/US dollar exchange rate. The relative performance of the models is evaluated on point forecasts and on interval forecasts. Point forecasts evaluation over the whole forecast period indicates that the performance of the models, when distinguishable, tends to favour the linear models. However, we show that if the evaluation of point forecasts is conducted over distinct subsamples or specific regimes there is more evidence of forecasting gains, especially from the SETAR models. Moreover, when we evaluate the validity of interval forecasts, the results produce clear evidence of the superiority of the non-linear models, and tend to favour especially the GARCH models.
APPLICATION OF DIVIDEND DISCOUNT MODEL VALUATION AT MACEDONIAN STOCK-EXCHANGE
Directory of Open Access Journals (Sweden)
Zoran Ivanovski
2015-06-01
Full Text Available Dividend discount model (DDM is the simplest model for valuing equities in finance. Many analysts belived that DDM is outmoded, but much of the intuition that drives Discounted Cash Flow (DCF valuation is embedded in the DDM model. There are also specific companies stocks where the DDM model remains a useful tool for estimating value. The basic task of these research is to examine if DDM models offer relevant and safe valuation of long-term securities at Macedonian Stock Exchange (MSE through the process of empirical valuation of random chosen stocks. This research helped us to identify problems in use of DDM valuation models at MSE, to determine causes for differences between the intrinsic values and the stock market prices and to determine basic parameters for implementation of valuation on Macedonian financial market. We find that DDM models are usefull only as additional tool beside relative and DCF stocks valuation at MSE.
Modelling fireside corrosion of heat exchangers in co-fired pulverised fuel power systems
Energy Technology Data Exchange (ETDEWEB)
Simms, N.J. [Cranfield Univ. (United Kingdom). Energy Technology Centre; Fry, A.T. [National Physical Laboratory, Teddington, Middlesex (United Kingdom)
2010-07-01
As a result of concerns about the effects of CO{sub 2} emissions on the global environment, there is increasing pressure to reduce such emissions from power generation systems. The use of biomass co-firing with coal in conventional pulverised fuel power stations has provided the most immediate route to introduce a class of fuel that is regarded as both sustainable and carbon neutral. In the future it is anticipated that increased levels of biomass will need to be used in such systems to achieve the desired CO{sub 2} emission targets. However there are concerns over the risk of fireside corrosion damage to the various heat exchangers and boiler walls used in such systems. Future pulverised fuel power systems will need to be designed to cope with the effects of using a wide range of coal-biomass mixes. However, such systems will also need to use much higher heat exchanger operating temperatures to increase their conversion efficiencies and counter the effects of the CO{sub 2} capture technologies that will need to be used in them. Higher operating temperatures will also increase the risk of fireside corrosion damage to the critical heat exchangers. This paper reports work that has been carried out to develop quantitative corrosion models for heat exchangers in pulverised fuel power systems. These developments have been particularly targeted at producing models that enable the evaluation of the effects of using different coal-biomass mixtures and of increasing heat exchanger operating conditions. Models have been produced that have been targeted at operating conditions and materials used in (a) superheaters/reheaters and (b) waterwalls. Data used in the development of these models has been produced from full scale and pilot scale plants in the UK using a wide range of coal and biomass mixtures, as well as from carefully targeted series of laboratory corrosion tests. Mechanistic and neural network based models have been investigated during this development process to
DEFF Research Database (Denmark)
Bjerg, Poul Løgstrup; Ammentorp, Hans Christian; Christensen, Thomas Højlund
1993-01-01
A large-scale and long-term field experiment on cation exchange in a sandy aquifer has been modelled by a three-dimensional geochemical transport model. The geochemical model includes cation-exchange processes using a Gaines-Thomas expression, the closed carbonate system and the effects of ionic...... of 800 days due to a substantially attenuation in the aquifer. The observed and the predicted breakthrough curves showed a reasonable accordance taking the duration of the experiment into account. However, some discrepancies were observed probably caused by the revealed non-ideal exchange behaviour of K+....
Study of a market model with conservative exchanges on complex networks
Braunstein, Lidia A.; Macri, Pablo A.; Iglesias, J. R.
2013-04-01
Many models of market dynamics make use of the idea of conservative wealth exchanges among economic agents. A few years ago an exchange model using extremal dynamics was developed and a very interesting result was obtained: a self-generated minimum wealth or poverty line. On the other hand, the wealth distribution exhibited an exponential shape as a function of the square of the wealth. These results have been obtained both considering exchanges between nearest neighbors or in a mean field scheme. In the present paper we study the effect of distributing the agents on a complex network. We have considered archetypical complex networks: Erdös-Rényi random networks and scale-free networks. The presence of a poverty line with finite wealth is preserved but spatial correlations are important, particularly between the degree of the node and the wealth. We present a detailed study of the correlations, as well as the changes in the Gini coefficient, that measures the inequality, as a function of the type and average degree of the considered networks.
Study of a Market Model with Conservative Exchanges on Complex Networks
Braunstein, L A; Iglesias, J R
2012-01-01
Many models of market dynamics make use of the idea of conservative wealth exchanges among economic agents. A few years ago an exchange model using extremal dynamics was developed and a very interesting result was obtained: a self-generated minimum wealth or poverty line. On the other hand, the wealth distribution exhibited an exponential shape as a function of the square of the wealth. These results have been obtained both considering exchanges between nearest neighbors or in a mean field scheme. In the present paper we study the effect of distributing the agents on a complex network. We have considered archetypical complex networks: Erd\\"{o}s-R\\'enyi random networks and scale-free networks. The presence of a poverty line with finite wealth is preserved but spatial correlations are important, particularly between the degree of the node and the wealth. We present a detailed study of the correlations, as well as the changes in the Gini coefficient, that measures the inequality, as a function of the type and av...
DFT calculations of EPR parameters for copper(II)-exchanged zeolites using cluster models.
Ames, William M; Larsen, Sarah C
2010-01-14
The coordination environment of Cu(II) in hydrated copper-exchanged zeolites was explored through the use of density functional theory (DFT) calculations of EPR parameters. Extensive experimental EPR data are available in the literature for hydrated copper-exchanged zeolites. The copper complex in hydrated copper-exchanged zeolites was previously proposed to be [Cu(H(2)O)(5)OH](+) based on empirical trends in tetragonal model complex EPR data. In this study, calculated EPR parameters for the previously proposed copper complex, [Cu(H(2)O)(5)OH](+), were compared to model complexes in which Cu(II) was coordinated to small silicate or aluminosilicate clusters as a first approximation of the impact of the zeolitic environment on the copper complex. Interpretation of the results suggests that Cu(II) is coordinated or closely associated with framework oxygen atoms within the zeolite structure. Additionally, it is proposed that the EPR parameters are dependent on the Si/Al ratio of the parent zeolite.
A review of air exchange rate models for air pollution exposure assessments.
Breen, Michael S; Schultz, Bradley D; Sohn, Michael D; Long, Thomas; Langstaff, John; Williams, Ronald; Isaacs, Kristin; Meng, Qing Yu; Stallings, Casson; Smith, Luther
2014-11-01
A critical aspect of air pollution exposure assessments is estimation of the air exchange rate (AER) for various buildings where people spend their time. The AER, which is the rate of exchange of indoor air with outdoor air, is an important determinant for entry of outdoor air pollutants and for removal of indoor-emitted air pollutants. This paper presents an overview and critical analysis of the scientific literature on empirical and physically based AER models for residential and commercial buildings; the models highlighted here are feasible for exposure assessments as extensive inputs are not required. Models are included for the three types of airflows that can occur across building envelopes: leakage, natural ventilation, and mechanical ventilation. Guidance is provided to select the preferable AER model based on available data, desired temporal resolution, types of airflows, and types of buildings included in the exposure assessment. For exposure assessments with some limited building leakage or AER measurements, strategies are described to reduce AER model uncertainty. This review will facilitate the selection of AER models in support of air pollution exposure assessments.
Neuville, Amélie; Schmittbuhl, Jean; 10.1111/j.1365-246X.2011.05126.x
2011-01-01
Natural open joints in rocks commonly present multi-scale self-affine apertures. This geometrical complexity affects fluid transport and heat exchange between the flow- ing fluid and the surrounding rock. In particular, long range correlations of self-affine apertures induce strong channeling of the flow which influences both mass and heat advection. A key question is to find a geometrical model of the complex aperture that describes at best the macroscopic properties (hydraulic conductivity, heat exchange) with the smallest number of parameters. Solving numerically the Stokes and heat equa- tions with a lubrication approximation, we show that a low pass filtering of the aperture geometry provides efficient estimates of the effective hydraulic and thermal properties (apertures). A detailed study of the influence of the bandwidth of the lowpass filtering on these transport properties is also performed. For instance, keeping the information of amplitude only of the largest Fourier length scales allows us to rea...
Relativistic model of 2p-2h meson exchange currents in (anti)neutrino scattering
Simo, I Ruiz; Barbaro, M B; De Pace, A; Caballero, J A; Donnelly, T W
2016-01-01
We develop a model of relativistic, charged meson-exchange currents (MEC) for neutrino-nucleus interactions. The two-body current is the sum of seagull, pion-in-flight, pion-pole and $\\Delta$-pole operators. These operators are obtained from the weak pion-production amplitudes for the nucleon derived in the non-linear $\\sigma$-model together with weak excitation of the $\\Delta(1232)$ resonance and its subsequent decay into $N\\pi$. With these currents we compute the five 2p-2h response functions contributing to $(\
Advances in understanding, models and parameterizations of biosphere-atmosphere ammonia exchange
Directory of Open Access Journals (Sweden)
C. R. Flechard
2013-07-01
Full Text Available Atmospheric ammonia (NH3 dominates global emissions of total reactive nitrogen (Nr, while emissions from agricultural production systems contribute about two-thirds of global NH3 emissions; the remaining third emanates from oceans, natural vegetation, humans, wild animals and biomass burning. On land, NH3 emitted from the various sources eventually returns to the biosphere by dry deposition to sink areas, predominantly semi-natural vegetation, and by wet and dry deposition as ammonium (NH4+ to all surfaces. However, the land/atmosphere exchange of gaseous NH3 is in fact bi-directional over unfertilized as well as fertilized ecosystems, with periods and areas of emission and deposition alternating in time (diurnal, seasonal and space (patchwork landscapes. The exchange is controlled by a range of environmental factors, including meteorology, surface layer turbulence, thermodynamics, air and surface heterogeneous-phase chemistry, canopy geometry, plant development stage, leaf age, organic matter decomposition, soil microbial turnover, and, in agricultural systems, by fertilizer application rate, fertilizer type, soil type, crop type, and agricultural management practices. We review the range of processes controlling NH3 emission and uptake in the different parts of the soil-canopy-atmosphere continuum, with NH3 emission potentials defined at the substrate and leaf levels by different [NH4+] / [H+] ratios (Γ. Surface/atmosphere exchange models for NH3 are necessary to compute the temporal and spatial patterns of emissions and deposition at the soil, plant, field, landscape, regional and global scales, in order to assess the multiple environmental impacts of airborne and deposited NH3 and NH4+. Models of soil/vegetation/atmosphere NH3 exchange are reviewed from the substrate and leaf scales to the global scale. They range from simple steady-state, "big leaf" canopy resistance models, to dynamic, multi-layer, multi-process, multi
Advances in understanding, models and parameterisations of biosphere-atmosphere ammonia exchange
Directory of Open Access Journals (Sweden)
C. R. Flechard
2013-03-01
Full Text Available Atmospheric ammonia (NH3 dominates global emissions of total reactive nitrogen (Nr, while emissions from agricultural production systems contribute about two thirds of global NH3 emissions; the remaining third emanates from oceans, natural vegetation, humans, wild animals and biomass burning. On land, NH3 emitted from the various sources eventually returns to the biosphere by dry deposition to sink areas, predominantly semi-natural vegetation, and by wet and dry deposition as ammonium (NH4+ to all surfaces. However, the land/atmosphere exchange of gaseous NH3 is in fact bi-directional over unfertilized as well as fertilized ecosystems, with periods and areas of emission and deposition alternating in time (diurnal, seasonal and space (patchwork landscapes. The exchange is controlled by a range of environmental factors, including meteorology, surface layer turbulence, thermodynamics, air and surface heterogeneous-phase chemistry, canopy geometry, plant development stage, leaf age, organic matter decomposition, soil microbial turnover, and, in agricultural systems, by fertilizer application rate, fertilizer type, soil type, crop type, and agricultural management practices. We review the range of processes controlling NH3 emission and uptake in the different parts of the soil-canopy-atmosphere continuum, with NH3 emission potentials defined at the substrate and leaf levels by different [NH4+] / [H+] ratios (Γ. Surface/atmosphere exchange models for NH3 are necessary to compute the temporal and spatial patterns of emissions and deposition at the soil, plant, field, landscape, regional and global scales, in order to assess the multiple environmental impacts of air-borne and deposited NH3 and NH4+. Models of soil/vegetation/atmosphereem NH3 exchange are reviewed from the substrate and leaf scales to the global scale. They range from simple steady-state, "big leaf" canopy resistance models, to dynamic, multi-layer, multi
Testing the CAPM and Three Factors Model in China: Evidence from the Shanghai Stock Exchange
Wang, Weixi
2015-01-01
Since inception, China’s stock market has grown rapidly and has become one of the most important emerging markets in the world. However, many popular financial media depicts China’s stock market as irrational. Besides, empirical studies on asset pricing in China’s stock market do not provide a consistent conclusion for different periods. This study tests the Capital Asset Pricing Model (CAPM) and Fama-French Three Factors Model in Shanghai Stock Exchange, China. For validity test of the CAPM,...
Kinetic exchange opinion model: solution in the single parameter map limit
Chowdhury, Krishanu Roy; Biswas, Soumyajyoti; Chakrabarti, Bikas K
2011-01-01
We study a recently proposed kinetic exchange opinion model (Lallouache et. al., Phys. Rev E 82, 056112 (2010)) in the limit of a single parameter map. Although it does not include the essentially complex behavior of the multiagent version, it provides us with the insight regarding the choice of order parameter for the system as well as some of its other dynamical properties. We also study the generalized two-parameter version of the model, and provide the exact phase diagram. The universal behavior along this phase boundary in terms of the suitably defined order parameter is seen.
Energy Technology Data Exchange (ETDEWEB)
Lazaro, Ana; Dolado, Pablo; Marin, Jose M.; Zalba, Belen [Aragon Institute for Engineering Research (I3A), Thermal Engineering and Energy Systems Group, Torres Quevedo Building, C/Maria de Luna 3, 50018 Zaragoza (Spain)
2009-03-15
This paper presents novel design conclusions based on the experimental results and on an empirical model for a real-scale prototype of a PCM-air heat exchanger. From experimental results, an empirical model was built aimed at simulating the thermal behavior in the tested heat exchanger in different cases. These simulations were used to evaluate the technical viability of its application. Since the thermal properties of PCM vary with temperature, a PCM-heat exchanger works as a transitory system and therefore, its design must be based on transitory analysis. This work shows that PCM selection criteria must include the power demand. The conclusions obtained for the PCM-air heat exchange can be useful for selecting PCM for other heat exchanger applications that use the tested geometry. (author)
Directory of Open Access Journals (Sweden)
Katherine A Dunn
Full Text Available Adequate modeling of mitochondrial sequence evolution is an essential component of mitochondrial phylogenomics (comparative mitogenomics. There is wide recognition within the field that lineage-specific aspects of mitochondrial evolution should be accommodated through lineage-specific amino-acid exchangeability matrices (e.g., mtMam for mammalian data. However, such a matrix must be applied to all sites and this implies that all sites are subject to the same, or largely similar, evolutionary constraints. This assumption is unjustified. Indeed, substantial differences are expected to arise from three-dimensional structures that impose different physiochemical environments on individual amino acid residues. The objectives of this paper are (1 to investigate the extent to which amino acid evolution varies among sites of mitochondrial proteins, and (2 to assess the potential benefits of explicitly modeling such variability. To achieve this, we developed a novel method for partitioning sites based on amino acid physiochemical properties. We apply this method to two datasets derived from complete mitochondrial genomes of mammals and fish, and use maximum likelihood to estimate amino acid exchangeabilities for the different groups of sites. Using this approach we identified large groups of sites evolving under unique physiochemical constraints. Estimates of amino acid exchangeabilities differed significantly among such groups. Moreover, we found that joint estimates of amino acid exchangeabilities do not adequately represent the natural variability in evolutionary processes among sites of mitochondrial proteins. Significant improvements in likelihood are obtained when the new matrices are employed. We also find that maximum likelihood estimates of branch lengths can be strongly impacted. We provide sets of matrices suitable for groups of sites subject to similar physiochemical constraints, and discuss how they might be used to analyze real data. We
Dunn, Katherine A.; Jiang, Wenyi; Field, Christopher; Bielawski, Joseph P.
2013-01-01
Adequate modeling of mitochondrial sequence evolution is an essential component of mitochondrial phylogenomics (comparative mitogenomics). There is wide recognition within the field that lineage-specific aspects of mitochondrial evolution should be accommodated through lineage-specific amino-acid exchangeability matrices (e.g., mtMam for mammalian data). However, such a matrix must be applied to all sites and this implies that all sites are subject to the same, or largely similar, evolutionary constraints. This assumption is unjustified. Indeed, substantial differences are expected to arise from three-dimensional structures that impose different physiochemical environments on individual amino acid residues. The objectives of this paper are (1) to investigate the extent to which amino acid evolution varies among sites of mitochondrial proteins, and (2) to assess the potential benefits of explicitly modeling such variability. To achieve this, we developed a novel method for partitioning sites based on amino acid physiochemical properties. We apply this method to two datasets derived from complete mitochondrial genomes of mammals and fish, and use maximum likelihood to estimate amino acid exchangeabilities for the different groups of sites. Using this approach we identified large groups of sites evolving under unique physiochemical constraints. Estimates of amino acid exchangeabilities differed significantly among such groups. Moreover, we found that joint estimates of amino acid exchangeabilities do not adequately represent the natural variability in evolutionary processes among sites of mitochondrial proteins. Significant improvements in likelihood are obtained when the new matrices are employed. We also find that maximum likelihood estimates of branch lengths can be strongly impacted. We provide sets of matrices suitable for groups of sites subject to similar physiochemical constraints, and discuss how they might be used to analyze real data. We also discuss how
An analytical model for estimating water exchange rate in white matter using diffusion MRI.
Davoodi-Bojd, Esmaeil; Chopp, Michael; Soltanian-Zadeh, Hamid; Wang, Shiyang; Ding, Guangliang; Jiang, Quan
2014-01-01
Substantial effort is being expended on using micro-structural modeling of the white matter, with the goal of relating diffusion weighted magnetic resonance imaging (DWMRI) to the underlying structure of the tissue, such as axonal density. However, one of the important parameters affecting diffusion is the water exchange rate between the intra- and extra-axonal space, which has not been fully investigated and is a crucial marker of brain injury such as multiple sclerosis (MS), stroke, and traumatic brain injury (TBI). To our knowledge, there is no diffusion analytical model which includes the Water eXchange Rate (WXR) without the requirement of short gradient pulse (SGP) approximation. We therefore propose a new analytical model by deriving the diffusion signal for a permeable cylinder, assuming a clinically feasible pulse gradient spin echo (PGSE) sequence. Simulations based on Markov Random Walk confirm that the exchange parameter included in our model has a linear correlation (R2>0.88) with the actual WXR. Moreover, increasing WXR causes the estimated values of diameter and volume fraction of the cylinders to increase and decrease, respectively, which is consistent with our findings from histology measurements in tissues near TBI regions. This model was also applied to the diffusion signal acquired from ex vivo brains of 14 male (10 TBI and 4 normal) rats using hybrid diffusion imaging. The estimated values of axon diameter and axonal volume fraction are in agreement with their corresponding histological measurements in normal brains, with 0.96 intra-class correlation coefficient value resulting from consistency analysis. Moreover, a significant increase (p = 0.001) in WXR and diameter and decrease in axonal volume fraction in the TBI boundary were detected in the TBI rats compared with the normal rats.
A Time-Varying Parameter Vector Autoregression Model for Forecasting Emerging Market Exchange Rates
Directory of Open Access Journals (Sweden)
Manish Kumar
2010-12-01
Full Text Available In this study, a vector autoregression (VAR model with time-varying parameters (TVP to predict the daily Indian rupee (INR/US dollar (USD exchange rates for the Indian economy is developed. The method is based on characterization of the TVP as an optimal control problem. The methodology is a blend of the flexible least squares and Kalman filter techniques. The out-of-sample forecasting performance of the TVP-VAR model is evaluated against the simple VAR and ARIMA models, by employing a cross-validation process and metrics such as mean absolute error, root mean square error, and directional accuracy. Outof-sample results in terms of conventional forecast evaluation statistics and directional accuracy show TVP-VAR model consistently outperforms the simple VAR and ARIMA models.
Password-only authenticated three-party key exchange with provable security in the standard model.
Nam, Junghyun; Choo, Kim-Kwang Raymond; Kim, Junghwan; Kang, Hyun-Kyu; Kim, Jinsoo; Paik, Juryon; Won, Dongho
2014-01-01
Protocols for password-only authenticated key exchange (PAKE) in the three-party setting allow two clients registered with the same authentication server to derive a common secret key from their individual password shared with the server. Existing three-party PAKE protocols were proven secure under the assumption of the existence of random oracles or in a model that does not consider insider attacks. Therefore, these protocols may turn out to be insecure when the random oracle is instantiated with a particular hash function or an insider attack is mounted against the partner client. The contribution of this paper is to present the first three-party PAKE protocol whose security is proven without any idealized assumptions in a model that captures insider attacks. The proof model we use is a variant of the indistinguishability-based model of Bellare, Pointcheval, and Rogaway (2000), which is one of the most widely accepted models for security analysis of password-based key exchange protocols. We demonstrated that our protocol achieves not only the typical indistinguishability-based security of session keys but also the password security against undetectable online dictionary attacks.
Password-Only Authenticated Three-Party Key Exchange with Provable Security in the Standard Model
Directory of Open Access Journals (Sweden)
Junghyun Nam
2014-01-01
Full Text Available Protocols for password-only authenticated key exchange (PAKE in the three-party setting allow two clients registered with the same authentication server to derive a common secret key from their individual password shared with the server. Existing three-party PAKE protocols were proven secure under the assumption of the existence of random oracles or in a model that does not consider insider attacks. Therefore, these protocols may turn out to be insecure when the random oracle is instantiated with a particular hash function or an insider attack is mounted against the partner client. The contribution of this paper is to present the first three-party PAKE protocol whose security is proven without any idealized assumptions in a model that captures insider attacks. The proof model we use is a variant of the indistinguishability-based model of Bellare, Pointcheval, and Rogaway (2000, which is one of the most widely accepted models for security analysis of password-based key exchange protocols. We demonstrated that our protocol achieves not only the typical indistinguishability-based security of session keys but also the password security against undetectable online dictionary attacks.
Energy Technology Data Exchange (ETDEWEB)
Hughes, Patrick [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Im, Piljae [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
2012-04-01
(FHX) has been coined to refer exclusively to ground heat exchangers installed in the overcut around the basement walls. The primary technical challenge undertaken by this project was the development and validation of energy performance models and design tools for FHX. In terms of performance modeling and design, ground heat exchangers in other construction excavations (e.g., utility trenches) are no different from conventional HGHX, and models and design tools for HGHX already exist. This project successfully developed and validated energy performance models and design tools so that FHX or hybrid FHX/HGHX systems can be engineered with confidence, enabling this technology to be applied in residential and light commercial buildings. The validated energy performance model also addresses and solves another problem, the longstanding inadequacy in the way ground-building thermal interaction is represented in building energy models, whether or not there is a ground heat exchanger nearby. Two side-by-side, three-level, unoccupied research houses with walkout basements, identical 3,700 ft{sup 2} floor plans, and hybrid FHX/HGHX systems were constructed to provide validation data sets for the energy performance model and design tool. The envelopes of both houses are very energy efficient and airtight, and the HERS ratings of the homes are 44 and 45 respectively. Both houses are mechanically ventilated with energy recovery ventilators, with space conditioning provided by water-to-air heat pumps with 2 ton nominal capacities. Separate water-to-water heat pumps with 1.5 ton nominal capacities were used for water heating. In these unoccupied research houses, human impact on energy use (hot water draw, etc.) is simulated to match the national average. At House 1 the hybrid FHX/HGHX system was installed in 300 linear feet of excavation, and 60% of that was construction excavation (needed to construct the home). At House 2 the hybrid FHX/HGHX system was installed in 360 feet of
Energy Technology Data Exchange (ETDEWEB)
Hughes, Patrick [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Im, Piljae [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
2012-01-01
(FHX) has been coined to refer exclusively to ground heat exchangers installed in the overcut around the basement walls. The primary technical challenge undertaken by this project was the development and validation of energy performance models and design tools for FHX. In terms of performance modeling and design, ground heat exchangers in other construction excavations (e.g., utility trenches) are no different from conventional HGHX, and models and design tools for HGHX already exist. This project successfully developed and validated energy performance models and design tools so that FHX or hybrid FHX/HGHX systems can be engineered with confidence, enabling this technology to be applied in residential and light commercial buildings. The validated energy performance model also addresses and solves another problem, the longstanding inadequacy in the way ground-building thermal interaction is represented in building energy models, whether or not there is a ground heat exchanger nearby. Two side-by-side, three-level, unoccupied research houses with walkout basements, identical 3,700 ft{sup 2} floor plans, and hybrid FHX/HGHX systems were constructed to provide validation data sets for the energy performance model and design tool. The envelopes of both houses are very energy efficient and airtight, and the HERS ratings of the homes are 44 and 45 respectively. Both houses are mechanically ventilated with energy recovery ventilators, with space conditioning provided by water-to-air heat pumps with 2 ton nominal capacities. Separate water-to-water heat pumps with 1.5 ton nominal capacities were used for water heating. In these unoccupied research houses, human impact on energy use (hot water draw, etc.) is simulated to match the national average. At House 1 the hybrid FHX/HGHX system was installed in 300 linear feet of excavation, and 60% of that was construction excavation (needed to construct the home). At House 2 the hybrid FHX/HGHX system was installed in 360 feet of
Directory of Open Access Journals (Sweden)
V. A. Lapin
2009-09-01
Full Text Available The mathematical model of heat transfer in vortex heat exchanger using natural gas energy which is released under decompression in gas-main pipe-lines for consumers of gas supply systems (dwellings, public and industrial buildings.
Modeling of dual gradient elution in ion exchange and mixed-mode chromatography.
Lee, Yi Feng; Schmidt, Michael; Graalfs, Heiner; Hafner, Mathias; Frech, Christian
2015-10-23
Protein retention using dual gradient elution in ion exchange- and mixed-mode chromatography can be modeled using the combination of a modified Yamamoto's LGE model and a conversion term to correlate the elution salt concentration and pH at any given gradient slope. Incorporation of the pH dependence of the binding charges into the model also provides some insights on the dual effects of salt and pH in protein-ligand interaction. The fitted thermodynamic parameters (ΔGP(0)/RT, ΔGS(0)/RT, number of charged amino acids involved in binding) of the dual gradient elution data using lysozyme and mAbs on SP Sepharose(®) FF, Eshmuno(®) HCX, and Capto(®) MMC ImpRes were consistent to the results of mono gradient data. This gives rise to an approach to perform thermodynamic modeling of protein retention in ion exchange- and mixed-mode chromatography by combining both salt and pH gradient into a single run of dual gradient elution which will increase time and cost efficiency. The dual gradients used in this study encompassed a wide range of pH (4-8) and NaCl concentrations (0-1M). Curve fits showed that ΔGP(0)/RT is protein type and ligand dependent. ΔGS(0)/RT is strongly dependent on the stationary phase but not the protein. For mAb04 on mixed-mode resin Capto(®) MMC, ΔGS(0)/RT is 5-6 times higher than the result reported for the same protein on cation exchanger Fractogel(®) EMD SO3(-) (S).
A parameter model of gas exchange for the seasonal sea ice zone
Directory of Open Access Journals (Sweden)
B. Loose
2013-07-01
Full Text Available Carbon budgets for the polar oceans require better constraint on air-sea gas exchange in the sea ice zone (SIZ. Here, we utilize recent advances in the theory of turbulence, mixing and air-sea flux in the ice-ocean boundary layer (IOBL to formulate a simple model for gas exchange when the surface ocean is partially covered by sea ice. The gas transfer velocity (k is related to shear-driven and convection-driven turbulence in the aqueous mass boundary layer, and to the mean-squared wave slope at the air–sea interface. We use the model to estimate k along the drift track of Ice-Tethered Profilers (ITPs in the Arctic. Individual estimates of daily-averaged k from ITP drifts ranged between 1.1 and 22 m d−1, and the fraction of open water (f ranged from 0 to 0.83. Converted to area-weighted effective transfer velocities (keff, the minimum value of keff was 10−5 m d−1 near f = 0 with values exceeding keff = 5 m d−1 at f = 0.4. The largest values of k occurred during the periods when ice cover around the ITP was changing rapidly; either in advance or retreat. The model indicates that effects from shear and convection in the sea ice zone contribute an additional 40% to the magnitude of keff, beyond what would be predicted from an estimate of keff based solely upon a windspeed parameterization. Although the ultimate scaling relationship for gas exchange in the sea ice zone will require validation in laboratory and field studies, the basic parameter model described here demonstrates that it is feasible to formulate estimates of k based upon properties of the IOBL using data sources that presently exist.
Influence of grain size and exchange interaction on the LLB modeling procedure
Vogler, Christoph; Abert, Claas; Bruckner, Florian; Suess, Dieter; Praetorius, Dirk
2016-12-01
Reliably predicting bit-error rates in realistic heat-assisted magnetic recording simulations is a challenging task. Integrating the Landau-Lifshitz-Bloch (LLB) equation, within a coarse graining approach, can reduce the computational effort to determine the magnetization dynamics in the vicinity of the Curie temperature, compared to solving the atomistic Landau-Lifshitz-Gilbert equation. If the aim is that the dynamics of both approaches coincide, temperature dependent material functions, such as the zero-field equilibrium magnetization as well as the parallel and normal susceptibilities, must be modeled carefully in order to use them as input in the LLB equation. We present an extensive study on how these functions depend on grain size and exchange interactions. We show that, if the size or the exchange constant of a reference grain is modified, the material functions can be scaled, according to the changed Curie temperature, yielding negligible errors. This is shown to be valid for volume changes of up to ±40% and variations of the exchange constant of up to ±10%. Besides the temperature dependent material curves, computed switching probabilities also agree well with probabilities separately determined for each system. Our study suggests that there is no need to recalculate the required LLB input functions for each particle. Within the presented limits, it is sufficient to scale them to the Curie temperature of the altered system.
Alguacil,Francisco José; Alonso Gámez, Manuel; Lozano, Kuis Javier
2004-01-01
The use of ion exchange technology was studied to remove chromium (III) from acidic waste solution by Amberlite IR-120 resin. Batch and column experimental tests were conducted to provide data for theoretical models and verify the system performance of the adsorption process. Results of batch equilibrium tests indicated that Langmuir isotherm describes well the adsorption process, whereas experimental data also provide evidence that, under the present experimental conditions, chro...
Modeling cesium ion exchange on fixed-bed columns of crystalline silicotitanate granules
Energy Technology Data Exchange (ETDEWEB)
Latheef, I.M.; Huckman, M.E.; Anthony, R.G.
2000-05-01
A mathematical model is presented to simulate Cs exchange in fixed-bed columns of a novel crystalline silicotitanate (CST) material, UOP IONSIV IE-911. A local equilibrium is assumed between the macropores and the solid crystals for the particle material balance. Axial dispersed flow and film mass-transfer resistance are incorporated into the column model. Cs equilibrium isotherms and diffusion coefficients were measured experimentally, and dispersion and film mass-transfer coefficients were estimated from correlations. Cs exchange column experiments were conducted in 5--5.7 M Na solutions and simulated using the proposed model. Best-fit diffusion coefficients from column simulations were compared with previously reported batch values of Gu et al. and Huckman. Cs diffusion coefficients for the column were between 2.5 and 5.0 x 10{sup {minus}11} m{sup 2}/s for 5--5.7 M Na solutions. The effect of the isotherm shape on the Cs diffusion coefficient was investigated. The proposed model provides good fits to experimental data and may be utilized in designing commercial-scale units.
Assessment of model estimates of land–atmosphere CO2 exchange across Northern Eurasia
Directory of Open Access Journals (Sweden)
M. A. Rawlins
2015-02-01
Full Text Available A warming climate is altering land–atmosphere exchanges of carbon, with a potential for increased vegetation productivity as well as the mobilization of permafrost soil carbon stores. Here we investigate land–atmosphere carbon dioxide (CO2 dynamics through analysis of net ecosystem productivity (NEP and its component fluxes of gross primary productivity (GPP and ecosystem respiration (ER and soil carbon residence time, simulated by a set of land surface models (LSMs over a region spanning the drainage basin of northern Eurasia. The retrospective simulations were conducted over the 1960–2009 record and at 0.5° resolution, which is a scale common among many global carbon and climate model simulations. Model performance benchmarks were drawn from comparisons against both observed CO2 fluxes derived from site-based eddy covariance measurements as well as regional-scale GPP estimates based on satellite remote sensing data. The site-based comparisons show the timing of peak GPP to be well simulated. Modest overestimates in model GPP and ER are also found, which are relatively higher for two boreal forest validation sites than the two tundra sites. Across the suite of model simulations, NEP increases by as little as 0.01 to as much as 0.79 g C m−2 yr−2, equivalent to 3 to 340% of the respective model means, over the analysis period. For the multimodel average the increase is 135% of the mean from the first to last ten years of record (1960–1969 vs 2000–2009, with a weakening CO2 sink over the latter decades. Vegetation net primary productivity increased by 8 to 30% from the first to last ten years, contributing to soil carbon storage gains, while model mean residence time for soil organic carbon decreased by 10% (−5 to −16%. This suggests that inputs to the soil carbon pool exceeded losses, resulting in a net gain amid a decrease in residence time. Our analysis points to improvements in model elements controlling vegetation
Behavior of human serum albumin on strong cation exchange resins: II. model analysis.
Voitl, Agnes; Butté, Alessandro; Morbidelli, Massimo
2010-08-20
Experiments with human serum albumin on a strong cation exchange resin exhibit a peculiar elution pattern: the protein elutes with two peaks in a modifier gradient. This behavior is modeled with a general rate model, where the two elution peaks are modeled with two binding conformations, one of which is at equilibrium conditions, while for the other, the adsorption process is rate limited. Isocratic experiments under nonadsorbing conditions were used to characterize the mass transfer process. The isotherm of both adsorption conformations as well as the kinetic of adsorption and desorption for the second conformation are functions of the modifier concentration. They are evaluated with linear modifier gradient experiments and step experiments with various adsorption times. All experimental features are well reproduced by the proposed modified general rate model.
Modelling shelf-ocean exchange and its biogeochemical consequences in coastal upwelling systems
DEFF Research Database (Denmark)
Muchamad, Al Azhar
reactions and biological respiration of marine organic matter (remineralization) under oxic and anoxic conditions. The developed model was coupled into a three-dimensional physical circulation model called the Regional Ocean Modeling System (ROMS). Then, the coupled model was employed and calibrated...... to relatively wide shelf areas because more sinking organic matter reach the shelf sea-floor and remineralize there, enhancing the nutrient trapping effect of the shelf circulation system. These results highlight the important role of the continental shelf bathymetry in modulating the shelf–ocean exchange......The biogeochemical cycles of organic carbon, nutrients, oxygen, and sulfur in the oceans have been suggested to dominantly occur across the shelf–ocean transition over the continental margin, although this zone represents only a small percentage of the global ocean area. Coastal upwelling zones...
Heat exchanger modelling in central receiver solar power plant using dense particle suspension
Reyes-Belmonte, Miguel A.; Gómez-García, Fabrisio; González-Aguilar, José; Romero, Manuel; Benoit, Hadrien; Flamant, Gilles
2017-06-01
In this paper, a detailed thermodynamic model for a heat exchanger (HX) working with a dense particle suspension (DPS) as heat transfer fluid (HTF) in the solar loop and water-steam as working fluid is presented. HX modelling is based on fluidized bed (FB) technology and its design has been conceived to couple solar plant using DPS as HTF and storage media with Rankine cycle for power generation. Using DPS as heat transfer fluid allows extending operating temperature range what will help to reduce thermal energy storage costs favoring higher energy densities but will also allow running power cycle at higher temperature what will increase its efficiency. Besides HX modelling description, this model will be used to reproduce solar plant performance under steady state and transient conditions.
An non-uniformity voltage model for proton exchange membrane fuel cell
Li, Kelei; Li, Yankun; Liu, Jiawei; Guo, Ai
2017-01-01
The fuel cell used in transportation has environmental protection, high efficiency and no line traction power system which can greatly reduce line construction investment. That makes it a huge potential. The voltage uniformity is one of the most important factors affecting the operation life of proton exchange membrane fuel cell (PEMFC). On the basis of principle and classical model of the PEMFC, single cell voltage is calculated and the location coefficients are introduced so as to establish a non-uniformity voltage model. These coefficients are estimated with the experimental datum at stack current 50 A. The model is validated respectively with datum at 60 A and 100 A. The results show that the model reflects the basic characteristics of voltage non-uniformity and provides the beneficial reference for fuel cell control and single cell voltage detection.
Neural network modeling and control of proton exchange membrane fuel cell
Institute of Scientific and Technical Information of China (English)
CHEN Yue-hua; CAO Guang-yi; ZHU Xin-jian
2007-01-01
A neural network model and fuzzy neural network controller was designed to control the inner impedance of a proton exchange membrane fuel cell(PEMFC)stack. A radial basis function(RBF)neural network model was trained by the input-output data of impedance. A fuzzy neural network controller Was designed to control the impedance response.The RBF neural network model was used to test the fuzzy neural network controller.The results show that the RBF model output Can imitate actual output well, themaximal errorisnotbeyond 20 mΩ, thetrainingtime is about 1 s by using 20 neurons, and the mean squared errors is 141.9 mΩ2.The impedance of the PEMFC stack is controlled within the optimum range when the load changes, and the adjustive time is ahnllt 3 rain.
Modelling short-term variability in carbon and water exchange in a temperate Scots pine forest
Directory of Open Access Journals (Sweden)
M. H. Vermeulen
2015-02-01
Full Text Available Vegetation – atmosphere carbon and water exchange at one particular site can strongly vary from year to year, and understanding this interannual variability in carbon and water exchange (IAVcw is a critical factor in projecting future ecosystem changes. However, the mechanisms driving this IAVcw are not well understood. We used data on carbon and water fluxes from a multi-year Eddy Covariance study (1997–2009 in a Dutch Scots pine forest and forced a process-based ecosystem model (LPJ-GUESS with local data to, firstly, test whether the model can explain IAVcw and seasonal carbon and water exchange from direct environmental factors only. Initial model runs showed low correlations with estimated annual gross primary productivity (GPP and annual actual evapotranspiration (AET, while monthly and daily fluxes showed high correlations. The model underestimated GPP and AET during winter and drought events. Secondly, we adapted the temperature inhibition function of photosynthesis to account for the observation that at this particular site, trees continue to assimilate at very low atmospheric temperatures (up to daily averages of −10 °C, resulting in a net carbon sink in winter. While we were able to improve daily and monthly simulations during winter by lowering the modelled minimum temperature threshold for photosynthesis, this did not increase explained IAVcw at the site. Thirdly, we implemented three alternative hypotheses concerning water uptake by plants in order to test which one best corresponds with the data. In particular, we analyse the effects during the 2003 heatwave. These simulations revealed a strong sensitivity of the modelled fluxes during dry and warm conditions, but no single formulation was consistently superior in reproducing the data for all time scales and the overall model-data match for IAVcw could not be improved. Most probably access to deep soil water leads to higher AET and GPP simulated during the heat wave of 2003
Energy Technology Data Exchange (ETDEWEB)
Phu, Nguyen Minh; Trinh, Nguyen Thi Minh [Vietnam National University, Ho Chi Minh City (Viet Nam)
2016-07-15
Today the helical coil heat exchanger is being employed widely due to its dominant advantages. In this study, a mathematical model was established to predict off-design works of the helical heat exchanger. The model was based on the LMTD and e-NTU methods, where a LMTD correction factor was taken into account to increase accuracy. An experimental apparatus was set-up to validate the model. Results showed that errors of thermal duty, outlet hot fluid temperature, outlet cold fluid temperature, shell-side pressure drop, and tube-side pressure drop were respectively +-5%, +-1%, +-1%, +-5% and +-2%. Diagrams of dimensionless operating parameters and a regression function were also presented as design-maps, a fast calculator for usage in design and operation of the exchanger. The study is expected to be a good tool to estimate off-design conditions of the single-phase helical heat exchangers.
Finite line-source model for borehole heat exchangers. Effect of vertical temperature variations
Energy Technology Data Exchange (ETDEWEB)
Bandos, Tatyana V.; Fernandez, Esther; Santander, Juan Luis G.; Isidro, Jose Maria; Perez, Jezabel; Cordoba, Pedro J. Fernandez de [Instituto Universitario de Matematica Pura y Aplicada, Universidad Politecnica de Valencia, Camino de Vera s/n, 46022 Valencia (Spain); Montero, Alvaro; Urchueguia, Javier F. [Instituto de Ingenieria Energetica, Universidad Politecnica de Valencia, Camino de Vera s/n, 46022 Valencia (Spain)
2009-06-15
A solution to the three-dimensional finite line-source (FLS) model for borehole heat exchangers (BHEs) that takes into account the prevailing geothermal gradient and allows arbitrary ground surface temperature changes is presented. Analytical expressions for the average ground temperature are derived by integrating the exact solution over the line-source depth. A self-consistent procedure to evaluate the in situ thermal response test (TRT) data is outlined. The effective thermal conductivity and the effective borehole thermal resistance can be determined by fitting the TRT data to the time-series expansion obtained for the average temperature. (author)
Breen, Michael S; Breen, Miyuki; Williams, Ronald W; Schultz, Bradley D
2010-12-15
A critical aspect of air pollution exposure models is the estimation of the air exchange rate (AER) of individual homes, where people spend most of their time. The AER, which is the airflow into and out of a building, is a primary mechanism for entry of outdoor air pollutants and removal of indoor source emissions. The mechanistic Lawrence Berkeley Laboratory (LBL) AER model was linked to a leakage area model to predict AER from questionnaires and meteorology. The LBL model was also extended to include natural ventilation (LBLX). Using literature-reported parameter values, AER predictions from LBL and LBLX models were compared to data from 642 daily AER measurements across 31 detached homes in central North Carolina, with corresponding questionnaires and meteorological observations. Data was collected on seven consecutive days during each of four consecutive seasons. For the individual model-predicted and measured AER, the median absolute difference was 43% (0.17 h(-1)) and 40% (0.17 h(-1)) for the LBL and LBLX models, respectively. Additionally, a literature-reported empirical scale factor (SF) AER model was evaluated, which showed a median absolute difference of 50% (0.25 h(-1)). The capability of the LBL, LBLX, and SF models could help reduce the AER uncertainty in air pollution exposure models used to develop exposure metrics for health studies.
Finite element modeling of borehole heat exchanger systems. Part 1. Fundamentals
Diersch, H.-J. G.; Bauer, D.; Heidemann, W.; Rühaak, W.; Schätzl, P.
2011-08-01
Single borehole heat exchanger (BHE) and arrays of BHE are modeled by using the finite element method. The first part of the paper derives the fundamental equations for BHE systems and their finite element representations, where the thermal exchange between the borehole components is modeled via thermal transfer relations. For this purpose improved relationships for thermal resistances and capacities of BHE are introduced. Pipe-to-grout thermal transfer possesses multiple grout points for double U-shape and single U-shape BHE to attain a more accurate modeling. The numerical solution of the final 3D problems is performed via a widely non-sequential (essentially non-iterative) coupling strategy for the BHE and porous medium discretization. Four types of vertical BHE are supported: double U-shape (2U) pipe, single U-shape (1U) pipe, coaxial pipe with annular (CXA) and centred (CXC) inlet. Two computational strategies are used: (1) The analytical BHE method based on Eskilson and Claesson's (1988) solution, (2) numerical BHE method based on Al-Khoury et al.'s (2005) solution. The second part of the paper focusses on BHE meshing aspects, the validation of BHE solutions and practical applications for borehole thermal energy store systems.
Modeling near-wall interphase exchanges for particle-laden flows
Desjardins, Olivier; Capecelatro, Jesse; National Renewable Energy Lab Collaboration
2012-11-01
In Eulerian-Lagrangian and Eulerian-Eulerian modeling approaches of dispersed multiphase flows, proper treatment of mass and momentum transfer between the phases is required to capture the correct physical behavior. Coupling often involves the volume fraction and momentum exchange term based on correlations for drag. The accuracy of these terms diminishes at regions close to walls, where key assumptions that were used in the formulation of the models are often violated. Defining particle volume fraction close to a solid boundary could require using detailed information on the distance between the surface of the particles and the wall. No-slip boundary conditions are imposed on the fluid phase while particles may slip, complicating the momentum transfer. In addition, experiments have reported enhanced lift at the walls, corresponding to values greater than what can be estimated from Saffman shear-induced models. In this study, coupling between the phases is handled in an Euler-Lagrange framework using a two-step filtering process that ensures a conservative exchange, as well as convergence under mesh refinement. A turbulent spout fluidized bed is simulated, and compared to experimental data. Different strategies are explored to properly account for the presence of the walls.
MODELING CST ION EXCHANGE FOR CESIUM REMOVAL FROM SCIX BATCHES 1 - 4
Energy Technology Data Exchange (ETDEWEB)
Smith, F.
2011-04-25
The objective of this work is, through modeling, to predict the performance of Crystalline Silicotitinate (CST) for the removal of cesium from Small Column Ion Exchange (SCIX) Batches 1-4 (as proposed in Revision 16 of the Liquid Waste System Plan). The scope of this task is specified in Technical Task Request (TTR) 'SCIX Feed Modeling', HLE-TTR-2011-003, which specified using the Zheng, Anthony, Miller (ZAM) code to predict CST isotherms for six given SCIX feed compositions and the VErsatile Reaction and SEparation simulator for Liquid Chromatography (VERSE-LC) code to predict ion-exchange column behavior. The six SCIX feed compositions provided in the TTR represent SCIX Batches 1-4 and Batches 1 and 2 without caustic addition. The study also investigated the sensitivity in column performance to: (1) Flow rates of 5, 10, and 20 gpm with 10 gpm as the nominal flow; and (2) Temperatures of 25, 35, and 45 C with 35 C as the nominal temperature. The isotherms and column predictions presented in this report reflect the expected performance of engineered CST IE-911. This form of CST was used in experiments conducted at the Savannah River National Laboratory (SRNL) that formed the basis for estimating model parameters (Hamm et al., 2002). As has been done previously, the engineered resin capacity is estimated to be 68% of the capacity of particulate CST without binder.
Modeling Ion-Exchange Processing With Spherical Resins For Cesium Removal
Energy Technology Data Exchange (ETDEWEB)
Hang, T.; Nash, C. A.; Aleman, S. E.
2012-09-19
The spherical Resorcinol-Formaldehyde and hypothetical spherical SuperLig(r) 644 ion-exchange resins are evaluated for cesium removal from radioactive waste solutions. Modeling results show that spherical SuperLig(r) 644 reduces column cycling by 50% for high-potassium solutions. Spherical Resorcinol Formaldehyde performs equally well for the lowest-potassium wastes. Less cycling reduces nitric acid usage during resin elution and sodium addition during resin regeneration, therefore, significantly decreasing life-cycle operational costs. A model assessment of the mechanism behind ''cesium bleed'' is also conducted. When a resin bed is eluted, a relatively small amount of cesium remains within resin particles. Cesium can bleed into otherwise decontaminated product in the next loading cycle. The bleed mechanism is shown to be fully isotherm-controlled vs. mass transfer controlled. Knowledge of residual post-elution cesium level and resin isotherm can be utilized to predict rate of cesium bleed in a mostly non-loaded column. Overall, this work demonstrates the versatility of the ion-exchange modeling to study the effects of resin characteristics on processing cycles, rates, and cold chemical consumption. This evaluation justifies further development of a spherical form of the SL644 resin.
Model-based prediction of monoclonal antibody retention in ion-exchange chromatography.
Guélat, Bertrand; Delegrange, Lydia; Valax, Pascal; Morbidelli, Massimo
2013-07-12
In order to support a model-based process design in ion-exchange chromatography, an adsorption equilibrium model was adapted to predict the protein retention behavior from the amino acid sequence and from structural information on the resin. It is based on the computation of protein-resin interactions with a colloidal model and accounts for the contribution of each ionizable amino acid to the protein charge. As a verification of the protein charge model, the experimental titration curve of a monoclonal antibody was compared to its predicted net charge. Using this protein charge model in the computation of the protein-resin interactions, it is possible to predict the adsorption equilibrium constant (i.e. retention factor or Henry constant) with an explicit pH and salt dependence. The application of the model-based predictions for an in silico screening of the protein retention on various stationary phases or, alternatively, for the comparison of various monoclonal antibodies on a given cation-exchanger was demonstrated. Furthermore, considering the structural differences between charge variants of a monoclonal antibody, it was possible to predict their individual retention times. The selectivity between the side variants and the main isoform of the monoclonal antibody were computed. The comparison with the experimental data showed that the model was reliable with respect to the identification of the operating conditions maximizing the selectivity, i.e. the most promising conditions for a monoclonal antibody variant separation. Such predictions can be useful in reducing the experimental effort to identify the parameter space.
A MODEL OF HETEROGENEOUS DISTRIBUTED SYSTEM FOR FOREIGN EXCHANGE PORTFOLIO ANALYSIS
Directory of Open Access Journals (Sweden)
Dragutin Kermek
2006-06-01
Full Text Available The paper investigates the design of heterogeneous distributed system for foreign exchange portfolio analysis. The proposed model includes few separated and dislocated but connected parts through distributed mechanisms. Making system distributed brings new perspectives to performance busting where software based load balancer gets very important role. Desired system should spread over multiple, heterogeneous platforms in order to fulfil open platform goal. Building such a model incorporates different patterns from GOF design patterns, business patterns, J2EE patterns, integration patterns, enterprise patterns, distributed design patterns to Web services patterns. The authors try to find as much as possible appropriate patterns for planned tasks in order to capture best modelling and programming practices.
Models of Heliospheric solar wind charge exchange X-ray emission
Koutroumpa, Dimitra
2016-04-01
The first models of the solar wind charge exchange (SWCX) X-ray production in the heliosphere were developed shortly after the discovery of SWCX emission at the end of 1990s. Since then, continuous monitoring of the global solar wind evolution through the solar cycle has allowed better constraints on its interaction with the interstellar neutrals. We have a fairly accurate description of the interstellar neutral density distributions in interplanetary space. However, the solar wind heavy ion fluxes, and especially their short term variability and propagation through interplanetary space, have remained relatively elusive due to the sparseness or lack of in situ data, especially towards high ecliptic latitudes. In this talk, I will present a summary the heliospheric SWCX modeling efforts, and an overview of the global solar cycle variability of heliospheric SWCX emission, while commenting on the difficulties of modeling the real-time variability of the heliospheric X-ray signal.
Tri-Lab data models and format (DMF) project: parallel I/O and data exchange
Energy Technology Data Exchange (ETDEWEB)
Cook, L. M.; Matarazzo, C. M.; Rathkopf, J.
1998-10-01
A central goal of the ASCI program is to push simulation and modeling for Science-based Stockpile Stewardship to unprecedented levels. ASCI applications will use extremely high-fidelity models, on the order of one billion cells, to generate terabytes of raw data. Such vast amounts of data produced by these supercomputing applications will overwhelm scientists, whose efforts to understand their results are hindered by inadequate visualization and data management tools. Much of the Scientific Data Management (SDM) effort concerns managing the large and complex data emerging from these simulation codes. One particular area for which commercial and scalable solutions do not exist is in Parallel I/O and data exchange between simulations. To address these needs, the Tri-lab Data Models and Formats effort of the SDM project is developing capabilities to enable the capturing and sharing of simulation data.
Modeling foreign exchange market activity around macroeconomic news: Hawkes-process approach
Rambaldi, Marcello; Pennesi, Paris; Lillo, Fabrizio
2015-01-01
We present a Hawkes-model approach to the foreign exchange market in which the high-frequency price dynamics is affected by a self-exciting mechanism and an exogenous component, generated by the pre-announced arrival of macroeconomic news. By focusing on time windows around the news announcement, we find that the model is able to capture the increase of trading activity after the news, both when the news has a sizable effect on volatility and when this effect is negligible, either because the news in not important or because the announcement is in line with the forecast by analysts. We extend the model by considering noncausal effects, due to the fact that the existence of the news (but not its content) is known by the market before the announcement.
DEFF Research Database (Denmark)
Sørensen, P. B.; Fauser, P.; Carlsen, L.;
It is shown how diffusion and deposition of solids drive the flux of substance between the water column and the sediment. The generic compartment models (Mackay type) use a one box model for the sediment in order to keep the calculations simple. However, when diffusion needs to be included...... in the calculations, the one box model needs to be evaluated in relation to a more complete solution of the differential equations for diffusion. General guidelines that are based on the system parameters are set up in order to establish the importance of diffusion and deposition respectively. These define the range...... where diffusion or deposition is negligible or where both processes must be included in order to describe the sediment-water substance exchange most appropriately....
Directory of Open Access Journals (Sweden)
Pradyot Ranjan Jena
2015-10-01
Full Text Available This paper presents a new adaptive forecasting model using a knowledge guided artificial neural network (KGANN structure for efficient prediction of exchange rate. The new structure has two parallel systems. The first system is a least mean square (LMS trained adaptive linear combiner, whereas the second system employs an adaptive FLANN model to supplement the knowledge base with an objective to improve its performance value. The output of a trained LMS model is added to an adaptive FLANN model to provide a more accurate exchange rate compared to that predicted by either a simple LMS or a FLANN model. This finding has been demonstrated through an exhausting computer simulation study and using real life data. Thus the proposed KGANN is an efficient forecasting model for exchange rate prediction.
Institute of Scientific and Technical Information of China (English)
无
2006-01-01
In this paper, an extended Kendall model for the priority scheduling input-line group output with multi-channel in Asynchronous Transfer Mode (ATM) exchange system is proposed and then the mean method is used to model mathematically the non-typical non-anticipative PRiority service (PR) model. Compared with the typical and non-anticipative PR model, it expresses the characteristics of the priority scheduling input-line group output with multi-channel in ATM exchange system. The simulation experiment shows that this model can improve the HOL block and the performance of input-queued ATM switch network dramatically. This model has a better developing prospect in ATM exchange system.
Gomez-Velez, J. D.; Harvey, J. W.
2014-12-01
Hyporheic exchange has been hypothesized to have basin-scale consequences; however, predictions throughout river networks are limited by available geomorphic and hydrogeologic data as well as models that can analyze and aggregate hyporheic exchange flows across large spatial scales. We developed a parsimonious but physically-based model of hyporheic flow for application in large river basins: Networks with EXchange and Subsurface Storage (NEXSS). At the core of NEXSS is a characterization of the channel geometry, geomorphic features, and related hydraulic drivers based on scaling equations from the literature and readily accessible information such as river discharge, bankfull width, median grain size, sinuosity, channel slope, and regional groundwater gradients. Multi-scale hyporheic flow is computed based on combining simple but powerful analytical and numerical expressions that have been previously published. We applied NEXSS across a broad range of geomorphic diversity in river reaches and synthetic river networks. NEXSS demonstrates that vertical exchange beneath submerged bedforms dominates hyporheic fluxes and turnover rates along the river corridor. Moreover, the hyporheic zone's potential for biogeochemical transformations is comparable across stream orders, but the abundance of lower-order channels results in a considerably higher cumulative effect for low-order streams. Thus, vertical exchange beneath submerged bedforms has more potential for biogeochemical transformations than lateral exchange beneath banks, although lateral exchange through meanders may be important in large rivers. These results have implications for predicting outcomes of river and basin management practices.
Techie Quaicoe, Michael; Twenefour, Frank B K; Baah, Emmanuel M; Nortey, Ezekiel N N
2015-01-01
This research article aimed at modeling the variations in the dollar/cedi exchange rate. It examines the applicability of a range of ARCH/GARCH specifications for modeling volatility of the series. The variants considered include the ARMA, GARCH, IGARCH, EGARCH and M-GARCH specifications. The results show that the series was non stationary which resulted from the presence of a unit root in it. The ARMA (1, 1) was found to be the most suitable model for the conditional mean. From the Box-Ljung test statistics x-squared of 1476.338 with p value 0.00217 for squared returns and 16.918 with 0.0153 p values for squared residuals, the null hypothesis of no ARCH effect was rejected at 5% significance level indicating the presence of an ARCH effect in the series. ARMA (1, 1) + GARCH (1, 1) which has all parameters significant was found to be the most suitable model for the conditional mean with conditional variance, thus showing adequacy in describing the conditional mean with variance of the return series at 5% significant level. A 24 months forecast for the mean actual exchange rates and mean returns from January, 2013 to December, 2014 made also showed that the fitted model is appropriate for the data and a depreciating trend of the cedi against the dollar for forecasted period respectively.
Institute of Scientific and Technical Information of China (English)
ZHOU Xiaopeng; SU Xueli; SUN Yan
2007-01-01
A study of nonlinear competitive adsorption equilibria of proteins is of fundamental importance in understanding the behavior of preparative chromatographic separation.This work describes the nonlinear binary protein adsorption equilibria on ion exchangers by the statistical thermodynamic (ST) model.The single-component and binary protein adsorption isotherms of bovine hemoglobin (Hb) and bovine serum albumin(BSA)on SP Sepharose FF were determined by batch adsorption experiments in 0.05 mol/L sodium acetate buffer at three pH values(4.5,5.0 and 5.5)and three NaCl concentrations(0.05,0.10 and 0.15 mol/L)at pH 5.0.The ST model was found to depict the effects of pH and ionic strength on the single-component equilibria well,with model parameters depending on the pH and ionic strength.Moreover,the ST model gave acceptable fitting to the binary adsorption data with the fltted singlecomponent model parameters,leading to the estimation of the binary ST model parameter.The effects of pH and ionic strength on the model parameters are reasonably interpreted by the electrostatic and thermodynamic theories.Results demonstrate the availability of the ST model for describing nonlinear competitive protein adsorption equilibria in the presence of two proteins.
D.E. Allen (David); M.J. McAleer (Michael); S. Peiris (Shelton); A.K. Singh (Abhay)
2015-01-01
textabstractThis paper features an analysis of major currency exchange rate movements in relation to the US dollar, as constituted in US dollar terms. Euro, British pound, Chinese yuan, and Japanese yen are modelled using a variety of non- linear models, including smooth transition regression models
Two-phase plate-fin heat exchanger modeling for waste heat recovery systems in diesel engines
Feru, E.; de Jager, B.; Willems, F.; Steinbuch, M.
2014-01-01
This paper presents the modeling and model validation for a modular two-phase heat exchanger that recovers energy in heavy-duty diesel engines. The model is developed for temperature and vapor quality prediction and for control design of the waste heat recovery system. In the studied waste heat reco
Abu-Labdeh, A M; MacIsaac, A B; De'Bell, K
2011-07-27
The effects of a uniform magnetic field on the phase diagram of the dipolar Heisenberg model with a dominant antiferromagnetic exchange interaction have been investigated. The model consists of a square lattice of classical spin vectors, where the spins interact through an antiferromagnetic exchange interaction of strength J and a dipole-dipole interaction of strength g. The spins couple to a magnetic surface anisotropy of strength κ and to an applied external magnetic field of strength H. The external field is applied perpendicular to the plane of the lattice. From extensive Monte Carlo simulations, representative magnetic phase diagrams have been determined as a function of the ratios κ/g and T/g, where T is temperature, and at three different ratios of H/g (H/g = 10, 20, 27). These results are compared to the previously investigated case of H/g = 0 and to analytic calculations for the ground state energies. The nature of the equilibrium phases and order of the phase boundaries separating them are considered and changes due to the strength of the applied field are highlighted.
ION EXCHANGE MODELING FOR REMOVAL OF CESIUM FROM HANFORD WASTE USING SUPERLIG 644 RESIN
Energy Technology Data Exchange (ETDEWEB)
Hamm, L
2004-05-01
The expected performance of a proposed ion exchange column using SuperLig{reg_sign} 644 resin for the removal of cesium from Hanford high level radioactive alkaline waste is discussed. This report represents a final report on the ability and knowledge with regard to modeling the Cesium-SuperLig{reg_sign} 644 resin ion exchange system. Only the loading phase of the cycle process is addressed within this report. Pertinent bench-scale column tests and batch equilibrium experiments are addressed. The methodology employed and sensitivity analyses are also included (i.e., existing methodology employed is referenced to prior developmental efforts while updated methodology is discussed). Pilot-scale testing is not assessed since no pilot-scale testing was available at the time of this report. Column performance predictions are made considering three selected feed compositions under nominal operating conditions. The sensitivity analyses provided help to identify key parameters that aid in resin procurement acceptance criteria. The methodology and application presented within this report reflect the expected behavior of SuperLig{reg_sign} 644 resin manufactured at the production-scale (i.e, 250 gallon batch size level). The primary objective of this work was, through modeling and verification based on experimental assessments, to predict the cesium removal performance of SuperLig{reg_sign} 644 resin for application in the RPP pretreatment facility.
Energy Technology Data Exchange (ETDEWEB)
Aleman, S. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Hamm, L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Smith, F. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
2007-06-27
This report discusses the expected performance of spherical Resorcinol-Formaldehyde (RF) ion exchange resin for the removal of cesium from alkaline Hanford radioactive waste. Predictions of full scale column performance in a carousel mode are made for the Hot Commissioning, Envelope B, and Subsequent Operations waste compositions under nominal operating conditions and for perturbations from the nominal. Only the loading phase of the process cycle is addressed in this report. Pertinent bench-scale column tests, kinetic experiments, and batch equilibrium experiments are used to estimate model parameters and to benchmark the ion-exchange model. The methodology and application presented in this report reflect the expected behavior of spherical RF resin manufactured at the intermediate-scale (i.e., approximately 100 gallon batch size; batch 5E-370/641). It is generally believed that scale-up to production-scale in resin manufacturing will result in similarly behaving resin batches whose chemical selectivity is unaffected while total capacity per gram of resin may vary some. As such, the full-scale facility predictions provided within this report should provide reasonable estimates of production-scale column performance.
Prerequisites for modeling price and return data series for the Bucharest Stock Exchange
Directory of Open Access Journals (Sweden)
Andrei TINCA
2013-11-01
Full Text Available Time series data from the capital market exhibits certain qualities which invalidate the hypotheses necessary for obtaining meaningful results from statistical modeling. This paper presents some of these qualities by looking at the time series for prices and returns on the Romanian Stock Exchange. The examples are based on the price time series and return time series of the Antibiotice securities and the BET-C index. The choice of a certain security and of the stock exchange index has been made with the intention of analyzing, in the future, the correlation between these two variables, and drawing significant conclusions which can be used for forecasts.Firstly, we will identify the empirical proprieties of the capital market, as they are described in the field research. Secondly, we will investigate the prerequisites for modeling chronological data series; these are stationary mean and variance. In the paper, the three methods are used: graphical representation, autocorrelation and the ADF test (Augmented Dickey-Fuller. For the frequent cases where the mean is not stationary, we will present the time series differentiation method, which can be used to obtain stationary values.Lastly, we will investigate the normality of the time series through the skewness and kurtosis methods, and through the Jarque-Bera statistic. We find out a characteristic for the capital market, in that the majority of the time series for securities have non-normal distributions.
A model of the CO2 exchanges between biosphere and atmosphere in the tundra
Labgaa, Rachid R.; Gautier, Catherine
1992-01-01
A physical model of the soil thermal regime in a permafrost terrain has been developed and validated with soil temperature measurements at Barrow, Alaska. The model calculates daily soil temperatures as a function of depth and average moisture contents of the organic and mineral layers using a set of five climatic variables, i.e., air temperature, precipitation, cloudiness, wind speed, and relative humidity. The model is not only designed to study the impact of climate change on the soil temperature and moisture regime, but also to provide the input to a decomposition and net primary production model. In this context, it is well known that CO2 exchanges between the terrestrial biosphere and the atmosphere are driven by soil temperature through decomposition of soil organic matter and root respiration. However, in tundra ecosystems, net CO2 exchange is extremely sensitive to soil moisture content; therefore it is necessary to predict variations in soil moisture in order to assess the impact of climate change on carbon fluxes. To this end, the present model includes the representation of the soil moisture response to changes in climatic conditions. The results presented in the foregoing demonstrate that large errors in soil temperature and permafrost depth estimates arise from neglecting the dependence of the soil thermal regime on soil moisture contents. Permafrost terrain is an example of a situation where soil moisture and temperature are particularly interrelated: drainage conditions improve when the depth of the permafrost increases; a decrease in soil moisture content leads to a decrease in the latent heat required for the phase transition so that the heat penetrates faster and deeper, and the maximum depth of thaw increases; and as excepted, soil thermal coefficients increase with moisture.
Process Model for Studying Regional 13C Stable Isotope Exchange between Vegetation and Atmosphere
Chen, J. M.; Chen, B.; Huang, L.; Tans, P.; Worthy, D.; Ishizawa, M.; Chan, D.
2007-12-01
The variation of the stable isotope 13CO2 in the air in exchange with land ecosystems results from fractionation processes in both plants and soil during photosynthesis and respiration. Its diurnal and seasonal variations therefore contain information on the carbon cycle. We developed a model (BEPS-iso) to simulate its exchange between vegetation and the atmosphere. To be useful for regional carbon cycle studies, the model has the following characteristics: (i) it considers the turbulent mixing in the vertical profile from the soil surface to the top of the planetary boundary layer (PBL); (ii) it scales individual leaf photosynthetic discrimination to the whole canopy through the separation of sunlit and shaded leaf groups; (iii) through simulating leaf-level photosynthetic processes, it has the capacity to mechanistically examine isotope discrimination resulting from meteorological forcings, such as radiation, precipitation and humidity; and (iv) through complete modeling of radiation, energy and water fluxes, it also simulates soil moisture and temperature needed for estimating ecosystem respiration and the 13C signal from the soil. After validation using flask data acquired at 20 m level on a tower near Fraserdale, Ontario, Canada, during intensive campaigns (1998-2000), the model has been used for several purposes: (i) to investigate the diurnal and seasonal variations in the disequilibrium in 13C fractionation between ecosystem respiration and photosynthesis, which is an important step in using 13C measurements to separate these carbon cycle components; (ii) to quantify the 13C rectification in the PBL, which differs significantly from CO2 rectification because of the diurnal and seasonal disequilibriums; and (iii) to model the 13C spatial and temporal variations over the global land surface for the purpose of CO2 inversion using 13C as an additional constraint.
THREE-DIMENSIONAL THERMAL MODELING ANALYSIS OF CST MEDIA FOR THE SMALL ION EXCHANGE PROJECT
Energy Technology Data Exchange (ETDEWEB)
Lee, S.; King, W.
2011-09-12
The Small Column Ion Exchange (SCIX) project is designed to accelerate closure of High Level Waste (HLW) tanks at the Savannah River Site (SRS). The SRS tanks store HLW in three forms: sludge, saltcake, and supernate. An in-tank ion exchange process is being designed to treat supernate and dissolved saltcake waste. Through this process, radioactive cesium from the salt solution is adsorbed into Crystalline Silicotitanate (CST) ion exchange media packed within a flow-through column. A packed column loaded with radioactive cesium generates significant heat from radiolytic decay. The waste supernate solution within the ion exchange bed will boil around 120 C. Solution superheating above the boiling point within the column could lead to violent hazardous energy releases. System heating from loaded CST is also of concern in other process modules, such as the waste tank. Due to tank structural integrity concerns, the wall temperature limit for the SRS waste tanks is 100 C. The transfer of cesium-loaded CST to the tank could result in localized hot spots on the tank floor and walls which may exceed this limit. As a result, thermal modeling calculations have been conducted to predict the maximum temperatures achievable both in the column and in the waste tank. As specified in the associated Technical Task Plan, one objective of the present work was to compute temperature distributions within the ion exchange column module under accident scenarios including loss of salt solution flow through the bed and loss of coolant system flow. The column modeling domain and the scope of the calculations in this case were broadened relative to previous two-dimensional calculations to include vertical temperature distributions within the packed bed of ion exchange media as well as the upper column plenum region containing only fluid. The baseline design conditions and in-column modeling domain for the ion-exchange column module are shown in Figure 1. These evaluations assumed the maximum
Directory of Open Access Journals (Sweden)
David E. Allen
2016-03-01
Full Text Available This paper features an analysis of major currency exchange rate movements in relation to the US dollar, as constituted in US dollar terms. Euro, British pound, Chinese yuan, and Japanese yen are modelled using a variety of non-linear models, including smooth transition regression models, logistic smooth transition regressions models, threshold autoregressive models, nonlinear autoregressive models, and additive nonlinear autoregressive models, plus Neural Network models. The models are evaluated on the basis of error metrics for twenty day out-of-sample forecasts using the mean average percentage errors (MAPE. The results suggest that there is no dominating class of time series models, and the different currency pairs relationships with the US dollar are captured best by neural net regression models, over the ten year sample of daily exchange rate returns data, from August 2005 to August 2015.
Modeling approaches to describe H2O and CO2 exchange in mare ecosystems
Olchev, A.; Novenko, E.; Volkova, E.
2012-04-01
The modern climatic conditions is strongly influenced by both internal variability of climatic system, and various external natural and anthropogenic factors (IPCC 2007). Significant increase of concentration of greenhouse gases in the atmosphere and especially the growth of atmospheric CO2 due to human activity are considered as the main factors that are responsible for global warming and climate changes. A significant part of anthropogenic CO2 is absorbed from the atmosphere by land biota and especially by vegetation cover. However, it is still not completely clear what is the role of different land ecosystems and especially forests and mares in global cycles of H2O and CO2 and what is a sensitivity of these ecosystems to climate changes. Within the frameworks of this study the spatial and temporal variability of H2O and CO2 fluxes in different types of mare ecosystems of the forest-steppe zone in European part of Russia was described using modeling approaches and results of field measurements. For this modeling and experimental study the mare ecosystems of Tula region were selected. The Tula region is located mostly in the forest-steppe zone and it is unique area for such studies because almost all existed types of mare ecosystems of Northern Eurasia distinguished by a geomorphological position, water and mineral supply can be found there. Most mares in Tula region have a relatively small size and surrounded by very heterogeneous forests that make not possible an application of the classical measuring and modeling approaches e.g. an eddy covariance technique or one-dimensional H2O and CO2 exchange models for flux estimation in such sites. In our study to describe the radiation, sensible heat, H2O and CO2 exchange between such heterogeneous mare ecosystems and the atmosphere a three-dimensional model Forbog-3D and one-dimensional Mixfor-SVAT were applied. The main concept used in the Forbog-3D and Mixfor-SVAT models is an aggregated description of physical and
I, Sahadudheen I
2013-01-01
This paper examines the effect of volatility in both rupee-dollar and rupee-euro exchange rates on stock prices in India using daily data from 3-Apr-2007 to 30-Mar-2012. Adopting a generalized autoregressive conditional heteroskedasticity (GARCH) and exponential GARCH (EGARCH) model, the study suggests a negative relationship between exchange rate and stock prices in India. Even though India is a major trade partner of European Union, the study couldn’t find any significant statistical effect...
Development of a Model for Water and Heat Exchange Between the Atmosphere and a Water Body
Institute of Scientific and Technical Information of China (English)
SUN Shufen; YAN Jinfeng; XIA Nan; SUN Changhai
2007-01-01
A model for studying the heat and mass exchange between the atmosphere and a water body is developed,in which the phase change process of water freezing in winter and melting in summer and the function of the convective mixing process are taken into consideration. The model uses enthalpy rather than temperature as the predictive variable. It helps to set up governing equations more concisely, to deal with the phase change process more easily, and make the numerical scheme simpler. The model is verified by observed data from Lake Kinneret for a non-frozen lake in summer time, and Lake Lower Two Medicine for a frozen lake in winter time. Reasonably good agreements between the model simulations and observed data indicate that the model can serve as a component for a water body in a land surface model. In order to more efficiently apply the scheme in a climate system model, a sensitivity study of various division schemes with less layers in the vertical direction in the water body is conducted. The results of the study show that the division with around 10 vertical layers could produce a prediction accuracy that is comparable to the fine division with around 40 layers.
Modeling cation exchange capacity and soil water holding capacity from basic soil properties
Directory of Open Access Journals (Sweden)
Idowu Olorunfemi
2016-10-01
Full Text Available Cation exchange capacity (CEC is a good indicator of soil productivity and is useful for making recommendations of phosphorus, potassium, and magnesium for soils of different textures. Soil water holding capacity (SWHC defines the ability of a soil to hold water at a particular time of the season. This research predicted CEC and SWHC of soils using pedotransfer models developed (using Minitab 17 statistical software from basic soil properties (Sand(S, Clay(C, soil pH, soil organic carbon (SOC and verify the model by comparing the relationship between measured and estimated (obtained by PTFs CEC and SWHC in the Forest Vegetative Zone of Nigeria. For this study, a total of 105 sampling points in 35 different locations were sampled in the study areas. Three sampling points were randomly selected per location and three undisturbed samples were collected at each sampling point. The results showed success in predicting CEC and SWHC from basic soil properties. In this study, five linear regression models for predicting soil CEC and seven linear regression models for predicting SWHC from some soil physical and chemical properties were suggested. Model 5 [CEC = -13.93+2.645 pH +0.0446 C (%+2.267 SOC (%] was best for predicting CEC while model 12 [SWHC (%=36.0- 0.215 S (%+0.113 C (%+10.36 SOC (%] is the most acceptable model for predicting SWHC.
Modeling of salt and pH gradient elution in ion-exchange chromatography.
Schmidt, Michael; Hafner, Mathias; Frech, Christian
2014-01-01
The separation of proteins by internally and externally generated pH gradients in chromatofocusing on ion-exchange columns is a well-established analytical method with a large number of applications. In this work, a stoichiometric displacement model was used to describe the retention behavior of lysozyme on SP Sepharose FF and a monoclonal antibody on Fractogel SO3 (S) in linear salt and pH gradient elution. The pH dependence of the binding charge B in the linear gradient elution model is introduced using a protein net charge model, while the pH dependence of the equilibrium constant is based on a thermodynamic approach. The model parameter and pH dependences are calculated from linear salt gradient elutions at different pH values as well as from linear pH gradient elutions at different fixed salt concentrations. The application of the model for the well-characterized protein lysozyme resulted in almost identical model parameters based on either linear salt or pH gradient elution data. For the antibody, only the approach based on linear pH gradients is feasible because of the limited pH range useful for salt gradient elution. The application of the model for the separation of an acid variant of the antibody from the major monomeric form is discussed.
Combining Coarse-Grained Protein Models with Replica-Exchange All-Atom Molecular Dynamics
Wabik, Jacek; Gront, Dominik; Kouza, Maksim; Kolinski, Andrzej
2013-01-01
We describe a combination of all-atom simulations with CABS, a well-established coarse-grained protein modeling tool, into a single multiscale protocol. The simulation method has been tested on the C-terminal beta hairpin of protein G, a model system of protein folding. After reconstructing atomistic details, conformations derived from the CABS simulation were subjected to replica-exchange molecular dynamics simulations with OPLS-AA and AMBER99sb force fields in explicit solvent. Such a combination accelerates system convergence several times in comparison with all-atom simulations starting from the extended chain conformation, demonstrated by the analysis of melting curves, the number of native-like conformations as a function of time and secondary structure propagation. The results strongly suggest that the proposed multiscale method could be an efficient and accurate tool for high-resolution studies of protein folding dynamics in larger systems.
Combining Coarse-Grained Protein Models with Replica-Exchange All-Atom Molecular Dynamics
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Andrzej Koliński
2013-05-01
Full Text Available We describe a combination of all-atom simulations with CABS, a well-established coarse-grained protein modeling tool, into a single multiscale protocol. The simulation method has been tested on the C-terminal beta hairpin of protein G, a model system of protein folding. After reconstructing atomistic details, conformations derived from the CABS simulation were subjected to replica-exchange molecular dynamics simulations with OPLS-AA and AMBER99sb force fields in explicit solvent. Such a combination accelerates system convergence several times in comparison with all-atom simulations starting from the extended chain conformation, demonstrated by the analysis of melting curves, the number of native-like conformations as a function of time and secondary structure propagation. The results strongly suggest that the proposed multiscale method could be an efficient and accurate tool for high-resolution studies of protein folding dynamics in larger systems.
Combining coarse-grained protein models with replica-exchange all-atom molecular dynamics.
Wabik, Jacek; Kmiecik, Sebastian; Gront, Dominik; Kouza, Maksim; Koliński, Andrzej
2013-05-10
We describe a combination of all-atom simulations with CABS, a well-established coarse-grained protein modeling tool, into a single multiscale protocol. The simulation method has been tested on the C-terminal beta hairpin of protein G, a model system of protein folding. After reconstructing atomistic details, conformations derived from the CABS simulation were subjected to replica-exchange molecular dynamics simulations with OPLS-AA and AMBER99sb force fields in explicit solvent. Such a combination accelerates system convergence several times in comparison with all-atom simulations starting from the extended chain conformation, demonstrated by the analysis of melting curves, the number of native-like conformations as a function of time and secondary structure propagation. The results strongly suggest that the proposed multiscale method could be an efficient and accurate tool for high-resolution studies of protein folding dynamics in larger systems.
Bednarek, Tomasz; Tsotridis, Georgios
2017-03-01
The objective of the current study is to highlight possible limitations and difficulties associated with Computational Fluid Dynamics in PEM single fuel cell modelling. It is shown that an appropriate convergence methodology should be applied for steady-state solutions, due to inherent numerical instabilities. A single channel fuel cell model has been taken as numerical example. Results are evaluated for quantitative as well qualitative points of view. The contribution to the polarization curve of the different fuel cell components such as bi-polar plates, gas diffusion layers, catalyst layers and membrane was investigated via their effects on the overpotentials. Furthermore, the potential losses corresponding to reaction kinetics, due to ohmic and mas transport limitations and the effect of the exchange current density and open circuit voltage, were also investigated. It is highlighted that the lack of reliable and robust input data is one of the issues for obtaining accurate results.
Test Of Capital Asset Pricing Model On Stocks At Karachi Stock Exchange
Directory of Open Access Journals (Sweden)
Arbab Khalid Cheema
2010-12-01
Full Text Available This paper attempts to empirically test the single-factor CAPM developed by Sharpe (1964, Lintner (1965 and Jan Mossin (1966 and others, which proposes that the expected returns of capital assets are dependent on their risk relative to the entire market which is quantified by a correlation co-efficient between asset returns and market returns. The test of 20 stocks at Karachi Stock Exchange have shown that though, the beta co-efficients are significant, their strength is considerably weak. Therefore, other factors which are unaccounted for in this model are important in determining risk and return. In addition, betas are less relevant in a volatile emerging capital markets like the KSE. Thus, the multi-factor models are better than the classical CAPM at determining the risk-return relationship. However, the single-factor CAPM remains in practice beacause of its simplicity.
Institute of Scientific and Technical Information of China (English)
LI Xi; DENG Zhong-hua; CAO Guang-yi; ZHU Xin-jian; WEI Dong
2006-01-01
Proton exchange membrane fuel cell (PEMFC) stack temperature and cathode stoichiometric oxygen are very important control parameters. The performance and lifespan of PEMFC stack are greatly dependent on the parameters. So, in order to improve the performance index, tight control of two parameters within a given range and reducing their fluctuation are indispensable.However, control-oriented models and control strategies are very weak junctures in the PEMFC development. A predictive control algorithm was presented based on their model established by input-output data and operating experiences. It adjusts the operating temperature to 80 ℃. At the same time, the optimized region of stoichiometric oxygen is kept between 1.8-2.2. Furthermore, the control algorithm adjusts the variants quickly to the destination value and makes the fluctuation of the variants the least. According to the test results, compared with traditional fuzzy and PID controllers, the designed controller shows much better performance.
Modelling Net Ecosystem Exchange and LUE in Mediterranean Oak Forest by Satellite Remote Sensing
Tramontana, Gianluca; Papale, Dario
2011-01-01
Net Ecosystem Exchange (NEE) is a key factor defining CO2 fluxes between atmosphere and ecosystems and CO2 flux measurements at individual eddy covariance flux sites provide valuable information on the seasonal dynamics of NEE. In this work, we developed and validated a satellite-based Light Use Efficiency (LUE) model to estimate NEE for a typical oak forest located in Central Italy. Satellite data were acquired by Moderate resolution spectroradiometer (MODIS) sensor installed on board Terra satellite. Oak forest studied is coppice managed; 2 eddy-covariance towers are located inside two forests parcels having different ages. We proposed to estimate LUE like function of mean brightness temperature, Normalized Difference Water Index (NDWI) and Photochemical Reflectance Index (PRI). Empirical multiple regressions models (MR) and Artificial Neural Network (ANN) were parameterized and validated using subset of data acquired by both the stations. Daily, 8-day and monthly temporal resolutions were investigated and accuracy estimation in space and time was performed.
Replica-exchange Wang-Landau simulations of the H0P lattice protein model
Shi, Guangjie; Wüst, Thomas; Li, Ying Wai; Landau, David P.
The hydrophobic-polar (HP) lattice protein model has been the subject of intensive investigation in an effort to aid our understanding of protein folding. However, the high ground state degeneracies caused by its simplification stands in contrast to the generally unique native states of natural proteins. Here we proposed a simple modification, by introducing a new type of ``neutral'' monomer, 0, i.e. neither hydrophobic nor polar, thus rendering the model more realistic without increasing the difficulties of sampling significantly. With the replica exchange Wang-Landau (REWL) scheme we investigated several widely studied HP proteins and their H0P counterparts. Dramatic differences in both ground state and thermodynamic properties have been found. For example, the H0P version of Crambin shows more clear two-step folding and 3 order of magnitudes less ground state degeneracy than its HP counterpart. Supported by NSF.
A review on the performance and modelling of proton exchange membrane fuel cells
Energy Technology Data Exchange (ETDEWEB)
Boucetta, A., E-mail: abirboucetta@yahoo.fr; Ghodbane, H., E-mail: h.ghodbane@mselab.org; Bahri, M., E-mail: m.bahri@mselab.org [Department of Electrical Engineering, MSE Laboratory, Mohamed khider Biskra University (Algeria); Ayad, M. Y., E-mail: ayadmy@gmail.com [R& D, Industrial Hybrid Vehicle Applications (France)
2016-07-25
Proton Exchange Membrane Fuel Cells (PEMFC), are energy efficient and environmentally friendly alternative to conventional energy conversion for various applications in stationary power plants, portable power device and transportation. PEM fuel cells provide low operating temperature and high-energy efficiency with near zero emission. A PEM fuel cell is a multiple distinct parts device and a series of mass, energy, transport through gas channels, electric current transport through membrane electrode assembly and electrochemical reactions at the triple-phase boundaries. These processes play a decisive role in determining the performance of the Fuel cell, so that studies on the phenomena of gas flows and the performance modelling are made deeply. This paper gives a comprehensive overview of the state of the art on the Study of the phenomena of gas flow and performance modelling of PEMFC.
Irreversible transitions in the exchange-striction model of spin-glass state
Valkov, V. I.; Golovchan, A. V.
2014-08-01
Based on the assumption of a negative volume dependence of random exchange integrals, it is possible to switch to a compressible Sherrington-Kirkpatrick spin-glass model. Within the proposed model, temperature-pressure phase diagrams were calculated and pressure- and magnetic-field-induced first-order phase transitions from the initial paramagnetic and spin-glass states to the ferromagnetic state were predicted. It was shown that the application of pressure in the spin-glass state not only increases and shifts magnetic susceptibility, but also reduces the critical magnetic fields of irreversible induced phase transitions from the spin-glass to the ferromagnetic state. The obtained results are used to describe the spin-glass state in (Sm1-xGdx)0.55Sr0.45MnO3.
A review on the performance and modelling of proton exchange membrane fuel cells
Boucetta, A.; Ghodbane, H.; Ayad, M. Y.; Bahri, M.
2016-07-01
Proton Exchange Membrane Fuel Cells (PEMFC), are energy efficient and environmentally friendly alternative to conventional energy conversion for various applications in stationary power plants, portable power device and transportation. PEM fuel cells provide low operating temperature and high-energy efficiency with near zero emission. A PEM fuel cell is a multiple distinct parts device and a series of mass, energy, transport through gas channels, electric current transport through membrane electrode assembly and electrochemical reactions at the triple-phase boundaries. These processes play a decisive role in determining the performance of the Fuel cell, so that studies on the phenomena of gas flows and the performance modelling are made deeply. This paper gives a comprehensive overview of the state of the art on the Study of the phenomena of gas flow and performance modelling of PEMFC.
Heat Transfer Modeling of Phase Change Materials in Multiple Plates Heat Exchanger
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M. Alipanah
2013-12-01
Full Text Available Nowadays, given the increasing importance of energy sources, the possibility of energy storage in the heat exchangers through the Phase Change Materials (PCM and releasing it when needed have been extremely essential. This study seeks to model the domestic water heat system in which the paraffin is as the phase change material and it stores the solar energy. The behavior of a PCM plate was studied by writing the governing equations and solving them as the one-dimensional, implicit method and through numerical calculation of the method equations. Given the confirmed accuracy of performed modeling by the results of similar studies for the complete melting and solidification of PCM, the application of this system seems appropriate for the solar domestic water heaters.
Adaptive multi-GPU Exchange Monte Carlo for the 3D Random Field Ising Model
Navarro, Cristóbal A.; Huang, Wei; Deng, Youjin
2016-08-01
This work presents an adaptive multi-GPU Exchange Monte Carlo approach for the simulation of the 3D Random Field Ising Model (RFIM). The design is based on a two-level parallelization. The first level, spin-level parallelism, maps the parallel computation as optimal 3D thread-blocks that simulate blocks of spins in shared memory with minimal halo surface, assuming a constant block volume. The second level, replica-level parallelism, uses multi-GPU computation to handle the simulation of an ensemble of replicas. CUDA's concurrent kernel execution feature is used in order to fill the occupancy of each GPU with many replicas, providing a performance boost that is more notorious at the smallest values of L. In addition to the two-level parallel design, the work proposes an adaptive multi-GPU approach that dynamically builds a proper temperature set free of exchange bottlenecks. The strategy is based on mid-point insertions at the temperature gaps where the exchange rate is most compromised. The extra work generated by the insertions is balanced across the GPUs independently of where the mid-point insertions were performed. Performance results show that spin-level performance is approximately two orders of magnitude faster than a single-core CPU version and one order of magnitude faster than a parallel multi-core CPU version running on 16-cores. Multi-GPU performance is highly convenient under a weak scaling setting, reaching up to 99 % efficiency as long as the number of GPUs and L increase together. The combination of the adaptive approach with the parallel multi-GPU design has extended our possibilities of simulation to sizes of L = 32 , 64 for a workstation with two GPUs. Sizes beyond L = 64 can eventually be studied using larger multi-GPU systems.
Assessment of model estimates of land-atmosphere CO2 exchange across Northern Eurasia
Rawlins, M. A.; McGuire, A. D.; Kimball, J. S.; Dass, P.; Lawrence, D.; Burke, E.; Chen, X.; Delire, C.; Koven, C.; MacDougall, A.; Peng, S.; Rinke, A.; Saito, K.; Zhang, W.; Alkama, R.; Bohn, T. J.; Ciais, P.; Decharme, B.; Gouttevin, I.; Hajima, T.; Ji, D.; Krinner, G.; Lettenmaier, D. P.; Miller, P.; Moore, J. C.; Smith, B.; Sueyoshi, T.
2015-07-01
A warming climate is altering land-atmosphere exchanges of carbon, with a potential for increased vegetation productivity as well as the mobilization of permafrost soil carbon stores. Here we investigate land-atmosphere carbon dioxide (CO2) cycling through analysis of net ecosystem productivity (NEP) and its component fluxes of gross primary productivity (GPP) and ecosystem respiration (ER) and soil carbon residence time, simulated by a set of land surface models (LSMs) over a region spanning the drainage basin of Northern Eurasia. The retrospective simulations cover the period 1960-2009 at 0.5° resolution, which is a scale common among many global carbon and climate model simulations. Model performance benchmarks were drawn from comparisons against both observed CO2 fluxes derived from site-based eddy covariance measurements as well as regional-scale GPP estimates based on satellite remote-sensing data. The site-based comparisons depict a tendency for overestimates in GPP and ER for several of the models, particularly at the two sites to the south. For several models the spatial pattern in GPP explains less than half the variance in the MODIS MOD17 GPP product. Across the models NEP increases by as little as 0.01 to as much as 0.79 g C m-2 yr-2, equivalent to 3 to 340 % of the respective model means, over the analysis period. For the multimodel average the increase is 135 % of the mean from the first to last 10 years of record (1960-1969 vs. 2000-2009), with a weakening CO2 sink over the latter decades. Vegetation net primary productivity increased by 8 to 30 % from the first to last 10 years, contributing to soil carbon storage gains. The range in regional mean NEP among the group is twice the multimodel mean, indicative of the uncertainty in CO2 sink strength. The models simulate that inputs to the soil carbon pool exceeded losses, resulting in a net soil carbon gain amid a decrease in residence time. Our analysis points to improvements in model elements
Assessment of model estimates of land-atmosphere CO2 exchange across northern Eurasia
Rawlins, M.A.; McGuire, A.D.; Kimball, J.S.; Dass, P.; Lawrence, D.; Burke, E.; Chen, X.; Delire, C.; Koven, C.; MacDougall, A.; Peng, S.; Rinke, A.; Saito, K.; Zhang, W.; Alkama, R.; Bohn, T. J.; Ciais, P.; Decharme, B.; Gouttevin, I.; Hajima, T.; Ji, D.; Krinner, G.; Lettenmaier, D.P.; Miller, P.; Moore, J.C.; Smith, B.; Sueyoshi, T.
2015-01-01
A warming climate is altering land-atmosphere exchanges of carbon, with a potential for increased vegetation productivity as well as the mobilization of permafrost soil carbon stores. Here we investigate land-atmosphere carbon dioxide (CO2) cycling through analysis of net ecosystem productivity (NEP) and its component fluxes of gross primary productivity (GPP) and ecosystem respiration (ER) and soil carbon residence time, simulated by a set of land surface models (LSMs) over a region spanning the drainage basin of Northern Eurasia. The retrospective simulations cover the period 1960–2009 at 0.5° resolution, which is a scale common among many global carbon and climate model simulations. Model performance benchmarks were drawn from comparisons against both observed CO2 fluxes derived from site-based eddy covariance measurements as well as regional-scale GPP estimates based on satellite remote-sensing data. The site-based comparisons depict a tendency for overestimates in GPP and ER for several of the models, particularly at the two sites to the south. For several models the spatial pattern in GPP explains less than half the variance in the MODIS MOD17 GPP product. Across the models NEP increases by as little as 0.01 to as much as 0.79 g C m−2 yr−2, equivalent to 3 to 340 % of the respective model means, over the analysis period. For the multimodel average the increase is 135 % of the mean from the first to last 10 years of record (1960–1969 vs. 2000–2009), with a weakening CO2 sink over the latter decades. Vegetation net primary productivity increased by 8 to 30 % from the first to last 10 years, contributing to soil carbon storage gains. The range in regional mean NEP among the group is twice the multimodel mean, indicative of the uncertainty in CO2 sink strength. The models simulate that inputs to the soil carbon pool exceeded losses, resulting in a net soil carbon gain amid a decrease in residence time. Our analysis points to improvements in model
Directory of Open Access Journals (Sweden)
J. E. Pleim
2012-08-01
Full Text Available Atmospheric ammonia (NH3 is the primary atmospheric base and an important precursor for inorganic particulate matter and when deposited NH3 contributes to surface water eutrophication, soil acidification and decline in species biodiversity. Flux measurements indicate that the air-surface exchange of NH3 is bi-directional. However, the effects of bi-directional exchange, soil biogeochemistry and human activity are not parameterized in air quality models. The US Environmental Protection Agency (EPA's Community Multiscale Air-Quality (CMAQ model with bi-directional NH3 exchange has been coupled with the United States Department of Agriculture (USDA's Environmental Policy Integrated Climate (EPIC agro-ecosystem model's nitrogen geochemistry algorithms. CMAQ with bi-directional NH3 exchange coupled to EPIC connects agricultural cropping management practices to emissions and atmospheric concentrations of reduced nitrogen and models the biogeochemical feedback on NH3 air-surface exchange. This coupled modeling system reduced the biases and error in NHx (NH3 + NH4+ wet deposition and in ambient aerosol concentrations in an annual 2002 Continental US (CONUS domain simulation when compared to a 2002 annual simulation of CMAQ without bi-directional exchange. Fertilizer emissions estimated in CMAQ 5.0 with bi-directional exchange exhibits markedly different seasonal dynamics than the US EPA's National Emissions Inventory (NEI, with lower emissions in the spring and fall and higher emissions in July.
Monitoring and modelling of biosphere/atmosphere exchange of gases and aerosols in Europe
Energy Technology Data Exchange (ETDEWEB)
Erisman, Jan Willem [Energy Research Centre of the Netherlands (ECN), P.O. Box 1, 1755 ZG Petten (Netherlands)]. E-mail: erisman@ecn.nl; Vermeulen, Alex [Energy Research Centre of the Netherlands (ECN), P.O. Box 1, 1755 ZG Petten (Netherlands); Hensen, Arjan [Energy Research Centre of the Netherlands (ECN), P.O. Box 1, 1755 ZG Petten (Netherlands); Flechard, Chris [Energy Research Centre of the Netherlands (ECN), P.O. Box 1, 1755 ZG Petten (Netherlands); Daemmgen, Ulrich [Federal Agricultural Research Centre, Institute of Agroecology, D-38116 Braunschweig, (Germany); Fowler, David [CEH, Bush Estate, Penicuik, Midlothian EH26 0QB (United Kingdom); Sutton, Mark [CEH, Bush Estate, Penicuik, Midlothian EH26 0QB (United Kingdom); Gruenhage, Ludger [Institute for Plant Ecology, Justus-Liebig-University, D-35392 Giessen (Germany); Tuovinen, Juha-Pekka [Finnish Meteorological Institute, FIN-00810 Helsinki (Finland)
2005-02-01
Monitoring and modelling of deposition of air pollutants is essential to develop and evaluate policies to abate the effects related to air pollution and to determine the losses of pollutants from the atmosphere. Techniques for monitoring wet deposition fluxes are widely applied. A recent intercomparison experiment, however, showed that the uncertainty in wet deposition is relatively high, up to 40%, apart from the fact that most samplers are biased because of a dry deposition contribution. Wet deposition amounts to about 80% of the total deposition in Europe with a range of 10-90% and uncertainty should therefore be decreased. During recent years the monitoring of dry deposition has become possible. Three sites have been operational for 5 years. The data are useful for model development, but also for model evaluation and monitoring of progress in policy. Data show a decline in SO{sub 2} dry deposition, whereas nitrogen deposition remained constant. Furthermore, surface affinities for pollutants changed leading to changes in deposition. Deposition models have been further developed and tested with dry deposition measurements and total deposition measurements on forests as derived from throughfall data. The comparison is reasonable given the measurement uncertainties. Progress in ozone surface exchange modelling and monitoring shows that stomatal uptake can be quantified with reasonable accuracy, but external surface uptake yields highest uncertainty. - Monitoring and modelling of the deposition of sulphur and nitrogen components and the exposure of ozone has gained much progress through the research within BIATEX.
The model study of water mass and energy exchange between the inland water body and atmosphere
Institute of Scientific and Technical Information of China (English)
SUN ShuFen; YAN JinFeng; XIA Nan; LI Qian
2008-01-01
Based on a one-dimensional eddy diffusion model, a model to study the water mass and energy exchange between the water body (such as lake and wetland) and the atmosphere is developed, which takes the phase change process due to the seasonal melting and freezing of water and the convection mixing process of en-ergy caused by temperature stratification into consideration. The model uses en-thalpy instead of temperature as predictive variable, which will help to deal with the phase change process and to design an efficient numerical scheme for obtaining the solution more easily. The performance of the model and the rationality of taking convection mixing into the consideration are validated by using observed data of Kinneret Lake in Israel and Lower Two Medicine Lake in Montana State in America. The comparison of model results with observed data indicates that the model pre-sented here is capable of describing the physical process of water mass and en-ergy between the water body (lake and wetland) and atmosphere. Comparison of the result from wetland with shallow and deep lakes under the same forcing condi-tions shows that the evaporation from wetland is much greater than that from lakes,which accords with the real observation fact and physical mechanism.
The model study of water mass and energy exchange between the inland water body and atmosphere
Institute of Scientific and Technical Information of China (English)
2008-01-01
Based on a one-dimensional eddy diffusion model,a model to study the water mass and energy exchange between the water body(such as lake and wetland) and the atmosphere is developed,which takes the phase change process due to the seasonal melting and freezing of water and the convection mixing process of energy caused by temperature stratification into consideration. The model uses enthalpy instead of temperature as predictive variable,which will help to deal with the phase change process and to design an efficient numerical scheme for obtaining the solution more easily. The performance of the model and the rationality of taking convection mixing into the consideration are validated by using observed data of Kinneret Lake in Israel and Lower Two Medicine Lake in Montana State in America. The comparison of model results with observed data indicates that the model presented here is capable of describing the physical process of water mass and energy between the water body(lake and wetland) and atmosphere. Comparison of the result from wetland with shallow and deep lakes under the same forcing conditions shows that the evaporation from wetland is much greater than that from lakes,which accords with the real observation fact and physical mechanism.
Diagnosing Model Errors in Canopy-Atmosphere Exchange Using Empirical Orthogonal Functions
Drewry, D.; Albertson, J.
2004-12-01
Multi-layer canopy process models (MLCPMs) have been established as tools for estimating local-scale canopy-atmosphere scalar (carbon dioxide, heat and water vapor) exchange as well as testing hypotheses regarding the mechanistic functioning of complex vegetated land surfaces and the interactions between vegetation and the local microenvironment. These model frameworks are composed of a coupled set of component submodels relating radiation attenuation and absorption, photosynthesis, turbulent mixing, stomatal conductance, surface energy balance and soil and subsurface processes. Submodel formulations have been validated for a variety of ecosystems under varying environmental conditions. However, each submodel component requires parameter values that are known to vary seasonally as canopy structure changes, and over shorter periods characterized by shifts in the environmental regime. The temporal dependence of submodel parameters limits application of MLCPMs to short-term integrations for which a specific parameterization can be trusted. We present a novel application of empirical orthogonal function (EOF) analysis to the identification of the primary source of MLCPM error. Carbon dioxide (CO2) concentration profiles, a commonly collected and underutilized data source, are the observed quantity in this analysis. The technique relies on an ensemble of model runs transformed to EOF space to determine the characteristic patterns of model error associated with specific submodel parameters. These patterns provide a basis onto which error residual (modeled - measured) CO2 concentration profiles can be projected to identify the primary source of model error. Synthetic tests and application to field data collected at Duke Forest (North Carolina, USA) are presented.
Wang, Pengfei; Semenova, Yuliya; Zheng, Jie; Wu, Qiang; Muhamad Hatta, Agus; Farrell, Gerald
2011-06-01
A numerical study is carried out to compare the two-dimensional (2-D) case and three-dimensional (3-D) case for the modelling of an ion-exchanged glass waveguide. It is shown that different waveguide widths on the photomask correspond to different ion concentration distributions after an annealing process. A numerical example is presented of two waveguide sections with different widths indicates that due to the abrupt change of the waveguide width, a 3-D theoretical model is required for an accurate prediction of the parameters of ion-exchanged glass waveguides. The good agreement between the modelled and measured results proves that the developed 3-D numerical model can be beneficially utilized in the generalized design of optical devices based on ion-exchange waveguides.
Modeling of protein-anion exchange resin interaction for the human growth hormone charge variants.
Lapelosa, Mauro; Patapoff, Thomas W; Zarraga, Isidro E
2015-12-01
Modeling ion exchange chromatography (IEC) behavior has generated significant interest because of the wide use of IEC as an analytical technique as well as a preparative protein purification process; indeed there is a need for better understanding of what drives the unique behavior of protein charge variants. We hypothesize that a complex protein molecule, which contains both hydrophobic and charged moieties, would interact strongly with an in silico designed resin through charged electrostatic patches on the surface of the protein. In the present work, variants of recombinant human growth hormone that mimic naturally-occurring deamidation products were produced and characterized in silico. The study included these four variants: rhGH, N149D, N152D, and N149D/N152D. Poisson-Boltzmann calculations were used to determine surface electrostatic potential. Metropolis Monte Carlo simulations were carried out with the resulting variants to simulate IEC systems, examining the free energy of the interaction of the protein with an in silico anion exchange column represented by polylysine polypeptide. The results show that the charge variants have different average binding energies and the free energy of interaction can be used to predict the retention time for the different variants.
Understanding and modeling removal of anionic organic contaminants (AOCs) by anion exchange resins.
Zhang, Huichun; Shields, Anthony J; Jadbabaei, Nastaran; Nelson, Maurice; Pan, Bingjun; Suri, Rominder P S
2014-07-01
Ionic organic contaminants (OCs) are a growing concern for water treatment and the environment and are removed inefficiently by many existing technologies. This study examined removal of anionic OCs by anion exchange resins (AXRs) as a promising alternative. Results indicate that two polystyrene AXRs (IRA910 and IRA96) have higher sorption capacities and selectivity than a polyacrylate resin (A860). For the polystyrene resins, selectivity follows: phenolates ≥ aromatic dicarboxylates > aromatic monocarboxylates > benzenesulfonate > aliphatic carboxylates. This trend can be explained based on hydration energy, the number of exchange groups, and aromaticity and hydrophobicity of the nonpolar moiety (NPM) of the anions. For A860, selectivity only varies within a narrow range (0.13-1.64). Despite the importance of the NPM of the anions, neutral solutes were sorbed much less, indicating synergistic combinations of electrostatic and nonelectrostatic interactions in the overall sorption. By conducting multiple linear regression between Abraham's descriptors and nature log of selectivity, induced dipole-related interactions and electrostatic interactions were found to be the most important interaction forces for sorption of the anions, while solute H-bond basicity has a negative effect. A predictive model was then developed for carboxylates and phenolates based on the poly parameter linear free energy relationships established for a diverse range of 16 anions and 5 neutral solutes, and was validated by accurate prediction of sorption of five test solutes within a wide range of equilibrium concentrations and that of benzoate at different pH.
Surface Adsorption from the Exchange-Hole Dipole Moment Dispersion Model.
Christian, Matthew S; Otero-de-la-Roza, Alberto; Johnson, Erin R
2016-07-12
The accurate calculation of intermolecular interaction energies with density functional theory requires methods that include a treatment of long-range, nonlocal dispersion correlation. In this work, we explore the ability of the exchange-hole dipole moment (XDM) dispersion correction to model molecular surface adsorption. Adsorption energies are calculated for six small aromatic molecules (benzene, furan, pyridine, thiophene, thiophenol, and benzenediamine) and the four DNA nucleobases (adenine, thymine, guanine, and cytosine) on the (111) surfaces of the three coinage metals (copper, silver, and gold). For benzene, where the experimental reference data is most precise, the mean absolute error in the computed absorption energies is 0.04 eV. For the other aromatic molecules, the computed binding energies are found to be within 0.09 eV of the available reference data, on average, which is well below the expected experimental uncertainties for temperature-programmed desorption measurements. Unlike other dispersion-corrected functionals, adequate performance does not require changes to the canonical XDM implementation, and the good performance of XDM is explained in terms of the behavior of the exchange hole. Additionally, the base functional employed (B86bPBE) is also optimal for molecular studies, making B86bPBE-XDM an excellent candidate for studying chemistry on material surfaces. Finally, the noncovalent interaction (NCI) plot technique is shown to detect adsorption effects in real space on the order of tenths of an eV.
Hong, Jung Sun; Huber, Kerry C
2015-05-20
Reaction patterns of wheat starch derivatized with a fluorescent probe (model reaction system) were investigated over the course of a reaction period (0.5, 4, 12, or 24h). Debranched derivatives were fractionated into three populations (Unbound, Bound-1, Bound-2) based on charge density via anion-exchange chromatography, with each ion-exchanged fraction further analyzed by size-exclusion chromatography (refractive index [RI] and fluorescence [FL] detection) to assess proportions and patterns of reaction on amylose (AM) and amylopectin (AP) long (LC), medium (MC), and short (SC) branch chains. Approximately 11-12% of the total chains accounted for 63-75% of the FL recovered in the two bound fractions. FL peaks representing AM, AP-LC, AP-MC, AP-SC, and intermediate material (eluted with AM based on molecular size, but reacted more akin to AP-LC) were monitored over the reaction period. Fractionation behaviors varied amongst starch chains, attributable to the impact of the granule structure on molecular reaction patterns.
Using a Theory-Consistent CVAR Scenario to Test an Exchange Rate Model Based on Imperfect Knowledge
Directory of Open Access Journals (Sweden)
Katarina Juselius
2017-07-01
Full Text Available A theory-consistent CVAR scenario describes a set of testable regularieties one should expect to see in the data if the basic assumptions of the theoretical model are empirically valid. Using this method, the paper demonstrates that all basic assumptions about the shock structure and steady-state behavior of an an imperfect knowledge based model for exchange rate determination can be formulated as testable hypotheses on common stochastic trends and cointegration. This model obtaines remarkable support for almost every testable hypothesis and is able to adequately account for the long persistent swings in the real exchange rate.
A two level hierarchical model of protein retention in ion exchange chromatography.
Salvalaglio, Matteo; Paloni, Matteo; Guelat, Bertrand; Morbidelli, Massimo; Cavallotti, Carlo
2015-09-11
Predicting protein retention in ion exchange chromatography (IEX) from first principles is a fascinating perspective. In this work a two level hierarchical modeling strategy is proposed in order to calculate protein retention factors. Model predictions are tested against experimental data measured for Lysozyme and Chymotrypsinogen A in IEX columns as a function of ionic strength and pH. At the highest level of accuracy Molecular Dynamics (MD) simulations in explicit water are used to determine the interaction free energy between each of the two proteins and the IEX stationary phase for a reference pH and ionic strength. At a lower level of accuracy a linear response model based on an implicit treatment of solvation and adopting a static protein structure is used to calculate interaction free energies for the full range of pHs and ionic strengths considered. A scaling coefficient, determined comparing MD and implicit solvent simulations, is then introduced in order to correct the linear response model for errors induced by the adoption of a static protein structure. The calculated free energies are then used to compute protein retention factors, which can be directly compared with experimental data. The possibility to introduce a third level of accuracy is explored testing the predictions of a semiempirical model. A quantitative agreement between the predicted and measured protein retention factors is obtained using the coupled MD-linear response models, supporting the reliability of the proposed approach. The model allows quantifying the electrostatic, van der Waals, and conformational contributions to the interaction free energies. A good agreement between experiments and model is obtained also using the semiempirical model that, although requiring parameterization over higher level models or experimental data, proves to be useful in order to rapidly determine protein retention factors across wide pH and ionic strength ranges as it is computationally inexpensive.
Model-based high-throughput design of ion exchange protein chromatography.
Khalaf, Rushd; Heymann, Julia; LeSaout, Xavier; Monard, Florence; Costioli, Matteo; Morbidelli, Massimo
2016-08-12
This work describes the development of a model-based high-throughput design (MHD) tool for the operating space determination of a chromatographic cation-exchange protein purification process. Based on a previously developed thermodynamic mechanistic model, the MHD tool generates a large amount of system knowledge and thereby permits minimizing the required experimental workload. In particular, each new experiment is designed to generate information needed to help refine and improve the model. Unnecessary experiments that do not increase system knowledge are avoided. Instead of aspiring to a perfectly parameterized model, the goal of this design tool is to use early model parameter estimates to find interesting experimental spaces, and to refine the model parameter estimates with each new experiment until a satisfactory set of process parameters is found. The MHD tool is split into four sections: (1) prediction, high throughput experimentation using experiments in (2) diluted conditions and (3) robotic automated liquid handling workstations (robotic workstation), and (4) operating space determination and validation. (1) Protein and resin information, in conjunction with the thermodynamic model, is used to predict protein resin capacity. (2) The predicted model parameters are refined based on gradient experiments in diluted conditions. (3) Experiments on the robotic workstation are used to further refine the model parameters. (4) The refined model is used to determine operating parameter space that allows for satisfactory purification of the protein of interest on the HPLC scale. Each section of the MHD tool is used to define the adequate experimental procedures for the next section, thus avoiding any unnecessary experimental work. We used the MHD tool to design a polishing step for two proteins, a monoclonal antibody and a fusion protein, on two chromatographic resins, in order to demonstrate it has the ability to strongly accelerate the early phases of process
Projecting Ammonia Dry Deposition Using Passive Samplers and a Bi-Directional Exchange Model
Robarge, W. P.; Walker, J. T.; Austin, R. E.
2011-12-01
Animal agriculture within the United States is known to be a source of ammonia (NH3) emissions. Dry deposition of NH3 to terrestrial ecosystems immediately surrounding large local sources of NH3 emissions (e.g. animal feeding operations) is difficult to measure, and is best estimated via models. Presented here are results for a semi-empirical modeling approach for estimating air-surface exchange fluxes of NH3 downwind of a large poultry facility (~ 3.5 million layers) using a bi-directional air-surface exchange model. The modeling domain is the western section of the Pocosin Lakes National Wildlife Refuge in Tyrrell, Washington, and Hyde Counties of eastern North Carolina in the South Atlantic Coastal Plain physiographic region. Vegetation within the modeling domain is primarily pocosin wetlands, characterized by acid (pH 3.6) peat soils and a thick canopy of shrub vegetation (leatherwood (Cyrilla racemiflora), inkberry (Ilex glabra), wax myrtle (Morella cerifera)). Land surrounding the refuge is primarily used for crop production: ~ 28%, 24%, and 45% agricultural in Tyrell, Hyde, and Washington counties, respectively. Ammonia air-surface exchange (flux) was calculated using a two-layer canopy compensation point model developed by Nemitz et al. (2001. Quart. J. Roy. Met. Soc. 127, 815 - 833.) as implemented by Walker et al. (2008. Atmos. Environ., 42, 3407 - 3418.), in which the competing processes of emission and deposition within the foliage-soil system were taken into account by relating the net canopy-scale NH3 flux to the net emission potential of the canopy (i.e., foliage and soil). Ammonia air concentrations were measured using ALPHA passive samplers (Center for Ecology and Hydrology, Edinburgh) along transects to the north and northeast of the poultry facility at distances of 800, 2000 and 3200 m, respectively. Samplers were deployed in duplicate at each location at a height of 5.8 m from July 2008 to July 2010 weekly during warm months and bi-weekly curing
Energy Technology Data Exchange (ETDEWEB)
Banerjee, Santanu; Vasu, P [Institute for Plasma Research, Bhat, Gandhinagar 382 428, Gujarat (India); Von Hellermann, M [FOM Institute for Plasma Physics, Rijnhuizen (Netherlands); Jaspers, R J E, E-mail: sbanerje@ipr.res.i [Applied Physics Department, Eindhoven University of Technology, Eindhoven (Netherlands)
2010-12-15
Contamination of optical signals by reflections from the tokamak vessel wall is a matter of great concern. For machines such as ITER and future reactors, where the vessel wall will be predominantly metallic, this is potentially a risk factor for quantitative optical emission spectroscopy. This is, in particular, the case when bremsstrahlung continuum radiation from the bulk plasma is used as a common reference light source for the cross-calibration of visible spectroscopy. In this paper the reflected contribution to the continuum level in Textor and ITER has been estimated for the detection channels meant for charge exchange recombination spectroscopy (CXRS). A model assuming diffuse reflection has been developed for the bremsstrahlung which is a much extended source. Based on this model, it is shown that in the case of ITER upper port 3, a wall with a moderate reflectivity of 20% leads to the wall reflected fraction being as high as 55-60% of the weak signals in the edge channels. In contrast, a complete bidirectional reflectance distribution function (BRDF) based model has been developed in order to estimate the reflections from more localized sources like the charge exchange (CX) emission from a neutral beam in tokamaks. The largest signal contamination of {approx}15% is seen in the core CX channels, where the true CX signal level is much lower than that in the edge channels. Similar values are obtained for Textor also. These results indicate that the contributions from wall reflections may be large enough to significantly distort the overall spectral features of CX data, warranting an analysis at different wavelengths.
Banerjee, Santanu; Vasu, P.; von Hellermann, M.; Jaspers, R. J. E.
2010-12-01
Contamination of optical signals by reflections from the tokamak vessel wall is a matter of great concern. For machines such as ITER and future reactors, where the vessel wall will be predominantly metallic, this is potentially a risk factor for quantitative optical emission spectroscopy. This is, in particular, the case when bremsstrahlung continuum radiation from the bulk plasma is used as a common reference light source for the cross-calibration of visible spectroscopy. In this paper the reflected contribution to the continuum level in Textor and ITER has been estimated for the detection channels meant for charge exchange recombination spectroscopy (CXRS). A model assuming diffuse reflection has been developed for the bremsstrahlung which is a much extended source. Based on this model, it is shown that in the case of ITER upper port 3, a wall with a moderate reflectivity of 20% leads to the wall reflected fraction being as high as 55-60% of the weak signals in the edge channels. In contrast, a complete bidirectional reflectance distribution function (BRDF) based model has been developed in order to estimate the reflections from more localized sources like the charge exchange (CX) emission from a neutral beam in tokamaks. The largest signal contamination of ~15% is seen in the core CX channels, where the true CX signal level is much lower than that in the edge channels. Similar values are obtained for Textor also. These results indicate that the contributions from wall reflections may be large enough to significantly distort the overall spectral features of CX data, warranting an analysis at different wavelengths.
Energy Technology Data Exchange (ETDEWEB)
Inan, Aslan; Izgi, Ercan; Ay, Selim [Department of Electrical Engineering, Faculty of Electric-Electronics, Technical University of Yildiz, 34349 Istanbul (Turkey)
2009-04-15
In this paper, to what extent a cogeneration system's fixed and variable costs and profits are affected from the exchange rate model implemented in the country is examined. An autoproductor system, as known, uses a part of its electrical energy production for its own requirements while selling the remaining energy to the regional energy corporation. As a function of the load factor and the fuel cost, the production cost and energy sale income of the system are influenced much by the exchange rate model of the country. A cost analysis of a natural gas cogeneration (autoproductor) system has been performed for the numerical application, based on the monetary program supported by the IMF commenced in January 2000. In order to investigate the effect of the change in exchange rate model (introducing the floating exchange rate model) on the fuel cost, both the characteristics of the IMF program and some various forecasting methods have been utilized. (author)
The paper discusses a refrigerator/freezer (RF) system that has two complete and independent refrigeration cycles for the two compartments. It uses a non-azeotropic refrigerant mixture (NARM) in each cycle and countercurrent heat exchangers throughout. This RF is housed in a stan...
Kong, Kook-Jin; Yu, Byung-Geel
2016-01-01
We investigate the role driven by the $\\sigma$ exchange in the photoproduction of $\\phi$ meson off a proton by using the Reggeized model. In this reaction, in addition to the Pomeron exchange which constitutes the background contribution extending to high energies, the $\\sigma$ Regge-pole exchange is found to give an interesting contribution to the reaction process near threshold. In particular, the $\\sigma$ exchange can reproduce reasonably well the bump structure at the forward angle in the differential cross section as well as the peaking behavior in the total cross section observed in the CLAS collaboration. We also show that our calculation reproduces well the recent data for the differential cross section from the LEPS and CLAS at low energies. Moreover, the scaled cross section $s^7d\\sigma /dt$ at the production angle $\\theta=90^{\\circ}$ obtained from the CLAS data is found to be consistent with the calculation using the canonical phase of the $\\sigma$ Regge-pole.
Monitoring and modelling of biosphere/atmosphere exchange of gases and aerosols in Europe.
Erisman, Jan Willem; Vermeulen, Alex; Hensen, Arjan; Flechard, Chris; Dämmgen, Ulrich; Fowler, David; Sutton, Mark; Grünhage, Ludger; Tuovinen, Juha-Pekka
2005-02-01
Monitoring and modelling of deposition of air pollutants is essential to develop and evaluate policies to abate the effects related to air pollution and to determine the losses of pollutants from the atmosphere. Techniques for monitoring wet deposition fluxes are widely applied. A recent intercomparison experiment, however, showed that the uncertainty in wet deposition is relatively high, up to 40%, apart from the fact that most samplers are biased because of a dry deposition contribution. Wet deposition amounts to about 80% of the total deposition in Europe with a range of 10-90% and uncertainty should therefore be decreased. During recent years the monitoring of dry deposition has become possible. Three sites have been operational for 5 years. The data are useful for model development, but also for model evaluation and monitoring of progress in policy. Data show a decline in SO(2) dry deposition, whereas nitrogen deposition remained constant. Furthermore, surface affinities for pollutants changed leading to changes in deposition. Deposition models have been further developed and tested with dry deposition measurements and total deposition measurements on forests as derived from throughfall data. The comparison is reasonable given the measurement uncertainties. Progress in ozone surface exchange modelling and monitoring shows that stomatal uptake can be quantified with reasonable accuracy, but external surface uptake yields highest uncertainty.
Ebrahimi, Shelir; Roberts, Deborah J
2016-01-01
Nitrate contamination is one of the largest issues facing communities worldwide. One of the most common methods for nitrate removal from water is ion exchange using nitrate selective resin. Although these resins have a great capacity for nitrate removal, they are considered non regenerable. The sustainability of nitrate-contaminated water treatment processes can be achieved by regenerating the exhausted resin several times rather than replacing and incineration of exhausted resin. The use of multi-cycle exhaustion/bioregeneration of resin enclosed in a membrane has been shown to be an effective and innovative regeneration method. In this research, the mechanisms for bioregeneration of resin were studied and a mathematical model which incorporated physical desorption process with biological removal kinetics was developed. Regardless of the salt concentration of the solution, this specific resin is a pore-diffusion controlled process (XδD ¯CDr0(5+2α)3) shows that the bioregeneration process is controlled by reaction kinetics and is governed by biological removal of nitrate. The model was validated by comparison to experimental data; the average of R-squared values for cycle 1 to 5 of regeneration was 0.94 ± 0.06 which shows that the developed model predicted the experimental results very well. The model sensitivity for different parameters was evaluated and a model bioreactor design for bioregeneration of highly selective resins was also presented.
Comparison of heat flux estimations from two turbulent exchange models based on thermal UAV data.
Hoffmann, Helene; Nieto, Hector; Jensen, Rasmus; Friborg, Thomas
2015-04-01
Advantages of UAV (Unmanned Aerial Vehicle) data-collection, compared to more traditional data-collections are numerous and already well-discussed (Berni et al., 2009; Laliberte et al., 2011; Turner et al., 2012). However studies investigating the quality and applications of UAV-data are crucial if advantages are to be beneficial for scientific purposes. In this study, thermal data collected over an agricultural site in Denmark have been obtained using a fixed-wing UAV and investigated for the estimation of heat fluxes. Estimation of heat fluxes requires high precision data and careful data processing. Latent, sensible and soil heat fluxes are estimates through two models of the two source energy modelling scheme driven by remotely sensed observations of land surface temperature; the original TSEB (Norman et al., 1995) and the DTD (Norman et al., 2000) which builds on the TSEB. The DTD model accounts for errors arising when deriving radiometric temperatures and can to some extent compensate for the fact that thermal cameras rarely are accurate. The DTD model requires an additional set of remotely sensed data during morning hours of the day at which heat fluxes are to be determined. This makes the DTD model ideal to use when combined with UAV data, because acquisition of data is not limited by fixed time by-passing tracks like satellite images (Guzinski et al., 2013). Based on these data, heat fluxes are computed from the two models and compared with fluxes from an eddy covariance station situated within the same designated agricultural site. This over-all procedure potentially enables an assessment of both the collected thermal UAV-data and of the two turbulent exchange models. Results reveal that both TSEB and DTD models compute heat fluxes from thermal UAV data that is within a very reasonable range and also that estimates from the DTD model is in best agreement with the eddy covariance system.
Simon, E.; Meixner, F.X.; Ganzeveld, L.N.; Kesselmeier, J.
2005-01-01
Detailed one-dimensional multilayer biosphere-atmosphere models, also referred to as CANVEG models, are used for more than a decade to describe coupled water-carbon exchange between the terrestrial vegetation and the lower atmosphere. Within the present study, a modified CANVEG scheme is described.
between-home and between-city variability in residential pollutant infiltration. This is likely a result of differences in home ventilation, or air exchange rates (AER). The Stochastic Human Exposure and Dose Simulation (SHEDS) model is a population exposure model that uses a pro...
Energy Technology Data Exchange (ETDEWEB)
Bauer, Dan
2011-07-15
The thermal use of the underground for heating and cooling applications can be done with borehole heat exchangers. This work deals with the further development of the modelling of thermal transport processes inside and outside the borehole as well as with the application of the further developed models. The combination of high accuracy and short computation time is achieved by the development of three-dimensional thermal resistance and capacity models for borehole heat exchangers. Short transient transport processes can be calculated by the developed model with a considerable higher dynamic and accuracy than with known models from literature. The model is used to evaluate measurement data of a thermal response test by parameter estimation technique with a transient three-dimensional model for the first time. Clear advantages like shortening of the test duration are shown. The developed borehole heat exchanger model is combined with a three-dimensional description of the underground in the Finite-Element-Program FEFLOW. The influence of moving groundwater on borehole heat exchangers and borehole thermal energy stores is then quantified.
Guevara-Arauza, J.C.; Yahia, E.M.; Cedeno, L.; Tijskens, L.M.M.
2006-01-01
A model to estimate gas profile of modified atmosphere packaged (MAP) prickly pear cactus stems was developed and calibrated. The model describes the transient gas exchange taking in consideration the effect of temperature (T) and relative humidity (RH) on film permeability (FPgas), respiration rate
Finite element modeling of borehole heat exchanger systems. Part 2. Numerical simulation
Diersch, H.-J. G.; Bauer, D.; Heidemann, W.; Rühaak, W.; Schätzl, P.
2011-08-01
Single borehole heat exchanger (BHE) and arrays of BHE are modeled by using the finite element method. Applying BHE in regional discretizations optimal conditions of mesh spacing around singular BHE nodes are derived. Optimal meshes have shown superior to such discretizations which are either too fine or too coarse. The numerical methods are benchmarked against analytical and numerical reference solutions. Practical application to a borehole thermal energy store (BTES) consisting of 80 BHE is given for the real-site BTES Crailsheim, Germany. The simulations are controlled by the specifically developed FEFLOW-TRNSYS coupling module. Scenarios indicate the effect of the groundwater flow regime on efficiency and reliability of the subsurface heat storage system.
Down-Hole Heat Exchangers: Modelling of a Low-Enthalpy Geothermal System for District Heating
Directory of Open Access Journals (Sweden)
M. Carlini
2012-01-01
Full Text Available In order to face the growing energy demands, renewable energy sources can provide an alternative to fossil fuels. Thus, low-enthalpy geothermal plants may play a fundamental role in those areas—such as the Province of Viterbo—where shallow groundwater basins occur and conventional geothermal plants cannot be developed. This may lead to being fuelled by locally available sources. The aim of the present paper is to exploit the heat coming from a low-enthalpy geothermal system. The experimental plant consists in a down-hole heat exchanger for civil purposes and can supply thermal needs by district heating. An implementation in MATLAB environment is provided in order to develop a mathematical model. As a consequence, the amount of withdrawable heat can be successfully calculated.
Risk Forecasting of Karachi Stock Exchange: A Comparison of Classical and Bayesian GARCH Models
Directory of Open Access Journals (Sweden)
Farhat Iqbal
2016-09-01
Full Text Available This paper is concerned with the estimation, forecasting and evaluation of Value-at-Risk (VaR of Karachi Stock Exchange before and after the global financial crisis of 2008 using Bayesian method. The generalized autoregressive conditional heteroscedastic (GARCH models under the assumption of normal and heavy-tailed errors are used to forecast one-day-ahead risk estimates. Various measures and backtesting methods are employed to evaluate VaR forecasts. The observed number of VaR violations using Bayesian method is found close to the expected number of violations. The losses are also found smaller than the competing Maximum Likelihood method. The results showed that the Bayesian method produce accurate and reliable VaR forecasts and can be preferred over other methods.
Two-photon-exchange effects in the unpolarized $\\mu p$ scattering within the hadronic model
Zhou, Hai-Qing
2016-01-01
In this work, the two-photon-exchange (TPE) effects in the unpolarized $\\mu p$ scattering are discussed within the hadronic model where the intermediate states $N,\\Delta$ and $\\sigma$ are considered. The contribution from the $N$ intermediate is close to the results given by Ref. \\cite{Tomalak2014} at the small $Q$ and there is a sizeable difference when $Q>0.25$GeV (where $Q^2$ is the four momentum transfer). The contributions from the $\\Delta$ and the $\\sigma$ intermediate states are much smaller than that from the $N$ intermediate at the small $Q$. In the kinematic region with $k_i\\subseteq [0.01,0.3]$ GeV and $Q \\leq0.4$GeV (where $k_i$ is the three momentum of initial muon at Lab frame), a naive expression for the TPE contributions is given, which can be used directly for other analysis.
Modelling shelf-ocean exchange and its biogeochemical consequences in coastal upwelling systems
DEFF Research Database (Denmark)
Muchamad, Al Azhar
slope and deeper depths. The coupled model may potentially serve as a robust tool in investigation of the dynamics of oceanic biogeochemical cycle throughout Earth history as well as a practical method to quantified storage of carbon flux into the ocean across the continental margins under present day...... in eastern boundary upwelling systems is an example of the most productive ocean waters over continental margins where intense supply of nutrients occur from deeper ocean waters. Interesting questions arise related to the biogeochemical cycles in such upwelling systems; such as 1) how the recently observed...... active but cryptic sulfur cycle possibly is coupled to the nitrogen cycle in an oxygen-minimum-zone (OMZ), 2) what is the relation between the shelf–ocean exchange, continental shelf width and development of the observed bottom water anoxia/euxinia associated with different configurations of continental...
Sánchez-Fuentes, María del Mar; Santos-Iglesias, Pablo
2016-01-01
The study of sexual satisfaction in Spain is scarce and has proceeded atheoretically. This study aimed at examining sexual satisfaction in 197 Spanish heterosexual couples based on the Interpersonal Exchange Model of Sexual Satisfaction. Men and women reported equal satisfaction. Men's sexual satisfaction was predicted by their own relationship satisfaction, balance of sexual rewards and costs, and comparison level of sexual rewards and costs. Women's sexual satisfaction was predicted by their own relationship satisfaction, balance of sexual rewards and costs, comparison level of sexual rewards and costs, equality of sexual costs, and their partner's balance of sexual rewards and costs. These results provide with a better understanding of the mechanisms that explain sexual satisfaction in Spanish couples. Implications for research and therapy are discussed.
A Web-Based Resource Model for eScience: Object Reuse & Exchange
Lagoze, Carl; Nelson, Michael; Warner, Simeon; Sanderson, Robert; Johnston, Pete
2008-01-01
Work in the Open Archives Initiative - Object Reuse and Exchange (OAI-ORE) focuses on an important aspect of infrastructure for eScience: the specification of the data model and a suite of implementation standards to identify and describe compound objects. These are objects that aggregate multiple sources of content including text, images, data, visualization tools, and the like. These aggregations are an essential product of eScience, and will become increasingly common in the age of data-driven scholarship. The OAI-ORE specifications conform to the core concepts of the Web architecture and the semantic Web, ensuring that applications that use them will integrate well into the general Web environment.
Two-component mixture model: Application to palm oil and exchange rate
Phoong, Seuk-Yen; Ismail, Mohd Tahir; Hamzah, Firdaus Mohamad
2014-12-01
Palm oil is a seed crop which is widely adopt for food and non-food products such as cookie, vegetable oil, cosmetics, household products and others. Palm oil is majority growth in Malaysia and Indonesia. However, the demand for palm oil is getting growth and rapidly running out over the years. This phenomenal cause illegal logging of trees and destroy the natural habitat. Hence, the present paper investigates the relationship between exchange rate and palm oil price in Malaysia by using Maximum Likelihood Estimation via Newton-Raphson algorithm to fit a two components mixture model. Besides, this paper proposes a mixture of normal distribution to accommodate with asymmetry characteristics and platykurtic time series data.
Modeling and simulation of the dynamic behavior of portable proton exchange membrane fuel cells
Energy Technology Data Exchange (ETDEWEB)
Ziegler, C.
2005-07-01
In order to analyze the operational behavior, a mathematical model of planar self-breathing fuel cells is developed and validated in Chapter 3 of this thesis. The multicomponent transport of the species is considered as well as the couplings between the transport processes of heat, charge, and mass and the electrochemical reactions. Furthermore, to explain the oxygen mass transport limitation in the porous electrode of the cathode side an agglomerate model for the oxygen reduction reaction is developed. In Chapter 4 the important issue of liquid water generation and transport in PEMFCs is addressed. One of the major tasks when operating this type of fuel cell is avoiding the complete flooding of the PEMFC during operation. A one-dimensional and isothermal model is developed that is based on a coupled system of partial differential equations. The model contains a dynamic and two-phase description of the proton exchange membrane fuel cell. The mass transport in the gas phase and in the liquid phase is considered as well as the phase transition between liquid water and water vapor. The transport of charges and the electrochemical reactions are part of the model. Flooding effects that are caused by liquid water accumulation are described by this model. Moreover, the model contains a time-dependent description of the membrane that accounts for Schroeder's paradox. The model is applied to simulate cyclic voltammograms. Chapter 5 is focused on the dynamic investigation of PEMFC stacks. Understanding the dynamic behavior of fuel cell stacks is important for the operation and control of fuel cell stacks. Using the single cell model of Chapter 3 and the dynamic model of Chapter 4 as basis, a mathematical model of a PEMFC stack is developed. However, due to the complexity of a fuel cell stack, the spatial resolution and dynamic description of the liquid water transport are not accounted for. These restrictions allow for direct comparison between the solution variables of
Model of a vanadium redox flow battery with an anion exchange membrane and a Larminie-correction
Wandschneider, F. T.; Finke, D.; Grosjean, S.; Fischer, P.; Pinkwart, K.; Tübke, J.; Nirschl, H.
2014-12-01
Membranes are an important part of vanadium redox flow battery cells. Most cell designs use Nafion®-type membranes which are cation exchange membranes. Anion exchange membranes are reported to improve cell performance. A model for a vanadium redox flow battery with an anion exchange membrane is developed. The model is then used to calculate terminal voltages for open circuit and charge-discharge conditions. The results are compared to measured data from a laboratory test cell with 40 cm2 active membrane area. For higher charge and discharge currents, an empirical correction for the terminal voltage is proposed. The model geometry comprises the porous electrodes and the connected pipes, allowing a study of the flow in the entrance region for different state-of-charges.
A mechanistic model of ion-exchange chromatography on polymer fiber stationary phases.
Winderl, Johannes; Hahn, Tobias; Hubbuch, Jürgen
2016-12-02
Fibers are prominent among novel stationary phase supports for preparative chromatography. Several recent studies have highlighted the potential of fiber-based adsorbents for high productivity downstream processing in both batch and continuous mode, but so far the development of these materials and of processes employing these materials has solely been based on experimental data. In this study we assessed whether mechanistic modeling can be performed on fiber-based adsorbents. With a column randomly filled with short cut hydrogel grafted anion exchange fibers, we tested whether tracer, linear gradient elution, and breakthrough data could be reproduced by mechanistic models. Successful modeling was achieved for all of the considered experiments, for both non-retained and retained molecules. For the fibers used in this study the best results were obtained with a transport-dispersive model in combination with a steric mass action isotherm. This approach accurately accounted for the convection and dispersion of non-retained tracers, and the breakthrough and elution behaviors of three different proteins with sizes ranging from 6 to 160kDa were accurately modeled, with simulation results closely resembling the experimental data. The estimated model parameters were plausible both from their physical meaning, and from an analysis of the underlying model assumptions. Parameters were determined within good confidence levels; the average confidence estimate was below 7% for confidence levels of 95%. This shows that fiber-based adsorbents can be modeled mechanistically, which will be valuable for the future design and evaluation of these novel materials and for the development of processes employing such materials.
Modelling the Interaction of Multiple Borehole Heat Exchangers in Shallow Geothermal Fields
Shao, H.; Schelenz, S.; Kist, N.; Shim, B. O.; Bucher, A.; Kolditz, O.
2014-12-01
The utilization of Borehole Heat Exchanger (BHE) to transfer heat from the shallow subsurface has been a common practice for the Ground Source Heat Pump (GSHP) system. To represent realistic application scenarios for numerical simulations of such systems, saturated and unsaturated conditions as well as heterogeneous soil properties have to be considered. Analytical solutions such as the Moving Finite Line Source (MFLS) model are not flexible enough to capture the full dynamics of the system. Furthermore, application examples with a high density of installed BHEs exist. There, temperature plumes produced by the individual BHEs may start to interact with each other and lead to lower thermal output. To simulate this interaction, a dual continuum approach has been implemented into the open-source FEM simulator OpenGeoSys (OGS). The model is capable of simulating the temperature evolution around the BHE, with the consideration of both saturated and unsaturated groundwater flow processes in the surrounding soil. Instead of imposing Dirichlet or Neumann type of boundary condition at the location of a BHE, the newly developed model allows the user to specify inflow refrigerant temperature and flow rate as the driving force of heat transport. In a benchmark with homogeneous soil properties and fully saturated condition, temperature evolution predicted by the numerical model has been verified against MFLS analytical solution. In a second benchmark, the model simulated outflow temperature is validated by comparing to field measured data from a Thermal Response Test (TRT), provided by the Korean Institute of Geoscience and Mineral Resources (KIGAM) in Dajeon, South Korea. After simulating several shallow geothermal scenarios of multiple BHEs operating in close vicinity, we find that the super-imposed MFLS based analytical solution predicts similar temperature distribution, provided the heat extraction from each BHE is relatively low. However, when the heat exchange rate is
Pan-Arctic modelling of net ecosystem exchange of CO2.
Shaver, G R; Rastetter, E B; Salmon, V; Street, L E; van de Weg, M J; Rocha, A; van Wijk, M T; Williams, M
2013-08-19
Net ecosystem exchange (NEE) of C varies greatly among Arctic ecosystems. Here, we show that approximately 75 per cent of this variation can be accounted for in a single regression model that predicts NEE as a function of leaf area index (LAI), air temperature and photosynthetically active radiation (PAR). The model was developed in concert with a survey of the light response of NEE in Arctic and subarctic tundras in Alaska, Greenland, Svalbard and Sweden. Model parametrizations based on data collected in one part of the Arctic can be used to predict NEE in other parts of the Arctic with accuracy similar to that of predictions based on data collected in the same site where NEE is predicted. The principal requirement for the dataset is that it should contain a sufficiently wide range of measurements of NEE at both high and low values of LAI, air temperature and PAR, to properly constrain the estimates of model parameters. Canopy N content can also be substituted for leaf area in predicting NEE, with equal or greater accuracy, but substitution of soil temperature for air temperature does not improve predictions. Overall, the results suggest a remarkable convergence in regulation of NEE in diverse ecosystem types throughout the Arctic.
Contribution of aboveground biomass uncertainty to bias in modeled global net ecosystem exchange
Poulter, B.; Delbart, N.; Maignan, F.; Saatchi, S. S.; Sitch, S.; Ciais, P.
2011-12-01
Biomass is a key ecosystem property that links biogeochemical fluxes with the accumulation of carbon. The spatial and temporal dynamics of biomass have implications for climate stability and other ecosystem services. Globally, terrestrial forest ecosystems store approximately 383 Pg C in aboveground biomass, about 45% compared to the amount of carbon in the atmosphere. Model-data comparisons of aboveground biomass have so far been limited by a lack of wall-to-wall coverage, which has recently been resolved from satellite remote sensing. These recent satellite products use lidar to measure forest structure directly or have developed novel data-fusion techniques. Here, we compare biomass estimates among terrestrial carbon cycle models, and benchmark these estimates with inventory and satellite-based estimates. Using an ensemble of dynamic global vegetation model simulations from the TRENDY archive, we then use the distribution of biomass estimates to evaluate bias in net ecosystem exchange caused by uncertainty from carbon turnover. By identifying detailed model structure and parameters that are linked to carbon turnover, targeted improvements can be made to more realistically simulate aboveground biomass.
Modelling heat and mass transfer in a membrane-based air-to-air enthalpy exchanger
Dugaria, S.; Moro, L.; Del, D., Col
2015-11-01
The diffusion of total energy recovery systems could lead to a significant reduction in the energy demand for building air-conditioning. With these devices, sensible heat and humidity can be recovered in winter from the exhaust airstream, while, in summer, the incoming air stream can be cooled and dehumidified by transferring the excess heat and moisture to the exhaust air stream. Membrane based enthalpy exchangers are composed by different channels separated by semi-permeable membranes. The membrane allows moisture transfer under vapour pressure difference, or water concentration difference, between the two sides and, at the same time, it is ideally impermeable to air and other contaminants present in exhaust air. Heat transfer between the airstreams occurs through the membrane due to the temperature gradient. The aim of this work is to develop a detailed model of the coupled heat and mass transfer mechanisms through the membrane between the two airstreams. After a review of the most relevant models published in the scientific literature, the governing equations are presented and some simplifying assumptions are analysed and discussed. As a result, a steady-state, two-dimensional finite difference numerical model is setup. The developed model is able to predict temperature and humidity evolution inside the channels. Sensible and latent heat transfer rate, as well as moisture transfer rate, are determined. A sensitive analysis is conducted in order to determine the more influential parameters on the thermal and vapour transfer.
Merrill, Jacqueline A; Deegan, Michael; Wilson, Rosalind V; Kaushal, Rainu; Fredericks, Kimberly
2013-06-01
To evaluate the complex dynamics involved in implementing electronic health information exchange (HIE) for public health reporting at a state health department, and to identify policy implications to inform similar implementations. Qualitative data were collected over 8 months from seven experts at New York State Department of Health who implemented web services and protocols for querying, receipt, and validation of electronic data supplied by regional health information organizations. Extensive project documentation was also collected. During group meetings experts described the implementation process and created reference modes and causal diagrams that the evaluation team used to build a preliminary model. System dynamics modeling techniques were applied iteratively to build causal loop diagrams representing the implementation. The diagrams were validated iteratively by individual experts followed by group review online, and through confirmatory review of documents and artifacts. Three casual loop diagrams captured well-recognized system dynamics: Sliding Goals, Project Rework, and Maturity of Resources. The findings were associated with specific policies that address funding, leadership, ensuring expertise, planning for rework, communication, and timeline management. This evaluation illustrates the value of a qualitative approach to system dynamics modeling. As a tool for strategic thinking on complicated and intense processes, qualitative models can be produced with fewer resources than a full simulation, yet still provide insights that are timely and relevant. System dynamics techniques clarified endogenous and exogenous factors at play in a highly complex technology implementation, which may inform other states engaged in implementing HIE supported by federal Health Information Technology for Economic and Clinical Health (HITECH) legislation.
Contact behavior modelling and its size effect on proton exchange membrane fuel cell
Qiu, Diankai; Peng, Linfa; Yi, Peiyun; Lai, Xinmin; Janßen, Holger; Lehnert, Werner
2017-10-01
Contact behavior between the gas diffusion layer (GDL) and bipolar plate (BPP) is of significant importance for proton exchange membrane fuel cells. Most current studies on contact behavior utilize experiments and finite element modelling and focus on fuel cells with graphite BPPs, which lead to high costs and huge computational requirements. The objective of this work is to build a more effective analytical method for contact behavior in fuel cells and investigate the size effect resulting from configuration alteration of channel and rib (channel/rib). Firstly, a mathematical description of channel/rib geometry is outlined in accordance with the fabrication of metallic BPP. Based on the interface deformation characteristic and Winkler surface model, contact pressure between BPP and GDL is then calculated to predict contact resistance and GDL porosity as evaluative parameters of contact behavior. Then, experiments on BPP fabrication and contact resistance measurement are conducted to validate the model. The measured results demonstrate an obvious dependence on channel/rib size. Feasibility of the model used in graphite fuel cells is also discussed. Finally, size factor is proposed for evaluating the rule of size effect. Significant increase occurs in contact resistance and porosity for higher size factor, in which channel/rib width decrease.
Directory of Open Access Journals (Sweden)
Federico Ramírez
2011-07-01
Full Text Available
One of the most common difficulties students face in learning Thermodynamics lies in grasping the physical meaning of concepts such as lost availability and entropy generation. This explains the quest for new approaches for explaining and comprehending these quantities, as suggested by diagrams from different authors. The difficulties worsen in the case of irreversibilities associated with heat transfer processes driven by a finite temperature difference, where no work transfer takes place. An equivalent mechanical model is proposed in this paper. Heat exchangers are modelled by means of Carnot heat engines and mechanical transmissions; the use of mechanical models allows an easy visualization of thermal irreversibilities. The proposed model is further applied to a power cycle, thus obtaining an “equivalent arrangement” where irreversibilities become clearly apparent.
Kumar, Vijesh; Leweke, Samuel; von Lieres, Eric; Rathore, Anurag S
2015-12-24
Ion-exchange chromatography (IEX) is universally accepted as the optimal method for achieving process scale separation of charge variants of a monoclonal antibody (mAb) therapeutic. These variants are closely related to the product and a baseline separation is rarely achieved. The general practice is to fractionate the eluate from the IEX column, analyze the fractions and then pool the desired fractions to obtain the targeted composition of variants. This is, however, a very cumbersome and time consuming exercise. A mechanistic model that is capable of simulating the peak profile will be a much more elegant and effective way to make a decision on the pooling strategy. This paper proposes a mechanistic model, based on the general rate model, to predict elution peak profile for separation of the main product from its variants. The proposed approach uses inverse fit of process scale chromatogram for estimation of model parameters using the initial values that are obtained from theoretical correlations. The packed bed column has been modeled along with the chromatographic system consisting of the mixer, tubing and detectors as a series of dispersed plug flow and continuous stirred tank reactors. The model uses loading ranges starting at 25% to a maximum of 70% of the loading capacity and hence is applicable to process scale separations. Langmuir model has been extended to include the effects of salt concentration and temperature on the model parameters. The extended Langmuir model that has been proposed uses one less parameter than the SMA model and this results in a significant ease of estimating the model parameters from inverse fitting. The proposed model has been validated with experimental data and has been shown to successfully predict peak profile for a range of load capacities (15-28mg/mL), gradient lengths (10-30CV), bed heights (6-20cm), and for three different resins with good accuracy (as measured by estimation of residuals). The model has been also
Institute of Scientific and Technical Information of China (English)
WANG Cui; ZHANG Xue-qing; SUN Ying-lan
2009-01-01
Based on theory of three-dimensional hydrodynamics,an Euler-Lagrangian particle model is established to study the transport and water exchange capability in the Jiaozhou Bay.The three-dimensional hydrodynamic model,driven by tide and wind,is used to study the effects of wetting and drying of eatuarine intertidal flats by the dry-wet grid technology based on the Estuarine,Coastal and Ocean Model (ECOM).The particle model includes the advection and the diffusion processes,of which the advection process is simulated with a certain method,and the diffusion process is simulated with the random walk method.The effect of the intertidal zone,the turbulent diffusion and the timescales of the water exchange are also discussed.The results show that a moving boundary model can simulate the transport process of the particle in the intertidal zone,where the particles are transported for a longer distance than that of the stationary result.Simulations with and without the turbulent random walk show that the effect of turbulent diffusion is very effective at spreading particles throughout the estuary and speeding up the particle movement.The spatial distribution of residence time is given to quantify the water exchange capability that has very important ramifications to water quality.The effect of wind on the water exchange is also examined and the southeasterly wind in summer tends to block the water exchange near the northeast coast,while the northerly wind in winter speeds up the transport process.These results indicate that the Lagrangian particle model is applicable and has a large potential to help understanding the water exchange capability in estuaries,which can also he useful to simulate the transport process of contaminant.
Ushakova, Sofya; Tikhomirov, Alexander A.; Velichko, Vladimir; Tikhomirova, Natalia; Trifonov, Sergey V.
2016-07-01
Mass exchange processes in the new experimental model of the biotechnical life support system (BTLSS) constructed at the Institute of Biophysics SB RAS have a higher degree of closure than in the previous BTLSS, and, thus, the technologies employed in the new system are more complex. Therefore, before closing the loops of mass exchange processes for several months, the new model of the BTLSS was run to match the technologies employed to cultivate plants and the methods used to involve inedible plant parts and human wastes into the mass exchange with the CO2 absorption rate and the amount of the resulting O2. The plant compartment included vegetables grown on the soil-like substrate (SLS) (chufa, beet, carrot, radish, and lettuce), plants hydroponically grown on expanded clay aggregate (wheat, soybean, watercress), and plants grown in aquaculture (common glasswort and watercress). Nutrient solutions for hydroponically grown plants were prepared by using products of physicochemical mineralization of human wastes. Growing the plants in aquaculture enabled maintaining NaCl concentration in the irrigation solution for hydroponically grown plants at a level safe for the plants. Inedible plant biomass was added to the SLS. Three cycles of closing the system were run, which lasted 7, 7, and 10 days. The comparison of the amount of CO2 fed into the system over 24 h (simulating human respiration) and the amount of CO2 daily exhaled by a 70-kg middle-aged human showed that between 1% and 4% of the daily emissions of CO2 were assimilated in the system, and about 3% of the average human daily O2 requirement accumulated in the system. Plant productivity was between 4 and 4.7% of the human daily vegetable requirement, or between 3 and 3.5% of the total human daily food requirement. Thus, testing of the BTLSS showed a match between the technologies employed to arrange mass exchange processes. This study was supported by the grant of the Russian Science Foundation (Project No. 14-14-00599).
Directory of Open Access Journals (Sweden)
V. MADERICH
2015-07-01
Full Text Available A chain of simple linked models is used to simulate the seasonal and interannual variability of the Turkish Straits System. This chain includes two-layer hydraulic models of the Bosphorus and Dardanelles straits simulating the exchange in terms of level and density difference along each strait, and a one-dimensional area averaged layered model of the Marmara Sea. The chain of models is complemented also by the similar layered model of the Black Sea proper and by a one-layer Azov Sea model with the Kerch Strait. This linked chain of models is used to study the seasonal and interannual variability of the system in the period 1970-2009. The salinity of the Black Sea water flowing into the Aegean Sea increases by approximately 1.7 times through entrainment from the lower layer. The flow entering into the lower layer of the Dardanelles Strait from the Aegean Sea is reduced by nearly 80% when it reaches the Black Sea. In the seasonal scale, a maximal transport in the upper layer and minimal transport in the bottom layer are during winter/spring for the Bosphorus and in spring for the Dardanelles Strait, whereas minimal transport in upper layer and maximal undercurrent are during the summer for the Bosphorus Strait and autumn for the Dardanelles Strait. The increase of freshwater flux into the Black Sea in interannual time scales (41 m3s-1 per year is accompanied by a more than twofold growth of the Dardanelles outflow to the North Aegean (102 m3s-1 per year.
Exchange frequency in replica exchange molecular dynamics
Sindhikara, Daniel; Meng, Yilin; Roitberg, Adrian E.
2008-01-01
The effect of the exchange-attempt frequency on sampling efficiency is studied in replica exchange molecular dynamics (REMD). We show that sampling efficiency increases with increasing exchange-attempt frequency. This conclusion is contrary to a commonly expressed view in REMD. Five peptides (1-21 residues long) are studied with a spectrum of exchange-attempt rates. Convergence rates are gauged by comparing ensemble properties between fixed length test REMD simulations and longer reference simulations. To show the fundamental correlation between exchange frequency and convergence time, a simple model is designed and studied, displaying the same basic behavior of much more complex systems.
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Hernandez Rodriguez, Oscar M.; Pecora, Arai A.B. [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Engenharia Termica e de Fluidos]. E-mail: oscarmh@fem.unicamp.br
1999-07-01
This work presents a simplified mathematical model of a shallow fluidized bed heat exchanger with immersed tubes. The thermal performance of the equipment is obtained for a counter flow heat exchanger with water flowing inside the tubes and the solid-gas suspension outside them. The fluidized bed is divided in stages along the longitudinal direction where the heat and mass balances among the three currents involved (sand particles, air and water) are considered. The predicted model temperature profile along the length of the equipment present good agreement with experimental data with a maximum deviation of 25%. (author)
Li, Shuai; Wang, Yiping; Wang, Tao; Yang, Xue; Deng, Yadong; Su, Chuqi
2016-11-01
Thermoelectric generators (TEGs) have become a topic of interest for vehicle exhaust energy recovery. Electrical power generation is deeply influenced by temperature differences, temperature uniformity and topological structures of TEGs. When the dimpled surfaces are adopted in heat exchangers, the heat transfer rates can be augmented with a minimal pressure drop. However, the temperature distribution shows a large gradient along the flow direction which has adverse effects on the power generation. In the current study, the heat exchanger performance was studied in a computational fluid dynamics (CFD) model. The dimple depth, dimple print diameter, and channel height were chosen as design variables. The objective function was defined as a combination of average temperature, temperature uniformity and pressure loss. The optimal Latin hypercube method was used to determine the experiment points as a method of design of the experiment in order to analyze the sensitivity of the design variables. A Kriging surrogate model was built and verified according to the database resulting from the CFD simulation. A multi-island genetic algorithm was used to optimize the structure in the heat exchanger based on the surrogate model. The results showed that the average temperature of the heat exchanger was most sensitive to the dimple depth. The pressure loss and temperature uniformity were most sensitive to the parameter of channel rear height, h 2. With an optimal design of channel structure, the temperature uniformity can be greatly improved compared with the initial exchanger, and the additional pressure loss also increased.
Zelano, I O; Sivry, Y; Quantin, C; Gélabert, A; Maury, A; Phalyvong, K; Benedetti, M F
2016-12-06
In this study an innovative approach is proposed to predict the relative contribution of each mineral phase to the total metal availability in soils, which, in other words, could be called the available metal fractionation. Through the use of isotopic exchange kinetics (IEK) performed on typical Ni bearing phases (i.e., two types of serpentines, chlorite, smectite, goethite, and hematite) the isotopic exchange and metal-solid interaction processes are connected, considering both the thermodynamic and kinetic aspects. Results of Ni IEK experiments on mineral phases are fitted with a pseudo-first order kinetic model. For each Ni bearing phase, this allows to (i) determine the number and size of exchangeable pools (ENi(i)), (ii) assess their corresponding kinetic constants (k(i)), and (iii) discuss the mechanism of Ni isotopic exchange at mineral surfaces. It is shown that all the phases investigated, with the only exception of hematite, present at least two distinct reactive pools with significantly different k(i) values. Results suggest also that metal involved in outer-sphere complexes would display isotopic exchange between 100 and 1000 times faster than metal involved in inner-sphere complexes, and that the presence of high and low affinity sites may influence the rate of isotopic exchange up to 1 order of magnitude. Moreover, the method developed represents a tool to predict and estimate Ni mobility and availability in natural soil samples on the basis of soil mineral composition, providing information barely obtained with other techniques.
The Prediction of Exchange Rates with the Use of Auto-Regressive Integrated Moving-Average Models
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Daniela Spiesová
2014-10-01
Full Text Available Currency market is recently the largest world market during the existence of which there have been many theories regarding the prediction of the development of exchange rates based on macroeconomic, microeconomic, statistic and other models. The aim of this paper is to identify the adequate model for the prediction of non-stationary time series of exchange rates and then use this model to predict the trend of the development of European currencies against Euro. The uniqueness of this paper is in the fact that there are many expert studies dealing with the prediction of the currency pairs rates of the American dollar with other currency but there is only a limited number of scientific studies concerned with the long-term prediction of European currencies with the help of the integrated ARMA models even though the development of exchange rates has a crucial impact on all levels of economy and its prediction is an important indicator for individual countries, banks, companies and businessmen as well as for investors. The results of this study confirm that to predict the conditional variance and then to estimate the future values of exchange rates, it is adequate to use the ARIMA (1,1,1 model without constant, or ARIMA [(1,7,1,(1,7] model, where in the long-term, the square root of the conditional variance inclines towards stable value.
Directory of Open Access Journals (Sweden)
E. Lokupitiya
2009-06-01
Full Text Available Croplands are man-made ecosystems that have high net primary productivity during the growing season of crops, thus impacting carbon and other exchanges with the atmosphere. These exchanges play a major role in nutrient cycling and climate change related issues. An accurate representation of crop phenology and physiology is important in land-atmosphere carbon models being used to predict these exchanges. To better estimate time-varying exchanges of carbon, water, and energy of croplands using the Simple Biosphere (SiB model, we developed crop-specific phenology models and coupled them to SiB. The coupled SiB-phenology model (SiBcrop replaces remotely-sensed NDVI information, on which SiB originally relied for deriving Leaf Area Index (LAI and the fraction of Photosynthetically Active Radiation (fPAR for estimating carbon dynamics. The use of the new phenology scheme within SiB substantially improved the prediction of LAI and carbon fluxes for maize, soybean, and wheat crops, as compared with the observed data at several AmeriFlux eddy covariance flux tower sites in the US mid continent region. SiBcrop better predicted the onset and end of the growing season, harvest, interannual variability associated with crop rotation, day time carbon uptake (especially for maize and day to day variability in carbon exchange. Biomass predicted by SiBcrop had good agreement with the observed biomass at field sites. In the future, we will predict fine resolution regional scale carbon and other exchanges by coupling SiBcrop with RAMS (the Regional Atmospheric Modeling System.
Wu, Zhiliang; Wang, Shuxin; Zhang, Lianhong; Hu, S. Jack
This paper presents an analytical model of the electrical contact resistance between the carbon paper gas diffusion layers (GDLs) and the graphite bipolar plates (BPPs) in a proton exchange membrane (PEM) fuel cell. The model is developed based on the classical statistical contact theory for a PEM fuel cell, using the same probability distributions of the GDL structure and BPP surface profile as previously described in Wu et al. [Z. Wu, Y. Zhou, G. Lin, S. Wang, S.J. Hu, J. Power Sources 182 (2008) 265-269] and Zhou et al. [Y. Zhou, G. Lin, A.J. Shih, S.J. Hu, J. Power Sources 163 (2007) 777-783]. Results show that estimates of the contact resistance compare favorably with experimental data by Zhou et al. [Y. Zhou, G. Lin, A.J. Shih, S.J. Hu, J. Power Sources 163 (2007) 777-783]. Factors affecting the contact behavior are systematically studied using the analytical model, including the material properties of the two contact bodies and factors arising from the manufacturing processes. The transverse Young's modulus of chopped carbon fibers in the GDL and the surface profile of the BPP are found to be significant to the contact resistance. The factor study also sheds light on the manufacturing requirements of carbon fiber GDLs for a better contact performance in PEM fuel cells.
Energy Technology Data Exchange (ETDEWEB)
Wu, Zhiliang; Wang, Shuxin; Zhang, Lianhong [School of Mechanical Engineering, Tianjin University, Tianjin 300072 (China); Hu, S. Jack [Department of Mechanical Engineering, The University of Michigan, Ann Arbor, MI 48109-2125 (United States)
2009-04-15
This paper presents an analytical model of the electrical contact resistance between the carbon paper gas diffusion layers (GDLs) and the graphite bipolar plates (BPPs) in a proton exchange membrane (PEM) fuel cell. The model is developed based on the classical statistical contact theory for a PEM fuel cell, using the same probability distributions of the GDL structure and BPP surface profile as previously described in Wu et al. [Z. Wu, Y. Zhou, G. Lin, S. Wang, S.J. Hu, J. Power Sources 182 (2008) 265-269] and Zhou et al. [Y. Zhou, G. Lin, A.J. Shih, S.J. Hu, J. Power Sources 163 (2007) 777-783]. Results show that estimates of the contact resistance compare favorably with experimental data by Zhou et al. [Y. Zhou, G. Lin, A.J. Shih, S.J. Hu, J. Power Sources 163 (2007) 777-783]. Factors affecting the contact behavior are systematically studied using the analytical model, including the material properties of the two contact bodies and factors arising from the manufacturing processes. The transverse Young's modulus of chopped carbon fibers in the GDL and the surface profile of the BPP are found to be significant to the contact resistance. The factor study also sheds light on the manufacturing requirements of carbon fiber GDLs for a better contact performance in PEM fuel cells. (author)
Measuring and modeling air exchange rates inside taxi cabs in Los Angeles, California
Shu, Shi; Yu, Nu; Wang, Yueyan; Zhu, Yifang
2015-12-01
Air exchange rates (AERs) have a direct impact on traffic-related air pollutant (TRAP) levels inside vehicles. Taxi drivers are occupationally exposed to TRAP on a daily basis, yet there is limited measurement of AERs in taxi cabs. To fill this gap, AERs were quantified in 22 representative Los Angeles taxi cabs including 10 Prius, 5 Crown Victoria, 3 Camry, 3 Caravan, and 1 Uplander under realistic driving (RD) conditions. To further study the impacts of window position and ventilation settings on taxi AERs, additional tests were conducted on 14 taxis with windows closed (WC) and on the other 8 taxis with not only windows closed but also medium fan speed (WC-MFS) under outdoor air mode. Under RD conditions, the AERs in all 22 cabs had a mean of 63 h-1 with a median of 38 h-1. Similar AERs were observed under WC condition when compared to those measured under RD condition. Under WC-MFS condition, AERs were significantly increased in all taxi cabs, when compared with those measured under RD condition. A General Estimating Equation (GEE) model was developed and the modeling results showed that vehicle model was a significant factor in determining the AERs in taxi cabs under RD condition. Driving speed and car age were positively associated with AERs but not statistically significant. Overall, AERs measured in taxi cabs were much higher than typical AERs people usually encounter in indoor environments such as homes, offices, and even regular passenger vehicles.
Fast Realistic MRI Simulations Based on Generalized Multi-Pool Exchange Tissue Model.
Liu, Fang; Velikina, Julia V; Block, Walter F; Kijowski, Richard; Samsonov, Alexey A
2017-02-01
We present MRiLab, a new comprehensive simulator for large-scale realistic MRI simulations on a regular PC equipped with a modern graphical processing unit (GPU). MRiLab combines realistic tissue modeling with numerical virtualization of an MRI system and scanning experiment to enable assessment of a broad range of MRI approaches including advanced quantitative MRI methods inferring microstructure on a sub-voxel level. A flexible representation of tissue microstructure is achieved in MRiLab by employing the generalized tissue model with multiple exchanging water and macromolecular proton pools rather than a system of independent proton isochromats typically used in previous simulators. The computational power needed for simulation of the biologically relevant tissue models in large 3D objects is gained using parallelized execution on GPU. Three simulated and one actual MRI experiments were performed to demonstrate the ability of the new simulator to accommodate a wide variety of voxel composition scenarios and demonstrate detrimental effects of simplified treatment of tissue micro-organization adapted in previous simulators. GPU execution allowed ∼ 200× improvement in computational speed over standard CPU. As a cross-platform, open-source, extensible environment for customizing virtual MRI experiments, MRiLab streamlines the development of new MRI methods, especially those aiming to infer quantitatively tissue composition and microstructure.
Estimation of Bid Curves in Power Exchanges using Time-varying Simultaneous-Equations Models
Ofuji, Kenta; Yamaguchi, Nobuyuki
Simultaneous-equations model (SEM) is generally used in economics to estimate interdependent endogenous variables such as price and quantity in a competitive, equilibrium market. In this paper, we have attempted to apply SEM to JEPX (Japan Electric Power eXchange) spot market, a single-price auction market, using the publicly available data of selling and buying bid volumes, system price and traded quantity. The aim of this analysis is to understand the magnitude of influences to the auctioned prices and quantity from the selling and buying bids, than to forecast prices and quantity for risk management purposes. In comparison with the Ordinary Least Squares (OLS) estimation where the estimation results represent average values that are independent of time, we employ a time-varying simultaneous-equations model (TV-SEM) to capture structural changes inherent in those influences, using State Space models with Kalman filter stepwise estimation. The results showed that the buying bid volumes has that highest magnitude of influences among the factors considered, exhibiting time-dependent changes, ranging as broad as about 240% of its average. The slope of the supply curve also varies across time, implying the elastic property of the supply commodity, while the demand curve remains comparatively inelastic and stable over time.
Replica-exchange Wang-Landau simulations of the H0P model of protein folding
Shi, Guangjie; Landau, David P.; Wüst, Thomas; Li, Ying Wai Li
2015-03-01
The hydrophobic-polar (HP) model has served as a coarse-grained lattice protein folding model attracting scientists from various disciplines. However, simplification into H and P monomers may yield high ground state degeneracies which stands in contrast to the generally unique native states of natural proteins. We propose a simple modification, by introducing a new type of ``neutral'' monomer, 0, i.e. neither hydrophobic nor polar, rendering the model more realistic without increasing the difficulties of sampling significantly. With the newly developed parallel Wang-Landau (replica exchange Wang-Landau) scheme and an innovative method of estimating the ground state degeneracies, we investigated some widely studied HP proteins and their H0P counterparts. Dramatic differences in ground state and thermodynamic properties have been observed, e.g. the estimation of ground state degeneracy for the 46mer is 460,000 for the HP version and only 20 for the H0P mapping. Similarly, the specific heat and structural properties: radius of gyration and etc. show more pronounced signals associated with folding. Supported by NSF.
Solar wind charge exchange X-ray emission from Mars Model and data comparison
Koutroumpa, Dimitra; Chanteur, Gerard; Chaufray, Jean-Yves; Kharchenko, Vasili; Lallement, Rosine
2012-01-01
Aims. We study the soft X-ray emission induced by charge exchange (CX) collisions between solar-wind, highly charged ions and neutral atoms of the Martian exosphere. Methods. A 3D multi species hybrid simulation model with improved spatial resolution (130 km) is used to describe the interaction between the solar wind and the Martian neutrals. We calculated velocity and density distributions of the solar wind plasma in the Martian environment with realistic planetary ions description, using spherically symmetric exospheric H and O profiles. Following that, a 3D test-particle model was developed to compute the X-ray emission produced by CX collisions between neutrals and solar wind minor ions. The model results are compared to XMM-Newton observations of Mars. Results. We calculate projected X-ray emission maps for the XMM-Newton observing conditions and demonstrate how the X-ray emission reflects the Martian electromagnetic structure in accordance with the observed X-ray images. Our maps confirm that X-ray imag...
Forecasting Exchange Rate Density Using Parametric Models: the Case of Brazil
Directory of Open Access Journals (Sweden)
Benjamin Miranda Tabak
2007-06-01
Full Text Available This paper employs a recently developed parametric technique to obtain density forecasts for the Brazilian exchange rate, using the exchange rate options market. Empirical results suggest that the option market contains useful information about future exchange rate density. These results suggests that density forecasts using options markets may add value for portfolio and risk management, and may be useful for financial regulators to assess financial stability.
International Organization for Standardization. Geneva
2003-01-01
Information technology - Telecommunications and information exchange between systems - Private integrated services network - Specification, functional model and information flows - Call interception additional network feature
International Organization for Standardization. Geneva
2003-01-01
Information technology - Telecommunications and information exchange between systems - Private integrated services network - Specification, functional model and information flows - Call priority interruption and call priority interruption protection supplementary services
International Organization for Standardization. Geneva
2003-01-01
Information technology - Telecommunications and information exchange between systems - Private Integrated Services Network - Specification, functional model and information flows - Call transfer supplementary service
International Organization for Standardization. Geneva
2003-01-01
Information technology - Telecommunications and information exchange between systems - Private integrated services network - Specification, functional model and information flows - Recall supplementary service
Unfolding of a model protein on ion exchange and mixed mode chromatography surfaces.
Gospodarek, Adrian M; Hiser, Diana E; O'Connell, John P; Fernandez, Erik J
2014-08-15
Recent studies with proteins indicate that conformational changes and aggregation can occur during ion exchange chromatography (IEC). Such behavior is not usually expected, but could lead to decreased yield and product degradation from both IEC and multi mode chromatography (MMC) that has ligands of both hydrophobic and charged functionalities. In this study, we used hydrogen exchange mass spectrometry to investigate unfolding of the model protein BSA on IEC and MMC surfaces under different solution conditions at 25°C. Increased solvent exposure, indicating greater unfolding relative to that in solution, was found for protein adsorbed on cationic IEC and MMC surfaces in the pH range of 3.0 to 4.5, where BSA has decreased stability in solution. There was no effect of anionic surfaces at pH values in the range from 6.0 to 9.0. Differences of solvent exposure of whole molecules when adsorbed and in solution suggest that adsorbed BSA unfolds at lower pH values and may show aggregation, depending upon pH and the surface type. Measurements on digested peptides showed that classifications of stability can be made for various regions; these are generally retained as pH is changed. When salt was added to MMC systems, where electrostatic interactions would be minimized, less solvent exposure was seen, implying that it is the cationic moieties, rather than the hydrophobic ligands, which cause greater surface unfolding at low salt concentrations. These results suggest that proteins of lower stability may exhibit unfolding and aggregation during IEC and MMC separations, as they can with hydrophobic interaction chromatography.
Hyperon interaction in free space and nuclear matter within a SU(3) based meson exchange model
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Dhar, Madhumita
2016-06-15
To establish the connection between free space and in-medium hyperon-nucleon interactions is the central issue of this thesis. The guiding principle is flavor SU(3) symmetry which is exploited at various levels. In first step hyperon-nucleon and hyperon- hyperon interaction boson exchange potential in free space are introduced. A new parameter set applicable for the complete baryon octet has been derived leading to an updated one-boson- exchange model, utilizing SU(3) flavor symmetry, optimizing the number of free parameters involved, and revising the set of mesons included. The scalar, pseudoscalar, and vector SU(3) meson octets are taken into account. T-matrices are calculated by solving numerically coupled linear systems of Lippmann-Schwinger equations obtained from a 3-D reduced Bethe-Salpeter equation. Coupling constants were determined by χ{sup 2} fits to the world set of scattering data. A good description of the few available data is achieved within the imposed SU(3) constraints. Having at hand a consistently derived vacuum interaction we extend the approach next to investigations of the in-medium properties of hyperon interaction, avoiding any further adjustments. Medium effect in infinite nuclear matter are treated microscopically by recalculating T-matrices by an medium-modified system of Lippmann-Schwinger equations. A particular important role is played by the Pauli projector accounting for the exclusion principle. The presence of a background medium induces a weakening of the vacuum interaction amplitudes. Especially coupled channel mixing is found to be affected sensitively by medium. Investigation on scattering lengths and effective range parameters are revealing the density dependence of the interaction on a quantitative level.
Potassium-and silver-double-ion-exchanged slab glass waveguides: characterization and modeling.
Auger, P L; Najafi, S I
1994-06-01
Double-ion-exchanged glass waveguides are made first by a potassium-ion exchange followed by a silver-ion exchange. The inverse WKB method is used to determine the index profile. It is shown that a combination of a truncated quadratic function and a complementary error function represents the refractive index best. A direct WKB method is employed to find the maximum index change and the diffusion coefficient of the second exchange process. The concentration of silver, potassium, and sodium ions are measured by an x-ray photoelectron spectroscopy technique. The results agree well with the index profile when a quadratic function is used.
Nikolov, Ned; Zeller, Karl F
2003-01-01
A new biophysical model (FORFLUX) is presented to study the simultaneous exchange of ozone, carbon dioxide, and water vapor between terrestrial ecosystems and the atmosphere. The model mechanistically couples all major processes controlling ecosystem flows trace gases and water implementing recent concepts in plant eco-physiology, micrometeorology, and soil hydrology. FORFLUX consists of four interconnected modules-a leaf photosynthesis model, a canopy flux model, a soil heat-, water- and CO2- transport model, and a snow pack model. Photosynthesis, water-vapor flux and ozone uptake at the leaf level are computed by the LEAFC3 sub-model. The canopy module scales leaf responses to a stand level by numerical integration of the LEAFC3model over canopy leaf area index (LAI). The integration takes into account (1) radiative transfer inside the canopy, (2) variation of foliage photosynthetic capacity with canopy depth, (3) wind speed attenuation throughout the canopy, and (4) rainfall interception by foliage elements. The soil module uses principles of the diffusion theory to predict temperature and moisture dynamics within the soil column, evaporation, and CO2 efflux from soil. The effect of soil heterogeneity on field-scale fluxes is simulated employing the Bresler-Dagan stochastic concept. The accumulation and melt of snow on the ground is predicted using an explicit energy balance approach. Ozone deposition is modeled as a sum of three fluxes- ozone uptake via plant stomata, deposition to non-transpiring plant surfaces, and ozone flux into the ground. All biophysical interactions are computed hourly while model projections are made at either hourly or daily time step. FORFLUX represents a comprehensive approach to studying ozone deposition and its link to carbon and water cycles in terrestrial ecosystems.
Modeling a Printed Circuit Heat Exchanger with RELAP5-3D for the Next Generation Nuclear Plant
Energy Technology Data Exchange (ETDEWEB)
2010-12-01
The main purpose of this report is to design a printed circuit heat exchanger (PCHE) for the Next Generation Nuclear Plant and carry out Loss of Coolant Accident (LOCA) simulation using RELAP5-3D. Helium was chosen as the coolant in the primary and secondary sides of the heat exchanger. The design of PCHE is critical for the LOCA simulations. For purposes of simplicity, a straight channel configuration was assumed. A parallel intermediate heat exchanger configuration was assumed for the RELAP5 model design. The RELAP5 modeling also required the semicircular channels in the heat exchanger to be mapped to rectangular channels. The initial RELAP5 run outputs steady state conditions which were then compared to the heat exchanger performance theory to ensure accurate design is being simulated. An exponential loss of pressure transient was simulated. This LOCA describes a loss of coolant pressure in the primary side over a 20 second time period. The results for the simulation indicate that heat is initially transferred from the primary loop to the secondary loop, but after the loss of pressure occurs, heat transfers from the secondary loop to the primary loop.
2016-08-26
and Astronomy, University of Leicester, Leicester, UK, 2Finnish Meteorological Institute, Helsinki, Finland Abstract An MHD-based model of terrestrial...check confirms that we should continue the analysis with these new simulations. Figure 9 shows the comparison of these newly calculated model count rates...Journal of Geophysical Research: Space Physics Modeling the magnetospheric X-ray emission from solar wind charge exchange with verification from XMM
von Hagen, Jürgen; Zhou, Jizhong
2008-01-01
We present an analysis of the determinants of de jure and de facto exchange rate regimes based on a panel probit model with simultaneous equations. The model is estimated using simulation-based maximum likelihood methods. The empirical results suggest a triangular structure of the model such that the choice of de facto regimes depends on the choice of de jure regimes but not vice versa. This gives rise to a novel interpretation of regime discrepancies.
A porosity model for flow resistance calculation of heat exchanger with louvered fins
Energy Technology Data Exchange (ETDEWEB)
Kim, Taek Keun [Halla Visteon Climate Control Corp. Daejeon (Korea, Republic of); Kang, Hie Chan [Kunsan National University, Gunsan (Korea, Republic of); Lee, Joon Sik [Seoul National University, Seoul (Korea, Republic of)
2016-04-15
A full 3-dimensional flow simulation of a louvered fin heat exchanger assembly requires a huge number of grid points and enormous computing time. This work proposes a porous media model for the flow resistance calculation of the louvered fin side in order to efficiently simulate a complex 3-dimensional flow over the louvered fins. In the present model, we determine the permeability and Ergun constant in the modified Darcy equation. We first build up a database of the friction factor from the available experimental data and our own CFD data, and then develop the friction factor correlation in the range of the Reynolds number based on the louver pitch from 0.001 to 20000 for 14 different louvered fin types. We use the non-linear and multi-linear regression analyses to obtain the friction factor correlation as a function of louvered fin geometric parameters such as louver pitch, louver angle and fin pitch. The present friction factor correlation shows an excellent agreement with the previous experimental and CFD data. The modified Darcy equation with the proposed permeability and Ergun constant for the louvered fin side can easily be coupled with the 3-dimensional computation of the main tube flow.
Atlantic-Arctic exchange in a series of ocean model simulations (CORE-II)
Roth, Christina; Behrens, Erik; Biastoch, Arne
2014-05-01
In this study we aim to improve the understanding of exchange processes between the North Atlantic and the Arctic Ocean. The Nordic Sea builds an important connector between these regions, by receiving and modifying warm and saline Atlantic waters, and by providing dense overflow as a backbone of the Atlantic Meridional Overturning Circulation (AMOC). Using a hierarchy of global ocean/sea-ice models, the specific role of the Nordic Seas, both providing a feedback with the AMOC, but also as a modulator of the Atlantic water flowing into the Arctic Ocean, is examined. The models have been performed under the CORE-II protocol, in which atmospheric forcing of the past 60 years was applied in a subsequent series of 5 iterations. During the course of this 300-year long integration, the AMOC shows substantial changes, which are correlated with water mass characteristics in the Denmark Strait overflow characteristics. Quantitative analyses using Lagrangian trajectories explore the impact of these trends on the Arctic Ocean through the Barents Sea and the Fram Strait.
Modeling of Air Temperature for Heat Exchange due to Vertical Turbulence and Horizontal Air Flow
Institute of Scientific and Technical Information of China (English)
ZHANG Lei; MENG Qing-lin
2009-01-01
In order to calculate the air temperature of the near surface layer in urban environment,the Sur-face layer air was divided into several layers in the vertical direction,and some energy bakmce equations were de-veloped for each air layer,in which the heat exchange due to vertical turbulence and horizontal air flow was tak-en into account.Then,the vertical temperature distribution of the surface layer air was obtained through the coupled calculation using the energy balance equations of underlying surfaces and building walls.Moreover,the measured air temperatures in a small area (with a horizontal scale of less than 500 m) and a large area (with ahorizontal scale of more than 1000 m) in Guangzhou in summer were used to validate the proposed model.The calculated results agree well with the measured ones,with a maximum relative error of 4.18%.It is thus con-cluded that the proposed model is a high-accuracy method to theoretically analyze the urban heat island and the thermal environment.
Fama and French Three-Factor Model: Evidence from Istanbul Stock Exchange
Directory of Open Access Journals (Sweden)
Veysel Eraslan
2013-04-01
Full Text Available This study tests the validity of the Fama and French three-factor asset pricing model on the Istanbul Stock Exchange (ISE. Monthly excess stock returns over the period from 2003 to 2010 are used in the analysis. Realized returns show that portfolios containing large firms have higher average excess returns than portfolios containing smaller sized firms. Generally, portfolios containing low book-to-market ratio firms perform better than those containing high book-to-market ratio firms. Nine portfolios are constructed according to size and book-to-market ratio of firms in order to explain the variations on excess portfolio returns by using market risk factor, size risk factor and book-to-market ratio risk factors. Size factor has no effect on portfolios having big-size firms but can explain the excess return variations on portfolios having small and medium-sized firms. Book-to-market ratio factor has an effect on portfolios with high book-to-market ratio firms. Fama and French three-factor model has power on explaining variations on excess portfolio returns but this power is not strong throughout the test period on the ISE.
Directory of Open Access Journals (Sweden)
H. W. Ter Maat
2010-08-01
Full Text Available This paper is a case study to investigate what the main controlling factors are that determine atmospheric carbon dioxide content for a region in the centre of The Netherlands. We use the Regional Atmospheric Modelling System (RAMS, coupled with a land surface scheme simulating carbon, heat and momentum fluxes (SWAPS-C, and including also submodels for urban and marine fluxes, which in principle should include the dominant mechanisms and should be able to capture the relevant dynamics of the system. To validate the model, observations are used that were taken during an intensive observational campaign in central Netherlands in summer 2002. These include flux-tower observations and aircraft observations of vertical profiles and spatial fluxes of various variables.
The simulations performed with the coupled regional model (RAMS-SWAPS-C are in good qualitative agreement with the observations. The station validation of the model demonstrates that the incoming shortwave radiation and surface fluxes of water and CO_{2} are well simulated. The comparison against aircraft data shows that the regional meteorology (i.e. wind, temperature is captured well by the model. Comparing spatially explicitly simulated fluxes with aircraft observed fluxes we conclude that in general latent heat fluxes are underestimated by the model compared to the observations but that the latter exhibit large variability within all flights. Sensitivity experiments demonstrate the relevance of the urban emissions of carbon dioxide for the carbon balance in this particular region. The same tests also show the relation between uncertainties in surface fluxes and those in atmospheric concentrations.
Energy Technology Data Exchange (ETDEWEB)
Walker, D.D.
1999-03-15
Non-elutable ion exchange using crystalline silicotitanate is being considered for removing cesium from Savannah River Site radioactive waste. The construction cost of this process depends strongly on the size of the ion exchange column required to meet product specifications.
Review of Air Exchange Rate Models for Air Pollution Exposure Assessments
A critical aspect of air pollution exposure assessments is estimation of the air exchange rate (AER) for various buildings, where people spend their time. The AER, which is rate the exchange of indoor air with outdoor air, is an important determinant for entry of outdoor air pol...
Directory of Open Access Journals (Sweden)
Moo-Yeon Lee
2012-01-01
Full Text Available The objective of this study is to provide the numerical model for prediction of the frost growth of the round plate fin for the purpose of using it as a round plate fin-tube heat exchanger (evaporator under frosting conditions. In this study, numerical model was considering the frost density change with time, and it showed better agreement with experimental data of Sahin (1994 than that of the Kim model (2004 and the Jonse and Parker model (1975. This is because the prediction on the frost height with time was improved by using the frost thermal conductivity reflecting the void fraction and density of ice crystal with frost growth. Therefore, the developed numerical model could be used for frosting performance prediction of the round plate fin-tube heat exchanger.
Guélat, Bertrand; Ströhlein, Guido; Lattuada, Marco; Morbidelli, Massimo
2010-08-27
A model for the adsorption equilibrium of proteins in ion-exchange chromatography explicitly accounting for the effect of pH and salt concentration in the limit of highly diluted systems was developed. It is based on the use of DLVO theory to estimate the electrostatic interactions between the charged surface of the ion-exchanger and the proteins. The corresponding charge distributions were evaluated as a function of pH and salt concentration using a molecular approach. The model was verified for the adsorption equilibrium of lysozyme, chymotrypsinogen A and four industrial monoclonal antibodies on two strong cation-exchangers. The adsorption equilibrium constants of these proteins were determined experimentally at various pH values and salt concentrations and the model was fitted with a good agreement using three adjustable parameters for each protein in the whole range of experimental conditions. Despite the simplifications of the model regarding the geometry of the protein-ion-exchanger system, the physical meaning of the parameters was retained.
Chun-Tai. Lai; G. Katul; J. Butnor; M. Siqueira; D. Ellsworth; C. Maier; Kurt Johnsen; S. Mickeand; R. Oren
2002-01-01
Using a combination of model simulations and detailed measurements at a hierarchy of scales conducted at a sandhills forest site, the effect of fertilization on net ecosystem exchange (NEE) and its components in 6-year-old Pinus taeda stands was quantified. The detailed measurements, collected over a 20-d period in September and October, included gas...
Killing scalar of non-linear σ-model on G/H realizing the classical exchange algebra
Energy Technology Data Exchange (ETDEWEB)
Aoyama, Shogo, E-mail: spsaoya@ipc.shizuoka.ac.jp
2014-10-07
The Poisson brackets for non-linear σ-models on G/H are set up on the light-like plane. A quantity which transforms irreducibly by the Killing vectors, called Killing scalar, is constructed in an arbitrary representation of G. It is shown to satisfy the classical exchange algebra.
Hu, Guilin; Fan, Jianren
The proton exchange membrane fuel cell (PEMFC) has become a promising candidate for the power source of electrical vehicles because of its low pollution, low noise and especially fast startup and transient responses at low temperatures. A transient, three-dimensional, non-isothermal and single-phase mathematical model based on computation fluid dynamics has been developed to describe the transient process and the dynamic characteristics of a PEMFC with a serpentine fluid channel. The effects of water phase change and heat transfer, as well as electrochemical kinetics and multicomponent transport on the cell performance are taken into account simultaneously in this comprehensive model. The developed model was employed to simulate a single laboratory-scale PEMFC with an electrode area about 20 cm 2. The dynamic behavior of the characteristic parameters such as reactant concentration, pressure loss, temperature on the membrane surface of cathode side and current density during start-up process were computed and are discussed in detail. Furthermore, transient responses of the fuel cell characteristics during step changes and sinusoidal changes in the stoichiometric flow ratio of the cathode inlet stream, cathode inlet stream humidity and cell voltage are also studied and analyzed and interesting undershoot/overshoot behavior of some variables was found. It was also found that the startup and transient response time of a PEM fuel cell is of the order of a second, which is similar to the simulation results predicted by most models. The result is an important guide for the optimization of PEMFC designs and dynamic operation.
A Distributed Model of Oilseed Biorefining, via Integrated Industrial Ecology Exchanges
Ferrell, Jeremy C.
As the demand for direct petroleum substitutes increases, biorefineries are poised to become centers for conversion of biomass into fuels, energy, and biomaterials. A distributed model offers reduced transportation, tailored process technology to available feedstock, and increased local resilience. Oilseeds are capable of producing a wide variety of useful products additive to food, feed, and fuel needs. Biodiesel manufacturing technology lends itself to smaller-scale distributed facilities able to process diverse feedstocks and meet demand of critical diesel fuel for basic municipal services, safety, sanitation, infrastructure repair, and food production. Integrating biodiesel refining facilities as tenants of eco-industrial parks presents a novel approach for synergistic energy and material exchanges whereby environmental and economic metrics can be significantly improved upon compared to stand alone models. This research is based on the Catawba County NC EcoComplex and the oilseed crushing and biodiesel processing facilities (capacity-433 tons biodiesel per year) located within. Technical and environmental analyses of the biorefinery components as well as agronomic and economic models are presented. The life cycle assessment for the two optimal biodiesel feedstocks, soybeans and used cooking oil, resulted in fossil energy ratios of 7.19 and 12.1 with carbon intensity values of 12.51 gCO2-eq/MJ and 7.93 gCO2-eq/MJ, respectively within the industrial ecology system. Economic modeling resulted in a biodiesel conversion cost of 1.43 per liter of fuel produced with used cooking oil, requiring a subsidy of 0.58 per liter to reach the break-even point. As subsidies continue significant fluctuation, metrics other than operating costs are required to justify small-scale biofuel projects.
Modelling of Split Condenser Heat Pump with Limited Set of Plate Heat Exchanger Dimensions
DEFF Research Database (Denmark)
Christensen, Stefan Wuust; Elmegaard, Brian; Markussen, Wiebke Brix
2017-01-01
This paper presents a numerical study of optimal plate dimensions in a split condenser heat pump (SCHP), using ammonia as refrigerant. The SCHP setup differs from a traditional heat pump (THP) setup in the way that two separate water streams on the secondary side of the condenser are heated...... in parallel to different temperature levels, whereas only one stream is heated in a THP. The length/width ratio of the plate heat exchangers on the high pressure side of a SCHP was investigated to find the optimal plate dimensions with respect to minimum area of the heat exchangers. The total heat exchanger...... area was found to decrease with an increasing length/width ratio of the plates. The marginal change in heat exchanger area was shown to be less significant for heat exchangers with high length/width ratios. In practice only a limited number of plate dimensions are available and feasible...
Bernard-Jannin, Léonard; Brito, David; Sun, Xiaoling; Jauch, Eduardo; Neves, Ramiro; Sauvage, Sabine; Sánchez-Pérez, José-Miguel
2016-08-01
Exchanges between surface water (SW) and groundwater (GW) are of considerable importance to floodplain ecosystems and biogeochemical cycles. Flood events in particular are important for riparian water budget and element exchanges and processing. However SW-GW exchanges present complex spatial and temporal patterns and modelling can provide useful knowledge about the processes involved at the scale of the reach and its adjacent floodplain. This study used a physically-based, spatially-distributed modelling approach for studying SW-GW exchanges. The modelling in this study is based on the MOHID Land model, combining the modelling of surface water flow in 2D with the Saint-Venant equation and the modelling of unsaturated groundwater flow in 3D with the Richards' equation. Overbank flow during floods was also integrated, as well as water exchanges between the two domains across the entire floodplain. Conservative transport simulations were also performed to study and validate the simulation of the mixing between surface water and groundwater. The model was applied to the well-monitored study site of Monbéqui (6.6 km²) in the Garonne floodplain (south-west France) for a five-month period and was able to represent the hydrology of the study area. Infiltration (SW to GW) and exfiltration (SW to GW) were characterised over the five-month period. Results showed that infiltration and exfiltration exhibited strong spatiotemporal variations, and infiltration from overbank flow accounted for 88% of the total simulated infiltration, corresponding to large flood periods. The results confirmed that overbank flood events played a determinant role in floodplain water budget and SW-GW exchanges compared to smaller (below bankfull) flood events. The impact of floods on water budget appeared to be similar for flood events exceeding a threshold corresponding to the five-year return period event due to the study area's topography. Simulation of overbank flow during flood events was an
Directory of Open Access Journals (Sweden)
G. M. Wolfe
2011-02-01
Full Text Available In a companion paper, we introduced the Chemistry of Atmosphere-Forest Exchange (CAFE model, a vertically-resolved 1-D chemical transport model designed to probe the details of near-surface reactive gas exchange. Here, we apply CAFE to noontime observations from the 2007 Biosphere Effects on Aerosols and Photochemistry Experiment (BEARPEX-2007. In this work we evaluate the CAFE modeling approach, demonstrate the significance of in-canopy chemistry for forest-atmosphere exchange and identify key shortcomings in the current understanding of intra-canopy processes.
CAFE generally reproduces BEARPEX-2007 observations but requires an enhanced radical recycling mechanism to overcome a factor of 6 underestimate of hydroxyl (OH concentrations observed during a warm (~29 °C period. Modeled fluxes of acyl peroxy nitrates (APN are quite sensitive to gradients in chemical production and loss, demonstrating that chemistry may perturb forest-atmosphere exchange even when the chemical timescale is long relative to the canopy mixing timescale. The model underestimates peroxy acetyl nitrate (PAN fluxes by 50% and the exchange velocity by nearly a factor of three under warmer conditions, suggesting that near-surface APN sinks are underestimated relative to the sources. Nitric acid typically dominates gross dry N deposition at this site, though other reactive nitrogen (NO_{y} species can comprise up to 28% of the N deposition budget under cooler conditions. Upward NO_{2} fluxes cause the net above-canopy NO_{y} flux to be ~30% lower than the gross depositional flux. CAFE under-predicts ozone fluxes and exchange velocities by ~20%. Large uncertainty in the parameterization of cuticular and ground deposition precludes conclusive attribution of non-stomatal fluxes to chemistry or surface uptake. Model-measurement comparisons of vertical concentration gradients for several emitted species suggests that the lower canopy airspace may be
Mechanisms underlying gas exchange alterations in an experimental model of pulmonary embolism
Directory of Open Access Journals (Sweden)
J.H.T. Ferreira
2006-09-01
Full Text Available The aim of the present study was to determine the ventilation/perfusion ratio that contributes to hypoxemia in pulmonary embolism by analyzing blood gases and volumetric capnography in a model of experimental acute pulmonary embolism. Pulmonary embolization with autologous blood clots was induced in seven pigs weighing 24.00 ± 0.6 kg, anesthetized and mechanically ventilated. Significant changes occurred from baseline to 20 min after embolization, such as reduction in oxygen partial pressures in arterial blood (from 87.71 ± 8.64 to 39.14 ± 6.77 mmHg and alveolar air (from 92.97 ± 2.14 to 63.91 ± 8.27 mmHg. The effective alveolar ventilation exhibited a significant reduction (from 199.62 ± 42.01 to 84.34 ± 44.13 consistent with the fall in alveolar gas volume that effectively participated in gas exchange. The relation between the alveolar ventilation that effectively participated in gas exchange and cardiac output (V Aeff/Q ratio also presented a significant reduction after embolization (from 0.96 ± 0.34 to 0.33 ± 0.17 fraction. The carbon dioxide partial pressure increased significantly in arterial blood (from 37.51 ± 1.71 to 60.76 ± 6.62 mmHg, but decreased significantly in exhaled air at the end of the respiratory cycle (from 35.57 ± 1.22 to 23.15 ± 8.24 mmHg. Exhaled air at the end of the respiratory cycle returned to baseline values 40 min after embolism. The arterial to alveolar carbon dioxide gradient increased significantly (from 1.94 ± 1.36 to 37.61 ± 12.79 mmHg, as also did the calculated alveolar (from 56.38 ± 22.47 to 178.09 ± 37.46 mL and physiological (from 0.37 ± 0.05 to 0.75 ± 0.10 fraction dead spaces. Based on our data, we conclude that the severe arterial hypoxemia observed in this experimental model may be attributed to the reduction of the V Aeff/Q ratio. We were also able to demonstrate that V Aeff/Q progressively improves after embolization, a fact attributed to the alveolar ventilation redistribution
Central Production of Eta and Eta-prime via Double Pomeron Exchange in the Sakai-Sugimoto Model
Anderson, Neil; Harvey, Jeffrey A; Mann, Nelia
2014-01-01
We construct a string-inspired model for the central production of $\\eta$ and $\\eta'$ mesons in proton-proton collisions, via double Pomeron exchange. Using general symmetry considerations, we construct a low-energy differential cross section for double glueball exchange in terms of some undetermined coupling constants and form factors. We extend this model to the Regge regime, replacing the glueball propagators with Pomeron trajectories, and modifying the interaction term by a factor derived from the 5-string scattering amplitude in flat space. We then fix the couplings which remain undetermined, using the Sakai-Sugimoto framework to model low-energy QCD. Finally, we generate a simulation of the scattering process at $\\sqrt{s} = 29.1 GeV$, where double Pomeron exchange should play a role (secondary to double Reggeon exchange). We focus on the dependence of the scattering cross section on the angle between the scattered protons in the transverse plane. The results exhibit a definite deviation from the angular...
A Mass Computation Model for Lightweight Brayton Cycle Regenerator Heat Exchangers
Juhasz, Albert J.
2010-01-01
Based on a theoretical analysis of convective heat transfer across large internal surface areas, this paper discusses the design implications for generating lightweight gas-gas heat exchanger designs by packaging such areas into compact three-dimensional shapes. Allowances are made for hot and cold inlet and outlet headers for assembly of completed regenerator (or recuperator) heat exchanger units into closed cycle gas turbine flow ducting. Surface area and resulting volume and mass requirements are computed for a range of heat exchanger effectiveness values and internal heat transfer coefficients. Benefit cost curves show the effect of increasing heat exchanger effectiveness on Brayton cycle thermodynamic efficiency on the plus side, while also illustrating the cost in heat exchanger required surface area, volume, and mass requirements as effectiveness is increased. The equations derived for counterflow and crossflow configurations show that as effectiveness values approach unity, or 100 percent, the required surface area, and hence heat exchanger volume and mass tend toward infinity, since the implication is that heat is transferred at a zero temperature difference. To verify the dimensional accuracy of the regenerator mass computational procedure, calculation of a regenerator specific mass, that is, heat exchanger weight per unit working fluid mass flow, is performed in both English and SI units. Identical numerical values for the specific mass parameter, whether expressed in lb/(lb/sec) or kg/ (kg/sec), show the dimensional consistency of overall results.
Eilola, Kari; Rosell, Elin Almroth; Dieterich, Christian; Fransner, Filippa; Höglund, Anders; Meier, H E Markus
2012-09-01
We quantified horizontal transport patterns and the net exchange of nutrients between shallow regions and the open sea in the Baltic proper. A coupled biogeochemical-physical circulation model was used for transient simulations 1961-2100. The model was driven by regional downscaling of the IPCC climate change scenario A1B from two global General Circulation Models in combination with two nutrient load scenarios. Modeled nutrient transports followed mainly the large-scale internal water circulation and showed only small circulation changes in the future projections. The internal nutrient cycling and exchanges between shallow and deeper waters became intensified, and the internal removal of phosphorus became weaker in the warmer future climate. These effects counteracted the impact from nutrient load reductions according to the Baltic Sea Action Plan. The net effect of climate change and nutrient reductions was an increased net import of dissolved inorganic phosphorus to shallow areas in the Baltic proper.
Modeling and Validation of Sodium Plugging for Heat Exchangers in Sodium-cooled Fast Reactor Systems
Energy Technology Data Exchange (ETDEWEB)
Ferroni, Paolo [Westinghouse Electric Company LLC, Cranberry Township, PA (United States). Global Technology Development; Tatli, Emre [Westinghouse Electric Company LLC, Cranberry Township, PA (United States); Czerniak, Luke [Westinghouse Electric Company LLC, Cranberry Township, PA (United States); Sienicki, James J. [Argonne National Lab. (ANL), Argonne, IL (United States); Chien, Hual-Te [Argonne National Lab. (ANL), Argonne, IL (United States); Yoichi, Momozaki [Argonne National Lab. (ANL), Argonne, IL (United States); Bakhtiari, Sasan [Argonne National Lab. (ANL), Argonne, IL (United States)
2016-06-29
The project “Modeling and Validation of Sodium Plugging for Heat Exchangers in Sodium-cooled Fast Reactor Systems” was conducted jointly by Westinghouse Electric Company (Westinghouse) and Argonne National Laboratory (ANL), over the period October 1, 2013- March 31, 2016. The project’s motivation was the need to provide designers of Sodium Fast Reactors (SFRs) with a validated, state-of-the-art computational tool for the prediction of sodium oxide (Na_{2}O) deposition in small-diameter sodium heat exchanger (HX) channels, such as those in the diffusion bonded HXs proposed for SFRs coupled with a supercritical CO_{2} (sCO_{2}) Brayton cycle power conversion system. In SFRs, Na_{2}O deposition can potentially occur following accidental air ingress in the intermediate heat transport system (IHTS) sodium and simultaneous failure of the IHTS sodium cold trap. In this scenario, oxygen can travel through the IHTS loop and reach the coldest regions, represented by the cold end of the sodium channels of the HXs, where Na_{2}O precipitation may initiate and continue. In addition to deteriorating HX heat transfer and pressure drop performance, Na_{2}O deposition can lead to channel plugging especially when the size of the sodium channels is small, which is the case for diffusion bonded HXs whose sodium channel hydraulic diameter is generally below 5 mm. Sodium oxide melts at a high temperature well above the sodium melting temperature such that removal of a solid plug such as through dissolution by pure sodium could take a lengthy time. The Sodium Plugging Phenomena Loop (SPPL) was developed at ANL, prior to this project, for investigating Na_{2}O deposition phenomena within sodium channels that are prototypical of the diffusion bonded HX channels envisioned for SFR-sCO_{2} systems. In this project, a Computational Fluid Dynamic (CFD) model capable of simulating the thermal-hydraulics of the SPPL test
Many-body dispersion interactions from the exchange-hole dipole moment model.
Otero-de-la-Roza, A; Johnson, Erin R
2013-02-07
In this article, we present the extension of the exchange-hole dipole moment model (XDM) of dispersion interactions to the calculation of two-body and three-body dispersion energy terms to any order, 2(l)-pole oscillator strengths, and polarizabilities. By using the newly-formulated coefficients, we study the relative importance of the higher-order two-body and the leading non-additive three-body (triple-dipole) interactions in gas-phase as well as in condensed systems. We show that the two-body terms up to R(-10), but not the terms of higher-order, are essential in the correct description of the dispersion energy, while there are a number of difficulties related to the choice of the damping function, which precludes the use three-body triple-dipole contributions in XDM. We conclude that further study is required before the three-body term can be used in production XDM density-functional calculations and point out the salient problems regarding its use.
Zhou, Yibo; Luo, Yueqi; Yu, Shuhai; Jiao, Kui
2014-02-01
In this study, a cold start model for proton exchange membrane fuel cell (PEMFC) stacks is developed, and a novel start-up method, variable heating and load control (VHLC), is proposed and evaluated. The main idea is to only apply load to the neighboring still-active cells, and to apply external heating to certain cells inside the stack simultaneously (load is not applied to the cells fully blocked by ice, although these cells can gain heat from neighboring cells). With the VHLC method, it is found that the stack voltage first increases, then decreases due to the full blockage of ice in some of the individual cells, and finally the dead cells are heated by the other active cells and activated again one by one. Based on this method, the external heating power and the stack self-heating ability are utilized more efficiently. With proper implementation of the VHLC method, it is demonstrated that the cold stat performance can be improved significantly, which is critically important for PEMFC in automotive applications.
CFD Modeling of Sodium-Oxide Deposition in Sodium-Cooled Fast Reactor Compact Heat Exchangers
Energy Technology Data Exchange (ETDEWEB)
Tatli, Emre; Ferroni, Paolo; Mazzoccoli, Jason
2015-09-02
The possible use of compact heat exchangers (HXs) in sodium-cooled fast reactors (SFR) employing a Brayton cycle is promising due to their high power density and resulting small volume in comparison with conventional shell-and-tube HXs. However, the small diameter of their channels makes them more susceptible to plugging due to Na2O deposition during accident conditions. Although cold traps are designed to reduce oxygen impurity levels in the sodium coolant, their failure, in conjunction with accidental air ingress into the sodium boundary, could result in coolant oxygen levels that are above the saturation limit in the cooler parts of the HX channels. This can result in Na2O crystallization and the formation of solid deposits on cooled channel surfaces, limiting or even blocking coolant flow. The development of analysis tools capable of modeling the formation of these deposits in the presence of sodium flow will allow designers of SFRs to properly size the HX channels so that, in the scenario mentioned above, the reactor operator has sufficient time to detect and react to the affected HX. Until now, analytical methodologies to predict the formation of these deposits have been developed, but never implemented in a high-fidelity computational tool suited to modern reactor design techniques. This paper summarizes the challenges and the current status in the development of a Computational Fluid Dynamics (CFD) methodology to predict deposit formation, with particular emphasis on sensitivity studies on some parameters affecting deposition.
Design Fluida Temperature Control in Heat Exchanger using Model Predictive Control Algoritm
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Fatimah Ekasari Masturi
2014-03-01
Full Text Available Heat Exchanger merupakan suatu alat proses pertukaran panas, berfungsi untuk memindahkan panas antara dua fluida yang berbeda temperatur dan dipisahkan oleh suatu sekat pemisah. Pada proses perpindahan panas ini terdapat delay time sehingga dibutuhkan suatu kontroller agar diperoleh temperatur fluida sesuai dengan kriteria yang diinginkan, tidak terdapat energi yang terbuang, serta pemanfaatan sumber energi yang tersedia benar-benar dapat lebih efisien. Model Predictive Control (MPC telah berhasil diaplikasikan di berbagai industri proses, karena kemampuannya untuk mengatasi berbagai masalah multivariabel kontrol seperti interaksi, waktu tunda dan batasan. Keuntungan dari MPC karena kedua variabel, yaitu variabel manipulasi dan variabel kontrol, dihitung dengan menggunakan teknik optimasi. Pengendalian terhadap pendekatan linear plant dengan Kontroler MPC menggunakan parameter Hp (prediksi horizon= 20 Hc(kontrol horizon= 4 matriks pembobot Q=1 R=0.1 dapat menghasilkan respon yang stabil tanpa adanya overshoot serta mampu mencapai setpoint yang diinginkan yaitu 70°C, pada beban tetap (nominal ataupun beban bervariasi sekitar 20 % dari beban nominal dengan waktu steady state 35s.
Two-photon-exchange effects in the unpolarized μ p scattering within a hadronic model
Zhou, Hai-Qing
2017-02-01
In this work, the two-photon-exchange (TPE) effects in the unpolarized μ p scattering are discussed within the hadronic model where the intermediate states N ,Δ , and σ are considered. The contribution from the N intermediate is close to the results given by Tomalak and Vanderhaeghen [Phys. Rev. D 90, 013006 (2014)], 10.1103/PhysRevD.90.013006 at small Q , and there is a sizable difference when Q >0.25 GeV (where Q2 is the four-momentum transfer). The contributions from the Δ and the σ intermediate states are much smaller than that from the N intermediate at small Q . In the kinematic region with ki⊆[0.01 ,0.3 ] GeV and Q ≤0.4 GeV (where ki is the three-momentum of initial muon in the laboratory frame), a naive expression for the TPE contributions is given, which can be used directly for other analysis.
Loyselle, Patricia; Prokopius, Kevin
2011-01-01
Proton exchange membrane (PEM) fuel cell technology is the leading candidate to replace the aging alkaline fuel cell technology, currently used on the Shuttle, for future space missions. This test effort marks the final phase of a 5-yr development program that began under the Second Generation Reusable Launch Vehicle (RLV) Program, transitioned into the Next Generation Launch Technologies (NGLT) Program, and continued under Constellation Systems in the Exploration Technology Development Program. Initially, the engineering model (EM) powerplant was evaluated with respect to its performance as compared to acceptance tests carried out at the manufacturer. This was to determine the sensitivity of the powerplant performance to changes in test environment. In addition, a series of tests were performed with the powerplant in the original standard orientation. This report details the continuing EM benchmark test results in three spatial orientations as well as extended duration testing in the mission profile test. The results from these tests verify the applicability of PEM fuel cells for future NASA missions. The specifics of these different tests are described in the following sections.
Whittleton, Sarah R; Otero-de-la-Roza, A; Johnson, Erin R
2017-02-14
Accurate energy ranking is a key facet to the problem of first-principles crystal-structure prediction (CSP) of molecular crystals. This work presents a systematic assessment of B86bPBE-XDM, a semilocal density functional combined with the exchange-hole dipole moment (XDM) dispersion model, for energy ranking using 14 compounds from the first five CSP blind tests. Specifically, the set of crystals studied comprises 11 rigid, planar compounds and 3 co-crystals. The experimental structure was correctly identified as the lowest in lattice energy for 12 of the 14 total crystals. One of the exceptions is 4-hydroxythiophene-2-carbonitrile, for which the experimental structure was correctly identified once a quasi-harmonic estimate of the vibrational free-energy contribution was included, evidencing the occasional importance of thermal corrections for accurate energy ranking. The other exception is an organic salt, where charge-transfer error (also called delocalization error) is expected to cause the base density functional to be unreliable. Provided the choice of base density functional is appropriate and an estimate of temperature effects is used, XDM-corrected density-functional theory is highly reliable for the energetic ranking of competing crystal structures.
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Radi A. Jishi
2016-01-01
Full Text Available We report first-principles calculations, within density functional theory, on the lead halide compounds PbCl2, PbBr2, and CH3NH3PbBr3−xClx, taking into account spin-orbit coupling. We show that, when the modified Becke-Johnson exchange potential is used with a suitable choice of defining parameters, excellent agreement between calculations and experiment is obtained. The computational model is then used to study the effect of replacing the methylammonium cation in CH3NH3PbI3 and CH3NH3PbBr3 with either N2H5+or N2H3+, which have slightly smaller ionic radii than methylammonium. We predict that a considerable downshift in the values of the band gaps occurs with this replacement. The resulting compounds would extend optical absorption down to the near-infrared region, creating excellent light harvesters for solar cells.
Developing a hybrid multi-criteria model for investment in stock exchange
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Safar Fazli
2012-04-01
Full Text Available One of the main challenges in Stock Market is to choose an appropriate combinations of various assets. The aim of this study is to propose a hybrid method, which is able to survey one problem with some criteria that it is very good for investment problem. In this study, we use a hybrid multiple criteria decision-making (MCDM model, which shows the dependent relationships among criteria with DEMATEL method to build a relations-structure among criteria. We then use Analytical Network Process (ANP to determine the relative weights of each criterion with dependence and feedback, and the VIKOR method is implemented to rank and select the best alternatives for investment. This study is in stock exchange in Iran to select the best stocks and the data are gathered through the years (2006-2010. There are a lot of methods to rank and select of firms that most of the methods just do one, ranking or selecting; but the used method in this study not only ranks the firms but also determines which firms (stocks are best for investment, so that in this study 2 of 50 firms are proposed for investment.
Spectral Modeling of the Charge-Exchange X-ray Emission from M82
Zhang, Shuinai; Ji, Li; Smith, Randall K; Foster, Adam R; Zhou, Xin
2014-01-01
It has been proposed that the charge exchange (CX) process at the interface between hot and cool interstellar gases could contribute significantly to the observed soft X-ray emission in star forming galaxies. We analyze the XMM-Newton/RGS spectrum of M82, using a newly developed CX model combined with a single-temperature thermal plasma to characterize the volume-filling hot gas. The CX process is largely responsible for not only the strongly enhanced forbidden lines of the K$\\alpha$ triplets of various He-like ions, but also good fractions of the Ly$\\alpha$ transitions of C VI (~87%), O VIII and N VII ($\\gtrsim$50%) as well. In total about a quarter of the X-ray flux in the RGS 6-30 \\AA\\ band originates in the CX. We infer an ion incident rate of $3\\times10^{51}\\,\\rm{s^{-1}}$ undergoing CX at the hot and cool gas interface, and an effective area of the interface as $\\sim2\\times10^{45}\\,{\\rm cm^2}$ that is one order of magnitude larger than the cross section of the global biconic outflow. With the CX contribu...
Modeling putative therapeutic implications of exosome exchange between tumor and immune cells.
Lu, Mingyang; Huang, Bin; Hanash, Samir M; Onuchic, José N; Ben-Jacob, Eshel
2014-10-07
Development of effective strategies to mobilize the immune system as a therapeutic modality in cancer necessitates a better understanding of the contribution of the tumor microenvironment to the complex interplay between cancer cells and the immune response. Recently, effort has been directed at unraveling the functional role of exosomes and their cargo of messengers in this interplay. Exosomes are small vesicles (30-200 nm) that mediate local and long-range communication through the horizontal transfer of information, such as combinations of proteins, mRNAs and microRNAs. Here, we develop a tractable theoretical framework to study the putative role of exosome-mediated cell-cell communication in the cancer-immunity interplay. We reduce the complex interplay into a generic model whose three components are cancer cells, dendritic cells (consisting of precursor, immature, and mature types), and killer cells (consisting of cytotoxic T cells, helper T cells, effector B cells, and natural killer cells). The framework also incorporates the effects of exosome exchange on enhancement/reduction of cell maturation, proliferation, apoptosis, immune recognition, and activation/inhibition. We reveal tristability-possible existence of three cancer states: a low cancer load with intermediate immune level state, an intermediate cancer load with high immune level state, and a high cancer load with low immune-level state, and establish the corresponding effective landscape for the cancer-immunity network. We illustrate how the framework can contribute to the design and assessments of combination therapies.
Determinants of the ZAR/USD exchange rate and policy implications: A simultaneous-equation model
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Yu Hsing
2016-12-01
Full Text Available This paper examines the determinants of the South African rand/US dollar (ZAR/USD exchange rate based on demand and supply analysis. Applying the EGARCH method, the paper finds that the ZAR/USD exchange rate is positively associated with the South African government bond yield, US real GDP, the US stock price and the South African inflation rate and negatively influenced by the 10-year US government bond yield, South African real GDP, the South African stock price, and the US inflation rate. The adoption of a free floating exchange rate regime has reduced the value of the rand vs. the US dollar.
Munz, Matthias; Schmidt, Christian; Fleckenstein, Jan; Oswald, Sascha
2013-04-01
In this study we used the deterministic, fully-integrated surface-subsurface flow and heat transport model (HydroGeoSphere) to investigate the spatial and temporal variability of surface water-groundwater (SFW-GW) interaction along a lowland river reach. The model incorporates the hydrological as well as the heat transport processes including (1) radiative fluxes warming and cooling the surface water; (2) seasonal groundwater temperature changes; (3) occasionally occurring heat inputs due to precipitation and (4) highly variable SFW-GW water advective heat exchange driven by the general relation between SFW and GW hydraulic heads and geomorphological structure of the riverbed. The study area is a 100 m long lowland river reach of the Selke river, at the boundary of the Harz mountains characterized by distinctive gravel bars. Continuous time series of hydraulic heads and temperatures at different depth in the river bank, the hyporheic zone and within the river are used to define the boundary conditions, to calibrate and to validate the numerical model. The 3D modelling results show that the water and heat exchange at the SFW-GW interface is highly variable in space with zones of daily temperature oscillations penetrating deep into the sediment and spots of daily constant temperature following the average GW temperature. To increase the understanding of evolving pattern, the observed temperature variations in space and time will be linked to dominant stream flow conditions, streambed morphology, advective and conductive heat exchange between SFW and GW and subsurface solute residence times. This study allows to analyse and quantify water and heat fluxes at the SFW-GW interface, to trace subsurface flow paths within the streambed sediments and thus improves the understanding of hyporheic zone exchange mechanisms. It is a sound basis for investigating quantitatively variations of sediment properties, boundary conditions and streambed morphology and also for subsequent
Ibáñez, Juan José; Ortega, David; Campos, Daniel; Khalidi, Lamya; Méndez, Vicenç
2015-06-06
In this paper, we explore the conditions that led to the origins and development of the Near Eastern Neolithic using mathematical modelling of obsidian exchange. The analysis presented expands on previous research, which established that the down-the-line model could not explain long-distance obsidian distribution across the Near East during this period. Drawing from outcomes of new simulations and their comparison with archaeological data, we provide results that illuminate the presence of complex networks of interaction among the earliest farming societies. We explore a network prototype of obsidian exchange with distant links which replicates the long-distance movement of ideas, goods and people during the Early Neolithic. Our results support the idea that during the first (Pre-Pottery Neolithic A) and second (Pre-Pottery Neolithic B) phases of the Early Neolithic, the complexity of obsidian exchange networks gradually increased. We propose then a refined model (the optimized distant link model) whereby long-distance exchange was largely operated by certain interconnected villages, resulting in the appearance of a relatively homogeneous Neolithic cultural sphere. We hypothesize that the appearance of complex interaction and exchange networks reduced risks of isolation caused by restricted mobility as groups settled and argue that these networks partially triggered and were crucial for the success of the Neolithic Revolution. Communities became highly dynamic through the sharing of experiences and objects, while the networks that developed acted as a repository of innovations, limiting the risk of involution. © 2015 The Author(s) Published by the Royal Society. All rights reserved.
Scrape-off layer modeling with kinetic or diffusion description of charge-exchange atoms
Tokar, M. Z.
2016-12-01
Hydrogen isotope atoms, generated by charge-exchange (c-x) of neutral particles recycling from the first wall of a fusion reactor, are described either kinetically or in a diffusion approximation. In a one-dimensional (1-D) geometry, kinetic calculations are accelerated enormously by applying an approximate pass method for the assessment of integrals in the velocity space. This permits to perform an exhaustive comparison of calculations done with both approaches. The diffusion approximation is deduced directly from the velocity distribution function of c-x atoms in the limit of charge-exchanges with ions occurring much more frequently than ionization by electrons. The profiles across the flux surfaces of the plasma parameters averaged along the main part of the scrape-off layer (SOL), beyond the X-point and divertor regions, are calculated from the one-dimensional equations where parallel flows of charged particles and energy towards the divertor are taken into account as additional loss terms. It is demonstrated that the heat losses can be firmly estimated from the SOL averaged parameters only; for the particle loss the conditions in the divertor are of importance and the sensitivity of the results to the so-called "divertor impact factor" is investigated. The coupled 1-D models for neutral and charged species, with c-x atoms described either kinetically or in the diffusion approximation, are applied to assess the SOL conditions in a fusion reactor, with the input parameters from the European DEMO project. It is shown that the diffusion approximation provides practically the same profiles across the flux surfaces for the plasma density, electron, and ion temperatures, as those obtained with the kinetic description for c-x atoms. The main difference between the two approaches is observed in the characteristics of these species themselves. In particular, their energy flux onto the wall is underestimated in calculations with the diffusion approximation by 20 %-30
Lukens, Wayne W; Magnani, Nicola; Booth, Corwin H
2012-10-01
Exchange coupling is quantified in lanthanide (Ln) single-molecule magnets (SMMs) containing a bridging N(2)(3-) radical ligand and between [Cp*(2)Yb](+) and bipy(•-) in Cp*(2)Yb(bipy), where Cp* is pentamethylcyclopentadienyl and bipy is 2,2'-bipyridyl. In the case of these lanthanide SMMs, the magnitude of exchange coupling between the Ln ion and the bridging N(2)(3-), 2J, is very similar to the barrier to magnetic relaxation, U(eff). A molecular version of the Hubbard model is applied to systems in which unpaired electrons on magnetic metal ions have direct overlap with unpaired electrons residing on ligands. The Hubbard model explicitly addresses electron correlation, which is essential for understanding the magnetic behavior of these complexes. This model is applied quantitatively to Cp*(2)Yb(bipy) to explain its very strong exchange coupling, 2J = -0.11 eV (-920 cm(-1)). The model is also used to explain the presence of strong exchange coupling in Ln SMMs in which the lanthanide spins are coupled via bridging N(2)(3-) radical ligands. The results suggest that increasing the magnetic coupling in lanthanide clusters could lead to an increase in the blocking temperatures of exchange-coupled lanthanide SMMs, suggesting routes to rational design of future lanthanide SMMs.
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Kido, K.; Sato, N.; Shimoji, M. [Konica Co. Ltd., Tokyo (Japan); Nakanishi, E. [Kobe University, Kobe (Japan). Faculty of Engineering
1996-01-20
Nonlinear and linear temperature dynamic models of a heat exchanger were investigated for air conditioning control of coating and drying processes for photosensitive materials. The nonlinear model was derived from heat balance based on the assumption of lumped parameter system that the heat exchanger is divided into small parts in the direction of flow (divided cell model). In each part, the temperature of the heating fluid, heated fluid and heat transfer tube with fin are assumed to be uniform. Parameters involved in this model were estimated from experimental data of the step response characteristics of temperature. The linear model is obtained by linearizing this nonlinear model. It was confirmed that the dynamic behavior of temperature can be successfully expressed by both nonlinear and linear models. Both models are considered to be utilizable for process analysis and control system design of the air conditioning system under consideration. 1 ref., 13 figs., 2 tabs.